Sample records for metamorphic core complexes

  1. Cordilleran metamorphic core complexes and their uranium favorability

    International Nuclear Information System (INIS)

    Coney, P.J.; Reynolds, S.J.


    The objective of this report is to provide a descriptive body of knowledge on Cordilleran metamorphic core complexes including their lithologic and structural characteristics, their distribution within the Cordillera, and their evolutionary history and tectonic setting. The occurrence of uranium in the context of possibility for uranium concentration is also examined. This volume contains appendices of the following: annotated bibliography of Cordilleran metamorphic core complexes; annotated bibliography of the uranium favorability of Cordilleran metamorphic core complexes; uranium occurrences in the Cordilleran metamorphic core complex belt; and geology, uranium favorability, uranium occurrences and tectonic maps of individual Cordilleran metamorphic core complexes; and locations, lithologic descriptions, petrographic information and analytical data for geochemical samples

  2. Cordilleran metamorphic core complexes and their uranium favorability. Final report

    International Nuclear Information System (INIS)

    Coney, P.J.; Reynolds, S.J.


    The objective of this report is to provide a descriptive body of knowledge on Cordilleran metamorphic core complexes including their lithologic and structural characteristics, their distribution within the Cordillera, and their evolutionary history and tectonic setting. The occurrence of uranium in the context of possibility for uranium concentration is also examined. Chapter 1 is an overview of Cordilleran metamorphic core complexes which describes their physical characteristics, tectonic setting and geologic history. This overview is accompanied by a tectonic map. Chapter 2 is a discussion of the mantled gneiss dome concept. The purpose of including this work is to provide a basic history of this concept and to describe the characteristics and distribution of gneiss domes throughout the world to enable one to compare and contrast them with the metamorphic core complexes as discussed in this report. Some gneiss domes are known producers of uranium (as are also some core complexes). Chapter 3 is an examination of the effects of the core complex process on adjacent sedimentary and volcanic cover terranes. Also included is a discussion of the kinematic significance of these cover terranes as they are related to process within the cores of the complexes. Some of the cover terranes have uranium prospects in them. Chapter 4 is a detailed discussion of uranium in Cordilleran metamorphic core complexes and includes the conceptual basis for the various types of occurrences and the processes that might favor concentration of uranium. The report is supported by a 5-part Appendix. The majority of the core complexes discussed in this report either do not appear or are not recognizable on existing published geologic maps

  3. Cretaceous metamorphic core complexes in the Otago Schist, New Zealand

    International Nuclear Information System (INIS)

    Forster, M.A.; Lister, G.S.


    The median antiformal axis of the Otago Schist, New Zealand, is marked by a zone of relatively high-grade (up to garnet-biotite-albite) greenschist facies rocks 40 Ar/ 39 Ar geochronology has been earned out in conjunction with structural analysis in regions distant from the effects of the Alpine Fault to determine the origin of this metamorphic welt. We have determined that the metamorphic welt is bounded on its northern and southern sides by multistage ductile shear zone(s) marked by intensely developed fabrics, and/or low-angle normal faults. These structures extend over a strike length of > ∼ 200 km and on the southern side of the metamorphic welt they mark the boundary between the Caples and the Torlesse terranes. The oldest such shear zone formed between 122 and 118 Ma. The metamorphic welt was exhumed beneath low-angle normal faults and ductile shear zones that formed from 112 to 109 Ma. The shear zones form the carapace to elongate domal culminations in the central Otago Schist. These geomorphological features are Cretaceous metamorphic core complexes dissected by younger Quaternary faults. Exhumation of the shear zones occurred shortly before volcanogenic sediments began to deposit on a Cretaceous unconformity. We propose that both the Cretaceous unconformity and the underlying ductile shear zones and low-angle faults are a direct result of extensional tectonism. The ductile shear zones display both 'cross-belt' and 'belt-parallel' stretching lineations. Cross-belt stretching may have been caused by rollback of the subducting Pacific slab. Belt parallel extension is interpreted to have taken place during extension associated with rifting between Australia and Antarctica, prior to breakup. Copyright (2003) Geological Society of Australia

  4. Metamorphic core complex formation by density inversion and lower-crust extrusion. (United States)

    Martinez, F; Goodliffe, A M; Taylor, B


    Metamorphic core complexes are domal uplifts of metamorphic and plutonic rocks bounded by shear zones that separate them from unmetamorphosed cover rocks. Interpretations of how these features form are varied and controversial, and include models involving extension on low-angle normal faults, plutonic intrusions and flexural rotation of initially high-angle normal faults. The D'Entrecasteaux islands of Papua New Guinea are actively forming metamorphic core complexes located within a continental rift that laterally evolves to sea-floor spreading. The continental rifting is recent (since approximately 6 Myr ago), seismogenic and occurring at a rapid rate ( approximately 25 mm yr-1). Here we present evidence-based on isostatic modelling, geological data and heat-flow measurements-that the D'Entrecasteaux core complexes accommodate extension through the vertical extrusion of ductile lower-crust material, driven by a crustal density inversion. Although buoyant extrusion is accentuated in this region by the geological structure present-which consists of dense ophiolite overlaying less-dense continental crust-this mechanism may be generally applicable to regions where thermal expansion lowers crustal density with depth.

  5. Late Cretaceous to Paleocene metamorphism and magmatism in the Funeral Mountains metamorphic core complex, Death Valley, California (United States)

    Mattinson, C.G.; Colgan, J.P.; Metcalf, J.R.; Miller, E.L.; Wooden, J.L.


    Amphibolite-facies Proterozoic metasedimentary rocks below the low-angle Ceno-zoic Boundary Canyon Detachment record deep crustal processes related to Meso-zoic crustal thickening and subsequent extension. A 91.5 ?? 1.4 Ma Th-Pb SHRIMP-RG (sensitive high-resolution ion microprobe-reverse geometry) monazite age from garnet-kyanite-staurolite schist constrains the age of prograde metamorphism in the lower plate. Between the Boundary Canyon Detachment and the structurally deeper, subparallel Monarch Spring fault, prograde metamorphic fabrics are overprinted by a pervasive greenschist-facies retrogression, high-strain subhorizontal mylonitic foliation, and a prominent WNW-ESE stretching lineation parallel to corrugations on the Boundary Canyon Detachment. Granitic pegmatite dikes are deformed, rotated into parallelism, and boudinaged within the mylonitic foliation. High-U zircons from one muscovite granite dike yield an 85.8 ?? 1.4 Ma age. Below the Monarch Spring fault, retrogression is minor, and amphibolite-facies mineral elongation lineations plunge gently north to northeast. Multiple generations of variably deformed dikes, sills, and leucosomal segregations indicate a more complex history of partial melting and intrusion compared to that above the Monarch Spring fault, but thermobarometry on garnet amphibolites above and below the Monarch Spring fault record similar peak conditions of 620-680 ??C and 7-9 kbar, indicating minor (sedimentary protoliths was a source for the structurally higher 86 Ma pegmatites. Two weakly deformed two-mica leucogranite dikes that cut the high-grademetamorphic fabrics below the Monarch Spring fault yield 62.3 ?? 2.6 and 61.7 ?? 4.7 Ma U-Pb zircon ages, and contain 1.5-1.7 Ga cores. The similarity of metamorphic, leuco-some, and pegmatite ages to the period of Sevier belt thrusting and the period of most voluminous Sierran arc magmatism suggests that both burial by thrusting and regional magmatic heating contributed to metamorphism and

  6. Structures, microfabrics and textures of the Cordilleran-type Rechnitz metamorphic core complex, Eastern Alps☆ (United States)

    Cao, Shuyun; Neubauer, Franz; Bernroider, Manfred; Liu, Junlai; Genser, Johann


    Rechnitz window group represents a Cordilleran-style metamorphic core complex, which is almost entirely located within nearly contemporaneous Neogene sediments at the transition zone between the Eastern Alps and the Neogene Pannonian basin. Two tectonic units are distinguished within the Rechnitz metamorphic core complex (RMCC): (1) a lower unit mainly composed of Mesozoic metasediments, and (2) an upper unit mainly composed of ophiolite remnants. Both units are metamorphosed within greenschist facies conditions during earliest Miocene followed by exhumation and cooling. The internal structure of the RMCC is characterized by the following succession of structure-forming events: (1) blueschist relics of Paleocene/Eocene age formed as a result of subduction (D1), (2) ductile nappe stacking (D2) of an ophiolite nappe over a distant passive margin succession (ca. E–W to WNW–ESE oriented stretching lineation), (3) greenschist facies-grade metamorphism annealing dominant in the lower unit, and (4) ductile low-angle normal faulting (D3) (with mainly NE–SW oriented stretching lineation), and (5) ca. E to NE-vergent folding (D4). The microfabrics are related to mostly ductile nappe stacking to ductile low-angle normal faulting. Paleopiezometry in conjunction with P–T estimates yield high strain rates of 10− 11 to 10− 13 s− 1, depending on the temperature (400–350 °C) and choice of piezometer and flow law calibration. Progressive microstructures and texture analysis indicate an overprint of the high-temperature fabrics (D2) by the low-temperature deformation (D3). Phengitic mica from the Paleocene/Eocene high-pressure metamorphism remained stable during D2 ductile deformation as well as preserved within late stages of final sub-greenschist facies shearing. Chlorite geothermometry yields two temperature groups, 376–328 °C, and 306–132 °C. Chlorite is seemingly accessible to late-stage resetting. The RMCC underwent an earlier large-scale coaxial

  7. Thermomechanics of an extensional shear zone, Raft River metamorphic core complex, NW Utah (United States)

    Gottardi, Raphaël; Teyssier, Christian


    A detailed structural and microstructural analysis of the Miocene Raft River detachment shear zone (NW Utah) provides insight into the thermomechanical evolution of the continental crust during extension associated with the exhumation of metamorphic core complexes. Combined microstructural, electron backscattered diffraction, strain, and vorticity analysis of the very well exposed quartzite mylonite show an increase in intensity of the rock fabrics from west to east, along the transport direction, compatible with observed finite strain markers and a model of ``necking'' of the shear zone. Microstructural evidence (quartz microstructures and deformation lamellae) suggests that the detachment shear zone evolved at its peak strength, close to the dislocation creep/exponential creep transition, where meteoric fluids played an important role on strain hardening, embrittlement, and eventually seismic failure. Empirically calibrated paleopiezometers based on quartz recrystallized grain size and deformation lamellae spacing show very similar results, indicate that the shear zone developed under stress ranging from 40 MPa to 60 MPa. Using a quartzite dislocation creep flow law we further estimate that the detachment shear zone quartzite mylonite developed at a strain rates between 10-12 and 10-14 s-1. We suggest that a compressed geothermal gradient across this detachment, which was produced by a combination of ductile shearing, heat advection, and cooling by meteoric fluids, may have triggered mechanical instabilities and strongly influenced the rheology of the detachment shear zone.

  8. Possible giant metamorphic core complex at the center of Artemis Corona, Venus (United States)

    Spencer, J.E.


    Hundreds of circular features on Venus known as coronae are characterized by annular fractures and commonly associated radial fractures and lava flows. Coronae are thought to have been produced by buoyant mantle diapirs that flatten and spread at the base of the lithosphere and cause fracturing, uplift, and magmatism. The interior of Artemis Corona, by far the largest corona at 2100 km diameter, is divided in half by a northeast-trending deformation belt that contains numerous rounded ridges resembling antiforms. The largest of these ridges, located at the center of Artemis Corona, is ???5 km high on its steep northwest flank where it is adjacent to a flat-bottomed, 10-km-wide trough interpreted as a rift valley. The 280-km-long antiformal ridge is marked by perpendicular grooves that cross the ???50-km-wide ridge and extend southeastward as far as 120 km across adjacent plains. The grooves abruptly terminate northwestward at the rift trough. The large antiformal ridge terminates southwestward at a transform shear zone that parallels the grooves. These features-rift valley, antiformal uplift, grooves, and transform shear zone-are morphologically and geometrically similar to grooved, elevated, submarine metamorphic core complexes on the inside corners of ridge-transform intersections of slow-spreading ridges on Earth. As with submarine core complexes, the grooved surface on Venus is interpreted as the footwall of a large-displacement normal fault, and the grooves are inferred to be the product of plastic molding of the footwall to irregularities on the underside of the hanging wall followed by tectonic exhumation of the molded grooves and conveyer-belt-like transport up and over the large antiform and across the southeastern plains. According to this interpretation, the trend of the grooves records the direction of extension, which is perpendicular to the thrusts at the leading edge of the annular thrust belt 1000 km to the southeast. Both may have formed at the

  9. A Geothermochronologic Investigation of the Coyote Mountains Metamorphic Core Complex (AZ) (United States)

    Borel, M.; Gottardi, R.; Casale, G.


    The Coyote Mountains metamorphic core complex (CM-MCC) makes up the northern end of the Baboquivari Mountain complex, which is composed of Mesozoic rocks, Tertiary granites, pegmatites, and metasediments. The CM-MCC expose the Pan Tak granite, a 58 Ma intrusive muscovite-biotite-garnet peraluminous granite. The Pan Tak and other intrusions within the Baboquivari Mountains have been interpreted as anatectic melts representing the culmination of a Laramide crustal shortening orogenic event started in the Late Cretaceous ( 70 Ma). Evidence of this magmatic episode includes polysynthetic twinning in plagioclase, myrmekitic texture in alkali feldspars, and garnet, mica and feldspar assemblages. The magmatic fabric is overprinted by a Tertiary tectonic fabric, associated with the exhumation of the CM-MCC along the Ajo road décollement and associated shear zone. In the shear zone, the Pan Tak mylonite display N-dipping foliation defined by gneissic layering and aligned muscovite, and N-trending mineral stretching lineation. Various shear sense indicators are all consistent with a top-to the-N shear sense. Preliminary argon geochronology results suggest that the shear zone was exhumed 29 Ma ago, an age similar to the onset of detachment faulting in other nearby MCCs (Catalina, Rincon, Pinaleño). In the Pan Tak mylonite, quartz grains display regime 2 to 3 microstructures and shows extensive recrystallization by subgrain rotation and grain boundary migration. The recrystallized grain size ranges between 20 and 50 µm in all samples. Quartz crystallographic preferred orientation measured using electron backscatter diffraction (EBSD) shows that recrystallization was accommodated by dominant prism and minor rhomb slip, suggesting deformation temperature ranging from 450°C to 550°C. These preliminary results constrain the timing of uplift and exhumation, and thermomechanical evolution of the CM-MCC, and improve our understanding of recycling of the continental crust in

  10. A conceptual model for the development of pristine drainage systems during exhumation of metamorphic core complexes (United States)

    Trost, Georg; Neubauer, Franz; Robl, Jörg


    Metamorphic core complexes (MCCs) are defined as large scale geological features of domal shape. The essential characteristic comprises metamorphic rocks, which have been exhumed from lower crustal levels and now are exposed to the surface. The updoming process occurs at different tectonic settings of high strain zones initially exposing pristine gently dipping fault planes to Earth's surface. Consequently, the dome shape highly influences the type of adaption of the drainage systems to the active landforms. However, drainage systems and their characteristic metrics in regions shaped by MCCs have only been sparsely investigated and were not examined regarding the distinction between different MCC-types (A-type, B-type, C-type). In this study we investigate the drainage patterns of MCCs formed by different tectonic settings and build up a conceptual model for the development of the drainage systems under these conditions. We apply the χ-method to detect variations in uplift, as well as spatial unconformities in the drainage patterns. The χ-method is a mathematical approach to transform stream longitudinal profiles to the χ space where the slope of steady state profiles is solely dependent on uplift rate and bedrock erodibility. From this transformation we calculate color-coded χ-maps and χ-profiles of the main streams draining the MCCs. The applied method allows the interpretation of channel metrics in terms of (a) spatial gradients in uplift rate and (b) the time dependent evolution of drainage divides including drainage divide migration. Our results show a high variation in the shape and greatest elevation of the χ-profiles. This indicates the migration of active uplift zones along the dome axes. Even though only MCCs younger than Miocene age are investigated, the shape of the χ-profiles clearly points to different development stages of these areas. K-profiles plotted over the detachment underlying an active updoming process show concave shaped

  11. Dating an actively exhuming metamorphic core complex, the Suckling Dayman Massif in SE Papua New Guinea (United States)

    Oesterle, J.; Seward, D.; Little, T.; Stockli, D. F.; Mizera, M.


    Low-temperature thermochronology is a powerful tool for revealing the thermal and kinematic evolution of metamorphic core complexes (MCCs). Most globally studied MCCs are ancient, partially eroded, and have been modified by deformation events that postdate their origin. The Mai'iu Fault is a rapidly slipping active low-angle normal fault (LANF) in the Woodlark Rift in Papua New Guinea that has exhumed a >25 km-wide (in the slip direction), and over 3 km-high domal fault surface in its footwall called the Suckling-Dayman massif. Some knowledge of the present-day thermal structure in the adjacent Woodlark Rift, and the pristine nature of this active MCC make it an ideal candidate for thermochronological study of a high finite-slip LANF. To constrain the thermal and kinematic evolution of this MCC we apply the U/Pb, fission-track (FT) and (U-Th)/He methods. Zircon U/Pb analyses from the syn-extensional Suckling Granite that intrudes the footwall of the MCC yield an intrusion age of 3.3 Ma. Preliminary zircon FT ages from the same body indicate cooling below 300 °C at 2.7 Ma. Ages decrease to 2.0 Ma with increasing proximity to the Mai'iu Fault and imply cooling controlled by tectonic exhumation. Almost coincident zircon U/Pb and FT ages from the nearby syn-extensional Mai'iu Monzonite, on the other hand, record extremely rapid cooling from magmatic temperatures to 300 °C at 2 Ma. As apparent from the preliminary He extraction stage, these syn-extensional plutons have young zircon and apatite (U-Th)/He ages. These initial results suggest that the Mai'iu Fault was initiated as an extensional structure by 3.3 Ma. We infer that it reactivated an older ophiolitic suture that had emplaced the Papuan Ultramafic body in the Paleogene. Rapid cooling of the Mai'iu Monzonite indicates that it was intruded into a part of the MCC's footwall that was already shallow in the crust by 2 Ma. This inference is further supported by the mineral andalusite occurring in the contact

  12. Metamorphic brines and no surficial fluids trapped in the detachment footwall of a Metamorphic Core Complex (Nevado-Filábride units, Betics, Spain) (United States)

    Dyja-Person, Vanessa; Tarantola, Alexandre; Richard, Antonin; Hibsch, Christian; Siebenaller, Luc; Boiron, Marie-Christine; Cathelineau, Michel; Boulvais, Philippe


    The ductile-brittle transition zone in extensional regimes can play the role of a hydrogeological barrier. Quartz veins developed within an orthogneiss body located in the detachment footwall of a Metamorphic Core Complex (MCC) in the Nevado-Filábride units (Betics, Spain). The detachment footwall is composed mainly of gneisses, schists and metacarbonates from the Bédar-Macael sub-unit. Schist and metacarbonate bodies show evidence of ductile deformation at the time the gneiss was already undergoing brittle deformation and vein opening during exhumation. The vein system provides the opportunity to investigate the origin, composition and PVTX conditions of the fluids that circulated in the detachment footwall while the footwall units were crossing the ductile-brittle transition. The analysis of fluid inclusions reveals the presence of a single type of fluid: 30-40 mass% NaCl > KCl > CaCl2 > MgCl2 brines, with trace amounts of CO2 and N2 and tens to thousands of ppm of metals such as Fe, Sr, Li, Zn, Ba, Pb and Cu. δDfluid values between -39.8 and -16.7‰ and δ18Ofluid values between 4.4 and 11.7 ± 0.5‰ show that the brines have undergone protracted interaction with the host orthogneissic body. Coupled salinity and Cl/Br ratios (200 to 4400) indicate that the brines originate from dissolution of Triassic metaevaporites by metamorphic fluids variably enriched in Br by interaction with graphitic schists. This study highlights the absence of any record of surficial fluids within the veins, despite the brittle deformation conditions prevailing in this orthogneiss body. The fact that fluids from the detachment footwall were isolated from surficial fluid reservoirs may result from the presence of overlying schists and metacarbonates that continued to be affected by ductile deformation during vein formation in the gneiss, preventing downward circulation of surface-derived fluids.

  13. Exhumation And Evolution Of Al-Taif Metamorphic Core Complex (Western Arabian Shield) During Dextral Transpressional Regime (United States)

    El-Fakharani, Abdelhamid; El-Shafei, Mohamed; Hamimi, Zakaria


    Al-Taif metamorphic belt is a NE-trending belt decorating steeply dipping major transpressional shear zone in western central Arabian Shield. It comprises gneisses and migmatites that were syn-kinematically invaded under relatively high-grade metamorphic conditions by voluminous granitic bodies and a confluence of pegmatitic veins. Field mapping and outcrop investigation reveal that the belt was evolved during at least three Neoproterozoic deformations (D1-D3). D1 and D2 were progressive deformations, took place during a contractional regime, and resulted in SW-mildly plunging isoclinal folds, superimposed by NE- gently to moderately plunging folds. The prevailed tectonic regime during D3was primordially plastic, accompanied with a NE-oriented oblique shearing that was subsequently evolved as semi ductile-semi brittle shearing during an episode of exhumation. Mesoscopic kinematic indicators, as well as microstructural analysis of the collected rock samples, reflect dextral sense of shearing. Such style of shearing is most probably the conjugate trend of the NNW- to NW- oriented sinistral Najd Fault System. Various cross cutting structures and overprinting relations were detected at both the outcrop- and microscopic scales, including; ductile S2folia with ESE-plunging amphibole mineral lineations; narrow, steeply dipping ductile D2 shear zones; and semi brittle to brittle fault zones. S-C' fabrics, asymmetric strain shadows around porphyroclasts and drag fault indicate a top-to-the-NE sense of shear for most structures. The geometry and style of deformation, together with map pattern highlighted in this study attest a simple shear rotational strain origin for the domed mylonitic foliation (S1) and mineral elongation lineation (L1). This result is in congruent with the landform pattern recorded in the inner parts of the metamorphic core complexes.

  14. Multiple tectonic mode switches indicate short-duration heat pulses in a Mio-Pliocene metamorphic core complex, West Papua, Indonesia (United States)

    White, L. T.; Hall, R.; Gunawan, I.


    The Wandaman Peninsula is a narrow (2 km) promontory in remote western New Guinea. The peninsula is almost entirely composed of medium- to high-grade metamorphic rocks considered to be associated with a Mio-Pliocene metamorphic core complex. Previous work has shown that the uplift and exhumation of the core complex has potentially brought some extremely young eclogite to the surface. These might be comparable to the world's youngest (4.3 Ma) eclogites found in the D'Entrecasteaux Islands at the opposite end of New Guinea. We show that tectonic history of this region is complex. This is because the metamorphic sequences in the Wandaman Peninsula record multiple phases of deformation, all within the last few million years. This is demonstrated through methodical collation of cross-cutting relations from field and microstructural studies across the peninsula. The first phase of deformation and metamorphism is associated with crustal extension and partial melting that took place at 5-7 Ma according to new U-Pb data from metamorphic zircons. This extensional phase ceased after a tectonic mode switch and the region was shortened. This is demonstrated by two phases of folding (1. recumbent and 2. open) that overprint the earlier extensional fabrics. All previous structures were later overprinted by brittle extensional faults and uplift. This extensional phase is still taking place today, as is indicated by submerged forests exposed along the coastline associated with recent earthquakes and hot springs. The sequence of metamorphic rocks that are exposed in the Wandaman Peninsula show that stress and thermal conditions can change rapidly. If we consider that the present is a key to the past, then such results can identify the duration of deformation and metamorphic events more accurately than in much older orogenic systems.

  15. The lateral boundary of a metamorphic core complex: The Moutsounas shear zone on Naxos, Cyclades, Greece☆ (United States)

    Cao, Shuyun; Neubauer, Franz; Bernroider, Manfred; Liu, Junlai


    We describe the structure, microstructures, texture and paleopiezometry of quartz-rich phyllites and marbles along N-trending Moutsounas shear zone at the eastern margin of the Naxos metamorphic core complex (MCC). Fabrics consistently indicate a top-to-the-NNE non-coaxial shear and formed during the main stage of updoming and exhumation between ca. 14 and 11 Ma of the Naxos MCC. The main stage of exhumation postdates the deposition of overlying Miocene sedimentary successions and predates the overlying Upper Miocene/Pliocene conglomerates. Detailed microstructural and textural analysis reveals that the movement along the Moutsounas shear zone is associated with a retrograde greenschist to subgreenschist facies overprint of the early higher-temperature rocks. Paleopiezometry on recrystallized quartz and calcite yields differential stresses of 20–77 MPa and a strain rate of 10−15–10−13 s−1 at 350 °C for quartz and ca. 300 °C for calcite. Chlorite geothermometry of the shear zone yields two temperature regimes, 300–360 °C, and 200–250 °C. The lower temperature group is interpreted to result from late-stage hydrothermal overprint. PMID:26523079

  16. Analysis of magnetotelluric profile data from the Ruby Mountains metamorphic core complex and southern Carlin Trend region, Nevada (United States)

    Wannamaker, Philip E.; Doerner, William M.; Stodt, John A.; Sodergen, Timothy L.; Rodriguez, Brian D.


    We have collected about 150 magnetotelluric (MT) soundings in northeastern Nevada in the region of the Ruby Mountains metamorphic core complex uplift and southern Carlin mineral trend, in an effort to illuminate controls on core complex evolution and deposition of world-class gold deposits. The region has experienced a broad range of tectonic events including several periods of compressional and extensional deformation, which have contributed to the total expression of electrical resistivity. Most of the soundings are in three east-west profiles across increasing degrees of core uplift to the north (Bald Mountain, Harrison Pass and Secret Pass latitudes). Two shorter lines cross a prominent east-west structure to the north of the northern profile. MT impedance tensor and vertical magnetic field rotations imply a N-NNE average regional geoelectric strike, similar to surface geologic trends. Model resistivity cross sections were derived using a 2-D inversion algorithm, which damps departures of model parameters from an a priori structure, emphasizing the transverse magnetic (TM) mode and vertical magnetic field data. Geological interpretation of the resistivity combines previous seismic, potential field and isotope models, structural and petrological models for regional compression and extension, and detailed structural/stratigraphic interpretations incorporating drilling for petroleum and mineral exploration. To first order, the resistivity structure is one of a moderately conductive, Phanerozoic sedimentary section fundamentally disrupted by intrusion and uplift of resistive crystalline rocks. Late Devonian and early Mississippian shales of the Pilot and Chainman Formations together form an important conductive marker sequence in the stratigraphy and show pronounced increases in conductance (conductivity-thickness product) from east to west. These increases in conductance are attributed to graphitization caused by Elko-Sevier era compressional shear deformation and

  17. Timing of exhumation of the Ereendavaa metamorphic core complex (north-eastern Mongolia) - U-Pb and 40Ar/39Ar constraints (United States)

    Daoudene, Yannick; Ruffet, Gilles; Cocherie, Alain; Ledru, Patrick; Gapais, Denis


    The occurrence of numerous NE-SW trending rift basins that locally bound metamorphic core complexes in Transbaikalia, northern Mongolia and north-eastern China indicates that the eastern domain of the Central Asian Orogenic Belt was affected by a large-scale NW-SE extensional tectonic event during late Jurassic to early Cretaceous times. Available geochronological information about the formation of metamorphic core complexes in the region define partly synchronous periods in Transbaikalia (134-121 Ma) and North China (136-110 Ma) suggesting dome exhumation during the early Cretaceous. In north-eastern Mongolia, the Ereendavaa Range, lined by the Onon Shear Zone, was recently interpreted as one of these metamorphic core complexes, of late Jurassic to early Cretaceous age, on the basis of U-Pb zircons data from two synkinematic pegmatite dykes. However, this wide time range remains to be discussed. The present work constrains the tectono-thermal evolution of the range by providing new MC-ICP-MS U-Pb zircons ages from pegmatite dykes and metamorphic igneous rocks, and mica and amphibole 40Ar/39Ar laser step-heating ages from metamorphic and magmatic rocks that crop out within the range. The results show that (1) the Ereendavaa range was the locus of a widespread magmatic activity prior to its exhumation from late Jurassic times, (2) cooling of the range began at least at 137.9 ± 0.3 Ma as revealed by a 40Ar/39Ar plateau ages obtained from an hornblende sampled within the range core, and (3) exhumation along the Onon Shear Zone occurred from 130.3 ± 1.9 Ma down to 124.8 ± 0.3 Ma, as shown by ages of most of micas and amphiboles from the Shear zone. These more accurate ages are consistent with metamorphic core complex ages from adjacent areas. Furthermore, they argue for an extensional dynamic paroxysm at the scale of eastern Asia during a narrow time range in the early Cretaceous between ca. 130 Ma and ca. 120 Ma.

  18. Late Cretaceous Localized Crustal Thickening as a Primary Control on the 3-D Architecture and Exhumation Histories of Cordilleran Metamorphic Core Complexes (United States)

    Gans, P. B.; Wong, M.


    The juxtaposition of mylonitic mid-crustal rocks and faulted supracrustal rocks in metamorphic core complexes (MMCs) is usually portrayed in 2 dimensions and attributed to a single event of large-scale slip ± isostatic doming along a low-angle "detachment fault"/ shear zone. This paradigm does not explain dramatic along strike (3-D) variations in slip magnitude, footwall architecture, and burial / exhumation histories of most MMCs. A fundamental question posed by MMCs is how did their earlier thickening and exhumation histories influence the geometric evolution and 3-D slip distribution on the subsequent detachment faults? New geologic mapping and 40Ar/39Ar thermochronology from the Snake Range-Kern Mts-Deep Creek Mts (SKDC) complex in eastern Nevada offer important insights into this question. Crustal shortening and thickening by large-scale non-cylindrical recumbent folds and associated thrust faults during the late Cretaceous (90-80 Ma) resulted in deep burial (650°C, 20-25 km) of the central part of the footwall, but metamorphic grade decreases dramatically to the N and S in concert with decreasing amplitude on the shortening structures. Subsequent Paleogene extensional exhumation by normal faulting and ESE-directed mylonitic shearing is greatest in areas of maximum earlier thickening and brought highest grade rocks back to depths of~10-12 km. After ≥15 Ma of quiescence, rapid E-directed slip initiated along the brittle Miocene Snake Range detachment at 20 Ma and reactivated the Eocene shear zone. The ≥200°C gradient across the footwall at this time implies that the Miocene slip surface originated as a moderately E-dipping normal fault. This Miocene slip surface can be tracked for more than 100 km along strike, but the greatest amount of Miocene slip also coincides with parts of the footwall that were most deeply buried in the Cretaceous. These relations indicate that not only is the SKDC MMC a composite feature, but that the crustal welt created by

  19. Integration of offshore seismic data, exploration wells, and onland outcrops as constraints on the tectonics and uplift age of metamorphic core complexes, eastern Papua New Guinea (United States)

    Fitz, G. G.; Mann, P.; Campos Aguiniga, H.


    of the core complexes occurred during the latest Miocene-earliest Pliocene period.

  20. Evidence of Failure on Low-Angle Normal Faults from Thermochronology and Paleomagnetism: A Case Study from South Mountains Metamorphic Core Complex, Arizona (United States)

    Hoehn, J. R.; Smith, D. M.; Goodwin, L. B.; Feinberg, J. M.; Heizler, M. T.; Singer, B. S.; Jicha, B. R.


    The South Mountains metamorphic core complex records progressive extension and exhumation of Miocene granodiorite. Early mylonites are cut by younger brittle faults, including locally abundant, shallowly dipping, pseudotachylyte-lined slip surfaces. These frictional melt generation veins can be grouped based on mesoscopic character of both pseudotachylyte and host granodiorite mylonite. All vein types are subparallel to biotite-lined, host rock C-surfaces. Thin (clasts. Though largely parallel C-surfaces, these veins possess S-surface-parallel segments up to several cms long, and cut host rock with a strong S-C fabric. Type 3 veins lack mesoscopic foliation and cut host rock ranging from protomylonite to ultramylonite. They are similar in thickness to type 2 veins, but include fewer survivor clasts. Previous 40Ar/39Ar dates on pseudotachylyte veins (16.24 ± 0.23 Ma and 17.44 ± 0.20 Ma) show pseudotachylyte-producing seismicity occurred over at least 1 million years. Multi- diffusion-domain analysis of host rock K-feldspar demonstrates cooling below 150°C by 21.8 Ma. Assuming a geothermal gradient between 25°C and 50°C/km, pseudotachylyte veins were generated at a maximum depth of 2.5-5 km. Fabric intensity of anisotropy of magnetic susceptibility (AMS) corresponds to vein types. Paleomagnetic analyses yield 3 clusters of characteristic remanent magnetizations (ChRMs) that correlate to AMS/vein types. ChRMs of nonfoliated type 3 veins are close to the Miocene pole. By contrast, ChRMs for type 1 and 2 veins are deflected close to the foliation due to strong anisotropy of their magnetic mineral assemblages. Normal faults dipping oriented for slip according to Andersonian fault mechanics. Previous workers therefore have suggested they failed at steeper dips, then rotated to current orientations. The uniformity of South Mountains generation vein orientations records no rotation between formation of the oldest and youngest veins. The proximity of the ChRMs of type 3

  1. Early Cretaceous overprinting of the Mesozoic Daqing Shan fold-and-thrust belt by the Hohhot metamorphic core complex, Inner Mongolia, China

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    Gregory A. Davis


    Full Text Available The Early Cretaceous Hohhot metamorphic core complex (mcc of the Daqing Shan (Mtns. of central Inner Mongolia is among the best exposed and most spectacular of the spatially isolated mcc’s that developed within the northern edge of the North China “craton”. All of these mcc’s were formed within the basement of a Late Paleozoic Andean-style arc and across older Mesozoic fold-and-thrust belts of variable age and tectonic vergence. The master Hohhot detachment fault roots southwards within the southern margin of the Daqing Shan for an along-strike distance of at least 120 km. Its geometry in the range to the north is complicated by interference patterns between (1 primary, large-scale NW-SE-trending convex and concave fault corrugations and (2 secondary ENE-WSW-trending antiforms and synforms that folded the detachment in its late kinematic history. As in the Whipple Mtns. of California, the Hohhot master detachment is not of the Wernicke (1981 simple rooted type; instead, it was spawned from a mid-crustal shear zone, the top of which is preserved as a mylonitic front within Carboniferous metasedimentary rocks in its exhumed lower plate. 40Ar–39Ar dating of siliceous volcanic rocks in basal sections of now isolated supradetachment basins suggest that crustal extension began at ca. 127 Ma, although lower-plate mylonitic rocks were not exposed to erosion until after ca. 119 Ma. Essentially synchronous cooling of hornblende, biotite, and muscovite in footwall mylonitic gneisses indicates very rapid exhumation and at ca. 122–120 Ma. Contrary to several recent reports, the master detachment clearly cuts across and dismembers older, north-directed thrust sheets of the Daqing Shan foreland fold-and-thrust belt. Folded and thrust-faulted basalts within its foredeep strata are as young as 132.6 ± 2.4 Ma, thus defining within 5–6 Ma the regional tectonic transition between crustal contraction and profound crustal extension.

  2. Metamorphers

    KAUST Repository

    Sorger, Johannes


    In molecular biology, illustrative animations are used to convey complex biological phenomena to broad audiences. However, such animations have to be manually authored in 3D modeling software, a time consuming task that has to be repeated from scratch for every new data set, and requires a high level of expertise in illustration, animation, and biology. We therefore propose metamorphers: a set of operations for defining animation states as well as the transitions to them in the form of re-usable storytelling templates. The re-usability is two-fold. Firstly, due to their modular nature, metamorphers can be re-used in different combinations to create a wide range of animations. Secondly, due to their abstract nature, metamorphers can be re-used to re-create an intended animation for a wide range of compatible data sets. Metamorphers thereby mask the low-level complexity of explicit animation specifications by exploiting the inherent properties of the molecular data, such as the position, size, and hierarchy level of a semantic data subset. We demonstrate the re-usability of our technique based on the authoring and application of two animation use-cases to three molecular data sets.

  3. Kinematics of the southern Rhodope Core Complex (North Greece).

    NARCIS (Netherlands)

    Brun, J.P.; Sokoutis, D.


    The Southern Rhodope Core Complex is a wide metamorphic dome exhumed in the northern Aegean as a result of large-scale extension from mid-Eocene to mid-Miocene times. Its roughly triangular shape is bordered on the SW by the Jurassic and Cretaceous metamorphic units of the Serbo-Macedonian in the

  4. Metamorphic complexes in accretionary orogens: Insights from the Beishan collage, southern Central Asian Orogenic Belt (United States)

    Song, Dongfang; Xiao, Wenjiao; Windley, Brian F.; Han, Chunming; Yang, Lei


    The sources of ancient zircons and the tectonic attributions and origins of metamorphic complexes in Phanerozoic accretionary orogens have long been difficult issues. Situated between the Tianshan and Inner Mongolia orogens, the Beishan orogenic collage (BOC) plays a pivotal role in understanding the accretionary processes of the southern Central Asian Orogenic Belt (CAOB), particularly the extensive metamorphic and high-strained complexes on the southern margin. Despite their importance in understanding the basic architecture of the southern CAOB, little consensus has been reached on their ages and origins. Our new structural, LA-ICP-MS zircon U-Pb and Hf isotopic data from the Baidunzi, Shibandun, Qiaowan and Wutongjing metamorphic complexes resolve current controversial relations. The metamorphic complexes have varied lithologies and structures. Detrital zircons from five para-metamorphic rocks yield predominantly Phanerozoic ages with single major peaks at ca. 276 Ma, 286 Ma, 427 Ma, 428 Ma and 461 Ma. Two orthogneisses have weighted mean ages of 294 ± 2 Ma and 304 ± 2 Ma with no Precambrian inherited zircons. Most Phanerozoic zircons show positive εHf(t) values indicating significant crustal growth in the Ordovician, Silurian and Permian. The imbricated fold-thrust deformation style combined with diagnostic zircon U-Pb-Hf isotopic data demonstrate that the metamorphic rocks developed in a subduction-accretion setting on an arc or active continental margin. This setting and conclusion are supported by the nearby occurrence of Ordovician-Silurian adakites, Nb-rich basalts, Carboniferous-Permian ophiolitic mélanges, and trench-type turbidites. Current data do not support the presence of a widespread Precambrian basement in the evolution of the BOC; the accretionary processes may have continued to the early Permian in this part of the CAOB. These relationships have meaningful implications for the interpretation of the tectonic attributions and origins of other

  5. Geochemistry and paleotectonomagmatic setting of metabasites protolith from Asalem metamorphic complex (northwest Rasht

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    Mohsen Nasrabady


    Full Text Available Asalem metamorphic complex consists mostly of metabasite, metapelite and serpentinite. Metabasites display metamorphic features of greenschist and blueschist facies. Greenschist facies rocks that found as both foliated and massive types contain mineralogical assemblage of actinolite, chlorite, albite and epidote. Blueschists contain mineralogical assemblage of sodic amphibole, epidote and phengite. Whole rock analyses of the metabasites indicate basaltic to andesitic composition with mainly calcalkaline nature of their protolith. According to the discrimination diagrams of tectonomagmatic setting, the protolith of investigated metabasites has been islands arc and somewhat mid ocean ridge. The patterns of rare earth elements and spider diagrams of the Asalem metabasites resemble to the basic and intermediate magmatism of islands arc or suprasubduction setting as well. Greenschists and blueschists facies rocks of the Asalem metamorphic complex have been probably equivalent to islands arc or young and hot oceanic crust of suprasubduction zone setting. This portion of oceanic basin unlike the subducted even and thick oceanic lithosphere of Paleotethys during accretion in the shallower levels of accretionary prisms, have underwent metamorphic conditions of blueschist and greenschist facies and finally gave rise to the formation of the metabasites of the Asalem metamorphic complex.

  6. High-pressure granulites in the Fuping Complex of the central North China Craton: Metamorphic P-T-t evolution and tectonic implications (United States)

    Qian, Jiahui; Yin, Changqing; Zhang, Jian; Ma, Li; Wang, Luojuan


    Mafic granulites in the Fuping Complex occur as lenses or boudins within high-grade TTG (Trondhjemite-Tonalite-Granodiorite) gneisses. Petrographic observations reveal four generations of mineral assemblage in the granulites: an inclusion assemblage of hornblende + plagioclase + ilmenite + quartz within garnet core; an inferred peak assemblage composed of garnet ± hornblende + plagioclase + clinopyroxene + rutile/ilmenite + quartz; a decompression assemblage characterized by symplectites of clinopyroxene ± orthopyroxene + plagioclase, coronae of plagioclase ± clinopyroxene ± hornblende around embayed garnet porphyroblasts or a two-pyroxene association; and a late amphibolite-facies retrogressive assemblage. Two representative samples were used for pseudosection modeling in NCFMASHTO model system to determine their metamorphic evolution. The results show that these granulites experienced a high-pressure stage of metamorphism with peak P-T conditions of 12-13 kbar and 760-800 °C (Pmax) and a post-peak history under P-T conditions of ∼9.0 kbar and 805-835 °C (Tmax), indicating a nearly isothermal decompression process (ITD) with a slight heating. Metamorphic evolution from the Pmax to the Tmax is predicted to be dominated by garnet breakdown through continuous metamorphic reactions of garnet + quartz ± diopside = hornblende + plagioclase + liquid and garnet + quartz + hornblende = plagioclase + diopside + liquid + orthopyroxene. Further metamorphic evolution after the Tmax is dominated by cooling, suggesting that high-pressure (HP) granulites may also exist in the Fuping Complex. Metamorphic zircons in the Fuping HP mafic granulites have left inclined REE patterns, Ti contents of 1.68-6.88 ppm and crystallization temperatures of 602-712 °C. SIMS zircon U-Pb dating on these zircons yields 207Pb/206Pb ages of 1891 ± 14 Ma and 1849 ± 6 Ma, interpreted to represent the cooling stage of metamorphism. The P-T-t evolution of the Fuping HP mafic granulites records

  7. Preliminary radiometric analyses of zircons from the Mount Copeland syenite gneiss, Shuswap metamorphic complex, British Columbia

    International Nuclear Information System (INIS)

    Okulitch, A.V.; Laveridge, W.D.; Sullivan, R.W.


    The isotopic ratios resulting from Pb and U analyses on three zircon fractions from syenite gneiss intrusive into metasediments of the Shuswap Metamorphic Complex are collinear on a concordia plot and yield upper and lower intercepts of about 773 Ma and 70 Ma. The upper intercept is tentatively interpreted as the minimum age of emplacement. The lower intercept is suggested to be the time of uplift and cooling associated with tectonic denudation of the Shuswap Complex. The implied age of the country rocks is pre-late Proterozoic and they may be correlatives of the Purcell Supergroup. (auth)

  8. P-T evolution of metasedimentary rocks of the Santa Filomena Complex, Riacho do Pontal Orogen, Borborema Province (NE Brazil): Geothermobarometry and metamorphic modelling (United States)

    Santos, Felipe H.; Amaral, Wagner S.; Luvizotto, George L.; Martins de Sousa, Daniel F.


    We present in this paper petrologic data and discuss the pressure-temperature (P-T) metamorphic history of the neoproterozoic metasedimentary rocks of the Santa Filomena Complex, Riacho do Pontal Orogen, which is inserted in the southern portion of the Borborema Province (Northeast Brazil). Therefore, the data provide constraints on metamorphic evolution during Neoproterozoic Brasiliano Orogeny in Northeast Brazil. The rocks studied are aluminous schists and paragneisses. Silver-gray and red pelitic schists are intensely deformed, biotite-muscovite rich, contain centimeter-sized garnet, staurolite and kyanite porphyroblasts, and subordinately plagioclase and quartz. Paragneisses are from light gray to dark gray colored, medium to coarse-grained and display a well-spaced foliated matrix of biotite, and kyanite and garnet porphyroblasts. Locally, the schists and paragneisses are migmatized. Pressure-temperature modelling based on thermobarometric calculations indicate that metamorphism reached 643 °C with pressures estimated in 12 kbar. Pre-peak and post-peak metamorphic conditions are constrained by mineralogical and textural relationships: garnet inclusion-rich and inclusion-free (possible of higher T) are documented and the inclusion-rich core probably indicates a Sn-1 foliation that was transposed by Sn. The pre-peak stage most probably occurred close to 500 °C and 8 kbar, in upper greenschist to lower amphibolite facies metamorphism along kyanite stability field. We also propose that post-peak stage was associated with isothermal decompression along a possible path of tectonic exhumation in conditions of 600 °C and 7 kbar. To further evaluate the equilibrium condition, pressure-temperature pseudosections were calculated for the metasedimentary rocks. Thus, the estimated metamorphic peak took place in the upper amphibolite facies. A suggested clockwise pressure-temperature path is compatible with the regional tectonic setting of continent-continent collision

  9. Evolution of Migmatitic Granulite Complexes: implications from Lapland Granulite Belt, Part I: metamorphic geology

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    Pekka Tuisku


    Full Text Available The Palaeoproterozoic Lapland granulite belt was juxtaposed between Archaean and Proterozoic terrains in the NE part of the Fennoscandian Shield concurrently with the accretion of Svecofennian arc complexes at ~1.9 Ga. The belt consists mainly of aluminous migmatiticmetagreywackes. Abundant noritic to enderbitic magmas were intruded concordantly into the metasediments and were probably an important heat source for metamorphism, which took place during the crystallization of the magmas. This is supported by structural and contact relations of metasediments and igneous rocks, and by the lack progressive metamorphic reaction textures in the igneous rock series. The peak of metamorphism took place above the dehydration melting temperature of the biotite-sillimanite-plagioclase-quartz assemblageat 750−850°C and 5−8.5 kbar which lead to formation of a restitic palaeosome and peraluminous granitic melt in metapelites. Subsequently, the rocks were decompressed and cooled below the wet melting temperature of pelitic rocks (650°C under the stability field of andalusite coexisting with potassium feldspar (2−3 kbar. Cooling was accompanied by the crystallization of the neosomes, often carrying aluminium-rich phases. Postmetamorphic duplexing of the LGB is clearly seen in the distribution of calculated PT conditions.

  10. Metamorphic reactions and preliminary P-T estimates of ultrahigh-temperature mafic granulite from Tonagh Island in the Napier Complex, East Antarctica


    Tunogae,Toshiaki; Osanai,Yasuhito; Toyoshima,Tsuyoshi; Owada,Masaaki; Hokada,Tomokazu; Crowe,Warwick A.


    Metamorphic reactions and P-T conditions of mafic granulites from Tonagh Island in the Archean Napier Complex were examined to evaluate the nature of mafic granulite which has suffered ultrahigh-temperature (UHT) metamorphism. Although a peak mineral assemblage is preserved in plagioclase-orthopyroxene-clinopyroxene mafic granulites, initial mineral chemistry was completely reset by retrograde metamorphism. Evidence of UHT metamorphism was therefore inferred using lamella-bearing pyroxenes as...

  11. Electron microprobe Th-U-Pb monazite dating and metamorphic evolution of the Acaiaca Granulite Complex, Minas Gerais, Brazil

    Energy Technology Data Exchange (ETDEWEB)

    Medeiros Junior, Edgar Batista; Marques, Rodson Abreu, E-mail:, E-mail: [Universidade Federal do Espirito Santo (UFES), Alegre, ES (Brazil). Departamento de Geologia; Jordt-Evangelista, Hanna; Queiroga, Glaucia Nascimento, E-mail:, E-mail: [Universidade Federal de Ouro Preto (UFOP), Ouro Preto, MG (Brazil). Escola de Minas. Departamento de Geologia; Schulz, Bernhard, E-mail: [TU Bergakademie - Institute of Mineralogy, Freiberg - Saxony (Germany)


    The Acaiaca Complex (AC) is located in southeastern Minas Gerais state, and comprises felsic, mafic, ultramafic, and aluminous granulite as well as lower grade gneisses and mylonite. The complex is distributed over an area of ca. 36 km by 6 km, surrounded by amphibolite facies gneisses of the Mantiqueira Complex (MC). The discrepancy in the metamorphic grade between both complexes led to the present study aiming to understand the metamorphic history of the AC by means of geothermobarometry calculations and electron microprobe Th-U-Pb monazite dating. Estimates of the metamorphic conditions of the granulite based on conventional geothermobarometry and THERMOCALC resulted in temperatures around 800 deg C and pressures between of 5.0 and 9.9 kbar and a retro metamorphic path characterized by near-isobaric cooling. Part of the granulite was affected by anatexis. The melting of felsic granulite resulted in the generation of pegmatites and two aluminous lithotypes. These are: 1) garnet-sillimanite granulite with euhedral plagioclase and cordierite that show straight faces against quartz, and is the crystallization product of an anatectic melt, and 2) garnet-kyanite-cordierite granulite, which is probably the restite of anatexis, as indicated by textures and high magnesium contents. Th-U-Pb monazite geochronology of two granulite samples resulted in a metamorphic age around 2060 Ma, which is similar to the age of the MC registered in the literature. The similar Paleoproterozoic metamorphic ages of both complexes lead to the conclusion that the Acaiaca Complex may be the high grade metamorphic unit geochronological related to the lower grade Mantiqueira Complex. (author)

  12. Extreme metamorphism in a firn core from the Allan Hills, Antarctica, as an analogue for glacial conditions (United States)

    Dadic, Ruzica; Schneebeli, Martin; Bertler, Nancy; Schwikowski, Margit; Matzl, Margret


    Understanding processes in near-zero accumulation areas can help to better understand the ranges of isotopic composition in ice cores, particularly during ice ages, when accumulation rates were lower than today. Snow metamorphism is a primary driver of the transition from snow to ice and can be accompanied by altered isotopic compositions and chemical species concentration. High degree snow metamorphism, which results in major structural changes, is little-studied but has been identified in certain places in Antarctica. Here we report on a 5-m firn core collected adjacent to a blue-ice field in the Allan Hills, Antarctica. We determined the physical properties of the snow using computer tomography (microCT) and measured the isotopic composition of δD and δ18O, as well as 210Pb activity. The core shows a high degree of snow metamorphism and an exponential decrease in specific surface area (SSA), but no clear densification, with depth. The micro-CT measurements show a homogenous and stable structure throughout the entire core, with obvious erosion features in the near-surface, where high-resolution data is available. The observed firn structure is likely caused by a combination of unique depositional and post-depositional processes. The defining depositional process is the impact deposition under high winds and with a high initial density. The defining post-depositional processes are a) increased moisture transport due to forced ventilation and high winds and b) decades of temperature-gradient driven metamorphic growth in the near surface due to prolonged exposure to seasonal temperature cycling. Both post-processes are enhanced in low accumulation regions where snow stays close to surface for a long time. We observe an irregular signal in δD and δ18O that does not follow the stratigraphic sequence. The isotopic signal is likely caused by the same post-depositional processes that are responsible for the firn structure, and that are driven by local climate

  13. Structural and metamorphic evolution of the Turku migmatite complex, southwestern Finland

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    Väisänen, M.


    Full Text Available The Turku migmatite complex in southwestern Finland is a representative area for the type of tectonic and metamorphic evolution seen within the Palaeoproterozoic Svecofennian Orogen in southern Finland. The orogeny can be divided into early, late and postorogenic stages. The early orogenic structural evolution of the crust is expressed by a D1/D2 deformation recorded as bedding-parallel S1 mica foliation deformed by tight to isoclinal D2 folds with subhorizontal axial planes and a penetrative S2 axial plane foliation. Syntectonic ca. 1890-1870 Ma tonalites were emplaced during D2 as sheet intrusions. This deformation is attributed to thrust tectonics and thickening of the crust. The late orogenic structural evolution produced the main D3 folding, which transposed previous structures into a NE-SW trend. The doubly plunging fold axis produced dome-and-basin structures. The attitude of the F3 folds varies from upright or slightly overturned to locally recumbent towards the NW. Granite dikes were intruded along S3 axial planes. Large D3 fold limbs are often strongly deformed, intensively migmatized and intruded by garnet- and cordierite-bearing granites. These observations suggest that these potassium-rich granites, dated at 1840-1830 Ma, were emplaced during D3. This late orogenic NW-SE crustal shortening further contributed to crustal thickening. Subvertical D4 shear zones that cut all previous rock types possibly controlled the emplacement of postorogenic granitoids. Steeply plunging lineations on D4 shear planes suggest vertical displacements during a regional uplift stage. Metamorphic grade increases from cordierite-sillimanite-K-feldspar gneisses in the northwest and from muscovite-quartz±andalusite rocks in the southeast to high-temperature granulite facies migmatites in the middle of the study area. Block movements during D4 caused the observed differences in metamorphic grade. Garnet and cordierite are mostly breakdown products of biotite

  14. Genesis and petrology of Late Neoproterozoic pegmatites and aplites associated with the Taba metamorphic complex in southern Sinai, Egypt

    Energy Technology Data Exchange (ETDEWEB)

    Abdelfadil, K.M.; Asimow, P.D.; Azer, M.K.; Gahlan, H.A.


    We present new field, petrographical, mineralogical and geochemical data from late Neoproterozoic pegmatites and aplites in southern Sinai, Egypt, at the northernmost limit of the Arabian-Nubian Shield. The pegmatites cross-cut host rocks in the Taba Metamorphic Complex (TMC) with sharp contacts and are divided into massive and zoned pegmatites. Massive pegmatites are the most common and form veins, dykes and masses of variable dimensions; strikes range mainly from E-W through NW-SE to N-S. Mineralogically, the massive pegmatites are divided into K-feldspar-rich and albite-rich groups. Zoned pegmatites occur as lenses of variable dimensions, featuring a quartz core, an intermediate zone rich in K-feldspars and an outer finer-grained zone rich in albite. All compositions are highly evolved and display geochemical characteristics of post-collisional A-type granites: high SiO2, Na2O+K2O, FeO*/MgO, Ga/Al, Zr, Nb, Ga and Y alongside low CaO, MgO, Ba and Sr. They are rich in Rare Earth Elements (REE) and have extreme negative Eu anomalies (Eu/Eu*= 0.03–0.09). A genetic linkage between the pegmatites, aplites and alkali granite is confirmed by their common mild alkaline affinity and many other geochemical characteristics. These pegmatites and aplites represent the last small fraction of liquid remaining after extensive crystallization of granitic magma, injected along the foliation and into fractures of the host metamorphic rocks. The extensional tectonic regime and shallow depth of emplacement are consistent with a post-collisional environment. (Author)

  15. Metamorphic Evolution of Garnet-bearing Epidote-Barroisite Schist from the Meratus Complex in South Kalimantan, Indonesia

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    Nugroho Imam Setiawan


    Full Text Available DOI:10.17014/ijog.2.3.139-156This paper presents metamorphic evolution of metamorphic rocks from the Meratus Complex in South Kalimantan, Indonesia. Eight varieties of metamorphic rocks samples from this location, which are garnet-bearing epidote-barroisite schist, epidote-barroisite schist, glaucophane-quartz schist, garnet-muscovite schist, actinolite-talc schist, epidote schist, muscovite schist, and serpentinite, were investigated in detail its petrological and mineralogical characteristics by using polarization microscope and electron probe micro analyzer (EPMA. Furthermore, the pressure-temperature path of garnet-bearing epidote-barroisite schist was estimated by using mineral parageneses, reaction textures, and mineral chemistries to assess the metamorphic history. The primary stage of this rock might be represented by the assemblage of glaucophane + epidote + titanite ± paragonite. The assemblage yields 1.7 - 1.0 GPa in assumed temperature of 300 - 550 °C, which is interpreted as maximum pressure limit of prograde stage. The peak P-T condition estimated on the basis of the equilibrium of garnet rim, barroisite, phengite, epidote, and quartz, yields 547 - 690 °C and 1.1 - 1.5 GPa on the albite epidote amphibolite-facies that correspond to the depth of 38 - 50 km. The retrograde stage was presented by changing mineral compositions of amphiboles from the Si-rich barroisite to the actinolite, which lies near 0.5 GPa at 350 °C. It could be concluded that metamorphic rocks from the Meratus Complex experienced low-temperature and high-pressure conditions (blueschist-facies prior to the peak metamorphism of the epidote amphibolite-facies. The subduction environments in Meratus Complex during Cretaceous should be responsible for this metamorphic condition.

  16. Amphibolite to granulite progressive metamorphism in the Niquelândia Complex, Central Brazil: regional tectonic implications (United States)

    Filho, C. F. Ferreira; De Moraes, R.; Fawcett, J. J.; Naldrett, A. J.


    The Niquelândia Complex is a major Proterozoic mafic and ultramafic layered intrusion in central Brazil. Ductile deformation and associated metamorphic recrystallization are widespread along ductile shear zones. Bands of alumina and silica-rich rocks (less than few meters thick) occur in the central parts of these ductile shear zones. Metamorphic grade, ranging from amphibolite to granulite facies, increases progressively downward in the layered intrusion stratigraphy. The three mapped metamorphic zones: amphibolite zone, amphibolite-granulite transition zone and granulite zone, are parallel to the intrusion stratigraphy. Metabasites show progressive changes in mineral assemblages, texture, and Ca-amphibole composition in a traverse covering the three metamorphic zones. With increasing metamorphic grade, amphibolites (hbl+pl ± cpx ± grt ± ep) give way to hornblende granulites (hbl+pl+cpx+opx) and anhydrous mafic granulites (pl+cpx+opx). The Ti, A1 IV and Na+K content of amphiboles increase progressively with metamorphic grade. Quartz-rich rocks have kyanite as the Al 2SiO 5 polymorph in the amphibolite zone, whereas sillimanite occurs in the granulite zone. Geothermobarometry and mineral stability data indicate P-T conditions of peak metamorphism at about 700 °C and 6-8 kbars in the amphibolite zone and temperatures higher than 800 °C in the granulite zone. In quartz-rich rocks of the granulite zone, retrogressive processes are indicated by reaction coronas of sil+grt between peak metamorphic assemblages of hc+qtz and replacement of sillimanite by kyanite. These reactions have an appreciable temperature dependence and together they indicate a retrogressive path characterized by an initial period of nearly isobaric cooling. Previously reported U-Pb zircon dating demonstrates the coeval nature of the amphibolite and granulite facies metamorphism and supports the notion that the entire terrain represents a single continuous crustal section. The metamorphic age

  17. Metamorphic evolution and U-Pb zircon SHRIMP geochronology of the Belizário ultramafic amphibolite, Encantadas Complex, southernmost Brazil

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    Hartmann Léo A.


    Full Text Available The integrated investigation of metamorphism and zircon U-Pb SHRIMP geochronology of the Belizário ultramafic amphibolite from southernmost Brazil leads to a better understanding of the processes involved in the generation of the Encantadas Complex. Magmatic evidence of the magnesian basalt or pyroxenite protolith is only preserved in cores of zircon crystals, which are dated at 2257 ± 12 Ma. Amphibolite facies metamorphism M1 formed voluminous hornblende in the investigated rock possibly at 1989 ± 21 Ma. This ultramafic rock was re-metamorphosed at 702±21 Ma during a greenschist facies eventM2; the assemblage actinolite + oligoclase + microcline + epidote + titanite + monazite formed by alteration of hornblende. The metamorphic events are probably related to the Encantadas Orogeny (2257±12 Ma and Camboriú Orogeny (~ 1989 Ma of the Trans-Amazonian Cycle, followed by an orogenic event (702±21 Ma of the Brasiliano Cycle. The intervening cratonic period (2000-700 Ma corresponds to the existence of the Supercontinent Atlantica, known regionally as the Rio de la Plata Craton.

  18. Late Cretaceous extension and exhumation of the Stong and Taku magmatic and metamorphic complexes, NE Peninsular Malaysia

    NARCIS (Netherlands)

    François, T.; Md Ali, M.A.; Matenco, L.; Willingshofer, E.; Ng, T.F.; Taib, N.I.; Shuib, M.K.


    Fragmentation of large continental areas by post-orogenic extension requires favourable geodynamic conditions and frequently occurs along pre-existing suture zones or nappe contacts, as exemplified by the Stong and Taku magmatic and metamorphic complexes of northern Peninsular Malaysia. For this

  19. Granulites and charnockites of the Gruf Complex: Evidence for Permian ultra-high temperature metamorphism in the Central Alps (United States)

    Galli, A.; Le Bayon, B.; Schmidt, M. W.; Burg, J.-P.; Caddick, M. J.; Reusser, E.


    We present a detailed field and petrological study of charnockites and ultra-high temperature (UHT) granulites from the Gruf Complex, eastern Central Alps. Charnockites occur as up to 0.5 km wide and 8 km long, internally boudinaged, opx-bearing sheet-like bodies within the regionally dominant migmatitic biotite-orthogneisses. Granulites occur as garnet-orthopyroxene-biotite-alkali feldspar-bearing schlieren (± sapphirine, sillimanite, cordierite, corundum, spinel, plagioclase, and quartz) within charnockites and as residual enclaves both in the charnockites and the migmatitic orthogneisses. Thermobarometric calculations, P-T pseudosections and orthopyroxene Al content, show that both charnockites and granulites equilibrated at metamorphic peak conditions of T = 920-940 °C and P = 8.5-9.5 kbar. Peak assemblages were subsequently overprinted by intergrowth, symplectite and corona textures involving orthopyroxene, sapphirine, cordierite and spinel at T = 720-740 °C and P = 7-7.5 kbar. We suggest that granulites and charnockites are lower crustal relicts preserved in the migmatitic orthogneisses. Garnet diffusion modelling shows that metamorphic garnet-opx ± sapphirine ± sillimanite peak assemblages and post-peak reaction textures always involving cordierite developed during two separate metamorphic cycles. Peak assemblages reflect UHT metamorphism related to post-Varican Permian extension, but post-peak coronae and symplectites formed during the mid-Tertiary, upper amphibolite facies, Alpine regional metamorphism. Fluid-absent partial melting of pelitic and psammitic sediments during the Permian UHT event lead to the formation of charnockitic magmas and granulitic residues. Intense melt loss and thorough dehydration of the granulites (although retaining biotite) favoured the partial preservation of peak mineral assemblages during Alpine metamorphism.

  20. Mayer Kangri metamorphic complexes in Central Qiangtang (Tibet, western China): implications for the Triassic-early Jurassic tectonics associated with the Paleo-Tethys Ocean (United States)

    Wang, Yixuan; Liang, Xiao; Wang, Genhou; Yuan, Guoli; Bons, Paul D.


    The Mesozoic orogeny in Central Qiangtang Metamorphic Belt, northern Tibet, provides important insights into the geological evolution of the Paleo-Tethys Ocean. However, the Triassic-early Jurassic tectonics, particularly those associated with the continental collisionstage, remains poorly constrained. Here we present results from geological mapping, structural analysis, P-T data, and Ar-Ar geochronology of the Mayer Kangri metamorphic complex. Our data reveal an E-W-trending, 2 km wide dome-like structure associated with four successive tectonic events during the Middle Triassic and Early Jurassic. Field observations indicate that amphibolite and phengite schist complexes in this complex are separated from the overlying lower greenschist mélange by normal faulting with an evident dextral shearing component. Open antiform-like S2 foliation of the footwall phengite schist truncates the approximately north-dipping structures of the overlying mélange. Microtextures and mineral chemistry of amphibole reveal three stages of growth: Geothermobarometric estimates yield temperatures and pressures of 524 °C and 0.88 GPa for pargasite cores, 386 °C and 0.34 GPa for actinolite mantles, and 404 °C and 0.76 GPa for winchite rims. Peak blueschist metamorphism in the phengite schist occurred at 0.7-1.1 GPa and 400 °C. Our Ar-Ar dating of amphibole reveals rim-ward decreasing in age bands, including 242.4-241.2 Ma, ≥202.6-196.8, and 192.9-189.8 Ma. The results provide evidence for four distinct phases of Mesozoic tectonic evolution in Central Qiangtang: (1) northward oceanic subduction beneath North Qiangtang ( 244-220 Ma); (2) syn-collisional slab-break off (223-202 Ma); (3) early collisional extension driven by buoyant extrusion flow from depth ( 202.6-197 Ma); and (4) post-collision contraction and reburial (195.6-188.7 Ma).

  1. The behaviour of monazite from greenschist facies phyllites to anatectic gneisses: An example from the Chugach Metamorphic Complex, southern Alaska (United States)

    Gasser, Deta; Bruand, Emilie; Rubatto, Daniela; Stüwe, Kurt


    Monazite is a common accessory mineral in various metamorphic and magmatic rocks, and is widely used for U-Pb geochronology. However, linking monazite U-Pb ages with the PT evolution of the rock is not always straightforward. We investigated the behaviour of monazite in a metasedimentary sequence ranging from greenschist facies phyllites into upper amphibolites facies anatectic gneisses, which is exposed in the Eocene Chugach Metamorphic Complex of southern Alaska. We investigated textures, chemical compositions and U-Pb dates of monazite grains in samples of differing bulk rock composition and metamorphic grade, with particular focus on the relationship between monazite and other REE-bearing minerals such as allanite and xenotime. In the greenschist facies phyllites, detrital and metamorphic allanite is present, whereas monazite is absent. In lower amphibolites facies schists (~ 550-650 °C and ≥ 3.4 kbar), small, medium-Y monazite is wide-spread (Mnz1), indicating monazite growth prior and/or simultaneous with growth of garnet and andalusite. In anatectic gneisses, new low-Y, high-Th monazite (Mnz2) crystallised from partial melts, and a third, high-Y, low-Th monazite generation (Mnz3) formed during initial cooling and garnet resorption. U-Pb SHRIMP analysis of the second and third monazite generations yields ages of ~ 55-50 Ma. Monazite became unstable and was overgrown by allanite and/or allanite/epidote/apatite coronas within retrograde muscovite- and/or chlorite-bearing shear zones. This study documents polyphase, complex monazite growth and dissolution during a single, relatively short-lived metamorphic cycle.

  2. Paleomagnetic evidence for an inverse rotation history of Western Anatolia during the exhumation of Menderes core complex

    NARCIS (Netherlands)

    Uzel, Bora; Langereis, Cornelis G.; Kaymakçı, Nuretdin; Sözbilir, Hasan; Özkaymak, Çağlar; Özkaptan, Murat


    Within the Aegean extensional system, the Izmir-Balikesir Transfer Zone (IBTZ) is a crucial element in the late Cenozoic evolution of western Anatolia since it accommodates the differential deformation between the Cycladic and the Menderes metamorphic core complexes. Here, we determine the

  3. The role of amphiboles in the metamorphic evolution of the UHP rocks: a case study from the Tso Morari Complex, northwest Himalayas (United States)

    Singh, Preeti; Pant, Naresch C.; Saikia, Ashima; Kundu, Amitava


    Amphiboles represent a crucial phase of the ultra-high-pressure (UHP) metamorphic rocks as their solid solution behavior reflects both bulk compositional and P- T changes. Three different types of amphibole have been reported from the UHP metamafic rocks of the Tso Morari Crystalline Complex, NW Himalayas: Na-rich (glaucophane); Na-Ca-rich (barroisite, taramite, winchite) and Ca-rich (tremolite, magnesio-hornblende, pargasite). The Na-amphibole is presented as a core of the zoned amphibole with Na-Ca-rich rim; Na-Ca-amphibole is presented as inclusion in garnets as well as in matrix, and Ca-amphibole is generally found in the matrix. The Na-Ca-amphibole is observed at two different stages of metamorphism. The first is pre-UHP, and the second is post-garnet-omphacite assemblage though with a significant difference in composition. The pressure-temperature estimations of the formation of these two sets of Na-Ca-amphiboles corroborate their textural associations. Ca-rich amphiboles are generally present in the matrix either as symplectite with plagioclase or as a pseudomorph after garnet along with other secondary minerals like chlorite and biotite. Two different types of zoning have been observed in the amphibole grains: (1) core is Na-rich followed by Na-Ca rim and (2) core of Na-Ca-amphibole is followed by Ca-rich rim. The pre-UHP (or the prograde P- T path) and post-UHP stages (or the retrograde P- T path) of Tso Morari eclogites are defined by characteristic amphibole compositions, viz. Na/Na-Ca-amphibole, Na-Ca-amphibole and Ca-amphibole and thus indicate their utility in inferring crustal evolution of this UHP terrain.

  4. Chemical and mineralogical data and processing methods management system prototype with application to study of the North Caucasus Blybsky Metamorphic Complexes metamorphism PT-condition (United States)

    Ivanov, Stanislav; Kamzolkin, Vladimir; Konilov, Aleksandr; Aleshin, Igor


    There are many various methods of assessing the conditions of rocks formation based on determining the composition of the constituent minerals. Our objective was to create a universal tool for processing mineral's chemical analysis results and solving geothermobarometry problems by creating a database of existing sensors and providing a user-friendly standard interface. Similar computer assisted tools are based upon large collection of sensors (geothermometers and geobarometers) are known, for example, the project TPF (Konilov A.N., 1999) - text-based sensor collection tool written in PASCAL. The application contained more than 350 different sensors and has been used widely in petrochemical studies (see A.N. Konilov , A.A. Grafchikov, V.I. Fonarev 2010 for review). Our prototype uses the TPF project concept and is designed with modern application development techniques, which allows better flexibility. Main components of the designed system are 3 connected datasets: sensors collection (geothermometers, geobarometers, oxygen geobarometers, etc.), petrochemical data and modeling results. All data is maintained by special management and visualization tools and resides in sql database. System utilities allow user to import and export data in various file formats, edit records and plot graphs. Sensors database contains up to date collections of known methods. New sensors may be added by user. Measured database should be filled in by researcher. User friendly interface allows access to all available data and sensors, automates routine work, reduces the risk of common user mistakes and simplifies information exchange between research groups. We use prototype to evaluate peak pressure during the formation of garnet-amphibolite apoeclogites, gneisses and schists Blybsky metamorphic complex of the Front Range of the Northern Caucasus. In particular, our estimation of formation pressure range (18 ± 4 kbar) agrees on independent research results. The reported study was

  5. Complex coacervate core micro-emulsions

    NARCIS (Netherlands)

    Hofs, P.S.; Keizer, de A.; Burgh, van der S.; Leermakers, F.A.M.; Cohen Stuart, M.A.; Millard, P.E.; Muller, A.H.E.


    Complex coacervate core micelles form in aqueous solutions from poly(acrylic acid)-block-poly(acrylamide) (PAAxPAAmy, x and y denote degree of polymerization) and poly(N,N-dimethyl aminoethyl methacrylate) (PDMAEMA150) around the stoichiometric charge ratio of the two components. The hydrodynamic

  6. Metamorphic P-T path and zircon U-Pb dating of HP mafic granulites in the Yushugou granulite-peridotite complex, Chinese South Tianshan, NW China (United States)

    Zhang, Lu; Zhang, Lifei; Xia, Bin; Lü, Zeng


    Co-existing granulite and peridotite may represent relics of the paleo-suture zone and provides an optimal opportunity for better understanding of orogeny between two blocks. In this study, we carried out petrological and U-Pb zircon dating investigation on the HP mafic granulites associated with peridotite complex at Yushugou in Chinese South Tianshan. The studied samples include garnet-bearing high-pressure mafic granulites which can be subdivided into two types: Type I orthopyroxene-free and Type II orthopyroxene-bearing granulites and amphibolite. Type I granulite (Y21-2) has a mineral assemblage of garnet (33 vol.%), clinopyroxene (32 vol.%) and plagioclase (30 vol.%); and Type II granulite (Y18-8) has a mineral assemblage of garnet (22 vol.%), clinopyroxene (10 vol.%), orthopyroxene (14 vol.%), plagioclase (45 vol.%) and quartz. Garnet in both granulites exhibits core-rim structure characterized by increasing grossular and decreasing pyrope from core to rim. Petrographic observations and phase equilibrium modeling using THERMOCALC in the NCFMASHTO system for the mafic granulites (Y21-2 and Y18-8) show three stages of metamorphism: Stage I (granulite facies) was recognized by the large porphyroblastic garnet core, with P-T conditions of 9.8-10.4 Kbar and 860-900 °C (Y21-2) and 9.9-10.6 Kbar and 875-890 °C (Y18-8), respectively; Stage II (HP granulite facies) has peak P-T conditions of 12.1 Kbar at 755 °C (Y21-2) and 13.8 Kbar at 815 °C (Y18-8) using mineral assemblages combining with garnet rim compositions with maximum grossular and minimum pyrope contents; Stage III (amphibolite facies) was characterized by the development of calcic amphibole in granulites with temperature of 446-563 °C. Therefore, an anticlockwise P-T path characterized by simultaneous temperature-decreasing and pressure-increasing was inferred for the Yushugou HP mafic granulite. Studies of zircon morphology and inclusions, combined with zircon U-Pb dating and REE geochemistry

  7. Late Cretaceous extension and exhumation of the Stong and Taku magmatic and metamorphic complexes, NE Peninsular Malaysia (United States)

    François, T.; Md Ali, M. A.; Matenco, L.; Willingshofer, E.; Ng, T. F.; Taib, N. I.; Shuib, M. K.


    Fragmentation of large continental areas by post-orogenic extension requires favourable geodynamic conditions and frequently occurs along pre-existing suture zones or nappe contacts, as exemplified by the Stong and Taku magmatic and metamorphic complexes of northern Peninsular Malaysia. For this case, we have employed a field and microstructural kinematic study combined with low temperature thermo-chronology to analyse the tectonic and exhumation history. The results show that the Late Palaeozoic - Triassic Indosinian orogeny created successive phases of burial related metamorphism, shearing and contractional deformation. This orogenic structure was subsequently dismembered during a Cretaceous thermal event that culminated in the formation of a large scale Late Santonian - Early Maastrichtian extensional detachment, genetically associated with crustal melting, the emplacement of syn-kinematic plutons and widespread migmatisation. The emplacement of these magmatic rocks led to an array of simultaneously formed structures that document deformation conditions over a wide temperature range, represented by amphibolite- and greenschist- facies mylonites and as well as brittle structures, such as cataclastic zones and normal faults that formed during exhumation in the footwall of the detachment. The formation of this detachment and a first phase of Late Cretaceous cooling was followed by renewed Eocene - Oligocene exhumation, as evidenced from our fission track ages. We infer that an initial Cretaceous thermal anomaly was responsible for the formation of an extensional gneiss dome associated with simple shear and rotation of normal faults. These Cretaceous processes played a critical role in the establishment of the presently observed crustal structure of Peninsular Malaysia.

  8. The eclogites of the Marun Keu complex, Polar Urals (Russia): fluid control on reaction kinetics and metasomatism during high P metamorphism (United States)

    Molina, José F.; Austrheim, Håkon; Glodny, Johannes; Rusin, Anatolij


    studied area presents a large variety of veins and metasomatic mineral sequences developing in the host-rock adjacent to the veins. High P minerals (garnet (Alm 40-60, Pyr 25-40, Gro 11-23), omphacite, phengite, paragonite) occur in both vein infillings and wall-rock mineral sequences, indicating that metasomatism was caused by the infiltration of out of equilibrium fluids (mostly silica-rich, alkali-rich compositions) during the eclogite-facies metamorphism. In zones of high fracture density, vein networks divide the host-rock into decimetre-scale blocks with omphacite-rich rinds replacing amphibolite cores. In contrast, metasomatic replacement of mafic eclogites by dendritic amphibole with barroisite composition ( M4Na˜0.64 apfu, based on 23 oxygens) also occurred at eclogite-facies conditions. We outline the importance of considering such metasomatic processes for the correct evaluation of P- T- t metamorphic histories. The Marun-Keu complex is another example that highlights the important control exerted by fluids on reaction kinetics during high P metamorphism and further points to an important metasomatic effect of these fluids.

  9. Thrusting and transpressional shearing in the Pan-African nappe southwest El-Sibai core complex, Central Eastern Desert, Egypt (United States)

    El-Wahed, Mohamed A. Abd.


    The Wadi El-Shush area in the Central Eastern Desert (CED) of Egypt is occupied by the Sibai core complex and its surrounding Pan-African nappe complex. The sequence of metamorphic and structural events in the Sibai core complex and the enveloping Pan-African nappe can be summarized as follows: (1) high temperature metamorphism associated with partial melting of amphibolites and development of gneissic and migmatitic rocks, (2) between 740 and 660 Ma, oblique island arc accretion resulted in Pan-African nappe emplacement and the intrusion of syn-tectonic gneissic tonalite at about 680 ± 10 Ma. The NNW-SSE shortening associated with oblique island arc accretion produced low angle NNW-directed thrusts and open folds in volcaniclastic metasediments, schists and isolated serpentinite masses (Pan-African nappe) and created NNE-trending recumbent folds in syn-tectonic granites. The NNW-SSE shortening has produced imbricate structures and thrust duplexes in the Pan-African nappe, (3) NE-ward thrusting which deformed the Pan-African nappe into SW-dipping imbricate slices. The ENE-WSW compression event has created NE-directed thrusts, folded the NNW-directed thrusts and produced NW-trending major and minor folds in the Pan-African nappe. Prograde metamorphism (480-525 °C at 2-4.5 kbar) was synchronous with thrusting events, (4) retrograde metamorphism during sinistral shearing along NNW- to NW-striking strike-slip shear zones (660-580 Ma), marking the external boundaries of the Sibai core complex and related to the Najd Fault System. Sinistral shearing has produced steeply dipping mylonitic foliation and open plunging folds in the NNW- and NE-ward thrust planes. Presence of retrograde metamorphism supports the slow exhumation of Sibai core complex under brittle-ductile low temperature conditions. Arc-accretion caused thrusting, imbrication and crustal thickening, whereas gravitational collapse of a compressed and thickened lithosphere initiated the sinistral movement

  10. Late Mesoproterozoic to Early Paleozoic history of metamorphic basement from the southeastern Chiapas Massif Complex, Mexico, and implications for the evolution of NW Gondwana (United States)

    Weber, Bodo; González-Guzmán, Reneé; Manjarrez-Juárez, Román; Cisneros de León, Alejandro; Martens, Uwe; Solari, Luigi; Hecht, Lutz; Valencia, Victor


    In this paper, U-Pb zircon geochronology, Lu-Hf and Sm-Nd isotope systematics, geochemistry and geothermobarometry of metaigneous basement rocks exposed in the southeastern Chiapas Massif Complex are presented. Geologic mapping of the newly defined "El Triunfo Complex" located at the southeastern edge of the Chiapas Massif reveals (1) partial melting of a metamorphic basement mainly constituted by mafic metaigneous rocks (Candelaria unit), (2) an Ediacaran metasedimentary sequence (Jocote unit), and (3) occurrence of massif-type anorthosite. All these units are intruded by undeformed Ordovician plutonic rocks of the Motozintla suite. Pressure and temperature estimates using Ca-amphiboles, plagioclase and phengite revealed prograde metamorphism that reached peak conditions at 650 °C and 6 kbar, sufficient for partial melting under water saturated conditions. Relict rutile in titanite and clinopyroxene in amphibolite further indicate a previous metamorphic event at higher P-T conditions. U-Pb zircon ages from felsic orthogneiss boudins hosted in deformed amphibolite and migmatite yield crystallization ages of 1.0 Ga, indicating that dry granitic protoliths represent remnants of Rodinia-type basement. Additionally, a mid-Tonian ( 920 Ma) metamorphic overprint is suggested by recrystallized zircon from a banded gneiss. Zircon from folded amphibolite samples yield mainly Ordovician ages ranging from 457 to 444 Ma that are indistinguishable from the age of the undeformed Motozintla plutonic suite. Similar ages between igneous- and metamorphic- zircon suggest a coeval formation during a high-grade metamorphic event, in which textural discrepancies are explained in terms of differing zircon formation mechanisms such as sub-solidus recrystallization and precipitation from anatectic melts. In addition, some amphibolite samples contain inherited zircon yielding Stenian-Tonian ages around 1.0 Ga. Lu-Hf and Sm-Nd isotopes and geochemical data indicate that the protoliths of

  11. Mineral chemistry and geothemobarometry of mantle harzburgites in the Eastern Metamorphic Complex of Khoy ophiolite -NW Iran

    Directory of Open Access Journals (Sweden)

    Morovvat Faridazad


    Full Text Available Introduction Khoy ophiolite at the global scale is in the middle part of the Alp-Himalaya orogenic belt and it is extended over 3900 Km2 which indicates remnant Neotethys oceanic lithosphere in the Mesozoic era (Kananian et al., 2010. In this paper, in addition to a review of previous investigations about Khoy ophiolite, we will try to determine the nature and kind of minerals, origin and partial melting rate as well as the equilibrium pressure and temperature of harzburgites from the Eastern Metamorphic Complex of Khoy ophiolite. Materials and methods Thin sections microscopy studies were carried out following field investigations. EPMA analysis was carried out with using a Superprobe JEOL, JXA 8200 Microprobe unit at the state of WDS and under condition of 15kv accelerating voltage, 10nA current beam, 1µm beam diameter and collection of natural and synthetic standards for calibration. Results The study area is located at the NW of Iran and north of the Khoy city in the west Azarbaijan province. This area is part of the ophiolitic complex of NW Iran and belongs to its Eastern Metamorphic Complex. This metamorphic zone has large tectonically segments of the metamorphic ophiolites which mainly include serpentinized peridotites with associated metagabbros. There are three types of peridotitic rocks in this area which are: Lherzolites, harzburgites and dunites. Lherzolites are composed of olivine (60-70%, orthopyroxene (10-30% and clinopyroxene (~10-20% with minor amounts (~2% of Cr-spinel mineral. Harzburgites are composed of olivine (70-80%, orthopyroxene (10-20% and clinopyroxene (~5% with minor amounts (~2% of Cr-spinel mineral. Dunites are composed of olivine (90-95%, orthopyroxene (5-10% with minor amounts (~1-2% of Cr-spinel mineral. Composition range of olivines is between Fo89.46 Fa10.37 to Fo89.86 Fa10.0 as well as NiO content range is 018-046 (wt %. The calculated Mg# of olivines is 0.90 and the composition of olivines in Fo-Fa diagram

  12. Core-periphery organization of complex networks. (United States)

    Holme, Petter


    Networks may, or may not, be wired to have a core that is both itself densely connected and central in terms of graph distance. In this study we propose a coefficient to measure if the network has such a clear-cut core-periphery dichotomy. We measure this coefficient for a number of real-world and model networks and find that different classes of networks have their characteristic values. Among other things we conclude that geographically embedded transportation networks have a strong core-periphery structure. We proceed to study radial statistics of the core, i.e., properties of the neighborhoods of the core vertices for increasing n. We find that almost all networks have unexpectedly many edges within n neighborhoods at a certain distance from the core suggesting an effective radius for nontrivial network processes.

  13. Characterizing core-periphery structure of complex network by h-core and fingerprint curve (United States)

    Li, Simon S.; Ye, Adam Y.; Qi, Eric P.; Stanley, H. Eugene; Ye, Fred Y.


    It is proposed that the core-periphery structure of complex networks can be simulated by h-cores and fingerprint curves. While the features of core structure are characterized by h-core, the features of periphery structure are visualized by rose or spiral curve as the fingerprint curve linking to entire-network parameters. It is suggested that a complex network can be approached by h-core and rose curves as the first-order Fourier-approach, where the core-periphery structure is characterized by five parameters: network h-index, network radius, degree power, network density and average clustering coefficient. The simulation looks Fourier-like analysis.

  14. Core-periphery organization of complex networks


    Holme, Petter


    Networks may, or may not, be wired to have a core that is both itself densely connected and central in terms of graph distance. In this study we propose a coefficient to measure if the network has such a clear-cut core-periphery dichotomy. We measure this coefficient for a number of real-world and model networks and find that different classes of networks have their characteristic values. For example do geographical networks have a strong core-periphery structure, while the core-periphery str...

  15. The effects of lower crustal strength and preexisting midcrustal shear zones on the formation of continental core complexes and low-angle normal faults

    KAUST Repository

    Wu, Guangliang


    To investigate the formation of core complexes and low-angle normal faults, we devise thermomechanical simulations on a simplified wedge-like orogenic hinterland that has initial topography, Moho relief, and a preexisting midcrustal shear zone that can accommodate shear at very low angles (<20°). We mainly vary the strength of the lower crust and the frictional strength of the preexisting midcrustal shear zone. We find that the strength of the lower crust and the existence and strength of a preexisting shear zone significantly affect the formation and evolution of core complexes. With increasing lower crustal strength, we recognize varying extensional features with decreasing exhumation rate: these are characterized by bivergent metamorphic massifs, classic Cordilleran metamorphic core complexes, multiple consecutive core complexes (or boudinage structures), and a flexural core complex underlined by a large subsurface low-angle detachment fault with a small convex curvature. Topographic loading and mantle buoyancy forces, together with divergent boundaries, drive a regional lower crustal flow that leads to the exhumation of the lower crust where intensive upper crustal faulting induces strong unloading. The detachment fault is a decoupling zone that accommodates large displacement and accumulates sustained shear strain at very low angle between upper and lower crust. Though the regional stress is largely Andersonian, we find non-Andersonian stress in regions adjacent to the preexisting shear zone and those with high topographic gradient. Our new models provide a view that is generally consistent with geological and geophysical observations on how core complexes form and evolve.

  16. Metamorphic chlorite and "vermiculitic" phases in mafic dikes from the Maláguide Complex (Betic Cordillera, Spain)

    Czech Academy of Sciences Publication Activity Database

    Ruiz Cruz, M. D.; Novák, Jiří Karel


    Roč. 15, č. 1 (2003), s. 1-14 ISSN 0935-1221 Grant - others:Ministerio de Educación y Cultura(ES) BTE-2000-1150; Research Group(ES) RNM-199 Institutional research plan: CEZ:AV0Z3013912 Keywords : low-grade metamorphism * vermiculite * Betic Cordillera Subject RIV: DB - Geology ; Mineralogy Impact factor: 1.185, year: 2003

  17. Structure and Stability of Complex Coacervate Core Micelles with Lysozyme

    NARCIS (Netherlands)

    Lindhoud, Saskia; de Vries, Renko; Norde, Willem; Cohen Stuart, Martinus Abraham


    Encapsulation of enzymes by polymers is a promising method to influence their activity and stability. Here, we explore the use of complex coacervate core micelles for encapsulation of enzymes. The core of the micelles consists of negatively charged blocks of the diblock copolymer PAA42PAAm417 and

  18. Structure and stability of complex coacervate core micelles with lysozyme

    NARCIS (Netherlands)

    Lindhoud, S.; Vries, de R.J.; Norde, W.; Cohen Stuart, M.A.


    Encapsulation of enzymes by polymers is a promising method to influence their activity and stability. Here, we explore the use of complex coacervate core micelles for encapsulation of enzymes. The core of the micelles consists of negatively charged blocks of the diblock copolymer PAA42PAAm417 and

  19. Structure and stability of complex coacervate core micelles with lysozyme

    NARCIS (Netherlands)

    Lindhoud, Saskia; de Vries, Renko; Norde, Willem; Cohen Stuart, Martien A.

    Encapsulation of enzymes by polymers is a promising method to influence their activity and stability. Here, we explore the use of complex coacervate core micelles for encapsulation of enzymes. The core of the micelles consists of negatively charged blocks of the diblock copolymer PAA(42)PAAm(417)

  20. Pliocene Core Complex Exhumation on Land and Rapid Subsidence in Gorontalo Bay, Sulawesi (Indonesia) (United States)

    Pezzati, G.; Hall, R.; Burgess, P.; Perez-Gussinye, M.


    Gorontalo Bay is a semi-enclosed sea between the North and East Arms of Sulawesi. It is surrounded by land on three sides, separating a northern volcanic province from metamorphic rocks to the south and west, and ophiolites to the southeast. Recently acquired multibeam bathymetry and 2D seismic data suggest a link between core complex exhumation on land and offshore subsidence driven by major young extension. In western Gorontalo Bay are two sub-basins with different histories: Tomini Basin in the north and Poso Basin in the south. In Tomini Basin six major seismic sequences (Units A to F) have a total thickness over 5 sec TWT. Ages are based on interpreted correlations with events on land. Basement Unit A subsided from the Early Miocene, with deposition of Units B and C, largely in a deep marine environment. There was regional uplift in the Middle Miocene. Carbonate platforms were thereafter deposited in shallow marine environments (Units D-E). The platforms show a wedge geometry that suggests tilting of the basin during their deposition. Subsidence accelerated during the deposition of Unit E in the Early Pliocene, causing backstepping of the shelf edge, formation of pinnacle reefs and then drowning of the carbonate platforms, leading to present depths of 2 km in the basin centre (Unit F). Poso Basin is younger than Tomini Basin and forms the southern part of western Gorontalo Bay. The deeper part of its sedimentary sequence is probably the time equivalent of Unit D in Tomini Basin. It contains a complex deformed sequence of sediments, up to 3 sec TWT, that are the probable equivalent of Units E and F to the north. On land to the south of Poso Basin is a large metamorphic core complex. Seismic data suggest that the northern flank of the complex can be traced into a potential low angle normal fault under the basin that caused subsidence offshore. Low T thermochronology and alluvial sediment records on land suggest major uplift and subsidence occurred in the

  1. Measurement of activity concentration of 222Rn in ground waters drawn from two wells drilled in the Amparo Complex metamorphic rocks, municipio de Amparo, SP

    International Nuclear Information System (INIS)

    Oliveira, Igor Jose Chaves de


    A sampling system was assembled for field 222 Rn activity concentration measurements in ground waters. The system consists of a sampling flask that prevents the contact between the water sample and the atmosphere and a closed line for radon extraction from water. The system, its operation and calibration, are described in full detail, as well as, the conversion of the measured alpha counting rates in activity concentrations. The assembled system was used in 222 Rn activity concentrations measurements in ground waters drawn from two wells drilled in the Amparo Complex metamorphic rocks. The wells are located at the urban area of the city of Amparo and are exploited for public use water. One well, named Vale Verde, is 56 meters deep and crosses 18 meters of soil, 26 meters of quartz rich gneiss and 12 meters of biotite-gneiss. The other well, named Seabra, is 117 meters deep, crosses 28 meters of soil and weathered rocks and ends in granite-gneiss. The mean activity concentrations for the year long observation were (377 +- 25) Bq/dm 3 , for Seabra well, and (1282 +- 57) Bq/dm3, for the Vale Verde well. The 222 Rn activity concentrations fall in the activity concentration range reported in the literature for similar geology areas and are larger than the concentrations found neighboring areas of the same metamorphic Complex. The seasonal activity concentration variations seem to correlate with rain fall variations in the study area. (author)

  2. Evaluating the core microbiota in complex communities: A systematic investigation. (United States)

    Astudillo-García, Carmen; Bell, James J; Webster, Nicole S; Glasl, Bettina; Jompa, Jamaluddin; Montoya, Jose M; Taylor, Michael W


    The study of complex microbial communities poses unique conceptual and analytical challenges, with microbial species potentially numbering in the thousands. With transient or allochthonous microorganisms often adding to this complexity, a 'core' microbiota approach, focusing only on the stable and permanent members of the community, is becoming increasingly popular. Given the various ways of defining a core microbiota, it is prudent to examine whether the definition of the core impacts upon the results obtained. Here we used complex marine sponge microbiotas and undertook a systematic evaluation of the degree to which different factors used to define the core influenced the conclusions. Significant differences in alpha- and beta-diversity were detected using some but not all core definitions. However, findings related to host specificity and environmental quality were largely insensitive to major changes in the core microbiota definition. Furthermore, none of the applied definitions altered our perception of the ecological networks summarising interactions among bacteria within the sponges. These results suggest that, while care should still be taken in interpretation, the core microbiota approach is surprisingly robust, at least for comparing microbiotas of closely related samples. © 2017 Society for Applied Microbiology and John Wiley & Sons Ltd.

  3. Metamorphic reactions, deformation localization and rheological evolution of gabbro to eclogite transformation: A case study from Lofoten Anorthosite Complex, Norway (United States)

    Nasipuri, P.; Stunitz, H.; Menegon, L.; Ravna, E. J.; Kullerud, K.; Berger, A.


    Eclogitization of lower crustal rocks during subduction processes and subsequent retrogression during exhumation will produce a range of mineral assemblages over widely spaced P-T conditions affecting the rheological behavior of the rock significantly. In this contribution, we describe the formation of syn-kinematic mineral assemblages which promotes development of centimeter- to meter-scale shear zones in undeformed leucogabbro from Lofoten, Norway. Plagioclase (Pl0), olivine (Ol0) and orthopyroxene (Opx0) form the igneous texture in the leucogabbro. Opx1 and Grt1 corona indicate the onset of metamorphism (M1) during subduction processes. Cm- wide alternating bands of a mixture of Pl-Amphibole(Amph) ± Spl and GrtI(M1) - Opx -Omph (M2A) phase mixtures characterize prograde metamorphic shear zones in the leucogabbro. Elongated Omph overgrow deformed Opx grains (D1). Relicts of Opx grains are surrounded by recrystallized opx indicating that the Opx grains survived in the Omph stability field. Grt- Cpx - Pl symplectite (M2B) rim the Omph± Opx porphyroblasts. GrtII(M3) occurs along the contact of deformed Opx± Omph and Pl. Amph ± Spl (M4) overgrow the finer grained pyroxene. Conventional thermobarometry indicate that metamorphism (M1) starts at 7000C at 1 GPa pressure. The peak PT-condition (650-7500C, > 1.8 GPa) was attained during the formation of Omph. The retrograde PT-path is represented by Cpx-Pl symplectite (600-6500C, 1 GPa) and Grt corona (6000C, 0.8 GPa). Replacement of fine-grained Cpx by Amph represents the last stage of metamorphism. Crystal orientation of Opx relicts is different from the CPO of the newly formed Opx (10 - 15 μm in size) indicating that Opx did not recrystallize by progressive subgrain rotation. The dramatic grain size reduction without significant change in chemical composition is probably caused by cracking of Opx at the onset of deformation. Small new grains may nucleate from fragments. In the fine grained Pl+ Amph± Spl aggregates

  4. Modularized Functions of the Fanconi Anemia Core Complex

    Directory of Open Access Journals (Sweden)

    Yaling Huang


    Full Text Available The Fanconi anemia (FA core complex provides the essential E3 ligase function for spatially defined FANCD2 ubiquitination and FA pathway activation. Of the seven FA gene products forming the core complex, FANCL possesses a RING domain with demonstrated E3 ligase activity. The other six components do not have clearly defined roles. Through epistasis analyses, we identify three functional modules in the FA core complex: a catalytic module consisting of FANCL, FANCB, and FAAP100 is absolutely required for the E3 ligase function, and the FANCA-FANCG-FAAP20 and the FANCC-FANCE-FANCF modules provide nonredundant and ancillary functions that help the catalytic module bind chromatin or sites of DNA damage. Disruption of the catalytic module causes complete loss of the core complex function, whereas loss of any ancillary module component does not. Our work reveals the roles of several FA gene products with previously undefined functions and a modularized assembly of the FA core complex.

  5. GluR2 ligand-binding core complexes

    DEFF Research Database (Denmark)

    Kasper, C; Lunn, M-L; Liljefors, T


    X-ray structures of the GluR2 ligand-binding core in complex with (S)-Des-Me-AMPA and in the presence and absence of zinc ions have been determined. (S)-Des-Me-AMPA, which is devoid of a substituent in the 5-position of the isoxazolol ring, only has limited interactions with the partly hydrophobic...

  6. Stability of complex coacervate core micelles containing metal coordination polymer

    NARCIS (Netherlands)

    Yan, Y.; Keizer, de A.; Cohen Stuart, M.A.; Drechsler, M.; Besseling, N.A.M.


    We report on the stability of complex coacervate core micelles, i.e., C3Ms (or PIC, BIC micelles), containing metal coordination polymers. In aqueous solutions these micelles are formed between charged-neutral diblock copolymers and oppositely charged coordination polymers formed from metal ions and

  7. Complex coacervate core micelles with a lysozyme-modified corona

    NARCIS (Netherlands)

    Danial, M.; Klok, H.A.; Norde, W.; Cohen Stuart, M.A.


    This paper describes the preparation, characterization, and enzymatic activity of complex coacervate core micelles (C3Ms) composed of poly(acrylic acid) (PAA) and poly(N-methyl-2-vinyl pyridinium iodide)-b-poly(ethylene oxide) (PQ2VP-PEO) to which the antibacterial enzyme lysozyme is end-attached.

  8. Complex coacervation core micelles. Colloidal stability and aggregation mechanism

    NARCIS (Netherlands)

    Burgh, van der S.; Keizer, de A.; Cohen Stuart, M.A.


    Complex coacervation core micelles were prepared with various polyelectrolytes and oppositely charged diblock copolymers. The diblock copolymers consist of a charged block and a water-soluble neutral block. Our experimental technique was dynamic light scattering in combination with titrations. At

  9. Geochemistry and metamorphism of the Mouriscas Complex, Ossa-Morena/Central Iberian zone boundary, Iberian Massif, Central Portugal: Implications for the Cadomian and Variscan orogenies (United States)

    Henriques, S. B. A.; Neiva, A. M. R.; Tajčmanová, L.; Dunning, G. R.


    The Mouriscas Complex is a deformed and metamorphosed predominantly mafic igneous complex of Ediacaran and Ordovician age and crops out at the Ossa-Morena/Central Iberian zone boundary in the Iberian Massif, Central Portugal. It comprises amphibolite with Neoproterozoic protoliths (ca. 544 Ma), protomylonitic felsic dykes derived from younger trondhjemitic protoliths (ca. 483 Ma) and garnet amphibolite derived of even younger dioritic protoliths (ca. 477 Ma). The protoliths of the Neoproterozoic amphibolites are calc-alkaline magmas of basic to intermediate compositions with intraplate and active continental margin affinities and are considered to represent the final phase of the Cadomian arc magmatism. They are interpreted to have originated as coarse-grained intrusions, likely gabbro or diorite and generated from the partial melting of meta-igneous lower crust and mantle. Their emplacement occurred near the Cadomian metamorphic event dated at ca. 540 Ma (P = 7-8 kbar and T = 640-660 °C) which is interpreted to represent a continental collision. During the Late Cambrian-Early Ordovician an extensional episode occurred in the central-southern Iberian Massif and was also observed in other areas of the Variscan Orogen. It led to mantle upwelling and to the development of an aborted intracratonic rift located at the Ossa-Morena/Central Iberian zone boundary and to the opening of the Rheic Ocean to the south of the area studied in present coordinates (i.e., between the Ossa-Morena and South Portuguese Zones). This event has been dated at ca. 477 Ma and was responsible for the melting of deep ancient mafic crust and mantle with formation of bimodal magmatism in an intra-plate setting, as indicated by the protoliths of the protomylonitic felsic dykes with trondhjemitic composition and of the garnet amphibolite. Subsequent Variscan metamorphism took place under amphibolite facies conditions (P = 4-5.5 kbar; T = 600-625 °C) at lower P-T conditions than the Cadomian

  10. Core promoter recognition complex changes accompany liver development (United States)

    D’Alessio, Joseph A.; Ng, Raymond; Willenbring, Holger; Tjian, Robert


    Recent studies of several key developmental transitions have brought into question the long held view of the basal transcriptional apparatus as ubiquitous and invariant. In an effort to better understand the role of core promoter recognition and coactivator complex switching in cellular differentiation, we have examined changes in transcription factor IID (TFIID) and cofactor required for Sp1 activation/Mediator during mouse liver development. Here we show that the differentiation of fetal liver progenitors to adult hepatocytes involves a wholesale depletion of canonical cofactor required for Sp1 activation/Mediator and TFIID complexes at both the RNA and protein level, and that this alteration likely involves silencing of transcription factor promoters as well as protein degradation. It will be intriguing for future studies to determine if a novel and as yet unknown core promoter recognition complex takes the place of TFIID in adult hepatocytes and to uncover the mechanisms that down-regulate TFIID during this critical developmental transition. PMID:21368148

  11. Using quantitative phase petrology to understand metamorphism (United States)

    White, Richard


    Quantitative phase petrology has become one of the mainstay methods for interpreting metamorphic rocks and processes. Its increased utility has been driven by improvements to end-member thermodynamics, activity-composition relationships and computer programs to undertake calculations. Such improvements now allow us to undertake calculations in increasingly complex chemical systems that more closely reflect those of rocks. Recent progress in activity-composition (a-x) relationships is aimed at developing suites of a-x relationships in large chemical systems that are calibrated together, which will allow a more direct application of the method to metamorphic rocks. In addition, considerable progress has been made in how quantitative phase diagrams can be used to understand features, including chemical potential diagrams for reaction textures, methods for fractionating bulk compositions and methods for modelling open system processes. One feature of calculated phase diagrams is that they present us with a great amount of information, such as mineral assemblages, mineral proportions, phase compositions, volume or density etc. An important aspect to using this information is to understand the potential uncertainties associated with these, which are significant. These uncertainties require that calculated phase diagrams be used with caution to interpret observed features in rocks. Features such as mineral zoning and reaction textures should still be interpreted in a semi-quantitative way, even if based on a fully quantitative diagram. Exercises such as the interpretation of reaction overstepping based on relating phase diagrams to observed mineral core compositions are likely to give spurious results given the infelicities in existing a-x models. Despite these limitations, quantitative phase petrology remains the most useful approach to interpreting the metamorphic history of rocks in that it provides a theoretical framework in which to interpret observed features rather

  12. Petrology and SHRIMP zircon geochronology of granulites from Vesleknausen, Lützow-Holm Complex, East Antarctica: Neoarchean magmatism and Neoproterozoic high-grade metamorphism

    Directory of Open Access Journals (Sweden)

    Toshiaki Tsunogae


    Full Text Available We report new petrological data and geochronological measurements of granulites from Vesleknausen in the highest-grade section of the Lützow-Holm Complex, part of the Gondwana-assembling collisional orogen in East Antarctica. The locality is dominated by felsic to intermediate orthogneiss (charnockite and minor biotite gneiss, mafic orthogneiss, and hornblende-pyroxene granulite, with deformed and undeformed dykes of metagranite and felsic pegmatite. Pseudosection analysis of charnockite in the system NCKFMASHTO, supported by geothermometry of mafic orthogneiss, was used to infer peak metamorphic temperatures of 750–850 °C, approximately 150 °C lower than those estimated for metasedimentary gneisses from Rundvågshetta, 6 km to the northeast. SHRIMP U-Pb analysis of zircons from feldspar-pyroxene gneiss, which corresponds to a partially molten patch around mafic orthogneiss, yielded a Concordia upper intercept ages of 2507.9 ± 7.4 Ma, corresponding to the time of formation of the magmatic protolith to the orthogneiss. Partial melting during peak metamorphism probably took place between 591 and 548 Ma, as recorded in rims overgrew around magmatic zircon. Our results suggest that Rundvågshetta-Vesleknausen-Strandnibba region in southwestern Lützow-Holm Bay, where orthogneisses are dominant, consists of a single crustal block, possibly formed by ca. 2.5 Ga arc magmatism. The Neoarchean magmatic terrane was tectonically mingled with other fragments (such as metasedimentary units in northern Lützow-Holm Bay by subduction/collision events during the assembly of Gondwana supercontinent, and subsequently underwent ∼850 °C granulite-facies metamorphosed during Neoproterozoic to Cambrian final collisional event.

  13. Possible origin and significance of extension-parallel drainages in Arizona's metamophic core complexes (United States)

    Spencer, J.E.


    The corrugated form of the Harcuvar, South Mountains, and Catalina metamorphic core complexes in Arizona reflects the shape of the middle Tertiary extensional detachment fault that projects over each complex. Corrugation axes are approximately parallel to the fault-displacement direction and to the footwall mylonitic lineation. The core complexes are locally incised by enigmatic, linear drainages that parallel corrugation axes and the inferred extension direction and are especially conspicuous on the crests of antiformal corrugations. These drainages have been attributed to erosional incision on a freshly denuded, planar, inclined fault ramp followed by folding that elevated and preserved some drainages on the crests of rising antiforms. According to this hypothesis, corrugations were produced by folding after subacrial exposure of detachment-fault foot-walls. An alternative hypothesis, proposed here, is as follows. In a setting where preexisting drainages cross an active normal fault, each fault-slip event will cut each drainage into two segments separated by a freshly denuded fault ramp. The upper and lower drainage segments will remain hydraulically linked after each fault-slip event if the drainage in the hanging-wall block is incised, even if the stream is on the flank of an antiformal corrugation and there is a large component of strike-slip fault movement. Maintenance of hydraulic linkage during sequential fault-slip events will guide the lengthening stream down the fault ramp as the ramp is uncovered, and stream incision will form a progressively lengthening, extension-parallel, linear drainage segment. This mechanism for linear drainage genesis is compatible with corrugations as original irregularities of the detachment fault, and does not require folding after early to middle Miocene footwall exhumations. This is desirable because many drainages are incised into nonmylonitic crystalline footwall rocks that were probably not folded under low

  14. Core promoter recognition complex changes accompany liver development


    D’Alessio, Joseph A.; Ng, Raymond; Willenbring, Holger; Tjian, Robert


    Recent studies of several key developmental transitions have brought into question the long held view of the basal transcriptional apparatus as ubiquitous and invariant. In an effort to better understand the role of core promoter recognition and coactivator complex switching in cellular differentiation, we have examined changes in transcription factor IID (TFIID) and cofactor required for Sp1 activation/Mediator during mouse liver development. Here we show that the differentiation of fetal li...

  15. Structural characterization of core-bradavidin in complex with biotin.

    Directory of Open Access Journals (Sweden)

    Nitin Agrawal

    Full Text Available Bradavidin is a tetrameric biotin-binding protein similar to chicken avidin and bacterial streptavidin, and was originally cloned from the nitrogen-fixing bacteria Bradyrhizobium diazoefficiens. We have previously reported the crystal structure of the full-length, wild-type (wt bradavidin with 138 amino acids, where the C-terminal residues Gly129-Lys138 ("Brad-tag" act as an intrinsic ligand (i.e. Gly129-Lys138 bind into the biotin-binding site of an adjacent subunit within the same tetramer and has potential as an affinity tag for biotechnological purposes. Here, the X-ray structure of core-bradavidin lacking the C-terminal residues Gly114-Lys138, and hence missing the Brad-tag, was crystallized in complex with biotin at 1.60 Å resolution [PDB:4BBO]. We also report a homology model of rhodavidin, an avidin-like protein from Rhodopseudomonas palustris, and of an avidin-like protein from Bradyrhizobium sp. Ai1a-2, both of which have the Brad-tag sequence at their C-terminus. Moreover, core-bradavidin V1, an engineered variant of the original core-bradavidin, was also expressed at high levels in E. coli, as well as a double mutant (Cys39Ala and Cys69Ala of core-bradavidin (CC mutant. Our data help us to further engineer the core-bradavidin-Brad-tag pair for biotechnological assays and chemical biology applications, and provide deeper insight into the biotin-binding mode of bradavidin.

  16. Structural characterization of core-bradavidin in complex with biotin. (United States)

    Agrawal, Nitin; Määttä, Juha A E; Kulomaa, Markku S; Hytönen, Vesa P; Johnson, Mark S; Airenne, Tomi T


    Bradavidin is a tetrameric biotin-binding protein similar to chicken avidin and bacterial streptavidin, and was originally cloned from the nitrogen-fixing bacteria Bradyrhizobium diazoefficiens. We have previously reported the crystal structure of the full-length, wild-type (wt) bradavidin with 138 amino acids, where the C-terminal residues Gly129-Lys138 ("Brad-tag") act as an intrinsic ligand (i.e. Gly129-Lys138 bind into the biotin-binding site of an adjacent subunit within the same tetramer) and has potential as an affinity tag for biotechnological purposes. Here, the X-ray structure of core-bradavidin lacking the C-terminal residues Gly114-Lys138, and hence missing the Brad-tag, was crystallized in complex with biotin at 1.60 Å resolution [PDB:4BBO]. We also report a homology model of rhodavidin, an avidin-like protein from Rhodopseudomonas palustris, and of an avidin-like protein from Bradyrhizobium sp. Ai1a-2, both of which have the Brad-tag sequence at their C-terminus. Moreover, core-bradavidin V1, an engineered variant of the original core-bradavidin, was also expressed at high levels in E. coli, as well as a double mutant (Cys39Ala and Cys69Ala) of core-bradavidin (CC mutant). Our data help us to further engineer the core-bradavidin-Brad-tag pair for biotechnological assays and chemical biology applications, and provide deeper insight into the biotin-binding mode of bradavidin.

  17. Structural characterization of core-bradavidin in complex with biotin (United States)

    Agrawal, Nitin; Määttä, Juha A. E.; Kulomaa, Markku S.; Hytönen, Vesa P.; Johnson, Mark S.; Airenne, Tomi T.


    Bradavidin is a tetrameric biotin-binding protein similar to chicken avidin and bacterial streptavidin, and was originally cloned from the nitrogen-fixing bacteria Bradyrhizobium diazoefficiens. We have previously reported the crystal structure of the full-length, wild-type (wt) bradavidin with 138 amino acids, where the C-terminal residues Gly129-Lys138 (“Brad-tag”) act as an intrinsic ligand (i.e. Gly129-Lys138 bind into the biotin-binding site of an adjacent subunit within the same tetramer) and has potential as an affinity tag for biotechnological purposes. Here, the X-ray structure of core-bradavidin lacking the C-terminal residues Gly114-Lys138, and hence missing the Brad-tag, was crystallized in complex with biotin at 1.60 Å resolution [PDB:4BBO]. We also report a homology model of rhodavidin, an avidin-like protein from Rhodopseudomonas palustris, and of an avidin-like protein from Bradyrhizobium sp. Ai1a-2, both of which have the Brad-tag sequence at their C-terminus. Moreover, core-bradavidin V1, an engineered variant of the original core-bradavidin, was also expressed at high levels in E. coli, as well as a double mutant (Cys39Ala and Cys69Ala) of core-bradavidin (CC mutant). Our data help us to further engineer the core-bradavidin–Brad-tag pair for biotechnological assays and chemical biology applications, and provide deeper insight into the biotin-binding mode of bradavidin. PMID:28426764

  18. Late-stage exhumation of metamorphic core complexes and landscape development during orogenic collapse of the North American Cordillera (United States)

    Tokombayev, Askhat

    Renewable portfolio standards prescribe for penetration of high amounts of renewable energy sources (RES) that may change the structure of existing power systems. The load growth and changes in power flow caused by RES integration may result in requirements of new available transmission capabilities and upgrades of existing transmission paths. Construction difficulties of new transmission lines can become a problem in certain locations. The increase of transmission line thermal ratings by reconductoring using High Temperature Low Sag (HTLS) conductors is a comparatively new technology introduced to transmission expansion. A special design permits HTLS conductors to operate at high temperatures (e.g., 200°C), thereby allowing passage of higher current. The higher temperature capability increases the steady state and emergency thermal ratings of the transmission line. The main disadvantage of HTLS technology is high cost. The high cost may place special emphasis on a thorough analysis of cost to benefit of HTLS technology implementation. Increased transmission losses in HTLS conductors due to higher current may be a disadvantage that can reduce the attractiveness of this method. Studies described in this thesis evaluate the expenditures for transmission line reconductoring using HTLS and the consequent benefits obtained from the potential decrease in operating cost for thermally limited transmission systems. Studies performed consider the load growth and penetration of distributed renewable energy sources according to the renewable portfolio standards for power systems. An evaluation of payback period is suggested to assess the cost to benefit ratio of HTLS upgrades. The thesis also considers the probabilistic nature of transmission upgrades. The well-known Chebyshev inequality is discussed with an application to transmission upgrades. The Chebyshev inequality is proposed to calculate minimum payback period obtained from the upgrades of certain transmission lines. The cost to benefit evaluation of HTLS upgrades is performed using a 225 bus equivalent of the 2012 summer peak Arizona portion of the Western Electricity Coordinating Council (WECC).

  19. Shock-induced kelyphite formation in the core of a complex impact crater (United States)

    Deseta, Natalie; Boonsue, Suporn; Gibson, Roger L.; Spray, John G.


    We present a compositional and textural analysis of shock-induced microtextures in garnet porphyroblasts in migmatitic garnet-cordierite-biotite paragneisses from the centre of the Vredefort impact structure, South Africa. Detailed imaging and major element analysis of deformation features in, and adjacent to, the garnet porphyroblasts record a complex, heterogeneous distribution of shock effects at the microscale. As the most competent silicate mineral in the assemblage, with the highest Hugoniot Elastic Limit and a wide pressure-temperature stability field, the porphyroblastic garnet preserves a more diverse shock deformation response compared to minerals such as quartz and feldspar, which underwent more comprehensive shock metamorphism and subsequent annealing. The garnet porphyroblasts display pre-impact fractures that are overprinted by later intra-granular Hertzian and distinctive planar fractures associated with the impact event. Shock-induced strain localization occurred along internal slip planes and defects, including pre-existing fractures and inclusion boundaries in the garnet. Symplectitic (kelyphitic) coronas commonly enclose the garnet porphyroblasts, and inhabit intra-granular fractures. The kelyphite assemblage in fractures with open communication beyond garnet grain boundaries is characterized by orthopyroxene—cordierite—sapphirine. Conversely, the kelyphite assemblage in closed-off intra-granular fractures is highly variable, comprising spatially restricted combinations of a secondary garnet phase with a majoritic component, Al-rich orthopyroxene, sapphirine and cordierite. The impedance contrast between garnet porphyroblasts and their inclusions further facilitated the formation of shock-induced features (Al-rich orthopyroxene coronas). Together, the textural and mineralogical data suggest that these features provide a record of oscillatory shock perturbations initiated under confining pressure beneath the transient crater floor. This

  20. Metamorphism in mesosiderites (United States)

    Delaney, J. S.; Nehru, C. E.; Prinz, M.; Harlow, G. E.

    Previous studies of mesosiderites have identified a metamorphic overprint in these meteorites. However, the effects and implications of this overprint have not yet been explored in detail. The present study documents several important textural and chemical features of the mesosiderites. The components of mesosiderites are examined, taking into account orthopyroxenites, olivine in clasts, mesosiderite mafic clasts, and metal. The characteristics of the silicate matrix of the mesosiderites is explored, and textural and chemical evidence of metamorphism is discussed, giving attention to coronas on olivine clasts, overgrowths on Mg-pyroxene clasts, rims on iron rich pyroxene grains, poikiloblasts of plagioclase, and resorption of clasts. Aspects of redox formation of merrillite are considered along with the causes and the implications of metamorphism. It is found that metamorphism has radically changed the texture of the silicate fraction of the mesosiderites.

  1. The UHP metamorphic Seve Nappe Complex of the Swedish Caledonides - a new occurrence of the microdiamond-bearing gneisses and their exhumation (United States)

    Klonowska, Iwona; Janák, Marian; Majka, Jarosław; ‎ Froitzheim, Nikolaus; Gee, David G.


    The ultra-high pressure metamorphism (UHPM) in the Seve Nappe Complex of the Swedish Caledonides has been recently recognized within several lithologies including gneisses, eclogites and garnet pyroxenites (e.g. Janák et al. 2013, Klonowska et al. 2014a, Majka et al. 2014). Thermodynamic modelling and thermobarometric calculations indicate peak pressure conditions of >3GPa at c. 800-900°C (reaching the diamond stability field) for eclogites and garnet pyroxenites from northern Jämtland (e.g. Klonowska et al. 2014b). In addition to this, the first microdiamonds were found in paragneisses from the Snasahögarna Mt. in central Jämtland (Majka et al. 2014). Here we report a new discovery of microdiamond together with moissanite (SiC) from one of the world's most famous localities for thrusting, Mount Åreskutan, where long transport distances were recognized already in the 19th century (Törnebohm 1888). Garnet porphyroblasts in gneisses from the Åreskutan Mt. contain abundant mineral inclusions, mainly graphite, carbonates and quartz, together with fluid inclusions of CO2 concentrated in swarms. Among these inclusions three microdiamonds were found in two gneiss samples. In one of the samples moissanite was also discovered. Both minerals were identified by micro-Raman spectroscopy. In addition to these 'swarm' inclusions, biotite, kyanite, rutile, feldspars, zircon, monazite, ±phengite, ±muscovite, ±spinel, ±ilmenite, ±apatite occur in garnets. Phase equilibrium modelling for the phengite-bearing gneiss confirms its UHP history at temperatures of c. 800°C. Recent discoveries of UHP metamorphism within the Seve Nappe Complex derived from the Baltican outer margin (part of the Middle Allochthon) challenged us to present a new tectonic model incorporating exhumation of the deeply subducted continental rocks together with mantle lithosphere peridotites. Majka et al. (2014) introduced a new "under-pressure"-driven exhumation mechanism of rocks buried in

  2. A- and I-type metagranites from the North Shahrekord Metamorphic Complex, Iran: Evidence for Early Paleozoic post-collisional magmatism (United States)

    Badr, Afsaneh; Davoudian, Ali Reza; Shabanian, Nahid; Azizi, Hossein; Asahara, Yoshihiro; Neubauer, Franz; Dong, Yunpeng; Yamamoto, Koshi


    The North Shahrekord Metamorphic Complex (NSMC) of the central Sanandaj-Sirjan Zone (SaSZ) consists of metagranitoid bodies, which were metamorphosed within high pressure-low temperature conditions. Whole rock chemistry shows relatively high amounts of SiO2 (65-77 wt%) and Al2O3 (12-15 wt%), low amounts of Nb, P, Sr, Ti, a high ratio of Ga/Al (4-9) and a negative Eu anomaly. The chemical compositions of metagranites are reasonably similar to A- and I-type granites. U-Pb zircon ages of three samples of metagranites indicate that crystallization of the granites occurred at 521.6 ± 9.1 to 513.5 ± 8.5 Ma, Middle Cambrian. The initial 87Sr/86Sr and 143Nd/144Nd ratios of samples vary from 0.7057-0.7239 and 0.511801-0.511890, respectively. High initial 87Sr/86Sr ratios and low εNd(t) values (- 3.39 to - 1.07) associated with high ratios of 206Pb/204Pb(t) = 17.8557-18.8045, 207Pb/204Pb(t) = 15.6721-15.7220, and 208Pb/204Pb(t) = 37.7490-38.4468 infer a significant contribution of continental crust in generating the source magma of the metagranite bodies. The results reveal that the metagranites were mainly produced through mixing of basaltic melts with components similar to metasedimentary sources. The new results show that crystallization of the metagranites occurred in Early Paleozoic times and much earlier than break-up and drifting of the SaSZ from the Arabian plate, suggesting that the metagranites were mainly produced in the western Iran after the closure of the Proto-Tethys Ocean. This model is consistent with the previously suggested models for formation of an Early Paleozoic granitoid belt along the northern rim of Gondwana.

  3. Ultrafast energy transfer within the photosystem II core complex. (United States)

    Pan, Jie; Gelzinis, Andrius; Chorošajev, Vladimir; Vengris, Mikas; Senlik, S Seckin; Shen, Jian-Ren; Valkunas, Leonas; Abramavicius, Darius; Ogilvie, Jennifer P


    We report 2D electronic spectroscopy on the photosystem II core complex (PSII CC) at 77 K under different polarization conditions. A global analysis of the high time-resolution 2D data shows rapid, sub-100 fs energy transfer within the PSII CC. It also reveals the 2D spectral signatures of slower energy equilibration processes occurring on several to hundreds of picosecond time scales that are consistent with previous work. Using a recent structure-based model of the PSII CC [Y. Shibata, S. Nishi, K. Kawakami, J. R. Shen and T. Renger, J. Am. Chem. Soc., 2013, 135, 6903], we simulate the energy transfer in the PSII CC by calculating auxiliary time-resolved fluorescence spectra. We obtain the observed sub-100 fs evolution, even though the calculated electronic energy shows almost no dynamics at early times. On the other hand, the electronic-vibrational interaction energy increases considerably over the same time period. We conclude that interactions with vibrational degrees of freedom not only induce population transfer between the excitonic states in the PSII CC, but also reshape the energy landscape of the system. We suggest that the experimentally observed ultrafast energy transfer is a signature of excitonic-polaron formation.

  4. Fluids in metamorphic rocks

    NARCIS (Netherlands)

    Touret, J.L.R.


    Basic principles for the study of fluid inclusions in metamorphic rocks are reviewed and illustrated. A major problem relates to the number of inclusions, possibly formed on a wide range of P-T conditions, having also suffered, in most cases, extensive changes after initial trapping. The

  5. Eocene and Miocene extension, meteoric fluid infiltration, and core complex formation in the Great Basin (Raft River Mountains, Utah) (United States)

    Methner, Katharina; Mulch, Andreas; Teyssier, Christian; Wells, Michael L.; Cosca, Michael A.; Gottardi, Raphael; Gebelin, Aude; Chamberlain, C. Page


    Metamorphic core complexes (MCCs) in the North American Cordillera reflect the effects of lithospheric extension and contribute to crustal adjustments both during and after a protracted subduction history along the Pacific plate margin. While the Miocene-to-recent history of most MCCs in the Great Basin, including the Raft River-Albion-Grouse Creek MCC, is well documented, early Cenozoic tectonic fabrics are commonly severely overprinted. We present stable isotope, geochronological (40Ar/39Ar), and microstructural data from the Raft River detachment shear zone. Hydrogen isotope ratios of syntectonic white mica (δ2Hms) from mylonitic quartzite within the shear zone are very low (−90‰ to −154‰, Vienna SMOW) and result from multiphase synkinematic interaction with surface-derived fluids. 40Ar/39Ar geochronology reveals Eocene (re)crystallization of white mica with δ2Hms ≥ −154‰ in quartzite mylonite of the western segment of the detachment system. These δ2Hms values are distinctively lower than in localities farther east (δ2Hms ≥ −125‰), where 40Ar/39Ar geochronological data indicate Miocene (18–15 Ma) extensional shearing and mylonitic fabric formation. These data indicate that very low δ2H surface-derived fluids penetrated the brittle-ductile transition as early as the mid-Eocene during a first phase of exhumation along a detachment rooted to the east. In the eastern part of the core complex, prominent top-to-the-east ductile shearing, mid-Miocene 40Ar/39Ar ages, and higher δ2H values of recrystallized white mica, indicate Miocene structural and isotopic overprinting of Eocene fabrics.

  6. Development and application of laser microprobe techniques for oxygen isotope analysis of silicates, and, fluid/rock interaction during and after granulite-facies metamorphism, highland southwestern complex, Sri Lanka

    Energy Technology Data Exchange (ETDEWEB)

    Elsenheimer, D.W.


    The extent of fluid/rock interaction within the crust is a function of crustal depth, with large hydrothermal systems common in the brittle, hydrostatically pressured upper crust, but restricted fluid flow in the lithostatically pressured lower crust. To quantify this fluid/rock interaction, a Nd-YAG/CO[sub 2] laser microprobe system was constructed to analyze oxygen isotope ratios in silicates. Developed protocols produce high precision in [sigma][sup 18]O ([+-]0.2, 1[sigma]) and accuracy comparable to conventional extraction techniques on samples of feldspar and quartz as small as 0.3mg. Analysis of sub-millimeter domains in quartz and feldspar in granite from the Isle of Skye, Scotland, reveals complex intragranular zonation. Contrasting heterogeneous and homogeneous [sigma][sup 18]O zonation patterns are revealed in samples <10m apart. These differences suggest fluid flow and isotopic exchange was highly heterogeneous. It has been proposed that granulite-facies metamorphism in the Highland Southwestern Complex (HSWC), Sri Lanka, resulted from the pervasive influx of CO[sub 2], with the marbles and calc-silicates within the HSWC a proposed fluid source. The petrologic and stable isotopic characteristic of HSWC marbles are inconsistent with extensive decarbonation. Wollastonite calc-silicates occur as deformed bands and as post-metamorphis veins with isotopic compositions that suggest vein fluids that are at least in part magmatic. Post-metamorphic magmatic activity is responsible for the formation of secondary disseminated graphite growth in the HSWC. This graphite has magmatic isotopic compositions and is associated with vein graphite and amphibolite-granulite facies transitions zones. Similar features in Kerela Khondalite Belt, South India, may suggest a common metamorphic history for the two terranes.

  7. Functional and structural analysis of photosystem II core complexes from spinach with high oxygen evolution capacity

    NARCIS (Netherlands)

    Haag, Elisabeth; Irrgang, Klaus-D.; Boekema, Egbert J.; Renger, Gernot


    Oxygen-evolving photo system II core complexes were prepared from spinach by solubilizing photosystem II membrane fragments with dodecyl-β-D-maltoside. The core complexes consist of the intrinsic 47-kDa, 43-kDa, D1 and D2 polypeptides, the two subunits of cytochrome b559 and the extrinsic 33-kDa

  8. Zircon U-Pb geochronology, geochemistry and Sr-Nd-Pb isotopes from the metamorphic basement in the Wuhe Complex: Implications for Neoarchean active continental margin along the southeastern North China Craton and constraints on the petrogenesis of Mesozoic granitoids

    Directory of Open Access Journals (Sweden)

    Andong Wang


    Full Text Available We report zircon U-Pb geochronology, geochemistry and Sr-Nd-Pb isotope data from mafic granulites and garnet amphibolites of the Wuhe Complex in the southeastern margin of the North China Craton (NCC. In combination with previous data, our results demonstrate that these rocks represent fragments of the ancient lower crust, and have features similar to those of the granulite basement in the northern margin of the NCC. A detailed evaluation of the Pb isotope data shows that Pb isotopes cannot effectively distinguish the role of the Yangtze Craton basement from that of the NCC basement with regard to the source and generation of magmas, at least for southeastern NCC. The age data suggest that the protoliths of the granulites or amphibolites in the Wuhe Complex were most likely generated in Neoarchean and that these rocks were subjected to Paleoproterozoic (1.8–1.9 Ga high-pressure granulite facies metamorphism. This study also shows that the Precambrian metamorphic basement in the southeastern margin of the NCC might have formed in a tectonic setting characterized by a late Neoarchean active continental margin.

  9. Metamorphic Testing for Cybersecurity. (United States)

    Chen, Tsong Yueh; Kuo, Fei-Ching; Ma, Wenjuan; Susilo, Willy; Towey, Dave; Voas, Jeffrey; Zhou, Zhi Quan


    Testing is a major approach for the detection of software defects, including vulnerabilities in security features. This article introduces metamorphic testing (MT), a relatively new testing method, and discusses how the new perspective of MT can help to conduct negative testing as well as to alleviate the oracle problem in the testing of security-related functionality and behavior. As demonstrated by the effectiveness of MT in detecting previously unknown bugs in real-world critical applications such as compilers and code obfuscators, we conclude that software testing of security-related features should be conducted from diverse perspectives in order to achieve greater cybersecurity.

  10. First evidence of high-pressure metamorphism in the ''Cover Series'' of the southern Menderes Massif. Tectonic and metamorphic implications for the evolution of SW Turkey (United States)

    Rimmelé, Gaëtan; Oberhänsli, Roland; Goffé, Bruno; Jolivet, Laurent; Candan, Osman; Çetinkaplan, Mete


    The Menderes Massif occupies a large part of western Turkey. It is tectonically overlain by nappes of the Izmir-Ankara Suture Zone (including the Bornova Flysch Zone) on its northern flank, the Afyon Zone on its eastern border, and the Lycian Nappes on its southern flank. The discovery of magnesiocarpholite-kyanite assemblages in the Mesozoic 'cover' sequence of the southern Menderes Massif leads to the very first consideration that a major high-pressure (HP) metamorphic event affected the massif during its Alpine evolution. Estimations of minimum pressure-temperature conditions about 10-12 kbar and 440 °C suggest a minimum burial of 30 km for the metasedimentary rocks of the Menderes Massif, similar to that for the Eocene Dilek Blueschists, which belong to the Cycladic complex. This finding of high-pressure rocks within the Menderes 'cover' series, as well as the recent description of low-grade high-pressure parageneses in the basal thrust sheets of the overlying Lycian nappe complex, has strong implications for the tectono-metamorphic evolution of these units. The characteristics of this high-pressure metamorphism and the deformation features observed in the southern Menderes Massif allow consideration of a fast burial during Alpine subduction and nappe stacking. Three high-pressure units were piled up during the Eocene collision of the Sakarya continent and the Tauride-Menderes block. The lowermost unit consists of the imbricated 'core' and 'cover' of the Menderes Massif. The intermediate unit is the Cycladic Blueschist complex (Dilek and Samos regions) and the uppermost unit is made of the Lycian Nappes. The retrogression of high-pressure parageneses from the Menderes Massif follows an isothermal decompression path and the associated deformation is characterized by a severe stretching oriented N-S to NE-SW during the high-pressure event and its exhumation. We propose a tectono-metamorphic model in three main stages: (1) the southward translation of the high

  11. Architecture of the human mTORC2 core complex. (United States)

    Stuttfeld, Edward; Aylett, Christopher Hs; Imseng, Stefan; Boehringer, Daniel; Scaiola, Alain; Sauer, Evelyn; Hall, Michael N; Maier, Timm; Ban, Nenad


    The mammalian target of rapamycin (mTOR) is a key protein kinase controlling cellular metabolism and growth. It is part of the two structurally and functionally distinct multiprotein complexes mTORC1 and mTORC2. Dysregulation of mTOR occurs in diabetes, cancer and neurological disease. We report the architecture of human mTORC2 at intermediate resolution, revealing a conserved binding site for accessory proteins on mTOR and explaining the structural basis for the rapamycin insensitivity of the complex. © 2018, Stuttfeld et al.

  12. The roles of heritage vs thermal state of the lithosphere in the localization of detachment zones : insights from Mediterranean Core Complexes and numerical experiments. (United States)

    Labrousse, L.; Huet, B.; Le Pourhiet, L.; Burov, E.; Jolivet, L.


    The most enigmatic features of metamorphic core complexes (MCC) refer to localized shallow dipping normal detachment shear zones, and preservation of almost flat Moho below the extended crust. Since the seminal work of R. Buck (1991), it is accepted that MCC form during extension of thermally relaxed hot, hence rheologically weak continental lithosphere. Initial Moho temperatures higher than 800°C are indeed predicted by many numerical models, and migmatites found in MCC cores also imply high temperature for the exhumed lower crust. A systematic review of tectonostratigraphies of the described-so-far Mediterranean MCCs shows that the detachment zones did not all develop on top of high-temperature metamorphic domes but some of them formed under much colder thermal conditions. This diversity can be described within a multi-parameter (P,T, strength) domain bound by 3 end-member cases: (1) high temperature core end-member (HT-MCC), representing most studied MCCs, and two cold end-member cases, one defined by (2) localization of crustal detachment in or on top of a preserved metasedimentary high-pressure metamorphic unit (HP-MCC), and (3) another one where the detachment is localized at the base of a high-strength upper unit, such as an obducted mafic sequence (HSU-MCC). Natural cases scatter within this triangular system, with pure HT-MCC cases (such as the Kabylian detachment, Algeria), pure HP-MCC cases (such as the Filabres detachment in the Betics, Spain), while HSU tectonostratigraphy is always coeval with a high-temperature core (eg Nigde, Anatolia) or a high-pressure nappe (in Corsica for instance). The largest core-complex systems, such as Menderes (Turkey), Rhodope (Greece and Bulgaria), and Cyclades (Greece), relate to the three end-member cases. We run thermo-mechanically coupled numerical models of extension of multi-layered lithosphere. In these models we primarily varied the rheological strength of crustal layers and initial thermal conditions to explore

  13. Interplay between water infiltration, metamorphic reactions and strain localization during subduction of gabbro from the basement rocks of the Lofoten anorthosite complex (United States)

    Nasipuri, P.; Stunitz, H.; Menegon, L.; Berger, A.


    Eclogitization of lower crustal rocks occurs during subduction processes. During the prograde segment of subduction cycle and subsequent exhumation, ranges of mineral assemblages are produced under different P-T conditions. In this contribution, we describe the role of water and formation of syn-kinematic mineral assemblages in the ductile shear zone within leucogabbro and in the retrograde equivalent (characterized by alternate bands of mafic and felsic layers) that are separated by a distance of 100-150 meter. In the undeformed gabbro, Plagioclase (Pl0), olivine (Ol0) and orthopyroxene (Opx0) form the igneous texture. The onset of metamorphism (M1, 700 0C, 1GPa) during subduction processes is indicated by growth of metamorphic Opx1 and Grt1 corona around Pl0 and Ol0. Cm- wide alternating bands of a mixture of Pl-amphibole (Amph) ± Spl and GrtI(M1) - Opx -Omph - Grt II (M2A, 650-750 0C, > 1.8 GPa) phase mixtures characterize shear zones. Omph overgrow deformed Opx grains (D1). Clinopyroxene (Cpx) -Pl symplectite (M2B, 600-650 0C, 1 GPa) occur at the outer rim the Omph. Breakdown of Grt I/IIto Amph ± Pl (An rich) ± Spl with increased water activity form during M3 metamorphism. In the retrograde eclogite, the mafic layer is composed of Cpx, sodic Pl and Qtz (grain size 50 μm). Coarse-grained calcic Pl (grain size 50-75 μm) forms the felsic layer. Grt porphyrolcast (eq. Grt I/II) with inclusions of Pl and Qtz occur within the mafic layer. A thin layer of amphibole and clinozoisite layer overgrows at the contact between the mafic and felsic layer (6000C, 0.6-0.8 GPa). In the ductile shear zone, crystallographic data of recrystallized Opx0 (grain size 20-30 μm) and the relict Opx0, chemical similarity and the grain size reduction indicate that Opx deformed by at the onset of subduction. The deformed Opx grains show sinistral sense of shear. Although, the fine-grained Pl is expected to show random CPO characteristics of diffusion creep, the strong CPO of Pl is

  14. Paleomagnetism of the Upper Proterozoic and Devonian rocks from the Kłodzko Metamorphic Complex in the West Sudetes (SW Poland): tectonic implications for the Variscan belt of Central Europe (United States)

    Kądziałko-Hofmokl, Magdalena; Kruczyk, Jadwiga; Mazur, Stanisław; Siemiątkowski, Jacek


    The Kłodzko Metamorphic Complex (KMC) consists of Upper Proterozoic metaigneous and metasedimentary rocks forming a stack pile thrusted over the Givetian and overlain by Frasnian-Fammenian sediments. Magnetomineralogical experiments show that the magnetic minerals are secondary. The paleomagnetic experiments identified three components of the Natural Remanent Magnetization; labeled A1, A2 and M. The mean pole positions calculated in situ correspond with the Baltica Upper Devonian (A1: PlatS=-18°, PlongE=317°), Permo-Carboniferous (A2: PlatS=-39°, PlongE=2°) and Triassic-Jurassic (M: PlatS=-60°C, PlongE=308°) segments of the Apparent Polar Wander Path (APWP) for Baltica. This indicates that the region studied was situated close to the Baltica plate at least since the Upper Devonian and was not folded after this period.

  15. Information and Symmetry: Adumbrating the Abstract Core of Complex Systems

    Directory of Open Access Journals (Sweden)

    Lin Bi


    Full Text Available Information and symmetry are essential theoretical concepts that underlie the scientific explanation of a variety of complex systems. In spite of clear-cut developments around both concepts, their intersection is really problematic, either in fields related to mathematics, physics, and chemistry, or even more in those pertaining to biology, neurosciences, and social sciences. The present Special Issue explores recent developments, both theoretical and applied, in most of these disciplines.

  16. Trauma, innocence and the core complex of dissociation. (United States)

    Kalsched, Donald E


    Trauma survivors often lament that they have lost their innocence or lost their souls and that something vulnerable and whole about themselves has been 'broken' or annihilated. Yet when the psychotherapeutic relationship begins, and symbolic material from dreams and the transference emerges, discernible patterns become apparent, indicating that a core of innocence and vitality has not been totally lost or annihilated. On the contrary, it has been 'saved' by dissociation and its system of inner objects and their protective and/or persecutory narrative 'scripts' or 'schemas'. The dissociative system splits off a wounded, orphaned 'child' in the psyche and clinging to this 'child' is a penumbra of innocence that apparently must be preserved at all costs. Unfortunately the costs of preservation are high because such encapsulated innocence becomes malignant, and the inner world turns perverse and destructive. Only when the wounded, orphaned, and innocent part of the personality is allowed to suffer experience again - this time with the promise of a new outcome - can true healing of trauma occur. How to facilitate this authentic suffering in the face of powerful resistances thrown up by the 'system', will be the focus of this paper. © 2017, The Society of Analytical Psychology.

  17. P-T-t conditions, Nd and Pb isotopic compositions and detrital zircon geochronology of the Massabesic Gneiss Complex, New Hampshire: isotopic and metamorphic evidence for the identification of Gander basement, central New England (United States)

    Dorais, Michael J.; Wintsch, Robert P.; Kunk, Michael J.; Aleinikoff, John; Burton, William; Underdown, Christine; Kerwin, Charles M.


    We present new evidence for the assignment of the Neoproterozoic Massabesic Gneiss Complex of New Hampshire to the Gander terrane rather than the Avalon terrane. The majority of Avalonian (sensu stricto) igneous and meta-igneous rocks as defined in Maritime Canada have positive whole-rock ɛNd compared to more negative values for Gander rocks, although there is a region of overlap in ɛNd between the two terranes. Our samples from areas in Connecticut previously thought to be Avalonian and samples from the Willimantic dome have the same isotopic signatures as Maritime Canada Avalon. In contrast, samples from the Clinton dome of southern Connecticut plots exclusively in the Gander field. The majority of the orthogneiss samples from Lyme dome (coastal Connecticut), Pelham dome (central Massachusetts) and Massabesic Gneiss Complex also plot in the Gander field, with a few samples plotting in the overlap zone between Gander and Avalon. U-Pb age distributions of detrital zircon populations from quartzites from the Massabesic Gneiss Complex more closely approximate the data from the Lyme Dome rather than Avalon. Additionally, the similarity of the P-T-t path for the rocks of the Massabesic Gneiss Complex (established by thermobarometry and 40Ar/39Ar dating of amphibole, muscovite, biotite and K-feldspar) with that established in the Ganderian Lyme dome of southern Connecticut strengthens the assignment of these rocks to a single Gander block that docked to Laurentia during the Salinic Orogeny. The identification of Ganderian isotopic signatures for these rocks all of which show evidence for Alleghanian metamorphism, supports the hypothesis that Neoproterozoic Gander lower crustal rocks underlie southern New Hampshire, Massachusetts, and Connecticut, and that all rocks of the overlying Central Maine trough that largely escaped high-grade Alleghanian metamorphism are allochthonous. We suggest that during the Alleghanian, the docking of Gondwana caused Avalon to wedge into

  18. Oligomerization state of photosynthetic core complexes is correlated with the dimerization affinity of a transmembrane helix. (United States)

    Hsin, Jen; LaPointe, Loren M; Kazy, Alla; Chipot, Christophe; Senes, Alessandro; Schulten, Klaus


    In the Rhodobacter (Rba.) species of photosynthetic purple bacteria, a single transmembrane α-helix, PufX, is found within the core complex, an essential photosynthetic macromolecular assembly that performs the absorption and the initial processing of light energy. Despite its structural simplicity, many unresolved questions surround PufX, the most important of which is its location within the photosynthetic core complex. One proposed placement of PufX is at the center of a core complex dimer, where two PufX helices associate in the membrane and form a homodimer. Inability for PufX of certain Rba. species to form a homodimer is thought to lead to monomeric core complexes. In the present study, we employ a combination of computational and experimental techniques to test the hypothesized homodimerization of PufX. We carry out a systematic investigation to measure the dimerization affinity of PufX from four Rba. species, Rba. blasticus , Rba. capsulatus , Rba. sphaeroides , and Rba. veldkampii , using a molecular dynamics-based free-energy method, as well as experimental TOXCAT assays. We found that the four PufX helices have substantially different dimerization affinities. Both computational and experimental techniques demonstrate that species with dimeric core complexes have PufX that can potentially form a homodimer, whereas the one species with monomeric core complexes has a PufX with little to no dimerization propensity. Our analysis of the helix-helix interface revealed a number of positions that may be important for PufX dimerization and the formation of a hydrogen-bond network between these GxxxG-containing helices. Our results suggest that the different oligomerization states of core complexes in various Rba. species can be attributed, among other factors, to the different propensity of its PufX helix to homodimerize.

  19. Distribution of Complex and Core Lipids within New Hyperthermophilic Members of the Archaea Domain


    Trincone, A.; Nicolaus, B.; Palmieri, G.; de Rosa, M.; Huber, Robert; Huber, Gertrud; Stetter, Karl Otto; Gambacorta, A.


    Core and complex lipids of several new hyperthermophilic archaeal isolates were analyzed. The organisms belong to the Sulfolobales,Archaeoglobus, Pyrobaculum, and Methanococcus. A detailed structural investigation of complex lipids of Pyrobaculum species is reported. The different lipid structures are of help for a rapid and simple phylogenetic classification of the new isolates. They are in agreement with the classification based on other features.

  20. The Lost South Gobi Microcontinent: Protolith Studies of Metamorphic Tectonites and Implications for the Evolution of Continental Crust in Southeastern Mongolia

    Directory of Open Access Journals (Sweden)

    Matthew J. Heumann


    Full Text Available The Central Asian Orogenic Belt, or Altaids, is an amalgamation of volcanic arcs and microcontinent blocks that records a complex late Precambrian–Mesozoic accretionary history. Although microcontinents cored by Precambrian basement are proposed to play an integral role in the accretion process, a lack of isotopic data hampers volume estimates of newly produced arc-derived versus old-cratonic crust in southeastern Mongolia. This study investigates metamorphic tectonites in southern Mongolia that have been mapped as Precambrian in age, largely on the basis of their high metamorphic grade and high strain. Here we present results from microstructural analyses and U-Pb zircon geochronology on samples from Tavan Har (44.05° N, 109.55° E and the Yagan-Onch Hayrhan metamorphic core complex (41.89° N, 104.24° E. Our results show no compelling evidence for Precambrian basement in southeastern Mongolia. Rather, the protoliths to all tectonites examined are Paleozoic–Mesozoic age rocks, formed during Devonian–Carboniferous arc magmatism and subsequent Permian–Triassic orogenesis during collision of the South Mongolia arc with the northern margin of China. These results yield important insights into the Paleozoic accretionary history of southern Mongolia, including the genesis of metamorphic and igneous basement during the Paleozoic, as well as implications for subsequent intracontinental reactivation.

  1. Containment and Support: Core and Complexity in Spatial Language Learning. (United States)

    Landau, Barbara; Johannes, Kristen; Skordos, Dimitrios; Papafragou, Anna


    Containment and support have traditionally been assumed to represent universal conceptual foundations for spatial terms. This assumption can be challenged, however: English in and on are applied across a surprisingly broad range of exemplars, and comparable terms in other languages show significant variation in their application. We propose that the broad domains of both containment and support have internal structure that reflects different subtypes, that this structure is reflected in basic spatial term usage across languages, and that it constrains children's spatial term learning. Using a newly developed battery, we asked how adults and 4-year-old children speaking English or Greek distribute basic spatial terms across subtypes of containment and support. We found that containment showed similar distributions of basic terms across subtypes among all groups while support showed such similarity only among adults, with striking differences between children learning English versus Greek. We conclude that the two domains differ considerably in the learning problems they present, and that learning in and on is remarkably complex. Together, our results point to the need for a more nuanced view of spatial term learning. Copyright © 2016 Cognitive Science Society, Inc.

  2. Identifying protein complex by integrating characteristic of core-attachment into dynamic PPI network.

    Directory of Open Access Journals (Sweden)

    Xianjun Shen

    Full Text Available How to identify protein complex is an important and challenging task in proteomics. It would make great contribution to our knowledge of molecular mechanism in cell life activities. However, the inherent organization and dynamic characteristic of cell system have rarely been incorporated into the existing algorithms for detecting protein complexes because of the limitation of protein-protein interaction (PPI data produced by high throughput techniques. The availability of time course gene expression profile enables us to uncover the dynamics of molecular networks and improve the detection of protein complexes. In order to achieve this goal, this paper proposes a novel algorithm DCA (Dynamic Core-Attachment. It detects protein-complex core comprising of continually expressed and highly connected proteins in dynamic PPI network, and then the protein complex is formed by including the attachments with high adhesion into the core. The integration of core-attachment feature into the dynamic PPI network is responsible for the superiority of our algorithm. DCA has been applied on two different yeast dynamic PPI networks and the experimental results show that it performs significantly better than the state-of-the-art techniques in terms of prediction accuracy, hF-measure and statistical significance in biology. In addition, the identified complexes with strong biological significance provide potential candidate complexes for biologists to validate.

  3. Discovery of protein complexes with core-attachment structures from Tandem Affinity Purification (TAP) data. (United States)

    Wu, Min; Li, Xiao-Li; Kwoh, Chee-Keong; Ng, See-Kiong; Wong, Limsoon


    Many cellular functions involve protein complexes that are formed by multiple interacting proteins. Tandem Affinity Purification (TAP) is a popular experimental method for detecting such multi-protein interactions. However, current computational methods that predict protein complexes from TAP data require converting the co-complex relationships in TAP data into binary interactions. The resulting pairwise protein-protein interaction (PPI) network is then mined for densely connected regions that are identified as putative protein complexes. Converting the TAP data into PPI data not only introduces errors but also loses useful information about the underlying multi-protein relationships that can be exploited to detect the internal organization (i.e., core-attachment structures) of protein complexes. In this article, we propose a method called CACHET that detects protein complexes with Core-AttaCHment structures directly from bipartitETAP data. CACHET models the TAP data as a bipartite graph in which the two vertex sets are the baits and the preys, respectively. The edges between the two vertex sets represent bait-prey relationships. CACHET first focuses on detecting high-quality protein-complex cores from the bipartite graph. To minimize the effects of false positive interactions, the bait-prey relationships are indexed with reliability scores. Only non-redundant, reliable bicliques computed from the TAP bipartite graph are regarded as protein-complex cores. CACHET constructs protein complexes by including attachment proteins into the cores. We applied CACHET on large-scale TAP datasets and found that CACHET outperformed existing methods in terms of prediction accuracy (i.e., F-measure and functional homogeneity of predicted complexes). In addition, the protein complexes predicted by CACHET are equipped with core-attachment structures that provide useful biological insights into the inherent functional organization of protein complexes. Our supplementary material can

  4. Fanconi anemia core complex-dependent HES1 mono-ubiquitination regulates its transcriptional activity. (United States)

    Tremblay, Cédric S; Huang, Feng Fei; Lévesque, Georges; Carreau, Madeleine


    The Hairy Enhancer of Split 1 (HES1) is a transcriptional repressor that regulates cellular proliferation and differentiation during development. We previously found an interaction between HES1 and Fanconi anemia (FA) proteins. FA is a hematological and developmental disorder caused by mutations in more than 20 different genes. Eight FA gene products form a nuclear core complex containing E3 ligase activity required for mono-ubiquitination of FANCD2 and FANCI, both of which are FA proteins. Given that HES1 interacts with members of the FA core complex, the aim of this study was to determine whether HES1 is mono-ubiquitinated via the FA core complex. We show that HES1 is mono-ubiquitinated on a highly-conserved lysine residue that is located within a FA-like recognition motif. HES1 modification is dependent on a functional FA complex. Absence of HES1 mono-ubiquitination affects transcriptional repression of its own promoter. This study uncovers a novel post-translational modification of HES1 that regulates its transcriptional activity and suggests that ubiquitination of HES1 occurs in a FA core complex-dependent manner.

  5. Identification of Protein Complexes Using Weighted PageRank-Nibble Algorithm and Core-Attachment Structure. (United States)

    Peng, Wei; Wang, Jianxin; Zhao, Bihai; Wang, Lusheng


    Protein complexes play a significant role in understanding the underlying mechanism of most cellular functions. Recently, many researchers have explored computational methods to identify protein complexes from protein-protein interaction (PPI) networks. One group of researchers focus on detecting local dense subgraphs which correspond to protein complexes by considering local neighbors. The drawback of this kind of approach is that the global information of the networks is ignored. Some methods such as Markov Clustering algorithm (MCL), PageRank-Nibble are proposed to find protein complexes based on random walk technique which can exploit the global structure of networks. However, these methods ignore the inherent core-attachment structure of protein complexes and treat adjacent node equally. In this paper, we design a weighted PageRank-Nibble algorithm which assigns each adjacent node with different probability, and propose a novel method named WPNCA to detect protein complex from PPI networks by using weighted PageRank-Nibble algorithm and core-attachment structure. Firstly, WPNCA partitions the PPI networks into multiple dense clusters by using weighted PageRank-Nibble algorithm. Then the cores of these clusters are detected and the rest of proteins in the clusters will be selected as attachments to form the final predicted protein complexes. The experiments on yeast data show that WPNCA outperforms the existing methods in terms of both accuracy and p-value. The software for WPNCA is available at "".

  6. Garnet peridotites from Pohorje: Petrography, geothermobarometry and metamorphic evolution

    Directory of Open Access Journals (Sweden)

    Mirijam Vrabec


    Full Text Available Ultrahigh-pressure (UHP metamorphism has been recorded in Eo-Alpine garnet peridotites from the PohorjeMts., Slovenia, belonging to the Eastern Alps. The garnet peridotite bodies are found within serpentinized metaultrabasitesin the SE edge of Pohorje and are closely associated with UHP kyanite eclogites. These rocks belongto the Lower Central Austroalpine basement unit of the Eastern Alps, exposed in the proximity of the Periadriaticfault system.Garnet peridotites show signs of a complex four-stage metamorphic history. The protolith stage is represented bya low-P high-T assemblage of olivine + Al-rich orthopyroxene + Al-rich clinopyroxene + Cr-spinel. Due to metamorphism,primary clinopyroxene shows exsolutions of garnet, orthopyroxene, amphibole, Cr-spinel and ilmenite. TheUHP metamorphic stage is defined by the assemblage garnet + olivine + Al-poor orthopyroxene + clinopyroxene +Cr-spinel. Subsequent decompression and final retrogression stage resulted in formation of kelyphitic rims aroundgarnet and crystallization of tremolite, chlorite, serpentine and talc.Pressure and temperature estimates indicate that garnet peridotites reached the peak of metamorphism at 4 GPaand 900 °C, that is well within the UHP stability field. Garnet peridotites in the Pohorje Mountains experiencedUHP metamorphism during the Cretaceous orogeny and thus record the highest-pressure conditions of all Eo-Alpinemetamorphism in the Alps.

  7. North Aegean core complexes, the gravity spreading of a thrust wedge

    NARCIS (Netherlands)

    Kydonakis, Konstantinos; Brun, Jean Pierre; Sokoutis, Dimitrios


    The North Aegean core complexes developed in middle Eocene soon after the end of continental block convergence and piling up of the Hellenic Thrust Wedge. They formed during back-arc extension, driven by the Hellenic slab rollback, at the back of the thrust wedge. A series of scaled laboratory

  8. Core Self-Evaluations as Causes of Satisfaction: The Mediating Role of Seeking Task Complexity (United States)

    Srivastava, Abhishek; Locke, Edwin A.; Judge, Timothy A.; Adams, John W.


    This study examined the mediating role of task complexity in the relationship between core self-evaluations (CSE) and satisfaction. In Study 1, eighty three undergraduate business students worked on a strategic decision-making simulation. The simulated environment enabled us to verify the temporal sequence of variables, use an objective measure of…

  9. Neoproterozoic igneous complex emplaced along major tectonic boundary in the Kaoko Belt (NW Namibia): ion probe and LA-ICP-MS dating of magmatic and metamorphic zircons

    Czech Academy of Sciences Publication Activity Database

    Konopásek, J.; Košler, J.; Tajčmanová, L.; Ulrich, Stanislav; Kitt, S. L.


    Roč. 165, č. 1 (2008), s. 153-166 ISSN 0016-7649 Institutional research plan: CEZ:AV0Z30120515 Keywords : boundary igneous complex * Kaoko Belt * zircon Subject RIV: DB - Geology ; Mineralogy Impact factor: 2.797, year: 2008

  10. Cryo-EM Structure of the TOM Core Complex from Neurospora crassa. (United States)

    Bausewein, Thomas; Mills, Deryck J; Langer, Julian D; Nitschke, Beate; Nussberger, Stephan; Kühlbrandt, Werner


    The TOM complex is the main entry gate for protein precursors from the cytosol into mitochondria. We have determined the structure of the TOM core complex by cryoelectron microscopy (cryo-EM). The complex is a 148 kDa symmetrical dimer of ten membrane protein subunits that create a shallow funnel on the cytoplasmic membrane surface. In the core of the dimer, the β-barrels of the Tom40 pore form two identical preprotein conduits. Each Tom40 pore is surrounded by the transmembrane segments of the α-helical subunits Tom5, Tom6, and Tom7. Tom22, the central preprotein receptor, connects the two Tom40 pores at the dimer interface. Our structure offers detailed insights into the molecular architecture of the mitochondrial preprotein import machinery. Copyright © 2017 Elsevier Inc. All rights reserved.

  11. Protein kinases responsible for the phosphorylation of the nuclear egress core complex of human cytomegalovirus. (United States)

    Sonntag, Eric; Milbradt, Jens; Svrlanska, Adriana; Strojan, Hanife; Häge, Sigrun; Kraut, Alexandra; Hesse, Anne-Marie; Amin, Bushra; Sonnewald, Uwe; Couté, Yohann; Marschall, Manfred


    Nuclear egress of herpesvirus capsids is mediated by a multi-component nuclear egress complex (NEC) assembled by a heterodimer of two essential viral core egress proteins. In the case of human cytomegalovirus (HCMV), this core NEC is defined by the interaction between the membrane-anchored pUL50 and its nuclear cofactor, pUL53. NEC protein phosphorylation is considered to be an important regulatory step, so this study focused on the respective role of viral and cellular protein kinases. Multiply phosphorylated pUL50 varieties were detected by Western blot and Phos-tag analyses as resulting from both viral and cellular kinase activities. In vitro kinase analyses demonstrated that pUL50 is a substrate of both PKCα and CDK1, while pUL53 can also be moderately phosphorylated by CDK1. The use of kinase inhibitors further illustrated the importance of distinct kinases for core NEC phosphorylation. Importantly, mass spectrometry-based proteomic analyses identified five major and nine minor sites of pUL50 phosphorylation. The functional relevance of core NEC phosphorylation was confirmed by various experimental settings, including kinase knock-down/knock-out and confocal imaging, in which it was found that (i) HCMV core NEC proteins are not phosphorylated solely by viral pUL97, but also by cellular kinases; (ii) both PKC and CDK1 phosphorylation are detectable for pUL50; (iii) no impact of PKC phosphorylation on NEC functionality has been identified so far; (iv) nonetheless, CDK1-specific phosphorylation appears to be required for functional core NEC interaction. In summary, our findings provide the first evidence that the HCMV core NEC is phosphorylated by cellular kinases, and that the complex pattern of NEC phosphorylation has functional relevance.

  12. CORE

    DEFF Research Database (Denmark)

    Krigslund, Jeppe; Hansen, Jonas; Hundebøll, Martin


    State-of-the-art in network coding for wireless, meshed networks typically considers two problems separately. First, the problem of providing reliability for a single session. Second, the problem of opportunistic combination of flows by using minimalistic coding, i.e., by XORing packets from...... different flows. Instead of maintaining these approaches separate, we propose a protocol (CORE) that brings together these coding mechanisms. Our protocol uses random linear network coding (RLNC) for intra- session coding but allows nodes in the network to setup inter- session coding regions where flows...

  13. Molecular and Structural Analysis of the Helicobacter pylori cag Type IV Secretion System Core Complex. (United States)

    Frick-Cheng, Arwen E; Pyburn, Tasia M; Voss, Bradley J; McDonald, W Hayes; Ohi, Melanie D; Cover, Timothy L


    Bacterial type IV secretion systems (T4SSs) can function to export or import DNA, and can deliver effector proteins into a wide range of target cells. Relatively little is known about the structural organization of T4SSs that secrete effector proteins. In this report, we describe the isolation and analysis of a membrane-spanning core complex from the Helicobacter pylori cag T4SS, which has an important role in the pathogenesis of gastric cancer. We show that this complex contains five H. pylori proteins, CagM, CagT, Cag3, CagX, and CagY, each of which is required for cag T4SS activity. CagX and CagY are orthologous to the VirB9 and VirB10 components of T4SSs in other bacterial species, and the other three Cag proteins are unique to H. pylori. Negative stain single-particle electron microscopy revealed complexes 41 nm in diameter, characterized by a 19-nm-diameter central ring linked to an outer ring by spoke-like linkers. Incomplete complexes formed by Δcag3 or ΔcagT mutants retain the 19-nm-diameter ring but lack an organized outer ring. Immunogold labeling studies confirm that Cag3 is a peripheral component of the complex. The cag T4SS core complex has an overall diameter and structural organization that differ considerably from the corresponding features of conjugative T4SSs. These results highlight specialized features of the H. pylori cag T4SS that are optimized for function in the human gastric mucosal environment. Type IV secretion systems (T4SSs) are versatile macromolecular machines that are present in many bacterial species. In this study, we investigated a T4SS found in the bacterium Helicobacter pylori. H. pylori is an important cause of stomach cancer, and the H. pylori T4SS contributes to cancer pathogenesis by mediating entry of CagA (an effector protein regarded as a "bacterial oncoprotein") into gastric epithelial cells. We isolated and analyzed the membrane-spanning core complex of the H. pylori T4SS and showed that it contains unique proteins

  14. Core size determination and structural characterization of intravenous iron complexes by cryogenic transmission electron microscopy. (United States)

    Wu, Yong; Petrochenko, Peter; Chen, Lynn; Wong, Sook Yee; Absar, Mohammad; Choi, Stephanie; Zheng, Jiwen


    Understanding physicochemical properties of intravenous (IV) iron drug products is essential to ensure the manufacturing process is consistent and streamlined. The history of physicochemical characterization of IV iron complex formulations stretches over several decades, with disparities in iron core size and particle morphology as the major source of debate. One of the main reasons for this controversy is room temperature sample preparation artifacts, which affect accurate determination of size, shape and agglomeration/aggregation of nanoscale iron particles. The present study is first to report the ultra-fine iron core structures of four IV iron complex formulations, sodium ferric gluconate, iron sucrose, low molecular weight iron dextran and ferumoxytol, using a cryogenic transmission electron microscopy (cryo-TEM) preservation technique, as opposed to the conventional room temperature (RT-TEM) technique. Our results show that room temperature preparation causes nanoparticle aggregation and deformation, while cryo-TEM preserves IV iron colloidal suspension in their native frozen-hydrated and undiluted state. In contrast to the current consensus in literature, all four IV iron colloids exhibit a similar morphology of their iron oxide cores with a spherical shape, narrow size distribution and an average size of 2nm. Moreover, out of the four tested formulations, ferumoxytol exhibits a cluster-like community of several iron carbohydrate particles which likely accounts for its large hydrodynamic size of 25nm, measured with dynamic light scattering. Our findings outline a suitable method for identifying colloidal nanoparticle core size in the native state, which is increasingly important for manufacturing and design control of complex drug formulations, such as IV iron drug products. Published by Elsevier B.V.

  15. Hyperbranched red light-emitting phosphorescent polymers based on iridium complex as the core

    Energy Technology Data Exchange (ETDEWEB)

    Guo, Ting; Yu, Lei; Yang, Yong; Li, Yanhu; Tao, Yun [Institute of Polymer Optoelectronic Materials and Devices, State Key Laboratory of Luminescent Materials and Devices, South China University of Technology, Guangzhou 510640 (China); Hou, Qiong [School of Chemistry & Environment, South China Normal University, Guangzhou 510006 (China); Ying, Lei, E-mail: [Institute of Polymer Optoelectronic Materials and Devices, State Key Laboratory of Luminescent Materials and Devices, South China University of Technology, Guangzhou 510640 (China); Yang, Wei; Wu, Hongbin; Cao, Yong [Institute of Polymer Optoelectronic Materials and Devices, State Key Laboratory of Luminescent Materials and Devices, South China University of Technology, Guangzhou 510640 (China)


    A series of hyperbranched π-conjugated light-emitting polymers containing an iridium complex as the branched core unit and polyfluorene or poly(fluorene-alt-carbazole) as the branched segments were synthesized via a palladium catalyzed Suzuki polymerization. Apparent Förster energy transfer in the photoluminescent spectra as thin films was observed, while no discernible characteristic absorbance and photoluminescence of the iridium complex can be realized in dilute solutions. Copolymers based on poly(fluorene-alt-carbazole) as the branched segments demonstrated enhanced highest occupied molecular orbital energy levels relative to those based on polyfluorene. The electroluminescent spectra of these copolymers exclusively showed the characteristic emission of the iridium complex, with corresponding CIE coordinates of (0.67±0.01, 0.31). All devices exhibited relatively slow roll-off of efficiency, and the best device performance with the maximum luminous efficiency of 5.33 cd A{sup −1} was attained by using PFCzTiqIr3 as the emissive layer. These results indicated that the hyperbranched conjugated architectures can be a promising molecular design strategy for efficient electrophosphorescent light-emitting polymers. - Highlights: • Hyperbranched red light-emitting polymers are synthesized. • Red light-emitting iridium complex is used as the branched core unit. • Hyperbranched polymers based on PFCz exhibit higher luminescence. • The highest luminous efficiency of 5.33 cd A{sup −1} is attained.

  16. Well log responses in metamorphic rocks near Maribor

    Directory of Open Access Journals (Sweden)


    Full Text Available In the Stražun forest at Pobrežje near Maribor, (Eastern Slovenia six boreholes have been drilled from 860 to 1600m deep. The paper describes geological conditions in mentioned boreholes, as well as in wider surroundings of Maribor with stress on metamorphic rocks. Based on pétrographie analysis of the rocks cuttings and well logs the upper phyllitic part ant the lower Pohorje series of themetamorphic complex could be separated. The first one includes phyllites with phyllitic quartzites and silicate marmorized limestones. The Pohorje series is represented by two-mica gneiss and schist, mainly with inclusions of amphibolite and eclogite, and subordinately retrograde chlorite-amphibole schist. The welllog responses for particular lithological sequences of metamorphic complex have been distinguished on the basis of conventional electrologs and gamma ray measurements.The problem of lithological interpretation of well logs in these rocks is described. Two fields of well log responses are distinguishable, as separated by the degree of natural radioactivity. Apart from veined quartzite, all rocks fromthe phyllitic part of the metamorphic complex are highly radioactive. In the Pohorje series gneiss, schist and diaphtorite-phyllonite are highly radioactive, while amphibolite, eclogite and retrograde chlorite-amphibole schist have low radioactivity.Finally, typical well log responses in lithological sequences of the discussed metamorphic rocks are presented.

  17. Fanconi anemia core complex gene promoters harbor conserved transcription regulatory elements.

    Directory of Open Access Journals (Sweden)

    Daniel Meier

    Full Text Available The Fanconi anemia (FA gene family is a recent addition to the complex network of proteins that respond to and repair certain types of DNA damage in the human genome. Since little is known about the regulation of this novel group of genes at the DNA level, we characterized the promoters of the eight genes (FANCA, B, C, E, F, G, L and M that compose the FA core complex. The promoters of these genes show the characteristic attributes of housekeeping genes, such as a high GC content and CpG islands, a lack of TATA boxes and a low conservation. The promoters functioned in a monodirectional way and were, in their most active regions, comparable in strength to the SV40 promoter in our reporter plasmids. They were also marked by a distinctive transcriptional start site (TSS. In the 5' region of each promoter, we identified a region that was able to negatively regulate the promoter activity in HeLa and HEK 293 cells in isolation. The central and 3' regions of the promoter sequences harbor binding sites for several common and rare transcription factors, including STAT, SMAD, E2F, AP1 and YY1, which indicates that there may be cross-connections to several established regulatory pathways. Electrophoretic mobility shift assays and siRNA experiments confirmed the shared regulatory responses between the prominent members of the TGF-β and JAK/STAT pathways and members of the FA core complex. Although the promoters are not well conserved, they share region and sequence specific regulatory motifs and transcription factor binding sites (TBFs, and we identified a bi-partite nature to these promoters. These results support a hypothesis based on the co-evolution of the FA core complex genes that was expanded to include their promoters.

  18. Metamorphic P-T evolution and U-Th-total Pb monazite dating of metapelites from the Nellore schist belt, Southeastern India: Implications for the Proterozoic tectonics (United States)

    Hrushikesh, Hari; Prabhakar, Naraga


    The Paleoproterozoic Nellore Schist Belt (NSB) in the southeastern margin of the eastern Dharwar Craton (India) is predominantly described as a collision zone formed by accretionary growth. Two lithological groups are distinguished within the NSB: (a) a lower Vinjamuru Domain (VD) mainly consists of amphibolite facies metagabbros and amphibolites, and (b) an upper Udayagiri domain with greenschist facies platformal metasedimentary sequences. The present study emphasizes on demonstrating the structural, metamorphic, and chronological history of the metapelites from Saidapuram and Malakonda areas of the VD. These metapelites are sporadically exposed as lensoidal bodies composed of garnet + staurolite + kyanite + biotite + muscovite + paragonite and garnet + staurolite + plagioclase + biotite + muscovite ± kyanite mineral assemblages along with quartz and ilmenite. Integration of deformation microtextures with the results of phase equilibrium modelling coupled with conventional thermobarometric studies indicate the presence of three stages of metamorphism (M1-M2-M3). The garnet + kyanite + muscovite + quartz ± biotite assemblage characterize the early metamorphic event (M1), which is syntectonic with F1 folding at P-T conditions 540-560 ˚ C and 6.0-6.4 kb. The P-T conditions of syn/post-D2 peak metamorphism (M2) represented by garnet + staurolite + muscovite + biotite + plagioclase + quartz ± kyanite assemblage were equilibrated at 600-620 ˚ C and 7.8-8.2 kb. The last episode of metamorphism (M3) coeval with D3 crenulation cleavage gave rise to chlorite + muscovite ± biotite retrograde mineral assemblage. Texturally constrained U-Th-total Pb monazite dating reveals three distinct populations clustering around 1.65-1.55, 1.45-1.35 and 0.80 Ga in the metapelites. The chemical ages (1.65-1.55 Ga) retrieved from monazite cores limit the upper amphibolite facies peak metamorphism in the pelitic rocks that presumably stabilized major part of the crust within the NSB

  19. Metamorphic P-T-t-d evolution of (U)HP metabasites from the South Tianshan accretionary complex (NW China) - Implications for rock deformation during exhumation in a subduction channel

    Czech Academy of Sciences Publication Activity Database

    Soldner, J.; Oliot, E.; Schulmann, K.; Štípská, P.; Kusbach, Vladimír; Anczkiewicz, R.


    Roč. 47, July (2017), s. 161-187 ISSN 1342-937X Institutional support: RVO:67985530 Keywords : eclogite * Tianshan massif * (U)HP metamorphic belt Subject RIV: DB - Geology ; Mineralogy OBOR OECD: Geology Impact factor: 6.959, year: 2016

  20. Alkali Metal Variation and Twisting of the FeNNFe Core in Bridging Diiron Dinitrogen Complexes. (United States)

    McWilliams, Sean F; Rodgers, Kenton R; Lukat-Rodgers, Gudrun; Mercado, Brandon Q; Grubel, Katarzyna; Holland, Patrick L


    Alkali metal cations can interact with Fe-N2 complexes, potentially enhancing back-bonding or influencing the geometry of the iron atom. These influences are relevant to large-scale N2 reduction by iron, such as in the FeMoco of nitrogenase and the alkali-promoted Haber-Bosch process. However, to our knowledge there have been no systematic studies of a large range of alkali metals regarding their influence on transition metal-dinitrogen complexes. In this work, we varied the alkali metal in [alkali cation]2[LFeNNFeL] complexes (L = bulky β-diketiminate ligand) through the size range from Na(+) to K(+), Rb(+), and Cs(+). The FeNNFe cores have similar Fe-N and N-N distances and N-N stretching frequencies despite the drastic change in alkali metal cation size. The two diketiminates twist relative to one another, with larger dihedral angles accommodating the larger cations. In order to explain why the twisting has so little influence on the core, we performed density functional theory calculations on a simplified LFeNNFeL model, which show that the two metals surprisingly do not compete for back-bonding to the same π* orbital of N2, even when the ligand planes are parallel. This diiron system can tolerate distortion of the ligand planes through compensating orbital energy changes, and thus, a range of ligand orientations can give very similar energies.

  1. HCV Core Residues Critical for Infectivity Are Also Involved in Core-NS5A Complex Formation (United States)

    Gawlik, Katarzyna; Baugh, James; Chatterji, Udayan; Lim, Precious J.; Bobardt, Michael D.; Gallay, Philippe A.


    Hepatitis C virus (HCV) infection is a major cause of liver disease. The molecular machinery of HCV assembly and particle release remains obscure. A better understanding of the assembly events might reveal new potential antiviral strategies. It was suggested that the nonstructural protein 5A (NS5A), an attractive recent drug target, participates in the production of infectious particles as a result of its interaction with the HCV core protein. However, prior to the present study, the NS5A-binding site in the viral core remained unknown. We found that the D1 domain of core contains the NS5A-binding site with the strongest interacting capacity in the basic P38-K74 cluster. We also demonstrated that the N-terminal basic residues of core at positions 50, 51, 59 and 62 were required for NS5A binding. Analysis of all substitution combinations of R50A, K51A, R59A, and R62A, in the context of the HCVcc system, showed that single, double, triple, and quadruple mutants were fully competent for viral RNA replication, but deficient in secretion of viral particles. Furthermore, we found that the extracellular and intracellular infectivity of all the mutants was abolished, suggesting a defect in the formation of infectious particles. Importantly, we showed that the interaction between the single and quadruple core mutants and NS5A was impaired in cells expressing full-length HCV genome. Interestingly, mutations of the four basic residues of core did not alter the association of core or NS5A with lipid droplets. This study showed for the first time that basic residues in the D1 domain of core that are critical for the formation of infectious extracellular and intracellular particles also play a role in core-NS5A interactions. PMID:24533158

  2. Evolution of complex organic molecules in hot molecular cores. Synthetic spectra at (sub-)mm wavebands (United States)

    Choudhury, R.; Schilke, P.; Stéphan, G.; Bergin, E.; Möller, T.; Schmiedeke, A.; Zernickel, A.


    Context. Hot molecular cores (HMCs) are intermediate stages of high-mass star formation and are also known for their rich chemical reservoirs and emission line spectra at (sub-)mm wavebands. Complex organic molecules (COMs) such as methanol (CH3OH), ethanol (C2H5OH), dimethyl ether (CH3OCH3), and methyl formate (HCOOCH3) produce most of these observed lines. The observed spectral feature of HMCs such as total number of emission lines and associated line intensities are also found to vary with evolutionary stages. Aims: We aim to investigate the spectral evolution of these COMs to explore the initial evolutionary stages of high-mass star formation including HMCs. Methods: We developed various 3D models for HMCs guided by the evolutionary scenarios proposed by recent empirical and modeling studies. We then investigated the spatio-temporal variation of temperature and molecular abundances in HMCs by consistently coupling gas-grain chemical evolution with radiative transfer calculations. We explored the effects of varying physical conditions on molecular abundances including density distribution and luminosity evolution of the central protostar(s) among other parameters. Finally, we simulated the synthetic spectra for these models at different evolutionary timescales to compare with observations. Results: Temperature has a profound effect on the formation of COMs through the depletion and diffusion on grain surface to desorption and further gas-phase processing. The time-dependent temperature structure of the hot core models provides a realistic framework for investigating the spatial variation of ice mantle evaporation as a function of evolutionary timescales. We find that a slightly higher value (15 K) than the canonical dark cloud temperature (10 K) provides a more productive environment for COM formation on grain surface. With increasing protostellar luminosity, the water ice evaporation font (~100 K) expands and the spatial distribution of gas phase abundances of

  3. Haploinsufficiency for Core Exon Junction Complex Components Disrupts Embryonic Neurogenesis and Causes p53-Mediated Microcephaly.

    Directory of Open Access Journals (Sweden)

    Hanqian Mao


    Full Text Available The exon junction complex (EJC is an RNA binding complex comprised of the core components Magoh, Rbm8a, and Eif4a3. Human mutations in EJC components cause neurodevelopmental pathologies. Further, mice heterozygous for either Magoh or Rbm8a exhibit aberrant neurogenesis and microcephaly. Yet despite the requirement of these genes for neurodevelopment, the pathogenic mechanisms linking EJC dysfunction to microcephaly remain poorly understood. Here we employ mouse genetics, transcriptomic and proteomic analyses to demonstrate that haploinsufficiency for each of the 3 core EJC components causes microcephaly via converging regulation of p53 signaling. Using a new conditional allele, we first show that Eif4a3 haploinsufficiency phenocopies aberrant neurogenesis and microcephaly of Magoh and Rbm8a mutant mice. Transcriptomic and proteomic analyses of embryonic brains at the onset of neurogenesis identifies common pathways altered in each of the 3 EJC mutants, including ribosome, proteasome, and p53 signaling components. We further demonstrate all 3 mutants exhibit defective splicing of RNA regulatory proteins, implying an EJC dependent RNA regulatory network that fine-tunes gene expression. Finally, we show that genetic ablation of one downstream pathway, p53, significantly rescues microcephaly of all 3 EJC mutants. This implicates p53 activation as a major node of neurodevelopmental pathogenesis following EJC impairment. Altogether our study reveals new mechanisms to help explain how EJC mutations influence neurogenesis and underlie neurodevelopmental disease.

  4. Gold, uranium and thorium in zones of greenschist displacement metamorphism

    International Nuclear Information System (INIS)

    Gavrilenko, B.V.; Savitskij, A.V.; Titov, V.V.


    Distribution of gold, uranium (bar and mobile) and thorium in 15 zones of greenschist dislocated metamorphism in different structures of the Karelo-Kola region carried out by geologic formations of the Early-Archean-Late-Proterozoic age has been studied. More than 200 samples of well core from 0-200 m depths have been analyzed. The results obtained testify to the increase of gold, uranium and less thorium content in zones of green-schist dislocated metamorphism in comparison with the enclosing rocks 1.4-3.1 times. The variation coefficient of gold, uranium and thorium content in green-schist dislocated tectonites increases 1.5-2.9 times. The correlation coefficient of Au/U mob. pair is +0.69, and Au/U bar pair -+0.87. Essential correlation between concentrations of all three elements in enclosing rocks is absent

  5. Complex inner core of the Earth: The last frontier of global seismology (United States)

    Tkalčić, Hrvoje


    The days when the Earth's inner core (IC) was viewed as a homogeneous solid sphere surrounded by the liquid outer core (OC) are now behind us. Due to a limited number of data sampling the IC and a lack of experimentally controlled conditions in the deep Earth studies, it has been difficult to scrutinize competitive hypotheses in this active area of research. However, a number of new concepts linking IC structure and dynamics has been proposed lately to explain different types of seismological observations. A common denominator of recent observational work on the IC is increased complexity seen in IC physical properties such as its isotropic and anisotropic structure, attenuation, inner core boundary (ICB) topography, and its rotational dynamics. For example, small-scale features have been observed to exist as a widespread phenomenon in the uppermost inner core, probably superimposed on much longer-scale features. The characterization of small-scale features sheds light on the nature of the solidification process and helps in understanding seismologically observed hemispherical dichotomy of the IC. The existence of variations in the rate and level of solidification is a plausible physical outcome in an environment where vigorous compositional convection in the OC and variations in heat exchange across the ICB may control the process of crystal growth. However, further progress is hindered by the fact that the current traveltime data of PKIKP waves traversing the IC do not allow discriminating between variations in isotropic P wave velocity and velocity anisotropy. Future studies of attenuation in the IC might provide crucial information about IC structure, although another trade-off exists—that of the relative contribution of scattering versus viscoelastic attenuation and the connection with the material properties. Future installations of dense arrays, cross paths of waves that sample the IC, and corresponding array studies will be a powerful tool to image and

  6. Temporal and spatial distribution of Paleozoic metamorphism in the southern Appalachian Blue Ridge and Inner Piedmont delimited by ion microprobe U-Pb ages of metamorphic zircon (United States)

    Merschat, Arthur J.; Bream, Brendan R.; Huebner, Matthew T.; Hatcher, Robert D.; Miller, Calvin F.


    Ion microprobe U-Pb zircon rim ages from 39 samples from across the accreted terranes of the central Blue Ridge, eastward across the Inner Piedmont, delimit the timing and spatial extent of superposed metamorphism in the southern Appalachian orogen. Metamorphic zircon rims are 10–40 µm wide, mostly unzoned, and dark gray to black or bright white in cathodoluminescence, and truncate and/or embay interior oscillatory zoning. Black unzoned and rounded or ovoid-shaped metamorphic zircon morphologies also occur. Th/U values range from 0.01 to 1.4, with the majority of ratios less than 0.1. Results of 206Pb/238U ages, ±2% discordant, range from 481 to 305 Ma. Clustering within these data reveals that the Blue Ridge and Inner Piedmont terranes were affected by three tectonothermal events: (1) 462–448 Ma (Taconic); (2) 395–340 Ma (Acadian and Neoacadian); and (3) 335–322 Ma, related to the early phase of the Alleghanian orogeny. By combining zircon rim ages with metamorphic isograds and other published isotopic ages, we identify the thermal architecture of the southern Appalachian orogen: juxtaposed and superposed metamorphic domains have younger ages to the east related to the marginward addition of terranes, and these domains can serve as a proxy to delimit terrane accretion. Most 462–448 Ma ages occur in the western and central Blue Ridge and define a continuous progression from greenschist to granulite facies that identifies the intact Taconic core. The extent of 462–448 Ma metamorphism indicates that the central Blue Ridge and Tugaloo terranes were accreted to the western Blue Ridge during the Taconic orogeny. Zircon rim ages in the Inner Piedmont span almost 100 m.y., with peaks at 395–385, 376–340, and 335–322 Ma, and delimit the Acadian-Neoacadian and Alleghanian metamorphic core. The timing and distribution of metamorphism in the Inner Piedmont are consistent with the Devonian to Mississippian oblique collision of the Carolina superterrane

  7. Crystalline diuranium phosphinidiide and μ-phosphido complexes with symmetric and asymmetric UPU cores

    Energy Technology Data Exchange (ETDEWEB)

    Rookes, Thomas M.; Gardner, Benedict M.; Gregson, Matthew; Tuna, Floriana; Wooles, Ashley J.; Liddle, Stephen T. [School of Chemistry, The University of Manchester, Manchester (United Kingdom); Balazs, Gabor; Scheer, Manfred [Institute of Inorganic Chemistry, University of Regensburg (Germany)


    Reaction of [U(Tren{sup TIPS})(PH{sub 2})] (1, Tren{sup TIPS}=N(CH{sub 2}CH{sub 2}NSiPr{sup i}{sub 3}){sub 3}) with C{sub 6}H{sub 5}CH{sub 2}K and [U(Tren{sup TIPS})(THF)][BPh{sub 4}] (2) afforded a rare diuranium parent phosphinidiide complex [{U(Tren"T"I"P"S)}{sub 2}(μ-PH)] (3). Treatment of 3 with C{sub 6}H{sub 5}CH{sub 2}K and two equivalents of benzo-15-crown-5 ether (B15C5) gave the diuranium μ-phosphido complex [{U(Tren"T"I"P"S)}{sub 2}(μ-P)][K(B15C5){sub 2}] (4). Alternatively, reaction of [U(Tren{sup TIPS})(PH)][Na(12C4){sub 2}] (5, 12C4=12-crown-4 ether) with [U{N(CH_2CH_2NSiMe_2Bu"t)_2CH_2CH_2NSi(Me)(CH_2)(Bu"t)}] (6) produced the diuranium μ-phosphido complex [{U(Tren"T"I"P"S)}(μ-P){U(Tren"D"M"B"S)}][Na(12C4){sub 2}] [7, Tren{sup DMBS}=N(CH{sub 2}CH{sub 2}NSiMe{sub 2}Bu{sup t}){sub 3}]. Compounds 4 and 7 are unprecedented examples of uranium phosphido complexes outside of matrix isolation studies, and they rapidly decompose in solution underscoring the paucity of uranium phosphido complexes. Interestingly, 4 and 7 feature symmetric and asymmetric UPU cores, respectively, reflecting their differing steric profiles. (copyright 2017 The Authors. Published by Wiley-VCH Verlag GmbH and Co. KGaA.)

  8. Complex molecules in the hot core of the low-mass protostar NGC 1333 IRAS 4A

    NARCIS (Netherlands)

    Bottinelli, S; Ceccarelli, C; Lefloch, B; Williams, JP; Castets, A; Caux, E; Cazaux, S; Maret, S; Parise, B; Tielens, AGGM


    We report the detection of complex molecules (HCOOCH3, HCOOH, and CH3CN), signposts of a hot core like region, toward the low-mass Class 0 source NGC 1333 IRAS 4A. This is the second low-mass protostar in which such complex molecules have been searched for and reported, the other source being IRAS

  9. The Detection of Hot Cores and Complex Organic Molecules in the Large Magellanic Cloud (United States)

    Sewiło, Marta; Indebetouw, Remy; Charnley, Steven B.; Zahorecz, Sarolta; Oliveira, Joana M.; van Loon, Jacco Th.; Ward, Jacob L.; Chen, C.-H. Rosie; Wiseman, Jennifer; Fukui, Yasuo; Kawamura, Akiko; Meixner, Margaret; Onishi, Toshikazu; Schilke, Peter


    We report the first extragalactic detection of the complex organic molecules (COMs) dimethyl ether (CH3OCH3) and methyl formate (CH3OCHO) with the Atacama Large Millimeter/submillimeter Array (ALMA). These COMs, together with their parent species methanol (CH3OH), were detected toward two 1.3 mm continuum sources in the N 113 star-forming region in the low-metallicity Large Magellanic Cloud (LMC). Rotational temperatures ({T}{rot}∼ 130 K) and total column densities ({N}{rot}∼ {10}16 cm‑2) have been calculated for each source based on multiple transitions of CH3OH. We present the ALMA molecular emission maps for COMs and measured abundances for all detected species. The physical and chemical properties of two sources with COMs detection, and the association with H2O and OH maser emission, indicate that they are hot cores. The fractional abundances of COMs scaled by a factor of 2.5 to account for the lower metallicity in the LMC are comparable to those found at the lower end of the range in Galactic hot cores. Our results have important implications for studies of organic chemistry at higher redshift.

  10. Metamorphism of bauxites on Naxos, Greece

    NARCIS (Netherlands)

    Feenstra, A.


    This thesis presents the results of a petrological-mineralogical and geochemical study of the metamorphosed karstbauxites on the island of Naxos, Greece. The bauxites have been subject to an Eocene highpressure metamorphism (M1), followed by a Late Oligocene-Miocene medium-pressure metamorphism

  11. Structure of the dimeric PufX-containing core complex of Rhodobacter blasticus by in situ atomic force microscopy. (United States)

    Scheuring, Simon; Busselez, Johan; Lévy, Daniel


    We have studied photosynthetic membranes of wild type Rhodobacter blasticus, a closely related strain to the well studied Rhodobacter sphaeroides, using atomic force microscopy. High-resolution atomic force microscopy topographs of both cytoplasmic and periplasmic surfaces of LH2 and RC-LH1-PufX (RC, reaction center) complexes were acquired in situ. The LH2 is a nonameric ring inserted into the membrane with the 9-fold axis perpendicular to the plane. The core complex is an S-shaped dimer composed of two RCs, each encircled by 13 LH1 alpha/beta-heterodimers, and two PufXs. The LH1 assembly is an open ellipse with a topography-free gap of approximately 25 A. The two PufXs, one of each core, are located at the dimer center. Based on our data, we propose a model of the core complex, which provides explanation for the PufX-induced dimerization of the Rhodobacter core complex. The QB site is located facing a approximately 25-A wide gap within LH1, explaining the PufX-favored quinone passage in and out of the core complex.

  12. Enhancing oxidative stability in heated oils using core/shell structures of collagen and α-tocopherol complex. (United States)

    Gim, Seo Yeong; Hong, Seungmi; Kim, Jisu; Kwon, YongJun; Kim, Mi-Ja; Kim, GeunHyung; Lee, JaeHwan


    In this study, collagen mesh structure was prepared by carrying α-tocopherol in the form of core/shell complex. Antioxidant properties of α-tocopherol loaded carriers were tested in moisture added bulk oils at 140°C. From one gram of collagen core/shell complex, 138mg α-tocopherol was released in medium chain triacylglycerol (MCT). α-Tocopherol was substantially protected against heat treatment when α-tocopherol was complexed in collagen core/shell. Oxidative stability in bulk oil was significantly enhanced by added collagen mesh structure or collagen core/shell complex with α-tocopherol compared to that in control bulk oils (pshell with α-tocopherol (p>0.05). Results of DPPH loss in methanol demonstrated that collagen core/shell with α-tocopherol had significantly (pshell complex is a promising way to enhance the stability of α-tocopherol and oxidative stability in oil-rich foods prepared at high temperature. Copyright © 2017 Elsevier Ltd. All rights reserved.

  13. Critical assessment of the emission spectra of various photosystem II core complexes. (United States)

    Chen, Jinhai; Kell, Adam; Acharya, Khem; Kupitz, Christopher; Fromme, Petra; Jankowiak, Ryszard


    We evaluate low-temperature (low-T) emission spectra of photosystem II core complexes (PSII-cc) previously reported in the literature, which are compared with emission spectra of PSII-cc obtained in this work from spinach and for dissolved PSII crystals from Thermosynechococcus (T.) elongatus. This new spectral dataset is used to interpret data published on membrane PSII (PSII-m) fragments from spinach and Chlamydomonas reinhardtii, as well as PSII-cc from T. vulcanus and intentionally damaged PSII-cc from spinach. This study offers new insight into the assignment of emission spectra reported on PSII-cc from different organisms. Previously reported spectra are also compared with data obtained at different saturation levels of the lowest energy state(s) of spinach and T. elongatus PSII-cc via hole burning in order to provide more insight into emission from bleached and/or photodamaged complexes. We show that typical low-T emission spectra of PSII-cc (with closed RCs), in addition to the 695 nm fluorescence band assigned to the intact CP47 complex (Reppert et al. J Phys Chem B 114:11884-11898, 2010), can be contributed to by several emission bands, depending on sample quality. Possible contributions include (i) a band near 690-691 nm that is largely reversible upon temperature annealing, proving that the band originates from CP47 with a bleached low-energy state near 693 nm (Neupane et al. J Am Chem Soc 132:4214-4229, 2010; Reppert et al. J Phys Chem B 114:11884-11898, 2010); (ii) CP43 emission at 683.3 nm (not at 685 nm, i.e., the F685 band, as reported in the literature) (Dang et al. J Phys Chem B 112:9921-9933, 2008; Reppert et al. J Phys Chem B 112:9934-9947, 2008); (iii) trap emission from destabilized CP47 complexes near 691 nm (FT1) and 685 nm (FT2) (Neupane et al. J Am Chem Soc 132:4214-4229, 2010); and (iv) emission from the RC pigments near 686-687 nm. We suggest that recently reported emission of single PSII-cc complexes from T. elongatus may not represent

  14. Effect of surface conditioning modalities on the repair bond strength of resin composite to the zirconia core / veneering ceramic complex. (United States)

    Ozcan, Mutlu; Valandro, Luiz Felipe; Pereira, Sarina Maciel; Amaral, Regina; Bottino, Marco Antonio; Pekkan, Gurel


    This study evaluated the effect of different surface conditioning protocols on the repair strength of resin composite to the zirconia core / veneering ceramic complex, simulating the clinical chipping phenomenon. Forty disk-shaped zirconia core (Lava Zirconia, 3M ESPE) (diameter: 3 mm) specimens were veneered circumferentially with a feldspathic veneering ceramic (VM7, Vita Zahnfabrik) (thickness: 2 mm) using a split metal mold. They were then embedded in autopolymerizing acrylic with the bonding surfaces exposed. Specimens were randomly assigned to one of the following surface conditioning protocols (n = 10 per group): group 1, veneer: 4% hydrofluoric acid (HF) (Porcelain Etch) + core: aluminum trioxide (50-µm Al2O3) + core + veneer: silane (ESPE-Sil); group 2: core: Al2O3 (50 µm) + veneer: HF + core + veneer: silane; group 3: veneer: HF + core: 30 µm aluminum trioxide particles coated with silica (30 µm SiO2) + core + veneer: silane; group 4: core: 30 µm SiO2 + veneer: HF + core + veneer: silane. Core and veneer ceramic were conditioned individually but no attempt was made to avoid cross contamination of conditioning, simulating the clinical intraoral repair situation. Adhesive resin (VisioBond) was applied to both the core and the veneer ceramic, and resin composite (Quadrant Posterior) was bonded onto both substrates using polyethylene molds and photopolymerized. After thermocycling (6000 cycles, 5°C-55°C), the specimens were subjected to shear bond testing using a universal testing machine (1 mm/min). Failure modes were identified using an optical microscope, and scanning electron microscope images were obtained. Bond strength data (MPa) were analyzed statistically using the non-parametric Kruskal-Wallis test followed by the Wilcoxon rank-sum test and the Bonferroni Holm correction (α = 0.05). Group 3 demonstrated significantly higher values (MPa) (8.6 ± 2.7) than those of the other groups (3.2 ± 3.1, 3.2 ± 3, and 3.1 ± 3.5 for groups 1, 2, and 4

  15. Measurement of activity concentration of {sup 222}Rn in ground waters drawn from two wells drilled in the Amparo Complex metamorphic rocks, municipio de Amparo, SP; Medida da atividade do {sup 222}Rn em aguas subterraneas extraidas de dois pocos perfurados em rochas metamorficas do Complexo Amparo, municipio de Amparo, SP

    Energy Technology Data Exchange (ETDEWEB)

    Oliveira, Igor Jose Chaves de


    A sampling system was assembled for field {sup 222}Rn activity concentration measurements in ground waters. The system consists of a sampling flask that prevents the contact between the water sample and the atmosphere and a closed line for radon extraction from water. The system, its operation and calibration, are described in full detail, as well as, the conversion of the measured alpha counting rates in activity concentrations. The assembled system was used in {sup 222}Rn activity concentrations measurements in ground waters drawn from two wells drilled in the Amparo Complex metamorphic rocks. The wells are located at the urban area of the city of Amparo and are exploited for public use water. One well, named Vale Verde, is 56 meters deep and crosses 18 meters of soil, 26 meters of quartz rich gneiss and 12 meters of biotite-gneiss. The other well, named Seabra, is 117 meters deep, crosses 28 meters of soil and weathered rocks and ends in granite-gneiss. The mean activity concentrations for the year long observation were (377 +- 25) Bq/dm{sup 3}, for Seabra well, and (1282 +- 57) Bq/dm3, for the Vale Verde well. The {sup 222}Rn activity concentrations fall in the activity concentration range reported in the literature for similar geology areas and are larger than the concentrations found neighboring areas of the same metamorphic Complex. The seasonal activity concentration variations seem to correlate with rain fall variations in the study area. (author)

  16. Isotopic evidence for two neoproterozoic high-grade metamorphic events in the Brazilia belt

    International Nuclear Information System (INIS)

    Pimentel, Marcio Martins; Fuck, Reinhardt Adolfo; Piuzanna, Danielle; Moraes, Renato de; Gioia, Simone Maria C.L


    The Brasilia Belt is part of a Brasiliano/Pan African orogen developed between the Amazon and Sao Francisco cratons. The stabilization of the belt occurred after the last metamorphic event at ca. 620 Ma. There has been increasing geochronological evidence, however, for an older Neoproterozoic metamorphic event at ca. 780 Ma, observed mainly in high grade rocks of three large mafic-ultramafic complexes in the northern part of the belt. In this study we present: (i) new U-Pb and Sm-Nd geochronological data, (ii) a review of the existing metamorphic ages in the Brasilia Belt, and (iii) a discussion on the tectonic model to explain the two Neoproterozoic metamorphic ages (au)

  17. Synthesis, characterisation, cellular uptake and cytotoxicity of functionalised magnetic ruthenium (II) polypyridine complex core-shell nanocomposite. (United States)

    Kandibanda, Srinivasa Rao; Gundeboina, Narasihmha; Das, Sourav; Sunkara, V Manorama


    The development of multifunctional nanoparticles comprising of a magnetic core in conjunction with appropriate molecules with capabilities to impart functionalities like luminescent, specific binding sites to facilitate attachment of moieties. This has attracted increasing attention and enables identification of promising candidates using for applications such as diagnostics and cure through early detection and localized delivery. Many studies have been performed on the synthesis and cellular interactions of core-shell nanoparticles, in which a functional inorganic core is coated with a biocompatible polymer layer that should reduce nonspecific uptake and cytotoxicity Here we report the synthesis and characterisation of multifunctional core-shell magnetic, luminescent nanocomposite (Fe 3 O 4 @SiO 2 @[Ru(Phen) 3 ] 2+ @SiO 2 @NH 2 ). Fe 3 O 4 as core and a luminescent ruthenium (II) complex encapsulated with silica shell, and then it is functionalized by an amine group by APTMS. The magnetic, luminescent, and biological activity of this multifunctional nanocomposite have also been studied to prove the nanocomposite is biocompatible, cellular uptake. The synthesized nanocomposite was completely characterized by X-ray diffraction (XRD), Fourier-transform infrared (FTIR) spectroscopy, transmission electron microscopy (TEM), vibrating sample magnetometer (VSM), and emission spectroscopy. MTT assay and cellular uptake by flow cytometry results proved that magnetic ruthenium (II) polypyridine complex - core shell nanocomposite has biocompatibility, minimum cytotoxicity and internalized inside B16F10 cells and confirms the potential biomedical applications. Copyright © 2017 Elsevier B.V. All rights reserved.

  18. Comparison of complex coacervate core micelles from two diblock copolymers or a single diblock copolymer with a polyelectrolyte.

    NARCIS (Netherlands)

    Hofs, P.S.; Voets, I.K.; Keizer, de A.; Cohen Stuart, M.A.


    With light scattering titrations, we show that complex coacervate core micelles (C3Ms) form from a diblock copolymer with a polyelectrolyte block and either an oppositely charged polyelectrolyte, a diblock copolymer with an oppositely charged polyelectrolyte or a mixture of the two. The effect of

  19. Microdeformation in Vredefort rocks; evidence for shock metamorphism (United States)

    Reimold, W. U.; Andreoli, M. A. G.; Hart, R. J.

    Planar microdeformations in quartz from basement or collar rocks of the Vredefort Dome have been cited for years as the main microtextural evidence for shock metamorphism in this structure. In addition, Schreyer describes feldspar recrystallization in rocks from the center of the Dome as the result of transformation of diaplectic glass, and Lilly reported the sighting of mosaicism in quartz. These textural observations are widely believed to indicate either an impact or an internally produced shock origin for the Vredefort Dome. Two types of (mostly sub) planar microdeformations are displayed in quartz grains from Vredefort rocks: (1) fluid inclusion trails, and (2) straight optical discontinuities that sometimes resemble lamellae. Both types occur as single features or as single or multiple sets in quartz grains. Besides qualitative descriptions of cleavage and recrystallization in feldspar and kinkbands in mica, no further microtextural evidence for shock metamorphism at Vredefort has been reported to date. Some 150 thin sections of Vredefort basement rocks were re-examined for potential shock and other deformation effects in all rock-forming minerals. This included petrographic study of two drill cores from the immediate vicinity of the center of the Dome. Observations recorded throughout the granitic core are given along with conclusions.

  20. Inert and stable erbium(III)-cored complexes based on metalloporphyrins bearing aryl-ether dendron for optical amplification: synthesis and emission enhancement

    International Nuclear Information System (INIS)

    Oh, Jae Buem; Kim, Yong Hee; Nah, Min Kook; Kim, Hwan Kyu


    We have developed novel inert and stable erbium (Er)(III)-cored complexes based on metalloporphyrins for optical amplification. The functionalized metalloporphyrin ligands have been designed and synthesized to provide enough coordination sites for the formation of inert and stable 9-coordinated Er(III)-cored complexes. Er 3+ ions were encapsulated by the metalloporphyrin ligands, such as Zn(II)- and Pt(II)-porphyrins. The near-infrared (IR) emission intensity of Er 3+ ion is much stronger in the Er(III)-cored complex based on Pt(II)-porphyrin than Er(III)-cored complex based on Zn(II)-porphyrin. Furthermore, we have incorporated a G2-aryl-ether functionalized dendron into the Er(III)-cored complex, yielding an Er(III)-cored dendrimer complex bearing the Pt(II)-porphyrin. The Er(III)-cored dendrimer complex shows the stronger near-IR emission intensity than the corresponding complex based on Pt(II)-porphyrin by seven times in solid state. The lifetimes of the emission band of Pt(II)-porphyrin ligands in the visible region were found to be 30 and 40 μs for the Er(III)-cored complex and the Er(III)-cored dendrimer complex based on Pt(II)-porphyrin in deoxygenated THF solution samples, respectively. Also, in both cases, the sensitized luminescence intensity is increased in deoxygenated solution. Therefore, it indicates that the energy transfer from the metalloporphyrins to Er 3+ ions takes places through the triplet state. In this paper, the synthesis and photophysical properties of novel Er(III)-cored complexes based on metalloporphyrins and Er(III)-cored dendrimer complex based on metalloporphyrin will be discussed

  1. Stenian - Tonian and Ediacaran metamorphic imprints in the southern Paleoproterozoic Ubendian Belt, Tanzania: Constraints from in situ monazite ages (United States)

    Boniface, Nelson; Appel, Peter


    In situ monazite geochronological data yield the timing of migmatitic metamorphism in southern Ubendian Belt. The mineral assemblage of garnet-biotite- sillimanite- K-feldspar- plagioclase-quartz- ilmenite, in migmatitic metapelitic gneisses was achieved during the Ediacaran metamorphic episode between 565 ± 4 Ma and 559 ± 8 Ma as manifested by dating of monazite grains that include garnet. The Ediacaran metamorphic event in the southern Ubendian Belt overprinted the Paleoproterozoic metamorphic event established at 1808 ± 9 Ma and the Mesoproterozoic metamorphic event at 944 ± 4 Ma (Tonian Period). The Stenian - Tonian and Ediacaran metamorphic imprints in the southern Ubendian Belt fall within the time window of metamorphism and deformation of the neighboring Irumide, southern Irumide, and Unango/Marrupa Complexes. The ca. 560 Ma old granulite facies imprinting in the southern Ubendian Belt is coeval with shear zone patterns in the neighboring Nyika Terrane in NE Malawi the event that was followed by eclogite facies metamorphism during the last stage of Gondwana amalgamation.

  2. Mantle rock exposures at oceanic core complexes along mid-ocean ridges (United States)

    Ciazela, Jakub; Koepke, Juergen; Dick, Henry J. B.; Muszynski, Andrzej


    The mantle is the most voluminous part of the Earth. However, mantle petrologists usually have to rely on indirect geophysical methods or on material found ex situ. In this review paper, we point out the in-situ existence of oceanic core complexes (OCCs), which provide large exposures of mantle and lower crustal rocks on the seafloor on detachment fault footwalls at slow-spreading ridges. OCCs are a common structure in oceanic crust architecture of slow-spreading ridges. At least 172 OCCs have been identified so far and we can expect to discover hundreds of new OCCs as more detailed mapping takes place. Thirty-two of the thirty-nine OCCs that have been sampled to date contain peridotites. Moreover, peridotites dominate in the plutonic footwall of 77% of OCCs. Massive OCC peridotites come from the very top of the melting column beneath ocean ridges. They are typically spinel harzburgites and show 11.3-18.3% partial melting, generally representing a maximum degree of melting along a segment. Another key feature is the lower frequency of plagioclase-bearing peridotites in the mantle rocks and the lower abundance of plagioclase in the plagioclase-bearing peridotites in comparison to transform peridotites. The presence of plagioclase is usually linked to impregnation with late-stage melt. Based on the above, OCC peridotites away from segment ends and transforms can be treated as a new class of abyssal peridotites that differ from transform peridotites by a higher degree of partial melting and lower interaction with subsequent transient melt.

  3. Mantle rock exposures at oceanic core complexes along mid-ocean ridges

    Directory of Open Access Journals (Sweden)

    Ciazela Jakub


    Full Text Available The mantle is the most voluminous part of the Earth. However, mantle petrologists usually have to rely on indirect geophysical methods or on material found ex situ. In this review paper, we point out the in-situ existence of oceanic core complexes (OCCs, which provide large exposures of mantle and lower crustal rocks on the seafloor on detachment fault footwalls at slow-spreading ridges. OCCs are a common structure in oceanic crust architecture of slow-spreading ridges. At least 172 OCCs have been identified so far and we can expect to discover hundreds of new OCCs as more detailed mapping takes place. Thirty-two of the thirty-nine OCCs that have been sampled to date contain peridotites. Moreover, peridotites dominate in the plutonic footwall of 77% of OCCs. Massive OCC peridotites come from the very top of the melting column beneath ocean ridges. They are typically spinel harzburgites and show 11.3–18.3% partial melting, generally representing a maximum degree of melting along a segment. Another key feature is the lower frequency of plagioclase-bearing peridotites in the mantle rocks and the lower abundance of plagioclase in the plagioclase-bearing peridotites in comparison to transform peridotites. The presence of plagioclase is usually linked to impregnation with late-stage melt. Based on the above, OCC peridotites away from segment ends and transforms can be treated as a new class of abyssal peridotites that differ from transform peridotites by a higher degree of partial melting and lower interaction with subsequent transient melt.

  4. Rapid extensional unroofing of a granite-migmatite dome with relics of high-pressure rocks, the Podolsko complex, Bohemian Massif

    Czech Academy of Sciences Publication Activity Database

    Žák, J.; Sláma, Jiří; Burjak, M.


    Roč. 154, č. 2 (2017), s. 354-380 ISSN 0016-7568 Institutional support: RVO:67985831 Keywords : anisotropy of magnetic susceptibility (AMS) * granite-migmatite dome * exhumation * metamorphic core complex * U-Pb zircon geochronology Subject RIV: DB - Geology ; Mineralogy OBOR OECD: Geology Impact factor: 1.965, year: 2016

  5. Exploring the GluR2 ligand-binding core in complex with the bicyclical AMPA analogue (S)-4-AHCP

    DEFF Research Database (Denmark)

    Nielsen, Bettina B; Pickering, Darryl S; Greenwood, Jeremy R


    The X-ray structure of the ionotropic GluR2 ligand-binding core (GluR2-S1S2J) in complex with the bicyclical AMPA analogue (S)-2-amino-3-(3-hydroxy-7,8-dihydro-6H-cyclohepta[d]-4-isoxazolyl)propionic acid [(S)-4-AHCP] has been determined, as well as the binding pharmacology of this construct...

  6. Combined Lu-Hf and Sm-Nd geochronology of the Mariánské Lázně Complex: New constraints on the timing of eclogite- and granulite-facies metamorphism (United States)

    Collett, Stephen; Štípská, Pavla; Schulmann, Karel; Peřestý, Vít; Soldner, Jeremie; Anczkiewicz, Robert; Lexa, Ondrej; Kylander-Clark, Andrew


    Lu-Hf and Sm-Nd garnet-whole rock geochronology combined with petrographic observations, minero-chemical variations, thermodynamic modelling and structural data was used to constrain the P-T-t-d evolution of eclogites from the Mariánské Lázně Complex (Bohemian Massif). Boudins of mostly isotropic eclogite with relict steep eclogite-facies fabric are affected by steep migmatitic foliation, which is followed on a regional scale by the development of almost pervasive, predominantly SE-dipping, extensional foliation. The structural succession shows continuous transition from eclogite to garnetiferous migmatitic amphibolite and to amphibolite migmatite. A least retrogressed sample of eclogite shows clusters of fine-grained inclusion-poor garnet, omphacite relicts surrounded by a fine-grained clinopyroxene-plagioclase symplectite with minor amphibole, biotite-plagioclase intergrowths after white mica, kyanite with plagioclase-spinel coronas and accessory rutile. Rare potassic white mica occurs as inclusions in omphacite. A more retrogressed eclogite, with no omphacite or kyanite relicts, contains inclusion-poor garnet surrounded by amphibole-plagioclase corona in a matrix dominated by plagioclase-amphibole symplectite with minor clinopyroxene. In places, the symplectite is overgrown by coarse-grained amphibole. Peak P-T conditions, inferred from combined conventional thermobarometry and phase-equilibria modelling and based on inclusions of white mica (up to 3.33 Si p.f.u.), matrix omphacite (Jd33-36) and garnet core (Alm33-38Prp38-42Grs22-25Sps1) compositions are 25 kbar at 650-750 °C. A HT overprint occurred at 14-18 kbar and >800 °C based on coexisting clinopyroxene (Jd18-24), plagioclase (An18-35), and amphibole (Na(B) textures, calculated P-T conditions, and distinct Lu-Hf and Sm-Nd ages, provide a complete P-T-t-D path characterised by rapid ( 15 Ma) transition from HP subduction, crustal thickening to extensional HT shearing. This unconventional exhumation

  7. Comparative chronology of Archean HT/UHT crustal metamorphism (United States)

    Caddick, Mark; Dragovic, Besim; Guevara, Victor


    Attainment of high crustal heat fluxes and consequent partial melting is critical to the stabilization of continental roots. Understanding the processes and timescales behind partial melting of continental crust in the Archean is thus paramount for understanding Archean tectonic modes and how stable cratons formed. High-temperature (HT) to ultrahigh-temperature (UHT) metamorphic rocks can record evidence for dynamic processes that result in advective heat fluxes and a substantial deviation from normal crustal geothermal gradients. Examination of the pressure-temperature conditions and timescales of HT/UHT metamorphism is thus essential to understanding the tectonic processes behind extreme crust heat fluxes and the formation of stable cratonic crust. Here, utilizing both traditional and nontraditional petrologic and geochronologic techniques, we compare the pressure-temperature-time paths of two Neoarchean terranes: the eastern Beartooth Mountains of the Wyoming Craton and the Pikwitonei Granulite Domain of the Superior Province. The Beartooth Mountains of Montana, USA, expose Archean rocks of the Wyoming Craton that are dominated by an ˜2.8 Ga calc-alkaline granitoid batholith known as the Long Lake Magmatic Complex (LLMC). The LLMC contains widespread, up to km-scale metasedimentary roof pendants, with ID-TIMS Sm-Nd garnet geochronology and laser ablation split stream (LASS) monazite geochronology suggesting that metamorphism occurred almost 100 Ma after entrainment by the LLMC [1]. Phase equilibria modeling and Zr-in-rutile thermometry constrain peak pressures and temperatures of ˜6-7 kbar and ˜780-800˚ C. Major element diffusion modeling of garnet suggest that granulite-facies temperatures were only maintained for a short duration, 150,000 km2 of high-grade metamorphic rocks situated in the NW Superior Province. Phase equilibria modeling and trace element thermometry constrain peak temperatures in the southernmost part of the PGD to ˜760˚ C, while across

  8. Oceanic core complexes in the Philippine Sea: results from Japan's extended continental shelf mapping (United States)

    Ohara, Y.; Yoshida, T.; Nishizawa, A.


    The United Nations Commission on the Limits of the Continental Shelf (CLCS) issued its recommendations on Japan's extended continental shelf in April 2012, confirming Japan's rights over the vast areas within the Philippine Sea and Pacific Plates. Japan submitted information on the limits of its continental shelf beyond the EEZ to the CLCS on November 2008, which was the result of 25 years of nation's continental shelf survey project since 1983, involving all of Japan's agency relevant to geosciences. The huge geological and geophysical data obtained through the project give the scientists unprecedented opportunity to study the geology and tectonics of the Philippine Sea and Pacific Plates. In this contribution, we show such an example from the Philippine Sea Plate, relevant to the global mid-ocean ridge problem. Oceanic core complexes (OCC) are dome-shaped bathymetric highs identified in mid-ocean ridges, interpreted as portions of the lower crust and/or upper mantle denuded via low-angle detachment faulting. OCCs are characterized morphologically by axis-normal striations (corrugations, or mullion structure) on the dome, and exposures of mantle peridotite and/or lower crustal gabbro. A strikingly giant OCC (named 'Godzilla Megamullion') was discovered in the Parece Vela Basin by the continental shelf survey project in 2001. Godzilla Megamullion is morphologically the largest OCC in the world, consisting mainly of fertile mantle peridotite along its entire length of over 125 km. Following its discovery in 2001, several academic cruises investigated the structure in detail, providing numerous important findings relevant to mid-ocean ridge tectono-magmatic processes and Philippine Sea evolution, including the slow- to ultraslow-spreading environment for denudation of the detachment fault (< 2.5 cm/y) and associated decreasing degree of partial melting of the peridotites towards the termination of Godzilla Megamullion. In addition to Godzilla Megamullion, several

  9. Environmental Communication Pedagogy for Sustainability: Developing Core Capacities to Engage with Complex Problems (United States)

    McGreavy, Bridie; Druschke, Caroline Gottschalk; Sprain, Leah; Thompson, Jessica L.; Lindenfeld, Laura A.


    Pedagogy informed by environmental communication can enhance collaboration within and outside the classroom. Through our collaborative, sustainability-focused work within the United States and internationally, we identified core capacities that prepare people to work together to form inclusive organizations and identify and respond to pressing…

  10. Permian high-temperature metamorphism in the Western Alps (NW Italy) (United States)

    Kunz, Barbara E.; Manzotti, Paola; von Niederhäusern, Brigitte; Engi, Martin; Darling, James R.; Giuntoli, Francesco; Lanari, Pierre


    During the late Palaeozoic, lithospheric thinning in part of the Alpine realm caused high-temperature low-to-medium pressure metamorphism and partial melting in the lower crust. Permian metamorphism and magmatism has extensively been recorded and dated in the Central, Eastern, and Southern Alps. However, Permian metamorphic ages in the Western Alps so far are constrained by very few and sparsely distributed data. The present study fills this gap. We present U/Pb ages of metamorphic zircon from several Adria-derived continental units now situated in the Western Alps, defining a range between 286 and 266 Ma. Trace element thermometry yields temperatures of 580-890 °C from Ti-in-zircon and 630-850 °C from Zr-in-rutile for Permian metamorphic rims. These temperature estimates, together with preserved mineral assemblages (garnet-prismatic sillimanite-biotite-plagioclase-quartz-K-feldspar-rutile), define pervasive upper-amphibolite to granulite facies conditions for Permian metamorphism. U/Pb ages from this study are similar to Permian ages reported for the Ivrea Zone in the Southern Alps and Austroalpine units in the Central and Eastern Alps. Regional comparison across the former Adriatic and European margin reveals a complex pattern of ages reported from late Palaeozoic magmatic and metamorphic rocks (and relics thereof): two late Variscan age groups ( 330 and 300 Ma) are followed seamlessly by a broad range of Permian ages (300-250 Ma). The former are associated with late-orogenic collapse; in samples from this study these are weakly represented. Clearly, dominant is the Permian group, which is related to crustal thinning, hinting to a possible initiation of continental rifting along a passive margin.

  11. Highly efficient phosphorescent materials based on Ir(iii) complexes-grafted on a polyhedral oligomeric silsesquioxane core. (United States)

    Yu, Tianzhi; Xu, Zixuan; Su, Wenming; Zhao, Yuling; Zhang, Hui; Bao, Yanjun


    A new iridium(iii) complex containing a coumarin derivative as the cyclometalated ligand (L) and a carbazole-functionalized β-diketonate (Cz-acac-allyl) as the ancillary ligand, namely, Ir(iii) bis(3-(pyridin-2-yl)coumarinato-N,C(4))(1-(9-butyl-9H-carbazol-3-yl)hept-6-ene-1,3-dionato-O,O) [Ir(L)2(Cz-acac-allyl)], was firstly synthesized as the emissive iridium(iii) complex. Then three new phosphorescent polyhedral oligomeric silsesquioxane (POSS) materials, consisting of the emissive Ir(iii) complex and carbazole moieties covalently attached to a polyhedral oligomeric silsesquioxane (POSS) core were successfully synthesized by hydrosilylation reaction in the presence of platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane (Pt-dvs) as the catalyst. These phosphorescent POSS materials offer many advantages including amorphous properties, good thermal stabilities, and good solubility in common solvents, and high purity via column chromatography. The photoluminescence spectra of the POSS materials in solution and in the solid state indicate a reduction in the degrees of interactions among the Ir(iii) complex units and concentration quenching due to the bulky POSS core. Solution processed light-emitting devices based on these phosphorescent POSS materials exhibit a maximum external quantum efficiency (EQE) of 9.77%.

  12. Spatial and temporal variation of heavy metals in sediment cores from the Calcasieu River/Lake Complex

    International Nuclear Information System (INIS)

    Mueller, C.S.; Ramelow, G.J.; Beck, J.N.


    Sediment cores were obtained from several locations in the Calcasieu River/Lake Complex, including Calcasieu Lake, Calcasieu River, two bayou tributaries, and Lake Charles during the period from November 1983 to November 1985. The cores were analyzed for Cu, Zn, Cr, and Pb. The approximate sedimentation rate and a core chronology were determined by the use of 137 Cs and 210 Pb isotopes. The increase in metal concentrations after 1933, particularly along Bayou d'Inde where most industries are located, points to anthropogenic input if these metals to the system. The fact that metal concentrations tend to merge to a common value prior to 1940 throughout the system suggests that geological factors do not contribute to the observed variations in metal concentrations in this area. The background concentrations of heavy metals found in this study for the Calcasieu River/Lake Complex were: Cu (10 mg kg -1 ), Cr (25 mg kg -1 ), Pb (8 mg kg -1 ), and Zn (40 mg kg -1 ). The main emphasis of the study focused along Bayou d'Inde due to the enhanced levels of heavy metals found

  13. Chiral multidentate oxazoline ligands based on cyclophosphazene cores: synthesis, characterization and complexation studies. (United States)

    Kumar, Dheeraj; Singh, Jatinder; Elias, Anil J


    Chiral oxazoline based bi and hexadentate ligands built on cyclophosphazene cores have been synthesized and characterized. (NPPh2)2[NP(m-OC6H4C(O)OCH3)2] (1) was prepared by the reaction of gem-(NPPh2)2(NPCl2) with methyl-3-hydroxy benzoate in the presence of Cs2CO3. Compound 1 was converted to the dicarboxylic acid (NPPh2)2[NP(m-OC6H4C(O)OH)2] (2) by base promoted hydrolysis with KO(t-Bu). The dicarboxylic acid 2 on reaction with oxalyl chloride followed by (S)-(+)-2-amino-3-methyl-1-butanol, triethylamine and mesyl chloride was converted to the C2-symmetric phosphazene based chiral bisoxazoline ligand (NPPh2)2[NP{m-OC6H4(4-iPr-2-Ox)}2] (3) (Ox = oxazolinyl). A similar C2-symmetric bisoxazoline derivative having an oxazoline group attached to the para position of the phenyl ring was also synthesized starting from (NPPh2)2[NP(p-OC6H4C(O)OCH3)2] (4) which was first converted to the dicarboxylic acid (NPPh2)2[NP(p-OC6H4C(O)OH)2] (5) and finally to (NPPh2)2[NP{p-OC6H4(4-iPr-2-Ox)}2] (6) and (NPPh2)2[NP{p-OC6H4(4-Ph-2-Ox)}2] (7) under similar reaction conditions. Reaction of 6 with Pd(OAc)2 in acetic acid at room temperature and with PdCl2(C6H5CN)2 in refluxing benzene resulted in chiral palladium complexes Pd(OAc)2(NPPh2)2[NP{p-OC6H4(4-iPr-2-Ox)}2] (8) and PdCl2(NPPh2)2[NP{p-OC6H4(4-iPr-2-Ox)}2] (9), respectively. The utility of these palladium complexes as chiral catalysts for the asymmetric rearrangement of trichloroacetimidates to trichloroacetamides has been explored. The hexa(methylbenzoate) derivative of cyclophosphazene [PN(OC6H4COOCH3)2]3 (10) on treatment with KO(t-Bu) and H2O gave the hexacarboxylic acid derivative [PN(OC6H4COOH)2]3 (11), which on treatment with oxalyl chloride followed by (S)-(+)-2-amino-3-methyl-1-butanol/(S)-(+)-2-phenylglycinol, triethylamine and mesyl chloride was converted to the C3-symmetric cyclophosphazene based chiral hexaoxazoline ligands [PN{OC6H4(4-iPr-2-Ox)}2]3 (12) and [PN{OC6H4(4-Ph-2-Ox)}2]3 (13). The bis(phebox) derivative

  14. A dense out-of-core solver (DOCS) for complex-valued linear systems

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Cullen E.


    Dense systems of linear equations are quite common in many science and engineering applications. Such linear systems place extreme storage and computational demands on computer resources and, in many cases, may severely limit the subsequent analysis. A dense out-of-core solver (DOCS) that operates on a partitioned coefficient matrix can reduce the in-core storage requirements of the linear system while spreading the associated computational burden over multiple processors (which reduces run time as well). In this report, I describe a DOCS that operates on a partitioned coefficient matrix that maybe distributed over multiple external storage devices. I have implemented this solver using Message-Passing Interface (MPI) protocols. This report presents petiormance data from a series of run time trials that compare the run time of both sequential and parallel implementations of the DOCS.

  15. CoreFlow: A computational platform for integration, analysis and modeling of complex biological data

    DEFF Research Database (Denmark)

    Pasculescu, Adrian; Schoof, Erwin; Creixell, Pau


    A major challenge in mass spectrometry and other large-scale applications is how to handle, integrate, and model the data that is produced. Given the speed at which technology advances and the need to keep pace with biological experiments, we designed a computational platform, CoreFlow, which...... provides programmers with a framework to manage data in real-time. It allows users to upload data into a relational database (MySQL), and to create custom scripts in high-level languages such as R, Python, or Perl for processing, correcting and modeling this data. CoreFlow organizes these scripts...... the next stages of experimentation. Its simple yet powerful interface provides a structure where scripts can be written and tested virtually simultaneously to shorten the life cycle of code development for a particular task. The scripts are exposed at every step so that a user can quickly see...

  16. Metamorphic evolution of the contact aureole of the Jhirgadandi ...

    Indian Academy of Sciences (India)

    The metamorphic evolution of the contact aureole around the Late Paleoproterozoic Jhirgadandi pluton in the eastern part of Parsoi Formation of Mahakoshal terrain, central India represents three distinct metamorphic zones, characterized by definite mineral assemblages. The contact-metamorphic event pro- duced the ...

  17. Synthesis of liquid core-shell particles and solid patchy multicomponent particles by shearing liquids into complex particles (SLICE). (United States)

    Tevis, Ian D; Newcomb, Lucas B; Thuo, Martin


    We report a simple method that uses (i) emulsion shearing with oxidation to make core-shell particles, and (ii) emulsion shearing with surface-tension driven phase segregation to synthesize particles with complex surface compositions and morphologies. Subjecting eutectic gallium-indium, a liquid metal, to shear in an acidic carrier fluid we synthesized smooth liquid core-shell particles 6.4 nm to over 10 μm in diameter. Aggregates of these liquid particles can be reconfigured into larger structures using a focused ion beam. Using Field's metal melts we synthesized homogeneous nanoparticles and solid microparticles with different surface roughness and/or composition through shearing and phase separation. This extension of droplet emulsion technique, SLICE, applies fluidic shear to create micro- and nanoparticles in a tunable, green, and low-cost approach.

  18. Uranium deposits in magmatic and metamorphic rocks

    International Nuclear Information System (INIS)


    The association of uranium with certain types of magmatic and metamorphic rocks is well known. They have consequently been explored and studied quite extensively. In recent years interest in them has been eclipsed by the discovery of larger, lower cost deposits in other geological environments. Nonetheless, magmatic and metamorphic rocks continue to be important sources of uranium and large areas of the Earth's crust with such rocks are prospective locations for additional discoveries. As future exploration and development could be more difficult the full importance of individual deposits may not be recognized until after many years of investigation and experience. In addition to being important host rocks, magmatic and metamorphic rocks have been of considerable interest to uranium geologists as they are considered to be important source rocks for uranium and thus can lead to deposits nearby in other environments. Furthermore, these rocks provide important information on the geochemical cycle of uranium in the Earth's crust and mantle. Such information can lead to identification of uranium provinces and districts and to a basic understanding of processes of formation of uranium deposits. The International Atomic Energy Agency convened a Technical Committee Meeting on Uranium Deposits in Magmatic and Metamorphic Rocks. The meeting was held in Salamanca, Spain, from 29 September to 3 October 1986. It was followed by a two day field trip to uranium deposits in the Ciudad Rodrigo and Don Benito areas. The meeting was attended by 48 participants from 22 countries. Two panels were organized for discussion of the following topics: (1) ore deposit genesis and characterization and (2) exploration and resource assessment. The technical papers together with the panel reports form this publication. The scope and variety of the papers included and the panel reports provide a good coverage of current knowledge and thinking on uranium in magmatic and metamorphic rocks

  19. Monazite behaviours during high-temperature metamorphism: a case study from Dinggye region, Tibetan Himalaya (United States)

    Wang, Jia-Min; Wu, Fu-Yuan; Rubatto, Daniela; Liu, Shi-Ran; Zhang, Jin-Jiang


    Monazite is a key accessory mineral for metamorphic geochronology, but its growth mechanisms during melt-bearing high-temperature metamorphism is not well understood. Therefore, the petrology, pressure-temperature and timing of metamorphism have been investigated in pelitic and psammitic granulites from the Greater Himalayan Crystalline Complex (GHC) in Dinggye, southern Tibet. These rocks underwent an isothermal decompression process from pressure conditions of >10 kbar to armour effect of matrix crystals (biotite and quartz). Most monazite grains formed at the M3-stage (21-19 Ma) through either dissolution-reprecipitation or recrystallization that was related to biotite dehydration melting reaction. These monazite grains record HREE and Y signatures in local equilibrium with different reactions involving either garnet breakdown or peritectic garnet growth. Another peak of monazite growth occurs during melt crystallization ( 15 Ma), and these monazites are unzoned and have homogeneous compositions. Our results documented the widespread recrystallization to account for monazite growth during high-temperature metamorphism and related melting reactions that trigger monazite recrystallization. In a regional sense, our P-T-t data along with published data indicate that the pre-M1 eclogite-facies metamorphism occurred at 39-30 Ma in the Dinggye Himalaya. Our results are in favour of a steady exhumation of the GHC rocks since Oligocene that was contributed by partial melting. Key words: U-Th-Pb geochronology, Monazite, Recrystallization, Pelitic granulite, Himalaya

  20. New 207 Pb/ 206 Pb-Zr minimum evaporation, metamorphic 87 Rb ...

    African Journals Online (AJOL)

    New ages were obtained from charnockites and tonalites collected in the So'o Group in the Ntem Complex. The rocks were analyzed for their petrography, tectonics and 207Pb/206Pb zircon minimum ages of their zircons as well as metamorphic 87Rb/86Sr isochron ages. The charnockites yielded zircon ages with a mean ...

  1. Conservation of core complex subunits shaped the structure and function of photosystem I in the secondary endosymbiont alga Nannochloropsis gaditana. (United States)

    Alboresi, Alessandro; Le Quiniou, Clotilde; Yadav, Sathish K N; Scholz, Martin; Meneghesso, Andrea; Gerotto, Caterina; Simionato, Diana; Hippler, Michael; Boekema, Egbert J; Croce, Roberta; Morosinotto, Tomas


    Photosystem I (PSI) is a pigment protein complex catalyzing the light-driven electron transport from plastocyanin to ferredoxin in oxygenic photosynthetic organisms. Several PSI subunits are highly conserved in cyanobacteria, algae and plants, whereas others are distributed differentially in the various organisms. Here we characterized the structural and functional properties of PSI purified from the heterokont alga Nannochloropsis gaditana, showing that it is organized as a supercomplex including a core complex and an outer antenna, as in plants and other eukaryotic algae. Differently from all known organisms, the N. gaditana PSI supercomplex contains five peripheral antenna proteins, identified by proteome analysis as type-R light-harvesting complexes (LHCr4-8). Two antenna subunits are bound in a conserved position, as in PSI in plants, whereas three additional antennae are associated with the core on the other side. This peculiar antenna association correlates with the presence of PsaF/J and the absence of PsaH, G and K in the N. gaditana genome and proteome. Excitation energy transfer in the supercomplex is highly efficient, leading to a very high trapping efficiency as observed in all other PSI eukaryotes, showing that although the supramolecular organization of PSI changed during evolution, fundamental functional properties such as trapping efficiency were maintained. © 2016 The Authors. New Phytologist © 2016 New Phytologist Trust.

  2. Hyperbranched Phosphorescent Conjugated Polymer Dots with Iridium(III) Complex as the Core for Hypoxia Imaging and Photodynamic Therapy. (United States)

    Feng, Zhiying; Tao, Peng; Zou, Liang; Gao, Pengli; Liu, Yuan; Liu, Xing; Wang, Hua; Liu, Shujuan; Dong, Qingchen; Li, Jie; Xu, Bingshe; Huang, Wei; Wong, Wai-Yeung; Zhao, Qiang


    Real-time monitoring of the contents of molecular oxygen (O 2 ) in tumor cells is of great significance in early diagnosis of cancer. At the same time, the photodynamic therapy (PDT) could be realized by highly toxic singlet oxygen ( 1 O 2 ) generated in situ during the O 2 sensing, making it one of the most promising methods for cancer therapy. Herein, the iridium(III) complex cored hyperbranched phosphorescent conjugated polymer dots with the negative charges for hypoxia imaging and highly efficient PDT was rationally designed and synthesized. The incomplete energy transfer between the polyfluorene and the iridium(III) complexes realized the ratiometric sensing of O 2 for the accurate measurements. Furthermore, the O 2 -dependent emission lifetimes are also used in photoluminescence lifetime imaging and time-gated luminescence imaging for eliminating the autofluorescence remarkably to enhance the signal-to-noise ratio of imaging. Notably, the polymer dots designed could generate the 1 O 2 effectively in aqueous solution, and the image-guided PDT of the cancer cells was successfully realized and investigated in detail by confocal laser scanning microscope. To the best of our knowledge, this represents the first example of the iridium(III) complex cored hyperbranched conjugated polymer dots with the negative charges for both hypoxia imaging and PDT of cancer cells simultaneously.

  3. Exploring molecular complexity with ALMA (EMoCA): Detection of three new hot cores in Sagittarius B2(N) (United States)

    Bonfand, M.; Belloche, A.; Menten, K. M.; Garrod, R. T.; Müller, H. S. P.


    Context. The Sagittarius B2 molecular cloud contains several sites forming high-mass stars. Sgr B2(N) is one of its main centers of activity. It hosts several compact and ultra-compact HII regions, as well as two known hot molecular cores (Sgr B2(N1) and Sgr B2(N2)) in the early stage of the high-mass star formation process, where complex organic molecules (COMs) are detected in the gas phase. Aims: Our goal is to use the high sensitivity of the Atacama Large Millimeter/submillimeter Array (ALMA) to characterize the hot core population in Sgr B2(N) and thereby shed new light on the star formation process in this star-forming region. Methods: We use a complete 3 mm spectral line survey conducted with ALMA to search for faint hot cores in the Sgr B2(N) region. The chemical composition of the detected sources and the column densities are derived by modeling the whole spectra under the assumption of local thermodynamic equilibrium. Population diagrams are constructed to fit rotational temperatures. Integrated intensity maps are produced to derive the peak position and fit the size of each molecule's emission distribution. The kinematic structure of the hot cores is investigated by analyzing the line wing emission of typical outflow tracers. The H2 column densities are computed from ALMA and SMA continuum emission maps. Results: We report the discovery of three new hot cores in Sgr B2(N) that we call Sgr B2(N3), Sgr B2(N4), and Sgr B2(N5). The three sources are associated with class II methanol masers, well known tracers of high-mass star formation, and Sgr B2(N5), also with a UCHII region. Their H2 column densities are found to be between approximately 16 and 36 times lower than the one of the main hot core Sgr B2(N1). The spectra of these new hot cores have spectral line densities of 11 up to 31 emission lines per GHz above the 7σ level, assigned to 22-25 molecules plus 13-20 less abundant isotopologs. We derive rotational temperatures of approximately 140-180 K for


    NARCIS (Netherlands)



    The highly symmetric pyruvate dehydrogenase multienzyme complexes have molecular masses ranging from 5 to 10 million daltons. They consist of numerous copies of three different enzymes: pyruvate dehydrogenase, dihydrolipoyl transacetylase, and lipoamide dehydrogenase. The three-dimensional crystal

  5. Screw dislocations in complex, low symmetry oxides: core structures, energetics, and impact on crystal growth. (United States)

    Shahsavari, Rouzbeh; Chen, Lu


    Determining the atomic structure and the influence of defects on properties of low symmetry oxides have long been an engineering pursuit. Here, we focus on five thermodynamically reversible monoclinic and orthorhombic polymorphs of dicalcium silicates (Ca2SiO3)-a key cement constituent-as a model system and use atomistic simulations to unravel the interplay between the screw dislocation core energies, nonplanar core structures, and Peierls stresses along different crystallographic planes. Among different polymorphs, we found that the α polymorphs (α-C2S) has the largest Peierls stress, corresponding to the most brittle polymorph, which make it attractive for grinding processes. Interestingly, our analyses indicate that this polymorphs has the lowest dislocation core energy, making it ideal for reactivity and crystal growth. Generally, we identified the following order in terms of grinding efficiency based on screw dislocation analysis, α-C2S > αH-C2S > αL-C2S > β-C2S > γ-C2S, and the following order in term of reactivity, α -C2S > αL-C2S > γ-C2S > αH-C2S > β-C2S. This information, combined with other deformation-based mechanisms, such as twinning and edge dislocation, can provide crucial insights and guiding hypotheses for experimentalists to tune the cement grinding mechanisms and reactivity processes for an overall optimum solution with regard to both energy consumption and performance. Our findings significantly broaden the spectrum of strategies for leveraging both crystallographic directions and crystal symmetry to concurrently modulate mechanics and crystal growth processes within an identical chemical composition.

  6. Structure of the exon junction core complex with a trapped DEAD-box ATPase bound to RNA

    DEFF Research Database (Denmark)

    Andersen, Christian Brix Folsted; Ballut, Lionel; Johansen, Jesper Sanderhoff


    exon junction core complex containing the DEAD-box adenosine triphosphatase (ATPase) eukaryotic initiation factor 4AIII (eIF4AIII) bound to an ATP analog, MAGOH, Y14, a fragment of MLN51, and a polyuracil mRNA mimic. eIF4AIII interacts with the phosphate-ribose backbone of six consecutive nucleotides...... and prevents part of the bound RNA from being double stranded. The MAGOH and Y14 subunits lock eIF4AIII in a prehydrolysis state, and activation of the ATPase probably requires only modest conformational changes in eIF4AIII motif I....

  7. Core Transcriptional Regulatory Circuit Controlled by the TAL1 Complex in Human T Cell Acute Lymphoblastic Leukemia


    Sanda, Takaomi; Lawton, Lee N.; Barrasa, M. Inmaculada; Fan, Zi Peng; Kohlhammer, Holger; Gutierrez, Alejandro; Ma, Wenxue; Tatarek, Jessica; Ahn, Yebin; Kelliher, Michelle A.; Jamieson, Catriona H.M.; Staudt, Louis M.; Young, Richard A.; Look, A. Thomas


    The oncogenic transcription factor TAL1/SCL is aberrantly expressed in over 40% of cases of human T-cell acute lymphoblastic leukemia (T-ALL), emphasizing its importance in the molecular pathogenesis of T-ALL. Here we identify the core transcriptional regulatory circuit controlled by TAL1 and its regulatory partners HEB, E2A, LMO1/2, GATA3 and RUNX1. We show that TAL1 forms a positive interconnected auto-regulatory loop with GATA3 and RUNX1, and that the TAL1 complex directly activates the MY...

  8. The Distribution of Complex Organic Molecules in the Orion KL Molecular Core (United States)

    Kuan, Yi-Jehng; Hsu, Yu-Sen; Charnley, Steven B.; Wang, Kuo-Song


    We conducted high angular-resolution observations toward the massive star-forming region Orion KL at 1.3 mm using the Submillimeter Array (SMA). Spectral emission from twelve complex organic molecules was simultaneously imaged. We discuss the distinct chemical characteristics among four sub- regions in Orion KL by comparing the spatial distributions and fractional abundances of these complex molecules. These observations will allow us to test and constrain chemical models of interstellar organic synthesis.

  9. A Genome-Wide Association Study and Complex Network Identify Four Core Hub Genes in Bipolar Disorder. (United States)

    Xie, Zengyan; Yang, Xianyan; Deng, Xiaoya; Ma, Mingyue; Shu, Kunxian


    Bipolar disorder is a common and severe mental illness with unsolved pathophysiology. A genome-wide association study (GWAS) has been used to find a number of risk genes, but it is difficult for a GWAS to find genes indirectly associated with a disease. To find core hub genes, we introduce a network analysis after the GWAS was conducted. Six thousand four hundred fifty eight single nucleotide polymorphisms (SNPs) with p sifted out from Wellcome Trust Case Control Consortium (WTCCC) dataset and mapped to 2045 genes, which are then compared with the protein-protein network. One hundred twelve genes with a degree >17 were chosen as hub genes from which five significant modules and four core hub genes ( FBXL13 , WDFY2 , bFGF , and MTHFD1L ) were found. These core hub genes have not been reported to be directly associated with BD but may function by interacting with genes directly related to BD. Our method engenders new thoughts on finding genes indirectly associated with, but important for, complex diseases.

  10. A Genome-Wide Association Study and Complex Network Identify Four Core Hub Genes in Bipolar Disorder

    Directory of Open Access Journals (Sweden)

    Zengyan Xie


    Full Text Available Bipolar disorder is a common and severe mental illness with unsolved pathophysiology. A genome-wide association study (GWAS has been used to find a number of risk genes, but it is difficult for a GWAS to find genes indirectly associated with a disease. To find core hub genes, we introduce a network analysis after the GWAS was conducted. Six thousand four hundred fifty eight single nucleotide polymorphisms (SNPs with p < 0.01 were sifted out from Wellcome Trust Case Control Consortium (WTCCC dataset and mapped to 2045 genes, which are then compared with the protein–protein network. One hundred twelve genes with a degree >17 were chosen as hub genes from which five significant modules and four core hub genes (FBXL13, WDFY2, bFGF, and MTHFD1L were found. These core hub genes have not been reported to be directly associated with BD but may function by interacting with genes directly related to BD. Our method engenders new thoughts on finding genes indirectly associated with, but important for, complex diseases.

  11. An atomic model AAA-ATPase/20S core particle sub-complex of the 26S proteasome. (United States)

    Förster, Friedrich; Lasker, Keren; Beck, Florian; Nickell, Stephan; Sali, Andrej; Baumeister, Wolfgang


    The 26S proteasome is the most downstream element of the ubiquitin-proteasome pathway of protein degradation. It is composed of the 20S core particle (CP) and the 19S regulatory particle (RP). The RP consists of 6 AAA-ATPases and at least 13 non-ATPase subunits. Based on a cryo-EM map of the 26S proteasome, structures of homologs, and physical protein-protein interactions we derive an atomic model of the AAA-ATPase-CP sub-complex. The ATPase order in our model (Rpt1/Rpt2/Rpt6/Rpt3/Rpt4/Rpt5) is in excellent agreement with the recently identified base-precursor complexes formed during the assembly of the RP. Furthermore, the atomic CP-AAA-ATPase model suggests that the assembly chaperone Nas6 facilitates CP-RP association by enhancing the shape complementarity between Rpt3 and its binding CP alpha subunits partners.

  12. Uranium, rare metals, and granulite-facies metamorphism

    Directory of Open Access Journals (Sweden)

    Michel Cuney


    The Tranomaro metasomatized marbles recrystallizing under granulite-facies conditions represent a demonstrative example of fluid transfer from granulite-facies supracrustals to traps represented by regional scale skarns. Such fluids may be at the origin of the incompatible element enrichment detected in leucosomes of migmatites from St Malo in Brittany (France and Black Hills in South Dakota. The northern French Massif Central provides us with an example of a potential association between incompatible element enrichment of granitic melts and granulite-facies metamorphism. U- and F-enriched fine-grained granites are emplaced along a crustal scale shear zone active during the emplacement within the St Sylvestre peraluminous leucogranitic complex. We propose that during granulite-facies metamorphism dominated by carbonic waves in a deep segment of the continental crust, these shear zones control: (i the percolation of F-, LILE-, rare metal-rich fluids liberated primarily by the breakdown of biotite; (ii the enhancement of partial melting by F-rich fluids at intermediate crustal levels with the generation of F-, LILE-, rare metal-rich granitic melts; (iii their transfer through the crust with protracted fractionation facilitated by their low viscosity due to high F-Li contents; and finally (iv their emplacement as rare metal intrusions at shallow crust levels.

  13. Post-peak metamorphic evolution of the Sumdo eclogite from the Lhasa terrane of southeast Tibet (United States)

    Cao, Dadi; Cheng, Hao; Zhang, Lingmin; Wang, Ke


    A reconstruction of the pressure-temperature-time (P-T-t) path of high-pressure eclogite-facies rocks in subduction zones may reveal important information about the tectono-metamorphic processes that occur at great depths along the plate interface. The majority of studies have focused on prograde to peak metamorphism of these rocks, whereas after-peak metamorphism has received less attention. Herein, we present a detailed petrological, pseudosection modeling and radiometric dating study of a retrograded eclogite sample from the Sumdo ultrahigh pressure belt of the Lhasa terrane, Tibet. Mineral chemical variations, textural discontinuities and thermodynamic modeling suggest that the eclogite underwent an exhumation-heating period. Petrographic observations and phase equilibria modeling suggest that the garnet cores formed at the pressure peak (∼2.5 GPa and ∼520 °C) within the lawsonite eclogite-facies and garnet rims (∼1.5 GPa and spans an interval of ∼7 million years, which is a minimum estimate of the duration of the eclogite-facies metamorphism of the Sumdo eclogite.

  14. Recommendations for a first Core Outcome Measurement set for complex regional PAin syndrome Clinical sTudies (COMPACT). (United States)

    Grieve, Sharon; Perez, Roberto S G M; Birklein, Frank; Brunner, Florian; Bruehl, Stephen; Harden, R Norman; Packham, Tara; Gobeil, Francois; Haigh, Richard; Holly, Janet; Terkelsen, Astrid; Davies, Lindsay; Lewis, Jennifer; Thomassen, Ilona; Connett, Robyn; Worth, Tina; Vatine, Jean-Jacques; McCabe, Candida S


    Complex regional pain syndrome (CRPS) is a persistent pain condition that remains incompletely understood and challenging to treat. Historically, a wide range of different outcome measures have been used to capture the multidimensional nature of CRPS. This has been a significant limiting factor in the advancement of our understanding of the mechanisms and management of CRPS. In 2013, an international consortium of patients, clinicians, researchers, and industry representatives was established, to develop and agree on a minimum core set of standardised outcome measures for use in future CRPS clinical research, including but not limited to clinical trials within adult populations. The development of a core measurement set was informed through workshops and supplementary work, using an iterative consensus process. "What is the clinical presentation and course of CRPS, and what factors influence it?" was agreed as the most pertinent research question that our standardised set of patient-reported outcome measures should be selected to answer. The domains encompassing the key concepts necessary to answer the research question were agreed as follows: pain, disease severity, participation and physical function, emotional and psychological function, self-efficacy, catastrophizing, and patient's global impression of change. The final core measurement set included the optimum generic or condition-specific patient-reported questionnaire outcome measures, which captured the essence of each domain, and 1 clinician-reported outcome measure to capture the degree of severity of CRPS. The next step is to test the feasibility and acceptability of collecting outcome measure data using the core measurement set in the CRPS population internationally.

  15. Chemodynamics of metal ion complexation by charged nanoparticles: a dimensionless rationale for soft, core-shell and hard particle types. (United States)

    Duval, Jérôme F L


    Soft nanoparticulate complexants are defined by a spatial confinement of reactive sites and electric charges inside their 3D body. In turn, their reactivity with metal ions differs significantly from that of simple molecular ligands. A revisited form of the Eigen mechanism recently elucidated the processes leading to metal/soft particle pair formation. Depending on e.g. particle size and metal ion nature, chemodynamics of nanoparticulate metal complexes is controlled by metal conductive diffusion to/from the particles, by intraparticulate complex formation/dissociation kinetics, or by both. In this study, a formalism is elaborated to achieve a comprehensive and systematic identification of the rate-limiting step governing the overall formation and dissociation of nanoparticulate metal complexes. The theory covers the different types of spherical particulate complexants, i.e. 3D soft/permeable and core-shell particles, and hard particles with reactive sites at the surface. The nature of the rate-limiting step is formulated by a dynamical criterion involving a power law function of the ratio between particle radius and an intraparticulate reaction layer thickness defined by the key electrostatic, diffusional and kinetic components of metal complex formation/dissociation. The analysis clarifies the intertwined contributions of particle properties (size, soft or hard type, charge, density or number of reactive sites) and aqueous metal ion dehydration kinetics in defining the chemodynamic behavior of nanoparticulate metal complexes. For that purpose, fully parameterized chemodynamic portraits involving the defining features of particulate ligand and metal ion as well as the physicochemical conditions in the local intraparticulate environment, are constructed and thoroughly discussed under conditions of practical interest.

  16. Shape Metamorphism Using p-Laplacian Equation

    Energy Technology Data Exchange (ETDEWEB)

    Cong, Ge; Esser, Mehmet; Parvin, Bahram; Bebis, George


    We present a new approach for shape metamorphism, which is a process of gradually changing a source shape (known) through intermediate shapes (unknown) into a target shape (known). The problem, when represented with implicit scalar function, is under-constrained, and regularization is needed. Using the p-Laplacian equation (PLE), we generalize a series of regularization terms based on the gradient of the implicit function, and we show that the present methods lack additional constraints for a more stable solution. The novelty of our approach is in the deployment of a new regularization term when p --> infinity which leads to the infinite Laplacian equation (ILE). We show that ILE minimizes the supremum of the gradient and prove that it is optimal for metamorphism since intermediate solutions are equally distributed along their normal direction. Applications of the proposed algorithm for 2D and 3D objects are demonstrated.

  17. Growing Languages with Metamorphic Syntax Macros

    DEFF Research Database (Denmark)

    Brabrand, Claus; Schwartzbach, Michael Ignatieff


    "From now on, a main goal in designing a language should be to plan for growth." Guy Steele: Growing a Language, OOPSLA '98 invited talk.We present our experiences with a syntax macro language which we claim forms a general abstraction mechanism for growing (domain-specific) extensions of program......"From now on, a main goal in designing a language should be to plan for growth." Guy Steele: Growing a Language, OOPSLA '98 invited talk.We present our experiences with a syntax macro language which we claim forms a general abstraction mechanism for growing (domain-specific) extensions...... of programming languages. Our syntax macro language is designed to guarantee type safety and termination.A concept of metamorphisms allows the arguments of a macro to be inductively defined in a meta level grammar and morphed into the host language. We also show how the metamorphisms can be made to operate...

  18. Human Cytomegalovirus Nuclear Capsids Associate with the Core Nuclear Egress Complex and the Viral Protein Kinase pUL97. (United States)

    Milbradt, Jens; Sonntag, Eric; Wagner, Sabrina; Strojan, Hanife; Wangen, Christina; Lenac Rovis, Tihana; Lisnic, Berislav; Jonjic, Stipan; Sticht, Heinrich; Britt, William J; Schlötzer-Schrehardt, Ursula; Marschall, Manfred


    The nuclear phase of herpesvirus replication is regulated through the formation of regulatory multi-component protein complexes. Viral genomic replication is followed by nuclear capsid assembly, DNA encapsidation and nuclear egress. The latter has been studied intensely pointing to the formation of a viral core nuclear egress complex (NEC) that recruits a multimeric assembly of viral and cellular factors for the reorganization of the nuclear envelope. To date, the mechanism of the association of human cytomegalovirus (HCMV) capsids with the NEC, which in turn initiates the specific steps of nuclear capsid budding, remains undefined. Here, we provide electron microscopy-based data demonstrating the association of both nuclear capsids and NEC proteins at nuclear lamina budding sites. Specifically, immunogold labelling of the core NEC constituent pUL53 and NEC-associated viral kinase pUL97 suggested an intranuclear NEC-capsid interaction. Staining patterns with phospho-specific lamin A/C antibodies are compatible with earlier postulates of targeted capsid egress at lamina-depleted areas. Important data were provided by co-immunoprecipitation and in vitro kinase analyses using lysates from HCMV-infected cells, nuclear fractions, or infectious virions. Data strongly suggest that nuclear capsids interact with pUL53 and pUL97. Combined, the findings support a refined concept of HCMV nuclear trafficking and NEC-capsid interaction.

  19. Assembly and stoichiometry of the core structure of the bacterial flagellar type III export gate complex. (United States)

    Fukumura, Takuma; Makino, Fumiaki; Dietsche, Tobias; Kinoshita, Miki; Kato, Takayuki; Wagner, Samuel; Namba, Keiichi; Imada, Katsumi; Minamino, Tohru


    The bacterial flagellar type III export apparatus, which is required for flagellar assembly beyond the cell membranes, consists of a transmembrane export gate complex and a cytoplasmic ATPase complex. FlhA, FlhB, FliP, FliQ, and FliR form the gate complex inside the basal body MS ring, although FliO is required for efficient export gate formation in Salmonella enterica. However, it remains unknown how they form the gate complex. Here we report that FliP forms a homohexameric ring with a diameter of 10 nm. Alanine substitutions of conserved Phe-137, Phe-150, and Glu-178 residues in the periplasmic domain of FliP (FliPP) inhibited FliP6 ring formation, suppressing flagellar protein export. FliO formed a 5-nm ring structure with 3 clamp-like structures that bind to the FliP6 ring. The crystal structure of FliPP derived from Thermotoga maritia, and structure-based photo-crosslinking experiments revealed that Phe-150 and Ser-156 of FliPP are involved in the FliP-FliP interactions and that Phe-150, Arg-152, Ser-156, and Pro-158 are responsible for the FliP-FliO interactions. Overexpression of FliP restored motility of a ∆fliO mutant to the wild-type level, suggesting that the FliP6 ring is a functional unit in the export gate complex and that FliO is not part of the final gate structure. Copurification assays revealed that FlhA, FlhB, FliQ, and FliR are associated with the FliO/FliP complex. We propose that the assembly of the export gate complex begins with FliP6 ring formation with the help of the FliO scaffold, followed by FliQ, FliR, and FlhB and finally FlhA during MS ring formation.

  20. Polyphase white mica growth in low-grade metapelites from La Cébila Metamorphic Complex (Famatinian Belt, Argentina: evidence from microstructural and XRD investigations Crecimiento polifásico de mica blanca en metapelitas de bajo grado del Complejo Metamórfico La Cébila (Faja Famatiniana, Argentina: evidencias a partir de investigaciones microestructurales y de DRX

    Directory of Open Access Journals (Sweden)

    Sebastián O Verdecchia


    Full Text Available Two tectono-thermal metamorphic events, M1-D1 (S1, with associated white mica and chlorite: WM1-Chl1 and M2-D2 (S2, with development of WM2-Chl2, are established from polyphase white mica growth for low-grade units from the Ordovician metasedimentary successions of La Cébila Metamorphic Complex in the Famatinian belt (western-central Argentina. The thermobarometric characterization of the M1 main event was carried out by means of clay-mineral analysis and crystallo-chemical parameter measurements. Epizonal (temperatures between 300 and 400°C and low-pressure conditions are suggested for M1 event, based in Kübler index values ranging from 0.23 to 0.17 A°20, white mica b parameter values between 9.004 and 9.022 Á (mean of 9.014 Á, n=16 and Si contents between 3.13-3.29 a.p.f.u. Temperatures of ~180-270°C are estimated for the M2 event, with Kübler index values ranging from 0.31 to 0.46 A°20. The M1-D1 event of La Cébila could be linked to high-strain heating tectono-metamorphic Ordovician regime recorded in others complexes from Famatinian foreland region of Sierras Pampeanas.Dos eventos tectono-metamórficos fueron establecidos a partir de la blastesis superpuesta de mica blanca en sucesiones metasedimentarias ordovícicas de bajo grado del Complejo Metamórfico La Cébila, cinturón Famati-niano (centro oeste de Argentina: M1-D1 (S1, con blastesis asociada de mica blanca y clorita: WM1-Chl1 y M2-D2 (S2, con desarrollo de WM2-Chl2. La caracterización termobarométrica del evento principal M1 fue llevada a cabo a través del análisis de minerales de arcilla y de la medición de parámetros cristaloquímicos. Las condiciones de epizona con temperaturas entre 300 y 400°C, y baja presión fueron estimadas para el evento M1 sobre la base de valores de índice de Kübler de 0,23 a 0,17 A°20, parámetro b de la mica blanca entre 9,004 y 9,022 Á (valor medio de 9,014 Á, n=16 y contenidos de Si entre 3,13-3,29 a.p.f.u. Se estimaron

  1. Geometric description and analysis of metamorphic tectonites (Pelagonian Zone, Internal Hellenides, Northern Greece) (United States)

    Diamantopoulos, A.


    An assortment of alpine and pre-Permian metamorphic tectonites, belonging to the Pelagonian Zone of the Internal Hellenides, are analyzed from Askion, Vernon and Vorras mountains. They in fact compose the Upper plate of the Western Macedonia core complex, overlying Late Tertiary high-P rocks through large-scale detachment fautls (Diamantopoulos et al. 2007). This work wants to determine the architecture and the kinematic path of rocks in a 3D assumption. Field analysis concludes: a) Meta-sedimentary lithologies and amphibolites, meta-igneous lithologies, granitoid mylonites composed of augen fieldspar gneisses, Permo-Triassic fossiliferous rocks, meta-carbonates of Triassic-Jurassic age, a Jurassic mélange including meta-sedimentary lithologies, serpentinites and carbonate tectonic blocks, Mesozoic Ophiolites, Cretaceous limestones and conglomerates as well as flysch sediments compose the architecture of the study area, b) Multiple high and low-angle cataclastic zones of intense non-coaxial strain separate distinct pre-Permian lithologies, alpine from pre-alpine rocks, Triassic-Jurassic rocks from Permo-Triassic rocks, Jurassic mélange from flysch sediments, Jurassic mélange from Triassic-Jurassic rocks, Cretaceous rocks from the Jurassic mélange, Cretaceous limestones from flysch lithologies and Cretaceous rocks from serpentinites, c) Geometric analysis and description of asymmetric structures found in fault cores, damage zones and in the footwall-related rocks showed a prominent kinematic direction towards WSW in low-T conditions affected all the rock lithologies, d) Multiple S- and L- shape fabric elements in the pre-Permian and Permo-Triassic rocks appear an intricate orientation, produced by intense non-coaxial syn-metamorphic deformation, e) Sheath and isoclinal folds oriented parallel to the L-shape fabric elements as well as a major S-shape fabric element, producing macroscopic fold-like structures compose the main syn-metamorphic fabric elements in the

  2. Dual core processing: MRB1 is an emerging kinetoplast RNA editing complex

    Czech Academy of Sciences Publication Activity Database

    Hashimi, Hassan; Zimmer, S.L.; Ammerman, M. L.; Read, L. K.; Lukeš, Julius


    Roč. 29, č. 2 (2013), s. 91-99 ISSN 1471-4922 R&D Projects: GA ČR GAP305/12/2261; GA ČR GA204/09/1667 Institutional support: RVO:60077344 Keywords : kinetoplastida * trypanosome * RNA editing * protein complexes * RECC * MRB1 Subject RIV: EB - Genetics ; Molecular Biology Impact factor: 6.217, year: 2013

  3. High-Resolution Side-Scan Sonar Map of the Mid-Atlantic Ridge 30N Core Complex (United States)

    Morgan, J.; Blackman, D.; Cann, J.


    During the MARVEL2000 cruise to the Mid-Atlantic Ridge in November-December last year, we obtained detailed side-scan sonar coverage of the summit area of the oceanic core complex in the eastern inside corner of the Atlantis Transform, centred on 30o 08' N, 42o08'W. The survey was conducted with the DSL 120 deep-towed side-scan instrument, with a spatial resolution of about 2m. The map shows clearly the structure of the striations on top of the core complex, which cover a gently-domed area of about 5 x 10 km, including the summit of the massif. The volcanic morphology of the adjacent hanging-wall block is defined in several areas, including two flat-topped seamounts, typical of those observed on the floor of the median valley. A patch of volcanic morphology, perhaps representing an outlier of the hanging-wall, can be seen in one place on top of the striated surface. Towards the south-west of the summit of the massif is an area of irregular topography, covered with a complex pattern of lineations, apparently representing intersection of planar features striking at a wide range of orientations with the sea floor. Some of these planar features could be vertical, and others dip at varying angles. Hydrothermal chimneys of the Lost City vent site, on the edge of the southern summit scarp are imaged over an area about 200m across, though part of this region coincides with the track nadir so we cannot rule out a somewhat greater extent of activity. No other vent sites have yet been identified on the summit of the massif. On the eastern side of the massif, towards the median valley, are a number of scarps that show signs of recent activity. We are not able to map the boundary between the domal core (the footwall) and the hanging wall directly. It is possible that a break in slope marks this boundary. One of the recently active scarps is short and steep and would be on the footwall, so defined . The others are faults up to several kilometres long, of very small throw, that

  4. Core regulatory network motif underlies the ocellar complex patterning in Drosophila melanogaster (United States)

    Aguilar-Hidalgo, D.; Lemos, M. C.; Córdoba, A.


    During organogenesis, developmental programs governed by Gene Regulatory Networks (GRN) define the functionality, size and shape of the different constituents of living organisms. Robustness, thus, is an essential characteristic that GRNs need to fulfill in order to maintain viability and reproducibility in a species. In the present work we analyze the robustness of the patterning for the ocellar complex formation in Drosophila melanogaster fly. We have systematically pruned the GRN that drives the development of this visual system to obtain the minimum pathway able to satisfy this pattern. We found that the mechanism underlying the patterning obeys to the dynamics of a 3-nodes network motif with a double negative feedback loop fed by a morphogenetic gradient that triggers the inhibition in a French flag problem fashion. A Boolean modeling of the GRN confirms robustness in the patterning mechanism showing the same result for different network complexity levels. Interestingly, the network provides a steady state solution in the interocellar part of the patterning and an oscillatory regime in the ocelli. This theoretical result predicts that the ocellar pattern may underlie oscillatory dynamics in its genetic regulation.

  5. Evidence that the assembly of the yeast cytochrome bc1 complex involves the formation of a large core structure in the inner mitochondrial membrane. (United States)

    Zara, Vincenzo; Conte, Laura; Trumpower, Bernard L


    The assembly status of the cytochrome bc(1) complex has been analyzed in distinct yeast deletion strains in which genes for one or more of the bc(1) subunits were deleted. In all the yeast strains tested, a bc(1) sub-complex of approximately 500 kDa was found when the mitochondrial membranes were analyzed by blue native electrophoresis. The subsequent molecular characterization of this sub-complex, carried out in the second dimension by SDS/PAGE and immunodecoration, revealed the presence of the two catalytic subunits, cytochrome b and cytochrome c(1), associated with the noncatalytic subunits core protein 1, core protein 2, Qcr7p and Qcr8p. Together, these bc(1) subunits build up the core structure of the cytochrome bc(1) complex, which is then able to sequentially bind the remaining subunits, such as Qcr6p, Qcr9p, the Rieske iron-sulfur protein and Qcr10p. This bc(1) core structure may represent a true assembly intermediate during the maturation of the bc(1) complex; first, because of its wide distribution in distinct yeast deletion strains and, second, for its characteristics of stability, which resemble those of the intact homodimeric bc(1) complex. By contrast, the bc(1) core structure is unable to interact with the cytochrome c oxidase complex to form respiratory supercomplexes. The characterization of this novel core structure of the bc(1) complex provides a number of new elements clarifying the molecular events leading to the maturation of the yeast cytochrome bc(1) complex in the inner mitochondrial membrane.

  6. Evidence that assembly of the yeast cytochrome bc1 complex involves formation of a large core structure in the inner mitochondrial membrane (United States)

    Zara, Vincenzo; Conte, Laura; Trumpower, Bernard L.


    The assembly status of the cytochrome bc1 complex has been analyzed in distinct yeast deletion strains in which genes for one or more of the bc1 subunits had been deleted. In all the yeast strains tested a bc1 sub-complex of about 500 kDa was found when the mitochondrial membranes were analyzed by blue native electrophoresis. The subsequent molecular characterization of this sub-complex, carried out in the second dimension by SDS-PAGE and immunodecoration, revealed the presence of the two catalytic subunits cytochrome b and cytochrome c1, associated with the non catalytic subunits core protein 1, core protein 2, Qcr7p and Qcr8p. Altogether these bc1 subunits build up the core structure of the cytochrome bc1 complex which is then able to sequentially bind the remaining subunits, such as Qcr6p, Qcr9p, the Rieske iron-sulfur protein and Qcr10p. This bc1 core structure may represent a true assembly intermediate during the maturation of the bc1 complex, first because of its wide distribution in distinct yeast deletion strains and second for its characteristics of stability which resemble those of the intact homodimeric bc1 complex. Differently from this latter, however, the bc1 core structure is not able to interact with the cytochrome c oxidase complex to form respiratory supercomplexes. The characterization of this novel core structure of the bc1 complex provides a number of new elements for clarification of the molecular events leading to the maturation of the yeast cytochrome bc1 complex in the inner mitochondrial membrane. PMID:19236481

  7. Core-Shell Soy Protein-Soy Polysaccharide Complex (Nano)particles as Carriers for Improved Stability and Sustained Release of Curcumin. (United States)

    Chen, Fei-Ping; Ou, Shi-Yi; Tang, Chuan-He


    Using soy protein isolate (SPI) and soy-soluble polysaccharides (SSPS) as polymer matrixes, this study reported a novel process to fabricate unique core-shell complex (nano)particles to perform as carriers for curcumin (a typical poorly soluble bioactive). In the process, curcumin-SPI nanocomplexes were first formed at pH 7.0 and then coated by SSPS. At this pH, the core-shell complex was formed in a way the SPI nanoparticles might be incorporated into the interior of SSPS molecules without distinctly affecting the size and morphology of particles. The core-shell structure was distinctly changed by adjusting pH from 7.0 to 4.0. At pH 4.0, SSPS was strongly bound to the surface of highly aggregated SPI nanoparticles, and as a consequence, much larger complexes were formed. The bioaccessibility of curcumin in the SPI-curcumin complexes was unaffected by the SSPS coating. However, the core-shell complex formation greatly improved the thermal stability and controlled release properties of encapsulated curcumin. The improvement was much better at pH 4.0 than that at pH 7.0. All of the freeze-dried core-shell complex preparations exhibited good redispersion behavior. The findings provide a simple approach to fabricate food-grade delivery systems for improved water dispersion, heat stability, and even controlled release of poorly soluble bioactives.

  8. Cyanthiwigin Natural Product Core as a Complex Molecular Scaffold for Comparative Late-Stage C-H Functionalization Studies. (United States)

    Kim, Kelly E; Adams, Ashley M; Chiappini, Nicholas D; Du Bois, J; Stoltz, Brian M


    The desire for maximally efficient transformations in complex molecule synthesis has contributed to a surge of interest in C-H functionalization methods development in recent years. In contrast to the steady stream of methodological reports, however, there are noticeably fewer studies comparing the efficacies of different C-H functionalization protocols on a single structurally intricate substrate. Recognizing the importance of heteroatom incorporation in complex molecule synthesis, this report discloses a comparative examination of diverse strategies for C-O, C-N, and C-X bond formation through late-stage C-H oxidation of the tricyclic cyanthiwigin natural product core. Methods for allylic C-H acetoxylation, tertiary C-H hydroxylation, tertiary C-H amination, tertiary C-H azidation, and secondary C-H halogenation are explored. These efforts highlight the robustness and selectivities of many well-established protocols for C-H oxidation when applied to a complex molecular framework, and the findings are relevant to chemists aiming to employ such strategies in the context of chemical synthesis.

  9. LA-ICP-MS trace element mapping: insights into the crystallisation history of a metamorphic garnet population (United States)

    George, Freya; Gaidies, Fred


    In comparison to our understanding of major element zoning, relatively little is known about the incorporation of trace elements into metamorphic garnet. Given their extremely slow diffusivities and sensitivity to changing mineral assemblages, the analysis of the distribution of trace elements in garnet has the potential to yield a wealth of information pertaining to interfacial attachment mechanisms during garnet crystallisation, the mobility of trace elements in both garnet and the matrix, and trace element geochronology. Due to advances in the spatial resolution and analytical precision of modern microbeam techniques, small-scale trace element variations can increasingly be documented and used to inform models of metamorphic crystallisation. Laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) in particular, can be used to rapidly quantify a wide range of elemental masses as a series of laser rasters, producing large volumes of spatially constrained trace element data. In this study, we present LA-ICP-MS maps of trace element concentrations from numerous centrally-sectioned garnets representative of the crystal size-distribution of a single sample's population. The study sample originates from the garnet-grade Barrovian zone of the Lesser Himalayan Sequence in Sikkim, northeast India, and has been shown to have crystallised garnet within a single assemblage between 515 ˚C and 565˚C, with no evidence for accessory phase reaction over the duration of garnet growth. Previous models have indicated that the duration of garnet crystallisation was extremely rapid (growth. In spite of straightforward (i.e. concentrically-zoned) major element garnet zonation, trace elements maps are characterised by significant complexity and variability. Y and the heavy rare earth elements are strongly enriched in crystal cores, where there is overprinting of the observed internal fabric, and exhibit numerous concentric annuli towards crystal rims. Conversely, the

  10. Perplexing cooperative folding and stability of a low-sequence complexity, polyproline 2 protein lacking a hydrophobic core. (United States)

    Gates, Zachary P; Baxa, Michael C; Yu, Wookyung; Riback, Joshua A; Li, Hui; Roux, Benoît; Kent, Stephen B H; Sosnick, Tobin R


    The burial of hydrophobic side chains in a protein core generally is thought to be the major ingredient for stable, cooperative folding. Here, we show that, for the snow flea antifreeze protein (sfAFP), stability and cooperativity can occur without a hydrophobic core, and without α-helices or β-sheets. sfAFP has low sequence complexity with 46% glycine and an interior filled only with backbone H-bonds between six polyproline 2 (PP2) helices. However, the protein folds in a kinetically two-state manner and is moderately stable at room temperature. We believe that a major part of the stability arises from the unusual match between residue-level PP2 dihedral angle bias in the unfolded state and PP2 helical structure in the native state. Additional stabilizing factors that compensate for the dearth of hydrophobic burial include shorter and stronger H-bonds, and increased entropy in the folded state. These results extend our understanding of the origins of cooperativity and stability in protein folding, including the balance between solvent and polypeptide chain entropies.

  11. Core transcriptional regulatory circuit controlled by the TAL1 complex in human T cell acute lymphoblastic leukemia. (United States)

    Sanda, Takaomi; Lawton, Lee N; Barrasa, M Inmaculada; Fan, Zi Peng; Kohlhammer, Holger; Gutierrez, Alejandro; Ma, Wenxue; Tatarek, Jessica; Ahn, Yebin; Kelliher, Michelle A; Jamieson, Catriona H M; Staudt, Louis M; Young, Richard A; Look, A Thomas


    The oncogenic transcription factor TAL1/SCL is aberrantly expressed in over 40% of cases of human T cell acute lymphoblastic leukemia (T-ALL), emphasizing its importance in the molecular pathogenesis of T-ALL. Here we identify the core transcriptional regulatory circuit controlled by TAL1 and its regulatory partners HEB, E2A, LMO1/2, GATA3, and RUNX1. We show that TAL1 forms a positive interconnected autoregulatory loop with GATA3 and RUNX1 and that the TAL1 complex directly activates the MYB oncogene, forming a positive feed-forward regulatory loop that reinforces and stabilizes the TAL1-regulated oncogenic program. One of the critical downstream targets in this circuitry is the TRIB2 gene, which is oppositely regulated by TAL1 and E2A/HEB and is essential for the survival of T-ALL cells. Copyright © 2012 Elsevier Inc. All rights reserved.

  12. Alkali control of high-grade metamorphism and granitization

    Directory of Open Access Journals (Sweden)

    Oleg G. Safonov


    Full Text Available We review petrologic observations of reaction textures from high-grade rocks that suggest the passage of fluids with variable alkali activities. Development of these reaction textures is accompanied by regular compositional variations in plagioclase, pyroxenes, biotite, amphibole and garnet. The textures are interpreted in terms of exchange and net-transfer reactions controlled by the K and Na activities in the fluids. On the regional scale, these reactions operate in granitized, charnockitized, syenitized etc. shear zones within high-grade complexes. Thermodynamic calculations in simple chemical systems show that changes in mineral assemblages, including the transition from the hydrous to the anhydrous ones, may occur at constant pressure and temperature due only to variations in the H2O and the alkali activities. A simple procedure for estimating the activity of the two major alkali oxides, K2O and Na2O, is implemented in the TWQ software. Examples of calculations are presented for well-documented dehydration zones from South Africa, southern India, and Sri Lanka. The calculations have revealed two end-member regimes of alkalis during specific metamorphic processes: rock buffered, which is characteristic for the precursor rocks containing two feldspars, and fluid-buffered for the precursor rocks without K-feldspar. The observed reaction textures and the results of thermodynamic modeling are compared with the results of available experimental studies on the interaction of the alkali chloride and carbonate-bearing fluids with metamorphic rocks at mid-crustal conditions. The experiments show the complex effect of alkali activities in the fluid phase on the mineral assemblages. Both thermodynamic calculations and experiments closely reproduce paragenetic relations theoretically predicted by D.S. Korzhinskii in the 1940s.

  13. Ostwald ripening of clays and metamorphic minerals (United States)

    Eberl, D.D.; Srodon, J.; Kralik, M.; Taylor, B.E.; Peterman, Z.E.


    Analyses of particle size distributions indicate that clay minerals and other diagenetic and metamorphic minerals commonly undergo recrystallization by Ostwald ripening. The shapes of their particle size distributions can yield the rate law for this process. One consequence of Ostwald ripening is that a record of the recrystallization process is preserved in the various particle sizes. Therefore, one can determine the detailed geologic history of clays and other recrystallized minerals by separating, from a single sample, the various particle sizes for independent chemical, structural, and isotopic analyses.

  14. Tectonic origin and deformation process of the Mayer Kangri medium-high pressure metamorphic dome in Central Qiangtang of Tibet (United States)

    Wang, Y.; Liang, X.


    The metamorphic characteristics, deformation process, geochronology of the medium-high pressure metamorphic rocks in blueschist bearing Central Qiangtang Metamorphic belt (CQMB) of Tibet were less well constrained. It is, however, commonly assumed that these rock slices in the margin also contain important implications on the evolution of the entire metamorphic belt. The well-exposed Mayer Kangri medium-high pressure metamorphic dome in north flank of the CQMB provides an unique opportunity to investigate the outer part of the CQMB, which could facilitate the study on the subduction-exhumation-post orogenic scenarios of the Triassic accretionary orogeny in Central Qiangtang. Field structural analyses indicate the Mayer Kangri metamorphic dome are bounded by low-angle normal faults (LANF) within the hanging wall of low-green schist facies mélange. It majorly consists of epidote-amphibolites, quartz-phengite schist, epidote-albite schist. The outcrop and micro structural observations of footwall metamorphic rocks show an open anticline with multiple foliation replacement, which largely differentiate themselves from the dextral strike-slip shearing of the hanging wall. Well-zoned amphiboles were found within the epidote-amphibolite after micro-structural observations and electron probe microanalyses (EPMA), which indicate that the amphibole zonation demonstrates a Hastingsite core, a Ferro-actinolite mantle and a Ferro-winchite rim in most cases. The mean temperature and pressure estimates of the zoned amphibolites change from 544 °, 0.98Gpa in the core, to 426°, 0.34Gpa in the mantle, and to ca.364° and 0.70 GPa in the rim. The detailed analyses on the stepwise-heating Ar-Ar results of the zoned amphiboles provide good constrains on the episodic deformation process of the CQMB. For Hast-cores, we obtained near plateau ages of 242.4-241.2 Ma, indicating the onset of the oceanic subduction is earlier than the Anisian stage of Middle Triassic. The subsequent

  15. Accessories after the facts: Constraining the timing, duration and conditions of high-temperature metamorphic processes (United States)

    Taylor, Richard J. M.; Kirkland, Christopher L.; Clark, Chris


    High-temperature metamorphic rocks are the result of numerous chemical and physical processes that occur during a potentially long-lived thermal evolution. These rocks chart the sequence of events during an orogenic episode including heating, cooling, exhumation and melt interaction, all of which may be interpreted through the elemental and isotopic characteristics of accessory minerals such as zircon, monazite and rutile. Developments in imaging and in situ chemical analysis have resulted in an increasing amount of information being extracted from these accessory phases. The refractory nature of these minerals, combined with both their use as geochronometers and tracers of metamorphic mineral reactions, has made them the focus of many studies of granulite-facies terrains. In such studies the primary aim is often to determine the timing and conditions of the peak of metamorphism, and high-temperature metasedimentary rocks may seem ideal for this purpose. For example pelites typically contain an abundance of accessory minerals in a variety of bulk compositions, are melt-bearing, and may have endured extreme conditions that facilitate diffusion and chemical equilibrium. However complexities arise due to the heterogeneous nature of these rocks on all scales, driven by both the composition of the protolith and metamorphic differentiation. In additional to lithological heterogeneity, the closure temperatures for both radiogenic isotopes and chemical thermometers vary between different accessory minerals. This apparent complexity can be useful as it permits a wide range of temperature and time (T-t) information to be recovered from a single rock sample. In this review we cover: 1) characteristic internal textures of accessory minerals in high temperature rocks; 2) the interpretation of zircon and monazite age data in relation to high temperature processes; 3) rare earth element partitioning; 4) trace element thermometry; 5) the incorporation of accessory mineral growth

  16. Cooling history of the Sanbagawa metamorphic belt inferred from fission track zircon ages (United States)

    Shinjoe, H.; Tagami, T.


    The Sanbagawa metamorphic belt in central Shikoku, Japan, is a classic example of a high-pressure, intermediate facies series metamorphic belt. The lowest structural horizon of the Sanbagawa belt exposed in central Shikoku is the Oboke unit and this is overlain by the Besshi unit, which contains high-grade mineral zones. Seven fission track (FT) zircon ages were obtained from five fractions of felsic igneous pebbles in conglomerate, the matrix schist of conglomerate and an intercalated psammitic schist from the Oboke unit. The ages are in the range 56-69 Ma and are younger than 40Ar/ 39Ar ages previously reported from the Oboke unit (70-77 Ma). These concordant grain ages are interpreted as being post-metamorphic cooling ages because the samples analyzed are composed of zircon crystals of igneous and various detrital origins and, therefore, of variable provenance age. The cooling rate of the Oboke unit is less than 8°C/Ma, which is lower than that obtained for the Besshi unit. Our results of FT zircon dating are close to those of the melange zone of the Northern (Cretaceous) Shimanto belt (ca. 65 Ma). This suggests that the underplating of the high-pressure type Sanbagawa metamorphic rock occurred contemporaneously within the same subduction system as the growth of the Shimanto accretionary complex.

  17. 40Ar/ 39Ar mineral age constraints for the tectonothermal evolution of the Sambagawa metamorphic belt, central Shikoku, Japan: a Cretaceous accretionary prism (United States)

    Takasu, A.; Dallmeyer, R. D.


    The Sambagawa metamorphic belt exposed in central Shikoku, Japan, is tectonostratigraphically represented by the Oboke and structurally overlying Besshi nappe complexes. Oboke units consist of metamorphic rocks largely derived from clastic protoliths (sandstone and conglomerate) whereas Besshi units are dominated by rocks with oceanic protolith affinities (shale, chert, and greenstone). Whole-rock schist samples from low-grade Oboke units record intermediate temperature. {40Ar }/{39Ar } plateau ages of 70-77 Ma, which are interpreted to closely date attainment of maximum metamorphic conditions. Whole-rock schist samples from Besshi units (chlorite zone) record plateau ages of 85-94 Ma suggesting an earlier metamorphic climax within this structural level. Amphibole within the albite-biotite zone in Besshi records {36Ar }/{40Ar } vs. {39Ar }/{40Ar } plateau isotope correlation ages of 84-87 Ma, which are interpreted as dating the post-metamorphic cooling through temperatures required for intracrystalline retention of argon. A slightly older isotope correlation age (94 Ma) is recorded by amphibole from the higher grade oligioclase-biotite zone. Contrasts in amphibole cooling ages are interpreted as reflecting thrust-related metamorphic inversion and resultant earlier cooling of higher grade structural units. Muscovite from all structural levels of the Besshi nappe complex records {40Ar }/{39Ar } plateau ages of 76-89 Ma. These are interpreted to date post-metamorphic cooling through appropriate closure temperatures following structural assembly of the Besshi nappe complex. Protoliths of the Besshi units originated at approx. 130 Ma and attained maximum metamorphic conditions during entrainment in an accretionary complex at approx. 90-100 Ma. Higher grade sequences developed at deeper levels along the hanging wall of the accretionary complex. During subsequent structural uplift to shallower crustal levels the Besshi nappe complex was tectonically emplaced over Oboke

  18. STRIP1, a core component of STRIPAK complexes, is essential for normal mesoderm migration in the mouse embryo. (United States)

    Bazzi, Hisham; Soroka, Ekaterina; Alcorn, Heather L; Anderson, Kathryn V


    Regulated mesoderm migration is necessary for the proper morphogenesis and organ formation during embryonic development. Cell migration and its dependence on the cytoskeleton and signaling machines have been studied extensively in cultured cells; in contrast, remarkably little is known about the mechanisms that regulate mesoderm cell migration in vivo. Here, we report the identification and characterization of a mouse mutation in striatin-interacting protein 1 ( Strip1 ) that disrupts migration of the mesoderm after the gastrulation epithelial-to-mesenchymal transition (EMT). STRIP1 is a core component of the biochemically defined mammalian striatin-interacting phosphatases and kinase (STRIPAK) complexes that appear to act through regulation of protein phosphatase 2A (PP2A), but their functions in mammals in vivo have not been examined. Strip1 -null mutants arrest development at midgestation with profound disruptions in the organization of the mesoderm and its derivatives, including a complete failure of the anterior extension of axial mesoderm. Analysis of cultured mesoderm explants and mouse embryonic fibroblasts from null mutants shows that the mesoderm migration defect is correlated with decreased cell spreading, abnormal focal adhesions, changes in the organization of the actin cytoskeleton, and decreased velocity of cell migration. The results show that STRIPAK complexes are essential for cell migration and tissue morphogenesis in vivo. Copyright © 2017 the Author(s). Published by PNAS.

  19. Petrología y Estructura del Complejo Ígneo-Metamórfico Aluminé, Provincia de Neuquén, Argentina Petrology and Structure of the Aluminé Igneous-Metamorphic Complex, Neuquén province, Argentina

    Directory of Open Access Journals (Sweden)

    Ivana A Urraza


    andinas (cretácicas o más modernas y el sector sur donde dominan los granitoides preandinos de edades permotriásicas-jurásicas, emplazados en un basamento paleozoico. Si bien los diagramas geoquímicos permiten diferenciar los diferentes petrotipos definidos petrográficamente y sus tendencias evolutivas podrían indicar procesos de cristalización fraccionada, la distribución areal de los mismos, sus características petrográfico-microestructurales y la geocronología, indican que podrían corresponder a diferentes pulsos-eventos magmáticos separados en el tiempo, aunque desarrollados en un contexto de características tectónicas similares.In the present contribution, the partial results of a detailed study of the magmatic, metamorphic and tectonic events developed in the Aluminé Igneous-Metamorphic Complex (AIMC are given. We define the AIMC as the set of pre-andean and andean intrusive igneous and metamorphic rocks, outcropping in the área located between the Aluminé, Moquehue, Ñorquinco and Pulmarí lakes in the Neuquén province, Argentina. Based on field and petrographic observations and geochemical characteristics, the granitic rocks forming part of the AIMC have been classified as: 1. quartz diorites, 2. tonalites-granodiorites, 3. granodiorites and 4. granites. The geochemical parameters indícate that the defined lithologies derive from calcic to weakly calcalkaline magmas of metaluminous composition, typical of Type I Cordilleran batholiths associated with active continental margins. Intercalated between the magmatic rocks, some outcrops of metamorphic basement composed mainly of schists, gneisses, amphibolites and scarce quartzose sandstones. Andesites, tuffs and basalts cover in part the metamorphites and granitoids are exposed. The structure of the sector is characterized by the presence of three main sets of regional lineaments, with NE-SW, NW-SE and N-S orientations. These directions coincide with the orientations of the three groups of

  20. X-ray color maps of the zoned garnets from Silgará Formation metamorphic rocks,SantanderMassif, Eastern Cordillera (Colombia

    Directory of Open Access Journals (Sweden)

    Takasu Akira


    Full Text Available

    The metamorphic rocks of the Lower Paleozoic Silgará Formation of the Santander Massif, Eastern Cordillera (Colombia, were affected by a Barrovian-type metamorphism under low to high temperature and medium pressure conditions. These rocks contain garnet porphyroblasts, which show several kinds of chemical zoning patterns. The garnet grains behave as closed systems with respect to the rock matrix. Most of the observed zoning patterns are due to gradual changes in physicochemical conditions during growth. However, some garnet grains show complex zoning patterns during multiple deformation and metamorphic events.

  1. An innovative approach for testing bioinformatics programs using metamorphic testing

    Directory of Open Access Journals (Sweden)

    Liu Huai


    Full Text Available Abstract Background Recent advances in experimental and computational technologies have fueled the development of many sophisticated bioinformatics programs. The correctness of such programs is crucial as incorrectly computed results may lead to wrong biological conclusion or misguide downstream experimentation. Common software testing procedures involve executing the target program with a set of test inputs and then verifying the correctness of the test outputs. However, due to the complexity of many bioinformatics programs, it is often difficult to verify the correctness of the test outputs. Therefore our ability to perform systematic software testing is greatly hindered. Results We propose to use a novel software testing technique, metamorphic testing (MT, to test a range of bioinformatics programs. Instead of requiring a mechanism to verify whether an individual test output is correct, the MT technique verifies whether a pair of test outputs conform to a set of domain specific properties, called metamorphic relations (MRs, thus greatly increases the number and variety of test cases that can be applied. To demonstrate how MT is used in practice, we applied MT to test two open-source bioinformatics programs, namely GNLab and SeqMap. In particular we show that MT is simple to implement, and is effective in detecting faults in a real-life program and some artificially fault-seeded programs. Further, we discuss how MT can be applied to test programs from various domains of bioinformatics. Conclusion This paper describes the application of a simple, effective and automated technique to systematically test a range of bioinformatics programs. We show how MT can be implemented in practice through two real-life case studies. Since many bioinformatics programs, particularly those for large scale simulation and data analysis, are hard to test systematically, their developers may benefit from using MT as part of the testing strategy. Therefore our work

  2. Record of high-pressure overprint in metamorphic soles of the Tavşanli zone, Western Anatolia (United States)

    Plunder, Alexis; Agard, Philippe; Chopin, Christian; Okay, Aral


    Large obducted ophiolites correspond to the emplacement of dense oceanic lithosphere on top of a continent and thereby provide insights into rheological and thermal coupling between plates or fluid budgets. Obducted ophiolites thrust onto the continental margin of the Anatolide-Tauride block (Western Anatolia, south of the Izmir-Ankara suture zone) are dated through their metamorphic sole at ca. 90-95Ma and derive from the same intra-oceanic Neotethyan subduction. We herein focus on the metamorphic soles of the Tavşanlı zone, which show a variable high-pressure low-temperature (HP-LT) overprint of the initial amphibolitic metamorphic conditions (Önen & Hall, 1993; Dilek & Whitney, 1997; Okay et al, 1998). Systematic sampling was done in both the already studied areas as well as new locations. PT conditions were estimated at 8 kbar and 700°C for the amphibolitic stage with the assemblage hornblende + plagioclase ± garnet ± epidote. The HP-LT metamorphic overprint reached incipient blueschist to blueschist facies PT conditions. Development of the characteristic assemblage glaucophane + lawsonite yields PT estimates of >6-7 kbar and 300°C. The high-pressure stage is similar to the one observed for the underlying accretionary-complex unit of the Tavşanlı zone (Plunder et al, this meeting). This HP overprint was not observed in other obduction contexts such as Oman or New Caledonia but was documented in Fransciscan Complex amphibolites (Wakayabashi, 1990). The record of two metamorphic events can be understood as: (1) rapid cooling of the subduction zone after initiation and the exhumation of the metamorphic sole; (2) reburial after or during exhumation of the amphibolite initially welded at the base of the ophiolite. Several observations (i.e., lack of tectonic contact between the ophiolitic body and the metamorphic sole, PT estimates,...) point to cooling as the most likely hypothesis. Metamorphic soles allow to highlight: (1) the dynamics of obducted

  3. Tectono-metamorphic evolution of the upper plate of the Eo-Alpine nappe-stack: constraints from the Oberhof Window (Carinthia, Austria) (United States)

    Hollinetz, Marianne Sophie; Huet, Benjamin; Iglseder, Christoph; Rantitsch, Gerd; Grasemann, Berhard


    The Upper Austro-Alpine Unit in the Eastern Alps corresponds to a nappe-stack that formed during the Eo-Alpine Cretaceous event. It is dominated by crystalline rocks that show Variscan, Permo-Triassic, Eo-Alpine and Neo-Alpine metamorphic imprints. Understanding the tectono-metamorphic evolution of the Eo-Alpine nappe-stack is therefore hampered by a complex polyphase history. Most published studies focused on the subducted lower plate that contains the eclogite-bearing nappes (Koralpe-Wölz nappe system) but the upper plate (Ötztal-Bundschuh nappe system and Drauzug-Gurktal nappe system) is less understood. Our contribution focuses on the tectono-metamorphic evolution of the Bundschuh nappe (Oberhof Window, Carinthia, Austria). This nappe contains metasediments intruded by granites of Ordovician age. Characteristically, these rocks underwent Variscan amphibolite-facies. They were later covered by Carboniferous to Mesozoic sediments and, all together, overprinted by greenschist to amphibolite-facies metamorphism in the upper plate of the Eo-Alpine wedge. During this event, the Bundschuh nappe was overthrusted by the nappes of the Drauzug-Gurktal nappe system. The core of the window is occupied by the middle-grained "Oberhof orthogneiss". LA-ICP-MS U/Pb zircon dating yielded a late Ordovician age for its protolith. The orthogneiss is overlain by the transgressive Carboniferous metasediments comprising meta-conglomerate, graphite schist and quartzite. The Bundschuh nappe is overthrusted by garnet-micaschist, amphibolite, hornblende-garbenschist, calc-micaschist, quarzite and graphitic schist interpreted as parts of the basal Drauzug-Gurktal nappe system. Deformation is characterized by isoclinal folds with an E-W/SE-NW trending fold-axes and top-to-the-East/South-East shearing. This kinematics is related to normal faulting in the upper part of the Eo-Alpine orogenic wedge. The graphite schist contains an assemblage of isolated round garnet and abundant chloritoid in

  4. Planting increases the abundance and structure complexity of soil core functional genes relevant to carbon and nitrogen cycling. (United States)

    Wang, Feng; Liang, Yuting; Jiang, Yuji; Yang, Yunfeng; Xue, Kai; Xiong, Jinbo; Zhou, Jizhong; Sun, Bo


    Plants have an important impact on soil microbial communities and their functions. However, how plants determine the microbial composition and network interactions is still poorly understood. During a four-year field experiment, we investigated the functional gene composition of three types of soils (Phaeozem, Cambisols and Acrisol) under maize planting and bare fallow regimes located in cold temperate, warm temperate and subtropical regions, respectively. The core genes were identified using high-throughput functional gene microarray (GeoChip 3.0), and functional molecular ecological networks (fMENs) were subsequently developed with the random matrix theory (RMT)-based conceptual framework. Our results demonstrated that planting significantly (P soils and 83.5% of microbial alpha-diversity can be explained by the plant factor. Moreover, planting had significant impacts on the microbial community structure and the network interactions of the microbial communities. The calculated network complexity was higher under maize planting than under bare fallow regimes. The increase of the functional genes led to an increase in both soil respiration and nitrification potential with maize planting, indicating that changes in the soil microbial communities and network interactions influenced ecological functioning.

  5. Heterologous Production of the Photosynthetic Reaction Center and Light Harvesting 1 Complexes of the Thermophile Thermochromatium tepidum in the Mesophile Rhodobacter sphaeroides and Thermal Stability of a Hybrid Core Complex. (United States)

    Jun, D; Huang, V; Beatty, J T


    The photosynthetic complexes of the thermophile Thermochromatium tepidum are of considerable interest in biohybrid solar cell applications because of the ability of thermophilic proteins to tolerate elevated temperatures. Synthetic operons encoding reaction center (RC) and light harvesting 1 (LH1) pigment-protein complexes of T. tepidum were expressed in the mesophile Rhodobacter sphaeroides The T. tepidum RC (TRC) was assembled and was found to be functional with the addition of menadione to populate the Q A pocket. The production of T. tepidum LH1 (TLH1) was increased by selection of a phototrophy-capable mutant after UV irradiation mutagenesis, which yielded a hybrid RC-TLH1 core complex consisting of the R. sphaeroides RC and T. tepidum TLH1, confirmed by the absorbance peak of TLH1 at 915 nm. Affinity chromatography partial purification and subsequent sucrose gradient analysis of the hybrid RC-TLH1 core complex indicated that this core complex assembled as a monomer. Furthermore, the RC-TLH1 hybrid core complex was more tolerant of a temperature of 70°C than the R. sphaeroides RC-LH1 core complexes in both the dimeric and monomeric forms; after 1 h, the hybrid complex retained 58% of the initial starting value, compared to values of 11% and 53% for the R. sphaeroides RC-LH1 dimer and monomer forms, respectively. IMPORTANCE This work is important because it is a new approach to bioengineering of photosynthesis proteins for potential use in biophotovoltaic solar energy capture. The work establishes a proof of principle for future biohybrid solar cell applications. Copyright © 2017 American Society for Microbiology.

  6. Miocene metamorphism of pan-African granites in the Edough Massif (NE Algeria)

    International Nuclear Information System (INIS)

    Hammor, D.; Lancelot, J.


    The Edough Massif is the eastern most crystalline core of the Maghrebides that represents the African segment of the west Mediterranean Alpine belt. U-Pb zircon dating provides upper intercept ages of 595± My and 606±55 My and orthogneiss of the lower unit and a deformed leucogranite of the upper pelitic unit, respectively. These ages suggest emplacement of the two granitoids during the Pan-African orogeny. Monazites from a paragneiss sample gave a 18± My U-Pb age that points to a Miocene age of the high-temperature metamorphism. (authors)

  7. Superposed orogenic collision and core-complex formation at the present contact between the Dinarides and the Pannonian basin: The Bukulja and Cer Mountains in central and western Serbia (United States)

    Matenco, Liviu; Toljic, Marinko; Ducea, Mihai; Stojadinovic, Uros


    basin. An Upper Cretaceous-Eocene phase of top-WSW shortening and metamorphism in the Sava zone and its subducting lower Adriatic plate was subsequently followed by massive core-complex exhumation and top-E directed extension during initiation of the Carpathians back-arc extension. Interestingly, the newly defined extensional detachments accompanying the Pannonian extension closely follow the pre-existing subduction zone and its associated duplications in the lower orogenic plate. This conclusion is compatible with observations in other areas of the Dinarides, such as the Prosara-Motajica in Bosnia/Croatia or Kopaonik-Studenica in southern Serbia (Schefer et al., 2008; Ustaszewski et al., 2009).

  8. Crystal Structure of the Core Region of Hantavirus Nucleocapsid Protein Reveals the Mechanism for Ribonucleoprotein Complex Formation (United States)

    Guo, Yu; Wang, Wenming; Sun, Yuna; Ma, Chao; Wang, Xu; Wang, Xin; Liu, Pi; Shen, Shu; Li, Baobin; Lin, Jianping; Deng, Fei


    ABSTRACT Hantaviruses, which belong to the genus Hantavirus in the family Bunyaviridae, infect mammals, including humans, causing either hemorrhagic fever with renal syndrome (HFRS) or hantavirus cardiopulmonary syndrome (HCPS) in humans with high mortality. Hantavirus encodes a nucleocapsid protein (NP) to encapsidate the genome and form a ribonucleoprotein complex (RNP) together with viral polymerase. Here, we report the crystal structure of the core domains of NP (NPcore) encoded by Sin Nombre virus (SNV) and Andes virus (ANDV), which are two representative members that cause HCPS in the New World. The constructs of SNV and ANDV NPcore exclude the N- and C-terminal portions of full polypeptide to obtain stable proteins for crystallographic study. The structure features an N lobe and a C lobe to clamp RNA-binding crevice and exhibits two protruding extensions in both lobes. The positively charged residues located in the RNA-binding crevice play a key role in RNA binding and virus replication. We further demonstrated that the C-terminal helix and the linker region connecting the N-terminal coiled-coil domain and NPcore are essential for hantavirus NP oligomerization through contacts made with two adjacent protomers. Moreover, electron microscopy (EM) visualization of native RNPs extracted from the virions revealed that a monomer-sized NP-RNA complex is the building block of viral RNP. This work provides insight into the formation of hantavirus RNP and provides an understanding of the evolutionary connections that exist among bunyaviruses. IMPORTANCE Hantaviruses are distributed across a wide and increasing range of host reservoirs throughout the world. In particular, hantaviruses can be transmitted via aerosols of rodent excreta to humans or from human to human and cause HFRS and HCPS, with mortalities of 15% and 50%, respectively. Hantavirus is therefore listed as a category C pathogen. Hantavirus encodes an NP that plays essential roles both in RNP formation and

  9. Structural and magnetic characterization of three tetranuclear Cu(II) complexes with face-sharing-dicubane/double-open-cubane like core framework (United States)

    Paul, Aparup; Bertolasi, Valerio; Figuerola, Albert; Manna, Subal Chandra


    Three novel tetranuclear copper(II) complexes namely [Cu4(L1)4]•2(dmf) (1), [Cu4(L1)4] (2) and [Cu4(L2)2(HL2)2(H2O)2]•2(ClO4)·6(H2O) (3) (H2L1, (E)-2-((1-hydroxybutan-2-ylimino)methyl)phenol; H2L2, (E)-2-((1-hydroxybutan-2-ylimino)methyl)-6-methoxyphenol)) were synthesized from the self-assembly of copper(II) perchlorate and the tridentate Schiff base ligands. The structural determination reveals that complex 1 crystallizes in the monoclinic system with space group C2/c, whereas both the complexes 2 and 3 crystallize in the triclinic system with space group P-1. Complexes 1 and 2 possess face-sharing dicubane core, on the other hand complex 3 has double open cubane core structure. The copper(II) ions in the cubane core are in distorted square planar geometries, and weak π…π and C-H…π interactions lead to formation of a 2D supramolecular architecture for complexes 1 and 2. At room temperature complexes 1, 2 and 3, exhibit fluorescence with a quantum yield (Φs) of 0.47, 0.49 and 0.38, respectively. Variable temperature magnetic susceptibility measurements in the range 2-300 K indicate an overall weak antiferromagnetic exchange coupling in all complexes. The PHI program was used to study their magnetic behaviour. In agreement with their face-sharing dicubane structure, a Hamiltonian of the type H =- J1(S1S2+S1S2'+S1'S2+S1'S2') - J2S1S1', where S1 = S1' = S2 = S2' = SCu =1/2, was used for studying complexes 1 and 2. Simulations performed suggest magnetic exchange constants with values close to J1 =-20 cm-1 and J2 =0 cm-1 for these complexes. On the other hand, the spin Hamiltonian H =- J1(S1S4+S2S3) - J2(S1S3+S2S4) - J3S1S2, where S1 = S2 = S3 = S4 = SCu =1/2, was used to study the magnetic behaviour of the double open cubane core of complex 3 and a good agreement between the experimental and simulated results was found by using the parameters g1 = g2 =2.20, g3 = g4 =2.18, J1 =-36 cm-1, J2 =-44 cm-1 and J3 =0 cm-1.

  10. Preliminary evidence for a Hercynian age of the Versoyen complex, western Alps; Evidence preliminaire d'un age Hercynian pour le complexe du Versoyen, Alpes occidentales

    Energy Technology Data Exchange (ETDEWEB)

    Scharer, U. [Paris-7 Univ., Lab. de Geochronologie, UMR 7578, 75 (France); Cannic, S.; Lapierre, H. [Universite Joseph-Fourier, Lab. de Geologie des Chaines Alpines, Upres A5025, Institut Dolomieu, Grenoble I, 38 (France)


    To date the magmatic event that generated the Versoyen mafic complex, four fractions of zircon from a cross-cutting leuco-gabbro dike, has been analyzed by the U-Pb method, defining a regression line that intercepts the concordia curve at 309 {+-} 6 (2 {sigma}) Ma and 3 240 {+-} 34 Ma. These two ages can be interpreted to date, respectively, emplacement of the leuco-gabbro into the Versoyen complex, and the age of inherited Archean zircon cores, present in the newly formed crystals. The age of 309 Ma suggests that both Versoyen mafic magmatism and subsequent eclogite facies metamorphism belong to the Hercynian, and not the Alpine orogenic cycle. (authors)

  11. New P-T and U-Pb constraints on Alpine Schist metamorphism in south Westland, New Zealand

    International Nuclear Information System (INIS)

    Scott, J.M.; Auer, A.; Muhling, J.R.; Czertowicz, T.A.; Cooper, A.F.; Billia, M.A.; Kennedy, A.K.


    Metamorphic mineral compositions of a staurolite-bearing greyschist from the middle reaches of the Moeraki River valley in south Westland reveal peak equilibration at c. 558±50 degrees C and c. 6.1±1.2 kbar. Two c. 83 Ma U-Pb monazite age populations from the cores of monazite-apatite-allanite-epidote corona structures in mylonitised schists from near Fox Glacier confirm that Alpine Schist metamorphism occurred during the Late Cretaceous. The published spread in Late Cretaceous metamorphic ages indicates that metamorphism was diachronous or was a protracted event. Further dating is required to pin down the cryptic transition into the Jurassic-Early Cretaceous metamorphosed Otago Schist, but the Alpine Schist must extend at least 11 km east of the Alpine Fault in south Westland and overprint the suture between the Pounamu and Rakaia terranes. The P-T-t results imply that the Late Cretaceous crust represented by portions of the Alpine Schist was probably of similar thickness to that beneath the Southern Alps today, but with dehydration and partial melting occurring near the base. The crust under Westland and Otago may be dry and therefore strong. (author).

  12. Inverted Metamorphic Multijunction (IMM) Cell Processing Instructions

    Energy Technology Data Exchange (ETDEWEB)

    Duda, A.; Ward, S.; Young, M.


    This technical report details the processing schedule used to fabricate Inverted Metamorphic Multijunction (IMM) concentrator solar cells at The National Renewable Energy Laboratory (NREL). These devices are used as experimental test structures to support the research at NREL that is focused on increasing the efficiency of photovoltaic power conversion. They are not intended to be devices suitable for deployment in working concentrator systems primarily because of heat sinking issues. The process schedule was developed to be compatible with small sample sizes and to afford relatively rapid turn-around times, in support of research efforts. The report describes the use of electro deposition of gold for both the back and front contacts. Electro-deposition is used because of its rapid turn around time and because it is a benign metallization technique that is seldom responsible for damage to the semiconductors. The layer transfer technique is detailed including the use of a commercially available adhesive and the etching away of the parent gallium arsenide substrate. Photolithography is used to define front contact grids as well as the mesa area of the cell. Finally, the selective wet chemical etchant system is introduced and its use to reveal the back contact is described.

  13. High Radiation Resistance Inverted Metamorphic Solar Cell, Phase II (United States)

    National Aeronautics and Space Administration — The innovation in this SBIR Phase II project is the development of a unique triple junction inverted metamorphic technology (IMM), which will enable the...

  14. High Radiation Resistance Inverted Metamorphic Solar Cell Project (United States)

    National Aeronautics and Space Administration — The innovation in the proposed SBIR Phase I project is the development of a unique triple unction inverted metamorphic technology (IMM), which will enable the...

  15. The Wisdom of Networks: A General Adaptation and Learning Mechanism of Complex Systems: The Network Core Triggers Fast Responses to Known Stimuli; Innovations Require the Slow Network Periphery and Are Encoded by Core-Remodeling. (United States)

    Csermely, Peter


    I hypothesize that re-occurring prior experience of complex systems mobilizes a fast response, whose attractor is encoded by their strongly connected network core. In contrast, responses to novel stimuli are often slow and require the weakly connected network periphery. Upon repeated stimulus, peripheral network nodes remodel the network core that encodes the attractor of the new response. This "core-periphery learning" theory reviews and generalizes the heretofore fragmented knowledge on attractor formation by neural networks, periphery-driven innovation, and a number of recent reports on the adaptation of protein, neuronal, and social networks. The core-periphery learning theory may increase our understanding of signaling, memory formation, information encoding and decision-making processes. Moreover, the power of network periphery-related "wisdom of crowds" inventing creative, novel responses indicates that deliberative democracy is a slow yet efficient learning strategy developed as the success of a billion-year evolution. Also see the video abstract here: © 2017 WILEY Periodicals, Inc.

  16. An oceanic core complex (OCC) in the Albanian Dinarides? Preliminary paleomagnetic and structural results from the Mirdita Ophiolite (northern Albania) (United States)

    Maffione, M.; Morris, A.; Anderson, M.


    Oceanic core complexes (OCCs) are dome-shaped massifs commonly associated with the inside corners of the intersection of transform faults and slow (and ultra-slow) spreading centres. They represent the uplifted footwalls of large-slip oceanic detachment faults (e.g. Cann et al., 1997; Blackman et al., 1998) and are composed of mantle and lower crustal rocks exhumed during fault displacement (Smith et al., 2006, 2008). Recent paleomagnetic studies of core samples from OCCs in the Atlantic Ocean (Morris et al., 2009; MacLeod et al., in prep) have confirmed that footwall sections undergo substantial rotation around (sub-) horizontal axes. These studies, therefore, support “rolling hinge” models for the evolution of OCCs, whereby oceanic detachment faults initiate at a steep angle at depth and then “roll-over” to their present day low angle orientations during unroofing (Buck, 1988; Wernicke & Axen, 1988; Lavier et al., 1999). However, a fully integrated paleomagnetic and structural analysis of this process is hampered by the one-dimensional sampling provided by ocean drilling of OCC footwalls. Therefore, ancient analogues for OCCs in ophiolites are of great interest, as these potentially provide 3-D exposures of these important structures and hence a more complete understanding of footwall strain and kinematics (providing that emplacement-related phases of deformation can be accounted for). Recently, the relationship between outcropping crustal and upper mantle rocks led Tremblay et al. (2009) to propose that an OCC is preserved within the Mirdita ophiolite of the Albanian Dinarides (northern Albania). This is a slice of Jurassic oceanic lithosphere exposed along a N-S corridor which escaped the main late Cenozoic Alpine deformation (Robertson, 2002, 2004; Dilek et al., 2007). Though in the eastern portion of the Mirdita ophiolite a Penrose-type sequence is present, in the western portion mantle rocks are in tectonic contact with upper crustal lithologies

  17. Dynamics of Energy and Electron Transfer in the FMO-Reaction Center Core Complex from the Phototrophic Green Sulfur Bacterium Chlorobaculum tepidum. (United States)

    He, Guannan; Niedzwiedzki, Dariusz M; Orf, Gregory S; Zhang, Hao; Blankenship, Robert E


    The reaction center core (RCC) complex and the RCC with associated Fenna-Matthews-Olson protein (FMO-RCC) complex from the green sulfur bacterium Chlorobaculum tepidum were studied comparatively by steady-state and time-resolved fluorescence (TRF) and femtosecond time-resolved transient absorption (TA) spectroscopies. The energy transfer efficiency from the FMO to the RCC complex was calculated to be ∼40% based on the steady-state fluorescence. TRF showed that most of the FMO complexes (66%), regardless of the fact that they were physically attached to the RCC, were not able to transfer excitation energy to the reaction center. The TA spectra of the RCC complex showed a 30-38 ps lifetime component regardless of the excitation wavelengths, which is attributed to charge separation. Excitonic equilibration was shown in TA spectra of the RCC complex when excited into the BChl a Qx band at 590 nm and the Chl a Qy band at 670 nm, while excitation at 840 nm directly populated the low-energy excited state and equilibration within the excitonic BChl a manifold was not observed. The TA spectra for the FMO-RCC complex excited into the BChl a Qx band could be interpreted by a combination of the excited FMO protein and RCC complex. The FMO-RCC complex showed an additional fast kinetic component compared with the FMO protein and the RCC complex, which may be due to FMO-to-RCC energy transfer.

  18. Recycling argon through metamorphic reactions: The record in symplectites (United States)

    McDonald, Christopher S.; Regis, Daniele; Warren, Clare J.; Kelley, Simon P.; Sherlock, Sarah C.


    The 40Ar/39Ar ages of metamorphic micas that crystallized at high temperatures are commonly interpreted as cooling ages, with grains considered to have lost 40Ar via thermally-driven diffusion into the grain boundary network. Recently reported laser-ablation data suggest that the spatial distribution of Ar in metamorphic micas does not always conform to the patterns predicted by diffusion theory and that despite high metamorphic temperatures, argon was not removed efficiently from the local system during metamorphic evolution. In the Western Gneiss Region (WGR), Norway, felsic gneisses preserve microtextural evidence for the breakdown of phengite to biotite and plagioclase symplectites during near isothermal decompression from c. 20-25 to c. 8-12 kbar at 700 °C. These samples provide an ideal natural laboratory to assess whether the complete replacement of one K-bearing mineral by another at high temperatures completely 'resets' the Ar clock, or whether there is some inheritance of 40Ar in the neocrystallized phase. The timing of the high-temperature portion of the WGR metamorphic cycle has been well constrained in previous studies. However, the timing of cooling following the overprint is still much debated. In-situ laser ablation spot dating in phengite, biotite-plagioclase symplectites and coarser, texturally later biotite yielded 40Ar/39Ar ages that span much of the metamorphic cycle. Together these data show that despite residence at temperatures of 700 °C, Ar is not completely removed by diffusive loss or during metamorphic recrystallization. Instead, Ar released during phengite breakdown appears to be partially reincorporated into the newly crystallizing biotite and plagioclase (or is trapped in fluid inclusions in those phases) within a close system. Our data show that the microtextural and petrographic evolution of the sample being dated provides a critical framework in which local 40Ar recycling can be tracked, thus potentially allowing 40Ar/39Ar dates

  19. Metamorphic mineral reactions: Porphyroblast, corona and symplectite growth


    F. Gaidies; R. Milke; W. Heinrich; R. Abart


    Much of the Earth’s dynamics is related to mineral reactions in the solid-state. Classically, this is referred to as metamorphic crystallization (Kretz, 1994). Based on the chemical compositions of the phases involved in a metamorphic mineral reaction, two basic reaction types may be distinguished. Reactions that involve only structural re-arrangements, while the compositions of the reactant and product phases are identical, are referred to as partitionless and ‘polymorphic phase transformati...

  20. Metamorphic III–V Solar Cells: Recent Progress and Potential

    Energy Technology Data Exchange (ETDEWEB)

    Garcia, Ivan; France, Ryan M.; Geisz, John F.; McMahon, William E.; Steiner, Myles A.; Johnston, Steve; Friedman, Daniel J.


    Inverted metamorphic multijunction solar cells have been demonstrated to be a pathway to achieve the highest photovoltaic (PV) conversion efficiencies. Attaining high-quality lattice-mismatched (metamorphic) semiconductor devices is challenging. However, recent improvements to compositionally graded buffer epitaxy and junction structures have led to the achievement of high-quality metamorphic solar cells exhibiting internal luminescence efficiencies over 90%. For this high material quality, photon recycling is significant, and therefore, the optical environment of the solar cell becomes important. In this paper, we first present recent progress and performance results for 1- and 0.7-eV GaInAs solar cells grown on GaAs substrates. Then, an electrooptical model is used to assess the potential performance improvements in current metamorphic solar cells under different realizable design scenarios. The results show that the quality of 1-eV subcells is such that further improving its electronic quality does not produce significant Voc increases in the four-junction inverted metamorphic subcells, unless a back reflector is used to enhance photon recycling, which would significantly complicate the structure. Conversely, improving the electronic quality of the 0.7-eV subcell would lead to significant Voc boosts, driving the progress of four-junction inverted metamorphic solar cells.

  1. The Chicxulub crater - impact metamorphism of sulfate and carbonate lithologies (United States)

    Deutsch, A.; Langenhorst, F.; Hornemann, U.; Ivanov, B. A.


    It is discussed whether in the aftermath of the Chicxulub event, impact-released CO_2 and SO_x have changed the Earth's climate, acting also as lethal thread for life. Undoubtedly, vaporization of carbonates and sulfates, which are major target lithologies at the Chicxulub impact site, occurred in the footprint of the projectile. What happened to these lithologies outside this very restricted zone was so far unconstrained. Petrologic observations on PEMEX and UNAM as well as on the CSDP cores allow to set up a general classification for shock-related pro-grade effects on sulfate and carbonate sedimentary rocks. Shock effects in lithic breccias are restricted to brecciation and formation of twins in calcite. Suevites mostly lack melted carbonate clasts; annealing effects in anhydrite fragments are absent. The underlying melt breccias contain anhydrite fragments still displaying a sedimentary texture, and limestone clasts, whose texture reflect crystallization from melt. Impact melt breccias from deeper levels frequently contain partially resorbed anhydrite clasts and a melt matrix with the Ca-rich mineral assemblage quartz + plagioclase + clinopyroxene; this mineral assemblage provides evidence for partial dissociation of CaSO_4. Large clasts of anhydrite consist of equant crystals with 120^o triple junctions, a feature indicative for re-crystallization in the solid state. Tagamites (impact melt rocks) are virtually free of clasts from sedimentary lithologies. These rocks have an extremely high formation temperature, which caused total dissociation of CaSO_4 and CaCO_3. Finally, up to 100 μm wide veins of anhydrite + calcite + quartz cut the matrix of all lithologies except the tagamites. They probably represent "degassing vents". The given scheme is in qualitative accordance with data of shock recovery and annealing experiments as well as with modeling results. In addition, it substantiates that annealing plays a fundamental role in the impact metamorphism of

  2. Design and accuracy analysis of a metamorphic CNC flame cutting machine for ship manufacturing (United States)

    Hu, Shenghai; Zhang, Manhui; Zhang, Baoping; Chen, Xi; Yu, Wei


    The current research of processing large size fabrication holes on complex spatial curved surface mainly focuses on the CNC flame cutting machines design for ship hull of ship manufacturing. However, the existing machines cannot meet the continuous cutting requirements with variable pass conditions through their fixed configuration, and cannot realize high-precision processing as the accuracy theory is not studied adequately. This paper deals with structure design and accuracy prediction technology of novel machine tools for solving the problem of continuous and high-precision cutting. The needed variable trajectory and variable pose kinematic characteristics of non-contact cutting tool are figured out and a metamorphic CNC flame cutting machine designed through metamorphic principle is presented. To analyze kinematic accuracy of the machine, models of joint clearances, manufacturing tolerances and errors in the input variables and error models considering the combined effects are derived based on screw theory after establishing ideal kinematic models. Numerical simulations, processing experiment and trajectory tracking experiment are conducted relative to an eccentric hole with bevels on cylindrical surface respectively. The results of cutting pass contour and kinematic error interval which the position error is from-0.975 mm to +0.628 mm and orientation error is from-0.01 rad to +0.01 rad indicate that the developed machine can complete cutting process continuously and effectively, and the established kinematic error models are effective although the interval is within a `large' range. It also shows the matching property between metamorphic principle and variable working tasks, and the mapping correlation between original designing parameters and kinematic errors of machines. This research develops a metamorphic CNC flame cutting machine and establishes kinematic error models for accuracy analysis of machine tools.

  3. The age of the rocks and the metamorphic episodes from the Southeastern of Sao Paulo state

    International Nuclear Information System (INIS)

    Tassinari, C.C.G.; Kawashita, K.; Schmuss, R. van; Taylor, P.N.


    Rb-Sr, Pb-Pb and U-Pb geochronologic studies carried out on precambrian rocks from the southeastern Sao Paulo state suggest a Complex geologic evolution during the Archean and Proterozoic times. This region is divided in five differents allochthonous terranes named Itapira-Amparo, Piracaiba-Jundiai, Sao Roque, Embu and Costeiro, separated by thrust and strike-slip faults. The Itapira-Amparo domain has a original history dating back to 3.4 Ga. and since 2.6 to 2.5 Ga. and 2.2 to 1.9 Ga. metamorphic rockformation episode occurred involving both mantle-derived magmas and recycled material. Supracrustal sequences developed around 1.4 Ga. The domain was locally reworked in 0.8 - 0.65 Ga. In the Piracaia-Jundiai the main rock-formation event occurred at 1.4 Ga., but this domian was affected by strong granization and migmatization episodes during the period 1.1 - 0.6 Ga. The third terrain is characterized by the Sao Roque metavolcanossedimentary sequence developed during the time period 1.8 - 0.7 Ga., and comprising two metamorphic superimposed events (1.4 and 0.8 - 0.7 Ga.). the post-tectonics granites ranging in ages from 0.7 to 0.55 Ga. Within the Embu terrain ages of 2.5, 1.4 and 0,75 Ga. were obtained for the metamorphic terrain, with post-tectonic activities around 650 Ma. In the Costeiro domain all the metamorphic rocks developed in late-Proterozoic time, with syntectonic phase around 650 Ma [pt

  4. Behavior of zircon in the upper-amphibolite to granulite facies schist/migmatite transition, Ryoke metamorphic belt, SW Japan: constraints from the melt inclusions in zircon


    Kawakami, Tetsuo; Yamaguchi, Isao; Miyake, Akira; Shibata, Tomoyuki; Maki, Kenshi; Yokoyama, Takaomi D.; Hirata, Takafumi


    Behavior of zircon at the schist/migmatite transition is investigated. Syn-metamorphic overgrowth is rare in zircon in schists, whereas zircon in migmatites has rims with low Th/U that give 90.3 ± 2.2 Ma U–Pb concordia age. Between inherited core and the metamorphic rim, a thin, dark-CL annulus containing melt inclusion is commonly developed, suggesting that it formed contemporaneous with the rim in the presence of melt. In diatexites, the annulus is further truncated by the brighter-CL overg...

  5. Core-satellites assembly of silver nanoparticles on a single gold nanoparticle via metal ion-mediated complex. (United States)

    Choi, Inhee; Song, Hyeon Don; Lee, Suseung; Yang, Young In; Kang, Taewook; Yi, Jongheop


    We report core-satellites (Au-Ag) coupled plasmonic nanoassemblies based on bottom-up, high-density assembly of molecular-scale silver nanoparticles on a single gold nanoparticle surface, and demonstrate direct observation and quantification of enhanced plasmon coupling (i.e., intensity amplification and apparent spectra shift) in a single particle level. We also explore metal ion sensing capability based on our coupled plasmonic core-satellites, which enabled at least 1000 times better detection limit as compared to that of a single plasmonic nanoparticle. Our results demonstrate and suggest substantial promise for the development of coupled plasmonic nanostructures for ultrasensitive detection of various biological and chemical analytes.

  6. First report of garnet corundum rocks from southern India: Implications for prograde high-pressure (eclogite-facies?) metamorphism (United States)

    Shimpo, Makoto; Tsunogae, Toshiaki; Santosh, M.


    We report here for the first time the occurrence of garnet and corundum in Mg-Al-rich rocks at Sevitturangampatti (Namakkal district) in the Palghat-Cauvery Shear Zone System (PCSS), southern India. The rocks contain several rare mineral assemblages such as garnet-corundum-sillimanite-cordierite-sapphirine-spinel-Mg-rich staurolite, garnet-corundum-sodic gedrite-cordierite-sillimanite/kyanite, garnet-Mg-rich staurolite-sillimanite/kyanite, sodic gedrite-Mg-rich staurolite-corundum-sapphirine, biotite-corundum-sapphirine and sodic gedrite-sapphirine-spinel-cordierite. Both garnet and corundum in these rocks occur as coarse-grained (1 mm to 10 cm) porphyroblasts in the matrix of sillimanite, cordierite and gedrite. Kyanite is common as inclusions in garnet, but matrix aluminosilicates are mainly sillimanite. The presence of rare garnet + corundum, which has so far been reported from kimberlite xenoliths, aluminous eclogites and ultrahigh-pressure metamorphic rocks as well as in high-pressure experiments, suggests that the assemblage is an indicator of an unusually high-pressure event, which has not been recorded in previous studies from southern India. Phase analysis of quartz-absent MAS system also suggests high-pressure stability of the assemblage. The inference of high pressure metamorphism is also supported by the presence of Mg-rich [Mg/(Fe + Mg) = 0.51] staurolite, which has been reported from high-pressure rocks, included from cores of coarse-grained garnet and gedrite. Porphyroblastic occurrence of garnet + corundum as well as staurolite and kyanite inclusions suggests that the area underwent prograde high-pressure metamorphism, probably in the eclogite field. The rocks subsequently underwent continuous heating at 940 to 990 °C, suggesting ultrahigh-temperature (UHT) metamorphism along a clockwise trajectory. Sapphirine + cordierite and spinel + cordierite symplectites between garnet and sillimanite suggest near isothermal decompression after the peak event

  7. A three-dimensional FRET analysis to construct an atomic model of the actin-tropomyosin-troponin core domain complex on a muscle thin filament. (United States)

    Miki, Masao; Makimura, Satoshi; Sugahara, Yasuyuki; Yamada, Ryuta; Bunya, Masashi; Saitoh, Takahiro; Tobita, Hidetaka


    It is essential to know the detailed structure of the thin filament to understand the regulation mechanism of striated muscle contraction. Fluorescence resonance energy transfer (FRET) was used to construct an atomic model of the actin-tropomyosin (Tm)-troponin (Tn) core domain complex. We generated single-cysteine mutants in the 167-195 region of Tm and in TnC, TnI, and the β-TnT 25-kDa fragment, and each was attached with an energy donor probe. An energy acceptor probe was located at actin Gln41, actin Cys374, or the actin nucleotide-binding site. From these donor-acceptor pairs, FRET efficiencies were determined with and without Ca(2+). Using the atomic coordinates for F-actin, Tm, and the Tn core domain, we searched all possible arrangements for Tm or the Tn core domain on F-actin to calculate the FRET efficiency for each donor-acceptor pair in each arrangement. By minimizing the squared sum of deviations for the calculated FRET efficiencies from the observed FRET efficiencies, we determined the location of Tm segment 167-195 and the Tn core domain on F-actin with and without Ca(2+). The bulk of the Tn core domain is located near actin subdomains 3 and 4. The central helix of TnC is nearly perpendicular to the F-actin axis, directing the N-terminal domain of TnC toward the actin outer domain. The C-terminal region in the I-T arm forms a four-helix-bundle structure with the Tm 175-185 region. After Ca(2+) release, the Tn core domain moves toward the actin outer domain and closer to the center of the F-actin axis. Copyright © 2012 Elsevier Ltd. All rights reserved.

  8. Interpreting metamorphic and metasomatic reactions from mineral textures (United States)

    Austrheim, Hâkon; Putnis, Andrew


    Metamorphism and metasomatism both involve the reequilibration of mineral assemblages due to changes in pressure, temperature and/or chemical environment. The distinction between metasomatism (which is a metamorphic reaction involving a significant change in chemical composition) and metamorphism (essentially isochemical) may appear to be well defined, but since no reaction can occur without transport these definitions require that we specify an arbitrary length scale to distinguish the two processes. It is generally accepted that material transport, even on a local scale, involves a fluid phase, and that dissolution and reprecipitation reactions are involved in converting one assemblage to another (Carmichael, 1969; Philpotts and Ague, 2009). Given that the fluid phase is not just pure water, a key question is the thermodynamic as well as the kinetic role of the fluid phase in the reaction. In a metamorphic event P-T paths are inferred from sequences of discontinuous reactions assumed to take place as a rock crosses univariant reaction lines in P-T space and continuous reactions involving chemical reequilibration in coexisting minerals. Any fluid is assumed to merely play a catalytic role and not affect the thermodynamics of the reaction. The criteria for a ‘metamorphic event' are primarily based on mineral textures in a rock, but this is subject to misinterpretation, as pointed out by Vernon et al. (2008). Microstructural criteria which have been considered reliable as indicating a sequence of metamorphic reactions in P,T space include corona structures and partial replacement textures, both suggesting arrested metamorphic reactions (Vernon and Clarke, 2008). As a typical example of a corona structure we describe the textural and chemical characteristics of a reaction between kyanite and garnet to form sapphirine and plagioclase. Based on Na mobility. we argue that the availability and chemistry of the fluid is the primary driver for the reaction (Straume and

  9. Microparticles obtained by complex coacervation: influence of the type of reticulation and the drying process on the release of the core material

    Directory of Open Access Journals (Sweden)

    Izabela Dutra Alvim


    Full Text Available Microparticles obtained by complex coacervation were crosslinked with glutaraldehyde or with transglutaminase and dried using freeze drying or spray drying. Moist samples presented Encapsulation Efficiency (%EE higher than 96%. The mean diameters ranged from 43.7 ± 3.4 to 96.4 ± 10.3 µm for moist samples, from 38.1 ± 5.36 to 65.2 ± 16.1 µm for dried samples, and from 62.5 ± 7.5 to 106.9 ± 26.1 µm for rehydrated microparticles. The integrity of the particles without crosslinking was maintained when freeze drying was used. After spray drying, only crosslinked samples were able to maintain the wall integrity. Microparticles had a round shape and in the case of dried samples rugged walls apparently without cracks were observed. Core distribution inside the particles was multinuclear and homogeneous and core release was evaluated using anhydrous ethanol. Moist particles crosslinked with glutaraldehyde at the concentration of 1.0 mM.g-1 protein (ptn, were more efficient with respect to the core retention compared to 0.1 mM.g-1 ptn or those crosslinked with transglutaminase (10 U.g-1 ptn. The drying processes had a strong influence on the core release profile reducing the amount released to all dry samples

  10. Evidence of volcanism in the Paleozoic metamorphic basement of the Sierra Madre Oriental, NE-Mexico (United States)

    Torres Sanchez, S. A.; Ramirez Fernandez, J. A.; Jenchen, U.; Barboza Gudino, J. R.; Augustsson, C.


    The Paleozoic metamorphic basement of the Sierra Madre Oriental comprises a wide variety of protoliths including psammites, pelites, tuffs, lava flows, pillow lavas as well as ultramafic rocks, metamorphosed under subgreenschist to greenschist facies. All these units are grouped under the Granjeno Schist Formation (GSF). They are limited by faults in the core of the Huizachal-Peregrina Anticlinorium (HPA), and in the uplifts of Miquihuana (M), Bustamante (B) and Aramberri (A) in NE Mexico. The aim of this work is to compare the metavolcanic units in the different localities, looking for a genetic relationship between them. These units include four different lithologies: a) pale green fine grained interstratified horizons of basic to intermediate metatuffs, b) massive, green and coarse greenstones, representing massive metalavas, c) well preserved dark green pillow lavas, and d) pale to dark massive talc schists. They are mainly massive, interbedded with the metasediments and do not display the typical pervasive schistosity of GSF. Preliminary analysis of the metavolcanic units indicate that they are alkaline (AB/OIB). Their origin is still under debate, they could be originated during continental intraplate volcanism or from an ancient oceanic island (?). It has to be noted that the Silurian to Permian HPÁs sedimentary sequence, encloses only a rhyolitic body (Aserradero Fm.) that cannot be directly correlated with the metavolcanics. The metamorphism age (≈ 330±30 Ma) and protoliths of all localities are similar, but there are enough petrographic differences to interpret that the metamorphic conditions are not similar at all. It is proposed that the vulcanosedimentary sequence were deposited in a forearc basin along the Pangea western margin, and later metamorphosed during the subduction process through Carboniferous times.

  11. Aberrant assembly complexes of the reaction center light-harvesting 1 PufX (RC-LH1-PufX) core complex of Rhodobacter sphaeroides imaged by atomic force microscopy. (United States)

    Olsen, John D; Adams, Peter G; Jackson, Philip J; Dickman, Mark J; Qian, Pu; Hunter, C Neil


    In the purple phototrophic bacterium Rhodobacter sphaeroides, many protein complexes congregate within the membrane to form operational photosynthetic units consisting of arrays of light-harvesting LH2 complexes and monomeric and dimeric reaction center (RC)-light-harvesting 1 (LH1)-PufX "core" complexes. Each half of a dimer complex consists of a RC surrounded by 14 LH1 αβ subunits, with two bacteriochlorophylls (Bchls) sandwiched between each αβ pair of transmembrane helices. We used atomic force microscopy (AFM) to investigate the assembly of single molecules of the RC-LH1-PufX complex using membranes prepared from LH2-minus mutants. When the RC and PufX components were also absent, AFM revealed a series of LH1 variants where the repeating α(1)β(1)(Bchl)2 units had formed rings of variable size, ellipses, and spirals and also arcs that could be assembly products. The spiral complexes occur when the LH1 ring has failed to close, and short arcs are suggestive of prematurely terminated LH1 complex assembly. In the absence of RCs, we occasionally observed captive proteins enclosed by the LH1 ring. When production of LH1 units was restricted by lowering the relative levels of the cognate pufBA transcript, we imaged a mixture of complete RC-LH1 core complexes, empty LH1 rings, and isolated RCs, leading us to conclude that once a RC associates with the first α1β1(Bchl)2 subunit, cooperative associations between subsequent subunits and the RC tend to drive LH1 ring assembly to completion. © 2014 by The American Society for Biochemistry and Molecular Biology, Inc.

  12. Seismicity in an active rift exposing ultra-high pressure metamorphic rocks: D'Entrecasteaux Islands, Papua New Guinea (United States)

    Dieck, C. C.; Abers, G. A.; Eilon, Z.; Gaherty, J. B.; Verave, R.


    Continental crust has rifted in the Woodlark Rift, Papua New Guinea for the last 6Ma, with sea floor spreading where extension is largest and farthest from the Euler pole. The D'Entrecasteaux Islands (DIs) lie immediately west of the present-day seafloor spreading centers. Metamorphic core complexes (MCCs) dominate these islands, some of which contain the youngest known ultra-high pressure (UHP) metamorphic rocks. These have been exhumed at 90 km depth, coeval with continental rifting. Sea floor magnetic anomalies and GPS data indicate 20-30 mm/yr extension should be accommodated across the rift near the DIs; however, it has been debated whether that takes place along the MCC-bounding faults, or parallel structures bounding the Papua Peninsula. To address these questions, we report on regional seismicity from the 2010-2011 CDPapua passive seismic experiment, which comprised an array of 31 on-land and 8 ocean-bottom seismographs over a 200km x 300km region centered on the DIs. We have used P- and S- wave arrivals to detect and locate local earthquakes. Most detected earthquakes lie outside the array, at very active subduction zones 300-600 km distant, but still an average of 3.3 local earthquakes within the array are observed to occur each day. Unexpectedly, we located a cluster of intermediate depth earthquakes, ranging from 70-110 km depth. This deep activity represents the first evidence of sub-crustal seismicity in this region and comes from the depths at which UHP rocks originate, ~100 km along strike from where they are exposed. The seismicity lies toward the Euler pole from the DIs, where extension is less, so potentially represents a not-yet-exhumed source region of UHP rocks in a less-extended region. Most crustal seismicity lies proximate to the D'Entrecasteaux Islands and is concentrated on the dome-bounding faults, revealing that these structures are actively accommodating extension and that MCC exhumation persists. Just SW of the westernmost DI, a dense

  13. Chafalote metamorphic suite metapelitic rocks (southheastern Uruguayan shield)

    International Nuclear Information System (INIS)

    Masquelin, H.; Nessi, A.; Paris, A.


    Chafalote Metamorphic Suite is characterized by politic, psamitic, calc-silicate and mafic gneisses, which are affected by a Neoproterozoic granulite facies metamorphism. The rocks derived from semipelite and pelite protoliths show mineral assemblages and textures typical for temperature over 8000 0 C. The metapelite fabrics are described to interpret these protoliths and to better understand the relationships between metamorphism and deformation. The main reference surface is interpreted as a S composite banding (Sb=So/S1/S2). Some layers record graded and crossed bedding preserved in fine-grained quartz-rich semipelites. They contain orthopyroxene. A correlation is presented between thermal peak fabrics and retrograde path derived fabrics, both for meapelites.

  14. Complex sclerosing lesions and radial sclerosing lesions on core needle biopsy: Low risk of carcinoma on excision in cases with clinical and imaging concordance. (United States)

    Nakhlis, Faina; Lester, Susan; Denison, Christine; Wong, Stephanie M; Mongiu, Anne; Golshan, Mehra


    Complex or radial sclerosing lesions (CSL/RSL) are uncommon diagnoses on core needle biopsy with a reported upgrade rate ranging between 0% and 23%. As a result, their management remains controversial. In this study, we sought to determine the rate of malignancy on excision for patients with pure CSL/RSL on core biopsy, and to evaluate future breast cancer risk when CSL/RSL is managed without excision. We retrospectively reviewed 118 cases of CSL/RSL diagnosed on image-guided breast biopsies between 2005 and 2014 at our institution. Of 98 analyzed patients, 34 (35%) underwent excision and 64 (65%) were observed. Demographic and clinical variables between excision and observation groups were compared. In excised specimens, factors associated with upgrade to malignancy were evaluated. The median age at diagnosis was 49 years (range, 27-88 years). In the excision group, 3/34 cases were associated with malignancy, an overall upgrade rate of 9%. All malignant cases had core needle biopsies interpreted as discordant and were BIRADS 4B or more on imaging. In the observation group, at a median follow-up of 2.2 years, 3/64 (5%) patients developed ipsilateral cancers, all of which were distant from the index CSL/RSL. In our series, we report a 9% malignancy rate on excision of BIRADS >4C lesions characterized as CSL/RSL on core biopsy. In patients with concordant biopsies and BIRADS 4A or lower lesions who underwent observation, we found a low rate of subsequent ipsilateral cancers. Further studies are needed to confirm that for CSL/RSL in concordant core biopsies and BIRADS 4A or lower, nonpalpable lesions, observation may be a reasonable alternative to excision. © 2017 Wiley Periodicals, Inc.

  15. Granitoid magmatism of Alarmaut granite-metamorphic dome, West Chukotka, NE Russia (United States)

    Luchitskaya, M. V.; Sokolov, S. D.; Bondarenko, G. E.; Katkov, S. M.


    domes at Russian North-East. Paper 2. Magmatism, metamorphism and migmatization in Late Mesozoic domes // Pacific geology. 1996. V. 15. № 1. P. 84-93. (in Russian) 13. Bering Strait Geologic Field Party, Koolen metamorphic complex, NE Russia: implications for the tectonic evolution of the Bering Strait region // Tectonics, vol. 16, no. 5, p. 713-729 14. Bondarenko G.E., Luchitskaya M.V. Mesozoic tectonic evolution of Alarmaut rise // Byul. MOIP. Otd. Geol. V. 78. Is. 3. P. 25-38. (in Russian) 15. Katkov S.M., Strikland A., Miller E.L. Age of granite batholiths in the Anyui-Chukotka Foldbelt // Doklady. Earth Sciences. 2007. Vol. 414. № 4. P. 515-518. 16. Amato J.M., Wright J.E. Potassic mafic magtism in the Kigluaik gneiss dome, northern Alaska: a geochemical study of arc magmatism in an extensional tectonic setting // J. Geophys. Res. 1997. Vol.102. N B4. P.8065-8084 17. Tikhomirov P.L., Luchitskaya M.V., Kravchenko-Berezhnoy I.R. Comparison of Cretaceous granitoids of the Chaun tectonic zone to those of the Taigonos Peninsula, NE Asia: rock chemistry, composition of rock forming minerals, and conditions of formation // Stephan Mueller series. Geology and Tectonic Origins of Northeast Russia: A Tribute to Leonid Parfenov (in press) 28. Velikoslavinsky S.D. Geochemical typification of acid magmatic rocks of leading geodynamic settings // Petrology. 2003. V. 11. № 4. P.363-380. (in Russian) 19. Pearce J.A. Sources and settings of granitic rocks // Episodes. 1996. V. 19. N. 4. P. 120-125

  16. The Heart of China revisited: II Early Paleozoic (ultra)high-pressure and (ultra)high-temperature metamorphic Qinling orogenic collage (United States)

    Bader, Thomas; Franz, Leander; Ratschbacher, Lothar; de Capitani, Christian; Webb, A. Alexander G.; Yang, Zhao; Pfänder, Jörg A.; Hofmann, Mandy; Linnemann, Ulf


    Orogens with multiple (ultra)high-pressure ((U)HP) and (ultra)high-temperature ((U)HT) metamorphic events provide a complex but telling record of oceanic and continental interaction. The Early Paleozoic history of the "Heart of China," the Qinling orogenic collage, offers snapshots of at least three (U)HP and two (U)HT metamorphic events. The preservation of remnants of both oceanic and continental domains together with a ≥110 Myr record of magmatism allows the reconstruction of the processes that resulted in this disparate metamorphism. Herein, we first illuminate the pressure-temperature-time (P-T-t) evolution of the Early Paleozoic (U)HP and (U)HT events by refining the petrographic descriptions and P-T estimates, assess published, and employ new U/Th-Pb zircon, monazite, and titanite, and 40Ar-39Ar phengite geochronology to date the magmatic and metamorphic events. Then we explore how the metamorphic and magmatic events are related tectonically and how they elucidate the affinities among the various complexes in the Qinling orogenic collage. We argue that a Meso-Neoproterozoic crustal fragment—the Qinling complex—localized subduction-accretion events that involved subduction, oceanic-arc formation, and back-arc spreading along its northern margin, and mtantle-wedge exhumation and spreading-ridge subduction along its southern margin.

  17. The FA Core Complex Contains a Homo-dimeric Catalytic Module for the Symmetric Mono-ubiquitination of FANCI-FANCD2

    Directory of Open Access Journals (Sweden)

    Paolo Swuec


    Full Text Available Activation of the main DNA interstrand crosslink repair pathway in higher eukaryotes requires mono-ubiquitination of FANCI and FANCD2 by FANCL, the E3 ligase subunit of the Fanconi anemia core complex. FANCI and FANCD2 form a stable complex; however, the molecular basis of their ubiquitination is ill defined. FANCD2 mono-ubiquitination by FANCL is stimulated by the presence of the FANCB and FAAP100 core complex components, through an unknown mechanism. How FANCI mono-ubiquitination is achieved remains unclear. Here, we use structural electron microscopy, combined with crosslink-coupled mass spectrometry, to find that FANCB, FANCL, and FAAP100 form a dimer of trimers, containing two FANCL molecules that are ideally poised to target both FANCI and FANCD2 for mono-ubiquitination. The FANCC-FANCE-FANCF subunits bridge between FANCB-FANCL-FAAP100 and the FANCI-FANCD2 substrate. A transient interaction with FANCC-FANCE-FANCF alters the FANCI-FANCD2 configuration, stabilizing the dimerization interface. Our data provide a model to explain how equivalent mono-ubiquitination of FANCI and FANCD2 occurs.

  18. Metamorphic history of Early Archean rocks of Anabaric shield

    International Nuclear Information System (INIS)

    Bibikova, E.V.; Belov, A.N.; Gracheva, T.V.; Makarov, V.A.; Rozen, O.M.; Sumin, L.V.


    U-Pb isotopic and thermoisochronous investigation into accessory zircons referring to two generations including relict magmatogenic and newly formed metamorphogenic ones, is conducted to ascertain the metamorphism time and substrate age evaluation. The results of the investigation conducted state two metamorphism stages within the limits of Anabaric shield: 1.97±0.02 billions of years ago and 2.6±0.1 billions of years ago, characterized by various geochemical parameters. Premetamorphic age of Daodynsk series roks is no younger than 3±2.0 billions of years

  19. Peak metamorphic temperatures from cation diffusion zoning in garnet

    DEFF Research Database (Denmark)

    Smit, Matthijs Arjen; Scherer, Erik; Mezger, Klaus


    is robust and provides a reliable means of estimating peak temperatures for different types of high-grade metamorphic rock. The tool could be of particular advantage in rocks where critical assemblages for conventional thermometry do not occur or have been replaced during retrogression.......) to develop a tool that uses the diffusion zoning of these cations in garnet to constrain peak temperature conditions for garnet-bearing rocks. The thermometric approach was externally tested by applying it to garnet crystals from various metamorphic terranes worldwide and comparing the results to published...

  20. Comparison between results of detailed tectonic studies on borehole core vs microresistivity images of borehole wall from gas-bearing shale complexes, Baltic Basin, Poland. (United States)

    Bobek, Kinga; Jarosiński, Marek; Pachytel, Radomir


    , cemented with calcite, were clearly visible in scanner image. We have also observed significantly lower density of veins in core than in the XRMI that occurs systematically in one formation enriched with carbonate and dolomite. In this case, veins are not fractured in core and obliterated for bare eye by dolomitization, but are still contrastive in respect of electric resistance. Calculated density of bedding planes per 1 meter reveals systematically higher density of fractures observed on core than in the XRMI (depicted automatically by interpretation program). This difference may come from additional fracking due to relaxation of borehole core while recovery. Comparison of vertical joint fractures density with thickness of mechanical beds shows either lack of significant trends or a negative correlation (greater density of bedding fractures correspond to lower density of joints). This result, obtained for shale complexes contradict that derived for sandstone or limestone. Boundary between CLUs are visible on both: joint and bedding fracture density profiles. Considering small-scale faults and slickensides we have obtained good agreement between results of core and scanner interpretation. This study in the frame of ShaleMech Project funded by Polish Committee for Scientific Research is in progress and the results are preliminary.

  1. Metamorphic P-T paths of metapelitic granulites from the Larsemann Hills, East Antarctica (United States)

    Tong, Laixi; Liu, Xiaohan; Wang, Yanbin; Liang, Xirong


    Through detailed textural observations, a peak M1 assemblage garnet + orthopyroxene + cordierite + K-feldspar has been identified in a structurally early Al-rich metapelitic granulite lens from the Larsemann Hills, East Antarctica. The M1 assemblage has been overprinted by M2 cordierite corona and M3 orthopyroxene + cordierite symplectite on garnet grains. Quantitative modeling for the peak M1 assemblage via the THERMOCALC program in the KFMASH system suggests that it was formed by the crossing of the univariant reaction garnet + biotite = cordierite + orthopyroxene + K-feldspar + melt under P-T conditions of 6-8 kbar and 840-880 °C, followed by post-peak near isobaric cooling. However, the average P-T calculations for the boron-bearing pelitic granulite indicate that peak M1 conditions reached ~ 9.0 kbar and ~ 900 °C, and the overprinting M2 assemblage formed under P-T conditions of ~ 7.0 kbar and 800-850 °C, reflecting a post-peak near isothermal decompression. P-T estimates show that M3 conditions reached 4-5 kbar and 700-750 °C. These imply that the M1 metamorphic evolution of the region displays contrasting P-T paths, while M2 to M3 evolution indicates a decompression-cooling process. The available chronological data support that the M1 metamorphic evolution occurred during the late Proterozoic (1000-900 Ma) Grenvillian high-grade compression tectonic event (D1), and was accompanied by strong magmatism, showing a close affinity to the northern Prince Charles Mountains and the Rayner complex. However, the overprinted M2 to M3 metamorphic evolution formed during the early Palaeozoic (~ 530 Ma) Pan-African high-grade tectonic events (D2-D3), and was associated with an important intracontinental reworking. This study presents an example for interpreting a complex polymetamorphic history.

  2. Metamorphism, P-T-t Conditions of Formation, and Prospects for the Practical Use of Al2SiO5 Polymorphs, Chloritoid, and Staurolite (Yenisei Ridge) (United States)

    Kozlov, P. S.


    The Yenisei Ridge is an accretion–collisional orogen located in the southwestern frame of the Siberian Craton in the interfluve between Podkamennaya Tunguska, Angara, Kan, and Yenisei rivers. The Precambrian mono- and polymetamorphic complexes composed predominantly of the Mesoarchean–Neoproterozoic metapelitic rocks have been studied. Based on the typification of metamorphic complexes by pressure, temperature, metamorphic gradient, as well as age of metamorphism, the location scheme of the fields of the Precambrian sedimentary–metamorphic rock which are prospective for searching deposits of high-alumina metamorphic minerals (andalusite, kyanite, and sillimanite, chloritoid, and staurolite) in the Trans-Angara segment of the Yenisei Region, was compiled. The Teya sillimanite and Panimbinsk andalusite deposits, which are confined to the fields of regional metamorphic complexes of iron-alumina metapelites of the And–Sill facies series, are recommended as a priority for the organization of prospecting works and the subsequent involvement to the metallurgical industry. These metapelites are classified as monomineral. Owing to widespread occurrence and abundance of andalusite and sillimanite, the above deposits have significant inferred resources. Stratiform deposits of garnet–staurolite and chloritoid high-alumina rocks are still insufficiently studied and should be investigated further. The prospects for the possible use of high-alumina andalusite and sillimanite together with Middle Tatarka and Kiya nepheline syenite massifs and the bauxites of the Chadobets uplift, already being explored in the region, for production of aluminum oxide, silumin, and aluminum, as well as, the prospects for the expansion of the raw material base of the Boguchansk Electrometallurgical Complex, brought into operation in 2016 in the Lower Angara region, are considered.

  3. 40Ar/ 39Ar mineral ages within metamorphic clasts from the Kuma Group (Eocene), central Shikoku, Japan: Implications for tectonic development of the Sambagawa accretionary prism (United States)

    Takasu, A.; Dallmeyer, R. D.


    The Sambagawa metamorphic belt exposed in central Shikoku records a high- P/T metamorphism. It is comprised by the Oboke nappe and the structurally overlying, internally imbricated Besshi nappe complex. The Besshi nappe complex locally is unconformably overlain by the Kuma Group (Eocene) which consists of conglomerates and subordinate sandstones and mudstones. Clasts within Kuma conglomerates exposed in the Kamegamori district include low-grade schists (derived from the unconformably underlying Sambagawa complex) and high-grade metamorphic rocks of uncertain provenance (including garnet-amphibolite and oligoclase-bearing pelitic schist). 36Ar/ 40Ar vs. 39Ar/ 40Ar isotope correlation ages recorded by hornblende from two amphibolite clasts are 131.1 ± 4.9 Ma and 156.8 ± 4.3 Ma. These are interpreted to date post-metamorphic cooling through temperatures required for intracrystalline retention of argon, and are older than cooling ages previously reported from any presently exposed segments of the Sambagawa terrane. Plateau ages of 108.8 ± 0.7 Ma and 115.7 ± 0.6 Ma are recorded by muscovite from two clasts of schist. Muscovite within a proximal basement exposure of unconformably underlying Sambagawa pelitic schist records a plateau age of 78.7 ± 0.5 Ma. Combined with isotopic ages previously reported for the Sambagawa terrane, 40Ar/ 39Ar data from clasts in the Kuma Group suggest that metamorphic culmination within a high-grade source terrane occured at c. 185-145 Ma. Sectors of this complex cooled through c. 500°C at c. 150 Ma. Other portions cooled through c. 500°C at c. 130 Ma. Contrasts in the cooling ages likely reflect internal imbrication within the source terrane. The Besshi nappe complex reached peak metamorphic conditions at c. 100-90 Ma and experienced relatively rapid uplift and cooling at c. 85-75 Ma. The Besshi nappe complex was structurally emplaced onto the Oboke nappe which attained peak metamorphic conditions at c. 75 Ma. Subsequently, the

  4. Modeling of the catalytic core of Arabidopsis thaliana Dicer-like 4 protein and its complex with double-stranded RNA. (United States)

    Mickiewicz, Agnieszka; Sarzyńska, Joanna; Miłostan, Maciej; Kurzyńska-Kokorniak, Anna; Rybarczyk, Agnieszka; Łukasiak, Piotr; Kuliński, Tadeusz; Figlerowicz, Marek; Błażewicz, Jacek


    Plant Dicer-like proteins (DCLs) belong to the Ribonuclease III (RNase III) enzyme family. They are involved in the regulation of gene expression and antiviral defense through RNA interference pathways. A model plant, Arabidopsis thaliana encodes four DCL proteins (AtDCL1-4) that produce different classes of small regulatory RNAs. Our studies focus on AtDCL4 that processes double-stranded RNAs (dsRNAs) into 21 nucleotide trans-acting small interfering RNAs. So far, little is known about the structures of plant DCLs and the complexes they form with dsRNA. In this work, we present models of the catalytic core of AtDCL4 and AtDCL4-dsRNA complex constructed by computational methods. We built a homology model of the catalytic core of AtDCL4 comprising Platform, PAZ, Connector helix and two RNase III domains. To assemble the AtDCL4-dsRNA complex two modeling approaches were used. In the first method, to establish conformations that allow building a consistent model of the complex, we used Normal Mode Analysis for both dsRNA and AtDCL4. The second strategy involved template-based approach for positioning of the PAZ domain and manual arrangement of the Connector helix. Our results suggest that the spatial orientation of the Connector helix, Platform and PAZ relative to the RNase III domains is crucial for measuring dsRNA of defined length. The modeled complexes provide information about interactions that may contribute to the relative orientations of these domains and to dsRNA binding. All these information can be helpful for understanding the mechanism of AtDCL4-mediated dsRNA recognition and binding, to produce small RNA of specific size. Copyright © 2016 Elsevier Ltd. All rights reserved.

  5. Three-dimensional structure of the ligand-binding core of GluR2 in complex with the agonist (S)-ATPA

    DEFF Research Database (Denmark)

    Lunn, Marie-Louise; Hogner, Anders; Stensbøl, Tine B


    Two X-ray structures of the GluR2 ligand-binding core in complex with (S)-2-amino-3-(5-tert-butyl-3-hydroxy-4-isoxazolyl)propionic acid ((S)-ATPA) have been determined with and without Zn(2+) ions. (S)-ATPA induces a domain closure of ca. 21 degrees compared to the apo form. The tert-butyl moiety...... of (S)-ATPA is buried in a partially hydrophobic pocket and forces the ligand into the glutamate-like binding mode. The structures provide new insight into the molecular basis of agonist selectivity between AMPA and kainate receptors....

  6. Complex New Product Development projects - How the Project Manager’s Information Sharing With Core Actors Changes Over Time

    DEFF Research Database (Denmark)

    Jepsen, Lisbeth Brøde


    with the information sharing during NPD projects is limited; therefore, this study of longitudinal objective email data (4658 emails) during a NPD project contributes to theory and practice by advancing our understanding of when and how the project manager establishes relationships with different core actors inside......A heavily burdened project manager must ensure effective information sharing with actors inside and outside the organization because this is a necessary condition for a new product development (NPD) project to achieve its objectives. Knowledge, however, on who actually assists a project manager...

  7. Complex New Product Development projects - How the Project Manager’s Information Sharing With Core Actors Changes Over Time

    DEFF Research Database (Denmark)

    Jepsen, Lisbeth Brøde


    A heavily burdened project manager must ensure effective information sharing with actors inside and outside the organization because this is a necessary condition for a new product development (NPD) project to achieve its objectives. Knowledge, however, on who actually assists a project manager...... with the information sharing during NPD projects is limited; therefore, this study of longitudinal objective email data (4658 emails) during a NPD project contributes to theory and practice by advancing our understanding of when and how the project manager establishes relationships with different core actors inside...

  8. The Metamorphic Rocks-Hosted Gold Mineralization At Rumbia Mountains Prospect Area In The Southeastern Arm of Sulawesi Island, Indonesia

    Directory of Open Access Journals (Sweden)

    Hasria Hasria


    Full Text Available Recently, in Indonesia gold exploration activities  are not only focused along volcanic-magmatic belts, but also starting to shift along metamorphic and sedimentary terrains. The study area is located in Rumbia mountains, Bombana Regency, Southeast Sulawesi Province. This paper is aimed to describe characteristics of alteration and ore mineralization associated  with metamorphic rock-related gold deposits.  The study area is found the placer and  primary gold hosted by metamorphic rocks. The gold is evidently derived from gold-bearing quartz veins hosted by Pompangeo Metamorphic Complex (PMC. These quartz veins are currently recognized in metamorphic rocks at Rumbia Mountains. The quartz veins are mostly sheared/deformed, brecciated, irregular vein, segmented and  relatively massive and crystalline texture with thickness from 1 cm to 15.7 cm. The wallrock are generally weakly altered. Hydrothermal alteration types include sericitization, argillic, inner propylitic, propylitic, carbonization and carbonatization. There some precious metal identified consist of native gold and ore mineralization including pyrite (FeS2, chalcopyrite (CuFeS2, hematite (Fe2O3, cinnabar (HgS, stibnite (Sb2S3 and goethite (FeHO2. The veins contain erratic gold in various grades from below detection limit <0.0002 ppm to 18.4 ppm. Based on those characteristics, it obviously indicates that the primary gold deposit present in the study area is of orogenic gold deposit type. The orogenic gold deposit is one of the new targets for exploration in Indonesia

  9. Engineering the metamorphic chemokine Lymphotactin/XCL1 into the GAG-binding, HIV-inhibitory dimer conformation


    Fox, Jamie C.; Tyler, Robert C.; Guzzo, Christina; Tuinstra, Robbyn L.; Peterson, Francis C.; Lusso, Paolo; Volkman, Brian F.


    Unlike other chemokines, XCL1 undergoes a distinct metamorphic interconversion between a canonical monomeric chemokine fold and a unique β-sandwich dimer. The monomeric conformation binds and activates the receptor XCR1, while the dimer binds extracellular matrix glycosaminoglycans and has been associated with anti-human immunodeficiency virus (HIV) activity. Functional studies of WT-XCL1 are complex as both conformations are populated in solution. To overcome this limitation, we engineered a...

  10. Dense SDM (12-core × 3-mode) transmission over 527 km with 33.2-ns mode-dispersion employing low-complexity parallel MIMO frequency-domain equalization

    DEFF Research Database (Denmark)

    Shibahara, K.; Mizuno, T.; Takara, H.

    We demonstrate 12-core × 3-mode dense SDM transmission over 527 km graded-index multi-core few-mode fiber without mode-dispersion management. Employing low baud rate multi-carrier signal and frequency-domain equalization enables 33.2-ns DMD compensation with low computational complexity. © 2015 OSA...

  11. New cyclic tetranuclear copper(II) complexes containing quadrilateral cores: Synthesis, structure, spectroscopy and their interactions with DNA in aqueous solution (United States)

    Giri, Gopal C.; Haldar, Shobhraj; Ghosh, Aloke Kumar; Chowdhury, Priyanka; Carrella, Luca; Ghosh, Utpal; Bera, Manindranath


    Three new cyclic tetranuclear copper(II) complexes, Tetrakis{3-[(2-pyridylmethyl)-amino]-propionato}(tetrachloro)tetracopper(II)methanolhydrate (1·CH3OH·H2O), Tetrakis{3-[(2-pyridylmethyl)-amino]-propionato}(tetrathiocyanato)tetracopper(II) (2) and Tetrakis{3-[(2-pyridylmethyl)-amino]-propionato}(tetraazido)tetracopper(II) (3) have been synthesized by exploiting the chelating ability and bridging potential of a carboxyamine functionalized tridentate ligand, HL (HL = 3-[(2-Pyridylmethyl)-amino]-propionic acid). Complexes 1, 2 and 3 have been synthesized by carrying out reaction of the ligand HL with stoichiometric amounts of CuCl2·2H2O, CuCl2·2H2O/NH4SCN, and CuCl2·2H2O/NaN3, respectively, in the presence of NMe4OH at ambient temperature. Various analytical techniques have been employed to characterize the complexes, including single crystal X-ray diffraction study of 1. Structures of complexes 2 and 3 have been optimized by DFT calculation at B3LYP/6-311G level. Analysis of X-ray crystal structure reveals that the metallic core of complex 1 contains four distorted square pyramidal Cu(II) ions. The Cu(II) ions in each complex are arranged at the corners of a quadrilateral showing a μ2:η1:η1syn-anti bidentate bridging mode of four carboxylate groups of L- ligands with each bridging between two Cu(II) ions. These complexes represent a new family of 16-MCCuII-4 metallocoronates with repeating -[CuIIsbnd Osbnd Csbnd O]- units. In aqueous solution (pH∼7.5), the interactions of complexes with DNA have been investigated by UV-Vis and fluorescence titration spectroscopy, and viscosity measurements.

  12. Mixed chloride/phosphine complexes of the dirhenium core. 10. Redox reactions of an edge-sharing dirhenium(III) non-metal-metal-bonded complex, Re(2)(mu-Cl)(2)Cl(4)(PMe(3))(4). (United States)

    Cotton, F A; Dikarev, E V; Petrukhina, M A


    Reduction and oxidation reactions of the dirhenium(III) non-metal-metal-bonded edge-sharing complex, Re(2)(mu-Cl)(2)Cl(4)(PMe(3))(4) (1), have been studied. Several new mono- and dinuclear rhenium compounds have been isolated and structurally characterized in the course of this study. Reductions of 1 with 1 and 2 equiv of KC(8) result in an unusual face-sharing complex having an Re(2)(5+) core, Re(2)(mu-Cl)(3)Cl(2)(PMe(3))(4) (2), and a triply bonded Re(II) compound, 1,2,7,8-Re(2)Cl(4)(PMe(3))(4) (3), respectively. Two-electron reduction of 1 in the presence of tetrabutylammonium chloride affords a new triply bonded complex of the Re(2)(4+) core, [Bu(n)()(4)N][1,2,7-Re(2)Cl(5)(PMe(3))(3)] (4). Oxidation of 1 with NOBF(4) yields a Re(IV) mononuclear compound, trans-ReCl(4)(PMe(3))(2) (5). Two isomers of the monomeric Re(III) anion, [ReCl(4)(PMe(3))(2)](-) (6, 7), have been isolated as side products. The crystal structures of compounds 2 and 4-7 have been determined by X-ray crystallography. The Re-Re distance in the face-sharing complex 2 of 2.686(1) A is relatively short. The metal-metal bond length in anion 4 of 2.2354(7) A is consistent with the usual values for the triply bonded Re(2)(4+) core compounds. In addition, a cis arrangement of trimethylphosphine ligands in the starting material 1 is retained upon reduction in the dinuclear products 2-4.

  13. The post-impact metamorphism textures of various type meteorites (United States)

    Grokhovsky, V.; Muftakhetdinova, R.; Petrova, E.; Yakovlev, G.


    A review of the features of shock metamorphism is given of stone and iron meteorites after high-intensity shock loading; In the simulation experiments, possible structural changes in the meteorite matter are demonstrated with significant peak pressure and temperature. This allows obtaining structural changes from melting to plastic deformation of the test substance.

  14. Analysis of lineament swarms in a Precambrian metamorphic rocks

    Indian Academy of Sciences (India)

    Addressing the geologic significance of lineaments and their correlation with joints/fractures is still unclear. The present study attempts to analyse the lineament swarms developed in a Precambrian metamorphic terrain in India using both unfiltered and filtered techniques. The unfiltered analysis technique shows that the ...

  15. Analysis of lineament swarms in a Precambrian metamorphic rocks ...

    Indian Academy of Sciences (India)

    Analysis of lineament swarms in a Precambrian metamorphic rocks in India ... Lineament; fracture; remote sensing; hydrology; data analysis. ... The unfiltered analysis technique shows that the major lineament and fracture trends are oriented along EW and NS directions respectively, thus failing to provide any correlation ...

  16. Metamorphic and Ar/Ar geochronology constraints on the Alakeci shear zone: Implications for the extensional exhumation history of the northern Kazdag Massif, NW Turkey

    International Nuclear Information System (INIS)

    Bonev, N; Beccaletto, L; Robyr, M; Monie, P


    The Kazdag Massif exposes a metamorphic dome in the Biga Peninsula of northwest Turkey. An extensional origin has been proposed for the dome, limited on both flanks by detachments and/or shear zones. The northern flank is bounded by the extensional Alakeci Shear Zone (ASZ), whose P-T-t path is still poorly known. We therefore focus on its metamorphic conditions and related temporal history to precise its tectono-metamorphic evolution. The local tectonostratigraphy in structurally ascending order comprises: (i) the high-grade metamorphic core rocks of the Kazdag Massif (gneisses and micaschists intercalated with amphibolites and marbles); (ii) the two kilometer-thick ASZ; (iii) the overlaying unmetamorphosed pre-Cenomanian accretionary Cetmi melange; and (iv) Neogene sedimentary and volcanic cover rocks. ASZ mylonites were derived from both the core rocks and the melange lithologies. From the north to the south the mylonitic fabrics in the ASZ depict a top-to-the N-NNE shearing, parallel to the NNE-plunging stretching lineation and NNW-dipping mylonitic foliation. This geometry implies normal sense movement i.e. north-side down-dip extensional displacement along this flank of the Kazdag Massif. The northward transition from ductile to brittle-ductile regime through the ASZ shows that the deformation occurred at decreasing temperatures and degree of metamorphism. The paragenesis in equilibrium within the mylonitic gneisses and schists contains Qtz + Fs + Ms + Bt + Grt ± St ± Sill, with late retrogressive chlorite after biotite and garnet. Four samples of ASZ rocks yielded pressures between 6.9-5.7 kbar and temperatures between 706-587 deg. C. Three samples from the mylonitic rocks supplied in situ isochron 36 Ar/ 40 Ar mica ages between 31.2-24.2 Ma, which we interpret to date the cooling of the mylonites following the P-T decrease across the ASZ. The metamorphic and structural results support the extensional character of the ASZ, and sketch transition from

  17. Conservation of core complex subunits shaped the structure and function of photosystem I in the secondary endosymbiont alga Nannochloropsis gaditana

    NARCIS (Netherlands)

    Alboresi, Alessandro; Le Quiniou, Clotilde; Yadav, Sathish K N; Scholz, Martin; Meneghesso, Andrea; Gerotto, Caterina; Simionato, Diana; Hippler, Michael; Boekema, Egbert J.; Croce, Roberta; Morosinotto, Tomas


    Photosystem I (PSI) is a pigment protein complex catalyzing the light-driven electron transport from plastocyanin to ferredoxin in oxygenic photosynthetic organisms. Several PSI subunits are highly conserved in cyanobacteria, algae and plants, whereas others are distributed differentially in the

  18. Conservation of core complex subunits shaped the structure and function of photosystem I in the secondary endosymbiont alga Nannochloropsis gaditana

    NARCIS (Netherlands)

    Alboresi, Alessandro; Le Quiniou, Clotilde; Yadav, Sathish K N; Scholz, Martin; Meneghesso, Andrea; Gerotto, Caterina; Simionato, Diana; Hippler, Michael; Boekema, Egbert J.; Croce, Roberta; Morosinotto, Tomas

    Photosystem I (PSI) is a pigment protein complex catalyzing the light-driven electron transport from plastocyanin to ferredoxin in oxygenic photosynthetic organisms. Several PSI subunits are highly conserved in cyanobacteria, algae and plants, whereas others are distributed differentially in the

  19. Structure function studies on the lipoate-acetyltransferase--component-X-core assembly of the ox heart pyruvate dehydrogenase complex. (United States)

    Hodgson, J A; De Marcucci, O G; Lindsay, J G


    Component X, the recently recognised subunit of mammalian pyruvate dehydrogenase complex, was shown by immune blotting to be present in all of nine tissues dissected from rat. This finding indicated that component X was not an isoenzyme of the lipoate acetyltransferase (E2) associated with one or a limited number of tissues. Native pyruvate dehydrogenase complex was shown to bind IgG raised to isolated component X, indicating that there were at least some regions of the X subunit exposed at the periphery of the complex. Lipoyl groups of ox heart pyruvate dehydrogenase complex were specifically cross-linked by reaction with phenylene-o-bismaleimide in the presence of pyruvate and the subunits contributing to the products of cross-linking were identified by immune blotting. Species with very high Mr containing both E2 and component X, were formed in high yield, as well as apparent E2/E2 and E2/X dimers and trimers and an X/X dimer. These results showed that acetylated lipoyl groups of different E2 and X subunits were able to interact in all possible combinations. The types of cross-linked E2 products formed suggested that two thiols, reactible with phenylene-o-bismaleimide, were rapidly generated in the presence of pyruvate. The results were most easily explained by the presence of two acetylatable lipoyl groups on each E2 polypeptide.

  20. K-Ar geochronologic evidence for a triassic metamorphic event in the main Chiloe Island, south-central Chile

    International Nuclear Information System (INIS)

    Duhart, P.; Munoz, J


    Pioneers geological reconnaissance studies in the Chiloe Archipelago recognised a Palaeozoic metamorphic basement (Saliot, 1969; Watters and Fleming, 1972; Valenzuela, 1982; Valdivia, 1986). Currently in progress geologic studies (Munoz et al., 1999, Duhart et al., 2000; Antinao et al., 2000) interpreted these rocks as part of the Bahia Mansa Metamorphic Complex (Duhart et al., 2000), well exposed to the north and equivalent to the 'Serie Occidental' (Aguirre et al., 1972). Geochronologic data set indicate that this complex evolved during Devonian to Triassic times. In the main Chiloe Island, this metamorphic complex is mainly conform by metasedimentary and metavolcanic rocks covered by Tertiary sedimentary and volcanic rocks and Quaternary glacial, fluvial, estuarine, beach, eolian and fluvial deposits. According to north-west and north-south lineament observed in satellite images, regional magnetic maps and topographic features, the main Chiloe island have been divide in northern, central and southern segments (Munoz et al., 1999). These lineaments are interpreted as regional faults but their ages and cinematic are not well constrained. The central segment was interpreted as an uplifted tectonic block and recent studies in the northern part of this segment have identified an intrusive body herein named as 'Metalqui Pluton'. Although the age of this pluton is unknown yet, Cretaceous intrusive rocks in the same tectonic setting of the Metalqui Pluton have been reported in the Valdivia area (Munizaga et al., 1988; Duhart et al., 1998). Previous U-Pb radiometric ages for detrital zircons from pelitic schists in the northern segment indicated a maximum sediment deposition age during Early to Middle Devonian (Duhart et al., 1999). Also, Triassic K-Ar and 40 Ar/ 39 Ar ages have been determined for the main metamorphic and tectonic event. This contribution report Triassic K-Ar ages for the central segment and discuss their regional significance (au)

  1. Investigating the response of biotite to impact metamorphism: Examples from the Steen River impact structure, Canada (United States)

    Walton, E. L.; Sharp, T. G.; Hu, J.; Tschauner, O.


    Impact metamorphic effects from quartz and feldspar and to a lesser extent olivine and pyroxene have been studied in detail. Comparatively, studies documenting shock effects in other minerals, such as double chain inosilicates, phyllosilicates, carbonates, and sulfates, are lacking. In this study, we investigate impact metamorphism recorded in crystalline basement rocks from the Steen River impact structure (SRIS), a 25 km diameter complex crater in NW Alberta, Canada. An array of advanced analytical techniques was used to characterize the breakdown of biotite in two distinct settings: along the margins of localized regions of shock melting and within granitic target rocks entrained as clasts in a breccia. In response to elevated temperature gradients along shock vein margins, biotite transformed at high pressure to an almandine-Ca/Fe majorite-rich garnet with a density of 4.2 g cm-3. The shock-produced garnets are poikilitic, with oxide and silicate glass inclusions. Areas interstitial to garnets are vesiculated, in support of models for the formation of shock veins via oscillatory slip, with deformation continuing during pressure release. Biotite within granitic clasts entrained within the hot breccia matrix thermally decomposed at ambient pressure to produce a fine-grained mineral assemblage of orthopyroxene + sanidine + titanomagnetite. These minerals are aligned to the (001) cleavage plane of the original crystal. In this and previous work, the transformation of an inosilicate (pargasite) and a phyllosilicate (biotite) to form garnet, an easily identifiable, robust mineral, has been documented. We contend that in deeply eroded astroblemes, high-pressure minerals that form within or in the environs of shock veins may serve as one of the possibly few surviving indicators of impact metamorphism.

  2. Differential equilibration and intergranular diffusion of trace elements during rapid regional metamorphism: constraints from LA-ICP-MS mapping of a garnet population (United States)

    George, F. R.; Gaidies, F.


    Trace element zoning contained within a metapelitic garnet population yields information pertaining to a more complex prograde reaction history than is evident in major element zoning patterns and other conventional analyses. In particular, while trace elements may not act as a rate-limiting component for garnet crystallization, their incorporation into garnet growth surfaces provides a nuanced insight into the crystallization history of the population, and the extent of equilibration of trace elements in the matrix. In this study, we present LA-ICP-MS raster maps of trace element concentrations from several population-representative, centrally sectioned garnets from a garnet-grade metapelite of the Sikkim Himalaya, India. Equilibrium forward modeling of garnet crystallization and simulation of diffusional modification indicates that the garnet population crystallized rapidly over <1 Myr between 515 °C/4.5 kbar and 565 °C/5.5 kbar, as a consequence of high heating rates during regional amphibolite-facies metamorphism. While the rate of diffusional homogenization of major divalent cations is interpreted to have exceeded the rate of interfacial advance (yielding simple prograde growth zoning), trace element distributions record a more complex transport history. In particular, yttrium and the heavy rare earth elements (HREE) document a transition from an overprinted sigmoidal core to concentric repeated HREE and yttrium annuli in all crystals. This suggests that there was a discrete increase in the length scale of equilibration along the advancing garnet interface at some point in the growth history. However, there is no evidence for a coeval change in HREE transport thorough the intergranular network. Conversely, spiral core-to-rim zoning of chromium indicates the element remains almost completely immobile in the matrix over the duration of garnet growth.

  3. Software concepts for the build-up of complex systems - selection and realization taking as example a program system for calculation of hypothetical core meltdown accidents

    International Nuclear Information System (INIS)

    Scheuermann, W.


    Development and application of simulation systems for the analysis of complex processes require on the one hand and detailed engineering knowledge of the plant and the processes to be simulated and on the other hand a detailled knowledge about software engineering, numerics and data structures. The cooperation of specialists of both areas will become easier if it is possible to reduce the complexicity of the problems to be solved in a way that the analyses will not be disturbed and the communication between different disciplines will not become unnecessarily complicated. One solution to reduce the complexity is to consider computer science as an engineering discipline which provides mainly abstract elements and to allow engineers to build application systems based on these abstract elements. The principle of abstraction leads through the processes of modularisation and the solution of the interface problem to an almost problem independent system architecture where the elements of the system (modules, model components and models) operate only on those data assigned to them. In addition the development of abstract data types allows the formal description of the relations and interactions between system elements. This work describes how these ideas can be concretized to build complex systems which allow reliable and effective problem solutions. These ideas were applied successfully during the design, realization and application of the code system KESS, which allows the analysis of core melt down accidents in pressurized water reactors. (orig.) [de

  4. Chloritoid and barroisite-bearing pelitic schists from the eclogite unit in the Besshi district, Sanbagawa metamorphic belt (United States)

    Zaw Win Ko; Enami, M.; Aoya, M.


    The Sanbagawa metamorphic rocks in the Besshi district, central Shikoku, are grouped into eclogite and noneclogite units. Chloritoid and barroisite-bearing pelitic schists occur as interlayers within basic schist in an eclogite unit of the Seba area in the Sanbagawa metamorphic belt, central Shikoku, Japan. Major matrix phases of the schists are garnet, chlorite, barroisite, paragonite, phengite, and quartz. Eclogite facies phases including chloritoid and talc are preserved only as inclusions in garnet. P- T conditions for the eclogite facies stage estimated using equilibria among chloritoid, barroisite, chlorite, interlayered chlorite-talc, paragonite, and garnet are 1.8 GPa/520-550 °C. Zonal structures of garnet and matrix amphibole show discontinuous growth of minerals between their core and mantle parts, implying the following metamorphic stages: prograde eclogite facies stage→hydration reaction stage→prograde epidote-amphibolite stage. This metamorphic history suggests that the Seba eclogite lithologies were (1) juxtaposed with subducting noneclogite lithologies during exhumation and then (2) progressively recrystallized under the epidote-amphibolite facies together with the surrounding noneclogite lithologies. The pelitic schists in the Seba eclogite unit contain paragonite of two generations: prograde phase of the eclogite facies included in garnet and matrix phase produced by local reequilibration of sodic pyroxene-bearing eclogite facies assemblages during exhumation. Paragonite is absent in the common Sanbagawa basic and pelitic schists, and is, however, reported from restricted schists from several localities near the proposed eclogite unit in the Besshi district. These paragonite-bearing schists could be lower-pressure equivalents of the former eclogite facies rocks and are also members of the eclogite unit. This idea implies that the eclogite unit is more widely distributed in the Besshi district than previously thought.

  5. Age and significance of core complex formation in a very curved orogen: Evidence from fission track studies in the South Carpathians (Romania) (United States)

    Fügenschuh, B.; Schmid, S. M.


    Twenty-four new zircon and apatite fission track ages from the Getic and Danubian nappes in the South Carpathians are discussed in the light of a compilation of published fission track data. A total of 101 fission track ages indicates that the Getic nappes are generally characterized by Cretaceous zircon and apatite fission track ages, indicating cooling to near-surface temperatures of these units immediately following Late Cretaceous orogeny. The age distribution of the Danubian nappes, presently outcropping in the Danubian window below the Getic nappes, depends on the position with respect to the Cerna-Jiu fault. Eocene and Oligocene zircon and apatite central ages from the part of the Danubian core complex situated southeast of this fault monitor mid-Tertiary tectonic exhumation in the footwall of the Getic detachment, while zircon fission track data from northwest of this fault indicate that slow cooling started during the Latest Cretaceous. The change from extension (Getic detachment) to strike-slip dominated tectonics along the curved Cerna-Jiu fault allowed for further exhumation on the concave side of this strike-slip fault, while exhumation ceased on the convex side. The available fission track data consistently indicate that the change to fast cooling associated with tectonic denudation by core complex formation did not occur before Late Eocene times, i.e. long after the cessation of Late Cretaceous thrusting. Core complex formation in the Danubian window is related to a larger-scale scenario that is characterized by the NNW-directed translation, followed by a 90° clockwise rotation of the Tisza-Dacia "block" due to roll-back of the Carpathian embayment. This led to a complex pattern of strain partitioning within the Tisza-Dacia "block" adjacent to the western tip of the rigid Moesian platform. Our results suggest that the invasion of these southernmost parts of Tisza-Dacia started before the Late Eocene, i.e. significantly before the onset of Miocene

  6. Radical non-radical states of the [Ru(PIQ)] core in complexes (PIQ = 9,10-phenanthreneiminoquinone). (United States)

    Bera, Sachinath; Maity, Suvendu; Weyhermüller, Thomas; Ghosh, Prasanta


    9,10-Phenanthreneiminosemiquinonate anion radical (PIQ˙(-)) complexes of ruthenium of types trans-[Ru(II)(PIQ˙(-))(PPh3)2(CO)Cl] () and trans-[Ru(III)(PIQ˙(-))(PPh3)2Cl2] () are reported. Reactions of and with I2 afford trans-[Ru(III)(PIQ˙(-))(PPh3)2(CO)Cl](+)I3(-)·½CH2Cl2 ((+)I3(-)·½CH2Cl2) and trans-[Ru(PIQ˙(-))2(PPh3)2(μ-Cl)3](+)I3(-)·¼I2·¼toluene) ((+)I3(-)·¼I2·¼toluene), while the reaction of with Br2 yields a 9,10-phenanthreneiminoquinone (PIQ) complex of the type mer-[Ru(III)(PIQ)(PPh3)Br3]·½CH2Cl2 (·½CH2Cl2). In comparison, the reaction of trans-[Ru(III)(PQ˙(-))(PPh3)2Cl2] (PQ), a 9,10-phenanthrenequinone (PQ) analogue of affords only trans-[Ru(III)(PQ)(PPh3)2Cl2](+)Br3(-) ((+)Br3(-)). Considering the X-ray bond parameters, EPR spectra and the atomic spin densities obtained from the density functional theory (DFT) calculations, is defined as a PIQ˙(-) (average C-O/N and C-C lengths, 1.280(2) and 1.453(3) Å) complex of ruthenium(ii) while is a neutral PIQ (average C-O, C-N, C-C and C-O/N lengths, 1.248(7), 1.284(7), 1.485(8) and 1.266(7) Å) complex of the ruthenium(iii) ion. The single crystal X-ray bond parameters proposed that (+)I3(-) (average C-O/N and C-C lengths, 1.294(8) and 1.449(9) Å) and (average C-O/N and C-C lengths, 1.289(2) and 1.447(4) Å) are PIQ˙(-) complexes of ruthenium(iii), while the (+) ion (average C-O/N and C-C lengths, 1.288 ± 0.004 and 1.450 ± 0.017 Å) is a co-facial bi-octahedral complex of ruthenium(iii). In contrast, the (+) ion is a PQ complex of the ruthenium(iii) ion. EPR spectra and the calculated atomic spin densities authenticated that the (+) ion obtained after constant potential coulometric oxidation of is a PIQ complex of ruthenium(iii), while the (-) ion is a hybrid state of [Ru(II)(PIQ˙(-))] and [Ru(III)(PIQ(2-))] states. It is observed that the PIQ˙(-) state in which spin is more localized on the nitrogen (∼38% in and ∼35% in (-) ion) is stable and the coordination of the PIQ(2

  7. Differential solvation of 'core' trimannoside complexes of the Dioclea grandiflora lectin and concanavalin A detected by primary solvent isotope effects in isothermal titration microcalorimetry

    International Nuclear Information System (INIS)

    Dam, T.K.; Oscarson, S.; Sacchettini, J.C.; Brewer, C.F.


    The thermodynamics of binding of the Man/Glc-specific seed lectin from Dioclea grandiflora (DGL) to deoxy analogs of the ''core'' trimannoside, 3, 6-di-O-(alpha-D-mannopyranosyl)-alpha-D-mannopyranoside was determined by isothermal titration microcalorimetry (ITC) in the first paper of this series (Dam, T. K., Oscarson, S., and Brewer, C. F. (1998) J. Biol. Chem. 273, 32812-32817). The data showed binding of specific hydroxyl groups on all three residues of the trimannoside, similar to that observed for ConA (Gupta, D., Dam, T. K., Oscarson, S., and Brewer, C. F. (1997) J. Biol. Chem. 272, 6388-6392). However, differences exist in the thermodynamics of binding of monodeoxy analogs of the alpha(1-6) Man residue of the trimannoside to the two lectins. The x-ray crystal structure of DGL complexed to the core trimannoside, presented in the second paper in this series (Rozwarski, D. A., Swami, B. M., Brewer, C. F., and Sacchettini, J. C. (1998) J. Biol. Chem. 273, 32818-32825), showed the overall structure of the complex to be similar to that of the ConA-trimannoside complex. Furthermore, the trimannoside is involved in nearly identical hydrogen bonding interactions in both complexes. However, differences were noted in the arrangement of ordered water molecules in the binding sites of the two lectins. The present study presents ITC measurements of DGL and ConA binding to the monodeoxy analogs of the trimannoside in hydrogen oxide (H2O) and deuterium oxide (D2O). The solvent isotope effects present in the thermodynamic binding data provide evidence for altered solvation of the parent trimannoside complexes at sites consistent with the x-ray crystal structures of both lectins. The results indicate that the differences in the thermodynamics of DGL and ConA binding to alpha(1-6) monodeoxy analogs of the trimannoside do not correlate with solvation differences of the parent trimannoside complexes. (author)

  8. Aberrant Assembly Complexes of the Reaction Center Light-harvesting 1 PufX (RC-LH1-PufX) Core Complex of Rhodobacter sphaeroides Imaged by Atomic Force Microscopy* (United States)

    Olsen, John D.; Adams, Peter G.; Jackson, Philip J.; Dickman, Mark J.; Qian, Pu; Hunter, C. Neil


    In the purple phototrophic bacterium Rhodobacter sphaeroides, many protein complexes congregate within the membrane to form operational photosynthetic units consisting of arrays of light-harvesting LH2 complexes and monomeric and dimeric reaction center (RC)-light-harvesting 1 (LH1)-PufX “core” complexes. Each half of a dimer complex consists of a RC surrounded by 14 LH1 αβ subunits, with two bacteriochlorophylls (Bchls) sandwiched between each αβ pair of transmembrane helices. We used atomic force microscopy (AFM) to investigate the assembly of single molecules of the RC-LH1-PufX complex using membranes prepared from LH2-minus mutants. When the RC and PufX components were also absent, AFM revealed a series of LH1 variants where the repeating α1β1(Bchl)2 units had formed rings of variable size, ellipses, and spirals and also arcs that could be assembly products. The spiral complexes occur when the LH1 ring has failed to close, and short arcs are suggestive of prematurely terminated LH1 complex assembly. In the absence of RCs, we occasionally observed captive proteins enclosed by the LH1 ring. When production of LH1 units was restricted by lowering the relative levels of the cognate pufBA transcript, we imaged a mixture of complete RC-LH1 core complexes, empty LH1 rings, and isolated RCs, leading us to conclude that once a RC associates with the first α1β1(Bchl)2 subunit, cooperative associations between subsequent subunits and the RC tend to drive LH1 ring assembly to completion. PMID:25193660

  9. Evaluation of the role of downregulation of SNF5/INI1 core subunit of SWI/SNF complex in clear cell renal cell carcinoma development. (United States)

    Sarnowska, Elzbieta; Szymanski, Michal; Rusetska, Nataliia; Ligaj, Marcin; Jancewicz, Iga; Cwiek, Pawel; Skrodzka, Marta; Leszczynski, Marcin; Szarkowska, Joanna; Chrzan, Alicja; Stachowiak, Malgorzata; Steciuk, Jaroslaw; Maassen, Anna; Galek, Lech; Demkow, Tomasz; Siedlecki, Janusz A; Sarnowski, Tomasz J


    Clear cell renal cell carcinoma (ccRCC) is characterized by stabilization of hypoxia-inducible factor (HIF1), and mutations in von Hippel-Lindau ( VHL ) gene. Additionally, in about 40% of ccRCC cases the mutation in PBRM1 ( POLYBROMO1 ) gene coding for a non-core subunit of SWI/SNF chromatin remodeling complex was found suggesting potential impairment of this complex function in ccRCC. In this study we assessed the extent to which the core SWI/SNF complex subunit - INI1 (hSNF5/SMARCB1) is affected in ccRCC and whether it has any consequences on the development of this type of cancer. The evaluation of INI1 protein level in samples from 50 patients with diagnosed ccRCC, including three displaying rhabdoid features, showed the INI1 positive staining in rhabdoid cells while the conventional ccRCC cells exhibited reduced INI1 level. This indicated the rhabdoid component of ccRCC as distinct from other known rhabdoid tumors. The reduced INI1 protein level observed in all conventional ccRCC cases used in this study correlated with decreased SMARCB1 gene expression at the transcript level. Consistently, the overexpression of INI1 protein in A498 ccRCC cell line resulted in the elevation of endogenous SMARCB1 transcript level indicating that the INI1-dependent regulatory feedback loop controlling expression of this gene is affected in ccRCC Moreover, the set of INI1 target genes including i.e. CXCL12/CXCR7/CXCR4 chemokine axis was identified to be affected in ccRCC. In summary, we demonstrated that the inactivation of INI1 may be of high importance for ccRCC development and aggressiveness.

  10. The Human Embryoid Body Cystic Core Exhibits Architectural Complexity Revealed by use of High Throughput Polymer Microarrays. (United States)

    Tomov, Martin L; Olmsted, Zachary T; Paluh, Janet L


    In pluripotent stem cell differentiation, embryoid bodies (EBs) provide a three-dimensional [3D] multicellular precursor in lineage specification. The internal structure of EBs is not well characterized yet is predicted to be an important parameter to differentiation. Here, we use custom SU-8 molds to generate transparent lithography-templated arrays of polydimethylsiloxane (LTA-PDMS) for high throughput analysis of human embryonic stem cell (hESC) EB formation and internal architecture. EBs formed in 200 and 500 μm diameter microarray wells by use of single cells, 2D clusters, or 3D early aggregates were compared. We observe that 200 μm EBs are monocystic versus 500 μm multicystic EBs that contain macro, meso and microsized cysts. In adherent differentiation of 500 μm EBs, the multicystic character impairs the 3D to 2D transition creating non-uniform monolayers. Our findings reveal that EB core structure has a size-dependent character that influences its architecture and cell population uniformity during early differentiation. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  11. U-Pb SHRIMP geochronology of zircon in garnet peridotite from the Sulu UHP terrane, China: Implications for mantle metasomatism and subduction-zone UHP metamorphism (United States)

    Zhang, R.Y.; Yang, J.S.; Wooden, J.L.; Liou, J.G.; Li, T.F.


    We studied the Zhimafang ultrahigh-pressure metamorphic (UHP) peridotite from pre-pilot drill hole PP-1 of Chinese Continental Scientific Drilling project in the Sulu UHP terrane, eastern China. The peridotite occurs as lens within quartofeldspathic gneiss, and has an assemblage of Ol + Opx + Cpx + Phl + Ti-clinohumite (Ti-Chu) + Grt (or chromite) ?? magnesite (Mgs). Zircons were separated from cores at depths of 152 m (C24, garnet lhezolite), 160 m (C27, strongly retrograded phlogopite-rich peridotite) and 225 m (C50, banded peridotite), and were dated by SHRIMP mass spectrometer. Isometric zircons without inherited cores contain inclusions of olivine (Fo91-92), enstatite (En91-92), Ti-clinohumite, diopside, phlogopite and apatite. The enstatite inclusions have low Al2O3 contents of only 0.04-0.13 wt.%, indicating a UHP metamorphic origin. The weighted mean 206Pb/238U zircon age for garnet lherzolite (C24) is 221 ?? 3 Ma, and a discordia lower intercept age for peridotite (C50) is 220 ?? 2 Ma. These ages are within error and represent the time of subduction-zone UHP metamorphism. A younger lower intercept age of 212 ?? 3 Ma for a foliated wehrlite (C27) was probably caused by Pb loss during retrograde metamorphism. The source of zirconium may be partially attributed to melt/fluid metasomatism within the mantle wedge. Geochronological and geochemical data confirm that the mantle-derived Zhimafang garnet peridotites (probably the most representative type of Sulu garnet peridotites) were tectonically inserted into a subducting crustal slab and subjected to in situ Triassic subduction-zone UHP metamorphism. ?? 2005 Elsevier B.V. All rights reserved.

  12. Metamorphic history and age of aluminous gneisses of the Belomorian belt of the Baltic shield

    International Nuclear Information System (INIS)

    Bibikova, E.V.; Borisova, E.Yu.; Makarov, V.A.; Drugova, G.M.


    Metamorphic conditions and age are determined for the early metamorphic stage of aluminous gneisses in the Chupa nappe in the Belomorian Mobile Belt. The granulite-facies metamorphic conditions during Late Archean time are determined based on the composition of garnet and biotie from the metapelites. The early metamorphic stage was dated at 2860 ± 30 Ma based on the U-Pb systematics of granulitic zircon from the metapelites. The U-Pb isotopic system of the zircon was strongly affected by Svecogennian metamorphism (at 1750 Ma). The geodynamic evolution of the Belomorian Mobile Belt is discussed in light of the data of this work

  13. Structural and magnetic characterization of three tetranuclear Cu(II) complexes with face-sharing-dicubane/double-open-cubane like core framework

    Energy Technology Data Exchange (ETDEWEB)

    Paul, Aparup [Department of Chemistry and Chemical Technology, Vidyasagar University, Midnapore 721102, West Bengal (India); Bertolasi, Valerio [Dipartimento di Scienze Chimiche e Farmaceutiche, Centro di Strutturistica Diffrattometrica, Università di Ferrara, Via L. Borsari, 46, 44100 Ferrara (Italy); Figuerola, Albert [Departament de Química Inorgànica i Orgànica (Secció de Química Inorgànica) and Institut de Nanociència i Nanotecnologia (IN2UB), Universitat de Barcelona, Martí i Franquès 1-11, 08028 Barcelona (Spain); Manna, Subal Chandra, E-mail: [Department of Chemistry and Chemical Technology, Vidyasagar University, Midnapore 721102, West Bengal (India)


    Three novel tetranuclear copper(II) complexes namely [Cu{sub 4}(L{sup 1}){sub 4}]∙2(dmf) (1), [Cu{sub 4}(L{sup 1}){sub 4}] (2) and [Cu{sub 4}(L{sup 2}){sub 2}(HL{sup 2}){sub 2}(H{sub 2}O){sub 2}]∙2(ClO{sub 4})·6(H{sub 2}O) (3) (H{sub 2}L{sup 1}, (E)−2-((1-hydroxybutan-2-ylimino)methyl)phenol; H{sub 2}L{sup 2}, (E)−2-((1-hydroxybutan-2-ylimino)methyl)−6-methoxyphenol)) were synthesized from the self-assembly of copper(II) perchlorate and the tridentate Schiff base ligands. The structural determination reveals that crystallizes in the monoclinic system with space group C2/c, whereas both the and crystallize in the triclinic system with space group P-1. and possess face-sharing dicubane core, on the other hand complex 3 has double open cubane core structure. The copper(II) ions in the cubane core are in distorted square planar geometries, and weak π…π and C–H…π interactions lead to formation of a 2D supramolecular architecture for and . At room temperature and , exhibit fluorescence with a quantum yield (Φ{sub s}) of 0.47, 0.49 and 0.38, respectively. Variable temperature magnetic susceptibility measurements in the range 2–300 K indicate an overall weak antiferromagnetic exchange coupling in all complexes. The PHI program was used to study their magnetic behaviour. In agreement with their face-sharing dicubane structure, a Hamiltonian of the type H =– J{sub 1}(S{sub 1}S{sub 2}+S{sub 1}S{sub 2’}+S{sub 1'}S{sub 2}+S{sub 1'}S{sub 2’}) – J{sub 2}S{sub 1}S{sub 1’}, where S{sub 1} = S{sub 1’} = S{sub 2} = S{sub 2’} = S{sub Cu} =1/2, was used for studying and . Simulations performed suggest magnetic exchange constants with values close to J{sub 1} =−20 cm{sup −1} and J{sub 2} =0 cm{sup -1} for these complexes. On the other hand, the spin Hamiltonian H =– J{sub 1}(S{sub 1}S{sub 4}+S{sub 2}S{sub 3}) – J{sub 2}(S{sub 1}S{sub 3}+S{sub 2}S{sub 4}) – J{sub 3}S{sub 1}S{sub 2}, where S{sub 1} = S{sub 2} = S{sub 3} = S{sub 4

  14. High mobility group protein number17 cross-links primarily to histone H2A in the reconstituted HMG 17 - nucleosome core particle complex

    International Nuclear Information System (INIS)

    Cook, G.R.; Yau, P.; Yasuda, H.; Traut, R.R.; Bradbury, E.M.


    The neighbor relationship of lamb thymus High Mobility Group (HMG) protein 17 to native HeLa nucleosome core particle histones in the reconstituted complex has been studied. 125 I-labeled HMG 17 was cross-linking to core histones using the protein-protein cross-linking reagent 2-iminothiolane. Specific cross-linked products were separated on a two-dimensional Triton-acid-urea/SDS gel system, located by autoradiography, excised and quantified. Disulfide bonds in the cross links were then cleaved and the protein constituents were identified by SDS gel electrophoresis. HMG 17 cross-linked primarily to histone H2A while lower levels of cross-linking occurred between HMG 17 and the other histones. In contrast, cross-linking between two HMG 17 molecules bound on the same nucleosome was relatively rare. It is concluded that the same nucleosome was relatively rare. It is concluded that H2A comprises part of the HMG 17 binding site but that HMG 17 is sufficiently elongated and mobile to permit cross-linking to the other histones and to a second HMG 17 molecule. These results are in agreement with the current model for the structure of the nucleosome and the proposed binding sites for HMG 17

  15. Geochemical, Metamorphic and Geodynamic Evolution implications from subduction-related serpentinites and metarodingites at East Thessaly (Central Greece) (United States)

    Koutsovitis, Petros


    In Central Greece, the East Thessaly region encompasses ophiolitic and metaophiolitic formations emplaced onto Mesozoic platform series rocks. Metaophiolitic thrust sheets are characterized either by the predominance of serpentinites or metabasites. Serpentinites have been distinguished into three groups, representing distinct metamorphic degrees. Group-1 serpentinites (East Othris region) are characterized by the progressive transformation of lizardite to antigorite, estimated to have been formed under greenschist facies conditions (˜320-340 ˚ C, P≈6-8 kbar) [1]. Group-2 serpentinites (NE Othris and Agia-Agiokampos region) are marked by the further prevalence of antigorite over lizardite, suggesting upper-greenschist to low-blueschist facies metamorphism (˜340-370 ˚ C, P≈9-11 kbar) [1]. Group-3 serpentinites (Agia-Agiokampos region) are characterized by the predominance of antigorite and Cr-magnetite, as well as by their relatively low LOI (10.9-12.6 wt.%), corresponding to blueschist facies metamorphism (˜360-400 ˚ C, P≈12 kbar) [1]. These metamorphic conditions are highly comparable with the P-T estimates from the Easternmost Thessaly metabasic rocks, strongly indicating that the entire metaophiolitic formation (excluding East Othris) underwent blueschist facies metamorphism. Serpentinites from East Thessaly were formed from serpentinization of highly depleted harzburgitic protoliths under extensive partial melting processes (>15%), pointing to a hydrous subduction-related environment. Group-1 serpentinites exhibit higher Mg/Si ratio values and LOI compared to serpentinite Groups-2 and -3. Differences in the trace element behavior amongst the three serpentinite groups are also consistent with increasing metamorphic conditions (e.g. Pb, La enrichments, Ti, Y, Yb depletions) [1]. The East Thessaly serpentinites reflect highly oxidizing conditions (-0.4Jurassic Pindos oceanic SSZ model appears to successfully interpret not only the geochemical and

  16. Petrology of blueschist facies metamorphic rocks of the Meliata Unit

    Directory of Open Access Journals (Sweden)

    Faryad Shah Wali


    Full Text Available Meliata blueschists originated from basalts, limestones, pelites, psammitic and amphibolite facies basement rocks. Compositionally, the metabasalts have a geochemical signature mostly indicative of a transitional arc-MORB origin, but some mafic rocks having affinity with within plate basalts also present. The mafic blueschists consist of blue amphibole, epidote and albite, rarely also garnet, Na-pyroxene and chloritoid. Apart from phengite and quartz the metapelites and metapsammites contain one or more of the minerals: chloritoid, paragonite, glaucophane, albite, chlorite, occasionally also Na-pyroxene and garnet. Amphibolite facies rocks contain relic garnet, plagioclase and hornblende, the latter two replaced by albite and blue amphibole, respectively. The zoning patterns of blue amphibole, garnet and chloritoid suggest their formation during prograde stage of metamorphism. P-T conditions of meta-morphism are estimated to be about 350-460 oC and 10-12 kbar.

  17. Metamorphic hemispherical microphone array for three-dimensional acoustics (United States)

    Biswas, Shantonu; Reiprich, Johannes; Cohrs, Thaden; Stauden, Thomas; Pezoldt, Joerg; Jacobs, Heiko O.


    This article describes the realization of a metamorphic stretchable microphone array, which can be inflated by air to morph from a planar to a hemispherical shape. The array undergoes morphological changes to adjust their receive characteristic. To realize this device, a metamorphic printed circuit board technology (m-PCB) is described. The resulting products are millimeter-thin stretchable silicone embedded and electrically interconnected electronic structures with mechanical properties, which resemble a silicone membrane. The microphone array is used to localize a sound source in a 3D space. The results of the planar orientation (resting shape), and the 3D hemispherical orientation after air inflation are compared. The inflated hemispherical microphone array proofs to be better for 3D acoustic localization and/or beam-forming.

  18. Repeated shock and thermal metamorphism of the Abernathy meteorite (United States)

    Lambert, P.; Lewis, C.; Moore, C. B.


    Based on the example of Abernathy (L6 chondrite), it is shown how petrographic investigation can be used to unravel the nature, chronology and conditions of superposed metamorphic events in chondrites. Features considered include the texture of the rock, optical characteristics of olivine, pyroxene and plagioclase, refractive index of plagioclase, metallographical characteristics and microhardness of Fe-Ni alloys. It is deduced that Abernathy has been involved in at least six metamorphic events since the formation of the chondrite. Four distinct shock events and two separate reheating events have been identified. The chronology of these events is established. The conditions for the last four events are reasonably well constrained. These include severe reheating (T greater than 1200 C); severe shock causing complete melting of plagioclase and local melting of the rock (P between 90 and 110 GPa, T between 1250 and 1350 C); mild shock (P between 10 and 25 GPa, T less than 500 C); and reheating below 800 C.

  19. Repair pathways independent of the Fanconi anemia nuclear core complex play a predominant role in mitigating formaldehyde-induced DNA damage

    Energy Technology Data Exchange (ETDEWEB)

    Noda, Taichi [Department of Biology, School of Medicine, Nara Medical University, 840 Shijo-cho, Kashihara, Nara 634-8521 (Japan); Department of Dermatology, School of Medicine, Nara Medical University, 840 Shijo-cho, Kashihara, Nara 634-8521 (Japan); Takahashi, Akihisa [Department of Biology, School of Medicine, Nara Medical University, 840 Shijo-cho, Kashihara, Nara 634-8521 (Japan); Kondo, Natsuko [Particle Radiation Oncology Research Center, Research Reactor Institute, Kyoto University, Kumatori-cho, Sennan-gun, Osaka 590-0494 (Japan); Mori, Eiichiro [Department of Biology, School of Medicine, Nara Medical University, 840 Shijo-cho, Kashihara, Nara 634-8521 (Japan); Okamoto, Noritomo [Department of Otorhinolaryngology, School of Medicine, Nara Medical University, 840 Shijo-cho, Kashihara, Nara 634-8521 (Japan); Nakagawa, Yosuke [Department of Oral and Maxillofacial Surgery, School of Medicine, Nara Medical University, 840 Shijo-cho, Kashihara, Nara 634-8521 (Japan); Ohnishi, Ken [Department of Biology, Ibaraki Prefectual University of Health Sciences, 4669-2 Ami, Ami-mati, Inasiki-gun, Ibaraki 300-0394 (Japan); Zdzienicka, Malgorzata Z. [Department of Molecular Cell Genetics, Collegium Medicum in Bydgoszcz, Nicolaus-Copernicus-University in Torun, ul. Sklodowskiej-Curie 9, 85-094 Bydgoszcz (Poland); Thompson, Larry H. [Biosciences and Biotechnology Division, L452, Lawrence Livermore National Laboratory, P.O. Box 808, Livermore, CA 94551-0808 (United States); Helleday, Thomas [Gray Institute for Radiation Oncology and Biology, University of Oxford, Old Road Campus Research Building, Off Roosevelt Drive, Oxford, OX3 7DQ (United Kingdom); Department of Genetics, Microbiology and Toxicology Stockholm University, SE-106 91 Stockholm (Sweden); Asada, Hideo [Department of Dermatology, School of Medicine, Nara Medical University, 840 Shijo-cho, Kashihara, Nara 634-8521 (Japan); and others


    The role of the Fanconi anemia (FA) repair pathway for DNA damage induced by formaldehyde was examined in the work described here. The following cell types were used: mouse embryonic fibroblast cell lines FANCA{sup -/-}, FANCC{sup -/-}, FANCA{sup -/-}C{sup -/-}, FANCD2{sup -/-} and their parental cells, the Chinese hamster cell lines FANCD1 mutant (mt), FANCGmt, their revertant cells, and the corresponding wild-type (wt) cells. Cell survival rates were determined with colony formation assays after formaldehyde treatment. DNA double strand breaks (DSBs) were detected with an immunocytochemical {gamma}H2AX-staining assay. Although the sensitivity of FANCA{sup -/-}, FANCC{sup -/-} and FANCA{sup -/-}C{sup -/-} cells to formaldehyde was comparable to that of proficient cells, FANCD1mt, FANCGmt and FANCD2{sup -/-} cells were more sensitive to formaldehyde than the corresponding proficient cells. It was found that homologous recombination (HR) repair was induced by formaldehyde. In addition, {gamma}H2AX foci in FANCD1mt cells persisted for longer times than in FANCD1wt cells. These findings suggest that formaldehyde-induced DSBs are repaired by HR through the FA repair pathway which is independent of the FA nuclear core complex. -- Research highlights: {yields} We examined to clarify the repair pathways of formaldehyde-induced DNA damage. Formaldehyde induces DNA double strand breaks (DSBs). {yields} DSBs are repaired through the Fanconi anemia (FA) repair pathway. {yields} This pathway is independent of the FA nuclear core complex. {yields} We also found that homologous recombination repair was induced by formaldehyde.

  20. Pathway to 50% Efficient Inverted Metamorphic Concentrator Solar Cells

    Energy Technology Data Exchange (ETDEWEB)

    Geisz, John F [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Steiner, Myles A [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Jain, Nikhil [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Schulte, Kevin L [National Renewable Energy Laboratory (NREL), Golden, CO (United States); France, Ryan M [National Renewable Energy Laboratory (NREL), Golden, CO (United States); McMahon, William E [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Perl, Emmett [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Horowitz, Kelsey A [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Friedman, Daniel J [National Renewable Energy Laboratory (NREL), Golden, CO (United States)


    Series-connected five (5J) and six junction (6J) concentrator solar cell strategies have the realistic potential to exceed 50% efficiency to enable low-cost CPV systems. We propose three strategies for developing a practical 6J device. We have overcome many of the challenges required to build such concentrator solar cell devices: We have developed 2.1 eV AlGaInP, 1.7 eV AlGaAs, and 1.7 eV GaInAsP junctions with external radiative efficiency greater than 0.1%. We have developed a transparent tunnel junction that absorbs minimal light intended for the second junction yet resists degradation under thermal load. We have developed metamorphic grades from the GaAs to the InP lattice constant that are transparent to sub-GaAs bandgap light. We have grown and compared low bandgap junctions (0.7eV - 1.2 eV) using metamorphic GaInAs, metamorphic GaInAsP, and GaInAsP lattice-matched to InP. And finally, we have demonstrated excellent performance in a high voltage, low current 4 junction inverted metamorphic device using 2.1, 1.7, 1.4, and 1.1 eV junctions with over 8.7 mA/cm2 one-sun current density that operates up to 1000 suns without tunnel junction failure.

  1. Correlated evolution of phenotypic plasticity in metamorphic timing


    Michimae, H.; Emura, T.


    Phenotypic plasticity has long been a focus of research, but the mechanisms of its evolution remain controversial. Many amphibian species exhibit a similar plastic response in metamorphic timing in response to multiple environmental factors; therefore, more than one environmental factor has likely influenced the evolution of plasticity. However, it is unclear whether the plastic responses to different factors have evolved independently. In this study, we examined the relationship between the ...

  2. Diffusion models in metamorphic thermo chronology: philosophy and methods

    International Nuclear Information System (INIS)

    Munha, Jose Manuel; Tassinari, Colombo Celso Gaeta


    Understanding kinetics of diffusion is of major importance to the interpretation of isotopic ages in metamorphic rocks. This paper provides a review of concepts and methodologies involved on the various diffusion models that can be applied to radiogenic systems in cooling rocks. The central concept of closure temperature is critically discussed and quantitative estimates for the various diffusion models are evaluated, in order to illustrate the controlling factors and the limits of their practical application. (author)

  3. From contemporary art to core clinical skills: observation, interpretation, and meaning-making in a complex environment. (United States)

    Schaff, Pamela B; Isken, Suzanne; Tager, Robert M


    Many medical schools have incorporated experiences with representational or figurative art into the curriculum in an effort to improve learners' powers of observation, visual diagnostic skills, and pattern recognition skills or to enhance communication skills, foster teamwork, and/or improve empathy. The Keck School of Medicine of the University of Southern California has partnered with Los Angeles' Museum of Contemporary Art to design an educational experience with the goal of honing students' abilities to observe, describe, and interpret complex information. The authors discovered that through a constructivist approach to viewing and discussing nonrepresentational, contemporary art, students were able not only to apply their observational and interpretive skills in a safe, nonclinical setting but also to accept the facts that ambiguity is inherent to art, life, and clinical experience and that there can be more than one answer to many questions. This intervention, entailing extensive guided inquiry, collaborative thinking, and process work, has allowed students and faculty to reflect on the parallel processes at work in clinical practice and art interpretation. In patient encounters, physicians (and physicians-in-training) begin with attention and observation, continue with multiple interpretations of that which they observe, move to sorting through often ambiguous evidence, proceed to collaboration within a community of observers, and finally move to consensus and direction for action. In the worlds of both art and medicine, individuals imagine experiences beyond their own and test hypotheses by integrating their own prior knowledge and intuition and by comparing their evidence with that of others.

  4. Middle Ordovician subduction of continental crust in the Scandinavian Caledonides: an example from Tjeliken, Seve Nappe Complex, Sweden (United States)

    Fassmer, Kathrin; Klonowska, Iwona; Walczak, Katarzyna; Andersson, Barbro; Froitzheim, Nikolaus; Majka, Jarosław; Fonseca, Raúl O. C.; Münker, Carsten; Janák, Marian; Whitehouse, Martin


    The Seve Nappe Complex of the Scandinavian Caledonides is thought to be derived from the distal passive margin of Baltica which collided with Laurentia in the Scandian Phase of the Caledonian Orogeny at 430-400 Ma. Parts of the Seve Nappe Complex were affected by pre-Scandian high- and ultrahigh-pressure metamorphism, in a tectonic framework that is still unclear, partly due to uncertainties about the exact timing. Previous age determinations yielded between 505 and 446 Ma, with a general trend of older ages in the North (Norrbotten) than in the South (Jämtland). New age determinations were performed on eclogite and garnet-phengite gneiss at Tjeliken in northern Jämtland. Thermodynamic modelling yielded peak metamorphic conditions of 25-27 kbar/680-760 °C for the garnet-phengite gneiss, similar to published peak metamorphic conditions of the eclogite (25-26 kbar/650-700 °C). Metamorphic rims of zircons from the garnet-phengite gneiss were dated using secondary ion mass spectrometry and yielded a concordia age of 458.9 ± 2.5 Ma. Lu-Hf garnet-whole rock dating yielded 458 ± 1.0 Ma for the eclogite. Garnet in the eclogite shows prograde major-element zoning and concentration of Lu in the cores, indicating that this age is related to garnet growth during pressure increase, i.e. subduction. The identical ages from both rock types, coinciding with published Sm-Nd ages from the eclogite, confirm subduction of the Seve Nappe Complex in Northern Jämtland during the Middle Ordovician in a fast subduction-exhumation cycle.

  5. The Age and Geodynamic Evolution of the Metamorphic sole rocks from Izmir-Ankara-Erzıncan suture zone (Northern-Turkey) (United States)

    Melih Çörtük, Rahmi; Faruk Çelik, Ömer; Özkan, Mutlu; Sherlock, Sarah C.; Marzoli, Andrea; Altıntaş, İsmail Emir; Topuz, Gültekin


    The İzmir-Ankara-Erzincan suture zone in northern Turkey is one of the major tectonic zones separating the Pontides to the North from the Anatolide-Tauride block and Kı rşehir Massif to the South. The accretionary complex of the İzmir-Ankara-Erzincan suture zone, near Artova, is composed mainly of peridotites with varying degree serpentinization, metamorphic rocks, basalt, sandstones, pelagic and neritic limestones. The metamorphic rocks are represented by amphibolite, garnet micaschit, calc-schist and marble. The metamorphic rocks were interpreted as the metamorphic sole rocks. Because; (i) They are tectonically located beneath the serpentinized peridotites. (ii) Foliation planes of both the amphibolites and mantle tectonites are parallel to each other. (iii) The metamorphic rocks are crosscut by non-metamorphic dolerite dikes which exhibite Nb and Ta depletion relative to Th enrichment on the N-MORB normalized multi-element spider diagram. The dolerite dikes display flat REE patterns (LaN/YbN=0.85-1.24). These geochemical signatures of the dolerite dikes are indicative of subduction component during their occurrences. Geochemical observations of the amphibolites suggest E-MORB- and OIB-like signatures (LaN/SmN= 1.39-3.14) and their protoliths are represented by basalt and alkali basaltic rocks. Amphiboles from the amphibolites are represented by calcic amphiboles (magnesio-hornblende, tchermakite and tremolite) and they yielded 40Ar-39Ar ages between 157.8 ± 3.6 Ma and 139 ± 11 Ma. These cooling ages were interpreted to be the intra-oceanic subduction/thrusting time of the İzmir-Ankara-Erzincan oceanic domain. This study was funded by TÜBİTAK (Project no: 112Y123).

  6. Tectonic Stacking of HP/LT Metamorphic Rocks in Accretionary Wedges and the Role of Shallowing Slab-Mantle Decoupling (United States)

    Aygül, Mesut; Oberhänsli, Roland


    High-pressure/low-temperature (HP/LT) chloritoid-bearing micaschists crop out widely in the central part of northern Turkey and represent deep-seated subduction-accretionary complexes. Three peak metamorphic assemblages are identified in the area studied: (1) garnet-chloritoid-glaucophane with pseudomorphs after lawsonite; (2) chloritoid with pseudomorphs after glaucophane; and (3) chloritoid with pseudomorphs after jadeite in addition to phengite, paragonite, quartz, chlorite, rutile, and apatite. The latter is interpreted as transformation of a chloritoid + glaucophane assemblage to chloritoid + jadeite with increasing pressure; PT modeling indicates 17 and 22-25 kbars for the two peak parageneses. The diversity of peak metamorphic assemblages and the PT estimates suggest that basal accretion occurred at different depths within the wedge. The depth of the basal accretion is possibly controlled by the slab-mantle decoupling depth. Stretching and thinning of the lithospheric fore arc induced by the slab rollback possibly caused shallowing of the slab-mantle decoupling depth which limited depth of the basal accretion from 70-80 km to 55 km within the subduction channel. A slab-mantle coupling depth-controlled basal accretion may also explain the scarcity of eclogite and high-grade blueschist facies metamorphic rocks in active intraoceanic subduction zones. Because the overriding plate is young and hot in intraoceanic subductions, the slab and mantle are coupled at a relatively shallow depth before eclogitization of the oceanic crust. This prevents accretion and exhumation of eclogite along the subduction channel.

  7. Internal deformation in layered Zechstein-III K-Mg salts. Structures formed by complex deformation and high contrasts in viscosity observed in drill cores. (United States)

    Raith, Alexander; Urai, Janos L.


    During the evaporation of a massive salt body, alternations of interrupted and full evaporation sequences can form a complex layering of different lithologies. Viscosity contrasts of up to five orders of magnitude between these different lithologies are possible in this environment. During the late stage of an evaporation cycle potassium and magnesium (K-Mg) salts are precipitated. These K-Mg salts are of economic interest but also a known drilling hazard due to their very low viscosity. How up to 200m thick layers of these evaporites affect salt deformation at different scales is not well known. A better understanding of salt tectonics with extreme mechanical stratification is needed for better exploration and production of potassium-magnesium salts and to predict the internal structure of potential nuclear waste repositories in salt. To gain a better understanding of the internal deformation of these layers we analyzed K-Mg salt rich drill cores out of the Zechstein III-1b subunit from the Veendam Pillow 10 km southeast of Groningen, near the city Veendam in the NE Netherlands. The study area has a complex geological history with multiple tectonic phases of extension and compression forming internal deformation in the pillow but also conserving most of the original layering. Beside halite the most common minerals in the ZIII-1b are carnallite, kieserite, anhydrite and bischofite alternating in thin layers of simple composition. Seismic interpretation revealed that the internal structure of the Veendam Pillow shows areas, in which the K-Mg salt rich ZIII 1b layer is much thicker than elsewhere, as a result of salt deformation. The internal structure of the ZIII-1b on the other hand, remains unknown. The core analysis shows a strong strain concentration in the weaker Bischofite (MgCl2*6H20) and Carnallite (KMgCl3*6H20) rich layers producing tectonic breccias and highly strained layers completely overprinting the original layering. Layers formed by alternating beds

  8. Preparation, characterization, and luminescence properties of dysprosium perchlorate with MABA-Si and phen or dipy complexes as well as SiO2@Dy(MABA-Si)L core-shell structure nanometermeter luminescent composites

    International Nuclear Information System (INIS)

    Li, Wen-Xian; Zheng, Yu-Shan; Cao, Xiao-fang; Bai, Juan; Fu, Zhi-Fang; Bao, Jin-Rong; Li, Yi-Lian


    Two novel ternary rare earth complexes Dy(MABA-Si)·L 2 (ClO 4 ) 3 ·2H 2 O (L= Phen or Dipy) were prepared using HOOCC 6 H 4 N(CONH(CH 2 ) 3 Si-(OCH 2 CH 3 ) 3 ) 2 which was abbreviated or denoted as MABA-Si. MABA-Si was the first ligand, L was the second ligand. The corresponding two SiO 2 @Dy(MABA-Si)L nanometermeter luminescent composites were synthesized as well, and the silica spheres is the core, and the ternary rare earth complex Dy(MABA-Si)·L 2 (ClO 4 ) 3 ·2H 2 O was the shell layer, who was abbreviated or denoted as Dy((MABA-Si)L). The ternary complexes have been characterized by element analysis, molar conductivity, IR spectra and 1 HNMR spectra. The results showed that the chemical formula of the complex was Dy(MABA-Si)·L 2 (ClO 4 ) 3 ·2H 2 O. The fluorescent spectra illustrated that the complexes displayed its characteristic luminescence in solid state, and the luminescence was superior than Dy 3+ . The core-shell structure of SiO 2 @Dy(MABA-Si)L nanometermeter luminescent composite was characterized by SEM, TEM and IR spectra. Based on the SEM photographs, the core-shell structure particles showed its regular microstructure including smooth surface, and good dispersity. The ternary complex coated on the mono-dispersed SiO 2 spheres by self-assembly. The fluorescent spectra illustrated that the core-shell structure of SiO 2 @Dy(MABA-Si)L nanometermeter luminescent composites exhibited stronger fluorescent than the ternary complexes. The fluorescence lifetime of the complexes and core-shell structure composites was measured as well.

  9. Dopamine D1 receptor agonist treatment attenuates extinction of morphine conditioned place preference while increasing dendritic complexity in the nucleus accumbens core. (United States)

    Kobrin, Kendra L; Arena, Danielle T; Heinrichs, Stephen C; Nguyen, Olivia H; Kaplan, Gary B


    The dopamine D1 receptor (D1R) has a role in opioid reward and conditioned place preference (CPP), but its role in CPP extinction is undetermined. We examined the effect of D1R agonist SKF81297 on the extinction of opioid CPP and associated dendritic morphology in the nucleus accumbens (NAc), a region involved with reward integration and its extinction. During the acquisition of morphine CPP, mice received morphine and saline on alternate days; injections were given immediately before each of eight daily conditioning sessions. Mice subsequently underwent six days of extinction training designed to diminish the previously learned association. Mice were treated with either 0.5mg/kg SKF81297, 0.8mg/kg SKF81297, or saline immediately after each extinction session. There was a dose-dependent effect, with the highest dose of SKF81297 attenuating extinction, as mice treated with this dose had significantly higher CPP scores than controls. Analysis of medium spiny neuron morphology revealed that in the NAc core, but not in the shell, dendritic arbors were significantly more complex in the morphine conditioned, SKF81297-treated mice compared to controls. In separate experiments using mice conditioned with only saline, SKF81297 administration after extinction sessions had no effect on CPP and produced differing effects on dendritic morphology. At the doses used in our experiments, SKF81297 appears to maintain previously learned opioid conditioned behavior, even in the face of new information. The D1R agonist's differential, rather than unidirectional, effects on dendritic morphology in the NAc core suggests that it may be involved in encoding reward information depending on previously learned behavior. Published by Elsevier B.V.

  10. Multi-core Microprocessors

    Indian Academy of Sciences (India)

    Design cost of multi-core processors is lower than the cost of designing very complex single processors. This is because in a multi-core pro- cessor a simple processor is designed and replicated. The idea of using several independent processors to work simul- taneously and cooperate to execute a single program is quite ...

  11. Proteomics Core (United States)

    Federal Laboratory Consortium — Proteomics Core is the central resource for mass spectrometry based proteomics within the NHLBI. The Core staff help collaborators design proteomics experiments in a...

  12. Multiphase boudinage: a case study of amphibolites in marble in the Naxos migmatite core

    Directory of Open Access Journals (Sweden)

    S. Virgo


    Full Text Available In multiply deformed terrains multiphase boudinage is common, but identification and analysis of these is difficult. Here we present an analysis of multiphase boudinage and fold structures in deformed amphibolite layers in marble from the migmatitic centre of the Naxos metamorphic core complex. Overprinting between multiple boudinage generations is shown in exceptional 3-D outcrop. We identify five generations of boudinage, reflecting the transition from high-strain high-temperature ductile deformation to medium- to low-strain brittle boudins formed during cooling and exhumation. All boudin generations indicate E–W horizontal shortening and variable direction of bedding parallel extension, evolving from subvertical extension in the earliest boudins to subhorizontal N–S extension during exhumation. Two phases of E–W shortening can be inferred, the first associated with lower crustal synmigmatic convergent flow and the second associated with exhumation and N–S extension, possibly related to movement of the North Anatolian Fault.

  13. Omphacite microstructures as time-temperature indicators of blueschist- and eclogite-facies metamorphism (United States)

    Carpenter, Michael A.


    Omphacites from a wide range of geological environments have been examined by transmission electron-microscopy. Their microstructures are sufficiently variable as to be potential indicators of thermal history for blueschist and eclogite metamorphism. In particular, the average size of equiaxed antiphase domains (APD's) arising from cation ordering appears to be a characteristic feature of each environment and increases in the sequence: Franciscan, blueschist (1) ≈ Turkey, blueschist (2) Wine Complex, Canada, amphibolite (1) disordering (75 kcal mole-1), available estimates of peak metamorphic temperature ( T) are used, and a reasonable geological time-scale is taken as 104 108 years. According to this model, APD sizes are set in a relatively short interval of the total history of a rock when its temperature is close to its peak value. APD sizes are much more sensitive to temperature than to time and may be used as a geothermometer which has the advantage of not being reset by re-equilibration at low temperatures. Petrological implications arising from the model are that Allalin metagabbros were metamorphosed at a similar peak temperature to Zermatt-Saas blueschists, Franciscan eclogites reached higher temperatures than has been previously supposed and that the microstructures in some Sesia-Lanzo omphacites are consistent with a high temperature, pre-blueschist origin. Deviation from an ideal coarsening law with n=2 implies that the APD's are not simply stacking mistakes but have some associated structural or compositional modification locally. Excess titanium concentrated at APD's in Red Wine Complex omphacites may account for their anomalously low observed APD size.

  14. Tectono-metamorphic evolution of the Tavşanli zone, Western Anatolia: implications for mechanical coupling during subduction/obduction processes (United States)

    Plunder, Alexis; Agard, Philippe; Chopin, Christian; Okay, Aral


    Obduction (i.e., emplacement of a dense oceanic lithosphere on top of a continent) and associated continental subduction provide insights into the rheology of the lithosphere and inter-plate mechanical coupling that usefully complements those inferred from normal oceanic subduction beneath continents. Structural and petrological data from the Tavşanlı zone are herein used to highlight processes occurring along the subduction interface from initial obduction stages (i.e., initiation of intra-oceanic subduction witnessed by metamorphic soles) to continental subduction (represented by high-pressure low-temperature, HP-LT rocks). The Tavşanlı zone (Western Anatolia) belongs to the İzmir-Ankara suture zone, which separates the Pontides and Anatolide-Tauride block. It represents a very well preserved late Cretaceous subduction interface, thanks to only mild, later collision. The Tavşanlı zone is divided in three main tectonic units related to (either continental or oceanic) subduction and obduction, respectively, which are from bottom to top: (i) the distal cover of the subducted north facing continental margin of the Anatolide-Tauride block (Orhaneli unit), which yields one of the lowest thermal gradients on earth (i.e., 5°C/km, with peak T and P of 430°C/22-24 kbar); (ii) an accretionary complex made of low-grade, subducted ocean-derived metamorphic rocks; (iii) the non-metamorphic obducted ophiolite, underlain by a thin metamorphic sole, which is found as klippen south of the İzmir-Ankara suture zone. Systematic sampling and structural work allow us to reappraise the nature, internal structure and P-T conditions of the accretionary complex sandwiched between the lower continental and upper oceanic plates. Two major tectonic units (termed complex 1 and 2) are recognised based on metamorphic grade and structural position with respect to the continental margin. Metamorphic conditions range from incipient HP-LT metamorphism (complex 1) to blueschist facies

  15. Nanoscale transient porosity controls large-scale metamorphic fluid flow (United States)

    Plümper, Oliver; Botan, Alexandru; Los, Catharina; Malthe-Sørenssen, Anders; Jamtveit, Bjørn


    The reaction of fluids with rocks is fundamental for Earth's dynamics as they facilitate heat/mass transfer and induce volume changes, weaknesses and instabilities in rock masses that localize deformation enabling tectonic responses to plate motion. During these fluid-rock interactions it is the ability of a rock to transmit fluid, its permeability, that controls the rates of metamorphic reactions. However, although some geological environments (e.g., sediments) are open to fluids, the majority of solid rocks (e.g., granites, elcogites, peridotites, etc.) are nearly impermeable. Surprisingly though, even in rocks that are nominally impermeable widespread fluid-rock interactions are observed leading to the question: How can fluids migrate through vast amounts of nominally impermeable rocks? Here we investigate one of the most wide-spread fluid-mediated metamorphic processes in the Earth's crust, the albitization of feldspatic rocks. We show that fluid flow and element mobilization during albitization is controlled by an interaction between grain boundary diffusion and reaction front migration through an interface-coupled dissolution-precipitation process. Using a combination of focused ion beam scanning electron microscopy (FIB-SEM)-assisted nanotomography combined with transmission electron microscopy (TEM) reveals that the porosity is dictated by pore channels with a pore diameter ranging between 10 to 100 nm. Three-dimensional visualization of the feldspar pore network reveals that the pore channels must have been connected during the replacement reaction. Analysis of the pore aspect ratios suggests that a Rayleigh-Taylor-type instability associated to surface energy minimization caused the disconnection of the pore channels. Fluid transport in nanometer-sized objects with at least one characteristic dimension below 100 nm enables the occurrence of physical phenomena that are impossible at bigger length scales. Thus, on the basis of our microstructural

  16. Self-induced nanofluidic transport enables crustal-scale metamorphism (United States)

    Plümper, Oliver; Botan, Alexandru; Los, Catharina; Liu, Yang; Malthe-Sørenssen, Anders; Jamtveit, Bjørn


    The reaction of fluids with rocks is fundamental for Earth's dynamics as they facilitate heat/mass transfer and induce volume changes, weaknesses and instabilities in rock masses that localize deformation enabling tectonic responses to plate motion. During these fluid-rock interactions it is the ability of a rock to transmit fluid, its permeability, that controls the rates of metamorphic reactions. However, although some geological environments (e.g., sediments) are open to fluids, the majority of solid rocks (e.g., granites, elcogites, peridotites, etc.) are nearly impermeable. Surprisingly though, even in rocks that are nominally impermeable widespread fluid-rock interactions are observed leading to the question: How can fluids migrate through vast amounts of nominally impermeable rocks? Here we investigate one of the most wide-spread fluid-mediated metamorphic processes in the Earth's crust, the albitization of feldspatic rocks. We show that fluid flow and element mobilization during albitization is controlled by an interaction between grain boundary diffusion and reaction front migration through an interface-coupled dissolution-precipitation process. Using a combination of focused ion beam scanning electron microscopy (FIB-SEM)-assisted nanotomography combined with transmission electron microscopy (TEM) we show that the porosity is dictated by pore channels with a pore diameter ranging between 10 to 100 nm. Three-dimensional visualization of the feldspar pore network reveals that the pore channels must have been connected during the replacement reaction. Analysis of the pore aspect ratios suggests that a Rayleigh-Taylor-type instability associated to surface energy minimization caused the disconnection of the pore channels. Fluid transport in nanometer-sized objects with at least one characteristic dimension below 100 nm enables the occurrence of physical phenomena that are impossible at bigger length scales. Thus, on the basis of our microstructural

  17. 2 : 2 Fe(III): ligand and "adamantane core" 4 : 2 Fe(III): ligand (hydr)oxo complexes of an acyclic ditopic ligand

    DEFF Research Database (Denmark)

    Ghiladi, Morten; Larsen, Frank B.; McKenzie, Christine J.


    crystalline platelets. The Fe4O6 core of 2 shows an adamantane-like structure: The six bridging oxygen atoms are provided by the two phenolato groups of the two bpbp(-) ligands, two bridging oxo groups and two bridging hydroxo groups. The hydroxo and oxo ligands could be distinguished on the basis of Fe - O......-ray structure of the dinuclear complex [{( Hbpbp) Fe(mu-OH)}(2)](ClO4)(4) center dot 2C(3)H(6)O ( 1 center dot 2C(3)H(6)O) shows that only one of the metal-binding cavities of each ligand is occupied by an iron( III) atom and two [Fe(Hbpbp)](3+) units are linked together by two hydroxo bridging groups to form...... a [ Fe(III) -(mu-OH)](2) rhomb structure with Fe center dot center dot center dot Fe = 3.109(1) angstrom. The non-coordinated tertiary amine of Hbpbp is protonated. Magnetic susceptibility measurements show a well-behaved weak antiferromagnetic coupling between the two Fe( III) atoms, J =- 8 cm(-1...

  18. A novel octanuclear vanadium(V) oxide cluster complex having an unprecedented neutral V8O20 core functionalized with 4,4'-di-tert-butyl-2,2'-bipyridine. (United States)

    Kodama, Shintaro; Taya, Nobuto; Ishii, Youichi


    A novel octanuclear vanadium(V) oxide cluster complex, [V8O20(4,4'-(t)Bubpy)4] (1), was synthesized and characterized by single-crystal X-ray structure analysis to reveal that 1 has an unprecedented neutral V8O20 core. An unexpected interconversion between 1 and the methoxo(oxo)vanadium(V) cluster complex, [V4O8(OMe)4(4,4'-(t)Bubpy)2] (2), was observed upon changes in the solvent systems.

  19. Metabolism of thyroxine in Rana catesbeiana tadpoles during metamorphic climax

    International Nuclear Information System (INIS)

    Galton, V.A.; Munck, K.


    Previous studies have indicated that premetamorphic tadpoles do not convert T4 to T3 to a measurable extent (1). The present study was performed to determine whether a T4 5'-monodeiodinating system is acquired at later stages of development. [ 125 I]T4 metabolism in vivo was determined in tadpoles at most stages of prometamorphosis and metamorphic climax and, for comparison, in premetamorphic tadpoles. The conversion of [ 125 I]T4 to [ 125 I]T3, as indicated by the presence of an 125 I-labeled product in serum and liver preparations that cochromatographed with carrier T3, was sometimes observed in tadpoles near the end of prometamorphosis and was always evident in tadpoles that were either undergoing or had completed metamorphic climax. However, during this phase, no correlation could be drawn between the extent of T3 production and morphological development. The formation of T3 from T4 in vivo was significantly decreased in tadpoles pretreated with propylthiouracil. The T45'-monodeiodinating system could be induced in premetamorphic tadpoles by injecting them with either T4 or T3. This finding together with the observation that normal acquisition of this system occurs at the time when endogenous T4 and T3 levels are rising rapidly suggest that its development is under the control of the thyroid hormones

  20. Building a Six-Junction Inverted Metamorphic Concentrator Solar Cell

    Energy Technology Data Exchange (ETDEWEB)

    Geisz, John F [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Steiner, Myles A [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Jain, Nikhil [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Schulte, Kevin L [National Renewable Energy Laboratory (NREL), Golden, CO (United States); France, Ryan M [National Renewable Energy Laboratory (NREL), Golden, CO (United States); McMahon, William E [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Perl, Emmett [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Friedman, Daniel J [National Renewable Energy Laboratory (NREL), Golden, CO (United States)


    We propose practical six-junction (6J) inverted metamorphic multijunction (IMM) concentrator solar cell designs with the potential to exceed 50% efficiency using moderately high quality junction materials. We demonstrate the top three junctions and their monolithic integration lattice matched to GaAs using 2.1-eV AlGaInP, 1.7-eV AlGaAs or GaInAsP, and 1.4-eV GaAs with external radiative efficiencies >0.1%. We demonstrate tunnel junctions with peak tunneling current >400 A/cm2 that are transparent to <2.1-eV light. We compare the bottom three GaInAs(p) junctions with bandgaps of 1.2, 1.0, and 0.7 eV grown on InP and transparent metamorphic grades with low dislocation densities. The solution to an integration challenge resulting from Zn diffusion in the GaAs junction is illustrated in a five-junction IMM. Excellent 1-sun performance is demonstrated in a complete 6J IMM device with VOC = 5.15 V, and a promising pathway toward >50% efficiency at high concentrations is presented.

  1. The Grant Range in eastern Nevada: a `proto' core complex exhumed entirely by brittle, low-angle (≤15°) detachment faults (United States)

    Long, S. P.; Walker, J. P.


    Documenting the range of styles of normal faulting is fundamental to understanding how the crust responds during extension. Here, we discuss field relationships that constrain the geometry and kinematic development of a system of W-vergent, upper-crustal detachment faults in the Grant Range in eastern Nevada. The faults exhibit brecciation and stratigraphic cutoff angles of 5-15° at all structural levels, deform a 10 km-thick section of Paleozoic and Paleogene rocks, and exhume a `core' of greenschist-facies Cambrian rocks and Cretaceous granite. The oldest faults are cut by a 29 Ma dike, and the highest fault cuts 32 Ma volcanic rocks that restore to a paleo-depth of 1 km. The fault system is folded across an anticlinal culmination, which grew during extension, as indicated by progressively increasing interlimb angles and incision in the axial zone. The eastern limb consists of an imbricate stack of faults that were emplaced from bottom-to-top. In the western limb, several faults exhibit apparent thrust relationships. Retro-deformation of folding and minimal structural relief and angularity across a Paleogene unconformity indicate that the faults were active at ≤15° angles. Retro-deformation of offset indicates ≥49 km (98%) extension. We propose a model of stationary, sustained isostatic uplift and incision at the culmination axis (a `fixed hinge'), with back-rotation and excision up-dip of the axis producing bottom-to-top growth of the imbricate stack, and excision down-dip of the axis yielding apparent thrust relationships. Initiation of extension, bracketed between 32-29 Ma, was coeval with the sweep of ignimbrite magmatism through this region. Therefore, the Grant Range can be placed in the temporal context of the episode of Paleogene, core complex-dominated extension within the retroarc plateau. Low-angle faulting is interpreted to have been favored by rotation of the upper-crustal stress field as a result of shear traction imparted by lower

  2. Possible zircon U-Pb evidence for Pan-African granulite-facies metamorphism in the Mozambique belt of southern Tanzania

    International Nuclear Information System (INIS)

    Coolen, J.J.M.M.M.


    Four zircon fractions of garnet-bearing two-pyroxene granulite, from the Furua granulite complex of southern Tanzania, plot very close to concordia. A discordia yields a lower intercept at 652 +- 10 Ma, an age slightly higher than the Rb-Sr whole-rock and mineral ages reported from the surrounding amphibolite-facies rocks. The U-Pb systematics indicate the presence of a very small amount of older (2-3 Ga) radiogenic lead. The zircon data may be interpreted as indicating an event of granulite-facies metamorphism during the Pan-African thermotectonic episode. This interpretation is at variance with current models postulating that the granulite complexes in the Mozambique belt are relicts of older, possibly Archaean events of metamorphism. (Auth.)

  3. Garnet growth interruptions during high- and ultra high-pressure metamorphism constrained by thermodynamic forward models (United States)

    Konrad-Schmolke, M.; Schildhauer, H.


    Growth and chemical composition of garnet in metamorphic rocks excellently reflect thermodynamic as well kinetic properties of the host rock during garnet growth. This valuable information can be extracted from preserved compositional growth zoning patterns in garnet. However, metamorphic rocks often contain multiple garnet generations that commonly develop as corona textures with distinct compositional core-overgrowth features. This circumstance can lead to a misinterpretation of information extracted from such grains if the age- and metamorphic relations between different garnet generations are unclear. Especially garnets from high-pressure (HP) and ultra high-pressure (UHP) rocks often preserve textures that show multiple growth stages reflected in core-overgrowth differences both in main and trace element composition and in the inclusion assemblage. Distinct growth zones often have sharp boundaries with strong compositional gradients and/or inclusion- and trace-element-enriched zones. Such growth patterns indicate episodic garnet growth as well as growth interruptions during the garnet evolution. A quantitative understanding of these distinct growth pulses enables the relationship between reaction path, age determinations in spatially controlled garnet domains or temperature-time constraints to be fully characterised. In this study we apply thermodynamic forward models to simulate garnet growth along a series of HP and UHP P-T paths, representative for subducted oceanic crust. We study garnet growth in different basaltic rock compositions and under different element fractionation scenarios in order to detect path-dependent P-T regions of limited or ceased garnet growth. Modeled data along P-T trajectories involving fractional crystallisation are assembled in P-T diagrams reflecting garnet growth in a changing bulk rock composition. Our models show that in all investigated rock compositions garnet growth along most P-T trajectories is discontinuous, pulse

  4. Petrology and SHRIMP U-Pb dating of Xitieshan eclogite, North Qaidam UHP metamorphic belt, NW China (United States)

    Zhang, Cong; Zhang, Lifei; Roermund, Herman Van; Song, Shuguang; Zhang, Guibin


    Normal bimineralic and phengite-bearing eclogites have been recognized within mafic boudins (or lenses) enclosed in granitic and pelitic gneisses in the Xitieshan terrane, NW China. Bimineralic eclogite contains the primary M1 mineral assemblage Grt + Omp + Rt + Qtz+/-Zrn. Inclusions in M1 omphacite may be coesite pseudomorphs. Phengite eclogite consists of the M1 mineral assemblage Grt + Omp + Phn + Qtz + Rt+/-Zrn. Most eclogites are retrogressed to various degrees and contain hornblende, diopside and plagioclase, which commonly form symplectitic and/or kelyphitic intergrowths. The peak M1 P-T conditions of the Xitieshan eclogite are calculated to be P = 2.71-3.17 GPa and T = 751-791 °C, consistent with the presence of coesite pseudomorphs in omphacite. In addition, we have identified two stages of retrograde metamorphism; an early isothermal decompression stage (M2) followed by a later stage (M3) that developed under decreasing temperatures and pressures. During M2 internally-derived fluids played an important role, whereas during M3 and below externally-derived fluids dominated. The composition of garnet in M1changed little during M2 isothermal decompression (ITD), although pyrope contents in garnet locally decrease from core to rim where the grains have amphibole and pargasite + plagioclase coronas. Also the jadeite content (56%) of M1 omphacite decreased in the presence of active fluids during retrograde metamorphism. M1 phengite is replaced by the M2 assemblage Ms + Bt accompanied by K-feldspar + quartz. Amphibole compositions changed from magnesio-katophorite in M2 to pargasite in M3. Zircon U-Pb SHRIMP dating shows that the bimineralic eclogite has a magmatic protolith age of 877 ± 8 Ma and a metamorphic age of 439 ± 8 to 461 ± 4 Ma. We conclude that the Xitieshan metabasic rocks formed in the late Proterozoic and were subsequently subducted to depths of about 100 km, where they were metamorphosed to UHP eclogite during the late Ordovician (440-460 Ma

  5. Thermal evolution of high-pressure metamorphic rocks in the Alps

    NARCIS (Netherlands)

    Brouwer, F.M.


    There are two major and currently unresolved issues in Alpine geology concerning the metamorphic evolution of the rocks in the internal zones of the Alps. First, rocks showing evidence for geologically young, high-pressure to very high-pressure metamorphism are now exposed at the Earth's surface,

  6. Shock metamorphism in the Vredefort Collar: Evidence for internal shock sources (United States)

    Lilly, P. A.


    Shock metamorphic microstructures in the Vredefort collar include planar features, crystallographically controlled cleavage, crystallographically controlled faults, and mosaic extinction. In addition, several recrystallization textures are developed in the quartzites of the collar, and quartz c axis distributions for both primary and recrystallized quartz grains are random. The degree of recrystallization decreases away from the core-collar contact. Two events of shock deformation have been identified in the collar, and using planar feature orientations, shock pressures have been estimated using the technique of Robertson (1975). The first shock (D1) subjected the lowermost Witwatersrand rocks to shock pressures of about 150 kbar and the uppermost beds to pressures of about 60 kbar. Following a period of extensive recrystallization of the quartzites came the second shock event (D2), which was weaker than the first and subjected the lowermost strata in the collar to pressures of between 75 and 100 kbar. The D2 event has been shown to be separated in time from the D1 event. The results are used to show that the shock sources were probably within the earth and that the Vredefort ring structure has formed as a result of endogenous processes rather than hypervelocity meteorite impact.

  7. Tectono-metamorphic evolution of a hot orogen during Gondwanaland assembly: a case study from Palni hills metapelite granulite, south India (United States)

    Bhadra, S.; Nasipuri, P.


    chemically distinct than sapphirine occurring in texturally similar type1 symplectite domain. Orthopyroxene porphyroblast records largest rim-ward decrease in Al2O3 (core: ~ 8 wt%; rim: 4.4 wt%). Also this domain lacks any veneer of meso-perthitic feldspar. P, T condition of M2 metamorphism is constrained at 7.5 kbar, 900 °C indicating a second stage of near-isothermal decompression (Opx+Sil = Spr + Crd). Monazites though occur as small inclusion (40 μm) in orthopyroxene porphyroblast, are predominant and larger (>100μm) in the biotite-feldspar defining leucosome domain suggesting melt-crystallization-assisted growth of monazite. Consequently, 560 Ma ages, which is recorded either uniformly from Opx-included monazite or from the core of matrix monazite, qualify to peak M1A and M1B metamorphism. The age relation further re-affirms that MB is a part of the transcontinental Pan-African granulite block that formed during Gondwanaland assembly and extends across Madagascar-India-Antarctica. As documented recently, final juxtaposition of MB with Archean Dharwar craton to the north was during Cambrian and marked by the closure of paleo-Mozambique Ocean along the Palghat Cauvery Shear Zone. Importantly, younger ages of 496 Ma were recorded from the rim of matrix monazite grains. Without proper textural relation, significance of this age remains uncertain. However, we tend to believe that 500 Ma age corresponds to M2 retrograde metamorphism and final exhumation of the UHT granulite at Perumalmalai. If proven, this possibly coincides with the tectonic extrusion related domal uplift of the MB during the final stage of Gondwanaland assembly.

  8. The Punta del Este terrain and its volcano sedimentary cover, metamorphic and sedimentary: geology, geochemistry and geochronology

    International Nuclear Information System (INIS)

    Preciozzi, F.


    Gariep belt it develops over the West Africa coastal region of Namibia underlying on Namaqua metamorphic complex.It characterized by supra crustal rocks affected for a very low to low metamorphism and in two tecto no-stratigraphic units identified by Base i et al 2005 showing that sediments of Formation Rocha in Uruguay and the Group Oranjemund Gariep in S E Africa have similar ages in the provenance of the zircons, suggesting that they were probably deposited in the same basin. This unit exhibits detrital zircons around 600my, sedimentation and metamorphism and deformación occur in a narrow time interval from 600-610 to 574 m (Granite de Castillo intrusion) .Cam pal et al, 2005 proposed to the Cerros Aguirre Formation similar in a range of age of different events. To the east separated from the Punta del Este Terrane –Pelotas. Aigua .Florianopolis batholith s by the shear zone Alferez Cordillera (Preciozzi et al. 1999, Basei et al. 2000) Another option develops this granitic belt is an integral part of Land Punta del Este Terrane(Preciozzi in this work), being deployed on a thin cratonic granite edge. The climax of the post-brasilian magmatism is 580my, strongly related to trans current movements (eg shear zones Major Gercino-Alferez- Cordillera and Sierra Ballena.In South America an old west domain is formed by the Piedra Alta Terrane which integrate the Río de la Pl ata Craton, a central domain intensely reworked by Neoproterozoic events known so far as Nico Perez . The primary coverage is integrated by two volcano-sedimentary basins (San Carlos Formation and Cerros de Aguirre Formation)In this study are considered the Geology,Geochemistry and Geochronology of the different units of Rocha Formation

  9. Zircon and monazite petrochronologic record of prolonged amphibolite to granulite facies metamorphism in the Ivrea-Verbano and Strona-Ceneri Zones, NW Italy (United States)

    Guergouz, Celia; Martin, Laure; Vanderhaeghe, Olivier; Thébaud, Nicolas; Fiorentini, Marco


    In order to improve the understanding of thermal-tectonic evolution of high-grade terranes, we conducted a systematic study of textures, REE content and U-Pb ages of zircon and monazite grains extracted from migmatitic metapelites across the amphibolite to granulite facies metamorphic gradient exposed in the Ivrea-Verbano and Strona-Ceneri Zones (Italy). This study documents the behaviour of these accessory minerals in the presence of melt. The absence of relict monazite grains in the metasediments and the gradual decrease in the size of inherited zircon grains from amphibolite to granulite facies cores indicate partial to total dissolution of accessory minerals during the prograde path and partial melting. The retrograde path is marked by (i) growth of new zircon rims (R1 and R2) around inherited cores in the mesosome, (ii) crystallisation of stubby zircon grains in the leucosome, especially at granulite facies, and (iii) crystallisation of new monazite in the mesosome. Stubby zircon grains have a distinctive fir-tree zoning and a constant Th/U ratio of 0.20. Together, these features reflect growth in the melt; conversely, the new zircon grains with R1 rims have dark prismatic habits and Th/U ratios ages obtained on both types are similar, indicating contemporaneous growth of stubby zircon and rims around unresorbed zircon grains, reflecting the heterogeneous distribution of the melt at the grain scale. In the Ivrea-Verbano Zone the interquartile range (IQR) of U-Pb ages on zircon and monazite are interpreted to represent the length of zircon and monazite crystallisation in the presence of melt. Accordingly, they provide an indication on the minimum duration for high-temperature metamorphism and partial melting of the lower crust: 20 Ma and 30 Ma in amphibolite and granulite facies, respectively. In amphibolite facies, zircon crystallisation between 310 and 294 Ma (IQR) is interpreted to reflect metamorphic peak condition and earlier retrograde history; conversely

  10. Amphibole and felsic veins from the gabbroic oceanic core complex of Atlantis Bank (Southwest Indian Ridge, IODP Hole U1473A): when the fluids meets the melts (United States)

    Sanfilippo, A.; Tribuzio, R.; Antonicelli, M.; Zanetti, A.


    We present a petrological/geochemical investigation of brown amphibole and felsic veins drilled during IODP 360 expedition at Atlantis Bank, a gabbroic oceanic core complex from Southwest Indian Ridge. The main purpose of this study is to unravel the role of seawater and magmatic components in the origin of these veins. Brown amphibole veins were collected at 90-170 mbsf. These veins typically include minor modal amounts of plagioclase and are associated with alteration halos made up of brown amphibole and whitish milky plagioclase in host gabbros. Two sets of late magmatic felsic veins, which mostly consist of plagioclase and minor brown amphibole, were selected. Amphibole-plagioclase geothermometry (Holland and Blundy, 1994) documents that crystallization of brown amphibole and felsic veins occurred in the 850-700 °C interval. In the brown amphibole veins, amphibole and plagioclase have relatively low concentrations of incompatible trace elements and significant Cl (0.2-0.3 wt%). The development of these veins at near surface levels is therefore attributed to seawater-derived fluids migrating downward through cracks developing in the exhuming gabbro. To explain the high temperature estimates for the development of these shallow veins, however, the seawater-derived fluids must have interacted not only with the gabbros, but also with a high temperature magmatic component. This petrogenetic hypothesis is consistent with oxygen and hydrogen isotopic compositions of amphiboles from shallow veins in adjacent Hole 735B gabbros (Alt and Bach, 2006). Trace element compositions of amphibole and plagioclase from the felsic veins show formation by silicate melts rich in incompatible elements. In addition, Cl concentrations in amphibole from the felsic veins are low, thereby indicating that the melts feeding these veins had low or no seawater component. We cautiously propose that: (i) the felsic veins were generated by SiO2-rich melts residual after crystallization of Fe

  11. Constraints on the Lost City Hydrothermal System from borehole thermal data; 3-D models of heat flow and hydrothermal circulation in an oceanic core complex. (United States)

    Titarenko, S.; McCaig, A. M.


    A perennial problem in near-ridge hydrothermal circulation is that the only directly measurable data to test models is often vent fluid temperature. Surface heat flow measurements may be available but without the underlying thermal structure it is not known if they are transient and affected by local hydrothermal flow, or conductive. The Atlantis Massif oceanic core complex at 30 °N on the mid-Atlantic Ridge, offers a unique opportunity to better constrain hydrothermal circulation models. The temperature profile in gabbroic rocks of IODP Hole 1309D was measured in IODPExpedition 340T, and found to be near-conductive, but with a slight inflexion at ~750 mbsf indicating downward advection of fluid above that level. The lack of deep convection is especially remarkable given that the long-lived Lost City Hydrothermal Field (LCHF) is located only 5km to the south. We have modelled hydrothermal circulation in the Massif using Comsol Multiphysics, comparing 2-D and 3-D topographic models and using temperature-dependent conductivity to give the best estimate of heatflow into the Massif. We can constrain maximum permeability in gabbro below 750 mbsf to 5e-17 m2. The thermal gradient in the upper part of the borehole can be matched with a permeability of 3e-14 m2 in a 750 m thick layer parallel to the surface of the massif, with upflow occurring in areas of high topography and downflow at the location of the borehole. However in 3-D the precise flow pattern is quite model dependent, and the thermal structure can be matched either by downflow centred on the borehole at lower permeability or centred a few hundred metres from the borehole at higher permeability. The borehole gradient is compatible with the longevity (>120 kyr) and outflow temperature (40-90 °C) of the LCHF either with a deep more permeable (1e-14 m2 to 1e-15 m2) domain beneath the vent site in 2-D or a permeable fault slot 500 to 1000m wide and parallel to the transform fault in 3-D. In both cases topography

  12. Low- to high-grade metamorphic transition in the Southern part of Karnataka Nucleus, India (United States)

    Naqvi, S. M.


    The southern part of Karnataka Nucleus has a strong imprint of 2.6 Ga metamorphism. This has affected the schist belts of Karnataka Nucleus from greenschist to upper amphibolite facies. The higher grades of metamorphism are in the Holenarasipur, Nuggihalli, Krishnarajpet, Hadnur and Melkote schist belts. In the high grade transition zone, around Sargur only keels of schist belts are preserved and occur as highly dismembered, disconnected belts with the top and bottom of the stratigraphic column obliterated due to high grade metamorphism and accompanying migmatization. Absence of high-grade metamorphic minerals in the sediments of the Dharwar schist belts supports the contention that high grade metamorphism post-dated the Dharwar sedimentation and occurred around 2.6 Ga ago. Sargur type metamorphism occurred at upper crustal levels and charnockite type metamorphism occurred in lower crustal levels. The P-T conditions for the mineral assemblage in metapelites of Sargur Group indicate burial depths up to at least 15 km suggesting that they were subducted and later obducted during the development of Early Proterozoic Mobile Belt along the southern border of the Karnataka Nucleus.

  13. Structural evolution of the Semail Ophiolite metamorphic sole, Wadi Hawasina and Northern Jebel Nakhl Culmination, Oman (United States)

    Hurtado, C.; Bailey, C.; Visokay, L.; Scharf, A.


    The Semail ophiolite is the world's largest and best-exposed ophiolite sequence, however the processes associated with both oceanic detachment and later emplacement onto the Arabian continental margin remain enigmatic. This study examines the upper mantle section of the ophiolite, its associated metamorphic sole, and the autochthonous strata beneath the ophiolite at two locations in northern Oman. Our purpose is to understand the structural history of ophiolite emplacement and evaluate the deformation kinematics of faulted and sheared rocks in the metamorphic sole. At Wadi Hawasina, the base of the ophiolite is defined by a 5- to 15-m thick zone of penetratively-serpentinized mylonitic peridotite. Kinematic indicators record top-to-the SW (reverse) sense-of-shear with a triclinic deformation asymmetry. An inverted metamorphic grade is preserved in the 300- to 500-m thick metamorphic sole that is thrust over deep-water sedimentary rocks of the Hawasina Group. The study site near Buwah, in the northern Jebel Nakhl culmination, contains a N-to-S progression of mantle peridotite, metamorphic sole, and underlying Jurassic carbonates. Liswanite crops out in NW-SE trending linear ridges in the peridotite. The metamorphic sole includes well-foliated quartzite, metachert, and amphibolite. Kinematic evidence indicates that the liswanite and a serpentinized mélange experienced top to-the north (normal) sense-of-shear. Two generations of E-W striking, N-dipping normal faults separate the autochthonous sequence from the metamorphic sole, and also cut out significant sections of the metamorphic sole. Fabric analysis reveals that the metamorphic sole experienced flattening strain (K<0.2) that accumulated during pure shear-dominated general shear (Wk<0.4). Normal faulting and extension at the Buwah site indicates that post-ophiolite deformation is significant in the Jebel Akhdar and Jebel Nakhl culminations.

  14. The discovery and significance of the northeastern Jiangxi Province ophiolite (NEJXO), its metamorphic peridotite and associated high temperature-high pressure metamorphic rocks (United States)

    Guoqing, Zhou

    The NEJXO with a N.E.-S.W. elongation occurs in the mid-Lower Qigong Group, under which lies the Jiuling Group (1401 Ma) and above which lies the Shangshu Group (817 ± 87 Ma), so that the age of NEJXO is defined to be Proterozoic between 1401 Ma and 817 ± 87 Ma. The sediments of the Jiuling Group show evidence of continental derivation, but the Qigong Group and Shangshu Group are characterised by CA volcanic rocks and probably represent a gradually growing island-arc. Thus, we regard the NEJXO as occurring in a back-island-arc basin between the ancient continent and the island-arc. On the whole, the main members of dismembered ophiolite are all present. The metamorphic periodotite present in them, is considered to be especially important, because it may be the sole representative of the older mantle present and it differs from those younger. The high-T metamorphic rocks associated with the NEJXO are various hornstones and melilite marble, whereas the high-P metamorphic rocks are aragonite-jadeite-glaucophane schist and schistose lawsonite marble. From the fact that high-P metamorphism was superimposed on the high-T metamorphic rocks, it may be suggested that early tension (at opening stage) and late compression (at closing stage) occurred during the development of the basin.

  15. Microtectonic-assisted P-T determination on low-grade Alpine metamorphic rocks from the "Tisia Mega-Unit" of the Slavonian Mountains in Croatia (United States)

    Balen, Dražen; Lihter, Iva; Massonne, Hans-Joachim


    The internal structure of the Tisia (Tisza) Mega-Unit in the Alpine-Carpathian-Dinaridic orogenic system encompasses large Alpine nappe systems brought to its present-day position by complex regional-scale movements. The Slavonian Mountains are part of the Bihor nappe system which is below the Codru and above the Mecsek nappe systems. The low-grade metamorphic schist unit of the Slavonian Mountains includes numerous rocks which were previously related to Precambrian and/or Lower Paleozoic orogeneses. However, recent studies (e.g. Balen, 2014, European Geosciences Union General Assembly, EGU 2014-6122) show that the metapelites of this unit should be attributed to the Alpine orogeny and the poorly known P-T conditions, which they experienced, should be refined. Although metapelites can be sensitive to changes of metamorphic conditions and, therefore, be suitable for the P-T estimation of metamorphic event(s), the extraction of mineral assemblages, being in equilibrium, and associated microtectonic data for particular low-grade metamorphic rocks is not straightforward. On the contrary, due to lack of suitable minerals and complex mictotectonic features, one can be faced with a severe problem concerning (dis)equilibrium. To avoid this, the observation scale in the research was set to the sub-mm level taking into account microtectonic positions of minerals. The investigated samples from the Slavonian Mountains are fine-grained schists consisting of chlorite (15-30 vol. %), white mica (15-25 vol. %), quartz (10-25 vol. %), feldspars (albite 10-15 vol. %; some K-feldspar), biotite (Financial support by the Croatian Science Foundation (IP-2014-09-9541) and T. Theye's help during microprobe work is greatly acknowledged.

  16. Deep levels in metamorphic InAs/InGaAs quantum dot structures with different composition of the embedding layers (United States)

    Golovynskyi, S.; Datsenko, O.; Seravalli, L.; Kozak, O.; Trevisi, G.; Frigeri, P.; Babichuk, I. S.; Golovynska, I.; Qu, Junle


    Deep levels in metamorphic InAs/In x Ga1-x As quantum dot (QD) structures are studied with deep level thermally stimulated conductivity (TSC), photoconductivity (PC) and photoluminescence (PL) spectroscopy and compared with data from pseudomorphic InGaAs/GaAs QDs investigated previously by the same techniques. We have found that for a low content of indium (x = 0.15) the trap density in the plane of self-assembled QDs is comparable or less than the one for InGaAs/GaAs QDs. However, the trap density increases with x, resulting in a rise of the defect photoresponse in PC and TSC spectra as well as a reduction of the QD PL intensity. The activation energies of the deep levels and some traps correspond to known defect complexes EL2, EL6, EL7, EL9, and EL10 inherent in GaAs, and three traps are attributed to the extended defects, located in InGaAs embedding layers. The rest of them have been found as concentrated mainly close to QDs, as their density in the deeper InGaAs buffers is much lower. This an important result for the development of light-emitting and light-sensitive devices based on metamorphic InAs QDs, as it is a strong indication that the defect density is not higher than in pseudomorphic InAs QDs.

  17. Transformer core

    NARCIS (Netherlands)

    Mehendale, A.; Hagedoorn, Wouter; Lötters, Joost Conrad


    A transformer core includes a stack of a plurality of planar core plates of a magnetically permeable material, which plates each consist of a first and a second sub-part that together enclose at least one opening. The sub-parts can be fitted together via contact faces that are located on either side

  18. Transformer core

    NARCIS (Netherlands)

    Mehendale, A.; Hagedoorn, Wouter; Lötters, Joost Conrad


    A transformer core includes a stack of a plurality of planar core plates of a magnetically permeable material, which plates each consist of a first and a second sub-part that together enclose at least one opening. The sub-parts can be fitted together via contact faces that are located on either side

  19. Oligomerization of the E. coli Core RNA Polymerase: Formation of (α2ββ'ω)2–DNA Complexes and Regulation of the Oligomerization by Auxiliary Subunits (United States)

    Kansara, Seema G.; Sukhodolets, Maxim V.


    In this work, using multiple, dissimilar physico-chemical techniques, we demonstrate that the Escherichia coli RNA polymerase core enzyme obtained through a classic purification procedure forms stable (α2ββ'ω)2 complexes in the presence or absence of short DNA probes. Multiple control experiments indicate that this self-association is unlikely to be mediated by RNA polymerase-associated non-protein molecules. We show that the formation of (α2ββ'ω)2 complexes is subject to regulation by known RNA polymerase interactors, such as the auxiliary SWI/SNF subunit of RNA polymerase RapA, as well as NusA and σ70. We also demonstrate that the separation of the core RNA polymerase and RNA polymerase holoenzyme species during Mono Q chromatography is likely due to oligomerization of the core enzyme. We have analyzed the oligomeric state of the polymerase in the presence or absence of DNA, an aspect that was missing from previous studies. Importantly, our work demonstrates that RNA polymerase oligomerization is compatible with DNA binding. Through in vitro transcription and in vivo experiments (utilizing a RapAR599/Q602 mutant lacking transcription-stimulatory function), we demonstrate that the formation of tandem (α2ββ'ω)2–DNA complexes is likely functionally significant and beneficial for the transcriptional activity of the polymerase. Taken together, our findings suggest a novel structural aspect of the E. coli elongation complex. We hypothesize that transcription by tandem RNA polymerase complexes initiated at hypothetical bidirectional “origins of transcription” may explain recurring switches of the direction of transcription in bacterial genomes. PMID:21533049

  20. The Functions of Metamorphic Metallothioneins in Zinc and Copper Metabolism. (United States)

    Krężel, Artur; Maret, Wolfgang


    Recent discoveries in zinc biology provide a new platform for discussing the primary physiological functions of mammalian metallothioneins (MTs) and their exquisite zinc-dependent regulation. It is now understood that the control of cellular zinc homeostasis includes buffering of Zn 2+ ions at picomolar concentrations, extensive subcellular re-distribution of Zn 2+ , the loading of exocytotic vesicles with zinc species, and the control of Zn 2+ ion signalling. In parallel, characteristic features of human MTs became known: their graded affinities for Zn 2+ and the redox activity of their thiolate coordination environments. Unlike the single species that structural models of mammalian MTs describe with a set of seven divalent or eight to twelve monovalent metal ions, MTs are metamorphic. In vivo, they exist as many species differing in redox state and load with different metal ions. The functions of mammalian MTs should no longer be considered elusive or enigmatic because it is now evident that the reactivity and coordination dynamics of MTs with Zn 2+ and Cu⁺ match the biological requirements for controlling-binding and delivering-these cellular metal ions, thus completing a 60-year search for their functions. MT represents a unique biological principle for buffering the most competitive essential metal ions Zn 2+ and Cu⁺. How this knowledge translates to the function of other families of MTs awaits further insights into the specifics of how their properties relate to zinc and copper metabolism in other organisms.

  1. The Functions of Metamorphic Metallothioneins in Zinc and Copper Metabolism

    Directory of Open Access Journals (Sweden)

    Artur Krężel


    Full Text Available Recent discoveries in zinc biology provide a new platform for discussing the primary physiological functions of mammalian metallothioneins (MTs and their exquisite zinc-dependent regulation. It is now understood that the control of cellular zinc homeostasis includes buffering of Zn2+ ions at picomolar concentrations, extensive subcellular re-distribution of Zn2+, the loading of exocytotic vesicles with zinc species, and the control of Zn2+ ion signalling. In parallel, characteristic features of human MTs became known: their graded affinities for Zn2+ and the redox activity of their thiolate coordination environments. Unlike the single species that structural models of mammalian MTs describe with a set of seven divalent or eight to twelve monovalent metal ions, MTs are metamorphic. In vivo, they exist as many species differing in redox state and load with different metal ions. The functions of mammalian MTs should no longer be considered elusive or enigmatic because it is now evident that the reactivity and coordination dynamics of MTs with Zn2+ and Cu+ match the biological requirements for controlling—binding and delivering—these cellular metal ions, thus completing a 60-year search for their functions. MT represents a unique biological principle for buffering the most competitive essential metal ions Zn2+ and Cu+. How this knowledge translates to the function of other families of MTs awaits further insights into the specifics of how their properties relate to zinc and copper metabolism in other organisms.

  2. Correlated evolution of phenotypic plasticity in metamorphic timing. (United States)

    Michimae, H; Emura, T


    Phenotypic plasticity has long been a focus of research, but the mechanisms of its evolution remain controversial. Many amphibian species exhibit a similar plastic response in metamorphic timing in response to multiple environmental factors; therefore, more than one environmental factor has likely influenced the evolution of plasticity. However, it is unclear whether the plastic responses to different factors have evolved independently. In this study, we examined the relationship between the plastic responses to two experimental factors (water level and food type) in larvae of the salamander Hynobius retardatus, using a cause-specific Cox proportional hazards model on the time to completion of metamorphosis. Larvae from ephemeral ponds metamorphosed earlier than those from permanent ponds when kept at a low water level or fed conspecific larvae instead of larval Chironomidae. This acceleration of metamorphosis depended only on the permanency of the larvae's pond of origin, but not on the conspecific larval density (an indicator of the frequency of cannibalism) in the ponds. The two plastic responses were significantly correlated, indicating that they may evolve correlatively. Once plasticity evolved as an adaptation to habitat desiccation, it might have relatively easily become a response to other ecological factors, such as food type via the pre-existing developmental pathway. © 2012 The Authors. Journal of Evolutionary Biology © 2012 European Society For Evolutionary Biology.

  3. The Functions of Metamorphic Metallothioneins in Zinc and Copper Metabolism (United States)

    Krężel, Artur; Maret, Wolfgang


    Recent discoveries in zinc biology provide a new platform for discussing the primary physiological functions of mammalian metallothioneins (MTs) and their exquisite zinc-dependent regulation. It is now understood that the control of cellular zinc homeostasis includes buffering of Zn2+ ions at picomolar concentrations, extensive subcellular re-distribution of Zn2+, the loading of exocytotic vesicles with zinc species, and the control of Zn2+ ion signalling. In parallel, characteristic features of human MTs became known: their graded affinities for Zn2+ and the redox activity of their thiolate coordination environments. Unlike the single species that structural models of mammalian MTs describe with a set of seven divalent or eight to twelve monovalent metal ions, MTs are metamorphic. In vivo, they exist as many species differing in redox state and load with different metal ions. The functions of mammalian MTs should no longer be considered elusive or enigmatic because it is now evident that the reactivity and coordination dynamics of MTs with Zn2+ and Cu+ match the biological requirements for controlling—binding and delivering—these cellular metal ions, thus completing a 60-year search for their functions. MT represents a unique biological principle for buffering the most competitive essential metal ions Zn2+ and Cu+. How this knowledge translates to the function of other families of MTs awaits further insights into the specifics of how their properties relate to zinc and copper metabolism in other organisms. PMID:28598392

  4. Radiation-Hardened, Substrate-Removed, Metamorphic InGaAs Detector Arrays, Phase I (United States)

    National Aeronautics and Space Administration — High-performance radiation-hardened metamorphic InGaAs imaging arrays sensitive from the ultraviolet (UV) through the short-wavelength infrared (SWIR) will be...

  5. Spatial and temporal relations of the ophiolites and the metamorphic soles along the Tauride belt, Turkey (United States)

    Parlak, Osman; Simsek, Emrah; Ezgi Ozturk, Selena; Simsek, Gokce; Simsek, Tugce; Robertson, Alastair; von Quadt, Albrecht; Köpke, Jürgen; Karaoglan, Fatih


    The Tauride belt ophiolites were generated above an intra-oceanic subduction zone and emplaced in the Late Cretaceous over the Tauride carbonate platform. The Tauride ophiolites are underlain by well-preserved metamorphic soles that have a constant structural position between the ophiolitic mélange, below and harzburgitic mantle tec- tonites, above. The dynamothermal metamorphic soles display a typical inverted metamorphic sequence, grading from amphibolite facies directly beneath the highly sheared harzburgitic tectonite to greenschist facies close to the melange contact. They display variable structural thickness (up to 500 m). The metamorphic soles beneath the Tauride ophiolites are interpreted to relate to the initiation of subduction and emplacement processes. The metamorphic soles are intruded by isolated post-metamorphic diabase dikes, derived from island arc tholeiitic magmas. In some places along the Tauride belt (Koycegiz and Pozanti-Karsanti regions), the contact between the metamorphic sole and the overlying serpentinized harzburgites is characterized by a 1.5-2 m thick zone of sheared serpentinized harzburgitic mantle tectonites, intercalated with amphibolites. These lithologies are cut by thick mafic dikes (7-8 m thick, individually) which postdate intraoceanic metamorphism and high-temperature ductile deformation. This contact is interpreted as an intra-oceanic decoupling surface along which volcanics in the upper levels of the down-going plate were metamorphosed to amphibolite facies and accreted to the base of the hanging wall plate. The geochemistry of the metamorphic sole amphibolites suggests their derivation from different geochemical environments; i.e. seamount-type alkaline basalts, mid-ocean ridge basalt (MORB) and island arc basalts. Zircon and rutile separates from the crustal rocks (gabbro and diabase) and from the metamorphic soles of the Tauride ophiolites have been dated by U-Pb SIMS (Edinburgh University) and LA-MC-ICP-MS (ETH Zurich

  6. Metamorphic zircon formation at the transition from gabbro to eclogite in Trollheimen-Surnadalen, Norwegian Caledonides (United States)

    Beckman, Victoria; Möller, Charlotte; Söderlund, Ulf; Corfu, Fernando; Chamberlain, Kevin


    A transition zone from gabbro to eclogite via coronitic stages has been investigated at Vindøldalen in south central Norway, with the aim of linking reaction textures to metamorphic zircon growth and obtaining a direct U-Pb zircon age of the metamorphic process. Different rocks from the transition zone contain various types of zircon: I) as igneous prismatic grains; II) metamorphic polycrystalline rims and pseudomorphs after baddeleyite, and III) tiny (> 10µm) bead-like zircon grains associated with a) oxidation and b) resorption of Ti-Fe oxides. During progressive transformation from gabbro to eclogite, titanomagnetite (magnetite with ilmenite lamellae) was oxidised to titanohematite (hematite + ilmenite); at advanced stages of recrystallization to eclogite, rutile was produced at the expense of Fe-Ti oxide. Textural relations suggests that the FeTi-oxides were the main source of Zr. Subsolidus liberation of Zr and formation of zircon beads took place by oxidation of titanomagnetite during fluid-assisted metamorphism in undeformed corona gabbro, and by resorption of FeTi-oxide in undeformed and strongly deformed rock domains that were recrystallized to eclogite. Secondary ionization mass spectrometry (SIMS) and Thermal ionization mass spectrometry (TIMS) were used to obtain U-Pb ages of zircon and baddeleyite. Magmatic baddeleyite yields a TIMS age of 1.46 Ga dating igneous crystallisation, whereas the SIMS age for baddeleyite and magmatic zircon from the same gabbro is slightly younger. Bead-type metamorphic zircon from eclogite gives an age of 425±10 Ma (TIMS), and dates directly the metamorphic transition from gabbro to eclogite in the upper basement of the Lower Allochthon in the south-central Scandinavian Caledonides. The metamorphic zircon age does not necessarily date the peak metamorphic temperature, but reflects fluid-induced reactions and oxidation of primary phases.

  7. Low-temperature thermochronologic constraints on cooling and exhumation trends along conjugate margins, within core complexes and eclogite-bearing gneiss domes of the Woodlark rift system of eastern Papua New Guinea (United States)

    Fitzgerald, P. G.; Baldwin, S.; Bermudez, M. A.; Miller, S. R.; Webb, L. E.; Little, T.


    In eastern Papua New Guinea, active sea-floor spreading within the Woodlark Basin has been propagating westward since at least 6 Ma into heterogeneous crust of the Woodlark Rift. The seafloor spreading system divides the northern conjugate margin (Woodlark Rise) from the southern margin (Pocklington Rise). West of the seafloor spreading rift-tip are high-standing extensional gneiss domes and core complexes of the D'Entrecasteaux Islands (DEI). Domes comprise amphibolite and eclogite-facies gneisses, and Pleistocene granitoid intrusions. Flanked by mylonitic shear zone carapaces and normal faults, the domes are juxtaposed against an upper plate that includes ultramafic rocks and gabbro, correlated with the Papuan ultramafic belt. Petrologic and structural evidence from the DEI has been interpreted as evidence for diapiric ascent of the largely felsic domes, with thermo-mechanical modeling proposing (U)HP exhumation in terms of diapiric flow aided by propagating extension, with feedback between the two. Core complexes lacking evidence for diapiric-aided exhumation include the Prevost Range (eastern Normanby Island), Dayman Dome (Papuan Peninsula), and Misima Island (southern conjugate margin). Thermochronology is being applied to understand the thermal and exhumation history, and hence help constrain mechanisms of (U)HP exhumation. AFT and AHe ages from samples near sea-level along conjugate margins and DEI range from ca. 12 Ma to <1 Ma, generally decreasing from east to west, although with some localized variation. Confined track length distributions (CTLD), obtained using 252Cf implantation, generally indicate rapid cooling (means ≥~14 μm), except on Goodenough Island, the western-most and highest-standing dome. On Goodenough Island, samples from the core zone have AFT ages from ~3 - <1 Ma with age decreasing with decreasing elevation. Core zone samples have mean track lengths (7-13 μm) and are positively skewed, whereas samples from shear zones are younger (<1

  8. Geochronological constraints on the metamorphic sole of the Semail ophiolite in the United Arab Emirates

    Directory of Open Access Journals (Sweden)

    Nick M.W. Roberts


    Full Text Available The Semail ophiolite of Oman and the United Arab Emirates (UAE provides the best preserved large slice of oceanic lithosphere exposed on the continental crust, and offers unique opportunities to study processes of ocean crust formation, subduction initiation and obduction. Metamorphic rocks exposed in the eastern UAE have traditionally been interpreted as a metamorphic sole to the Semail ophiolite. However, there has been some debate over the possibility that the exposures contain components of older Arabian continental crust. To help answer this question, presented here are new zircon and rutile U-Pb geochronological data from various units of the metamorphic rocks. Zircon was absent in most samples. Those that yielded zircon and rutile provide dominant single age populations that are 95–93 Ma, partially overlapping with the known age of oceanic crust formation (96.5–94.5 Ma, and partially overlapping with cooling ages of the metamorphic rocks (95–90 Ma. The data are interpreted as dating high-grade metamorphism during subduction burial of the sediments into hot mantle lithosphere, and rapid cooling during their subsequent exhumation. A few discordant zircon ages, interpreted as late Neoproterozoic and younger, represent minor detrital input from the continent. No evidence is found in favour of the existence of older Arabian continental crust within the metamorphic rocks of the UAE.

  9. Timing and duration of ultra-high temperature metamorphism in sapphirine-bearing metapelite granulite from Kodaikanal, Madurai block, South India: constraints from mineral chemistry and U-Th - total Pb EPMA age of monazite

    International Nuclear Information System (INIS)

    Bhadra, Subhadip


    The southern part of Peninsular India, popularly known as the Southern Granulite Terrane (SGT) witnessed a pervasive granulite faces metamorphism, ductile shearing and widespread migmatization during Pan-African orogeny, which marks the final assembly of the Gondwanaland during Cambrian (ca 500 Mu). The tectonic evolution of SGT, irrespective of its Gondwana connection, is far-reaching due to occurrences of ultra-high temperature (UHT) granulites in different parts of the SGT. In the present study, dynamics of melting and temporal evolution of sapphirine-bearing metapelite granulite, hosted within the Kodaikanal charnockite massif, during syn - to post - UHT metamorphic conditions are examined. The onset of UHT metamorphism in the rock is marked by the growth of Al-rich orthopyroxene (Al 2 O 3 ∼8 wt%) porphyroblast, sapphirine-cordierite symplectite via biotite dehydration melting. Embayment of orthopyroxene porphyroblast and accumulation of melt, now preserved as mesoperthites, in the pressure shadow region around the porphyroblast attest to syn-tectonic melting and crystallization. Monazites of varying sizes (40 to 100 mm) occur pervasively, either as inclusion in peritectic phases or in the biotite-mesoperthite rich matrix. Diagnostic chemical variation diagram, such as 4 (REE + Y + P) versus 4 (Th + U + Si), (Si + Y + REE) versus (Ca + P) suggests that the core and rims domains are linked by dominantly huttonitic (Th 4+ - Si 4+ = REE 3+ P 5+ ) and cheralite (Th 4+ + Ca 2+ = 2 REE 4+ ) substitutions. An increase in partitioning of Th towards the rim is also accompanied with a decrease in La/Sm ratio towards the rim. This together with core to rim chemical variation in monazite attests to monazite growth (core) and overgrowth (rim) during peak UHT metamorphism and subsequent cooling. U - Th - total Pb monazite ages constrain the timing of dehydration melting as well as peak UHT metamorphism at - 560 Ma and post-peak cooling at ∼510 Ma. This establishes a time

  10. The Chinese Continental Drilling Program: Geochemical and Isotopic (O, Sr, Nd, Pb), Investigations on a Vertical Sequence of UHP metamorphism (United States)

    Hoefs, J.; Xiao, Y.; Zhang, Z.; Romer, R. L.


    Various UHP metamorphic rocks - orthogneiss, paragneiss, eclogite, amphibolite, ultra-mafic rocks, and rare schist and quartzite - have been drilled within the main hole of the Chinese Continental Drilling Program (CCSD) in Donghai, Sulu. Petrographic studies indicate that all the rocks have been subjected to UHP metamorphism. R-mode factor analysis vs. depth, combined with rock associations and lithologies, indicate that the 2050-m-thick slab can be divided into 6 units in order of increasing depth. Geochemical characteristics of eclogites from different units suggest that their protoliths may be of diverse origins: eclogites from unit 1(0-530m) are probably of cumulate origin being similar to Bixiling and Maowu in Dabie Shan; the protolith of the eclogite from unit 2 (530-600m) is a Fe-Ti-rich gabbroic rock-body, whereas that of the eclogite within ultramafic rocks from unit 3 (600-690m) is of mantle origin; eclogites fom unit 4 (690-1160m) and unit 6 (1600-2050m) that interlayered with paragneiss are metamorphic supracrustal rocks. Geochemical characteristics of orthogneiss (unit 5, 1160-1600m) and paragneiss suggest that their protoliths are probably of granitic and of supracrustal sedimentary origins, respectively. Oxygen isotope data indicate that eclogites and gneiss from depths above 1600m of the main hole have depleted bulk d18O values of -5.3 to 4.5%, indicating significant meteoric water/rock interaction; by contrast, samples from depths between 1600-2050m show bulk d18O values greater than 5.8%, without any indication of a meteoric water/rock interaction. This suggests an "in situ" origin and structural coherence throughout subduction and exhumation. The lowest d18O values occur at depths of 1100-1200m, which corresponds to the boundary between eclogites and the about 400m-thick ortho- (granitic) gneiss layer (boundary between unit 4 and unit 5; this implies that the intrusion of the granitic body could be a heat source for initiating meteoric water

  11. Physiological effects and cellular responses of metamorphic larvae and juveniles of sea urchin exposed to ionic and nanoparticulate silver. (United States)

    Magesky, Adriano; Ribeiro, Ciro A Oliveiro; Pelletier, Émilien


    The widespread use of silver nanoparticles (AgNPs) would likely result in their discharge into wastewater and inevitable release in densely populated coastal areas. It is known that AgNPs can cause harmful effects to marine fauna, but how they affect development stages is still an open question. In order to understand in details how polymer-coated AgNPs (PAAm-AgNPs) (from 0.19 to 4.64mM as Ag) can affect critical stages of marine invertebrate development, metamorphic larvae and juveniles of sea urchins were used as biological models. Multidimensional scaling (MDS) approach based on Bray-Curtis similarity matrix with PERMANOVA showed organisms in a multivariate space undergoing through different physiological conditions as a function of time, chemical forms of silver, nominal concentrations, and presence or absence of food. Sublethal effects such as lethargy, oedema and immobility mainly characterized PAAm-AgNPs effects with juveniles and postlarvae, whereas necrosis and death arose in Ag(+) conditions in short-term tests. Chronically exposed metamorphic larvae had their morphogenic processes interrupted by PAAm-AgNPs and a high mortality rate was observed in recovery period. On the contrary, Ag(+) ions caused progressive mortality during exposure, but a quick recovery in uncontaminated seawater was observed. By means of fluorescent markers we showed that nanosilver could be transferred between consecutive stages (swimming larvae and postlarvae) and highlighted how important is food to enhance PAAm-AgNPs uptake. Using TEM we observed that unfed juveniles had nanosilver aggregates mostly restricted to their coelomic sinuses, while metamorphic larvae already had nano-contamination overspread in different tissues and blastocoel. Our main hypothesis for nanotoxicity of PAAM-AgNPs relies on the slow dissolution of nano-core over time, but in this study the effects of particulate silver form itself are also evoked. Main mechanisms governing tissular and cellular responses

  12. Ice Cores (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Records of past temperature, precipitation, atmospheric trace gases, and other aspects of climate and environment derived from ice cores drilled on glaciers and ice...

  13. Core BPEL

    DEFF Research Database (Denmark)

    Hallwyl, Tim; Højsgaard, Espen

    extensions. Combined with the fact that the language definition does not provide a formal semantics, it is an arduous task to work formally with the language (e.g. to give an implementation). In this paper we identify a core subset of the language, called Core BPEL, which has fewer and simpler constructs......, does not allow omissions, and does not contain ignorable elements. We do so by identifying syntactic sugar, including default values, and ignorable elements in WS-BPEL. The analysis results in a translation from the full language to the core subset. Thus, we reduce the effort needed for working...... formally with WS-BPEL, as one, without loss of generality, need only consider the much simpler Core BPEL. This report may also be viewed as an addendum to the WS-BPEL standard specification, which clarifies the WS-BPEL syntax and presents the essential elements of the language in a more concise way...

  14. Core mechanics and configuration behavior of advanced LMFBR core restraint concepts

    International Nuclear Information System (INIS)

    Fox, J.N.; Wei, B.C.


    Core restraint systems in LMFBRs maintain control of core mechanics and configuration behavior. Core restraint design is complex due to the close spacing between adjacent components, flux and temperature gradients, and irradiation-induced material property effects. Since the core assemblies interact with each other and transmit loads directly to the core restraint structural members, the core assemblies themselves are an integral part of the core restraint system. This paper presents an assessment of several advanced core restraint system and core assembly concepts relative to the expected performance of currently accepted designs. A recommended order for the development of the advanced concepts is also presented

  15. Metamorphic crystallization kinetics quantified through space and time (United States)

    Kelly, E. D.; Carlson, W. D.; Ketcham, R. A.


    Numerical simulations of diffusion-controlled nucleation and growth of garnet porphyroblasts in regionally metamorphosed rocks constrain values for interfacial energy and rates of nucleation and Al intergranular diffusion, quantities that exert a strong control on the sizes and disposition of porphyroblasts in most metamorphic rocks. During simulation of a reaction, product crystals consume a rate-limiting component (Al) and gradients in Al concentration in the intergranular fluid develop between the product and reactant crystals. Low Al concentrations surrounding product crystals (low reaction affinity) reduce nucleation probability, creating a tendency toward spatial ordering of crystal centers in homogeneous portions of a rock. Also, as Al depletion zones impinge, crystals compete for Al, resulting in a tendency toward smaller sizes for neighboring crystals and larger sizes for those that grow in isolation. These phenomena produce distinctive textural effects that allow the simulations to be constrained by measurements of the sizes and locations of porphyroblasts in natural samples. The 13 rocks analyzed in this study were collected from 7 localities exhibiting a diverse range of crystallization conditions. In the simulations, unknown kinetic parameters governing nucleation and intergranular diffusion were adjusted iteratively to achieve fits between simulated and natural porphyroblastic textures. Model fits were assessed primarily from textural characteristics precisely measured by high-resolution X-ray computed tomography. The range of interfacial energies obtained for heterogeneous nucleation is 0.007-0.118 J/m2 for the sample suite, assuming shape factors in the range 0.1-1.0. Nucleation rates change through space and time due to growth and impingement of Al depletion zones. In some modeled rocks, the actual (whole-rock) rate rises steeply, achieves a steady state, and then falls rapidly as reactants are consumed; in others, the steady-state is not achieved

  16. Histamine is a modulator of metamorphic competence in Strongylocentrotus purpuratus (Echinodermata: Echinoidea

    Directory of Open Access Journals (Sweden)

    Sutherby Josh


    Full Text Available Abstract Background A metamorphic life-history is present in the majority of animal phyla. This developmental mode is particularly prominent among marine invertebrates with a bentho-planktonic life cycle, where a pelagic larval form transforms into a benthic adult. Metamorphic competence (the stage at which a larva is capable to undergo the metamorphic transformation and settlement is an important adaptation both ecologically and physiologically. The competence period maintains the larval state until suitable settlement sites are encountered, at which point the larvae settle in response to settlement cues. The mechanistic basis for metamorphosis (the morphogenetic transition from a larva to a juvenile including settlement, i.e. the molecular and cellular processes underlying metamorphosis in marine invertebrate species, is poorly understood. Histamine (HA, a neurotransmitter used for various physiological and developmental functions among animals, has a critical role in sea urchin fertilization and in the induction of metamorphosis. Here we test the premise that HA functions as a developmental modulator of metamorphic competence in the sea urchin Strongylocentrotus purpuratus. Results Our results provide strong evidence that HA leads to the acquisition of metamorphic competence in S. purpuratus larvae. Pharmacological analysis of several HA receptor antagonists and an inhibitor of HA synthesis indicates a function of HA in metamorphic competence as well as programmed cell death (PCD during arm retraction. Furthermore we identified an extensive network of histaminergic neurons in pre-metamorphic and metamorphically competent larvae. Analysis of this network throughout larval development indicates that the maturation of specific neuronal clusters correlates with the acquisition of metamorphic competence. Moreover, histamine receptor antagonist treatment leads to the induction of caspase mediated apoptosis in competent larvae. Conclusions We

  17. Structural, metamorphic and geochronological insights on the Variscan evolution of the Alpine basement in the Belledonne Massif (France) (United States)

    Fréville, Kévin; Trap, Pierre; Faure, Michel; Melleton, Jérémie; Li, Xian-Hua; Lin, Wei; Blein, Olivier; Bruguier, Olivier; Poujol, Marc


    A structural and petrochronological study was carried out in the southern part of the Belledonne crystalline massif. A first tectonometamorphic event, Dx, corresponds to the eastward thrusting of the Chamrousse ophiolitic complex characterized by a low-temperature-moderate-pressure metamorphism reaching 0.535 ± 0.045 GPa and 427.5 ± 17.5 °C. A subsequent D1 deformation is defined by a penetrative S1 foliation that mostly dips toward the west and displays an E-W- to NE-SW-trending mineral and stretching lineation L1. D1 is associated with a top-to-the east shearing and is responsible for the crustal thickening accommodated by the eastward nappe stacking and the emplacement of the Chamrousse ophiolitic complex upon the Rioupéroux-Livet unit. This event is characterized by an amphibolite facies metamorphism (0.58 GPa ± 0.06; 608 ± 14 °C) that attains partial melting at the base of the nappe pile (0.78 ± 0.07 GPa; 680.5 ± 11.5 °C). LA-ICP-MS U-Pb dating of monazite grains from the mica schists of the Rioupéroux-Livet unit constrain the age of D1 to 337 ± 7 Ma. The D2 tectono-metamorphic event is characterized by NE-SW trending, upright to NE-verging synfolial folding. Folding associated with D2 is pervasively developed in all lithotectonic units with the development of a steeply-dipping S2 foliation. In particular, D2 involves the uppermost weakly metamorphosed Taillefer unit. LA-ICP-MS U-Pb dating performed on detrital zircon grains shows that the Taillefer conglomerates was deposited during the Visean. A zircon SIMS U-Pb age of 352 ± 1 Ma from a plagioglase-rich leucocratic sill of the Rioupéroux-Livet unit is interpreted as the age of magmatic emplacement. Our results suggest that the D2 event took place between 330 Ma and 310 Ma. We propose a new interpretation of the tectonometamorphic evolution of the southern part of the Belledonne massif, focusing on the Middle Carboniferous stages of the Variscan orogeny.

  18. The Amphibole-Bearing Chondrite Meteorite LAP04840: Metamorphism and `Tectonics' in a Hydrous Asteroid (United States)

    Treiman, A. H.; McCanta, M. C.; Essene, E. J.


    LAP04840 is an R-chondrite found in Antarctica, and is unique among meteorites in containing abundant amphibole and biotite. Its chondrules (>500 μm diam) sit in a granoblastic matrix of grains ~20 μm across. Amphibole and biotite grains are anhedral to subhedral, to ~100 μm, and concentrated in chondrules. Commonly, they fit among the olivine and opx grains in regions that would (in anhydrous chondrules) have been occupied by cpx, mesostasis, or glass. Minerals are unzoned, and have constant compositions: olivine Fo62Fa38, Opx En60Wo01, plagioclase An07Ab90, magnesio-hornblende, (Ca1.52Na0.81K0.44) (Mg3.60Fe1.27Mn0.01Ti0.04Cr0.08) (Si6.95Al1.02Fe0.03) O22 (OH1.94?F0.05Cl0.01), sodian phlogopite (low Ti, F, Cl), magnetite (Mt63Chr28Sp05Usp04) and Fe-Ni sulfides. This assemblage is consistent with amphibolite facies equilibrium. Amph-plg thermometry (Holland &Blundy, 1994) gives 675°C, which is consistent with limits of ~600metamorphism are simple. After accretion in the early solar nebula, a chondritic asteroid is heated principally by decay of ^{26}Al (Ghosh et al., 2006) in a single prograde event. An asteroid in the inner belt (<~3AU) would accrete little ice, would be dry, and could be heated to (and beyond) 950°C (Hutchison, 2004). The R chondrites fit nicely here; all but LAP are dry and contain strongly metamorphosed clasts (but no melt rocks). Depending on bulk composition, heating can continue to and beyond the basalt solidus, with core formation and widespread melting and differentiation. An asteroid in the outer belt would accrete abundant ice, which would dilute ^{26}Al and sink much of its heat in melting and vaporization even cores of large asteroids (100+ km radius) would barely reach 675

  19. Pressure-temperature evolution of Neoproterozoic metamorphism in the Welayati Formation (Kabul Block), Afghanistan (United States)

    Collett, Stephen; Faryad, Shah Wali


    The Welayati Formation, consisting of alternating layers of mica-schist and quartzite with lenses of amphibolite, unconformably overlies the Neoarchean Sherdarwaza Formation of the Kabul Block that underwent Paleoproterozoic granulite-facies and Neoproterozoic amphibolite-facies metamorphic events. To analyze metamorphic history of the Welayati Formation and its relations to the underlying Sherdarwaza Formation, petrographic study and pressure-temperature (P-T) pseudosection modeling were applied to staurolite- and kyanite-bearing mica-schists, which crop out to the south of Kabul City. Prograde metamorphism, identified by inclusion trails and chemical zonation in garnet from the micaschists indicates that the rocks underwent burial from around 6.2 kbar at 525 °C to maximum pressure conditions of around 9.5 kbar at temperatures of around 650 °C. Decompression from peak pressures under isothermal or moderate heating conditions are indicated by formation of biotite and plagioclase porphyroblasts which cross-cut and overgrow the dominant foliation. The lack of sillimanite and/or andalusite suggests that cooling and further decompression occurred in the kyanite stability field. The results of this study indicate a single amphibolite-facies metamorphism that based on P-T conditions and age dating correlates well with the Neoproterozoic metamorphism in the underlying Sherdarwaza Formation. The rocks lack any paragenetic evidence for a preceding granulite-facies overprint or subsequent Paleozoic metamorphism. Owing to the position of the Kabul Block, within the India-Eurasia collision zone, partial replacement of the amphibolite-facies minerals in the micaschist could, in addition to retrogression of the Neoproterozoic metamorphism, relate to deformation associated with the Alpine orogeny.

  20. Structure, metamorphism, and geochronology of the Cosmos Hills and Ruby Ridge, Brooks Range schist belt, Alaska (United States)

    Christiansen, Peter B.; Snee, Lawrence W.


    The boundary of the internal zones of the Brooks Range orogenic belt (the schist belt) is a fault contact that dips toward the hinterland (the Yukon-Koyukuk province). This fault, here referred to as the Cosmos Hills fault zone, juxtaposes oceanic rocks and unmetamorphosed sedimentary rocks structurally above blueschist-to-greenschist facies metamorphic rocks of the schist belt. Near the fault contact, schist belt rocks are increasingly affected by a prominent, subhorizontal transposition foliation that is locally mylonitic in the fault zone. Structural and petrologic observations combined with 40Ar/39Ar incremental-release geochronology give evidence for a polyphase metamorphic and deformational history beginning in the Middle Jurassic and continuing until the Late Cretaceous. Our 40Ar/39Ar cooling age for Jurassic metamorphism is consistent with stratigraphic and other evidence for the onset of Brooks Range orogenesis. Jurassic metamorphism is nearly everywhere overprinted by a regional greenschist-facies event dated at 130–125 Ma. Near the contact with the Cosmos Hills fault zone, the schist belt is increasingly affected by a younger greenschist metamorphism that is texturally related to a prominent foliation that folds and transposes an older fabric. The 40Ar/39Ar results on phengite and fuchsite that define this younger fabric give recrystallization ages ranging from 103 to less than 90 Ma. We conclude that metamorphism that formed the transposition fabric peaked around 100 Ma and may have continued until well after 90 Ma. This age for greenschist metamorphism is broadly synchronous with the depositional age of locally derived, shallow-marine clastic sedimentary strata in the hanging wall of the fault zone and thus substantiates the interpretation that the fault zone accommodated extension in the Late Cretaceous. This extension unroofed and exhumed the schist belt during relative subsidence of the Yukon-Koyukuk province.

  1. Saturn-like charge-transfer complexes Li₄&B₃₆, Li₅&B₃₆⁺, and Li₆&B₃₆²⁺: exohedral metalloborospherenes with a perfect cage-like B₃₆⁴⁻ core. (United States)

    Tian, Wen-Juan; Chen, Qiang; Li, Hai-Ru; Yan, Miao; Mu, Yue-Wen; Lu, Hai-Gang; Zhai, Hua-Jin; Li, Si-Dian


    Based on extensive first-principles theory calculations, we present the possibility of construction of the Saturn-like charge-transfer complexes Li4&B36 (2), Li5&B36(+) (3), and Li6&B36(2+) (4) all of which contain a perfect cage-like B36(4-) (1) core composed of twelve interwoven boron double chains with a σ + π double delocalization bonding pattern, extending the Bn(q) borospherene family from n = 38-42 to n = 36 with the highest symmetry of T(h).

  2. Matrix metalloproteinase-10/TIMP-2 structure and analyses define conserved core interactions and diverse exosite interactions in MMP/TIMP complexes.

    Directory of Open Access Journals (Sweden)

    Jyotica Batra

    Full Text Available Matrix metalloproteinases (MMPs play central roles in vertebrate tissue development, remodeling, and repair. The endogenous tissue inhibitors of metalloproteinases (TIMPs regulate proteolytic activity by binding tightly to the MMP active site. While each of the four TIMPs can inhibit most MMPs, binding data reveal tremendous heterogeneity in affinities of different TIMP/MMP pairs, and the structural features that differentiate stronger from weaker complexes are poorly understood. Here we report the crystal structure of the comparatively weakly bound human MMP-10/TIMP-2 complex at 2.1 Å resolution. Comparison with previously reported structures of MMP-3/TIMP-1, MT1-MMP/TIMP-2, MMP-13/TIMP-2, and MMP-10/TIMP-1 complexes offers insights into the structural basis of binding selectivity. Our analyses identify a group of highly conserved contacts at the heart of MMP/TIMP complexes that define the conserved mechanism of inhibition, as well as a second category of diverse adventitious contacts at the periphery of the interfaces. The AB loop of the TIMP N-terminal domain and the contact loops of the TIMP C-terminal domain form highly variable peripheral contacts that can be considered as separate exosite interactions. In some complexes these exosite contacts are extensive, while in other complexes the AB loop or C-terminal domain contacts are greatly reduced and appear to contribute little to complex stability. Our data suggest that exosite interactions can enhance MMP/TIMP binding, although in the relatively weakly bound MMP-10/TIMP-2 complex they are not well optimized to do so. Formation of highly variable exosite interactions may provide a general mechanism by which TIMPs are fine-tuned for distinct regulatory roles in biology.

  3. Matrix metalloproteinase-10/TIMP-2 structure and analyses define conserved core interactions and diverse exosite interactions in MMP/TIMP complexes. (United States)

    Batra, Jyotica; Soares, Alexei S; Mehner, Christine; Radisky, Evette S


    Matrix metalloproteinases (MMPs) play central roles in vertebrate tissue development, remodeling, and repair. The endogenous tissue inhibitors of metalloproteinases (TIMPs) regulate proteolytic activity by binding tightly to the MMP active site. While each of the four TIMPs can inhibit most MMPs, binding data reveal tremendous heterogeneity in affinities of different TIMP/MMP pairs, and the structural features that differentiate stronger from weaker complexes are poorly understood. Here we report the crystal structure of the comparatively weakly bound human MMP-10/TIMP-2 complex at 2.1 Å resolution. Comparison with previously reported structures of MMP-3/TIMP-1, MT1-MMP/TIMP-2, MMP-13/TIMP-2, and MMP-10/TIMP-1 complexes offers insights into the structural basis of binding selectivity. Our analyses identify a group of highly conserved contacts at the heart of MMP/TIMP complexes that define the conserved mechanism of inhibition, as well as a second category of diverse adventitious contacts at the periphery of the interfaces. The AB loop of the TIMP N-terminal domain and the contact loops of the TIMP C-terminal domain form highly variable peripheral contacts that can be considered as separate exosite interactions. In some complexes these exosite contacts are extensive, while in other complexes the AB loop or C-terminal domain contacts are greatly reduced and appear to contribute little to complex stability. Our data suggest that exosite interactions can enhance MMP/TIMP binding, although in the relatively weakly bound MMP-10/TIMP-2 complex they are not well optimized to do so. Formation of highly variable exosite interactions may provide a general mechanism by which TIMPs are fine-tuned for distinct regulatory roles in biology.

  4. Striatins Contain a Noncanonical Coiled Coil That Binds Protein Phosphatase 2A A Subunit to Form a 2:2 Heterotetrameric Core of Striatin-interacting Phosphatase and Kinase (STRIPAK) Complex* (United States)

    Chen, Cuicui; Shi, Zhubing; Zhang, Wenqing; Chen, Min; He, Feng; Zhang, Zhenzhen; Wang, Yicui; Feng, Miao; Wang, Wenjia; Zhao, Yun; Brown, Jerry H.; Jiao, Shi; Zhou, Zhaocai


    The protein phosphatase 2A (PP2A) and kinases such as germinal center kinase III (GCKIII) can interact with striatins to form a supramolecular complex called striatin-interacting phosphatase and kinase (STRIPAK) complex. Despite the fact that the STRIPAK complex regulates multiple cellular events, it remains only partially understood how this complex itself is assembled and regulated for differential biological functions. Our recent work revealed the activation mechanism of GCKIIIs by MO25, as well as how GCKIIIs heterodimerize with CCM3, a molecular bridge between GCKIII and striatins. Here we dissect the structural features of the coiled coil domain of striatin 3, a novel type of PP2A regulatory subunit that functions as a scaffold for the assembly of the STRIPAK complex. We have determined the crystal structure of a selenomethionine-labeled striatin 3 coiled coil domain, which shows it to assume a parallel dimeric but asymmetric conformation containing a large bend. This result combined with a number of biophysical analyses provide evidence that the coiled coil domain of striatin 3 and the PP2A A subunit form a stable core complex with a 2:2 stoichiometry. Structure-based mutational studies reveal that homodimerization of striatin 3 is essential for its interaction with PP2A and therefore assembly of the STRIPAK complex. Wild-type striatin 3 but not the mutants defective in PP2A binding strongly suppresses apoptosis of Jurkat cells induced by the GCKIII kinase MST3, most likely through a mechanism in which striatin recruits PP2A to negatively regulate the activation of MST3. Collectively, our work provides structural insights into the organization of the STRIPAK complex and will facilitate further functional studies. PMID:24550388

  5. The structure of a mixed GluR2 ligand-binding core dimer in complex with (S)-glutamate and the antagonist (S)-NS1209

    DEFF Research Database (Denmark)

    Kasper, Christina; Pickering, Darryl S; Mirza, Osman


    of this novel class of antagonists. We present here the first X-ray structure of a mixed GluR2 ligand-binding core dimer, with the high-affinity antagonist (S)-8-methyl-5-(4-(N,N-dimethylsulfamoyl)phenyl)-6,7,8,9,-tetrahydro-1H-pyrrolo[3,2-h]-isoquinoline-2,3-dione-3-O-(4-hydroxybutyrate-2-yl)oxime [(S)-NS1209......] in one protomer and the endogenous ligand (S)-glutamate in the other. (S)-NS1209 stabilises an even more open conformation of the D1 and D2 domains of the ligand-binding core than that of the apo structure due to steric hindrance. This is the first time ligand-induced hyperextension of the binding...... domains has been observed. (S)-NS1209 adopts a novel binding mode, including hydrogen bonding to Tyr450 and Gly451 of D1. Parts of (S)-NS1209 occupy new areas of the GluR2 ligand-binding cleft, and bind near residues that are not conserved among receptor subtypes. The affinities of (RS)-NS1209 at the Glu...

  6. Coring apparatus

    Energy Technology Data Exchange (ETDEWEB)

    Mount, W.W.


    This invention relates to coring equipment and has special reference to such as are intended to be driven or otherwise inserted into sand or other loose formations to obtain a true sample of the formation. The device includes a plurality of elongated angular members positioned to form an elongated core receptacle between them. A plurality of links are each pivotally mounted at each end on an adjacent member to hold the members in spaced-apart relation in one position. The receptable is driven into the sand, and the members are moved toward one another when they are longitudinally moved with respect to one another to close the receptable. (3 claims)

  7. Calculation of stability of sodic phases in high-pressure metapelites and observation of Sambagawa metamorphic rocks (United States)

    Kouketsu, Y.; Enami, M.


    the garnet of metapelites. These quartz grains are considered to be relicts that were sealed by garnet during the prograde eclogite facies stage. In these metapelites, garnet commonly exhibits composite zoning with a resolved core and overgrown mantle parts with discontinuous chemical trend between them. The core part of the composite zoned garnet usually contains paragonite. These facts suggest that (1) a combination of paragonite and quartz with high residual pressure included in garnet can be used as a useful indicator to verify the evidence for the eclogite facies metamorphism of metapelites, and (2) eclogitic garnet commonly remains as a core of composite zoned grains in metapelites throughout the Besshi region.

  8. The Cedrolina Chromitite, Goiás State, Brazil: A Metamorphic Puzzle

    Directory of Open Access Journals (Sweden)

    Yuri de Melo Portella


    Full Text Available The Cedrolina chromitite body (Goiás-Brazil is concordantly emplaced within talc-chlorite schists that correspond to the poly-metamorphic product of ultramafic rocks inserted in the Pilar de Goiás Greenstone Belt (Central Brazil. The chromite ore displays a nodular structure consisting of rounded and ellipsoidal orbs (up to 1.5 cm in size, often strongly deformed and fractured, immersed in a matrix of silicates (mainly chlorite and talc. Chromite is characterized by high Cr# (0.80–0.86, high Fe2+# (0.70–0.94, and low TiO2 (av. = 0.18 wt % consistent with variation trends of spinels from metamorphic rocks. The chromitite contains a large suite of accessory phases, but only irarsite and laurite are believed to be relicts of the original igneous assemblage, whereas most accessory minerals are thought to be related to hydrothermal fluids that emanated from a nearby felsic intrusion, metamorphism and weathering. Rutile is one of the most abundant accessory minerals described, showing an unusually high Cr2O3 content (up to 39,200 ppm of Cr and commonly forming large anhedral grains (>100 µm that fill fractures (within chromite nodules and in the matrix or contain micro-inclusions of chromite. Using a trace element geothermometer, the rutile crystallization temperature is estimated at 550–600 °C (at 0.4–0.6 GPa, which is in agreement with P and T conditions proposed for the regional greenschist to low amphibolite facies metamorphic peak of the area. Textural, morphological, and compositional evidence confirm that rutile did not crystallize at high temperatures simultaneously with the host chromitite, but as a secondary metamorphic mineral. Rutile may have been formed as a metamorphic overgrowth product following deformation and regional metamorphic events, filling fractures and incorporating chromite fragments. High Cr contents in rutile very likely are due to Cr remobilization from Cr-spinel during metamorphism and suggest that Ti was

  9. Clumped isotope thermometry of calcite and dolomite in a contact metamorphic environment (United States)

    Lloyd, Max K.; Eiler, John M.; Nabelek, Peter I.


    Clumped isotope compositions of slowly-cooled calcite and dolomite marbles record apparent equilibrium temperatures of roughly 150-200 °C and 300-350 °C, respectively. Because clumped isotope compositions are sensitive to the details of T-t path within these intervals, measurements of the Δ47 values of coexisting calcite and dolomite can place new constraints on thermal history of low-grade metamorphic rocks over a large portion of the upper crust (from ∼5 to ∼15 km depth). We studied the clumped isotope geochemistry of coexisting calcite and dolomite in marbles from the Notch Peak contact metamorphic aureole, Utah. Here, flat-lying limestones were intruded by a pluton, producing a regular, zoned metamorphic aureole. Calcite Δ47 temperatures are uniform, 156 ± 12 °C (2σ s.e.), across rocks varying from high-grade marbles that exceeded 500 °C to nominally unmetamorphosed limestones >5 km from the intrusion. This result appears to require that the temperature far from the pluton was close to this value; an ambient temperature just 20 °C lower would not have permitted substantial re-equilibration, and should have preserved depositional or early diagenetic Δ47 values several km from the pluton. Combining this result with depth constraints from overlying strata suggests the country rock here had an average regional geotherm of 22.3-27.4 °C/km from the late Jurassic Period until at least the middle Paleogene Period. Dolomite Δ47 in all samples above the talc + tremolite-in isograd record apparent equilibrium temperatures of 328-12+13 °C (1σ s.e.), consistent with the apparent equilibrium blocking temperature we expect for cooling from peak metamorphic conditions. At greater distances, dolomite Δ47 records temperatures of peak (anchi)metamorphism or pre-metamorphic diagenetic conditions. The interface between these domains is the location of the 330 °C isotherm associated with intrusion. Multiple-phase clumped isotope measurements are complemented by

  10. Development of III-Sb metamorphic DBR membranes on InP for vertical cavity laser applications (United States)

    Addamane, S. J.; Mansoori, A.; Renteria, E. J.; Dawson, N.; Shima, D. M.; Rotter, T. J.; Hains, C. P.; Dawson, L. R.; Balakrishnan, G.


    Sb-based metamorphic DBR membranes are developed for InP-based vertical cavity laser applications. The reflectivity of the metamorphic DBR membrane is compared to the reflectivity of a lattice-matched DBR to characterize the optical quality of the DBR membrane. The metamorphic interface between InP and the III-antimonides is found to degrade the reflectivity of the DBR. Therefore, the growth temperature for the metamorphic DBR is optimized in order to obtain highly reflective (>99.8%) III-Sb thin-film membranes.

  11. Sapphirine granulites from Panasapattu, Eastern Ghats belt, India: Ultrahigh-temperature metamorphism in a Proterozoic convergent plate margin

    Directory of Open Access Journals (Sweden)

    C.V. Dharma Rao


    Full Text Available We report equilibrium sapphirine + quartz assemblage in biotite–orthopyroxene–garnet granulites from a new locality in Panasapattu of Paderu region in the Eastern Ghats granulite belt, which provide new evidence for ultrahigh-temperature (UHT metamorphism at 1030–1050 °C and 10 kbar in this region. The development of migmatitic texture, stabilization of the garnet–orthopyroxene–plagioclase–K-feldspar association, prograde biotite inclusions within garnet and sapphirine as well as sapphirine and cordierite inclusions within garnet in these granulites indicate that the observed peak assemblages probably formed during prograde dehydration melting of a Bt–Sill–Qtz assemblage, and constrain the prograde stage of the p–T path. The core domains of orthopyroxene porphyroblasts have up to w(Al2O3 9.6%, which suggest that the temperatures reached up to 1150 °C suggesting extreme crustal metamorphism. These conditions were also confirmed by the garnet–orthopyroxene thermobarometery, which yields a p–T range of 1012–960 °C and 9.4 kbar. The p–T phase topologies computed using isochemical sections calculated in the model system Na2O–CaO–K2O–FeO–MgO–Al2O3–SiO2–H2O (NCKFMASH for metapelites, garnet-free sapphirine granulites and garnet-bearing sapphirine granulites match the melt-bearing assemblages observed in these rocks. Isochemical sections constructed in the NCKFMASH system for an average sub-aluminous metapelite bulk composition, and contoured for modal proportions of melt and garnet, as well as for the compositional isopleths of garnet, predict phase and reaction relations that are consistent with those observed in the rocks. Garnet and orthopyroxene contain Ti-rich phlogopite inclusions, suggesting formation by prograde melting reactions at the expense of phlogopite during ultrahigh-temperature conditions. These p–T results underestimate ‘peak’ conditions, in part as a result of the modification

  12. Evidence for Complex P-T-t Histories in Subduction Zone Rocks: A Case Study from Syros, Greece (United States)

    Gorce, J. S.; Kendall, J.; Caddick, M. J.; Baxter, E. F.


    Numerical models predict that material can move freely at the interface between the subducting slab and the overlying mantle wedge (mélange zone) independent of the motion of the subducting slab (i.e. Cloos 1982, Gerya et al. 2002). This is possible because the mélange zone consists of rigid blocks of metagabbroic and metabasic material suspended in a strongly sheared matrix of serpentinite, talc, and chlorite. The implication of this is that blocks of subducted material exposed in outcrops at the earth's surface could experience complex Pressure-Temperature-time (P-T-t) paths due to the cycling and recycling of subducted material within the mélange zone. Such behavior can affect the expulsion and retention of fluid during metamorphism and thus affect elemental cycles, geodynamics, mineral phase equilibra and mass transport of materials in the mélange zone depending on the physical properties and location of the blocks. The island of Syros, Greece preserves rocks that experienced blueschist-eclogite grade metamorphism during the subduction of the Pindos Oceanic Unit and thus provides a natural laboratory for investigating the evolution of subducted lithologies. Complex compositional zoning in a garnet-bearing quartz mica schist indicates that garnet crystals grew in two distinct stages. The presence of distinct cores and rims is interpreted as the result of a complex P-T-t history. Through the use of thermodynamic modeling, we calculate that the core of the garnet equilibrated at 485oC and 22.5 kbars. The edge of the first growth zone is predicted to stop growing at approximately 530oC and 20.5 kbars. We calculate that the rim began to grow at 21.7 kbars and 560oC and that the end of garnet growth occurred at approximately 16 kbars and 500oC. Sm/Nd garnet geochronology was used to date the cores of the garnets at 47 ± 3 Ma, with preliminary results suggesting that the rims grew at a significantly younger age. These data support the hypothesis that the cycling

  13. Cretaceous high-pressure metamorphic belts of the Central Pontides (northern Turkey): pre-collisional Pacific-type accretionary continental growth of Laurasian Margin (United States)

    Aygul, Mesut; Okay, Aral I.; Oberhaensli, Roland; Sudo, Masafumi


    Cretaceous blueschist-facies metamorphic rocks crop out widely in the central part of the Pontides, an east-west trending mountain belt in northern Turkey. They comprise an accretionary wedge along to the southern Laurasian active continental margin and predate the opening of Black Sea basin. From North to South, the wedge consists of a low grade metaflysch unit with marble, Na-amphibole-bearing metabasite and serpentinite blocks. An extensional shear zone separates the accreted distal terrigenous sediments from HP/LT micaschists and metabasites of oceanic origin, known as Domuzdaǧ Complex. The shear zone reaches up to one km in thickness and consists of tectonic slices of serpentinite, metabasite, marble, phyllite and micaschist with top to the NW sense of shear. The Domuzdaǧ Complex predominantly consists of carbonaceous micaschist and metabasite with serpentinite, and minor metachert, marble and metagabbro. Metabasites consist mainly of epidote-blueschists sometimes with garnet. Fresh lawsonite-blueschists are found as blocks within the shear zone. Peak metamorphic assemblages in the micaschists are chloritoid-glaucophane and garnet-chloritoid-glaucophane-lawsonite in addition to phengite, paragonite, quartz, chlorite and rutile (P: 17 ± 1 Kbar, T: 390-450 °C). To the south, lithologies change slightly, with metabasite and thick, pale marble with few metachert and metapelitic horizons. The degree of metamorphism also changes. The metabasites range from high-pressure upper-greenschist facies with growth of sodic-amphibole to lower greenschist without any HP index mineral, suggesting a general decrease in pressure toward south within the prism. While Domuzdaǧ Complex represents deep-seated underplated oceanic sediments and basalts, the carbonate-rich southern parts can be interpreted as seamounts integrated into the accretionary prism. Ar/Ar dating on phengite separates both from terrigenous and oceanic metasediments give consistent plateau ages of 100 ± 2

  14. Timing and duration of Variscan high-pressure metamorphism in the French Massif Central: A multimethod geochronological study from the Najac Massif (United States)

    Lotout, Caroline; Pitra, Pavel; Poujol, Marc; Anczkiewicz, Robert; Van Den Driessche, Jean


    Accurate dating of eclogite-facies metamorphism is of paramount importance in order to understand the tectonic evolution of an orogen. An eclogite sample from the Najac Massif (French Massif Central, Variscan belt) displays a zircon-bearing garnet-omphacite-amphibole-rutile-quartz peak assemblage. Pseudosection modeling suggests peak pressure conditions of 15-20 kbar, 560-630 °C. Eclogite-facies garnet displays Lu-enriched cores and Sm-rich rims and yields a Lu-Hf age of 382.8 ± 1.0 Ma and a Sm-Nd age of 376.7 ± 3.3 Ma. The ages are interpreted as marking the beginning of the prograde garnet growth during the initial stages of the eclogite-facies metamorphism, and the high-pressure (and temperature) peak reached by the rock, respectively. Zircon grains display chondrite-normalized REE spectra with variably negative, positive or no Eu anomalies and are characterized by either enriched or flat HREE patterns. However, they yield a well constrained in situ LA-ICP-MS U-Pb age of 385.5 ± 2.3 Ma, despite this REE pattern variability. Zr zonation in garnet, Y content in zircon and the diversity of zircon HREE spectra may suggest that zircon crystallized prior to and during incipient garnet growth on the prograde P-T path, recording the initial stages of the eclogite-facies conditions. Consequently, the zircon age of 385.5 ± 2.3 Ma, comparable within error with the Lu-Hf age obtained on garnet, is interpreted as dating the beginning of the eclogite-facies metamorphism. Accordingly, the duration of the prograde part of the eclogite-facies event is estimated at 6.1 ± 4.3 Myr. Subsequent exhumation is constrained by an apatite U-Pb age at 369 ± 13 Ma.

  15. On the Magnitude and Orientation of Stress during Shock Metamorphism: Understanding Peak Ring Formation by Combining Observations and Models. (United States)

    Rae, A.; Poelchau, M.; Collins, G. S.; Timms, N.; Cavosie, A. J.; Lofi, J.; Salge, T.; Riller, U. P.; Ferrière, L.; Grieve, R. A. F.; Osinski, G.; Morgan, J. V.; Expedition 364 Science Party, I. I.


    Shock metamorphism occurs during the earliest moments after impact. The magnitude and orientation of shock leaves recordable signatures in rocks, which spatially vary across an impact structure. Consequently, observations of shock metamorphism can be used to understand deformation and its history within a shock wave, and to examine subsequent deformation during crater modification. IODP-ICDP Expedition 364 recovered nearly 600 m of shocked target rocks from the peak ring of the Chicxulub Crater. Samples from the expedition were used to measure the magnitude and orientation of shock in peak ring materials, and to determine the mechanism of peak-ring emplacement. Here, we present the results of petrographic analyses of the shocked granitic target rocks of the Chicxulub peak ring; using universal-stage optical microscopy, back-scattered electron images, and electron back-scatter diffraction. Deformation microstructures in quartz include planar deformation features (PDFs), feather features (FFs), which are unique to shock conditions, as well as planar fractures and crystal-plastic deformation bands. The assemblage of PDFs in quartz suggest that the peak-ring rocks experienced shock pressures of 15 GPa throughout the recovered drill core, and that the orientation of FFs are consistent with the present-day orientation of the maximum principal stress direction during shock is close to vertical. Numerical impact simulations of the impact event were run to determine the magnitude and orientation of principal stresses during shock and track those orientations throughout crater formation. Our results are remarkably consistent with the geological data, and accurately predict both the shock-pressure magnitudes, and the final near-vertical orientation of the direction of maximum principal stress in the shock wave. Furthermore, analysis of the state of stress throughout the impact event can be used to constrain the timing of fracture and fault orientations observed in the core

  16. Petrogenesis and Tectonic Implications of Paleoproterozoic Metapelitic Rocks in the Archean Kongling Complex from the Northern Yangtze Craton, South China (United States)

    Li, Y.; Zheng, J.; Wang, W.; Xiong, Q.


    The Archean Kongling Complex in the northern Yangtze Craton is an ideal target to investigate the Precambrian accretion and evolution of continental crust in South China. This study aims to unravel the crustal evolution and tectonic setting of the Yangtze Craton during the Paleoproterozoic time, using integrated studies of petrography, zircon U-Pb and Hf isotopes and whole-rock geochemistry of Paleoproterozoic metapelitic rocks in the Kongling Complex. These rocks contain garnet, sillimanite, biotite, plagioclase, minor graphite and ilmenite. Zircons from the samples show nebulous sector-zoning and rim-core structure, suggesting both metamorphic origin and detrital origin with metamorphic overprints. The metamorphic zircons and metamorphic overprints have concordant 207Pb/206Pb age at ~2.0 Ga, while detrital grains yield three distinct concordant-age populations of >2.5 Ga, 2.4-2.2 Ga and 2.2-2.1 Ga. The age patterns indicate that the depositional age of the metasedimentary rocks was 2.1-2.0 Ga. Those 2.2-2.1 Ga detrital zircons with variable ɛHf(t) values (-7.28 to 2.97) suggest the addition of juvenile materials from depleted mantle to the crust during 2.2-2.1 Ga. The 2.4-2.2 Ga zircons have Hf model ages (TDM2) of ~2.6-3.5 Ga and >2.5 Ga zircons have TDM2 ages varying from 2.9 Ga to 3.3 Ga. The new data suggest that the Kongling Complex was originally a Paleoarchean (old up to 3.5 Ga) continental nucleus, which experienced multiple episodes of growth and reworking events at 3.3-3.2 Ga, 2.9 Ga, 2.7-2.6 Ga, 2.4-2.2 Ga and 2.2-2.1 Ga. In combination with available data, the new results in this study suggest a continent-arc-continent evolution model to explain the tectonic evolution of the Yangtze Craton during the Paleoproterozoic time: the western margin of Yangtze Craton was originally an individual continent, which underwent a reworking event during 2.4-2.2 Ga and a crust growth event caused by continent-arc collision during 2.2-2.1 Ga; it subsequently collided

  17. SHRIMP U-Pb zircon dating of Archean core complex formatio and pancratonic strike-slip deformation in the East Pilbara Granite-Greenstone Terrain

    NARCIS (Netherlands)

    Zegers, T.E.; Nelson, D.R.; Wijbrans, J.R.; White, S.H.


    Sensitive high-resolution ion microprobe (SHRIMP) U-Pb dating of zircons from granitic rocks in the East Pilbara Granite-Greenstone Terrain has provided time constraints for main tectonic events in the Shaw Granitoid Complex and has shown that deformation was intricately related to granitoid

  18. The tectonics of the Central Anatolian crystalline complex: a structural, metamorphic and paleomagnetic study


    Lefebvre, C.J.C.


    The Anatolian region is a segment of the Alpine-Himalayan orogen. The rocks presently exposed in Anatolia provide a geological record of the closure history of the Neotethyan Ocean(s) situated between the converging African and Eurasian continents during late Mesozoic – Cenozoic times. The location of the former northern Neo-Tethyan ocean is marked by the presence of an ophiolitic mélange forming the Izmir-Ankara-Erzincan Suture Zone (IAESZ). South of the IAESZ, the Central Anatolian Crystall...

  19. The tectonics of the Central Anatolian crystalline complex: a structural, metamorphic and paleomagnetic study

    NARCIS (Netherlands)

    Lefebvre, C.J.C.


    The Anatolian region is a segment of the Alpine-Himalayan orogen. The rocks presently exposed in Anatolia provide a geological record of the closure history of the Neotethyan Ocean(s) situated between the converging African and Eurasian continents during late Mesozoic – Cenozoic times. The location

  20. Radioactive occurrences in veins and igneous and metamorphic rocks of New Mexico with annotated bibliography

    International Nuclear Information System (INIS)

    McLemore, V.T.


    The primary objectives of this report are to list known radioactive occurrences in veins and igneous and metamorphic rocks in New Mexico, and to provide an annotated bibliography of geologic reports concerning these regions. Only plutonic, metamorphic, vein, and Precambrian quartz-pebble conglomerate uranium deposits are considered in this report; other nonsandstone uranium deposits (such as shale, limestone, phosphorite, coal, evaporative precipitates, and fossil placer deposits) will be considered at a later time. These objectives were achieved through a literature search. Some field examinations of some of the radioactive occurrences have been completed. A table of known radioactive occurrences in veins and igneous and metamorphic rocks was compiled from the literature (Appendix I)


    Directory of Open Access Journals (Sweden)

    Rodrigo Fina Ferreira


    Full Text Available Iron ore exploited in Brazil can be classified into several lithological types which have distinct features. The progress of mining over time leads to scarcity of high grade iron ores, leading to the exploitation of poor, contaminated and compact ores. There is a growing trend of application of process flowsheets involving grinding to promote mineral liberation, essential condition for concentration processes. Several authors have correlated metamorphism processes of banded iron formations to mineralogical features observed on itabirites from the Iron Quadrangle, mainly the crystals size. This paper presents the implications of such variation in defining the mesh of grinding. Mineralogical characterization and grinding, desliming and flotation tests have been carried out with samples from two regions of the Iron Quadrangle subjected to different degrees of metamorphism. It was found a trend of reaching satisfactory liberation degree in coarser size for the itabirite of higher metamorphic degree, which has larger crystals. The flotation tests have confirmed the mineralogical findings.

  2. Origin of pseudotachylite in the lower Witwatersrand Supergroup, Vredefort Dome (South Africa): constraints from metamorphic studies (United States)

    Gibson, R. L.; Reimold, W. U.; Wallmach, T.


    Small, sub-millimetre to centimetre thick, pseudotachylite veins in metapelitic rocks of the lower Witwatersrand Supergroup in the collar of the Vredefort Dome are recrystallized to a biotite±cordierite paragenesis, indicating the attainment of lower amphibolite facies metamorphic conditions ( T ≥ 500°C) following their formation. The veins occur along ubiquitous anastomosing fracture networks displaying millimetre- to centimetre-scale displacements and truncate, and incorporate fragments of, an older, ca. 2.05 Ga, mid-amphibolite facies, peak metamorphic assemblage. The post-pseudotachylite metamorphism is attributed to the same event that caused highly variable annealing of ca. 2.02 Ga shock microdeformation features in rocks across the dome. Together with the disproportionately large volume of pseudotachylite in the rocks relative to that found in tectonic provinces, and the absence of evidence of genetically related large-scale shear or fault zones, this metamorphic evidence suggests an origin for the pseudotachylite related to the 2.02 Ga Vredefort bolide impact event that produced the dome. Possible origins for the pseudotachylite include shock brecciation and melting, post-shock decompression melting, and friction melting associated with the post-impact high-velocity excavation and modification phases of crater formation. The post-pseudotachylite metamorphism is attributed to the combined effects of an elevated pre-impact crustal geotherm (˜25°C/km) related to the waning stages of the 2.05 Ga peak metamorphism, release of elastic strain energy from the impact shock event and contact effects beneath the impact melt body.

  3. MRB3010 is a core component of the MRB1 complex that facilitates an early step of the kinetoplastid RNA editing process

    Czech Academy of Sciences Publication Activity Database

    Ammerman, M. L.; Hashimi, Hassan; Novotná, Lucie; Číčová, Zdeňka; Mcevoy, S. M.; Lukeš, Julius; Read, L. K.


    Roč. 17, č. 5 (2011), 865-877 ISSN 1355-8382 R&D Projects: GA ČR GA204/09/1667; GA MŠk 2B06129; GA MŠk LC07032 Institutional research plan: CEZ:AV0Z60220518 Keywords : RNA editing * trypanosome * MRB1 complex * mitochondria * kinetoplast Subject RIV: EB - Genetics ; Molecular Biology Impact factor: 5.095, year: 2011

  4. Timing and duration of garnet granulite metamorphism in magmatic arc crust, Fiordland, New Zealand (United States)

    Stowell, H.; Tulloch, A.; Zuluaga, C.; Koenig, A.


    Pembroke Granulite from Fiordland, New Zealand provides a window into the mid- to lower crust of magmatic arcs. Garnet Sm-Nd and zircon U-Pb ages constrain the timing and duration of high-P partial melting that produced trondhjemitic high Sr/Y magma. Trace element zoning in large, euhedral garnet is compatible with little post growth modification and supports the interpretation that garnet Sm-Nd ages of 126.1??2.0 and 122.6??2.0. Ma date crystal growth. Integration of the garnet ages with U-Pb zircon ages elucidates a history of intrusion(?) and a protracted period of high-temperature metamorphism and partial melting. The oldest zircon ages of 163 to 150. Ma reflect inheritance or intrusion and a cluster of zircon ages ca. 134. Ma date orthopyroxene-bearing mineral assemblages that may be magmatic or metamorphic in origin. Zircon and garnet ages from unmelted gneiss and garnet reaction zones record garnet granulite facies metamorphism at 128 to 126. Ma. Peritectic garnet and additional zircon ages from trondhjemite veins and garnet reaction zones indicate that garnet growth and partial melting lasted until ca. 123. Ma. Two single fraction garnet ages and young zircon ages suggest continued high-temperature re-equilibration until ca. 95. Ma. Phase diagram sections constrain orthopyroxene assemblages to <0.6 GPa @ 650??C, peak garnet granulite facies metamorphic conditions to 680-815??C @ 1.1-1.4. GPa, and a P-T path with a P increase of???0.5. GPa. These sections are compatible with water contents???0.28wt.%, local dehydration during garnet granulite metamorphism, and <0.3. GPa P increases during garnet growth. Results demonstrate the utility of integrated U-Pb zircon and Sm-Nd garnet ages, and phase diagram sections for understanding the nature, duration, and conditions of deep crustal metamorphism and melting. Geochronologic and thermobarometric data for garnet granulite indicate that thickening of arc crust, which caused high-pressure metamorphism in northern

  5. Age succession of metamorphism, paleovolcanism and granitoid magnetism processes in greenstone belts of Middle Dnieper region (Ukrainian shield)

    International Nuclear Information System (INIS)

    Shcherbak, N.P.; Artemenko, G.V.; Bartnitskij, E.N.; Strueva, O.M.


    Time succession of paleovolcanism, granatoid magmatism and metamorphism process is considered on the basis of geological, petrological and geochronological data obtained using U-Pb isochronous method by accessory zircons. Paleovolcanism process prevailed 3200-3000 billions of years ago, granatoid magmatism-3100-2950 millions of years ago and regional metamorphism-3000-2840 millions of years ago

  6. Uranium deposits in the metamorphic basement of the Rouergue massif. Genesis and extension of related albitization processes

    International Nuclear Information System (INIS)

    Schmitt, J.M.


    Albitization processes in the Rouergue metamorphic basement, probably Permian aged is evidenced. Late development of uranium orebodies occured within albitized zones. The detection of the latter serves as a highly valuable indirect guide for prospecting this type of deposits in a metamorphic basement [fr

  7. Response of zircon to melting and metamorphism in deep arc crust, Fiordland (New Zealand): implications for zircon inheritance in cordilleran granites (United States)

    Bhattacharya, Shrema; Kemp, A. I. S.; Collins, W. J.


    The Cretaceous Mount Daniel Complex (MDC) in northern Fiordland, New Zealand was emplaced as a 50 m-thick dyke and sheet complex into an active shear zone at the base of a Cordilleran magmatic arc. It was emplaced below the 20-25 km-thick, 125.3 ± 1.3 Ma old Western Fiordland Orthogneiss (WFO) and is characterized by metre-scale sheets of sodic, low and high Sr/Y diorites and granites. 119.3 ± 1.2 Ma old, pre-MDC lattice dykes and 117.4 ± 3.1 Ma late-MDC lattice dykes constrain the age of the MDC itself. Most dykes were isoclinally folded as they intruded, but crystallised within this deep-crustal, magma-transfer zone as the terrain cooled and was buried from 25 to 50 km (9-14 kbar), based on published P-T estimated from the surrounding country rocks. Zircon grains formed under these magmatic/granulite facies metamorphic conditions were initially characterized by conservatively assigning zircons with oscillatory zoning as igneous and featureless rims as metamorphic, representing 54% of the analysed grains. Further petrological assignment involved additional parameters such as age, morphology, Th/U ratios, REE patterns and Ti-in-zircon temperature estimates. Using this integrative approach, assignment of analysed grains to metamorphic or igneous groupings improved to 98%. A striking feature of the MDC is that only 2% of all igneous zircon grains reflect emplacement, so that the zircon cargo was almost entirely inherited, even in dioritic magmas. Metamorphic zircons of MDC show a cooler temperature range of 740-640 °C, reflects the moderate ambient temperature of the lower crust during MDC emplacement. The MDC also provides a cautionary tale: in the absence of robust field and microstructural relations, the igneous-zoned zircon population at 122.1 ± 1.3 Ma, derived mostly from inherited zircons of the WFO, would be meaningless in terms of actual magmatic emplacement age of MDC, where the latter is further obscured by younger (ca. 114 Ma) metamorphic overgrowths

  8. Highly fluorescent platinum(II) organometallic complexes of perylene and perylene monoimide, with Pt σ-bonded directly to the perylene core. (United States)

    Lentijo, Sergio; Miguel, Jesús A; Espinet, Pablo


    3-Bromoperylene (BrPer) or N-(2,5-di-tert-butylphenyl)-9-bromo-perylene-3,4-dicarboximide (BrPMI) react with [Pt(PEt(3))(4)] to yield trans-[PtR(PEt(3))(2)Br] (R = Per, 1a; R = PMI, 1b). Neutral and cationic perylenyl complexes containing a Pt(PEt(3))X group have been prepared from 1a,b by substitution of the Br ligand by a variety of other ligands (NCS, CN, NO(3), CN(t)Bu, PyMe). The X-ray structures of trans-[PtR(PEt(3))(2)X] (R = Per, X = NCS (2a); R = PMI, X = NO(3) (4b); R = Per, X = CN(t)Bu (5a)) show that the perylenyl fragment remains nearly planar and is arranged almost orthogonal to the coordination plane: The three molecules appear as individual entities in the solid state, with no π-π stacking of perylenyl rings. Each platinum complex exhibits fluorescence associated to the perylene or PMI fragments with emission quantum yields, in solution at room temperature, in the range 0.30-0.80 and emission lifetimes ∼4 ns, but with significantly different emission maxima, by influence of the X ligands on Pt. The similarity of the overall luminescence spectra of these metalated complexes with the perylene or PMI strongly suggests a perylene-dominated intraligand π-π*emissive state, metal-perturbed by interaction of the platinum fragment mostly via polarization of the Ar-Pt bond.

  9. Paleomagnetism of the Oman Ophiolite: New Results from Oman Drilling Project Cores (United States)

    Horst, A. J.; Till, J. L.; Koornneef, L.; Usui, Y.; Kim, H.; Morris, A.


    The Oman Drilling Project drilled holes at four sites in a transect through the southern massifs of the Samail ophiolite, and recovered 1500 m of igneous and metamorphic rocks. We focus on three sites from the oceanic crustal section including lower layered gabbros (GT1A), the mid-crustal layered to foliated gabbro transition (GT2A), and the shallower transition from sheeted dikes to varitextured gabbros (GT3A). Detailed core descriptions, analyses, and paleomagnetic measurements, were made on D/V Chikyu from July to September 2017 to utilize the core laboratory facilities similar to IODP expeditions. Shipboard measurements included anisotropy of magnetic susceptibility (AMS) and alternating field and thermal demagnetization of 597 discrete samples. Sample demagnetization behavior is varied from each of the cores, with some revealing multiple components of magnetization, and others yielding nearly univectorial data. The interpretation of results from the lower crustal cores is complicated by the pervasive presence of secondary magnetite. In almost all samples, a stable component was resolved (interpreted as a characteristic remanent magnetization) after removal of a lower-coercivity or lower unblocking-temperature component. The inclinations of the stable components in the core reference frame are very consistent in Hole GT1A. However, a transition from negative to positive inclinations in GT2A suggests some structural complexity, possibly as a result of intense late faulting activity. Both abrupt and gradual transitions between multiple zones of negative and positive inclinations occur in Hole GT3A. Interpretation and direct comparison of remanence between drill sites is difficult as recovered core pieces currently remain azimuthally unoriented, and GT2A was drilled at a plunge of 60°, whereas GT1A and GT3A were both drilled vertically. Work is ongoing to use borehole imagery to reorient the core pieces and paleomagnetic data into a geographic in situ reference

  10. Arrested development - a comparative analysis of multilayer corona textures in high-grade metamorphic rocks (United States)

    Ogilvie, Paula; Gibson, Roger L.


    Coronas, including symplectites, provide vital clues to the presence of arrested reaction and preservation of partial equilibrium in metamorphic and igneous rocks. Compositional zonation across such coronas is common, indicating the persistence of chemical potential gradients and incomplete equilibration. Major controls on corona mineralogy include prevailing pressure (P), temperature (T) and water activity (aH2O) during formation, reaction duration (t) single-stage or sequential corona layer growth; reactant bulk compositions (X) and the extent of metasomatic exchange with the surrounding rock; relative diffusion rates for major components; and/or contemporaneous deformation and strain. High-variance local equilibria in a corona and disequilibrium across the corona as a whole preclude the application of conventional thermobarometry when determining P-T conditions of corona formation, and zonation in phase composition across a corona should not be interpreted as a record of discrete P-T conditions during successive layer growth along the P-T path. Rather, the local equilibria between mineral pairs in corona layers more likely reflect compositional partitioning of the corona domain during steady-state growth at constant P and T. Corona formation in pelitic and mafic rocks requires relatively dry, residual bulk rock compositions. Since most melt is lost along the high-T prograde to peak segment of the P-T path, only a small fraction of melt is generally retained in the residual post-peak assemblage. Reduced melt volumes with cooling limit length scales of diffusion to the extent that diffusion-controlled corona growth occurs. On the prograde path, the low melt (or melt-absent) volumes required for diffusion-controlled corona growth are only commonly realized in mafic igneous rocks, owing to their intrinsic anhydrous bulk composition, and in dry, residual pelitic compositions that have lost melt in an earlier metamorphic event. Experimental work characterizing rate

  11. Evaluation of whole-rock lead isotope data for drill cores of the Eye-Dashwa Lakes pluton and the Vermilion granitic complex

    International Nuclear Information System (INIS)

    Doe, B.R.


    Disturbances of the U-Th-Pb systems in drill-core samples of the Eye-Dashwa Lakes pluton are related to a fracturing event in the Early Proterozoic and to more recent loss of lead due to fluid ingress at shallow crustal levels. The U-Pb and Th-Pb systems of five samples considered to be fresh on petrographic grounds (gray granite) are closed or show only limited parent/daughter mobility. U-Pb data for these samples are within about 10 percent of being concordant and define a concordia intercept age of 2684 ± 33 Ma, in agreement with the whole-rock Rb-Sr age of 2637 ± 33 Ma and U-Pb age of 2665 Ma inferred from zircon and titanite. The 207 Pb/ 204 Pb- 206 Pb/ 204 Pb plot for the fresh samples is 2684 ± 10 Ma. Three strongly altered samples define a chord on a concordia plot with intercepts at 2471 and 88 Ma. These samples are part of a suite of fractured, oxidized, and epidotized rocks that define a Rb-Sr isochron of 2281 ± 153 Ma. The whole-rock U-Pb systems of the altered samples are interpreted to have been perturbed by loss of Pb or gain of U during the fracturing event and again much more recently (Late Phanerozoic). The U-Pb systems in the fresh samples were not affected by the Early Proterozoic event, indicating that fluid ingress was largely restricted to the fracture zones

  12. Reconstruction of P-T-t metamorphic conditions from symplectites: insights from Pouso Alegre mafic rocks (Brasília Belt, Brazil) (United States)

    Tedeschi, Mahyra; Lanari, Pierre; Rubatto, Daniela; Hermann, Jörg; Pedrosa-Soares, Antônio Carlos; Dussin, Ivo; Aurélio Pinheiro, Marco; Bouvier, Anne-Sophie; Baumgartner, Lukas


    Reconstructing the metamorphic history of polycyclic tectono-metamorphic mafic rocks that preserve potential relicts of high-pressure metamorphism is challenging because such rocks are commonly retrogressed and rare in supercrustal sequences. However, pressure-temperature-time (P-T-t) information is required to obtain the paleo-geothermal gradients and thus to define those units as markers for suture zones. The mafic rocks from Pouso Alegre in the Meridional Brasília Orogen (SW-Brazil) outcrop as rare lenses within Sil-Grt gneisses, Amp-Grt orthogneisses and Bt granites. They are heavily weathered. They have previously been defined as "retro-eclogites", based on the characteristic symplectite texture and some mineralogical observations. They have been intepreted to mark the suture zone between the Paranapanema and São Francisco cratons, although no quantitative estimates of the pressure is available to support this conclusion. In this study we investigated in detail these samples to refine their P-T-t history. As commonly observed in retrogressed eclogites, the studied mafic rock shows symplectite and corona textures overprinting the former paragenesis of Garnet (Grt) - Clinopyroxene (Cpx) 1 - Amphibole (Amp) 1 - Rutile (Rt). Phase equilibrium modelling shows that this assemblage is stable at 690°C and 13.5 kbar, in line with Zr-in-rutile thermometry (720 ±30° C). Local compositions of the symplectite domains were used to retrieve the jadeite content of Cpx1. This low-Jd cpx is in line with the predictions of the model and confirms a maximum pressure of 14 kbar. The symplectite formed from the reaction Cpx1+Qz+H2O→Cpx2+Amp+Pl+Qz taking place at conditions of 600-750°C and <7 kbar. Zircon and monazite U-Th-Pb geochronology was performed for the mafic and surrounding rocks. Zircon core dates from the mafic rock spread along concordia from ca. 1.7 to 1.0 Ga with a cluster at 1520±17 Ma, which is interpreted as the protolith crystallization age. Zircon rim

  13. Death Valley turtlebacks: Mesozoic contractional structures overprinted by Cenozoic extension and metamorphism beneath syn-extensional plutons (United States)

    Pavlis, T. L.; Miller, M.; Serpa, L.


    -thrust belts. Our work to the east of Death Valley suggests these thrusts were part of a NW trending thrust system that overprinted an older NE trending fold-thrust system that tracks into the Death Valley region from Nevada. These NW trending thrusts probably underlie all of the southern Black Mountains (south of the turtlebacks) and we suggest that pre-extensional structural relief along these basement thrusts placed basement at shallow crustal levels throughout what is now the Black Mountains; a conclusion consistent with the absence of rocks younger than Cambrian beneath Tertiary unconformities throughout the southern Death Valley region. In Late Miocene time, a major detachment system formed and the turtlebacks represent a mid-crustal shear zone developed during that time period, but this system is older, and structurally beneath younger detachments systems that comprise the Amargosa fault system. During motion on the detachment, an ~2km thick plutonic sheet was emplaced along the shear zone forming the Miocene plutonic assemblages of the Black Mountains, and produced upper amphibolite facies metamorphic assemblages along the floor of the pluton in what are now the Copper Canyon and Mormon Point turtlebacks, but the Badwater Turtleback escaped this metamorphism due to a different structural position. Motion continued along the floor of the pluton but syn-extensional folding produced structural relief along folds with axes parallel to the extension direction. Ultimately a new detachment system cut obliquely across the older extensional system, removing the roof of the pluton, but cutting down to its floor in the turtlebacks. This fault system formed a complex detachment system updip in the famous 'Amargosa Chaos', and removing the entire cover sequence from the Black Mountains (~10-12km of crustal section). The turtlebacks are therefore a composite structure in which extension contemporaneous with folding, presumably as a result of distributed transcurrent motion during

  14. Mafic and related complexes in Galicia: an excursion guide

    NARCIS (Netherlands)

    Arps, C.E.S.; Calsteren, van P.W.C.; Hilgen, J.D.; Kuijper, R.P.; Tex, den E.


    In Galicia occur several polymetamorphic complexes that contain mafic and ultramafic rocks. Mafic volcanics and gabbros are situated in or near the complexes. An episode of metamorphism and granitization encompassed the generation of the volcanics and gabbros. Gravity surveys revealed the existence

  15. Vanadium complexes having [VO]2+, [VO]3+ and [VO2]+ cores with hydrazones of 2,6-diformyl-4-methylphenol: synthesis, characterization, reactivity, and catalytic potential. (United States)

    Maurya, Mannar R; Haldar, Chanchal; Kumar, Amit; Kuznetsov, Maxim L; Avecilla, Fernando; Costa Pessoa, João


    The Schiff bases H3dfmp(L)2 obtained by the condensation of 2,6-diformyl-4-methylphenol and hydrazones [L = isonicotinoylhydrazide (inh), nicotinoylhydrazide (nah) and benzoylhydrazide (bhz)] are prepared and characterized. By reaction of [V(IV)O(acac)2] and the H3dfmp(L)2 in methanol the V(IV)O-complexes [V(IV)O{Hdfmp(inh)2}(H2O)] (1), [V(IV)O{Hdfmp(nah)2}(H2O)] (2) and [V(IV)O{Hdfmp(bhz)2}(H2O)] (3) were obtained. Upon their aerial oxidation in methanol [V(V)O(OMe)(MeOH){Hdfmp(inh)2}] (4), [V(V)O(OMe)(MeOH){Hdfmp(nah)2}] (5) and [V(V)O(OMe)(MeOH){Hdfmp(bhz)2}] (6) were isolated. In the presence of KOH, oxidation of 1-3 results in the formation of [V(V)O2{H2dfmp(inh)2}]n·5H2O (7), K[V(V)O2{Hdfmp(nah)2}] (8) and K[V(V)O2{Hdfmp(bhz)2}] (9). All compounds are characterized in the solid state and in solution, namely by spectroscopic techniques (IR, UV-Vis, EPR, (1)H, (13)C and (51)V NMR), and DFT is also used to calculate the V(IV) hyperfine coupling constants of V(IV)-compounds and (51)V NMR chemical shifts of several V(V)-species and assign them to those formed in solution. Single crystal X-ray analysis of [V(V)O(OMe)(MeOH){Hdfmp(bhz)2}] (6) and [V(V)O2{H2dfmp(inh)2}]n·5H2O (7) confirm the coordination of the ligand in the dianionic (ONO(2-)) enolate tautomeric form, one of the hydrazide moieties remaining non-coordinated. In the case of 7 the free N(pyridine) atom of the inh moiety coordinates to the other vanadium center yielding a polynuclear complex in the solid state. It is also demonstrated that the V(V)O2-complexes are catalyst precursors in the oxidative bromination of styrene by H2O2, therefore acting as functional models of vanadium dependent haloperoxidases. Plausible intermediates involved in the catalytic process are established by UV-Vis, (51)V NMR and DFT studies.

  16. Experimental and theoretical analysis of a rare nitrato bridged 3d-4f complex containing LaZn2 core synthesized from a Zn(II) metalloligand (United States)

    Sreejith, S. S.; Mohan, Nithya; Kurup, M. R. Prathapachandra


    A trinulcear Zn2La Schiff base complex was synthesized using slow-solvent evaporation technique from a Zn(II) mononuclear metalloligand by 2:1 addition with La(NO3)3 salt. Single crystal XRD analysis revealed a rare nitrato bridged trinuclear entity which is seldom seen in these class of ligand systems. Qualitative and quantitative analysis of intermolecular interactions/short contacts were done using Hirshfeld surface and 2D finger print analysis. The thermally stable, blue luminescent compound exhibits internal heavy atom effect thereby quenching the emission intensity of the ligand. DFT calculations were performed on the compound to analyze frontier orbitals and also ESP plots were used to monitor nucleophilic/electrophilic regions on the compound and its implications on hydrogen bonding. A comparison of the bond orders and atomic charges on the trinuclear compound and the Zn(II) metalloligand precursor was performed to substantiate the formation of the trinuclear product through ligand exchange.

  17. Assessment of fire-damaged concrete. Combining metamorphic petrology and concrete petrography

    NARCIS (Netherlands)

    Larbi, J.A.; Nijland, T.G.


    Metamorphic petrology is a branch of geology that deals with the study of changes in rocks due changing physio-chemical conditions. As conditions shift in or out of the thermodynamic stability field of phases, new phases may appear whereas others disappear. A basic approach is mapping of so-called

  18. Review of the intrusive, structural and metamorphic history of the Namaqualand geotraverse and environs

    International Nuclear Information System (INIS)

    Blignault, H.J.; Van Aswegen, G.; Van der Merwe, S.W.


    The Namaqualand excursion is concerned with the geologic strata, stratigraphy and metamorhic history of the Namaqualand geotraverse and its environs. The general aim of the project was to decipher the history and interactions of tectonic, metamorphic and magmatic processes. Isotope dating were used to determine the ages of various rock formations

  19. Fluid-driven metamorphism of the continental crust governed by nanoscale fluid flow

    NARCIS (Netherlands)

    Plümper, O.; Botan, Alexandru; Los, Catharina; Liu, Yang; Malthe-Sorenssen, Anders; Jamtveit, Bjørn


    The transport of fluids through the Earth’s crust controls the redistribution of elements to form mineral and hydrocarbon deposits, the release and sequestration of greenhouse gases, and facilitates metamorphic reactions that influence lithospheric rheology. In permeable systems with a

  20. Selection of diet by metamorphic and juvenile western toads (Bufo boreas) in northeastern Oregon (United States)

    Evelyn L Bull; Jane L. Hayes


    The decline of Bufo boreas, the Western Toad, in portions of its range has accentuated the need for more complete information on all life stages of this species. Our objectives were to describe the diet of recently metamorphosed and juvenile (one-year old) B. boreas and then compare it to the available arthropods. Metamorphs (n...

  1. Assessment of role of metamorphic remobilization in genesis of uranium ores from Ralston Buttes area, Colorado

    International Nuclear Information System (INIS)

    Chatterjee, S.K.


    The Ralston Buttes mining district, the principal source of commercial uranium in the Front Range since the late 1940s, is located northeast of Golden and southeast of the Front Range mineral belt. Uranium ore occurs in veins emplaced in fault breccia in Precambrian metamorphic rocks. The progenitors of the metamorphic rocks are a possible source for the uranium. Hornblende gneisses of the Idaho Springs Formation is the major rock type in the area, thus its origin is a major consideration in assessing the quantity of uranium that might have been contributed by metamorphic processes. To evaluate this, 41 rock samples (19 hornblende gneisses, 7 biotite gneisses, 5 chlorite gneisses, and 10 metapelites) were analyzed for major elements, and 3 rock samples (16 hornblende gneisses, 8 biotite gneisses, 4 chlorite gneisses, and 5 mica schists) were analyzed for trace metals (Rb, Sc, Zr, V, Ni, Co, Cr, Ba, U, and Th). Four samples of hornblende gneiss and 1 sample of mica schists were also analyzed for rare earth elements. Major elements are rare earth data indicate that the hornblende gneiss was derived from sediments and tholeiitic basalts. Trace element data suggest a volcanic provenance for these sediments. Rare earth patterns and uranium and thorium abundances of metapelites are similar to average North American shales. Low uranium and thorium values and low thorium-uranium ratios in hornblende gneisses and mica schists preclude large-scale uranium remobilization during metamorphism of these source rocks

  2. Geology of the Biwabik Iron Formation and Duluth Complex. (United States)

    Jirsa, Mark A; Miller, James D; Morey, G B


    The Biwabik Iron Formation is a approximately 1.9 billion year-old sequence of iron-rich sedimentary rocks that was metamorphosed at its eastern-most extent by approximately 1.1 billion year-old intrusions of the Duluth Complex. The metamorphic recrystallization of iron-formation locally produced iron-rich amphiboles and other fibrous iron-silicate minerals. The presence of these minerals in iron-formation along the eastern part of what is known as the Mesabi Iron Range, and their potential liberation by iron mining has raised environmental health concerns. We describe here the geologic setting and mineralogic composition of the Biwabik Iron Formation in and adjacent to the contact metamorphic aureole of the Duluth Complex. The effects of metamorphism are most pronounced within a few kilometers of the contact, and decrease progressively away from it. The contact aureole has been divided into four metamorphic zones-each characterized by the composition and crystal structure of the metamorphic minerals it contains. The recrystallization of iron-formation to iron-rich amphibole minerals (grunerite and cummingtonite) and iron-pyroxene minerals (hedenbergite and ferrohypersthene) is best developed in zones that are most proximal to the Duluth Complex contact.

  3. Geology of the Biwabik Iron Formation and Duluth Complex (United States)

    Jirsa, M.A.; Miller, J.D.; Morey, G.B.


    The Biwabik Iron Formation is a ???1.9 billion year-old sequence of iron-rich sedimentary rocks that was metamorphosed at its eastern-most extent by ???1.1 billion year-old intrusions of the Duluth Complex. The metamorphic recrystallization of iron-formation locally produced iron-rich amphiboles and other fibrous iron-silicate minerals. The presence of these minerals in iron-formation along the eastern part of what is known as the Mesabi Iron Range, and their potential liberation by iron mining has raised environmental health concerns. We describe here the geologic setting and mineralogic composition of the Biwabik Iron Formation in and adjacent to the contact metamorphic aureole of the Duluth Complex. The effects of metamorphism are most pronounced within a few kilometers of the contact, and decrease progressively away from it. The contact aureole has been divided into four metamorphic zones-each characterized by the composition and crystal structure of the metamorphic minerals it contains. The recrystallization of iron-formation to iron-rich amphibole minerals (grunerite and cummingtonite) and iron-pyroxene minerals (hedenbergite and ferrohypersthene) is best developed in zones that are most proximal to the Duluth Complex contact. ?? 2007 Elsevier Inc. All rights reserved.

  4. 3D-reconstructions and virtual 4D-visualization to study metamorphic brain development in the sphinx moth Manduca sexta

    Directory of Open Access Journals (Sweden)

    Wolf Huetteroth


    Full Text Available During metamorphosis, the transition from the larva to the adult, the insect brain undergoes considerable remodeling: New neurons are integrated while larval neurons are remodeled or eliminated. One well acknowledged model to study metamorphic brain development is the sphinx moth Manduca sexta. To further understand mechanisms involved in the metamorphic transition of the brain we generated a 3D standard brain based on selected brain areas of adult females and 3D reconstructed the same areas during defined stages of pupal development. Selected brain areas include for example mushroom bodies, central complex, antennal- and optic lobes. With this approach we eventually want to quantify developmental changes in neuropilar architecture, but also quantify changes in the neuronal complement and monitor the development of selected neuronal populations. Furthermore, we used a modeling software (Cinema 4D to create a virtual 4D brain, morphing through its developmental stages. Thus the didactical advantages of 3D visualization are expanded to better comprehend complex processes of neuropil formation and remodeling during development. To obtain datasets of the M. sexta brain areas, we stained whole brains with an antiserum against the synaptic vesicle protein synapsin. Such labeled brains were then scanned with a confocal laser scanning microscope and selected neuropils were reconstructed with the 3D software AMIRA 4.1.

  5. Core calculations of JMTR

    Energy Technology Data Exchange (ETDEWEB)

    Nagao, Yoshiharu [Japan Atomic Energy Research Inst., Oarai, Ibaraki (Japan). Oarai Research Establishment


    In material testing reactors like the JMTR (Japan Material Testing Reactor) of 50 MW in Japan Atomic Energy Research Institute, the neutron flux and neutron energy spectra of irradiated samples show complex distributions. It is necessary to assess the neutron flux and neutron energy spectra of an irradiation field by carrying out the nuclear calculation of the core for every operation cycle. In order to advance core calculation, in the JMTR, the application of MCNP to the assessment of core reactivity and neutron flux and spectra has been investigated. In this study, in order to reduce the time for calculation and variance, the comparison of the results of the calculations by the use of K code and fixed source and the use of Weight Window were investigated. As to the calculation method, the modeling of the total JMTR core, the conditions for calculation and the adopted variance reduction technique are explained. The results of calculation are shown. Significant difference was not observed in the results of neutron flux calculations according to the difference of the modeling of fuel region in the calculations by K code and fixed source. The method of assessing the results of neutron flux calculation is described. (K.I.)

  6. Discovery of microscopic evidence for shock metamorphism at the Serpent Mound structure, south-central Ohio: Confirmation of an origin by impact (United States)

    Carlton, R.W.; Koeberl, C.; Baranoski, M.T.; SchuMacHer, G.A.


    The origin of the Serpent Mound structure in south-central Ohio has been disputed for many years. Clearly, more evidence was needed to resolve the confusion concerning the origin of the Serpent Mound feature either by endogenic processes or by hypervelocity impact. A petrographic study of 21 samples taken from a core 903 m long drilled in the central uplift of the structure provides evidence of shock metamorphism in the form of multiple sets of planar deformation features in quartz grains, as well as the presence of clasts of altered impact-melt rock. Crystallographic orientations of the planar deformation features show maxima at the shock-characteristic planes of {101??3} and {101??2} and additional maxima at {101??1}, {213??1}, and {516??1}. Geochemical analyses of impact breccias show minor enrichments in the abundances of the siderophile elements Cr, Co, Ni, and Ir, indicating the presence of a minor meteoritic component.

  7. On the role of Yttrium during plurifacial Hercynian metamorphism as expressed in the Northern part of the Central galician schist Area (NW Spain)

    NARCIS (Netherlands)

    Hilgen, J.D.


    Recent investigations of the distribution of trace elements in metamorphic index minerals of metapelites have revealed, that the plurifacial character of the Hercynian metamorphism in this area is confirmed by the distribution of Yttrium in Hercynian garnets of the metamorphic series.

  8. Metamorphic evolution of the Lesser Himalayan Crystalline Sequence, Siyom Valley, NE Himalaya, India (United States)

    Nandini, P.; Thakur, S. S.


    The paper reports classical Barrovian inverted metamorphism in the Lesser Himalayan Crystalline Sequence, Siyom Valley, NE Himalaya. The sequence is thrust-bounded and constitutes a part of the western limb of the Siang antiform. Six metamorphic zones are delineated with increasing grade from biotite zone through garnet-, staurolite-, kyanite-, sillimanite- to sillimanite-K-feldspar zone with increasing structural level. Granulite-facies pelitic assemblages, marked by the occurrence of garnet + cordierite occur in the sillimanite-K-feldspar zone. Three phases of folding, F 1, F 2 and F 3 and two generations of planar structures, S 1 and S 2 are recognised. Peak metamorphic mineral growths are dominantly syn-F 2. Metamorphic isograds and boundary thrusts of the sequence are co-folded around the Siang antiform by F 3 deformation. Garnet shows prograde growth zoning in lower grade rocks and retrograde diffusion zoning in higher grade rocks. Pelites of the sillimanite-K-feldspar zone show textural evidence of decompression such as corona of cordierite around kyanite. Breakdown reactions of muscovite and biotite in this zone are attributed to decompression. Geothermobarometric calculations show gradual increase of temperature from garnet zone to sillimanite-K-feldspar zone, whereas pressure increases sharply from garnet zone to staurolite zone and remains nearly constant thereafter. Peak metamorphism reached temperature of >750 °C and pressure of ˜10 kbar in the sillimanite-K-feldspar zone. P-T estimates, decompression reactions and pseudosection topologies suggest a clockwise path with steep decompression for the evolution of the sillimanite-K-feldspar zone in the Siyom Valley.

  9. Helicobacter pylori CheZ(HP) and ChePep form a novel chemotaxis-regulatory complex distinct from the core chemotaxis signaling proteins and the flagellar motor. (United States)

    Lertsethtakarn, Paphavee; Howitt, Michael R; Castellon, Juan; Amieva, Manuel R; Ottemann, Karen M


    Chemotaxis is important for Helicobacter pylori to colonize the stomach. Like other bacteria, H. pylori uses chemoreceptors and conserved chemotaxis proteins to phosphorylate the flagellar rotational response regulator, CheY, and modulate the flagellar rotational direction. Phosphorylated CheY is returned to its non-phosphorylated state by phosphatases such as CheZ. In previously studied cases, chemotaxis phosphatases localize to the cellular poles by interactions with either the CheA chemotaxis kinase or flagellar motor proteins. We report here that the H. pylori CheZ, CheZ(HP), localizes to the poles independently of the flagellar motor, CheA, and all typical chemotaxis proteins. Instead, CheZ(HP) localization depends on the chemotaxis regulatory protein ChePep, and reciprocally, ChePep requires CheZ(HP) for its polar localization. We furthermore show that these proteins interact directly. Functional domain mapping of CheZ(HP) determined the polar localization motif lies within the central domain of the protein and that the protein has regions outside of the active site that participate in chemotaxis. Our results suggest that CheZ(HP) and ChePep form a distinct complex. These results therefore suggest the intriguing idea that some phosphatases localize independently of the other chemotaxis and motility proteins, possibly to confer unique regulation on these proteins' activities. © 2015 John Wiley & Sons Ltd.

  10. Short-Wavelength Infrared (SWIR) spectroscopy of low-grade metamorphic volcanic rocks of the Pilbara Craton (United States)

    Abweny, Mohammad S.; van Ruitenbeek, Frank J. A.; de Smeth, Boudewijn; Woldai, Tsehaie; van der Meer, Freek D.; Cudahy, Thomas; Zegers, Tanja; Blom, Jan-Kees; Thuss, Barbara


    This paper shows the results of Short-Wavelength Infrared (SWIR) spectroscopy investigations of volcanic rocks sampled from low-grade metamorphic greenstone belts of the Archean Pilbara Craton in Western Australia. From the reflectance spectra a range of spectrally active minerals were identified, including chlorites, hornblende, actinolite, epidote and white micas. The rock samples were grouped into mineral assemblages based on their spectrally identified minerals and stratigraphic positions. The metamorphic amphibolite and greenschist facies could be identified from the SWIR spectroscopic data as well as three sub zones of the greenschist facies: 1) a zone containing Fe-chlorite; 2) a zone containing intermediate chlorite and epidote; and 3) a zone containing intermediate chlorite, actinolite and hornblende. Spectral parameters were calculated from the reflectance spectra to assess the metamorphic grade and zones. Plots of the depth parameters of the Fe-OH feature near 2250 nm versus the Mg-OH feature near 2390 nm differentiate the metamorphic amphibolite and greenschist facies and a transition zone between the two. The wavelength position parameter of the Mg-OH absorption feature near 2340 nm also serves to discriminate between the various metamorphic sub zones. The identification of the metamorphic grades of the volcanic sequences in greenstone belts with SWIR spectroscopy is useful for regional geological field studies, exploration for metamorphic mineral deposits hosted in the greenstone belts and the interpretation of hyperspectral remote sensing data sets covering similar types of terranes.

  11. Multi-core Microprocessors

    Indian Academy of Sciences (India)

    core processors. Abstract. Multi-core microprocessor is an interconnected set of independentprocessors called cores integrated on a single siliconchip. These processing cores communicate and cooperatewith one another to execute one or more ...

  12. The effects of metamorphism on iron mineralogy and the iron speciation redox proxy (United States)

    Slotznick, Sarah P.; Eiler, John M.; Fischer, Woodward W.


    As the most abundant transition metal in the Earth's crust, iron is a key player in the planetary redox budget. Observations of iron minerals in the sedimentary record have been used to describe atmospheric and aqueous redox environments over the evolution of our planet; the most common method applied is iron speciation, a geochemical sequential extraction method in which proportions of different iron minerals are compared to calibrations from modern sediments to determine water-column redox state. Less is known about how this proxy records information through post-depositional processes, including diagenesis and metamorphism. To get insight into this, we examined how the iron mineral groups/pools (silicates, oxides, sulfides, etc.) and paleoredox proxy interpretations can be affected by known metamorphic processes. Well-known metamorphic reactions occurring in sub-chlorite to kyanite rocks are able to move iron between different iron pools along a range of proxy vectors, potentially affecting paleoredox results. To quantify the effect strength of these reactions, we examined mineralogical and geochemical data from two classic localities where Silurian-Devonian shales, sandstones, and carbonates deposited in a marine sedimentary basin with oxygenated seawater (based on global and local biological constraints) have been regionally metamorphosed from lower-greenschist facies to granulite facies: Waits River and Gile Mountain Formations, Vermont, USA and the Waterville and Sangerville-Vassalboro Formations, Maine, USA. Plotting iron speciation ratios determined for samples from these localities revealed apparent paleoredox conditions of the depositional water column spanning the entire range from oxic to ferruginous (anoxic) to euxinic (anoxic and sulfidic). Pyrrhotite formation in samples highlighted problems within the proxy as iron pool assignment required assumptions about metamorphic reactions and pyrrhotite's identification depended on the extraction techniques

  13. Hydrogen bonding, solvent exchange, and coupled proton and electron transfer in the oxidation and reduction of redox-active tyrosine Y(Z) in Mn-depleted core complexes of photosystem II. (United States)

    Diner, B A; Force, D A; Randall, D W; Britt, R D


    The redox-active tyrosines, Y(Z) and Y(D), of Photosystem II are oxidized by P680+ to the neutral tyrosyl radical. This oxidation thus involves the transfer of the phenolic proton as well as an electron. It has recently been proposed that tyrosine Y(Z) might replace the lost proton by abstraction of a hydrogen atom or a proton from a water molecule bound to the manganese cluster, thereby increasing the driving force for water oxidation. To compare and contrast with the intact system, we examine here, in a simplified Mn-depleted PSII core complex, isolated from a site-directed mutant of Synechocystis PCC 6803 lacking Y(D), the role of proton transfer in the oxidation and reduction of Y(Z). We show how the oxidation and reduction rates for Y(Z), the deuterium isotope effect on these rates, and the Y(Z)* - Y(Z) difference spectra all depend on pH (from 5.5 to 9.5). This simplified system allows examination of electron-transfer processes over a broader range of pH than is possible with the intact system and with more tractable rates. The kinetic isotope effect for the oxidation of P680+ by Y(Z) is maximal at pH 7.0 (3.64). It decreases to lower pH as charge recombination, which shows no deuterium isotope, starts to become competitive with Y(Z) oxidation. To higher pH, Y(Z) becomes increasingly deprotonated to form the tyrosinate, the oxidation of which at pH 9.5 becomes extremely rapid (1260 ms(-1)) and no longer limited by proton transfer. These observations point to a mechanism for the oxidation of Y(Z) in which the tyrosinate is the species from which the electron occurs even at lower pH. The kinetics of oxidation of Y(Z) show elements of rate limitation by both proton and electron transfer, with the former dominating at low pH and the latter at high pH. The proton-transfer limitation of Y(Z) oxidation at low pH is best explained by a gated mechanism in which Y(Z) and the acceptor of the phenolic proton need to form an electron/proton-transfer competent complex in

  14. Eclogite-high-pressure granulite metamorphism records early collision in West Gondwana: new data from the Southern Brasilia Belt, Brazil

    DEFF Research Database (Denmark)

    Reno II, Barry Len; Brown, Michael; Kobayashi, Katsura


    constrain the age of. (1) retrograded eclogite from a block along the tectonic contact beneath the uppermost nappe in a stack of passive margin-derived nappes; (2) high-pressure granulite-facies metamorphism in the uppermost passive margin-derived nappe; (3) high-pressure granulite-facies metamorphism...... in the overlying arc-derived nappe. Rare zircons from a retrograded eclogite yield a Pb-206/U-238 age of 678 +/- 29 Ma. which we interpret as most likely to (late close-to-peak-P metamorphism and to provide a minimum age for detachment of the overlying passive margin-derived nappe from the subducting plate. Zircon...

  15. Uranium cycle and tectono-metamorphic evolution of the Lufilian Pan-African orogenic belt (Zambia)

    International Nuclear Information System (INIS)

    Eglinger, Aurelien


    Uranium is an incompatible and lithophile element, and thus more concentrated in silicate melt produced by the partial melting of the mantle related to continental crust formation. Uranium can be used as a geochemical tracer to discuss the generation and the evolution of continental crust. This thesis, focused on the Pan-African Lufilian belt in Zambia, combines structural geology, metamorphic petrology and thermos-barometry, fluid inclusions, geochemistry and geochronology in order to characterize the uranium cycle for this crustal segment. Silici-clastic and evaporitic sediments have been deposited within an intra-continental rift during the dislocation of the Rodinia super-continent during the early Neo-proterozoic. U-Pb ages on detrital zircon grains in these units indicate a dominant Paleo-proterozoic provenance. The same zircon grains show sub-chondritic εHf (between 0 and -15) and yield Hf model ages between ∼2.9 and 2.5 Ga. These data suggest that the continental crust was generated before the end of the Archean (< 2.5 Ga) associated with uranium extraction from the mantle. This old crust has been reworked by deformation and metamorphism during the Proterozoic. Uranium has been re-mobilized and reconcentrated during several orogenic cycles until the Pan-African orogeny. During this Pan-African cycle, U-Pb and REY (REE and Yttrium) signatures of uranium oxides indicate a first mineralizing event at ca. 650 Ma during the continental rifting. This event is related to late diagenesis hydrothermal processes at the basement/cover interface with the circulation of basinal brines linked to evaporites of the Roan. The second stage, dated at 530 Ma, is connected to metamorphic highly saline fluid circulations, synchronous to the metamorphic peak of the Lufilian orogeny (P=9±3 kbar; T=610±30 deg. C). These fluids are derived from the Roan evaporite dissolution. Some late uranium re-mobilizations are described during exhumation of metamorphic rocks and their

  16. Low-grade metamorphism in the eastern Southern Alps: Distribution, conditions, timing and implications for the tectonics of the Alps and NW Dinarides (United States)

    Neubauer, Franz; Heberer, Bianca; Genser, Johann; Friedl, Getrude


    Based on 40Ar/39Ar dating of newly-grown syntectonic metamorphic white mica (sericite), we recognize for the first time the timing of Alpine low-grade metamorphism in the eastern part of the Southalpine unit: (1) A Silurian phyllite of Seeberg inlier located to the south of the Periadriatic fault yields a plateau age at c. 75 Ma suggesting a Late Cretaceous age of previously recognized low-grade (Rantitsch & Rainer, 2003) metamorphism. (2) Within the Tolmin nappe, four sericite plateau ages of mainly Middle Triassic volcanics are at c. 51 Ma (Early Eocene). The Late Cretaceous age in the Seeberg inlier is considered to record ductile deformation during formation of a retro-wedge related to the Eo-Alpine orogeny in the Austroalpine units in the Eastern Alps exposed north of the future Periadriatic fault. The Eocene age at the boundary of very low-grade to low-grade metamorphism in the Tolmin nappe (Rainer et al., 2009) relates to the emplacement of the Southalpine nappe complex onto the Dinarides and is contemporaneous with the initial ductile deformation in the Dinarides during Adria-directed shortening and formation of a siliciclastic flysch belt in front of the SW-directed growing fold-thrust belt (Placer, 2008). Similar rare Late Cretaceous and dominant Eocene ages within post-Variscan units are virtually more widespread in the Southalpine unit and Dinarides as considered before. These regions include the Collio basin (Feijth, 2002) and the Eder unit (Läufer et al., 1996) in the western and central Southern Alps, in the internal NW Dinarides (Borojević Šoštarić et al., 2012) and the Mid Bosnian Schist Mountains (Pamić et al., 2004) and Lim Paleozoic unit in the central Dinarides (Ilic et al., submitted). Consequently, the Southalpine unit and Dinarides were affected by two stages of metamorphism, Late Cretaceous (ca. 80 to 75 Ma) and Eocene (ca. 51 - 40 Ma), both stages are related to back-thrusting. The ages of metamorphism are different from those in the

  17. Tuning the Solubility of Copper Complex in Atom Transfer Radical Self-Condensing Vinyl Polymerizations to Control Polymer Topology via One-Pot to the Synthesis of Hyperbranched Core Star Polymers

    Directory of Open Access Journals (Sweden)

    Zong-Cheng Chen


    Full Text Available In this paper, we propose a simple one-pot methodology for proceeding from atom transfer reaction-induced conventional free radical polymerization (AT-FRP to atom transfer self-condensing vinyl polymerization (AT-SCVP through manipulation of the catalyst phase homogeneity (i.e., CuBr/2,2'-bipyridine (CuBr/Bpy in a mixture of styrene (St, 4-vinyl benzyl chloride (VBC, and ethyl 2-bromoisobutyrate. Tests of the solubilities of CuBr/Bpy and CuBr2/Bpy under various conditions revealed that both temperature and solvent polarity were factors affecting the solubility of these copper complexes. Accordingly, we obtained different polymer topologies when performing AT-SCVP in different single solvents. We investigated two different strategies to control the polymer topology in one-pot: varying temperature and varying solvent polarity. In both cases, different fractions of branching revealed the efficacy of varying the polymer topology. To diversify the functionality of the peripheral space, we performed chain extensions of the resulting hyperbranched poly(St-co-VBC macroinitiator (name as: hbPSt MI with either St or tBA (tert-butyl acrylate. The resulting hyperbranched core star polymer had high molecular weights (hbPSt-g-PSt: Mn = 25,000, Đ = 1.77; hbPSt-g-PtBA: Mn = 27,000, Đ = 1.98; hydrolysis of the tert-butyl groups of the later provided a hyperbranched core star polymer featuring hydrophilic poly(acrylic acid segments.

  18. Evidence for Cyclical Fractional Crystallization, Recharge, and Assimilation in Basalts of the Kimama Drill Core, Central Snake River Plain, Idaho: 5.5-Million-Years of Petrogenesis in a Mid-crustal Sill Complex

    Directory of Open Access Journals (Sweden)

    Katherine E. Potter


    , evolved and high K-Fe flows are compositionally unrelated to SROT magmas and represent highly fractionated basalt, probably accompanied by crustal assimilation. These evolved lavas may be sourced from the Craters of the Moon/Great Rift system to the northeast. The Kimama drill core is the longest record of geochemical variation in the central Snake River Plain and reinforces the concept of magma processing in a layered complex.

  19. Mid amphibolite facies metamorphism of harzburgites in the Neoproterozoic Cerro Mantiqueiras Ophiolite, southernmost Brazil

    Directory of Open Access Journals (Sweden)



    Full Text Available Valuable information is retrieved from the integrated investigation of the field relationships, microstructure and mineral compositions of harzburgites from the Neoproterozoic Cerro Mantiqueiras Ophiolite. This important tectonic marker of the geological evolution of southernmost Brazilian Shield was thoroughly serpentinized during progressive metamorphism, because the oldest mineral assemblage is: olivine + orthopyroxene + tremolite + chlorite + chromite. This M1 was stabilized in mid amphibolite facies - 550-600ºC as calculated from mineral equilibria. No microstructural (e.g. ductile deformation of olivine or chromite or compositional (e.g. mantle spinel remnant of mantle history was identified. A metamorphic event M2 occurred in the low amphibolite facies along 100 m-wide shear zones, followed by intense serpentinization (M3 and narrow 1-3 m-wide shear zones (M4 containing asbestos.

  20. Epitaxial nanowire formation in metamorphic GaAs/GaPAs short-period superlattices (United States)

    Zheng, Nan; Ahrenkiel, S. Phillip


    Metamorphic growth presents routes to novel nanomaterials with unique properties that may be suitable for a range of applications. We discuss self-assembled, epitaxial nanowires formed during metalorganic chemical vapor deposition of metamorphic GaAs/GaPAs short-period superlattices. The heterostructures incorporate strain-engineered GaPAs compositional grades on 6°-B miscut GaAs substrates. Lateral diffusion within the SPS into vertically aligned, three-dimensional columns results in nanowires extending along A directions with a lateral period of 70-90 nm. The microstructure is probed by transmission electron microscopy to confirm the presence of coherent GaAs nanowires within GaPAs barriers. The compositional profile is inferred from analysis of {200} dark-field image contrast and lattice images.

  1. Heat production rate from radioactive elements in igneous and metamorphic rocks in eastern desert, Egypt

    International Nuclear Information System (INIS)

    Abbady, A G.E.; Arabi, A.M.; Abbay, A.


    Radioactive heat - production data of igneous and metamorphic rocks cropping out from the eastern desert are presented. Samples were analysed using low level gamma-ray spectrometer (HPGe) in the laboratory. A total of 205 rock samples were investigated, covering all major rock types of the area. The heat-production rate of igneous rocks ranges from 0.11 (basalt) to 9.53 Μ Wm-3 (granite). In metamorphic rocks it varies from 0.28 (serpentinite) to 0.91 (metagabroo) Μ W.m-3. The contribution due to U is about (51%), whereas that of Th (31%) and (18%) by K. The corresponding values in igneous rocks are 76%: 19%: 5%, respectively. The calculated values showed good agreement with global values expect in some areas contained granite rocks

  2. Metamorphic evolution of metadolerites from the Frido Unit ophiolites (Southern Apennine-Italy) (United States)

    Cristi Sansone, Maria T.; Prosser, Giacomo; Rizzo, Giovanna; Tartarotti, Paola


    The Southern Apennines chain is a fold-and-thrust belt resulting from the convergence of the African and European plates and simultaneous roll-back of SE-directed Ionian subduction (Upper Oligocene-Quaternary). Ophiolites in the Southern Apennines are related to northwest subduction of the oceanic lithosphere pertaining to the Ligurian sector of the Jurassic western Tethys. The ophiolitic sequences are enclosed within remnants of the Liguride accretionary wedge now incorporated in the Southern Apennine chain and they crop out in the north-eastern slope of the Pollino Ridge (Calabria-Lucania border zone). Mafic and ultramafic rocks, with garnet-bearing felses, amphibolites, gneiss and granitoides occur as tectonic slices within a matrix mainly composed of calcschists and phyllites. Metadolerites occur as dikes cutting through serpentinized peridotites. Metadolerites have different kinds of texture reflecting various degree of crystallinity and strain: porphyritic or aphyric, intersertal/intergranular, blastophitic, cataclastic to mylonitic. In all metadolerites primary plagioclase and clinopyroxene can be observed. The metamorphic mineral assemblage consists of brown amphibole, green amphibole, chlorite, blue amphibole, pumpellyite, prehnite, quartz, epidote, white mica, lawsonite and plagioclase (Pl2 and Pl3). Accessory phases are opaque minerals, Fe-hydroxides and zircon. Metadolerites are cross- cut by veins filled with pumpellyite, chlorite, prehnite, tremolite, plagioclase, white, mica, quartz, lawsonite, epidote and zircon. The veins are straight, a few millimetres in thickness and occur isolated or in closely spaced sets. The vein morphology ranges from planar to sinuous and irregular. On the basis of metamorphic mineral phases three different types of metadolerite can be distinguished: i) rocks with a high content of prehnite crystals in cataclastic-mylonitic bands, exhibiting an intersertal or a blastophitic texture or a mylonitic fabric and in some cases a

  3. Radioactive occurrences in veins and igneous and metamorphic rocks of New Mexico with annotated bibliography

    International Nuclear Information System (INIS)

    McLemore, V.T.


    From an extensive literature search and field examination of 96 nonsandstone radioactive occurrences, the author compiled an annotated bibliography of over 600 citations and a list of 327 radioactive occurrences in veins and igneous and metamorphic rocks of New Mexico. The citations are indexed by individual radioactive occurrence, geographic area, county, fluorspar deposits and occurrences, geochemical analyses, and geologic maps. In addition, the geology, mineralization, and uranium and thorium potential of 41 geographic areas in New Mexico containing known radioactive occurrences in veins and igneous and metamorphic rocks or that contain host rocks considered favorable for uranium or thorium mineralization are summarized. A list of aerial-radiometric, magnetic, hydrogeochemical, and stream-sediment survey reports is included

  4. Relaxation dynamics and residual strain in metamorphic AlSb on GaAs

    International Nuclear Information System (INIS)

    Ripalda, J. M.; Rivera, A.; Alen, B.; Gonzalez, Y.; Gonzalez, L.; Briones, F.; Sanchez, A. M.; Taboada, A. G.; Rotter, T. J.; Balakrishnan, G.


    We have observed the evolution of the accumulated stress during heteroepitaxial growth of highly lattice mismatched AlSb on GaAs by measuring the deformation of the substrate as a function of time. High resolution transmission electron microscopy images show almost all of the plastic relaxation is accommodated by an array of 90 deg. misfit dislocations at the interface. The in-plane lattice parameter of the resulting metamorphic AlSb is slightly smaller (0.3%) than the bulk value and perfectly matches the lattice parameter of bulk GaSb. It is, therefore, possible to grow nearly stress-free GaSb on GaAs using a metamorphic AlSb buffer layer.

  5. Relaxation dynamics and residual strain in metamorphic AlSb on GaAs

    Energy Technology Data Exchange (ETDEWEB)

    Ripalda, J. M.; Rivera, A.; Alen, B.; Gonzalez, Y.; Gonzalez, L.; Briones, F. [IMM-Instituto de Microelectronica de Madrid (CNM-CSIC), Isaac Newton 8, PTM, E-28760 Tres Cantos, Madrid (Spain); Sanchez, A. M. [Physics Department, University of Warwick, Coventry CV4 7AL (United Kingdom); Taboada, A. G. [Laboratory for Solid State Physics, ETH Zurich, Schafmattstr. 16, CH-8093 Zurich (Switzerland); Rotter, T. J.; Balakrishnan, G. [Center for High Technology Materials, University of New Mexico, Albuquerque, New Mexico 87106 (United States)


    We have observed the evolution of the accumulated stress during heteroepitaxial growth of highly lattice mismatched AlSb on GaAs by measuring the deformation of the substrate as a function of time. High resolution transmission electron microscopy images show almost all of the plastic relaxation is accommodated by an array of 90 deg. misfit dislocations at the interface. The in-plane lattice parameter of the resulting metamorphic AlSb is slightly smaller (0.3%) than the bulk value and perfectly matches the lattice parameter of bulk GaSb. It is, therefore, possible to grow nearly stress-free GaSb on GaAs using a metamorphic AlSb buffer layer.

  6. Enhanced Contacts for Inverted Metamorphic Multi-Junction Solar Cells Using Carbon Nanotube Metal Matrix Composites (United States)



  7. Study on microwave induced pyrolysis of low metamorphic coal and liquefaction residue (United States)

    Li, Zhao; Wu, Kunyao; Cao, Jing; Wang, Yongfeng


    This paper mainly studies pyrolysis characteristic in the different heating of microwave of low metamorphic coal and Liquefaction Residue, which was focused on the effects of particle sizes, pyrolysis reaction time, and microwave powers. The product are analyzed by Gas chromatography- mass spectrometry (GC-MS), etc. The results showed that when heating time is 40 min and 800 W, yield of tar is about 15.51%.

  8. Morphological preservation of carbonaceous plant fossils in blueschist metamorphic rocks from New Zealand. (United States)

    Galvez, M E; Beyssac, O; Benzerara, K; Bernard, S; Menguy, N; Cox, S C; Martinez, I; Johnston, M R; Brown, G E


    Morphological and chemical evidence of ancient life is widespread in sedimentary rocks retrieved from shallow depths in the Earth's crust. Metamorphism is highly detrimental to the preservation of biological information in rocks, thus limiting the geological record in which traces of life might be found. Deformation and increasing pressure/temperature during deep burial may alter the morphology as well as the composition and structure of both the organic and mineral constituents of fossils. However, microspore fossils have been previously observed in intensely metamorphosed rocks. It has been suggested that their small size, and/or the nature of the polymer composing their wall, and/or the mineralogy of their surrounding matrix were key parameters explaining their exceptional preservation. Here, we describe the remarkable morphological preservation of plant macrofossils in blueschist metamorphic rocks from New Zealand containing lawsonite. Leaves and stems can be easily identified at the macroscale. At the microscale, polygonal structures with walls mineralized by micas within the leaf midribs and blades may derive from the original cellular ultrastructure or, alternatively, from the shrinkage during burial of the gelified remnants of the leaves in an abiotic process. Processes and important parameters involved in the remarkable preservation of these fossils during metamorphism are discussed. Despite the excellent morphological preservation, the initial biological polymers have been completely transformed to graphitic carbonaceous matter down to the nanometer scale. This occurrence demonstrates that plant macrofossils may experience major geodynamic processes such as metamorphism and exhumation involving deep changes and homogenization of their carbon chemistry and structure but still retain their morphology with remarkable integrity even if they are not shielded by any hard-mineralized concretion. © 2012 Blackwell Publishing Ltd.

  9. Arrested development – a comparative analysis of multilayer corona textures in high-grade metamorphic rocks


    Ogilvie, Paula; Gibson, Roger L.


    Coronas, including symplectites, provide vital clues to the presence of arrested reaction and preservation of partial equilibrium in metamorphic and igneous rocks. Compositional zonation across such coronas is common, indicating the persistence of chemical potential gradients and incomplete equilibration. Major controls on corona mineralogy include prevailing pressure (P), temperature (T) and water activity (aH2O) during formation, reaction duration (t) single-stage or seque...

  10. Microstructure of selected metamorphic rock types - application of petrographic image analysis

    Czech Academy of Sciences Publication Activity Database

    Šachlová, Š.; Schenk, Vladimír; Schenková, Zdeňka


    Roč. 7, č. 4 (2010), s. 431-443 ISSN 1214-9705 R&D Projects: GA MŠk(CZ) LC506 Institutional research plan: CEZ:AV0Z30460519 Keywords : metamorphic rock * texture * structure Subject RIV: DB - Geology ; Mineralogy Impact factor: 0.452, year: 2010

  11. Dating of retrograde metamorphism in Western Carpathians by K-Ar analysis of muscovites

    International Nuclear Information System (INIS)

    Cambel, B.; Korikovskij, S.P.; Krasivskaya, I.S.; Arakelyants, M.M.


    Using the K-Ar isotope dating method of muscovites it was found that many retrogradely metamorphosed rocks are the results of Variscan retrograde metamorphism and are not pre-Cambrian or Alpine metamorphites (diaphthorites). Samples for dating were taken from the Western Carpathian crystalline formation. The content of radiogenic argon was determined by mass spectrometry using the method of isotope dilution. (M.D.)

  12. Early Cretaceous wedge extrusion in the Indo-Burma Range accretionary complex: implications for the Mesozoic subduction of Neotethys in SE Asia (United States)

    Zhang, Ji'en; Xiao, Wenjiao; Windley, Brian F.; Cai, Fulong; Sein, Kyaing; Naing, Soe


    The Indo-Burma Range (IBR) of Myanmar, the eastern extension of the Yarlung-Tsangpo Neotethyan belt of Tibet in China, contains mélanges with serpentinite, greenschist facies basalt, chert, sericite schist, silty slate and unmetamorphosed Triassic sandstone, mudstone and siltstone interbedded with chert in the east, and farther north high-pressure blueschist and eclogite blocks in the Naga Hills mélange. Our detailed mapping of the Mindat and Magwe sections in the middle IBR revealed a major 18 km antiformal isocline in a mélange in which greenschist facies rocks in the core decrease in grade eastwards and westwards symmetrically `outwards' to lower grade sericite schist and silty slate, and at the margins to unmetamorphosed sediments, and these metamorphic rocks are structurally repeated in small-scale imbricated thrust stacks. In the Mindat section the lower western boundary of the isoclinal mélange is a thrust on which the metamorphic rocks have been transported over unmetamorphosed sediments of the Triassic Pane Chaung Group, and the upper eastern boundary is a normal fault. These relations demonstrate that the IBR metamorphic rocks were exhumed by wedge extrusion in a subduction-generated accretionary complex. Along strike to the north in the Naga Hills is a comparable isoclinal mélange in which central eclogite lenses are succeeded `outwards' by layers of glaucophane schist and glaucophanite, and to lower grade greenschist facies sericite schist and slate towards the margins. In the Natchaung area (from west to east) unmetamorphosed Triassic sediments overlie quartzites, sericite schists, actinolite schists and meta-volcanic amphibolites derived from MORB-type basalt, which are in fault contact with peridotite. Olivine in the peridotite has undulatory extinction suggesting deformation at 600-700 °C, similar to the peak temperature of the amphibolite; these relations suggest generation in a metamorphic sole. The amphibolites have U/Pb zircon ages of 119

  13. Gneiss Macuira: tectonic evolution of Paleozoic metamorphic rocks of the Alta Guajira, Colombia

    International Nuclear Information System (INIS)

    Lopez I; A Julian; Zuluaga C; A, Carlos


    The Macuira Gneiss is a Paleozoic metamorphic unit that outcrops in the Simarua, Jarara and Macuira ranges, Alta Guajira. It is composed by a lithologies metamorphosed under amphibolite facies P-T conditions and consist of amphibolitic and quartz feldspathic gneisses, amphibolites, schists, pegmatites, calc-silicated rocks and marbles, with migmatization evidences in gneisses and amphibolites. Five foliations (S1-5) and three folding events (F1-3) were identified and interpreted as product of two metamorphic events, developed in a progressive barrovian metamorphic gradient of intermediate pressure with intermediate P-T ratio, interpreted as product of continental collision tectonics. This unit is important in understanding of the tectonic evolution of the Alta Guajira and Caribbean because it records different deformational phases pre-, syn- and post-migmatitic, that could be related with different tectonic episodes: the first associated with the collision between Laurasia and Gondwana (Alleghanian Orogeny - Late Paleozoic), and the second related with the Caribbean Plate evolution (Andean Orogeny - Meso-Cenozoic).

  14. Effects of the herbicide triclopyr on metamorphic northern red-legged frogs. (United States)

    Yahnke, Amy E; Grue, Christian E; Hayes, Marc P; Pearman-Gillman, Schuyler


    Aquatic herbicides are used to manage invasive emergent plants in and around wetlands. Metamorphic frogs that emerge during the aquatic weed management season may be at risk of herbicide exposure. Metamorphic northern red-legged frogs (Rana aurora) were exposed to a triclopyr tank mix labeled for control of broadleaf emergent aquatic weeds such as invasive purple loosestrife (Lythrum salicaria). The tank mix consisted of Renovate® 3 (triclopyr triethylamine salt 44.4%), the modified vegetable oil surfactant Competitor®, and the marker dye Hi-Light ® . Metamorphs were exposed to the tank mix and a clean-water control for 96 h, and then reared in clean water for 60 d. Exposure to the tank mix resulted in no treatment-related mortalities, no effects on behavior immediately post exposure, and no effects on body or liver condition indices. Exposure to the tank mix resulted in lethargy during exposure and a 1-d delay in completion of metamorphosis. Deformities present in the rearing population confounded results for some endpoints. Observed effects were minimal, especially compared with the potential for ecological impacts from unmanaged invasive plants. Environ Toxicol Chem 2017;36:2316-2326. © 2017 SETAC. © 2017 SETAC.

  15. Formation Mechanism of Surface Metamorphic Layer on Turning End Face of GH4169 Superalloy

    Directory of Open Access Journals (Sweden)

    YAO Changfeng


    Full Text Available Turning experiments and Deform-3D finite element methods were used to study the formation mechanism of surface metamorphic layer on turning GH4169 processed. The investigations were carried out by analyzing the changing of cutting force, the temperature and strain field, the residual stress, micro-hardness, microstructure, as well as the distribution of the above all along the direction of the depth under various process parameters. The results show that the surface metamorphic layer is formed due to the thermal-mechanical coupled effects on the microstructure of the material in the machining process. The cutting force, heat and strain of surface material are increased with the increase of machining intensity. Besides the higher strength of machining, the greater changes of plastic deformation, metallographic and grain deformation are acquired. In the range of processing parameters, the temperature layer is 130-200 μm,the strain layer is 100-220 μm, the residual stress layer is 80-110 μm, the depth of hardening layer is 50-80 μm, and the depth of surface metamorphic layer is 2.5-5μm.

  16. Proterozoic metamorphism and uplift history of the north-central Laramie Mountains, Wyoming, USA (United States)

    Patel, S.C.; Frost, B.R.; Chamberlain, K.R.; Snyder, G.L.


    The Laramie Mountains of south-eastern Wyoming contain two metamorphic domains that are separated by the 1.76 Ga. Laramie Peak shear zone (LPSZ). South of the LPSZ lies the Palmer Canyon block, where apatite U-Pb ages are c. 1745 Ma and the rocks have undergone Proterozoic kyanite-grade Barrovian metamorphism. In contrast, in the Laramie Peak block, north of the shear zone, the U-Pb apatite ages are 2.4-2.1 Ga, the granitic rocks are unmetamorphosed and supracrustal rocks record only low-T amphibolite facies metamorphism that is Archean in age. Peak mineral assemblages in the Palmer Canyon block include (a) quartz-biotite-plagioclase-garnet-staurolite-kyanite in the pelitic schists; (b) quartz-biotite-plagioclase-low-Ca amphiboles-kyanite in Mg-Al-rich schists, and locally (c) hornblende-plagioclase-garnet in amphibolites. All rock types show abundant textural evidence of decompression and retrograde re-equilibration. Notable among the texturally late minerals are cordierite and sapphirine, which occur in coronas around kyanite in Mg-Al-rich schists. Thermobarometry from texturally early and late assemblages for samples from different areas within the Palmer Canyon block define decompression from > 7 kbar to textures. The Proterozoic tectonic history of the central Laramie Range is similar to exhumation that accompanied late-orogenic oblique convergence in many Phanerozoic orogenic belts.


    Directory of Open Access Journals (Sweden)

    E. G. Kolomyts


    Full Text Available The paper presents a novel approach to the study of development of microstructures in snowpack based on the crystal-morphology and on the fundamental laws of natural symmetry. An empirical deterministic model describing the sublimation-metamorphic cycle in seasonal snow cover and the polymorphic variants of this cycle is suggested. Staging in the formation of crystal shapes and self-development of snow microstructure in snow layers is revealed. The crystal shapes are the result of successive process of superposition of ice crystal-chemical symmetry and dissymmetry of the soil – snow cover – atmosphere system, according to the known P. Curie principle. Morphological classification of snow crystals in seasonal snow cover is developed on the base of evolutionary model. Evolution of snow microstructure is conditioned by a marked degree by probabilistic conformity to natural laws, manifesting itself in the processes of auto-regulation of metamorphism. These processes include two types of regulation: the self-regulation of snow layers, on the one hand, and the regulation related to external conditions – under the influence of atmospheric perturbations, on the other hand. The accounting the processes of auto-regulation of snow metamorphism for allows development of new methods in short- and long-term avalanche forecast.

  18. The role of evaporites in the formation of gems during metamorphism of carbonate platforms: a review (United States)

    Giuliani, Gaston; Dubessy, Jean; Ohnenstetter, Daniel; Banks, David; Branquet, Yannick; Feneyrol, Julien; Fallick, Anthony E.; Martelat, Jean-Emmanuel


    The mineral and fluid inclusions trapped by gemstones during the metamorphism of carbonate platform successions are precious markers for the understanding of gem genesis. The nature and chemical composition of inclusions highlight the major contribution of evaporites through dissolution or fusion, depending on the temperature of formation from greenschist to granulite facies. The fluids are highly saline NaCl-brines circulating either in an open system in the greenschist facies (Colombian and Afghan emeralds) and with huge fluid-rock metasomatic interactions, or sulphurous fluids (ruby, garnet tsavorite, zoisite tanzanite and lapis-lazuli) or molten salts formed in a closed system with a low fluid mobility (ruby in marble) in the conditions of the amphibolite to granulite facies. These chloride-fluoride-sulphate ± carbonate-rich fluids scavenged the metals essential for gem formation. At high temperature, the anions SO4 2-, NO3 -, BO3 - and F- are powerful fluxes which lower the temperature of chloride- and fluoride-rich ionic liquids. They provided transport over a very short distance of aluminium and/or silica and transition metals which are necessary for gem growth. In summary, the genetic models proposed for these high-value and ornamental gems underline the importance of the metamorphism of evaporites formed on continental carbonate shelves and emphasise the chemical power accompanying metamorphism at moderate to high temperatures of evaporite-rich and organic matter-rich protoliths to form gem minerals.

  19. Core stability training for injury prevention. (United States)

    Huxel Bliven, Kellie C; Anderson, Barton E


    Enhancing core stability through exercise is common to musculoskeletal injury prevention programs. Definitive evidence demonstrating an association between core instability and injury is lacking; however, multifaceted prevention programs including core stabilization exercises appear to be effective at reducing lower extremity injury rates. PUBMED WAS SEARCHED FOR EPIDEMIOLOGIC, BIOMECHANIC, AND CLINICAL STUDIES OF CORE STABILITY FOR INJURY PREVENTION (KEYWORDS: "core OR trunk" AND "training OR prevention OR exercise OR rehabilitation" AND "risk OR prevalence") published between January 1980 and October 2012. Articles with relevance to core stability risk factors, assessment, and training were reviewed. Relevant sources from articles were also retrieved and reviewed. Stabilizer, mobilizer, and load transfer core muscles assist in understanding injury risk, assessing core muscle function, and developing injury prevention programs. Moderate evidence of alterations in core muscle recruitment and injury risk exists. Assessment tools to identify deficits in volitional muscle contraction, isometric muscle endurance, stabilization, and movement patterns are available. Exercise programs to improve core stability should focus on muscle activation, neuromuscular control, static stabilization, and dynamic stability. Core stabilization relies on instantaneous integration among passive, active, and neural control subsystems. Core muscles are often categorized functionally on the basis of stabilizing or mobilizing roles. Neuromuscular control is critical in coordinating this complex system for dynamic stabilization. Comprehensive assessment and training require a multifaceted approach to address core muscle strength, endurance, and recruitment requirements for functional demands associated with daily activities, exercise, and sport.

  20. Ultrasonic polarization measurements of elastic-anisotropic properties of metamorphized rocks on the slit of the German KTB superdeep well in the 4100-7100 m depth range (United States)

    Kovalevskiy, Mikhail


    The KTB German Superdeep Well (Germany, Windischeschenbach) has limiting depth of 9101 m. It is one of the world deepest well among the continental boreholes. A study of physical parameters including elastic ones of the massif intersected by the well allowed to represent a real pattern of changing properties and the state of crystalline rocks in upper and middle part of the Earth crust. Such a deep section enables performing analyses of large spectrum of geological and geophysical objects, such as minerals, crystalline rocks, geological strata, formation complexes et al. Recently obtained results permit to get a general idea of elastic-anisotropic properties of crystalline rocks extracted from great depths. A study of properties and state of rocks along the KTB section will make it possible to most precisely determine regular changes of the Earth's rock properties within a large range of depths. Below are the results of investigation of elastic-anisotropic properties for 13 core samples of the KTB rocks in the range of 4.1 to 7.1 km. In this interval the well has penetrated metamorphosed rocks [1]. The measurements have been done by an acoustopolarization method with recent improvements and with devices for determination of sample elastic properties [2 3]. The data obtained are the result of extended study into the KTB rock samples by the method [4]. Study of rock samples from the KTB Superdeep Well in the 4100-7100 m depth range showed that they all are elastic anisotropic and pertain to a orthorhombic symmetry type. Virtually the degree of linear acoustic anisotropic absorption (LAAA) effect has been detected in all samples. Its appearance is likely related to directional orientation of mineral grains as well as to the generation of microcracks during drilling and lithostatic stress release. The several samples showed an angular unconformity between the LAAA orientation and elastic symmetry elements. The shear waves depolarization (DSW) effect was detected in

  1. Engineering Metamorphic Chemokine Lymphotactin/XCL1 into the GAG-Binding, HIV-Inhibitory Dimer Conformation. (United States)

    Fox, Jamie C; Tyler, Robert C; Guzzo, Christina; Tuinstra, Robbyn L; Peterson, Francis C; Lusso, Paolo; Volkman, Brian F


    Unlike other chemokines, XCL1 undergoes a distinct metamorphic interconversion between a canonical monomeric chemokine fold and a unique β-sandwich dimer. The monomeric conformation binds and activates the receptor XCR1, whereas the dimer binds extracellular matrix glycosaminoglycans and has been associated with anti-human immunodeficiency virus (HIV) activity. Functional studies of WT-XCL1 are complex, as both conformations are populated in solution. To overcome this limitation, we engineered a stabilized dimeric variant of XCL1 designated CC5. This variant features a new disulfide bond (A36C-A49C) that prevents structural interconversion by locking the chemokine into the β-sandwich dimeric conformation, as demonstrated by NMR structural analysis and hydrogen/deuterium exchange experiments. Functional studies analyzing glycosaminoglycan binding demonstrate that CC5 binds with high affinity to heparin. In addition, CC5 exhibits potent inhibition of HIV-1 activity in primary peripheral blood mononuclear cells (PBMCs), demonstrating the importance of the dimer in blocking viral infection. Conformational variants like CC5 are valuable tools for elucidating the biological relevance of the XCL1 native-state interconversion and will assist in future antiviral and functional studies.

  2. U-Pb age of the Diana Complex and Adirondack granulite ...

    Indian Academy of Sciences (India)

    For the most concordant analyses, the 207Pb/206Pb ages range between 1115 and 1150 Ma. Detailed petrographic studies revealed that most grains contained at least two phases of zircon growth, either primary magmatic cores enclosed by variable thickness of metamorphic overgrowths or magmatic portions enclosing ...

  3. Thermal Structure and Tectono-Metamorphic Evolution of the Alboran Domain. New Insights From the Rif belt (Northern Morocco) and Correlations With the Betics (Southern Spain) (United States)

    Negro, F.; Beyssac, O.; Goffe, B.; Saddiqi, O.; Bouybaouene, M.


    The Betico-Rifan Cordilleras represent the western termination of the Alpine Mediterranean orogen. The internal zone of this orogen is the Alboran Domain which consists in a complex stacking of metamorphic nappes including, locally, mantle-derived bodies: the Ronda and Beni Bousera peridotites. In order to assess the tectono-metamorphic evolution of theses nappes and their relation with the underlying peridotites, we have combined RSCM (Raman spectroscopy of carbonaceous material) thermometry and P-T estimates based on chlorite-phengite local equilibria together with a careful analysis of ductile deformation. In the inner Rif, the lower units (lower Sebtides) of the Alboran Domain are directly on top of the Beni Bousera peridotites. Our study shows that peak T was reached during thinning of these units, and that heating continued after this event. A Miocene thermal imprint is also recorded at the base of the upper units of the Alboran Domain (Ghomarides) and evidenced by an increase of T coeval with resetting of K-Ar ages. Retrograde P-T paths in the HP-LT units of the Sebtide Complex also agree with this thermal structure. The units located near the peridotites experienced heating during final decompression stages whereas the more distant units underwent mostly isothermal decompression. In addition analysis of ductile deformation shows that the whole complex was exhumed in a single tectonic event characterized by N-S to NW-SE stretching and top-to-the-N senses of shear. The same approach in the equivalent units (Alpujarrides) from Western Betics evidences a very similar thermal structure over the Ronda peridotites but tectonic dismembering of the orogenic prism was stronger in the Betics compared to the Rif. Finally, analysis of these observations at orogenic scale shows that the Alboran Domain underwent a strong thermal event during the Early Miocene. This event can be interpreted as the result of ascending hot mantle units coeval with thinning of the whole

  4. Grain Boundary Sliding (GBS) as a Plastic Instability Leading to Coeval Pseudotachylyte Development in Mylonites: an EBSD Study of the Seismic Cycle in Brittle-Ductile Transition Rocks of the South Mountains Core Complex, Arizona, USA (United States)

    Miranda, E.; Stewart, C.


    Exposures of coeval pseudotachylytes and mylonites are relatively rare, but are crucial for understanding the seismic cycle in the vicinity of the brittle-ductile transition (BDT). We use both field observations and electron backscatter diffraction (EBSD) analysis to investigate the coeval pseudotachylytes and granodiorite mylonites exposed in the footwall of the South Mountains core complex, Arizona, to evaluate how strain is localized both prior to and during pseudotachylyte development at the BDT. In the field, we observe numerous pseudotachylyte veins oriented parallel to mylonitic foliation; the veins have synthetic shear sense with adjacent mylonites, and are orientation (LPO) patterns indicative of dislocation creep. Foliation-parallel zones of finely recrystallized, (clasts that also exhibit GBS traits, suggesting that pseudotachylytes form within GBS zones in mylonites. We interpret the onset of GBS as a triggering mechanism for coeval pseudotachylyte development, where the accompanying decrease in effective viscosity and increase in strain rate initiated seismic slip and pseudotachylyte formation within GBS zones. Strain became localized within the pseudotachylyte until crystallization of melt impeded flow, inducing pseudotachylyte development in other GBS zones. We associate the pseudotachylyte veins and host mylonites with the coseismic and interseismic parts of the seismic cycle, respectively, where the abundance and lateral discontinuity of pseudotachylyte veins suggests repeated events. We speculate that periodic, GBS-initiated pseudotachylyte generation may correlate with intermediate slip rate seismic events in the vicinity of the BDT, suggesting that coeval pseudotachylytes and mylonites are evidence of a unique class of seismic event.

  5. Experimental Constraints on Core Composition (United States)

    Li, J.; Fei, Y.


    complex structure of the Earth's interior, seismic investigations require extensive data coverage, sophisticated modeling and efficient data analytical methods. Deciphering geochemical core signatures carried by mantle plumes faces similar challenges. In addition, experimental and computational simulations have been hindered by the necessity to approach extreme pressure and temperature conditions prevalent in the core. For these reasons, many fundamental issues concerning the Earth's core remain controversial or poorly understood.Along with steady improvement in observational, experimental, and computational techniques, research interest in the Earth's core has been growing over the last few decades. Issues of current interest include the timing, duration, and mechanism of core formation, the identity and abundance of light elements in the core, the thermal and chemical evolution of the core, the possibility of ongoing radioactive decay in the core, evidence for continuing core-mantle interaction, structure and dynamics of the outer and inner core, and the origin, structure, and evolution of the geomagnetic field. Progress in the study of the Earth's core has been reviewed by a number of researchers with different perspectives (e.g., Stevenson, 1981; Jacobs, 1987; Jeanloz, 1990; Poirier, 1994; Hillgren et al., 2000). The aim of this chapter is to provide an updated summary of our understanding of the composition of the Earth's core, with an emphasis on experimental constraints. Another chapter focusing on cosmochemical and geochemical observations can be found in Chapter 2.15.We will start with a description of experimental and analytical techniques used in the studies of the Earth's core. Following a review of geophysical and geochemical evidence for iron being the most abundant element in the core, we will provide a summary of experimental data on the phase diagram, equation-of-state (EOS), and physical properties of iron and discuss their implications for the core

  6. Prograde and retrograde metamorphic processes in high-pressure subduction zone serpentinites from East Thessaly, Greece (United States)

    Koutsovitis, Petros


    The East Thessaly region, Central Greece, includes metaophiolitic mélange formations which extend from the eastern foothills of Mt. Olympus and Ossa, throughout the Agia basin, Mt. Mavrovouni (Sklithro region), South Pelion and reaching up to northeast Othris (regions of Aerino and Velestino). They appear in the form of dispersed and deformed thrust sheets having been variably emplaced onto Mesozoic platform series rocks of the Pelagonian tectonostratigraphic zone[1]. These formations consist mainly of serpentinites, as well as metasediments, metagabbros, metadolerites, rodingites, ophicalcites, talc-schists and chromitites. Based upon petrographic observations, mineral chemistry data and XRD patterns, the subduction zone-related serpentinites from the regions of Potamia, Anavra, Aetolofos and Kalochori-Chasanbali (Agia basin), as well as from the regions of Aerino and Velestino, are characterized by the progressive transformation of lizardite to antigorite and are distinguished into two groups. The first group includes serpentinites from the metaophiolitic formations of Potamia, Anavra, Aerino and Velestino, which are marked by destibillization of lizardite to antigorite, mostly along the grain boundaries of the lizardite mesh textured relics. The presence of lizardite and antigorite in almost equal amounts indicates medium-temperature blueschist facies metamorphic conditions (˜340-370 ° C; P≈10-11 kbar)[2,3,4]. The second serpentinite group appears in the regions of Aetolofos and Kalochori, characterized by the predominance of antigorite, the minor occurrence of lizardite and the complete replacement of spinel by Cr-magnetite. The absence of metamorphic olivine suggests that these serpentinites were most likely formed at slightly higher temperature and pressure conditions compared to the first serpentinite group, corresponding to medium or high temperature blueschist facies metamorphism (˜360-380 ° C; P≈12 kbar)[2,3,4]. These metamorphic conditions are

  7. Drilling the leading edge of the mantle wedge and the underlying metamorphic sole of the Samail Ophiolite: Hole BT1B, Oman Drilling Project (United States)

    Morishita, T.; Kelemen, P. B.; Coggon, J. A.; Harris, M.; Matter, J. M.; Michibayashi, K.; Takazawa, E.; Teagle, D. A. H.


    Hole BT1B (23°21.861' N, 58°10.957' E) was drilled by the Oman Drilling Project (OmDP) on the north side of Wadi Mansah in the Samail ophiolite, Oman. OmDP is an international collaboration supported by the International Continental Scientific Drilling Program, Deep Carbon Observatory, NSF, IODP, JAMSTEC, and the European, Japanese, German and Swiss Science Foundations, with in-kind support in Oman from the Ministry of Regional Municipalities and Water Resources, Public Authority of Mining, Sultan Qaboos University, and the German University of Technology. Hole BT1B was cored from 6 to 23 March 2017, to a depth of 300.05 m. The outer surfaces of the cores were imaged and described onsite before being curated, boxed and shipped to the IODP drill ship Chikyu. Hole BT1B sampled carbonated peridotite (listvenite), 2 carbonate-veined serpentinite bands at 80-100 and 180-185 m depth, a few cm of ultracataclasite and 70 cm of fault gouge at 197 m depth, followed by 103 m metamorphic sole. Onboard Chikyu, BT1B underwent X-ray computed tomography (CT) and multi-sensor logging, imaging and spectroscopy, macroscopic and thin section observations, physical properties measurements, and XRF, XRD and ICP-MS analyses. 1st authors of abstracts reporting initial results are Beinlich (matrix characteristics), de Obeso (modeling mass transfer), Godard (XRF and ICP-MS whole rock data), Greenberger (infrared spectroscopy), Johnson (XRF core scanner), Kelemen (overall petrology), Manning (veins), and Michibayashi (X-ray CT). Listvenite is composed of carbonate + quartz + Fe-oxyhydroxides, + minor relict spinel ± chromian mica (fuchsite). The mineralogy suggests formation at < 150°C. The bulk rock density is similar to that of gabbro but the P-wave velocity is generally higher. Rock textures suggest viscous deformation, while additional brittle deformation is recorded by older veins and younger breccias and faults. The metamorphic sole consists of fine-grained to microcrystalline

  8. Unraveling an antique subduction process from metamorphic basement around Medellín city, Central Cordillera of Colombian Andes (United States)

    Bustamante, Andres; Juliani, Caetano


    In the surroundings of Caldas and El Retiro cities (Colombia) metamorphic rocks derived from basic and pelitic protoliths comprise the Caldas amphibole schist and the Ancón schist respectively. Subordinated metamorphosed granite bodies (La Miel gneiss) are associated to these units, and The El Retiro amphibolites, migmatites and granulites crops out eastwards of these units, separated by shear zones. The Caldas amphibole schist and the Ancón schist protoliths could have been formed in a distal marine reduced environment and amalgamated to the South American continent in an apparent Triassic subduction event. The El Retiro rocks are akin to a continental basement and possible include impure metasediments of continental margin, whose metamorphism originated granulite facies rocks and migmatites as a result of the anatexis of quartz-feldspathic rocks. The metamorphism was accompanied by intense deformation, which has juxtaposed both migmatites and granulite blocks. Afterward, heat and fluid circulation associated with the emplacement of minor igneous intrusions resulted in intense fluid-rock interaction, variations in the grain size of the minerals and, especially, intense retrograde metamorphic re-equilibrium. Thermobarometric estimations for the Caldas amphibole schist indicate metamorphism in the Barrovian amphibolite facies. The metamorphic path is counter-clockwise, but retrograde evolution could not be precisely defined. The pressures of the metamorphism in these rocks range from 6.3 to 13.5 kbar, with narrow temperature ranging from 550 to 630 °C. For the Ancón schist metapelites the P- T path is also counter-clockwise, with a temperature increase evidenced by the occurrence of sillimanite and the cooling by later kyanite. The progressive metamorphism event occurred at pressures of 7.6-7.2 kbar and temperatures of 645-635 °C for one sample and temperature between 500 and 600 °C under constant pressure of 6 kbar. The temperature estimated for these rocks

  9. SHRIMP chronology of the Magallanes Basin basement, Tierra del Fuego: Cambrian plutonism and Permian high-grade metamorphism Geocronología SHRIMP del basamento de la Cuenca de Magallanes, Tierra del Fuego: plutonismo Cámbrico y metamorfismo Pérmico de alto grado

    Directory of Open Access Journals (Sweden)

    Francisco Hervé


    Full Text Available Five new SHRTMP U-Pb zircon ages are reported for gneisses and foliated plutonic rocks belonging to the Tierra del Fuego igneous and metamorphic basement complex (TFIMC, obtained from the bottom of borehole cores through the Magallanes Basin. Three of the samples yielded weighted mean 206Pb/238U ages (523±7 Ma, 522±6 Ma and 538±6 Ma, interpreted as indicating Early Cambrian igneous crystallization of the host rocks. A migmatitic gneiss shows peaks at ca. 950-1,100 Ma and 560-650 Ma from inherited zircon grains in addition to two grains with ages of ca. 525 Ma, suggesting involvement of Grenvillian and Brasiliano material in the protolith of a Cambrian migmatite. A cordierite-sillimanite-garnet gneiss contains igneous zircons of Cambrian age and a population of U-rich metamorphic Permian zircons, indicating that a Permian high-grade metamorphic and anatectic (P=2-3 kbar, T=730-770°C event affected the Cambrian igneous rocks or sedimentary rocks derived from them. Cambrian/Ediacaran plutonic rocks are known from the basement of NW Argentina, the Sierra de la Ventana, the Cape Fold Belt in South Africa, and the Ross Orogen in Antarctica. The Permian metamorphic event is coeval with the deformation and low-grade metamorphism of the sedimentary successions that overlie the basement in many of these areas. In Tierra del Fuego at least 8 to 12 km of cover rocks were removed following the high-grade Permian metamorphic episode and the unconformable deposition of the Tobífera Formation volcanic rocks in the Middle to Late Jurassic. This eroded cover could nave been an important source of detritus for the conglomeratic Permian and Triassic? Successions of neighboring regions in South America, Africa and Antarctica.Cinco nuevas edades radiométricas logradas mediante análisis U-Pb en circón utilizando el SHRIMP, fueron determinadas en gneises y rocas plutónicas foliadas obtenidas desde el fondo de pozos de sondajes en la Cuenca de Magallanes y

  10. Observations of exotic inner core waves

    NARCIS (Netherlands)

    Waszek, Lauren; Deuss, A.F.


    The seismic structure of Earth’s inner core is highly complex, displaying strong anisotropy and further regional variations. However, few seismic waves are sensitive to the inner core and fundamental questions regarding the origin of the observed seismic features remain unanswered. Thus, new

  11. Investigating the translation of Earth's inner core

    DEFF Research Database (Denmark)

    Day, Elizabeth A; Cormier, Vernon F; Geballe, Zachary M


    The Earth’s inner core provides unique insights into processes that are occurring deep within our Earth today, as well as processes that occurred in the past. The seismic structure of the inner core is complex, and is dominated by anisotropic and isotropic differences between the Eastern and West...

  12. Geochronology, geochemistry, and petrogenesis of late Permian to early Triassic mafic rocks from Darongshan, South China: Implications for ultrahigh-temperature metamorphism and S-type granite generation (United States)

    Xu, Wang-Chun; Luo, Bi-Ji; Xu, Ya-Jun; Wang, Lei; Chen, Qi


    The role of the mantle in generating ultrahigh-temperature metamorphism and peraluminous S-type granites, and the extent of crust-mantle interaction are topics fundamental to our understanding of the Earth's evolution. In this study we present geochronological, geochemical, and Sr-Nd-Hf isotopic data for dolerites and mafic volcanic rocks from the Darongshan granite complex belt in western Cathaysia, South China. LA-ICP-MS U-Pb zircon analyses yielded magma crystallization ages of ca. 250-248 Ma for the dolerites, which are coeval with eruption of the mafic volcanic rocks, ultrahigh-temperature metamorphism, and emplacement of S-type granites in the Darongshan granite complex belt. The mafic volcanic rocks are high-K calc-alkaline or shoshonitic, enriched in Th, U, and light rare earth elements, and depleted in Nb, Ta and Ti. The dolerites are characterized by high Fe2O3tot (11.61-20.39 wt%) and TiO2 (1.62-3.17 wt%), and low MgO (1.73-4.38 wt%), Cr (2.8-10.8 ppm) and Ni (2.5-11.4 ppm). Isotopically, the mafic volcanic rocks have negative whole-rock εNd(t) values (-6.7 to -9.0) and high ISr values (0.71232 to 0.71767), which are slightly depleted compared with the dolerite samples (εNd(t) = -10.3 to -10.4 and ISr = 0.71796 to 0.71923). Zircons in the dolerites have εHf(t) values of -7.6 to -10.9. The mafic volcanic rocks are interpreted to have resulted from the partial melting of an enriched lithospheric mantle source with minor crustal contamination during ascent, whereas the dolerites formed by late-stage crystallization of enriched lithospheric mantle-derived magmas after fractionation of olivine and pyroxene. The formation of these mantle-derived mafic rocks may be attributed to transtension along a NE-trending strike-slip fault zone that was related to oblique subduction of the Paleo-Pacific plate beneath South China. Such underplated mafic magmas would provide sufficient heat for the generation of ultrahigh-temperature metamorphism and S-type granites, and

  13. Animal MRI Core (United States)

    Federal Laboratory Consortium — The Animal Magnetic Resonance Imaging (MRI) Core develops and optimizes MRI methods for cardiovascular imaging of mice and rats. The Core provides imaging expertise,...

  14. Mapping contact metamorphic aureoles in Extremadura, Spain, using Landsat thematic mapper images (United States)

    Rowan, L.C.; Anton-Pacheco, C.; Brickey, D.W.; Kingston, M.J.; Payas, A.


    In the Extremadura region of western Spain, Ag, Pb, Zn, and Sn deposits occur in the pieces of late Hercynian granitic plutons and near the pluton contacts in late Proterozoic slate and metagraywacke that have been regionally metamorphosed to the green schist facies. The plutons generally are well exposed and have distinctive geomorphological expression and vegetation; poor exposures of the metasedimentary host rocks and extensive cultivation, however, make delineation of the contact aureoles difficult. Landsat Thematic Mapper (TM) images have been used to distinguish soil developed on the contact metamorphic rocks from soil formed on the stratigraphically equivalent slate-metagraywacke sequence. The mineral constituents of these soils are similar, except that muscovite is more common in the contact metamorphic soil; carbonaceous material is common in both soils. Contact metamorphic soil have lower reflectance, especially in the 1.6-micrometers wavelength region (TM 5), and weaker Al-OH, Mg-OH, and Fe3+ absorption features than do spectra of the slate-metagraywacke soil. The low-reflectance and subdued absorption features exhibited by the contact metamorphic soil spectra are attributed to the high absorption coefficient f the carbonaceous material caused by heating during emplacement of the granitic plutons. These spectral differences are evident in a TM 4/3, 4/5, 3/1 color-composite image. Initially, this image was used to outline the contact aureoles, but digital classification of the TM data was necessary for generating internally consistent maps of the distribution of the exposed contact metamorphic soil. In an August 1984, TM scene of the Caceras area, the plowed, vegetation-free fields were identified by their low TM 4/3 values. Then, ranges of TM 4/5 and 3/1 values were determine for selected plower fields within and outside the contact aureoles; TM 5 produced results similar to TM 4/5. Field evaluation, supported by X-ray diffraction and petrographic

  15. Multistage metasomatism in ultrahigh-pressure mafic rocks from the North Dabie Complex (China) (United States)

    Malaspina, Nadia; Hermann, Jörg; Scambelluri, Marco; Compagnoni, Roberto


    Release of metamorphic fluids within the slab and/or from the slab to the mantle wedge in subduction environments can produce important metasomatic effects. Ultrahigh-pressure (UHP) metasomatised rocks represent ideal materials to study the element exchange at pressures corresponding to sub-arc depths in subduction zones. We present a petrologic and geochemical study of eclogites (s.l.) from the Dabie Mountains (China). The investigated samples were collected in the North Dabie Complex, where eclogite-facies rocks are significantly overprinted by granulite-facies metamorphism and partial melting. The studied eclogites are included in meta-lherzolitic bodies, which are in turn hosted by leucocratic gneisses. The textural relations among the various rock-forming minerals enabled us to identify several re-crystallisation stages. The peak (UHP) paragenesis consists of garnet, clinopyroxene and rutile. UHP garnet and clinopyroxene display oriented inclusions of polycrystalline rods of rutile + ilmenite and of albite, K-Ba-feldspar and quartz, respectively. Garnet and clinopyroxene are both rimmed by an inclusion free zone that formed after the peak, still at high-pressure conditions. Such optical zoning does not correspond to a difference in major element concentrations between garnet core and rim. This observation provides evidence that the major element composition of garnet was reset during exhumation, thus preventing thermobarometric determination of peak metamorphic conditions. Further decompression is documented by the formation of limited ilmenite + amphibole and granulite-facies coronas consisting of clinopyroxene, orthopyroxene, plagioclase and amphibole around garnet. In order to investigate the stability of observed mineral parageneses, a series of reconnaissance piston cylinder synthesis experiments were carried out in an identical bulk composition. The experimental study indicates that the peak metamorphic paragenesis is stable at P˜3.5 GPa and T ≥ 750

  16. Geology of uranium vein deposits (including Schwartzwalder Mine) in Proterozoic metamorphic rocks, Front Range, Colorado

    International Nuclear Information System (INIS)

    Voto, R.H. de; Paschis, J.A.


    The Schwartzwalder uranium deposit is one of many uranium vein occurrences in the Lower Proterozoic metamorphic rocks of the Front Range, Colorado. The principal veins of significant uranium content occur marginal to the Colorado Mineral Belt; are localized by structural dilation zones, vein junctions, fault deflections or branching; and occur dominantly within or at the contact of certain preferred metamorphic-stratigraphic units, particularly the siliceous, garnetiferous gneisses, where these rock units are broken by faults and fractures associated with the north-northwest-trending throughgoing faults. Uranium at the Schwartzwalder mine occurs primarily as open-space brecciated vein filling along the steeply west-dipping Illinois vein and numerous east-dipping subsidiary veins where they cut preferred metamorphic host rocks that are tightly folded. Uraninite occurs with molybdenite, adularia, jordisite, ankerite, pyrite, base-metal sulphides, and calcite in vein-filling paragenetic sequence. Minor wall-rock alteration is mainly hematite alteration and bleaching. Vertical relief on the developed ore deposit is 900 metres and still open-ended at depth. No vertical zonation of alteration, vein mineralogy, density of the subsidiary veins, or ore grade has been detected. The Schwartzwalder uranium deposit is of substantial tonnage (greater than 10,000 metric tons of U 3 O 8 ) and grade (averaging 0.57% U 3 O 8 ). Structural mapping shows that the Illinois vein-fault is a Proterozoic structure. Discordant Proterozoic (suggested) and Laramide dates have been obtained from Schwartzwalder ore. The data suggest, therefore, a Proterozoic ancestry of this heretofore presumed Laramide (Late Cretaceous-Early Tertiary) hydrothermal uranium deposit. The authors suggest a polygenetic model for the origin of the Schwartzwalder uranium deposit

  17. Pressure Variations in Metamorphic Rocks: Implications for the Interpretation of Petrographic Observations (United States)

    Tajčmanová, Lucie


    Metamorphic petrologists and structural geologists, using direct measurements, bring the only direct observational constrains for validating geodynamic models. Therefore, petrological and structural geological observations are essential for the quality and reproducibility of geodynamic reconstructions and models. One of the important assumptions for geodynamic reconstructions arises from the pressure and temperature estimates in the petrology analysis. Pressure is commonly converted to depth through the equation for lithostatic pressure and so the original position of the rock sample within the Earth's interior can be constrained. The current assumption that the studied sample corresponds to uniform pressure may not be correct, and if so, it has serious implications. Increasing evidence from analytical data shows that pressure is not constant even on a grain scale, posing new challenges because, if ignored, it leads to an incorrect use of petrology data in constraining geodynamic models. Well known examples of the preservation of coesite and diamond in a host mineral like garnet show that high pressure inclusions are preserved during decompression. Tajčmanová et al. (2014) has shown that grain-scale pressure variations can develop and that these pressure variations allow compositional zoning in minerals preserved over geological time scales. A new unconventional barometric method based on equilibrium under pressure variations has been developed . Such pressure variations are also connected with differences in fluid pressure in open systems and can be thus observed at all scales. Tajčmanová L., Podladchikov Y., Powell R., Moulas E., Vrijmoed J. and Connolly J. (2014). Grain scale pressure variations and chemical equilibrium in high-grade metamorphic rocks.Journal of Metamorphic Geology, doi:10.1111/jmg.12066 This work was supported by ERC starting grant 335577 to Lucie Tajcmanova

  18. Extensional ductile tectonics of the Sioule metamorphic series (Variscan French Massif Central) (United States)

    Faure, M.; Grolier, J.; Pons, J.


    In the Northern part of the Variscan French Massif Central, the Sioule series, from top to bottom, consists of a pre-Viséan granite, migmatite, gneiss and mica schist. Two ductile deformations have been recognized. The earlier phase is characterized by a north-east-south-west trending stretching lineation; the second phase, characterized by a north-west-south-east trending mineral, stretching and crenulation lineation, is better marked in the lower mica schist part than in the upper granito-gneissic part. This second phase occurred during retrogression of the metamorphic rocks; related shear criteria indicate a top to the south-west shear. The Namurian-Westphalian magmatic bodies such as the Echassières leucogranite, Pouzol-Servant microgranite and numerous north-east -south-west trending microgranite dykes are emplaced in extensional fractures related to the same north-west-south-east maximum stretching direction. The asymmetrical shapes of the two granitic massifs indicate that they intruded towards the south-east. The synkinematic retrogression of the metamorphic rocks, the shape of the magmatic bodies and a re-examination of the numerous available data support the interpretation that the deformation is due to the extensional tectonic regime related to the Variscan crustal re-quilibration. This interpretation is in agreement with the correlation of the Sioule series with the Chavanon series. The two series belong to a unique tectono-metamorphic unit left-laterally offset by the Stephanian motion of the Sillon Houiller fault. This study also shows that the Sillon Houiller did not play a significant part during the Namurian-Westphalian extensional tectonics of the Massif Central.

  19. Ultra-high temperature granulite-facies metamorphic rocks from the Mozambique belt of SW Tanzania (United States)

    Sommer, H.; Kröner, A.


    The metamorphic rocks in the Neoproterozoic (Pan-African) Mozambique belt of southwestern Tanzania, around the town of Songea, can be subdivided into one- and two pyroxene bearing charnockitic gneisses, migmatitic granitoid gneisses and amphibolite-facies metapelites. Lower-grade amphibolite-facies rocks are rare and can be classified as sillimanite- and/or garnet-bearing metapelites. Most of the studied charnockitic gneisses show excellent corona textures with large orthopyroxene grains rimmed by clinopyroxene, followed by quartz and well developed garnet rims due to the reaction Opx + Pl = Grt + Cpx + Qtz that formed during isobaric cooling. These and other charnockitic gneisses show symplectites of orthopyroxene and An-rich plagioclase that resulted from the breakdown of garnet during isothermal decompression due to the reaction Grt + Cpx + Qtz = Opx + Pl. Geothermobarometric calculations yield up to ~ 1050 °C and up to ~ 12 kbar for peak metamorphic conditions. These are higher temperature and slightly lower pressure conditions than reported for other granulite-facies terrains in the Mozambique belt of Tanzania. Single zircon Pb-Pb evaporation and U-Pb SHRIMP ages for magmatic zircons extracted from two charnockitic and two granitic gneisses cluster in two groups, one at ~ 750 Ma and one at ~ 1150 Ma with the older reflecting the time of emplacement of the igneous precursors, and the younger approximating the time of charnockitization. These protolith ages are similar to those farther east in the Masasi area of southern Tanzania, as well as in northern Mozambique and in southern Malawi, and suggest that the Mozambique belt consists of chronologically heterogeneous assemblages whose pre-metamorphic tectonic setting remains obscure.

  20. A versatile digitally-graded buffer structure for metamorphic device applications (United States)

    Ma, Yingjie; Zhang, Yonggang; Chen, Xingyou; Gu, Yi; Shi, Yanhui; Ji, Wanyan; Du, Ben


    Exploring more effective buffer schemes for mitigating dislocation deficiencies is the key technology towards higher performance metamorphic devices. Here we demonstrate a versatile metamorphic grading structure consisting of 38-period alternated multilayers of In0.52Al0.48As and In0.82Al0.18As on InP substrate, thicknesses of which in each period were gradually varied in opposite directions from 48.7 and 1.3 nm to 1.3 and 48.7 nm, respectively, akin to a digital alloy. Both preferentially dislocation nucleation and blocking of threading dislocation transmission are observed near the In0.82Al0.18As/In0.52Al0.48As interfaces, which help relax the strain and lower the residual defect density. A 2.6 μm In0.83Ga0.17As pin photodetector is fabricated on this pseudo-substrate, attaining a low dark current density of 2.9  ×  10‑6 A cm‑2 and a high detectivity of 1.8  ×  1010 cmHz1/2W‑1 at room temperature, comparable with the states of the art that on linearly-graded buffer layers. These results indicate such digitally-graded buffer structures are promising for enhancing performances of metamorphic devices, and can be easily generalized to other lattice-mismatched material systems.

  1. Adult educators' core competences

    DEFF Research Database (Denmark)

    Wahlgren, Bjarne


    Abstract Which competences do professional adult educators need? This research note discusses the topic from a comparative perspective, finding that adult educators’ required competences are wide-ranging, heterogeneous and complex. They are subject to context in terms of national and cultural...... environment as well as the kind of adult education concerned (e.g. basic education, work-related education etc.). However, it seems that it is possible to identify certain competence requirements which transcend national, cultural and functional boundaries. This research note summarises these common or “core......” requirements, organising them into four thematic subcategories: (1) communicating subject knowledge; (2) taking students’ prior learning into account; (3) supporting a learning environment; and (4) the adult educator’s reflection on his or her own performance. At the end of his analysis of different competence...

  2. Dating by fission tracers of some metamorphic rocks within the city of Rio de Janeiro

    International Nuclear Information System (INIS)

    Fonseca, A.C.; Poupeau, G.


    Fission-Track (FT) ages were measured in apatites from metamorphic rocks outcropping within the city of Rio de Janeiro. One apatite presented a 'substraction age' of 124 + - 10 my (2σ) and a second one a 'plateau age' of 117 + - 5 my. These ages are supposed to be related to the isostatic uplift related to the opening of the South-Atlantic Ocean. A younger plateau age of 85 + - 5 my might possibly be related to a later readjustment phase. Based on these and Fonseca et al. (1984) results, a cooling history for the rocks in Rio de Janeiro city is proposed. (Author) [pt

  3. Forecast of promising areas for uranium prospection at the metamorphic Massif of Isla de la Juventud

    International Nuclear Information System (INIS)

    Gongora, L.E.; Macola, E.; Sanchez, J.; Torres, J.C.; Alaminos, C.; LLanes, A.; Morales, M.


    A mineralization conceptual model for uranium of the metamorphic Massif of Isla de la Juventud was established taking into account the study of the geological and metallogenic characteristic of the territory. The determined indications of mineralization were plotted on the geological map in order to conform a forecasting map and the selection of 22 hypothetical promising areas was carried out. As result of the field words three really promising areas were selected. A group of exploration techniques needed to evaluate the targets areas is presented

  4. Research of the chemical activity of microgrinding coals of various metamorphism degree (United States)

    Burdukov, A. P.; Butakov, E. B.; Kuznetsov, A. V.


    In this paper, we investigate the effect of mechanically activating grinding of coals of various degrees of metamorphism by two different methods - determination of the flash time in a vertical tubular furnace and thermogravimetric analysis. In the experiments, the coals that had been processed on a vibrating centrifugal mill and a disintegrator, aged for some time, were compared. The experiments showed a decrease in the ignition temperature of mechanically activated coals - deactivation of fuel, as well as the effect of mechanical activation on the further process of thermal-oxidative degradation.

  5. Uranium mineralization possibilities in metamorphic Massif of Isla de Juventud, Cuba

    International Nuclear Information System (INIS)

    Gongora Dominguez, L.E.; Llanes Castro, A.I.; Pena Fortes, B.; Capote Rodriguez, G.


    The geologic and metallogenic characteristic of the metamorphic Massif shows the presence of possible uranium vein type mineralization as a result of a hidrotermal genetic process. Metalliferous fluids rising along the fault system were responsible for the deposition of the uranium in the reduction zones, i.e. presence of pyrite, organic matter and others. This type of uranium minerization is proposed for the Bibijagua area and for the Revolucion and Lela area the same type is expected. The gamma spectrometric analysis was used to evaluate the geological samples

  6. Nanodiamond Formation at the Lithogenesis and Low-Stages of Regional Metamorphism (United States)

    Simakov, S. K.; Melnik, N. N.; Vyalov, V. I.


    Samples of gilsonite from Adzharia, anthraxolite and graphite of coal from Taimyr, shungite from Karelia, and anthracite from Donbass are studied using Raman spectroscopy. Peaks at 1600 cm-1, indicating the presence of nanographite, are recorded in all samples. The anthracite sample from Donbass, 1330 cm-1, corresponds to the sp 3-line of carbon hybridization conforming to a nanodiamond. It is concluded that in nature diamonds can be formed at late stages of lithogenesis (catagensis, metagenesis), and for coals, it can occur at the zeolite stage of regional metamorphism of rocks, before the green schist stage.

  7. On ultrahigh temperature crustal metamorphism: Phase equilibria, trace element thermometry, bulk composition, heat sources, timescales and tectonic settings

    Directory of Open Access Journals (Sweden)

    David E. Kelsey


    Full Text Available Ultrahigh temperature (UHT metamorphism is the most thermally extreme form of regional crustal metamorphism, with temperatures exceeding 900 °C. UHT crustal metamorphism is recognised in more than 50 localities globally in the metamorphic rock record and is accepted as ‘normal’ in the spectrum of regional crustal processes. UHT metamorphism is typically identified on the basis of diagnostic mineral assemblages such as sapphirine + quartz, orthopyroxene + sillimanite ± quartz and osumilite in Mg–Al-rich rock compositions, now usually coupled with pseudosection-based thermobarometry using internally-consistent thermodynamic data sets and/or Al-in-Orthopyroxene and ternary feldspar thermobarometry. Significant progress in the understanding of regional UHT metamorphism in recent years includes: (1 development of a ferric iron activity–composition thermodynamic model for sapphirine, allowing phase diagram calculations for oxidised rock compositions; (2 quantification of UHT conditions via trace element thermometry, with Zr-in-rutile more commonly recording higher temperatures than Ti-in-zircon. Rutile is likely to be stable at peak UHT conditions whereas zircon may only grow as UHT rocks are cooling. In addition, the extent to which Zr diffuses out of rutile is controlled by chemical communication with zircon; (3 more fully recognising and utilising temperature-dependent thermal properties of the crust, and the possible range of heat sources causing metamorphism in geodynamic modelling studies; (4 recognising that crust partially melted either in a previous event or earlier in a long-duration event has greater capacity than fertile, unmelted crust to achieve UHT conditions due to the heat energy consumed by partial melting reactions; (5 more strongly linking U–Pb geochronological data from zircon and monazite to P–T points or path segments through using Y + REE partitioning between accessory and major phases, as well as phase

  8. Challenges Regarding IP Core Functional Reliability (United States)

    Berg, Melanie D.; LaBel, Kenneth A.


    For many years, intellectual property (IP) cores have been incorporated into field programmable gate array (FPGA) and application specific integrated circuit (ASIC) design flows. However, the usage of large complex IP cores were limited within products that required a high level of reliability. This is no longer the case. IP core insertion has become mainstream including their use in highly reliable products. Due to limited visibility and control, challenges exist when using IP cores and subsequently compromise product reliability. We discuss challenges and suggest potential solutions to critical application IP insertion.

  9. Investigating the translation of Earth's inner core

    DEFF Research Database (Denmark)

    Day, Elizabeth A; Cormier, Vernon F; Geballe, Zachary M


    The Earth’s inner core provides unique insights into processes that are occurring deep within our Earth today, as well as processes that occurred in the past. The seismic structure of the inner core is complex, and is dominated by anisotropic and isotropic differences between the Eastern...... in the inner core and apply mineral physics models for the evolution of grain size to estimate likely changes in seismic properties throughout the inner core. We then compare these predictions to the observations of seismic studies that target two regions that are highly sensitive to the translation...

  10. Death Valley turtlebacks: Mesozoic contractional structures overprinted by Cenozoic extension and metamorphism beneath syn-extensional plutons

    International Nuclear Information System (INIS)

    Pavlis, T L; Serpa, L; Miller, M


    -thrust belts. Our work to the east of Death Valley suggests these thrusts were part of a NW trending thrust system that overprinted an older NE trending fold-thrust system that tracks into the Death Valley region from Nevada. These NW trending thrusts probably underlie all of the southern Black Mountains (south of the turtlebacks) and we suggest that pre-extensional structural relief along these basement thrusts placed basement at shallow crustal levels throughout what is now the Black Mountains; a conclusion consistent with the absence of rocks younger than Cambrian beneath Tertiary unconformities throughout the southern Death Valley region. In Late Miocene time, a major detachment system formed and the turtlebacks represent a mid-crustal shear zone developed during that time period, but this system is older, and structurally beneath younger detachments systems that comprise the Amargosa fault system. During motion on the detachment, an ∼2km thick plutonic sheet was emplaced along the shear zone forming the Miocene plutonic assemblages of the Black Mountains, and produced upper amphibolite facies metamorphic assemblages along the floor of the pluton in what are now the Copper Canyon and Mormon Point turtlebacks, but the Badwater Turtleback escaped this metamorphism due to a different structural position. Motion continued along the floor of the pluton but syn-extensional folding produced structural relief along folds with axes parallel to the extension direction. Ultimately a new detachment system cut obliquely across the older extensional system, removing the roof of the pluton, but cutting down to its floor in the turtlebacks. This fault system formed a complex detachment system updip in the famous 'Amargosa Chaos', and removing the entire cover sequence from the Black Mountains (∼10-12km of crustal section). The turtlebacks are therefore a composite structure in which extension contemporaneous with folding, presumably as a result of distributed transcurrent motion

  11. Dynamic recrystallization and metamorphic evolution of ca. 1.85 Ga quartzofeldspathic and cordierite-garnet gneisses, western Gyeonggi Massif, Korea (United States)

    Cho, Moonsup; Yang, Soh-young; Kim, Taehwan; Yi, Keewook


    Quartzofeldspathic orthogneisses together with cordierite-garnet gneisses occur in the Mt. Cheonggye area, western Gyeonggi Massif, where the transition from weakly-deformed gneiss to mylonite is revealed. These gneisses consist primarily of biotite, garnet, K-feldspar, plagioclase, and quartz with or without sillimanite (or kyanite) and cordierite. Microstructures in mylonites and gneisses were investigated to delineate the relationship between dynamic recrystallization and pressure-temperature (P-T) path, based on field and petrologic studies. For constraining the timing of deformation and metamorphism, zircon and monazite were dated using a sensitive high-resolution ion microprobe (SHRIMP) housed at the Korea Basic Science Institute. Recrystallization microstructures systematically vary in accordance with the degree of strain in weakly- to intensely-deformed gneisses or mylonites. Quartz shows the subgrain rotation (SGR) to grain boundary migration (GBM) recrystallization such as the ribbon structure, and K-feldspar is characterized by the core-and-mantle structure together with occasional development of myrmekite. Some isolated grains of K-feldspar appear to be the product of the solution-precipitation growth. Plagioclase was recrystallized by SGR and high-T GBM, forming fine-grained polygonal aggregates in weakly- and moderately-deformed gneisses. With increasing strain, plagioclase grains are connected with each other to form the interconnected weak layer. The microstructures described in the above suggest the deformation temperatures of ca. 490-650°C. Mineral assemblages and reaction textures in cordierite-garnet gneisses suggest a clockwise P-T path, evolving from the kyanite- to sillimanite-stable fields. The SHRIMP U-Th-Pb analyses of zircon and monazite in both cordierite-garnet gneisses and orthogneisses yielded the Paleoproterozoic metamorphic ages of ca. 1.86-1.85 Ga. Some zircons are overgrown by low Th/U rims dated at ca. 240-220 Ma. Monazite

  12. Eclogite Facies Relicts and Decompression Assemblages; Evidence for the Exhumation of a Large Coherent Metabasite Block From > 40 km Depth; Central Metamorphic Terrane, Eastern Klamath Mountains, Northern California (United States)

    Barrow, W. M.; Fairhurst, R. J.; Metcalf, R. V.


    Recent exhumation models for eclogite terranes have focused on the exhumation of sialic rocks. Exhumed high pressure terranes are typically > 85% - 90% sialic material with only minor amounts of mafic and ultramafic rock. Most known metabasitic eclogites are blocks in mélange rather than large coherent bodies. The Central Metamorphic terrane (CMt) is a large (~300 km3) coherent, fault-bounded package of metabasites thought to represent a remnant of a downing plate subducted in an intra-oceanic convergent margin. Thermochronology indicates that the CMt was metamorphosed and later accreted to the base of the Trinity ophiolite along the Trinity fault during Early Permian extension (Hbl and Musc 40Ar/39Ar ages of 275 Ma - 294 Ma). Previous work suggested that the peak metamorphic temperatures and pressures were ~650°C and 0.4 to 0.8 GPa (Peacock and Norris, 1989) which is consistent with the amphibolite facies mineral assemblage. Trace element data confirm the NMORB-like composition of CMt metabasite protoliths. Newly discovered relict textures, however, suggest that CMt amphibolites record much deeper subduction burial with subsequent decompression exhumation. A decompression sequence consisting of rutile cores within ilmenite crystals mantled by titanite is observed in CMt amphibolite samples. Zr-in-rutile thermometry (Watson et al., 2006) combined with experimental data for rutile stability in metabasites (Ernst and Lui, 1998) suggests that relict rutile crystals preserve early P-T conditions of ~600°C and > 1.3 GPa consistent with eclogite facies metamorphism. Transition from eclogite facies is further supported by ilmenite-plagioclase-amphibole symplectites suggesting replacement of garnet (Bhowmik and Roy, 2003) during decompression. Amphibole compositions vary significantly and reflect lower grade (low Na, Al, Ti actinolite) overprint of earlier amphibolite facies compositions (high Na, Al, Ti magnesio- hornblende). Application of the Al-Ti hornblende

  13. Advantages of iron core in a tokamak

    International Nuclear Information System (INIS)

    Bettis, E.S.; Ballou, J.K.; Becraft, W.R.; Peng, Y.K.M.; Watts, H.L.


    A quantitative comparison of the iron core vs air core concepts was carried out on a preliminary basis by using a representative tokamak reactor design with the following self-consistent reference parameters. In the area of plasma engineering, poloidal field and MHD equilibrium considerations with an unsaturated iron core is discussed. The question of proper poloidal field coils to maintain D-shaped plasmas of relatively high anti β (7%) with a saturated iron core is also discussed. Estimates of the required iron core size, volt seconds, magnetic flux and its influence on force loading on the superconducting toroidal field coils are shown. Conceptual designs of the mechanical structure of an iron core device are presented. Favorable impacts on the OH power supply cost and complexity are indicated

  14. One Health Core Competency Domains

    Directory of Open Access Journals (Sweden)

    Rebekah Frankson


    Full Text Available The emergence of complex global challenges at the convergence of human, animal, and environmental health has catalyzed a movement supporting ‘One Health’ approaches. Despite recognition of the importance of One Health approaches to address these complex challenges, little effort has been directed at identifying the seminal knowledge, skills and attitudes necessary for individuals to successfully contribute to One Health efforts. Between 2008 and 2011, three groups independently embarked on separate initiatives to identify core competencies for professionals involved with One Health approaches. Core competencies were considered critically important for guiding curriculum development and continuing professional education as they describe the knowledge, skills and attitudes required to be effective. A workshop was convened in 2012 to synthesize the various strands of work on One Health competencies. Despite having different mandates, participants, and approaches, all of these initiatives identified similar core competency domains: management; communication and informatics; values and ethics; leadership; teams and collaboration; roles and responsibilities; and systems thinking. These core competency domains have been used to develop new continuing professional education programs for One Health professionals and help university curricula prepare new graduates to be able to contribute more effectively to One Health approaches.

  15. The metamorphic basement of the southern Sierra de Aconquija, Eastern Sierras Pampeanas: Provenance and tectonic setting of a Neoproterozoic back-arc basin (United States)

    Cisterna, Clara Eugenia; Altenberger, Uwe; Mon, Ricardo; Günter, Christina; Gutiérrez, Antonio


    The Eastern Sierras Pampeanas are mainly composed of Neoproterozoic-early Palaeozoic metamorphic complexes whose protoliths were sedimentary sequences deposited along the western margin of Gondwana. South of the Sierra de Aconquija, Eastern Sierras Pampeanas, a voluminous metamorphic complex crops out. It is mainly composed of schists, gneisses, marbles, calk-silicate schists, thin layers of amphibolites intercalated with the marbles and granitic veins. The new data correlate the Sierra de Aconquija with others metamorphic units that crop out to the south, at the middle portion of the Sierra de Ancasti. Bulk rock composition reflects originally shales, iron rich shales, wackes, minor litharenites and impure limestones as its protoliths. Moreover, comparisons with the northern Sierra de Aconquija and from La Majada (Sierra de Ancasti) show similar composition. Amphibolites have a basaltic precursor, like those from the La Majada (Sierra de Ancasti) ones. The analyzed metamorphic sequence reflects low to moderate weathering conditions in the sediments source environment and their chemical composition would be mainly controlled by the tectonic setting of the sedimentary basin rather than by the secondary sorting and reworking of older deposits. The sediments composition reveal relatively low maturity, nevertheless the Fe - shale and the litharenite show a tendency of minor maturity among them. The source is related to an acid one for the litharenite protolith and a more basic to intermediate for the other rocks, suggesting a main derivation from intermediate to felsic orogen. The source of the Fe-shales may be related to and admixture of the sediments with basic components. Overall the composition point to an upper continental crust as the dominant sediment source for most of the metasedimentary rocks. The protolith of the amphibolites have basic precursors, related to an evolving back-arc basin. The chemical data in combination with the specific sediment association

  16. Structure and tectonic evolution of the southwestern Trinidad dome, Escambray complex, Central Cuba: Insights into deformation in an accretionary wedge (United States)

    Despaigne-Díaz, Ana Ibis; García Casco, Antonio; Cáceres Govea, Dámaso; Wilde, Simon A.; Millán Trujillo, Guillermo


    The Trinidad dome, Escambray complex, Cuba, forms part of an accretionary wedge built during intra-oceanic subduction in the Caribbean from the Late Cretaceous to Cenozoic. The structure reflects syn-subduction exhumation during thickening of the wedge, followed by extension. Field mapping, metamorphic and structural analysis constrain the tectonic evolution into five stages. Three ductile deformation events (D1, D2 and D3) are related to metamorphism in a compressional setting and formation of several nappes. D1 subduction fabrics are only preserved as relict S1 foliation and rootless isoclinal folds strongly overprinted by the main S2 foliation. The S2 foliation is parallel to sheared serpentinised lenses that define tectonic contacts, suggesting thrust stacks and underthrusting at mantle depths. Thrusting caused an inverted metamorphic structure with higher-grade on top of lower-grade nappes. Exhumation started during D2 when the units were incorporated into the growing accretionary wedge along NNE-directed thrust faults and was accompanied by substantial decompression and cooling. Folding and thrusting continued during D3 and marks the transition from ductile to brittle-ductile conditions at shallower crustal levels. The D4-5 events are related to extension and contributed to the final exhumation (likely as a core complex). D4 is associated with a regional spaced S4 cleavage, late open folds, and numerous extension veins, whereas D5 is recorded by normal and strike-slip faults affecting all nappes. The P-t path shows rapid exhumation during D2 and slower rates during D3 when the units were progressively incorporated into the accretionary prism. The domal shape formed in response to tectonic denudation assisted by normal faulting and erosion at the surface during the final stages of structural development. These results support tectonic models of SW subduction of the Proto-Caribbean crust under the Caribbean plate during the latest Cretaceous and provide

  17. Fluid-driven metamorphism of the continental crust governed by nanoscale fluid flow (United States)

    Plümper, Oliver; Botan, Alexandru; Los, Catharina; Liu, Yang; Malthe-Sørenssen, Anders; Jamtveit, Bjørn


    The transport of fluids through the Earth's crust controls the redistribution of elements to form mineral and hydrocarbon deposits, the release and sequestration of greenhouse gases, and facilitates metamorphic reactions that influence lithospheric rheology. In permeable systems with a well-connected porosity, fluid transport is largely driven by fluid pressure gradients. In less permeable rocks, deformation may induce permeability by creating interconnected heterogeneities, but without these perturbations, mass transport is limited along grain boundaries or relies on transformation processes that self-generate transient fluid pathways. The latter can facilitate large-scale fluid and mass transport in nominally impermeable rocks without large-scale fluid transport pathways. Here, we show that pervasive, fluid-driven metamorphism of crustal igneous rocks is directly coupled to the production of nanoscale porosity. Using multi-dimensional nano-imaging and molecular dynamics simulations, we demonstrate that in feldspar, the most abundant mineral family in the Earth's crust, electrokinetic transport through reaction-induced nanopores (mediated mineral transformation reactions can be considerably influenced by nanofluidic transport phenomena.

  18. The metamorphic basement of the Cordillera Frontal of Mendoza: New geochronologic and isotopic data

    International Nuclear Information System (INIS)

    Basei, Miguel; Ramos, Victor A.; Vujovich, Graciela I.; Poma, Stella


    The metamorphic rocks of the Cordillera Frontal exposed in the Cordon del Portillo, Mendoza were examined by Rb/Sr geochronology and Nd/Sm isotopic analysis. The Rb/Sr data defined a Devonian age for the last metamorphic episode, similar to the previous K/Ar and Ar/Ar ages obtained in this region and western Precordillera. The isotopic analysis identified three sets of model ages: 1.- The oldest corresponds to a set of meta sedimentary rocks with a model age of 1,400 to 1,700 Ma; 2.- A monzogranodiorite with a model age of 1,000 Ma; and 3.- Metabasites with model ages between 577 and 330 Ma. These rocks are interpreted as 1.- A typical Grenvillian derived basement; 2.- Late Paleozoic granitoids derived from a different Proterozoic basement; and 3.- Some Eopaleozoic metabasites tectonically inter fingered with the Grenvillian basement. These new data are coherent with the existence of a Laurentia derived terrane, Chilenia, that was separated by oceanic rocks from the basement of Pre cordillera during Eopaleozoic times. This last basement known as the Cuyania terrane, was also derived from Laurentia. (author)

  19. Complex analysis

    CERN Document Server

    Freitag, Eberhard


    The guiding principle of this presentation of ``Classical Complex Analysis'' is to proceed as quickly as possible to the central results while using a small number of notions and concepts from other fields. Thus the prerequisites for understanding this book are minimal; only elementary facts of calculus and algebra are required. The first four chapters cover the essential core of complex analysis: - differentiation in C (including elementary facts about conformal mappings) - integration in C (including complex line integrals, Cauchy's Integral Theorem, and the Integral Formulas) - sequences and series of analytic functions, (isolated) singularities, Laurent series, calculus of residues - construction of analytic functions: the gamma function, Weierstrass' Factorization Theorem, Mittag-Leffler Partial Fraction Decomposition, and -as a particular highlight- the Riemann Mapping Theorem, which characterizes the simply connected domains in C. Further topics included are: - the theory of elliptic functions based on...

  20. k -core covers and the core

    NARCIS (Netherlands)

    Sanchez-Rodriguez, E.; Borm, P.; Estevez Fernandez, M.A.; Fiestras-Janeiro, M.G.; Mosquera, M.A.


    This paper extends the notion of individual min