WorldWideScience

Sample records for metric tons molybdenum

  1. Semiportable load-cell-based weighing system prototype of 18.14-metric-ton (20-ton) capacity for UF6 cylinder weight verifications: description and testing procedure

    International Nuclear Information System (INIS)

    McAuley, W.A.

    1984-01-01

    The 18.14-metric-ton-capacity (20-ton) Load-Cell-Based Weighing System (LCBWS) prototype tested at the Oak Ridge (Tennessee) Gaseous Diffusion Plant March 20-30, 1984, is semiportable and has the potential for being highly accurate. Designed by Brookhaven National Laboratory, it can be moved to cylinders for weighing as opposed to the widely used operating philosophy of most enrichment facilities of moving cylinders to stationary accountability scales. Composed mainly of commercially available, off-the-shelf hardware, the system's principal elements are two load cells that sense the weight (i.e., force) of a uranium hexafluoride (UF 6 ) cylinder suspended from the LCBWS while the cylinder is in the process of being weighed. Portability is achieved by its attachment to a double-hook, overhead-bridge crane. The LCBWS prototype is designed to weigh 9.07- and 12.70-metric ton (10- and 14-ton) UF 6 cylinders. A detailed description of the LCBWS is given, design information and criteria are supplied, a testing procedure is outlined, and initial test results are reported. A major objective of the testing is to determine the reliability and accuracy of the system. Other testing objectives include the identification of (1) potential areas for system improvements and (2) procedural modifications that will reflect an improved and more efficient system. The testing procedure described includes, but is not limited to, methods that account for temperature sensitivity of the instrumentation, the local variation in the acceleration due to gravity, and buoyance effects. Operational and safety considerations are noted. A preliminary evaluation of the March test data indicates that the LCBWS prototype has the potential to have an accuracy in the vicinity of 1 kg

  2. Production equipment development needs for a 700 metric ton/year light water reactor mixed oxide fuel manufacturing plant

    International Nuclear Information System (INIS)

    Blahnik, D.E.

    1977-09-01

    A literature search and survey of fuel suppliers was conducted to determine how much development of production equipment is needed for a 700 metric tons/y LWR mixed-oxide (UO 2 --PuO 2 ) fuel fabrication plant. Results indicate that moderate to major production equipment development is needed in the powder and pellet processing areas. The equipment in the rod and assembly processing areas need only minor development effort. Required equipment development for a 700 MT/y plant is not anticipated to delay startup of the plant. The development, whether major or minor, can be done well within the time frame for licensing and construction of the plant as long as conventional production equipment is used

  3. Proposed method for assigning metric tons of heavy metal values to defense high-level waste forms to be disposed of in a geologic repository

    International Nuclear Information System (INIS)

    1987-08-01

    A proposed method is described for assigning an equivalent metric ton heavy metal (eMTHM) value to defense high-level waste forms to be disposed of in a geologic repository. This method for establishing a curie equivalency between defense high-level waste and irradiated commercial fuel is based on the ratio of defense fuel exposure to the typical commercial fuel exposure, MWd/MTHM. application of this technique to defense high-level wastes is described. Additionally, this proposed technique is compared to several alternate calculations for eMTHM. 15 refs., 2 figs., 10 tabs

  4. Recent situation and future of molybdenum mineral resources; Molybdenum shigen no genjo to shorai

    Energy Technology Data Exchange (ETDEWEB)

    Ono, K.; Nishiyama, T. [Kyoto University, Kyoto (Japan)

    1997-05-05

    Molybdenum is produced mainly from molybdenite, and the majority of this ore is exploited from the porphyry deposit. The reserve is estimated at 5.5-million ton. A total of 118-thousand ton was produced across the world in 1995, in the U.S., China, Chile, and Canada, the countries named in the order of quantities they exploited. Molybdenite is first refined by flotation for the production of a sulphide. It is subjected to oxidizing roasting for conversion into crude molybdenum trioxide, which is next subjected to extraction in warmed-up aqueous ammonia and then to evaporation for the crystallization of ammonium paramolybdate. The crystals are baked for conversion into molybdenum trioxide of the ordinary purity, to be further processed into ferromolybdenum, molybdenum compounds, molybdenum powder, etc. In view of the magnitude of demand, the metal is used mostly for the manufacture of special steels and special alloys. The demand for this metal, though small in size, involves important articles, such as line materials for semiconductors in the power industry, catalysts in the chemical industry, and lubricants. Japan`s stockpile includes molybdenum, but the U.S. has been stockpiling none since 1977. 9 refs., 4 figs., 1 tab.

  5. Transportation system benefits of early deployment of a 75-ton multipurpose canister system

    International Nuclear Information System (INIS)

    Wankerl, M.W.; Schmid, S.P.

    1995-01-01

    In 1993 the US Civilian Radioactive Waste Management System (CRWMS) began developing two multipurpose canister (MPC) systems to provide a standardized method for interim storage and transportation of spent nuclear fuel (SNF) at commercial nuclear power plants. One is a 75-ton concept with an estimated payload of about 6 metric tons (t) of SNF, and the other is a 125-ton concept with an estimated payload of nearly 11 t of SNF. These payloads are two to three times the payloads of the largest currently certified US rail transport casks, the IF-300. Although is it recognized that a fully developed 125-ton MPC system is likely to provide a greater cost benefit, and radiation exposure benefit than the lower-capacity 75-ton MPC, the authors of this paper suggest that development and deployment of the 75-ton MPC prior to developing and deploying a 125-ton MPC is a desirable strategy. Reasons that support this are discussed in this paper

  6. Molybdenum extraction from copper-molybdenum ores

    International Nuclear Information System (INIS)

    Nevaeva, L.M.

    1982-01-01

    Molybdenum extraction from copper-molybdenum ores as practised in different countries is reviewed. In world practice the production process including depression of copper and iron sulfides and flotation of molybdenite is widely spread. At two USA factories the process of a selective flotation with molybdenite depression by dextrin is used

  7. Molybdenum, molybdenum oxides, and their electrochemistry.

    Science.gov (United States)

    Saji, Viswanathan S; Lee, Chi-Woo

    2012-07-01

    The electrochemical behaviors of molybdenum and its oxides, both in bulk and thin film dimensions, are critical because of their widespread applications in steels, electrocatalysts, electrochromic materials, batteries, sensors, and solar cells. An important area of current interest is electrodeposited CIGS-based solar cells where a molybdenum/glass electrode forms the back contact. Surprisingly, the basic electrochemistry of molybdenum and its oxides has not been reviewed with due attention. In this Review, we assess the scattered information. The potential and pH dependent active, passive, and transpassive behaviors of molybdenum in aqueous media are explained. The major surface oxide species observed, reversible redox transitions of the surface oxides, pseudocapacitance and catalytic reduction are discussed along with carefully conducted experimental results on a typical molybdenum glass back contact employed in CIGS-based solar cells. The applications of molybdenum oxides and the electrodeposition of molybdenum are briefly reviewed. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  8. Analytic chemistry of molybdenum

    International Nuclear Information System (INIS)

    Parker, G.A.

    1983-01-01

    Electrochemical, colorimetric, gravimetric, spectroscopic, and radiochemical methods for the determination of molybdenum are summarized in this book. Some laboratory procedures are described in detail while literature citations are given for others. The reader is also referred to older comprehensive reviews of the analytical chemistry of molybdenum. Contents, abridged: Gravimetric methods. Titrimetric methods. Colorimetric methods. X-ray fluorescence. Voltammetry. Catalytic methods. Molybdenum in non-ferrous alloys. Molydbenum compounds

  9. Molybdenum from uranium solutions

    International Nuclear Information System (INIS)

    Gardner, H.E.

    1981-01-01

    A method of removing molybdenum from a uranium bearing solution is claimed. It comprises adding sufficient reactive lead compound to supply at least 90 percent of the stoichiometric quantity of lead ion required to fully react with the molybdenum present to form insoluble lead molybdate and continuing the reaction with agitation until the desired percentage of the molybdenum present has reacted with the lead ion

  10. Potentiometric determination of molybdenum

    International Nuclear Information System (INIS)

    Rusina, O.N.; Gorbatkova, B.Kh.

    1977-01-01

    Potentiometric titration by lead acetate is used to determine molybdenum in the form of molybdate ions. The behaviour of bimetallic electrode couples, i.e. tungsten-lead, platinum-lead, lead-carbon electrode, molybdenum-carbon electrode platinum-molibdenum has been investigated. The greatest jump of the potential in the finite point is observed for platinum-molybdenum electrode couple (150 mV/ml at pH 4.0-5.5). The limiting concentration of molybdenum in potentiometric titration by lead acetate is 2.8x10 -4 M. The measurements are accurate to within +-0.1%

  11. Molybdenum market in transition

    International Nuclear Information System (INIS)

    Sutulov, A.

    1980-01-01

    Since the beginning of 1980 - after seven years of constant unbalance between supply and demand of molybdenum, characterized by a demand overhang and after two years of unprecedented spot market prices - clear signals for a consolidation of the molybdenum market can be recognized. (orig.) [de

  12. High-strength chromium--molybdenum rails

    International Nuclear Information System (INIS)

    Smith, Y.E.; Sawhill, J.M. Jr.; Cias, W.W.; Eldis, G.T.

    1976-01-01

    A laboratory study was conducted with the aim of developing an as-rolled rail of over 100 ksi (689 N/mm 2 ) yield strength. A series of compositions providing both pearlitic and bainitic microstructures was evaluated. A fine pearlitic structure was developed in a 0.73 percent C -- 0.83 percent Mn -- 0.16 percent Si -- 0.75 percent Cr -- 0.21 percent Mo steel by simulating the mill cooling rate of 132-lb/yd (65.5-kg/m) rail. Two 100-ton commercial heats were made of this approximate composition and processed into 132-lb/yd (65.5-kg/m) rail. Samples tested in the laboratory ranged from 109 to 125 ksi (750 to 860 N/mm 2 ) in yield strength. The chromium-molybdenum rails also exhibited excellent fracture toughness and fatigue properties. Sections of the rail were joined by both flash-butt welding and thermite welding. The hardness peaks produced in the flash-butt welds could be reduced by applying either a postweld current or an induction heating cycle. The high-strength chromium-molybdenum rails have been in service for over eight months in curved sections of an ore railway that carries over 55 million gross long tons per year. 7 tables, 18 figs

  13. Process for purifying molybdenum

    International Nuclear Information System (INIS)

    Cheresnowsky, J.

    1989-01-01

    This patent describes a process for purifying molybdenum containing arsenic and phosphorus. The process comprising: adding to an acidic slurry of molybdenum trioxide, a source of magnesium ions in a solid form, with the amount of magnesium and the magnesium ion concentration in the subsequently formed ammonium molybdate solution being sufficient to subsequently form insoluble compounds containing greater than about 80% by weight of the arsenic and greater than about 80% by weight of the phosphorus, and ammonia in an amount sufficient to subsequently dissolve the molybdenum and subsequently form the insoluble compounds, with the source of magnesium ions being added prior to the addition of the ammonia; digesting the resulting ammoniated slurry at a temperature sufficient to dissolve the molybdenum and form an ammonium molybdate solution while the pH is maintained at from bout 9 to about 10 to form a solid containing the insoluble compounds; and separating the solid from the ammonium molybdate solution

  14. Bibliographic study on molybdenum biokinetics

    International Nuclear Information System (INIS)

    Erzberger, A.

    1988-05-01

    This bibliographical study compiles and analyzes findings about the metabolism and resorption of molybdenum. Besides including studies on the physiology of molybdenum 99, a general survey is given on molybdenum in the environment and on its physiological behaviour. In particular, information on the dependence of molybdenum resorption on various factors, such as the chemical form, antagonisms etc., are gathered from literature. These factors have to be considered for sensibly carrying out necessary experiments. (orig./MG) [de

  15. Semantic metrics

    OpenAIRE

    Hu, Bo; Kalfoglou, Yannis; Dupplaw, David; Alani, Harith; Lewis, Paul; Shadbolt, Nigel

    2006-01-01

    In the context of the Semantic Web, many ontology-related operations, e.g. ontology ranking, segmentation, alignment, articulation, reuse, evaluation, can be boiled down to one fundamental operation: computing the similarity and/or dissimilarity among ontological entities, and in some cases among ontologies themselves. In this paper, we review standard metrics for computing distance measures and we propose a series of semantic metrics. We give a formal account of semantic metrics drawn from a...

  16. Molybdenum solar neutrino experiment

    International Nuclear Information System (INIS)

    Wolfsberg, K.; Cowan, G.A.; Bryant, E.A.

    1984-01-01

    The goal of the molybdenum solar neutrino experiment is to deduce the 8 B solar neutrino flux, averaged over the past several million years, from the concentration of 98 Tc in a deeply buried molybdenum deposit. The experiment is important to an understanding of stellar processes because it will shed light on the reason for the discrepancy between theory and observation of the chlorine solar neutrino experiment. Possible reasons for the discrepancy may lie in the properties of neutrinos (neutrino oscillations or massive neutrinos) or in deficiencies of the standard solar model. The chlorine experiment only measures the 8 B neutrino flux in current times and does not address possible temporal variations in the interior of the sun, which are also not considered in the standard model. In the molybdenum experiment, we plan to measure 98 Tc (4.2 Myr), also produced by 8 B neutrinos, and possibly 97 Tc (2.6 Myr), produced by lower energy neutrinos

  17. Method of producing molybdenum-99

    Science.gov (United States)

    Pitcher, Eric John

    2013-05-28

    Method of producing molybdenum-99, comprising accelerating ions by means of an accelerator; directing the ions onto a metal target so as to generate neutrons having an energy of greater than 10 MeV; directing the neutrons through a converter material comprising techentium-99 to produce a mixture comprising molybdenum-99; and, chemically extracting the molybdenum-99 from the mixture.

  18. The molybdenum-technetium solar neutrino experiment

    International Nuclear Information System (INIS)

    Schroeder, N.C.; Wolfsberg, K.; Rokop, D.J.

    1991-01-01

    The authors are attempting to measure the time-averaged 8 B solar-neutrino flux over 10 Myr by measuring 98 Tc produced through the 98 Mo( nu ,e - ) reaction in a deeply buried molybdenum deposit. This will test the prediction of periodic mixing of the Sun's core over long time intervals. To separate technetium from 10,000-ton quantities of Henderson ore, the authors have taken advantage of the commercial processing of molybdenite. Technetium, volatilized during roasting of molybdenite to MoO 3 , was scrubbed from the gas stream and collected on anion exchange columns. After sample reduction and chemical separation and purification they measured technetium, as TcO 4 - , using negative thermal ionization mass spectrometry. Measurement of 99 Tc in spiked and 98 Tc in unspiked fractions from one sample gives an apparent solar neutrino production rate of 95.8 SNU. However, roaster memory probably invalidates this result

  19. Climax-Type Porphyry Molybdenum Deposits

    Science.gov (United States)

    Ludington, Steve; Plumlee, Geoffrey S.

    2009-01-01

    Climax-type porphyry molybdenum deposits, as defined here, are extremely rare; thirteen deposits are known, all in western North America and ranging in age from Late Cretaceous to mainly Tertiary. They are consistently found in a postsubduction, extensional tectonic setting and are invariably associated with A-type granites that formed after peak activity of a magmatic cycle. The deposits consist of ore shells of quartz-molybdenite stockwork veins that lie above and surrounding the apices of cupola-like, highly evolved, calc-alkaline granite and subvolcanic rhyolite-porphyry bodies. These plutons are invariably enriched in fluorine (commonly >1 percent), rubidium (commonly >500 parts per million), and niobium-tantalum (Nb commonly >50 parts per million). The deposits are relatively high grade (typically 0.1-0.3 percent Mo) and may be very large (typically 100-1,000 million tons). Molybdenum, as MoS2, is the primary commodity in all known deposits. The effect on surface-water quality owing to natural influx of water or sediment from a Climax-type mineralized area can extend many kilometers downstream from the mineralized area. Waste piles composed of quartz-silica-pyrite altered rocks will likely produce acidic drainage waters. The potential exists for concentrations of fluorine or rare metals in surface water and groundwater to exceed recommended limits for human consumption near both mined and unmined Climax-type deposits.

  20. Molybdenum dioxide-molybdenite roasting

    International Nuclear Information System (INIS)

    Sabacky, B.J.; Hepworth, M.T.

    1984-01-01

    A process is disclosed for roasting molybdenite concentrates directly to molybdenum dioxide. The process comprises establishing a roasting zone having a temperature of about 700 0 C. to about 800 0 C., introducing into the roasting zone particulate molybdenum dioxide and molybdenite in a weight ratio of at least about 2:1 along with an oxygen-containing gas in amount sufficient to oxidize the sulfur content of the molybdenite to molybdenum dioxide

  1. Metric learning

    CERN Document Server

    Bellet, Aurelien; Sebban, Marc

    2015-01-01

    Similarity between objects plays an important role in both human cognitive processes and artificial systems for recognition and categorization. How to appropriately measure such similarities for a given task is crucial to the performance of many machine learning, pattern recognition and data mining methods. This book is devoted to metric learning, a set of techniques to automatically learn similarity and distance functions from data that has attracted a lot of interest in machine learning and related fields in the past ten years. In this book, we provide a thorough review of the metric learnin

  2. Multi-Ton Argon and Xenon

    Energy Technology Data Exchange (ETDEWEB)

    Alarcon, Ricardo; Balascuta, Septimiu; Alton, Drew; Aprile, Elena; Giboni, Karl-Ludwig; Haruyama, Tom; Lang, Rafael; Melgarejo, Antonio Jesus; Ni, Kaixuan; Plante, Guillaume; Choi, Bin [et al.

    2009-01-01

    There is a wide range of astronomical evidence that the visible stars and gas in all galaxies, including our own, are immersed in a much larger cloud of non-luminous matter, typically an order of magnitude greater in total mass. The existence of this ''dark matter'' is consistent with evidence from large-scale galaxy surveys and microwave background measurements, indicating that the majority of matter in the universe is non-baryonic. The nature of this non-baryonic component is still totally unknown, and the resolution of the ''dark matter puzzle'' is of fundamental importance to cosmology, astrophysics, and elementary particle physics. A leading explanation, motivated by supersymmetry theory, is the existence of as yet undiscovered Weakly Interacting Massive Particles (WIMPs), formed in the early universe and subsequently clustered in association with normal matter. WIMPs could, in principle, be detected in terrestrial experiments by their collisions with ordinary nuclei, giving observable low energy (< 100 keV) nuclear recoils. The predicted low collision rates require ultra-low background detectors with large (0.1-10 ton) target masses, located in deep underground sites to eliminate neutron background from cosmic ray muons. The establishment of the Deep Underground Science and Engineering Laboratory for large-scale experiments of this type would strengthen the current leadership of US researchers in this and other particle astrophysics areas. We propose to detect nuclear recoils by scintillation and ionization in ton-scale liquid noble gas targets, using techniques already proven in experiments at the 0.01-0.1 ton level. The experimental challenge is to identify these events in the presence of background events from gammas, neutrons, and alphas.

  3. ICARUS 600 ton: A status report

    CERN Document Server

    Vignoli, C; Badertscher, A; Barbieri, E; Benetti, P; Borio di Tigliole, A; Brunetti, R; Bueno, A; Calligarich, E; Campanelli, Mario; Carli, F; Carpanese, C; Cavalli, D; Cavanna, F; Cennini, P; Centro, S; Cesana, A; Chen, C; Chen, Y; Cinquini, C; Cline, D; De Mitri, I; Dolfini, R; Favaretto, D; Ferrari, A; Gigli Berzolari, A; Goudsmit, P; He, K; Huang, X; Li, Z; Lu, F; Ma, J; Mannocchi, G; Mauri, F; Mazza, D; Mazzone, L; Montanari, C; Nurzia, G P; Otwinowski, S; Palamara, O; Pascoli, D; Pepato, A; Periale, L; Petrera, S; Piano Mortari, Giovanni; Piazzoli, A; Picchi, P; Pietropaolo, F; Rancati, T; Rappoldi, A; Raselli, G L; Rebuzzi, D; Revol, J P; Rico, J; Rossella, M; Rossi, C; Rubbia, C; Rubbia, A; Sala, P; Scannicchio, D; Sergiampietri, F; Suzuki, S; Terrani, M; Ventura, S; Verdecchia, M; Wang, H; Woo, J; Xu, G; Xu, Z; Zhang, C; Zhang, Q; Zheng, S

    2000-01-01

    The goal of the ICARUS Project is the installation of a multi-kiloton LAr TPC in the underground Gran Sasso Laboratory. The programme foresees the realization of the detector in a modular way. The first step is the construction of a 600 ton module which is now at an advanced phase. It will be mounted and tested in Pavia in one year and then it will be moved to Gran Sasso for the final operation. The major cryogenic and purification systems and the mechanical components of the detector have been constructed and tested in a 10 m3 prototype. The results of these tests are here summarized.

  4. Machining of Molybdenum by EDM-EP and EDC Processes

    Science.gov (United States)

    Wu, K. L.; Chen, H. J.; Lee, H. M.; Lo, J. S.

    2017-12-01

    Molybdenum metal (Mo) can be machined with conventional tools and equipment, however, its refractory propertytends to chip when being machined. In this study, the nonconventional processes of electrical discharge machining (EDM) and electro-polishing (EP) have been conducted to investigate the machining of Mo metal and fabrication of Mo grid. Satisfactory surface quality was obtained using appropriate EDM parameters of Ip ≦ 3A and Ton EDMed Mo metal. Experimental results proved that the appropriate parameters of Ip = 5A and Ton = 50μs at Toff = 10μs can obtain the deposit with about 60μm thickness. The major phase of deposit on machined Mo surface was SiC ceramic, while the minor phases included MoSi2 and/or SiO2 with the presence of free Si due to improper discharging parameters and the use of silicone oil as the dielectric fluid.

  5. Metrication manual

    International Nuclear Information System (INIS)

    Harper, A.F.A.; Digby, R.B.; Thong, S.P.; Lacey, F.

    1978-04-01

    In April 1978 a meeting of senior metrication officers convened by the Commonwealth Science Council of the Commonwealth Secretariat, was held in London. The participants were drawn from Australia, Bangladesh, Britain, Canada, Ghana, Guyana, India, Jamaica, Papua New Guinea, Solomon Islands and Trinidad and Tobago. Among other things, the meeting resolved to develop a set of guidelines to assist countries to change to SI and to compile such guidelines in the form of a working manual

  6. Improvements in BTS estimation of ton-miles

    Science.gov (United States)

    2004-08-01

    Ton-miles (one ton of freight shipped one mile) is the primary physical measure of freight transportation output. This paper describes improved measurements of ton-miles for air, truck, rail, water, and pipeline modes. Each modal measure contains a d...

  7. On molybdenum (6) alcoholates

    International Nuclear Information System (INIS)

    Turova, N.Ya.; Kessler, V.G.

    1990-01-01

    Synthesis techniques for molybdenum (6) alcoholates of MoO(OR) 4 (1) and MoO 2 (OR) 2 (2) series by means of exchange interaction of corresponding oxychloride with MOR (M=Li, Na) are obtained. These techniques have allowed to prepare 1(R=Me, Et, i-Pr) and 2(R=Me, Et) with 70-98 % yield. Methylates are also prepared at ether interchange of ethylates by methyl alcohol. Metal anode oxidation in corresponding alcohol may be used for 1 synthesis. Physicochemical properties of both series alcoholates, solubility in alcohols in particular, depend on their formation conditions coordination polymerism. Alcoholates of 1 are rather unstable and tend to decomposition up to 2 and ether. It is suggested to introduce NaOR microquantities to stabilize those alcoholates

  8. Molybdenum Tube Characterization report

    Energy Technology Data Exchange (ETDEWEB)

    Beaux II, Miles Frank [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Usov, Igor Olegovich [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2017-02-07

    Chemical vapor deposition (CVD) techniques have been utilized to produce free-standing molybdenum tubes with the end goal of nuclear fuel clad applications. In order to produce tubes with properties desirable for this application, deposition rates were lowered requiring long deposition durations on the order of 50 hours. Standard CVD methods as well as fluidized-bed CVD (FBCVD) methods were applied towards these objectives. Characterization of the tubes produced in this manner revealed material suitable for fuel clad applications, but lacking necessary uniformity across the length of the tubes. The production of freestanding Mo tubes that possess the desired properties across their entire length represents an engineering challenge that can be overcome in a next iteration of the deposition system.

  9. Diffusion in molybdenum disilicide

    International Nuclear Information System (INIS)

    Salamon, M.; Mehrer, H.

    2005-01-01

    The diffusion behaviour of the high-temperature material molybdenum disilicide (MoSi 2 ) was completely unknown until recently. In this paper we present studies of Mo self-diffusion and compare our present results with our already published studies of Si and Ge diffusion in MoSi 2 . Self-diffusion of molybdenum in monocrystalline MoSi 2 was studied by the radiotracer technique using the radioisotope 99 Mo. Deposition of the radiotracer and serial sectioning after the diffusion anneals to determine the concentration-depth profiles was performed using a sputtering device. Diffusion of Mo is a very slow process. In the entire temperature region investigated (1437 to 2173 K), the 99 Mo diffusivities in both principal directions of the tetragonal MoSi 2 crystals obey Arrhenius laws, where the diffusion perpendicular to the tetragonal axis is faster by two to three orders of magnitude than parallel to it. The activation enthalpies for diffusion perpendicular and parallel to the tetragonal axis are Q perpendicular to = 468 kJ mol -1 (4.85 eV) and Q parallel = 586 kJ mol -1 (6.07 eV), respectively. Diffusion of Si and its homologous element Ge is fast and is mediated by thermal vacancies of the Si sublattice of MoSi 2 . The diffusion of Mo is by several orders of magnitude slower than the diffusion of Si and Ge. This large difference suggests that Si and Mo diffusion are decoupled and that the diffusion of Mo likely takes place via vacancies on the Mo sublattice. (orig.)

  10. Reheating experiment in the 35-ton pile

    International Nuclear Information System (INIS)

    Cherot, J.; Girard, Y.

    1957-01-01

    When the 35-ton pile was started up it was necessary for us, in order to study certain effects (xenon for example), to know the anti reactivity value of the rods as a function of their dimensions. We have made use of the possibility, in the reheating experiment, of raising the temperature of the graphite-uranium block by simple heating, in order to determine the anti reactivity curves of the rods, and from that the overall temperature coefficient. For the latter we have considered two solutions: first, one in which the average temperature of the pile is defined as our arithmetical mean of the different values given by the 28 thermocouples distributed throughout the pile; a second in which the temperature in likened to a poisoning and is balanced by the square of the flux. The way in which the measurements have been made is indicated, and the different instruments used are described. The method of reheating does not permit the separation of the temperature coefficients of uranium and of graphite. The precision obtained is only moderate, and suffers from the changes of various parameters necessary to other manipulations carried out simultaneously (life time modulators for example), and finally it is a function of the comparatively restricted time allowed. It is evident of course that more careful stabilisation at the different plateaux chosen would have necessitated long periods of reheating. (author) [fr

  11. From Throw Weights to Metric Tons: The Radioactive Waste Problems of Russia's Northern Fleet

    National Research Council Canada - National Science Library

    Pruefer, Donald

    2000-01-01

    .... In a microcosm of the shortsighted planning, reckless development and lack of ecological concern that epitomized the Soviet era, 70 decommissioned nuclear submarines are currently moored in ports...

  12. Purification of molybdenum

    International Nuclear Information System (INIS)

    Cheresnowsky, M.J.; Brunelli, T.A.; Kim, T.K.

    1987-01-01

    A method for purifying molybdenum is described comprising: (a) adding to an ammoniacal ammonium molybdate solution which is at a pH of from about 8.5 to about 11 and which contains the impurities of phosphorus and arsenic with the phosphorus concentration being from about 0.01 to about 0.12 g/l, a soluble magnesium salt to form a precipitate comprising magnesium ammonium salts of the phosphorus and the arsenic, and to form a purified ammonium molybdate solution, with the amount of the magnesium salt being added in an amount sufficient to result in a concentration of from about 0.005 to about 0.04 moles Mg/l in the ammoniacal ammonium molybdate solution, and the purified solution containing no greater than about 0.01 g P/l; (b) separating the precipitate from the purified ammonium molybdate solution; and (c) contacting the purified ammonium molybdate solution with a chelating cation exchange resin supplying a sufficient amount of ammonium as the cation to remove the major portion of the magnesium ions from the purified solution and form a further purified ammonium molybdate solution

  13. Death of the TonB Shuttle Hypothesis.

    Science.gov (United States)

    Gresock, Michael G; Savenkova, Marina I; Larsen, Ray A; Ollis, Anne A; Postle, Kathleen

    2011-01-01

    A complex of ExbB, ExbD, and TonB couples cytoplasmic membrane (CM) proton motive force (pmf) to the active transport of large, scarce, or important nutrients across the outer membrane (OM). TonB interacts with OM transporters to enable ligand transport. Several mechanical models and a shuttle model explain how TonB might work. In the mechanical models, TonB remains attached to the CM during energy transduction, while in the shuttle model the TonB N terminus leaves the CM to deliver conformationally stored potential energy to OM transporters. Previous studies suggested that TonB did not shuttle based on the activity of a GFP-TonB fusion that was anchored in the CM by the GFP moiety. When we recreated the GFP-TonB fusion to extend those studies, in our hands it was proteolytically unstable, giving rise to potentially shuttleable degradation products. Recently, we discovered that a fusion of the Vibrio cholerae ToxR cytoplasmic domain to the N terminus of TonB was proteolytically stable. ToxR-TonB was able to be completely converted into a proteinase K-resistant conformation in response to loss of pmf in spheroplasts and exhibited an ability to form a pmf-dependent formaldehyde crosslink to ExbD, both indicators of its location in the CM. Most importantly, ToxR-TonB had the same relative specific activity as wild-type TonB. Taken together, these results provide conclusive evidence that TonB does not shuttle during energy transduction. We had previously concluded that TonB shuttles based on the use of an Oregon Green(®) 488 maleimide probe to assess periplasmic accessibility of N-terminal TonB. Here we show that the probe was permeant to the CM, thus permitting the labeling of the TonB N-terminus. These former results are reinterpreted in the context that TonB does not shuttle, and suggest the existence of a signal transduction pathway from OM to cytoplasm.

  14. Nitrogen reduction: Molybdenum does it again

    Science.gov (United States)

    Schrock, Richard R.

    2011-02-01

    Nature reduces dinitrogen under mild conditions using nitrogenases, the most active of which contains molybdenum and iron. The only abiological dinitrogen reduction catalyst that avoids the harsh conditions of the Haber-Bosch process contains just molybdenum.

  15. Sneak Peek to the 2016 Billion-Ton Report

    Energy Technology Data Exchange (ETDEWEB)

    None

    2016-06-01

    The 2005 Billion-Ton Study became a landmark resource for bioenergy stakeholders, detailing for the first time the potential to produce at least one billion dry tons of biomass annually in a sustainable manner from U.S. agriculture and forest resources. The 2011 U.S. Billion-Ton Update expanded and updated the analysis, and in 2016, the U.S. Department of Energy’s Bioenergy Technologies Office plans to release the 2016 Billion-Ton Report: Advancing Domestic Resources for a Thriving Bioeconomy.

  16. Method of molybdenum kinetic determination

    International Nuclear Information System (INIS)

    Krejngol'd, S.U.; Dzotsenidze, N.E.; Ruseishviyai, T.G.; Nelen', I.M.

    1980-01-01

    The method molybdenum kinetic determination according to oxidation of pyrogallol with bromate in the medium of 0.05-0.15 M perchloric or sulphuric acids is presented. 1 mg of Ni, Co, Mn, Mg, Zn, Cr(3); 100 μg of Ca, Al, Cu, 10 μg of Cr(4), W; 10 μg of Fe in the presence of 22x10 - 4 M solution of EDTA, as well as 10 - 4 M solutions of chlorides and fluorides, 10 - 5 M solutions of bromides do not interfere with molybdenum determination using the given method. The method is rather simple, it takes 30 min to carry out the analysis. Determination limit of molybdenum constitutes 0.01 μg/ml

  17. Isotope analysis of molybdenum in selected minerals

    International Nuclear Information System (INIS)

    Becker, S.; Dietze, H.J.

    1980-01-01

    An analytical method is described for the mass spectrometric determination of molybdenum abundance values. The results of analyses of three molybdenum mineral samples are presented and compared with the results of other authors. It is shown that the fine variations of molybdenum in natural minerals cannot be analysed with currently available mass spectrometers

  18. Death of the TonB shuttle hypothesis

    Directory of Open Access Journals (Sweden)

    Michael George Gresock

    2011-10-01

    Full Text Available A complex of ExbB, ExbD, and TonB transduces cytoplasmic membrane (CM proton motive force (pmf to outer membrane (OM transporters so that large, scarce, and important nutrients can be released into the periplasmic space for subsequent transport across the CM. TonB is the component that interacts with the OM transporters and enables ligand transport, and several mechanical models and a shuttle model explain how TonB might work. In the mechanical models, TonB remains attached to the CM during energy transduction, while in the shuttle model the TonB N terminus leaves the CM to deliver conformationally stored potential energy to OM transporters. Previous efforts to test the shuttle model by anchoring TonB to the CM by fusion to a large globular cytoplasmic protein have been hampered by the proteolytic susceptibility of the fusion constructs. Here we confirm that GFP-TonB, tested in a previous study by another laboratory, again gave rise to full-length TonB and slightly larger potentially shuttleable fragments that prevented unambiguous interpretation of the data. Recently, we discovered that a fusion of the Vibrio cholerae ToxR cytoplasmic domain to the N terminus of TonB was proteolytically stable. ToxR-TonB was able to be completely converted into a proteinase K-resistant conformation in response to loss of pmf in spheroplasts and exhibited an ability to form a pmf-dependent formaldehyde crosslink to ExbD, both indicators of its location in the CM. Most importantly, ToxR-TonB had the same relative specific activity as wild-type TonB. Taken together, these results provide the first conclusive evidence that TonB does not shuttle during energy transduction. The interpretations of our previous study, which concluded that TonB shuttled in vivo, were complicated by the fact that the probe used in those studies, Oregon Green® 488 maleimide, was permeant to the CM and could label proteins, including a TonB ∆TMD derivative, confined exclusively to the

  19. Evaluation of molybdenum and its alloys

    International Nuclear Information System (INIS)

    Lundberg, L.B.

    1981-01-01

    The choice of pure molybdenum as the prime candidate material for space reactor core heat pipes is critically examined. Pure molybdenum's high ductile-brittle transition temperature appears to be its major disadvantage. The candidate materials examined in detail for this application include low carbon arc-cast molybdenum, TZM-molybdenum alloy, and molybdenum-rhenium alloys. Published engineering properties are collected and compared, and it appears that Mo-Re alloys with 10 to 15% rhenium offer the best combination. Hardware is presently being made from electron beam melted Mo-13Re to test this conclusion

  20. Gel Fabrication of Molybdenum “Beads”

    Energy Technology Data Exchange (ETDEWEB)

    Lowden, Richard Andrew [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division; Armstrong, Beth L. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division; Cooley, Kevin M. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division

    2016-11-01

    Spherical molybdenum particles or “beads” of various diameters are of interest as feedstock materials for the additive manufacture of targets and assemblies used in the production of 99Mo medical isotopes using accelerator technology. Small metallic beads or ball bearings are typically fabricated from wire; however, small molybdenum spheres cannot readily be produced in this manner. Sol-gel processes are often employed to produce small dense microspheres of metal oxides across a broad diameter range that in the case of molybdenum could be reduced and sintered to produce metallic spheres. These Sol-gel type processes were examined for forming molybdenum oxide beads; however, the molybdenum trioxide was chemically incompatible with commonly used gelation materials. As an alternative, an aqueous alginate process being assessed for the fabrication of oxide spheres for catalyst applications was employed to form molybdenum trioxide beads that were successfully reduced and sintered to produce small molybdenum spheres.

  1. HYDROGEN VACANCY INTERACTION IN MOLYBDENUM

    NARCIS (Netherlands)

    Abd El Keriem, M.S.; van der Werf, D.P.; Pleiter, F

    1993-01-01

    Vacancy-hydrogen interaction in molybdenum was investigated by means of the perturbed angular correlation technique, using the isotope In-111 as a probe. The complex InV2 turned out to trap up to two hydrogen atoms: trapping of a single hydrogen atom gives rise to a decrease of the quadrupole

  2. Metrics of quantum states

    International Nuclear Information System (INIS)

    Ma Zhihao; Chen Jingling

    2011-01-01

    In this work we study metrics of quantum states, which are natural generalizations of the usual trace metric and Bures metric. Some useful properties of the metrics are proved, such as the joint convexity and contractivity under quantum operations. Our result has a potential application in studying the geometry of quantum states as well as the entanglement detection.

  3. $\\eta$-metric structures

    OpenAIRE

    Gaba, Yaé Ulrich

    2017-01-01

    In this paper, we discuss recent results about generalized metric spaces and fixed point theory. We introduce the notion of $\\eta$-cone metric spaces, give some topological properties and prove some fixed point theorems for contractive type maps on these spaces. In particular we show that theses $\\eta$-cone metric spaces are natural generalizations of both cone metric spaces and metric type spaces.

  4. Response Surface Model (RSM)-based Benefit Per Ton Estimates

    Science.gov (United States)

    The tables below are updated versions of the tables appearing in The influence of location, source, and emission type in estimates of the human health benefits of reducing a ton of air pollution (Fann, Fulcher and Hubbell 2009).

  5. Summary and Comparison of the 2016 Billion-Ton Report with the 2011 U.S. Billion-Ton Update

    Energy Technology Data Exchange (ETDEWEB)

    None

    2016-06-01

    In terms of the magnitude of the resource potential, the results of the 2016 Billion-Ton Report (BT16) are consistent with the original 2005 Billion-Ton Study (BTS) and the 2011 report, U.S. Billion-Ton Update: Biomass Supply for a Bioenergy and Bioproducts Industry (BT2. An effort was made to reevaluate the potential forestland, agricultural, and waste resources at the roadside, then extend the analysis by adding transportation costs to a biorefinery under specified logistics assumptions to major resource fractions.

  6. Neutron scattering and models: molybdenum

    International Nuclear Information System (INIS)

    Smith, A.B.

    1999-01-01

    A comprehensive interpretation of the fast-neutron interaction with elemental and isotopic molybdenum at energies of le 30 MeV is given. New experimental elemental-scattering information over the incident energy range 4.5 r a rrow 10 MeV is presented. Spherical, vibrational and dispersive models are deduced and discussed, including isospin, energy-dependent and mass effects. The vibrational models are consistent with the ''Lane potential''. The importance of dispersion effects is noted. Dichotomies that exist in the literature are removed. The models are vehicles for fundamental physical investigations and for the provision of data for applied purposes. A ''regional'' molybdenum model is proposed. Finally, recommendations for future work are made

  7. 305 Building 2 ton bridge crane and monorail assembly analysis

    International Nuclear Information System (INIS)

    Axup, M.D.

    1995-12-01

    The analyses in the appendix of this document evaluate the integrity of the existing bridge crane structure, as depicted on drawing H-3-34292, for a bridge crane and monorail assembly with a load rating of 2 tons. This bridge crane and monorail assembly is a modification of a 1 1/2 ton rated manipulator bridge crane which originally existed in the 305 building

  8. CVD molybdenum films of high infrared reflectance

    Energy Technology Data Exchange (ETDEWEB)

    Carver, G. E.

    1979-01-01

    Molybdenum thin films of high infrared reflectance have been deposited by pyrolytic decomposition of molybdenum carbonyl (Mo(CO)/sub 6/), and by hydrogen reduction of molybdenum pentachloride (MoCl/sub 5/). Reflectance values within 0.7% of the reflectance of supersmooth bulk molybdenum have been attained by annealing films of lower reflectance in both reducing and non-reducing atmospheres. All depositions and anneals proceed at atmospheric pressure, facilitating a continuous, flow-through fabrication. These reflectors combine the high temperature stability of molybdenum thin films with the infrared reflectance of a material such as aluminum. Deposition from Mo(CO)/sub 6/ under oxidizing conditions, and subsequent anneal in a reducing atmosphere, results in films that combine high solar absorptance with low thermal emittance. If anti-reflected, black molybdenum films can serve as highly selective single layer photothermal converters. Structural, compositional, and crystallographic properties have been measured after both deposition and anneal.

  9. Carbon, chromium and molybdenum contents

    International Nuclear Information System (INIS)

    Sinatora, A; Goldenstein, H.; Mei, P.R.; Albertin, E.; Fuoco, R.; Mariotto, C.L.

    1992-01-01

    This work describes solidification experiments on white cast iron, with 15 and 20% of chromium, 2.3, 3.0 and 3.6 % of carbon and 0.0, 1.5 and 2.5 % of molybdenum in test de samples with 30 mm diameter. Measurements were performed on the austenite and eutectic formation arrests, the number of the eutectic carbide particles relative to the total and the eutectic volumes, and the volume fraction of the primary austenite

  10. Molybdenum: the element and aqueous solution chemistry

    International Nuclear Information System (INIS)

    Sykes, A.G.

    1987-01-01

    This chapter on the chemistry of the coordination compounds of molybdenum concentrates on the element itself, its recovery from ores and its use in the manufacture of steels. Most of the chapter is devoted to the aqueous solution chemistry of molybdenum in oxidation states II, III and IV. (UK)

  11. Investigation of pressing of molybdenum powder compacts

    International Nuclear Information System (INIS)

    Mymrin, S.A.; Kuznetsov, V.Eh.; Yampol'skij, M.L.; Leonov, S.A.; Mikhridinov, R.M.; Korzukhin, V.A.

    1990-01-01

    Results of an experimental investigation into pressing of compacts of MCh type molybdenum powders using the industrial equipment are presented. To measure the density of powder molybdenum billets a radioisotopic density meter with cesium-137 is used as radioactive gamma radiation source. The dependence of the produced billet density on the specific compacting pressure at different values of the powder bulk density is ascertained

  12. Extraction of molybdenum VI by alpha benzoinoxime

    International Nuclear Information System (INIS)

    Achache, M.; Meklati, M.

    1990-06-01

    The concentration of molybdenum, was studied using alpha benzoinoxime dissolved in chloroform. Several acids and salt at different levels of concentration were investigated as well as other parameters such as (mixing time, extractant to metal ratio, temperature etc.) The molybdenum stippling was also studied in alkaline medium with the subsequent recovery of the extractant and solvent

  13. Molybdenum sealing glass-ceramic composition

    International Nuclear Information System (INIS)

    Eagan, R.J.

    1976-01-01

    A glass-ceramic composition is described having low hydrogen and helium permeability properties, along with high fracture strength, and a thermal coefficient of expansion similar to that of molybdenum. The composition is adaptable for hermetically sealing to molybdenum at temperatures between 900 and about 950 0 C to form a hermetically sealed insulator body

  14. Materials for Molybdenum 99 purification

    International Nuclear Information System (INIS)

    Wilkinson, M. Victoria; Mondino, Angel V.; Manzini, Alberto C.

    2003-01-01

    The National Atomic Energy Commission (CNEA) produces fission Mo 99, an isotope of wide use in nuclear medicine. In order to simplify the current Mo 99 production process, to shorten its duration and reduce impurities in the final product, alternative methods for purification steps were looked for. In this work a variety of new materials for the purification columns were designed, all of them with carbon. These materials were studied and a material which contribute with the best results for molybdenum retention, was selected. The preparation procedure and the working conditions were determined. (author)

  15. Molybdenum Oxides - From Fundamentals to Functionality.

    Science.gov (United States)

    de Castro, Isabela Alves; Datta, Robi Shankar; Ou, Jian Zhen; Castellanos-Gomez, Andres; Sriram, Sharath; Daeneke, Torben; Kalantar-Zadeh, Kourosh

    2017-10-01

    The properties and applications of molybdenum oxides are reviewed in depth. Molybdenum is found in various oxide stoichiometries, which have been employed for different high-value research and commercial applications. The great chemical and physical characteristics of molybdenum oxides make them versatile and highly tunable for incorporation in optical, electronic, catalytic, bio, and energy systems. Variations in the oxidation states allow manipulation of the crystal structure, morphology, oxygen vacancies, and dopants, to control and engineer electronic states. Despite this overwhelming functionality and potential, a definitive resource on molybdenum oxide is still unavailable. The aim here is to provide such a resource, while presenting an insightful outlook into future prospective applications for molybdenum oxides. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  16. METRIC context unit architecture

    Energy Technology Data Exchange (ETDEWEB)

    Simpson, R.O.

    1988-01-01

    METRIC is an architecture for a simple but powerful Reduced Instruction Set Computer (RISC). Its speed comes from the simultaneous processing of several instruction streams, with instructions from the various streams being dispatched into METRIC's execution pipeline as they become available for execution. The pipeline is thus kept full, with a mix of instructions for several contexts in execution at the same time. True parallel programming is supported within a single execution unit, the METRIC Context Unit. METRIC's architecture provides for expansion through the addition of multiple Context Units and of specialized Functional Units. The architecture thus spans a range of size and performance from a single-chip microcomputer up through large and powerful multiprocessors. This research concentrates on the specification of the METRIC Context Unit at the architectural level. Performance tradeoffs made during METRIC's design are discussed, and projections of METRIC's performance are made based on simulation studies.

  17. Vapor deposition of molybdenum oxide using bis(ethylbenzene) molybdenum and water

    International Nuclear Information System (INIS)

    Drake, Tasha L.; Stair, Peter C.

    2016-01-01

    Three molybdenum precursors—bis(acetylacetonate) dioxomolybdenum, molybdenum isopropoxide, and bis(ethylbenzene) molybdenum—were tested for molybdenum oxide vapor deposition. Quartz crystal microbalance studies were performed to monitor growth. Molybdenum isopropoxide and bis(ethylbenzene) molybdenum achieved linear growth rates 0.01 and 0.08 Å/cycle, respectively, using atomic layer deposition techniques. Negligible MoO_x growth was observed on alumina powder using molybdenum isopropoxide, as determined by inductively coupled plasma optical emission spectroscopy. Bis(ethylbenzene) molybdenum achieved loadings of 0.5, 1.1, and 1.9 Mo/nm"2 on alumina powder after one, two, and five cycles, respectively, using atomic layer deposition techniques. The growth window for bis(ethylbenzene) molybdenum is 135–150 °C. An alternative pulsing strategy was also developed for bis(ethylbenzene) molybdenum that results in higher growth rates in less time compared to atomic layer deposition techniques. The outlined process serves as a methodology for depositing molybdenum oxide for catalytic applications. All as-deposited materials undergo further calcination prior to characterization and testing.

  18. Factory Acceptance Test Procedure Westinghouse 100 ton Hydraulic Trailer

    International Nuclear Information System (INIS)

    Aftanas, B.L.

    1994-01-01

    This Factory Acceptance Test Procedure (FAT) is for the Westinghouse 100 Ton Hydraulic Trailer. The trailer will be used for the removal of the 101-SY pump. This procedure includes: safety check and safety procedures; pre-operation check out; startup; leveling trailer; functional/proofload test; proofload testing; and rolling load test

  19. Evaluation of SinoRhizobium meliloti Efficiency and Qualitative Traits of Alfalfa under Application of Molybdenum

    Directory of Open Access Journals (Sweden)

    F Ahmadi Dana

    2017-12-01

    Full Text Available Introduction Agriculture depends heavily on nitrogen which is biologically fixed through the symbiotic association between rhizobia and legume plants in nodules located on plant roots. Alfalfa is a legume that should fix most of its own N requirement if it is sufficiently nodulated by viable Rhizobium meliloti inoculums. The process of nitrogen fixation is done by the help of an enzyme called nitrogenase and molybdenum which is an important element in the formation of this compound. Molybdenum is required by plants for protein synthesis and is especially important for legumes as it is needed for nitrogen fixation by rhizobia. Therefore the following research was done aimed on studying the effect of different amount of molybdenum and S. rhizobium bacteria on alfalfa’s yield. Material and Methods Alfalfa (Medicago sativa were grown in a field. The experiment was conducted at Karaj in 2013 in split plot arrangement based on completely randomized block design (RCBD, including 2 caring S. rhizobium inoculated seed and non-inoculated as the main plot factorand 3 levels of Molybdenum (0,5,10 kg ha-1 from ammonium molybdate (as the sub plot factor in three replications. Sinorhizobium meliloti bacteria were cultured on plates. Then half of the seeds were inoculated by Sinorhizobium meliloti. Nitrogen fertilizer was added only in one stage before planting up to 50 kg per hectare. Plants were grown until flowering. The data were analyzed by the SAS (9.1 software and mean comparisons were done by Duncan's MRT at the 1% and 5% probability level. Results and Discussion The results showed the effect of different levels of molybdenum and S. Rhizobium bacteria on dry matter yield, molybdenum concentrations in shoots and roots and the number of root nodules was significant. This treatment was significant in comparison to the control treatment with the14.27 ton per hectare. Increasing of molybdenum application, led to increasing of root nodules and showed a

  20. Metric diffusion along foliations

    CERN Document Server

    Walczak, Szymon M

    2017-01-01

    Up-to-date research in metric diffusion along compact foliations is presented in this book. Beginning with fundamentals from the optimal transportation theory and the theory of foliations; this book moves on to cover Wasserstein distance, Kantorovich Duality Theorem, and the metrization of the weak topology by the Wasserstein distance. Metric diffusion is defined, the topology of the metric space is studied and the limits of diffused metrics along compact foliations are discussed. Essentials on foliations, holonomy, heat diffusion, and compact foliations are detailed and vital technical lemmas are proved to aide understanding. Graduate students and researchers in geometry, topology and dynamics of foliations and laminations will find this supplement useful as it presents facts about the metric diffusion along non-compact foliation and provides a full description of the limit for metrics diffused along foliation with at least one compact leaf on the two dimensions.

  1. Metric modular spaces

    CERN Document Server

    Chistyakov, Vyacheslav

    2015-01-01

    Aimed toward researchers and graduate students familiar with elements of functional analysis, linear algebra, and general topology; this book contains a general study of modulars, modular spaces, and metric modular spaces. Modulars may be thought of as generalized velocity fields and serve two important purposes: generate metric spaces in a unified manner and provide a weaker convergence, the modular convergence, whose topology is non-metrizable in general. Metric modular spaces are extensions of metric spaces, metric linear spaces, and classical modular linear spaces. The topics covered include the classification of modulars, metrizability of modular spaces, modular transforms and duality between modular spaces, metric  and modular topologies. Applications illustrated in this book include: the description of superposition operators acting in modular spaces, the existence of regular selections of set-valued mappings, new interpretations of spaces of Lipschitzian and absolutely continuous mappings, the existe...

  2. Prognostic Performance Metrics

    Data.gov (United States)

    National Aeronautics and Space Administration — This chapter presents several performance metrics for offline evaluation of prognostics algorithms. A brief overview of different methods employed for performance...

  3. Overview of journal metrics

    Directory of Open Access Journals (Sweden)

    Kihong Kim

    2018-02-01

    Full Text Available Various kinds of metrics used for the quantitative evaluation of scholarly journals are reviewed. The impact factor and related metrics including the immediacy index and the aggregate impact factor, which are provided by the Journal Citation Reports, are explained in detail. The Eigenfactor score and the article influence score are also reviewed. In addition, journal metrics such as CiteScore, Source Normalized Impact per Paper, SCImago Journal Rank, h-index, and g-index are discussed. Limitations and problems that these metrics have are pointed out. We should be cautious to rely on those quantitative measures too much when we evaluate journals or researchers.

  4. molybdenum

    African Journals Online (AJOL)

    A [13]). However, the larger size leads to an enhanced Si-C bond length (1.868 A [13]) relative to that of the C-C bond (1.527 Á [13]). This leads to a net cancellation of effects. Consequently the data suggest that the SiMe, and 'Bu appear of similar size when viewed from the centroid of the substituted cyclopentadienyl ligand ...

  5. Brand metrics that matter

    NARCIS (Netherlands)

    Muntinga, D.; Bernritter, S.

    2017-01-01

    Het merk staat steeds meer centraal in de organisatie. Het is daarom essentieel om de gezondheid, prestaties en ontwikkelingen van het merk te meten. Het is echter een uitdaging om de juiste brand metrics te selecteren. Een enorme hoeveelheid metrics vraagt de aandacht van merkbeheerders. Maar welke

  6. Privacy Metrics and Boundaries

    NARCIS (Netherlands)

    L-F. Pau (Louis-François)

    2005-01-01

    textabstractThis paper aims at defining a set of privacy metrics (quantitative and qualitative) in the case of the relation between a privacy protector ,and an information gatherer .The aims with such metrics are: -to allow to assess and compare different user scenarios and their differences; for

  7. Features of soldering of molybdenum a lols

    International Nuclear Information System (INIS)

    Grishin, V.L.; Rybkin, B.V.; Cherkasov, A.F.

    1980-01-01

    Soldering features of complex-alloy molybdenum alloys were investigated in comparison with alloys based on solid solutions. Soldering features of heterogeneous molybdenum base alloys were investigated using samples of 0.5-1.O mm sheets with the strain of about 95% made of ingots which had been smelted in arc vacuum furnaces. The soldering of samples was carried out in 5x1O -5 mm Hg vacuum using different sources of heating: radiation, electron-ray and contact. It was shown that heat-resisting soldered joints of heterogeneous molybdenum alloys could be produced using zirconium and niobium base solders containing the most effective hardeners of the parent material (titanum, vanadium, tantalum, molybdenum, tungsten). To preserve high mechanical properties of heterogeneous alloys it was expedient to use for welding local heating sources which permitted to decrease considerably temperature- time conditions of the process

  8. Recovery of molybdenum in froth flotation

    International Nuclear Information System (INIS)

    Parlman, R.M.; Bresson, C.R.

    1981-01-01

    Beta-mercaptoethanol has been found to be an effective suppressant for such minerals as copper, iron and lead in a molybdenum sulfide ore froth flotation operation. The recovery process and a suppressant utilizing said compound are claimed

  9. Large-Batch Reduction of Molybdenum Trioxide

    Energy Technology Data Exchange (ETDEWEB)

    Kiggans, Jr, James O. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Lowden, Richard Andrew [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Menchhofer, Paul A. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Nunn, Stephen D. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Bryan, Chris [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

    2015-12-01

    Unconverted, isotopically-enriched molybdenum metal must be recovered from the spent radiopharmaceutical solution used in NorthStar’s Technetium-99m generator and reused. The recycle process begins by recovering the metal from the aqueous potassium molybdate (K2MoO4) solutions as molybdenum trioxide (MoO3) employing a process developed at Argonne National Laboratory. The MoO3 powder is subsequently reduced to molybdenum metal powder which can be blended with new powder and further processed into a flowable form to be used to produce target disks for irradiation. The molybdenum oxide reduction process has been examined and scaled to produce kilogram quantities of metal powder suitable for processing into a useable form employing spray drying or similar technique and ultimately used for target fabrication.

  10. Molybdenum (6) determination by the method of high-frequency and pH titration

    International Nuclear Information System (INIS)

    Lukianets, I.G.; Kulish, N.G.

    1981-01-01

    A possibility to determine Mo(6) using the method of high frequency and pH-metric titration is investigated. By means of the high frequency contact R-cell Mo(6) titration is performed using different precipitators: 8-oxiquinoline, lead nitrate and acetate and silver nitrate. It is established that the best conditions are achieved during titration of 67.2-1343 mg/10 ml Mo(6) with lead acetate (pH 4.5-6.5). Relative standard deviation Ssub(r) constitutes 0.005 pH-metric titration of Mo(6) with complexone 3 is studied. The range of Mo(6) concentrations determined constitutes 13.43-134.3 mg at pH initial value of 3.5-5.5. Relative standard deviation Ssub(r) constitutes 0.003. Techniques of molybdenum determination in ferromolybdenum using the method of high frequency and pH-metric titration are developed [ru

  11. Molybdenum solubility in aluminium nitrate solutions

    Energy Technology Data Exchange (ETDEWEB)

    Heres, X.; Sans, D.; Bertrand, M.; Eysseric, C. [CEA, Centre de Marcoule, Nuclear Energy Division, DRCP, BP 17171, 30207 Bagnols-sur-Ceze Cedex (France); Brackx, E.; Domenger, R.; Excoffier, E. [CEA, Centre de Marcoule, Nuclear Energy Division, DTEC, BP 17171, 30207 Bagnols-sur-Ceze Cedex (France); Valery, J.F. [AREVA-NC, DOR/RDP, Paris - La Defense (France)

    2016-07-01

    For over 60 years, research reactors (RR or RTR for research testing reactors) have been used as neutron sources for research, radioisotope production ({sup 99}Mo/{sup 99m}Tc), nuclear medicine, materials characterization, etc... Currently, over 240 of these reactors are in operation in 56 countries. They are simpler than power reactors and operate at lower temperature (cooled to below 100 C. degrees). The fuel assemblies are typically plates or cylinders of uranium alloy and aluminium (U-Al) coated with pure aluminium. These fuels can be processed in AREVA La Hague plant after batch dissolution in concentrated nitric acid and mixing with UOX fuel streams. The aim of this study is to accurately measure the solubility of molybdenum in nitric acid solution containing high concentrations of aluminium. The higher the molybdenum solubility is, the more flexible reprocessing operations are, especially when the spent fuels contain high amounts of molybdenum. To be most representative of the dissolution process, uranium-molybdenum alloy and molybdenum metal powder were dissolved in solutions of aluminium nitrate at the nominal dissolution temperature. The experiments showed complete dissolution of metallic elements after 30 minutes long stirring, even if molybdenum metal was added in excess. After an induction period, a slow precipitation of molybdic acid occurs for about 15 hours. The data obtained show the molybdenum solubility decreases with increasing aluminium concentration. The solubility law follows an exponential relation around 40 g/L of aluminium with a high determination coefficient. Molybdenum solubility is not impacted by the presence of gadolinium, or by an increasing concentration of uranium. (authors)

  12. Elimination of excess molybdenum by cattle

    Energy Technology Data Exchange (ETDEWEB)

    Toelgyesi, G.; Elmoty, I.A.

    1967-01-01

    It was found that cattle would ingest spontaneously 5-15 g of molybdenum on one occasion. The uptake of this quantity caused but moderate loss of appetite and mild enteritis, both normalizing in one week. The occurrence of a severe acute molybdenum poisoning can be practically excluded, owing to refusal of the poisoned feed. Spontaneously ingested molybdenum caused on the first day a 30-100 fold rise of ruminal Mo-level, decreasing to the order of the normal value in about one week. But in the urine and faeces, Mo-level was at least 10 fold, in the blood and milk about 4 fold of the normal one, even one or two weeks after ingestion. During this period at least 90% of ingested Mo was eliminated with the faeces, urine and milk. One week after the ingestion of molybdenum, the rumen content showed no evidence on poisoning and no trace of molybdenum. Oral administration of ammonium molybdenate in an amount equivalent to 40 g molybdenum caused no fatality. In fact, cattle would never ingest spontaneously such a large dose.

  13. Method of producing oxidation resistant coatings for molybdenum

    International Nuclear Information System (INIS)

    Timmons, G.A.

    1989-01-01

    A method is described for producing a molybdenum element having adherently bonded thereto a thermally self-healing plasma-sprayed coating consisting essentially of a composite of molybdenum and a refactory oxide material capable of reacting with molybdenum oxide under oxidizing conditions to form a substantially thermally stable refractory compound of molybdenum, the method comprising plasma-spraying a coating formed by the step-wise application of a plurality of interbonded plasma-sprayed layers of a composite of molybdenum/refractory oxide material produced from a particulate mixture thereof. The coating comprises a first layer of molybdenum plasma-sprayed bonded to the substrate of the molybdenum element, a second layer of plasma-sprayed mixture of particulate molybdenum/refactory oxide consisting essentially of predominantly molybdenum bonded to the first layer, and succeeding layers of this mixture. The next step is heating the coated molybdenum element under oxidizing conditions to an elevated temperature sufficient to cause oxygen to diffuse into the surface of the multi-layered coating to react with dispersed molybdenum therein to form molybdenum oxide and effect healing of the coating by reaction of the molybdenum oxide with the contained refractory oxide and thereby protect the substrate of the molybdenum element against oxidation

  14. Holographic Spherically Symmetric Metrics

    Science.gov (United States)

    Petri, Michael

    The holographic principle (HP) conjectures, that the maximum number of degrees of freedom of any realistic physical system is proportional to the system's boundary area. The HP has its roots in the study of black holes. It has recently been applied to cosmological solutions. In this article we apply the HP to spherically symmetric static space-times. We find that any regular spherically symmetric object saturating the HP is subject to tight constraints on the (interior) metric, energy-density, temperature and entropy-density. Whenever gravity can be described by a metric theory, gravity is macroscopically scale invariant and the laws of thermodynamics hold locally and globally, the (interior) metric of a regular holographic object is uniquely determined up to a constant factor and the interior matter-state must follow well defined scaling relations. When the metric theory of gravity is general relativity, the interior matter has an overall string equation of state (EOS) and a unique total energy-density. Thus the holographic metric derived in this article can serve as simple interior 4D realization of Mathur's string fuzzball proposal. Some properties of the holographic metric and its possible experimental verification are discussed. The geodesics of the holographic metric describe an isotropically expanding (or contracting) universe with a nearly homogeneous matter-distribution within the local Hubble volume. Due to the overall string EOS the active gravitational mass-density is zero, resulting in a coasting expansion with Ht = 1, which is compatible with the recent GRB-data.

  15. Determination of molybdenum by the gravimetric plumbate method (with the molybdenum content from 50 % and above)

    International Nuclear Information System (INIS)

    Stepin, V.V.; Kurbatova, V.I.; Fedorova, N.D.

    1980-01-01

    A gravimetric method of molybdenum determination in ferromolybdenum (Mo content from 50% and higher) after its dissolving in HNO 3 is developed. The method is based on Mo deposition in acetic acid solution in the form of molybdenum oxide lead after separation of Fe and other interfering elements with sodium hydroxide [ru

  16. Rapid analysis of molybdenum contents in molybdenum master alloys by X-ray fluorescence technique

    International Nuclear Information System (INIS)

    Tongkong, P.

    1985-01-01

    Determination of molybdenum contents in molybdenum master alloy had been performed using energy dispersive x-ray fluorescence (EDX) technique where analysis were made via standard additions and calibration curves. Comparison of EDX technique with other analyzing techniques, i.e., wavelength dispersive x-ray fluorescence, neutron activation analysis and inductive coupled plasma spectrometry, showed consistency in the results. This technique was found to yield reliable results when molybdenum contents in master alloys were in the range of 13 to 50 percent using HPGe detector or proportional counter. When the required error was set at 1%, the minimum analyzing time was found to be 30 and 60 seconds for Fe-Mo master alloys with molybdenum content of 13.54 and 49.09 percent respectively. For Al-Mo master alloys, the minimum times required were 120 and 300 seconds with molybdenum content of 15.22 and 47.26 percent respectively

  17. Molybdenum reduction to molybdenum blue in Serratia sp. Strain DRY5 is catalyzed by a novel molybdenum-reducing enzyme.

    Science.gov (United States)

    Shukor, M Y; Halmi, M I E; Rahman, M F A; Shamaan, N A; Syed, M A

    2014-01-01

    The first purification of the Mo-reducing enzyme from Serratia sp. strain DRY5 that is responsible for molybdenum reduction to molybdenum blue in the bacterium is reported. The monomeric enzyme has an apparent molecular weight of 105 kDalton. The isoelectric point of this enzyme was 7.55. The enzyme has an optimum pH of 6.0 and maximum activity between 25 and 35°C. The Mo-reducing enzyme was extremely sensitive to temperatures above 50°C (between 54 and 70°C). A plot of initial rates against substrate concentrations at 15 mM 12-MP registered a V max for NADH at 12.0 nmole Mo blue/min/mg protein. The apparent K m for NADH was 0.79 mM. At 5 mM NADH, the apparent V max and apparent K m values for 12-MP of 12.05 nmole/min/mg protein and 3.87 mM, respectively, were obtained. The catalytic efficiency (k cat/K m ) of the Mo-reducing enzyme was 5.47 M(-1) s(-1). The purification of this enzyme could probably help to solve the phenomenon of molybdenum reduction to molybdenum blue first reported in 1896 and would be useful for the understanding of the underlying mechanism in molybdenum bioremediation involving bioreduction.

  18. Molybdenum Reduction to Molybdenum Blue in Serratia sp. Strain DRY5 Is Catalyzed by a Novel Molybdenum-Reducing Enzyme

    Directory of Open Access Journals (Sweden)

    M. Y. Shukor

    2014-01-01

    Full Text Available The first purification of the Mo-reducing enzyme from Serratia sp. strain DRY5 that is responsible for molybdenum reduction to molybdenum blue in the bacterium is reported. The monomeric enzyme has an apparent molecular weight of 105 kDalton. The isoelectric point of this enzyme was 7.55. The enzyme has an optimum pH of 6.0 and maximum activity between 25 and 35°C. The Mo-reducing enzyme was extremely sensitive to temperatures above 50°C (between 54 and 70°C. A plot of initial rates against substrate concentrations at 15 mM 12-MP registered a Vmax for NADH at 12.0 nmole Mo blue/min/mg protein. The apparent Km for NADH was 0.79 mM. At 5 mM NADH, the apparent Vmax and apparent Km values for 12-MP of 12.05 nmole/min/mg protein and 3.87 mM, respectively, were obtained. The catalytic efficiency (kcat/Km of the Mo-reducing enzyme was 5.47 M-1 s-1. The purification of this enzyme could probably help to solve the phenomenon of molybdenum reduction to molybdenum blue first reported in 1896 and would be useful for the understanding of the underlying mechanism in molybdenum bioremediation involving bioreduction.

  19. Probabilistic metric spaces

    CERN Document Server

    Schweizer, B

    2005-01-01

    Topics include special classes of probabilistic metric spaces, topologies, and several related structures, such as probabilistic normed and inner-product spaces. 1983 edition, updated with 3 new appendixes. Includes 17 illustrations.

  20. Tracker Performance Metric

    National Research Council Canada - National Science Library

    Olson, Teresa; Lee, Harry; Sanders, Johnnie

    2002-01-01

    .... We have developed the Tracker Performance Metric (TPM) specifically for this purpose. It was designed to measure the output performance, on a frame-by-frame basis, using its output position and quality...

  1. IT Project Management Metrics

    Directory of Open Access Journals (Sweden)

    2007-01-01

    Full Text Available Many software and IT projects fail in completing theirs objectives because different causes of which the management of the projects has a high weight. In order to have successfully projects, lessons learned have to be used, historical data to be collected and metrics and indicators have to be computed and used to compare them with past projects and avoid failure to happen. This paper presents some metrics that can be used for the IT project management.

  2. Mass Customization Measurements Metrics

    DEFF Research Database (Denmark)

    Nielsen, Kjeld; Brunø, Thomas Ditlev; Jørgensen, Kaj Asbjørn

    2014-01-01

    A recent survey has indicated that 17 % of companies have ceased mass customizing less than 1 year after initiating the effort. This paper presents measurement for a company’s mass customization performance, utilizing metrics within the three fundamental capabilities: robust process design, choice...... navigation, and solution space development. A mass customizer when assessing performance with these metrics can identify within which areas improvement would increase competitiveness the most and enable more efficient transition to mass customization....

  3. Responsible for 45 000 tons CO2 emissions

    International Nuclear Information System (INIS)

    Nedrelid, Ola N.

    2006-01-01

    Waste combustion has much better tax conditions in Sweden compared to Norway. Today waste is being transported from Norway to Sweden, resulting in a 45 000 ton emission of CO 2 every year, when the waste could have remained in Norway, utilized as regained energy in district heating. The tax regime, however, does not provide the conditions for a profitable use of the waste in Norway. The district heating association is disappointed with the new government's proposed fiscal budget, which only worsens the competitive situation for Norway handling its own waste (ml)

  4. Acceptance test report for the Westinghouse 100 ton hydraulic trailer

    International Nuclear Information System (INIS)

    Barrett, R.A.

    1995-01-01

    The SY-101 Equipment Removal System 100 Ton Hydraulic Trailer was designed and built by KAMP Systems, Inc. Performance of the Acceptance Test Procedure at KAMP's facility in Ontario, California (termed Phase 1 in this report) was interrupted by discrepancies noted with the main hydraulic cylinder. The main cylinder was removed and sent to REMCO for repair while the trailer was sent to Lampson's facility in Pasco, Washington. The Acceptance Test Procedure was modified and performance resumed at Lampson (termed Phase 2 in this report) after receipt of the repaired cylinder. At the successful conclusion of Phase 2 testing the trailer was accepted as meeting all the performance criteria specified

  5. Preparation of selective molybdenum concentrate from collective coppermolybdenum concentrate

    Directory of Open Access Journals (Sweden)

    N. Tusupbaev

    2016-06-01

    Full Text Available The paper considers possibilities of selective separation of the concentrate of copper and molybdenum from a collective copper-molybdenum concentrate of Aktogay deposit using regrinding and conventional flotation reagents. In the case of conventional flotoreagents, the content of molybdenum in a molybdenum concentrate was 8.0% at extraction effectiveness 83.12%. At 27.96% extraction degree of copper, it’s content in the concentrate equaled to 21.3%. After regrinding, molybdenum content in the concentrate was 24.0% at the extraction effectiveness 59.63%, and copper content in the concentrate was 21.9% at the recovery of 61.23%. Thus, the regrinding of a collective copper-molybdenum concentrate resulted in an increase in the content of molybdenum in molybdenum concentrate by 16%, and the copper concentration increased by 0.6%.

  6. Dilution Refrigeration of Multi-Ton Cold Masses

    CERN Document Server

    Wikus, P; CERN. Geneva

    2007-01-01

    Dilution refrigeration is the only means to provide continuous cooling at temperatures below 250 mK. Future experiments featuring multi-ton cold masses require a new generation of dilution refrigeration systems, capable of providing a heat sink below 10 mK at cooling powers which exceed the performance of present systems considerably. This thesis presents some advances towards dilution refrigeration of multi-ton masses in this temperature range. A new method using numerical simulation to predict the cooling power of a dilution refrigerator of a given design has been developed in the framework of this thesis project. This method does not only allow to take into account the differences between an actual and an ideal continuous heat exchanger, but also to quantify the impact of an additional heat load on an intermediate section of the dilute stream. In addition, transient behavior can be simulated. The numerical model has been experimentally verified with a dilution refrigeration system which has been designed, ...

  7. Bibliographic study on molybdenum biokinetics. Literaturstudie zur Biokinetik von Molybdaen

    Energy Technology Data Exchange (ETDEWEB)

    Erzberger, A.

    1988-05-01

    This bibliographical study compiles and analyzes findings about the metabolism and resorption of molybdenum. Besides including studies on the physiology of molybdenum 99, a general survey is given on molybdenum in the environment and on its physiological behaviour. In particular, information on the dependence of molybdenum resorption on various factors, such as the chemical form, antagonisms etc., are gathered from literature. These factors have to be considered for sensibly carrying out necessary experiments.

  8. The XUV spectra of highly ionised molybdenum

    International Nuclear Information System (INIS)

    Mansfield, M.W.D.; Peacock, N.J.; Smith, C.C.; Hobby, M.G.; Cowan, R.D.

    1978-01-01

    The spectra of molybdenum ions produced in Tokamaks in the wavelength range 10-200 A have been reproduced in a plasma formed by laser beam irradiation of solid molybdenum targets. Lines from highly ionised stages of molybdenum (Mo XXX to Mo XXXII) have been distinguished by varying the laser beam intensity. Detailed analyses of the simpler ions, Mo XV (Ni-like), Mo XVI (Co-like), Mo XXXII (Na-like), and to a lesser extent Mo XXXI (Mg-like) and Mo XVII (Fe-like), have been achieved by comparison with ab initio calculations. A general interpretation of intermediate ion stages is also given but it is shown that most of these spectra are so complex, as a result of inner-subshell excitation, that detailed term-scheme analyses are nearly impossible. (author)

  9. XUV spectra of highly ionised molybdenum

    Energy Technology Data Exchange (ETDEWEB)

    Mansfield, M W.D.; Peacock, N J; Smith, C C; Hobby, M G [UKAEA, Abingdon. Culham Lab.; Cowan, R D

    1978-05-14

    The spectra of molybdenum ions produced in Tokamaks in the wavelength range 10-200 A have been reproduced in a plasma formed by laser beam irradiation of solid molybdenum targets. Lines from highly ionised stages of molybdenum (Mo XXX to Mo XXXII) have been distinguished by varying the laser beam intensity. Detailed analyses of the simpler ions, Mo XV (Ni-like), Mo XVI (Co-like), Mo XXXII (Na-like), and to a lesser extent Mo XXXI (Mg-like) and Mo XVII (Fe-like), have been achieved by comparison with ab initio calculations. A general interpretation of intermediate ion stages is also given but it is shown that most of these spectra are so complex, as a result of inner-subshell excitation, that detailed term-scheme analyses are nearly impossible.

  10. Molybdenum peroxo complex. Structure and thermal behavior

    Energy Technology Data Exchange (ETDEWEB)

    Segawa, Koichi; Ooga, Katsumi; Kurusu, Yasuhiko

    1984-10-01

    The molybdenum peroxide (Mo-y) prepared by oxidation of molybdenum metal with hydrogen peroxide has been studied to determine its structure and thermal behavior. Temperature programmed decomposition has been used to study the thermal stability of Mo-y. Two distinct peaks, I and II, of decomposition processes are discernible in Mo-y. Peak I corresponds to the elimination of water of crystallization and peak II to the decomposition of a peroxide ion of Mo-y. IR and UV examinations support the results of the thermal analysis. The IR band at 931 cm/sup -1/ and the UV band at 381 nm show the same thermal behavior. Both bands are attributable to the peroxide ion of Mo-y. Spectroscopic studies show that Mo-y has the tetrahedral coordination derived from the single molybdenum complex, which has double bond oxygens attached to Mo atom and has a symmetric type of peroxide ion with one water of crystallization.

  11. Separation and selective determination of molybdenum with sodiumthiosulfate and ethylacetate

    International Nuclear Information System (INIS)

    Hainberger, L.; de Oliveira Andrade, W.

    1982-01-01

    A sensitive and selective method of spectrophotometric determination of molybdenum is described. Molybdenum is extracted to more than 97%. Lambert-Beer's law is obeyed between 0.35 and 30μg/10ml of the used aqueous solution. 43 ions concerning their interference are studied. The method was used to determine the content of molybdenum in black beans. (Author)

  12. Recovery of uranium and molybdenum from a carbonate type uranium-molybdenum ore

    International Nuclear Information System (INIS)

    Zhou Genmao; Zeng Yijun; Tang Baobin; Meng Shu; Xu Guolong

    2014-01-01

    Based on the results of process mineralogical research of a carbonate type uranium-molybdenum ore, leaching behaviors of the uranium-molybdenum ore were studied by alkali agitation leaching, conventional alkali column leaching and alkali curing column leaching processes. The results showed that using the alkali curing column leaching process, the leaching rate of molybdenum increased to more than 90%, and the leaching rate of uranium was about 85%, Compared with the conventional alkali column leaching process, the leaching time of the alkali curing column leaching process decreased by 60 days. (authors)

  13. Fault Management Metrics

    Science.gov (United States)

    Johnson, Stephen B.; Ghoshal, Sudipto; Haste, Deepak; Moore, Craig

    2017-01-01

    This paper describes the theory and considerations in the application of metrics to measure the effectiveness of fault management. Fault management refers here to the operational aspect of system health management, and as such is considered as a meta-control loop that operates to preserve or maximize the system's ability to achieve its goals in the face of current or prospective failure. As a suite of control loops, the metrics to estimate and measure the effectiveness of fault management are similar to those of classical control loops in being divided into two major classes: state estimation, and state control. State estimation metrics can be classified into lower-level subdivisions for detection coverage, detection effectiveness, fault isolation and fault identification (diagnostics), and failure prognosis. State control metrics can be classified into response determination effectiveness and response effectiveness. These metrics are applied to each and every fault management control loop in the system, for each failure to which they apply, and probabilistically summed to determine the effectiveness of these fault management control loops to preserve the relevant system goals that they are intended to protect.

  14. Deep Transfer Metric Learning.

    Science.gov (United States)

    Junlin Hu; Jiwen Lu; Yap-Peng Tan; Jie Zhou

    2016-12-01

    Conventional metric learning methods usually assume that the training and test samples are captured in similar scenarios so that their distributions are assumed to be the same. This assumption does not hold in many real visual recognition applications, especially when samples are captured across different data sets. In this paper, we propose a new deep transfer metric learning (DTML) method to learn a set of hierarchical nonlinear transformations for cross-domain visual recognition by transferring discriminative knowledge from the labeled source domain to the unlabeled target domain. Specifically, our DTML learns a deep metric network by maximizing the inter-class variations and minimizing the intra-class variations, and minimizing the distribution divergence between the source domain and the target domain at the top layer of the network. To better exploit the discriminative information from the source domain, we further develop a deeply supervised transfer metric learning (DSTML) method by including an additional objective on DTML, where the output of both the hidden layers and the top layer are optimized jointly. To preserve the local manifold of input data points in the metric space, we present two new methods, DTML with autoencoder regularization and DSTML with autoencoder regularization. Experimental results on face verification, person re-identification, and handwritten digit recognition validate the effectiveness of the proposed methods.

  15. Spectrographic analysis of uranium-molybdenum alloys

    International Nuclear Information System (INIS)

    Roca, M.

    1967-01-01

    A spectrographic method of analysis has been developed for uranium-molybdenum alloys containing up to 10 % Mo. The carrier distillation technique, with gallium oxide and graphite as carriers, is used for the semiquantitative determination of Al, Cr, Fe, Ni and Si, involving the conversion of the samples into oxides. As a consequence of the study of the influence of the molybdenum on the line intensities, it is useful to prepare only one set of standards with 0,6 % MoO 3 . Total burning excitation is used for calcium, employing two sets of standards with 0,6 and 7.5 MoO 3 . (Author) 5 refs

  16. Increase of alcohol yield per ton of pulp

    Energy Technology Data Exchange (ETDEWEB)

    Sokolov, B N

    1957-01-01

    Digestion processes of cellulose were studied under production conditions. When the digestion was carried out with acid having 5.2% total SO/sub 2/ and 0.92% CaO, the concentration of total sugars in the spent liquor was 1.8 to 2.5%. When the acidity was reduced to 4.8% total SO/sub 2/ and 0.82% CaO, all other conditions being the same, the sugar concentration in the spent liquor increased to 3.0 to 3.7%. The importance of the acid strength and CaO content of the cooking liquor was further demonstrated at the end of 1955. At that time the total SO/sub 2/ in the acid rose to 8% while the amount of CaO remained practically the same-0.85 to 0.90%. These conditions permitted an increase in the amount of ships by 25 to 30%, which further changed the ratio CaO: wood and created conditions favorable for an improved yield of sugar. The increase in the activity of the acid was reflected favorably in the degree of hydrolysis of the hemicelluloses and in the degree to which the oligosaccharides or polysaccharides were hydrolyzed to simple sugars. At that time the yield of alcohol reached 53 1/ton of unbleached pulp. The process was further improved in 1956 by the use of successive washings; at the end of the digestion period the concentrated spent liquor was piped to the alcohol unit. The yield of alcohol reached 59.4 1/ton of pulp. Sugar recovery from the tank was 92.5% of that theoretically possible. Further improvements resulted by saturating the wood chips with acid under variable pressures. As a result, the base of the cooking acid was reduced to 0.7 to 0.72% and, at the end of the process the liquor contained 0.03 to 0.06% CaO instead of 0.2 to 0.18%. The alcohol yield/ton of pulp then rose to 66.8 l.

  17. Cyber threat metrics.

    Energy Technology Data Exchange (ETDEWEB)

    Frye, Jason Neal; Veitch, Cynthia K.; Mateski, Mark Elliot; Michalski, John T.; Harris, James Mark; Trevino, Cassandra M.; Maruoka, Scott

    2012-03-01

    Threats are generally much easier to list than to describe, and much easier to describe than to measure. As a result, many organizations list threats. Fewer describe them in useful terms, and still fewer measure them in meaningful ways. This is particularly true in the dynamic and nebulous domain of cyber threats - a domain that tends to resist easy measurement and, in some cases, appears to defy any measurement. We believe the problem is tractable. In this report we describe threat metrics and models for characterizing threats consistently and unambiguously. The purpose of this report is to support the Operational Threat Assessment (OTA) phase of risk and vulnerability assessment. To this end, we focus on the task of characterizing cyber threats using consistent threat metrics and models. In particular, we address threat metrics and models for describing malicious cyber threats to US FCEB agencies and systems.

  18. Adaptive metric kernel regression

    DEFF Research Database (Denmark)

    Goutte, Cyril; Larsen, Jan

    2000-01-01

    Kernel smoothing is a widely used non-parametric pattern recognition technique. By nature, it suffers from the curse of dimensionality and is usually difficult to apply to high input dimensions. In this contribution, we propose an algorithm that adapts the input metric used in multivariate...... regression by minimising a cross-validation estimate of the generalisation error. This allows to automatically adjust the importance of different dimensions. The improvement in terms of modelling performance is illustrated on a variable selection task where the adaptive metric kernel clearly outperforms...

  19. Adaptive Metric Kernel Regression

    DEFF Research Database (Denmark)

    Goutte, Cyril; Larsen, Jan

    1998-01-01

    Kernel smoothing is a widely used nonparametric pattern recognition technique. By nature, it suffers from the curse of dimensionality and is usually difficult to apply to high input dimensions. In this paper, we propose an algorithm that adapts the input metric used in multivariate regression...... by minimising a cross-validation estimate of the generalisation error. This allows one to automatically adjust the importance of different dimensions. The improvement in terms of modelling performance is illustrated on a variable selection task where the adaptive metric kernel clearly outperforms the standard...

  20. Matrix model and time-like linear dila ton matter

    International Nuclear Information System (INIS)

    Takayanagi, Tadashi

    2004-01-01

    We consider a matrix model description of the 2d string theory whose matter part is given by a time-like linear dilaton CFT. This is equivalent to the c=1 matrix model with a deformed, but very simple Fermi surface. Indeed, after a Lorentz transformation, the corresponding 2d spacetime is a conventional linear dila ton background with a time-dependent tachyon field. We show that the tree level scattering amplitudes in the matrix model perfectly agree with those computed in the world-sheet theory. The classical trajectories of fermions correspond to the decaying D-boranes in the time-like linear dilaton CFT. We also discuss the ground ring structure. Furthermore, we study the properties of the time-like Liouville theory by applying this matrix model description. We find that its ground ring structure is very similar to that of the minimal string. (author)

  1. Acceptance test report for the Westinghouse 100 ton hydraulic trailer

    Energy Technology Data Exchange (ETDEWEB)

    Barrett, R.A.

    1995-03-06

    The SY-101 Equipment Removal System 100 Ton Hydraulic Trailer was designed and built by KAMP Systems, Inc. Performance of the Acceptance Test Procedure at KAMP`s facility in Ontario, California (termed Phase 1 in this report) was interrupted by discrepancies noted with the main hydraulic cylinder. The main cylinder was removed and sent to REMCO for repair while the trailer was sent to Lampson`s facility in Pasco, Washington. The Acceptance Test Procedure was modified and performance resumed at Lampson (termed Phase 2 in this report) after receipt of the repaired cylinder. At the successful conclusion of Phase 2 testing the trailer was accepted as meeting all the performance criteria specified.

  2. Ants at Ton Nga Chang Wildlife Sanctuary, Songkhla

    Directory of Open Access Journals (Sweden)

    Watanasit, S.

    2005-03-01

    Full Text Available The aim of this study was to investigate diversity of ant at Ton Nga Chang Wildlife Sanctuary, Hat Yai, Songkhla. Three line transects (100 m each were randomly set up in 2 types of forest area, disturbed and undisturbed. Hand collecting (HC and leaf litter sampling (LL were applied for ant collection within a time limit of 30 minutes for each method. This study was carried out every month during Febuary 2002- Febuary 2003. The results showed that 206 species were placed under 8 subfamilies: Aenictinae, Cerapachyinae, Dolichoderinae, Formicinae, Leptanillinae, Myrmicinae, Ponerinae and Pseudomyrmecinae. Study sites and collection methods could divide ant species into 2 groups, whereas seasonal change could not distinguish the groups by DCA of multivariate analysis.

  3. Dark matter sensitivity of multi-ton liquid xenon detectors

    International Nuclear Information System (INIS)

    Schumann, Marc; Bütikofer, Lukas; Baudis, Laura; Kish, Alexander; Selvi, Marco

    2015-01-01

    We study the sensitivity of multi ton-scale time projection chambers using a liquid xenon target, e.g., the proposed DARWIN instrument, to spin-independent and spin-dependent WIMP-nucleon scattering interactions. Taking into account realistic backgrounds from the detector itself as well as from neutrinos, we examine the impact of exposure, energy threshold, background rejection efficiency and energy resolution on the dark matter sensitivity. With an exposure of 200 t × y and assuming detector parameters which have been already demonstrated experimentally, spin-independent cross sections as low as 2.5 × 10 −49 cm 2 can be probed for WIMP masses around 40 GeV/c 2 . Additional improvements in terms of background rejection and exposure will further increase the sensitivity, while the ultimate WIMP science reach will be limited by neutrinos scattering coherently off the xenon nuclei

  4. Metrical Phonology and SLA.

    Science.gov (United States)

    Tice, Bradley S.

    Metrical phonology, a linguistic process of phonological stress assessment and diagrammatic simplification of sentence and word stress, is discussed as it is found in the English language with the intention that it may be used in second language instruction. Stress is defined by its physical and acoustical correlates, and the principles of…

  5. Engineering performance metrics

    Science.gov (United States)

    Delozier, R.; Snyder, N.

    1993-03-01

    Implementation of a Total Quality Management (TQM) approach to engineering work required the development of a system of metrics which would serve as a meaningful management tool for evaluating effectiveness in accomplishing project objectives and in achieving improved customer satisfaction. A team effort was chartered with the goal of developing a system of engineering performance metrics which would measure customer satisfaction, quality, cost effectiveness, and timeliness. The approach to developing this system involved normal systems design phases including, conceptual design, detailed design, implementation, and integration. The lessons teamed from this effort will be explored in this paper. These lessons learned may provide a starting point for other large engineering organizations seeking to institute a performance measurement system accomplishing project objectives and in achieving improved customer satisfaction. To facilitate this effort, a team was chartered to assist in the development of the metrics system. This team, consisting of customers and Engineering staff members, was utilized to ensure that the needs and views of the customers were considered in the development of performance measurements. The development of a system of metrics is no different than the development of any type of system. It includes the steps of defining performance measurement requirements, measurement process conceptual design, performance measurement and reporting system detailed design, and system implementation and integration.

  6. Metrics for Probabilistic Geometries

    DEFF Research Database (Denmark)

    Tosi, Alessandra; Hauberg, Søren; Vellido, Alfredo

    2014-01-01

    the distribution over mappings is given by a Gaussian process. We treat the corresponding latent variable model as a Riemannian manifold and we use the expectation of the metric under the Gaussian process prior to define interpolating paths and measure distance between latent points. We show how distances...

  7. Process for separation of tungsten and molybdenum by extraction

    International Nuclear Information System (INIS)

    Zelikman, A.N.; Voldman, G.M.; Rumyantsev, V.K.; Ziberov, G.N.; Kagermanian, V.S.

    1976-01-01

    A process for the separation of tungsten and molybdenum by extraction involves the addition of HCl or HNO 3 to an aqueous solution containing tungsten and molybdenum to obtain a pH from 0.5 to 4.3, and introduction of a stabilizer comprising water-soluble phosphorus salts and a complexing agent, hydrogen peroxide, in an amount from 1.5 to 2 mole per 1 g-atom of the total content of tungsten and molybdenum. Then molybdenum is selectively extracted from the resulting aqueous solution with tri-n-butylphosphate with equal volumetric proportioning of the aqueous and organic solutions. Re-extraction of molybdenum and partially tungsten is carried out from the organic extracting agent with an alkali or soda solution. The process makes possible the preparation of tungsten solution containing no more than 0.001 g/l of molybdenum, and an increase in the degree of extraction of tungsten and molybdenum

  8. Thermodynamic Properties of Manganese and Molybdenum

    International Nuclear Information System (INIS)

    Desai, P.D.

    1987-01-01

    This work reviews and discusses the data on the various thermodynamic properties of manganese and molybdenum available through March 1985. These include heat capacity, enthalpy, enthalpy of transitions and melting, vapor pressure, and enthalpy of vaporization. The existing data have been critically evaluated and analyzed. The recommended values for the heat capacity, enthalpy, entropy, and Gibbs energy function from 0.5 to 2400 K for manganese and from 0.4 to 5000 K for molybdenum have been generated, as have heat capacity values for supercooled β-Mn and for γ-Mn below 298.15 K. The recommended values for vapor pressure cover the temperature range from 298.15 to 2400 K for manganese and from 298.15 to 5000 K for molybdenum. These values are referred to temperatures based on IPTS-1968. The uncertainties in the recommended values of the heat capacity range from +-3% to +-5% for manganese and from +-1.5% to +-3% for molybdenum

  9. Paraelasticity in electron-irradiated molybdenum

    International Nuclear Information System (INIS)

    Beuneu, Brigitte; Quere, Yves.

    1981-11-01

    The relaxation of a radiation-induced point defect-most probably the rotation of a dumbell-is observed during isothermal anneals of irradiated molybdenum by resistivity measurements. The recovery of close pairs is not affected, in first analysis, by the presence of a uniaxial stress

  10. Exploring atomic defects in molybdenum disulphide monolayers

    KAUST Repository

    Hong, Jinhua; Hu, Zhixin; Probert, Matt; Li, Kun; Lv, Danhui; Yang, Xinan; Gu, Lin; Mao, Nannan; Feng, Qingliang; Xie, Liming; Zhang, Jin; Wu, Dianzhong; Zhang, Zhiyong; Jin, Chuanhong; Ji, Wei; Zhang, Xixiang; Yuan, Jun; Zhang, Ze

    2015-01-01

    Defects usually play an important role in tailoring various properties of two-dimensional materials. Defects in two-dimensional monolayer molybdenum disulphide may be responsible for large variation of electric and optical properties. Here we present a comprehensive joint experiment-theory investigation of point defects in monolayer molybdenum disulphide prepared by mechanical exfoliation, physical and chemical vapour deposition. Defect species are systematically identified and their concentrations determined by aberration-corrected scanning transmission electron microscopy, and also studied by ab-initio calculation. Defect density up to 3.5 × 10 13 cm '2 is found and the dominant category of defects changes from sulphur vacancy in mechanical exfoliation and chemical vapour deposition samples to molybdenum antisite in physical vapour deposition samples. Influence of defects on electronic structure and charge-carrier mobility are predicted by calculation and observed by electric transport measurement. In light of these results, the growth of ultra-high-quality monolayer molybdenum disulphide appears a primary task for the community pursuing high-performance electronic devices.

  11. Exploring atomic defects in molybdenum disulphide monolayers

    KAUST Repository

    Hong, Jinhua

    2015-02-19

    Defects usually play an important role in tailoring various properties of two-dimensional materials. Defects in two-dimensional monolayer molybdenum disulphide may be responsible for large variation of electric and optical properties. Here we present a comprehensive joint experiment-theory investigation of point defects in monolayer molybdenum disulphide prepared by mechanical exfoliation, physical and chemical vapour deposition. Defect species are systematically identified and their concentrations determined by aberration-corrected scanning transmission electron microscopy, and also studied by ab-initio calculation. Defect density up to 3.5 × 10 13 cm \\'2 is found and the dominant category of defects changes from sulphur vacancy in mechanical exfoliation and chemical vapour deposition samples to molybdenum antisite in physical vapour deposition samples. Influence of defects on electronic structure and charge-carrier mobility are predicted by calculation and observed by electric transport measurement. In light of these results, the growth of ultra-high-quality monolayer molybdenum disulphide appears a primary task for the community pursuing high-performance electronic devices.

  12. Reaction of boron carbide with molybdenum disilicide

    International Nuclear Information System (INIS)

    Novikov, A.V.; Melekhin, V.F.; Pegov, V.S.

    1989-01-01

    The investigation results of interaction in the B 4 C-MoSi 2 system during sintering in vacuum are presented. Sintering of boron carbide with molybdenum disilicide is shown to lead to the formation of MoB 2 , SiC, Mo 5 Si 3 compounds, the presence of carbon-containing covering plays an important role in sintering

  13. Molybdenum silicide based materials and their properties

    International Nuclear Information System (INIS)

    Yao, Z.; Stiglich, J.; Sudarshan, T.S.

    1999-01-01

    Molybdenum disilicide (MoSi 2 ) is a promising candidate material for high temperature structural applications. It is a high melting point (2030 C) material with excellent oxidation resistance and a moderate density (6.24 g/cm 3 ). However, low toughness at low temperatures and high creep rates at elevated temperatures have hindered its commercialization in structural applications. Much effort has been invested in MoSi 2 composites as alternatives to pure molybdenum disilicide for oxidizing and aggressive environments. Molybdenum disilicide-based heating elements have been used extensively in high-temperature furnaces. The low electrical resistance of silicides in combination with high thermal stability, electron-migration resistance, and excellent diffusion-barrier characteristics is important for microelectronic applications. Projected applications of MoSi 2 -based materials include turbine airfoils, combustion chamber components in oxidizing environments, missile nozzles, molten metal lances, industrial gas burners, diesel engine glow plugs, and materials for glass processing. On this paper, synthesis, fabrication, and properties of the monolithic and composite molybdenum silicides are reviewed

  14. Metrics for energy resilience

    International Nuclear Information System (INIS)

    Roege, Paul E.; Collier, Zachary A.; Mancillas, James; McDonagh, John A.; Linkov, Igor

    2014-01-01

    Energy lies at the backbone of any advanced society and constitutes an essential prerequisite for economic growth, social order and national defense. However there is an Achilles heel to today's energy and technology relationship; namely a precarious intimacy between energy and the fiscal, social, and technical systems it supports. Recently, widespread and persistent disruptions in energy systems have highlighted the extent of this dependence and the vulnerability of increasingly optimized systems to changing conditions. Resilience is an emerging concept that offers to reconcile considerations of performance under dynamic environments and across multiple time frames by supplementing traditionally static system performance measures to consider behaviors under changing conditions and complex interactions among physical, information and human domains. This paper identifies metrics useful to implement guidance for energy-related planning, design, investment, and operation. Recommendations are presented using a matrix format to provide a structured and comprehensive framework of metrics relevant to a system's energy resilience. The study synthesizes previously proposed metrics and emergent resilience literature to provide a multi-dimensional model intended for use by leaders and practitioners as they transform our energy posture from one of stasis and reaction to one that is proactive and which fosters sustainable growth. - Highlights: • Resilience is the ability of a system to recover from adversity. • There is a need for methods to quantify and measure system resilience. • We developed a matrix-based approach to generate energy resilience metrics. • These metrics can be used in energy planning, system design, and operations

  15. Software Quality Assurance Metrics

    Science.gov (United States)

    McRae, Kalindra A.

    2004-01-01

    Software Quality Assurance (SQA) is a planned and systematic set of activities that ensures conformance of software life cycle processes and products conform to requirements, standards and procedures. In software development, software quality means meeting requirements and a degree of excellence and refinement of a project or product. Software Quality is a set of attributes of a software product by which its quality is described and evaluated. The set of attributes includes functionality, reliability, usability, efficiency, maintainability, and portability. Software Metrics help us understand the technical process that is used to develop a product. The process is measured to improve it and the product is measured to increase quality throughout the life cycle of software. Software Metrics are measurements of the quality of software. Software is measured to indicate the quality of the product, to assess the productivity of the people who produce the product, to assess the benefits derived from new software engineering methods and tools, to form a baseline for estimation, and to help justify requests for new tools or additional training. Any part of the software development can be measured. If Software Metrics are implemented in software development, it can save time, money, and allow the organization to identify the caused of defects which have the greatest effect on software development. The summer of 2004, I worked with Cynthia Calhoun and Frank Robinson in the Software Assurance/Risk Management department. My task was to research and collect, compile, and analyze SQA Metrics that have been used in other projects that are not currently being used by the SA team and report them to the Software Assurance team to see if any metrics can be implemented in their software assurance life cycle process.

  16. The Development of Molybdenum Speciation as a Paleoredox Tool

    Science.gov (United States)

    Rodley, J.; Peacock, C.; Mosselmans, J. F. W.; Poulton, S.

    2017-12-01

    The redox state of the oceans has changed throughout geological time and an understanding of these changes is essential to elucidate links between ocean chemistry, climate and life. Due to its abundance in seawater and redox-sensitive nature, molybdenum has enormous potential as a paleoredox proxy. Although a significant amount of research has been done on molybdenum in ancient and modern sediments in terms of its concentrations and isotopic ratios there remains a limited understanding of the drawdown mechanisms of molybdenum under different redox conditions restricting its use in identifying a range of redox states. In order to address these uncertainties, we have developed a novel sequential extraction technique to examine molybdenum concentrations in six sediment fractions from modern samples that represent oxic, nitrogenous, ferruginous and euxinic environments. In addition we use µ-XRF and µ-XANES synchrotron spectroscopy to examine the molybdenum speciation within these fractions and environments. To interpret our µ-XANES data we have developed an extensive library of molybdenum XANES standards that represent molybdenum sequestration by the sediment fractions identified from the sequential extraction. To further verify our synchrotron results we developed a series of µ-XANES micro-column experiments to examine preferential uptake pathways of molybdenum to different sediment phases under a euxinic water column. The initial data from both the sequential extraction and µ-XANES methods indicate that molybdenum is not limited to a single burial pathway in any of the redox environments. We find that each of the redox environments can be characterised by a limited set of molybdenum phase associations, with molybdenum adsorption to pyrite likely the dominant burial pathway. These findings agree with existing research for molybdenum speciation in euxinic environments suggesting that both pyrite and sulphidised organic matter act as important molybdenum sinks. Our

  17. Defining a standard metric for electricity savings

    International Nuclear Information System (INIS)

    Koomey, Jonathan; Akbari, Hashem; Blumstein, Carl; Brown, Marilyn; Brown, Richard; Calwell, Chris; Carter, Sheryl; Cavanagh, Ralph; Chang, Audrey; Claridge, David; Craig, Paul; Diamond, Rick; Eto, Joseph H; Fulkerson, William; Gadgil, Ashok; Geller, Howard; Goldemberg, Jose; Goldman, Chuck; Goldstein, David B; Greenberg, Steve

    2010-01-01

    The growing investment by governments and electric utilities in energy efficiency programs highlights the need for simple tools to help assess and explain the size of the potential resource. One technique that is commonly used in this effort is to characterize electricity savings in terms of avoided power plants, because it is easier for people to visualize a power plant than it is to understand an abstraction such as billions of kilowatt-hours. Unfortunately, there is no standardization around the characteristics of such power plants. In this letter we define parameters for a standard avoided power plant that have physical meaning and intuitive plausibility, for use in back-of-the-envelope calculations. For the prototypical plant this article settles on a 500 MW existing coal plant operating at a 70% capacity factor with 7% T and D losses. Displacing such a plant for one year would save 3 billion kWh/year at the meter and reduce emissions by 3 million metric tons of CO 2 per year. The proposed name for this metric is the Rosenfeld, in keeping with the tradition among scientists of naming units in honor of the person most responsible for the discovery and widespread adoption of the underlying scientific principle in question-Dr Arthur H Rosenfeld.

  18. Defining a standard metric for electricity savings

    Energy Technology Data Exchange (ETDEWEB)

    Koomey, Jonathan [Lawrence Berkeley National Laboratory and Stanford University, PO Box 20313, Oakland, CA 94620-0313 (United States); Akbari, Hashem; Blumstein, Carl; Brown, Marilyn; Brown, Richard; Calwell, Chris; Carter, Sheryl; Cavanagh, Ralph; Chang, Audrey; Claridge, David; Craig, Paul; Diamond, Rick; Eto, Joseph H; Fulkerson, William; Gadgil, Ashok; Geller, Howard; Goldemberg, Jose; Goldman, Chuck; Goldstein, David B; Greenberg, Steve, E-mail: JGKoomey@stanford.ed

    2010-01-15

    The growing investment by governments and electric utilities in energy efficiency programs highlights the need for simple tools to help assess and explain the size of the potential resource. One technique that is commonly used in this effort is to characterize electricity savings in terms of avoided power plants, because it is easier for people to visualize a power plant than it is to understand an abstraction such as billions of kilowatt-hours. Unfortunately, there is no standardization around the characteristics of such power plants. In this letter we define parameters for a standard avoided power plant that have physical meaning and intuitive plausibility, for use in back-of-the-envelope calculations. For the prototypical plant this article settles on a 500 MW existing coal plant operating at a 70% capacity factor with 7% T and D losses. Displacing such a plant for one year would save 3 billion kWh/year at the meter and reduce emissions by 3 million metric tons of CO{sub 2} per year. The proposed name for this metric is the Rosenfeld, in keeping with the tradition among scientists of naming units in honor of the person most responsible for the discovery and widespread adoption of the underlying scientific principle in question-Dr Arthur H Rosenfeld.

  19. Defining a Standard Metric for Electricity Savings

    Energy Technology Data Exchange (ETDEWEB)

    Brown, Marilyn; Akbari, Hashem; Blumstein, Carl; Koomey, Jonathan; Brown, Richard; Calwell, Chris; Carter, Sheryl; Cavanagh, Ralph; Chang, Audrey; Claridge, David; Craig, Paul; Diamond, Rick; Eto, Joseph H.; Fulkerson, William; Gadgil, Ashok; Geller, Howard; Goldemberg, Jose; Goldman, Chuck; Goldstein, David B.; Greenberg, Steve; Hafemeister, David; Harris, Jeff; Harvey, Hal; Heitz, Eric; Hirst, Eric; Hummel, Holmes; Kammen, Dan; Kelly, Henry; Laitner, Skip; Levine, Mark; Lovins, Amory; Masters, Gil; McMahon, James E.; Meier, Alan; Messenger, Michael; Millhone, John; Mills, Evan; Nadel, Steve; Nordman, Bruce; Price, Lynn; Romm, Joe; Ross, Marc; Rufo, Michael; Sathaye, Jayant; Schipper, Lee; Schneider, Stephen H; Sweeney, James L; Verdict, Malcolm; Vorsatz, Diana; Wang, Devra; Weinberg, Carl; Wilk, Richard; Wilson, John; Worrell, Ernst

    2009-03-01

    The growing investment by governments and electric utilities in energy efficiency programs highlights the need for simple tools to help assess and explain the size of the potential resource. One technique that is commonly used in this effort is to characterize electricity savings in terms of avoided power plants, because it is easier for people to visualize a power plant than it is to understand an abstraction such as billions of kilowatt-hours. Unfortunately, there is no standardization around the characteristics of such power plants. In this letter we define parameters for a standard avoided power plant that have physical meaning and intuitive plausibility, for use in back-of-the-envelope calculations. For the prototypical plant this article settles on a 500 MW existing coal plant operating at a 70percent capacity factor with 7percent T&D losses. Displacing such a plant for one year would save 3 billion kW h per year at the meter and reduce emissions by 3 million metric tons of CO2 per year. The proposed name for this metric is the Rosenfeld, in keeping with the tradition among scientists of naming units in honor of the person most responsible for the discovery and widespread adoption of the underlying scientific principle in question--Dr. Arthur H. Rosenfeld.

  20. Molybdenum distribution and sensitivity in tomatoes, sunflowers and beans

    Energy Technology Data Exchange (ETDEWEB)

    Hecht-Buchholz, C

    1973-01-01

    The influence of increasing levels of molybdenum on the growth, molybdenum uptake and distribution in individual plant organs was investigated in tomatoes, beans and sunflowers in a 9 day trial. With tomatoes, which showed marked damage with high molybdenum levels, the molybdenum content of dry matter was highest in the leaf and lowest in the stem. On the other hand, beans, insensitive towards the high molybdenum level, dry matter molybdenum content was appreciably higher in the stem than in the leaf. It is supposed that in plant species, insensitive to high molybdenum levels, molybdenum is held less firmly in this tissue and can attain damaging levels in the cytoplasm of the youngest leaf tissue cells. It is supposed, on the basis of the reactions which were carried out with expressed root juice and on the basis of the yellow coloration attainable in vitro in the tissue caused by the addition of molybdate solution, that the yellow coloration appearing in the cells and plant organs of various plant species, here tomatoes and sunflowers, with high molybdenum levels is due to a reaction between molybdenum and polyvalent phenols in cellsap.

  1. Enterprise Sustainment Metrics

    Science.gov (United States)

    2015-06-19

    are negatively impacting KPIs” (Parmenter, 2010: 31). In the current state, the Air Force’s AA and PBL metrics are once again split . AA does...must have the authority to “take immediate action to rectify situations that are negatively impacting KPIs” (Parmenter, 2010: 31). 3. Measuring...highest profitability and shareholder value for each company” (2014: 273). By systematically diagraming a process, either through a swim lane flowchart

  2. Symmetries of the dual metrics

    International Nuclear Information System (INIS)

    Baleanu, D.

    1998-01-01

    The geometric duality between the metric g μν and a Killing tensor K μν is studied. The conditions were found when the symmetries of the metric g μν and the dual metric K μν are the same. Dual spinning space was constructed without introduction of torsion. The general results are applied to the case of Kerr-Newmann metric

  3. Kerr metric in cosmological background

    Energy Technology Data Exchange (ETDEWEB)

    Vaidya, P C [Gujarat Univ., Ahmedabad (India). Dept. of Mathematics

    1977-06-01

    A metric satisfying Einstein's equation is given which in the vicinity of the source reduces to the well-known Kerr metric and which at large distances reduces to the Robertson-Walker metric of a nomogeneous cosmological model. The radius of the event horizon of the Kerr black hole in the cosmological background is found out.

  4. Kinetics of molybdenum reduction to molybdenum blue by Bacillus sp. strain A.rzi.

    Science.gov (United States)

    Othman, A R; Bakar, N A; Halmi, M I E; Johari, W L W; Ahmad, S A; Jirangon, H; Syed, M A; Shukor, M Y

    2013-01-01

    Molybdenum is very toxic to agricultural animals. Mo-reducing bacterium can be used to immobilize soluble molybdenum to insoluble forms, reducing its toxicity in the process. In this work the isolation of a novel molybdate-reducing Gram positive bacterium tentatively identified as Bacillus sp. strain A.rzi from a metal-contaminated soil is reported. The cellular reduction of molybdate to molybdenum blue occurred optimally at 4 mM phosphate, using 1% (w/v) glucose, 50 mM molybdate, between 28 and 30 °C and at pH 7.3. The spectrum of the Mo-blue product showed a maximum peak at 865 nm and a shoulder at 700 nm. Inhibitors of bacterial electron transport system (ETS) such as rotenone, sodium azide, antimycin A, and potassium cyanide could not inhibit the molybdenum-reducing activity. At 0.1 mM, mercury, copper, cadmium, arsenic, lead, chromium, cobalt, and zinc showed strong inhibition on molybdate reduction by crude enzyme. The best model that fitted the experimental data well was Luong followed by Haldane and Monod. The calculated value for Luong's constants p max, K(s), S(m), and n was 5.88 μmole Mo-blue hr(-1), 70.36 mM, 108.22 mM, and 0.74, respectively. The characteristics of this bacterium make it an ideal tool for bioremediation of molybdenum pollution.

  5. Evaluation of oxide dispersion strengthened (ODS) molybdenum and molybdenum-rhenium alloys

    International Nuclear Information System (INIS)

    Mueller, A.J.; Bianco, R.; Buckman, R.W. Jr.

    1999-01-01

    Oxide dispersion strengthened (ODS) molybdenum alloys being developed for high temperature applications possess excellent high temperature strength and creep resistance. In addition they exhibit a ductile-to-brittle transition temperature (DBIT) in the worked and stress-relieved condition under longitudinal tensile load well below room temperature. However, in the recrystallized condition, the DBTT maybe near or above room temperature, depending on the volume fraction of oxide dispersion and the amount of prior work. Dilute rhenium additions (7 and 14 wt.%) to ODS molybdenum were evaluated to determine their effect on low temperature ductility. The addition of 7 wt.% rhenium to the ODS molybdenum did not significantly enhance the mechanical properties. However, the addition of 14 wt.% rhenium to the ODS molybdenum resulted in a DBTT well below room temperature in both the stress-relieved and recrystallized condition. Additionally, the tensile strength of ODS Mo-14Re is greater than the base ODS molybdenum at 1,000 to 1,250 C

  6. Study of the molybdenum retention in alumina

    International Nuclear Information System (INIS)

    Wilkinson, Maria V.; Mondino, Angel V.; Manzini, Alberto

    2002-01-01

    The Argentine National Atomic Energy Commission routinely produces 99 Mo by fission of highly enriched uranium contained in targets irradiated in RA-3 reactor. The current process begins with the dissolution of the irradiated target in a basic media, considering the possibility of changing the targets, it could be convenient to dissolve them in acid media. The use of alumina as a first separation step in acid dissolution processes is already known although it is necessary to determine both the type of alumina to be used and the separation conditions. The study of molybdenum retention in alumina was performed at laboratory scale, using Mo-99 as radiotracer. Different kinds of alumina were tried, varying charge solution acidity. Influence of uranium concentration in the loading solution on molybdenum retention was also studied. (author)

  7. Evaluation of a molybdenum assay canister

    International Nuclear Information System (INIS)

    Yoshizumi, T.T.; Keener, S.J.

    1988-01-01

    The performance characteristics of a commercial molybdenum assay canister were evaluated. The geometrical variation of the technetium-99m (/sup 99m/Tc) activity reading was studied as a function of the elution volume for the standard vials. It was found that the /sup 99m/Tc canister activity reading was ∼ 5% lower than that of the standard method. This is due to attenuation by the canister wall. However, the effect of the geometric variation on the clinical dose preparation was found to be insignificant. The molybdenum-99 ( 99 Mo) contamination level was compared by two methods: (1) the commercial canister and (2) the standard assay kit. The 99 Mo contamination measurements with the canister indicated consistently lower readings than those with the standard 99 Mo assay kit. The authors conclude that the canister may be used in the clinical settings. However, the user must be aware of the problems and the limitations associated with this canister

  8. Electrical resistivity of sputtered molybdenum films

    International Nuclear Information System (INIS)

    Nagano, J.

    1980-01-01

    The electrical resistivity of r.f. sputtered molybdenum films of thickness 5-150 nm deposited on oxidized silicon substrates was resolved into the three electron scattering components: isotropic background scattering, scattering at grain boundaries and scattering at surfaces. It was concluded that the isotropic background scattering is almost equal to that of bulk molybdenum and is not influenced by sputtering and annealing conditions. When the film thickness is sufficient that surface scattering can be ignored, the decrease in film resistivity after annealing is caused by the decrease in scattering at the grain boundaries for zero bias sputtered films, and is caused by an increase of the grain diameter for r.f. bias sputtered films. (Auth.)

  9. Investigation of molybdenum pentachloride interaction with chlorine

    International Nuclear Information System (INIS)

    Salyulev, A.B.; Vovkotrub, Eh.G.; Strekalovskij, V.N.

    1993-01-01

    In Raman spectra of molybdenum pentachloride solutions in liquid chlorine lines were recorded in case of 397, 312, 410, 217 and 180 cm - 1 vibrations of ν 1 (A 1 '), ν 2 (A 1 '), ν 5 (E'), ν 6 (E') and ν 8 (E'') monomer (symmetry D 3h ) molecules of MoCl 5 . Interaction of molten molybdenum pentachloride with chlorine at increased (up to 6 MPa) pressures of Cl 2 was studied. In Raman spectra of its vapour distillation in liquid chlorine alongside with MoCl 5 lines appearance of new lines at 363 and 272 cm -1 , similar in their frequency to the ones calculated for the vibrations ν 1 (A 1g ) and ν 2 (E g ) of MoCl 6 molecules (symmetry O h ), was observed

  10. Molybdenum-99 supply: a global issue

    International Nuclear Information System (INIS)

    Cote, R.V.

    2011-01-01

    This article discusses the global supply of Molybdenum 99 used in nuclear medicine. Following a disruption in supplies of isotopes in the last few years, a Canadian expert panel assessed the most viable options for securing a sustainable supply of Technitium 99 over the medium to long term. The general recommendations were to strive for diversity and redundancy throughout the supply chain, leverage multi-use infrastructure, continue with international coordination and seek processing standardization within North America.

  11. Reaction between molybdenum hexafluoride and carboxylic acids

    International Nuclear Information System (INIS)

    Shustov, L.D.; Nikolenko, L.N.; Senchenkova, T.M.

    1983-01-01

    Trifluoromethyl derivatives of pyridine, imidazole and difluoromethane are synthesized during interaction of MoF 6 surplUs (190-210 deg) with nicotine-isomicotine-, 2,6-pyridinedicarboxylic-, 4,5-imidazoledicarboxyclic- and diffluoroacetic acids. The yield of trifluoromethyl derivatives attains 84%. Molybdenum hexafluoride offers some advantages in comparisoo with toxic SF 4 . MoF 6 toxicity is low; leakage of MoF 6 vapors is easily detected

  12. Statistics of grain misorientations in molybdenum

    Energy Technology Data Exchange (ETDEWEB)

    Rybin, V V; Titovets, Yu F; Teplitskij, D M; Zolotorevskij, N Yu

    1982-03-01

    Sets of misorientations between neighbouring grains for three recrystallized molybdenum polycrystals differing in purity, phase composition and prehistory are experimentally determined. The data obtained are analyzed according to modern representations of intergrain boundary structure. In the two materials among the three mentioned above the share of boundaries close to special boundaries with high density of coinciding points turned to be 1.5 times higher than in the polycrystal with chaotic distribution of grains by orientations.

  13. The Role of TonB Gene in Edwardsiella ictaluri Virulence

    Directory of Open Access Journals (Sweden)

    Hossam Abdelhamed

    2017-12-01

    Full Text Available Edwardsiella ictaluri is a Gram-negative facultative intracellular pathogen that causes enteric septicemia in catfish (ESC. Stress factors including poor water quality, poor diet, rough handling, overcrowding, and water temperature fluctuations increase fish susceptibility to ESC. The TonB energy transducing system (TonB-ExbB-ExbD and TonB-dependent transporters of Gram-negative bacteria support active transport of scarce resources including iron, an essential micronutrient for bacterial virulence. Deletion of the tonB gene attenuates virulence in several pathogenic bacteria. In the current study, the role of TonB (NT01EI_RS07425 in iron acquisition and E. ictaluri virulence were investigated. To accomplish this, the E. ictaluri tonB gene was in-frame deleted. Growth kinetics, iron utilization, and virulence of the EiΔtonB mutant were determined. Loss of TonB caused a significant reduction in bacterial growth in iron-depleted medium (p > 0.05. The EiΔtonB mutant grew similarly to wild-type E. ictaluri when ferric iron was added to the iron-depleted medium. The EiΔtonB mutant was significantly attenuated in catfish compared with the parent strain (21.69 vs. 46.91% mortality. Catfish surviving infection with EiΔtonB had significant protection against ESC compared with naïve fish (100 vs. 40.47% survival. These findings indicate that TonB participates in pathogenesis of ESC and is an important E. ictaluri virulence factor.

  14. Learning Low-Dimensional Metrics

    OpenAIRE

    Jain, Lalit; Mason, Blake; Nowak, Robert

    2017-01-01

    This paper investigates the theoretical foundations of metric learning, focused on three key questions that are not fully addressed in prior work: 1) we consider learning general low-dimensional (low-rank) metrics as well as sparse metrics; 2) we develop upper and lower (minimax)bounds on the generalization error; 3) we quantify the sample complexity of metric learning in terms of the dimension of the feature space and the dimension/rank of the underlying metric;4) we also bound the accuracy ...

  15. Biomass as biosorbent for molybdenum ions

    Energy Technology Data Exchange (ETDEWEB)

    Yamaura, Mitiko; Santos, Jacinete L. dos; Damasceno, Marcos O.; Egute, Nayara dos S.; Moraes, Adeniane A.N.; Santos, Bruno Z., E-mail: myamaura@ipen.br, E-mail: jlsantos@ipen.br, E-mail: molidam@ipen.br, E-mail: nayara.egute@usp.br, E-mail: adenianemrs@ig.com.br, E-mail: bzsantos@gmail.com [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)

    2013-07-01

    Biosorbents have been focused as renewable materials of low cost, and have been used for metal removal from the wastewater by adsorption phenomenon. Biosorbents are prepared of biomass, whose reactive sites in its chemical structure have affinity to bind to metal ions. In this work, performance of corn husk, sugarcane bagasse, coir, banana peel, fish scale, chitin and chitosan as biosorbents of molybdenum (VI) ions in aqueous medium was evaluated. The adsorption experiments were investigated in a batch system varying the pH solution from 0.5 to 12 and the contact time between the phases from 2 min to 70 min. {sup 99}Mo radioisotope was used as radioactive tracer for analysis of molybdenum ions by gamma spectroscopy using a HPGe detector. Results revealed that acidity of the solution favored the adsorption of Mo (VI) ions on the all biosorbents. Adsorption values higher than 85% were found on sugarcane bagasse, coir, corn husk, chitin and chitosan at pH 2.0. Only the chitosan was dissolved at pH 0.5 and a gel was formed. The models of pseudo-second order and external film diffusion described the kinetics of adsorption of Mo ions on the coir. This work showed that the studied biomass has high potential to be used as biosorbent of molybdenum ions from acidic wastewater, and the kinetics of Mo adsorption on the coir suggested high-affinity adsorption governed by chemisorption. (author)

  16. Biomass as biosorbent for molybdenum ions

    International Nuclear Information System (INIS)

    Yamaura, Mitiko; Santos, Jacinete L. dos; Damasceno, Marcos O.; Egute, Nayara dos S.; Moraes, Adeniane A.N.; Santos, Bruno Z.

    2013-01-01

    Biosorbents have been focused as renewable materials of low cost, and have been used for metal removal from the wastewater by adsorption phenomenon. Biosorbents are prepared of biomass, whose reactive sites in its chemical structure have affinity to bind to metal ions. In this work, performance of corn husk, sugarcane bagasse, coir, banana peel, fish scale, chitin and chitosan as biosorbents of molybdenum (VI) ions in aqueous medium was evaluated. The adsorption experiments were investigated in a batch system varying the pH solution from 0.5 to 12 and the contact time between the phases from 2 min to 70 min. 99 Mo radioisotope was used as radioactive tracer for analysis of molybdenum ions by gamma spectroscopy using a HPGe detector. Results revealed that acidity of the solution favored the adsorption of Mo (VI) ions on the all biosorbents. Adsorption values higher than 85% were found on sugarcane bagasse, coir, corn husk, chitin and chitosan at pH 2.0. Only the chitosan was dissolved at pH 0.5 and a gel was formed. The models of pseudo-second order and external film diffusion described the kinetics of adsorption of Mo ions on the coir. This work showed that the studied biomass has high potential to be used as biosorbent of molybdenum ions from acidic wastewater, and the kinetics of Mo adsorption on the coir suggested high-affinity adsorption governed by chemisorption. (author)

  17. Preparation of single phase molybdenum boride

    International Nuclear Information System (INIS)

    Camurlu, Hasan Erdem

    2011-01-01

    Highlights: → Formation of Mo and a mixture of molybdenum boride phases take place in preparation of molybdenum borides. → It is intricate to prepare single phase molybdenum borides. → Formation of single phase MoB from MoO 3 + B 2 O 3 + Mg mixtures has not been reported previously. → Single phase MoB was successfully prepared through a combination of mechanochemical synthesis and annealing process. - Abstract: The formation of MoB through volume combustion synthesis (VCS), and through mechanochemical synthesis (MCS) followed by annealing has been investigated. MoO 3 , B 2 O 3 and Mg were used as reactants while MgO and NaCl were introduced as diluents. Products were leached in dilute HCl solution and were subjected to X-ray diffraction (XRD) analysis and scanning electron microscopy (SEM) examinations. Mo was the major phase component in the VCS products under all the experimental conditions. Mo 2 B, MoB, MoB 2 and Mo 2 B 5 were found as minor phases. Products of MCS contained a mixture of Mo 2 B, MoB, MoB 2 and Mo. After annealing the MCS product at 1400 deg. C for 3 h, single phase α-MoB was obtained.

  18. Weldability of powder-metallurgy molybdenum with low oxygen content

    International Nuclear Information System (INIS)

    Hiraoka, Yutaka; Okada, Masatoshi

    1987-01-01

    Relationships between the formation of weld pores and the chemical compositions in powder-metallurgy molybdenum were investigated. It is suggested that almost 100% of Ca and Mg form oxides. In contrast, Fe, Ni, Cr and Al, Si only partly form oxides. A powder-metallurgy molybdenum containing less than 84 at.ppm oxygen did not show any large weld pores. The reduction of the oxygen content was achieved by purifying the molybdenum powder. (orig.) [de

  19. Molybdenum(6) complexing with ethylenediaminedisuccinic acid from PMR spectroscopy data

    International Nuclear Information System (INIS)

    Larchenko, V.E.; Kovaleva, I.B.; Mitrofanova, N.D.; Martynenko, L.I.

    1989-01-01

    Methods of high resolution PMR spectroscopy and pH potentiometry are used to study molybdenum(6) complexing with ethylenediaminedisuccinic acid in aqueous solutions. It is shown that molybdenum(6) interacts with ethylenediaminedisuccinic acid in the narrow range of pH values 4.0-6.5, where MoO 3 H 2 L 2 - and MoO 3 HL 3- complexes with asymmetrical structure are formed. Composition and structure of molybdenum(6) ethylenediaminedisuccinates and ethylenediaminetetraacetates are compared

  20. Deformation localization and cyclic strength in polycrystalline molybdenum

    Energy Technology Data Exchange (ETDEWEB)

    Sidorov, O.T.; Rakshin, A.F.; Fenyuk, M.I.

    1983-06-01

    Conditions of deformation localization and its interrelation with cyclic strength in polycrystalline molybdenum were investigated. A fatigue failure of polycrystalline molybdenum after rolling and in an embrittled state reached by recrystallization annealing under cyclic bending at room temperature takes place under nonuniform distribution of microplastic strain resulting in a temperature rise in separate sections of more than 314 K. More intensive structural changes take place in molybdenum after rolling than in recrystallized state.

  1. Criticality safety review of 2 1/2-, 10-, and 14-ton UF6 cylinders

    International Nuclear Information System (INIS)

    Broadhead, B.L.

    1991-10-01

    Currently, UF 6 cylinders designed to contain 2 1/2 tons of UF 6 are classified as Fissile Class 2 packages with a transport index (TI) of 5 for the purpose of transportation. The 10-ton UF 6 cylinders are classified as Fissile Class 1 with no TI assigned for transportation. The 14-ton cylinders, although not certified for transport with enrichments greater than 1 wt % because they have no approved overpack, can be used in on-site operations for enrichments greater than 1 wt %. The maximum 235 U enrichments for these cylinders are 5.0 wt % for the 2 1/2-ton cylinder and 4.5 wt % for the 10- and 14-ton cylinders. This work reviews the suitability for reclassification of the 2 1/2-ton UF 6 packages as Fissile Class 1 with a maximum 235 U enrichment of 5 wt %. Additionally, the 10- and 14-ton cylinders are reviewed to address a change in maximum 235 U enrichment from 4.5 to 5 wt %. Based on this evaluation, the 2 1/2-ton UF 6 cylinders meet the 10 CFR.71 criteria for Fissile Class 1 packages, and no TI is needed for criticality safety purposes; however, a TI may be required based on radiation from the packages. Similarly, the 10- and 14-ton UF 6 packages appear acceptable for a maximum enrichment rating change to 5 wt % 235 U. 11 refs., 13 figs., 7 tabs

  2. Sorption of molybdenum by cellulose polyphosphate from acid solutions

    International Nuclear Information System (INIS)

    Luneva, N.K.; Oputina, A.G.; Ermolenko, I.N.

    1985-01-01

    The sorption of molybdenum on cellulose polyphosphate from acid solutions of ammonium molybdate depending on the phosphorus content in samples, concentration and pH of the solution, sorption time is studied. It is shown that a maximum molybdenum content on the cellulose samples with different phosphorus content is pointed out at an ammonium molybdate concentration 0.02 M. Saturation of the sorption curve is attained at molar ratio of adsrbed molybdenum to phosphorus 1:4. In case of small fillings the compound with molybdenum to phosphorus ratio 1:10 is formed

  3. Separation of uranium from molybdenum by alkyl phosphoric acid extraction

    Energy Technology Data Exchange (ETDEWEB)

    Zhongshi, Li

    1986-08-01

    The regularities of separation of uranium from molybdenum by alkyl phosphoric acid extraction are described. Two parameters, i.e., density ratio of uranium to molybdenum in organic phase at first stage and density of uranium in raffinate at last stage are presented. The relationship between these parameters and purity of molybdenum and uranium products is given. The method of adjusting and controlling these parameters in experiments and production is worked out. The technical key problem in comprehensive utilization of sedimentary type uranium ore containing molybdenum with close concentration of these to elements has been solved.

  4. High strength tungsten heavy alloys with molybdenum additions

    International Nuclear Information System (INIS)

    Bose, A.; Sims, D.M.; German, R.M.

    1987-01-01

    Tungsten heavy alloys are candidates for numerous applications based on the unique combination of high density, high strength, and high ductility coupled with excellent machinability. Though there has been considerable research on heavy alloys, the primary focus has been on the ductility. These alloys are well suited for ballistic uses due to their high densities and it is expected that for superior ballistic performance, a high hardness, high strength and moderate ductility alloy would be ideal. The major goal of this investigation was to obtain heavy alloys with hardness greater than HRA 72. It is evident from the phase diagrams that molybdenum, which goes into solution in tungsten, nickel and iron, could act as a potential strengthening addition. With this in view, tungsten heavy alloys with molybdenum additions were fabricated from mixed elemental powders. A baseline composition of 90W-7Ni-3Fe was chosen to its good elongation and moderate strength. The molybdenum additions were made by replacing the tungsten. Compared to the baseline properties with no molybdenum addition, the strength and hardness showed a continuous increase with molybdenum addition. The ductility of the alloy continued to decrease with increasing molybdenum content, but even with 16% wt. % molybdenum of the elongation was still around 6%. An interesting facet of these alloying additions is the grain refinement that is brought about by adding to molybdenum to the system. The grain refinement is related to the lower solubility of tunbsten in the matrix due to partial displacement by molybdenum

  5. Effect of molybdenum and iron supply on molybdenum (99Mo) and iron (59Fe) uptake and activity of certain enzymes in tomato plants grown in sand culture

    International Nuclear Information System (INIS)

    Chatterjee, C.; Agarwala, S.C.

    1979-01-01

    Tomato (Lycopersicon esculentum Mill. var. Marglobe) plants were raised under controlled sand culture to study the interaction of molybdenum and iron supply on the uptake of molybdenum and iron and activity of certain enzymes affected by iron and/or molybdenum supply. Iron deficiency caused a decrease in the molybdenum uptake and accentuated the effect of molybdenum deficiency in reducing the uptake and more so the translocation of molybdenum from roots to shoots, thus inducing more severe molybdenum deficiency. The deficiency of iron and molybdenum decreased the activity of catalase, succinate dehydrogenase and nitrate reductase, the most marked decrease being found in plants supplied with both iron and molybdenum at low levels. Changes in the activities of nitrate reductase and catalase can be attributed to the interaction of iron and molybdenum supply in their absorption and translocation. (auth.)

  6. On the effect of interaction of molybdenum trioxide and magnesium oxide in water

    International Nuclear Information System (INIS)

    Bunin, V.M.; Karelin, A.I.; Solov'eva, L.N.

    1992-01-01

    Interaction of molybdenum trioxide and magnesium oxide in water was studied. It is shown that molybdenum trioxide forms consecutively magnesium molybdate, dimolybdate and magnesium polymolybdates with magnesium oxide

  7. Metrics with vanishing quantum corrections

    International Nuclear Information System (INIS)

    Coley, A A; Hervik, S; Gibbons, G W; Pope, C N

    2008-01-01

    We investigate solutions of the classical Einstein or supergravity equations that solve any set of quantum corrected Einstein equations in which the Einstein tensor plus a multiple of the metric is equated to a symmetric conserved tensor T μν (g αβ , ∂ τ g αβ , ∂ τ ∂ σ g αβ , ...,) constructed from sums of terms, the involving contractions of the metric and powers of arbitrary covariant derivatives of the curvature tensor. A classical solution, such as an Einstein metric, is called universal if, when evaluated on that Einstein metric, T μν is a multiple of the metric. A Ricci flat classical solution is called strongly universal if, when evaluated on that Ricci flat metric, T μν vanishes. It is well known that pp-waves in four spacetime dimensions are strongly universal. We focus attention on a natural generalization; Einstein metrics with holonomy Sim(n - 2) in which all scalar invariants are zero or constant. In four dimensions we demonstrate that the generalized Ghanam-Thompson metric is weakly universal and that the Goldberg-Kerr metric is strongly universal; indeed, we show that universality extends to all four-dimensional Sim(2) Einstein metrics. We also discuss generalizations to higher dimensions

  8. Sharp metric obstructions for quasi-Einstein metrics

    Science.gov (United States)

    Case, Jeffrey S.

    2013-02-01

    Using the tractor calculus to study smooth metric measure spaces, we adapt results of Gover and Nurowski to give sharp metric obstructions to the existence of quasi-Einstein metrics on suitably generic manifolds. We do this by introducing an analogue of the Weyl tractor W to the setting of smooth metric measure spaces. The obstructions we obtain can be realized as tensorial invariants which are polynomial in the Riemann curvature tensor and its divergence. By taking suitable limits of their tensorial forms, we then find obstructions to the existence of static potentials, generalizing to higher dimensions a result of Bartnik and Tod, and to the existence of potentials for gradient Ricci solitons.

  9. Completion of a Dislocated Metric Space

    Directory of Open Access Journals (Sweden)

    P. Sumati Kumari

    2015-01-01

    Full Text Available We provide a construction for the completion of a dislocated metric space (abbreviated d-metric space; we also prove that the completion of the metric associated with a d-metric coincides with the metric associated with the completion of the d-metric.

  10. TonEBP modulates the protective effect of taurine in ischemia-induced cytotoxicity in cardiomyocytes

    Science.gov (United States)

    Yang, Y J; Han, Y Y; Chen, K; Zhang, Y; Liu, X; Li, S; Wang, K Q; Ge, J B; Liu, W; Zuo, J

    2015-01-01

    Taurine, which is found at high concentration in the heart, exerts several protective actions on myocardium. Physically, the high level of taurine in heart is maintained by a taurine transporter (TauT), the expression of which is suppressed under ischemic insult. Although taurine supplementation upregulates TauT expression, elevates the intracellular taurine content and ameliorates the ischemic injury of cardiomyocytes (CMs), little is known about the regulatory mechanisms of taurine governing TauT expression under ischemia. In this study, we describe the TonE (tonicity-responsive element)/TonEBP (TonE-binding protein) pathway involved in the taurine-regulated TauT expression in ischemic CMs. Taurine inhibited the ubiquitin-dependent proteasomal degradation of TonEBP, promoted the translocation of TonEBP into the nucleus, enhanced TauT promoter activity and finally upregulated TauT expression in CMs. In addition, we observed that TonEBP had an anti-apoptotic and anti-oxidative role in CMs under ischemia. Moreover, the protective effects of taurine on myocardial ischemia were TonEBP dependent. Collectively, our findings suggest that TonEBP is a core molecule in the protective mechanism of taurine in CMs under ischemic insult. PMID:26673669

  11. Metric adjusted skew information

    DEFF Research Database (Denmark)

    Hansen, Frank

    2008-01-01

    ) that vanishes for observables commuting with the state. We show that the skew information is a convex function on the manifold of states. It also satisfies other requirements, proposed by Wigner and Yanase, for an effective measure-of-information content of a state relative to a conserved observable. We...... establish a connection between the geometrical formulation of quantum statistics as proposed by Chentsov and Morozova and measures of quantum information as introduced by Wigner and Yanase and extended in this article. We show that the set of normalized Morozova-Chentsov functions describing the possible......We extend the concept of Wigner-Yanase-Dyson skew information to something we call "metric adjusted skew information" (of a state with respect to a conserved observable). This "skew information" is intended to be a non-negative quantity bounded by the variance (of an observable in a state...

  12. Research of the technology of obtaining pure and disperse molybdenum disulfide from molybdenum concentrate

    International Nuclear Information System (INIS)

    Hovsepyan, A.H.; Israyelyan, S.M.

    2009-01-01

    The technology of obtaining pure and disperse molybdenum disulfide is worked out. The processes of refinement from the flotation reagents and deslimation by means of decantation, refinement of molybdenite concentrate from impurities by selective leaching methods are studied. The optimal regime of technological process is chosen

  13. The Effect of Molybdenum Fertilization on Arachis Glabrata Biomass ...

    African Journals Online (AJOL)

    The effect of molybdenum fertilization on biomass and the number of nodules of Arachis glabrata was assessed at the Teaching and Research Farm of the University of Dschang in 2011 at different periods of mowing. A factorial design comparing four doses of molybdenum as ammonium molybdate (0, 0.75, 1.5 and 2.25 ...

  14. Tetrathionate reductase of Salmonella thyphimurium: a molybdenum containing enzyme

    International Nuclear Information System (INIS)

    Hinojosa-Leon, M.; Dubourdieu, M.; Sanchez-Crispin, J.A.; Chippaux, M.

    1986-01-01

    Use of radioactive molybdenum demonstrates that the tetrathionate reductase of Salmonella typhimurium is a molydenum containing enzyme. It is proposed that this enzyme shares with other molybdo-proteins, such as nitrate reductase, a common molybdenum containing cofactor the defect of which leads to the loss of the tetrathionate reductase and nitrate reductase activities

  15. Influence of Soil Solution Salinity on Molybdenum Adsorption by Soils

    Science.gov (United States)

    Molybdenum (Mo) adsorption on five arid-zone soils from California was investigated as a function of equilibrium solution Mo concentration (0-30 mg L-1), solution pH (4-8), and electrical conductivity (EC = 0.3 or 8 dS m-1). Molybdenum adsorption decreased with increasing pH. An adsorption maximum...

  16. Low-temperature heat capacity of molybdenum borides

    International Nuclear Information System (INIS)

    Bolgar, A.S.; Klinder, A.V.; Novoseletskaya, L.M.; Turov, V.P.; Klochkov, L.A.; Lyashchenko, A.B.

    1988-01-01

    Heat capacity of molybdenum borides Mo 2 B, MoB, Mo 2 B 5 is studied for the first time in the 60-300 K range using the adiabatic method. Standard (at 298.15 K) thermodynamic functions (enthalpy, heat capacity, entropy, reduced Gibbs energy) of molybdenum borides are calculated

  17. The metric system: An introduction

    Energy Technology Data Exchange (ETDEWEB)

    Lumley, S.M.

    1995-05-01

    On July 13, 1992, Deputy Director Duane Sewell restated the Laboratory`s policy on conversion to the metric system which was established in 1974. Sewell`s memo announced the Laboratory`s intention to continue metric conversion on a reasonable and cost effective basis. Copies of the 1974 and 1992 Administrative Memos are contained in the Appendix. There are three primary reasons behind the Laboratory`s conversion to the metric system. First, Public Law 100-418, passed in 1988, states that by the end of fiscal year 1992 the Federal Government must begin using metric units in grants, procurements, and other business transactions. Second, on July 25, 1991, President George Bush signed Executive Order 12770 which urged Federal agencies to expedite conversion to metric units. Third, the contract between the University of California and the Department of Energy calls for the Laboratory to convert to the metric system. Thus, conversion to the metric system is a legal requirement and a contractual mandate with the University of California. Public Law 100-418 and Executive Order 12770 are discussed in more detail later in this section, but first they examine the reasons behind the nation`s conversion to the metric system. The second part of this report is on applying the metric system.

  18. Attack-Resistant Trust Metrics

    Science.gov (United States)

    Levien, Raph

    The Internet is an amazingly powerful tool for connecting people together, unmatched in human history. Yet, with that power comes great potential for spam and abuse. Trust metrics are an attempt to compute the set of which people are trustworthy and which are likely attackers. This chapter presents two specific trust metrics developed and deployed on the Advogato Website, which is a community blog for free software developers. This real-world experience demonstrates that the trust metrics fulfilled their goals, but that for good results, it is important to match the assumptions of the abstract trust metric computation to the real-world implementation.

  19. The metric system: An introduction

    Science.gov (United States)

    Lumley, Susan M.

    On 13 Jul. 1992, Deputy Director Duane Sewell restated the Laboratory's policy on conversion to the metric system which was established in 1974. Sewell's memo announced the Laboratory's intention to continue metric conversion on a reasonable and cost effective basis. Copies of the 1974 and 1992 Administrative Memos are contained in the Appendix. There are three primary reasons behind the Laboratory's conversion to the metric system. First, Public Law 100-418, passed in 1988, states that by the end of fiscal year 1992 the Federal Government must begin using metric units in grants, procurements, and other business transactions. Second, on 25 Jul. 1991, President George Bush signed Executive Order 12770 which urged Federal agencies to expedite conversion to metric units. Third, the contract between the University of California and the Department of Energy calls for the Laboratory to convert to the metric system. Thus, conversion to the metric system is a legal requirement and a contractual mandate with the University of California. Public Law 100-418 and Executive Order 12770 are discussed in more detail later in this section, but first they examine the reasons behind the nation's conversion to the metric system. The second part of this report is on applying the metric system.

  20. Metric-adjusted skew information

    DEFF Research Database (Denmark)

    Liang, Cai; Hansen, Frank

    2010-01-01

    on a bipartite system and proved superadditivity of the Wigner-Yanase-Dyson skew informations for such states. We extend this result to the general metric-adjusted skew information. We finally show that a recently introduced extension to parameter values 1 ...We give a truly elementary proof of the convexity of metric-adjusted skew information following an idea of Effros. We extend earlier results of weak forms of superadditivity to general metric-adjusted skew information. Recently, Luo and Zhang introduced the notion of semi-quantum states...... of (unbounded) metric-adjusted skew information....

  1. Two classes of metric spaces

    Directory of Open Access Journals (Sweden)

    Isabel Garrido

    2016-04-01

    Full Text Available The class of metric spaces (X,d known as small-determined spaces, introduced by Garrido and Jaramillo, are properly defined by means of some type of real-valued Lipschitz functions on X. On the other hand, B-simple metric spaces introduced by Hejcman are defined in terms of some kind of bornologies of bounded subsets of X. In this note we present a common framework where both classes of metric spaces can be studied which allows us to see not only the relationships between them but also to obtain new internal characterizations of these metric properties.

  2. Kinetics of Molybdenum Reduction to Molybdenum Blue by Bacillus sp. Strain A.rzi

    Directory of Open Access Journals (Sweden)

    A. R. Othman

    2013-01-01

    Full Text Available Molybdenum is very toxic to agricultural animals. Mo-reducing bacterium can be used to immobilize soluble molybdenum to insoluble forms, reducing its toxicity in the process. In this work the isolation of a novel molybdate-reducing Gram positive bacterium tentatively identified as Bacillus sp. strain A.rzi from a metal-contaminated soil is reported. The cellular reduction of molybdate to molybdenum blue occurred optimally at 4 mM phosphate, using 1% (w/v glucose, 50 mM molybdate, between 28 and 30°C and at pH 7.3. The spectrum of the Mo-blue product showed a maximum peak at 865 nm and a shoulder at 700 nm. Inhibitors of bacterial electron transport system (ETS such as rotenone, sodium azide, antimycin A, and potassium cyanide could not inhibit the molybdenum-reducing activity. At 0.1 mM, mercury, copper, cadmium, arsenic, lead, chromium, cobalt, and zinc showed strong inhibition on molybdate reduction by crude enzyme. The best model that fitted the experimental data well was Luong followed by Haldane and Monod. The calculated value for Luong’s constants pmax, Ks, Sm, and n was 5.88 μmole Mo-blue hr−1, 70.36 mM, 108.22 mM, and 0.74, respectively. The characteristics of this bacterium make it an ideal tool for bioremediation of molybdenum pollution.

  3. Software metrics: Software quality metrics for distributed systems. [reliability engineering

    Science.gov (United States)

    Post, J. V.

    1981-01-01

    Software quality metrics was extended to cover distributed computer systems. Emphasis is placed on studying embedded computer systems and on viewing them within a system life cycle. The hierarchy of quality factors, criteria, and metrics was maintained. New software quality factors were added, including survivability, expandability, and evolvability.

  4. Behaviour of helium after implantation in molybdenum

    International Nuclear Information System (INIS)

    Viaud, C.; Maillard, S.; Carlot, G.; Valot, C.; Gilabert, E.; Sauvage, T.; Peaucelle, C.; Moncoffre, N.

    2009-01-01

    This study deals with the behaviour of helium in a molybdenum liner dedicated to the retention of fission products. More precisely this work contributes to evaluate the release of implanted helium when the gas has precipitated into nanometric bubbles close to the free surface. A simple model dedicated to calculate the helium release in such a condition is presented. The specificity of this model lays on the assumption that the gas is in equilibrium with a simple distribution of growing bubbles. This effort is encouraging since the calculated helium release fits an experimental dataset with a set of parameters in good agreement with the literature

  5. Spectra from foil-excited molybdenum ions

    International Nuclear Information System (INIS)

    Johnson, B.M.; Jones, K.W.; Cecchi, J.L.; Kruse, T.H.

    1978-01-01

    The extreme-ultraviolet spectra (5 to 55 nm) for foil-excited molybdenum ions have been measured using 22 to 200 MeV beams from the Brookhaven National Laboratory MP tandem Van de Graaff accelerator facility, 20 μg/cm 2 C stripping foils, and a grazing incidence spectrometer. The mean ion charge states (13 to 28) and the narrow distribution widths (about 2 charge states) were accurately predictable from experimental parameters. Where possible, comparisons are given with Mo radiation from tokamaks, vacuum sparks, and laser-excited plasmas

  6. Molybdenum protective coatings adhesion to steel substrate

    Science.gov (United States)

    Blesman, A. I.; Postnikov, D. V.; Polonyankin, D. A.; Teplouhov, A. A.; Tyukin, A. V.; Tkachenko, E. A.

    2017-06-01

    Protection of the critical parts, components and assemblies from corrosion is an urgent engineering problem and many other industries. Protective coatings’ forming on surface of metal products is a promising way of corrosionprevention. The adhesion force is one of the main characteristics of coatings’ durability. The paper presents theoretical and experimental adhesion force assessment for coatings formed by molybdenum magnetron sputtering ontoa steel substrate. Validity and reliability of results obtained by simulation and sclerometry method allow applying the developed model for adhesion force evaluation in binary «steel-coating» systems.

  7. MHD simulations of molybdenum X-pinches

    International Nuclear Information System (INIS)

    Ivanenkov, G.V.; Stepnevski, V.

    2002-01-01

    One investigates into compression of molybdenum X-pinches applying numerical MHD-models with parabolic and conical initial geometry. The second model describing plasma axial motion in greater detail offers a real geometry of a discharge and is applicable to loads characterized by higher masses in contrast to the first one. Both models enabled to describe all basic phases of compression including origination of a minidiode, occurrence of a narrow neck, microexplosion of a hot point and origination of shock waves followed by sausage instability [ru

  8. Hot rolling of thick uranium molybdenum alloys

    Science.gov (United States)

    DeMint, Amy L.; Gooch, Jack G.

    2015-11-17

    Disclosed herein are processes for hot rolling billets of uranium that have been alloyed with about ten weight percent molybdenum to produce cold-rollable sheets that are about one hundred mils thick. In certain embodiments, the billets have a thickness of about 7/8 inch or greater. Disclosed processes typically involve a rolling schedule that includes a light rolling pass and at least one medium rolling pass. Processes may also include reheating the rolling stock and using one or more heavy rolling passes, and may include an annealing step.

  9. Electrochemical ammonia production on molybdenum nitride nanoclusters

    DEFF Research Database (Denmark)

    Howalt, Jakob Geelmuyden; Vegge, Tejs

    2013-01-01

    Theoretical investigations of electrochemical production of ammonia at ambient temperature and pressure on nitrogen covered molybdenum nanoparticles are presented. Density functional theory calculations are used in combination with the computational hydrogen electrode approach to calculate the free...... energy profile for electrochemical protonation of N2 and N adatoms on cuboctahedral Mo13 nanoparticles. Pathways for electrochemical ammonia production via direct protonation of N adatoms and N2 admolecules with an onset potential as low as -0.5 V and generally lower than -0.8 V on both a nitrogen...

  10. Simulations of intergranular fracture in nanocrystalline molybdenum

    DEFF Research Database (Denmark)

    Frederiksen, Søren Lund; Jacobsen, Karsten Wedel; Schiøtz, Jakob

    2004-01-01

    Using molecular dynamics simulations we investigate the plastic deformation of nanocrystalline molybdenum with a grain size of 12 nm at high strain rates. The simulations are performed with an interatomic potential which is obtained through matching of atomic forces to a database generated...... with density-functional calculations. The simulations show the plastic deformation to involve both grain boundary processes and dislocation migration which in some cases lead to twin boundary formation. A large component of the strain is accommodated through the formation of cracks in the grain boundaries...

  11. Molybdenum Dichalcogenides for Environmental Chemical Sensing

    Directory of Open Access Journals (Sweden)

    Dario Zappa

    2017-12-01

    Full Text Available 2D transition metal dichalcogenides are attracting a strong interest following the popularity of graphene and other carbon-based materials. In the field of chemical sensors, they offer some interesting features that could potentially overcome the limitation of graphene and metal oxides, such as the possibility of operating at room temperature. Molybdenum-based dichalcogenides in particular are among the most studied materials, thanks to their facile preparation techniques and promising performances. The present review summarizes the advances in the exploitation of these MoX2 materials as chemical sensors for the detection of typical environmental pollutants, such as NO2, NH3, CO and volatile organic compounds.

  12. Molybdenum oxide nanocubes: Synthesis and characterizations

    Energy Technology Data Exchange (ETDEWEB)

    Muthamizh, S.; Suresh, R.; Giribabu, K.; Manigandan, R.; Kumar, S. Praveen; Munusamy, S.; Narayanan, V., E-mail: vnnara@yahoo.co.in [Department of Inorganic Chemistry, University of Madras, Guindy Campus, Chennai -600025 (India); Stephen, A. [Department of Nuclear Physics, University of Madras, Guindy Campus, Chennai-600025 (India)

    2015-06-24

    Molybdenum oxide nanoparticles were prepared by Solid state synthesis. The MoO{sub 3} nanoparticles were synthesized by using commercially available ammonium heptamolybdate. The XRD pattern reveals that the synthesized MoO{sub 3} has orthorhombic structure. In addition, lattice parameter values were also calculated using XRD data. The Raman analysis confirm the presence of Mo-O in MoO{sub 3} nanoparticles. DRS-UV analysis shows that MoO{sub 3} has a band gap of 2.89 eV. FE-SEM analysis confirms the material morphology in cubes with nano scale.

  13. Solid solutions of hydrogen in niobium, molybdenum and their alloys

    International Nuclear Information System (INIS)

    Ishikawa, T.T.

    1981-01-01

    The solubility of hydrogen in niobium, molybdenum and niobium-molybdenum alloys with varying atomic fraction of molybdenum from 0.15 to 0.75 was measured on the temperature range of 673 0 K to 1273 0 k for one atmosphere hydrogen pressure. The experimental technique involved the saturation of the solvent metal or alloy with hydrogen, followed by quenching and analysis of the solid solution. The results obtained of hydrogen solubility are consistent with the quasi-regular model for the dilute interstitial solid solutions. The partial molar enthalpy and partial molar entropy in excess of the dissolved hydrogen atoms were calculated from data of solubility versus reciprocal doping temperature. The variation of the relative partial molar enthalpy of hydrogen dissolved in niobium-molybdenum alloys, with the increase of molybdenum content of the alloy was analized. (Author) [pt

  14. Thermal cyclic strength of molybdenum monocrystal at high temperatures

    International Nuclear Information System (INIS)

    Strizhalo, V.A.; Uskov, E.I.

    1975-01-01

    The results of the investigation of the thermocyclic creep and low-cycle fatigue of a molybdenum single crystal are discussed. The strength of a molybdenum single crystal under nonisothermal stressing has been investigated by using two different regimes of temperature and load variation. The temperature limits of the cycle were the same for the two testing regimes, the maximum temperature being 1700degC and the minimum 350degC. At higher temperatures (above 1500degC) the short-term strength of single-crystal molybdenum is comparable with that of commercial molybdenum and the refractory alloys, while the ductility is considerably higher. It should be noted that the failure of single-crystal molybdenum under rigid alternating loading is preceded by intensive distortion of the specimen, owing to directional cyclic creep of the metal in zones of bulging and thinning

  15. Synthesis of molybdenum borides and molybdenum silicides in molten salts and their oxidation behavior in an air-water mixture

    NARCIS (Netherlands)

    Kuznetsov, S.A.; Kuznetsova, S.V.; Rebrov, E.V.; Mies, M.J.M.; Croon, de M.H.J.M.; Schouten, J.C.

    2005-01-01

    The formation of various coatings in molybdenum-boron and molybdenum-silicon systems was investigated. Boronizing and siliciding treatments were conducted in molten salts under inert gas atm. in the 850-1050 DegC temp. range for 7 h. The presence of boride (e.g. Mo2B, MoB, Mo2B5) and silicide

  16. Multimetric indices: How many metrics?

    Science.gov (United States)

    Multimetric indices (MMI’s) often include 5 to 15 metrics, each representing a different attribute of assemblage condition, such as species diversity, tolerant taxa, and nonnative taxa. Is there an optimal number of metrics for MMIs? To explore this question, I created 1000 9-met...

  17. Metrical Phonology: German Sound System.

    Science.gov (United States)

    Tice, Bradley S.

    Metrical phonology, a linguistic process of phonological stress assessment and diagrammatic simplification of sentence and word stress, is discussed as it is found in the English and German languages. The objective is to promote use of metrical phonology as a tool for enhancing instruction in stress patterns in words and sentences, particularly in…

  18. Extending cosmology: the metric approach

    OpenAIRE

    Mendoza, S.

    2012-01-01

    Comment: 2012, Extending Cosmology: The Metric Approach, Open Questions in Cosmology; Review article for an Intech "Open questions in cosmology" book chapter (19 pages, 3 figures). Available from: http://www.intechopen.com/books/open-questions-in-cosmology/extending-cosmology-the-metric-approach

  19. Numerical Calabi-Yau metrics

    International Nuclear Information System (INIS)

    Douglas, Michael R.; Karp, Robert L.; Lukic, Sergio; Reinbacher, Rene

    2008-01-01

    We develop numerical methods for approximating Ricci flat metrics on Calabi-Yau hypersurfaces in projective spaces. Our approach is based on finding balanced metrics and builds on recent theoretical work by Donaldson. We illustrate our methods in detail for a one parameter family of quintics. We also suggest several ways to extend our results

  20. High resolution metric imaging payload

    Science.gov (United States)

    Delclaud, Y.

    2017-11-01

    Alcatel Space Industries has become Europe's leader in the field of high and very high resolution optical payloads, in the frame work of earth observation system able to provide military government with metric images from space. This leadership allowed ALCATEL to propose for the export market, within a French collaboration frame, a complete space based system for metric observation.

  1. Neutron activation determination of impurities in molybdenum

    International Nuclear Information System (INIS)

    Usmanova, M.M.; Mukhamedshina, N.M.; Obraztsova, T.V.; Saidakhmedov, K.Kh.

    1984-01-01

    Instrumental neutron-activation techniques of impurity element determination in molybdenum and MoO 3 (solid and powdered samples) have been developed. When determining impurities of Na, K, Mn, Cu, W, Re molybdenum has been irradiated by thermal neutrons in reactor for 20 min, the sample mass constituted 200-300 mg, sample cooling time after irradiation - 2.5-3.5 h. It is shown that in the process of Cr, Fe, Co, Zn determination the samples should be irradiated with thermal neutrons, and in the process of Sb, Ta and Ni determination - with resonance and fast neutrons. Simultaneous determination of the elements during irradiation with neutrons with reactor spectrum is possible. When determining P and S the samples are irradiated with thermal and epithermal neutrons and β-activity of samples and comparison samples are measured using β-spectrometer with anthracene crystal. The techniques developed permit to determine impurities in Mo with a relative standard deviation 0.07-0.15 and lower boundaries of contents determined - 10 -4 - 10 -7 %

  2. Weyl metrics and wormholes

    Energy Technology Data Exchange (ETDEWEB)

    Gibbons, Gary W. [DAMTP, University of Cambridge, Wilberforce Road, Cambridge, CB3 0WA U.K. (United Kingdom); Volkov, Mikhail S., E-mail: gwg1@cam.ac.uk, E-mail: volkov@lmpt.univ-tours.fr [Laboratoire de Mathématiques et Physique Théorique, LMPT CNRS—UMR 7350, Université de Tours, Parc de Grandmont, Tours, 37200 France (France)

    2017-05-01

    We study solutions obtained via applying dualities and complexifications to the vacuum Weyl metrics generated by massive rods and by point masses. Rescaling them and extending to complex parameter values yields axially symmetric vacuum solutions containing singularities along circles that can be viewed as singular matter sources. These solutions have wormhole topology with several asymptotic regions interconnected by throats and their sources can be viewed as thin rings of negative tension encircling the throats. For a particular value of the ring tension the geometry becomes exactly flat although the topology remains non-trivial, so that the rings literally produce holes in flat space. To create a single ring wormhole of one metre radius one needs a negative energy equivalent to the mass of Jupiter. Further duality transformations dress the rings with the scalar field, either conventional or phantom. This gives rise to large classes of static, axially symmetric solutions, presumably including all previously known solutions for a gravity-coupled massless scalar field, as for example the spherically symmetric Bronnikov-Ellis wormholes with phantom scalar. The multi-wormholes contain infinite struts everywhere at the symmetry axes, apart from solutions with locally flat geometry.

  3. Metrics for image segmentation

    Science.gov (United States)

    Rees, Gareth; Greenway, Phil; Morray, Denise

    1998-07-01

    An important challenge in mapping image-processing techniques onto applications is the lack of quantitative performance measures. From a systems engineering perspective these are essential if system level requirements are to be decomposed into sub-system requirements which can be understood in terms of algorithm selection and performance optimization. Nowhere in computer vision is this more evident than in the area of image segmentation. This is a vigorous and innovative research activity, but even after nearly two decades of progress, it remains almost impossible to answer the question 'what would the performance of this segmentation algorithm be under these new conditions?' To begin to address this shortcoming, we have devised a well-principled metric for assessing the relative performance of two segmentation algorithms. This allows meaningful objective comparisons to be made between their outputs. It also estimates the absolute performance of an algorithm given ground truth. Our approach is an information theoretic one. In this paper, we describe the theory and motivation of our method, and present practical results obtained from a range of state of the art segmentation methods. We demonstrate that it is possible to measure the objective performance of these algorithms, and to use the information so gained to provide clues about how their performance might be improved.

  4. Metric regularity and subdifferential calculus

    International Nuclear Information System (INIS)

    Ioffe, A D

    2000-01-01

    The theory of metric regularity is an extension of two classical results: the Lyusternik tangent space theorem and the Graves surjection theorem. Developments in non-smooth analysis in the 1980s and 1990s paved the way for a number of far-reaching extensions of these results. It was also well understood that the phenomena behind the results are of metric origin, not connected with any linear structure. At the same time it became clear that some basic hypotheses of the subdifferential calculus are closely connected with the metric regularity of certain set-valued maps. The survey is devoted to the metric theory of metric regularity and its connection with subdifferential calculus in Banach spaces

  5. Twitching motility and biofilm formation are associated with tonB1 in Xylella fastidiosa.

    Science.gov (United States)

    Cursino, Luciana; Li, Yaxin; Zaini, Paulo A; De La Fuente, Leonardo; Hoch, Harvey C; Burr, Thomas J

    2009-10-01

    A mutation in the Xylella fastidiosa tonB1 gene resulted in loss of twitching motility and in significantly less biofilm formation as compared with a wild type. The altered motility and biofilm phenotypes were restored by complementation with a functional copy of the gene. The mutation affected virulence as measured by Pierce's disease symptoms on grapevines. The role of TonB1 in twitching and biofilm formation appears to be independent of the characteristic iron-uptake function of this protein. This is the first report demonstrating a functional role for a tonB homolog in X. fastidiosa.

  6. Preparation of molybdenum oxide thin films by MOCVD

    International Nuclear Information System (INIS)

    Guerrero, R. Martinez; Garcia, J.R. Vargas; Santes, V.; Gomez, E.

    2007-01-01

    In this study, molybdenum oxide films were prepared in a horizontal hot-wall MOCVD apparatus using molybdenum dioxide acetylacetonate as precursor. The molybdenum precursor was synthesized from acetylacetone and molybdenum oxide powder. Thermal gravimetric (TG) and differential thermal analyses (DTA) of the precursor suggested the formation of molybdenum oxides around 430 o C (703 K). Thus, a range of deposition temperatures varying from 350 to 630 o C (623-903 K) was explored to investigate the effects on the nature of the molybdenum oxide films. X-ray diffraction (XRD) results showed that the films consisted of α-MoO 3 phase at deposition temperatures ranging from 400 to 560 o C (673-833 K). Crystalline α-MoO 3 films can be obtained from molybdenum dioxide acetylacetonate precursor, without need of a post-annealing treatment. The best crystalline quality was found in films having needle-like crystallites grown at deposition temperature of about 560 o C (833 K), which exhibit a strong (0 1 0) preferred orientation and a transparent visual appearance

  7. Preparation of molybdenum oxide thin films by MOCVD

    Energy Technology Data Exchange (ETDEWEB)

    Guerrero, R. Martinez [Depto. de Ingenieria Metalurgica, ESIQIE-IPN, Mexico 07300, D.F. (Mexico); Garcia, J.R. Vargas [Depto. de Ingenieria Metalurgica, ESIQIE-IPN, Mexico 07300, D.F. (Mexico)]. E-mail: rvargasga@ipn.mx; Santes, V. [CIIEMAD-IPN, Miguel Othon de Mendizabal 485, Mexico 07700, D.F. (Mexico); Gomez, E. [Instituto de Quimica-UNAM, Circuito Exterior-Ciudad Universitaria, Mexico 04510, D.F. (Mexico)

    2007-05-31

    In this study, molybdenum oxide films were prepared in a horizontal hot-wall MOCVD apparatus using molybdenum dioxide acetylacetonate as precursor. The molybdenum precursor was synthesized from acetylacetone and molybdenum oxide powder. Thermal gravimetric (TG) and differential thermal analyses (DTA) of the precursor suggested the formation of molybdenum oxides around 430 {sup o}C (703 K). Thus, a range of deposition temperatures varying from 350 to 630 {sup o}C (623-903 K) was explored to investigate the effects on the nature of the molybdenum oxide films. X-ray diffraction (XRD) results showed that the films consisted of {alpha}-MoO{sub 3} phase at deposition temperatures ranging from 400 to 560 {sup o}C (673-833 K). Crystalline {alpha}-MoO{sub 3} films can be obtained from molybdenum dioxide acetylacetonate precursor, without need of a post-annealing treatment. The best crystalline quality was found in films having needle-like crystallites grown at deposition temperature of about 560 {sup o}C (833 K), which exhibit a strong (0 1 0) preferred orientation and a transparent visual appearance.

  8. Behavior of molybdenum in mixed-oxide fuel

    International Nuclear Information System (INIS)

    Giacchetti, G.; Sari, C.

    1976-01-01

    Metallic molybdenum, Mo--Ru--Rh--Pd alloys, barium, zirconium, and tungsten were added to uranium and uranium--plutonium oxides by coprecipitation and mechanical mixture techniques. This material was treated in a thermal gradient similar to that existing in fuel during irradiation to study the behavior of molybdenum in an oxide matrix as a function of the O/(U + Pu) ratio and some added elements. Result of ceramographic and microprobe analysis shows that when the overall O/(U + Pu) ratio is less than 2, molybdenum and Mo--Ru--Rh--Pd alloy inclusions are present in the uranium--plutonium oxide matrix. If the O/(U + Pu) ratio is greater than 2, molybdenum oxidizes to MoO 2 , which is gaseous at a temperature approximately 1000 0 C. Molybdenum oxide vapor reacts with barium oxide and forms a compound that exists as a liquid phase in the columnar grain region. Molybdenum oxide also reacts with tungsten oxide (tungsten is often present as an impurity in the fuel) and forms a compound that contains approximately 40 wt percent of actinide metals. The apparent solubility of molybdenum in uranium and uranium--plutonium oxides, determined by electron microprobe, was found to be less than 250 ppM both for hypo- and hyperstoichiometric fuels

  9. Spheroidization of molybdenum powder by radio frequency thermal plasma

    Science.gov (United States)

    Liu, Xiao-ping; Wang, Kuai-she; Hu, Ping; Chen, Qiang; Volinsky, Alex A.

    2015-11-01

    To control the morphology and particle size of dense spherical molybdenum powder prepared by radio frequency (RF) plasma from irregular molybdenum powder as a precursor, plasma process parameters were optimized in this paper. The effects of the carrier gas flow rate and molybdenum powder feeding rate on the shape and size of the final products were studied. The molybdenum powder morphology was examined using high-resolution scanning electron microscopy. The powder phases were analyzed by X-ray diffraction. The tap density and apparent density of the molybdenum powder were investigated using a Hall flow meter and a Scott volumeter. The optimal process parameters for the spherical molybdenum powder preparation are 50 g/min powder feeding rate and 0.6 m3/h carrier gas rate. In addition, pure spherical molybdenum powder can be obtained from irregular powder, and the tap density is enhanced after plasma processing. The average size is reduced from 72 to 62 µm, and the tap density is increased from 2.7 to 6.2 g/cm3. Therefore, RF plasma is a promising method for the preparation of high-density and high-purity spherical powders.

  10. METRICS DEVELOPMENT FOR PATENTS.

    Science.gov (United States)

    Veiga, Daniela Francescato; Ferreira, Lydia Masako

    2015-01-01

    To develop a proposal for metrics for patents to be applied in assessing the postgraduate programs of Medicine III - Capes. From the reading and analysis of the 2013 area documents of all the 48 areas of Capes, a proposal for metrics for patents was developed to be applied in Medicine III programs. Except for the areas Biotechnology, Food Science, Biological Sciences III, Physical Education, Engineering I, III and IV and Interdisciplinary, most areas do not adopt a scoring system for patents. The proposal developed was based on the criteria of Biotechnology, with adaptations. In general, it will be valued, in ascending order, the deposit, the granting and licensing/production. It will also be assigned higher scores to patents registered abroad and whenever there is a participation of students. This proposal can be applied to the item Intellectual Production of the evaluation form, in subsection Technical Production/Patents. The percentage of 10% for academic programs and 40% for Masters Professionals should be maintained. The program will be scored as Very Good when it reaches 400 points or over; Good, between 200 and 399 points; Regular, between 71 and 199 points; Weak up to 70 points; Insufficient, no punctuation. Desenvolver uma proposta de métricas para patentes a serem aplicadas na avaliação dos Programas de Pós-Graduação da Área Medicina III - Capes. A partir da leitura e análise dos documentos de área de 2013 de todas as 48 Áreas da Capes, desenvolveu-se uma proposta de métricas para patentes, a ser aplicada na avaliação dos programas da área. Constatou-se que, com exceção das áreas Biotecnologia, Ciência de Alimentos, Ciências Biológicas III, Educação Física, Engenharias I, III e IV e Interdisciplinar, a maioria não adota sistema de pontuação para patentes. A proposta desenvolvida baseou-se nos critérios da Biotecnologia, com adaptações. De uma forma geral, foi valorizado, em ordem crescente, o depósito, a concessão e o

  11. Development of Silicide Coating on Molybdenum Alloy Cladding

    International Nuclear Information System (INIS)

    Lim, Woojin; Ryu, Ho Jin

    2015-01-01

    The molybdenum alloy is considered as one of the accident tolerant fuel (ATF) cladding materials due to its high temperature mechanical properties. However, molybdenum has a weak oxidation resistance at elevated temperatures. To modify the oxidation resistance of molybdenum cladding, silicide coating on the cladding is considered. Molybdenum silicide layers are oxidized to SiO 2 in an oxidation atmosphere. The SiO 2 protective layer isolates the substrate from the oxidizing atmosphere. Pack cementation deposition technique is widely adopted for silicide coating for molybdenum alloys due to its simple procedure, homogeneous coating quality and chemical compatibility. In this study, the pack cementation method was conducted to develop molybdenum silicide layers on molybdenum alloys. It was found that the Mo 3 Si layer was deposited on substrate instead of MoSi 2 because of short holding time. It means that through the extension of holding time, MoSi 2 layer can be formed on molybdenum substrate to enhance the oxidation resistance of molybdenum. The accident tolerant fuel (ATF) concept is to delay the process following an accident by reducing the oxidation rate at high temperatures and to delay swelling and rupture of fuel claddings. The current research for Atf can be categorized into three groups: First, modification of existing zirconium-based alloy cladding by improving the high temperature oxidation resistance and strength. Second, replacing Zirconium based alloys with alternative metallic materials such as refractory elements with high temperature oxidation resistance and strength. Third, designing alternative fuel structures using ceramic and composite systems

  12. Crystalline silicon films sputtered on molybdenum A study of the silicon-molybdenum interface

    Energy Technology Data Exchange (ETDEWEB)

    Reinig, P.; Fenske, F.; Fuhs, W.; Schoepke, A.; Selle, B

    2003-04-15

    Polycrystalline silicon films were grown on molybdenum (Mo)-coated substrates at high deposition rate using the pulsed magnetron sputtering technique. Our study investigates the silicon-molybdenum interface of these films to elucidate stimulating mechanisms for an ordered crystalline silicon thin film growth. Both Auger electron spectroscopy and Rutherford backscattering reveal that at a substrate temperature as low as T{sub S}=450 deg. C during the deposition process intermixing of Si and Mo at the Si-Mo interface takes place leading to a compositional ratio Mo:Si of about 1:2. By Raman spectroscopy hexagonal {beta}-MoSi{sub 2} could be identified as the dominant phase in this intermixed region. The dependence of the resulting thickness of the reacted interface layer on the deposition conditions is not fully understood yet.

  13. Crystalline silicon films sputtered on molybdenum A study of the silicon-molybdenum interface

    International Nuclear Information System (INIS)

    Reinig, P.; Fenske, F.; Fuhs, W.; Schoepke, A.; Selle, B.

    2003-01-01

    Polycrystalline silicon films were grown on molybdenum (Mo)-coated substrates at high deposition rate using the pulsed magnetron sputtering technique. Our study investigates the silicon-molybdenum interface of these films to elucidate stimulating mechanisms for an ordered crystalline silicon thin film growth. Both Auger electron spectroscopy and Rutherford backscattering reveal that at a substrate temperature as low as T S =450 deg. C during the deposition process intermixing of Si and Mo at the Si-Mo interface takes place leading to a compositional ratio Mo:Si of about 1:2. By Raman spectroscopy hexagonal β-MoSi 2 could be identified as the dominant phase in this intermixed region. The dependence of the resulting thickness of the reacted interface layer on the deposition conditions is not fully understood yet

  14. A Metric for Heterotic Moduli

    Science.gov (United States)

    Candelas, Philip; de la Ossa, Xenia; McOrist, Jock

    2017-12-01

    Heterotic vacua of string theory are realised, at large radius, by a compact threefold with vanishing first Chern class together with a choice of stable holomorphic vector bundle. These form a wide class of potentially realistic four-dimensional vacua of string theory. Despite all their phenomenological promise, there is little understanding of the metric on the moduli space of these. What is sought is the analogue of special geometry for these vacua. The metric on the moduli space is important in phenomenology as it normalises D-terms and Yukawa couplings. It is also of interest in mathematics, since it generalises the metric, first found by Kobayashi, on the space of gauge field connections, to a more general context. Here we construct this metric, correct to first order in {α^{\\backprime}}, in two ways: first by postulating a metric that is invariant under background gauge transformations of the gauge field, and also by dimensionally reducing heterotic supergravity. These methods agree and the resulting metric is Kähler, as is required by supersymmetry. Checking the metric is Kähler is intricate and the anomaly cancellation equation for the H field plays an essential role. The Kähler potential nevertheless takes a remarkably simple form: it is the Kähler potential of special geometry with the Kähler form replaced by the {α^{\\backprime}}-corrected hermitian form.

  15. Molybdenum plasma spray powder, process for producing said powder, and coating made therefrom

    International Nuclear Information System (INIS)

    Lafferty, W.D.; Cheney, R.F.; Pierce, R.H.

    1979-01-01

    Plasma spray powders of molybdenum particles containing 0.5 to 15 weight percent oxygen and obtained by reacting molybdenum particles with oxygen or oxides in a plasma, form plasma spray coatings exhibiting hardness comparable to flame sprayed coatings formed from molybdenum wire and plasma coatings of molybdenum powders. Such oxygen rich molybdenum powders may be used to form wear resistant coatings, such as for piston rings. (author)

  16. Implications of Metric Choice for Common Applications of Readmission Metrics

    OpenAIRE

    Davies, Sheryl; Saynina, Olga; Schultz, Ellen; McDonald, Kathryn M; Baker, Laurence C

    2013-01-01

    Objective. To quantify the differential impact on hospital performance of three readmission metrics: all-cause readmission (ACR), 3M Potential Preventable Readmission (PPR), and Centers for Medicare and Medicaid 30-day readmission (CMS).

  17. The extended family of hexagonal molybdenum oxide

    Energy Technology Data Exchange (ETDEWEB)

    Hartl, Monika [Los Alamos National Laboratory; Daemen, Luke [Los Alamos National Laboratory; Lunk, J H [NON LANL; Hartl, H [NON LANL; Frisk, A T [NON LANL; Shendervich, I [NON LANL; Mauder, D [NON LANL; Feist, M [NON LANL; Eckelt, R [NON LANL

    2009-01-01

    Over the last 40 years, a large number of isostructural compounds in the system MoO{sub 3}-NH{sub 3}-H{sub 2}O have been published. The reported molecular formulae of 'hexagonal molybdenum oxide' (HEMO) varied from MoO{sub 3}, MoO{sub 3} {center_dot} 0.33NH{sub 3}, MoO{sub 3} {center_dot} nH{sub 2}O (0.09 {le} n {le} 0.69) to MoO{sub 3} {center_dot} mNH{sub 3} {center_dot} nH{sub 2}O (0.09 {le} m {le} 0.20; 0.18 {le} n {le} 0.60). Samples, prepared by the acidification route, were investigated using thermal analysis coupled on-line to a mass spectrometer for evolved gas analysis; X-ray powder diffraction; Fourier Transform Infrared, Raman and Magic-Angle-Spinning {sup 1}H-NMR spectroscopy; Incoherent Inelastic Neutron Scattering. The X-ray study of a selected monocrystal confirmed the presence of the well-known framework of edge-sharing MoO{sub 6} octahedra: Space group P6{sub 3}/m, a = 10.527(1), c =3.7245(7) {angstrom}, {gamma} = 120{sup o}. The structure of the synthesized samples can best be described by the structural formula (NH{sub 4})[Mo{sub x}{open_square}{sub 1/2+p/2}(O{sub 3x + 1/2-p/2})(OH){sub p}] {center_dot} yH{sub 2}O (x 5.9-7.1; p {approx} 0.1; y = 1.2-2.6), which is consistent with the existence of one vacancy for 12-15 molybdenum sites. The 'chimie douce' reaction of MoO{sub 3} {center_dot} 0.155NH{sub 3} {center_dot} 0.440H{sub 2}O with a 1:1 mixture of NO/NO{sub 2} at 100 C resulted in the synthesis of MoO{sub 3} {center_dot} 0.539H{sub 2}O. Tailored nano-sized molybdenum powders can be produced using HEMO as precursor.

  18. Low cycle fatigue behavior of titanium carbide coated molybdenum

    International Nuclear Information System (INIS)

    Nishi, Hiroshi; Oku, Tatsuo; Kodaira, Tsuneo; Kikuyama, Toshihiko

    1985-09-01

    Sintered molybdenum coated by TiC is used for the first wall such as a troidal fixed limiter and a magnetic limiter plate in JT-60, that is being operated at JAERI presently. This report describes the low cycle fatigue behavior of sintered molybdenum and the influence of TiC coating on fatigue strength. The low cycle fatigue test was conducted at room temperature and 500 0 C. The test results was also analyzed by fractographic observation, metallography and element analysis using EPMA. The low cycle fatigue strength of the molybdenum coated by TiC at 500 0 C is decreased compared with the one at room temperature. (author)

  19. Issues in Benchmark Metric Selection

    Science.gov (United States)

    Crolotte, Alain

    It is true that a metric can influence a benchmark but will esoteric metrics create more problems than they will solve? We answer this question affirmatively by examining the case of the TPC-D metric which used the much debated geometric mean for the single-stream test. We will show how a simple choice influenced the benchmark and its conduct and, to some extent, DBMS development. After examining other alternatives our conclusion is that the “real” measure for a decision-support benchmark is the arithmetic mean.

  20. Background metric in supergravity theories

    International Nuclear Information System (INIS)

    Yoneya, T.

    1978-01-01

    In supergravity theories, we investigate the conformal anomaly of the path-integral determinant and the problem of fermion zero modes in the presence of a nontrivial background metric. Except in SO(3) -invariant supergravity, there are nonvanishing conformal anomalies. As a consequence, amplitudes around the nontrivial background metric contain unpredictable arbitrariness. The fermion zero modes which are explicitly constructed for the Euclidean Schwarzschild metric are interpreted as an indication of the supersymmetric multiplet structure of a black hole. The degree of degeneracy of a black hole is 2/sup 4n/ in SO(n) supergravity

  1. Generalized Painleve-Gullstrand metrics

    Energy Technology Data Exchange (ETDEWEB)

    Lin Chunyu [Department of Physics, National Cheng Kung University, Tainan 70101, Taiwan (China)], E-mail: l2891112@mail.ncku.edu.tw; Soo Chopin [Department of Physics, National Cheng Kung University, Tainan 70101, Taiwan (China)], E-mail: cpsoo@mail.ncku.edu.tw

    2009-02-02

    An obstruction to the implementation of spatially flat Painleve-Gullstrand (PG) slicings is demonstrated, and explicitly discussed for Reissner-Nordstroem and Schwarzschild-anti-deSitter spacetimes. Generalizations of PG slicings which are not spatially flat but which remain regular at the horizons are introduced. These metrics can be obtained from standard spherically symmetric metrics by physical Lorentz boosts. With these generalized PG metrics, problematic contributions to the imaginary part of the action in the Parikh-Wilczek derivation of Hawking radiation due to the obstruction can be avoided.

  2. Daylight metrics and energy savings

    Energy Technology Data Exchange (ETDEWEB)

    Mardaljevic, John; Heschong, Lisa; Lee, Eleanor

    2009-12-31

    The drive towards sustainable, low-energy buildings has increased the need for simple, yet accurate methods to evaluate whether a daylit building meets minimum standards for energy and human comfort performance. Current metrics do not account for the temporal and spatial aspects of daylight, nor of occupants comfort or interventions. This paper reviews the historical basis of current compliance methods for achieving daylit buildings, proposes a technical basis for development of better metrics, and provides two case study examples to stimulate dialogue on how metrics can be applied in a practical, real-world context.

  3. Next-Generation Metrics: Responsible Metrics & Evaluation for Open Science

    Energy Technology Data Exchange (ETDEWEB)

    Wilsdon, J.; Bar-Ilan, J.; Peters, I.; Wouters, P.

    2016-07-01

    Metrics evoke a mixed reaction from the research community. A commitment to using data to inform decisions makes some enthusiastic about the prospect of granular, real-time analysis o of research and its wider impacts. Yet we only have to look at the blunt use of metrics such as journal impact factors, h-indices and grant income targets, to be reminded of the pitfalls. Some of the most precious qualities of academic culture resist simple quantification, and individual indicators often struggle to do justice to the richness and plurality of research. Too often, poorly designed evaluation criteria are “dominating minds, distorting behaviour and determining careers (Lawrence, 2007).” Metrics hold real power: they are constitutive of values, identities and livelihoods. How to exercise that power to more positive ends has been the focus of several recent and complementary initiatives, including the San Francisco Declaration on Research Assessment (DORA1), the Leiden Manifesto2 and The Metric Tide3 (a UK government review of the role of metrics in research management and assessment). Building on these initiatives, the European Commission, under its new Open Science Policy Platform4, is now looking to develop a framework for responsible metrics for research management and evaluation, which can be incorporated into the successor framework to Horizon 2020. (Author)

  4. Electron emission from molybdenum under ion bombardment

    International Nuclear Information System (INIS)

    Ferron, J.; Alonso, E.V.; Baragiola, R.A.; Oliva-Florio, A.

    1981-01-01

    Measurements are reported of electron emission yields of clean molybdenum surfaces under bombardment with H + , H 2 + , D + , D 2 + , He + , N + , N 2 + , O + , O 2 + , Ne + , Ar + , Kr + and Xe + in the wide energy range 0.7-60.2 keV. The clean surfaces were produced by inert gas sputtering under ultrahigh vacuum. The results are compared with those predicted by a core-level excitation model. The disagreement found when using correct values for the energy levels of Mo is traced to wrong assumptions in the model. A substantially improved agreement with experiment is obtained using a model in which electron emission results from the excitation of valence electrons from the target by the projectiles and fast recoiling target atoms. (author)

  5. Molybdenum-base cermet fuel development

    International Nuclear Information System (INIS)

    Gurwell, W.E.; Moss, R.W.; Pilger, J.P.; White, G.D.

    1987-07-01

    Development of a multimegawatt (MMW) space nuclear power system requires identification and resolution of several technical feasibility issues before selecting one or more promising system concepts. Demonstration of reactor fuel fabrication technology is required for cermet-fueled reactor concepts. MMW reactor fuel development activity at Pacific Northwest Laboratory (PNL) is focused on producing a molybdenum-matrix uranium-nitride (UN) fueled cermet. This cermet is to have a high matrix density (≥95%) for high strength and high thermal conductance coupled with a high particle (UN) porosity (∼25%) for retention of released fission gas at high burnup. Fabrication process development involves the use of porous TiN microspheres as surrogate fuel material until porous UN microspheres become available. Process development has been conducted in the areas of microsphere synthesis, particle sealing/coating, and high-energy-rate forming (HERF) and vacuum hot press consolidation techniques. This paper summarizes the status of these activities

  6. Dithiolato complexes of molybdenum and tungsten

    International Nuclear Information System (INIS)

    Nieuwpoort, A.

    1975-01-01

    The synthesis of eight-coordinated and six-coordinated tungsten and molybdenum complexes with dithioligands is described. Molecular and crystal structures are determined and bond angles, bond lengths and structural parameters tabulated. Infrared spectra of dithiocarbamato complexes are discussed more extensively. Redox reactions are studied by voltammetry and electron transfer properties derived. Properties of the d electrons of the metal ion are interpreted in the ligand field model with data from electronic and e.s.r. spectra and magnetic susceptibilities. The result of molecular orbital calculations with the extended Hueckel-LCAO method are presented for eight-coordinated d 1 and d 2 systems, the six-coordinated complexes, and the free ligands

  7. Scattering of fast neutrons from elemental molybdenum

    International Nuclear Information System (INIS)

    Smith, A.B.; Guenther, P.T.

    1982-11-01

    Differential broad-resolution neutron-scattering cross sections of elemental molybdenum were measured at 10 to 20 scattering angles distributed between 20 and 160 degrees and at incident-neutron energy intervals of approx. = 50 to 200 keV from 1.5 to 4.0 MeV. Elastically-scattered neutrons were fully resolved from inelastic events. Lumped-level inelastic-neutron-scattering cross sections were determined corresponding to observed excitation energies of; 789 +- 23, 195 +- 23, 1500 +- 34, 1617 +- 12, 1787, 1874, 1991, 2063 +- 24, 2296, 2569 and 2802 keV. An optical-statistical model was deduced from the measured elastic-scattering results. The experimental values were compared with the respective quantities given in ENDF/B-V

  8. Thermal ripples in model molybdenum disulfide monolayers

    Energy Technology Data Exchange (ETDEWEB)

    Remsing, Richard C.; Klein, Michael L. [Institute for Computational Molecular Science, Center for the Computational, Design of Functional Layered Materials, and Department of Chemistry, Temple University, 1925 N. 12th St., 19122, Philadelphia, PA (United States); Waghmare, Umesh V. [Theoretical Sciences Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, 560 064, Jakkur, Bangalore (India)

    2017-01-15

    Molybdenum disulfide (MoS{sub 2}) monolayers have the potential to revolutionize nanotechnology. To reach this potential, it will be necessary to understand the behavior of this two-dimensional (2D) material on large length scales and under thermal conditions. Herein, we use molecular dynamics (MD) simulations to investigate the nature of the rippling induced by thermal fluctuations in monolayers of the 2H and 1T phases of MoS{sub 2}. The 1T phase is found to be more rigid than the 2H phase. Both monolayer phases are predicted to follow long wavelength scaling behavior typical of systems with anharmonic coupling between vibrational modes as predicted by classic theories of membrane-like systems. (copyright 2017 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  9. Ion adsorption properties of molybdenum (II) bromide

    International Nuclear Information System (INIS)

    Ganzerli-Valentini, M.T.; Meloni, S.; Caramella-Crespi, V.; Borroni, P.A.

    1976-01-01

    The adsorption of about 50 ions on molybdenum dibromide, (Mo 6 Br 8 )Br 4 .2H 2 O in nitric acid was investigated. The behaviour of the investigated elements on MDB in nitric acid, in the concentration range 10 -2 -8M is presented, where the distribution coefficients are given against the HNO 3 molarity. In some cases the elements were investigated in different oxidation states. Most of the elements are not adsorbed or poorly adsorbed, among these the stable anions, thus indicating that bromide ions substitution with other anions is not competitive. The preparation of the adsorber and its characterization is presented and discussed. Adsorption mechanism studies were carried out for some noble metals and chromium. Sorption cannot be ascribed to ion exchange mechanism but to formation of insoluble species, and to settlement of few ions into surface sorption sites or into a limited number of cavitites in the cluster crystal structure of the adsorber. (T.G.)

  10. Radio frequency induction plasma spraying of molybdenum

    International Nuclear Information System (INIS)

    Jiang Xianliang

    2003-01-01

    Radio frequency (RF) induction plasma was used to make free-standing deposition of molybdenum (Mo). The phenomena of particle melting, flattening, and stacking were investigated. The effect of process parameters such as plasma power, chamber pressure, and spray distance on the phenomena mentioned above was studied. Scanning electron microscopy (SEM) was used to analyze the plasma-processed powder, splats formed, and deposits obtained. Experimental results show that less Mo particles are spheroidized when compared to the number of spheroidized tungsten (W) particles at the same powder feed rate under the same plasma spray condition. Molten Mo particles can be sufficiently flattened on substrate. The influence of the process parameters on the flattening behavior is not significant. Mo deposit is not as dense as W deposit, due to the splash and low impact of molten Mo particles. Oxidation of the Mo powder with a large particle size is not evident under the low pressure plasma spray

  11. Microplastic relaxations of single and polycrystalline molybdenum

    Energy Technology Data Exchange (ETDEWEB)

    Pichl, W.; Weiss, B. [Wien Univ. (Austria). Inst. fuer Materialphysik; Chen, D.L.

    1998-05-01

    The microplasticity of high-purity molybdenum single crystals and of Mo polycrystals of technical purity has been investigated by relaxation step tests in uniaxial compression. A new model for the evaluation of relaxation tests in the microplastic range of b.c.c metals is presented which takes into account the decrease of the mobile dislocation density due to exhaustion of non-screw dislocations. The model allows an independent determination of the activation volume and of the microstructure parameters controlling dislocation exhaustion. The results indicate that in the high-purity single crystals the deformation rate is controlled by interactions of non-screw dislocations with the grown-in network. In the polycrystals additional interactions with impurity atoms seem to occur. In the single crystals the activity and subsequent exhaustion of two different glide systems was observed, followed by a gradual onset of screw dislocation motion. (orig.) 26 refs.

  12. Measured oscillator strengths in singly ionized molybdenum

    Science.gov (United States)

    Mayo-García, R.; Aragón, C.; Aguilera, J. A.; Ortiz, M.

    2015-11-01

    In this article, 112 oscillator strengths from Mo II have been measured, 79 of which for the first time. The radiative parameters have been obtained by laser-induced breakdown spectroscopy (LIBS). The plasma is produced from a fused glass sample prepared from molybdenum oxide with a Mo atomic concentration of 0.1%. The plasma evolved in air at atmospheric pressure, and measurements were carried out with the following plasma parameters: an electron density of (2.5+/- 0.1)\\cdot {10}17 cm-3 and an electron temperature of 14,400+/- 200 K. In these conditions, a local thermodynamic equilibrium environment and an optically thin plasma were confirmed for the measurements. The relative intensities were placed on an absolute scale by combining branching fractions with the measured lifetimes and by comparing well-known lines using the plasma temperature. Comparisons were made to previously obtained experimental and theoretical values wherever possible.

  13. Let's Make Metric Ice Cream

    Science.gov (United States)

    Zimmerman, Marianna

    1975-01-01

    Describes a classroom activity which involved sixth grade students in a learning situation including making ice cream, safety procedures in a science laboratory, calibrating a thermometer, using metric units of volume and mass. (EB)

  14. Experiential space is hardly metric

    Czech Academy of Sciences Publication Activity Database

    Šikl, Radovan; Šimeček, Michal; Lukavský, Jiří

    2008-01-01

    Roč. 2008, č. 37 (2008), s. 58-58 ISSN 0301-0066. [European Conference on Visual Perception. 24.08-28.08.2008, Utrecht] R&D Projects: GA ČR GA406/07/1676 Institutional research plan: CEZ:AV0Z70250504 Keywords : visual space perception * metric and non-metric perceptual judgments * ecological validity Subject RIV: AN - Psychology

  15. Coverage Metrics for Model Checking

    Science.gov (United States)

    Penix, John; Visser, Willem; Norvig, Peter (Technical Monitor)

    2001-01-01

    When using model checking to verify programs in practice, it is not usually possible to achieve complete coverage of the system. In this position paper we describe ongoing research within the Automated Software Engineering group at NASA Ames on the use of test coverage metrics to measure partial coverage and provide heuristic guidance for program model checking. We are specifically interested in applying and developing coverage metrics for concurrent programs that might be used to support certification of next generation avionics software.

  16. Phantom metrics with Killing spinors

    Directory of Open Access Journals (Sweden)

    W.A. Sabra

    2015-11-01

    Full Text Available We study metric solutions of Einstein–anti-Maxwell theory admitting Killing spinors. The analogue of the IWP metric which admits a space-like Killing vector is found and is expressed in terms of a complex function satisfying the wave equation in flat (2+1-dimensional space–time. As examples, electric and magnetic Kasner spaces are constructed by allowing the solution to depend only on the time coordinate. Euclidean solutions are also presented.

  17. Molybdenum-UO2 cermet irradiation at 1145 K.

    Science.gov (United States)

    Mcdonald, G.

    1971-01-01

    Two molybdenum-uranium dioxide cermet fuel pins with molybdenum clad were fission-heated in a forced-convection helium coolant for sufficient time to achieve 5.3% burnup. The cermet core contained 20 wt % of 93.2% enriched uranium dioxide. The results were as follows: there was no visible change in the appearance of the molybdenum clad during irradiation; the maximum increase in diameter of the fuel pins was 0.8%; there was no migration of uranium dioxide along grain boundaries and no evident interaction between molybdenum and uranium dioxide; and, finally, approximately 12% of the fission gas formed was released from the cermet core into the gas plenum.

  18. Recovering and recycling uranium used for production of molybdenum-99

    Science.gov (United States)

    Reilly, Sean Douglas; May, Iain; Copping, Roy; Dale, Gregory Edward

    2017-12-12

    A processes for recycling uranium that has been used for the production of molybdenum-99 involves irradiating a solution of uranium suitable for forming fission products including molybdenum-99, conditioning the irradiated solution to one suitable for inducing the formation of crystals of uranyl nitrate hydrates, then forming the crystals and a supernatant and then separating the crystals from the supernatant, thus using the crystals as a source of uranium for recycle. Molybdenum-99 is recovered from the supernatant using an adsorbent such as alumina. Another process involves irradiation of a solid target comprising uranium, forming an acidic solution from the irradiated target suitable for inducing the formation of crystals of uranyl nitrate hydrates, then forming the crystals and a supernatant and then separating the crystals from the supernatant, thus using the crystals as a source of uranium for recycle. Molybdenum-99 is recovered from the supernatant using an adsorbent such as alumina.

  19. Sintering of cermets on the base of corundum and molybdenum

    International Nuclear Information System (INIS)

    Fedotov, A.V.

    1987-01-01

    Liquid-phase sintering of cermets has been studied to develop rational technology allowing to produce a dense material at lower temperatures. Molybdenum of the MPCh mark with the specific surface ranged from 1900 to 4000 cm 2 /g and the corundum powder of the VK-94-1 mark with the specific surface of 6000 cm 2 /g containing upto 10% of the glass-phase have been used as initial materials. It is shown that application of the VK-94-1 ceramics powder for molybdenum content cermets allows to decrease the temperature of dense material production (∼ upto 100 deg C). To produce dense materials, it is necessary to restrict the initial porosity of compaction and to correspond it to the sintering conditions. The increase of molybdenum dispersion allows to produce material with the more homogeneous structure, higher density and strength. Molybdenum presence decreases recrystallization of corundum crystals and causes structure production resistant to high-temperature heating

  20. Physical chemical quality control of the molybdenum technetium generator

    International Nuclear Information System (INIS)

    Olive, E.; Cruz, J.; Isaac, M.; Gamboa, R.; D'Alessandro, K.; Desdin, L.F.

    1995-01-01

    Comparative operational procedure imported molybdenum technetium generators have been made. Procedures for determination of chemical, radiochemical and radionuclidic purities that may be applied in Hospital's laboratories and in the quality control of generators production are developed

  1. Electroplating and stripping copper on molybdenum and niobium

    Science.gov (United States)

    Power, J. L.

    1978-01-01

    Molybdenum and niobium are often electroplated and subsequently stripped of copper. Since general standard plating techniques produce poor quality coatings, general procedures have been optimized and specified to give good results.

  2. Alkaline elution of uranium and molybdenum and their recovery

    International Nuclear Information System (INIS)

    Song Wenlan; Wu Peisheng; Zhao Pinzhi; Tao Dening; Xie Chaoyan

    1987-01-01

    The uranium and molybdenum can be simultaneously eluted by using eluant (NH 4 ) 2 CO 3 + (NH 4 ) 2 SO 4 from resin loaded uranium and molybdenum. The ADU is precipitated from eluant by volatilization of ammonia. The molybdenum is extracted by TFA-TBP-kerosene from the filtrate at pH 3.0-3.2 with molybdenum extraction > 98%. Uranium is nearly not extracted. The precipitation of Mo is reached by sulphuric acid after stripping and the ammonium multimolybdate is obtained. This process can give the total recovery more than 99% for U and 90% for Mo. Because of the use of sulphate salt system, the hazard of NO 3 - can be avoided

  3. Mechanical properties of molybdenum coated with titanium carbide film

    International Nuclear Information System (INIS)

    Shikama, T.; Shinno, H.; Fukutomi, M.; Fujitsuka, M.; Okada, M.

    1983-01-01

    TiC-coated molybdenum is mechanically tensile tested. The 6 μm thick TiC-coated molybdenum has a higher 0.2% proof strength with a slight decrease in uniform and rupture elongation than the uncoated one. This strengthening effect of the TiC coating can be explained by the constrained effect of the high strength TiC film. The 1.2 μm thick TiC-coated molybdenum starts its plastic deformation at a lower stress than the uncoated one. Also, the coating makes the stress-strain curve more smooth. These effects are attributed to the surface effect, namely, that the interface between the molybdenum substrate and the strong and brittle TiC film acts as a strong dislocation source. The compressive stress in the TiC film will also help the start of plastic deformation at lower external stresses. (author)

  4. Molybdenum-A Key Component of Metal Alloys

    Science.gov (United States)

    Kropschot, S.J.

    2010-01-01

    Molybdenum, whose chemical symbol is Mo, was first recognized as an element in 1778. Until that time, the mineral molybdenite-the most important source of molybdenum-was believed to be a lead mineral because of its metallic gray color, greasy feel, and softness. In the late 19th century, French metallurgists discovered that molybdenum, when alloyed (mixed) with steel in small quantities, creates a substance that is remarkably tougher than steel alone and is highly resistant to heat. The alloy was found to be ideal for making tools and armor plate. Today, the most common use of molybdenum is as an alloying agent in stainless steel, alloy steels, and superalloys to enhance hardness, strength, and resistance to corrosion.

  5. X-ray target with substrate of molybdenum alloy

    International Nuclear Information System (INIS)

    Hirsch, H.H.

    1980-01-01

    Rotary targets for x-ray tubes are provided comprising a molybdenum base body alloyed with a stabilizing proportion of iron, silicon, cobalt, tantalum, niobium, hafnium, stable metal oxide, or a mixture of the preceding

  6. Change of mechanical properties of molybdenum after chemical heat treatment

    International Nuclear Information System (INIS)

    Skuratov, L.P.; Yatsimirskij, V.K.; Kirillova, N.V.

    1987-01-01

    Gaseous media (argon, ammonia, nitrogen-hydrogen-ammonia mixture) are studied for their effect on mechanical characteristics of molybdenum at temperatures up to 1000 deg C. It is established that the highest hardening occurs when molybdenum is esposed in the nitrogen-hydrogen medium, while the highest lost of strength takes place in the ammonia medium. An increase of the ammonia concentration in nitrogen-hydrogen-ammonia mixture promotes regular increasing of the deformation rate. With ammonia concentration of 33.3% the gaseous mixture acts the same as pure ammonia. Change of physical-and-mechanical properties of molybdenum under the action of nitrogen-containing gaseous media is associated with formation of molybdenum compounds with nitrogen. During nitriding in ammonia an internal (volume) nitriding proceeds while in the medium of nitrogen-hydrogen mixture surface nitride layers form

  7. Hydrotreatment activities of supported molybdenum nitrides and carbides

    Energy Technology Data Exchange (ETDEWEB)

    Dolce, G.M.; Savage, P.E.; Thompson, L.T. [University of Michigan, Ann Arbor, MI (United States). Dept. of Chemical Engineering

    1997-05-01

    The growing need for alternative sources of transportation fuels encourages the development of new hydrotreatment catalysts. These catalysts must be active and more hydrogen efficient than the current commercial hydrotreatment catalysts. Molybdenum nitrides and carbides are attractive candidate materials possessing properties that are comparable or superior to those of commercial sulfide catalysts. This research investigated the catalytic properties of {gamma}-Al{sub 2}O{sub 3}-supported molybdenum nitrides and carbides. These catalysts were synthesized via temperature-programmed reaction of supported molybdenum oxides with ammonia or methane/hydrogen mixtures. Phase constituents and compositions were determined by X-ray diffraction, elemental analysis, and neutral activation analysis. Oxygen chemisorption was used to probe the surface properties of the catalysts. Specific activities of the molybdenum nitrides and carbides were competitive with those of a commercial sulfide catalyst for hydrodenitrogenation (HDN), hydrodesulfurization (HDS), and hydrodeoxygenation (HDO). For HDN and HDS, the catalytic activity on a molybdenum basis was a strong inverse function of the molybdenum loading. Product distributions of the HDN, HDO and HDS of a variety of heteroatom compounds indicated that several of the nitrides and carbides were more hydrogen efficient than the sulfide catalyst. 35 refs., 8 figs., 7 tabs.

  8. Scalar-metric and scalar-metric-torsion gravitational theories

    International Nuclear Information System (INIS)

    Aldersley, S.J.

    1977-01-01

    The techniques of dimensional analysis and of the theory of tensorial concomitants are employed to study field equations in gravitational theories which incorporate scalar fields of the Brans-Dicke type. Within the context of scalar-metric gravitational theories, a uniqueness theorem for the geometric (or gravitational) part of the field equations is proven and a Lagrangian is determined which is uniquely specified by dimensional analysis. Within the context of scalar-metric-torsion gravitational theories a uniqueness theorem for field Lagrangians is presented and the corresponding Euler-Lagrange equations are given. Finally, an example of a scalar-metric-torsion theory is presented which is similar in many respects to the Brans-Dicke theory and the Einstein-Cartan theory

  9. Regional Feedstock Partnership Summary Report: Enabling the Billion-Ton Vision

    Energy Technology Data Exchange (ETDEWEB)

    Owens, Vance N. [South Dakota State Univ., Brookings, SD (United States). North Central Sun Grant Center; Karlen, Douglas L. [Dept. of Agriculture Agricultural Research Service, Ames, IA (United States). National Lab. for Agriculture and the Environment; Lacey, Jeffrey A. [Idaho National Lab. (INL), Idaho Falls, ID (United States). Process Science and Technology Division

    2016-07-12

    The U.S. Department of Energy (DOE) and the Sun Grant Initiative established the Regional Feedstock Partnership (referred to as the Partnership) to address information gaps associated with enabling the vision of a sustainable, reliable, billion-ton U.S. bioenergy industry by the year 2030 (i.e., the Billion-Ton Vision). Over the past 7 years (2008–2014), the Partnership has been successful at advancing the biomass feedstock production industry in the United States, with notable accomplishments. The Billion-Ton Study identifies the technical potential to expand domestic biomass production to offset up to 30% of U.S. petroleum consumption, while continuing to meet demands for food, feed, fiber, and export. This study verifies for the biofuels and chemical industries that a real and substantial resource base could justify the significant investment needed to develop robust conversion technologies and commercial-scale facilities. DOE and the Sun Grant Initiative established the Partnership to demonstrate and validate the underlying assumptions underpinning the Billion-Ton Vision to supply a sustainable and reliable source of lignocellulosic feedstock to a large-scale bioenergy industry. This report discusses the accomplishments of the Partnership, with references to accompanying scientific publications. These accomplishments include advances in sustainable feedstock production, feedstock yield, yield stability and stand persistence, energy crop commercialization readiness, information transfer, assessment of the economic impacts of achieving the Billion-Ton Vision, and the impact of feedstock species and environment conditions on feedstock quality characteristics.

  10. Electron accelerator-based production of molybdenum-99: Bremsstrahlung and photoneutron generation from molybdenum vs. tungsten

    Energy Technology Data Exchange (ETDEWEB)

    Tsechanski, A. [Ben-Gurion University of the Negev, Department of Nuclear Engineering, P.O. Box 653, Beer-Sheva 84105 (Israel); Bielajew, A.F. [Department of Nuclear Engineering and Radiological Sciences, The University of Michigan, 2355 Bonisteel Boulevard, Ann Arbor, MI 48109 (United States); Archambault, J.P.; Mainegra-Hing, E. [National Research Council of Canada, Ionizing Radiation Standards Laboratory, Ottawa, ON K1A 0R6 (Canada)

    2016-01-01

    A new “one-stage” approach for production of {sup 99}Mo and other radioisotopes by means of an electron linear accelerator is described. It is based on using a molybdenum target both as a bremsstrahlung converter and as a radioisotope producing target for the production of {sup 99}Mo via the photoneutron reaction {sup 100}Mo(γ,n){sup 99}Mo. Bremsstrahlung characteristics, such as bremsstrahlung efficiency, angular distribution, and energy deposition for molybdenum targets were obtained by means of the EGSnrc Monte Carlo simulation code system. As a result of our simulations, it is concluded that a 60 MeV electron beam incident on a thick Mo target will have greater bremsstrahlung efficiency than the same thickness (in units of r{sub 0}) W target, for target thickness z > 1.84r{sub 0}, where r{sub 0} is the electron range. A 50 MeV electron beam incident on a Mo target will result in greater bremsstrahlung efficiency than the same thickness W target (in units of r{sub 0}) for target thickness case: z ⩾ 2.0r{sub 0}. It is shown for the one-stage approach with thicknesses of (1.84–2.0)r{sub 0}, that the {sup 99}Mo-production bremsstrahlung efficiency of a molybdenum target is greater by ∼100% at 30 MeV and by ∼70% at 60 MeV compared to the values for tungsten of the same thickness (in units of the appropriate r{sub 0}) in the traditional two-stage approach (W converter and separate {sup 99}Mo producing target). This advantage of the one-stage approach arises from the fact that the bremsstrahlung produced is attenuated only once from attenuation in the molybdenum converter/target. In the traditional, two-stage approach, the bremsstrahlung generated in the W-converter/target is attenuated both in the converter in the {sup 99}Mo-producing molybdenum target. The photoneutron production yield of molybdenum and tantalum (as a substitute for tungsten) target was calculated by means of the MCNP5 transport code. On the basis of these data, the specific activity

  11. Regge calculus from discontinuous metrics

    International Nuclear Information System (INIS)

    Khatsymovsky, V.M.

    2003-01-01

    Regge calculus is considered as a particular case of the more general system where the linklengths of any two neighbouring 4-tetrahedra do not necessarily coincide on their common face. This system is treated as that one described by metric discontinuous on the faces. In the superspace of all discontinuous metrics the Regge calculus metrics form some hypersurface defined by continuity conditions. Quantum theory of the discontinuous metric system is assumed to be fixed somehow in the form of quantum measure on (the space of functionals on) the superspace. The problem of reducing this measure to the Regge hypersurface is addressed. The quantum Regge calculus measure is defined from a discontinuous metric measure by inserting the δ-function-like phase factor. The requirement that continuity conditions be imposed in a 'face-independent' way fixes this factor uniquely. The term 'face-independent' means that this factor depends only on the (hyper)plane spanned by the face, not on it's form and size. This requirement seems to be natural from the viewpoint of existence of the well-defined continuum limit maximally free of lattice artefacts

  12. Symmetries of Taub-NUT dual metrics

    International Nuclear Information System (INIS)

    Baleanu, D.; Codoban, S.

    1998-01-01

    Recently geometric duality was analyzed for a metric which admits Killing tensors. An interesting example arises when the manifold has Killing-Yano tensors. The symmetries of the dual metrics in the case of Taub-NUT metric are investigated. Generic and non-generic symmetries of dual Taub-NUT metric are analyzed

  13. Operation and maintenance techniques of 1 ton bucket elevator in IMEF

    International Nuclear Information System (INIS)

    Soong, Woong Sup

    1999-04-01

    IMEF pool is used as a pathway between pool and hot cell in order to transfer (incoming and outgoing) irradiated materials. Transfer is performed by 1 ton bucket elevator which is moved inside the rectangular tube installed between pool and M1 hot cell. Allowable load capacity is 1 ton of the bucket elevator and its size is 25 X 25 X 150 cm. Bucket is driven by chain system which is moved up and down through the guide rail. Guide rail is installed in rectangular tube that is tilted about 63 degree. Chain which is moved by using the roller sliding method is driven by sprocket wheel being rotated by the shaft and the shaft is driven by gear reducing motor. In this report operation and maintenance techniques of 1 ton bucket elevator in IMEF are described in detail. (Author). 8 refs., 14 tabs., 6 figs

  14. Operation and maintenance techniques of 1 ton bucket elevator in IMEF

    Energy Technology Data Exchange (ETDEWEB)

    Soong, Woong Sup

    1999-04-01

    IMEF pool is used as a pathway between pool and hot cell in order to transfer (incoming and outgoing) irradiated materials. Transfer is performed by 1 ton bucket elevator which is moved inside the rectangular tube installed between pool and M1 hot cell. Allowable load capacity is 1 ton of the bucket elevator and its size is 25 X 25 X 150 cm. Bucket is driven by chain system which is moved up and down through the guide rail. Guide rail is installed in rectangular tube that is tilted about 63 degree. Chain which is moved by using the roller sliding method is driven by sprocket wheel being rotated by the shaft and the shaft is driven by gear reducing motor. In this report operation and maintenance techniques of 1 ton bucket elevator in IMEF are described in detail. (Author). 8 refs., 14 tabs., 6 figs.

  15. A Kerr-NUT metric

    International Nuclear Information System (INIS)

    Vaidya, P.C.; Patel, L.K.; Bhatt, P.V.

    1976-01-01

    Using Galilean time and retarded distance as coordinates the usual Kerr metric is expressed in form similar to the Newman-Unti-Tamburino (NUT) metric. The combined Kerr-NUT metric is then investigated. In addition to the Kerr and NUT solutions of Einstein's equations, three other types of solutions are derived. These are (i) the radiating Kerr solution, (ii) the radiating NUT solution satisfying Rsub(ik) = sigmaxisub(i)xisub(k), xisub(i)xisup(i) = 0, and (iii) the associated Kerr solution satisfying Rsub(ik) = 0. Solution (i) is distinct from and simpler than the one reported earlier by Vaidya and Patel (Phys. Rev.; D7:3590 (1973)). Solutions (ii) and (iii) gave line elements which have the axis of symmetry as a singular line. (author)

  16. Complexity Metrics for Workflow Nets

    DEFF Research Database (Denmark)

    Lassen, Kristian Bisgaard; van der Aalst, Wil M.P.

    2009-01-01

    analysts have difficulties grasping the dynamics implied by a process model. Recent empirical studies show that people make numerous errors when modeling complex business processes, e.g., about 20 percent of the EPCs in the SAP reference model have design flaws resulting in potential deadlocks, livelocks......, etc. It seems obvious that the complexity of the model contributes to design errors and a lack of understanding. It is not easy to measure complexity, however. This paper presents three complexity metrics that have been implemented in the process analysis tool ProM. The metrics are defined...... for a subclass of Petri nets named Workflow nets, but the results can easily be applied to other languages. To demonstrate the applicability of these metrics, we have applied our approach and tool to 262 relatively complex Protos models made in the context of various student projects. This allows us to validate...

  17. Twitching motility and biofilm formation are associated with tonB1 in Xylella fastidiosa

    OpenAIRE

    Cursino, Luciana; Li, Yaxin; Zaini, Paulo A.; De La Fuente, Leonardo; Hoch, Harvey C.; Burr, Thomas J.

    2017-01-01

    A mutation in the Xylella fastidiosa tonB1 gene resulted in loss of twitching motility and in significantly less biofilm formation as compared with a wild type. The altered motility and biofilm phenotypes were restored by complementation with a functional copy of the gene. The mutation affected virulence as measured by Pierce's disease symptoms on grapevines. The role of TonB1 in twitching and biofilm formation appears to be independent of the characteristic iron-uptake function of this prote...

  18. The uniqueness of the Fisher metric as information metric

    Czech Academy of Sciences Publication Activity Database

    Le, Hong-Van

    2017-01-01

    Roč. 69, č. 4 (2017), s. 879-896 ISSN 0020-3157 Institutional support: RVO:67985840 Keywords : Chentsov’s theorem * mixed topology * monotonicity of the Fisher metric Subject RIV: BA - General Mathematics OBOR OECD: Pure mathematics Impact factor: 1.049, year: 2016 https://link.springer.com/article/10.1007%2Fs10463-016-0562-0

  19. Thermodynamic metrics and optimal paths.

    Science.gov (United States)

    Sivak, David A; Crooks, Gavin E

    2012-05-11

    A fundamental problem in modern thermodynamics is how a molecular-scale machine performs useful work, while operating away from thermal equilibrium without excessive dissipation. To this end, we derive a friction tensor that induces a Riemannian manifold on the space of thermodynamic states. Within the linear-response regime, this metric structure controls the dissipation of finite-time transformations, and bestows optimal protocols with many useful properties. We discuss the connection to the existing thermodynamic length formalism, and demonstrate the utility of this metric by solving for optimal control parameter protocols in a simple nonequilibrium model.

  20. Invariant metrics for Hamiltonian systems

    International Nuclear Information System (INIS)

    Rangarajan, G.; Dragt, A.J.; Neri, F.

    1991-05-01

    In this paper, invariant metrics are constructed for Hamiltonian systems. These metrics give rise to norms on the space of homeogeneous polynomials of phase-space variables. For an accelerator lattice described by a Hamiltonian, these norms characterize the nonlinear content of the lattice. Therefore, the performance of the lattice can be improved by minimizing the norm as a function of parameters describing the beam-line elements in the lattice. A four-fold increase in the dynamic aperture of a model FODO cell is obtained using this procedure. 7 refs

  1. Generalization of Vaidya's radiation metric

    Energy Technology Data Exchange (ETDEWEB)

    Gleiser, R J; Kozameh, C N [Universidad Nacional de Cordoba (Argentina). Instituto de Matematica, Astronomia y Fisica

    1981-11-01

    In this paper it is shown that if Vaidya's radiation metric is considered from the point of view of kinetic theory in general relativity, the corresponding phase space distribution function can be generalized in a particular way. The new family of spherically symmetric radiation metrics obtained contains Vaidya's as a limiting situation. The Einstein field equations are solved in a ''comoving'' coordinate system. Two arbitrary functions of a single variable are introduced in the process of solving these equations. Particular examples considered are a stationary solution, a nonvacuum solution depending on a single parameter, and several limiting situations.

  2. Chalcogenhalide cluster rhenium- and molybdenum complexes

    International Nuclear Information System (INIS)

    Fedin, V.P.; Gubin, S.P.; Mishchenko, A.V.; Fedorov, V.E.

    1984-01-01

    The interaction of rhenium- and molybdenum chalcogenhalides with n-donor ligands (L) is studied. At heating Re 3 X 2 Hal 5 complexes up to 100 deg in DMSO in the L presence obtained are the complexes of the 1-6 composition Re 3 X 2 Hal 5 -x Lx DMSO (X=Se, Hal=Cl, L=Et 3 N(1); X=Se, Hal=Cl, L=Bipy(2); X=Se, Hal=Br, L=Et 3 N(3); X=Se, Hal=Br, L=Bipy(4); X=Te, Hal=Br, L=Et 3 N(5); X=Te, Hal=Br, L=(Me 2 NCH 2 ) 2 (6). In the course of boiling of Mo 3 S 7 Hal 4 with PPh 3 in MeCN the Mo 3 S 7 Hal 4 2PPh 3 complexes (Hal=Cl(7); Br(8)) are obtained. For 1 through 8 complexes the chemical analysis data and IR spectra are given. For 4 and 8 complexes the molecular mass is measured. A possible method of obtaining molecular trinuclear clusters from polymer clusters is discussed

  3. Improved processes of molybdenum-99 production

    International Nuclear Information System (INIS)

    Dadachova, K.; La Riviere, K.; Anderon, P.

    1997-01-01

    Two improved processes of Molybdenum-99 production have been developed at ANSTO on laboratory scale. The first one allows to purify Mo of natural isotopic composition from tungsten impurities by using preferential adsorption of tungsten on hydrated tin(IV) oxide SnO 2 x nH 2 O before irradiation in the nuclear reactor. Mo-99 obtained via this route can be used for production of i nstant Tc-99m. As the starting material MoO 3 contains considerable amounts of tungsten impurity (W > 60 ppm), 5-7 days irradiation results in generation of W-188 in amounts sufficient to contaminate the final Tc-99m product with rhenium-188 (Re-188, 16.8 h half-life) - radioactive daughter of W-188. To overcome this problem, a method of MoO 3 purification from W, based on preferential adsorption of W by hydrated tin (IV) oxide has been developed. The contents of W in MoO 3 purified by this technique became 3 and retaining of Mo-99 on a large alumina column. Mo-99 is stripped off the column with 200 mL 1M NH 4 OH followed by loading this solution onto the AG 1x8 column. The next steps are different for each version of separation process

  4. Combustion of environmentally altered molybdenum trioxide nanocomposites

    Energy Technology Data Exchange (ETDEWEB)

    Moore, Kevin; Pantoya, Michelle L. [Mechanical Engineering Department, Texas Tech University, 2500 Broadway, Lubbock, TX 79409 (United States)

    2006-06-15

    Nanocomposite thermite mixtures are currently under development for many primer applications due to their high energy densities, high ignition sensitivity, and low release of toxins into the environment. However, variability and inconsistencies in combustion performance have not been sufficiently investigated. Environmental interactions with the reactants are thought to be a contributing factor to these variabilities. Combustion velocity experiments were conducted on aluminum (Al) and molybdenum trioxide (MoO{sub 3}) mixtures to investigate the role of environmental interactions such as light exposure and humidity. While the Al particles were maintained in an ambient, constant environment, the MoO{sub 3} particles were exposed to UV or fluorescent light, and highly humid environments. Results show that UV and fluorescent lighting over a period of days does not significantly contribute to performance deterioration. However, a humid environment severely decreases combustion performance if the oxidizer particles are not heat-treated. Heat treatment of the MoO{sub 3} greatly increases the material's ability to resist water absorption, yielding more repeatable combustion performance. This work further quantifies the role of the environment in the decrease of combustion performance of nanocomposites over time. (Abstract Copyright [2006], Wiley Periodicals, Inc.)

  5. Groundwater Molybdenum from Emerging Industries in Taiwan.

    Science.gov (United States)

    Tsai, Kuo-Sheng; Chang, Yu-Min; Kao, Jimmy C M; Lin, Kae-Long

    2016-01-01

    This study determined the influence of emerging industries development on molybdenum (Mo) groundwater contamination. A total of 537 groundwater samples were collected for Mo determination, including 295 samples from potentially contaminated areas of 3 industrial parks in Taiwan and 242 samples from non-potentially contaminated areas during 2008-2014. Most of the high Mo samples are located downstream from a thin film transistor-liquid crystal display (TFT-LCD) panel factory. Mean groundwater Mo concentrations from potentially contaminated areas (0.0058 mg/L) were significantly higher (p industry and following wastewater batch treatment were 0.788 and 0.0326 mg/L, respectively. This indicates that wastewater containing Mo is a possible source of both groundwater and surface water contamination. Nine samples of groundwater exceed the World Health Organization's suggested drinking water guideline of 0.07 mg/L. A non-carcinogenic risk assessment for Mo in adults and children using the Mo concentration of 0.07 mg/L yielded risks of 0.546 and 0.215, respectively. These results indicate the importance of the development of a national drinking water quality standard for Mo in Taiwan to ensure safe groundwater for use. According to the human health risk calculation, the groundwater Mo standard is suggested as 0.07 mg/L. Reduction the discharge of Mo-contaminated wastewater from factories in the industrial parks is also the important task in the future.

  6. Raman Signatures of Polytypism in Molybdenum Disulfide.

    Science.gov (United States)

    Lee, Jae-Ung; Kim, Kangwon; Han, Songhee; Ryu, Gyeong Hee; Lee, Zonghoon; Cheong, Hyeonsik

    2016-02-23

    Since the stacking order sensitively affects various physical properties of layered materials, accurate determination of the stacking order is important for studying the basic properties of these materials as well as for device applications. Because 2H-molybdenum disulfide (MoS2) is most common in nature, most studies so far have focused on 2H-MoS2. However, we found that the 2H, 3R, and mixed stacking sequences exist in few-layer MoS2 exfoliated from natural molybdenite crystals. The crystal structures are confirmed by HR-TEM measurements. The Raman signatures of different polytypes are investigated by using three different excitation energies that are nonresonant and resonant with A and C excitons, respectively. The low-frequency breathing and shear modes show distinct differences for each polytype, whereas the high-frequency intralayer modes show little difference. For resonant excitations at 1.96 and 2.81 eV, distinct features are observed that enable determination of the stacking order.

  7. Molybdenum disilicide composites produced by plasma spraying

    International Nuclear Information System (INIS)

    Castro, R.G.; Hollis, K.J.; Kung, H.H.; Bartlett, A.H.

    1998-01-01

    The intermetallic compound, molybdenum disilicide (MoSi 2 ) is being considered for high temperature structural applications because of its high melting point and superior oxidation resistance at elevated temperatures. The lack of high temperature strength, creep resistance and low temperature ductility has hindered its progress for structural applications. Plasma spraying of coatings and structural components of MoSi 2 -based composites offers an exciting processing alternative to conventional powder processing methods due to superior flexibility and the ability to tailor properties. Laminate, discontinuous and in situ reinforced composites have been produced with secondary reinforcements of Ta, Al 2 O 3 , SiC, Si 3 N 4 and Mo 5 Si 3 . Laminate composites, in particular, have been shown to improve the damage tolerance of MoSi 2 during high temperature melting operations. A review of research which as been performed at Los Alamos National Laboratory on plasma spraying of MoSi 2 -based composites to improve low temperature fracture toughness, thermal shock resistance, high temperature strength and creep resistance will be discussed

  8. Technical Privacy Metrics: a Systematic Survey

    OpenAIRE

    Wagner, Isabel; Eckhoff, David

    2018-01-01

    The file attached to this record is the author's final peer reviewed version The goal of privacy metrics is to measure the degree of privacy enjoyed by users in a system and the amount of protection offered by privacy-enhancing technologies. In this way, privacy metrics contribute to improving user privacy in the digital world. The diversity and complexity of privacy metrics in the literature makes an informed choice of metrics challenging. As a result, instead of using existing metrics, n...

  9. Remarks on G-Metric Spaces

    Directory of Open Access Journals (Sweden)

    Bessem Samet

    2013-01-01

    Full Text Available In 2005, Mustafa and Sims (2006 introduced and studied a new class of generalized metric spaces, which are called G-metric spaces, as a generalization of metric spaces. We establish some useful propositions to show that many fixed point theorems on (nonsymmetric G-metric spaces given recently by many authors follow directly from well-known theorems on metric spaces. Our technique can be easily extended to other results as shown in application.

  10. DLA Energy Biofuel Feedstock Metrics Study

    Science.gov (United States)

    2012-12-11

    moderately/highly in- vasive  Metric 2: Genetically modified organism ( GMO ) hazard, Yes/No and Hazard Category  Metric 3: Species hybridization...4– biofuel distribution Stage # 5– biofuel use Metric 1: State inva- siveness ranking Yes Minimal Minimal No No Metric 2: GMO hazard Yes...may utilize GMO microbial or microalgae species across the applicable biofuel life cycles (stages 1–3). The following consequence Metrics 4–6 then

  11. Adsorption of heavy metal ions on molybdenum and molybdenum trioxide from dilute aqueous solution

    International Nuclear Information System (INIS)

    Utsunomiya, Taizo; Hoshino, Yoshio; Sakabe, Ken-ichi

    1984-01-01

    The adsorption of heavy metal ions such as Co(II), Cu(II) and Pb(II) on molybdenum powder has been investigated by the batch technique as a function of soaking time, concentration of heavy metal ions and coexisting salts, pH etc. Molybdenum trioxide was also used as an adsorbent for a comparison to discuss the adsorption mechanism. The amount of these heavy metal ions adsorbed was highly pH and coexisting salts dependent. These adsorbents have features of selective adsorption for Pb(II) and large adsorption rate. The adsorption of heavy metal ions on these adsorbents proceeds independently or concurrently by following complex mechanism; (1) cation exchange reaction by hydroxyl radical on the surface of Mo and MoO 3 is predominant for most of heavy metal ions except Pb(II) [Co(II), Mn(II), Fe(III), Ni(II), Zn(II), Cd(II) and Sr(II)], (2) reduction (electron exchange reaction) to low ionic or metallic state after cation exchange reaction [Cu(II) and Ag(I) on Mo] and (3) formation of a compound [Pb(II) on both Mo and MoO 3 ]. (author)

  12. Uranium and Molybdenum extraction from a Cerro Solo deposit ore

    International Nuclear Information System (INIS)

    Becquart, Elena T.; Arias, Maria J.; Fuente, Juan C. de la; Misischia, Yamila A.; Santa Cruz, Daniel E.; Tomellini, Guido C.

    2009-01-01

    Cerro Solo, located in Chubut, Argentina, is a sandstone type uranium-molybdenum deposit. Good recovery of both elements can be achieved by acid leaching of the ore but the presence of molybdenum in pregnant liquors is an inconvenient to uranium separation and purification. A two steps process is developed. A selective alkaline leaching of the ore with sodium hydroxide allows separating and recovering of molybdenum and after solid-liquid separation, the ore is acid leached to recover uranium. Several samples averaging 0,2% uranium and 0,1% molybdenum with variable U/Mo ratio have been used and in both steps, leaching and oxidant reagents concentration, temperature and residence time in a stirred tank leaching have been studied. In alkaline leaching molybdenum recoveries greater than 96% are achieved, with 1% uranium extraction. In acid leaching up to 93% of the uranium is extracted and Mo/U ratio in solvent extraction feed is between 0,013 and 0,025. (author)

  13. Ion exchange resin fouling of molybdenum in recovery uranium processess

    International Nuclear Information System (INIS)

    Zhang Guowei; Zhao Guirong

    1990-09-01

    The relationship between anion exchange resin fouling and molybdic acid polymerization was studied. By using potentiometer titration and laser-Raman spectroscopy the relationship of molybdic acid polymerization and the pH value of solution or the molybdenum concentration was determined. It was shown that as the concentration of initial molybdenum in solution decreases from 0.2 mol/L to 0.5 mmol/L, the pH value of starting polymerization decreased from 6.5 to 4.5. The experimental results show that the fouling of 201 x 7 resin in the acidic solution is mainly caused by the adsorbing of Mo 3 O 26 4- ion and occupying the exchange radical site of the resin. Under the leaching conditions the molybdenum and phosphate existing in the leaching liquor can form 12-molybdo-phosphate ion. It also leads to resin fouling. The molybdenum on the fouled resin can synergically be desorbed by mixed desorbents containing ammonium hydroxide and ammonium sulfate. The desorbed resin can be used for uranium adsorption and the desorbed molybdenum can be recovered by ion exchange method

  14. Reduction and immobilization of molybdenum by Desulfovibrio desulfuricans

    Energy Technology Data Exchange (ETDEWEB)

    Tucker, M.D.; Barton, L.L.; Thomson, B.M. [Sandia National Laboratories, Albuquerque, NM (United States)

    1997-07-01

    Molybdenum contamination of groundwater occurs through activities such as molybdenum and copper mining and processing, shale oil production and power generation from coal-fired power plants. The mobility of Mo in the environment is strongly dependent on its chemical oxidation state. Under oxidizing conditions, Mo occurs as highly soluble and mobile Mo(VI) and Mo(V) compounds. However, under reducing conditions Mo usually forms insoluble Mo(IV) phases. The objective of this study was to demonstrate the ability of the sulfate-reducing bacterium, Desulfovibrio desulfuricans, to reduce Mo(IV) to Mo(IV) in anaerobic environments. Molybdenum-VI was reduced to Mo(IV) by washed cells of D. desulfuricans suspended in bicarbonate buffer solution with either lactate or H{sub 2} as the electron donor and Mo(VI) as the electron acceptor. Molybdenum-VIi reduction by D. desulfuricans in the presence of sulfide resulted in the extracelluar precipitation of the mineral molybdenite. Molybdenum-VI reduction did not occur in the absence of an electron donor or in the presence of heat-killed cells of D. desulfuricans. The results indicate that enzymatic reduction of Mo(VI) by sulfate-reducing bacteria may contribute to the accumulation of Mo(IV) in anaerobic environments and that there organisms may be useful for removing soluble Mo from contaminated water. 20 refs., 6 figs., 4 tabs.

  15. The potential roles of lime and molybdenum on the growth, nitrogen ...

    African Journals Online (AJOL)

    STORAGESEVER

    2010-04-26

    Apr 26, 2010 ... and Molybdenum (Mo) are essential plant nutrients; whose role has been well ... interaction on different photosynthetic activities in P. vulgaris grown ..... concentrations of nickel, cadmium lead and molybdenum. J. Plant. Nutr.

  16. Separable metrics and radiating stars

    Indian Academy of Sciences (India)

    We study the junction condition relating the pressure to heat flux at the boundary of an accelerating and expanding spherically symmetric radiating star. We transform the junction condition to an ordinary differential equation by making a separability assumption on the metric functions in the space–time variables.

  17. Socio-technical security metrics

    NARCIS (Netherlands)

    Gollmann, D.; Herley, C.; Koenig, V.; Pieters, W.; Sasse, M.A.

    2015-01-01

    Report from Dagstuhl seminar 14491. This report documents the program and the outcomes of Dagstuhl Seminar 14491 “Socio-Technical Security Metrics”. In the domain of safety, metrics inform many decisions, from the height of new dikes to the design of nuclear plants. We can state, for example, that

  18. Leading Gainful Employment Metric Reporting

    Science.gov (United States)

    Powers, Kristina; MacPherson, Derek

    2016-01-01

    This chapter will address the importance of intercampus involvement in reporting of gainful employment student-level data that will be used in the calculation of gainful employment metrics by the U.S. Department of Education. The authors will discuss why building relationships within the institution is critical for effective gainful employment…

  19. Safety analysis report on the ''Paducah Tiger'' protective overpack for 10-ton cylinders of uranium hexafluoride

    International Nuclear Information System (INIS)

    Stitt, D.H.

    1975-01-01

    The ''Paducah Tiger'' is a protective overpack used in shipment of 10-ton cylinders of enriched UF 6 . The calculations and tests are described which made and which indicate that the overpack is in compliance with the type B packaging requirements of ERDA Manual Chapter 0529 and Title 10 Code Federal Regulations Part 71. (U.S.)

  20. A method to press powder at 6000 ton using small amount of explosive

    Science.gov (United States)

    Hilmi, Ahmad Humaizi; Azmi, Nor Azmaliana; Ismail, Ariffin

    2017-12-01

    Large die hydraulic press forces are one of the key instruments in making jumbo planes. The machine can produce aircraft components such as wing spars, landing gear supports and armor plates. Superpower nations such as USA, Russia, Germany, Japan, Korea and China have large die hydraulic press which can press 50,000 tons. In Malaysia, heavy-duty press is available from companies such as Proton that builds chassis for cars. However, that heavy-duty press is not able to produce better bulkhead for engines, fuselage, and wings of an aircraft. This paper presents the design of an apparatus that uses 50 grams of commercial grade explosives to produce 6000 tons of compaction. This is a first step towards producing larger scale apparatus that can produce 50,000-ton press. The design was done using AUTODYN blast simulation software. According to the results, the maximum load the apparatus can withstand was 6000 tons which was contributed by 50 grams of commercial explosive(Emulex). Explosive size larger than 50 grams will lead to catastrophic failure. Fabrication of the apparatus was completed. However, testing of the apparatus is not presented in this article.

  1. 10'000 ton ALICE gets her UK-built "Brain"

    CERN Multimedia

    Maddock, Julia

    2007-01-01

    For one of the four LEP experiments, called ALICE, the process got a step closer last week when a crucial part of the 10'000-ton detector, the British-built Central Trigger Processor (CTP), was installed in the ALICE cavern, some 150 feet underground. (plus background information about ALICE) (2,5 pages)

  2. Structure-activity correlations for TON, FER and MOR in the hydroisomerization of n-butane

    NARCIS (Netherlands)

    Pieterse, J.A.Z.; Seshan, Kulathuiyer; Lercher, J.A.

    2000-01-01

    n-Butane hydroconversion was studied over (Pt-loaded) molecular sieves with TON, FER, and MOR morphology. The conversion occurs via a complex interplay of mono- and bimolecular bifunctional acid mechanism and monofunctional platinum-catalyzed hydrogenolysis. Hydroisomerization occurs bimolecularly

  3. Applied molecular simulations over FER-, TON- and AEL-type zeolites

    NARCIS (Netherlands)

    Domokos, L.; Lefferts, Leonardus; Seshan, Kulathuiyer; Lercher, J.A.

    2001-01-01

    Interaction and transport of representative (un)saturated hydrocarbon molecules involved in the proposed reaction network of n-butene isomerization in zeolites FER, TON, and AEL have been studied by classic molecular modeling calculations. Docking of the guest molecules into the zeolite frameworks

  4. Optical flare observed in the flaring gamma-ray blazar Ton 599

    Science.gov (United States)

    Pursimo, Tapio; Sagues, Ana; Telting, John; Ojha, Roopesh

    2017-11-01

    We report optical photometry of the flat spectrum radio quasar Ton 599, obtained with the 2.56m Nordic Optical Telescope in La Palma, to look for any enhanced optical activity associated with a recent flare in the daily averaged gamma-ray flux (ATel#10931, ATel#10937).

  5. 2016 Billion-Ton Report: Advancing Domestic Resources for a Thriving Bioeconomy

    Energy Technology Data Exchange (ETDEWEB)

    None

    2016-07-06

    This product builds on previous efforts, namely the 2005 Billion-Ton Study (BTS) and the 2011 U.S. Billion-Ton Update (BT2).With each report, greater perspective is gained on the potential of biomass resources to contribute to a national energy strategy. Similarly, each successive report introduces new questions regarding commercialization challenges. BTS quantified the broad biophysical potential of biomass nationally, and BT2 elucidated the potential economic availability of these resources. These reports clearly established the potential availability of up to one billion tons of biomass resources nationally. However, many questions remain, including but not limited to crop yields, climate change impacts, logistical operations, and systems integration across production, harvest, and conversion. The present report aims to address many of these questions through empirically modeled energy crop yields, scenario analysis of resources delivered to biorefineries, and the addition of new feedstocks. Volume 2 of the 2016 Billion-Ton Report is expected to be released by the end of 2016. It seeks to evaluate environmental sustainability indicators of select scenarios from volume 1 and potential climate change impacts on future supplies.

  6. Potentiometric titration of molybdenum (6) with a cathode-polarized solid electrode

    International Nuclear Information System (INIS)

    Boeva, L.V.; Kimstach, V.A.; Bagdasarov, K.N.

    1980-01-01

    The possibility has been studied of using solid electrodes for potentiometric precipitation titration of molybdenum (6). A cathode-polarized electrode, electrochemically covered with a molybdenum blue layer, can be used as indicator electrode. The best results were obtained during deposition of molybdenum blue on a tungsten electrode. The mechanism of electrode work during titration has been investigated. A procedure has been developed of titration of molybdenum (6) in acid solutions using hydroxylamine N-aryl derivatives as titrants

  7. Molybdenum Cycling During Crust Formation and Destruction

    Science.gov (United States)

    Greaney, A. T.; Rudnick, R. L.

    2016-12-01

    Molybdenum geochemistry has become an important tool for tracking the redox state of the early atmosphere and oceans as well as the emergence and sustainability of Mo-cofactored enzymes. However, in order for Mo to be enriched in the oceans, it must first be weathered out of the crust. Sulfides that weather in the presence of atmospheric O2have historically been deemed the predominant crustal source of Mo. Here, we test this assumption by determining the mineralogical hosts of Mo in Archean, Proterozoic, and Phanerozoic upper crustal rocks, using LA-ICP-MS. We also investigate Mo behavior during igneous differentiation and continental crust formation. We find that molybdenite, MoS2, is a weatherable sulfide source of Mo, but common igneous sulfides are not because their Mo concentrations are too low. However, molybdenite is uncommon in the upper continental crust. By contrast, volcanic glass is much more abundant and is a significant weatherable source of Mo that readily breaks down to release oxidized, soluble Mo whether or not atmospheric O2is present. Other common crustal mineral hosts of Mo are Ti-bearing phases like titanite, ilmenite, magnetite, and rutile that are resistant to weathering. Significant Mo depletion (relative to Ce and Pr) is observed in nearly every granitic rock analyzed in our study, but is not observed in OIB or MORB (Jenner and O'Neill, 2012). There are two possible reasons for this: 1) Mo is removed from cooling plutons during fluid expulsion, or 2) Mo is fractionated during igneous differentiation. The first scenario is a likely explanation given the solubility of oxidized Mo. However, correlations between Mo/Ce and Nb/La in several plutonic suites suggest a fractionating phase like rutile may sequester Mo in the lower crust. Additionally, a correlation between Mo/Ce and inferred tectonic setting (enrichments observed in rift-related plutons) suggest an overall tectonic influence on the availability of Mo in the upper crust.

  8. Confined Mobility of TonB and FepA in Escherichia coli Membranes.

    Directory of Open Access Journals (Sweden)

    Yoriko Lill

    Full Text Available The important process of nutrient uptake in Escherichia coli, in many cases, involves transit of the nutrient through a class of beta-barrel proteins in the outer membrane known as TonB-dependent transporters (TBDTs and requires interaction with the inner membrane protein TonB. Here we have imaged the mobility of the ferric enterobactin transporter FepA and TonB by tracking them in the membranes of live E. coli with single-molecule resolution at time-scales ranging from milliseconds to seconds. We employed simple simulations to model/analyze the lateral diffusion in the membranes of E.coli, to take into account both the highly curved geometry of the cell and artifactual effects expected due to finite exposure time imaging. We find that both molecules perform confined lateral diffusion in their respective membranes in the absence of ligand with FepA confined to a region [Formula: see text] μm in radius in the outer membrane and TonB confined to a region [Formula: see text] μm in radius in the inner membrane. The diffusion coefficient of these molecules on millisecond time-scales was estimated to be [Formula: see text] μm2/s and [Formula: see text] μm2/s for FepA and TonB, respectively, implying that each molecule is free to diffuse within its domain. Disruption of the inner membrane potential, deletion of ExbB/D from the inner membrane, presence of ligand or antibody to FepA and disruption of the MreB cytoskeleton was all found to further restrict the mobility of both molecules. Results are analyzed in terms of changes in confinement size and interactions between the two proteins.

  9. A ton is not always a ton: A road-test of landfill, manure, and afforestation/reforestation offset protocols in the U.S. carbon market

    International Nuclear Information System (INIS)

    Lee, Carrie M.; Lazarus, Michael; Smith, Gordon R.; Todd, Kimberly; Weitz, Melissa

    2013-01-01

    Highlights: • Protocols are the foundation of an offset program. • Using sample projects, we “road test” landfill, manure and afforestation protocols from 5 programs. • For a given project, we find large variation in the volume of offsets generated. • Harmonization of protocols can increase the likelihood that “a ton is a ton”. • Harmonization can enhance prospects for linking emission trading systems. -- Abstract: The outcome of recent international climate negotiations suggests we are headed toward a more fragmented carbon market, with multiple emission trading and offset programs operating in parallel. To effectively harmonize and link across programs, it will be important to ensure that across offset programs and protocols that a “ton is a ton”. In this article, we consider how sample offsets projects in the U.S. carbon market are treated across protocols from five programs: the Clean Development Mechanism, Climate Action Reserve, Chicago Climate Exchange, Regional Greenhouse Gas Initiative, and the U.S. EPA's former program, Climate Leaders. We find that differences among protocols for landfill methane, manure management, and afforestation/reforestation project types in accounting boundary definitions, baseline setting methods, measurement rules, emission factors, and discounts lead to differences in offsets credited that are often significant (e.g. greater than 50%). We suggest opportunities for modification and harmonization of protocols that can improve offset quality and credibility and enhance prospects for future linking of trading units and systems

  10. Study of defects near molybdenum surface using thermal desorption spectrometer

    International Nuclear Information System (INIS)

    Naik, P.K.

    1980-01-01

    Thermal desorption spectrometry is utilized to study the migration of atoms and defects near molybdenum surface. The thermal desorption spectra of inert gas ions (neon, argon and krypton) injected with various energies (430-1950 eV) into a polycrystalline molybdenum target with various dosages (6.4 x 10sup(12) - 3.9 x 10sup(14) ions/cmsup(2)) are investigated. Four different states of binding of the trapped atoms corresponding to the activation energies for desorption have been revealed from the spectra. The activation energies are found to be relatively insensitive to the species of the bombarding ion, incident ion energy and the dosage. The patterns of the spectra are strongly influenced by the mean projected range of the ions into the solid. The activation energies deduced are in good agreement with those reported for the migration of atoms and defects in molybdenum. (auth.)

  11. Targets for the production of neutron activated molybdenum-99

    International Nuclear Information System (INIS)

    Hetherington, E.L.R.; Boyd, R.E.

    1999-01-01

    Neutron activation of natural molybdenum is, ostensibly, the least complex route to 99m Tc. However in most commercial generators the severe limitation in 99 Mo specific activity that the route imposes has caused manufacturers to choose the alternative fission process despite its disadvantages of being more expensive and requiring a more complex waste management strategy. The development of a newer generator technology is capable of reviving the demand for neutron activated 99 Mo and might encourage the production of 99m Tc by countries possessing less developed nuclear infrastructures. The targets used in the (n,γ) production route consist of analytical grade molybdenum trioxide which has been further refined to remove both rhenium and tungsten trace impurities. The basic methods used by ANSTO to produce a molybdenum target capable of yielding 99m Tc of high radionuclidic purity are described. (author)

  12. Microstructures define melting of molybdenum at high pressures

    Science.gov (United States)

    Hrubiak, Rostislav; Meng, Yue; Shen, Guoyin

    2017-03-01

    High-pressure melting anchors the phase diagram of a material, revealing the effect of pressure on the breakdown of the ordering of atoms in the solid. An important case is molybdenum, which has long been speculated to undergo an exceptionally steep increase in melting temperature when compressed. On the other hand, previous experiments showed nearly constant melting temperature as a function of pressure, in large discrepancy with theoretical expectations. Here we report a high-slope melting curve in molybdenum by synchrotron X-ray diffraction analysis of crystalline microstructures, generated by heating and subsequently rapidly quenching samples in a laser-heated diamond anvil cell. Distinct microstructural changes, observed at pressures up to 130 gigapascals, appear exclusively after melting, thus offering a reliable melting criterion. In addition, our study reveals a previously unsuspected transition in molybdenum at high pressure and high temperature, which yields highly textured body-centred cubic nanograins above a transition temperature.

  13. Molybdenum erosion measurements in Alcator C-Mod

    Energy Technology Data Exchange (ETDEWEB)

    Wampler, W.R. [Sandia National Labs., Albuquerque, NM (United States); LaBombard, B.; Lipshultz, B.; Pappas, D.; Pitcher, C.S. [Massachusetts Inst. of Tech., Cambridge, MA (United States); McCracken, G.M. [JET Joint Undertaking, Abingdon (United Kingdom)

    1998-05-01

    Erosion of molybdenum was measured on a set of 21 tiles after a run campaign of 1,090 shots in the Alcator C-Mod tokamak. The net erosion of molybdenum, was determined from changes in the depth of a thin chromium marker layer measured by Rutherford backscattering. Net Mo erosion was found to be approximately 150 nm near the outer divertor strike point, and much less everywhere else. Gross erosion rates by sputtering were estimated using ion energies and fluxes obtained from Langmuir probe measurements of edge-plasma conditions. Predicted net erosion using calculated gross erosion with prompt redeposition and measured net erosion agree within a factor of 3. Sputtering by boron and molybdenum impurities dominates erosion.

  14. A molybdenum disulfide/carbon nanotube heterogeneous complementary inverter.

    Science.gov (United States)

    Huang, Jun; Somu, Sivasubramanian; Busnaina, Ahmed

    2012-08-24

    We report a simple, bottom-up/top-down approach for integrating drastically different nanoscale building blocks to form a heterogeneous complementary inverter circuit based on layered molybdenum disulfide and carbon nanotube (CNT) bundles. The fabricated CNT/MoS(2) inverter is composed of n-type molybdenum disulfide (MOS(2)) and p-type CNT transistors, with a high voltage gain of 1.3. The CNT channels are fabricated using directed assembly while the layered molybdenum disulfide channels are fabricated by mechanical exfoliation. This bottom-up fabrication approach for integrating various nanoscale elements with unique characteristics provides an alternative cost-effective methodology to complementary metal-oxide-semiconductors, laying the foundation for the realization of high performance logic circuits.

  15. Experiment on bio-leaching of associated molybdenum and uranium ore

    International Nuclear Information System (INIS)

    Zheng Ying; Fan Baotuan; Liu Jian; Meng Yunsheng; Liu Chao

    2007-01-01

    Column leaching experiment results on associated molybdenum uranium ore by bacteria (T. f) are introduced. The ore are leached for 210 days using bacteria domesticated to tolerate molybdenum, the leaching of uranium is of 98% and leaching of molybdenum is of 41%. Sulphuric acid produced by bio-oxidation of sulfides in ore can meet the demand of ore leaching. (authors)

  16. Composite sheet made of molybdenum and dispersion-strengthened copper

    International Nuclear Information System (INIS)

    Nicholson, R.D.; Fusco, R.S.

    1990-01-01

    This patent describes a roll-bonded composite sheet product having at least one layer of dispersion-strengthened copper and at least one layer of molybdenum. The composite is characterized by a sharply defined, cleavage-resistant interface between the copper and the molybdenum with substantially no detectable diffusion of one metal into the other across the interface. The composite is resistant to delamination and being capable of maintaining structural integrity upon repeated high temperature firings at temperatures up to 900 degrees C

  17. Recovery of uranium from sulphate solutions containing molybdenum

    International Nuclear Information System (INIS)

    Weir, D.R.; Genik-Sas-Berezowsky, R.M.

    1983-01-01

    A process for recovering uranium from a sulphate solution containing dissolved uranium and molybdenum includes reacting the solution with ammonia (pH 8 to 10), the pH of the original solution must not exceed 5.5 and after the addition of ammonia the pH must not be in the vicinity of 7 for a significant time. The resultant uranium precipitate is relatively uncontaminated by molybdenum. The precipitate is then separated from the remaining solution while the pH is maintained within the stated range

  18. Electrochemistry and biochemistry of molybdenum. Ehlektrokhimiya i biokhimiya molibdena

    Energy Technology Data Exchange (ETDEWEB)

    Ryzhov, A M; Zajtsev, P M; Mambetkaziev, E A; Zhdanov, S I

    1992-07-01

    Using the review of data on polarographic behaviour of double and ternary systems molybdenum(6)-oxidant-organic ligand (oxy- and aminoacids of protein composition) by way of example, the possibility to use the metal ferments for the study of peculiarities in behaviour of the metal ions manifested in reactions was considered. The content of molybdenum in organism is noticeably different for healthy people and patients with malignant neoplasms and diabetes mellitus. There is a certain relation between catalytic activity of the metal ions and multiplicity of their accumulation in human organism.

  19. Nitrogen incorporation in sputter deposited molybdenum nitride thin films

    Energy Technology Data Exchange (ETDEWEB)

    Stöber, Laura, E-mail: laura.stoeber@tuwien.ac.at; Patocka, Florian, E-mail: florian.patocka@tuwien.ac.at; Schneider, Michael, E-mail: michael.schneider@tuwien.ac.at; Schmid, Ulrich, E-mail: ulrich.e366.schmid@tuwien.ac.at [Institute of Sensor and Actuator Systems, TU Wien, Gußhausstraße 27-29, A-1040 Vienna (Austria); Konrath, Jens Peter, E-mail: jenspeter.konrath@infineon.com; Haberl, Verena, E-mail: verena.haberl@infineon.com [Infineon Technologies Austria AG, Siemensstraße 2, 9500 Villach (Austria)

    2016-03-15

    In this paper, the authors report on the high temperature performance of sputter deposited molybdenum (Mo) and molybdenum nitride (Mo{sub 2}N) thin films. Various argon and nitrogen gas compositions are applied for thin film synthetization, and the amount of nitrogen incorporation is determined by Auger measurements. Furthermore, effusion measurements identifying the binding conditions of the nitrogen in the thin film are performed up to 1000 °C. These results are in excellent agreement with film stress and scanning electron microscope analyses, both indicating stable film properties up to annealing temperatures of 500 °C.

  20. A review of chromium, molybdenum, and tungsten alloys

    International Nuclear Information System (INIS)

    Klopp, W.D.

    1975-01-01

    The mechanical properties of chromium, molybdenum, and tungsten alloys are reviewed, with particular emphasis on high-temperature strength and low-temperature ductility. Precipitate strengthening is highly effective at 0.4-0.8 Tsub(m) in these metals, with HfC being most effective in tungsten and molybdenum, and Ta(B,C) most effective in chromium. Low-temperature ductility can be improved by alloying to promote rhenium ductilizing or solution softening. The low-temperature mechanical properties of these alloys appear related to electronic interactions rather than to the usual metallurgical considerations. (Auth.)

  1. Selective emission multilayer coatings for a molybdenum thermophotovoltaic radiator

    Science.gov (United States)

    Cockeram, Brian Vern

    2004-01-27

    Multilayer coating designs have been developed to provide selective emission for a molybdenum thermophotovoltaic (TPV) radiator surface. These coatings increase the surface emissivity of a molybdenum TPV radiator substrate in the wavelength range that matches the bandgap of the TPV cells to increase the power density of the TPV system. Radiator emission at wavelengths greater than the bandgap energy of the TPV cells is greatly reduced through the use of these coatings, which significantly increases the efficiency of the TPV system. The use of this coating greatly improves the performance of a TPV system, and the coating can be tailored to match the bandgap of any practical TPV system.

  2. Preparation and characterization of molybdenum disilicide coating on molybdenum substrate by air plasma spraying

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Yi [Key Laboratory of Ministry of Education for Non-ferrous Materials Science and Engineering, Central South University, Changsha 410083 (China); Key Laboratory of Hunan Province for Metallurgy and Material Processing of Rare Metals, Central South University, Changsha 410083 (China); School of Materials Science and Engineering, Central South University, Changsha 410083 (China); Wang, Dezhi, E-mail: dzwang68@163.com [Key Laboratory of Ministry of Education for Non-ferrous Materials Science and Engineering, Central South University, Changsha 410083 (China); Key Laboratory of Hunan Province for Metallurgy and Material Processing of Rare Metals, Central South University, Changsha 410083 (China); School of Materials Science and Engineering, Central South University, Changsha 410083 (China); Yan, Jianhui [Advanced Materials Synthesis and Application Technology Laboratory, Hunan University of Science and Technology, Xiangtan 411201 (China); Sun, Aokui [Key Laboratory of Ministry of Education for Non-ferrous Materials Science and Engineering, Central South University, Changsha 410083 (China); Key Laboratory of Hunan Province for Metallurgy and Material Processing of Rare Metals, Central South University, Changsha 410083 (China); School of Materials Science and Engineering, Central South University, Changsha 410083 (China)

    2013-11-01

    MoSi{sub 2} oxidation protective coatings on molybdenum substrate were prepared by air plasma spraying technique (APS). Microstructure, phase composition, porosity, microhardness and bonding strength of the coatings were investigated and determined. Oxidation behavior of the coating at high temperature was also examined. Results show that composition of the coatings is constituted with MoSi{sub 2} and Mo{sub 5}Si{sub 3}, the surface morphology is described as flattened lamellar features, insufficiently flattened protuberance with some degree of surface roughness, a certain quantity of spherical particles, microcracks and pores. Testing results reveal that microhardness and bonding strength of the coatings increase, and porosity decreases with increasing power or decreasing Ar gas flow rate. Moreover, with decreasing the porosity, the microhardness of the coatings increases. The bonding strength of the coatings also increases with increasing spray distance. The MoSi{sub 2} coated Mo substrate exhibited a good oxidation resistance at 1200 °C.

  3. Preparation and characterization of molybdenum disilicide coating on molybdenum substrate by air plasma spraying

    International Nuclear Information System (INIS)

    Wang, Yi; Wang, Dezhi; Yan, Jianhui; Sun, Aokui

    2013-01-01

    MoSi 2 oxidation protective coatings on molybdenum substrate were prepared by air plasma spraying technique (APS). Microstructure, phase composition, porosity, microhardness and bonding strength of the coatings were investigated and determined. Oxidation behavior of the coating at high temperature was also examined. Results show that composition of the coatings is constituted with MoSi 2 and Mo 5 Si 3 , the surface morphology is described as flattened lamellar features, insufficiently flattened protuberance with some degree of surface roughness, a certain quantity of spherical particles, microcracks and pores. Testing results reveal that microhardness and bonding strength of the coatings increase, and porosity decreases with increasing power or decreasing Ar gas flow rate. Moreover, with decreasing the porosity, the microhardness of the coatings increases. The bonding strength of the coatings also increases with increasing spray distance. The MoSi 2 coated Mo substrate exhibited a good oxidation resistance at 1200 °C.

  4. Catalytic hydrotreatment of Illinois No. 6 coal-derived naphtha: comparison of molybdenum nitride and molybdenum sulfide for heteroatom removal

    Energy Technology Data Exchange (ETDEWEB)

    Raje, A.; Liaw, S.J.; Chary, K.V.R.; Davis, B.H. [University of Kentucky, Lexington, KY (United States). Center for Applied Energy Research

    1995-03-16

    The hydrotreatment of naphtha derived from Illinois No. 6 coal was investigated using molybdenum sulfide and nitride catalysts. The two catalysts are compared on the basis of total catalyst weight. Molybdenum sulfide is more active than molybdenum nitride for hydrodesulfurization (HDS) of a coal-derived naphtha. The rate of hydrodeoxygenation (HDO) of the naphtha over both catalysts are comparable. For hydrodenitrogenation (HDN), the sulfide is more active than the nitride only at higher temperatures ({gt}325{degree}C). Based upon conversion data, the naphtha can be lumped into a reactive and a less reactive fraction with each following first-order kinetics for heteroatom removal. The HDS and HDN rates and activation energies of the less reactive lump are smaller for the nitride than for the sulfide catalyst.

  5. Group covariance and metrical theory

    International Nuclear Information System (INIS)

    Halpern, L.

    1983-01-01

    The a priori introduction of a Lie group of transformations into a physical theory has often proved to be useful; it usually serves to describe special simplified conditions before a general theory can be worked out. Newton's assumptions of absolute space and time are examples where the Euclidian group and translation group have been introduced. These groups were extended to the Galilei group and modified in the special theory of relativity to the Poincare group to describe physics under the given conditions covariantly in the simplest way. The criticism of the a priori character leads to the formulation of the general theory of relativity. The general metric theory does not really give preference to a particular invariance group - even the principle of equivalence can be adapted to a whole family of groups. The physical laws covariantly inserted into the metric space are however adapted to the Poincare group. 8 references

  6. General relativity: An erfc metric

    Science.gov (United States)

    Plamondon, Réjean

    2018-06-01

    This paper proposes an erfc potential to incorporate in a symmetric metric. One key feature of this model is that it relies on the existence of an intrinsic physical constant σ, a star-specific proper length that scales all its surroundings. Based thereon, the new metric is used to study the space-time geometry of a static symmetric massive object, as seen from its interior. The analytical solutions to the Einstein equation are presented, highlighting the absence of singularities and discontinuities in such a model. The geodesics are derived in their second- and first-order differential formats. Recalling the slight impact of the new model on the classical general relativity tests in the solar system, a number of facts and open problems are briefly revisited on the basis of a heuristic definition of σ. A special attention is given to gravitational collapses and non-singular black holes.

  7. hdm: High-dimensional metrics

    OpenAIRE

    Chernozhukov, Victor; Hansen, Christian; Spindler, Martin

    2016-01-01

    In this article the package High-dimensional Metrics (\\texttt{hdm}) is introduced. It is a collection of statistical methods for estimation and quantification of uncertainty in high-dimensional approximately sparse models. It focuses on providing confidence intervals and significance testing for (possibly many) low-dimensional subcomponents of the high-dimensional parameter vector. Efficient estimators and uniformly valid confidence intervals for regression coefficients on target variables (e...

  8. Multi-Metric Sustainability Analysis

    Energy Technology Data Exchange (ETDEWEB)

    Cowlin, Shannon [National Renewable Energy Lab. (NREL), Golden, CO (United States); Heimiller, Donna [National Renewable Energy Lab. (NREL), Golden, CO (United States); Macknick, Jordan [National Renewable Energy Lab. (NREL), Golden, CO (United States); Mann, Margaret [National Renewable Energy Lab. (NREL), Golden, CO (United States); Pless, Jacquelyn [National Renewable Energy Lab. (NREL), Golden, CO (United States); Munoz, David [Colorado School of Mines, Golden, CO (United States)

    2014-12-01

    A readily accessible framework that allows for evaluating impacts and comparing tradeoffs among factors in energy policy, expansion planning, and investment decision making is lacking. Recognizing this, the Joint Institute for Strategic Energy Analysis (JISEA) funded an exploration of multi-metric sustainability analysis (MMSA) to provide energy decision makers with a means to make more comprehensive comparisons of energy technologies. The resulting MMSA tool lets decision makers simultaneously compare technologies and potential deployment locations.

  9. Sensory Metrics of Neuromechanical Trust.

    Science.gov (United States)

    Softky, William; Benford, Criscillia

    2017-09-01

    Today digital sources supply a historically unprecedented component of human sensorimotor data, the consumption of which is correlated with poorly understood maladies such as Internet addiction disorder and Internet gaming disorder. Because both natural and digital sensorimotor data share common mathematical descriptions, one can quantify our informational sensorimotor needs using the signal processing metrics of entropy, noise, dimensionality, continuity, latency, and bandwidth. Such metrics describe in neutral terms the informational diet human brains require to self-calibrate, allowing individuals to maintain trusting relationships. With these metrics, we define the trust humans experience using the mathematical language of computational models, that is, as a primitive statistical algorithm processing finely grained sensorimotor data from neuromechanical interaction. This definition of neuromechanical trust implies that artificial sensorimotor inputs and interactions that attract low-level attention through frequent discontinuities and enhanced coherence will decalibrate a brain's representation of its world over the long term by violating the implicit statistical contract for which self-calibration evolved. Our hypersimplified mathematical understanding of human sensorimotor processing as multiscale, continuous-time vibratory interaction allows equally broad-brush descriptions of failure modes and solutions. For example, we model addiction in general as the result of homeostatic regulation gone awry in novel environments (sign reversal) and digital dependency as a sub-case in which the decalibration caused by digital sensorimotor data spurs yet more consumption of them. We predict that institutions can use these sensorimotor metrics to quantify media richness to improve employee well-being; that dyads and family-size groups will bond and heal best through low-latency, high-resolution multisensory interaction such as shared meals and reciprocated touch; and

  10. Metric reconstruction from Weyl scalars

    Energy Technology Data Exchange (ETDEWEB)

    Whiting, Bernard F; Price, Larry R [Department of Physics, PO Box 118440, University of Florida, Gainesville, FL 32611 (United States)

    2005-08-07

    The Kerr geometry has remained an elusive world in which to explore physics and delve into the more esoteric implications of general relativity. Following the discovery, by Kerr in 1963, of the metric for a rotating black hole, the most major advance has been an understanding of its Weyl curvature perturbations based on Teukolsky's discovery of separable wave equations some ten years later. In the current research climate, where experiments across the globe are preparing for the first detection of gravitational waves, a more complete understanding than concerns just the Weyl curvature is now called for. To understand precisely how comparatively small masses move in response to the gravitational waves they emit, a formalism has been developed based on a description of the whole spacetime metric perturbation in the neighbourhood of the emission region. Presently, such a description is not available for the Kerr geometry. While there does exist a prescription for obtaining metric perturbations once curvature perturbations are known, it has become apparent that there are gaps in that formalism which are still waiting to be filled. The most serious gaps include gauge inflexibility, the inability to include sources-which are essential when the emitting masses are considered-and the failure to describe the l = 0 and 1 perturbation properties. Among these latter properties of the perturbed spacetime, arising from a point mass in orbit, are the perturbed mass and axial component of angular momentum, as well as the very elusive Carter constant for non-axial angular momentum. A status report is given on recent work which begins to repair these deficiencies in our current incomplete description of Kerr metric perturbations.

  11. Metric reconstruction from Weyl scalars

    International Nuclear Information System (INIS)

    Whiting, Bernard F; Price, Larry R

    2005-01-01

    The Kerr geometry has remained an elusive world in which to explore physics and delve into the more esoteric implications of general relativity. Following the discovery, by Kerr in 1963, of the metric for a rotating black hole, the most major advance has been an understanding of its Weyl curvature perturbations based on Teukolsky's discovery of separable wave equations some ten years later. In the current research climate, where experiments across the globe are preparing for the first detection of gravitational waves, a more complete understanding than concerns just the Weyl curvature is now called for. To understand precisely how comparatively small masses move in response to the gravitational waves they emit, a formalism has been developed based on a description of the whole spacetime metric perturbation in the neighbourhood of the emission region. Presently, such a description is not available for the Kerr geometry. While there does exist a prescription for obtaining metric perturbations once curvature perturbations are known, it has become apparent that there are gaps in that formalism which are still waiting to be filled. The most serious gaps include gauge inflexibility, the inability to include sources-which are essential when the emitting masses are considered-and the failure to describe the l = 0 and 1 perturbation properties. Among these latter properties of the perturbed spacetime, arising from a point mass in orbit, are the perturbed mass and axial component of angular momentum, as well as the very elusive Carter constant for non-axial angular momentum. A status report is given on recent work which begins to repair these deficiencies in our current incomplete description of Kerr metric perturbations

  12. Implications of\tenhanced\teffectiveness\tof\tvincristine\tsulfate/ε-viniferin combination\tcompared\tto\tvincristine\tsulfate\tonly\ton\tHepG2\tcells

    Directory of Open Access Journals (Sweden)

    Filiz\tÖzdemir

    2016-12-01

    Full Text Available Objective: This\tstudy\twas\tdesigned\tto\tinvestigate\tthe\teffects\tof\tε-viniferin\t(ε-VNF\ton\tthe\tmitochondrial\tpathway\tof\tapoptosis and\ton\tlate\tapoptosis\tin\tHepG2\tcell\tlines.\tTo\tobserve\tthese\teffects,\tε-VNF\tand\tvincristine\tsulfate\t(VNC,\tanti-cancer\tdrugs\tused for\ttreatment\ton\tHepG2\tcells,\twere\tadministered\teither\talone\tor\tin\tcombination\tat\tdifferent\ttime\tintervals. Methods:\tMitochondrial\tmembrane\tpotential\tchanges\tin\tthe\tcells\t(ΔΨm\twere\tevaluated\tusing\tcationic\tdye\tJC-1,\twhile\tBax,\tBcl- 2\texpression\tlevels\twith\tRT-PCR\tand\tcaspase-3\tactivity\twere\tanalyzed\tusing\ta\tkit.\tFor\tdetection\tof\tapoptotic\tactivity,\tan\tin\tsitu TUNEL\tassay\twas\tperformed. Results: When 98.3µM ε-VNF, 52.5µM VNC and the 11.25+15.8µM VNC+ε-VNF combination were compared with the control group,\tΔΨm\tchanges\tat\tthe\t6th\thour\twere\tfound\tto\tbe\t19.5%,\t5.5%,\t24.6%,\tand\t3.5%\t,\trespectively.\tThese\tfinding\tshow\tthat\tthe combination\tgroup\t(24.6%\tresulted\tin\tearly\tapoptosis\tof\tthe\tcell\tat\tthe\t6th\thour.\tBax\tmRNA\texpression\tincreased\tat\tthe\t24th hour in the VNC+ε-VNF group compared to control group (160%, and caspase-3 activation increased in the 1.25+15.8 µM[VNC+ε-VNF]\tgroup\tcompared\tto\tthe\tcontrol\tgroup\tat\tthe\t48th\thour.\tThe\tdetection\tof\tDNA\tfragments\tin\tHepG2\tcells\twithin 24\thours\tsuggests\tdirect\tapoptosis. Conclusion: These findings demonstrate that the doses administered to the VNC+ε-VNF combination group\twere\tlower than those\tadministered\tto\tgroups\tusing\tone\tagent\talone\t(e.g.\tVNC,\tthe\tresults\tof\twhich\treduce\tthe\tpossibility\tof\tadministering\ttoxic doses.

  13. Sustainability Metrics: The San Luis Basin Project

    Science.gov (United States)

    Sustainability is about promoting humanly desirable dynamic regimes of the environment. Metrics: ecological footprint, net regional product, exergy, emergy, and Fisher Information. Adaptive management: (1) metrics assess problem, (2) specific problem identified, and (3) managemen...

  14. 50 CFR Table 1b to Part 660... - 2009, Harvest Guidelines for Minor Rockfish by Depth Sub-groups (weights in metric tons)

    Science.gov (United States)

    2010-10-01

    ... population in the California Current ecosystem, a non-quantitative assessment was conducted in 2007. The... 50 percent of the 2008 ABC and OY values. The stock is expected to remain at its current equilibrium... catcher/processors, 60.0 mt for motherships, and 105.0 mt for shore-based. r Canary rockfish—A canary...

  15. 50 CFR Table 1c to Part 660... - 2009, Open Access and Limited Entry Allocations by Species or Species Group (weights in metric tons)

    Science.gov (United States)

    2010-10-01

    ... population in the California Current ecosystem, a non-quantitative assessment was conducted in 2007. The... 50 percent of the 2008 ABC and OY values. The stock is expected to remain at its current equilibrium... fishery: 85.0 mt for catcher/processors, 60.0 mt for motherships, and 105.0 mt for shore-based. r/ Canary...

  16. 50 CFR Table 2b to Part 660... - 2010, and Beyond, Harvest Guidelines for Minor Rockfish by Depth Sub-groups (weights in metric tons)

    Science.gov (United States)

    2010-10-01

    ... unexploited rockfish population in the California Current ecosystem, a non-quantitative assessment was... current equilibrium with these harvest specifications. q Widow rockfish was assessed in 2005, and an... Canary rockfish—A canary rockfish stock assessment was completed in 2007 and the stock was estimated to...

  17. Cleavage and formation of molecular dinitrogen in a single system assisted by molybdenum complexes bearing ferrocenyldiphosphine.

    Science.gov (United States)

    Miyazaki, Takamasa; Tanaka, Hiromasa; Tanabe, Yoshiaki; Yuki, Masahiro; Nakajima, Kazunari; Yoshizawa, Kazunari; Nishibayashi, Yoshiaki

    2014-10-20

    The N≡N bond of molecular dinitrogen bridging two molybdenum atoms in the pentamethylcyclopentadienyl molybdenum complexes that bear ferrocenyldiphosphine as an auxiliary ligand is homolytically cleaved under visible light irradiation at room temperature to afford two molar molybdenum nitride complexes. Conversely, the bridging molecular dinitrogen is reformed by the oxidation of the molybdenum nitride complex at room temperature. This result provides a successful example of the cleavage and formation of molecular dinitrogen induced by a pair of two different external stimuli using a single system assisted by molybdenum complexes bearing ferrocenyldiphosphine under ambient conditions. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  18. Activity of molybdenum-containing oxide catalysts in the reaction of ethane oxidation

    International Nuclear Information System (INIS)

    Konovalov, V.I.; Ehpova, T.I.; Shchukin, V.P.; Averbukh, A.Ya.

    1977-01-01

    Investigation results concerning the catalytic activity of molybdenum-containing catalysts in ethane oxidation reaction are presented. It has been found that the greatest activity in the temperature range from 450 to 600 deg C is exhibited by cobalt-molybdenum catalyst; at 600 deg C bismuth-molybdenum catalyst is the most active. Nickel-molybdenum catalyst is selective and active with respect to ethylene. Iron- and manganese-molybdenum catalysts do not show high ethane oxidation rates and their selectivity is insignificant

  19. In vivo evidence of TonB shuttling between the cytoplasmic and outer membrane in Escherichia coli.

    Science.gov (United States)

    Larsen, Ray A; Letain, Tracy E; Postle, Kathleen

    2003-07-01

    Gram-negative bacteria are able to convert potential energy inherent in the proton gradient of the cytoplasmic membrane into active nutrient transport across the outer membrane. The transduction of energy is mediated by TonB protein. Previous studies suggest a model in which TonB makes sequential and cyclic contact with proteins in each membrane, a process called shuttling. A key feature of shuttling is that the amino-terminal signal anchor must quit its association with the cytoplasmic membrane, and TonB becomes associated solely with the outer membrane. However, the initial studies did not exclude the possibility that TonB was artifactually pulled from the cytoplasmic membrane by the fractionation process. To resolve this ambiguity, we devised a method to test whether the extreme TonB amino-terminus, located in the cytoplasm, ever became accessible to the cys-specific, cytoplasmic membrane-impermeant molecule, Oregon Green(R) 488 maleimide (OGM) in vivo. A full-length TonB and a truncated TonB were modified to carry a sole cysteine at position 3. Both full-length TonB and truncated TonB (consisting of the amino-terminal two-thirds) achieved identical conformations in the cytoplasmic membrane, as determined by their abilities to cross-link to the cytoplasmic membrane protein ExbB and their abilities to respond conformationally to the presence or absence of proton motive force. Full-length TonB could be amino-terminally labelled in vivo, suggesting that it was periplasmically exposed. In contrast, truncated TonB, which did not associate with the outer membrane, was not specifically labelled in vivo. The truncated TonB also acted as a control for leakage of OGM across the cytoplasmic membrane. Further, the extent of labelling for full-length TonB correlated roughly with the proportion of TonB found at the outer membrane. These findings suggest that TonB does indeed disengage from the cytoplasmic membrane during energy transduction and shuttle to the outer membrane.

  20. Crowdsourcing metrics of digital collections

    Directory of Open Access Journals (Sweden)

    Tuula Pääkkönen

    2015-12-01

    Full Text Available In the National Library of Finland (NLF there are millions of digitized newspaper and journal pages, which are openly available via the public website  http://digi.kansalliskirjasto.fi. To serve users better, last year the front end was completely overhauled with its main aim in crowdsourcing features, e.g., by giving end-users the opportunity to create digital clippings and a personal scrapbook from the digital collections. But how can you know whether crowdsourcing has had an impact? How much crowdsourcing functionalities have been used so far? Did crowdsourcing work? In this paper the statistics and metrics of a recent crowdsourcing effort are analysed across the different digitized material types (newspapers, journals, ephemera. The subjects, categories and keywords given by the users are analysed to see which topics are the most appealing. Some notable public uses of the crowdsourced article clippings are highlighted. These metrics give us indications on how the end-users, based on their own interests, are investigating and using the digital collections. Therefore, the suggested metrics illustrate the versatility of the information needs of the users, varying from citizen science to research purposes. By analysing the user patterns, we can respond to the new needs of the users by making minor changes to accommodate the most active participants, while still making the service more approachable for those who are trying out the functionalities for the first time. Participation in the clippings and annotations can enrich the materials in unexpected ways and can possibly pave the way for opportunities of using crowdsourcing more also in research contexts. This creates more opportunities for the goals of open science since source data becomes ­available, making it possible for researchers to reach out to the general public for help. In the long term, utilizing, for example, text mining methods can allow these different end-user segments to

  1. A family of metric gravities

    Science.gov (United States)

    Shuler, Robert

    2018-04-01

    The goal of this paper is to take a completely fresh approach to metric gravity, in which the metric principle is strictly adhered to but its properties in local space-time are derived from conservation principles, not inferred from a global field equation. The global field strength variation then gains some flexibility, but only in the regime of very strong fields (2nd-order terms) whose measurement is now being contemplated. So doing provides a family of similar gravities, differing only in strong fields, which could be developed into meaningful verification targets for strong fields after the manner in which far-field variations were used in the 20th century. General Relativity (GR) is shown to be a member of the family and this is demonstrated by deriving the Schwarzschild metric exactly from a suitable field strength assumption. The method of doing so is interesting in itself because it involves only one differential equation rather than the usual four. Exact static symmetric field solutions are also given for one pedagogical alternative based on potential, and one theoretical alternative based on inertia, and the prospects of experimentally differentiating these are analyzed. Whether the method overturns the conventional wisdom that GR is the only metric theory of gravity and that alternatives must introduce additional interactions and fields is somewhat semantical, depending on whether one views the field strength assumption as a field and whether the assumption that produces GR is considered unique in some way. It is of course possible to have other fields, and the local space-time principle can be applied to field gravities which usually are weak-field approximations having only time dilation, giving them the spatial factor and promoting them to full metric theories. Though usually pedagogical, some of them are interesting from a quantum gravity perspective. Cases are noted where mass measurement errors, or distributions of dark matter, can cause one

  2. Hybrid metric-Palatini stars

    Science.gov (United States)

    Danilǎ, Bogdan; Harko, Tiberiu; Lobo, Francisco S. N.; Mak, M. K.

    2017-02-01

    We consider the internal structure and the physical properties of specific classes of neutron, quark and Bose-Einstein condensate stars in the recently proposed hybrid metric-Palatini gravity theory, which is a combination of the metric and Palatini f (R ) formalisms. It turns out that the theory is very successful in accounting for the observed phenomenology, since it unifies local constraints at the Solar System level and the late-time cosmic acceleration, even if the scalar field is very light. In this paper, we derive the equilibrium equations for a spherically symmetric configuration (mass continuity and Tolman-Oppenheimer-Volkoff) in the framework of the scalar-tensor representation of the hybrid metric-Palatini theory, and we investigate their solutions numerically for different equations of state of neutron and quark matter, by adopting for the scalar field potential a Higgs-type form. It turns out that the scalar-tensor definition of the potential can be represented as an Clairaut differential equation, and provides an explicit form for f (R ) given by f (R )˜R +Λeff, where Λeff is an effective cosmological constant. Furthermore, stellar models, described by the stiff fluid, radiation-like, bag model and the Bose-Einstein condensate equations of state are explicitly constructed in both general relativity and hybrid metric-Palatini gravity, thus allowing an in-depth comparison between the predictions of these two gravitational theories. As a general result it turns out that for all the considered equations of state, hybrid gravity stars are more massive than their general relativistic counterparts. Furthermore, two classes of stellar models corresponding to two particular choices of the functional form of the scalar field (constant value, and logarithmic form, respectively) are also investigated. Interestingly enough, in the case of a constant scalar field the equation of state of the matter takes the form of the bag model equation of state describing

  3. Metrics for Evaluation of Student Models

    Science.gov (United States)

    Pelanek, Radek

    2015-01-01

    Researchers use many different metrics for evaluation of performance of student models. The aim of this paper is to provide an overview of commonly used metrics, to discuss properties, advantages, and disadvantages of different metrics, to summarize current practice in educational data mining, and to provide guidance for evaluation of student…

  4. Context-dependent ATC complexity metric

    NARCIS (Netherlands)

    Mercado Velasco, G.A.; Borst, C.

    2015-01-01

    Several studies have investigated Air Traffic Control (ATC) complexity metrics in a search for a metric that could best capture workload. These studies have shown how daunting the search for a universal workload metric (one that could be applied in different contexts: sectors, traffic patterns,

  5. Properties of C-metric spaces

    Science.gov (United States)

    Croitoru, Anca; Apreutesei, Gabriela; Mastorakis, Nikos E.

    2017-09-01

    The subject of this paper belongs to the theory of approximate metrics [23]. An approximate metric on X is a real application defined on X × X that satisfies only a part of the metric axioms. In a recent paper [23], we introduced a new type of approximate metric, named C-metric, that is an application which satisfies only two metric axioms: symmetry and triangular inequality. The remarkable fact in a C-metric space is that a topological structure induced by the C-metric can be defined. The innovative idea of this paper is that we obtain some convergence properties of a C-metric space in the absence of a metric. In this paper we investigate C-metric spaces. The paper is divided into four sections. Section 1 is for Introduction. In Section 2 we recall some concepts and preliminary results. In Section 3 we present some properties of C-metric spaces, such as convergence properties, a canonical decomposition and a C-fixed point theorem. Finally, in Section 4 some conclusions are highlighted.

  6. Diabetes\tand\tdepression:\tA\treview\twith\tspecial\tfocus\ton\tIndia

    Directory of Open Access Journals (Sweden)

    Megha\tThakur

    2015-10-01

    Full Text Available Diabetes,\ta\tpsychologically\tchallenging\tcondition for the\tpatients\tand their care givers, has been found to be a significant risk factor for depression. Depression\tmay\tbe\ta\tcritical\tbarrier\tto\teffective\tdiabetes\tmanagement.\tThe accompanying\tfatigue\tremarkably\tlowers\tthe\tmotivation\tfor\tself-care,\toften leading to lowered physical and emotion well-being, poor markers of diabetes control, poor adherence to medication, and increased mortality among individuals with diabetes. A very small proportion of the diabetes patients\twith\tdepression\tget\tdiagnosed,\tand\tfurthermore,\tonly\ta\thandful\tof the ones diagnosed get treated for depression. Despite the fact that 80 percent\tof\tthe\tpeople\twith\ttype\t2\tdiabetes\treside\tin\tlow\tand\tmiddle\tincome\tcountries,\tmost\tof\tthe\tevidence\ton diabetes\tand\tdepression\tcomes\tfrom\thigh\tincome\tcountries.\tThis\treview\toffers\ta\tsummary\tof\texisting\tevidence and\tthe\tpotential\tgaps\tthat\tneed\tto\tbe\taddressed.

  7. Design and analysis of a 1-ton prototype of the Jinping Neutrino Experiment

    International Nuclear Information System (INIS)

    Wang, Zongyi; Wang, Yuanqing; Wang, Zhe; Chen, Shaomin; Du, Xinxi; Zhang, Tianxiong; Guo, Ziyi; Yuan, Huanxin

    2017-01-01

    The Jinping Neutrino Experiment will perform an in-depth research on solar neutrinos and geo-neutrinos. Two structural options (i.e., cylindrical and spherical schemes) are proposed for the Jinping detector based on other successful underground neutrino detectors. Several key factors in the design are also discussed in detail. A 1-ton prototype of the Jinping experiment is proposed based on physics requirements. Subsequently, the structural design, installation procedure, and mechanical analysis of the neutrino detector prototype are discussed. The results show that the maximum Mises stresses on the acrylic vessel, stainless steel truss, and the tank are all lower than the design values of the strengths. The stability requirement of the stainless steel truss in the detector prototype is satisfied. Consequently, the structural scheme for the 1-ton prototype is safe and reliable.

  8. Design and analysis of a 1-ton prototype of the Jinping Neutrino Experiment

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Zongyi, E-mail: wangzongyi1990@outlook.com [School of Civil Engineering, Wuhan University, Wuhan 430072 (China); Wang, Yuanqing [Key Laboratory of Civil Engineering Safety and Durability of Education Ministry, Tsinghua University, Beijing 100084 (China); Wang, Zhe; Chen, Shaomin [Department of Engineering Physics, Tsinghua University, Beijing 100084 (China); Du, Xinxi [School of Civil Engineering, Wuhan University, Wuhan 430072 (China); Zhang, Tianxiong [School of Civil Engineering, Tianjin University, Tianjin 300072 (China); Guo, Ziyi [Department of Engineering Physics, Tsinghua University, Beijing 100084 (China); Yuan, Huanxin [School of Civil Engineering, Wuhan University, Wuhan 430072 (China)

    2017-05-21

    The Jinping Neutrino Experiment will perform an in-depth research on solar neutrinos and geo-neutrinos. Two structural options (i.e., cylindrical and spherical schemes) are proposed for the Jinping detector based on other successful underground neutrino detectors. Several key factors in the design are also discussed in detail. A 1-ton prototype of the Jinping experiment is proposed based on physics requirements. Subsequently, the structural design, installation procedure, and mechanical analysis of the neutrino detector prototype are discussed. The results show that the maximum Mises stresses on the acrylic vessel, stainless steel truss, and the tank are all lower than the design values of the strengths. The stability requirement of the stainless steel truss in the detector prototype is satisfied. Consequently, the structural scheme for the 1-ton prototype is safe and reliable.

  9. 2016 Billion-Ton Report: Environmental Sustainability Effects of Select Scenarios from Volume 1 (Volume 2)

    Energy Technology Data Exchange (ETDEWEB)

    Efroymson, R. A. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Langholtz, M. H. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Johnson, K. E. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Stokes, B. J. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

    2017-01-13

    On behalf of all the authors and contributors, it is a great privilege to present the 2016 Billion-Ton Report (BT16), volume 2: Environmental Sustainability Effects of Select Scenarios from volume 1. This report represents the culmination of several years of collaborative effort among national laboratories, government agencies, academic institutions, and industry. BT16 was developed to support the U.S. Department of Energy’s efforts towards national goals of energy security and associated quality of life.

  10. Comportement d'un béton à hautes performances à base de laitier ...

    African Journals Online (AJOL)

    L'utilisation de béton à hautes performances (BHP) intégrant des ajouts cimentaires comme les cendres volantes, les fumées de silice ou le laitier hydraulique ... armatures qui sont, à leur tour attaquées. Il est possible de modifier la ... refroidissement brutal par l'eau sous pression, c'est un sable de granulométrie 0/5 mm.

  11. The design of steel string crane with lifting capacity 10 tons

    International Nuclear Information System (INIS)

    Syamsurrijal Ramdja

    2007-01-01

    The steel string (sling) used for lift Crane of type of Overhead Travelling Crane, with capacities lifting 10 ton are designed. If compared to other string type, string of steel have some excellence. At this design, election of type of string become primary and the factor of safety become prima facie matter with pursuant to up to date standard. From made of design, is hence got by specification and age of steel string. (author)

  12. Mine design for producing 100,000 tons per day of uranium-bearing Chattanooga Shale

    International Nuclear Information System (INIS)

    Hoe, H.L.

    1979-01-01

    Chattanooga Shale, underlying some 40,000 square miles in the southeastern United States, is considered to be a potentially large, low-grade source of uranium. The area in and near Dekalb County, Tennessee, appears to be the most likely site for commercial development. This paper deals with the mine design, mining procedures, equipment requirements, and operating maintenance costs for an underground mining complex capable of producing 100,000 tons of Chattanooga Shale per day for delivery to a beneficiation process

  13. Overall view of the AA hall dominated by the 50 ton crane (Donges).

    CERN Multimedia

    1980-01-01

    A 50 ton, 32 metre span overhead travelling cranre was mounted in one of the bays of Hall 193 (AA). An identical crane was mounted on the other bay. See also photo 8004261. For photos of the AA in different phases of completion (between 1979 and 1982) see: 7911303, 7911597X, 8004261, 8004608X, 8005563X, 8005565X, 8006716X, 8006722X, 8010939X, 8010941X, 8202324, 8202658X, 8203628X .

  14. Recovery of uranium and molybdenum elements from gebel gattar raw material, eastern desert, Egypt. Vol. 3

    International Nuclear Information System (INIS)

    El-Hazek, N.T.; Mahdy, M.A.; Mahmoud, H.M.K.

    1996-01-01

    G. Gatter uranium mineralizations are located along the faults and fracture zones crossing G.Gattar granitic pluton and long the contact of the pluton with the hammamat sediments. Also, molybdenum id presented in more than one mode of occurrence. The molybdenum mineralization treated in this work is the dessimenated type. The uranium and molybdenum raw material was subjected to series of leaching experiments including acid and alkaline agitation, alkaline percolation, and acid heap leaching techniques. Recovery of uranium and molybdenum was achieved by anion-exchange method followed by their elution by acidified sodium chloride. Uranium precipitation was performed in the form of ammonium diuranate (Yellow Cake). On the other hand molybdenum was precipitated in the form of molybdenum oxide. A tentative flowsheet for the extraction of both uranium and molybdenum is proposed and discussed. 13 figs., 3 tabs

  15. Recovery of uranium and molybdenum elements from gebel gattar raw material, eastern desert, Egypt. Vol. 3

    Energy Technology Data Exchange (ETDEWEB)

    El-Hazek, N T; Mahdy, M A; Mahmoud, H M.K. [Nuclear Materials Authority, Cairo, (Egypt)

    1996-03-01

    G. Gatter uranium mineralizations are located along the faults and fracture zones crossing G.Gattar granitic pluton and long the contact of the pluton with the hammamat sediments. Also, molybdenum id presented in more than one mode of occurrence. The molybdenum mineralization treated in this work is the dessimenated type. The uranium and molybdenum raw material was subjected to series of leaching experiments including acid and alkaline agitation, alkaline percolation, and acid heap leaching techniques. Recovery of uranium and molybdenum was achieved by anion-exchange method followed by their elution by acidified sodium chloride. Uranium precipitation was performed in the form of ammonium diuranate (Yellow Cake). On the other hand molybdenum was precipitated in the form of molybdenum oxide. A tentative flowsheet for the extraction of both uranium and molybdenum is proposed and discussed. 13 figs., 3 tabs.

  16. Activity and selectivity of three molybdenum catalysts for coal liquefaction reactions

    Energy Technology Data Exchange (ETDEWEB)

    Curtis, C.W.; Pellegrino, J.L.

    The activity and selectivity of three different molybdenum catalysts for reactions occurring in coal liquefaction, specifically for hydrogenation (HYD), hydrodeoxygenation (HDO), hydrodenitrogenation (HDN), hydrodesulfurization (HDS), and hydrocracking (HYC), have been examined. The three molybdenum catalysts used were molybdenum napthenate, molybdenum on ..gamma..-alumina, and a precipitated, disordered MoS/sub 2/. Molybdenum naphthenate was most selective for HYD and HDN. All three catalysts exhibited approximately equal activity for HDS and HDO and little selectivity for HYC of alkyl bridge structures. The activity and selectivity of the three molybdenum catalysts for producing hydrocarbons and removing heteroatoms from coal during liquefaction were determined and compared. Molybdenum naphthenate was the most active catalyst for hydrocarbon production and removal of nitrogen- and oxygen-containing species during coal liquefaction. 31 refs., 4 figs., 7 tabs.

  17. Microstructure and mechanical properties of multi-components rare earth oxide-doped molybdenum alloys

    International Nuclear Information System (INIS)

    Zhang Guojun; Sun Yuanjun; Zuo Chao; Wei Jianfeng; Sun Jun

    2008-01-01

    Pure molybdenum and molybdenum alloys doped with two- or three-components rare earth oxide particles were prepared by powder metallurgy. Both the tensile property and fracture toughness of the pure molybdenum and multi-components rare earth oxide-doped molybdenum alloys were determined at room temperature. The multi-components rare earth oxide-doped molybdenum alloys are fine grained and contain a homogeneous distribution of fine particles in the submicron and nanometer size ranges, which is why the molybdenum alloys have higher strength and fracture toughness than pure molybdenum. Quantitative analysis is used to explain the increase in yield strength with respect to grain size and second phase strengthening. Furthermore, the relationship between the tensile properties and microstructural parameters is quantitatively established

  18. Response of soybean plants to phosphorus, boron and molybdenum fertilization

    International Nuclear Information System (INIS)

    Abdel-Aziz, H. A.; Aly, M. E.

    2012-12-01

    A pot experiment was carried out to study the effect of added phosphorus levels (30. 60 kg p/fed) with the addition of boron at (2, 6 ppm) and molybdenum at (5, 10.ppm) and without addition beside the control the control on growth and mineral content and root nodules in soybean plants. The results indicated that the effect of phosphorus on the formation of nodules had a clear effect when added with boron, molybdenum and when boron added at a rate of 2 ppm in the absence of phosphorus led to increase in root nodules in each of the 5, 10 ppm led to increased formation of, naldetuss in of the alluvial and calcareous soil. The molybdenum, nitrogen and phosphorus uptake increased directly proportional to the result of increased rate of addition of phosphorus and molybdenum. While the uptake born may be added with the rate of increased concentration of 2 ppm, while when added at 6 ppm led tp increased absorption of boron in the calcareous soil, but led to a decrease in the alluvial soils. (Author)

  19. Technology of niobium and molybdenum refining by electron beam

    International Nuclear Information System (INIS)

    Conti, R.A.; Pinatti, D.G.; Sandim, H.R.Z.

    1988-01-01

    The uses of metals and alloys in superconductors (Nb46%Ti), aerospatial industry (Ti6Al4V), electroeletronic industry (Nb, Mo, W) and in surgical implants (Ti, Nb) are increasing nowadays. A refining process of niobium and molybdenum by electron beam technique, since the oxides reduction till the obtention of a high purity ingot is presented. (C.G.C.) [pt

  20. Radiation damage in molybdenum and tungsten in high neutron fluxes

    Energy Technology Data Exchange (ETDEWEB)

    Veljkovic, S; Milasin, N [Institute of Nuclear Sciences Boris Kidric, Department of Reactor Materials, Vinca, Beograd (Serbia and Montenegro)

    1964-04-15

    The effects of radiation on molybdenum and tungsten in high neutron fluxes are presented. The changes induced, particularly defects with a high migration activation energy, are analyzed. The correlation of these changes with the basic concepts of radiation damage in solids is considered. An attempt is made to relate the defects studied with the changes in macroscopic properties (author)

  1. Electrical Transport Properties of Polycrystalline Monolayer Molybdenum Disulfide

    Science.gov (United States)

    2014-07-14

    Lou, Sina Najmaei, Matin Amani, Matthew L. Chin, Zheng Se. TASK NUMBER Liu Sf. WORK UNIT NUMBER 7. PERFORMING ORGANIZATION NAMES AND ADDRESSES 8...Transport Properties of Polycrystalline Monolayer Molybdenum Disulfide Sina Najmaei,t.§ Matin Ama ni,M Matthew L. Chin,* Zhe ng liu/ ·"·v: A. Gle n

  2. Flexible Molybdenum Electrodes towards Designing Affinity Based Protein Biosensors.

    Science.gov (United States)

    Kamakoti, Vikramshankar; Panneer Selvam, Anjan; Radha Shanmugam, Nandhinee; Muthukumar, Sriram; Prasad, Shalini

    2016-07-18

    Molybdenum electrode based flexible biosensor on porous polyamide substrates has been fabricated and tested for its functionality as a protein affinity based biosensor. The biosensor performance was evaluated using a key cardiac biomarker; cardiac Troponin-I (cTnI). Molybdenum is a transition metal and demonstrates electrochemical behavior upon interaction with an electrolyte. We have leveraged this property of molybdenum for designing an affinity based biosensor using electrochemical impedance spectroscopy. We have evaluated the feasibility of detection of cTnI in phosphate-buffered saline (PBS) and human serum (HS) by measuring impedance changes over a frequency window from 100 mHz to 1 MHz. Increasing changes to the measured impedance was correlated to the increased dose of cTnI molecules binding to the cTnI antibody functionalized molybdenum surface. We achieved cTnI detection limit of 10 pg/mL in PBS and 1 ng/mL in HS medium. The use of flexible substrates for designing the biosensor demonstrates promise for integration with a large-scale batch manufacturing process.

  3. Brazing molybdenum and tungsten for high temperature service

    International Nuclear Information System (INIS)

    Lundberg, L.B.; Turner, W.C.; Hoffman, C.G.

    1978-01-01

    Investigations were conducted to develop vacuum brazes for molybdenum and tungsten which can be used in seal joint applications up to 1870 K (1597 C, 2907 F). Joints were attempted in molybdenum, tungsten and tungsten--molybdenum. The braze materials included: Ti--10Cr powder, Ti--30V wire, Ti--65V wire, V wire, Ni electroplate, MoB--50MoC powder mixture, V--50Mo powder mixture, Mo--15MoB 2 powder mixture and Mo--49V--15MoB 2 powder mixture. Braze temperature ranged from 1900 K (1627 C, 2961 F) to 2530 K, (2257 C, 4095 F), and leak-tight joints were made with all braze materials except Ti--10Cr. After heat treatments up to 1870 K (1597 C, 2907 F) Kirkendall voiding was found to cause leakage of some of the joints made with only substitutional alloying elements. However, adding base metal powders to the braze or narrowing the root opening eliminated this problem. Kirkendall voiding was not a problem when interstitial elements were a major ingredient in the braze material. Shear testing of Ti--65V, V, MoB--50MoC and V--50Mo brazed molybdenum at 1670 K (1397 C, 2547 F) indicated strengths equal to or better than the base metal. Ti--65V, V--50Mo and MoB--50MoC brazed joints were exposed to basalt at 1670 K (1397 C, 2547 F) for 3 h without developing leaks

  4. Preparation of isotopic molybdenum foils utilizing small quantities of material

    Science.gov (United States)

    Lipski, A. R.; Lee, L. L.; Liang, J. F.; Mahon, J. C.

    1993-09-01

    A simple method utilizing a small amount of isotopic material for production of molybdenum foils is discussed. An e-gun is used in the procedure. The Mo powder undergoes reduction-sintering and melting-solidifying steps leading to the creation of a metallic droplet suitable for further cold rolling or vacuum deposition.

  5. Radiation damage in molybdenum and tungsten in high neutron fluxes

    International Nuclear Information System (INIS)

    Veljkovic, S.; Milasin, N.

    1964-01-01

    The effects of radiation on molybdenum and tungsten in high neutron fluxes are presented. The changes induced, particularly defects with a high migration activation energy, are analyzed. The correlation of these changes with the basic concepts of radiation damage in solids is considered. An attempt is made to relate the defects studied with the changes in macroscopic properties (author)

  6. Femtosecond laser surface structuring of molybdenum thin films

    Energy Technology Data Exchange (ETDEWEB)

    Kotsedi, L., E-mail: Kotsedi@tlabs.ac.za [UNESCO-UNISA Africa Chair in Nanosciences-Nanotechnology, College of Graduate Studies, University of South Africa, Muckleneuk ridge, PO Box 392, Pretoria (South Africa); Nanosciences African Network (NANOAFNET), iThemba LABS-National Research Foundation, 1 Old Faure Road, Somerset West 7129, PO Box 722, Somerset West, Western Cape Province (South Africa); Mthunzi, P. [Council for Scientific and Industrial Research (CSIR), Biophotonics Lab: National Laser Centre Pretoria, 0001 (South Africa); Nuru, Z.Y. [UNESCO-UNISA Africa Chair in Nanosciences-Nanotechnology, College of Graduate Studies, University of South Africa, Muckleneuk ridge, PO Box 392, Pretoria (South Africa); Nanosciences African Network (NANOAFNET), iThemba LABS-National Research Foundation, 1 Old Faure Road, Somerset West 7129, PO Box 722, Somerset West, Western Cape Province (South Africa); Eaton, S.M. [Physics Department, Politecnico di Milano, Piazza Leonardo Da Vinci, 32, 20133 Milano (Italy); Center for Nano Science and Technology, Istituto Italiano di Tecnologia, Via Pascoli 70/3, 20133 Milano, Itala (Italy); Sechoghela, P.; Mongwaketsi, N. [UNESCO-UNISA Africa Chair in Nanosciences-Nanotechnology, College of Graduate Studies, University of South Africa, Muckleneuk ridge, PO Box 392, Pretoria (South Africa); Nanosciences African Network (NANOAFNET), iThemba LABS-National Research Foundation, 1 Old Faure Road, Somerset West 7129, PO Box 722, Somerset West, Western Cape Province (South Africa); Ramponi, R. [Institute for Photonics and Nanotechnologies (IFN)–CNR, Piazza Leanardo Da Vinci, 32, 20133 Milano (Italy); Maaza, M. [UNESCO-UNISA Africa Chair in Nanosciences-Nanotechnology, College of Graduate Studies, University of South Africa, Muckleneuk ridge, PO Box 392, Pretoria (South Africa); Nanosciences African Network (NANOAFNET), iThemba LABS-National Research Foundation, 1 Old Faure Road, Somerset West 7129, PO Box 722, Somerset West, Western Cape Province (South Africa)

    2015-10-30

    Highlights: • Color change of the molybdenum thin film from shinny to violet–yellowish color after laser irradiation at various laser powers. • Formation of the molybdenum dioxide coating after laser exposure, as confirmed by the X-ray diffraction spectrometry. • Selective solar absorbing nature of the laser exposed films. • Study of the binding energies is presented in this contribution using the XPS spectrometry. - Abstract: This contribution reports on the femtosecond surface structuring of molybdenum thin coatings deposited by electron beam evaporation onto Corning glass substrates. The 1-D type periodic grating lines created by such an ablation showed that the widths of the shallow grooves followed a logarithmic dependence with the laser energy incident on the molybdenum film. The electronic valence “x” of the created oxide surface layer MoO{sub x} was found to be incident laser power dependent via Rutherford backscattering spectrometry, X-ray photoelectron spectroscopy and X-ray diffraction investigations. Such a photo-induced MoO{sub x}–Mo nanocomposite exhibited effective selective solar absorption in the UV–vis–IR spectral range.

  7. Chromium and molybdenum diffusion in tungsten single crystals

    International Nuclear Information System (INIS)

    Klotsman, S.M.; Koloskov, V.M.; Osetrov, S.V.; Polikarpova, I.P.; Tatarinova, G.N.; Timofeev, A.N.

    1989-01-01

    Consideration is given to results of measuring temperature dependences of diffusion coefficients of homovalent impurities of chromium and molybdenum in tungsten single crystals. It is concluded that the difference of activation energies of selfdiffusion and impurity diffusion in the system 'tungsten-homovalent impurity' is conditioned by interaction of screened potentials of impurity and vacancy with Lazarus-Le Claire model

  8. Process for producing molybdenum foil and collapsible tubing

    Science.gov (United States)

    Bretts, G. R.; Gavert, R. B.; Groschke, G. F.

    1971-01-01

    Manufacturing process produces molybdenum foil 0.002 cm thick and 305 m long, and forms foil into high-strength, thin-walled tubing which can be flattened for storage on a spool. Desirable metal properties include high thermal conductivity stiffness, yield and tensile stress, and low thermal expansion coeffecient.

  9. Chemical effects of nuclear transformations in molybdenum complexes

    International Nuclear Information System (INIS)

    Millan S, S.A.

    1977-01-01

    The Szilard-Chalmers effect was studied in the complexes: tetraacetatedimolybdenum(II), tetrabenzoatedimolybdenum(II), benzenetricarbonylmolybdenym(0). The results we obtained in the measurement of the Szilard-Chalmers effect on the studied complexes imply some influence of the structure in the molecular fragmentation, or the conservation of the links molybdenum-ligands. (author)

  10. Recovery of Tungsten and Molybdenum from Low-Grade Scheelite

    Science.gov (United States)

    Li, Yongli; Yang, Jinhong; Zhao, Zhongwei

    2017-10-01

    With most high-quality tungsten ores being exhausted, the enhancement of low-grade scheelite concentrates processing has attracted a great deal of attention. The objective of this study is to develop a method to maximize the recovery tungsten and molybdenum from a low-grade scheelite via a new acid leaching process followed by solvent extraction. Under optimal conditions (350 g/L H2SO4, 95°C, and 2 h), approximately 99.8% of tungsten and 98% of molybdenum were leached out. In the subsequent solvent extraction process, more than 99% of the tungsten and molybdenum were extracted with a co-extraction system (50% TBP, 30% HDEHP, and 10% 2-octanol in kerosene) using a three-stage cross-flow extraction. The raffinate can be recycled for the next leaching process after replenishing the H2SO4 to the initial value (approximately 350 g/L). Based on these results, a conceptual flowsheet is presented to recover tungsten and molybdenum from the low-grade scheelite.

  11. Characterization of the uranium--2 weight percent molybdenum alloy

    International Nuclear Information System (INIS)

    Hemperly, V.C.

    1976-01-01

    The uranium-2 wt percent molybdenum alloy was prepared, processed, and age hardened to meet a minimum 930-MPa yield strength (0.2 percent) with a minimum of 10 percent elongation. These mechanical properties were obtained with a carbon level up to 300 ppM in the alloy. The tensile-test ductility is lowered by the humidity of the laboratory atmosphere

  12. GEMAS: Molybdenum Spatial Distribution Patterns in European Soil

    Science.gov (United States)

    Cicchella, Domenico; Zuzolo, Daniela; Demetriades, Alecos; De Vivo, Benedetto; Eklund, Mikael; Ladenberger, Anna; Negrel, Philippe; O'Connor, Patrick

    2017-04-01

    Molybdenum is an essential trace element for both plants and animals as well as for human being. It is one such trace element for which potential health concerns have been raised but for which few data exist and little investigation or interpretation of distributions in soils has been made. The main goal of this study was to fill this gap. Molybdenum (Mo) concentrations are reported for the similar spatial distribution patterns mainly governed by geology (parent material and mineralisation), as well as weathering, soil formation and climate since the last glaciations period. The dominant feature is represented by low Mo concentrations over the coarse-grained sandy deposits of the last glaciations in central northern Europe while the most extensive anomalies occur in Scandinavian soils. The highest Mo concentration value occurs to the North of Oslo close to one of the largest porphyry Mo deposit of the World. Some interesting anomalous patterns occur also in Italy in correspondence with alkaline volcanics, in Spain and Greece associated with sulfides mineralizations and in Slovenia and Croatia where are probably related to the long weathering history of karstic residual soils. Anomalous concentrations in some areas of Ireland represent a clear example of how an excess of molybdenum has produced potentially toxic pastures. In fact, these give rise to problems particularly in young cattle when excess molybdenum in the herbage acts as an antagonist, which militates against efficient copper absorption by the animal.

  13. MOLYBDENUM CATALYZED ACID PEROXIDE BLEACHING OF EUCALYPTUS KRAFT PULP

    Directory of Open Access Journals (Sweden)

    Marcos S. Rabelo

    2008-08-01

    Full Text Available Molybdenum catalyzed peroxide bleaching (PMo Stage consists of pulp treatment with hydrogen peroxide under acidic conditions in the presence of a molybdenum catalyst. Molybdenum is applied in catalytic doses (50-200 mg/kg pulp and may originate from various sources, including (NH46Mo7O24.4H2O, Na2MoO4.2H2O, siliconmolybdate, etc. This work is aimed at optimizing the PMo stage and evaluating its industrial application in the OAZDP sequence. Optimum PMo stage conditions for bleaching eucalyptus pulp were 90 ºC, pH 3.5, 2 h, 0.1 kg/adt Mo and 5 kg/adt H2O2. The PMo stage was more efficient to remove pulp hexenuronic acids than lignin. Its efficiency decreased with increasing pH in the range of 1.5-5.5, while it increased with increasing temperature and peroxide and molybdenum doses. The application of the PMo stage as replacement for the A-stage of the AZDP sequence significantly decreased chlorine dioxide demand. The PMo stage caused a decrease of 20-30% in the generation of organically bound chlorine. The quality parameters of the pulp produced during the PMo stage mill trial were comparable to those obtained with the reference A-stage.

  14. Growth of molybdenum disulphide using iodine as transport material

    Indian Academy of Sciences (India)

    In the present paper an attempt has been made to describe the chemical vapor transport (CVT) technique used for the growth of molybdenum disulphide (MoS2) single crystals. Iodine (I2) is used as transporting material for this purpose. The energy dispersive analysis by X-ray (EDAX) confirmed the stoichiometry of the ...

  15. Determination of molybdenum in flotation concentrates by atomic absorption spectrophotometry

    International Nuclear Information System (INIS)

    Ise, Kazuo

    1978-01-01

    Molybdenum was determined by atomic absorption spectrophotometry in 0.05 N ammoniacal solution after the decomposition of the concentrate with aqua regia. Negros ore from Philippines was used as a flotation feed, which contained chalcopyrites and calcium-magnesium minerals. Among the metals tested copper, iron and the alkaline earths interfered. Less than 50 ppm of copper yielded lower results for molybdenum. Higher results came out with more than 50 ppm of copper. In the presence of iron and citric acid (0.4 g/100 ml) which is a suppressor for hydroxide formation, a lower estimation resulted for molybdenum. Calcium interfered, lower results by 2 and >10% being obtained with respective 2.5 and 20 ppm of calcium. More than 20 ppm of magnesium behaved similarly. Sodium sulfate (0.5 g/100 ml) served as the suppressor for copper, iron and citric acid; 100 ppm each of copper and iron did not interfere in this way. Interferences due to calcium and magnesium (less than 60 ppm) was able to be masked by the addition of sodium silicate (200 ppm as silica). The analysis of flotation products and synthetic samples consisting of molybdenite, chalcopyrite, calcium chloride and magnesium sulfate revealed that the atomic absorption method can be applied to the analysis of the concentrates for molybdenum with an error of about 2%. (auth.)

  16. Comportement en flexion des bétons fibrés sous chargement cyclique

    Directory of Open Access Journals (Sweden)

    Boulekbache Bensaid

    2014-04-01

    Full Text Available Ce papier présente les résultats d’une étude expérimentale sur le comportement en flexion des bétons de fibres métalliques. On étudie l’effet de la rhéologie du béton sur l’orientation des fibres et l’influence de l’orientation sur les propriétés mécaniques. La rigidité de l’ancrage des fibres étudiée par les essais cycliques est liée aux caractéristiques rhéologiques et mécaniques de la matrice. Les résultats montrent que la fluidité des bétons est un paramètre essentiel de l’orientation des fibres. Dès lors que l’on obtient une orientation dans le sens de l’efficacité mécanique, la résistance à la flexion est nettement améliorée.

  17. 2016 Billion-ton report: Advancing domestic resources for a thriving bioeconomy, Volume 1: Economic availability of feedstock

    Science.gov (United States)

    M.H. Langholtz; B.J. Stokes; L.M. Eaton

    2016-01-01

    This product builds on previous efforts, namely the 2005 Billion-Ton Study (BTS) and the 2011 U.S. Billion-Ton Update (BT2).With each report, greater perspective is gained on the potential of biomass resources to contribute to a national energy strategy. Similarly, each successive report introduces new questions regarding commercialization challenges. BTS quantified...

  18. 46 CFR 25.25-17 - Survival craft requirements for uninspected passenger vessels of at least 100 gross tons.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 1 2010-10-01 2010-10-01 false Survival craft requirements for uninspected passenger... Survival craft requirements for uninspected passenger vessels of at least 100 gross tons. (a) Each uninspected passenger vessel of at least 100 gross tons must have adequate survival craft with enough capacity...

  19. On characterizations of quasi-metric completeness

    Energy Technology Data Exchange (ETDEWEB)

    Dag, H.; Romaguera, S.; Tirado, P.

    2017-07-01

    Hu proved in [4] that a metric space (X, d) is complete if and only if for any closed subspace C of (X, d), every Banach contraction on C has fixed point. Since then several authors have investigated the problem of characterizing the metric completeness by means of fixed point theorems. Recently this problem has been studied in the more general context of quasi-metric spaces for different notions of completeness. Here we present a characterization of a kind of completeness for quasi-metric spaces by means of a quasi-metric versions of Hu’s theorem. (Author)

  20. The behaviour of molybdenum dialkyldithiocarbamate friction modifier additives

    International Nuclear Information System (INIS)

    Graham, Jocelyn Claire Herries

    2001-01-01

    In recent years there has been growing concern to produce energy-efficient lubricated components and modem engine oil specifications require lubricants to demonstrate fuel efficiency in standardised engine tests. One important method of producing low friction and thus fuel-efficient lubricants is to use oil-soluble, molybdenum-containing, friction modifier additives. In optimal conditions these additives are able to produce very low friction coefficients, in the range 0.045 to 0.075 in boundary lubrication conditions. Very little is known about the chemical and physical mechanisms by which oil soluble molybdenum additives form low friction films in tribological contacts. Information about their activity could lead to optimal use of these additives in lubricants and, therefore, more efficient engine running. The work outlined in this thesis investigated the behaviour of oil-soluble molybdenum additives and showed that these additives were able to effectively reduce friction in the absence of other additives such as ZnDTP. Their activity was shown to be highly concentration and temperature dependent and was also found to be sensitive to the roughness of the contacting surfaces. Raman spectroscopy was used to analyse the chemical nature of molybdenum-containing reaction films and found that friction reduction indubitably arises from the local formation of platelets (diameter 30-50 nm) of MoS 2 . The formation of MoS 2 -rich films was found to occur only during direct asperity-asperity rubbing of the contacting surfaces (this type of contact being especially prevalent in pure sliding contacts). At elevated temperatures and in the presence of oxidising gases the consumption of MoDTC was monitored. MoDTC concentration dropped until the total value fell below a critical level to reduce friction. The study showed that decay rate of molybdenum-containing species was reduced by the addition of peroxide-decomposing antioxidants. (author)

  1. The structure and function of supported molybdenum nitride and molybdenum carbide hydrotreating catalysts

    Science.gov (United States)

    Dolce, Gregory Martin

    1997-11-01

    A series of gamma-Alsb2Osb3 supported molybdenum nitrides and carbides were prepared by the temperature programmed reaction of supported molybdates with ammonia and methane/hydrogen mixtures, respectively. In the first part of this research, the effects of synthesis heating rates and molybdenum loading on the catalytic properties of the materials were examined. A significant amount of excess carbon was deposited on the surface of the carbides during synthesis. The materials consisted of small particles which were very highly dispersed. Oxygen chemisorption indicated that the nitride particles may have been two-dimensional. The dispersion of the carbides, however, appeared to decrease as the loading increased. The catalysts were evaluated for hydrodenitrogenation (HDN), hydrodesulfurization (HDS), and hydrodeoxygenation (HDO). The molybdenum loading had the largest effect on the activity of the materials. For the nitrides, the HDN and HDS activities were inverse functions of the loading. This suggested that the most active HDN and HDS sites were located at the perimeter of the two-dimensional particles. The HDN and HDS activities of the carbides followed the same trend as the oxygen uptake. This result suggested that oxygen titrated the active sites on the supported carbides. Selected catalysts were evaluated for methylcarbazole HDN, dibenzothiophene HDS, and dibenzofuran HDO. The activity and selectivity of the nitrides and carbides were competitive with a presulfided commercial catalyst. In the second part of this work, a series of supported nitrides and carbides were prepared using a wider range of loadings (5-30 wt% Mo). Thermogravimetric analysis was used to determine the temperature at which excess carbon was deposited on the carbides. By modifying the synthesis parameters, the deposition of excess carbon was effectively inhibited. The dispersions of the supported nitrides and carbides were constant and suggested that the materials consisted of two

  2. The Metric of Colour Space

    DEFF Research Database (Denmark)

    Gravesen, Jens

    2015-01-01

    and found the MacAdam ellipses which are often interpreted as defining the metric tensor at their centres. An important question is whether it is possible to define colour coordinates such that the Euclidean distance in these coordinates correspond to human perception. Using cubic splines to represent......The space of colours is a fascinating space. It is a real vector space, but no matter what inner product you put on the space the resulting Euclidean distance does not correspond to human perception of difference between colours. In 1942 MacAdam performed the first experiments on colour matching...

  3. Product Operations Status Summary Metrics

    Science.gov (United States)

    Takagi, Atsuya; Toole, Nicholas

    2010-01-01

    The Product Operations Status Summary Metrics (POSSUM) computer program provides a readable view into the state of the Phoenix Operations Product Generation Subsystem (OPGS) data pipeline. POSSUM provides a user interface that can search the data store, collect product metadata, and display the results in an easily-readable layout. It was designed with flexibility in mind for support in future missions. Flexibility over various data store hierarchies is provided through the disk-searching facilities of Marsviewer. This is a proven program that has been in operational use since the first day of the Phoenix mission.

  4. Web metrics for library and information professionals

    CERN Document Server

    Stuart, David

    2014-01-01

    This is a practical guide to using web metrics to measure impact and demonstrate value. The web provides an opportunity to collect a host of different metrics, from those associated with social media accounts and websites to more traditional research outputs. This book is a clear guide for library and information professionals as to what web metrics are available and how to assess and use them to make informed decisions and demonstrate value. As individuals and organizations increasingly use the web in addition to traditional publishing avenues and formats, this book provides the tools to unlock web metrics and evaluate the impact of this content. The key topics covered include: bibliometrics, webometrics and web metrics; data collection tools; evaluating impact on the web; evaluating social media impact; investigating relationships between actors; exploring traditional publications in a new environment; web metrics and the web of data; the future of web metrics and the library and information professional.Th...

  5. Metrics for building performance assurance

    Energy Technology Data Exchange (ETDEWEB)

    Koles, G.; Hitchcock, R.; Sherman, M.

    1996-07-01

    This report documents part of the work performed in phase I of a Laboratory Directors Research and Development (LDRD) funded project entitled Building Performance Assurances (BPA). The focus of the BPA effort is to transform the way buildings are built and operated in order to improve building performance by facilitating or providing tools, infrastructure, and information. The efforts described herein focus on the development of metrics with which to evaluate building performance and for which information and optimization tools need to be developed. The classes of building performance metrics reviewed are (1) Building Services (2) First Costs, (3) Operating Costs, (4) Maintenance Costs, and (5) Energy and Environmental Factors. The first category defines the direct benefits associated with buildings; the next three are different kinds of costs associated with providing those benefits; the last category includes concerns that are broader than direct costs and benefits to the building owner and building occupants. The level of detail of the various issues reflect the current state of knowledge in those scientific areas and the ability of the to determine that state of knowledge, rather than directly reflecting the importance of these issues; it intentionally does not specifically focus on energy issues. The report describes work in progress and is intended as a resource and can be used to indicate the areas needing more investigation. Other reports on BPA activities are also available.

  6. Uranium-molybdenum alloys containing 0,5 to 3 per cent by weight of molybdenum

    International Nuclear Information System (INIS)

    Lehmann, J.

    1959-01-01

    The following properties have been determined in the new cast state of uranium alloys containing 0.5-1-1.8-2 and 3.5 per cent of molybdenum: micro-graphical aspect, crystalline structure, thermal expansion, the mechanical characteristics, behaviour when subjected to cyclic temperature variations, and heat treatment. The transformation curves have been established for continuous cooling at rates varying between 2.5 and 200 deg. C per minute, using a dilatation method for the alloys containing 1.0, 2.0 and 3.0 per cent Mo. T.T.T. curves have been traced for 0.5 and 1.0 per cent Mo alloys and the Ms points determined for alloys containing 2.0 and 3.0 par cent Mo. In this way it has been possible to show the different results of transformation, brought about either by nucleation and diffusion or by shear - the alloy containing 1 per cent Mo, give two martensites α' and α'' and the alloys containing 2 and 3 per cent Mo give one martensite with a band structure. (author) [fr

  7. U.S. Billion-Ton Update: Biomass Supply for a Bioenergy and Bioproducts Industry

    Energy Technology Data Exchange (ETDEWEB)

    Downing, Mark [ORNL; Eaton, Laurence M [ORNL; Graham, Robin Lambert [ORNL; Langholtz, Matthew H [ORNL; Perlack, Robert D [ORNL; Turhollow Jr, Anthony F [ORNL; Stokes, Bryce [Navarro Research & Engineering; Brandt, Craig C [ORNL

    2011-08-01

    The report, Biomass as Feedstock for a Bioenergy and Bioproducts Industry: The Technical Feasibility of a Billion-Ton Annual Supply (generally referred to as the Billion-Ton Study or 2005 BTS), was an estimate of 'potential' biomass based on numerous assumptions about current and future inventory, production capacity, availability, and technology. The analysis was made to determine if conterminous U.S. agriculture and forestry resources had the capability to produce at least one billion dry tons of sustainable biomass annually to displace 30% or more of the nation's present petroleum consumption. An effort was made to use conservative estimates to assure confidence in having sufficient supply to reach the goal. The potential biomass was projected to be reasonably available around mid-century when large-scale biorefineries are likely to exist. The study emphasized primary sources of forest- and agriculture-derived biomass, such as logging residues, fuel treatment thinnings, crop residues, and perennially grown grasses and trees. These primary sources have the greatest potential to supply large, reliable, and sustainable quantities of biomass. While the primary sources were emphasized, estimates of secondary residue and tertiary waste resources of biomass were also provided. The original Billion-Ton Resource Assessment, published in 2005, was divided into two parts-forest-derived resources and agriculture-derived resources. The forest resources included residues produced during the harvesting of merchantable timber, forest residues, and small-diameter trees that could become available through initiatives to reduce fire hazards and improve forest health; forest residues from land conversion; fuelwood extracted from forests; residues generated at primary forest product processing mills; and urban wood wastes, municipal solid wastes (MSW), and construction and demolition (C&D) debris. For these forest resources, only residues, wastes, and small

  8. Valorisation et Recyclage des Déchets Plastiques dans le Béton

    Directory of Open Access Journals (Sweden)

    Benimam Samir

    2014-04-01

    Full Text Available La valorisation des déchets dans le génie civil est un secteur important dans la mesure où les produits que l’on souhaite obtenir ne sont pas soumis à des critères de qualité trop rigoureux. Le recyclage des déchets touche deux impacts très importants à savoir l’impact et l’impact économique. Donc plusieurs pays du monde, différents déchets sont utilisé dans le domaine de la construction et spécialement dans le ciment ou béton comme poudre, fibres ou agrégats. Ce travail s’intéresse à la valorisation d’un déchet qui est nuisible pour l’environnement vu son caractère encombrant et inesthétique il s’agit du déchet plastique. Trois types de déchets plastiques sont ajoutés dans le béton (sous forme de grains et fibres (ondulées et rectilignes. Les propriétés à l’état frais (maniabilité, air occlus et densité et à l’état durci (résistance à la compression, à la traction, retrait et absorption d’eau des différents bétons réalisés sont analysées et comparés par rapport leurs témoins respectifs. D’après les résultats expérimentaux on peut conclure que le renforcement de la matrice cimentaire avec des fibres plastiques ondulées montrent une nette amélioration de la résistance à la traction du béton ainsi qu’une diminution remarquable de sa capacité d’absorption de l’eau lorsqu’on utilise des grains plastiques.

  9. Molybdenum isotope fractionation in the mantle

    Science.gov (United States)

    Liang, Yu-Hsuan; Halliday, Alex N.; Siebert, Chris; Fitton, J. Godfrey; Burton, Kevin W.; Wang, Kuo-Lung; Harvey, Jason

    2017-02-01

    We report double-spike molybdenum (Mo) isotope data for forty-two mafic and fifteen ultramafic rocks from diverse locations and compare these with results for five chondrites. The δ98/95Mo values (normalized to NIST SRM 3134) range from -0.59 ± 0.04 to +0.10 ± 0.08‰. The compositions of one carbonaceous (CI) and four ordinary chondrites are relatively uniform (-0.14 ± 0.01‰, 95% ci (confidence interval)) in excellent agreement with previous data. These values are just resolvable from the mean of 10 mid-ocean ridge basalts (MORBs) (0.00 ± 0.02‰, 95% ci). The compositions of 13 mantle-derived ultramafic xenoliths from Kilbourne Hole, Tariat and Vitim are more diverse (-0.39 to -0.07‰) with a mean of -0.22 ± 0.06‰ (95% ci). On this basis, the isotopic composition of the bulk silicate Earth (BSE or Primitive Mantle) is within error identical to chondrites. The mean Mo concentration of the ultramafic xenoliths (0.19 ± 0.07 ppm, 95% ci) is similar in magnitude to that of MORB (0.48 ± 0.13 ppm, 95% ci), providing evidence, either for a more compatible behaviour than previously thought or for selective Mo enrichment of the subcontinental lithospheric mantle. Intraplate and ocean island basalts (OIBs) display significant isotopic variability within a single locality from MORB-like to strongly negative (-0.59 ± 0.04‰). The most extreme values measured are for nephelinites from the Cameroon Line and Trinidade, which also have anomalously high Ce/Pb and low Mo/Ce relative to normal oceanic basalts. δ98/95Mo correlates negatively with Ce/Pb and U/Pb, and positively with Mo/Ce, explicable if a phase such as an oxide or a sulphide liquid selectively retains isotopically heavy Mo in the mantle and fractionates its isotopic composition in low degree partial melts. If residual phases retain Mo during partial melting, it is possible that the [Mo] for the BSE may be misrepresented by values estimated from basalts. This would be consistent with the high Mo

  10. Metric approach to quantum constraints

    International Nuclear Information System (INIS)

    Brody, Dorje C; Hughston, Lane P; Gustavsson, Anna C T

    2009-01-01

    A framework for deriving equations of motion for constrained quantum systems is introduced and a procedure for its implementation is outlined. In special cases, the proposed new method, which takes advantage of the fact that the space of pure states in quantum mechanics has both a symplectic structure and a metric structure, reduces to a quantum analogue of the Dirac theory of constraints in classical mechanics. Explicit examples involving spin-1/2 particles are worked out in detail: in the first example, our approach coincides with a quantum version of the Dirac formalism, while the second example illustrates how a situation that cannot be treated by Dirac's approach can nevertheless be dealt with in the present scheme.

  11. Metrics for Business Process Models

    Science.gov (United States)

    Mendling, Jan

    Up until now, there has been little research on why people introduce errors in real-world business process models. In a more general context, Simon [404] points to the limitations of cognitive capabilities and concludes that humans act rationally only to a certain extent. Concerning modeling errors, this argument would imply that human modelers lose track of the interrelations of large and complex models due to their limited cognitive capabilities and introduce errors that they would not insert in a small model. A recent study by Mendling et al. [275] explores in how far certain complexity metrics of business process models have the potential to serve as error determinants. The authors conclude that complexity indeed appears to have an impact on error probability. Before we can test such a hypothesis in a more general setting, we have to establish an understanding of how we can define determinants that drive error probability and how we can measure them.

  12. Production of Molybdenum-99 using Neutron Capture Methods

    Energy Technology Data Exchange (ETDEWEB)

    Toth, James J; Greenwood, Lawrence R; Soderquist, Chuck Z; Wittman, Richard S; Pierson, Bruce D; Burns, Kimberly A; Lavender, Curt A; Painter, Chad L; Love, Edward F; Wall, Donald E

    2011-01-01

    Pacific Northwest National Laboratory (PNNL), operated by Battelle, has identified a reference process for the production of molybdenum-99 (99Mo) for use in a chromatographic generator to separate the daughter product, technetium-99m (99mTc). The reference process uses the neutron capture reaction of natural or enriched molybdenum oxide via the reaction 98Mo(n,γ)99Mo. The irradiated molybdenum is dissolved in an alkaline solution, whereby the molybdenum, dissolved as the molybdate anion, is loaded on a proprietary ion exchange material in the chromatographic generator. The approach of this investigation is to provide a systematic collection of technologies to make the neutron capture method for Mo-99 production economically viable. This approach would result in the development of a technetium Tc99m generator and a new type of target. The target is comprised of molybdenum, either natural or enriched, and is tailored to the design of currently operating U.S. research reactors. The systematic collection of technologies requires evaluation of new metallurgical methods to produce the target, evaluation of target geometries tailored to research reactors, and chemical methods to dissolve the irradiated target materials for use in a chromatographic generator. A Technical specification for testing the target and neutron capture method in a research reactor is also required. This report includes identification of research and demonstration activities needed to enable deployment of neutron capture production method, including irradiations of prototypic targets, chemical processing of irradiated targets, and loading and extraction tests of Mo99 and Tc99m on the sorbent material in a prototypic generator design. The prototypical generator design is based on the proprietary method and systems for isotope product generation. The proprietary methods and systems described in this report are clearly delineated with footnotes. Ultimately, the Tc-99m generator solution provided by

  13. Molybdenum-UO2 cerment irradiation at 1145 K

    Science.gov (United States)

    Mcdonald, G.

    1971-01-01

    Two molybdenum-UO2 cermet fuel pins were fission heated in a helium-cooled loop at a temperature of 1145 K and to a total burnup of 5.3 % of the U-235. After irradiation the fuel pins were measured to check dimensional stability, punctured at the plenums to determine fission gas release, and examined metallographically to determine the effect of irradiation. Burnup was determined in several sections of the fuel pin. The results of the postirradiation examination indicated: (1) There was no visible change in the fuel pins on irradiation under the above conditions. (2) The maximum swelling of the fuel pins was less than 1%. (3) There was no migration of UO2 and no visible interaction between the molybdenum and the UO2. (4) Approximately 12% of the fission gas formed was released from the cermet cone into the gas plenum.

  14. The Structure and Stability of Molybdenum Ditelluride Thin Films

    Directory of Open Access Journals (Sweden)

    Zhouling Wang

    2014-01-01

    Full Text Available Molybdenum-tellurium alloy thin films were fabricated by electron beam evaporation and the films were annealed in different conditions in N2 ambient. The hexagonal molybdenum ditelluride thin films with well crystallization annealed at 470°C or higher were obtained by solid state reactions. Thermal stability measurements indicate the formation of MoTe2 took place at about 350°C, and a subtle weight-loss was in the range between 30°C and 500°C. The evolution of the chemistry for Mo-Te thin films was performed to investigate the growth of the MoTe2 thin films free of any secondary phase. And the effect of other postdeposition treatments on the film characteristics was also investigated.

  15. Predicting molybdenum toxicity to higher plants: Influence of soil properties

    Energy Technology Data Exchange (ETDEWEB)

    McGrath, S.P., E-mail: steve.mcgrath@bbsrc.ac.u [Soil Science Department, Centre for Soils and Ecosystems Functions, Rothamsted Research, Harpenden, Hertfordshire AL5 2JQ (United Kingdom); Mico, C. [Soil Science Department, Centre for Soils and Ecosystems Functions, Rothamsted Research, Harpenden, Hertfordshire AL5 2JQ (United Kingdom); Curdy, R. [Laboratory for Environmental Biotechnology (LBE), Swiss Federal Institute of Technology Lausanne (EPFL) Station 6 CH, 1015 Lausanne (Switzerland); Zhao, F.J. [Soil Science Department, Centre for Soils and Ecosystems Functions, Rothamsted Research, Harpenden, Hertfordshire AL5 2JQ (United Kingdom)

    2010-10-15

    The effect of soil properties on the toxicity of molybdenum (Mo) to four plant species was investigated. Soil organic carbon or ammonium-oxalate extractable Fe oxides were found to be the best predictors of the 50% effective dose (ED{sub 50}) of Mo in different soils, explaining > 65% of the variance in ED{sub 50} for four species except for ryegrass (26-38%). Molybdenum concentrations in soil solution and consequently plant uptake were increased when soil pH was artificially raised because sorption of Mo to amorphous oxides is greatly reduced at high pH. The addition of sulphate significantly decreased Mo uptake by oilseed rape. For risk assessment, we suggest that Mo toxicity values for plants should be normalised using soil amorphous iron oxide concentrations. - Amorphous iron oxides or organic carbon were found to be the best predictors of the toxicity threshold values of Mo to higher plants on different soils.

  16. Crystallochemical transformations at low temperature reduction of molybdenum trioxide

    International Nuclear Information System (INIS)

    Solonin, Yu.M.

    1979-01-01

    Results are given of studying development of reaction products morphology at different stages of reduction of molybdenum trioxide separate crystals. It is determined that character of MoO 3 macrocrystals destruction at the first stage (MoO 3 -MoO 2 ) is determined by anisotropy of the chemical bond at the original crystal. MoO 2 nuclei are formed as intensively branched dendrite-like single crystals regularly oriented with respect to MoO 3 crystal. The degree of branching is determined by the reduction temperature and increases with its decrease. Formation of MoO 2 nuclei is proceeded by appearance of crystallographic shear planes in MoO 3 crystal. At the stage of MoO 2 -Mo transition no additional development of the reduction products surface takes place. The forming molybdenum crystals are strongly textured

  17. Novel target configurations for selective ionization state studies in molybdenum

    International Nuclear Information System (INIS)

    Ilcisin, K.J.; Feldman, U.; Schwob, J.L.; Wouters, A.; Suckewer, S.; Princeton Univ., NJ

    1990-03-01

    Details of experiments aimed at achieving low ionization state selectivity in molybdenum are presented. Targets are excited with a 10 J CO 2 laser and the resultant VUV spectrum (300--700 Angstrom) has been studied. Combinations of focal spot size, target depth, and target geometries are compared. Simple attenuation of energy is shown not to vary ionization stage composition significantly. Experiments conducted with grazing incidence targets result only in a hot plasma. Modular targets with cooling cylinders of various radii demonstrated good selectivity of the ionization states, but with low absolute signals. Finally, results from combinations of focal spot adjustment and radiative cooling illustrate increased control over desired plasma temperature and density for spectroscopic studies of molybdenum. 7 refs., 14 figs

  18. Preparation and properties of molybdenum-tungsten-carbonitrides

    International Nuclear Information System (INIS)

    Schreiner, M.; Ettmayer, P.; Kieffer, R.

    1982-01-01

    Molybdenum-tungsten-carbonitrides can be prepared by reacting prealloyed powders of Mo and W with carbon in the presence of nitrogen or ammonia. Single phase carbonitrides (Mo,W) (C,N) with the WC-type structure can be obtained. The nitrogen content of these carbonitrides increases with increasing molybdenum content. Flowing ammonia has a decarburizing effect, which has to be counterbalanced by an addition of a carbonaceous gas such as methane. Nitrogen instead of ammonia is equally effective and gives carbonitrides which have a nitrogen content only insignificantly lower than the carbonitrides obtained in flowing ammonia. The lattice parameters of the carbonitrides are found to slightly smaller than the lattice parameters of the corresponding carbides. (Author)

  19. In situ hydrogenation of molybdenum oxide nanowires for enhanced supercapacitors

    KAUST Repository

    Shakir, Imran

    2014-01-01

    In situ hydrogenation of orthorhombic molybdenum trioxide (α-MoO 3) nanowires has been achieved on a large scale by introducing alcohol during the hydrothermal synthesis for electrochemical energy storage supercapacitor devices. The hydrogenated molybdenum trioxide (H xMoO3) nanowires yield a specific capacitance of 168 F g-1 at 0.5 A g-1 and maintain 108 F g-1 at 10 A g-1, which is 36-fold higher than the capacitance obtained from pristine MoO3 nanowires at the same conditions. The electrochemical devices made with HxMoO3 nanowires exhibit excellent cycling stability by retaining 97% of their capacitance after 3000 cycles due to an enhanced electronic conductivity and increased density of hydroxyl groups on the surface of the MoO3 nanowires. This journal is © The Royal Society of Chemistry.

  20. Predicting molybdenum toxicity to higher plants: Influence of soil properties

    International Nuclear Information System (INIS)

    McGrath, S.P.; Mico, C.; Curdy, R.; Zhao, F.J.

    2010-01-01

    The effect of soil properties on the toxicity of molybdenum (Mo) to four plant species was investigated. Soil organic carbon or ammonium-oxalate extractable Fe oxides were found to be the best predictors of the 50% effective dose (ED 50 ) of Mo in different soils, explaining > 65% of the variance in ED 50 for four species except for ryegrass (26-38%). Molybdenum concentrations in soil solution and consequently plant uptake were increased when soil pH was artificially raised because sorption of Mo to amorphous oxides is greatly reduced at high pH. The addition of sulphate significantly decreased Mo uptake by oilseed rape. For risk assessment, we suggest that Mo toxicity values for plants should be normalised using soil amorphous iron oxide concentrations. - Amorphous iron oxides or organic carbon were found to be the best predictors of the toxicity threshold values of Mo to higher plants on different soils.

  1. Active Metric Learning for Supervised Classification

    OpenAIRE

    Kumaran, Krishnan; Papageorgiou, Dimitri; Chang, Yutong; Li, Minhan; Takáč, Martin

    2018-01-01

    Clustering and classification critically rely on distance metrics that provide meaningful comparisons between data points. We present mixed-integer optimization approaches to find optimal distance metrics that generalize the Mahalanobis metric extensively studied in the literature. Additionally, we generalize and improve upon leading methods by removing reliance on pre-designated "target neighbors," "triplets," and "similarity pairs." Another salient feature of our method is its ability to en...

  2. On Nakhleh's metric for reduced phylogenetic networks

    OpenAIRE

    Cardona, Gabriel; Llabrés, Mercè; Rosselló, Francesc; Valiente Feruglio, Gabriel Alejandro

    2009-01-01

    We prove that Nakhleh’s metric for reduced phylogenetic networks is also a metric on the classes of tree-child phylogenetic networks, semibinary tree-sibling time consistent phylogenetic networks, and multilabeled phylogenetic trees. We also prove that it separates distinguishable phylogenetic networks. In this way, it becomes the strongest dissimilarity measure for phylogenetic networks available so far. Furthermore, we propose a generalization of that metric that separates arbitrary phyl...

  3. Generalized tolerance sensitivity and DEA metric sensitivity

    OpenAIRE

    Neralić, Luka; E. Wendell, Richard

    2015-01-01

    This paper considers the relationship between Tolerance sensitivity analysis in optimization and metric sensitivity analysis in Data Envelopment Analysis (DEA). Herein, we extend the results on the generalized Tolerance framework proposed by Wendell and Chen and show how this framework includes DEA metric sensitivity as a special case. Further, we note how recent results in Tolerance sensitivity suggest some possible extensions of the results in DEA metric sensitivity.

  4. The definitive guide to IT service metrics

    CERN Document Server

    McWhirter, Kurt

    2012-01-01

    Used just as they are, the metrics in this book will bring many benefits to both the IT department and the business as a whole. Details of the attributes of each metric are given, enabling you to make the right choices for your business. You may prefer and are encouraged to design and create your own metrics to bring even more value to your business - this book will show you how to do this, too.

  5. Generalized tolerance sensitivity and DEA metric sensitivity

    Directory of Open Access Journals (Sweden)

    Luka Neralić

    2015-03-01

    Full Text Available This paper considers the relationship between Tolerance sensitivity analysis in optimization and metric sensitivity analysis in Data Envelopment Analysis (DEA. Herein, we extend the results on the generalized Tolerance framework proposed by Wendell and Chen and show how this framework includes DEA metric sensitivity as a special case. Further, we note how recent results in Tolerance sensitivity suggest some possible extensions of the results in DEA metric sensitivity.

  6. Common Metrics for Human-Robot Interaction

    Science.gov (United States)

    Steinfeld, Aaron; Lewis, Michael; Fong, Terrence; Scholtz, Jean; Schultz, Alan; Kaber, David; Goodrich, Michael

    2006-01-01

    This paper describes an effort to identify common metrics for task-oriented human-robot interaction (HRI). We begin by discussing the need for a toolkit of HRI metrics. We then describe the framework of our work and identify important biasing factors that must be taken into consideration. Finally, we present suggested common metrics for standardization and a case study. Preparation of a larger, more detailed toolkit is in progress.

  7. Chaotic inflation with metric and matter perturbations

    International Nuclear Information System (INIS)

    Feldman, H.A.; Brandenberger, R.H.

    1989-01-01

    A perturbative scheme to analyze the evolution of both metric and scalar field perturbations in an expanding universe is developed. The scheme is applied to study chaotic inflation with initial metric and scalar field perturbations present. It is shown that initial gravitational perturbations with wavelength smaller than the Hubble radius rapidly decay. The metric simultaneously picks up small perturbations determined by the matter inhomogeneities. Both are frozen in once the wavelength exceeds the Hubble radius. (orig.)

  8. Gravitational lensing in metric theories of gravity

    International Nuclear Information System (INIS)

    Sereno, Mauro

    2003-01-01

    Gravitational lensing in metric theories of gravity is discussed. I introduce a generalized approximate metric element, inclusive of both post-post-Newtonian contributions and a gravitomagnetic field. Following Fermat's principle and standard hypotheses, I derive the time delay function and deflection angle caused by an isolated mass distribution. Several astrophysical systems are considered. In most of the cases, the gravitomagnetic correction offers the best perspectives for an observational detection. Actual measurements distinguish only marginally different metric theories from each other

  9. Critical evaluation of molybdenum and its alloys for use in space reactor core heat pipes

    International Nuclear Information System (INIS)

    Lundberg, L.B.

    1981-01-01

    The choice of pure molybdenum as the prime candidate material for space reactor core heat pipes is examined, and the advantages and disadvantages of this material are brought into focus. Even though pure molybdenum heat pipes have been built and tested, this metal's high ductile-brittle transition temperature and modest creep strength place significant design restrictions on a core heat pipe made from it. Molybdenum alloys are examined with regard to their promise as potential replacements for pure molybdenum. The properties of TZM and molybdenum-rhenium alloys are examined, and it appears that Mo-Re alloys with 10 to 15 wt % rhenium offer the most advantage as an alternative to pure molybdenum in space reactor core heat pipes

  10. Friction and corrosion resistance of sputter deposited supersaturated metastable aluminium-molybdenum alloys

    Energy Technology Data Exchange (ETDEWEB)

    Abu-Zeid, O.A. [Univ. of the United Arab Emirates, Al-Ain (United Arab Emirates). Dept. of Mech. Eng.; Bates, R.I. [Design, Mfg. and Marketing Research Inst., Univ. of Salford (United Kingdom)

    1996-12-15

    Two closed field unbalanced magnetrons with targets of aluminium and molybdenum have been used for the co-deposition of aluminium-molybdenum coatings with different compositions. A pin on disk machine and a computer controlled potentiostat have been used to evaluate respectively, the tribological and corrosion properties of the deposited alloys. Results have shown that introducing molybdenum into aluminium coatings improves their poor tribological properties. Aluminium-molybdenum coatings with different compositions have shown low wear behaviour and for coatings with high molybdenum contents (> 80%) friction coefficients against steel, as low as 0.18 have been obtained. The addition of molybdenum into aluminium coatings has reduced their corrosion tendency and corrosion current density in a marine environment. (orig.)

  11. Weldability of molybdenum and its alloy sheet, 1

    International Nuclear Information System (INIS)

    Matsuda, Fukuhisa; Ushio, Masao; Nakata, Kazuhiro; Edo, Yoshiaki

    1979-01-01

    Basic weldability of electron-beam melted pure molybdenum has been examined in electron-beam welding in high vacuum and GTA welding in pure and air mixed argon atmospheres by paying attention to weld defects such as hot cracking and porosity in weld metal and also mechanical properties of welded joint in comparison with conventional TZM alloys. The main conclusions obtained were as follows; (1) The weld metals of electron-beam melted pure molybdenum with electron-beam and GTA weldings in pure and air mixed argon atmosphere up to about 1% were almost porosity free. However, large amount of oxygen content of 200 ppm in powder-metallurgy TZM alloy made very porous weld bead in electron-beam welding in high vacuum. Therefore, oxygen content in base metal should be lowered to the minimum, that is, less than 10 ppm, especially in electron-beam welding in high vacuum. (2) Hot cracking occurred in the weld metal of GTA welding when air content in argon atmosphere exceeded about 0.6% for electron-beam melted pure molybdenum and powder metallurgy TZM alloy. In less than 0.26% air, no hot cracking were observed in this experiment. Moreover, in electron-beam welding, no hot cracking was observed in weld metals for both materials. In order to prevent the formation of hot cracking, the purity of welding atmosphere should be kept as high as possible. (3) Joint efficiency of the welded joint of electron-beam melted pure molybdenum with electron-beam welding was 50 to 60% to base metal at room temperature and 500 0 C and almost 100% at 1000 0 C. Those of GTA welds in pure and 0.13% air mixed argon atmospheres were fairly lower than those in electron-beam welding for each testing temperature. (author)

  12. Ternary cobalt-molybdenum-zirconium coatings for alternative energies

    Science.gov (United States)

    Yar-Mukhamedova, Gulmira; Ved', Maryna; Sakhnenko, Nikolay; Koziar, Maryna

    2017-11-01

    Consistent patterns for electrodeposition of Co-Mo-Zr coatings from polyligand citrate-pyrophosphate bath were investigated. The effect of both current density amplitude and pulse on/off time on the quality, composition and surface morphology of the galvanic alloys were determined. It was established the coating Co-Mo-Zr enrichment by molybdenum with current density increasing up to 8 A dm-2 as well as the rising of pulse time and pause duration promotes the content of molybdenum because of subsequent chemical reduction of its intermediate oxides by hydrogen ad-atoms. It was found that the content of the alloying metals in the coating Co-Mo-Zr depends on the current density and on/off times extremely and maximum Mo and Zr content corresponds to the current density interval 4-6 A dm-2, on-/off-time 2-10 ms. Chemical resistance of binary and ternary coatings based on cobalt is caused by the increased tendency to passivity and high resistance to pitting corrosion in the presence of molybdenum and zirconium, as well as the acid nature of their oxides. Binary coating with molybdenum content not less than 20 at.% and ternary ones with zirconium content in terms of corrosion deep index are in a group ;very proof;. It was shown that Co-Mo-Zr alloys exhibits the greatest level of catalytic properties as cathode material for hydrogen electrolytic production from acidic media which is not inferior a platinum electrode. The deposits Co-Mo-Zr with zirconium content 2-4 at.% demonstrate high catalytic properties in the carbon(II) oxide conversion. This confirms the efficiency of materials as catalysts for the gaseous wastes purification and gives the reason to recommend them as catalysts for red-ox processes activating by oxygen as well as electrode materials for red-ox batteries.

  13. Determination of U (Ⅵ) content in uranium molybdenum ores

    International Nuclear Information System (INIS)

    Wang Haisheng; Ding Hongfang

    2014-01-01

    Potentionmetric titration is established to determine U (Ⅵ) in uranium molybdenum ores. In the closed condition, U (Ⅵ) is leached by carbonate solution. U (Ⅵ) is reduced to U (Ⅳ) by ferrous sulfate in phosphoric acid. The exess ferrous sulfate is oxidized by sodium nitrite. urea decompose the exess sodium nitrite. U (Ⅳ) is titrated by ammonium metavanadate standard solution with potentionmetric titration. The precision is better than 5%, The recovery rate is 97.2%∼101.9%. (authors)

  14. Deposit of molybdenum associated with uranium in Pena Blanca, Mexico

    International Nuclear Information System (INIS)

    Reyes-Cortes, M.

    1985-01-01

    The uranium-molybdenum deposits are in the Sierra Pena Blanca, 45 km north of the city of Chihuahua. The largest amounts of uranium-molybdenum ore are found in the area of Las Margaritas-Puerto III. The ratio of molybdenum mineralization to uranium is 2:1 in this area and the deposits are distributed at depths of 55-100 m in ignimbritic rocks of the so called Escuadra Formation. This volcanic unit consists of an altered crystalline-lithic ash-flow tuff of Oligocene age. The molybdenum mineral occurs as powellite (CaMoO 4 ) and is found predominantly in two size ranges: phenocrysts 0.1-20 mm in diameter are abundant in the upper part of the deposit, while a material which varies between cryptocrystalline and amorphous predominates in the lower part. This latter material can easily be identified inside the mine by its strong orange fluorescence; it is also easy to recover by leaching. In contrast, the metallurgical process of recovery by leaching of the phenocrystalline portion of the powellite has so far presented problems. Powellite is generally found in association with carnotite, margaritasite and uranophane, and its mineralization consists of disseminated lumps, druses, crustifications and veins; frequently, it partially replaces the phenocrysts of argillized feldspars of the Escuadra Formation. Fractured and brecciated zones with intense oxidation of jarosite, haematite, limonite and goethite sometimes show high U-Mo concentrations; on other occasions the concentration is found with alunite at the contact between the ignimbrite and the layers of argillized vitrophyre. The mineralizations of fluorite, pyrite, jarosite, alunite and opal are indicative of hydrothermal deposition, possibly at low temperature with supergene or geothermal alterations. (author)

  15. Concentrations of boron, molybdenum, and selenium in chinook salmon

    Science.gov (United States)

    Hamilton, Steven J.; Wiedmeyer, Raymond H.

    1990-01-01

    The concentrations of boron, molybdenum, and selenium in young chinook salmon Oncorhynchus tshawytscha were determined in three partial life cycle chronic toxicity studies. In each study, fish were exposed to a mixture of boron, molybdenum, selenate, and selenite in the proportions found in subsurface agricultural drainage water in the basin of the San Joaquin Valley, California. Tests were conducted in well water and in site-specific fresh and brackish waters. No boron or molybdenum was detected in fish exposed to concentrations as high as 6,046 μg boron/L and 193 μg molybdenum/L for 90 d in well water or fresh water; however, whole-body concentrations of selenium increased with increasing exposure concentrations in well water and fresh water, but not in brackish water. Concentrations of selenium in chinook salmon were strongly correlated with reduced survival and growth of fish in well water and with reduced survival in a 15-d seawater challenge test of fish from fresh water. Concentrations of selenium in fish seemed to reach a steady state after 60 d of exposure in well water or fresh water. Fish in brackish water had only background concentrations of selenium after 60 d of exposure, and no effects on survival and growth in brackish water or on survival in a 10-d seawater challenge test were exhibited. This lack of effect in brackish water was attributed to initiation of the study with advanced fry, which were apparently better able to metabolize the trace element mixture than were the younger fish used in studies with well water and fresh water. In all three experimental waters, concentration factors (whole-body concentration/waterborne concentration) for selenium decreased with increasing exposure concentrations, suggesting decreased uptake or increased excretion, or both, of selenium at the higher concentrations.

  16. Production of uranium-molybdenum particles by spark-erosion

    International Nuclear Information System (INIS)

    Cabanillas, E.D.; Lopez, M.; Pasqualini, E.E.; Cirilo Lombardo, D.J.

    2004-01-01

    With the spark-erosion method we have produced spheroidal particles of an uranium-molybdenum alloy using pure water as dielectric. The particles were characterized by optical metallography, scanning electron microscopy, energy dispersive spectrometry and X-ray diffraction. Mostly spherical particles of UO 2 with a distinctive size distribution with peaks centered at 70 and 10 μm were obtained. The particles have central inclusions of U and Mo compounds

  17. Production of uranium-molybdenum particles by spark-erosion

    Energy Technology Data Exchange (ETDEWEB)

    Cabanillas, E.D. E-mail: cabanill@cnea.gov.ar; Lopez, M.; Pasqualini, E.E.; Cirilo Lombardo, D.J

    2004-01-01

    With the spark-erosion method we have produced spheroidal particles of an uranium-molybdenum alloy using pure water as dielectric. The particles were characterized by optical metallography, scanning electron microscopy, energy dispersive spectrometry and X-ray diffraction. Mostly spherical particles of UO{sub 2} with a distinctive size distribution with peaks centered at 70 and 10 {mu}m were obtained. The particles have central inclusions of U and Mo compounds.

  18. Analysis of molybdenum, chromium, vanadium and iron by polarographic techniques

    International Nuclear Information System (INIS)

    Al-Zand, T.K.

    1986-01-01

    The application of direct current Tast polarograph, differential pulse polarography and phase-selective alternative current Tast polarography to the problem of determining molybdenum, chromium, vanadium and iron in various supporting electrolytes is reported. The effect of the supporting electrolyte on the wave/peak potential and sensitivity of the metal ion have been examined. The polarographic methods were applied for simultaneous determination of chromium (3)/chromium (6), vanadium (4), vanadium (5) and iron (2)/iron (3) in different supporting electrolytes

  19. Experimental determination of critical data of liquid molybdenum

    International Nuclear Information System (INIS)

    Seydel, U.; Fucke, W.

    1978-01-01

    The submicrosecond resistive pulse heating of wire-shaped metallic samples in a highly incompressible medium leads to a thermodynamic state very close to the critical point of the liquid metal. The additional application of a static pressure may result in a critical or supercritical transition. First results on the critical data of molybdenum are reported: Tsub(c) = (11 150 +- 550) K, psub(c) = (5460 +- 1160) bar, vsub(c) = (36.5 +- 3.5) cm 3 mol -1 . (author)

  20. About the possibility of a generalized metric

    International Nuclear Information System (INIS)

    Lukacs, B.; Ladik, J.

    1991-10-01

    The metric (the structure of the space-time) may be dependent on the properties of the object measuring it. The case of size dependence of the metric was examined. For this dependence the simplest possible form of the metric tensor has been constructed which fulfils the following requirements: there be two extremal characteristic scales; the metric be unique and the usual between them; the change be sudden in the neighbourhood of these scales; the size of the human body appear as a parameter (postulated on the basis of some philosophical arguments). Estimates have been made for the two extremal length scales according to existing observations. (author) 19 refs

  1. Techniques et systèmes de renfort des structures en béton

    CERN Document Server

    Miranda-Vizuete, J

    2000-01-01

    Bien qu'appelé « pierre artificielle », le béton est un matériau vivant qui se modifie tout au long de sa vie utile. Il change car la structure dont il fait partie subit elle-même des changements. Ces changements proviennent soit de modifications ou de rénovations, soit d'une altération de sa capacité de support par un accroissement des charges. Dans la plupart des cas, ils nécessitent un renfort. Le renforcement d'une structure en béton consiste à améliorer les caractéristiques mécaniques des éléments qui la composent, de manière à ce qu'elle offre une meilleure solidité aussi bien en état de service qu'en état de résistances ultimes. Ce document présente les méthodes les plus utilisées dans le domaine de renfort des structures dont l'incorporation des profiles métalliques, l'augmentation de section structurelle et celle plus récente du renforcement à base d'adjonction de matériaux composites extérieurs.

  2. Drought analysis in the Tons River Basin, India during 1969-2008

    Science.gov (United States)

    Meshram, Sarita Gajbhiye; Gautam, Randhir; Kahya, Ercan

    2018-05-01

    The primary focus of this study is the analysis of droughts in the Tons River Basin during the period 1969-2008. Precipitation data observed at four gauging stations are used to identify drought over the study area. The event of drought is derived from the standardized precipitation index (SPI) on a 3-month scale. Our results indicated that severe drought occurred in the Allahabad, Rewa, and Satna stations in the years 1973 and 1979. The droughts in this region had occurred mainly due to erratic behavior in monsoons, especially due to long breaks between monsoons. During the drought years, the deficiency of the annual rainfall in the analysis of annual rainfall departure had varied from -26% in 1976 to -60% in 1973 at Allahabad station in the basin. The maximum deficiency of annual and seasonal rainfall recorded in the basin is 60%. The maximum seasonal rainfall departure observed in the basin is in the order of -60% at Allahabad station in 1973, while maximum annual rainfall departure had been recorded as -60% during 1979 at the Satna station. Extreme dry events ( z score <-2) were detected during July, August, and September. Moreover, severe dry events were observed in August, September, and October. The drought conditions in the Tons River Basin are dominantly driven by total rainfall throughout the period between June and November.

  3. Effect of deformation diagram on molybdenum structure and properties

    International Nuclear Information System (INIS)

    Larin, Eh.N.; Abalikhin, A.A.; Kolikov, A.P.; Ushakova, N.E.

    1984-01-01

    Effect of deformation diagram on a tendency to lamination and mechanical properties of disks made of molybdenum alloy is studied. Investigated samples were subjected to hot rolling or forging. X-ray structural analysis of texture is carried out along with estimation of the level of mechanical properties across item cross section. Sample mechanical bending tests were conducted. Sample microstructure is also studied. It is shown that rolled molybdenum has a tendency to lamination, but forged molybdenum is free of such a tendency. Forged sample ductility is practically equal in all directionse but rolled sample ductility in a surface layer is high and decreases with depth. A conclusion is drawn that forged sample grains in a setting surface are equiaxial, but distinct deformation texture is observed for rolled samples and their grains are elongated in the direction of rolling. A conclusion is made that a flow diagram of the process of disk fabrication by forging or stamping ppovides a necessary complex of physicomechanical properties of metal as compared to polling, and metal discharge coefficient decreases sharply in this case

  4. Molybdenum carbide coating electrodeposited from molten fluoride bath

    International Nuclear Information System (INIS)

    Topor, D.C.; Selman, J.R.

    1987-01-01

    Molybdenum carbide has been recently considered as a candidate material for the protection of common steel-based substrates in high-temperature high-sulfur activity applications. Methods to produce coatings of materials such as Mo/sub 2/C are scarce and only the electrodeposition from molten salts can yield dense, pore-free layers on various metallic profiles. Recently Stern reported the deposition of a Mo/sub 2/C coating on nickel substrate form, FLINAK + K/sub 2/MoCl/sub 6/ + Na/sub 2/CO/sub 3/ mixture at 850 0 C. Electrodeposition of Mo/sub 2/C on a cathode surface proceeds according to a rather complicated mechanism which may involve simultaneous reduction of carbonate to C, of molybdate to Mo and a subsequent chemical reaction between both species. The deposit grows further as a coherent coating. Reduction of CO/sub 2/ or carbonate to carbon in a fused salt medium could follow different paths but Li/sup +/ ions or other highly polarizing ions must be present. A similar situation in which a polyatomic anion discharges at the cathode is encountered when molybdates are used as source of molybdenum. In fluoride melts the chemistry of Mo(VI) species is considered to be much simpler due to the hard fluoride ions. These ions form strong complexes with molybdenum and the resulting solution is more stable

  5. Direct determination of molybdenum in seawater by adsorption voltametry

    International Nuclear Information System (INIS)

    Berg, M.G. van den.

    1985-01-01

    Complex ions of molybdenum(VI) with 8-hydroxyquinoline (oxine) are shown to adsorb onto the hanging mercury drop electrode. This property forms the basis of a sensitive electrochemical technique by which dissolved molybdenum in seawater can be determined directly. The reduction current of adsorbed complex ions is measured by differential pulse adsorption voltametry, preceded by a period of 1 or 2 min of unstirred collection at an adsorption potential of -0.2 V. In the presence of 2 x 10 -3 M oxine and at pH 2.5 the potential of the main reduction peak is located at -0.59 V. The peak current-molybdenum concentration relationship is linear up to 3 x 10 -7 M; the detection limit is 4 nM. Greater sensitivity is obtained after stirred collection at pH 3.0 and with 10 -4 M oxine, but the calibration curve is nonlinear. In these conditions the limit of detection lies at 10 -10 M after 10 min stirred collection. 19 references, 8 figures

  6. Bandgap tunability at single-layer molybdenum disulphide grain boundaries

    KAUST Repository

    Huang, Yu Li

    2015-02-17

    Two-dimensional transition metal dichalcogenides have emerged as a new class of semiconductor materials with novel electronic and optical properties of interest to future nanoelectronics technology. Single-layer molybdenum disulphide, which represents a prototype two-dimensional transition metal dichalcogenide, has an electronic bandgap that increases with decreasing layer thickness. Using high-resolution scanning tunnelling microscopy and spectroscopy, we measure the apparent quasiparticle energy gap to be 2.40±0.05 eV for single-layer, 2.10±0.05 eV for bilayer and 1.75±0.05 eV for trilayer molybdenum disulphide, which were directly grown on a graphite substrate by chemical vapour deposition method. More interestingly, we report an unexpected bandgap tunability (as large as 0.85±0.05 eV) with distance from the grain boundary in single-layer molybdenum disulphide, which also depends on the grain misorientation angle. This work opens up new possibilities for flexible electronic and optoelectronic devices with tunable bandgaps that utilize both the control of two-dimensional layer thickness and the grain boundary engineering.

  7. Separation of fission Molybdenum for production of technetium generator

    International Nuclear Information System (INIS)

    Bayat, L.; Shaham, V.; Davarkha, R.

    2002-01-01

    There are two basically different methods for Mo-99 productions: Activation of Mo-99 contained at about 24% in natural isotopic mixtures. Mo-98 enriched targets are irradiated in high-flux reactors in order to achieve the highest possible specific activity of the product. Idolisation of fission molybdenum from irradiated nuclear fuel targets which have undergone short-term cooling. Maximum fission yield can be attained by irradiation of uranium-235 with the highest possible enrichment. On account of its approximately 1000 times higher specific activity. Fission molybdenum has almost replaced worldwide the product fabricated by activation. However, fission molybdenum-99 production has as its prerequisite a suitably advanced technology by which the production process taking place under high activity conditions can be controlled. An integral part of the process consist in the retention of the fission gases the recycling of non-consumed fuel and the treatment of the waste streams arising. This publication will deal with the individual steps in the process

  8. Synthesis and superconductivity of molybdenum cluster compounds (Chevrel phase)

    International Nuclear Information System (INIS)

    Culetto, F.J.

    1979-05-01

    The discovery of superconductivity in ternary molybdenum sulfides (Chevrel phases) in 1972 has stimulated research on these compounds. Some of the phases show extremely high critical fields Hc 2 and might therefore find technical application as high field superconductors. In order to understand the electron-phonon-interaction in these substances, measurements of the superconducting isotope effect in 92-100 Mo 6 Se 8 , Mo 6 76-82 Se 8 , and 116-124 SnMo 6 S 8 have been performed. The corresponding isotope effect exponents β (βmo=0.27 +- 0.04, βSe=0.27 +- 0.05 and βSn 6 Se 8 . In case of the ternary Chevrel phase SnMo 6 S 8 , phonon modes connected with displacements of the Sn-ions have only minor influence on the transition temperature. This result can be explained by the weak overlap of the molybdenum dsub(x)2sub(-y)2 - orbitals with Sn-sites. Furthermore, we report experiments on the synthesis of new Chevrel phase materials. In order to optimize the valence electron concentration in some ternary molybdenum selenide compounds, chalcogen exchange reactions have been performed. A new Chevrel phase superconductor, Cusub(x)Mo 6 S 6 J 2 with x=0 - 1.2, has been synthesized by copper diffusion into the non occupied channels running between the Mo 6 S 6 J 2 -'molecules' of Mo 6 S 6 J 2 . (orig.)

  9. Thermal cycling behaviour and thermal stability of uranium-molybdenum alloys of low molybdenum content

    International Nuclear Information System (INIS)

    Decours, J.; Fabrique, B.; Peault, O.

    1963-01-01

    We have studied the behaviour during thermal cycling of as-cast U-Mo alloys whose molybdenum content varies from 0.5 to 3 per cent; results are given concerning grain stability during extended heat treatments and the effect of treatments combining protracted heating with thermal cycling. The thermal cycling treatments were carried out at 550, 575, 600 and 625 deg C for 1000 cycles; the protracted heating experiments were done at 550, 575, 600 and 625 deg C for 2000 hours (4000 hrs at 625 deg C). The 0.5 per cent alloy resists much better to the thermal cycling than does the non-alloyed uranium. This resistance is, however, much lower than that of alloys containing over l per cent, even at 550 deg C it improves after a heat treatment for grain-refining. Alloys of over 1.1 per cent have a very good resistance to a cycling treatment even at 625 deg C, and this behaviour improves with increasing concentrations up to 3 per cent. An increase in the temperature up to the γ-phase has few disadvantages provided that it is followed by rapid cooling (50 to 100 deg C/min). The α grain is fine, the γ-phase is of the modular form, and the behaviour during a thermal cycling treatment is satisfactory. If this cooling is slow (15 deg /hr) the α-grain is coarse and cycling treatment behaviour is identical to that of the 0.5 per cent alloy. The protracted heat treatments showed that the α-grain exhibits satisfactory stability after 2000 hours at 575, 600 and 625 deg C, and after 4000 hours at 625 deg C. A heat cycling treatment carried out after these tests affects only very little the behaviour of these alloys during cycling. (authors) [fr

  10. Feasibility of preparing patterned molybdenum coatings on bismuth telluride thermoelectric modules.

    Energy Technology Data Exchange (ETDEWEB)

    Sarobol, Pylin; Hall, Aaron Christopher; Miller, Stephen Samuel; Knight, Marlene E.; LePage, William S.; Sobczak, Catherine Elizabeth.; Wesolowski, Daniel Edward

    2013-09-01

    Molybdenum electrical interconnects for thermoelectric modules were produced by air plasma spraying a 30%CE%BCm size molybdenum powder through a laser-cut Kapton tape mask. Initial feasibility demonstrations showed that the molybdenum coating exhibited excellent feature and spacing retention (~170%CE%BCm), adhered to bismuth-telluride, and exhibited electrical conductivity appropriate for use as a thermoelectric module interconnect. A design of experiments approach was used to optimize air plasma spray process conditions to produce a molybdenum coating with low electrical resistivity. Finally, a molybdenum coating was successfully produced on a fullscale thermoelectric module. After the addition of a final titanium/gold layer deposited on top of the molybdenum coating, the full scale module exhibited an electrical resistivity of 128%CE%A9, approaching the theoretical resistivity value for the 6mm module leg of 112%CE%A9. Importantly, air plasma sprayed molybdenum did not show significant chemical reaction with bismuth-telluride substrate at the coating/substrate interface. The molybdenum coating microstructure consisted of lamellar splats containing columnar grains. Air plasma sprayed molybdenum embedded deeply (several microns) into the bismuth-telluride substrate, leading to good adhesion between the coating and the substrate. Clusters of round pores (and cracks radiating from the pores) were found immediately beneath the molybdenum coating. These pores are believed to result from tellurium vaporization during the spray process where the molten molybdenum droplets (2623%C2%B0C) transferred their heat of solidification to the substrate at the moment of impact. Substrate cooling during the molybdenum deposition process was recommended to mitigate tellurium vaporization in future studies.

  11. A highly sensitive method for detection of molybdenum-containing proteins

    International Nuclear Information System (INIS)

    Kalakutskii, K.L.; Shvetsov, A.A.; Bursakov, S.A.; Letarov, A.V.; Zabolotnyi, A.I.; L'vov, N.P.

    1992-01-01

    A highly sensitive method for detection of molybdenum-containing proteins in gels after electrophoresis has been developed. The method involves in vitro labeling of the proteins with the radioactive isotope 185 W. The method used to detect molybdenum-accumulating proteins in lupine seeds, xanthine dehydrogenase and another molybdenum-containing protein in wheat, barley, and pea seedlings, and nitrate reductase and xanthine dehydrogenase in bacteroides from lupine nodules. Nitrogenase could not be detected by the method. 16 refs., 5 figs

  12. Importance of molybdenum in the nitrogen metabolism of microorganisms and higher plants

    Energy Technology Data Exchange (ETDEWEB)

    Mulder, E G

    1948-01-01

    The effect of molybdenum on the growth of microorganisms and higher plants and on some well-defined biochemical reactions was investigated. Results indicate that Aspergillus niger requires small amounts of molybdenum when growing in a culture solution supplied with nitrate nitrogen. With ammonium sulfate as a source of nitrogen, the response of the fungus to molybdenum was much smaller. It was shown that this different response of Aspergillus to molybdenum was not brought about by a difference in purity of both nitrogen compounds used, nor by a difference in absorption of the molybdenum impurity, but by a considerably higher requirement of molybdenum in a medium with nitrate nitrogen. The growth-rate curve and the increasing sporulation of Aspergillus niger with increasing amounts of molybdenum were used in estimating very small amounts of this element in various materials. In culture solution experiments with tomato, barley and oat plants the effect of traces of molybdenum on the growth of these plants was investigated. In good agreement with the results of the experiments with Aspergillus and denitrifying bacteria it could be shown that in the green plant as in these microorganisms molybdenum is acting as a catalyst in nitrate reduction. In experiments with Azotobacter chroococcum and leguminous plants the effect of molybdenum on the fixation of gaseous N/sub 2/ was studied. In culture solutions with pea plants the effect of molybdenum on the nitrogen fixation of the nodules was investigated. In the absence of molybdenum as well as in a complete nutrient medium many nodules were formed. 30 references, 6 figures, 16 tables.

  13. Effect of high concentration of molybdenum on the structure and properties of niobium

    International Nuclear Information System (INIS)

    Trekina, M.I.; Vasil'eva, E.V.

    1989-01-01

    The effect of alloying of 20,25 and 30 % Mo on the structure and mechanical properties of niobium is studied. It is shown that niobium alloying with molybdenum in the studied concentration leads to grain grinding, which increases with the molybdenum content growth in the alloy. The effective energy values of recrystallization activation of the studied niobium and molybdenum alloys are determined. The high hardness level at some plasticity and deformability of niobium alloy with 20 % Mo is established

  14. Effect of drying method on properties of vanadium-molybdenum oxide catalysts

    International Nuclear Information System (INIS)

    Gorshkova, T.P.; Savchenko, L.A.; Tarasova, D.V.; Tret'yakov, Yu.D.; Olen'kova, I.P.; Nikoro, T.A.; Maksimov, N.G.

    1981-01-01

    Effect of drying method of molybdenum and vanadium salt solutions on physicochemical and catalytical properties of vanadium-molybdenum catalysts is studied. It is shown that the drying method of solutions determines the completeness of vanadium binding into oxide vanadium-molybdenum compounds and thus effects the activity and selectivity of catalysts in acrolein oxidation into acrylic acid. Besides the drying method determines the porous structure of catalysts [ru

  15. Study of arsenic and molybdenum retention in organism during hydrotherapy by neutron activation analysis

    International Nuclear Information System (INIS)

    Irigaray, J.L.; Mannou, B.; Pepin, D.; Fauquert, J.L.

    1989-01-01

    At La Bourboule (France), arsenic and molybdenum are contained in high concentrations in the spring water used for hydrotherapy. Thermal neutron activation analysis was applied to determine arsenic and molybdenum penetration into the organism for the first time. The results obtained with children, men and rabbits are similar. The chronology of the absorption of arsenic and molybdenum in blood and urine during the treatment is in good accordance with the medical therapeutic observations. (author) 10 refs.; 10 figs.; 10 tabs

  16. Combustion characteristics and NO formation for biomass blends in a 35-ton-per-hour travelling grate utility boiler.

    Science.gov (United States)

    Li, Zhengqi; Zhao, Wei; Li, Ruiyang; Wang, Zhenwang; Li, Yuan; Zhao, Guangbo

    2009-04-01

    Measurements were taken for a 35-ton-per-hour biomass-fired travelling grate boiler. Local mean concentrations of O(2), CO, SO(2) and NO gas species and gas temperatures were determined in the region above the grate. For a 28-ton-per-hour load, the mass ratios of biomass fly ash and boiler slag were 42% and 58%, the boiler efficiency was 81.56%, and the concentrations of NO(x) and SO(2) at 6% O(2) were 257 and 84 mg/m(3). For an 18-ton-per-hour load, the fuel burning zone was nearer to the inlet than it was for the 28-ton-per-hour load, and the contents of CO and NO in the fuel burning zone above the grate were lower.

  17. Determination of molybdenum in plant reference material by thermal-ionization isotope-dilution mass spectrometry

    International Nuclear Information System (INIS)

    Saumer, M.; Gantner, E.; Reinhardt, J.; Ache, H.J.

    1992-01-01

    An analytical method is described for the determination of the concentration and the isotopic composition of molybdenum in plant samples using thermal ionization mass spectrometry. After microwave acid digestion and liquid-liquid extractive separation with Amberlite LA-2, the molybdenum isotopes are measured as MoO 3 - -ions in a quadrupole mass spectrometer. In all cases, the relative standard deviation of the measurements of both natural and spike molybdenum was better than 3% for all ratios measured. The concentration of molybdenum found in three different plant reference materials agreed well with the certified values. (orig.)

  18. Modification of molybdenum disulfide in methanol solvent for hydrogen evolution reaction

    Science.gov (United States)

    Niyitanga, Theophile; Jeong, Hae Kyung

    2018-05-01

    Molybdenum disulfide is a promising catalyst to replace the expensive platinum as an electrocatalyst but needs to be modified to present excellent electrocatalytic properties. Herein, we successfully modify molybdenum disulfide in methanol solvent for hydrogen evolution reaction by using a simple hydrothermal method. Overpotential reduced to -0.6 V from -1.5 V, and energy band gap decreased from 1.73 eV to 1.58 eV after the modification. The modified molybdenum disulfide also demonstrated lower resistance (42 Ω) at high frequency (1000 kHz) compared with that (240 Ω) of the precursor, showing that conductivity of the modified molybdenum disulfide has improved.

  19. Study of mechanoactivation of tungsten-molybdenum containing raw material in gas-jet mill

    International Nuclear Information System (INIS)

    Agnokov, T.Sh.; Gorobets, L.Zh.; Martynenko, V.P.; Fedorov, Yu.P.; Krakhmaleva, M.T.; Sokolova, L.A.

    1988-01-01

    Investigation is aimed at intensifying autoclave-soda leaching of tungsten-molybdenum-containing raw material. Connection of reactivity and physicochemical properties of crushed tungsten-molybdenum-containing products under different gas-jet crushing parameters is investigated. Optimal technological indices of hydrometallurgical reprocessing of tungsten-molybdenum-containing raw materials and products processed by gas-jet technique are given. The results obtained point out to perspectiveness of applying gas-jet technique of thermomechanical processing for intensifying and increasing the quality of tungsten- and molybdenum-containing raw materials and products of hydrometallurgical production

  20. Comparison of early stages of precipitation in molybdenum-rich and molybdenum-poor maraging stainless steels

    International Nuclear Information System (INIS)

    Andersson, M.; Stiller, K.; Haettestrand, M.

    2004-01-01

    Full text: The precipitation hardening process in the molybdenum-rich Sandvik alloy 1RK91, with composition 12.8Cr-8.6Ni-2.3Mo-1.7Cu-1.2Ti-0.7Al (at. %), has previously been investigated with APFIM, energy-filtering transmission electron microscopy, and conventional transmission electron microscopy. The initial ageing response corresponds to Ni 3 (Al, Ti)-type precipitates, nucleating on copper clusters after only five minutes of ageing at 475 o C. After several hours of ageing, the precipitation hardening also includes contribution from molybdenum-rich quasicrystalline precipitates of icosahedral symmetry (R'), and another nickel-rich phase of type L1 0 . This complex precipitation behaviour, in combination with a resistance to coarsening of R', results in a continuous increase in material hardness for up to several hundred of hours of ageing. A significant difference in ageing response has been observed between the Sandvik alloy 1RK91 and molybdenum-poor alloy Carpenter 455 with composition 12.3Cr-7.9Ni-0.3Mo-1.8Cu-1.3Ti-0.1Al (at. %). During ageing at 475 o C, the hardness of Carpenter 455 saturates with a subsequent softening after just a few hours. The reason for the discrepancy in the ageing behaviour of the two steels is not well understood, since the precipitation reactions in Carpenter 455 have not been thoroughly surveyed. Therefore, the precipitation hardening process of Carpenter 455 has been studied, by using three-dimensional atom probe and energy-filtering transmission electron microscopy. The results have been compared with the precipitation hardening process of 1RK91 in order to explain the difference in ageing response of the two steels. Special interest has been devoted to understand the influence of molybdenum in the precipitation process of 1RK91. Refs 3 (author)

  1. Enhancing Authentication Models Characteristic Metrics via ...

    African Journals Online (AJOL)

    In this work, we derive the universal characteristic metrics set for authentication models based on security, usability and design issues. We then compute the probability of the occurrence of each characteristic metrics in some single factor and multifactor authentication models in order to determine the effectiveness of these ...

  2. Gravitational Metric Tensor Exterior to Rotating Homogeneous ...

    African Journals Online (AJOL)

    The covariant and contravariant metric tensors exterior to a homogeneous spherical body rotating uniformly about a common φ axis with constant angular velocity ω is constructed. The constructed metric tensors in this gravitational field have seven non-zero distinct components.The Lagrangian for this gravitational field is ...

  3. Invariant metric for nonlinear symplectic maps

    Indian Academy of Sciences (India)

    In this paper, we construct an invariant metric in the space of homogeneous polynomials of a given degree (≥ 3). The homogeneous polynomials specify a nonlinear symplectic map which in turn represents a Hamiltonian system. By minimizing the norm constructed out of this metric as a function of system parameters, we ...

  4. Finite Metric Spaces of Strictly negative Type

    DEFF Research Database (Denmark)

    Hjorth, Poul G.

    If a finite metric space is of strictly negative type then its transfinite diameter is uniquely realized by an infinite extent (“load vector''). Finite metric spaces that have this property include all trees, and all finite subspaces of Euclidean and Hyperbolic spaces. We prove that if the distance...

  5. Fixed point theory in metric type spaces

    CERN Document Server

    Agarwal, Ravi P; O’Regan, Donal; Roldán-López-de-Hierro, Antonio Francisco

    2015-01-01

    Written by a team of leading experts in the field, this volume presents a self-contained account of the theory, techniques and results in metric type spaces (in particular in G-metric spaces); that is, the text approaches this important area of fixed point analysis beginning from the basic ideas of metric space topology. The text is structured so that it leads the reader from preliminaries and historical notes on metric spaces (in particular G-metric spaces) and on mappings, to Banach type contraction theorems in metric type spaces, fixed point theory in partially ordered G-metric spaces, fixed point theory for expansive mappings in metric type spaces, generalizations, present results and techniques in a very general abstract setting and framework. Fixed point theory is one of the major research areas in nonlinear analysis. This is partly due to the fact that in many real world problems fixed point theory is the basic mathematical tool used to establish the existence of solutions to problems which arise natur...

  6. Metric solution of a spinning mass

    International Nuclear Information System (INIS)

    Sato, H.

    1982-01-01

    Studies on a particular class of asymptotically flat and stationary metric solutions called the Kerr-Tomimatsu-Sato class are reviewed about its derivation and properties. For a further study, an almost complete list of the papers worked on the Tomimatsu-Sato metrics is given. (Auth.)

  7. On Information Metrics for Spatial Coding.

    Science.gov (United States)

    Souza, Bryan C; Pavão, Rodrigo; Belchior, Hindiael; Tort, Adriano B L

    2018-04-01

    The hippocampal formation is involved in navigation, and its neuronal activity exhibits a variety of spatial correlates (e.g., place cells, grid cells). The quantification of the information encoded by spikes has been standard procedure to identify which cells have spatial correlates. For place cells, most of the established metrics derive from Shannon's mutual information (Shannon, 1948), and convey information rate in bits/s or bits/spike (Skaggs et al., 1993, 1996). Despite their widespread use, the performance of these metrics in relation to the original mutual information metric has never been investigated. In this work, using simulated and real data, we find that the current information metrics correlate less with the accuracy of spatial decoding than the original mutual information metric. We also find that the top informative cells may differ among metrics, and show a surrogate-based normalization that yields comparable spatial information estimates. Since different information metrics may identify different neuronal populations, we discuss current and alternative definitions of spatially informative cells, which affect the metric choice. Copyright © 2018 IBRO. Published by Elsevier Ltd. All rights reserved.

  8. Validation of Metrics for Collaborative Systems

    Directory of Open Access Journals (Sweden)

    Ion IVAN

    2008-01-01

    Full Text Available This paper describe the new concepts of collaborative systems metrics validation. The paper define the quality characteristics of collaborative systems. There are proposed a metric to estimate the quality level of collaborative systems. There are performed measurements of collaborative systems quality using a specially designed software.

  9. Validation of Metrics for Collaborative Systems

    OpenAIRE

    Ion IVAN; Cristian CIUREA

    2008-01-01

    This paper describe the new concepts of collaborative systems metrics validation. The paper define the quality characteristics of collaborative systems. There are proposed a metric to estimate the quality level of collaborative systems. There are performed measurements of collaborative systems quality using a specially designed software.

  10. Software Power Metric Model: An Implementation | Akwukwuma ...

    African Journals Online (AJOL)

    ... and the execution time (TIME) in each case was recorded. We then obtain the application functions point count. Our result shows that the proposed metric is computable, consistent in its use of unit, and is programming language independent. Keywords: Software attributes, Software power, measurement, Software metric, ...

  11. Metrics for border management systems.

    Energy Technology Data Exchange (ETDEWEB)

    Duggan, Ruth Ann

    2009-07-01

    There are as many unique and disparate manifestations of border systems as there are borders to protect. Border Security is a highly complex system analysis problem with global, regional, national, sector, and border element dimensions for land, water, and air domains. The complexity increases with the multiple, and sometimes conflicting, missions for regulating the flow of people and goods across borders, while securing them for national security. These systems include frontier border surveillance, immigration management and customs functions that must operate in a variety of weather, terrain, operational conditions, cultural constraints, and geopolitical contexts. As part of a Laboratory Directed Research and Development Project 08-684 (Year 1), the team developed a reference framework to decompose this complex system into international/regional, national, and border elements levels covering customs, immigration, and border policing functions. This generalized architecture is relevant to both domestic and international borders. As part of year two of this project (09-1204), the team determined relevant relative measures to better understand border management performance. This paper describes those relative metrics and how they can be used to improve border management systems.

  12. The metrics of science and technology

    CERN Document Server

    Geisler, Eliezer

    2000-01-01

    Dr. Geisler's far-reaching, unique book provides an encyclopedic compilation of the key metrics to measure and evaluate the impact of science and technology on academia, industry, and government. Focusing on such items as economic measures, patents, peer review, and other criteria, and supported by an extensive review of the literature, Dr. Geisler gives a thorough analysis of the strengths and weaknesses inherent in metric design, and in the use of the specific metrics he cites. His book has already received prepublication attention, and will prove especially valuable for academics in technology management, engineering, and science policy; industrial R&D executives and policymakers; government science and technology policymakers; and scientists and managers in government research and technology institutions. Geisler maintains that the application of metrics to evaluate science and technology at all levels illustrates the variety of tools we currently possess. Each metric has its own unique strengths and...

  13. Smart Grid Status and Metrics Report Appendices

    Energy Technology Data Exchange (ETDEWEB)

    Balducci, Patrick J. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Antonopoulos, Chrissi A. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Clements, Samuel L. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Gorrissen, Willy J. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Kirkham, Harold [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Ruiz, Kathleen A. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Smith, David L. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Weimar, Mark R. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Gardner, Chris [APQC, Houston, TX (United States); Varney, Jeff [APQC, Houston, TX (United States)

    2014-07-01

    A smart grid uses digital power control and communication technology to improve the reliability, security, flexibility, and efficiency of the electric system, from large generation through the delivery systems to electricity consumers and a growing number of distributed generation and storage resources. To convey progress made in achieving the vision of a smart grid, this report uses a set of six characteristics derived from the National Energy Technology Laboratory Modern Grid Strategy. The Smart Grid Status and Metrics Report defines and examines 21 metrics that collectively provide insight into the grid’s capacity to embody these characteristics. This appendix presents papers covering each of the 21 metrics identified in Section 2.1 of the Smart Grid Status and Metrics Report. These metric papers were prepared in advance of the main body of the report and collectively form its informational backbone.

  14. Metrics for Polyphonic Sound Event Detection

    Directory of Open Access Journals (Sweden)

    Annamaria Mesaros

    2016-05-01

    Full Text Available This paper presents and discusses various metrics proposed for evaluation of polyphonic sound event detection systems used in realistic situations where there are typically multiple sound sources active simultaneously. The system output in this case contains overlapping events, marked as multiple sounds detected as being active at the same time. The polyphonic system output requires a suitable procedure for evaluation against a reference. Metrics from neighboring fields such as speech recognition and speaker diarization can be used, but they need to be partially redefined to deal with the overlapping events. We present a review of the most common metrics in the field and the way they are adapted and interpreted in the polyphonic case. We discuss segment-based and event-based definitions of each metric and explain the consequences of instance-based and class-based averaging using a case study. In parallel, we provide a toolbox containing implementations of presented metrics.

  15. Development and Manufacturing Technology of Prototype Monoblock Low Pressure Rotor Shaft by 650ton Large Ingot

    Energy Technology Data Exchange (ETDEWEB)

    Song, Duk-Yong; Kim, Dong-Soo; Kim, Jungyeup; Lee, Jongwook; Ko, Seokhee [Doosan Heavy Industries and Construction, Changwon(Korea, Republic of)

    2016-10-15

    In order to establish the manufacturing technology for monoblock LP rotor shaft, DHI has produced the prototype monoblock LP rotor shaft with a maximum diameter of φ 2,800 mm using 650 ton ingot and investigated the mechanical properties and the internal quality of the ingot. As a result, the quality and mechanical properties required the large rotor shaft for nuclear power plant met a target. These results indicate that DHI can be contributed to increasing demands with high efficiency and capacity at the nuclear power plant. Additionally, some tests such as high cycle fatigue (HCF), low cycle fatigue (LCF), fracture toughness (K1C/J1C) and dynamic crack propagation velocity (da/dN) are in progress.

  16. Modified Cooling System for Low Temperature Experiments in a 3000 Ton Multi-Anvil Press

    Science.gov (United States)

    Secco, R.; Yong, W.

    2017-12-01

    A new modified cooling system for a 3000-ton multi-anvil press has been developed to reach temperatures below room temperature at high pressures. The new system is much simpler in design, easier to make and use, and has the same cooling capability as the previous design (Secco and Yong, RSI, 2016). The key component of the new system is a steel ring surrounding the module wedges that contains liquid nitrogen (LN2) which flows freely through an entrance port to flood the interior of the pressure module. Upper and lower O-rings on the ring seal in the liquid while permitting modest compression and an thermally insulating layer of foam is attached to the outside of the ring. The same temperature of 220 K reached with two different cooling systems suggests that thermal equilibrium is reached between the removal of heat by LN2 and the influx of heat through the massive steel components of this press.

  17. Synthesis and characterization of Al-TON zeolite using a dialkylimizadolium as structure-directing agent

    Energy Technology Data Exchange (ETDEWEB)

    Lopes, Christian Wittee; Pergher, Sibele Berenice Castella, E-mail: chriswittee@gmail.com [Universidade Federal do Rio Grande do Norte (UFRN), Natal, RN (Brazil); Villarroel-Rocha, Jhonny [Laboratorio de Solidos Porosos, Instituto de Fisica Aplicada, Universidad Nacional de San Luis, Chacabuco, San Luis (Argentina); Silva, Bernardo Araldi Da; Mignoni, Marcelo Luis [Universidade Regional Integrada, Erechim, RS (Brazil)

    2016-11-15

    In this work, the synthesis of zeolites using 1-butyl-3-methylimidazolium chloride [C{sub 4}MI]Cl as a structure-directing agent was investigated. The organic cation shows effectiveness and selectivity for the syntheses of TON zeolites under different reaction conditions compared to the traditional structure directing agent, 1,8-diaminooctane. The 1-butyl-3-methylimidazolium cation lead to highly crystalline materials and its role as OSDA in our synthesis conditions has been confirmed by characterization techniques. ICP-OES confirms the presence of Al in the samples and {sup 27}Al MAS NMR analysis indicated that aluminum atoms were incorporated in tetrahedral coordination. Scanning electron microscopy indicated that changing the crystallization condition (static or stirring), zeolites with different crystal size were obtained, which consequently affects the textural properties of the zeolites. Moreover, varying some synthesis parameters MFI zeolite can also be obtained. (author)

  18. Cracked lifting lug welds on ten-ton UF{sub 6} cylinders

    Energy Technology Data Exchange (ETDEWEB)

    Dorning, R.E. [Martin Marietta Energy Systems, Inc., Piketon, OH (United States)

    1991-12-31

    Ten-ton, Type 48X, UF{sub 6} cylinders are used at the Portsmouth Gaseous Diffusion Plant to withdraw enriched uranium hexafluoride from the cascade, transfer enriched uranium hexafluoride to customer cylinders, and feed enriched product to the cascade. To accomplish these activities, the cylinders are lifted by cranes and straddle carriers which engage the cylinder lifting lugs. In August of 1988, weld cracks on two lifting lugs were discovered during preparation to lift a cylinder. The cylinder was rejected and tagged out, and an investigating committee formed to determine the cause of cracking and recommend remedial actions. Further investigation revealed the problem may be general to this class of cylinder in this use cycle. This paper discusses the actions taken at the Portsmouth site to deal with the cracked lifting lug weld problem. The actions include inspection activities, interim corrective actions, metallurgical evaluation of cracked welds, weld repairs, and current monitoring/inspection program.

  19. Light Readout for a 1 ton Liquid Argon Dark Matter Detector

    CERN Document Server

    Boccone, Vittorio; Baudis, Laura; Otyugova, Polina; Regenfus, Christian

    2010-01-01

    Evidence for dark matter (DM) has been reported using astronomical observations in systems such as the Bullet cluster. Weakly interactive massive particles (WIMPs), in particular the lightest neutralino, are the most popular DM candidates within the Minimal Supersymmetric Standard Model (MSSM). Many groups in the world are focussing their attention on the direct detection of DM in the laboratory. The detectors should have large target masses and excellent noise rejection capabilities because of the small cross section between DM and ordinary matter (σWIMP−nucleon < 4 · 10−8 pb). Noble liquids are today considered to be one of the best options for large-size DM experiments, as they have a relatively low ionization energy, good scintillation properties and long electron lifetime. Moreover noble liquid detectors are easily scalable to large masses. This thesis deals with the development of a large (1 ton) LAr WIMP detector (ArDM) which could measure simultaneously light and charge from the scintilla...

  20. Extraction of molybdenum with TBP-dodecane mixture in nitric medium. Application to uranium refining

    International Nuclear Information System (INIS)

    Donnet, Louis

    1993-01-01

    Uranium ores may contain high quantities of molybdenum which represents an undesirable impurity in the uranium conversion process. Thus it is necessary to check carefully its extraction and its stripping during the purification step. The purpose of this study was to investigate the molybdenum behaviour during this step. We have developed a radiochemical method for the determination of the molybdenum concentration in each phase. This method used gamma radiation of technetium 99m issued from molybdenum 99 disintegration. After a systematic study of all the extraction parameters, we have proposed mechanisms accounting for molybdenum extraction and we have calculated the constants for the different equilibria. In particular, we have furnished new data concerning the extraction of polymerised molybdenum species with tri butyl phosphate. We have also determined the polymerization constants of molybdenum in the aqueous phase. The influence of uranium and phosphate ions on the molybdenum behaviour during the extraction and stripping has been investigated. We have shown that the extraction of molybdenum was not modified by uranium but improved in the presence of phosphate ions. In the general case, we have shown that uranium, phosphate ions and the ageing of the solvent have an unfavourable effect on stripping. We have explained this result by the evolution of the complex in the organic phase to an un-stripped polymeric form. In conclusion, our study has allowed to explain the behaviour of molybdenum during the purification process, and the role of impurities present in the industrial solutions. It would serve as a guide to improve the exploitation for a better molybdenum-uranium separation. (author) [fr

  1. Community Extreme Tonnage User Service (CETUS): A 5000 Ton Open Research Facility in the United States

    Science.gov (United States)

    Danielson, L. R.; Righter, K.; Vander Kaaden, K. E.; Rowland, R. L., II; Draper, D. S.; McCubbin, F. M.

    2017-12-01

    Large sample volume 5000 ton multi-anvil presses have contributed to the exploration of deep Earth and planetary interiors, synthesis of ultra-hard and other novel materials, and serve as a sample complement to pressure and temperature regimes already attainable by diamond anvil cell experiments. However, no such facility exists in the Western Hemisphere. We are establishing an open user facility for the entire research community, with the unique capability of a 5000 ton multi-anvil and deformation press, HERA (High pressure Experimental Research Apparatus), supported by a host of extant co-located experimental and analytical laboratories and research staff. We offer wide range of complementary and/or preparatory experimental options. Any required synthesis of materials or follow up experiments can be carried out controlled atmosphere furnaces, piston cylinders, multi-anvil, or experimental impact apparatus. Additionally, our division houses two machine shops that would facilitate any modification or custom work necessary for development of CETUS, one for general fabrication and one located specifically within our experimental facilities. We also have a general sample preparation laboratory, specifically for experimental samples, that allows users to quickly and easily prepare samples for ebeam analyses and more. Our focus as contract staff is on serving the scientific needs of our users and collaborators. We are seeking community expert input on multiple aspects of this facility, such as experimental assembly design, module modifications, immediate projects, and future innovation initiatives. We've built a cooperative network of 12 (and growing) collaborating institutions, including COMPRES. CETUS is a coordinated effort leveraging HERA with our extant experimental, analytical, and planetary process modelling instrumentation and expertise in order to create a comprehensive model of the origin and evolution of our solar system and beyond. We are looking to engage

  2. Methods and results for stress analyses on 14-ton, thin-wall depleted UF6 cylinders

    International Nuclear Information System (INIS)

    Kirkpatrick, J.R.; Chung, C.K.; Frazier, J.L.; Kelley, D.K.

    1996-10-01

    Uranium enrichment operations at the three US gaseous diffusion plants produce depleted uranium hexafluoride (DUF 6 ) as a residential product. At the present time, the inventory of DUF 6 in this country is more than half a million tons. The inventory of DUF 6 is contained in metal storage cylinders, most of which are located at the gaseous diffusion plants. The principal objective of the project is to ensure the integrity of the cylinders to prevent causing an environmental hazard by releasing the contents of the cylinders into the atmosphere. Another objective is to maintain the cylinders in such a manner that the DUF 6 may eventually be converted to a less hazardous material for final disposition. An important task in the DUF 6 cylinders management project is determining how much corrosion of the walls can be tolerated before the cylinders are in danger of being damaged during routine handling and shipping operations. Another task is determining how to handle cylinders that have already been damaged in a manner that will minimize the chance that a breach will occur or that the size of an existing breach will be significantly increased. A number of finite element stress analysis (FESA) calculations have been done to analyze the stresses for three conditions: (1) while the cylinder is being lifted, (2) when a cylinder is resting on two cylinders under it in the customary two-tier stacking array, and (3) when a cylinder is resting on tis chocks on the ground. Various documents describe some of the results and discuss some of the methods whereby they have been obtained. The objective of the present report is to document as many of the FESA cases done at Oak Ridge for 14-ton thin-wall cylinders as possible, giving results and a description of the calculations in some detail

  3. Reconstruction and Analysis for the DUNE 35-ton Liquid Argon Prototype

    Energy Technology Data Exchange (ETDEWEB)

    Wallbank, Michael James [Sheffield U.

    2018-01-01

    Neutrino physics is approaching the precision era, with current and future experiments aiming to perform highly accurate measurements of the parameters which govern the phenomenon of neutrino oscillations. The ultimate ambition with these results is to search for evidence of CP-violation in the lepton sector, currently hinted at in the world-leading analyses from present experiments, which may explain the dominance of matter over antimatter in the Universe. The Deep Underground Neutrino Experiment (DUNE) is a future long-baseline experiment based at Fermi National Accelerator Laboratory (FNAL), with a far detector at the Sanford Underground Research Facility (SURF) and a baseline of 1300 km. In order to make the required precision measurements, the far detector will consist of 40 kton liquid argon and an embedded time projection chamber. This promising technology is still in development and, since each detector module is around a factor 15 larger than any previous experiment employing this design, prototyping the detector and design choices is critical to the success of the experiment. The 35-ton experiment was constructed for this purpose and will be described in detail in this thesis. The outcomes of the 35-ton prototype are already influencing DUNE and, following the successes and lessons learned from the experiment, confidence can be taken forward to the next stage of the DUNE programme. The main oscillation signal at DUNE will be electron neutrino appearance from the muon neutrino beam. High-precision studies of these νe interactions requires advanced processing and event reconstruction techniques, particularly in the handling of showering particles such as electrons and photons. Novel methods developed for the purposes of shower reconstruction in liquid argon are presented with an aim to successfully develop a selection to use in a νe charged-current analysis, and a first-generation selection using the new techniques is presented.

  4. Robustness Metrics: Consolidating the multiple approaches to quantify Robustness

    DEFF Research Database (Denmark)

    Göhler, Simon Moritz; Eifler, Tobias; Howard, Thomas J.

    2016-01-01

    robustness metrics; 3) Functional expectancy and dispersion robustness metrics; and 4) Probability of conformance robustness metrics. The goal was to give a comprehensive overview of robustness metrics and guidance to scholars and practitioners to understand the different types of robustness metrics...

  5. Partial rectangular metric spaces and fixed point theorems.

    Science.gov (United States)

    Shukla, Satish

    2014-01-01

    The purpose of this paper is to introduce the concept of partial rectangular metric spaces as a generalization of rectangular metric and partial metric spaces. Some properties of partial rectangular metric spaces and some fixed point results for quasitype contraction in partial rectangular metric spaces are proved. Some examples are given to illustrate the observed results.

  6. Measuring Information Security: Guidelines to Build Metrics

    Science.gov (United States)

    von Faber, Eberhard

    Measuring information security is a genuine interest of security managers. With metrics they can develop their security organization's visibility and standing within the enterprise or public authority as a whole. Organizations using information technology need to use security metrics. Despite the clear demands and advantages, security metrics are often poorly developed or ineffective parameters are collected and analysed. This paper describes best practices for the development of security metrics. First attention is drawn to motivation showing both requirements and benefits. The main body of this paper lists things which need to be observed (characteristic of metrics), things which can be measured (how measurements can be conducted) and steps for the development and implementation of metrics (procedures and planning). Analysis and communication is also key when using security metrics. Examples are also given in order to develop a better understanding. The author wants to resume, continue and develop the discussion about a topic which is or increasingly will be a critical factor of success for any security managers in larger organizations.

  7. Characterising risk - aggregated metrics: radiation and noise

    International Nuclear Information System (INIS)

    Passchier, W.

    1998-01-01

    The characterisation of risk is an important phase in the risk assessment - risk management process. From the multitude of risk attributes a few have to be selected to obtain a risk characteristic or profile that is useful for risk management decisions and implementation of protective measures. One way to reduce the number of attributes is aggregation. In the field of radiation protection such an aggregated metric is firmly established: effective dose. For protection against environmental noise the Health Council of the Netherlands recently proposed a set of aggregated metrics for noise annoyance and sleep disturbance. The presentation will discuss similarities and differences between these two metrics and practical limitations. The effective dose has proven its usefulness in designing radiation protection measures, which are related to the level of risk associated with the radiation practice in question, given that implicit judgements on radiation induced health effects are accepted. However, as the metric does not take into account the nature of radiation practice, it is less useful in policy discussions on the benefits and harm of radiation practices. With respect to the noise exposure metric, only one effect is targeted (annoyance), and the differences between sources are explicitly taken into account. This should make the metric useful in policy discussions with respect to physical planning and siting problems. The metric proposed has only significance on a population level, and can not be used as a predictor for individual risk. (author)

  8. Energy functionals for Calabi-Yau metrics

    International Nuclear Information System (INIS)

    Headrick, M; Nassar, A

    2013-01-01

    We identify a set of ''energy'' functionals on the space of metrics in a given Kähler class on a Calabi-Yau manifold, which are bounded below and minimized uniquely on the Ricci-flat metric in that class. Using these functionals, we recast the problem of numerically solving the Einstein equation as an optimization problem. We apply this strategy, using the ''algebraic'' metrics (metrics for which the Kähler potential is given in terms of a polynomial in the projective coordinates), to the Fermat quartic and to a one-parameter family of quintics that includes the Fermat and conifold quintics. We show that this method yields approximations to the Ricci-flat metric that are exponentially accurate in the degree of the polynomial (except at the conifold point, where the convergence is polynomial), and therefore orders of magnitude more accurate than the balanced metrics, previously studied as approximations to the Ricci-flat metric. The method is relatively fast and easy to implement. On the theoretical side, we also show that the functionals can be used to give a heuristic proof of Yau's theorem

  9. Strengthening and elongation mechanism of Lanthanum-doped Titanium-Zirconium-Molybdenum alloy

    Energy Technology Data Exchange (ETDEWEB)

    Hu, Ping, E-mail: huping1985@126.com [School of Metallurgy Engineering, Xi’an University of Architecture and Technology, Xi’an 710055 (China); Jinduicheng Molybdenum Co., Ltd., Xi’an 710068 (China); Hu, Bo-liang; Wang, Kuai-she; Song, Rui; Yang, Fan [School of Metallurgy Engineering, Xi’an University of Architecture and Technology, Xi’an 710055 (China); Yu, Zhi-tao [Ruifulai Tungsten & Molybdenum Co., Ltd., Xi’an 721914 (China); Tan, Jiang-fei [School of Metallurgy Engineering, Xi’an University of Architecture and Technology, Xi’an 710055 (China); Cao, Wei-cheng; Liu, Dong-xin; An, Geng [Jinduicheng Molybdenum Co., Ltd., Xi’an 710068 (China); Guo, Lei [Ruifulai Tungsten & Molybdenum Co., Ltd., Xi’an 721914 (China); Yu, Hai-liang [School of Mechanical, Materials and Mechatronics Engineering, University of Wollongong, NSW 2522 (Australia)

    2016-12-15

    The microstructural contributes to understand the strengthening and elongation mechanism in Lanthanum-doped Titanium-Zirconium-Molybdenum alloy. Lanthanum oxide particles not only act as heterogeneous nucleation core, but also act as the second phase to hinder the grain growth during sintering crystallization. The molybdenum substrate formed sub-grain under the effect of second phase when the alloy rolled to plate.

  10. Special features of nickel-molybdenum alloy electrodeposition onto screen-type cathodes

    International Nuclear Information System (INIS)

    Aleksandrova, G.S.; Varypaev, V.N.

    1982-01-01

    Electrolytic nickel-molybdenum alloy, which has a rather low hydrogen overpotential and high corrosion resistance, is of interest as cathode material in industrial electrolysis. Screen-type electrodes with a nickel-molybdenum coating can be used as nonconsumable cathodes in water-activated magnesium-alloy batteries

  11. A study on direct alloying with molybdenum oxides by feed wire method

    Directory of Open Access Journals (Sweden)

    Jingjing Zou

    2018-04-01

    Full Text Available Direct alloying with molybdenum oxides has been regarded in years; the main addition methods are adding to the bottom of electric arc furnace (EAF with scrap, adding to the ladle during the converter tapping and mixing molybdenum oxide, lime and reductant to prepare pellet added to basic oxygen furnace (BOF. In this paper, a new method for direct alloying with molybdenum trioxide is proposed, adding molybdenum trioxide molten steel by feeding wire method in ladle furnace (LF refining process. The feasibility of molybdenum oxide reduction, the influence rules of bottom-blown on liquid steel fluidity and the yield of molybdenum by feeding wire method were analyzed. Results show that molybdenum oxide can be reduced by [Al], [Si], [C], and even [Fe] in molten steel. Bottom blowing position has a significant influence on the flow of molten steel when the permeable brick is located in 1/2 radius. The yields of Mo are higher than 97% for the experiments with feed wire method, the implementation of direct alloying with molybdenum trioxide by feed wire method works even better than that uses of ferromolybdenum in the traditional process.

  12. Low resistivity molybdenum thin film towards the back contact of dye ...

    Indian Academy of Sciences (India)

    Abstract. This paper reports the optimization of the molybdenum thin film electrode as the back contact of dye-sensitized solar cell (DSSC). The molybdenum thin film was grown on the glass substrate by direct current sputtering techniques of which the sputtering power was 150Wat 18 sccm flow rate of Ar. At such sputtering ...

  13. Problems in producing nuclear reactor for medical isotopes and the Global Crisis of molybdenum supply

    International Nuclear Information System (INIS)

    Zubiarrain, A.

    2011-01-01

    Nuclear medicine uses drugs that incorporate a radioactive isotope radiopharmaceuticals. Every year are performed, worldwide, 35 million nuclear medicine procedures, of which 80% are done with radiopharmaceuticals containing the isotope, molybdenum-99, produced in nuclear reactors. In recent years, there have been several supply crisis of molybdenum-99, which have hampered diagnostic procedure with technitium-99m. (Author)

  14. Active carbon supported molybdenum carbides for higher alcohols synthesis from syngas

    DEFF Research Database (Denmark)

    Wu, Qiongxiao; Chiarello, Gian Luca; Christensen, Jakob Munkholt

    This work provides an investigation of the high pressure CO hydrogenation to higher alcohols on K2CO3 promoted active carbon supported molybdenum carbide. Both activity and selectivity to alcohols over supported molybdenum carbides increased significantly compared to bulk carbides in literatures...

  15. Molybdenum-cofactor deficiency: an easily missed cause of neonatal convulsions

    NARCIS (Netherlands)

    Slot, H. M.; Overweg-Plandsoen, W. C.; Bakker, H. D.; Abeling, N. G.; Tamminga, P.; Barth, P. G.; van Gennip, A. H.

    1993-01-01

    Intractable seizures in the neonatal period may be caused by molybdenum-cofactor deficiency, an inborn error which combines the deficiencies of sulphite oxidase and xanthine dehydrogenase. The neurological symptoms of molybdenum cofactor and isolated sulphite oxidase deficiencies are identical. Two

  16. Effect of liming on the molybdenum content in the root and leaf of ...

    African Journals Online (AJOL)

    Three liming treatments were employed (1, 3 and 4 t/ha CaCO3). The liming operation used on pseudogley induced a statistically significant increase in molybdenum ion absorption into the root system of tomato. Independently from the aforementioned, the values for the root and leaf molybdenum content of tomato in each ...

  17. Measurement of Actinides in Molybdenum-99 Solution Analytical Procedure

    Energy Technology Data Exchange (ETDEWEB)

    Soderquist, Chuck Z. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Weaver, Jamie L. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    2015-11-01

    This document is a companion report to a previous report, PNNL 24519, Measurement of Actinides in Molybdenum-99 Solution, A Brief Review of the Literature, August 2015. In this companion report, we report a fast, accurate, newly developed analytical method for measurement of trace alpha-emitting actinide elements in commercial high-activity molybdenum-99 solution. Molybdenum-99 is widely used to produce 99mTc for medical imaging. Because it is used as a radiopharmaceutical, its purity must be proven to be extremely high, particularly for the alpha emitting actinides. The sample of 99Mo solution is measured into a vessel (such as a polyethylene centrifuge tube) and acidified with dilute nitric acid. A gadolinium carrier is added (50 µg). Tracers and spikes are added as necessary. Then the solution is made strongly basic with ammonium hydroxide, which causes the gadolinium carrier to precipitate as hydrous Gd(OH)3. The precipitate of Gd(OH)3 carries all of the actinide elements. The suspension of gadolinium hydroxide is then passed through a membrane filter to make a counting mount suitable for direct alpha spectrometry. The high-activity 99Mo and 99mTc pass through the membrane filter and are separated from the alpha emitters. The gadolinium hydroxide, carrying any trace actinide elements that might be present in the sample, forms a thin, uniform cake on the surface of the membrane filter. The filter cake is first washed with dilute ammonium hydroxide to push the last traces of molybdate through, then with water. The filter is then mounted on a stainless steel counting disk. Finally, the alpha emitting actinide elements are measured by alpha spectrometry.

  18. Measurement of Actinides in Molybdenum-99 Solution Analytical Procedure

    International Nuclear Information System (INIS)

    Soderquist, Chuck Z.; Weaver, Jamie L.

    2015-01-01

    This document is a companion report to a previous report, PNNL 24519, Measurement of Actinides in Molybdenum-99 Solution, A Brief Review of the Literature, August 2015. In this companion report, we report a fast, accurate, newly developed analytical method for measurement of trace alpha-emitting actinide elements in commercial high-activity molybdenum-99 solution. Molybdenum-99 is widely used to produce 99m Tc for medical imaging. Because it is used as a radiopharmaceutical, its purity must be proven to be extremely high, particularly for the alpha emitting actinides. The sample of 99 Mo solution is measured into a vessel (such as a polyethylene centrifuge tube) and acidified with dilute nitric acid. A gadolinium carrier is added (50 µg). Tracers and spikes are added as necessary. Then the solution is made strongly basic with ammonium hydroxide, which causes the gadolinium carrier to precipitate as hydrous Gd(OH) 3 . The precipitate of Gd(OH) 3 carries all of the actinide elements. The suspension of gadolinium hydroxide is then passed through a membrane filter to make a counting mount suitable for direct alpha spectrometry. The high-activity 99 Mo and 99m Tc pass through the membrane filter and are separated from the alpha emitters. The gadolinium hydroxide, carrying any trace actinide elements that might be present in the sample, forms a thin, uniform cake on the surface of the membrane filter. The filter cake is first washed with dilute ammonium hydroxide to push the last traces of molybdate through, then with water. The filter is then mounted on a stainless steel counting disk. Finally, the alpha emitting actinide elements are measured by alpha spectrometry.

  19. Pyranopterin Coordination Controls Molybdenum Electrochemistry in Escherichia coli Nitrate Reductase.

    Science.gov (United States)

    Wu, Sheng-Yi; Rothery, Richard A; Weiner, Joel H

    2015-10-09

    We test the hypothesis that pyranopterin (PPT) coordination plays a critical role in defining molybdenum active site redox chemistry and reactivity in the mononuclear molybdoenzymes. The molybdenum atom of Escherichia coli nitrate reductase A (NarGHI) is coordinated by two PPT-dithiolene chelates that are defined as proximal and distal based on their proximity to a [4Fe-4S] cluster known as FS0. We examined variants of two sets of residues involved in PPT coordination: (i) those interacting directly or indirectly with the pyran oxygen of the bicyclic distal PPT (NarG-Ser(719), NarG-His(1163), and NarG-His(1184)); and (ii) those involved in bridging the two PPTs and stabilizing the oxidation state of the proximal PPT (NarG-His(1092) and NarG-His(1098)). A S719A variant has essentially no effect on the overall Mo(VI/IV) reduction potential, whereas the H1163A and H1184A variants elicit large effects (ΔEm values of -88 and -36 mV, respectively). Ala variants of His(1092) and His(1098) also elicit large ΔEm values of -143 and -101 mV, respectively. An Arg variant of His(1092) elicits a small ΔEm of +18 mV on the Mo(VI/IV) reduction potential. There is a linear correlation between the molybdenum Em value and both enzyme activity and the ability to support anaerobic respiratory growth on nitrate. These data support a non-innocent role for the PPT moieties in controlling active site metal redox chemistry and catalysis. © 2015 by The American Society for Biochemistry and Molecular Biology, Inc.

  20. Pyranopterin Coordination Controls Molybdenum Electrochemistry in Escherichia coli Nitrate Reductase*

    Science.gov (United States)

    Wu, Sheng-Yi; Rothery, Richard A.; Weiner, Joel H.

    2015-01-01

    We test the hypothesis that pyranopterin (PPT) coordination plays a critical role in defining molybdenum active site redox chemistry and reactivity in the mononuclear molybdoenzymes. The molybdenum atom of Escherichia coli nitrate reductase A (NarGHI) is coordinated by two PPT-dithiolene chelates that are defined as proximal and distal based on their proximity to a [4Fe-4S] cluster known as FS0. We examined variants of two sets of residues involved in PPT coordination: (i) those interacting directly or indirectly with the pyran oxygen of the bicyclic distal PPT (NarG-Ser719, NarG-His1163, and NarG-His1184); and (ii) those involved in bridging the two PPTs and stabilizing the oxidation state of the proximal PPT (NarG-His1092 and NarG-His1098). A S719A variant has essentially no effect on the overall Mo(VI/IV) reduction potential, whereas the H1163A and H1184A variants elicit large effects (ΔEm values of −88 and −36 mV, respectively). Ala variants of His1092 and His1098 also elicit large ΔEm values of −143 and −101 mV, respectively. An Arg variant of His1092 elicits a small ΔEm of +18 mV on the Mo(VI/IV) reduction potential. There is a linear correlation between the molybdenum Em value and both enzyme activity and the ability to support anaerobic respiratory growth on nitrate. These data support a non-innocent role for the PPT moieties in controlling active site metal redox chemistry and catalysis. PMID:26297003

  1. Metrics Are Needed for Collaborative Software Development

    Directory of Open Access Journals (Sweden)

    Mojgan Mohtashami

    2011-10-01

    Full Text Available There is a need for metrics for inter-organizational collaborative software development projects, encompassing management and technical concerns. In particular, metrics are needed that are aimed at the collaborative aspect itself, such as readiness for collaboration, the quality and/or the costs and benefits of collaboration in a specific ongoing project. We suggest questions and directions for such metrics, spanning the full lifespan of a collaborative project, from considering the suitability of collaboration through evaluating ongoing projects to final evaluation of the collaboration.

  2. Indefinite metric fields and the renormalization group

    International Nuclear Information System (INIS)

    Sherry, T.N.

    1976-11-01

    The renormalization group equations are derived for the Green functions of an indefinite metric field theory. In these equations one retains the mass dependence of the coefficient functions, since in the indefinite metric theories the masses cannot be neglected. The behavior of the effective coupling constant in the asymptotic and infrared limits is analyzed. The analysis is illustrated by means of a simple model incorporating indefinite metric fields. The model scales at first order, and at this order also the effective coupling constant has both ultra-violet and infra-red fixed points, the former being the bare coupling constant

  3. Metric learning for DNA microarray data analysis

    International Nuclear Information System (INIS)

    Takeuchi, Ichiro; Nakagawa, Masao; Seto, Masao

    2009-01-01

    In many microarray studies, gene set selection is an important preliminary step for subsequent main task such as tumor classification, cancer subtype identification, etc. In this paper, we investigate the possibility of using metric learning as an alternative to gene set selection. We develop a simple metric learning algorithm aiming to use it for microarray data analysis. Exploiting a property of the algorithm, we introduce a novel approach for extending the metric learning to be adaptive. We apply the algorithm to previously studied microarray data on malignant lymphoma subtype identification.

  4. Software metrics a rigorous and practical approach

    CERN Document Server

    Fenton, Norman

    2014-01-01

    A Framework for Managing, Measuring, and Predicting Attributes of Software Development Products and ProcessesReflecting the immense progress in the development and use of software metrics in the past decades, Software Metrics: A Rigorous and Practical Approach, Third Edition provides an up-to-date, accessible, and comprehensive introduction to software metrics. Like its popular predecessors, this third edition discusses important issues, explains essential concepts, and offers new approaches for tackling long-standing problems.New to the Third EditionThis edition contains new material relevant

  5. Procedure for Uranium-Molybdenum Density Measurements and Porosity Determination

    Energy Technology Data Exchange (ETDEWEB)

    Prabhakaran, Ramprashad [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Devaraj, Arun [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Joshi, Vineet V. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Lavender, Curt A. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    2016-08-13

    The purpose of this document is to provide guidelines for preparing uranium-molybdenum (U-Mo) specimens, performing density measurements, and computing sample porosity. Typical specimens (solids) will be sheared to small rectangular foils, disks, or pieces of metal. A mass balance, solid density determination kit, and a liquid of known density will be used to determine the density of U-Mo specimens using the Archimedes principle. A standard test weight of known density would be used to verify proper operation of the system. By measuring the density of a U-Mo sample, it is possible to determine its porosity.

  6. Determination of molybdenum with gallic acid and hydroxylamine

    International Nuclear Information System (INIS)

    Bermejo-Barrera, Ma.P.; Vazquez-Gonzalez, J.F.; Pazos-Naveira, Ma.C.; Bermejo-Martinez, F.

    1987-01-01

    A method for the spectrophotometric determination of molybdenum with gallic acid and hydroxylamine is proposed. The spectrum of the complex formed has a stable absorption maximum at 420 nm in acidic media and the molar absorptivity is 4.84 x 10 3 l mol -1 cm -1 in the range in which the complex obeys Beer's law (3.02-25.12 μg ml -1 of Mo). The effects of the concentration of reagent, pH, time and temperature were investigated, together with the stoicheiometry of the complex, the reproducibility and precision of the method and its susceptibility to interferences. (author)

  7. Disposition of plutonium-239 via production of fission molybdenum-99

    Energy Technology Data Exchange (ETDEWEB)

    Mushtaq, A., E-mail: muahtaq_a1953@hotmail.co [Isotope Production Division, Pakistan Institute of Nuclear Science and Technology, P.O. Nilore, Islamabad (Pakistan)

    2011-04-15

    A heritage of physical consequences of the U.S.-Soviet arms race has accumulated, the weapons-grade plutonium (WPu), which will become excess as a result of the dismantlement of the nuclear weapons under the arms reduction agreements. Disposition of Pu has been proposed by mixing WPu with high-level radioactive waste with subsequent vitrification into large, highly radioactive glass logs or fabrication into mixed oxide fuel with subsequent irradiation in existing light water reactors. A potential option may be the production of medical isotope molybdenum-99 by using Pu-239 targets.

  8. Tungsten and molybdenum with oxide dispersion, production and properties

    International Nuclear Information System (INIS)

    Haerdtle, S.; Schmidberger, R.

    1989-01-01

    By the reaction spray process metal powders with dispersed metal oxides can be produced in one step. The systems investigated here are tungsten and molybdenum with 0,5% resp. 5% La 2 O 3 , Y 2 O 3 and ZrO 2 . The oxides with diameters below 0,5μm are finely dispersed within the metal powder particles. The sinterability of the powders depends on the oxide content. Maximum density at an oxide content of 0,5% is about 96% at a sintering temperature of 1600 0 C. The type of oxide influences the densification versus temperature but not the final density. 5 refs., 11 figs. (Author)

  9. Primary defect production by high energy displacement cascades in molybdenum

    Energy Technology Data Exchange (ETDEWEB)

    Selby, Aaron P. [Department of Nuclear Engineering, University of Tennessee, Knoxville, TN 37996 (United States); Xu, Donghua, E-mail: xudh@utk.edu [Department of Nuclear Engineering, University of Tennessee, Knoxville, TN 37996 (United States); Juslin, Niklas; Capps, Nathan A. [Department of Nuclear Engineering, University of Tennessee, Knoxville, TN 37996 (United States); Wirth, Brian D. [Department of Nuclear Engineering, University of Tennessee, Knoxville, TN 37996 (United States); Oak Ridge National Laboratory, P.O. Box 2008, MS6003, Oak Ridge, TN 37831 (United States)

    2013-06-15

    We report molecular dynamics simulations of primary damage in molybdenum produced by high energy displacement cascades on the femto- to pico-second and Angstrom to nanometer scales. Clustering directly occurred for both interstitials and vacancies in the 1–50 keV cascade energy range explored. Point defect survival efficiency and partitioning probabilities into different sized clusters were quantified. The results will provide an important reference for kinetic models to describe the microstructural evolution in Mo under ion or neutron irradiations over much longer time and length scales.

  10. Molybdenum(5) template action in acetone with ethylenediamine condensation reaction

    International Nuclear Information System (INIS)

    Ashurova, N.Kh.; Yakubov, K.G.; Tsivadze, A.Yu.; AN SSSR, Moscow

    1994-01-01

    Ability of molybdenum(5) oxopentahalides [MoOX 5 ] 2- (X = Cl - , Br - ) to show their template action in acetone with ethylenediamine condensation reaction is identified. Macrocyclic metallic complexes [MoO(Td)X]X 2 , where Td is 5,7,7,12,14,14 hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11 dien, are separated and identified. Perchlorate salt of Td·2HClO 4 macrocycle is obtained through action of concentrated perchloric acid on synthesized complexes. 13 refs.; 3 figs

  11. Set up of Uranium-Molybdenum powder production (HMD process)

    International Nuclear Information System (INIS)

    Lopez, Marisol; Pasqualini, Enrique E.; Gonzalez, Alfredo G.

    2003-01-01

    Powder metallurgy offers different alternatives for the production of Uranium-Molybdenum (UMo) alloy powder in sizes smaller than 150 microns. This powder is intended to be used as a dispersion fuel in an aluminum matrix for research, testing and radioisotopes production reactors (MTR). A particular process of massive hydriding the UMo alloy in gamma phase has been developed. This work describes the final adjustments of process variables to obtain UMo powder by hydriding-milling-de hydriding (HMD) and its capability for industrial scaling up. (author)

  12. Positron lifetime study of neutron-irradiated molybdenum

    International Nuclear Information System (INIS)

    Hinode, Kenji; Tanigawa, Shoichiro; Kumakura, Hiroaki; Doyama, Masao; Shiraishi, Kensuke.

    1978-01-01

    Annealing behavior of fast-neutron-irradiated molybdenum was studied by means of positron lifetime technique. It was found that Stage III annealing can be mainly identified as the vacancy migration process from the detailed analyses of data. The void growth after successive high temperature annealings was clearly detected through the changes of positron lifetime parameters. An attempt to analyse the size distribution of voids from positron lifetime spectra was presented, and discussions on the evaluation of void concentration from positron data are also given. (author)

  13. Study of internal oxidation kinetics of molybdenum base alloys

    International Nuclear Information System (INIS)

    Krushinskij, Yu.Yu.; Belyakov, B.G.; Belomyttsev, M.Yu.

    1989-01-01

    Metallographic and microdurometric method as well as new technique were used to study kinetics of internal oxidation (IO). It is shown that study of IO kinetics on the base of metallographic measurements of layers depth is not correct because it is related with insufficient sensitivity of the method. IO kinetics under conditions of formation of molybdenum oxide layer on saturated material surface as well as IO of alloy with high carbon content were investigated. Oxide film formation does not affect the IO kinetics; decarburization observed along with oxidation increases the apparent activation energy and K exponent on time dependence of diffusion layer depth

  14. Amplitude dependent damping in single crystalline high purity molybdenum

    International Nuclear Information System (INIS)

    Zelada-Lambri, G.I; Lambri, O.A; Garcia, J.A; Lomer, J.N

    2004-01-01

    Amplitude dependent damping measurements were performed on high purity single crystalline molybdenum at several different constant temperatures between room temperature and 1273K. The employed samples were single crystals with the orientation, having a residual resistivity ratio of about 8000. Previously to the amplitude dependent damping tests, the samples were subjected to different thermomechanical histories. Amplitude dependent damping effects appear only during the first heating run in temperature where the samples have the thermomechanical state of the deformation process at room temperature. In the subsequent run-ups in temperature, i.e, after subsequent annealings, amplitude dependent damping effects were not detected (au)

  15. Magnetite effect in radionuclide retention : cesium, strontium, molybdenum and selenium

    International Nuclear Information System (INIS)

    Rovira, M.; Casas, I.; Gimenez, J.; Clarens, F.; Pablo, J. de

    2004-01-01

    In this work we have investigated the interaction of magnetite with cesium, strontium, molybdenum and selenium, in the frame of radionuclide retention by canister corrosion products. For each radionuclide, the retention on magnetite has been studied as a function of pH and the mass/ volume ratio. The experimental results have been modeled by means of Surface Complexation Models (SCM), that constitute a tool that allows an approach to sorption mechanisms in a wide range of experimental conditions taking into account electrostatic interactions at the mineral-water interface.(Author)

  16. Microstructure and mechanical properties of molybdenum silicides with Al additions

    International Nuclear Information System (INIS)

    Rosales, I.; Bahena, D.; Colin, J.

    2007-01-01

    Several molybdenum silicides alloys with different aluminum additions were produced by the arc-cast method. Microstructure observed in the alloys presented a variation of the precipitated second phase respect to the aluminum content. Evaluation of the compressive behavior at high temperature of the alloys shows an important improvement in its ductility, approximately of 20%. Fracture toughness was increased proportionally with Al content. In addition at room temperature the alloys show a better mechanical behavior in comparison with the sample unalloyed. In general, Al additions result to be a good alternative to improve the resistance of these intermetallic alloys. The results are interpreted on the base of the analysis of second phase strengthening

  17. Rapid diffusion of molybdenum trace contamination in silicon

    International Nuclear Information System (INIS)

    Tobin, S.P.; Greenwald, A.C.; Wolfson, R.G.; Meier, D.L.; Drevinsky, P.J.

    1985-01-01

    Molybdenum contamination has been detected in silicon epitaxial layers and substrate wafers after processing in any one of several epitaxial silicon reactors. Greatly reduced minority carrier diffusion lengths and lifetimes are consistent with Mo concentrations measured by DLTS in the 10 12 and 10 13 cm -3 ranges. Depth profiling of diffusion length and the Mo deep level show much greater penetration than expected from previous reports of Mo as a slow diffuser. The data indicate a lower limit of 10 -8 cm 2 /sec for the diffusion coefficient of Mo in silicon at 1200 0 C, consistent with high diffusivities measured for other transition metals

  18. Influence of Chromium and Molybdenum on the Corrosion of Nickel Based Alloys

    International Nuclear Information System (INIS)

    Hayes, J R; Gray, J; Szmodis, A W; Orme, C A

    2005-01-01

    The addition of chromium and molybdenum to nickel creates alloys with exceptional corrosion resistance in a diverse range of environments. This study examines the complementary roles of Cr and Mo in Ni alloy passivation. Four nickel alloys with varying amounts of chromium and molybdenum were studied in 1 molar salt solutions over a broad pH range. The passive corrosion and breakdown behavior of the alloys suggests that chromium is the primary element influencing general corrosion resistance. The breakdown potential was nearly independent of molybdenum content, while the repassivation potential is strongly dependant on the molybdenum content. This indicates that chromium plays a strong role in maintaining the passivity of the alloy, while molybdenum acts to stabilize the passive film after a localized breakdown event

  19. Use of molybdenum as a structural material of fuel elements for improving nuclear reactors safety

    Energy Technology Data Exchange (ETDEWEB)

    Shmelev, Anatoly N.; Kulikov, Gennady G.; Kozhahmet, Bauyrzhan K.; Kulikov, Evgeny G.; Apse, Vladimir A. [National Research Nuclear Univ., Moscow (Russian Federation). Moscow Engineering Physics Institute (MEPhI)

    2016-12-15

    Main purpose of the study is justifying the use of molybdenum as a structural material of fuel elements for improving the safety of nuclear reactors. Particularity of the used molybdenum is that its isotopic composition corresponds to molybdenum, which is obtained as tailing during operation of the separation cascade for producing a material for medical diagnostics of cancer. The following results were obtained: A method for reducing the thermal constant of fuel elements for light water and fast reactors by using dispersion fuel in cylindrical fuel rods containing, for example, granules of metallic U-Mo-alloy into Mo-matrix was proposed; the necessity of molybdenum enrichment by weakly absorbing isotopes was shown; total use of isotopic molybdenum will be more than 50 %.

  20. Recovery of molybdenum metal powder from a low grade molybdenite concentrate

    International Nuclear Information System (INIS)

    Mukherjee, T.K.; Menon, P.R.; Shukla, P.P.; Gupta, C.K.

    1988-01-01

    An account is given of the development of a process for the production of molybdenum metal powder from a low grade molybdenite concentrate. The molybdenum value present in the concentrate was leached with a dilute hypochlorite solution generated in-situ by electrolysis of brine solution. The leach liquor was subsequently purified by carbon adsorption process. The leach liquor was chemically processed to recover the molybdenum value in the forms of calcium molybdate and ammonium molybdate salts. These molybdenum intermediates were hydrogen-reduced to metallic molybdenum powder. The experimental set up used, procedure followed and results obtained are discussed and a flowsheet indicating the entire processing scheme is included. 11 refs., 4 figs., 8 tabs

  1. Constructing experimental devices for half-ton synthesis of gadolinium-loaded liquid scintillator and its performance

    Science.gov (United States)

    Park, Young Seo; Jang, Yeong Min; Joo, Kyung Kwang

    2018-04-01

    This paper describes in brief features of various experimental devices constructed for half-ton synthesis of gadolinium(Gd)-loaded liquid scintillator (GdLS) and also includes the performances and detailed chemical and physical results of a 0.5% high-concentration GdLS. Various feasibility studies on useful apparatus used for loading Gd into solvents have been carried out. The transmittance, Gd concentration, density, light yield, and moisture content were measured for quality control. We show that with the help of adequate automated experimental devices and tools, it is possible to perform ton scale synthesis of GdLS at moderate laboratory scale without difficulty. The synthesized GdLS was satisfactory to meet chemical, optical, and physical properties and various safety requirements. These synthesizing devices can be expanded into massive scale next-generation neutrino experiments of several hundred tons.

  2. Study of light detection and sensitivity for a ton-scale liquid xenon dark matter detector

    International Nuclear Information System (INIS)

    Wei, Y; Lin, Q; Xiao, X; Ni, K

    2013-01-01

    Ton-scale liquid xenon detectors operated in two-phase mode are proposed and being constructed recently to explore the favored parameter space for the Weakly Interacting Massive Particles (WIMPs) dark matter. To achieve a better light collection efficiency while limiting the number of electronics channels compared to the previous generation detectors, large-size photo-multiplier tubes (PMTs) such as the 3-inch-diameter R11410 from Hamamatsu are suggested to replace the 1-inch-square R8520 PMTs. In a two-phase xenon dark matter detector, two PMT arrays on the top and bottom are usually used. In this study, we compare the performance of two different ton-scale liquid xenon detector configurations with the same number of either R11410 (config.1) or R8520 (config.2) for the top PMT array, while both using R11410 PMTs for the bottom array. The self-shielding of liquid xenon suppresses the background from the PMTs and the dominant background is from the pp solar neutrinos in the central fiducial volume. The light collection efficiency for the primary scintillation light is largely affected by the xenon purity and the reflectivity of the reflectors. In the optimistic situation with a 10 m light absorption length and a 95% reflectivity, the light collection efficiency is 43%(34%) for config.1(config.2). In the conservative situation with a 2.5 m light absorption length and a 85% reflectivity, the value is only 18%(13%) for config.1(config.2). The difference between the two configurations is due to the larger PMT coverage on the top for config.1. The slightly different position resolutions for the two configurations have a negligible effect on the sensitivity. Based on the above considerations, we estimate the sensitivity reach of the two detector configurations. Both configurations can reach a sensitivity of 2 ∼ 3 × 10 −47 cm 2 for spin-independent WIMP-nucleon cross section for 100 GeV/c 2 WIMPs after two live-years of operation. The one with R8520 PMTs for the top

  3. Metrics, Media and Advertisers: Discussing Relationship

    Directory of Open Access Journals (Sweden)

    Marco Aurelio de Souza Rodrigues

    2014-11-01

    Full Text Available This study investigates how Brazilian advertisers are adapting to new media and its attention metrics. In-depth interviews were conducted with advertisers in 2009 and 2011. In 2009, new media and its metrics were celebrated as innovations that would increase advertising campaigns overall efficiency. In 2011, this perception has changed: New media’s profusion of metrics, once seen as an advantage, started to compromise its ease of use and adoption. Among its findings, this study argues that there is an opportunity for media groups willing to shift from a product-focused strategy towards a customer-centric one, through the creation of new, simple and integrative metrics

  4. Networks and centroid metrics for understanding football

    African Journals Online (AJOL)

    Gonçalo Dias

    games. However, it seems that the centroid metric, supported only by the position of players in the field ...... the strategy adopted by the coach (Gama et al., 2014). ... centroid distance as measures of team's tactical performance in youth football.

  5. Clean Cities Annual Metrics Report 2009 (Revised)

    Energy Technology Data Exchange (ETDEWEB)

    Johnson, C.

    2011-08-01

    Document provides Clean Cities coalition metrics about the use of alternative fuels; the deployment of alternative fuel vehicles, hybrid electric vehicles (HEVs), and idle reduction initiatives; fuel economy activities; and programs to reduce vehicle miles driven.

  6. Metric Guidelines Inservice and/or Preservice

    Science.gov (United States)

    Granito, Dolores

    1978-01-01

    Guidelines are given for designing teacher training for going metric. The guidelines were developed from existing guidelines, journal articles, a survey of colleges, and the detailed reactions of a panel. (MN)

  7. Science and Technology Metrics and Other Thoughts

    National Research Council Canada - National Science Library

    Harman, Wayne; Staton, Robin

    2006-01-01

    This report explores the subject of science and technology metrics and other topics to begin to provide Navy managers, as well as scientists and engineers, additional tools and concepts with which to...

  8. Using Activity Metrics for DEVS Simulation Profiling

    Directory of Open Access Journals (Sweden)

    Muzy A.

    2014-01-01

    Full Text Available Activity metrics can be used to profile DEVS models before and during the simulation. It is critical to get good activity metrics of models before and during their simulation. Having a means to compute a-priori activity of components (analytic activity may be worth when simulating a model (or parts of it for the first time. After, during the simulation, analytic activity can be corrected using dynamic one. In this paper, we introduce McCabe cyclomatic complexity metric (MCA to compute analytic activity. Both static and simulation activity metrics have been implemented through a plug-in of the DEVSimPy (DEVS Simulator in Python language environment and applied to DEVS models.

  9. Evaluating and Estimating the WCET Criticality Metric

    DEFF Research Database (Denmark)

    Jordan, Alexander

    2014-01-01

    a programmer (or compiler) from targeting optimizations the right way. A possible resort is to use a metric that targets WCET and which can be efficiently computed for all code parts of a program. Similar to dynamic profiling techniques, which execute code with input that is typically expected...... for the application, based on WCET analysis we can indicate how critical a code fragment is, in relation to the worst-case bound. Computing such a metric on top of static analysis, incurs a certain overhead though, which increases with the complexity of the underlying WCET analysis. We present our approach...... to estimate the Criticality metric, by relaxing the precision of WCET analysis. Through this, we can reduce analysis time by orders of magnitude, while only introducing minor error. To evaluate our estimation approach and share our garnered experience using the metric, we evaluate real-time programs, which...

  10. 16 CFR 1511.8 - Metric references.

    Science.gov (United States)

    2010-01-01

    ... 16 Commercial Practices 2 2010-01-01 2010-01-01 false Metric references. 1511.8 Section 1511.8 Commercial Practices CONSUMER PRODUCT SAFETY COMMISSION FEDERAL HAZARDOUS SUBSTANCES ACT REGULATIONS... parentheses for convenience and information only. ...

  11. Flight Crew State Monitoring Metrics, Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — eSky will develop specific crew state metrics based on the timeliness, tempo and accuracy of pilot inputs required by the H-mode Flight Control System (HFCS)....

  12. Supplier selection using different metric functions

    Directory of Open Access Journals (Sweden)

    Omosigho S.E.

    2015-01-01

    Full Text Available Supplier selection is an important component of supply chain management in today’s global competitive environment. Hence, the evaluation and selection of suppliers have received considerable attention in the literature. Many attributes of suppliers, other than cost, are considered in the evaluation and selection process. Therefore, the process of evaluation and selection of suppliers is a multi-criteria decision making process. The methodology adopted to solve the supplier selection problem is intuitionistic fuzzy TOPSIS (Technique for Order Preference by Similarity to the Ideal Solution. Generally, TOPSIS is based on the concept of minimum distance from the positive ideal solution and maximum distance from the negative ideal solution. We examine the deficiencies of using only one metric function in TOPSIS and propose the use of spherical metric function in addition to the commonly used metric functions. For empirical supplier selection problems, more than one metric function should be used.

  13. Behavior of molybdenum in pyrochemical reprocessing: A spectroscopic study of the chlorination of molybdenum and its oxides in chloride melts

    International Nuclear Information System (INIS)

    Volkovicha, Vladimir A.; Griffiths, Trevor R.; Thied, Robert C.; Lewin, Bob

    2003-01-01

    The high temperature reactions of molybdenum and its oxides with chlorine and hydrogen chloride in molten alkali metal chlorides were investigated between 400 and 700 deg. C. The melts studied were LiCl-KCl, NaCl-CsCl and NaCl-KCl and the reactions were followed by in situ electronic absorption spectroscopy measurements. In these melts Mo reacts with Cl 2 and initially produces MoCl 6 2- and then a mixture of Mo(III) and Mo(V) chlorocomplexes, the final proportion depending on the reaction conditions. The Mo(V) content can be removed as MoCl 5 from the melt under vacuum or be reduced to Mo(III) by Mo metal. The reaction of Mo when HCl gas is bubbled into alkali chloride melts yields only MoCl 6 3- . MoO 2 reacts in these melts with chlorine to form soluble MoOCl 5 2- and volatile MoO 2 Cl 2 . MoO 3 is soluble in chloride melts and then decomposes into the oxychloride MoO 2 Cl 2 , which sublimes or can be sparged from the melt, and molybdate. Pyrochemical reprocessing can thus be employed for molybdenum since, after various intermediates, the end-products are chloride melts containing chloro and oxychloro anions of molybdenum plus molybdate, and volatile chlorides and oxychlorides that can be readily separated off. The reactions were fastest in the NaCl-KCl melt. The X-ray diffraction pattern of MoO 2 Cl 2 is reported for the first time

  14. Nouvelles Techniques d'Intervention sur la Corrosion des Armatures du Béton Armé

    CERN Document Server

    Colloca, C

    1999-01-01

    Les principaux dégâts constatés dans les armatures passives du béton armé sont la corrosion généralisée et la corrosion locale. Ces dégradations sont provoquées soit par la carbonatation du béton soit par le contact avec l'eau pure ou l'eau chargée de chlorures pénétrant dans les pores et dans les fissures de surface. Ce document présente de nouvelles techniques d'intervention, fondées sur d'anciens principes, introduites pour le traitement électrochimique des zones altérées liées aux différentes conditions. La réalcalinisation (dans le cas de béton carbonaté) permet d'augmenter le pH du béton et de rétablir un niveau de basicité garantissant la passivation de l'armature. La désalification (dans le cas de béton entamé par les chlorures) provoque l'élimination des ions chlorure à travers la surface du béton. Les avantages de ces traitements, par rapport aux anciennes techniques, sont appréciables si l'on considère la durée d'exécution et leur coût moins élevé.

  15. Classroom reconstruction of the Schwarzschild metric

    OpenAIRE

    Kassner, Klaus

    2015-01-01

    A promising way to introduce general relativity in the classroom is to study the physical implications of certain given metrics, such as the Schwarzschild one. This involves lower mathematical expenditure than an approach focusing on differential geometry in its full glory and permits to emphasize physical aspects before attacking the field equations. Even so, in terms of motivation, lacking justification of the metric employed may pose an obstacle. The paper discusses how to establish the we...

  16. Marketing communication metrics for social media

    OpenAIRE

    Töllinen, Aarne; Karjaluoto, Heikki

    2011-01-01

    The objective of this paper is to develop a conceptual framework for measuring the effectiveness of social media marketing communications. Specifically, we study whether the existing marketing communications performance metrics are still valid in the changing digitalised communications landscape, or whether it is time to rethink them, or even to devise entirely new metrics. Recent advances in information technology and marketing bring a need to re-examine measurement models. We combine two im...

  17. Some observations on a fuzzy metric space

    Energy Technology Data Exchange (ETDEWEB)

    Gregori, V.

    2017-07-01

    Let $(X,d)$ be a metric space. In this paper we provide some observations about the fuzzy metric space in the sense of Kramosil and Michalek $(Y,N,/wedge)$, where $Y$ is the set of non-negative real numbers $[0,/infty[$ and $N(x,y,t)=1$ if $d(x,y)/leq t$ and $N(x,y,t)=0$ if $d(x,y)/geq t$. (Author)

  18. Area Regge calculus and discontinuous metrics

    International Nuclear Information System (INIS)

    Wainwright, Chris; Williams, Ruth M

    2004-01-01

    Taking the triangle areas as independent variables in the theory of Regge calculus can lead to ambiguities in the edge lengths, which can be interpreted as discontinuities in the metric. We construct solutions to area Regge calculus using a triangulated lattice and find that on a spacelike or timelike hypersurface no such discontinuity can arise. On a null hypersurface however, we can have such a situation and the resulting metric can be interpreted as a so-called refractive wave

  19. Relaxed metrics and indistinguishability operators: the relationship

    Energy Technology Data Exchange (ETDEWEB)

    Martin, J.

    2017-07-01

    In 1982, the notion of indistinguishability operator was introduced by E. Trillas in order to fuzzify the crisp notion of equivalence relation (/cite{Trillas}). In the study of such a class of operators, an outstanding property must be pointed out. Concretely, there exists a duality relationship between indistinguishability operators and metrics. The aforesaid relationship was deeply studied by several authors that introduced a few techniques to generate metrics from indistinguishability operators and vice-versa (see, for instance, /cite{BaetsMesiar,BaetsMesiar2}). In the last years a new generalization of the metric notion has been introduced in the literature with the purpose of developing mathematical tools for quantitative models in Computer Science and Artificial Intelligence (/cite{BKMatthews,Ma}). The aforementioned generalized metrics are known as relaxed metrics. The main target of this talk is to present a study of the duality relationship between indistinguishability operators and relaxed metrics in such a way that the aforementioned classical techniques to generate both concepts, one from the other, can be extended to the new framework. (Author)

  20. Ici, la priorité est aux piétons / Pedestrians have the right of way at CERN

    CERN Multimedia

    2002-01-01

    Au CERN, nous sommes tous piétons, très souvent automobilistes et parfois cyclistes. Mais peu importe notre moyen de locomotion si l'on reste vigilant et si l'on se rappelle que le piéton est un usager de la route à part entière, mais plus vulnérable. / At CERN, we are all pedestrians, often drivers, and occasionally cyclists. But our means of locomotion do no matter so long as we exercise caution and remember that a pedestrian has equal rights as a roa user, except than that he runs greater risks.

  1. Atomic Layer-Deposited Molybdenum Oxide/Carbon Nanotube Hybrid Electrodes: The Influence of Crystal Structure on Lithium-Ion Capacitor Performance.

    Science.gov (United States)

    Fleischmann, Simon; Zeiger, Marco; Quade, Antje; Kruth, Angela; Presser, Volker

    2018-05-25

    Merging of supercapacitors and batteries promises the creation of electrochemical energy storage devices that combine high specific energy, power, and cycling stability. For that purpose, lithium-ion capacitors (LICs) that store energy by lithiation reactions at the negative electrode and double-layer formation at the positive electrode are currently investigated. In this study, we explore the suitability of molybdenum oxide as a negative electrode material in LICs for the first time. Molybdenum oxide-carbon nanotube hybrid materials were synthesized via atomic layer deposition, and different crystal structures and morphologies were obtained by post-deposition annealing. These model materials are first structurally characterized and electrochemically evaluated in half-cells. Benchmarking in LIC full-cells revealed the influences of crystal structure, half-cell capacity, and rate handling on the actual device level performance metrics. The energy efficiency, specific energy, and power are mainly influenced by the overpotential and kinetics of the lithiation reaction during charging. Optimized LIC cells show a maximum specific energy of about 70 W·h·kg -1 and a high specific power of 4 kW·kg -1 at 34 W·h·kg -1 . The longevity of the LIC cells is drastically increased without significantly reducing the energy by preventing a deep cell discharge, hindering the negative electrode from crossing its anodic potential limit.

  2. Simultaneous spectrophotometric determination of tungsten and molybdenum with dithiol

    International Nuclear Information System (INIS)

    Navale, A.S.

    1987-01-01

    Toluene-3,4-dithiol is a very sensitive reagent for the spectrophotometric determination of tungsten and molybdenum. Since the absorption spectra of the dithiol complexes of these two elements overlap, a separation of the two elements is carried out. This leads to time consuming extraction procedures. Measuring the absorption of the mixed complexes at two wavelengths and solving a set of simultaneous equations is also not favorable because a lot of time and effort is required for solving the simultaneous equations for each sample. A faster and simpler method is described here for the simultaneous determination of the two elements. The method is based on measurement of absorbance of the mixed complexes at three pre-selected wavelengths and simple calculations involving the absorbance differences. The criteria for selecting the three wavelengths and the theory are described. Application of the method for the determination of tungsten and molybdenum in ore samples is presented. The method is applicable to any similar system consisting of two interfering components. 4 figures, 2 tables, 6 refs. (author)

  3. Synthesis and characterization of several molybdenum chloride cluster compounds

    Energy Technology Data Exchange (ETDEWEB)

    Beers, W.W.

    1983-06-01

    Investigation into the direct synthesis of Mo/sub 4/Cl/sub 8/(P(C/sub 2/H/sub 5/)/sub 3/)/sub 4/ from Mo/sub 2/(OAc)/sub 4/ led to a synthetic procedure that produces yields greater than 80%. The single-crystal structure disclosed a planar rectangular cluster of molybdenum atoms. Metal-metal bond distances suggest that the long edges of the rectangular cluster should be considered to be single bonds and the short metal-metal bonds to be triple bonds. This view is reinforced by an extended Hueckel calculation. Attempts to add a metal atom to Mo/sub 4/Cl/sub 8/(PR/sub 3/)/sub 4/ to form Mo/sub 5/Cl/sub 10/(PR/sub 3/)/sub 3/ led instead to a compound with the composition Mo/sub 8/Cl/sub 16/(PR/sub 3/)/sub 4/. Solution and reflectance uv-visible spectra and x-ray photoelectron spectra suggest that tetranuclear molybdenum units are present. The facile reaction between Mo/sub 8/Cl/sub 16/(PR/sub 3/)/sub 4/ and PR/sub 3/ imply that the linkage between tetrameric units is weak.

  4. Reprocessability of molybdenum and magnesia based inert matrix fuels

    Directory of Open Access Journals (Sweden)

    Ebert Elena L.

    2015-12-01

    Full Text Available This work focuses on the reprocessability of metallic 92Mo and ceramic MgO, which is under investigation for (Pu,MA-oxide (MA = minor actinide fuel within a metallic 92Mo matrix (CERMET and a ceramic MgO matrix (CERCER. Magnesium oxide and molybdenum reference samples have been fabricated by powder metallurgy. The dissolution of the matrices was studied as a function of HNO3 concentration (1-7 mol/L and temperature (25-90°C. The rate of dissolution of magnesium oxide and metallic molybdenum increased with temperature. While the MgO rate was independent of the acid concentration (1-7 mol/L, the rate of dissolution of Mo increased with acid concentration. However, the dissolution of Mo at high temperatures and nitric acid concentrations was accompanied by precipitation of MoO3. The extraction of uranium, americium, and europium in the presence of macro amounts of Mo and Mg was studied by three different extraction agents: tri-n-butylphosphate (TBP, N,Nʹ-dimethyl-N,Nʹ-dioctylhexylethoxymalonamide (DMDOHEMA, and N,N,N’,N’- -tetraoctyldiglycolamide (TODGA. With TBP no extraction of Mo and Mg occurred. Both matrix materials are partly extracted by DMDOHEMA. Magnesium is not extracted by TODGA (D < 0.1, but a weak extraction of Mo is observed at low Mo concentration.

  5. Recovery of molybdenum and cobalt powders from spent hydrogenation catalyst

    International Nuclear Information System (INIS)

    Rabah, M.A.; Hewaidy, I.F.; Farghaly, F.E.

    1996-01-01

    Free powders as well as compact shapes of molybdenum and cobalt have been successfully recovered from spent hydrogenation and desulphurization catalysts. A process flow sheet was followed involving crushing, milling, particle sizing, hydrometallurgical acid leaching roasting of the obtained salts in an atmospheric oxygen to obtain the respective oxides. These were reduced by hydrogen gas at 110 degree C and 900 degree C respectively. Parameters affecting the properties of the products and the recovery efficiency value such as acid concentration, particle diameter of the solid catalyst, temperature time under a constant mass flow rate the hydrogen gas, have been investigated. A mixture of concentration.sulphuric and nitric acids (3:1 by volume) achieved adequate recovery of both metals. The latter increased with the increase in acid concentration, time up 10 3 hours and temperature: 100 degree C and with the decrease in particle diameter of the spent catalyst. The PH of the obtained filtrate was adjusted to 2 with ammonia to precipitate insoluble ammonium molybdate and a solution of cobalt sulphate. Cobalt hydroxide can be precipitate from the latter solution at a PH = 7.6 using excess ammonium hydroxide solution. The obtained results showed that the metallic products are technically pure meeting the standard specifications. Compact shapes of molybdenum acquire density values increasing with the increase of the pressing load whereby a maximum density value of 2280 kg/m 3 is attained at 0.75 MPa. Maximum recovery efficiency amounts to 96%. 10 figs., 3 tabs

  6. Materials and Breakdown Phenomena: Heterogeneous Molybdenum Metallic Films

    Directory of Open Access Journals (Sweden)

    Augusto Marcelli

    2017-05-01

    Full Text Available Technological activities to design, manufacture, and test new accelerating devices using different materials and methods is under way all over the world. The main goal of these studies is to increase the accelerating gradients and reduce the probability of radio-frequency (RF breakdown. Indeed, it is still not clear why, by increasing the intensity of the applied field, intense surface damage is observed in copper structures, limiting the lifetime and, therefore, the practical applications. A possible solution is represented by a coating of a relatively thick layer of molybdenum in order to improve the breakdown rate. molybdenum can be reliably grown on different substrates with a negligible strain and, for thicknesses up to 600 nm, with a resistivity < 100–150·μΩ cm. Moreover, Mo coatings with controlled composition, internal stress, and roughness may allow improving thermo-mechanical properties reaching values not attainable by uncoated copper. Although the Mo conductivity remains lower compared to Cu, a Mo coating represents a very interesting option for high gradient accelerator components manufactured in copper.

  7. Regularities of the vertical distribution of uranium-molybdenum mineralization

    International Nuclear Information System (INIS)

    Konstantinov, V.M.; Kazantsev, V.V.; Protasov, V.N.

    1980-01-01

    The geological structure of one of ore fields of the uranium-molybdenum formation pertaining to the northern framing of a large volcano-tectonic depression is studied. The main uranium deposits are related to necks formed by neck facies of brown liparites. Three zones are singled out within the limits of the ore field. In the upper one there are small ore bodies with a low uranium content represented by phenolite-chlorite, pitchblende 3-coffinite 3-jordizite and calcinite-sulphide associations, in the middle one - the main ore bodies formed by pitchblende 1-chlorite, molybdenite 2 (jordizite)-pitchblende 2-hydromica, coffinite 2-pyrite associations; in the lower one-thin veinlets formed by coffinite-molybdenite 1-chlorite, brannerite-pyrite and pitchblende 1-chlorite associations. Dimensions of the ore deposits depend on the neck sizes: in small necks the middle zone and, rarely, the lower one are of the industrial interest; in the large ones - the upper middle and, probably, lower ones. The regularities found can be extended to other deposits of the uranium-molybdenum formation [ru

  8. Predicted crystal structures of molybdenum under high pressure

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Bing; Zhang, Guang Biao [Institute for Computational Materials Science, School of Physics and Electronics, Henan University, Kaifeng 475004 (China); Wang, Yuan Xu, E-mail: wangyx@henu.edu.cn [Institute for Computational Materials Science, School of Physics and Electronics, Henan University, Kaifeng 475004 (China); Guizhou Provincial Key Laboratory of Computational Nano-Material Science, Institute of Applied Physics, Guizhou Normal College, Guiyang 550018 (China)

    2013-04-15

    Highlights: ► A double-hexagonal close-packed (dhcp) structure of molybdenum is predicted. ► Calculated acoustic velocity confirms the bcc–dhcp phase transition at 660 GPa. ► The valence electrons of dhcp Mo are mostly localized in the interstitial sites. -- Abstract: The high-pressure structures of molybdenum (Mo) at zero temperature have been extensively explored through the newly developed particle swarm optimization (PSO) algorithm on crystal structural prediction. All the experimental and earlier theoretical structures were successfully reproduced in certain pressure ranges, validating our methodology in application to Mo. A double-hexagonal close-packed (dhcp) structure found by Mikhaylushkin et al. (2008) [12] is confirmed by the present PSO calculations. The lattice parameters and physical properties of the dhcp phase were investigated based on first principles calculations. The phase transition occurs only from bcc phase to dhcp phase at 660 GPa and at zero temperature. The calculated acoustic velocities also indicate a transition from the bcc to dhcp phases for Mo. More intriguingly, the calculated density of states (DOS) shows that the dhcp structure remains metallic. The calculated electron density difference (EDD) reveals that its valence electrons are localized in the interstitial regions.

  9. Consideration on the 1 ton bucket elevator installed under water of pool in IMEF

    Energy Technology Data Exchange (ETDEWEB)

    Song, Ung Sup; Lee, Jong Heon; Lee, Hong Gi; Choo, Yong Sun; Jung, Yang Hong [Korea Atomic Energy Research Institute, Taejon (Korea, Republic of)

    2004-07-01

    The bucket elevator which can transfer examination capsule or fuel from pool to hot cell is installed under water of pool (3x6x10 m) in IMEF. A allowable load is 1 ton and the dimension of bucket is 25x25x150 cm. The upper and lower sides motion of bucket have about 63 degrees inclined duties with a chain driving system. A specialized made chain catches a rug of bucket with a roller sliding way between right and left guide rails which are fixed at inner of a square tube and moves to an upper and lower sides and it is made so that it is operated by sprocket wheel installed in a hot cell working table below. Sprocket wheel is executed to two steps of driving shaft by reduction geared motor installed at right outside of M1 hot cell. As for the starting operation, it is executed by push an operation button on a operating panel located at front of M1 hot cell.

  10. Study of hot cracking potential in a 6-ton steel ingot casting

    Science.gov (United States)

    Yang, Jing'an; Liu, Baicheng; Shen, Houfa

    2018-04-01

    A new hot cracking potential (HCP) criterion, for the appearance of hot tearing in steel ingot castings, is proposed. The maximum value of the first principal stress, divided by the dynamic yield strength in the brittle temperature range (BTR), was used to identify the HCP. Experiments were carried out on a 6-ton P91 steel ingot in which severe hot tearing was detected in the upper centerline. Another ingot, with a better heat preservation riser, and without hot tearing, was used for comparison. Samples were obtained from the area of the ingot body with hot tearing, and their morphologies were inspected by a X-ray high energy industrial computed tomography. The carbon and sulfur distributions around the hot tearing were characterized by an infrared spectrometry carbon and sulfur analyzer. High temperature mechanical properties were obtained by a Gleeble thermal simulation machine, under different strain rates. Then, thermo-mechanical simulations using an elasto-viscoplastic finite-element model were conducted to analyze the stress and strain evolution during ingot solidification. The results showed that the hot tearing area, which was rich in both carbon and sulfur, was under excessive tensile stress in the BTR, bearing the highest HCP.

  11. 1000–ton testing machine for cyclic fatigue tests of materials at liquid nitrogen temperatures

    Energy Technology Data Exchange (ETDEWEB)

    Khitruk, A. A.; Klimchenko, Yu. A.; Kovalchuk, O. A.; Marushin, E. L.; Mednikov, A. A.; Nasluzov, S. N.; Privalova, E. K.; Rodin, I. Yu.; Stepanov, D. B.; Sukhanova, M. V. [The D.V. Efremov Scientific Research Institute of Electrophysical Apparatus (NIIEFA), 3 Doroga na Metallostroy, Metallostroy, Saint Petersburg 196641 (Russian Federation)

    2014-01-29

    One of the main tasks of superconductive magnets R and D is to determine the mechanical and fatigue properties of structural materials and the critical design elements in the cryogenic temperature range. This paper describes a new facility built based on the industrial 1000-ton (10 MN) testing machine Schenk PC10.0S. Special equipment was developed to provide the mechanical and cyclic tensile fatigue tests of large-scale samples at the liquid nitrogen temperature and in a given load range. The main feature of the developed testing machine is the cryostat, in which the device converting a standard compression force of the testing machine to the tensile force affected at the test object is placed. The control system provides the remote control of the test and obtaining, processing and presentation of test data. As an example of the testing machine operation the test program and test results of the cyclic tensile fatigue tests of fullscale helium inlet sample of the PF1 coil ITER are presented.

  12. 1000–ton testing machine for cyclic fatigue tests of materials at liquid nitrogen temperatures

    International Nuclear Information System (INIS)

    Khitruk, A. A.; Klimchenko, Yu. A.; Kovalchuk, O. A.; Marushin, E. L.; Mednikov, A. A.; Nasluzov, S. N.; Privalova, E. K.; Rodin, I. Yu.; Stepanov, D. B.; Sukhanova, M. V.

    2014-01-01

    One of the main tasks of superconductive magnets R and D is to determine the mechanical and fatigue properties of structural materials and the critical design elements in the cryogenic temperature range. This paper describes a new facility built based on the industrial 1000-ton (10 MN) testing machine Schenk PC10.0S. Special equipment was developed to provide the mechanical and cyclic tensile fatigue tests of large-scale samples at the liquid nitrogen temperature and in a given load range. The main feature of the developed testing machine is the cryostat, in which the device converting a standard compression force of the testing machine to the tensile force affected at the test object is placed. The control system provides the remote control of the test and obtaining, processing and presentation of test data. As an example of the testing machine operation the test program and test results of the cyclic tensile fatigue tests of fullscale helium inlet sample of the PF1 coil ITER are presented

  13. High temperature experiments on a 4 tons UF6 container TENERIFE program

    Energy Technology Data Exchange (ETDEWEB)

    Casselman, C.; Duret, B.; Seiler, J.M.; Ringot, C.; Warniez, P.

    1991-12-31

    The paper presents an experimental program (called TENERIFE) whose aim is to investigate the behaviour of a cylinder containing UF{sub 6} when exposed to a high temperature fire for model validation. Taking into account the experiments performed in the past, the modelization needs further information in order to be able to predict the behaviour of a real size cylinder when engulfed in a 800{degrees}C fire, as specified in the regulation. The main unknowns are related to (1) the UF{sub 6} behaviour beyond the critical point, (2) the relationship between temperature field and internal pressure and (3) the equivalent conductivity of the solid UF{sub 6}. In order to investigate these phenomena in a representative way it is foreseen to perform experiments with a cylinder of real diameter, but reduced length, containing 4 tons of UF{sub 6}. This cylinder will be placed in an electrically heated furnace. A confinement vessel prevents any dispersion of UF{sub 6}. The heat flux delivered by the furnace will be calibrated by specific tests. The cylinder will be changed for each test.

  14. Eight Tons of Material Footprint—Suggestion for a Resource Cap for Household Consumption in Finland

    Directory of Open Access Journals (Sweden)

    Michael Lettenmeier

    2014-07-01

    Full Text Available The paper suggests a sustainable material footprint of eight tons, per person, in a year as a resource cap target for household consumption in Finland. This means an 80% (factor 5 reduction from the present Finnish average. The material footprint is used as a synonym to the Total Material Requirement (TMR calculated for products and activities. The paper suggests how to allocate the sustainable material footprint to different consumption components on the basis of earlier household studies, as well as other studies, on the material intensity of products, services, and infrastructures. It analyzes requirements, opportunities, and challenges for future developments in technology and lifestyle, also taking into account that future lifestyles are supposed to show a high degree of diversity. The targets and approaches are discussed for the consumption components of nutrition, housing, household goods, mobility, leisure activities, and other purposes. The paper states that a sustainable level of natural resource use by households is achievable and it can be roughly allocated to different consumption components in order to illustrate the need for a change in lifestyles. While the absolute material footprint of all the consumption components will have to decrease, the relative share of nutrition, the most basic human need, in the total material footprint is expected to rise, whereas much smaller shares than at present are proposed for housing and especially mobility. For reducing material resource use to the sustainable level suggested, both social innovations, and technological developments are required.

  15. Shrinkage Porosity Criterion and Its Application to A 5.5 Ton Steel Ingot

    Directory of Open Access Journals (Sweden)

    Zhang C.

    2016-06-01

    Full Text Available In order to predict the distribution of shrinkage porosity in steel ingot efficiently and accurately, a criterion R√L and a method to obtain its threshold value were proposed. The criterion R√L was derived based on the solidification characteristics of steel ingot and pressure gradient in the mushy zone, in which the physical properties, the thermal parameters, the structure of the mushy zone and the secondary dendrite arm spacing were all taken into consideration. The threshold value of the criterion R√L was obtained with combination of numerical simulation of ingot solidification and total solidification shrinkage rate. Prediction of the shrinkage porosity in a 5.5 ton ingot of 2Cr13 steel with criterion R√L>0.21 m · °C1/2 · s−3/2 agreed well with the results of experimental sectioning. Based on this criterion, optimization of the ingot was carried out by decreasing the height-to-diameter ratio and increasing the taper, which successfully eliminated the centreline porosity and further proved the applicability of this criterion.

  16. VALIDACIÓN RESISTIVA ESTRUCTURAL DE UN VARADERO PARA EMBARCACIONES DE 600 ton.

    Directory of Open Access Journals (Sweden)

    Carlos Novo Soto

    2005-09-01

    Full Text Available En el presente trabajo se valida la capacidad de carga portante de la estructura de un varadero a partirde las condiciones a resistencia y rigidez. El varadero consta de 2 carros trapezoidales, sobre los cualesse desplazan transversalmente 6 boggies, que permiten trasladar la embarcación varada hacia losapartaderos, así mismo dispone de 3 motores con sus respectivos sistemas de reducción y tamboras,uno de ellos permite sacar la embarcación que se encuentra soportada sobre los boggies y los 2 carroscunas, otro se emplea para retornar dicha embarcación al mar y el último se utiliza para desplazar laembarcación sobre los boggies, transversalmente a los carros cunas, hacia los apartaderos.Dada la complejidad estructural del sistema se desarrolla un modelo físico matemático, el que mediantela aplicación del Método de los Elementos Finitos, permite obtener los esfuerzos equivalente máximos deMises y los desplazamientos máximos con lo que finalmente se valida, a través del Análisis porElementos Finitos, la capacidad portante de la estructura para varar una embarcación de 600 ton.

  17. The economic value of one ton CO2: what system of reference for public action?

    International Nuclear Information System (INIS)

    2007-04-01

    Given the convergence of scientific analyses of global warming and its consequences for the planet - evaluated for years by the Intergovernmental Panel on Climate Change (IPCC) - it is no longer possible to postpone the efforts required to reduce our emissions of greenhouse gases substantially. However, the choice of actions to take and the calendar of priorities are proving complex to define: the social and economic consequences are great, and neither France (which represents 2% of global emissions) nor Europe (15%) are up to treating the problem independently of the rest of the world. Faced with this challenge, and with budgetary constraints imposing a rationalisation of expenditure, public action must have measuring instruments at its disposal: the value of one ton of carbon is one such instrument. This Strategic Newswatch has a twofold objective: to recall the usefulness of this reference value which, though it cannot guarantee the validity of different public policies, may contribute to ensuring their consistency; and to present the different approaches and difficulties that producing such a reference system introduces. (author)

  18. Application of anion-exchange techniques to the determination of traces of molybdenum in sea-water

    International Nuclear Information System (INIS)

    Kiriyama, T.; Kuroda, R.

    1984-01-01

    A combined ion-exchange spectrophotometric method has been developed for the determination of molybdenum in sea-water. Molybdenum is sorbed strongly on Amberlite CG 400 (Cl - ) at pH 3 from sea-water containing ascorbic acid and is easily eluted with 6 M nitric acid. Molybdenum in the effluent can be determined spectrophotometrically with potassium thiocyanate and stannous chloride. The combined method allows selective and sensitive determination of traces of molybdenum in sea-water. The precision of the method is 2% at a molybdenum level of approx. 10 μg/l. (author)

  19. Effect of pH and modifier-concentration on the solvent extraction of molybdenum with an alkyl amine

    International Nuclear Information System (INIS)

    Al-Siddique, F.R.; Adeler, I.; Huwyler, S.

    1980-07-01

    The results of the extraction behaviour of molybdenum in aqueous sulfuric acid solutions of an alkyl amine (amberlite LA-2) in kerosene under various pH and in the presence of various percentage of 1-octanol has been reported. The concentration of molybdenum employed was high enough to precipitate it partially during extraction as an amine-molybdenum complex. The maximum extraction coefficient was found to lie between pH 1.5-2.5. Presence of 1-octanol increased the extraction coefficient of molybdenum by increasing the solubility of the amine-molybdenum complex in the organic phase without changing the pH at the maximum extraction. (Auth.)

  20. Baby universe metric equivalent to an interior black-hole metric

    International Nuclear Information System (INIS)

    Gonzalez-Diaz, P.F.

    1991-01-01

    It is shown that the maximally extended metric corresponding to a large wormhole is the unique possible wormhole metric whose baby universe sector is conformally equivalent ot the maximal inextendible Kruskal metric corresponding to the interior region of a Schwarzschild black hole whose gravitational radius is half the wormhole neck radius. The physical implications of this result in the black hole evaporation process are discussed. (orig.)