Nicola Cabibbo (1935-2010)

CERN Multimedia

2010-01-01

  Nicola Cabibbo, one of the most important theoretical physicists of our time, died of cancer in Rome on 16 August, 2010 at the age of 75.   Copyright Massimo Silvano, ICTP Photo Archives. Before the discovery of quarks, he gave the correct formulation of the weak current couplings that in modern terms corresponds to the phenomenon of quark mixing. His formulation, in terms of the famous Cabibbo angle, was later extended to three families of fermions (and more recently also applied to neutrino mixing), and plays an essential role in the Standard Model of fundamental interactions. Over the years he applied his extremely lucid, deep and flexible mind to a wide range of problems, also including experiments, such as the measurement in 1963 of the electron helicity in muon decay, and the conception and design of the parallel computers APE, which he developed, starting in the early 1980s, for the simulation of the QCD theory of the strong interactions on discrete space-time. Highly respect...

[The anatomy Lesson of Dr. Nicolaes Tulp: The beginning of a medical utopia].

Science.gov (United States)

Rosler, Roberto; Young, Pablo

2011-04-01

The Anatomy Lesson of Dr. Nicolaes Tulp was painted by Rembrandt Harmen-szoon van Rijn at the early age of 26 years. In the XVII century these paintings were very popular in the Netherlands, and in this country the cities flourished as cultural centers searching the anatomy knowledge. Nicolaes Tulp was one of the persons in the center of Amsterdam's scene during XVII century. In 1632 Tulp was 39 years old, and he was an anatomist and a surgeon. Rembrandt masterly shows an autopsy performed by Dr. Tulp. This picture is the description of the beginning of a medical intellectual utopia: the absolute visibility of the disease. Unfortunately this utopia is blind to the complete visibility of the psycho-socio-cultural dimensions of the ill.

Jounin Nicolas, Chantier interdit au public

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Williams Nuytens

2011-09-01

Full Text Available Le travail de Nicolas Jounin s’appuie sur des enquêtes de terrain réalisées dans la première moitié des années 2000, en France, dans le monde du bâtiment, sur des chantiers et autour de ceux-ci. Il paraît pour la première fois en 2008 et se présente comme un récit d’observations participantes (tandis que l’auteur aura usé d’autres techniques de recherche au cours de sa thèse de doctorat. Cette option de publier essentiellement une version dynamique du terrain, qui se retrouve dans six des hu...

Spatial analysis of noise emission at the Los Azufres geothermal field, Mich.; Analisis espacial de emision de ruido en el campo geotermico de Los Azufres, Mich.

Energy Technology Data Exchange (ETDEWEB)

Camarena Magana, Emilio; Ordaz Mendez, Christian A. [Comision Federal de Electricidad, Residencia de Los Azufres, Morelia, Michoacan (Mexico)]. E-mail: emilio.camarena@cfe.gob.mx

2010-01-15

To verify noise emissions from the usual activities in an operating geothermal field, noise measurements were carried out in a 4.2 km{sup 2} area in the southern zone of the Los Azufres, Mich., geothermal field. There are seven production wells operating here and three abandoned wells. The average noise emission in the southern zone was 36.5 decibels (dB), regarded as the natural reading of environmental-noise emission. In the Christmas (valves) tree for operating production wells, the noise ranges from 70.9 to 91.7 dB, while in open discharging valves for steam-pipes, the noise can reach 118 dB. In Mexico the maximum permissible limit of noise on the periphery of a property is 68 dB in daytime and 65 dB at night. Based on measurements made at the periphery of lots where the geothermal wells are located, four out of seven production wells measured do not exceed the maximum allowable level, while the other three seem to exceed it. However no definite limits exist for the lots. It is recommended that the measurement points as indicated by the official standard in environmental matters be re-established, which will enable noise emissions by several wells that have exceeded the permissible limit, to actually fall within it. [Spanish] Se realizaron mediciones sonicas en un area de 4.2 km{sup 2} localizada en la zona sur del campo geotermico de Los Azufres, Mich., a fin de verificar la emision de ruido asociada a las actividades usuales en un campo geotermico en operacion. En esta area se encuentran siete pozos productores en operacion y tres pozos abandonados. La emision promedio de ruido en estos ultimos fue de 36.5 decibeles (dB), considerandose como la condicion natural de emision de ruido ambiental. En el arbol de valvulas de los pozos productores en operacion el ruido va de los 70.9 a los 91.7 dB, mientras que en valvulas abiertas de descarga de vaporductos la emision puede llegar hasta los 118 dB. En Mexico el limite maximo permisible de ruido en la periferia de

Persuasion: Nicolas Pineau's Designs on the Social

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Scott, Katie

2014-03-01

Full Text Available This essay offers a Latourian account of the wood sculptor Nicolas Pineau's design process via a reading of Jean-François Bastide's novella La petite maison. It argues that the conventional form assumed by his drawings or 'inscriptions' – the indications of scale, the delineation of options, the signatures and marginal notes – can be read as traces of seduction that helped 'translate' potential patrons to a taste for Rococo. The essay further suggests that the activation of the taste at the point of commission was kept alive in the designs executed by the bi-modal asymmetry that is characteristic of the goût pittoresque because its exercise was considered a mark of refinement.

Nicolas Guichon, Langues et TICE. Méthodologie de conception multimédia

OpenAIRE

Frost, Dan

2014-01-01

Nicolas Guichon est enseignant-chercheur en anglais et en didactique des langues au centre de langues de l’université Lumière (Lyon 2). Il est concepteur du logiciel Virtual Cabinet, responsable de l’enseignement TICE du master « Didactique des langues et TICE » et membre de l’équipe Plurilinguisme et multimédia (ENS de Lyon). Cet ouvrage est le fruit de son expérience dans le domaine des recherches, du développement et de l’enseignement dans l’univers des TICE et de l’apprentissage des langu...

The anatomy lesson of Dr. Nicolaes Tulp by Rembrandt : A comparison of the painting with a dissected left forearm of a Dutch male cadaver

NARCIS (Netherlands)

Ijpma, Frank F. A.; van de Graaf, Robert C.; Nicolai, Jean-Philippe A.; Meek, Marcel F.

2006-01-01

Rembrandt's The Anatomy Lesson of Dr. Nicolaes Tulp (1632) is considered a masterpiece and is a group portrait of the Amsterdam Guild of Surgeons in the form of an anatomy lesson. Dr. Nicolaes Tulp, Doctor of Medicine and Praelector Anatomiae to the Amsterdam Guild of Surgeons, showed an anatomic

Nicolae Milescu Spătarul - ancestor of a Nobel Laureate - Ilia I. Mecinikov. Part I. Nicolae Milescu-Spătarul’s secular European impact; 1st of June 2011 - 375 years since the birth of the European erudite

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Dan RIGA

2011-01-01

Full Text Available The culture of tradition and patrimony is an act of civilization, as well as one of identitaryeducation. This is why the promotion of restitution comprises all areas of progress and humancreation.Nicolae Milescu-Spătarul (b. 1636 in Moldavia - d. 1708 in Russia was an eruditehumanist scholar, an encyclopaedist, a theologist, diplomat, historian, geographer, ethnographer,translator, memorialist and a polyglot (Romanian, ancient and modern Greek, Latin, Turkish andSlavonic-Russian. Commemorating and honouring this figure, of European and Eurasianimportance alike, is a debt of honour: 1958 – 250 years since death; 2011 – 375 years since birth.At this time, the need to fully publish his work arises, as a large part of it is still kept in libraries,archives and European private collections in the form of manuscripts. Nicolae Milescu-Spătarulwas the ancestor of the Nobel Laureate (1908, scientist Ilia I. Mecinikov (1845-1916.The work reveals the great scholar’s (eastern, but also western, European and Asiancultural, scientific and diplomatic impact – at that moment and throughout time – but also theSorin Riga, Dan Riga, Vasile Man - Nicolae Milescu Spătarul - ancestor of a Nobel Laureate - Ilia I. Mecinikov impact of his vast work. The remarkable monograph The Description of China (58 chapters was published in Romanian only in 1958.

Nicolae Ceausescu and Santiago Carrillo. On the reform of proletarian internationalism

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Cezar Stanciu

2014-11-01

Full Text Available This article analyzes the close relations developed between the Romanian and Spanish Communist parties in the context of the Soviet-led intervention in Czechoslovakia. It explores the similarities and differences between the visions of Nicolae Ceaușescu and Santiago Carrillo on the reform of the world Communist movement and also the new meaning attributed by both to proletarian internationalism. Drawing on transcripts of their conversations in crucial political moments, the article reveals how Eastern and Western Communists found ways to work together in order to undermine Soviet control over world Communism.

Nicola Cafés capsules compatible with Nespresso machines : risky marketing decision

OpenAIRE

Dotti, João Baptista Geraldes Barba

2015-01-01

The demanding and traditional coffee market in Portugal is changing in some of its main components. Consumers, limited financially by the economic crisis, and taking advantage of the growth of coffee machines with capsules, drink more coffee at home, reducing consumption in establishments such as bars, restaurants and pastry shops. The Nutricafés S.A. is the third player of the coffee market in Portugal, and through its main brand, Nicola Cafés will have to choose between two marketing strate...

Ajaloolased ja teised. Ajaloolaste rollist Prantsusmaa avalikes aruteludes / Gérard Noiriel, Nicolas Offenstadt ; prantsuse keelest tõlkinud Indrek Koff

Index Scriptorium Estoniae

Noiriel, Gérard

2007-01-01

Ajaloo avalikust kasutamisest. Artikli aluseks on Nicolas Offenstadti ettekanne TLÜ Eesti Humanitaarinstituudi ja Prantsuse Kultuurikeskuse korraldatud rahvusvahelisel konverentsil "Ajalugu ja poliitika. Mineviku kasutamisest ja ärakasutamisest" 14. oktoobril 2006 Tallinnas.

Aspects of 17th century Binding Medium: inclusions in Rembrandt’s Anatomy Lesson of Dr Nicolaes Tulp

DEFF Research Database (Denmark)

Noble, Petria; Wadum, Jørgen; Groen, Karin

2000-01-01

During the recent restoration of Rembrandt's Anatomy Lesson of Dr. Nicolaes Tulp minuscule crater-like holes, which cover the surface of the painting, were studied. Whitish material within the holes was identified as lead chloride hydroxide and a variety of lead soaps. These inclusions, which...

Sea-level history during the Last Interglacial complex on San Nicolas Island, California: implications for glacial isostatic adjustment processes, paleozoogeography and tectonics

Science.gov (United States)

Muhs, Daniel R.; Simmons, Kathleen R.; Schumann, R. Randall; Groves, Lindsey T.; Mitrovica, Jerry X.; Laurel, Deanna

2012-01-01

San Nicolas Island, California has one of the best records of fossiliferous Quaternary marine terraces in North America, with at least fourteen terraces rising to an elevation of ~270 m above present-day sea level. In our studies of the lowest terraces, we identified platforms at 38-36 m (terrace 2a), 33-28 m (terrace 2b), and 13-8 m (terrace 1). Uranium-series dating of solitary corals from these terraces yields three clusters of ages: ~120 ka on terrace 2a (marine isotope stage [MIS] 5.5), ~120 and ~100 ka on terrace 2b (MIS 5.5 and 5.3), and ~80 ka (MIS 5.1) on terrace 1. We conclude that corals on terrace 2b that date to ~120 ka were reworked from a formerly broader terrace 2a during the ~100 ka sea stand. Fossil faunas differ on the three terraces. Isolated fragments of terrace 2a have a fauna similar to that of modern waters surrounding San Nicolas Island. A mix of extralimital southern and extralimital northern species is found on terrace 2b, and extralimital northern species are on terrace 1. On terrace 2b, with its mixed faunas, extralimital southern species, indicating warmer than present waters, are interpreted to be from the ~120 ka high sea stand, reworked from terrace 2a. The extralimital northern species on terrace 2b, indicating cooler than present waters, are interpreted to be from the ~100 ka sea stand. The abundant extralimital northern species on terrace 1 indicate cooler than present waters at ~80 ka. Using the highest elevations of the ~120 ka platform of terrace 2a, and assuming a paleo-sea level of +6 m based on previous studies, San Nicolas Island has experienced late Quaternary uplift rates of ~0.25-0.27 m/ka. These uplift rates, along with shoreline angle elevations and ages of terrace 2b (~100 ka) and terrace 1 (~80 ka) yield relative (local) paleo-sea level elevations of +2 to +6 m for the ~100 ka sea stand and -11 to -12 m for the ~80 ka sea stand. These estimates are significantly higher than those reported for the ~100 ka and ~80 ka

'Mercator Sapiens' (De Wijze Koopman). Het wereldwijde onderzoek van Nicolaes Witsen (1641-1717), burgemeester en VOC-bewindhebber van Amsterdam

NARCIS (Netherlands)

Peters, Marion Hélène

2008-01-01

De waardigheid van een regent omvatte de verplichting om als magistraat voor het publieke welzijn verantwoordelijk te zijn. De Amsterdamse burgemeester Nicolaes Witsen (16411717) heeft deze opdracht serieus genomen. Vrijwel alle tijd die hem naast zijn bestuursfuncties restte, besteedde hij aan

Condensers for measuring steam quality at the inlet of back-pressure units of the Los Azufres, Mich., geothermal field; Condensadores para medir la calidad del vapor a la entrada de las turbinas a contrapresion del campo geotermico de Los Azufres, Mich.

Energy Technology Data Exchange (ETDEWEB)

Sandoval Medina, Fernando; Gonzalez Gonzalez, Rubi; Reyes Delgado, Lisette; Medina Martinez, Moises [Comision Federal de Electricidad, Gerencia de Proyectos Geotermoelectricos, Residencia de Los Azufres (Mexico)]. E-mail: fernando.sandoval@cfe.gob.mx

2007-01-15

Electrical conductivity is an indirect measurement of the quality of the steam supplied to power units. In the Los Azufres, Mich., geothermal field, the electrical conductivity once was measured in a discrete and periodic way by condensing steam samples through a water-cooled condenser. In an attempt to continuously measure conductivity, conductivity meters were installed where the units discharged, but the values proved unstable and unrepresentative. Thereafter, taking into account that steam quality should be measured at the steam delivery-reception point, equipment was designed and tested for continuously condensing steam. Finally it was possible to get an air-cooled condenser able to condense 500 milliliters per minute, enough to collect a representative flow of the steam and to measure its electrical conductivity. The equipment was installed in all seven back-pressure units operating in the field and to date has been operating in an optimal manner. [Spanish] La conductividad electrica es una medida indirecta de la calidad del vapor que se suministra a las unidades turbogeneradoras. En el campo geotermico de Los Azufres, Mich., la conductividad electrica se media en forma puntual y periodica, condensando muestras de vapor por medio de un serpentin enfriado con agua. Despues, ante la necesidad de medirla en forma continua, se instalaron conductivimetros en las descargas de las unidades, pero los valores resultaron muy inestables y poco representativos. Considerando, ademas, que la calidad del vapor debe medirse en el punto de entrega-recepcion, se disenaron y probaron equipos para condensar vapor de manera continua, lograndose construir un condensador enfriado por aire que logra condensar un flujo de 500 mililitros por minuto, cantidad suficiente para tener un flujo representativo del vapor que alimenta a las turbinas y medirle su conductividad electrica. Se instalaron estos equipos en las siete unidades turbogeneradoras a contrapresion que funcionan en el campo

An outstanding researcher of the solar eclipses- Nicolas Donitch

Science.gov (United States)

Gaina, Alex

1998-09-01

Nicolae Donitch (1874, Chisinau-1958, Nice, France?) worked in Russia (until 1917), Romania (1918-1944) and France (1945-1958?). His observatory was placed in Dubossary-Vechi (where he worked with some intervals between 1908 and 1944. He was designated by the Russian Academy of Sciences for the observations of the total Solar eclipse in Elche (Spain) on 28 May 1900. Other solar eclipses observed by N. Donitch: 17-18 may 1901, Padong (Sumatra); 1904 - the annular eclipse of the Sun in Pnom-Penh (Cambodge); august 1905, Alcala de Chisvert (Spain) and Assuan (Upper Egypt); 16/17 April 1912, Portugal; 21 august 1914, Crimea; 1925, USA; 1929 Indochina and Philipines; 1930, Egypt; 1932 Egypt and cape Porpoise,Maine USA; 1936, Inneboli, Turkey. Other solar investigations by N. Donitch; Solar cromosphere (Odessa, 1902; Mount- Blanch, 1902-1903); The passage of the planet Mercury through the solar disk (November, 1907, Egypt; October 1914, Algeria).

Relações entre a câmara de Neubauer a espectrofotometria utilizadas para a determinação da concentração espermática de catetos (Pecari tajacu

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Andréia Maria da Silva

2014-01-01

Full Text Available Em ejaculados provenientes de 28 catetos, verificou-se a existência de relações entre a concentração espermática determinada por meio da câmara de Neubauer e a tramitância observada por espectrofotometria, utilizando comprimentos de onda variando de 530 a 590nm. Os ejaculados apresentaram uma concentração média de 283,9±30,8x106 espermatozoides mL-1, com variação de 30 a 640x106 espermatozoides mL-1. Os valores para tramitância variaram entre 36,9 a 96,3, nos diferentes comprimentos de onda. Não foram detectadas relações significativas entre os dois métodos (P>0,05. Dessa forma, não se recomenda a espectrofotometria para os procedimentos de rotina na determinação da concentração espermática em catetos.

Isotope dates and strontium isotopic ratios for plutonic and volcanic rocks in the Quesnel Trough and Nicola Belt, south central British Columbia

International Nuclear Information System (INIS)

Preto, V.A.; McMillan, W.J.; Armstrong, R.L.

1979-01-01

Four distinct events of the southern Intermontane Belt are represented in new K-Ar and Rb-Sr dates. The first and regionally most important event is sharply defined by new K-Ar dates between 200 and 209 Ma for the Thuya, Wildhorse, Iron Mask, and Allison batholiths and a 205 +- 10 Ma Rb-Sr isochron for the Guichon Creek batholith. All these plutons were emplaced approximately at the change from Triassic to Jurassic time. The related and slightly older Nicola volcanic rocks are altered by addition of more radiogenic sedimentary Sr (Carnian Nicola limestone having 87 Sr/ 86 Sr=0.7075+- 1) and do not give an isochron date. The Coldwater stock is anomalously old (K-Ar dates range from 215-267 Ma). The Mid- to late Jurassic igneous event is indicated by a 141 Ma K-Ar date for the Mount Martley batholith. Mid-Cretaceous volcanic rocks of the Kingsvale Group give a Rb-Sr isochron date of 112 +- 10 Ma and are postdated by the crosscutting and slightly younger Summers Creek stock (100 Ma by K-Ar). The final event straddles the Cretaceous-Tertiary boundary with the Nicola batholith emplaced about 60 Ma ago (K-Ar) and the Rey Lake stock perhaps slightly earlier (69 Ma by K-Ar). Initial 87 Sr/ 86 Sr ratios range from 0.7025-0.7046 with a mean and mode near 0.7037 which is within the range of modern circum-Pacific volcanoes. Initial ratios of 0.7034 +- 1 for the Guichon Creek batholith, 0.7035 +- 1 for the Iron Mask batholith 70435 +-10 for the Thuya batholith, and 0.70379 +- 4 for the Kingsvale volcanic rocks are the most precisely determined. The Coldwater stock is anomalously low at 0.7025. For the other plutonic bodies only scattered or single analyses are available. The Nicola volcanic rocks appear to have once been similar in initial ratio the the Guichon Creek batholith but their calculated initial ratios now scatter from 0.7034-0.7073. (auth)

A multi-decade time series of kelp forest community structure at San Nicolas Island, California

Science.gov (United States)

Lafferty, Kevin D.; Kenner, Michael C.; Estes, James A.; Tinker, M. Tim; Bodkin, James L.; Cowen, Robert K.; Harrold, Christopher; Novak, Mark; Rassweiler, Andrew; Reed, Daniel C.

2013-01-01

San Nicolas Island is surrounded by broad areas of shallow subtidal habitat, characterized by dynamic kelp forest communities that undergo dramatic and abrupt shifts in community composition. Although these reefs are fished, the physical isolation of the island means that they receive less impact from human activities than most reefs in Southern California, making San Nicolas an ideal place to evaluate alternative theories about the dynamics of these communities. Here we present monitoring data from seven sampling stations surrounding the island, including data on fish, invertebrate, and algal abundance. These data are unusual among subtidal monitoring data sets in that they combine relatively frequent sampling (twice per year) with an exceptionally long time series (since 1980). Other outstanding qualities of the data set are the high taxonomic resolution captured and the monitoring of permanent quadrats and swaths where the history of the community structure at specific locations has been recorded through time. Finally, the data span a period that includes two of the strongest ENSO events on record, a major shift in the Pacific decadal oscillation, and the reintroduction of sea otters to the island in 1987 after at least 150 years of absence. These events provide opportunities to evaluate the effects of bottom-up forcing, top-down control, and physical disturbance on shallow rocky reef communities.

Magnetoelectric effect in Cr2O3 thin films

Science.gov (United States)

He, Xi; Wang, Yi; Sahoo, Sarbeswar; Binek, Christian

2008-03-01

Magnetoelectric materials experienced a recent revival as promising components of novel spintronic devices [1, 2, 3]. Since the magnetoelectric (ME) effect is relativistically small in traditional antiferromagnetic compounds like Cr2O3 (max. αzz 4ps/m ) and also cross- coupling between ferroic order parameters is typically small in the modern multiferroics, it is a challenge to electrically induce sufficient magnetization required for the envisioned device applications. A straightforward approach is to increase the electric field at constant voltage by reducing the thickness of the ME material to thin films of a few nm. Since magnetism is known to be affected by geometrical confinement thickness dependence of the ME effect in thin film Cr2O3 is expected. We grow (111) textured Cr2O3 films with various thicknesses below 500 nm and study the ME effect for various ME annealing conditions as a function of temperature with the help of Kerr-magnetometry. [1] P. Borisov et al. Phys. Rev. Lett. 94, 117203 (2005). [2] Ch. Binek, B.Doudin, J. Phys. Condens. Matter 17, L39 (2005). [3] R. Ramesh and Nicola A. Spaldin 2007 Nature Materials 6 21.

The anatomy lesson of Dr. Nicolaes Tulp by Rembrandt (1632): a comparison of the painting with a dissected left forearm of a Dutch male cadaver.

Science.gov (United States)

IJpma, Frank F A; van de Graaf, Robert C; Nicolai, Jean-Philippe A; Meek, Marcel F

2006-01-01

Rembrandt's The Anatomy Lesson of Dr. Nicolaes Tulp (1632) is considered a masterpiece and is a group portrait of the Amsterdam Guild of Surgeons in the form of an anatomy lesson. Dr. Nicolaes Tulp, Doctor of Medicine and Praelector Anatomiae to the Amsterdam Guild of Surgeons, showed an anatomic dissection of a forearm on the corpse of an executed criminal. The anatomic accuracy in Rembrandt's famous painting has been discussed in the literature for decades without any general consensus. In 2006, on the 400th anniversary of Rembrandt's birth, a forearm dissection of a cadaver and a comparison with the anatomy in the painting are presented to analyze the anatomic accuracy of Rembrandt's famous painting.

Haunting the Text: Nicola Pierce’s Spirit of the Titanic and Irish Historical Children’s Fiction

OpenAIRE

Beyer, Charlotte

2015-01-01

My article explores representations of Irish identity, history, and trauma in the Irish writer Nicola Pierce’s contemporary children’s novel, Spirit of the Titanic (2011). I examine the representation of Irish society and culture around the time of the construction of the Titanic,\\ud with a particular emphasis on the portrayal of marginalised individuals and groups. My article analyses the representation of history and the portrayal of trauma and affective ties, and concludes that Spirit of t...

The Matrix Regained: Reflections on the Use of the Grid in the Architectural Theories of Nicolaus Goldmann and Jean-Nicolas-Louis Durand

NARCIS (Netherlands)

Goudeau, J.J.W.

2015-01-01

In addition to the superficial visual similarities between the architectural theories of the Silesian-born, seventeenth-century Dutch mathematician Nicolaus Goldmann and the early nineteenth-century French architect Jean-Nicolas-Louis Durand, there is a more profound interconnection: their use of

Molecular Taxonomical Re-classification of the Genus Suillus Micheli ex S. F. Gray in South Korea.

Science.gov (United States)

Min, Young Ju; Park, Myung Soo; Fong, Jonathan J; Seok, Soon Ja; Han, Sang-Kuk; Lim, Young Woon

2014-09-01

The fungal genus Suillus Micheli ex S. F. Gray plays important roles in the survival and growth of plant seedlings. Humans have utilized these ectomycorrhizal fungi to enhance the nutrient uptake and defense systems of plants, particularly in the reforestation of coniferous forests. The genus Suillus is easily distinguishable by its distinctive morphological features, although the morphology of the fruiting body does not facilitate reliable interspecies discrimination. On the basis of micro-morphological features and internal transcribed spacer sequence analysis, we found that 51 of 117 Korean Suillus specimens had initially been misidentified. The list of the 12 Suillus species previously recorded in Korea was re-evaluated and revised to only eight distinct species: S. americanus, S. bovinus, S. granulatus, S. grevillei, S. luteus, S. pictus, S. placidus, and S. viscidus. We provide taxonomical descriptions for six of these species from the sample specimens.

Peter Paul Rubens, Nicolas-Claude Fabri de Peiresc and Joan of Arc

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Borusowski Piotr

2015-11-01

Full Text Available In 2011 a discovery was made at the Department of Prints and Drawings of the National Museum in Warsaw - a drawing hitherto described as a Kneeling knight by an anonymous seventeenth-century artist, turned out to be Joan of Arc, a sketch well-known to art historians studying the oeuvre of Peter Paul Rubens, although thought to be lost during the Second World War. The drawing, until now known only through the black and white photograph, could be thoroughly analysed for the first time. In the context of information thus obtained, the historical context of creating the sketch transpired as an equally important matter, including the hypothetical role that may have been played in its creation by Nicolas-Claude Fabri de Peiresc.

Neubauer's plantlet method - an alternative procedure for evaluating the effectiveness of potassium based fertilizers in reducing radiocaesium from soil to plant

International Nuclear Information System (INIS)

Mocanu, N.; Cotarlea, M.; Boldor, O.

1996-01-01

Accidental releases of radiocaesium into the environment have necessitated the search for effective soil-based countermeasures to reduce its transfer along food-chains. As field experiments can be impractical and protracted to predict rapidly the effectiveness of chemical treatments of radioactive contaminated soils to reduce soil-to-plant transfer of radionuclides, laboratory experiments are a suitable alternative for rapid evaluation of the most appropriate countermeasure to apply under a range of different circumstances in the event of accidental radioactive contamination of agricultural lands. Taking into account these considerations our study focuses on the use of a laboratory experiment based on Neubauer's plantlet method to evaluate the effectiveness of potassic salt 30 % applied on two soil types (alluvial and brown-reddish forest type) contaminated with 137 Cs for reducing uptake of the radionuclide to wheat plants grown-up on these soils. The experimental results evidence diminished values for 137 Cs/K quotient in wheat plantlets grown-up on soils treated with potassic salt 30 %, compared to those registered for wheat plantlets grown-up on untreated soils. The diminished values of 137 Cs/K quotient result from the reduced uptake of 137 Cs to plantlets accompanied by the enhanced uptake of potassium. (author)

Nicolas Chevillard (XVIIe siècle : tableaux en Bourgogne et en Normandie

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Renaud Benoit-Cattin

2012-04-01

Full Text Available La vie et l'œuvre de Nicolas Chevillard, peintre de Mâcon (Saône-et-Loire sont fort mal documentées. Ce que l'on en sait tient en peu de lignes : il est taxé de 40 livres à Mâcon en 1660 et reçoit 33 livres de la ville "pour avoir fait, en grand volume, le portrait de Son Altesse Sérénissime Mons. Le Prince, gouverneur de Bourgogne, qui est joinct à ceux de ses prédécesseurs audit gouvernement, en la salle de l'hostel commun de la ville de Macon". On ignore ce qu'il est advenu de ce tableau,...

Determination and evaluation of the metals and metalloids in the Chapeu-de-couro (Echinodorus macrophyllus (Kunth) Micheli).

Science.gov (United States)

Barbosa, Uenderson Araujo; dos Santos, Ivanice Ferreira; dos Santos, Ana Maria Pinto; dos Santos, Debora Correia; da Costa, Grenivel Mota

2013-09-01

The Chapeu-de-couro (Echinodorus macrophyllus (Kunth) Micheli) is a native plant from Brazil, which has been mainly used in medicinal application being a potent antirheumatic and diuretic, in the production of soft drinks, and also in the ornamentation of aquariums. In this paper, the metals and metalloids for the leaves of chapeu-de-couro collected in the Paraguacu River from the city Cachoeira, Bahia State, Brazil, was determined and evaluated using multivariate analysis. The samples were digested using nitric acid and hydrogen peroxide and were analyzed using inductively coupled plasma mass spectrometry. The accuracy of the method was confirmed by analysis of a certified reference material of apple leaves, furnished by National Institute of Standard and Technology. The study involved 15 samples of the Paraguacu River. The results expressed as milligrams of element per kilogram of sample demonstrated that the concentration ranges varied: 1.39-5.27 for chromium, 44.85-165.39 for manganese, 0.55-0.84 for arsenic, 0.01-3.94 for antimony, and 0.18-0.31 for lead. The principal component analysis and hierarchical cluster analysis evidenced that the concentrations of the metals and metalloids varied according with the variations in the water of the Paraguacu.

Aspects of financial history in Romania. Reform and reformers. The financial tax reform accomplished BY Nicolae Titulescu

Directory of Open Access Journals (Sweden)

Ciobanu, R.

2012-01-01

Full Text Available This paper presents a brief history of the financial reform designed by Nicolae Titulescu at the beginning of the 1920’s. His tax reform law was formulated after thorough research of other European tax systems. He tried to implement it while he was Minister of Finance. Even though the law was adopted, it was never enacted. It met a certain amount of controversy in the Assembly of Deputies. The analysis made also tries to explain the cedular tax system.

Terrestrial and lacustrine gastropods from the Priabonian (upper Eocene) of the Sultanate of Oman.

Science.gov (United States)

Harzhauser, Mathias; Neubauer, Thomas A; Kadolsky, Dietrich; Pickford, Martin; Nordsieck, Hartmut

2016-01-01

Terrestrial and aquatic gastropods from the upper Eocene (Priabonian) Zalumah Formation in the Salalah region of the Sultanate of Oman are described. The assemblages reflect the composition of the continental mollusc fauna of the Palaeogene of Arabia, which, at that time, formed parts of the southeastern Tethys coast. Several similarities with European faunas are observed at the family level, but are rarer at the genus level. These similarities point to an Eocene (Priabonian) rather than to a Rupelian age, although the latter correlation cannot be entirely excluded. At the species level, the Omani assemblages lack any relations to coeval faunas. This suggests the possible presence of a distinct biogeographic province during the Palaeogene or may simply reflect the extremely sparse non-marine fossil record of the Eocene in the Tethys region. The occurrence of the genera Lanistes, Pila, and Gulella along with some pomatiids, probably related to extant genera, suggests that the modern African-Arabian continental faunas can be partly traced back to Eocene times and reflect very old autochthonous developments. In contrast, the diverse Vidaliellidae went extinct, and the morphologically comparable Neogene Achatinidae may have occupied the equivalent niches in extant environments. Carnevalea Harzhauser and Neubauer nov. gen., Arabiella Kadolsky, Harzhauser and Neubauer nov. gen., Pyrgulella Harzhauser, Kadolsky and Neubauer nov. gen., Salalahia Kadolsky, Harzhauser and Neubauer nov. gen., Omanitopsis Harzhauser and Neubauer nov. gen., Arabicolaria Harzhauser and Neubauer nov. gen., Pacaudiella Harzhauser and Neubauer nov. gen., Goniodomulus Harzhauser and Neubauer nov. gen., Eoquickia Harzhauser and Neubauer nov. gen., Omanillya H. Nordsieck nov. gen. and Omanifera H. Nordsieck nov. gen. are introduced as new genera. Pila neuberti Harzhauser and Neubauer nov. sp., Arabiella arabica Kadolsky, Harzhauser and Neubauer nov. sp., Pyrgulella parva Harzhauser, Kadolsky and

THE BAGATELLE GENRE AND ITS REALIZATION IN THE CREATION OF COMPOSER NICOLAE CIOLAC

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ANDRONOVICI-RUSU ADELA

2015-09-01

Full Text Available In the present paper there is an excursion into the history of the bagatelle genre. Initially conceived as a piece of minor importance, with a moderate instrumental-technical aspect that belongs to „easy” pieces for interpretation, the bagatelle dur­ing its evolution, obtained a status of an aphoristic musical genre in which a profound ideative content is essentially conveyed in a laconic, concentrated form. Further are analyzed five Bagatelles for piano written by composer Nicolae Ciolac. The author considers the thematic and architectural problems of the opus, as well as some speciic interpretative peculiarities. In conclu­sion it is affirmed that the analyzed bagatelles represent s group of pieces novel for Moldovan composition that has at its base a logic characteristic of the miniature genre.

Effect of the γ-radiation on phenol fractions obtained from the leaves of Echinodorus macrophyllus Mich

International Nuclear Information System (INIS)

Silva, T.M.; Dias, M.D.; Pereira, M.T.; Takahashi, J.A.; Ferraz, V.P.; Pilo-Veloso, D.; Alcantara, A.F.C.

2012-01-01

Echinodorus macrophyllus Mich. (Chapeu-de-couro) is popularly used as diuretic, anti-arrhythmic, anti-inflammatory, and anti-rheumatic agents. Leaves of this species are largely commercialized and show high level of microbiological contamination (bacteria and fungi). This work describes the effect of the 60 Co γ-radiation on the phenol fractions obtained from the leaves of E. macrophyllus. trans-Ferulic acid, (E)-caffeoyltartronic acid, 6-C-(1-hexitol)-apigenin, and 6-C-(1-hexitol)-luteolin were isolated by preparative HPLC. HPLC chromatograms showed concentration changes of some phenolic constituents, suggesting the formation of radiolytic products. The phenol fractions were active against Bacillus subitilis and Staphylococcus aureus and showed high antioxidant activity. However, the antibacterial and antioxidant activities reduced when the absorbed dose was increased. - Highlights: → Effects of the γ-radiation on the chemical constituents of the leaves of E. macrophyllus. → To determine the conditions, which are sufficient for microbiological decontamination. → Analysis by HPLC of the phenol fractions obtained from the leaves of E. macrophyllys. → Effects of the γ-radiation in the antioxidant and antimicrobial activities of E. macrophyllus.

Clinical features of multiple spontaneous intracerebral hemorrhages

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Tao CHANG

2016-01-01

Full Text Available Objective To analyze the clinical features of multiple spontaneous intracerebral hemorrhages (MICH. Methods Conservative therapy, puncture and drainage, hematoma removal and/or decompressive craniectomy were used in the treatment of 630 intracerebral hemorrhage (ICH patients, who were divided into 2 groups: 30 cases with MICH and another 600 cases with solitary intracerebral hemorrhage (SICH. Three months after onset, modified Rankin Scale (mRS was used to evaluate the prognosis of all cases. Results Compared with patients in SICH group, the occurrence rate of hypertension > 5 years (P = 0.008, diabetes mellitus (P = 0.024, hypercholesterolemia (P = 0.050 and previous ischemic stroke (P = 0.026 were all significantly higher in MICH group. The mean arterial pressure (MAP level (P = 0.002 and the incidence of limb movement disorder (P = 0.000 were significantly higher in patients with MICH than those with SICH. Basal ganglia and thalamus were the predilection sites of hematoma (P = 0.001. Patients with MICH had worse prognosis compared to those with SICH 3 months after onset (P = 0.006. Conclusions Hypertension > 5 years, diabetes mellitus, hypercholesterolemia and ischemic stroke were identified to be the pathophysiological basis of MICH in this study. All patients with MICH had more serious clinical manifestations after onset and worse prognosis. DOI: 10.3969/j.issn.1672-6731.2016.01.008

Descripción actual de la enfermedad de Durand, Nicolas y Favre

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Laurentino Muñoz

1950-04-01

Full Text Available En los últimos años la ciencia médica logra esclarecer el cuadro de la Enfermedad de Durand, Nicolas y Favre; confundida con las otras enfermedades venéreas y aun con la Tuberculosis en épocas que se van alejando, somos dueños ahora no solo de la enseñanza clínica, de medios de diagnostico y terapéuticos, para apreciar y combatir la primitiva lesión y sus complicaciones, sino que el cuadro de la enfermedad se ensancha y adquiere importancia inusitada, de simple adenitis inguinal con bubón o fistulizada que a pesar de la cronicidad se consideraba como lesión local, llegamos a la realidad de localizaciones del virus paradenico a 10 largo del tubo digestivo, en los vasos sanguíneos y linfáticos (a distancia, en el ojo y oído, en el sistema nervioso, en la piel, en las articulaciones.

Nicolas Michel, Une économie de subsistances. Le Maroc précolonial, IFAO, Le Caire, 1997.

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Sylvie Denoix

2004-11-01

Full Text Available Le titre de cet ouvrage peut apparaître paradoxal si l'on considère, comme le rappelle Nicolas Michel, que le Maroc, dès avant le XIXe siècle, était inséré dans une économie marchande internationale "faisant circuler dans tout le pays produits et espèces monétaires". En fait, les produits de première nécessité échappent au grand négoce et font plutôt l'objet d'un troc, d'un échange contre services, hors système monétaire. Néanmoins, dans un souci de rigueur méthodologique, l'auteur nous garde...

Nicolas Lémery (1645-1715 and his Physical-chemical Theory about Different Phenomena for Earth Sciences

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Cándido Manuel GARCÍA CRUZ

2016-06-01

Full Text Available An unabridged translation of a work of Nicolas Lémery (1645–1715 is presented for the first time in Spanish, wherein this French chemist and apothecary attempts an explanation on physical and chemical basis of several significant phenomena in Earth Sciences, such as earthquakes, subterranean fires, hurricanes, lightning and thunder. This explanation had a common cause for all the aforementioned phenomena: the processes of mineral fermentation, in this case of sulfur and iron, as a heat source, within the corpuscular theory of matter and mechanistic philosophy, and likewise it represents an interesting contribution of the influence of chemistry on the incipient development of experimental geology at the dawn of the 18th Century. 

THE PHILOSOPHY OF NICOLAE GRIGORESCU’S AND VASILY VERESHCHAGHIN’S CREATION (on the basis of the 1877-1878 events

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IUDINA ECATERINA

2015-09-01

Full Text Available The creation of Nicolae Grigorescu and that of Vassili Veresciaghin have been considered in scientific works not just once and the works of every artist have been studied not only in his home country but abroad as well. In this article the authors tried a new foreshortening – they focused an aspecst common to these two special plastic artists – the battle theme, approaching the philosophy of Grigorescu’s and Veresciaghin’s creation on the basis of the events that took place during the Russian-Turkish war.

Morozov-type discrepancy principle for nonlinear ill-posed problems ...

Indian Academy of Sciences (India)

[3] Engl H W, Kunisch K and Neubauer A, Convergence rates for Tikhonov regularization of nonliner problems, Inverse Problems 5 (1989) 523–540. [4] Hanke M, Neubauer A and Scherzer O, A convergence analysis of Landweber iteration for nonlinear ill-posed problems, Numer. Math. 72 (1995) 21–37. [5] Hofmann B and ...

L’acqua come fonte di reddito e di discordia. Le pertinenze dei monasteri di S. Maria del Sagittario e San Nicola in Valle: opifici idraulici nella media Valle del Sinni durante il medioevo / Water as a source of income and discord. Appurtenances of the monasteries of Santa Maria del Sagittario and San Nicola in Valle: hydraulic factories in the middle Valley of Sinni in the Middle Ages

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Valentino Vitale

2015-12-01

Holders of this economic power, during the buckets. XII-XVI AD, were the Cistercian monastery of Santa Maria of Sagittarius and the Certosa di San Nicola Valley, foundations willed by the families the Clermont and the Sanseverino in Count of Chiaromonte.

Un moment de la vie du Dr Nicolae Balan (1882-1955. Son élection comme métropolite de la Transylvanie

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Stefan Argatu

2009-12-01

Full Text Available Prominent personality of the Orthodox Church and of the Romanian people, Nicolae Balan, the metropolitan of the Romanian Orthodox Church, contributed as a theology professor to the union of Transylvania with the other Romanian countries, which took place on the 1 st of December 1918. As a Metropolitan of Ardeal (1920-1955, he defended the autonomy of the church and militated for the territorial reunification of the country, required by the evil Viena Dictat of 29/30 August 1940.

Study with liquid and steam tracers at the Tejamaniles area, Los Azufres, Mich., geothermal field; Estudio con trazadores de liquido y vapor en el area Tejamaniles del campo geotermico de Los Azufres, Mich.

Energy Technology Data Exchange (ETDEWEB)

Iglesias, Eduardo R. [Instituto de Investigaciones Electricas, Gerencia de Geotermia, Cuernavaca, Morelos (Mexico)]. E-mail: iglesias@iie.org.mx; Flores Armenta, Magaly [Comision Federal de Electricidad, Gerencia de Proyectos Geotermoelectricos, Morelia, Michoacan (Mexico); Torres, Rodolfo J. [Instituto de Investigaciones Electricas, Gerencia de Geotermia, Cuernavaca, Morelos (Mexico); Ramirez Montes, Miguel [Comision Federal de Electricidad, Gerencia de Proyectos Geotermoelectricos, Morelia, Michoacan (Mexico); Reyes Picasso, Neftali [Instituto de Investigaciones Electricas, Gerencia de Geotermia, Cuernavaca, Morelos (Mexico); Reyes Delgado, Lisette [Comision Federal de Electricidad, Gerencia de Proyectos Geotermoelectricos, Morelia, Michoacan (Mexico)

2011-01-15

The Mexican Federal Commission for Electricity injects brines produced by nearby geothermal wells into well Az-08, located in the Tejamaniles area, in the southwestern portion of Los Azufres, Mich., geothermal field. The main goals of this study are to determine whether or not the injected fluid recharges nine producing wells in the area, and if so, to estimate the fraction of the injected fluid recharging each producing well. Five of the selected wells produce mixes of liquid and steam and the rest produce only steam. For this reason, we designed this study with simultaneous injections of liquid- and steam-tracers. The nine selected producing wells detected the steam-tracer, and the five wells producing mixes detected the liquid-phase tracer. The residence curves of both tracers present a series of peaks reflecting the known fractured nature of the reservoir. The results show the feeding areas of the nine selected wells are recharged by the fluid injected into well Az-08. When this paper was written, the arrival of steam-tracers in all wells was completed, but the wells producing mixes of liquid and steam continued to record the arrival of the liquid-tracer. Until 407 days after injecting the tracer, the total percentage recovery of liquid phase tracer in the five wells producing mixes of liquid and steam was 3.5032%. The arrival of the steam tracer ended in all nine wells 205 days after the tracer was injected, with an overall recovery rate of 2.1553 x 10-2%. The recovery rates imply the recharge rates of the monitored wells by the injector Az-08 are modest, but it appears the amounts of the recovered liquid-phase tracer will increase significantly. The modest recovery rates suggest most of the fluid injected into the well Az-08 disperses in the reservoir, contributing to recharge and maintaining the pressure. Results reveal that: (i) the injected fluid is heated at depths from 700 to over 1000 m, where it boils and rises to reach the feeding areas of the

Cross-Cultural Adaptation of the Micheli Functional Scale to Persian Language for Evaluation of Low Back Pain in the Young Athletes.

Science.gov (United States)

Naghdi, Soofia; Nakhostin Ansari, Noureddin; Ashrafi, Hanieh; Entezary, Ebrahim; Nakhostin Ansari, Amin; Olyaei, Gholamreza

2015-12-01

A clinical outcome tool is needed for the assessment of young athletes with low back pain. To translate and culturally adapt the Micheli functional scale (MFS), a self-report questionnaire developed to evaluate young athletes with low back pain (LBP) into Persian language and examine the reliability and validity of the Persian MFS (PMFS). A cross-sectional study was conducted to assess the psychometric properties of the PMFS. The PMFS was cross-culturally adapted into Persian language adopting forward/backward translation, expert panel review, and pre-testing. The PMFS was administered to young athletes with and without LBP. Main outcome measures were Persian MFS, Persian functional rating Index (PFRI), and visual analogue scale (VAS). A sample of 100 young athletes with LBP with a mean age of 16.5 ± 2.5 years participated. Fifty young athletes without LBP completed the PMFS. There was no missing responses and floor or ceiling effects. There was a significant difference for the total PMFS scores between young athletes with and without LBP. A significant correlation was found between the total PMFS score and the VAS (r = 0.92) or the PFRI (r = 0.82; P Persian MFS is valid and reliable for use in Persian-speaking young athletes with LBP.

Modification of the water-level control system at the Unit 12 of Los Azufres, Mich., geothermal field; Modificacion del sistema de control de nivel de agua en la Unidad 12 del campo geotermico de Los Azufres, Mich.

Energy Technology Data Exchange (ETDEWEB)

Tello Hinojosa, Raul; Aburto Huerta, S. Ramon; Mendoza Covarrubias, Hector M [Comision Federal de Electricidad, Gerencia de Proyectos Geotermoelectricos, Morelia, Michoacan (Mexico)]. E-mail: raul.tello@cfe.gob.mx

2007-01-15

Unit 12 of the Los Azufres, Mich., geothermal field is a binary cycle unit of 1.45 MW, installed at the pad of production well Az-22. There are two separators on this pad. One separates the mix extracted from well Az-22 and the other from adjacent wells. The separated brine from both separators is gathered in a horizontal tank and sent to Unit 12. The steam is sent to Unit 7, which generates 50 MW. Once some interference occurred affecting the power generation of Unit 7 when Unit 12 was off line. This was caused by the original flow arrangement and water-level control system. To avoid interference, a water-level control system was designed and installed in the separators. The system operates independently of Unit 12, with tanks in each separator connected by a pipe. Regulation of the water level is accomplished by three motor valves and a level sensor. To ensure permanent feeding of electrical power to the valves, an automatic system was installed from transmission lines of 23 and 115 kV. In case both lines fail, there is an uninterrupted power supply (UPS) unit. At the beginning of 2005, Unit 12 was again online with a modified water-level control system that has operated satisfactorily since then. Its short periods offline have not affected Unit 7. [Spanish] La Unidad 12 del campo geotermico de Los Azufres, Mich., es una unidad de ciclo binario de 1.45 MW, instalada en la plataforma del pozo productor Az-22. En esta plataforma hay dos separadores, uno de los cuales separa la mezcla extraida del pozo Az-22 y el otro la de varios pozos aledanos. El agua separada de ambos se concentra en un tanque horizontal y de este pasa a la Unidad 12, mientras que el vapor se envia a la Unidad 7, de 50 MW. Por el tipo de arreglo original de flujo y control de nivel de agua en los equipos, ocurrian interferencias que provocaban que cuando la Unidad 12 se disparaba se afectara la generacion en la Unidad 7. Para evitar esta interferencia se diseno e instalo un sistema de control de

Analysis of tethered balloon data from San Nicolas Island on 8 July 1987

Science.gov (United States)

Cox, Stephen K.; Duda, David P.; Guinn, Thomas A.; Johnson-Pasqua, Christopher M.; Schubert, Wayne H.; Snider, Jack B.

1990-01-01

Analysis of the 8 July 1987 (Julian Day 189) tethered balloon flight from San Nicolas Island is summarized. The flight commenced at about 14:30 UTC (7:30 Pacific Daylight Time) and lasted six and one-half hours. The position of the Colorado State University (CSU) instrument package as a function of time is shown. For the purpose of presentation of results, researchers divided the flight into 13 legs. These legs consist of 20 minute constant level runs, with the exception of leg 1, which is a sounding from the surface to just above 930 mb. The laser ceilometer record of cloud base is also shown. The cloud base averaged around 970 mb during much of the flight but was more variable near the end. Before the tethered balloon flight commenced, a Communications Link Analysis and Simulation System (CLASS) sounding was released at 12:11 UTC (5:11 PDT). Temperature and moisture data below 927 mb for this sounding is shown. The sounding indicates a cloud top around 955 mb at this time.

Automated System for Holographic Lightfield 3D Display Metrology (HL3DM)

Science.gov (United States)

2015-04-01

see that: Equation 7 - X = L* TAN (Ɵ)  Ɵ = ATAN(X/L) Equation 8 - L^2 + (X + W/2)^2 = P^2  P = sqrt( L^2 + (X + W/2)^2 ) Equation 9 - P...Physiol. Opt 2011, 31, 111–122. (2011, The College of Optometrists) 12. Nicolas S. Holliman, Neil A. Dodgson, Gregg E. Favalora, and Lachlan Pockett

Espaços com história na Lisboa dos séculos XVIII e XIX. Do Martinho ao Nicola

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Maria do Rosário Pimentel

2014-06-01

Full Text Available Places with a history in Lisbon between the 18th and the 19th centuries: From Martinho to Nicola. Following Miguel de Unamuno’s statement, that the «coffee-house» and the «public square» were the «true Spanish popular University», our goal will be to travel through such Portuguese public spaces, which symbolically received the name of the drink they served, Café, and became centres for the exchange of ideas, for literary gatherings, for meetings and amusements, a symbol of European modernity in the 17th and 18th centuries.

Adolphe Nicolas, Énergies : une pénurie au secours du climat ?, Paris, Belin, 2011, 160 p.

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Mathilde Szuba

2012-05-01

Full Text Available Géologue et professeur émérite à l’université de Montpellier, Adolphe Nicolas signe ici un court ouvrage, très facile d’accès, sur la pénurie des ressources énergétiques fossiles. On peut saluer ce travail de vulgarisation qui, en dépit de sa modestie, contribue activement à rendre possible un débordement des frontières disciplinaires, en traduisant les données de la controverse sur le pic pétrolier dans un langage très accessible, avec juste ce qu’il faut de graphiques et de chiffres. C’est ...

Catherine Halpern, Michèle Bitton, Lilith, l’épouse de Satan, Paris, Larousse, coll. « Dieux, Mythes et Héros », 2010, 191 p.

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Guillaume Roucoux

2011-10-01

Full Text Available Lilith, l’épouse de Satan est la quatrième figure féminine à s’inscrire dans la collection de « Dieux, Mythes & Héros » qui ne cache pas « le caractère profondément masculin de la mythologique en général » (p. 167, pour mieux lui résister. Ce portrait en six chapitres, dressé par la journaliste Catherine Halpern et la sociologue Michèle Bitton à partir de textes théologiques judéo-chrétiens et d’analyses scientifiques, nous donne à voir une Lilith plurielle mais dont « la plus grande partie ...

Nicola Michelassi y Salomé Vuelta García, Il teatro spagnolo a Firenze nel Seicento. Vol. I: Giacinto Andrea Cicognini, Giovan Battista Ricciardi, Pietro Susini, Mattias Maria Bartolommei

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Diego Símini

2015-01-01

Full Text Available Reseña de Nicola Michelassi y Salomé Vuelta García, Il teatro spagnolo a Firenze nel Seicento. Vol. I: Giacinto Andrea Cicognini, Giovan Battista Ricciardi, Pietro Susini, Mattias Maria Bartolommei, Alinea (Secoli d’Oro, 67; Commedia Aurea Spagnola e Pubblico Italiano, VIII, Florencia, 2013, 257 pp. ISBN: 9788860557865.

Analysis of tethered balloon, ceilometer and class sounding data taken on San Nicolas Island during the FIRE project

Science.gov (United States)

Schubert, Wayne H.; Ciesielski, Paul E.; Guinn, Thomas A.; Cox, Stephen K.; Mckee, Thomas B.

1990-01-01

During the FIRE Marine Stratocumulus Program on San Nicolas Island, Colorado State University (CSU) and the British Meteorological Office (BMO) operated separate instrument packages on the NASA tethered balloon. The CSU package contained instrumentation for the measurement of temperature, pressure, humidity, cloud droplet concentration, and long and short wave radiation. Eight research flights, performed between July 7 and July 14, are summarized. An analysis priority to the July 7, 8 and 11 flights was assigned for the purposes of comparing the CSU and BMO data. Results are presented. In addition, CSU operated a laser ceilometer for the determination of cloud base, and a CLASS radiosonde site which launched 69 sondes. Data from all of the above systems are being analyzed.

Œuvre 220 : Édouard Levé d’après Nicolas Brasseur - Entretien avec Olivier Sécardin

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Olivier Sécardin

2017-06-01

Full Text Available Nicolas Brasseur, artiste, photographe, né en 1981 à Nantes. Vit et travaille à Paris. Diplômé de l’École Nationale Supérieure des Arts Décoratifs de Paris en 2008, Nicolas Brasseur poursuit un travail documentaire au sein d’institutions françaises autour de la notion « d’images modèles ». Ses recherches l’ont amené à photographier l’hôpital, l’école et plus récemment la prison en parte-nariat avec le Centre Photographique d’Ile-de-France (CPIF.Édouard Levé, écrivain, artiste, photographe, né en 1965, mort en 2007. Diplômé de l’ESSEC, il commence à peindre en 1991, puis brûle presque toutes ses toiles avant de se consacrer à la photographie. En 1999, il réalise sa première série, Homonymes, qui propose des portraits photographiques de personnes inconnues portant des noms célèbres : Georges Bataille, Yves Klein, Henri Michaux… Il reprend le même procédé dans Amérique (2006, reportage sur des villes américaines qui portent le nom d’autres villes connues : Florence, Berlin, Paris... Il est l’auteur de plusieurs séries photographiques. Admirateur de Raymond Roussel, lecteur de Jacques Roubaud et de Raymond Queneau, Édouard Levé est aussi écrivain. OEuvres, publié en 2002 est le catalogue de 533 projets d’oeuvres d’art, installations, peintures, sculptures ou photographies imaginés dont l’artiste a « eu l’idée, mais qu’il n’a pas réalisés ». Son Autoportrait le présente en « 1600 phrases sans solution de continuité ». Trois jours avant de se donner la mort, Édouard Levé dépose chez son éditeur le manuscrit de son dernier texte, Suicide (2008.

Poirier Nicolas, Un espace rural à la loupe. Paysage, peuplement et territoires en Berry de la préhistoire à nos jours

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Frédérique Bertoncello

2011-01-01

Full Text Available Cet ouvrage est la publication de la thèse de Doctorat soutenue par Nicolas Poirier à l’Université de Tours en décembre 2007. L’originalité de l’étude tient à l’échelle d’analyse adoptée pour retracer la dynamique d’un espace rural aux confins du Berry et du Nivernais, qui associe micro-échelle spatiale (une cinquantaine de km² correspondant aux territoires des communes de Sancergues, Charentonnay et Saint-Martin-des-Champs, à l’est du département du Cher et longue durée chronologique (du se...

Between Vienna and Moscow: the Protopope and the General Vicar Nicolae Pop Balomiri(c. 1700 to c. 1764

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Cristian Ioan Popa

2016-12-01

Full Text Available This article explores the life of Nicolae Pop Balomiri, a Greek-Catholic Protopope and Orthodox Archimandrite. Appointed General Vicar by the exiled Bishop Inochentie Micu-Klein in 1747, Balomiri fled Transylvania shortly afterwards when the Court in Vienna refused to acknowledge his appointment, instead supporting his predecessor, Petru Pavel Aaron. Early on in his exile, Balomiri converted to Orthodoxy, and was later made Archimandrite of the Monastery of Curtea de Argeş. From exile in Wallachia, he continued to campaign for the rights of Romanian Orthodox Christians in Transylvania, lobbying Russian Empress Elisabeta Petrovna to intervene with the Viennese to request a non-United bishop for Transylvania. Many historians have glossed over Balomiri’s importance, possibly because of his controversial role as an apostate priest.

New insight into the enigmatic white cord in Rembrandt's The Anatomy Lesson of Dr. Nicolaes Tulp (1632).

Science.gov (United States)

Jackowe, David J; Moore, Michael K; Bruner, Andrew E; Fredieu, John R

2007-11-01

The anatomic accuracy of Rembrandt's The Anatomy Lesson of Dr. Nicolaes Tulp (1632) has been debated in the literature for many years. The white cord that courses along the ulnar aspect of the carpus and small finger of the cadaver in Dr. Tulp's dissection conforms to no normal anatomic structure and is believed to represent an anomalous branch of the ulnar nerve, an artistic error, or a combination of both. After the discovery of an accessory abductor digiti minimi (AADM) during a routine dissection of a late-middle-aged male cadaver, we noted that the course of its tendon over the hypothenar eminence resembled the white cord in the painting. After conducting a detailed literature search and anatomic interpretation of the painting, we established 4 criteria for identifying the white cord. Using these criteria, we evaluated the plausibility of an AADM being represented in the painting. We conclude that an AADM should be considered as a possible explanation for the white cord.

Os retratos de Maria Isabel e Maria Francisca de Bragança, de Nicolas-Antoine Taunay

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Elaine Dias

2011-01-01

Full Text Available Nicolas-Antoine Taunay, French landscape painter, produced also several portraits during his stay at the Rio de Janeiro Court. In this city, in 1816, he paints the queen Carlota Joaquina and all her daughters. In this group, two portraits have a very special way: the paintings still today catalogued as Maria Francisca and Maria Teresa, but probably being Maria Isabel and Maria Francisca de Assis - princesses that, in this year, left Brazil to marry the Spanish King Fernando VII, and his brother Carlos Maria Isidro de Bourbon. In this article, beyond to describe these portraits (and analyse the identities of the portrayed princesses, I analyse their functions in the Court society and the mains artists of this gender in Europe. I will discuss, as well, the hypothesis about the Taunay choices. In this sense, I will analyse the possible circulation of the typologies of portrait between Italy, Portugal, Spain and France, understanding these productions by Taunay and the functions occupied by these portraits in the political relations between Brazil and Europe.

[Universal elixir of Thomas-Nicolas Larcheret (1819) and his elixirian and normal doctrine].

Science.gov (United States)

Bonnemain, Bruno

2014-06-01

Thomas-Nicolas Larcheret, teacher in singing, declamation, guitar or lyre and violin, author of music and books, but also inventor of the universal elixir by his name, is a good example of quack of the 19th century. His book Larcheregium ou Dictionnaires spéciaux de mon élixir, ainsi que toute ma doctrine et de mes adhérens (Larcheregium or special Dictionaries of my elixir, as well as all my doctrine and my adherents), published in 1819, deserves a deep study to show the most frequently used arguments by the ones who emphasize the value of their secret remedy. The opportunities are there to present themselves as victims of medical authorities, experts and authorities as a whole, that do not recognize the value of their product. The only acceptable judge for them is the experience reported by the patients who are able to demonstrate the efficacy of the product since they do buy it (probably at a very high price). From this viewpoint, the book of Larcheret is a good example of turning the authorities down and of diatribe against physicians and pharmacists. It is also the demonstration that, even with the Empire's new regulations against secret remedies and quacks, they will still persist for a large part of the 19th century in France.

Feminism and Faith: Exploring Christian Spaces in the Writing of Sara Maitland and Michèle Roberts

Directory of Open Access Journals (Sweden)

Arina LUNGU-CIRSTEA

2011-03-01

Full Text Available En 1983, les féministes britanniques Sara Maitland et Jo Garcia ont publié Walking on the Water (London : Virago, une collection d’essais, de récits, de poèmes et de photos produits par des femmes sur le thème de la spiritualité. Les contributrices ont été en particulier invitées à explorer la relation entre leur identité féministe et leurs croyances religieuses. Le ton de ces contributions varie fortement, allant de l’envie passionnée de concilier les objectifs du féminisme avec le christianisme à un rejet total de l’Eglise comme institution patriarcale suprême. Cet article met en dialogue des récits diamétralement opposés du rapport entre christianisme et féminisme en s’intéressante plus particulièrement à deux des contributrices, Sara Maitland (1950 - et Michèle Roberts (1949 - . Ces deux écrivaines, qui se sont activement impliquées dans les mouvements féministes des années 1970, ont toutes deux lutté pour se réconcilier avec leur héritage chrétien. Néanmoins, alors que Maitland tente essentiellement de revisiter le christianisme en y incorporant les points essentiels d’une idéologie féministe, Roberts sent le besoin impérieux de se défaire de son identité religieuse afin de devenir indépendante ; en effet, dans son autobiographie Paper Houses (2007 elle décrit son éducation catholique comme “autoritaire et misogyne” (16. Cet article explore les façons dont l’identité spirituelle se construit dans le jeu complexe des interactions entre féminisme et foi. Il se propose, dans une perspective comparatiste, d’analyser d’une part le recueil de nouvelles de Sara Maitland intitulé A Book of Spells, et d’autre part, le roman acclamé de Michèle Roberts, Daughters of the House. Dans ces écrits, Maitland et Roberts ont un objectif commun qui est de renégocier la place des femmes dans l’histoire chrétienne dont elles reconnaissent – il est vrai à partir de perspectives diff

CTC Sentinel. Volume 9, Issue 3

Science.gov (United States)

2016-03-01

for the Caliphate,” CTC Sentinel 8:8 (2015). 28 Nicolas Beau, “Syrte, une cinquantaine de français aux cotés de Daech,” MondeAfrique, February 12...scale.”2 Earlier this month, Assistant Commissioner Mark Rowley, who oversees counterterrorism efforts for the London Metropoli- tan Police, warned

77 FR 61657 - Indiana Northeastern Railroad Company-Abandonment Exemption-In Branch and St. Joseph Counties, MI

Science.gov (United States)

2012-10-10

... Northeastern Railroad Company--Abandonment Exemption--In Branch and St. Joseph Counties, MI Indiana... Branch County, Mich., and milepost 100.69 near Sturgis in St. Joseph County, Mich. (the Line). The Line... .'' Decided: October 2, 2012. By the Board, Rachel D. Campbell, Director, Office of Proceedings. Derrick A...

Improvement in using steam for electric generation at the Los Azufres, Mich., geothermal field; Mejora en el aprovechamiento del vapor para generar energia electrica en el campo geotermico de Los Azufres, Mich.

Energy Technology Data Exchange (ETDEWEB)

Torres Rodriguez, Marco A.; Flores Armenta, Magaly; Mendoza Covarrubias, Alfredo [Comision Federal de Electricidad, Gerencia de Proyectos Geotermoelectricos, Morelia, Michoacan (Mexico)]. E-mail: magaly.flores@cfe.gob.mx

2010-01-15

Commercial exploitation in the Los Azufres geothermal field, Michoacan, Mexico, started in 1982 when the first five backpressure-power units of 5-MW each were commissioned. Nowadays the installed capacity is 188 MW from 14 units: five in the South Zone fed by steam produced from 18 production wells plus two binary-cycle power units fed by residual brines; and seven in the North Zone with steam supplied by 22 production wells. There are seven backpressure-power units with high specific consumption [between 14.5 and 13.6 tons per hour of steam (t/h) per MW]. Three operate in the South Zone and four in the North Zone. This paper shows a way to achieve more efficient use of the geothermal resource by replacing the seven backpressure units, which have completed their useful lifetime-or are close to do it-with two, new condensing power units with lower specific consumption: one unit of 50 MW to be located in the North Zone and the other of 25 MW to be placed in the South Zone. No new wells need be drilled. In this way, the average specific consumption would be reduced to 8.8-7.2 t/h per MW (saving 47% of the steam), the income for electric generation would be increased and the steam-extraction rate would remain the same. [Spanish] En 1982 empezo la explotacion comercial del campo geotermico de Los Azufres, Mich., Mexico, con la instalacion y puesta en servicio de las primeras cinco unidades turbogeneradoras a contrapresion de 5 MW cada una. Actualmente la capacidad instalada es de 188 MW, con catorce unidades: cinco en la zona sur, alimentadas por el vapor de 18 pozos productores, mas dos unidades de ciclo binario que utilizan salmuera residual, y siete unidades en la zona norte, alimentadas por 22 pozos. Hay siete unidades a contrapresion con un consumo especifico elevado [entre 14.5 y 13.6 toneladas por hora (t/h) de vapor por MW], tres de las cuales se localizan en la zona sur y cuatro en la zona norte. En este documento se presenta un proyecto para hacer mas

The biological soil crusts of the San Nicolas Island: Enigmatic algae from a geographically isolated ecosystem

Science.gov (United States)

Flechtner, V.R.; Johansen, J.R.; Belnap, J.

2008-01-01

Composite soil samples from 7 sites on San Nicolas Island were evaluated quantitatively and qualitatively for the presence of cyanobacteria and eukaryotic microalgae. Combined data demonstrated a rich algal flora with 19 cyanobacterial and 19 eukaryotic microalgal genera being identified, for a total of 56 species. Nine new species were identified and described among the cyanobacteria and the eukaryotic microalgae that were isolated: Leibleinia edaphica, Aphanothece maritima, Chroococcidiopsis edaphica, Cyanosarcina atroveneta, Hassallia californica, Hassallia pseudoramosissima, Microchaete terrestre, Palmellopsis californiens, and Pseudotetracystis compactis. Distinct distributional patterns of algal taxa existed among sites on the island and among soil algal floras of western North America. Some algal taxa appeared to be widely distributed across many desert regions, including Microcoleus vaginatus, Nostoc punctiforme, Nostoc paludosum, and Tolypothrix distorta, Chlorella vulgaris, Diplosphaera cf. chodatii, Myrmecia astigmatica, Myrmecia biatorellae, Hantzschia amphioxys, and Luticola mutica. Some taxa share a distinctly southern distribution with soil algae from southern Arizona, southern California, and Baja California (e.g., Scenedesmus deserticola and Eustigmatos magnus). The data presented herein support the view that the cyanobacterial and microalgal floras of soil crusts possess significant biodiversity, much of it previously undescribed.

California sea otter (Enhydra lutris nereis) census results, Spring 2017

Science.gov (United States)

Tinker, M. Tim; Hatfield, Brian B.

2017-09-29

The 2017 census of southern sea otters (Enhydra lutris nereis) was conducted between late April and early July along the mainland coast of central California and in April at San Nicolas Island in southern California. The 3-year average of combined counts from the mainland range and San Nicolas Island was 3,186, down by 86 sea otters from the previous year. This is the second year that the official index has exceeded 3,090, the Endangered Species Act delisting threshold identified in the U.S. Fish and Wildlife Service’s Southern Sea Otter Recovery Plan (the threshold would need to be exceeded for 3 consecutive years before delisting consideration). The 5-year average trend in abundance, including both the mainland range and San Nicolas Island populations, remains positive at 2.3 percent per year. Continuing lack of growth in the range peripheries likely explains the cessation of range expansion.

Diet patterns of island foxes on San Nicolas Island relative to feral cat removal

Science.gov (United States)

Cypher, Brian L.; Kelly, Erica C.; Ferrara, Francesca J.; Drost, Charles A.; Westall, Tory L.; Hudgens, Brian

2017-01-01

Island foxes (Urocyon littoralis) are a species of conservation concern that occur on six of the Channel Islands off the coast of southern California. We analysed island fox diet on San Nicolas Island during 2006–12 to assess the influence of the removal of feral cats (Felis catus) on the food use by foxes. Our objective was to determine whether fox diet patterns shifted in response to the cat removal conducted during 2009–10, thus indicating that cats were competing with foxes for food items. We also examined the influence of annual precipitation patterns and fox abundance on fox diet. On the basis of an analysis of 1975 fox scats, use of vertebrate prey – deer mice (Peromyscus maniculatus), birds, and lizards – increased significantly during and after the complete removal of cats (n = 66) from the island. Deer mouse abundance increased markedly during and after cat removal and use of mice by foxes was significantly related to mouse abundance. The increase in mice and shift in item use by the foxes was consistent with a reduction in exploitative competition associated with the cat removal. However, fox abundance declined markedly coincident with the removal of cats and deer mouse abundance was negatively related to fox numbers. Also, annual precipitation increased markedly during and after cat removal and deer mouse abundance closely tracked precipitation. Thus, our results indicate that other confounding factors, particularly precipitation, may have had a greater influence on fox diet patterns.

Coherent Operations, Entanglement, and Progress Toward Quantum Search in a Large 2D Array of Neutral Atom Qubits

Science.gov (United States)

2015-08-18

by Benjamin Bederson and Herbert Walther, pp. 95 –170. issn: 1049-250X. doi: 10.1016/S1049-250X(08)60186-X. [49] Nicolas Schlosser, Georges Reymond...144 9.5.1.2 Genetic Algorithm . . . . . . . . . . . . . . . . . . . . . . . . 145 9.5.1.3 Nelder- Mead Simplex...from 2013-11-14-15-18-54. 90 Nelder- Mead optimizing readout frequency, power and time Readout frequency Iterations Python Controller Arroyo TEC and

The Pilgrimage to The San Nicola Shrine in Bari and its Impact

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Katia Rizzello

2013-12-01

Full Text Available Pilgrimage is defined as a journey to the Holy but more specifically as an inner journey to one’s deepest religious feelings. This type of journey has assumed new forms and types that bring it closer to modern tourism in general, though it maintains its distinctive characteristics, which will be the object of this paper. These changes in the nature of pilgrimage, which in part reflect the parallel socio-cultural transformation of the average visitor, have brought about a major reorganisation of the places involved and have had a significant socio-economic impact on the territories involved. The concentration of visitors and in some cases the presence of various categories of visit have led to structural changes in holy places and their surroundings. These changes, which arise from the need to meet the requirements of travellers as consumers, in turn have social and environmental impacts on the surrounding area that are similar to those caused by mass tourism. The most evident types of impact are structural, resulting from the creation or expansion of hotel and catering infrastructure and the start-up of new businesses such as travel agencies, specialised tour operators, shops selling religious souvenirs and establishments providing entertainment. All this alters the physiognomy and the layout of the towns where the religious sites are located, in some cases completely transforming the economy of the location and the use of land. The aim of this research is to study pilgrimage flows associated with the cult of Saint Nicholas (San Nicola in Bari, specifically concerning the pilgrimage's main characteristics and the most significant impacts on the district. The study follows a mixed approach that includes participant observation, use of archival documents and empirical evaluation of the material landscape and observed practices.

NRL tethered balloon measurements at San Nicolas Island during FIRE IFO 1987

Science.gov (United States)

Gerber, Hermann; Gathman, Stuart; James, Jeffrey; Smith, Mike; Consterdine, Ian; Brandeki, Scott

1990-01-01

An overview is given of the tethered balloon measurements made during the First ISCCP Regional Experiment (FIRE) marine stratocumulus intensive field observations (IFO) at San Nicolas Island in 1987. The instrument utilized on the balloon flights, the 17 flights over a 10 day period, the state of the data analysis, and some preliminary results are described. A goal of the measurements with the Naval Research Laboratory (NRL) balloon was to give a unique and greatly improved look at the microphysics of the clear and cloud-topped boundary layer. For this goal, collocated measurements were made of turbulence, aerosol, cloud particles, and meteorology. Two new instruments which were expected to make significant contributions to this effort were the saturation hygrometer, capable of measuring 95 percent less than RH 105 percent (with an accuracy of 0.05 percent near 100 percent) and used for the first time in clouds; and the forward scatter meter which gives in situ LWC measurements at more than 10 Hz. The data set, while unfortunately only partially simultaneous with the bulk of the FIRE stratocumulus observations, is unique and worthwhile in its own right. For the first time accurate RH measurements near 100 percent have been made in-cloud; although, the use of the saturation hygrometer reflected a learning experience which will result is substantially better performance the next time. These measurements were made in conjunction with other microphysical measurements such as aerosol and cloud droplet spectra, and perhaps most important of all, they were all collocated with bivane turbulence measurements thus permitting flux calculations. Thus the analysis of this data set, which consisted of about 50 percent stratocumulus cases including increasing and decreasing partial cloud cover, should lead to new insights on the physical mechanisms which drive the boundary-layer/cloud/turbulence system.

Nicolas Lyon-Caen , La boîte à Perrette, le jansénisme parisien au xviiie siècle

OpenAIRE

Vermander, Benoît

2012-01-01

Nicolas Lyon-­­­Caen publie ici sa thèse sou­­te­­nue en 2008 à l’uni­­ver­­sité Paris I (dir. Cl. Mi­­­chaud) sous le titre Mar­­chands de miracles. La bour­­geoi­­sie jan­­sé­­niste pari­­sienne au xviiie siècle, elle-­­­même pro­­lon­­ge­­ment d’une thèse de l’École des Chartes consa­­crée au finan­­ce­­ment du « parti » jan­­sé­­niste au xviiie siècle (La boîte à Perrette, 2002). Ce n’est donc pas une his­­toire de l’ensemble des jan­­sé­­nistes pari­­siens que l’on trou­­vera dans cet ou...

4. The Feldenkrais Method in the Puppeteer’s Training from the Perspective of Nicolas Gousseff’s Handheld Puppets Workshops

Directory of Open Access Journals (Sweden)

Ciofu Anca-Mihaela

2018-03-01

Full Text Available Although the Feldenkrais method is quite well-known and used in relation to dance, music, and acting, it is rather uncommon to associate it with animation theatre. The puppeteer’s art is a profession that requires motor skills and sustained physical effort, which demands that the animating actor has an extended consciousness of oneself and of the space. Therefore, the Feldenkrais method can be a useful instrument in the puppeteer’s education and training, as the placing of the body in a relaxed stance, one which helps in the management of pain and effort, facilitates the conscious and creative learning of animation techniques, with an emphasis on the coordination and fluidity of movement. These are learning principles of the art of animation that are successfully used by Nicolas Gousseff, an artist that was formed at ESNAM (École Supérieure Nationale des Arts de la Marionnette de la Charleville-Mézières, and who has specialized in handheld puppets and using the actor’s body as a performative space for this type of animation.

La teoria della letteratura di Nicolas Calas. Surrealismo, marxismo e psicanalisi in Foyers d’incendie

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A. D'Urso

2013-10-01

Full Text Available ENThis contribution – probably the first specifically concerning Nicolas Calas to be published in Italian – intends to examine some particular topics of Foyers d’incendie [Hearths of Arson] (1938, a work that hardly can be found, by now. So this study will try to partially fill the absence at an international level of a detailed analysis of this book which is usually considered to be ‘difficult’ and therefore often hastily put under the label of ‘Freudo-Marxism’. Not only does this label appear confusing when we look more care-fully at the historical context of the Thirties, but it also does not allow to understand in what both Marxism and Freudism are criticized indeed, this aspect defining more clearly the surrealist character – eluded or taken for granted by critics – of Foyers d’incendie. In the first half of this paper, we will underline the role of Surrealism in Calas’ critical evolution in relation to orthodox Communism, whose language he still used before becoming indubitably a Surrealist. Then we will show the enthusiastic reception of Foyers d’incendie among the Surrealists and also the reasons of their appreciation. In the second half, we will go deep inside some pages of this book which concern more spe-cifically the theory of literature and the critique of ideology we can draw from Foyers d’incendie. This is why – for the first time – we will summarize Calas’ understanding of the literary and philosophical history, and show the role that Dialectical Materialism (chiefly that of Engels’ Origin of the Family, Private Property and the State and psychoanalysis (as it is considered by Surrealism play in his analysis.>>Questo contributo – apparentemente il primo studio specificamente dedicato a Nicolas Calas ad essere pubblicato in italiano – intende affrontare alcuni particolari contenuti dell’ormai quasi introvabile Foyers d’incendie (1938, tentando così di colmare, almeno parzialmente, l�

A crowd of pedestrian dynamics - The perspective of physics. Comment on "Human behaviours in evacuation crowd dynamics: From modelling to "big data" toward crisis management" by Nicola Bellomo et al.

Science.gov (United States)

Miguel, António F.

2016-09-01

Walking is the most basic form of transportation. A good understanding of pedestrian's dynamics is essential in meeting the mobility and accessibility needs of people by providing a safe and quick walking flow [1]. Advances in the dynamics of pedestrians in crowds are of great theoretical and practical interest, as they lead to new insights regarding the planning of pedestrian facilities, crowd management, or evacuation analysis. Nicola Bellomo's et al. article [2] is a very timely review of the related research on modelling approaches, computational simulations, decision-making and crisis response. It also includes an attempt to accurately define commonly used terms, as well as a critical analysis of crowd dynamics and safety problems. As noted by the authors, ;models and simulations offer a virtual representation of real dynamics; that are essential to understand and predict the ;behavioural dynamics of crowds; [2]. As a physicist, I would like to put forward some additional theoretical and practical contributions that could be interesting to explore, regarding the perspective of physics on about human crowd dynamics (panic as a specific form of behaviour excluded).

High mass and spatial resolution mass spectrometry imaging of Nicolas Poussin painting cross section by cluster TOF-SIMS.

Science.gov (United States)

Noun, M; Van Elslande, E; Touboul, D; Glanville, H; Bucklow, S; Walter, P; Brunelle, A

2016-12-01

The painting Rebecca and Eliezer at the Well, which hangs in the Fitzwilliam Museum, Cambridge, UK, is possibly one of the last figure painting executed by Nicolas Poussin at the very end of his life and is usually dated to the early 1660s. In this perspective special feature, Philippe Walter, Alain Brunelle and colleagues give new insights on the artist's working methods by a careful stateof-the-art imaging ToF-SIMS study of one sample taken on the edge of the painting. This approach allowed for the identification of the pigments used in the painting, their nature and components and those of the ground and preparatory layers, with the identification of the binder(s) and possible other additions of organic materials such as glue. This study paves the way to a wider use of ToF-SIMS for the analysis of ancient cultural heritage artefacts. Dr. Walter is the Director of the Molecular and Structural Archeology Laboratory (Université Pierre et Marie Curie, Paris, France). Dr. Brunelle is Head of the Mass Spectrometry Laboratory at the Institut de Chimie des Substances Naturelles (CNRS, Gif-sur-Yvette, France). Their long standing collaboration has led to several seminal publications on the analysis of ancient artefacts by mass spectrometry. Copyright © 2016 John Wiley & Sons, Ltd.

Comportamento fisiológico de sementes osmocondicionadas de Platymiscium pubescens Micheli (tamboril-da-mata

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Borges Eduardo Euclydes de Lima e

2002-01-01

Full Text Available O objetivo deste trabalho foi investigar alterações fisiológicas e bioquímicas em sementes osmocondicionadas de tamboril-da-mata (Platymiscium pubescens Micheli. Foram analisados o crescimento do eixo embrionário, a germinação, as alterações na parede celular, a mobilização de carboidratos e proteínas e a atividade de a-galactosidase. Observou-se que o teor de umidade das sementes da testemunha aumentou continuamente até 96 horas de embebição, enquanto as mantidas nas soluções de PEG estabilizaram-se a partir de 48 horas. A germinação ocorreu somente nas sementes mantidas em água, alcançando 30% em 120 horas. As sementes mantidas em solução-0,4 MPa de PEG por 120 horas tiveram 66% de germinação quando transferidas para água, sendo a maior em relação aos demais potenciais. A massa fresca e o comprimento do embrião aumentaram significativamente durante o período de 120 horas em solução de PEG (-0,4 MPa/120 horas, porém a massa seca teve incremento não-significativo. Os teores de arabinose e xilose em membranas lavadas com água decresceram significativamente durante o osmocondicionamento. A galactose não foi detectada na membrana em 120 horas. A arabinose mostrou ser a principal constituinte da membrana. A atividade de a-galactosidase mostrou diferença significativa durante o período de 120 horas. Os teores de ramnose, arabinose e xilose alteraram-se significativamente na fração péctica, enquanto a ramnose foi a única na fração hemicelulósica. A glicose foi detectada somente nessa última fração. Os teores de glicose no embrião e cotilédones alteraram-se significativamente durante o osmocondicionamento. Os teores de estaquiose e de rafinose não tiveram alterações significativas nos cotilédones, enquanto o de sacarose reduziu-se significativamente, mantendo-se mais alto do que os dos outros dois oligossacarídeos. O teor de proteína decresceu significativamente nas 120 horas de

A Preliminary Study Associated with the Experimental Measurement of the Aero-Optic Characteristics of Hypersonic Configurations

Science.gov (United States)

1992-06-01

and Neubauer , R.A., "Experimental Studies of Pulsed Microwave Breakdown Effects in a Hypersonic Air Plasma," Calspan Report No. AA-2053-Y-2, AFCRL...perhaps 100 jim intervals. For example 16 images will be exposed on 128 x 128 pixels sectors of a 512 x 512 pixel CCD camera , all during a 3.2 ms period of...device uses a laser and CCD camera . Acoustic-optic beam deflectors will scan the LOS during the short duration test, allowing image exposure durations

From the Island of the Blue Dolphins: A unique 19th century cache feature from San Nicolas Island, California

Science.gov (United States)

Erlandson, Jon M.; Thomas-Barnett, Lisa; Vellanoweth, René L.; Schwartz, Steven J.; Muhs, Daniel R.

2013-01-01

A cache feature salvaged from an eroding sea cliff on San Nicolas Island produced two redwood boxes containing more than 200 artifacts of Nicoleño, Native Alaskan, and Euro-American origin. Outside the boxes were four asphaltum-coated baskets, abalone shells, a sandstone dish, and a hafted stone knife. The boxes, made from split redwood planks, contained a variety of artifacts and numerous unmodified bones and teeth from marine mammals, fish, birds, and large land mammals. Nicoleño-style artifacts include 11 knives with redwood handles and stone blades, stone projectile points, steatite ornaments and effigies, a carved stone pipe, abraders and burnishing stones, bird bone whistles, bone and shell pendants, abalone shell dishes, and two unusual barbed shell fishhooks. Artifacts of Native Alaskan style include four bone toggling harpoons, two unilaterally barbed bone harpoon heads, bone harpoon fore-shafts, a ground slate blade, and an adze blade. Objects of Euro-American origin or materials include a brass button, metal harpoon blades, and ten flaked glass bifaces. The contents of the cache feature, dating to the early-to-mid nineteenth century, provide an extraordinary window on a time of European expansion and global economic development that created unique cultural interactions and social transformations.

Distributed Autonomous Control of Multiple Spacecraft During Close Proximity Operations

Science.gov (United States)

2007-12-01

Neubauer [54][55]. 87 VII. LQR/APF CONTROL ALGORITHM APPROACH The LQR approach can be recursively applied to the multiple spacecraft close... Neubauer and Swartwout’s research [55]. It is generally possible to select a closed map over which the algorithm is stable and robust. For these...can be easily edited and transferred into video format for presentations. Modifications of camera key frames ( camera position and angle) and

Study of liquid and steam tracers at the Maritaro - La Cumbre area of the Los Azufres geothermal field, Mich.; Estudio con trazadores de liquido y vapor en la zona Maritaro - La Cumbre del campo geotermico de Los Azufres, Mich.

Energy Technology Data Exchange (ETDEWEB)

Iglesias, Eduardo R [Instituto de Investigaciones Electricas, Cuernavaca, Morelos, (Mexico)]. E-mail: iglesias@iie.org.mx; Flores Armenta, Magaly; Quijano Leon, Jose Luis; Torres Rodriguez, Marco A [Comision Federal de Electricidad, Morelia, Michoacan (Mexico); Torres, Rodolfo J; Reyes Picasso, Neftali [Instituto de Investigaciones Electricas, Cuernavaca, Morelos, (Mexico)

2008-01-15

We ran two simultaneous tracer tests in the Maritaro-La Cumbre area of the Los Azufres geothermal field in Mexico. We wished to determine whether or not fluids injected in well Az-15 recharged the productive areas of six production wells and to estimate the fractions of injected fluid recovered in them, if any. Because only three of the wells produce water and all of them produce steam, two tracers were used, sulfur hexafluoride (SF{sub 6}) for the gas phase and 1,3,6 naphthalene trisulfonate (1,3,6-nts) for the liquid phase. All of the observation wells recorded SF{sub 6}, and the three water-producing wells recorded 1,3,6-nts, proving that fluids injected in well Az-15 do recharge the area of interest. When sampling was suspended, the three water-producing wells were still producing 1,3,6-nts at significant rates. The total recovery of 1,3,6-nts at wells Az-65D, Az-04 and Az-28, 279 days after injection when sampling was halted, were, respectively, 6.1%, 0.90% y 0.16%, for a total of 7.61%. We concluded that these quantities constitute the lower boundaries for the respective recovery factors. When sampling was halted, wells Az-65D, Az-66D and Az-30 were still producing some SF{sub 6} at lower rates, and the rest of the wells were no longer recording the gas phase tracer. The total recovery of SF{sub 6} at wells Az-65D, Az-04, Az-41, Az-30, Az-28 and Az-66D were, respectively, 4.82 e-02%, 1.37 e-03%, 1.48 e-03%, 6.38 e-04%, 1.38 e-03% y 4.31 e-04%, for a total of 5.35 e-02%. The liquid recharge occurred in orders of magnitude greater than the steam. [Spanish] Se efectuaron dos pruebas simultaneas en la zona Maritaro-La Cumbre del campo geotermico de Los Azufres, Mich., Mexico. Los objetivos de estas pruebas fueron determinar si la salmuera de desecho inyectada en el pozo Az-15 recarga las zonas de alimentacion de seis pozos productores designados por CFE, y estimar que fraccion de lo inyectado recarga dichos pozos productores. Debido a que solo tres de los pozos

Genetics Home Reference: epilepsy-aphasia spectrum

Science.gov (United States)

... Szepetowski P, Scheffer IE, Mefford HC. GRIN2A mutations cause epilepsy-aphasia spectrum disorders. Nat Genet. 2013 Sep;45( ... Neubauer BA, Biskup S, von Spiczak S. Mutations in GRIN2A cause idiopathic focal epilepsy with rolandic spikes. Nat Genet. 2013 Sep;45( ...

Ecological Risk Assessment of Munitions Compounds on Coral and Coral Reef Health

Science.gov (United States)

2014-01-01

and temperature and salinity were measured. At the 48 h and 96 h time points, cells from each treatment were counted using a C-Chip Neubauer Improved...concentration of the stock culture was determined using a Bright-Line® Improved Neubauer hemacytometer. A subsample of the stock culture was then...same routine. Fragments were orientated in the Teflon® stand under the fluorometer camera using infrared light supplied by the instrument. The

JPRS Report, East Europe

Science.gov (United States)

1991-06-04

Neubauer (the spokesman of the expellees* association) continually wants to wash laundry that no one wears anymore. He wants a return of Sudeten German...laws. If Mr. Neubauer wants to participate in the nego- tiations about the German-Czechoslovak treaty, he would have to have the trust of both sides.1...video cameras and photographic equipment we were carrying. Wc were granted permis- sion to take pictures without any restrictions of all activities

NICOLAS MALEBRANCHE: FROM THE THEORY OF “GENERAL WILL” TO THE CONCEPT OF “INCLINATION”

Directory of Open Access Journals (Sweden)

CRISTIAN MOISUC

2014-11-01

Full Text Available The period between 1670 and 1740 is considered a time of “crisis of Christian rationalism” (A. McKenna or a time of “skepticism” (V.Cousin, since the Christian apologetics, trapped between Protestantism and the Rationalism, are gradually reduced to a row of inefficient and traditional “proofs” for the existence and kindness of God. In 1680, Nicolas Malebranche publishes the Treatise on Nature and Grace, following to explain the way in which God granted His grace to all mankind. In order to fight the skeptical thesis according to which God takes not directly part in this world, Malebranche refers the action of God to the concept of “general/divine will”. If such a theory is useful at a certain metaphysical level in explaining the presence of the evil in the world (God does not create but allows the evil, it raises some anthropological issues, especially concerning the nature of the human free will. If anything in the world emerges as a direct consequence of God’s “general will”, how can be conceived a real free human will? The theory of God’s general will generates an unexpected anthropological consequence (the dissolution of the human free will that Malebranche tries to hide it by inventing the concept of “inclination of the will”: God does not interfere (by causation with the human will, but He influences it (by inclination. Is it philosophically defensible? The aim of the article is to analyze some philosophical and methodological difficulties related to the new Malebranchist concept of “inclination of human will” in order to prove that the passage from the occasionalist theory of general will to an inquiry about the human will is quite problematic.

Oplyst slaveri?

DEFF Research Database (Denmark)

Ladegaard, Jakob; Smed, Sine Jensen

2017-01-01

Om forholdet mellem oplysningsidealer og slaveri set gennem dansk litteratur fra H.C. Andersens Mulatten til Mich Vraas Haabet.......Om forholdet mellem oplysningsidealer og slaveri set gennem dansk litteratur fra H.C. Andersens Mulatten til Mich Vraas Haabet....

78 FR 11638 - Michigan Consolidated Gas Company, DTE Gas Company, DTE Gas Company; Notice of Petition

Science.gov (United States)

2013-02-19

... corporate name change from MichCon to DTE Gas, and pursuant to section 284.123 of the Commissions... Gas Company (DTE Gas) filed to institute a name change to both itself from MichCon to DTE Gas and to...

KINESIOLOGY- THE SCIENCE OF MOVEMENT In Relation to Education, Hygiene and Therapy. A piece of the legacy of Nicolas Dally (1795-1862 for contemporary kinesiology scholars and professionals

Directory of Open Access Journals (Sweden)

Franjo Prot

2010-01-01

Full Text Available Kinesiology has recently gained full worldwide credibility as an academic discipline in the field of human movement and exercise practice in the area of education, sport, recreation and kinesitherapy, becoming a proper denominator for the field of sport or exercise science. It seems almost compulsory that on the occasion of the introduction of the first issue of Annales Kinesiologiae, a new scientific journal in the field, to remember and speak about Nicolas Dally and his work. In this paper a short biography of the forefather of KINESIOLOGY, or CINÉSIOLOGIE, will be presented as well as how Dally introduced the term and the concept in his book from 1857. It is presented and integrated with some newly available illustrative material. Dally’s bibliography based on resources of worldwide relevant library catalogues is added to the references.

A Study of the Nearfield of an Excited Spherical Shell.

Science.gov (United States)

1980-03-17

sound field. This varying light intensity was recorded by means of a camera set at a long time exposure. The typical measurement time for one picture...Spheres in Water," J. Acoust. Soc. Amer. 41, 380-393 (1967). 7. Dragonette, L. R., Vogt, R. H., Flax, L. and Neubauer , W. G., "Acoustic Reflection from...34 J. Acoust. Soc. Amer. 50, 1334-1342 (1971). 34. Neubauer , W. G., Vogt, R. H. and Dragonette, L. R., "Acoustic Reflection from Elastic Sphere. I

2-3D nonlocal transport model in magnetized laser plasmas.

Science.gov (United States)

Nicolaï, Philippe; Feugeas, Jean-Luc; Schurtz, Guy

2004-11-01

We present a model of nonlocal transport for multidimensional radiation magneto-hydrodynamics codes. This model, based on simplified Fokker-Planck equations, aims at extending the formulae of G Schurtz,Ph.Nicolaï and M. Busquet [Phys. Plasmas,7,4238 (2000)] to magnetized plasmas.The improvements concern various points as the electric field effects on nonlocal transport or conversely the kinetic effects on E field. However the main purpose of this work is to generalize the previous model by including magnetic field effects. A complete system of nonlocal equations is derived from kinetic equations with self-consistent E and B fields. These equations are analyzed and simplified in order to be implemented into large laser fusion codes and coupled to other relevent physics. Finally, our model allows to obtain the deformation of the electron distribution function due to nonlocal effects. This deformation leads to a non-maxwellian function which could be used to compute the influence on other physical processes.

Estudo comparativo da eficiência de diferentes técnicas de mensuração da concentração espermática em suínos Efficiency of different measurement techniques of sperm concentration in swine

Directory of Open Access Journals (Sweden)

Wagner Loesch Vianna

2004-12-01

Full Text Available A inseminação artificial (IA em suínos é uma técnica cada vez mais utilizada na suinocultura moderna, pois propicia ao suinocultor vantagens quanto ao desempenho dos reprodutores, ao controle dos cruzamentos e à facilidade na introdução de material genético. Objetivando o aperfeiçoamento da técnica de IA, foram avaliadas a acurácia, a precisão e a robustez do Espermiodensímetro (ESPERMIO e do Espectrofotômetro (ESPECTRO, em comparação à Câmara de Neubauer. Utilizaram-se 142 ejaculados, que revelaram concentrações espermáticas médias (em milhões de sptz/mL e número médio de doses que poderiam ser produzidas, respectivamente, de 229,1 e 22,6; 185,0 e 18,5; 283,6 e 28,0 para a Câmara de Neubauer, o Espectrofotômetro e o Espermiodensímetro. O viés médio (acurácia e o desvio-padrão do viés médio (precisão do ESPECTRO, em comparação à Câmara de Neubauer, foram, respectivamente, de - 44,1 e 52,6, enquanto para o ESPERMIO foram de 54,5 e 44,8 (milhões de sptz/mL. Pode-se inferir que o ESPECTRO tende a subestimar e o ESPERMIO, a superestimar a concentração espermática, em comparação à Câmara de Neubauer. O ESPECTRO foi mais acurado e igualmente preciso que o ESPERMIO. A influência do volume de ejaculado sobre os resultados do ESPERMIO e do ESPECTRO pode ser comprovada pelos resultados de robustez para o volume do ejaculado.Artificial Insemination (AI in swines is a rising technique that has been used during the last years at the swine production systems, because it furnish several advantages to the producers just like boar high efficiency, better breeding control and easiness in introducing foreign genetic materials. Accuracy, precision and robustness for ejaculation volume of spermdensimeter (ESPERMIO and spectrofotometer (ESPECTRO in relation to the Neubauer Count, designed as the standard technique, were evaluated objectifying higher performance of AI technique. A total of 142 boar ejaculation was used

La laicità francese secondo Nicolas Sarkozy

Directory of Open Access Journals (Sweden)

Maria d'Arienzo

2011-05-01

Full Text Available Il contributo è destinato agli Studi in onore del Professore Piero Pellegrino. SOMMARIO: 1. Premesse sul concetto di laicità – 2. Le radici della laicità in Francia – 3. Laicità e sentimento religioso nel discorso di Sarkozy – 4. La laicità positiva di Sarkozy. Un modello nuovo per la Francia?

78 FR 41993 - Ann Arbor Railroad, Inc.-Lease Exemption-Norfolk Southern Railway Company

Science.gov (United States)

2013-07-12

... number of carloads interchanged with NSR in a given year.\\1\\ AARR states that the interchange commitment..., Canadian National Railway Company (CN), CSX Transportation, Inc., and Wheeling & Lake Erie Railway in Toledo; the Indiana and Ohio Railway and CN in Diann, Mich.; NSR in Milan, Mich.; and Great Lakes Central...

At the XI International Conference on High Energy Accelerators

CERN Multimedia

CERN PhotoLab

1980-01-01

The Conference was held at CERN and attracted some 300 specialists (see CERN Courier 1980 p. 231). The conference was a success thanks also to many CERN people. Here, first raw, Susannah Tracy, Ingrid Barnett, ..?, Danièle Lajust, Simon Newman, Owen Lock. Second raw, (2) Ed Powell, (3) Ernest Bissa, (7) Myrna Guarisco, (8) Barbara Strasser, (10) Michèle Compoint, (11) Anne Caton, (12) Mike Crowley-Milling.

France @ CERN | Come and meet 37 French companies at the 2014 “France @ CERN” Event | 1-3 December

CERN Multimedia

2014-01-01

The 13th “France @ CERN” event will take place from 1 December to 3 December 2014. Thanks to Ubifrance, the French agency for international business development, 37 French firms will have the opportunity to showcase their know-how at CERN.   These companies are looking forward to meeting you during the B2B sessions which will be held on Tuesday, 2 December (afternoon) and on Wednesday, 3 December (afternoon) in buildings 500 and 61 or at your convenience in your own office. The fair’s opening ceremony will take place on Tuesday, 2 December (morning) in the Council Chamber in the presence of Rolf Heuer, Director-General of CERN and Nicolas Niemtchinow, Ambassador, Permanent Representative of France to the United Nations in Geneva and to international organisations in Switzerland. For more information about the event and the 37 participating French firms, please visit: http://www.la-france-au-cern.com/

Pilot study on the additive effects of berberine and oral type 2 diabetes agents for patients with suboptimal glycemic control

OpenAIRE

Di Pierro, Francesco; Villanova,Nicola; Agostini,Federica; Soverini,Valentina; Marchesini,Giulio; Marzocchi,Rebecca

2012-01-01

Francesco Di Pierro,1 Nicola Villanova,2 Federica Agostini,2 Rebecca Marzocchi,2 Valentina Soverini,2 Giulio Marchesini21Scientific Department, Velleja Research, Milano, 2Diseases of Metabolism, S Orsola Malpighi Hospital, Bologna, ItalyBackground: Suboptimal glycemic control is a common situation in diabetes, regardless of the wide range of drugs available to reach glycemic targets. Basic research in diabetes is endeavoring to identify new actives working as insulin savers, use of which coul...

Natural Language Video Description using Deep Recurrent Neural Networks

Science.gov (United States)

2015-11-23

ht = f (Wxhxt + Whhht−1) (2.1) zt = g(Wzhht) (2.2) where f and g are element-wise non-linear functions such as a sigmoid or hyperbolic tan - gent, xt...space. arXiv preprint arXiv:1301.3781, 2013. 22 [68] Volodymyr Mnih, Nicolas Heess, Alex Graves, et al. Recurrent models of visual attention. In...2010. 2 36 Bibliography [107] Li Yao, Atousa Torabi, Kyunghyun Cho, Nicolas Ballas, Christopher Pal, Hugo Larochelle, and Aaron Courville. Describing

Research

African Journals Online (AJOL)

abp

24 juin 2015 ... Page number not for citation purposes. 1. Epaisseur de l'intima-média carotidienne et facteurs de risque cardio-vasculaires. Nicolas Fanantenana Herinirina1, Lova Hasina Ny Ony Narindra Rajaonarison2,&, Andry Roussel Herijoelison3, Ahmad Ahmad2. 1Service Imagerie Médicale, Centre Hospitalier ...

Mail2Print online tutorial

CERN Multimedia

CERN. Geneva

2016-01-01

Mail2print is a feature which allows you to send documents to a printer by mail. This tutorial (text attached to the event page) explains how to use this service. Content owner: Vincent Nicolas Bippus Presenter: Pedro Augusto de Freitas Batista Tell us what you think via e-learning.support at cern.ch More tutorials in the e-learning collection of the CERN Document Server (CDS) https://cds.cern.ch/collection/E-learning%20modules?ln=en All info about the CERN rapid e-learning project is linked from http://twiki.cern.ch/ELearning  

Nonequilibrium Dynamics of Arbitrary-Range Ising Models with Decoherence: An Exact Analytic Solution

Science.gov (United States)

2013-04-03

C. Cross, Phys. Rev. Lett. 108, 023602 (2012). [4] B. Kraus, H. P. Büchler, S. Diehl, A. Kantian , A. Micheli, and P. Zoller, Phys. Rev. A 78...042307 (2008). 042101-7 FOSS-FEIG, HAZZARD, BOLLINGER, AND REY PHYSICAL REVIEW A 87, 042101 (2013) [5] S. Diehl, A. Micheli, A. Kantian , B. Kraus, H. P

Dynamical Quantum Correlations of Ising Models on an Arbitrary Lattice and Their Resilience to Decoherence

Science.gov (United States)

2013-01-01

transition in itinerant electron systems. Phys. Rev. Lett., 95:177201, 2005. [19] Diehl S, Micheli A, Kantian A, Kraus B, Büchler H P, and Zoller P...strongly driven open xxz chain. Phys. Rev. Lett., 107:137201, 2011. [21] Kraus B, Büchler H P, Diehl S, Kantian A, Micheli A, and Zoller P. Preparation

The Security of the South Atlantic: Is It a Case for ’SATO’--South Atlantic Treaty Organization

Science.gov (United States)

1982-05-10

p. 704. 21Ibid. 2 2 Ibid. 2 3A.R.A. Nicolas Piccaluga, Control Del Trafico Maritimo en el Atlantic Sud. Politics para la Defensa v Seguridad de las...1981. Piccaluga, A. R. A, Nicolis. Control Del Trafico Maritimo En El Atlantico Sud. Politicar, Para La Defensa Y Seguridad De Las Rutas Maritimas En

Systems of Ba(PO3)2-Sr(Pu3)2, Cd(PO3)2-Ca(PO3)2

International Nuclear Information System (INIS)

Tokman, I.A.; Bukhalova, G.A.

1977-01-01

Phase diagrams of the Ba(PO 3 ) 2 -Sr(PO 3 ) 2 and Cd(PO 3 ) 2 -Ca(PO 3 ) 2 systems have been studied and plotted by the methods of differential-thermal analysis (DTA), visual-polythermal, X-ray phase and infrared spectroscopy. The Ba(PO 3 ) 2 -Sr(PO 3 ) 2 system is of the eutectic type. In the binary system Cd(PO 3 ) 2 -Ca(PO 3 ) 2 the existence of a continuous series of solid solutions with a minimum at 858 deg C and 27.5 mol.% Ca(PO 3 ) 2 has been established

Optoelectronic Device Integration in Silicon (OpSIS)

Science.gov (United States)

2015-10-26

silicon-on-insulator," Opt. Express 22, 17872-17879 (2014) Y. Yang, C. Galland, Y. Liu, K. Tan , R. Ding, Q. Li, K. Bergman, T. Baehr-Jones, M...Jaeger, Nicolas AF; Chrostowski, Lukas; “Electrically tunable resonant filters in phase-shifted contra- directional couplers” IEEE Group IV Photonics... Nicolas AF; Chrostowski, Lukas; “Silicon photonic grating-assisted, contra-directional couplers” Optics express Vol. 21, No. 3; 3633-3650 (2013

Psychometric data concerning the Positive and Negative Affect Schedule – Direction (PANAS-D in athletes in Arabic-Tunisian language supporting a 2-factor structure of its short modified version

Directory of Open Access Journals (Sweden)

Sofiane Mnadla

2017-04-01

Full Text Available The Positive and Negative Affect Schedule – Direction (PANAS-D questionnaire was translated from the French version developed by Nicolas and coworkers into Arabic-Tunisian language and administered to a sample of 519 athletes (mean age 19.43±3.78 years; 230 male, 229 female; 75 competing at international level, 287 at national level, 130 at regional level, and 27 at local level. A semi-confirmatory factor analysis was carried out in order to shed light on the factor structure of the questionnaire. Different models were tested, including the 1-factor, the 2-factor and the 3-factor structure models, and compared in terms of fitting indexes. Data support a 2-factor solution of the modified short version of the PANAS-D questionnaire.

Methanesulfonates of high-valent metals. Syntheses and structural features of MoO_2(CH_3SO_3)_2, UO_2(CH_3SO_3)_2, ReO_3(CH_3SO_3), VO(CH_3SO_3)_2, and V_2O_3(CH_3SO_3)_4 and their thermal decomposition under N_2 and O_2 atmosphere

International Nuclear Information System (INIS)

Betke, Ulf; Neuschulz, Kai; Wickleder, Mathias S.

2011-01-01

Oxide methanesulfonates of Mo, U, Re, and V have been prepared by reaction of MoO_3, UO_2(CH_3COO)_2.2 H_2O, Re_2O_7(H_2O)_2, and V_2O_5 with CH_3SO_3H or mixtures thereof with its anhydride. These compounds are the first examples of solvent-free oxide methanesulfonates of these elements. MoO_2(CH_3SO_3)_2 (Pbca, a=1487.05(4), b=752.55(2), c=1549.61(5) pm, V=1.73414(9) nm"3, Z=8) contains [MoO_2] moieties connected by [CH_3SO_3] ions to form layers parallel to (100). UO_2(CH_3SO_3)_2 (P2_1/c, a=1320.4(1), b=1014.41(6), c=1533.7(1) pm, β=112.80(1) "c"i"r"c"l"e, V=1.8937(3) nm"3, Z=8) consists of linear UO_2"2"+ ions coordinated by five [CH_3SO_3] ions, forming a layer structure. VO(CH_3SO_3)_2 (P2_1/c, a=1136.5(1), b=869.87(7), c=915.5(1) pm, β=113.66(1) "c"i"r"c"l"e, V=0.8290(2) nm"3, Z=4) contains [VO] units connected by methanesulfonate anions to form corrugated layers parallel to (100). In ReO_3(CH_3SO_3) (P anti 1, a=574.0(1), b=1279.6(3), c=1641.9(3) pm, α=102.08(2), β=96.11(2), γ=99.04(2) "c"i"r"c"l"e, V=1.1523(4) nm"3, Z=8) a chain structure exhibiting infinite O-[ReO_2]-O-[ReO_2]-O chains is formed. Each [ReO_2]-O-[ReO_2] unit is coordinated by two bidentate [CH_3SO_3] ions. V_2O_3(CH_3SO_3)_4 (I2/a, a=1645.2(3), b=583.1(1), c=1670.2(3) pm, β=102.58(3), V=1.5637(5) pm"3, Z=4) adopts a chain structure, too, but contains discrete [VO]-O-[VO] moieties, each coordinated by two bidentate [CH_3SO_3] ligands. Additional methanesulfonate ions connect the [V_2O_3] groups along [001]. Thermal decomposition of the compounds was monitored under N_2 and O_2 atmosphere by thermogravimetric/differential thermal analysis and XRD measurements. Under N_2 the decomposition proceeds with reduction of the metal leading to the oxides MoO_2, U_3O_7, V_4O_7, and VO_2; for MoO_2(CH_3SO_3)_2, a small amount of MoS_2 is formed. If the thermal decomposition is carried out in a atmosphere of O_2 the oxides MoO_3 and V_2O_5 are formed. (Copyright copyright 2011 WILEY-VCH Verlag

Geochemical, petrographic and physical characterizations and associated alterations of the volcanic rocks of the Romanesque San Nicola Church (Ottana, central Sardinia, Italy)

Science.gov (United States)

Columbu, Stefano; Palomba, Marcella; Sitzia, Fabio

2015-04-01

In this research, the volcanic rocks belonging to the Sardinia Oligo-Miocene volcanic cycle (32 - 11 Ma) and building up the structure of the San Nicola church, one of the most representative churches of the Romanesque architecture, were studied. These stones were widely used in medieval architecture for the excellent workability, but they present some disadvantages, since they are greatly affected by alteration phenomena. The main objectives of this research are i) to focus the mineral, chemical and petrographic compositions of the San Nicola stones, ii) the chemical and physical alteration processes affecting these materials, and iii) to establish the exactly provenance of the volcanic rocks. Furthermore, a comparative study between the rocks from the ancient quarries and those forming the structure of the church was performed. In the ancient quarries, where presumably a more advanced alteration occurs due to the vertical alteration gradient, different facies of the same volcanic lithology, characterized by macroscopical evidences of chemical-physical degradation degree, were sampled. Petrographic, geochemical (both major elements that the traces) and physical-mechanical features of the collected samples were determined to highlight the compositional differences (density, porosity, water-absorption kinetics, mechanical resistance) as a function of the different alteration degree. Moreover, chemical-mineralogical analysis of the sample surfaces from the church, was performed, to highlight possible presence and nature of secondary newly-formed phases (e.g., salt efflorescence). Several methodologies were applied to carry out physical-chemical and petrographic analysis: X-Ray fluorescence (XRF) and Inductively Coupled Mass Spectrometry (ICP-MS), X-Ray Diffractometry (XRD) for chemical and mineral composition; Optical and Scanning Electron Microscopy (SEM) for textures, mineral assemblages and microstructures studies; He-picnometry, water-absorption and mechanical

Study with a steam tracer in a zone near well Az-64, in the Los Azufres geothermal field, Mich.; Estudio con un trazador de vapor en la zona aledana al pozo Az-64, en el campo geotermico de Los Azufres, Mich.

Energy Technology Data Exchange (ETDEWEB)

Iglesias, Eduardo R. [Instituto de Investigaciones Electricas, Cuernavaca, Morelos (Mexico)]. E-mail: iglesias@iie.org.mx; Flores Armenta, Magaly; Quijano Leon, Jose Luis; Torres Rodriguez, Marco A. [Comision Federal de Electricidad, Gerencia de Proyectos Geotermoelectricos, Morelia, Michoacan (Mexico); Torres, Rodolfo J.; Reyes Picasso, Neftali [Instituto de Investigaciones Electricas, Cuernavaca, Morelos (Mexico); Sandoval Medina, Fernando [Comision Federal de Electricidad, Gerencia de Proyectos Geotermoelectricos, Morelia, Michoacan (Mexico)

2009-01-15

A previous tracer study in the Maritaro-La Cumbre area of the Los Azufres, Mich., geothermal field concluded that injection in well Az-15 recharges a group of producing wells located east of the injector to a maximum distance of about 2000 m. The study also indicated injection in Az-15 either does not recharge wells farther east in the neighborhood of the Laguna Verde fault, or does so at very low rates over a long period. Because it is important to recharge this zone, it was decided to explore the possibility of doing it by injecting in well Az-64, located in the area. Thus the present study was designed. Six producing wells were chosen to monitor tracer arrivals. Because all the chosen wells produce steam (several also produce water) and for economic reasons, it was decided to use a steam-phase tracer. We chose sulfur hexafluoride (SF6), a tracer successfully used before in the field. On October 24, 2006, we injected 96.4 kg of SF6 into well Az-64. All six chosen wells were sampled for 156 days, starting the day of injection. The tracer was detected in all six wells and for every well the shape of the residence curve clearly depicted the fractured nature of the corresponding permeability. Again in every case, the recovery curves indicated recovery was completed within the 156-day sampling period. The largest recoveries were in wells Az-05 (48.5%) and Az-43 (1.27%), those closest to the injection well and on the same side of the Maritaro fault as Az-64. Well Az-51, lying at 848 m from the injector and farthest away, registered the third-highest recovery percentage (1.01 x 10-5%), significantly higher than well Az-19 (6.95 x 10-6%), located 490 m from the injector; the two wells are on the same side of the Maritaro fault as Az-64. Well Az-32, located 423 m from the injector, but on the other side of the Maritaro fault, recovered 5.6 x 10-7% of the injected tracer, comparable to 8.67 x 10-7%, the amount recovered in well Az-13 on the same side of the Maritaro fault

National Commission on the Structure of the Air Force: Report to the President and Congress of the United States

Science.gov (United States)

2014-01-30

August 20, 2013, with public hearing in Oklahoma City Alpena CRTC, Mich., September 13, 2013 Selfridge ANGB, Mich., September 14, 2013, with public...Colonel Bryan Teff (ANG), Commander, Alpena Combat Readiness Training Center, Michigan Colonel Sean Southworth (ANG), Commander, 217th Air Operations...Group, W.K. Kellogg ANGB, Michigan Lieutenant Colonel Matt Trumble (ANG), Director of Operations, Grayling Air Gunnery Range, Alpena Combat Readiness

A Hard Look at Hard Power: Assessing the Defense Capabilities of Key U.S. Allies and Security Partners

Science.gov (United States)

2015-07-01

as a means to reduce the public deficit. The third white paper was released in summer 2008 following Nicolas Sarkozy’s election as president the...Caroline Wyatt, “Crucial Role of Helicopters in Afghanis- tan ,” BBC News, March 2, 2010, available from news.bbc.co.uk/2/hi/ uk_news/8545695.stm. 35. It...September 18, 2014, available from aco.nato.int/general-breedlove-thanks-spain- for-patriot-commitment.aspx. 14. Edward Wong and Nicola Clark

Triggers of Chinese Economic Coercion

Science.gov (United States)

2014-09-01

2007 Angela Merkel–Dalai Lama Meeting ..............................70 2. The 2008 Nicolas Sarkozy–Dalai Lama Meeting ............................72 E...president Nicolas Sarkozy,35 Reilly nevertheless asserts that that while a mixture of statecraft tactics will continue, carrots are the first weapon of...144 Kim Tan and Anita O. Legaspi, “PHL Says It Will ‘Secure Sovereignty’ if Challenged by China,” GMA News Online, April

Illustrations

OpenAIRE

2016-01-01

Fig. 1 : Nicolas Poussin, Ravissement de saint Paul (version Scarron), Paris, musée du Louvre. Fig. 4 : Nicolas Poussin, Ravissement de saint Paul (version Scarron), restitution du format d’origine : environ 128 x 96 cm (détail de la fig. 1). Fig. 5 : Giovanni Lanfranco, Ravissement de la Madeleine, Naples, museo nazionale Capodimonte. Fig. 6 : Nicolas Poussin, Ravissement de saint Paul (version Chantelou), Sarasota, Ringling Museum of Art. Fig. 7 : Nicolas Poussin, Assomption, Paris, mus...

Comparison Of Six Extractants For Assessing Available Phosphorus ...

African Journals Online (AJOL)

... 0.01M CaCl2, Bray-1 and electro-ultra-filtration (EUF) technique] for simultaneous assessment of the availability of these nutrients in selected Nigerian soils was evaluated using guinea-corn (Sorghum bicolor) as test crop in Neubauer experiment. The respective average amounts of P, Zn and Mn extracted by 1N NH4OAc ...

2052-IJBCS-Article-Nicolas Kiye

African Journals Online (AJOL)

hp

chimiques (l'urée, le phosphate super tricalcique, le sulfate d'ammonium) ; des sachets polyéthylène de 3kg de capacité ; du tamis de 0,5mm de maille ; d'un spectrophotomètre DR/ 2000 ; d'une balance du type INCA de Lux de 5kg de capacité ; d'une balance de précision de type Mettler. 1509001. Les traitements suivants ...

Proceedings of the 12th European, Mediterranean & Middle Eastern Conference on Information Systems (EMCIS)

OpenAIRE

Lambrinoudakis Kostantinos, Morabito Vincenzo, Themistocleous Marinos

2015-01-01

Table of Contents Track – Cloud Computing 1. [PID-1] George Pittas, “THE USAGE OF SOCIAL MEDIA AS PART OF MARKETING PROMOTIONAL MIX” 2. [PID-5] Avraam Giogourtsoglou , “IoT AND CLOUD COMPUTING” 3. [PID-11] Giorgio De Michelis, Gianluigi Viscusi and Tiziano Salmi, “DRIFTING CLOUDS: A CASE STUDY OF IT TRANSFORMATION AT ENI” 4. [PID-65] Rania El-Gazzar and Fathul Wahid, “STRATEGIES FOR CLOUD COMPUTING ADOPTION: INSIGHTS FROM THE NORWEGIAN PUBLIC SECTOR” 5. [PID-100] Mi...

Pluriannual variability of sedimentation on mudflats in a macrotidal estuary

Science.gov (United States)

Cuvilliez, A.; Lafite, R.; Deloffre, J.; Massei, N.; Langlois, E.; Sakho, I.

2010-12-01

Antoine Cuvilliez1, Robert Lafite2, Julien Deloffre2, Nicolas Massei2, Estelle Langlois 3 and Issa Sakho2 1 Université du Havre, FRE 3102, Laboratoire d’ondes et milieux complexes, Université du Havre, 76058 Le Havre cedex, France 2 Université de Rouen, UMR 6143, Morphodynamique Continentale et Côtière, 76821 Mont Saint Aignan Cedex, France. 3 Université de Rouen, ECODIV , Etude et Compréhension de la Biodiversité, 76821 Mont Saint Aignan Cedex, France.

Validation of the sperm class analyser CASA system for sperm counting in a busy diagnostic semen analysis laboratory.

Science.gov (United States)

Dearing, Chey G; Kilburn, Sally; Lindsay, Kevin S

2014-03-01

Sperm counts have been linked to several fertility outcomes making them an essential parameter of semen analysis. It has become increasingly recognised that Computer-Assisted Semen Analysis (CASA) provides improved precision over manual methods but that systems are seldom validated robustly for use. The objective of this study was to gather the evidence to validate or reject the Sperm Class Analyser (SCA) as a tool for routine sperm counting in a busy laboratory setting. The criteria examined were comparison with the Improved Neubauer and Leja 20-μm chambers, within and between field precision, sperm concentration linearity from a stock diluted in semen and media, accuracy against internal and external quality material, assessment of uneven flow effects and a receiver operating characteristic (ROC) analysis to predict fertility in comparison with the Neubauer method. This work demonstrates that SCA CASA technology is not a standalone 'black box', but rather a tool for well-trained staff that allows rapid, high-number sperm counting providing errors are identified and corrected. The system will produce accurate, linear, precise results, with less analytical variance than manual methods that correlate well against the Improved Neubauer chamber. The system provides superior predictive potential for diagnosing fertility problems.

Ostrich: Journal of African Ornithology - Vol 86, No 1-2 (2015)

African Journals Online (AJOL)

Movement ecology of five Afrotropical waterfowl species from Malawi, Mali and Nigeria § · EMAIL FULL TEXT EMAIL FULL TEXT DOWNLOAD FULL TEXT DOWNLOAD FULL TEXT. John Y Takekawa, Shane R Heath, Samuel A Iverson, Nicolas Gaidet, Julien Cappelle, Tim Dodman, Ward Hagemeijer, William D Eldridge, ...

The melatonergic system: effects on sleep and implications for the treatment of psychiatric disorders

OpenAIRE

De Berardis, Domenico

2011-01-01

Domenico De Berardis1,2, Tiziano Acciavatti1, Giuseppe Di Iorio1, Mariangela Corbo1, Nicola Serroni2, Daniela Campanella2, Fabiola Di Emidio2, Monica Piersanti3, Marilde Cavuto4, Giovanni Martinotti5, Francesco Saverio Moschetta2, Massimo Di Giannantonio11Department of Neurosciences and Imaging, Chair of Psychiatry, University “G. D'Annunzio”, Chieti; 2NHS, Department of Mental Health, Psychiatric Service of Diagnosis and Treatment, Hospital “G. Mazzini&a...

Cationic polyhydrido cluster complexes. Crystal and molecular structures of (Ir3(Ph2P(CH2)3PPh2)3(H)7(CO))2+ and (Ir3(Ph2P(CH2)2(2-py))3(H)7)2+

International Nuclear Information System (INIS)

Hsienhau Wang; Casalnuovo, A.L.; Johnson, B.J.; Mueting, A.M.; Pignolet, L.H.

1988-01-01

Two new cationic polyhydrido cluster complexes of iridium have been synthesized and characterized by single-crystal x-ray diffraction and by ir and 1 H and 31 P NMR spectroscopy (Ir 3 (dppp) 3 (H) 7 (CO)) 2+ (2) and (Ir3 (PN) 3 (H) 7)2+ (5), where dppp = 1,3-bis(diphenylphosphino)propane and PN = 1-(2-pyridyl)-2-(diphenylphosphino)ethane, were synthesized by the reaction of CO with (Ir 3 (dppp) 3 (H) 7 ) 2+ (1) in CH 2 Cl 2 solution and H 2 with (Ir(PN)(COD)) + (4) in CH 3 OH solution, respectively. Crystal structures for both compounds is reported. The hydride positions were not located in the crystal structure analyses but were deduced from structural and 1 H NMR data. The molecular structure of 2 consists of a bilateral triangle of three iridium atoms with a carbonyl at the vertex and a chelating dppp ligand on each iridium atom. 1 H NMR data with use of acetone-d 6 as solvent showed that 2 possesses four doubly bridging hydrides and three terminal hydrides, yielding C 1 symmetry. The molecular structure of 5 consists of an approximately equilateral triangle of three iridium atoms (average Ir-Ir distance 2.746 (1) angstrom) with one PN ligand chelated to each iridium atom. 1 H NMR analysis, with use of CD 2 Cl 2 as solvent, showed that 5 has one triply bridging hydride and six terminal hydrides, giving C 3 symmetry. (Ir 3 (dppp) 3 (H) 7 (CH 3 C 6 H 4 NC)) 2+ (3) a complex structurally analogous to 2, was synthesized from 1 and p-tolyl isocyanide in CH 2 Cl 2 solution and characterized by ir and 1 H and 31 P NMR spectroscopy. 44 refs., 3 figs., 3 tabs

AVALIAÇÃO DA ATIVIDADE DE TRÊS COMPOSTOS DO ÓLEO DE MELALEUCA SOBRE O Trypanosoma evansi

OpenAIRE

Matheus Dellaméa Baldissera

2016-01-01

O objetivo deste estudo foi avaliar a atividade tripanocida do terpinen-4-ol, gama-(γ)-terpinen e alfa-(α)-terpinen contra o Trypanosoma evansi in vitro e in vivo. Os testes in vitro foram realizados em meio de cultura contendo T. evansi, utilizando-se três concentrações de cada composto (0.5, 1.0 e 2.0%) de forma individual e em associação. A contagem de tripomastigotas vivas foi realizada em câmara de Neubauer após 1, 3, 6 e 9 horas pós-incubação. A partir dos testes in vitro, foi...

Eine neue Tornaria aus dem Ostindischen Archipel (Tornaria Sunieri)

NARCIS (Netherlands)

Stiasny, G.

1921-01-01

Da aus dem malayischen Archipel durch die Siboga-Monographie Spengels (2) zwar eine Anzahl Enteropneusten, jedoch nur eine einzige Tornaria bekannt worden ist, war anzunehmen, dass noch andere Tornarien in diesem Gebiete nachzuweisen sein würden. Von dieser Erwartung ausgehend wandte ich mich an

Inhibition of Androgen-Independent Growth of Prostate Cancer by siRNA- Mediated Androgen Receptor Gene Silencing

Science.gov (United States)

2008-02-01

and then photographed using a digital camera . AAV production and infection. To silence AR gene expression, a hairpin- structured expression vector...Sandusky GE, Vessella RL, Neubauer BL. Increased AKT activity contributes to prostate cancer progression by dramatically accelerating prostate tumor...HeNe laser. The spectrograph has an f/2.0 Czerny–Turner imaging spec- trometer plus a thermo-electrically cooled Kodak 0401 CCD camera . The fiberoptic

An Optimal Dissipative Encoder for the Toric Code

Science.gov (United States)

2014-01-16

Topological quantummemory J. Math. Phys. 43 4452–505 [6] Diehl S, Micheli A, Kantian A, Kraus B, Büchler H P and Zoller P 2008 Quantum states and phases in...Diehl S, Kantian A, Micheli A and Zoller P 2008 Preparation of entangled states by quantum Markov processes Phys. Rev. A 78 042307 [12] Marvian I 2013...Information Theory (Cambridge: Cambridge University Press) [20] Wolf M and Cirac J I 2008 Dividing quantum channels Commun. Math. Phys. 279 147 11

Endocrine Pancreas Regeneration

Science.gov (United States)

2010-06-01

conditions and then counted using Neubauer Hemocytometer (Hausser Scientific, Horsham, A), as previously published [4,25]. .3. UASMC Ki-67 staining As another...digital camera and interfaced with a computer. . Statistical analysis Results from each experiment were averaged and xpressed as mean± S.D. Comparisons...Images were captured by a Photometrics Cool SNAP digital camera (Roper Scientific, Tucson, AZ) and Nikon C1 confocal system at 40× objective lens and

Behavior patterns of chemical and isotopic species (2006-2007) in the Los Azufres, Mich., geothermal field, as a response to reinjection; Patrones de comportamiento de especies quimicas e isotopicas (2006-2007) en el campo geotermico de Los Azufres, Mich., en respuesta a la reinyeccion

Energy Technology Data Exchange (ETDEWEB)

Barragan R, Rosa Maria; Arellano G, Victor Manuel; Martinez E, Ignacio; Aragon A, Alfonso [Instituto de Investigaciones Electricas, Cuernavaca, Morelos (Mexico)]. E-mail: rmb@iie.org.mx; Reyes D, Lisette; Gonzalez, Rubi [Comision Federal de Electricidad, Gerencia de Proyectos Geotermoelectricos, Residencia de Los Azufres, Morelia, Michoacan (Mexico)

2009-07-15

quimicos e isotopicos ({delta}18 O y {delta}D) de fluidos de pozos del campo geotermico de Los Azufres, Mich., obtenidos en 2006 y 2007, para investigar los cambios ocurridos en sus patrones de comportamiento y su relacion con el proceso de reinyeccion de fluidos al yacimiento. El analisis de los datos comprendio las estimaciones de cloruros en las descargas totales, temperaturas de yacimiento, exceso de vapor en los fluidos de alimentacion, las concentraciones de CO{sub 2} en las descargas totales y en la fase liquida del yacimiento y las saturaciones de liquido en la formacion. Con los resultados se elaboraron mapas de isovalores de los parametros mencionados correspondientes a 2006 y 2007 para investigar su evolucion con respecto a los mapas obtenidos en 2005, asi como su relacion con las historias de reinyeccion. Se correlacionaron las composiciones isotopicas de los fluidos incluyendo los de reinyeccion para estimar efectos de mezcla de fluidos. Los resultados indican que las variables estudiadas responden a las tasas de reinyeccion en el campo. Las relaciones {delta}D vs {delta}18 O indican que un buen numero de pozos del campo producen diferentes proporciones de retornos de reinyeccion; en la zona norte los pozos AZ-65D, AZ-13, AZ-32, AZ-9A, AZ-9AD, AZ-28A, AZ-69D y AZ-44 producen una mayor proporcion mientras que los pozos AZ-5, AZ-28 y AZ-19 entre otros, producen una menor proporcion. En la zona sur los pozos AZ-2A, AZ-16AD, AZ-46 y AZ-33 producen relativamente altas proporciones de retornos de reinyeccion mientras que los pozos AZ-34, AZ-36 y AZ-37 producen menores proporciones. La distribucion de saturaciones de liquido hallada en 2007 muestra que las areas de maxima saturacion han disminuido con respecto a las distribuciones de este parametro en 2005 y 2006. En 2007 las saturaciones maximas de liquido se localizaron alrededor de los pozos AZ-22 y AZ-23 (zona sur) y AZ-28, AZ-32, AZ-45 y AZ-48 (zona norte), mientras que las saturaciones minimas se localizaron en

Study into non-quasibinary sections of Pr2S3-Bi2S3-Pr2O3 triple system (Bi2S3)0. 45(Pr2O3)0. 55 - (Bi2S3)0. 45(Pr2S3)0. 55 and (Bi2S3)0. 75 (Pr2S3)0. 25 - (Bi2S3)0. 75(Pr2O3)0. 25

OpenAIRE

НЕЙМАТОВА А.В.; МАМЕДОВ Ф.М.; БАХТИЯРЛЫ И.Б.

2016-01-01

Методами дифференциальнo-термическoго (ДТ), рентгенофазового (РФ), микроструктурного (МС) методов анализа исследованы неквазибинарные разрезы (Bi2S3)0.45(Pr2O3)0.55 (Bi2S3)0.45(Pr2S3)0.55 и (Bi2S3)0.75 (Pr2S3)0.25 (Bi2S3)0.75(Pr2O3)0.25 тройной системы Pr2S3-Bi2S3-Pr2O3 построена диаграмма состояния, определены координанты нони моновариантныхравновесий....

Nicolae Milescu Spătarul - ancestor of a Nobel Laureate - Ilia I. Mecinikov. Part II. Ilia I. Mecinikov’s life and scientific work; 16th of May 2011 - 166 years since the birth of the European scholar; 15th of July 2011 - 95 years since death

Directory of Open Access Journals (Sweden)

Dan RIGA

2011-01-01

Full Text Available The work showcases the promotion of Romanian lineage - Nicolae Milescu Spătarul (1636-1708 as ancestor of scientist Ilia Ilici Mecinikov (1845-1916, Nobel Laureate (1908.A great figure in world science and bio-medicine, the scientist - creator of two new modernsciences (immunology and gerontology – is claimed and honoured by four nations: Israeli, French,Russian and Ukrainian. Despite his known Romanian descent on his paternal side – biographicallyconsecrated by his wife Olga Mecinikov – Romania has pushed him into oblivion, by not promotingthis historical truth and reality to all.In our country, Prof. Dr. doc. Ilie Th. Riga (1908-1977 publishes in 1930, in the Romanianmagazine, Natura (Nature, Originea românească a lui Metchnikoff (Metchnikoff’s Romanianorigins. In the 2007-2011 period, two of the authors of the work continuously publish, in thecountry and abroad, thus creating Dosarul ascendenţei româneşti al lui Mecinikov (Mecinikov’sfile on his Romanian lineage, for the global informational civilization. They published their worksin printed version: in scientific magazines (2007, 2011, in their own monograph Medicina antiîmbătrânireşi ştiinţele longevităţii (Anti-aging Medicine and Longevity Sciences, (2007, innewspapers Ziua USA (The Day - USA, (2008 and Clipa. Magazinul Actualităţii CulturaleRomâneşti (The Moment. The Romanian Cultural Current Affairs Magazine, (2011, inEnciclopedia medicală Românească (Encyclopaedia of Romanian Medicine, (2009 and also onSorin Riga, Dan Riga, Vasile Man - Nicolae Milescu Spătarul - ancestor of a Nobel Laureate - Ilia I. Mecinikov...250webpages (the online era: www.DacoRomanica.ro (2010, www.revista-studii-uvvg.ro (2011,www.ziuausa.com (2008, www.revistaclipa.com (2011, taken over by other internet websites.

La Vie de Marillac : un essai hagiographique ? Analyse comparée des sources utilisées par Nicolas Lefèvre de Lezeau dans la Vie de Marillac et la Vie de Morvillier

Directory of Open Access Journals (Sweden)

Dora De Lima

2012-01-01

Full Text Available Considérer Nicolas Lefèvre de Lezeau comme le biographe de son grand oncle ou comme l’hagiographe de son ami Michel de Marillac revient à glorifier la mémoire des trois héros au détriment du projet d’écriture de l’auteur. La Vie de Jean de Morvillier et la Vie de Michel de Marillac sont vivement marquées par l’omniprésence de leur auteur, quand bien même l’illusion de la richesse documentaire sur les trois héros voudrait l’estomper. Parce qu’ils convoquent une documentation riche et de nombreuses références littéraires, les trois récits de vie retrouvés témoignent d’une quête d’authenticité par leur auteur. En ce sens, la Vie de Marillac se dégage des deux autres récits de vie écrits par Lezeau. Le conseiller d’état n’y cherche effectivement pas seulement à raviver la mémoire de la Ligue dans le milieu dévot, ni même à construire une filiation entre ces deux partis. L’originalité de la Vie de Marillac tient de l’abondance des références spirituelles et de l’autorité que les mystiques incarnent pour sa validation. Pour les mystiques, la vie chargée d’un officier d’état demeure incompatible avec le mode de vie humble et contemplatif d’un « petit ». Du côté des politiques, la « cabale des dévots » représente une menace croissante pour l’autorité du roi. Dès lors, la Vie de Marillac de Lezeau nous invite à réfléchir sur les caractéristiques de rejet d’un modèle de sainteté (E. Suire. La postérité retient Marillac pour sa témérité et sa faillite face à la raison d’état de Richelieu, comme l’attestent le peu de biographies des xixe-xxe siècles de ce garde des sceaux. Parallèlement, si Marillac est décrit comme un laïc ayant fait preuve d’une grande dévotion dans les Histoires de l’ordre des Carmélites déchaussées parues aux xixe et xxe siècles, sa part active à la fondation de l’ordre en France ne suffit pas à faire de lui un saint

Multimediale Kommunikationsarchitekturen: Herausforderungen und Weiterentwicklungen der Forschungen im Kulturraum Internet

Directory of Open Access Journals (Sweden)

Winfried Marotzki

2008-04-01

Full Text Available Im Folgenden setze ich mich mit der Frage auseinander, wie der sich rasch verändernde kulturelle Raum Internet forschungsmässig zu erschliessen ist. Dabei möchte ich weniger den aktuellen Stand der Internet Forschung bilanzieren, das ist durch verschiedene einschlägige Publikationen bereits geschehen. Vielmehr werde ich mich darauf konzentrieren, die Hauptveränderungen des Internet in den letzten Jahren zu skizzieren, um daran anknüpfend einige ausgewählte methodische Probleme, die damit verbunden sind, zu bearbeiten.

Activity of cyclosporine ® against Schistosoma mansoni cercariae ...

African Journals Online (AJOL)

Farin Gada, Jos, Plateau State), examined for cercariae by exposure to sunshine for 30 minutes andcercariae obtained were estimated using Neubauer's counting chamber before toxicity test was conducted. The schistosomicidal properties of ...

Symposium DD: Low-Dimensional Materials-Synthesis, Assembly, Property Scaling and Modeling. Held in San Francisco, CA on April 9-13, 2007

Science.gov (United States)

2008-06-01

Ciencia e Ingenieria de los Materiales , Universidad de Costa Rica, San Jose, Costa Rica. We have developed a new unifying tight-binding theory that...Fisico Matem6ticas, Universidad Aut6noma de Nuevo Le6n, San Nicolas de los Garza, Nuevo LeAfA3n, Mexico; 2Chemical Engineering Department and Texas...ORNL), Oak Ridge, Tennessee; 2Departamento de Ciencia de los Materiales e IM y QI, Universidad de Cadiz, Puerto Real, Cadiz, Spain; 3Departamento de

Partial response to proton pump inhibitor therapy for GERD: observational study of patient characteristics, burden of disease, and costs in the USA

OpenAIRE

St?lhammar, Nils-Olov; Spiegel, Brennan M; Granstedt L?fman, Helena; Karlsson, Maria; Wahlqvist, Peter; N?sdal, J?rgen; Nelson, M Todd; Despi?gel, Nicolas

2012-01-01

Nils-Olov Stålhammar,1 Brennan M Spiegel,2,3 Helena Granstedt Löfman,1 Maria Karlsson,1 Peter Wahlqvist,1 Jørgen Næsdal,4 M Todd Nelson,5 Nicolas Despiégel61Payer Evidence, AstraZeneca R&D, Mölndal, Sweden; 2Department of Gastroenterology, VA Greater Los Angeles Healthcare System, 3David Geffen School of Medicine at UCLA, Los Angeles, CA, USA; 4Medical Department, AstraZeneca R&D, Mölndal, Sweden; 5Late Phase...

3-[2-(1,3-Benzothiazol-2-ylsulfanylethyl]-1,3-oxazolidin-2-one

Directory of Open Access Journals (Sweden)

Yong-Hong Wen

2010-10-01

Full Text Available The title compound, C12H12N2S2O2, consists of a benzothiazole group and a oxazolidin-1-one linked via a flexible ethane-1,2-diyl spacer. The benzothiazole group and the oxazolidine ring are each almost planar [with maximum deviations of 0.007 (2 and 0.044 (3 Å, respectively] and make a dihedral angle of 9.35 (10°. In the crystal structure, adjacent molecules were connected through C—H...O and C—H...N hydrogen bonds, and further extended into a three-dimensional network structure through intermolecular aromatic π–π stacking interactions in which the centroid–centroid distance is 3.590 (1 Å.

The uranium(VI) oxoazides [UO{sub 2}(N{sub 3}){sub 2}.CH{sub 3}CN], [(bipy){sub 2}(UO{sub 2}){sub 2}(N{sub 3}){sub 4}], [(bipy)UO{sub 2}(N{sub 3}){sub 3}]{sup -}, [UO{sub 2}(N{sub 3}){sub 4}]{sup 2-}, and [(UO{sub 2}){sub 2}(N{sub 3}){sub 8}]{sup 4-}

Energy Technology Data Exchange (ETDEWEB)

Haiges, Ralf; Christe, Karl O. [Loker Hydrocarbon Research Institute and Department of Chemistry, University of Southern California, Los Angeles, CA (United States); Vasiliu, Monica; Dixon, David A. [Department of Chemistry, The University of Alabama, Tuscaloosa, AL (United States)

2017-01-12

The reaction between [UO{sub 2}F{sub 2}] and an excess of Me{sub 3}SiN{sub 3} in acetonitrile solution results in fluoride-azide exchange and the uranium(VI) dioxodiazide adduct [UO{sub 2}(N{sub 3}){sub 2}.CH{sub 3}CN] was isolated in quantitative yield. The subsequent reaction of [UO{sub 2}(N{sub 3}){sub 2}.CH{sub 3}CN] with 2,2{sup '}-bipyridine (bipy) resulted in the formation of the azido-bridged binuclear complex [(bipy){sub 2}(UO{sub 2}){sub 2}(N{sub 3}){sub 4}]. The triazido anion [(bipy)UO{sub 2}(N{sub 3}){sub 3}]{sup -} was obtained by the reaction of [UO{sub 2}(N{sub 3}){sub 2}.CH{sub 3}CN] with stoichiometric amounts of bipy and the ionic azide [PPh{sub 4}][N{sub 3}]. The reaction of [UO{sub 2}(N{sub 3}){sub 2}] with two equivalents of the [PPh{sub 4}][N{sub 3}] resulted in the formation of the mononuclear tetraazido anion [UO{sub 2}(N{sub 3}){sub 4}]{sup 2-} as well as the azido-bridged binuclear anion [(UO{sub 2}){sub 2}(N{sub 3}){sub 8}]{sup 4-}. The novel uranium oxoazides were characterized by their vibrational spectra and in the case of [(bipy){sub 2}(UO{sub 2}){sub 2}(N{sub 3}){sub 4}].CH{sub 3}CN, [PPh{sub 4}][(bipy)UO{sub 2}(N{sub 3}){sub 3}], [PPh{sub 4}]{sub 2}[UO{sub 2}(N{sub 3}){sub 4}], [PPh{sub 4}]{sub 2}[UO{sub 2}(N{sub 3}){sub 4}].2CH{sub 3}CN, and [PPh{sub 4}]{sub 4}[(UO{sub 2}){sub 2}(N{sub 3}){sub 8}].4CH{sub 3}CN by their X-ray crystal structures. (copyright 2017 Wiley-VCH Verlag GmbH and Co. KGaA, Weinheim)

Fragrance material review on 3-methyl-5-(2,2,3-trimethyl-3-cyclopenten-1-yl)pent-3-en-2-one.

Science.gov (United States)

Scognamiglio, J; Letizia, C S; Api, A M

2013-12-01

A toxicologic and dermatologic review of 3-methyl-5-(2,2,3-trimethyl-3-cyclopenten-1-yl)pent-3-en-2-one when used as a fragrance ingredient is presented. 3-Methyl-5-(2,2,3-trimethyl-3-cyclopenten-1-yl)pent-3-en-2-one is a member of the fragrance structural group Alkyl Cyclic Ketones. These fragrances can be described as being composed of an alkyl, R1, and various substituted and bicyclic saturated or unsaturated cyclic hydrocarbons, R2, in which one of the rings may include up to 12 carbons. Alternatively, R2 may be a carbon bridge of C2-C4 carbon chain length between the ketone and cyclic hydrocarbon. This review contains a detailed summary of all available toxicology and dermatology papers that are related to this individual fragrance ingredient and is not intended as a stand-alone document. Available data for 3-methyl-5-(2,2,3-trimethyl-3-cyclopenten-1-yl)pent-3-en-2-one were evaluated then summarized and includes physical properties, acute toxicity, skin irritation, mucous membrane (eye) irritation, sensitization, phototoxicity, photoallergy, and genotoxicity data. A safety assessment of the entire Alkyl Cyclic Ketones will be published simultaneously with this document; please refer to Belsito et al. (Belsito, D., Bickers, D., Bruze, M., Calow, P., Dagli, M., Fryer, A.D., Greim, H., Miyachi, Y., Saurat, J.H., Sipes, I.G., 2013. A Toxicologic and Dermatologic Assessment of Alkyl Cyclic Ketones when used as fragrance ingredients. Submitted for publication) for an overall assessment of the safe use of this material and all Alkyl Cyclic Ketones in fragrances. Copyright © 2013 Elsevier Ltd. All rights reserved.

The synthesis of [2-3H2] taurine and [2-3H2] hypotaurine

International Nuclear Information System (INIS)

Fellman, J.H.

1981-01-01

The synthesis of [2- 3 H 2 ]-2-aminoethanesulfonate [2- 3 H]-taurine by the reduction of cyanomethanesulfonic acid with tritium gas is described. The conversion of [2- 3 H]-taurine and its 14 C and 35 S isotopic forms to 2-aminoethanesulfinate (hypotaurine) was accomplished by converting taurine to its corresponding sulfonyl chloride and reducing the latter with metallic zinc. (author)

Influencia del Pseudo Dionisio en Nicolás de Cusa

Directory of Open Access Journals (Sweden)

Andrés Hubert R

2007-01-01

Full Text Available Nicolás de Cusa (1401-1464 reconoce la influencia del Pseudo Dionisio en su propio pensamiento, especialmente en su teología negativa. Este trabajo busca mostrar esta influencia en el libro referencia del Cusano: el De Docta Ignorantia (la Docta Ignorancia. Esta obra consta de 3 partes. Solo en la primera parte, Nicolás sigue de cerca las ideas del Pseudo Dionisio y solo en ella lo cita. En las demás, aunque se nota la influencia, nuestro autor se siente más libre: las fundaciones están firmes, el constructor puede construir libremente. Para probar esta tesis, se toman dos ejemplos: el tema de las tinieblas y la coincidencia de los opuestos. Este ejercicio permite conocer cómo y por qué se recibió al Pseudo Dionisio en la historia de la teología. Permite también profundizar el sentido de la teología de Nicolás de CusaThe reflections of Nicolas of Cusa (1401-1464 recognise the influence of Pseudo Dyonisius, particularly in his negative theology. The present study shows this influence on Nicolas' most important book: the De Docta Ignorantia (the Learned Ignorance. The book is divided into three parts and it is in the first part that Nicolas directly pursues the ideas of Pseudo Dyonisius and it is only here that he quotes them. In the other parts of the book although the influence is noted, the foundations have been set and are solid and the author or builder can construct with freedom. To prove this thesis, 2 examples are presented: the theme of darkness and the coincidence of opposites. This exercise shows how and why Pseudo Dyonisius has been accepted into the history of the theology. It also deepens the meaning of the Nicolas of Cusa's theology

Raman and Fluorescence Spectroscopy of CeO2, Er2O3, Nd2O3, Tm2O3, Yb2O3, La2O3, and Tb4O7

Directory of Open Access Journals (Sweden)

Jianlan Cui

2015-01-01

Full Text Available To better understand and ascertain the mechanisms of flotation reagent interaction with rare earth (RE minerals, it is necessary to determine the physical and chemical properties of the constituent components. Seven rare earth oxides (CeO2, Er2O3, Nd2O3, Tm2O3, Yb2O3, La2O3, and Tb4O7 that cover the rare earth elements (REEs from light to heavy REEs have been investigated using Raman spectroscopy. Multiple laser sources (wavelengths of 325 nm, 442 nm, 514 nm, and 632.8 nm for the Raman shift ranges from 100 cm−1 to 5000 cm−1 of these excitations were used for each individual rare earth oxide. Raman shifts and fluorescence emission have been identified. Theoretical energy levels for Er, Nd, and Yb were used for the interpretation of fluorescence emission. The experimental results showed good agreement with the theoretical calculation for Er2O3 and Nd2O3. Additional fluorescence emission was observed with Yb2O3 that did not fit the reported energy level diagram. Tb4O7 was observed undergoing laser induced changes during examination.

(E-3-Methyl-6-(3-oxo-3-(thiophen-2-yl-1-propenyl-2(3H-benzothiazolone

Directory of Open Access Journals (Sweden)

Yordanka Ivanova

2016-04-01

Full Text Available The title compound, (E-3-methyl-6-(3-oxo-3-(thiophen-2-yl-1-propenyl-2(3H-benzothiazolone, was synthesized by Claisen-Schmidt condensation of 3-methyl-2(3H-benzothiazolone-6-carbaldehyde with 2-acetylthiophene in 94% yield. The structure of the target compound was confirmed using 1H-NMR, 13C-NMR, IR, MS, and elemental analysis.

Facet-dependent study of efficient growth of graphene on copper by ...

Indian Academy of Sciences (India)

faster on Cu(111) than on Cu(100).16 Different shapes,8,17,18 such as tetragonal .... (c) Optical micrograph of a graphene film on a SiO2/Si substrate; dotted line ..... Coraux J, N'Diaye A T, Busse C and Michely T 2008 Nano. Lett. 8 565. 4.

A multi-century analysis of disturbance dynamics in pine-oak forests of the Missouri Ozark Highlands

Science.gov (United States)

Chad King; Rose-Marie. Muzika

2013-01-01

Using dendrochronology and growth release approaches, we analyzed the disturbance history of shortleaf pine (Pinus echinata Mich.) white oak (Quercus alba L.) forests in the Missouri Ozark Highlands. The objectives of this study were to (1) identify growth release events using living and remnant shortleaf pine and white oak, (2)...

Bis{(E-3-[2-(hydroxyiminopropanamido]-2,2-dimethylpropan-1-aminium} bis[μ-(E-N-(3-amino-2,2-dimethylpropyl-2-(hydroxyiminopropanamido(2−]bis{[(E-N-(3-amino-2,2-dimethylpropyl-2-(hydroxyiminopropanamide]copper(II} bis((E-{3-[2-(hydroxyiminopropanamido]-2,2-dimethylpropyl}carbamate acetonitrile disolvate

Directory of Open Access Journals (Sweden)

Andrii I. Buvailo

2012-12-01

Full Text Available The reaction between copper(II nitrate and (E-N-(3-amino-2,2-dimethylpropyl-2-(hydroxyiminopropanamide led to the formation of the dinuclear centrosymmetric copper(II title complex, (C8H18N3O22[Cu2(C8H15N3O22(C8H17N3O22](C9H16N3O42·2CH3CN, in which an inversion center is located at the midpoint of the Cu2 unit in the center of the neutral [Cu2(C8H15N3O22(C8H17N3O22] complex fragment. The Cu2+ ions are connected by two N—O bridging groups [Cu...Cu separation = 4.0608 (5 Å] while the CuII ions are five-coordinated in a square-pyramidal N4O coordination environment. The complex molecule co-crystallizes with two molecules of acetonitrile, two molecules of the protonated ligand (E-3-[2-(hydroxyiminopropanamido]-2,2-dimethylpropan-1-aminium and two negatively charged (E-{3-[2-(hydroxyiminopropanamido]-2,2-dimethylpropyl}carbamate anions, which were probably formed as a result of condensation between (E-N-(3-amino-2,2-dimethylpropyl-2-(hydroxyiminopropanamide and hydrogencarbonate anions. In the crystal, the complex fragment [Cu2(C8H15N3O22(C8H17N3O22] and the ion pair C8H18N3O2+.C9H16N3O4− are connected via an extended system of hydrogen bonds.

Luminescence and energy transfer of Tb3+-doped BaO-Gd2O3-Al2O3-B2O3-SiO2 glasses.

Science.gov (United States)

Zuo, Chenggang; Huang, Jinze; Liu, Shaoyou; Xiao, Anguo; Shen, Youming; Zhang, Xiangyang; Zhou, Zhihua; Zhu, Ligang

2017-12-05

Transparent Tb 3+ -doped BaO-Gd 2 O 3 -Al 2 O 3 -B 2 O 3 -SiO 2 glasses with the greater than 4g/cm 3 were prepared by high temperature melting method and its luminescent properties have been investigated by measured UV-vis transmission, excitation, emission and luminescence decay spectra. The transmission spectrum shows there are three weak absorption bands locate at about 312, 378 and 484nm in the glasses and it has good transmittance in the visible spectrum region. Intense green emission can be observed under UV excitation. The effective energy transfer from Gd 3+ ion to Tb 3+ ion could occur and sensitize the luminescence of Tb 3+ ion. The green emission intensity of Tb 3+ ion could change with the increasing SiO 2 /B 2 O 3 ratio in the borosilicate glass matrix. With the increasing concentration of Tb 3+ ion, 5 D 4 → 7 F J transitions could be enhanced through the cross relaxation between the two nearby Tb 3+ ions. Luminescence decay time of 2.12ms from 546nm emission is obtained. The results indicate that Tb 3+ -doped BaO-Gd 2 O 3 -Al 2 O 3 -B 2 O 3 -SiO 2 glasses would be potential scintillating material for applications in X-ray imaging. Copyright © 2017 Elsevier B.V. All rights reserved.

2-(2,3-Dihydro-1H-indol-3-yl)ethanol

DEFF Research Database (Denmark)

Frydenvang, Karla Andrea; Sommer, Michael Bech; Heckmann, Dieter

2004-01-01

The first direct resolution of racemic 2-(2,3-dihydro-lH-indol-3-yl)ethanol-prepared by catalytic hydrogenation of 2-(lH-indol-3-yl)ethanol-has been accomplished by chiral simulated moving bed (SMB) chromatography. The single enantiomers were isolated as their dihydrogen phosphate salts. Single......-crystal X-ray analyses were successful, revealing that the (+)-enantiomer of 2-(2,3-dihydro-lH-indol-3-yl)ethanol has the (S) configuration. Chirality 16:126-130, 2004....

3D hybrid simulation of the Titan's plasma environment

Science.gov (United States)

Lipatov, Alexander; Sittler, Edward, Jr.; Hartle, Richard

2007-11-01

Titan plays an important role as a simulation laboratory for multiscale kinetic plasma processes which are key processes in space and laboratory plasmas. A development of multiscale combined numerical methods allows us to use more realistic plasma models at Titan. In this report, we describe a Particle-Ion--Fluid-Ion--Fluid--Electron method of kinetic ion-neutral simulation code. This method takes into account charge-exchange and photoionization processes. The model of atmosphere of Titan was based on a paper by Sittler, Hartle, Vinas et al., [2005]. The background ions H^+, O^+ and pickup ions H2^+, CH4^+ and N2^+ are described in a kinetic approximation, where the electrons are approximated as a fluid. In this report we study the coupling between background ions and pickup ions on the multiple space scales determined by the ion gyroradiis. The first results of such a simulation of the dynamics of ions near Titan are discussed in this report and compared with recent measurements made by the Cassini Plasma Spectrometer (CAPS, [Hartle, Sittler et al., 2006]). E C Sittler Jr., R E Hartle, A F Vinas, R E Johnson, H T Smith and I Mueller-Wodarg, J. Geophys. Res., 110, A09302, 2005.R E Hartle, E C Sittler, F M Neubauer, R E Johnson, et al., Planet. Space Sci., 54, 1211, 2006.

On D=2 (1/3,1/3) supersymmetric theories 2

International Nuclear Information System (INIS)

Saidi, E.H.; Zerouaoui, J.; Sedra, M.B.

1994-06-01

Denoting by D=2 (1/3,1/3) superalgebra; the off critical symmetry of the Φ 5/7,5/7 perturbation of the C=6/7 conformal theory, we build a new superspace solution of the (1/3,1/3) - subalgebra generated by spin ±1/3 charge operators extending the usual (1/2,1/2) supersymmetry generated by spin ±1/2 charges. This solution is based on the use of two Grassmann variables instead of one parafermionic variable θ ±1/3 satisfying the cubic nilpotency condition (θ ±1/3 ) 3 =0. Known results on the C=6/7 tricritical Potts model are recovered as special features. A relation with N=2 Landau-Ginzburg models is also discussed. (author). 17 refs, 1 tab

Formation of ternary CaUO2(CO3)3(2-) and Ca2UO2(CO3)3(aq) complexes under neutral to weakly alkaline conditions.

Science.gov (United States)

Lee, Jun-Yeop; Yun, Jong-Il

2013-07-21

The chemical behavior of ternary Ca-UO2-CO3 complexes was investigated by using time-resolved laser fluorescence spectroscopy (TRLFS) in combination with EDTA complexation at pH 7-9. A novel TRLFS revealed two distinct fluorescence lifetimes of 12.7 ± 0.2 ns and 29.2 ± 0.4 ns for uranyl complexes which were formed increasingly dependent upon the calcium ion concentration, even though nearly indistinguishable fluorescence peak shapes and positions were measured for both Ca-UO2-CO3 complexes. For identifying the stoichiometric number of complexed calcium ions, slope analysis in terms of relative fluorescence intensity versus calcium concentration was employed in a combination with the complexation reaction of CaEDTA(2-) by adding EDTA. The formation of CaUO2(CO3)3(2-) and Ca2UO2(CO3)3(aq) was identified under given conditions and their formation constants were determined at I = 0.1 M Na/HClO4 medium, and extrapolated to infinitely dilute solution using specific ion interaction theory (SIT). As a result, the formation constants for CaUO2(CO3)3(2-) and Ca2UO2(CO3)3(aq) were found to be log β113(0) = 27.27 ± 0.14 and log β213(0) = 29.81 ± 0.19, respectively, providing that the ternary Ca-UO2-CO3 complexes were predominant uranium(vi) species at neutral to weakly alkaline pH in the presence of Ca(2+) and CO3(2-) ions.

Potassium vanadium selenite, K(VO2)3(SeO3)2

International Nuclear Information System (INIS)

Harrison, W.T.A.; Dussack, L.L.; Jacobson, A.J.

1995-01-01

The hydrothermal synthesis and single-crystal structure of potassium vanadium(V) selenite, K(VO 2 ) 3 (SeO 3 ) 2 , are reported. K(VO 2 ) 3 (SeO 3 ) 2 is a layered phase based on a hexagonal tungsten-oxide-like array of corner-sharing VO 6 octahedra capped by Se atoms, and is isostructural with NH 4 (VO 2 ) 3 (SeO 3 ) 2 . (orig.)

Toetust kaotav Sarkozy võib varsti taas abielluda / Hendrik Vosman

Index Scriptorium Estoniae

Vosman, Hendrik

2008-01-01

Ilmunud ka: Postimees : na russkom jazõke 8. jaan. 2008, lk. 7. Prantsusmaa presidendi Nicolas Sarkozy kavatsusest abielluda itaallannast laulja ja endise modelli Carla Bruniga. Rahva vähenevast usaldusest presidendi suhtes. Lisa: Nicolas Sarkozy naised

Ion radical rupture of the carbon-carbon bond in oxidation of 1,3,1',3'-tetramethyl-2,3,2',3'- tetrahydro-2,2'-diperimidinyl

International Nuclear Information System (INIS)

Sabanov, V.Kh.; Kibizova, A.Yu.; Klimov, E.S.; Berberova, N.T.; Okhlobystin, O.Yu.

1987-01-01

Electrochemical and chemical oxidation of 1,3,1',3'-tetramethyl-2,3,2',3'-tetrahydro-2,2'-dipyriminyl takes place with rupture of the C-C bond in the initially formed cation radical. In the oxidation of the compound with aluminum chloride in nitrobenzene, ESR revealed a cation radical with an unresolved hyperfine structure. Oxidation of the dihydrodimer with nitrosonium perchlorate in nitrobenzene or nitromethane resulted in the same spectra. Cyclic volt-ampere diagrams are included

Al{sub 2}O{sub 3} reinforced nanoparticle ZrO{sub 2} (3at%?Y{sub 2}O{sub 3}); Al{sub 2}O{sub 3} reforcado com nanoparticulas de ZrO{sub 2}(3%mol Y{sub 2}O{sub 3})

Energy Technology Data Exchange (ETDEWEB)

Cossu, C.M.F.A.; Alves, M.F.R.P.; Campos, L.Q.B.; Magnago, R.O.; Santos, C., E-mail: caio.cossu@usp.br [Universidade do Estado do Rio de Janeiro (UERJ), Resende, RJ (Brazil). Faculdade de Tecnologia; Simba, B.G. [Universidade Estadual Paulista Julio de Mesquita Filho (UNESP), Guaratingueta, SP (Brazil). Faculdade de Engenharia

2016-07-01

This work developed a composite Al{sub 2}O{sub 3}-based reinforced with nanoparticles of ZrO{sub 2} (Y{sub 2}O{sub 3}), to evaluate the effect of the content of ZrO{sub 2} nanoparticles (Y{sub 2}O{sub 3}) on the mechanical properties. Mixtures containing a matrix of Al{sub 2}O{sub 3} with fractions in weight of 3%, 5%, 10% and 15%, ZrO{sub 2} (Y{sub 2}O{sub 3}), and were mixed in mortar mill. Mixtures received 5% polymeric binder (PVA); and after adding the binder, the material was pressed uniaxially to 50MPa, and then sintered at a temperature of 1600 ° C - 2h. The sintered products were characterized by X-ray diffraction, scanning electron microscopy (SEM), relative density, hardness and fracture toughness. The results of X-ray diffraction showed that Al{sub 2}O{sub 3} and tetragonal ZrO{sub 2} as crystal phases found after sintering. Furthermore, the relative green density of 55% was predominant in the compact; and after sintering, varied depending on the ZrO{sub 2} content, reaching 97% in sintered compositions with 3% ZrO{sub 2} nanoparticles (Y{sub 2O}3). The hardness of the samples showed values of 1670HV and the maximum toughness of 3.2 MPa × m{sup 1/2}, directly influenced by the presence of nanoparticles ZrO{sub 2} uniformly dispersed in the matrix Al{sub 2}O{sub 3}, which results in at least two main mechanisms tenacifiers: transformation of tetragonal-monoclinic phase of zirconia, and compressive residual strain between the two phases present, Al{sub 2}O{sub 3} and tetragonal ZrO{sub 2}. (author)

A Statistical Approach to Characterize and Detect degradation Within the Barabasi-Albert Network

Science.gov (United States)

2016-09-01

0 30 1 π tan −1 √ 2− 9 Pareto(α, β) α β(1−1/α)(2−1/α) 1+1/α 3−1/α (1+1/α)(2+1/α) (3−1/α)(4−1/α) Student’s t, 2 df π/28/2 0 3/8 Student’s t, 4 df 15π/64...lishers Inc., San Francisco, CA, USA, 2002. 33. Greenwood, J. Arthur, J. Maciunas Landwehr, Nicolas C. Matalas, and James R. Wallis. “Probability...Hamed Valizadegan, Samah Fodeh, and Pang-Ning Tan . “A Probabilistic Substructure-Based Approach for Graph Classification”. Tools with Artificial

Atmospheric chemistry of (CF3)2CHOCH3, (CF3)2CHOCHO, and CF3C(O)OCH3

DEFF Research Database (Denmark)

Østerstrøm, Freja From; Wallington, Timothy J.; Andersen, Mads Peter Sulbæk

2015-01-01

Smog chambers with in situ FTIR detection were used to measure rate coefficients in 700 Torr of air and 296 ± 2 K of: k(Cl+(CF3)2CHOCH3) = (5.41 ± 1.63) × 10(-12), k(Cl+(CF3)2CHOCHO) = (9.44 ± 1.81) × 10(-15), k(Cl+CF3C(O)OCH3) = (6.28 ± 0.98) × 10(-14), k(OH+(CF3)2CHOCH3) = (1.86 ± 0.41) × 10(-1...

Ion Internal Excitation and Co++ 2 Reactivity: Effect On The Titan, Mars and Venus Ionospheric Chemistry

Science.gov (United States)

Nicolas, C.; Zabka, J.; Thissen, R.; Dutuit, O.; Alcaraz, C.

In planetary ionospheres, primary molecular and atomic photoions can be produced with substantial electronic and vibrational internal energy. In some cases, this is known to strongly affect both the rate constants and the branching ratio between the reac- tion products. A previous experimental study (Nicolas et al.) made at the Orsay syn- chrotron radiation facility has shown that many endothermic charge transfer reactions which were not considered in the ionospheric chemistry models of Mars, Venus and Earth have to be included because they are driven by electronic excitation of the parent ions. New measurements on two important reactions for Titan and Mars ionospheres, N+ + CH4 and O+ + CO2, will be presented. Branching ratios between products are very different when the parent atomic ions are prepared in their ground states, N+(3P) and O+(4S), or in their first electronic metastable states N+(1D) and O+(2D or P). 2 As the lifetime of these states are long enough, they survive during the mean time be- tween two collisions in the ionospheric conditions. So, the reactions of these excited states must be included in the ionospheric models. Absolute cross section measurements of the reactivity of stable doubly charged molec- ular ions CO++ and their implications for the Martian ionosphere will also be pre- 2 sented. The molecular dication CO++ production by VUV photoionisation and elec- 2 tron impact in the upper ionosphere of Mars is far from being negligible. However, to determine its concentration, it was necessary to evaluate the major loss channels of these ions. For this purpose, we measured the absolute reaction cross section of the sta- ble dications with CO2, the major neutral species of the Mars ionosphere. CO++ ions 2 were produced either by photoionisation or by electron impact, and a reaction cross section of 45 Å2 with 13CO2 was measured. The reaction leads to charge transfer or to collision induced dissociation. These results were integrated in a model

Strategic Studies Quarterly. Volume 9, Number 2. Summer 2015

Science.gov (United States)

2015-01-01

Leadership Monitor 31 (Winter 2010): http://media .hoover.org/sites/default/files/documents/CLM31JCM.pdf. 41. Nicola Horsburgh, "Change and Innovation...Vietnamese president Truong Tan Sang promoted partnership with China in a wide range of fields, including people-to-people exchanges and economic...Truong Tan Sang of Vietnam, Stressing to Forge Ahead in the Overall Direction of the Development of China-Vietnam Relations," 15 October 2013, http

The Ca(PO3)2-Sr(PO3)2 system

International Nuclear Information System (INIS)

Bukhalova, G.A.; Tokman, I.A.

1977-01-01

Phase diagram of the system Ca(PO 3 ) 2 -Sr(PO 3 ) 2 has been studied and plotted with the aid of differential thermal, visual polythermal, X-ray analysis, and infrared spectroscopy. Continuous solid solutions are formed in the system with a minimum at 968 deg C and 25 mol.% of Sr(PO 3 ) 2 . Solid solutions decompose with the formation of about 30 mol.% of Sr(PO 3 ) 2

The system La(PO3)3-Ca(PO3)2-P2O5

International Nuclear Information System (INIS)

Jungowska, W.; Znamierowska, T.

1993-01-01

Ternary system La(PO 3 ) 3 -Ca(PO 3 ) 2 -P 2 O 5 has been studied by means of thermal and roentgenography analysis. The existence of single intermediate compound CaLa(PO 3 ) 5 has been observed. The phase diagrams for the ternary system as well as for two binary systems La(PO 3 ) 3 -Ca(PO 3 ) 2 and CaLa(PO 3 ) 5 -LaP 5 O 11 have been shown. 7 refs, 3 figs

Oxidative Lung Injury in Virus-Induced Wheezing

Science.gov (United States)

2015-07-01

respiratory syncytial virus Yashoda M. Hosakote,1 Narayana Komaravelli,1 Nicolas Mautemps,1 Tianshuang Liu,1 Roberto P. Garofalo,1,2,3 and Antonella Casola1,2,3...1097/MNH.0b013e3283430651. 5. Li L, Whiteman M, Guan YY, Neo KL, Cheng Y, Lee SW, Zhao Y, Baskar R, Tan CH, Moore PK. 2008. Characterization of a novel...L, Whiteman M, Guan YY, Neo KL, Cheng Y, Lee SW, Zhao Y, Baskar R, Tan CH, Moore PK. Characterization of a novel, water-soluble hydrogen sulfide

Porous Na2O-B2O3-Nd2O3 material

Energy Technology Data Exchange (ETDEWEB)

De Villiers, D R; Res, M A; Richter, P W

1986-12-01

Substitution of SiO2 by Nd2O3 in the sodium borosilicate system produced glasses containing up to 50 mass% Nd2O3. Sodium borate was leached out of some of the materials to produce either a porous Nd2O3-rich glass or a porous glass-ceramic containing NdBO3, depending on the starting material. Surface areas of up to 190 mS g- were measured. Powder X-ray diffraction (XRD) revealed the NdBO3 to be the high-temperature form with low symmetry.

Phase 2 Study of AZD2014, a Dual mTORC1/mTORC1 Inhibitor,for NF2 Patients with Progressive or Symptomatic Meningiomas

Science.gov (United States)

2017-06-01

statistical support for the clinical trial. Funding support N/A Name Nicola Gribbin, RN Project Role Research Nurse Nearest person-month worked 1...the author(s) and should not be construed as an official Department of the Army position, policy or decision unless so designated by other...Obtain institutional approval for proposed clinical trial (months 1-6) In year 1, we obtained IRB approval at MGH and USAMRMC Human Research Protection

Synthesis and X-ray crystal structure of (OsO(3)F(2))(2)2XeOF(4) and the Raman spectra of (OsO(3)F(2))(infinity), (OsO(3)F(2))(2), and (OsO(3)F(2))(2)2XeOF(4).

Science.gov (United States)

Hughes, Michael J; Mercier, Hélène P A; Schrobilgen, Gary J

2009-05-18

The adduct, (OsO(3)F(2))(2)2XeOF(4), was synthesized by dissolution of the infinite chain polymer, (OsO(3)F(2))(infinity), in XeOF(4) solvent at room temperature followed by removal of excess XeOF(4) under dynamic vacuum at 0 degrees C. Continued pumping at 0 degrees C resulted in removal of associated XeOF(4), yielding (OsO(3)F(2))(2), a new low-temperature phase of OsO(3)F(2). Upon standing at 25 degrees C for 1(1)/(2) h, (OsO(3)F(2))(2) underwent a phase transition to the known monoclinic phase, (OsO(3)F(2))(infinity). The title compounds, (OsO(3)F(2))(infinity), (OsO(3)F(2))(2), and (OsO(3)F(2))(2)2XeOF(4) have been characterized by low-temperature (-150 degrees C) Raman spectroscopy. Crystallization of (OsO(3)F(2))(2)2XeOF(4) from XeOF(4) solution at 0 degrees C yielded crystals suitable for X-ray structure determination. The structural unit contains the (OsO(3)F(2))(2) dimer in which the OsO(3)F(3) units are joined by two Os---F---Os bridges having fluorine bridge atoms that are equidistant from the osmium centers (2.117(5) and 2.107(4) A). The dimer coordinates to two XeOF(4) molecules through Os-F...Xe bridges in which the Xe...F distances (2.757(5) A) are significantly less than the sum of the Xe and F van der Waals radii (3.63 A). The (OsO(3)F(2))(2) dimer has C(i) symmetry in which each pseudo-octahedral OsO(3)F(3) unit has a facial arrangement of oxygen ligands with XeOF(4) molecules that are only slightly distorted from their gas-phase C(4v) symmetry. Quantum-chemical calculations using SVWN and B3LYP methods were employed to calculate the gas-phase geometries, natural bond orbital analyses, and vibrational frequencies of (OsO(3)F(2))(2), (OsO(3)F(2))(2)2XeOF(4), XeOF(4), OsO(2)F(4), and (mu-FOsO(3)F(2))(2)OsO(3)F(-) to aid in the assignment of the experimental vibrational frequencies of (OsO(3)F(2))(2), (OsO(3)F(2))(2)2XeOF(4), and (OsO(3)F(2))(infinity). The vibrational modes of the low-temperature polymeric phase, (OsO(3)F(2))(infinity), have been

Nd(BrO3)3-Yb(BrO3)3-H2O and Nd2(SeO4)3-Yb2(SeO4)3-H2O systems at 25 deg C

International Nuclear Information System (INIS)

Serebrennikov, V.V.; Batyreva, V.A.; Tsybukova, T.N.

1981-01-01

Using the methods of isothermal solubility the Nd(BrO 3 ) 3 - Yb(BrO 3 ) 3 -H 2 O and Nd 2 (SeO 4 ) 3 -Yb 2 (SeO 4 ) 3 -H 2 O systems are studied at 25 deg C. The compositions of the solid phases are determined by the method of ''residues''. The formation of two series of solid solutions in both systems is established. Besides, there is a crystallization region of Nd 2 (SeO 4 ) 3 in the system of selenates. The solubility diagrams of the systems are presented [ru

Violet-green excitation for NIR luminescence of Yb3+ ions in Bi2O3-B2O3-SiO2-Ga2O3 glasses.

Science.gov (United States)

Li, Weiwei; Cheng, Jimeng; Zhao, Guoying; Chen, Wei; Hu, Lili; Guzik, Malgorzata; Boulon, Georges

2014-04-21

60Bi(2)O(3)-20B(2)O(3)-10SiO(2)-10Ga(2)O(3) glasses doped with 1-9 mol% Yb(2)O(3) were prepared and investigated mainly on their violet-green excitation for the typical NIR emission of Yb(3+), generally excited in the NIR. Two violet excitation bands at 365 nm and 405 nm are related to Yb(2+) and Bi(3+). 465 nm excitation band and 480 nm absorption band in the blue-green are assigned to Bi(0) metal nanoparticles/grains. Yb-content-dependence of the excitation and absorption means that Bi(0) is the reduced product of Bi(3+), but greatly competed by the redox reaction of Yb(2+) ↔ Yb(3+). It is proved that the violet-green excitations result in the NIR emission of Yb(3+). On the energy transfer, the virtual level of Yb(3+)-Yb(3+) as well as Bi(0) dimers probably plays an important role. An effective and controllable way is suggested to achieve nano-optical applications by Bi(0) metal nanoparticles/grains and Yb(3+).

Reactions at the Metal Vertex of a Monometal Metallocarborane Cluster. The Chemistry of (closo-3,3-(PPh3)2-3-(HSO4)-3,1,2-RhC2B9H11) and (closo-3-(PPh3)-3,3-(NO3)-3,1,2RhC2B9H11).

Science.gov (United States)

1982-03-09

4) produced by dissociation of PPh 3 from (2) or through an ionic species such as [closo-3,3- (PPh 3)2 -3,1,2-RhC 289 H ] [HSO4 (4a). Secondly, the...acetylene molecule and subsequent insertion into a metal-carbon bond has been observed in the linear oligomerization of acetylere catalyzed by [Ni(CO...monoxide were obtained from Liquid Carbonic and used without further treatment. Phenylacetylene (Aldrich) was distilled under vacuum before use and n

Methanesulfonates of high-valent metals. Syntheses and structural features of MoO{sub 2}(CH{sub 3}SO{sub 3}){sub 2}, UO{sub 2}(CH{sub 3}SO{sub 3}){sub 2}, ReO{sub 3}(CH{sub 3}SO{sub 3}), VO(CH{sub 3}SO{sub 3}){sub 2}, and V{sub 2}O{sub 3}(CH{sub 3}SO{sub 3}){sub 4} and their thermal decomposition under N{sub 2} and O{sub 2} atmosphere

Energy Technology Data Exchange (ETDEWEB)

Betke, Ulf; Neuschulz, Kai; Wickleder, Mathias S. [Carl von Ossietzky University of Oldenburg, Institute of Pure and Applied Chemistry (Germany)

2011-11-04

Oxide methanesulfonates of Mo, U, Re, and V have been prepared by reaction of MoO{sub 3}, UO{sub 2}(CH{sub 3}COO){sub 2}.2 H{sub 2}O, Re{sub 2}O{sub 7}(H{sub 2}O){sub 2}, and V{sub 2}O{sub 5} with CH{sub 3}SO{sub 3}H or mixtures thereof with its anhydride. These compounds are the first examples of solvent-free oxide methanesulfonates of these elements. MoO{sub 2}(CH{sub 3}SO{sub 3}){sub 2} (Pbca, a=1487.05(4), b=752.55(2), c=1549.61(5) pm, V=1.73414(9) nm{sup 3}, Z=8) contains [MoO{sub 2}] moieties connected by [CH{sub 3}SO{sub 3}] ions to form layers parallel to (100). UO{sub 2}(CH{sub 3}SO{sub 3}){sub 2} (P2{sub 1}/c, a=1320.4(1), b=1014.41(6), c=1533.7(1) pm, β=112.80(1) {sup circle}, V=1.8937(3) nm{sup 3}, Z=8) consists of linear UO{sub 2}{sup 2+} ions coordinated by five [CH{sub 3}SO{sub 3}] ions, forming a layer structure. VO(CH{sub 3}SO{sub 3}){sub 2} (P2{sub 1}/c, a=1136.5(1), b=869.87(7), c=915.5(1) pm, β=113.66(1) {sup circle}, V=0.8290(2) nm{sup 3}, Z=4) contains [VO] units connected by methanesulfonate anions to form corrugated layers parallel to (100). In ReO{sub 3}(CH{sub 3}SO{sub 3}) (P anti 1, a=574.0(1), b=1279.6(3), c=1641.9(3) pm, α=102.08(2), β=96.11(2), γ=99.04(2) {sup circle}, V=1.1523(4) nm{sup 3}, Z=8) a chain structure exhibiting infinite O-[ReO{sub 2}]-O-[ReO{sub 2}]-O chains is formed. Each [ReO{sub 2}]-O-[ReO{sub 2}] unit is coordinated by two bidentate [CH{sub 3}SO{sub 3}] ions. V{sub 2}O{sub 3}(CH{sub 3}SO{sub 3}){sub 4} (I2/a, a=1645.2(3), b=583.1(1), c=1670.2(3) pm, β=102.58(3), V=1.5637(5) pm{sup 3}, Z=4) adopts a chain structure, too, but contains discrete [VO]-O-[VO] moieties, each coordinated by two bidentate [CH{sub 3}SO{sub 3}] ligands. Additional methanesulfonate ions connect the [V{sub 2}O{sub 3}] groups along [001]. Thermal decomposition of the compounds was monitored under N{sub 2} and O{sub 2} atmosphere by thermogravimetric/differential thermal analysis and XRD measurements. Under N{sub 2} the decomposition proceeds

2,3-Dibromo-3-(2-bromophenyl-1-(3-phenylsydnon-4-ylpropan-1-one

Directory of Open Access Journals (Sweden)

Balakrishna Kalluraya

2010-12-01

Full Text Available In the title compound [systematic name: 2,3-dibromo-3-(2-bromophenyl-1-(5-oxido-3-phenyl-1,2,3-oxadiazol-3-ium-4-ylpropan-1-one], C17H11Br3N2O3, the oxadiazole ring is essentially planar, with a maximum deviation of 0.003 (1 Å. The –CHBr–CHBr– chain and bromophenyl ring are disordered over two sets of sites with a refined occupany ratio of 0.756 (5:0.244 (5. The central oxadiazole ring makes dihedral angles of 54.07 (11 and 13.76 (18° with the attached phenyl and the major component of the bromo-substituted benzene rings, respectively. The dihedral angle between the major and minor components of the bromophenyl rings is 13.4 (5°. In the crystal structure, molecules are connected by C—H...O hydrogen bonds, forming [010] ribbons.

Crystal structures of 2,2′-bipyridin-1-ium 1,1,3,3-tetracyano-2-ethoxyprop-2-en-1-ide and bis(2,2′-bipyridin-1-ium 1,1,3,3-tetracyano-2-(dicyanomethylenepropane-1,3-diide

Directory of Open Access Journals (Sweden)

Zouaoui Setifi

2015-05-01

Full Text Available In 2,2′-bipyridin-1-ium 1,1,3,3-tetracyano-2-ethoxyprop-2-en-1-ide, C10H9N2+·C9H5N4O−, (I, the ethyl group in the anion is disordered over two sets of atomic sites with occupancies 0.634 (9 and 0.366 (9, and the dihedral angle between the ring planes in the cation is 2.11 (7°. The two independent C(CN2 groups in the anion make dihedral angles of 10.60 (6 and 12.44 (4° with the central propenide unit, and the bond distances in the anion provide evidence for extensive electronic delocalization. In bis(2,2′-bipyridin-1-ium 1,1,3,3-tetracyano-2-(dicyanomethylenepropane-1,3-diide [alternative name bis(2,2′-bipyridin-1-ium tris(dicyanomethylenemethanediide], 2C10H9N2+·C10N62− (II, the dihedral angles between the ring planes in the two independent cations are 7.7 (2 and 10.92 (17°. The anion exhibits approximate C3 symmetry, consistent with extensive electronic delocalization, and the three independent C(CN2 groups make dihedral angles of 23.8 (2, 27.0 (3 and 27.4 (2° with the central plane. The ions in (I are linked by an N—H...N hydrogen bond and the resulting ion pairs are linked by two independent C—H...N hydrogen bonds, forming a ribbon containing alternating R44(18 and R44(26 rings, where both ring types are centrosymmetric. The ions in (II are linked by two independent N—H...N hydrogen bonds and the resulting ion triplets are linked by a C—H...N hydrogen bond, forming a C21(7 chain containing anions and only one type of cation, with the other cation linked to the chain by a further C—H...N hydrogen bond.

Electron-impact excitation of multiply-charged ions using energy loss in merged beams: e + Si3+(3s2S1/2) → e + Si3+(3p2P1/2,3/2)

International Nuclear Information System (INIS)

Wahlin, E.K.; Thompson, J.S.; Dunn, G.H.; Phaneuf, R.A.; Gregory, D.C.; Smith, A.C.H.

1990-01-01

For the first time absolute total cross sections for electron-impact excitation of a multiply-charged ion have been measured using an electron-energy-loss technique. Measurements were made near threshold for the process e + Si 3+ (3s 2 S 1/2 ) → e + Si 3+ (3p 2 P 1/2 , 3/2 ) -- 8.88 eV. The 10 -15 cm 2 measured cross section agrees with results of 7-state close coupling calculations to better than the ±20% (90% CL) total uncertainty of the measurements. Convoluting the theoretical curve with a Gaussian energy distribution indicates an energy width of 0.15 approx-lt ΔE approx-lt 0.20 eV. 12 refs., 2 figs

Convenient synthesis of 2,2-Dimethyl-3,4-dihydro-2 H-pyrano[2,3- b]quinolines

Digital Repository Service at National Institute of Oceanography (India)

Parsekar, S.B.; Amonkar, C.P.; Parameswaran, P.S.; Tilve, S.G.

A convenient general synthesis of 2,2-dimethyl-3,4-dihydro-2H-pyrano[2,3-b]quinolines using the Wittig reaction is described. The o-nitrobenzaldehydes (1a-d) on reaction with phosphorane 2 provided (E)-ethyl-a-(2,2-dimethylprop-2-ene)-2...

Electrical conduction of glasses in the system Fe2O3-Sb2O3-TeO2; Fe2O3-Sb2O3-TeO2 kei garasu no denki dendo

Energy Technology Data Exchange (ETDEWEB)

Qiu, Honghua; Mori, H; Sakata, H; Hirayama, T [Tokai Univ., Tokyo (Japan). Faculty of Engineering

1995-01-01

In this study, taking into consideration that TeO2 is a component of the glass network and Sb2O3 shows the redox effect in the glasses reducing its possibility of transformation of Sb{sup 3+} to Sb{sup 5+} as well as glass basicity, highly conductive tellurite based glasses have been prepared by the press-quenching method selecting the Fe2O3-Sb2O3-TeO2 system, and the electroconductive mechanism of the glasses has been examined by measuring its D.C. conductivity {sigma}. Part of the obtained information is as follows; the glass formation range of the Fe2O3-Sb2O3-TeO2 system has been 0 {le} Fe2O3 {le} 15mol%, 0 {le} Sb2O3 {le} 18mol% and 78 {le} TeO2 {le} 100mol% and about 15mol% of the additional amount of Fe2O3 has been the limit of glass formation. As the amount of Fe2O3 has increased, C{sub Fe} has also increased and with this, the linear electroconductivity of the glasses has increased from 1.86 {times} 10{sup -7}S{center_dot}cm{sup -1} to 1.62 {times} 10{sup -6}S{center_dot}cm{sup -1} and the glasses have been confirmed as the n-type semiconductor. The factor determining {sigma} of the glasses has been C{sub Fe} which has increased as the amount of Fe2O3 has increased. 34 refs., 8 figs., 2 tabs.

(3aS,7aS-5-[(S-3,3,3-Trifluoro-2-methoxy-2-phenylpropanoyl]-2,3,4,5,6,7-hexahydro-1H-pyrrolo[3,4-c]pyridin-3(2H-one monohydrate

Directory of Open Access Journals (Sweden)

Huichun Zhu

2010-01-01

Full Text Available rac-Benzyl 3-oxohexahydro-1H-pyrrolo[3,4-c]pyridine-5(6H-carboxylate was separated by chiral chromatography, and one of the enantiomers ([α]22D = +10° was hydrogenated in the presence of Pd/C in methanol, producing octahydro-3H-pyrrolo[3,4-c]pyridin-3-one. The latter was reacted with (2R-3,3,3-trifluoro-2-methoxy-2-phenylpropanoyl chloride [(R-(−-Mosher acid chloride], giving rise to the title compound, C17H19F3N2O3·H2O. The present structure established the absolute configuration of the pyrrolopiperidine fragment based on the known configuration of the (R-Mosher acid chloride. The piperidine ring has a somewhat distorted chair conformation and is cis-fused with the five-membered envelope-shaped ring; the plane of the exocyclic amide bond is approximately orthogonal to the plane of the phenyl ring, making a dihedral angle of 82.31 (3°. The water molecule acts as an acceptor to the proton of the amino group in an N—H...O interaction, and as a double proton donor in O—H...O hydrogen bonds, generating infinite bands along the a axis.

A New Method for the Synthesis of 2,3-Aziridino-2,3-dideoxyhexonamides and Their Conversion into 3-Amoni-2,3-dideoxyhexonic Acids

DEFF Research Database (Denmark)

Jørgensen, Christel Thea; Pedersen, Christian; Søtofte, Inger

1998-01-01

The new 2,3-Aziridino-2,3-dideoxyhexonamides 3 and 11 were prepared by a three-step procedure from commercially available D-glucono-1,5-lactone and D-gulono-1,4-lactone, respectively. The lactones were converted into methyl 3,4;5,6-di-O-isopropylidene-2-Omesyl esters 2 and 10, which upon treatmen...... with ammonia formed the title aziridino compounds. These were reductively cleaved by hydrazine to give 3-amino-2,3-dideoxyhexonic hydrazides 13 and 15, which were easily converted into corresponding lactone 14 and acid 16, respectively....

2,2-Dimethyl-2,3-dihydropyrano[2,3-a]carbazol-4(11H-one

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Makuteswaran Sridharan

2008-11-01

Full Text Available The title compound, C17H15NO2, was prepared from 1-hydroxycarbazole and 3,3-dimethylacrylic acid with a mixture of AlCl3 and POCl3 as the cyclization catalyst. Owing to the presence of the –CMe2– group, the molecule is not quite planar. In the crystal structre, strong N—H...O hydrogen bonds and weaker C—H...π interactions occur, and a slipped π–π stacking interaction [centroid–centroid separation = 3.8425 (8 Å] is also observed.

4,6-Dibromo-N-{3-[(4,6-dibromo-2,3-dimethylphenylimino]butan-2-ylidene}-2,3-dimethylaniline

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Lina Huang

2013-10-01

Full Text Available The title compound, C20H20Br4N2, is a product of the condensation reaction of 4,6-dibromo-2,3-dimethylaniline and butane-2,3-dione. The molecule has a center of symmetry at the mid-point of the central C—C bond. The dihedral angle between the benzene ring and the 1,4-diazabutadiene plane is 78.3 (2°. Niether hydrogen bonding nor aromatic stacking is observed in the crystal structure.

Facile Synthesis of 3-Aryl-3-hydroxy-2-oxindoles from 2-Arylindoles

Energy Technology Data Exchange (ETDEWEB)

Moon, Hye Ran; Roh, Hwa Jung; Kim, Jae Nyoung [Chonnam National University, Gwangju (Korea, Republic of); Lee, Sangku [Korea Research Institute of Bioscience and Biotechnology, Chungju (Korea, Republic of)

2016-07-15

An efficient synthetic route of 3-aryl-3-hydroxy-2-oxindoles has been developed from 2-arylindoles. The procedure provides a brand-new synthetic method of 3-aryl-3-hydroxy-2-oxindoles from readily available starting materials in high yields. We reported an aerobic transition metal-free synthesis of 2,3-diarylindoles via an oxidative nucleophilic substitution of hydrogen (ONSH) pathway from 2-arylindoles and nitroarenes. As an example, the reaction of 2-phenylindole (1a) and 1,3-dinitrobenzene in DMSO in the presence of Cs{sub 2}CO{sub 3} under O{sub 2} balloon atmosphere afforded 2,3-diarylindole in good yield (78%) in short time, as shown in Scheme 1. During the study, we found the formation of 3-phenyl-3-hydroxy-2-oxindole (2a), albeit in moderate yield (41%), under the same reaction condition for a long time (8 h) without 1,3-dinitrobenzene. Based on the experimental results, the reaction mechanism for the conversion of 1a to 2a is proposed, as shown in Scheme 2. The indole anion I was converted to 3-hydroxyindolenine intermediate III via the hydroperoxide intermediate II. Subsequently, III was changed to an epoxide intermediate IV under basic condition, and a following semipinacol type rearrangement of IV would produce 3-phenyloxindole VI. A subsequent aerobic oxidation of VI would produce 2a.

Heterobranchus longifilis x Clarias gariepinus

African Journals Online (AJOL)

Owner

2005-08-12

Aug 12, 2005 ... were determined with a haemocytometer with improved Neubauer counting chamber as described by Blaxhall and Diasley (1973). Haemoglobin (Hb) concentration estimates were determined as described by Wedemeyer and Yasutake (1977). The data obtained were subjected to analysis of variance and.

Tuning of magnetic frustration in S = 1 / 2 Kagomé lattices {[Cu3(CO3)2(bpe)3](CLO4)2}n and {[Cu3(CO3)2(bpy)3](CLO4)2}n through rigid and flexible ligands

Science.gov (United States)

Ajeesh, M. O.; Yogi, A.; Padmanabhan, M.; Nath, R.

2015-04-01

Single crystalline and polycrystalline samples of S = 1 / 2 Kagomé lattices { [Cu3(CO3)2(bpe)3 ](CLO4)2 } n and { [Cu3(CO3)2(bpy)3 ](CLO4)2 } n, respectively were synthesized. Their structural and magnetic properties were characterized by means of x-ray diffraction and magnetization measurements. Both compounds crystalize in a hexagonal structure (space group P-6) consisting of CuO4 Kagomé layers in the ab-plane but linked along c direction through either rigid bpy or flexible bpe ligands to form 3D frame works. Magnetic measurements reveal that both the compounds undergo ferromagnetic ordering (TC) at low temperatures and the TC and the extent of frustration could be tuned by changing the nature of the pillar ligands. {[Cu3(CO3)2(bpe)3](CLO4)2}n which is made up of flexible bpe ligands has a TC of 5.7 K and a Curie-Weiss temperature (θCW) of -39.7 K giving rise to a frustration parameter of |θCW | /TC ≃ 6.96. But the replacement of bpe by a more rigid and electronically delocalized bpy ligand leads to an enhanced TC ≃ 9.3 K and a reduced frustration parameter of |θCW | /TC ≃ 3.54.

Studies of Eu2O3 - Bi2O3 - B2O3 glasses using Raman and IR spectroscopy

International Nuclear Information System (INIS)

Pop, Lidia; Culea, Eugen N.; Bratu, I.

2004-01-01

The bismuth borate (3Bi 2 O 3 ·B 2 O 3 ) glasses were prepared with different concentrations of Eu 3+ . The structure of these systems were investigated by Raman and IR spectroscopy. The structural study reveals that the glasses contain BiO 3 , BiO 6 , BO 3 , BO 4 and Eu-O structural units. For the samples with a higher content of Eu 2 O 3 , the spectra became very large indicating a more disordered structure. The hygroscopic character of the 3Bi 2 O 3 ·B 2 O 3 glass matrix and the progressive decrease of this behaviour with increasing the Eu 2 O 3 content was observed. Therefore, we conclude that the europium oxide acts as a network modifier in these glasses. (authors)

2-(3-Methylphenyl-1,2-benzoselenazol-3(2H-one

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Liyun Wang

2017-04-01

Full Text Available In the title ebselen derivative, C14H11NOSe, the nine-membered benzisoselenazolyl ring system is approximately planar (r.m.s. deviation = 0.021 Å. The dihedral angle between its mean plane and that of the 3-methylphenyl ring is 5.37 (11°. The five-membered isoselenazolyl ring is severely strained at the Se atom: Se—N = 1.889 (2 Å, Se—Car = 1.882 (3 Å and N—Se—Car = 83.30 (10°. In the crystal, molecules are linked by C—H...O hydrogen bonds and short intermolecular Se...O contacts of 2.6917 (19 Å, forming chains along the c-axis direction. Neighbouring molecules are linked by offset π–π interactions [intercentroid distance = 3.535 (2 Å]. The chains are also linked by C—H...π interactions, forming a three-dimensional structure.

Spectroscopic properties and energy transfer analysis of Tm3+-doped BaF2-Ga2O3-GeO2-La2O3 glass.

Science.gov (United States)

Yu, Shenglei; Yang, Zhongmin; Xu, Shanhui

2010-05-01

This paper reports on the spectroscopic properties and energy transfer analysis of Tm(3+)-doped BaF(2)-Ga(2)O(3)-GeO(2)-La(2)O(3) glasses with different Tm(2)O(3) doping concentrations (0.2, 0.5, 2.0, 2.5, 3.0, 3.5, 3.5, 4.0 wt%). Mid-IR fluorescence intensities in the range of 1,300 nm-2,200 nm have been measured when excited under an 808 nm LD for all the samples with the same pump power. Energy level structure and Judd-Ofelt parameters have been calculated based on the absorption spectra of Tm(3+), cross-relaxation rates and multi-phonon relaxation rates have been estimated with different Tm(2)O(3) doping concentrations. The maximum fluorescence intensity at around 1.8 mum has been obtained in Tm(2)O(3)-3 wt% sample and the maximum value of calculated stimulated emission cross-section of Tm(3+) in this sample is about 0.48 x 10(-20) cm(2) at 1,793 nm, and there is not any crystallization peak in the DSC curve of this sample, which indicate the potential utility of Tm(3+)-doped BaF(2)-Ga(2)O(3)-GeO(2)- La(2)O(3) glass for 2.0-microm optical fiber laser.

Synthesis and structures of two isostructural phosphites, Al2(HPO3)3 and Ga2(HPO3)3

International Nuclear Information System (INIS)

Morris, R.E.; Attfield, M.P.; Cheetham, A.K.

1994-01-01

Aluminium hydrogen phosphite, Al 2 (HPO 3 ) 3 , and gallium hydrogen phosphite, Ga 2 (HPO 3 ) 3 , were prepared hydrothermally in Teflon-lined steel autoclaves at 473 K. The compounds are isostructural with Fe 2 (HPO 3 ) 3 . The structures consist of very distorted MO 6 octahedra which share faces to form a dimeric M 2 O 9 unit. These dimers are interlinked by the phosphite groups, which link three different dimers into a three-dimensional arrangement having small proton-lined channels running parallel to the c axis. (orig.)

77 FR 25538 - Quarterly Publication of Individuals, Who Have Chosen To Expatriate

Science.gov (United States)

2012-04-30

... ERIK PAUL FURLER NICOLAS SILVAN FURRER GAJA MARIA FURRER JONAS KEVIN FURRER SACHA GABRIELLA GAGNON... CATHERINE MARIE MILNE NATASHA JANE MIN CHRIS SHIK MIN STEVE BAE MIZRACHI ELI HAIM MONTAGUE ALEXANDRE NICOLAS... CHRISTIAN MARTIN SYZ ISABEL SUSAN TAN CHUAN LIONG TAN WEI-EE BEVERLY [[Page 25544

Characterization of connective tissue growth factor expression in primary cultures of human tubular epithelial cells: modulation by hypoxia

NARCIS (Netherlands)

Kroening, Sven; Neubauer, Emily; Wullich, Bernd; Aten, Jan; Goppelt-Struebe, Margarete

2010-01-01

Kroening S, Neubauer E, Wullich B, Aten J, Goppelt-Struebe M. Characterization of connective tissue growth factor expression in primary cultures of human tubular epithelial cells: modulation by hypoxia. Am J Physiol Renal Physiol 298:F796-F806, 2010. First published December 23, 2009;

X-ray and NQR studies of bromoindate(III) complexes. [C2H5NH3]4InBr7, [C(NH2)3]3InBr6, and [H3NCH2C(CH3)2CH2NH3]InBr5

International Nuclear Information System (INIS)

Iwakiri, Takeharu; Ishihara, Hideta; Terao, Hiromitsu; Lork, Enno; Gesing, Thorsten M.

2017-01-01

The crystal structures of [C 2 H 5 NH 3 ] 4 InBr 7 (1), [C(NH 2 ) 3 ] 3 InBr 6 (2), and [H 3 NCH 2 C(CH 3 ) 2 CH 2 NH 3 ]InBr 5 (3) were determined at 100(2) K: monoclinic, P2 1 /n, a=1061.94(3), b=1186.40(4), c=2007.88(7) pm, β= 104.575(1) , Z=4 for 1; monoclinic, C2/c, a=3128.81(12), b=878.42(3), c=2816.50(10) pm, β=92.1320(10) , Z=16 for 2; orthorhombic, P2 1 2 1 2 1 , a=1250.33(5), b=1391.46(6), c=2503.22(9) pm, Z=4 for 3. The structure of 1 contains an isolated octahedral [InBr 6 ] 3- ion and a Br - ion. The structure of 2 contains three different isolated octahedral [InBr 6 ] 3- ions. The structure of 3 has a corner-shared double-octahedral [In 2 Br 11 ] 5- ion and an isolated tetrahedral [InBr 4 ] - ion. The 81 Br nuclear quadrupole resonance (NQR) lines of the terminal Br atoms of the compounds are widely spread in frequency, and some of them show unusual positive temperature dependence. These observations manifest the N-H..Br-In hydrogen bond networks developed between the cations and anions to stabilize the crystal structures. The 81 Br NQR and differential thermal analysis (DTA) measurements have revealed the occurrence of unique phase transitions in 1 and 3. When the bond angles were estimated from the electric field gradient (EFG) directions calculated by the molecular orbital (MO) methods, accurate values were obtained for [InBr 6 ] 3- of 1 and for [In 2 Br 11 ] 5- and [InBr 4 ] - of 3, except for several exceptions in those for the latter two ions. On the other hand, the calculations of 81 Br NQR frequencies have produced up to 1.4 times higher values than the observed ones.

CTC-Endothelial Cell Interactions during Metastasis

Science.gov (United States)

2014-06-01

equipped with a Zeiss AxioCam MRm camera . A syringe pump (KDS 230, IITC Life Science, Woodland Hills, CA) was used to control the shear stress of the...HUVECs in 2 ml growth medium at 180 x g for 5 min. Measure the cell concentration using a neubauer hemocytometer and prepare 107 HUVEC cells/100 µl...selectin (R&D Systems, Minneapolis, MN). Coated microtubes were mounted on an inverted microscope equipped with a Zeiss AxioCam MRm camera . A syringe pump

Fabrication and Properties of Multilayer Structures

Science.gov (United States)

1983-09-01

according to both the high x-ray count and a Read camera pattern which showed only the 111 8 SiC reflection in a tight ± 30 distribution about the substrate...structural rearrangement. X-ray analysis of the deposited films at the composition of Pd2 Si using a Read camera indicated strong texturing. The...Phys. 35, 547 (1964). 11. C.A. Neubauer and J.R. Randen, Proc. IEEE 52, 1234 (1964). 12. W.A. Tiller, "Fabrication and Properties of Multilayer

The influence of SiO2 Addition on 2MgO-Al2O3-3.3P2O5 Glass

DEFF Research Database (Denmark)

Larsen, P.H.; Poulsen, F.W.; Berg, Rolf W.

1999-01-01

2MgO-Al2O3-3.3P2O5 glasses with increasing amounts of SiO2 are considered for sealing applications in Solid Oxide Fuel Cells (SOFC). The change in chemical durability under SOFC anode conditions and the linear thermal expansion is measured as functions of the SiO2 concentration. Raman spectroscopy...... analysis of the glasses reveals no sign of important changes in the glass structure upon SiO2 addition. Some increase in glass durability with SiO2 concentration is reported and its cause is discussed....

Structure of LaH(PO3H)2.3H2O

International Nuclear Information System (INIS)

Loukili, M.; Durand, J.; Larbot, A.; Cot, L.; Rafiq, M.

1991-01-01

Lanthanum hydrogen bis(hydrogenphosphite) trihydrate, LaH(Po 3 H) 2 .3H 2 O, M r =353.8, monoclinic, P2 1 /c, a=9.687 (3), b=7.138 (2), c=13.518 A, β=104.48 (3) deg, V=905.0 (5) A 3 , Z=4, D m =2.56 (2), D x =2.598 Mg m -3 , λ(MoKα)=0.71073 A, μ(MoKα)=5.103 mm -1 , F(000)=672, T=300 K, R=0.032 for 1018 independent observed reflections. The structure contains two phosphite anions connected by a hydrogen bond. The La 3+ cation is eight coordinated by seven O atoms from phosphite anions and one O atom of a water molecule. (orig.)

ANP3 & NAP2

DEFF Research Database (Denmark)

Lindberg, Erik

1996-01-01

Modelling and SimulationANP3 introductionNAP2 introductionThe Exended Node EquationsThe input languages of ANP3 and NAP2The output from ANP3 and NAP2Literature......Modelling and SimulationANP3 introductionNAP2 introductionThe Exended Node EquationsThe input languages of ANP3 and NAP2The output from ANP3 and NAP2Literature...

Synthesis and structural characterization of two cobalt phosphites: 1-D (H3NC6H4NH3)Co(HPO3)2 and 2-D (NH4)2Co2(HPo3)3

International Nuclear Information System (INIS)

Cheng, C.-C.; Chang, W.-K.; Chiang, R.-K.; Wang, S.-L.

2010-01-01

Two new cobalt phosphites, (H 3 NC 6 H 4 NH 3 )Co(HPO 3 ) 2 (1) and (NH 4 ) 2 Co 2 (HPO 3 ) 3 (2), have been synthesized and characterized by single-crystal X-ray diffraction. All the cobalt atoms of 1 are in tetrahedral CoO 4 coordination. The structure of 1 comprises twisted square chains of four-rings, which contain alternating vertex-shared CoO 4 tetrahedra and HPO 3 groups. These chains are interlinked with trans-1,4-diaminocyclohexane cations by hydrogen bonds. The 2-D structure of 2 comprises anionic complex sheets with ammonium cations present between them. An anionic complex sheet contains three-deck phosphite units, which are interconnected by Co 2 O 9 to form complex layers. Magnetic susceptibility measurements of 1 and 2 showed that they have a weak antiferromagnetic interaction. - Graphical abstract: The 2-D structure of (NH 4 ) 2 Co 2 (HPO 3 ) 3 comprises anionic complex sheets with ammonium cations present between them. An anionic complex sheet contains three-deck phosphite units, which are interconnected by dimmeric Co 2 O 9 to form complex layers.

Crystal and molecular structure of 2,2’-(quinoxaline-2,3-diyl)dipyridinium dinitrate (H_2L)(NO_3)_2

International Nuclear Information System (INIS)

Egorova, O. A.; Polyakova, I. N.; Sergienko, V. S.; Davydov, V. V.

2016-01-01

The crystal structure of 2,2’-(quinoxaline-2,3-diyl)dipyridinium dinitrate (H_2L)(NO_3)_2 is studied by X-ray diffraction (T = 150 K, R1 = 0.0467). The H_2L"2"+ cation is located on the twofold rotation axis and connected with two NO_3"− anions by strong N–H···O hydrogen bonds. Planar quinoxaline fragments of cations form stacks with the interplanar spacing of 3.308 Å. The structure of the diprotonated H_2L"2"+ cation is compared with those of the monoprotonated H_2L"2"+ cation and neutral L molecule.

Efeito do meio Erd Schreiber no cultivo das microalgas Dunaliella salina, Tetraselmis chuii e Isochrysis galbana = Erd Schreiber medium effect in culture of microalgae Dunaliella salina, Tetraselmis chuii and Isochrysis galbana

Directory of Open Access Journals (Sweden)

Vera Lucia Mota Klein

2006-04-01

Full Text Available As microalgas são utilizadas como fonte de alimento em aqüicultura. Neste trabalho cultivaram-se D. salina, T. chuii e I. galbana. O objetivo do trabalho consistiu em determinar o efeito do meio Erd Schreiber sobre o seu crescimento. Iniciou-se o cultivo com a mistura de 200 mg de Na2HPO4,7H2O, 100 mg de NaNO3 e 50 mL de extrato de solo. No monitoramento, manteve-se a temperatura entre 24 - 28 oC, a salinidade a 34 ppt, à iluminação constante, a densidade celular com uma câmara de Neubauer e um microscópio binocular modelo ZEISS. Como resultado, I. galbana, D. salina e T. chuii atingiram 969 104 cel/mL, 457 x 104 cel/mL e 258,66 x 104 cel/mL, respectivamente, e oscoeficientes angulares b foram 3,76 x 104 cel./mL/dia, 6,84 x 104 cel./mL/dia e 2,08 x 104 cel./mL/dia respectivamente, indicando bom desempenho de todas as microalgas no meio Erd Shreiber.The microalgae is used as food source in aqüicultura. In this work they had cultivated D. salina , T. chuii and I. galbana . The objective of the work is to determine the effect of Erd Schreiber´s culture medium on the microalgae growth. The culture initiated mixting 200mg of Na2HPO4,7H2O, 100 mg of NaNO3 and 50 mL of soil extract. During the culture the temperature had varied between 24 and 28oC, the salinity was fixed on 34 %o, and the illumination was maintained constant. The assessment of the culture was made by a chamber of Neubauer and a binocular microscope ZEISS model. As result I. galbana D. salina and T.chuii reached 969 104 cel/mL, 457 x 104cel/mL and 258,66 x 104 cel/mL respectively and as angular coefficient 3,76 x 104 cel/mL/dia, 6,84 x 104 cel/mL/dia and 2,08 104 x cel/mL/dia respectively, showing good answer of the microalgae to the effect of Erd Schreiber´ s medium.

Z-contrast imaging of ordered structures in Pb(Mg1/3Nb2/3)O3 and Ba(Mg1/3Nb2/3)O3

International Nuclear Information System (INIS)

Yan, Y.; Pennycook, S.J.; Xu, Z.; Viehland, D.

1998-02-01

Lead-based cubic perovskites such as Pb(B 1/3 2+ B 2/3 5+ )O 3 (B 2+ Mg, Co, Ni, Zn; B 5+ = Nb, Ta) are relaxor ferroelectrics. Localized order and disorder often occur in materials of this type. In the Pb(Mg 1/3 Nb 2/3 )O 3 (PMN) family, previous studies have proposed two models, space-charge and charge-balance models. In the first model, the ordered regions carry a net negative charge [Pb(Mg 1/2 Nb 1/2 )O 3 ], while in the second model it does not carry a net charge [Pb((Mg 2/3 Nb 1/3 ) 1/2 Nb 1/2 )O 3 ]. However, no direct evidence for these two models has appeared in the literature yet. In this paper the authors report the first direct observations of local ordering in undoped and La-doped Pb(Mg 1/3 Nb 2/3 )O 3 , using high-resolution Z-contrast imaging. Because the ordered structure in Ba(Mg 1/3 Nb 2/3 )O 3 is well known, the Z-contrast image from an ordered domain is used as a reference for this study

3-{2-[(3-{(E-2-[4-(Dimethylaminophenyl]ethenyl}quinoxalin-2-yloxy]ethyl}-1,3-oxazolidin-2-one monohydrate

Directory of Open Access Journals (Sweden)

Youssef Ramli

2012-01-01

Full Text Available In the title compound, C23H24N4O3·H2O, the 1,3-oxazoline ring is nearly planar [maximum deviation = 0.059 (2 Å] and its mean plane is twisted by 30.12 (8° with respect to the quinoxaline fused-ring system; the benzene ring is nearly coplanar with the quinoxaline fused-ring system [dihedral angle = 2.52 (2°]. The water molecule of crystallization is hydrogen-bond donor to an N atom of the quinoxaline ring system as well as an O atom of the oxazolinone unit, the two hydrogen bonds generating a chain running along the c axis.

Zn2(TeO3)Br2

Science.gov (United States)

Zhang, Dong; Johnsson, Mats

2008-01-01

Single crystals of dizinc tellurium dibromide trioxide, Zn2(TeO3)Br2, were synthesized via a transport reaction in sealed evacuated silica tubes. The compound has a layered crystal structure in which the building units are [ZnO4Br] distorted square pyramids, [ZnO2Br2] distorted tetra­hedra, and [TeO3 E] tetra­hedra (E being the 5s 2 lone pair of Te4+) joined through sharing of edges and corners to form layers of no net charge. Bromine atoms and tellurium lone pairs protrude from the surfaces of each layer towards adjacent layers. This new compound Zn2(TeO3)Br2 is isostructural with the synthetic compounds Zn2(TeO3)Cl2, CuZn(TeO3)2, Co2(TeO3)Br2 and the mineral sophiite, Zn2(SeO3)Cl2. PMID:21202162

Ion-irradiation-induced phase transformation in rare earth sesquioxides (Dy2O3,Er2O3,Lu2O3)

International Nuclear Information System (INIS)

Tang, M.; Lu, P.; Valdez, J.A.; Sickafus, K.E.

2006-01-01

Polycrystalline pellets of cubic C-type rare earth structure (Ia3) Dy 2 O 3 , Er 2 O 3 , and Lu 2 O 3 were irradiated at cryogenic temperature (120 K) with 300 keV Kr ++ ions to a maximum fluence of 1x10 20 Kr/m 2 . Irradiated specimens were examined using grazing incidence x-ray diffraction and transmission electron microscopy. Ion irradiation leads to different radiation effects in these three materials. First, Dy 2 O 3 begins to transform to a monoclinic B-type rare earth structure (C2/m) at a peak dose of ∼5 displacements per atom (dpa) (corresponding to a fluence of 2x10 19 Kr/m 2 ). This transformation is nearly complete at a peak dose of 25 dpa (a fluence of 1x10 20 Kr/m 2 ). Er 2 O 3 also transforms to the B-type structure, but the transformation starts at a higher irradiation dose of about 15-20 dpa [a fluence of about (6-8)x10 19 Kr/m 2 ]. Lu 2 O 3 was found to maintain the C-type structure even at the highest irradiation dose of 25 dpa (a fluence of 1x10 20 Kr/m 2 ). No C-to-B transformation was observed in Lu 2 O 3 . The irradiation dose dependence of the C-to-B phase transformation observed in Dy 2 O 3 , Er 2 O 3 , and Lu 2 O 3 is closely related to the temperature dependence of the C-to-B phase transformation found in phase diagrams for these three materials

Solubility of NaNd(CO3)2.6H2O(c) in concentrated Na2CO3 and NaHCO3 solutions

International Nuclear Information System (INIS)

Rao, L.; Rai, D.; Felmy, A.R.; Fulton, R.W.; Novak, C.F.

1996-01-01

NaNd(CO 3 ) 2 x 6 H 2 O(c) was identified to be the final equilibrium solid phase in suspensions containing concentrated sodium carbonate (0.1 to 2.0 M) and sodium bicarbonate (0.1 to 1.0 M), with either NaNd(CO 3 ) 2 x 6 H 2 O(c) or Nd 2 (CO 3 ) 3 x xH 2 O(s) as initial solids. A thermodynamic model, based on Pitzer's specific into-interaction approach, was developed to interpret the solubility of NaNd(CO 3 ) 2 x 6 H 2 O(c) as functions of sodium carbonate and sodium bicarbonate concentrations. In this model, the solubility data of NaNd(CO 3 ) 2 x 6 H 2 O(c) were explained by assuming the formation of NdCO 3 + , Nd(CO 3 ) 2 - and Nd(CO 3 ) 3 3- species and invoking the specific ion interactions between Na + and Nd(CO 3 ) 3 3- . Ion interaction parameters for Na + -Nd(CO 3 ) 3 3- were developed to fit the solubility data. Based on the model calculations, Nd(CO 3 ) 3 3- was the predominant aqueous neodymium species in 0.1 to 2 M sodium carbonate and 0.1 to 1 M sodium bicarbonate solutions. The logarithm of the NaNd(CO 3 ) 2 x 6 H 2 O solubility product (NaNd(CO 3 ) 2 x 6 H 2 O(c)=Na + +Nd 3+ +2 CO 3 2- +6 H 2 O) was calculated to be -21.39. This model also provided satisfactory interpretation of the solubility data of the analogous Am(III) system in less concentrated carbonate and bicarbonate solutions. (orig.)

Development and characterization of nickel catalysts supported in CeO2-ZrO2-Al2O3, CeO2-La2O3-Al2O3 e ZrO2-La2O3-Al2O3 matrixes evaluated for methane reforming reactions

International Nuclear Information System (INIS)

Abreu, Amanda Jordão de

2012-01-01

Nowadays, the methane reforming is large interest industrial for the take advantage of these gas in production the hydrogen and synthesis gas (syngas). Among in the reactions of methane stand of the reactions steam reforming and carbon dioxide reforming of methane. The main catalysts uses in the methane reforming is Ni/Al 2 O 3 . However, the supported-nickel catalyst is susceptible to the deactivation or the destruction by coke deposition. The carbon dissolves in the nickel crystallite and its diffuses through the nickel, leading for formation of the carbon whiskers, which results in fragmentation of the catalyst. Modification of such catalysts, like incorporation of suitable promoters, is desirable to achieve reduction of the methane hydrogenolysis and/or promotion of the carbon gasification. Catalysts 5%Ni/Al 2 O 3 supported on solid solutions formed by ZrO 2 -CeO 2 , La 2 O 3 and CeO 2 -ZrO 2 -La 2 O 3 were prepared, characterized and evaluated in reactions steam and carbon dioxide reforming and partial oxidation of methane with objective the value effect loading solution solid in support. The supports were prepared by co-precipitation method and catalysts were prepared by impregnation method and calcined at 500 deg C. The supports and catalysts were characterized by Nitrogen Adsorption, method -rays diffraction (XRD), X-rays dispersive spectroscopy (XDS), spectroscopy in the region of the ultraviolet and the visible (UV-vis NIR) to and temperature programmed reduction (TPR), Raman Spectroscopy, X-ray absorption spectroscopy and Thermogravimetric Analysis. After all the catalytic reactions check which the addition of solid solution is beneficial for Ni/Al 2 O 3 catalysts and the best catalysts are Ni/CeO 2 -La 2 O 3 -Al 2 O 3 . (author)

Measurement of the hyperfine structure of the 4d2D3/2,5/2 levels and isotope shifts of the 4p2P3/2->4d2D3/2 and 4p2P3/2->4d2D5/2 transitions in gallium 69 and 71

International Nuclear Information System (INIS)

Rehse, Steven J.; Fairbank, William M.; Lee, Siu Au

2001-01-01

The hyperfine structure of the 4d 2 D 3/2,5/2 levels of 69,71 Ga is determined. The 4p 2 P 3/2 ->4d 2 D 3/2 (294.50-nm) and 4p 2 P 3/2 ->4d 2 D 5/2 (294.45-nm) transitions are studied by laser-induced fluorescence in an atomic Ga beam. The hyperfine A constant measured for the 4d 2 D 5/2 level is 77.3±0.9 MHz for 69 Ga and 97.9± 0.7 MHz for 71 Ga (3σ errors). The A constant measured for the 4d 2 D 3/2 level is -36.3±2.2 MHz for 69 Ga and -46.2±3.8 MHz for 71 Ga. These measurements correct sign errors in the previous determination of these constants. For 69 Ga the hyperfine B constants measured for the 4d 2 D 5/2 and the 4d 2 D 3/2 levels are 5.3±4.1 MHz and 4.6±4.2 MHz, respectively. The isotope shift is determined to be 114±8 MHz for the 4p 2 P 3/2 ->4d 2 D 3/2 transition and 115±7 MHz for the 4p 2 P 3/2 ->4d 2 D 5/2 transition. The lines of 71 Ga are shifted to the blue. This is in agreement with previous measurement. [copyright] 2001 Optical Society of America

Hydrothermal syntheses, structural, Raman, and luminescence studies of Cm[M(CN)2]3.3H2O and Pr[M(CN)2]3.3H2O (M=Ag, Au)

International Nuclear Information System (INIS)

Assefa, Zerihun; Haire, Richard G.; Sykora, Richard E.

2008-01-01

We have prepared Cm[Au(CN) 2 ] 3 .3H 2 O and Cm[Ag(CN) 2 ] 3 .3H 2 O as a part of our continuing investigations into the chemistry of the 5f-elements' dicyanometallates. Single crystals of Cm[Au(CN) 2 ] 3 .3H 2 O were obtained from the reaction of CmCl 3 and KAu(CN) 2 under mild hydrothermal conditions. Due to similarities in size, the related praseodymium compounds were also synthesized and characterized for comparison with the actinide systems. The compounds crystallize in the hexagonal space group P6 3 /mcm, where the curium and the transition metals interconnect through cyanide bridging. Crystallographic data (Mo Kα, λ=0.71073 A): Cm[Au(CN) 2 ] 3 .3H 2 O (1), a=6.6614(5) A, c=18.3135(13) A, V=703.77(9), Z=2; Pr[Au(CN) 2 ] 3 .3H 2 O (3), a=6.6662(8) A, c=18.497(3) A, V=711.83(17), Z=2; Pr[Ag(CN) 2 ] 3 .3H 2 O (4), a=6.7186(8) A, c=18.678(2) A, V=730.18(14), Z=2. The Cm 3+ and/or Pr 3+ ions are coordinated to six N-bound CN - groups resulting in a trigonal prismatic arrangement. Three oxygen atoms of coordinated water molecules tricap the trigonal prismatic arrangement providing a coordination number of nine for the f-elements. The curium ions in both compounds exhibit a strong red emission corresponding to the 6 D 7/2 → 8 S 7/2 transition. This transition is observed at 16,780 cm -1 , with shoulders at 17,080 and 16,840 cm -1 for the Ag complex, while the emission is red shifted by ∼100 cm -1 in the corresponding gold complex. The Pr systems also provide well-resolved emissions upon f-f excitation. - Graphical abstract: Coordination polymeric compounds between a trans-plutonium element, curium and transition metal ions, gold(I) and silver(I), were prepared using the hydrothermal synthetic procedure. The curium ion and the transition metals are interconnected through cyanide bridging. The Cm ion has a tricapped trigonal prismatic coordination environment with coordination number of nine. Detail photoluminescence studies of the complexes are also reported

A Strategy Based on Faith: The Enduring Appeal of Progressive American Airpower

Science.gov (United States)

2008-01-01

street lights remained on in Baghdad, as once Cockpit camera view onboard F/A–18C shows Paveway laser-guided bombs and Sidewinder missiles U .S . N...Tretler, Stephen Ran- dolph, Harvey Rishikof, Kurt Neubauer , George Ballinger, William Andrews, Joseph Connors, Christopher Holland, and students of the

[(2S-2-(3,5-Dichloro-2-oxidobenzylideneamino-3-(4-hydroxyphenylpropionato-κ3O,N,O′](dimethylformamide-κOcopper(II

Directory of Open Access Journals (Sweden)

Hong Liang

2008-04-01

Full Text Available In the title complex, [Cu(C16H11Cl2NO4(C3H7NO] , the CuII atom is coordinated by two O atoms and one N atom from the tridentate ligand L2− {LH2 = (2S-[2-(3,5-dichloro-2-hydroxybenzylideneimino]-3-(4-hydroxyphenylpropionic acid} and one O atom from a dimethylformamide molecule, resulting in a slightly distorted square-planar geometry. The structure forms a one-dimensional chain through weak coordination bonds [Cu...O 3.080 (1, Cu...Cl 3.269 (1 Å] and a three-dimensional network through O—H...O and C—H...O hydrogen bonds.

Reduction of Decoherence in the Flux Qubit

Science.gov (United States)

2014-12-08

Letters, (04 2012): 142601. doi: 10.1063/1.3700964 Nicolas Vogt, Jared Cole, Michael Marthaler, Gerd Schön. Influence of two-level fluctuators on adiabatic...a loss tangent tan δi = 1/Qi = 2.2-3×10−5 in the 4-8 GHz band. Crystalline dielectrics, such as silicon can exhibit low intrinsic loss and have been...the observed loss to the capacitive element, our measurements place and upper bound on the loss tangent of the silicon dielectric layer of tan δi = 5

Zn2(TeO3Br2

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Mats Johnsson

2008-05-01

Full Text Available Single crystals of dizinc tellurium dibromide trioxide, Zn2(TeO3Br2, were synthesized via a transport reaction in sealed evacuated silica tubes. The compound has a layered crystal structure in which the building units are [ZnO4Br] distorted square pyramids, [ZnO2Br2] distorted tetrahedra, and [TeO3E] tetrahedra (E being the 5s2 lone pair of Te4+ joined through sharing of edges and corners to form layers of no net charge. Bromine atoms and tellurium lone pairs protrude from the surfaces of each layer towards adjacent layers. This new compound Zn2(TeO3Br2 is isostructural with the synthetic compounds Zn2(TeO3Cl2, CuZn(TeO32, Co2(TeO3Br2 and the mineral sophiite, Zn2(SeO3Cl2.

(Z-Ethyl 3-(4-chlorophenyl-2-cyano-3-(2,6-difluorobenzamidoacrylate

Directory of Open Access Journals (Sweden)

Zhang Xiaoyan

2008-12-01

Full Text Available The title compound, C19H13ClF2N2O3, was prepared by the reaction of (Z-ethyl 3-amino-3-(4-chlorophenyl-2-cyanoacrylate and 2,6-difluorobenzoyl chloride. The dihedral angle between the chlorobenzene and fluorobenzene rings is 37.0 (1°. The ethyl group is disordered over two positions [occupancies = 0.52 (2:0.48 (2]. In addition to intramolecular N—H...O and N—H...F hydrogen bonds, the crystal packing shows the molecules to be connected by intermolecular C—H...O and C—H...N hydrogen bonds.

Superacid univalent metal phosphites (MH2PO3)2·H3PO3 (M Rb, Tl+) and MH2PO3·H3PO3 (M = K, Cs): synthesis and structure

International Nuclear Information System (INIS)

Kosterina, E.V.; Troyanov, S.I.; Aslanov, L.A.; Kemnits, Eh.

2001-01-01

Crystal superacid phosphites α-CsH 2 PO 3 ·H 3 PO 3 (1) and β-CsH 2 PO 3 ·H 3 PO 3 (2) were prepared by means of interaction between cesium carbonate and phosphoric acid excess. The structure of the compounds, i.e.: 1-rhombic crystal system, sp.gr. P2 1 2 1 2 1 , a = 6.033 (1), b = 6.444 (1), c = 18.345 (4) A: 2-monoclinic crystal system, sp.gr. C2/c, a = 9.990 (3), b = 12.197 (4), c = 6.866 (2) A, β = 118.14 (3) deg, was determined by the method of X-ray diffraction analysis of monocrystals at 150 K. Comparative analysis of the crystal structure and hydrogen bond systems in acid phosphites of different composition was conducted [ru

Sadhana | Indian Academy of Sciences

Indian Academy of Sciences (India)

Home; Journals; Sadhana. Nicolas Sturmel. Articles written in Sadhana. Volume 36 Issue 5 October 2011 pp 601-622. Glottal closure instant and voice source analysis using time-scale lines of maximum amplitude · Christophe D'Alessandro Nicolas Sturmel · More Details Abstract Fulltext PDF. 1Time-scale representation of ...

Evaluation of small scale laboratory and pot experiments to determine realistic transfer factors for the radionuclides 90Sr, 137Cs, 60Co and 54Mn

International Nuclear Information System (INIS)

Steffens, W.; Fuehr, F.; Mittelstaedt, W.

1980-01-01

Transfer factors for the root uptake of 90 Sr, 137 Cs, 60 Co and 54 Mn were compared using outdoor lysimeters, Kick-Brauckmann experimental pots under greenhouse conditions and Neubauer cups under growth chamber conditions. The uptake was studied in barley, potatoes, sugar beet and salad vegetables grown on either podsolic or loess soil. The transfer factors for these radionuclides under the specific conditions of the small scale Neubauer cup experiments differed greatly from those obtained from the outdoor lysimeter. In the pot experiments, the transfer factors for 90 Sr, 137 Cs and 54 Mn showed less deviation from the lysimeter results especially in crops grown on podsolic soil. For 60 Co, the transfer factors varied for the different crops grown. Transfer factors obtained in pot experiments can only be applicable to a limited extent to field conditions; factors influencing the transfer factors in pot experiments include soil volume, root density, root/shoot ratio, water supply and fertilizer application rate. (UK)

ZZ ORIGEN2.2-UPJ, A complete package of ORIGEN2 libraries based on JENDL-3.2 and JENDL-3.3

International Nuclear Information System (INIS)

Ishikawa, Makoto; Kataoka, Masaharu; Ohkawachi, Yasushi; Ohki, Shigeo; JIN, Tomoyuki; Katakura, Jun-ich; Suyama, Kenya; Yanagisawa, Hiroshi; Matsumoto, Hideki; ONOUE, Akira; Sasahara, Akihiro

2006-01-01

1 - Description: ORLIBJ32 is a package of the libraries for ORIGEN2 code based on JENDL-3.2(NEA-1642). The one grouped cross section data for PWR and BWR were compiled using the burnup calculation results by SWAT code. The FBR libraries were compiled by the analysis system used at JNC for FBR core calculation. The fission yield and decay constants data were also updated using the second version of the JNDC FP library. In ORLIBJ32, not only one-grouped cross section data but also variable actinide cross section data are prepared, using a code written in FORTRAN77. The routines should be linked to the Original ORIGEN2.1 program. The LWR Libraries are prepared based on the current PWR fuel assembly specification, and the FBR libraries are based on the request by the Japanese FBR researchers. Before compiling the libraries, the specification of fuel assembly was completely reviewed and evaluated by the members of Working Group in the Japanese Nuclear Data Committee, 'working group on the evaluation of the amount of isotope generation'. ORLIBJ33 is a new libraries based on JENDL-3.3 following the release of JENDL-3.3. The parameters used to prepare the library are the same as those of ORLIBJ32. The Original version or ORLIBJ33 is coupled with ORIGEN2.1. But after the release of ORIGEN2.2 from ORNL as CCC-0371 through RSICC, several requests for a combination with ORLIBJ33 and ORIGEN2.2 were received. During the development of ORLIBJ33, released as NEA-1642, authors found a problem in the library maker for FBR libraries, and consequently it was revised and tested in JNC-Oarai. This package 'ORIGEN2.2-UPJ' contains: - updated source code of ORIGEN2.2 of CCC-0371 to use ORLIBJ32 and ORLIBJ33, - all Original libraries in CCC-0371, - ORLIBJ32 in NEA-164/03 (but libraries for FBR are revised), - and ORLIBJ33. In this package, decay data based on the second version of the JNDC FP library and, photon and decay data libraries based on JENDL-3.3 are also included. NLB and NLIB

Homogeneity of peraluminous SiO2-B2O3-Al2O3-Na2O-CaO-Nd2O3 glasses: Effect of neodymium content

International Nuclear Information System (INIS)

Gasnier, E.; Bardez-Giboire, I.; Massoni, N.; Montouillout, V.; Pellerin, N.; Allix, M.; Ory, S.; Cabie, M.; Poissonnet, S.; Massiot, D.

2014-01-01

Considering the interest of developing new glass matrices able to immobilize higher concentration of high level nuclear wastes than currently used nuclear borosilicate compositions, glasses containing high rare earth contents are of particular interest. This study focuses on a peraluminous alumino borosilicate system SiO 2 -B 2 O 3 -Al 2 O 3 -Na 2 O-CaO-Nd 2 O 3 defined by a per-alkaline/peraluminous ratio RP = ([Na 2 O] + [CaO])/ ([Na 2 O] + [CaO] + [Al 2 O 3 ]) ≤ 0.5. Samples with various contents of Nd 2 O 3 from 0 to 10 mol% were studied using DSC, XRD, SEM, TEM, STEM and EMPA methods. The glasses present a high thermal stability even after a slow cooling treatment from the melt. Only a slight mullite crystallization is detected for low Nd 2 O 3 content (≤2.3 mol%) and crystallization of a neodymium borosilicate crystalline phase combined to a phase separation occurred at high Nd 2 O 3 content (≥8 mol%). The solubility of neodymium in the presence of aluminum is demonstrated, with higher neodymium incorporation amounts than in per-alkaline glasses. (authors)

Ho3+/Yb3+ co-doped TeO2-BaF2-Y2O3 glasses for ∼1.2 μm laser applications

Science.gov (United States)

Wang, Shunbin; Li, Chengzhi; Yao, Chuanfei; Jia, Shijie; Jia, Zhixu; Qin, Guanshi; Qin, Weiping

2017-02-01

Intense ∼1.2 μm fluorescence is observed in Ho3+/Yb3+ co-doped TeO2-BaF2-Y2O3 glasses under 915 nm laser diode excitation. The 1.2 μm emission can be ascribed to the transition 5I6→5I8 of Ho3+. With the introducing of BaF2, the content of OH in the glasses drops markedly, and the 1.2 μm emission intensity increases gradually as increasing the concentration percentage of BaF2. Furthermore, microstructured fibers based on the TeO2-BaF2-Y2O3 glasses are fabricated by using a rod-in-tube method, and a relative positive gain of ∼9.42 dB at 1175.3 nm is obtained in a 5 cm long fiber.

2-[2-Benzoyl-3,3-bis(methylsulfanylprop-2-enylidene]malononitrile

Directory of Open Access Journals (Sweden)

Joseph Nirmala

2009-08-01

Full Text Available The title compound, C15H12N2OS2, is an example of a push–pull butadiene in which the electron-releasing methylsulfanyl groups and electron-withdrawing nitrile groups on either end of the butadiene chain enhance the conjugation in the system. Short intramolecular C—H...S interactions are observed. In the crystal structure, an O...C short contact of 2.917 (3 Å is observed.

Crystal and molecular structure of the coordination compounds of Er3+ with 1-(methoxydiphenylphosphoryl)-2-diphenylphosphorylbenzene [ErL21(NO3)2]2[Er(NO3)2(H2O)5]0.333(NO3)2.333 · 2.833H2O and its ethyl substituted derivative [ErL22(NO3)2][Er(NO3)5]0.5 · 0.5H2O

International Nuclear Information System (INIS)

Polyakova, I. N.; Baulin, V. E.; Ivanova, I. S.; Pyatova, E. N.; Sergienko, V. S.; Tsivadze, A. Yu.

2015-01-01

The coordination compounds of Er 3+ with 1-(methoxydiphenylphosphoryl)-2-diphenylphosphorylbenzene [ErL 2 1 (NO 3 ) 2 ] 2 [Er(NO 3 ) 2 (H 2 O) 5 ] 0.333 (NO 3 ) 2.333 · 2.833H 2 O (I) and its ethyl substituted derivative [ErL 2 2 (NO 3 ) 2 ][Er(NO 3 ) 5 ] 0.5 · 0.5H 2 O (II) are synthesized and their crystal structures are studied. I and II contain [ErL 2 (NO 3 ) 2 ] + complex cations of identical composition and close structure. The eight-vertex polyhedron of the Er atom in the shape of a distorted octahedron with two split trans vertices is formed by the O atoms of the phosphoryl groups of L ligands and nitrate anions. L ligands close nine-membered metallocycles. The structures contain spacious channels which are populated differently, namely, by disordered [Er(NO 3 ) 2 (H 2 O) 5 ] + complex cations, NO 3 − anions, and crystallization water molecules in I and disordered [Er(NO 3 ) 5 ] 2− complex anions and crystallization water molecules in II. The IR spectra of I and II are studied

Optical characterization of Tm3+ doped Bi2O3-GeO2-Ga2O3 glasses in absence and presence of BaF2

Science.gov (United States)

Han, Kexuan; Zhang, Peng; Wang, Shunbin; Guo, Yanyan; Zhou, Dechun; Yu, Fengxia

2016-01-01

In this paper, Two new Bi2O3-GeO2-Ga2O3 glasses (one presence of BaF2) doped with 1mol% Tm2O3 were prepared by melt-quenching technique. Differential thermal analysis (DTA), the absorption, Raman, IR spectra and fluorescence spectra were measured. The Judd–Ofelt intensity parameters, emission cross section, absorption cross section, and gain coefficient of Tm3+ ions were comparatively investigated. After the BaF2 introduced, the glass showed a better thermal stability, lower phonon energy and weaker OH− absorption coefficient, meanwhile, a larger ~1.8 μm emission cross section σem (7.56 × 10−21 cm2) and a longer fluorescence lifetime τmea (2.25 ms) corresponding to the Tm3+: 4F3 → 3H6 transition were obtained, which is due to the addition of fluoride in glass could reduce the quenching rate of hydroxyls and raise the cross-relaxation (3H6 + 3H4 → 3F4 + 3F4) rate. Our results suggest that the Tm3+ doped Bi2O3-GeO2-Ga2O3 glass with BaF2 might be potential to the application in efficient ~1.8 μm lasers system. PMID:27506152

Optical characterization of Tm(3+) doped Bi2O3-GeO2-Ga2O3 glasses in absence and presence of BaF2.

Science.gov (United States)

Han, Kexuan; Zhang, Peng; Wang, Shunbin; Guo, Yanyan; Zhou, Dechun; Yu, Fengxia

2016-08-10

In this paper, Two new Bi2O3-GeO2-Ga2O3 glasses (one presence of BaF2) doped with 1mol% Tm2O3 were prepared by melt-quenching technique. Differential thermal analysis (DTA), the absorption, Raman, IR spectra and fluorescence spectra were measured. The Judd-Ofelt intensity parameters, emission cross section, absorption cross section, and gain coefficient of Tm(3+) ions were comparatively investigated. After the BaF2 introduced, the glass showed a better thermal stability, lower phonon energy and weaker OH(-) absorption coefficient, meanwhile, a larger ~1.8 μm emission cross section σem (7.56 × 10(-21) cm(2)) and a longer fluorescence lifetime τmea (2.25 ms) corresponding to the Tm(3+): (4)F3 → (3)H6 transition were obtained, which is due to the addition of fluoride in glass could reduce the quenching rate of hydroxyls and raise the cross-relaxation ((3)H6 + (3)H4 → (3)F4 + (3)F4) rate. Our results suggest that the Tm(3+) doped Bi2O3-GeO2-Ga2O3 glass with BaF2 might be potential to the application in efficient ~1.8 μm lasers system.

Relationship of 2,3-diphosphoglycerate and 2,3-diphosphoglycerate mutase in various mammals.

Science.gov (United States)

Chemtob, S; Gibb, W; Bard, H

1980-01-01

To investigate a possible mechanism involved in the regulation of 2,3-diphosphoglycerate (2,3-DPG) synthesis, 2,3-DPG mutase (DPGM) was measured in different mammals presenting large differences in 2,3-DPG concentration between fetal, neonatal and adult life to see the activity of this enzyme, necessary for 2,3-DPG synthesis, was related to the levels of 2,3-DPG. The data demonstrated that the minimal levels of 2,3-DPG in the adult sheep are likely due to the very low levels of DPGM. Also these findings show that the increases in 2,3-DPG levels, found in the newborn sheep during the 1st week of life, in adult rabbit and guinea pig when compared with their fetuses, are not due to an increase in levels of the DPGM.

Intense 2.7 µm emission and structural origin in Er3+-doped bismuthate (Bi2O3-GeO2-Ga2O3-Na2O) glass.

Science.gov (United States)

Guo, Yanyan; Li, Ming; Hu, Lili; Zhang, Junjie

2012-01-15

The 2.7 μm emission properties in Er3+-doped bismuthate (Bi2O3-GeO2-Ga2O3-Na2O) glass were investigated in the present Letter. An intense 2.7 μm emission in Er3+-doped bismuthate glass was observed. It is found that Er3+-doped bismuthate glass possesses high spontaneous transition probability A (65.26 s(-1)) and large 2.7 μm emission cross section σ(em) (9.53×10(-21) cm2) corresponding to the stimulated emission of Er3+:4I11/2→4I13/2 transition. The emission characteristic and energy transfer process upon excitation of a conventional 980 nm laser diode in bismuthate glass were analyzed. Additionally, the structure of bismuthate glass was analyzed by the Raman spectrum. The advantageous spectroscopic characteristics of Er3+ single-doped bismuthate glass together with the prominent thermal property indicate that bismuthate glass might become an attractive host for developing solid-state lasers around 2.7 μm.

Synthesis of the (N2)3- radical from Y2+ and its protonolysis reactivity to form (N2H2)2- via the Y[N(SiMe3)2]3/KC8 reduction system.

Science.gov (United States)

Fang, Ming; Lee, David S; Ziller, Joseph W; Doedens, Robert J; Bates, Jefferson E; Furche, Filipp; Evans, William J

2011-03-23

Examination of the Y[N(SiMe(3))(2)](3)/KC(8) reduction system that allowed isolation of the (N(2))(3-) radical has led to the first evidence of Y(2+) in solution. The deep-blue solutions obtained from Y[N(SiMe(3))(2)](3) and KC(8) in THF at -35 °C under argon have EPR spectra containing a doublet at g(iso) = 1.976 with a 110 G hyperfine coupling constant. The solutions react with N(2) to generate (N(2))(2-) and (N(2))(3-) complexes {[(Me(3)Si)(2)N](2)(THF)Y}(2)(μ-η(2):η(2)-N(2)) (1) and {[(Me(3)Si)(2)N](2)(THF)Y}(2)(μ-η(2):η(2)-N(2))[K(THF)(6)] (2), respectively, and demonstrate that the Y[N(SiMe(3))(2)](3)/KC(8) reaction can proceed through an Y(2+) intermediate. The reactivity of (N(2))(3-) radical with proton sources was probed for the first time for comparison with the (N(2))(2-) and (N(2))(4-) chemistry. Complex 2 reacts with [Et(3)NH][BPh(4)] to form {[(Me(3)Si)(2)N](2)(THF)Y}(2)(μ-N(2)H(2)), the first lanthanide (N(2)H(2))(2-) complex derived from dinitrogen, as well as 1 as a byproduct, consistent with radical disproportionation reactivity.

Magnetic ordering of Hf{sub 3}Ni{sub 2}Si{sub 3}-type {Sm, Tb, Er}{sub 3}Co{sub 2}Ge{sub 3} and {Tb, Ho}{sub 3}Ni{sub 2}Ge{sub 3} compounds

Energy Technology Data Exchange (ETDEWEB)

Morozkin, A.V., E-mail: morozkin@tech.chem.msu.ru [Department of Chemistry, Moscow State University, Leninskie Gory, House 1, Building 3, Moscow, GSP-1, 119991 (Russian Federation); Yapaskurt, V.O. [Department of Petrology, Geological Faculty Moscow State University, Leninskie Gory, Moscow 119991 (Russian Federation); Nirmala, R. [Indian Institute of Technology Madras, Chennai 600036 (India); Quezado, S.; Malik, S.K. [Departamento de Física Teórica e Experimental, Universidade Federal do Rio Grande do Norte, Natal 59082-970 (Brazil); Mozharivskyj, Y. [Department of Chemistry and Chemical Biology, McMaster University, 1280 Main Street West, Hamilton, Ontario, Canada L8S 4M1 (Canada); Isnard, O. [CNRS, Institut. Néel, 25 rue des Martyrs BP166 x, F-38042 Grenoble (France); Université Grenoble Alpes, Inst. Néel, F-38042 Grenoble (France)

2017-02-15

The magnetic ordering of Hf{sub 3}Ni{sub 2}Si{sub 3}-type {Sm, Tb, Er}{sub 3}Co{sub 2}Ge{sub 3} and {Tb, Ho}{sub 3}Ni{sub 2}Ge{sub 3} compounds (space group Cmcm, oC32) was investigated via magnetization measurements and neutron diffraction study in a zero-applied field. {Sm, Tb, Er}{sub 3}Co{sub 2}Ge{sub 3} and Ho{sub 3}Ni{sub 2}Ge{sub 3} exhibit field sensitive complex antiferromagnetic orderings with T{sub N}=51 K, T{sub m}=10 K for Sm{sub 3}Co{sub 2}Ge{sub 3}, T{sub N}=34 K, T{sub m}=13 K for Tb{sub 3}Co{sub 2}Ge{sub 3}, T{sub N}=7 K for Er{sub 3}Co{sub 2}Ge{sub 3} and T{sub N}=11 K for Ho{sub 3}Ni{sub 2}Ge{sub 3}. At 2 K and above the critical field of ~5 kOe, 20 kOe, 4 kOe and 7 kOe for Sm{sub 3}Co{sub 2}Ge{sub 3}, Tb{sub 3}Co{sub 2}Ge{sub 3}, Er{sub 3}Co{sub 2}Ge{sub 3} and Ho{sub 3}Ni{sub 2}Ge{sub 3}, respectively, saturation magnetizations per rare-earth atom are 6.5 μ{sub B} for Tb{sub 3}Co{sub 2}Ge{sub 3}, 7.0 μ{sub B} for Er{sub 3}Co{sub 2}Ge{sub 3} and 8.0 μ{sub B} for Ho{sub 3}Ni{sub 2}Ge{sub 3} in the field of 140 kOe, whereas magnetization of Sm{sub 3}Co{sub 2}Ge{sub 3} has an antiferromagnetic behaviour. The isothermal magnetic entropy change, ΔS{sub m}, indicates a field-induced ferromagnetic ordering in Sm{sub 3}Co{sub 2}Ge{sub 3}, Tb{sub 3}Co{sub 2}Ge3, Er{sub 3}Co{sub 2}Ge{sub 3} and Ho{sub 3}Ni{sub 2}Ge{sub 3} with a maximal ΔS{sub m} value of −10.9 J/kg K for Ho{sub 3}Ni{sub 2}Ge{sub 3} at 11 K for a field change of 50 kOe. In a zero-applied magnetic field, below T{sub N}=33 K and down to T{sub m}{sup ND}=15 K Tb{sub 3}Ni{sub 2}Ge{sub 3} shows an ac-antiferromagnetic ordering with the C2′/c magnetic space group, a K{sub 0}=[0, 0, 0] propagation vector and a a{sub Tb3Ni2Ge3}×b{sub Tb3Ni2Ge3}×c{sub Tb3Ni2Ge3} magnetic unit cell. Below T{sub m}{sup ND}=15 K, its magnetic structure is a sum of the ac-antiferromagnetic component with the C2′/c magnetic space group of the K{sub 0} vector and a sine-modulated a

Eu3+/Tb3+-doped La2O2CO3/La2O3 nano/microcrystals with multiform morphologies: facile synthesis, growth mechanism, and luminescence properties.

Science.gov (United States)

Li, Guogang; Peng, Chong; Zhang, Cuimiao; Xu, Zhenhe; Shang, Mengmeng; Yang, Dongmei; Kang, Xiaojiao; Wang, Wenxin; Li, Chunxia; Cheng, Ziyong; Lin, Jun

2010-11-15

LaCO(3)OH nano/microcrystals with a variety of morphologies/sizes including nanoflakes, microflowers, nano/microrhombuses, two-double microhexagrams sandwichlike microspindles, and peach-nucleus-shaped microcrystals have been synthesized via a facile homogeneous precipitation route under mild conditions. A series of controlled experiments indicate that the pH values in the initial reaction systems, carbon sources, and simple ions (NH(4)(+) and Na(+)) were responsible for the shape determination of the LaCO(3)OH products. A possible formation mechanism for these products with diverse architectures has been presented. After annealing at suitable temperatures, LaCO(3)OH was easily converted to La(2)O(2)CO(3) and La(2)O(3) with the initial morphologies. A systematic study on the photoluminescence and cathodoluminescence properties of Eu(3+)- or Tb(3+)-doped La(2)O(2)CO(3)/La(2)O(3) samples has been performed in detail. The excitation and site-selective emission spectra were recorded to investigate the microstructure, site symmetry, and difference in the (5)D(0) → (7)F(2) transition of Eu(3+) ions in La(2)O(2)CO(3) and La(2)O(3) host lattices. In addition, the dependence of the luminescent intensity on the morphology for the as-prepared La(2)O(2)CO(3)/La(2)O(3):Ln(3+) (Ln = Eu, Tb) samples has been investigated. The ability of generating diverse morphologies and multiemitting colors for different rare-earth activator ion (Ln = Eu, Tb) doped La(2)O(2)CO(3)/La(2)O(3) nano/microstructures provides a great opportunity for the systematic evaluation of morphology-dependent luminescence properties, as well as the full exploration of their application in many types of color display fields.

Comments on "Precise model measurements versus theoretical prediction of barrier insertion loss in presence of the ground" [J. Acoust. Soc. Am. 73, 44–54 (1983)

DEFF Research Database (Denmark)

Rasmussen, Karsten Bo

1983-01-01

Some of the theoretical curves in the article by J. Nicolas et al. [J. Acoust. soc. Am. 73, 44–54 (1983)] appear to be erroneous.......Some of the theoretical curves in the article by J. Nicolas et al. [J. Acoust. soc. Am. 73, 44–54 (1983)] appear to be erroneous....

3H-1,2-Benzodithiole-3-thione

Directory of Open Access Journals (Sweden)

Khaled Boukebbous

2016-10-01

Full Text Available The almost planar (r.m.s. deviation = 0.034 Å title compound, C7H4S3, was synthesized by reacting 2,2-dithiodibenzoic acid with phosphorus pentasulfide in xylene solution. In the crystal, short S...S [3.3727 (14, 3.3765 (13 and 3.4284 (13 Å] contacts and aromatic π–π stacking [shortest centroid–centroid separation = 3.618 (2 Å] are observed.

Poly[(μ3-benzene-1,3,5-tricarboxylato-κ3O1:O3:O5(μ2-2-methylimidazolato-κ2N:N′tris(2-methylimidazole-κNdizinc(II

Directory of Open Access Journals (Sweden)

Palanikumar Maniam

2011-06-01

Full Text Available Hydrothermal reaction involving zinc nitrate hexahydrate, trisodium benzene-1,3,5-tricarboxylate (Na3BTC and 2-methylimidazole (2-MeImH yielded the title compound, [Zn2(C9H3O6(C4H5N2(C4H6N23]. In this mixed-ligand metal-organic compound, Zn2+ ions are coordinated by N atoms from 2-MeImH molecules and (2-MeIm− ions, as well as by O atoms from (BTC3− ions. This results in two different distorted tetrahedra, viz. ZnN3O and ZnN2O2. These tetrahedra are interconnected via (BTC3− ions and N:N′-bridging (2-MeIm− ions, thus forming a layered structure in the bc plane. Hydrogen bonds between the O atoms of carboxylate ions and NH groups of 2-MeImH ligands link the layers into a three-dimensional structure.

Electronic structure of Ti/sub 2/O/sub 3/, V/sub 2/O/sub 3/, and Cr/sub 2/O/sub 3/

Energy Technology Data Exchange (ETDEWEB)

Bondarenko, T N; Zhurakovskii, E A; Dzeganovskii, V P [AN Ukrainskoj SSR, Kiev. Inst. Problem Materialovedeniya

1975-11-01

Electronic structure of oxides Ti/sub 2/O/sub 3/, V/sub 2/O/sub 3/, Cr/sub 2/O/sub 3/ was elucidated by means of X-ray and ESCA methods and the results were compared with the data obtained by other methods and with the available models of electronic structures. Energy diagram of V/sub 2/O/sub 3/ and common energy scale of X-ray spectra of Ti and Cr in Ti/sub 2/O/sub 3/ and Cr/sub 2/O/sub 3/ are presented. X-ray spectra show that these oxides possess the states which are related genetically to the M4p-states i.e. the X-ray data complement essentially to the result of optical and electrophysical measurements. MO and M/sub 2/O/sub 3/ compounds in the region of Fermi level have overlapping emission and absorption spectra which is specific to the matters with the metallic type of bonding. Actually TiO, VO, Ti/sub 2/O/sub 3/ and V/sub 2/O/sub 3/ have metallic type of bonding. However such overlap was observed in Cr/sub 2/O/sub 3/ as well whose forbidden zone according to photoconductivity measurments is about 3 eV. Absence of energy gap between emission and absorption spectra in Cr/sub 2/O/sub 3/ may be explained by traces of impurities which convert dielectrics conductors - impurities act as agents caus:ng filling or generation of vacancies rather than independent allowing additives. On the other hand this may be due to the defects in Cr/sub 2/O/sub 3/ lattice which may cause appearance of excited states in forbidden zone. These investigations enable to draw energy diagram of V/sub 2/O/sub 3/ and to combine the spectra of M in Ti/sub 2/O/sub 3/ into common energy scheme. Analysis of the diagram and combined spectra revealed great similarity in the electronic structures of M/sub 2/O/sub 3/ oxides (M - Ti, V, Cr) .

D3-??????????????????????? ? ???? ?????????? ?2 ?????? ?????? ?????

OpenAIRE

?????????, ????; ???????, ???????; ??????, ?????????; ?????????????, ????; ??????, ??????

2011-01-01

????? ?????? ??????? ????? ????? ??????????? ?????? ?????? ????? ? ?????? ? ???????? ????? ?????????. ?????????? ???????????? ?????? ?? ?2 ?????? ?????? ????? ??????? ?? D3 ???????????????? ??????? ??????????? ?????? ????????? ????? ?????????? ??? ??? ??????????. ? ????? ????????????? ??????????? ??? ????????? ????????????? ?????????? ???? ?????????? ?????????? ????? ????????? ?????? ???????? ?? D3-????????????????? ???????.

Leukocyte profile of different breeds of the Nigerian cattle in ...

African Journals Online (AJOL)

The total white blood cell (WBC) count and differential counts of WBC were determined using Neubauer Chamber and Thin blood smear techniques. Data generated were analysed using Genstat statistical software, with sex, breed and haemparasite species detected as factors. Results showed that 22% of the cattle were ...

The Effect Of Hexane Extract Of Azidirachta indica Leaves On ...

African Journals Online (AJOL)

Improved Neubauer's chamber was used to determine the testicular sperm reserve. The right testis, liver, kidney and spleen were routinely prepared for light microscopy. The control mice had significantly higher (P<0.05) testicular sperm reserve than the treatment group mice, which received the highest dose of the extract.

(2E-3-(6-Chloro-2-methoxyquinolin-3-yl-1-(2-methyl-4-phenylquinolin-3-ylprop-2-en-1-one acetone monosolvate

Directory of Open Access Journals (Sweden)

Edward R. T. Tiekink

2013-08-01

Full Text Available In the title solvate, C29H21ClN2O2·C3H6O, a prop-2-en-1-one bridge links two quinolinyl residues; the latter are almost perpendicular [dihedral angle = 78.27 (6°]. The dihedral angle between the quinonyl ring system and its pendant phenyl group is 59.78 (8°. A small twist in the bridging prop-2-en-1-one group is noted [O=C—C=C torsion angle = −10.6 (3°]. In the crystal, a three-dimensional architecture arises as a result of C—H...O and π–π stacking [centroid–centroid distances = 3.5504 (12–3.6623 (12 Å].

Formation, stability and structural characterization of ternary MgUO{sub 2}(CO{sub 3}){sub 3}{sup 2-} and Mg{sub 2}UO{sub 2}(CO{sub 3}){sub 3}(aq) complexes

Energy Technology Data Exchange (ETDEWEB)

Lee, Jun-Yeop; Yun, Jong-Il [KAIST, Daejeon (Korea, Republic of). Dept. of Nuclear and Quantum Engineering; Vespa, Marika; Gaona, Xavier; Dardenne, Kathy; Rothe, Joerg; Rabung, Thomas; Altmaier, Marcus [Karlsruhe Institute of Technology, Karlsruhe (Germany). Inst. for Nuclear Waste Disposal

2017-06-01

The formation of ternary Mg-UO{sub 2}-CO{sub 3} complexes under weakly alkaline pH conditions was investigated by time-resolved laser fluorescence spectroscopy (TRLFS) and extended X-ray absorption fine structure (EXAFS) and compared to Ca-UO{sub 2}-CO{sub 3} complexes. The presence of two different Mg-UO{sub 2}-C{sub 3} complexes was identified by means of two distinct fluorescence lifetimes of 17±2 ns and 51±2 ns derived from the multi-exponential decay of the fluorescence signal. Slope analysis in terms of fluorescence intensity coupled with fluorescence intensity factor as a function of log [Mg(II)] was conducted for the identification of the Mg-UO{sub 2}-CO{sub 3} complexes forming. For the first time, the formation of both MgUO{sub 2}(CO{sub 3}){sub 3}{sup 2-} and Mg{sub 2}UO{sub 2}(CO{sub 3}){sub 3}(aq) species was confirmed and the corresponding equilibrium constants were determined as log β {sub 113}=25.8±0.3 and β {sub 213}=27.1±0.6, respectively. Complementarily, fundamental structural information for both Ca-UO{sub 2}-CO{sub 3} and Mg-UO{sub 2}-CO{sub 3} complexes was gained by extended EXAFS revealing very similar structures between these two species, except for the clearly shorter U-Mg distance (3.83 Aa) compared with U-Ca distance (4.15 Aa). These results confirmed the inner-sphere character of the Ca/Mg-UO{sub 2}-CO{sub 3} complexes. The formation constants determined for MgUO{sub 2}(CO{sub 3}){sub 3}{sup 2-} and Mg{sub 2}UO{sub 2}(CO{sub 3}){sub 3}(aq) species indicate that ternary Mg-UO{sub 2}-CO{sub 3} complexes contribute to the relevant uranium species in carbonate saturated solutions under neutral to weakly alkaline pH conditions in the presence of Mg(II) ions, which will induce notable influences on the U(VI) chemical species under seawater conditions.

Atmospheric chemistry of HFE-7000 (CF(3)CF (2)CF (2)OCH (3)) and 2,2,3,3,4,4,4-heptafluoro-1-butanol (CF (3)CF (2)CF (2)CH (2)OH): kinetic rate coefficients and temperature dependence of reactions with chlorine atoms.

Science.gov (United States)

Díaz-de-Mera, Yolanda; Aranda, Alfonso; Bravo, Iván; Rodríguez, Diana; Rodríguez, Ana; Moreno, Elena

2008-10-01

The adverse environmental impacts of chlorinated hydrocarbons on the Earth's ozone layer have focused attention on the effort to replace these compounds by nonchlorinated substitutes with environmental acceptability. Hydrofluoroethers (HFEs) and fluorinated alcohols are currently being introduced in many applications for this purpose. Nevertheless, the presence of a great number of C-F bonds drives to atmospheric long-lived compounds with infrared absorption features. Thus, it is necessary to improve our knowledge about lifetimes and global warming potentials (GWP) for these compounds in order to get a complete evaluation of their environmental impact. Tropospheric degradation is expected to be initiated mainly by OH reactions in the gas phase. Nevertheless, Cl atoms reaction may also be important since rate constants are generally larger than those of OH. In the present work, we report the results obtained in the study of the reactions of Cl radicals with HFE-7000 (CF(3)CF(2)CF(2)OCH(3)) (1) and its isomer CF(3)CF(2)CF(2)CH(2)OH (2). Kinetic rate coefficients with Cl atoms have been measured using the discharge flow tube-mass spectrometric technique at 1 Torr of total pressure. The reactions of these chlorofluorocarbons (CFCs) substitutes have been studied under pseudo-first-order kinetic conditions in excess of the fluorinated compounds over Cl atoms. The temperature ranges were 266-333 and 298-353 K for reactions of HFE-7000 and CF(3)CF(2)CF(2)CH(2)OH, respectively. The measured room temperature rate constants were k(Cl+CF(3)CF(2)CF(2)OCH(3)) = (1.24 +/- 0.28) x 10(-13) cm(3) molecule(-1) s(-1)and k(Cl+CF(3)CF(2)CF(2)CH(2)OH) = (8.35 +/- 1.63) x 10(-13) cm(3) molecule(-1) s(-1) (errors are 2sigma + 10% to cover systematic errors). The Arrhenius expression for reaction 1 was k (1)(266-333 K) = (6.1 +/- 3.8) x 10(-13)exp[-(445 +/- 186)/T] cm(3) molecule(-1) s(-1) and k (2)(298-353 K) = (1.9 +/- 0.7) x 10(-12)exp[-(244 +/- 125)/T] cm(3) molecule(-1) s(-1) (errors

Atmospheric chemistry of (CF3)2CFOCH3

DEFF Research Database (Denmark)

Andersen, Lene Løffler; Østerstrøm, Freja From; Nielsen, Ole John

2014-01-01

FTIR smog chamber techniques were used to measure k(Cl + (CF 3)2CFOCH3) = (1.80 ± 0.42) × 10-13, k(Cl + (CF3)2CFOCHO) = (1.47 ± 0.56) × 10-14, and k(OH + (CF3) 2CFOCH3) = (1.55 ± 0.24) × 10-14 cm3 molecule-1 s-1. The chlorine-atom initiated oxidation of (CF3)2CFOCH3 in air in the absence of NOX r...

Neutron irradiation damage in Al2O3 and Y2O3

International Nuclear Information System (INIS)

Clinard, F.W. Jr.; Bunch, J.M.; Ranken, W.A.

1975-01-01

Two ceramics under consideration for use in fusion reactors, Al 2 O 3 and Y 2 O 3 , were irradiated in the EBR-II fission reactor at 650, 875, and 1025 0 K to fluences between 2 and 6 x 10 21 n/cm 2 (E greater than 0.1 MeV). Samples evaluated include sapphire, Lucalox, alumina, Y 2 O 3 , and Y 2 O 3 -10 percent ZrO 2 (Yttralox). All Al 2 O 3 specimens swelled significantly (1 to 3 percent), with most of the growth observed in sapphire along the c-axis at the higher temperatures. Al 2 O 3 samples irradiated at 875 to 1025 0 K contained a high density of small aligned ''pores''. Irradiated Y 2 O 3 -based ceramics exhibited dimensional stability and a defect content consisting primarily of unresolved damage and/or dislocation loops. The behavior of these ceramics under irradiation is discussed, and the relevance of fission neutron damage studies to fusion reactor applications is considered. (auth)

2-Aminopyrimidine-3,3,3-triphenylpropanoic acid (1/1).

Science.gov (United States)

Serafin, Mateusz F; Wheeler, Kraig A

2007-11-01

The title bimolecular compound, C(4)H(5)N(3).C(21)H(18)O(2), constructed from 2-aminopyrimidine and 3,3,3-triphenylpropanoic acid, forms a tetramolecular hydrogen-bonded motif via O-H...N, N-H...O and N-H...N contacts. This aggregate organizes to give crystal-packing motifs with hydrophilic and hydrophobic regions.

Faraday rotation and photoluminescence in heavily Tb(3+)-doped GeO2-B2O3-Al2O3-Ga2O3 glasses for fiber-integrated magneto-optics.

Science.gov (United States)

Gao, Guojun; Winterstein-Beckmann, Anja; Surzhenko, Oleksii; Dubs, Carsten; Dellith, Jan; Schmidt, Markus A; Wondraczek, Lothar

2015-03-10

We report on the magneto-optical (MO) properties of heavily Tb(3+)-doped GeO2-B2O3-Al2O3-Ga2O3 glasses towards fiber-integrated paramagnetic MO devices. For a Tb(3+) ion concentration of up to 9.7 × 10(21) cm(-3), the reported glass exhibits an absolute negative Faraday rotation of ~120 rad/T/m at 632.8 nm. The optimum spectral ratio between Verdet constant and light transmittance over the spectral window of 400-1500 nm is found for a Tb(3+) concentration of ~6.5 × 10(21) cm(-3). For this glass, the crystallization stability, expressed as the difference between glass transition temperature and onset temperature of melt crystallization exceeds 100 K, which is a prerequisite for fiber drawing. In addition, a high activation energy of crystallization is achieved at this composition. Optical absorption occurs in the NUV and blue spectral region, accompanied by Tb(3+) photoluminescence. In the heavily doped materials, a UV/blue-to-green photo-conversion gain of ~43% is achieved. The lifetime of photoluminescence is ~2.2 ms at a stimulated emission cross-section σem of ~1.1 × 10(-21) cm(2) for ~ 5.0 × 10(21) cm(-3) Tb(3+). This results in an optical gain parameter σem*τ of ~2.5 × 10(-24) cm(2)s, what could be of interest for implementation of a Tb(3+) fiber laser.

Faraday rotation and photoluminescence in heavily Tb3+-doped GeO2-B2O3-Al2O3-Ga2O3 glasses for fiber-integrated magneto-optics

Science.gov (United States)

Gao, Guojun; Winterstein-Beckmann, Anja; Surzhenko, Oleksii; Dubs, Carsten; Dellith, Jan; Schmidt, Markus A.; Wondraczek, Lothar

2015-01-01

We report on the magneto-optical (MO) properties of heavily Tb3+-doped GeO2-B2O3-Al2O3-Ga2O3 glasses towards fiber-integrated paramagnetic MO devices. For a Tb3+ ion concentration of up to 9.7 × 1021 cm−3, the reported glass exhibits an absolute negative Faraday rotation of ~120 rad/T/m at 632.8 nm. The optimum spectral ratio between Verdet constant and light transmittance over the spectral window of 400–1500 nm is found for a Tb3+ concentration of ~6.5 × 1021 cm−3. For this glass, the crystallization stability, expressed as the difference between glass transition temperature and onset temperature of melt crystallization exceeds 100 K, which is a prerequisite for fiber drawing. In addition, a high activation energy of crystallization is achieved at this composition. Optical absorption occurs in the NUV and blue spectral region, accompanied by Tb3+ photoluminescence. In the heavily doped materials, a UV/blue-to-green photo-conversion gain of ~43% is achieved. The lifetime of photoluminescence is ~2.2 ms at a stimulated emission cross-section σem of ~1.1 × 10−21 cm2 for ~ 5.0 × 1021 cm−3 Tb3+. This results in an optical gain parameter σem*τ of ~2.5 × 10−24 cm2s, what could be of interest for implementation of a Tb3+ fiber laser. PMID:25754819

75 FR 10026 - Proposed Collection; Comment Request for Forms W-2, W-2c, W-2AS, W-2GU, W-2VI, W-3, W-3c, W-3cPR...

Science.gov (United States)

2010-03-04

... W-2, W-2c, W-2AS, W-2GU, W-2VI, W-3, W-3c, W-3cPR, W-3PR, and W-3SS AGENCY: Internal Revenue Service....C. 3506(c)(2)(A)). Currently, the IRS is soliciting comments concerning Forms W-2, W-2c, W-2AS, W-2GU, W-2VI, W-3, W-3c, W- 3cPR, W-3PR, and W-3SS. DATES: Written comments should be received on or...

Preparation of YBa2Cu3O7-δ powders by the thermal decomposition of a heteronuclear complex, CuY1/3Ba2/3(dhbaen)(NO3)1/3(H2O)3

International Nuclear Information System (INIS)

Hasegawa, E.; Aono, H.; Sadaoka, Y.; Traversa, E.

1999-01-01

YBa 2 Cu 3 O 7-δ powders were prepared by the thermal decomposition of a heteronuclear complex, CuY 1/3 Ba 2/3 (dhbaen)(NO 3 ) 1/3 (H 2 O) 3 . The products of the complex thermal decomposition were analyzed by TG-DTA, XRD, SEM-Auger and XPS. The decomposition of the CuY 1/3 Ba 2/3 -complex was obtained at about 500 C and the product was a mixture of oxides and carbonates. The formation of YBa 2 Cu 3 O 7-δ proceeded at 800 C, with a gradual decomposition of the carbonates. A homogeneous distribution of each element, Y, Ba, and Cu, was observed for the decomposed CuY 1/3 Ba 2/3 -complex by SEM-Auger analysis. The binding energy values of Ba3d 5/2 and O1s photolines from Ba and O in the superconductive lattice did not shift during the sputtering period. Furthermore, the formation of Ba rich regions on the surface was depressed by using the complex as a starting material for homogeneous 123-oxide, YBa 2 Cu 3 O 7-δ . (orig.)

Yield and Nitrogen Assimilation of Potato Varieties (Solanum tuberosum L.) as Affected by Saline Water Irrigation and Organic Manure

International Nuclear Information System (INIS)

Hamdy, A.; Gadalla, A.M.; El-Kholi, A.F.; Galal, Y.G.M.; Ismail, M.M.

2008-01-01

The experiment was carried out in lysimeter under controlled greenhouse conditions. Saline water was applied in different levels, i.e. fresh water, 3 and 6 dS/m. Organic manure were applied to soil at rates of 0, 2.6 and 5.2 kg/m2. Basal recommended doses of P and K were applied. Labelled urea (10% a.e.) was applied at rate of 200 kg N/ha. 15 N technique was used to evaluate N-uptake and fertilizer efficiency. Comparison held between the two potato varieties indicated that higher reduction in shoot dry weight was recorded with Nicola variety than Spunta one which irrigated with 6 dS/m water salinity level. Addition of 2.6 kg/m 2 organic rate induced an increase in N uptake with fresh water and 3 dS/m salinity then tended to decrease with 6 dS/m level as compared to the untreated control. Concerning the nitrogen fertilization, data of 15 N analysis showed that, water salinity levels combined with organic addition rates were frequently affected the nitrogen derived from fertilizer and consequently the fertilizer use efficiency. Most of nitrogen was derived from the applied nitrogen fertilizer with maximum accumulation in tuber rather than shoots or roots of both potato varieties. Gradual increase of tuber starch with increasing salinity levels was noticed with addition of 2.6 kg/m 2 of organic matter. In general, Spunta variety showed some superiority in tuber starch over those of Nicola variety tuber

The Vaporization of B2O3(l) to B2O3(g) and B2O2(g)

Science.gov (United States)

Jacobson, Nathan S.; Myers, Dwight L.

2011-01-01

The vaporization of B2O3 in a reducing environment leads to formation of both B2O3(g) and B2O2(g). While formation of B2O3(g) is well understood, many questions about the formation of B2O2(g) remain. Previous studies using B(s) + B2O3(l) have led to inconsistent thermodynamic data. In this study, it was found that after heating, B(s) and B2O3(l) appear to separate and variations in contact area likely led to the inconsistent vapor pressures of B2O2(g). To circumvent this problem, an activity of boron is fixed with a two-phase mixture of FeB and Fe2B. Both second and third law enthalpies of formation were measured for B2O2(g) and B2O3(g). From these the enthalpies of formation at 298.15 K are calculated to be -479.9 +/- 41.5 kJ/mol for B2O2(g) and -833.4 +/- 13.1 kJ/mol for B2O3(g). Ab initio calculations to determine the enthalpies of formation of B2O2(g) and B2O3(g) were conducted using the W1BD composite method and show good agreement with the experimental values.

Biotransformation of 2,3,3,3-tetrafluoropropene (HFO-1234yf)

International Nuclear Information System (INIS)

Schuster, Paul; Bertermann, Ruediger; Snow, Timothy A.; Han Xing; Rusch, George M.; Jepson, Gary W.; Dekant, Wolfgang

2008-01-01

2,3,3,3-Tetrafluoropropene (HFO-1234yf) is a non-ozone-depleting fluorocarbon replacement with a low global warming potential which has been developed as refrigerant. The biotransformation of HFO-1234yf was investigated after inhalation exposure. Male Sprague-Dawley rats were exposed to air containing 2000, 10,000, or 50,000 ppm HFO-1234yf for 6 h and male B6C3F1 mice were exposed to 50,000 ppm HFO-1234yf for 3.5 h in a dynamic exposure chamber (n = 5/concentration). After the end of the exposure, animals were individually housed in metabolic cages and urines were collected at 6 or 12-hour intervals for 48 h. For metabolite identification, urine samples were analyzed by 1 H-coupled and decoupled 19 F-NMR and by LC/MS-MS or GC/MS. Metabolites were identified by 19 F-NMR chemical shifts, signal multiplicity, 1 H- 19 F coupling constants and by comparison with synthetic reference compounds. In all urine samples, the predominant metabolites were two diastereomers of N-acetyl-S-(3,3,3-trifluoro-2-hydroxy-propyl)-L-cysteine. In 19 F-NMR, the signal intensity of these metabolites represented more than 85% (50,000 ppm) of total 19 F related signals in the urine samples. Trifluoroacetic acid, 3,3,3-trifluorolactic acid, 3,3,3-trifluoro-1-hydroxyacetone, 3,3,3-trifluoroacetone and 3,3,3-trifluoro-1,2-dihydroxypropane were present as minor metabolites. Quantification of N-acetyl-S-(3,3,3-trifluoro-2-hydroxy-propyl)-L-cysteine by LC/MS-MS showed that most of this metabolite (90%) was excreted within 18 h after the end of exposure (t 1/2 app. 6 h). In rats, the recovery of N-acetyl-S-(3,3,3-trifluoro-2-hydroxy-propyl)-L-cysteine excreted within 48 h in urine was determined as 0.30 ± 0.03, 0.63 ± 0.16, and 2.43 ± 0.86 μmol at 2000, 10,000 and 50,000 ppm, respectively suggesting only a low extent (<< 1% of dose received) of biotransformation of HFO-1234yf. In mice, the recovery of this metabolite was 1.774 ± 0.4 μmol. Metabolites identified after in vitro incubations of HFO

Study of directionally solidified eutectic Al2O3-ZrO2(3%Y2O3 doped with TiO2

Directory of Open Access Journals (Sweden)

Peña, J. I.

2007-06-01

Full Text Available An study of directionally grown samples of the eutectic composition in the Al2O3-ZrO2 (3 mol% Y2O3 system, with small TiO2 additions (1 wt%, is presented. The microstructural changes induced by this addition are analysed using SEM (EDX techniques. The mechanical changes, when TiO2 is added, are studied by measuring the flexural strength by three point bending. Also, the toughness is determined by Vickers indentation method. When slow growth rates (10 mm/h are used, interpenetratred and homogeneous microstructure is obtained, independently of the TiO2 doping. When growth rates are higher (300 and 1000 mm/h the structure changes and the phases are organized in form of colonies or cells, which have smaller size when TiO2 is present. This size reduction is accompanied with an increase of the toughness.Este trabajo presenta un estudio de muestras crecidas direccionalmente del sistema Al2O3-ZrO2 (3 mol% Y2O3 en su composición eutéctica con pequeñas adiciones de óxido de titanio (1% de TiO2 en peso. Se analizan los cambios microestructurales inducidos por esta adición mediante SEM (EDX y se estudian los cambios en su comportamiento mecánico medido por flexión en tres puntos, así como la tenacidad de fractura mediante indentación Vickers. Con velocidades lentas de solidificación (10 mm/h se obtiene en ambos casos una microestructura homogénea e interpenetrada, mientras que a velocidades mayores, 300 y 1000 mm/h, se forma una estructura en las que las fases se organizan en forma de colonias o células, siendo éstas de menor tamaño en las muestras dopadas. Esta disminución en el tamaño viene acompañada de un aumento de la tenacidad de fractura medida por indentación.

40 CFR 721.8145 - Propane,1,1,1,2,2,3,3-heptafluoro-3-methoxy-.

Science.gov (United States)

2010-07-01

... 40 Protection of Environment 30 2010-07-01 2010-07-01 false Propane,1,1,1,2,2,3,3-heptafluoro-3-methoxy-. 721.8145 Section 721.8145 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED... significant new uses are: (i) Industrial, commercial, and consumer activities. Requirements as specified § 721...

Dentritic Carbosilanes Containing Silicon-Bonded 1-[C6H2(CH2NMe2)2-3,5-Li-4] or 1-[C6H3(CH2NMe2)-4-Li-3] Mono-and Bis(amino)aryllithium End Groups: Structure of {[CH2SiMe2C6H3(CH2NMe2)-4-Li-3]2}2

NARCIS (Netherlands)

Koten, G. van; Kleij, A.W.; Kleijn, H.; Jastrzebski, J.T.B.H.; Smeets, W.J.J.; Spek, A.L.

1999-01-01

A useful synthetic procedure for the incorporation of the potentially multidentate monoanionic 1-[C6H2(CH2NMe2)2-3,5]- (=NCN) and 1-[C6H3(CH2NMe2)-4]- (=CN) ligands via the para-position on the periphery of carbosilane (CS) dendrimers has been developed. Lithiation of suitable brominated precursors

Syntheses, structures, and properties of Ag4(Mo2O5)(SeO4)2(SeO3) and Ag2(MoO3)3SeO3

International Nuclear Information System (INIS)

Ling Jie; Albrecht-Schmitt, Thomas E.

2007-01-01

Ag 4 (Mo 2 O 5 )(SeO 4 ) 2 (SeO 3 ) has been synthesized by reacting AgNO 3 , MoO 3 , and selenic acid under mild hydrothermal conditions. The structure of this compound consists of cis-MoO 2 2+ molybdenyl units that are bridged to neighboring molybdenyl moieties by selenate anions and by a bridging oxo anion. These dimeric units are joined by selenite anions to yield zigzag one-dimensional chains that extended down the c-axis. Individual chains are polar with the C 2 distortion of the Mo(VI) octahedra aligning on one side of each chain. However, the overall structure is centrosymmetric because neighboring chains have opposite alignment of the C 2 distortion. Upon heating Ag 4 (Mo 2 O 5 )(SeO 4 ) 2 (SeO 3 ) looses SeO 2 in two distinct steps to yield Ag 2 MoO 4 . Crystallographic data: (193 K; MoKα, λ=0.71073 A): orthorhombic, space group Pbcm, a=5.6557(3), b=15.8904(7), c=15.7938(7) A, V=1419.41(12), Z=4, R(F)=2.72% for 121 parameters with 1829 reflections with I>2σ(I). Ag 2 (MoO 3 ) 3 SeO 3 was synthesized by reacting AgNO 3 with MoO 3 , SeO 2 , and HF under hydrothermal conditions. The structure of Ag 2 (MoO 3 ) 3 SeO 3 consists of three crystallographically unique Mo(VI) centers that are in 2+2+2 coordination environments with two long, two intermediate, and two short bonds. These MoO 6 units are connected to form a molybdenyl ribbon that extends along the c-axis. These ribbons are further connected together through tridentate selenite anions to form two-dimensional layers in the [bc] plane. Crystallographic data: (193 K; MoKα, λ=0.71073 A): monoclinic, space group P2 1 /n, a=7.7034(5), b=11.1485(8), c=12.7500(9) A, β=105.018(1) V=1002.7(2), Z=4, R(F)=3.45% for 164 parameters with 2454 reflections with I>2σ(I). Ag 2 (MoO 3 ) 3 SeO 3 decomposes to Ag 2 Mo 3 O 10 on heating above 550 deg. C. - Graphical abstract: A view of the one-dimensional [(Mo 2 O 5 )(SeO 4 ) 2 (SeO 3 )] 4- chains that extend down the c-axis in the structure of Ag 4 (Mo 2 O 5 )(SeO 4

Reactions of R(2)P-P(SiMe(3))Li with [(R'(3)P)(2)PtCl(2)]. A general and efficient entry to phosphanylphosphinidene complexes of platinum. Syntheses and structures of [(eta(2)-P=(i)Pr(2))Pt(p-Tol(3)P)(2)], [(eta(2)-P=(t)Bu(2))Pt(p-Tol(3)P)(2)], [{eta(2)-P=(N(i)Pr(2))(2)}Pt(p-Tol(3)P)(2)] and [{(Et(2)PhP)(2)Pt}(2)P(2)].

Science.gov (United States)

Domańska-Babul, Wioleta; Chojnacki, Jaroslaw; Matern, Eberhard; Pikies, Jerzy

2009-01-07

The reactions of lithium derivatives of diphosphanes R(2)P-P(SiMe(3))Li (R = (t)Bu, (i)Pr, Et(2)N and (i)Pr(2)N) with [(R'(3)P)(2)PtCl(2)] (R'(3)P = Et(3)P, Et(2)PhP, EtPh(2)P and p-Tol(3)P) proceed in a facile manner to afford side-on bonded phosphanylphosphinidene complexes of platinum [(eta(2)-P=R(2))Pt(PR'(3))(2)]. The related reactions of Ph(2)P-P(SiMe(3))Li with [(R'(3)P)(2)PtCl(2)] did not yield [(eta(2)-P=PPh(2))Pt(PR'(3))(2)] and resulted mainly in the formation of [{(R'(3)P)(2)Pt}(2)P(2)], Ph(2)P-PLi-PPh(2), (Me(3)Si)(2)PLi and (Me(3)Si)(3)P. Crystallographic data are reported for the compounds [(eta(2)-P=R(2))Pt(p-Tol(3)P)(2)] (R = (t)Bu, (i)Pr, ((i)Pr(2)N)(2)P) and for [{(Et(2)PhP)(2)Pt}(2)P(2)].

Emission analysis of RE3+ (RE = Sm, Dy):B2O3-TeO2-Li2O-AlF3 glasses.

Science.gov (United States)

Raju, C Nageswara; Sailaja, S; Kumari, S Pavan; Dhoble, S J; Kumar, V Ramesh; Ramanaiah, M V; Reddy, B Sudhakar

2013-01-01

This article reports on the optical properties of 0.5% mol of Sm(3+), Dy(3+) ion-doped B2O3-TeO2-Li2O-AlF3 (LiAlFBT) glasses. The glass samples were characterized by optical absorption and emission spectra. Judd-Ofelt theory was applied to analyze the optical absorption spectra and calculate the intensity parameters and radiative properties of the emission transitions. The emission spectra of Sm(3+) and Dy(3+):LiAlFBT glasses showed a bright reddish-orange emission at 598 nm ((4)G5/2 → (6)H7/2) and an intense yellow emission at 574 nm ((4)F9/2 → (6)H13/2), respectively. Full width at half maximum (FWHM), stimulated emission cross section, gain bandwidth and optical gain values were also calculated to extend the applications of the Sm(3+) and Dy(3+):LiAlFBT glasses. Copyright © 2012 John Wiley & Sons, Ltd.

Investigation of radiation shielding properties for MeO-PbCl2-TeO2 (MeO = Bi2O3, MoO3, Sb2O3, WO3, ZnO) glasses

Science.gov (United States)

Sayyed, M. I.; Çelikbilek Ersundu, M.; Ersundu, A. E.; Lakshminarayana, G.; Kostka, P.

2018-03-01

In this work, glasses in the MeO-PbCl2-TeO2 (MeO = Bi2O3, MoO3, Sb2O3, WO3, ZnO) system, which show a great potential for optoelectronic applications, were used to evaluate their resistance under high energy ionizing radiations. The basic shielding quantities for determining the penetration of radiation in glass, such as mass attenuation coefficient (μ/ρ), half value layer (HVL), mean free path (MFP) and exposure buildup factor (EBF) values were investigated within the energy range 0.015 MeV ‒ 15 MeV using XCOM program and variation of shielding parameters were compared with different glass systems and ordinary concrete. From the derived results, it was determined that MeO-PbCl2-TeO2 (MeO = Bi2O3, MoO3, Sb2O3, WO3, ZnO) glasses show great potentiality to be used under high energy radiations. Among the studied glass compositions, Bi2O3 and WO3 containing glasses were found to possess superior gamma-ray shielding effectiveness.

Thermal expansion of Cr2xFe2-2xMo3O12, Al2xFe2-2xMo3O12 and Al2xCr2-2xMo3O12 solid solutions

International Nuclear Information System (INIS)

Ari, M.; Jardim, P.M.; Marinkovic, B.A.; Rizzo, F.; Ferreira, F.F.

2008-01-01

The transition temperature from monoclinic to orthorhombic and the thermal expansion of the orthorhombic phase were investigated for three systems of the family A 2 M 3 O 12 : Cr 2x Fe 2-2x Mo 3 O 12 , Al 2x Fe 2-2x Mo 3 O 12 and Al 2x Cr 2-2x Mo 3 O 12 . It was possible to obtain a single-phase solid solution in all studied samples (x=0, 0.1, 0.3, 0.5, 0.7, 0.9 and 1). A linear relationship between the transition temperature and the fraction of A 3+ cations (x) was observed for each system. In all orthorhombic solid solutions studied here the observed thermal expansion was anisotropic. These anisotropic thermal expansion properties of crystallographic axes a, b and c result in a low positive or near-zero overall linear coefficient of thermal expansion (α l =α V /3). The relationship between the size of A 3+ cations in A 2 M 3 O 12 and the coefficient of thermal expansion is discussed. Near-zero thermal expansion of Cr 2 Mo 3 O 12 is explained by the behavior of Cr-O and Mo-O bond distances, Cr-Mo non-bond distances and Cr-O-Mo bond angles with increasing temperature, estimated by Rietveld analysis of synchrotron X-ray powder diffraction data. - Graphical abstract: In this figure, all published overall linear coefficients of thermal expansion for orthorhombic A 2 M 3 O 12 family obtained through diffraction methods as a function of A 3+ cation radii size, together with dilatometric results, are plotted. Our results indicate that Cr 2 Mo 3 O 12 does not exactly follow the established relationship

Hydrothermal syntheses and characterization of two layered molybdenum selenites, Rb2(MoO3)3SeO3 and Tl2(MoO3)3SeO3

International Nuclear Information System (INIS)

Dussack, L.L.; Harrison, W.T.A.; Jacobson, A.J.

1996-01-01

The hydrothermal syntheses of Rb 2 (MoO 3 ) 3 SeO 3 , and Tl 2 (MoO 3 ) 3 SeO 3 are described. These compounds have structures built up from hexagonal-WO 3 -type sheets and are isostructural with the previously reported Cs 2 (MoO 3 ) 3 SeO 3 and (NH 4 ) 2 (MoO 3 ) 3 SeO 3 . Powder X-ray, thermogravimetric, and spectroscopic data are presented and discussed

National Guard Posture Statement 2010. America’s Indispensable Force

Science.gov (United States)

2010-01-01

remote-controlled camera to watch for illegal border crossers, smugglers, and other suspicious activity during Operation Jump Start. Did you Know... Neubauer , CA SPC Joshua M. Neusche, MO SGT Long N. Nguyen, OR SPC Paul A. Nicholas, CA SFC Scott E. Nisely, IA SGT William J. Normandy, VT PFC Francis C

2nd February 2011 - EPFL Vice President, Academic Affairs, P. Gillet signing the guest book with Director-General R. Heuer.

CERN Multimedia

Jean-Claude Gadmer

2011-01-01

On photograph 16: form left to right: Nicolas Guérin, Willy Zwaenepoel, Bastien Confino, Frédérick Bordry (CERN), Philippe Gillet, Benoît Deveaud-Plédran, Dominique Bonvin, Gérard Escher, Jacques Giovanola, Tatsuya Nakada, Stéphane Decoutère, Ambrogio Fasoli, Demetri Psaltis, Olivier Schneider, Aurelio Bay and Leonid Rivkin.

Phase relations in the SiC-Al2O3-Pr2O3 system

International Nuclear Information System (INIS)

Pan, W.; Wu, L.; Jiang, Y.; Huang, Z.

2016-01-01

Phase relations in the Si-Al-Pr-O-C system, including the SiC-Al 2 O 3 -Pr 2 O 3 , the Al 2 O 3 -Pr 2 O 3 -SiO 2 and the SiC-Al 2 O 3 -Pr 2 O 3 -SiO 2 subsystems, were determined by means of XRD phase analysis of solid-state-reacted samples fabricated by using SiC, Al 2 O 3 , Pr 2 O 3 and SiO 2 powders as the starting materials. Subsolidus phase diagrams of the systems were presented. Two Pr-aluminates, namely PrAlO 3 (PrAP) and PrAl 11 O 18 (β(Pr) β-Al 2 O 3 type) were formed in the SiC-Al 2 O 3 -Pr 2 O 3 system. SiC was compatible with both of them. Pr-silicates of Pr 2 SiO 5 , Pr 2 Si 2 O 7 and Pr 9.33 Si 6 O 26 (H(Pr) apatite type) were formed owing to presence of SiO 2 impurity in the SiC powder. The presence of the SiO 2 extended the ternary system of SiC-Al 2 O 3 -Pr 2 O 3 into a quaternary system of SiC-Al 2 O 3 -SiO 2 -Pr 2 O 3 (Si-Al-Pr-O-C). SiC was compatible with Al 2 O 3 , Pr 2 O 3 and the Pr-silicates. The effect of SiO 2 on the phase relations and liquid phase sintering of SiC ceramics was discussed.

Copper diffusion in In2S3 and charge separation at In2S3/CuSCN and TiO2/In2S3 interfaces

International Nuclear Information System (INIS)

Juma, Albert Owino

2013-01-01

The concept of inorganic nanostructured solar cells consists of a very thin absorber layer sandwiched between highly structured electron and hole conductors. When a TiO 2 /In 2 S 3 /CuSCN nanocomposite heterostructure is illuminated with light, photo-generated electrons in In 2 S 3 can be injected into the conduction band of TiO 2 and holes into the valence band of CuSCN. Charge transfer at the interfaces is limited by the deposition parameters, band alignment and diffusion of Cu from CuSCN into In 2 S 3 , which was the focus of this work. TiO 2 nanoparticles were screen printed onto SnO 2 :F (FTO)-coated glass substrates to give a layer of nanoporous (np) TiO 2 . In 2 S 3 layers were deposited by thermal evaporation or ion layer gas reaction (ILGAR) methods producing Cl-free (In(acac) 3 precursor) and Cl-containing (InCl 3 precursor) layers. A spray-spin method was developed for deposition of CuSCN onto In 2 S 3 . Diffusion of Cu into In 2 S 3 layers was investigated by Rutherford backscattering spectrometry (RBS) while charge transport mechanisms were studied with surface photovoltage (SPV) technique in the fixed capacitor configuration. The activation energy (Ea) for Cu diffusion in thermally evaporated and Cl-free ILGAR In 2 S 3 layers was 0.30 and 0.24 eV, respectively but increased to between 0.72 and 0.78 eV for Cl-containing In 2 S 3 with residual Cl concentrations of 7.8 - 13.8 at.%. The diffusion prefactor (D 0 ) was six orders of magnitude higher for Cl-containing compared to Cl-free layers. The relationship between E a and D 0 was described by the Meyer-Neldel rule with a Meyer-Neldel energy of 40 meV. The presence of Cl has no significant influence on the structural properties of In 2 S 3 but resulted in a modified diffusion mechanism for Cu diffusion. The photovoltage of In 2 S 3 /CuSCN samples decreased after annealing for longer than 2 min at 200 C. A defect band was formed near the interface where holes accumulated and electrons tunneled through

Broadband ˜2μm emission in Tm3+/Ho3+ co-doped TeO2-WO3-La2O3 glass

Science.gov (United States)

Li, Kefeng; Wang, Guonian; Zhang, Junjie; Hu, Lili

2010-10-01

In this work, we report the infrared emission properties of Tm 3+/Ho 3+ co-doped TeO 2-WO 3-La 2O 3 (TWL) glass under 808 nm laser excitation. A broad and flat emission from 1600 to 2200 nm corresponding to the Tm 3+ ( 3F 4→ 3H 6) and Ho 3+ ( 5I 7→ 5I 8) emissions is observed. The full width at half maximum (FWHM) of this broadband increases up to a value of ˜370 nm with an optimal [Tm 3+]/[Ho 3+] concentration ratio. The energy transfer processes of Tm 3+↔Ho 3+ are analyzed and the results show that energy transfer between Tm 3+ and Ho 3+ plays an important role in the luminescence mechanism. The OH - influence on the broadband emission is also discussed. These results indicate that Tm 3+-Ho 3+ co-doped TWL glass could be a promising material for widely tunable laser or broadband amplifier applications.

Optical transitions of Er3+/Yb3+ codoped TeO2-WO3-Bi2O3 glass.

Science.gov (United States)

Shen, Xiang; Nie, Qiuhua; Xu, Tiefeng; Gao, Yuan

2005-10-01

Optical absorption and emission properties of the Er3+/Yb3+ codoped TeO2-WO3-Bi2O3 (TWB) glass has been investigated. The transition probabilities, excited state lifetimes, and the branching ratios have been predicted for Er3+ based on the Judd-Ofelt theory. The broad 1.5 microm fluorescence was observed under 970 nm excitation, and its full width at half maximum (FWHM) is 77 nm. The emission cross-section is calculated using the McCumber theory, and the peak emission cross-section is 1.03 x 10(-21) cm2 at 1.531 microm. This value is much larger than those of the silicate and phosphate glasses. Efficient green and weak red upconversion luminescence from Er3+ centers in the glass sample was observed at room temperature, and the upconversion excitation processes have been analyzed.

Novel 2D or 3D alkaline-earth metal sulfonate-phosphonates based on [O 3S-C 2H 4-PO 3H] 2- ligand

Science.gov (United States)

Du, Zi-Yi; Wen, He-Rui; Xie, Yong-Rong

2008-11-01

Three novel alkaline-earth metal sulfonate-phosphonates based on [O 3S-C 2H 4-PO 3H] 2- ligand, namely, [Ca(O 3SC 2H 4PO 3H)(H 2O) 2] ( 1), [Sr(O 3SC 2H 4PO 3H)] ( 2) and [Ba 2(O 3SC 2H 4PO 3H) 2] ( 3), have been synthesized by hydrothermal reactions. They represent the first structurally characterized alkaline-earth metal complexes of phosphonic acid attached with a sulfonate group. The structure of compound 1 features a 2D layer based on 1D chains of [Ca 2(PO 3) 2] bridged by -CH 2-CH 2-SO 3- groups. Compounds 2 and 3 show pillar-layer architecture based on two different inorganic layers linked by -CH 2-CH 2- groups. The inorganic layer in compound 2 features a 1D chain of edge-sharing SrO 8 polyhedra whereas that in compound 3 features an edge-sharing Ba 2O 14 di-polyhedral unit which is further corner-shared with four neighboring ones. The [O 3S-C 2H 4-PO 3H] 2- ligand shows diverse coordination modes in the three alkaline-earth metal sulfonate-phosphonates.

Synthesis and crystal structure of hydrogen phosphites RbH2PO3, CsH2PO3, and TlH2PO3

International Nuclear Information System (INIS)

Kosterina, E.V.; Troyanov, S.I.; Kemnits, Eh.; Aslanov, L.A.

2001-01-01

The crystal acid phosphites RbH 2 PO 3 , CsH 2 PO 3 and TlH 2 PO 3 were separated during reaction of Rb, Cs and Tl carbonates with phosphorous acid solution. The crystal structure of the compounds was analyzed by X-ray diffraction method at 150 K. CsH 2 PO 3 has a monoclinic system, a = 7.930(2), b = 8.929(2), c = 13.163(3) A, β = 104.84(3) Deg, V = 900.9(4) A 3 , Z 8, sp. gr. P2 1 /c, R 1 = 0.239. In the structure hydrogen bonds integrate the PHO 3 tetrahedrons in the unlimited zigzag chains [HPHO 3 ] n n- laying at the layers, which are alternate to the layers of metal cations. The layers of anion chains have a wavy form [ru

Performance comparison of 2-1-3, 1-3 and 1-3-2 piezoelectric composite transducers by finite element method

Directory of Open Access Journals (Sweden)

Y. Sun

2018-03-01

Full Text Available 1-3 type, 1-3-2 type and 2-1-3 type piezoelectric composites are three proper smart materials for the design and manufacture of ultrasonic transducers. They have been proposed in different stages but possess similar properties. Compared with the initial 1-3 type composite, 1-3-2 composite is of higher mechanical stability. Compared with 1-3-2 composite, 2-1-3 composite has lower manufacturing difficulty. In this paper, a comparative study on these three composites in terms of receiving transducer material properties is presented. Finite element method (FEM has been adopted to calculate longitudinal velocity, thickness electromechanical coupling coefficient and voltage receiving sensitivity. It is concluded that for a large aspect ratio α=1, the performance of 2-1-3 composite transducer is much better than that of 1-3 and 1-3-2 composite transducers. The thickness electromechanical coupling coefficient of 2-1-3 composite transducer is about 5.58 times that of 1-3 composite transducer and 7.42 times that of 1-3-2 composite transducer. The voltage receiving sensitivity at 2 kHz of 2-1-3 composite transducer is 13.1 dB higher than that of 1-3-2 composite transducer and 12.3 dB higher than that of 1-3 composite transducer.

Crystal structure and magnetic properties of the Ba3TeCo3P2O14, Pb3TeCo3P2O14, and Pb3TeCo3V2O14 langasites

DEFF Research Database (Denmark)

Krizan, J.W.; de la Cruz, C.; Andersen, Niels Hessel

2013-01-01

We report the structural and magnetic characterizations of Ba3TeCo3P2O14, Pb3TeCo3P2O14, and Pb3TeCo3V2O14, compounds that are based on the mineral dugganite, which is isostructural to langasites. The magnetic part of the structure consists of layers of Co2+ triangles. Nuclear and magnetic...... structures were determined through a co-refinement of synchrotron and neutron powder diffraction data. In contrast to the undistorted P321 langasite structure of Ba3TeCo3P2O14, a complex structural distortion yielding a large supercell is found for both Pb3TeCo3P2O14 and Pb3TeCo3V2O14. Comparison...... of the three compounds studied along with the zinc analog Pb3TeZn3P2O14, also characterized here, suggests that the distortion is driven by Pb2+ lone pairs; as such, the Pb compounds crystallize in a pyroelectric space group, P2. Magnetic susceptibility, magnetization, and heat capacity measurements were...

X-ray structural study of Nd[N(CN)2]3x2OP(NMe2)3

International Nuclear Information System (INIS)

Kapshuk, A.A.; Skopenko, V.V.

1985-01-01

The results of X-ray structure study of Nd(N(CN) 2 ) 3 x2OP(NMe) 2 ) 3 are presented. The crystals are monoclinic: a=12,787(6), b=17.731(9), c=15.302(5) A, γ=114.84(3) deg, Z=4, sp.gr. p2 1 /n. The structure is formed of infinite corrugated netting consisting of neodymium atoms, coordinating two OP(NMe 2 ) 3 molecules, and three bidentate-bridge dicyanamide groups. Neodymium coordination number is 8, coordination polyhedron is a distorted twocapped trigonal prism. Certain aspects of crystal chemistry of dicyanamide complexes are discussed

Synthesis of pyrano[2,3-c]carbazoles, pyrano[3,2-b]carbazoles and ...

Indian Academy of Sciences (India)

2,3-c]carbazoles, pyrano[3,2-b]carbazoles and furo[3,2-b]carbazole derivatives via iodocyclization. KRISHNA CHAITANYA TALLURI and RAJAGOPAL NAGARAJAN. ∗. School of Chemistry, University of Hyderabad, Hyderabad 500046, India.

Theory of the 4d → 2p X-ray emission spectroscopy in Ce2O3, Pr2O3 and Dy2O3

International Nuclear Information System (INIS)

Tanaka, Satoshi; Ogasawara, Haruhiko; Okada, Kozo; Kotani, Akio.

1995-01-01

The 4d → 2p X-ray emission spectra (XES) of Ce 2 O 3 , Pr 2 O 3 and Dy 2 O 3 have been calculated with an impurity Anderson model with the full multiplet couplings, following the Kramers-Heisenberg formula in the second order optical process. Experimental results have been well reproduced with this model by using a constant value for the 4d core hole lifetime damping Γ(4d) in the case of Ce 2 O 3 and Pr 2 O 3 , while in the case of Dy 2 O 3 it is necessary to take into account the term dependence of Γ(4d), which is consistent with the previous theoretical analyses of 4d X-ray photoemission spectra. It was also shown that both the spin-orbit couplings of the 4d core level in the final state and the 4f level in the initial state are key factors to cause the branching ratio in the L γ line larger than that in the L β line. The phase matching of the wave functions between the intermediate and final states smears out the hybridization effect in the 4d → 2p XES in Ce 2 O 3 and Pr 2 O 3 . (author)

Vacuum ultraviolet excited photoluminescence properties of Gd2O2CO3:Eu3+ phosphor

Institute of Scientific and Technical Information of China (English)

WANG Zhilong; WANG Yuhua; ZHANG Jiachi

2008-01-01

The Gd2O2CO3:Eu3+ with type-II structure phosphor was successfully synthesized via flux method at 400℃ and their photoluminescence properties in vacuum ultraviolet (VUV) region were examined. The broad and strong excitation bands in the range of 153-205 nm owing to the CO32- host absorption and charge transfer (CT) of Gd3+-O2- were observed for Gd2O2CO3:Eu3+. Under 172 nm excitation, Gd2O2CO3:Eu3+ exhibited strong red emission with good color purity, indicating Eu3+ ions located at low symmetry sites and the chromaticity coordination of luminescence for Gd2O2CO3:Eu3+ was (x=0.652, y=0.345). The photoluminescence quenching concentration of Eu3+ excited by 172 nm for Gd2O2CO3:Eu3+ was about 5%. Gd2O2CO3:Eu3+ would be a potential VUV-excited red phosphor applied in mercury-free fluorescent lamps.

Phase equilibria in the system Li2O - MoO3 - Sc2O3

International Nuclear Information System (INIS)

Safonov, V.V.; Chaban, N.G.; Porotnikov, N.V.

1984-01-01

Using the methods of DTA and X-ray phase analysis, interaction of components in the system Li 2 O-MoO 3 -Sc 2 O 3 in concentration range, adjacent to the vertex of MoO 3 , has been studied. Projection of the Li 2 MoO 4 -MoO 3 -Sc 2 (MoO 4 ) 3 system liquidus on concentrational triangle of the compositions Li 2 O-MoO 3 -Sc 2 O 3 , which consists of the fields of primary separation of Li 2 MoO 4 , Li 2 Mo 5 O 17 , Li 2 Mo 4 O 13 , MoO 3 , Sc 2 (MoO 4 ) 3 , Li 3 Sc(MoO 4 ) 3 and LiSc(MoO 4 ) 2 , is built

NMR Spectroscopic Characterization of Methylcobalt(III) Compounds with Classical Ligands. Crystal Structures of [Co(NH(3))(5)(CH(3))]S(2)O(6), trans-[Co(en)(2)(NH(3))(CH(3))]S(2)O(6) (en = 1,2-Ethanediamine), and [Co(NH(3))(6)]-mer,trans-[Co(NO(2))(3)(NH(

DEFF Research Database (Denmark)

Kofod, Pauli; Harris, Pernille; Larsen, Sine

1997-01-01

magnetic resonance spectroscopy and by absorption spectroscopy. Single-crystal X-ray structure determinations at 122.0(5) K were performed on [Co(NH(3))(5)(CH(3))]S(2)O(6) (1), trans-[Co(en)(2)(NH(3))(CH(3))]S(2)O(6) (2), and [Co(NH(3))(6)]-mer,trans-[Co(NO(2))(3)(NH(3))(2)(CH(3))](2)-trans-[Co(NO(2...

Color-tunable and highly thermal stable Sr_2MgAl_2_2O_3_6:Tb"3"+ phosphors

International Nuclear Information System (INIS)

Zhang, Haiming; Zhang, Haoran; Liu, Yingliang; Lei, Bingfu; Deng, Jiankun; Liu, Wei-Ren; Zeng, Yuan; Zheng, Lingling; Zhao, Minyi

2017-01-01

Tb"3"+ activated Sr_2MgAl_2_2O_3_6 phosphor was prepared by a high-temperature solid-state reaction route. The X-ray diffraction, scanning electron microscopy, and photoluminescence spectroscopy were used to characterize the as-prepared samples. The Sr_2MgAl_2_2O_3_6:Tb"3"+ phosphors show intense green light emission under UV excitation. The phosphor exhibit two groups of emission lines from about 370 to 700 nm, which originating from the characteristic "5D_3-"7F_J and "5D_4-"7F_J transitions of the Tb"3"+ ion, respectively. The cross-relaxation mechanism between the "5D_3 and "5D_4 emission was investigated and discussed. The emission colors of these phosphors can be tuned from bluish-green to green by adjusting the Tb"3"+ doping concentration. Furthermore, the thermal quenching temperature (T_1_/_2) is higher than 500 K. The excellent thermal stability and color-tunable luminescent properties suggest that the developed material is a promising green-emitting phosphor candidate for optical devices. - Highlights: • A Color-tunable emitting phosphor Sr_2MgAl_2_2O_3_6:Tb"3"+ was prepared successfully via high-temperature solid-state reaction. • The photoluminescence of Sr_2MgAl_2_2O_3_6:Tb"3"+ shows highly thermal stable. • The cross-relaxation mechanism between the "5D_3 and "5D_4 emission was investigated and discussed.

Development of a Novel Translational Model of Vibration Injury to the Spine to Study Acute Injury

Science.gov (United States)

2013-10-01

to Dr. Nicolas Jaumard for input on device fabrica- tion and mechanical analyses. REFERENCES 1. Boshuizen HC, Bongers PM, Hulshof CT. 1992. Self...reported back pain in fork-lift truck and freight-container tractor drivers exposed to whole-body vibration. Spine 17:59–65. 2. Bovenzi M, Hulshof CTJ. 1988...Occup Environ Health 72:351–365. 3. Boshuizen HC, Bongers PM, Hulshof CT. 1999. Effect of whole body vibration on low back pain. Spine 24:2506–2515. 4

Poly[propane-1,3-diammonium [cuprate(II-bis(μ2-pyridine-2,3-dicarboxylato] trihydrate

Directory of Open Access Journals (Sweden)

Shabnam Hooshmand

2008-02-01

Full Text Available The title polymeric compound {(C3H12N2[Cu(C7H3NO42]·3H2O}n or {(pnH2[Cu(py-2,3-dc2]·3H2O}n (pn is propane-1,3-diamine and py-2,3-dcH2 is pyridine-2,3-dicarboxylic acid, was synthesized by reaction of copper(II chloride dihydrate with a proton-transfer compound, propane-1,3-diammonium pyridine-2,3-dicarboxylate or (pnH2(py-2,3-dc, in aqueous solution. The anion is a six-coordinate complex (site symmetry overline{1}, with a distorted octahedral geometry around CuII, consisting of two bidentate pyridine-2,3-dicarboxylate groups and two O atoms of bridging ligands from (py-2,3-dc2− fragments, which are located in trans positions. The (pnH22+ cation is disordered over two sites by the center of inversion. Intermolecular hydrogen bonds, π–π [centroid–centroid distances of 3.539 (3 Å] and C—O...π stacking interactions [O...Cg = 3.240 (5 Å; Cg is the center of the pyridine ring], connect the various components into a supramolecular structure.

N-{4-[(2E-3-(2H-1,3-Benzodioxol-5-ylprop-2-enoyl]phenyl}quinoline-3-carboxamide

Directory of Open Access Journals (Sweden)

Efrain Polo

2017-10-01

Full Text Available An amide chalconehas been synthesized in a two-step reaction. First, N-(4-acetylphenylquinoline-3-carboxamide 2 was synthesized by the reaction of quinoline-3-carboxylic acid 1 and thionyl chloride (SOCl2, following the addition of 4-aminoacetophenone. Then, a typical Claisen–Schmidtreactionwas made between 2 and piperonal using KOH solution as a catalystin ethanol, under ultrasonic irradiation. The structure of the target compound was established by FTIR (Fourier-transform infrared spectroscopy, HRMS, 1H and 13C-NMR.

3-{2-[2-(2-Fluorobenzylidenehydrazinyl]-1,3-thiazol-4-yl}-2H-chromen-2-one

Directory of Open Access Journals (Sweden)

Afsheen Arshad

2010-06-01

Full Text Available In the title compound, C19H12FN3O2S, the chromene ring system and the thiazole ring are approximately planar [maximum deviations of 0.023 (3 Å and 0.004 (2 Å, respectively]. The chromene ring system is inclined at angles of 4.78 (10 and 26.51 (10° with respect to the thiazole and benzene rings, respectively, while the thiazole ring makes a dihedral angle of 23.07 (12° with the benzene ring. The molecular structure is stabilized by an intramolecular C—H...O hydrogen bond, which generates an S(6 ring motif. The crystal packing is consolidated by intermolecular N—H...O hydrogen bonds, which link the molecules into chains parallel to [100], and by C—H...π and π–π [centroid–centroid distance = 3.4954 (15 Å] stacking interactions.

Synthesis and Characterization of Mixed Chalcogen Triangular Complexes with New Mo-3(mu(3)-S)(mu(2)-Se-2)(3)(4+) and M-3(mu(3)-S)mu(2)-Se)(3)(4+) (M = Mo, W) Cluster Cores

DEFF Research Database (Denmark)

Gushchin, Artem; Ooi, Bee Lean; Harris, Pernille

2009-01-01

In our pursuit of mixed chalcogen-bridged cluster complexes, solids of the compositions Mo3SSe6Br4 and W3SSe6Br4 were prepared using high-temperature synthesis from the elements. Treatment of Mo3SSe6Br4 with Bu4NBr in a vibration mill yielded (Bu4N)(3)([Mo-3(mu(3)-S)(mu(2)-Se-2)(3)Br-6]Br} (I). Its......), was isolated and its structure determined using X-ray crystallography. W3SSe6Br4 upon reaction with H3PO2 gave a mixture of all of the [W3SxSe4-x(H2O)(9)](4+) species. After repeated chromatography, crystals of {[W-3(mu(3)-S)(mu(2)-Se)(3)(H2O)(7)Cl--(2)](2)CB[6]}Cl-4 center dot 12H(2)O (IV) were crystallized...

Olematu linn / Nicola Desiderio

Index Scriptorium Estoniae

Desiderio, Nicola

2006-01-01

10. Veneetsia arhitektuuribiennaalist (kuraator Richard Burdett). Näitusest "Linn, arhitektuur ja ühiskond". Itaalia paviljoni väljapanekust "Uus linn. Itaalia 2026. Kutse Vemasse" (kuraator Franco Purini), lühidalt Belgia väljapanekust ja Saksa paviljoni ekspositsioonist "Muundatav linn"

Synthesis and properties of γ-Ga2O3-Al2O3 solid solutions

Science.gov (United States)

Afonasenko, T. N.; Leont'eva, N. N.; Talzi, V. P.; Smirnova, N. S.; Savel'eva, G. G.; Shilova, A. V.; Tsyrul'nikov, P. G.

2017-10-01

The textural and structural properties of mixed oxides Ga2O3-Al2O3, obtained via impregnating γ-Al2O3 with a solution of Ga(NO3)3 and subsequent heat treatment, are studied. According to the results from X-ray powder diffraction, gallium ions are incorporated into the structure of aluminum oxide to form a solid solution of spinel-type γ-Ga2O3-Al2O3 up to a Ga2O3 content of 50 wt % of the total weight of the sample, accompanied by a reduction in the specific surface area, volume, and average pore diameter. It is concluded that when the Ga2O3 content exceeds 50 wt %, the β-Ga2O3 phase is observed along with γ-Ga2O3-Al2O3 solid solution. 71Ga and 27Al NMR spectroscopy shows that gallium replaces aluminum atoms from the tetrahedral position to the octahedral coordination in the structure of γ-Ga2O3-Al2O3.

Quantification of "2"3"2Th, "2"3"4U, "2"3"5U and "2"3"8U in river mollusks by magnetic sector mass spectrometry with inductively coupled plasma source (Icp-SFMS)

International Nuclear Information System (INIS)

Arevalo R, D. L.; Hernandez M, H.; Romero G, E. T.; Lara A, N.; Alfaro de la T, M. C.

2016-09-01

The present work deals with the methodology established for the quantification of "2"3"2Th, "2"3"4U, "2"3"8U and "2"3"5U in the shell of gastropod mollusks collected in the rivers Valles, Coy and Axtla of San Luis Potosi, Mexico, which belong to the Panuco River basin; these rivers have as main source of pollution the discharge of municipal sewage, waste from small industries, agricultural and cattle residues and from natural sources. Conventional methods for measuring radio-nuclides are confronted with certain conditions related to the requirement in measurement, basically in the characterization that is related to the concepts of precision and accuracy. The analysis of the gastropod mollusk shell was performed by the Icp-SFMS technique; the main advantages of this technique lie in the isotope quantification capacity, the high precision and the low limits of detection, in this study are very important because these elements are in concentrations between ppb and ppt. This technique allowed the analysis of the samples having a complex matrix by the presence CaCO_3 minimizing the interferences thanks to the ionization efficiency of the Ar plasma. For the species Pachychilus monachus were found concentrations of "2"3"2Th of 0.16-5.37 μg/g and of total U of 0.101-4.081 μg/g being this species where the highest values of total U were found. For Thiara (melanoids) tuberculata the lowest values were found among the different species ("2"3"2Th 0.61-3.61 μg/g and total U 0.006-0.042 μg/g), for Pachychilus suturalis, values of "2"3"2Th of 0.58-6.4 μg/g and for Pachychilus sp. were found between 0.26-7.62 μg/g and for total U values between 0.28-3.33 μg/g. The method offers several advantages: speed, good precision, low values of quantification limits and high sensitivity in the measurement of radio-nuclides and heavy metals. (Author)

2-[3-Furyl(hydroxy)methyl]-2,3-dimethylcyclohexanone.

Science.gov (United States)

García, Esther; Mendoza, Virgilio; Guzmán, José Agustín; Maldonado Graniel, Luis Angel; Hernández-Ortega, Simón

2002-06-01

Contribution No. 1750 of the Instituto de Quimica, UNAM, Mexico. In the molecule of the title compound, C(13)H(18)O(3), there is a syn relationship between the two vicinal methyl groups. The six-membered ring adopts a chair conformation, with one equatorial and two axial groups, and the furyl group is almost parallel to the ketone group. Intermolecular hydrogen bonds [O[bond]H...O[double bond]C 2.814 (3) A] form chains along [100].

Heterospin systems constructed from [Cu2Ln]3+ and [Ni(mnt)2]1-,2- Tectons: First 3p-3d-4f complexes (mnt = maleonitriledithiolato).

Science.gov (United States)

Madalan, Augustin M; Avarvari, Narcis; Fourmigué, Marc; Clérac, Rodolphe; Chibotaru, Liviu F; Clima, Sergiu; Andruh, Marius

2008-02-04

New heterospin complexes have been obtained by combining the binuclear complexes [{Cu(H(2)O)L(1)}Ln(O(2)NO)(3)] or [{CuL(2)}Ln(O(2)NO)(3)] (L(1) = N,N'-propylene-di(3-methoxysalicylideneiminato); L(2) = N,N'-ethylene-di(3-methoxysalicylideneiminato); Ln = Gd(3+), Sm(3+), Tb(3+)), with the mononuclear [CuL(1)(2)] and the nickel dithiolene complexes [Ni(mnt)(2)](q)- (q = 1, 2; mnt = maleonitriledithiolate), as follows: (1)infinity[{CuL(1)}(2)Ln(O(2)NO){Ni(mnt)(2)}].Solv.CH(3)CN (Ln = Gd(3+), Solv = CH(3)OH (1), Ln = Sm(3+), Solv = CH(3)CN (2)) and [{(CH(3)OH)CuL(2)}(2)Sm(O(2)NO)][Ni(mnt)(2)] (3) with [Ni(mnt)2]2-, [{(CH(3)CN)CuL(1)}(2)Ln(H(2)O)][Ni(mnt)(2)]3.2CH(3)CN (Ln = Gd(3+) (4), Sm(3+) (5), Tb(3+) (6)), and [{(CH(3)OH)CuL(2)}{CuL(2)}Gd(O(2)NO){Ni(mnt)(2)}][Ni(mnt)(2)].CH(2)Cl(2) (7) with [Ni(mnt))(2]*-. Trinuclear, almost linear, [CuLnCu] motifs are found in all the compounds. In the isostructural 1 and 2, two trans cyano groups from a [Ni(mnt)2]2- unit bridge two trimetallic nodes through axial coordination to the Cu centers, thus leading to the establishment of infinite chains. 3 is an ionic compound, containing discrete [{(CH(3)OH)CuL(2)}(2)Sm(O(2)NO)](2+) cations and [Ni(mnt)(2)](2-) anions. Within the series 4-6, layers of discrete [CuLnCu](3+) motifs alternate with stacks of interacting [Ni(mnt)(2)](*-) radical anions, for which two overlap modes, providing two different types of stacks, can be disclosed. The strength of the intermolecular interactions between the open-shell species is estimated through extended Hückel calculations. In compound 7, [Ni(mnt)(2)](*-) radical anions coordinate group one of the Cu centers of a trinuclear [Cu(2)Gd] motif through a CN, while discrete [Ni(mnt)(2)](*-) units are also present, overlapping in between, but also with the coordinated ones. Furthermore, the [Cu(2)Gd] moieties dimerize each other upon linkage by two nitrato groups, both acting as chelate toward the gadolinium ion from one unit and monodentate toward a

Atmospheric Chemistry of CH3CH2OCH3

DEFF Research Database (Denmark)

Andersen, Mads Peter Sulbæk; Bjørn Svendsen, Sissel; Østerstrøm, Freja From

2017-01-01

The atmospheric chemistry of methyl ethyl ether, CH3CH2OCH3, was examined using FT-IR/relative-rate methods. Hydroxyl radical and chlorine atom rate coefficients of k(CH3CH2OCH3+OH) = (7.53 ± 2.86) × 10−12 cm3 molecule−1 s−1 and k(CH3CH2OCH3+Cl) = (2.35 ± 0.43) × 10−10 cm3 molecule−1 s−1 were...

(2E-3-(3,5-Dimethyl-1-phenyl-1H-pyrazol-4-yl-1-(2,5-dimethyl-3-thienylprop-2-en-1-one

Directory of Open Access Journals (Sweden)

Salman A. Khan

2010-04-01

Full Text Available The title compound, (2E-3-(3,5-dimethyl-1-phenyl-1H-pyrazol-4-yl-1-(2,5-dimethyl-3-thienylprop-2-en-1-one (3 was synthesized in high yield by aldol condensation of 3-acetyl-2,5-dimethylthiophene and 3,5-dimethyl-1-phenylpyrazole-4-carboxaldehyde in ethanolic NaOH at room temperature. Its structure was fully characterized by elemental analysis, IR, 1H NMR, 13C NMR and EI-MS spectral analysis.

Pankrotis riik ja valusad reformid kärbivad Sarkozy senist tähelendu / Triin Oppi, Karin Volmer

Index Scriptorium Estoniae

Oppi, Triin

2007-01-01

Ilmunud ka: Postimees : na russkom jazõke, 25. sept. 2007, lk. 7. Postimees : na russkom jazõke lüh. Prantsusmaa presidendi Nicolas Sarkozy plaanib riigi pankrotist väljatoomiseks mitmeid seadusemuudatusi ja uuendusi. Peaminister Francois Fillon tunnistas eelarvepuudujääki. Lisa: Toetus. Väljavõtteid ajakirjale Time antud hinnangutest Nicolas Sarkozy valitsusajale: Philip H. Gordon, Marielle de Sarnez, Dominique Moisi

Directed laser processing of compacted powder mixtures Al2O3-TiO2-Y2O3

Directory of Open Access Journals (Sweden)

Vlasova M.

2013-01-01

Full Text Available The phase formation, microstructure and surface texture of laser treated ternary powder mixtures of Al2O3-TiO2-Y2O3 had been studied. Rapid high temperature heating and subsequent rapid cooling due to the directed movement of the laser beam forms concave ceramic tracks. Phase composition and microstructure of the tracks depends on the Al2O3 content and the TiO2/Y2O3 ratio of the initial mixtures. The main phases observed are Y3Al5O12, Y2Ti2O7, Al2O3 and Al2TiO5. Due to the temperature gradient in the heating zone, complex layered structures are formed. The tracks consist of three main layers: a thin surface layer, a layer of crystallization products of eutectic alloys, and a lower sintered layer. The thickness of the crystallization layer and the shrinkage of the irradiation zone depend on the amount of Y3Al5O12 and Al2O3 crystallized from the melt.

Effect of concentration variation on 2.0 µm emission of Ho3+-doped SiO2-Al2O3-Na2CO3-SrF2-CaF2 oxyfluorosilicate glasses

Science.gov (United States)

Gelija, Devarajulu; Borelli, Deva Prasad Raju

2018-02-01

The concentration variation of Ho3+ ion-doped SiO2-Al2O3-Na2CO3-SrF2-CaF2 glasses has been prepared by conventional melt quenching method. The thermal stability of 1 mol % of Ho3+-doped oxyfluorosilicate glass has been calculated using the differential thermal analysis (DTA) spectra. The phenomenological Judd-Ofelt intensity parameters Ωλ ( λ = 2, 4 and 6) were calculated for all concentrations of Ho3+ ions. The luminescence spectra in visible region of Ho3+ ion-doped glasses were recorded under the excitation wavelength of 452 nm. The spectra consists of several intense emission bands (5F4, 5S2) → 5I8 (547 nm), 5F3 → 5I8 (647 nm), 5F5 → 5I7 (660 nm) and (5F4, 5S2) → 5I7 (750 nm) in the range 500-780 nm. The fluorescence emission at ˜2.0 µm (5I7 → 5I8) was observed under the excitation of 488 nm Ar-ion laser. The stimulated emission cross section for 5I7 → 5I8 transition (˜2.0 µm) varies from 8.46 to 9.52 × 10-21 cm2, as calculated by the Fuchtbauer-Ladenburg (FL) theory. However, Mc-Cumber theory was used to calculate emission cross section values about 4.24-5.75 × 10-21 cm2 for the 5I7 → 5I8 transition in all concentrations of Ho3+-doped oxyfluorosilicate glasses. Therefore, these results reveal that the 0.5 mol % of Ho3+-doped oxyfluorosilicate glasses, exhibiting higher emission cross section, has potentially been used for laser applications at ˜ 2.0 µm.

Lanthanite-(Nd), Nd2(CO3)3·8H2O

Science.gov (United States)

Morrison, Shaunna M.; Andrade, Marcelo B.; Wenz, Michelle D.; Domanik, Kenneth J.; Downs, Robert T.

2013-01-01

Lanthanite-(Nd), ideally Nd2(CO3)3·8H2O [dineodymium(III) tricarbonate octa­hydrate], is a member of the lanthanite mineral group characterized by the general formula REE 2(CO3)3·8H2O, where REE is a 10-coordinated rare earth element. Based on single-crystal X-ray diffraction of a natural sample from Mitsukoshi, Hizen-cho, Karatsu City, Saga Prefecture, Japan, this study presents the first structure determination of lanthanite-(Nd). Its structure is very similar to that of other members of the lanthanite group. It is composed of infinite sheets made up of corner- and edge-sharing of two NdO10-polyhedra (both with site symmetry ..2) and two carbonate triangles (site symmetries ..2 and 1) parallel to the ab plane, and stacked perpendicular to c. These layers are linked to one another only through hydrogen bonding involving the water mol­ecules. PMID:23476479

Life Expectancies Applied to Specific Statuses: a History of the Indicators and the Methods of Calculation {Population, 3, 1998)

OpenAIRE

N. Brouard; J.-M. Robine; E. Cambois

1999-01-01

Cambois (Emmanuelle), Robin? (Jean-Marie), Brouard (Nicolas).- Life Expectancies Applied to Specific Statuses: A History of the Indicators and the Methods of Calculation Indicators of life expectancy applied to specific statuses, such as the state of health or professional status, were introduced at the end of the 1930s and are currently the object of renewed interest. Because they relate mortality to different domains (health, professional activity) applied life expectancies reflect simultan...

Gold(I) Complexes with N-Donor Ligands. 2.(1) Reactions of Ammonium Salts with [Au(acac-kappaC(2))(PR(3))] To Give [Au(NH(3))L](+), [(AuL)(2)(&mgr;(2)-NH(2))](+), [(AuL)(4)(&mgr;(4)-N)](+), or [(AuL)(3)(&mgr;(3)-O)](+). A New and Facile Synthesis of [Au(NH(3))(2)](+) Salts. Crystal Structure of [{AuP(C(6)H(4)OMe-4)(3)}(3)(&mgr;(3)-O)]CF(3)SO(3).

Science.gov (United States)

Vicente, José; Chicote, María-Teresa; Guerrero, Rita; Jones, Peter G.; Ramírez De Arellano, M. Carmen

1997-09-24

The complexes [Au(acac-kappaC(2))(PR(3))] (acac = acetylacetonate, R = Ph, C(6)H(4)OMe-4) react with (NH(4))ClO(4) to give amminegold(I), [Au(NH(3))(PR(3))]ClO(4), amidogold(I), [(AuPR(3))(2)(&mgr;(2)-NH(2))]ClO(4), or nitridogold(I), [(AuPR(3))(4)(&mgr;(4)-N)]ClO(4), complexes, depending on the reaction conditions. Similarly, [Au(acac-kappaC(2))(PPh(3))] reacts with (NH(3)R')OTf (OTf = CF(3)SO(3)) (1:1) or with [H(3)N(CH(2))(2)NH(2)]OTf (1:1) to give (amine)gold(I) complexes [Au(NH(2)R')(PPh(3))]OTf (R' = Me, C(6)H(4)NO(2)-4) or [(AuPPh(3))(2){&mgr;(2)-H(2)N(CH(2))(2)NH(2)}](OTf)(2), respectively. The ammonium salts (NH(2)R'(2))OTf (R' = Et, Ph) react with [Au(acac-kappaC(2))(PR(3))] (R = Ph, C(6)H(4)OMe-4) (1:2) to give, after hydrolysis, the oxonium salts [(AuPR(3))(3)(&mgr;(3)-O)]OTf (R = Ph, C(6)H(4)OMe-4). When NH(3) is bubbled through a solution of [AuCl(tht)] (tht = tetrahydrothiophene), the complex [Au(NH(3))(2)]Cl precipitates. Addition of [Au(NH(3))(2)]Cl to a solution of AgClO(4) or TlOTf leads to the isolation of [Au(NH(3))(2)]ClO(4) or [Au(NH(3))(2)]OTf, respectively. The crystal structure of [(AuPR(3))(3)(&mgr;(3)-O)]OTf.Me(2)CO (R = C(6)H(4)OMe-4) has been determined: triclinic, space group P&onemacr;, a = 14.884(3) Å, b = 15.828(3) Å, c = 16.061(3) Å, alpha = 83.39(3) degrees, beta = 86.28(3) degrees, gamma = 65.54(3) degrees, R1 (wR2) = 0.0370 (0.0788). The [(AuPR(3))(3)(&mgr;(3)-O)](+) cation shows an essentially trigonal pyramidal array of three gold atoms and one oxygen atom with O-Au-P bond angles of ca. 175 degrees and Au.Au contacts in the range 2.9585(7)-3.0505(14) Å. These cations are linked into centrosymmetric dimers through two short Au.Au [2.9585(7), 3.0919(9) Å] contacts. The gold atoms of the dimer form a six-membered ring with a chair conformation.

Synthesis of 14C-labelled polychlorobiphenyls derived from the labelled 4-chloro-, 2,5-dichloro-, 3,4-dichloro-, 2,3-dichloro-2,4,5-trichloro- and 2,3,6-trichloroanilines

International Nuclear Information System (INIS)

Bergman, A.; Bamford, I.; Wachtmeister, C.A.

1981-01-01

[ 14 C]Aniline hydrogen sulphate was acetylated, and the acetanilide obtained was chlorinated with N-chlorosuccinimide to 2-chloro, 4-chloro- and 2,4-dichloroacet[ 14 C]anilide. The labelled 2- and 4-chloroacet[ 14 C]anilides were hydrolyzed and treated with aluminium chloride, hydrogen chloride and chlorine in dry dichloromethane to give the major products 2,5-dichloro-and 3,4-dichloro[ 14 C]aniline. The labelled 2,3-dichloro- and 2,3,6-trichloroanilines were obtained as minor products from the chlorination of 2-chloro[ 14 C]aniline, likewise 2,4,5-trichloroaniline was obtained from 4-chloro[ 14 C]aniline. The [ 14 C]anilines prepared were coupled with benzene, 1,4-dichloro-, 1,2-dichloro- or 1,3-dichlorobenzene to give 4-chloro-, 2,3',4',5-tetrachloro-, 2,3,3',4'-tetrachloro-, 3,3',4,4'-tetrachloro-, 2,2',5,5'-tetrachloro-, 2,2',3,3'-tetrachloro-, 2,2',3,5',6-pentachloro-, 2,2',4,4',5-pentachloro- and 2,3',4,5,5'-pentachloro[ 14 C]biphenyl. 3,4-Dichloro[ 14 C]aniline and biphenyls prepared from this aniline were found to be contaminated by bromoanalogues. The origin of these have been studied. (author)

Solubility Modeling of the Binary Systems Fe(NO3)3–H2O, Co(NO3)2–H2O and the Ternary System Fe(NO3)3–Co(NO3)2–H2O with the Extended Universal Quasichemical (UNIQUAC) Model

DEFF Research Database (Denmark)

Arrad, Mouad; Kaddami, Mohammed; Goundali, Bahija El

2016-01-01

Solubility modeling in the binary system Fe(NO3)3–H2O, Co(NO3)2–H2O and the ternary system Fe(NO3)3–Co(NO3)2–H2O is presented. The extended UNIQUAC model was applied to the thermodynamic assessment of the investigated systems. The model parameters obtained were regressed simultaneously using...... the available databank but with more experimental points, recently published in the open literature. A revision of previously published parameters for the cobalt ion and new parameters for the iron(III) nitrate system are presented. Based on this set of parameters, the equilibrium constants of hydrates...

Rapid rate sintering of nanocrystalline ZrO2-3 mol% Y2O3

International Nuclear Information System (INIS)

Chen, D.J.; Mayo, M.J.

1996-01-01

Conventional ramp-and-hold sintering with a wide range of heating rates was conducted on submicrometer and nanocrystalline ZrO 2 -3 mol% Y 2 O 3 powder compacts. Although rapid heating rates have been reported to produce high density/fine grain size products for many submicrometer and smaller starting powders, the application of this technique to ZrO 2 -3 mol% Y 2 O 3 produced mixed results. In the case of submicrometer ZrO 2 -3 mol% Y 2 O 3 , neither densification nor grain growth was affected by the heating rate used. In the case of nanocrystalline ZrO 2 -3 mol% Y 2 O 3 , fast heating rates severely retarded densification and had a minimal effect on grain growth. The large adverse effect of fast heating rates on the densification of the nanocrystalline powder was traced to a thermal gradient/differential densification effect. Microstructural evidence suggests that the rate of densification greatly exceeded the rate of heat transfer in this material; consequently, the sample interior was not able to densify before being geometrically constrained by a fully dense shell which formed at the sample exterior. This finding implies that rapid rate sintering will meet severe practical constraints in the manufacture of bulk nanocrystalline ZrO 2 -3 mol% Y 2 O 3 specimens

La Justice et la Vengeance divine poursuivant le Crime. Pierre-Paul Prud’hon a emblematická tradice

Czech Academy of Sciences Publication Activity Database

Konečný, Lubomír

2014-01-01

Roč. 63, 1/2 (2014), s. 86-93 ISSN 1211-7390 Institutional support: RVO:68378033 Keywords : Pierre-Paul Prud’hon * Nicolas Frochot * Marin Le Roy de Gomberville * Otto van Veen Subject RIV: AL - Art, Architecture, Cultural Heritage

Raman spectroscopic study of structure and crystallisation behaviour of MoO3-La2O3-B2O3 and MoO3-ZnO-B2O3 glasses

Science.gov (United States)

Aleksandrov, L.; Komatsu, T.; Nagamine, K.; Oishi, K.

2011-03-01

In this study, we focus on the structure and crystallization behavior of MoO3-La2O3-B2O3 and MoO3-ZnO-B2O3 glasses. Glasses of both systems were prepared by a melt-quenching method. The thermal stability of the glasses was examined using differential thermal anaysis (DTA) measurements, and the crystalline phases formed by heat treatments were identified by X-ray diffraction (XRD) analysis. Raman scattering spectra at room temperature for the glasses and crystallized samples were measured with a laser microscope operated with an Ar+ (wavelength: 488 nm) laser. DTA measurements indicated that the thermal stability against crystallization of the glasses decreases drastically with increasing MoO3 content. XRD analysis confirmed that crystallization at 600°C for 3 h of glass with the nominal composition of 50MoO3-25La2O3-25B2O3 resulted in the formation of monoclinic LaMoBO6. Crystallization of 50ZnO-xMoO3-(50-x)B2O3 glasses formed triclinic α-ZnMoO4 as an initial crystalline phase. Moreover, for 30 mol% MoO3 glass, transmission electron microscopy observations showed the formation of α-ZnMoO4 nanocrystals with a diameter of ~ 5 nm. Raman bands at 860, 930 and 950 cm-1 suggested that the coordination state of Mo6+ ions in the glasses were mainly (MoO4)2- tetrahedral units. Therefore, MoO3-containing glasses have good potential for optical applications.

Improved direct production of 2,3-dimethylbutenes and 3,3-dimethylbutene from 2-methylpropene on tungsten hydride based catalysts

KAUST Repository

Garron, Anthony; Stoffelbach, Franç ois; Merle, Nicolas; Szeto, Kaï Chung; Thivolle-Cazat, Jean; Basset, Jean-Marie; Norsic, Sé bastien; Taoufik, Mostafa

2012-01-01

2-Methylpropene in the presence of W-H/Ni 1%-Al 2O 3-(500) is transformed in high selectivity into a mixture of 2,3-dimethylbutenes (2,3-DMBs = DMB-1 and DMB-2) and neohexene. 2,3-DMBs arise from the unfavoured 2-methylpropene self-metathesis reaction whereas the neohexene originates from a cascade reaction: 2-methylpropene dimerisation followed by cross metathesis. © 2012 The Royal Society of Chemistry.

Growth and Characterization of Organic Based Marine Dye NLO Material: 7-Bromo-6-chloro-3-[3-[(2R, 3S)-3-hydroxy-2-piperidyl]-2-oxopropyl]-4(3H)-quinazolinone

OpenAIRE

M. Jayandran; V. Balasubramanian

2011-01-01

An organic marine dye compound (7-bromo-6-chloro-3-[3-[(2R, 3S)-3-hydroxy-2-piperidyl]-2-oxopropyl]-4(3H)-quinazolinone) was synthesized. The characteristics of this dye is soluble in water. The organic compound was made into a crystal by slow evaporation technique. The grown crystals were characterized by single crystal x-ray diffraction (XRD) analysis, FTIR studies and UV-visible transmittance studies and the NLO activity of the grown crystal has been checked by second harmonic generation (...

The Data Base for the May 1979 Marine Surface Layer Micrometeorological Experiment at San Nicolas Island, California.

Science.gov (United States)

1982-05-07

solar short wave + sensl/t. + latent) TUR microthermal TURbulence temperature structure parameter ((2) V( ) average raw data Voltage for analog channe...meter height from profile C,2 measurements. TTABLE meter Tide table referenced to mean sea level. TURI OK/m - 2/ 3 Microthermal turbulence temperature...structure parameter (C,2 ) at the ZTURI height. TUR2 *K/m - 2/ 3 Microthermal turbulence temperature structure parameter (C,2) at the ZTUR2 height

2,2,3,3,5,5,6,6-Octa-p-tolyl-1,4-dioxa-2,3,5,6-tetragermacyclohexane dichloromethane disolvate

Directory of Open Access Journals (Sweden)

Monika L. Amadoruge

2009-09-01

Full Text Available The title compound, C56H56Ge4O2·2CH2Cl2 or Tol8Ge4O2·2CH2Cl2 (Tol = p-CH3C6H4, was obtained serendipitously during the attempted synthesis of a branched oligogermane from Tol3GeNMe2 and PhGeH3. The molecule contains an inversion center in the middle of the Ge4O2 ring which is in a chair conformation. The Ge—Ge bond distance is 2.4418 (5 Å and the Ge—O bond distances are 1.790 (2 and 1.785 (2 Å. The torsion angles within the Ge4O2 ring are −56.7 (1 and 56.1 (1° for the Ge—Ge—O—Ge angles and −43.9 (1° for the O—Ge—Ge—O angle.

Electron Excitation Cross Sections for the S II Transitions: 3s(exp 2)3p(exp 3) 4S(exp o) approaches 3s(exp 2)3p(exp 3) 2D(exp o), 2P(exp o), and 3s3p(exp 4) 4P

Science.gov (United States)

Liao, C.; Chutjian, A.; Hitz, D.; Tayal, S. S.

1997-01-01

Experimental and theoretical collisional excitation cross sections are reported for the transitions 3s(exp 2)3p(exp 3)4S(exp o) approaches 3s(exp 2)3p(exp 3) 2D(exp o), 2P(exp o), and 3s3P(exp 4) 4P in S II. The transition wavelengths (energies) are 6716 A (1.85 eV), 4069 A (3.05 eV), and 1256 A (9.87 eV), respectively. In the experiments, use is made of the energy-loss merged-beams method. The metastable fraction of the S II beam was assessed and minimized. The contribution of elastically scattered electrons was reduced by the use of a lowered solenoidal magnetic field and a modulated radio-frequency voltage on the analyzing plates and by retarding grids to reject the elastically scattered electrons with larger Larmor radii. For each transition, comparisons are made among experiments, the new 19 state R-matrix calculation, and three other close-coupling calculations.

Crystal and molecular structure of 2,2’-(quinoxaline-2,3-diyl)dipyridinium dinitrate (H{sub 2}L)(NO{sub 3}){sub 2}

Energy Technology Data Exchange (ETDEWEB)

Egorova, O. A. [People’s Friendship University of Russia (Russian Federation); Polyakova, I. N., E-mail: polyakova@igic.ras.ru; Sergienko, V. S. [Russian Academy of Sciences, Kurnakov Institute of General and Inorganic Chemistry (Russian Federation); Davydov, V. V. [People’s Friendship University of Russia (Russian Federation)

2016-07-15

The crystal structure of 2,2’-(quinoxaline-2,3-diyl)dipyridinium dinitrate (H{sub 2}L)(NO{sub 3}){sub 2} is studied by X-ray diffraction (T = 150 K, R1 = 0.0467). The H{sub 2}L{sup 2+} cation is located on the twofold rotation axis and connected with two NO{sub 3}{sup −} anions by strong N–H···O hydrogen bonds. Planar quinoxaline fragments of cations form stacks with the interplanar spacing of 3.308 Å. The structure of the diprotonated H{sub 2}L{sup 2+} cation is compared with those of the monoprotonated H{sub 2}L{sup 2+} cation and neutral L molecule.

[Ag(NH3)2]Ag(OsO3N)2: a new nitridoosmate(VIII)

International Nuclear Information System (INIS)

Wickleder, M.S.; Pley, Martin

2004-01-01

Dark brown single crystals of [Ag(NH 3 ) 2 ]Ag(OsO 3 N) 2 were obtained from the reaction of Ag 2 CO 3 , OsO 4 , and NH 3 in aqueous solution. The crystal structure was solved in the monoclinic space group C2/m, with the following unit-cell dimensions: a=1962.5(3), b=633.1(1), c=812.6(1) pm, β=96.71(1) deg. The final reliability factor was R=0.0256 for 1034 reflections with I>2σ(I). Linear [Ag(NH 3 ) 2 ] + ions are present oriented perpendicular to the [010] direction, leading to short Ag + -Ag + distances of 316 pm. A second type of Ag + ions in the crystal structure present coordination number '6+1' and are surrounded by oxygen and nitrogen atoms of the nitridoosmate groups. Within the first of the two crystallographically distinguishable anions one can clearly differentiate between oxygen and nitrogen atoms while the second one exhibits a N/O disorder over two positions. The infrared spectrum of [Ag(NH 3 ) 2 ]Ag(OsO 3 N) 2 shows the typical absorptions which can be attributed to the complex anions and the NH 3 ligands

Synthesis and crystal structure of Na6[(UO2)3O(OH)3(SeO4)2]2·10H2O

International Nuclear Information System (INIS)

Baeva, E.Eh.; Serezhkina, L.B.; Virovets, A.V.; Peresypkina, E.V.

2006-01-01

The complex Na 6 [(UO 2 ) 3 O(OH) 3 (SeO 4 ) 2 ] 2 ·10H 2 O (I) is synthesized and studied by monocrystal X-ray diffraction. The compound crystallizes in the orthorhombic crystal system with the unit cell parameters: a=14.2225(7) A, b=18.3601(7) A, c=16.5406(6) A, V=4319.2(3) A 3, Z=4, space group Cmcm, R 1 =0.0406. Compound I is found to be a representative of the crystal-chemical group A 3 M 3 M 3 2 T 2 3 (A=UO 2 2+ , M 3 =O 2- , M 2 =OH - , T 3 =SeO 4 2- ) of the uranyl complexes; it contains layer uranium-containing groups [(UO 2 ) 3 O(OH) 3 (SeO 4 ) 2 ] 3- . These layers are linked to form a three-dimensional cage through bonds formed by the sodium atoms with the oxygen atoms of the uranyl ions and SeO 4 groups that belong to different layers [ru

Investigation of thermal stability and spectroscopic properties in Er3+/Yb3+-codoped TeO2-Li2O-B2O3-GeO2 glasses.

Science.gov (United States)

Nie, Qiu-Hua; Gao, Yuan; Xu, Tie-Feng; Shen, Xiang

2005-06-01

The new Er3+/Yb3+ co-doped 70TeO2-5Li2O-(25-x)B2O3-xGeO2 (x = 0, 5, 10, 15 fand 20 mol.%) glasses were prepared. The thermal stability, absorption spectra, emission spectra and lifetime of the 4I(13/2) level of Er3+ ions were measured and studied. The FT-IR spectra were carried out in order to investigate the structure of local arrangements in glasses. It is found that the thermal stability, absorption cross-section of Yb3+, emission intensity and lifetime of the 4I(13/2) level of Er3+ increase with increasing GeO2 content in the glass composition, while the fluorescence width at half maximum (FWHM) at 1.5 um of Er3+ is about 70 nm. The obtained data suggest that this system glass can be used as a candidate host material for potential broadband optical amplifiers.

Luminescence, scintillation, and energy transfer in SiO{sub 2}-Al{sub 2}O{sub 3}-B{sub 2}O{sub 3}-Gd{sub 2}O{sub 3}:Ce{sup 3+},Pr{sup 3+} glasses

Energy Technology Data Exchange (ETDEWEB)

Lertloypanyachai, Prapon; Chewpraditkul, Weerapong; Pattanaboonmee, Nakarin [Department of Physics, King Mongkut' s University of Technology Thonburi, Bangkok (Thailand); Chen, Danping [Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai (China); Babin, Vladimir; Beitlerova, Alena; Nikl, Martin [Institute of Physics, AS CR, Prague (Czech Republic)

2017-09-15

Ce{sup 3+},Pr{sup 3+}-codoped SiO{sub 2}-Al{sub 2}O{sub 3}-B{sub 2}O{sub 3}-Gd{sub 2}O{sub 3} glasses (SABG:Ce,Pr) were prepared by melt quenching under a CO reducing atmosphere. Luminescence properties were investigated under UV and X-ray excitations. A dominant emission band at 430 nm belonging to the Ce{sup 3+}:5d{sub 1} → 4f transition was observed in the photo- and radio-luminescence spectra. The energy transfer occurs from this Ce{sup 3+} band toward the {sup 3}P{sub J} levels of Pr{sup 3+} with an efficiency of up to 24%, followed by the reduction of integrated luminescence intensity with an increasing Pr{sup 3+} concentration. This result is attributed to the increase in the reabsorption of Ce{sup 3+} luminescence and the non-radiative energy transfer toward the {sup 3}P{sub J} levels of Pr{sup 3+}. The cross-relaxation process within the Pr{sup 3+} pairs can further diminish the total luminescence yield at high Pr{sup 3+} concentrations. The integral scintillation efficiency and light yield measurements were carried out and compared to the reference Bi{sub 4}Ge{sub 3}O{sub 12} (BGO) crystal. (copyright 2017 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

Synthesis and crystal structures of nitratocobaltates Na2[Co(NO3)4], K2[Co(NO3)4], and Ag[Co(NO3)3] and potassium nitratonickelate K2[Ni(NO3)4

International Nuclear Information System (INIS)

Morozov, I. V.; Fedorova, A. A.; Albov, D. V.; Kuznetsova, N. R.; Romanov, I. A.; Rybakov, V. B.; Troyanov, S. I.

2008-01-01

The cobalt(II) and nickel(II) nitrate complexes with an island structure (Na 2 [Co(NO 3 ) 4 ] (I) and K 2 [Co(NO 3 ) 4 ] (II)] and a chain structure [Ag[Co(NO 3 ) 3 ] (III) and K 2 [Ni(NO 3 ) 4 ] (IV)] are synthesized and investigated using X-ray diffraction. In the anionic complex [Co(NO 3 ) 4 ] 2− of the crystal structure of compound I, the Co coordination polyhedron is a twisted tetragonal prism formed by the O atoms of four asymmetric bidentate nitrate groups. In the anion [Co(NO 3 ) 4 ] 2− of the crystal structure of compound II, one of the four NO 3 groups is monodentate and the other NO 3 groups are bidentate (the coordination number of the cobalt atom is equal to seven, and the cobalt coordination polyhedron is a monocapped trigonal prism). The crystal structures of compounds III and IV contain infinite chains of the compositions [Co(NO 3 ) 2 (NO 3 ) 2/2 ] − and [Ni(NO 3 ) 3 (NO 3 ) 2/2 ] 2− , respectively. In the crystal structure of compound III, seven oxygen atoms of one monodentate and three bidentate nitrate groups form a dodecahedron with an unoccupied vertex of the A type around the Co atom. In the crystal structure of compound IV, the octahedral polyhedron of the Ni atom is formed by five nitrate groups, one of which is terminal bidentate. The data on the structure of Co(II) coordination polyhedra in the known nitratocobaltates are generalized.

Synthesis and crystal structures of nitratocobaltates Na2[Co(NO3)4], K2[Co(NO3)4], and Ag[Co(NO3)3] and potassium nitratonickelate K2[Ni(NO3)4

International Nuclear Information System (INIS)

Morozov, I. V.; Fedorova, A. A.; Albov, D. V.; Kuznetsova, N. R.; Romanov, I. A.; Rybakov, V. B.; Troyanov, S. I.

2008-01-01

The cobalt(II) and nickel(II) nitrate complexes with an island structure (Na 2 [Co(NO 3 ) 4 ] (I) and K 2 [Co(NO 3 ) 4 ] (II)] and a chain structure [Ag[Co(NO 3 ) 3 ] (III) and K 2 [Ni(NO 3 ) 4 ] (IV)] are synthesized and investigated using X-ray diffraction. In the anionic complex [Co(NO 3 ) 4 ] 2- of the crystal structure of compound I, the Co coordination polyhedron is a twisted tetragonal prism formed by the O atoms of four asymmetric bidentate nitrate groups. In the anion [Co(NO 3 ) 4 ] 2- of the crystal structure of compound II, one of the four NO 3 groups is monodentate and the other NO 3 groups are bidentate (the coordination number of the cobalt atom is equal to seven, and the cobalt coordination polyhedron is a monocapped trigonal prism). The crystal structures of compounds III and IV contain infinite chains of the compositions [Co(NO 3 ) 2 (NO 3 ) 2/2 ] - and [Ni(NO 3 ) 3 (NO 3 ) 2/2 ] 2- , respectively. In the crystal structure of compound III, seven oxygen atoms of one monodentate and three bidentate nitrate groups form a dodecahedron with an unoccupied vertex of the A type around the Co atom. In the crystal structure of compound IV, the octahedral polyhedron of the Ni atom is formed by five nitrate groups, one of which is terminal bidentate. The data on the structure of Co(II) coordination polyhedra in the known nitratocobaltates are generalized

Interactive Algorithms for Unsupervised Machine Learning

Science.gov (United States)

2015-06-01

in Neural Information Processing Systems, 2013. 14 [3] Louigi Addario-Berry, Nicolas Broutin, Luc Devroye, and Gábor Lugosi. On combinato- rial...Myung Jin Choi, Vincent Y F Tan , Animashree Anandkumar, and Alan S Willsky. Learn- ing Latent Tree Graphical Models. Journal of Machine Learning

Evaluation of a disposable plastic Neubauer counting chamber for semen analysis.

Science.gov (United States)

Kirkman-Brown, Jackson; Björndahl, Lars

2009-02-01

To evaluate whether disposable plastic counting chambers effectively could replace nondisposable, time-consuming, and potentially dangerous glass hemocytometers. Evaluation of equipment in modern laboratory andrology. Comparison of results obtained with plastic chambers with results obtained with "gold-standard" glass hemocytometer counts. Diagnostic laboratory for andrology. Twenty-one patients undergoing investigation for infertility problems. No interventions with patients; sperm in diluted semen samples were used when patients had allowed the use for research and training. Sperm concentration, difference from results obtained with standard equipment. In the first three experimental series, with use of standard routine phase-contrast microscopy, significantly lower count results were obtained consistently from the plastic chambers than from standard chambers. In the fourth series, with use of specialized equipment, equivalent results were obtained but with a considerably greater time commitment because of difficulties in distinguishing sperm adjacent to the gridlines in the plastic chambers. The plastic disposable chamber type was not suitable for routine semen analysis because results are variable depending on the microscope used, and increased time is necessary to do the assessment accurately.

Superstructure formation in PrNi_2Al_3 and ErPd_2Al_3

International Nuclear Information System (INIS)

Eustermann, Fabian; Hoffmann, Rolf-Dieter; Janka, Oliver; Oldenburg Univ.

2017-01-01

The intermetallic phase ErPd_2Al_3 was obtained by arc-melting of the elements and subsequent annealing for crystal growth. The sample was studied by X-ray diffraction on powders and single crystals. The structure of ErPd_2Al_3 was refined from X-ray diffraction data and revealed a superstructure of PrNi_2Al_3 - a CaCu_5 derivative (P6/m, a=1414.3(1), c=418.87(3) pm wR=0.0820, 1060 F"2 values, 48 variables). The same superstructure was subsequently found for PrNi_2Al_3 (P6/m, a=1407.87(4), c=406.19(2) pm, wR=0.0499, 904 F"2 values, 47 variables). In the crystal structure, the aluminium and transition metal atoms form a polyanionic network according to [T_2Al_3]"δ"-, while rare earth atoms fill cavities within the networks. They are coordinated by six transition metal and twelve aluminum atoms. In contrast to the PrNi_2Al_3 type structure reported so far, two crystallographic independent rare-earth sites are found of which one (1b) is shifted by 1/2 z, causing a distortion in the structure along with a recoloring of the T and Al atoms in the network.

Combined use of O3/H2O2 and O3/Mn2+ in flotation of dairy wastewater

Directory of Open Access Journals (Sweden)

Marta Cristina Silva Carvalho

2018-05-01

Full Text Available This work investigated the degradation of organic matter present in synthetic dairy wastewater by the combination of ozonation (ozone (O3/hydrogen peroxide (H2O2 and catalytic ozonation (ozone (O3/manganese (Mn2+ associated with dispersed air flotation process. The effect of independent factors such as O3 concentration, pH and H2O2 and Mn2+ concentration was evaluated. For the flotation/O3/H2O2 treatment, the significant variables (p ≤ 0.05 were: O3 concentration (linear and quadratic effect, H2O2 concentration linear and quadratic effect, pH values (linear and quadratic effect and interaction O3 concentration versus pH. For catalytic ozonation, it was observed that the significant variable was the linear effect of O3 concentration. According to the desirability function, it was concluded that the optimal condition for the treatment of flotation/O3/H2O2 can be obtained in acidic solution using O3 concentrations greater than 42.9 mg L-1 combined with higher concentrations of H2O2 to 1071.5 mg L-1. On other hand, at pH values higher than 9.0, the addition of O3 may be neglected when using higher concentrations than 1071.5 mg L-1 of H2O2. For flotation/ozonation catalyzed by Mn2+, it was observed that metal addition did not affect treatment, resulting in an optimum condition: 53.8 mg L-1 of O3 and pH 3.6.

Growth and Characterization of Organic Based Marine Dye NLO Material: 7-Bromo-6-chloro-3-[3-[(2R, 3S-3-hydroxy-2-piperidyl]-2-oxopropyl]-4(3H-quinazolinone

Directory of Open Access Journals (Sweden)

M. Jayandran

2011-01-01

Full Text Available An organic marine dye compound (7-bromo-6-chloro-3-[3-[(2R, 3S-3-hydroxy-2-piperidyl]-2-oxopropyl]-4(3H-quinazolinone was synthesized. The characteristics of this dye is soluble in water. The organic compound was made into a crystal by slow evaporation technique. The grown crystals were characterized by single crystal x-ray diffraction (XRD analysis, FTIR studies and UV-visible transmittance studies and the NLO activity of the grown crystal has been checked by second harmonic generation (SHG test.

Effect of concentration variation on 2.0 μm emission of Ho3+-doped SiO2-Al2O3-Na2CO3-SrF2-CaF2 oxyfluorosilicate glasses

International Nuclear Information System (INIS)

Gelija, Devarajulu; Borelli, Deva Prasad Raju

2018-01-01

The concentration variation of Ho 3+ ion-doped SiO 2 -Al 2 O 3 -Na 2 CO 3 -SrF 2 -CaF 2 glasses has been prepared by conventional melt quenching method. The thermal stability of 1 mol % of Ho 3+ -doped oxyfluorosilicate glass has been calculated using the differential thermal analysis (DTA) spectra. The phenomenological Judd-Ofelt intensity parameters Ω λ (λ = 2, 4 and 6) were calculated for all concentrations of Ho 3+ ions. The luminescence spectra in visible region of Ho 3+ ion-doped glasses were recorded under the excitation wavelength of 452 nm. The spectra consists of several intense emission bands ( 5 F 4 , 5 S 2 ) → 5 I 8 (547 nm), 5 F 3 → 5 I 8 (647 nm), 5 F 5 → 5 I 7 (660 nm) and ( 5 F 4 , 5 S 2 ) → 5 I 7 (750 nm) in the range 500-780 nm. The fluorescence emission at ∝ 2.0 μm ( 5 I 7 → 5 I 8 ) was observed under the excitation of 488 nm Ar-ion laser. The stimulated emission cross section for 5 I 7 → 5 I 8 transition (∝ 2.0 μm) varies from 8.46 to 9.52 x 10 -21 cm 2 , as calculated by the Fuchtbauer-Ladenburg (FL) theory. However, Mc-Cumber theory was used to calculate emission cross section values about 4.24-5.75 x 10 -21 cm 2 for the 5 I 7 → 5 I 8 transition in all concentrations of Ho 3+ -doped oxyfluorosilicate glasses. Therefore, these results reveal that the 0.5 mol % of Ho 3+ -doped oxyfluorosilicate glasses, exhibiting higher emission cross section, has potentially been used for laser applications at ∝ 2.0 μm. (orig.)

Study on spectroscopic properties and effects of tungsten ions in 2Bi2O3-3GeO2/SiO2 glasses.

Science.gov (United States)

Yu, Pingsheng; Su, Liangbi; Cheng, Junhua; Zhang, Xia; Xu, Jun

2017-04-01

The 2Bi 2 O 3 -3GeO 2 /SiO 2 glass samples have been prepared by the conventional melt quenching technique. XRD patterns, absorption spectra, excitation-emission spectra and Raman measurements were utilized to characterize the synthesized glasses. When substitute SiO 2 for GeO 2 , the 0.4Bi 2 O 3 -(0.4-0.1)GeO 2 -(0.2-0.5)SiO 2 glasses exhibit strong emission centered at about 475nm (under 300nm excitation), and the decay constants are within the scope of 20-40ns. W doping into 2Bi 2 O 3 -3SiO 2 glass could increase the emission intensity of 470nm, and the W-doped 2Bi 2 O 3 -3SiO 2 glass has shown another emission at about 433nm with much shorter decay time (near 10ns). The 2Bi 2 O 3 -3GeO 2 /SiO 2 glass system could be the possible candidate for scintillator in high energy physics applications. Copyright © 2017 Elsevier Ltd. All rights reserved.

Subsolidus phase relations of Bi2O3-Nd2O3-CuO

International Nuclear Information System (INIS)

Sun Yezhou

1997-01-01

The subsolidus phase relations of the Bi 2 O 3 -Nd 2 O 3 -CuO ternary system and its binary systems along with crystallographic parameters of the compounds were investigated by X-ray powder diffraction and differential thermal analysis. The room temperature section of the phase diagram of the Bi 2 O 3 -Nd 2 O 3 -CuO system can be divided into two diphase regions and six triphase regions. No ternary compound was found. There exist two solid solutions (α, β) and a compound Bi 0.55 Nd 0.45 O 1.5 in the (Bi 2 O 2 ) 1-x (Nd 2 O 3 ) x system. Both solid solution α (0.05≤x≤0.30) and β (0.53≤x≤0.73) belong to the rhombohedral system (R3m). The lattice parameters represented by a hexagonal cell are a=3.9832(4), c=27.536(5) A for Bi 0.8 Nd 0.2 O 1.5 (α phase) and a=3.8826(3), c=9.727(1) A for Bi 0.4 Nd 0.8 O 1.5 (β phase). The Bi 0.55 Nd 0.45 O 1.5 compound crystallizes in a face-centered cubic (f.c.c.) lattice with a=5.5480(2) A. (orig.)

Enzymatic degradation of cyclic 2,3-diphosphoglycerate to 2,3-diphosphoglycerate in Methanobacterium thermoautotrophicum

International Nuclear Information System (INIS)

Krishna Sastry, M.V.; Robertson, D.E.; Moynihan, J.A.; Roberts, M.F.

1992-01-01

2,3-Diphosphoglycerate (2,3-DPG) has been found to be the product of the enzymatic degradation of cyclic 2,3-diphosphoglycerate (cDPG) in the archaebacterium Methanobacterium thermoautotrophicum ΔH. Although 2,3-DPG has not previously been detected as a major soluble component of M. thermoautotrophicum, large pools accumulated at an incubation temperature of 50C. Under these conditions, cellular activity was significantly decreased; a return of the culture to the optimum growth temperature restored the 2,3-DPG pool back to original low levels and caused steady-state cDPG levels to increase again. While 13 CO 2 -pulse/ 12 CO 2 -chase experiments at 50C showed that the cDPG turned over, the appearance of 2,3-DPG at NMR-visible concentrations required at least 10 h. Production of 2,3-DPG in vivo was prevented by exposure of the cells to O 2 . the enzyme responsible for this hydrolysis of cDPG was purified by affinity chromatography and appears to be a 33-kDa protein. Activity was detected in the presence of oxygen and was enhanced by a solution of 1 M KCl, 25 mM MgCl 2 , and dithiothreitol. Both K m and V max have been determined at 37C; kinetics also indicate that in vitro the product, 2,3-DPG, is an inhibitor of cDPG hydrolysis. These findings are discussed in view of a proposed role for cDPG in methanogens

Chemical quenching of positronium in Fe2O3/Al2O3 catalysts