Lethal and Sublethal Effects of Mineral Oil on Potato Pests.

Science.gov (United States)

Galimberti, Andrew; Alyokhin, Andrei

2018-05-28

Mineral oil is a product used to reduce Potato Virus Y transmission in potato fields. However, there is little information available about other effects that oil may have on insect pests of potato. To better understand how mineral oil affects potato pests, we performed a series of experiments testing the effects of oil on mortality, behavior, and development of potato aphids, Macrosiphum euphorbiae (Thomas) (Hemiptera: Aphididae), green peach aphids, Myzus persicae (Sulzer) (Hemiptera: Aphididae), and Colorado potato beetles, Leptinotarsa decemlineata (Say) (Coleoptera: Chrysomelidae). All three species showed negative behavioral responses to oil-treated potato foliage. Oil treatment also increased aphid mortality. Colorado potato beetle mortality was not affected, but developing on oil-treated potato plants resulted in prolonged development and smaller adults. Additionally, oil acted synergistically with the entomopathogenic fungus Beauveria bassiana (Balsamo) Vuillemin (Hypocreales: Clavicipitaceae); Colorado potato beetle larvae were killed more rapidly when sprayed with both products compared with when sprayed with B. bassiana alone. Based on these results, mineral oil has the potential for expanded use in potato IPM programs.

Removal of mineral oil and wastewater pollutants using hard coal

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BRANISLAV R. SIMONOVIĆ

2009-05-01

Full Text Available This study investigates the use of hard coal as an adsorbent for removal of mineral oil from wastewater. In order to determine the efficiency of hard coal as an adsorbent of mineral oil, process parameters such as sorption capacity (in static and dynamic conditions, temperature, pH, contact time, flow rate, and chemical pretreatment were evaluated in a series of batch and continuous flow experiments. There were significant differences in the mineral oil removal for various pH values examined. The adsorption of mineral oil increased as pH values diverged from 7 (neutral. At lower temperatures, the adsorption was notably higher. The wastewater flow rate was adjusted to achieve optimal water purification. Equilibrium was reached after 10 h in static conditions. At that time, more than 99% of mineral oil had been removed. At the beginning of the filtering process, the adsorption rate increased rapidly, only to show a minor decrease afterwards. Equilibrium data were fitted to Freundlich models to determine the water-hard coal partitioning coefficient. Physical adsorption caused by properties of the compounds was the predominant mechanism in the removal process.

Mineral oil barrier sequential polymer treatment for recycled paper products in food packaging

Science.gov (United States)

Paul, Uttam C.; Fragouli, Despina; Bayer, Ilker S.; Mele, Elisa; Conchione, Chiara; Cingolani, Roberto; Moret, Sabrina; Athanassiou, Athanassia

2017-01-01

Recycled cellulosic paperboards may include mineral oils after the recycle process, which together with their poor water resistance limit their use as food packaging materials. In this work, we demonstrate that a proper functionalization of the recycled paper with two successive polymer treatments, imposes a mineral oil migration barrier and simultaneously renders it waterproof and grease resistant, making it an ideal material for food contact. The first poly (methyl methacrylate) treatment penetrates the paper network and creates a protective layer around every fiber, permitting thus the transformation of the paperboard to a hydrophobic material throughout its thickness, reducing at the same time the mineral oil migration. Subsequently, the second layer with a cyclic olefin copolymer fills the open pores of the surface, and reduces the mineral oil hydrocarbons migration at levels below those proposed by the BMEL. Online liquid chromatography-gas chromatography coupled with flame ionization detection quantitatively demonstrate that this dual functional treatment prevents the migration of both saturated (mineral oil saturated hydrocarbons) and aromatic hydrocarbon (mineral oil aromatic hydrocarbons) mineral oils from the recycled paperboard to a dry food simulant.

New Method for Shallow and Deep Trap Distribution Analysis in Oil Impregnated Insulation Paper Based on the Space Charge Detrapping

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Jian Hao

2018-01-01

Full Text Available Space charge has close relation with the trap distribution in the insulation material. The phenomenon of charges trapping and detrapping has attracted significant attention in recent years. Space charge and trap parameters are effective parameters for assessing the ageing condition of the insulation material qualitatively. In this paper, a new method for calculating trap distribution based on the double exponential fitting analysis of charge decay process and its application on characterizing the trap distribution of oil impregnated insulation paper was investigated. When compared with the common first order exponential fitting analysis method, the improved dual-level trap method could obtain the energy level range and density of both shallow traps and deep traps, simultaneously. Space charge decay process analysis of the insulation paper immersed with new oil and aged oil shows that the improved trap distribution calculation method can distinguish the physical defects and chemical defects. The trap density shows an increasing trend with the oil ageing, especially for the deep traps mainly related to chemical defects. The greater the energy could be filled by the traps, the larger amount of charges could be trapped, especially under higher electric field strength. The deep trap energy level and trap density could be used to characterize ageing. When one evaluates the ageing condition of oil-paper insulation using trap distribution parameters, the influence of oil performance should not be ignored.

Pressure variation characteristics at trapping region in oil hydraulic piston pumps

International Nuclear Information System (INIS)

Kim, Jong Ki; Jung, Jae Youn; Rho, Byung Joon; Song, Kyu Keun; Oh, Seok Hyung

2003-01-01

Pressure variation is one of the major sources on noise emission in the oil hydraulic piston pumps. Therefore, it is necessary to clarify about pressure variation characteristics of the oil hydraulic piston pumps to reduce noise. Pressure variations in a cylinder at trapping region were measured during pump working period with discharge pressures, rotational speeds. The effect of pre-compression of the discharge port with three types valve plates also investigated. It was found that the pressure variation characteristics of oil hydraulic piston pumps deeply related with pre-compression design of the discharge port. Also, it was found that the pressure overshoot at trapping region can reduce by use of pre-compression at the end of the discharge port in valve plate

The Galeta Oil Spill. II. Unexpected Persistence of Oil Trapped in Mangrove Sediments

Science.gov (United States)

Burns, K. A.; Garrity, S. D.; Jorissen, D.; MacPherson, J.; Stoelting, M.; Tierney, J.; Yelle-Simmons, L.

1994-04-01

Sediment chemistry studies, undertaken as part of the long-term assessment of the Bahía las Minas (Panamá) oil spill, showed the unexpected persistence of the full range of aromatic hydrocarbon residues of the spilled crude oil in anoxic muds of coastal mangroves. Mangrove muds served as long-term reservoirs for chronic contamination of contiguous coastal communities for over 5 years. One result of the repeated history of oil pollution incidents along this coast was an increased proportion of dead mangrove ( Rhizophora mangle) roots in sediment cores which was related to contaminant loading and was detectable for at least 20 years after major oil spills. We suggest that this is the minimum time-scale that is to be expected for the loss of toxicity of oil trapped in muddy coastal habitats impacted by catastrophic oil spills.

Spin trapping studies of essential oils in lipid systems

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Makarova Katerina

2015-07-01

Full Text Available In the present work, we report the results of a spin trapping ESR study of four essential oils widely used for skin care products such as creams and bath salts. The studied essential oils are Rosmarini aetheroleum (rosemary, Menthae piperitae aetheroleum (mint, Lavandulae aetheroleum (lavender, and Thymi aetheroleum (thyme. Fenton reaction in the presence of ethanol was used to generate free radicals. The N-tert-butyl-α-phenylnitrone (PBN was used as a spin trap. In the Fenton reaction, the rosemary oil had the lowest effect on radical adduct formation as compared to the reference Fenton system. Since essential oils are known to be lipid soluble, we also conducted studies of essential oils in Fenton reaction in the presence of lipids. Two model lipids were used, namely 1,2-dioleoyl-sn-glycero-3-phosphocholine (DOPC and 1,2-dipalmitoyl-sn-glycero-3-phosphocholine (DPPC. The obtained results suggested that in the presence of DOPC lipids, the •OH and PBN/•CHCH3(OH radicals are formed in both phases, that is, water and lipids, and all the studied essential oils affected the Fenton reaction in a similar way. Whereas, in the DPPC system, the additional type of PBN/X (aN = 16.1 G, aH = 2.9 G radical adduct was generated. DFT calculations of hyperfine splittings were performed at B3LYP/6-311+G(d,p/EPR-II level of theory for the set of c-centered PBN adducts in order to identify PBN/X radical.

A Comparative Experimental Analysis of Tribological Properties Between Commercial Mineral Oil and Neat Castor Oil using Taguchi Method in Boundary Lubrication Regime

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S. Bhaumik

2016-03-01

Full Text Available The present work aims to carry out a comparative experimental analysis of tribological properties of 372cSt mineral oil and 229cSt castor oil. The antiwear and extreme pressure properties of both the oils have been analysed according to ASTM G 99 and ASTM D-2783 standards. The surfaces of the balls and pins after tribo tests have been analysed using Scanning Electron Microscope (SEM images. The present test results predict that the antiwear and extreme pressure properties in case of the selected commercially available mineral oil are better than neat castor oil. Both coefficient of friction and frictional force increased by 16-42 % and 16-35 % respectively in case of neat castor oil as compared with that of the mineral oil. The load carrying capacity in case of mineral oil has been found to be 250 kg while in case of castor oil it has been found to be 126 kg. SEM images show a higher plastic deformation in case of castor oil as compared to the mineral oil. Both mineral oil and castor oil showed surface deteriorations and increase in roughness after 40 hrs of intermittent running during scuffing test. Thus, the present investigation indicates that the tribological properties of neat castor are inferior to that of mineral oil although close observation of the results shows that both AW and EP properties of neat castor oil are much closer to that of commercial mineral oil. Thus, the present work would help in formulating castor oil based new bio lubricants with better anti wear and extreme pressure properties

Method for the production of solid hydroxides contained in mineral oils, mineral oil-like materials or mineral oil-containing materials and uses of products thus obtained. Verfahren zur Herstellung von Mineraloele, mineraloelaehnliche Stoffe oder mineraloelhaltige Stoffe enthaltenden festen Hydroxiden sowie die Verwendung danach erhaltener Produkte

Energy Technology Data Exchange (ETDEWEB)

Boelsing, F

1975-07-29

A method has been developed which permits mineral oils, mineral oil-like substances or mineral oil-containing substances (eg waste oil) to be separated in powder form, even when these substance are present in a continuous phase with water (for example, oil slurries). A compound (eg. line) which forms a hydroxide with water is added, the formed hydroxide then acts as carrier substance. Prerequisite for obtaining the end-product in powdered form is that the homogeneous mixing of the oil-containing substance and hydroxide-forming substance takes place at a faster rate than the necessary auxilliary reaction, namely hydroxide formation, and further that water in present in at least stoichiometric quantities. The powdered end-product finds numerous applications eg. road construction, soil conditioning and compacting, recultivation measures in cement manufacture, and others.

Method of removing paraffin from mineral oils, shale oils, tar oils, and their fractions or residues

Energy Technology Data Exchange (ETDEWEB)

Palmquist, F T.E.

1949-09-08

A method is described for removing paraffin from mineral oils, shale oils, tar oils, and their fractions or residues by centrifuging in the presence of oil-dissolving and paraffin-precipitating solvents, by which the precipitated paraffin is made to pass through an indifferent auxiliary liquid, in which a removal of oil takes place, characterized in that as auxiliary liquid is used a liquid or mixture of liquids whose surface tension against the oil solution is sufficiently low for the paraffin to pass the layer of auxiliary liquid in the form of separate crystals.

Mineral content of insect infested stored legumes treated with edible oils.

Science.gov (United States)

Modgil, R

2000-12-01

Mineral content of three insect (pulse beetle, Callosobruchus chinensis L.) infested legumes viz. chick pea, mung pea and pigeon pea stored for six months and treated with three edible oils viz. groundnut, mustard and coconut oil has been studied. With increase in storage period significant increase in calcium, phosphorus and iron content of untreated legumes was observed. After three months of storage slight increase in three minerals was observed in the legumes treated with coconut oil which continued till the end of sixth months as compared to other two oil treated counterparts. The storage period was associated with insect infestation which in turn influenced the mineral content of legumes. Ground nut and mustard oils were able to protect legumes for six months against insect infestation when applied in small amounts (0.5%). Whereas coconut oil had protective effect against insect infestation for four months only.

Aspiration pneumonia of mineral oil: a case report

International Nuclear Information System (INIS)

Malheiros, Noemia Reis; Costa Praxedes, Marcia da; Machado, Dianne Mello; Marchiori, Edson

1995-01-01

The authors report a case of 14 month-old boy with clinical features of dyspnea, cough and acrocyanosis following aspiration of mineral oil used in the treatment of partial small bowel obstruction by Ascaris lumbricoides. A chest roentgenogram was reported as extensive bilateral confluent consolidation that showed progressive improvement and the presence of a bilateral infiltration. The diagnosis of aspiration pneumonia of mineral oil was confirmed by lung biopsy. Radiological and anatomo pathological aspects are presented as well as a review of the medical literature about the case. (author). 6 refs., 3 figs

The Galeta oil spill: Pt. 2; Unexpected persistence of oil trapped in mangrove sediments

Energy Technology Data Exchange (ETDEWEB)

Burns, K.A.; Jorissen, D.; MacPherson, J.; Stoelting, M.; Tierney, J.; Yelle-Simmons, L. (Bermuda Biological Station, Ferry Reach (Bermuda)); Garrity, S.D. (Coastal Zone Analysis, Sopchoppy, FL (United States))

1994-04-01

Sediment chemistry studies, undertaken as part of the long-term assessment of the Bahia las Minas (Panama) oil spill, showed the unexpected persistence of the full range of aromatic hydrocarbon residues of the spilled crude oil in anoxic muds of coastal mangroves. Mangrove muds served as long-term reservoirs for chronic contamination of contiguous coastal communities for over 5 years. One result of the repeated history of oil pollution incidents along this coast was an increased proportion of dead mangrove (Rhizophora mangle) roots in sediment cores which was related to contaminant loading and was detectable for at least 20 years after major oil spills. We suggest that this is the minimum time-scale that is to be expected for the loss of toxicity of oil trapped in muddy coastal habitats impacted by catastrophic oil spills. (author)

Ex situ bioremediation of mineral oil in soils: Aerated pile treatment. Final report

International Nuclear Information System (INIS)

Graves, D.

1998-04-01

Under a contract with Southern Company Services, a pilot-scale evaluation of mineral oil biodegradation was conducted at Plant Mitchell. The evaluation consisted of two demonstrations to examine land treatment and aerated pile treatment of soil contaminated with the mineral insulating oil used in electrical transformers. Treatment of mineral oil contaminated soil is problematic in the State of Georgia and throughout the US because current practice is to excavate and landfill the contaminated soil. In many cases, the cost associated with these activities far exceeds the environmental risk of mineral oil in soil. This project was designed to evaluate the performance of bioremediation for the treatment of mineral oil in soil. Testing was carried out in a demonstration facility prepared by Georgia Power Company. The facility consisted of 12 independent treatment cells constructed on a concrete pad and covered with a roof

Refining of the cracked products of mineral oils, etc

Energy Technology Data Exchange (ETDEWEB)

Seelig, S

1928-06-02

A process is disclosed for the refining of the distilled or cracked products from mineral oil, shale oil, or brown-coal-tar oil, with the aid of alkali-plumbite solution, characterized by adding to the plumbite solution from oxide, iron hydroxide, basic oxide, or an iron salt.

Effects of Mineral Oils on Host Selection Behavior of Diaphorina citri

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Mofit Eko Poerwanto

2008-07-01

Full Text Available Response of Diaphorina citri Kuwayama (Hemiptera: Psyllidae on citrus leaves treated with horticultural and agricultural mineral oil (HMO & AMO was evaluated under laboratory condition in choice and non-choice trials. Combination of HMO and AMO at concentration of 0 up to 2% was applied to citrus leaves. Mineral oil applications significantly reduced the proportion of D. citri stayed on citrus leaves for feeding with the proposed mechanisms: 1 oils covered leaves thus hampered it for releasing volatile compounds, 2 oil film preventing the direct contact of tarsus or palpus to leaf surfaces, and 3 the volatile compounds produced by mineral oils also blended with plant volatiles in the atmosphere and reduced the probability of olfactory receptors capturing the olfactory cues for locating the feeding site. Mineral oils also increased the mortality of D. citri due to the refusion for feeding on the treated citrus leaves. The effect of AMO was more prominent than HMO.   Tanggapan Diaphorina citri Kuwayama (Hemiptera: Psyllidae pada daun jeruk yang diperlakukan dengan minyak mineral (HMO dan AMO dievaluasi dengan metode pilihan maupun tanpa pilihan di laboratorium. Kombinasi antara HMO dan AMO pada konsentrasi 0% sampai dengan 2% diaplikasikan pada daun jeruk. Minyak mineral secara nyata menurunkan proporsi D. citri hinggap untuk makan pada daun jeruk, yang mungkin disebabkan oleh mekanisme: 1 minyak melapisi daun sehingga tidak mampu melepaskan senyawa volatil, 2 lapisan minyak menghalangi kontak langsung antara tarsus atau palpus pada permukaan daun, dan 3 senyawa volatil dari minyak bercampur dengan volatil tanaman di udara sehingga menurunkan probabilitas reseptor olfaktori menangkap sinyal penanda lokasi inang. Minyak mineral juga meningkatkan mortalitas, akibat dari penolakan makan pada daun jeruk yang diperlakukan. Pengaruh AMO lebih besar dari pada HMO.

Chemical changes of minerals trapped in the lichen Trapelia involuta. Implication for lichen effect on mobility of uranium and toxic metals

International Nuclear Information System (INIS)

Kasama, Takeshi; Murakami, Takashi; Ohnuki, Toshihiko

2002-01-01

To elucidate development of minerals trapped in a lichen, we examined the lichen Trapelia involuta growing directly on secondary uranyl minerals and U-enriched Fe oxide and hydroxide minerals. Sericite and other minerals in the underlying rock are trapped in the lichen T. involuta during its biological growth and chemically changed by lichen activities. The presence of chemically changed sericite accompanied by an Fe-bearing mineral in the lichen suggests that dissolution of sericite is promoted mainly by polysaccharides excreted by the lichen. Oxalic acid or lichen acids absent in the medulla may not play an important role in the dissolution. Our results suggest that lichens on metal-rich surface affect the mobility of uranium and other toxic metals through dissolution followed by trap of minerals from the underlying rock. (author)

Studies about mineral oils maintenance in NPP

International Nuclear Information System (INIS)

Ceclan, R.E.; Floarea, O.; Ceclan, M.; Bercia, R.

1997-01-01

The maintenance of mineral oils, used as lubricating agent or insulating fluids is a very important problem for the reducing of operating costs in the Nuclear Power Plants. Their maintenance means the maintaining of their solid particles and water content between the allowed limits given by the international standards. A modern dehydration technology is the film desorption of water from mineral oils. The paper presents a mathematical model of the falling film dehydration process of mineral oils in a cylindrical film desorber. The model's equations were solved numerically using a FORTRAN programme made by the authors. The model allows the determination of water concentration radial and longitudinal profiles in the oil film. The simulation results are compared with the experimental results obtained by the authors on their own laboratory experimental plant and the good agreement found validated the mathematical model. The model was solved using a fully implicit numerical scheme, in which the longitudinal convection terms were approximated by the upstream difference and the transverse diffusion terms by the central difference to transform the governing equations into finite-difference equations. The finite-difference system obtained is an algebraic system with a tridiagonal matrix that can be efficiently solved by the Thomas algorithm. To account for the drastic variations of velocity and concentration in the regions near the inner boundary and interface, a nonuniform spatial grid in the r-direction was chosen. A grid with 401 gridpoints was used in the computations.The model allows the determination of water concentration radial and longitudinal profiles in the oil film. The simulation results are compared with the experimental results obtained by the authors on their own laboratory experimental plant and the good agreement found validated the mathematical model. (authors)

Interaction of oil and mineral fines on shorelines: review and assessment

International Nuclear Information System (INIS)

Owens, Edward H.; Lee, Kenneth

2003-01-01

The interaction of fine mineral particles with stranded oil in an aqueous medium reduces the adhesion of the oil to solid surfaces, such as sediments or bedrock. The net result is the formation of stable, micron-sized, oil droplets that disperse into the water column. In turn, the increase in surface area makes the oil more available for biodegradation. This interaction, referred to as oil-mineral aggregate (OMA) formation, can explain how oiled shorelines are cleaned naturally in the absence of wave action in very sheltered coastal environments. OMA formation also plays an important role in the efficacy of shoreline treatment techniques, such as physical mixing and sediment relocation that move oiled sediments into the zone of wave action to promote the interaction between oil and mineral fines. Successful application of these shoreline treatment options has been demonstrated at two spill events (the Tampa Bay response in Florida and the Sea Empress operation in Wales) and at a controlled oil spill experiment in the field (the 1997 Svalbard ITOSS program). Sediment relocation harnesses the hydraulic action of waves so that the processes of fine-particle interaction and physical abrasion usually occur in tandem on open coasts. There has been no evidence of significant detrimental side-effects of residual oil in pelagic or benthic environments associated with the use of these treatment options to enhance rates of dispersion and oil biodegradation

Interaction of oil and mineral fines on shorelines: review and assessment

Energy Technology Data Exchange (ETDEWEB)

Owens, Edward H.; Lee, Kenneth

2003-12-01

The interaction of fine mineral particles with stranded oil in an aqueous medium reduces the adhesion of the oil to solid surfaces, such as sediments or bedrock. The net result is the formation of stable, micron-sized, oil droplets that disperse into the water column. In turn, the increase in surface area makes the oil more available for biodegradation. This interaction, referred to as oil-mineral aggregate (OMA) formation, can explain how oiled shorelines are cleaned naturally in the absence of wave action in very sheltered coastal environments. OMA formation also plays an important role in the efficacy of shoreline treatment techniques, such as physical mixing and sediment relocation that move oiled sediments into the zone of wave action to promote the interaction between oil and mineral fines. Successful application of these shoreline treatment options has been demonstrated at two spill events (the Tampa Bay response in Florida and the Sea Empress operation in Wales) and at a controlled oil spill experiment in the field (the 1997 Svalbard ITOSS program). Sediment relocation harnesses the hydraulic action of waves so that the processes of fine-particle interaction and physical abrasion usually occur in tandem on open coasts. There has been no evidence of significant detrimental side-effects of residual oil in pelagic or benthic environments associated with the use of these treatment options to enhance rates of dispersion and oil biodegradation.

Separating cresote from tars, mineral oils, etc

Energy Technology Data Exchange (ETDEWEB)

Erdmann, E

1921-01-07

Phenolic bodies are extracted from tars such as lignite, shale, peat, coal, producer and low temperature tars, and from tar distillates and residues and from mineral oils and distillates by washing with a mixture of acetone and water. Acetone extracts of the tars etc., may be mixed with water or aqueous acetone to cause the separation of the oils, while the creosote remains in solution.

DEEP HANGING WALL TRAPS-THE REMAINING PROMISSING TARGETS FOR OIL EXPLORATION IN THE NIGER DELTA

International Nuclear Information System (INIS)

Oton, S.W

2004-01-01

It is well known that the most dominant types of Hydrocarbon types found in the petroliferous Niger Delta are the classical rollover anticlinical traps 'I of oil exploration in the delta, these easy-to-find rollover structures are getting exhausted. They are most numerous at shallow depths in the younger delta front sedimentary sequence. Generally, during this primary oil exploration stage, oil and gas exploration have been concentrated in the shallow depths where they are easy to reach, easy to explore and easy to produce. This means that the present and future exploration campaigns in the Niger Delta should be directed towards other types of hydrocarbon trapping mechanisms that have been mapped in the delta. Many exploration models have been used and oil has been found in at least nine types of traps in the Niger Delta. The contrary (or anitithetic) fault model was used at the close of the last century. This model is so called because the controlling antithetic fault has a regional dip contrary to the structure-building growth fault with which it is associated. These faults, which are widespread in the Niger Delta, are easy to map especially on the Petro geological model. In this period, several promising hydrocarbon accumulations trapped against antithetic faults were discovered and tested. These hydrocarbon targets also seem fully explored and exhausted now. Recently, from modern high resolution 2-D and 3-D seismic data a lot of good prospects have been mapped and drilled in the deep horizon. In the last few years, a lot of unexplored oil have been discovered and tested in the deep horizons. They are mostly in hanging wall traps, at depth below 4,000 meters. This shows that most of the remaining undiscovered hydrocarbons in the Niger Delta may well be in these deep hanging wall traps between 4,000 and close to 5,600 meters. A definite search for deep-seated hanging wall traps is therefore recommended in a bid to find more new reservoirs and thereby increase the

Mineral oil metal working fluids (MWFs)-development of practical criteria for mist sampling.

Science.gov (United States)

Simpson, A T; Groves, J A; Unwin, J; Piney, M

2000-05-01

Not all mineral oil metalworking fluids (MWFs) in common use form stable airborne mists which can be sampled quantitatively onto a filter. This much has been known for some time but no simple method of identifying oils too volatile for customary filter sampling has been developed. Past work was reviewed and experiments were done to select simple criteria which would enable such oils to be identified. The sampling efficiency for a range of commercial mineral oil MWF were assessed by drawing clean air through spiked filters at 2 l. min(-1) for periods up to 6 h before analysis. The physical properties of MWF are governed by their composition and kinematic viscosity was found to be the most practical and easily available index of the potential for sample loss from the filter. Oils with viscosities greater that 18 cSt (at 40 degrees C) lost less than 5% of their weight, whereas those with viscosities less than 18 cSt gave losses up to 71%. The losses from the MWF were mostly aliphatic hydrocarbons (C(10)-C(18)), but additives such as alkyl benzenes, esters, phenols and terpene odorants were also lost. The main recommendation to arise from the work is that filter sampling can be performed on mineral oils with viscosities of 18 cSt (at 40 degrees C) or more with little evaporative losses from the filter. However, sampling oils with viscosities less than 18 cSt will produce results which may significantly underestimate the true value. Over a quarter of UK mineral oil MWFs are formulated from mineral oils with viscosities less than 18 cSt (at 40 degrees C). The problem of exposure under-estimation and inappropriate exposure sampling could be widespread. Further work is being done on measurement of mixed phase mineral oil mist exposure.

Evaluation of mineral oil saturated hydrocarbons (MOSH and mineral oil aromatic hydrocarbons (MOAH in pure mineral hydrocarbon-based cosmetics and cosmetic raw materials using 1H NMR spectroscopy [version 2; referees: 3 approved

Directory of Open Access Journals (Sweden)

Dirk W. Lachenmeier

2017-08-01

Full Text Available Mineral hydrocarbons consist of two fractions, mineral oil saturated hydrocarbons (MOSH and mineral oil aromatic hydrocarbons (MOAH. MOAH is a potential public health hazard because it may include carcinogenic polycyclic compounds. In the present study, 400 MHz nuclear magnetic resonance (NMR spectroscopy was introduced, in the context of official controls, to measure MOSH and MOAH in raw materials or pure mineral hydrocarbon final products (cosmetics and medicinal products. Quantitative determination (qNMR has been established using the ERETIC methodology (electronic reference to access in vivo concentrations based on the PULCON principle (pulse length based concentration determination. Various mineral hydrocarbons (e.g., white oils, paraffins or petroleum jelly were dissolved in deuterated chloroform. The ERETIC factor was established using a quantification reference sample containing ethylbenzene and tetrachloronitrobenzene. The following spectral regions were integrated: MOSH δ 3.0 – 0.2 ppm and MOAH δ 9.2 - 6.5, excluding solvent signals. Validation showed a sufficient precision of the method with a coefficient of variation <6% and a limit of detection <0.1 g/100 g. The applicability of the method was proven by analysing 27 authentic samples with MOSH and MOAH contents in the range of 90-109 g/100 g and 0.02-1.10 g/100 g, respectively. It is important to distinguish this new NMR-approach from the hyphenated liquid chromatography-gas chromatography methodology previously used to characterize MOSH/MOAH amounts in cosmetic products. For mineral hydrocarbon raw materials or pure mineral hydrocarbon-based cosmetic products, NMR delivers higher specificity without any sample preparation besides dilution. Our sample survey shows that previous methods may have overestimated the MOAH amount in mineral oil products and opens new paths to characterize this fraction. Therefore, the developed method can be applied for routine monitoring of consumer

Method of refining mineral and shale oils, etc

Energy Technology Data Exchange (ETDEWEB)

1950-12-06

A method is described for refining mineral oils, shale oils, tar oil. The oil is preferably treated with concentrated sulphuric acid, of not less than 90% by weight concentration or with chloro-sulphonic acid in order to extract the more reactive components of the oil. The solution (extract phase) is separated from the treated oil (raffinate phase) by centrifuging, characterised by centrifugally separating the extract phase from the raffinate phase before any noticeable chemical reaction with subsequent solution of acid reaction products in the raffinate phase has taken place. The acid remaining in the raffinate phase is allowed to react chemically with the more reactive constituents. The sludge formed is removed from the raffinate phase by centrifuging.

Corrosion protection performance of palm and mineral oil media

International Nuclear Information System (INIS)

Wan Nik Sani, W.B.; Ani, F.N.; Masjuki, H.H.

2002-01-01

In European forest, especially Scandinavian, almost all forest machines are filled with biodegradable fluid. The fluid is of synthetic type. The ratio between the lowest cost of mineral oil and the synthetic fluid is about 1:4. The high cost of this biodegradable fluid can be a major obstacle to be used in developing countries. Malaysia and South East Asia are known for its natural beauties. However, a spill of mineral based oils to their land and seas may result in long term water and soil contamination. Thus crop or agricultural based oil product can provide the solution to this problem. However, considering the demand placed on the oil in service, the service performance such as relation to component compatibility with the crop based oil is crucial to be investigated. The ability of crop based oils to protect and reduce corrosion formation is still unexplored. It is important for each oil to preserve its oxidation stability and remain non-corrosive during service. This paper reports the results of copper corrosion tests. The test includes mass change monitoring, oxide scales and microscopic analysis using Scanning Electron Microscope (SEM). Relative Increase of total acid number and weight loss during copper immersion has proved that metal corrosion in contact with oil was caused by oil degradation that produces acidic compounds. Coppers that were immersed in oil temperature of 60 0 C show that increase of temperature in presence of transition metal induces oil degradation. (Author)

The surface-active bio oil solution in sulfured copper mineral benefit

Directory of Open Access Journals (Sweden)

L.E. Brossard

2005-03-01

Full Text Available Surface-active bio-oil (SABO solutions, prepared from vacuum pyrolysis bio-oil with a phenol-to-levoglucosan mass ratio of 4.8, was compared to pine-oil (PO as foaming agent in the process of flotation of sulfured copper minerals. With the aid of 2³ factorial designs, regression models were obtained for % Cu in flotation concentrate (L Cu and % Cu recovery (R, as functions of foaming agent-to-Cu mineral, collector-to-Cu mineral mass ratio and liquid-to-solid ratio (v/w. Experimental designs composed of a saturated design in its first half and a fold over design in its second half allowed to study the influence of flotation conditions on L Cu and R when SABO was the foaming agent. The factors selected were: particle size; pulp pH; flotation time; initial Cu content in the mineral (mineral type; liquid-to-solid ratio and finally SABO-to-mineral and collector-to-mineral mass ratio. Within the chosen experimental region only pulp pH affected significantly both responses. It is shown that high pulp pH, in the presence of minerals rich in Cu content leads to a significant increase in L Cu and R. Although SABO to mineral mass ratio is high compared to PO, it is considered that an optimization study on pulp pH should reduce this difference making SABO an attractive alternative to PO and a way to widen the field of applications of pyrolysis products.

How much CO2 is trapped in carbonate minerals of a natural CO2 occurrence?

Science.gov (United States)

Király, Csilla; Szabó, Zsuzsanna; Szamosfalvi, Ágnes; Cseresznyés, Dóra; Király, Edit; Szabó, Csaba; Falus, György

2017-04-01

Carbon Capture and Storage (CCS) is a transitional technology to decrease CO2 emissions from human fossil fuel usage and, therefore, to mitigate climate change. The most important criteria of a CO2 geological storage reservoir is that it must hold the injected CO2 for geological time scales without its significant seepage. The injected CO2 undergoes physical and chemical reactions in the reservoir rocks such as structural-stratigraphic, residual, dissolution or mineral trapping mechanisms. Among these, the safest is the mineral trapping, when carbonate minerals such as calcite, ankerite, siderite, dolomite and dawsonite build the CO2 into their crystal structures. The study of natural CO2 occurrences may help to understand the processes in CO2 reservoirs on geological time scales. This is the reason why the selected, the Mihályi-Répcelak natural CO2 occurrence as our research area, which is able to provide particular and highly significant information for the future of CO2 storage. The area is one of the best known CO2 fields in Central Europe. The main aim of this study is to estimate the amount of CO2 trapped in the mineral phase at Mihályi-Répcelak CO2 reservoirs. For gaining the suitable data, we apply petrographic, major and trace element (microprobe and LA-ICP-MS) and stable isotope analysis (mass spectrometry) and thermodynamic and kinetic geochemical models coded in PHREEQC. Rock and pore water compositions of the same formation, representing the pre-CO2 flooding stages of the Mihályi-Répcelak natural CO2 reservoirs are used in the models. Kinetic rate parameters are derived from the USGS report of Palandri and Kharaka (2004). The results of petrographic analysis show that a significant amount of dawsonite (NaAlCO3(OH)2, max. 16 m/m%) precipitated in the rock due to its reactions with CO2 which flooded the reservoir. This carbonate mineral alone traps about 10-30 kg/m3 of the reservoir rock from the CO2 at Mihályi-Répcelak area, which is an

Mineral oils, tars. [British patent

Energy Technology Data Exchange (ETDEWEB)

O' Brien, A M; Handmarch, E

1933-08-11

Hydrocarbon materials such as mineral oils and tars from coal, shale, lignite, or peat are freed from phenols and like oxy-bodies by heating under pressure in a closed vessel to a temperature and for a time sufficient to effect reduction of the oxy-bodies, and then removing the water formed by the reaction. 350/sup 0/ to 400/sup 0/C. for 30 to 60 minutes is suitable. Any wax-like constituents are converted to liquids of lower viscosity and settling point. The product may be fractionated to give light oils and a residue of aviation Diesel fuel. In an example, oil from the low-temperature distillation of coal and having a tar acid content of 30 per cent is treated in a tubular converter at 380/sup 0/C. and 400 lb. per sq. in for 40 min., and the benzine toluol, and xylol distilled; the residue has a tar acid content of only 7.6 per cent.

Response ofMeteorus leviventris, (Hymenoptera: Braconidae) to mustard oils in field trapping experiments.

Science.gov (United States)

Pivnick, K A

1993-09-01

Trapping experiments were carried out near Saskatoon, Canada, from May through August 1990 to assess the response of the braconid wasp,Meteorus leviventris, to four selected mustard oils or isothiocyanates (IC) at a release rate of 4 mg/day, and for allyl IC only, at 40 mg/day. Only allyl IC at 4 mg/day was significantly attractive when trap captures were compared to the captures in the control traps. The others (n-propyl IC, 2-phenylethyl IC., and ethyl IC) were not attractive, nor was allyl IC at the higher dose, although trap captures with the latter bait were the second highest.

A Novel Approach for Analyzing Water Diffusion in Mineral and Vegetable Oil-Paper Insulation

Directory of Open Access Journals (Sweden)

Bin Du

2014-04-01

Full Text Available Water diffusion characteristics of mineral and vegetable oil-paper insulation systems are important for insulation condition evaluation of oil-filled transformers. In this paper, we describe a novel application method of in situ attenuated total reflection Fourier transform infrared (ATR-FTIR approach for analyzing the diffusion process of water molecules in oil-immersed insulating paper. Two-dimensional correlation was used to analyze the 3700 cm-1 to 3000 cm- 1 hydroxyl peak. The observed results indicated that water molecules form two types of hydroxyl (OH with oil-impregnated paper in the diffusion process are weak and strong hydrogen bonds, respectively. 2D infrared correlation analysis revealed that three OH stretching vibration spectra absorption peaks was existed in hygroscopic vegetable oil-immersed insulating paper. And there are four OH stretching vibration spectra absorption peaks in mineral oil-immersed insulation paper. Furthermore, mineral oil-impregnated paper and vegetable oil-impregnated paper diffusion coefficients were obtained by nonlinear fitting.

Mineral and surface issues in oil and gas operations

International Nuclear Information System (INIS)

Vasseur, P.F.

1998-01-01

The Farmers' Advocate Office was created in 1972 to help put Alberta mineral owners on an equal footing with the energy sector. Most mineral owners are at a disadvantage when dealing with the disposition of their minerals because they have little or no knowledge of what they own or what their surface rights are. This paper addresses key features of mineral leasing arrangements in Alberta and explains their potential impact. It also brings to the mineral owner's attention some specific problems and concerns including mineral rights, the lease agreement, signing considerations, length of leases, delayed production payment, drilling rental, royalties, and gas cost allowance. Issues regarding oil and gas production including shut-in wells, off-set clauses , drilling depth, taxes and prepayment for minerals are also discussed from the perspective of a mineral owner

Experimental Investigation of the Use of Waste Mineral Oils as a Fuel with Organic-Based Mn Additive

Directory of Open Access Journals (Sweden)

Bülent Özdalyan

2018-06-01

Full Text Available The heat values of waste mineral oils are equal to the heat value of the fuel oil. However, heat value alone is not sufficient for the use of waste minerals oils as fuel. However, the critical physical properties of fuels such as density and viscosity need to be adapted to the system in order to be used. In this study, the engine oils used in the first 10,000 km of the vehicles were used as waste mineral oil. An organic-based Mn additive was synthesized to improve the properties of the waste mineral oil. It was observed that mixing the Mn additive with the waste mineral oil at different doses (4, 8, 12, and 16 ppm improves the viscosity of the waste oil and the flash point. The resulting fuel was evaluated for emission using different loads in a 5 kW capacity generator to compare the fuel with standard diesel fuel and to determine the effect of Mn addition. In the experimental study, it was observed that the emission characteristics of the fuel obtained from waste mineral oil were worse than diesel fuel, but some improvement was observed with Mn addition. As a result, we found that the use of waste mineral oils in engines in fuel standards was not appropriate, but may be improved with additives.

Improvement of mineral oil saturated and aromatic hydrocarbons determination in edible oil by liquid-liquid-gas chromatography with dual detection.

Science.gov (United States)

Zoccali, Mariosimone; Barp, Laura; Beccaria, Marco; Sciarrone, Danilo; Purcaro, Giorgia; Mondello, Luigi

2016-02-01

Mineral oils, which are mainly composed of saturated hydrocarbons and aromatic hydrocarbons, are widespread food contaminants. Liquid chromatography coupled to gas chromatography with flame ionization detection represents the method of choice to determine these two families. However, despite the high selectivity of this technique, the presence of olefins (particularly squalene and its isomers) in some samples as in olive oils, does not allow the correct quantification of the mineral oil aromatic hydrocarbons fraction, requiring additional off-line tools to eliminate them. In the present research, a novel on-line liquid chromatography coupled to gas chromatography method is described for the determination of hydrocarbon contamination in edible oils. Two different liquid chromatography columns, namely a silica one (to retain the bulk of the matrix) and a silver-ion one (which better retains the olefins), were coupled in series to obtain the mineral oil aromatic hydrocarbons hump free of interfering peaks. Furthermore, the use of a simultaneous dual detection, flame ionization detector and triple quadrupole mass spectrometer allowed us not only to quantify the mineral oil contamination, but also to evaluate the presence of specific markers (i.e. hopanes) to confirm the petrogenic origin of the contamination. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

The effect of used engine oil on carbohydrate, mineral content and ...

African Journals Online (AJOL)

MICHAEL

reductase activity in plants that were exposed to engine oil. Therefore ... change oil from motor vehicles and power generating machines. ... The availability of essential mineral element is ... representing each treatment and this was replicated.

Encapsulated Essential Oils as an Alternative to Insecticides in Funnel Traps.

Science.gov (United States)

Pascual-Villalobos, M J; López, M D; Castañé, C; Soler, A; Riudavets, J

2015-08-01

Pheromone-lured funnel traps are widely used for pest monitoring and mass trapping in agricultural fields and stores. DDVP vapona (dichlorvos), the insecticide of choice as a killing agent inside traps, has been banned, and research on new products is being pursued. Essential oils (EO) could be an alternative if properly formulated. To test their potential, beads of encapsulated coriander and basil EO were tested in funnel traps in stores of almonds and pet foods during 2 mo. The number of adult moth (Plodia interpunctella (Hübner) and Ephestia kuehniella Zeller) dead captures was similar with either coriander or basil EO beads and with vapona tablets while there were more insects alive in the control. These preliminary results indicate a good potential for the development of such natural products as an alternative to synthetic insecticides to include them inside funnel traps. © The Authors 2015. Published by Oxford University Press on behalf of Entomological Society of America. All rights reserved. For Permissions, please email: journals.permissions@oup.com.

21 CFR 172.878 - White mineral oil.

Science.gov (United States)

2010-04-01

... yeast contamination during fermentation In an amount not to exceed good manufacturing practice. 4. As a... 21 Food and Drugs 3 2010-04-01 2009-04-01 true White mineral oil. 172.878 Section 172.878 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) FOOD FOR HUMAN...

AFM annual report 1983 (Petroleum Industry). [Export Federation for Mineral Oil, Federal Republic of Germany]. AFM Jahresbericht 1983

Energy Technology Data Exchange (ETDEWEB)

1983-01-01

The annual report 1983 of the Export Federation for Mineral Oil (AFM) contains informations about the mineral oil economics, the market development for selected main products and the environmental protection. The AFM terms (standard conditions for barge transactions) for the mineral oil industry are given. The AFM Oil Market Report Daily has extended the frame of its reports in 1983.

Research of losses of oil oil and mineral oil at transportation and storage

International Nuclear Information System (INIS)

Akzhigitov, A.S.

2005-01-01

Full text : All way of hydrocarbonic raw material from a mouth of oil wells up to the consumer is accompanied by losses which occur as a result of evaporation, outflow and change of quality. Therefore preservation of quantity and quality of oil and mineral oil during transportation and storages is the major not only economic, but also an ecological problem. The facilitated fractional structure, the big maintenance concern to prominent features of the majority oil from underground salts adjournment Prycaspi in them of the easy hydrocarbons, the raised gas factor in conditions of deposits and presence in structure of gases, except for hydrocarbons and sour a component, - hydrogen sulphide, carbonic gas, etc. The superficial tests stabilized on phase structure oil depending on conditions of preparation for external transport and the subsequent processing can contain this or that quantity of residual hydrogen sulphide, easy hydrocarbons and the lowest sulfhydrates. For change of temperature and external pressure, during transportation and storage the part of easy hydrocarbons and not hydrocarbonic connections (sulfur organic) can be allocated from oil in a gaseous phase and in case of hit in an atmosphere sharply worsens ecology. In the Western Kazakhstan during the years period the temperature of air sometimes reaches up to 40-45 degrees. As is known, at such temperature there is a strengthened warming up of the open surface of oil tanks, that finally leads to increase evaporation easy oil and oil hydrocarbons. With this purpose experiences by quantitative definition evaporation lungs oil and petromixes of the Western Kazakhstan were spent. As a result of the lead works it is found out, that the size of losses at the given fixed temperature depends on evaporation by nature, fractional and hydrocarbonic structures of oil

[Trapping techniques for Solenopsis invicta].

Science.gov (United States)

Liang, Xiao-song; Zhang, Qiang; Zhuang, Yiong-lin; Li, Gui-wen; Ji, Lin-peng; Wang, Jian-guo; Dai, Hua-guo

2007-06-01

A field study was made to investigate the trapping effects of different attractants, traps, and wind directions on Solenopsis invicta. The results showed that among the test attractants, TB1 (50 g fishmeal, 40 g peptone, 10 ml 10% sucrose water solution and 20 ml soybean oil) had the best effect, followed by TB2 (ham), TB6 (100 g cornmeal and 20 ml soybean oil) and TB4 (10 ml 10% sucrose water solution, 100 g sugarcane powder and 20 ml soybean oil), with a mean capture efficiency being 77.6, 58.7, 29 and 7.7 individuals per trap, respectively. No S. invicta was trapped with TB3 (10 ml 10% sucrose water solution, 100 g cornmeal and 20 ml soybean oil) and TB5 (honey). Tube trap was superior to dish trap, with a trapping efficiency of 75.2 and 35 individuals per trap, respectively. The attractants had better effects in leeward than in windward.

Mineral content prediction for unconventional oil and gas reservoirs based on logging data

Science.gov (United States)

Maojin, Tan; Youlong, Zou; Guoyue

2012-09-01

Coal bed methane and shale oil &gas are both important unconventional oil and gas resources, whose reservoirs are typical non-linear with complex and various mineral components, and the logging data interpretation model are difficult to establish for calculate the mineral contents, and the empirical formula cannot be constructed due to various mineral. The radial basis function (RBF) network analysis is a new method developed in recent years; the technique can generate smooth continuous function of several variables to approximate the unknown forward model. Firstly, the basic principles of the RBF is discussed including net construct and base function, and the network training is given in detail the adjacent clustering algorithm specific process. Multi-mineral content for coal bed methane and shale oil &gas, using the RBF interpolation method to achieve a number of well logging data to predict the mineral component contents; then, for coal-bed methane reservoir parameters prediction, the RBF method is used to realized some mineral contents calculation such as ash, volatile matter, carbon content, which achieves a mapping from various logging data to multimineral. To shale gas reservoirs, the RBF method can be used to predict the clay content, quartz content, feldspar content, carbonate content and pyrite content. Various tests in coalbed and gas shale show the method is effective and applicable for mineral component contents prediction

Microbial mineral illization of montmorillonite in low-permeability oil reservoirs for microbial enhanced oil recovery.

Science.gov (United States)

Cui, Kai; Sun, Shanshan; Xiao, Meng; Liu, Tongjing; Xu, Quanshu; Dong, Honghong; Wang, Di; Gong, Yejing; Sha, Te; Hou, Jirui; Zhang, Zhongzhi; Fu, Pengcheng

2018-05-11

Microbial mineral illization has been investigated for its role in the extraction and recovery of metals from ores. Here we report our application of mineral bioillization for the microbial enhanced oil recovery in low-permeability oil reservoirs. It aimed to reveal the etching mechanism of the four Fe (III)-reducing microbial strains under anaerobic growth conditions on the Ca-montmorillonite. The mineralogical characterization of the Ca-montmorillonite was performed by Fourier transform infrared spectroscopy, X-ray powder diffraction, scanning electron microscopy and energy dispersive spectrometer. Results showed that the microbial strains could efficiently reduce Fe (III) at an optimal rate of 71 %, and alter the crystal lattice structure of the lamella to promote the interlayer cation exchange, and to efficiently inhibit the Ca-montmorillonite swelling at an inhibitory rate of 48.9 %. Importance Microbial mineral illization is ubiquitous in the natural environment. Microbes in low-permeability reservoirs are able to enable the alteration of the structure and phase of the Fe-poor minerals by reducing Fe (III) and inhibiting clay swelling which is still poorly studied. This study aimed to reveal the interaction mechanism between Fe (III)-reducing bacterial strains and Ca-montmorillonite under anaerobic atmosphere, and to investigate the extent and rates of Fe (III) reduction and phase changes with their activities. Application of Fe (III)-reducing bacteria will provide a new way to inhibit clay swelling, to elevate reservoir permeability, and to reduce pore throat resistance after water flooding for enhanced oil recovery in low-permeability reservoirs. Copyright © 2018 American Society for Microbiology.

Towards an understanding of the role of clay minerals in crude oil formation, migration and accumulation

Science.gov (United States)

Wu, Lin Mei; Zhou, Chun Hui; Keeling, John; Tong, Dong Shen; Yu, Wei Hua

2012-12-01

This article reviews progress in the understanding of the role of clay minerals in crude oil formation, migration and accumulation. Clay minerals are involved in the formation of kerogen, catalytic cracking of kerogen into petroleum hydrocarbon, the migration of crude oil, and the continued change to hydrocarbon composition in underground petroleum reservoirs. In kerogen formation, clay minerals act as catalysts and sorbents to immobilize organic matter through ligand exchange, hydrophobic interactions and cation bridges by the mechanisms of Maillard reactions, polyphenol theory, selective preservation and sorptive protection. Clay minerals also serve as catalysts in acid-catalyzed cracking of kerogen into petroleum hydrocarbon through Lewis and Brønsted acid sites on the clay surface. The amount and type of clay mineral affect the composition of the petroleum. Brønsted acidity of clay minerals is affected by the presence and state of interlayer water, and displacement of this water is a probable driver in crude oil migration from source rocks. During crude oil migration and accumulation in reservoirs, the composition of petroleum is continually modified by interaction with clay minerals. The clays continue to function as sorbents and catalysts even while they are being transformed by diagenetic processes. The detail of chemical interactions and reaction mechanisms between clay minerals and crude oil formation remains to be fully explained but promises to provide insights with broader application, including catalytic conversion of biomass as a source of sustainable energy into the future.

THE ORGANIZATIONAL-ECONOMIC MECHANISM OF RESTRUCTURING OF THE MARKET OF MINERAL OIL IN REGION

Directory of Open Access Journals (Sweden)

V.I. Efimenkov

2007-12-01

Full Text Available Restructuring, in opinion of the experts, one of the basic ways of steady development of managing subjects in modern conditions. In clause strategy of organizational-economic restructuring of the regional market of mineral oil is considered. Concrete actions of complex restructuring of the market of mineral oil in region and the mechanism of management are resulted by reorganization of the given market.

Mineral oil hydrocarbons in food - a review.

Science.gov (United States)

Grob, Koni

2018-06-12

Work on mineral oil hydrocarbons (MOH) contaminating food is reviewed up to about 2010, when the subject received broad publicity. It covers the period of the main discoveries and elimination or reduction of the dominant sources: release agents used in industrial bakeries, spraying of rice, additions to animal feed, contamination of edible oils from various sources and migration from paperboard packaging. In most cases highly refined ("white") oils were involved, but also technical oils, e.g. from the environment, and more or less crude oil fractions from jute and sisal bags. There were numerous unexpected sources, and there might still be more of those. The exposure of the consumers to MOH must have been markedly reduced in the meantime. Environmental influx may have become dominant, particularly when taking into account that these MOH go through several degradation processes which might enrich the species resisting metabolic elimination. Major gaps are in the systematic investigation of sources and the largely unavoidable levels from environmental contamination, but also in the toxicological evaluation of the various types of hydrocarbons. A regulation is overdue that avoids the present discrepancy between the low tolerance to MOH perceived as contaminants and the very high legal limits for some applications - the MOH are largely the same.

Review of data on the dermal penetration of mineral oils and waxes used in cosmetic applications.

Science.gov (United States)

Petry, T; Bury, D; Fautz, R; Hauser, M; Huber, B; Markowetz, A; Mishra, S; Rettinger, K; Schuh, W; Teichert, T

2017-10-05

Mineral oils and waxes used in cosmetic products, also referred to as "personal care products" outside the European Union, are mixtures of predominantly saturated hydrocarbons consisting of straight-chain, branched and ring structures with carbon chain lengths greater than C16. They are used in skin and lip care cosmetic products due to their excellent skin tolerance as well as their high protecting and cleansing performance and broad viscosity options. Recently, concerns have been raised regarding potential adverse health effects of mineral oils and waxes from dermal application of cosmetics. In order to be able to assess the risk for the consumer the dermal penetration potential of these ingredients has to be evaluated. The scope and objective of this review are to identify and summarize publicly available literature on the dermal penetration of mineral oils and waxes as used in cosmetic products. For this purpose, a comprehensive literature search was conducted. A total of 13 in vivo (human, animal) and in vitro studies investigating the dermal penetration of mineral oils and waxes has been identified and analysed. The majority of the substances were dermally adsorbed to the stratum corneum and only a minor fraction reached deeper skin layers. Overall, there is no evidence from the various studies that mineral oils and waxes are percutaneously absorbed and become systemically available. Thus, given the absence of dermal uptake, mineral oils and waxes as used in cosmetic products do not present a risk to the health of the consumer. Copyright © 2017 The Authors. Published by Elsevier B.V. All rights reserved.

Modernisation of the mineral oil industry in the new Laender

International Nuclear Information System (INIS)

Schlueter, P.

1995-01-01

The structural differences between the energy economies of the two Germanies on the advent of reunification could hardly have been greater. The centralist, planned economy was oriented to autarky and therefore relied heavily on its domestic energy source of brown coal. In 1989 brown coal accounted for 68.4%, hence more than two thirds, of the Democratic Republic's total primary energy consumption of 128 million t of coal equivalent. Its corresponding share in the old Laender was only 23.5%. In the old Laender mineral oil with a share of 40% represented the prime energy source, whereas in the new Laender it accounted for only 14% of primary energy consumption. However, this small proportion in no way reflects the true significance of the mineral oil industry in the former GDR. (orig.) [de

Risk assessment for mineral oil : development of standardized analitical methods in soil and soil-like materials

NARCIS (Netherlands)

Harmsen, J.; Hutter, J.W.; Win, T.; Barnabas, I.; Whittle, P.; Hansen, N.; Sakai, H.

2005-01-01

The present standard methods for the determination of mineral oil in environmental matrices give a total concentration. This concentration is not found to be a good estimate for ecotoxicological, human and agricultural risks. It is shown that the existing ISO standards for mineral oil and volatile

Mineral oil residues in soil and apple under temperate conditions of Kashmir, India.

Science.gov (United States)

Ahmad, Malik Mukhtar; Wani, Ashraf Alam; Sofi, Mubashir; Ara, Ishrat

2018-03-09

The study was undertaken to ascertain the persistence of Orchol-13, a mineral oil used against insect pests of horticultural fruit crops in soil and apple following the dormant and summer applications of 2 and 0.75% respectively. Soil samples were collected during dormant, while as both soil and apple samples were collected during summer season. Samples were collected at 0, 1, 3, and 5 days post treatment in both the seasons. Average recoveries of paraffinic constituents (which constitute about 60% of mineral oils by composition) from soil and apple at 1 μg ml -1 spiking level were found to be 74.18 and 76.81% respectively. The final quantification of paraffinic constituents was performed on gas chromatograph equipped with flame ionization detector (GC-FID). No paraffinic constituents of mineral oil could be detected in soil and apple at 0 day post treatment in both the seasons.

The influence of external field on the lubricity of mineral oil for railway transport

Directory of Open Access Journals (Sweden)

Voronin Serhii

2017-01-01

Full Text Available The use of mineral oil is associated with its gradual operational degradation caused by its natural aging and contamination with various impurities. As the concentration of impurities increases, the number of active surface molecules which determine the operational properties of mineral oils decreases. A promising method of recovery of the operational properties of oils is the treatment with an electric field, which makes it possible to enhance the activity of surfactants in the tribo-contact area. This statement is proved through the improvement of the wettability of the bronze surface with mineral oils after their treatment with an electrostatic field. However, the method of electrical treatment is associated with the need to increase the requirements for the purity of liquids, especially to the presence of water, which requires creating an oil pre-treatment system. As an alternative, a method of electrical treatment with special field parameters is proposed enabling to accelerate the coalescence process. The major parameter that accelerates the coalescence process is the electric field oscillation frequency. The results of the study give grounds for choosing the optimal field parameters.

Effects of tallow, choice white grease, palm oil, corn oil, or soybean oil on apparent total tract digestibility of minerals in diets fed to growing pigs.

Science.gov (United States)

Merriman, L A; Walk, C L; Parsons, C M; Stein, H H

2016-10-01

An experiment was conducted to determine the effect of supplementing diets fed to growing pigs with fat sources differing in their composition of fatty acids on the apparent total tract digestibility (ATTD) of minerals. A diet based on corn, potato protein isolate, and 7% sucrose was formulated. Five additional diets that were similar to the previous diet with the exception that sucrose was replaced by 7% tallow, choice white grease, palm oil, corn oil, or soybean oil were also formulated. Diets were formulated to contain 0.70% Ca and 0.33% standardized total tract digestible P. Growing barrows ( = 60; 15.99 ± 1.48 kg initial BW) were allotted to a randomized complete block design with 2 blocks of 30 pigs, 6 dietary treatments, and 10 replicate pigs per treatment. Experimental diets were provided for 12 d with the initial 5 d being the adaptation period. Total feces were collected for a 5-d collection period using the marker-to-marker approach, and the ATTD of minerals, ether extract, and acid hydrolyzed ether extract was calculated for all diets. Digestibility of DM was greater ( soybean oil compared with the diet containing choice white grease or the basal diet, with all other diets being intermediate. The ATTD of Ca, S, and P was greater ( soybean oil, corn oil, palm oil, or tallow than for pigs fed the basal diet or the diet containing choice white grease. The ATTD of Mg, Zn, Mn, Na, and K were not different among dietary treatments. The ATTD of ether extract was greater ( oil, corn oil, or soybean oil compared with the diet containing choice white grease, and the ATTD of acid hydrolyzed ether extract in the diet containing soybean oil was also greater ( oil, corn oil, or soybean oil may increase the ATTD of some macrominerals, but that appears not to be the case if choice white grease is used. There was no evidence of negative effects of the fat sources used in this experiment on the ATTD of any minerals.

Iron utilization and liver mineral concentrations in rats fed safflower oil, flaxseed oil, olive oil, or beef tallow in combination with different concentrations of dietary iron.

Science.gov (United States)

Shotton, Andrea D; Droke, Elizabeth A

2004-03-01

Diets with a higher proportion of polyunsaturated fatty acids (i.e., linoleic acid) have decreased iron absorption and utilization compared with diets containing a higher proportion of the saturated fatty acid stearic acid (e.g., beef tallow). However, less is known regarding the influence of other polyunsaturated or monounsaturated fatty acids, along with higher dietary iron, on iron absorption and utilization. The present study was conducted to compare the effects of dietary fat sources known to vary in (n-3), (n-6), and (n-9) fatty acids on iron utilization and liver mineral concentrations. Male weanling rats were fed a diet containing 10, 35, or 100 microg/g iron in combination with safflower oil, flaxseed oil, olive oil, or beef tallow for 8 wk. Indicators of iron status, iron utilization, and liver iron concentrations were unaffected by an interaction between the fat source and iron concentration. Plasma copper was the only variable affected by an interaction between the fat source and dietary iron. Findings of this study demonstrate that flaxseed oil and olive oil may alter tissue minerals and affect iron utilization. Further studies should be conducted to establish the effect of varying (n-3), (n-6), and (n-9) fatty acids on trace mineral status and iron utilization.

Clay minerals trap hydrogen in the Earth's crust: Evidence from the Cigar Lake uranium deposit, Athabasca

Science.gov (United States)

Truche, Laurent; Joubert, Gilles; Dargent, Maxime; Martz, Pierre; Cathelineau, Michel; Rigaudier, Thomas; Quirt, David

2018-07-01

Hydrogen (H2)-rich fluids are observed in a wide variety of geologic settings including gas seeps in serpentinized ultramafic rocks, sub-seafloor hydrothermal vents, fracture networks in crystalline rocks from continental and oceanic crust, and volcanic gases. Natural hydrogen sources can sustain deep microbial ecosystems, induce abiotic hydrocarbons synthesis and trigger the formation of prebiotic organic compounds. However, due to its extreme mobility and small size, hydrogen is not easily trapped in the crust. If not rapidly consumed by redox reactions mediated by bacteria or suitable mineral catalysts it diffuses through the rocks and migrates toward the surface. Therefore, H2 is not supposed to accumulate in the crust. We challenge this view by demonstrating that significant amount of H2 may be adsorbed by clay minerals and remain trapped beneath the surface. Here, we report for the first time H2 content in clay-rich rocks, mainly composed of illite, chlorite, and kaolinite from the Cigar Lake uranium ore deposit (northern Saskatchewan, Canada). Thermal desorption measurements reveal that H2 is enriched up to 500 ppm (i.e. 0.25 mol kg-1 of rock) in these water-saturated rocks having a very low total organic content (reported elsewhere for pure clay minerals or shales. Sudoite (Al-Mg di-trioctahedral chlorite) is probably the main mineral responsible for H2 adsorption in the present case. The presence of multiple binding sites in interlinked nanopores between crystal layers of illite-chlorite particles offers the ideal conditions for hydrogen sorption. We demonstrate that 4 to 17% of H2 produced by water radiolysis over the 1.4-Ga-lifetime of the Cigar Lake uranium ore deposit has been trapped in the surrounding clay alteration haloes. As a result, sorption processes on layered silicates must not be overlooked as they may exert an important control on the fate and mobility of H2 in the crust. Furthermore, the high capacity of clay minerals to sorb molecular

Tribological Effects of Mineral-Oil Lubricant Contamination with Biofuels: A Pin-on-Disk Tribometry and Wear Study

Directory of Open Access Journals (Sweden)

S. M. Shanta

2011-01-01

Full Text Available Use of biodiesel produces engine oil dilution because of unburned biodiesel impinging on cold walls of the combustion chamber, being scrapped to the oil pan, and leading to changes of oil friction, wear and lubricity properties. In this paper, mixtures of SAE 15W-40 oil, which were contaminated by known percentages of the biodiesels from canola oil, peanut oil, soybean oil, and chicken fat, were tested in a pin-on-disk tribometer. A contact was employed of AISI 1018 steel disk and AISI 316 stainless-steel ball for pin material, and friction force and specific wear were measured. Wear on the disk surfaces showed that any degree of mineral-oil dilution by the tested biodiesels reduces the wear protection of engine oil even at small mixture percentages. However, these reductions were not substantially different than those observed for same percentages of dilution of mineral oil by fossil diesel. The tested mixture of oil contaminated with animal fat feedstock (e.g., chicken fat biodiesel showed the best wear behavior as compared to those for the other tested mixtures (of mineral oil with vegetable feedstock biodiesel dilutions. Obtained results are discussed as baseline for further studies in a renewable energy multidisciplinary approach on biofuels and biolubes.

Application of thin-layer chromatography of fat and oil, fatty acid and mineral oil for science education. Yushi, shibosan, koyu no hakuso chromatography to sono kyozaiteki katsuyo

Energy Technology Data Exchange (ETDEWEB)

Kawabuchi, K [Ehime Univ., Ehime (Japan); Takechi, Y; Morimoto, M [Ehime (Japan)

1990-08-20

In this article, with regard to application of thin-layer chromatography of fat and oil, fatty acid and mineral oil for science education, a study was made mainly on quality finding of n-hexane extracts provided in the law of prevention of water pollution, and separation of hydrolysis products of fat and oil. As a result, the existance of fat and oil, fatty acid and mineral oil in the enviromental water and the hydrolysis process of fat and oil could experimentally be confirmed. This is considered to be useful for studying teaching material on fat and oil. This report deals with the reagents and device, and specifies standard solution, thin-layer plate, spread solvent, spread tank and thermostat, and states, for its operation, the method using enzyme for hydrolysis of fat and oil and the method using potassium hydroxide. It also contemplates on R {sub f} values of fat and oil, fatty acid and mineral oil, etc., as well as spread of fat and oil, oils contained in n-hexane extracts and hydrolysis products of fat and oil. 6 refs., 4 figs., 1 tab.

Oil spill research program, U. S. Minerals Management Service

International Nuclear Information System (INIS)

LaBelle, R. P.; Mullin, J. V.; White, A. C.

1997-01-01

The oil spill prevention and response research program of the U.S. Minerals Management Service was described including its goals and objectives, some recently funded projects, and future research directions. As it is now the trend in most research organizations, a large part of the program is carried out in cooperation with other major research centers to leverage funds and to maximize study results. For example, joint research with Environment Canada focuses on the physical and chemical properties of dispersants, remote sensing and mapping oil slicks and shoreline cleanup strategies. Similarly, cooperative projects are underway with the National Institute of Standards and Technology in assessing the capabilities of in-situ burning as an oil spill response tool. Research capabilities of OHMSETT - The National Oil Spill Response Test Facility were also reviewed. A series of tables listed titles of research projects completed during 1995-1996. 5 tabs.,

Mineralization of a Malaysian crude oil by Pseudomonas sp. and Achromabacter sp. isolated from coastal waters

Energy Technology Data Exchange (ETDEWEB)

Ahmad, J.; Ahmad, M.F.

1995-12-31

Regarded as being a potentially effective tool to combat oil pollution, bioremediation involves mineralization, i.e., the conversion of complex hydrocarbons into harmless CO{sub 2} and water by action of microorganisms. Therefore, in achieving optimum effectiveness from the application of these products on crude oil in local environments, the capability of the bacteria to mineralize hydrocarbons was evaluated. The microbial laboratory testing of mineralization on local oil degraders involved, first, isolation of bacteria found at a port located on the west coast of Peninsular Malaysia. Subsequently, these bacteria were identified by means of Biomereux`s API 20E and 20 NE systems and later screened by their growth on a Malaysian crude oil. Selected strains of Pseudomonas sp. and Achromabacter sp. were then exposed individually to a similar crude oil in a mineralization unit and monitored for 16 days for release of CO{sub 2}. Pseudomonas paucimobilis was found to produce more CO{sub 2} than Achromobacter sp. When tested under similar conditions, mixed populations of these two taxa produced more CO{sub 2} than that produced by any individual strain. Effective bioremediation of local crude in Malaysian waters can therefore be achieved from biochemically developed Pseudomonas sp. strains.

Tensão superficial estática de soluções aquosas com óleos minerais e vegetais utilizados na agricultura Surface tension of mineral oils and vegetable oils

Directory of Open Access Journals (Sweden)

Cristina G. de Mendonça

2007-01-01

Full Text Available O trabalho teve como objetivo avaliar a tensão superficial estática de soluções aquosas com formulações de óleos minerais e vegetais emulsionáveis utilizados como adjuvantes na agricultura. Os óleos minerais e vegetais, quando adicionados aos produtos fitossanitários, podem imprimir características desejáveis à calda de pulverização, como reduzir a tensão superficial em soluções aquosas, possibilitar maior contato da calda com a superfície vegetal ou reduzir o potencial de deriva durante as pulverizações. Foram testados os seguintes produtos comerciais: óleos minerais (Assist, Attach, Dytrol, Iharol, Mineral Oil, Spinner, Sunspray-E e Triona e óleos vegetais (Agrex'oil Vegetal, Crop Oil, Natur'l Óleo, Óleo Vegetal Nortox e Veget Oil, todos com registro de uso na agricultura. A tensão superficial das soluções aquosas foi avaliada em 11 concentrações para cada produto (0,025; 0,05; 0,1; 0,25; 0,5; 0,75; 1,0; 1,5; 2,0; 2,5 e 3,0% v/v. Essa propriedade dos óleos minerais e dos óleos vegetais foi estimada medindo-se a massa das gotas formadas na extremidade de uma bureta. Ao conjunto de dados obtidos para cada produto, na avaliação da tensão superficial, foram determinadas as análises de variância e de regressão, ajustando-se os dados ao Modelo de Mitscherlich. Entre os óleos minerais, destacaram-se os produtos: Assist, Dytrol, Iharol e Mineral Oil por apresentarem as menores tensões superficiais mínimas estimadas pelo Modelo, respectivamente, 29,255; 28,442; 26,097 e 28,584 mN m-1. Os óleos vegetais que apresentaram os menores valores de tensão superficial mínima estimados pelo Modelo, foram: Agrex' oil Vegetal (27,716 mN m-1, Natur'l óleo (28,216 mN m-1, Veget Oil (27,308 mN m-1 e Crop Oil (29,964 mN m-1.The aim of this work was to evaluate the surface tension of water emulsion with mineral oils and vegetable oils used as adjuvant. The mineral and vegetable oils when added to the agrochemicals can

Natural (Mineral, Vegetable, Coconut, Essential) Oils and Contact Dermatitis.

Science.gov (United States)

Verallo-Rowell, Vermén M; Katalbas, Stephanie S; Pangasinan, Julia P

2016-07-01

Natural oils include mineral oil with emollient, occlusive, and humectant properties and the plant-derived essential, coconut, and other vegetable oils, composed of triglycerides that microbiota lipases hydrolyze into glycerin, a potent humectant, and fatty acids (FAs) with varying physico-chemical properties. Unsaturated FAs have high linoleic acid used for synthesis of ceramide-I linoleate, a barrier lipid, but more pro-inflammatory omega-6:-3 ratios above 10:1, and their double bonds form less occlusive palisades. VCO FAs have a low linoleic acid content but shorter and saturated FAs that form a more compact palisade, more anti-inflammatory omega-6:-3 ratio of 2:1, close to 7:1 of olive oil, which disrupts the skin barrier, otherwise useful as a penetration enhancer. Updates on the stratum corneum illustrate how this review on the contrasting actions of NOs provide information on which to avoid and which to select for barrier repair and to lower inflammation in contact dermatitis genesis.

Structural effects of C60+ bombardment on various natural mineral samples-Application to analysis of organic phases in geological samples

International Nuclear Information System (INIS)

Siljestroem, S.; Lausmaa, J.; Hode, T.; Sundin, M.; Sjoevall, P.

2011-01-01

Organic phases trapped inside natural mineral samples are of considerable interest in astrobiology, geochemistry and geobiology. Examples of such organic phases are microfossils, kerogen and oil. Information about these phases is usually retrieved through bulk crushing of the rock which means both a risk of contamination and that the composition and spatial distribution of the organics to its host mineral is lost. An attractive of way to retrieve information about the organics in the rock is depth profiling using a focused ion beam. Recently, it was shown that it is possible to obtain detailed mass spectrometric information from oil-bearing fluid inclusions, i.e. small amounts of oil trapped inside a mineral matrix, using ToF-SIMS. Using a 10 keV C 60 + sputter beam and a 25 keV Bi 3 + analysis beam, oil-bearing inclusions in different minerals were opened and analysed individually. However, sputtering with a C 60 + beam also induced other changes to the mineral surface, such as formation of topographic features and carbon deposition. In this paper, the cause of these changes is explored and the consequences of the sputter-induced features on the analysis of organic phases in natural mineral samples (quartz, calcite and fluorite) in general and fluid inclusions in particular are discussed. The dominating topographical features that were observed when a several micrometers deep crater is sputtered with 10 keV C 60 + ions on a natural mineral surface are conical-shaped and ridge-like structures that may rise several micrometers, pointing in the direction of the incident C 60 + ion beam, on an otherwise flat crater bottom. The sputter-induced structures were found to appear at places with different chemistry than the host mineral, including other minerals phases and fluid inclusions, while structural defects in the host material, such as polishing marks or scratches, did not necessarily result in sputter-induced structures. The ridge-like structures were often covered

The U.S. Minerals Management Service - oil spill response research program

International Nuclear Information System (INIS)

Mullin, J.V.

1998-01-01

The Minerals Management Service (MMS), is the principal U.S. Government agency funding offshore oil spill response research. The MMS, a bureau of the Department of the lnterior, maintains a comprehensive Oil Spill Response Research program in support of oil spill prevention and response. Through funding provided by MMS, scientists and engineers from the public and private sectors worldwide are working to address outstanding gaps in information and technology concerning the cleanup of oil spills. A large portion of the program is executed through cooperation with major research centers to leverage funds and maximize sharing of research results. This paper outlines the program, its goals, results from recently funded projects and future research directions. (author)

25 CFR 215.23a - Suspension of operations and production on leases for minerals other than oil and gas.

Science.gov (United States)

2010-04-01

... minerals other than oil and gas. 215.23a Section 215.23a Indians BUREAU OF INDIAN AFFAIRS, DEPARTMENT OF THE INTERIOR ENERGY AND MINERALS LEAD AND ZINC MINING OPERATIONS AND LEASES, QUAPAW AGENCY § 215.23a Suspension of operations and production on leases for minerals other than oil and gas. The provisions of...

Evaluation of efficacy of mineral oil, charcoal, and smectite in a rat model of equine cantharidin toxicosis.

Science.gov (United States)

Qualls, H J; Holbrook, T C; Gilliam, L L; Njaa, B L; Panciera, R J; Pope, C N; Payton, M E

2013-01-01

The efficacy of orally administered therapeutics for the treatment of cantharidin intoxication has not been evaluated in controlled studies. To develop a model of acute cantharidin intoxication in laboratory rats and to evaluate in this model the relative efficacy of 3 gastrointestinal therapies used to treat equine cantharidin toxicosis. Sixty-four male Sprague-Dawley rats. A blinded, randomized, controlled study was performed on rats surgically implanted with telemetry transmitters for evaluating heart rate, locomotor activity, and body temperature. Orogastric administration of cantharidin was performed within 15 seconds before administration of mineral oil, activated charcoal, or smectite. Negative control groups received therapeutic agents alone. Urine was collected for cantharidin analysis. Rats were sacrificed 24 hours after intoxication, and tissues were collected for histopathologic evaluation. Data analysis included ANOVA procedures and contingency tables. Six of 8 cantharidin-intoxicated rats treated with mineral oil died; bradycardia and hypothermia developed in the animals of this group 0-8 hours after intoxication. Rats treated with mineral oil had higher urine cantharidin concentrations than rats receiving cantharidin alone or with smectite (P = .04). The most severe hypothermia (30.6°C ± 1.0) developed in rats administered mineral oil at 4-8 hours after intoxication, whereas those treated with charcoal (35.2°C ± 0.8) had mean body temperatures higher than all other treatment groups (P = .03). Survival times in the charcoal (P = .16) and smectite (P = .12) treatment groups were not statistically different from negative controls. Mineral oil is often used in the treatment of equine cantharidin toxicosis. Our findings suggest that mineral oil increases cantharidin absorption, worsening morbidity and fatality in rats. Copyright © 2013 by the American College of Veterinary Internal Medicine.

Association between occupational exposure to mineral oil and rheumatoid arthritis: results from the Swedish EIRA case–control study

Science.gov (United States)

Sverdrup, Berit; Källberg, Henrik; Bengtsson, Camilla; Lundberg, Ingvar; Padyukov, Leonid; Alfredsson, Lars; Klareskog, Lars

2005-01-01

The aim of the present study was to investigate the association between exposure to mineral oil and the risk of developing rheumatoid arthritis (RA), and in addition to perform a separate analysis on the major subphenotypes for the disease; namely, rheumatoid factor (RF)-positive RA, RF-negative RA, anticitrulline-positive RA and anticitrulline-negative RA, respectively. A population-based case–control study of incident cases of RA was performed among the population aged 18–70 years in a defined area of Sweden during May 1996–December 2003. A case was defined as an individual from the study base who for the first time received a diagnosis of RA according to the American College of Rheumatology criteria of 1987. Controls were randomly selected from the study base with consideration taken for age, gender and residential area. Cases (n = 1,419) and controls (n = 1,674) answered an extensive questionnaire regarding lifestyle factors and occupational exposures, including different types of mineral oils. Sera from cases and controls were investigated for RF and anticitrulline antibodies. Among men, exposure to any mineral oil was associated with a 30% increased relative risk of developing RA (relative risk = 1.3, 95% confidence interval = 1.0–1.7). When cases were subdivided into RF-positive RA and RF-negative RA, an increased risk was only observed for RF-positive RA (relative risk = 1.4, 95% confidence interval 1.0–2.0). When RA cases were subdivided according to the presence of anticitrulline antibodies, an increased risk associated with exposure to any mineral oil was observed only for anticitrulline-positive RA (relative risk = 1.6, 95% confidence interval = 1.1–2.2). Analysis of the interaction between oil exposure and the presence of HLA-DR shared epitope genes regarding the incidence of RA indicated that the increased risk associated with exposure to mineral oil was not related to the presence of shared epitope genotypes. In conclusion, our study

Mineral oil

International Nuclear Information System (INIS)

Schult-Bornemann, Karl-Heinz

2015-01-01

The dominant theme in the world energy market was the fall in oil prices in 2014. From 115 US-$/bbl in June it dropped to below 50 US-$/bbl in January 2015. Thereby the shale oil revolution has had the strong impact on the global energy situation, to this point has been predicted for three years. Although no one could predict the exact height of the fall in oil prices, but with oil as a reserve currency for all other fuels, it has not only had an impact on the gas and coal prices, but other commodities, such as copper, have also yielded. About cause and effect, there is a lot of speculation - not all of which are supported by wisdom. [de

Method for obtaining a varnish with a base of mineral oil obtained by distillation of bituminous schists

Energy Technology Data Exchange (ETDEWEB)

Marchionni, A

1945-07-24

A method for obtaining a varnish is described characterized by the fact that the following ingredients are being used; mineral oil from the distillation of bituminous schists in the proportions already cited in the description, diluted with benzene or turpentine, with admixture of coloring matter. Varnish with a base of mineral oil from the distillation of bituminous schists is obtained.

Verification of geomechanical integrity and prediction of long-term mineral trapping for the Ketzin CO2 storage pilot site

Science.gov (United States)

Kempka, Thomas; De Lucia, Marco; Kühn, Michael

2014-05-01

Static and dynamic numerical modelling generally accompany the entire CO2 storage site life cycle. Thereto, it is required to match the employed models with field observations on a regular basis in order to predict future site behaviour. We investigated the coupled processes at the Ketzin CO2 storage pilot site [1] using a model coupling concept focusing on the temporal relevance of processes involved (hydraulic, chemical and mechanical) at given time-scales (site operation, abandonment and long-term stabilization). For that purpose, long-term dynamic multi-phase flow simulations [2], [3] established the basis for all simulations discussed in the following. Hereby, pressure changes resulting in geomechanical effects are largest during site operation, whereas geochemical reactions are governed by slow kinetics resulting in a long-term stabilization. To account for mechanical integrity, which may be mainly affected during site operation, we incorporated a regional-scale coupled hydro-mechanical model. Our simulation results show maximum ground surface displacements of about 4 mm, whereas shear and tensile failure are not observed. Consequently, the CO2 storage operation at the Ketzin pilot site does not compromise reservoir, caprock and fault integrity. Chemical processes responsible for mineral trapping are expected to mainly occur during long-term stabilization at the Ketzin pilot site [4]. Hence, our previous assessment [3] was extended by integrating two long-term mineral trapping scenarios. Thereby, mineral trapping contributes to the trapping mechanisms with 11.7 % after 16,000 years of simulation in our conservative and with 30.9 % in our maximum reactivity scenarios. Dynamic flow simulations indicate that only 0.2 % of the CO2 injected (about 67,270 t CO2 in total) is in gaseous state, but structurally trapped after 16,000 years. Depending on the studied long-term scenario, CO2 dissolution is the dominating trapping mechanism with 68.9 % and 88

Estrogenic Activity of Mineral Oil Aromatic Hydrocarbons Used in Printing Inks.

Directory of Open Access Journals (Sweden)

Patrick Tarnow

Full Text Available The majority of printing inks are based on mineral oils (MOs which contain complex mixtures of saturated and aromatic hydrocarbons. Consumer exposure to these oils occurs either through direct skin contacts or, more frequently, as a result of MO migration into the contents of food packaging that was made from recycled newspaper. Despite this ubiquitous and frequent exposure little is known about the potential toxicological effects, particularly with regard to the aromatic MO fractions. From a toxicological point of view the huge amount of alkylated and unsubstituted compounds therein is reason for concern as they can harbor genotoxicants as well as potential endocrine disruptors. The aim of this study was to assess both the genotoxic and estrogenic potential of MOs used in printing inks. Mineral oils with various aromatic hydrocarbon contents were tested using a battery of in vitro assays selected to address various endpoints such as estrogen-dependent cell proliferation, activation of estrogen receptor α or transcriptional induction of estrogenic target genes. In addition, the comet assay has been applied to test for genotoxicity. Out of 15 MOs tested, 10 were found to potentially act as xenoestrogens. For most of the oils the effects were clearly triggered by constituents of the aromatic hydrocarbon fraction. From 5 oils tested in the comet assay, 2 showed slight genotoxicity. Altogether it appears that MOs used in printing inks are potential endocrine disruptors and should thus be assessed carefully to what extent they might contribute to the total estrogenic burden in humans.

Comparison of male and female emerald ash borer (Coleoptera: Buprestidae) responses to phoebe oil and (Z)-3-hexanol lures in light green prism traps

Science.gov (United States)

Gary G. Grant; Therese M. Poland; Tina Ciaramitaro; D. Barry Lyons; Gene C. Jones

2011-01-01

We conducted trapping experiments for the emerald ash borer, Agrilus planipennis Fairmaire (Coleoptera: Buprestidae) in Michigan, USA, and Ontario, Canada, to compare unbaited light green sticky prism traps with traps baited with phoebe oil, (Z)-3-hexenol (Z3-6:OH), or blends of other green leaf volatiles (GLVs) with Z3-6:OH. Traps were placed in the...

Some physio-graphical keys to interpret reservoirs-traps, hosts of uranium-bearing mineralizations

International Nuclear Information System (INIS)

Parize, O.; Feybesse, J.L.; Wattinne-Morice, A.; Benedicto, A.; Richard, Y.; Sol, R.; Milesi, J.P.; Duchemin, Ch.; James, O.; Girard, Ch.

2009-01-01

As an approach in the search for silici-clastic formations which are reservoirs-traps hosting uranium-bearing mineralizations, the authors describe the use of facies sedimentology to describe successive deposits the arrangement of which determines the sequences according to which mineralisation will preferentially concentrate. They describe the use of sequential stratigraphy and how uranium had moved and deposited in successive eras and formations. They illustrate this approach by discussing different uranium-bearing deposits located in Niger and in France. They show how diagenesis, tectonics and sedimentology are combined to analyse these sites, and even to reassess them while exploiting them

Review of Research Progress on the Electrical Properties and Modification of Mineral Insulating Oils Used in Power Transformers

Directory of Open Access Journals (Sweden)

Xiaobo Wang

2018-02-01

Full Text Available In November 2017, the first ±1100 kV high-voltage direct-current power transformer in the world, which was made by Siemens in Nurnberg, passed its type test. Meanwhile, in early 2017, a ±1000 kV ultra-high voltage (UHV substation was officially put into operation in Tianjin, China. These examples illustrate that the era of UHV power transmission is coming. With the rapid increase in power transmission voltage, the performance requirements for the insulation of power transformers are getting higher and higher. The traditional mineral oils used inside power transformers as insulating and cooling agents are thus facing a serious challenge to meet these requirements. In this review, the basic properties of traditional mineral insulating oil are first introduced. Then, the variation of electrical properties such as breakdown strength, permittivity, and conductivity during transformer operation and aging is summarized. Next, the modification of mineral insulating oil is investigated with a focus on the influence of nanoparticles on the electrical properties of nano-modified insulating oil. Recent studies on the performance of mineral oil at molecular and atomic levels by molecular dynamics simulations are then described. Finally, future research hotspots and notable research topics are discussed.

Minerals

Directory of Open Access Journals (Sweden)

Vaquero, M. P.

1998-08-01

Full Text Available The possible changes in the mineral composition of food during frying could be the consequence of losses by leaching, or changes in concentrations caused by exchanges between the food and culinary fat of other compounds. The net result depends on the type of food, the frying fat used and the frying process. Moreover, the modifications that frying produces in other nutrients could indirectly affect the availability of dietary minerals. The most outstanding ones are those that can take place in the fat or in the protein. With respect to the interactions between frying oils and minerals, we have recent knowledge concerning the effects of consuming vegetable oils used in repeated fryings of potatoes without turnover, on the nutritive utilization of dietary minerals. The experiments have been carried out in pregnant and growing rats, which consumed diets containing, as a sole source of fat, the testing frying oils or unused oils. It seems that the consumption of various frying oils, with a polar compound content lower or close to the maximum limit of 25% accepted for human consumption, does not alter the absorption and metabolism of calcium, phosphorous, iron or copper. Magnesium absorption from diets containing frying oils tends to increase but the urinary excretion of this element increases, resulting imperceptible the variations in the magnesium balance. The urinary excretion of Zn also increased although its balance remained unchanged. Different studies referring to the effects of consuming fried fatty fish on mineral bioavailability will also be presented. On one hand, frying can cause structural changes in fish protein, which are associated with an increase in iron absorption and a decrease in body zinc retention. The nutritive utilization of other elements such as magnesium, calcium and copper seems to be unaffected. On the other hand; it has been described that an excess of fish fatty acids in the diet produces iron depletion, but when fatty

Modeling CO2-Water-Mineral Wettability and Mineralization for Carbon Geosequestration.

Science.gov (United States)

Liang, Yunfeng; Tsuji, Shinya; Jia, Jihui; Tsuji, Takeshi; Matsuoka, Toshifumi

2017-07-18

Carbon dioxide (CO 2 ) capture and storage (CCS) is an important climate change mitigation option along with improved energy efficiency, renewable energy, and nuclear energy. CO 2 geosequestration, that is, to store CO 2 under the subsurface of Earth, is feasible because the world's sedimentary basins have high capacity and are often located in the same region of the world as emission sources. How CO 2 interacts with the connate water and minerals is the focus of this Account. There are four trapping mechanisms that keep CO 2 in the pores of subsurface rocks: (1) structural trapping, (2) residual trapping, (3) dissolution trapping, and (4) mineral trapping. The first two are dominated by capillary action, where wettability controls CO 2 and water two-phase flow in porous media. We review state-of-the-art studies on CO 2 /water/mineral wettability, which was found to depend on pressure and temperature conditions, salt concentration in aqueous solutions, mineral surface chemistry, and geometry. We then review some recent advances in mineral trapping. First, we show that it is possible to reproduce the CO 2 /water/mineral wettability at a wide range of pressures using molecular dynamics (MD) simulations. As the pressure increases, CO 2 gas transforms into a supercritical fluid or liquid at ∼7.4 MPa depending on the environmental temperature. This transition leads to a substantial decrease of the interfacial tension between CO 2 and reservoir brine (or pure water). However, the wettability of CO 2 /water/rock systems depends on the type of rock surface. Recently, we investigated the contact angle of CO 2 /water/silica systems with two different silica surfaces using MD simulations. We found that contact angle increased with pressure for the hydrophobic (siloxane) surface while it was almost constant for the hydrophilic (silanol) surface, in excellent agreement with experimental observations. Furthermore, we found that the CO 2 thin films at the CO 2 -hydrophilic

Problems of mineral tax computation in the oil and gas sector

Directory of Open Access Journals (Sweden)

Н. Г. Привалов

2017-04-01

Full Text Available The paper demonstrates the role of mineral tax in the overall sum of tax revenues in the budget. Problems of tax computation and payment have been reviewed; taxpayers and taxation basis of the amount of extracted minerals have been clearly defined. Issues of rental content of natural resource taxes are reviewed, as well as problems of right definition of the rental component in the process of mineral tax calculation for liquid and gaseous hydrocarbons.One of important problems in mineral tax calculation is a conflict between two laws – the Subsoil Law and the Tax Code of Russian Federation (26th chapter. There is an ambiguity in the mechanism of calculating amounts of extracted mineral resources – from the positions of the Tax Code and the Subsoil Law. The second problem is in the necessity to amend the mineral tax for oil extraction the same way as it has been done for gas extraction, when characteristics of each field are taken into account.This will provide a basis for correct computation of the natural resource rent for liquid and gaseous hydrocarbons. The paper offers recommendations for Russian authorities on this issue.

Organic and mineral fertilization and chemical composition of lemon balm (Melissa officinalis essential oil

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Ana Carolina B. Sodré

2011-10-01

Full Text Available Melissa officinalis L., Lamiaceae, is an herb with great growth prospects in the cosmetic industry due to its essential oil. In order to improve its production, it is necessary to study related agricultural practices. This study evaluated the effect of organic and mineral fertilization on the chemical composition of lemon balm (Melissa officinalis L. essential oil. The assay was conducted at the "Fazenda Experimental do Glória" of the Federal University of Uberlândia, and essential oil extraction and GC/MS analyses were completed by the Centre for Research and Development on Plant Genetic Resources of the Campinas Agronomic Institute. The assay was conducted in a randomized complete block design with three replications. The tested treatments were six types of fertilization (0, 1, 2, 4, 8 kg.m-2 of cattle manure and mineral fertilizing with 60 g.m-2 of NPK 4-14-8 + 4 g.m-2 of boric acid with four replications. The essential oil was extracted by hydrodistillation in a modified Clevenger apparatus. The chemical composition was analyzed by GC/MS. The essential oil presented the same compounds for all treatments; however, the relative proportion of some chemical constituents was altered according to the treatment. Neral, geranial, and citronellal were the major constituents.

Organic and mineral fertilization and chemical composition of lemon balm (Melissa officinalis essential oil

Directory of Open Access Journals (Sweden)

Ana Carolina B. Sodré

2012-02-01

Full Text Available Melissa officinalis L., Lamiaceae, is an herb with great growth prospects in the cosmetic industry due to its essential oil. In order to improve its production, it is necessary to study related agricultural practices. This study evaluated the effect of organic and mineral fertilization on the chemical composition of lemon balm (Melissa officinalis L. essential oil. The assay was conducted at the "Fazenda Experimental do Glória" of the Federal University of Uberlândia, and essential oil extraction and GC/MS analyses were completed by the Centre for Research and Development on Plant Genetic Resources of the Campinas Agronomic Institute. The assay was conducted in a randomized complete block design with three replications. The tested treatments were six types of fertilization (0, 1, 2, 4, 8 kg.m-2 of cattle manure and mineral fertilizing with 60 g.m-2 of NPK 4-14-8 + 4 g.m-2 of boric acid with four replications. The essential oil was extracted by hydrodistillation in a modified Clevenger apparatus. The chemical composition was analyzed by GC/MS. The essential oil presented the same compounds for all treatments; however, the relative proportion of some chemical constituents was altered according to the treatment. Neral, geranial, and citronellal were the major constituents.

Influence of Water and Mineral Oil on the Leaks in Satellite Motor Commutation Unit Clearances

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Śliwiński Paweł

2017-09-01

Full Text Available The article describes the flow rates of mineral oil and water flowing, as working media, through the commutation unit of a hydraulic satellite motor. It is demonstrated that geometrical dimensions of commutation unit clearances change as a function of the machine shaft rotation angle. Methods for measuring the rate of this flow and the pressure in the working chamber are presented. The results of pressure measurements in the working chamber during the transition from the filling cycle to the emptying cycle are included. The pressure in the motor’s working chamber changes linearly as a function of the shaft rotation angle, which has a significant effect on the leakage in the commutation unit clearances. The paper presents new mathematical formulas in the form: Q=f(Δpγ to calculate the flow rate of water and mineral oil in the commutation unit clearances. The γ factor is described as a function of fluid viscosity and clearance length (the motor shaft rotation angle. The coefficients used in these formulas were determined based on the results of laboratory tests of a motor supplied with water and mineral oil.

Improving detection tools for emerald ash borer (Coleoptera: Buprestidae): comparison of multifunnel traps, prism traps, and lure types at varying population densities.

Science.gov (United States)

Crook, Damon J; Francese, Joseph A; Rietz, Michael L; Lance, David R; Hull-Sanders, Helen M; Mastro, Victor C; Silk, Peter J; Ryall, Krista L

2014-08-01

The emerald ash borer, Agrilus planipennis Fairmaire (Coleoptera: Buprestidae), is a serious invasive pest of North American ash (Fraxinus spp.) that has caused devastating mortality since it was first identified in North America in 2002. In 2012, we conducted field trapping assays that tested the efficacy of purple prism and fluon-coated green multifunnel (Lindgren funnel) traps. Traps were baited with combinations of several lures that were previously shown to be attractive to A. planipennis: manuka oil--a sesquiterpene-rich oil, (3Z)-hexenol--a green leaf volatile, or (3Z)-dodecen-12-olide [= (3Z)-lactone], a sex pheromone. Eighty-nine blocks (trap lines) were tested throughout nine states along the outer edges of the currently known A. planipennis infestation in North America. Trap catch was highest on fluon-coated green multifunnel traps, and trap detections at sites with low A. planipennis population density ranged from 72 to 76% for all trap and lure types tested. (3Z)-hexenol and (3Z)-lactone baited traps functioned as well as (3Z)-hexenol and manuka oil-baited traps. Independent of the lure used, detection rates on green fluon-coated multifunnel traps were comparable with glued purple prism traps in areas with low A. planipennis population densities.

Reactive Transport Modeling of Microbe-mediated Fe (II) Oxidation for Enhanced Oil Recovery

Science.gov (United States)

Surasani, V.; Li, L.

2011-12-01

Microbially Enhanced Oil Recovery (MEOR) aims to improve the recovery of entrapped heavy oil in depleted reservoirs using microbe-based technology. Reservoir ecosystems often contain diverse microbial communities those can interact with subsurface fluids and minerals through a network of nutrients and energy fluxes. Microbe-mediated reactions products include gases, biosurfactants, biopolymers those can alter the properties of oil and interfacial interactions between oil, brine, and rocks. In addition, the produced biomass and mineral precipitates can change the reservoir permeability profile and increase sweeping efficiency. Under subsurface conditions, the injection of nitrate and Fe (II) as the electron acceptor and donor allows bacteria to grow. The reaction products include minerals such as Fe(OH)3 and nitrogen containing gases. These reaction products can have large impact on oil and reservoir properties and can enhance the recovery of trapped oil. This work aims to understand the Fe(II) oxidation by nitrate under conditions relevant to MEOR. Reactive transport modeling is used to simulate the fluid flow, transport, and reactions involved in this process. Here we developed a complex reactive network for microbial mediated nitrate-dependent Fe (II) oxidation that involves both thermodynamic controlled aqueous reactions and kinetic controlled Fe (II) mineral reaction. Reactive transport modeling is used to understand and quantify the coupling between flow, transport, and reaction processes. Our results identify key parameter controls those are important for the alteration of permeability profile under field conditions.

Pre-treatment of Used-Cooking Oil as Feed Stocks of Biodiesel Production by Using Activated Carbon and Clay Minerals

Directory of Open Access Journals (Sweden)

Rudy Syah Putra

2014-02-01

Full Text Available Many low-cost feedstock i.e. used-cooking oil (UCO for the production of biodiesel fuel (BDF has contained a large amount of water and high proportion of free fatty acids (FFAs. Therefore, a pre-treatment process to reduce the water content (<0.1 wt.% and FFAs (<2.0 wt.% were necessary in order to avoid an undesirable side reactions, such as saponification, which could lead to serious problem of product separation and low fatty acid methyl ester (FAME yield. . In this study, a pre-treatment process of used cooking oil as a feedstock for the production of BDF by using various adsorbents such as Activated Carbon (AC and various clay minerals, for example Smectite (S, Bentonite (B, Kaolinite (K, and Powdered Earthenware (PE were evaluated. The oil obtained from pre-treatment was compared with oil without pre-treatment process. In this study, we reported a basic difference in material ability to the oil, depending on the adsorption condition with respect to the physico-chemical parameters, e.g. refractive index (R, density (ρ, FFAs, and water content (W. The results showed that the water content and FFAs in the oil has decreased when using AC as an adsorbent compared with clay minerals. However, the refractive index of oil has similar with the oil without pre-treatment process as well; meanwhile, the density of oil has increased after the pre-treatment process by using clay minerals.

Effects of bioremediation agents on oil degradation in mineral and sandy salt marsh sediments

International Nuclear Information System (INIS)

Lin, Q.; Mendelssohn, I.A.; Henry, C.B. Jr.; Roberts, P.O.; Walsh, M.M.; Overton, E.B.; Portier, R.J.

1999-01-01

Although bioremediation for oil spill cleanup has received considerable attention in recent years, its satisfactory use in the cleanup of oil spills in the wetland environment is still generally untested. A study of the often most used bioremediation agents, fertiliser, microbial product and soil oxidation, as a means of enhancing oil biodegradation in coastal mineral and sandy marsh substrates was conducted in controlled greenhouse conditions. Artificially weathered south Louisiana crude oil was applied to sods of marsh (soil and intact vegetation) at the rate of 2 l m -2 . Fertiliser application enhanced marsh plant growth, soil microbial populations, and oil biodegradation rate. The live aboveground biomass of Spartina alterniflora with fertiliser application was higher than that without fertiliser. The application of fertiliser significantly increased soil microbial respiration rates, indicating the potential for enhancing oil biodegradation. Bioremediation with fertiliser application significantly reduced the total targeted normal hydrocarbons (TTNH) and total targeted aromatic hydrocarbons (TTAH) remaining in the soil, by 81% and 17%, respectively, compared to those of the oil controls. TTNH/hopane and TTAAH/hopane ratios showed a more consistent reduction, further suggesting an enhancement of oil biodegradation by fertilisation. Furthermore, soil type affected oil bioremediation; the extent of fertiliser-enhanced oil biodegradation was greater for sandy (13% TTNH remaining in the treatments with fertiliser compared to the control) than for mineral soils (26% of the control), suggesting that fertiliser application was more effective in enhancing TTNH degradation in the former. Application of microbial product and soil oxidant had no positive effects on the variables mentioned above under the present experimental conditions, suggesting that microbial degraders are not limiting biodegradation in this soil. Thus, the high cost of microbial amendments during

Influence of trap color and host volatiles on capture of the emerald ash borer (Coleoptera: Buprestidae).

Science.gov (United States)

Crook, Damon J; Khrimian, Ashot; Cossé, Allard; Fraser, Ivich; Mastro, Victor C

2012-04-01

Field trapping assays were conducted in 2009 and 2010 throughout western Michigan, to evaluate lures for adult emerald ash borer, A. planipennis Fairmaire (Coleoptera: Buprestidae). Several ash tree volatiles were tested on purple prism traps in 2009, and a dark green prism trap in 2010. In 2009, six bark oil distillate lure treatments were tested against manuka oil lures (used in 2008 by USDA APHIS PPQ emerald ash borer cooperative program). Purple traps baited with 80/20 (manuka/phoebe oil) significantly increased beetle catch compared with traps baited with manuka oil alone. In 2010 we monitored emerald ash borer attraction to dark green traps baited with six lure combinations of 80/20 (manuka/phoebe), manuka oil, and (3Z)-hexenol. Traps baited with manuka oil and (3Z)-hexenol caught significantly more male and total count insects than traps baited with manuka oil alone. Traps baited with manuka oil and (3Z)-hexenol did not catch more beetles when compared with traps baited with (3Z)-hexenol alone. When compared with unbaited green traps our results show that (3Z)-hexenol improved male catch significantly in only one of three field experiments using dark green traps. Dark green traps caught a high number of A. planipennis when unbaited while (3Z)-hexenol was seen to have a minimal (nonsignificant) trap catch effect at several different release rates. We hypothesize that the previously reported kairomonal attractancy of (3Z)-hexenol (for males) on light green traps is not as obvious here because of improved male attractancy to the darker green trap.

A Comparative Experimental Analysis of Tribological Properties Between Commercial Mineral Oil and Neat Castor Oil using Taguchi Method in Boundary Lubrication Regime

OpenAIRE

S. Bhaumik; S.D Pathak

2016-01-01

The present work aims to carry out a comparative experimental analysis of tribological properties of 372cSt mineral oil and 229cSt castor oil. The antiwear and extreme pressure properties of both the oils have been analysed according to ASTM G 99 and ASTM D-2783 standards. The surfaces of the balls and pins after tribo tests have been analysed using Scanning Electron Microscope (SEM) images. The present test results predict that the antiwear and extreme pressure properties in case of the sele...

Methods of mineral potential assessment of uranium deposits: A mineral systems approach

International Nuclear Information System (INIS)

Jaireth, S.

2014-01-01

Mineral potential represents the likelihood (probability) that an economic mineral deposit could have formed in an area. Mineral potential assessment and prospectivity analysis use a probabilistic concepts to mineral deposits, where the probability of an event (formation of a mineral deposit) is conditional on two factors : i) geological processes occurring in the area, and ii) the presence of geological features indicative of those process. For instance, one of the geological processes critical for the formation of sandstone-hosted uranium deposits in an area is transport of uranium in groundwaters. Geological features indicative of this process in an area comprise, i) presence of leachable source rocks of uranium; ii) presence of highly permeable sandstone; and iii) suitable hydrogeological gradient driving flow groundwaters. Mineral deposits can also be conceptualised as mineral systems with more emphasis on mineralising processes. This concept has some clear parallels with the petroleum systems approach which has proven to be a useful in oil and gas exploration. Mineral systems are defined as ‘all geological factors that control the generation and preservation of mineral deposits’. Seven important geological factors are outlined to define the characteristics of a hydrothermal mineral system. These factors include: i) source of the mineralising fluids and transporting legends; ii) source of metals and other ore components; iii) migration pathways which may include inflow as well as outflow zones; iv) thermal gradients; v) source of energy to mobilised fluids; vi) mechanical and structural focusing mechanism at the trap site; and vii) chemical and/or physical cause for precipitation of ore minerals at the trap site. This approach, commonly known as the ‘source’, ‘transport’ and ‘trap’ paradigm has been redefined to introduce five questions as a basis to understand spatial and temporal evolution of a mineral system at all scales (regional to

75 FR 67996 - Environmental Documents Prepared for Proposed Oil, Gas, and Mineral Operations by the Gulf of...

Science.gov (United States)

2010-11-04

... Environmental Documents Prepared for Proposed Oil, Gas, and Mineral Operations by the Gulf of Mexico Outer... regarding whether those effects have significant impacts. Environmental Assessments are used to evaluate.... ACTION: Notice of the Availability of Environmental Documents Prepared for OCS Mineral Proposals by the...

Control of coffee berry borer, Hypothenemus hampei (Ferrari (Coleoptera: Curculionidae: Scolytinae with botanical insecticides and mineral oils

Directory of Open Access Journals (Sweden)

Flávio Neves Celestino

2016-01-01

Full Text Available The objective of this study was to evaluate botanical oils, mineral oils and an insecticide that contained azadirachtin (ICA for the control of Hypothenemus hampei, in addition to the effects of residual castor oil. We evaluated the effectiveness of the vegetable oils of canola, sunflower, corn, soybean and castor, two mineral oils (assist® and naturol®, and the ICA for the control of H. hampei. The compounds were tested at a concentration of 3.0% (v v-1. The median lethal concentration (LC50 was estimated with Probit analysis. The oil of castor bean and extract of castor bean cake were also evaluated at concentrations of 3.0% (v v-1 and 3.0% (m v-1, respectively. The mortality rates for H. hampei caused by the ICA and the castor oil were 40.8 and 53.7%, with LC50 values of 6.71 and 3.49% (v v-1, respectively. In the castor oil, the methyl esters of the fatty acids were palmitic (1.10%, linoleic (4.50%, oleic (4.02%, stearic (0.50% and ricinoleic acids (88.04%. The extract of the castor bean cake was not toxic to H. hampei. The persistence of the castor oil in the environment was low, and the cause of mortality for H. hampei was most likely the blockage of the spiracles, which prevented the insects from breathing.

Analysis of Anti-Wear Properties of CuO Nanoparticles as Friction Modifiers in Mineral Oil (460cSt Viscosity Using Pin-On-Disk Tribometer

Directory of Open Access Journals (Sweden)

S. Bhaumik

2015-06-01

Full Text Available The present work investigated the anti-wear properties of CuO nanoparticles based mineral oil using pin-on-disk apparatus. The pin material selected was EN 24(untreated as it is used in gear manufacturing. Commonly used graphite macro particles (wt.% and CuO nanoparticles(wt.% were used as additives. It had been observed that the additives based mineral oil samples exhibited superior antiwear properties than pure mineral oil. Both CuO nanoparticles (0.2 wt.% and graphite (0.2 wt.% based lubricant showed significant decrease in coefficient of friction and specific wear rate. There was a reduction in both coefficient of friction (28.5 % approx. and specific wear rate (70 % approx. in case of CuO nanolubricants and graphite based mineral oil as compared with the pure mineral oil.Flash-fire point, viscosity and viscosity index also increased with the increase in additive concentration. The surface characteristics of the pin were studied using Scanning Electron Microscope (SEM and surface roughness tester. The SEM images showed more rough surfaces in case of pure mineral oil samples as compared with graphite and CuO nanoparticles based samples. The surface roughness values of the pins in case of graphite (0.2 wt.% and CuO nano particles (0.2 wt.% based lubricant were much lesser than pure mineral oil. From the results predicted minimum 0.2 wt.% CuO nanoparticles were required to enhance the antiwear property of the lubricant. This work aimed in bringing a comparative experimental analysis using CuO nanoparticles and commonly used graphite macro particles as lubricant additives on various properties such as viscosity, flash point, fire point, surface roughness and anti-wear properties. Thus, the work would be useful in developing new nano lubricants with minimum additive concentration.

Mineral Resource Information System for Field Lab in the Osage Mineral Reservation Estate

Energy Technology Data Exchange (ETDEWEB)

Carroll, H.B.; Johnson, William I.

1999-04-27

The Osage Mineral Reservation Estate is located in Osage County, Oklahoma. Minerals on the Estate are owned by members of the Osage Tribe who are shareholders in the Estate. The Estate is administered by the Osage Agency, Branch of Minerals, operated by the U.S. Bureau of Indian Affairs (BIA). Oil, natural gas, casinghead gas, and other minerals (sand, gravel, limestone, and dolomite) are exploited by lessors. Operators may obtain from the Branch of Minerals and the Osage Mineral Estate Tribal Council leases to explore and exploit oil, gas, oil and gas, and other minerals on the Estate. Operators pay a royalty on all minerals exploited and sold from the Estate. A mineral Resource Information system was developed for this project to evaluate the remaining hydrocarbon resources located on the Estate. Databases on Microsoft Excel spreadsheets of operators, leases, and production were designed for use in conjunction with an evaluation spreadsheet for estimating the remaining hydrocarbons on the Estate.

Floating Oil-Spill Containment Device

Science.gov (United States)

Jones, Jack A.

2012-01-01

Previous oil containment booms have an open top that allows natural gas to escape, and have significant oil leakage due to wave action. Also, a subsea pyramid oil trap exists, but cannot move relative to moving oil plumes from deepsea oil leaks. The solution is to have large, moveable oil traps. One version floats on the sea surface and has a flexible tarp cover and a lower weighted skirt to completely entrap the floating oil and natural gas. The device must have at least three sides with boats pulling at each apex, and sonar or other system to track the slowly moving oil plume, so that the boats can properly locate the booms. The oil trap device must also have a means for removal of the oil and the natural gas. A second design version has a flexible pyramid cover that is attached by lines to ballast on the ocean floor. This is similar to fixed, metal pyramid oil capture devices in the Santa Barbara Channel off the coast of California. The ballast lines for the improved design, however, would have winches that can move the pyramid to always be located above the oil and gas plume. A third design is a combination of the first two. It uses a submerged pyramid to trap oil, but has no anchor and uses boats to locate the trap. It has ballast weights located along the bottom of the tarp and/or at the corners of the trap. The improved floating oil-spill containment device has a large floating boom and weighted skirt surrounding the oil and gas entrapment area. The device is triangular (or more than three sides) and has a flexible tarp cover with a raised gas vent area. Boats pull on the apex of the triangles to maintain tension and to allow the device to move to optimum locations to trap oil and gas. The gas is retrieved from a higher buoyant part of the tarp, and oil is retrieved from the floating oil layer contained in the device. These devices can be operated in relatively severe weather, since waves will break over the devices without causing oil leaking. Also, natural

Microbiological method for exploitation of oil deposits with a high mineralization of interstitial waters

Energy Technology Data Exchange (ETDEWEB)

Senyukov, V M; Yulbarisov, E M; Taldykina, N N; Shishenina, E P

1970-07-01

A literature review is made of microbiological processes suitable for secondary oil recovery. On the basis of literature data, basic experiments were conducted in the Arlansk field. This field has viscous oil, highly mineralized connate water (rho = 1.18) and permeability above 1,000 md. A mixture of aerobic and anaerobic bacteria with nutrient was injected through one well, then 650 cu m of fresh water was injected. Mineralogical and bacteriological analyses were made of produced fluids in nearby wells. Both aerobic and anaerobic bacteria were found in produced fluids, 600 m from the injection wells. On the basis of this result, it was concluded that microbiological processes can be used to increase secondary recovery of oil. However, no oil recovery data are presented. (10 refs.)

Biodegradation of oils in uranium deposits

International Nuclear Information System (INIS)

Landais, P.

1989-01-01

The biodegradation of free hydrocarbons that have migrated in reservoir facies has often been observed in the field of petroleum exploration. This alteration is characterized by the progressive removal by bacteria of the different types of hydrocarbons: n-alkanes, branched alkanes, aromatics, cycloalkanes, etc. One of the most important consequences of biodegradation is the biogenic reduction of sulphate, which has been noticed in several Pb-Zn deposits. Biodegradation of oils spatially associated with uranium mineralizations has been observed in Temple Mountain, Utah, and the Grand Canyon, Arizona, in the United States of America, and in Lodeve in France. It leads to the transformation of fluid oils into solid bitumens. Emphasis is placed on the relationships between the effects of biodegradation on organic matter (oxidation of aromatization) and the nature of aqueous fluids analysed in fluid inclusions trapped in authigenic minerals. Different mechanisms are proposed to explain the transformations of organic matter during biodegradation and their possible links with the ore forming process. (author). 40 refs, 13 figs, 1 tab

Increased mineral oil bioavailability in slurries by monovalent cation-induced dispersion

International Nuclear Information System (INIS)

Jonge, H. de; Verstraten, J.M.

1995-01-01

Bioavailability of apolar contaminants is an important limiting factor for microbial reclamation of polluted soils. This paper describes a laboratory study of the relation between microaggregate stability and bioavailability of mineral oil in soil-water slurries. The stability of microaggregates in slurries is regulated by the valence and surface affinity of the cations in the system, and by the complexing anion P 2 O 7 4- (metaphosphate). A silt loam, contaminated with a weathered gas oil, was collected from an oil refinery site. Degradation rates were monitored in small-scale incubations at solid:liquid ratios of 1:5 (w/w). The solution contained Ca, Na, or K as the dominant cation. The levels of nutrients and metaphosphate were varied. Biodegradation rates increased with the sequence Ca 2 treatment. Measurements of the particle size distribution the slurry showed that an increase in the finer fractions qualitatively correlated with enhanced biodegradation. This is a strong indication that dispersion of the microaggregates increased bioavailability of the contaminant

Crude oil polycyclic aromatic hydrocarbons removal via clay-microbe-oil interactions: Effect of acid activated clay minerals.

Science.gov (United States)

Ugochukwu, Uzochukwu C; Fialips, Claire I

2017-07-01

Acid treatment of clay minerals is known to modify their properties such as increase their surface area and surface acidity, making them suitable as catalysts in many chemical processes. However, the role of these surface properties during biodegradation processes of polycyclic aromatic hydrocarbons (PAHs) is only known for mild acid (0.5 M Hydrochloric acid) treated clays. Four different clay minerals were used for this study: a montmorillonite, a saponite, a palygorskite and a kaolinite. They were treated with 3 M hydrochloric acid to produce acid activated clay minerals. The role of the acid activated montmorillonite, saponite, palygorskite and kaolinite in comparison with the unmodified clay minerals in the removal of PAHs during biodegradation was investigated in microcosm experiments. The microcosm experiments contained micro-organisms, oil, and clays in aqueous medium with a hydrocarbon degrading microorganism community predominantly composed of Alcanivorax spp. Obtained results indicated that acid activated clays and unmodified kaolinite did not enhance the biodegradation of the PAHs whereas unmodified montmorillonite, palygorskite and saponite enhanced their biodegradation. In addition, unmodified palygorskite adsorbed the PAHs significantly due to its unique channel structure. Copyright © 2017 Elsevier Ltd. All rights reserved.

Effects of packaging, mineral oil coating, and storage time on biogenic amine levels and internal quality of eggs.

Science.gov (United States)

Figueiredo, T C; Assis, D C S; Menezes, L D M; Oliveira, D D; Lima, A L; Souza, M R; Heneine, L G D; Cançado, S V

2014-12-01

This study was carried out with the aim of evaluating the effects of mineral oil application on eggshells and the use of plastic packages with lids on the physical-chemical and microbiological quality and biogenic amine contents of eggs stored under refrigeration for up to 125 d. A total of 1,920 eggs from 46-wk-old Hyline W36 laying hens were randomly distributed into 4 groups soon after classification: (i) 480 eggs were stored in pulp carton tray packages; (ii) 480 eggs were stored in plastic packages with lids; (iii) 480 eggs were stored in carton packages after the application of mineral oil; and (iv) 480 eggs were stored in plastic packages with lids after the application of mineral oil. The internal quality was measured by Haugh units, by the counts of mesophilic and psychrotrophic microorganisms, by the most probable number of total and thermal-tolerant coliforms, by the counts of molds and yeasts, by the analysis of Salmonella spp. and Staphylococcus spp., and by the levels of biogenic amines in the egg yolk and albumen. The application of mineral oil to the eggshell resulted in higher Haugh unit values throughout storage, and the use of plastic packages altered the internal quality. The application of mineral oil and the use of packaging had no effects on the microbiological and biogenic amine results. Microbiological analyses showed the absence of Salmonella spp., Staphylococcus aureus, thermal-tolerant coliforms, and fungi. However, the highest counts of mesophilic (1.1 × 10(7) cfu/g) and psychrotrophic (6.7 × 10(7) cfu/g) microorganisms were recorded. The highest values of biogenic amines detected and quantified were putrescine (2.38 mg/kg) and cadaverine (7.27 mg/kg) in the egg yolk and putrescine (1.95 mg/kg), cadaverine (2.83 mg/kg), and phenylethylamine (2.57 mg/kg) in the albumen. Despite these results, the biogenic amine levels recorded were considered low and would not be harmful to consumer health. ©2014 Poultry Science Association Inc.

Bacterial diversity in the active stage of a bioremediation system for mineral oil hydrocarbon-contaminated soils.

Science.gov (United States)

Popp, Nicole; Schlömann, Michael; Mau, Margit

2006-11-01

Soils contaminated with mineral oil hydrocarbons are often cleaned in off-site bioremediation systems. In order to find out which bacteria are active during the degradation phase in such systems, the diversity of the active microflora in a degrading soil remediation system was investigated by small-subunit (SSU) rRNA analysis. Two sequential RNA extracts from one soil sample were generated by a procedure incorporating bead beating. Both extracts were analysed separately by generating individual SSU rDNA clone libraries from cDNA of the two extracts. The sequencing results showed moderate diversity. The two clone libraries were dominated by Gammaproteobacteria, especially Pseudomonas spp. Alphaproteobacteria and Betaproteobacteria were two other large groups in the clone libraries. Actinobacteria, Firmicutes, Bacteroidetes and Epsilonproteobacteria were detected in lower numbers. The obtained sequences were predominantly related to genera for which cultivated representatives have been described, but were often clustered together in the phylogenetic tree, and the sequences that were most similar were originally obtained from soils and not from pure cultures. Most of the dominant genera in the clone libraries, e.g. Pseudomonas, Acinetobacter, Sphingomonas, Acidovorax and Thiobacillus, had already been detected in (mineral oil hydrocarbon) contaminated environmental samples. The occurrence of the genera Zymomonas and Rhodoferax was novel in mineral oil hydrocarbon-contaminated soil.

Certified reference materials for the determination of mineral oil hydrocarbons in water, soil and waste

Energy Technology Data Exchange (ETDEWEB)

Koch, M.; Liebich, A.; Win, T.; Nehls, I.

2005-07-01

The international research project HYCREF, funded by the European Commission in the 5{sup th} Framework programme, aimed to develop methods to prepare homogeneous and stable water-, soil- and waste reference materials contaminated with mineral oil hydrocarbons and to test certify the mineral oil content by gas chromatographic methods. As mineral oil products are important sources for environmental contaminations a high need exists for certified reference materials for their determination using the new gas chromatographic methods (soil: ISO/FDIS 16703, waste: ENpr 14039, water: ISO 9377-2). The experimental conditions and results for preparation and characterisation of a total of nine reference materials (3 water, 3 soil- and 3 waste materials) are described and discussed. Target values for the reference materials were defined at the beginning of the project in order to have clear quality criteria, which could be compared with the achieved results at the end of the project. These target specifications were related to the maximum uncertainty from test certification exercises (<5% for soil/waste and <10% for water), the maximum inhomogeneity between bottles (<3%) and minimum requirements for stability (>5 years for soil/waste and >2 years for water). The feasibility studies showed that solid materials (soil, waste) could be prepared sufficiently homogeneous and stable. The test certified values of the 6 solid materials comprise a wide range of mineral oil content from about 200-9000 mg/kg with expanded uncertainties between 5.7-13.1% using a coverage factor k (k=2). The development of new water reference materials - the so-called ''spiking pills'' for an offshore- and a land-based discharge water represents one of the most innovative aspects of the project. The spiking pill technology facilitates the application and storage and improves the material stability compared with aqueous materials. Additional to the preparation and test certification of

Understanding the contamination of food with mineral oil: the need for a confirmatory analytical and procedural approach.

Science.gov (United States)

Spack, Lionel W; Leszczyk, Gabriela; Varela, Jesus; Simian, Hervé; Gude, Thomas; Stadler, Richard H

2017-06-01

The contamination of food by mineral oil hydrocarbons (MOHs) found in packaging is a long-running concern. A main source of MOHs in foods is the migration of mineral oil from recycled board into the packed food products. Consequently, the majority of food manufacturers have taken protective measures, e.g., by using virgin board instead of recycled fibres and, where feasible, introducing functional barriers to mitigate migration. Despite these protective measures, MOHs may still be observed in low amounts in certain food products, albeit due to different entry points across the food supply chain. In this study, we successfully apply gas chromatography coupled to mass spectrometry (GC-MS) to demonstrate, through marker compounds and the profile of the hydrocarbon response, the possible source of contamination using mainly chocolate and cereals as food matrices. The conventional liquid chromatography-one-dimensional GC coupled to a flame ionisation detector (LC-GC-FID) is a useful screening method, but in cases of positive samples it must be complemented by a confirmatory method such as, for example, GC-MS, allowing a verification of mineral oil contamination. The procedural approach proposed in this study entails profile analysis, marker identification, and interpretation and final quantification.

Recovery of mineral oil from waste emulsion using electrocoagulation method

Directory of Open Access Journals (Sweden)

Razali Mohd Najib

2016-01-01

Full Text Available This paper presents a research to recover mineral oil from industrial waste emulsion. This research also evaluates the standard of water produced after the oil recovery. The ecosystem could be polluted if this waste is not treated prior to discharge. The equipment needed for this experiment is power supply (generator, connecting wire and metal plate for providing the coagulant. The chosen plates were aluminium and iron plate. The power supply will be connected to the plate producing anode (positive terminal and cathode (negative terminal. Both plates are immersed into a beaker containing waste emulsion. The charge supplied by the current will cause the aluminium or ferum to dissisipate and became ions. These ions will attract the oil to flock together and float at the surface. The water will then filter by using filter paper. Electrocoagulation was done without addition of chemical thus can prevent the hazard from the chemicals. The samples was sent for oil and grease test. The optimum time needed for recovery of oil was 3 hours. The percentage recovery reach constant trend of 95% afterwards. When the power consumption increases, the percentage recovery also increases. However, the current should be lower than 0.5 ampere as it is the limit that human body can withstand. Thus, power consumption of 27.5 Watt was chosen as optimum value. The oil recovery of at power consumption at 27.5W is 96%. The best plate in the process was the aluminium pair which can recover more than ferum plate. The present work concludes the promising future for waste water treatment by usage of electrocoagulation technique.

Soybean plant-based toxicity assessment and phytoremediation of soils contaminated by vegetable and mineral oils used in power electrical transformers.

Science.gov (United States)

Sanderson, Karina; Módenes, Aparecido Nivaldo; Espinoza-Quiñones, Fernando Rodolfo; Trigueros, Daniela Estelita Goes; Júnior, Luiz Antônio Zanão; Schuelter, Adilson Ricken; Neves, Camila Vargas; Kroumov, Alexander Dimitrov

2018-04-01

In this work, deleterious effects in soils due to the presence of dielectric fluids were investigated. For this purpose, vegetable (Envirotemp ® FR3) and mineral (Lubrax AV 66 IN) oils were used for simulating a set of soils contaminated in different oil contents (0.5, 1.0, 2.0, 2.5, 5.0, 7.5 and 10%) in which three 120-days soybean crop periods (SCP) were carried out using the species Glycine max (L.) Merr. Both soil and soybean plant samples were analysed on following the changes on chemical attributes, content of oils and greases (COG) in soils and phytotechnical characteristics of soybean plant. No significant changes on soil chemical attributes were found. For a 0.5% vegetable oil fraction, COG removals of 35, 60 and 90% were observed after the 1st, 2nd, and 3rd SCPs, respectively, whereas removals of 25, 40 and 70% were observed for 0.5% mineral oil fraction after the 1st, 2nd, and 3rd SCPs, respectively. There was an effectively accumulated removal on all tested oil fractions as being proportional to the integrated 120-days SCPs, suggesting a lesser number of crops for a complete abatement of oil fraction in soil. A 100% recovery on the seedlings emergence fractions was also evidenced, revealing that at least a number of 7 and 9 SCPs should be applied continuously in soils contaminated by vegetable and mineral oils, respectively, in order to no longer jeopardize soybean plant growth. Finally, an empirical prediction of the number of SCPs necessary for the complete removal of oil from the soil was proposed. Copyright © 2018 Elsevier Ltd. All rights reserved.

Distribution of clay minerals in the process streams produced by the extraction of bitumen from Athabasca oil sands

Energy Technology Data Exchange (ETDEWEB)

Kaminsky, H.A.W.; Etsell, T.H.; Ivey, D.G. [Alberta Univ., Edmonton, AB (Canada). Dept. of Chemical and Materials Engineering; Omotoso, O. [Natural Resources Canada, Devon, AB (Canada). CETC

2009-02-15

The clay minerals present in the oil sands were studied with particular reference to how they are partitioned in bitumen ore during the extraction process. Bitumen production from surface-mined oil sands accounts for nearly two-thirds of the total bitumen production in Alberta. Every cubic meter of mined ore results in 1.3 cubic meters of mature fine tailings (MFT). The characteristic differences between the clay minerals that report to the froth versus the tailings streams were also examined to determine which minerals could impact different unit operations in the bitumen extraction process. X-ray diffraction and random powder samples were used to quantify the clay minerals. Particle size distribution and clay activity balances were also conducted. The degree of partitioning during the conditioning and flotation stages in a batch extractor was determined by the surface properties of the clay minerals. The water-continuous tailings stream was separated into fine and coarse tailings fractions through sedimentation. The study showed that bitumen-clay interactions may be dominated by kaolinite or iron oxides. Clays are responsible for the poor settling behaviour of MFTs. The clay minerals present in the oil sands include illite, illite-smectite, kaolinite, kaolinite-smectite, and chlorite. The close proximity of the tailings ponds to the Athabasca River and volatile organic compounds (VOCs) emission require that the ponds be reclaimed to a natural landscape before mine closure. In addition to its impact on fine tailings reclamation, clay mineralogy plays a role in extraction froth flotation and emulsion stability during froth treatment. The mineralogy of the froth solids was found to be different from the mineralogy of the middlings and tailings solids. 39 refs., 6 tabs., 6 figs.

77 FR 34405 - Environmental Documents Prepared for Oil, Gas, and Mineral Operations by the Gulf of Mexico Outer...

Science.gov (United States)

2012-06-11

... Geophysical Survey, SEA M09- Planning Area of the 013. Gulf of Mexico. Energy Resource Technology GOM, South... Oil, Gas, and Mineral Operations by the Gulf of Mexico Outer Continental Shelf (OCS) Region AGENCY... documents prepared for OCS mineral proposals by the Gulf of Mexico OCS Region SUMMARY: BOEM, in accordance...

Synthetics, mineral oils, and bio-based lubricants chemistry and technology

CERN Document Server

Rudnick, Leslie R

2005-01-01

As the field of tribology has evolved, the lubrication industry is also progressing at an extraordinary rate. Updating the author's bestselling publication, Synthetic Lubricants and High-Performance Functional Fluids, this book features the contributions of over 60 specialists, ten new chapters, and a new title to reflect the evolving nature of the field: Synthetics, Mineral Oils, and Bio-Based Lubricants: Chemistry and Technology. The book contains chapters on all major lubricant fluids used in a wide range of applications. For each type of lubricant, the authors discuss the historical develo

Evaluation of double-decker traps for emerald ash borer (Coleoptera: Buprestidae).

Science.gov (United States)

Poland, Therese M; McCullough, Deborah G; Anulewicz, Andrea C

2011-04-01

Improved detection tools are needed for the emerald ash borer, Agrilus planipennis Fairmaire (Coleoptera: Buprestidae), an invasive forest insect from Asia that has killed millions of ash (Fraxinus spp.) trees in North America since its discovery in Michigan in 2002. We evaluated attraction of adult A. planipennis to artificial traps incorporating visual (e.g., height, color, silhouette) and olfactory cues (e.g., host volatiles) at field sites in Michigan. We developed a double-decker trap consisting of a 3-m-tall polyvinyl pipe with two purple prisms attached near the top. In 2006, we compared A. planipennis attraction to double-decker traps baited with various combinations of manuka oil (containing sesquiterpenes present in ash bark), a blend of four ash leaf volatiles (leaf blend), and a rough texture to simulate bark. Significantly more A. planipennis were captured per trap when traps without the rough texture were baited with the leaf blend and manuka oil lures than on traps with texture and manuka oil but no leaf blend. In 2007, we also tested single prism traps set 1.5 m above ground and tower traps, similar to double-decker traps but 6 m tall. Double-decker traps baited with the leaf blend and manuka oil, with or without the addition of ash leaf and bark extracts, captured significantly more A. planipennis than similarly baited single prism traps, tower traps, or unbaited double-decker traps. A baited double-decker trap captured A. planipennis at a field site that was not previously known to be infested, representing the first detection event using artificial traps and lures. In 2008, we compared purple or green double-decker traps, single prisms suspended 3-5 m above ground in the ash canopy (canopy traps), and large flat purple traps (billboard traps). Significantly more A. planipennis were captured in purple versus green traps, baited traps versus unbaited traps, and double-decker versus canopy traps, whereas billboard traps were intermediate. At sites

Moisture effect on the dielectric response and space charge behaviour of mineral oil impregnated paper insulation

International Nuclear Information System (INIS)

Hao Jian; Liao Ruijin; Chen, George

2011-01-01

Dielectric response and space charge behaviour of oil-paper insulation sample with different moisture contents were investigated using the frequency dielectric spectroscopy (FDS) and the pulsed electroacoustic (PEA) technique, respectively. The influence of moisture on the dielectric response and space charge behaviour of oil impregnated paper insulation was analysed. Results show that the moisture has great effect on the FDS and space charge behaviour of oil impregnated paper insulation. In the frequency range of 10 -2 ∼10 6 Hz, the conductivity and the capacitance of oil impregnated paper increases with its moisture content. The space charge distribution of oil-paper sample with lower and higher moisture contents is very different from each other. The higher the moisture concentration of the oil impregnated paper, the easier the negative charge penetration into the insulation paper. There is a significant amount of positive charge accumulated at the paper-paper interface near to the cathode for oilpaper sample with lower moisture content. However, the positive charge appears in the middle layer paper for oil-paper sample with higher moisture content. Due to the high conductivity, the charge trapped in the oil-paper sample with higher moisture content disappears much faster than that in the oil-paper sample with lower moisture content after removing the voltage.

Moisture effect on the dielectric response and space charge behaviour of mineral oil impregnated paper insulation

Energy Technology Data Exchange (ETDEWEB)

Hao Jian; Liao Ruijin [State Key Laboratory of Power Transmission Equipment and System Security and New Technology, Chongqing University (China); Chen, George, E-mail: jh210v@ecs.soton.ac.uk [School of Electronics and Computer Science, University of Southampton (United Kingdom)

2011-08-12

Dielectric response and space charge behaviour of oil-paper insulation sample with different moisture contents were investigated using the frequency dielectric spectroscopy (FDS) and the pulsed electroacoustic (PEA) technique, respectively. The influence of moisture on the dielectric response and space charge behaviour of oil impregnated paper insulation was analysed. Results show that the moisture has great effect on the FDS and space charge behaviour of oil impregnated paper insulation. In the frequency range of 10{sup -2}{approx}10{sup 6}Hz, the conductivity and the capacitance of oil impregnated paper increases with its moisture content. The space charge distribution of oil-paper sample with lower and higher moisture contents is very different from each other. The higher the moisture concentration of the oil impregnated paper, the easier the negative charge penetration into the insulation paper. There is a significant amount of positive charge accumulated at the paper-paper interface near to the cathode for oilpaper sample with lower moisture content. However, the positive charge appears in the middle layer paper for oil-paper sample with higher moisture content. Due to the high conductivity, the charge trapped in the oil-paper sample with higher moisture content disappears much faster than that in the oil-paper sample with lower moisture content after removing the voltage.

Mineral oil; Mineraloel

Energy Technology Data Exchange (ETDEWEB)

Schult-Bornemann, Karl-Heinz [Magdeburg Univ. (Germany)

2015-07-01

The dominant theme in the world energy market was the fall in oil prices in 2014. From 115 US-$/bbl in June it dropped to below 50 US-$/bbl in January 2015. Thereby the shale oil revolution has had the strong impact on the global energy situation, to this point has been predicted for three years. Although no one could predict the exact height of the fall in oil prices, but with oil as a reserve currency for all other fuels, it has not only had an impact on the gas and coal prices, but other commodities, such as copper, have also yielded. About cause and effect, there is a lot of speculation - not all of which are supported by wisdom. [German] Das beherrschende Thema im Weltenergiemarkt war der Absturz des Rohoelpreises in 2014. Von 115 US-$/bbl im Juni sank er auf unter 50 US-$/bbl im Januar 2015. Damit hat die Schieferoelrevolution den kraeftigen Einfluss auf die Weltenergiesituation gehabt, der an dieser Stelle seit drei Jahren vorhergesagt wurde. Zwar konnte niemand die exakte Hoehe des Rueckgangs des Oelpreises prognostizieren, aber mit Oel als Leitwaehrung fuer alle anderen Energietraeger hat es nicht nur Einfluss auf den Gas- und Kohlepreis gehabt, sondern andere Rohstoffe, wie zum Beispiel Kupfer, haben ebenfalls nachgegeben. Ueber Ursache und Wirkung gibt es viele Spekulationen - nicht alle sind von Weisheit getragen.

Mineral statistics yearbook 1994

International Nuclear Information System (INIS)

1994-01-01

A summary of mineral production in Saskatchewan was compiled and presented as a reference manual. Statistical information on fuel minerals such as crude oil, natural gas, liquefied petroleum gas and coal, and of industrial and metallic minerals, such as potash, sodium sulphate, salt and uranium, was provided in all conceivable variety of tables. Production statistics, disposition and value of sales of industrial and metallic minerals were also made available. Statistical data on drilling of oil and gas reservoirs and crown land disposition were also included. figs., tabs

Lipoid pneumonia in children following aspiration of mineral oil used in the treatment of constipation: high-resolution CT findings in 17 patients

International Nuclear Information System (INIS)

Zanetti, Glaucia; Marchiori, Edson; Gasparetto, Taisa D.; Escuissato, Dante L.; Soares Souza, Arthur

2007-01-01

Exogenous lipoid pneumonia is a rare disorder caused by aspiration of mineral, vegetable and animal oils. High-resolution CT findings of lipoid pneumonia in children taking mineral oil for constipation have been rarely reported. To evaluate the high-resolution CT findings in 17 children with exogenous lipoid pneumonia following aspiration of mineral oil. The study included nine boys and eight girls, with ages ranging from 2 months to 9 years. All patients underwent high-resolution CT and the images were reviewed by two radiologists who reached decisions by consensus. The inclusion criteria were an abnormal radiograph, history of taking mineral oil and the presence of intrapulmonary lipids proved by bronchoalveolar lavage or open lung biopsy. The most common symptoms were cough (n = 13), mild fever (n = 11), and progressive dyspnea (n = 9). The main CT findings were air-space consolidations (100%), usually with areas of fatty attenuation (70.6%), areas of ground-glass attenuation (52.9%), and a crazy-paving pattern (17.6%), predominating bilaterally in the posterior and lower regions of the lungs. The high-resolution CT features in children with exogenous lipoid pneumonia are air-space consolidations and ground-glass attenuation, occasionally with a crazy-paving pattern, distributed bilaterally in the posterior and lower zones of the lungs. (orig.)

Lipoid pneumonia in children following aspiration of mineral oil used in the treatment of constipation: high-resolution CT findings in 17 patients

Energy Technology Data Exchange (ETDEWEB)

Zanetti, Glaucia [University of Rio de Janeiro, Department of Radiology, Rio de Janeiro (Brazil); Marchiori, Edson [University of Rio de Janeiro, Department of Radiology, University Federal Fluminense, Rio de Janeiro (Brazil); Gasparetto, Taisa D. [University Federal Fluminense, Department of Radiology, Rio de Janeiro (Brazil); Escuissato, Dante L. [University of Parana, Department of Radiology, Curitiba (Brazil); Soares Souza, Arthur [School of Medicine of Sao Jose do Rio Preto (ASSJ), Department of Radiology, Sao Jose do Rio Preto (Brazil)

2007-11-15

Exogenous lipoid pneumonia is a rare disorder caused by aspiration of mineral, vegetable and animal oils. High-resolution CT findings of lipoid pneumonia in children taking mineral oil for constipation have been rarely reported. To evaluate the high-resolution CT findings in 17 children with exogenous lipoid pneumonia following aspiration of mineral oil. The study included nine boys and eight girls, with ages ranging from 2 months to 9 years. All patients underwent high-resolution CT and the images were reviewed by two radiologists who reached decisions by consensus. The inclusion criteria were an abnormal radiograph, history of taking mineral oil and the presence of intrapulmonary lipids proved by bronchoalveolar lavage or open lung biopsy. The most common symptoms were cough (n = 13), mild fever (n = 11), and progressive dyspnea (n = 9). The main CT findings were air-space consolidations (100%), usually with areas of fatty attenuation (70.6%), areas of ground-glass attenuation (52.9%), and a crazy-paving pattern (17.6%), predominating bilaterally in the posterior and lower regions of the lungs. The high-resolution CT features in children with exogenous lipoid pneumonia are air-space consolidations and ground-glass attenuation, occasionally with a crazy-paving pattern, distributed bilaterally in the posterior and lower zones of the lungs. (orig.)

Mineral oil and synthetic hydrocarbons in cosmetic lip products.

Science.gov (United States)

Niederer, M; Stebler, T; Grob, K

2016-04-01

Lipsticks and lip care products may contain saturated hydrocarbons which either stem from mineral oil saturated hydrocarbons (MOSH) or are synthetic, that is polyolefin oligomeric saturated hydrocarbons (POSH). Some of these hydrocarbons are strongly accumulated and form granulomas in human tissues, which prompted Cosmetics Europe (former Colipa) to issue a recommendation for their use in lip care and oral products. From 2012 to 2014, MOSH+POSH were determined in 175 cosmetic lip products taken from the Swiss market in order to estimate their contribution to human exposure. Mineral oil saturated hydrocarbons and POSH were extracted and analysed by GC with FID. Areas were integrated as a total as well as by mass ranges with cuts at n-C25 and n-C34 to characterize the molecular mass distribution. About 68% of the products contained at least 5% MOSH+POSH (total concentration). For regular users, these products would be major contributors to their MOSH+POSH exposure. About 31% of the products contained more than 32% MOSH+POSH. Their regular usage would amount in an estimated MOSH+POSH exposure exceeding the highest estimated dietary exposure. The majority of the products contained hydrocarbons with a molecular mass range which was not in line with the recommendations of Cosmetics Europe. Taking into account that material applied to the lips largely ends up being ingested, MOSH and POSH levels should be reduced in the majority of cosmetic lip products. As the extensive evaluation of the data available on MOSH (EFSA J., 10, 2012, 2704) did not enable the specification of limits considered as safe, the present level of dietary exposure and its evaluation as 'of potential concern' provide the relevant bench mark, which means that lip products should contain clearly less than 5% MOSH+POSH. © 2015 Society of Cosmetic Scientists and the Société Française de Cosmétologie.

On the recovery of oil-polluted soils with mineral zeolite

International Nuclear Information System (INIS)

Rasulova, Z.Q.; Huseynzade, G.A.; Hajiyeva, S.A.

2014-01-01

Full text : The purpose of this study - ecological analysis of soil invertebrates in the oil-polluted soils and testing adsorbent for purificatication of such soils. In the study cenoses of Absheron 48 species of soil invertebrates belonging to 5 families, 13 orders, 24 families were revealed. For these purposes the local mineral -zeolite was applied. The results of experiments showed that refinement with zeolite makes positive impact on development of fauna of soil invertebrates. The studies were conducted in 2011-2013 in locally contaminated areas of oilfields of Absheron Peninsula. Radiation background in the studied areas ranges from 50-600 mR/hr

Mineral-Surfactant Interactions for Minimum Reagents Precipitation and Adsorption for Improved Oil Recovery

Energy Technology Data Exchange (ETDEWEB)

P. Somasundaran

2008-09-20

Chemical EOR can be an effective method for increasing oil recovery and reducing the amount of produced water; however, reservoir fluids are chemically complex and may react adversely to the polymers and surfactants injected into the reservoir. While a major goal is to alter rock wettability and interfacial tension between oil and water, rock-fluid and fluid-fluid interactions must be understood and controlled to minimize reagent loss, maximize recovery and mitigate costly failures. The overall objective of this project was to elucidate the mechanisms of interactions between polymers/surfactants and the mineral surfaces responsible for determining the chemical loss due to adsorption and precipitation in EOR processes. The role of dissolved inorganic species that are dependent on the mineralogy is investigated with respect to their effects on adsorption. Adsorption, wettability and interfacial tension are studied with the aim to control chemical losses, the ultimate goal being to devise schemes to develop guidelines for surfactant and polymer selection in EOR. The adsorption behavior of mixed polymer/surfactant and surfactant/surfactant systems on typical reservoir minerals (quartz, alumina, calcite, dolomite, kaolinite, gypsum, pyrite, etc.) was correlated to their molecular structures, intermolecular interactions and the solution conditions such as pH and/or salinity. Predictive models as well as general guidelines for the use of polymer/surfactant surfactant/surfactant system in EOR have been developed The following tasks have been completed under the scope of the project: (1) Mineral characterization, in terms of SEM, BET, size, surface charge, and point zero charge. (2) Study of the interactions among typical reservoir minerals (quartz, alumina, calcite, dolomite, kaolinite, gypsum, pyrite, etc.) and surfactants and/or polymers in terms of adsorption properties that include both macroscopic (adsorption density, wettability) and microscopic (orientation

Determination of mineral oil aromatic hydrocarbons in edible oils and fats by online liquid chromatography-gas chromatography-flame ionization detection - Evaluation of automated removal strategies for biogenic olefins.

Science.gov (United States)

Nestola, Marco; Schmidt, Torsten C

2017-07-07

The determination of mineral oil aromatic hydrocarbons (MOAH) in foodstuffs gained in importance over the last years as carcinogenicity cannot be excluded for certain MOAH. The existence of olefins in foodstuffs, such as edible oils and fats, can be problematic for the determination of MOAH by LC-GC-FID. Removal of these interfering substances by HPLC based on polarity differences is not possible. During gas chromatographic separation heavily overloaded peaks are observed rendering the detection of small mineral oil contaminations almost impossible. Therefore, removal of these olefins is necessary before subjection of the sample to LC-GC-FID. Epoxidation of olefins to increase their polarity proved to be a valuable tool in the past. Precision and trueness of the results as shown in a collaborative trial, however, are relying on exact reaction conditions. Additionally, it is known that certain MOAH are oxidized during epoxidation and therefore get lost. In the scope of this work, hydroboration, bromohydrin reaction, and epoxidation were examined for their potential for derivatization of unsaturated hydrocarbons with increased robustness and higher recovery of MOAH. Epoxidation by meta-chloroperoxybenzoic acid (mCPBA) delivered the best removal of olefins. Factors influencing this reaction were enlightened. Adaption of the reaction conditions and time-controlled automation increased the recovery of polycyclic MOAH. Good precision (RSD r oils spiked with a lubricating mineral oil (at 24.5mg/kg of MOAH). The trueness of the method was verified by analyzing collaborative trial samples. Copyright © 2017 Elsevier B.V. All rights reserved.

High-sensitive portable ASE-2 X-ray analyzer of sulfur in mineral oil

International Nuclear Information System (INIS)

Anchugov, I.S.; Goganov, A.D.; Plotnikov, R.I.

2007-01-01

The high-sensitivity ASE-2 analyzer of sulfur on the basis of existing ASE-I device is designed. ASE-2 analyzer realizes a standard method of energy dispersion X-ray fluorescent determinations of a sulfur mass fraction in mineral oil and allows to carry out the quantitative determination of sulfur in hydrocarbonic raw material and fuel in a 0.002-5 mass.% range [ru

The increasing importance of the oil issue in the Middle East by the 1970's. Oil and development: the trap of oil income in the Middle East

International Nuclear Information System (INIS)

Chatelus, Michel

2015-10-01

In a first article, after having recalled some aspects of the context of the Middle East during the second half of the 1960's and the first half of the 1970's, notably in terms of GDP and population in the different countries, the author comments how these countries tried to take possession of what they considered as their own oil, how some of them tried to reorganise oil production (notably Iraq and Syria) when others tried to act differently in collaboration with western companies or through specific bodies (OPEC). The author outlines that evolutions which occurred during this period (1960's-1970's) resulted in an unprecedented, brutal and uneven enrichment (particularly at the beginning of the 1970's) of oil producing states. He comments how oil was then used as a weapon against some western countries (first oil crisis), and that Arab countries also had different policies in terms of development, finance or reserve management. In the second article which addresses the fact that high oil incomes could become a trap, the author comments the consequences of the existence of high oil incomes. He discusses the policies adopted by Arab countries except Iraq: creation of a welfare economy, development of activities related to hydrocarbon availability, a minimum redistribution to other countries of the region, lucrative and safe investments, and requirements in terms of peacekeeping. Then, the author briefly comments the situation of countries of the regions. He distinguishes those which are not oil producers but are involved in wealth circulation and can take some profit out of it (Lebanon, Jordan), those which are excluded (Syria and Yemen), and the specific case of Iraq. He finally evokes the perspectives and contradictions of the growth scheme

Evaluation of low toxicity mineral oil base drilling fluids; Avaliacao de fluidos de perfuracao a base de oleo mineral de baixa toxidez

Energy Technology Data Exchange (ETDEWEB)

Ponte, Ielton Frederico da [PETROBRAS, Rio de Janeiro (Brazil). Centro de Pesquisas. Div. de Explotacao

1989-12-31

In order to introduce low toxicity mineral oil base drilling fluids in Brazil, we carried out a series with a low aromatic content basic oil for lubricants, produced by PETROBRAS: the Lubrax Industrial OB-9 (Lubind OB-9). This oil, as well as its mixture with aviation kerosene to reduce viscosity, was found adequate for use in drilling fluids together with other national products developed by companies that supply additives for drilling fluids in Brazil. We present the results of laboratory tests with systems of four different manufacturers, one of which was chosen for initial field tests. These tests, which were carried out at the Miranga and Bu River Fields, in the Drilling District of Bahia, produced satisfactory results. We anticipate the use of these fluids in other areas where the company operates. (author) 2 refs., 3 tabs.

Evaluation of low toxicity mineral oil base drilling fluids; Avaliacao de fluidos de perfuracao a base de oleo mineral de baixa toxidez

Energy Technology Data Exchange (ETDEWEB)

Ponte, Ielton Frederico da [PETROBRAS, Rio de Janeiro (Brazil). Centro de Pesquisas. Div. de Explotacao

1990-12-31

In order to introduce low toxicity mineral oil base drilling fluids in Brazil, we carried out a series with a low aromatic content basic oil for lubricants, produced by PETROBRAS: the Lubrax Industrial OB-9 (Lubind OB-9). This oil, as well as its mixture with aviation kerosene to reduce viscosity, was found adequate for use in drilling fluids together with other national products developed by companies that supply additives for drilling fluids in Brazil. We present the results of laboratory tests with systems of four different manufacturers, one of which was chosen for initial field tests. These tests, which were carried out at the Miranga and Bu River Fields, in the Drilling District of Bahia, produced satisfactory results. We anticipate the use of these fluids in other areas where the company operates. (author) 2 refs., 3 tabs.

Testing the ecotoxicology of vegetable versus mineral based lubricating oils: 1. Degradation rates using tropical marine microbes

International Nuclear Information System (INIS)

Mercurio, Philip; Burns, Kathryn A.; Negri, Andrew

2004-01-01

Vegetable-derived lubricants (VDL) might be more biodegradable than mineral-derived lubricants (MDL) due to the absence of high molecular weight aromatics, but this remains largely untested in tropical conditions. In this laboratory study, the degradation rates of 2-stroke, 4-stroke and hydraulic VDLs were compared with their MDL counterparts in the presence of mangrove and coral reef microbial communities. While MDLs were comprised largely of unresolved saturated and some aromatic hydrocarbons, their VDL counterparts contained, potentially more degradable, fatty acid methyl esters. Degradation of some VDL was observed by day 7, with the 2-stroke VDL markedly consumed by mangrove microorganisms and the hydraulic VDL degraded by both microorganism communities after this short period. All of the VDL groups were significantly more degraded than the comparable MDLs mineral oil lubricants over 14 days in the presence of either mangrove or coral reef microbial communities. In general the mangrove-sourced microorganisms more efficiently degraded the lubricants than reef-sourced microorganisms. - Vegetable-derived lubricants were more degradable than mineral oil lubricants

Testing the ecotoxicology of vegetable versus mineral based lubricating oils: 1. Degradation rates using tropical marine microbes

Energy Technology Data Exchange (ETDEWEB)

Mercurio, Philip; Burns, Kathryn A.; Negri, Andrew

2004-05-01

Vegetable-derived lubricants (VDL) might be more biodegradable than mineral-derived lubricants (MDL) due to the absence of high molecular weight aromatics, but this remains largely untested in tropical conditions. In this laboratory study, the degradation rates of 2-stroke, 4-stroke and hydraulic VDLs were compared with their MDL counterparts in the presence of mangrove and coral reef microbial communities. While MDLs were comprised largely of unresolved saturated and some aromatic hydrocarbons, their VDL counterparts contained, potentially more degradable, fatty acid methyl esters. Degradation of some VDL was observed by day 7, with the 2-stroke VDL markedly consumed by mangrove microorganisms and the hydraulic VDL degraded by both microorganism communities after this short period. All of the VDL groups were significantly more degraded than the comparable MDLs mineral oil lubricants over 14 days in the presence of either mangrove or coral reef microbial communities. In general the mangrove-sourced microorganisms more efficiently degraded the lubricants than reef-sourced microorganisms. - Vegetable-derived lubricants were more degradable than mineral oil lubricants.

Testing the ecotoxicology of vegetable versus mineral based lubricating oils: 2. Induction of mixed function oxidase enzymes in barramundi, Lates calcarifer, a tropical fish species

International Nuclear Information System (INIS)

Mercurio, Philip; Burns, Kathryn A.; Cavanagh, Joanne

2004-01-01

An increasing number of vegetable-based oils are being developed as environmentally friendly alternatives to petroleum products. However, toxicity towards key tropical marine species has not been investigated. In this study we used laboratory-based biomarker induction experiments to compare the relative stress of a vegetable-based lubricating oil for marine 2-stroke engines with its mineral oil-based counterpart on tropical fish. The sub-lethal stress of 2-stoke outboard lubricating oils towards the fish Lates calcarifer (barramundi) was examined using liver microsomal mixed function oxidase (MFO) induction assays. This study is the first investigation into the use of this key commercial species in tropical North Queensland, Australia in stress assessment of potential hydrocarbon pollution using ethoxyresorufin O-deethylase (EROD) induction. Our results indicated that barramundi provide a wide range of inducible rates of EROD activity in response to relevant organic stressors. The vegetable- and mineral-based lubricants induced significant EROD activity at 1.0 mg kg -1 and there was no significant difference between the two oil treatments at that concentration. At increasing concentrations of 2 and 3 mg kg -1 , the mineral-based lubricant resulted in slightly higher EROD activity than the vegetable-based lubricant. The EROD activity of control and treated barramundi are found to be within ranges for other species from temperate and tropical environments. These results indicate that vegetable-based lubricants may be less stressful to barramundi than their mineral counterparts at concentrations of lubricant ≥2 mg kg -1 . There is great potential for this species to be used in the biomonitoring of waterways around tropical North Queensland and SE Asia. - Vegetable-based lubricating oils appear to cause a tropical fish species less stress than mineral oils

Testing the ecotoxicology of vegetable versus mineral based lubricating oils: 2. Induction of mixed function oxidase enzymes in barramundi, Lates calcarifer, a tropical fish species

Energy Technology Data Exchange (ETDEWEB)

Mercurio, Philip; Burns, Kathryn A.; Cavanagh, Joanne

2004-05-01

An increasing number of vegetable-based oils are being developed as environmentally friendly alternatives to petroleum products. However, toxicity towards key tropical marine species has not been investigated. In this study we used laboratory-based biomarker induction experiments to compare the relative stress of a vegetable-based lubricating oil for marine 2-stroke engines with its mineral oil-based counterpart on tropical fish. The sub-lethal stress of 2-stoke outboard lubricating oils towards the fish Lates calcarifer (barramundi) was examined using liver microsomal mixed function oxidase (MFO) induction assays. This study is the first investigation into the use of this key commercial species in tropical North Queensland, Australia in stress assessment of potential hydrocarbon pollution using ethoxyresorufin O-deethylase (EROD) induction. Our results indicated that barramundi provide a wide range of inducible rates of EROD activity in response to relevant organic stressors. The vegetable- and mineral-based lubricants induced significant EROD activity at 1.0 mg kg{sup -1} and there was no significant difference between the two oil treatments at that concentration. At increasing concentrations of 2 and 3 mg kg{sup -1}, the mineral-based lubricant resulted in slightly higher EROD activity than the vegetable-based lubricant. The EROD activity of control and treated barramundi are found to be within ranges for other species from temperate and tropical environments. These results indicate that vegetable-based lubricants may be less stressful to barramundi than their mineral counterparts at concentrations of lubricant {>=}2 mg kg{sup -1}. There is great potential for this species to be used in the biomonitoring of waterways around tropical North Queensland and SE Asia. - Vegetable-based lubricating oils appear to cause a tropical fish species less stress than mineral oils.

Comparative study of the chemical composition and mineral element content of Artocarpus heterophyllus and Treculia africana seeds and seed oils.

Science.gov (United States)

Ajayi, Ibironke Adetolu

2008-07-01

A comparative study of Artocarpus heterophyllus and Treculia africana seeds, both of Moraceae family, was carried out to establish their chemical compositions and evaluate their mineral element content in order to investigate the possibility of using them for human and or animal consumption and also to examine if there is a relationship between the properties of these seeds. A. heterophyllus and T. africana are rich in protein; their protein contents are higher than those from high protein animal sources such as beef and marine fishes. Both seeds have high carbohydrate content and could act as source of energy for animals if included in their diets. The oil contents of the seeds are 11.39% and 18.54% for A. heterophyllus and T. africana, respectively. The oils are consistently liquid at room temperature. The results of the physicochemical properties of the two seeds are comparable to those of conventional oil seeds such as groundnut and palm kernel oils and could be useful for nutritional and industrial purposes. The seeds were found to be good sources of mineral elements. The result revealed potassium to be the prevalent mineral elements which are 2470.00 ppm and 1680.00 ppm for A. heterophyllus and T. africana, respectively followed by sodium, magnesium and then calcium. They also contain reasonable quantity of iron, in particular A. heterophyllus 148.50 ppm.

Recovery of asphalt from bituminous minerals

Energy Technology Data Exchange (ETDEWEB)

Jossinet, J

1881-12-31

A process is disclosed for the recovery of asphalt from bituminous minerals, consisting in that the mineral is extracted with mineral oil, which is recovered by distilling the raw asphalt and distilling the solution to obtain on the one hand the liquid oil contained in the raw asphalt for use in the extraction and on the other hand distilled asphalt.

Numerical modeling of injection and mineral trapping of CO2 withH2S and SO2 in a Sandstone Formation

Energy Technology Data Exchange (ETDEWEB)

Xu, Tianfu; Apps, John A.; Pruess, Karsten; Yamamoto, Hajime

2004-09-07

Carbon dioxide (CO{sub 2}) injection into deep geologic formations could decrease the atmospheric accumulation of this gas from anthropogenic sources. Furthermore, by co-injecting H{sub 2}S or SO{sub 2}, the products respectively of coal gasification or combustion, with captured CO{sub 2}, problems associated with surface disposal would be mitigated. We developed models that simulate the co-injection of H{sub 2}S or SO{sub 2} with CO{sub 2} into an arkose formation at a depth of about 2 km and 75 C. The hydrogeology and mineralogy of the injected formation are typical of those encountered in Gulf Coast aquifers of the United States. Six numerical simulations of a simplified 1-D radial region surrounding the injection well were performed. The injection of CO{sub 2} alone or co-injection with SO{sub 2} or H{sub 2}S results in a concentrically zoned distribution of secondary minerals surrounding a leached and acidified region adjacent to the injection well. Co-injection of SO{sub 2} with CO{sub 2} results in a larger and more strongly acidified zone, and alteration differs substantially from that caused by the co-injection of H{sub 2}S or injection of CO{sub 2} alone. Precipitation of carbonates occurs within a higher pH (pH > 5) peripheral zone. Significant quantities of CO{sub 2} are sequestered by ankerite, dawsonite, and lesser siderite. The CO{sub 2} mineral-trapping capacity of the formation can attain 40-50 kg/m{sup 3} medium for the selected arkose. In contrast, secondary sulfates precipitate at lower pH (pH < 5) within the acidified zone. Most of the injected SO{sub 2} is transformed and immobilized through alunite precipitation with lesser amounts of anhydrite and minor quantities of pyrite. The dissolved CO{sub 2} increases with time (enhanced solubility trapping). The mineral alteration induced by injection of CO{sub 2} with either SO{sub 2} or H{sub 2}S leads to corresponding changes in porosity. Significant increases in porosity occur in the acidified

Efficacy and Safety of a Mineral Oil-Based Head Lice Shampoo: A Randomized, Controlled, Investigator-Blinded, Comparative Study.

Directory of Open Access Journals (Sweden)

Luise Wolf

Full Text Available Due to increased resistance and safety concerns with insecticide-based pediculicides, there is growing demand for head lice treatments with a physical mode of action. Certain mineral oils kill lice by blocking spiracles or by disrupting the epicuticular wax layer. The present study was performed to evaluate efficacy and safety of a mineral oil-based shampoo.This randomized, controlled, investigator-blinded, monocentric study (EudraCT registration no. 2014-002918-23 was performed from October 2014-June 2015 in Germany. A mineral oil shampoo (Mosquito® Med Läuse Shampoo 10 in Germany, Paranix or Silcap shampoo elsewhere, registered as medical device, was compared to a conventional, locally reimbursed, pyrethroid-based pediculicide (Goldgeist® Forte solution. In total, 107 patients (>1 year with confirmed head lice infestation were included (test arm: n = 53; control arm: n = 54. All subjects received two applications of either test or control product at day 0 and day 7, according to the instructions for use. Efficacy and safety was evaluated directly, 1h and 24h after first application, before and after second treatment, and at day 10. The main objective was demonstrating a cure rate for the test product, being superior to 70% at day 10.Cure rates at day 10 (corrected for re-infestation for the test product (96.1% and control (94% significantly exceeded the pre-defined target (70% (p < 0.001, 2-sided, 1-sample, chi-square test with confirmed non-inferiority for the test product. Over all visits, cure rates were consistently higher for the test product, whereas more initially-cured subjects remained lice-free until end of study (78%; control: 60%. Both products were safe and well tolerated, offering good esthetical effects.This study showed that substance-based medical devices (including the tested mineral oil shampoo can be safe and effective alternatives for insecticide-based pediculicides, with less risk for development of resistance because

Treatment of Mineral Oil Refinery Wastewater in Microbial Fuel Cells Using Ionic Liquid Based Separators

Directory of Open Access Journals (Sweden)

Hasna Addi

2018-03-01

Full Text Available Microbial fuel cells (MFCs are an environmentally friendly technology that can recover electricity directly from several wastes at ambient temperatures. This work explores the use of mineral oil refinery wastewater as feedstock in single-chamber air-cathode MFC devices. A polymer inclusion membrane based on the ionic liquid methyltrioctylammonium chloride, [MTOA+][Cl−], at a concentration of 70% w/w, was used as separator, showing a good efficiency in power production and chemical oxygen demand (COD removal. The power and the chemical oxygen demand removal reached values of 45 mW/m3 and over 80%, respectively. The evolution of other parameters of the wastewater including nitrites, phosphates and sulphates were also studied. Kjeldahl nitrogen and sulphates were significantly reduced during MFC operation. The results show that mineral oil refinery wastewater can be used as feedstock in air breathing cathode-microbial fuel cells based on polymer ionic liquid inclusion membranes. This configuration could represent a good alternative for wastewater depuration while producing energy during the process.

Determination of optimum harvesting time for vitamin C, oil and mineral elements in berries sea buckthorn (hippophae rhamnoides)

International Nuclear Information System (INIS)

Arif, S.; Ahmed, S.D.; Shah, A.H.; Hassan, L.; Awan, S.I.; Hamid, A.; Batool, F.

2010-01-01

Sea buck thorn a magic plant from Northern areas of Pakistan has multiple uses against various ailments, soil enrichment and environmental purposes. The fruit berries are rich in vitamin C, vitamin A, vitamin E, essential oil, Phytosterol and minerals (Fe, Ca, P, Mn and K). The micro nutrient like vitamin C, oil, phosphorus, magnesium and calcium contents in fruit berries of cultivated sea buck thorn (Hippophae rhamnoides. L. spp. sinensis) harvested at three ripening times were determined using biochemical analysis techniques. Harvesting at different stages of fruit ripening was the primary factor determining maximum expression of these biochemical constituents. Biochemical contents were determined at three fruit developmental stages i.e., unripened stage, medium stage and at full-ripened stage. During this study a decline in vitamin C contents was observed along with the fruit ripening. The oil contents in both seed and pulp increased with fruit ripening. Similarly, the mineral contents like magnesium, calcium and phosphorus contents increases with the fruit ripening in sea buck thorn. The main idea was to identify the maximum expression of biochemical at different stages of fruit maturity. It is concluded that it is better to harvest fruit berries at medium stage of fruit ripening when maximum vitamin C is present. For maximum oil and mineral contents fruit must be harvested at ripening stage. The fruit mesocarp is the area where all genes related with micro nutrients are active at one time i.e., when fruit is maturing, hence the characterization of gene expression activities at this stage may help in the isolation of these genes for future commercial use. (author)

Theory and application of landfarming to remediate polycyclic aromatic hydrocarbons and mineral oil-contaminated sediments: beneficial reuse

NARCIS (Netherlands)

Harmsen, J.; Rulkens, W.H.; Sims, R.C.; Rijtema, P.E.; Zweers, A.J.

2007-01-01

When applying landfarming for the remediation of contaminated soil and sediment, a fraction of the soil-bound contaminant is rapidly degraded; however, a residual concentration may remain, which slowly degrades. Degradation of polycyclic aromatic hydrocarbons (PAHs) and mineral oil can be described

Water pollution potential of mineral oils with high content of polycyclic aromatic hydrocarbons (heavy fuel oil and neutral oil extracts); Untersuchungen zur Wassergefaehrdung durch Mineraloele mit hohen Gehalten an polycyclischen aromatischen Kohlenwasserstoffen (Heizoel Schwer und Extrakte)

Energy Technology Data Exchange (ETDEWEB)

Albers, G. [Mobil Schmierstoff GmbH, Hamburg (Germany)

1999-01-01

A data base on highly aromatic mineral oils has been compiled to classify mineral oil products according to their water-pollution potential (water hazard class or Wassergefaehrdungsklasse, WGK). This activity has been undertaken through the Commission for Water Hazardous Materials (Kommission Bewertung Wassergefaehrdender Stoffe, KBwS). In this special case, highly aromatic mineral oils containing a high concentration of polycyclic aromatic hydrocarbons (Polyaromatische Kohlenwasserstoffe, PAK) were evaluated. A test method for measuring the elution potential of PAK into water was developed on petroleum products with high viscosity and high freeze point. This method was applied to determine the solubility of 23 PAK (including 16 PAK according to EPA 610 and 6 PAK according to the German drinking water regulation (Trinkwasserverordnung, TVO)) from heavy fuel oil and neutral oil extract in the aqueous phase. For the 6 PAK, according to TVO, a sum limit of 0,2 {mu}g/l in drinking water is permitted by German legislation. This limit was not exceeded in any of the water phases examined. (orig.) [Deutsch] Fuer die Einstufung von Mineraloelprodukten in die Wassergefaehrdungsklassen (WGK) durch die Kommission Bewertung Wassergefaehrdender Stoffe ist es notwendig, Basisdaten zur Verfuegung zu stellen. Im speziellen Fall handelt es sich um die Bewertung von Mineraloelen, die sich durch einen hohen Gehalt an polycyclischen aromatischen Kohlenwasserstoffen (PAK) auszeichnen. Zur Eluierbarkeit von PAK`s aus Produkten mit hoher Viskosiaet bzw. mit hohem Stockpunkt wurde eine Pruefmethode entwickelt. Diese Methode wurde zur Bestimmung der Loeslichkeit von 23 PAK`s (16 PAK`s nach EPA-Liste incl. 6 PAK`s der TVO) aus den Mineraloelen Heizoel Schwer und Neutralextrakt in der Wasserphase eingesetzt. Fuer die PAK der TVO ist in der TVO ein Summengrenzwert von 0,2 {mu}g/l Trinkwasser angegeben. Dieser Grenzwert wurde in keiner der untersuchten Wasserphasen ueberschritten. (orig.)

Tribological Characteristics Evaluation of Mustard Oil Blends

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Mohammed Hassan Jabal

2018-03-01

Full Text Available A progressive increase in the desire for environmentally friendly lubricants by users and strict government regulations for the use of these lubricants has provided an opportunity to use plant oils as biodegradable lubricants, therefore vegetable oils have been investigated to replace oil lubricants because of their maintaining the conditions of nature (environment properties. In this paper, the influences of the blending ratio of mustard seeds oil with commercial mineral oil (SAE40 on the tribological characteristics were investigated and compared with mineral oil using the four-ball tribotester. Mustard seeds oil was blended with mineral oil at a volumetric ratio ranging from 22.5 to 90%. All experimental works were confirmed to ASTM D4172-B standard. The results exhibit that some blends of mustard seeds oil with mineral oil have lower wear scar diameter, friction torque, Friction coefficient and a higher parameter of flash temperature value compared to mineral oil and neat mustard seed oil. In conclusion, the mustard seed oil blend (MU22.5 shows a better anti-wear and anti-friction performance compared to oil samples. Therefore, mustard seeds oil has the potential to be used as a lubricant of mating surfaces.

Influence of the mineral composition of clay rocks on the stability of oil wells

International Nuclear Information System (INIS)

Amorocho, P. R; Badillo, Juan

2012-01-01

In the oil companies, the operation of drilling well bore could be more expensive if the composition of the rocks is clay, the cost could increase between 10 and 15% from the starting budget. In order to decrease this problem, the oil industry has spent too much money for developing mechanisms that can provide better control and stability in clay formations during the drilling. The Society Petroleum Engineers (SPE) in some researches have published that the main chemical effects that are involved in the interaction of perforation fluids and the clay formation are: 1) chemical osmosis; and 2) hydration stresses, although, there are others like: Capillary effects, dehydration, differences in pressure and cationic exchange. These factors are not present generally in independent form. At Piedemonte Llanero the problem of the well bore stability represents a high spending of money for oil companies, caused in this region by chemical factors between fluid/rock and mechanical factors as resulted of the stresses in the area. Metil Blue Testing (MBT) and X-ray Diffraction (DR-X) were made in samples of clay; these were taken from cuts extracted of boreholes drilled in some places of the Colombian Llanos. It was found that these samples had a moderate content of reactive and low content of swell minerals.The samples main component was kaolinite, this mineral does not let the rock get swell, but it produces caving in the hole. However, it is necessary to do other tests to quantify the damages and evaluate the influence of there gime of the stress during the perforation of well bore.

Cottonseed protein, oil, and mineral status in near-isogenic Gossypium hirsutum cotton lines expressing fuzzy/linted and fuzzless/linted seed phenotypes under field conditions

Directory of Open Access Journals (Sweden)

Nacer eBellaloui

2015-03-01

Full Text Available Cotton is an important crop in the world and is a major source of oil for human consumption and cotton meal for livestock. Cottonseed nutrition (seed composition: protein, oil, and minerals determine the quality of seeds. Therefore, maintaining optimum levels of cottonseed nutrition is critical. Physiological and genetic mechanisms controlling the levels of these constituents in cottonseed are still largely unknown. Our previous research conducted under greenhouse conditions showed that seed and leaf nutrition differed between fuzzless and fuzzy seed isolines. Therefore, the objective of this research was to investigate the seed fuzz phenotype (trait effects on seed protein, oil, N, C, S, and minerals in five sets of near-isogenic mutant cotton lines for seed fuzz in a two-year experiment under field condition to evaluate the stability of the effect of the trait on seed nutrition. The isolines (genotypes in each set differ for the seed fuzz trait (fuzzless/linted seed line, N lines, and fuzzy/linted seed line, F lines. Results showed that seed protein was higher in the fuzzy genotype in all sets, but seed oil was higher in fuzzless genotype in all sets. The concentrations of seed Ca and C were higher in all fuzzless genotypes, but N, S, B, Fe, and Zn were higher in most of the fuzzy genotypes. Generally, minerals were higher in leaves of F lines, suggesting the translocation of minerals from leaves to seeds was limited. The research demonstrated that fiber development could be involved in cottonseed composition. This may be due to the involvement of fiber development in carbon and nitrogen metabolism, and the mobility of nutrients from leaves (source to seed (sink. This information is beneficial to breeders to consider fuzzless cottonseed for potential protein and oil use and select for higher oil or higher protein content, and to physiologists to further understand the mobility of minerals to increase the quality of cottonseed nutrition for

Mineral catalysis of oil producing reactions in coal liquefaction

Energy Technology Data Exchange (ETDEWEB)

Shridharani, K.G.

1983-01-01

This work was concerned primarily with the development of a relatively inexpensive, readily available, high activity catalyst that can be used as a disposable catalyst in coal liquefaction processes. For a fair evaluation of the developmental mineral catalyst (presulfided iron oxide), it was necessary to determine at different stages of this work, whether catalyst inhibition, deactivation or activity was the limiting factor in coal liquefaction catalysis. First, different routes were explored to prepare a high hydrogenation activity, iron-based catalyst. Naphthalene hydrogenation was used as a model reaction to rate the hydrogenation activities of different additives. Presulfiding of iron oxide with H/sub 2/S, under controlled conditions, rendered the highest hydrogenation activity mineral catalyst, which had a hydrogenation activity even greater than that of commercial CoMo/Al/sub 2/O/sub 3/ catalyst sulfided with creosote oil and hydrogen. Sulfiding of CoMo/Al/sub 2/O/sub 3/ catalyst with H/sub 2/S remarkably improved its initial hydrogenation activity. Second, the catalyst inhibition and deactivation during liquefaction were studied. Liquefaction-process solvents contain a number of compounds that can either deactivate or inhibit the hydrogenation activity of a catalyst. Finally, the hydrocracking activity of the presulfided iron oxide catalyst was compared with that of commercial catalysts, CoMo/Al/sub 2/O/sub 3/ and low alumina FCC catalyst.

Gloves against mineral oils and mechanical hazards: composites of carboxylated acrylonitrile-butadiene rubber latex.

Science.gov (United States)

Krzemińska, Sylwia; Rzymski, Władysław M; Malesa, Monika; Borkowska, Urszula; Oleksy, Mariusz

2016-09-01

Resistance to permeation of noxious chemical substances should be accompanied by resistance to mechanical factors because the glove material may be torn, cut or punctured in the workplace. This study reports on glove materials, protecting against mineral oils and mechanical hazards, made of carboxylated acrylonitrile-butadiene rubber (XNBR) latex. The obtained materials were characterized by a very high resistance of the produced materials to oil permeation (breakthrough time > 480 min). The mechanical properties, and especially tear resistance, of the studied materials were improved after the addition of modified bentonite (nanofiller) to the XNBR latex mixture. The nanocomposite meets the requirements in terms of parameters characterizing tear, abrasion, cut and puncture resistance. Therefore, the developed material may be used for the production of multifunctional protective gloves.

The Influence of Water and Mineral Oil On Volumetric Losses in a Hydraulic Motor

Directory of Open Access Journals (Sweden)

Śliwiński Pawel

2017-04-01

Full Text Available In this paper volumetric losses in hydraulic motor supplied with water and mineral oil (two liquids having significantly different viscosity and lubricating properties are described and compared. The experimental tests were conducted using an innovative hydraulic satellite motor, that is dedicated to work with different liquids, including water. The sources of leaks in this motor are also characterized and described. On this basis, a mathematical model of volumetric losses and model of effective rotational speed have been developed and presented. The results of calculation of volumetric losses according to the model are compared with the results of experiment. It was found that the difference is not more than 20%. Furthermore, it has been demonstrated that this model well describes in both the volumetric losses in the motor supplied with water and oil. Experimental studies have shown that the volumetric losses in the motor supplied with water are even three times greater than the volumetric losses in the motor supplied with oil. It has been shown, that in a small constant stream of water the speed of the motor is reduced even by half in comparison of speed of motor supplied with the same stream of oil.

The Initial Rise Method in the case of multiple trapping levels

International Nuclear Information System (INIS)

Furetta, C.; Guzman, S.; Cruz Z, E.

2009-10-01

The aim of the paper is to extent the well known Initial Rise Method (IR) to the case of multiple trapping levels. The IR method is applied to the minerals extracted from Nopal herb and Oregano spice because the thermoluminescent glow curves shape suggests a trap distribution instead of a single trapping level. (Author)

The Initial Rise Method in the case of multiple trapping levels

Energy Technology Data Exchange (ETDEWEB)

Furetta, C. [Centro de Investigacion en Ciencia Aplicada y Tecnologia Avanzada, IPN, Av. Legaria 694, Col. Irrigacion, 11500 Mexico D. F. (Mexico); Guzman, S.; Cruz Z, E. [Instituto de Ciencias Nucleares, UNAM, A. P. 70-543, 04510 Mexico D. F. (Mexico)

2009-10-15

The aim of the paper is to extent the well known Initial Rise Method (IR) to the case of multiple trapping levels. The IR method is applied to the minerals extracted from Nopal herb and Oregano spice because the thermoluminescent glow curves shape suggests a trap distribution instead of a single trapping level. (Author)

Boron deprivation alters rat behaviour and brain mineral composition differently when fish oil instead of safflower oil is the diet fat source.

Science.gov (United States)

Nielsen, Forrest H; Penland, James G

2006-01-01

To determine whether boron deprivation affects rat behaviour and whether behavioural responses to boron deprivation are modified by differing amounts of dietary long-chain omega-3 fatty acids. Female rats were fed diets containing 0.1 mg (9 micromol)/kg boron in a factorial arrangement with dietary variables of supplemental boron at 0 and 3mg (278 micromol)/kg and fat sources of 75 g/kg safflower oil or 65 g/kg fish (menhaden) oil plus 10 g/kg linoleic acid. After 6 weeks, six females per treatment were bred. Dams and pups continued on their respective diets through gestation, lactation and after weaning. Between ages 6 and 20 weeks, behavioural tests were performed on 13-15 male offspring from three dams in each dietary treatment. The rats were euthanized at age 21 weeks for the collection of tissues and blood. At ages 6 and 19 weeks, auditory startle was evaluated with an acoustic startle system and avoidance behaviour was evaluated by using an elevated plus maze. At ages 7 and 20 weeks, spontaneous behaviour activity was evaluated with a photobeam activity system. A brightness discrimination test was performed on the rats between age 15 and 16 weeks. Brain mineral composition was determined by coupled argon plasma atomic emission spectroscopy. Plasma total glutathione was determined by HPLC and total cholesterol and 8-iso-prostaglandin F2alpha (8-iso-PGF2alpha) were determined by using commercially available kits. Boron-deficient rats were less active than boron-adequate rats when fed safflower oil based on reduced number, distance and time of horizontal movements, front entries, margin distance and vertical breaks and jumps in the spontaneous activity evaluation. Feeding fish oil instead of safflower oil attenuated the activity response to boron deprivation. In the plus maze evaluation, the behavioural reactivity of the boron-deficient rats fed fish oil was noticeably different than the other three treatments. They made more entries into both open and closed

Carbon dioxide sequestration in oil sands tailings streams

Energy Technology Data Exchange (ETDEWEB)

Mikula, R.; Afara, M.; Namsechi, B.; Demko, B.; Wong, P. [Natural Resources Canada, Devon, AB (Canada). CANMET Western Research Centre

2010-07-01

This PowerPoint presentation discussed the use of carbon dioxide (CO{sub 2}) as an oil sands tailings process aid and investigated its role in maximizing recycle water availability by rapid consolidation of the transition zone. The potential for CO{sub 2} sequestration was also investigated. CO{sub 2} composite tailings (CT) pilot plants were discussed and the results of cylinder tests and water chemistry analyses were presented. Issues related to physical entrapment, ionic trapping, and mineral trapping were discussed. The study showed that carbonic acid lowers pH, dissolving calcite and dolomite. Aluminum hydroxide groups on the clay surface reacted to produce water and Al{sup 3+} and Na+. Increased bicarbonate and calcium resulted in precipitated calcite. The reduction of a transition zone from 6 to 3 meters increased the available recycle water by 15 mm{sup 3} in a 5 km{sup 2} recycle water pond. Optimum CO{sub 2} additions to whole tailings are now being investigated. tabs., figs.

Effect of seed treatments on the chemical composition of two amaranth species: oil, sugars, fibres, minerals and vitamins

NARCIS (Netherlands)

Gamel, T.H.; Linssen, J.P.H.; Mesallam, A.S.; Damir, A.A.; Shekib, L.A.

2006-01-01

The effects of seed treatments, including cooking, popping, germination and flour air classification on several components of Amaranthus caudatus and A. cruentus seeds, including oil, sugars, fibre, minerals and vitamins were studied. The lipid, crude and dietary fibre, ash, and sugar contents were

Microfluidic acoustophoretic force based low-concentration oil separation and detection from the environment.

Science.gov (United States)

Wang, Han; Liu, Zhongzheng; Kim, Sungman; Koo, Chiwan; Cho, Younghak; Jang, Dong-Young; Kim, Yong-Joe; Han, Arum

2014-03-07

Detecting and quantifying extremely low concentrations of oil from the environment have broad applications in oil spill monitoring in ocean and coastal areas as well as in oil leakage monitoring on land. Currently available methods for low-concentration oil detection are bulky or costly with limited sensitivities. Thus they are difficult to be used as portable and field-deployable detectors in the case of oil spills or for monitoring the long-term effects of dispersed oil on marine and coastal ecosystems. Here, we present a low-concentration oil droplet trapping and detection microfluidic system based on the acoustophoresis phenomenon where oil droplets in water having a negative acoustic contrast factor move towards acoustic pressure anti-nodes. By trapping oil droplets from water samples flowing through a microfluidic channel, even very low concentrations of oil droplets can be concentrated to a detectable level for further analyses, which is a significant improvement over currently available oil detection systems. Oil droplets in water were successfully trapped and accumulated in a circular acoustophoretic trapping chamber of the microfluidic device and detected using a custom-built compact fluorescent detector based on the natural fluorescence of the trapped crude oil droplets. After the on-line detection, crude oil droplets released from the trapping chamber were successfully separated into a collection outlet by acoustophoretic force for further off-chip analyses. The developed microfluidic system provides a new way of trapping, detecting, and separating low-concentration crude oil from environmental water samples and holds promise as a low-cost field-deployable oil detector with extremely high sensitivity. The microfluidic system and operation principle are expected to be utilized in a wide range of applications where separating, concentrating, and detecting small particles having a negative acoustic contrast factor are required.

Trapping hydropyrolysates on silica and their subsequent desorption to facilitate rapid fingerprinting by GC-MS

Energy Technology Data Exchange (ETDEWEB)

Meredith, W.; Russell, C.A.; Cooper, M.; Snape, C.E. [Nottingham Univ. (United Kingdom). Fuel and Energy Centre; Love, G.D. [Newcastle upon Tyne Univ. (United Kingdom). School of Civil Engineering and Geosciences; Fabbri, D. [Universita di Bologna, Ravenna (Italy). Lab. di Chimica Ambientale; Vane, C.H. [British Geological Society, Keyworth (United Kingdom)

2004-01-01

Analytical hydropyrolysis performed under high hydrogen gas pressure (>10 MPa) has been demonstrated to possess the unique ability to release high yields of biomarker hydrocarbons covalently bound within the non-hydrocarbon macromolecular fraction of crude oils and source rocks. This study describes the development of the experimental procedure for trapping the product oils (hydropyrolysates) on silica to facilitate more convenient recovery than conventional collection and to allow analysis by thermal desorption-GC-MS without any prior work-up. Conventionally, the trap has consisted of a stainless steel coil, cooled with dry ice from which the products are recovered in organic solvents. Replacing this with a system in which the hydropyrolysates are adsorbed on a small mass of silica greatly reduces the turn-around time between tests, and aids the recovery and separation of the products. This method has been developed using an oil shale and an oil asphaltene fraction, with the silica trap producing very similar biomarker profiles to that from the conventional trap. The quantitative recovery of hydrocarbons from a light crude oil desorbed from silica under hydropyrolysis conditions demonstrates no significant loss of the high molecular weight n-alkanes (>n-C{sub 10}) for both trapping methods. The use of liquid nitrogen as the trap coolant results in significantly improved recovery of the lower molecular mass constituents. The silica trapping method allows for the hydropyrolysates to be characterised by thermal desorption-GC-MS, which has been investigated both on- and off-line. The oils undergo relatively little cracking during desorption, with similar n-alkane and biomarker profiles being obtained as with normal work-up and GC-MS analysis. Thus, in terms of fingerprinting geomacromolecules, ''hypy-thermal desorption-GC-MS'' appears to have the potential to be developed as an attractive alternative to traditional py-GC-MS. (author)

30 CFR 202.100 - Royalty on oil.

Science.gov (United States)

2010-07-01

... 30 Mineral Resources 2 2010-07-01 2010-07-01 false Royalty on oil. 202.100 Section 202.100 Mineral... Federal and Indian Oil § 202.100 Royalty on oil. (a) Royalties due on oil production from leases subject...) All oil (except oil unavoidably lost or used on, or for the benefit of, the lease, including that oil...

Gloves against mineral oils and mechanical hazards: composites of carboxylated acrylonitrile–butadiene rubber latex

Science.gov (United States)

Krzemińska, Sylwia; Rzymski, Władysław M.; Malesa, Monika; Borkowska, Urszula; Oleksy, Mariusz

2016-01-01

Resistance to permeation of noxious chemical substances should be accompanied by resistance to mechanical factors because the glove material may be torn, cut or punctured in the workplace. This study reports on glove materials, protecting against mineral oils and mechanical hazards, made of carboxylated acrylonitrile–butadiene rubber (XNBR) latex. The obtained materials were characterized by a very high resistance of the produced materials to oil permeation (breakthrough time > 480 min). The mechanical properties, and especially tear resistance, of the studied materials were improved after the addition of modified bentonite (nanofiller) to the XNBR latex mixture. The nanocomposite meets the requirements in terms of parameters characterizing tear, abrasion, cut and puncture resistance. Therefore, the developed material may be used for the production of multifunctional protective gloves. PMID:26757889

Oil prospection using the tectonic plate model

Science.gov (United States)

Pointu, Agnès

2015-04-01

sedimentation rate is necessary to bury organic matter and to restrict the mineralization. Consequences of crustal extension are also studied by using an experimental sand box model. The creation of faults is related to the subsidence of the margin. This subsidence allows the crossing of the oil window, leading to pyrolysis of organic matter and its transformation into oil. Afterwards, students compare the structures obtained after extension in their sand box to the actual organization of the Ghawar oil accumulation (seismic line). They can see that faults created by extension forces have not been preserved and can assume that compression forces have caused formation of the traps. An animation of paleo-location of continents during the upper Jurassic helps them to think that compression forces are linked to the closure of the Tethys Sea. A model using gravel and clay is used to show the principle of oil trapping. This way, students understand how the tectonic plate models explain the actual location of oil deposits and then how it can be used to look for new deposits.

76 FR 38673 - Environmental Documents Prepared for Proposed Oil, Gas, and Mineral Operations by the Gulf of...

Science.gov (United States)

2011-07-01

... the Survey, SEA M10-008. Gulf of Mexico. Coastal Technology Corporation, Located on the Atlantic 2/1.... Planning Areas of the Gulf of Mexico. Energy Resource Technology GOM, Matagorda Island, Block 2/3/2011 Inc... Environmental Documents Prepared for Proposed Oil, Gas, and Mineral Operations by the Gulf of Mexico Outer...

Carbon sequestration in depleted oil shale deposits

Science.gov (United States)

Burnham, Alan K; Carroll, Susan A

2014-12-02

A method and apparatus are described for sequestering carbon dioxide underground by mineralizing the carbon dioxide with coinjected fluids and minerals remaining from the extraction shale oil. In one embodiment, the oil shale of an illite-rich oil shale is heated to pyrolyze the shale underground, and carbon dioxide is provided to the remaining depleted oil shale while at an elevated temperature. Conditions are sufficient to mineralize the carbon dioxide.

The forming of coke by catalytic cracking of black mineral oil by catalysts on the base of activated aluminium alloys

International Nuclear Information System (INIS)

Mirzaeva, L.M.; Akhverdiev, R.B.; Aliev, Eh.T.; Gusejnova, A.D.; Gadzhi-Kasumov, V.S.; Akerson, V.I.; Sarmurzina, R.G.

1995-01-01

The paper deals with an investigation in coke formation under black mineral oil reactions on oxide catalysts which care based on activated aluminium alloys containing 2-20% of active components of In and Ga. The coke yield is of extreme nature and depends on the content of active components in the catalyst composition. The application of thermogravimetric method shows that the oxidation of coke depositions after black mineral oil cracking proceeds in the same temperature range while after the steam-water treatment of coked catalysts the oxidation of coke deposition proceeds at higher temperatures with different temperature maximums which points to the inhomogeneity of coke depositions. It is shown that the catalyst phase composition changes significantly during the reaction under the effect of reaction mixture. 4 refs., 3 figs

Fruit quality in the peach and nectarine with application of hydrogenated cyanamide and mineral oil

Directory of Open Access Journals (Sweden)

Sarita Leonel

Full Text Available This work evaluated the quality of the fruit in peach and nectarine cultivars with and without the application of hydrogenated cyanamide and mineral oil, for two production cycles (2009 and 2010. The experiment was carried out at the School of Agricultural Science of the São Paulo State University (UNESP, at Botucatu in the Brazilian state of São Paulo, located at latitude 22º51'55" S and longitude 48º26'22" E, at an altitude of 810 m. The predominant climate type is warm temperate (mesothermal with rains in the summer and dry in the winter. The following were evaluated: soluble solids, titratable acidity, pH, ratio, firmness, vitamin C and pulp yield. The use of hydrogenated cyanamide and mineral oil had no effect on the quality attributes of the fruit, except for pH, where those fruits under application of the products showed higher values. The cultivars all had a pulp yield greater than 90%, with 'Tourmaline' showing the highest yield (96 %. The levels of vitamin C varied according to the cultivars, where 'Marli' (16.9 mg 100 g-1 and 'Dourado-2' (16.5 mg 100 g-1, stood out for having the highest levels.

Reactivity of dolomite in water-saturated supercritical carbon dioxide: Significance for carbon capture and storage and for enhanced oil and gas recovery

International Nuclear Information System (INIS)

Wang Xiuyu; Alvarado, Vladimir; Swoboda-Colberg, Norbert; Kaszuba, John P.

2013-01-01

Highlights: ► Dolomite reactivity with wet and dry supercritical CO 2 were evaluated. ► Dolomite does not react with dry CO 2 . ► H 2 O-saturated supercritical CO 2 dissolves dolomite and precipitates carbonate mineral. ► Temperature/reaction time control morphology and extent of carbonate mineralization. ► Reaction with wet CO 2 may impact trapping, caprock integrity, and CCS/EOR injectivity. - Abstract: Carbon dioxide injection in porous reservoirs is the basis for carbon capture and storage, enhanced oil and gas recovery. Injected carbon dioxide is stored at multiple scales in porous media, from the pore-level as a residual phase to large scales as macroscopic accumulations by the injection site, under the caprock and at reservoir internal capillary pressure barriers. These carbon dioxide saturation zones create regions across which the full spectrum of mutual CO 2 –H 2 O solubility may occur. Most studies assume that geochemical reaction is restricted to rocks and carbon dioxide-saturated formation waters, but this paradigm ignores injection of anhydrous carbon dioxide against brine and water-alternating-gas flooding for enhanced oil recovery. A series of laboratory experiments was performed to evaluate the reactivity of the common reservoir mineral dolomite with water-saturated supercritical carbon dioxide. Experiments were conducted at reservoir conditions (55 and 110 °C, 25 MPa) and elevated temperature (220 °C, 25 MPa) for approximately 96 and 164 h (4 and 7 days). Dolomite dissolves and new carbonate mineral precipitates by reaction with water-saturated supercritical carbon dioxide. Dolomite does not react with anhydrous supercritical carbon dioxide. Temperature and reaction time control the composition, morphology, and extent of formation of new carbonate minerals. Mineral dissolution and re-precipitation due to reaction with water-saturated carbon dioxide may affect the contact line between phases, the carbon dioxide contact angle, and the

Efficacy and Safety of a Mineral Oil-Based Head Lice Shampoo: A Randomized, Controlled, Investigator-Blinded, Comparative Study.

Science.gov (United States)

Wolf, Luise; Eertmans, Frank; Wolf, Doerte; Rossel, Bart; Adriaens, Els

2016-01-01

Due to increased resistance and safety concerns with insecticide-based pediculicides, there is growing demand for head lice treatments with a physical mode of action. Certain mineral oils kill lice by blocking spiracles or by disrupting the epicuticular wax layer. The present study was performed to evaluate efficacy and safety of a mineral oil-based shampoo. This randomized, controlled, investigator-blinded, monocentric study (EudraCT registration no. 2014-002918-23) was performed from October 2014-June 2015 in Germany. A mineral oil shampoo (Mosquito® Med Läuse Shampoo 10 in Germany, Paranix or Silcap shampoo elsewhere), registered as medical device, was compared to a conventional, locally reimbursed, pyrethroid-based pediculicide (Goldgeist® Forte solution). In total, 107 patients (>1 year) with confirmed head lice infestation were included (test arm: n = 53; control arm: n = 54). All subjects received two applications of either test or control product at day 0 and day 7, according to the instructions for use. Efficacy and safety was evaluated directly, 1h and 24h after first application, before and after second treatment, and at day 10. The main objective was demonstrating a cure rate for the test product, being superior to 70% at day 10. Cure rates at day 10 (corrected for re-infestation) for the test product (96.1%) and control (94%) significantly exceeded the pre-defined target (70%) (p shampoo) can be safe and effective alternatives for insecticide-based pediculicides, with less risk for development of resistance because of the physical mode of action. German Clinical Trials Register (DRKS) DRKS00009753 and EudraCT database 2014-002918-23.

Distilling oil shale

Energy Technology Data Exchange (ETDEWEB)

Crozier, R H

1923-04-18

In the fractional distillation of oils from oil shale and similar materials the charge is passed continuously through a vertical retort heated externally by hot combustion gases in flues and internally by the passage of these gases through flues passing through the retort so that zones of increasing temperature are maintained. A vapor trap is provided in each zone having an exit pipe leading through a dust trap to a condenser. The bottoms of the conical vapor traps are provided with annular passages perforated to permit of steam being sprayed into the charge to form screens which prevent the vapors in different zones from mingling, and steam may also be introduced through perforations in an annular steam box. Dampers are provided to control the passage of the heating gases through the flues independently.

Biodegradation performance of environmentally-friendly insulating oil

Science.gov (United States)

Yang, Jun; He, Yan; Cai, Shengwei; Chen, Cheng; Wen, Gang; Wang, Feipeng; Fan, Fan; Wan, Chunxiang; Wu, Liya; Liu, Ruitong

2018-02-01

In this paper, biodegradation performance of rapeseed insulating oil (RDB) and FR3 insulating oil (FR3) was studied by means of ready biodegradation method which was performed with Organization for Economic Co-operation and Development (OECD) 301B. For comparison, the biodegradation behaviour of 25# mineral insulating oil was also characterized with the same method. The testing results shown that the biodegradation degree of rapeseed insulating oil, FR3 insulating oil and 25# mineral insulating oil was 95.8%, 98.9% and 38.4% respectively. Following the “new chemical risk assessment guidelines” (HJ/T 154 - 2004), which illustrates the methods used to identify and assess the process safety hazards inherent. The guidelines can draw that the two vegetable insulating oils, i.e. rapeseed insulating oil and FR3 insulating oil are easily biodegradable. Therefore, the both can be classified as environmentally-friendly insulating oil. As expected, 25# mineral insulating oil is hardly biodegradable. The main reason is that 25# mineral insulating oil consists of isoalkanes, cyclanes and a few arenes, which has few unsaturated bonds. Biodegradation of rapeseed insulating oil and FR3 insulating oil also remain some difference. Biodegradation mechanism of vegetable insulating oil was revealed from the perspective of hydrolysis kinetics.

30 CFR 281.8 - Rights to minerals.

Science.gov (United States)

2010-07-01

... 30 Mineral Resources 2 2010-07-01 2010-07-01 false Rights to minerals. 281.8 Section 281.8 Mineral Resources MINERALS MANAGEMENT SERVICE, DEPARTMENT OF THE INTERIOR OFFSHORE LEASING OF MINERALS OTHER THAN OIL, GAS, AND SULPHUR IN THE OUTER CONTINENTAL SHELF General § 281.8 Rights to minerals. (a) Unless...

On-road performance analysis of R134a/R600a/R290 refrigerant mixture in an automobile air-conditioning system with mineral oil as lubricant

International Nuclear Information System (INIS)

Ravikumar, T.S.; Mohan Lal, D.

2009-01-01

R134a has been accepted as the single major refrigerant in the automobile industry and it has been used worldwide. But, the problem associated with it is the use of the PAG oil as the lubricant. Unlike the conventional mineral oil, the synthetic PAG oil used with R134a is highly hygroscopic in nature. The PAG lubricants come with different additives unique for different compressors. This leads to serious service issues. Therefore, a refrigerant, which will be readily available to replace R12, and also compatible with mineral oil, is needed. In the present study the readily available R134a is used in place of R12. However, to avoid PAG oil and to use the conventional mineral oil as lubricant, R134a is mixed with the commercially available hydrocarbon blend, (45.2% R290 and 56.8% R600a) in the proportion of 91% and 9%, respectively by mass. The quantity of hydrocarbons used is well below the lower flammable limit. This new mixture R134a/R600a/R290 is tested in the air-conditioning system of a passenger car 'on road' in the true running conditions and compared with the results that has been obtained with R12. The cool down performance under varying speed and varying ambient conditions, system performance under severe accelerating conditions and bumper-to-bumper traffic conditions is studied. The test results show that the new blend can be a promising substitute for the existing R12 systems and it can eliminate the use of hygroscopic PAG oil.

Comparison of mineral oil and esters as cooling liquids in high voltage transformer in aspect of environment protection

OpenAIRE

Dombek Grzegorz; Goscinski Przemyslaw; Nadolny Zbigniew

2017-01-01

The article presents the results of computer simulation of temperature field of transformer filled with mineral oil and alternatives insulating liquids which include synthetic and natural esters. The analysis was based on the results of computer simulation of temperature field of 10 MVA distribution transformer, using the program COMSOL Multiphysics.

77 FR 55420 - Minerals Management: Adjustment of Cost Recovery Fees

Science.gov (United States)

2012-09-10

... mining, oil and gas extraction, and the mining and quarrying of nonmetallic minerals) as an individual...\\ New value \\4\\ New fee \\5\\ Oil & Gas (parts 3100, 3110, 3120, 3130, 3150) Noncompetitive lease... Leasing of Solid Minerals Other Than Coal and Oil Shale (parts 3500, 3580) Applications other than those...

Bio-derived fuels may ease the regeneration of diesel particulate traps

Energy Technology Data Exchange (ETDEWEB)

E. Coda Zabetta; M. Hupa; S. Niemi [Aabo Akademi Process Chemistry Centre, Turku (Finland)

2006-12-15

Particulate is the most problematic emission from diesel engines. To comply with environmental regulations, these engines are often equipped with particulate traps, which must be regenerated frequently for the sake of efficiency. The regeneration is commonly achieved by rising the temperature in the trap till the particulate self-ignites. However, this method implies energy losses and thermal shocks in the trap. Alternatively, catalysts and additives have been recently considered for reducing the ignition temperature of particulate, but these techniques suffer from poisoning and undesirable byproducts. The present experimental study shows that the ignition temperature of particulate from seed-derived oils (SO) and from blends of SO with diesel fuel oil (DO) can be lower than that of particulate from neat DO. If substantiated by more extensive studies, such finding could have noteworthy implications on the future of fuels and traps. Short communication. 8 refs., 3 figs., 2 tabs.

Porphyrin metabolism in lymphocytes of miners exposed to diesel exhaust at oil shale mine

Energy Technology Data Exchange (ETDEWEB)

Muzyka, V.; Bogovski, S.; Lang, I.; Schmidt, N.; Ryazanov, V.; Veidebaum, T. [Laboratory of Environmental Carcinogens, Institute of Experimental and Clinical Medicine, Hiiu 42, Tallinn 11619 (Estonia); Scheepers, P.T.J. [Department of Epidemiology and Biostatistics, University Medical Centre St Radboud, P.O. Box 9101, Nijmegen NL 6500 HB (Netherlands)

2004-04-25

The present study was carried out on the evaluation and application of new biomarkers for populations exposed to occupational diesel exhaust at oil shale mines. Since not only genotoxic effects may play an important role in the generation of tumors, the level of porphyrin metabolism was proposed as a biomarker of diesel exhaust exposure effects. The data on determination of 5-aminolevulinic acid (ALA) synthesis and heme formation in lymphocytes from groups of 50 miners exposed to diesel exhaust and 50 unexposed surface workers of oil shale mine are presented. All workers were examined and interviewed using structured questionnaires. The levels of benzene, carbon monoxide and nitric oxides in air as well as concentrations of 1-nitropyrene and elemental carbon in particulate matter were used for evaluation of exposure to diesel exhaust in mine. The levels of ALA and protoporphyrin (PP), activities of ALA synthetase (ALA-S) and ferrochelatase (FC), as well as levels of PP associated with DNA (PP/DNA) were investigated in lymphocytes spectrophotometrically. Significant differences in activity of ALA synthesis and heme formation between exposed miners and surface workers were found (207{+-}23 vs. 166{+-}14 pmol/10{sup 6} lymp./30' for ALA-S and 46.1{+-}3.8 vs. 54.8{+-}4.1 pmol/10{sup 6} lymp./60' for FC activities, respectively, P<0.001). ALA-S activity was higher and ALA accumulated in lymphocytes of exposed miners. Inhibition of FC activity caused PP cellular accumulation and an increase in the PP/DNA level (P<0.05). Tobacco smoking led to the increase of ALA biosynthesis in lymphocytes of both surface and underground smokers. The comparison of data obtained for non-smokers and smokers of both groups of workers has shown a significant difference (P<0.05). The work duration of underground or surface workers did not significantly influence the investigated biochemical parameters. The determination of ALA synthesis in lymphocytes could be a useful biomonitoring

Combination of complementary data mining methods for geographical characterization of extra virgin olive oils based on mineral composition.

Science.gov (United States)

Sayago, Ana; González-Domínguez, Raúl; Beltrán, Rafael; Fernández-Recamales, Ángeles

2018-09-30

This work explores the potential of multi-element fingerprinting in combination with advanced data mining strategies to assess the geographical origin of extra virgin olive oil samples. For this purpose, the concentrations of 55 elements were determined in 125 oil samples from multiple Spanish geographic areas. Several unsupervised and supervised multivariate statistical techniques were used to build classification models and investigate the relationship between mineral composition of olive oils and their provenance. Results showed that Spanish extra virgin olive oils exhibit characteristic element profiles, which can be differentiated on the basis of their origin in accordance with three geographical areas: Atlantic coast (Huelva province), Mediterranean coast and inland regions. Furthermore, statistical modelling yielded high sensitivity and specificity, principally when random forest and support vector machines were employed, thus demonstrating the utility of these techniques in food traceability and authenticity research. Copyright © 2018 Elsevier Ltd. All rights reserved.

Electron-trapping probability in natural dosemeters as a function of irradiation temperature

DEFF Research Database (Denmark)

Wallinga, J.; Murray, A.S.; Wintle, A.G.

2002-01-01

The electron-trapping probability in OSL traps as a function of irradiation temperature is investigated for sedimentary quartz and feldspar. A dependency was found for both minerals; this phenomenon could give rise to errors in dose estimation when the irradiation temperature used in laboratory...... procedures is different from that in the natural environment. No evidence was found for the existence of shallow trap saturation effects that Could give rise to a dose-rate dependency of electron trapping....

Outlook 96: Minerals and Energy

International Nuclear Information System (INIS)

1996-01-01

Papers discussing the future of Australia's minerals and energy are presented under the following headings: Australia in the global minerals and energy markets; minerals exploration; steelmaking raw materials; aluminium and alumina; gold; nickel; base metals; titanium minerals; energy for a sustainable future; electricity; electricity in Asia; crude oil; coal trade; natural gas in Australia and uranium. Relevant papers are individually indexed/abstracted. Tabs., figs., refs

Comparison of mineral oil and esters as cooling liquids in high voltage transformer in aspect of environment protection

Directory of Open Access Journals (Sweden)

Dombek Grzegorz

2017-01-01

Full Text Available The article presents the results of computer simulation of temperature field of transformer filled with mineral oil and alternatives insulating liquids which include synthetic and natural esters. The analysis was based on the results of computer simulation of temperature field of 10 MVA distribution transformer, using the program COMSOL Multiphysics.

Novel concepts for the containment of oil in flowing water

International Nuclear Information System (INIS)

Brown, H.M.; Nicholson, P.; Goodman, R.H.; Berry, B.A.; Hughes, B.R.

1993-01-01

Both a laboratory study of the hydrodynamic properties of variously shaped objects and a meso-scale flume study of several containment concepts have been undertaken to determine whether these can be used to contain oil in fast flowing water. The laboratory study showed that stable vortices are difficult to generate and that spilled oil is not easily trapped by them. Only two of the structures studied showed some promise of trapping oil in fast moving water: a partially submerged barrier with fins placed at an angle across the flume and a horizontal hydrofoil placed across the channel near the surface. Several filter materials were tested in an outdoor flowing channel with both floating and neutrally buoyant oil. Although some of these materials trapped and held heavy oil, they were not a significant improvement over nylon fishing nets which had been tested previously. The filter materials would not hold a medium gravity oil. A hydrofoil device which generated a horizontal eddy successfully trapped and held surface oil at water speeds up to 0.35 m/s. Neutrally buoyant oil was often caught by the eddy but was never held for more than 1-2 minutes. 9 refs., 5 figs., 3 tabs

Ferrofluid synthesis using oleic acid coated Fe3O4 nanoparticles dispersed in mineral oil for heat transfer applications

Science.gov (United States)

Imran, Mohd; Rahman Ansari, Akhalakur; Hussain Shaik, Aabid; Abdulaziz; Hussain, Shahir; Khan, Afzal; Rehaan Chandan, Mohammed

2018-03-01

Ferrofluids are stable dispersion of iron oxide nanoparticles in a carrier fluid which find potential applications in heat transfer. Fe3O4 nanoparticles of mean size in the range of 5–10 nm were synthesized using conventional co-precipitation method. This work deals with the synthesis of ferrofluids using mineral oil as a carrier fluid and oleic acid coated Fe3O4 nanoparticles as dispersed phase. Morphology (shape and size) and crystallinity of the synthesized nanoparticle is captured using TEM and XRD. Oleic acid coating on nanoparticle is probed using FTIR for confirming the stability of ferrofluid. Thermal properties of mineral oil based ferrofluid with varying concentration of nanoparticles are evaluated in terms of thermal conductivity. It was found that the thermal conductivity of ferrofluid increases upto 2.5% (w/v) nanoparticle loading, where a maximum enhancement of ∼51% in thermal conductivity was recorded as compared to the base fluid.

Use of nanoparticles to make mineral oil lubricants feasible for use in a residential air conditioner employing hydro-fluorocarbons refrigerants

Energy Technology Data Exchange (ETDEWEB)

Wang, Ruixiang [School of Energy and Power Engineering, Xi' an Jiaotong University 710049 Xi' an (China); School of Environment and Energy Engineering, Beijing University of Civil Engineering and Architecture, No. 1, Zhanlan Guan Road, Beijing 100044 (China); Wu, Qingping; Wu, Yezheng [School of Energy and Power Engineering, Xi' an Jiaotong University 710049 Xi' an (China)

2010-11-15

The application of nano-fluids in refrigerating systems is considered to be a potential way to improve the energy efficiency and reliability of HVAC and R facilities and to make economic the use of environment-friendly refrigerants. In this paper, we report a method that uses nanoparticles to enhance the energy efficiency of retrofitted residential air conditioners (RAC) employing HFCs as alternative refrigerants. The reliability and performance of RAC with nanoparticles in the working fluid have been investigated experimentally. A new mineral-based nano-refrigeration oil (MNRO), formed by blending some nanoparticles (NiFe{sub 2}O{sub 4}) into naphthene based oil B32, was employed in the RAC using R410a as refrigerant. A method showing how to disperse the NiFe{sub 2}O{sub 4} nanoparticles in the mineral oil refrigeration lubricants is presented together with an investigation of their stability. The solubilities of the new MNRO in R134a, R407C, R410a and R425a were measured. The performances of the RAC, such as the cooling/heating capacity, the power input and the energy efficiency ratio, were determined. The results indicate that the mixture of R410a/MNRO works normally in the RAC. The cooling/heating EER of the RAC increased about 6% by replacing the Polyol-Easter oil VG 32 lubricant with MNRO. (author)

78 FR 49945 - Minerals Management: Adjustment of Cost Recovery Fees

Science.gov (United States)

2013-08-16

..., oil and gas extraction, and the mining and quarrying of nonmetallic minerals) as an individual...\\ Increase \\3\\ New value \\4\\ New fee \\5\\ Oil & Gas (parts 3100, 3110, 3120, 3130, 3150) Noncompetitive lease... Solid Minerals Other Than Coal and Oil Shale (parts 3500, 3580) Applications other than those 35 34.99 0...

Carbonizing bituminous minerals

Energy Technology Data Exchange (ETDEWEB)

1921-05-01

A process for carbonizing bituminous minerals, like oil-shale, in a furnace with addition of air in the presence of heat-receiving material is characterized by the fact that to the feed such solid or liquid material (with the exception of oil) is added, which, through vaporization or heat-binding decomposition or conversion, hinders the establishment of excessive temperatures.

Mineralization of Carbon Dioxide: Literature Review

Energy Technology Data Exchange (ETDEWEB)

Romanov, V; Soong, Y; Carney, C; Rush, G; Nielsen, B; O' Connor, W

2015-01-01

CCS research has been focused on CO2 storage in geologic formations, with many potential risks. An alternative to conventional geologic storage is carbon mineralization, where CO2 is reacted with metal cations to form carbonate minerals. Mineralization methods can be broadly divided into two categories: in situ and ex situ. In situ mineralization, or mineral trapping, is a component of underground geologic sequestration, in which a portion of the injected CO2 reacts with alkaline rock present in the target formation to form solid carbonate species. In ex situ mineralization, the carbonation reaction occurs above ground, within a separate reactor or industrial process. This literature review is meant to provide an update on the current status of research on CO2 mineralization. 2

Dual-fuel production from restaurant grease trap waste: bio-fuel oil extraction and anaerobic methane production from the post-extracted residue.

Science.gov (United States)

Kobayashi, Takuro; Kuramochi, Hidetoshi; Maeda, Kouji; Tsuji, Tomoya; Xu, Kaiqin

2014-10-01

An effective way for restaurant grease trap waste (GTW) treatment to generate fuel oil and methane by the combination of physiological and biological processes was investigated. The heat-driven extraction could provide a high purity oil equivalent to an A-grade fuel oil of Japanese industrial standard with 81-93 wt% of extraction efficiency. A post-extracted residue was treated as an anaerobic digestion feedstock, and however, an inhibitory effect of long chain fatty acid (LCFA) was still a barrier for high-rate digestion. From the semi-continuous experiment fed with the residual sludge as a single substrate, it can be concluded that the continuous addition of calcium into the reactor contributed to reducing LCFA inhibition, resulting in the long-term stable operation over one year. Furthermore, the anaerobic reactor performed well with 70-80% of COD reduction and methane productivity under an organic loading rate up to 5.3g-COD/L/d. Copyright © 2014 Elsevier Ltd. All rights reserved.

Some basic properties of environmentally adapted oils

Energy Technology Data Exchange (ETDEWEB)

Hoeglund, E. [Div. of Machine Elements, Luleaa University of Technology (Sweden)

1998-11-01

Environmental concern has led to a development of lubricants that are less harmful to the environmental than traditional mineral based oils. Biodegradability and non-toxicity are desired properties together with a competitive price and if possible they should also be derived from renewable raw materials. In order to have a major breakthrough for the new, environmentally adapted lubricating oils they must perform well in mechanical and hydraulic systems. They must reduce wear, increase efficiency and reduce maintenance costs equally well, or preferably better than mineral based oils. This paper presents primary results from an investigation where four environmentally adapted oils (rape seed, pine tree, diester and TMP-ester) are compared to a conventional naphthenic mineral oil. Viscosity and viscosity-pressure coefficients, limiting shear stress, friction properties and film forming ability have been evaluated under elastohydrodynamic conditions. It was found that the mineral oil had the highest values of pressure-viscosity coefficient, limiting shear stress and coefficient of friction. Rape seed oil had the second highest pressure-viscosity coefficient but the lowest limiting shear stress and coefficient of friction. Pine tree oil, diester and TMP-ester formed an intermediate group with rather similar results. The Hamrock-Dowson equation for central film thickness was found to overestimate film thickness by about 10-20 per cent with the least discrepancy for the mineral oil. (orig.) 8 refs.

Fenologia, brotação de gemas e produção de frutos de macieira em resposta à aplicação de cianamida hidrogenada e óleo mineral Phenology, budbreak and apple fruit production by hydrogen cyanamide and mineral oil application

Directory of Open Access Journals (Sweden)

Fernando José Hawerroth

2009-01-01

, detecting this effects along of productive season became important. Thus, this study was carried out during 2007/2008 season, in Caçador, Santa Catarina State, Brazil, aiming to evaluate different hydrogen cyanamide and mineral oil combinations on phenology, budbreak and apple fruit production. The experimental design was a randomized block, with six replications, in factorial arrangement (5x2, with five budbreak promoter treatments (1. control; 2. mineral oil 3.2%; 3. mineral oil 3.2% + hydrogen cyanamide 0.20%; 4. mineral oil 3.2% + hydrogen cyanamide 0.39%; 5. mineral oil 3.2% + hydrogen cyanamide 0.59% and two cultivars (Imperial Gala and Suprema's Fuji. The budbreak promoters application anticipated and reduced the blooming period, increasing the blooming overlap between Imperial Gala and Suprema's Fuji cultivars. The budbreak promoters equalized and increased the budbreak in axillary and terminal buds, with the major budbreak level observed in Imperial Gala cultivar with 0.44% of hydrogen cyanamide and 3.2% of mineral oil treatment. The increase of hydrogen cyanamide concentration showed the tendency to decrease the fruit set. It was observed different treatment responses on production and mean fruit weight, probably to be related to fruit production predominance in different frutification structures.

76 FR 59058 - Minerals Management: Adjustment of Cost Recovery Fees

Science.gov (United States)

2011-09-23

... mining, oil and gas extraction, and the mining and quarrying of nonmetallic minerals) as an individual... increase New value New fee \\5\\ fee \\1\\ value \\2\\ \\3\\ \\4\\ Oil & Gas (parts 3100, 3110, 3120, 3130, 3150... interest transfer 60 61.94 0.84 62.78 65 Leasing of Solid Minerals Other Than Coal and Oil Shale (parts...

Minerals From the Marine Environment

Science.gov (United States)

Cruickshank, Michael J.

The current interest in minerals centering on, among other things, potential shortages, long-term needs, and deep seabed nodules, accentuates the usefulness and timeliness of this little book authored by a former chairman of the British National Environmental Research Council.In less than 100 pages, the author puts into perspective the potential for producing minerals from offshore areas of the world. After introducing the reader to the ocean environment and the extraordinary variety of the nature of the seabed, the author describes in some detail the variety of minerals found there. This is done in seven separate chapters entitled ‘Bulk and Non-Metallic Minerals From the Seas’ ‘Metals From the Shallow Seas’ ‘Metals From the Deep Oceans’ ‘Minerals From Solution’ ‘Oil and Gas from the Shallow Seas’ ‘Oil and Gas From Deep Waters’ and ‘Coal Beneath the Sea.’ The remaining chapters give a brief regional review of marine minerals distribution for eight areas of significant socioeconomic structure, and a short recapitulation of special problems of mineral recovery in the marine environment including such matters as the effect of water motion on mineral processing and of international law on investments. Glossaries of geological periods and technical terms, a short list of references, and an index complete the work.

Purifying mineral oils

Energy Technology Data Exchange (ETDEWEB)

Hood, J J

1919-02-24

A natural or an uncracked oil is desulfurized by vaporizing it and bringing the vapor into contact with granular alumina or ignited magnesite at a temperature below the boiling-point of sulfur. The alumina may be prepared from the trihydrate or bauxite. Sulfuretted hydrogen resulting from the dissociation of the sulfur compounds may be absorbed in oxide of iron, Weldon mud, or the like. Specifications 5,208/83, 14,405/92, 7,272/14, and 109,077 are referred to.

Optimization of pressurized liquid extraction (PLE) for rapid determination of mineral oil saturated (MOSH) and aromatic hydrocarbons (MOAH) in cardboard and paper intended for food contact.

Science.gov (United States)

Moret, Sabrina; Sander, Maren; Purcaro, Giorgia; Scolaro, Marianna; Barp, Laura; Conte, Lanfranco S

2013-10-15

Packaging can represent a primary source of food contamination with mineral oil saturated hydrocarbons (MOSH) and aromatic hydrocarbons (MOAH), especially when recycled cardboard or mineral oil based printing inks are used. A pressurized liquid extraction (PLE) method, followed by on-line LC-GC analysis, has been optimized for rapid mineral oil determination in cardboard and paper samples. The proposed method involves extraction with hexane (2 cycles) at 60°C for 5 min, and allows for the processing of up to 6 samples in parallel with minimal sample manipulation and solvent consumption. It gave good repeatability (coefficient of variation lower than 5%) and practically quantitative extraction yield (less than 2% of the total contamination found in a third separate cycle). The method was applied to different cardboards and paper materials intended for food contact. Results obtained were similar to those obtained by applying classical solvent extraction with hexane/ethanol 1:1 (v/v) as described by Lorenzini et al. [20]. Copyright © 2013 Elsevier B.V. All rights reserved.

Process for treating the dialyzed spent liquor from sulphonic acid containing sulfur minerals or tar oils or ammonium salts

Energy Technology Data Exchange (ETDEWEB)

Wernicke, E A

1936-08-09

Process for working up the dialyzate from sulfonic acid, sulfur-containing mineral or tar oils, or their ammonium salts, characterized by the combination of known steps, in the dialyzate being reacted with alkaline-earth oxide, hydroxide, or carbonate, and the resulting slightly soluble sulfate being filtered off and evaporated if necessary.

25 CFR 225.33 - Assignment of minerals agreements.

Science.gov (United States)

2010-04-01

... 25 Indians 1 2010-04-01 2010-04-01 false Assignment of minerals agreements. 225.33 Section 225.33 Indians BUREAU OF INDIAN AFFAIRS, DEPARTMENT OF THE INTERIOR ENERGY AND MINERALS OIL AND GAS, GEOTHERMAL, AND SOLID MINERALS AGREEMENTS Minerals Agreements § 225.33 Assignment of minerals agreements. An...

Oil Origin and Age

Directory of Open Access Journals (Sweden)

A.A. Barenbaum

2017-03-01

Full Text Available The question of oil age is discussed on the basis of the biosphere concept of oil and gas formation. It considers oil and gas deposits as underground carbon traps circulating through the Earth’s surface in the three main cycles of the circulation. A theoretical model has been developed that makes it possible to explain from these positions the phenomenon of replenishment of oil and gas deposits in the process of field development. The model provides a balance between carbon flows on the ascending and descending branches of its circulation through the Earth’s surface. In this model, the ascending flow of carbon is represented by the products of subsoil degassing (СН4, СО2 and extracted by the person from the depths of oil, gas and coal. A descending flow is an organic matter and carbonates that are submerged in the subsoil in the processes of sedimentation and subduction of lithospheric plates, as well as atmospheric COsub>2, entering the Earth’s surface with meteoric waters in the process of their climatic circulation. Since the fields are filled with hydrocarbons formed in cycles of carbon with widely differing circulation times, instead of the term ‘age of oil’, it is suggested to use the terms ‘trap formation time’ and ‘hydrocarbon life time in the trap’. This approach to the question of oil age in the biosphere concept leads to a number of conclusions, from which it follows that: 1 the ‘old’ petroleum of biogenic genesis is extracted at the initial stage of the development of deposits, whereas in the depletion stage the ‘young’ hydrocarbons of abiogenic synthesis prevail; 2 the age of industrial accumulations of oil on our planet is hardly older than the Pleistocene, while gaseous, liquid and bituminous fractions of oil have different lifetimes in traps.

ANTIOXIDANT CAPACITY, MINERAL CONTENT AND ESSENTIAL OIL COMPOSITION FROM SELECT ALGERIAN MEDICINAL PLANTS

Directory of Open Access Journals (Sweden)

Hadjira Guenane1

2017-10-01

Full Text Available The objective of the present study was to analyze the total antioxidant capacity, minerals contents of four plants (Juniperus oxycedrus, Thymus capitatus, Laurus nobilis and Eruca vesicaria and chemical composition of the essential oils of the aerial parts of T. capitatus. Their antioxidant activity was assessed by DPPH, ABTS and FRAPS assays. Total phenol and flavonoid contents of the extracts were also determined. The results showed that the L. nobilis extract had the highest total phenolic and flavonoids contents (19.11 ± 0.22 mg GAE•g-1 dw, 4.47 ± 0.12 mg QE•g-1 dw, respectively. The extract of E. vesicaria had the highest value of TEAC for scavenging DPPH, whereas L. nobilis extract was active for ABTS and FRAP. GC/MS analysis revealed that the essential oil from the aerial parts of T. capitatus contained thirty-seven compounds; thymol was the major constituent (82.79 %. Atomic absorption spectroscopy showed high levels of Ca, K, Mg and Fe, and trace amounts of Zn, Cu and Mn in all four extracts.

The containment of heavy oil in flowing water

International Nuclear Information System (INIS)

Brown, H.M.; Goodman, R.H.; Nicholson, P.

1992-01-01

Viscous bitumen from Alberta oil sand deposits is diluted with a gas condensate before pipeline transport. Because of its unique properties, the diluent/bitumen mix (dilbit) may require novel containment and recovery techniques in the case of an accidental spill. Preliminary experiments were conducted in a large flowing water channel to determine whether several conventional containment devices could be utilized to trap weathered and emulsified dilbit and bitumen. These devices included a conventional river boom, a nylon fine-weave net, and a low-pressure bubble barrier. The behavior of the oil samples during boom failure was noted in order to understand more completely the mechanisms of failure. The river boom failed to hold viscous floating oil by vortex shedding at flows of under 0.25 m/s. A fine mesh net successfully trapped both floating and mid-channel neutrally buoyant oil but the retention time depends on the oil viscosity. The bubble barrier was not successful in trapping either floating viscous oil or neutrally buoyant oil. At low water velocities, the barrier was able to divert some oils but in an inconsistent manner. The results indicate that conventional barriers need improvement to be effective at higher water velocities and suggest that new concepts in containment should be considered. 9 refs., 3 figs., 2 tabs

Short and long term modulation of tissue minerals concentrations following oral administration of black cumin (Nigella sativa L.) seed oil to laboratory rats.

Science.gov (United States)

Basheer, Irum; Qureshi, Irfan Zia

2018-01-15

Nigella sativa, or commonly called black cumin is a small herb of family Ranunculaceae is a well-known medicinal plant but its effects on tissue mineral concentrations of animal bodies is unknown. To study the effect of oral administration of fixed oil of black cumin seeds on tissues mineral content using laboratory rats as experimental model. Experimental animals were exposed to two oral doses of seed oil (60 and 120 ml kg -1 body weight). Short- and long term experiments lasted 24 h and 60 days respectively, with three replicates each. Oil extracted from black cumin seeds was subjected to GC-MS to identify chemical components. Following the wet digestion in nitric acid, samples of whole blood and organs of rats were subjected to atomic absorption spectrophotometry for determination of elements concentrations. Data were compared statistically at p < .05. Compared to control, Cr, Mn, Ni, Cu, Zn showed decrease, whereas Co, Na, Mg and K demonstrated increase, but Ca showed both increase and decrease in most of the tissues upon short term exposure to low and high doses of black cumin oil. During long term exposure, Cr, Fe, Mn, Cu exhibited decrease; Co, Na, Mg and Ca concentrations demonstrated an upregulation, whereas Ni and Zn showed increase and decrease in most of the tissues. Comparison of short term with long term experiments at low dose revealed increases in Fe, Zn, Cu, Mg, K and Ca, a decrease in Cr, Mn, Ni and Cu in most tissues, but both increase and decrease in Na. At high dose, an increase occurred in Fe, Ni, Zn, K, Ca, Mg, a decrease in Cr, while both increase and decrease in Cu, Co and Na concentrations. Our study demonstrates that oral administration of black cumin seeds oil to laboratory rats significantly alters tissue trace elements and electrolytes concentrations. The study appears beneficial but indicates modulatory role of black cumin oil as regards mineral metabolism with far reaching implications in health and disease. Copyright © 2017

30 CFR 256.80 - Leases of other minerals.

Science.gov (United States)

2010-07-01

... 30 Mineral Resources 2 2010-07-01 2010-07-01 false Leases of other minerals. 256.80 Section 256.80 Mineral Resources MINERALS MANAGEMENT SERVICE, DEPARTMENT OF THE INTERIOR OFFSHORE LEASING OF SULPHUR OR OIL AND GAS IN THE OUTER CONTINENTAL SHELF Section 6 Leases § 256.80 Leases of other minerals. The...

Spilt oil mineralization and influence upon marine organisms

International Nuclear Information System (INIS)

Tokuda, Hiroshi

1991-01-01

Several months have elapsed since the end of the Gulf War, and in spite of the efforts of specialists and workers, several hundreds oil fields are still burning, and coasts are smeared with oil. The effect that oil field fires exerted to the atmosphere and global environment is set aside, and in this report, the decomposition of oil spilled into the sea and its effect exerted to living things are discussed. The oil quantity flowed out from the valve for loading tankers was difficult to estimate, but it seemed 3 or 4 million barrels. Spilled durable oil impairs the amenity. The process of oil decomposition, the presence of the bacteria decomposing hydrocarbon in the sea, the factors affecting the microorganism decomposition, the capability of oil decomposition in Japanese coastal areas, and the final products of oil decomposition are reported. The effects that spilled oil exerted to marine plants, animals, the drowning of sea birds, the disturbance of information transmission and the ecosystem that does not recover are described. When useful marine living things are restored to the original state, marine product industry can declare the end of pollution, but on the ecosystem, the declaration of end does not exist. (K.I.)

Converting heavy oils into light oils, etc

Energy Technology Data Exchange (ETDEWEB)

Mony, H

1915-12-22

A process is described for transforming heavy oils obtained by the carbonization of lignites, peats, coals, shales into light oils, and also the heavy oils of mineral and vegetable origin, consisting of heating the heavy oils or tars in the presence of one or more solid substances or liquids suitably chosen to cause the distillation of the oils under atmospheric pressure at an appropriate temperature; solid and liquid substances which favor the production of light products under the influence of heat being added preferably to the oil to be treated before putting it in the retort and before heating, so that light oils are obtained by treatment of the heavy oils in a single operation.

Use of Bio-Amp, a commercial bio-additive for the treatment of grease trap wastewater containing fat, oil, and grease.

Science.gov (United States)

Tang, Hao L; Xie, Yuefeng F; Chen, Yen-Chih

2012-11-01

This research investigated the application of Bio-Amp, a commercial bio-additive for the treatment of fat, oil, and grease (FOG) in a grease trap, and evaluated potential impacts of treated effluent on downstream collection system and treatment processes. Results show that after Bio-Amp treatment, FOG deposit formation was reduced by 40%, implicating a potential reduction of sewer line blockages. Chemical oxygen demand (COD), total nitrogen (TN), total phosphorus (TP) and total fatty acids were reduced by 39%, 33%, 56%, and 59%, respectively, which represents an overall loading reduction of 9% COD, 5% TN and 40% TP received by the treatment plant from all the dining halls. On the other hand, readily biodegradable COD fractions significantly increased, which implies a potential improvement on Bio-P removal. Overall, the results showed that application of Bio-Amp in grease trap provides potential reduction of sewer line blockages, and can also alleviate downstream treatment burden. Copyright © 2012 Elsevier Ltd. All rights reserved.

Destabilization of emulsions by natural minerals.

Science.gov (United States)

Yuan, Songhu; Tong, Man; Wu, Gaoming

2011-09-15

This study developed a novel method to destabilize emulsions and recycle oils, particularly for emulsified wastewater treatment. Natural minerals were used as demulsifying agents, two kinds of emulsions collected from medical and steel industry were treated. The addition of natural minerals, including artificial zeolite, natural zeolite, diatomite, bentonite and natural soil, could effectively destabilize both emulsions at pH 1 and 60 °C. Over 90% of chemical oxygen demand (COD) can be removed after treatment. Medical emulsion can be even destabilized by artificial zeolite at ambient temperature. The mechanism for emulsion destabilization by minerals was suggested as the decreased electrostatic repulsion at low pH, the enhanced gathering of oil microdroplets at elevated temperature, and the further decreased surface potential by the addition of minerals. Both flocculation and coalescence were enhanced by the addition of minerals at low pH and elevated temperature. Copyright © 2011 Elsevier B.V. All rights reserved.

Effect of insulin combined alendronate sodium on bone mineral density and levels of serum BAP, TRAP-5b and BGP in aged patients with type 2 diabetes mellitus with osteoporosis

Directory of Open Access Journals (Sweden)

Fang Wang

2016-06-01

Full Text Available Objective: To explore the effect of insulin combined alendronate sodium on bone mineral density and levels of serum BAP, TRAP-5b and BGP in aged patients with type 2 diabetes mellitus with osteoporosis. Methods: A total of 136 patients with type 2 diabetes mellitus with osteoporosis in January 2014 to January 2016 in our hospital for the treatment were selected, and randomly divided into 4 groups, each of 40 cases. Caltrate D was given as a basic treatment to all the patients, and the control group was given the treatment of insulin, and the metformin group was given the treatment of metformin, and the combination group was given the treatment of metformin combined alendronate, and the experiment group was given the treatment of insulin combined alendronate. BMD of the femoral neck and the serum levels of BAP, TRAP-5b and BGP were detected and recorded before the treatment and after one year’s treatment. Results: On index of bone mineral density, the control group and the metformin group showed no significant differences; the combination group was slightly improved, but showed no statistical significance; After the treatment, the bone mineral density of the experiment was significantly improved. On index of bone turnover, the levels of serum BAP and BGP all had been improved and the level of TRAP-5b all was reduced then before the treatment in the control group, the combination group and the experiment group, but only the experiment group showed significant differences; On index of bone turnover, the experiment group were better than other groups, the differences were statistical significant. Conclusions: It has greater clinical curative effect that insulin combined alendronate sodium in the treatment of aged patients with type 2 diabetes mellitus with osteoporosis, it can effectively balance the metabolism of bone, safe and reliable, and it is worthy of application.

Distilling mineral oils

Energy Technology Data Exchange (ETDEWEB)

Henderson, N M

1885-10-29

Stills of waggon-shape with side flues are employed; the legs are sheltered from the direct furnace heat, and apparatus for injecting steam into them is provided. The feed pipe to the primary still is vertical; as the more volatile portions of the oil evaporate the heavier portions sink into the legs from which they are drawn off by pipes entering secondary stills horizontally. In the same manner the heavier portions are removed from these stills to coking ovens. A feed-heating apparatus of the kind described in Specification No. 540, A.D. 1883, is employed.

Comparison of trap types and colors for capturing emerald ash borer adults at different population densities.

Science.gov (United States)

Poland, Therese M; Mccullough, Deborah G

2014-02-01

Results of numerous trials to evaluate artificial trap designs and lures for detection of Agrilus planipennis Fairmaire, the emerald ash borer, have yielded inconsistent results, possibly because of different A. planipennis population densities in the field sites. In 2010 and 2011, we compared 1) green canopy traps, 2) purple canopy traps, 3) green double-decker traps, and 4) purple double-decker traps in sites representing a range of A. planipennis infestation levels. Traps were baited with cis-3-hexenol in both years, plus an 80:20 mixture of Manuka and Phoebe oil (2010) or Manuka oil alone (2011). Condition of trees bearing canopy traps, A. planipennis infestation level of trees in the vicinity of traps, and number of A. planipennis captured per trap differed among sites in both years. Overall in both years, more females, males, and beetles of both sexes were captured on double-decker traps than canopy traps, and more beetles of both sexes (2010) or females (2011) were captured on purple traps than green traps. In 2010, detection rates were higher for purple (100%) and green double-decker traps (100%) than for purple (82%) or green canopy traps (64%) at sites with very low to low A. planipennis infestation levels. Captures of A. planipennis on canopy traps consistently increased with the infestation level of the canopy trap-bearing trees. Differences among trap types were most pronounced at sites with low A. planipennis densities, where more beetles were captured on purple double-decker traps than on green canopy traps in both years.

Experimental Precipitation of Carbonate Minerals: Effect of pH, Supersaturation and Substrate

OpenAIRE

Tetteh, Abednego

2012-01-01

Understanding the controlling factors and elucidating the requirements and conditions necessary for carbon dioxide (CO2) storage by mineral trapping (or carbonation) is of paramount interest for any technical application as a means for carbon dioxide capture and storage (CCS). The effect of pH, supersaturation and substrate has been studied using non-stirred batch reactors at initial constant temperature of 150 oC. These conditions are relevant for mineral trapping. A set of experiments was c...

Minerals industry survey, 1984

Energy Technology Data Exchange (ETDEWEB)

1984-01-01

This is the seventh edition of the statistical survey commissioned by the Australian Mining Industry Council. It represents the most comprehensive review of the financial position of the Australian minerals industry and provides timely financial data on the minerals industry. The tables of this survey have been prepared for AMIC by Coopers and Lybrand, Chartered Accountants, based on information supplied to them in confidence by the respondent companies. For the purpose of the survey, the minerals industry has been defined as including exploration for, and extraction and primary processing of, minerals in Australia. The oil and gas industry is not included.

Application of Thermal Desorption Unit (TDU) to treat low-toxicity mineral oil base cuttings in Barinas District, Venezuela

Energy Technology Data Exchange (ETDEWEB)

Rendon, Ruben [Petroleos de Venezuela, Caracas (Venezuela); Luzardo, Janeth; Alcoba, Alcides [M-I SWACO, Houston, TX (United States)

2008-07-01

The potential environmental impact of oil-based drill cuttings is generating increased scrutiny in the oil and gas industry. If left untreated, oil-based cuttings not only increase the risk of environmental liabilities, but also affect revenue, as drilling generates wastes that in most cases require special treatment before disposal. Consequently, the oil industry is looking for technologies to help minimize environmental liabilities. Accordingly, the Barinas District of PDVSA has started a pilot trial to treat oil-based drilling cuttings by applying thermal desorption technology. The main objective of this technology is recovering trapped hydrocarbons, while minimizing wastes and preparing solids to be disposed of through a mobile treatment plant. This novel technology has been used worldwide to treat organic pollutants in soil. Thermal desorption is a technology based on the application of heat in soils polluted with organic compounds. With this technology, target temperatures vary according to the type and concentration of detected pollutants along with its characterization, in such a way that compounds are disposed of by volatilization. As part of the integral waste management development along with the pilot trial for hydrocarbon-contaminated solid waste treatment, trials on soils were undertaken by applying process-generated ashes in equally-sized bins, with different mixtures (ashes, ashes organic material, ashes-organic material-sand, ashes-land). The resulting process offers an immediate soil remediation and final disposal solution for toxic and dangerous waste. (author)

Theoretical investigation of isotope exchange reaction in tritium-contaminated mineral oil in vacuum pump

Energy Technology Data Exchange (ETDEWEB)

Dong, Liang; Xie, Yun [Institute of Nuclear Physics and Chemistry, China Academy of Engineering Physics, Mianyang 621900 (China); Du, Liang [Institute of Nuclear Physics and Chemistry, China Academy of Engineering Physics, Mianyang 621900 (China); School of Radiation Medicine and Protection (SRMP), School for Radiological and Interdisciplinary Sciences (RAD-X), Suzhou 215000 (China); Li, Weiyi [School of Physics and Chemistry, Xihua University, Chengdu 610065 (China); Tan, Zhaoyi, E-mail: zhyitan@126.com [Institute of Nuclear Physics and Chemistry, China Academy of Engineering Physics, Mianyang 621900 (China)

2015-04-28

Highlights: • This is the first theoretical investigation about T–H exchange in vacuum oil. • T–H isotope exchange is accomplished through two different change mechanisms. • Isotope exchange is selective, molecules with −OH and −COOH exchange more easily. • The methyl and methylene radicals in waste oil were observed by {sup 1}HNMR. - Abstract: The mechanism of the isotope exchange reaction between molecular tritium and several typical organic molecules in vacuum pump mineral oil has been investigated by density functional theory (DFT), and the reaction rates are determined by conventional transition state theory (TST). The tritium–hydrogen isotope exchange reaction can proceed with two different mechanisms, the direct T–H exchange mechanism and the hyrogenation–dehydrogenation exchange mechanism. In the direct exchange mechanism, the titrated product is obtained through one-step via a four-membered ring hydrogen migration transition state. In the hyrogenation–dehydrogenation exchange mechanism, the T–H exchange could be accomplished by the hydrogenation of the unsaturated bond with tritium followed by the dehydrogenation of HT. Isotope exchange between hydrogen and tritium is selective, and oil containing molecules with −OH and −COOH groups can more easily exchange hydrogen for tritium. For aldehydes and ketones, the ability of T–H isotope exchange can be determined by the hydrogenation of T{sub 2} or the dehydrogenation of HT. The molecules containing one type of hydrogen provide a single product, while the molecules containing different types of hydrogens provide competitive products. The rate constants are presented to quantitatively estimate the selectivity of the products.

Efeito da inclusão de diferentes fontes lipídicas e óleo mineral na dieta sobre a digestibilidade dos nutrientes e os níveis plasmáticos de gordura em equinos Inclusion of different fat sources and mineral oil in equine diet

Directory of Open Access Journals (Sweden)

Rodrigo Martins Ribeiro

2009-10-01

quantity nor the type of oil added to the diets. The smallest dry matter (DM digestibility values, organic matter (OM and ether extract (EE were observed for the diets with the addition of mineral oil (58.90, 60.29 and 32.02% compared to the control diet, whose values were 62.58, 64.41 and 77.71%. The EE digestibility coefficient obtained for the diets with animal fat (90.26% and vegetable fat (86.47%. The diet with mineral oil reduced the HDL-C concentration (68.75 mg/dL compared to the control diet (76.00 mg/dL. The adition of fat sources and mineral oil did not influence the acceptability of the diet by the horses. The vegetable oil did not differ from animal fat regarding nutrient digestibility, but these fat sources affected ether extract digestibility. The addition of mineral oil reduced the plastmatic HDL-C levels while the addition of animal fat and vegetable fat did not alter the cholesterol plasmatic concentrations.

A novel non-mineral oil-based adjuvant. II. Efficacy of a synthetic sulfolipopolysaccharide in a squalane-in-water emulsion in pigs

NARCIS (Netherlands)

L.A.Th. Hilgers (L. A Th); P.L.I. Platenburg (P. L I); A. Luitjens (A.); B. Groenveld (B.); T. Dazelle (T.); J.T.M. Weststrate

1994-01-01

textabstractThe adjuvanticity of a sulfolipopolysaccharide (SLP) incorporated into a squalane-in-water emulsion (SLP/S/W) was compared with that of a mineral oil-in-water (O/W) adjuvant currently used in commercial porcine vaccines. Groups of pigs were immunized twice with vaccines comprising either

The impact of fish oil and wheat germ oil combination on mineral-bone and inflammatory markers in maintenance hemodialysis patients: a randomized, double-blind, placebo-controlled clinical trial.

Science.gov (United States)

Zakaria, Hadeer; Mostafa, Tarek M; El-Azab, Gamal A; Abd El Wahab, Ahmed M; Elshahawy, Heba; Sayed-Ahmed, Nagy Ah

2017-10-01

This study aimed to examine the impact of combined supplementation of fish oil (FO) with antioxidants like wheat germ oil (WGO) on mineral-bone and inflammatory markers in maintenance HD patients. This randomized, double-blind, placebo-controlled trial involved 46 HD patients who were randomly assigned into two groups to receive daily 3000 mg of FO [1053 mg omega-3 fatty acids (ω-3 FAs)] plus 300 mg of WGO [0.765 mg vitamin E] or placebo for 4 months. Blood concentrations of hemoglobin (Hgb), white blood cells, mineral-bone parameters including serum calcium (Ca), phosphorus, calcium-phosphorus product, parathyroid hormone, alkaline phosphatase, and osteoprotegerin and serum concentrations of inflammatory markers including high-sensitivity C-reactive protein, ferritin, and uric acid were measured before and after the intervention. Eighty-seven percentage of patients in each group completed the study. The mean serum Ca levels increased significantly in the supplemented group at the end of study (p = 0.0016), and this increment was also significant as compared to placebo group (p = 0.0418). No significant alterations were observed in the other measured parameters within each group during the study (as p values were >0.05). FO plus WGO supplementation showed beneficial effect on serum Ca levels of HD patients without any statistically significant effect on other mineral-bone and inflammatory markers. Further investigations are required to confirm it.

Brazil's mineral development: potential and problems

Energy Technology Data Exchange (ETDEWEB)

Lloyd, B; Wheeler, E

1977-03-01

Brazil's vast mineral wealth still lies in the ground largely unexploited. Lack of adequate communications and the past political instability of the country has greatly hampered mineral exploration, and risk capital for major schemes has only recently been forthcoming. In 1975, Brazil's oil imports alone cost US $3073 million, creating an unhealthy balance of payments deficit and causing the external national debt to reach US $22 billion by the end of that year--an increase of a further 25% in this debt took place during 1976. Substantial price rises in imported machinery followed that of oil, while the prices of Brazil's main exports, coffee, sugar and soya, have continued to fluctuate widely. As a result of the oil price rise Brazil has moved from a traditional trade balance to substantial deficit, although this has fallen from its 1974 peak of 4.6 billion, largely as a result of government policies. Brazil has untapped deposits of bauxite, tin, zinc, iron ore, nickel, as well as oil, and is firmly set on the path that will make her one of the world's major sources of raw materials by the year 2000. The government has made the exploitation of natural resources, particularly the previously neglected oil and gas sectors, one of the cornerstones of its economic strategy. Yet in 1975 the mineral sector produced less than 2% of Brazil's GNP, although it did contribute 11% of exports. Apart from iron oreand manganese, mineral production is small and the country is still a net importer of copper, zinc, nickel, tin, and lead. Without a substantial increase in exports the government's whole economic/social and political strategy will be at risk.

Mineral exploration, Australia, March quarter 1983

Energy Technology Data Exchange (ETDEWEB)

1983-01-01

This publication contains annual and quarterly statistics of exploration for minerals in Australia. Part 1 sets out statistics of exploration for minerals and oil shale for which data are no longer available for separate publication. Part 2 gives details of petroleum exploration.

Patterns of spatial and temporal distribution of the asparagus miner (Diptera: Agromyzidae): implications for management.

Science.gov (United States)

Morrison, William R; Szendrei, Zsofia

2013-06-01

The asparagus miner is an obligatory feeder on asparagus and a putative vector for pathogenic fungi implicated in the early decline of asparagus fields. To date, the distribution of the asparagus miner over space and time is poorly understood. Our study evaluated the spatial and temporal pattern of adult asparagus miners in commercial asparagus fields in Michigan in 2011 and 2012. We sampled adults and damage weekly during the growing season using yellow sticky traps outside, at the edge, and inside commercial fields. Yellow sticky traps at each trapping location were placed at the canopy and ground level to determine vertical distribution of adults. During the first generation, adults were more evenly distributed throughout the field. In the second generation, adults were more commonly found on the edge of the field. Overall, there was a greater percent of mining damage near the edge of the field. Additionally, three times as many asparagus miners were found in the canopy compared with ground-level traps. There were 12 times as many asparagus miner adults on edges bordered by another asparagus field than on ones bordered by forest. Taken together, our results indicate that while asparagus miner management in the beginning of the growing season should focus on the entire field, in the latter half of the season, growers could save money and resources by targeting miner adults at the edges of fields. Finally, conserving the remaining naturally forested landscape and planting borders of trees may help ameliorate pest pressure in asparagus fields.

Mineral raw materials for power production in legislation of the Republic of Croatia

International Nuclear Information System (INIS)

Matisa, Z.

1999-01-01

According to the Constitution of the Republic of Croatia, mineral wealth is a public good of legal interest to the Republic of Croatia and enjoys its special protection. The Mining Law establishes that mineral wealth (including mineral resources that are used for power production) is the property of the Republic of Croatia. Among other mineral raw materials, this refers to mineral raw materials that are used for power production: coal, oil, natural gas, radioactive mineral raw materials and geothermal waters. These mineral resources are as almost all other mineral raw materials with the exception of geothermal waters, an unrecoverable natural resource. The right to use that natural resource may be granted only by a concession. The mining legislation provides for exploration and exploitation of mineral raw materials. Exploration of oil and gas is considered to comprise operations and testing with the aim to establish the existence, position and form of oil and natural gas deposits, their quality and quantity, as well as exploitation conditions. Exploitation of oil and natural gas is considered to comprise extraction from deposits, refining and transport, as well as disposal in geological structures. Mineral raw materials used in power production amount to 63% of national total primary energy production, and they cover 33% of total power consumption in the country. Legislation in the Republic of Croatia, which refers to exploration and exploitation of oil and natural gas, allows economic utilization of that unrecoverable natural wealth to run smoothly and in compliance with practices in our European environment. (author)

Influence of salinity on bioremediation of oil in soil

International Nuclear Information System (INIS)

Rhykerd, R.L.; Weaver, R.W.; McInnes, K.J.

1995-01-01

Spills from oil production and processing result in soils being contaminated with oil and salt. The effect of NaCl on degradation of oil in a sandy-clay loam and a clay loam soil was determined. Soils were treated with 50 g kg -1 non-detergent motor oil (30 SAE). Salt treatments included NaCl amendments to adjust the soil solution electrical conductivities to 40, 120, and 200 dS m -1 . Soils were amended with nutrients and incubated at 25 o C. Oil degradation was estimated from the quantities of CO 2 evolved and from gravimetric determinations of remaining oil. Salt concentrations of 200 dS m -1 in oil amended soils resulted in a decrease in oil mineralized by 44% for a clay loam and 20% for a sandy-clay loam soil. A salt concentration of 40 dS m -1 reduced oil mineralization by about 10% in both soils. Oil mineralized in the oil amended clay-loam soil was 2-3 times greater than for comparable treatments of the sandy-clay loam soil. Amending the sandy-clay loam soil with 5% by weight of the clay-loam soil enhanced oil mineralization by 40%. Removal of salts from oil and salt contaminated soils before undertaking bioremediation may reduce the time required for bioremediation. (author)

Study on geochemical occurrences of REE in Wangqing oil shale

Energy Technology Data Exchange (ETDEWEB)

Bai, Jing-ru; Wang, Qing; Liu, Tong; Wei, Yan-zhen; Bai, Zhang [Northeast Dianli Univ., Jilin (China). Engineering Research Centre

2013-07-01

Sequential chemical extraction experiment (SCEE) and Float- sink experiment (FSE) have been employed on oil shale research from Wangqing, Jilin province China, in order to determine the binding forms of rare earth elements (REE) in oil shale. The REE contents were determined by the inductively coupled plasma-mass spectrometry (ICP-MS). Wangqing oil shale was screened into specific gravity density level: <1.5g/cm{sup 3}, 1.5-1.6g/cm{sup 3}, 1.6-2.0g/cm{sup 3}, 2.0-2.4g/cm{sup 3}, >2.4g/cm{sup 3}. The mode of occurrences of rare earth elements in Wangqing oil shale was studied by six-step SCEE. FSE results show that REEs in Wangqing oil shale exist mainly in inorganic minerals and more in excluded mineral, while SCEE results show that REEs of Wangqing oil shale is primarily occurred in minerals, including carbonate, Fe-Mn oxide, sulfide, and Si-minerals. FSE and SCEE results fully illustrate excluded mineral is mainly mode of occurrence of REEs in Wangqing oil shale, whereas inorganic minerals and organic matter is not that. The REE distribution pattern curves of FSE density and SCEE fraction products are similar with that of raw oil shale. The REE in different densities products has a close connection with terrigenous clastic rock, and the supply of terrestrial material is stable.

Oil. From mineral resource treasure to resource plague

International Nuclear Information System (INIS)

Cabezas, M.

2006-01-01

Rising oil prices in the seventies resulted, also because of overspending, in disappointing economic development in the oil-producing countries. Although policy reactions to the current rise of the oil prices did not have that effect so far, there is the danger for financial instability [nl

Case study of the effectiveness of passive grease trap for management on domestic kitchen waste water

Science.gov (United States)

Nidzamuddin, M. Y.; Juffrizal, K.; Mustapha, F.; Zulfattah, Z. M.; Tan, C. F.; Taha, M. M.; Hidayah, I.; Hilwa, M. Z.

2015-05-01

Household waste, generally known as trash or garbage is mostly includes food wastes, product packaging, and other miscellaneous inorganic wastes that are coming from domestic household. Grease waste such as oil and fats can contaminate water and also clot on pipes provoking blockages. Thus, waste water from kitchen sink need a proper way of filtration. Grease trap developed in this paper is viable in trapping the grease residue. The experiments have been conducted in controlled environment and the objectives are to investigate the effectiveness of grease trap by proving the existence of retention time and the expected ratio of collected water and oil during experiment process using a prototype model.

Process for complete conversion of coal oils, shale oils, etc

Energy Technology Data Exchange (ETDEWEB)

Dubois, P

1911-07-08

A process is described for complete conversion of mineral coal oil, shale oil, and other similar oils in pitch, characterized by these oils being mixed with a nonvolatile substance with a boiling point on the average higher than the boiling point of the oil to be treated, and then being heated under pressure with the introduction of air, whereby the heating is interrupted if necessary on account of the known exothermic reaction and the conversion of the oil in the pitch or its distillation can be carried out without further heating.

A-DROP: A predictive model for the formation of oil particle aggregates (OPAs)

Science.gov (United States)

Zhao, Lin; Boufadel, Michel C.; Geng, Xiaolong; Lee, Kenneth; King, Thomas; Robinson, Brian; Fitzpatrick, Faith A.

2016-01-01

Oil–particle interactions play a major role in removal of free oil from the water column. We present a new conceptual–numerical model, A-DROP, to predict oil amount trapped in oil–particle aggregates. A new conceptual formulation of oil–particle coagulation efficiency is introduced to account for the effects of oil stabilization by particles, particle hydrophobicity, and oil–particle size ratio on OPA formation. A-DROP was able to closely reproduce the oil trapping efficiency reported in experimental studies. The model was then used to simulate the OPA formation in a typical nearshore environment. Modeling results indicate that the increase of particle concentration in the swash zone would speed up the oil–particle interaction process; but the oil amount trapped in OPAs did not correspond to the increase of particle concentration. The developed A-DROP model could become an important tool in understanding the natural removal of oil and developing oil spill countermeasures by means of oil–particle aggregation.

Results of experiments with flare type igniters on diesel fuel and crude oil emulsions

International Nuclear Information System (INIS)

Moffat, C.; Hankins, P.

1997-01-01

Development of a hand-deployable igniter that could ignite contained diesel fuel and crude oil emulsions on water was described. The igniter was developed as part of the U.S. Navy Supervisor of Salvage (SUPSALV) In-Situ Burn (ISB) system. It is a manually operated, electrically fired, high temperature flare type igniter. It is 41 cm long, 10 cm in diameter, weighs 1.5 kg, and is packaged and shipped with the ISB system. The chemical and mineral composition of the flair allows for a three minute burn of up to 1370 degrees C (2500 degrees F) at the center. The flare is most effective when used in conjunction with a shroud of sorbent material which traps and holds oil around the burning flare aiding the ignition process by increasing the initial propagation area. In small-scale tank experiments the flare ignited diesel fuel in ambient temperatures of 3 degrees C, with winds of 8 to 10 m/sec. The flare also ignited 22.5 per cent water-in crude oil emulsion in 3 degrees C temperatures. 4 refs., 3 tabs

Metal working oils. Cutting oils, rolling oils, quenching oils, rust preventive oils; Kinzoku kakoyu. Sessakuyu, atsuenyu, yakiireyu, boseiyu

Energy Technology Data Exchange (ETDEWEB)

Koyama, S. [Idemitsu Kosan Co. Ltd., Tokyo (Japan)

1996-04-01

With the demand against complicating working techniques for a background, foundations of the consideration for each of the lubricants in future are outlined. 1. Cutting oils: From the standpoint of speeding up and fireproofing, share of water-soluble type has come up to 30-40%. In this type, emulsifying dispersants and preservatives are combined. 2. Rolling oils: According to thinning of the standard thickness of steel plates, pressure of contacting surfaces has come up to 300 kg/mm{sup 2}(max.) and slip speed has increased too. In stainless steel plates, in order to get rid of the heat-streak (baking streak originated from wearing-out of oil film) shifting from neat oil to emulsion type is required. 3. Quenching oils: Following two systems are recent tendencies, the mineral oil system having excellent thermostability or the water system containing polyalkylneglycol etc., but the latter is expected from the viewpoint of fireproofing. 4. Rust preventive oils: As this oils do not aim at the rust prevention for long term, degreasing property is required. 20 refs., 5 figs., 1 tab.

25 CFR 225.22 - Approval of minerals agreements.

Science.gov (United States)

2010-04-01

... 25 Indians 1 2010-04-01 2010-04-01 false Approval of minerals agreements. 225.22 Section 225.22 Indians BUREAU OF INDIAN AFFAIRS, DEPARTMENT OF THE INTERIOR ENERGY AND MINERALS OIL AND GAS, GEOTHERMAL... financial return to the Indian parties thereto; the extent, nature, value or disposition of the mineral...

Peroxidized mineral oil increases the oxidant status of culture media and inhibits in vitro porcine embryo development.

Science.gov (United States)

Martinez, C A; Nohalez, A; Ceron, J J; Rubio, C P; Roca, J; Cuello, C; Rodriguez-Martinez, H; Martinez, E A; Gil, M A

2017-11-01

The use of oils with undetected alterations is a long-recognized problem for in vitro embryo production systems. Since peroxides in oils have been associated with reduced embryo production outcomes, our goals were (1) to evaluate the effects of a batch of mineral oil (MO) that was suspected to be altered on the in vitro production of pig embryos and (2) to determine oil peroxide values throughout culture and the transfer of oxidant agents from oil to culture media. Sunflower oil, which has a completely different chemical composition than MO but a higher oxidative status, and unaltered MO were used as controls. Oocyte maturation, fertilization and embryo development were affected differently depending on the oil overlay used. While the suspected MO was not able to sustain in vitro maturation and fertilization, the oocytes incubated in the presence of sunflower oil were matured and fertilized similarly to those of the unaltered MO group. Moreover, the cleavage rate of presumed zygotes cultured under the suspected MO was severely reduced compared with those cultured under the other oils, and none of the cleaved embryos developed to the blastocyst stage. Although the cleavage rates in the sunflower oil and unaltered MO groups were similar, embryos cultured under sunflower oil also failed to develop to the blastocyst stage. Our results revealed that the suspected MO and sunflower oil had similar levels of peroxides and that these levels were much higher than those of the unaltered MO. The total oxidant status was higher in media incubated under peroxidized oils than in fresh media or media incubated without an oil overlay or under unaltered MO, indicating that oxidant agents were transferred to the incubation media. However, unlike the sunflower oil group, the culture media incubated under the suspected MO had high levels of total oxidant status and low levels of hydrogen peroxide and reactive oxygen species, suggesting the presence of other unknown oxidant agents in

Preservation of bone structure and function by Lithothamnion sp. derived minerals.

Science.gov (United States)

Aslam, Muhammad Nadeem; Bergin, Ingrid; Jepsen, Karl; Kreider, Jaclynn M; Graf, Kristin H; Naik, Madhav; Goldstein, Steven A; Varani, James

2013-12-01

Progressive bone mineral loss and increasing bone fragility are hallmarks of osteoporosis. A combination of minerals isolated from the red marine algae, Lithothamnion sp. was examined for ability to inhibit bone mineral loss in female mice maintained on either a standard rodent chow (control) diet or a high-fat western diet (HFWD) for 5, 12, and 18 months. At each time point, femora were subjected to μ-CT analysis and biomechanical testing. A subset of caudal vertebrae was also analyzed. Following this, individual elements were assessed in bones. Serum levels of the 5b isoform of tartrate-resistant acid phosphatase (TRAP) and procollagen type I propeptide (P1NP) were also measured. Trabecular bone loss occurred in both diets (evident as early as 5 months). Cortical bone increased through month 5 and then declined. Cortical bone loss was primarily in mice on the HFWD. Inclusion of the minerals in the diet reduced bone mineral loss in both diets and improved bone strength. Bone mineral density was also enhanced by these minerals. Of several cationic minerals known to be important to bone health, only strontium was significantly increased in bone tissue from animals fed the mineral diets, but the increase was large (5-10 fold). Serum levels of TRAP were consistently higher in mice receiving the minerals, but levels of P1NP were not. These data suggest that trace minerals derived from marine red algae may be used to prevent progressive bone mineral loss in conjunction with calcium. Mineral supplementation could find use as part of an osteoporosis-prevention strategy.

Manitoba oil activity review, 1996

International Nuclear Information System (INIS)

1997-01-01

This report is the annual review of Manitoba Crown oil and gas dispositions, mineral owner leasing and revenue, geophysical and drilling activity, areas of activity, oil production and markets, oil prices, value of production, provincial revenue from oil production, surface owners, spills and reclamation, municipal taxes, the Manitoba Drilling Incentive Program, oil reserves, oil industry expenditures, and industry employment. Highlights of the current year are included

Manitoba oil activity review, 1997

International Nuclear Information System (INIS)

1998-01-01

Annual review is presented of Manitoba Crown oil and gas dispositions, mineral owner leasing and revenue, geophysical and drilling activity, areas of activity, oil production and markets, oil prices, value of production, provincial revenue from oil production, surface owners, spills and reclamation, municipal taxes, the Manitoba Drilling Incentive Program, oil reserves, oil industry expenditures, and industry employment. Highlights of the current year are included

Manitoba oil activity review, 1995

International Nuclear Information System (INIS)

1996-01-01

This report is the annual review of Manitoba Crown oil and gas dispositions, mineral owner leasing and revenue, geophysical and drilling activity, areas of activity, oil production and markets, oil prices, value of production, provincial revenue from oil production, surface owners, spills and reclamation, municipal taxes, the Manitoba Drilling Incentive Program, oil reserves, oil industry expenditures, and industry employment. Highlights of the current year are included

25 CFR 225.40 - Government employees cannot acquire minerals agreements.

Science.gov (United States)

2010-04-01

... 25 Indians 1 2010-04-01 2010-04-01 false Government employees cannot acquire minerals agreements. 225.40 Section 225.40 Indians BUREAU OF INDIAN AFFAIRS, DEPARTMENT OF THE INTERIOR ENERGY AND MINERALS OIL AND GAS, GEOTHERMAL, AND SOLID MINERALS AGREEMENTS Minerals Agreements § 225.40 Government...

Excise taxes for mineral oils. Investigation of the monitoring. Retrospective of the report; Accijnzen op minerale olien. Toezicht doorgelicht. Terugblik 2006

Energy Technology Data Exchange (ETDEWEB)

NONE

2006-03-30

December 2003 the Netherlands Court of Audit published a report with the title 'Excise Taxes for Mineral Oils. Investigation of the Monitoring'. The study was carried out in cooperation with the Belgian Court of Audit. The aim of the report was to assess the tasks of the customs with regard to excise taxes on mineral oils (licensing and related procedures). The aim of this report is to review if and whether the Dutch government followed and implemented the recommendations, as formulated in the 2003 report. [Dutch] De Algemene Rekenkamer publiceerde op 13 december 2003 haar onderzoek 'Accijnzen op minerale olien: toezicht doorgelicht. In dit onderzoek, dat gezamenlijk met het Rekenhof van Belgie werd uitgevoerd, is nagegaan in hoeverre de Douane zijn taken op het gebied van de accijns op minerale olien (vergunningverlening, vergunningbeheer en controles) op een goede manier vervult (volgens de eigen voorschriften, risico's in voldoende mate afgedekt enzovoort). Ook is onderzocht in hoeverre er sprake is van een 'administratief gesloten' Europees accijnssysteem, zoals bij de instelling in 1993 werd beoogd.

Process for the extraction of valuable products from coals, pitches, mineral oils, and the like

Energy Technology Data Exchange (ETDEWEB)

1936-06-05

A process is described for the treating of coke, lignite, peat, etc., and mineral oils with the help of hydrogen or other reducing gases and under pressure to recover valuable hydrocarbons, characterized by the carbonaceous substances and the reducing gas coming together already heated totally or in part at least from 350/sup 0/C to the temperature necessary for the reaction. The substances to be treated becoming extracted in the form of paste or liquid from the reaction chamber and then returned to it and being reacted outside the reaction zone in the presence of the reducing gases at the temperature necessary for the reaction.

Matching Index-of-Refraction for 3D Printing Model Using Mixture of Herb Essential Oil and Light Mineral Oil

International Nuclear Information System (INIS)

Song, Min Seop; Choi, Hae Yoon; Kim, Eung Soo

2013-01-01

This study has extensively investigated the emerging 3-D printing technologies for use of MIR-based flow field visualization methods such as PIV and LDV. As a result, mixture of Herb essential oil and light mineral oil has been evaluated to be great working fluid due to its adequate properties. Using this combination, the RIs between 1.45 and 1.55 can be accurately matched, and most of the transparent materials are found to be ranged in here. Conclusively, the proposed MIR method are expected to provide large flexibility of model materials and geometries for laser based optical measurements. Particle Image Velocimetry (PIV) and Laser Doppler Velocimetry (LDV) are the two major optical technologies used for flow field visualization in the latest fundamental thermal-hydraulics researches. Those techniques seriously require minimizing optical distortions for enabling high quality data. Therefore, matching index of refraction (MIR) between model materials and working fluids are an essential part of minimizing measurement uncertainty. This paper proposes to use 3-D Printing technology for manufacturing models for the MIR-based optical measurements. Because of the large flexibility in geometries and materials of the 3-D Printing, its application is obviously expected to provide tremendous advantages over the traditional MIR-based optical measurements. This study focuses on the 3-D printing models and investigates their optical properties, transparent printing techniques, and index-matching fluids

Matching Index-of-Refraction for 3D Printing Model Using Mixture of Herb Essential Oil and Light Mineral Oil

Energy Technology Data Exchange (ETDEWEB)

Song, Min Seop; Choi, Hae Yoon; Kim, Eung Soo [Seoul National Univ., Seoul (Korea, Republic of)

2013-10-15

This study has extensively investigated the emerging 3-D printing technologies for use of MIR-based flow field visualization methods such as PIV and LDV. As a result, mixture of Herb essential oil and light mineral oil has been evaluated to be great working fluid due to its adequate properties. Using this combination, the RIs between 1.45 and 1.55 can be accurately matched, and most of the transparent materials are found to be ranged in here. Conclusively, the proposed MIR method are expected to provide large flexibility of model materials and geometries for laser based optical measurements. Particle Image Velocimetry (PIV) and Laser Doppler Velocimetry (LDV) are the two major optical technologies used for flow field visualization in the latest fundamental thermal-hydraulics researches. Those techniques seriously require minimizing optical distortions for enabling high quality data. Therefore, matching index of refraction (MIR) between model materials and working fluids are an essential part of minimizing measurement uncertainty. This paper proposes to use 3-D Printing technology for manufacturing models for the MIR-based optical measurements. Because of the large flexibility in geometries and materials of the 3-D Printing, its application is obviously expected to provide tremendous advantages over the traditional MIR-based optical measurements. This study focuses on the 3-D printing models and investigates their optical properties, transparent printing techniques, and index-matching fluids.

Formation of carbonaceous nano-layers under high interfacial pressures during lubrication with mineral and bio-based oils

Energy Technology Data Exchange (ETDEWEB)

Baltrus, John P. [U.S. DOE

2014-01-01

In order to better protect steel surfaces against wear under high loads, understanding of chemical reactions between lubricants and metal at high interfacial pressures and elevated temperatures needs to be improved. Solutions at 5 to 20 wt. % of zinc di-2-ethylhexyl dithio phosphate (ZDDP) and chlorinated paraffins (CP) in inhibited paraffinic mineral oil (IPMO) and inhibited soy bean oil (ISBO) were compared on a Twist Compression Tribotester (TCT) at 200 MPa. Microscopy of wear tracks after 10 seconds tribotesting showed much smoother surface profiles than those of unworn areas. X-ray photoelectron spectroscopy (XPS) coupled with Ar-ion sputtering demonstrated that additive solutions in ISBO formed 2–3 times thicker carbon-containing nano-layers compared to IPMO. The amounts of Cl, S or P were unexpectedly low and detectable only on the top surface with less than 5 nm penetration. CP blends in IPMO formed more inorganic chlorides than those in ISBO. It can be concluded that base oils are primarily responsible for the thickness of carbonaceous nano-layers during early stages of severe boundary lubrication, while CP or ZDDP additive contributions are important, but less significant.

25 CFR 225.28 - Approval of amendments to minerals agreements.

Science.gov (United States)

2010-04-01

... 25 Indians 1 2010-04-01 2010-04-01 false Approval of amendments to minerals agreements. 225.28 Section 225.28 Indians BUREAU OF INDIAN AFFAIRS, DEPARTMENT OF THE INTERIOR ENERGY AND MINERALS OIL AND GAS, GEOTHERMAL, AND SOLID MINERALS AGREEMENTS Minerals Agreements § 225.28 Approval of amendments to...

Novel approaches to microbial enhancement of oil recovery.

Science.gov (United States)

Kryachko, Yuriy

2018-01-20

Microbially enhanced oil recovery (MEOR) was shown to be feasible in a number of laboratory experiments and field trials. However, it has not been widely used in the oil industry because necessary conditions cannot always be easily established in an oil reservoir. Novel approaches to MEOR, which are based on newly discovered biosurfactant-mediated MEOR-mechanisms, are discussed in this review. Particularly, the possibility of combining MEOR with chemical enhancement of oil recovery in heterogeneous oil reservoirs, which involves rock surface wettability shifts and emulsion inversions, is discussed. In wider (centimeter/millimeter-scale) rock pores, the activity of (bio)surfactants and microbial cells attached to oil may allow releasing trapped oil blobs through oil-in-water emulsification. After no more oil can be emulsified, the addition of alkali or surfactants, which turn rock surface oil-wet, may help release oil droplets trapped in narrow (micrometer-scale) pores through coalescence of the droplets and water-in-oil emulsification. Experiments demonstrating the possibility of (bio)surfactant-mediated enhancement of immiscible gas-driven oil recovery are also reviewed. Interestingly, very low (bio)surfactant concentrations were shown to be needed for enhancement of immiscible gas-driven oil recovery. Some possible side effects of MEOR, such as unintended bioplugging and microbially influenced corrosion (MIC), are discussed as well. Crown Copyright © 2017. Published by Elsevier B.V. All rights reserved.

Mineral wealth and the economic transition: Kazakhstan

International Nuclear Information System (INIS)

Auty, R.M.

1998-01-01

The exploitation of mineral wealth can amplify the problems of the transition economies in three basic ways. First, the rebound of the real exchange rate that characterises a successful transition may be augmented by the capital inflow required to expand mineral production. This can cause both recession in the short-run and lower growth in the medium-term. Second, when the mineral revenues expand, the Dutch Disease effects may intensify the transition-related shrinkage of the non-mining tradable sector, thereby retarding economic diversification and rendering the economy vulnerable to external shocks. Third, a mineral boom tends to concentrate revenue on the government, which may use it to postpone difficult decisions on economic reform and/or dissipate the revenue due to weak financial markets and inadequate public accountability. Kazakhstan, like oil-rich Azerbaijan, is a late reformer and displays evidence of a faster transition rebound than other less resource-rich countries in the CIS do. However, Kazakhstan has two advantages over Azerbaijan. First, Kazakhstan has a more diversified mineral endowment with which to counter any trend towards single commodity specialization. Second, Kazakhstan is making a later start on oil expansion so that it can learn from the experience of Azerbaijan. Priorities for Kazakhstan are the continuation of prudent economic policies, the creation of institutions to enhance the transparency of the revenue flows, and the use of environmental accounting to provide a rationale for the deployment of the oil rents. (author)

Relationships among rat numbers, abundance of oil palm fruit and damage levels to fruit in an oil palm plantation.

Science.gov (United States)

Puan, Chong Leong; Goldizen, Anne W; Zakaria, Mohamed; Hafidzi, Mohd N; Baxter, Greg S

2011-06-01

The relationships between vertebrate pests and crop damage are often complex and difficult to study. In palm oil plantations rodents remain the major pests, causing substantial monetary losses. The present study examined the numerical and functional responses of rodents to changes in the availability of oil palm fruit and the damage associated with that response. For the study, 200 traps were set in pairs on a 10 × 10 trapping grid for 3 consecutive nights in each of 6 study plots at 8-week intervals in a 2569 ha oil palm plantation at Labu, Negeri Sembilan state in Peninsular Malaysia over 14 months. A total of 1292 individual rats were captured over 25 200 trap-nights. Animals were identified, aged, sexed, weighed and measured. An index of the relative abundance of rats was calculated based on trapping success. Damage to infructescences was assessed at each trap point. Regardless of the age of palms, there were positive and significant relationships between the relative abundance of rats and numbers of infructescences. The levels of damage to infructescences were significantly correlated with the relative abundance of rats. A steep increase in damage was observed with an increase in mature infructescences, indicating a feeding preference of rats for mature infructescences. For both males and females of all rat species, there were weak and non-significant correlations between body condition and infructescence numbers. These results indicated that there was a numerical and a functional response by rats to the availability of palm fruit and a resulting increase in depredation of oil palm fruits. The ways in which this information might aid in future pest control are discussed. © 2011 ISZS, Blackwell Publishing and IOZ/CAS.

Mineral industry statistics 1975

Energy Technology Data Exchange (ETDEWEB)

1978-01-01

Production, consumption and marketing statistics are given for solid fuels (coal, peat), liquid fuels and gases (oil, natural gas), iron ore, bauxite and other minerals quarried in France, in 1975. Also accident statistics are included. Production statistics are presented of the Overseas Departments and territories (French Guiana, New Caledonia, New Hebrides). An account of modifications in the mining field in 1975 is given. Concessions, exploitation permits, and permits solely for prospecting for mineral products are discussed. (In French)

The chronic toxicity of mineral oil-wet and synthetic liquid-wet cuttings on an estuarine fish, Fundulus grandis

International Nuclear Information System (INIS)

Jones, F.V.; Rushing, J.H.; Churan, M.A.

1991-01-01

One of the major factors concerning oil-wet cuttings discharges in the long-term effect on the aquatic environment. This paper investigates the survival and growth of the mud minnow, Fundulus grandis, when exposed to different concentrations of mineral oil-wet and synthetic liquid-wet cuttings in flow-through bioassay chambers. The test fluids were a low aromatic mineral oil-based mud (MOBM) and a synthetic liquid-based mud (SBM). Each test fluid was added to a container of dried water-based cuttings which contained minimum hydrocarbons. The fluid and cuttings were mixed to obtain the desired test concentrations. The study tested three concentrations (1%, 5%, and 8.4% by dry weight) of each fluid on the cuttings. Growth rates during the 3-day period were modest with fish in 1% MOBM losing weight. The highest percent growth rates were obtained with fish cultured in 5% SBM and the controls. However, overall growth was not significantly different between treatments. Mean growth did show a significant difference between controls and 5% SBM, and other treatments. The cuttings of the 5% and 8.4% concentrations of both treatments looked like paste. These pastes may have slowed the movement of organics off of the cuttings beds and affected biodegradability and growth rates. Cuttings in the controls and 1% concentrations stayed suspended in the water column longer when disturbed and looked more like loose gravel. Uptake of the MOBM occurred in the internal organs and tissue of fish. No such uptake was observed in the fish tissue with the SBM; a very low level of synthetic liquid was detected in one gut sample only. This may be the major reason for the variations noted in growth rates. Fish mortality during the study was related to the buildup of anaerobic conditions and insufficient aeration. Fish survival for the entire study was 94%

Birches against mineral oils. Lignin - a renewable resource for the alternative production of phenols; Birke contra Erdoel. Lignin - ein nachwachsender Rohstoff zur alternativen Gewinnung von Phenolen

Energy Technology Data Exchange (ETDEWEB)

Zehnpfund, C.; Bormann, J.; Wehrkamp zu Hoene, F. [Gymnasium Bersenbrueck (Germany)

1998-02-01

We wanted to offer an alternative for the `After-mineral oil time` with our work when we attempted to isolate phenols, which are won up to now from mineral oil, of a growing raw material. Phenols are economic important substances for production of epoxies, herbicides, artificial resins, dyes and drugs (e.g. aspirin or Paracetamol). We managed to isolate phenols with normal conditions of lignin, a component of wood. (orig.) [Deutsch] Wir wollten mit unserer Arbeit eine Alternative fuer die `Nach-Erdoel-Zeit` bieten, indem wir versuchten, Phenole, die bisher aus Erdoel gewonnen werden, aus einem nachwachsenden Rohstoff zu isolieren. Phenole sind volkswirtschaftlich bedeutsame Substanzen zur Herstellung von Kunststoffen, Herbiziden, Kunstharzen, Farbstoffen und Arzneimitteln (z.B. Aspirin oder Paracetamol). Es gelang uns, Phenole unter Normalbedingungen aus Lignin, einem Bestandteil des Holzes, zu isolieren. (orig.)

Summary of research and information needs for the management of selected onshore energy minerals: oil shale, tar sands, arctic oil and gas, and uranium. Final report 1982-83

Energy Technology Data Exchange (ETDEWEB)

1983-11-01

The report assesses research needs for the management, regulation, reclamation, and conservation of oil shale, tar sands, arctic oil and gas, and uranium deposits currently under federal jurisdiction and concludes that additional research is required to achieve the goals of good management, including conservation, protection of life and property, and minimization of environmental degradation. The report recommends (1) establishment of a standing advisory scientific and engineering committee on onshore minerals management research to influence future research directions and implementation; (2) development of a comprehensive library and data center for research results; and (3) encouragement of the operation of demonstration-scale production facilities where they are lacking. More detailed summaries of current knowledge and perceived research needs are to be found in the four interim reports of the committee.

Method of treating oil-bearing shale

Energy Technology Data Exchange (ETDEWEB)

Freeman, N H

1926-04-14

The process is given for treating shale or other oil-bearing mineral which consists of the application of dry heat to render the oil soluble and subjects the product of the heat treatment to an operation to extract the soluble oils.

Testing the ecotoxicology of vegetable versus mineral based lubricating oils: 1. Degradation rates using tropical marine microbes.

Science.gov (United States)

Mercurio, Philip; Burns, Kathryn A; Negri, Andrew

2004-05-01

Vegetable-derived lubricants (VDL) might be more biodegradable than mineral-derived lubricants (MDL) due to the absence of high molecular weight aromatics, but this remains largely untested in tropical conditions. In this laboratory study, the degradation rates of 2-stroke, 4-stroke and hydraulic VDLs were compared with their MDL counterparts in the presence of mangrove and coral reef microbial communities. While MDLs were comprised largely of unresolved saturated and some aromatic hydrocarbons, their VDL counterparts contained, potentially more degradable, fatty acid methyl esters. Degradation of some VDL was observed by day 7, with the 2-stroke VDL markedly consumed by mangrove microorganisms and the hydraulic VDL degraded by both microorganism communities after this short period. All of the VDL groups were significantly more degraded than the comparable MDLs mineral oil lubricants over 14 days in the presence of either mangrove or coral reef microbial communities. In general the mangrove-sourced microorganisms more efficiently degraded the lubricants than reef-sourced microorganisms.

Comprehensive two-dimensional gas chromatography for fast characterization of oil contamination

International Nuclear Information System (INIS)

Van De Weghe, H.; Vanermen, G.; Gemoets, J.; Lookman, R.; Bertels, D.

2005-01-01

Most analytical methods for the characterization of oil contamination rely on gas chromatography. Capillary GC offers a high separation power (peak capacity typically 100 - 500), and by using a boiling point column a volatility based distribution is obtained. However, petrochemical mixtures like mineral oil easily contain more then 5000 compounds, and capillary GC does not succeed in separating such mixtures up to the level of individual components. Analytical results are therefore limited to a classification into boiling point (or equivalent-carbon) fractions. Recent methods refined the classification by fractionation in aromatic and aliphatic hydrocarbons prior to GC-analysis (TPH method, Weisman 1998), and by incorporating water solubility (TTE and OK method, for a detailed description we refer to the Consoil 2005 lecture by R. Lookman 'Oil characterization: assessment of composition, degradation and remediation potential of total petroleum hydrocarbons in soil'). However, besides analytical difficulties and time consuming protocols related with these methods, the resulting classification still remains coarse and the various groups are not univocally chemically identified. Recently, comprehensive two-dimensional GC (GCXGC) was introduced. This technique combines two GC-columns with different separation mechanisms. The two columns are connected by a modulator, a device that traps, focuses and re-injects the peaks that elute from the first column into the second column. Each peak from the first column (representing a number of overlapping peaks) is further separated on the second column. The very high separation power of GCXGC (peak capacity 2000 - 10000) is ideal for the analysis of complex mixtures like mineral oil. Another important feature is the generation of structured chromatograms. Isomers appear as distinct groups in the chromatogram as a result of their similar interaction with the 2D-column phase. For chemical identification comprehensive GC can be

Comprehensive two-dimensional gas chromatography for fast characterization of oil contamination

Energy Technology Data Exchange (ETDEWEB)

Van De Weghe, H.; Vanermen, G.; Gemoets, J.; Lookman, R.; Bertels, D. [VITO, Mol (Belgium)

2005-07-01

Most analytical methods for the characterization of oil contamination rely on gas chromatography. Capillary GC offers a high separation power (peak capacity typically 100 - 500), and by using a boiling point column a volatility based distribution is obtained. However, petrochemical mixtures like mineral oil easily contain more then 5000 compounds, and capillary GC does not succeed in separating such mixtures up to the level of individual components. Analytical results are therefore limited to a classification into boiling point (or equivalent-carbon) fractions. Recent methods refined the classification by fractionation in aromatic and aliphatic hydrocarbons prior to GC-analysis (TPH method, Weisman 1998), and by incorporating water solubility (TTE and OK method, for a detailed description we refer to the Consoil 2005 lecture by R. Lookman 'Oil characterization: assessment of composition, degradation and remediation potential of total petroleum hydrocarbons in soil'). However, besides analytical difficulties and time consuming protocols related with these methods, the resulting classification still remains coarse and the various groups are not univocally chemically identified. Recently, comprehensive two-dimensional GC (GCXGC) was introduced. This technique combines two GC-columns with different separation mechanisms. The two columns are connected by a modulator, a device that traps, focuses and re-injects the peaks that elute from the first column into the second column. Each peak from the first column (representing a number of overlapping peaks) is further separated on the second column. The very high separation power of GCXGC (peak capacity 2000 - 10000) is ideal for the analysis of complex mixtures like mineral oil. Another important feature is the generation of structured chromatograms. Isomers appear as distinct groups in the chromatogram as a result of their similar interaction with the 2D-column phase. For chemical identification comprehensive GC

Application of passive sonar technology to mineral processing and oil sands applications : if you can measure it, you can manage it

Energy Technology Data Exchange (ETDEWEB)

O' Keefe, C.; Viega, J.; Fernald, M. [CiDRA Corp., Wallingford, CT (United States)

2007-07-01

SONAR-based flow and entrained air measurement instruments were described. This new class of industrial flow and compositional analyzers was developed by CiDRA to provide new measurement insight and quantifiable value to industrial process operators. Passive sonar array-based processing units have been installed worldwide in several industrial applications and are particularly suited for a wide range of mineral processing applications, including slurry flow rate measurement and fluid characterization. This paper also described the SONAR-based, clamp-on SONARtrac technology, a scalable platform that provides several other value added measurements and information such as speed of sound, entrained air/gas, gas hold-up, and velocity profile. Oil sands, tailings and bitumen slurries present considerable measurement challenges for in-line flow measurement devices in terms of measurement accuracy, reliability and maintenance. The sonar-based technology platform has been used in a variety of oil sands processes, hydrotransport, and minerals beneficiation applications. This paper described these applications with particular reference to difficult slurry flow measurement and control in the areas of comminution and flotation such as mill discharge, hydrocyclone feed/overflow, final concentrate, thickener discharge, and tailings. 5 refs., 4 tabs., 23 figs.

Field Trapping Bactrocera latifrons (Diptera: Tephritidae with Select Eugenol Analogs That Have Been Found to Attract Other ‘Non-Responsive’ Fruit Fly Species

Directory of Open Access Journals (Sweden)

Grant T. McQuate

2018-05-01

Full Text Available Bactrocera latifrons (Hendel (Diptera: Tephritidae is a pest fruit fly species native to Oriental Asia which has invaded and established in Hawaii and Tanzania and has been recovered in detection trapping in California. It is largely non-responsive to the male lures cuelure and methyl eugenol. Alpha-ionol + cade oil is a moderately effective male B. latifrons attractant, but is not as attractive as cuelure or methyl eugenol are to other fruit fly species. An improved attractant is therefore desired. With the recent success in finding other non-responsive fruit fly species attracted to isoeugenol, methyl-isoeugenol, or dihydroeugenol in Australia and other countries, we wanted to assess whether B. latifrons might also respond to these “eugenol analogs.” Working with wild B. latifrons populations in Hawaii, we assessed the relative catch of B. latifrons in traps baited with the eugenol analogs with catch in traps baited with alpha-ionol, alpha-ionol + cade oil, or alpha-ionol + eugenol. Catch was significantly higher in traps baited with alpha-ionol + cade oil relative to traps with any of the other baits. There was, though, some male B. latifrons catch in traps baited with dihydroeugenol or isoeugenol but none in traps baited with methyl-isoeugenol.

Theoretical investigation of isotope exchange reaction in tritium-contaminated mineral oil in vacuum pump.

Science.gov (United States)

Dong, Liang; Xie, Yun; Du, Liang; Li, Weiyi; Tan, Zhaoyi

2015-04-28

The mechanism of the isotope exchange reaction between molecular tritium and several typical organic molecules in vacuum pump mineral oil has been investigated by density functional theory (DFT), and the reaction rates are determined by conventional transition state theory (TST). The tritium-hydrogen isotope exchange reaction can proceed with two different mechanisms, the direct T-H exchange mechanism and the hyrogenation-dehydrogenation exchange mechanism. In the direct exchange mechanism, the titrated product is obtained through one-step via a four-membered ring hydrogen migration transition state. In the hyrogenation-dehydrogenation exchange mechanism, the T-H exchange could be accomplished by the hydrogenation of the unsaturated bond with tritium followed by the dehydrogenation of HT. Isotope exchange between hydrogen and tritium is selective, and oil containing molecules with OH and COOH groups can more easily exchange hydrogen for tritium. For aldehydes and ketones, the ability of T-H isotope exchange can be determined by the hydrogenation of T2 or the dehydrogenation of HT. The molecules containing one type of hydrogen provide a single product, while the molecules containing different types of hydrogens provide competitive products. The rate constants are presented to quantitatively estimate the selectivity of the products. Copyright © 2015 Elsevier B.V. All rights reserved.

Analysis of the kerogen of oil shales

Energy Technology Data Exchange (ETDEWEB)

Quass, F W; Down, A L

1939-01-01

Comments are given on the method developed by F. W. Quass for reducing the amount of mineral matter present in certain coals and oil shales (torbanites). The method consisted of grinding oil shale with water in a porcelain ball mill in the presence of oil. The oil formed a paste with the carbonaceous material, and a greater portion of the mineral matter remained suspended in the water and was separated. Ultimate analyses of the enriched samples indicated that the percent of carbon was higher, the percent of hydrogen and oxygen was lower, and the ratio of carbon to hydrogen and carbon to oxygen increased in the enriched samples.

Characteristics of a tractor engine using mineral and biodiesel fuels blended with rapeseed oil Características de um motor de trator alimentado com combustíveis mineral e biodisel misturados com óleo de colza

Directory of Open Access Journals (Sweden)

Tone Godeša

2010-10-01

Full Text Available One of the most unfavourable characteristics of crude vegetable oil when used as the fuel is the high viscosity. To improve this weakness, oil can be blended with mineral diesel or biodiesel fuels. This study was designed to evaluate how the use of mineral diesel or biodiesel blend with cold pressed rapeseed (Brassica napus oil affects the engine power, torque and fuel consumption. A tractor equipped with direct injection, water cooling system and three-cylinder diesel engine was used for the experiment. Fuels used were standard diesel fuel (diesel, rapeseed oil methyl ester - biodiesel (B100 and their mixtures with 10, 30 and 50 vol. % of cold pressed rapeseed oil (RO. Increased portion of RO in diesel fuel blends had almost no effect on the torque measured on the tractor PTO shaft; it however decreased the maximal power. Fuel blends with B100 and rising RO content (up to 50% gave a positive correlation with maximal torque and power. By increasing the portion of RO from 0 to 50%, the minimal specific fuel consumption increased by 6.65% with diesel and decreased by 2.98% with B100 based fuel.Uma das características mais desfavoráveis dos óleos vegetais crus usados como combustível é a alta viscosidade. Para melhorar este ponto fraco, o óleo pode ser misturado com diesel mineral ou biodiesel. Este estudo foi desenvolvido para avaliar como o uso de diesel mineral ou biodiesel misturado a oleo de colza (Brassica napus extraído por pressão a frio afeta a potência do motor, o torque e o consumo de combustível, empregando um trator equipado com injeção direta, sistema de refrigeração de água e um motor de três cilindros. Os combustíveis utilizados foram o diesel padrão (diesel, éster metílico de óleo de sementes de colza - biodiesel (B100 e suas misturas com 10, 30 e 50 % vol. de óleo de semente de colza pressionado a frio (RO. Maiores proporções de RO nas misturas de diesel praticamente não tiveram efeito sobre o torque

Recovery of hydrocarbon oils

Energy Technology Data Exchange (ETDEWEB)

1941-02-10

A process is disclosed for recovery of hydrocarbon oils, especially lubricating oils or diesel oils, through pressure hydrogenation of distillation, extraction of hydrogenation products from coal or coaly materials or from oils such as mineral oils or tars in liquid phase by use in a reaction vessel of fixed-bed catalysts, characterized in that as starting material is employed material which has been freed of asphaltic and resinous material by hydrogenation refining, vacuum-steam distillation, treatment with hydrogen-rich hydrocarbons (hydroforming), or sulfuric acid.

30 CFR 201.100 - Responsibilities of the Associate Director for Minerals Revenue Management.

Science.gov (United States)

2010-07-01

... 30 Mineral Resources 2 2010-07-01 2010-07-01 false Responsibilities of the Associate Director for Minerals Revenue Management. 201.100 Section 201.100 Mineral Resources MINERALS MANAGEMENT SERVICE, DEPARTMENT OF THE INTERIOR MINERALS REVENUE MANAGEMENT GENERAL Oil and Gas, Onshore § 201.100...

Migration kinetics of mineral oil hydrocarbons from recycled paperboard to dry food: monitoring of two real cases.

Science.gov (United States)

Lorenzini, R; Biedermann, M; Grob, K; Garbini, D; Barbanera, M; Braschi, I

2013-01-01

Mineral oil hydrocarbons present in printing inks and recycled paper migrate from paper-based food packaging to foods primarily through the gas phase. Migration from two commercial products packed in recycled paperboard, i.e. muesli and egg pasta, was monitored up to the end of their shelf life (1 year) to study the influence of time, storage conditions, food packaging structure and temperature. Mineral oil saturated and aromatic hydrocarbons (MOSH and MOAH, respectively), and diisopropyl naphthalenes (DIPN) were monitored using online HPLC-GC/FID. Storage conditions were: free standing, shelved, and packed in transport boxes of corrugated board, to represent domestic, supermarket and warehouse storage, respectively. Migration to food whose packs were kept in transport boxes was the highest, especially after prolonged storage, followed by shelved and free-standing packs. Tested temperatures were representative of refrigeration, room temperature, storage in summer months and accelerated migration testing. Migration was strongly influenced by temperature: for egg pasta directly packed in paperboard, around 30 mg kg⁻¹ of MOSH migrated in 8 months at 20°C, but in only 1 week at 40°C. Muesli was contained into an internal polyethylene bag, which firstly adsorbed hydrocarbons and later released them partly towards the food. Differently, the external polypropylene bag, containing pasta and recycled paper tray, strongly limited the migration towards the atmosphere and gave rise to the highest level of food contamination. Tests at increased temperatures not only accelerated migration, but also widened the migration of hydrocarbons to higher molecular masses, highlighting thus a difficult interpretation of data from accelerated simulation.

Preservation of bone structure and function by Lithothamnion sp. – derived minerals

Science.gov (United States)

Aslam, Muhammad Nadeem; Bergin, Ingrid; Jepsen, Karl; Kreider, Jaclynn M.; Graf, Kristin H.; Naik, Madhav; Goldstein, Steven A.; Varani, James

2013-01-01

Progressive bone mineral loss and increasing bone fragility are hallmarks of osteoporosis. A combination of minerals isolated from the red marine algae, Lithothamnion sp. was examined for ability to inhibit bone mineral loss in female mice maintained on either a standard rodent chow (control) diet or a high-fat western diet (HFWD) for 5-, 12- and 18-months. At each time-point, femora were subjected to μ-CT analysis and biomechanical testing. A subset of caudal vertebrae was also analyzed. Following this, individual elements were assessed in bones. Serum levels of the 5b isoform of tartrate-resistant acid phosphatase (TRAP) and procollagen type I propeptide (P1NP) were also measured. Trabecular bone loss occurred in both diets (evident as early as 5-months). Cortical bone increased through month-5 and then declined. Cortical bone loss was primarily in mice on the HFWD. Inclusion of the minerals in the diet reduced bone mineral loss in both diets and improved bone strength. Bone mineral density (BMD) was also enhanced by these minerals. Of several cationic minerals known to be important to bone health, only strontium was significantly increased in bone tissue from animals fed the mineral diets, but the increase was large (5–10 fold). Serum levels of TRAP were consistently higher in mice receiving the minerals but levels of P1NP were not. These data suggest that trace minerals derived from marine red algae may be used to prevent progressive bone mineral loss in conjunction with calcium. Mineral supplementation could find use as part of an osteoporosis - prevention strategy. PMID:24096551

Solid-State Fermentation Reduces Phytic Acid Level, Improves the Profile of Myo-Inositol Phosphates and Enhances the Availability of Selected Minerals in Flaxseed Oil Cake

Science.gov (United States)

2017-01-01

Summary Flaxseed oil cake was subjected to fermentation with Rhizopus oligosporus (DSM 1964 and ATCC 64063), and the phytate (InsP6) content, myo-inositol phosphate profile and in vitro bioavailability of essential minerals were studied. Flaxseed oil cake had a phytate mass fraction of 13.9 mg/g. A 96-hour fermentation of flaxseed oil cake by R. oligosporus DSM 1964 and R. oligosporus ATCC 64063 decreased the InsP6 content by 48 and 33%, respectively. The strains had different phytate-degrading activities: fermentation of flaxseed oil cake with R. oligosporus DSM 1964 was more advantageous, yielding InsP3-5 as a predominating myo-inositol compound, while fermentation with R. oligosporus ATCC 64603 produced predominantly InsP5-6. Solid-state fermentation of flaxseed oil cake enhanced in vitro bioavailability of calcium by 14, magnesium by 3.3 and phosphorus by 2–4%. PMID:29089855

A laboratory study on formation of oil-SPM aggregates using the NIST standard reference material 1941b. Volume 1

International Nuclear Information System (INIS)

Khelifa, A.; Fieldhouse, B.; Wang, Z.; Yang, C.; Landriault, M.; Fingas, M.; Brown, C.E.; Gamble, L.; Pjontek, D.

2007-01-01

The dispersion of spilled oil in water can be enhanced by a natural process in which suspended particulate matter (SPM) combines with oil droplets to form Oil-SPM aggregates (OSA). A laboratory setup and procedure were developed in this study to examine the formation of OSAs in which the sediment (Standard Reference Material 1941b) was mixed with Arabian Medium, Alaska North Slope and South Louisiana crudes at concentrations varying from 25 to 300 mg/L. The OSAs were separated from the bulk water using a newly developed procedure. Gas chromatography combined with flame ionization analysis was used to measure the oil trapped in the OSAs. The sediment trapped in the sinking OSAs was then isolated for gravimetric quantification. This procedure has the potential to isolate sinking OSAs with minimum alteration with dispersed oil. Oil mass of less than 2 mg trapped in OSAs was measured with 0.8 mg uncertainty at a 95 per cent confidence level. This setup was capable of imaging droplets of 0.1 μg and up in size. The study showed that formation of sinking OSAs reaches maximum efficiency at an optimum oil to sediment ratio that decreases from 0.5 to approximately 0.1 when the ratio between oil density and the water density increases from 0.84 to 0.97. The percentage of oil trapped in sinking OSAs increases quickly from approximately 0.5 per cent to 30 per cent of the initial oil mass when sediment concentration increases from 25 to 100 mg/l. The highest trapping efficiency was found to decrease exponentially with oil density. 33 refs., 2 tabs., 12 figs

[Mineral elements analysis of Momordica charantiap seeds by ICP-AES and fatty acid profile identification of seed oil by GC-MS].

Science.gov (United States)

Liu, Xiao-ru; Deng, Ze-yuan; Fan, Ya-wei; Li, Jing; Liu, Zhi-han

2010-08-01

In the present study, a special kind of Momordica charantia seeds produced in Hai Nan was selected and analyzed. Firstly, inductively coupled plasma-atomic emission spectrophotometry (ICP-AES) was used to determine the mineral elements. It was clear that the contents of K, Mg and P are the highest in the seeds; Cr and Zn takes up to 5.65% and 45.45% high, especially, which are rare in plant foods. These minerals, especially Cr and Zn might have a complex effect on those proteins or polysaccharides and form a stronger anticipation of hyperlipidemia, hyperglycemia and cholesterol. Secondly, seed oil was extracted by supercritical CO2 extraction with a yield ratio of 36.89, and the fatty acids were treated by methylation in alkaline process and purified by thin-layer chromatography, then analyzed by gas chromatography-mass spectrometer (GC-MS) identification. The saturated fatty acids (SFA) take up 36.712, and mainly are stearic acid; monounsaturated fatty acid (MUFA) is only 3.33% which is dominantly linoleic acid (LA); Polyunsaturated fatty acid (PUFA) accounted for 59.96%, and the alpha-eleostearic acid takes up 54.26% as the main fatty acids in all. The plentiful alpha-eleostearic acid leads to strong effects of inhibiting tumor cell proliferation, lowering blood fat, anti-cancer, anti-inflammatory and preventing cardiovascular diseases, and so on. Knowing clearly the mineral elements distribution and identifying the composition of fatty acid, especially the main fatty acids in the oil, are both of great guiding importance to further exploit the clinical and edible value in Momordica charantiap seeds.

Area balance and strain in an extensional fault system: Strategies for improved oil recovery in fractured chalk, Gilbertown Field, southwestern Alabama. Final report, March 1996--September 1998

Energy Technology Data Exchange (ETDEWEB)

Pashin, J.C.; Raymond, D.E.; Rindsberg, A.K.; Alabi, G.G.; Carroll, R.E.; Groshong, R.H.; Jin, G.

1998-12-01

This project was designed to analyze the structure of Mesozoic and Tertiary strata in Gilbertown Field and adjacent areas to suggest ways in which oil recovery can be improved. The Eutaw Formation comprises 7 major flow units and is dominated by low-resistivity, low-contrast play that is difficult to characterize quantitatively. Selma chalk produces strictly from fault-related fractures that were mineralized as warm fluid migrated from deep sources. Resistivity, dipmeter, and fracture identification logs corroborate that deformation is concentrated in the hanging-wall drag zones. New area balancing techniques were developed to characterize growth strata and confirm that strain is concentrated in hanging-wall drag zones. Curvature analysis indicates that the faults contain numerous fault bends that influence fracture distribution. Eutaw oil is produced strictly from footwall uplifts, whereas Selma oil is produced from fault-related fractures. Clay smear and mineralization may be significant trapping mechanisms in the Eutaw Formation. The critical seal for Selma reservoirs, by contrast, is where Tertiary clay in the hanging wall is juxtaposed with poorly fractured Selma chalk in the footwall. Gilbertown Field can be revitalized by infill drilling and recompletion of existing wells. Directional drilling may be a viable technique for recovering untapped oil from Selma chalk. Revitalization is now underway, and the first new production wells since 1985 are being drilled in the western part of the field.

Assessment of Antioxidant Indices after incorporating Crude Oil ...

African Journals Online (AJOL)

ADOWIE PERE

Exposure to crude oil pollution leads to the formation ... vitamin/mineral mixture (5 %). The food ..... hepatic antioxidant enzymes against cadmium induced liver ... Interaction of crude oil with alpha-tocopherol: ... Essential oil from Monodora.

Trapping guidelines for area-wide fruit fly programmes

International Nuclear Information System (INIS)

2003-11-01

Different traps and lures have been developed and used over decades to survey fruit fly populations. The first attractant for male fruit flies was methyl eugenol (ME) (for Bactrocera zonata, Howlett, 1912) followed by kerosene for Mediterranean fruit fly, Ceratitis capitata, (medfly), Severin and Severin, 1913. In 1956, Angelica seed oil was used to trap medfly (Steiner et al, 1957). Beroza et al. (1961) discovered trimedlure (TML) to be effective for the same purpose. Beroza and Green, 1963, demonstrated cuelure to be an effective attractant for Bactrocera cucurbitae. Food baits based on protein solutions, fermenting sugar solutions, fruit juices, and vinegar have been used since 1918 for the capture of females of several species. The McPhail trap was the first device to be used with protein baits (McPhail, 1929). Steiner traps were developed in 1957 (Steiner et al., 1957) and Jackson traps in 1971 for TML (Harris et al., 1971). These traps are currently used in various countries for fruit fly surveys in support of control activities and eradication campaigns. The combination of a McPhail trap with a protein attractant, Jackson trap with TML, and the Steiner trap with ME or cuelure (CUE), has remained unchanged for several decades. Global trends in increasing food quality, revenue sources, and fruit and vegetable trade, has resulted in an increased worldwide movement of fruit fly species and requires refinement of survey systems. After years of validating trapping technology through coordinated research programmes (CRP's) and extensive technical assistance to member countries, the Joint Division FAO/IAEA proposes the use of proven technologies in improving trap sensitivity in area-wide fruit fly control programmes (IAEA 1996 and IAEA 1998). These proven technologies include the use of synthetic food lures such as female attractants that can be used for several species of Anastrepha, Bactrocera and Ceratitis. Other citations of information on these developments are

Trapping guidelines for area-wide fruit fly programmes

Energy Technology Data Exchange (ETDEWEB)

NONE

2003-11-01

Different traps and lures have been developed and used over decades to survey fruit fly populations. The first attractant for male fruit flies was methyl eugenol (ME) (for Bactrocera zonata, Howlett, 1912) followed by kerosene for Mediterranean fruit fly, Ceratitis capitata, (medfly), Severin and Severin, 1913. In 1956, Angelica seed oil was used to trap medfly (Steiner et al, 1957). Beroza et al. (1961) discovered trimedlure (TML) to be effective for the same purpose. Beroza and Green, 1963, demonstrated cuelure to be an effective attractant for Bactrocera cucurbitae. Food baits based on protein solutions, fermenting sugar solutions, fruit juices, and vinegar have been used since 1918 for the capture of females of several species. The McPhail trap was the first device to be used with protein baits (McPhail, 1929). Steiner traps were developed in 1957 (Steiner et al., 1957) and Jackson traps in 1971 for TML (Harris et al., 1971). These traps are currently used in various countries for fruit fly surveys in support of control activities and eradication campaigns. The combination of a McPhail trap with a protein attractant, Jackson trap with TML, and the Steiner trap with ME or cuelure (CUE), has remained unchanged for several decades. Global trends in increasing food quality, revenue sources, and fruit and vegetable trade, has resulted in an increased worldwide movement of fruit fly species and requires refinement of survey systems. After years of validating trapping technology through coordinated research programmes (CRP's) and extensive technical assistance to member countries, the Joint Division FAO/IAEA proposes the use of proven technologies in improving trap sensitivity in area-wide fruit fly control programmes (IAEA 1996 and IAEA 1998). These proven technologies include the use of synthetic food lures such as female attractants that can be used for several species of Anastrepha, Bactrocera and Ceratitis. Other citations of information on these developments are

Process for treating oil-chalk

Energy Technology Data Exchange (ETDEWEB)

1925-10-20

A process for treating oil-chalk or similar oil-containing minerals is characterized in that the material is treated in a stream of air diluted with indifferent gases at a temperature of about 150/sup 0/ to 160/sup 0/C.

Efficacy of mineral oil combined with insecticides for the control of aphid virus vectors to reduce potato virus Y infections in seed potatoes (Solanum tuberosum)

DEFF Research Database (Denmark)

Hansen, Lars M.; Nielsen, Steen L.

2012-01-01

Aphids are major vectors of plant viruses. Potato virus Y (PVY) is the most important aphid-transmitted virus affecting potato crops in Denmark. Because of a changed seed potato growing strategy, the seed potato area in Denmark is changing from regions with a low average temperature to regions...... with a higher average temperature. This means that the aphids may infest the potato crops earlier and the population development of the aphids may be faster, and consequently PVY may more easily become epidemic in seed potato crops. With a view to reducing the spread of PVY a 3-year experiment was carried out...... with a combination of mineral oil and insecticides. In 2005 and 2007 when a very high number of aphids were present, nearly all plants were infected with PVY. In 2006 with a lower number of aphids a smaller proportion of the plants were infected, and a tendency to a lower PVY incidence in mineral-oil treated plots...

Fast selective trapping and release of picoliter droplets in a 3D microfluidic PDMS multi-trap system with bubbles.

Science.gov (United States)

Rambach, Richard W; Biswas, Preetika; Yadav, Ashutosh; Garstecki, Piotr; Franke, Thomas

2018-02-12

The selective manipulation and incubation of individual picoliter drops in high-throughput droplet based microfluidic devices still remains challenging. We used a surface acoustic wave (SAW) to induce a bubble in a 3D designed multi-trap polydimethylsiloxane (PDMS) device to manipulate multiple droplets and demonstrate the selection, incubation and on-demand release of aqueous droplets from a continuous oil flow. By controlling the position of the acoustic actuation, individual droplets are addressed and selectively released from a droplet stream of 460 drops per s. A complete trapping and releasing cycle can be as short as 70 ms and has no upper limit for incubation time. We characterize the fluidic function of the hybrid device in terms of electric power, pulse duration and acoustic path.

Status and trends in nuclear techniques in the mineral industry in India

International Nuclear Information System (INIS)

Eapen, A.C.; Rao, S.M.; Murthy, T.S.

1991-01-01

The status and use of nuclear techniques in the various parts of the mineral industry in India are reviewed. The techniques and applications include nucleonic level control in ore hoppers; radiometric density gauges; coal ash monitoring using x-ray backscattering; mineral analysis by x-ray fluorescence and radioisotope analysis; neutron and gamma logging of oil wells; radiotracer techniques in bauxite processing and in the oil industry. (UK)

Degradation diagnosis of transformer insulating oils with terahertz time-domain spectroscopy

Science.gov (United States)

Kang, Seung Beom; Kim, Won-Seok; Chung, Dong Chul; Joung, Jong Man; Kwak, Min Hwan

2017-12-01

We report the frequency-dependent complex optical constants, refractive index and absorption, and complex dielectric properties over the frequency range from 0.2 to 3.0 THz for aged power transformer mineral insulating oils. These results have been obtained using terahertz time-domain spectroscopy (THz-TDS) and demonstrate the double-Debye relaxation behavior of the mineral insulating oil. The measured complex optical and dielectric characteristics can be important benchmarks for liquid molecular dynamics and theoretical studies of insulating oils. Due to clear differences in THz responses of aged mineral insulating oils, THz-TDS can be used as a novel on-site diagnostic technique to monitor the insulation condition in aged power transformers and may be valuable alternative to characterize other developing eco-friendly insulating oils and industrial liquids.

Performance evaluation of NEEM oil and HONGE Oil as cutting fluid in drilling operation of mild steel

Science.gov (United States)

Jyothi, P. N.; Susmitha, M.; Sharan, P.

2017-04-01

Cutting fluids are used in machining industries for improving tool life, reducing work piece and thermal deformation, improving surface finish and flushing away chips from the cutting zone. Although the application of cutting fluids increases the tool life and Machining efficiency, but it has many major problems related to environmental impacts and health hazards along with recycling & disposal. These problems gave provision for the introduction of mineral, vegetable and animal oils. These oils play an important role in improving various machining properties, including corrosion protection, lubricity, antibacterial protection, even emulsibility and chemical stability. Compared to mineral oils, vegetable oils in general possess high viscosity index, high flash point, high lubricity and low evaporative losses. Vegetable oils can be edible or non-edible oils and Various researchers have proved that edible vegetable oils viz., palm oil, coconut oil, canola oil, soya bean oil can be effectively used as eco-friendly cutting fluid in machining operations. But in present situations harnessing edible oils for lubricants formation restricts the use due to increased demands of growing population worldwide and availability. In the present work, Non-edible vegetable oil like Neem and Honge are been used as cutting fluid for drilling of Mild steel and its effect on cutting temperature, hardness and surface roughness are been investigated. Results obtained are compared with SAE 20W40 (petroleum based cutting fluid)and dry cutting condition.

Evaluation of kraft paper chemical byproducts in insulating mineral oil of energized transformers; Avaliacao de subprodutos quimicos de papel tipo kraft em oleo mineral isolante de transformadores energizados

Energy Technology Data Exchange (ETDEWEB)

Portella, Mariana d' Orey Gaivao; Portella, Kleber Franke; Swinka Filho, Vitoldo; Silva, Guilherme Cunha da; Stocco, Guilherme Barrachina; Batista, Douglas Antonio; Sabec, Daiane Cristina; Deger, Claudio Adriano [Instituto de Tecnologia para o Desenvolvimento (LATEC), Curitiba, PR (Brazil)], E-mails: mariana.portella@lactec.org.br, portella@laclec.org.br; Andreoli, Mario Carlos [Centro de Transmissao de Energia Eletrica Paulista (CTEEP), Sao Paulo, SP (Brazil)], E-mail: mandreoli@cteep.com.br

2011-10-15

The insulating paper is a major determinant of the remaining lifetime of an electrical transformer, since it is not possible to analyse or replace this equipment during operation. However, using the quantification of the furanic compounds concentration formed in mineral oil, it is possible to infer about the quality of the material, confirming the presence of degradation. Given the existence of new kinds of solid insulation, this research aimed at studying a new analytical methodology, using the techniques of liquid chromatography with mass detection of these substances in order to increase the reliability of the results, assisting the preventive maintenance. (author)

25 CFR 225.36 - Minerals agreement cancellation; Bureau of Indian Affairs notice of noncompliance.

Science.gov (United States)

2010-04-01

... 25 Indians 1 2010-04-01 2010-04-01 false Minerals agreement cancellation; Bureau of Indian Affairs... INTERIOR ENERGY AND MINERALS OIL AND GAS, GEOTHERMAL, AND SOLID MINERALS AGREEMENTS Minerals Agreements § 225.36 Minerals agreement cancellation; Bureau of Indian Affairs notice of noncompliance. (a) If the...

Experimental study of the processes of aerosol production for technical oil cleanup

Directory of Open Access Journals (Sweden)

Medvedev Gennadiy

2017-01-01

Full Text Available From the experimental study of mechanism of fine mist formation in oil-flooded screw compressor it has been drawn the conclusion on evaporation of fine aerosol of mineral oil that has been obtained in two ways: on the basis of oil spray with mechanical burner and on the basis of volume condensation of oil vapour in air. The given paper presents experimental facility for the production of mineral oil aerosol and also comparison of the experimentation results with calculations.

Pathogenic characteristics of yeasts isolated from vaginal secretion preserved under mineral oil

Directory of Open Access Journals (Sweden)

B Severo Gomes

2011-01-01

Full Text Available In order to evaluate the pathogenicity of yeasts isolated from vaginal secretion of pregnant and non-pregnant women - stored in mineral oil at the URM Mycology Collection, Department of Mycology, Federal University of Pernambuco - 30 samples belonging to the genera Candida, Rhodotorula, Trichosporon, and Kloeckera, were studied regarding their pathogenic characteristics, ability to grow at room temperature (28°C ± 1°C, 37°C, and 42°C for 72 hours, and production of both phospholipase and proteinase. Results showed that all 30 isolates (100% were able to grow at room temperature and 37°C, and that 17 samples (57% were able to grow at 42°C. Evaluation of enzymatic activity showed protease activity in only two isolates (7%, namely C. maritima and C. obtusa. Phospholipase activity was detected in 20 isolates (67% using soy lecithin as substrate at different temperatures. The characterization of yeasts isolated from vaginal secretion and determination of their enzymatic activity may contribute to understanding the epidemiology of vulvovaginitis and assist in the treatment of patients.

Evaluation of replacement thread lubricants for red lead and graphite in mineral oil

Energy Technology Data Exchange (ETDEWEB)

Jungling, T.L.; Rauth, D.R.; Goldberg, D.

1998-04-30

Eight commercially available thread lubricants were evaluated to determine the best replacement for Red Lead and Graphite in Mineral Oil (RLGMO). The evaluation included coefficient of friction testing, high temperature anti-seizing testing, room temperature anti-galling testing, chemical analysis for detrimental impurities, corrosion testing, off-gas testing, and a review of health and environmental factors. The coefficient of friction testing covered a wide variety of factors including stud, nut, and washer materials, sizes, manufacturing methods, surface coatings, surface finishes, applied loads, run-in cycles, and relubrication. Only one lubricant, Dow Corning Molykote P37, met all the criteria established for a replacement lubricant. It has a coefficient of friction range similar to RLGMO. Therefore, it can be substituted directly for RLGMO without changing the currently specified fastener torque values for the sizes, materials and conditions evaluated. Other lubricants did not perform as well as Molykote P37 in one or more test or evaluation categories.

Analysis of mineral trapping for CO{sub 2} disposal in deep aquifers

Energy Technology Data Exchange (ETDEWEB)

Xu, Tianfu; Apps, John A.; Pruess, Karsten

2001-07-20

CO{sub 2} disposal into deep aquifers has been suggested as a potential means whereby atmospheric emissions of greenhouse gases may be reduced. However, our knowledge of the geohydrology, geochemistry, geophysics, and geomechanics of CO{sub 2} disposal must be refined if this technology is to be implemented safely, efficiently, and predictably. As a prelude to a fully coupled treatment of physical and chemical effects of CO{sub 2} injection, we have analyzed the impact of CO{sub 2} immobilization through carbonate precipitation. A survey of all major classes of rock-forming minerals, whose alteration would lead to carbonate precipitation, indicated that very few minerals are present in sufficient quantities in aquifer host rocks to permit significant sequestration of CO{sub 2}. We performed batch reaction modeling of the geochemical evolution of three different aquifer mineralogies in the presence of CO{sub 2} at high pressure. Our modeling considered (1) redox processes that could be important in deep subsurface environments, (2) the presence of organic matter, (3) the kinetics of chemical interactions between the host rock minerals and the aqueous phase, and (4) CO{sub 2} solubility dependence on pressure, temperature and salinity of the system. The geochemical evolution under both natural background and CO{sub 2} injection conditions was evaluated. In addition, changes in porosity were monitored during the simulations. Results indicate that CO{sub 2} sequestration by matrix minerals varies considerably with rock type. Under favorable conditions the amount of CO{sub 2} that may be sequestered by precipitation of secondary carbonates is comparable with and can be larger than the effect of CO{sub 2} dissolution in pore waters. The precipitation of ankerite and siderite is sensitive to the rate of reduction of ferric mineral precursors such as glauconite, which in turn is dependent on the reactivity of associated organic material. The accumulation of carbonates in

A Review on Properties, Opportunities, and Challenges of Transformer Oil-Based Nanofluids

Directory of Open Access Journals (Sweden)

Muhammad Rafiq

2016-01-01

Full Text Available The mineral oil or synthetic oil in conjunction with paper is mainly being applied as dielectric medium in many of the high voltage apparatus. However, the advent of high voltage levels such high voltage alternating current (HVAC and high voltage direct current (HVDC has prompted researchers to direct their focus onto an insulation system which can bear the rising high voltage levels. The modern insulating liquid material development is guided by various factors such as high electrical insulation requirements and other safety and economic considerations. Therefore transformer manufacturer companies have to design transformers with these new specific requirements. The transformer oil-based nanofluids with improved dielectric and thermal properties have the potential to replace mineral oil base products in the market place. They are favorable because they function more superior than mineral oil and they contribute definite insulating and thermal gains. This paper reviews recent status of nanofluids use as transformer oils. The nanofluids used as transformer oils are presented and their advantages are described in comparison with mineral oil. The multiple experimental works carried out by different researchers are described, providing an overview of the current research conducted on nanofluids. In addition scope and challenges being confronted in this area of research are clearly presented.

Numerical simulation of CO2 disposal by mineral trapping in deep aquifers

International Nuclear Information System (INIS)

Xu Tianfu; Apps, John A.; Pruess, Karsten

2004-01-01

Carbon dioxide disposal into deep aquifers is a potential means whereby atmospheric emissions of greenhouse gases may be reduced. However, our knowledge of the geohydrology, geochemistry, geophysics, and geomechanics of CO 2 disposal must be refined if this technology is to be implemented safely, efficiently, and predictably. As a prelude to a fully coupled treatment of physical and chemical effects of CO 2 injection, the authors have analyzed the impact of CO 2 immobilization through carbonate mineral precipitation. Batch reaction modeling of the geochemical evolution of 3 different aquifer mineral compositions in the presence of CO 2 at high pressure were performed. The modeling considered the following important factors affecting CO 2 sequestration: (1) the kinetics of chemical interactions between the host rock minerals and the aqueous phase, (2) CO 2 solubility dependence on pressure, temperature and salinity of the system, and (3) redox processes that could be important in deep subsurface environments. The geochemical evolution under CO 2 injection conditions was evaluated. In addition, changes in porosity were monitored during the simulations. Results indicate that CO 2 sequestration by matrix minerals varies considerably with rock type. Under favorable conditions the amount of CO 2 that may be sequestered by precipitation of secondary carbonates is comparable with and can be larger than the effect of CO 2 dissolution in pore waters. The precipitation of ankerite and siderite is sensitive to the rate of reduction of Fe(III) mineral precursors such as goethite or glauconite. The accumulation of carbonates in the rock matrix leads to a considerable decrease in porosity. This in turn adversely affects permeability and fluid flow in the aquifer. The numerical experiments described here provide useful insight into sequestration mechanisms, and their controlling geochemical conditions and parameters

The ecotoxicology of vegetable versus mineral based lubricating oils 3. Coral fertilization and adult corals

International Nuclear Information System (INIS)

Mercurio, Philip; Negri, Andrew P.; Burns, Kathryn A.; Heyward, Andrew J.

2004-01-01

Biodegradable vegetable-derived lubricants (VDL) might be less toxic to marine organisms than mineral-derived oils (MDL) due to the absence of high molecular weight aromatics, but this remains largely untested. In this laboratory study, adult corals and coral gametes were exposed to various concentrations of a two-stroke VDL-1A and a corresponding MDL to determine which lubricant type was more toxic to each life stage. In the fertilization experiment, gametes from the scleractinian coral Acropora microphthalma were exposed to water-accommodated fractions (WAF) of VDL-1A and MDL for four hours. The MDL and VDL-1A WAFs inhibited normal fertilization of the corals at 200 μg l -1 total hydrocarbon content (THC) and 150 μg l -1 THC respectively. Disturbance of a stable coral-dinoflagellate symbiosis is regarded as a valid measure of sub-lethal stress in adult corals. The state of the symbiosis in branchlets of adult colonies of Acropora formosa was monitored using indicators such as dinoflagellate expulsion and dark-adapted photosystem II yields of dinoflagellate (using pulse amplitude modulation fluorescence). An effect on symbiosis was measurable following 48 h exposure to the lubricants at concentrations of 190 μg l -1 and 37 μg l -1 THC for the MDL and VDL-1A respectively. GC/MS revealed that the main constituent of the VDL-1A WAF was the compound coumarin, added by the manufacturer to improve odour. The fragrance containing coumarin was removed from the lubricant formulation and the toxicity towards adult corals re-examined. The coumarin-free VDL-2 exhibited significantly less toxicity towards the adult corals than all of the other oil types tested, with the only measurable effect being a slight but significant drop in photosynthetic efficiency at 280 μg l -1 . - Vegetable-derived lubricants were less toxic to adult corals than their mineral counterparts

Photoionization of radiation-induced traps in quartz and alkali feldspars.

Science.gov (United States)

Hütt, G; Jaek, I; Vasilchenko, V

2001-01-01

For the optimization of luminescence dating and dosimetry techniques on the basis of the optically stimulated luminescence, the stimulation spectra of quartz and alkali feldspars were measured in the spectral region of 250-1100 nm using optically stimulated afterglow. Optically stimulated luminescence in all studied spectral regions is induced by the same kind of deep traps, that produce thermoluminescence in the regions of palaeodosimetric peaks for both minerals. The mechanism for photoionization of deep traps was proposed as being due to delocalization of the excited state of the corresponding lattice defects. The excited state overlaps the zone states; i.e. is situated in the conduction band. Because of the high quantum yield of deep electron trap ionization in the UV spectral region, the present aim was to study the possibility of using UV-stimulation for palaeodose reconstruction.

Photoionization of radiation-induced traps in quartz and alkali feldspars

International Nuclear Information System (INIS)

Huett, G.; Jaek, I.; Vasilchenko, V.

2001-01-01

For the optimization of luminescence dating and dosimetry techniques on the basis of the optically stimulated luminescence, the stimulation spectra of quartz and alkali feldspars were measured in the spectral region of 250-1100 nm using optically stimulated afterglow. Optically stimulated luminescence in all studied spectral regions is induced by the same kind of deep traps, that produce thermoluminescence in the regions of palaeodosimetric peaks for both minerals. The mechanism for photoionization of deep traps was proposed as being due to delocalization of the excited state of the corresponding lattice defects. The excited state overlaps the zone states; i.e. is situated in the conduction band. Because of the high quantum yield of deep electron trap ionization in the UV spectral region, the present aim was to study the possibility of using UV-stimulation for palaeodose reconstruction

Photoionization of radiation-induced traps in quartz and alkali feldspars

Energy Technology Data Exchange (ETDEWEB)

Huett, G. E-mail: hutt@pdos.gi.ee; Jaek, I.; Vasilchenko, V

2001-01-15

For the optimization of luminescence dating and dosimetry techniques on the basis of the optically stimulated luminescence, the stimulation spectra of quartz and alkali feldspars were measured in the spectral region of 250-1100 nm using optically stimulated afterglow. Optically stimulated luminescence in all studied spectral regions is induced by the same kind of deep traps, that produce thermoluminescence in the regions of palaeodosimetric peaks for both minerals. The mechanism for photoionization of deep traps was proposed as being due to delocalization of the excited state of the corresponding lattice defects. The excited state overlaps the zone states; i.e. is situated in the conduction band. Because of the high quantum yield of deep electron trap ionization in the UV spectral region, the present aim was to study the possibility of using UV-stimulation for palaeodose reconstruction.

Assessment of undiscovered oil and gas resources in the Ventura Basin Province, California, 2016

Science.gov (United States)

Tennyson, Marilyn E.; Schenk, Christopher J.; Pitman, Janet K.; Lillis, Paul G.; Klett, Timothy R.; Brownfield, Michael E.; Finn, Thomas M.; Gaswirth, Stephanie B.; Hawkins, Sarah J.; Marra, Kristen R.; Mercier, Tracey J.; Le, Phuong A.; Leathers-Miller, Heidi M.

2017-10-02

The U.S. Geological Survey (USGS) completed a geology-based assessment of undiscovered, technically recoverable conventional and continuous oil and gas resources in the part of the Ventura Basin Province that lies onshore or within State waters (within 3 miles of the shoreline) of California (fig. 1). Conventional oil and gas resources are those that have migrated upward into structural or stratigraphic traps from deep zones where the oil and gas is generated; water is present below the oil or gas. Continuous accumulations, in contrast, are those in which oil or gas is pervasively present in essentially all wells that penetrate them, that may not be structurally or stratigraphically trapped, and that typically lack oil-water or gas-water contacts. They are commonly produced with well-stimulation technology, such as hydraulic fracturing, referred to as “unconventional.” The same stimulation technology, however, is also used in many conventionally trapped accumulations. We estimated both the likely range of oil and gas volumes remaining to be discovered in accumulations similar to existing conventional oil and gas fields in the Ventura Basin Province (previously assessed by Keller [1995] as 1,060 million barrels of oil [MMBO], 1,900 billion cubic feet of gas [BCFG], and 60 million barrels of natural gas liquids [MMBNGL]), and the potential for oil and gas that might be present in a continuous accumulation at extreme depth in the floor of the basin.

Effect of Fe{sub 3}O{sub 4} nanoparticles on positive streamer propagation in transformer oil

Energy Technology Data Exchange (ETDEWEB)

Lv, Yuzhen, E-mail: yzlv@ncepu.edu.cn [Beijing Key Laboratory of High Voltage and EMC, School of Electric and Electronic Engineering, North China Electric Power University, Beijing, 102206 (China); School of Energy, Power and Mechanical Engineering, North China Electric Power University, Beijing, 102206 (China); Wang, Qi; Ge, Yang [Beijing Key Laboratory of High Voltage and EMC, School of Electric and Electronic Engineering, North China Electric Power University, Beijing, 102206 (China); Zhou, You [Hunan Province Key Laboratory of Smart Grids Operation and Control, Changsha University of Science and Technology, Changsha, 410076 (China); Li, Chengrong, E-mail: lcr@ncepu.edu.cn; Qi, Bo [Beijing Key Laboratory of High Voltage and EMC, School of Electric and Electronic Engineering, North China Electric Power University, Beijing, 102206 (China); State Key Laboratory of Alternate Electrical Power System with Renewable Energy Sources, North China Electric Power University, Beijing, 102206 (China)

2016-03-15

Fe{sub 3}O{sub 4} nanoparticles with an average diameter of 10 nm were prepared and used to modify streamer characteristic of transformer oil. It was found that positive streamer propagation velocity in transformer oil-based Fe{sub 3}O{sub 4} nanofluid is greatly reduced by 51% in comparison with that in pure oil. The evolution of streamer shape is also dramatically affected by the presence of nanoparticles, changing from a tree-like shape with sharp branches in pure oil to a bush-like structure with thicker and denser branches in nanofluid. The TSC results reveal that the modification of Fe{sub 3}O{sub 4} nanoparticle can greatly increase the density of shallow trap and change space charge distribution in nanofluid by converting fast electrons into slow electrons via trapping and de-trapping process in shallow traps. These negative space charges induced by nanoparticles greatly alleviate the electric field distortion in front of the positive streamer tip and significantly hinder the propagation of positive streamer.

Performance of palm oil as a biobased machining lubricant when drilling inconel 718

OpenAIRE

Abd Rahim Erween; Sasahara Hiroyuki

2017-01-01

Metalworking fluid acts as cooling and lubrication agent at the cutting zone in the machining process. However, conventional Metalworking fluid such mineral oil gives negative impact on the human and environment. Therefore, the manufacture tends to substitute the mineral oil to bio-based oil such as vegetables and synthetic oil. In this paper, the drilling experiment was carried out to evaluate the efficiency of palm oil and compare it with minimal quantity lubrication technique using synthet...

Process of transforming into light oils heavy oils from carbonization of lignites, coals, etc

Energy Technology Data Exchange (ETDEWEB)

Mony, H

1926-12-20

A process is described for transforming into light oils the heavy oils coming from the carbonization of lignites, peats, coals, and shales, and heavy oils from original minerals and vegetables, consisting of heating the heavy oils or tars in the presence of one or more solid or liquid substances conveniently chosen, with a veiw to effect distillation of the oils under atmospheric pressure at an appropriate temperature, the solids or liquid substances favoring the formation of light products under the influence of heat, being preferably added to the oil before admitting it to the retort and heating, so that the light oils are obtained from the heavy oils in a single operation.

Capillary pressure - saturation relations in quartz and carbonate sands: Limitations for correlating capillary and wettability influences on air, oil, and supercritical CO2 trapping

Science.gov (United States)

Tokunaga, T. K.; Wang, S.; Wan, J.; Dong, W.; Kim, Y.

2016-12-01

Capillary pressure (Pc) - saturation (Sw) relations are essential for predicting equilibrium and flow of immiscible fluid pairs in soils and deeper geologic formations. In systems that are difficult to measure, behavior is often estimated based on capillary scaling of easily measured Pc-Sw relations (e.g., air-water, and oil-water), yet the reliability of such approximations needs to be examined. In this study, seventeen sets of brine drainage and imbibition curves were measured with air-brine, decane-brine, and supercritical (sc) CO2-brine in homogeneous quartz and carbonate sands, using porous plate systems under ambient (0.1 MPa, 23 °C) and reservoir (12.0 MPa, 45 °C) conditions. Comparisons between these measurements showed significant differences in residual nonwetting phase saturation, Snw,r. Through applying capillary scaling, changes in interfacial properties were indicated, particularly wettability. With respect to the residual trapping of the nonwetting phases, Snwr, CO2 > Snwr, decane > Snwr, air. Decane-brine and scCO2-brine Pc-Sw curves deviated significantly from predictions assuming hydrophilic interactions. Moreover, neither the scaled capillary behavior nor Snw,r for scCO2-brine were well represented by decane-brine, apparently because of differences in wettability and viscosities, indicating limitations for using decane (and other organic liquids) as a surrogate fluid in studies intended to apply to geological carbon sequestration. Thus, challenges remain in applying scaling for predicting capillary trapping and multiphase displacement processes across such diverse fields as vadose zone hydrology, enhanced oil recovery, and geologic carbon sequestration.

Nylon 6,6 Nonwoven Fabric Separates Oil Contaminates from Oil-in-Water Emulsions.

Directory of Open Access Journals (Sweden)

Ryan A Ortega

Full Text Available Industrial oil spills into aquatic environments can have catastrophic environmental effects. First responders to oil spills along the coast of the Gulf of Mexico in the southern United States have used spunbond nylon fabric bags and fences to separate spilled oil and oil waste from contaminated water. Low area mass density spunbond nylon is capable of sorbing more than 16 times its mass in low viscosity crude oil and more than 26 times its mass in higher viscosity gear lube oil. Nylon bags separated more than 95% of gear lube oil contaminate from a 4.5% oil-in-water emulsion. Field testing of spunbond nylon fences by oil spill first responders has demonstrated the ability of this material to contain the oily contaminate while allowing water to flow through. We hypothesize that the effectiveness of nylon as an oil filter is due to the fact that it is both more oleophilic and more hydrophilic than other commonly used oil separation materials. The nylon traps oil droplets within the fabric or on the surface, while water droplets are free to flow through the fabric to the water on the opposite side of the fabric.

IARC 1987 re-evaluation of carcinogenicity of mineral oils and bitumens - CONCAWE comments and interpretation

Energy Technology Data Exchange (ETDEWEB)

1988-10-01

Following the IARC response to CONCAWE comments on their 1987 re-evaluation of carcinogenicity of mineral oils and bitumens, CONCAWE decided that a revised version of Report No. 87/63 should be published in this report. The objective is to ensure that all who may be concerned with carcinogenicity classifications of these petroleum products, including national and international regulatory authorities, are aware of the reasons for the differences between the 1984 and 1987 IARC classifications and of CONCAWE's reservations concerning the revised classifications. This document reviews important differences between the new and previous evaluations, which are summarized in tabular form, and also indicates how the differences have occurred. In addition, it provides CONCAWE's interpretation of the available evidence, taking into account points discussed with IARC. 1 tab.

Integrated project: Microbiological and physiological studies on the presence of residual concentrations in mineral-oil-contaminated soils after rehabilitation. Final report. Pt. 2; Mikrobiologische und physiologische Untersuchungen zur Frage der Restkonzentration bei der Sanierung mineraloelkontaminierter Boeden. Abschlussbericht. T. 2

Energy Technology Data Exchange (ETDEWEB)

Miethe, D.; Riis, V.; Stimming, M.

1996-01-04

It has been known for a long time that microorganisms are able to utilise mineral oils. Today various methods are practised which exploit autochthonous microorganisms` ability to utilise mineral oils. The main problem of microbial decomposition of hydrocarbons is that mineral oil residues remain. The aim of the present research project was therefore to determine the limits of the metabolisability of the substrate and find out why residues remain. Mineral oils and residual fractions differ markedly in their decomposability. Intermediate distillates are easily decomposed to a degree of 95-97% by well-adapted consorts. For high-boiling mineral oils (bp>400 C) the degree of decomposition is approx. 60%. Extracts from contaminated sites range from 40 to 60% in their degree of decomposability. The incomplete microbial decomposition of mineral oils is mainly due to their structure. There remain chemically and thermally extremely, inert hydrocarbons (mainly aliphatic and aromatic fused-ring systems) which are either hardly metabolisable or not at all. An important factor in soils or at other contaminated sites is that some of the substrate is not available because it is bound to the matrix thus increasing the proportion of residue. The next task after examining and presenting the causes of incomplete decomposition is to minimise residual mineral oil concentrations remaining after microbial decomposition. Here the use of special surfactants or of auxiliary substrates could point a way. Project applications to this end have already been submitted to the Federal Ministry for Education and Research. (orig.) [Deutsch] Dass Mikroorganismen in der Lage sind, Mineraloele zu verwerten, ist seit langem bekannt. Verfahren, die das Potential autochthoner Mikroorganismen zur Verwertung von Mineraloelen nutzen sind Praxis. Hauptproblem beim mikrobiellen Abbau der Kohlenwasserstoffe ist das Verbleiben von Mineraloelresten. Das Ziel des Forschungsvorhabens war die Ermittlung der Grenzen

Seletividade de cultivares de soja RR® submetidos a misturas em tanque de glyphosate + chlorimuron-ethyl associadas a óleo mineral e inseticidas selectivity of soybean RR® genotypes submitted to glyphosate + chlorimuron-ethyl tank mixtures associated to mineral oil and insecticides

Directory of Open Access Journals (Sweden)

C.D.G. Maciel

2009-01-01

Full Text Available O uso de glyphosate para o controle de plantas daninhas em soja RR® apresenta características essenciais no conceito de praticabilidade. Entretanto, apesar de não permitido na legislação brasileira, tem-se aumentado a associação com outros herbicidas para manejo de espécies de difícil controle, assim como a sua mistura em tanque em combinação com inseticidas e adjuvantes. Com o objetivo de avaliar a seletividade de cultivares de soja RR® submetidos a misturas em tanque de formulações de glyphosate (Polaris®, Roundup Ready® e Roundup WG® com chlorimuron-ethyl (Classic®, e suas associações com óleo mineral (Joint Oil® e inseticidas novaluron (Gallaxy 100 EC®, permethrin (Piredan® e methomyl (Lannate BR®, um experimento foi conduzido a campo na cidade de Maracaí-SP, na safra 2006/2007. O delineamento experimental utilizado foi o de blocos ao acaso, com quatro repetições, em esquema fatorial 16 x 4, sendo 16 as associações das misturas em tanque entre as formulações de glyphosate, óleo mineral e inseticidas e quatro cultivares: Monsoy 7210RR®, Monsoy 7979RR®, BRS 245RR® e CD 214RR®. Sintomas visuais de intoxicação inicial dos cultivares estudados foram caracterizados por clorose e encarquilhamento nas folhas para todas as misturas em tanque das formulações de glyphosate + chlorimuron-ethyl, associadas ou não ao óleo mineral e inseticidas novaluron, permethrin e methomyl. Todas as misturas em tanque não promoveram reduções significativas de produtividade para os cultivares Monsoy 7210RR®, Monsoy 7979RR® e BRS 245RR® e controlaram Ipomoea spp. com eficácia apenas satisfatória a partir dos 21 DAA (dias após aplicação.The use of glyphosate for weed control in soybean RR® presents essential practical characteristics. However, although not allowed by the current Brazilian legislation, the association with other herbicides has been increasing for species of difficult control, as well as the use of tank

Market analysis of shale oil co-products. Summary report

Energy Technology Data Exchange (ETDEWEB)

1980-12-01

This study examines the potential for separating, upgrading and marketing sodium mineral co-products together with shale oil production. The co-products investigated are soda ash and alumina which are derived from the minerals nahcolite and dawsonite. Five cases were selected to reflect the variance in mineral and shale oil content in the identified resource. In the five cases examined, oil content of the shale was varied from 20 to 30 gallons per ton. Two sizes of facilities were analyzed for each resource case to determine economies of scale between a 15,000 barrel per day demonstration unit and a 50,000 barrel per day full sized plant. Three separate pieces of analysis were conducted in this study: analysis of manufacturing costs for shale oil and co-products; projection of potential world markets for alumina, soda ash, and nahcolite; and determination of economic viability and market potential for shale co-products.

Experimental and simulation studies on mineral trapping of CO2 with brine

International Nuclear Information System (INIS)

Soong, Y.; Goodman, A.L.; McCarthy-Jones, J.R.; Baltrus, J.P.

2004-01-01

The reaction of carbon dioxide (CO 2 ) with brine samples collected from the Oriskany Formation in Indiana County, PA, was investigated in an autoclave reactor under various conditions. A geochemical code, PHREEQC, was used as to simulate the reaction in the autoclave reactor. The combined experimental and modeling data suggests that pH (pH > 9) plays a key role in the formation of carbonate minerals. The effects of temperature and CO 2 pressure have a lesser impact on the formation of carbonate minerals

The initial rise method extended to multiple trapping levels in thermoluminescent materials

Energy Technology Data Exchange (ETDEWEB)

Furetta, C. [CICATA-Legaria, Instituto Politecnico Nacional, 11500 Mexico D.F. (Mexico); Guzman, S. [Instituto de Ciencias Nucleares, Universidad Nacional Autonoma de Mexico, A.P. 70-543, 04510 Mexico D.F. (Mexico); Ruiz, B. [Instituto de Ciencias Nucleares, Universidad Nacional Autonoma de Mexico, A.P. 70-543, 04510 Mexico D.F. (Mexico); Departamento de Agricultura y Ganaderia, Universidad de Sonora, A.P. 305, 83190 Hermosillo, Sonora (Mexico); Cruz-Zaragoza, E., E-mail: ecruz@nucleares.unam.m [Instituto de Ciencias Nucleares, Universidad Nacional Autonoma de Mexico, A.P. 70-543, 04510 Mexico D.F. (Mexico)

2011-02-15

The well known Initial Rise Method (IR) is commonly used to determine the activation energy when only one glow peak is presented and analysed in the phosphor materials. However, when the glow peak is more complex, a wide peak and some holders appear in the structure. The application of the Initial Rise Method is not valid because multiple trapping levels are considered and then the thermoluminescent analysis becomes difficult to perform. This paper shows the case of a complex glow curve structure as an example and shows that the calculation is also possible using the IR method. The aim of the paper is to extend the well known Initial Rise Method (IR) to the case of multiple trapping levels. The IR method is applied to minerals extracted from Nopal cactus and Oregano spices because the thermoluminescent glow curve's shape suggests a trap distribution instead of a single trapping level.

The initial rise method extended to multiple trapping levels in thermoluminescent materials

International Nuclear Information System (INIS)

Furetta, C.; Guzman, S.; Ruiz, B.; Cruz-Zaragoza, E.

2011-01-01

The well known Initial Rise Method (IR) is commonly used to determine the activation energy when only one glow peak is presented and analysed in the phosphor materials. However, when the glow peak is more complex, a wide peak and some holders appear in the structure. The application of the Initial Rise Method is not valid because multiple trapping levels are considered and then the thermoluminescent analysis becomes difficult to perform. This paper shows the case of a complex glow curve structure as an example and shows that the calculation is also possible using the IR method. The aim of the paper is to extend the well known Initial Rise Method (IR) to the case of multiple trapping levels. The IR method is applied to minerals extracted from Nopal cactus and Oregano spices because the thermoluminescent glow curve's shape suggests a trap distribution instead of a single trapping level.

Enhanced oil recovery using local alkaline | Akpoturi | Nigerian ...

African Journals Online (AJOL)

Improvement in productivity is one of the Oil and Gas industry's biggest challenges. About 60% of crude Oil still lay trapped in the reservoir even after primary and secondary recovery process have been completed, hence the need for a method that further improves recovery. In this study, flooding experiment was conducted ...

Volatile characteristic of trace elements during microwave pyrolysis of oil shale

Energy Technology Data Exchange (ETDEWEB)

Bai, Jing-ru; Wang, Qing; Kong, Ling-wen; Bai, Zhang [Northeast Dianli Univ., Jilin (China). Engineering Research Centre

2013-07-01

Oil shale is abundant in the world. Today, the industry of oil shale retorting for producing shale oil is developing owing to high price of oil in the world. In order to study migratory behavior of trace elements in oil shale at microwave pyrolysis, tests were performed in laboratory with oil shale of the Huadian deposit of China at different powers from 400 to 700 W. The trace elements As, Cd, Hg, Mo, Pb, Se, Cr, Cu, Ni, V, Zn, Ba, Co, Mn present in oil shale and shale char were determined by the inductively coupled plasma-mass spectrometry (ICP-MS). By comparing the content of trace elements in oil shale and shale char, distribution characteristics of trace elements at retorting were studied. The overall trends of volatile ratio of trace elements are ascending with higher microwave power and higher than the conventional pyrolysis. The differences in the volatile ratio indicate that the trace elements investigated are bound with the oil shale kerogen and its mineral matter in different manner. So Float-sink experiments (FSE) were performed on oil shale. Huadian oil shale has more included mineral. The volatilization of organic matter is not the main reason for the volatilization of trace elements in oil shale. The trace elements combined with the mineral elements may be also certain volatility.

Efeito da aplicação de cianamida hidrogenada e óleo mineral na quebra de dormência e producão do pessegueiro-'Flamecrest' Effect of the application of hidrogen cyanamid and mineral oil on dormancy breaking and peach production, cv. Flamecrest

Directory of Open Access Journals (Sweden)

GILMAR ARDUINO BETTIO MARODIN

2002-08-01

Full Text Available Com o objetivo de aumentar a produção e qualidade de frutos do pessegueiro- 'Flamecrest', de alta exigência em frio, realizou-se um experimento no Município de Farroupilha-RS, no ano de 2000, com o uso de cianamida hidrogenada e óleo mineral. Estudou-se o efeito de duas diferentes épocas de aplicação dos tratamentos (15-7 e 2-8 sobre a brotação, floração, frutificação, produção e antecipação de colheita. Foram testados os efeitos dos seguintes tratamentos: cianamida hidrogenada (C.H. 1,22; 2,45; 3,675 e 4,90 g de i.a.L-1 com óleo mineral (O.M. 10 g de i.a.L-1; O.M. 10 g de i.a.L-1 isolado e testemunha (sem pulverização. Os tratamentos não anteciparam a brotação das gemas floríferas, porém C.H. 2,45 e 4,90 g de i.a.L-1 com O.M. a 10 g de i.a.L-1 proporcionaram plantas com maior brotação das gemas vegetativas. Não houve efeito marcante dos tratamentos sobre a floração e a porcentagem de frutos vingados nas duas épocas. O número de frutos raleados por planta foi superior para os tratamentos com C.H. 2,45 e 4,90 g de i.a.L-1 com O.M. 10 g de i.a.L-1 quando aplicados na segunda época. Já, para o número e massa total dos frutos colhidos, destacaram-se, na primeira época (15-7, os tratamentos com C.H. 1,22 e 3,675 g de i.a.L-1 + O.M. 10 g de i.a.L-1 e, na segunda época (2-8, os tratamentos com C.H. 2,45 e 4,90 g de i.a.L-1 + O.M. 10 g de i.a.L-1. Os tratamentos da segunda época resultaram em produções médias superiores à primeira. A massa média dos frutos não foi alterada de forma clara pelos tratamentos, assim como o teor de sólidos solúveis totais e a resistência de polpa.With the objective of increasing yields and fruit quality of cv. Flamecrest peaches, a cultivar with high chilling units demand, the present experiment was conducted in an orchard near to the Farroupilha city, in the year 2000. The hidrogen cyanamid and mineral oil were applied in two different times: middle of July and begining of

Complex of spectral techniques for remote monitoring of oil spills on water surface

International Nuclear Information System (INIS)

Patsayeva, S.; Yuzhakov, V.; Barbini, R.; Fantini, R.; Frassanito, C.; Palucci, A.; Varlamov, V.

1999-01-01

Spectral properties of oil films on water surfaces were studied under laboratory conditions. A laser fluorosensor was used to measure fluorescence response; fluorescence decay measurements were also performed. Differences in decay time were noted for different mineral oils (ranging from 1 ns to 3.5 ns) and for refined oils (which ranged from 3.5 ns to 8 ns). Film thickness was estimated by calculating the wavelength -dependent absorption of the mineral oil. This new approach is independent of many accidental factors, and does not demand the a priori measured signal from clean water which is required by the more conventional method of suppression of the water Raman integral signal. These experiments confirmed the suitability of fluorescent spectroscopy as a very sensitive tool for oil detection and mapping, however, when applied to quantitative measurement or oil recognition in remote sensing, care must be taken to account for the factors influencing fluorescence response of mineral oil. It was also shown that fluorescence decay time is a useful technique to characterize the type of mineral oil spilled on water surface in that it provides a means to distinguish between the various types, using time-resolved spectra. 12 refs., 1 tab., 4 figs

Polymer as permeability modifier in porous media for enhanced oil recovery

Science.gov (United States)

Parsa, Shima; Weitz, David

2017-11-01

We use confocal microscopy to directly visualize the changes in morphology and mobilization of trapped oil ganglia within a 3D micromodel of porous media upon polymer flooding. Enhanced oil recovery is achieved in polymer flooding with large molecular weight at concentrations close or higher than a critical concentration of polymer. We also measure the fluctuations of the velocity of the displacing fluid and show that the velocities change upon polymer flooding in the whole medium. The changes in the fluid velocities are heterogeneous and vary in different pores, hence only providing enough pressure gradient across a few of the trapped oil ganglia and mobilize them. Our measurements show that polymer flooding is an effective method for enhancing oil recovery due to retention of polymer on the solid surfaces and changing the resistances of the available paths to water.

Tribological Characteristics Evaluation of Mustard Oil Blends

OpenAIRE

Mohammed Hassan Jabal; Muhannad Zaidan Khalefa

2018-01-01

A progressive increase in the desire for environmentally friendly lubricants by users and strict government regulations for the use of these lubricants has provided an opportunity to use plant oils as biodegradable lubricants, therefore vegetable oils have been investigated to replace oil lubricants because of their maintaining the conditions of nature (environment) properties. In this paper, the influences of the blending ratio of mustard seeds oil with commercial mineral oil (SAE40) on the ...

Effect of iron cation on geochemical trapping of CO2 in brine

Science.gov (United States)

Liu, Qi; Maroto-Valer, Mercedes

2014-05-01

Carbon dioxide sequestration using brines has emerged as a promising technology to mitigate the adverse impacts of climate change due to its large storage capacity and favorable chemistries. However, the permanent storage (mineral trapping) of CO2 in brines takes significantly long periods of time as the formation and precipitation of carbonates is very slow .[1]. The main parameters reported to effect on mineral trapping of CO2 sequestration in brines are brine composition, brine pH, system temperature and pressure.[2, 3]. It is suggested that the precipitation of mineral carbonates is mostly dependent on brine pH. Previous studies by the authors concluded that iron in natural brines causes pH instability, but it was not ascertained whether ferric iron or ferrous iron caused pH instability .[4]. Accordingly, the aim of this project is to study synthetic brines mimicking the major ions found in natural brines and including different concentrations of ferric and ferrous iron. Three brines were prepared, as follows: Brine 1 was prepared with ferric Fe3+ iron, Brine 2 prepared with ferrous Fe2+ iron and Brine 3 prepared with no iron. A series of pH stability studies and carbonation reactions were conducted using the above three brines. It is concluded that the ferrous iron causes pH instability, while ferric iron might promote carbonate precipitation. .1. Garcia, S., et al., Sequestration of non-pure carbon dioxide streams in iron oxyhydroxide-containing saline repositories. International Journal of Greenhouse Gas Control, 2012. 7: p. 89-97. 2. Liu, Q. and M.M. Maroto-Valer, Investigation of the pH effect of a typical host rock and buffer solution on CO 2 sequestration in synthetic brines. Fuel Processing Technology, 2010. 91(10): p. 1321-1329. 3. Liu, Q. and M.M. MarotoValer, Parameters affecting mineral trapping of CO2 sequestration in brines. Greenhouse Gases: Science and Technology, 2011. 1(3): p. 211-222. 4. Druckenmiller, M.L. and M.M. Maroto-Valer, Carbon

Test for Local Insect Traps against some Solanacea Insects Plant under Green House Conditions in Riyadh, Saudi Arabia

International Nuclear Information System (INIS)

Al-Ayedh, Hassan Ibn Yahiya

2005-01-01

Trapping efficiency of seven different colored sticky traps (Green, Fluorescent yellow, Orange, Pink, red, White and Yellow) was evaluated in some solanacea plants, tomatoes (Lycopersicon esculentum), eggplant (Solanum Magellan) and sweet pepper (Capsicum spp.) crops, for whitefly (Bemis ia airlifting), leaf miners (Liriomyza trifolii), thrips (Thrips tabaci) in Riyadh, Saudi Arabia. The traps were placed at four different heights (0.5, 1.0, 1.5 and 2.0 m above the ground). The experiment was laid out in a Completely Randomized Block Design (CRBD) with four replications during autumn 2001, spring and autumn 2002. Significantly high insect populations were trapped on Fluorescent yellow, yellow and green colored sticky traps. No significant differences were witnessed between mean numbers of various insects caught on sticky traps placed at different heights but more insects were trapped at 0.5 - 1.5m. (author)

Application of porous materials in oil substances separation from water

Science.gov (United States)

Gołub, Adam; Piekutin, Janina

2017-11-01

The aim of the study was to determine the ability of the four porous materials: birch bark, cork, glass wool, and polyurethane foam to reduce the mineral oil index and the concentration of n-alkanes C7H16-C38H78 as well as to select the most efficient materials. Model solutions of gasoline, diesel oil, and distilled water with the following values of mineral oil index were prepared to tests: 52 μg/dm3, 68 μg/dm3 and 73 μg/dm3. Then, studies were carried out using a dynamic method, wherein the columns were filled with adsorbents tested, and in each of three testing series, 500 mL of the model solution at constant bed load of 1,0551 m3/m2h was filtered through the column. After filtration, the collected sample had volume of 250 mL. The collected samples were subject to determination of mineral oil index and concentrations of n-alkanes from C7H16 to C38H78. Studies have shown that the most effective materials to lower the mineral oil index and the concentrations of n-alkanes in water are birch bark and glass wool.

Aerobic microbial enhanced oil recovery

Energy Technology Data Exchange (ETDEWEB)

Torsvik, T. [Univ. of Bergen (Norway); Gilje, E.; Sunde, E.

1995-12-31

In aerobic MEOR, the ability of oil-degrading bacteria to mobilize oil is used to increase oil recovery. In this process, oxygen and mineral nutrients are injected into the oil reservoir in order to stimulate growth of aerobic oil-degrading bacteria in the reservoir. Experiments carried out in a model sandstone with stock tank oil and bacteria isolated from offshore wells showed that residual oil saturation was lowered from 27% to 3%. The process was time dependent, not pore volume dependent. During MEOR flooding, the relative permeability of water was lowered. Oxygen and active bacteria were needed for the process to take place. Maximum efficiency was reached at low oxygen concentrations, approximately 1 mg O{sub 2}/liter.

A Network Model for the Kinetics of Bioclogged Flow Diversion for Enhanced Oil Recovery

NARCIS (Netherlands)

Lopez Pena, L.A.; Meulenbroek, B.J.; Vermolen, F.J.

2016-01-01

After the primary extraction in oil reservoirs up to 60 % of the oil remains trapped in the reservoir (Sen, 2008). Therefore, different mechanisms have been developed to get the oil out to the reservoir. One of these techniques is Microbial Enhanced Oil Recovery (MEOR) which is a technique used

Biological impacts of oil pollution: saltmarshes. V. 6

International Nuclear Information System (INIS)

1997-01-01

Saltmarshes are priority areas for protection following oil spills, because they can trap and retain large quantities of oil and are difficult to clean. They are included in the 'most vulnerable' category of habitats, as defined by international shoreline vulnerability indices. However, whilst some oiled marshes may take decades to recover, others have shown excellent recovery within one to two years. This report considers factors affecting the fate and effects of oil on saltmarshes, and provides guidelines on clean-up options. The report includes information on the ecology and uses of saltmarshes. (UK)

The initial rise method extended to multiple trapping levels in thermoluminescent materials.

Science.gov (United States)

Furetta, C; Guzmán, S; Ruiz, B; Cruz-Zaragoza, E

2011-02-01

The well known Initial Rise Method (IR) is commonly used to determine the activation energy when only one glow peak is presented and analysed in the phosphor materials. However, when the glow peak is more complex, a wide peak and some holders appear in the structure. The application of the Initial Rise Method is not valid because multiple trapping levels are considered and then the thermoluminescent analysis becomes difficult to perform. This paper shows the case of a complex glow curve structure as an example and shows that the calculation is also possible using the IR method. The aim of the paper is to extend the well known Initial Rise Method (IR) to the case of multiple trapping levels. The IR method is applied to minerals extracted from Nopal cactus and Oregano spices because the thermoluminescent glow curve's shape suggests a trap distribution instead of a single trapping level. Copyright © 2010 Elsevier Ltd. All rights reserved.

Bioremediation potential of coal-tar-oil-contaminated soil

International Nuclear Information System (INIS)

Lajoie, C.A.

1991-01-01

The bioremediation of coal tar oil contaminated soil was investigated in 90 day laboratory simulation experiments. The effect of soil moisture, humic acid amendment, and coal tar oil concentration on the rate of disappearance of individual coal tar oil constituents (PAHs and related compounds) was determined by methylene chloride extraction and gas chromatography. Mass balance experiments determined the fate of both the individual 14 C-labeled PAHs phenanthrene, pyrene, and benzo(a)pyrene, and the total coal tar oil carbon. Mineralization, volatilization, incorporation into microbial biomass, disappearance of individual coal tar oil constitutents, and the distribution of residual 14 C-activity in different soil fractions were measured. The rate of disappearance of coal tar oil constituents increased with increasing soil moisture over the experimental range. Humic acid amendment initially enhanced the rate of disappearance, but decreased the extent of disappearance. The amount of contamination removed decreased at higher coal tar oil concentrations. The practical limit for biodegradation in the system tested appeared to be between 1.0 and 2.5% coal tar oil. Mineralization accounted for 40 to 50% of the applied coal tar oil. Volatilization was a minor pathway of disappearance

Mineral facilities of Europe

Science.gov (United States)

Almanzar, Francisco; Baker, Michael S.; Elias, Nurudeen; Guzman, Eric

2010-01-01

This map displays over 1,700 records of mineral facilities within the countries of Europe and western Eurasia. Each record represents one commodity and one facility type at a single geographic location. Facility types include mines, oil and gas fields, and plants, such as refineries, smelters, and mills. Common commodities of interest include aluminum, cement, coal, copper, gold, iron and steel, lead, nickel, petroleum, salt, silver, and zinc. Records include attributes, such as commodity, country, location, company name, facility type and capacity (if applicable), and latitude and longitude geographical coordinates (in both degrees-minutes-seconds and decimal degrees). The data shown on this map and in table 1 were compiled from multiple sources, including (1) the most recently available data from the U.S. Geological Survey (USGS) Minerals Yearbook (Europe and Central Eurasia volume), (2) mineral statistics and information from the USGS Minerals Information Web site (http://minerals.usgs.gov/minerals/pubs/country/europe.html), and (3) data collected by the USGS minerals information country specialists from sources, such as statistical publications of individual countries, annual reports and press releases of operating companies, and trade journals. Data reflect the most recently published table of industry structure for each country at the time of this publication. Additional information is available from the country specialists listed in table 2.

Essential abilities of the oil-finding geologist

International Nuclear Information System (INIS)

Sebring, L. Jr.

1992-01-01

This paper reports that the oil-finder must be able to locate and recognize a significant anomaly, and he must be able to get this anomaly tested. A significant anomaly is defined as a trapping anomaly, one that might trap hydrocarbons. So, the oil-finder has a dual job. He must be both a scientist and a salesman, a prospector and a promoter, a researcher and a hustler. He must locate the prospect, and, unless he is financially self-sufficient, he must persuade his management or his investors to test the prospect. One ability is not enough. To be a successful oil-finder he must have both abilities, although not necessarily in equal degree. The truth is self-evident-all geologist are not equal in ability; either as trap locators or as prospect salesmen. Some have considerable ability to locators or a s prospect salesmen. Some have considerable ability to locate anomalies, but have great difficulty in persuading their management or investors to test their prospects. Other have difficulty in recognizing a prospect, but once one is located can easily persuade their management or clients to test it. And some, a truly blessed minority, can not only easily locate the recognize a significant anomaly but can, just as easily, persuade their management or investors to pursue the investigation of this anomaly to its logical conclusion

Impact of applying edible oils to silk channels on ear pests of sweet corn.

Science.gov (United States)

Ni, Xinzhi; Sparks, Alton N; Riley, David G; Li, Xianchun

2011-06-01

The impact of applying edible oils to corn silks on ear-feeding insects in sweet corn, Zea mays L., production was evaluated in 2006 and 2007. Six edible oils used in this experiment were canola, corn, olive, peanut, sesame, and soybean. Water and two commercial insecticidal oils (Neemix neem oil and nC21 Sunspray Ultrafine, a horticultural mineral oil) were used as the controls for the experiment. Six parameters evaluated in this experiment were corn earworm [Helicoverpa zea (Boddie) (Lepidoptera: Noctuidae)] damage rating, the number of sap beetle [Carpophilus spp. (Coleoptera: Nitidulidae)] adults and larvae, the number of corn silk fly (or picture-winged fly) (Diptera: Ulidiidae) larvae, common smut [Ustilago maydis (D.C.) Corda] infection rate, and corn husk coverage. Among the two control treatments, neem oil reduced corn earworm damage at both pre- and postpollination applications in 2006, but not in 2007, whereas the mineral oil applied at postpollination treatments reduced corn earworm damage in both years. The mineral oil also reduced the number of sap beetle adults, whereas the neem oil applied at postpollination attracted the most sap beetle adults in 2007. Among the six edible oil treatments, the corn and sesame oils applied at postpollination reduced corn earworm damage only in 2007. The application of the peanut oil at postpollination attracted more sap beetle adults in 2006, and more sap beetle larvae in 2007. Olive and neem oils significantly reduced husk coverage compared with the water control in both years. The mineral oil application consistently increased smut infection rate in both 2006 and 2007. Ramifications of using oil treatments in ear pest management also are discussed.

Foam flow in a model porous medium: II. The effect of trapped gas.

Science.gov (United States)

Jones, S A; Getrouw, N; Vincent-Bonnieu, S

2018-05-09

Gas trapping is an important mechanism in both Water or Surfactant Alternating Gas (WAG/SAG) and foam injection processes in porous media. Foams for enhanced oil recovery (EOR) can increase sweep efficiency as they decrease the gas relative permeability, and this is mainly due to gas trapping. However, gas trapping mechanisms are poorly understood. Some studies have been performed during corefloods, but little work has been carried out to describe the bubble trapping behaviour at the pore scale. We have carried out foam flow tests in a micromodel etched with an irregular hexagonal pattern. Image analysis of the foam flow allowed the bubble centres to be tracked and local velocities to be obtained. It was found that the flow in the micromodel is dominated by intermittency and localized zones of trapped gas. The quantity of trapped gas was measured both by considering the fraction of bubbles that were trapped (via velocity thresholding) and by measuring the area fraction containing immobile gas (via image analysis). A decrease in the quantity of trapped gas was observed for both increasing total velocity and increasing foam quality. Calculations of the gas relative permeability were made with the Brooks Corey equation, using the measured trapped gas saturations. The results showed a decrease in gas relative permeabilities, and gas mobility, for increasing fractions of trapped gas. It is suggested that the shear thinning behaviour of foam could be coupled to the saturation of trapped gas.

Performance Evaluation Of Africa Elemi Melon And Africa Locust Bean Oil As Potential Quenchants For Medium Carbon Steel

Directory of Open Access Journals (Sweden)

C. S. Ibeh

2017-06-01

Full Text Available A qualitative and comparative study was carried out on some locally sourced oils melon oil Africa elemi oil and Africa locust bean oil to evaluate suitability as substitute quenching media to mineral-based oil. The cooling ability of the oils was investigated using AISI 1034 medium carbon steel. The effect of heat transfer coefficient on quench severity mechanical properties of the quenched specimens were investigated in the course of the study. Results showed that the peak rate of heat extraction of melon oil Africa locust bean and Africa elemi oil were higher than that of mineral oil. Higher heat transfer coefficient of 1463 1023 Wm2k were obtained for melon oil and Africa locust bean Africa elemi and SAE 40 oil have heat transfer coefficient of 982 and 469 Wm2k respectively. The selected oils can be used as quenchants for medium carbon steel since the oils exhibits better cooling properties and mechanical properties than mineral-based oil.

Mineral Licks as Diversity Hotspots in Lowland Forest of Eastern Ecuador

Directory of Open Access Journals (Sweden)

David Romo

2011-04-01

Full Text Available Mineral licks are sites where a diverse array of mammals and birds consume soil (geophagy or drink water, likely for mineral supplementation. The diversity of species that visit such sites makes them important for conservation, particularly given that hunters often target animals at licks. Use of mineral licks varies among species, with frugivores among the most common visitors but there is considerable temporal and spatial variation in lick use both within and among species. Camera traps triggered by heat and motion were used to document use of mineral licks by birds and non-volant mammals over a four-year period at a lowland forest site in eastern Ecuador. We obtained 7,889 photographs representing 23 mammal species and 888 photographs representing 15 bird species. Activity (photographs/100 trap-days at the four licks varied from 89 to 292 for mammals and from six to 43 for birds. Tapirs (Tapirus terrestris, peccaries (Pecari tajacu, Tayassu pecari, deer (Mazama americana, and pacas (Cuniculus paca were the most frequent mammal visitors; guans (Pipile pipile and pigeons (Columba plumbea were the most common birds. Use of licks varied diurnally and seasonally but patterns of use varied among species and sites. Mineral licks provide an important resource for many species but further studies are needed to determine the precise benefit(s obtained and how benefits may vary with diet and other factors, such as rainfall.

Oil and gas leasing/production program

International Nuclear Information System (INIS)

Heimberger, M.L.

1992-01-01

As the Congress declared in the Outer Continental Shelf Lands Act the natural gas and oil production from the Outer Continental Shelf constitutes an important part of the Nation's domestic energy supply. Federal offshore minerals are administered within the Department of the Interior by the Minerals Management Service (MMS), which provides access to potential new sources of natural gas and oil offshore by conducting lease sales. Each year, on or before March 31, the MMS presents to Congress a fiscal year annual report on the Federal offshore natural gas and oil leasing and production program. In FY 1991, this program was the third largest producer of non-tax revenue for the US Treasury, contributing more than $3 billion. This report presents Federal offshore leasing, sales, production, and exploration activities, and environmental monitoring activities

[Study of Determination of Oil Mixture Components Content Based on Quasi-Monte Carlo Method].

Science.gov (United States)

Wang, Yu-tian; Xu, Jing; Liu, Xiao-fei; Chen, Meng-han; Wang, Shi-tao

2015-05-01

Gasoline, kerosene, diesel is processed by crude oil with different distillation range. The boiling range of gasoline is 35 ~205 °C. The boiling range of kerosene is 140~250 °C. And the boiling range of diesel is 180~370 °C. At the same time, the carbon chain length of differentmineral oil is different. The carbon chain-length of gasoline is within the scope of C7 to C11. The carbon chain length of kerosene is within the scope of C12 to C15. And the carbon chain length of diesel is within the scope of C15 to C18. The recognition and quantitative measurement of three kinds of mineral oil is based on different fluorescence spectrum formed in their different carbon number distribution characteristics. Mineral oil pollution occurs frequently, so monitoring mineral oil content in the ocean is very important. A new method of components content determination of spectra overlapping mineral oil mixture is proposed, with calculation of characteristic peak power integrationof three-dimensional fluorescence spectrum by using Quasi-Monte Carlo Method, combined with optimal algorithm solving optimum number of characteristic peak and range of integral region, solving nonlinear equations by using BFGS(a rank to two update method named after its inventor surname first letter, Boyden, Fletcher, Goldfarb and Shanno) method. Peak power accumulation of determined points in selected area is sensitive to small changes of fluorescence spectral line, so the measurement of small changes of component content is sensitive. At the same time, compared with the single point measurement, measurement sensitivity is improved by the decrease influence of random error due to the selection of points. Three-dimensional fluorescence spectra and fluorescence contour spectra of single mineral oil and the mixture are measured by taking kerosene, diesel and gasoline as research objects, with a single mineral oil regarded whole, not considered each mineral oil components. Six characteristic peaks are

Analysis of mineral trapping for CO(sub 2) disposal in deep aquifers; TOPICAL

International Nuclear Information System (INIS)

Xu, Tianfu; Apps, John A.; Pruess, Karsten

2001-01-01

CO(sub 2) disposal into deep aquifers has been suggested as a potential means whereby atmospheric emissions of greenhouse gases may be reduced. However, our knowledge of the geohydrology, geochemistry, geophysics, and geomechanics of CO(sub 2) disposal must be refined if this technology is to be implemented safely, efficiently, and predictably. As a prelude to a fully coupled treatment of physical and chemical effects of CO(sub 2) injection, we have analyzed the impact of CO(sub 2) immobilization through carbonate precipitation. A survey of all major classes of rock-forming minerals, whose alteration would lead to carbonate precipitation, indicated that very few minerals are present in sufficient quantities in aquifer host rocks to permit significant sequestration of CO(sub 2). We performed batch reaction modeling of the geochemical evolution of three different aquifer mineralogies in the presence of CO(sub 2) at high pressure. Our modeling considered (1) redox processes that could be important in deep subsurface environments, (2) the presence of organic matter, (3) the kinetics of chemical interactions between the host rock minerals and the aqueous phase, and (4) CO(sub 2) solubility dependence on pressure, temperature and salinity of the system. The geochemical evolution under both natural background and CO(sub 2) injection conditions was evaluated. In addition, changes in porosity were monitored during the simulations. Results indicate that CO(sub 2) sequestration by matrix minerals varies considerably with rock type. Under favorable conditions the amount of CO(sub 2) that may be sequestered by precipitation of secondary carbonates is comparable with and can be larger than the effect of CO(sub 2) dissolution in pore waters. The precipitation of ankerite and siderite is sensitive to the rate of reduction of ferric mineral precursors such as glauconite, which in turn is dependent on the reactivity of associated organic material. The accumulation of carbonates in

The Galeta oil spill: Pt. 2

International Nuclear Information System (INIS)

Burns, K.A.; Jorissen, D.; MacPherson, J.; Stoelting, M.; Tierney, J.; Yelle-Simmons, L.; Garrity, S.D.

1994-01-01

Sediment chemistry studies, undertaken as part of the long-term assessment of the Bahia las Minas (Panama) oil spill, showed the unexpected persistence of the full range of aromatic hydrocarbon residues of the spilled crude oil in anoxic muds of coastal mangroves. Mangrove muds served as long-term reservoirs for chronic contamination of contiguous coastal communities for over 5 years. One result of the repeated history of oil pollution incidents along this coast was an increased proportion of dead mangrove (Rhizophora mangle) roots in sediment cores which was related to contaminant loading and was detectable for at least 20 years after major oil spills. We suggest that this is the minimum time-scale that is to be expected for the loss of toxicity of oil trapped in muddy coastal habitats impacted by catastrophic oil spills. (author)

Oils

Energy Technology Data Exchange (ETDEWEB)

Fabbri, S

1909-11-29

Mineral, shale, and like oils are treated successively with sulfuric acid, milk of lime, and a mixture of calcium oxide, sodium chloride, and water, and finally a solution of naphthalene in toluene is added. The product is suitable for lighting, and for use as a motor fuel; for the latter purpose, it is mixed with a light spirit.

NORSE2015 - A Focused Experiment On Oil Emulsion Characterization Using PolSAR During the 2015 Norwegian Oil-On-Water Exercise

Science.gov (United States)

Holt, B.; Jones, C. E.; Brekke, C.; Breivik, O.; Skrunes, S.; Espeseth, M.

2016-02-01

A targeted experiment in characterizing the properties and development of mineral oil slicks was undertaken by NASA, UiT - The Arctic University of Norway, and the Norwegian Meteorological Institute during the 2015 Norwegian oil-on-water spill exercise in the North Sea (OPV2015). NORSE2015 (Norwegian Radar oil Spill Experiment) involved controlled release of plant oil and mineral emulsions of three different oil-to-water ratios, imaging of the slicks with satellite-borne synthetic aperture radars (SAR), and tracking their development with the NASA-UAVSAR instrument over a period of eight hours following release. During the experiment, in situ measurements were made from ship or aircraft with meteorological instruments, released drift buoys, and optical/IR imagers. The experiment was designed to provide validation data for development of a physical model relating polarization-dependent electromagnetic scattering to the dielectric properties of oil mixed with ocean water in a thick slick or emulsion. UAVSAR is a particularly low noise instrument, which enables detection of oil characteristics, and serves as the basis for a relative comparison of different radar frequencies and instruments in oil slick detection and characterization. The time series of UAVSAR polarimetric SAR (PolSAR) is used to track the spreading, movement, and change in backscatter of the different emulsion slicks and the plant oil, to look at movement relative to wind and wave directions, and to develop methods to differentiate between biogenic and mineral slicks based upon temporal changes in the slicks, including environment-driven changes. In this presentation, the experiment will be described and preliminary results presented. This work was carried out in part at the Jet Propulsion Laboratory, California Institute of Technology, under a contract with NASA. The Norwegian experiment was partly financed by CIRFA - Centre for integrated remote sensing and forecasting for arctic operations.

Laser tweezers: spectroscopy of optically trapped micron-sized particles

Energy Technology Data Exchange (ETDEWEB)

Kerr, K M; Livett, M K; Nugent, K W [Melbourne Univ., Parkville, VIC (Australia). School of Physics

1997-12-31

Information is often obtained about biological systems by analysis of single cells in the system. The optimum conditions for this analysis are when the cells are living and in their natural surroundings as they will be performing their normal functions and interactions. Analysis of cells can be difficult due to their mobility. Laser tweezing is a non contact method that can be employed to overcome this problem and provides a powerful tool in the analysis of functions and interactions at single cell level. In this investigation Raman spectra of a molecule of {beta} - carotene, dissolved in microdroplets of oil was obtained. The droplets were trapped using Nd-YAG beam and a low intensity Ar{sup +} beam was used to analyse the trapped particles. 2 refs., 5 figs.

Laser tweezers: spectroscopy of optically trapped micron-sized particles

Energy Technology Data Exchange (ETDEWEB)

Kerr, K.M.; Livett, M.K.; Nugent, K.W. [Melbourne Univ., Parkville, VIC (Australia). School of Physics

1996-12-31

Information is often obtained about biological systems by analysis of single cells in the system. The optimum conditions for this analysis are when the cells are living and in their natural surroundings as they will be performing their normal functions and interactions. Analysis of cells can be difficult due to their mobility. Laser tweezing is a non contact method that can be employed to overcome this problem and provides a powerful tool in the analysis of functions and interactions at single cell level. In this investigation Raman spectra of a molecule of {beta} - carotene, dissolved in microdroplets of oil was obtained. The droplets were trapped using Nd-YAG beam and a low intensity Ar{sup +} beam was used to analyse the trapped particles. 2 refs., 5 figs.

Control of San Jose Scale Nymphs, Diaspidiotus perniciosus (Comstock, on Almond and Apple Orchards with Pyriproxyfen, Phenoxycarb, Chlorpyrifos, and Mineral Oil Control de Ninfas de la Escama de San José, Diaspidiotus perniciosus (Comstock, en Almendros y Manzanos con Piriproxifen, Fenoxicarb, Clorpirifos y Aceite Mineral

Directory of Open Access Journals (Sweden)

Luis Sazo

2008-09-01

Full Text Available The effect of pyriproxyfen, phenoxycarb, chlorpyrifos, and mineral oil in the control of first generation nymphs of the San Jose scale (SJC, Diaspidiotus perniciosus (Comstock, in almond, Prunusdulcis (Mill. D.A. Webb, and apple, Malusdomestica Borkh. orchards was studied in the 2001-2002 season in central Chile. One and two sprays of pyriproxyfen 0.07% and phenoxycarb 0.05% were applied, the first at the beginning of the appearance of nymphs in early spring (biofix, and the other 15 days later, and were compared with one spray of chlorpyrifos 0.08% applied at the biofix. Also, one and two sprays of mineral oil 1% were evaluated, the first applied 7 days after the biofix, and the second 15 days after the first spray. Evaluations were done in the laboratory at the end of the dispersion of first generation nymphs, on December 27 and 28 for almonds and apples, respectively, counting the number of nymphs fixed per lineal meter of new twigs collected at infested sectors, percentage of infested apples, and the number of scales fixed per fruit. Results were subjected to ANOVA and Duncan multiple range tests. At low level infestation, one application of pyriproxyfen 0.07%, phenoxycarb 0.05%, or mineral oil 1% in spring reduced significantly (P≤0.05 the number of nymphs fixed per twig, at a level similar to that of a traditional treatment of chlorpyrifos 0.08%. However, at greater infestations, one spray of pyriproxyfen or mineral oil in spring was insufficient to control ESJ.En la temporada 2001-2002 se estudió el efecto de piriproxifen, fenoxicarb, clorpyrifos y aceite mineral en el control de las ninfas de la primera generación de la Escama de San José (ESJ, Diaspidiotus perniciosus (Comstock, en almendros, Prunusdulcis (Mill. D.A. Webb, y manzanos, Malusdomestica Borkh., en Chile central. Se hicieron una y dos aplicaciones de piriproxifen 0,07% y fenoxicarb 0,05%, la primera en el inicio del nacimiento de ninfas de primavera (biofix y la segunda

The paleogeologic-geographical conditions of non-anti clinical traps formation in Azerbaijan

International Nuclear Information System (INIS)

Suleymanov, A.M.

2002-01-01

Full text : The plegicil-geographical researches had established the predominant development of definite non-anticlinal traps in some stages and oil deposits related with them. At the final stage of the Alpine tectonic cycle more favorable conditions rise for formation of paleogemorphological and structural-stractigraphical types of non-anticlinal traps due to relation with increase of the tectonic movements contrast and existence of numerous regional and local bakers in sedimentation. The complex history of the geotechnical development of the mentioned large tectonic units made the favorable conditions for formation of non-anticlinal traps of different in various stratigraphical complexes. Marine tangerines begun in the Early Cretaceous had led to accumulation of carbonaceous mainly, then sandy-clayey formations. The Middle Cretaceous is characterized with instability of the geotectonic regime

Fumigant Toxicity of the Essential Oil of Caraway, Carum carvi on the Tomato Leaf Miner, Tuta absoluta (Meyrick (Lepidoptera: Gelechiidae

Directory of Open Access Journals (Sweden)

S. Goudarzvande Chegini

2017-08-01

Full Text Available Introduction: The tomato leafminer (TLM, Tuta absoluta (Meyrick (Lepidoptera: Gelechiidae, is an important pest on tomato, potato and other Solanaceous with a great economic importance. Tomato borer can be regarded as a serious threat to tomato production in Iran. TLM larvae cause losses of up to 100% by attacking tomato leaves, flowers, stems, and especially fruits. TLM larvae act as leaf miners, and in high numbers, they can totally destroy the plant foliage; TLM infestation can destroy crop production early on by infesting both developing and ripe fruits. Management of the pest can be problematic, particularly when the infestation pressure is high. One of the main tools in its management is the use of conventional synthetic insecticides, however, this overreliance on the use of synthetic insecticides quickly leads to problems of insecticide resistance. The use of natural compounds such as plant essential oils is considered as alternatives to chemical pesticides due to their lower toxicity on the non-target and low persistence in the environment. In recent years essential oils of medicinal plants have received much attention as pest control chemical agents. The discovery of active compounds that are less persistent will be beneficial for both the environment and agricultural product consumers. Materials and Methods: The egg, 2nd larval instars, and adult of TLM were used to determine the fumigant toxicity of the C. cavi. The essential oil of aerial parts of C. cavi, was extracted by hydrodistillation using a modified Clevenger-type apparatus. Conditions of extraction were: 50g of air-dried sample, 1:12 plant material/water volume ratio and 4h distillation. The obtained oil was dried over anhydrous sodium sulfate and stored in the refrigerator at + 4°C until used. The fumigant toxicity of essential oil on larvae 2nd (inside leaf and egg were tested in macro plastic container volume 1800 ml, The vials were contained leaves containing larvae

Distilling hydrocarbon oils

Energy Technology Data Exchange (ETDEWEB)

Schulze, J E

1923-03-19

In distilling mineral oils such as petroleum, shale oil, distillates and topped or residual oils, particularly to obtain lubricating oils, the distillation is carried out under reduced pressures below an absolute pressure of 25 mm. of mercury and preferably below about 5 mm. of mercury, and the distillate is collected in fractions determined by the physical characteristics, such as viscosity, flash point, fire point, etc. Superheated steam may be passed through the liquid during distillation. A horizontal cylindrical still provided with cross braces and peripheral ribs interrupted at the base is connected through a condensing coil immersed in a steam chest and a baffled chamber with distillate receiver and is evacuated by a pump. Steam from a boiler and superheater is injected into the still through a perforated pipe. Steam and light oil vapors passing from the chamber are condensed in a coil.

Rate of biodegradation of crude oil by microorganisms isolated from ...

African Journals Online (AJOL)

The rate of biodegradation of crude oil by micro-organisms isolated from crude oil sludge environment in Eket, Akwa Ibom State of Nigeria was studied. Mineral salt medium supplemented with crude oil was used and three most abundant species isolated from a crude oil sludged soil - Micrococcus varians, Bacillus subtilis ...

Thermal properties of mixtures of mineral oil and natural ester in terms of their application in the transformer

Directory of Open Access Journals (Sweden)

Nadolny Zbigniew

2017-01-01

Full Text Available The article describes research results of thermal properties of mineral oil and natural ester. Percentage proportions of both the liquids were as follows: 100/0, 95/5, 80/20, 50/50, 20/80, 0/100. The authors present measurement results of thermal conductivity, viscosity, specific heat, density, and thermal expansion of the created mixtures. The measurements were taken in a relatively wide temperature range: 25 °C, 40 °C, 60 °C, and 80 °C. On the basis of the measurement results, convection heat transfer coefficient α was calculated and the most advantageous proportion of both the components of the mixture was pointed in terms of cooling effectiveness of the transformer.

Polyalhpaolefins and VHVI base oils - base oils for high performance lubricants; Polyalfaolefine und VHVI-Grundoele - Grundoele fuer hochwertige Schmierstoffe

Energy Technology Data Exchange (ETDEWEB)

Lehmus, M.; Nissfolk, F.; Kulmala, K. [Fortum Oil and Gas Oyj / Base Oils, Fortum (Finland)

2002-01-01

Next to polyalphaolefines (PAOs base oils of the API/ATIEL Group IV), VHVI base oils (belonging to API/ATIEL Group III) are being increasingly used in high-performance automotive and industrial lubricants. A comparative study of the properties of VHVI base oils and polyalphaolefins shows that high-quality VHVI base oils have comparable volatility, oxidation stability and viscosity indices to polyalphaolefins, whereas the most pronounced differences are viscometric properties in the low-temperature range. However, there are noticeable differences between different market-typical VHVI base oils, depending primarily on the manufacturing process. The differences in the physicochemical properties of PAOs and various VHVI base oils are attributable to differences in the typical molecular composition. This is illustrated by a compositional analysis of several VHVI base oils, in which the (iso)paraffin content and the content of different naphthenic and aromatic compounds is analyzed. The base oil influence on specific properties of formulated lubricants is discussed on the basis of several examples, and studies conducted with passenger car engine oils (PCMOs), heavy-duty engine oils (HDEOs) and gear oils are described in detail. As a result of extremely low CCS viscosities, PAOs are optimally suited for use in 0W-X PCMOs whereas 5W-X PCMOs meeting highest performance requirements can also be formulated with high-quality VHVI base oils. Emission measurements with HDEOs formulated with either SN mineral base oil or VHVI base oil demonstrated that the base oil type affects tailpipe particle emissions in the particle size range <5 {mu}m as replacement of SN mineral base oil with VHVI base oil resulted in lower particle emissions. Test stand measurements with gear oils formulated with either VHVI base oils or PAOs yielded comparable results in terms of power transfer ratio and oil temperature increase. (orig.)

Sorption mechanisms of selenium species (selenite and selenate) on copper-based minerals

International Nuclear Information System (INIS)

Devoy, J.

2001-09-01

The sorption of radionuclides on the surface of minerals represents a process capable to delay the migration of the elements from a spent fuel deep repository towards the biosphere. In the framework of a deep underground repository, an engineered clay barrier has a high trapping capacity for cationic radio-elements, in particular because of the negative charge of clay surfaces. However, anionic radioelements like selenium species, would be only weakly retained by chemical processes. In order to optimize the trapping capacity of a clay barrier with respect to anionic species, prospective studies are carried out in order to find and evaluate some minerals with specific chemical trapping functions. Among radionuclides, the case of selenium has to be considered because its isotope 79 Se is present in radioactive wastes and has a half life time of 6.5 10 4 years. It is also judicious to find a mineral capable of trapping simultaneously several anionic radio-elements. Copper oxides and sulfides (Cu 2 O, CuO, Cu 2 S, CuS, CuFeS 2 and Cu 5 FeS 4 ) are good adsorbents with respect to selenium species (selenite and selenate). These minerals, with their selenium retention properties, could be used also for the decontamination of soils and waters or to process industrial effluents. The sorption mechanisms have been studied in details for copper oxides (Cu 2 O and CuO) with respect to selenite and selenate. Chalcomenite precipitates in acid pH conditions when selenite is added to a Cu 2 O and CuO suspension. Selenate, in contact with cuprite (Cu 2 O) leads also to a selenium-based precipitate in acid pH environment. For higher pH values, selenite and selenate are adsorbed on copper oxides (Cu 2 O and CuO) and lead to internal and external sphere complexes, respectively. In the case of a selenite/cuprite mixture in basic pH environment and at the equilibrium, a chemical reaction occurs between the oxidation product of cuprite, Cu(OH) 2 and HSeO 3 . A preliminary study of

Optimization of Refining Craft for Vegetable Insulating Oil

Science.gov (United States)

Zhou, Zhu-Jun; Hu, Ting; Cheng, Lin; Tian, Kai; Wang, Xuan; Yang, Jun; Kong, Hai-Yang; Fang, Fu-Xin; Qian, Hang; Fu, Guang-Pan

2016-05-01

Vegetable insulating oil because of its environmental friendliness are considered as ideal material instead of mineral oil used for the insulation and the cooling of the transformer. The main steps of traditional refining process included alkali refining, bleaching and distillation. This kind of refining process used in small doses of insulating oil refining can get satisfactory effect, but can't be applied to the large capacity reaction kettle. This paper using rapeseed oil as crude oil, and the refining process has been optimized for large capacity reaction kettle. The optimized refining process increases the acid degumming process. The alkali compound adds the sodium silicate composition in the alkali refining process, and the ratio of each component is optimized. Add the amount of activated clay and activated carbon according to 10:1 proportion in the de-colorization process, which can effectively reduce the oil acid value and dielectric loss. Using vacuum pumping gas instead of distillation process can further reduce the acid value. Compared some part of the performance parameters of refined oil products with mineral insulating oil, the dielectric loss of vegetable insulating oil is still high and some measures are needed to take to further optimize in the future.

Finding Trapped Miners by Using a Prototype Seismic Recording System Made from Music-Recording Hardware

Science.gov (United States)

Pratt, Thomas L.

2009-01-01

The goal of this project was to use off-the-shelf music recording equipment to build and test a prototype seismic system to listen for people trapped in underground chambers (mines, caves, collapsed buildings). Previous workers found that an array of geophones is effective in locating trapped miners; displaying the data graphically, as well as playing it back into an audio device (headphones) at high speeds, was found to be effective for locating underground tapping. The desired system should record the data digitally to allow for further analysis, be capable of displaying the data graphically, allow for rudimentary analysis (bandpass filter, deconvolution), and allow the user to listen to the data at varying speeds. Although existing seismic reflection systems are adequate to record, display and analyze the data, they are relatively expensive and difficult to use and do not have an audio playback option. This makes it difficult for individual mines to have a system waiting on the shelf for an emergency. In contrast, music recording systems, like the one I used to construct the prototype system, can be purchased for about 20 percent of the cost of a seismic reflection system and are designed to be much easier to use. The prototype system makes use of an ~$3,000, 16-channel music recording system made by Presonus, Inc., of Baton Rouge, Louisiana. Other manufacturers make competitive systems that would serve equally well. Connecting the geophones to the recording system required the only custom part of this system - a connector that takes the output from the geophone cable and breaks it into 16 microphone inputs to be connected to the music recording system. The connector took about 1 day of technician time to build, using about $300 in off-the-shelf parts. Comparisons of the music recording system and a standard seismic reflection system (A 24-channel 'Geode' system manufactured by Geometrics, Inc., of San Jose, California) were carried out at two locations. Initial

CONTRIBUTIONS TO EVALUATION OF THE BIODEGRADABILITY BY ASPERGILLUS NIGER AND OTHER FUNGI’S OF SOME INSULATING OILS

Directory of Open Access Journals (Sweden)

RADU E.

2015-06-01

Full Text Available Mineral insulating oils used in electrical equipment because of their toxic organic substances and xenobiotic, represents a major risk to the environment - to accidental spills pollute soil, groundwater and surface water. By microbiological tests were evaluated the biodegradability of some insulating oils used in electrical equipment. The assays were performed in comparison with edible sunflower oil and with a control sample (culture medium - without oil. The experimental results indicate that the mineral oils are more readily biodegradable than synthetic ester oil and vegetable oils. It was also found that oils with high sulfur content are more readily biodegradable.

Measurement of optically and thermally stimulated electron emission from natural minerals

DEFF Research Database (Denmark)

Ankjærgaard, C.; Murray, A.S.; Denby, P.M.

2006-01-01

to a Riso TL/OSL reader, enabling optically stimulated electrons (OSE) and thermally stimulated electrons (TSE) to be measured simultaneously with optically stimulated luminescence (OSL) and thermoluminescence (TL). Repeated irradiation and measurement is possible without removing the sample from...... the counting chamber. Using this equipment both OSE and TSE from loose sand-sized grains of natural minerals has been recorded. It is shown that both the surface electron traps (giving rise to the OSE signals) and the bulk traps (giving rise to OSL) have the same dosimetric properties. A comparison of OSL...

Structure- and oil type-based efficacy of emulsion adjuvants.

Science.gov (United States)

Jansen, Theo; Hofmans, Marij P M; Theelen, Marc J G; Manders, Frans; Schijns, Virgil E J C

2006-06-29

Oil-based emulsions are well-known immunopotentiators for inactivated, "killed" vaccines. We addressed the relationship between emulsion structure and levels of in vivo antibody formation to inactivated New Castle Disease virus (NDV) and Infectious Bronchitis virus (IBV) as antigens in 3-week-old chickens. The use of a polymeric emulsifier allowed for direct comparison of three types of emulsions, water-in-oil (W/O), oil-in-water (O/W) and W/O-in-water (W/O/W), while maintaining an identical content of components for each vehicle. They were prepared with either non-metabolizable, mineral oil or metabolizable, Miglyol 840. In addition, we assessed the inherent release capacity of each emulsion variant in vitro. Remarkably, we noted that W/O-type emulsions induced the best immune responses, while they released no antigen during 3 weeks. In general, mineral oil vaccines showed superior efficacy compared to Miglyol 840-based vaccines.

Experimental study on kinetics oil oil-suspended particulate matter aggregation

International Nuclear Information System (INIS)

Sun, J.; Environment Canada, Ottawa, ON; Khelifa, A.; Wang, Z.; Brown, C.; Fieldhouse, B.; Yang, C.; Zheng, X.; Wong, S.; So, L.C.

2009-01-01

Past studies of oil spills have shown that oil suspended particulate matter aggregates (OSAs) play a role in enhancing the natural cleansing of oiled shorelines. OSAs result from aggregation between suspended oil droplets and suspended particulate matter (SPM) in aquatic environments. During this process, oil dispersion into the water column is significantly increased since the surface of the oil droplet is surrounded by sediment particles. In addition, the accelerated biodegradation of the oil can be attributed to the greater oil-water contact area. This study focused on the kinetic aspects of OSA formation, with particular reference to the time scale of this process and its significance to oil dispersion following oil spills in water. A laboratory study was conducted to measure the time scale of OSA formation and its variations with mixing conditions. A reciprocating shaker and various oil/sediment mixtures were used to prepare the OSAs. Standard reference material 1941b was used as the natural sediment mixed with Arabian medium crude and artificial seawater under various mixing energies. The sediment-to-oil ratio remained constant for all experiments. Gas chromatography-flame ionization detection (GC-FID) analysis was used to measure the total petroleum hydrocarbons (TPH) trapped in negatively buoyant OSAs. Results showed that the TPH in OSAs increased exponentially with shaking time and reached an equilibrium value within 3 hours. The equilibrium decreased from 3 hours to 1.3 hours when the shaking rate increased from 2.0 to 2.3 Hz. It was concluded that high mixing energy enhances OSA formation and shortens the time for OSA formation. 42 refs., 6 tabs., 5 figs

Experimental study on kinetics oil oil-suspended particulate matter aggregation

Energy Technology Data Exchange (ETDEWEB)

Sun, J. [Ocean Univ. of China, Qingdoa (China). Environmental Science and Engineering Inst.; Environment Canada, Ottawa, ON (Canada). Emergencies Science and Technology Section, Emergencies, Operational Analytical Laboratories and Research Support Division; Khelifa, A.; Wang, Z.; Brown, C.; Fieldhouse, B.; Yang, C. [Environment Canada, Ottawa, ON (Canada). Emergencies Science and Technology Section, Emergencies, Operational Analytical Laboratories and Research Support Division; Zheng, X. [Ocean Univ. of China, Qingdoa (China). Environmental Science and Engineering Inst.; Wong, S. [Ottawa Univ., ON (Canada). Dept. of Chemistry; So, L.C. [Waterloo Univ., ON (Canada). Faculty of Engineering

2009-07-01

Past studies of oil spills have shown that oil suspended particulate matter aggregates (OSAs) play a role in enhancing the natural cleansing of oiled shorelines. OSAs result from aggregation between suspended oil droplets and suspended particulate matter (SPM) in aquatic environments. During this process, oil dispersion into the water column is significantly increased since the surface of the oil droplet is surrounded by sediment particles. In addition, the accelerated biodegradation of the oil can be attributed to the greater oil-water contact area. This study focused on the kinetic aspects of OSA formation, with particular reference to the time scale of this process and its significance to oil dispersion following oil spills in water. A laboratory study was conducted to measure the time scale of OSA formation and its variations with mixing conditions. A reciprocating shaker and various oil/sediment mixtures were used to prepare the OSAs. Standard reference material 1941b was used as the natural sediment mixed with Arabian medium crude and artificial seawater under various mixing energies. The sediment-to-oil ratio remained constant for all experiments. Gas chromatography-flame ionization detection (GC-FID) analysis was used to measure the total petroleum hydrocarbons (TPH) trapped in negatively buoyant OSAs. Results showed that the TPH in OSAs increased exponentially with shaking time and reached an equilibrium value within 3 hours. The equilibrium decreased from 3 hours to 1.3 hours when the shaking rate increased from 2.0 to 2.3 Hz. It was concluded that high mixing energy enhances OSA formation and shortens the time for OSA formation. 42 refs., 6 tabs., 5 figs.

Sugars, organic acids, minerals and lipids in jabuticaba

Directory of Open Access Journals (Sweden)

Annete de Jesus Boari Lima

2011-06-01

Full Text Available The aim of this work was to determine the sugar, organic acid and mineral compositions of the whole fruit and fractions (skin, pulp and seed of the Paulista (Plinia cauliflora and Sabará (Plinia jaboticaba jabuticaba tree genotypes, as well as the oil compositions of their skin and seeds. High levels of sugar, especially fructose, followed by glucose and sucrose, were encountered in the fruit. In the Paulista genotype, higher levels of total and reducing sugars were found in the pulp and skin, which was not observed when comparing the whole fruit of both genotypes. Five organic acids were found in the whole fruit and in the fractions of the two jabuticaba genotypes in quantitative order: citric acid > succinic acid > malic acid > oxalic acid > acetic acid. Potassium was the most abundant mineral found. This fruit was also shown to be rich in magnesium, phosphorus, calcium and copper. The seed oil had nearly the same constitution as the oil extracted from the skin in both genotypes and the major compounds were an unidentified phytosterol, palmitic, linoleic and oleic acids, and squalene.

Structural financing and management of investment projects in the Nigerian mineral industry

International Nuclear Information System (INIS)

Akingbola, E. B. O.

1997-01-01

The mineral industry is attractive because of the diversity and abundance of the deposits. The economic and financial implications of exploiting these are considered. The issues discussed include capital requirement, international outlook, investment opportunities in the mineral industry, oil and gas, solid minerals, attracting investment into the mineral industry,structural financing, macro economic stability. The paper concludes that the ability of the industry to continue attracting foreign capital is crucial to its survival, growth and development

Efficacy of fipronil aerially applied in oil adjuvants and drift retardants against boll weevils, Anthonomus Grandis Boheman (Coleoptera:Curculionidae)

Science.gov (United States)

Joseph E. Mulrooney

2002-01-01

Results of aerial application tests in the field and insecticide transfer tests in the laboratory showed that cottonseed oil was the most effective oil adjuvant to use with fipronil for controlling boll weevils under field conditions and for transferring fipronil from cotton leaf surfaces to boll weevils. The mineral oil and mineral oil + drift retardant more...

Possible Involvement of Permian Phosphoria Formation Oil as a Source of REE and Other Metals Associated with Complex U-V Mineralization in the Northern Bighorn Basin?

Directory of Open Access Journals (Sweden)

Anita L. Moore-Nall

2017-11-01

Full Text Available The origin of V, U, REE and other metals in the Permian Phosphoria Formation have been speculated and studied by numerous scientists. The exceptionally high concentrations of metals have been interpreted to reflect fundamental transitions from anoxic to oxic marine conditions. Much of the oil in the Bighorn Basin, is sourced by the Phosphoria Formation. Two of the top 10 producing oil fields in Wyoming are located approximately 50 km west of two abandoned U-V mining districts in the northern portion of the basin. These fields produce from basin margin anticlinal structures from Mississippian age reservoir rock. Samples collected from abandoned U-V mines and prospects hosted in Mississippian aged paleokarst in Montana and Wyoming have hydrocarbon residue present and contain anomalous high concentrations of many metals that are found in similar concentrations in the Phosphoria Formation. As, Hg, Mo, Pb, Tl, U, V and Zn, often metals of environmental concern occur in high concentrations in Phosphoria Formation samples and had values ranging from 30–1295 ppm As, 0.179–12.8 ppm Hg, 2–791 ppm Mo, <2–146 ppm Pb, 10–490 ppm Tl, 907–86,800 ppm U, 1240–18,900 ppm V, and 7–2230 ppm Zn, in mineralized samples from this study. The REE plus Y composition of Madison Limestone- and limestone breccia hosted-bitumen reflect similar patterns to both mineralized samples from this study and to U.S. Geological Survey rock samples from studies of the Phosphoria Formation. Geochemical, mineralogical and field data were used to investigate past theories for mineralization of these deposits to determine if U present in home wells and Hg content of fish from rivers on the proximal Crow Indian Reservation may have been derived from these deposits or related to their mode of mineralization.

Simplified models of rates of CO2 mineralization in Geologic Carbon Storage

Science.gov (United States)

DePaolo, D. J.; Zhang, S.

2017-12-01

Geologic carbon storage (GCS) reverses the flow of carbon to the atmosphere, returning the carbon to long-term geologic storage. Models suggest that most of the injected CO2 will be "trapped" in the subsurface by physical means, but the most risk-free and permanent form of carbon storage is as carbonate minerals (Ca,Mg,Fe)CO3. The transformation of CO2 to carbonate minerals requires supply of divalent cations by dissolution of silicate minerals. Available data suggest that rates of transformation are difficult to predict. We show that the chemical kinetic observations and experimental results, when reduced to a single timescale that describes the fractional rate at which cations are released to solution by mineral dissolution, show sufficiently systematic behavior that the rates of mineralization can be estimated with reasonable certainty. Rate of mineralization depends on both the abundance (determined by the reservoir rock mineralogy) and the rate at which cations are released by dissolution into pore fluid that has been acidified with dissolved CO2. Laboratory-measured rates and field observations give values spanning 8 to 10 orders of magnitude, but when evaluated in the context of reservoir-scale reactive transport simulations, this range becomes much smaller. Reservoir scale simulations indicate that silicate mineral dissolution and subsequent carbonate mineral precipitation occur at pH 4.5 to 6, fluid flow velocity less than 5m/yr, and 50-100 years or more after the start of injection. These constraints lead to estimates of 200 to 2000 years for conversion of 60-90% of injected CO2 when the reservoir rock has a sufficient volume fraction of divalent cation-bearing silicate minerals (ca. 20%), and confirms that when reservoir rock mineralogy is not favorable the fraction of CO2 converted to carbonate minerals is minimal over 104 years. A sufficient amount of reactive minerals represents the condition by which the available cations per volume of rock plus pore

Modification of the process for separating and recovering oil from oil-sands, etc

Energy Technology Data Exchange (ETDEWEB)

Preller, H

1922-08-30

A method of carrying out the process according to Patent 400,122 especially for washing oil or bitumen-bearing mineral materials contaminated with more or less clay, marl, and so forth is characterized in that the oil-bearing raw material is first washed in an opposing stream of warm water for separating the larger part of the oil and settling the larger part of the rock. At the same time the fine clay suspended during the washing operation to a large extent and the remaining rock particles, which are unbound from the oil, by means of a regulatable water stream for further washing are carried into a receptacle of greater cross section, where by the very slow rise of the liquid the finer oil particles find an opportunity to ascend.

Alternatives to Mineral Oil Adjuvants in Vaccines Against Aeromonas salmonicida subs. salmonicida in Rainbow Trout Offer Reductions in Adverse Effects

DEFF Research Database (Denmark)

Villumsen, Kasper Rømer; Koppang, Erling Olaf; Christensen, Dennis

2017-01-01

In an effort to reduce the frequency and severity of adverse reactions seen from the use of mineral oil adjuvants in salmonid fish, the effects of two alternative adjuvants were assessed, focusing on the induction of adverse effects as well as protection. Using rainbow trout (Oncorhynchus mykiss)...... protection appears similar to that of the benchmark formulation, thus introducing viable, potential alternative types of adjuvants for use in future fish vaccines....

Performance of palm oil as a biobased machining lubricant when drilling inconel 718

Directory of Open Access Journals (Sweden)

Abd Rahim Erween

2017-01-01

Full Text Available Metalworking fluid acts as cooling and lubrication agent at the cutting zone in the machining process. However, conventional Metalworking fluid such mineral oil gives negative impact on the human and environment. Therefore, the manufacture tends to substitute the mineral oil to bio-based oil such as vegetables and synthetic oil. In this paper, the drilling experiment was carried out to evaluate the efficiency of palm oil and compare it with minimal quantity lubrication technique using synthetic ester, flood coolant and air blow with respect to cutting temperature, cutting force, torque and tool life. The experimental results showed that the application of palm oil under minimal quantity lubrication condition as the cutting fluid was more efficient process as it improves the machining performances.

Application of high-performance liquid chromatography-tandem mass spectrometry with a quadrupole/linear ion trap instrument for the analysis of pesticide residues in olive oil.

Science.gov (United States)

Hernando, M D; Ferrer, C; Ulaszewska, M; García-Reyes, J F; Molina-Díaz, A; Fernández-Alba, A R

2007-11-01

This article describes the development of an enhanced liquid chromatography-mass spectrometry (LC-MS) method for the analysis of pesticides in olive oil. One hundred pesticides belonging to different classes and that are currently used in agriculture have been included in this method. The LC-MS method was developed using a hybrid quadrupole/linear ion trap (QqQ(LIT)) analyzer. Key features of this technique are the rapid scan acquisition times, high specificity and high sensitivity it enables when the multiple reaction monitoring (MRM) mode or the linear ion-trap operational mode is employed. The application of 5 ms dwell times using a linearly accelerating (LINAC) high-pressure collision cell enabled the analysis of a high number of pesticides, with enough data points acquired for optimal peak definition in MRM operation mode and for satisfactory quantitative determinations to be made. The method quantifies over a linear dynamic range of LOQs (0.03-10 microg kg(-1)) up to 500 microg kg(-1). Matrix effects were evaluated by comparing the slopes of matrix-matched and solvent-based calibration curves. Weak suppression or enhancement of signals was observed (ion (EPI) and MS3 were developed.

Effects of dietary lipid composition and inulin-type fructans on mineral bioavailability in growing rats.

Science.gov (United States)

Lobo, Alexandre Rodrigues; Filho, Jorge Mancini; Alvares, Eliana Parisi; Cocato, Maria Lucia; Colli, Célia

2009-02-01

This study reports the effects of feeding with a combination of inulin-type fructans (ITF) and fish oil (FO) on mineral absorption and bioavailability as part of a semipurified diet offered to rats. Male Wistar rats (n = 24) were fed a 15% lipid diet (soybean oil [SO] or a 1:0.3 fish:soybean oil mixture [FSO]) and diets containing the same sources of lipids supplemented with 10% ITF (Raftilose Synergy 1) ad libitum for 15 d. Feces and urine were collected for mineral analyses during the last 5 d of the test period. Fatty acid composition was determined in liver and cecal mucosa homogenates. Liver and bone mineral analyses were performed by atomic absorption spectrophotometry. Bone biomechanical analyses were evaluated by a 3-point bending test. Compared with the controls, ITF-fed rats had enlarged ceca and a significant decrease in cecal content pH (P mineral absorption was improved in these rats, and this effect was enhanced by dietary combination with FO for all minerals except for magnesium. Addition of ITF to the diet resulted in higher bone mineral content (calcium and zinc) and bone strength, but increased bone mineral content was only statistically significant in FO-fed animals. A decrease in liver iron stores (P = 0.015) was observed in rats fed FO, considering that ITF consumption returned to levels comparable to the SO control group. These findings confirm the positive influence of ITF on mineral bioavailability, which was potentiated by addition of FO to the diet.

Process and apparatus for distilling bituminous minerals

Energy Technology Data Exchange (ETDEWEB)

Veyrier, J A

1922-03-27

This process of distillation of bituminous minerals and particularly bituminous limestone is characterized by the fact that the minerals are introduced into the retort where they stand only the temperature necessary to distill the water and lighter oils that they contain and then are drawn out into the hearth and serve for heating the retort. The apparatus is characterized by the fact that the retort has a screw conveyor, placed in the flue of the hearth, supplied with a chamber for evacuation below this hearth.

Record of the solar corpuscular radiation in minerals from lunar soils - A comparative study of noble gases and tracks

International Nuclear Information System (INIS)

Wieler, R.; Etique, P.

1980-01-01

A comparative study is made of trapped light noble gases and solar flare tracks in mineral separates from lunar soils in an investigation aimed at detecting possible temporal variations of the ratio between solar flare and solar wind activity. He, Ne, Ar and solar flare tracks are measured on plagioclase separates of 12 surface soils and two Apollo 15 drill core samples, and track density histograms are compared with gas concentration distributions obtained from aliquot samples. Results show that solar wind Ar is probably well retained in all minerals. He, Ne, and Ar are not saturated macroscopically, and semi-microscopic or microscopic saturation is very rare for Ar, even in gas-rich plagioclase populations. All grains contain trapped noble gases, even in relatively gas-poor mineral populations, and for clean minerals in the size range of 150-200 microns, the time between the first and last surface exposure is in the order of 10 to the 7th to 10 to the 8th years

Manuka oil and phoebe oil are attractive baits for Xyleborus glabratus (Coleoptera: Scolytinae), the vector of laurel wilt.

Science.gov (United States)

Hanula, James L; Sullivan, Brian

2008-12-01

Redbay ambrosia beetle, Xyleborus glabratus Eichhoff, is a native of Southeast Asia recently established in coastal forests of Georgia, SC and Florida. It vectors a wilt fungus, Raffaelea sp., lethal to redbay trees, Persea borbonia L. Spreng, and certain other Lauraceae. No practical monitoring system exists for this beetle so we conducted studies to identify host attractants and develop lures. Volatiles were collected from redbay wood and bark by steam distillation, direct solvent extraction, and dynamic headspace sampling with a Poropak Q cartridge. Steam, methanol, and pentane extracts were tested as baits in trapping trials but were not attractive to X. glabratus. Major constituents in Poropak aerations identified by gas chromatography-mass spectrometry included alpha-pinene, beta-pinene, delta-3-carene, eucalyptol, p-cymene, alpha-copaene, terpinene-4-ol, linalool, calamenene, and nonanoic acid. We assayed several of these compounds (including eucalyptol, p-cymene, terpinene-4-ol, linalool, nonanoic acid, and caryophyllene oxide) both individually and in combination, but none were attractive at tested doses. Two other redbay odor components, alpha-copaene and calamenene, were unavailable in sufficient quantities commercially so we substituted manuka oil, the essential oil extracted from Leptospermum scoparium Forst. and Forst., which contains high proportions of both compounds. Manuka oil was equally attractive as redbay wood to X. glabratus, but increasing release rates >10-fold did not enhance its activity. Phoebe oil, an extract of Brazilian walnut (Phoebe porosa Mez.), which contains significant quantities of alpha-copaene and calamenene, was also attractive. Fractions of manuka oil were not more attractive than the whole oil. Manuka and phoebe oil are readily available and are good alternatives to redbay wood as a trap bait for monitoring X. glabratus distribution and population trends.

Dynamics of mineral crystallization from precipitated slab-derived fluid phase: first in situ synchrotron X-ray measurements

Science.gov (United States)

Malaspina, Nadia; Alvaro, Matteo; Campione, Marcello; Wilhelm, Heribert; Nestola, Fabrizio

2015-03-01

Remnants of the fluid phase at ultrahigh pressure (UHP) in subduction environments may be preserved as primary multiphase inclusions in UHP minerals. The mode of crystallization of daughter minerals during precipitation within the inclusion and/or the mechanism of interaction between the fluid at supercritical conditions and the host mineral are still poorly understood from a crystallographic point of view. A case study is represented by garnet-orthopyroxenites from the Maowu Ultramafic Complex (China) deriving from harzburgite precursors metasomatized at ~4 GPa, 750 °C by a silica- and incompatible trace element-rich fluid phase. This metasomatism produced poikilitic orthopyroxene and inclusion-rich garnet porphyroblasts. Solid multiphase primary inclusions in garnet display a size within a few tens of micrometres and negative crystal shapes. Infilling minerals (spinel: 10-20 vol%; amphibole, chlorite, talc, mica: 80-90 vol%) occur with constant volume proportions and derive from trapped solute-rich aqueous fluids. To constrain the possible mode of precipitation of daughter minerals, we performed for the first time a single-crystal X-ray diffraction experiment by synchrotron radiation at Diamond Light Source. In combination with electron probe microanalyses, this measurement allowed the unique identification of each mineral phase and reciprocal orientations. We demonstrated the epitaxial relationship between spinel and garnet and between some hydrous minerals. Such information is discussed in relation to the physico-chemical aspects of nucleation and growth, shedding light on the mode of mineral crystallization from a fluid phase trapped at supercritical conditions.

The Susceptibility of Some Oil Palm Elaeis guineensis Jacq Progenies to Coelaenomenodera lameensis Berti and Mariau, (Coleoptera: Chrysomelidae)

OpenAIRE

S.O.N. Dimkpa

2010-01-01

Damage by the oil palm leaf miner C. lam eensis has been observed in all oil palm growing countriesin Africa causing wide spread defoliation and result to considerable reduction in the yield of fresh fruit bunches(ffb). The understanding of the susceptibility levels of different oil palm progenies to the oil palm leaf minerC. lameensis become highly imperative in the development and incorporation of host plant resistance in theintegrated pest management strategy for the management of the oil ...

Hydraulic considerations in deigning an oil spill control system for stormwater outfall

Energy Technology Data Exchange (ETDEWEB)

Li, J.; Chui, J. [Ryerson University, Dept. of Civil Engineering, Toronto, ON (Canada)

2004-09-01

An oil spill control system, consisting of an on-line triangular lateral diversion channel and an off-line tilted-plate oil-water separator, installed in the Humber Creek sub-watershed in Toronto, Ontario, is described. The area, which rims the shore of Lake Ontario from the Niagara Peninsula to Oshawa, is heavily industrialized, and is home to some 5.6 million people. During the 1990s an estimated average of 1050 litre/day of petroleum products have escaped into the environment; soil contamination occurred in 55 per cent of the cases, and water-course pollution in 31 per cent. A physical model study was conducted at the National Water Research Institute's Hydraulic Laboratory in Burlington, Ontario, to investigate the hydraulic behaviour of the spill control system under different flow conditions. Results of the investigation confirmed the design conveyance capacity of the lateral diversion channel; it also confirmed that floating objects and settleable solids could be trapped inside the oil-water separator under various flow conditions. Because the angled diversion channel was observed to cause a vortex action inside the first and second chambers of the separator and increase the potential for trapped oil to be flushed out, it is recommended that the final design of the spill control system pay special attention to the vortex problem. One potential solution for this problem may be the installation of baffles at the second chamber of the oil-water separator. It was further recommended that the design should also address the flushing of trapped oil during wet weather conditions. 23 refs., 2 tabs., 10 figs.

Magnesium Sulfate as a Key Mineral for the Detection of Organic Molecules on Mars Using Pyrolysis

Science.gov (United States)

Francois, P.; Szopa, C.; Buch, A.; Coll, P.; McAdam, A. C.; Mahaffy, P. R.; Freissinet, C.; Glavin, D. P.; Navarro-Gonzalez, R.; Cabane, M.

2016-01-01

Pyrolysis of soil or rock samples is the preferred preparation technique used on Mars to search for organic molecules up today. During pyrolysis, oxichlorines present in the soil of Mars release oxidant species that alter the organic molecules potentially contained in the samples collected by the space probes.This process can explain the difficulty experienced by in situ exploration probes to detect organic materials in Mars soil samples until recently. Within a few months, the Curiosity rover should reach and analyze for the first time soils rich in sulfates which could induce a different behavior of the organics during the pyrolysis compared with the types of soils analyzed up today. For this reason, we systematically studied the pyrolysis of organic molecules trapped in magnesium sulfate, in the presence or absence of calcium perchlorate. Our results show that organics trapped in magnesium sulfate can undergo some oxidation and sulfuration during the pyrolysis. But these sulfates are also shown to protect organics trapped inside the crystal lattice and/or present in fluid inclusions from the oxidation induced by the decomposition of calcium perchlorate and probably other oxychlorine phases currently detected on Mars. Trapped organics may also be protected from degradation processes induced by other minerals present in the sample, at least until these organics are released from the pyrolyzed sulfate mineral (700C in our experiment). Hence, we suggest magnesium sulfate as one of the minerals to target in priority for the search of organic molecules by the Curiosity and ExoMars 2018 rovers.

Comparison between jojoba oil and other vegetable oils as a substitute to petroleum

Energy Technology Data Exchange (ETDEWEB)

El Kinawy, O. [National Research centre, Dokki, Cairo (Egypt)

2004-06-15

Jojoba oil and other vegetable oils, such as soybean, sunflower and castor oils, were evaluated to be used as lubricants. Three standard mineral lubricating oils were considered in this study as reference. The essential parameters tested for comparison were the oil viscosity, viscosity index, and viscosity--temperature and shear rate--shear stress relationships. The effect of excessive heating on the vegetable oils' stability was studied and the corresponding parameters were also measured. Jojoba oil was found to be the best among all tested oils, whereas it gave the minimum change in viscosity gradient and hence the highest viscosity index. There was a linear relation between shear rate and shear stress of all oils before and after heat deterioration. Therefore, these oils were considered as Newtonion liquids. However, the oil viscosity, as well as the rate of viscosity variation with temperature, ({delta}{sup '}{eta}/{delta}{tau}) were affected by heat deterioration being lowered in value, in case of jojoba oil, and higher value, in case of castor oil. Jojoba oil was examined for other important properties for its use as a lubricant, such as refractive index, acid value, peroxide value, saponification value, iodine value, flash, fire and pour points. (author)

Reduced Need of Lubricity Additives in Soybean Oil Blends Under Boundary Lubrication Conditions

Science.gov (United States)

Converging prices of vegetable oils and petroleum, along with increased focus on renewable resources, gave more momentum to vegetable oil lubricants. Boundary lubrication properties of four Extreme Pressure (EP) additive blends in conventional Soy Bean Oil (SBO) and Paraffinic Mineral Oil (PMO) of ...

Partial Discharge Phase Distribution Of Palm Oil As Insulating Liquid

Directory of Open Access Journals (Sweden)

Abdul Rajab

2011-04-01

Full Text Available Due to the low biodegradability level of mineral oil and its susceptibility to the fire, palm oil was proposed as alternative insulating liquid. This paper discusses partial discharge (PD in palm oil under sinusoidal voltages and the comparison with mineral oil. PD was generated using a needle-plane electrode configuration which is enable enhancing electric field at the needle tip. PD pulses were detected using RC detector and they were measured using a Computer-based partial discharge measurement system. The results showed that PD activities in both oils are similar. The PD was initiated at the negative polarity of applied voltage. The discharges took place in both polarity’s of applied voltage with PD number was higher at negative one. Several discharges phenomena showed the presence of space charge which changed electric field and governed PD activities besides the main field introduced by voltage application.

Rheology of unstable mineral emulsions

Directory of Open Access Journals (Sweden)

Sokolović Dunja S.

2013-01-01

Full Text Available In this paper, the rheology of mineral oils and their unstable water emulsion were investigated. The oil samples were domestic crude oil UA, its fractions UA1, UA4 and blend semi-product UP1, while the concentration of oil in water emulsions was in the range from 1 up to 30%. The results were analyzed based on shear stress. The oil samples UA, UA1 and UP1 are Newtonian fluids, while UA4 is pseudoplastic fluid. The samples UA and UA4 show higher value of shear stress (83.75 Pa, 297 Pa, then other two samples UA1 and UP1 (18.41 Pa, 17.52 Pa. Rheology of investigated oils due to its complex chemical composition should be analyzed as a simultaneous effect of all their components. Therefore, structural composition of the oils was determined, namely content of paraffins, naphthenes, aromatics and asphaltenes. All samples contain paraffins, naphthenes and aromatics but only oils UA and UA4 contain asphaltenes as well. All investigated emulsions except 30% EUA4 are Newtonian fluids. The EUA4 30% emulsion shows pseudoplastic behaviour, and it is the only 30% emulsion among investigated ones that achieves lower shear stress then its oil. The characteristics of oil samples that could have an influence on their properties and their emulsion rheology, were determined. These characteristics are: neutralization number, interfacial tension, dielectric constant, and emulsivity. Oil samples UA and UA4 have significantly higher values of neutralization number, dielectric constants, and emulsivity. The sample UA has the lowest value of interface tension and the greatest emulsivity, indicating that this oil, among all investigated, has the highest preference for building emulsion. This could be the reason why 20% and 30% emulsions of the oil UA achieve the highest shear stress among all investigated emulsions.

Microbial activity in Alaskan taiga soils contaminated by crude oil in 1976

International Nuclear Information System (INIS)

Monroe, E.M.; Lindstrom, J.E.; Brown, E.J.; Raddock, J.F.

1995-01-01

Biodegradation, often measured via microbial activity, includes destruction of environmental pollutants by living microorganisms and is dependent upon many physical and chemical factors. Effects of mineral nutrients and organic matter on biodegradation of Prudhoe Bay crude oil were investigated at a nineteen-year-old oil spill site in Alaskan taiga. Microcosms of two different soil types from the spill site; one undeveloped soil with forest litter and detritus (O horizon) and one more developed with lower organic content (A horizon), were treated with various nitrogen and phosphorus amendments, and incubated for up to six weeks. Each microcosm was sampled periodically and assayed for hydrocarbon mineralization potential using radiorespirometry, for total carbon dioxide respired using gas chromatography, and for numbers of hydrocarbon-degrading bacteria and heterotrophic bacteria using most probable number counting techniques. Organic matter in the O horizon soil along with combinations of mineral nutrients were found to stimulate microbial activity. No combination of mineral nutrient additions to the A horizon soil stimulated any of the parameters above those measured in control microcosms. The results of this study indicate that adding mineral nutrients and tilling the O horizon into the A horizon of subarctic soils contaminated with crude oil, would stimulate microbial activity, and therefore the biodegradation potential, ultimately increasing the rate of destruction of crude oil in these soils

Biodegradable multifunctional oil production chemicals: Thermal polyaspartates

International Nuclear Information System (INIS)

Ross, R.J.; Ravenscroft, P.D.

1996-01-01

The paper deals with biodegradable oil production chemicals. Control of both mineral scale and corrosion with a single, environmentally acceptable material is an ambitious goal. Polyaspartate polymers represent a significant milestone in the attainment of this goal. Thermal polyaspartates (TPA) are polycarboxylate polymers derived via thermal condensation of the naturally occurring amino acid aspartic acid. These protein-like polymers are highly biodegradable and non-toxic, and are produced by an environmentally benign manufacturing process. TPAs exhibit excellent mineral scale inhibition activity and CO 2 corrosion control. Laboratory data on scale inhibition and corrosion control in the North Sea oil field production applications is presented. 8 refs., 2 figs., 6 tabs

Biodegradable multifunctional oil production chemicals: Thermal polyaspartates

Energy Technology Data Exchange (ETDEWEB)

Ross, R J [Donlar Corporation (United States); Ravenscroft, P D [BP Exploration Operating Company, (United Kingdom)

1997-12-31

The paper deals with biodegradable oil production chemicals. Control of both mineral scale and corrosion with a single, environmentally acceptable material is an ambitious goal. Polyaspartate polymers represent a significant milestone in the attainment of this goal. Thermal polyaspartates (TPA) are polycarboxylate polymers derived via thermal condensation of the naturally occurring amino acid aspartic acid. These protein-like polymers are highly biodegradable and non-toxic, and are produced by an environmentally benign manufacturing process. TPAs exhibit excellent mineral scale inhibition activity and CO{sub 2} corrosion control. Laboratory data on scale inhibition and corrosion control in the North Sea oil field production applications is presented. 8 refs., 2 figs., 6 tabs.

Direct Detection of Oil; Case History From Iran

International Nuclear Information System (INIS)

Tabatabaee, S. H.

2007-01-01

Iran is one of the main petroleum producers and also one of the countries which experiences contemporary geophysical techniques in Middle East region. Main aim of this study is direct detection of oil hydrocarbons by a special geophysical technique. To accomplish that, FEM, TEM and IP integrated geophysical techniques were successfully applied to measure IP phase shift which might relate to existence of oil traps. Target penetration for this prospecting is about 6 kms

Uranium traps in the phosphate bearing sudr chalk, in northeastern sinai, Egypt

International Nuclear Information System (INIS)

Hussein, H.A.; El-Aassy, I.E.; Mahdy, M.A.; Dabbour, G.A.; Mansour, M.Gh.; Morsy, A.M.

1998-01-01

The maastrichtian sudr formation in northeastern sinai is composed of three members, the lower chalk, the middle phosphate and chart-bearing and the upper chalk members. Lemon yellow secondary uranium mineralization, distributed in the lower chalk member and in some phosphate beds from the middle phosphate member are observed. The XRD analyses of some samples from the uranium bearing chalk and the phosphate beds showed the presence of the secondary uranium minerals carnotite, bergenite and upalite. The mode of uranium occurrences could be interpreted as a result of the phosphatic beds decomposition and their subjection to later diagenetic processes. Uranium leaching circulation from phosphate rocks led to the liberation of uranium from the phosphates, and vanadium from the bituminous material and clay minerals. These migrated and were deposited locally and within the underlying chalk beds which acted as a lithologic trap

30 CFR 208.4 - Royalty oil sales to eligible refiners.

Science.gov (United States)

2010-07-01

... 30 Mineral Resources 2 2010-07-01 2010-07-01 false Royalty oil sales to eligible refiners. 208.4... MANAGEMENT SALE OF FEDERAL ROYALTY OIL General Provisions § 208.4 Royalty oil sales to eligible refiners. (a... and defense. The Secretary will review these items and will determine whether eligible refiners have...

Performance of compression ignition engine with indigenous castor oil bio diesel in Pakistan

International Nuclear Information System (INIS)

Chakrabarti, M.H.

2009-01-01

Castor oil available indigenously in Pakistan was converted successfully to bio diesel and blended to 10% quantity (by volume) with high speed mineral diesel (HSD) fuel. This fuel was tested in a compression-ignition engine in order to assess its environmental emissions as well as engine performance parameters. The blended fuel was found to give lower environmental emissions in most accounts except for higher CO/sub 2/ and higher NOx. In addition, three engine performance parameters were assessed; which were engine brake power, engine torque and exhaust temperature. In the first two cases, blended bio diesel fuel gave lower figures than pure mineral diesel due to lower calorific value. However, its higher flash point resulted in higher engine exhaust temperatures than pure mineral diesel. Overall, in terms of engine performance, castor oil bio diesel (from non edible oil of castor bean -growing on marginal lands of Pakistan) fared better in comparison to canola oil bio diesel (from expensive edible oil) and can be recommended for further tests at higher blend ratios. (author)

Biodiesel development from rice bran oil: Transesterification process optimization and fuel characterization

International Nuclear Information System (INIS)

Sinha, Shailendra; Agarwal, Avinash Kumar; Garg, Sanjeev

2008-01-01

Increased environmental awareness and depletion of resources are driving industry to develop viable alternative fuels from renewable resources that are environmentally more acceptable. Vegetable oil is a potential alternative fuel. The most detrimental properties of vegetable oils are its high viscosity and low volatility, and these cause several problems during their long duration usage in compression ignition (CI) engines. The most commonly used method to make vegetable oil suitable for use in CI engines is to convert it into biodiesel, i.e. vegetable oil esters using process of transesterification. Rice bran oil is an underutilized non-edible vegetable oil, which is available in large quantities in rice cultivating countries, and very little research has been done to utilize this oil as a replacement for mineral Diesel. In the present work, the transesterification process for production of rice bran oil methyl ester has been investigated. The various process variables like temperature, catalyst concentration, amount of methanol and reaction time were optimized with the objective of producing high quality rice bran oil biodiesel with maximum yield. The optimum conditions for transesterification of rice bran oil with methanol and NaOH as catalyst were found to be 55 deg. C reaction temperature, 1 h reaction time, 9:1 molar ratio of rice bran oil to methanol and 0.75% catalyst (w/w). Rice bran oil methyl ester thus produced was characterized to find its suitability to be used as a fuel in engines. Results showed that biodiesel obtained under the optimum conditions has comparable properties to substitute mineral Diesel, hence, rice bran oil methyl ester biodiesel could be recommended as a mineral Diesel fuel substitute for compression ignition (CI) engines in transportation as well as in the agriculture sector

Oil and gas in the Ogaden Basin, Ethiopia

Energy Technology Data Exchange (ETDEWEB)

Du Toit, S.R.; Kurdy, S. [Alconsult International, Calgary, AB (Canada); Asfaw, S.H.; Gessesse, A.A. [Petroleum Operations Dept., Ministry of Mines and Energy, Addis Ababa (Ethiopia)

1997-09-01

To date, many of the 47 exploration and development wells drilled in the Ogaden Basin in Ethiopia have exhibited natural oil seeps and oil and gas shows. The Calub gas field and the Hilala oil field occurs in the central part of the 350,000 sq. km. basin. The various units within the basin consist of continental sediments, a regional organic-rich interval close to the Permo-Triassic boundary, organic-rich marine sediments and carbonates. The Ogaden Basin is dissected by several faults that are related to the Ethiopian Rift and may form a component of traps in the Calub-Hilala area.

Orthogonal trapping and sensing with long working distance optics [invited

DEFF Research Database (Denmark)

Glückstad, Jesper; Palima, Darwin; Tauro, Sandeep

2010-01-01

We are developing a next generation BioPhotonics Workstation to be applied in research on regulated microbial cell growth including their underlying physiological mechanisms, in vivo characterization of cell constituents and manufacturing of nanostructures and meta-materials. The workstation......Photonics Workstation that allows the user to directly control and simultaneously measure a portfolio of important chemical and biological processes. We arc currently able to generate up to 100 powerful optical traps using well-separated objectives, which eliminates the need for high numerical aperture oil or water...... immersion objectives required in conventional optical tweezers. This generates a large field of view and leaves vital space for integrating other enabling tools for probing the trapped particles, such as linear and nonlinear microscopy or micro-spectroscopy. Together with chcmists at another Danish...

The infrared stage Linkam FTIR 600 for microthermometric studies in dark and opaque minerals associated to uranium mineralization

International Nuclear Information System (INIS)

Lima, Tatiana Aparecida Fernandes de; Rios, Francisco Javier; Fuzikawa, Kazuo; Oliveira, Lucilia A. Ramos de; Oliveira, Elizabeth Kerpe; Neves, Jose Marques Correia; Prates, Sonia Pinto

2009-01-01

Fluid composition studies, throughout fluid inclusions (FI), contribute to improve the understanding of mineral deposits. FI correspond to small portions of fluids trapped in minerals by many processes that preserve relevant information related to fluid composition which forms ore deposits. Microscopy and microthermometry techniques applied to fluid inclusions studies of opaque and/or dark minerals use infrared light (IR). A specific stage heating/cooling that allows working in the near infrared (NIR). Thus, the infrared stage model FTIR600 Linkam coupled the IR OLYMPUS BX51, with the automatic controllers LNP 94/2 and TMS 94, and software Linksys 32 - Linkam installed in computer was implemented and tested. An infrared QUICAM fast 1394 QIMAGING TM camera with the program QCAPTURE SUITE was acquisition for images capture and adapted the new system. This infrared stage Linkam FTIR600 reach temperatures between -196 deg C to +600 deg C, with the differential of working in the NIR; it is all automated, obtaining computerized data, graphics in real time of analysis and storage the data. It also controls the speed of the experiment (up to 130 deg C/min); it runs consecutively heating and cooling with a small N 2 (l) consuming; besides greater results repeatability, obtaining accurate and precise temperatures. Actually the Linkam stage FTIR600 is operating in the Metallogenesis and Fluid Inclusions Laboratory (LIFM) at CDTN/CNEN. Uranium ore and/or others mineralization studies which shows dark or opaque mineral have been developed. The uranium mineralization in the Lagoa Real Uraniferous Province, Bahia, Brazil, shows several rock-forming minerals together with the dark and opaque minerals (garnet, magnetite, pyroxene) emphasized in the present work. (author)

Insights on the criteria of selection of vegetable and mineral dielectric fluids used in power transformers on the basis of their biodegradability and toxicity assessments.

Science.gov (United States)

Módenes, Aparecido Nivaldo; Sanderson, Karina; Trigueros, Daniela Estelita Goes; Schuelter, Adilson Ricken; Espinoza-Quiñones, Fernando Rodolfo; Neves, Camila Vargas; Zanão Junior, Luiz Antônio; Kroumov, Alexander Dimitrov

2018-05-01

Leakage of transformer dielectric fluids is a concern because it may pose a risk of environmental contamination. In this study, the deleterious effects of vegetable and mineral dielectric fluids in water bodies were investigated using biodegradability and acute toxicity tests with Danio rerio and Artemia salina. Regarding biodegradability, all four tested vegetable oils (soy, canola, sunflower and crambe) were considered as easily biodegradable, presenting degradation rates significantly higher than the Lubrax-type mineral fluid. Acute toxicity tests were performed in two separate experiments without solution renewal. In the first experiment, the organisms were exposed in direct contact to different concentrations of vegetable (soy) and mineral (Lubrax) oils. Total soy-type vegetable oil has a higher toxic effect than Lubrax-type mineral oil. In the second experiment, the organisms were exposed to increasing percentages of the water-soluble fraction (WSF) of both types of tested oils. The LC 50 values for the water-soluble fraction of the Lubrax-type mineral oil were about 5 and 8% for the Danio rerio and Artemia salina bioindicators, respectively, whereas the vegetable oil did not present toxic effect, regardless of its WSF. These results have shown that a strict selection of dielectric fluids and monitoring the leakage from power transformers is a serious duty of environmental protection agencies. Copyright © 2018 Elsevier Ltd. All rights reserved.

Thermoluminescence characterization of the irradiated minerals extracted from nopal

Science.gov (United States)

Cruz-Zaragoza, E.; Furetta, C.; Kitis, G.; Gomez, B. T.; Polymeris, G. S.; Tsirliganis, N.; Loukou, Z.

2006-05-01

The mineral fraction from dehydrated nopal leaves (Opuntia ficus indica ) belonging to the Cactaceae family was extracted and selected by sizes of 10 and 74 mu m and exposed to 60 Co gamma radiation at different doses in the range 70 Gy-20 kGy. The glow-curves from these polyminerals show a thermoluminescence (TL) band with one very intense peak at a temperature around 150 degrees C and a second one emerging in the high temperature region, moving in a large zone of temperature values according to the preparation used and the level of irradiation. The XRD analysis shows a composition of both biominerals as whewellite and weddellite and a mineral fraction as anorthoclase and quartz. The main TL characteristics of the polymineral content of the nopal was analyzed, i.e . the TL response at different doses and fading during storage at room temperature. The activation energy of the traps responsible for the TL emission was also investigated and a possible continuous distribution of traps is discussed. A review of the scientific literature shows that this is the first time that a TL study on nopal ionized by irradiation has been carried out.

Purifying oils

Energy Technology Data Exchange (ETDEWEB)

1930-04-15

Gasoline, lamp oils, and lubricating or other mineral or shale oils are refined by contacting the vapor with a hot aqueous solution of salts of zinc, cadmium, or mercury, or mixtures thereof which may contain 0-5-3-0 percent of oxide or hydroxide in solution or suspension. Chlorides, bromides, iodides, sulfates, nitrates, and sulfonates of benzol, toluol, xylol, and petroleum are specified. Washing with a solution of sodium or potassium hydroxide or carbonate of calcium hydroxide may follow. The oil may first be purified by sulfuric acid or other known agent, or afterwards caustic alkali and sulfuric acid. The Specification as open to inspection under Sect. 91 (3) (a) describes also the use of salts of copper, iron, chromium, manganese, aluminum, nickel, or cobalt, with or without their oxides or hydroxides. This subject-matter does not appear in the Specification as accepted.

The splitting of P and NG and oil sands rights: an historical perspective

Energy Technology Data Exchange (ETDEWEB)

Coombs, F. D. [Alberta Department of Energy, Edmonton, AB (Canada)

1997-12-31

Changes in the Mines and Minerals Act of Alberta are described to illustrate the evolution of the priorities and thinking over time that led to the present administration of oil sands and natural gas as separate minerals. Natural gas was first excluded from the definition of bituminous sands in 1955. The definition of bituminous sands was changed in 1957 to include natural gas once again. In a further change in 1978, both petroleum and natural gas were excluded from the definition of oil sands. More changes followed in 1984, when petroleum was added back into the definition, leaving natural gas as the only mineral excluded from the definition of oil sands. The 1984 change was triggered by changes in the Oil Sands Conservation Act. It is the current definition, which includes `sands and other rock materials containing crude bitumen, and any other mineral substances, other than natural gas, in association with that crude bitumen`. It was a resource conservation issue in the past, and it is a conservation issue today, although much influenced by changes in technology and increased knowledge and understanding of the relevant factors. 2 tabs.

Refining of wax-containing oil by distillation

Energy Technology Data Exchange (ETDEWEB)

1930-04-28

A continuous method is disclosed for producing low cold test oil from wax-containing mineral oil, which comprises continuously heating the oil in a tubular heater with avoidance of cracking, and fractionating the resulting liquid and vapor in a fractionating tower with reflux to produce a wax-containing fraction having therein substantially all of the amorphous wax and being sufficiently free of crystalline wax so as to be waxable by a method suitable for the removal of amorphous wax.

Oil analysis in machine diagnostics

Energy Technology Data Exchange (ETDEWEB)

Vaehaeoja, P.

2006-07-01

spilled into the soil during use and in accident situations, and they can migrate to groundwater layers. Biodegradation of oils can remove them from the soil or water completely or at least diminish the amount of harmful substances. An automatic, respirometric BOD OxiTop method was used to evaluate the biodegradability of various oils in water and soil media. The biodegradation of certain bio and mineral hydraulic oils was evaluated in groundwater, where bio oils usually biodegraded more effectively than mineral oils. The use of oils in machines weakened especially the biodegradability of bio oils. Biodegradability of bio oils was also studied in standard conditions of OECD 301 F and bio oils usually biodegraded moderately good in these conditions. The biodegradation of forestry chain oils and wood preservative oils was evaluated in forest soils. Linseed oil biodegraded moderately, but certain experimental wood preservatives biodegraded more effectively. Widely used creosote oil biodegraded in a lesser degree. Rapeseed oil-based chain oils biodegraded more effectively than corresponding tall oil. (orig.)

Migration of mineral oil from party plates of recycled paperboard into foods: 1. Is recycled paperboard fit for the purpose? 2. Adequate testing procedure.

Science.gov (United States)

Dima, Giovanna; Verzera, Antonella; Grob, Koni

2011-11-01

Party plates made of recycled paperboard with a polyolefin film on the food contact surface (more often polypropylene than polyethylene) were tested for migration of mineral oil into various foods applying reasonable worst case conditions. The worst case was identified as a slice of fried meat placed onto the plate while hot and allowed to cool for 1 h. As it caused the acceptable daily intake (ADI) specified by the Joint FAO/WHO Expert Committee on Food Additives (JECFA) to be exceeded, it is concluded that recycled paperboard is generally acceptable for party plates only when separated from the food by a functional barrier. Migration data obtained with oil as simulant at 70°C was compared to the migration into foods. A contact time of 30 min was found to reasonably cover the worst case determined in food.

Simulating oil droplet dispersal from the Deepwater Horizon spill with a Lagrangian approach

Science.gov (United States)

North, Elizabeth W.; Schlag, Zachary; Adams, E. Eric; Sherwood, Christopher R.; He, Ruoying; Hyun, Hoon; Socolofsky, Scott A.

2011-01-01

An analytical multiphase plume model, combined with time-varying flow and hydrographic fields generated by the 3-D South Atlantic Bight and Gulf of Mexico model (SABGOM) hydrodynamic model, were used as input to a Lagrangian transport model (LTRANS), to simulate transport of oil droplets dispersed at depth from the recent Deepwater Horizon MC 252 oil spill. The plume model predicts a stratification-dominated near field, in which small oil droplets detrain from the central plume containing faster rising large oil droplets and gas bubbles and become trapped by density stratification. Simulated intrusion (trap) heights of ∼ 310–370 m agree well with the midrange of conductivity-temperature-depth observations, though the simulated variation in trap height was lower than observed, presumably in part due to unresolved variability in source composition (percentage oil versus gas) and location (multiple leaks during first half of spill). Simulated droplet trajectories by the SABGOM-LTRANS modeling system showed that droplets with diameters between 10 and 50 μm formed a distinct subsurface plume, which was transported horizontally and remained in the subsurface for >1 month. In contrast, droplets with diameters ≥90 μm rose rapidly to the surface. Simulated trajectories of droplets ≤50 μm in diameter were found to be consistent with field observations of a southwest-tending subsurface plume in late June 2010 reported by Camilli et al. [2010]. Model results suggest that the subsurface plume looped around to the east, with potential subsurface oil transport to the northeast and southeast. Ongoing work is focusing on adding degradation processes to the model to constrain droplet dispersal.

Studies on the lipophilicity of vehicles (or co-vehicles) and botanical oils used in cosmetic products.

Science.gov (United States)

Mbah, C J

2007-05-01

The lipophilic character of five vehicles (or co-vehicles): diethylhexylmaleate, dimethicone, light mineral oil, octyldodecanol and oleyl alcohol and eight botanical oils: Aloe vera oil, coconut oil, extra virgin olive oil, grape leaf oil, grape seed oil, hazelnut oil, jojoba oil and safflower oil was determined by partitioning esters of p-hydroxybenzoic acid (parabens) between them and phosphate buffer (pH 7.4). The results were compared to those obtained with 1-octanol. The most lipophilic effects were observed with octyldodecanol and oleyl alcohol for the vehicles (or co-vehicles), coconut oil, jojoba oil and safflower oil for botanical oils. Light mineral oil showed the least lipophilic effect. With butylparaben, it was observed that oleyl alcohol, octyldodecanol, coconut oil and jojoba oil were 0.94, 0.91, 0.74 and 0.68 times as lipophilic as 1-octanol respectively. The study indicates that octyldodecanol and oleyl alcohol could be good substitutes for 1-octanol in partition coefficient determination. The estimated permeability coefficients of the parabens suggest that octyldodecanol, oleyl alcohol, coconut oil and jojoba oil could be potential dermal permeation enhancers.

Effects of oil transferred from incubating gulls to their eggs

Science.gov (United States)

King, K.A.; LeFever, C.A.

1979-01-01

No. 2 fuel oil, or water, was applied to the breast feathers of incubating laughing gulls trapped at their nest site on an island colony in Texas. Gulls were released after treatment and allowed to incubate their eggs for 5 days. Oil was transferred from the feathers of incubating adults to their eggs and resulted in 41% embryo mortality compared with 2% in controls.

Possibilities of substituting mineral oil products in the Land Baden-Wuerttemberg

International Nuclear Information System (INIS)

Dolinski, U.; Labahn, K.D.

1979-10-01

The target given in the energy programme of Baden-Wuerttemberg in the year 1975, to lower the share of mineral oil products in this Federal State to less than 50%, can be realized. As a consequence of the structure of heating plants in industry as well as in households and, for other consumers and power plants, 5.7 million t coal equivalents of petroleum are to be substituted within one year. Thus the share of petroleum - compared to the values estimated in the status-quo prognosis - would be lowered to even less than 45%. The energy sources required for substitution are mainly available in the form of the energy sources natural gas and pit-coal, and, in the long term, in the form of 'new energy sources'. But since the prices of energy sources finally decide whether the consumers are prepared for substituting their petroleum or not in a competitive economic system, and the price relations among the energy sources are not likely to change - even if there are further price increases - the realization of the objective can hardly be expected without supporting measures from energy policy. The investigation showed that the most efficient measures would be also the most dirigistic ones, however, they cannot be recommended from the point of view of a policy of order. At last there are - apart from the enlightenment - the monetary measures which are able to change the corner data of the competitive situation among the energy sources with the desired substitution effect, but which do not affect the individual freedom of decision. (orig./UA) [de

Effects of oxide traps, interface traps, and ''border traps'' on metal-oxide-semiconductor devices

International Nuclear Information System (INIS)

Fleetwood, D.M.; Winokur, P.S.; Reber, R.A. Jr.; Meisenheimer, T.L.; Schwank, J.R.; Shaneyfelt, M.R.; Riewe, L.C.

1993-01-01

We have identified several features of the 1/f noise and radiation response of metal-oxide-semiconductor (MOS) devices that are difficult to explain with standard defect models. To address this issue, and in response to ambiguities in the literature, we have developed a revised nomenclature for defects in MOS devices that clearly distinguishes the language used to describe the physical location of defects from that used to describe their electrical response. In this nomenclature, ''oxide traps'' are simply defects in the SiO 2 layer of the MOS structure, and ''interface traps'' are defects at the Si/SiO 2 interface. Nothing is presumed about how either type of defect communicates with the underlying Si. Electrically, ''fixed states'' are defined as trap levels that do not communicate with the Si on the time scale of the measurements, but ''switching states'' can exchange charge with the Si. Fixed states presumably are oxide traps in most types of measurements, but switching states can either be interface traps or near-interfacial oxide traps that can communicate with the Si, i.e., ''border traps'' [D. M. Fleetwood, IEEE Trans. Nucl. Sci. NS-39, 269 (1992)]. The effective density of border traps depends on the time scale and bias conditions of the measurements. We show the revised nomenclature can provide focus to discussions of the buildup and annealing of radiation-induced charge in non-radiation-hardened MOS transistors, and to changes in the 1/f noise of MOS devices through irradiation and elevated-temperature annealing

Influence of copper on the by-products of different oil-paper insulations

International Nuclear Information System (INIS)

Hao Jian; Liao Ruijin; Chen, George; Ma Chao

2011-01-01

Transformer failure caused by the corrosion of copper material in transformer attracts great attention of researchers and engineers. In this paper, Karamay No. 25 naphthenic mineral oil, Karamay No. 25 paraffinic mineral oil, Kraft paper and copper were used to compose four combinations of oil-paper insulation samples. The ageing by-products and dielectric properties of the four combinations of oil-paper insulation samples were compared after they were thermally aged at 130 deg. C. The influence of copper on the by-products and dielectric properties of different oil-paper insulations was obtained. The results show that copper can accelerate the ageing rate of insulation oils and reduce their AC breakdown voltage. The content of copper substance dissolved in insulating oil increases with ageing time at first and then decreases. The paper aged in the oil-paper insulation sample with copper has higher moisture content than the one without copper. Results of energy dispersive spectroscopy (EDS) in the scanning electron microscope (SEM) show that there is copper product deposited on the surface of insulation paper. The insulation oil and paper aged in the oil-paper insulation sample with copper have higher dielectric loss and conductivity than that without copper.

Influence of copper on the by-products of different oil-paper insulations

Energy Technology Data Exchange (ETDEWEB)

Hao Jian; Liao Ruijin [State Key Laboratory of Power Transmission Equipment and System Security and New Technology, Chongqing University (China); Chen, George [School of Electronics and Computer Science, University of Southampton (United Kingdom); Ma Chao, E-mail: cquhaojian@126.com [Gansu Electric Power Research Institute (China)

2011-08-12

Transformer failure caused by the corrosion of copper material in transformer attracts great attention of researchers and engineers. In this paper, Karamay No. 25 naphthenic mineral oil, Karamay No. 25 paraffinic mineral oil, Kraft paper and copper were used to compose four combinations of oil-paper insulation samples. The ageing by-products and dielectric properties of the four combinations of oil-paper insulation samples were compared after they were thermally aged at 130 deg. C. The influence of copper on the by-products and dielectric properties of different oil-paper insulations was obtained. The results show that copper can accelerate the ageing rate of insulation oils and reduce their AC breakdown voltage. The content of copper substance dissolved in insulating oil increases with ageing time at first and then decreases. The paper aged in the oil-paper insulation sample with copper has higher moisture content than the one without copper. Results of energy dispersive spectroscopy (EDS) in the scanning electron microscope (SEM) show that there is copper product deposited on the surface of insulation paper. The insulation oil and paper aged in the oil-paper insulation sample with copper have higher dielectric loss and conductivity than that without copper.

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