Yield degradation in inertial-confinement-fusion implosions due to shock-driven kinetic fuel-species stratification and viscous heating

Science.gov (United States)

Taitano, W. T.; Simakov, A. N.; Chacón, L.; Keenan, B.

2018-05-01

Anomalous thermonuclear yield degradation (i.e., that not describable by single-fluid radiation hydrodynamics) in Inertial Confinement Fusion (ICF) implosions is ubiquitously observed in both Omega and National Ignition experiments. Multiple experimental and theoretical studies have been carried out to investigate the origin of such a degradation. Relative concentration changes of fuel-ion species, as well as kinetically enhanced viscous heating, have been among possible explanations proposed for certain classes of ICF experiments. In this study, we investigate the role of such kinetic plasma effects in detail. To this end, we use the iFP code to perform multi-species ion Vlasov-Fokker-Planck simulations of ICF capsule implosions with the fuel comprising various hydrodynamically equivalent mixtures of deuterium (D) and helium-3 (3He), as in the original Rygg experiments [J. R. Rygg et al., Phys. Plasmas 13, 052702 (2006)]. We employ the same computational setup as in O. Larroche [Phys. Plasmas 19, 122706 (2012)], which was the first to simulate the experiments kinetically. However, unlike the Larroche study, and in partial agreement with experimental data, we find a systematic yield degradation in multi-species simulations versus averaged-ion simulations when the D-fuel fraction is decreased. This yield degradation originates in the fuel-ion species stratification induced by plasma shocks, which imprints the imploding system and results in the relocation of the D ions from the core of the capsule to its periphery, thereby reducing the yield relative to a non-separable averaged-ion case. By comparing yields from the averaged-ion kinetic simulations and from the hydrodynamic scaling, we also observe yield variations associated with ion kinetic effects other than fuel-ion stratification, such as ion viscous heating, which is typically neglected in hydrodynamic implosions' simulations. Since our kinetic simulations are driven by hydrodynamic boundary conditions at the

Kinetic Studies on State of the Art Solid Oxide Cells – A Comparison between Hydrogen/Steam and Reformate Fuels

DEFF Research Database (Denmark)

Njodzefon, Jean-Claude; Graves, Christopher R.; Mogensen, Mogens Bjerg

2015-01-01

Electrochemical reaction kinetics at the electrodes of Solid Oxide Cells (SOCs) were investigated at 700 °C for two cells with different fuel electrode microstructures as well as on a third cell with a reduced active electrode area. Three fuel mixtures were investigated – hydrogen/steam and refor......Electrochemical reaction kinetics at the electrodes of Solid Oxide Cells (SOCs) were investigated at 700 °C for two cells with different fuel electrode microstructures as well as on a third cell with a reduced active electrode area. Three fuel mixtures were investigated – hydrogen....../steam fuel split into two processes with opposing temperature behavior in the reformate fuels. An 87.5% reduction in active electrode area diminishes the gas conversion impedance in the hydrogen/steam fuel at high fuel flow rates. In both reformates, the second and third lowest frequency processes merged...

HTGR Technology Family Assessment for a Range of Fuel Cycle Missions

International Nuclear Information System (INIS)

Piet, Steven J.; Bays, Samuel E.; Soelberg, Nick

2010-01-01

This report examines how the HTGR technology family can provide options for the once through, modified open cycle (MOC), or full recycle fuel cycle strategies. The HTGR can serve all the fuel cycle missions that an LWR can; both are thermal reactors. Additional analyses are warranted to determine if HTGR 'full recycle' service could provide improved consumption of transuranic (TRU) material than LWRs (as expected), to analyze the unique proliferation resistance issues associated with the 'pebble bed' approach, and to further test and analyze methods to separate TRISO-coated fuel particles from graphite and/or to separate used HTGR fuel meat from its TRISO coating. The feasibility of these two separation issues is not in doubt, but further R and D could clarify and reduce the cost and enable options not adequately explored at present. The analyses here and the now-demonstrated higher fuel burnup tests (after the illustrative designs studied here) should enable future MOC and full recycle HTGR concepts to more rapidly consume TRU, thereby offering waste management advantages. Interest in 'limited separation' or 'minimum fuel treatment' separation approaches motivates study of impurity-tolerant fuel fabrication. Several issues are outside the scope of this report, including the following: thorium fuel cycles, gas-cooled fast reactors, the reliability of TRISO-coated particles (billions in a reactor), and how soon any new reactor or fuel type could be licensed and then deployed and therefore impact fuel cycle performance measures.

HTGR Technology Family Assessment for a Range of Fuel Cycle Missions

Energy Technology Data Exchange (ETDEWEB)

Steven J. Piet; Samuel E. Bays; Nick Soelberg

2010-08-01

This report examines how the HTGR technology family can provide options for the once through, modified open cycle (MOC), or full recycle fuel cycle strategies. The HTGR can serve all the fuel cycle missions that an LWR can; both are thermal reactors. Additional analyses are warranted to determine if HTGR “full recycle” service could provide improved consumption of transuranic (TRU) material than LWRs (as expected), to analyze the unique proliferation resistance issues associated with the “pebble bed” approach, and to further test and analyze methods to separate TRISO-coated fuel particles from graphite and/or to separate used HTGR fuel meat from its TRISO coating. The feasibility of these two separation issues is not in doubt, but further R&D could clarify and reduce the cost and enable options not adequately explored at present. The analyses here and the now-demonstrated higher fuel burnup tests (after the illustrative designs studied here) should enable future MOC and full recycle HTGR concepts to more rapidly consume TRU, thereby offering waste management advantages. Interest in “limited separation” or “minimum fuel treatment” separation approaches motivates study of impurity-tolerant fuel fabrication. Several issues are outside the scope of this report, including the following: thorium fuel cycles, gas-cooled fast reactors, the reliability of TRISO-coated particles (billions in a reactor), and how soon any new reactor or fuel type could be licensed and then deployed and therefore impact fuel cycle performance measures.

Improving fuel quality by whole crude oil hydrotreating: A kinetic model for hydrodeasphaltenization in a trickle bed reactor

International Nuclear Information System (INIS)

Jarullah, A.T.; Mujtaba, I.M.; Wood, A.S.

2012-01-01

Highlights: ► Asphaltene contaminant must be removed to a large extent from the fuel to meet the regulatory demand. ► Kinetics for hydrodeasphaltenization are estimated via experimentation and modeling. ► Using the kinetic parameters, a full process model for the trickle bed reactor (TBR) is developed. ► The model is used for simulating the behavior of the TBR to get further insight of the process. ► The influences of operating conditions in the hydrodeasphaltenization process are reported. -- Abstract: Fossil fuel is still a predominant source of the global energy requirement. Hydrotreating of whole crude oil has the ability to increase the productivity of middle distillate fractions and improve the fuel quality by simultaneously reducing contaminants such as sulfur, nitrogen, vanadium, nickel and asphaltene to the levels required by the regulatory bodies. Hydrotreating is usually carried out in a trickle bed reactor (TBR) where hydrodesulfurization (HDS), hydrodenitrogenation (HDN), hydrodemetallization (HDM) and hydrodeasphaltenization (HDAs) reactions take place simultaneously. To develop a detailed and a validated TBR process model which can be used for design and optimization of the hydrotreating process, it is essential to develop kinetic models for each of these reactions. Most recently, the authors have developed kinetic models for all of these chemical reactions except that of HDAs. In this work, a kinetic model (in terms of kinetic parameters) for the HDAs reaction in the TBR is developed. A three phase TBR process model incorporating the HDAs reactions with unknown kinetic parameters is developed. Also, a series of experiments has been conducted in an isothermal TBR under different operating conditions affecting the removal of asphaltene. The unknown kinetic parameters are then obtained by applying a parameter estimation technique based on minimization of the sum of square errors (SSEs) between the experimental and predicted concentrations of

Kinetic parameters of a material test research reactor fueled with various low enriched uranium dispersion fuels

International Nuclear Information System (INIS)

Muhammad, Farhan; Majid, Asad

2009-01-01

The effects of using different low enriched uranium fuels, having same uranium density, on the kinetic parameters of a material test research reactor were studied. For this purpose, the original aluminide fuel (UAl x -Al) containing 4.40 gU/cm 3 of an MTR was replaced with silicide (U 3 Si-Al and U 3 Si 2 -Al) and oxide (U 3 O 8 -Al) dispersion fuels having the same uranium density as of the original fuel. Simulations were carried out to calculate prompt neutron generation time, effective delayed-neutron fraction, core excess reactivity and neutron flux spectrum. Nuclear reactor analysis codes including WIMS-D4 and CITATION were used to carry out these calculations. It was observed that both the silicide fuels had the same prompt neutron generation time 0.02% more than that of the original aluminide fuel, while the oxide fuel had a prompt neutron generation time 0.05% less than that of the original aluminide fuel. The effective delayed-neutron fraction decreased for all the fuels; the decrease was maximum at 0.06% for U 3 Si 2 -Al followed by 0.03% for U 3 Si-Al, and 0.01% for U 3 O 8 -Al fuel. The U 3 O 8 -Al fueled reactor gave the maximum ρ excess at BOL which was 21.67% more than the original fuel followed by U 3 Si-Al which was 2.55% more, while that of U 3 Si 2 -Al was 2.50% more than the original UAl x -Al fuel. The neutron flux of all the fuels was more thermalized, than in the original fuel, in the active fuel region of the core. The thermalization was maximum for U 3 O 8 -Al followed by U 3 Si-Al and then U 3 Si 2 -Al fuel.

Elementary kinetic modelling applied to solid oxide fuel cell pattern anodes and a direct flame fuel cell system

Energy Technology Data Exchange (ETDEWEB)

Vogler, Marcel

2009-05-27

In the course of this thesis a model for the prediction of polarisation characteristics of solid oxide fuel cells (SOFC) was developed. The model is based on an elementary kinetic description of electrochemical reactions and the fundamental conservation principles of mass and energy. The model allows to predict the current-voltage relation of an SOFC and offers ideal possibilities for model validation. The aim of this thesis is the identification of rate-limiting processes and the determination of the elementary pathway during charge transfer. The numerical simulation of experiments with model anodes allowed to identify a hydrogen transfer to be the most probable charge-transfer reaction and revealed the influence of diffusive transport. Applying the hydrogen oxidation kinetics to the direct flame fuel cell system (DFFC) showed that electrochemical oxidation of CO is possible based on the same mechanism. Based on the quantification of loss processes in the DFFC system, improvements on cell design, predicting 80% increase of efficiency, were proposed. (orig.)

A reduced chemical kinetic model for the analytical investigations on the oxidation kinetics and performance characteristics of diesel fuel

International Nuclear Information System (INIS)

Selvaraj, N.; Manoj Kumar, C.V.; Babu, M.S.

2010-01-01

A detailed study of the combustion of diesel fuel has been conducted analytically using a kinetic scheme with 767 elementary reactions and 158 species. A program has been developed in MATLAB for the analysis of ignition delay, performance, soot formation and emission characteristics of diesel fuel. Nitrogen is considered as the diluent and its percentage is assumed as 79%. The criteria used for the determination of ignition delay time are based on OH concentration to reach a value of 1x10 -9 . A brief review of diesel combustion and soot formation is given. (author)

Asteroid Kinetic Impactor Missions

Science.gov (United States)

Chesley, Steven

2015-08-01

Asteroid impact missions can be carried out as a relatively low-cost add-ons to most asteroid rendezvous missions and such impact experiments have tremendous potential, both scientifically and in the arena of planetary defense.The science returns from an impactor demonstration begin with the documentation of the global effects of the impact, such as changes in orbit and rotation state, the creation and dissipation of an ejecta plume and debris disk, and morphological changes across the body due to the transmission of seismic waves, which might induce landslides and toppling of boulders, etc. At a local level, an inspection of the impact crater and ejecta blanket reveals critical material strength information, as well as spectral differences between the surface and subsurface material.From the planetary defense perspective, an impact demonstration will prove humankind’s capacity to alter the orbit of a potentially threatening asteroid. This technological leap comes in two parts. First, terminal guidance systems that can deliver an impactor with small errors relative to the ~100-200 meter size of a likely impactor have yet to be demonstrated in a deep space environment. Second, the response of an asteroid to such an impact is only understood theoretically due to the potentially significant dependence on the momentum carried by escaping ejecta, which would tend to enhance the deflection by tens of percent and perhaps as much as a factor of a few. A lack of validated understanding of momentum enhancement is a significant obstacle in properly sizing a real-world impactor deflection mission.This presentation will describe the drivers for asteroid impact demonstrations and cover the range of such concepts, starting with ESA’s pioneering Don Quijote mission concept and leading to a brief description of concepts under study at the present time, including the OSIRIS-REx/ISIS, BASiX/KIX and AIM/DART (AIDA) concepts.

Turbulent Flame Speeds and NOx Kinetics of HHC Fuels with Contaminants and High Dilution Levels

Energy Technology Data Exchange (ETDEWEB)

Peterson, Eric [Texas A & M Univ., College Station, TX (United States); Krejci, Michael [Texas A & M Univ., College Station, TX (United States); Mathieu, Olivier [Texas A & M Univ., College Station, TX (United States); Vissotski, Andrew [Texas A & M Univ., College Station, TX (United States); Ravi, Sankat [Texas A & M Univ., College Station, TX (United States); Plichta, Drew [Texas A & M Univ., College Station, TX (United States); Sikes, Travis [Texas A & M Univ., College Station, TX (United States); Levacque, Anthony [Texas A & M Univ., College Station, TX (United States); Camou, Alejandro [Texas A & M Univ., College Station, TX (United States); Aul, Christopher [Texas A & M Univ., College Station, TX (United States)

2014-01-24

This final report documents the technical results of the 3-year project entitled, “Turbulent Flame Speeds and NOx Kinetics of HHC Fuels with Contaminants and High Dilution Levels,” funded under the NETL of DOE. The research was conducted under six main tasks: 1) program management and planning; 2) turbulent flame speed measurements of syngas mixtures; 3) laminar flame speed measurements with diluents; 4) NOx mechanism validation experiments; 5) fundamental NOx kinetics; and 6) the effect of impurities on NOx kinetics. Experiments were performed using primary constant-volume vessels for laminar and turbulent flame speeds and shock tubes for ignition delay times and species concentrations. In addition to the existing shock- tube and flame speed facilities, a new capability in measuring turbulent flame speeds was developed under this grant. Other highlights include an improved NOx kinetics mechanism; a database on syngas blends for real fuel mixtures with and without impurities; an improved hydrogen sulfide mechanism; an improved ammonia kintics mechanism; laminar flame speed data at high pressures with water addition; and the development of an inexpensive absorption spectroscopy diagnostic for shock-tube measurements of OH time histories. The Project Results for this work can be divided into 13 major sections, which form the basis of this report. These 13 topics are divided into the five areas: 1) laminar flame speeds; 2) Nitrogen Oxide and Ammonia chemical kinetics; 3) syngas impurities chemical kinetics; 4) turbulent flame speeds; and 5) OH absorption measurements for chemical kinetics.

Fuel spray combustion of waste cooking oil and palm oil biodiesel: Direct photography and detailed chemical kinetics

KAUST Repository

Kuti, Olawole

2013-10-14

This paper studies the ignition processes of two biodiesel from two different feedstock sources, namely waste cooked oil (WCO) and palm oil (PO). They were investigated using the direct photography through high-speed video observations and detailed chemical kinetics. The detailed chemical kinetics modeling was carried out to complement data acquired using the high-speed video observations. For the high-speed video observations, an image intensifier combined with OH* filter connected to a high-speed video camera was used to obtain OH* chemiluminscence image near 313 nm. The OH* images were used to obtain the experimental ignition delay of the biodiesel fuels. For the high-speed video observations, experiments were done at an injection pressure of 100, 200 and 300 MPa using a 0.16 mm injector nozzle. Also a detailed chemical kinetics for the biodiesel fuels was carried out using ac chemical kinetics solver adopting a 0-D reactor model to obtain the chemical ignition delay of the combusting fuels. Equivalence ratios obtained from the experimental ignition delay were used for the detailed chemical kinetics analyses. The Politecnico di Milano\\'s thermochemical and reaction kinetic data were adopted to simulate the ignition processes of the biodiesels using the five fatty acid methyl esters (FAME) major components in the biodiesel fuels. From the high-speed video observations, it was observed that at increasing injection pressure, experimental ignition delay increased as a result of improvement in fuel and air mixing effects. Also the palm oil biodiesel has a shorter ignition delay compared to waste cooked oil biodiesel. This phenomenon could be attributed to the higher cetane number of palm biodiesel. The fuel spray ignition properties depend on both the physical ignition delay and chemical ignition delay. From the detailed chemical kinetic results it was observed that at the low temperature, high ambient pressure conditions reactivity increased as equivalent ratio

Fuel spray combustion of waste cooking oil and palm oil biodiesel: Direct photography and detailed chemical kinetics

KAUST Repository

Kuti, Olawole; Nishida, Keiya; Sarathy, Mani; Zhu, Jingyu

2013-01-01

This paper studies the ignition processes of two biodiesel from two different feedstock sources, namely waste cooked oil (WCO) and palm oil (PO). They were investigated using the direct photography through high-speed video observations and detailed chemical kinetics. The detailed chemical kinetics modeling was carried out to complement data acquired using the high-speed video observations. For the high-speed video observations, an image intensifier combined with OH* filter connected to a high-speed video camera was used to obtain OH* chemiluminscence image near 313 nm. The OH* images were used to obtain the experimental ignition delay of the biodiesel fuels. For the high-speed video observations, experiments were done at an injection pressure of 100, 200 and 300 MPa using a 0.16 mm injector nozzle. Also a detailed chemical kinetics for the biodiesel fuels was carried out using ac chemical kinetics solver adopting a 0-D reactor model to obtain the chemical ignition delay of the combusting fuels. Equivalence ratios obtained from the experimental ignition delay were used for the detailed chemical kinetics analyses. The Politecnico di Milano's thermochemical and reaction kinetic data were adopted to simulate the ignition processes of the biodiesels using the five fatty acid methyl esters (FAME) major components in the biodiesel fuels. From the high-speed video observations, it was observed that at increasing injection pressure, experimental ignition delay increased as a result of improvement in fuel and air mixing effects. Also the palm oil biodiesel has a shorter ignition delay compared to waste cooked oil biodiesel. This phenomenon could be attributed to the higher cetane number of palm biodiesel. The fuel spray ignition properties depend on both the physical ignition delay and chemical ignition delay. From the detailed chemical kinetic results it was observed that at the low temperature, high ambient pressure conditions reactivity increased as equivalent ratio

New Procedure to Develop Lumped Kinetic Models for Heavy Fuel Oil Combustion

KAUST Repository

Han, Yunqing

2016-09-20

A new procedure to develop accurate lumped kinetic models for complex fuels is proposed, and applied to the experimental data of the heavy fuel oil measured by thermogravimetry. The new procedure is based on the pseudocomponents representing different reaction stages, which are determined by a systematic optimization process to ensure that the separation of different reaction stages with highest accuracy. The procedure is implemented and the model prediction was compared against that from a conventional method, yielding a significantly improved agreement with the experimental data. © 2016 American Chemical Society.

Kinetic Study on Catalytic Cracking of Rubber Seed (Hevea brasiliensis Oil to Liquid Fuels

Directory of Open Access Journals (Sweden)

Wara Dyah Pita Rengga

2015-03-01

Full Text Available Reaction kinetics of catalytic cracking of rubber seed oil to liquid fuels has been investigated. The reac-tion was performed with sulfuric acid as catalyst at temperatures of 350-450 oC and the ratio of oil-catalyst of 0-2 wt.% for 30-90 minutes. Kinetics was studied using the model of 6-lump parameters. The parameters were rubber seed oil, gasoline, kerosene, diesel, gas, and coke. Analysis of experimen-tal data using regression models to obtain reaction rate constants. Activation energies and pre-exponential factors were then calculated based on the Arrhenius equation. The simulation result illus-trated that the six-lump kinetic model can well predict the product yields of rubber seed oil catalytic cracking. The product has high selectivity for gasoline fraction as liquid fuel and the smallest amount of coke. The constant indicates that secondary reactions occurred in diesel products compared to gaso-line and kerosene. The predicted results indicate that catalytic cracking of rubber seed oil had better be conducted at 450 oC for 90 minutes using 0.5 wt.% catalyst. © 2015 BCREC UNDIP. All rights reservedReceived: 3rd December 2013; Revised: 5th December 2014; Accepted: 7th December 2014How to Cite: Rengga, W.D.P., Handayani, P.A., Kadarwati, S., Feinnudin, A.(2015. Kinetic Study on Catalytic Cracking of Rubber Seed (Hevea brasiliensis Oil  to Liquid Fuels. Bulletin of Chemical Reaction Engineering & Catalysis, 10 (1: 50-60. (doi:10.9767/bcrec.10.1.5852.50-60Permalink/DOI: http://dx.doi.org/10.9767/bcrec.10.1.5852.50-60

An Experimental and Chemical Kinetics Study of the Combustion of Syngas and High Hydrogen Content Fuels

Energy Technology Data Exchange (ETDEWEB)

Santoro, Robers [Pennsylvania State Univ., State College, PA (United States); Dryer, Frederick [Princeton Univ., NJ (United States); Ju, Yiguang [Princeton Univ., NJ (United States)

2013-09-30

An integrated and collaborative effort involving experiments and complementary chemical kinetic modeling investigated the effects of significant concentrations of water and CO2 and minor contaminant species (methane [CH4], ethane [C2H6], NOX, etc.) on the ignition and combustion of HHC fuels. The research effort specifically addressed broadening the experimental data base for ignition delay, burning rate, and oxidation kinetics at high pressures, and further refinement of chemical kinetic models so as to develop compositional specifications related to the above major and minor species. The foundation for the chemical kinetic modeling was the well validated mechanism for hydrogen and carbon monoxide developed over the last 25 years by Professor Frederick Dryer and his co-workers at Princeton University. This research furthered advance the understanding needed to develop practical guidelines for realistic composition limits and operating characteristics for HHC fuels. A suite of experiments was utilized that that involved a high-pressure laminar flow reactor, a pressure-release type high-pressure combustion chamber and a high-pressure turbulent flow reactor.

MASCOT2, a Lander to Characterize the Target of an Asteroid Kinetic Impactor Deflection Test (AIM) Mission

Science.gov (United States)

Biele, J.; Ulamec, S.; Krause, C.; Cozzoni, B.; Lange, C.; Grundmann, J. T.; Grimm, C.; Ho, T.-M.; Herique, A.; Plettemeier, D.; Grott, M.; Auster, H.-U.; Hercik, D.; Carnelli, I.; Galvez, A.; Philippe, C.; Küppers, M.; Grieger, B.; Gil Fernandez, J.; Grygorczuk, J.

2017-09-01

In the course of the AIDA/AIM mission studies [1,2] a lander, MASCOT2, has been studied to be deployed on the moon of the binary Near-Earth Asteroid system, (65803) Didymos. The AIDA technology demonstration mission, composed of a kinetic impactor, DART, and an observing spacecraft, AIM, has been designed to deliver vital data to determine the momentum transfer efficiency of the kinetic impact and key physical properties of the target asteroid. This will enable derivation of the impact response of the object as a function of its physical properties, a crucial quantitative point besides the qualitative proof that the asteroid has been deflected at all. A landed asset on the target asteroid greatly supports analyzing its dynamical state, mass, geophysical properties, surface and subsurface structure. The lander's main instrument is a bistatic, low frequency radar (LFR) [3a,b] to sound the interior structure of the asteroid. It is supported by a camera (MasCAM) [4], a radiometer (MARA)[5], an accelerometer (DACC [9]), and, optionally regarding the science case, also a magnetometer (MasMAG)[6].

High-resolution Statistics of Solar Wind Turbulence at Kinetic Scales Using the Magnetospheric Multiscale Mission

Energy Technology Data Exchange (ETDEWEB)

Chasapis, Alexandros; Matthaeus, W. H.; Parashar, T. N.; Maruca, B. A. [University of Delaware, Newark, DE (United States); Fuselier, S. A.; Burch, J. L. [Southwest Research Institute, San Antonio, TX (United States); Phan, T. D. [Space Sciences Laboratory, University of California, Berkeley, CA (United States); Moore, T. E.; Pollock, C. J.; Gershman, D. J. [NASA Goddard Space Flight Center, Greenbelt, MD (United States); Torbert, R. B. [University of New Hampshire, Durham, NH (United States); Russell, C. T.; Strangeway, R. J., E-mail: chasapis@udel.edu [University of California, Los Angeles, CA (United States)

2017-07-20

Using data from the Magnetospheric Multiscale (MMS) and Cluster missions obtained in the solar wind, we examine second-order and fourth-order structure functions at varying spatial lags normalized to ion inertial scales. The analysis includes direct two-spacecraft results and single-spacecraft results employing the familiar Taylor frozen-in flow approximation. Several familiar statistical results, including the spectral distribution of energy, and the sale-dependent kurtosis, are extended down to unprecedented spatial scales of ∼6 km, approaching electron scales. The Taylor approximation is also confirmed at those small scales, although small deviations are present in the kinetic range. The kurtosis is seen to attain very high values at sub-proton scales, supporting the previously reported suggestion that monofractal behavior may be due to high-frequency plasma waves at kinetic scales.

Numerical solution of the point reactor kinetics equations with fuel burn-up and temperature feedback

International Nuclear Information System (INIS)

Tashakor, S.; Jahanfarnia, G.; Hashemi-Tilehnoee, M.

2010-01-01

Point reactor kinetics equations are solved numerically using one group of delayed neutrons and with fuel burn-up and temperature feedback included. To calculate the fraction of one-group delayed neutrons, a group of differential equations are solved by an implicit time method. Using point reactor kinetics equations, changes in mean neutrons density, temperature, and reactivity are calculated in different times during the reactor operation. The variation of reactivity, temperature, and maximum power with time are compared with the predictions by other methods.

The assessment of the long-term evolution of the spent nuclear fuel matrix by kinetic, thermodynamic and spectroscopic studies of uranium minerals

International Nuclear Information System (INIS)

Bruno, J.; Casas, I.; Cera, E.; Ewing, R.C.; Finch, R.J.

1995-01-01

The long term behavior of spent nuclear fuel is discussed in the light of recent thermodynamic and kinetic data on mineralogical analogues related to the key phases in the oxidative alteration of uraninite. The implications for the safety assessment of a repository of the established oxidative alteration sequence of the spent fuel matrix are illustrated with Pagoda calculations. The application to the kinetic and thermodynamic data to source term calculations indicates that the appearance and duration of the U(VI) oxyhydroxide transient is critical for the stability of the fuel matrix

Development of multi-component diesel surrogate fuel models – Part I: Validation of reduced mechanisms of diesel fuel constituents in 0-D kinetic simulations

DEFF Research Database (Denmark)

Poon, Hiew Mun; Pang, Kar Mun; Ng, Hoon Kiat

2016-01-01

In the present work, development and validation of reduced chemical kinetic mechanisms for several different hydrocarbons are performed. These hydrocarbons are potential representative for practical diesel fuel constituents. n-Hexadecane (HXN), 2,2,4,4,6,8,8-heptamethylnonane (HMN), cyclohexane...... (CHX) and toluene are selected to represent straight-alkane, branched-alkane, cyclo-alkane and aromatic compounds in the diesel fuel. A five-stage chemical kinetic mechanism reduction scheme formulated in the previous work is applied to develop the reduced HMN and CHX models based on their respective...... detailed mechanisms. Alongside with the development of the reduced CHX model, a skeletal toluene sub-mechanism is constructed since the elementary reactions for toluene are subset of the detailed CHX mechanism. The final reduced HMN mechanism comprises 89 species with 319 elementary reactions, while...

Thermal analysis and kinetics of coal during oxy-fuel combustion

Science.gov (United States)

Kosowska-Golachowska, Monika

2017-08-01

The pyrolysis and oxy-fuel combustion characteristics of Polish bituminous coal were studied using non-isothermal thermogravimetric analysis. Pyrolysis tests showed that the mass loss profiles were almost similar up to 870°C in both N2 and CO2 atmospheres, while further mass loss occurred in CO2 atmosphere at higher temperatures due to char-CO2 gasification. Replacement of N2 in the combustion environment by CO2 delayed the combustion of bituminous coal. At elevated oxygen levels, TG/DTG profiles shifted through lower temperature zone, ignition and burnout temperatures decreased and mass loss rate significantly increased and complete combustion was achieved at lower temperatures and shorter times. Kinetic analysis for the tested coal was performed using Kissinger-Akahira-Sunose (KAS) method. The activation energies of bituminous coal combustion at the similar oxygen content in oxy-fuel with that of air were higher than that in air atmosphere. The results indicated that, with O2 concentration increasing, the activation energies decreased.

Implementation into a CFD code of neutron kinetics and fuel pin models for nuclear reactor transient analyses

International Nuclear Information System (INIS)

Chen Zhao; Chen, Xue-Nong; Rineiski, Andrei; Zhao Pengcheng; Chen Hongli

2014-01-01

Safety analysis is an important tool for justifying the safety of nuclear reactors. The traditional method for nuclear reactor safety analysis is performed by means of system codes, which use one-dimensional lumped-parameter method to model real reactor systems. However, there are many multi-dimensional thermal-hydraulic phenomena cannot be predicated using traditional one-dimensional system codes. This problem is extremely important for pool-type nuclear systems. Computational fluid dynamics (CFD) codes are powerful numerical simulation tools to solve multi-dimensional thermal-hydraulics problems, which are widely used in industrial applications for single phase flows. In order to use general CFD codes to solve nuclear reactor transient problems, some additional models beyond general ones are required. Neutron kinetics model for power calculation and fuel pin model for fuel pin temperature calculation are two important models of these additional models. The motivation of this work is to develop an advance numerical simulation method for nuclear reactor safety analysis by implementing neutron kinetics model and fuel pin model into general CFD codes. In this paper, the Point Kinetics Model (PKM) and Fuel Pin Model (FPM) are implemented into a general CFD code FLUENT. The improved FLUENT was called as FLUENT/PK. The mathematical models and implementary method of FLUENT/PK are descripted and two demonstration application cases, e.g. the unprotected transient overpower (UTOP) accident of a Liquid Metal cooled Fast Reactor (LMFR) and the unprotected beam overpower (UBOP) accident of an Accelerator Driven System (ADS), are presented. (author)

Experimental and numerical studies of burning velocities and kinetic modeling for practical and surrogate fuels

Science.gov (United States)

Zhao, Zhenwei

To help understand the fuel oxidation process in practical combustion environments, laminar flame speeds and high temperature chemical kinetic models were studied for several practical fuels and "surrogate" fuels, such as propane, dimethyl ether (DME), and primary reference fuel (PRF) mixtures, gasoline and n-decane. The PIV system developed for the present work is described. The general principles for PIV measurements are outlined and the specific considerations are also reported. Laminar flame speeds were determined for propane/air over a range of equivalence ratios at initial temperature of 298 K, 500 K and 650 K and atmospheric pressure. Several data sets for propane/air laminar flame speeds with N 2 dilution are also reported. These results are compared to the literature data collected at the same conditions. The propane flame speed is also numerically calculated with a detailed kinetic model and multi component diffusion, including Soret effects. This thesis also presents experimentally determined laminar flame speeds for primary reference fuel (PRF) mixtures of n-heptane/iso-octane and real gasoline fuel at different initial temperature and at atmospheric pressure. Nitrogen dilution effects on the laminar flame speed are also studied for selected equivalence ratios at the same conditions. A minimization of detailed kinetic model for PRF mixtures on laminar flame speed conditions was performed and the measured flame speeds were compared with numerical predictions using this model. The measured laminar flame speeds of n-decane/air mixtures at 500 K and at atmospheric pressure with and without dilution were determined. The measured flame speeds are significantly different that those predicted using existing published kinetic models, including a model validated previously against high temperature data from flow reactor, jet-stirred reactor, shock tube ignition delay, and burner stabilized flame experiments. A significant update of this model is described which

Final Report for NFE-07-00912: Development of Model Fuels Experimental Engine Data Base & Kinetic Modeling Parameter Sets

Energy Technology Data Exchange (ETDEWEB)

Bunting, Bruce G [ORNL

2012-10-01

The automotive and engine industries are in a period of very rapid change being driven by new emission standards, new types of after treatment, new combustion strategies, the introduction of new fuels, and drive for increased fuel economy and efficiency. The rapid pace of these changes has put more pressure on the need for modeling of engine combustion and performance, in order to shorten product design and introduction cycles. New combustion strategies include homogeneous charge compression ignition (HCCI), partial-premixed combustion compression ignition (PCCI), and dilute low temperature combustion which are being developed for lower emissions and improved fuel economy. New fuels include bio-fuels such as ethanol or bio-diesel, drop-in bio-derived fuels and those derived from new crude oil sources such as gas-to-liquids, coal-to-liquids, oil sands, oil shale, and wet natural gas. Kinetic modeling of the combustion process for these new combustion regimes and fuels is necessary in order to allow modeling and performance assessment for engine design purposes. In this research covered by this CRADA, ORNL developed and supplied experimental data related to engine performance with new fuels and new combustion strategies along with interpretation and analysis of such data and consulting to Reaction Design, Inc. (RD). RD performed additional analysis of this data in order to extract important parameters and to confirm engine and kinetic models. The data generated was generally published to make it available to the engine and automotive design communities and also to the Reaction Design Model Fuels Consortium (MFC).

LLNL Chemical Kinetics Modeling Group

Energy Technology Data Exchange (ETDEWEB)

Pitz, W J; Westbrook, C K; Mehl, M; Herbinet, O; Curran, H J; Silke, E J

2008-09-24

The LLNL chemical kinetics modeling group has been responsible for much progress in the development of chemical kinetic models for practical fuels. The group began its work in the early 1970s, developing chemical kinetic models for methane, ethane, ethanol and halogenated inhibitors. Most recently, it has been developing chemical kinetic models for large n-alkanes, cycloalkanes, hexenes, and large methyl esters. These component models are needed to represent gasoline, diesel, jet, and oil-sand-derived fuels.

Heavy fuel oil pyrolysis and combustion: kinetics and evolved gases investigated by TGA-FTIR

KAUST Repository

Abdul Jameel, Abdul Gani

2017-08-24

Heavy fuel oil (HFO) obtained from crude oil distillation is a widely used fuel in marine engines and power generation technologies. In the present study, the pyrolysis and combustion of a Saudi Arabian HFO in nitrogen and in air, respectively, were investigated using non-isothermal thermo-gravimetric analysis (TGA) coupled with a Fourier-transform infrared (FTIR) spectrometer. TG and DTG (differential thermo-gravimetry) were used for the kinetic analysis and to study the mass loss characteristics due to the thermal degradation of HFO at temperatures up to 1000°C and at various heating rates of 5, 10 and 20°C/min, in air and N2 atmospheres. FTIR analysis was then performed to study the composition of the evolved gases. The TG/DTG curves during HFO combustion show the presence of three distinct stages: the low temperature oxidation (LTO); fuel decomposition (FD); and high temperature oxidation (HTO) stages. The TG/DTG curves obtained during HFO pyrolysis show the presence of two devolatilization stages similar to that seen in the LTO stage of HFO combustion. Apart from this, the TG/DTG curves obtained during HFO combustion and pyrolysis differ significantly. Kinetic analysis was also performed using the distributed activation energy model, and the kinetic parameter (E) was determined for the different stages of HFO combustion and pyrolysis processes, yielding a good agreement with the measured TG profiles. FTIR analysis showed the signal of CO2 as approximately 50 times more compared to the other pollutant gases under combustion conditions. Under pyrolytic conditions, the signal intensity of alkane functional groups was the highest followed by alkenes. The TGA-FTIR results provide new insights into the overall HFO combustion processes, which can be used to improve combustor designs and control emissions.

Analysis of fluid fuel flow to the neutron kinetics on molten salt reactor FUJI-12

International Nuclear Information System (INIS)

Aji, Indarta Kuncoro; Waris, Abdul; Permana, Sidik

2015-01-01

Molten Salt Reactor is a reactor are operating with molten salt fuel flowing. This condition interpret that the neutron kinetics of this reactor is affected by the flow rate of the fuel. This research analyze effect by the alteration velocity of the fuel by MSR type Fuji-12, with fuel composition LiF-BeF 2 -ThF 4 - 233 UF 4 respectively 71.78%-16%-11.86%-0.36%. Calculation process in this study is performed numerically by SOR and finite difference method use C programming language. Data of reactivity, neutron flux, and the macroscopic fission cross section for calculation process obtain from SRAC-CITATION (Standard thermal Reactor Analysis Code) and JENDL-4.0 data library. SRAC system designed and developed by JAEA (Japan Atomic Energy Agency). This study aims to observe the effect of the velocity of fuel salt to the power generated from neutron precursors at fourth year of reactor operate (last critical condition) with number of multiplication effective; 1.0155

Electrocatalysis and kinetics of the direct alcohol fuel cells. DEMS and ac voltammetry studies

Energy Technology Data Exchange (ETDEWEB)

Othman Mostafa, Ehab Mostafa

2013-01-11

For the direct methanol fuel cell (DMFC) operating at low temperature, the main problem that arises at the anode is its poisoning (deactivation) due to the accumulation of the fuel adsorption product (CO{sub ad}) which can only be oxidized at high potentials (> 0.7 V). For low temperature direct ethanol fuel cells (DEFCs), the main problem that arises at the anode, beside its poisoning by ethanol adsorption products (CO{sub ad} and CH{sub x,ad}), is the incomplete ethanol oxidation due to the difficulty of (C-C) bond breaking. In the previous types of fuel cells, a sluggish oxygen reduction reaction (ORR) kinetics was observed at the cathode which results in a large voltage drop. Such behavior is due to strong inhibition of the cathodic ORR, resulting in high overpotentials and therefore, significant deterioration in the energy conversion efficiency of the cell. The slow kinetic behavior stems from the difficulty of (O=O) bond breaking. In order to model the conditions of continuous oxidation/reduction in a fuel cell, the continuous mass transfer to the electrode surface is necessary. Therefore, mass spectrometry and AC voltammetry measurements presented here were done using the thin layer flow through cell. This thesis aims at a determination of the rate constant of single reaction steps during the oxidation of CO, methanol and ethanol at different platinum surfaces. Towards that aim, I investigated the electrocatalytic oxidation and adsorption rate of methanol (chapter 3) and the electrocatalytic oxidation of ethanol (chapter 4) at different Pt surfaces, using DEMS. In chapter 5, the potential dependence of the bulk and adsorbed methanol oxidation reaction rate (presented by the apparent transfer coefficient, {alpha}') and the corresponding Tafel slope of the reaction have been determined under convection conditions using a potential modulation ac voltammetry technique. Finally, as an application of the method presented in chapter 5, my work in chapter 6

Analysis of fluid fuel flow to the neutron kinetics on molten salt reactor FUJI-12

Energy Technology Data Exchange (ETDEWEB)

Aji, Indarta Kuncoro, E-mail: indartaaji@s.itb.ac.id [Department of Physics, Faculty of Mathematics and Natural Sciences, Institut Teknologi Bandung, Jl. Ganesa 10 Bandung 40132 (Indonesia); Waris, Abdul, E-mail: awaris@fi.itb.ac.id; Permana, Sidik [Nuclear Physics & Biophysics Research Division, Department of Physics, Faculty of Mathematics and Natural Sciences, Institut Teknologi Bandung, Jl. Ganesa 10 Bandung 40132 (Indonesia)

2015-09-30

Molten Salt Reactor is a reactor are operating with molten salt fuel flowing. This condition interpret that the neutron kinetics of this reactor is affected by the flow rate of the fuel. This research analyze effect by the alteration velocity of the fuel by MSR type Fuji-12, with fuel composition LiF-BeF{sub 2}-ThF{sub 4}-{sup 233}UF{sub 4} respectively 71.78%-16%-11.86%-0.36%. Calculation process in this study is performed numerically by SOR and finite difference method use C programming language. Data of reactivity, neutron flux, and the macroscopic fission cross section for calculation process obtain from SRAC-CITATION (Standard thermal Reactor Analysis Code) and JENDL-4.0 data library. SRAC system designed and developed by JAEA (Japan Atomic Energy Agency). This study aims to observe the effect of the velocity of fuel salt to the power generated from neutron precursors at fourth year of reactor operate (last critical condition) with number of multiplication effective; 1.0155.

Reduced chemical kinetic model of detonation combustion of one- and multi-fuel gaseous mixtures with air

Science.gov (United States)

Fomin, P. A.

2018-03-01

Two-step approximate models of chemical kinetics of detonation combustion of (i) one hydrocarbon fuel CnHm (for example, methane, propane, cyclohexane etc.) and (ii) multi-fuel gaseous mixtures (∑aiCniHmi) (for example, mixture of methane and propane, synthesis gas, benzene and kerosene) are presented for the first time. The models can be used for any stoichiometry, including fuel/fuels-rich mixtures, when reaction products contain molecules of carbon. Owing to the simplicity and high accuracy, the models can be used in multi-dimensional numerical calculations of detonation waves in corresponding gaseous mixtures. The models are in consistent with the second law of thermodynamics and Le Chatelier's principle. Constants of the models have a clear physical meaning. The models can be used for calculation thermodynamic parameters of the mixture in a state of chemical equilibrium.

Proton-Exchange-Membrane Fuel Cell Powerplants Developed and Tested for Exploration Missions

Science.gov (United States)

Hoberecht, Mark A.; Pham, Nang T.

2005-01-01

Proton-exchange-membrane fuel cell (PEMFC) technology has received major attention for terrestrial applications, such as the automotive and residential markets, for the past 20 years. This attention has significantly advanced the maturity of the technology, resulting in ever more compact, efficient, reliable, and inexpensive PEMFC designs. In comparison to the terrestrial operating environment, the space operating environment is much more demanding. Microgravity to high-gravity loads and the need to use pure oxygen (rather than air) as the fuel cell oxidizer place more stringent demands on PEMFC technology. NASA and its partners from industry are leveraging terrestrial PEMFC advancements by conducting parallel space technology development for future exploration missions. A team from the NASA Glenn Research Center, NASA Johnson Space Center, and NASA Kennedy Space Center recently completed the first phase of a PEMFC powerplant development effort for exploration missions. The industry partners for this phase of the development effort were ElectroChem, Inc., and Teledyne Energy Systems, Inc. Under contract to Glenn, both of these industry partners successfully designed, fabricated, and tested a breadboard PEMFC powerplant in the 1- to 5-kW power range. These powerplants were based on existing company-proprietary fuel cell stack designs, combined with off-the-shelf components, which formed the balance of the powerplant design. Subsequent to the contractor development efforts, both powerplants were independently tested at Johnson to verify operational and performance characteristics, and to determine suitability for further technology development in the second phase of the NASA-led effort. Following the independent NASA testing, Teledyne Energy Systems, Inc., was selected to develop an engineering model PEMFC powerplant. This effort was initiated by the 2nd Generation Reusable Launch Vehicle (RLV) Program Office in 2001; it transitioned to the Next Generation Launch

Proton-Exchange-Membrane Fuel Cell Powerplants Developed and Tested for Exploration Missions

Science.gov (United States)

Hoberecht, Mark A.; Pham, Nang T.

2005-06-01

Proton-exchange-membrane fuel cell (PEMFC) technology has received major attention for terrestrial applications, such as the automotive and residential markets, for the past 20 years. This attention has significantly advanced the maturity of the technology, resulting in ever more compact, efficient, reliable, and inexpensive PEMFC designs. In comparison to the terrestrial operating environment, the space operating environment is much more demanding. Microgravity to high-gravity loads and the need to use pure oxygen (rather than air) as the fuel cell oxidizer place more stringent demands on PEMFC technology. NASA and its partners from industry are leveraging terrestrial PEMFC advancements by conducting parallel space technology development for future exploration missions. A team from the NASA Glenn Research Center, NASA Johnson Space Center, and NASA Kennedy Space Center recently completed the first phase of a PEMFC powerplant development effort for exploration missions. The industry partners for this phase of the development effort were ElectroChem, Inc., and Teledyne Energy Systems, Inc. Under contract to Glenn, both of these industry partners successfully designed, fabricated, and tested a breadboard PEMFC powerplant in the 1- to 5-kW power range. These powerplants were based on existing company-proprietary fuel cell stack designs, combined with off-the-shelf components, which formed the balance of the powerplant design. Subsequent to the contractor development efforts, both powerplants were independently tested at Johnson to verify operational and performance characteristics, and to determine suitability for further technology development in the second phase of the NASA-led effort. Following the independent NASA testing, Teledyne Energy Systems, Inc., was selected to develop an engineering model PEMFC powerplant. This effort was initiated by the 2nd Generation Reusable Launch Vehicle (RLV) Program Office in 2001; it transitioned to the Next Generation Launch

Detailed Reaction Kinetics for CFD Modeling of Nuclear Fuel Pellet Coating for High Temperature Gas-Cooled Reactors

International Nuclear Information System (INIS)

Battaglia, Francine

2008-01-01

The research project was related to the Advanced Fuel Cycle Initiative and was in direct alignment with advancing knowledge in the area of Nuclear Fuel Development related to the use of TRISO fuels for high-temperature reactors. The importance of properly coating nuclear fuel pellets received a renewed interest for the safe production of nuclear power to help meet the energy requirements of the United States. High-temperature gas-cooled nuclear reactors use fuel in the form of coated uranium particles, and it is the coating process that was of importance to this project. The coating process requires four coating layers to retain radioactive fission products from escaping into the environment. The first layer consists of porous carbon and serves as a buffer layer to attenuate the fission and accommodate the fuel kernel swelling. The second (inner) layer is of pyrocarbon and provides protection from fission products and supports the third layer, which is silicon carbide. The final (outer) layer is also pyrocarbon and provides a bonding surface and protective barrier for the entire pellet. The coating procedures for the silicon carbide and the outer pyrocarbon layers require knowledge of the detailed kinetics of the reaction processes in the gas phase and at the surfaces where the particles interact with the reactor walls. The intent of this project was to acquire detailed information on the reaction kinetics for the chemical vapor deposition (CVD) of carbon and silicon carbine on uranium fuel pellets, including the location of transition state structures, evaluation of the associated activation energies, and the use of these activation energies in the prediction of reaction rate constants. After the detailed reaction kinetics were determined, the reactions were implemented and tested in a computational fluid dynamics model, MFIX. The intention was to find a reduced mechanism set to reduce the computational time for a simulation, while still providing accurate results

Effect of Utilization of Silicide Fuel with the Density 4.8 gU/cc on the Kinetic Parameters of RSG-GAS Reactor

International Nuclear Information System (INIS)

Setiyanto; Sembiring, Tagor M.; Pinem, Surian

2007-01-01

Presently, the RSG-GAS reactor using silicide fuel element of 2.96 gU/cc. For increasing reactor operation time, its planning to change to higher density fuel. The kinetic calculation of silicide core with density 4.8 gU/cc has been carried out, since it has an influence on the reactor operation safety. The calculated kinetic parameters are the effective delayed neutron fraction, the delayed neutron decay constant, prompt neutron lifetime and feedback reactivity coefficient very important for reactor operation safety. the calculation is performed in 2-dimensional neutron diffusion-perturbation method using modified Batan-2DIFF code. The calculation showed that the effective delayed neutron fraction is 7. 03256x10 -03 , total delay neutron time constant is 7.85820x10 -02 s -1 and the prompt neutron lifetime is 55.4900 μs. The result of prompt neutron lifetime smaller 10 % compare with silicide fuel of 4.8 gU/cc. The calculated results showed that all of the feedback reactivity coefficient silicide core 4.8 gU/cc is negative. Totally, the feedback reactivity coefficient of silicide fuel of 4.8 gU/cc is 10% less than that of silicide fuel of 2.96 gU/cc. The results shown that kinetic parameters result decrease compared with the silicide core with density 2.96 gU/cc, but no significant influence in the RSG-GAS reactor operation. (author)

Numerical studies of spray combustion processes of palm oil biodiesel and diesel fuels using reduced chemical kinetic mechanisms

KAUST Repository

Kuti, Olawole; Sarathy, Mani; Nishida, Keiya; Roberts, William L.

2014-01-01

Spray combustion processes of palm oil biodiesel (PO) and conventional diesel fuels were simulated using the CONVERGE CFD code. Thermochemical and reaction kinetic data (115 species and 460 reactions) by Luo et al. (2012) and Lu et al. (2009) (68

Fuel performance of DOE fuels in water storage

International Nuclear Information System (INIS)

Hoskins, A.P.; Scott, J.G.; Shelton-Davis, C.V.; McDannel, G.E.

1993-01-01

Westinghouse Idaho Nuclear Company operates the Idaho Chemical Processing Plant (ICPP) at the Idaho National Engineering Laboratory. In April of 1992, the U.S. Department of Energy (DOE) decided to end the fuel reprocessing mission at ICPP. Fuel performance in storage received increased emphasis as the fuel now needs to be stored until final dispositioning is defined and implemented. Fuels are stored in four main areas: an original underwater storage facility, a modern underwater storage facility, and two dry fuel storage facilities. As a result of the reactor research mission of the DOE and predecessor agencies, the Energy Research and Development Administration and the Atomic Energy Commission, many types of nuclear fuel have been developed, used, and assigned to storage at the ICPP. Fuel clad with stainless steel, zirconium, aluminum, and graphite are represented. Fuel matrices include uranium oxide, hydride, carbide, metal, and alloy fuels, resulting in 55 different fuel types in storage. Also included in the fuel storage inventory is canned scrap material

Kinetic Re-Evaluation of Fuel Neutralization by AKGA

Science.gov (United States)

Oropeza Cristina; Kosiba, Mike; Davis, Chuck

2010-01-01

Baseline characterization testing previously identified alpha-ketoglutaric acid (AKGA) cis a potential alternative to the current standard hydrazine (HZ) family fuel neutralization techniques in use at Kennedy Space Center (KSC). Thus far, the reagent shows promise for use in hardware decontamination operations and as a drop-in replacement for the scrubber liquor currently used in KSC four tower vapor scrubbers. Implementation of AKGA could improve process safety and reduce or eliminate generation of hydrazine-Iaden waste streams. This paper focuses on evaluation of the kinetics of these decontamination reactions in solution. Pseudo first order reaction rate constants with respect to the pyridazine products (6-oxo-4,5-dihydro-1H-pyridazine-3-carboxylic acid, (PCA) and 1-methyl-6-oxo-4,5-dihydro-pyridazine-3-carboxylic acid (mPCA)) in the presence of excess AKGA were determined by monitoring product formation using a ultra-violet visible absorption spectroscopy method. The results are presented here in comparison to previous data obtained by monitoring reactant depletion by gas chromatography with nitrogen phosphorus detector (GC-NPD).

Oxygen reduction kinetics on graphite cathodes in sediment microbial fuel cells.

Science.gov (United States)

Renslow, Ryan; Donovan, Conrad; Shim, Matthew; Babauta, Jerome; Nannapaneni, Srilekha; Schenk, James; Beyenal, Haluk

2011-12-28

Sediment microbial fuel cells (SMFCs) have been used as renewable power sources for sensors in fresh and ocean waters. Organic compounds at the anode drive anodic reactions, while oxygen drives cathodic reactions. An understanding of oxygen reduction kinetics and the factors that determine graphite cathode performance is needed to predict cathodic current and potential losses, and eventually to estimate the power production of SMFCs. Our goals were to (1) experimentally quantify the dependence of oxygen reduction kinetics on temperature, electrode potential, and dissolved oxygen concentration for the graphite cathodes of SMFCs and (2) develop a mechanistic model. To accomplish this, we monitored current on polarized cathodes in river and ocean SMFCs. We found that (1) after oxygen reduction is initiated, the current density is linearly dependent on polarization potential for both SMFC types; (2) current density magnitude increases linearly with temperature in river SMFCs but remains constant with temperature in ocean SMFCs; (3) the standard heterogeneous rate constant controls the current density temperature dependence; (4) river and ocean SMFC graphite cathodes have large potential losses, estimated by the model to be 470 mV and 614 mV, respectively; and (5) the electrochemical potential available at the cathode is the primary factor controlling reduction kinetic rates. The mechanistic model based on thermodynamic and electrochemical principles successfully fit and predicted the data. The data, experimental system, and model can be used in future studies to guide SMFC design and deployment, assess SMFC current production, test cathode material performance, and predict cathode contamination.

Mission aware energy saving strategies for Army ground vehicles

Science.gov (United States)

Dattathreya, Macam S.

Fuel energy is a basic necessity for this planet and the modern technology to perform many activities on earth. On the other hand, quadrupled automotive vehicle usage by the commercial industry and military has increased fuel consumption. Military readiness of Army ground vehicles is very important for a country to protect its people and resources. Fuel energy is a major requirement for Army ground vehicles. According to a report, a department of defense has spent nearly $13.6 billion on fuel and electricity to conduct ground missions. On the contrary, energy availability on this plant is slowly decreasing. Therefore, saving energy in Army ground vehicles is very important. Army ground vehicles are embedded with numerous electronic systems to conduct missions such as silent and normal stationary surveillance missions. Increasing electrical energy consumption of these systems is influencing higher fuel consumption of the vehicle. To save energy, the vehicles can use any of the existing techniques, but they require complex, expensive, and time consuming implementations. Therefore, cheaper and simpler approaches are required. In addition, the solutions have to save energy according to mission needs and also overcome size and weight constraints of the vehicle. Existing research in the current literature do not have any mission aware approaches to save energy. This dissertation research proposes mission aware online energy saving strategies for stationary Army ground vehicles to save energy as well as to meet the electrical needs of the vehicle during surveillance missions. The research also proposes theoretical models of surveillance missions, fuzzy logic models of engine and alternator efficiency data, and fuzzy logic algorithms. Based on these models, two energy saving strategies are proposed for silent and normal surveillance type of missions. During silent mission, the engine is on and batteries power the systems. During normal surveillance mission, the engine is

Business analysis: The commercial mission of the International Asteroid Mission

Science.gov (United States)

The mission of the International Asteroid Mission (IAM) is providing asteroidal resources to support activities in space. The short term goal is to initiate IAM by mining a near-Earth, hydrous carbonaceous chondrite asteroid to service the nearer-term market of providing cryogenic rocket fuel in low lunar orbit (LLO). The IAM will develop and contract for the building of the transportation vehicles and equipment necessary for this undertaking. The long-term goal is to expand operations by exploiting asteroids in other manners, as these options become commercially viable. The primary business issues are what revenue can be generated from the baseline mission, how much will the mission cost, and how funding for this mission can be raised. These issues are addressed.

A computational methodology for formulating gasoline surrogate fuels with accurate physical and chemical kinetic properties

KAUST Repository

Ahmed, Ahfaz

2015-03-01

Gasoline is the most widely used fuel for light duty automobile transportation, but its molecular complexity makes it intractable to experimentally and computationally study the fundamental combustion properties. Therefore, surrogate fuels with a simpler molecular composition that represent real fuel behavior in one or more aspects are needed to enable repeatable experimental and computational combustion investigations. This study presents a novel computational methodology for formulating surrogates for FACE (fuels for advanced combustion engines) gasolines A and C by combining regression modeling with physical and chemical kinetics simulations. The computational methodology integrates simulation tools executed across different software platforms. Initially, the palette of surrogate species and carbon types for the target fuels were determined from a detailed hydrocarbon analysis (DHA). A regression algorithm implemented in MATLAB was linked to REFPROP for simulation of distillation curves and calculation of physical properties of surrogate compositions. The MATLAB code generates a surrogate composition at each iteration, which is then used to automatically generate CHEMKIN input files that are submitted to homogeneous batch reactor simulations for prediction of research octane number (RON). The regression algorithm determines the optimal surrogate composition to match the fuel properties of FACE A and C gasoline, specifically hydrogen/carbon (H/C) ratio, density, distillation characteristics, carbon types, and RON. The optimal surrogate fuel compositions obtained using the present computational approach was compared to the real fuel properties, as well as with surrogate compositions available in the literature. Experiments were conducted within a Cooperative Fuels Research (CFR) engine operating under controlled autoignition (CAI) mode to compare the formulated surrogates against the real fuels. Carbon monoxide measurements indicated that the proposed surrogates

Use of Measured Species Class Concentrations with Chemical Kinetic Modeling for the Prediction of Autoxidation and Deposition of Jet Fuels (Postprint)

National Research Council Canada - National Science Library

Kuprowicz, Nicholas J; Zabarnick, Steven; West, Zachary J; Ervin, Jamie S

2007-01-01

.... In the present work, a chemical kinetic mechanism developed previously is refined to include the roles of key fuel species classes, such as phenols, reactive sulfur species, dissolved metals, and hydroperoxides...

Optimization of vehicle weight for Mars excursion missions

Science.gov (United States)

Ferebee, Melvin J., Jr.

1991-01-01

The excursion class mission to Mars is defined as a mission with one year durations coupled with a stay time of up to 30 days. The fuel budget for such a mission is investigated. The overall figure of merit in such an assessment is the vehicle weight ratio, the ratio between the wet vehicle weight to the dry vehicle weight. It is necessary to minimize the overall fuel budget for the mission in order to maximize the benefits that could be obtained by sending humans to Mars. Assumptions used in the analysis are: each mission will depart and terminate in low-earth-orbit (LEO) (500 km circular) and the maximum stay time at Mars is 30 days. The maximum mission duration is one year (355-375 days). The mass returned to LEO is 135,000 kg, the dropoff mass left at Mars is 168,000 kg. Three propulsive techniques for atmospheric interface are investigated: aerobraking, all-chemical propulsion, and nuclear thermal propulsion. By defining the fuel requirements, the space transfer vehicle's configuration is defined.

Communication received on 12 September 2006 from the Permanent Mission of Japan to the Agency concerning arrangements for the assurance of nuclear fuel supply

International Nuclear Information System (INIS)

2006-01-01

The Secretariat has received on 12 September 2006 a communication from the Permanent Mission of Japan attaching a document entitled 'Japan's Proposal: IAEA Standby Arrangements System for the Assurance of Nuclear Fuel Supply'. As requested by the Permanent Mission, the text of the attachment is herewith reproduced for the information of Member States

A comprehensive detailed kinetic mechanism for the simulation of transportation fuels

KAUST Repository

Mehl, Marco; Zhang, Kuiwen; Wagnon, Scott; Kukkadapu, Goutham; Westbrook, Charles K.; Pitz, William J.; Zhang, Yinjia; Curran, Henry J.; Al Rachidi, Mariam; Atef, Nour; Sarathy, Mani; Ahmed, Ahfaz

2017-01-01

This work presents a recently compiled comprehensive model for transportations fuels resulting from the collaboration of three research groups: LLNL, NUI Galway and KAUST. In the past 5 years new fundamental calculations led to significant improvements in the fidelity of detailed kinetic models of important surrogate components (e.g. n-heptane, iso-octane, toluene…) improving predictions of the combustion behavior of pure components and mixtures. By extending the newly adopted reaction rate rules, mechanisms for components that were not included in the previous LLNL gasoline and diesel surrogate mechanisms were developed (e.g. polyalkylated aromatics, cycloalkanes, components from bio-logical sources…). The major features of this updated and extended model are presented together with validation comparisons, examples of applications and future directions.

A comprehensive detailed kinetic mechanism for the simulation of transportation fuels

KAUST Repository

Mehl, Marco

2017-02-27

This work presents a recently compiled comprehensive model for transportations fuels resulting from the collaboration of three research groups: LLNL, NUI Galway and KAUST. In the past 5 years new fundamental calculations led to significant improvements in the fidelity of detailed kinetic models of important surrogate components (e.g. n-heptane, iso-octane, toluene…) improving predictions of the combustion behavior of pure components and mixtures. By extending the newly adopted reaction rate rules, mechanisms for components that were not included in the previous LLNL gasoline and diesel surrogate mechanisms were developed (e.g. polyalkylated aromatics, cycloalkanes, components from bio-logical sources…). The major features of this updated and extended model are presented together with validation comparisons, examples of applications and future directions.

308 Building deactivation mission analysis report

International Nuclear Information System (INIS)

Lund, D.P.

1995-01-01

This report presents the results of the 308 Building (Fuels Development Laboratory) Deactivation Project mission analysis. Hanford systems engineering (SE) procedures call for a mission analysis. The mission analysis is an important first step in the SE process. The functions and requirements to successfully accomplish this mission, the selected alternatives and products will later be defined using the SE process

309 Building deactivation mission analysis report

International Nuclear Information System (INIS)

Lund, D.P.

1995-01-01

This report presents the results of the 309 Building (Plutonium Fuels Utilization Program) Deactivation Project mission analysis. Hanford systems engineering (SE) procedures call for a mission analysis. The mission analysis is an important first step in the SE process. The functions and requirements to successfully accomplish this mission, the selected alternatives and products will later be defined using the SE process

Kinetics of in situ combustion. SUPRI TR 91

Energy Technology Data Exchange (ETDEWEB)

Mamora, D.D.; Ramey, H.J. Jr.; Brigham, W.E.; Castanier, L.M.

1993-07-01

Oxidation kinetic experiments with various crude oil types show two reaction peaks at about 250{degree}C (482{degree}F) and 400{degree}C (725{degree}F). These experiments lead to the conclusion that the fuel during high temperature oxidation is an oxygenated hydrocarbon. A new oxidation reaction model has been developed which includes two partially-overlapping reactions: namely, low-temperature oxidation followed by high-temperature oxidation. For the fuel oxidation reaction, the new model includes the effects of sand grain size and the atomic hydrogen-carbon (H/C) and oxygen-carbon (O/C) ratios of the fuel. Results based on the new model are in good agreement with the experimental data. Methods have been developed to calculate the atomic H/C and O/C ratios. These methods consider the oxygen in the oxygenated fuel, and enable a direct comparison of the atomic H/C ratios obtained from kinetic and combustion tube experiments. The finding that the fuel in kinetic tube experiments is an oxygenated hydrocarbon indicates that oxidation reactions are different in kinetic and combustion tube experiments. A new experimental technique or method of analysis will be required to obtain kinetic parameters for oxidation reactions encountered in combustion tube experiments and field operations.

LLNL Site plan for a MOX fuel lead assembly mission in support of surplus plutonium disposition

Energy Technology Data Exchange (ETDEWEB)

Bronson, M.C.

1997-10-01

The principal facilities that LLNL would use to support a MOX Fuel Lead Assembly Mission are Building 332 and Building 334. Both of these buildings are within the security boundary known as the LLNL Superblock. Building 332 is the LLNL Plutonium Facility. As an operational plutonium facility, it has all the infrastructure and support services required for plutonium operations. The LLNL Plutonium Facility routinely handles kilogram quantities of plutonium and uranium. Currently, the building is limited to a plutonium inventory of 700 kilograms and a uranium inventory of 300 kilograms. Process rooms (excluding the vaults) are limited to an inventory of 20 kilograms per room. Ongoing operations include: receiving SSTS, material receipt, storage, metal machining and casting, welding, metal-to-oxide conversion, purification, molten salt operations, chlorination, oxide calcination, cold pressing and sintering, vitrification, encapsulation, chemical analysis, metallography and microprobe analysis, waste material processing, material accountability measurements, packaging, and material shipping. Building 334 is the Hardened Engineering Test Building. This building supports environmental and radiation measurements on encapsulated plutonium and uranium components. Other existing facilities that would be used to support a MOX Fuel Lead Assembly Mission include Building 335 for hardware receiving and storage and TRU and LLW waste storage and shipping facilities, and Building 331 or Building 241 for storage of depleted uranium.

LLNL Site plan for a MOX fuel lead assembly mission in support of surplus plutonium disposition

International Nuclear Information System (INIS)

Bronson, M.C.

1997-01-01

The principal facilities that LLNL would use to support a MOX Fuel Lead Assembly Mission are Building 332 and Building 334. Both of these buildings are within the security boundary known as the LLNL Superblock. Building 332 is the LLNL Plutonium Facility. As an operational plutonium facility, it has all the infrastructure and support services required for plutonium operations. The LLNL Plutonium Facility routinely handles kilogram quantities of plutonium and uranium. Currently, the building is limited to a plutonium inventory of 700 kilograms and a uranium inventory of 300 kilograms. Process rooms (excluding the vaults) are limited to an inventory of 20 kilograms per room. Ongoing operations include: receiving SSTS, material receipt, storage, metal machining and casting, welding, metal-to-oxide conversion, purification, molten salt operations, chlorination, oxide calcination, cold pressing and sintering, vitrification, encapsulation, chemical analysis, metallography and microprobe analysis, waste material processing, material accountability measurements, packaging, and material shipping. Building 334 is the Hardened Engineering Test Building. This building supports environmental and radiation measurements on encapsulated plutonium and uranium components. Other existing facilities that would be used to support a MOX Fuel Lead Assembly Mission include Building 335 for hardware receiving and storage and TRU and LLW waste storage and shipping facilities, and Building 331 or Building 241 for storage of depleted uranium

Kinetic Model Development for the Combustion of Particulate Matter from Conventional and Soy Methyl Ester Diesel Fuels

Energy Technology Data Exchange (ETDEWEB)

Strzelec, Andrea [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

2009-12-01

The primary objective of this research has been to investigate how the oxidation characteristics of diesel particulate matter (PM) are affected by blending soy-based biodiesel fuel with conventional ultra low sulfur diesel (ULSD) fuel. PM produced in a light duty engine from different biodiesel-conventional fuel blends was subjected to a range of physical and chemical measurements in order to better understand the mechanisms by which fuel-related changes to oxidation reactivity are brought about. These observations were then incorporated into a kinetic model to predict PM oxidation. Nanostructure of the fixed carbon was investigated by HR-TEM and showed that particulates from biodiesel had a more open structure than particulates generated from conventional diesel fuel, which was confirmed by BET surface area measurements. Surface area evolution with extent of oxidation reaction was measured for PM from ULSD and biodiesel. Biodiesel particulate has a significantly larger surface area for the first 40% of conversion, at which point the samples become quite similar. Oxidation characteristics of nascent PM and the fixed carbon portion were measured by temperature programmed oxidation (TPO) and it was noted that increased biodiesel blending lowered the light-off temperature as well as the temperature where the peak rate of oxidation occurred. A shift in the oxidation profiles of all fuels was seen when the mobile carbon fraction was removed, leaving only the fixed carbon, however the trend in temperature advantage of the biofuel blending remained. The mobile carbon fraction was measured by temperature programmed desorption found to generally increase with increasing biodiesel blend level. The relative change in the light-off temperatures for the nascent and fixed carbon samples was found to be related to the fraction of mobile carbon. Effective Arrhenius parameters for fixed carbon oxidation were directly measured with isothermal, differential oxidation experiments

On direct internal methane steam reforming kinetics in operating solid oxide fuel cells with nickel-ceria anodes

Science.gov (United States)

Thallam Thattai, A.; van Biert, L.; Aravind, P. V.

2017-12-01

Major operating challenges remain to safely operate methane fuelled solid oxide fuel cells due to undesirable temperature gradients across the porous anode and carbon deposition. This article presents an experimental study on methane steam reforming (MSR) global kinetics for single operating SOFCs with Ni-GDC (gadolinium doped ceria) anodes for low steam to carbon (S/C) ratios and moderate current densities. The study points out the hitherto insufficient research on MSR global and intrinsic kinetics for operating SOFCs with complete Ni-ceria anodes. Further, it emphasizes the need to develop readily applicable global kinetic models as a subsequent step from previously reported state-of-art and complex intrinsic models. Two rate expressions of the Power law (PL) and Langmuir-Hinshelwood (LH) type have been compared and based on the analysis, limitations of using previously proposed rate expressions for Ni catalytic beds to study MSR kinetics for complete cermet anodes have been identified. Firstly, it has been shown that methane reforming on metallic (Ni) current collectors may not be always negligible, contrary to literature reports. Both PL and LH kinetic models predict significantly different local MSR reaction rate and species partial pressure distributions along the normalized reactor length, indicating a strong need for further experimental verifications.

Real Mission Profile Based Lifetime Estimation of Fuel-cell Power Converter

DEFF Research Database (Denmark)

Zhou, Dao; Wang, Huai; Blaabjerg, Frede

2016-01-01

. This paper describes a lifetime prediction method for the power semiconductors used in the power conditioning of a fuel cell based backup system, considering both the long-term standby mode and active operation mode. The annual ambient temperature profile is taken into account to estimate its impact...... on the degradation of MOSFETs during the standby mode. At the presence of power outages, the backup system is activated into the operation mode and the MOSFETs withstand additional thermal stresses due to power losses. A study case of a 1 kW backup system is presented with two annual mission profiles in Denmark...... and India, respectively. The ambient temperature, occurrence frequency of power outages, active operation time and power levels are considered for the lifetime prediction of the applied MOSFETs. Comparisons of the accumulated lifetime consumptions are performed between standby mode and operation mode...

Neutron kinetics of fluid-fuel systems by the quasi-static method

International Nuclear Information System (INIS)

Dulla, S.; Ravetto, P.; Rostagno, M.M.

2004-01-01

The quasi-static method for the neutron kinetics of nuclear reactors is generalized for application to neutron multiplying systems fueled by a fluid multiplying material, typically a mixture of fissile molten salts. The method is derived by the application of factorization formulae for both the neutron density and the delayed precursor concentrations and the projection of the balance equations upon a weighting function. A physically meaningful weight can be assumed as the solution of the adjoint model, which is constructed for the situation considered, including delayed neutrons. The quasi-static scheme is then applied to calculations of some transients for a typical configuration of a molten-salt reactor, in a multigroup diffusion model with a one-dimensional slug-flow velocity field. The physical features associated to the motion of the fissile material are highlighted

Pyrolysis and oxy-fuel combustion characteristics and kinetics of petrochemical wastewater sludge using thermogravimetric analysis.

Science.gov (United States)

Chen, Jianbiao; Mu, Lin; Cai, Jingcheng; Yao, Pikai; Song, Xigeng; Yin, Hongchao; Li, Aimin

2015-12-01

The pyrolysis and oxy-fuel combustion characteristics of petrochemical wastewater sludge (PS) were studied in air (O2/N2) and oxy-fuel (O2/CO2) atmospheres using non-isothermal thermogravimetric analysis (TGA). Pyrolysis experiments showed that the weight loss profiles were almost similar up to 1050K in both N2 and CO2 atmospheres, while further weight loss took place in CO2 atmosphere at higher temperatures due to char-CO2 gasification. Compared with 20%O2/80%N2, the drying and devolatilization stage of PS were delayed in 20%O2/80%CO2 due to the differences in properties of the diluting gases. In oxy-fuel combustion experiments, with O2 concentration increasing, characteristic temperatures decreased, while characteristic combustion rates and combustion performance indexes increased. Kinetic analysis of PS decomposition under various atmospheres was performed using Coats-Redfern approach. The results indicated that, with O2 concentration increasing, the activation energies of Step 1 almost kept constant, while the values of subsequent three steps increased. Copyright © 2015 Elsevier Ltd. All rights reserved.

Development of a kinetic model for the dissolution of the UO2 spent nuclear fuel. Application of the model to the minor radionuclides

International Nuclear Information System (INIS)

Bruno, J.; Cera, E.; Duro, L.; Pon, J.; Pablo, J. de; Eriksen, Trygve

1998-05-01

A kinetic model has been developed in order to explain the evolution of the spent fuel matrix/groundwater system. Mass balance equations have been used to follow the evolution of the system with time. The model has been calibrated by using experimental dissolution data from spent fuel leaching tests from Studsvik and KTH and from synthetic unirradiated UO 2 dissolution tests from VTT. The results of the testing exercise indicate that the combination of mass balance equations together with the kinetic rate laws constitute a useful tool to model and explain experimental dissolution data available in the literature for UO 2 solid phases, including uraninites, unirradiated UO 2 and spent fuel. Although the key processes are well identified and understood, there are still some remaining uncertainties concerning some of the critical parameters of the model. This is particularly true for the density of UO 2 sites prone to oxidation and the rates and mechanisms of the hydrogen peroxide and the combined oxygen and bicarbonate promoted dissolution of UO 2 for oxidant concentration ranges relevant to the spent fuel disposal system. The mass balance kinetic model developed has been extended to minor radionuclides contained in the matrix, i.e. Pu, Tc and Sr. In the case of Pu, the model presented reproduces the behaviour of this critical radionuclide even at early contact times. As it would be expected, Tc seems to follow a different mechanism for its release with respect to the UO 2 matrix dissolution, which is probably linked to the rate of oxidation of Tc metallic inclusions in the fuel. A co- dissolution process of Sr with the UO 2 matrix reproduces the long term dissolution behaviour of this radionuclide, better than the initial Sr release rates

IAEA expert review mission completes assessment of fuel cleaning incident at Paks Nuclear Power Plant

International Nuclear Information System (INIS)

2003-01-01

Full text: The IAEA today completed its expert review mission to investigate the 10 April fuel cleaning incident at the Paks nuclear power plant in Hungary. The mission was requested by the Hungarian Government to provide an independent assessment of the causes and actions taken by the plant and Hungarian authorities. The team was composed of nuclear and radiation experts from the IAEA, Austria, Canada, Finland, Slovakia, the United Kingdom and the United States. In a press conference, team leader Miroslav Lipar highlighted the team's findings in five areas: On management, the team concluded that the Hungarian Atomic Energy Authority and Paks are committed to improving the safety of the plant. They noted that as a result of steam generator decontamination in previous years, deposits became attached to the fuel assemblies. A decision was made to clean the fuel and contract an outside company to develop and operate a fuel cleaning process. The team found that the design and operation of the fuel cleaning tank and system was not accomplished in the manner prescribed by the IAEA Safety Standards. Neither the Hungarian Atomic Energy Authority nor Paks used conservative decision-making in their safety assessments for this unproven fuel cleaning system. The team determined that there was an over-reliance on the contractor that had been selected for the design, management and operation of the fuel cleaning system. Time pressure related to a prescribed fuel outage schedule, combined with confidence generated by previous successful fuel cleaning operations, contributed to a weak assessment of a new design and operation, which involved fuel directly removed from the reactor following a planned shutdown. On regulatory oversight, the IAEA team concluded that the Hungarian Atomic Energy Authority underestimated the safety significance of the proposed designs for the fuel cleaning system, which resulted in a less than rigorous review and assessment than should have been necessary

Computer-Aided Construction of Chemical Kinetic Models

Energy Technology Data Exchange (ETDEWEB)

Green, William H. [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)

2014-12-31

The combustion chemistry of even simple fuels can be extremely complex, involving hundreds or thousands of kinetically significant species. The most reasonable way to deal with this complexity is to use a computer not only to numerically solve the kinetic model, but also to construct the kinetic model in the first place. Because these large models contain so many numerical parameters (e.g. rate coefficients, thermochemistry) one never has sufficient data to uniquely determine them all experimentally. Instead one must work in “predictive” mode, using theoretical rather than experimental values for many of the numbers in the model, and as appropriate refining the most sensitive numbers through experiments. Predictive chemical kinetics is exactly what is needed for computer-aided design of combustion systems based on proposed alternative fuels, particularly for early assessment of the value and viability of proposed new fuels before those fuels are commercially available. This project was aimed at making accurate predictive chemical kinetics practical; this is a challenging goal which requires a range of science advances. The project spanned a wide range from quantum chemical calculations on individual molecules and elementary-step reactions, through the development of improved rate/thermo calculation procedures, the creation of algorithms and software for constructing and solving kinetic simulations, the invention of methods for model-reduction while maintaining error control, and finally comparisons with experiment. Many of the parameters in the models were derived from quantum chemistry calculations, and the models were compared with experimental data measured in our lab or in collaboration with others.

Solar-Electrochemical Power System for a Mars Mission

Science.gov (United States)

Withrow, Colleen A.; Morales, Nelson

1994-01-01

This report documents a sizing study of a variety of solar electrochemical power systems for the intercenter NASA study known as 'Mars Exploration Reference Mission'. Power systems are characterized for a variety of rovers, habitation modules, and space transport vehicles based on requirements derived from the reference mission. The mission features a six-person crew living on Mars for 500 days. Mission power requirements range from 4 kWe to 120 kWe. Primary hydrogen and oxygen fuel cells, regenerative hydrogen and oxygen fuel cells, sodium sulfur batteries advanced photovoltaic solar arrays of gallium arsenide on germanium with tracking and nontracking mechanisms, and tent solar arrays of gallium arsenide on germanium are evaluated and compared.

Numerical studies of spray combustion processes of palm oil biodiesel and diesel fuels using reduced chemical kinetic mechanisms

KAUST Repository

Kuti, Olawole

2014-04-01

Spray combustion processes of palm oil biodiesel (PO) and conventional diesel fuels were simulated using the CONVERGE CFD code. Thermochemical and reaction kinetic data (115 species and 460 reactions) by Luo et al. (2012) and Lu et al. (2009) (68 species and 283 reactions) were implemented in the CONVERGE CFD to simulate the spray and combustion processes of the two fuels. Tetradecane (C14H30) and n- heptane (C7H 16) were used as surrogates for diesel. For the palm biodiesel, the mixture of methyl decanoate (C11H20O2), methyl-9-decenoate (C11H19O2) and n-heptane was used as surrogate. The palm biodiesel surrogates were combined in proportions based on the previous GC-MS results for the five major biodiesel components namely methyl palmitate, methyl stearate, methyl oleate, methyl linoleate and methyl linolenate. The Favre-Averaged Navier Stokes based simulation using the renormalization group (RNG) k-ε turbulent model was implemented in the numerical calculations of the spray formation processes while the SAGE chemical kinetic solver is used for the detailed kinetic modeling. The SAGE chemical kinetic solver is directly coupled with the gas phase calculations by renormalization group (RNG) k-ε turbulent model using a well-stirred reactor model. Validations of the spray liquid length, ignition delay and flame lift-off length data were performed against previous experimental results. The simulated liquid length, ignition delay and flame lift-off length were validated at an ambient density of 15kg/m3, and injection pressure conditions of 100, 200 and 300 MPa were utilized. The predicted liquid length, ignition delay and flame lift-off length agree with the trends obtained in the experimental data at all injection conditions. Copyright © 2014 SAE International.

Chemical Kinetic Modeling of 2-Methylhexane Combustion

KAUST Repository

Mohamed, Samah Y.

2015-03-30

Accurate chemical kinetic combustion models of lightly branched alkanes (e.g., 2-methylalkanes) are important for investigating the combustion behavior of diesel, gasoline, and aviation fuels. Improving the fidelity of existing kinetic models is a necessity, as new experiments and advanced theories show inaccuracy in certain portions of the models. This study focuses on updating thermodynamic data and kinetic model for a gasoline surrogate fuel, 2-methylhexane, with recently published group values and rate rules. These update provides a better agreement with rapid compression machine measurements of ignition delay time, while also strengthening the fundamental basis of the model.

Reaction network modelling for kinetic parameters of pyrolytic reactions of CHON extractants in nuclear fuel processing waste management. Contributed Paper IT-07

International Nuclear Information System (INIS)

Gaikar, Vilas G.; Thaore, Vaishali

2014-01-01

The recovery and purification of plutonium (Pu) from uranium (U) and of U from Thorium (Th) in spent nuclear fuel reprocessing is accomplished by processes that employ organophosphorous compounds as extractants.The main objective of the present work was to develop a suitable kinetic model and to determine the kinetic parameters of the set of reactions involved in the pyrolysis of amides by fitting the experimental data in the reaction network model. The experimental data and analysis are expected to be useful in the steam pyrolysis of amide waste in fuel reprocessing in the nuclear industry. The basic approach was to understand the reaction mechanism of the steam pyrolysis of amides and then to estimate the reaction rate constants for the generation and consumption of different species by solving the model equations, allowing for the determination of important species in the reaction network

A novel study of the kinetics of external hierarchical nanostructures in methanol fuel cell

International Nuclear Information System (INIS)

Al-Halhouli, M; Yurchenko, O; Urban, G; Kieninger, J

2015-01-01

For the purpose of a direct methanol fuel cell (DMFC), this research investigates the kinetics of methanol oxidation in a porous layer consisting of external hierarchical nanostructures through 2D COMSOL simulation. Three different lengths of nanowires (L) were considered in simulations. The investigation showed that specific activity was reversely proportional to nanowires length and roughness factor (Rf). However, the current density increased by increasing Rf. Although the current density in case of L = 200 nm and 500 nm was identical with respect to Rf, there was a slight deviation when L = 1000 nm due to the changing from kinetic to diffusion controlled regime, which was identified by investigation of Thiele modulus. The catalytic efficiency for L = 1000 nm dropped to 50% at Rf = 140, whereas the high efficiency with no mass-transport limitation was achieved by shorter nanowires. Therefore, increasing Rf within the simulation range resulted in increasing the total catalytic activity but simultaneously decreasing the specific activity because of the decrease in pore accessibility and catalytic efficiency of nanostructures. (paper)

Recent progress in gasoline surrogate fuels

KAUST Repository

Sarathy, Mani; Farooq, Aamir; Kalghatgi, Gautam T.

2017-01-01

Petroleum-derived gasoline is currently the most widely used fuel for transportation propulsion. The design and operation of gasoline fuels is governed by specific physical and chemical kinetic fuel properties. These must be thoroughly understood in order to improve sustainable gasoline fuel technologies in the face of economical, technological, and societal challenges. For this reason, surrogate mixtures are formulated to emulate the thermophysical, thermochemical, and chemical kinetic properties of the real fuel, so that fundamental experiments and predictive simulations can be conducted. Early studies on gasoline combustion typically adopted single component or binary mixtures (n-heptane/isooctane) as surrogates. However, the last decade has seen rapid progress in the formulation and utilization of ternary mixtures (n-heptane/isooctane/toluene), as well as multicomponent mixtures that span the entire carbon number range of gasoline fuels (C4–C10). The increased use of oxygenated fuels (ethanol, butanol, MTBE, etc.) as blending components/additives has also motivated studies on their addition to gasoline fuels. This comprehensive review presents the available experimental and chemical kinetic studies which have been performed to better understand the combustion properties of gasoline fuels and their surrogates. Focus is on the development and use of surrogate fuels that emulate real fuel properties governing the design and operation of engines. A detailed analysis is presented for the various classes of compounds used in formulating gasoline surrogate fuels, including n-paraffins, isoparaffins, olefins, naphthenes, and aromatics. Chemical kinetic models for individual molecules and mixtures of molecules to emulate gasoline surrogate fuels are presented. Despite the recent progress in gasoline surrogate fuel combustion research, there are still major gaps remaining; these are critically discussed, as well as their implications on fuel formulation and engine

Recent progress in gasoline surrogate fuels

KAUST Repository

Sarathy, Mani

2017-12-06

Petroleum-derived gasoline is currently the most widely used fuel for transportation propulsion. The design and operation of gasoline fuels is governed by specific physical and chemical kinetic fuel properties. These must be thoroughly understood in order to improve sustainable gasoline fuel technologies in the face of economical, technological, and societal challenges. For this reason, surrogate mixtures are formulated to emulate the thermophysical, thermochemical, and chemical kinetic properties of the real fuel, so that fundamental experiments and predictive simulations can be conducted. Early studies on gasoline combustion typically adopted single component or binary mixtures (n-heptane/isooctane) as surrogates. However, the last decade has seen rapid progress in the formulation and utilization of ternary mixtures (n-heptane/isooctane/toluene), as well as multicomponent mixtures that span the entire carbon number range of gasoline fuels (C4–C10). The increased use of oxygenated fuels (ethanol, butanol, MTBE, etc.) as blending components/additives has also motivated studies on their addition to gasoline fuels. This comprehensive review presents the available experimental and chemical kinetic studies which have been performed to better understand the combustion properties of gasoline fuels and their surrogates. Focus is on the development and use of surrogate fuels that emulate real fuel properties governing the design and operation of engines. A detailed analysis is presented for the various classes of compounds used in formulating gasoline surrogate fuels, including n-paraffins, isoparaffins, olefins, naphthenes, and aromatics. Chemical kinetic models for individual molecules and mixtures of molecules to emulate gasoline surrogate fuels are presented. Despite the recent progress in gasoline surrogate fuel combustion research, there are still major gaps remaining; these are critically discussed, as well as their implications on fuel formulation and engine

Preliminary Development of the MARS/FREK Spatial Kinetics Coupled System Code for Square Fueled Fast Reactor Applications

International Nuclear Information System (INIS)

Bae, Moo Hoon; Joo, Han Gyu

2009-01-01

Incorporation of a three-dimensional (3-D) reactor kinetics model into a system thermal-hydraulic (T/H) code enhances the capability to perform realistic analyses of the core neutronic behavior and the plant system dynamics which are coupled each other. For this advantage, several coupled system T/H and spatial kinetics codes, such as RELAP/PARCS, RELAP5/ PANBOX, and MARS/MASTER have been developed. These codes, however, so far limited to LWR applications. The objective of this work is to develop such a coupled code for fast reactor applications. Particularly, applications to lead-bismuth eutectic (LBE) cooled fast reactor are of interest which employ open square lattices. A fast reactor kinetics code applicable to square fueled cores called FREK is coupled the LBE version of the MARS code. The MARS/MASTER coupled code is used as the reference for the integration. The coupled code MARS/FREK is examined for a conceptual reactor called P-DEMO which is being developed by NUTRECK. In order to check the validity of the coupled code, however, the OECD MSLB benchmark exercise III calculation is solved first

Development of a kinetic model for the dissolution of the UO{sub 2} spent nuclear fuel. Application of the model to the minor radionuclides

Energy Technology Data Exchange (ETDEWEB)

Bruno, J.; Cera, E.; Duro, L.; Pon, J. [QuantiSci SL, Barcelona (Spain); Pablo, J. de [UPC, Barcelona (Spain). Dept. Enginyeria Quimica; Eriksen, Trygve [Royal Inst. of Tech., Stockholm (Sweden). Dept. of Nuclear Chemistry

1998-05-01

A kinetic model has been developed in order to explain the evolution of the spent fuel matrix/groundwater system. Mass balance equations have been used to follow the evolution of the system with time. The model has been calibrated by using experimental dissolution data from spent fuel leaching tests from Studsvik and KTH and from synthetic unirradiated UO{sub 2} dissolution tests from VTT. The results of the testing exercise indicate that the combination of mass balance equations together with the kinetic rate laws constitute a useful tool to model and explain experimental dissolution data available in the literature for UO{sub 2} solid phases, including uraninites, unirradiated UO{sub 2} and spent fuel. Although the key processes are well identified and understood, there are still some remaining uncertainties concerning some of the critical parameters of the model. This is particularly true for the density of UO{sub 2} sites prone to oxidation and the rates and mechanisms of the hydrogen peroxide and the combined oxygen and bicarbonate promoted dissolution of UO{sub 2} for oxidant concentration ranges relevant to the spent fuel disposal system. The mass balance kinetic model developed has been extended to minor radionuclides contained in the matrix, i.e. Pu, Tc and Sr. In the case of Pu, the model presented reproduces the behaviour of this critical radionuclide even at early contact times. As it would be expected, Tc seems to follow a different mechanism for its release with respect to the UO{sub 2} matrix dissolution, which is probably linked to the rate of oxidation of Tc metallic inclusions in the fuel. A co- dissolution process of Sr with the UO{sub 2} matrix reproduces the long term dissolution behaviour of this radionuclide, better than the initial Sr release rates 49 refs, 22 figs, 2 tables

Preliminary analysis of aircraft fuel systems for use with broadened specification jet fuels

Science.gov (United States)

Pasion, A. J.; Thomas, I.

1977-01-01

An analytical study was conducted on the use of broadened specification hydrocarbon fuels in present day aircraft. A short range Boeing 727 mission and three long range Boeing 747 missions were used as basis of calculation for one-day-per-year extreme values of fuel loading, airport ambient and altitude ambient temperatures with various seasonal and climatic conditions. Four hypothetical fuels were selected; two high-vapor-pressure fuels with 35 kPa and 70 kPa RVP and two high-freezing-point fuels with -29 C and -18 C freezing points. In-flight fuel temperatures were predicted by Boeing's aircraft fuel tank thermal analyzer computer program. Boil-off rates were calculated for the high vapor pressure fuels and heating/insulation requirements for the high freezing point fuels were established. Possible minor and major heating system modifications were investigated with respect to heat output, performance and economic penalties for the high freezing point fuels.

Fuel Cells: Power System Option for Space Research

Science.gov (United States)

Shaneeth, M.; Mohanty, Surajeet

2012-07-01

Fuel Cells are direct energy conversion devices and, thereby, they deliver electrical energy at very high efficiency levels. Hydrogen and Oxygen gases are electrochemically processed, producing clean electric power with water as the only by product. A typical, Fuel Cell based power system involve a Electrochemical power converter, gas storage and management systems, thermal management systems and relevant control units. While there exists different types of Fuel cells, Proton Exchange Membrane (PEM) Fuel Cells are considered as the most suitable one for portable applications. Generally, Fuel Cells are considered as the primary power system option in space missions requiring high power ( > 5kW) and long durations and also where water is a consumable, such as manned missions. This is primarily due to the advantage that fuel cell based power systems offer, in terms of specific energy. Fuel cells have the potential to attain specific energy > 500Wh/kg, specific power >500W/kg, energy density > 400Whr/L and also power density > 200 W/L. This apart, a fuel cell system operate totally independent of sun light, whereas as battery based system is fully dependent on the same. This uniqueness provides added flexibility and capabilities to the missions and modularity for power system. High power requiring missions involving reusable launch vehicles, manned missions etc are expected to be richly benefited from this. Another potential application of Fuel Cell would be interplanetary exploration. Unpredictable and dusty atmospheres of heavenly bodies limits sun light significantly and there fuel cells of different types, eg, Bio-Fuel Cells, PEMFC, DMFCs would be able to work effectively. Manned or unmanned lunar out post would require continuous power even during extra long lunar nights and high power levels are expected. Regenerative Fuel Cells, a combination of Fuel Cells and Electrolysers, are identified as strong candidate. While application of Fuel Cells in high power

A deformation and thermodynamic model for hydride precipitation kinetics in spent fuel cladding

International Nuclear Information System (INIS)

Stout, R.B.

1989-10-01

Hydrogen is contained in the Zircaloy cladding of spent fuel rods from nuclear reactors. All the spent fuel rods placed in a nuclear waste repository will have a temperature history that decreases toward ambient; and as a result, most all of the hydrogen in the Zircaloy will eventually precipitate as zirconium hydride platelets. A model for the density of hydride platelets is a necessary sub-part for predicting Zircaloy cladding failure rate in a nuclear waste repository. A model is developed to describe statistically the hydride platelet density, and the density function includes the orientation as a physical attribute. The model applies concepts from statistical mechanics to derive probable deformation and thermodynamic functionals for cladding material response that depend explicitly on the hydride platelet density function. From this model, hydride precipitation kinetics depend on a thermodynamic potential for hydride density change and on the inner product of a stress tensor and a tensor measure for the incremental volume change due to hydride platelets. The development of a failure response model for Zircaloy cladding exposed to the expected conditions in a nuclear waste repository is supported by the US DOE Yucca Mountain Project. 19 refs., 3 figs

Fuel cycle kinetics

International Nuclear Information System (INIS)

Maudlin, P.J.

1979-01-01

A theoretical methodology describing the time dependent growth of large populations of nuclear power reactors of different types is pursued. This methodology is based on the apparent close analogy between the time dependent variations of neutrons and of fuel in nuclear reactors. Methods for the realistic projection of reactor populations, as they develop in a reactor park, are provided using the point park model as kernel in a superposition of reactor deployment elements that form a realistic park scenario. Typical deployment strategy results are presented illustrating the theoretical and computational advantages of the point park model methodology

Development of ceramics based fuel, Phase I, Kinetics of UO2 sintering by vibration compacting of UO2 powder (Introductory report)

International Nuclear Information System (INIS)

Ristic, M.M.

1962-10-01

After completing the Phase I of the task related to development of ceramics nuclear fuel the following reports are presented: Kinetics of UO 2 sintering; Vibrational compacting and sintering of UO 2 ; Characterisation of of UO 2 powder by DDK and TGA methods; Separation of UO 2 powder

Reactor kinetics revisited: a coefficient based model (CBM)

International Nuclear Information System (INIS)

Ratemi, W.M.

2011-01-01

In this paper, a nuclear reactor kinetics model based on Guelph expansion coefficients calculation ( Coefficients Based Model, CBM), for n groups of delayed neutrons is developed. The accompanying characteristic equation is a polynomial form of the Inhour equation with the same coefficients of the CBM- kinetics model. Those coefficients depend on Universal abc- values which are dependent on the type of the fuel fueling a nuclear reactor. Furthermore, such coefficients are linearly dependent on the inserted reactivity. In this paper, the Universal abc- values have been presented symbolically, for the first time, as well as with their numerical values for U-235 fueled reactors for one, two, three, and six groups of delayed neutrons. Simulation studies for constant and variable reactivity insertions are made for the CBM kinetics model, and a comparison of results, with numerical solutions of classical kinetics models for one, two, three, and six groups of delayed neutrons are presented. The results show good agreements, especially for single step insertion of reactivity, with the advantage of the CBM- solution of not encountering the stiffness problem accompanying the numerical solutions of the classical kinetics model. (author)

Fundamentals of 3-D Neutron Kinetics and Current Status

International Nuclear Information System (INIS)

Aragones, J.M.

2008-01-01

This lecture includes the following topics: 1) A summary of the cell and lattice calculations used to generate the neutron reaction data for neutron kinetics, including the spectral and burnup calculations of LWR cells and fuel assembly lattices, and the main nodal kinetics parameters: mean neutron generation time and delayed neutron fraction; 2) the features of the advanced nodal methods for 3-D LWR core physics, including the treatment of partially inserted control rods, fuel assembly grids, fuel burnup and xenon and samarium transients, and excore detector responses, that are essential for core surveillance, axial offset control and operating transient analysis; 3) the advanced nodal methods for 3-D LWR core neutron kinetics (best estimate safety analysis, real-time simulation); and 4) example applications to 3-D neutron kinetics problems in transient analysis of PWR cores, including model, benchmark and operational transients without, or with simple, thermal-hydraulics feedback.

The NEOTωIST mission (Near-Earth Object Transfer of angular momentum spin test)

Science.gov (United States)

Drube, Line; Harris, Alan W.; Engel, Kilian; Falke, Albert; Johann, Ulrich; Eggl, Siegfried; Cano, Juan L.; Ávila, Javier Martín; Schwartz, Stephen R.; Michel, Patrick

2016-10-01

We present a concept for a kinetic impactor demonstration mission, which intends to change the spin rate of a previously-visited asteroid, in this case 25143 Itokawa. The mission would determine the efficiency of momentum transfer during an impact, and help mature the technology required for a kinetic impactor mission, both of which are important precursors for a future space mission to deflect an asteroid by collisional means in an emergency situation. Most demonstration mission concepts to date are based on changing an asteroid's heliocentric orbit and require a reconnaissance spacecraft to measure the very small orbital perturbation due to the impact. Our concept is a low-cost alternative, requiring only a single launch. Taking Itokawa as an example, an estimate of the order of magnitude of the change in the spin period, δP, with such a mission results in δP of 4 min (0.5%), which could be detectable by Earth-based observatories. Our preliminary study found that a mission concept in which an impactor produces a change in an asteroid's spin rate could provide valuable information for the assessment of the viability of the kinetic-impactor asteroid deflection concept. Furthermore, the data gained from the mission would be of great benefit for our understanding of the collisional evolution of asteroids and the physics behind crater and ejecta-cloud development.

CFD analysis of the dynamic behaviour of a fuel rod subchannel in a supercritical water reactor with point kinetics

International Nuclear Information System (INIS)

Ampomah-Amoako, Emmanuel; Akaho, Edward H.K.; Nyarko, Benjamin J.B.; Ambrosini, Walter

2013-01-01

Highlights: • The analysis of flow stability of nuclear fuel subchannels with supercritical water is presented. • The results obtained by a CFD code are compared with those of a system code. • The model includes also heat conduction in the fuel rod and point neutron kinetics. - Abstract: The paper presents the analysis by a CFD code of coupled neutronic–thermal hydraulic instabilities in a subchannel slice belonging to a square lattice assembly. The work represents a further phase in the assessment of the suitability of CFD codes for studies of flow stability of supercritical fluids; the research started in previous work with the analysis of bare 2D circular pipes and already addressed 3D subchannel slices with no allowance for heat conduction or neutronic effects. In the present phase, a more realistic system is considered, dealing with a slice of a fuel assembly subchannel containing the regions of the pellet, the gap and the cladding and including also the effect of inlet and outlet throttling. The adopted neutronic model is a point kinetics one, including six delayed neutron groups with global Doppler and fluid density feedbacks. The response of the model to perturbations applied starting from a steady-state condition at the rated power is compared with that of a similar model developed for a 1D system code. Upward, horizontal and downward flow orientations are addressed making use of a uniform power profile and changing relevant parameters as the gap equivalent conductance and the density reactivity coefficient. A bottom-peaked power profile is also considered in the case of vertical upward flow. Though the adopted model can still be considered simple in comparison with actual details of fuel assemblies, the obtained results demonstrate the potential of the adopted methodology for more accurate analyses to be made with larger computational resources

Review of oxidation rates of DOE spent nuclear fuel : Part 1 : nuclear fuel

International Nuclear Information System (INIS)

Hilton, B.A.

2000-01-01

The long-term performance of Department of Energy (DOE) spent nuclear fuel (SNF) in a mined geologic disposal system depends highly on fuel oxidation and subsequent radionuclide release. The oxidation rates of nuclear fuels are reviewed in this two-volume report to provide a baseline for comparison with release rate data and technical rationale for predicting general corrosion behavior of DOE SNF. The oxidation rates of nuclear fuels in the DOE SNF inventory were organized according to metallic, Part 1, and non-metallic, Part 2, spent nuclear fuels. This Part 1 of the report reviews the oxidation behavior of three fuel types prototypic of metallic fuel in the DOE SNF inventory: uranium metal, uranium alloys and aluminum-based dispersion fuels. The oxidation rates of these fuels were evaluated in oxygen, water vapor, and water. The water data were limited to pure water corrosion as this represents baseline corrosion kinetics. Since the oxidation processes and kinetics discussed in this report are limited to pure water, they are not directly applicable to corrosion rates of SNF in water chemistry that is significantly different (such as may occur in the repository). Linear kinetics adequately described the oxidation rates of metallic fuels in long-term corrosion. Temperature dependent oxidation rates were determined by linear regression analysis of the literature data. As expected the reaction rates of metallic fuels dramatically increase with temperature. The uranium metal and metal alloys have stronger temperature dependence than the aluminum dispersion fuels. The uranium metal/water reaction exhibited the highest oxidation rate of the metallic fuel types and environments that were reviewed. Consequently, the corrosion properties of all DOE SNF may be conservatively modeled as uranium metal, which is representative of spent N-Reactor fuel. The reaction rate in anoxic, saturated water vapor was essentially the same as the water reaction rate. The long-term intrinsic

Combustion-based power source for Venus surface missions

Science.gov (United States)

Miller, Timothy F.; Paul, Michael V.; Oleson, Steven R.

2016-10-01

The National Research Council has identified in situ exploration of Venus as an important mission for the coming decade of NASA's exploration of our solar system (Squyers, 2013 [1]). Heavy cloud cover makes the use of solar photovoltaics extremely problematic for power generation for Venus surface missions. In this paper, we propose a class of planetary exploration missions (for use on Venus and elsewhere) in solar-deprived situations where photovoltaics cannot be used, batteries do not provide sufficient specific energy and mission duration, and nuclear systems may be too costly or complex to justify or simply unavailable. Metal-fueled, combustion-based powerplants have been demonstrated for application in the terrestrial undersea environment. Modified or extended versions of the undersea-based systems may be appropriate for these sunless missions. We describe systems carrying lithium fuel and sulfur-hexafluoride oxidizer that have the potential for many days of operation in the sunless craters of the moon. On Venus a system level specific energy of 240 to 370 We-hr/kg should be possible if the oxidizer is brought from earth. By using either lithium or a magnesium-based alloy fuel, it may be possible to operate a similar system with CO2 derived directly from the Venus atmosphere, thus providing an estimated system specific energy of 1100 We+PV-hr/kg (the subscript refers to both electrical and mechanical power), thereby providing mission durations that enable useful scientific investigation. The results of an analysis performed by the NASA Glenn COMPASS team describe a mission operating at 2.3 kWe+PV for 5 days (120 h), with less than 260 kg power/energy system mass total. This lander would be of a size and cost suitable for a New Frontiers class of mission.

Communication of 12 June 2009 received from the Permanent Missions of Germany and the Russian Federation with regard to a working paper 'Principles of fuel supply guarantees and the multilateralization of fuel cycle activities'

International Nuclear Information System (INIS)

2009-01-01

The Secretariat has received a communication dated 12 June 2009 from the Permanent Missions of Germany and the Russian Federation, transmitting the text of the working paper 'Principles of fuel supply guarantees and the multilateralization of fuel cycle activities' submitted by Germany and the Russian Federation to the Preparatory Committee for the 2010 Review Conference of the Parties to the Treaty on the Non-Proliferation of Nuclear Weapons. As requested in that communication, the abovementioned paper is herewith circulated for the information of all Member States

Optimizing Materials for Energy Harvesting on Interplanetary Return Missions

Data.gov (United States)

National Aeronautics and Space Administration — Manned interplanetary missions will only be desirable once the ability to return is established. Even using improved fuel technologies we have not resourced the fuel...

Fuel Combustion Laboratory | Transportation Research | NREL

Science.gov (United States)

Fuel Combustion Laboratory Fuel Combustion Laboratory NREL's Fuel Combustion Laboratory focuses on designs, using both today's technology and future advanced combustion concepts. This lab supports the combustion chamber platform for fuel ignition kinetics research, was acquired to expand the lab's

Chemical Kinetic Models for Advanced Engine Combustion

Energy Technology Data Exchange (ETDEWEB)

Pitz, William J. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Mehl, Marco [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Westbrook, Charles K. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

2014-10-22

The objectives for this project are as follows: Develop detailed chemical kinetic models for fuel components used in surrogate fuels for compression ignition (CI), homogeneous charge compression ignition (HCCI) and reactivity-controlled compression-ignition (RCCI) engines; and Combine component models into surrogate fuel models to represent real transportation fuels. Use them to model low-temperature combustion strategies in HCCI, RCCI, and CI engines that lead to low emissions and high efficiency.

Nitrogen Chemistry During Burnout in Fuel-Staged Combustion

DEFF Research Database (Denmark)

Kristensen, Per Gravers; Glarborg, Peter; Dam-Johansen, Kim

1996-01-01

A parametric study involving flow reactor experiments and chemical kinetic modeling is presented for the burnout zone in fuel-staging (reburning). The results provide guidelines for optimizing the reburn process and provide a test basis for verifying kinetic models for nitrogen chemistry at tempe......A parametric study involving flow reactor experiments and chemical kinetic modeling is presented for the burnout zone in fuel-staging (reburning). The results provide guidelines for optimizing the reburn process and provide a test basis for verifying kinetic models for nitrogen chemistry...

Thermodynamic and kinetic aspects of UO 2 fuel oxidation in air at 400-2000 K

Science.gov (United States)

Taylor, Peter

2005-09-01

Most nuclear fuel oxidation research has addressed either low-temperature (1500 K) steam oxidation linked to reactor safety. This paper attempts to unify modelling for air oxidation of UO 2 fuel over a wide range of temperature, and thus to assist future improvement of the ASTEC code, co-developed by IRSN and GRS. Phenomenological correlations for different temperature ranges distinguish between oxidation on the scale of individual grains to U 3O 7 and U 3O 8 below ˜700 K and individual fragments to U 3O 8 via UO 2+ x and/or U 4O 9 above ˜1200 K. Between about 700 and 1200 K, empirical oxidation rates slowly decline as the U 3O 8 product becomes coarser-grained and more coherent, and fragment-scale processes become important. A more mechanistic approach to high-temperature oxidation addresses questions of oxygen supply, surface reaction kinetics, thermodynamic properties, and solid-state oxygen diffusion. Experimental data are scarce, however, especially at low oxygen partial pressures and high temperatures.

Fuel Optimization for Low Earth Orbit Maintenance

Directory of Open Access Journals (Sweden)

Yong Jae Park

2008-06-01

Full Text Available The resolution of Earth images taken from a satellite has close relation with satellite's altitude. If a satellite has lower altitude, it gets a picture having better resolution. However the satellite will be exposed to heavier air drag and will spend more fuel to maintain its altitude for a desired mission. Therefore, in this study, the required fuel to maintain very low earth orbit(LEO with severe air drag is analyzed using optimization method such as collocation method. The required fuel to maintain the low altitude has significantly increased as the mission altitude is lowered and the solar activity is maximized. This study also shows that the fuel reduced by increasing the period of the satellite maneuver is very small, and that slightly increasing the satellite's mission altitude is much effective in reducing the amount of fuel to maintain its altitude. The calculated fuel to maintain very low earth orbit in this study would give useful information in planning the budget of fuel and cost for LEO satellites.

Reactor kinetics - pulse and steady state

Energy Technology Data Exchange (ETDEWEB)

Estes, B F; Morris, F M [Sandia Laboratories (United States)

1974-07-01

An analytical model has been developed which couples the nuclear and thermal characteristics of the Annular Core Pulse Reactor (ACPR) into a solution which describes both the neutron kinetics of the reactor and the temperature behavior of a fuel-moderator element. The model describes both pulse and steady state operations. This paper describes the important aspects of the reactor, the fuel- moderator elements, the neutron kinetic equations of the reactor, and the time-temperature behavior of a fuel-moderator element that is being subjected to the maximum power density in the core. The parameters which are utilized in the equations are divided into two classes, those that can be measured directly and those that are assumed to be known (each is described briefly). Some of the solutions which demonstrate the versatility of the analytical model are described. (author)

Post mitigation impact risk analysis for asteroid deflection demonstration missions

Science.gov (United States)

Eggl, Siegfried; Hestroffer, Daniel; Thuillot, William; Bancelin, David; Cano, Juan L.; Cichocki, Filippo

2015-08-01

Even though mankind believes to have the capabilities to avert potentially disastrous asteroid impacts, only the realization of mitigation demonstration missions can validate this claim. Such a deflection demonstration attempt has to be cost effective, easy to validate, and safe in the sense that harmless asteroids must not be turned into potentially hazardous objects. Uncertainties in an asteroid's orbital and physical parameters as well as those additionally introduced during a mitigation attempt necessitate an in depth analysis of deflection mission designs in order to dispel planetary safety concerns. We present a post mitigation impact risk analysis of a list of potential kinetic impactor based deflection demonstration missions proposed in the framework of the NEOShield project. Our results confirm that mitigation induced uncertainties have a significant influence on the deflection outcome. Those cannot be neglected in post deflection impact risk studies. We show, furthermore, that deflection missions have to be assessed on an individual basis in order to ensure that asteroids are not inadvertently transported closer to the Earth at a later date. Finally, we present viable targets and mission designs for a kinetic impactor test to be launched between the years 2025 and 2032.

Kinetics of ethylcyclohexane pyrolysis and oxidation: An experimental and detailed kinetic modeling study

KAUST Repository

Wang, Zhandong

2015-07-01

Ethylcyclohexane (ECH) is a model compound for cycloalkanes with long alkyl side-chains. A preliminary investigation on ECH (Wang et al., Proc. Combust. Inst., 35, 2015, 367-375) revealed that an accurate ECH kinetic model with detailed fuel consumption mechanism and aromatic growth pathways, as well as additional ECH pyrolysis and oxidation data with detailed species concentration covering a wide pressure and temperature range are required to understand the ECH combustion kinetics. In this work, the flow reactor pyrolysis of ECH at various pressures (30, 150 and 760Torr) was studied using synchrotron vacuum ultraviolet (VUV) photoionization mass spectrometry (PIMS) and gas chromatography (GC). The mole fraction profiles of numerous major and minor species were evaluated, and good agreement was observed between the PIMS and GC data sets. Furthermore, a fuel-rich burner-stabilized laminar premixed ECH/O2/Ar flame at 30Torr was studied using synchrotron VUV PIMS. A detailed kinetic model for ECH high temperature pyrolysis and oxidation was developed and validated against the pyrolysis and flame data performed in this work. Further validation of the kinetic model is presented against literature data including species concentrations in jet-stirred reactor oxidation, ignition delay times in a shock tube, and laminar flame speeds at various pressures and equivalence ratios. The model well predicts the consumption of ECH, the growth of aromatics, and the global combustion properties. Reaction flux and sensitivity analysis were utilized to elucidate chemical kinetic features of ECH combustion under various reaction conditions. © 2015 The Combustion Institute.

Development of a model system to study fuel autoxidation in supercritical media: decomposition kinetics of 2,2{prime}-azobis (isobutyronitrile) in supercritical carbon dioxide

Energy Technology Data Exchange (ETDEWEB)

Morris, R.E.; Mera, A.E.; Brady, R.F. Jr. [Naval Research Laboratory, Washington, DC (USA)

2000-07-01

A high pressure reactor has been constructed and used for in situ spectroscopic measurements of reaction kinetics in supercritical fluids. The thermal decomposition of 2,2{prime}-azobis(isobutyronitrile) (AIBN) in supercritical carbon dioxide (SC-CO{sub 2}) was studied as part of an effort to characterize free-radical autoxidation of hydrocarbon fuels under supercritical conditions. The findings show that AIBN decomposes both thermally and photochemically in SC-CO{sub 2} to form the 2-cyano-2-propyl free radical which dimerizes to form tetramethylsuccinic dinitrile and dimethyl-N-(2-cyano-2-propyl) ketenimine. Examination of the decomposition kinetics of the ketenimine revealed that it was photochemically stable in the kinetic reactor, but decomposed thermally to form the dinitrile. 21 refs., 4 figs., 1 tab.

Development of a thermo-kinetic diffusion model for UO2 and (U,Pu)O2 oxide fuels using the DICTRA code

International Nuclear Information System (INIS)

Moore, Emily Elaine

2013-01-01

Uranium dioxide is the most widely used nuclear fuel for light water reactors, while some countries including France make use of the uranium-plutonium (U,Pu)O 2±x mixed oxide (MOX). The MOX is also considered for future use in the Gen IV reactors, of which the sodium cooled fast reactor (SFR) is of current research interest. Both oxides exhibit a large range of non-stoichiometry due to various oxidative states of uranium and plutonium metal. Thermo-physical properties of the fuel strongly depend on deviations in composition and temperature. Extreme temperature gradients (800 K) between the center (2300 K)and periphery of the MOX fuel pellet expose a central void due to the migration and subsequent redistribution of the fuel-elements. To gain insight into the restructuring, which occurs during the fuel lifetime as well as possible accident scenarios the thermodynamic and kinetic behavior, is crucial. A comprehensive evaluation of these properties can be incorporated in computational models to describe fuel behavior over large temperature and compositions ranges, providing a predictive tool that is applicable to other parts of the fuel cycle, such as optimizing the sintering conditions for manufacturing. Atomic transport especially in UO 2 is widely treated in the experimental and computational materials communities. The current understanding of diffusion properties is limited by the stoichiometric deviations inherent to the fuel. The difficulty is apparent in experimental settings as controlling the oxygen content is problematic. Defects (interstitial and vacancy) associated with the stoichiometric deviations of the oxides facilitate the diffusion process and is of interest in regards to the restructuring of the fuel. Experimental data is widely available; however, coherence between the evaluated diffusion coefficients is not always evident. Existing computational models based on the migration of defects are often based on atomistic level simulations. A complete

Effect of power system technology and mission requirements on high altitude long endurance aircraft

Science.gov (United States)

Colozza, Anthony J.

1994-01-01

An analysis was performed to determine how various power system components and mission requirements affect the sizing of a solar powered long endurance aircraft. The aircraft power system consists of photovoltaic cells and a regenerative fuel cell. Various characteristics of these components, such as PV cell type, PV cell mass, PV cell efficiency, fuel cell efficiency, and fuel cell specific mass, were varied to determine what effect they had on the aircraft sizing for a given mission. Mission parameters, such as time of year, flight altitude, flight latitude, and payload mass and power, were also altered to determine how mission constraints affect the aircraft sizing. An aircraft analysis method which determines the aircraft configuration, aspect ratio, wing area, and total mass, for maximum endurance or minimum required power based on the stated power system and mission parameters is presented. The results indicate that, for the power system, the greatest benefit can be gained by increasing the fuel cell specific energy. Mission requirements also substantially affect the aircraft size. By limiting the time of year the aircraft is required to fly at high northern or southern latitudes, a significant reduction in aircraft size or increase in payload capacity can be achieved.

Radioactive waste management. Ukraine. WAMAP mission to Ukraine

International Nuclear Information System (INIS)

Bergman, C.; Samiei, M.; Takats, F.

1993-01-01

In February 1992, the Ukrainian State Committee on Nuclear and Radiation Safety IAEA assisted in management of radwaste and spent fuel. A three member IAEA mission was sent to Ukraine for fact-finding. The present report discusses the outcome of this mission. It gives present legislation, regulations and organizational situation in Ukraine and generation and waste management of radioactive wastes. It discusses possible area of technical co-operation, conclusions and recommendations of the mission

A Path Forward to Advanced Nuclear Fuels: Spectroscopic Calorimetry of Nuclear Fuel Materials

International Nuclear Information System (INIS)

Tobin, J.G.

2009-01-01

The goal is to relieve the shortage of thermodynamic and kinetic information concerning the stability of nuclear fuel alloys. Past studies of the ternary nuclear fuel UPuZr have demonstrated constituent redistribution when irradiated or with thermal treatment. Thermodynamic data is key to predicting the possibilities of effects such as constituent redistribution within the fuel rods and interaction with cladding materials

Alternate-Fueled Flight: Halophytes, Algae, Bio-, and Synthetic Fuels

Science.gov (United States)

Hendricks, R. C.

2012-01-01

Synthetic and biomass fueling are now considered to be near-term aviation alternate fueling. The major impediment is a secure sustainable supply of these fuels at reasonable cost. However, biomass fueling raises major concerns related to uses of common food crops and grasses (some also called "weeds") for processing into aviation fuels. These issues are addressed, and then halophytes and algae are shown to be better suited as sources of aerospace fuels and transportation fueling in general. Some of the history related to alternate fuels use is provided as a guideline for current and planned alternate fuels testing (ground and flight) with emphasis on biofuel blends. It is also noted that lessons learned from terrestrial fueling are applicable to space missions. These materials represent an update (to 2009) and additions to the Workshop on Alternate Fueling Sustainable Supply and Halophyte Summit at Twinsburg, Ohio, October 17 to 18, 2007.

Detailed Chemical Kinetic Modeling of Hydrazine Decomposition

Science.gov (United States)

Meagher, Nancy E.; Bates, Kami R.

2000-01-01

The purpose of this research project is to develop and validate a detailed chemical kinetic mechanism for gas-phase hydrazine decomposition. Hydrazine is used extensively in aerospace propulsion, and although liquid hydrazine is not considered detonable, many fuel handling systems create multiphase mixtures of fuels and fuel vapors during their operation. Therefore, a thorough knowledge of the decomposition chemistry of hydrazine under a variety of conditions can be of value in assessing potential operational hazards in hydrazine fuel systems. To gain such knowledge, a reasonable starting point is the development and validation of a detailed chemical kinetic mechanism for gas-phase hydrazine decomposition. A reasonably complete mechanism was published in 1996, however, many of the elementary steps included had outdated rate expressions and a thorough investigation of the behavior of the mechanism under a variety of conditions was not presented. The current work has included substantial revision of the previously published mechanism, along with a more extensive examination of the decomposition behavior of hydrazine. An attempt to validate the mechanism against the limited experimental data available has been made and was moderately successful. Further computational and experimental research into the chemistry of this fuel needs to be completed.

Evaluation and Development of Chemical Kinetic Mechanism Reduction Scheme for Biodiesel and Diesel Fuel Surrogates

DEFF Research Database (Denmark)

Poon, Hiew Mun; Ng, Hoon Kiat; Gan, Suyin

2013-01-01

The aim of this study is to evaluate the existing chemical kinetic mechanism reduction techniques. From here, an appropriate reduction scheme was developed to create compact yet comprehensive surrogate models for both diesel and biodiesel fuels for diesel engine applications. The reduction...... techniques applied here were Directed Relation Graph (DRG), DRG with Error Propagation, DRG-aided Sensitivity Analysis, and DRG with Error Propagation and Sensitivity Analysis. Nonetheless, the reduced mechanisms generated via these techniques were not sufficiently small for application in multi......-dimensional computational fluid dynamics (CFD) study. A new reduction scheme was therefore formulated. A 68-species mechanism for biodiesel surrogate and a 49-species mechanism for diesel surrogate were successfully derived from the respective detailed mechanisms. An overall 97% reduction in species number...

IAEA Mission Sees High Commitment to Safety at Ghana's Research Reactor After HEU to LEU Fuel Conversion

International Nuclear Information System (INIS)

2018-01-01

An International Atomic Energy Agency (IAEA) team of experts said the operator of Ghana’s research reactor has demonstrated a high commitment to safety following the conversion of the reactor core to use low enriched uranium (LEU) as fuel instead of high enriched uranium (HEU). The team also made recommendations for further safety enhancements. The Integrated Safety Assessment for Research Reactors (INSARR) team concluded a five-day mission today to assess the safety of the GHARR-1 research reactor, originally commissioned in 1994. The 30 kW reactor, operated by the Ghana Atomic Energy Commission (GAEC) at the National Nuclear Research Institute in the capital Accra, is used primarily for trace element analysis for industrial or agricultural purposes, research, education and training. In 2017, the reactor core was converted in a joint effort by Ghana, the United States and China, with assistance from the IAEA. The IAEA supported the operation to eliminate proliferation risks associated with HEU, while maintaining important scientific research. The team made recommendations for improvements to the GAEC, including: • Completing the revision of reactor safety and operating documents to reflect the results of the commissioning of the reactor after the core fuel conversion. • Enhancing the training and qualification programme for operating personnel. • Improving the capability for monitoring operational safety parameters under all conditions. • Strengthening radiation protection by establishing an effective radiation monitoring of workplace. The GAEC said it will request a follow-up INSARR mission by 2020.

Fuel Fabrication Capability Research and Development Plan

Energy Technology Data Exchange (ETDEWEB)

Senor, David J.; Burkes, Douglas

2013-06-28

The purpose of this document is to provide a comprehensive review of the mission of the Fuel Fabrication Capability (FFC) within the Global Threat Reduction Initiative (GTRI) Convert Program, along with research and development (R&D) needs that have been identified as necessary to ensuring mission success. The design and fabrication of successful nuclear fuels must be closely linked endeavors.

Kinetics of ethylcyclohexane pyrolysis and oxidation: An experimental and detailed kinetic modeling study

KAUST Repository

Wang, Zhandong; Zhao, Long; Wang, Yu; Bian, Huiting; Zhang, Lidong; Zhang, Feng; Li, Yuyang; Sarathy, Mani; Qi, Fei

2015-01-01

species were evaluated, and good agreement was observed between the PIMS and GC data sets. Furthermore, a fuel-rich burner-stabilized laminar premixed ECH/O2/Ar flame at 30Torr was studied using synchrotron VUV PIMS. A detailed kinetic model for ECH high

Proton exchange membrane fuel cells

CERN Document Server

Qi, Zhigang

2013-01-01

Preface Proton Exchange Membrane Fuel CellsFuel CellsTypes of Fuel CellsAdvantages of Fuel CellsProton Exchange Membrane Fuel CellsMembraneCatalystCatalyst LayerGas Diffusion MediumMicroporous LayerMembrane Electrode AssemblyPlateSingle CellStackSystemCell Voltage Monitoring Module (CVM)Fuel Supply Module (FSM)Air Supply Module (ASM)Exhaust Management Module (EMM)Heat Management Module (HMM)Water Management Module (WMM)Internal Power Supply Module (IPM)Power Conditioning Module (PCM)Communications Module (COM)Controls Module (CM)SummaryThermodynamics and KineticsTheoretical EfficiencyVoltagePo

Energy Conservation Tests of a Coupled Kinetic-kinetic Plasma-neutral Transport Code

Energy Technology Data Exchange (ETDEWEB)

Stotler, D. P.; Chang, C. S.; Ku, S. H.; Lang, J.; Park, G.

2012-08-29

A Monte Carlo neutral transport routine, based on DEGAS2, has been coupled to the guiding center ion-electron-neutral neoclassical PIC code XGC0 to provide a realistic treatment of neutral atoms and molecules in the tokamak edge plasma. The DEGAS2 routine allows detailed atomic physics and plasma-material interaction processes to be incorporated into these simulations. The spatial pro le of the neutral particle source used in the DEGAS2 routine is determined from the uxes of XGC0 ions to the material surfaces. The kinetic-kinetic plasma-neutral transport capability is demonstrated with example pedestal fueling simulations.

On the effects of fuel properties and injection timing in partially premixed compression ignition of low octane fuels

KAUST Repository

Naser, Nimal

2017-06-29

A better understanding on the effects of fuel properties and injection timing is required to improve the performance of advanced engines based on low temperature combustion concepts. In this work, an experimental and computational study was conducted to investigate the effects of physical and chemical kinetic properties of low octane fuels and their surrogates in partially premixed compression ignition (PPCI) engines. The main objective was to identify the relative importance of physical versus chemical kinetic properties in predicting practical fuel combustion behavior across a range of injection timings. Two fuel/surrogate pairs were chosen for comparison: light naphtha (LN) versus the primary reference fuel (PRF) with research octane number of 65 (PRF 65), and FACE (fuels for advanced combustion engines) I gasoline versus PRF 70. Two sets of parametric studies were conducted: the first varied the amount of injected fuel mass at different injection timings to match a fixed combustion phasing, and the second maintained the same injected fuel mass at each injection timing to assess resulting combustion phasing changes. Full-cycle computational fluid dynamic engine simulations were conducted by accounting for differences in the physical properties of the original and surrogate fuels, while employing identical chemical kinetics. The simulations were found to capture trends observed in the experiments, while providing details on spatial mixing and chemical reactivity for different fuels and injection timings. It was found that differences in physical properties become increasingly important as injection timing was progressively delayed from premixed conditions, and this was rationalized by analysis of mixture stratification patterns resulting from injection of fuels with different physical properties. The results suggest that accurate descriptions of both physical and chemical behavior of fuels are critical in predictive simulations of PPCI engines for a wide range of

On the effects of fuel properties and injection timing in partially premixed compression ignition of low octane fuels

KAUST Repository

Naser, Nimal; Jaasim, Mohammed; Atef, Nour; Chung, Suk-Ho; Im, Hong G.; Sarathy, Mani

2017-01-01

A better understanding on the effects of fuel properties and injection timing is required to improve the performance of advanced engines based on low temperature combustion concepts. In this work, an experimental and computational study was conducted to investigate the effects of physical and chemical kinetic properties of low octane fuels and their surrogates in partially premixed compression ignition (PPCI) engines. The main objective was to identify the relative importance of physical versus chemical kinetic properties in predicting practical fuel combustion behavior across a range of injection timings. Two fuel/surrogate pairs were chosen for comparison: light naphtha (LN) versus the primary reference fuel (PRF) with research octane number of 65 (PRF 65), and FACE (fuels for advanced combustion engines) I gasoline versus PRF 70. Two sets of parametric studies were conducted: the first varied the amount of injected fuel mass at different injection timings to match a fixed combustion phasing, and the second maintained the same injected fuel mass at each injection timing to assess resulting combustion phasing changes. Full-cycle computational fluid dynamic engine simulations were conducted by accounting for differences in the physical properties of the original and surrogate fuels, while employing identical chemical kinetics. The simulations were found to capture trends observed in the experiments, while providing details on spatial mixing and chemical reactivity for different fuels and injection timings. It was found that differences in physical properties become increasingly important as injection timing was progressively delayed from premixed conditions, and this was rationalized by analysis of mixture stratification patterns resulting from injection of fuels with different physical properties. The results suggest that accurate descriptions of both physical and chemical behavior of fuels are critical in predictive simulations of PPCI engines for a wide range of

Battery and Fuel Cell Development for NASA's Constellation Missions

Science.gov (United States)

Manzo, Michelle A.

2009-01-01

NASA's return to the moon will require advanced battery, fuel cell and regenerative fuel cell energy storage systems. This paper will provide an overview of the planned energy storage systems for the Orion Spacecraft and the Aries rockets that will be used in the return journey to the Moon. Technology development goals and approaches to provide batteries and fuel cells for the Altair Lunar Lander, the new space suit under development for extravehicular activities (EY A) on the Lunar surface, and the Lunar Surface Systems operations will also be discussed.

Battery and Fuel Cell Development for NASA's Exploration Missions

Science.gov (United States)

Manzo, Michelle A.; Reid, Concha M.

2009-01-01

NASA's return to the moon will require advanced battery, fuel cell and regenerative fuel cell energy storage systems. This paper will provide an overview of the planned energy storage systems for the Orion Spacecraft and the Aries rockets that will be used in the return journey to the Moon. Technology development goals and approaches to provide batteries and fuel cells for the Altair Lunar Lander, the new space suit under development for extravehicular activities (EVA) on the Lunar surface, and the Lunar Surface Systems operations will also be discussed.

Fission-Based Electric Propulsion for Interstellar Precursor Missions

International Nuclear Information System (INIS)

HOUTS, MICHAEL G.; LENARD, ROGER X.; LIPINSKI, RONALD J.; PATTON, BRUCE; POSTON, DAVID; WRIGHT, STEVEN A.

1999-01-01

This paper reviews the technology options for a fission-based electric propulsion system for interstellar precursor missions. To achieve a total ΔV of more than 100 km/s in less than a decade of thrusting with an electric propulsion system of 10,000s Isp requires a specific mass for the power system of less than 35 kg/kWe. Three possible configurations are described: (1) a UZrH-fueled,NaK-cooled reactor with a steam Rankine conversion system,(2) a UN-fueled gas-cooled reactor with a recuperated Brayton conversion system, and (3) a UN-fueled heat pipe-cooled reactor with a recuperated Brayton conversion system. All three of these systems have the potential to meet the specific mass requirements for interstellar precursor missions in the near term. Advanced versions of a fission-based electric propulsion system might travel as much as several light years in 200 years

A Comparison of Flow-Through Versus Non-Flow-Through Proton Exchange Membrane Fuel Cell Systems for NASA's Exploration Missions

Science.gov (United States)

Hoberecht, Mark A.

2010-01-01

As part of the Exploration Technology Development Program (ETDP) under the auspices of the Exploration Systems Mission Directorate (ESMD), NASA is developing both primary fuel cell power systems and regenerative fuel cell (RFC) energy storage systems within the fuel cell portion of the Energy Storage Project. This effort is being led by the NASA Glenn Research Center (GRC) in partnership with the NASA Johnson Space Center (JSC), Jet Propulsion Laboratory (JPL), NASA Kennedy Space Center (KSC), and industrial partners. The development goals are to improve fuel cell and electrolysis stack electrical performance, reduce system mass, volume, and parasitic power requirements, and increase system life and reliability. A major focus of this effort has been the parallel development of both flow-through and non-flow-through proton exchange membrane (PEM) primary fuel cell power systems. The plan has been, at the appropriate time, to select a single primary fuel cell technology for eventual flight hardware development. Ideally, that appropriate time would occur after both technologies have achieved a technology readiness level (TRL) of six, which represents an engineering model fidelity PEM fuel cell system being successfully tested in a relevant environment. Budget constraints in fiscal year 2009 and beyond have prevented NASA from continuing to pursue the parallel development of both primary fuel cell options. Because very limited data exists for either system, a toplevel, qualitative assessment based on engineering judgement was performed expeditiously to provide guidance for a selection. At that time, the non-flow-through technology was selected for continued development because of potentially major advantages in terms of weight, volume, parasitic power, reliability, and life. This author believes that the advantages are significant enough, and the potential benefits great enough, to offset the higher state of technology readiness of flow-through technology. This paper

A Detailed Chemical Kinetic Reaction Mechanism for Oxidation of Four Small Alkyl Esters in Laminar Premixed Flames

Energy Technology Data Exchange (ETDEWEB)

Westbrook, C K; Pitz, W J; Westmoreland, P R; Dryer, F L; Chaos, M; Osswald, P; Kohse-Hoinghaus, K; Cool, T A; Wang, J; Yang, B; Hansen, N; Kasper, T

2008-02-08

A detailed chemical kinetic reaction mechanism has been developed for a group of four small alkyl ester fuels, consisting of methyl formate, methyl acetate, ethyl formate and ethyl acetate. This mechanism is validated by comparisons between computed results and recently measured intermediate species mole fractions in fuel-rich, low pressure, premixed laminar flames. The model development employs a principle of similarity of functional groups in constraining the H atom abstraction and unimolecular decomposition reactions in each of these fuels. As a result, the reaction mechanism and formalism for mechanism development are suitable for extension to larger oxygenated hydrocarbon fuels, together with an improved kinetic understanding of the structure and chemical kinetics of alkyl ester fuels that can be extended to biodiesel fuels. Variations in concentrations of intermediate species levels in these flames are traced to differences in the molecular structure of the fuel molecules.

Advanced Fuel Cell System Thermal Management for NASA Exploration Missions

Science.gov (United States)

Burke, Kenneth A.

2009-01-01

The NASA Glenn Research Center is developing advanced passive thermal management technology to reduce the mass and improve the reliability of space fuel cell systems for the NASA exploration program. An analysis of a state-of-the-art fuel cell cooling systems was done to benchmark the portion of a fuel cell system s mass that is dedicated to thermal management. Additional analysis was done to determine the key performance targets of the advanced passive thermal management technology that would substantially reduce fuel cell system mass.

Mechanisms and kinetics of granulated sewage sludge combustion.

Science.gov (United States)

Kijo-Kleczkowska, Agnieszka; Środa, Katarzyna; Kosowska-Golachowska, Monika; Musiał, Tomasz; Wolski, Krzysztof

2015-12-01

This paper investigates sewage sludge disposal methods with particular emphasis on combustion as the priority disposal method. Sewage sludge incineration is an attractive option because it minimizes odour, significantly reduces the volume of the starting material and thermally destroys organic and toxic components of the off pads. Additionally, it is possible that ashes could be used. Currently, as many as 11 plants use sewage sludge as fuel in Poland; thus, this technology must be further developed in Poland while considering the benefits of co-combustion with other fuels. This paper presents the results of experimental studies aimed at determining the mechanisms (defining the fuel combustion region by studying the effects of process parameters, including the size of the fuel sample, temperature in the combustion chamber and air velocity, on combustion) and kinetics (measurement of fuel temperature and mass changes) of fuel combustion in an air stream under different thermal conditions and flow rates. The combustion of the sludge samples during air flow between temperatures of 800 and 900°C is a kinetic-diffusion process. This process determines the sample size, temperature of its environment, and air velocity. The adopted process parameters, the time and ignition temperature of the fuel by volatiles, combustion time of the volatiles, time to reach the maximum temperature of the fuel surface, maximum temperature of the fuel surface, char combustion time, and the total process time, had significant impacts. Copyright © 2015 Elsevier Ltd. All rights reserved.

BILLIARDS: A Demonstration Mission for Hundred-Meter Class Near Earth Asteroid Disruption

Science.gov (United States)

Marcus, Matthew; Sloane, Joshua; Ortiz, Oliver; Barbee, Brent W.

2015-01-01

Currently, no planetary defense demonstration mission has ever been flown. While Nuclear Explosive Devices (NEDs) have significantly more energy than a kinetic impactor launched directly from Earth, they present safety and political complications, and therefore may only be used when absolutely necessary. The Baseline Instrumented Lithology Lander, Inspector, and Asteroid Redirection Demonstration System (BILLIARDS) is a demonstration mission for planetary defense, which is capable of delivering comparable energy to the lower range of NED capabilities in the form of a safer kinetic impactor. A small asteroid (disrupt the larger asteroid. To reduce the cost and complexity, an asteroid pair which has a natural close approach is selected.

Vehicle Design Evaluation Program (VDEP). A computer program for weight sizing, economic, performance and mission analysis of fuel-conservative aircraft, multibodied aircraft and large cargo aircraft using both JP and alternative fuels

Science.gov (United States)

Oman, B. H.

1977-01-01

The NASA Langley Research Center vehicle design evaluation program (VDEP-2) was expanded by (1) incorporating into the program a capability to conduct preliminary design studies on subsonic commercial transport type aircraft using both JP and such alternate fuels as hydrogen and methane;(2) incorporating an aircraft detailed mission and performance analysis capability; and (3) developing and incorporating an external loads analysis capability. The resulting computer program (VDEP-3) provides a preliminary design tool that enables the user to perform integrated sizing, structural analysis, and cost studies on subsonic commercial transport aircraft. Both versions of the VDEP-3 Program which are designated preliminary Analysis VDEP-3 and detailed Analysis VDEP utilize the same vehicle sizing subprogram which includes a detailed mission analysis capability, as well as a geometry and weight analysis for multibodied configurations.

The coupled kinetics of grain growth and fission product behavior in nuclear fuel under degraded-core accident conditions

International Nuclear Information System (INIS)

Rest, J.

1985-01-01

The theoretical FASTGRASS-VFP model has been used in the interpretation of fission gas, iodine, and cesium release from (1) irradiated high-burnup LWR fuel in a flowing steam atmosphere during high-temperature, in-cell heating tests (performed at Oak Ridge National Laboratory) and (2) trace-irratiated LWR fuel during severe-fuel-damage (SFD) tests (performed in the PBF reactor in Idaho). A theory of grain boundary sweeping of gas bubbles has been included within the FASTGRASS-VFP formalism. This theory considers the interaction between the moving grain boundary and two distinct size classes of bubbles, those on grain faces and on grain edges, and provides a means of determining whether gas bubbles are caught up and moved along by a moving grain boundary or whether the grain boundary is only temporarily retarded by the bubbles and then breaks away. In addition, as FASTGRASS-VFP provides for a mechanistic calculation of intra- and intergranular fission product behavior, the coupled calculation between fission gas behavior and grain growth is kinetically comprehensive. Results of the analyses demonstrate that intragranular fission product behavior during both types of tests can be interpreted in terms of a grain-growth/grain-boundary-sweeping mechanism that enhances the flow of fission products from within the grains to the grain boundaries. The effect of fuel oxidation by steam on fission product and grain growth behavior is also considered. The FASTGRASS-VFP predictions, measured release rates from the above tests, and previously published release rates are compared and differences between fission product behavior in trace-irradiated and in high-burnup fuel are highlighted. (orig.)

Improved point-kinetics model for the BWR control rod drop accident

International Nuclear Information System (INIS)

Neogy, P.; Wakabayashi, T.; Carew, J.F.

1985-01-01

A simple prescription to account for spatial feedback weighting effects in RDA (rod drop accident) point-kinetics analyses has been derived and tested. The point-kinetics feedback model is linear in the core peaking factor, F/sub Q/, and in the core average void fraction and fuel temperature. Comparison with detailed spatial kinetics analyses indicates that the improved point-kinetics model provides an accurate description of the BWR RDA

Kinetics of Pressurized Water Reactors with Hot or Cold Moderators

Energy Technology Data Exchange (ETDEWEB)

Norinder, O

1960-11-15

The set of neutron kinetic equations developed in this report permits the use of long integration steps during stepwise integration. Thermal relations which describe the transfer of heat from fuel to coolant are derived. The influence upon the kinetic behavior of the reactor of a number of parameters is studied. A comparison of the kinetic properties of the hot and cold moderators is given.

Fuel processing for PEM fuel cells: transport and kinetic issues of system design

Science.gov (United States)

Zalc, J. M.; Löffler, D. G.

In light of the distribution and storage issues associated with hydrogen, efficient on-board fuel processing will be a significant factor in the implementation of PEM fuel cells for automotive applications. Here, we apply basic chemical engineering principles to gain insight into the factors that limit performance in each component of a fuel processor. A system consisting of a plate reactor steam reformer, water-gas shift unit, and preferential oxidation reactor is used as a case study. It is found that for a steam reformer based on catalyst-coated foils, mass transfer from the bulk gas to the catalyst surface is the limiting process. The water-gas shift reactor is expected to be the largest component of the fuel processor and is limited by intrinsic catalyst activity, while a successful preferential oxidation unit depends on strict temperature control in order to minimize parasitic hydrogen oxidation. This stepwise approach of sequentially eliminating rate-limiting processes can be used to identify possible means of performance enhancement in a broad range of applications.

Communication dated 18 May 2009 received from the Permanent Mission of Kazakhstan to the Agency enclosing a position paper regarding the establishment of IAEA nuclear fuel banks

International Nuclear Information System (INIS)

2009-01-01

The Secretariat has received a communication dated 18 May 2009 from the Permanent Mission of Kazakhstan, transmitting a position paper of Kazakhstan regarding the establishment of IAEA nuclear fuel banks. As requested in that communication, the attached position paper is herewith circulated for the information of all Member States

Analysis of the kinetic behaviour of iodine and caesium isotopes in the primary circuit of LWR's during severe fuel damage accidents

International Nuclear Information System (INIS)

Alonso, A.; Fernandez, S.; Buron, J.M.; Lopez, J.V.

1991-01-01

This State of the Art report deals with the chemical behaviour of caesium and iodine in the primary system, focusing particularly on kinetic chemical aspects. In case of a postulated severe accident in a nuclear reactor, cesium and iodine fission products are among the major contributors to health harm because of their high volatility and radiotoxicity. The extent of the release of such fission products to the environment depends on the effectiveness of transport through different structures in the reactor coolant system and within the reactor building. The release from fuel has been briefly studied; only those aspects concerning to iodine and caesium chemical forms when released have been reviewed; nevertheless the emphasis has been put on the transport of such elements and their species through the primary system. Some thermochemical equilibrium studies, applied to primary circuit conditions in LWR's, have been analyzed. The revision of the few kinetic studies existing on this matter has shown that kinetic behaviour of iodine and caesium isotopes in the primary circuit is an aspect poorly studied, despite the fact that kinetic aspects could have great importance on the chemical species formed under certain conditions. Other phenomena affecting iodine and caesium transport, besides chemical reactions, such as interactions with surfaces, aerosols or other chemical species have also been examined from available information on diverse experiments

Kinetic Study of Methyl Acetate Oxidation in a Pt/Al2O3 Fixed-Bed Reactor

Science.gov (United States)

Hoy, Michael; Li, K. Y.; Li, Jeffrey S.; Chen, S. M.; Yaws, C. L.; Chu, H. W.; Simon, W. E.

1994-01-01

To support technology development for future long-term missions, a metabolic simulator will be used in a closed chamber to test the functions of a Controlled Ecological Life Support System (CELSS). Methyl acetate (MA) was selected as the fuel because its metabolic respiratory quotient is near that of humans. A kinetic study of the catalytic oxidation of MA over Pt/Al203 was then conducted to support the design and operation of the simulator. Kinetic data were obtained as a conversion percentage of MA versus retention time. The reaction was studied at one atmosphere and temperatures from 220 to 340 deg. C. The inlet MA concentration was varied from 100 to 2000 ppm with retention times from 0.01 to 10 sec. A first-order rate law and a Langmuir-Hinshelwood rate equation were tested by nonlinear regression of the kinetic data to estimate rate constants in the rate law. Regression results of the L-H equation explain the kinetic data better than the results of the first-order rate law. A Taguchi experimental design was used to study the effects of temperature, retention time, and concentrations of MA, CO2, and O2 on the conversion of MA. Results indicate that temperature has greatest effect, followed by retention time, and finally MA concentration. It was further determined that the effects of CO2 and O2 concentrations, and the cross effects, are negligible.

Growth kinetic and fuel quality parameters as selective criterion for screening biodiesel producing cyanobacterial strains.

Science.gov (United States)

Gayathri, Manickam; Shunmugam, Sumathy; Mugasundari, Arumugam Vanmathi; Rahman, Pattanathu K S M; Muralitharan, Gangatharan

2018-01-01

The efficiency of cyanobacterial strains as biodiesel feedstock varies with the dwelling habitat. Fourteen indigenous heterocystous cyanobacterial strains from rice field ecosystem were screened based on growth kinetic and fuel parameters. The highest biomass productivity was obtained in Nostoc punctiforme MBDU 621 (19.22mg/L/day) followed by Calothrix sp. MBDU 701 (13.43mg/L/day). While lipid productivity and lipid content was highest in Nostoc spongiaeforme MBDU 704 (4.45mg/L/day and 22.5%dwt) followed by Calothrix sp. MBDU 701 (1.54mg/L/day and 10.75%dwt). Among the tested strains, Nostoc spongiaeforme MBDU 704 and Nostoc punctiforme MBDU 621 were selected as promising strains for good quality biodiesel production by Preference Ranking Organization Method for Enrichment Evaluation (PROMETHEE) and Graphical Analysis for Interactive Assistance (GAIA) analysis. Copyright © 2017 Elsevier Ltd. All rights reserved.

Fuel properties and combustion kinetics of hydrochar prepared by hydrothermal carbonization of bamboo.

Science.gov (United States)

Yang, Wei; Wang, Hui; Zhang, Meng; Zhu, Jiayu; Zhou, Jie; Wu, Shengji

2016-04-01

Hydrothermal carbonization, an environmental friendly treatment method was employed to pretreat bamboo for hydrochar preparation in the present study. Hydrothermal carbonization could elevate the fuel properties and combustion behavior of bamboo. The combustion kinetic parameters of raw bamboo and hydrochars were calculated by a simple Arrhenius equation based on the thermogravimetric curves. Two distinct zones were observed for raw bamboo and hydrochars. The activation energies of raw bamboo in zone 1 and zone 2 were 109.5kJ/mol and 46.6kJ/mol, respectively, in the heating rate of 20°C/min. The activation energy of hydrochar in zone 1 increased at the hydrothermal carbonization temperature under 220°C and then decreased at higher hydrothermal carbonization temperature, due to the decomposition of relative reactive compounds in bamboo, and destruction of cellulose and hemicellulose structures, respectively. The activation energies of hydrochars in zone 2 were among 52.3-57.5kJ/mol, lower than that of lignin extracted from bamboo. Copyright © 2016 Elsevier Ltd. All rights reserved.

A genetically optimized kinetic model for ethanol electro-oxidation on Pt-based binary catalysts used in direct ethanol fuel cells

Science.gov (United States)

Sánchez-Monreal, Juan; García-Salaberri, Pablo A.; Vera, Marcos

2017-09-01

A one-dimensional model is proposed for the anode of a liquid-feed direct ethanol fuel cell. The complex kinetics of the ethanol electro-oxidation reaction is described using a multi-step reaction mechanism that considers free and adsorbed intermediate species on Pt-based binary catalysts. The adsorbed species are modeled using coverage factors to account for the blockage of the active reaction sites on the catalyst surface. The reaction rates are described by Butler-Volmer equations that are coupled to a one-dimensional mass transport model, which incorporates the effect of ethanol and acetaldehyde crossover. The proposed kinetic model circumvents the acetaldehyde bottleneck effect observed in previous studies by incorporating CH3CHOHads among the adsorbed intermediates. A multi-objetive genetic algorithm is used to determine the reaction constants using anode polarization and product selectivity data obtained from the literature. By adjusting the reaction constants using the methodology developed here, different catalyst layers could be modeled and their selectivities could be successfully reproduced.

High-Level Functional and Operational Requirements for the Advanced Fuel Cycle Facility

International Nuclear Information System (INIS)

Charles Park

2006-01-01

This document describes the principal functional and operational requirements for the proposed Advanced Fuel Cycle Facility (AFCF). The AFCF is intended to be the world's foremost facility for nuclear fuel cycle research, technology development, and demonstration. The facility will also support the near-term mission to develop and demonstrate technology in support of fuel cycle needs identified by industry, and the long-term mission to retain and retain U.S. leadership in fuel cycle operations. The AFCF is essential to demonstrate a more proliferation-resistant fuel cycle and make long-term improvements in fuel cycle effectiveness, performance and economy

Thorium oxide dissolution kinetics for hydroxide and carbonate complexation

International Nuclear Information System (INIS)

Jardin, R.; Curran, V.; Czerwinski, K.R.

2002-01-01

The purpose of this project was to determine the kinetics and thermodynamics of thorium oxide dissolution in the environment. Solubility is important because it establishes an upper concentration limit on the concentration of a dissolved radionuclide in solution L1. While understanding the behavior of thorium fuels in the proposed repository at Yucca Mountain is most applicable, a more rigorous study of thorium solubility over a wide pH range was performed so that the data could also be used to model the behavior of thorium fuels in any environmental system. To achieve this, the kinetics and thermodynamics of thorium oxide dissolution under both pure argon and argon with P CO2 of 0. 1 were studied under the full pH range available in each atmosphere. In addition, thorium oxide powder remnants were studied after each experiment to examine structural changes that may affect kinetics

Sulfur Tolerant Solid Oxide Fuel Cell for Coal Syngas Application: Experimental Study on Diverse Impurity Effects and Fundamental Modeling of Electrode Kinetics

Science.gov (United States)

Gong, Mingyang

With demand over green energy economy, fuel cells have been developed as a promising energy conversion technology with higher efficiency and less emission. Solid oxide fuel cells (SOFC) can utilize various fuels in addition to hydrogen including coal derived sygas, and thus are favored for future power generation due to dependence on coal in electrical industry. However impurities such as sulfur and phosphorous present in coal syngas in parts per million (p.p.m.) levels can severely poison SOFC anode typically made of Ni/yttria-stabilized-zirconia (Ni-YSZ) and limit SOFC applicability in economically derivable fuels. The focus of the research is to develop strategy for application of high performance SOFC in coal syngas with tolerance against trace impurities such as H2S and PH3. To realize the research goal, the experimental study on sulfur tolerant anode materials and examination of various fuel impurity effects on SOFC anode are combined with electrochemical modeling of SOFC cathode kinetics in order to benefit design of direct-coal-syngas SOFC. Tolerant strategy for SOFC anode against sulfur is studied by using alternative materials which can both mitigate sulfur poisoning and function as active anode components. The Ni-YSZ anode was modified by incorporation of lanthanum doped ceria (LDC) nano-coatings via impregnation. Cell test in coal syngas containing 20 ppm H2S indicated the impregnated LDC coatings inhibited on-set of sulfur poisoning by over 10hrs. Cell analysis via X-ray photon spectroscopy (XPS), X-ray diffraction (XRD) and electrochemistry revealed LDC coatings reacted with H2S via chemisorptions, resulting in less sulfur blocking triple--phase-boundary and minimized performance loss. Meanwhile the effects of PH3 impurity on SOFC anode is examined by using Ni-YSZ anode supported SOFC. Degradation of cell is found to be irreversible due to adsorption of PH3 on TPB and further reaction with Ni to form secondary phases with low melting point. The

Cruising in afterburner: Air force fuel use and emerging energy policy

International Nuclear Information System (INIS)

Lucia, David J.

2011-01-01

Operational and mission efficiency were estimated for Air Force fighters, bombers and transports from fuel use data from 2001 through 2008 as reported in the Air Force Total Cost of Ownership (AFTOC) database. This analysis estimated efficiency in terms of the best performance theoretically possible for each platform based upon the energy available in the fuel expended. Operational efficiency considered aircraft operations in general, without regard for the type of mission. Mission efficiency only considered use of allocated fuel for combat (non-training) sorties. The cost associated with fuel inefficiency of the combined fighter, bomber and tanker force were estimated based on the fiscal year 2008 costs of fuel, fully burdened to include the cost of aerial refueling. The total cost of operational inefficiency was estimated at $5 billion per year. The fully burdened cost of mission inefficiency added an additional $3.6 billion for a total per year cost estimate of $8.6 billion. This represents 21.5% of the $40 billion portion of the 2009 budget dedicated to modernization. A business case for force-structure change is presented, which describes how these cost savings can be leveraged for modernization. - Highlights: → I assess how efficiently the United States Air Force uses fuel for aviation. → I estimate the cost associated with fuel inefficiency. → Improved technology can dramatically improve fuel efficiency. → There is potentially a large cost savings associated with improved fuel efficiency. → I present a business case to leverage this cost savings for modernization.

Analysis of fuel densification

International Nuclear Information System (INIS)

Meyer, R.O.

1976-06-01

A chronology is given of NRC reviews of analytical models that are used by U.S. fuel manufacturers for the analysis of fuel densifications. A new NRC densification model, which is based on a 1700 0 C-24 hr resintering test and non-instantaneous kinetics, is also described. Statistical methods are presented for applying the model to production quantities of fuel. The NRC densification model is being used in licensing activities, but it was not developed with the intention of replacing approved vendor models

Transport Phenomena and Interfacial Kinetics in Planar Microfluidic Membraneless Fuel Cells

Energy Technology Data Exchange (ETDEWEB)

Abruna, Hector Daniel [Cornell University

2013-08-01

Our work is focused on membraneless laminar flow fuel cells, an unconventional fuel cell technology, intended to create a system that not only avoids most typical fuel cell drawbacks, but also achieves the highest power density yet recorded for a non-H{sub 2} fuel cell. We have employed rigorous electrochemistry to characterize the high-energy- density fuel BH4-, providing important mechanistic insight for anode catalyst choice and avoiding deleterious side reactions. Numerous fuel cell oxidants, used in place of O{sub 2}, are compared in a detailed, uniform manner, and a powerful new oxidant, cerium ammonium nitrate (CAN), is described. The high-voltage BH{sub 4}{sup -}/CAN fuel/oxidant combination is employed in a membraneless, room temperature, laminar-flow fuel cell, with herringbone micromixers which provide chaotic-convective flow which, in turn, enhances both the power output and efficiency of the device. We have also been involved in the design of a scaled-up version of the membraneless laminar flow fuel cell intended to provide a 10W output.

Innovative Fuel Cell Health Monitoring IC, Phase I

Data.gov (United States)

National Aeronautics and Space Administration — Energy storage devices, including fuel cells, are needed to enable future robotic and human exploration missions. Historically, the reliability of the fuel cells has...

Chemical Kinetic Modeling of 2-Methylhexane Combustion

KAUST Repository

Mohamed, Samah Y.; Sarathy, Mani

2015-01-01

necessity, as new experiments and advanced theories show inaccuracy in certain portions of the models. This study focuses on updating thermodynamic data and kinetic model for a gasoline surrogate fuel, 2-methylhexane, with recently published group values

The theory of dissipative structures of the kinetic system for defects of nonlinear physical system 'metal+loading+irradiation'. Part 3

International Nuclear Information System (INIS)

Tarasov, V.A.; Borikov, T.L.; Kryzhanovskaya, T.V.; Chernezhenko, S.A.; Rusov, V.D.

2007-01-01

The kinetic system for defects of physical nonlinear system 'metal + load + irradiation' is specified [1, 2, 3]. Developing the approaches offered in [4], where distinctions of mechanisms of radiating creep and areas of their applicability are formalized (depending on external parameters) for fuel and constructional metals, division of kinetic systems for defects of constructional and fuel metals is carrying out. Thus the accent on the autocatalytic features of kinetic system for defects of reactor fuel metals, resulting from the exoenergic autocatalytic character of nuclear fission reactions being the main point defect source is done. In this part of the article the basic attention is given to the kinetic of sink drains for point defects. For kinetic systems of sinks-sources new approaches for the task of boundary conditions are offered. The possible structure of the computer program modelling kinetic system for defects of nonlinear physical system 'metal + load + irradiation' is considered

Improved Kinetic Models for High-Speed Combustion Simulation

National Research Council Canada - National Science Library

Montgomery, C. J; Tang, Q; Sarofim, A. F; Bockelie, M. J; Gritton, J. K; Bozzelli, J. W; Gouldin, F. C; Fisher, E. M; Chakravarthy, S

2008-01-01

Report developed under an STTR contract. The overall goal of this STTR project has been to improve the realism of chemical kinetics in computational fluid dynamics modeling of hydrocarbon-fueled scramjet combustors...

Experimental and Chemical Kinetic Modeling Study of Dimethylcyclohexane Oxidation and Pyrolysis

KAUST Repository

Eldeeb, Mazen A.

2016-08-30

A combined experimental and chemical kinetic modeling study of the high-temperature ignition and pyrolysis of 1,3-dimethylcyclohexane (13DMCH) is presented. Ignition delay times are measured behind reflected shock waves over a temperature range of 1049–1544 K and pressures of 3.0–12 atm. Pyrolysis is investigated at average pressures of 4.0 atm at temperatures of 1238, 1302, and 1406 K. By means of mid-infrared direct laser absorption at 3.39 μm, fuel concentration time histories are measured under ignition and pyrolytic conditions. A detailed chemical kinetic model for 13DMCH combustion is developed. Ignition measurements show that the ignition delay times of 13DMCH are longer than those of its isomer, ethylcyclohexane. The proposed chemical kinetic model predicts reasonably well the effects of equivalence ratio and pressure, with overall good agreement between predicted and measured ignition delay times, except at low dilution levels and high pressures. Simulated fuel concentration profiles agree reasonably well with the measured profiles, and both highlight the influence of pyrolysis on the overall ignition kinetics at high temperatures. Sensitivity and reaction pathway analyses provide further insight into the kinetic processes controlling ignition and pyrolysis. The work contributes toward improved understanding and modeling of the oxidation and pyrolysis kinetics of cycloalkanes.

IAEA Mission Says France Committed to Safe, Responsible Management of Radioactive Waste

International Nuclear Information System (INIS)

2018-01-01

An International Atomic Energy Agency (IAEA) team of experts said France demonstrated a comprehensive commitment to safety with a responsible approach to the management of radioactive waste and spent nuclear fuel. The team also made suggestions aimed at further enhancements and noted several good practices. The Integrated Review Service for Radioactive Waste and Spent Fuel Management, Decommissioning and Remediation (ARTEMIS) team concluded an 11-day mission to France on 24 January. The mission, requested by the Government of France, was hosted by the Directorate General of Energy and Climate (DGEC), with the participation of officials from several relevant organizations including the French National Radioactive Waste Agency (ANDRA) and the Nuclear Safety Authority (ASN), which is responsible for nuclear and radiation safety regulation in the country. ARTEMIS missions provide independent expert advice from an international team of specialists convened by the IAEA. Reviews are based on the IAEA safety standards as well as international good practices. The mission to France aimed to help the country meet European Union obligations that require an independent peer review of national programmes for the safe and responsible management of spent fuel and radioactive waste. Nuclear power currently generates more than 70 percent of France’s electricity. The country has 58 operating nuclear power reactors, which will require the continuing safe management of radioactive waste and spent fuel. France operates facilities for the disposal of very low-level and low-level wastes, and is developing a deep geological repository for the disposal of high-level waste.

Spent fuel characterization for the commercial waste and spent fuel packaging program

International Nuclear Information System (INIS)

Fish, R.L.; Davis, R.B.; Pasupathi, V.; Klingensmith, R.W.

1980-03-01

This document presents the rationale for spent fuel characterization and provides a detailed description of the characterization examinations. Pretest characterization examinations provide quantitative and qualitative descriptions of spent fuel assemblies and rods in their irradiated conditions prior to disposal testing. This information is essential in evaluating any subsequent changes that occur during disposal demonstration and laboratory tests. Interim examinations and post-test characterization will be used to identify fuel rod degradation mechanisms and quantify degradation kinetics. The nature and behavior of the spent fuel degradation will be defined in terms of mathematical rate equations from these and laboratory tests and incorporated into a spent fuel performance prediction model. Thus, spent fuel characterization is an essential activity in the development of a performance model to be used in evaluating the ability of spent fuel to meet specific waste acceptance criteria and in evaluating incentives for modification of the spent fuel assemblies for long-term disposal purposes

Tuning of platinum nano-particles by Au usage in their binary alloy for direct ethanol fuel cell: Controlled synthesis, electrode kinetics and mechanistic interpretation

Science.gov (United States)

Dutta, Abhijit; Mondal, Achintya; Datta, Jayati

2015-06-01

Understanding of the electrode-kinetics and mechanism of ethanol oxidation reaction (EOR) is of considerable interest for optimizing electro-catalysis in direct ethanol fuel cell (DEFC). This work attempts to design Pt based electro-catalyst on carbon support, tuned with gold nano-particles (NPs), for their use in DEFC operating in alkaline medium. The platinum-gold alloyed NPs are synthesized at desired compositions and size (2-10 nm) by controlled borohydride reduction method and successfully characterized by XRD, TEM, EDS and XPS techniques. The kinetic parameters along with the activation energies for the EOR are evaluated over the temperature range 20-80 °C and the oxidation reaction products estimated through ion chromatographic analysis. Compared to single Pt/C catalyst, the over potential of EOR is reduced by ca. 500 mV, at the onset during the reaction, for PtAu/C alloy with only 23% Pt content demonstrating the ability of Au and/or its surface oxides providing oxygen species at much lower potentials compared to Pt. Furthermore, a considerable increase in the peak power density (>191%) is observed in an in-house fabricated direct ethanol anion exchange membrane fuel cell, DE(AEM)FC using the best performing Au covered Pt electrode (23% Pt) compared to the monometallic Pt catalyst.

Adsorption kinetics of cadmium and lead by chitosan

African Journals Online (AJOL)

STORAGESEVER

2010-04-26

Apr 26, 2010 ... The lead and cadmium adsorption kinetic behavior could not be described using the Langmuir ... by chemical or by physical adsorption (Dean and Dixon,. 1992 ... phate fertilizer burning fuels, cement production, mining.

Chemical kinetic modeling of H{sub 2} applications

Energy Technology Data Exchange (ETDEWEB)

Marinov, N.M.; Westbrook, C.K.; Cloutman, L.D. [Lawrence Livermore National Lab., CA (United States)] [and others

1995-09-01

Work being carried out at LLNL has concentrated on studies of the role of chemical kinetics in a variety of problems related to hydrogen combustion in practical combustion systems, with an emphasis on vehicle propulsion. Use of hydrogen offers significant advantages over fossil fuels, and computer modeling provides advantages when used in concert with experimental studies. Many numerical {open_quotes}experiments{close_quotes} can be carried out quickly and efficiently, reducing the cost and time of system development, and many new and speculative concepts can be screened to identify those with sufficient promise to pursue experimentally. This project uses chemical kinetic and fluid dynamic computational modeling to examine the combustion characteristics of systems burning hydrogen, either as the only fuel or mixed with natural gas. Oxidation kinetics are combined with pollutant formation kinetics, including formation of oxides of nitrogen but also including air toxics in natural gas combustion. We have refined many of the elementary kinetic reaction steps in the detailed reaction mechanism for hydrogen oxidation. To extend the model to pressures characteristic of internal combustion engines, it was necessary to apply theoretical pressure falloff formalisms for several key steps in the reaction mechanism. We have continued development of simplified reaction mechanisms for hydrogen oxidation, we have implemented those mechanisms into multidimensional computational fluid dynamics models, and we have used models of chemistry and fluid dynamics to address selected application problems. At the present time, we are using computed high pressure flame, and auto-ignition data to further refine the simplified kinetics models that are then to be used in multidimensional fluid mechanics models. Detailed kinetics studies have investigated hydrogen flames and ignition of hydrogen behind shock waves, intended to refine the detailed reactions mechanisms.

The ENVISAT Atmospheric Chemistry mission (GOMOS, MIPAS and SCIAMACHY) -Instrument status and mission evolution

Science.gov (United States)

Dehn, Angelika

The ENVISAT ESA's satellite was launched on a polar orbit on March 2002. It carries on-board three atmospheric chemistry instruments: GOMOS, MIPAS and SCIAMACHY [1]. At the present time, although the mission expected lifetime of 5 years has been already exceeded, all the payload modules are in good to excellent status. The only limiting factor is the available fuel that is used for orbit control manoeuvre. A new strategy was proposed [2] that will allow to save fuel and to extend the mission up to 2013. Following this strategy, the altitude of the orbit will be lowered by 17 km starting from end of 2010 and the inclination will be allowed to drift. The new orbit scenario will result in a new repeating cycle with a variation of the Mean Local Solar Time (MLST). This will have an impact on both the in-flight operations, on the science data and on the mission. The simulations carried out for the atmospheric chemistry instruments show that the new orbit strategy will neither have a significant impact in the instrument operations nor on the quality of the science data. Therefore we expect that the atmospheric mission will continue nominally until the end of the platform life time, providing to the scientist a unique dataset of the most important geophysical parameters (e.g., trace gases, clouds, and aerosol) spanning a time interval of about 11 years. The aim of this paper is to review the overall ENVISAT atmospheric mission status for the past, present and future. The evolution of the instrument performances since launch will be analyzed with focus on the life-limited items monitoring. The tuning of the instrument in-flight operations decided to cope with instrument degradation or scientific needs will be described. The lessons learned on how to operate and monitor the instruments will be highlighted. Finally the expected evolution of the instrument performances until the ENVISAT end-of-life will be discussed. [1] H. Nett, J. Frerick, T. Paulsen, and G. Levrini, "The

The combustion kinetics of the lignocellulosic biofuel, ethyl levulinate

KAUST Repository

Ghosh, Manik Kumer; Howard, Mí cheá l Sé amus; Zhang, Yingjia; Djebbi, Khalil; Capriolo, Gianluca; Farooq, Aamir; Curran, Henry J.; Dooley, Stephen

2018-01-01

Ethyl levulinate (Ethyl 4-oxopentanoate) is a liquid molecule at ambient temperature, comprising of ketone and ethyl ester functionalities and is one of the prominent liquid fuel candidates that may be easily obtained from lignocellulosic biomass. The combustion kinetics of ethyl levulinate have been investigated. Shock tube and rapid compression machine apparatuses are utilised to acquire gas phase ignition delay measurements of 0.5% ethyl levulinate/O2 mixtures at ϕ = 1.0 and ϕ = 0.5 at ∼ 10 atm over the temperature range 1000–1400 K. Ethyl levulinate is observed not to ignite at temperatures lower than ∼1040 K in the rapid compression machine. The shock tube and rapid compression machine data are closely consistent and show ethyl levulinate ignition delay to exhibit an Arrhenius dependence to temperature. These measurements are explained by the construction and analysis of a detailed chemical kinetic model. The kinetic model is completed by establishing thermochemical-kinetic analogies to 2-butanone, for the ethyl levulinate ketone functionality, and to ethyl propanoate for the ethyl ester functionality. The so constructed model is observed to describe the shock tube data very accurately, but computes the rapid compression machine data set to a lesser but still applicable fidelity. Analysis of the model suggests the autooxidation mechanism of ethyl levulinate to be entirely dominated by the propensity for the ethyl ester functionality to unimolecularly decompose to form levulinic acid and ethylene. The subsequent reaction kinetics of these species is shown to dictate the overall rate of the global combustion reaction. This model is then use to estimate the Research and Motored Octane Numbers of ethyl levulinate to be ≥97.7 and ≥ 93, respectively. With this analysis ethyl levulinate would be best suited as a gasoline fuel component, rather than as a diesel fuel as suggested in the literature. Indeed it may be considered to be useful as an

The combustion kinetics of the lignocellulosic biofuel, ethyl levulinate

KAUST Repository

Ghosh, Manik Kumer

2018-04-04

Ethyl levulinate (Ethyl 4-oxopentanoate) is a liquid molecule at ambient temperature, comprising of ketone and ethyl ester functionalities and is one of the prominent liquid fuel candidates that may be easily obtained from lignocellulosic biomass. The combustion kinetics of ethyl levulinate have been investigated. Shock tube and rapid compression machine apparatuses are utilised to acquire gas phase ignition delay measurements of 0.5% ethyl levulinate/O2 mixtures at ϕ = 1.0 and ϕ = 0.5 at ∼ 10 atm over the temperature range 1000–1400 K. Ethyl levulinate is observed not to ignite at temperatures lower than ∼1040 K in the rapid compression machine. The shock tube and rapid compression machine data are closely consistent and show ethyl levulinate ignition delay to exhibit an Arrhenius dependence to temperature. These measurements are explained by the construction and analysis of a detailed chemical kinetic model. The kinetic model is completed by establishing thermochemical-kinetic analogies to 2-butanone, for the ethyl levulinate ketone functionality, and to ethyl propanoate for the ethyl ester functionality. The so constructed model is observed to describe the shock tube data very accurately, but computes the rapid compression machine data set to a lesser but still applicable fidelity. Analysis of the model suggests the autooxidation mechanism of ethyl levulinate to be entirely dominated by the propensity for the ethyl ester functionality to unimolecularly decompose to form levulinic acid and ethylene. The subsequent reaction kinetics of these species is shown to dictate the overall rate of the global combustion reaction. This model is then use to estimate the Research and Motored Octane Numbers of ethyl levulinate to be ≥97.7 and ≥ 93, respectively. With this analysis ethyl levulinate would be best suited as a gasoline fuel component, rather than as a diesel fuel as suggested in the literature. Indeed it may be considered to be useful as an

Mathematical simulation of stressed-deformed state in rod cylindrical fuel elemnts KONDOR program

International Nuclear Information System (INIS)

Khmelevskij, M.Ya.; Malakhova, E.I.; Dolmatov, P.S.

1987-01-01

A mathematical model for numerical computation of stressed-deformed stae in a rod cylindrical fuel element is developed. The model is based on preliminary discretization of the design scheme and linearization of radial parameters as radius functions. The formulation generality enables to calculate strength parameter kinetics in any circular cylindrical fuel element (e.g. annular fuel element; solid or tubular core; ceramic, metallic or dispersion fuel) for arbitrary transient operating conditions and taking into account all possible loading factors. The method is realized in the KONDOR programm (FORTRAN, ES-1061 computer). An example illustrating computation of stress kinetics in a fast reactor fuel element during transient operation is given

Block Copolymers for Alkaline Fuel Cell Membrane Materials

Science.gov (United States)

2014-07-30

temperature fuel cells including proton exchange membrane fuel cell ( PEMFC ) and alkaline fuel cell (AFC) with operation temperature usually lower than 120...advantages over proton exchange membrane fuel cells ( PEMFCs ) resulting in the popularity of AFCs in the US space program.[8-11] The primary benefit AFC...offered over PEMFC is better electrochemical kinetics on the anode and cathode under the alkaline environment, which results in the ability to use

MITEE: A Compact Ultralight Nuclear Thermal Propulsion Engine for Planetary Science Missions

Science.gov (United States)

Powell, J.; Maise, G.; Paniagua, J.

2001-01-01

A new approach for a near-term compact, ultralight nuclear thermal propulsion engine, termed MITEE (Miniature Reactor Engine) is described. MITEE enables a wide range of new and unique planetary science missions that are not possible with chemical rockets. With U-235 nuclear fuel and hydrogen propellant the baseline MITEE engine achieves a specific impulse of approximately 1000 seconds, a thrust of 28,000 newtons, and a total mass of only 140 kilograms, including reactor, controls, and turbo-pump. Using higher performance nuclear fuels like U-233, engine mass can be reduced to as little as 80 kg. Using MITEE, V additions of 20 km/s for missions to outer planets are possible compared to only 10 km/s for H2/O2 engines. The much greater V with MITEE enables much faster trips to the outer planets, e.g., two years to Jupiter, three years to Saturn, and five years to Pluto, without needing multiple planetary gravity assists. Moreover, MITEE can utilize in-situ resources to further extend mission V. One example of a very attractive, unique mission enabled by MITEE is the exploration of a possible subsurface ocean on Europa and the return of samples to Earth. Using MITEE, a spacecraft would land on Europa after a two-year trip from Earth orbit and deploy a small nuclear heated probe that would melt down through its ice sheet. The probe would then convert to a submersible and travel through the ocean collecting samples. After a few months, the probe would melt its way back up to the MITEE lander, which would have replenished its hydrogen propellant by melting and electrolyzing Europa surface ice. The spacecraft would then return to Earth. Total mission time is only five years, starting from departure from Earth orbit. Other unique missions include Neptune and Pluto orbiter, and even a Pluto sample return. MITEE uses the cermet Tungsten-UO2 fuel developed in the 1960's for the 710 reactor program. The W-UO2 fuel has demonstrated capability to operate in 3000 K hydrogen for

Nuclear risk analysis of the Ulysses mission

International Nuclear Information System (INIS)

Bartram, B.W.; Vaughan, F.R.; Englehart, D.R.W.

1991-01-01

The use of a radioisotope thermoelectric generator fueled with plutonium-238 dioxide on the Space Shuttle-launched Ulysses mission implies some level of risk due to potential accidents. This paper describes the method used to quantify risks in the Ulysses mission Final Safety Analysis Report prepared for the U.S. Department of Energy. The starting point for the analysis described herein is following input of source term probability distributions from the General Electric Company. A Monte Carlo technique is used to develop probability distributions of radiological consequences for a range of accident scenarios thoughout the mission. Factors affecting radiological consequences are identified, the probability distribution of the effect of each factor determined, and the functional relationship among all the factors established. The probability distributions of all the factor effects are then combined using a Monte Carlo technique. The results of the analysis are presented in terms of complementary cumulative distribution functions (CCDF) by mission sub-phase, phase, and the overall mission. The CCDFs show the total probability that consequences (calculated health effects) would be equal to or greater than a given value

Ignition delay time measurements of primary reference fuel blends

KAUST Repository

Alabbad, Mohammed

2017-02-07

Ignition delay times of four different primary reference fuels (PRF), mixtures of n-heptane and iso-octane, were measured behind reflected shock waves in a high-pressure shock tube facility. The PRFs were formulated to match the RON of two high-octane gasolines (RON 95 and 91) and two prospective low-octane naphtha fuels (RON 80 and 70). Experiments were carried out over a wide range of temperatures (700–1200K), pressures (10, 20, and 40bar) and equivalence ratios (0.5 and 1). Kinetic modeling predictions from four chemical kinetic mechanisms are compared with the experimental data. Ignition delay correlations are developed to reproduce the measured ignition delay times. Brute force sensitivity analyses are carried out to identify reactions that affect ignition delay times at specific temperature, pressure and equivalence ratio. The large experimental data set provided in the current work will serve as a benchmark for the validation of chemical kinetic mechanisms of primary reference fuel blends.

Ignition delay time measurements of primary reference fuel blends

KAUST Repository

Alabbad, Mohammed; Javed, Tamour; Khaled, Fathi; Badra, Jihad; Farooq, Aamir

2017-01-01

Ignition delay times of four different primary reference fuels (PRF), mixtures of n-heptane and iso-octane, were measured behind reflected shock waves in a high-pressure shock tube facility. The PRFs were formulated to match the RON of two high-octane gasolines (RON 95 and 91) and two prospective low-octane naphtha fuels (RON 80 and 70). Experiments were carried out over a wide range of temperatures (700–1200K), pressures (10, 20, and 40bar) and equivalence ratios (0.5 and 1). Kinetic modeling predictions from four chemical kinetic mechanisms are compared with the experimental data. Ignition delay correlations are developed to reproduce the measured ignition delay times. Brute force sensitivity analyses are carried out to identify reactions that affect ignition delay times at specific temperature, pressure and equivalence ratio. The large experimental data set provided in the current work will serve as a benchmark for the validation of chemical kinetic mechanisms of primary reference fuel blends.

Response of a direct methanol fuel cell to fuel change

Energy Technology Data Exchange (ETDEWEB)

Leo, T.J. [Dpto de Sistemas Oceanicos y Navales- ETSI Navales, Univ. Politecnica de Madrid, Avda Arco de la Victoria s/n, 28040 Madrid (Spain); Raso, M.A.; de la Blanca, E. Sanchez [Dpto de Quimica Fisica I- Fac. CC. Quimicas, Univ. Complutense de Madrid, Avda Complutense s/n, 28040 Madrid (Spain); Navarro, E.; Villanueva, M. [Dpto de Motopropulsion y Termofluidodinamica, ETSI Aeronauticos, Univ. Politecnica de Madrid, Pza Cardenal Cisneros 3, 28040 Madrid (Spain); Moreno, B. [Instituto de Ceramica y Vidrio, Consejo Superior de Investigaciones Cientificas, C/Kelsen 5, Campus de la UAM, 28049 Cantoblanco, Madrid (Spain)

2010-10-15

Methanol and ethanol have recently received much attention as liquid fuels particularly as alternative 'energy-vectors' for the future. In this sense, to find a direct alcohol fuel cell that able to interchange the fuel without losing performances in an appreciable way would represent an evident advantage in the field of portable applications. In this work, the response of a in-house direct methanol fuel cell (DMFC) to the change of fuel from methanol to ethanol and its behaviour at different ambient temperature values have been investigated. A corrosion study on materials suitable to fabricate the bipolar plates has been carried out and either 316- or 2205-duplex stainless steels have proved to be adequate for using in direct alcohol fuel cells. Polarization curves have been measured at different ambient temperature values, controlled by an experimental setup devised for this purpose. Data have been fitted to a model taking into account the temperature effect. For both fuels, methanol and ethanol, a linear dependence of adjustable parameters with temperature is obtained. Fuel cell performance comparison in terms of open circuit voltage, kinetic and resistance is established. (author)

Neutronic analysis of a fuel element with variations in fuel enrichment and burnable poison

Energy Technology Data Exchange (ETDEWEB)

Faria, Rochkhudson B. de; Martins, Felipe; Velasquez, Carlos E.; Cardoso, Fabiano; Fortini, Angela; Pereira, Claubia, E-mail: rochkdefaria@yahoo.com.br, E-mail: claubia@nuclear.ufmg.br [Universidade Federal de Minas Gerais (UFMG), Belo Horizonte, MG (Brazil). Departamento de Engenharia Nuclear

2017-07-01

In this work, the goal was to evaluate the neutronic behavior during the fuel burnup changing the amount of burnable poison and fuel enrichment. For these analyses, it was used a 17 x 17 PWR fuel element, simulated using the 238 groups library cross-section collapsed from ENDF/BVII.0 and TRITON module of SCALE 6.0 code system. The results confirmed the effective action of the burnable poison in the criticality control, especially at Beginning Of Cycle (BOC) and in the burnup kinetics, because at the end of the fuel cycle there was a minimal residual amount of neutron absorbers ({sup 155}Gd and {sup 157}Gd), as expected. At the end of the cycle, the fuel element was still critical in all simulated situations, indicating the possibility of extending the fuel burn. (author)

Medium-Power Lead-Alloy Reactors: Missions for This Reactor Technology

International Nuclear Information System (INIS)

Todreas, Neil E.; MacDonald, Philip E.; Hejzlar, Pavel; Buongiorno, Jacopo; Loewen, Eric P.

2004-01-01

A multiyear project at the Idaho National Engineering and Environmental Laboratory and the Massachusetts Institute of Technology investigated the potential of medium-power lead-alloy-cooled technology to perform two missions: (1) the production of low-cost electricity and (2) the burning of actinides from light water reactor (LWR) spent fuel. The goal of achieving a high power level to enhance economic performance simultaneously with adoption of passive decay heat removal and modularity capabilities resulted in designs in the range of 600-800 MW(thermal), which we classify as a medium power level compared to the lower [∼100 MW(thermal)] and higher [2800 MW(thermal)] power ratings of other lead-alloy-cooled designs. The plant design that was developed shows promise of achieving all the Generation-IV goals for future nuclear energy systems: sustainable energy generation, low overnight capital cost, a very low likelihood and degree of core damage during any conceivable accident, and a proliferation-resistant fuel cycle. The reactor and fuel cycle designs that evolved to achieve these missions and goals resulted from study of the following key trade-offs: waste reduction versus reactor safety, waste reduction versus cost, and cost versus proliferation resistance. Secondary trade-offs that were also considered were monolithic versus modular design, active versus passive safety systems, forced versus natural circulation, alternative power conversion cycles, and lead versus lead-bismuth coolant.These studies led to a selection of a common modular design with forced convection cooling, passive decay heat removal, and a supercritical CO 2 power cycle for all our reactor concepts. However, the concepts adopt different core designs to optimize the achievement of the two missions. For the low-cost electricity production mission, a design approach based on fueling with low enriched uranium operating without costly reprocessing in a once-through cycle was pursued to achieve a

Kinetics of two phase fuel reflected reactors

International Nuclear Information System (INIS)

Buzano, M.L.; Corno, S.E.; Mattioda, F.

2000-01-01

In the present work a self-consistent mathematical model for the local dynamics of a quite particular class of fission reactors has been developed and solved. These devices consist of an innermost multiplying region, in which a significant fraction of the fissile fuel is diluted into a liquid phase, while the complementary fuel fraction operates as a standing solid matrix. This unconventional active region is surrounded by a standard peripheral reflector. For cooling purposes, the fluid fraction of the fuel needs to be circulated through external heat exchangers. The pump driven circulation causes the delayed neutron precursors, dissolved inside the fluid phase, to be spatially homogenized in the core volume well before decaying, while a continuous removal of precursor nuclei from the core takes place as a consequence of the outside circulation. Furthermore, the fraction of the extracted precursors still surviving after the solenoidal trip through the heat exchangers is continuously reinserted into the core. A new type of dynamical model is required to account for these unusual technological features. The mathematical structure of the evolution model presented in this paper consists of a system of integro-differential-difference equations, whose solution is derived in closed-form, by means of fully analytical techniques. Many dynamics and safety features of reactors of this type can be clarified a priori, upon inspection of the mathematical properties of the solution of the model. The rigorous time-eigenvalue generating equation can be explicitly established in the present theoretical context, together with the evaluation of any kind of transients. A short survey on the possible fields of application of these reactors is also presented

Advanced Fuels Campaign FY 2015 Accomplishments Report

Energy Technology Data Exchange (ETDEWEB)

Braase, Lori Ann [Idaho National Lab. (INL), Idaho Falls, ID (United States); Carmack, William Jonathan [Idaho National Lab. (INL), Idaho Falls, ID (United States)

2015-10-29

The mission of the Advanced Fuels Campaign (AFC) is to perform research, development, and demonstration (RD&D) activities for advanced fuel forms (including cladding) to enhance the performance and safety of the nation’s current and future reactors; enhance proliferation resistance of nuclear fuel; effectively utilize nuclear energy resources; and address the longer-term waste management challenges. This report is a compilation of technical accomplishment summaries for FY-15. Emphasis is on advanced accident-tolerant LWR fuel systems, advanced transmutation fuels technologies, and capability development.

Determination of reactivity of multiplying systems filled with spherical HTGR-fuel elements using kinetic methods with regard to the pulsed-neutron method

International Nuclear Information System (INIS)

Drueke, V.

1978-06-01

At three critical or subcritical facilities - two of them filled with spherical HTGR-fuel elements - the reactivity is determined using kinetic methods. Besides the inverskinetic method the applicability of the pulsed-neutron method is investigated. The experimental results using the pulsed-neutron method are compared partly with the inverskinetic method and partly with diffusion-calculations. It is shown, that in the HTGR the space dependence of the reactivity in radial direction is not remarkable in spite of the 'kinetic distortion'; on the contrary in axial direction - the direction of the external neutron source - space dependent reactivity worths are measured. The results of the pulsed-neutron methods of Sjoestrand and Simmons-King are rather good applicable in all configurations. For the method of Sjoestrand it is necessary to select the detector positions, whereas for Simmons-King the calculated life-time determines the results. Therefore it is proposed to compare calculated and measured decay constants of the prompt neutron field in future. (orig.) [de

Colloidal Au and Au-alloy catalysts for direct borohydride fuel cells: Electrocatalysis and fuel cell performance

Science.gov (United States)

Atwan, Mohammed H.; Macdonald, Charles L. B.; Northwood, Derek O.; Gyenge, Elod L.

Supported colloidal Au and Au-alloys (Au-Pt and Au-Pd, 1:1 atomic ratio) on Vulcan XC-72 (with 20 wt% metal load) were prepared by the Bönneman method. The electrocatalytic activity of the colloidal metals with respect to borohydride electro-oxidation for fuel cell applications was investigated by voltammetry on static and rotating electrodes, chronoamperometry, chronopotentiometry and fuel cell experiments. The fundamental electrochemical techniques showed that alloying Au, a metal that leads to the maximum eight-electron oxidation of BH 4 -, with Pd or Pt, well-known catalysts of dehydrogenation reactions, improved the electrode kinetics of BH 4 - oxidation. Fuel cell experiments corroborated the kinetic studies. Using 5 mg cm -2 colloidal metal load on the anode, it was found that Au-Pt was the most active catalyst giving a cell voltage of 0.47 V at 100 mA cm -2 and 333 K, while under identical conditions the cell voltage using colloidal Au was 0.17 V.

Colloidal Au and Au-alloy catalysts for direct borohydride fuel cells: Electrocatalysis and fuel cell performance

Energy Technology Data Exchange (ETDEWEB)

Atwan, Mohammed H.; Northwood, Derek O. [Department of Mechanical, Auto and Materials Engineering, University of Windsor, Windsor (Canada N9B 3P4); Macdonald, Charles L.B. [Department of Chemistry and Biochemistry, University of Windsor, Windsor (Canada N9B 3P4); Gyenge, Elod L. [Department of Chemical and Biological Engineering, The University of British Columbia, Vancouver, BC (Canada V6T 1Z4)

2006-07-14

Supported colloidal Au and Au-alloys (Au-Pt and Au-Pd, 1:1 atomic ratio) on Vulcan XC-72 (with 20wt% metal load) were prepared by the Bonneman method. The electrocatalytic activity of the colloidal metals with respect to borohydride electro-oxidation for fuel cell applications was investigated by voltammetry on static and rotating electrodes, chronoamperometry, chronopotentiometry and fuel cell experiments. The fundamental electrochemical techniques showed that alloying Au, a metal that leads to the maximum eight-electron oxidation of BH{sub 4}{sup -}, with Pd or Pt, well-known catalysts of dehydrogenation reactions, improved the electrode kinetics of BH{sub 4}{sup -} oxidation. Fuel cell experiments corroborated the kinetic studies. Using 5mgcm{sup -2} colloidal metal load on the anode, it was found that Au-Pt was the most active catalyst giving a cell voltage of 0.47V at 100mAcm{sup -2} and 333K, while under identical conditions the cell voltage using colloidal Au was 0.17V. (author)

Optimal mission planning of GEO on-orbit refueling in mixed strategy

Science.gov (United States)

Chen, Xiao-qian; Yu, Jing

2017-04-01

The mission planning of GEO on-orbit refueling (OOR) in Mixed strategy is studied in this paper. Specifically, one SSc will be launched to an orbital slot near the depot when multiple GEO satellites are reaching their end of lives. The SSc replenishes fuel from the depot and then extends the lifespan of the target satellites via refueling. In the mixed scenario, only some of the target satellites could be served by the SSc, and the remaining ones will be fueled by Pseudo SScs (the target satellite which has already been refueled by the SSc and now has sufficient fuel for its operation as well as the fuel to refuel other target satellites is called Pseudo SSc here). The mission sequences and fuel mass of the SSc and Pseudo SScs, the dry mass of the SSc are used as design variables, whereas the economic benefit of the whole mission is used as design objective. The economic cost and benefit models are stated first, and then a mathematical optimization model is proposed. A comprehensive solution method involving enumeration, particle swarm optimization and modification is developed. Numerical examples are carried out to demonstrate the effectiveness of the model and solution method. Economic efficiencies of different OOR strategies are compared and discussed. The mixed strategy would perform better than the other strategies only when the target satellites satisfy some conditions. This paper presents an available mixed strategy scheme for users and analyzes its advantages and disadvantages by comparing with some other OOR strategies, providing helpful references to decision makers. The best strategy in practical applications depends on the specific demands and user preference.

Spent Nuclear Fuel (SNF) Project Execution Plan

International Nuclear Information System (INIS)

LEROY, P.G.

2000-01-01

The Spent Nuclear Fuel (SNF) Project supports the Hanford Site Mission to cleanup the Site by providing safe, economic, environmentally sound management of Site spent nuclear fuel in a manner that reduces hazards by staging it to interim onsite storage and deactivates the 100 K Area facilities

Spent Nuclear Fuel (SNF) Project Execution Plan

Energy Technology Data Exchange (ETDEWEB)

LEROY, P.G.

2000-11-03

The Spent Nuclear Fuel (SNF) Project supports the Hanford Site Mission to cleanup the Site by providing safe, economic, environmentally sound management of Site spent nuclear fuel in a manner that reduces hazards by staging it to interim onsite storage and deactivates the 100 K Area facilities.

Towards an efficient conversion of ethanol in low temperature fuel cells

Energy Technology Data Exchange (ETDEWEB)

Rao, Vineet [Technische Universitaet Muenchen, Physik Department E19, James-Franck-Str. 1, D-85747 Garching (Germany); Stimming, Ulrich [Technische Universitaet Muenchen, Physik Department E19, James-Franck-Str. 1, D-85747 Garching (Germany); ZAE Bayern, Abteilung 1, Walther-Meissner-Str. 6, D-85748 Garching (Germany)

2009-07-01

Direct conversion of ethanol in low temperature fuel cells is a major goal in the development of fuel cells. Advantages of ethanol are its availability from biomass and the high energy density of such liquid fuel. Nevertheless, a major drawback is the incomplete oxidation of ethanol. Recent research focused mainly on novel catalyst materials for the ethanol oxidation reaction (EOR) based on e.g. Pt-Sn. Furthermore, some groups have carried out tests on solid OH- ion exchange membrane fuel cells. Better kinetics of fuel cell processes in such exchange membrane fuel cells could allow using also higher alcohols as fuel. Ethanol has slower kinetics of oxidation in acidic media and several by-products are formed because of incomplete oxidation. In our studies we investigated EOR in alkaline membrane electrode assemblies (MEA). Here, ethanol undergoes significantly more complete electro-oxidation to CO{sub 2} than in case of acidic MEA with same Pt anode.

Evaluation of Metal-Fueled Surface Reactor Concepts

International Nuclear Information System (INIS)

Poston, David I.; Marcille, Thomas F.; Kapernick, Richard J.; Hiatt, Matthew T.; Amiri, Benjamin W.

2007-01-01

Surface fission power systems for use on the Moon and Mars may provide the first use of near-term reactor technology in space. Most near-term surface reactor concepts specify reactor temperatures <1000 K to allow the use of established material and power conversion technology and minimize the impact of the in-situ environment. Metal alloy fuels (e.g. U-10Zr and U-10Mo) have not traditionally been considered for space reactors because of high-temperature requirements, but they might be an attractive option for these lower temperature surface power missions. In addition to temperature limitations, metal fuels are also known to swell significantly at rather low fuel burnups (∼1 a/o), but near-term surface missions can mitigate this concern as well, because power and lifetime requirements generally keep fuel burnups <1 a/o. If temperature and swelling issues are not a concern, then a surface reactor concept may be able to benefit from the high uranium density and relative ease of manufacture of metal fuels. This paper investigates two reactor concepts that utilize metal fuels. It is found that these concepts compare very well to concepts that utilize other fuels (UN, UO2, UZrH) on a mass basis, while also providing the potential to simplify material safeguards issues

Understanding Yield Anomalies in ICF Implosions via Fully Kinetic Simulations

Science.gov (United States)

Taitano, William

2017-10-01

In the quest towards ICF ignition, plasma kinetic effects are among prime candidates for explaining some significant discrepancies between experimental observations and rad-hydro simulations. To assess their importance, high-fidelity fully kinetic simulations of ICF capsule implosions are needed. Owing to the extremely multi-scale nature of the problem, kinetic codes have to overcome nontrivial numerical and algorithmic challenges, and very few options are currently available. Here, we present resolutions of some long-standing yield discrepancy conundrums using a novel, LANL-developed, 1D-2V Vlasov-Fokker-Planck code iFP. iFP possesses an unprecedented fidelity and features fully implicit time-stepping, exact mass, momentum, and energy conservation, and optimal grid adaptation in phase space, all of which are critically important for ensuring long-time numerical accuracy of the implosion simulations. Specifically, we concentrate on several anomalous yield degradation instances observed in Omega campaigns, with the so-called ``Rygg effect'', or an anomalous yield scaling with the fuel composition, being a prime example. Understanding the physical mechanisms responsible for such degradations in non-ignition-grade Omega experiments is of great interest, as such experiments are often used for platform and diagnostic development, which are then used in ignition-grade experiments on NIF. In the case of Rygg's experiments, effects of a kinetic stratification of fuel ions on the yield have been previously proposed as the anomaly explanation, studied with a kinetic code FPION, and found unimportant. We have revisited this issue with iFP and obtained excellent yield-over-clean agreement with the original Rygg results, and several subsequent experiments. This validates iFP and confirms that the kinetic fuel stratification is indeed at the root of the observed yield degradation. This work was sponsored by the Metropolis Postdoctoral Fellowship, LDRD office, Thermonuclear Burn

The Asteroid Impact and Deflection Assessment Mission and its Potential Contributions to Human Exploration of Asteroids

Science.gov (United States)

Abell, Paul A.; Rivkin, Andy S.

2014-01-01

The joint ESA and NASA Asteroid Impact and Deflection Assessment (AIDA) mission will directly address aspects of NASA's Asteroid Initiative and will contribute to future human exploration. The NASA Asteroid Initiative is comprised of two major components: the Grand Challenge and the Asteroid Mission. The first component, the Grand Challenge, focuses on protecting Earth's population from asteroid impacts by detecting potentially hazardous objects with enough warning time to either prevent them from impacting the planet, or to implement civil defense procedures. The Asteroid Mission, involves sending astronauts to study and sample a near-Earth asteroid (NEA) prior to conducting exploration missions of the Martian system, which includes Phobos and Deimos. AIDA's primary objective is to demonstrate a kinetic impact deflection and characterize the binary NEA Didymos. The science and technical data obtained from AIDA will aid in the planning of future human exploration missions to NEAs and other small bodies. The dual robotic missions of AIDA, ESA's Asteroid Impact Monitor (AIM) and NASA's Double Asteroid Redirection Test (DART), will provide a great deal of technical and engineering data on spacecraft operations for future human space exploration while conducting in-depth scientific examinations of the binary target Didymos both prior to and after the kinetic impact demonstration. The knowledge gained from this mission will help identify asteroidal physical properties in order to maximize operational efficiency and reduce mission risk for future small body missions. The AIDA data will help fill crucial strategic knowledge gaps concerning asteroid physical characteristics that are relevant for human exploration considerations at similar small body destinations.

Nanofluidic fuel cell

Science.gov (United States)

Lee, Jin Wook; Kjeang, Erik

2013-11-01

Fuel cells are gaining momentum as a critical component in the renewable energy mix for stationary, transportation, and portable power applications. State-of-the-art fuel cell technology benefits greatly from nanotechnology applied to nanostructured membranes, catalysts, and electrodes. However, the potential of utilizing nanofluidics for fuel cells has not yet been explored, despite the significant opportunity of harnessing rapid nanoscale reactant transport in close proximity to the reactive sites. In the present article, a nanofluidic fuel cell that utilizes fluid flow through nanoporous media is conceptualized and demonstrated for the first time. This transformative concept captures the advantages of recently developed membraneless and catalyst-free fuel cell architectures paired with the enhanced interfacial contact area enabled by nanofluidics. When compared to previously reported microfluidic fuel cells, the prototype nanofluidic fuel cell demonstrates increased surface area, reduced activation overpotential, superior kinetic characteristics, and moderately enhanced fuel cell performance in the high cell voltage regime with up to 14% higher power density. However, the expected mass transport benefits in the high current density regime were constrained by high ohmic cell resistance, which could likely be resolved through future optimization studies.

Kinetic energy absorbing pad

International Nuclear Information System (INIS)

Bricmont, R.J.; Hamilton, P.A.; Ming Long Ting, R.

1981-01-01

Reactors, fuel processing plants etc incorporate pipes and conduits for fluids under high pressure. Fractures, particularly adjacent to conduit elbows, produce a jet of liquid which whips the broken conduit at an extremely high velocity. An enormous impact load would be applied to any stationary object in the conduit's path. The design of cellular, corrugated metal impact pads to absorb the kinetic energy of the high velocity conduits is given. (U.K.)

Improved lumped parameter for annular fuel element thermohydraulic analysis

International Nuclear Information System (INIS)

Duarte, Juliana Pacheco; Su, Jian; Alvim, Antonio Carlos Marques

2011-01-01

Annular fuel elements have been intensively studied for the purpose of increasing power density in light water reactors (LWR). This paper presents an improved lumped parameter model for the dynamics of a LWR core with annular fuel elements, composed of three sub-models: the fuel dynamics model, the neutronics model, and the coolant energy balance model. The transient heat conduction in radial direction is analyzed through an improved lumped parameter formulation. The Hermite approximation for integration is used to obtain the average temperature of the fuel and cladding and also to obtain the average heat flux. The volumetric heat generation in fuel rods was obtained with the point kinetics equations with six delayed neutron groups. The equations for average temperature of fuel and cladding are solved along with the point kinetic equations, assuming linear reactivity and coolant temperature in cases of reactivity insertion. The analytical development of the model and the numeric solution of the ordinary differential equation system were obtained by using Mathematica 7.0. The dynamic behaviors for average temperatures of fuel, cladding and coolant in transient events as well as the reactor power were analyzed. (author)

Separation of the Shuttle Columbia's external fuel tank

Science.gov (United States)

1981-01-01

Separation of the Shuttle Columbia's external fuel tank (ET), photographed by a camera in the umbilical bay. Camera was able to record the underside of the tank as the orbiter toward its earth-orbital mission and the fuel tank fell toward the earth.

Status of IFR fuel cycle demonstration

International Nuclear Information System (INIS)

Lineberry, M.J.; Phipps, R.D.; McFarlane, H.F.

1993-01-01

The next major step in Argonne's Integral Fast Reactor (IFR) Program is demonstration of the pyroprocess fuel cycle, in conjunction with continued operation of EBR-II. The Fuel Cycle Facility (FCF) is being readied for this mission. This paper will address the status of facility systems and process equipment, the initial startup experience, and plans for the demonstration program

FFTF Plant transition mission analysis report

International Nuclear Information System (INIS)

Lund, D.P.

1995-01-01

FFTF (Fast Flux Test Facility) is a 400-MW(t) sodium-cooled, fast flux test reactor at Hanford, designed to test fuels and materials for advanced nuclear power plants; it has no capability for generating electric power. Since a long-term mission could not be found for FFTF, it was placed in standby, and a recommendation was made that it be shut down. Purpose of the FFTF Transition Project is to prepare it for Decontamination and Decommissioning; this will be accomplished by establishing a passively safe and environmentally secure configuration, that can be preserved for several decades. This report presents the results of the mission analysis, which is required by Hanford systems engineering procedures

Communication dated 26 May 2009 received from the Permanent Mission of Austria to the Agency enclosing a working paper regarding Multilateralisation of the Nuclear Fuel Cycle

International Nuclear Information System (INIS)

2009-01-01

The Secretariat has received a communication dated 26 May 2009 from the Permanent Mission of Austria, transmitting a working paper entitled 'Multilateralisation of the Nuclear Fuel Cycle: Increasing Transparency and Sustainable Security'. The working paper is based on a food-for-thought paper previously submitted by Austria on 10 May 2007, and issued as INFCIRC/706. As requested in that communication, the working paper is herewith circulated for the information of all Member States

Feasibility study on AFR-100 fuel conversion from uranium-based fuel to thorium-based fuel

Energy Technology Data Exchange (ETDEWEB)

Heidet, F.; Kim, T.; Grandy, C. (Nuclear Engineering Division)

2012-07-30

best core performance characteristics for each of them. With the exception of the fuel type and enrichment, the reference AFR-100 core design characteristics were kept unchanged, including the general core layout and dimensions, assembly dimensions, materials and power rating. In addition, the mass of {sup 235}U required was kept within a reasonable range from that of the reference AFR-100 design. The core performance characteristics, kinetics parameters and reactivity feedback coefficients were calculated using the ANL suite of fast reactor analysis code systems. Orifice design calculations and the steady-state thermal-hydraulic analyses were performed using the SE2-ANL code. The thermal margins were evaluated by comparing the peak temperatures to the design limits for parameters such as the fuel melting temperature and the fuel-cladding eutectic temperature. The inherent safety features of AFR-100 cores proposed were assessed using the integral reactivity parameters of the quasi-static reactivity balance analysis. The design objectives and requirements, the computation methods used as well as a description of the core concept are provided in Section 2. The three major approaches considered are introduced in Section 3 and the neutronics performances of those approaches are discussed in the same section. The orifice zoning strategies used and the steady-state thermal-hydraulic performance are provided in Section 4. The kinetics and reactivity coefficients, including the inherent safety characteristics, are provided in Section 5, and the Conclusions in Section 6. Other scenarios studied and sensitivity studies are provided in the Appendix section.

A conceptual model for the fuel oxidation of defective fuel

International Nuclear Information System (INIS)

Higgs, J.D.; Lewis, B.J.; Thompson, W.T.; He, Z.

2007-01-01

A mechanistic conceptual model has been developed to predict the fuel oxidation behaviour in operating defective fuel elements for water-cooled nuclear reactors. This theoretical work accounts for gas-phase transport and sheath reactions in the fuel-to-sheath gap to determine the local oxygen potential. An improved thermodynamic analysis has also been incorporated into the model to describe the equilibrium state of the oxidized fuel. The fuel oxidation kinetics treatment accounts for multi-phase transport including normal diffusion and thermodiffusion for interstitial oxygen migration in the solid, as well as gas-phase transport in the fuel pellet cracks. The fuel oxidation treatment is further coupled to a heat conduction equation. A numerical solution of the coupled transport equations is obtained by a finite-element technique with the FEMLAB 3.1 software package. The model is able to provide radial-axial profiles of the oxygen-to-uranium ratio and the fuel temperatures as a function of time in the defective element for a wide range of element powers and defect sizes. The model results are assessed against coulometric titration measurements of the oxygen-to-metal profile for pellet samples taken from ten spent defective elements discharged from the National Research Universal Reactor at the Chalk River Laboratories and commercial reactors

Battery and Fuel Cell Development Goals for the Lunar Surface and Lander

Science.gov (United States)

Mercer, Carolyn R.

2008-01-01

NASA is planning a return to the moon and requires advances in energy storage technology for its planned lunar lander and lunar outpost. This presentation describes NASA s overall mission goals and technical goals for batteries and fuel cells to support the mission. Goals are given for secondary batteries for the lander s ascent stage and suits for extravehicular activity on the lunar surface, and for fuel cells for the lander s descent stage and regenerative fuel cells for outpost power. An overall approach to meeting these goals is also presented.

Growth Kinetics of Rhodococcus Erythropolis IGTS8 on Thiophene and Dimethylsulphoxide

International Nuclear Information System (INIS)

El-Temtamy, S.A.; Farahat, L.A.; Al-Shatnawi, D.F.; AI-Sayed, S.

2004-01-01

Sulfur oxides emissions through fossil fuel combustion posse environmental problems because these oxides are major cause of acid rain, which dissolve buildings, kills forests and poisons lakes. That is why world environmental regulations are becoming harder with respect to sulfur content in fossil fuels. The demand for new low-cost desulfurization technologies has led to renewed interest in bio desulfurization. In this work the growth kinetics of Rhodococcus Erythopolis IGTS8 have been studied on two model sulfur compounds that are found among other sulfur compounds in petroleum fractions. These are namely thiophene and dimethyl sulfoxide, DEMSO. Batch reactor and different substrate concentrations ranging between 1 and 8 gl -1 were used to study the growth kinetics. Growth on thiophene was shown to follow Monode kinetics with μ m ax =0.064 h -1 and K s = 2.8 gl -1 , on the other hand, growth on DEMSO was found to be substrate inhibited

Design and evaluation of aircraft heat source systems for use with high-freezing point fuels

Science.gov (United States)

Pasion, A. J.

1979-01-01

The objectives were the design, performance and economic analyses of practical aircraft fuel heating systems that would permit the use of high freezing-point fuels on long-range aircraft. Two hypothetical hydrocarbon fuels with freezing points of -29 C and -18 C were used to represent the variation from current day jet fuels. A Boeing 747-200 with JT9D-7/7A engines was used as the baseline aircraft. A 9300 Km mission was used as the mission length from which the heat requirements to maintain the fuel above its freezing point was based.

Sandia reactor kinetics codes: SAK and PK1D

International Nuclear Information System (INIS)

Pickard, P.S.; Odom, J.P.

1978-01-01

The Sandia Kinetics code (SAK) is a one-dimensional coupled thermal-neutronics transient analysis code for use in simulation of reactor transients. The time-dependent cross section routines allow arbitrary time-dependent changes in material properties. The one-dimensional heat transfer routines are for cylindrical geometry and allow arbitrary mesh structure, temperature-dependent thermal properties, radiation treatment, and coolant flow and heat-transfer properties at the surface of a fuel element. The Point Kinetics 1 Dimensional Heat Transfer Code (PK1D) solves the point kinetics equations and has essentially the same heat-transfer treatment as SAK. PK1D can address extended reactor transients with minimal computer execution time

Three-dimensional coupled kinetics/thermal- hydraulic benchmark TRIGA experiments

International Nuclear Information System (INIS)

Feltus, Madeline Anne; Miller, William Scott

2000-01-01

This research project provides separate effects tests in order to benchmark neutron kinetics models coupled with thermal-hydraulic (T/H) models used in best-estimate codes such as the Nuclear Regulatory Commission's (NRC) RELAP and TRAC code series and industrial codes such as RETRAN. Before this research project was initiated, no adequate experimental data existed for reactivity initiated transients that could be used to assess coupled three-dimensional (3D) kinetics and 3D T/H codes which have been, or are being developed around the world. Using various Test Reactor Isotope General Atomic (TRIGA) reactor core configurations at the Penn State Breazeale Reactor (PSBR), it is possible to determine the level of neutronics modeling required to describe kinetics and T/H feedback interactions. This research demonstrates that the small compact PSBR TRIGA core does not necessarily behave as a point kinetics reactor, but that this TRIGA can provide actual test results for 3D kinetics code benchmark efforts. This research focused on developing in-reactor tests that exhibited 3D neutronics effects coupled with 3D T/H feedback. A variety of pulses were used to evaluate the level of kinetics modeling needed for prompt temperature feedback in the fuel. Ramps and square waves were used to evaluate the detail of modeling needed for the delayed T/H feedback of the coolant. A stepped ramp was performed to evaluate and verify the derived thermal constants for the specific PSBR TRIGA core loading pattern. As part of the analytical benchmark research, the STAR 3D kinetics code (, STAR: Space and time analysis of reactors, Version 5, Level 3, Users Guide, Yankee Atomic Electric Company, YEAC 1758, Bolton, MA) was used to model the transient experiments. The STAR models were coupled with the one-dimensional (1D) WIGL and LRA and 3D COBRA (, COBRA IIIC: A digital computer program for steady-state and transient thermal-hydraulic analysis of rod bundle nuclear fuel elements, Battelle

Kinetics of palm kernel oil and ethanol transesterification

Energy Technology Data Exchange (ETDEWEB)

Ahiekpor, Julius C. [Centre for Energy, Environment and Sustainable Development (CEESD), P.O. Box FN 793, Kumasi (Ghana); Kuwornoo, David K. [Faculty of Chemical and Materials Engineering, Kwame Nkrumah University of Science and Technology (KNUST), Private Mail Bag, Kumasi (Ghana)

2010-07-01

Biodiesel, an alternative diesel fuel made from renewable sources such as vegetable oils and animal fats, has been identified by government to play a key role in the socio-economic development of Ghana. The utilization of biodiesel is expected to be about 10% of the total liquid fuel mix of the country by the year 2020. Despite this great potential and the numerous sources from which biodiesel could be developed in Ghana, there are no available data on the kinetics and mechanisms of transesterification of local vegetable oils. The need for local production of biodiesel necessitates that the mechanism and kinetics of the process is well understood, since the properties of the biodiesel depends on the type of oil use for the transesterification process. The objective of this work is to evaluate the appropriate kinetics mechanism and to find out the reaction rate constants for palm kernel oil transesterification with ethanol when KOH was used as a catalyst. In this present work, 16 biodiesel samples were prepared at specified times based on reported optimal conditions and the samples analysed by gas chromatography. The experimental mass fractions were calibrated and fitted to mathematical models of different proposed mechanisms in previous works.The rate data fitted well to second-order kinetics without shunt mechanism. It was also observed that, although transesterification reaction of crude palm kernel oil is a reversible reaction, the reaction rate constants indicated that the forward reactions were the most prominent.

An experimental and kinetic modeling study of glycerol pyrolysis

International Nuclear Information System (INIS)

Fantozzi, F.; Frassoldati, A.; Bartocci, P.; Cinti, G.; Quagliarini, F.; Bidini, G.; Ranzi, E.M.

2016-01-01

Highlights: • Glycerol pyrolysis can produce about 44–48%v hydrogen at 750–800 °C. • A simplified 452 reactions kinetic model of glycerol pyrolysis has been developed. • The model has good agreement with experimental data. • Non condensable gas yields can reach 70%. - Abstract: Pyrolysis of glycerol, a by-product of the biodiesel industry, is an important potential source of hydrogen. The obtained high calorific value gas can be used either as a fuel for combined heat and power (CHP) generation or as a transportation fuel (for example hydrogen to be used in fuel cells). Optimal process conditions can improve glycerol pyrolysis by increasing gas yield and hydrogen concentration. A detailed kinetic mechanism of glycerol pyrolysis, which involves 137 species and more than 4500 reactions, was drastically simplified and reduced to a new skeletal kinetic scheme of 44 species, involved in 452 reactions. An experimental campaign with a batch pyrolysis reactor was properly designed to further validate the original and the skeletal mechanisms. The comparisons between model predictions and experimental data strongly suggest the presence of a catalytic process promoting steam reforming of methane. High pyrolysis temperatures (750–800 °C) improve process performances and non-condensable gas yields of 70%w can be achieved. Hydrogen mole fraction in pyrolysis gas is about 44–48%v. The skeletal mechanism developed can be easily used in Computational Fluid Dynamic software, reducing the simulation time.

Fuel transfer cask concept design for reactor TRIGA PUSPATI (RTP)

International Nuclear Information System (INIS)

Ahmad Nabil Ab Rahim; Phongsakorn Prak; Tonny Lanyau; Mohd Fazli Zakaria

2010-01-01

Reactor Triga PUSPATI (RTP) has been operated since 1982 till now. For such long period, the organization feels the need to upgrade the power from 1 MW to 3 MW which involved changing new fuels. Spent fuels will be stored in a Spent Fuel Pool. The process of transferring spent fuels into Spent Fuels Pool required a fuel transfer cask. This paper discussed the design concept for the fuel transfer cast which is essential equipment for reactor upgrading mission. (author)

Adsorption isotherms and kinetics for dibenzothiophene on activated

Indian Academy of Sciences (India)

Adsorption isotherms were obtained and desulphurization kinetics were carried out on solutions of dibenzothiophene (DBT) and thiophene in a model fuel. The efficiencies of DBT and thiophene removal were reported. The adsorption isotherms fitted the Langmuir and Freundlich models. The highest adsorption capacity for ...

Oxidation kinetic changes of UO2 by additive addition and irradiation

International Nuclear Information System (INIS)

You, Gil-Sung; Kim, Keon-Sik; Min, Duck-Kee; Ro, Seung-Gy

2000-01-01

The kinetic changes of air-oxidation of UO 2 by additive addition and irradiation were investigated. Several kinds of specimens, such as unirradiated-UO 2 , simulated-UO 2 for spent PWR fuel (SIMFUEL), unirradiated-Gd-doped UO 2 , irradiated-UO 2 and -Gd-doped UO 2 , were used for these experiments. The oxidation results represented that the kinetic patterns among those samples are remarkably different. It was also revealed that the oxidation kinetics of irradiated-UO 2 seems to be more similar to that of unirradiated-Gd-doped UO 2 than that of SIMFUEL

Hydrogen as a fuel for fuel cell vehicles: A technical and economic comparison

Energy Technology Data Exchange (ETDEWEB)

Ogden, J.; Steinbugler, M.; Kreutz, T. [Princeton Univ., NJ (United States). Center for Energy and Environmental Studies

1997-12-31

All fuel cells currently being developed for near term use in vehicles require hydrogen as a fuel. Hydrogen can be stored directly or produced onboard the vehicle by reforming methanol, ethanol or hydrocarbon fuels derived from crude oil (e.g., Diesel, gasoline or middle distillates). The vehicle design is simpler with direct hydrogen storage, but requires developing a more complex refueling infrastructure. In this paper, the authors compare three leading options for fuel storage onboard fuel cell vehicles: compressed gas hydrogen storage; onboard steam reforming of methanol; onboard partial oxidation (POX) of hydrocarbon fuels derived from crude oil. Equilibrium, kinetic and heat integrated system (ASPEN) models have been developed to estimate the performance of onboard steam reforming and POX fuel processors. These results have been incorporated into a fuel cell vehicle model, allowing us to compare the vehicle performance, fuel economy, weight, and cost for various fuel storage choices and driving cycles. A range of technical and economic parameters were considered. The infrastructure requirements are also compared for gaseous hydrogen, methanol and hydrocarbon fuels from crude oil, including the added costs of fuel production, storage, distribution and refueling stations. Considering both vehicle and infrastructure issues, the authors compare hydrogen to other fuel cell vehicle fuels. Technical and economic goals for fuel cell vehicle and hydrogen technologies are discussed. Potential roles for hydrogen in the commercialization of fuel cell vehicles are sketched.

Electron Heating at Kinetic Scales in Magnetosheath Turbulence

International Nuclear Information System (INIS)

Chasapis, Alexandros; Matthaeus, W. H.; Parashar, T. N.; LeContel, O.; Retinò, A.; Breuillard, H.; Khotyaintsev, Y.; Vaivads, A.; Eriksson, E.; Lavraud, B.; Moore, T. E.; Burch, J. L.; Torbert, R. B.; Chutter, M.; Needell, J.; Lindqvist, P.-A.; Marklund, G.; Ergun, R. E.; Goodrich, K. A.; Wilder, F. D.

2017-01-01

We present a statistical study of coherent structures at kinetic scales, using data from the Magnetospheric Multiscale mission in the Earth’s magnetosheath. We implemented the multi-spacecraft partial variance of increments (PVI) technique to detect these structures, which are associated with intermittency at kinetic scales. We examine the properties of the electron heating occurring within such structures. We find that, statistically, structures with a high PVI index are regions of significant electron heating. We also focus on one such structure, a current sheet, which shows some signatures consistent with magnetic reconnection. Strong parallel electron heating coincides with whistler emissions at the edges of the current sheet.

Primary Reference Fuels (PRFs) as Surrogates for Low Sensitivity Gasoline Fuels

KAUST Repository

Bhavani Shankar, Vijai Shankar; Sajid, Muhammad Bilal; Al-Qurashi, Khalid; Atef, Nour; Al Khesho, Issam; Ahmed, Ahfaz; Chung, Suk-Ho; Roberts, William L.; Morganti, Kai; Sarathy, Mani

2016-01-01

This study presents an experimental evaluation of PRF surrogates for four real gasoline fuels termed FACE (Fuels for Advanced Combustion Engines) A, C, I, and J in a motored CFR (Cooperative Fuels Research) engine. This approach enables the surrogate mixtures to be evaluated purely from a chemical kinetic perspective. The gasoline fuels considered in this study have very low sensitivities, S (RON-MON), and also exhibit two-stage ignition behavior. The first stage heat release, which is termed Low Temperature Heat Release (LTHR), controls the combustion phasing in this operating mode. As a result, the performance of the PRF surrogates was evaluated by its ability to mimic the low temperature chemical reactivity of the real gasoline fuels. This was achieved by comparing the LTHR from the engine pressure histories. The PRF surrogates were able to consistently reproduce the amount of LTHR, closely match the phasing of LTHR, and the compression ratio for the start of hot ignition of the real gasoline fuels. This suggests that the octane quality of a surrogate fuel is a good indicator of the fuel’s reactivity across low (LTC), negative temperature coefficient (NTC), and high temperature chemical (HTC) reactivity regimes.

Modeling Of Proton Exchange Membrane Fuel Cell Systems

DEFF Research Database (Denmark)

Nielsen, Mads Pagh

The objective of this doctoral thesis was to develop reliable steady-state and transient component models suitable to asses-, develop- and optimize proton exchange membrane (PEM) fuel cell systems. Several components in PEM fuel cell systems were characterized and modeled. The developed component...... cell systems. Consequences of indirectly fueling PEM stacks with hydrocarbons using reforming technology were investigated using a PEM stack model including CO poisoning kinetics and a transient Simulink steam reforming system model. Aspects regarding the optimization of PEM fuel cell systems...

Architecture Study for a Fuel Depot Supplied from Lunar Assets

Science.gov (United States)

Perrin, Thomas M.; Casler, James G.

2016-01-01

This architecture study sought to determine the optimum architecture for a fuel depot supplied from lunar assets. Four factors - the location of propellant processing (on the Moon or on the depot), the depot location (on the Moon, L1, GEO, or LEO), the propellant transfer location (L1, GEO, or LEO), and the propellant transfer method (bulk fuel or canister exchange) were combined to identify 18 candidate architectures. Two design reference missions (DRMs) - a commercial satellite servicing mission and a Government cargo mission to Mars - created demand for propellants, while a propellant delivery DRM examined supply issues. The study concluded Earth-Moon L1 is the best location for an orbiting depot. For all architectures, propellant boiloff was less than anticipated, and was far overshadowed by delta-v requirements and resulting fuel consumption. Bulk transfer is the most flexible for both the supplier and customer. However, since canister exchange bypasses the transfer of bulk cryogens and necessary chilldown losses, canister exchange shows promise and merits further investigation. Overall, this work indicates propellant consumption and loss is an essential factor in assessing fuel depot architectures.

Study of kinetics of extraction of actinides in processes of reprocessing of nuclear fuels

International Nuclear Information System (INIS)

Lamotte, Claude

1978-01-01

This research thesis reports a bibliographical study on extraction kinetics. After some generalities on solvent-based extraction, and on the chemistry of actinides in solution, on the methods of kinetics study which are generally used and their mathematical treatments, the author compares the published results for the extraction kinetics of nitric acid, uranium VI, uranium IV, neptunium IV and plutonium IV [fr

Reducing DoD Fossil-Fuel Dependence

Science.gov (United States)

2006-09-01

domestic market for demand and consumption of fossil fuel alternatives, or to drive fuel and transportation technology developments, in general. Barring...wholesale to the power market . IPPs own and operate their stations as non-utilities and do not own the transmission lines. Joule The (kinetic) energy acquired...maturiry for its seed. [Wikipedia, 13Aug06] TW Terawatt = 1012 Watts UAV Unmanned/Unpiloted Air Vehicle UCG Underground coal gasification USDA U.S

Modelling the release behaviour of cesium during severe fuel degradation

International Nuclear Information System (INIS)

Lewis, B.J.; Andre, B.; Morel, B.

1995-01-01

An analytical model has been applied to describe the diffusional release of fission product cesium from Zircaloy-clad fuel under high-temperature reactor accident conditions. The present treatment accounts for the influence of the atmosphere (i.e., changing oxygen potential) on the state of fuel oxidation and the release kinetics. The effects of fuel dissolution on the volatile release behaviour (under reducing conditions) is considered in terms of earlier crucible experiments and a simple model based on bubble coalescence and transport in metal pools. The model has been used to interpret the cesium release kinetics observed in steam and hydrogen experiments at the Vertical Irradiation (VI) Facility in the Oak Ridge National Laboratory and at the HEVA/VERCORS Facility in the Commissariat a l'Energie Atomique. (author)

Diesel Surrogate Fuels for Engine Testing and Chemical-Kinetic Modeling: Compositions and Properties.

Science.gov (United States)

Mueller, Charles J; Cannella, William J; Bays, J Timothy; Bruno, Thomas J; DeFabio, Kathy; Dettman, Heather D; Gieleciak, Rafal M; Huber, Marcia L; Kweon, Chol-Bum; McConnell, Steven S; Pitz, William J; Ratcliff, Matthew A

2016-02-18

The primary objectives of this work were to formulate, blend, and characterize a set of four ultralow-sulfur diesel surrogate fuels in quantities sufficient to enable their study in single-cylinder-engine and combustion-vessel experiments. The surrogate fuels feature increasing levels of compositional accuracy (i.e., increasing exactness in matching hydrocarbon structural characteristics) relative to the single target diesel fuel upon which the surrogate fuels are based. This approach was taken to assist in determining the minimum level of surrogate-fuel compositional accuracy that is required to adequately emulate the performance characteristics of the target fuel under different combustion modes. For each of the four surrogate fuels, an approximately 30 L batch was blended, and a number of the physical and chemical properties were measured. This work documents the surrogate-fuel creation process and the results of the property measurements.

Review of alternative fuels data bases

Science.gov (United States)

Harsha, P. T.; Edelman, R. B.

1983-01-01

Based on an analysis of the interaction of fuel physical and chemical properties with combustion characteristics and indicators, a ranking of the importance of various fuel properties with respect to the combustion process was established. This ranking was used to define a suite of specific experiments whose objective is the development of an alternative fuels design data base. Combustion characteristics and indicators examined include droplet and spray formation, droplet vaporization and burning, ignition and flame stabilization, flame temperature, laminar flame speed, combustion completion, soot emissions, NOx and SOx emissions, and the fuels' thermal and oxidative stability and fouling and corrosion characteristics. Key fuel property data is found to include composition, thermochemical data, chemical kinetic rate information, and certain physical properties.

A calculational study on neutron kinetics and thermodynamics of a gaseous core fission reactor

International Nuclear Information System (INIS)

Kuijper, J.C.

1992-06-01

A numerical and analytical study of the static and dynamic properties of a GCFR with oscillating fuel gas (uranium and carbon fluorides) is presented. Neutron kinetics parts of combined GCFR models are introduced. Thermodynamic properties of the GCFR and of the fuel gas are treated. (HP)

High temperature mechanisms and kinetics of SiC oxidation under low partial pressures of oxygen: application to the fuel cladding of gas fast reactors

International Nuclear Information System (INIS)

Hun, N.

2011-01-01

Gas Fast Reactor (GFR) is one of the different Generation IV concepts under investigation for energy production. SiC/SiC composites are candidates of primary interest for a GFR fuel cladding use, thanks to good corrosion resistance among other properties. The mechanisms and kinetics of SiC oxidation under operating conditions have to be identified and quantified as the corrosion can decrease the mechanical properties of the composite. An experimental device has been developed to study the oxidation of silicon carbide under high temperature and low oxygen partial pressure. The results pointed out that not only parabolic oxidation, but also interfacial reactions and volatilization occur under such conditions. After determining the kinetics of each mechanism, as functions of oxygen partial pressure and temperature, the data are used for the modeling of the composites oxidation. The model will be used to predict the lifetime of the composite in operating conditions. (author) [fr

Three-peat NREL Intern Pushes Boundaries of Early-Stage Fuels Research on

Science.gov (United States)

-Stage Fuels Research on Way to Master's Degree January 4, 2018 Woman preparing a fuel evaluation in a . Mission & Programs Awards History Leadership Community Education Center Economic Impact Environment

Kinetics of Chlorella protothecoides microalgal oil using base catalyst

Directory of Open Access Journals (Sweden)

Mukesh Kumar

2016-09-01

Full Text Available Due to continuous diminishing of fossil fuel resources and emission of greenhouse gases, the search for alternative fuels such as biodiesel and bioethanol has become inevitable. Biodiesel, also known as fatty acid methyl or ethyl ester, has emerged as a substitute for diesel because of similar fuel properties. Presently, biodiesel is produced from edible, non-edible and microalgal oil. Chlorella protothecoides (lipid content 14.6–57.8% is being investigated as the potential microalgae species owing to high oil content, less land area required for cultivation and faster growth rate. The present investigation shows the results of the kinetics of transesterification of C. protothecoides microalgal oil carried out at optimum conditions of catalyst concentration, reaction temperature, molar ratio and reaction time. The percentage of methyl ester yield is the only parameter chosen to carry out the optimum parameter and the kinetics of transesterification. The reaction rate constant was to be 0.0618 min−1. Furthermore, microalgal biodiesel is characterized for physico-chemical properties that are found to meet American (ASTM D6751 and Indian (IS 15607 standards, especially in cold flow properties and stability of conventional biodiesel.

Energy partitioning constraints at kinetic scales in low-β turbulence

Science.gov (United States)

Gershman, Daniel J.; F.-Viñas, Adolfo; Dorelli, John C.; Goldstein, Melvyn L.; Shuster, Jason; Avanov, Levon A.; Boardsen, Scott A.; Stawarz, Julia E.; Schwartz, Steven J.; Schiff, Conrad; Lavraud, Benoit; Saito, Yoshifumi; Paterson, William R.; Giles, Barbara L.; Pollock, Craig J.; Strangeway, Robert J.; Russell, Christopher T.; Torbert, Roy B.; Moore, Thomas E.; Burch, James L.

2018-02-01

Turbulence is a fundamental physical process through which energy injected into a system at large scales cascades to smaller scales. In collisionless plasmas, turbulence provides a critical mechanism for dissipating electromagnetic energy. Here, we present observations of plasma fluctuations in low-β turbulence using data from NASA's Magnetospheric Multiscale mission in Earth's magnetosheath. We provide constraints on the partitioning of turbulent energy density in the fluid, ion-kinetic, and electron-kinetic ranges. Magnetic field fluctuations dominated the energy density spectrum throughout the fluid and ion-kinetic ranges, consistent with previous observations of turbulence in similar plasma regimes. However, at scales shorter than the electron inertial length, fluctuation power in electron kinetic energy significantly exceeded that of the magnetic field, resulting in an electron-motion-regulated cascade at small scales. This dominance is highly relevant for the study of turbulence in highly magnetized laboratory and astrophysical plasmas.

Preliminary Thermohydraulic Analysis of a New Moderated Reactor Utilizing an LEU-Fuel for Space Nuclear Thermal Propulsion

International Nuclear Information System (INIS)

Nam, Seung Hyun; Choi, Jae Young; Venneria, Paolo F.; Jeong, Yong Hoon; Chang, Soon Heung

2015-01-01

The Korea Advanced NUclear Thermal Engine Rocket utilizing an LEU fuel (KANUTER-LEU) is a non-proliferative and comparably efficient NTR engine with relatively low thrust levels of 40 - 50 kN for in-space transportation. The small modular engine can expand mission versatility, when flexibly used in a clustered engine arrangement, so that it can perform various scale missions from low-thrust robotic science missions to high-thrust manned missions. In addition, the clustered engine system can enhance engine redundancy and ensuing crew safety as well as the thrust. The propulsion system is an energy conversion system to transform the thermal energy of the reactor into the kinetic energy of the propellant to produce the powers for thrust, propellant feeding and electricity. It is mainly made up of a propellant Feeding System (PFS) comprising a Turbo-Pump Assembly (TPA), a Regenerative Nozzle Assembly (RNA), etc. For this core design study, an expander cycle is assumed to be the propulsion system. The EGS converts the thermal energy of the EHTGR in the idle operation (only 350 kW th power) to electric power during the electric power mode. This paper presents a preliminary thermohydraulic design analysis to explore the design space for the new reactor and to estimate the referential engine performance. The new non-proliferative NTR engine concept, KANUTER-LEU, is under designing to surmount the nuclear proliferation obstacles on allR and Dactivities and eventual commercialization for future generations. To efficiently implement a heavy LEU fuel for the NTR engine, its reactor design innovatively possesses the key characteristics of the high U density fuel with high heating and H 2 corrosion resistances, the thermal neutron spectrum core and also minimizing non-fission neutron loss, and the compact reactor design with protectively cooling capability. To investigate feasible design space for the moderated EHTGR-LEU and resultant engine performance, the preliminary design

An Innovative Solution to NASA's NEO Impact Threat Mitigation Grand Challenge and Flight Validation Mission Architecture Development

Data.gov (United States)

National Aeronautics and Space Administration — A Hypervelocity Asteroid Intercept Vehicle (HAIV) mission architecture, which blends a hypervelocity kinetic impactor with a subsurface nuclear explosion for optimal...

Hydrogen and fuel cell research: Institute for Integrated Energy Systems (IESVic)

International Nuclear Information System (INIS)

Pitt, L.

2006-01-01

Vision: IESVic's mission is to chart feasible paths to sustainable energy. Current research areas of investigation: 1. Energy system analysis 2. Computational fuel cell engineering; Fuel cell parameter measurement; Microscale fuel cells 3. Hydrogen dispersion studies for safety codes 4. Active magnetic refrigeration for hydrogen liquifaction and heat transfer in metal hydrides 5. Hydrogen and fuel cell system integration (author)

Autoignition of liquid-fuel sprays

International Nuclear Information System (INIS)

Mitzutani, Y.

1991-01-01

This paper reports on the published autoignition data of liquid fuel sprays that were extensively reviewed by classifying them into the following three categories; liquid fuels injected into a stagnant hot atmosphere, liquid fuels injected into a hot air stream (vitiated or unvitiated), and droplet cluster ignited behind an incident or reflected shock. Comparison of these data with the counterparts of gaseous fuels and single droplets revealed that it was the ignition process dominated by droplet evaporation whereas it was the one dominated by chemical kinetics. It consisted, depending on the experimental condition, of the data and of the ignition process dominated by the shattering of droplets by an incident shock. In addition, theoretical works on spray autoignition were reviewed, pointing out that they were still far from universally predicting the ignition delays of liquid fuel sprays

Point kinetics model with one-dimensional (radial) heat conduction formalism

International Nuclear Information System (INIS)

Jain, V.K.

1989-01-01

A point-kinetics model with one-dimensional (radial) heat conduction formalism has been developed. The heat conduction formalism is based on corner-mesh finite difference method. To get average temperatures in various conducting regions, a novel weighting scheme has been devised. The heat conduction model has been incorporated in the point-kinetics code MRTF-FUEL. The point-kinetics equations are solved using the method of real integrating factors. It has been shown by analysing the simulation of hypothetical loss of regulation accident in NAPP reactor that the model is superior to the conventional one in accuracy and speed of computation. (author). 3 refs., 3 tabs

Fusion energy for space missions in the 21st Century

International Nuclear Information System (INIS)

Schulze, N.R.

1991-08-01

Future space missions were hypothesized and analyzed and the energy source for their accomplishment investigated. The mission included manned Mars, scientific outposts to and robotic sample return missions from the outer planets and asteroids, as well as fly-by and rendezvous mission with the Oort Cloud and the nearest star, Alpha Centauri. Space system parametric requirements and operational features were established. The energy means for accomplishing the High Energy Space Mission were investigated. Potential energy options which could provide the propulsion and electric power system and operational requirements were reviewed and evaluated. Fusion energy was considered to be the preferred option and was analyzed in depth. Candidate fusion fuels were evaluated based upon the energy output and neutron flux. Reactors exhibiting a highly efficient use of magnetic fields for space use while at the same time offering efficient coupling to an exhaust propellant or to a direct energy convertor for efficient electrical production were examined. Near term approaches were identified

A new improvement on a chemical kinetic model of primary reference fuel for multi-dimensional CFD simulation

International Nuclear Information System (INIS)

Zhen, Xudong; Wang, Yang; Liu, Daming

2016-01-01

Highlights: • A new optimized chemical kinetic mechanism for PRF is developed. • New mechanism optimization is performed based on the CHEMKIN simulations. • More reactions of C_0–C_1 oxidation are added in the present mechanism. • Good performance is achieved of mechanism by validating various reactors and operating conditions. - Abstract: In the present study, for the multi-dimensional CFD (computational fluid dynamics) combustion simulations of internal combustion engines, a new optimized chemical kinetic reaction mechanism for the oxidation of PRF (primary reference fuel) instead of gasoline has been developed. In order to carry out the in-depth research for combustion phenomenon of internal combustion engines, an optimized reduced PRF mechanism including more intermediate species and radicals was developed. The developed mechanism contains of iso-octane (C_8H_1_8) and n-heptane (C_7H_1_6) surrogates, which contains of 51-species and 193 reactions. Compared with many other mechanisms of PRF, more reactions of C_0–C_1 oxidation (100 reactions) are added in the present mechanism. In order to improve the performances of the model, the developed mechanism focused on the improvement through the prediction of the ignition delay time. The developed mechanism has been validated against various experimental and simulation data including shock tube data, laminar flame speed data and HCCI (homogeneous charge compression ignition) engine data. The results showed that the developed PRF mechanism was agreements with the experimental data and other approved reduced mechanisms, and it could be applied to the multi-dimensional CFD simulations for internal combustion engines.

Application of Detailed Chemical Kinetics to Combustion Instability Modeling

Science.gov (United States)

2016-01-04

Clearance Number 15692 Clearance Date 12/3/2015 14. ABSTRACT A comparison of a single step global reaction and the detailed GRI -Mech 1.2 for combustion...comparison of a single step global reaction and the detailed GRI -Mech 1.2 for com- bustion instability modeling in a methane-fueled longitudinal-mode...methane as the fuel. We use the GRI -Mech 1.2 kinetics mechanism for methane oxidation.11 The GRI -Mech 1.2 was chosen over 2.11 because the only

K-Rankine systems for piloted and cargo Mars missions

International Nuclear Information System (INIS)

Mills, J.C.; Rovang, R.D.; Johnson, G.A.

1992-03-01

Studies are performed to demonstrate the attractiveness of potassium-Rankine (K-Rankine) nuclear electric propulsion (NEP) systems for both piloted and cargo Mars missions. The key results of the piloted mission study are that a full-up piloted mission can be accomplished with a trip time of less than 390 days with an attractive initial mass in low earth orbit (IMLEO) of 700 metric tons. This is achieved by coupling two advanced cermet fuel reactors (1550 K outlet temperature) to K-Rankine power-conversion systems to produce the 46 MWe needed to power advanced ion engines. This design approach offers an alternative to a more risky split-sprint mission where comparable trip times and IMLEO can be achieved with a nearer-term reactor (SP-100 at 1350 K outlet temperature) technology. The results of the cargo-mission study indicate that a lower-power K-Rankine system (5.5 MWe) operating at SP-100 reactor conditions would best perform a representative Mars cargo transport. A round-trip mission (480 days outbound; 600 day return) to Mars requires only 225 metric tons IMLEO and permit possible system reuse. 6 refs

Study of LH2 fueled subsonic passenger transport aircraft

Science.gov (United States)

Brewer, G. D.; Morris, R. E.

1976-01-01

The potential of using liquid hydrogen as fuel in subsonic transport aircraft was investigated to explore an expanded matrix of passenger aircraft sizes. Aircraft capable of carrying 130 passengers 2,780 km (1500 n.mi.); 200 passengers 5,560 km (3000 n.mi.); and 400 passengers on a 9,265 km (5000 n.mi.) radius mission, were designed parametrically. Both liquid hydrogen and conventionally fueled versions were generated for each payload/range in order that comparisons could be made. Aircraft in each mission category were compared on the basis of weight, size, cost, energy utilization, and noise.

Kinetic interaction in hydrogenitrogenation of quinoline and acridine

International Nuclear Information System (INIS)

El-Bishtawi, R.F.; Seapan, M.

1988-01-01

Liquid fossil fuels contain numerous nitrogen compounds. During hydrodenitrogenation processes, these compounds for the active catalytic sites, with each compound affecting the kinetics of the other compounds. An understanding of the kinetic interaction is essential in using the results of model compound kinetics to predict the behavior of complex mixtures. In this work, the authors study the hydrodenitrogenation of quinoline and acridine in n-hexadecane over a commercial nickel-molybdenum catalyst in a batch autoclave reactor at 8.3 MPa (1200 psig) and 357-390 0 C. The reaction networks and kinetics of individual compounds were developed. These results confirm the existing knowledge of reaction networks for quinoline and acridine. Furthermore, their experiments show that formation for o-ethylaniline, o-toluidine and aniline are also important steps in quinoline denitrogenation. For total nitrogen removal, a dual site Langmuir-Hinshelwood type model considering separate sites for adsorption of hydrogen and nitrogen compounds give the best fit

Thermodynamic analysis and kinetic modelling of dioxin formation and emissions from power boilers firing salt-laden hog fuel.

Science.gov (United States)

Duo, Wenli; Leclerc, Denys

2007-04-01

Both organic chlorine (e.g. PVC) and inorganic chlorides (e.g. NaCl) can be significant chlorine sources for dioxin and furan (PCDD/F) formation in combustion processes. This paper presents a thermodynamic analysis of high temperature salt chemistry. Its influence on PCDD/F formation in power boilers burning salt-laden wood waste is examined through the relationships between Cl2, HCl, NaCl(g) and NaCl(c). These analyses show that while HCl is a product of combustion of PVC-laden municipal solid waste, NaCl can be converted to HCl in hog fuel boilers by reactions with SO2 or alumino-silicate materials. Cl2 is a strong chlorinating agent for PCDD/F formation. HCl can be oxidized to Cl2 by O2, and Cl2 can be reduced back to HCl by SO2. The presence of sulphur at low concentrations thus enhances PCDD/F formation by increasing HCl concentrations. At high concentrations, sulphur inhibits de novo formation of PCDD/Fs through Cl2 reduction by excess SO2. The effect of NH3, CO and NOx on PCDD/F formation is also discussed. A semi-empirical kinetic model is proposed. This model considers both precursor and de novo formation mechanisms. A simplified version is used as a stack emission model. The kinetic model indicates that stack dioxin emissions will increase linearly with decreasing electrostatic precipitator (ESP) efficiency and exponentially with increasing ESP temperature.

Thermal-hydraulic and neutron-physical characteristics of a new SCWR fuel assembly

International Nuclear Information System (INIS)

Liu, X.J.; Cheng, X.

2009-01-01

A new fuel assembly design for a thermal supercritical water cooled reactor (SCWR) core is proposed. Compared to the existing fuel assemblies, the present fuel assembly has two-rows of fuel rods between the moderator channels, to achieve a more uniform moderation for all fuel rod cells, and subsequently, a more uniform radial power distribution. In addition, a neutron-kinetics/thermal-hydraulics coupling method is developed, to analyze the neutron-physical and thermal-hydraulic behavior of the fuel assembly designs. This coupling method is based on the sub-channel analysis code COBRA-IV for thermal-hydraulics and the neutron-kinetics code SKETCH-N for neutron-physics. Both the COBRA-IV code and the SKETCH-N code are accordingly modified. An interface is established for the data transfer between these two codes. This coupling method is applied to both the one-row fuel assemblies (previous design) and the two-row fuel assemblies (present design). The performance of the two types of fuel assemblies is compared. The results show clearly that the two-row fuel assembly has more favorable neutron-physical and thermal-hydraulic characteristics than the one-row fuel assembly. The effect of various parameters on the fuel assembly performance is discussed. The coupling method is proven to be well suitable for further applications to SCWR fuel assembly design analysis

Phosphoric acid doped polybenzimidazole membranes: Physiochemical characterization and fuel cell applications [PEM fuel cells

DEFF Research Database (Denmark)

Qingfeng, Li; Hjuler, Hans Aage; Bjerrum, Niels

2001-01-01

A polymer electrolyte membrane fuel cell operational at temperatures around 150-200 degrees C is desirable for fast electrode kinetics and high tolerance to fuel impurities. For this purpose polybenzimidazole (PBI) membranes have been prepared and H/sub 3/PO/sub 4/-doped in a doping range from 300...... doping level. At 160 degrees C a conductivity as high as 0.13 S cm/sup -1/ is obtained for membranes of high doping levels. Mechanical strength measurements show, however, that a high acid doping level results in poor mechanical properties. At operational temperatures up to 190 degrees C, fuel cells...... based on this polymer membrane have been tested with both hydrogen and hydrogen containing carbon monoxide....

BILLIARDS: A Demonstration Mission for Hundred-Meter Class Near-Earth Asteroid Disruption

Science.gov (United States)

Marcus, Matthew; Sloane, Joshua; Ortiz, Oliver; Barbee, Brent William

2015-01-01

Collisions from near-Earth asteroids (NEAs) have the potential to cause widespread harm to life on Earth. The hypervelocity nature of these collisions means that a relatively small asteroid (about a quartermile in diameter) could cause a global disaster. Proposed strategies for deflecting or disrupting such a threatening asteroid include detonation of a nuclear explosive device (NED) in close proximity to the asteroid, as well as intercepting the asteroid with a hypervelocity kinetic impactor. NEDs allow for the delivery of large amounts of energy to a NEA for a given mass launched from the Earth, but have not yet been developed or tested for use in deep space. They also present safety and political complications, and therefore may only be used when absolutely necessary. Kinetic impactors require a relatively simple spacecraft compared to NEDs, but also deliver a much lower energy for a given launch mass. To date, no demonstration mission has been conducted for either case, and such a demonstration mission must be conducted prior to the need to utilize them during an actual scenario to ensure that an established, proven system is available for planetary defense when the need arises. One method that has been proposed to deliver a kinetic impactor with impact energy approaching that of an NED is the "billiard-ball" approach. This approach would involve capturing an asteroid approximately ten meters in diameter with a relatively small spacecraft (compared to the launch mass of an equivalent direct kinetic impactor), and redirecting it into the path of an Earth-threatening asteroid. This would cause an impact which would disrupt the Earth-threatening asteroid or deflect it from its Earth-crossing trajectory. The BILLIARDS Project seeks to perform a demonstration of this mission concept in order to establish a protocol that can be used in the event of an impending Earth/asteroid collision. In order to accomplish this objective, the mission must (1) rendezvous with a

A performance comparison of urban utility vehicles powered with IC engine and solid polymer fuel cell technologies

International Nuclear Information System (INIS)

Teachman, M.E.; Scott, D.S.

1993-01-01

Utility vehicles provide ground transportation for crew and electric power at work sites that lack grid supply. The performances of utility vehicles designed with conventional architectures (spark ignition engine for propulsion and a motor generator for electric power) and with a fuel cell/battery architectures, are compared over a range of vehicle missions. Results indicate that fuel cell/battery hybrid systems are lighter than conventional systems for missions requiring short driving distances and work site power levels exceeding 10 kW. Conventional spark ignition engine/gen-set power systems are lighter for missions requiring more than 1 hour of driving and less than 10 kW of work site power. Fuel cell/battery systems are more efficient than spark ignition engine/gen-set systems for all missions. 7 figs., 3 tabs., 20 refs

Recent Trends in the Production, Combustion and Modeling of Furan-Based Fuels

Directory of Open Access Journals (Sweden)

Mazen A. Eldeeb

2018-02-01

Full Text Available There is growing interest in the use of furans, a class of alternative fuels derived from biomass, as transportation fuels. This paper reviews recent progress in the characterization of its combustion properties. It reviews their production processes, theoretical kinetic explorations and fundamental combustion properties. The theoretical efforts are focused on the mechanistic pathways for furan decomposition and oxidation, as well as the development of detailed chemical kinetic models. The experiments reviewed are mostly concerned with the temporal evolutions of homogeneous reactors and the propagation of laminar flames. The main thrust in homogeneous reactors is to determine global chemical time scales such as ignition delay times. Some studies have adopted a comparative approach to bring out reactivity differences. Chemical kinetic models with varying degrees of predictive success have been established. Experiments have revealed the relative behavior of their combustion. The growing body of literature in this area of combustion chemistry of alternative fuels shows a great potential for these fuels in terms of sustainable production and engine performance. However, these studies raise further questions regarding the chemical interactions of furans with other hydrocarbons. There are also open questions about the toxicity of the byproducts of combustion.

Kinetic analysis of nitric oxide reduction using biogas as reburning fuel

African Journals Online (AJOL)

Biogas was suggested more suitable as reburning fuel to reduce NO emission and Miller-Bowan's mechanism was performed to analyze the effect of reaction environment in the process of biogas reburning. Results show that the NO reduction efficiency increased with the increase of hydrocarbon in biogas, reburning fuel ...

Experimental study of the kinetics of dry, forward combustion. Final report

Energy Technology Data Exchange (ETDEWEB)

Thomas, G.W.; Buthod, A.P.; Allag, O.

1979-02-01

Results are presented of an experimental investigation of dry, forward combustion with two main objectives, viz, (1) to develop a method for determining the kinetic perameters of fuel laydown and burnoff from combustion tube data, and (2) to evaluate them for a particular crude-sand mixture. In the light of past experimental work, a two-step chain reaction model is postulated in which fuel laydown and burnoff are considered as competitive kinetic reactions. Laboratory equipment consisting of a combustion tube assembly and sampling probe, a flow control system, an electronic control assembly, and a fluid analysis system are described in detail. The sampling probe provides a novel method for taking fluid samples at selected interior points within the combustion cell. Six experimental runs were performed using a 27/sup 0/ API Prudhoe Bay crude. Analyses of the data indicte that, in addition to the coke residue, some light ends of the crude enter into the total fuel consumed by the burning zone. The use of the moveable sampling probe permitted the reconstruction of CO + CO/sub 2/ production rate curves as functions of time and distance. A technique is presented for solving the integral equation and estimating the activation energies, pre-exponential factors, and some associated constants for fuel deposition and combustion. It was found that operating pressure has essentially no effect on the exponential energy, but it does affect the preexponential (or frequency) factor. It is concluded that the essential phenomena of forward combustion can be adequately depicted by the two-step chain reaction concept, and that kinetic data,or their bounds, can be determined from combustion tube data.

ELECTROCHEMICAL STUDIES OF URANIUM METAL CORROSION MECHANISM AND KINETICS IN WATER

International Nuclear Information System (INIS)

Boudanova, Natalya; Maslennikov, Alexander; Peretroukhine, Vladimir F.; Delegard, Calvin H.

2006-01-01

During long-term underwater storage of low burn-up uranium metal fuel, a corrosion product sludge forms containing uranium metal grains, uranium dioxide, uranates and, in some cases, uranium peroxide. Literature data on the corrosion of non-irradiated uranium metal and its alloys do not allow unequivocal prediction of the paragenesis of irradiated uranium in water. The goal of the present work conducted under the program 'CORROSION OF IRRADIATED URANIUM ALLOYS FUEL IN WATER' is to study the corrosion of uranium and uranium alloys and the paragenesis of the corrosion products during long-term underwater storage of uranium alloy fuel irradiated at the Hanford Site. The elucidation of the physico-chemical nature of the corrosion of irradiated uranium alloys in comparison with non-irradiated uranium metal and its alloys is one of the most important aspects of this work. Electrochemical methods are being used to study uranium metal corrosion mechanism and kinetics. The present part of work aims to examine and revise, where appropriate, the understanding of uranium metal corrosion mechanism and kinetics in water

Dynamic analysis and application of fuel elements pneumatic transportation in a pebble bed reactor

International Nuclear Information System (INIS)

Liu, Hongbing; Du, Dong; Han, Zandong; Zou, Yirong; Pan, Jiluan

2015-01-01

Almost 10,000 spherical fuel elements are transported pneumatically one by one in the pipeline outside the core of a pebble bed reactor every day. Any failure in the transportation will lead to the shutdown of the reactor, even safety accidents. In order to ensure a stable and reliable transportation, it's of great importance to analyze the motion and force condition of the fuel element. In this paper, we focus on the dynamic analysis of the pneumatic transportation of the fuel element and derive kinetic equations. Then we introduce the design of the transportation pipeline. On this basis we calculate some important data such as the velocity of the fuel element, the force between the fuel element and the pipeline and the efficiency of the pneumatic transportation. Then we analyze these results and provide some suggestions for the design of the pipeline. The experiment was carried out on an experimental platform. The velocities of the fuel elements were measured. The experimental results were consistent with and validated the theoretical analysis. The research may offer the basis for the design of the transportation pipeline and the optimization of the fuel elements transportation in a pebble bed reactor. - Highlights: • The kinetic equations of the fuel element in pneumatic transportation are derived. • The dynamic characteristics of the fuel element are analyzed. • Some important parameters are calculated based on the kinetic equations. • The experimental results were consistent with the analysis and verified the analysis. • This paper may offer an important guide to the research of a pebble bed reactor

The Decomposition of Surrogate Fuel Molecules During Combustion

National Research Council Canada - National Science Library

Tsang, Wing; Manion, Jeffrey A

2006-01-01

This project is aimed at developing a chemical kinetic database consisting of the rate constants of fundamental single step reactions that describe the pyrolytic decomposition of surrogate fuels molecules...

FUNDAMENTAL INVESTIGATION OF FUEL TRANSFORMATIONS IN PULVERIZED COAL COMBUSTION AND GASIFICATION TECHNOLOGIES

Energy Technology Data Exchange (ETDEWEB)

Robert Hurt; Joseph Calo; Thomas H. Fletcher; Alan Sayre

2005-04-29

The goal of this project was to carry out the necessary experiments and analyses to extend current capabilities for modeling fuel transformations to the new conditions anticipated in next-generation coal-based, fuel-flexible combustion and gasification processes. This multi-organization, multi-investigator project has produced data, correlations, and submodels that extend present capabilities in pressure, temperature, and fuel type. The combined experimental and theoretical/computational results are documented in detail in Chapters 1-8 of this report, with Chapter 9 serving as a brief summary of the main conclusions. Chapters 1-3 deal with the effect of elevated pressure on devolatilization, char formation, and char properties. Chapters 4 and 5 deal with advanced combustion kinetic models needed to cover the extended ranges of pressure and temperature expected in next-generation furnaces. Chapter 6 deals with the extension of kinetic data to a variety of alternative solid fuels. Chapter 7 focuses on the kinetics of gasification (rather than combustion) at elevated pressure. Finally, Chapter 8 describes the integration, testing, and use of new fuel transformation submodels into a comprehensive CFD framework. Overall, the effects of elevated pressure, temperature, heating rate, and alternative fuel use are all complex and much more work could be further undertaken in this area. Nevertheless, the current project with its new data, correlations, and computer models provides a much improved basis for model-based design of next generation systems operating under these new conditions.

Application of the monolithic solid oxide fuel cell to space power systems

International Nuclear Information System (INIS)

Myles, K.M.; Bhattacharyya, S.K.

1991-01-01

The monolithic solid-oxide fuel cell (MSOFC) is a promising electrochemical power generation device that is currently under development at Argonne National Laboratory. The extremely high power density of the MSOFC leads to MSOFC systems that have sufficiently high energy densities that they are excellent candidates for a number of space missions. The fuel cell can also be operated in reverse, if it can be coupled to an external power source, to regenerate the fuel and oxidant from the water product. This feature further enhances the potential mission applications of the MSOFC. In this paper, the current status of the fuel cell development is presented---the focus being on fabrication and currently achievable performance. In addition, a specific example of a space power system, featuring a liquid metal cooled fast spectrum nuclear reactor and a monolithic solid oxide fuel cell, is presented to demonstrate the features of an integrated system

Application of the monolithic solid oxide fuel cell to space power systems

Science.gov (United States)

Myles, Kevin M.; Bhattacharyya, Samit K.

1991-01-01

The monolithic solid-oxide fuel cell (MSOFC) is a promising electrochemical power generation device that is currently under development at Argonne National Laboratory. The extremely high power density of the MSOFC leads to MSOFC systems that have sufficiently high energy densities that they are excellent candidates for a number of space missions. The fuel cell can also be operated in reverse, if it can be coupled to an external power source, to regenerate the fuel and oxidant from the water product. This feature further enhances the potential mission applications of the MSOFC. In this paper, the current status of the fuel cell development is presented—the focus being on fabrication and currently achievable performance. In addition, a specific example of a space power system, featuring a liquid metal cooled fast spectrum nuclear reactor and a monolithic solid oxide fuel cell, is presented to demonstrate the features of an integrated system.

Advanced fuels campaign 2013 accomplishments

Energy Technology Data Exchange (ETDEWEB)

Braase, Lori [Idaho National Lab. (INL), Idaho Falls, ID (United States); Hamelin, Doug [Idaho National Lab. (INL), Idaho Falls, ID (United States)

2013-10-01

The mission of the Advanced Fuels Campaign (AFC) is to perform Research, Development, and Demonstration (RD&D) activities for advanced fuel forms (including cladding) to enhance the performance and safety of the nation’s current and future reactors; enhance proliferation resistance of nuclear fuel; effectively utilize nuclear energy resources; and address the longer-term waste management challenges. This includes development of a state-of-the art Research and Development (R&D) infrastructure to support the use of “goal-oriented science-based approach.” In support of the Fuel Cycle Research and Development (FCRD) program, AFC is responsible for developing advanced fuels technologies to support the various fuel cycle options defined in the Department of Energy (DOE) Nuclear Energy Research and Development Roadmap, Report to Congress, April 2010. Accomplishments made during fiscal year (FY) 2013 are highlighted in this report, which focuses on completed work and results. The process details leading up to the results are not included; however, the technical contact is provided for each section.

Spent nuclear fuel project integrated schedule plan

International Nuclear Information System (INIS)

Squires, K.G.

1995-01-01

The Spent Nuclear Fuel Integrated Schedule Plan establishes the organizational responsibilities, rules for developing, maintain and status of the SNF integrated schedule, and an implementation plan for the integrated schedule. The mission of the SNFP on the Hanford site is to provide safe, economic, environmentally sound management of Hanford SNF in a manner which stages it to final disposition. This particularly involves K Basin fuel

Spent nuclear fuel project integrated schedule plan

Energy Technology Data Exchange (ETDEWEB)

Squires, K.G.

1995-03-06

The Spent Nuclear Fuel Integrated Schedule Plan establishes the organizational responsibilities, rules for developing, maintain and status of the SNF integrated schedule, and an implementation plan for the integrated schedule. The mission of the SNFP on the Hanford site is to provide safe, economic, environmentally sound management of Hanford SNF in a manner which stages it to final disposition. This particularly involves K Basin fuel.

Advances in nuclear fuel technology. 3. Development of advanced nuclear fuel recycle systems

International Nuclear Information System (INIS)

Arie, Kazuo; Abe, Tomoyuki; Arai, Yasuo

2002-01-01

Fast breeder reactor (FBR) cycle technology has a technical characteristics flexibly easy to apply to diverse fuel compositions such as plutonium, minor actinides, and so on and fuel configurations. By using this characteristics, various feasibilities on effective application of uranium resources based on breeding of uranium of plutonium for original mission of FBR, contribution to radioactive wastes problems based on amounts reduction of transuranium elements (TRU) in high level radioactive wastes, upgrading of nuclear diffusion resistance, extremely upgrading of economical efficiency, and so on. In this paper, were introduced from these viewpoints, on practice strategy survey study on FBR cycle performed by cooperation of the Japan Nuclear Cycle Development Institute (JNC) with electric business companies and so on, and on technical development on advanced nuclear fuel recycle systems carried out at the Central Research Institute of Electric Power Industry, Japan Atomic Energy Research Institute, and so on. Here were explained under a vision on new type of fuels such as nitride fuels, metal fuels, and so on as well as oxide fuels, a new recycle system making possible to use actinides except uranium and plutonium, an 'advanced nuclear fuel cycle technology', containing improvement of conventional wet Purex method reprocessing technology, fuel manufacturing technology, and so on. (G.K.)

Transportation Packages to Support Savannah River Site Missions

International Nuclear Information System (INIS)

Opperman, E.

2001-01-01

The Savannah River Site's missions have expanded from primarily a defense mission to one that includes environmental cleanup and the stabilization, storage, and preparation for final disposition of nuclear materials. The development of packaging and the transportation of radioactive materials are playing an ever-increasing role in the successful completion of the site's missions. This paper describes the Savannah River Site and the three strategic mission areas of (1) nuclear materials stewardship, (2) environmental stewardship, and (3) nuclear weapons stockpile stewardship. The materials and components that need to be shipped, and associated packaging, will be described for each of the mission areas. The diverse range of materials requiring shipment include spent fuel, irradiated target assemblies, excess plutonium and uranium materials, high level waste canisters, transuranic wastes, mixed and low level wastes, and nuclear weapons stockpile materials and components. Since many of these materials have been in prolonged storage or resulted from disassembly of components, the composition, size and shape of the materials present packaging and certification challenges that need to be met. Over 30 different package designs are required to support the site's missions. Approximately 15 inbound shipping-legs transport materials into the Savannah River Site and the same number (15) of outgoing shipment-legs are carrying materials from the site for further processing or permanent disposal

Modeling the homogenization kinetics of as-cast U-10wt% Mo alloys

Energy Technology Data Exchange (ETDEWEB)

Xu, Zhijie, E-mail: zhijie.xu@pnnl.gov [Computational Mathematics Group, Pacific Northwest National Laboratory, Richland, WA 99352 (United States); Joshi, Vineet [Energy Processes & Materials Division, Pacific Northwest National Laboratory, Richland, WA 99352 (United States); Hu, Shenyang [Reactor Materials & Mechanical Design, Pacific Northwest National Laboratory, Richland, WA 99352 (United States); Paxton, Dean [Nuclear Engineering and Analysis Group, Pacific Northwest National Laboratory, Richland, WA 99352 (United States); Lavender, Curt [Energy Processes & Materials Division, Pacific Northwest National Laboratory, Richland, WA 99352 (United States); Burkes, Douglas [Nuclear Engineering and Analysis Group, Pacific Northwest National Laboratory, Richland, WA 99352 (United States)

2016-04-01

Low-enriched U-22at% Mo (U–10Mo) alloy has been considered as an alternative material to replace the highly enriched fuels in research reactors. For the U–10Mo to work effectively and replace the existing fuel material, a thorough understanding of the microstructure development from as-cast to the final formed structure is required. The as-cast microstructure typically resembles an inhomogeneous microstructure with regions containing molybdenum-rich and -lean regions, which may affect the processing and possibly the in-reactor performance. This as-cast structure must be homogenized by thermal treatment to produce a uniform Mo distribution. The development of a modeling capability will improve the understanding of the effect of initial microstructures on the Mo homogenization kinetics. In the current work, we investigated the effect of as-cast microstructure on the homogenization kinetics. The kinetics of the homogenization was modeled based on a rigorous algorithm that relates the line scan data of Mo concentration to the gray scale in energy dispersive spectroscopy images, which was used to generate a reconstructed Mo concentration map. The map was then used as realistic microstructure input for physics-based homogenization models, where the entire homogenization kinetics can be simulated and validated against the available experiment data at different homogenization times and temperatures.

Fuel Cell Stations Automate Processes, Catalyst Testing

Science.gov (United States)

2010-01-01

Glenn Research Center looks for ways to improve fuel cells, which are an important source of power for space missions, as well as the equipment used to test fuel cells. With Small Business Innovation Research (SBIR) awards from Glenn, Lynntech Inc., of College Station, Texas, addressed a major limitation of fuel cell testing equipment. Five years later, the company obtained a patent and provided the equipment to the commercial world. Now offered through TesSol Inc., of Battle Ground, Washington, the technology is used for fuel cell work, catalyst testing, sensor testing, gas blending, and other applications. It can be found at universities, national laboratories, and businesses around the world.

H2-O2 fuel cell and advanced battery power systems for autonomous underwater vehicles: performance envelope comparisons

International Nuclear Information System (INIS)

Schubak, G.E.; Scott, D.S.

1993-01-01

Autonomous underwater vehicles have traditionally been powered by low energy density lead-acid batteries. Recently, advanced battery technologies and H 2 -O 2 fuel cells have become available, offering significant improvements in performance. This paper compares the solid polymer fuel cell to the lithium-thionyl chloride primary battery, sodium-sulfur battery, and lead acid battery for a variety of missions. The power system performance is simulated using computer modelling techniques. Performance envelopes are constructed, indicating domains of preference for competing power system technologies. For most mission scenarios, the solid polymer fuel cell using liquid reactant storage is the preferred system. Nevertheless, the advanced battery systems are competitive with the fuel cell systems using gaseous hydrogen storage, and they illustrate preferred performance for missions requiring high power density. 11 figs., 4 tabs., 15 refs

Proceedings of the 6. international conference on stability and handling of liquid fuels. Volume 2

Energy Technology Data Exchange (ETDEWEB)

Giles, H.N. [ed.] [Deputy Assistant Secretary for Strategic Petroleum Reserve, Washington, DC (United States). Operations and Readiness Office

1998-12-01

Volume 2 of these proceedings contain 42 papers arranged under the following topical sections: Fuel blending and compatibility; Middle distillates; Microbiology; Alternative fuels; General topics (analytical methods, tank remediation, fuel additives, storage stability); and Poster presentations (analysis methods, oxidation kinetics, health problems).

Interface agreement for the management of 308 Building Spent Nuclear Fuel. Revision 1

International Nuclear Information System (INIS)

Danko, A.D.

1995-01-01

The Hanford Site Spent Nuclear Fuel (SNF) Project was formed to manage the SNF at Hanford. Specifically, the mission of the SNF Project on the Hanford Site is to ''provide safe, economic, environmentally sound management of Hanford SNF in a manner which stages it for final disposition.'' The current mission of the Fuel Fabrication Facilities Transition Project (FFFTP) is to transition the 308 Building for turn over to the Environmental Restoration Contractor for decontamination and decommissioning

CFD analysis of bubble hydrodynamics in a fuel reactor for a hydrogen-fueled chemical looping combustion system

International Nuclear Information System (INIS)

Harichandan, Atal Bihari; Shamim, Tariq

2014-01-01

Highlights: • Computational study of the fuel reactor of chemical looping combustion technology. • The results yield better understanding of the bubble hydrodynamics in fuel reactor. • Increasing the reactor bed length increases the conversion rate. • Small oxygen carrier particles improves the conversion rate. - Abstract: This study investigates the temporal development of bubble hydrodynamics in the fuel reactor of a hydrogen-fueled chemical looping combustion (CLC) system by using a computational model. The model also investigates the molar fraction of products in gas and solid phases. The study assists in developing a better understanding of the CLC process, which has many advantages such as being a potentially promising candidate for an efficient carbon dioxide capture technology. The study employs the kinetic theory of granular flow. The reactive fluid dynamic system of the fuel reactor is customized by incorporating the kinetics of an oxygen carrier reduction into a commercial computational fluid dynamics (CFD) code. An Eulerian multiphase treatment is used to describe the continuum two-fluid model for both gas and solid phases. CaSO 4 and H 2 are used as an oxygen carrier and a fuel, respectively. The computational results are validated with the experimental and numerical results available in the open literature. The CFD simulations are found to capture the features of the bubble formation, rise and burst in unsteady and quasi-steady states very well. The results show a significant increase in the conversion rate with higher dense bed height, lower bed width, higher free board height and smaller oxygen carrier particles which upsurge an overall performance of the CLC plant

The Versatility of an Online Database for Spent Nuclear Fuel Management

International Nuclear Information System (INIS)

Canas, L.R.

1997-12-01

A vast and diverse database on spent nuclear fuel (SNF) supports the mission of the Westinghouse Savannah River Company's (WSRC) Spent Fuel Storage Division (SFSD) at the Department of Energy's (DOE) Savannah River Site (SRS) chemical-nuclear complex. Prior to 1994, this documentation resided in multiple files maintained by various organizations across SRS. Since that time, in an attempt to improve the efficiency of SNF data retrieval upon demand, the files have been substantially rearranged and consolidated. Moreover, selected data have been captured electronically in a web-style, online Spent Nuclear Fuel Database (SNFD) for quick and easy access from any personal computer on the SRS intranet. Originally released in August 1996, the SNFD has continued to expand at regular intervals commensurate with the SFSD mission

Comparative analysis of different methods of modelling of most loaded fuel pin in transients

International Nuclear Information System (INIS)

Ovdiyenko, Y.; Khalimonchuk, V.; Ieremenko, M.

2007-01-01

Different methods of modeling of most loaded fuel pin are presented at the work. Calculation studies are performed on example of accident related to WWER-1000 cluster rod ejection with using of spatial kinetic code DYN3D that uses nodal method to calculate distribution of neutron flux in the core. Three methods of modeling of most loaded fuel pin are considered - flux reconstruction in fuel macrocell, pin-by-pin calculation by using of DYN3D/DERAB package and by introducing of additional 'hot channel'. Obtained results of performed studies could be used for development of calculation kinetic models during preparing of safety analysis report (Authors)

A comprehensive iso-octane combustion model with improved thermochemistry and chemical kinetics

KAUST Repository

Atef, Nour

2017-02-05

Iso-Octane (2,2,4-trimethylpentane) is a primary reference fuel and an important component of gasoline fuels. Moreover, it is a key component used in surrogates to study the ignition and burning characteristics of gasoline fuels. This paper presents an updated chemical kinetic model for iso-octane combustion. Specifically, the thermodynamic data and reaction kinetics of iso-octane have been re-assessed based on new thermodynamic group values and recently evaluated rate coefficients from the literature. The adopted rate coefficients were either experimentally measured or determined by analogy to theoretically calculated values. Furthermore, new alternative isomerization pathways for peroxy-alkyl hydroperoxide (ȮOQOOH) radicals were added to the reaction mechanism. The updated kinetic model was compared against new ignition delay data measured in rapid compression machines (RCM) and a high-pressure shock tube. These experiments were conducted at pressures of 20 and 40 atm, at equivalence ratios of 0.4 and 1.0, and at temperatures in the range of 632–1060 K. The updated model was further compared against shock tube ignition delay times, jet-stirred reactor oxidation speciation data, premixed laminar flame speeds, counterflow diffusion flame ignition, and shock tube pyrolysis speciation data available in the literature. Finally, the updated model was used to investigate the importance of alternative isomerization pathways in the low temperature oxidation of highly branched alkanes. When compared to available models in the literature, the present model represents the current state-of-the-art in fundamental thermochemistry and reaction kinetics of iso-octane; and thus provides the best prediction of wide ranging experimental data and fundamental insights into iso-octane combustion chemistry.

Nuclear fuel element recovery using PEDSCO RMI Unit

International Nuclear Information System (INIS)

Martin, D.G.; Pedersen, B.V.

1984-01-01

In September 1982, a PEDSCO Remote Mobile Investigation Unit was used to recover damaged irradiated fuel elements from a fueling machine and trolley deck at Bruce Nuclear Generating Station 'A'. This Canadian-made remote controlled vehicle was originally designed for explosive ordinance disposal by law enforcement agencies. This paper describes its adaptation to nuclear service and its first mission, within a nuclear facility

Reforming petroleum-based fuels for fuel cell vehicles : composition-performance relationships

International Nuclear Information System (INIS)

Kopasz, J. P.; Miller, L. E.; Ahmed, S.; Devlin, P. R.; Pacheco, M.

2001-01-01

Onboard reforming of petroleum-based fuels, such as gasoline, may help ease the introduction of fuel cell vehicles to the marketplace. Although gasoline can be reformed, it is optimized to meet the demands of ICEs. This optimization includes blending to increase the octane number and addition of oxygenates and detergents to control emissions. The requirements for a fuel for onboard reforming to hydrogen are quite different than those for combustion. Factors such as octane number and flame speed are not important; however, factors such as hydrogen density, catalyst-fuel interactions, and possible catalyst poisoning become paramount. In order to identify what factors are important in a hydrocarbon fuel for reforming to hydrogen and what factors are detrimental, we have begun a program to test various components of gasoline and blends of components under autothermal reforming conditions. The results indicate that fuel composition can have a large effect on reforming behavior. Components which may be beneficial for ICEs for their octane enhancing value were detrimental to reforming. Fuels with high aromatic and naphthenic content were more difficult to reform. Aromatics were also found to have an impact on the kinetics for reforming of paraffins. The effects of sulfur impurities were dependent on the catalyst. Sulfur was detrimental for Ni, Co, and Ru catalysts. Sulfur was beneficial for reforming with Pt catalysts, however, the effect was dependent on the sulfur concentration

A minimalist functional group (MFG) approach for surrogate fuel formulation

KAUST Repository

Abdul Jameel, Abdul Gani

2018-03-20

Surrogate fuel formulation has drawn significant interest due to its relevance towards understanding combustion properties of complex fuel mixtures. In this work, we present a novel approach for surrogate fuel formulation by matching target fuel functional groups, while minimizing the number of surrogate species. Five key functional groups; paraffinic CH, paraffinic CH, paraffinic CH, naphthenic CH–CH and aromatic C–CH groups in addition to structural information provided by the Branching Index (BI) were chosen as matching targets. Surrogates were developed for six FACE (Fuels for Advanced Combustion Engines) gasoline target fuels, namely FACE A, C, F, G, I and J. The five functional groups present in the fuels were qualitatively and quantitatively identified using high resolution H Nuclear Magnetic Resonance (NMR) spectroscopy. A further constraint was imposed in limiting the number of surrogate components to a maximum of two. This simplifies the process of surrogate formulation, facilitates surrogate testing, and significantly reduces the size and time involved in developing chemical kinetic models by reducing the number of thermochemical and kinetic parameters requiring estimation. Fewer species also reduces the computational expenses involved in simulating combustion in practical devices. The proposed surrogate formulation methodology is denoted as the Minimalist Functional Group (MFG) approach. The MFG surrogates were experimentally tested against their target fuels using Ignition Delay Times (IDT) measured in an Ignition Quality Tester (IQT), as specified by the standard ASTM D6890 methodology, and in a Rapid Compression Machine (RCM). Threshold Sooting Index (TSI) and Smoke Point (SP) measurements were also performed to determine the sooting propensities of the surrogates and target fuels. The results showed that MFG surrogates were able to reproduce the aforementioned combustion properties of the target FACE gasolines across a wide range of conditions

A minimalist functional group (MFG) approach for surrogate fuel formulation

KAUST Repository

Abdul Jameel, Abdul Gani; Naser, Nimal; Issayev, Gani; Touitou, Jamal; Ghosh, Manik Kumer; Emwas, Abdul-Hamid M.; Farooq, Aamir; Dooley, Stephen; Sarathy, Mani

2018-01-01

Surrogate fuel formulation has drawn significant interest due to its relevance towards understanding combustion properties of complex fuel mixtures. In this work, we present a novel approach for surrogate fuel formulation by matching target fuel functional groups, while minimizing the number of surrogate species. Five key functional groups; paraffinic CH, paraffinic CH, paraffinic CH, naphthenic CH–CH and aromatic C–CH groups in addition to structural information provided by the Branching Index (BI) were chosen as matching targets. Surrogates were developed for six FACE (Fuels for Advanced Combustion Engines) gasoline target fuels, namely FACE A, C, F, G, I and J. The five functional groups present in the fuels were qualitatively and quantitatively identified using high resolution H Nuclear Magnetic Resonance (NMR) spectroscopy. A further constraint was imposed in limiting the number of surrogate components to a maximum of two. This simplifies the process of surrogate formulation, facilitates surrogate testing, and significantly reduces the size and time involved in developing chemical kinetic models by reducing the number of thermochemical and kinetic parameters requiring estimation. Fewer species also reduces the computational expenses involved in simulating combustion in practical devices. The proposed surrogate formulation methodology is denoted as the Minimalist Functional Group (MFG) approach. The MFG surrogates were experimentally tested against their target fuels using Ignition Delay Times (IDT) measured in an Ignition Quality Tester (IQT), as specified by the standard ASTM D6890 methodology, and in a Rapid Compression Machine (RCM). Threshold Sooting Index (TSI) and Smoke Point (SP) measurements were also performed to determine the sooting propensities of the surrogates and target fuels. The results showed that MFG surrogates were able to reproduce the aforementioned combustion properties of the target FACE gasolines across a wide range of conditions

Dry air oxidation kinetics of K-Basin spent nuclear fuel

International Nuclear Information System (INIS)

Abrefah, J.; Buchanan, H.C.; Gerry, W.M.; Gray, W.J.; Marschman, S.C.

1998-06-01

The safety and process analyses of the proposed Integrated Process Strategy (IPS) to move the N-Reactor spent nuclear fuel (SNF) stored at K-Basin to an interim storage facility require information about the oxidation behavior of the metallic uranium. Limited experiments have been performed on the oxidation reaction of SNF samples taken from an N-Reactor outer fuel element in various atmospheres. This report discusses studies on the oxidation behavior of SNF using two independent experimental systems: (1) a tube furnace with a flowing gas mixture of 2% oxygen/98% argon; and (2) a thermogravimetric system for dry air oxidation

Calculation of Kinetic Parameters of TRIGA Reactor

International Nuclear Information System (INIS)

Snoj, Luka; Kavcic, Andrej; Zerovnik, Gasper; Ravnik, Matjaz

2008-01-01

Modern Monte Carlo transport codes in combination of fast computer clusters enable very accurate calculations of the most important reactor kinetic parameters. Such are the effective delayed neutron fraction, β eff , and mean neutron generation time, Λ. We calculated the β eff and Λ for various realistic and hypothetical annular TRIGA Mark II cores with different types and amount of fuel. It can be observed that the effective delayed neutron fraction strongly depends on the number of fuel elements in the core or on the core size. E.g., for 12 wt. % uranium standard fuel with 20 % enrichment, β eff varies from 0.0080 for a small core (43 fuel rods) to 0.0075 for a full core (90 fuel rods). It is interesting to note that calculated value of β eff strongly depends also on the delayed neutron nuclear data set used in calculations. The prompt neutron life-time mainly depends on the amount (due to either content or enrichment) of 235 U in the fuel as it is approximately inversely proportional to the average absorption cross-section of the fuel. E.g., it varies from 28 μs for 30 wt. % uranium content fuelled core to 48 μs for 8.5 wt. % uranium content LEU fuelled core. The results are especially important for pulse mode operation and analysis of the pulses. (authors)

Modelling of elementary kinetics of H2 and CO oxidation on ceria pattern cells

International Nuclear Information System (INIS)

Patel, HC; Tabish, AN; Aravind, PV

2015-01-01

Elementary kinetic mechanisms of fuel oxidation on ceria have not been dealt with in detail in literature. An elementary kinetic model is developed considering charge transfer and adsorption steps for electrochemical H 2 and CO oxidation on ceria. The reaction chemistry is solved by fitting previously obtained impedance spectra for H 2 and CO oxidation on ceria. The rate determining step is found to be the charge transfer rather than the adsorption for both H 2 and CO. A method is presented to extend the kinetics obtained from pattern anodes to macroscopic simulations in which the activation overvoltage can be calculated on the basis of elementary kinetics.

Fundamental aspects of nuclear reactor fuel elements

International Nuclear Information System (INIS)

Olander, D.R.

1976-01-01

The book presented is designed to function both as a text for first-year graduate courses in nuclear materials and as a reference for workers involved in the materials design and performance aspects of nuclear power plants. The contents are arranged under the following chapter headings: statistical thermodynamics, thermal properties of solids, crystal structures, cohesive energy of solids, chemical equilibrium, point defects in solids, diffusion in solids, dislocations and grain boundaries, equation of state of UO 2 , fuel element thermal performance, fuel chemistry, behavior of solid fission products in oxide fuel elements, swelling due to fission gases, pore migration and fuel restructuring kinetics, fission gas release, mechanical properties of UO 2 , radiation damage, radiation effects in metals, interaction of sodium and stainless steel, modeling of the structural behavior of fuel elements and assemblies

Interim report spent nuclear fuel retrieval system fuel handling development testing

Energy Technology Data Exchange (ETDEWEB)

Ketner, G.L.; Meeuwsen, P.V.; Potter, J.D.; Smalley, J.T.; Baker, C.P.; Jaquish, W.R.

1997-06-01

Fuel handling development testing was performed in support of the Fuel Retrieval System (FRS) Sub-Project at the Hanford Site. The project will retrieve spent nuclear fuel, clean and remove fuel from canisters, repackage fuel into baskets, and load fuel into a multi-canister overpack (MCO) for vacuum drying and interim dry storage. The FRS is required to retrieve basin fuel canisters, clean fuel elements sufficiently of uranium corrosion products (or sludge), empty fuel from canisters, sort debris and scrap from whole elements, and repackage fuel in baskets in preparation for MCO loading. The purpose of fuel handling development testing was to examine the systems ability to accomplish mission activities, optimization of equipment layouts for initial process definition, identification of special needs/tools, verification of required design changes to support performance specification development, and validation of estimated activity times/throughput. The test program was set up to accomplish this purpose through cold development testing using simulated and prototype equipment; cold demonstration testing using vendor expertise and systems; and graphical computer modeling to confirm feasibility and throughput. To test the fuel handling process, a test mockup that represented the process table was fabricated and installed. The test mockup included a Schilling HV series manipulator that was prototypic of the Schilling Hydra manipulator. The process table mockup included the tipping station, sorting area, disassembly and inspection zones, fuel staging areas, and basket loading stations. The test results clearly indicate that the Schilling Hydra arm cannot effectively perform the fuel handling tasks required unless it is attached to some device that can impart vertical translation, azimuth rotation, and X-Y translation. Other test results indicate the importance of camera locations and capabilities, and of the jaw and end effector tool design. 5 refs., 35 figs., 3 tabs.

Investigation of ion kinetic effects in direct-drive exploding-pusher implosions at the NIF

Energy Technology Data Exchange (ETDEWEB)

Rosenberg, M. J., E-mail: mrosenbe@mit.edu; Zylstra, A. B.; Séguin, F. H.; Rinderknecht, H. G.; Frenje, J. A.; Gatu Johnson, M.; Sio, H.; Waugh, C. J.; Sinenian, N.; Li, C. K.; Petrasso, R. D. [Plasma Science and Fusion Center, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States); McKenty, P. W.; Hohenberger, M.; Radha, P. B.; Delettrez, J. A.; Glebov, V. Yu.; Betti, R.; Goncharov, V. N.; Knauer, J. P.; Sangster, T. C. [Laboratory for Laser Energetics, University of Rochester, Rochester, New York 14623 (United States); and others

2014-12-15

Measurements of yield, ion temperature, areal density (ρR), shell convergence, and bang time have been obtained in shock-driven, D{sub 2} and D{sup 3}He gas-filled “exploding-pusher” inertial confinement fusion (ICF) implosions at the National Ignition Facility to assess the impact of ion kinetic effects. These measurements probed the shock convergence phase of ICF implosions, a critical stage in hot-spot ignition experiments. The data complement previous studies of kinetic effects in shock-driven implosions. Ion temperature and fuel ρR inferred from fusion-product spectroscopy are used to estimate the ion-ion mean free path in the gas. A trend of decreasing yields relative to the predictions of 2D DRACO hydrodynamics simulations with increasing Knudsen number (the ratio of ion-ion mean free path to minimum shell radius) suggests that ion kinetic effects are increasingly impacting the hot fuel region, in general agreement with previous results. The long mean free path conditions giving rise to ion kinetic effects in the gas are often prevalent during the shock phase of both exploding pushers and ablatively driven implosions, including ignition-relevant implosions.

Communication of 10 June 2009 received from the Permanent Mission of the United Kingdom with regard to the International Nuclear Fuel Supply Conference: Securing safe access to peaceful power

International Nuclear Information System (INIS)

2009-01-01

The Secretariat has received a communication dated 10 June 2009 from the Permanent Mission of the United Kingdom of Great Britain and Northern Ireland, attaching a note from the United Kingdom and the final remarks of the Chairman of the International Nuclear Fuel Supply Conference: Securing safe access to peaceful power, held in London on 17 and 18 March 2009. As requested in that communication, the note and final remarks are herewith circulated for the information of Member States

An Atmospheric Variability Model for Venus Aerobraking Missions

Science.gov (United States)

Tolson, Robert T.; Prince, Jill L. H.; Konopliv, Alexander A.

2013-01-01

Aerobraking has proven to be an enabling technology for planetary missions to Mars and has been proposed to enable low cost missions to Venus. Aerobraking saves a significant amount of propulsion fuel mass by exploiting atmospheric drag to reduce the eccentricity of the initial orbit. The solar arrays have been used as the primary drag surface and only minor modifications have been made in the vehicle design to accommodate the relatively modest aerothermal loads. However, if atmospheric density is highly variable from orbit to orbit, the mission must either accept higher aerothermal risk, a slower pace for aerobraking, or a tighter corridor likely with increased propulsive cost. Hence, knowledge of atmospheric variability is of great interest for the design of aerobraking missions. The first planetary aerobraking was at Venus during the Magellan mission. After the primary Magellan science mission was completed, aerobraking was used to provide a more circular orbit to enhance gravity field recovery. Magellan aerobraking took place between local solar times of 1100 and 1800 hrs, and it was found that the Venusian atmospheric density during the aerobraking phase had less than 10% 1 sigma orbit to orbit variability. On the other hand, at some latitudes and seasons, Martian variability can be as high as 40% 1 sigmaFrom both the MGN and PVO mission it was known that the atmosphere, above aerobraking altitudes, showed greater variability at night, but this variability was never quantified in a systematic manner. This paper proposes a model for atmospheric variability that can be used for aerobraking mission design until more complete data sets become available.

Preliminary Thermohydraulic Analysis of a New Moderated Reactor Utilizing an LEU-Fuel for Space Nuclear Thermal Propulsion

Energy Technology Data Exchange (ETDEWEB)

Nam, Seung Hyun; Choi, Jae Young; Venneria, Paolo F.; Jeong, Yong Hoon; Chang, Soon Heung [KAIST, Daejeon (Korea, Republic of)

2015-10-15

The Korea Advanced NUclear Thermal Engine Rocket utilizing an LEU fuel (KANUTER-LEU) is a non-proliferative and comparably efficient NTR engine with relatively low thrust levels of 40 - 50 kN for in-space transportation. The small modular engine can expand mission versatility, when flexibly used in a clustered engine arrangement, so that it can perform various scale missions from low-thrust robotic science missions to high-thrust manned missions. In addition, the clustered engine system can enhance engine redundancy and ensuing crew safety as well as the thrust. The propulsion system is an energy conversion system to transform the thermal energy of the reactor into the kinetic energy of the propellant to produce the powers for thrust, propellant feeding and electricity. It is mainly made up of a propellant Feeding System (PFS) comprising a Turbo-Pump Assembly (TPA), a Regenerative Nozzle Assembly (RNA), etc. For this core design study, an expander cycle is assumed to be the propulsion system. The EGS converts the thermal energy of the EHTGR in the idle operation (only 350 kW{sub th} power) to electric power during the electric power mode. This paper presents a preliminary thermohydraulic design analysis to explore the design space for the new reactor and to estimate the referential engine performance. The new non-proliferative NTR engine concept, KANUTER-LEU, is under designing to surmount the nuclear proliferation obstacles on allR and Dactivities and eventual commercialization for future generations. To efficiently implement a heavy LEU fuel for the NTR engine, its reactor design innovatively possesses the key characteristics of the high U density fuel with high heating and H{sub 2} corrosion resistances, the thermal neutron spectrum core and also minimizing non-fission neutron loss, and the compact reactor design with protectively cooling capability. To investigate feasible design space for the moderated EHTGR-LEU and resultant engine performance, the

Research in Supercritical Fuel Properties and Combustion Modeling

Science.gov (United States)

2015-09-18

identified reactions needing further study and C-2 and C-3 species to add to the mechanism . 15. SUBJECT TERMS Supercritical fluids , Brillouin scattering...kinetics mechanism for combustion of hydrocarbon fuels containing up to 2 carbon atoms, including uncertainties. • We identified key reactions and...safety. The chemical mechanisms for combustion of all of these fuels share the same set of elementary reactions of smaller-fragment hydrocarbons , and

Diffuse Charge Effects in Fuel Cell Membranes

NARCIS (Netherlands)

Biesheuvel, P.M.; Franco, A.A.; Bazant, M.Z.

2009-01-01

It is commonly assumed that electrolyte membranes in fuel cells are electrically neutral, except in unsteady situations, when the double-layer capacitance is heuristically included in equivalent circuit calculations. Indeed, the standard model for electron transfer kinetics at the membrane/electrode

Transport of fresh MOX fuel assemblies for the Monju initial core

International Nuclear Information System (INIS)

Kurakami, J.; Ouchi, Y.; Usami, M.

1997-01-01

Transport of fresh MOX fuel assemblies for the prototype FBR MONJU initial core started in July 1992 and ended in March 1994. As many as 205 fresh MOX fuel assemblies for an inner core, 91 assemblies for an outer core and 5 assemblies for testing) were transported in nine transport missions. The packaging for fuel assemblies, which has shielding and shock absorbing material inside, meets IAEA regulatory requirements for Type B(U) packaging including hypothetical accident conditions such as the 9 m drop test, fire test, etc. Moreover, this package design feature such advanced technologies as high performance neutron shielding material and an automatic hold-down mechanism for the fuel assemblies. Every effort was made to carry out safe transport in conjunction with the cooperation of every competent organisation. This effort includes establishment of the transport control centre, communication training, and accompanying of the radiation monitoring expert. No transport accident occurred during the transport and all the transport missions were successfully completed on schedule. (Author)

Primary Reference Fuels (PRFs) as Surrogates for Low Sensitivity Gasoline Fuels

KAUST Repository

Bhavani Shankar, Vijai Shankar

2016-04-05

Primary Reference Fuels (PRFs) - binary mixtures of n-heptane and iso-octane based on Research Octane Number (RON) - are popular gasoline surrogates for modeling combustion in spark ignition engines. The use of these two component surrogates to represent real gasoline fuels for simulations of HCCI/PCCI engines needs further consideration, as the mode of combustion is very different in these engines (i.e. the combustion process is mainly controlled by the reactivity of the fuel). This study presents an experimental evaluation of PRF surrogates for four real gasoline fuels termed FACE (Fuels for Advanced Combustion Engines) A, C, I, and J in a motored CFR (Cooperative Fuels Research) engine. This approach enables the surrogate mixtures to be evaluated purely from a chemical kinetic perspective. The gasoline fuels considered in this study have very low sensitivities, S (RON-MON), and also exhibit two-stage ignition behavior. The first stage heat release, which is termed Low Temperature Heat Release (LTHR), controls the combustion phasing in this operating mode. As a result, the performance of the PRF surrogates was evaluated by its ability to mimic the low temperature chemical reactivity of the real gasoline fuels. This was achieved by comparing the LTHR from the engine pressure histories. The PRF surrogates were able to consistently reproduce the amount of LTHR, closely match the phasing of LTHR, and the compression ratio for the start of hot ignition of the real gasoline fuels. This suggests that the octane quality of a surrogate fuel is a good indicator of the fuel’s reactivity across low (LTC), negative temperature coefficient (NTC), and high temperature chemical (HTC) reactivity regimes.

Equilibrium, kinetic and reactive transport models for Pu: employing numerical methods to uncover the nature of the intrinsic colloid

International Nuclear Information System (INIS)

Schwantes, Jon M.; Batchelor, Bill

2000-01-01

Future missions for the Department of Defense include processing plutonium for vitrification and conversion to mixed oxide fuels for commercial use. Such processing could result in the production of Pu-containing waste and unplanned releases of Pu to the environment. Some releases related to plutonium processing have occurred in the past. However, scientists are currently not able to explain the observed behavior of plutonium in natural systems. For example, classical filtration theory predicts that plutonium transport within groundwater should be limited to a few tens of meters. Experimental observations, however, show that plutonium is present in groundwater at distances orders of magnitude farther away from its source than predicted. Before adequate disposal practices can be designed for plutonium, its behavior in these systems must be better understood. The overall goal of this project is to develop equilibrium, kinetic and reactive transport models that describe the behavior of Pu in aqueous systems and to apply these models to natural and engineered systems

Reduced Gasoline Surrogate (Toluene/n-Heptane/iso-Octane) Chemical Kinetic Model for Compression Ignition Simulations

KAUST Repository

Sarathy, Mani; Atef, Nour; Alfazazi, Adamu; Badra, Jihad; Zhang, Yu; Tzanetakis, Tom; Pei, Yuanjiang

2018-01-01

Toluene primary reference fuel (TPRF) (mixture of toluene, iso-octane and heptane) is a suitable surrogate to represent a wide spectrum of real fuels with varying octane sensitivity. Investigating different surrogates in engine simulations is a prerequisite to identify the best matching mixture. However, running 3D engine simulations using detailed models is currently impossible and reduction of detailed models is essential. This work presents an AramcoMech reduced kinetic model developed at King Abdullah University of Science and Technology (KAUST) for simulating complex TPRF surrogate blends. A semi-decoupling approach was used together with species and reaction lumping to obtain a reduced kinetic model. The model was widely validated against experimental data including shock tube ignition delay times and premixed laminar flame speeds. Finally, the model was utilized to simulate the combustion of a low reactivity gasoline fuel under partially premixed combustion conditions.

Reduced Gasoline Surrogate (Toluene/n-Heptane/iso-Octane) Chemical Kinetic Model for Compression Ignition Simulations

KAUST Repository

Sarathy, Mani

2018-04-03

Toluene primary reference fuel (TPRF) (mixture of toluene, iso-octane and heptane) is a suitable surrogate to represent a wide spectrum of real fuels with varying octane sensitivity. Investigating different surrogates in engine simulations is a prerequisite to identify the best matching mixture. However, running 3D engine simulations using detailed models is currently impossible and reduction of detailed models is essential. This work presents an AramcoMech reduced kinetic model developed at King Abdullah University of Science and Technology (KAUST) for simulating complex TPRF surrogate blends. A semi-decoupling approach was used together with species and reaction lumping to obtain a reduced kinetic model. The model was widely validated against experimental data including shock tube ignition delay times and premixed laminar flame speeds. Finally, the model was utilized to simulate the combustion of a low reactivity gasoline fuel under partially premixed combustion conditions.

Simulation of the organic-waste processing in plasma with allowance for kinetics of thermochemical transformations

Science.gov (United States)

Messerle, V. E.; Ustimenko, A. B.

2017-07-01

Kinetic calculations of the plasma processing/utilization process of organic waste in air and steam ambient were carried out. It is shown that, during the time of waste residence in the plasma reactor, 0.7 and 1.2 s, at the exit from the reactor there forms a high-calorific fuel gas with a combustion heat of 3540 and 5070 kcal/kg, respectively. In this process, 1 kg of waste yields 1.16 kg of fuel gas at air gasification of waste and 0.87 kg of pure synthesis gas at steam gasification. The energy efficiency of the waste gasification process, defined by the ratio between the calorific value of the resultant fuel gas and the initial calorific value of the waste amounts to 91 % in air plasma and 98 % in steam plasma. A comparison between the results of kinetic and thermodynamic calculations has revealed their good agreement.

Fission-product SiC reaction in HTGR fuel

International Nuclear Information System (INIS)

Montgomery, F.

1981-01-01

The primary barrier to release of fission product from any of the fuel types into the primary circuit of the HTGR are the coatings on the fuel particles. Both pyrolytic carbon and silicon carbide coatings are very effective in retaining fission gases under normal operating conditions. One of the possible performance limitations which has been observed in irradiation tests of TRISO fuel is chemical interaction of the SiC layer with fission products. This reaction reduces the thickness of the SiC layer in TRISO particles and can lead to release of fission products from the particles if the SiC layer is completely penetrated. The experimental section of this report describes the results of work at General Atomic concerning the reaction of fission products with silicon carbide. The discussion section describes data obtained by various laboratories and includes (1) a description of the fission products which have been found to react with SiC; (2) a description of the kinetics of silicon carbide thinning caused by fission product reaction during out-of-pile thermal gradient heating and the application of these kinetics to in-pile irradiation; and (3) a comparison of silicon carbide thinning in LEU and HEU fuels

Kinetic and thermodynamic studies of uranium minerals. Assessment of the long-term evolution of spent nuclear fuel

Energy Technology Data Exchange (ETDEWEB)

Casas, I; Bruno, J; Cera, E [MBT Tecnologia Ambiental, Cerdanyola (Spain); Finch, R J; Ewing, R C [Department of Earth and Planetary Sciences, University of New Mexico, Albuquerque, NM (United States)

1994-10-01

We have studied the dissolution behavior of uraninite, becquerelite, schoepite and uranophane. The information obtained under a variety of experimental conditions has been combined with extensive solid phase characterizations, performed in both leached and unleached samples. The overall objective is to construct a thermodynamic and kinetic model for the long-term oxidation alteration of UO{sub 2}(s), as an analogy of the spent nuclear fuel matrix. We have determined the solubility product for becquerelite (logK{sub s0} 32.7{+-}1.3) and uranophane (logK{sub s0} = 7.8{+-}0.8). In some experiments, the reaction progress has shown initial dissolution of uranophane followed by precipitation of a secondary solid phase, characterized as soddyite. The solubility production for this phase has been determined (logK{sub s0} = 3.0{+-}2.9). We have studied the kinetics of dissolution of uraninite, uranophane and schoepite under oxidizing conditions in synthetic granitic groundwater. BET measurements have been performed for uraninite and uranophane. For schoepite, the measurement has not been performed due to lack of sufficient amount of sample. The normalized rates of dissolution of uraninite and uranophane have been calculated referred to the uranium release, as 1.97x10{sup -8} moles h{sup -1} m{sup -2} and 4.0x 10{sup -9} moles h{sup -1} m{sup -2}, respectively. For schoepite, the dissolution process has shown two different rates, with a relatively fast initial dissolution rate of 1.97x10{sup -8} moles h{sup -1} followed, after approximately 1000 hours, by a slower one of 1.4x10{sup -9} moles h{sup -1}. No formation of secondary phases has been observed in those experiments, although final uranium concentrations have in all cases exceeded the solubility of uranophane, the thermodynamically more stable phase under the experimental conditions. 24 refs, 45 figs.

Kinetic and thermodynamic studies of uranium minerals. Assessment of the long-term evolution of spent nuclear fuel

International Nuclear Information System (INIS)

Casas, I.; Bruno, J.; Cera, E.; Finch, R.J.; Ewing, R.C.

1994-10-01

We have studied the dissolution behavior of uraninite, becquerelite, schoepite and uranophane. The information obtained under a variety of experimental conditions has been combined with extensive solid phase characterizations, performed in both leached and unleached samples. The overall objective is to construct a thermodynamic and kinetic model for the long-term oxidation alteration of UO 2 (s), as an analogy of the spent nuclear fuel matrix. We have determined the solubility product for becquerelite (logK s0 32.7±1.3) and uranophane (logK s0 = 7.8±0.8). In some experiments, the reaction progress has shown initial dissolution of uranophane followed by precipitation of a secondary solid phase, characterized as soddyite. The solubility production for this phase has been determined (logK s0 = 3.0±2.9). We have studied the kinetics of dissolution of uraninite, uranophane and schoepite under oxidizing conditions in synthetic granitic groundwater. BET measurements have been performed for uraninite and uranophane. For schoepite, the measurement has not been performed due to lack of sufficient amount of sample. The normalized rates of dissolution of uraninite and uranophane have been calculated referred to the uranium release, as 1.97x10 -8 moles h -1 m -2 and 4.0x 10 -9 moles h -1 m -2 , respectively. For schoepite, the dissolution process has shown two different rates, with a relatively fast initial dissolution rate of 1.97x10 -8 moles h -1 followed, after approximately 1000 hours, by a slower one of 1.4x10 -9 moles h -1 . No formation of secondary phases has been observed in those experiments, although final uranium concentrations have in all cases exceeded the solubility of uranophane, the thermodynamically more stable phase under the experimental conditions. 24 refs, 45 figs

Investigations on the kinetics of the oxygen reduction in high temperature fuel cells

International Nuclear Information System (INIS)

Erning, J.W.

1998-07-01

Lanthan-Strontium-Manganite perowskites are the most widespread materials in use for solid oxide fuel cell cathodes. The electrode reaction taking place, i.e. the reduction of oxygen supplied by air, was investigated by electrochemical means to obtain further knowledge about the electrode processes. The high activation energy of this reaction (200 kJ/mol), preventing lower operation temperatures of the SOFC, was the starting point for the investigation. Quasi steady state current voltage measurements and impedance spectroscopy were performed in a three electrode configuration. The electrodes were of circular shape with a diameter of 10 mm. The preparation was made by screen printing as well as wet powder spraying onto plates made of Yttria-stabilized zirconia. Perowskite powders of varying chemical and stoichiometric composition were used. To obtain higher power densities and, more important, lower apparent activation energies, catalytic layers were added at the interface electrode/electrolyte. Additionally, a less complex system, a model electrode/electrolyte setup made from single-crystal YSZ as electrolyte and gold in liquid and solid state as electrode was developed to create a better defined system. This setup was used to investigate the behaviour of the electrode/electrolyte interface. Reliable, reproducible results could be obtained using either setup. The experimental conditions i.e. oxygen partial pressure, temperature and overpotential were varied in order to determine the kinetic properties of the electrodes. Apparent activation energies, pre-exponential factors, apparent charge-transfer coefficients and electrochemical orders of reaction were calculated from the current-voltage data in order to propose possible reaction steps. (orig.)

Radioisotope fueled pulsed power generation system for propulsion and electrical power for deep space missions

Science.gov (United States)

Howe, Troy

Space exploration missions to the moon, Mars, and other celestial bodies have allowed for great scientific leaps to enhance our knowledge of the universe; yet the astronomical cost of these missions limits their utility to only a few select agencies. Reducing the cost of exploratory space travel will give rise to a new era of exploration, where private investors, universities, and world governments can send satellites to far off planets and gather important data. By using radioisotope power sources and thermal storage devices, a duty cycle can be introduced to extract large amounts of energy in short amounts of time, allowing for efficient space travel. The same device can also provide electrical power for subsystems such as communications, drills, lasers, or other components that can provide valuable scientific information. This project examines the use of multiple radioisotope sources combined with a thermal capacitor using Phase Change Materials (PCMs) which can collect energy over a period of time. The result of this design culminates in a variety of possible spacecraft with their own varying costs, transit times, and objectives. Among the most promising are missions to Mars which cost less than 17M, missions that can provide power to satellite constellations for decades, or missions that can deliver large, Opportunity-sized (185kg) payloads to mars for less than 53M. All made available to a much wider range of customer with commercially available satellite launches from earth. The true cost of such progress though lies in the sometimes substantial increase in transit times for these missions.

Reduced chemical kinetic mechanisms for hydrocarbon fuels

International Nuclear Information System (INIS)

Montgomery, C.J.; Cremer, M.A.; Heap, M.P.; Chen, J-Y.; Westbrook, C.K.; Maurice, L.Q.

1999-01-01

Using CARM (Computer Aided Reduction Method), a computer program that automates the mechanism reduction process, a variety of different reduced chemical kinetic mechanisms for ethylene and n-heptane have been generated. The reduced mechanisms have been compared to detailed chemistry calculations in simple homogeneous reactors and experiments. Reduced mechanisms for combustion of ethylene having as few as 10 species were found to give reasonable agreement with detailed chemistry over a range of stoichiometries and showed significant improvement over currently used global mechanisms. The performance of reduced mechanisms derived from a large detailed mechanism for n-heptane was compared to results from a reduced mechanism derived from a smaller semi-empirical mechanism. The semi-empirical mechanism was advantageous as a starting point for reduction for ignition delay, but not for PSR calculations. Reduced mechanisms with as few as 12 species gave excellent results for n-heptane/air PSR calculations but 16-25 or more species are needed to simulate n-heptane ignition delay

Detectability of CO2 Flux Signals by a Space-Based Lidar Mission

Science.gov (United States)

Hammerling, Dorit M.; Kawa, S. Randolph; Schaefer, Kevin; Doney, Scott; Michalak, Anna M.

2015-01-01

Satellite observations of carbon dioxide (CO2) offer novel and distinctive opportunities for improving our quantitative understanding of the carbon cycle. Prospective observations include those from space-based lidar such as the Active Sensing of CO2 Emissions over Nights, Days, and Seasons (ASCENDS) mission. Here we explore the ability of such a mission to detect regional changes in CO2 fluxes. We investigate these using three prototypical case studies, namely the thawing of permafrost in the Northern High Latitudes, the shifting of fossil fuel emissions from Europe to China, and changes in the source-sink characteristics of the Southern Ocean. These three scenarios were used to design signal detection studies to investigate the ability to detect the unfolding of these scenarios compared to a baseline scenario. Results indicate that the ASCENDS mission could detect the types of signals investigated in this study, with the caveat that the study is based on some simplifying assumptions. The permafrost thawing flux perturbation is readily detectable at a high level of significance. The fossil fuel emission detectability is directly related to the strength of the signal and the level of measurement noise. For a nominal (lower) fossil fuel emission signal, only the idealized noise-free instrument test case produces a clearly detectable signal, while experiments with more realistic noise levels capture the signal only in the higher (exaggerated) signal case. For the Southern Ocean scenario, differences due to the natural variability in the ENSO climatic mode are primarily detectable as a zonal increase.

Analysis of Kinetic Parameter Effect on Reactor Operation Stability of the RSG-GAS Reactor

International Nuclear Information System (INIS)

Rokhmadi

2007-01-01

Kinetic parameter has influence to behaviour on RSG-GAS reactor operation. In this paper done is the calculation of reactivity curve, period-reactivity relation and low power transfer function in silicide fuel. This parameters is necessary and useful for reactivity characteristic analysis and reactor stability. To know the reactivity response, it was done reactivity insertion at power 1 watt using POKDYN code because at this level of power no feedback reactivity so important for reactor operation safety. The result of calculation showed that there is no change of significant a period-reactivity relation and transfer function at low power for 2.96 gU/cc, 3.55 gU/cc and 4.8 gU/cc density of silicide fuels. The result of the transfer function at low power showed that the reactor is critical stability with no feedback. The result of calculation also showed that reactivity response no change among three kinds of fuel densities. It can be concluded that from kinetic parameter point of view period-reactivity relation, transfer function at low power, and reactivity response are no change reactor operation from reactivity effect when fuel exchanged. (author)

Fundamental aspects of nuclear reactor fuel elements

Energy Technology Data Exchange (ETDEWEB)

Olander, D.R.

1976-01-01

The book presented is designed to function both as a text for first-year graduate courses in nuclear materials and as a reference for workers involved in the materials design and performance aspects of nuclear power plants. The contents are arranged under the following chapter headings: statistical thermodynamics, thermal properties of solids, crystal structures, cohesive energy of solids, chemical equilibrium, point defects in solids, diffusion in solids, dislocations and grain boundaries, equation of state of UO/sub 2/, fuel element thermal performance, fuel chemistry, behavior of solid fission products in oxide fuel elements, swelling due to fission gases, pore migration and fuel restructuring kinetics, fission gas release, mechanical properties of UO/sub 2/, radiation damage, radiation effects in metals, interaction of sodium and stainless steel, modeling of the structural behavior of fuel elements and assemblies. (DG)

Evaluation of the use of metal alloy fuels in pressurized water reactors

International Nuclear Information System (INIS)

1990-01-01

The project concentrated on model development. Reactor physics modeling involved establishing accurate models with PC versions of COMBINE and VENTURE. Fuel performance analysis will start with METAL- LIFE. In order to justify the change of fuel to metal alloy, large benefits will have to be found; the cost benefit reported is not sufficient. The fuel pin will be annular and contact the clad; the clad thickness will force the fuel to grow toward the central hole. This report reports: design improvements, neutronic model development, COBRA modifications, reactor kinetics model development, RELAP code, and fuel performance

Effects of grain boundaries at the electrolyte/cathode interfaces on oxygen reduction reaction kinetics of solid oxide fuel cells

Energy Technology Data Exchange (ETDEWEB)

Choi, Min Gi; Koo, Ja Yang; Ahn, Min Woo; Lee, Won Young [Dept. of Mechanical Engineering, Sungkyunkwan University, Suwon (Korea, Republic of)

2017-04-15

We systematically investigated the effects of grain boundaries (GBs) at the electrolyte/cathode interface of two conventional electrolyte materials, i.e., yttria-stabilized zirconia (YSZ) and gadolinia-doped ceria (GDC). We deposited additional layers by pulsed laser deposition to control the GB density on top of the polycrystalline substrates, obtaining significant improvements in peak power density (two-fold for YSZ and three-fold for GDC). The enhanced performance at high GB density in the additional layer could be ascribed to the accumulation of oxygen vacancies, which are known to be more active sites for oxygen reduction reactions (ORR) than grain cores. GDC exhibited a higher enhancement than YSZ, due to the easier formation, and thus higher concentration, of oxygen vacancies for ORR. The strong relation between the concentration of oxygen vacancies and the surface exchange characteristics substantiated the role of GBs at electrolyte/cathode interfaces on ORR kinetics, providing new design parameters for highly performing solid oxide fuel cells.

An experimental and numerical investigation of the combustion characteristics of a dual fuel engine with a swirl chamber

Energy Technology Data Exchange (ETDEWEB)

Liu, C.; Karim, G.A.; Xiao, F.; Sohrabi, A. [Calgary Univ., AB (Canada). Schulich School of Engineering, Mechanical and Manufacturing Dept.

2007-07-01

The results of an experimental investigation of the performance of a small bore engine with a swirl chamber when operating as a dual fuel engine with commercial methane as the gaseous fuel were presented in this paper. The experiment involved using a 3-dimensional computational fluid dynamics model to predict the performance of the engine. A detailed chemical kinetics for the gaseous fuel component, consisting primarily of methane and a reduced detailed chemical kinetics for the diesel fuel while considering the turbulent combustion processes an associated performance of a dual fuel engine with a swirl chamber were incorporated in the simulation. The study experimentally and numerically investigated the effects of changes in the quantities of the liquid fuel pilot and gaseous fuels on the combustion processes, engine performance, cyclic variations, and emissions. The paper discussed the experimental approach and results. It also discussed the simulation of the dual fuel engine combustion process. It was concluded that dual fuel combustion was an effective method to burn a gaseous fuel-air mixture with a low energy density. 9 refs., 6 figs.

Radiation shielding aspects for long manned mission to space: Criteria, survey study, and preliminary model

OpenAIRE

Sztejnberg Manuel; Xiao Shanjie; Satvat Nader; Limón Felisa; Hopkins John; Jevremović Tatjana

2006-01-01

The prospect of manned space missions outside Earth's orbit is limited by the travel time and shielding against cosmic radiation. The chemical rockets currently used in the space program have no hope of propelling a manned vehicle to a far away location such as Mars due to the enormous mass of fuel that would be required. The specific energy available from nuclear fuel is a factor of 106 higher than chemical fuel; it is therefore obvious that nuclear power production in space is a must. On th...

Growth of the interaction layer around fuel particles in dispersion fuel

International Nuclear Information System (INIS)

Olander, D.

2009-01-01

Corrosion of uranium particles in dispersion fuel by the aluminum matrix produces interaction layers (an intermetallic-compound corrosion product) around the shrinking fuel spheres. The rate of this process was modeled as series resistances due to Al diffusion through the interaction layer and reaction of aluminum with uranium in the fuel particle to produce UAl x . The overall kinetics are governed by the relative rates of these two steps, the slowest of which is reaction at the interface between Al in the interaction layer and U in the fuel particle. The substantial volume change as uranium is transferred from the fuel to the interaction layer was accounted for. The model was compared to literature data on in-reactor growth of the interaction layer and the Al/U gradient in this layer, the latter measured in ex-reactor experiments. The rate constant of the Al-U interface reaction and the diffusivity of Al in the interaction layer were obtained from this fitting procedure. The second feature of the corrosion process is the transfer of fission products from the fuel particle to the interaction layer due to the reaction. It is commonly assumed that the observed swelling of irradiated fuel elements of this type is due to release of fission gas in the interaction layer to form large bubbles. This hypothesis was tested by using the model to compute the quantity of fission gas available from this source and comparing the pressure of the resulting gas with the observed swelling of fuel plates. It was determined that the gas pressure so generated is too small to account for the observed delamination of the fuel

Fuel performance in water storage

International Nuclear Information System (INIS)

Hoskins, A.P.; Scott, J.G.; Shelton-Davis, C.V.; McDannel, G.E.

1993-11-01

Westinghouse Idaho Nuclear Company operates the Idaho Chemical Processing Plant (ICPP) at the Idaho National Engineering Laboratory (INEL) for the Department of Energy (DOE). A variety of different types of fuels have been stored there since the 1950's prior to reprocessing for uranium recovery. In April of 1992, the DOE decided to end fuel reprocessing, changing the mission at ICPP. Fuel integrity in storage is now viewed as long term until final disposition is defined and implemented. Thus, the condition of fuel and storage equipment is being closely monitored and evaluated to ensure continued safe storage. There are four main areas of fuel storage at ICPP: an original underwater storage facility (CPP-603), a modern underwater storage facility (CPP-666), and two dry fuel storage facilities. The fuels in storage are from the US Navy, DOE (and its predecessors the Energy Research and Development Administration and the Atomic Energy Commission), and other research programs. Fuel matrices include uranium oxide, hydride, carbide, metal, and alloy fuels. In the underwater storage basins, fuels are clad with stainless steel, zirconium, and aluminum. Also included in the basin inventory is canned scrap material. The dry fuel storage contains primarily graphite and aluminum type fuels. A total of 55 different fuel types are currently stored at the Idaho Chemical Processing Plant. The corrosion resistance of the barrier material is of primary concern in evaluating the integrity of the fuel in long term water storage. The barrier material is either the fuel cladding (if not canned) or the can material

Comparison of fuel assemblies in lead cooled fast reactors

Energy Technology Data Exchange (ETDEWEB)

Perez, A.; Sanchez, H.; Aguilar, L.; Espinosa P, G., E-mail: alejandria.peval@gmail.com [Universidad Autonoma Metropolitana, Unidad Iztapalapa, San Rafael Atlixco No. 186, Col. Vicentina, 09340 Ciudad de Mexico (Mexico)

2016-09-15

This paper presents a comparison of the thermal-fluid processes in the core, fuel heat transfer, and thermal power between two fuel assemblies: square and hexagonal, in a lead-cooled fast reactor (Lfr). A multi-physics reduced order model for the analysis of Lfr single channel is developed in this work. The work focused on a coupling between process of neutron kinetic, fuel heat transfer process and thermal-fluid, in a single channel. The thermal power is obtained from neutron point kinetics model, considering a non-uniform power distribution. The analysis of the processes of thermal-fluid considers thermal expansion effects. The transient heat transfer in fuel is carried out in an annular geometry, and one-dimensional in radial direction for each axial node. The results presented in comparing these assemblies consider the temperature field in the fuel, in the thermal fluid and under steady state, and transient conditions. Transients consider flow of coolant and inlet temperature of coolant. The mathematical model of Lfr considers three main modules: the heat transfer in the annular fuel, the power generation with feedback effects on neutronic, and the thermal-fluid in the single channel. The modeling of nuclear reactors in general, the coupling is crucial by the feedback between the neutron processes with fuel heat transfer, and thermo-fluid, where is very common the numerical instabilities, after all it has to refine the model to achieve the design data. In this work is considered as a reference the ELSY reactor for the heat transfer analysis in the fuel and pure lead properties for analyzing the thermal-fluid. The results found shows that the hexagonal array has highest temperature in the fuel, respect to square array. (Author)

Comparison of fuel assemblies in lead cooled fast reactors

International Nuclear Information System (INIS)

Perez, A.; Sanchez, H.; Aguilar, L.; Espinosa P, G.

2016-09-01

This paper presents a comparison of the thermal-fluid processes in the core, fuel heat transfer, and thermal power between two fuel assemblies: square and hexagonal, in a lead-cooled fast reactor (Lfr). A multi-physics reduced order model for the analysis of Lfr single channel is developed in this work. The work focused on a coupling between process of neutron kinetic, fuel heat transfer process and thermal-fluid, in a single channel. The thermal power is obtained from neutron point kinetics model, considering a non-uniform power distribution. The analysis of the processes of thermal-fluid considers thermal expansion effects. The transient heat transfer in fuel is carried out in an annular geometry, and one-dimensional in radial direction for each axial node. The results presented in comparing these assemblies consider the temperature field in the fuel, in the thermal fluid and under steady state, and transient conditions. Transients consider flow of coolant and inlet temperature of coolant. The mathematical model of Lfr considers three main modules: the heat transfer in the annular fuel, the power generation with feedback effects on neutronic, and the thermal-fluid in the single channel. The modeling of nuclear reactors in general, the coupling is crucial by the feedback between the neutron processes with fuel heat transfer, and thermo-fluid, where is very common the numerical instabilities, after all it has to refine the model to achieve the design data. In this work is considered as a reference the ELSY reactor for the heat transfer analysis in the fuel and pure lead properties for analyzing the thermal-fluid. The results found shows that the hexagonal array has highest temperature in the fuel, respect to square array. (Author)

Fuel corrosion processes under waste disposal conditions

International Nuclear Information System (INIS)

Shoesmith, D.W.

1999-09-01

Under the oxidizing conditions likely to be encountered in the Yucca Mountain Repository, fuel dissolution is a corrosion process involving the coupling of the anodic dissolution of the fuel with the cathodic reduction of oxidants available within the repository. The oxidants potentially available to drive fuel corrosion are environmental oxygen, supplied by the transport through the permeable rock of the mountain and molecular and radical species produced by the radiolysis of available aerated water. The mechanism of these coupled anodic and cathodic reactions is reviewed in detail. While gaps in understanding remain, many kinetic features of these reactions have been studied in considerable detail, and a reasonably justified mechanism for fuel corrosion is available. The corrosion rate is determined primarily by environmental factors rather than the properties of the fuel. Thus, with the exception of increase in rate due to an increase in surface area, pre-oxidation of the fuel has little effect on the corrosion rate

Fuel corrosion processes under waste disposal conditions

Energy Technology Data Exchange (ETDEWEB)

Shoesmith, D.W. [Univ. of Western Ontario, Dept. of Chemistry, London, Ontario (Canada)

1999-09-01

Under the oxidizing conditions likely to be encountered in the Yucca Mountain Repository, fuel dissolution is a corrosion process involving the coupling of the anodic dissolution of the fuel with the cathodic reduction of oxidants available within the repository. The oxidants potentially available to drive fuel corrosion are environmental oxygen, supplied by the transport through the permeable rock of the mountain and molecular and radical species produced by the radiolysis of available aerated water. The mechanism of these coupled anodic and cathodic reactions is reviewed in detail. While gaps in understanding remain, many kinetic features of these reactions have been studied in considerable detail, and a reasonably justified mechanism for fuel corrosion is available. The corrosion rate is determined primarily by environmental factors rather than the properties of the fuel. Thus, with the exception of increase in rate due to an increase in surface area, pre-oxidation of the fuel has little effect on the corrosion rate.

Recent Advances in Enzymatic Fuel Cells: Experiments and Modeling

Directory of Open Access Journals (Sweden)

Ivan Ivanov

2010-04-01

Full Text Available Enzymatic fuel cells convert the chemical energy of biofuels into electrical energy. Unlike traditional fuel cell types, which are mainly based on metal catalysts, the enzymatic fuel cells employ enzymes as catalysts. This fuel cell type can be used as an implantable power source for a variety of medical devices used in modern medicine to administer drugs, treat ailments and monitor bodily functions. Some advantages in comparison to conventional fuel cells include a simple fuel cell design and lower cost of the main fuel cell components, however they suffer from severe kinetic limitations mainly due to inefficiency in electron transfer between the enzyme and the electrode surface. In this review article, the major research activities concerned with the enzymatic fuel cells (anode and cathode development, system design, modeling by highlighting the current problems (low cell voltage, low current density, stability will be presented.

Investigation of Coal-biomass Catalytic Gasification using Experiments, Reaction Kinetics and Computational Fluid Dynamics

Energy Technology Data Exchange (ETDEWEB)

Battaglia, Francine [Virginia Polytechnic Inst. and State Univ. (Virginia Tech), Blacksburg, VA (United States); Agblevor, Foster [Virginia Polytechnic Inst. and State Univ. (Virginia Tech), Blacksburg, VA (United States); Klein, Michael [Univ. of Delaware, Newark, DE (United States); Sheikhi, Reza [Northeastern Univ., Boston, MA (United States)

2015-12-31

A collaborative effort involving experiments, kinetic modeling, and computational fluid dynamics (CFD) was used to understand co-gasification of coal-biomass mixtures. The overall goal of the work was to determine the key reactive properties for coal-biomass mixed fuels. Sub-bituminous coal was mixed with biomass feedstocks to determine the fluidization and gasification characteristics of hybrid poplar wood, switchgrass and corn stover. It was found that corn stover and poplar wood were the best feedstocks to use with coal. The novel approach of this project was the use of a red mud catalyst to improve gasification and lower gasification temperatures. An important results was the reduction of agglomeration of the biomass using the catalyst. An outcome of this work was the characterization of the chemical kinetics and reaction mechanisms of the co-gasification fuels, and the development of a set of models that can be integrated into other modeling environments. The multiphase flow code, MFIX, was used to simulate and predict the hydrodynamics and co-gasification, and results were validated with the experiments. The reaction kinetics modeling was used to develop a smaller set of reactions for tractable CFD calculations that represented the experiments. Finally, an efficient tool was developed, MCHARS, and coupled with MFIX to efficiently simulate the complex reaction kinetics.

Compact Kinetic Mechanisms for Petroleum-Derived and Alternative Aviation Fuels, Phase I

Data.gov (United States)

National Aeronautics and Space Administration — To be useful for computational combustor design and analysis using tools like the National Combustion Code (NCC), low-dimensional chemical kinetic mechanisms for...

In-Space Propulsion, Logistics Reduction, and Evaluation of Steam Reformer Kinetics: Problems and Prospects

Science.gov (United States)

Jaworske, D. A.; Palaszewski, B. A.; Kulis, M. J.; Gokoglu, S. A.

2015-01-01

Human space missions generate waste materials. A 70-kg crewmember creates a waste stream of 1 kg per day, and a four-person crew on a deep space habitat for a 400+ day mission would create over 1600 kg of waste. Converted into methane, the carbon could be used as a fuel for propulsion or power. The NASA Advanced Exploration Systems (AES) Logistics Reduction and Repurposing (LRR) project is investing in space resource utilization with an emphasis on repurposing logistics materials for useful purposes and has selected steam reforming among many different competitive processes as the preferred method for repurposing organic waste into methane. Already demonstrated at the relevant processing rate of 5.4 kg of waste per day, high temperature oxygenated steam consumes waste and produces carbon dioxide, carbon monoxide, and hydrogen which can then be converted into methane catalytically. However, the steam reforming process has not been studied in microgravity. Data are critically needed to understand the mechanisms that allow use of steam reforming in a reduced gravity environment. This paper reviews the relevant literature, identifies gravity-dependent mechanisms within the steam gasification process, and describes an innovative experiment to acquire the crucial kinetic information in a small-scale reactor specifically designed to operate within the requirements of a reduced gravity aircraft flight. The experiment will determine if the steam reformer process is mass-transport limited, and if so, what level of forced convection will be needed to obtain performance comparable to that in 1-g.

Mechanisms of fuel-cladding chemical interaction: US interpretation

International Nuclear Information System (INIS)

Adamson, M.G.

1977-01-01

Proposed mechanisms of fuel-cladding chemical interaction (FCCI) in LMFBR fuel pins are reviewed and examined in terms of in-pile and out-of-pile data. From this examination several factors are identified which may govern the occurrence of localized deep intergranular penetrations of Type-316SS cladding. Using a plausible mechanistic hypothesis for FCCI, first steps have been taken towards developing a quantitative, physically-meaningful, mathematical method of predicting cladding wastage in operating fuel pins. Both kinetic and thermodynamic aspects of FCCI are considered in the development of this prediction method, together with a fuel chemistry model that describes the evolution of thermochemical conditions at the fuel-cladding gap. On the basis of results from recent fuel pin and laboratory tests a thermal transport mechanism has been proposed to explain the thermal gradient-induced migration of Fe, Cr, and Ni from cladding into the fuel. This mechanism involves chemical transport of the metallic cladding components (as tellurides) in liquid Cs-Te. (author)

Mechanisms of fuel-cladding chemical interaction: US interpretation

Energy Technology Data Exchange (ETDEWEB)

Adamson, M G [General Electric Company, Vallecitos Nuclear Center, Pleasanton, CA (United States)

1977-04-01

Proposed mechanisms of fuel-cladding chemical interaction (FCCI) in LMFBR fuel pins are reviewed and examined in terms of in-pile and out-of-pile data. From this examination several factors are identified which may govern the occurrence of localized deep intergranular penetrations of Type-316SS cladding. Using a plausible mechanistic hypothesis for FCCI, first steps have been taken towards developing a quantitative, physically-meaningful, mathematical method of predicting cladding wastage in operating fuel pins. Both kinetic and thermodynamic aspects of FCCI are considered in the development of this prediction method, together with a fuel chemistry model that describes the evolution of thermochemical conditions at the fuel-cladding gap. On the basis of results from recent fuel pin and laboratory tests a thermal transport mechanism has been proposed to explain the thermal gradient-induced migration of Fe, Cr, and Ni from cladding into the fuel. This mechanism involves chemical transport of the metallic cladding components (as tellurides) in liquid Cs-Te. (author)

Regulation at nuclear fuel cycle

International Nuclear Information System (INIS)

2002-01-01

This bulletin contains information about activities of the Nuclear Regulatory Authority of the Slovak Republic (UJD). In this leaflet the role of the UJD in regulation at nuclear fuel cycle is presented. The Nuclear Fuel Cycle (NFC) is a complex of activities linked with production of nuclear fuel for nuclear reactors as a source of energy used for production of electricity and heat, and of activities linked with spent nuclear fuel handling. Activities linked with nuclear fuel (NF) production, known as the Front-End of Nuclear Fuel Cycle, include (production of nuclear fuel from uranium as the most frequently used element). After discharging spent nuclear fuel (SNF) from nuclear reactor the activities follow linked with its storage, reprocessing and disposal known as the Back-End of Nuclear Fuel Cycle. Individual activity, which penetrates throughout the NFC, is transport of nuclear materials various forms during NF production and transport of NF and SNF. Nuclear reactors are installed in the Slovak Republic only in commercial nuclear power plants and the NFC is of the open type is imported from abroad and SNF is long-term supposed without reprocessing. The main mission of the area of NFC is supervision over: - assurance of nuclear safety throughout all NFC activities; - observance of provisions of the Treaty on Non-Proliferation of Nuclear Weapons during nuclear material handling; with an aim to prevent leakage of radioactive substances into environment (including deliberated danage of NFC sensitive facilities and misuse of nuclear materials to production of nuclear weapons. The UJD carries out this mission through: - assessment of safety documentation submitted by operators of nuclear installations at which nuclear material, NF and SNF is handled; - inspections concentrated on assurance of compliance of real conditions in NFC, i.e. storage and transport of NF and SNF; storage, transport and disposal of wastes from processing of SNF; with assumptions of the safety

Historical fuel reprocessing and HLW management in Idaho

International Nuclear Information System (INIS)

Knecht, D.A.; Staiger, M.D.; Christian, J.D.

1997-01-01

This article review some of the key decision points in the historical development of spent fuel reprocessing and waste management practices at the Idaho Chemical Processing Plant that have helped ICPP to successfully accomplish its mission safely and with minimal impact on the environment. Topics include ICPP reprocessing development; batch aluminum-uranium dissolution; continuous aluminum uranium dissolution; batch zirconium dissolution; batch stainless steel dissolution; semicontinuous zirconium dissolution with soluble poison; electrolytic dissolution of stainless steel-clad fuel; graphite-based rover fuel processing; fluorinel fuel processing; ICPP waste management consideration and design decisions; calcination technology development; ICPP calcination demonstration and hot operations; NWCF design, construction, and operation; HLW immobilization technology development. 80 refs., 4 figs

Asteroid Rendezvous Mission Design Using Multiobjective Particle Swarm Optimization

Directory of Open Access Journals (Sweden)

Ya-zhong Luo

2014-01-01

Full Text Available A new preliminary trajectory design method for asteroid rendezvous mission using multiobjective optimization techniques is proposed. This method can overcome the disadvantages of the widely employed Pork-Chop method. The multiobjective integrated launch window and multi-impulse transfer trajectory design model is formulated, which employes minimum-fuel cost and minimum-time transfer as two objective functions. The multiobjective particle swarm optimization (MOPSO is employed to locate the Pareto solution. The optimization results of two different asteroid mission designs show that the proposed approach can effectively and efficiently demonstrate the relations among the mission characteristic parameters such as launch time, transfer time, propellant cost, and number of maneuvers, which will provide very useful reference for practical asteroid mission design. Compared with the PCP method, the proposed approach is demonstrated to be able to provide much more easily used results, obtain better propellant-optimal solutions, and have much better efficiency. The MOPSO shows a very competitive performance with respect to the NSGA-II and the SPEA-II; besides a proposed boundary constraint optimization strategy is testified to be able to improve its performance.

New type fuel exchange system

International Nuclear Information System (INIS)

Meshii, Toshio; Maita, Yasushi; Hirota, Koichi; Kamishima, Yoshio.

1988-01-01

When the reduction of the construction cost of FBRs is considered from the standpoint of the machinery and equipment, to make the size small and to heighten the efficiency are the assigned mission. In order to make a reactor vessel small, it is indispensable to decrease the size of the equipment for fuel exchange installed on the upper part of a core. Mitsubishi Heavy Industries Ltd. carried out the research on the development of a new type fuel exchange system. As for the fuel exchange system for FBRs, it is necessary to change the mode of fuel exchange from that of LWRs, such as handling in the presence of chemically active sodium and inert argon atmosphere covering it and handling under heavy shielding against high radiation. The fuel exchange system for FBRs is composed of a fuel exchanger which inserts, pulls out and transfers fuel and rotary plugs. The mechanism adopted for the new type fuel exchange system that Mitsubishi is developing is explained. The feasibility of the mechanism on the upper part of a core was investigated by water flow test, vibration test and buckling test. The design of the mechanism on the upper part of the core of a demonstration FBR was examined, and the new type fuel exchange system was sufficiently applicable. (Kako, I.)

Les nouveaux carburants pour l'automobile. Carburants oxygénés : emploi et émissions New Automotive Fuels. Oxygenated Fuels: Their Use and Emissions

Directory of Open Access Journals (Sweden)

Guibet J. C.

2006-11-01

Full Text Available A la lumière de résultats nouveaux obtenus à l'IFP et de publications récentes sur le sujet, on étudie les principales répercussions de l'emploi de carburants oxygénés sur les émissions de polluants à l'échapement et sur les risques possibles associés à la manipulation des produits. Les polluants examinés sont les alkyles de plomb, l'oxyde de carbone, les oxydes d'azote, les produits imbrûlés, les aldéhydes et les hydrocarbures aromatiques polynucléaires. Les émissions de fumées et de particules solides par les moteurs diesel font aussi l'objet de quelques commentaires. On aborde également les problèmes de pertes par évaporation et on fournit quelques informations sur la toxicité des alcools et des aldéhydes. L'étude fait apparaître un besoin réel de nouvelles recherches dans le domaine, mais elle indique déjà que l'emploi de produits organiques oxygénés comme carburants ne devrait pas changer l'ordre de grandeur des niveaux de polluants. In the light of new results from IFP and recent publications on the subject, this article examines the main repercussions of the use of oxygenated fuelss on pollutant exhauts emissions and on possible risks associated with the handling of products. The pollutants examined are lead alkyls, carbon monoxide, nitrogen oxides, unburned products, aldehydes and polynuclear aromatic hydrocarbons. Emissions of smoke and solid particles by diesel engines are also the subject of various comments. Likewise, the article takes up the problem of losses by evaporation, and some information is provided on the toxicity of alcohols and aldehydes. This study reveals the real need for further research in the field, but it already shows that the use of oxygenated organic products as fuels should not bring about much change in the order of magnitude of pollutant levels.

Dissolution behavior of irradiated mixed oxide fuel with short stroke shearing for fast reactor reprocessing

International Nuclear Information System (INIS)

Ikeuchi, Hirotomo; Sano, Yuichi; Shibata, Atsuhiro; Koizumi, Tsutomu; Washiya, Tadahiro

2013-01-01

An efficient dissolution process was established for future reprocessing in which mixed-oxide (MOX) fuels with high plutonium contents and dissolver solution with high heavy-metal (HM) concentrations (more than 500 g dm -3 ) will be treated. This dissolution process involves short stroke shearing of fuels (∼10 mm in length). The dissolution kinetics of irradiated MOX fuels and the effects of the Pu content, HM concentration, and fuel form on the dissolution rate were investigated. Irradiated fuel was found to dissolve as 10 2 -10 3 times fast as non-irradiated fuel, but the rate decreased with increasing Pu content. Kinetic analysis based on the fragmentation model, which considers the penetration and diffusion of nitric acid through fuel matrices prior to chemical reaction, indicated that the dissolution rate of irradiated fuel was affected not only by the volume ratio of liquid to solid (L/S ratio) but also by the exposed surface area per unit mole of nitric acid (A/m ratio). The penetration rate of nitric acid is expected to be decreased at high HM concentrations by a reduction in the L/S ratio, but enhanced by shearing the fuel pieces with short strokes and thus enlarging the A/m ratio. (author)

CANDU fuel behaviour under transient conditions

International Nuclear Information System (INIS)

Segel, A.W.L.

1979-04-01

The Canadian R and D program to understand CANDU fuel behaviour under transient conditions is described. Fuel sheath behaviour studies have led to the development of a model of transient plastic strain in inert gas, which integrates the deformation due to several mechanisms. Verification tests demonstrated that on average the model overpredicts strain by 20%. From oxidation kinetics studies a sheath failure embrittlement criterion based on oxygen distribution has been developed. We have also established a rate equation for high-temperature stress-dependent crack formation due to embrittlement of the sheath by beryllium. An electric, simulated fuel element is being used in laboratory tests to characterize the behaviour of fuel in the horizontal. In-reactor, post-dryout tests have been done for several years. There is an axially-segmented, axisymmetric fuel element model in place and a fully two-dimensional code is under development. Laboratory testing of bundles, in its early stages, deals with the effects of geometric distortion and sheath-to-sheath interaction. In-reactor, post-dryout tests of CANDU fuel bundles with extensive central UO 2 melting did not result in fuel fragmentation nor damage to the pressure tube. (author)

Computational fluid dynamics application: slosh analysis of a fuel tank model

International Nuclear Information System (INIS)

Iu, H.S.; Cleghorn, W.L.; Mills, J.K.

2004-01-01

This paper presents the analysis of fluid slosh behaviour inside a fuel tank model. The fuel tank model was a simplified version of a stock fuel tank that has a sloshing noise problem. A commercial CFD software, FLOW-3D, was used to simulate the slosh behaviour. Slosh experiments were performed to verify the computer simulation results. High speed video equipment enhanced with a data acquisition system was used to record the slosh experiments and to obtain the instantaneous sound level of each video frame. Five baffle configurations including the no baffle configuration were considered in the computer simulations and the experiments. The simulation results showed that the best baffle configuration can reduce the mean kinetic energy by 80% from the no baffle configuration in a certain slosh situation. The experimental results showed that 15dB(A) noise reduction can be achieved by the best baffle configuration. The correlation analysis between the mean kinetic energy and the noise level showed that high mean kinetic energy of the fluid does not always correspond to high sloshing noise. High correlation between them only occurs for the slosh situations where the fluid hits the top of the tank and creates noise. (author)

Catastrophic Disruption Threshold and Maximum Deflection from Kinetic Impact

Science.gov (United States)

Cheng, A. F.

2017-12-01

The use of a kinetic impactor to deflect an asteroid on a collision course with Earth was described in the NASA Near-Earth Object Survey and Deflection Analysis of Alternatives (2007) as the most mature approach for asteroid deflection and mitigation. The NASA DART mission will demonstrate asteroid deflection by kinetic impact at the Potentially Hazardous Asteroid 65803 Didymos in October, 2022. The kinetic impactor approach is considered to be applicable with warning times of 10 years or more and with hazardous asteroid diameters of 400 m or less. In principle, a larger kinetic impactor bringing greater kinetic energy could cause a larger deflection, but input of excessive kinetic energy will cause catastrophic disruption of the target, leaving possibly large fragments still on collision course with Earth. Thus the catastrophic disruption threshold limits the maximum deflection from a kinetic impactor. An often-cited rule of thumb states that the maximum deflection is 0.1 times the escape velocity before the target will be disrupted. It turns out this rule of thumb does not work well. A comparison to numerical simulation results shows that a similar rule applies in the gravity limit, for large targets more than 300 m, where the maximum deflection is roughly the escape velocity at momentum enhancement factor β=2. In the gravity limit, the rule of thumb corresponds to pure momentum coupling (μ=1/3), but simulations find a slightly different scaling μ=0.43. In the smaller target size range that kinetic impactors would apply to, the catastrophic disruption limit is strength-controlled. A DART-like impactor won't disrupt any target asteroid down to significantly smaller size than the 50 m below which a hazardous object would not penetrate the atmosphere in any case unless it is unusually strong.

Low Cost Nuclear Thermal Rocket Cermet Fuel Element Environment Testing

Science.gov (United States)

Bradley, David E.; Mireles, Omar R.; Hickman, Robert R.

2011-01-01

Deep space missions with large payloads require high specific impulse (Isp) and relatively high thrust in order to achieve mission goals in reasonable time frames. Conventional, storable propellants produce average Isp. Nuclear thermal rockets (NTR) capable of high Isp thrust have been proposed. NTR employs heat produced by fission reaction to heat and therefore accelerate hydrogen which is then forced through a rocket nozzle providing thrust. Fuel element temperatures are very high (up to 3000K) and hydrogen is highly reactive with most materials at high temperatures. Data covering the effects of high temperature hydrogen exposure on fuel elements is limited. The primary concern is the mechanical failure of fuel elements which employ high-melting-point metals, ceramics or a combination (cermet) as a structural matrix into which the nuclear fuel is distributed. It is not necessary to include fissile material in test samples intended to explore high temperature hydrogen exposure of the structural support matrices. A small-scale test bed designed to heat fuel element samples via non-contact RF heating and expose samples to hydrogen is being developed to assist in optimal material and manufacturing process selection without employing fissile material. This paper details the test bed design and results of testing conducted to date.

pyJac: Analytical Jacobian generator for chemical kinetics

Science.gov (United States)

Niemeyer, Kyle E.; Curtis, Nicholas J.; Sung, Chih-Jen

2017-06-01

Accurate simulations of combustion phenomena require the use of detailed chemical kinetics in order to capture limit phenomena such as ignition and extinction as well as predict pollutant formation. However, the chemical kinetic models for hydrocarbon fuels of practical interest typically have large numbers of species and reactions and exhibit high levels of mathematical stiffness in the governing differential equations, particularly for larger fuel molecules. In order to integrate the stiff equations governing chemical kinetics, generally reactive-flow simulations rely on implicit algorithms that require frequent Jacobian matrix evaluations. Some in situ and a posteriori computational diagnostics methods also require accurate Jacobian matrices, including computational singular perturbation and chemical explosive mode analysis. Typically, finite differences numerically approximate these, but for larger chemical kinetic models this poses significant computational demands since the number of chemical source term evaluations scales with the square of species count. Furthermore, existing analytical Jacobian tools do not optimize evaluations or support emerging SIMD processors such as GPUs. Here we introduce pyJac, a Python-based open-source program that generates analytical Jacobian matrices for use in chemical kinetics modeling and analysis. In addition to producing the necessary customized source code for evaluating reaction rates (including all modern reaction rate formulations), the chemical source terms, and the Jacobian matrix, pyJac uses an optimized evaluation order to minimize computational and memory operations. As a demonstration, we first establish the correctness of the Jacobian matrices for kinetic models of hydrogen, methane, ethylene, and isopentanol oxidation (number of species ranging 13-360) by showing agreement within 0.001% of matrices obtained via automatic differentiation. We then demonstrate the performance achievable on CPUs and GPUs using py

Communication of 8 June 2009 received from the Permanent Mission of the Republic of Korea concerning a non-paper 'The Republic of Korea's suggestion on possible criteria for multilateral approaches to the nuclear fuel cycle'

International Nuclear Information System (INIS)

2009-01-01

The Secretariat has received a communication dated 8 June 2009 from the Permanent Mission of the Republic of Korea, transmitting the text of a non-paper entitled 'The Republic of Korea's Suggestion on Possible Criteria for Multilateral Approaches to the Nuclear Fuel Cycle'. As requested in that communication, the abovementioned non-paper is herewith circulated for the information of all Member States

Navigating the MESSENGER Spacecraft through End of Mission

Science.gov (United States)

Bryan, C. G.; Williams, B. G.; Williams, K. E.; Taylor, A. H.; Carranza, E.; Page, B. R.; Stanbridge, D. R.; Mazarico, E.; Neumann, G. A.; O'Shaughnessy, D. J.; McAdams, J. V.; Calloway, A. B.

2015-12-01

The MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) spacecraft orbited the planet Mercury from March 2011 until the end of April 2015, when it impacted the planetary surface after propellant reserves used to maintain the orbit were depleted. This highly successful mission was led by the principal investigator, Sean C. Solomon, of Columbia University. The Johns Hopkins University Applied Physics Laboratory (JHU/APL) designed and assembled the spacecraft and served as the home for spacecraft operations. Spacecraft navigation for the entirety of the mission was provided by the Space Navigation and Flight Dynamics Practice (SNAFD) of KinetX Aerospace. Orbit determination (OD) solutions were generated through processing of radiometric tracking data provided by NASA's Deep Space Network (DSN) using the MIRAGE suite of orbital analysis tools. The MESSENGER orbit was highly eccentric, with periapsis at a high northern latitude and periapsis altitude in the range 200-500 km for most of the orbital mission phase. In a low-altitude "hover campaign" during the final two months of the mission, periapsis altitudes were maintained within a narrow range between about 35 km and 5 km. Navigating a spacecraft so near a planetary surface presented special challenges. Tasks required to meet those challenges included the modeling and estimation of Mercury's gravity field and of solar and planetary radiation pressure, and the design of frequent orbit-correction maneuvers. Superior solar conjunction also presented observational modeling issues. One key to the overall success of the low-altitude hover campaign was a strategy to utilize data from an onboard laser altimeter as a cross-check on the navigation team's reconstructed and predicted estimates of periapsis altitude. Data obtained from the Mercury Laser Altimeter (MLA) on a daily basis provided near-real-time feedback that proved invaluable in evaluating alternative orbit estimation strategies, and

STS-61 mission director's post-mission report

Science.gov (United States)

Newman, Ronald L.

1995-01-01

To ensure the success of the complex Hubble Space Telescope servicing mission, STS-61, NASA established a number of independent review groups to assess management, design, planning, and preparation for the mission. One of the resulting recommendations for mission success was that an overall Mission Director be appointed to coordinate management activities of the Space Shuttle and Hubble programs and to consolidate results of the team reviews and expedite responses to recommendations. This report presents pre-mission events important to the experience base of mission management, with related Mission Director's recommendations following the event(s) to which they apply. All Mission Director's recommendations are presented collectively in an appendix. Other appendixes contain recommendations from the various review groups, including Payload Officers, the JSC Extravehicular Activity (EVA) Section, JSC EVA Management Office, JSC Crew and Thermal Systems Division, and the STS-61 crew itself. This report also lists mission events in chronological order and includes as an appendix a post-mission summary by the lead Payload Deployment and Retrieval System Officer. Recommendations range from those pertaining to specific component use or operating techniques to those for improved management, review, planning, and safety procedures.

Near-optimal operation of dual-fuel launch vehicles

International Nuclear Information System (INIS)

Ardema, M.D.; Chou, H.C.; Bowles, J.V.

1994-01-01

Current studies of single-stage-to-orbit (SSTO) launch vehicles are focused on all-rocket propulsion systems. One option for such vehicles is the use of dual-fuel (liquid hydrocarbon and liquid hydrogen (LH 2 )), for a portion of the mission. As compared with LH 2 , hydrocarbon fuel has higher density and produces higher thrust-to-weight, but has lower specific impulse. The advantages of hydrocarbon fuel are important early in the ascent trajectory, and its use may be expected to lead to reduced vehicle size and weight. Because LH 2 is also needed for cooling purposes, in the early portion of the trajectory both fuels must be burned simultaneously. Later in the ascent, when vehicle weight is lower, specific impulse is the key parameter, indicating single-fuel LH 2 use

Criticality safety evaluation report for FFTF 42% fuel assemblies

International Nuclear Information System (INIS)

Richard, R.F.

1997-01-01

An FFTF tritium/isotope production mission will require a new fuel supply. The reference design core will use a mixed oxide fuel nominally enriched to 40 wt% Pu. This enrichment is significantly higher than that of the standard Driver Fuel Assemblies used in past operations. Consequently, criticality safety for handling and storage of this fuel must be addressed. The purpose of this document is to begin the process by determining the minimum critical number for these new fuel assemblies in water, sodium and air. This analysis is preliminary and further work can be done to refine the results reported here. Analysis was initially done using 45 wt 5 PuO. Additionally, a preliminary assessment is done concerning storage of these fuel assemblies in Interim Decay Storage (IDS), Fuel Storage Facility (FSF), and Core Component Containers/Interim Storage Casks (CCC/ISC)

Mitigation-relevant science with Don Quijote - a European-led mission to a near-Earth asteroid

Science.gov (United States)

Harris, A. W.; Galvez, A.; Benz, W.; Fitzsimmons, A.; Green, S. F.; Michel, P.; Valsecchi, G.; Paetzold, M.; Haeusler, B.; Carnelli, I.

The Don Quijote concept includes a rendezvous spacecraft and an impactor vehicle The main aim of the mission is to carry out an experiment to demonstrate the modification of a near-Earth asteroid s orbit in a controlled way as a first step in establishing mitigation measures against an eventual hazardous object In particular the spacecraft would study the physical properties of the target asteroid and the effects of a kinetic impact on its dynamical state It is also expected that some spacecraft resources will be available for more general solar-system science investigations The Don Quijote mission is currently at the phase-A stage during which a number of European consortia of industrial and scientific partners will study its technical feasibility and potential scientific return The basic mission concept current scientific issues and the possibilities for international participation in the mission will be discussed

A kinetic study on the decomposition of 5-hydroxymethylfurfural into levulinic acid

NARCIS (Netherlands)

Girisuta, B.; Janssen, L. P. B. M.; Heeres, H. J.

2006-01-01

Levulinic acid (LA), accessible by the acid catalyzed degradation of biomass, is potentially a very versatile green intermediate chemical for the synthesis of various (bulk) chemicals for applications like fuel additives, polymers, and resin precursors. We report here a kinetic study on one of the

Kinetic study on the acid-catalyzed hydrolysis of cellulose to levulinic acid

NARCIS (Netherlands)

Girisuta, B.; Janssen, L. P. B. M.; Heeres, H. J.

2007-01-01

A variety of interesting bulk chemicals is accessible by the acid-catalyzed hydrolysis of cellulose. An interesting example is levulinic acid, a versatile precursor for fuel additives, polymers, and resins. A detailed kinetic study on the acid-catalyzed hydrolysis of cellulose to levulinic acid is

Light weight radioisotope heater unit (LWRHU) production for the Cassini mission

International Nuclear Information System (INIS)

Rinehart, G.H.

1997-01-01

The Light-Weight Radioisotope Heater Unit (LWRHU) is a [sup 238]PuO[sub 2] fueled heat source designed to provide one thermal watt in each of various locations on a spacecraft. The heat sources are required to maintain the temperature of specific components within normal operating ranges. The heat source consists of a hot- pressed [sup 238]PuO[sub 2] fuel pellet, a Pt-3ORh vented capsule, a pyrolytic graphite insulator, and a woven graphite aeroshell assembly. Los Alamos National Laboratory has fabricated 180 heat sources, 157 of which will be used on the Cassini mission

Oxygen Reduction Kinetics of La2-xSrxNiO 4+delta Electrodes for Solid Oxide Fuel Cells

Science.gov (United States)

Guan, Bo

In the development of intermediate temperature solid oxide fuel cell (IT-SOFC), mixed ionic-electronic conductors (MIEC) have drawn big interests due to their both ionic and electronic species transport which can enlarge the 3-dimension of the cathode network. This thesis presents an investigation of MIEC of Ruddlesden-popper (RP) phases like K2NiF4 type La2NiO4+delta (LNO)-based oxides which have interesting transport, catalytic properties and suitable thermal expansion coefficients. The motivation of this present work is to further understand the fundamental of the effect of Sr doing on the oxygen reduction reaction (ORR) kinetics of LNO cathode. Porous symmetrical cells of La2-xSrxNiO4+delta (0≤x≤0.4) were fabricated and characterized by electrochemical impedance spectroscopy (EIS) in different PO2 from temperature range of 600˜800°C. The spectra were analyzed based on the impedance model introduced by Adler et al. The rate determining steps (RDS) for ORR were proposed and the responsible reasons were discussed. The overall polarization resistances of doped samples increase with Sr level. Surface oxygen exchange and bulk ionic diffusion co-control the ORR kinetics. With high Sr content (x=0.3, 0.4), oxygen ion transfer resistance between nickelate/electrolyte is observed. However for porous symmetrical cells it is hard to associate the resistance from EIS directly to each ORR elementary processes because of the difficulty in describing the microstructure of the porous electrode. The dense electrode configuration was adopted in this thesis. By using the dense electrode, the surface area, the thickness of electrode, the interface between electrode and electrolyte and lastly the 3PB are theoretically well-defined. Through this method, there is a good chance to distinguish the contribution of surface exchange from other processes. Dense and thin electrode layers in thickness of ˜40 mum are fabricated by using a novel spray modified pressing method. Negligible

GCFR Fuels and Materials Program at Argonne National Laboratory

International Nuclear Information System (INIS)

Neimark, L.A.; Greenberg, S.; Johnson, C.E.; Purohit, A.; Liu, Y.Y.; Rest, J.; Reimann, K.J.; McLennan, G.A.

1979-01-01

The F-5 fuel-pin irradiation experiment in EBR-II is a cornerstone of the GCFR program. It is the largest-scale fuel-pin experiment in the present program and will provide data on the performance of pins and a pin-support structure that are prototypic of the GCFR Demonstration Plant. The fuel pins are presently undergoing interim examination after successfully achieving 4.6 at.% burnup. Studies of the thermodynamics and kinetics of the U--Cs--O system, supplemented by analysis of the results of previously irradiated fuel pins, have led to the incorporation of fuel-design modifications in the F-5 experiment to insure adequate performance of the vented fuel. The effect of ribbing, as well as the ribbing process, on the short- and long-term structural performance of fuel-pin cladding is being evaluated via in-reactor and out-of-reactor tests and with the fuel-element modeling code LIFE-GCFR and the finite element program, ADINA

Design and analysis of RTGs for CRAF and Cassini missions

International Nuclear Information System (INIS)

Schock, A.; Noravian, H.; Or, C.; Sankarankandath, K.

1991-01-01

The paper describes the design and analysis of Radioisotope Thermoelectric Generators (RTGs) integrated with the Jet Proplusion Laboratory's CRAF (Comet Rendezvous and Asteroid Flyby) and Cassini Spacecraft. The principal purpose of the CRAF mission is the study of Asteroids and comets, and the principal purpose of the Cassini mission is the study of asteroids, Saturn, and its moons (particularly Titan). Both misions will employ the Mariner/Mark-2 spacecraft, and each will be powered by two GPHS-RTGs (General Purpose Heat Source-RTGs). JPL's spacecraft designers wish to locate the two RTGs in close proximity to each other, resulting in mutual and unsymmetrical obstruction of their heat rejection paths. To support JPL's design studies, the U.S. Department of Energy asked Fairchild to determine the effect of the RTGs' proximity on their power output. As described in the paper, this required the development of novel analysis methods and computer codes for the coupled thermal and electrical analysis of obstructed RTGs with axial and circumferential temperature, voltage, and current variations. The code was validated against measured data of unobstructed RTG tests, and was used for the detailed analysis of the obstructed CRAF and Cassini RTGs. Also described is a new method for predicting the combined effect of fuel decay and thermoelectric degradation on the output of obstructed RTGs, which amounts for the effect of diminishing temperatures on degradation rates. For the 24-degree separation angle of JPL's original baseline design, and for the 35-degree RTG separation of JPL's revised design, the computed results indicate that the mutually obstructed GPHS/RTGs with standard fuel loading and operating temperatures can comfortably meet the JPL-specified power requirements for the CRAF mission and almost meet the specified requirements for the Cassini mission

Nuclear safety. Romania. Nuclear fuel performance, modeling and evaluation. Technical report. Report prepared for the Government of Romania

Energy Technology Data Exchange (ETDEWEB)

Hsu, Tai-Ran

1992-08-01

The document contains the technical report submitted by an IAEA expert as a result of a field mission undertaken in June-July 1992 at the Institute for Nuclear Power Research, Pitesti, Romania, in the frame of the project IAEA/UNDP-Rom/87/002 (Nuclear Safety). The objectives of the mission were to assist the Institute in understanding the physical processes during fuel power cycling, to develop a computer code for power cycling behavior of fuel elements under both normal operation and power transient conditions, to advise on the design of irradiation tests aiming at the evaluation of fuel behavior during power cycling, and on the application of Computer-Aided Design (CAD) for fuel bundles.

Nuclear safety. Romania. Nuclear fuel performance, modeling and evaluation. Technical report. Report prepared for the Government of Romania

International Nuclear Information System (INIS)

Hsu, Tai-Ran

1992-08-01

The document contains the technical report submitted by an IAEA expert as a result of a field mission undertaken in June-July 1992 at the Institute for Nuclear Power Research, Pitesti, Romania, in the frame of the project IAEA/UNDP-Rom/87/002 (Nuclear Safety). The objectives of the mission were to assist the Institute in understanding the physical processes during fuel power cycling, to develop a computer code for power cycling behavior of fuel elements under both normal operation and power transient conditions, to advise on the design of irradiation tests aiming at the evaluation of fuel behavior during power cycling, and on the application of Computer-Aided Design (CAD) for fuel bundles

Combustion of High Molecular Weight Hydrocarbon Fuels and JP-8 at Moderate Pressures

Science.gov (United States)

2016-07-26

1. Introduction Fundamental knowledge of mechanisms of autoignition of condensed hydrocarbon fuels at elevated pressures is essential for accurate...particular JP-8) and surrogates of jet-fuels in laminar non-uniform flows at elevated pressures upto 2.5 MPa. Experimental and kinetic modeling studies...AGENCY NAME(S) AND ADDRESS (ES) U.S. Army Research Office P.O. Box 12211 Research Triangle Park, NC 27709-2211 Combustion, Jet Fuels, JP-8, Elevated

Fuel-assembly vibration-induced neutron noise in PWRs

International Nuclear Information System (INIS)

Sweeney, F.J.; Renier, J.P.

1983-01-01

Space-dependent reactor kinetics calculations were performed to interpret observed increases in the amplitude of pressurized water reactor (PWR), ex-core neutron detector noise with increasing fuel burnup and correspondingly decreasing soluble boron concentration. These noise amplitude increases have occurred at both low frequencies (< 1.0 Hz) and in the 2.0- to 4.0-Hz frequency range. The noise amplitude increases in the 2.0- to 4.0-Hz frequency range have usually been accompanied by a decrease in the fundamental mode fuel assembly resonant frequency from 3.5 to 2.5 Hz over a fuel cycle, which has also been attributed to grid spacer spring relaxation

Catalyst development and systems analysis of methanol partial oxidation for the fuel processor - fuel cell integration

Energy Technology Data Exchange (ETDEWEB)

Newson, E; Mizsey, P; Hottinger, P; Truong, T B; Roth, F von; Schucan, Th H [Paul Scherrer Inst. (PSI), Villigen (Switzerland)

1999-08-01

Methanol partial oxidation (pox) to produce hydrogen for mobile fuel cell applications has proved initially more successful than hydrocarbon pox. Recent results of catalyst screening and kinetic studies with methanol show that hydrogen production rates have reached 7000 litres/hour/(litre reactor volume) for the dry pox route and 12,000 litres/hour/(litre reactor volume) for wet pox. These rates are equivalent to 21 and 35 kW{sub th}/(litre reactor volume) respectively. The reaction engineering problems remain to be solved for dry pox due to the significant exotherm of the reaction (hot spots of 100-200{sup o}C), but wet pox is essentially isothermal in operation. Analyses of the integrated fuel processor - fuel cell systems show that two routes are available to satisfy the sensitivity of the fuel cell catalysts to carbon monoxide, i.e. a preferential oxidation reactor or a membrane separator. Targets for individual system components are evaluated for the base and best case systems for both routes to reach the combined 40% efficiency required for the integrated fuel processor - fuel cell system. (author) 2 figs., 1 tab., 3 refs.

The qualification of a new fuel - the operator's perspective

International Nuclear Information System (INIS)

Koonen, E.

2001-01-01

Operators of a research reactor generally have as their primary mission to provide the users with a safe, reliable and economic source of neutrons. They have to assure the availability of that source, while respecting the requirements of the license. The fuel management is one of the major aspects they have to tackle in order to fulfill their mission. This sometimes includes the qualification of a new fuel and the core conversion. The operator has to assure that the whole process is conducted in such manner that the availability of the neutron source is only minimally disturbed, that the costs are kept under control and the characteristics of the neutron source are preserved. This paper gives an overview of the various issues that the operator has to consider. (author)

UAV Mission Optimization through Hybrid-Electric Propulsion

Science.gov (United States)

Blackwelder, Philip Scott

Hybrid-electric powertrain leverages the superior range of petrol based systems with the quiet and emission free benefits of electric propulsion. The major caveat to hybrid-electric powertrain in an airplane is that it is inherently heavier than conventional petroleum powertrain due mostly to the low energy density of battery technology. The first goal of this research is to develop mission planning code to match powertrain components for a small-scale unmanned aerial vehicle (UAV) to complete a standard surveillance mission within a set of user input parameters. The second goal is to promote low acoustic profile loitering through mid-flight engine starting. The two means by which midmission engine starting will be addressed is through reverse thrust from the propeller and a servo actuated gear to couple and decouple the engine and motor. The mission planning code calculates the power required to complete a mission and assists the user in sourcing powertrain components including the propeller, motor, battery, motor controller, engine and fuel. Reverse thrust engine starting involves characterizing an off the shelf variable pitch propeller and using its torque coefficient to calculate the advance ratio required to provide sufficient torque and speed to start an engine. Geared engine starting works like the starter in a conventional automobile. A servo actuated gear will couple the motor to the engine to start it and decouple once the engine has started. Reverse thrust engine starting was unsuccessful due to limitations of available off the shelf variable pitch propellers. However, reverse thrust engine starting could be realized through a custom larger diameter propeller. Geared engine starting was a success, though the system was unable to run fully as intended. Due to counter-clockwise crank rotation of the engine and the right-hand threads on the crankshaft, cranking the engine resulted in the nut securing the engine starter gear to back off as the engine cranked

Westinghouse fuel manufacturing systems: a step change in performance improvements

International Nuclear Information System (INIS)

Mutyala, Meena

2009-01-01

Today's competitive electrical generation industry demands that nuclear power plant operators minimize total operating costs, including fuel cycle cost while maintaining flawless fuel performance. The mission of Westinghouse Nuclear Fuel is to be the industry's most responsive supplier of flawless, value added fuel products and services, as judged by our customers. As nuclear is fast becoming the choice of many countries, existing manufacturing plants and facilities are once again running at full capacity. In this context Westinghouse Nuclear Fuel is committed to deliver a step change in performance improvement worldwide through its manufacturing operations by the introduction of a set of fundamentals collectively named the 'Westinghouse Fuel Manufacturing System' (WFMS), whose key principles are discussed in this paper. (author)

Determination of the temperature coefficients and the kinetic parameters for the HTTR safety analysis

International Nuclear Information System (INIS)

Tokuhara, K.; Nakata, T.; Murata, I.; Yamashita, K.; Shindo, R.

1991-01-01

This report describes the calculational methods which were employed to determine the temperature coefficients and the kinetic parameters for the safety analysis in the HTTR (High Temperature Engineering Test Reactor). The temperature coefficients (doppler, moderator temperature) and the kinetic parameters (prompt neutron life time; l, effective delayed neutron fraction; β eff) are important for the point model core dynamic analysis and should be evaluated properly. The temperature coefficients were calculated by the whole core model. Doppler coefficient was evaluated under the conditions of all control rods withdrawn and the uniform change of fuel temperature. The minimum and the maximum value of the evaluated doppler coefficients in a burnup cycle are -4.6x10 -5 and -1.5x10 -5 ΔK/K/deg. C respectively. The moderator temperature coefficient was evaluated under the conditions of all control rods withdrawn and the uniform change of moderator temperature. The minimum and the maximum value of the evaluated moderator temperature coefficients in a burnup cycle are -17.1x10 -5 and 0.99x10 -5 ΔK/K/deg. C respectively. In spite of positive moderator temperature coefficient, the power coefficient is always negative. Therefore the HTTR possesses inherent power-suppressing feed back characteristic in all operating condition. We surveyed the effects of the Xe existence, the control rods existence, the fuel temperature and the region in which the temperature was changed on the moderator temperature coefficients. The kinetic parameters were calculated by the perturbation method with the whole core model. The minimum and the maximum value of the evaluated effective delayed neutron fraction (β eff) are 0.0047 and 0.0065 respectively. These of the evaluated prompt neutron life time (l) are 0.67 and 0.78 ms respectively. We have surveyed the effects of the fuel depletion and the core power level on these parameters, and considered these effects on the kinetic parameters. From

Application of ac impedance in fuel cell research and development

Energy Technology Data Exchange (ETDEWEB)

Selman, J R; Lin, Y P [Illinois Inst. of Tech., Chicago, IL (United States). Dept. of Chemical Engineering

1993-10-01

In applying ac impedance to fuel cells and their porous (gas diffusion) electrodes the emphasis lies on different fuel cell components, and their properties, according to the fuel cell type. The focus has been directed at the electrode/electrolyte interface in MCFC and PAFC, whereas in SOFC and PEMFC the ionic/electronic conductivity of the electrolyte or the characteristics of its composite with the electrocatalyst is of primary interest. The limitations of ac impedance in fuel cell application are in part due to difficulties of interpretation and in part due to experimental difficulties because of the generally fast electrode reaction kinetics. Further research directions are indicated. (author)

Fuel-Flexible Combustion System for Co-production Plant Applications

Energy Technology Data Exchange (ETDEWEB)

Joel Haynes; Justin Brumberg; Venkatraman Iyer; Jonathan Janssen; Ben Lacy; Matt Mosbacher; Craig Russell; Ertan Yilmaz; Williams York; Willy Ziminsky; Tim Lieuwen; Suresh Menon; Jerry Seitzman; Ashok Anand; Patrick May

2008-12-31

Future high-efficiency, low-emission generation plants that produce electric power, transportation fuels, and/or chemicals from fossil fuel feed stocks require a new class of fuel-flexible combustors. In this program, a validated combustor approach was developed which enables single-digit NO{sub x} operation for a future generation plants with low-Btu off gas and allows the flexibility of process-independent backup with natural gas. This combustion technology overcomes the limitations of current syngas gas turbine combustion systems, which are designed on a site-by-site basis, and enable improved future co-generation plant designs. In this capacity, the fuel-flexible combustor enhances the efficiency and productivity of future co-production plants. In task 2, a summary of market requested fuel gas compositions was created and the syngas fuel space was characterized. Additionally, a technology matrix and chemical kinetic models were used to evaluate various combustion technologies and to select two combustor concepts. In task 4 systems analysis of a co-production plant in conjunction with chemical kinetic analysis was performed to determine the desired combustor operating conditions for the burner concepts. Task 5 discusses the experimental evaluation of three syngas capable combustor designs. The hybrid combustor, Prototype-1 utilized a diffusion flame approach for syngas fuels with a lean premixed swirl concept for natural gas fuels for both syngas and natural gas fuels at FA+e gas turbine conditions. The hybrid nozzle was sized to accommodate syngas fuels ranging from {approx}100 to 280 btu/scf and with a diffusion tip geometry optimized for Early Entry Co-generation Plant (EECP) fuel compositions. The swozzle concept utilized existing GE DLN design methodologies to eliminate flow separation and enhance fuel-air mixing. With changing business priorities, a fully premixed natural gas & syngas nozzle, Protoytpe-1N, was also developed later in the program. It did

Systematic technology evaluation program for SiC/SiC composite-based accident-tolerant LWR fuel cladding and core structures: Revision 2015

Energy Technology Data Exchange (ETDEWEB)

Katoh, Yutai [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Terrani, Kurt A. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

2015-08-01

Fuels and core structures in current light water reactors (LWR’s) are vulnerable to catastrophic failure in severe accidents as unfortunately evidenced by the March 2011 Fukushima Dai-ichi Nuclear Power Plant Accident. This vulnerability is attributed primarily to the rapid oxidation kinetics of zirconium alloys in a water vapor environment at very high temperatures. Zr alloys are the primary material in LWR cores except for the fuel itself. Therefore, alternative materials with reduced oxidation kinetics as compared to zirconium alloys are sought to enable enhanced accident-tolerant fuels and cores.

NASA Glenn Research Center Electrochemistry Branch Battery and Fuel Cell Development Overview

Science.gov (United States)

Manzo, Michelle A.

2011-01-01

This presentation covers an overview of NASA Glenn s history and heritage in the development of electrochemical systems for aerospace applications. Current developments related to batteries and fuel cells are addressed. Specific areas of focus are Li-ion batteries and Polymer Electrolyte Membrane Fuel cells systems and their development for future Exploration missions.

Fuel Price Effects on Readiness

Science.gov (United States)

2014-05-01

have also excluded liquefied propane gas ( LPG ), from this study. 10 through four IDIQ...Wide Fuel Management 1. DLA’s Role DLA-E has the mission of acquiring, storing, selling, and distributing energy including petroleum, natural gas ...energy, and installations also use energy in the form of electricity (11 percent), natural gas (8 percent), and coal (2 percent). See Schwartz, Blakely

Fundamental and semi-global kinetic mechanisms for hydrocarbon combustion. Final report, March 1977-October 1980

Energy Technology Data Exchange (ETDEWEB)

Dryer, F L; Glassman, I; Brezinsky, K

1981-03-01

Over the past three and one half years, substantial research efforts of the Princeton Fuels Research Group have been directed towards the development of simplified mechanisms which would accurately describe the oxidation of hydrocarbons fuels. The objectives of this combustion research included the study of semi-empirical modeling (that is an overall description) of the chemical kinetic mechanisms of simple hydrocarbon fuels. Such fuels include the alkanes: ethane, propane, butane, hexane and octane as well as the critically important alkenes: ethene, propene and butene. As an extension to this work, the study of the detailed radical species characteristics of combustion systems was initiated as another major aspect of the program, with emphasis on the role of the OH and HO/sub 2/ radicals. Finally, the studies of important alternative fuel problems linked the program to longer range approaches to the energy supply question. Studies of alternative fuels composed the major elements of this area of the program. The efforts on methanol research were completed, and while the aromatics aspects of the DOE work have been a direct extension of efforts supported by the Air Force Office of Scientific Research, they represented a significant part of the overall research effort. The emphasis in the proposed program is to provide further fundamental understanding of the oxidation of hydrocarbon fuels which will be useful in guiding engineering approaches. Although the scope of program ranges from the fundamentals of chemical kinetics to that of alternative fuel combustion, the objective in mind is to provide insight and guidance to the understanding of practical combustion environments. The key to our approach has been our understanding of the fundamental combustion chemistry and its relation to the important practical combustion problems which exist in implementing energy efficient, alternate fuels technologies.

Study of the aqueous corrosion mechanisms and kinetics of the AlFeNi aluminium based alloy used for the fuel cladding in the Jules Horowitz research reactor

International Nuclear Information System (INIS)

Wintergerst, M.

2009-05-01

For the Jules Horowitz new material-testing reactor (JHR), an aluminium base alloy, called AlFeNi, will be used for the cladding of the fuel plates. This alloy (Al - 1% Fe - 1% Ni - 1 % Mg), which is already used as fuel cladding, was developed for its good corrosion resistance in water at high temperatures. However, few studies dealing with the alteration process in water and the relationships with irradiation effects have been performed on this alloy. The conception of the JHR fuel requires a better knowledge of the corrosion mechanisms. Corrosion tests were performed in autoclaves at 70 C, 165 C and 250 C on AlFeNi plates representative of the fuel cladding. Several techniques were used to characterize the corrosion scale: SEM, TEM, EPMA, XRD, Raman spectroscopy. Our observations show that the corrosion scale is made of two main layers: a dense amorphous scale close to the metal and a porous crystalline scale in contact with the water. More than the morphology, the chemical compositions of both layers are different. This duplex structure results from a mixed growth mechanism: an anionic growth to develop the inner oxide and a cationic diffusion followed by a dissolution-precipitation process to form the outer one. Dynamic experiments at 70 C and corrosion kinetics measurements have demonstrated that the oxide growth process is controlled by a diffusion step associated to a dissolution/precipitation process. A corrosion mechanism of the AlFeNi alloy in aqueous media has been proposed. Then post-irradiation exams performed on irradiated fuel plates were used to investigate the effects of the irradiation on the corrosion behaviour in the reactor core. (author)

NASA Double Asteroid Redirection Test (DART) Trajectory Validation and Robutness

Science.gov (United States)

Sarli, Bruno V.; Ozimek, Martin T.; Atchison, Justin A.; Englander, Jacob A.; Barbee, Brent W.

2017-01-01

The Double Asteroid Redirection Test (DART) mission will be the first to test the concept of a kinetic impactor. Several studies have been made on asteroid redirection and impact mitigation, however, to this date no mission tested the proposed concepts. An impact study on a representative body allows the measurement of the effects on the target's orbit and physical structure. With this goal, DART's objective is to verify the effectiveness of the kinetic impact concept for planetary defense. The spacecraft uses solar electric propulsion to escape Earth, fly by (138971) 2001 CB21 for impact rehearsal, and impact Didymos-B, the secondary body of the binary (65803) Didymos system. This work focuses on the heliocentric transfer design part of the mission with the validation of the baseline trajectory, performance comparison to other mission objectives, and assessment of the baseline robustness to missed thrust events. Results show a good performance of the selected trajectory for different mission objectives: latest possible escape date, maximum kinetic energy on impact, shortest possible time of flight, and use of an Earth swing-by. The baseline trajectory was shown to be robust to a missed thrust with 1% of fuel margin being enough to recover the mission for failures of more than 14 days.

Recent Progress in the Development of Diesel Surrogate Fuels

Energy Technology Data Exchange (ETDEWEB)

Pitz, W J; Mueller, C J

2009-12-09

There has been much recent progress in the area of surrogate fuels for diesel. In the last few years, experiments and modeling have been performed on higher molecular weight components of relevance to diesel fuel such as n-hexadecane (n-cetane) and 2,2,4,4,6,8,8-heptamethylnonane (iso-cetane). Chemical kinetic models have been developed for all the n-alkanes up to 16 carbon atoms. Also, there has been much experimental and modeling work on lower molecular weight surrogate components such as n-decane and n-dodecane that are most relevant to jet fuel surrogates, but are also relevant to diesel surrogates where simulation of the full boiling point range is desired. For two-ring compounds, experimental work on decalin and tetralin recently has been published. For multi-component surrogate fuel mixtures, recent work on modeling of these mixtures and comparisons to real diesel fuel is reviewed. Detailed chemical kinetic models for surrogate fuels are very large in size. Significant progress also has been made in improving the mechanism reduction tools that are needed to make these large models practicable in multi-dimensional reacting flow simulations of diesel combustion. Nevertheless, major research gaps remain. In the case of iso-alkanes, there are experiments and modeling work on only one of relevance to diesel: iso-cetane. Also, the iso-alkanes in diesel are lightly branched and no detailed chemical kinetic models or experimental investigations are available for such compounds. More components are needed to fill out the iso-alkane boiling point range. For the aromatic class of compounds, there has been no new work for compounds in the boiling point range of diesel. Most of the new work has been on alkyl aromatics that are of the range C7 to C8, below the C10 to C20 range that is needed. For the chemical class of cycloalkanes, experiments and modeling on higher molecular weight components are warranted. Finally for multi-component surrogates needed to treat real

Communication dated 30 May 2007 from the Permanent Mission of the United Kingdom of Great Britain and Northern Ireland to the IAEA concerning enrichment bonds - A voluntary scheme for reliable access to nuclear fuel

International Nuclear Information System (INIS)

2007-01-01

The Secretariat has received a letter dated 30 May 2007 from the Permanent Mission of the United Kingdom of Great Britain and Northern Ireland to the IAEA attaching a UK Non-paper entitled 'Food for Thought: Enrichment Bonds - A Voluntary Scheme for Reliable Access to Nuclear Fuel'. As requested in that letter, the letter and the attachment is now being circulated for the information of all Member States

Kinetic physics in ICF: present understanding and future directions

Science.gov (United States)

Rinderknecht, Hans G.; Amendt, P. A.; Wilks, S. C.; Collins, G.

2018-06-01

Kinetic physics has the potential to impact the performance of indirect-drive inertial confinement fusion (ICF) experiments. Systematic anomalies in the National Ignition Facility implosion dataset have been identified in which kinetic physics may play a role, including inferred missing energy in the hohlraum, drive asymmetry in near-vacuum hohlraums, low areal density and high burn-averaged ion temperatures (〈Ti 〉) compared with mainline simulations, and low ratios of the DD-neutron and DT-neutron yields and inferred 〈Ti 〉. Several components of ICF implosions are likely to be influenced or dominated by kinetic physics: laser-plasma interactions in the LEH and hohlraum interior; the hohlraum wall blowoff, blowoff/gas and blowoff/ablator interfaces; the ablator and ablator/ice interface; and the DT fuel all present conditions in which kinetic physics can significantly affect the dynamics. This review presents the assembled experimental data and simulation results to date, which indicate that the effects of long mean-free-path plasma phenomena and self-generated electromagnetic fields may have a significant impact in ICF targets. Simulation and experimental efforts are proposed to definitively quantify the importance of these effects at ignition-relevant conditions, including priorities for ongoing study.

Exploring the chemical kinetics of partially oxidized intermediates by combining experiments, theory, and kinetic modeling.

Science.gov (United States)

Hoyermann, Karlheinz; Mauß, Fabian; Olzmann, Matthias; Welz, Oliver; Zeuch, Thomas

2017-07-19

Partially oxidized intermediates play a central role in combustion and atmospheric chemistry. In this perspective, we focus on the chemical kinetics of alkoxy radicals, peroxy radicals, and Criegee intermediates, which are key species in both combustion and atmospheric environments. These reactive intermediates feature a broad spectrum of chemical diversity. Their reactivity is central to our understanding of how volatile organic compounds are degraded in the atmosphere and converted into secondary organic aerosol. Moreover, they sensitively determine ignition timing in internal combustion engines. The intention of this perspective article is to provide the reader with information about the general mechanisms of reactions initiated by addition of atomic and molecular oxygen to alkyl radicals and ozone to alkenes. We will focus on critical branching points in the subsequent reaction mechanisms and discuss them from a consistent point of view. As a first example of our integrated approach, we will show how experiment, theory, and kinetic modeling have been successfully combined in the first infrared detection of Criegee intermediates during the gas phase ozonolysis. As a second example, we will examine the ignition timing of n-heptane/air mixtures at low and intermediate temperatures. Here, we present a reduced, fuel size independent kinetic model of the complex chemistry initiated by peroxy radicals that has been successfully applied to simulate standard n-heptane combustion experiments.

Scramjet Combustor Simulations Using Reduced Chemical Kinetics for Practical Fuels

Science.gov (United States)

2003-12-01

JP-8 kinetics and soot models into the UNICORN CFD code (Montgomery et al., 2003a) NSF Phase I and II SBIRs for development of a computer-assisted...the consequent large relative ratio of communication to computation, which increases as the number of processors increases. Table 6. CPU Times for 2-D...divided by diameter QSS quasi-steady state REI Reaction Engineering International UNICORN UNsteady Ignition and COmbustion with ReactioNs VULCAN Viscous Upwind aLgorithm for Complex flow ANalysis

Measurements of fuel temperature coefficient of reactivity on a commercial AGR

International Nuclear Information System (INIS)

Telford, A.; Bridge, M.J.

1978-01-01

Tests have been carried out on the commercial AGR at Hikley Point to determine the fuel temperature coefficient of reactivity, an important safety related parameter. Reactor neutron flux was measured during transients induced by movement of a bank of control rods from one steady position to another. An inverse kinetics analysis was applied to the measured flux to determine the change which occured in core reactivity as the fuel temperature changed. The variation of mean fuel temperature was deduced from the flux transient by means of a nine-plane thermal hydraulics representation of the AGR fuel channel. Results so far obtained confirm the predicted variation of fuel temperature coefficient with butn-up. (author)

C-5M Fuel Efficiency Through MFOQA Data Analysis

Science.gov (United States)

2015-03-26

then contribute to more accurate fuel loading and more efficient fleet fuel usage. Flight Operations Quality Assurance (FOQA) data uses the quick access ...into the ranges in Table 2. Visual Basic ( VBA ) code was written to quickly parse an entire mission (one of the thirty samples) into usable cruise...segments within the Altitude ranges of Table 2. The logic for focusing upon stable cruise flight segments was outlined in Chapter II. The VBA code

Improvement performance and emissions in a diesel engine dual-fueled with natural gas; Tennen gas dual fuel diesel kikan no seino haishutsu gas tokusei no kaizen

Energy Technology Data Exchange (ETDEWEB)

Nakayama, S; Okamoto, T; Kusaka, J; Daisho, Y; Kihara, R; Saito, T [Waseda University, Tokyo (Japan)

1997-10-01

This paper deals with a study on combustion and emission characteristics of a direct injection diesel engine dual-fueled with natural gas. Dual fueling systems tend to emit high unburned fuel especially at low load, resulting in a decreased thermal efficiency. This is because natural gas-air mixtures are too lean for flame to propagate under low load conditions. Intake charge heating and uncooled EGR are very useful to improve emissions and thermal efficiency at low load. Such favorable effects are supported by NO kinetic simulations. 2 refs., 13 figs.

Kinetic and geometric aspects of solid oxide fuel cell electrodes

DEFF Research Database (Denmark)

Mogensen, Mogens Bjerg; Skaarup, Steen

1996-01-01

The paper gives an overview of the main factors controlling the performance of the solid oxide fuel cell (SOFC) electrodes, emphasizing the most widely chosen anodes and cathodes, Ni-YSZ and LSM-YSZ. They are often applied as composites (mixtures) of the electron conducting electrode material...

Fuel Effective Photonic Propulsion

Science.gov (United States)

Rajalakshmi, N.; Srivarshini, S.

2017-09-01

With the entry of miniaturization in electronics and ultra-small light-weight materials, energy efficient propulsion techniques for space travel can soon be possible. We need to go for such high speeds so that the generation’s time long interstellar missions can be done in incredibly short time. Also renewable energy like sunlight, nuclear energy can be used for propulsion instead of fuel. These propulsion techniques are being worked on currently. The recently proposed photon propulsion concepts are reviewed, that utilize momentum of photons generated by sunlight or onboard photon generators, such as blackbody radiation or lasers, powered by nuclear or solar power. With the understanding of nuclear photonic propulsion, in this paper, a rough estimate of nuclear fuel required to achieve the escape velocity of Earth is done. An overview of the IKAROS space mission for interplanetary travel by JAXA, that was successful in demonstrating that photonic propulsion works and also generated additional solar power on board, is provided; which can be used as a case study. An extension of this idea for interstellar travel, termed as ‘Star Shot’, aims to send a nanocraft to an exoplanet in the nearest star system, which could be potentially habitable. A brief overview of the idea is presented.

Impact of physical properties of mixture of diesel and biodiesel fuels on hydrodynamic characteristics of fuel injection system

Directory of Open Access Journals (Sweden)

Filipović Ivan M.

2014-01-01

Full Text Available One of the alternative fuels, originating from renewable sources, is biodiesel fuel, which is introduced in diesel engines without major construction modifications on the engine. Biodiesel fuel, by its physical and chemical properties, is different from diesel fuel. Therefore, it is expected that by the application of a biodiesel fuel, the characteristic parameters of the injection system will change. These parameters have a direct impact on the process of fuel dispersion into the engine cylinder, and mixing with the air, which results in an impact on the quality of the combustion process. Method of preparation of the air-fuel mixture and the quality of the combustion process directly affect the efficiency of the engine and the level of pollutant emissions in the exhaust gas, which today is the most important criterion for assessing the quality of the engine. The paper presents a detailed analysis of the influence of physical properties of a mixture of diesel and biodiesel fuels on the output characteristics of the fuel injection system. The following parameters are shown: injection pressure, injection rate, the beginning and duration of injection, transformation of potential into kinetic energy of fuel and increase of energy losses in fuel injection system of various mixtures of diesel and biodiesel fuels. For the analysis of the results a self-developed computer program was used to simulate the injection process in the system. Computational results are verified using the experiment, for a few mixtures of diesel and biodiesel fuels. This paper presents the verification results for diesel fuel and biodiesel fuel in particular.

Small Stirling dynamic isotope power system for robotic space missions

International Nuclear Information System (INIS)

Bents, D.J.

1992-08-01

The design of a multihundred-watt Dynamic Isotope Power System (DIPS), based on the US Department of Energy (DOE) General Purpose Heat Source (GPHS) and small (multihundred-watt) free-piston Stirling engine (FPSE), is being pursued as a potential lower cost alternative to radioisotope thermoelectric generators (RTG's). The design is targeted at the power needs of future unmanned deep space and planetary surface exploration missions ranging from scientific probes to Space Exploration Initiative precursor missions. Power level for these missions is less than a kilowatt. The incentive for any dynamic system is that it can save fuel and reduce costs and radiological hazard. Unlike DIPS based on turbomachinery conversion (e.g. Brayton), this small Stirling DIPS can be advantageously scaled to multihundred-watt unit size while preserving size and mass competitiveness with RTG's. Stirling conversion extends the competitive range for dynamic systems down to a few hundred watts--a power level not previously considered for dynamic systems. The challenge for Stirling conversion will be to demonstrate reliability and life similar to RTG experience. Since the competitive potential of FPSE as an isotope converter was first identified, work has focused on feasibility of directly integrating GPHS with the Stirling heater head. Thermal modeling of various radiatively coupled heat source/heater head geometries has been performed using data furnished by the developers of FPSE and GPHS. The analysis indicates that, for the 1050 K heater head configurations considered, GPHS fuel clad temperatures remain within acceptable operating limits. Based on these results, preliminary characterizations of multihundred-watt units have been established

Robotic cleaning of a spent fuel pool

International Nuclear Information System (INIS)

Roman, H.T.; Marian, F.A.; Silverman, E.B.; Barkley, V.P.

1987-01-01

Spent fuel pools at nuclear power plants are not cleaned routinely, other than by purifying the water that they contain. Yet, debris can collect on the bottom of a pool and should be removed prior to fuel transfer. At Public Service Electric and Gas Company's Hope Creek Nuclear Power Plant, a submersible mobile robot - ARD Corporation's SCAVENGER - was used to clean the bottom of the spent fuel pool prior to initial fuel loading. The robotic device was operated remotely (as opposed to autonomously) with a simple forward/reverse control, and it cleaned 70-80% of the pool bottom. This paper reports that a simple cost-benefit analysis shows that the robotic device would be less expensive, on a per mission basis, than other cleaning alternatives, especially if it were used for other similar cleaning operations throughout the plant

Mission Benefits Analysis of Logistics Reduction Technologies

Science.gov (United States)

Ewert, Michael K.; Broyan, James Lee, Jr.

2013-01-01

Future space exploration missions will need to use less logistical supplies if humans are to live for longer periods away from our home planet. Anything that can be done to reduce initial mass and volume of supplies or reuse or recycle items that have been launched will be very valuable. Reuse and recycling also reduce the trash burden and associated nuisances, such as smell, but require good systems engineering and operations integration to reap the greatest benefits. A systems analysis was conducted to quantify the mass and volume savings of four different technologies currently under development by NASA s Advanced Exploration Systems (AES) Logistics Reduction and Repurposing project. Advanced clothing systems lead to savings by direct mass reduction and increased wear duration. Reuse of logistical items, such as packaging, for a second purpose allows fewer items to be launched. A device known as a heat melt compactor drastically reduces the volume of trash, recovers water and produces a stable tile that can be used instead of launching additional radiation protection. The fourth technology, called trash-to-gas, can benefit a mission by supplying fuel such as methane to the propulsion system. This systems engineering work will help improve logistics planning and overall mission architectures by determining the most effective use, and reuse, of all resources.

Neutronic and Logistic Proposal for Transmutation of Plutonium from Spent Nuclear Fuel as Mixed-Oxide Fuel in Existing Light Water Reactors

International Nuclear Information System (INIS)

Trellue, Holly R.

2004-01-01

The use of light water reactors (LWRs) for the destruction of plutonium and other actinides [especially those in spent nuclear fuel (SNF)] is being examined worldwide. One possibility for transmutation of this material is the use of mixed-oxide (MOX) fuel, which is a combination of uranium and plutonium oxides. MOX fuel is used in nuclear reactors worldwide, so a large experience base for its use already exists. However, to limit implementation of SNF transmutation to only a fraction of the LWRs in the United States with a reasonable number of license extensions, full cores of MOX fuel probably are required. This paper addresses the logistics associated with using LWRs for this mission and the design issues required for full cores of MOX fuel. Given limited design modifications, this paper shows that neutronic safety conditions can be met for full cores of MOX fuel with up to 8.3 wt% of plutonium

NASA fuel cell applications for space: Endurance test results on alkaline fuel cell electrolyzer components

International Nuclear Information System (INIS)

Sheibley, D.W.

1984-01-01

Fuel cells continue to play a major role in manned spacecraft power generation. The Gemini and Apollo programs used fuel cell power plants as the primary source of mission electrical power, with batteries as the backup. The current NASA use for fuel cells is in the Orbiter program. Here, low temperature alkaline fuel cells provide all of the on-board power with no backup power source. Three power plants per shipset are utilized; the original power plant contained 32-cell substacks connected in parallel. For extended life and better power performance, each power plant now contains three 32-cell substacks connected in parallel. One of the possible future applications for fuel cells will be for the proposed manned Space Station in low earth orbit (LEO)(1, 2, 3). By integrating a water electrolysis capability with a fuel cell (a regenerative fuel cell system), a multikilowatt energy storage capability ranging from 35 kW to 250 kW can be achieved. Previous development work on fuel cell and electrolysis systems would tend to minimize the development cost of this energy storage system. Trade studies supporting initial Space Station concept development clearly show regenerative fuel cell (RFC) storage to be superior to nickel-cadmium and nickel-hydrogen batteries with regard to subsystem weight, flexibility in design, and integration with other spacecraft systems when compared for an initial station power level ranging from 60 kW to 75 kW. The possibility of scavenging residual O 2 and H 2 from the Shuttle external tank for use in fuel cells for producing power also exists

Kinetic data bank for Ramona of the Siemens 9x9-IX

International Nuclear Information System (INIS)

Alonso V, G.

1993-12-01

With the purpose of making the transitory analyses of the Laguna Verde Nuclear Power station when Siemens fuel of the type 9x9-IX is used, proposed for the cycle 2 of the Unit 2, the kinetic data bank in hot condition for the Ramona code has been generated. (Author)

The next generation fuel cells: anion exchange membrane fuel cells (AEMFC)

International Nuclear Information System (INIS)

Tauqir, A.; Zahoor, S.

2013-01-01

Many environmentally friendly alternatives (solar, wind, hydroelectric, and geothermal power) can only be used in particular environments. In contrast, fuel cells can have near-zero emissions, are quiet and efficient, and can work in any environment where the temperature is lower than the cell's operating temperature. Among various types of fuel cells, the AEMFC is the most recent one and has advantages such as excellent performance compared to other candidate fuel cells due to its active O/sub 2/ electrode kinetics and flexibility to use a wide range of electro-catalysts such as silver and nickels contrary to expensive one (Platinum) required for proton exchange membrane fuel cell (PEMFC). Anion exchange membrane (AEM) is a crucial part in AEMFC, determining durability and electrochemical performances of membrane electrode assembly (MEA). The role of an AEM is to conduct hydroxyl ions from cathode to anode. If this conduction is not sufficiently high and selective, the corresponding fuel cell will not find any practical application. One of the major problems associated with AEMFC is much lower conductivities of anion compare to proton conductivity in PEMFCs, even upon similar working condition. Thus AEMs is only practical, if it is chemically and mechanically stable against severe basic operation conditions and highly hydroxyl ions conductive. The conventional AEMs based on animated aliphatic and aromatic hydrocarbon or even fluorinated polymers tend to be attacked by hydroxyl ions, causing the degradation during operation is strongly basic conditions. (author)

Benchmark physics tests in the metallic-fueled assembly ZPPR-15

International Nuclear Information System (INIS)

McFarlane, H.F.; Brumbach, S.B.; Carpenter, S.G.; Collins, P.J.

1989-01-01

Results of the first benchmark physics tests of a metallic-fueled, demonstration-size liquid-metal reactor (LMR) are reported. A simple, two-zone, cylindrical conventional assembly was built with three distinctly different compositions to represent the stages of the Integral Fast Reactor fuel cycle. Experiments included criticality, control, power distribution, reaction rate ratios, reactivity coefficients, shielding, kinetics, and spectrum. Analysis was done with three-dimensional nodal diffusion calculations and ENDF/B-V.2 cross sections. Predictions of the ZPPR-15 reactor physics parameters agreed sufficiently well with the measured values to justify confidence in design analyses for metallic-fueled LMRs

Design Evolutuion of Hot Isotatic Press Cans for NTP Cermet Fuel Fabrication

Science.gov (United States)

Mireles, O. R.; Broadway, J.; Hickman, R.

2014-01-01

Nuclear Thermal Propulsion (NTP) is under consideration for potential use in deep space exploration missions due to desirable performance properties such as a high specific impulse (> 850 seconds). Tungsten (W)-60vol%UO2 cermet fuel elements are under development, with efforts emphasizing fabrication, performance testing and process optimization to meet NTP service life requirements [1]. Fuel elements incorporate design features that provide redundant protection from crack initiation, crack propagation potentially resulting in hot hydrogen (H2) reduction of UO2 kernels. Fuel erosion and fission product retention barriers include W coated UO2 fuel kernels, W clad internal flow channels and fuel element external W clad resulting in a fully encapsulated fuel element design as shown.

Enhanced Generic Phase-field Model of Irradiation Materials: Fission Gas Bubble Growth Kinetics in Polycrystalline UO2

Energy Technology Data Exchange (ETDEWEB)

Li, Yulan; Hu, Shenyang Y.; Montgomery, Robert O.; Gao, Fei; Sun, Xin

2012-05-30

Experiments show that inter-granular and intra-granular gas bubbles have different growth kinetics which results in heterogeneous gas bubble microstructures in irradiated nuclear fuels. A science-based model predicting the heterogeneous microstructure evolution kinetics is desired, which enables one to study the effect of thermodynamic and kinetic properties of the system on gas bubble microstructure evolution kinetics and morphology, improve the understanding of the formation mechanisms of heterogeneous gas bubble microstructure, and provide the microstructure to macroscale approaches to study their impact on thermo-mechanical properties such as thermo-conductivity, gas release, volume swelling, and cracking. In our previous report 'Mesoscale Benchmark Demonstration, Problem 1: Mesoscale Simulations of Intra-granular Fission Gas Bubbles in UO2 under Post-irradiation Thermal Annealing', we developed a phase-field model to simulate the intra-granular gas bubble evolution in a single crystal during post-irradiation thermal annealing. In this work, we enhanced the model by incorporating thermodynamic and kinetic properties at grain boundaries, which can be obtained from atomistic simulations, to simulate fission gas bubble growth kinetics in polycrystalline UO2 fuels. The model takes into account of gas atom and vacancy diffusion, vacancy trapping and emission at defects, gas atom absorption and resolution at gas bubbles, internal pressure in gas bubbles, elastic interaction between defects and gas bubbles, and the difference of thermodynamic and kinetic properties in matrix and grain boundaries. We applied the model to simulate gas atom segregation at grain boundaries and the effect of interfacial energy and gas mobility on gas bubble morphology and growth kinetics in a bi-crystal UO2 during post-irradiation thermal annealing. The preliminary results demonstrate that the model can produce the equilibrium thermodynamic properties and the morphology of gas

Near-term hybrid vehicle program, phase 1. Appendix A: Mission analysis and performance specification studies report

Science.gov (United States)

1979-01-01

Results of a study leading to the preliminary design of a five passenger hybrid vehicle utilizing two energy sources (electricity and gasoline/diesel fuel) to minimize petroleum usage on a fleet basis are presented. The study methodology is described. Vehicle characterizations, the mission description, characterization, and impact on potential sales, and the rationale for the selection of the reference internal combustion engine vehicle are presented. Conclusions and recommendations of the mission analysis and performance specification report are included.

Electrode Kinetics in High Temperature Fuel Cells

DEFF Research Database (Denmark)

Bay, Lasse

1998-01-01

^3s and 10^5s for a cathodic current. For the deactivation is the time constant about 10^4s. The origin for the hysteresis is not clear, but expansion of the three phase boundary (TPB) or change of the catalytic properties due to surface segregation are suggested.The hysteresis phenomenon is also......-electrolyte interface show dynamics of the YSZ surface and formation of a bank of YSZ along the TPB. These changes are induced by passage of current. The origin of the dynamics behaviour may be a localised temperature increase or it might be driven by segregation. The dynamics of the YSZ surface seems...... to be irreversible to annealing at 1000^oC.A separated part of the project was performed at National Institute of Materials and Chemical Research, Tsukuba, Japan. Here YSZ, Pr doped YSZ and Y doped SrCeO_3 were tested as electrolytes in a one chamber fuel cell. Electrochemical measurements and SIMS analysis...

Gardening for Therapeutic People-Plant Interactions during Long-Duration Space Missions

Directory of Open Access Journals (Sweden)

Odeh Raymond

2017-02-01

Full Text Available Plants provide people with vital resources necessary to sustain life. Nutrition, vitamins, calories, oxygen, fuel, and medicinal phytochemicals are just a few of the life-supporting plant products, but does our relationship with plants transcend these physical and biochemical products? This review synthesizes some of the extant literature on people-plant interactions, and relates key findings relevant to space exploration and the psychosocial and neurocognitive benefits of plants and nature in daily life. Here, a case is made in support of utilizing plant-mediated therapeutic benefits to mitigate potential psychosocial and neurocognitive decrements associated with long-duration space missions, especially for missions that seek to explore increasingly distant places where ground-based support is limited.

Update of the Used Fuel Dispositon Campaign Implementation Plan

Energy Technology Data Exchange (ETDEWEB)

McMahon, Kevin A. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Bragg-Sitton, Shannon [Idaho National Lab. (INL), Idaho Falls, ID (United States); Mackinnon, Robert James [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Saltzstein, Sylvia J. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Sorenson, Ken B. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Swift, Peter N. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Birkholzer, Jens T. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

2014-10-01

This Update to the Used Fuel Disposition Campaign Implementation Plan provides summary level detail describing how the Used Fuel Disposition Campaign (UFDC) supports achievement of the overarching mission and objectives of the Department of Energy Office of Nuclear Energy Fuel Cycle Technologies Program, building on work completed in this area since 2009. This implementation plan begins with the assumption of target dates that are set out in the January 2013 DOE Strategy for the Management and Disposal of Used Nuclear Fuel and High-Level Radioactive Waste (http://energy.gov/downloads/strategy-management-and-disposal-used-nuclearfuel- and-high-level-radioactive-waste). These target dates and goals are summarized in section III. This implementation plan will be maintained as a living document and will be updated as needed in response to available funding and progress in the Used Fuel Disposition Campaign and the Fuel Cycle Technologies Program.

Effect of grain morphology on gas bubble swelling in UMo fuels – A 3D microstructure dependent Booth model

Energy Technology Data Exchange (ETDEWEB)

Hu, Shenyang, E-mail: shenyang.hu@pnnl.gov; Burkes, Douglas; Lavender, Curt A.; Joshi, Vineet

2016-11-15

A three dimensional microstructure dependent swelling model is developed for studying the fission gas swelling kinetics in irradiated nuclear fuels. The model is extended from the Booth model [1] in order to investigate the effect of heterogeneous microstructures on gas bubble swelling kinetics. As an application of the model, the effect of grain morphology, fission gas diffusivity, and spatially dependent fission rate on swelling kinetics are simulated in UMo fuels. It is found that the decrease of grain size, the increase of grain aspect ratio for the grain having the same volume, and the increase of fission gas diffusivity (fission rate) cause the increase of swelling kinetics. Other heterogeneities such as second phases and spatially dependent thermodynamic properties including diffusivity of fission gas, sink and source strength of defects could be naturally integrated into the model to enhance the model capability.

Kinetic modeling of methyl butanoate in shock tube.

Science.gov (United States)

Huynh, Lam K; Lin, Kuang C; Violi, Angela

2008-12-25

An increased necessity for energy independence and heightened concern about the effects of rising carbon dioxide levels have intensified the search for renewable fuels that could reduce our current consumption of petrol and diesel. One such fuel is biodiesel, which consists of the methyl esters of fatty acids. Methyl butanoate (MB) contains the essential chemical structure of the long-chain fatty acids and a shorter, but similar, alkyl chain. This paper reports on a detailed kinetic mechanism for MB that is assembled using theoretical approaches. Thirteen pathways that include fuel decomposition, isomerization, and propagation steps were computed using ab initio calculations [J. Org. Chem. 2008, 73, 94]. Rate constants from first principles for important reactions in CO(2) formation, namely CH(3)OCO=CH(3) + CO(2) (R1) and CH(3)OCO=CH(3)O + CO (R2) reactions, are computed at high levels of theory and implemented in the mechanism. Using the G3B3 potential energy surface together with the B3LYP/6-31G(d) gradient, Hessian and geometries, the rate constants for reactions R1 and R2 are calculated using the Rice-Ramsperger-Kassel-Marcus theory with corrections from treatments for tunneling, hindered rotation, and variational effects. The calculated rate constants of reaction R1 differ from the data present in the literature by at most 20%, while those of reaction R2 are about a factor of 4 lower than the available values. The new kinetic model derived from ab initio simulations is combined with the kinetic mechanism presented by Fisher et al. [Proc. Combust. Inst. 2000, 28, 1579] together with the addition of the newly found six-centered unimolecular elimination reaction that yields ethylene and methyl acetate, MB = C(2)H(4) + CH(3)COOCH(3). This latter pathway requires the inclusion of the CH(3)COOCH(3) decomposition model suggested by Westbrook et al. [Proc. Combust. Inst. 2008, accepted]. The newly composed kinetic mechanism for MB is used to study the CO(2) formation

Kinetic mix mechanisms in shock-driven inertial confinement fusion implosions

Energy Technology Data Exchange (ETDEWEB)

Rinderknecht, H. G.; Sio, H.; Li, C. K.; Zylstra, A. B.; Rosenberg, M. J.; Frenje, J. A.; Gatu Johnson, M.; Séguin, F. H.; Petrasso, R. D. [Plasma Science and Fusion Center, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States); Hoffman, N.; Kagan, G.; Molvig, K. [Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Betti, R.; Yu Glebov, V.; Meyerhofer, D. D.; Sangster, T. C.; Seka, W.; Stoeckl, C. [Laboratory for Laser Energetics, University of Rochester, Rochester, New York 14623 (United States); Bellei, C.; Amendt, P. [Lawrence Livermore National Laboratory, Livermore, California 94550 (United States); and others

2014-05-15

Shock-driven implosions of thin-shell capsules, or “exploding pushers,” generate low-density, high-temperature plasmas in which hydrodynamic instability growth is negligible and kinetic effects can play an important role. Data from implosions of thin deuterated-plastic shells with hydroequivalent D{sup 3}He gas fills ranging from pure deuterium to pure {sup 3}He [H. G. Rinderknecht et al., Phys. Rev. Lett. 112, 135001 (2014)] were obtained to evaluate non-hydrodynamic fuel-shell mix mechanisms. Simulations of the experiments including reduced ion kinetic models support ion diffusion as an explanation for these data. Several additional kinetic mechanisms are investigated and compared to the data to determine which are important in the experiments. Shock acceleration of shell deuterons is estimated to introduce mix less than or comparable to the amount required to explain the data. Beam-target mechanisms are found to produce yields at most an order of magnitude less than the observations.

Core-Shell Al-Polytetrafluoroethylene (PTFE) Configurations to Enhance Reaction Kinetics and Energy Performance for Nanoenergetic Materials.

Science.gov (United States)

Wang, Jun; Qiao, Zhiqiang; Yang, Yuntao; Shen, Jinpeng; Long, Zhang; Li, Zhaoqian; Cui, Xudong; Yang, Guangcheng

2016-01-04

The energy performance of solid energetic materials (Al, Mg, etc.) is typically restricted by a natural passivation layer and the diffusion-limited kinetics between the oxidizer and the metal. In this work, we use polytetrafluoroethylene (PTFE) as the fluorine carrier and the shielding layer to construct a new type of nano-Al based fuels. The PTFE shell not only prevents nano-Al layers from oxidation, but also assists in enhancing the reaction kinetics, greatly improving the stability and reactivity of fuels. An in situ chemical vapor deposition combined with the electrical explosion of wires (EEW) method is used to fabricate core-shell nanostructures. Studies show that by controlling the stoichiometric ratio of the precursors, the morphology of the PTFE shell and the energy performance can be easily tuned. The resultant composites exhibit superior energy output characters than that of their physically mixed Al/PTFE counterparts. This synthetic strategy might provide a general approach to prepare other high-energy fuels (Mg, Si). © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Fission-induced recrystallization effect on intergranular bubble-driven swelling in U-Mo fuel

Energy Technology Data Exchange (ETDEWEB)

Liang, Linyun; Mei, Zhi-Gang; Yacout, Abdellatif M.

2017-10-01

We have developed a mesoscale phase-field model for studying the effect of recrystallization on the gas-bubble-driven swelling in irradiated U-Mo alloy fuel. The model can simulate the microstructural evolution of the intergranular gas bubbles on the grain boundaries as well as the recrystallization process. Our simulation results show that the intergranular gas-bubble-induced fuel swelling exhibits two stages: slow swelling kinetics before recrystallization and rapid swelling kinetics with recrystallization. We observe that the recrystallization can significantly expedite the formation and growth of gas bubbles at high fission densities. The reason is that the recrystallization process increases the nucleation probability of gas bubbles and reduces the diffusion time of fission gases from grain interior to grain boundaries by increasing the grain boundary area and decreasing the diffusion distance. The simulated gas bubble shape, size distribution, and density on the grain boundaries are consistent with experimental measurements. We investigate the effect of the recrystallization on the gas-bubble-driven fuel swelling in UMo through varying the initial grain size and grain aspect ratio. We conclude that the initial microstructure of fuel, such as grain size and grain aspect ratio, can be used to effectively control the recrystallization and therefore reduce the swelling in U-Mo fuel.

Development of advanced spent fuel management process

International Nuclear Information System (INIS)

Ro, Seung Gy; Shin, Y. J.; Do, J. B.; You, G. S.; Seo, J. S.; Lee, H. G.

1998-03-01

This study is to develop an advanced spent fuel management process for countries which have not yet decided a back-end nuclear fuel cycle policy. The aims of this process development based on the pyroreduction technology of PWR spent fuels with molten lithium, are to reduce the storage volume by a quarter and to reduce the storage cooling load in half by the preferential removal of highly radioactive decay-heat elements such as Cs-137 and Sr-90 only. From the experimental results which confirm the feasibility of metallization technology, it is concluded that there are no problems in aspects of reaction kinetics and equilibrium. However, the operating performance test of each equipment on an engineering scale still remain and will be conducted in 1999. (author). 21 refs., 45 tabs., 119 figs

NASA's Planned Fuel Cell Development Activities for 2009 and Beyond in Support of the Exploration Vision

Science.gov (United States)

Hoberecht, Mark A.

2010-01-01

NASA s Energy Storage Project is one of many technology development efforts being implemented as part of the Exploration Technology Development Program (ETDP), under the auspices of the Exploration Systems Mission Directorate (ESMD). The Energy Storage Project is a focused technology development effort to advance lithium-ion battery and proton-exchange-membrane fuel cell (PEMFC) technologies to meet the specific power and energy storage needs of NASA Exploration missions. The fuel cell portion of the project has as its focus the development of both primary fuel cell power systems and regenerative fuel cell (RFC) energy storage systems, and is led by the NASA Glenn Research Center (GRC) in partnership with the Johnson Space Center (JSC), the Jet Propulsion Laboratory (JPL), the Kennedy Space Center (KSC), academia, and industrial partners. The development goals are to improve stack electrical performance, reduce system mass and parasitic power requirements, and increase system life and reliability.

Thermal coupling of a high temperature PEM fuel cell with a complex hydride tank

DEFF Research Database (Denmark)

Pfeifer, P.; Wall, C.; Jensen, Jens Oluf

2009-01-01

the possibilities of a thermal coupling of a high temperature PEM fuel cell operating at 160-200 degrees C. The starting temperatures and temperature hold-times before starting fuel cell operation, the heat transfer characteristics of the hydride storage tanks, system temperature, fuel cell electrical power......Sodium alanate doped with cerium catalyst has been proven to have fast kinetics for hydrogen ab- and de-sorption as well as a high gravimetric storage density around 5 wt%. The kinetics of hydrogen sorption can be improved by preparing the alanate as nanocrystalline material. However, the second...... decomposition step, i.e. the decomposition of the hexahydride to sodium hydride and aluminium which refers to 1.8 wt% hydrogen is supposed to happen above 110 degrees C. The discharge of the material is thus limited by the level of heat supplied to the hydride storage tank. Therefore, we evaluated...

Alkaline fuel cell technology in the lead

International Nuclear Information System (INIS)

Nor, J.K.

2004-01-01

The Alkaline Fuel Cell (AFC) was the first fuel cell successfully put into practice, a century after William Grove patented his 'hydrogen battery' in 1839. The space program provided the necessary momentum, and alkaline fuel cells became the power source for both the U.S. and Russian manned space flight. Astris Energi's mission has been to bring this technology down to earth as inexpensive, rugged fuel cells for everyday applications. The early cells, LABCELL 50 and LABCELL 200 were aimed at deployment in research labs, colleges and universities. They served well in technology demonstration projects such as the 1998 Mini Jeep, 2001 Golf Car and a series of portable and stationary fuel cell generators. The present third generation POWERSTACK MC250 poised for commercialization is being offered to AFC system integrators as a building block of fuel cell systems in numerous portable, stationary and transportation applications. It is also used in Astris' own E7 and E8 alkaline fuel cell generators. Astris alkaline technology leads the way toward economical, plentiful fuel cells. The paper highlights the progress achieved at Astris, improvements of performance, durability and simplicity of use, as well as the current and future thrust in technology development and commercialization. (author)

Canada's plan for the long-term management of used nuclear fuel

Energy Technology Data Exchange (ETDEWEB)

Shaver, K. [Nuclear Waste Management Organization, Toronto, ON (Canada)

2015-07-01

Our mission is to develop and implement collaboratively with Canadians, a management approach for the long-term care of Canada's used nuclear fuel that is socially acceptable, technically sound, environmentally responsible, and economically feasible. The technical method is for Isolation of used nuclear fuel in deep geological repository with continuous monitoring and potential for retrievability.

Measurement of gap and grain-boundary inventories of 129I in used CANDU fuels

International Nuclear Information System (INIS)

Stroes-Gascoyne, S.; Moir, D.L.; Kolar, M.; Porth, R.J.; McConnell, J.L.; Kerr, A.H.

1995-01-01

Combined gap and grain-boundary inventories of 129 I in 14 used CANDU fuel elements were measured by crushing and simultaneously leaching fuel segments for 4 h in a solution containing KI carrier. From analogy with previous work a near one-to-one correlation was anticipated between the amount of stable Xe and the amount of 128 I in the combined gap and grain-boundary regions of the fuel. However, the results showed that such a correlation was only apparent for low linear power rating (LLPR) fuels with an average linear power rating of 44 kW/m), the 129 I values were considerably smaller than expected. The combined gap and grain-boundary inventories of 129 I in the 14 fuels tested varied from 1.8 to 11.0%, with an average value of 3.6 ± 2.4% which suggests that the average value of 8.1 ± 1% used in safety assessment calculations overestimates the instant release fraction for 129 I. Segments of used CANDU fuels were leached for 92 d (samples taken at 5, 28 and 92 d) to determine the kinetics of 129 I release. Results could be fitted tentatively to half-order reaction kinetics, implying that 129 I release is a diffusion-controlled process for LLPR fuels, and also for HLPR fuels, once the gap inventory has been leached. However, more data are needed over longer leaching periods to gain more understanding of the processes that control grain-boundary release of 129 I from used CANDU fuel

Release of indigenous gases from LWR fuel and the reaction kinetics with Zircaloy cladding

International Nuclear Information System (INIS)

Beyer, C.E.; Hann, C.R.

1977-04-01

The objective of this study was to evaluate the open literature data to estimate: the rate of gaseous impurity release from oxide fuel, the amount and composition of the gaseous impurities, and their subsequent rate of reaction with the fuel or Zircaloy

Waste management and the nuclear fuel cycle

International Nuclear Information System (INIS)

Molinari, J.

1982-01-01

The present lecture deals with energy needs and nuclear power, the importance of waste and its relative place in the fuel cycle, the games of controversies over nuclear waste in the strategies of energy and finally with missions and functions of the IAEA for privileging the rational approach and facilitating the transfer of technology. (RW)

Modeling the reaction kinetics of a hydrogen generator onboard a fuel cell -- Electric hybrid motorcycle

Science.gov (United States)

Ganesh, Karthik

Owing to the perceived decline of the fossil fuel reserves in the world and environmental issues like pollution, conventional fuels may be replaced by cleaner alternative fuels. The potential of hydrogen as a fuel in vehicular applications is being explored. Hydrogen as an energy carrier potentially finds applications in internal combustion engines and fuel cells because it is considered a clean fuel and has high specific energy. However, at 6 to 8 per kilogram, not only is hydrogen produced from conventional methods like steam reforming expensive, but also there are storage and handling issues, safety concerns and lack of hydrogen refilling stations across the country. The purpose of this research is to suggest a cheap and viable system that generates hydrogen on demand through a chemical reaction between an aluminum-water slurry and an aqueous sodium hydroxide solution to power a 2 kW fuel cell on a fuel cell hybrid motorcycle. This reaction is essentially an aluminum-water reaction where sodium hydroxide acts as a reaction promoter or catalyst. The Horizon 2000 fuel cell used for this purpose has a maximum hydrogen intake rate of 28 lpm. The study focuses on studying the exothermic reaction between the reactants and proposes a rate law that best describes the rate of generation of hydrogen in connection to the surface area of aluminum available for the certain reaction and the concentration of the sodium hydroxide solution. Further, the proposed rate law is used in the simulation model of the chemical reactor onboard the hybrid motorcycle to determine the hydrogen flow rate to the fuel cell with time. Based on the simulated rate of production of hydrogen from the chemical system, its feasibility of use on different drive cycles is analyzed. The rate of production of hydrogen with a higher concentration of sodium hydroxide and smaller aluminum powder size was found to enable the installation of the chemical reactor on urban cycles with frequent stops and starts

The comet rendezvous asteroid flyby mission

International Nuclear Information System (INIS)

Morrison, D.; Neugebauer, M.; Weissman, P.R.

1989-01-01

The Comet Rendezvous Asteroid Flyby (CRAF) mission is designed to answer the many questions raised by the Halley missions by exploring a cometary nucleus in detail, following it around its orbit and studying its changing activity as it moves closer to and then away from the Sun. In addition, on its way to rendezvous with the comet, CRAF will fly by a large, primitive class main belt asteroid and will return valuable data for comparison with the comet results. The selected asteroid is 449 Hamburga with a diameter of 88 km and a surface composition of carbonaceous chondrite meteorites. The expected flyby date is January, 1998. The CRAF spacecraft will continue to make measurements in orbit around the cometary nucleus as they both move closer to the Sun, until the dust and gas hazard becomes unsafe. At that point the spacecraft will move in and out between 50 and 2,500 kilometers to study the inner coma and the cometary ionosphere, and to collect dust and gas samples for onboard analysis. Following perihelion, the spacecraft will make a 50,000 km excursion down the comet's tail, further investigating the solar wind interaction with the cometary atmosphere. The spacecraft will return to the vicinity of the nucleus about four months after perihelion to observe the changes that have taken place. If the spacecraft remains healthy and adequate fuel is still onboard, an extended mission to follow the comet nucleus out to aphelion is anticipated

Proton Exchange Membrane Fuel Cell Engineering Model Powerplant. Test Report: Benchmark Tests in Three Spatial Orientations

Science.gov (United States)

Loyselle, Patricia; Prokopius, Kevin

2011-01-01

Proton exchange membrane (PEM) fuel cell technology is the leading candidate to replace the aging alkaline fuel cell technology, currently used on the Shuttle, for future space missions. This test effort marks the final phase of a 5-yr development program that began under the Second Generation Reusable Launch Vehicle (RLV) Program, transitioned into the Next Generation Launch Technologies (NGLT) Program, and continued under Constellation Systems in the Exploration Technology Development Program. Initially, the engineering model (EM) powerplant was evaluated with respect to its performance as compared to acceptance tests carried out at the manufacturer. This was to determine the sensitivity of the powerplant performance to changes in test environment. In addition, a series of tests were performed with the powerplant in the original standard orientation. This report details the continuing EM benchmark test results in three spatial orientations as well as extended duration testing in the mission profile test. The results from these tests verify the applicability of PEM fuel cells for future NASA missions. The specifics of these different tests are described in the following sections.

FCRD Advanced Reactor (Transmutation) Fuels Handbook

Energy Technology Data Exchange (ETDEWEB)

Janney, Dawn Elizabeth [Idaho National Lab. (INL), Idaho Falls, ID (United States); Papesch, Cynthia Ann [Idaho National Lab. (INL), Idaho Falls, ID (United States)

2016-09-01

Transmutation of minor actinides such as Np, Am, and Cm in spent nuclear fuel is of international interest because of its potential for reducing the long-term health and safety hazards caused by the radioactivity of the spent fuel. One important approach to transmutation (currently being pursued by the DOE Fuel Cycle Research & Development Advanced Fuels Campaign) involves incorporating the minor actinides into U-Pu-Zr alloys, which can be used as fuel in fast reactors. U-Pu-Zr alloys are well suited for electrolytic refining, which leads to incorporation rare-earth fission products such as La, Ce, Pr, and Nd. It is, therefore, important to understand not only the properties of U-Pu-Zr alloys but also those of U-Pu-Zr alloys with concentrations of minor actinides (Np, Am) and rare-earth elements (La, Ce, Pr, and Nd) similar to those in reprocessed fuel. In addition to requiring extensive safety precautions, alloys containing U, Pu, and minor actinides (Np and Am) are difficult to study for numerous reasons, including their complex phase transformations, characteristically sluggish phasetransformation kinetics, tendency to produce experimental results that vary depending on the histories of individual samples, rapid oxidation, and sensitivity to contaminants such as oxygen in concentrations below a hundred parts per million. Although less toxic, rare-earth elements such as La, Ce, Pr, and Nd are also difficult to study for similar reasons. Many of the experimental measurements were made before 1980, and the level of documentation for experimental methods and results varies widely. It is, therefore, not surprising that little is known with certainty about U-Pu-Zr alloys, particularly those that also contain minor actinides and rare-earth elements. General acceptance of results commonly indicates that there is only a single measurement for a particular property. This handbook summarizes currently available information about U, Pu, Zr, Np, Am, La, Ce, Pr, and Nd and

Electrochemical characteristics of vanadium redox reactions on porous carbon electrodes for microfluidic fuel cell applications

International Nuclear Information System (INIS)

Lee, Jin Wook; Hong, Jun Ki; Kjeang, Erik

2012-01-01

Microfluidic vanadium redox fuel cells are membraneless and catalyst-free fuel cells comprising a microfluidic channel network with two porous carbon electrodes. The anolyte and catholyte for fuel cell operation are V(II) and V(V) in sulfuric acid based aqueous solution. In the present work, the electrochemical characteristics of the vanadium redox reactions are investigated on commonly used porous carbon paper electrodes and compared to a standard solid graphite electrode as baseline. Half-cell electrochemical impedance spectroscopy is applied to measure the overall ohmic resistance and resistivity of the electrodes. Kinetic parameters for both V(II) and V(V) discharging reactions are extracted from Tafel plots and compared for the different electrodes. Cyclic voltammetry techniques reveal that the redox reactions are irreversible and that the magnitudes of peak current density vary significantly for each electrode. The obtained kinetic parameters for the carbon paper are implemented into a numerical simulation and the results show a good agreement with measured polarization curves from operation of a microfluidic vanadium redox fuel cell employing the same material as flow-through porous electrodes. Recommendations for microfluidic fuel cell design and operation are provided based on the measured trends.

Fuel processor integrated H{sub 2}S catalytic partial oxidation technology for sulfur removal in fuel cell power plants

Energy Technology Data Exchange (ETDEWEB)

Gardner, T.H.; Berry, D.A.; Lyons, K.D.; Beer, S.K.; Freed, A.D. [U.S. Department of Energy, Morgantown, WV (USA). National Energy Technology Laboratory

2002-12-01

H{sub 2}S catalytic partial oxidation technology with an activated carbon catalyst was found to be a promising method for the removal of hydrogen sulfide from fuel cell hydrocarbon feedstocks. Three different fuel cell feedstocks were considered for analysis: sour natural gas, sour effluent from a liquid middle distillate fuel processor and a Texaco O{sub 2}-blown coal-derived synthesis gas. The H{sub 2}S catalytic partial oxidation reaction, its integratability into fuel cell power plants with different hydrocarbon feedstocks and its salient features are discussed. Experimental results indicate that H{sub 2}S concentration can be removed down to the part-per-million level in these plants. Additionally, a power law rate expression was developed and reaction kinetics compared to prior literature. The activation energy for this reaction was determined to be 34.4 kJ/g mol with the reaction being first order in H{sub 2}S and 0.3 order in O{sub 2}. 18 refs., 14 figs., 3 tabs.

High temperature PEM fuel cells

Energy Technology Data Exchange (ETDEWEB)

Zhang, Jianlu; Xie, Zhong; Zhang, Jiujun; Tang, Yanghua; Song, Chaojie; Navessin, Titichai; Shi, Zhiqing; Song, Datong; Wang, Haijiang; Wilkinson, David P.; Liu, Zhong-Sheng; Holdcroft, Steven [Institute for Fuel Cell Innovation, National Research Council Canada, Vancouver, BC (Canada V6T 1W5)

2006-10-06

There are several compelling technological and commercial reasons for operating H{sub 2}/air PEM fuel cells at temperatures above 100{sup o}C. Rates of electrochemical kinetics are enhanced, water management and cooling is simplified, useful waste heat can be recovered, and lower quality reformed hydrogen may be used as the fuel. This review paper provides a concise review of high temperature PEM fuel cells (HT-PEMFCs) from the perspective of HT-specific materials, designs, and testing/diagnostics. The review describes the motivation for HT-PEMFC development, the technology gaps, and recent advances. HT-membrane development accounts for {approx}90% of the published research in the field of HT-PEMFCs. Despite this, the status of membrane development for high temperature/low humidity operation is less than satisfactory. A weakness in the development of HT-PEMFC technology is the deficiency in HT-specific fuel cell architectures, test station designs, and testing protocols, and an understanding of the underlying fundamental principles behind these areas. The development of HT-specific PEMFC designs is of key importance that may help mitigate issues of membrane dehydration and MEA degradation. (author)

Carbon components in the phosphoric acid fuel cell-an overview

International Nuclear Information System (INIS)

Appleby, J.

1983-01-01

The single breakthrough that has made the phosphoric acid fuel cell a practical reality has been the use of carbon or graphite components for the repeat parts of the cell stack. While the thermodynamic stability of carbon is such that rapid corrosion would be expected at the cathode at fuel cell operating temperature, its kinetic stability is remarkable despite the absence of passivating layers analogous to those on, for example, the Group VA elements niobium and tantalum. This happy accident, combined with the adequate electronic conductivity of the carbon materials used, has provided the opportunity to reduce fuel cell cost to attractive levels. The development of these carbon compounds is reviewed

Study of corrosion kinetics of fuel element tubes from calcium-thermal zirconium alloy Zr1Nb in water at 350 degree C and in vapour at 400 and 500 degree C

International Nuclear Information System (INIS)

Petel'guzov, I.A.

2002-01-01

In the report brought results of corrosion process studies in water medium of pipe samples for fuel element shells from Zr1Nb alloy (earlier KTZ-110),made from the calcium-thermal zirconium alloys developed in the Ukraine of technology and,for the comparison,samples of pipes from the staff alloy E110, applicable in fuel elements acting reactors of type WWER. Tests were conducted under the working temperature of fuel shells in the reactor (350 degree C) in during of 14000 hours and under increased temperatures (400 degree C) within a time acordinly 4000 hours. Samples from the alloy Zr1Nb had more high contents of oxygen (before 0,12%...0,16%), than staff alloy Eh110 (0,08%O). Studies have shown sufficiently high corrosion stability of experimental alloy Zr1Nb, close to stability of alloy E110.Discovered signs of corrosion 'breakway' or 'transition' on kinetic corrosion curves of Zr1Nb alloys and E110 alloy, characterisating zircaloy type of alloy. Considered mechanism of influence of oxygen on the corrosion process of zirconium alloys with the additive a niobium

Kinetic analysis of nitric oxide reduction using biogas as reburning fuel

African Journals Online (AJOL)

STORAGESEVER

2009-05-18

May 18, 2009 ... Emission of nitric oxide (NO) from coal combustion continues to be a significant ... mass has been focused as a renewable fuel without CO2 addition, and researches ..... Giles DE, Som S, Aggarwal SK (2006). NOx emission ...

Rendezvous missions with minimoons from L1

Science.gov (United States)

Chyba, M.; Haberkorn, T.; Patterson, G.

2014-07-01

We propose to present asteroid capture missions with the so-called minimoons. Minimoons are small asteroids that are temporarily captured objects on orbits in the Earth-Moon system. It has been suggested that, despite their small capture probability, at any time there are one or two meter diameter minimoons, and progressively greater numbers at smaller diameters. The minimoons orbits differ significantly from elliptical orbits which renders a rendezvous mission more challenging, however they offer many advantages for such missions that overcome this fact. First, they are already on geocentric orbits which results in short duration missions with low Delta-v, this translates in cost efficiency and low-risk targets. Second, beside their close proximity to Earth, an advantage is their small size since it provides us with the luxury to retrieve the entire asteroid and not only a sample of material. Accessing the interior structure of a near-Earth satellite in its morphological context is crucial to an in-depth analysis of the structure of the asteroid. Historically, 2006 RH120 is the only minimoon that has been detected but work is ongoing to determine which modifications to current observation facilities is necessary to provide detection algorithm capabilities. In the event that detection is successful, an efficient algorithm to produce a space mission to rendezvous with the detected minimoon is highly desirable to take advantage of this opportunity. This is the main focus of our work. For the design of the mission we propose the following. The spacecraft is first placed in hibernation on a Lissajoux orbit around the liberation point L1 of the Earth-Moon system. We focus on eight-shaped Lissajoux orbits to take advantage of the stability properties of their invariant manifolds for our transfers since the cost to minimize is the spacecraft fuel consumption. Once a minimoon has been detected we must choose a point on its orbit to rendezvous (in position and velocities

NASA CYGNSS Mission Overview

Science.gov (United States)

Ruf, C. S.; Balasubramaniam, R.; Gleason, S.; McKague, D. S.; O'Brien, A.

2017-12-01

The CYGNSS constellation of eight satellites was successfully launched on 15 December 2016 into a low inclination (tropical) Earth orbit. Each satellite carries a four-channel bi-static radar receiver that measures GPS signals scattered by the ocean, from which ocean surface roughness, near surface wind speed, and air-sea latent heat flux are estimated. The measurements are unique in several respects, most notably in their ability to penetrate through all levels of precipitation, made possible by the low frequency at which GPS operates, and in the frequent sampling of tropical cyclone intensification and of the diurnal cycle of winds, made possible by the large number of satellites. Engineering commissioning of the constellation was successfully completed in March 2017 and the mission is currently in the early phase of science operations. Level 2 science data products have been developed for near surface (10 m referenced) ocean wind speed, ocean surface roughness (mean square slope) and latent heat flux. Level 3 gridded versions of the L2 products have also been developed. A set of Level 4 products have also been developed specifically for direct tropical cyclone overpasses. These include the storm intensity (peak sustained winds) and size (radius of maximum winds), its extent (34, 50 and 64 knot wind radii), and its integrated kinetic energy. Assimilation of CYGNSS L2 wind speed data into the HWRF hurricane weather prediction model has also been developed. An overview and the current status of the mission will be presented, together with highlights of early on-orbit performance and scientific results.

Nuclear Thermal Rocket/Vehicle Design Options for Future NASA Missions to the Moon and Mars

Science.gov (United States)

Borowski, Stanley K.; Corban, Robert R.; Mcguire, Melissa L.; Beke, Erik G.

1995-01-01

The nuclear thermal rocket (NTR) provides a unique propulsion capability to planners/designers of future human exploration missions to the Moon and Mars. In addition to its high specific impulse (approximately 850-1000 s) and engine thrust-to-weight ratio (approximately 3-10), the NTR can also be configured as a 'dual mode' system capable of generating electrical power for spacecraft environmental systems, communications, and enhanced stage operations (e.g., refrigeration for long-term liquid hydrogen storage). At present the Nuclear Propulsion Office (NPO) is examining a variety of mission applications for the NTR ranging from an expendable, single-burn, trans-lunar injection (TLI) stage for NASA's First Lunar Outpost (FLO) mission to all propulsive, multiburn, NTR-powered spacecraft supporting a 'split cargo-piloted sprint' Mars mission architecture. Each application results in a particular set of requirements in areas such as the number of engines and their respective thrust levels, restart capability, fuel operating temperature and lifetime, cryofluid storage, and stage size. Two solid core NTR concepts are examined -- one based on NERVA (Nuclear Engine for Rocket Vehicle Application) derivative reactor (NDR) technology, and a second concept which utilizes a ternary carbide 'twisted ribbon' fuel form developed by the Commonwealth of Independent States (CIS). The NDR and CIS concepts have an established technology database involving significant nuclear testing at or near representative operating conditions. Integrated systems and mission studies indicate that clusters of two to four 15 to 25 klbf NDR or CIS engines are sufficient for most of the lunar and Mars mission scenarios currently under consideration. This paper provides descriptions and performance characteristics for the NDR and CIS concepts, summarizes NASA's First Lunar Outpost and Mars mission scenarios, and describes characteristics for representative cargo and piloted vehicles compatible with a

MITEE: A new nuclear engine concept for ultra fast, lightweight solar system exploration missions

Science.gov (United States)

Powell, James; Paniagua, John; Ludewig, Hans; Maise, George; Todosow, Michael

1998-01-01

A new ultra compact nuclear engine concept, MITEE (MIniature R_eactor E_nginE_), is described, and its performance evaluated for various solar system exploration missions. The MITEE concept is based on the Particle Bed Reactor (PBR), with modifications that enable a smaller, lighter nuclear engine. A range of MITEE Engine designs is described. Representative design parameters for the baseline MITEE reactor are: 75MW(th) power level, 1000 second Isp, 100 kilogram mass, 10 MW/Liter fuel element power density, 39 cm core diameter/height. Total engine mass, including turbo pump assembly, nozzles, controls, and contingency, is estimated to be 200 kilograms. Using the MITEE engine, ultra fast, lightweight solar system exploration missions are enabled. A range of such missions has been analyzed using the MULIMP code, and are described.

A detailed kinetic mechanism including methanol and nitrogen pollutants relevant to the gas-phase combustion and pyrolysis of biomass-derived fuels

Energy Technology Data Exchange (ETDEWEB)

Coda Zabetta, Edgardo; Hupa, Mikko [Aabo Akademi Process Chemistry Centre, Piispankatu 8, FI-20500 Turku (Finland)

2008-01-15

A detailed chemical kinetic mechanism for the simulation of the gas-phase combustion and pyrolysis of biomass-derived fuels was compiled by assembling selected reaction subsets from existing mechanisms (parents). The mechanism, here referred to as ''AaA,'' includes reaction subsets for the oxidation of hydrogen (H{sub 2}), carbon monoxide (CO), light hydrocarbons (C{sub 1} and C{sub 2}), and methanol (CH{sub 3}OH). The mechanism also takes into account reaction subsets of nitrogen pollutants, including the reactions relevant to staged combustion, reburning, and selective noncatalytic reduction (SNCR). The AaA mechanism was validated against suitable experimental data from the literature. Overall, the AaA mechanism gave more accurate predictions than three other mechanisms of reference, although the reference mechanisms performed better occasionally. The predictions from AaA were also found to be consistent with the predictions of its parent mechanisms within most of their range of validity, thus transferring the validity of the parents to the inheriting mechanism (AaA). In parametric studies the AaA mechanism predicted that the effect of methanol on combustion and pollutants is often similar to that of light hydrocarbons, but it also showed that there are important exceptions, thus suggesting that methanol should be taken into account when simulating biomass combustion. To our knowledge, the AaA mechanism is currently the only mechanism that accounts for the chemistry of methanol and nitrogen relevant to the gas-phase combustion and pyrolysis of biomass-derived fuels. (author)

Uranyl peroxide enhanced nuclear fuel corrosion in seawater.

Science.gov (United States)

Armstrong, Christopher R; Nyman, May; Shvareva, Tatiana; Sigmon, Ginger E; Burns, Peter C; Navrotsky, Alexandra

2012-02-07

The Fukushima-Daiichi nuclear accident brought together compromised irradiated fuel and large amounts of seawater in a high radiation field. Based on newly acquired thermochemical data for a series of uranyl peroxide compounds containing charge-balancing alkali cations, here we show that nanoscale cage clusters containing as many as 60 uranyl ions, bonded through peroxide and hydroxide bridges, are likely to form in solution or as precipitates under such conditions. These species will enhance the corrosion of the damaged fuel and, being thermodynamically stable and kinetically persistent in the absence of peroxide, they can potentially transport uranium over long distances.

Evaluation of fuel-temperature feedback mechanisms in TRAC-PF1/MOD2/NESTLE

International Nuclear Information System (INIS)

Knepper, Paula L.; Feltus, Madeline; Hochreiter, L.E.; Ivanov, Kostadin

1999-01-01

Coupled spatial kinetics and thermal-hydraulics system codes provide a means to model transient nuclear reactor behavior more accurately. Transients marked by strong perturbations, both with thermal-hydraulics and neutronics, such as a control-rod ejection or a main steam-line break, are especially of interest. It is now feasible to model complex reactor behavior with a coupled thermal-hydraulics and spatial kinetics code that provides a means to forecast safety margins. Recently, the Transient Reactor Analysis Code (TRAC)-PF1/MOD2, Version 5.4.25, was coupled with the NESTLE code. This coupled code (TRAC-PF1/MOD2/NESTLE) is used to examine effective fuel-temperature models. The Electric Power Research Institute (EPRI) rod-ejection benchmark was analyzed to evaluate the influence of effective fuel temperature. The rod-ejection transient tests only the fuel-rod, heat-conduction coupling. The coolant thermal-hydraulic coupling is not tested because of the speed of the transient. The neutronics solution changes extremely rapidly, whereas the convective heat transfer at the fuel surface requires more time to influence the coolant temperature of the system. The need to model the response of the system coolant temperature is not crucial in this analysis. The influence of the effective fuel temperature is the key component of this study. Various models were examined using the coupled code to calculate effective fuel temperatures. The influence of different, effective fuel-temperature models on the coupled-code results is studied. Three effective fuel-temperature models are examined: (l) volume average effective fuel temperature, (2) the effective fuel-temperature model suggested by the Office of Economic Cooperation and Development (OECD) rod-ejection benchmark, and (3) the NESTLE effective fuel-temperature model. A discussion is provided describing the effective fuel-temperature models examined in TRAC-PF1/MOD2/NESTLE and the influence of effective fuel temperature in

Development of ceramics based fuel, Phase I, Kinetics of UO{sub 2} sintering by vibration compacting of UO{sub 2} powder (Introductory report); Razvoj goriva na bazi keramike, I faza, Kinetika sinterovanja UO{sub 2} vibraciono kompaktiranje praha UO{sub 2} (Uvodni izvestaj)

Energy Technology Data Exchange (ETDEWEB)

Ristic, M M [Institute of Nuclear Sciences Vinca, Laboratorija za reaktorske materijale, Beograd (Serbia and Montenegro)

1962-10-15

After completing the Phase I of the task related to development of ceramics nuclear fuel the following reports are presented: Kinetics of UO{sub 2} sintering; Vibrational compacting and sintering of UO{sub 2}; Characterisation of of UO{sub 2} powder by DDK and TGA methods; Separation of UO{sub 2} powder.

High-silicon 238PuO2 fuel characterization study: Half module impact tests

International Nuclear Information System (INIS)

Reimus, M.A.H.

1997-01-01

The General-Purpose Heat Source (GPHS) provides power for space missions by transmitting the heat of [sup 238]Pu decay to an array of thermoelectric elements. The modular GPHS design was developed to address both survivability during launch abort and return from orbit. Previous testing conducted in support of the Galileo and Ulysses missions documented the response of GPHSs to a variety of fragment- impact, aging, atmospheric reentry, and Earth-impact conditions. The evaluations documented in this report are part of an ongoing program to determine the effect of fuel impurities on the response of the heat source to conditions baselined during the Galileo/Ulysses test program. In the first two tests in this series, encapsulated GPHS fuel pellets containing high levels of silicon were aged, loaded into GPHS module halves, and impacted against steel plates. The results show no significant differences between the response of these capsules and the behavior of relatively low-silicon fuel pellets tested previously

Fuel Efficiency Assessment with DEA

Science.gov (United States)

2010-03-01

weighted with regard to their relative importance. The weights are subjectively de - fined by subject experts, which makes the FEI vulnerable to...Energy Information Administration, Imports, Exports and Movements. The US government consumes only a small amount of fuel/energy of the US de - mand...it takes every measure to conserve energy and this is stated in their mission statement. Gen. Arthur J. Lichte stated AMC’s new five focus areas as

IAEA OSART/EXPERT follow-up review mission completes assessment of actions taken by Paks Nuclear Power Plant

International Nuclear Information System (INIS)

2004-01-01

On 28 February 2004 the IAEA completed its follow-up review mission to assess the actions taken by Paks nuclear power plant (NPP) in response to the Agency's recommendations and suggestions made during the 2001 Operational Safety Review Team (OSART) mission and the 2003 Expert mission that investigated the fuel cleaning incident at the Paks NPP in Hungary. The mission was requested by the Hungarian Government to provide an independent assessment of the actions taken by Paks NPP. The IAEA team determined that the actions taken by Paks have resulted in tangible progress and concluded that all issues were either fully resolved or progressing satisfactorily. In a press conference, the team's conclusions in five areas were highlighted: management, Regulatory Oversight/Interface, operations and maintenance, including operating experience, radiation protection, emergency planning and preparedness, and transparency

Evaluation of wood residues from Crete as alternative fuels

Energy Technology Data Exchange (ETDEWEB)

Vamvuka, D. [Department of Mineral Resources Engineering, Technical University of Crete (Greece); Bandelis, G. [Professional School of Chania, EPAS Chania (Greece)

2010-07-01

Olive and citrus prunings, the main agricultural residues of Crete, are considered to be of premium importance for local energy production, substituting a large part of conventional fuels. The thermal behaviour of these fuels during combustion was studied by thermogravimetry, at non-isothermal heating conditions. Fly ashes were collected from tests in a lab-scale fluidized bed facility. The effect of the inorganic constituents of the fuels on slagging/fouling and agglomeration propensities, as well as environmental pollution was examined. Kinetic models were developed and reaction rates were determined. The agroresidues studied were characterized as good quality fuels, having high volatile and low ash and sulphur contents. Their ash was rich in Ca, Si, K and P minerals. However, fly ashes were poorer in alkali compounds, implying lower deposition and corrosion problems in boilers. The environmental impact of heavy metals is negligible. The thermochemical reactivity of the two fuels in air was very similar. A power low model fitted the experimental results accurately.

Final safety analysis report for the Galileo mission: Volume 3 (Book 2), Nuclear risk analysis document: Appendices: Revision 1

Energy Technology Data Exchange (ETDEWEB)

1989-01-25

It is the purpose of the NRAD to provide an analysis of the range of potential consequences of accidents which have been identified that are associated with the launching and deployment of the Galileo mission spacecraft. The specific consequences analyzed are those associated with the possible release of radioactive material (fuel) of the Radioisotope Thermoelectric Generators (RTGs). They are in terms of radiation doses to people and areas of deposition of radioactive material. These consequence analyses can be used in several ways. One way is to identify the potential range of consequences which might have to be dealt with if there were to be an accident with a release of fuel, so as to assure that, given such an accident, the health and safety of the public will be reasonably protected. Another use of the information, in conjunction with accident and release probabilities, is to estimate the risks associated with the mission. That is, most space launches occur without incident. Given an accident, the most probable result relative to the RTGs is complete containment of the radioactive material. Only a small fraction of accidents might result in a release of fuel and subsequent radiological consequences. The combination of probability with consequence is risk, which can be compared to other human and societal risks to assure that no undue risks are implied by undertaking the mission. Book 2 contains eight appendices.

[The mission].

Science.gov (United States)

Ruiz Moreno, J; Blanch Mon, A

2000-01-01

After having made a historical review of the concept of mission statement, of evaluating its importance (See Part I), of describing the bases to create a mission statement from a strategic perspective and of analyzing the advantages of this concept, probably more important as a business policy (See Parts I and II), the authors proceed to analyze the mission statement in health organizations. Due to the fact that a mission statement is lacking in the majority of health organizations, the strategy of health organizations are not exactly favored; as a consequence, neither are its competitive advantage nor the development of its essential competencies. After presenting a series of mission statements corresponding to Anglo-Saxon health organizations, the authors highlight two mission statements corresponding to our social context. The article finishes by suggesting an adequate sequence for developing a mission statement in those health organizations having a strategic sense.

HETEROGENEOUS REBURNING BY MIXED FUELS

Energy Technology Data Exchange (ETDEWEB)

Wei-Yin Chen; Benson B. Gathitu

2005-01-14

Recent studies of heterogeneous reburning, i.e., reburning involving a coal-derived char, have elucidated its variables, kinetics and mechanisms that are valuable to the development of a highly efficient reburning process. Young lignite chars contain catalysts that not only reduce NO, but they also reduce HCN that is an important intermediate that recycles to NO in the burnout zone. Gaseous CO scavenges the surface oxides that are formed during NO reduction, regenerating the active sites on the char surface. Based on this mechanistic information, cost-effective mixed fuels containing these multiple features has been designed and tested in a simulated reburning apparatus. Remarkably high reduction of NO and HCN has been observed and it is anticipated that mixed fuel will remove 85% of NO in a three-stage reburning process.

Implementation and Test of the Automatic Flight Dynamics Operations for Geostationary Satellite Mission

Directory of Open Access Journals (Sweden)

Sangwook Park

2009-12-01

Full Text Available This paper describes the Flight Dynamics Automation (FDA system for COMS Flight Dynamics System (FDS and its test result in terms of the performance of the automation jobs. FDA controls the flight dynamics functions such as orbit determination, orbit prediction, event prediction, and fuel accounting. The designed FDA is independent from the specific characteristics which are defined by spacecraft manufacturer or specific satellite missions. Therefore, FDA could easily links its autonomous job control functions to any satellite mission control system with some interface modification. By adding autonomous system along with flight dynamics system, it decreases the operator’s tedious and repeated jobs but increase the usability and reliability of the system. Therefore, FDA is used to improve the completeness of whole mission control system’s quality. The FDA is applied to the real flight dynamics system of a geostationary satellite, COMS and the experimental test is performed. The experimental result shows the stability and reliability of the mission control operations through the automatic job control.

Thermal behavior and kinetics assessment of ethanol/gasoline blends during combustion by thermogravimetric analysis

International Nuclear Information System (INIS)

3, CEP 12.516-410 Guaratinguetá, SP (Brazil); U.T.P. – Universidad Tecnológica de Pereira, Faculty of Mechanical Engineering, Pereira, Risaralda (Colombia))" data-affiliation=" (UNESP – Univ Estadual Paulista, Campus of Guaratinguetá, Department of Energy, Laboratory of Combustion and Carbon Capture LC3, CEP 12.516-410 Guaratinguetá, SP (Brazil); U.T.P. – Universidad Tecnológica de Pereira, Faculty of Mechanical Engineering, Pereira, Risaralda (Colombia))" >Rios Quiroga, Luis Carlos; 3, CEP 12.516-410 Guaratinguetá, SP (Brazil))" data-affiliation=" (UNESP – Univ Estadual Paulista, Campus of Guaratinguetá, Department of Energy, Laboratory of Combustion and Carbon Capture LC3, CEP 12.516-410 Guaratinguetá, SP (Brazil))" >Balestieri, José 3, CEP 12.516-410 Guaratinguetá, SP (Brazil))" data-affiliation=" (UNESP – Univ Estadual Paulista, Campus of Guaratinguetá, Department of Energy, Laboratory of Combustion and Carbon Capture LC3, CEP 12.516-410 Guaratinguetá, SP (Brazil))" >Antonio Perrella; 3, CEP 12.516-410 Guaratinguetá, SP (Brazil))" data-affiliation=" (UNESP – Univ Estadual Paulista, Campus of Guaratinguetá, Department of Energy, Laboratory of Combustion and Carbon Capture LC3, CEP 12.516-410 Guaratinguetá, SP (Brazil))" >Ávila, Ivonete

2017-01-01

Highlights: • Kinetic parameters of thermal decomposition events were obtained. • Thermal analysis was used as a tool for understanding combustion processes. • Blends would be classified using thermogravimetric analysis technics. • Synergistic effect of ethanol mixed with gasoline was studied and defined. • Relative error and activation energy values were used to analyze the synergy. - Abstract: The use of ethanol as a fuel or as an additive blended with gasoline is very important for most countries, which aim to reduce the heavy dependence on fossil fuels and mitigate greenhouse gases emission. An increased use of ethanol-gasoline blends has placed great relevance on acquiring knowledge about their physical and chemical properties. Thus, knowledge of such properties favors a better understanding of the effect of the percentage of ethanol/gasoline blends on engine performance. Thence, the present study has established a correlation between activation energy and synergetic effects, obtained by a thermal analysis, and ethanol content in gasoline for different blends in order to use this technique as a tool to classify these blends in the process in order to obtain useful energy in spark ignition engines. For such a purpose, a kinetic study has been conducted through a simultaneous thermal analysis system – TGA (thermogravimetry analysis) and DTA (differential thermal analysis) by following the methodology of non-isothermal tests. Thermogravimetric tests were performed and fuel activation energies for gasoline, ethanol, and percentages of 5, 10, 15, 20, 25, 30, 50, and 75% (%v) ethanol mixed with gasoline, which was achieved by the model free kinetics. The analysis results suggest that the theoretical curves characteristics of the thermal decomposition of ethanol-gasoline blends are rather different due to their ethanol content. Furthermore, it was observed significant interactions and synergistic effects, especially regarding those with low ethanol

Short rendezvous missions for advanced Russian human spacecraft

Science.gov (United States)

Murtazin, Rafail F.; Budylov, Sergey G.

2010-10-01

The two-day stay of crew in a limited inhabited volume of the Soyuz-TMA spacecraft till docking to ISS is one of the most stressful parts of space flight. In this paper a number of possible ways to reduce the duration of the free flight phase are considered. The duration is defined by phasing strategy that is necessary for reduction of the phase angle between the chaser and target spacecraft. Some short phasing strategies could be developed. The use of such strategies creates more comfortable flight conditions for crew thanks to short duration and additionally it allows saving spacecraft's life support resources. The transition from the methods of direct spacecraft rendezvous using one orbit phasing (first flights of " Vostok" and " Soyuz" vehicles) to the currently used methods of two-day rendezvous mission can be observed in the history of Soviet manned space program. For an advanced Russian human rated spacecraft the short phasing strategy is recommended, which can be considered as a combination between the direct and two-day rendezvous missions. The following state of the art technologies are assumed available: onboard accurate navigation; onboard computations of phasing maneuvers; launch vehicle with high accuracy injection orbit, etc. Some operational requirements and constraints for the strategies are briefly discussed. In order to provide acceptable phase angles for possible launch dates the experience of the ISS altitude profile control can be used. As examples of the short phasing strategies, the following rendezvous missions are considered: direct ascent, short mission with the phasing during 3-7 orbits depending on the launch date (nominal or backup). For each option statistical modeling of the rendezvous mission is fulfilled, as well as an admissible phase angle range, accuracy of target state vector and addition fuel consumption coming out of emergency is defined. In this paper an estimation of pros and cons of all options is conducted.

Waste heat recovery for transport trucks using thermally regenerative fuel cells

Energy Technology Data Exchange (ETDEWEB)

Carrier, A.; Wechsler, D.; Whitney, R.; Jessop, P. [Queen' s Univ., Kingston, ON (Canada). Dept. of Chemistry; Davis, B.R. [Queen' s-RMC Fuel Cell Research Centre, Kingston, ON (Canada)

2009-07-01

Carbon emissions associated with transportation can be reduced by increasing the fuel efficiency of transport trucks. This can be achieved with thermally regenerative fuel cells that transform the waste heat from the engine block into electricity. In order to operate such a fuel cell, one needs a fluid which rapidly, reversibly, and selectively undergoes dehydrogenation. Potential fluids have been screened for their ability to dehydrogenate and then rehydrogenate at the appropriate temperatures. An examination of the thermodynamics, kinetics, and selectivities of these processes have shown that the challenge involving hydrogenolysis at high temperature must be addressed. This paper discussed the economics of thermally regenerative fuel cells and the advantages and disadvantages of the identified fluids, and of such systems in general.

The feasibility study I on the blanket fuel options for the ATW/HYPER

Energy Technology Data Exchange (ETDEWEB)

Hwang, Woan; Lee, Byoung Oon; Lee, Bong Sang; Park, Won Seok; Meyer, M.K; Hayes, S.L

2001-01-01

The choice of a blanket fuel cycle technology and the fuel type for HYPER/ATW are important to develop an ADS with better economics, performance and safety. Even though several fuel types have been considered as an alternative of the blanket fuels for HYPER/ATW, the metal alloy and the dispersion fuels were selected as the candidate fuels for ADS, and the technical feasibilities for both fuels are evaluated in this report. General performance characteristics, fabrication abilities, technical aspects, safety aspects, economics, and non-proliferation aspects for each fuel type are reviewed and evaluated. And some technological problems are addressed in this report, focused on the development strategy, the roadmaps, and the flexibility to meet the missions and specific designs. This study has been performed at the first stage of conceptual design. Since it is under the lack of physical properties for each fuel material, no an attempt is made to select the best fuel option, but the more better fuel options are recommended.

The feasibility study I on the blanket fuel options for the ATW/HYPER

International Nuclear Information System (INIS)

Hwang, Woan; Lee, Byoung Oon; Lee, Bong Sang; Park, Won Seok; Meyer, M.K; Hayes, S.L.

2001-01-01

The choice of a blanket fuel cycle technology and the fuel type for HYPER/ATW are important to develop an ADS with better economics, performance and safety. Even though several fuel types have been considered as an alternative of the blanket fuels for HYPER/ATW, the metal alloy and the dispersion fuels were selected as the candidate fuels for ADS, and the technical feasibilities for both fuels are evaluated in this report. General performance characteristics, fabrication abilities, technical aspects, safety aspects, economics, and non-proliferation aspects for each fuel type are reviewed and evaluated. And some technological problems are addressed in this report, focused on the development strategy, the roadmaps, and the flexibility to meet the missions and specific designs. This study has been performed at the first stage of conceptual design. Since it is under the lack of physical properties for each fuel material, no an attempt is made to select the best fuel option, but the more better fuel options are recommended

Non-kinetic capabilities: complementing the kinetic prevalence to targeting

OpenAIRE

Ducheine, P.

2014-01-01

Targeting is used in military doctrine to describe a military operational way, using (military) means to influence a target (or addressee) in order to achieve designated political and/or military goals. The four factors italicized are used to analyse non-kinetic targeting, complementing our knowledge and understanding of the kinetic prevalence. Paradoxically, non-kinetic targeting is not recognized as a separate concept: kinetic and non-kinetic are intertwined facets of targeting. Kinetic tar...

Presumptions of effective operation of diesel engines running on rme biodiesel. Research on kinetics of combustion of RME biodiesel

Directory of Open Access Journals (Sweden)

A. Vaicekauskas

2007-06-01

Full Text Available The results of experimental research on kinetics of fuel combustion of diesel engine A41are presented in the publication. The change of characteristics of indicated work (in-cylinder pressure and temperature, period of induction, heat release and heat release rate and fuel injection (fuel injection pressure, fuel injection phases was determined in diesel engine running on RME biodiesel being compared to diesel fuel. The results of researches were used to explain experimentally determined changes of operational and ecological characteristics of diesel engine running on RME biodiesel. In addition, the reliability of diesel engine A41 running on RME biodiesel was evaluated. The presumptions of effective operation of diesel engines running on RME biodiesel were formulated.

Effects of high density dispersion fuel loading on the kinetic parameters of a low enriched uranium fueled material test research reactor

Energy Technology Data Exchange (ETDEWEB)

Muhammad, Farhan [Department of Nuclear Engineering, Pakistan Institute of Engineering and Applied Sciences, P.O. Nilore, Islamabad 45650 (Pakistan)], E-mail: mfarhan_73@yahoo.co.uk; Majid, Asad [Department of Nuclear Engineering, Pakistan Institute of Engineering and Applied Sciences, P.O. Nilore, Islamabad 45650 (Pakistan)

2008-09-15

The effects of using high density low enriched uranium on the neutronic parameters of a material test research reactor were studied. For this purpose, the low density LEU fuel of an MTR was replaced with high density LEU fuels currently being developed under the RERTR program. Since the alloying elements have different cross-sections affecting the reactor in different ways, therefore fuels U-Mo (9 w/o) which contain the same elements in same ratio were selected for analysis. Simulations were carried out to calculate core excess reactivity, neutron flux spectrum, prompt neutron generation time, effective delayed neutron fraction and feedback coefficients including Doppler feedback coefficient, and reactivity coefficients for change of water density and temperature. Nuclear reactor analysis codes including WIMS-D4 and CITATION were employed to carry out these calculations. It is observed that the excess reactivity at the beginning of life does not increase as the uranium density of fuel. Both the prompt neutron generation time and the effective delayed neutron fraction decrease as the uranium density increases. The absolute value of Doppler feedback coefficient increases while the absolute values of reactivity coefficients for change of water density and temperature decrease.

Effects of high density dispersion fuel loading on the kinetic parameters of a low enriched uranium fueled material test research reactor

International Nuclear Information System (INIS)

Muhammad, Farhan; Majid, Asad

2008-01-01

The effects of using high density low enriched uranium on the neutronic parameters of a material test research reactor were studied. For this purpose, the low density LEU fuel of an MTR was replaced with high density LEU fuels currently being developed under the RERTR program. Since the alloying elements have different cross-sections affecting the reactor in different ways, therefore fuels U-Mo (9 w/o) which contain the same elements in same ratio were selected for analysis. Simulations were carried out to calculate core excess reactivity, neutron flux spectrum, prompt neutron generation time, effective delayed neutron fraction and feedback coefficients including Doppler feedback coefficient, and reactivity coefficients for change of water density and temperature. Nuclear reactor analysis codes including WIMS-D4 and CITATION were employed to carry out these calculations. It is observed that the excess reactivity at the beginning of life does not increase as the uranium density of fuel. Both the prompt neutron generation time and the effective delayed neutron fraction decrease as the uranium density increases. The absolute value of Doppler feedback coefficient increases while the absolute values of reactivity coefficients for change of water density and temperature decrease

Analysis of UO{sub 2}-BeO fuel under transient using fuel performance code

Energy Technology Data Exchange (ETDEWEB)

Gomes, Daniel S.; Abe, Alfredo Y.; Muniz, Rafael O.R.; Giovedi, Claudia, E-mail: dsgomes@ipen.br, E-mail: alfredo@ctmsp.mar.mil.br, E-mail: rafael.orm@gmail.com, E-mail: claudia.giovedi@ctmsp.mar.mil.br [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil); Universidade de São Paulo (USP), São Paulo, SP (Brazil). Departamento de Engenharia Naval e Oceânica

2017-11-01

Recent research has appointed the need to replace the classic fuel concept, used in light water reactors. Uranium dioxide has a weak point due to the low thermal conductivity, that produce high temperatures on the fuel. The ceramic composite fuel formed of uranium dioxide (UO{sub 2}), with the addition of beryllium oxide (BeO), presents high thermal conductivity compared with UO{sub 2}. The oxidation of zirconium generates hydrogen gas that can create a detonation condition. One of the preferred options are the ferritic alloys formed of iron-chromium and aluminum (FeCrAl), that should avoid the hydrogen release due to oxidation. In general, the FeCrAl alloys containing 10 - 20Cr, 3 - 5Al, and 0 - 0.12Y in weight percent. The FeCrAl alloys should exhibit a slow oxidation kinetics due to chemical composition. Resistance to oxidation in the presence of steam is improved as a function of the content of chromium and aluminum. In this way, the thermal and mechanical properties of the UO{sub 2}-BeO-10%vol, composite fuel were coupled with FeCrAl alloys and added to the fuel codes. In this work, we examine the fuel rod behavior of UO{sub 2}-10%vol-BeO/FeCrAl, including a simulated transient of reactivity. The fuels behavior shown reduced temperature with UO{sub 2}-BeO/Zr, UO{sub 2}-BeO/FeCrAl also were compared with UO{sub 2}/Zr system. The case reactivity initiated accident analyzed, reproducing the fuel rod called VA-1 using UO{sub 2}/Zr alloys and compared with UO{sub 2}-BeO/FeCrAl. (author)

Oxidation behaviour of Zr-Ce alloys. Kinetic and microstructure aspects

International Nuclear Information System (INIS)

Rouillon, Ludovic

1996-01-01

As Zircaloy alloys are used for fuel rods in pressurized water nuclear reactors, this research thesis aims at studying and improving corrosion resistance of zirconium alloys while maintaining their mechanical properties. It more precisely deals with the kinetic and microstructure aspects of the external corrosion of the cladding by the coolant. In the case of Zircaloys, this corrosion is characterized by a kinetic transition from an initially parabolic to a linear regime. This research aims at intervening on this transition by elaborating zirconium alloys containing an element which stabilizes zirconia, in this case cerium. After having reported a bibliographical study on sheath oxidation, on parameters which influence sheath oxidation kinetics, on zirconia stabilization by doping elements, on the interest of lanthanide oxides, the author reports a feasibility study on the use of cerium (choice and preparation, sintered ceramic characterization, annealing of stabilized zirconia), reports a metallurgical study of Zr-Ce alloys, reports the study of the oxidation behaviour of these alloys (in autoclave, in presence of oxygen, under oxygen and then water) and the characterization of the microstructures of the oxide layers. He finally discusses the relationship between microstructure and oxidation kinetics, the role of cerium in the oxidation process, and the role of water in the oxidation process [fr

Modeling the burnout of solid polydisperse fuel under the conditions of external heat transfer

Science.gov (United States)

Skorik, I. A.; Goldobin, Yu. M.; Tolmachev, E. M.; Gal'perin, L. G.

2013-11-01

A self-similar burnout mode of solid polydisperse fuel is considered taking into consideration heat transfer between fuel particles, gases, and combustion chamber walls. A polydisperse composition of fuel is taken into account by introducing particle distribution functions by radiuses obtained for the kinetic and diffusion combustion modes. Equations for calculating the temperatures of particles and gases are presented, which are written for particles average with respect to their distribution functions by radiuses taking into account the fuel burnout ratio. The proposed equations take into consideration the influence of fuel composition, air excess factor, and gas recirculation ratio. Calculated graphs depicting the variation of particle and gas temperatures, and the fuel burnout ratio are presented for an anthracite-fired boiler.

Kinetic Evaluation of Lipid Oils Conversion to Biofuel Using Layered Double Hydroxide Doped with Triazabicyclodece Catalyst

Science.gov (United States)

Nato Lopez, Frank D.

Worldwide, there is an ever increasing need for sustainable, renewable fuels that will accommodate the rapidly increasing energy demand and provide independence from fossil fuels. The search for a sustainable alternative to petroleum based fuels has been a great challenge to the scientific community; therefore, great efforts are being made to overcome the fossil fuels dependence by exploring the prominent field of biofuels (bioethanol and biodiesel). Traditional biodiesel is produced from feedstocks such as vegetable oils and animal fats by converting the triglycerides with methanol in the presence of a homogeneous catalyst to produce fatty acid methyl esters (FAMEs). However, drawbacks of this process are the undesired glycerol byproduct and post reaction processing, including separation from reaction mixture, that results in high costs factors. In the present work, the reaction kinetics of a glycerol-free biodiesel method is studied. This method consists of the transesterification of a vegetable oil (i.e. canola oil) using dimethyl carbonate (DMC) as an alternative methylating agent in presence of layered double hydroxides doped with triazabicyclodecene catalyst (a basic organocatalyst). Furthermore, is theorized that this heterogeneous catalyst (TBD/LDH) simultaneously converts both FFAs and triglycerides due to acid sites formed by Al3+ active sites of the LDH structure. Additionally, the versatility of the Raman in situ technique was used as quantitative analysis tool to monitor the reaction kinetics and collect real time data.

Thermal conversion of polyolefins/polystyrene ternary mixtures: Kinetics and pyrolysis on a laboratory and commercial scales

Czech Academy of Sciences Publication Activity Database

Straka, Pavel; Bičáková, Olga; Šupová, Monika

2017-01-01

Roč. 128, November (2017), s. 196-207 ISSN 0165-2370 Institutional support: RVO:67985891 Keywords : kinetics * pyrolysis * oil * waste plastics * GS-MS * TG-MS Subject RIV: DM - Solid Waste and Recycling OBOR OECD: Energy and fuels Impact factor: 3.471, year: 2016

Origin and monitoring of pollutants in fossil-fuel flames

International Nuclear Information System (INIS)

Chigier, N.A.

1976-01-01

A review is given of the origin of pollutants in fossil-fuel flames. Burning of fossil fuels is the major cause of air pollution and significant reductions in levels of environmental pollution can be achieved by more effective control of combustion systems. The chemical kinetics of formation of unburned hydrocarbons, oxides of nitrogen, carbon monoxide and particulate matter are described, as well as the reactions which can lead to oxidation and destruction of these pollutants within the flame. The important influence of mixing and aerodynamics is discussed, together with methods of mathematical modelling and prediction methods. Practical problems arising in gas turbine engines, spark ignition engines and diesel engines are investigated in order to minimize the emission of pollutants while preserving fuel economy. (author)

Direct dimethyl ether high temperature polymer electrolyte membrane fuel cells

DEFF Research Database (Denmark)

Vassiliev, Anton; Jensen, Jens Oluf; Li, Qingfeng

and suffers from low DME solubility in water. When the DME - water mixture is fed as vapour miscibility is no longer a problem. The increased temperature is more beneficial for the kinetics of the direct oxidation of DME than of methanol. The Open Circuit Voltage (OCV) with DME operation was 50 to 100 m......A high temperature polybenzimidazole (PBI) polymer fuel cell was fed with dimethyl ether (DME) and water vapour mixture on the anode at ambient pressure with air as oxidant. A peak power density of 79 mW/cm2 was achieved at 200°C. A conventional polymer based direct DME fuel cell is liquid fed......V higher than that of methanol, indicating less fuel crossover....

Spatial kinetics studies in liquid-metal fast breeder reactor critical assemblies

International Nuclear Information System (INIS)

Brumback, S.B.; Goin, R.W.; Carpenter, S.G.

1988-01-01

Recent measurements in the zero-power physics reactor have been used to study the effect of spatial decoupling in fast reactor critical assemblies of various sizes and compositions. Flux distributions in these assemblies had varying degrees of sensitivity to perturbations. Decoupling was investigated using rod-drop, boron-oscillator, and noise-coherence techniques, which emphasized different times following perturbations. Equilibrium flux distributions were also measured for subcritical configurations with inserted control rods. For most assemblies, accurate reactivity measurements were obtained by analyzing the power history from a single detector using inverse kinetics methods, assuming an instantaneous efficiency change for the detector. The instantaneous efficiency change assumption broke down, however, in assemblies with zones in which normal plutonium fuel was replaced by /sup 235/U fuel or fuel with a high /sup 240/Pu content. Flux redistributions caused by perturbations in these cores took several minutes to evolve

INL Initial Input to the Mission Need for Advanced Post-Irradiation Examination Capability A Non-Major System Acquisition Project

International Nuclear Information System (INIS)

Tonc, Vince

2010-01-01

Consolidated and comprehensive post-irradiation examination (PIE) capabilities will enable the science and engineering understanding needed to develop the innovative nuclear fuels and materials that are critical to the success of the U.S. Department of Energy's (DOE) Office of Nuclear Energy (NE) programs. Existing PIE capabilities at DOE Laboratories, universities, and in the private sector are widely distributed, largely antiquated, and insufficient to support the long-range mission needs. In addition, DOE's aging nuclear infrastructure was not designed to accommodate modern, state-of-the-art equipment and instrumentation. Currently, the U.S. does not have the capability to make use of state-of-the-art technology in a remote, hot cell environment to characterize irradiated fuels and materials on the micro, nano, and atomic scale. This 'advanced PIE capability' to make use of state-of-the-art scientific instruments in a consolidated nuclear operating environment will enable comprehensive characterization and investigation that is essential for effectively implementing the nuclear fuels and materials development programs in support of achieving the U.S. DOE-NE Mission.

Transient analysis of carbon monoxide transport phenomena and adsorption kinetics in HT-PEMFC during dynamic current extraction

International Nuclear Information System (INIS)

Raj, Kamal Abdul Rasheedj; Chan, Siew Hwa

2015-01-01

Highlights: • Increasing the fuel cell temperature reduces outlet CO concentration. • Increasing the CO inlet (initial) concentration increases outlet CO concentration. • Increasing current density step and dwell time increases outlet CO concentration. • Increasing in the CL and GDL porosities reduces outlet CO concentration. - Abstract: This paper investigates the transport phenomena of carbon monoxide (CO) and adsorption kinetics, in a high-temperature proton exchange membrane fuel cell (HT-PEMFC) during step-wise current extraction (step-change in current extraction). Step-wise current extraction is a common process done to accommodate a sudden power surge during an operation. Since HT-PEMFCs are capable of handling high impurity of CO, hydrogen fuel that is contaminated with trace amount of CO is usually considered for commercial benefits. Thus, a transient three-dimensional isothermal anodic electro-kinetic numerical model is developed to determine the effect of operating parameters such as fuel cell temperature, CO inlet (initial) concentration, step-change of current density and dwell time on the transport phenomena of CO and adsorption kinetics. In addition, geometrical factors such as the catalyst layer (CL) and gas diffusion layer (GDL) porosity are also varied as well. The results show that the above-mentioned operating parameters can affect the maximum CO concentration at the CL, especially at the outlet of the channel. Specifically, a reduction of fuel cell temperature can significantly increase the CO concentration near the outlet, while increasing CO inlet (initial) concentration, step-change amplitude of current density and current density dwell time can cause an increase in CO concentration at the outlet, albeit to different extent. In addition, the increase in the porosity of CL and GDL, results in the reduction of the maximum CO concentration at the outlet, albeit to different extent. In addition, the CO and hydrogen surface coverage

Autonomous Mission Design in Extreme Orbit Environments

Science.gov (United States)

Surovik, David Allen

An algorithm for autonomous online mission design at asteroids, comets, and small moons is developed to meet the novel challenges of their complex non-Keplerian orbit environments, which render traditional methods inapplicable. The core concept of abstract reachability analysis, in which a set of impulsive maneuvering options is mapped onto a space of high-level mission outcomes, is applied to enable goal-oriented decision-making with robustness to uncertainty. These nuanced analyses are efficiently computed by utilizing a heuristic-based adaptive sampling scheme that either maximizes an objective function for autonomous planning or resolves details of interest for preliminary analysis and general study. Illustrative examples reveal the chaotic nature of small body systems through the structure of various families of reachable orbits, such as those that facilitate close-range observation of targeted surface locations or achieve soft impact upon them. In order to fulfill extensive sets of observation tasks, the single-maneuver design method is implemented in a receding-horizon framework such that a complete mission is constructed on-the-fly one piece at a time. Long-term performance and convergence are assured by augmenting the objective function with a prospect heuristic, which approximates the likelihood that a reachable end-state will benefit the subsequent planning horizon. When state and model uncertainty produce larger trajectory deviations than were anticipated, the next control horizon is advanced to allow for corrective action -- a low-frequency form of feedback control. Through Monte Carlo analysis, the planning algorithm is ultimately demonstrated to produce mission profiles that vary drastically in their physical paths but nonetheless consistently complete all goals, suggesting a high degree of flexibility. It is further shown that the objective function can be tuned to preferentially minimize fuel cost or mission duration, as well as to optimize

Transport phenomena in fuel cells : from microscale to macroscale

Energy Technology Data Exchange (ETDEWEB)

Djilali, N. [Victoria Univ., BC (Canada). Dept. of Mechanical Engineering]|[Victoria Univ., BC (Canada). Inst. for Integrated Energy Systems

2006-07-01

Proton Exchange Membrane (PEM) fuel cells rely on an array of thermofluid transport processes for the regulated supply of reactant gases and the removal of by-product heat and water. Flows are characterized by a broad range of length and time scales that take place in conjunction with reaction kinetics in a variety of regimes and structures. This paper examined some of the challenges related to computational fluid dynamics (CFD) modelling of PEM fuel cell transport phenomena. An overview of the main features, components and operation of PEM fuel cells was followed by a discussion of the various strategies used for component modelling of the electrolyte membrane; the gas diffusion layer; microporous layer; and flow channels. A review of integrated CFD models for PEM fuel cells included the coupling of electrochemical thermal and fluid transport with 3-D unit cell simulations; air-breathing micro-structured fuel cells; and stack level modelling. Physical models for modelling of transport at the micro-scale were also discussed. Results of the review indicated that the treatment of electrochemical reactions in a PEM fuel cell currently combines classical reaction kinetics with solutions procedures to resolve charged species transport, which may lead to thermodynamically inconsistent solutions for more complex systems. Proper representation of the surface coverage of all the chemical species at all reaction sites is needed, and secondary reactions such as platinum (Pt) dissolution and oxidation must be accounted for in order to model and understand degradation mechanisms in fuel cells. While progress has been made in CFD-based modelling of fuel cells, functional and predictive capabilities remain a challenge because of fundamental modelling and material characterization deficiencies in ionic and water transport in polymer membranes; 2-phase transport in porous gas diffusion electrodes and gas flow channels; inadequate macroscopic modelling and resolution of catalyst

From laboratory experiments to a geological disposal vault: calculation of used nuclear fuel dissolution rates

International Nuclear Information System (INIS)

Sunder, S.; Shoesmith, D.W.; Kolar, M.; Leneveu, D.M.

1998-01-01

Calculation of used nuclear fuel dissolution rates in a geological disposal vault requires a knowledge of the redox conditions in the vault. For redox conditions less oxidizing than those causing UO 2 oxidation to the U 3 O 7 , stage, a thermodynamically-based model is appropriate. For more oxidizing redox conditions a kinetic or an electrochemical model is needed to calculate these rates. The redox conditions in a disposal vault will be affected by the radiolysis of groundwater by the ionizing radiation associated with the fuel. Therefore, we have calculated the alpha-, beta- and gamma-dose rates in water in contact with the reference used fuel in the Canadian Nuclear Fuel Waste Management Program (CNFWMP) as a function of cooling time. Also, we have determined dissolution rates of UO 2 fuel as a function of alpha and gamma dose rates from our electrochemical measurements. These room-temperature rates are used to calculate the dissolution rates of used fuel at 100 o C, the highest temperature expected in a container in the CNFWMP, as a function of time since emplacement. It is shown that beta radiolysis of water will be the main cause of oxidation of used CANDU fuel in a failed container. The use of a kinetic or an electrochemical corrosion model, to calculate fuel dissolution rates, is required for a period of ∼1000 a following emplacement of copper containers in the geologic disposal vault envisaged in the CNFWMP. Beyond this time period a thermodynamically-based model adequately predicts the fuel dissolution rates. The results presented in this paper can be adopted to calculate used fuel dissolution rates for other used UO 2 fuels in other waste management programs. (author)

Spectroscopy, Kinetics, and Dynamics of Combustion Radicals

Energy Technology Data Exchange (ETDEWEB)

Nesbitt, David J. [Research/Professor

2013-08-06

Spectroscopy, kinetics and dynamics of jet cooled hydrocarbon transients relevant to the DOE combustion mission have been explored, exploiting i) high resolution IR lasers, ii) slit discharge sources for formation of jet cooled radicals, and iii) high sensitivity detection with direct laser absorption methods and near the quantum shot noise limit. What makes this combination powerful is that such transients can be made under high concentrations and pressures characteristic of actual combustion conditions, and yet with the resulting species rapidly cooled (T ≈10-15K) in the slit supersonic expansion. Combined with the power of IR laser absorption methods, this provides novel access to spectral detection and study of many critical combustion species.

Enhancing charge transfer kinetics by nanoscale catalytic cermet interlayer.

Science.gov (United States)

An, Jihwan; Kim, Young-Beom; Gür, Turgut M; Prinz, Fritz B

2012-12-01

Enhancing the density of catalytic sites is crucial for improving the performance of energy conversion devices. This work demonstrates the kinetic role of 2 nm thin YSZ/Pt cermet layers on enhancing the oxygen reduction kinetics for low temperature solid oxide fuel cells. Cermet layers were deposited between the porous Pt cathode and the dense YSZ electrolyte wafer using atomic layer deposition (ALD). Not only the catalytic role of the cermet layer itself but the mixing effect in the cermet was explored. For cells with unmixed and fully mixed cermet interlayers, the maximum power density was enhanced by a factor of 1.5 and 1.8 at 400 °C, and by 2.3 and 2.7 at 450 °C, respectively, when compared to control cells with no cermet interlayer. The observed enhancement in cell performance is believed to be due to the increased triple phase boundary (TPB) density in the cermet interlayer. We also believe that the sustained kinetics for the fully mixed cermet layer sample stems from better thermal stability of Pt islands separated by the ALD YSZ matrix, which helped to maintain the high-density TPBs even at elevated temperature.

SP-100 multimegawatt scaleup to meet electric propulsion mission requirements

International Nuclear Information System (INIS)

Newkirk, D.W.; Salamah, S.A.; Stewart, S.L.; Pluta, P.R.

1991-01-01

The SP-100 space power nuclear reactor nuclear heat source technology, utilizing uranium nitride fuel clad in PWC-11 in a fast reactor with lithium coolant circulated by an electromagnetic pump, is shown in this paper to be directly extrapolatable to thermal power levels that meet NASA nuclear electric propulsion requirements using different power conversion techniques. The SP-100 nuclear technology can be applied for missions with NEP requirements as low as 10's of kWe to 10's of MWe

A comparative study of the oxidation characteristics of two gasoline fuels and an n-heptane/iso-octane surrogate mixture

KAUST Repository

Javed, Tamour