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Sample records for metales pesados pb

  1. Metales pesados (Pb, Cd, Cr y Hg en población general adulta próxima a una planta de tratamiento de residuos urbanos de Bizkaia

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    Miren Begoña Zubero Oleagoitia

    2008-01-01

    Full Text Available Fundamento: Entre las posibles emisiones de una planta de valorización energética de residuos sólidos urbanos (PVERSU se encuentran los metales pesados. el objetivo del estudio es conocer los niveles en sangre y orina de metales pesados en población general de Bizkaia. Métodos: En 2006 se midió la exposición a Pb en 95 muestras de sangre y Cd, Cr y Hg en 93 muestras de orina de adultos de la población general de Bizkaia, País Vasco, obtenidas de dos áreas con alta densidad de tráfico del área metropolitana de Bilbao en la cercanía de una PVERSU que iniciaba su actividad, una tercera correspondiente a una zona urbana de Bilbao con tráfico denso y alejada del área de influencia de las posibles emisiones de la PVERSU y la cuarta alejada de la planta y con baja densidad de tráfico. De cada área se estableció como objetivo elegir a un mínimo 20 participantes, la mitad de cada sexo y, a su vez, la mitad de 20 a 44 años y la mitad de 45 a 69. Se utilizó la prueba de la c2 para estudiar la asociación entre variables categóricas. Como prueba de comparación de medias se utilizó la t de Student y la ANOVA para variables con dos o más categorías, respectivamente. Para ajustar factores de confusión se utilizó un modelo de regresión lineal múltiple. Resultados: Las concentraciones medias fueron PbS: 2,68 ¿g/100ml, CdU 0,54 ug/g creatinina, CrU: 0,51 uig/g creatinina, y HgU: 0,65 ug/g creatinina. Conclusión: No se observaron diferencias entre las zonas. El análisis unifactorial y multifactorial mostró que los niveles de PbS se incrementaban con la edad y estaban asociados con el consumo de productos locales de huerta y con el trabajo en la metalurgia. La edad eleva los niveles de CdU y se observa en clases sociales altas niveles más elevados, así como en mujeres y en personas fumadoras. Los niveles de CrU eran más elevados en zonas alejadas a la PVERSU y en las clases altas. Los niveles de HgU fueron más elevados en

  2. METALES PESADOS EN SUELOS DE PLANTACIONES DE CACAO (Theobroma cacao L.) EN TRES REGIONES DEL PERÚ

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    Arévalo-Gardini, Enrique; Instituto de Cultivos Tropicales, (ICT), Tarapoto, Perú.; Obando-Cerpa, Meyier E.; Instituto de Cultivos Tropicales, (ICT), Tarapoto, Perú.; Zúñiga-Cernades, Luis B.; Instituto de Cultivos Tropicales, (ICT), Tarapoto, Perú.; Arévalo-Hernández, Cesar O.; Instituto de Cultivos Tropicales, (ICT), Tarapoto, Perú.; Baligar, Virupax; U.S. Department of Agriculture/Agricultural Research Service, Beltsville Agricultural Research Center, Beltsville, MD 20705, U.S.A.; He, Zhenli; Indian River Research and Education Center (IRREC), University of Florida, Fort Pierce, Fl 34945, U.S.A.

    2016-01-01

    El cacao ha tenido un crecimiento significativo en los últimos años en el Perú y la presencia de metales pesados en los suelos de estas plantaciones es un potencial problema para las exportaciones de este producto. El objetivo del presente estudio fue determinar los contenidos totales de metales pesados (Cd, Ni, Pb, Fe, Cu, Zn, Mn) en los suelos de plantaciones de cacao en las principales áreas de producción del Perú: Zona Norte (Tumbes, Piura, Cajamarca y Amazonas); Zona central (San Martín,...

  3. Neurotoxicidad de los metales pesados: plomo, mercurio, aluminio

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    Tostado Martín, Elena

    2014-01-01

    Este trabajo muestra las consecuencias para la salud en la población que sufre una exposición aguda o crónica a metales pesados. Más concretamente, se centra en la afectación del sistema nervioso central y su desarrollo tras la exposición al plomo, el mercurio y el aluminio. Esta revisión comienza con una breve introducción en la que se explica detalladamente las propiedades de cada metal pesado enunciado anteriormente, seguido de un breve repaso epidemiológico acerca de los pa...

  4. Calidad seminal y toxicidad de metales pesados y plaguicidas

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    Lidia Mínguez-Alarcón; Jaime Mendiola Olivares; Alberto Manuel Torres-Cantero

    2014-01-01

    La función reproductiva masculina se ha visto deteriorada significativamente en los últimos 50 años y dicha alteración podría estar relacionada con la exposición a diferentes tóxicos y contaminantes ocupacionales y ambientales. El objetivo de este trabajo es resumir el impacto de la exposición humana a metales pesados y plaguicidas sobre la función reproductiva masculina. La mayoría de los plaguicidas y metales pesados se consideran tóxicos reproductivos y podrían afectar negativamente al sis...

  5. Riesgo por metales pesados en horticultura urbana Heavy metals risk in urban agriculture

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    Lidia Giuffré

    2005-07-01

    Full Text Available La agricultura urbana y periurbana puede implicar riesgos para la salud humana si no es adecuadamente manejada. El objetivo de esta contribución fue presentar un relevamiento de metales pesados en suelos hortícolas de Buenos Aires. La información se comparó con estandares de calidad nacionales e internacionales, y se calcularon factores de enriquecimiento con referencia a estandares holandeses. Con respecto a la corteza terrestre, el Cd. Pb, Cu y Zn se incrementaron. Los factores medios y máximos de enriquecimiento fueron mayores para Cu, Pb, Cd y Zn. Los suelos hortícolas urbanos y periurbanos deben ser cuidadosamente monitoreados considerando el riesgo de entrada de metales en al cadena alimenticia.Urban and periurban agriculture may imply risks for human health if it is not appropriately conducted. The objective of this contribution was to present a survey of heavy metal content in horticultural soils of Buenos Aires. The information is compared to national and international quality standards, and enrichment factors for heavy metals were calculated with reference to Dutch values. With reference to earth crust, Cd, Pb, Cu and Zn were increased. Mean and maximum enrichment factors were higher for Cu, Pb, Cd and Zn. Horticultural urban and periurban soils must be carefully monitored considering risk of metal input in food chain.

  6. Monitoreo por exposición a metales pesados

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    Bautista Gómez, Ronald Sixto

    2012-01-01

    En el Laboratorio Químico Toxicológico y Clínico del Centro Nacional de Salud Ocupacional y Protección del Ambiente para la Salud (CENSOPAS) del Instituto Nacional de Salud, se realiza la determinación de metales pesados y de otros metabolitos implicados en la contaminación, ya sea en muestras de sangre u orina de la población o en muestras ambientales.

  7. Concentración de metales pesados (Cu, Ni, Zn, Cd, Pb en la biota y sedimentos de una playa artificial, en la bahía San Jorge 23°S, norte de Chile Heavy metals concentration (Cu, Ni, Zn, Cd, Pb, in biota and sediments of an artificial beach, in San Jorge bay 23°S, northern Chile

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    Gabriel Castro

    2012-07-01

    Full Text Available Se evaluó el contenido de metales pesados (Cu, Ni, Zn, Cd, Pb en la biota y el sedimento de una playa artificial (Paraíso y una playa natural (El Lenguado, ubicadas en la bahía San Jorge, norte de Chile. Los resultados fueron utilizados para comparar ambos sistemas, el grado de cumplimiento de la normativa ambiental nacional e internacional, y el efecto de la construcción de la playa artificial sobre el nivel de contaminación por metales existentes históricamente en esa zona. En cada playa se ubicaron estaciones equidistantes que abarcaron desde el intermareal hasta el submareal de las cuales fueron extraídos los organismos. Se tomaron muestras de sedimento en cada playa y se determinaron las pendientes con el método de Emery. El análisis granulométrico evidenció el predominio de arena media en playa El Lenguado, y arena media y fina en playa Paraíso. El contenido de materia orgánica fue mayor en El Lenguado. En playa Paraíso se determinaron cinco phylum/superclase agrupados en 19 taxa, mientras que en El Lenguado se encontraron cuatro phylum/superclase agrupados en cc taxa. El contenido de metales en sedimentos y en la mayoría de organismos presentó valores mayores en playa Paraíso. Estos resultados, junto a las normas de calidad chilenas y norteamericanas, sugieren un evidente deterioro en la calidad ambiental de playa Paraíso lo que se demostró por un incremento en las concentraciones de estos metales desde su construcción, los que sobrepasan los límites establecidos por ambas normas.It was evaluated the heavy metal content (Cu, Ni, Zn, Cd, Pb in biota and sediment of an artificial beach (Paraíso and a natural beach (El Lenguado, both located in San Jorge bay, northern Chile. The results were used to compare both systems, the degree of fulfillment of national and international environmental regulations, and the effect of the construction of the artificial beach on the level of metal contamination historically existing in

  8. Metales pesados en hongos de areas contaminadas Heavy metals in wild mushrooms from contaminated areas

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    A. Moyano

    2010-01-01

    Full Text Available Los hongos, saprobios y micorrícicos, desempeñan un papel importante en los eco­sistemas forestales, en especial en los ciclos biogeoquímicos. Los saprobios actúan en los procesos de degradación y mineraliza­ción de la materia orgánica, mientras que los micorrícicos son esenciales en la adquisi­ción y translocación de los nutrientes a las plantas huéspedes. En lugares contaminados por metales pesados la simbiosis micorrícica confiere resistencia a la plantas; en algunos casos se ha demostrado que plantas infecta­das pueden sobrevivir más fácilmente a la contaminación que las no micorrizadas. El micelio secuestra la fracción asimilable de los metales pesados disminuyendo la trans­locación a las plantas. Los cuerpos fructífe­ros de los hongos son consumidos por una gran cantidad de animales y también por el hombre. Algunas setas silvestres tienen un alto valor nutricional y son un recurso natu­ral con un valor económico importante. Sin embargo, la acumulación de metales pesa­dos por los hongos puede representar un riesgo para la salud tanto para humanos como para otros seres vivos. Suelos, hongos y hojarasca fueron mues­treados en una zona contaminada con meta­les pesados en las proximidades de una mina de Pb-Zn (Cd, actualmente abando­nada (Loma Charra, Soria. Los contenidos de metales en suelos, hojarascas y hongos indican un elevado grado de contaminación en relación a áreas cercanas, utilizadas como control, no afectadas por actividad minera. En el suelo los contenidos de Zn: 797-3540 mg/kg, Cd: 2,1-10 mg/kg y Pb: 1485-8166 mg/kg, en hojarasca (Zn: 92­1475 mg/kg; Cd 0,9-4,2 mg/kg; Pb: 54­2756 mg/kg y en setas (Zn 118-915 mg/kg; Cd: 1,2-45,2 mg/kg y Pb 12-1475 mg/kg. Los factores de bioacumulación indican alto riesgo medioambiental.Saprotroph and mycorrhizal fungi play an important role in forest ecosystem, particu­lary in the biogeochemical cycles. Sapro­ troph fungi are crucial for degradation of the

  9. Calidad seminal y toxicidad de metales pesados y plaguicidas

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    Lidia Mínguez-Alarcón

    2014-06-01

    Full Text Available La función reproductiva masculina se ha visto deteriorada significativamente en los últimos 50 años y dicha alteración podría estar relacionada con la exposición a diferentes tóxicos y contaminantes ocupacionales y ambientales. El objetivo de este trabajo es resumir el impacto de la exposición humana a metales pesados y plaguicidas sobre la función reproductiva masculina. La mayoría de los plaguicidas y metales pesados se consideran tóxicos reproductivos y podrían afectar negativamente al sistema reproductivo masculino debido al efecto alterador sobre el eje hipotálamo-pituitario-gonadal, o directamente afectando a la espermatogénesis, dando lugar a una alteración de la calidad seminal. Los efectos negativos de estos compuestos se han relacionado con los principales parámetros espermáticos (concentración, morfología y movilidad normal, volumen seminal y recuento total espermático, alteración del ADN espermático, así como con cambios en los niveles de hormonas reproductivas. El uso de algunas de estas sustancias ya está prohibido mientras que se continúa comercializando con otras. Sería recomendable una legislación más severa que impida cualquier exposición a este tipo de tóxicos debido a su confirmado efecto perjudicial sobre la salud reproductiva masculina.

  10. Metais pesados em amostras biológicas de bovinos Heavy metals in cattle biological samples

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    Maria Verônica de Souza

    2009-09-01

    Full Text Available O objetivo deste trabalho foi determinar a concentração de metais pesados no sangue (Pb, Ni e Cd, soro (Cu e Zn, pelo e leite (Pb, Ni, Cd, Cu e Zn de bovinos criados em área industrializada (com siderúrgicas e não-industrial do Estado de Minas Gerais, em amostras coletadas em duas épocas (inverno e verão, buscando avaliar a contaminação em animais em função do ambiente de exposição e da estação do ano. O local de criação dos animais afetou significativamente somente a concentração de Cu obtida nas amostras de soro, com maiores valores determinados no grupo de bovinos da região industrializada. A época de amostragem afetou a concentração dos metais Cu (soro, Zn (soro e leite, Pb (sangue e Cd (sangue e pelo, com as determinações efetuadas no verão proporcionando maiores teores do que as executadas no inverno, à exceção do Cd avaliado no pelo. Interações significativas (PThe aim of this research was to determine the heavy metals concentration in blood (Pb, Ni and Cd, serum (Cu and Zn, hair and milk (Pb, Ni, Cd, Cu and Zn of cattle raised in industrial (with steel mill and non-industrial areas in Minas Gerais, Brazil. The samples were collected during summer and winter, aiming to verify animals contamination related to environment and year season. The environment significantly influenced the concentration of Cu obtained on serum samples, with higher values for cattle from the industrialized area. The sampling time affected the concentration of Cu (serum, Zn (serum and milk, Pb (blood and Cd (blood and hair, with higher values for summer, except for Cd measured on hair. Meaningful interactions (P<0.05 between environment and year season were identified for Cu (hair and milk, Zn (hair and Ni (serum, hair and milk. The results obtained show that the presence of steel mills in a determined area does not mean, necessarily that higher concentration of heavy metals will be found in cattle biological matrices. The seasonality

  11. Evaluation of the heavy metals Cr, Mn, Fe, Cu, Zn and Pb in water penny wort (Hydrocotyle ranunculoides) from the upper course of the Lerma River, Mexico; Evaluacion de los metales pesados Cr, Mn, Fe, Cu, Zn y Pb en sombrerillo de agua (Hydrocotyle ranunculoides) del curso alto del Rio Lerma, Mexico

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    Zarazua, G.; Avila P, P.; Tejeda, S. [ININ, Carretera Mexico-Toluca s/n, 52750 Ocoyoacac, Estado de Mexico (Mexico); Valdivia B, M.; Macedo M, G. [Instituto Tecnologico de Toluca, Av. Tecnologico s/n, Ex-Rancho La Virgen, 52140 Metepec, Estado de Mexico (Mexico); Zepeda G, C., E-mail: graciela.zarazua@inin.gob.mx [Universidad Autonoma del Estado de Mexico, Cerro de Coatepec s/n, Ciudad Universitaria, 50100 Toluca, Estado de Mexico (Mexico)

    2013-07-01

    The Lerma river is one of the most polluted water bodies in Mexico, it presents low biodiversity and lets grow up aquatic plants resistant to the pollution. The aim of this work was to evaluate the concentration and bioaccumulation factors of Cr, Mn, Fe, Cu, Zn and Pb in aerial and submerged structures of water penny wort (Hydrocotyle ranunculoides) from the upper course of the Lerma river. Inductively coupled plasma-optical emission spectrometry was used to determine the concentration of heavy metals in water and H. ranunculoides. Results show that the bioaccumulation factors of Fe and Zn were higher than those of Cu, Mn, Cr and Pb; with the exception of Zn, bioaccumulation factors were higher in the submerged structures of the plant, which shows low mobility of analyzed metals. As a result of this study H. ranunculoides can be considered as good indicator of metal pollution in water bodies. (Author)

  12. Total concentration and speciation of heavy metals in biosolids from urban origin; Concentracion total y especiacion de metales pesados en biosolidos de origen urbano origin

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    Gonzalez Flores, Eduardo [Laboratorio de Ingenieria Ambiental, Instituto Tecnologico de Puebla, Puebla, Puebla (Mexico)]. E-mail: egonz1962@yahoo.com.mx; Tornero Campante, Mario Alberto [Colegio de Postgraduados - Campus Puebla, San Pedro Cholula, Puebla (Mexico); Angeles Cruz, Yolanda [Laboratorio de Ingenieria Ambiental, Instituto Tecnologico de Puebla, Puebla, Puebla (Mexico); Bonilla y Fernandez, Noemi [Departamento de Agroecologia y Ambiente, Instituto de Ciencias - Benemerita Universidad Autonoma de Puebla, Puebla, Puebla (Mexico)

    2009-02-15

    The analysis of heavy metals is a very important task to asses the potential environmental and health risk associated with biosolids deposition in agricultural soil. However, it is widely accepted that determination of total concentration of heavy metals does not give an accurate estimation of the potential environmental impact. So, it is necessary to apply speciation studies to obtain suitable information about their bioavailability. This study was carried out on sewage sludge samples collected in a municipal waste-water treatment plant, located in Puebla City (Mexico). They are used for amendment agricultural soil. The speciation of heavy metals (Cd, Cr, Cu, Ni, Pb and Zn) was made using a sequential extraction procedure. The aim was to determine their concentration in bioavailability fractions. It was got the total concentration of heavy metals using acid digestion in a closed system and was determined with atomic absorption spectrometry. The total concentrations of heavy metals were lower than that established by Mexican legislation. The heavy metals are mainly associated with the mineral fraction and organic matter and consequently they show low bioavailability. [Spanish] El analisis de metales pesados es una actividad importante cuando se quiere valorar el potencial riesgo ambiental y de salud asociado con la utilizacion de biosolidos en suelos agricolas. Sin embargo, es ampliamente aceptado que la determinacion del contenido total no da una valoracion apropiada del impacto ambiental causado. Por lo tanto, es necesario realizar estudios de especiacion para obtener informacion mas detallada sobre su biodisponibilidad. Este estudio se llevo a cabo con muestras de lodos residuales producidos en una planta de tratamiento de aguas residuales ubicada en la ciudad de Puebla (Mexico). Estos biosolidos son utilizados para enmendar suelos agricolas. La especiacion de metales pesados (Cd, Cr, Cu, Ni, Pb y Zn) se realizo usando un procedimiento de extraccion secuencial

  13. Adsorción de metales pesados en andisoles, vertisoles y ácidos húmicos

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    Luis Enrique Cortés Páez

    2015-01-01

    Full Text Available Se estudió la adsorción de los metales pesados cadmio (Cd, cobre (Cu, níquel (Ni, plomo (Pb y zinc (Zn en Andisoles (Typic Melanudand y Vertisoles (Epiaquert ústico arcilloso fino isohipertérmico 1% de Colombia y en ácidos húmicos (AH extraídos de muestras de leonardita tomadas en España. En todos los casos se determinaron las propiedades químicas y físicas: pH, capacidad de intercambio catiónico (CIC, carbono orgánico (%CO, bases intercambiables y contenido total de metales. La composición química de los AH se determinó empleando técnicas espectrométricas como ICP_MS, FTIR, UV-Vis, CPMAS 13C NMR y Py-GC/MS-THMA. Los resultados de adsorción de los metales ajustados al modelo de Freundlich mostraron un comportamiento diferente de los adsorbentes en relación con los metales estudiados, siendo la máxima capacidad de adsorción (K y la fuerza de retención (n de los metales diferente (P Pb > Cu > Ni > Zn; en Andisol: Pb > Cu > Cd > Zn > Ni; y en Vertisol: Cd > Pb > Cu > Ni > Z. Para n en ácidos húmicos: Pb > Zn > Cd > Cu > Ni; en Andisol: Cu > Ni > Zn > Pb > Cd, y en Vertisol: Zn > Ni > Cu > Pb > Cd.

  14. Extracciones quimicas secuenciales de metales pesados. Aplicacion en ciencias geologicas

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    Mandado Collado, J. M.

    2002-12-01

    de extracción secuencial diferentes, sin haberse impuesto todavía uno de ellos como un método estándar plenamente aceptado. Las fracciones de metales pesados que comúnmente se suelen diferenciar en los sólidos mediante este tipo de metodologías son: intercambiable, asociada a carbonatos, asociada a óxidos Fe y Mn, asociada a materia orgánica y fracción residual. Los distintos protocolos existentes difieren en los reactivos empleados y también en las condiciones experimentales, todo ello dependiendo de los objetivos concretos del estudio a realizar. Las extracciones secuenciales han encontrado unos campos de aplicación muy amplios en las ciencias geológicas, sobre todo en los estudios de geoquímica ambiental en medios acuáticos (ríos, lagos, estuarios, en edafología y también en hidrología subterránea. Los protocolos de extracción secuencial adolecen, en conjunto, de una serie de problemas metodológicos de cierta envergadura y que han sido abordados por distintos autores, pudiendo destacar entre ellos la selectividad de los reactivos empleados, la propia definición operativa de estos métodos, la redistribución (o readsorción elemental, las condiciones experimentales bajo las que se pueden ejecutar los protocolos, la escasez de materiales sólidos de referencia y, derivados de este último problema, la dificultad de validación de los distintos métodos y la evaluación de su precisión. A pesar de todos estos inconvenientes metodológicos, los procedimientos de extracción secuencial constituyen en la actualidad la mejor aproximación para describir la asociación geoquímica de los elementos traza con las diferentes fracciones de los sólidos.

  15. Metales pesados en hongos de areas contaminadas Heavy metals in wild mushrooms from contaminated areas

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    A. Moyano; A. García Sánchez; L.M. Fernández Toirán; E. Charro

    2010-01-01

    Los hongos, saprobios y micorrícicos, desempeñan un papel importante en los eco­sistemas forestales, en especial en los ciclos biogeoquímicos. Los saprobios actúan en los procesos de degradación y mineraliza­ción de la materia orgánica, mientras que los micorrícicos son esenciales en la adquisi­ción y translocación de los nutrientes a las plantas huéspedes. En lugares contaminados por metales pesados la simbiosis micorrícica confiere resistencia a la plantas; en algunos casos se ha demostrado...

  16. Presencia de metales pesados en cultivo de cacao (Theobroma cacao L. orgánico

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    Hugo Alfredo Huamaní-Yupanqui

    2012-12-01

    Full Text Available La presencia de metales pesados en el cultivo de cacao (Theobroma cacao L. es actualmente un grave problema para agricultores y cooperativas de las regiones Huánuco y Ucayali, Perú. En el presente trabajo se evaluaron los contenidos de cadmio y plomo en suelos y hojas del cacao en estas regiones. Para el efecto se recolectaron y analizaron en laboratorio muestras tomadas en 22 parcelas con cultivos orgánicos de esta especie, 17 en la región Huánuco y cinco en la región Ucayali. Se realizaron análisis de correlación de Pearson entre los contenidos de plomo y cadmio disponibles en el suelo con variables foliares (P, Mg, Ca, Zn, Cd, Pb y del suelo (arena, arcilla y K. En los suelos, sólo en el caso de potasio se presentan deficiencias; mientras que en el tejido foliar se presentaron deficiencias de N, P, K, Mg y Zn. Los valores promedio de cadmio y plomo disponible en los suelos fueron 0.53 y 3.02 ppm y en las hojas de cacao de 0.21 y 0.58 ppm respectivamente.

  17. Uso del ácido etilendiaminotetraacético para evaluar la biodisponibilidad de metales pesados en lechuga

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    Y. Cordero,

    2009-01-01

    Los metales pesados se acumularon principalmente en el sistema radical de las plantas, con posibilidades de ser traslocados posteriormente hacia las hojas y acumularse en ellas, luego de culminar su ciclo vegetativo.

  18. SALES SOLUBLES Y METALES PESADOS EN SUELOS TRATADOS CON BIOSÓLIDOS

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    E. Robledo- Santoyo

    2010-01-01

    Full Text Available Las plantas de tratamientos de aguas residuales (PTAR generan diariamente toneladas de lodos (biosólidos, los cuales pueden tener un uso agrícola como fuente de nutrientes y material mejorador del suelo, aunque también pueden ser fuente de contaminación por metales pesados y sales solubles. En este estudio se evaluó, en un suelo representativo de la zona de influencia de la PTAR de la ciudad de Aguascalientes, México, la aplicación de biosólidos y el efecto de su contenido de metales pesados y sales solubles en el suelo y plantas de pasto ballico, con la finalidad de establecer su aprovechamiento agrícola sin riesgo potencial de degradación y contaminación de suelos y plantas. Se hizo una caracterización química de los biosólidos y los suelos estudiados. Los biosólidos presentaron pH ligeramente ácido, alto contenido en sales solubles y concentración de metales pesados dentro de los límites máximos permisibles según la NOM-004-SEMARNAT-2002, por lo que se les puede dar uso agrícola. Dosis crecientes de biosólidos incorporados al suelo no presentaron efectos en éste, en cuanto a acumulación de metales pesados, pero sí se incrementó el contenido de sales solubles, y con dosis superiores a 80 t·ha-1 se llegó a niveles que pueden reducir el rendimiento de la mayoría de cultivos.

  19. Evaluation of the air quality regarding total suspended particles and heavy metals (Pb, Cd, Ni, Cu, Cr) in the Hermosillo city, Sonora, Mexico, during a yearly period; Evaluacion de la calidad del aire respecto de particulas suspendidas totales y metales pesados (Pb, Cd, Ni, Cu, Cr) en la Ciudad de Hermosillo, Sonora, Mexico, durante un periodo anual

    Energy Technology Data Exchange (ETDEWEB)

    Cruz C, M. E.; Quintero N, M. [Universidad Autonoma de Baja California, Instituto de Ingenieria, Campus Mexicali, Calle de la Normal s/n, y Blvd. Benito Juarez, Col. Insurgentes Este, Mexicali, Baja California (Mexico); Gomez A, A.; Varela S, J., E-mail: martincruzcampas@hotmail.com [Universidad de Sonora, Departamento de Ingenieria Quimica y Metalurgia, Blvd. Rosales y Luis Ensina s/n, Edificio 5B, Col. Centro, 83000 Hermosillo, Sonora (Mexico)

    2013-07-01

    In the present study, the air quality of the city of Hermosillo, Sonora, Mexico was assessed considering total suspended particulates (tsp) and heavy metals (Pb, Cd, Ni, Cu, Cr) from June 2001 through May 2002 in three monitoring sites Centro (Mazon), Nor este (CESUES) and Noroeste (CBTIS). The filter-samples used for that purpose were provided by the Air Quality Evaluation and Improvement Program (PEMCA) of the municipality of Hermosillo. The sampling method was based on high volume sampling frequency set every 6 days with non-simultaneous sampling among the three sampling sites. Filters were dissolved for metal determination by acidic-extraction, and then analyzed by flame atomic absorption spectrophotometry. Results indicate that tsp concentrations at Centro and Noroeste sites were frequently higher than the maximum daily permissible level (260 {mu}g/m{sup 3}), while in the three sites the annual average was higher than the maximum annual permissible level (75 {mu}g/m{sup 3}) both established in the standard NOM-024-Ssa-1993 (Ssa 1994a). According to the Air Quality Standard Index (US EPA 1992a), used in Mexico by Air Quality Metropolitan Index (IMECA) the results indicate that the air quality in the city of Hermosillo regarding tsp was placed between no satisfactory and poor. In regard to heavy metals (Pb, Cd, Ni, Cu, Cr), concentrations detected were below the maximum permissible levels and/or criteria taking into account the standard NOM-026-Ssa-1993 (Ssa 1994b), the Who criterion (2000), the European Union criterion (Cec 2003), and the European Environmental Agency criteria (EEA 2004). Such findings would mean that airborne metals are of no concern; however, air quality is still classified as no satisfactory due to high particulate matter concentrations. Keeping air quality parameters monitoring is recommended in order to get extensive data for use in risk studies of air quality and health (morbidity/mortality), as well as topographic conditions

  20. Riesgo de contaminación de leche de vaca con metales pesados en los estados de Puebla y Tlaxcala, México

    OpenAIRE

    Castro González, Numa Pompilio

    2017-01-01

    La presente investigación tuvo como objetivo determinar el riesgo de contaminación con metales pesados en la leche producida por vacas alimentadas con alfalfa, siguiendo su posible fuente de contamiancion desde los suelos agrícolas irrigados con aguas residuales procedentes de zonas urbanas y de la industria, en la sub cuenca del Alto Balsas en los estados de Puebla y Tlaxcala, México. Para conseguir este objetivo se determinó el contenido Cd, Pb, Ni, Cu, Co, Cr, Zn y As en agu...

  1. Uso de bacterias sulfato-reductoras inmovilizadas para la precipitación de metales pesados

    OpenAIRE

    Vicente, Mariana Soledad

    2006-01-01

    Los objetivos de la tesis son: utilizar bacterias sulfato-reductoras para la precipitación de metales pesados; caracterizar el crecimiento de bacterias del género Desulfovibrio en distintas condiciones de cultivo; caracterizar la precipitación de iones metálicos por bacterias del género Desulfovibrio en cultivos batch; caracterizar el crecimiento de bacterias del género Desulfovibrio inmovilizadas sobre diferentes soportes inerte; caracterizar la precipitación de iones metálicos con bacterias...

  2. Presencia de metales pesados en cultivo de cacao (Theobroma cacao L.) orgánico

    OpenAIRE

    Hugo Alfredo Huamaní-Yupanqui; Miguel ángel Huauya-Rojas; Luis Germán Mansilla-Minaya; Nelino Florida-Rofner; Gilmer Milton Neira-Trujillo

    2012-01-01

    La presencia de metales pesados en el cultivo de cacao (Theobroma cacao L.) es actualmente un grave problema para agricultores y cooperativas de las regiones Huánuco y Ucayali, Perú. En el presente trabajo se evaluaron los contenidos de cadmio y plomo en suelos y hojas del cacao en estas regiones. Para el efecto se recolectaron y analizaron en laboratorio muestras tomadas en 22 parcelas con cultivos orgánicos de esta especie, 17 en la región Huánuco y cinco en la región Ucayali. Se realizaron...

  3. La corteza de pino como adsorbente natural de metales pesados en suelos contaminados

    OpenAIRE

    Cutillas Barreiro, Laura

    2017-01-01

    La contaminación de suelos por metales pesados se está convirtiendo en una preocupación ambiental en las últimas décadas debido al incremento de las actividades industriales y al progreso de la agricultura, que pueden provocar que se eleven sus concentraciones hasta niveles potencialmente fitotóxicos, provocando una pérdida de la calidad del suelo y limitando su uso. Esto también puede afectar a la calidad de las aguas, tanto superficiales como freáticas, ampliando así el impac...

  4. Susceptibility of Arcobacter butzleri to heavy metals Sensibilidade de Arcobacter butzleri a metais pesados

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    Laura Otth

    2005-09-01

    Full Text Available The susceptibility of 50 strains of Arcobacter butzleri isolated from chicken liver [12], mussels [18], river water [6] and bovine [5], duck [2] and pelicans [7] feces to mercury (Hg, chromium (Cr, silver (Ag, nickel (Ni, cobalt (Co, iron (Fe, manganese (Mn, molybdenum (Mo and lead (Pb was determined.All the strains were resistant to Mo, Mn, Ni, Co, Pb and Fe and susceptible to Hg, Ag and Cr. MIC values showed high variability, indicating a non homogeneous behavior among the strains.Arcobacter butzleri é um bacilo Gram negativo de caráter zoonótico, pertencente à Família Campylobacteraceae, que tem sido associado a diarréia e septicemia no ser humano. A susceptibilidade de 50 amostras de A. butzleri isoladas de fígados de frango [12], mariscos [18], água de rio [6] e fezes de bovinos [5], patos [2] e pelicanos [7] aos metais pesados mercúrio (Hg, cromo (Cr, prata (Ag, níquel (Ni, cobalto Co, ferro (Fe, manganês (Mn, molibdênio (Mo e chumbo (Pb foi determinada.Todas as amostras foram resistentes a Mo, Mn, Ni, Co, Pb e Fe, sendo susceptíveis a Hg, Ag e Cr. Os valores das CIM apresentaram alta variabilidade indicando um comportamento não homogêneo entre as amostras.

  5. Concentración, enriquecimiento y distribución de metales pesados en sedimentos de la bahía de Tánger, Marruecos

    OpenAIRE

    Rodríguez-Barroso, María Rocío; Benhamou, Youssef; El Moumni, Bouchta; Coello, Dolores; García-Morales, José Luis

    2010-01-01

    Se ha investigado la distribución y acumulación de metales pesados en sedimentos superficiales de la bahía de Tánger, Marruecos. Se tomaron 11 muestras de sedimentos superficiales ubicadas en la bahía de Tánger durante el año 2007 y se analizaron los metales (Fe, Mn, Cr, Cu, Ni, Pb, Zn y Cd), materia orgánica y distribución granulométrica. El estado de contaminación por metales de la bahía, se evaluó mediante el cálculo del factor de enriquecimiento (EF) y en general mostró bajo enriquecimien...

  6. Distribución de metales pesados en los sedimentos superficiales del Saco del Golfo de Cariaco, Sucre, Venezuela

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    María Valentina Fuentes H

    2010-10-01

    Full Text Available El Golfo de Cariaco es un ecosistema marino con mucha productividad primaria, lo que le confiere especial importancia ecológica y socioeconómica. Sin embargo, los desechos de las actividades antropogénicas son descargados directamente o arrastradas por las escorrentías. El objetivo de este estudio fue determinar la distribución de cadmio, cobre, plomo, manganeso, níquel y zinc en las fracciones geoquímica de los sedimentos superficiales, usando el método modificado de extracción secuencial de la Comunidad Europea (BCR. Las concentraciones de los metales fueron medidas por espectroscopía de absorción atómica. Además, se compararon los contenidos de metales intercambiables y asociados a los carbonatos determinados por el procedimiento BCR modificado con los determinados por el método de Campanella. La recolección de muestras se hizo en 12 estaciones del sector oriental del Golfo de Cariaco, Estado Sucre, específicamente en el sector conocido como el Saco, en junio 2007. Las metodologías aplicadas fueron evaluadas usando un material de referencia certificado de sedimentos marino (HISS - 1. Los resultados indicaron que los métodos proveen exactitud y precisión adecuadas para la extracción de metales. Las concentraciones totales (μg g-1 fueron, Cd: < límite de detección (LD-5.0; Pb: 1.79- 60.41; Cu: no detectado (ND-42.18; Zn: 25.13-104.57; Mn: 66.31-80.29 y Ni: 3.29-24.58. Cd, Cu, Ni y Pb excedieron en varias estaciones los límites que pueden afectar la biota, establecidos por la Guía de Evaluación de la Calidad de los Sedimentos de Canadá. El cadmio fue el metal identificado como el más móvil, teniendo las más altas concentraciones como intercambiable y asociado a las fracciones de carbonatos. Sin embargo, Pb, Cu, Mn y Zn mostraron su mayor abundancia en la fracción asociada a materia orgánica y azufre. Los métodos no presentan diferencias significativas para extraer la primera fracción. Se encontraron

  7. Contenido de metales pesados en agua y sedimento en el bajo Nanay

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    Víctor Sotero Solís

    2013-06-01

    Full Text Available Se presenta en este estudio la evaluación de la concentración de metales pesados en agua  y mercurio en sedimentos del rio Nanay, s realizó el muestreo desde el caserío Libertad, hasta su desembocadura en el rio Amazonas, en las épocas de creciente y vaciante del año 2011. La cuenca del rio Nanay comprende 340 km2 s y alberga a cuatro comunidades nativas y ocho campesinas y además tiene influencia sobre los distritos de San Juan, Iquitos y Punchana, además de ser la fuente de agua potable para la población de estos distritos. Los análisis de metales pesados se realizaran utilizando la técnica de la absorción atómica en el laboratorio de Sustancias Naturales Bioactivas del Instituto de Investigaciones de la amazonia Peruana (IIAP. Según los resultados de añiláis de agua el plomo y mercurio se encuentran presentes sen concentraciones mayores que lo indicado por las normas nacionales. El plomo tanto en creciente es en promedio de 0,111 ppm y 0,053 ppm respectivamente y el mercurio en vaciante se encuentra en 0,008 ppm Del mismo modo la presencia de mercurio es alta en los sedimentos que acompañan a este rio con 1,636 ppm en creciente y 3,03 ppm en vaciante.

  8. Contenido de metales pesados en agua y sedimento en el bajo Nanay

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    Victor Sotero Solís

    2013-06-01

    Full Text Available Se presenta en este estudio la evaluación de la concentración de metales pesados en agua y mercurio en sedimentos del rio Nanay, s realizó el muestreo desde el caserío Libertad, hasta su desembocadura en el rio Amazonas, en las épocas de creciente y vaciante del año 2011. La cuenca del rio Nanay comprende 340 km2 s y alberga a cuatro comunidades nativas y ocho campesinas y además tiene influencia sobre los distritos de San Juan, Iquitos y Punchana, además de ser la fuente de agua potable para la población de estos distritos. Los análisis de metales pesados se realizarán utilizando la técnica de la absorción atómica en el laboratorio de Sustancias Naturales Bioactivas del Instituto de Investigaciones de la Amazonia Peruana (IIAP. Según los resultados de añiláis de agua el plomo y mercurio se encuentran presentes sen concentraciones mayores que lo indicado por las normas nacionales. El plomo tanto en creciente es en promedio de 0,111 ppm y 0,053 ppm respectivamente y el mercurio en vaciante se encuentra en 0,008 ppm Del mismo modo la presencia de mercurio es alta en los sedimentos que acompañan a este rio con 1,636 ppm en creciente y 3,03 ppm en vaciante.

  9. Evaluación de metales pesados en los suelos del coto minero manganesífero Cristo -Barrancas

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    Pedro S. Bergues-Garrido

    2011-09-01

    Full Text Available Se estudiaron muestras de suelo de la antigua mina de manganeso Cristo-Barrancas y áreas adyacentes para evaluar el contenido de metales pesados (Cd, Ni, Pb, Co, Zn, Cu y Cr atendiendo a que, en la actualidad, algunos de estos suelos se dedican al cultivo de plantaciones para el consumo humano y animal. Se calcularon los índices de geoacumulación y de carga de polución, así como el factor de enriquecimiento y el grado de contaminación. Los resultados revelaron contaminación moderada por Cd, Co y Cu en ambas zonas y una ligera contaminación por Ni en el área de la mina. El empleo adicional de los estándares holandeses (lista ABC corroboró los niveles de contaminación obtenidos, al encontrarse los valores resultantes para el Cd, Co, Cu y Ni entre el nivel de referencia A y el nivel de contenido máximo admisible B; asimismo los resultados de la evaluación de los índices y estándares holandeses indicaron que, prácticamente, no existe contaminación por Pb, Cr y Zn. La contaminación moderada, principalmente por Cd, puede invalidar los suelos para el cultivo de hortalizas y viandas debido a la capacidad que tienen estos vegetales para absorber y acumular el cadmio en sus hojas, bulbos y tubérculos, los que al ser ingeridos pueden ocasionar daños a la salud.

  10. Aplicación de un material vitrocerámico a la biorremediación de metales pesados

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    García, A. M.

    2004-02-01

    Full Text Available In this study, a glassceramic material with hydroxyapatite phase was manufactured from industrial and urban wastes. On this material, biofilms from the microorganisms usually appearing in wastewater were developed. Batch assays were made using different heavy metals to analyze glassceramic material capacity to retain these elements from an aqueous medium in biofilm presence and absence. The results suggest that microorganisms are implicated in the removing of heavy metals from the aqueous medium and open the possibility to use the glassceramic material in a bioremediation process.

    En este trabajo se elaboró un material vitrocerámico conteniendo la fase de hidroxiapatita, partiendo de residuos industriales y urbanos. Sobre la superficie del material se desarrollaron biopelículas de los microorganismos que aparecen habitualmente en las aguas residuales. Se hicieron ensayos de retención usando distintos metales pesados para evaluar la capacidad del material de eliminar tales elementos de un medio acuoso en presencia y ausencia de la biopelícula. Los resultados ponen de manifiesto la participación microbiana en los procesos de eliminación de los metales pesados del medio acuoso y ofrecen la posibilidad de utilizar el material vitrocerámico en un proceso de biorremediación de aguas contaminadas por metales pesados.

  11. Manifestaciones cutáneas como parámetro de teratogenicidad en la intoxicación con metales pesados Cutaneous signs as parameter in teratogenicity by heavy metal intoxication

    OpenAIRE

    N L Pauza; M J Pérez Cotti; M L Godar; Y Sopena; A M Ferramola de Sancovich; H A Sancovich

    2007-01-01

    Se estudiaron los efectos teratogénicos de metales pesados (acetatos de Cd2+ y Pb2+ y sulfato de Cu2+), en embriones de pollo en desarrollo, después de la administración de una monodosis del metal. Los huevos embrionados fueron inyectados en la yema en el día 12 de incubación. Las concentraciones de los iones fueron (nmoles/g huevo): Cd2+: Dosis 1 (D1): 0,16 y Dosis 2 (D2): 0,32; Pb2+: D1: 8,0 y D2: 16,0 y Cu2+: D1: 1,7 y D2: 3,3. Los resultados se evaluaron después de continuar la incubación...

  12. Isotermas de sorção de metais pesados em solos do cerrado de Goiás Sorption isotherm of heavy metals in soils of 'Cerrado' of Goiás

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    Luiz F. C. Oliveira

    2010-07-01

    Full Text Available A contaminação do solo e das águas subterrâneas por metais pesados é, extremamente perniciosa por serem basntante persistentes no ambiente. Objetivou-se, com este trabalho, a análise da sorção do Cu, Cr, Zn, Cd, Pb e Ni em Latossolo Vermelho Acriférrico (LVwf, Argissolo Vermelho Eutrófico (PVe, Nitossolo Vermelho Eutroférrico (NVef e Neossolo Quartzarênico (RQ pelos modelos potencial e linear da isoterma Freundlich. Para o estabelecimento de isotermas de sorção adicionaram-se a 5,0 mL de solo e 50,0 mL de solução contendo o metal pesado a ser avaliado com diferentes concentrações, respeitando-se os limites aceitáveis. As isotermas de sorção potencial e linear apresentaram bom ajuste para descrever o comportamento de adsorção dos metais pesados nas diferentes classes de solo estudadas. A sequência da retenção dos metais pesados em ordem decrescente, foi, para: o PVe: Cr+3 > Cr+6 > Ni+2 > Zn+2 > Cu+2 > Pb+2 > Cd+2; o LVwf: Cr+3 > Cr+6 > Ni+2 > Cu+2 > Cd+2 > Zn+2 > Pb+2; o RQ: Cr+6 > Cr+3 >Cu+2 > Pb+2 > Ni+2 > Zn+2 > Cd+2 e, para, o NVef: Cr+3 > Cr+6 > Pb+2 > Cu+2 > Zn+2 > Ni+2 >Cd+2. O RQ foi a classe de solo que apresentou menor retenção de metais em comparação com as demais classes de solo sendo, portanto, mais vulnerável à contaminação de águas subterrâneas.The contamination of soil and groundwater by heavy metals is extremely damaging due to high persistence of heavy metals in the environment. This work targeted the analysis of the sorption in Oxisol Typic Acrustox(LVwf, Ultisol (PVe, Kandic Oxisol (NVef and Quartzipsamment (RQ of heavy metals Cu, Cr, Zn, Cd, Pb and Ni. The sorption of the heavy metals in the soil was evaluated by batch method and described by potential and linear models of the Freundlich isotherm. For the establishment the of sorption isotherm, 50.0 mL of solution containing the heavy metal were added in 5.0 mL of soil, assessing with different concentrations within the acceptable soil

  13. Contenido de metales pesados en pescados comercializados en Iquitos, Nauta y Requena

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    Dora García de Sotero

    2013-06-01

    Full Text Available En este trabajo se presenta la evaluación de la concentración de metales pesados en el músculo de los  pescados colectados en los mercados de las ciudades de Iquitos (Cuenca del Ríos Amazonas; Nauta (Cuenca del Río Marañón y Requena (Cuenca del Río Ucayali en el año 2011. Para la muestra de cada lugar se consideró cinco individuos por cada especie. La metodología empleada para la determinación de Hierro, Cobre, Plomo, Cadmio, Cromo y Cinc fue el método de espectrofotometría de absorción atómica (EEA, y para la determinación de Mercurio se efectuó por la EEA acoplado la Cámara de vapor frio.  De acuerdo a los resultados se observó que en todas las especies estudiadas de las Cuencas de los Ríos Amazonas y Marañón, tanto en creciente como en vaciante, superaron los límites máximos permisibles con respecto a la acumulación de plomo y cromo comparados con los Límites Máximos Permisibles reportados por las Normas Internacionales. Para las especies de la Cuenca del Río Ucayali, en creciente algunas especies (lisa, boquichico y paco pasaron el límite máximo permisible con respecto a la acumulación de cromo; pero en vaciante todas las especies pasaron ese límite. Con respecto al mercurio, ninguna de las especies en estudio, de las tres Cuencas pasaron el límite máximo permisible cuando fueron comparados con los valores reportados por las Normas Internacionales.

  14. Contenido de metales pesados en pescados comercializados en Iquitos, Nauta y Requena

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    Dora García de Sotero

    2013-06-01

    Full Text Available En este trabajo se presenta la evaluación de la concentración de metales pesados en el músculo de los pescados colectados en los mercados de las ciudades de Iquitos (Cuenca del Ríos Amazonas; Nauta (Cuenca del Río Marañón y Requena (Cuenca del Río Ucayali en el año 2011. Para la muestra de cada lugar se consideró cinco individuos por cada especie. La metodología empleada para la determinación de Hierro, Cobre, Plomo, Cadmio, Cromo y Cinc fue el método de espectrofotometría de absorción atómica (EEA, y para la determinación de Mercurio se efectuó por la EEA acoplado la Cámara de vapor frio.  De acuerdo a los resultados se observó que, en todas las especies estudiadas de las Cuencas de los Ríos Amazonas y Marañón, tanto en creciente como en vaciante, superaron los límites máximos permisibles con respecto a la acumulación de plomo y cromo comparados con los Límites Máximos Permisibles reportados por las Normas Internacionales. Para las especies de la Cuenca del Río Ucayali, en creciente algunas especies (lisa, boquichico y paco pasaron el límite máximo permisible con respecto a la acumulación de cromo; pero en vaciante todas las especies pasaron ese límite. Con respecto al mercurio, ninguna de las especies en estudio, de las tres Cuencas pasaron el límite máximo permisible cuando fueron comparados con los valores reportados por las Normas Internacionales.

  15. Evaluación de metales pesados en los sedimentos superficiales del río Pirro Evaluation of heavy metals in superficial sediments of Pirro river

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    Jacqueline Herrera Núñez

    2013-03-01

    Full Text Available Los metales pesados tienen una importante fuente en las actividades de origen antropogénico y constituyen un peligro para la biota acuática y el ser humano y un factor de deterioro de la calidad hídrica y ambiental. Los sedimentos ribereños, uno de los principales reservorios de estos elementos, actúan como fuentes secundarias de contaminación de los cuerpos de agua, por lo que resulta importante evaluar la concentración de metales como una herramienta que permite rastrear el origen de los contaminantes en el medio y predecir los impactos que pueden producir en los ecosistemas acuáticos. En el presente trabajo se analizó por espectrofotometría de absorción atómica la concentración de Cd, Ag, Se, Sn, Ni, Cr, Cu, B, Zn, Hg, Ba, Pb, Mn, As y Al en los sedimentos superficiales del sector medio del río Pirro (Heredia, Costa Rica. Las concentraciones de estos elementos fueron muy elevadas para la mayoría de las sustancias analizadas en todos los puntos de muestreo seleccionados. Su distribución no fue homogénea, ni presentó un patrón geográfico marcadamente definido, pudiéndose encontrar altos niveles distribuidos a lo largo del transecto estudiado.Anthropogenic activities are important sources of heavy metals, which are dangerous for the aquatic biota and the human being and a factor of environmental and water quality deterioration. The sediments, one of the main reservoirs of these elements, act as secondary resources of contamination of the rivers; this is why it is important to evaluate the concentration of metals, as a tool that allows to track the origin of the contaminants in the environment and to predict their impact on the aquatic ecosystems. In the present study, the concentration of Cd, Ag, Se, Sn, Ni, Cr, Cu, B, Zn, Hg, Ba, Pb, Mn, As and Al was determined in the superficial sediments of the medium sector of Pirro River (Heredia, Costa Rica by using atomic absorption spectrophotometry. The concentrations of these

  16. CONTENIDO DE METALES PESADOS EN ABONOS ORGÁNICOS, SUSTRATOS Y PLANTAS CULTIVADAS EN ORGANOPÓNICOS

    OpenAIRE

    Mirelys Rodríguez Alfaro; Olegario Muñiz Ugarte; Bernardo Calero Martín; Alfredo Montero Álvarez; Francisco Martínez Rodríguez; Teudys Limeres Jiménez; Mercedes Orphee Montoya; Adriana M. de Aguilar Accioly

    2012-01-01

    La utilización de abonos orgánicos (AO) de diversos orígenes, como los compost obtenidos a partir de residuales sólidos urbanos (RSU), en organopónicos de la agricultura urbana, es una alternativa para la producción de alimentos con bajos insumos. Para el uso de estos productos, se requiere una evaluación sistemática de sus contenidos en metales pesados (MP), porque pueden acumularse en los suelos y sustratos, alterar el equilibrio biológico de los mismos y afectar al rendimiento de los cult...

  17. Detección de metales pesados en bovinos, en los valles de los rios Sinú y San Jorge, departamento de Córdoba, Colombia

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    Aura Madero G

    2011-04-01

    Full Text Available Objetivo. Evaluar la presencia de metales pesados: plomo(Pb, cobre (Cu, cadmio (Cd y mercurio (Hg en hígado y músculo pectoral derecho de bovino, procedentes de fincas de la zona del Sinú y San Jorge. Materiales y métodos. Se muestrearon bovinos machos, adultos, de raza cebú mestizo, entre 2 a 7 años los cuales fueron sacrificados para consumo humano durante seis meses. Las muestras se analizaron mediante: espectroscopia de absorción atómica, empleando lámparas de cátodo hueco y un quemador de aire acetileno para determinar Cu; vapor frío para la detección de Hg y polarografía para la detección de Cd y Pb. Resultados. Se observó que Los rangos de Hg, Cu, Cd y Pb estaban por debajo de los parámetros de referencia de la Comisión Europea y la Norma Oficial Mexicana. En el 4% de las muestras se encontraron niveles de Cu no permisibles para consumo humano. Conclusiones. La industria cárnica de la región presenta una gran potencialidad para acceder a mercados internacionales, debido a que el 96% de las reses presentaron niveles de metales por debajo de los límites permisibles de México y Europa. A pesar de que los niveles de mercurio se encuentran en los límites permisibles, la evaluación del riesgo basado en el índice de peligrosidad, sugiere que el consumo diario de 100 gramos de productos cárnicos con niveles de 0.08 ppm, podría incrementar el riesgo de envenenamiento a una persona de 70Kg.

  18. Efecto de metales pesados en el crecimiento de la microalga tropical Tetraselmis chuii (Prasinophyceae

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    Jiudith Cordero

    2005-09-01

    Full Text Available El presente trabajo determina el efecto tóxico de los metales cadmio (Cd, cobre (Cu, mercurio (Hg y plomo (Pb en la microalga tropical Tetraselmis chuii (Butcher, 1959. Se expuso, por triplicado, 50 ml de cultivo (f/2 Guillard de la microalga en fase de crecimiento logarítmica ante las concentraciones de 0 (control; 0.1; 1.0; 5.0; 10.0 y 20.0 mg· l-1 durante 96 hr. La evaluación del efecto letal se realizó diariamente, mediante recuento celular con una cámara de Neubauer. En el tratamiento control, sin exposición al metal, se observó un incremento de la densidad celular, en contraste con un decrecimiento en los tratamientos con exposición a los metales, los cuales fueron acelerados hasta las 48 hr, a partir de cuando el decrecimiento se hizo menos pronunciado. Una excepción se produjo con el Cd y el Cu a las 24 h, donde no se determinó decrecimiento significativo, probablemente debido a su capacidad de actuar como micronutriente a bajas concentraciones. El metal que produjo mayor efecto fue el Pb, produciendo una letalidad al 50% de la población microalgal a 0.40 mg· l-1, la cual fue casi tres veces menor que la establecida para el Hg y más de 13 veces menor que la del Cd y Cu. Se recomienda la microalga Tetraselmis chuii como especie modelo para la utilización en pruebas en función estimar efectos tóxicos por xenobióticos en el ambiente acuático marino tropical.Efect of heavy metals on the growth of the tropical microalga Tetrasermis chuii (Prasinophyceae. We determined the toxic effect of four metals, cadmium (Cd, copper (Cu, mercury (Hg and lead (Pb, on the tropical microalga Tetraselmis Chuii (Butcher, 1959. We exposed 50 ml of cultivated microalgae (f/2 Guillard in the exponential growth phase, with three replicates, to concentrations of 0 (control, 0.1, 1.0, 5.0, 10.0 and 20.0 mg· l-1 with each metal for 96 hr. We evaluated the lethal effect daily, through the cellular count. In the control treatment (not exposed to any

  19. Manifestaciones cutáneas como parámetro de teratogenicidad en la intoxicación con metales pesados Cutaneous signs as parameter in teratogenicity by heavy metal intoxication

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    N L Pauza

    2007-03-01

    Full Text Available Se estudiaron los efectos teratogénicos de metales pesados (acetatos de Cd2+ y Pb2+ y sulfato de Cu2+, en embriones de pollo en desarrollo, después de la administración de una monodosis del metal. Los huevos embrionados fueron inyectados en la yema en el día 12 de incubación. Las concentraciones de los iones fueron (nmoles/g huevo: Cd2+: Dosis 1 (D1: 0,16 y Dosis 2 (D2: 0,32; Pb2+: D1: 8,0 y D2: 16,0 y Cu2+: D1: 1,7 y D2: 3,3. Los resultados se evaluaron después de continuar la incubación in ovo durante 12 y 60 hs Cu2+ y Pb2+ no aumentaron la mortalidad de los embriones, en cambio, la presencia de Cd2+ produjo entre 30 y 86 % de mortalidad de los embriones, con efectos dosis y tiempo dependientes. Los embriones intoxicados con la D2 de Cd2+ durante 60 hs fueron los únicos ejemplares que presentaron disminución en su peso promedio, respecto de los ejemplares de control. La administración de Cd2+ causó efectos teratogénicos más severos que los tratamientos con Cu2+ y Pb2+. Se puede concluir que los metales pesados son embriotóxicos e inducen teratogenia en embriones de pollo en desarrollo. Se sugiere que los mejores parámetros para evaluar la teratogenicidad producida por la intoxicación Cd2+, Cu2+ y Pb2+ son los derrames cutáneos y hepáticos.Teratogenic effects of heavy metals (Cd2+- and Pb2+- acetates and Cu2+- suphate were studied on chick embryos, after the administration as a single dose. Test materials were injected into the yolk on day 12 of incubation. Tested concentrations were (nmole/g egg: Cd2+ Dose 1 (D1: 0.16 and Dose 2 (D2: 0.32; Pb2+: D1: 8.0 and D2: 16.0 and Cu2+: D1: 1.7 and D2: 3.3. Evaluations were performed after in ovo incubation for 12 and 60 hours. Embryonic mortality did not increase at the two dose levels of Cu2+ and Pb2+, while Cd2+ caused 30 and 86% of mortality, showing dose and time responses. Eggs treated with D2 of Cd2+ for 60 hs, significantly decreased the average of body mass embryo, when

  20. LOS RIESGOS DE LOS METALES PESADOS EN LA SALUD HUMANA Y ANIMAL

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    LUIS FERNANDO LONDOÑO FRANCO

    2016-12-01

    Full Text Available This work is a study of heavy metals and the potential risk they may pose to the health of humans and animals, including the food chain. In order to contribute to knowledge and lay foundation on the situation of these pollutants in our environment. Undoubtedly the mining, pollution of soil, water, plants and animals on behalf of industrialization, fertilizers, chemical insecticides and other activities for the development of modern societies have led to an inordinate increase of heavy metals: mercury (Hg, lead (Pb, arsenic (As, cadmium (Cd, copper (Cu, chromium (Cr, among others, and as a direct result of pollution. Furthermore it added to factors such as climate change, the greenhouse effect, deforestation, loss of natural resources in flora and fauna have increased the threat of heavy metals in nature. The aim is to examine the heavy metal as its source, distribution, general purposes and major alterations on the environment, also affecting human and animal health. To promote greater awareness and research on the subject, which may lead to reduced risks of heavy metals in ecosystems.

  1. Heavy metals in geochemical sediment fractions of the border region between Baja California, Mexico, and California, USA; Metales pesados en fracciones geoquimicas de sedimentos de la region fronteriza de Baja California, Mexico, y California, EUA

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    Villaescusa-Celaya, Julio A; Gutierrez-Galindo, Efrain A; Flores-Munoz, Gilberto [Instituto de Investigaciones Oceanologicas, Universidad Autonoma de Baja California, Ensenada, B.C., (Mexico)

    1997-03-01

    water in the coastal zone are being transported outside the region. [Spanish] En este estudio se evalua la concentracion de los metales pesados Cu, Zn, Ni, Cr, Pb, Cd, Ag, Mn y Fe en las diferentes fracciones geoquimicas del sedimento, como una medida para conocer el impacto de las descargas de agua residuales sobre los sedimentos costeros de la region. Para este proposito, durante un crucero oceanografico realizado en abril de 1992 (ECOBAC IV), se recolectaron 20 muestras de sedimento superficial en la plataforma costera de la region fronteriza de Baja California (Mexico) y California (EUA). Las muestras de sedimento se sometieron a un procedimiento de extraccion secuencial, disenado para obtener las fracciones geoquimicas operacionalmente definidas como: intercambiable (F1), carbonatos (F2), oxihidroxidos de Fe y Mn (F3), materia organica/sulfuros (F4) y residual o litogenica (F5). La especiacion operacional de los metales indica que las principales fases que acumulan metales en el sedimento son la matriz detrital o litogenica, los oxihidroxidos de Fe y Mn y la materia organica/sulfuros, en este orden. La distribucion espacial de los metales pesados en la fase reactiva (definida como la suma de F1-F4) presento, en general, una tendencia a aumentar en concentracion en sedimentos alejados de la costa. Los metales pesados en la fase reactiva aparentemente son controlados por la concentracion de hierro reactivo en los sedimentos, con excepcion del Pb, el Cd y la Ag. Esto sugiere que estos ultimos elementos son controlados por otros procesos, tales como el material particulado de origen biogenico. En contraste, la distribucion espacial de los metales pesados en la fase detrital presento un comportamiento inverso, esto es, las mayores concentraciones de metales se encuentran cercanas a la costa frente a la planta de tratamiento de aguas residuales de Punta Bandera, Baja California. Las concentraciones promedio de metales totales (suma de F1-F5) fueron de 7.6, 40, 21, 68

  2. Desarrollo y validación de un método ambientalmente amigable para determinación de metales pesados en pastos

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    Amanda Lucia Chaparro

    2016-12-01

    Full Text Available Los metales pesados son peligrosos para los seres vivos y el medio ambiente, pues no pueden ser degradados y pueden llegar a los seres humanos a través la cadena trófica, por lo tanto, su determinación en diferentes matrices para consumo humano y animal, es de vital importancia. La metodología más utilizada para su extracción, es cenizas, la cual conlleva a tiempos largos de análisis y elevado consumo de energía, por esta razón, en el presente trabajo se desarrolló y validó un método ambientalmente amigable para la digestión y extracción de Cd+2 y Pb+2 en pastos, utilizando ultrasonido y espectroscopia de absorción atómica. Se evaluaron diferentes variables que afectan la digestión, como posición en el ultrasonido, peso de muestra, solvente, volumen del solvente, tiempo de sonicación y tipo de recipiente, en muestras de pastos dopadas con los metales, teniéndose como variable de respuesta, el porcentaje de recuperación. Las condiciones para extraer Cd+2 y Pb+2 en estas pasturas, fueron: 0,50g de tejido vegetal; 3,00mL de HCl:HNO3-3:1 expuestos 60min al ultrasonido, en tubos de vidrio cónicos. Este procedimiento mostró un comportamiento lineal en el rango de 0,50 - 8,00mg/Kg con R2 de 0,99 tanto para Cd como para Pb. Los límites de detección y cuantificación, fueron 0,25 y 0,43mg/Kg para Cd; 0,22 y 0,37mg/Kg para Pb. La metodología propuesta, se comparó con la técnica clásica y permitió determinar niveles trazas de estos metales tóxicos, en forraje proveniente del Magdalena medio, con porcentajes de recuperación de 97,54 y 98,62%, respectivamente.

  3. Modified silicates applied in adsorption of heavy metal; Silicatos modificados aplicados na adsorcao de metal pesado

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    Farias, M.C.M. de [Universidade Federal de Campina Grande (UFCG), PB (Brazil). Unidade Academica de Engenharia de Materiais; Raposo, C.M.O., E-mail: raposo@dmg.ufcg.edu.b [Universidade Federal de Campina Grande (UFCG), Campina Grande, PB (Brazil). Unidade Academica de Mineracao e Geologia

    2010-07-01

    The levels of heavy metals in the environment has increased considerably in recent decades due to various human activities, which cause serious pollution problems, both in aquatic systems and in soil. The clay minerals present himself as amenable to the adsorption of metal ions and, sometimes, taking the advantage of being abundant and inexpensive. Vermiculite has intrinsic characteristics which favor its use as adsorbent. In this work, we investigate the adsorption of lead (II) from aqueous solutions by vermiculite fractions in commercial, fine to medium in molar concentration between 1-4 mmol (s). The samples provided by the Uniao Brasileira de Mineracao/Paraiba/Brazil were modified thermal and organically. The results of X-ray diffraction associated with the results of X-ray fluorescence showed that the average fraction vermiculite exfoliated organically modified responded most significantly to the adsorption process when compared to vermiculite fine fraction under the same conditions. (author)

  4. Perfiles de resistencia a antibióticos y metales pesados en Pseudomonas aeruginosa potencialmente patógenas aisladas de agua de uso agrícola

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    Oscar G. Gutiérrez Cárdenas

    2017-01-01

    clas i ficaron en 1 1 grupos. Mientras que para los metales pesados se presentaron altos niveles de tol e rancia para Cu +2 , Zn +2 , Ba +2 , Pb +2 y Se +4 . Conclusión : Las P. aeruginosa aisladas de agua de uso agrícola en la zona de estu dio son potencialmente patógenas debido a la presencia de genes de virulencia. Además presentaron altos índices de resistencia a antibióticos y tolerancia metales pesados.

  5. Metais pesados em plantas de milho cultivadas em Latossolos repetidamente tratados com biossólido Heavy metals in corn grown on oxisols continuously amended with biosolid

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    Ana Rosa Martins dos Anjos

    2000-12-01

    Full Text Available A presença de metais pesados em biossólidos é motivo de preocupação quando do uso agrícola desse resíduo em função da possibilidade de absorção desses metais pelas plantas crescendo nesse solo. A fitodisponibilidade de metais pesados, em solos repetidamente tratados com biossólido, foi avaliada num experimento em vasos de 0,5 m³, contendo LATOSSOLO AMARELO Distrófico (LAd e LATOSSOLO VERMELHO Distrófico (LVd. O experimento foi montado no delineamento em blocos ao acaso, com quatro tratamentos (LAd+lodo, LAd, LVd+lodo e LVd e quatro repetições utilizando milho como planta teste. Incorporou-se biossólido, proveniente da Estação de Tratamento de Esgotos ETE-SABESP-Barueri, São Paulo, na camada 0-0,2 m dos solos durante um período de até doze meses antes do plantio, numa quantidade total correspondente a 388 Mg ha-1, base seca. Antes da semeadura, os tratamentos testemunhas receberam calcário e adubação NPK, porém houve necessidade de adubação NPK nos tratamentos com biossólido, durante o desenvolvimento das plantas. As análises do tecido vegetal foram feitas por digestão nitro-perclórica, seguindo-se a quantificação dos metais por absorção atômica, nas seguintes partes da plantas: pendão, folha diagnose, folhas ao final do ciclo, colmo, bainha, grãos, sabugo e palha. As sucessivas aplicações do biossólido, em doses correspondentes a 78 Mg ha-1, não proporcionaram aumento de produtividade. Foi observado aumento dos teores de Cu e Zn nas plantas, evidenciando a disponibilidade desses metais adicionados via biossólido. Não foi observada disponibilidade de Cd, Cr, Mn, Ni e Pb para as plantas de milho.The presence of heavy metals in sewage sludge amended soils can cause concern due to the possibility of the absorption of these metals by plants growing on these soils. The availability of Cd, Cr, Cu, Ni, Pb and Zn to corn plants in soils continuously treated with biosolids (sewage sludge was evaluated by an

  6. Influencia del tráfico en la acumulación de metales pesados sobre vías urbanas: Torrelavega (España-Soacha (Colombia

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    Carlos Alfonso Zafra Mejía

    2013-01-01

    Full Text Available Asociado al suelo de áreas con una alta densidad de tráfico se han detectado elevadas concentraciones de metales. Los usuarios de las vías y aquéllos que viven en ambientes cercanos están potencialmente expuestos. Este artículo presenta un estudio del comportamiento de la concentración de metales pesados asociados con el sedimento acumulado sobre superficies viales (Torrelavega-España y Soacha-Colombia. Se distinguieron dos tipos de muestras: la aspirada directamente y la recolectada tras un barrido. Se determinó su distribución granulométrica (63-2800 μm y la concentración de metales (Pb, Zn, Cu, Cr, Cd y Ba asociada con cada fracción de tamaño por medio de espectrometría de absorción atómica de llama y de plasma inductivamente acoplado con espectrometría de masas. Los resultados mostraron que el sedimento con un mayor tiempo de residencia sobre la superficie estuvo más expuesto a la trituración generada por el tráfico (i.e., granulometría más fina; de esta manera, probablemente tendió a presentar una mayor susceptibilidad a la suspensión por el viento y la turbulencia del tráfico. En este sentido, la fracción de tamaño inferior a 63 μm presentó las mayores concentraciones. A mayor tiempo de residencia del sedimento sobre la superficie, mayores concentraciones metálicas asociadas. Las zonas con una mayor densidad de tráfico tienden a presentar las mayores concentraciones. Además, las calzadas con un mayor uso como línea de aparcamiento tienden a presentar mayores concentraciones, a pesar de registrar una menor densidad de tráfico. En las ciudades de investigación, el Pb supera los límites establecidos por la legislación utilizada como de referencia.

  7. Heavy metal levels in surface waters from a tropical river basin, Pernambuco State, northeastern Brazil = Níveis de metais pesados em águas superficiais de um rio tropical, Estado de Pernambuco, Brasil

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    Marc Bouvy

    2010-10-01

    Full Text Available Monthly, the distribution and enrichment of heavy metals (Fe, Mn, Cu, Pb and Zn in surface waters were examined at eight sampling sites, in Tapacurá river (Pernambuco State, Brazil, from March 1997 to December 1998 and from June 2005 to March 2006. On average, metal levels ranged from 0.30 to 4.22 for Fe; 0.02 to 1.09 for Mn; 0.001 to 0.014 for Cu; . 0.006 to 0.029 for Pb and 0.003 to 0.020 for Zn, all in mg L-1. Heavy metals presented a great heterogeneous horizontal distribution, with hotspots in municipal and agricultural areas. Theenrichment factor (EF and the potential contamination index (Cp indicated moderate to severe contamination by Cu and Zn. The results pointed the potential pathways of trace metals via the transport of soil for the river basin, mainly from agricultural areas, and inefficient sewage treatment at the cities. The first step to apply a remedial measure is the inspection of the agricultural areas, the controlled use of fertilizers and herbicides, as well as the development of an efficient sewage treatment to urban areas.Mensalmente, a distribuição e o enriquecimento de metais pesados (Fe, Mn, Cu, Pb e Zn em águas superficiais foram analisados em oitopontos de amostragem no rio Tapacurá, Estado do Pernambuco, Brasil. O estudo foi realizado entre março/1997 e dezembro/1998 e entre junho/2005 e março/2006. Em média, o nível de metais pesados variou em mg L-1 entre 0,30 e 4,22 Fe; 0,02 e 1,09 Mn; 0,001 e 0,014 Cu; . 0,006 e 0,029 Pb e 0,003 e 0,020 Zn. Os metais mostraram distribuiçãohorizontal heterogênea grande com ênfase nas áreas municipais e agrícolas. O fator de enriquecimento (EF e o índice de contaminação potencial (Cp indicaram moderada a severa contaminação por Cu e Zn. Os resultados indicaram um caminho preferencial de metais pelo transporte de solo para bacia, principalmente de áreas agrícolas e pelo tratamento ineficiente de esgotos urbanos. O primeiro passo para uma medida corretiva é a

  8. Availability of nutrients and toxic heavy metals in marigold plants=Disponibilidade de nutrientes e metais pesados tóxicos em plantas de calêndula

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    Herbert Nacke

    2012-10-01

    Full Text Available Availability of nutrients and toxic heavy metals in marigold plants. This study was performed aiming to assess the availability of nutrients and toxic heavy metals present in marigold plants (Calendula officinalis treated with different fertilizers. The treatments were arranged in factorial scheme (2 x 2 x 3 in a completely randomized experimental design (CRD, with two textures of soil (sandy and clayey, two forms of fertilization (organic and chemical and three fertilization levels (without fertilization, recommended dose, and twice the recommended dose totaling 12 treatments, with four replications. The results showed that the clayey soil promoted the availability of N P, K, Mg, Cu, Zn and Fe; on the other hand, the sandy soil favored the availability of Ca, Mn, Pb and Cr. The organic fertilization provided higher levels of P and Fe, while the leaf tissue of marigold plants chemically fertilized presented higher concentrations of K and Mn.Realizou-se este trabalho com o objetivo de avaliar a disponibilidade de nutrientes e de metais pesados tóxicos presentes em plantas de calêndula (Calendula officinalis após diferentes tipos de adubação. Os tratamentos foram arranjados em esquema fatorial (2 x 2 x 3 dispostos em delineamento experimental inteiramente casualizado (DIC, sendo duas texturas de solo, (argilosa e arenosa, duas formas de adubação (química e orgânica e três doses de adubação (sem adubação, dose recomendada e o dobro da dose recomendada, totalizando 12 tratamentos com quatro repetições. Os resultados demonstraram que os solos argilosos favoreceram a disponibilidade de N P, K, Mg, Cu, Zn e Fe; os solos de textura arenosa favoreceram a disponibilidade de Ca, Mn, Pb e Cr. A adubação orgânica disponibilizou maiores teores de P e Fe, enquanto o tecido foliar de plantas de calêndula adubadas com adubação química apresentaram concentrações maiores de K e Mn.

  9. ESPECIACION QUÍMICA DE METALES PESADOS EN SUELOS INCUBADOS CON LODOS RESIDUALES PROVENIENTES DE UNA PLANTA DE TRATAMIENTO DE AGUAS

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    Adriana Forero Hernandez

    2008-03-01

    Full Text Available Con el objeto de evaluar el destino de los metales pesados en los suelos agrícolas, provenientes de los lodos de las aguas residuales de plantas de tratamiento, se determinó la especiación química en los suelos después de 9 semanas de aplicación, para lo cual se realizaron ensayos de incubación utilizando una dosis de 2,5% de lodo p/p equivalente a 81,5 Ton lodo/ha de suelo. Las unidadesexperimentales consistieron en materos con una mezcla suelo-lodo que se mantuvieron entre 17 y 25 ºC, humedad acapacidad de campo, dispuestos en invernadero con un diseño estadístico completamente aleatorizado con cuatroréplicas y siete tratamientos. Se encontró que los niveles de concentración total en el lodo de Cd, Cu, Mn, Pb y Zn fueron muy inferiores a los establecidos por la normatividad del Environmental Protection Agency (EPA para su utilización en suelos.Además, el contenido de carbono orgánico, nitrógeno y fósforo disponible estuvo en el intervalo normal reportado para fertilizantes orgánicos.La adición de lodo al suelo produjo un incremento significativo de la fracción de Cd enlazada a materia orgánica comparada con las fracciones intercambiable y unida a óxidos de hierro-manganeso, el Cu presentó mayor afinidad por la fracción de óxidos de hierro- manganeso, el Pb mostró una fracción enlazada a materia orgánica la cual estaba ausente en el suelo testigo, el Zn tuvo una mayor proporción en la fracción asociada a óxidos de hierro-manganesoy el Mn en comparación con los otros metales fue el que presentó la mayor fracción intercambiable.

  10. La contaminación por metales pesados en la Ciénaga Grande de Santa Marta, Caribe colombiano La contaminación por metales pesados en la Ciénaga Grande de Santa Marta, Caribe colombiano

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    Campos C. Néstor Hernando

    1990-09-01

    Full Text Available Se dan los resultados de los estudios sobre la contaminación por metales pesados en la Ciénaga Grande de Santa Marta. Las determinaciones se realizaron en el material en suspensión, en los bivalvos Crassostrea rhizophorae e Isognomon alatus y en los peces Gathorops spixii y Ariopsis bonillai. Los análisis de los metales Cd, Zn y Cu en el material en suspensión permitieron determinar que las mayores descargas de estos metales se suceden principalmente desde el Río Magdalena a través del Canal del Clarín y de los ríos que fluyen del piedemonte de la Sierra Nevada de Santa Marta. La comparación de los contenidos en bivalvas permiten determinar la importancia de estos organismos como bioindicadores. Los análisis en las dos especies de peces mostraron una diferenciación en la capacidad de acumulación entre una y otra.  Al comparar los contenidos de metales entre los diferentes tipos de muestras con los cambios en los contenidos en el material en suspensión y la salinidad, se observó que estos dos parámetros son principalmente los que controlan la biodisponibilidad de los metales y además afectan los procesos fisiológicos de los organismos, aumentando o disminuyendo la capacidad de bioacumulación. Results of the studies of heavy metals pollution in the Ciénaga Grande de Santa Marta are provided. The determinations have been done on the suspended matter, on the bivalves Crassostrea rhizophorae and Isognomon alatus, and in the fishes Gathorops spixii and Ariopsis bonillai. The analysis of Cd, Zn and Cu in the suspended matter led to determine that the discharges come principally from the Río Magdalena through the Canal del Clarín and the rivers coming from the Sierra Nevada de Santa Marta. Comparisons of the concentration in bivalves show the importance of this organisms as bioindicators. The analysis in both fish species show a difference in their capacity of accumulation. Comparison of the metals contents between different types

  11. Metais pesados em solos de área de mineração e metalurgia de chumbo: I - Fitoextração Heavy metals in soils of a lead mining and metallurgy area: I - Phytoextraction

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    Maurício Gomes de Andrade

    2009-12-01

    Full Text Available A fitoextração tem sido sugerida como alternativa viável às práticas tradicionais de recuperação de solos contaminados por metais pesados (remoção do solo e destinação em aterros ou coprocessamento em cimento, etc., em razão dos menores custos e por ser menos impactante ao ambiente. Este trabalho objetivou avaliar a fitoextração induzida (uso de ácido cítrico como agente quelante de metais pesados, com o cultivo de aveia-preta (Avena strigosa Schreber, girassol (Helianthus annuus L. e grama-batatais (Paspalum notatum Flügge, em solos poluídos (solos 2, 3 e 4 de uma área de mineração de Pb em Adrianópolis (PR. O solo 1 foi amostrado em área de mata nativa (referência. O experimento foi realizado em casa de vegetação, com três repetições. Foram determinados os teores de Pb, Cd, Cu, Ni, Cr e Zn no solo com HNO3/HCl (3:1 concentrados. Após a colheita das plantas, determinaram-se a massa de matéria seca e os teores de metais pesados nas raízes e parte aérea (digestão nítrico-perclórica. Os solos contaminados (2, 3 e 4 apresentaram as seguintes faixas de teores de metais pesados (mg kg-1: Pb - 2.598,5 a 9.678,2; Cd - 1,9 a 22,2; Cu - 165,5 a 969,2; Ni - 22,6 a 38,4; Cr - 15,2 a 27,8; e Zn - 87,4 a 894,8. A adição de quelante não induziu a uma absorção mais efetiva de metais pesados pelas plantas. O solo 2 possibilitou melhor crescimento das plantas, e o girassol deve ser preferido na fitorremediação das áreas sob as mesmas condições. Na área próxima à planta fabril (solo 3 e nas áreas com grande ocorrência de rejeitos (solo 4, a fitoextração não foi eficiente. Nesses ambientes, recomenda-se o estudo de outras plantas nativas e, ou, exóticas resistentes a altos teores de Pb (solo 3 ou a remobilização de solo mais rejeito para aterros industriais (solo 4.Phytoextraction has been suggested as a viable alternative to traditional restoration practices for heavy metal-contaminated soils (e.g., soil

  12. Fungos micorrízicos no crescimento e na extração de metais pesados pela braquiária em solo contaminado Mycorrhizal fungi influence on brachiariagrass growth and heavy metal extraction in a contaminated soil

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    Silvana da Silva

    2006-12-01

    Full Text Available Avaliou-se, em casa de vegetação, a influência de 14 isolados de fungos micorrízicos arbusculares (FMA no crescimento e extração de Zn, Cd, Cu e Pb pela Brachiaria decumbens em solo contaminado. Foram utilizadas plantas com e sem FMA, em vasos com 0,92 kg de solo com (mg kg-1: Zn, 3.300; Cu, 60; Cd, 29; Pb, 73. Os isolados fúngicos tiveram efeitos diferenciados no crescimento e aumentaram a produção de matéria seca em 84%. Os teores de metais na planta foram elevados e apresentaram relação inversa com a produção de matéria seca. Verificou-se que os FMA não afetaram os teores de Pb, mas reduziram em 20, 28 e 63% os teores de Zn, Cd e Cu na parte aérea, respectivamente, e aumentaram os teores de Cu nas raízes em mais de 1.000%. Os FMA aumentaram a quantidade de metais extraídos do solo em 845, 142, 68 e 54% para Cu, Pb, Zn e Cd, respectivamente. Acaulospora spinosa, Acaulospora morrowiae-UFLA e Gigaspora gigantea aumentaram a extração simultânea dos quatro metais contaminantes. Os FMA, de acordo com a espécie, aumentam a capacidade da B. decumbens de extrair metais pesados do solo.The influence of 14 arbuscular mycorrhiza fungal isolates (AMF on brachiariagrass growth and extraction of Zn, Cd, Cu and Pb from a contaminated soil was evaluated in a greenhouse experiment. Mycorrhizal and nonmycorrhizal Brachiaria decumbens plants were grown in pots with 0.92 kg of soil containing (mg kg-1: Zn, 3,300; Cu, 60; Cd, 29; Pb, 73. The AMF increased dry matter yield in 84%. Plant heavy metal concentrations were high and were inversely related to dry matter yield. Isolates caused no effect on Pb, but reduced shoot Zn, Cd and Cu concentrations by 20, 28 and 63%, respectively. It was observed effect of mycorrhiza on Cu accumulation in roots (over 1,000%. Isolates enhanced the total amount of soil extracted metals by 845, 142, 68 and 54% for Cu, Pb, Zn and Cd, respectively. Only Acaulospora spinosa, Acaulospora morrowiae-UFLA and Gigaspora

  13. Impact of the Prestige oil spill on marsh soils: Relationship between heavy metal, sulfide and total petroleum hydrocarbon contents at the Villarrube and Lires marshes (Galicia, Spain); Impacto de la marea negra del Prestige en suelos de marisma: relacion entre los contenidos de metales pesados, sulfuros e hidrocarburos en las marismas de Villarrube y Lires (Galicia, Espana)

    Energy Technology Data Exchange (ETDEWEB)

    Andrade, L.; Marcet, P.; Covelo, E.F.; Vega, F.A. [Department of Vegetable Biology and Soil Science, Vigo (Spain); Fernandez-Feal, L.; Fernandez-Feal, C. [Escuela Politecnica Superior, Universidad de la Coruna, Ferrol (Spain)

    2004-09-15

    The objectives of this study were to determine the effect of the Prestige oil spill on the total petroleum hydrocarbons and heavy metal contents of soils in two marshes (Lires and Villarrube, Galicia, Spain) and the relationship between their oxidation-reduction potential and the solubility of heavy metals with sulfide and sulfate contents. Soil samples were taken from polluted and unpolluted areas and their petroleum hydrocarbon contents, heavy metal contents and other chemical characteristics were measured. The soils affected by the oil spill show remarkable contents of Cr, Cu, Ni, Pb and V. The Lires marsh soils are more affected by fuel oil than Villarrube marsh. The effects of the contaminating agents on the soils reach distances of up to 500 m from the coastline. In the first 400 m, there are important spatial variations because the fuel oil penetrated into the soils through tidal action and not directly. The Cr, Cu, Ni, Pb and V contents of polluted soils were between 50 and 200 times higher than those of their unpolluted counterparts and the background concentrations in Galician coastal sediments. In the case of Cr, Cu, Ni, Pb and V, their origin through the fuel oil was corroborated by the high correlation (r > 0.90) between the concentrations of these metals and the total petroleum hydrocarbon content of the polluted soils, which shows the combined addition of these metals through the fuel oil. [Spanish] Los objetivos de este trabajo fueron determinar el efecto de la marea negra del buque tanque Prestige en el contenido total de hidrocarburos y de metales pesados en suelos de dos marismas (Lires y Villarrube, Galicia, Espana) y la relacion entre el potencial de oxidacion-reduccion y la solubilidad de los metales pesados con los contenidos de sulfuros y de sulfatos. Se tomaron muestras de suelos de las zonas contaminadas y no contaminadas y se determinaron diversas caracteristicas quimicas, el contenido total de hidrocarburos y de metales pesados. Los

  14. Metodologías para establecer valores de referencia de metales pesados en suelos agrícolas: perspectivas para Colombia

    OpenAIRE

    Germán Rueda Saa; Jenny Alexandra Rodríguez Victoria; Raúl Madriñán Molina

    2011-01-01

    Los problemas ambientales de los metales pesados en los suelos están relacionados con su carácter tóxico cuando se acumulan o cuando interactüan con algunas propiedades especificas, se movilizan a  través del perfil a la cadena trófica mediante los cuerpos de agua o los cultivos y pueden llegar a afectar la salud humana. En países desarrollados el establecimiento de valores de referencia de estos metales ha permitido el mejoramiento de la planeación y la gestión ambiental del recurso...

  15. Aproximación ecotoxicológica a la contaminación por metales pesados en la laguna costera del Mar Menor

    OpenAIRE

    Marín Guirao, Lázaro

    2007-01-01

    El objetivo de la Tesis es obtener una visión de la situación actual de la laguna costera del Mar Menor en relación con la contaminación por metales pesados procedentes de actividades mineras mediante el empleo de herramientas ecotoxicológicas. Comienza con el estudio de la entrada de residuos mineros en el ecosistema, su distribución en las aguas de la laguna así como los efectos tóxicos asociados. Continua valorando la biodisponibilidad de los metales contenidos en los sedimentos lagunares ...

  16. Metodologías para establecer valores de referencia de metales pesados en suelos agrícolas: Perspectivas para Colombia

    Directory of Open Access Journals (Sweden)

    Rueda Saa Germán

    2011-09-01

    Full Text Available

    Los problemas ambientales de los metales pesados en los suelos están relacionados con su carácter tóxico cuando se acumulan o cuando interactüan con algunas propiedades especificas, se movilizan a  través del perfil a la cadena trófica mediante los cuerpos de agua o los cultivos y pueden llegar a afectar la salud humana. En países desarrollados el establecimiento de valores de referencia de estos metales ha permitido el mejoramiento de la planeación y la gestión ambiental del recurso suelo, y se ha convertido en un instrumento de control para las entidades ambientales que ha permitido evaluar el impacto en diferentes actividades agrícolas.

    En este artículo se analizan diferentes conceptos relacionados con los niveles de metales pesados en suelos agrícolas y la incidencia de las características edafológicas en su concentración. Se revisan, igualmente, algunas metodologias para derivar valores de referencia especificos aplicables a suelos agrícolas colombianos, y se plantean algunas perspectivas orientadas a la protección y recuperación de suelos en el país. En Colombia en la actualidad no se cuenta con criterios y estándares de calidad para metales pesados en suelos agrícolas; por esto se hace necesario gestionar el apoyo de entidades gubernamentales con el fin de iniciar y desarrollar investigaciones en diferentes sectores agricolas primarios, contribuyendo de esta forma a garantizar la producción agrícola y la sostenibilidad ambiental del recurso suelo.

  17. Evaluación de la mutagenicidad causada por metales pesados presentes en agua del río Cauca en la ciudad de Cali, Colombia

    Directory of Open Access Journals (Sweden)

    Aura H. Vivas

    2014-05-01

    Full Text Available Se evaluó la mutagenicidad del agua del río Cauca debida a la presencia de metales pesados en la zona urbana de la Ciudad de Santiago de Cali, a partir de muestras tomadas en la temporada seca y lluviosa en el año 2013. Los metales se extrajeron pasando el agua por la resina Amberlite XAD-16. Las concentraciones de los metales pesados se midieron por absorción atómica y la mutagenicidad se evaluó por medio del test de Ames, con las cepas TA98 y TA100 de Salmonella typhimurium con y sin activador enzimático S9. Los resultados mostraron índices de mutagenicidad (IM positivos (IM > 2,0 para muestras colectadas en temporada lluviosa en tres de los cinco puntos evaluados: puente El Hormiguero (IM = 3,6, desembocadura del Canal Colector Sur (IM = 2,9 y desembocadura del río Cali (IM = 2,7, todos con la cepa TA98 sin S9. Estos sitios presentaron a su vez las mayores concentraciones totales de metales pesados en sus extractos. El análisis de la variación espacio-temporal del índice mutagénico se realizó haciendo un análisis de varianza multifactorial del IM. Los resultados encontrados indican que la época de muestreo contribuye significativamente a la variabilidad del IM, mientras que los puntos de muestreo no.

  18. Metodologías para establecer valores de referencia de metales pesados en suelos agrícolas: perspectivas para Colombia

    Directory of Open Access Journals (Sweden)

    Germán Rueda Saa

    2011-07-01

    Full Text Available Los impactos ambientales de los metales pesados en los suelos están relacionados con su carácter tóxico cuando se acumulan o interactúan con algunas propiedades específicas, se movilizan a través del perfil a la cadena trófica mediante los cuerpos de agua o los cultivos y pueden llegar a afectar la salud humana. En países desarrollados el establecimiento de valores de referencia de estos metales ha permitido el mejoramiento de la planeación y la gestión ambiental del recurso suelo, y se ha convertido en un instrumento de control para las entidades ambientales que ha permitido evaluar el impacto en diferentes actividades agrícolas. En este artículo se analizan diversos conceptos relacionados con los niveles de metales pesados en suelos agrícolas y la incidencia de las características edafológicas en su concentración. Se revisan, igualmente, algunas metodologías para derivar valores de referencia específicos aplicables a suelos agrícolas colombianos, y se plantean algunas perspectivas orientadas a la protección y recuperación de suelos en el país. En Colombia en la actualidad no se cuenta con criterios y estándares de calidad para medir la contaminación por metales pesados en suelos agrícolas; por esto se hace necesario gestionar el apoyo de entidades gubernamentales con el fin de iniciar y desarrollar investigaciones en diferentes sectores agrícolas primarios, contribuyendo de esta forma a garantizar una producción más limpia y la sostenibilidad ambiental del recurso suelo.

  19. Efecto del secado de los biosólidos de la planta de tratamiento de aguas residuales El Salitre (Bogotá sobre su contenido de nutrientes, metales pesados y patógenos

    Directory of Open Access Journals (Sweden)

    Giraldo Óscar

    2006-12-01

    Full Text Available

    Se acondicionó el biosólido proveniente  de la planta de tratamiento de aguas residuales El Salitre, en Bogotá, para su uso agrícola o forestal, de tal manera que el producto obtenido se encontrara dentro de los límites máximos permisibles de contaminantes establecidos por la estadounidense Environmental Protection Agency (EPA y su contenido de nutrientes se afectara en la menor proporción posible. Se realizaron tratamientos térmicos a temperaturas de 50, 55, 60, 65 y 70 °C, y se determinó el contenido de coliformes totales, E. coli y Salmonella, el contenido de nutrientes totales (N, P, K y metales pesados disponibles (Cd, Cr, Cu, Mn, Ni, Pb, Zn, antes y después de cada uno de los tratamientos. Los tratamientos de secado entre 55-70 °C redujeron los coliformes totales y E. coli hasta niveles apropiados para que el biosólido pueda ser utilizado en aplicaciones forestales. Aunque los contenidos de nutrientes del producto se redujeron entre 75% y 95%, aún se considera apropiados para su utilización como fertilizante. Los metales Cu y Zn aumentaron sus contenidos disponibles después de los tratamientos, Cd y Cr no fueron detectados y los contenidos de  algunos metales pesados (Mn, Ni, Pb se redujeron con el proceso de secado. Sin embargo, para  todos  los metales los valores se encontraron por debajo de los límites establecidos por la EPA para la aplicación del biosólido en terrenos agrícolas. Se concluyó que el tratamiento de secado de biosólido puede considerarse como una opción válida para su acondicionamiento para uso forestal.

  20. Organic acids effects on desorption of heavy metals from a contaminated soil Ácidos orgânicos e seus efeitos na dessorção de metais pesados em solo contaminado

    Directory of Open Access Journals (Sweden)

    Clístenes Williams Araújo do Nascimento

    2006-06-01

    Full Text Available Phytoremediation of heavy metals is a biotechnology that extracts metals from soils and transfer them to plant. As hyperaccumulator species have demonstrated low potential for commercial phytoextraction, synthetic chelates have been successfully used to induce accumulation of metals by high-biomass plants. However, they pose serious environmental drawbacks regarding excessive amount of metals solubilized. In search for synthetic chelate-alternatives, this paper evaluate the performance of DTPA, EDTA, citric acid, oxalic acid, vanillic acid, and gallic acid in desorbing Cd, Pb, Zn, Cu, and Ni from soil. DTPA and EDTA were highly effective in desorbing Cd, Pb, Zn, Cu, and Ni from soil. However, the excessively high concentration of metals brought in solution by such chelates limits their application in the field. Citric and oxalic acids desorbed substantial quantities of Zn, Cu, and Ni if applied at 10 or 20 mmol kg-1. At the 20 mmol kg-1 dose, vanillic and gallic acids solubilized significant amounts of Zn, Ni, and Cd from soil. None of the tested low molecular weight organic acids substantially increased the Pb concentration in soil solution.Fitoremediação de metais pesados é uma biotecnologia que usa plantas para extrair metais pesados de solos e transferi-los para a parte aérea. Como espécies naturalmente hiperacumuladoras de metais têm demonstrado baixo potencial para fitoextração comercial, agentes quelantes sintéticos são utilizados para induzir acumulação de metais em plantas de alta produção de biomassa. Esses quelantes, entretanto, apresentam a limitação ambiental de solubilizarem quantidades excessivamente altas de metais. Em busca de alternativas para o uso de quelantes sintéticos, o trabalho avaliou a capacidade de seis quelantes (DTPA, EDTA, ácido cítrico, ácido oxálico, ácido vanílico e ácido gálico na dessorção de Cd, Pb, Zn, Cu e Ni de um solo contaminado. DTPA e EDTA foram eficientes na dessorção de

  1. DETERMINACIÓN DE METALES PESADOS EN RESIDUOS SÓLIDOS Y LIXIVIADOS EN BIORREACTORES A DIFERENTES TASAS DE RECIRCULACIÓN

    OpenAIRE

    María del Consuelo HERNÁNDEZ BERRIEL

    2012-01-01

    Los metales pesados (MP) son parte de los contaminantes que contiene el lixiviado, este es generado por la descomposición de los residuos sólidos urbanos (RSU), el cual por su toxicidad puede causar severos problemas al ambiente. El propósito de este trabajo fue conocer el efecto de diferentes tasas de recirculación de lixiviados en la concentración de MP, así como en la matriz de residuos de biorreactores anaerobios (BrA) a escala laboratorio, para determinar la tasa que produzca la menor li...

  2. Uso de líquenes como bioindicadores de presencia de metales pesados en áreas cercanas a empresas mineras de altura del Perú

    OpenAIRE

    Díaz Rivas Plata, Eimy Tabatha; Díaz Rivas Plata, Eimy Tabatha

    2006-01-01

    El presente trabajo de tesis demuestra la utilización de los líquenes como bioindicadores de contaminación por presencia de metales pesados en áreas andinas ubicadas en los alrededores de las unidades mineras. Por ser organismos simbiontes, se considera a los líquenes como bioindicadores por excelencia. El área de trabajo estudiada comprende dos áreas adyacentes, ubicadas en el distrito de Huay Huay, provincia de Yauli, Región Junín, entre 4700 - 4900 msnm, una de las cuales se encuentra ...

  3. Estudio experimental de la movilidad de metales pesados en sedimentos de la cuenca del Jequetepeque, Perú

    OpenAIRE

    Isern Roselló, Regina; Martínez Planas, María del Mar

    2011-01-01

    Este proyecto tiene como objetivos determinar la concentración de metales en sedimentos procedentes de actividades mineras en la cuenca del río Jequetepeque así como su movilidad. Estos estudios son necesarios para el análisis de suelos contaminados ya que definen la capacidad tóxica de los sedimentos y, por tanto, su impacto en el medio ambiente. Para poder conocer el comportamiento de los metales estudiados (Zn, Cu, Al, Fe, Cd, Hg, Cr, Pb, As, Ni), se analizan los sedimentos de 5 zonas d...

  4. Elaboración de bio-resina intercambiadora de cationes a partir de cáscara de plátano o guineo para eliminar metales pesados en agua contaminada

    OpenAIRE

    García, Alma Verónica

    2016-01-01

    Esta investigación tuvo por objetivo obtener una bio-resina intercambiadora de cationes utilizando cáscaras de guineo o plátano, la cual reduzca la concentración de metales pesados en agua contaminada. A esta bio-resina se le realizaron pruebas fisicoquímicas: densidad seca aparente, pH y solubilidad en agua y solventes orgánicos. Se evaluó su efectividad filtrando agua contaminada con metales pesados, tales como hierro, cromo y níquel (Fe3+, Cr6+ y Ni2+), variando las condiciones de tiempo d...

  5. Acúmulo de metais pesados e alterações químicas em Cambissolo cultivado com meloeiro Accumulation of heavy metals and chemical alterations in a Ultisol cultivated with melon

    Directory of Open Access Journals (Sweden)

    Alessandra M. S. Mendes

    2010-01-01

    Full Text Available Com a utilização intensiva de agroquímicos, os solos cultivados podem ter o teor de metais pesados disponíveis às plantas aumentado com possível contaminação subsequente da cadeia trófica. Propôs-se, no presente trabalho, avaliar a influência do tempo de uso agrícola de um Cambissolo Háplico cultivado com meloeiro (Cucumis melo L. sob o acúmulo de metais pesados e as características químicas do solo. O solo com plantios de meloeiro com um, dois e três anos de implantação foram avaliados, além de uma área de vegetação natural, nas camadas de 0-20 e 20-40 cm de profundidade. Os resultados mostraram que o tempo de cultivo alterou as características químicas do solo, com aumento do pH e do teor de N, P e K nas duas camadas de solo estudadas; já os teores de Ca foram diminuídos pelo cultivo. Houve acréscimos no teor total e disponível de Ni, Pb, Cu e Mn, na camada superficial, em função do tempo de cultivo do solo, enquanto os teores totais de Fe e Zn foram reduzidos em ambas as camadas avaliadas, no entanto, os teores disponíveis ainda são relativamente baixos.Soil cultivation using agrochemicals may increase the concentration of availability of heavy metals to plant and cause contamination of the trophic chain as well. This work was carried out to evaluate the influence of length of time under cultivation with melon (Cucumis melo L. on the heavy metals accumulation and chemical alterations in Ultisol. Melon plantations of one, two and three years were studied. A benchmark area under natural vegetation was used to compare the data obtained. The results showed that the lengthiest time under cultivation altered the chemical characteristics of the soil. An increase in pH and contents of N, P and K was observed for the two soil layers evaluated. On the other hand, Ca contents were decreased by cultivation. The larger the cultivation time the higher the concentration of N, Pb, Cu, and Mn in the soil surface layer, whereas

  6. Efeito do silício e do fósforo na disponibilidade de metais pesados do solo pelo extrator mehlich-1 Effect of silicon and phosphorus on the availability of soil heavy metals by mehlich-1 extractor

    Directory of Open Access Journals (Sweden)

    Lilian Aparecida Paim

    2003-08-01

    Full Text Available Este trabalho foi desenvolvido em um solo contaminado por metais pesados de uma área de extração e industrialização de zinco pertencente à Companhia Mineira de Metais, em Três Marias, MG, com o objetivo de avaliar a eficiência do silício e do fósforo como agentes amenizadores da toxidez dos metais pesados. As amostras coletadas foram preparadas e incubadas em frascos de polietileno, com umidade equivalente a 60% do volume total de poros. Foram utilizados 25 tratamentos: cinco doses de silício (0; 2.340; 6.040; 9.860 e 13.660 mg dm-3 e cinco de fósforo (0; 90; 180; 360 e 720 mg dm-3, com quatro repetições, totalizando 100 unidades experimentais. Aos 30 e 60 dias, coletaram-se amostras de cada tratamento, submetidas a análises de pH em água e extrações simples por Mehlich-1. Os teores extraídos receberam influência do silício, do fósforo e do pH. Os teores de Zn e Cd, embora reduzidos, permaneceram acima dos níveis permitidos. O Pb diminuiu influenciado pelo incremento de silício e fósforo a níveis inferiores aos permitidos.This work was developed on a soil contaminated by heavy metals from a zinc-extracting and industrializing area belonging to the Companhia Mineira de Metais at Tres Marias, Minas Gerais state, Brazil, with a view to evaluating the efficiency of silicon and phosphorus as ameliorating agents of heavy metal toxicity. The samples collected were prepared and incubated into polyethylene flasks, moisture equivalent to 60% of the total volume of pores. 25 treatments were utilized: five doses of silicon (0; 2.340; 6.040; 9.860 and 13.660 mg dm-3 and five of phosphorus (0; 90; 180; 360 and 720 mg dm-3 with four replicates amounting to 100 experimental units. At 30 and 60 days, samples from each treatment were collected, submitted to water pH analysis and simple extraction by Mehlich-1. The extracted contents received greater influence from both silicon and phosphorous and at a lesser extent from pH. Zn and Cd

  7. Experimental Liquidus Studies of the Pb-Fe-Si-O System in Equilibrium with Metallic Pb

    Science.gov (United States)

    Shevchenko, M.; Jak, E.

    2018-02-01

    Phase equilibria of the Pb-Fe-Si-O system have been investigated at 943 K to 1773 K (670 °C to 1500 °C) for oxide liquid in equilibrium with liquid Pb metal and solid oxide phases: (a) quartz, tridymite, or cristobalite; (b) (fayalite + tridymite) or (fayalite + spinel); (c) spinel (Fe3O4); (d) complex lead-iron silicates (melanotekite PbO·FeO1.5·SiO2, barysilite 8PbO·FeO·6SiO2, 5PbO·FeO1.5·SiO2, and 6PbO·FeO1.5·SiO2); (e) lead silicates (Pb2SiO4, Pb11Si3O17); (f) lead ferrites (magnetoplumbite Pb1+ x Fe12- x O19- x solid solution range); and (g) lead oxide (PbO, massicot). High-temperature equilibration on primary phase or iridium substrates, followed by quenching and direct measurement of Pb, Fe, and Si concentrations in the phases with the electron probe X-ray microanalysis, has been used to accurately characterize the system in equilibrium with Pb metal. All results are projected onto the PbO-"FeO"-SiO2 plane for presentation purposes. The present study is the first systematic characterization of liquidus over a wide range of compositions in this system in equilibrium with metallic Pb.

  8. Afección de suelos agrícolas por metales pesados en áreas limítrofes a explotaciones mineras del Sureste de España

    Directory of Open Access Journals (Sweden)

    F. Belmonte Serrato

    2010-01-01

    Full Text Available Se analiza la contaminación por metales en suelos agrícolas en el entorno de la Sierra minera de Cartagena-La Unión. El muestreo se realizó cogiendo 20 muestras de suelo en uso agrícola mediante una distribución aleatoria en un área de unos 100 km2 en torno a la Sierra Minera. Los resultados han detectado concentraciones importantes, que alcanzan y superan los niveles máximos permitidos por diversas normativas internacionales de hasta 11 de los elementos denominados «metales pesados». Aluminio y Hierro destaca sobre los demás con concentraciones medias porcentuales de 13% y 10% respectivamente. Pero hay que destacar la contaminación excesiva de plomo (Pb y Zinc (Zn que duplica e incluso triplica el máximo establecido por las leyes más permisivas, superando con mucho los niveles máximos a partir de los cuales se requiere una intervención obligatoria en todas las legislaciones consultadas.

  9. Biomarcadores en monitoreo de exposición a metales pesados en metalurgia

    Directory of Open Access Journals (Sweden)

    Augusto Ramírez

    2006-03-01

    Full Text Available La salud del trabajador es el hecho más importante en la vigilancia por exposición a tóxicos industriales. En metalurgia extractiva, existe exposición a muchos elementos y compuestos químicos. El avance tecnológico actual permite realizar mediciones muy precisas en medios biológicos. Monitoreo biológico es medir la concentración del agente tóxico en los medios biológicos del trabajador, para establecer niveles de exposición y medidas de control en el ambiente laboral. Un indicador biológico de exposición valora la cantidad absorbida de un químico o de los subproductos de su biotransformación en medios biológicos, lo que permite cuantificar al agente en el organismo. En la exposición industrial para valorar daño renal, usamos función renal, citotoxicidad específica, proteínas de peso molecular bajo o enzimas excretadas. Para el sistema nervioso, se desarrolla indicadores ‘substitutos’ y, en genotoxicidad, aductos del ADN. El presente trabajo revisa indicadores de exposición para metales en metalurgia extractiva.

  10. Levels of heavy metals in the environment of a wastewater treatment plant. Metales pesados en aguas, sedimentos y suelos de las inmediaciones de una EDAR

    Energy Technology Data Exchange (ETDEWEB)

    Nuez Delgado, A.; Cardenas Botas, S.; Diaz-Fierros Viqueira, F. (Facultad de Farmacia. Universidad de Santiago de Compostela. Corua (Spain))

    1994-01-01

    The concentration levels of the heavy metals Zn, Cu, Ni, Pb, Cr, and Cd, were studied in different points of a wastewater treatment plant, in sediment and water samples of the riverbeds, and in soil samples of its environment. The concentrations of heavy metals in influent and effluent waters were not high: only Zn and Cu were detected and they were always below the legal threshold level, as they were in the waters of the riverbeds in the nearby. however, in several soil and sediment samples, phytotoxic levels of Pb and Zn were found.

  11. The effects of polycyclic aromatic hydrocarbons and heavy metals on terrestrial annelids in urban soils O efeito de hidrocarbonetos aromáticos policíclicos e metais pesados em anelídeos terrestres de solos urbanos

    Directory of Open Access Journals (Sweden)

    Pižl Václav

    2009-08-01

    Full Text Available The effect of soil contamination by polycyclic aromatic hydrocarbons (PAH and heavy metals on earthworms and enchytraeids was studied in urban parks, in Brno, Czech Republic. In spring and autumn 2007, annelids were collected and soil samples taken in lawns along transects, at three different distances (1, 5 and 30 m from streets with heavy traffic. In both seasons, two parks with two transects each were sampled. Earthworms were collected using the electrical octet method. Enchytraeids were extracted by the wet funnel method from soil cores. All collected annelids were counted and identified. Basic chemical parameters and concentrations of 16 PAH, Cd, Cu, Pb, and Zn were analysed from soil from each sampling point. PAH concentrations were rather low, decreasing with the distance from the street in spring but not in autumn. Heavy metal concentrations did not decrease significantly with increasing distance. Annelid densities did not significantly differ between distances, although there was a trend of increase in the number of earthworms with increasing distance. There were no significant correlations between soil content of PAH or heavy metals and earthworm or enchytraeid densities. Earthworm density and biomass were negatively correlated with soil pH; and enchytraeid density was positively correlated with soil phosphorus.O efeito da contaminação do solo por hidrocarbonetos aromáticos policíclicos (PAH e metais pesados em minhocas e enquitreídeos foi estudado em parques urbanos, em Brno, República Tcheca. Na primavera e outono de 2007, os anelídeos foram coletados, e amostras de solo foram retiradas de gramados ao longo de transectos, em três diferentes distâncias (1, 5 e 30 m de ruas com muito tráfego. Nas duas estações, foram amostrados dois parques com dois transectos cada um. As minhocas com uso do método do octeto elétrico, e os enquitreídeos foram extraídos das amostras de solo pelo método do funil úmido. Todos os anel

  12. Zonación de la contaminación por metales pesados en la cuenca del Almendares según mapeo de la susceptibilidad magnética

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    Ida Inés Pedroso-Herrera

    2013-09-01

    Full Text Available La susceptibilidad magnética de los suelos de la cuenca del río Almendares se tomó como indicador preliminar de la contaminación potencial por metales pesados. Para obtener el esquema de zonación de la contaminación se realizaron mediciones de la susceptibilidad magnética en polígonos y perfiles de áreas potencialmente contaminadas. Se realizó un levantamiento kappamétrico a escala 1: 200 000, usando una red de 2x2 km, y se elaboraron estadísticamente datos de susceptibilidad magnética en suelos contaminados y en los no contaminados por metales pesados. Con base en la nueva versión de la Clasificación Genética de los Suelos de Cuba, los resultados de la elaboración estadística de los datos de susceptibilidad magnética y las concentraciones de metales pesados en muestras de suelo, se establecieron los rangos de susceptibilidad magnética que caracterizan los suelos contaminados en los grupos genéticos presentes en la cuenca. Como resultado se obtuvo el mapa de zonación de la contaminación por metales pesados de la cuenca del río Almendares

  13. Distribución de metales pesados en los sedimentos superficiales del Saco del Golfo de Cariaco, Sucre, Venezuela

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    María Valentina Fuentes H

    2010-10-01

    atomic absorption spectroscopy. In addition, the contents of soluble and exchangeable metals associated to carbonate fractions, determined by BCR, were compared with those determined by the method of Campanella. Samples were collected in 12 stations during June 2007. The applied methodologies were evaluated with a certified reference material of marine sediments (HISS-1 and the results indicated that these methods provide adequate accuracy and precision for the extraction of metals. The total metal concentrations (μg g-1 were, Cd: < limit of detection (LD-5.0; Pb: 1.79-60.41; Cu: no detected (ND-42.18; Zn: 25.13-104.57; Mn: 66.31-80.29 and Ni: 3.29-24.58. Cd, Cu, Ni and Pb at several stations, exceeded the Canadian Sediment Quality Guidelines of the Lowest Effect Levels (LEL. Cadmium was identified as being the most mobile of the elements, having the highest concentrations in soluble and exchangeable cations and carbonates. However, Pb, Cu, Mn and Zn levels were found highly associated to organic matter and sulfide fractions. The methods did not show significant statistical differences for the extraction of soluble and exchangeable cations and the metals associated to carbonate fraction. There are several significant correlations between heavy metals, which suggest their common origin. Rev. Biol. Trop. 58 (Suppl. 3: 129-140. Epub 2010 October 01.

  14. Solubilidade, fracionamento e fitoextração de metais pesados após aplicação de agentes quelantes Solubility, phytoextraction and fractionation of heavy metals as a function of chelating agents applied to soil

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    Évio Eduardo Chaves de Melo

    2006-12-01

    Full Text Available A baixa biodegrabilidade de quelantes sintéticos usados para induzir a fitoextração resulta em alto risco ambiental pela possibilidade de lixiviação de metais pesados. Agentes quelantes naturais, mais rapidamente degradados no solo, podem ser uma alternativa para os quelantes sintéticos. O objetivo deste trabalho foi comparar a performance de ácidos orgânicos naturais (gálico, cítrico e oxálico com ácidos sintéticos (EDTA, DTPA e NTA na fitoextração induzida de metais. O solo foi contaminado com 500, 300 e 200 mg kg-1 de Pb, Zn e Cu, respectivamente, e cultivado com milho (Zea mays e mucuna preta (Stizolobium aterrimum. Os agentes quelantes, na dose de 10 mmol kg-1, foram aplicados no solo sete dias antes da coleta das plantas. Amostras do solo foram submetidas à extração com CaCl2 e fracionamento. Os teores dos metais na solução do solo foram também determinados. Os quelantes sintéticos EDTA, DTPA e NTA foram eficientes na solubilização dos metais pesados no solo. Dentre os ácidos orgânicos naturais, apenas o ácido cítrico foi eficiente na solubilização dos metais nas primeiras vinte e quatro horas após a sua aplicação. A distribuição dos metais entre as frações apresentou a seguinte ordem: Pb: matéria orgânica (MO > óxido de Fe amorfo (OxFeA > trocável (Tr > óxido de Fe cristalino (OxFeC; Cu: MO > Tr > OxFeC > OxFeA; e Zn: MO > Tr > OxFeC > OxFeA. De modo geral, a adição dos quelantes sintéticos provocou aumento nos teores trocáveis de Pb e Cu e redução nos teores de Pb, Cu e Zn nas frações óxidos de Fe amorfo e cristalino. O extrator CaCl2 0,01 mol L-1 pode ser utilizado para predição da concentração de Pb, Cu e Zn na solução do solo.The low biodegradability of synthetic chelating agents used for phytoextraction poses a great environmental risk due to the potential for metal leaching. Natural chelating agents can be an alternative to synthetic chelates due to their rapid biodegrability

  15. Uso de biomassa seca de aguapé (Eichornia crassipes visando à remoção de metais pesados de soluções contaminadas = Use of water hyacinth (Eichornia crassipes dry biomass for removing heavy metals from contaminated solutions

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    Affonso Celso Gonçalves Junior

    2009-01-01

    Full Text Available O presente trabalho avaliou a eficiência da biomassa seca de aguapé (Eichornia crassipes na remoção dos metais pesados cádmio (Cd, chumbo (Pb, cromo (Cr, cobre (Cu, zinco (Zn e níquel (Ni de soluções preparadas com estes metais. O delineamento utilizado foi inteiramente casualizado, com cinco tratamentos (soluções com diferentes concentrações dos metais pesados e quatro repetições. A biomassa seca permaneceu nas soluções dos tratamentos por um período de 48h, e nos intervalos de 1; 2; 3; 6; 12; 24; 36 e 48h após a instalação do experimento, coletaram-se alíquotas de cada tratamento,determinando-se a maior remoção de cada metal pesado pela biomassa seca do aguapé. Foi realizada digestão nitroperclórica na biomassa seca e determinação dos teores dos metais na biomassa e nas alíquotas por espectrometria de absorção atômica, modalidade chama. Paraos metais Cd, Pb, Cr, Cu e Zn ocorreu remoção significativa pela massa seca do aguapé nos diferentes tratamentos, enquanto para o Ni não foi encontrada diferença significativa. Dessa forma, conclui-se que a biomassa seca produzida, a partir do aguapé Eichornia crassipes, é um excelente material para a remoção, tanto em pequena como em grande escala, de corpos hídricos contaminados com metais pesados.The present work evaluated the efficiency of the dry biomass of water hyacinth (Eichornia crassipes in the removal of heavy metalscadmium (Cd, lead (Pb, chromium (Cr, cupper (Cu, zinc (Zn and nickel (Ni from solutions prepared with these metals. The delineation used was entirely randomized, with five treatments (solutions with different concentrations of heavy metals and fourrepetitions. The dry biomass remained in the treatment solutions for a period of 48h. In the intervals of 1; 2; 3; 6; 12; 24; 36 and 48h after experiment installation, samples were collected of each treatment, determining the greater removal for each heavy metal by water hyacinth dry biomass. Nitro

  16. Metales pesados en tejido muscular del bagre Ariopsis felis en el sur del golfo de México (2001-2004 Heavy metals in muscular tissue of the catfish, Ariopsis felis, in the southern Gulfof México (2001-2004

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    Felipe Vázquez

    2008-01-01

    Full Text Available Se analizó el contenido de metales pesados en tejido muscular del bagre, Ariopsis felis en el sur del golfo de México durante el período 2001-2004. La investigación fue efectuada buscando establecer un marco de referencia ambiental para este organismo. La concentración metálica siguió el orden: Hg We analyzed the heavy metal content in the muscular tissue of the catfish, Ariopsis felis, in the southern Gulf of México between 2001 and 2004. The research was done in order to establish an environmental frame of reference for this organism. The metal concentration was as follows: Hg < Co < Pb < Ni < V < Cr. Cobalt and vanadium contents were found to decrease and those of nickel, mercury, and chromium to ulerease; however, neither of these trends was observed for the lead content. One-way analyses of variance con-firm significant temporal variation only for cobalt, mercury, lead, and vanadium. Significant linear correlation coefficients (p ≤ 0.05 were found for Co-V, Cr-Ni, Cr-Pb, Co-Hg, Ni-V, and V-Pb. The first three associa-tions showed positive correlations, whereas the remaining ones had negative correlations. A factor analysis grouped the studied metals depending on their origins. The metal levels found in the muscular tissue of A. felis from the southern Gulf of México were lower than those set by national and international regulations.

  17. The Speciation of heavy metals in marine sediments; La especiacion de los metales pesados en los sedimentos marinos

    Energy Technology Data Exchange (ETDEWEB)

    Arribas Rojo, P.; MaraNon Maison, E.; Garcia Mendez, R. [Departamento de Ingenieria Quimica, Tecnologia del Medio Ambiente, Universidad de Oviedo (Spain)

    1995-12-31

    The specification of metals is essential for establishing the toxicity hazard they represent. The area at the bottom of the water column, in this case sediments, is of particular interest. The different fractionation techniques applied, such as filtration, dialysis, ion exchange and photo oxidation, are described as well as aggressive techniques such as digestion and ultraviolet light. Several specification approaches combining these operations are presented together with acknowledgement of their authors. Separation is carried out according to size, charge, polarity and degree of oxidization or bonding force. Finally the factors affecting their bioavailability of trace metals are discussed. They can lead to bioaccumulation in organisms with consequent negative effects on the ecosystem. (Author) 63 refs.

  18. Heavy metal removal from produced water using retorted shale; Remocao de metais pesados em aguas produzidas utilizando xisto retortado

    Energy Technology Data Exchange (ETDEWEB)

    Pimentel, Patricia M.; Melo, Marcos A.F.; Melo, Dulce M.A.; Silva Junior, Carlos N.; Assuncao, Ary L.C. [Universidade Federal do Rio Grande do Norte (UFRN), Natal, RN (Brazil); Anjos, Marcelino J. [Universidade Federal, Rio de Janeiro, RJ (Brazil). Coordenacao dos Programas de Pos-graduacao de Engenharia

    2004-07-01

    The Production of oil and gas is usually accompanied by the production of large volume of water that can have significant environmental effects if not properly treated. In this work, the use of retort shale was investigated as adsorbent agent to remove heavy metals in produced water. Batch adsorption studies in synthetic solution were performed for several metal ions. The efficiency removal was controlled by solution pH, adsorbent dosage, and initial ion concentration and agitation times. Two simple kinetic models were used, pseudo-first- and second-order, were tested to investigate the adsorption mechanisms. The equilibrium data fitted well with Langmuir and Freundlich models. The produced water samples were treated by retorted shale under optimum adsorption conditions. Synchrotron radiation total reflection X-ray fluorescence was used to analyze the elements present in produced water samples from oil field in Rio Grande do Norte, Brazil. The removal was found to be approximately 20-50% for Co, Ni, Sr and above 80% for Cr, Ba, Hg and Pb. (author)

  19. Determination of some heavy metals in wetlands by PIXE; Determinacion de algunos metales pesados en jales por medio de PIXE

    Energy Technology Data Exchange (ETDEWEB)

    Ramirez O, J.; Rios M, C. [UAZ, 98160 Zacatecas (Mexico)

    2008-07-01

    In this work the results of the analysis are presented, using the PIXE technique (Proton Induced X-ray Emission), in soil samples of the El Bordo, Vetagrande, Zacatecas, before and after subjecting them to a lixiviation process for the recovering of gold, silver and mercury. This community is part of the mining region nearer to the Zacatecas city municipality, region in which the mining exploitation dates from the colonial time. During almost 350 years the 'yard benefit' method was used or amalgamation with mercury, process that besides having used big quantities of mercury, generated a great quantity of mineral waste calls 'mine wetlands', those that were accumulating, crawled by the rains, toward the streams that end in the prey 'The Pedernalillo'. The dispersion of wetlands them it has extended from the prey until the communities of Tacoaleche, Zoquite, Lampotal and El Bordo, embracing an approximate area of 16 x 2 Km{sup 2} and forming with the course of the time an accumulated of several millions of tons. In order to determining if the process of recovery of gold, silver and mercury make soluble to other contained metals in these wastes, samples were gathered in an area of 600 m{sup 2} in the community of The Border, Vetagrande, Zacatecas. Half of the samples were subjected to the lixiviation process in a local metal recovery plant and the other part was analyzed without processing. The analysis of both types of samples by means of the PIXE was carried out in the University of Arizona in Tucson. (Author)

  20. Silicato de cálcio como amenizante da toxidez de metais pesados em mudas de eucalipto Calcium silicate to reduce heavy metal toxicity in eucalyptus seedlings

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    Adriana Maria de Aguiar Accioly

    2009-02-01

    Full Text Available O objetivo deste trabalho foi avaliar o efeito do silicato de cálcio na redução da toxidez de metais pesados no solo para Eucalyptus camaldulensis. Foram utilizadas cinco doses de silicato de cálcio (0, 1,6, 3,2, 4,8 e 6,4 g kg-1, em solos com diferentes graus de contaminação. O experimento foi conduzido em vasos com 1,5 kg de solo, com uma muda por vaso, em esquema fatorial 4x5 (quatro graus de contaminação x cinco doses de silicato. O silicato de cálcio reduziu a toxidez de metais pesados em E.camaldulensis, retardou o aparecimento dos sintomas de toxidez e diminuiu os teores de zinco e cádmio na parte aérea das plantas. Entretanto, não evitou totalmente a depressão no crescimento, nos solos com contaminação elevada. O efeito amenizante do silicato foi crescente com o aumento das doses e mais evidente nos solos com contaminação elevada. O efeito benéfico do silicato de cálcio está relacionado à redução da transferência do zinco para a parte aérea do eucalipto.The objective of this study was to evaluate the effect of calcium silicate to reduce heavy metal toxicity in Eucalyptus camaldulensis seedlings. Five doses of calcium silicate (0, 1.6, 3.2, 4.8, and 6.4 g kg-1 were used in soils with increasing levels of contamination. The experiment was carried out in pots with 1.5 kg of soil, with one plant each, in a 4x5 factorial array (four levels of contamination x five silicate doses. Calcium silicate minimized heavy metal toxicity to E.camaldulensis, delayed the onset of toxicity symptoms, and decreased zinc and cadmium shoot concentrations. However, calcium silicate did not completely overcome the depressive effect upon plant growth in soils with high metal concentrations. Calcium silicate effects increased with increasing doses and were more evident in highly contaminated soils. The beneficial effects of calcium silicate on metal toxicity were highly related to the decrease in zinc translocation to the eucalyptus shoots.

  1. Avaliação da integridade e da retenção de metais pesados em materiais estabilizados por solidificação Assessment of integrity and retention of heavy metals in materials stabilized by solidification

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    André Luiz Fiquene de Brito

    2009-03-01

    Full Text Available A quantidade de resíduos sólidos industriais tem aumentado significativamente em decorrência da industrialização, e o seu gerenciamento adequado é necessário para reduzir o impacto ao meio ambiente e aos ecossistemas. Neste trabalho, foram avaliadas a integridade e a retenção de metais pesados em materiais estabilizados por solidificação. Foi adotado o planejamento completamente aleatorizado com um único fator, ou seja, foram comparadas as médias de quatro tratamentos (A, B, C e D com 0, 40, 50 e 60% respectivamente de contaminantes e três repetições. Cimento Portland comum, bentonita sódica e hidróxido de cálcio foram usados para estabilizar por solidificação o resíduo sólido sintético contendo óxido de Cd2+, Pb2+ e Cu2+. Pode-se concluir que os tratamentos influenciaram no resultado de lixiviação do cádmio, chumbo e cobre. Os tratamentos mostraram que as concentrações do extrato solubilizado e lixiviado aumentam em função da quantidade de cádmio, chumbo e cobre adicionada. O maior valor encontrado foi para o material proveniente do tratamento D, que apresentou lixiviação igual a 32,815 mg.kg-1 para o cádmio e 29,769 mg.kg-1 para o chumbo. Para os ensaios de integridade/durabilidade, constatou-se que o aumento da absorção de água fez com que a resistência à compressão diminuísse. O uso de cimento, de hidróxido de cálcio e de bentonita sódica se mostrou ideal para retenção de metais pesados, evitando a sua lixiviação e a solubilização para o meio ambiente.As the quantity of hazardous industrial wastes increases significantly owing to rapid industrialization, its appropriate management is required to reduce adverse impacts on humans and ecosystems. This work evaluated the integrity and retention of heavy metals in materials stabilized by solidification. It was adopted a completely randomized design with a single factor, that is, the averages of four treatments were compared (A, B, C and D with 0

  2. Metais pesados em LATOSSOLO tratado com lodo de esgoto e em plantas de cana-de-açúcar Heavy metals in an Oxisol treated with sewage sludge and in sugarcane plants

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    Fernando Carvalho Oliveira

    2001-09-01

    Full Text Available A presença de metais pesados no lodo de esgoto constitui um dos maiores entraves para sua aplicação em solos agrícolas. Neste contexto, o presente trabalho teve como objetivos avaliar os efeitos de aplicações sucessivas de lodo de esgoto sobre o acúmulo de metais pesados num LATOSSOLO AMARELO Distrófico e em plantas de cana-de-açúcar e a fitodisponibilidade desses elementos através de extratores químicos. O experimento foi conduzido nos anos agrícolas 1996/97 e 1997/98 sendo que, no primeiro ano, além dos tratamentos calagem + adubação mineral e testemunha, foram aplicadas em área total, doses equivalentes a 33, 66 e 99 mg ha-1 (base seca de lodo de esgoto. Em 1997/98 o lodo foi reaplicado em doses equivalentes a 37, 74 e 110 mg ha-1 (base seca. Foram detectados acúmulos de Cu, Cr, Ni e Zn na camada 0 0,2 m do solo. As concentrações de Cd, Cr, Ni e Pb nas amostras de plantas de cana-de-açúcar estiveram abaixo dos limites de determinação do método analítico empregado, porém, no caldo, a presença de Cd, Cr e Ni, esteve abaixo de 0,02 mg kg-1. Os teores de Cu e Zn nas várias partes da cana-de-açúcar não foram superiores aos limites normais de variação encontrados na literatura. As soluções extratoras apresentaram eficiência apenas na avaliação da fitodisponibilidade do Zn, determinado nas amostras de colmo e caldo, no ano agrícola 1997/98.The concern about the presence of heavy metals in plants growing in soils treated with sewage sludge can be a restricting factor for the use of this waste in agriculture. The aim of this paper was to evaluate the possibility of heavy metal accumulation in an acid soil after two successive sewage sludge applications and the availability, using chemical extractants for a typic hapludox, of these metals to sugarcane plants. The experiment was managed during two years, 1996/1997 and 1997/1998, and had 5 treatments in a randomized block design: lime + mineral fertilization

  3. Efeito do período de incubação e de doses de composto de lixo urbano na disponibilidade de metais pesados em diferentes solos Effect of incubation period and doses of urban trash compost on the readiness of heavy metal in different soils

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    Fábio Cesar da Silva

    2003-03-01

    Full Text Available O uso do composto de lixo nas lavouras constitui alternativa econômica e ambiental viável, por ser fonte considerável de nutrientes e matéria orgânica. Este estudo, realizado em casa de vegetação, teve como objetivo avaliar a disponibilidade temporal dos metais pesados Cd, Co, Cr, Ni e Pb, por meio do extrator Mehlich-1, em cinco tipos de solos, incubados com 0, 25, 50 e 100 Mg ha-1 de composto de lixo, em períodos de 0, 16, 32, 64 e 150 dias. A maioria dos metais pesados teve sua disponibilidade reduzida nos primeiros períodos de incubação, sendo esse efeito dependente de textura, pH e teor de matéria orgânica do solo. O uso continuado de composto de lixo, principalmente nas doses mais elevadas, pode resultar em riscos de contaminação do ambiente pelo efeito cumulativo, em especial nos solos Latossolo Vermelho-Amarelo distrófico, Chernossolo Háplico órtico e Nitossolo Vermelho eutroférrico, cujo período para redução da disponibilidade dos metais pesados varia de 6 a 12 meses.The agricultural use of urban waste compost is an alternative for a better technician-scientific-economic viability, because this organic residue is a source of nutrients and organic matter. This study was carried out in greenhouse conditions in order to evaluate the temporal availability, by Mehlich-1 extractor, of Cd, Co, Cr, Ni, and Pb in five types of soils incubated with 0, 25, 50 and 100 Mg ha-1 of waste compost during 0, 16, 32, 64 and 150 days. Most of the heavy metals had its availability reduced at the beginning of incubation. The availabitily of heavy metals was dependent of the soil texture, pH and content of soil organic matter. The application of the highest doses of waste compost can result in risks of soil contamination mainly in the Oxisol, Mollisol and Alfisol, with periods from 6 to 12 months for reduction of heavy metal availability.

  4. BOTANICAL DIVERSITY AND HEAVY METAL CONTENT IN THE RESIDUE MATRIX AND PLANTS AT THE MORAVIA DUMP IN MEDELLÍN, COLOMBIA DIVERSIDAD BOTÁNICA Y CONTENIDO DE METALES PESADOS EN LA MATRIZ DE RESIDUOS Y LAS PLANTAS EN EL BASURERO DE MORAVIA EN MEDELLÍN, COLOMBIA

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    Maria Solange Sanchez Pinzón

    2010-06-01

    Full Text Available . Floristic characterization, plant tissue and residue matrix (RM analysis were conducted to establish the extent of heavy metal (HM pollution of the Moravia dump at Medellín, Colombia, a site that was inhabited by more than 17000 people since 1984. More than 65 plant species (28 families were identified, most of which were herbaceous. Content of HM in the (RM was determined in 14 different RM samples varied greatly among them, reaching 121 and 9600 mg/kg of Hg and Pb respectively. Mean content of HM (mg/kg in the RM had the following pattern: Pb > Ni > Cr > Hg > Cd. Uptake of HM from the RM to plants was evident in most sampled species, with concentrations of Pb, Cr, and Hg reaching maximum values of 1.0, 123.7, 263.7 mg/kg of Hg, Pb and Cr respectively. However, Lepidium virginicum excluded, estimated bioconcentration factors were not greater than 1.0. Given their adaptation, Bidens pilosa, Urochloa maxima and L. virginicum, appear to be suitable for the revegetation of Moravia. Twenty-four years after its closure, HM content in Moravia continue to be high and the local flora actively takes up HM. Since other studies have shown that in Moravia there is still production of lixiviates and that there is an active heavy metal transference to the local Moravia fauna, it is imperative to implement adequate control measures in order to control HM contamination at this site.Con el fin de establecer el nivel de contaminación por metales pesados (MP, se llevó a cabo una caracterización florística y análisis de la matriz de residuos (MR y muestras de tejidos vegetales en el morro de basuras de Moravia en Medellín, un antiguo botadero de basuras habitado desde 1984 por más de 17.000 personas. Se identificaron más de 65 especies vegetales, la mayoría de ellas herbáceas, agrupadas en 28 familias. El contenido de MP en 14 diferentes muestras de MR varió considerablemente, yendo de 121 y 9.600 mg/kg de Hg y Pb, respectivamente. El contenido

  5. Contaminación por metales pesados en la Cuenca del Río Moche, 1980 – 2010, La Libertad – Perú

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    Félix Huaranga Moreno

    2012-01-01

    Full Text Available La contaminación de las aguas continentales es un problema de escala mundial,principalmente debido alimpacto de los relaves mineros. Utilizando tecnologías de punta,como plantas de neutralización de aguasácidas,muchas empresas están mitigando el impacto de su funcionamiento; por lo que tomando comoreferencia los cambios en la concentración de metales pesados presentes en aguas, suelos y cultivos de lacuenca alta, media y baja del río Moche, se realizaron muestreos de agua en ocho estaciones del río Moche(Trujillo, Perú, y en cuatro sectores de sus márgenes para suelos y cultivos. Los metales pesados másrepresentativos en el agua se presentaron en el Cuenca Alta durante el año de 1980: hierro (557.500 ppm,plomo (100.375 ppm, cadmio (4.550 ppm, cobre (6.900 ppm, zinc (262.900 ppm y arsénico (9.000 ppm;mientras que en los suelos las mayores concentraciones se encontraron en la margen derecha de la CuencaBaja para el año 1980: hierro (83.400 mg/kg; plomo (0.820 mg/kg; cadmio (0.012 mg/kg; cobre (1.240mg/kg; zinc (0.380 mg/kg y arsénico (0.016 mg/kg; en relación con la acumulación de metales en loscultivos, el hierro (0.6525 mg/kg fue el de mayor predominio, siendo la yuca (Manihot esculentus el cultivodonde se presentó. Se concluye que la mayor contaminación a nivel del análisis de agua se presentó en lacuenca alta y durante el año de 1980; mientras que la margen derecha de la cuenca media presentó los mayoresniveles de contaminación en las muestras de suelos; así como a nivel de los cultivos, la yuca (Manihotesculentus fue la especie más contaminada.

  6. Applicability of Moringa oleifera Lam. pie as an adsorbent for removal of heavy metals from waters Aplicabilidade da torta de Moringa oleifera Lam. como adsorvente para remoção de metais pesados de águas

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    Affonso C. Gonçalves Junior

    2013-01-01

    Full Text Available This study evaluated the efficacy of moringa seeds (Moringa oleifera Lam. as an adsorbent material for removing toxic heavy metals such as cadmium, lead, and chromium from contaminated solutions. The effect of the adsorbent mass was investigated at two pH conditions (5.0 and 7.0. The optimized conditions were 0.300 g of adsorbent at pH 5.0, used for the isotherms construction, and linearized according to Langmuir and Freundlich models. Results showed that cadmium adsorption was similar in both the models used. For lead, the Freundlich model had the best adjustment and chromium was better adjusted by the Langmuir model. It was concluded that the adsorbent was effective in the remediation of solutions containing cadmium, lead and chromium, thus, its use as sustainable alternative material is feasible, since it has low cost, does not need a previous treatment and it is a byproduct.Este estudo objetivou avaliar a eficácia do uso da torta de moringa (Moringa oleifera Lam. como material adsorvente dos metais pesados tóxicos cádmio (Cd, chumbo (Pb e cromo (Cr de soluções contaminadas. Nos testes cinéticos foram variadas as massas do adsorvente em duas condições de pH (5,0 e 7,0. As condições otimizadas foram pH 5,0 e massa de 0.300 g de adsorvente, utilizados para a construção das isotermas e linearizadas conforme os modelos de Langmuir e Freundlich. Realizou-se a determinação dos metais por espectrometria de absorção atômica. Os resultados mostraram que houve semelhança em ambos os modelos utilizados para a adsorção do Cd. Para o Pb, o modelo de Freundlich apresentou o melhor ajuste e, para o Cr, houve melhor ajuste pelo modelo de Langmuir. Conclui-se, com base nos resultados obtidos, que o adsorvente foi eficaz na remediação de soluções contendo Cd, Pb e Cr e, assim, é viável a utilização desse adsorvente como material alternativo sustentável, pois apresenta baixo custo, não necessita de tratamento prévio e se trata de

  7. Avaliação das espécies de plantas avicennia schaueriana, laguncularia racemosa e rhizophora mangle como bioindicadoras de poluição por metais pesados em ambientes de mangues Assessment of avicennia schaueriana, laguncularia racemosa e rhizophora mangle plant species as bioindicator of heavy metal pollution in mangrove environments

    Directory of Open Access Journals (Sweden)

    Miriam Gonçalves Martins Ramos

    2007-12-01

    Full Text Available Neste trabalho, investigou-se o nível de contaminação por Cd, Cr, Cu, Pb e Zn, nos ambientes de mangues próximos ao Rio Cubatão, utilizando como bioindicador as espécies de plantas A. schaueriana, L. racemosa e R. mangle. As amostras de folhas destas plantas foram coletadas em quatro pontos de amostragem situados fora da área povoada da cidade de Cubatão. O conteúdo de metais pesados nas folhas foi determinado utilizando a técnica de Espectrometria por Absorção Atômica (FAAS. Os resultados obtidos indicam uma contaminação por cádmio e cromo em diversas amostras analisadas neste trabalho. De uma forma geral, as três espécies de plantas apresentaram resultados muito similares tanto no teor como na ordem em que bioacumulam os metais estudados: Zn > Pb > Cr > Cu > Cd. Desta forma, em princípio, qualquer uma delas poderia ser utilizada como bioindicador de poluição ambiental por metais pesados naquela região.In this work, the contamination level by Cd, Cr, Cu, Pb and Zn in mangrove environments near the Cubatão River has been investigated using as bioindicator the plant species A. schaueriana, L. racemosa and R. mangle. Leave samples of these plants were collected in four locals situated out of the populated area of the Cubatão town. The heavy metals content in the leaves were determined by the Flame Atomic Absorption Spectrometry (FAAS technique. The results obtained have shown some contamination by cadmium and cromium for several leave samples analysed in this work. In general, the three species of plants presented similar results concerning the content as well as the bioaccumulation order for the studied metals: Zn > Pb > Cr > Cu > Cd. In this way, any one of them could, in principle, be employed as bioindicator of heavy metal environmental pollution in that region.

  8. Alternatives for recovering metals from spent catalysts for hydrotreating of heavy hydrocarbons: a case study; Alternativas para la recuperacion de metales a partir de catalizadores gastados del hidrotratamiento de hidrocarburos pesados: un caso de estudio

    Energy Technology Data Exchange (ETDEWEB)

    Alonso, Fernando; Ramirez, Sergio; Ancheyta, Jorge; Mavil, Martha [Instituto Mexicano del Petroleo, Mexico, D.F. (Mexico)]. E-mail: jancheyt@imp.mx

    2008-05-15

    The increasing production of spent hydrotreating catalysts used for processing heavy hydrocarbons and the problems related to their disposal are described in this work. These catalysts contain important amounts of heavy metals such as molybdenum (Mo), nickel (Ni), cobalt (Co) and vanadium (V), which can be recovered and hence an economical benefit may be obtained. The results of experimental tests for alkaline leaching (NaOH) to recover V and Mo, and the effect of operating conditions on metal recovery are also presented. The results show that, in general, the highest recovery of Mo is obtained at pH 8.5 and leaching time of 12 hours, while in the case of V, the highest recovery is observed at pH 9.0 and 8 hours. In both cases, the leaching solution contained 10 wt % alkaline. Based on the experimental information and data from a commercial plant, a preliminary economy study was developed, in which the expected economical benefits of metals recovery from spent catalysts used for hydrotreating heavy hydrocarbon are estimated. [Spanish] En el presente trabajo se describe la problematica de la creciente produccion de catalizadores gastados de los procesos de hidrotratamiento de hidrocarburos pesados. Estos catalizadores contienen cantidades importantes de metales pesados como molibdeno (Mo), niquel (Ni), cobalto (Co) y vanadio (V), que son susceptibles de recuperarse y obtener con ello un beneficio economico. Tambien se presentan resultados de pruebas experimentales de lixiviacion alcalina (NaOH) para la recuperacion de V y Mo, y el efecto de las variables de operacion sobre la recuperacion de metales. En general, se encontro que las mejores recuperaciones de Mo fueron a pH de 8.5 y 12 h, mientras que para el V fueron a pH de 9.0 y 8 h, ambos a una concentracion del agente lixiviante de 10% en peso. Con base en la informacion experimental obtenida y datos de una planta industrial se presenta un estudio economico preliminar, en el que se estiman los beneficios

  9. Teores de metais pesados e caracterização mineralógica de solos do Cemitério Municipal de Santa Cândida, Curitiba (PR Heavy metal contents and mineralogical characterization of soils from the Santa Cândida Municipal Cemetery, in Curitiba (PR, brazil

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    Yara Jurema Barros

    2008-08-01

    , em parte determinadas pelo material de origem, não apresentaram relação de causa e efeito com metais pesados nas áreas estudadas.The metal pieces of coffins, such as handles and adornments, are considered the main source of soil heavy metal contamination. Other sources of pollutants are the products used in the body embalming, wood preservatives and fluids released from body decomposition. The purpose of this study was to investigate the clay fraction mineralogy and heavy metal contents of soils from Santa Cândida Municipal Cemetery, in Curitiba (PR, and estimate the contamination risk. The samples were collected at three depths (0-20, 20-80 and 80-120 cm at seven selected points, representing two parent materials (granite/gneiss and claystone and two burial modalities (unmarked graves and mausoleum area. The clay fraction was studied by X ray diffractometry and thermal analysis, and Fe and Al contents were determined, after acid ammonium oxalate (amorphous Fe and Al oxides and sodium citrate-bicarbonate-dithionite (crystalline Fe oxides extractions, by atomic absorption spectroscopy (AAS. The total and exchangeable heavy metal contents were determined by AAS, after sample digestion with concentrated HF and BaCl2 1 mol L-1 solution, respectively. The predominance of kaolinite and occurrence of vermiculite with Al-hydroxy interlayers and smectite determined the high values of soil CEC. Heavy metal contents were higher in the mausoleum area, where the highest Cr and Pb contents were found (516.3 and 260.2 mg kg-1, respectively. The lower metal contamination in the area of unmarked graves may be attributed to simpler burial practices, with less potential heavy metal sources, such as wood preservatives and metal parts of coffins. No cause-effect relation was observed between the chemical and mineralogical soil characteristics, in part determined by the parent material, and the heavy metal contents in the studied area.

  10. Metodologías para establecer valores de referencia de metales pesados en suelos agrícolas: perspectivas para Colombia Methods for establishing baseline values for heavy metals in agricultural soils:: Prospects for Colombia

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    Germán Rueda Saa

    2011-07-01

    Full Text Available Los impactos ambientales de los metales pesados en los suelos están relacionados con su carácter tóxico cuando se acumulan o interactúan con algunas propiedades específicas, se movilizan a través del perfil a la cadena trófica mediante los cuerpos de agua o los cultivos y pueden llegar a afectar la salud humana. En países desarrollados el establecimiento de valores de referencia de estos metales ha permitido el mejoramiento de la planeación y la gestión ambiental del recurso suelo, y se ha convertido en un instrumento de control para las entidades ambientales que ha permitido evaluar el impacto en diferentes actividades agrícolas. En este artículo se analizan diversos conceptos relacionados con los niveles de metales pesados en suelos agrícolas y la incidencia de las características edafológicas en su concentración. Se revisan, igualmente, algunas metodologías para derivar valores de referencia específicos aplicables a suelos agrícolas colombianos, y se plantean algunas perspectivas orientadas a la protección y recuperación de suelos en el país. En Colombia en la actualidad no se cuenta con criterios y estándares de calidad para medir la contaminación por metales pesados en suelos agrícolas; por esto se hace necesario gestionar el apoyo de entidades gubernamentales con el fin de iniciar y desarrollar investigaciones en diferentes sectores agrícolas primarios, contribuyendo de esta forma a garantizar una producción más limpia y la sostenibilidad ambiental del recurso suelo.From an environmental perspective, the importance of heavy metals in soils is related to their toxicity either due to accumulation or to any interaction among them and some of their specific properties. In each case, heavy metals can move through the soil profile and transfer into the trofic chain by using through water bodies or crops affecting de human health. In developed countries, the establishment of baseline values has permitted improvements

  11. Niveles de metales pesados en el ambiente y su exposición en la población luego de cinco años de exploración minera en Las Bambas, Perú 2010

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    Jonh Astete

    Full Text Available Objetivos. Determinar las concentraciones de material particulado (PM10 y metales pesados en el ambiente, así como en población aledaña al proyecto Las Bambas luego de cinco años de exploración minera. Materiales y métodos. Estudio comparativo de corte transversal realizado en tres distritos del área de influencia del proyecto Las Bambas en la región Apurímac, Perú. Se obtuvo muestras de agua, aire y suelo para determinar las concentraciones de PM10 y metales pesados. Se tomó muestras de sangre y orina a 310 pobladores para evaluar niveles de plomo, cadmio, arsénico y mercurio. Los resultados se compararon con los obtenidos el año 2005. Resultados. Concentraciones ambientales de PM10 y metales pesados no sobrepasaron los valores referenciales establecidos. La calidad de agua de consumo y suelo no se encuentra alterada. Para el año 2010 comparado con los valores hallados el 2005, los niveles promedio de cadmio y mercurio en orina se incrementaron significativamente en la población del distrito de Chalhuahuacho (2,4 + 0,8 y 2,6 + 0,4, el Progreso (2,6 + 1,1 y 2,9 + 1,3 y Haquira (3,2 + 1,2 y 2,6 + 0,9. Los valores de cadmio superaron los límites permisibles. Conclusiones. Luego de cinco años de actividad de exploración minera, no se han visto afectadas las características ambientales de la zonas de influencia del proyecto minero Las Bambas, sin embargo, se observan cambios en los niveles de cadmio en orina y en el porcentaje de personas que lo presentan.

  12. Metal pollution (Pb, Zn, Ni and Cr) in air, road and soil sediment in a high traffic area; Contaminacion por metales (Pb, Zn, Ni y Cr) en aire, sedimentos viales y suelo en una zona de alto trafico vehicular

    Energy Technology Data Exchange (ETDEWEB)

    Manchado, Anali; Garcia, Neyma; Garcia, Cezar; Acosta, Lorena; Cordova, Alberto; Linares, Maria; Giraldoth, Debora [Centro de Investigaciones CEDEGAS, Facultad de Ingenieria, Universidad del Zulia, Maracaibo (Venezuela)]. E-mail: analimachado@yahoo.com; amachadop@luz.edu.ve; Velasquez, Harvi [Facultad Experimental de Ciencias, Universidad del Zulia, Maracaibo (Venezuela)

    2008-11-15

    sequia y de lluvia, empleando un muestreador de bajo volumen con filtros de fibra de cuarzo -para las muestras de PM10- con una frecuencia de una muestra cada tres dias para un total de 26; para los sedimentos viales y suelo fueron colectadas tres muestras con una frecuencia de 15 dias para un periodo de medicion de mes y medio en epoca seca. Todas las muestras fueron sometidas a un proceso de digestion y analizadas por espectrometria de absorcion atomica. Las concentraciones de las PM10 resultaron 2 veces mas altas en la zona de emision que en la zona de dispersion durante ambas epocas climatologicas, presentando una mejor correlacion entre las zonas para epoca de sequia. Todos los metales analizados presentaron diferencias estadisticamente significativas entre las zonas de muestreo. Por otra parte, para el periodo global existen diferencias significativas entre las zonas y las epocas climatologicas tanto para PM10 como para la totalidad de los metales. El Pb no excedio el estandar de calidad del aire establecido para Venezuela, pero su concentracion promedio en la zona de emision fue de 1.13 {mu}g/m{sup 3}, muy cercano al limite diario permitido en Venezuela y por la EPA; por su parte, tanto Pb como Ni sobrepasaron el limite permisible de la Organizacion Mundial de la Salud (OMS) en ambas zonas durante todo el periodo de muestreo. Para las muestras de sedimento y de suelo se encontraron concentraciones significativamente elevadas de Pb, Zn, Ni y Cr en comparacion con la muestra testigo. Los niveles hallados de Pb y Zn estan por encima de los limites permitidos por el decreto 2635 de la normativa venezolana y la EPA, clasificandose la zona como suelo con alta contaminacion por metales pesados. Adicionalmente, el analisis estadistico demostro la adecuada seleccion de la zona de monitoreo, confirmando que la principal fuente de emision de los contaminantes es el parque automotor.

  13. Biodisponibilidad y toxicidad de metales pesados en aguas naturales con características físico-químicas extremas. Bases para su monitoreo y remediación

    OpenAIRE

    Casares, María Victoria

    2012-01-01

    En esta tesis doctoral se presentan los resultados obtenidos en el marco de la aplicación de dos herramientas importantes para ser tenidas en cuenta en el manejo, restauración y monitoreo de ecosistemas acuáticos contaminados por metales pesados: el Modelo del Ligando Biótico y la Fitorremediación, evaluadas en dos aguas naturales de nuestro país con características físico-químicas extremas, como lo constituyen las aguas del Río Pilcomayo, caracterizadas por los elevados valores de sus iones ...

  14. Crescimento e teor de metais de mudas de espécies arbóreas cultivadas em solo contaminado com metais pesados Growth and metal concentration of seedlings of woody species in a heavy metal contaminated soil

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    Teresa Cristina Lara Lanza de Sá e Melo Marques

    2000-01-01

    Full Text Available O objetivo do trabalho foi avaliar o teor de metais pesados e o crescimento de mudas de 20 espécies arbóreas tropicais em solo com elevado grau de contaminação com metais pesados. Em casa de vegetação, as mudas foram transplantadas para vasos contendo 3,3 kg de misturas com diferentes proporções (0, 20, 40 e 60% v/v de solo contaminado. Verificou-se comportamento diferenciado das espécies quanto à inibição de crescimento e aos teores de metais na raiz e na parte aérea em decorrência da contaminação. Com base na produção de matéria seca da parte aérea, concluiu-se que apenas Myrsine umbellata, Cedrella fissilis, Tabebuia impetiginosa e Copaifera langsdorffii não foram afetadas pela contaminação, enquanto Hymenaea courbaril, Mimosa caesalpiniaefolia, Acacia mangium e Platypodium gonoacantha sofreram pequeno impacto. As demais espécies foram muito inibidas pela contaminação do solo, o que é causado pela absorção, na maioria dos casos, de Zn e Cd. Várias espécies apresentaram elevada capacidade de reter esses metais nas raízes, evitando sua translocação para a parte aérea.The objective of the paper was to evaluate metal content and ability to grow in soil with excess of heavy metals of seedlings of 20 woody species. In the greenhouse, seedlings were transplanted to pots with 3.3 kg of soil-mixes with different proportions (0, 20, 40, 60% v/v of a heavy metal contaminated soil. It was found that plant species behaved differently in terms of growth inhibition and metal content in the shoots and roots. Based upon the dry matter yield, only Myrsine umbellata, Cedrella fissilis, Tabebuia impetiginosa and Copaifera langsdorffii were not affected by increasing contamination, whereas Hymenaea courbaril, Mimosa caesalpiniaefolia, Acacia mangium and Platypodium gonoacantha were only slightly affected by it. All the other species were highly inhibited by the excess of metals in the soil, being such effects related, in most

  15. Assessment of heavy metals in soils of a vineyard region with the use of principal component analysis Avaliação de metais pesados em solos de região de vinhedos com o uso da análise dos componentes principais

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    Gustavo Souza Valladares

    2009-06-01

    Full Text Available Agricultural management with chemicals may contaminate the soil with heavy metals. The objective of this study was to apply Principal Component Analysis and geoprocessing techniques to identify the origin of the metals Cu, Fe, Mn, Zn, Ni, Pb, Cr and Cd as potential contaminants of agricultural soils. The study was developed in an area of vineyard cultivation in the State of São Paulo, Brazil. Soil samples were collected and GPS located under different uses and coverings. The metal concentrations in the soils were determined using the DTPA method. The Cu and Zn content was considered high in most of the samples, and was larger in the areas cultivated with vineyards that had been under the application of fungicides for several decades. The concentrations of Cu and Zn were correlated. The geoprocessing techniques and the Principal Component Analysis confirmed the enrichment of the soil with Cu and Zn because of the use and management of the vineyards with chemicals in the preceding decades.O manejo agrícola com agroquímicos pode levar a contaminação dos solos por metais pesados. O objetivo deste trabalho foi aplicar a Análise dos Componentes Principais e técnicas de geoprocessamento para identificar a origem dos metais pesados Cu, Fe, Mn, Zn, Ni, Pb, Cr e Cd como contaminantes potenciais em solos agrícolas. O estudo foi desenvolvido em uma área cultivada com vinhedos no Estado de São Paulo, Brazil. Amostras de solos foram coletadas e georeferenciadas por GPS sob diferentes usos e coberturas. As concentrações dos metais nos solos foram obtidas pelo método de extração com DTPA. As concentrações de Cu e Zn foram consideradas altas na maioria das amostras pesquisadas, sendo maiores nas áreas cultivadas com vinhedos sob aplicações de fungicidas por décadas. As concentrações de Cu e Zn apresentaram correlação. As técnicas de geoprocessamento e a Análise dos Componentes Principais indicaram enriquecimento do solo com Cu e Zn

  16. Potential Of Microalgae Chlorella vulgaris As Bioremediation Agents of Heavy Metal Pb (Lead) On Culture Media

    OpenAIRE

    Rita Sulistya Dewi Endah; Nuravivah Riza

    2018-01-01

    The purpose of this study to determine the ability of Chlorella vulgaris in absorbing Pb (lead) and the effect of the variation of Pb metal concentration on the growth of Chlorella vulgaris.This study using an experimental study with complete random design with 4 treatments, namely control (without the addition of metal), Pb1 (addition of metal 1 mg / l), Pb3 (3 mg / l) and Pb5 (5 mg / l), respectively 3 replications. Exposure Pb ion in Chlorella vulgaris for 7 days. Analysis of the metal con...

  17. Efeito do composto de resíduo sólido urbano no teor de metais pesados em solo e goiabeira Effect of the urban solid waste compost in the heavy content of metals in soil and guava orchard (Psidium guajava L.

    Directory of Open Access Journals (Sweden)

    Leonardo Santos Collier

    2004-12-01

    Full Text Available O trabalho foi realizado no município de Cachoeiras de Macacu (RJ com o objetivo de avaliar as várias formas dos metais Cu, Cr, Mn, Ni, Pb e Zn em solo Gleissolo pouco húmico tratado com composto de resíduos urbanos, e as concentrações desses metais nas folhas e nos frutos de goiabeira (Psidium guajava L.. Foram utilizadas três áreas com históricos distintos: área que recebeu doses de 40 t.ha¹ de composto de resíduo sólido urbano (CRSU na superfície por onze anos consecutivos; área com uma única aplicação de CRSU na cova; e área-controle que não utilizou CRSU e sem goiabeiras. As amostras de solo foram tomadas dentro de cada área, nas camadas de 05; 515 e 1530 cm. A extração seqüencial dos metais contidos nas amostras (05 cm de terra demonstrou uma tendência de redução das formas móveis ou mais biodisponíveis de metais pesados no solo com uso do CRSU. Houve aumento nos teores de metais pesados em folhas e frutos de goiabeira cultivadas em áreas que receberam CRSU; porém os teores obtidos estavam dentro da faixa considerada normal. Há necessidade de monitoramento dos teores totais de metais no solo e nas plantas, devido ao incremento dos teores de metais pesados em solos tratados com CRSU.The work was performed in the municipal district of Cachoeiras de Macacu, Rio de Janeiro State and had as objective to obtain information on the contents of chemical forms of Cu, Cr, Mn, Ni, Pb and Zn in soil Gleissolo pouco húmico treated with composted urban residues, and the concentrations in the leaves and fruits of guava (Psidium guajava L.. Three areas with different land use history were used: area that received doses of 40 t.ha¹ of composted of urban solid residue (CRSU in the surface for eleven consecutive years; area with only one application of CRSU in the hole; and control area, with no guava and no CRSU. The soil samples were taken from each area, in the layers of 05, 515 and 15-30 cm. The sequential extraction of

  18. Heavy metal resistance of microorganisms isolated from coal mining environments of Santa Catarina Resistência a metais pesados em microrganismos isolados de ambientes da mineração do carvão de Santa Catarina

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    Marcus Adonai Castro-Silva

    2003-11-01

    Full Text Available The coal mining activity is characterized by the generation of large amount of by-products. One of them is pyrite, which tends to acidify the water, solubilizing heavy metals. As a consequence the environment becomes acid and rich in heavy metals, selecting microorganisms able to survive in this condition, which are of great interest as bioremediation agents. This work describes the isolation and characterization of microorganisms from a coal mining area in Santa Catarina. These microorganisms comprised bacteria, fungi and yeasts resistant to zinc, nickel and cadmium.A atividade de mineração do carvão é responsável pela geração de diferentes sub-produtos. Entre esses, está a pirita que acidifica a água e acelera o processo de solubilização de metais. Como conseqüência, o ambiente torna-se ácido e rico em metais pesados, os quais selecionam os microrganismos capazes de sobreviver nestas condições. Esses microrganismos podem, por sua vez, serem empregados como agentes para a biorremediação de áreas contaminadas com metais pesados. No presente trabalho é descrito o isolamento e a caracterização de bactérias, fungos e leveduras resistentes aos metais zinco, níquel e cádmio.

  19. The solubility of metals in Pb-17Li liquid alloy

    International Nuclear Information System (INIS)

    Borgstedt, H.U.; Feuerstein, H.

    1992-01-01

    The solubility data of iron in the eutectic alloy Pb-17Li which were evaluated from corrosion tests in a turbulent flow of the molten alloy are discussed in the frame of solubilities of the transition metals in liquid lead. It is shown that the solubility of iron in the alloy is close to that in lead. This is also the fact for several other alloying elements of steels. A comparison of all known data shows that they are in agreement with generally shown trends for the solubility of the transition metals in low melting metals. These trends indicate comparably high solubilities of nickel and manganese in the liquid metals, lower saturation concentration of vanadium, chromium, iron, and cobalt, and extremely low solubility of molybdenum. (orig.)

  20. Avaliação dos níveis de metais pesados em efluente líquido percolado do aterro sanitário de Paranavaí, Estado do Paraná, Brasil = Assessment of heavy metal levels in percolated liquid from sanitary landfill in Paranavaí, Paraná State, Brazil

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    Lucila Akiko Nagashima

    2009-01-01

    Full Text Available O percolado pode conter diversas substâncias químicas com características tóxicas, dentre elas os metais pesados oriundos de vários materiais provenientes de indústrias, atividades agrícolas, laboratórios, hospitais, residências. A contaminação pormetais apresenta amplo espectro de toxicidade que inclui efeitos neurotóxicos, hepatóxicos, nefrotóxicos, teratogênicos, carcinogênicos ou mutagênicos. O objetivo deste trabalho foi aavaliação dos níveis de Cd, Cr, Cu, Mn, Ni, Pb e Zn do percolado gerado no aterro sanitário de Paranavaí - PR. As amostras foram coletadas a partir de setembro de 2006 a julho de 2007, em quatro pontos distintos nas lagoas de tratamento. Para detecção dosmetais utilizou-se o espectrofotômetro de absorção atômica com chama. Os resultados foram comparados com os limites máximos de concentração de metais em efluentes líquidos estabelecidos pela Resolução 397/2008 - Conama (BRASIL, 2008. Verificou-se que os níveis dos metais analisados, com exceção do Pb, estão dentro dos limites permissíveispela legislação ambiental.Percolated liquid may contain several chemical substances with toxic characteristics, among them heavy metals from industrial sources, agricultural activities, laboratories, hospitals and residences. Metal contamination presents a wide array of toxicities, such as neurotoxic, hepatotoxic, nephrotoxic, teratogenic, carcinogenic or mutagenic effects. The objective of this work was to assess the levels of Cd, Cr, Cu, Mn, Ni, Pb, and Zn in percolated liquid produced at the sanitary landfill in Paranavaí. The samples were collected from September of 2006 to July of 2007, at fourdistinct places of the treatment lake. An atomic absorption spectrophotometer with a burner was used to detect the metals. The results were compared with the maximum allowed values for metal concentration present in Resolution 397/2008 – Conama (BRAZIL, 2008.It was verified that the level of analyzed

  1. Presencia de metales pesados Cadmio y Plomo en el estuario del río Chone Manabí, Ecuador

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    Pozo-Miranda, Francisco

    2017-09-01

    Full Text Available The present study aims to determine the presence of cadmium and lead heavy metals in the Chone River estuary; Ecuador, during June to September 2014, six water samples and five soil samples were obtained at six sites, with two replications per site giving a total of 66 samples. The analysis was performed according to the protocol of Merck-Millipore Kit for cadmium and lead. Cadmium concentrations in the water were higher at the P4 site (0.129 mg/L. The level of cadmium in the sediment showed greater accumulation (0.0033 mg/g in the P2 site. The sites with higher level of lead were P5 and P6 (0.18 y 0.21 mg/L respectively, these were places with greater flow of water of the Chone River estuary (8 UPS: Practical Units of Salinity and less influence of the sea water currents (30 UPS. The results compared with Ecuadorian legislation show high concentrations of cadmium in the ecosystem of Chone River estuary, which could affect the health of organisms living at the water column level, such as fish, as well as recreational activities for local bathers from Sucre and San Vicente cantons from Manabí province.

  2. Estudio preliminar de la fauna en el morro de basuras de Moravia y presencia de metales pesados en artrópodos y roedores

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    Rolando Barahona

    2010-04-01

    Full Text Available Preliminary study of the fauna in the Morro de Moravia open dump and presence of heavy metals in arthropods and rodents.Characterization of the species present in a given locality by means of biological inventories provides information about diversity, even ifit is done in disturbed environments such as open dumps, which are considered a threat for health due to the accumulation of heavy metalsthat are well known for their negative effects on human health and the environment. Objectives. To carry out a preliminary characterizationof arthropods and non-flying small mammals in the Morro de Moravia open dump, and to determine the heavy metal contents in animaltissue samples. Materials and Methods. Arthropods were collected with pitfall traps and manually. Rodents were captured with Shermantraps. The heavy metal analysis was carried out with atomic spectroscopy. Results. A total of 9 orders, 51 families and 75 morphospeciesof insects, 5 families of spiders, two syrphid and a millipede species were identified; Mus musculus was the only small mammal speciesidentified. Heavy metal analysis showed various concentrations mainly of Pb and Cd. The highest content of Pb (45.05 mg/kg was foundin samples of M. musculus and the highest Cd content (10.31 mg/kg was found in spiders of the family Gasteracantha. Conclusions. TheMorro de Moravia open dump provides conditions that allow the establishment of an arthropod community with various diets and niches.The transference of heavy metals from the residue matrix towards higher levels of the trophic chain was corroborated.

  3. Estabelecimento de plantas herbáceas em solo com contaminação de metais pesados e inoculação de fungos micorrízicos arbusculares Establishment of herbaceous plants in heavy metal contaminated soils inoculated with arbuscular mycorrhizal fungi

    Directory of Open Access Journals (Sweden)

    Marco Aurélio Carbone Carneiro

    2001-12-01

    Full Text Available Neste trabalho estudou-se o estabelecimento de plantas herbáceas em solo com contaminação de metais pesados (MP e inoculação de fungos micorrízicos arbusculares (FMAs. O experimento foi realizado em bandejas, em esquema fatorial 5 x 2, sendo cinco proporções de solo contaminado com MP na ausência e presença de FMAs. Sementes de oito espécies de gramíneas e uma crucífera (mostarda -- Brassica sp. foram plantadas e cultivadas por 120 dias e avaliadas em dois cortes. No primeiro corte, as gramíneas foram severamente afetadas pela contaminação, e a mostarda foi pouco afetada, mostrando alta tolerância. No segundo corte, o efeito da contaminação foi negligível para as gramíneas, e a inoculação dos FMAs aumentou em 24% a matéria seca destas em relação ao controle sem inoculação. A inoculação teve também efeito positivo na matéria seca das raízes e na colonização micorrízica. Os teores de Cd, Zn e Pb na parte aérea foram maiores na mostarda do que nas gramíneas em ambos os cortes. Apesar de a inoculação não ter efeito no crescimento das gramíneas do primeiro corte, as plantas com inoculação apresentaram maior acúmulo de Zn, Cd e Pb no segundo corte. A maior tolerância da mostarda aos metais pesados permitiu seu crescimento e conseqüente acúmulo de Zn, Cd e Pb do solo contaminado. A extração destes elementos do solo pode ter contribuído para o melhor desenvolvimento subseqüente das gramíneas, favorecendo o estabelecimento das plantas.The establishment of herbaceous plants in soil contaminated by heavy metals (HM and inoculated with arbuscular mycorrhizal fungi (AMF was evaluated in the present study. The experiment was conducted in trays, in a 5 x 2 factorial, being five proportions of contaminated soil with or without inoculation with arbuscular mycorrhizal fungi (AMF. Seeds of eight grass species and a mustard (Brassica sp. were planted and allowed to grow for 120 days under greenhouse conditions

  4. [Immobilization of heavy metal Pb2+ with geopolymer].

    Science.gov (United States)

    Jin, Man-tong; Jin, Zan-fang; Huang, Cai-ju

    2011-05-01

    A series of geopolymers were synthesized by mixing metakaolinite, water glass, sodium hydroxide and water, and the lead ion solidification experiments were performed with the geopolymer. Then, the immobilization efficiency was characterized by monitoring the leaching concentration and compressive strength of solidified products. Additionally, the structure and properties of the solidified products were studied by X-ray diffraction (XRD), scan electron microscopy (SEM) and Fourier transform infrared (FTIR) spectroscopy. Furthermore, based on the analysis of immobilization efficiency, microstructure and mineral structure, the difference between geopolymer and cement on the performance of immobilizing heavy metals was discussed. The results of lead ion immobilization experiments showed that over 99.7% of heavy metal was captured by the geopolymer as the doping concentration of lead ion was less than 3%. Meanwhile, the compressive strength of the solidified product ranged from 40 MPa to 50 MPa. Furthermore, by using the same Pb2+ concentration, the geopolymer showed higher compressive strength and lower leaching concentration compared to the cement. Because lead ion participated in constitution of structure of geopolymer, or Pb2+ was adsorbed by the aluminium ions on the geopolymeric skeleton and held in geopolymer. However, cement mainly solidified lead ion by physical encapsulation and adsorption mechanism. Therefore, both from the compressive strength and leaching concentration and from the microstructure characterization as well as the mechanism of the geopolymerization reaction, the geopolymer has more advantages in immobilizing Pb2+ than the cement.

  5. Potential Of Microalgae Chlorella vulgaris As Bioremediation Agents of Heavy Metal Pb (Lead) On Culture Media

    Science.gov (United States)

    Dewi, Endah Rita Sulistya; Nuravivah, Riza

    2018-02-01

    The purpose of this study to determine the ability of Chlorella vulgaris in absorbing Pb (lead) and the effect of the variation of Pb metal concentration on the growth of Chlorella vulgaris.This study using an experimental study with complete random design with 4 treatments, namely control (without the addition of metal), Pb1 (addition of metal 1 mg / l), Pb3 (3 mg / l) and Pb5 (5 mg / l), respectively 3 replications. Exposure Pb ion in Chlorella vulgaris for 7 days. Analysis of the metal content of Pb concentration performed on culture media after exposure it at 3 hours after dispersion Chlorella vulgaris and on day 7 of culture using the AAS method. Do also counting the growth of cells each day. The results of the analysis of the average metal content of Pb in the culture medium at the end of the study was the control (0.1980), Pb1 (0.1453), Pb3 (0.4144) and Pb5 (0.5305). While the average growth of Chlorella vulgaris at the end of the study were control (630.1116 x 104), Pb1 (829.0012 x 104), Pb3 (1069.9446 x 104) and Pb 5 (808.94450 x 104). The results of the analysis of the content of Pb in the F test shown that the difference in concentration of water Pb given real influence on the ability of Chlorella vulgaris in absorbing Pb and growth. The conclusion of this study was Chlorella vulgaris has the ability to absorb metals in the waters, and the provision of various concentrations of Pb can affect the growth of Chlorella vulgaris.

  6. Potential Of Microalgae Chlorella vulgaris As Bioremediation Agents of Heavy Metal Pb (Lead On Culture Media

    Directory of Open Access Journals (Sweden)

    Rita Sulistya Dewi Endah

    2018-01-01

    Full Text Available The purpose of this study to determine the ability of Chlorella vulgaris in absorbing Pb (lead and the effect of the variation of Pb metal concentration on the growth of Chlorella vulgaris.This study using an experimental study with complete random design with 4 treatments, namely control (without the addition of metal, Pb1 (addition of metal 1 mg / l, Pb3 (3 mg / l and Pb5 (5 mg / l, respectively 3 replications. Exposure Pb ion in Chlorella vulgaris for 7 days. Analysis of the metal content of Pb concentration performed on culture media after exposure it at 3 hours after dispersion Chlorella vulgaris and on day 7 of culture using the AAS method. Do also counting the growth of cells each day. The results of the analysis of the average metal content of Pb in the culture medium at the end of the study was the control (0.1980, Pb1 (0.1453, Pb3 (0.4144 and Pb5 (0.5305. While the average growth of Chlorella vulgaris at the end of the study were control (630.1116 x 104, Pb1 (829.0012 x 104, Pb3 (1069.9446 x 104 and Pb 5 (808.94450 x 104. The results of the analysis of the content of Pb in the F test shown that the difference in concentration of water Pb given real influence on the ability of Chlorella vulgaris in absorbing Pb and growth. The conclusion of this study was Chlorella vulgaris has the ability to absorb metals in the waters, and the provision of various concentrations of Pb can affect the growth of Chlorella vulgaris.

  7. Heavy metal biosorption by chitin and chitosan isolated from Cunninghamella elegans (IFM 46109 Remoção de metais pesados por quitina e quitosana isoladas de Cunninghamella elegans (IFM 46109

    Directory of Open Access Journals (Sweden)

    Luciana de Oliveira Franco

    2004-09-01

    Full Text Available Chitin and chitosan were extracted from mycelial biomass of Cunninghamella elegans and the performance for copper, lead and iron biosorption in aqueous solution was evaluated. The growth curve of C. elegans was accomplished by determination of biomass, pH, glucose and nitrogen consumption. Chitin and chitosan were extracted by alkali-acid treatment and the yields were 23.8 and 7.8%, respectively. For the adsorption analysis, the process of heavy uptake metal sorption was evaluated using polysaccharides solutions (1% w/v. The rate of metallic biosorption was dependent upon the concentration and pH of metal solutions, and the best results were observed with pH 4.0. Chitosan showed the highest affinity for copper and chitin for iron adsorption. The results suggest that C. elegans (IFM 46109 is an attractive source of production of chitin and chitosan, with a great potential of heavy metals bioremediation in polluted environments.Quitina e quitosana foram extraídas a partir da massa micelial de Cunninghamella elegans (IFM 46109 e avaliou-se a aplicação destes polissacarídeos na remoção dos metais pesados cobre, chumbo e ferro preparados em solução aquosa. O crescimento de C. elegans foi acompanhado através da determinação de biomassa, pH, consumo de glicose e de nitrogênio. A extração de quitina e quitosana realizou-se através de tratamento álcali-ácido e a produção dos polissacarídeos foi de 23,8 e 7,8 %, respectivamente. A avaliação do processo de remoção dos metais pesados foi realizada utilizando-se os polissacarídeos em solução a 1% (p/v. Os níveis de biossorção de metais foram dependentes da concentração e do pH das soluções. Os melhores resultados foram obtidos em pH 4,0. A quitosana mostrou maior índice de biossorção para o íon cobre e a quitina para o ferro. Os resultados sugerem que C.elegans pode ser considerada uma fonte atrativa para a produção alternativa de quitina e quitosana, e que demonstra

  8. Aplicaciones de los minerales arcillosos de Cayo Guan, Cuba, como adsorbentes de metales pesados y materia prima cerámica

    Directory of Open Access Journals (Sweden)

    Fonseca, D.

    2012-10-01

    Guan, municipio de Moa, hay junto a las importantes explotaciones industriales de lateritas, minerales arcillosos cuya caractarización química, mineralógica y evolución de fases con la temperatura han sido objeto de estudio por estos autores en un anterior trabajo; entre las características físicas, químicas y mineralógicas del yacimiento destacan los altos contenidos de óxidos de hierro y aluminio, bajas concentraciones de SiO2 y óxidos alcalinos, y la caolinita como mineral más abundante, además de hematita, gibsita y goethita en forma de geles. Se pretende en esta investigación estudiar sus propiedades tecnológicas para dilucidar la posible aplicabilidad a estos recursos minerales en la fabricación de ladrillos, baldosas de pasta roja, gres rústico y para la inmovilización de metales pesados en efluentes acuosos. El estudio por microscopía óptica de calefacción de los minerales arcillosos, indica que son unos materiales refractarios cuyo reblandecimiento aparece después de los 1500 ºC. El diagrama de trabajabilidad de las diferentes arcillas y el cálculo de la plasticidad por el método de la cuchara de Casagrande presentan dentro de la zona favorable para la extrusión sólo a una de las muestras. Los diagramas de gresificación informan que es a partir de 1400 ºC cuando se consigue una capacidad de absorción de agua < 0,6 %. El diseño de un programa ha posibilitado el cálculo de múltiples composiciones de un gres porcelánico preparado a partir de dichas arcillas, modificadas con materias primas de bajo coste que facilitan la formación de fase vítrea (feldespato potásico y casco de vidrio y/o incrementan el contenido de sílice (arena y diatomea utilizada como filtros en la industria cervecera. Se presentan los resultados de una de ellas (60 % de mineral arcilloso, 30 % de feldespato potásico y 10 % de diatomea que calcinada a 1250 ºC con una velocidad de calentamiento de 15 ºC/min dio lugar a una absorción de agua

  9. a Simple Method to Prepare Nanoporous Sn:Pb Composite Metal Foam

    Science.gov (United States)

    Zandi, Majid; Amirhoseiny, Maryam; Mosayyebi, Abolghasem

    2015-03-01

    A novel and simple approach for preparing nanoporous binder free Sn:Pb composite metal foam has been demonstrated. The anodized metallic composite block was functionalized and also found a nanoporous structure. A scanning electron microscopy (SEM) result shows that the nanoflake-like arrangement has synthesized. The X-ray diffraction (XRD) results confirm the nanoporous structure of the Sn/Pb foam after etching with 6 M NaOH. The prepared Sn:Pb metal foam is able to be used as a super capacitors electrode to offer large areal capacitance with regards to the synergic integration of Sn and Pb metals and the unique nanoporous structure.

  10. Disponibilidade de metais pesados em Latossolo com aplicação superficial de escória, lama cal, lodos de esgoto e calcário Heavy metal exchangeable in an Oxisol with surface application of flue dust, aqueous lime, sewage sludge and limestone

    Directory of Open Access Journals (Sweden)

    Juliano Corulli Corrêa

    2008-03-01

    Full Text Available O objetivo deste trabalho foi avaliar alguns atributos químicos do solo e a disponibilidade de cádmio (Cd, cromo (Cr, níquel (Ni, mercúrio (Hg, chumbo (Pb e arsênio (As, por meio da extração pelo DTPA, em conseqüência da aplicação superficial de escória de aciaria, lama cal e lodos de esgoto centrifugados e de biodigestores, nas doses 0 (testemunha, 2, 4 e 8 Mg ha-1 e um tratamento adicional composto pela calagem superficial na dose 2 Mg ha-1. O experimento foi conduzido em delineamento de blocos ao acaso, em condições de campo, em área sob sistema plantio direto, durante 2003 e 2004. A aplicação superficial de escória de aciaria, lama cal, lodo de esgoto centrifugado e de biodigestor, até a dose 8 Mg ha-1, assim como o calcário na dose 2 Mg ha-1, não trazem problemas de disponibilidade ao ambiente, com relação aos metais pesados Cd, Cr, Hg, Pb, Ni e As, quando aplicados sobre a superfície em Latossolo Vermelho distrófico, no sistema plantio direto. A fitodisponibilidade de metais pesados às culturas da soja e aveia-preta foi nula, quando foram aplicadas doses de até 8 Mg ha-1 de lodo de esgoto, escória e lama cal sobre a superfície do solo, no sistema plantio direto.The objective of this work was to evaluate the soil chemical attributes and exchange of cadmium (Cd, chromium (Cr, nickel (Ni, mercury (Hg, lead (Pb and arsenic (As by DTPA extractor in an Oxisol with surface application of flue dust, aqueous lime, sewage sludge in rates of zero (control, 2, 4 and 8 Mg ha-1 and one additional treatment of dolomitic limestone at 2 Mg ha-1. The experiment was carried out in a randomized blocks design under field conditions, in a no-tillage system in 2003 and 2004. The surface applications of flue dust, aqueous lime and sewage sludge centrifuge and biodigestor at 8 Mg ha-1, as well as the application of limestone at 2 Mg ha-1, cause no problems of exchange to the environment, related to the heavy metals Cd, Cr, Hg, Pb, Ni

  11. Source identification of heavy metal contamination using metal association and Pb isotopes in Ulsan Bay sediments, East Sea, Korea

    International Nuclear Information System (INIS)

    Chae, Jung Sun; Choi, Man Sik; Song, Yun Ho; Um, In Kwon; Kim, Jae Gon

    2014-01-01

    Highlights: • The levels of Cu, Zn, and Pb in sediments were higher than the Korean TEL at one-third of all sites. • The primary source of metal contamination came from activities related to nonferrous metal refineries near Onsan Harbor. • Three different anthropogenic sources and background sediments could be identified as endmembers using Pb isotopes. • The major anthropogenic Pb sources were identified as imported ores from Australia and Peru. • Isotope ratios in anthropogenic Pb discharged from Ulsan Bay to offshore could be identified. - Abstract: To determine the characteristics of metal pollution sources in Ulsan Bay, East Sea, 39 surface and nine core sediments were collected within the bay and offshore area, and analyzed for metals and stable lead (Pb) isotopes. Most surface sediments (>95% from 48 sites) had high copper (Cu), zinc (Zn), cadmium (Cd), and Pb concentrations that were as much as 1.3 times higher than background values. The primary source of metal contamination came from activities related to nonferrous metal refineries near Onsan Harbor, and the next largest source was from shipbuilding companies located at the mouth of the Taehwa River. Three different anthropogenic sources and background sediments could be identified as end-members using Pb isotopes. Isotopic ratios for the anthropogenic Pb revealed that the sources were imported ores from Australia, Peru, and the United States. In addition, Pb isotopes of anthropogenic Pb discharged from Ulsan Bay toward offshore could be determined

  12. Concentrações de metais pesados em grãos de café produzidos em lavouras sobre solos originados do basalto e do arenito Caiuá Heavy metals concentration in coffee grains produced in farming under basalt and Caiuá sandstone soils

    Directory of Open Access Journals (Sweden)

    Carla Adriana Pizarro Schmidt

    2009-08-01

    Full Text Available Tendo em vista que o Brasil é um grande produtor e consumidor de café, fica evidente a importância de sua caracterização em diferentes locais de cultivo. O objetivo do presente estudo foi quantificar os teores de metais pesados em amostras de grãos de café, provenientes de lavouras implantadas em solos oriundos do basalto e do arenito Caiuá do Estado do Paraná. Foram examinadas 30 amostras de grãos de café, sendo 15 cultivados em solos predominantemente arenosos e 15 em solos argilosos. A determinação de Cromo (Cr, Cobalto (Co, Níquel (Ni, Chumbo (Pb, Cádmio (Cd, Cobre (Cu, Zinco (Zn e Manganês (Mn foi feita por espectrometria de emissão atômica com fonte de plasma induzido com Thermo Jarrel-ash ICAP 612 E (ICP-EAS. Os níveis foram variáveis entre as amostras.Considering that Brazil is a big producer and coffee consumer its evident the importance of its characterization in the different places of cultivation. The purpose of the present study was quantify the levels of high metals in coffee grains samples 'IAPAR 59' derived from farming introduced in basalt and Caiuá sandstone soils in Paraná, Brazil . Thirty ground samples were examined, being 15 of predominantly arenaceous ground and 15 of argillaceous ground. The determination of Chrome (Cr, Cobalt (Co, Nickel (Ni, Lead (Pb, Cadmium (Cd, Copper (Cu, Zinc (Zn and Manganese (Mn, was made through atomic emission spectrometry with induced plasma source with Thermo 612 Jarrel-ash ICAP E (ICP-EAS. The levels changed among the samples.

  13. Remoción de Cd y Pb y reducción de Cr(VI) en agua sintética y residual de una industria de galvanoplastia utilizando biomasa bacteriana

    OpenAIRE

    Ceron Rios, Cecilia Araceli

    2015-01-01

    La contaminación del agua por metales pesados tales como Cd, Pb y Cr(VI) se ha incrementado en forma paralela a la actividad industrial debido a la falta de cumplimiento de la normatividad en la materia y a la inadecuada disposición y manejo de desechos industriales, la exposición a metales pesados en determinadas circunstancias es la causa de la degradación y muerte de la vegetación, ríos, animales e incluso, de daños directos en el hombre. Cierto grupo de bacterias presentan la capacidad d...

  14. Desarrollo de membranas de quitosano y diseño de un equipo para la eliminación de metales pesados del agua Chitosan membrane development and design of equipment for the removal of heavy metals from water

    Directory of Open Access Journals (Sweden)

    Jesús Mora Molina

    2012-11-01

    Full Text Available El presente estudio comparó la eficiencia de la filtración con membranas de quitosano 1,75% m/v, entrecruzadas con glutaraldehído (0,08% m/v y sin entrecruzar, para estimar la capacidad de remoción de iones de cadmio, cromo y cobre de disoluciones modelo. Además, se diseñó un equipo de bajo costo para la experimentación con las membranas elaboradas. La finalidad de la investigación era emplear materiales biodegradables para remover metales pesados de aguas, mediante una técnica de bajo consumo energético y, por otra parte, generar soluciones baratas, efectivas y aplicables a problemas específicos. Se elaboraron dos fichas técnicas con información sobre las membranas y se encontró que el cromo fue el metal removido en mayor medida por las membranas entrecruzadas, ajustándose al modelo de isoterma de Freundlich. Sin embargo, no se encontró relación entre el tamaño de poro de las membranas y el grado de entrecruzamiento.A filtration technique with 1,75% m/v chitosan membranes crosslinked with glutaraldehyde (0,08% v/v was used to quantify the removal capacity of chromium, copper and cadmium ions from water. A simple and low cost filtration system was developed to use with prepared membranes.The main goal was to use biodegradable materials for removing heavy metals from water, through a low energy consumption, cheap, and specific method.As a result, two data sheets were prepared for the membranes. It was found out that chromium was the metal with the highest removal from water, by using a crosslinked membrane. Metal adsorption was best adjusted to the Freundlich isotherm model, better than Langmuir isotherm model.However, it was found no correlation between pore size and crosslinking degree.

  15. Metales pesados y toxicidad de aguas del Río Aconcagua en Chile Heavy metals and toxicity of waters of the Aconcagua River in Chile

    Directory of Open Access Journals (Sweden)

    Hernán Gaete

    2007-08-01

    Full Text Available The toxicity of surface waters in a zone with mining activity in the Aconcagua River was determined through growth inhibition bioassays of Pseudokirchneriella subcapitata, and correlated with heavy metal concentrations. Results show that the waters near the discharge of the mining effluent displayed toxicity during all periods of study; the molybdenum and copper concentration exceeded the norms of water quality. The correlations between the concentrations of metals and the growth rate of P. subcapitata varied in the different periods of the study; inverse and significant correlations with copper stand out in some periods.

  16. Evaluación de la eficiencia de una batería de filtros empacados en zeolita en la remoción de metales pesados presentes en un licor mixto bajo condiciones de laboratorio Evaluation of efficiency of a filter battery packaging zeolite in the removal of heavy metals in a mixed liquor under laboratory conditions

    Directory of Open Access Journals (Sweden)

    Diana Rocío Acevedo Cifuentes

    2011-01-01

    Full Text Available En este artículo se muestran resultados de investigación obtenidos en la remoción de los metales pesados, plomo, níquel, cromo, cadmio y mercurio, presentes en una solución compuesta por licor mixto proveniente de la planta de tratamiento de aguas residuales de San Fernando y una solución preparada con metales pesados con una concentración conocida, mediante el uso de una batería de filtros empacados en zeolita clinoptilolita. La experimentación se desarrolló bajo condiciones controladas de caudal y pH, a temperatura ambiente. Se encontró que la eficiencia de los filtros bajo las condiciones específicas de diseño es significativamente alta en la remoción de los metales pesados evaluados en la solución acuosa. Se encontró, además, que sin importar el valor de la concentración inicial, se obtuvo una remoción importante en los contaminantes luego de pasar por los filtros con una mayor eficiencia en la remoción del mercurio.This article shows the research results on the removal of five heavy metals (lead, nickel, chromium, cadmium and mercury present in a liquor made of a mixture of wastewater from San Fernando wastewater treatment plant and a solution prepared with known concentrations of heavy metals, using a series of batery filters packed with zeolita clinoptilolita. The experiments were run under controlled conditions of flow and pH, at room temperature. It was found that the removal efficiency was significantly high under the specified design conditions; also, it was found an important removal of the contaminants after passing through the filters, independently of the initial concentration, with the highest observed removal for mercury.

  17. Inhibition of the heavy metal nitrification process at the Granollers waste water treatment plant; Inhibicion del proceso de nitrificacion por metales pesados en le EDAR de Granollers

    Energy Technology Data Exchange (ETDEWEB)

    Serrano Jimenez, M.; Jorda LLona, J.; Rovira Gallejones, S.; Freixo Rey, A.; Polo Canas, P.

    2004-07-01

    Nowadays is habitual to find wastewater treatment plants with nutrient removal in which industrial wastes in collectors are capable of inhibiting the nitrification process. This article is about a procedure to follow when determining the origin of this inhibition in a WWTP and finding the best solution to the problem. Through discontinuous rests of AUR we find a strong intoxication of the WWTP activated sludge. A pilot plant is started with this sludge at laboratory level to be able to activate the process at a real plant level. A bio sorption process is started up by using activated sludge. The results of metal decrease in water and mixed liquor because of sludge washing are presented, as well as the increase in nitrification speed and other authors experience in metal adsorption by secondary sludge. (Author)

  18. Retenção de metais pesados em micélio de fungos micorrízicos arbusculares Retention of heavy metals by arbuscular mycorrhizal fungi mycelium

    Directory of Open Access Journals (Sweden)

    Lucélia Cabral

    2010-01-01

    Full Text Available This work evaluated the kinetics as well as the retention capacity of Cu, Zn, Cd, and Pb by arbuscular mycorrhizal fungi (AMF mycelium. The metal retention is a fast process with Cu being retained 3, 30, and 60 times faster than Zn, Cd, and Pb, respectively. Metal retention capacity varied amongst the different tested AMF species and decreased in the following order: Cu>Zn>>Cd>Pb. The Glomus clarum mycelium showed the highest retention capacity for Cu, Cd and Pb, whereas Zn was mostly retained by Gigaspora gigantea mycelium. The simultaneous application of all tested metals in solution decreased Cu and Zn retention by AMF mycelium. The high retention capacity of Cu and Zn by mycelium of G. clarum and G. gigantea suggests a promising use of these isolates in phytoremediation.

  19. Síntesis de zeolita LTA sobre soportes de corindón: Evaluación preliminar para la eliminación de metales pesados de efluentes acuosos

    Directory of Open Access Journals (Sweden)

    Jacas, A.

    2012-10-01

    Full Text Available The effectiveness of materials based on LTA Zeolite as active phase, for their incorporation into systems aimed at the removal of heavy metals on waste water is evaluated in a preliminary way. This type of Zeolite with the main channel of a minimum free diameter of 0,41 nm and a low SiO2/Al2O3 ratio is an interesting molecular sieve, which in turn display a high ion exchange capacity. From this point of view, LTA Zeolite crystals were obtained “in situ” by hydrothermal synthesis and characterized by x ray diffraction (XRD and scanning electron microscopy (SEM. We have studied the effect of hydrothermal synthesis time at 378 K. Likewise, the removal capacity of heavy metal from the active phase was evaluated in as a first step on diluted solutions of cooper salts at slightly acidic pH (~ 4,7.

    En este trabajo se evalúa de forma preliminar la efectividad del empleo de materiales basados en zeolita LTA, como fase activa para su incorporación en sistemas orientados a la eliminación de metales pesados presentes en aguas residuales. Este tipo de zeolitas con el canal principal de un diámetro mínimo libre de 0,41 nm y una baja relación SiO2/Al2O3 se presenta como un tamiz molecular interesante, que a su vez manifiesta una gran capacidad de intercambio iónico. Partiendo de este punto de vista, cristales de zeolita LTA fueron obtenidos “in situ” por síntesis hidrotermal y caracterizados por difracción de rayos X (DRX, y microscopia electrónica de barrido (MEB. Se ha estudiado el efecto del tiempo de tratamiento hidrotermal a 378 K. Asimismo, la capacidad de eliminación de metales pesados de la fase activa de los sistemas obtenidos fue evaluada en una primera etapa en soluciones diluidas de sales de cobre a pH ácido (~ 4,7.

  20. Batch adsorption of heavy metals (Cu, Pb, Fe, Cr and Cd) from ...

    African Journals Online (AJOL)

    cinthia

    This study was carried out to evaluate the efficiency of metals (Cu, Fe, Pb, Cr and Cd) removal from mixed metal ions solution using coconut husk as adsorbent. The effects of varying contact time, initial metal ion concentration, adsorbent dose and pH on adsorption process of these metals were studied using synthetically ...

  1. Contamination of soil by heavy metals in the mining Sierra of Cartegena La Union and its environment (Southeast Spain); Contaminacion de suelos por metales pesados en la sierra minera de Cartagena La Union y su entorno (Sureste de Espana)

    Energy Technology Data Exchange (ETDEWEB)

    Belmonte Serrato, F.; Rojo Lopez, S.; Romero Diaz, A.; Moreno Brotons, J.; Alonso Sarria, F.

    2009-07-01

    This paper analyzes the metal pollution in natural, agricultural and mineral-industrial soils in the Sierra of Cartagena La Union and its adjacent area. The analysis was conducted on 52 soil samples randomly selected and 23 samples form the bed of the channels draining to the Mar Menor and the Mediterranean sea. The results indicate high concentrations of metals that exceed, in many cases, the maximum allowable by the relevant laws of various countries, including Spain. Of note is the excessive contamination by lead (Pb) and Cinz (Zn) that doubles or even triples the maximum of the most permissive laws. (Author) 9 refs.

  2. Sistemas de preparo de solo e acúmulo de metais pesados no solo e na cultura do pimentão (Capsicum Annum L. Systems preparation of soil and accumulation of heavy metals in the soil and in the culture of pepper (Capsicum Annum L.

    Directory of Open Access Journals (Sweden)

    José Ezequiel Villarreal Núñez

    2006-02-01

    Full Text Available Este trabalho teve por objetivos determinar a influência de diferentes métodos de preparo do solo sobre as perdas por erosão de metais pesados e na contaminação do solo e de frutos de pimentão (Capsicum annuum L. com esses elementos. A avaliação foi realizada durante os meses de dezembro de 1999 a março de 2000, no ciclo de cultivo do Pimentão (Capsicum annuum L.. Foram utilizadas parcelas do tipo Wischmeier, de tamanho de 22,0 x 4,0m. Os tratamentos utilizados foram os seguintes: (i aração com trator morro abaixo e queima dos resíduos vegetais (MAQ; (ii aração com trator morro abaixo e não queima dos resíduos vegetais (MANQ; (iii aração com tração animal em nível, faixas de capim colonião a cada 7,0m (AA e (iv cultivo mínimo, com preparo de covas em nível (CM. As perdas mais elevadas de metais pesados por erosão foram verificadas no tratamento MAQ, típico da região. A concentração de Pb no fruto in natura, nos quatros sistemas de preparo do solo, e de Cd no CM estiveram acima dos limites permitidos para alimentos in natura, estando impróprios para o consumo humano Os resultados obtidos neste trabalho permitem concluir que o uso intensivo de agroquímicos associados às elevadas perdas de solo por erosão pode determinar sérios riscos de contaminação do solo, água e alimentos produzidos.The objectives of this study were to determine the influence of different soil tillage methods on the loss of heavy metals by erosion, and to evaluate the level of contamination of soil and food in Paty do Alferes County, State of Rio de Janeiro, Brazil. The experiment was conducted from December of 1999 to March of 2000, and pepper (Capsicum annuum L. was the cultivated crop. Four Wichmeier plots were installed, with an area of 22 x 4m. The treatments utilized were the following: (i tillage with machinery and operation down hill and burning of the grassland (MAQ; (ii tillage with machinery and operation down and without burning

  3. Separation tests of heavy metals in samples of industrial wastes through flotation; Pruebas de separacion de metales pesados en muestras de residuos industriales mediante flotacion

    Energy Technology Data Exchange (ETDEWEB)

    Abrego L, J

    1995-12-15

    Samples of residual muds, taken at the exit of the filter-press of the water treatment plant of a galvanoplastics industry in Lerma, Estado de Mexico, its were prepared for its qualitative and quantitative analysis. Likewise, the residual waters of the cistern located at the end of the electrodeposition process, was subjected to qualitative chemical analysis for the neutron activation technique and to quantitative analysis by atomic absorption spectrometry. The samples were treated by a flotation process by means of the one which it was studied the heavy metals removal. The results show that the AP-845 collector is the one that better it fulfilled the objectives since, it solves the problem, unless by the copper that although their concentration in the residual waters drop a lot, it was not inside the standard. (Author)

  4. Evaluation of the capacity of heavy metal adsorption in exfoliated vermiculite; Avaliacao da capacidade de adsorcao de metal pesado em vermiculitas esfoliadas

    Energy Technology Data Exchange (ETDEWEB)

    Lima, J.F.; Silva, P.S.; Hanken, R.B.L. [Universidade Federal de Campina Grande (UAEMa/UFCG), PB (Brazil). Unidade Academica de Engenharia de Materiais; Raposo, C.M.O., E-mail: raposo@dmg.ufcg.edu.b [Universidade Federal de Campina Grande (UAMG/UFCG), Bodocongo, PB (Brazil). Unidade Academica de Mineracao e Geologia

    2009-07-01

    Many groups from modern society have seen with attention the issues of pollutants, generally present in nature, those same that have caused irreversible damages to the environment. The Vermiculite, a phyllosilicate, with t-o-t structure, have high interlamelar charge, has been studied as cationic exchanger, whose application when exfoliated, are increased. This work has the objective of evaluate the absorption capacity of chromium (III), in different concentrations, in high, slim and medium concentrations of exfoliated vermiculites. The results obtained from the characterization by spectroscopy in infrared and by diffraction of x-ray from prepared solids showed important variations in the quantity of adsorbed metal in order the size of the concentrated particles. (author)

  5. Study of casks shielded with heavy metal to transport highly radioactive substances; Estudo de embalados com blindagem em metal pesado para transporte de substancias altamente radioativas

    Energy Technology Data Exchange (ETDEWEB)

    Lucchesi, R.F.; Hara, D.H.S.; Martinez, L.G.; Mucsi, C.S.; Rossi, J.L., E-mail: rflguimaraes@ipen.br [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)

    2014-07-01

    Nowadays, Brazil relies on casks produced abroad for transportation in its territory of substances that are sources of high radioactivity, especially the Mo-99. The product of the radioactive decay of the Mo-99 is the Tc-99m, which is used in nuclear medicine for administration to humans in the form of injectable radioactive drugs for the image diagnosis of numerous pathologies. This paper aims to study the existing casks in order to propose materials for the construction of the core part as shielding against gamma radiation. To this purpose, the existing literature on the subject was studied, as well as evaluation of existing and available casks. The study was focused on the core of which is made of heavy metals, especially depleted uranium for shielding the emitted radiation. (author)

  6. Adsorção de metais pesados após calagem superficial em um Latossolo Vermelho sob sistema de plantio direto Heavy metals adsorption after surface lime in a Rhodic Hapludox under no-tillage system

    Directory of Open Access Journals (Sweden)

    Helio Antonio Wood Joris

    2012-03-01

    Full Text Available A influência da correção da acidez do solo sob sistema plantio direto (SPD na adsorção de metais pesados é pouco conhecida. Este trabalho teve o objetivo de avaliar a adsorção de cádmio (Cd, níquel (Ni, cobre (Cu e zinco (Zn em um Latossolo Vermelho distrófico textura argilosa sem e com calagem superficial (4,5 t ha-1 de calcário, manejado no SPD. O experimento foi instalado em 1998, no município de Ponta Grossa, PR. Após 10 anos, amostras de solo foram coletadas nas camadas 0-5; 5-10 e 10-20 cm e foram adicionadas doses crescentes de 0 a 180 mg L-1 de Cd e Ni e de 0 a 180 mg L-1 de Cu e Zn, em sistemas competitivos. Após equilíbrio, foi determinada a quantidade de metais adsorvidos. A calagem superficial no SPD aumentou o pH do solo em todas as camadas estudadas, resultando em incremento na adsorção de Cu, Zn, Cd e Ni, principalmente, na camada superficial. Ainda, a calagem alterou a dinâmica dos metais pesados no solo, sendo uma estratégia eficiente com potencial para minimizar problemas ambientais com Cu, Zn, Cd e Ni no SPD.There are few researches about control of soil acidy and adsorption of heavy metals in no-till system (NTS. The aim of this study was evaluate the cadmium (Cd, nickel (Ni, copper (Cu and zinc (Zn adsorption in a Rhodic Hapludox, clayey, without and with surface liming (4.5 t ha-1 under NTS. The experiment was established in Ponta Grossa, PR, in 1998. After 10 years, soil samples were collected to adsorption study. Doses of 0 to 180 mg L-1 of Cd and Ni, and of 0 to 180 mg L-1 of Cu and Zn were added, in competitive systems. After the equilibrium, the quantity of heavy metals was measured. Surface liming increased soil pH in all studied layers, resulting in improve of Cu, Zn, Cd and Ni adsorptions, mostly in the superficial layer. Moreover, surface liming changed dynamics of heavy metals in soil, being an efficient strategy to minimize environmental problems associate with Cd, Ni, Cu and Zn in NTS.

  7. Varied roles of Pb in transition-metal PbMO3perovskites (M= Ti, V, Cr, Mn, Fe, Ni, Ru).

    Science.gov (United States)

    Goodenough, John B; Zhou, Jianshi

    2015-06-01

    Different structural chemistries resulting from the Pb 2+ lone-pair electrons in the Pb M O 3 perovskites are reviewed. The Pb 2+ lone-pair electrons enhance the ferroelectric transition temperature in PbTiO 3 , stabilize vanadyl formation in PbVO 3 , and induce a disproportionation reaction of Cr IV in PbCrO 3 . A Pb 2+ + Ni IV = Pb 4+ + Ni II reaction in PbNiO 3 stabilizes the LiNbO 3 structure at ambient pressure, but an A -site Pb 4+ in an orthorhombic perovskite PbNiO 3 is stabilized at modest pressures at room temperature. In PbMnO 3 , a ferroelectric displacement due to the lone pair electron effect is minimized by the spin-spin exchange interaction and the strong octahedral site preference of the Mn IV/III cation. PbRuO 3 is converted under pressure from the defective pyrochlore to the orthorhombic ( Pbnm ) perovskite structure where Pb-Ru interactions via a common O -2p orbital stabilize at low temperature a metallic Imma phase at ambient pressure. Above P c [Formula: see text] a covalent Pb-Ru bond is formed by Pb 2+ + Ru IV = Pb 4+ + Ru II electron sharing.

  8. Bryophytes use like atmospheric indicators of heavy metals in the metropolitan area of the Toluca Valley; Uso de briofitas como indicadores atmosfericos de metales pesados en la zona metropolitana del Valle de Toluca

    Energy Technology Data Exchange (ETDEWEB)

    Poblano B, J.

    2013-07-01

    The objective of this work was to evaluate the concentration of Ti, V, Cr, Mn, Fe, Cu, Zn and Pb in species of frequent and abundant bryophytes in the Metropolitan Area of the Toluca Valley (MATV). The concentration of the studied metals was determined in two different seasons (cold-dry and warm-humid) in 11 sites of the MATV, 7 of them classified as urban areas, 2 as transition areas and 2 as protected natural areas. Only epiphyte organisms found to a superior height of 100 cm of the floor were considered and the species determination was realized in the Sciences Faculty of the Universidad Autonoma del Estado de Mexico, while the processing of the samples was carried out in the Instituto Nacional de Investigaciones Nucleares (ININ). The samples processing consisted on separating the bryophytes of the bark of the trees, later on each one of the samples was washed, milled and homogenized, at the end they were subjected to a digestion process accelerated by microwaves. The concentration of Ti, V, Cr, Mn, Fe, Cu, Zn and Pb in the bryophytes was determined applying the X-rays Fluorescence technique, using a spectrometer Tx-2000 Ital-Structures, with a detector type Si (Li), a tube of Mo (40 kV, 30 m A) with 17,4 keV like excitement energy. Each sample was analyzed six times with a counting time of 500 seconds. Additionally enrichment factors were obtained using reference soils considered as not impacted by anthropogenic activities. With the obtained results space and temporary differences were established through descriptive statistic, also the enrichment factor to infer the possible origin of the metals was calculated, as well as the sites that could represent a risk for the health. The species more frequent and abundant were F. ciliaris and L. angustata, presenting the following tendency in their metals concentration Fe>Ti>Mn>Zn>Pb>V ≅ Cu>Cr, being observed that the temporality is a factor that influences in the metals concentration and that in general F. ciliaris

  9. Avaliação dos níveis de metais pesados em efluente líquido percolado do aterro sanitário de Paranavaí, Estado do Paraná, Brasil - DOI: 10.4025/actascihealthsci.v31i1.1154 Assessment of heavy metal levels in percolated liquid from sanitary landfill in Paranavaí, Paraná State, Brazil - DOI: 10.4025/actascihealthsci.v31i1.1154

    Directory of Open Access Journals (Sweden)

    Cynthia Algayer da Silva

    2009-05-01

    Full Text Available O percolado pode conter diversas substâncias químicas com características tóxicas, dentre elas os metais pesados oriundos de vários materiais provenientes de indústrias, atividades agrícolas, laboratórios, hospitais, residências. A contaminação por metais apresenta amplo espectro de toxicidade que inclui efeitos neurotóxicos, hepatóxicos, nefrotóxicos, teratogênicos, carcinogênicos ou mutagênicos. O objetivo deste trabalho foi a avaliação dos níveis de Cd, Cr, Cu, Mn, Ni, Pb e Zn do percolado gerado no aterro sanitário de Paranavaí - PR. As amostras foram coletadas a partir de setembro de 2006 a julho de 2007, em quatro pontos distintos nas lagoas de tratamento. Para detecção dos metais utilizou-se o espectrofotômetro de absorção atômica com chama. Os resultados foram comparados com os limites máximos de concentração de metais em efluentes líquidos estabelecidos pela Resolução 397/2008 - Conama (BRASIL, 2008. Verificou-se que os níveis dos metais analisados, com exceção do Pb, estão dentro dos limites permissíveis pela legislação ambiental.Percolated liquid may contain several chemical substances with toxic characteristics, among them heavy metals from industrial sources, agricultural activities, laboratories, hospitals and residences. Metal contamination presents a wide array of toxicities, such as neurotoxic, hepatotoxic, nephrotoxic, teratogenic, carcinogenic or mutagenic effects. The objective of this work was to assess the levels of Cd, Cr, Cu, Mn, Ni, Pb, and Zn in percolated liquid produced at the sanitary landfill in Paranavaí. The samples were collected from September of 2006 to July of 2007, at four distinct places of the treatment lake. An atomic absorption spectrophotometer with a burner was used to detect the metals. The results were compared with the maximum allowed values for metal concentration present in Resolution 397/2008 – Conama (BRAZIL, 2008. It was verified that the level of

  10. Efectos en la calidad espermática del ciervo de la exposición a plomo y otros metales pesados: aplicación de modelos de exposición in vitro con espermatozoides.

    OpenAIRE

    Castellanos Expósito, Pilar

    2014-01-01

    El plomo (Pb) uno de los tóxicos ambientales e industriales más difundidos en el planeta debido al uso con muy variados fines que se ha hecho de este metal por diferentes civilizaciones a lo largo de la historia, lo que explica la intensa actividad de extracción minera de Pb que se ha tenido que asegurar cantidades suficientes de este metal. En lo que a nuestro país se refiere, la comarca minera del Valle de Alcudia y Sierra Madrona durante los siglos XX y XX se encontraba a la cabeza de pr...

  11. Study of the heavy metals speciation in the atmospheric suspended particles in Sevilla (Spain); Estudio de la especiacion de metales pesados en la materia particulada atmosferica de la ciudad de Sevilla

    Energy Technology Data Exchange (ETDEWEB)

    Ternero Rodriguez, M.; Sequeiros Madueno, L.; Jimenez Sanchez, C.; Barragan de la Rosa, J.; Bello Lopez, M.; Fernandez Espinosa, A.J.; Perez Bernal, J.L. [Facultad de Quimica, Universidad de Sevilla (Spain)

    1997-06-01

    This work develops analytical methods for the heavy metals speciation in the atmospheric suspended particles. In base to these methods, we study the atmospheric contamination of the city of Seville, determining the metals Al, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Cd and Pb. We also study the effects of metallic species in the alteration processes on rocks material, in base to the SO{sub 2}/SO{sub 4}{sup {minus}{minus}}. The project develops in two years: in the first, we develop the methods of chemistry speciation based on the extraction with different reagents and the methods of physical speciation based on the particle size distribution with cascade impactors. Also, we develop the methodology for the environmental simulation of alteration processes, in base to the heterogeneous catalysis, by metallic ions, of the SO{sub 2} on the surface of the stone. In the second year we apply the methods of speciation to the study of the contamination by heavy metals in the city of Seville. This part divides in two phases: a first of the preliminary study in the city in order to identify the different polluting focuses, and a secondary of study of the contamination produced by punctual sources, in the more polluted points of the city. On the other hand, the study of the alteration processes of rock materials has centred on materials employees in monuments of the city and on application of the catalyzers found in the particulate matter of the true environment of the materials. (Author)

  12. Heavy Metal Pb Content in the Seawater, Sediment and Green Mussel Tissue Perna Viridis

    OpenAIRE

    Haryono, M. Gandri; Mulyanto,; Kilawati, Yuni

    2017-01-01

    Accumulation of heavy metal Pb into the tissue can proceed through a food chain or environmental exposure. This study was to determine the content of heavy metals Pb in water, sediments and mussels (perna viridis). This research was conducted in March 2016, in the waters of Lekok Pasuruan at the three stations. TPI Station 1, Station 2 at the mouth of the Rejoso river and station 3 nearby PLTU 3. The water, sediments and green mussels (Perna viridis) samples were collected for Pb analysis usi...

  13. Cuantificación de metales pesados en Anadara tuberculosa(Mollusca:bivalvia del estero Huaylá de Puerto Bolívar, por espectrofotometría de absorción atómica

    Directory of Open Access Journals (Sweden)

    Collaguazo-Collaguazo, Yadira

    2017-09-01

    Full Text Available The presence of heavy metals in bivalve molluscs implies a serious problem for the consumers health of this type of food. Therefore, the objective of the present investigation was to determine the presence of heavy metals in Anadara tuberculosa, mollusc of commercial importance at Puerto Bolívar, Ecuador. Atomic absorption spectrophotometry was the method used to quantify the concentration of heavy metals. The concentration of six metals was determined: lead (Pb, arsenic (As, mercury (Hg, cadmium (Cd, chromium (Cr and cobalt (Co. The average values obtained, expressed in mg.kg-1 were: Pb (7.52 ± 0.46; As (1.55 ± 0.14; Hg (364.38 ± 91.39; Cd (1.68 ± 0.28; Cr (3,89 ± 1,82 and Co (2,71 ± 0,34 in A. tuberculosa The results show that Pb, As, Cd, and Hg exceed the maximum permissible limits, mercury exceeds by more than 100 times the limit value. The smaller size (3-4 cm studied mollusc, has the capacity to bioaccumulate higher concentration of Pb, Cd and Cr.

  14. Uso de biomassa seca de aguapé (Eichornia crassipes visando à remoção de metais pesados de soluções contaminadas - DOI: 10.4025/actascitechnol.v31i1.3166

    Directory of Open Access Journals (Sweden)

    Affonso Celso Gonçalves Júnior

    2009-04-01

    Full Text Available O presente trabalho avaliou a eficiência da biomassa seca de aguapé (Eichornia crassipes na remoção dos metais pesados cádmio (Cd, chumbo (Pb, cromo (Cr, cobre (Cu, zinco (Zn e níquel (Ni de soluções preparadas com estes metais. O delineamento utilizado foi inteiramente casualizado, com cinco tratamentos (soluções com diferentes concentrações dos metais pesados e quatro repetições. A biomassa seca permaneceu nas soluções dos tratamentos por um período de 48h, e nos intervalos de 1; 2; 3; 6; 12; 24; 36 e 48h após a instalação do experimento, coletaram-se alíquotas de cada tratamento, determinando-se a maior remoção de cada metal pesado pela biomassa seca do aguapé. Foi realizada digestão nitroperclórica na biomassa seca e determinação dos teores dos metais na biomassa e nas alíquotas por espectrometria de absorção atômica, modalidade chama. Para os metais Cd, Pb, Cr, Cu e Zn ocorreu remoção significativa pela massa seca do aguapé nos diferentes tratamentos, enquanto para o Ni não foi encontrada diferença significativa. Dessa forma, conclui-se que a biomassa seca produzida, a partir do aguapé Eichornia crassipes, é um excelente material para a remoção, tanto em pequena como em grande escala, de corpos hídricos contaminados com metais pesados.

  15. Content Heavy Metal Pb, Cd In Perna viridis And Sediments In Semarang Bay

    Science.gov (United States)

    Suprapto, D.; Suryanti, S.; Latifah, N.

    2018-02-01

    Waste disposal from human activities, generally contain heavy metals such as Pb and Cd which derived from industrial activities. The aims of the study were to know the concentration of Pb and Cd heavy metals contained in Perna viridis tissue, sediment and water at Semarang Bay. This study was conducted in May 2017 at Semarang Bay. - Samples were collected using purposive sampling method. The heavy metal content in the water and clam was observed using- APHA method and was analyzed using AAS (Atomic Absorption Spectrophotometer). The results showed that concentration of heavy metal of Pb in the water was 0.00-50.5mg/L and the Cd content was of 26.9-51.7 mg/L, whereas the concentration of Pb in the sediment is 445.5-2.053.0mg/L and Cd 963.3-2,150.0 mg/L. Pb content in soft tissue of Perna viridis - is 67.1-1.933.9 mg/L and the concentration of Cd was 203.5-5.787.3 mg/L. The analysis of Pb and Cd in seawater, sediment and soft tissue of Perna viridis according to Enviroment Ministerial decree (KepMenLH ) number 51 of 2004 and applied by NOAA 1999 does not exceed the quality standard, that meant that the Perna viridis has been contaminated by metal Pb it is controversial with the above sentence and Cd. It concluded that the metal content of Pb and Cd in Perna viridis tissue exceeds the quality standard, so it is not suitable to be consumed, especially in high quantity

  16. Biosorption of Zinc (Zn) and lead (Pb) by metal resistant bacterial isolate from mining tail

    Energy Technology Data Exchange (ETDEWEB)

    Bautista Hernandez, D. A.; Carranza Alvarado, M.; Fernandez Linares, L.; Ramirez Landy, I.

    2009-07-01

    The use of microbial biomass in the removal of metals in solution, mainly of low concentrations (100 mg L{sup -}1), present advantages in relation to the physicochemical methods. The resistant microorganisms are potential bio sorbents. The objective of the present study was the isolation, starting from mining tail, of strains with capacity of metal bio sorption (Zn and Pb). (Author)

  17. Biosorption of Zinc (Zn) and lead (Pb) by metal resistant bacterial isolate from mining tail

    International Nuclear Information System (INIS)

    Bautista Hernandez, D. A.; Carranza Alvarado, M.; Fernandez Linares, L.; Ramirez Landy, I.

    2009-01-01

    The use of microbial biomass in the removal of metals in solution, mainly of low concentrations (100 mg L - 1), present advantages in relation to the physicochemical methods. The resistant microorganisms are potential bio sorbents. The objective of the present study was the isolation, starting from mining tail, of strains with capacity of metal bio sorption (Zn and Pb). (Author)

  18. FONTES E TRANSPORTE DE METAIS PESADOS PARA ENSEADA DE JURUJUBA (BAIA DE GUANABARA RJ - BRASIL

    Directory of Open Access Journals (Sweden)

    José Antônio Baptista Neto

    2005-12-01

    Full Text Available As fontes de sedimentos e metais pesados para um estuário urbanizado são complexas e difusas. Esta pesquisa tem como objetivo acessar as principais fontes de metais pesados para a enseada de Jurujuba (RJ. Analisaram- se as concentrações dos elementos Cr, Cu, Ni, Pb, Zn e Fe, em amostras de solo, rios e escoamento superficial urbano, bem como sedimentos de marinas. Apesar de se poderem distinguir as fontes naturais das antrópicas de metais pesados para a Enseada de Jurujuba, é evidente que os processos de urbanização são os principais responsáveis pelas maiores concentrações de metais pesados para a enseada, através de rios e escoamento superficial urbano. No entanto, não se podem desprezar a deposição atmosférica e as atividades náuticas como importantes fontes de poluição.Palavras-chave: fontes de sedimentos, poluição de metais pesados, Enseada de Jurujuba, processo de urbanização.

  19. Lead isotopes and trace metal ratios of aerosols as tracers of Pb pollution sources in Kanpur, India

    Science.gov (United States)

    Sen, Indra; Bizimis, Michael; Tripathi, Sachchida; Paul, Debajyoti; Tyagi, Swati; Sengupta, Deep

    2015-04-01

    The anthropogenic flux of Pb in the Earth's surface is almost an order of magnitude higher than its corresponding natural flux [1]. Identifying the sources and pathways of anthropogenic Pb in environment is important because Pb toxicity is known to have adverse effects on human health. Pb pollution sources for America, Europe, and China are well documented. However, sources of atmospheric Pb are unknown in India, particularly after leaded gasoline was phased out in 2000. India has a developing economy with a rapidly emerging automobile and high temperature industry, and anthropogenic Pb emission is expected to rise in the next decade. In this study, we report on the Pb- isotope compositions and trace metal ratios of airborne particulates collected in Kanpur, an industrial city in northern India. The Pb concentration in the airborne particulate matter varies between 14-216 ng/m3, while the other heavy metals vary by factor of 10 or less, e.g. Cd=0.3-3 ng/m3, As=0.4-3.5 ng/m3, Zn=36-161 ng/m3, and Cu=3-22 ng/m3. The 206Pb/207Pb, 208Pb/206Pb, and 208Pb/207Pb vary between 1.112 - 1.129, 2.123-2.141, and 2.409-2.424 respectively, and are highly correlated with each other (R2>0.9). Pb isotopes and trace metal data reveals that coal combustion is the major source of anthropogenic Pb in the atmosphere, with limited contribution from mining and smelting processes. We further conclude that combination of Pb isotope ratios and V/Pb ratios are powerful tracers for Pb source apportionment studies, which is otherwise difficult to differentiate based only on Pb systematics [1] Sen and Peucker-Ehrenbrink (2012), Environ. Sci. Technol.(46), 8601-8609

  20. Assessment of heavy metal mobility in mine tailings in the province of Huelva; Evaluacion de la movilidad de metales pesados en residuos mineros de flotacion de mineria metalica en la provincia de Huelva

    Energy Technology Data Exchange (ETDEWEB)

    Arranz Gonzalez, J. C.; Cala Rivero, V.

    2011-07-01

    Metallurgic mine wastes often contain high concentrations of potentially toxic elements, the mobility of which may pose an environmental hazard for water and surrounding ecosystems. We have examined the mobility of Ag, As, Cu, Pb and Zn from composite surface samples (0-20 cm) of different pyritic tailings impoundments in the province of Huelva (Spain). These samples were also subject to physical chemical and mineralogical (XRD) characterization. The total metal content of the tailings ranged between 1.89-11.2 ppm for Ag, 72-610 ppm for As, 245-1194 ppm for Cu, 220-11933 for Pb and 41-706 for Zn, all proving to be highly acidic. The mobility of these elements was assessed by using a seven-step sequential extraction procedure and applying the toxicity characteristic leaching procedure (TCLP). We investigated the applicability of TCLP to the tailings by comparing the results with those of the first steps of the sequential extraction procedure. It was found that the pH values remained buffered (close to 4.97) upon adding the TCLP extraction reagent and that the pH values differed significantly from those of the aqueous extracts. This could result in an underestimation of mobile forms compared with those dissolved in water. We may also conclude that due to the presence of specific minerals or to the preference of some elements for acetate ions the results of any assessment of metal mobility in pyritic tailings using the TCLP test may be questionable. (Author) 42 refs.

  1. Electrochemical attributes and availability of nutrients, toxic elements, and heavy metals in tropical soils Atributos eletroquímicos e disponibilidade de nutrientes, elementos tóxicos e metais pesados em solos tropicais

    Directory of Open Access Journals (Sweden)

    Mauricio Paulo Ferreira Fontes

    2006-12-01

    Full Text Available Electrochemical properties of soils are very important for the understanding of the physico-chemical phenomena which affect soil fertility and the availability of nutrients for plants. This review highlights the electrochemical properties of tropical soils, the behavior and the availability of nutrients, toxic elements and heavy metals in the soil, especially for soils with predominant variable charge minerals. Availability of the elements is related to ionic exchange, solution speciation, and electrostatic and specific adsorptive soil properties. Empirical and surface complexation models are briefly described, and some results of their application in tropical soils are presented. A better understanding of the role of the double diffuse layer of charges and CEC on nutrient cation availability for highly weathered soils is required, as well as a solid comprehension of surface complexation models, in order to improve the knowledge regarding the behavior of anions in soils. More studies have to be conducted to generate results that enable the use of chemical speciation concepts and calculation of several constants used in surface complexation models, especially for highly weathered soils from the humid tropics. There has to be a continuing development and use of computer softwares that have already incorporated the concepts of chemical speciation and adsorption models in the study of nutrients, toxic elements and heavy metal availability in the soil-plant system.As propriedades eletroquímicas dos solos tropicais são muito importantes para entendimento dos fenômenos físico-químicos que afetam a fertilidade do solo e a disponibilidade dos nutrientes das plantas. Essa revisão destaca os atributos eletroquímicos de solos e o comportamento e a disponibilidade de nutrientes, elementos tóxicos e metais pesados no solo, especialmente aqueles com predominância de minerais com cargas variáveis. A disponibilidade dos elementos é relacionada com a

  2. Metais pesados, agrotóxicos e combustíveis: efeito na população de colêmbolos no solo Heavy metal, pesticides and fuels: effect in the population of collembola in the soil

    Directory of Open Access Journals (Sweden)

    Zaida Inês Antoniolli

    2013-06-01

    Full Text Available O objetivo deste trabalho foi avaliar o desenvolvimento de colêmbolos no solo com diferentes níveis de metais pesados, combustíveis e agrotóxicos em condição de laboratório. Os tratamentos foram: Cádmio (1, 10 e 100mg kg-1 de solo; Cobre (50, 500 e 5000mg kg-1 de solo; Zinco (100, 1000 e 10000mg kg-1 de solo; fungicida epoxiconazol + piraclostrobina (1 e 2L ha-1; fungicida epoxiconazol (0,75 e 1,5L ha-1; herbicida glifosato (2 e 4L ha-1; óleo lubrificante queimado (5, 50 e 100mL kg-1 solo e óleo diesel (5, 50 e 100mL kg-1 solo e controle. Na dose de 1mg kg-1 de Cd no solo, houve grande aumento na população de colêmbolos e o pH do solo diminuiu à medida que aumentaram as doses de Cd, Zn e Cu no solo. Na presença de combustíveis, os colêmbolos apresentaram incapacidade de reprodução, independente da dose aplicada no solo. O número de colêmbolos apresentou incremento com o aumento da dosagem de glifosato e epoxiconazol. Os metais pesados Cu e Zn têm ação negativa sobre a população de colêmbolos e somente o Cd (1mg kg-1 solo proporciona aumento na população de colêmbolos no solo. A presença de óleo lubrificante queimado e óleo diesel no solo inibem o desenvolvimento dos colêmbolos no solo. Os agrotóxicos glifosato, epoxiconazol e epoxiconazol + piraclostrobina não influenciam negativamente sobre a população de colêmbolos no solo.The aim of this research was to evaluate the collembola development in soils with different levels of heavy metals, fuels and pesticides, in laboratory conditions. Treatments were: Cadmium - 1, 10 and 100mg kg-1 soil; Copper - 50, 500 and 5000mg kg-1 soil; Zinc - 100, 1000 and 10000 mg kg-1 soil; fungicide epoxiconazol + piraclostrobina - 1 and 2L ha-1; fungicide epoxiconazol - 0,75 and 1,5L ha-1; herbicide glyphosate - 2 and 4L ha-1; burned lubricating oil - 5, 50 and 100mL kg-1 soil and diesel oil - 5, 50 and 100mL kg-1 soil and control. In the 1mg kg-1 dose of Cd there was a great

  3. Coliformes fecais em águas de esgoto: I. Resistência a antibióticos, metais pesados e colicinogenia Fecal coliforms in sewage treatment: I. Antibiotic and heavy metal resistance and colicinogeny

    Directory of Open Access Journals (Sweden)

    José Cavalcante de Albuquerque Ribeiro Dias

    1987-09-01

    Full Text Available Análise bacteriológica de ordem qualitativa foi desenvolvida em duas estações de tratamento de esgoto da cidade do Rio de Janeiro no período de 1984 a 1985. A pesquisa considerou o isolamento e a identificação de 540 culturas de Escherichia coli, advindas de afluentes e efluentes. Estudou-se a resistência a oito antimicrobianos (sulfadiazina, estreptomicina, tetraciclina, cloranfenicol, canamicina, ampicilina, ácido nalidíxico e gentamicina e a três metais pesados (sulfato de cobre, cloreto de mercúrio e sulfato de zinco, além da colicinogenia. Foi possivel a detecção de percentuais até 95 para culturas isoladas dos efluentes com marcadores genéticos, contrapondo-se com taxas ao redor de 70% para aquelas provindas dos afluentes.Qualitative bacteriological analysis was carried out in two sewage treatment plants in the city of Rio de Janeiro during the period 1984-1985. Specific points of the plants were selected for the collection of affluent and effluent samples. The study involved the isolation and the identification of 540 cultures of Escherichia coli that were analyzed for their resistance to eight antibiotics (sulfadiazine, streptomycin, tetracycline, chloramphenicol, kanamycin, ampicillin, nalidixic acid and gentamycin, and three heavy metals (copper sulphate, mercuric chloride and zinc sulphate as well as colicinogeny. About 95% of the isolated cultures from the effluents had genetic markers while the samples originated from the affluents showed 70%.

  4. Metal (Pb, Cd, and Zn) Binding to Diverse Organic Matter Samples and Implications for Speciation Modeling.

    Science.gov (United States)

    Chen, Weibin; Guéguen, Céline; Smith, D Scott; Galceran, Josep; Puy, Jaume; Companys, Encarnació

    2018-04-03

    This study evaluated the influence of dissolved organic matter (DOM) properties on the speciation of Pb, Zn, and Cd. A total of six DOM samples were categorized into autochthonous and allochthonous sources based on their absorbance and fluorescence properties. The concentration of free metal ions ( C M 2+ ) measured by titration using the absence of gradients and Nernstian equilibrium stripping (AGNES) method was compared with that predicted by the Windermere humic aqueous model (WHAM). At the same binding condition (pH, dissolved organic carbon, ionic strength, and total metal concentration) the allochthonous DOM showed a higher level of Pb binding than the autochthonous DOM (84- to 504-fold C Pb 2+ variation). This dependency, however, was less pronounced for Zn (12- to 74-fold C Zn 2+ variation) and least for Cd (2- to 14-fold C Cd 2+ variation). The WHAM performance was affected by source variation through the active DOM fraction ( F). The commonly used F = 1.3 provided reliable C Pb 2+ for allochthonous DOMs and acceptable C Cd 2+ for all DOM, but it significantly under-predicted C Pb 2+ and C Zn 2+ for autochthonous DOM. Adjusting F improved C M 2+ predictions, but the optimum F values were metal-specific (e.g., 0.03-1.9 for Pb), as shown by linear correlations with specific optical indexes. The results indicate a potential to improve WHAM by incorporating rapid measurement of DOM optical properties for site-specific F.

  5. Availability of heavy metals (Cd, Pb, And Cr) in agriculture from commercial fertilizers.

    Science.gov (United States)

    Nacke, H; Gonçalves, A C; Schwantes, D; Nava, I A; Strey, L; Coelho, G F

    2013-05-01

    The purpose of this study was to investigate the availability of the heavy metals cadmium (Cd), lead (Pb), and chromium (Cr) to soil and maize plants fertilized with different sources and doses of zinc (Zn) in a Rhodic Eutrudox soil. For that purpose, concentrations of Cd, Pb, and Cr were evaluated in leaf tissue and grains of maize plants and in 0-20 and 20-40 cm soil layers after fertilization with four doses of Zn from eight different sources of fertilizer. There was no accumulation of Cd, Pb, and Cr in maize grain and Cd and Cr in leaf tissue of the plants; nevertheless, there was accumulation of Pb in leaf tissue, showing its availability throughout different sources of Zn and consequent uptake by plants. Regarding the soil, it was observed that fertilizer from the different sources made Cd, Pb, and Cr available at increasing amounts proportional to increased Zn doses. Under experimental conditions, fertilization with Zn increased concentrations of heavy metals Cd, Pb and Cr in soil, further highlighting the importance of conducting more studies related to the application of mineral fertilizers for micronutrient supply and the availability of heavy metals.

  6. Distribution And Metal Adsorption of Lead (Pb In Estuary Banyuasin, South Sumatra (Distribusi dan Adsorpsi Logam Timbal (Pb di Muara Sungai Banyuasin, Sumatera Selatan

    Directory of Open Access Journals (Sweden)

    Anna Ida Sunaryo Purwiyanto

    2015-09-01

    Full Text Available Muara Sungai Banyuasin merupakan wilayah penting bagi masyarakat Sumatera Selatan. Tingginya aktivitas yang terjadi, mengakibatkan muara ini menjadi rentan pencemaran, terutama logam Pb, baik pada biota maupun perairan. Penelitian ini bertujuan untuk menganalisis kandungan logam berat Pb dan memprediksi terjadinya adsorpsi logam Pb pada kolom perairan dan sedimen seluruh sisi dan bagian Muara Sungai Banyuasin menggunakan pendekatan pemodelan. Penelitian ini menggunakan 3 stasiun yang mewakili 3 daerah muara, yaitu bagian luar muara, tengah muara, dan bagian dalam muara, dimana pada tiap stasiun diambil 3 sampel air (permukaan air, kolom air, dan dasar perairan dan 1 sampel sedimen. Logam Pb pada sampel air dan sedimen dianalisis menggunakan AAS. Data divisualisasikan dalam bentuk peta distribusi persebaran dengan bantuan software ODV, sedangkan adsorpsi logam Pb pada perairan dimodelkan dengan menggunakan model partisi, Freundlich dan Langmuir. Hasil penelitian menunjukkan bahwa logam Pb di Muara Sungai Banyuasin merupakan akumulasi dari aktivitas manusia pada hulu sungai dengan konsentrasi yang telah melebihi ambang batas yang ditetapkan Menteri Lingkungan Hidup. Konsentrasi logam Pb lebih tinggi pada bagian sedimen sehingga mengindikasikan bahwa memang terjadi adsorpsi logam Pb oleh sedimen. Hasil pemodelan menunjukkan bahwa proses adsorpsi logam Pb tersebut berlangsung sesuai dengan asumsi Langmuir dengan dominasi fisiosorpsi. Kata kunci: distribusi, logam Pb, adsorpsi, pemodelan, Muara Sungai Banyuasin   Banyuasin River estuary is an important area for the people of South Sumatra. The high activity that occurs in this estuary resulted susceptible of pollution, especially Pb, both on water and aquatic organism. This research aims to analyze the content of heavy metals Pb and predict the occurrence of adsorption of Pb in the water column and sediments around the sides and the estuary Banyuasin using modeling approaches. This study used three

  7. Efectos genotóxicos asociados a metales pesados en una población humana de la región de La Mojana, Colombia, 2013

    Directory of Open Access Journals (Sweden)

    Clelia Rosa Calao

    2015-08-01

    Conclusión. Estos resultados sugieren que el daño genético registrado en pobladores de la región de La Mojana, Colombia, puede estar asociado a la presencia de los metales estudiados en las muestras de sangre.

  8. Preparation of glasses and glass ceramics of heavy metal oxides containing silver: optical, structural and electrochemical properties; Preparacao de vidros e vitroceramicas de oxidos de metais pesados contendo prata: propriedades opticas, estruturais e eletroquimicas

    Energy Technology Data Exchange (ETDEWEB)

    Bregadiolli, Bruna A. [Departamento de Fisica, Faculdade de Ciencias, Universidade Estadual Paulista, Bauru - SP (Brazil); Souza, Ernesto R.; Sigoli, Fernando A. [Instituto de Quimica, Universidade Estadual de Campinas, Campinas - SP (Brazil); Caiut, Jose M.A. [Departamento de Quimica, Faculdade de Filosofia Ciencias e Letras de Ribeirao Preto, Universidade de Sao Paulo, Ribeirao Preto - SP (Brazil); Alencar, Monica A.S.; Benedetti, Assis V. [Instituto de Quimica, Universidade Estadual Paulista, Araraquara - SP (Brazil); Nalin, Marcelo, E-mail: mnalin@ufscar.br [Departamento de Quimica, Universidade Federal de Sao Carlos, SP, (Brazil)

    2012-07-01

    Silver containing heavy metal oxide glasses and glass ceramics of the system WO{sub 3}-SbPO{sub 4} -PbO-AgCl with different AgCl contents have been prepared and their thermal, structural and optical properties characterized. Glass ceramics containing metallic silver nanoparticles have been prepared by annealing glass samples at temperatures above the glass transition and analyzed by transmission electron microscopy and energy dispersive X-ray microanalysis. The presence of the metallic clusters has been also confirmed by the observation of a surface plasmon resonance band in the visible range. Cyclic voltammetric measurements indicated the presence of metallic silver into the glasses, even before to perform the thermal treatment. (author)

  9. Niveles y distribución de metales pesados en el agua de la zona de playa de Riohacha, La Guajira, Colombia

    Directory of Open Access Journals (Sweden)

    Carlos Doria Argumedo

    2015-03-01

    Full Text Available La zona de playa de Riohacha, La Guajira, Colombia, constituye un ecosistema muy rico, diverso y productivo, dotado de gran capacidad para proveer bienes y servicios que sostienen actividades como pesca, turismo y navegacion; sin embargo, experimenta problematicas ambientales producto de la dinamica de la ciudad, relacionadas con la infiltración de aguas residuales, acumulacion de residuos solidos organicos y descargue de sedimentos del rio Rancheria. En la metodologia de esta investigación se tomaron muestras de agua de mar en cuatro puntos de un sector de aproximadamente 2.5 km de playa, durante ocho meses en el ano 2013, en epocas de lluvia y sequia. Los metalesanalizados fueron Cobalto, Cobre, Zinc, Aluminio, Manganeso, Niquel y Hierro. Las concentraciones de los metales Ni y Zn, considerados muy toxicos, se encontraron por encima de los niveles segun la normativa nacional y algunas establecidas a nivel internacional, para efectos agudos en aguas marinas y estuarinas destinadas a la preservacion de fauna y flora; las concentraciones de Cu y Zn, se encuentran por debajo de los limites establecidos por la EEA y la EPA. La correlacion significativa existente entre las concentraciones de los metales Fe, Mn, Zn, Co con los nutrientes nitrato y fosfato, indica posible acumulacion de ellos en el sedimento e incluso bioacumulacion en la fauna asociada a esta zona. La presencia y concentraciones de los metales son producto, principalmente, de la intervención humana en las labores de mineria y en el ciclo biogeoquimico de los metales.

  10. Heavy metals extractability in a soil amended with sewage sludge Extractabilidade de metais pesados em um solo tratado com lodo de esgoto

    Directory of Open Access Journals (Sweden)

    Giuliano Marchi

    2009-10-01

    Full Text Available Few investigations have been carried out about the comparison of desorption rate and amount of heavy metals extracted successively by organic acid mixtures mimicking the rhizosphere and routine extractants in sewage sludge-amended soils. Extractions of Zn, Cd, Ni, Cr, and Cu were performed in samples of a sewage sludge-amended soil using seven extractants: four organic acid mixtures and three routine extractants (DTPA, Mehlich-I, and ammonium acetate. Results from single pass extractions, in which the extractable metal contents were determined by simply extracting the soil a single time, as well as from 15 successive extractions, in which the solid residues of the first extraction was successively extracted 14 additional times, of heavy metals were analyzed. The extractability of heavy metals in a single pass extraction was, in general, as follows: Mehlich-I > DTPA > organic acids > NH4OAc. The highest rates of extraction followed the general order: DTPA > Mehlich-I > organic acids > NH4OAc. While Mehlich-I presented the highest extractability of heavy metals among studied extractants, DTPA showed a high extractability of Zn, Cd, Ni, and Cu in a single extraction as well as the highest rates of extraction among the studied extractants. The transfer of heavy metals from soil to organic acid solutions is slower than to DTPA and Mehlich-I extractants.Poucos trabalhos têm sido realizados sobre a comparação da taxa de dessorção e da quantidade de metais extraídos sucessivamente por misturas de ácidos orgânicos que imitam a composição da rizosfera e por extratores usados na rotina em amostras de solo tratado com lodo de esgoto. Extrações de Zn, Cd, Ni, Cr e Cu foram realizadas em amostras de um solo de carga variável tratado com lodo de esgoto usando-se sete extratores: quatro misturas com ácidos orgânicos e três extratores usados na rotina (DTPA, Mehlich-I e acetato de amônio. Os resultados para uma única extração, em que o conte

  11. Determinación de la exposición a metales pesados en la industria Metalmecánica en Costa Rica.

    OpenAIRE

    Medina-Escobar, María de Lourdes; Mata-Montero, Carlos

    2012-01-01

    Informe Final de Proyecto de Investigación. El número de empresas dedicadas a labores que involucran corte, lijado, pulido y soldadura de metales en Costa Rica ha venido creciendo en los últimos años y por tanto el número de trabajadores expuestos a los humos y material particulado proveniente de estas operaciones. Los efectos a la salud asociados a este tipo de trabajo son muy variados y abarcan desde irritación de ojos hasta enfermedades respiratorias incluyendo cáncer de pulmón. Estu...

  12. Ecological effects of some heavy metals (Cd, Pb, Hg, Cr) pollution of ...

    African Journals Online (AJOL)

    STORAGESEVER

    2008-06-17

    Jun 17, 2008 ... reaching the lakes through their catchments area and the atmosphere. Typical results of human activities proved to be elevated levels of heavy metals present in fresh water, and among these microelements lead (Pb), cadmium. (Cd), mercury (Hg), chrome (Cr) are most specific. (Farkas et al., 2001).

  13. Effect of metal ion concentration on the biosorption of Pb2+ and ...

    African Journals Online (AJOL)

    The influence of initial metal ion concentration of the batch sorption of Pb2+ and Cd2+ onto a low-cost biosorbent was investigated. The experimental results were analysed in terms of Langmuir and Freundlich isotherms. According to the evaluation using Langmuir equation, the monolayer sorption capacity obtained were ...

  14. Kinetic modeling of metal ion transport for desorption of Pb(II) ion ...

    African Journals Online (AJOL)

    The kinetics of desorption of lead (II) ion from metal loaded adsorbent of mercaptoacetic acid modified and unmodified oil palm (Elaeis guineensis) fruit fiber was studied using different solutions, at different contact times. At the end of 25 minutes, 79.19%, 75.99%, 57.14%, 50.56% and 32.72% of Pb2+ were desorbed using ...

  15. Evaluation of toxic trace metals Cd and Pb in Arabian Sea waters

    Digital Repository Service at National Institute of Oceanography (India)

    Sanzgiri, S.; Mesquita, A.; Kureishy, T.W.; SenGupta, R.

    An attempt has been made to present a picture of the distribution of toxic trace elements Cd and Pb in the Northern Arabian Sea by applying an improved analytical technique for the detection of dissolved forms of the metals at nanogram levels...

  16. The Enrichment and Transfer of Heavy Metals for Two Ferns in Pb-Zn Tailing

    Directory of Open Access Journals (Sweden)

    Mai Jiajie

    2017-01-01

    Full Text Available The enrichment and transfer of 8 heavy metals of Equisetum ramosissimum and Pteris vittata growing naturally close to edge of the sewage pool in Bencun Pb-Zn Tailing, Eastern Guangdong were investigated. The results indicated that the pollution of Cd, Pb, Hg, Zn was very severe in this tailing, followed by Cu and Mn. The potential ecological risk of heavy metals was assessed to be very strong based on soil background values of Guangdong Province and at high risk according to criteria of the second grade State Soil Environmental Quality Standard, and Cd, Hg, Pb were the main factors leading to potential ecological risk. The content of 8 heavy metals in the two ferns did not reach critical content of hyperaccumulator, so neither of them was typical hyperaccumulator, but both had a certain tolerance to these heavy metal pollution. Underground parts of Pteris vittata had an enrichment coefficient above 1 and that of Equisetum ramosissimum had a value near 1, therefore the two ferns could be utilized as potential enrichment plants. The two ferns have strong adaptability to the tailing habitat and can be used as pioneers in ecological restoration of Pb-Zn tailings.

  17. Sequential chemical extraction of heavy metals in a study of the chemical alteration of mine tailings at Ticapampa (Huaraz, Peru); Extraccion quimica secuencial de metales pesados en el estudio de alteracion quimica de relaves de mina en Ticapampa (Huaraz, Peru)

    Energy Technology Data Exchange (ETDEWEB)

    Jara Facundo, M. A.

    2011-07-01

    The upper reaches of the Rio Santa (Huaraz, Peru) are highly affected by the mining activities of generally small and very small mining companies located in two specific areas, Cordillera Blanca, and Cordillera Negra, with the largest mining claims located in the districts of Recuay and Ticapampa. To assess the mobility and bioavailability of heavy metals in the abandoned tailings pond belonging to the Alianza mining company in the district of Ticapampa, and to identify the fractions to which they are associated we applied a sequential chemical extraction. The results were compared with studies into their mineralogical characterization, a quantitative chemical analysis and a determination of potential acidity and potential neutralization by the ABA (acid-base accounting) method applied to samples of tailings. The sequential extraction procedure confirmed the mode of general alteration observed in the area through mineralogical studies: a relatively easy mobility of Pb, and Cd, and considerable immobility with regard to Ag, Cr and Co, as well as an intermediate mobility of Cu, Zn, and As. Significant cadmium and lead contents found in the most mobile fractions of the tailings may represent an environmental threat, bearing in mind the toxic nature of these elements. Despite the low mobility of arsenic, the total quantities of this element are so high that the waters of the Rio Santa are being affected. (Author) 22 refs.

  18. Coexistence of polar distortion and metallicity in PbTi1 -xNbxO3

    Science.gov (United States)

    Gu, Jun-xing; Jin, Kui-juan; Ma, Chao; Zhang, Qing-hua; Gu, Lin; Ge, Chen; Wang, Jie-su; Wang, Can; Guo, Hai-zhong; Yang, Guo-zhen

    2017-10-01

    Ferroelectricity has been believed unable to coexist with metallicity since the free carriers can screen the internal Coulomb interactions of dipoles. Very recently, one kind of material called ferroelectric metal was reexamined. Here, we report the coexistence of metallicity and polar distortion in a candidate for ferroelectric metal PbT i1 -xN bxO3 via doping engineering. The ferroelectriclike polar distortion in all the doped PbT i1 -xN bxO3 , with x ranging from 0.04 to 0.12, was observed by the piezoresponse force microscopy and the scanning transmission electron microscopy measurements. PbT i1 -xN bxO3 films become more conductive with more doping density, and a metallic behavior emerges when x reaches 0.12. Our first-principles calculations further revealed that the doped Nb ions in the films can only provide free electrons, but are not able to damage the dipoles in unit cells even with the heaviest doping density of 0.12. We believe that these results confirm a feasibility of realizing the coexistence of metallicity and polar distortion for other ferroelectrics in a common way, and motivate the synthesis of some new materials with artificially designed properties even incompatible in nature.

  19. Adsorção de metais pesados em serragem de madeira tratada com ácido cítrico Heavy metals sorption on treated wood sawdust

    Directory of Open Access Journals (Sweden)

    Rafael Falco Rodrigues

    2006-03-01

    Full Text Available Neste estudo, avaliou-se a capacidade da madeira Paraju (Manilkara longifolia, modificada quimicamente, para a retenção de íons metálicos. A modificação refere-se a um tratamento com ácido cítrico que leva à reação de grupos carboxilato com a celulose da biomassa. A introdução desses grupos foi observada através de espectrometria de infravermelho. Foram realizados ensaios em sistemas de batelada contendo cádmio e cobre. Os ensaios foram conduzidos em condições de equilíbrio, ajustados segundo o modelo de Langmuir. Obteve-se um carregamento máximo nos sistemas contendo apenas um metal, de 0,56 mmol-Cd/g e 0,94 mmol-Cu/g. O carregamento de cádmio reduziu-se de 0,56 mmol-Cd/g para 0,21 mmol-Cd/g, à medida que a concentração de cobre cresceu no sistema mostrando que existe uma competição entre os metais pelos grupos de troca.In the present work, the exchange capacity of Manilkara longifolia sawdust, chemically modified, was studied. The modification was carried out by a chemical treatment with citric acid, which introduced carboxilate groups in the material surface. The introduction of these groups was confirmed by infrared spectroscopy. Cadmium and copper sorption was studied batchwise. Isotherms were drawn and adjusted to the Langmuir model. Maximum loadings of 0.56 mmolCd/g and 0.94 mmolCu/g were achieved in single metal adsorption. Cadmium uptake was reduced from 0.56 mmolCd/g to 0.21 mmolCd/g as the copper concentration increased in the reaction system. These results show that there is a competition between the two metals for the exchange sites.

  20. Heavy metals availability in lake sediments using chemical extraction and X-ray fluorescence techniques; Disponibilidade de metais pesados em sedimentos de lagos utilizando tecnicas de extracao quimica e de fluorescencia de raios-X

    Energy Technology Data Exchange (ETDEWEB)

    Brienza, Sandra Maria Boscolo [Universidade Metodista de Piracicaba (UNIMEP), Santa Barbara d' Oeste, SP (Brazil). Faculdade de Engenharia e Ciencias Quimicas; Vives, Ana Elisa Sirito de [Universidade Metodista de Piracicaba (UNIMEP), Santa Barbara d' Oeste, SP (Brazil). Faculdade de Ciencias Matematicas e da Natureza; Nascimento Filho, Virgilio Franco do [Centro de Energia Nuclear na Agricultura (CENA), Piracicaba, SP (Brazil). Lab. de Instrumentacao Nuclear]|[Sao Paulo Univ., Piracicaba, SP (Brazil). Escola Superior de Agricultura Luiz de Queiroz. Dept. de Ciencias Exatas; Simabuco, Silvana Moreira [Universidade Estadual de Campinas, SP (Brazil). Faculdade de Engenharia Civil

    2002-07-01

    Aiming to evaluate contamination degree by heavy metals in bottom sediments at the lakes at the Santa Gertrudes region, Sao Paulo State, Brazil, where ceramic industries of enameled pavement are installed, bottom sediment samples were collected in two lakes, in different seasons (rainy season and dry season). To determine biological availability metal concentrations (no-residual fraction), and the residual fraction (geological matrix), acid extraction procedure were implemented. To enhance analytical sensibility, the obtained extracts were preconcentrated by complexation with ammonium pyrrolidine dithiocarbamate. To determine the complexed metals concentration, were used the analytical technique energy dispersive X-ray fluorescence analysis (EDXRF). To produces characteristic X-rays it was used an X-ray tube, and to detect the characteristic X-rays, a Si(Li) detector. The X-ray net intensities were obtained using the AXIL software. In the analyzed samples were possible to determine the elements V, Cr, Mn, Fe, Co, Ni, Cu, Zn and Pb. (author)

  1. Immobilization of heavy metals arising sludge galvanic, in glass ceramic material; Imobilizacao de metais pesados oriundos de lodo galvanico em material vitreo

    Energy Technology Data Exchange (ETDEWEB)

    Felisberto, R., E-mail: regina.felisberto@poa.ifrs.edu.br [Instituto Federal do Rio Grande do Sul (IFRS), Porto Alegre, RS (Brazil); Santos, M.C.; Basegio, T.; Bergmann, C.P. [Universidade Federal do Rio Grande do Sul (PPGEM/UFRGS), Porto Alegre, RS (Brazil)

    2016-07-01

    The use of galvanic sludge in the glass-ceramic formulation for immobilizing environmentally harmful materials is consolidated in more developed countries as raw material in the formulation of new materials. In this work, we have used galvanic sludge provided by a metallurgical company located in Vale dos Sinos, RS. The sludge was dried at 105°C and mixed with soda-lime glass in proportions of 1, 5, 10 and 20%, relative to the glass mass. Its composition was determined by FRX, and evaluated for leaching (NBR 10005) and solubilization (NBR 10006). The specimens (CPs) were burned at temperatures 750, 800 and 850°C, also submitted to the tests. The sludge, Class I - dangerous, presented Se content greater than provisions of NBR 10004. It was possible to immobilize the heavy metals at a temperature of 850°C for specimens of the F1 formulation, having been thus classified as Class II B Inert Residue. (author)

  2. Preparation and characterization of bentonite clays mixture destined to the removal of heavy metals; Preparacao e caracterizacao da mistura de argilas bentoniticas destinadas a remocao de metais pesados

    Energy Technology Data Exchange (ETDEWEB)

    Almeida Neto, A.F. de; Silva, M.G.C. da, E-mail: ambrosio@feq.unicamp.b [Universidade Estadual de Campinas (UNICAMP), SP (Brazil). Fac. de Engenharia Quimica. Dept. de Termofluidodinamica

    2009-07-01

    In this work a mixture was prepared with 50% wt. of the Bofe and Verde-lodo clays. The characterization methods used they were: thermal analyses (TG and DTG), X-ray diffraction, fisissorption of N{sub 2}, scanning electron microscopy and X-ray energy dispersive spectroscopy. The rehearsals of adsorption we accomplished in system of finite bath using as adsorbent the mixture loamy in natura or it mixes calcined. Starting from TG and DTG a thermal treatment was accomplished to 500 deg C of the loamy mixture. Through the results of the copper adsorption, it was verified that mixes loamy it provokes chemical precipitation of the copper while the calcined sample presents amount metal adsorbed around 7.31 mg of copper/g of adsorbent. The value of removal percentage obtained by the calcined sample it was of 63.02%. (author)

  3. Impacto ambiental por metales pesados en suelos y plantas del entorno de un depósito de chatarra procedente de automóviles de desguace

    Directory of Open Access Journals (Sweden)

    Chicharro, A.

    1998-05-01

    Full Text Available The contaminant impact of cadmium, chromium, copper, nickel, lead and zinc on soils and vegetation in the surroundings of a scrapyard of discarded vehicles, taken at several distances of the contaminant source, is evaluated and compared with control samples free of contamination. The total metal contents of these elements in the soils and vegetation samples are determined by ICP-AES and their presence in soils is detected by particles analysis with SEM-EDXRA. The contents of the affected soils are remarkably higher than the ones of a control sample for the all elements and gradually decrease from the contaminant source. These contents in plants are also relevantly higher than the values of the control sample, and are especially high for the aereal parts. This remarkable contamination, moreover the great retention capacity of these soils, due to their edaphical characteristics, and the presence of a great quantity of not-mineral particles, may indicate that the probable access path of the metal contaminants to the plants could be the atmospherical dispersion of the particles generated by the scrapyard activities (burning and transformation of the vehicles scrap.

    Se evalúa el impacto contaminante de cadmio, cromo, cobre, níquel, plomo y cinc en suelos y vegetación del entorno de un depósito de chatarra de automóviles, a diferentes distancias del mismo, tomando como referencia muestras control no contaminadas. Los contenidos totales de dichos elementos en muestras de suelos y plantas se determinan mediante ICP-AES, y su presencia en suelos mediante análisis de partículas por SEM-EDXRA. En los suelos, se detectan contenidos muy superiores a los de una muestra control para todos los elementos, que decrecen de forma gradual desde el foco contaminante. Estos contenidos en las plantas también son muy superiores a los valores de la muestra control, siendo especialmente elevados en las partes aéreas. Esta alta contaminación de las partes

  4. Metales pesados y su relación con marcadores de estrés oxidativo en fumadores crónicos

    Directory of Open Access Journals (Sweden)

    Raquel Salazar-Lugo

    2015-12-01

    Full Text Available Se evaluaron las concentraciones de metales Fe, Zn, Cu, Cr, Cd y Ni y su relación con marcadores de estrés oxidativo en 50 fumadores crónicos de ambos géneros (30 y 84 años. Los fumadores se dividieron en dos grupos: 25 fumadores de 1-5 cigarrillos/día (cig/día y 25 fumadores de más de 6 cig/día. Los niveles de metales en sangre total y en orina fueron determinados por espectrofotometría de emisión atómica con plasma inductivamente acoplado (ICPOES. Se realizaron determinaciones hematológicas y bioquímicas de proteínas totales, fraccionadas y de tioles totales. Los fumadores presentaron mayores concentraciones de Fe en sangre independientemente del número de cigarrillos fumados y menores concentraciones de Zn, Cr y Ni. No se observaron diferencias en las concentraciones de Cu en sangre. El Cd en fumadores estuvo entre 5,0-10,0 μg/L y en no-fumadores entre 0,0-5,0 μg/L. No se observaron diferencias signi cativas en las concentraciones de hemoglobina, hematocrito y la hemoglobina corpuscular media en los grupos, ni entre las concentraciones de albúmina ni globulinas; se observó un incremento en los leucocitos y en los grupos tioles totales de fumadores. Las concentraciones de Fe en sangre se correlacionaron con los glóbulos blancos y con el Cd; igualmente se encontró correlación entre la albúmina y los grupos tioles. Las concentraciones de Zn y el Cu se incrementaron en la orina de fumadores, no así las concentraciones de Fe. De acuerdo a estos resultados, en los fumadores crónicos, la distribución de Fe en el organismo juega un papel central en la posible progresión y desarrollo de las enfermedades relacionadas con este hábito.

  5. Lead (Pb) and other metals in New York City community garden soils: factors influencing contaminant distributions

    Science.gov (United States)

    Mitchell, Rebecca G.; Spliethoff, Henry M.; Ribaudo, Lisa N.; Lopp, Donna M.; Shayler, Hannah A.; Marquez-Bravo, Lydia G.; Lambert, Veronique T.; Ferenz, Gretchen S.; Russell-Anelli, Jonathan M.; Stone, Edie B.; McBride, Murray B.

    2014-01-01

    Urban gardens provide affordable fresh produce to communities with limited access to healthy food but may also increase exposure to lead (Pb) and other soil contaminants. Metals analysis of 564 soil samples from 54 New York City (NYC) community gardens found at least one sample exceeding health-based guidance values in 70% of gardens. However, most samples (78%) did not exceed guidance values, and medians were generally below those reported in NYC soil and other urban gardening studies. Barium (Ba) and Pb most frequently exceeded guidance values and along with cadmium (Cd) were strongly correlated with zinc (Zn), a commonly measured nutrient. Principal component analysis suggested that contaminants varied independently from organic matter and geogenic metals. Contaminants were associated with visible debris and a lack of raised beds; management practices (e.g., importing uncontaminated soil) have likely reduced metals concentrations. Continued exposure reduction efforts would benefit communities already burdened by environmental exposures. PMID:24502997

  6. Estudio de organismos acuáticos macrobentónicos como indicadores de la contaminación por metales pesados en ríos de la Huasteca Potosina

    OpenAIRE

    CYNTHIA WONG ARGUELLES

    2009-01-01

    La importancia de utilizar organismos acuáticos macrobentónicos como indicadores de la contaminación es la de evaluar de manera directa el impacto biológico de los metales traza (Cu, Pb, Cd y Zn). El análisis en organismos acuáticos ha sido utilizado como un complemento para el muestreo tradicional, utilizando los organismos acuáticos como biomonitores u organismos centinelas. El biomonitoreo pretende buscar la relación entre la concentración del contaminante en el organismo y en su ambiente...

  7. Milk and Dairy Products Intake Is Associated with Low Levels of Lead (Pb) in Workers highly Exposed to the Metal.

    Science.gov (United States)

    Gomes, Willian Robert; Devóz, Paula Pícoli; Araújo, Marília Ladeira; Batista, Bruno Lemos; Barbosa, Fernando; Barcelos, Gustavo Rafael Mazzaron

    2017-07-01

    Lead (Pb) is a toxic metal, frequently associated with occupational exposure, due to its widespread use in industry and several studies have shown high Pb levels in workers occupationally exposed to the metal. The aim of this study was to evaluate the influence of milk and dairy products (MDP) on Pb levels in blood (B-Pb), plasma (P-Pb), and urine (U-Pb), in workers from automotive battery industries in Brazil. The study included 237 male workers; information concerning diet and lifestyle were gathered through a questionnaire, and B-Pb, P-Pb, and U-Pb were determined by ICP-MS. Mean B-Pb, P-Pb, and U-Pb were 21 ± 12, 0.62 ± 0.73 μg/dL, and 39 ± 47 μg/g creatinine, respectively. Forty three percent of participants declared consuming ≤3 portions/week of MDP (classified as low-MDP intake), while 57% of individuals had >3portions/week of MDP (high-MDP intake). B-Pb and P-Pb were correlated with working time (r s  = 0.21; r s  = 0.20; p < 0.010). Multivariable linear regressions showed a significant influence of MDP intake on B-Pb (β = -0.10; p = 0.012) and P-Pb (β = -0.16; p < 0.010), while no significance was seen on U-Pb. Our results suggest that MDP consumption may modulate Pb levels in individuals highly exposed to the metal; these findings may be due to the Pb-Ca interactions, since the adverse effects of Pb are partially based on its interference with Ca metabolism and proper Ca supplementation may help to reduce the adverse health effects induced by Pb exposure.

  8. Distributions and pollution assessment of heavy metals Pb, Cd and Cr in the water system of Kendari Bay, Indonesia

    Science.gov (United States)

    Armid, A.; Shinjo, R.; Ruslan, R.; Fahmiati

    2017-02-01

    The concentrations of heavy metals Pb, Cd and Cr in the coastal waters of Kendari Bay were analyzed to assess their pollution status. Water samples from 32 sampling points were analyzed for dissolved heavy metals concentrations by using inductively coupled plasma mass spectrometry (ICP-MS). The RSD(%) of each metal was accounted to analyze the diversity of the heavy metals among 32 sampling points. The results demonstrate that the dissolved heavy metal Pb had the highest concentrations (0.009 to 0.549 μg/L, average = 0.210 μg/L) followed by Cr (0.085 to 0.386 μg/L, average = 0.149 μg/L), and Cd (0.001 to 0.015 μg/L, average = 0.008 μg/L). Based on the the RSD values (Pb = 87.8%, Cd = 45.2% and Cr = 41.3%), it is suggested that the antropogenic activities controls the high diversity of concentrations for heavy metal Pb relative to those of Cd and Cr. Comparing the data with the mean oceanic concentrations, only the concentrations of Pb exceed the mean oceanic level (210 folds). Therefore, the water system of Kendari Bay is severely polluted with heavy metal Pb. More management and treatment should be introduced to protect the marine environment in the study area, especially from Pb pollution.

  9. Pb isotope evidence for contaminant-metal dispersal in an international river system: The lower Danube catchment, Eastern Europe

    International Nuclear Information System (INIS)

    Bird, Graham; Brewer, Paul A.; Macklin, Mark G.; Nikolova, Mariyana; Kotsev, Tsvetan; Mollov, Mihail; Swain, Catherine

    2010-01-01

    Lead isotope signatures ( 207 Pb/ 206 Pb, 208 Pb/ 206 Pb, 208 Pb/ 204 Pb, 206 Pb/ 204 Pb), determined by magnetic sector ICP-MS in river channel sediment, metal ores and mine waste, have been used as geochemical tracers to quantify the delivery and dispersal of sediment-associated metals in the lower Danube River catchment. Due to a diverse geology and range of ore-body ages, Pb isotope signatures in ore-bodies within the lower Danube River catchment show considerable variation, even within individual metallogenic zones. It is also possible to discriminate between the Pb isotopic signatures in mine waste and river sediment within river systems draining individual ore bodies. Lead isotopic data, along with multi-element data; were used to establish the provenance of river sediments and quantify sedimentary contributions to mining-affected tributaries and to the Danube River. Data indicate that mining-affected tributaries in Serbia and Bulgaria contribute up to 30% of the river channel sediment load of the lower Danube River. Quantifying relative sediment contributions from mining-affected tributaries enables spatial patterns in sediment-associated metal and As concentrations to be interpreted in terms of key contaminant sources. Combining geochemical survey data with that regarding the provenance of contaminated sediments can therefore be used to identify foci for remediation and environmental management strategies.

  10. Chelating agents to solubilize heavy metals from Oxisols contaminated by the addition of organic and inorganic residues Uso de quelantes na solubilização de metais pesados de Latossolos contaminados pela adição de resíduos orgânico e inorgânico

    Directory of Open Access Journals (Sweden)

    Aline Renée Coscione

    2009-02-01

    Full Text Available Phytoremediation is an attractive technique for soils contaminated with heavy metals, especially in conjunction with chelating agents to assist metal phytoextraction. Nevertheless, their studies in Brazil are rare. Thus, the objective of the present work was to evaluate the efficiency of the chelating agents EDDS and EDTA for the solubilization of heavy metals from two Oxisols contaminated by organic sources in Jaguariúna (LVJ and inorganic sources in Paulínia (LVP, São Paulo State, Southeastern Brazil. First, the soil samples were fractionated and the DTPA method was used to quantify heavy metals available forms. The results indicated that the metals were highly available in the soil fractions and could be solubilized by the chelating agents. The soil was suspended for 24 h in a chelating agent solution (EDTA or EDDS at rates of 0, 250, 500 and 750 mg kg-1 of soil. The concentration of solubilized heavy metals was determined in the resulting solution. The extent of metal solubilization varied according to soil type, the chelating agent added and the specific metal. The amount of iron solubilized, as compared to the total iron (LVJ was 11% (EDTA and 19% (EDDS. EDDS solubilized more Cu than EDTA in both soils but more Ni in LVJ, while EDTA solubilized more Zn in both soils but more Cd in LVP. Both EDTA and EDDS may be useful for phytoextraction from soils, although the iron content is an important factor regarding the phytoextraction of heavy metals with chelating agents in Oxisols.A fitoextração tem sido uma opção atrativa para remediar solos contaminados com metais pesados, principalmente quando associada à aplicação de quelantes ao solo, embora no Brasil seus estudos sejam muito incipientes. Portanto, o objetivo deste trabalho foi avaliar a eficiência dos quelantes EDTA e EDDS na solubilização de metais pesados em Latossolos contaminados por Cu, Zn, Cd e Ni, cujas fontes de contaminação foram: orgânica em Jaguariúna (LVJ e

  11. A Review on Heavy Metals (As, Pb, and Hg Uptake by Plants through Phytoremediation

    Directory of Open Access Journals (Sweden)

    Bieby Voijant Tangahu

    2011-01-01

    Full Text Available Heavy metals are among the most important sorts of contaminant in the environment. Several methods already used to clean up the environment from these kinds of contaminants, but most of them are costly and difficult to get optimum results. Currently, phytoremediation is an effective and affordable technological solution used to extract or remove inactive metals and metal pollutants from contaminated soil and water. This technology is environmental friendly and potentially cost effective. This paper aims to compile some information about heavy metals of arsenic, lead, and mercury (As, Pb, and Hg sources, effects and their treatment. It also reviews deeply about phytoremediation technology, including the heavy metal uptake mechanisms and several research studies associated about the topics. Additionally, it describes several sources and the effects of As, Pb, and Hg on the environment, the advantages of this kind of technology for reducing them, and also heavy metal uptake mechanisms in phytoremediation technology as well as the factors affecting the uptake mechanisms. Some recommended plants which are commonly used in phytoremediation and their capability to reduce the contaminant are also reported.

  12. Metal pollution (Cd, Pb, Zn, and As) in agricultural soils and soybean, Glycine max, in southern China.

    Science.gov (United States)

    Zhao, Yunyun; Fang, Xiaolong; Mu, Yinghui; Cheng, Yanbo; Ma, Qibin; Nian, Hai; Yang, Cunyi

    2014-04-01

    Crops produced on metal-polluted agricultural soils may lead to chronic toxicity to humans via the food chain. To assess metal pollution in agricultural soils and soybean in southern China, 30 soybean grain samples and 17 soybean-field soil samples were collected from 17 sites in southern China, and metal concentrations of samples were analyzed by graphite furnace atomic absorption spectrophotometer. The integrated pollution index was used to evaluate if the samples were contaminated by Cd, Pb, Zn and As. Results showed that Cd concentration of 12 samples, Pb concentration of 2 samples, Zn concentration of 2 samples, and As concentrations of 2 samples were above the maximum permissible levels in soils. The integrated pollution index indicated that 11 of 17 soil samples were polluted by metals. Metal concentrations in soybean grain samples ranged from 0.11 to 0.91 mg kg(-1) for Cd; 0.34 to 2.83 mg kg(-1) for Pb; 42 to 88 mg kg(-1) for Zn; and 0.26 to 5.07 mg kg(-1) for As, which means all 30 soybean grain samples were polluted by Pb, Pb/Cd, Cd/Pb/As or Pb/As. Taken together, our study provides evidence that metal pollution is an important concern in agricultural soils and soybeans in southern China.

  13. [Study on heavy metal contaminations and the sources of Pb pollution in Jinghai Bay using the stable isotope technique].

    Science.gov (United States)

    Xu, Lin-Bo; Gao, Qin-Feng; Dong, Shuang-Lin; Liu, Jia; Fu, Xiu-Juan

    2013-02-01

    The concentrations of typical heavy metals including Cu, Hg, Pb, Zn, Mn, Cd, Cr and As in the surface sediment and suspended particulate matter (SPM) in Jinghai Bay, Rongcheng city were tested. The degree of heavy metal pollution in the surface sediment was assessed according to the national standard of marine sediment quality. The potential ecological risk (PER) of heavy metals to marine ecosystem in Jinghai Bay was assessed using PER coefficient and risk index. The results showed that the levels of heavy metals and PER in the surface sediments were low enough to meet the requirement of the first class of the sediment quality standards except the levels of Cu and Zn in the sampling site S2 and Cd in S3, S4, S5 and S6 which met the requirements of the second class of the sediment quality standards. The PER coefficients of heavy metals increased following the sequence of Zn heavy metals in surface sediment and SPM were the highest at S2 and gradually declined with the increasing distance between the sampling sites and the shoreline. The correlation analysis of the loss on ignition (LOI) and the levels of heavy metals showed that LOI was positively correlated to the levels of Cu, Cr, Pb, Zn, Mn, Hg and As in surface sediment. Stable isotope technique was used to trace the dominant sources of Pb contamination in surface sediments and SPM. The results showed that the ratios of 208Ph/204Pb, 207Pb/204Pb, 206Pb/204Pb and 206pb/207pb in surface sediment were more closely related to that of SPM. The ratio of 206pb/207Pb for both surface sediment and SPM was the lowest at the sampling site S2 and negatively correlated to the Pb concentration. The comparisons of Pb stable isotope ratio between the isotope ratios of natural and anthropogenic source showed that the Pb contamination was mainly derived from the human activities such as industrial discharges and leaded gasoline.

  14. The Liquid-Liquid Extraction of Toxic Metals (Cd, Hg and Pb by Calixarenes

    Directory of Open Access Journals (Sweden)

    D. Max Roundhill

    2009-12-01

    Full Text Available Toxic metals (Cd, Hg and Pb are mostly present in the environment due to natural phenomenon and human activities as well. Exposure of these non-essential elements in the environment causes severe effects. They are known to cause problems in humans as well as in aquatic life. In this work, we demonstrate various studies regarding liquid-liquid extraction of selected ions with different functionalized calixarenes. This review article briefly discusses several molecular designs of calixarenes for divalent ion (Cd2+, Hg2+ and Pb2+ recognition; as well as the relationship between structure and selectivity of the macrocycles is elaborated. The article does not, however, attempt to cover all of the different approaches to these toxic metal ions extraction.

  15. CARACTERIZAÇÃO FÍSICO-QUÍMICA DA ÁGUA E DETERMINAÇÃO DE METAIS PESADOS (Cr, Cu, Pb e Zn NO SEDIMENTO DO RIACHO ARROIO DO PADRE (ARROIO DO PADRE, BRASIL/RS

    Directory of Open Access Journals (Sweden)

    Glauco Rasmussen Betemps

    2014-12-01

    Full Text Available A hidrografia do município de Arroio do Padre é constituída por sangas e arroios, entre os quais está o arroio do Padre. Desde a emancipação, o pequeno município tem se expandido próximo a este riacho comprometendo sua qualidade, devido à atividade agrícola e ao crescimento populacional. O presente trabalho investiga a qualidade ambiental do riacho Arroio do Padre, caracterizando-o através de análises físico-químicas da água e determinando a granulometria, o Carbono Orgânico Total e a concentração dos metais Cu, Cr, Pb e Zn no sedimento. As águas do riacho se enquadram nas Águas Doces de Classe 1 da Resolução do CONAMA 357/05. Os resultados dos ensaios físico-químicos indicaram baixo impacto ambiental sobre o riacho. O sedimento apresenta baixos níveis de contaminação pelos metais estudados, com exceção do Zn, não oferecendo risco à vida aquática.

  16. High Efficient Nanocomposite for Removal of Heavy Metals (Hg2+ and Pb2+ from Aqueous Solution

    Directory of Open Access Journals (Sweden)

    M. Ebadi

    2016-01-01

    Full Text Available In current work, CdS/black carbon nanocomposites were successfully synthesized with the aid of chestnut and cadmium nitrate as the starting reagents. Besides, the effects of preparation parameters such as reaction time, and precursor concentration on the morphology of products and removal of heavy metals (Hg+2, Pb+2 were studied by scanning electron microscopy images and batch adsorption mode. CdS/black carbon nanocomposite introduced as new and high efficient system for removal of heavy metal ions. The as-synthesized products were characterized by powder X-ray diffraction, scanning electron microscopy, and spectra energy dispersive analysis of X-ray.

  17. Evaluation of Diazatetraoxa Cryptand as Extractant for Transition Metals and Pb2+

    OpenAIRE

    Gülsev Dilber; Halit Kantekin; Dilek Başaran; Ümmühan Ocak; Miraç Ocak

    2014-01-01

    The extractability of metal cations such as Mn2+, Co2+, Cu2+, Zn2+ and Pb2+ from aqueous phase to organic phase with 19-nitro-6,7,15,16,23,24-hexahydro-13H,26H-14,25-propanotribenzo-[b,I,o][1,4,11,14,7,18]-tetraoxadiazacycloikocine was investigated by means of UV-vis spectrophotometer. The aqueous phase and the organic phase contained metal picrate and the ligands, respectively. Chloroform and dichloromethane were the organic solvents. The effect of pH on the percent extraction was evaluated ...

  18. Heavy metal input to agricultural soils from irrigation with treated wastewater: Insight from Pb isotopes

    Science.gov (United States)

    Kloppmann, Wolfram; Cary, Lise; Psarras, Georgios; Surdyk, Nicolas; Chartzoulakis, Kostas; Pettenati, Marie; Maton, Laure

    2010-05-01

    A major objective of the EU FP6 project SAFIR was to overcome certain drawbacks of wastewater reuse through the development of a new irrigation technology combining small-scale modular water treatment plants on farm level and improved irrigation hardware, in the aim to lower the risks related to low quality water and to increase water use efficiency. This innovative technology was tested in several hydro-climatic contexts (Crete, Italy, Serbia, China) on experimental irrigated tomato and potato fields. Here we present the heavy metal variations in soil after medium-term (3 irrigation seasons from 2006-2008) use of treated municipal wastewater with a special focus on lead and lead isotope signatures. The experimental site is located in Chania, Crete. A matrix of plots were irrigated, combining different water qualities (secondary, primary treated wastewater, tap water, partially spiked with heavy metals, going through newly developed tertiary treatment systems) with different irrigation strategies (surface and subsurface drip irrigation combined with full irrigation and partial root drying). In order to assess small scale heavy metal distribution around a drip emitter, Pb isotope tracing was used, combined with selective extraction. The sampling for Pb isotope fingerprinting was performed after the 3rd season of ww-irrigation on a lateral profile from a drip irrigator (half distance between drip lines, i.e. 50cm) and three depth intervals (0-10, 10-20, 20-40 cm). These samples were lixiviated through a 3 step selective extraction procedure giving rise to the bio-accessible, mobile and residual fraction: CaCl2/NaNO3 (bio-accessible fraction), DPTA (mobile fraction), total acid attack (residual fraction). Those samples were analysed for trace elements (including heavy metals) and major inorganic compounds by ICP-MS. The extracted fractions were then analysed by Thermal Ionisation Mass Spectrometry (TIMS) for their lead isotope fingerprints (204Pb, 206Pb, 207Pb, 208Pb

  19. Estudo termogravimétrico do processo de sorção de metais pesados por resíduos sólidos orgânicos Thermogravimetric study of the sorption process of heavy metals in organic solid waste

    Directory of Open Access Journals (Sweden)

    Aldre Jorge Morais Barros

    2006-06-01

    Full Text Available A poluição de uma bacia hidrográfica pode causar alterações das propriedades físicas, químicas e biológicas da massa de água, comprometendo o seu uso para o consumo humano e para outros tipos de atividades, dependendo do grau de poluição ou contaminação. Os métodos de tratamentos convencionais de efluentes contendo metais pesados produzem quantidades significativas de subprodutos com características recalcitrantes, além de serem técnicas onerosas e de reprodutibilidade baixa. A busca por soluções mais baratas e definitivas levou ao desenvolvimento de tecnologias limpas, dentre estas tecnologias destaca-se o processo de sorção que baseia-se na utilização de substâncias absorventes desses elementos químicos. Este trabalho teve como objetivo avaliar o processo de sorção de metais pesados pelos resíduos sólidos orgânicos utilizando-se das técnicas de termogravimetria. Os resultados obtidos demonstraram que os perfis das curvas da termogravimetria dos resíduos sólidos orgânicos apresentam modificações significativas nas características físicas e químicas, quando submetidas ao processo de sorção dos metais pesados.Pollution of a hydrographic basin can cause alterations in physical, chemical and biological properties of water mass, committing its use for the human consumption and for other types of activities, depending on the contamination or pollution level. The conventional treatment methods for effluents containing heavy metals produce significant amounts of byproducts with recalcitrant characteristics; besides the techniques being onerous their reproducibility is low. The search for cheaper and definitive solutions led to the development of clean technologies, among these technologies the sorption process based on utilization of absorbent substances for these elements can be pointed out. This work has the objective of evaluating the sorption process of heavy metals by organic solid waste utilizing the

  20. Contamination and Health Risks from Heavy Metals (Cd and Pb and Trace Elements (Cu and Zn in Dairy Products

    Directory of Open Access Journals (Sweden)

    Hamid Reza Ghafari

    2017-08-01

    Conclusion: Considering the serious contamination of some brands of butter and cheese by Cu and Pb, a control of heavy metals and trace elements levels during the whole production processing of dairy products must be applied.

  1. Concentrations of heavy metals (Mn, Co, Ni, Cr, Ag, Pb) in coffee.

    Science.gov (United States)

    Nędzarek, Arkadiusz; Tórz, Agnieszka; Karakiewicz, Beata; Clark, Jeremy Simon; Laszczyńska, Maria; Kaleta, Agnieszka; Adler, Grażyna

    2013-01-01

    Technologies involved in roasting coffee beans, as well as the methods used to prepare infusions, vary according to culture, and contribute to differences in the concentration of elements in the drink. Concentrations of six elements: manganese (Mn), cobalt (Co), nickel (Ni), chrome (Cr), silver (Ag) and lead (Pb) were investigated in coffee infusions from eleven samples of coffee, roasted and purchased in four countries: Bosnia and Herzegovina, Brazil, Lebanon and Poland. Metal concentrations were determined using an induction coupled plasma technique in combination with mass spectrometry (ICP-MS, Perkin Elmer) which measures total metal (ionic and non-ionic) content. Metal intake estimated for individual countries (in the respective order; mean consumption per person per year) was as follows: Mn: 26.8-33.1, 28.3-29.5, 29.7, 12.6-18.9 mg; Co: 0.33-0.48, 0.42-0.35, 0.32, 0.12-0.17 mg; Ni: 3.83-5.68, 4.85-5.51, 4.04, 2.06-2.24 mg; Cr: 0.17-0.41, 0.21-0.47, 0.17, 0.09-0.28 mg; Ag: 0.16-1.13, 0.26-0.70, 0.61, 0.33-1.54 mg, Pb: 4.76-7.56, 3.59-5.13, 3.33, 1.48-2.43 mg. This finding gives new data for Mn, Co, Ni, Cr, and Ag intake from coffee , and suggests that the amounts are negligible. However, the data for Pb consumption in heavy drinkers, for example in Bosnia and Herzegovina, indicate that Pb intake from coffee may contribute to the disease burden. The high lead level in some coffees suggests the need for a more precise control of coffee contamination.

  2. Heavy metals (Pb, Cd, As and MeHg) as risk factors for cognitive dysfunction: A general review of metal mixture mechanism in brain.

    Science.gov (United States)

    Karri, Venkatanaidu; Schuhmacher, Marta; Kumar, Vikas

    2016-12-01

    Human exposure to toxic heavy metals is a global challenge. Concurrent exposure of heavy metals, such as lead (Pb), cadmium (Cd), arsenic (As) and methylmercury (MeHg) are particularly important due to their long lasting effects on the brain. The exact toxicological mechanisms invoked by exposure to mixtures of the metals Pb, Cd, As and MeHg are still unclear, however they share many common pathways for causing cognitive dysfunction. The combination of metals may produce additive/synergetic effects due to their common binding affinity with NMDA receptor (Pb, As, MeHg), Na + - K + ATP-ase pump (Cd, MeHg), biological Ca +2 (Pb, Cd, MeHg), Glu neurotransmitter (Pb, MeHg), which can lead to imbalance between the pro-oxidant elements (ROS) and the antioxidants (reducing elements). In this process, ROS dominates the antioxidants factors such as GPx, GS, GSH, MT-III, Catalase, SOD, BDNF, and CERB, and finally leads to cognitive dysfunction. The present review illustrates an account of the current knowledge about the individual metal induced cognitive dysfunction mechanisms and analyse common Mode of Actions (MOAs) of quaternary metal mixture (Pb, Cd, As, MeHg). This review aims to help advancement in mixture toxicology and development of next generation predictive model (such as PBPK/PD) combining both kinetic and dynamic interactions of metals. Copyright © 2016 Elsevier B.V. All rights reserved.

  3. Metal and metalloid contamination in roadside soil and wild rats around a Pb-Zn mine in Kabwe, Zambia

    Energy Technology Data Exchange (ETDEWEB)

    Nakayama, Shouta M.M.; Ikenaka, Yoshinori; Hamada, Kyohei [Laboratory of Toxicology, Department of Environmental Veterinary Sciences, Graduate School of Veterinary Medicine, Hokkaido University, Kita 18, Nishi 9, Kita-ku, Sapporo 060-0818 (Japan); Muzandu, Kaampwe; Choongo, Kennedy [Department of Biomedical Studies, School of Veterinary Medicine, University of Zambia, P.O. Box 32379, Lusaka (Zambia); Teraoka, Hiroki; Mizuno, Naoharu [Department of Toxicology, School of Veterinary Medicine, Rakuno Gakuen University, Ebetsu 069-8501 (Japan); Ishizuka, Mayumi, E-mail: ishizum@vetmed.hokudai.ac.j [Laboratory of Toxicology, Department of Environmental Veterinary Sciences, Graduate School of Veterinary Medicine, Hokkaido University, Kita 18, Nishi 9, Kita-ku, Sapporo 060-0818 (Japan)

    2011-01-15

    Metal (Cr, Co, Cu, Zn, Cd, Pb, Ni) and metalloid (As) accumulation was studied in roadside soil and wild rat (Rattus sp.) samples from near a Pb-Zn mine (Kabwe, Zambia) and the capital city of Zambia (Lusaka). The concentrations of the seven metals and As in the soil samples and Pb in the rat tissue samples were quantified using atomic absorption spectroscopy. The concentrations of Pb, Zn, Cu, Cd, and As in Kabwe soil were much higher than benchmark values. Geographic Information System analysis indicated the source of metal pollution was mining and smelting activity. Interestingly, the area south of the mine was more highly contaminated even though the prevailing wind flow was westward. Wild rats from Kabwe had much higher tissue concentrations of Pb than those from Lusaka. Their body weight and renal Pb levels were negatively correlated, which suggests that mining activity might affect terrestrial animals in Kabwe. - The area around Kabwe, Zambia is highly polluted with metals and As. Wild rats from this area had high tissue concentrations of Pb and decreased body weight.

  4. Biosorption of Cd, Cr, Mn, and Pb from aqueous solutions by Bacillus sp strains isolated from industrial waste activate sludge

    Directory of Open Access Journals (Sweden)

    Rocío García

    2016-01-01

    Full Text Available Los microorganismos tienen capacidad de acumular metales pesados como agentes bioadsorbentes ofreciendo una alternativa para la remoción de metales tóxicos en aguas de efluentes industriales. El objetivo del presente trabajo fue aislar e identificar bacterias tolerantes a los metales pesados (Cd, Cr, Mn y Pb de lodos activados provenientes de la planta de tratamiento de agua del Municipio de Santa Rosa Jáuregui, Querétaro. Para seleccionar las bacterias que son tolerantes a los metales se aislaron 37 cepas bacterianas de las cuales se seleccionaron la Cepa-13 y Cepa-16 (C-13 y C-16, que presentaron una máxima capacidad de adsorción para los metales estudiados. En este artículo, el término biosorción describe la remoción de contaminantes y la utilización de biomasas (muerta mediante mecanismos fisicoquímicos como el proceso de adsorción o de intercambio iónico. Para obtener las condiciones de máxima adsorción se aplicó un tratamiento alcalino y uno ácido. La capacidad de adsorción fue menor en medio ácido que el bioadsorbente con tratamiento alcalino. Una segunda etapa del estudio fue la biosorción de metales pesados (Cd, Cr, Mn, y Pb utilizando las biomasas muertas de Bacillus sp (cepa C13 y C16 aisladas de los lodos activados de la primera etapa.

  5. Heavy metal pollution and Pb isotopic tracing in the intertidal surface sediments of Quanzhou Bay, southeast coast of China.

    Science.gov (United States)

    Yu, Ruilian; Zhang, Weifang; Hu, Gongren; Lin, Chengqi; Yang, Qiuli

    2016-04-15

    Concentrations of 16 heavy metals and Pb isotopic ratios in the intertidal surface sediments of Quanzhou Bay were determined to study the pollution level of heavy metals and the sources of Pb. The results showed that most concentrations of Cd, Sn, Mn, Cu, Zn, Cr, Pb, Hg, Ni, Co, Cs, Fe and V were higher than the background values, while most concentrations of Ti, Sb and Sr were lower than the background values. The mean concentrations of Cu, Zn, Pb, Cr and Cd exceeded the first-grade criteria of Chinese marine sediment quality. The geo-accumulation indexes revealed that the sediments had been polluted by some heavy metals. The results of Pb isotopic tracing indicated that the total Pb in the sediments were mainly from parent material, industrial emission and vehicle exhaust with the mean contributions of 38.2%, 51.3% and 10.5%, respectively, calculated by a three-end-member model of Pb isotopic ratios. Copyright © 2016 Elsevier Ltd. All rights reserved.

  6. Competitive immobilization of Pb in an aqueous ternary-metals system by soluble phosphates with varying pH.

    Science.gov (United States)

    Zhang, Zhuo; Ren, Jie; Wang, Mei; Song, Xinlai; Zhang, Chao; Chen, Jiayu; Li, Fasheng; Guo, Guanlin

    2016-09-01

    Chemical immobilization by phosphates has been widely and successfully applied to treat Pb in wastewater and contaminated soils. Pb in wastewaters and soils, however, always coexists with other heavy metals and their competitive reactions with phosphates have not been quantitatively and systematically studied. In this approach, immobilization of Pb, Zn, and Cd by mono-, di-, and tripotassium phosphate (KH2PO4, K2HPO4, and K3PO4) was observed in the single- and ternary-metals solutions. The immobilization rates of the three metals were determined by the residual concentration. The mineral composition and structure of the precipitates were characterized by powder X-ray diffraction (XRD) analysis and scanning electron microscopy (SEM). The results indicated that competitive reaction occurred in Pb-Zn-Cd ternary system, with immobilization rates decrease of system. The reaction of Pb with three phosphates exhibited intense competitiveness and the phosphates had a stronger affinity for Pb when Cl(-) was added. Pb-phosphate minerals formed by KH2PO4 with the better crystalline characteristics and largest size were very stable with a low dissolution rate (system. Copyright © 2016 Elsevier Ltd. All rights reserved.

  7. Analysis of Heavy Metal Content (Pb) on Waters and Fish at The Floating Cages BPPP Ambon

    Science.gov (United States)

    Wattimena, Rachel L.; Selanno, Debby A. J.; Tuhumury, Semuel F.; Tuahatu, Juliana W.

    2018-02-01

    Coastal waters play important roles due to highly in natural resources and developing of environmental services. However, there are highly intensity of natural resources utilization, environment and settlement. Consequently, environment and natural resources would be degraded such as in the Ambon Bay. One of the potency at the Ambon Bay is mariculture area namely the floating cages (KJA) which belongs to Fisheries education and training (BPPP) Ambon. The research aimed to analyze physical-chemical of waters (temperature, pH, salinity and current speed), to analyze heavy metal concentration (Pb) on water and fish from floating cages (KJA) and to analyze waters pollution status at KJA BPPP Ambon. The average salinity of each floating cage ranged from 30.09 - 30.34°C, pH ranged from 8.03 - 8.44, salinity ranged from 31.36 - 33.34 PSU, and current speed at spring tide ranged from 0.5 - 55.8 Cm/sec while neap tide ranged from 0.1 - 9.8 Cm/sec. Heavy metal concentration (Pb) on waters was below the standard for waters quality and the average concentration was 0.002 mg/l. Whilst, the heavy metal concentration (Pb) on fishes was below standard for floating cages (floating cages 2-6) which was 0.05 and 0.17mg/l. Otherwise, floating cage 1 had been above maximum standard for fish food and its processing following SNI 7387:2009 (0.3mg/l) which was 0.31 mg/l. The status of waters pollution at KJA BPPP Ambon belonged to C class and could be categorized as moderate based on standard for waters quality issued by State Ministerial Decree for the Environment No. 51 Year 2004.

  8. Analysis of Heavy Metal Content (Pb on Waters and Fish at The Floating Cages BPPP Ambon

    Directory of Open Access Journals (Sweden)

    Wattimena Rachel L.

    2018-01-01

    Full Text Available Coastal waters play important roles due to highly in natural resources and developing of environmental services. However, there are highly intensity of natural resources utilization, environment and settlement. Consequently, environment and natural resources would be degraded such as in the Ambon Bay. One of the potency at the Ambon Bay is mariculture area namely the floating cages (KJA which belongs to Fisheries education and training (BPPP Ambon. The research aimed to analyze physical-chemical of waters (temperature, pH, salinity and current speed, to analyze heavy metal concentration (Pb on water and fish from floating cages (KJA and to analyze waters pollution status at KJA BPPP Ambon. The average salinity of each floating cage ranged from 30.09 - 30.34°C, pH ranged from 8.03 − 8.44, salinity ranged from 31.36 − 33.34 PSU, and current speed at spring tide ranged from 0.5 – 55.8 Cm/sec while neap tide ranged from 0.1 – 9.8 Cm/sec. Heavy metal concentration (Pb on waters was below the standard for waters quality and the average concentration was 0.002 mg/l. Whilst, the heavy metal concentration (Pb on fishes was below standard for floating cages (floating cages 2-6 which was 0.05 and 0.17mg/l. Otherwise, floating cage 1 had been above maximum standard for fish food and its processing following SNI 7387:2009 (0.3mg/l which was 0.31 mg/l. The status of waters pollution at KJA BPPP Ambon belonged to C class and could be categorized as moderate based on standard for waters quality issued by State Ministerial Decree for the Environment No. 51 Year 2004.

  9. Orbital-exchange and fractional quantum number excitations in an f-electron metal, Yb2Pt2Pb

    NARCIS (Netherlands)

    Wu, L.S.; Gannon, W.J.; Zaliznyak, I.A.; Tsvelik, A.M.; Brockmann, M.; Caux, J.-S.; Kim, M.S.; Qiu, Y.; Copley, J.R.D.; Ehlers, G.; Podlesnyak, A.; Aronson, M.C.

    2016-01-01

    Exotic quantum states and fractionalized magnetic excitations, such as spinons in one-dimensional chains, are generally expected to occur in 3d transition metal systems with spin 1/2. Our neutron-scattering experiments on the 4f-electron metal Yb2Pt 2 Pb overturn this conventional wisdom. We observe

  10. Removal of industrial dyes and heavy metals by Beauveria bassiana: FTIR, SEM, TEM and AFM investigations with Pb(II).

    Science.gov (United States)

    Gola, Deepak; Malik, Anushree; Namburath, Maneesh; Ahammad, Shaikh Ziauddin

    2017-10-01

    Presence of industrial dyes and heavy metal as a contaminant in environment poses a great risk to human health. In order to develop a potential technology for remediation of dyes (Reactive remazol red, Yellow 3RS, Indanthrene blue and Vat novatic grey) and heavy metal [Cu(II), Ni(II), Cd(II), Zn(II), Cr(VI) and Pb(II)] contamination, present study was performed with entomopathogenic fungi, Beauveria bassiana (MTCC no. 4580). High dye removal (88-97%) was observed during the growth of B. bassiana while removal percentage for heavy metals ranged from 58 to 75%. Further, detailed investigations were performed with Pb(II) in terms of growth kinetics, effect of process parameters and mechanism of removal. Growth rate decreased from 0.118 h -1 (control) to 0.031 h -1 , showing 28% reduction in biomass at 30 mg L -1 Pb(II) with 58.4% metal removal. Maximum Pb(II) removal was observed at 30 °C, neutral pH and 30 mg L -1 initial metal concentration. FTIR analysis indicated the changes induced by Pb(II) in functional groups on biomass surface. Further, microscopic analysis (SEM and atomic force microscopy (AFM)) was performed to understand the changes in cell surface morphology of the fungal cell. SEM micrograph showed a clear deformation of fungal hyphae, whereas AFM studies proved the increase in surface roughness (RSM) in comparison to control cell. Homogenous bioaccumulation of Pb(II) inside the fungal cell was clearly depicted by TEM-high-angle annular dark field coupled with EDX. Present study provides an insight into the mechanism of Pb(II) bioremediation and strengthens the significance of using entomopathogenic fungus such as B. bassiana for metal and dye removal.

  11. Effect of the air pollution by heavy metals in the tree leaves in the metropolitan area of Toluca Valley; Efecto de la contaminacion atmosferica por metales pesados en las hojas de los arboles de la zona metropolitana del Valle de Toluca

    Energy Technology Data Exchange (ETDEWEB)

    Ledesma O, C. I.

    2014-07-01

    Leaves of two tree species: Juniperus sp and Ligustrum sp were studied as indicators of pollution heavy metals (Mn, Fe, Cu, Zn and Pb) in the atmosphere of the Metropolitan Area of the Toluca Valley. Bio markers of catalase, superoxide dismutase, ascorbate peroxidase, guaiacol, proteins and pigments were measured in order to determine the effects to atmospheric stress caused by heave metals during two periods in the year (December 2012 and May 2013). Metals were quantified in dry deposit and tissue on trees tissue leaves using the technique of Energy Dispersive X-ray Fluorescence Spectroscopy and Total Reflection X-ray Fluorescence Spectroscopy respectively. The results show greater response of enzyme inhibition in Juniperus sp. species, with decreased protein content and increased lipid peroxidation at sites with higher content of metals in tissue belonging to urban areas with increased industrial activity and traffic flow. In dry deposit bioavailability factor of metals was Fe>Mn> Zn> Cu>Pb for the first time of sampling and Fe>Mn> Cu> Zn>Pb for the second sampling period. (Author)

  12. Concentration of Heavy Metal (Pb and Cu in Sediment and Mangrove Avicennia Marina at Porong River Estuary, Sidoarjo, East Java

    Directory of Open Access Journals (Sweden)

    Ledhyane Ika Harlyan

    2015-06-01

    Full Text Available Abstract –The ability of mangrove (Avicennia to absorb heavy metal has been known. This study aims to determine whether there are differences of absorption level of non-essential (Pb essential (Cu heavy metals in Avicennia marinafrom different location, based on distance of pollutants sources (downstream toward to the mouth of Porong River Estuary at Sidoarjo. Results showed that accumulation of Pb in the roots and leaves was ranged from 0.0044 to 0.139 ppm and from 0.004 to 0.019 ppm respectively, while in sediment was ranged from 0.0560 to 0.0660 ppm. The accumulation of Cu in the roots and leaves was ranged from 0.07 to 0.415 ppm and 0.0318 to 0.2520 ppm while in sediments was from 0.2930 to 0.381 ppm. The highest concentration of Pb and Cu were found from sediments followed by roots and leaves. The high concentration of heavy metal (Pb and Cu in the root is likely due to sediment size. The high concentration of heavy metal (Pb and Cu in the root is likely due to sediment size. When the size is finer, heavy metal accumulation will be higher, although there was no significantly different from different location.

  13. Soil heavy metal pollution and risk assessment associated with the Zn-Pb mining region in Yunnan, Southwest China.

    Science.gov (United States)

    Cheng, Xianfeng; Danek, Tomas; Drozdova, Jarmila; Huang, Qianrui; Qi, Wufu; Zou, Liling; Yang, Shuran; Zhao, Xinliang; Xiang, Yungang

    2018-03-07

    The environmental assessment and identification of sources of heavy metals in Zn-Pb ore deposits are important steps for the effective prevention of subsequent contamination and for the development of corrective measures. The concentrations of eight heavy metals (As, Cd, Cr, Cu, Hg, Ni, Pb, and Zn) in soils from 40 sampling points around the Jinding Zn-Pb mine in Yunnan, China, were analyzed. An environmental quality assessment of the obtained data was performed using five different contamination and pollution indexes. Statistical analyses were performed to identify the relations among the heavy metals and the pH in soils and possible sources of pollution. The concentrations of As, Cd, Pb, and Zn were extremely high, and 23, 95, 25, and 35% of the samples, respectively, exceeded the heavy metal limits set in the Chinese Environmental Quality Standard for Soils (GB15618-1995, grade III). According to the contamination and pollution indexes, environmental risks in the area are high or extremely high. The highest risk is represented by Cd contamination, the median concentration of which exceeds the GB15618-1995 limit. Based on the combination of statistical analyses and geostatistical mapping, we identified three groups of heavy metals that originate from different sources. The main sources of As, Cd, Pb, Zn, and Cu are mining activities, airborne particulates from smelters, and the weathering of tailings. The main sources of Hg are dust fallout and gaseous emissions from smelters and tailing dams. Cr and Ni originate from lithogenic sources.

  14. Fitoextração de cádmio e zinco de um latossolo vermelho-amarelo contaminado com metais pesados Phytoextraction of cadmium and zinc from an oxisol contaminated with heavy metals

    Directory of Open Access Journals (Sweden)

    Carolina de Freitas Zeittouni

    2007-01-01

    Full Text Available Avaliou-se a capacidade das plantas de mamona, girassol, pimenta da amazônia e tabaco, cultivadas em vasos de 3 L, em casa de vegetação, em extrair metais de um Latossolo Vermelho-Amarelo distrófico. O delineamento experimental foi em blocos ao acaso, esquema fatorial 4 espécies x 3 doses de metais x 2 doses de EDTA (Ácido Etilenodiaminotetraacético, com três repetições. As doses empregadas de metais, aplicadas na forma de sais inorgânicos foram, em mg kg-1: dose zero - sem adição de metal; dose 1 - adição conjunta de 0,75 de Cd, 6,25 de Pb, 20,0 de Cu, 8,75 de Ni e 62,5 de Zn e; dose 2 - adição conjunta de 1,5 de Cd, 12,5 de Pb, 40,0 de Cu, 17,5 de Ni e 125,0 de Zn, na presença (1 mmol kg-1 e ausência de EDTA. A colheita da parte aérea das quatro espécies de plantas variou de 48 dias (pimenta até 100 dias (tabaco. A aplicação do EDTA diminuiu a produção de matéria seca da parte aérea de todas as plantas, embora tenha provocado aumento na concentração de Cd na parte aérea da mamoneira e do girassol e nenhuma influência na concentração de Cd (pimenta e tabaco e na de Zn em todas as espécies. Concluiu-se que a planta mais eficiente em extrair o Cd e o Zn do solo enriquecido com metais foi o tabaco (Nicotiana tabacum e que para descontaminar o solo, será necessário um maior número de cultivos para todas as culturas, com exceção da mamoneira, se houver a aplicação de EDTA na dose de 1 mmol kg-1.In a greenhouse experiment, the ability of sunflower (Helianthus annuus L., castor bean (Ricinus communis L., tobacco (Nicotiana tabacum L., and Amazon pepper (Capsicum baccatum L. to extract Cd and Zn from an oxisol contaminated with heavy metals was evaluated. The experiment was carried out in a complete ramdomized block design in a factorial scheme consisted of 4 species x 3 rates of metals x 2 rates of EDTA, with 3 replicates and using plastic pots with 3 L capacity. Heavy metals were applied to the soil, as

  15. Application of Pb isotopes to track the sources and routes of metal uptake in the earthworm Eisenia fetida

    Directory of Open Access Journals (Sweden)

    Bader Albogami

    2014-12-01

    Full Text Available The aim of this work is to determine the important routes of metal uptake in earthworms to enable a better understanding of the primary source of metal uptake in the environment. Earthworms can take up chemicals from pore water and soil both by ingestion and through contact with their skin. However, it is unclear which pathway is the most important for metal uptake. An experiment was designed in which both soil chemistry and foods were artificially manipulated, producing different pools of soil lead (Pb with different isotope compositions at a range of Pb concentrations. Earthworms (Eiseniafetida were exposed to different lead concentrations through the addition of 500 mg/kg lead oxide (Pb3O4 to soil and 500 mg/kg lead nitrate to food (manure, with distinctly different isotopic compositions. Earthworms were also exposed to combinations of soil only and soil plus food in order to quantify the proportions of Pb taken up from each component. After acid digestion of the earthworm tissues, the Pb isotope composition of the accumulated lead in the earthworms was measured using a Thermo-fisher, iCAPQ, ICP-MS for 208Pb/206Pb and 207Pb/206Pb ratios measured relative to NIST SRM 981, allowing us to determine the pathway of lead uptake. Mixing calculations have been used to deconvolute the lead isotope signatures and identify the amount of lead taken up by the earthworms from the different soil pools. Differences in bioaccumulation factors and the relative amounts of lead accumulated from different pools changes as a function of concentration in the different pools. Earthworms were shown to uptake lead from bothsoil and food sources through ingestion route. Our findings suggest that a major pathway of lead uptake in earthworm species is heavily influenced by their ecology.

  16. Heavy metal (Cu, Zn, Cd and Pb) partitioning and bioaccessibility in uncontaminated and long-term contaminated soils

    International Nuclear Information System (INIS)

    Lamb, Dane T.; Ming Hui; Megharaj, Mallavarapu; Naidu, Ravi

    2009-01-01

    We investigated the pore-water content and speciation of copper (Cu), zinc (Zn), cadmium (Cd) and lead (Pb) in a range of uncontaminated and long-term contaminated soils in order to establish their potential bioaccessibility to soil biota, plants and humans. Among the samples, soil pH (0.01 M CaCl 2 ) ranged from 4.9 to 8.2. The total metal content of the uncontaminated soils ranged from 3.8 to 93.8 mg Cu kg -1 , 10.3 to 95 mg kg -1 Zn, 0.1 to 1.8 mg Cd kg -1 and 5.2 to 183 mg kg -1 Pb, while metal content in the contaminated soils ranged from 104 to 6841 mg Cu kg -1 , 312 to 39,000 mg kg -1 Zn, 6 to 302 mg Cd kg -1 and 609 to 12,000 mg kg -1 Pb. Our analysis of pore-water found the Cu concentrations to be much higher in contaminated soils than in uncontaminated soils, with the distribution coefficients (K d ) correlating significantly with the log of dissolved organic carbon concentrations. Despite the high total metal content of the contaminated soil, Zn, Cd and Pb were not generally found at elevated levels in the pore-water with the exception of a single contaminated soil. A long period of ageing and soil weathering may have led to a substantial reduction in heavy metal concentrations in the pore-water of contaminated soils. On the other hand, Pb bioaccessibility was found to be comparatively high in Pb contaminated soils, where it tended to exceed the total Pb values by more than 80%. We conclude that, despite the extensive ageing of some contaminated soils, the bioaccessibility of Pb remains relatively high.

  17. DETERMINAÇÃO DE METAIS PESADOS EM LEITE INTEGRAL BOVINO PASTEURIZADO NO ESTADO DE GOIÁS DETERMINING HEAVY METALS IN PASTEURIZED WHOLE BOVINE MILK IN STATE OF GOIÁS

    Directory of Open Access Journals (Sweden)

    José Rubens Gonçalves

    2008-07-01

    Full Text Available

    Os teores de chumbo, cádmio, zinco, cobre e ferro em leite integral bovino pasteurizado produzidos nos meses de setembro de 2003 a dezembro de 2004, nas mesorregiões do Estado de Goiás, foram determinados utilizando espectrofotometria de absorção atômica com chama. Adotando-se o critério estabelecido no anuário estatístico do Estado de Goiás, da Secretaria do Planejamento (ANUALPEC, 2005, que dividiu o Estado de Goiás em cinco mesorregiões, foram colhidas 27 amostras de leite integral pasteurizado em cada mesorregião, com um total de 135 amostras, e 675 determinações analíticas para os cinco microelementos analisados. Seguiu-se o modelo estatístico de amostragem por conglomerados (SPIEGEL, 1978. As amostras obtidas em embalagens plásticas de polietileno pigmentado foram processadas. Após a avaliação da amostra, separaram-se aquelas que estavam de acordo com os padrões físico-químicos e procedeu-se à determinação dos metais pesados, conforme metodologia oficial (BRASIL, 1994. Quanto aos teores de cádmio e chumbo, o limite máximo de resíduos aceitos pelo MERCOSUL é 0,05 mg/L. Todavia não foram encontradas diferenças significativas a 5 % de probabilidade, entre as médias dos teores de chumbo, cádmio, zinco e cobre no leite integral entre as mesorregiões. A média geral obtida para chumbo foi de 0,238 mg/L, superior ao limite máximo de resíduos, para o cádmio foi de 0,0482 mg/L, para o zinco foi de 3,732 mg/L, para o cobre foi de 0,4869 mg/L e para o ferro foi de 0,9626 mg/L. Tendo em vista os resultados médios obtidos no presente estudo, depreende-se que o leite analisado foi considerado uma fonte pobre em zinco, cobre e ferro.

     

    Palavras-Chave: Espectrofotometria de absorção atômica, Chumbo, microelementos.

    The lead texts, cadmium, zinc, copper and iron in pasteurized integral bovine milk produced in the months of September of

  18. Evaluation of the risk for heavy metals and dioxin from the incineration plant of urban solid wastes; Evaluacion del riesgo por exposicion a metales pesados y dioxinas emitidos por una planta incineradora de RSU

    Energy Technology Data Exchange (ETDEWEB)

    Domingo, J.L.; Schuhmacher, M.

    1997-12-31

    Public fear of dioxin and cancer has heightened the controversy surrounding municipal solid waste (MSW) incinerators. Concern about MSW incineration has focused especial attention on the emissions of dioxins together with metals, as potential sources of human exposure to these toxics. This paper provides data on the assessment of the human health risks for the population living in the neighbourhood of a modern MSW incinerator. Results show that food is the major source of human exposure to metals and dioxin, while MSW incineration is not a principal source of human exposure. The authors conclude suggesting that studies on the background levels of metals and dioxin in the vicinity of new MSW incinerators are essentials. (Author) 7 refs.

  19. Absorção de metais pesados do lodo de esgoto pelo feijoeiro (Phaseolus vulgaris L. Heavy Metal Uptake Of The Sewage Sludge By Bean Plants(Phaseolus vulgaris L.

    Directory of Open Access Journals (Sweden)

    Mário Miyazawa

    1998-06-01

    Full Text Available Toxicity and uptake of heavy metals of sewage sludge by beans (Phaseolus vulgaris L. were evaluated in green house experiments. Treatments consisted of 1,0 ; 2,0 and 5,0% (m/m of dry sewage sludge, collected from Londrina (Bom Retiro and ETE-Sul and Curitiba (ETE-Belém and RALF. Bean ( variety IAPAR 57 was sown three times at 0, 120 and 240 days after the treatments have been applied. Contents of Cd, Cr, Co, Cu, Ni, and Pb in bean tissues cultivated with 5,0% (m/m of all sewage sludge were similar to the control and Ba contents were reduced by increasing the quantity of sewage sludge in the soil. The Zn content in tissue bean incresed from 86 mg kg-1 of control to 462 mg kg-1 by applying 5% (m/m of sewage sludge in soil, but plant beans did not show toxicity symptons. The addition of 5% (m/m of sewage sludge increased Mn content in plants, from 193 mg kg-1 of control to 1.960 mg kg-1, showing toxity in bean leaves when the contents were more than 500 mg kg-1. The addition of sewage sludges in soils increased only available Zn carbonate and Cu organic species.

  20. The Investigation of Heavy Metal Content (Cu, Cd, Pb in Sapu-Sapu Fish (Hypostomus plecostomus in Bengawan Solo River

    Directory of Open Access Journals (Sweden)

    Ristiyana Eko Setyarini

    2016-12-01

    Full Text Available A study had been carried out to investigate heavy metal (Cu, Cd, Pb content in sapu-sapu fish (hypostomus plecostomus in Bengawan Solo river. The type of this research was observational research, with sapu-sapu fish inhabit Bengawan Solo River as the population. The samples were taken with purposive random sampling. Nine sapu-sapu fishes taken from 3 places, i.e.: Nguter Sukoharjo area, Premulung river outlet and Anyar river, 3 fishes from each palce, and then take examined the content of heavy metal. The result of study showed that the average content of Cu: 0.027 mg/100gr, Cd: 0.005 mg/100gr and Pb: 0.042 mg/100gr. Hence, sapu-sapu fish in Be3ngawan Solo had been contaminated with heavy metal (Cu, Cd, and Pb and should not be consumed.

  1. Evaluation of Diazatetraoxa Cryptand as Extractant for Transition Metals and Pb2+

    Directory of Open Access Journals (Sweden)

    Gülsev Dilber

    2014-12-01

    Full Text Available The extractability of metal cations such as Mn2+, Co2+, Cu2+, Zn2+ and Pb2+ from aqueous phase to organic phase with 19-nitro-6,7,15,16,23,24-hexahydro-13H,26H-14,25-propanotribenzo-[b,I,o][1,4,11,14,7,18]-tetraoxadiazacycloikocine was investigated by means of UV-vis spectrophotometer. The aqueous phase and the organic phase contained metal picrate and the ligands, respectively. Chloroform and dichloromethane were the organic solvents. The effect of pH on the percent extraction was evaluated between 2.0 and 5.5 for both organic solvents. The range at which high percent extraction of the ligand was obtained was between pH 5.0 to 5.5 for both solvents. The most effective transport was observed for Mn2+ with 84.69 % picrate among the tested metal picrates with dichloromethane at pH 5.5. The extraction constant values (log Kex were determined for extracted metal complexes at the most effective extraction pH.

  2. Contamination of soils by heavy metals. New Speciation from the kinetic aspect; La contaminacion de los suelos por metales pesados. Una nueva aproximacion a la especiacion desde el punto de vista cenitico

    Energy Technology Data Exchange (ETDEWEB)

    Garcia-Morales, J. L.; Sales, D. [Universidad de Cadiz (Spain); Bermond, A. [Institut National Agronomique. Paris (France)

    1999-11-01

    Nowadays the public opinion is very sensitive with the problem associated to the heavy metals soil contamination. Environmental catastrophes like the events happened in Aznalcollar and its future effects have shown the serious problem associated to this form of contamination. The study of the different existent species of the metals, as well as its possible biodisponibility, is a section that the diverse authors in a very different way have approached. Often, when they are carried out chemical methods of especiacion, one does not keep in mind the dependence with the time that you/they have the extraction phenomenon. However, this parameter is probably strongly linked with the mobility or biodisponibility of the metals appearance in the soil. The present work applies the kinetic especiacion to the heavy metals present in a cultivation soil in which the agronomic sludge application of a wastewater treatment plant has been made. The results of the copper content of these soils in comparison with a reference parcel are presented. (Author) 20 refs.

  3. Lixiviation of heavy metals of hazardous industrial wastes by means of thermostatized columns and design of a pilot plant; Lixiviacion de metales pesados de residuos industriales peligrosos por medio de columnas termostatizadas y diseno de una planta piloto

    Energy Technology Data Exchange (ETDEWEB)

    Vite T, J.; Leon, C.C. de [ININ, 52045 Ocoyoacac, Estado de Mexico (Mexico); Vite T, M.; Soto T, J.L. [IPN, SEPI, ESIME 07738 Mexico D.F. (Mexico)]. e-mail: jvite@nuclear.inin.mx

    2006-07-01

    purpose of this work was to evaluate the efficiency of lixiviation of heavy metals, using thermostatized columns and hazardous industrial residual wastes: those by the volume with which are generated and its high toxicity, its represent a great problem for it treatment and disposition, in this work a diagram of a pilot plant for extraction of heavy metals is included. The process and equipment were patented in United States and in Mexico. For the development of this study four thermostated columns were used that were coupled. The waste were finely milled and suspended in an aqueous pulp adding of 10 - 40gL{sup -1} of mineral acid or sodium hydroxide until reaching an interval of pH of 2,5,7 and 10. Its were used of 4-10 gL{sup -1} of a reducer agent and of 0.3-1.5 g of a surfactant agent. In some cases with this method was possible to remove until 100% of heavy metals. It was used Plasma Emission Spectroscopy to determine the concentrations of the cations in the lixiviation liquors. For studying the metallic alloys the X-ray diffraction technique was used. (Author)

  4. Estudo da contaminação por mercurio e metais pesados em garimpo de ouro primario : o estudo de caso da região de Pilar de Goias e Guarinos, Goias

    OpenAIRE

    Paulo Valladares Soares

    1990-01-01

    Resumo: Este estudo coloca os principais conceitos da química aquática do mercúrio e caracteriza a contaminação antropogênica deste metal. proveniente do processo de beneficiamento das minerações de ouro primário em garimpos na região de Pilar de Goiás e Guarinos (GO). De forma complementar. são analisados os metais pesados de origem litogênica (Cd, Zn. Cu. As, Pb,) que são liberados para o sistema h1drico após o processo de extração e beneficiamento. Procurou-se verificar a influência de tod...

  5. Heavy Metals (Cu, Pb and Cd) in Water and Angel Fish (Chelmon rostractus) from Batam Coastal, Indonesia

    OpenAIRE

    Ismarti Ismarti; Ramses Ramses; Suheryanto Suheryanto; Fitrah Amelia

    2017-01-01

    Fish play an important role in human nutrition and therefore need to be carefully and routinely monitored to ensure that there are no high levels of heavy metals being transferred to human through their consumption. This study has been carried out to determine level of heavy metals (Cu, Pb, and Cd) in water and angel fish, Chelmon rostractus collected from coast of Batam. We report levels of Cu, Cd and Pb in water and angel fish from Coast Batam using Atomic Absorption Spectroscopy (AAS). Lev...

  6. Polluted soils with heavy metals. Stabilization by magnesium oxide. Ex-situ and in-situ testings; Suelos contaminados con metales pesados. Estabilizacion con oxido de magnesio. Ensayos ex situ-in situ

    Energy Technology Data Exchange (ETDEWEB)

    Cenoz, S.; Hernandez, J.; Gangutia, N.

    2004-07-01

    This work describes the use of Low-Grade MgO as a stabiliser agent for polluted soil reclaim. Low-Grade MgO may be an economically feasible alternative in the stabilisation of heavy metals from heavily contaminated soils. The effectiveness of Low-Grade MgO has been studied in three ex-situ stabilisation of heavily polluted soils contaminated by the flue-dust of pyrite roasting. LG-MgO provides an alkali reservoir guaranteeing long-term stabilisation without varying the pH conditions. The success of the ex-situ stabilisation was corroborated with the analysis of heavy metals in the leachates collected from the landfill o ver a long period of time. The study also includes the results obtained in an in-situ pilot scale stabilisation of contaminated soil. (Author) 17 refs.

  7. Synthesis of LTA zeolite on corundum supports: Preliminary assessment for heavy metal removal from waste water; Sintesis de zeolita LTA sobre soportes de corindon: Evaluacion preliminar para la eliminacion de metales pesados de efluentes acuosos

    Energy Technology Data Exchange (ETDEWEB)

    Jacas, A.; Ortega, P.; Velasco, M. J.; Camblor, M. A.; Rodriguez, M. A.

    2012-11-01

    The effectiveness of materials based on LTA Zeolite as active phase, for their incorporation into systems aimed at the removal of heavy metals on waste water is evaluated in a preliminary way. This type of Zeolite with the main channel of a minimum free diameter of 0,41 nm and a low SiO{sub 2}/Al{sub 2}O{sub 3} ratio is an interesting molecular sieve, which in turn display a high ion exchange capacity. From this point of view, LTA Zeolite crystals were obtained in situ by hydrothermal synthesis and characterized by x ray diffraction (XRD) and scanning electron microscopy (SEM). We have studied the effect of hydrothermal synthesis time at 378 K. Likewise, the removal capacity of heavy metal from the active phase was evaluated in as a first step on diluted solutions of cooper salts at slightly acidic pH ({approx} 4,7). (Author) 28 refs.

  8. Influence of amendments and aided phytostabilization on metal availability and mobility in Pb/Zn mine tailings.

    Science.gov (United States)

    Lee, Sang-Hwan; Ji, WonHyun; Lee, Won-Seok; Koo, Namin; Koh, Il Ha; Kim, Min-Suk; Park, Jeong-Sik

    2014-06-15

    A greenhouse experiment was conducted to evaluate the effect of four different amendments, bone mill, bottom ash, furnace slag, and red mud, as immobilizing agents and the plant species Miscanthus sinensis and Pteridium aquilinum in aided phytostabilization of Pb/Zn mine tailings. The effects of amendments and plants on the availability and mobility of heavy metals were evaluated using single extraction, sequential extraction, pore-water analysis, and determination of heavy metal concentrations in plants. The application of Fe-rich amendments significantly reduced the amount of soluble and extractable heavy metals in the tailings (p aquilinum treatment was the most effective at decreasing bioaccessible Pb, reducing it to 34% of the total Pb. Compared to control, water soluble Cd, Cu, Pb, and Zn were reduced by 99, 99, 98, and 99%, respectively, in the red mud and P. aquilinum tailings. M. sinensis accumulated heavy metals mainly in the root, and had lower translocation factors compared with P. aquilinum. The results of this study suggest that M. sinensis can be used in aided phytostabilization for these types of mine tailings and Fe-rich amendments are effective for the in situ immobilization of metals. Copyright © 2014 Elsevier Ltd. All rights reserved.

  9. Heavy metal content (Cd, Ni, Cr and Pb) in soil amendment with a low polluted biosolid

    Science.gov (United States)

    Gomez Lucas, Ignacio; Lag Brotons, Alfonso; Navarro-Pedreño, Jose; Belén Almendro-Candel, Maria; Jordán, Manuel M.; Bech, Jaume; Roca, Nuria

    2016-04-01

    The progressively higher water quality standards in Europe has led to the generation of large quantities of sewage sludge derived from wastewater treatment (Fytili and Zabaniotou 2008). Composting is an effective method to minimize these risks, as pathogens are biodegraded and heavy metals are stabilized as a result of organic matter transformations (Barker and Bryson 2002; Noble and Roberts 2004). Most of the studies about sewage sludge pollution are centred in medium and high polluted wastes. However, the aim of this study was to assess the effects on soil heavy metal content of a low polluted sewage sludge compost in order to identify an optimal application rate based in heavy metal concentration under a period of cultivation of a Mediterranean horticultural plant (Cynara carducnculus). The experiment was done between January to June: rainfall was 71 mm, the volume of water supplied every week was 10.5 mm, mean air temperatures was 14.2, 20.4 (maximum), and 9.2◦C (minimum). The soil was a clay-loam anthrosol (WRB 2006). The experimental plot (60 m2) was divided into five subplots with five treatments corresponding to 0, 2, 4, 6, and 8 kg compost/m2. Three top-soil (first 20 cm) samples from each treatment were taken (January, April and June) and these parameters were analysed: pH, electrical conductivity, organic matter and total content of heavy metals (microwave acid digestion followed by AAS-spectrometry determination). The results show that sewage sludge compost treatments increase the organic matter content and salinity (electrical conductivity of the soils) and diminish the pH. Cd and Ni total content in top-soil was affected and both slightly reduce their concentration. Pb and Cr show minor changes. In general, the application of this low polluted compost may affect the mobility of Cd and Ni due to the pH modification and the water added by irrigation along time but Pb and Cr remain their content in the top-soil. References Barker, A.V., and G.M. Bryson

  10. Behavior of Paramecium sp. in solutions containing Sr and Pb: Do Paramecium sp. alter chemical forms of those metals?

    Science.gov (United States)

    Kozai, Naofumi; Ohnuki, Toshihiko; Koka, Masahi; Satoh, Takahiro; Kamiya, Tomihiro

    2011-10-01

    The behavior of Paramecium sp. (Paramecium bursaria) in aqueous solutions containing Sr and Pb was investigated to determine the role of protozoa in the migration of radionuclides in the environment. Precultured living cells of P. bursaria were exposed to aqueous solutions containing 0.01 or 0.05 mM Sr or Pb at pH 7 for 24 h. For comparison, pre-killed cells were treated with the metal solutions in the same way. Two-dimensional elemental mappings of cells were obtained by micro-PIXE. Aquatic species of Sr and Pb were analyzed by size exclusion chromatography (SEC) coupled online to ultraviolet (UV) spectroscopy and inductivity coupled plasma mass spectroscopy (ICP-MS). The amounts of Sr adsorbed or taken up by the cells surviving for 24 h and adsorbed on pre-killed cells were below the detection limit. Cells of P. bursaria adsorbed or took up a fraction of Pb. The Pb adsorbed or taken up by the cells surviving for 24 h in the Pb solution was barely detectable, while the Pb adsorbed on pre-killed cells was clearly mappable. These findings suggest that living cells of P. bursaria have functions that reduce adsorption or uptake of Pb on the cells. Quantitative and SEC-UV-ICP-MS analyses of the Sr and Pb in aqueous phases showed no clear evidences that living cells of P. bursaria alter the chemical form of Sr or Pb remaining in the aqueous phases after the cell-solution contact.

  11. Behavior of Paramecium sp. in solutions containing Sr and Pb: Do Paramecium sp. alter chemical forms of those metals?

    International Nuclear Information System (INIS)

    Kozai, Naofumi; Ohnuki, Toshihiko; Koka, Masahi; Satoh, Takahiro; Kamiya, Tomihiro

    2011-01-01

    The behavior of Paramecium sp. (Paramecium bursaria) in aqueous solutions containing Sr and Pb was investigated to determine the role of protozoa in the migration of radionuclides in the environment. Precultured living cells of P. bursaria were exposed to aqueous solutions containing 0.01 or 0.05 mM Sr or Pb at pH 7 for 24 h. For comparison, pre-killed cells were treated with the metal solutions in the same way. Two-dimensional elemental mappings of cells were obtained by micro-PIXE. Aquatic species of Sr and Pb were analyzed by size exclusion chromatography (SEC) coupled online to ultraviolet (UV) spectroscopy and inductivity coupled plasma mass spectroscopy (ICP-MS). The amounts of Sr adsorbed or taken up by the cells surviving for 24 h and adsorbed on pre-killed cells were below the detection limit. Cells of P. bursaria adsorbed or took up a fraction of Pb. The Pb adsorbed or taken up by the cells surviving for 24 h in the Pb solution was barely detectable, while the Pb adsorbed on pre-killed cells was clearly mappable. These findings suggest that living cells of P. bursaria have functions that reduce adsorption or uptake of Pb on the cells. Quantitative and SEC-UV-ICP-MS analyses of the Sr and Pb in aqueous phases showed no clear evidences that living cells of P. bursaria alter the chemical form of Sr or Pb remaining in the aqueous phases after the cell-solution contact.

  12. Behavior of Paramecium sp. in solutions containing Sr and Pb: Do Paramecium sp. alter chemical forms of those metals?

    Energy Technology Data Exchange (ETDEWEB)

    Kozai, Naofumi, E-mail: kozai.naofumi@jaea.go.jp [Advanced Sciences Research Center, Japan Atomic Energy Agency (JAEA), Tokai, Ibaraki 319-1195 (Japan); Ohnuki, Toshihiko [Advanced Sciences Research Center, Japan Atomic Energy Agency (JAEA), Tokai, Ibaraki 319-1195 (Japan); Koka, Masahi; Satoh, Takahiro; Kamiya, Tomihiro [Takasaki Advanced Radiation Research Institute, JAEA, 1233 Watanuki-machi, Takasaki, Gunma 370-1292 (Japan)

    2011-10-15

    The behavior of Paramecium sp. (Paramecium bursaria) in aqueous solutions containing Sr and Pb was investigated to determine the role of protozoa in the migration of radionuclides in the environment. Precultured living cells of P. bursaria were exposed to aqueous solutions containing 0.01 or 0.05 mM Sr or Pb at pH 7 for 24 h. For comparison, pre-killed cells were treated with the metal solutions in the same way. Two-dimensional elemental mappings of cells were obtained by micro-PIXE. Aquatic species of Sr and Pb were analyzed by size exclusion chromatography (SEC) coupled online to ultraviolet (UV) spectroscopy and inductivity coupled plasma mass spectroscopy (ICP-MS). The amounts of Sr adsorbed or taken up by the cells surviving for 24 h and adsorbed on pre-killed cells were below the detection limit. Cells of P. bursaria adsorbed or took up a fraction of Pb. The Pb adsorbed or taken up by the cells surviving for 24 h in the Pb solution was barely detectable, while the Pb adsorbed on pre-killed cells was clearly mappable. These findings suggest that living cells of P. bursaria have functions that reduce adsorption or uptake of Pb on the cells. Quantitative and SEC-UV-ICP-MS analyses of the Sr and Pb in aqueous phases showed no clear evidences that living cells of P. bursaria alter the chemical form of Sr or Pb remaining in the aqueous phases after the cell-solution contact.

  13. Electrochemiluminescent immunosensing of prostate-specific antigen based on silver nanoparticles-doped Pb (II) metal-organic framework.

    Science.gov (United States)

    Ma, Hongmin; Li, Xiaojian; Yan, Tao; Li, Yan; Zhang, Yong; Wu, Dan; Wei, Qin; Du, Bin

    2016-05-15

    In this work, silver nanoparticles-doped Pb (II) metal-organic framework (Ag-MOF) was prepared and exploited as a luminescence probe for the development of label-free electrochemiluminescence (ECL) immunosensing scheme for prostate-specific antigen (PSA). The β-cyclodextrin based MOF, Pb-β-cyclodextrin (Pb(II)-β-CD) shows excellent ECL behavior and unexpected reducing capacity towards silver ions. Silver nanoparticles could massively form on the surface of Pb(II)-β-CD (Ag@Pb(II)-β-CD) without use any additional reducing agent, while the ECL behavior of Pb(II)-β-CD still was well retained. The Ag@Pb(II)-β-CD was used as a substrate material to modify glass carbon electrodes and formed a sensing platform for the fabricating ECL immunosensor. The presence of silver nanoparticles enables the facile immobilization of capturing antibody of PSA. The specific binding of PSA onto the electrode surface induces the decrease of ECL signals. A linear range of 0.001-50 ng mL(-1) with a detection limit of 0.34 pg mL(-1) (S/N=3) was obtained after the optimization of experimental conditions. This simply fabricated immunosensor exhibits good stability, accuracy and acceptable reproducibility, which suggesting its potential applications in clinical diagnostics. Copyright © 2015 Elsevier B.V. All rights reserved.

  14. Metal Halide Perovskite Supercrystals: Gold-Bromide Complex Triggered Assembly of CsPbBr3 Nanocubes.

    Science.gov (United States)

    Wang, Kun-Hua; Yang, Jun-Nan; Ni, Qian-Kun; Yao, Hong-Bin; Yu, Shu-Hong

    2018-01-16

    Using nanocrystals as "artificial atoms" to construct supercrystals is an interesting process to explore the stacking style of nanoscale building blocks and corresponding collective properties. Various types of semiconducting supercrystals have been constructed via the assembly of nanocrystals driven by the entropic, electrostatic, or van der Waals interactions. We report a new type of metal halide perovskite supercrystals via the gold-bromide complex triggered assembly of newly emerged attractive CsPbBr 3 nanocubes. Through introducing gold-bromide (Au-Br) complexes into CsPbBr 3 nanocubes suspension, the self-assembly process of CsPbBr 3 nanocubes to form supercrystals was investigated with the different amount of Au-Br complexes added to the suspensions, which indicates that the driven force of the formation of CsPbBr 3 supercrystals included the van der Waals interactions among carbon chains and electrostatic interactions between Au-Br complexes and surfactants. Accordingly, the optical properties change with the assembly of CsPbBr 3 nanocubes and the variation of mesoscale structures of supercrystals with heating treatment was revealed as well, demonstrating the ionic characteristics of CsPbBr 3 nanocrystals. The fabricated CsPbBr 3 supercrystal presents a novel type of semiconducting supercrystals that will open an avenue for the assembly of ionic nanocrystals.

  15. Geochemical and Pb isotopic evidence for sources and dispersal of metal contamination in stream sediments from the mining and smelting district of Pribram, Czech Republic

    International Nuclear Information System (INIS)

    Ettler, Vojtech; Mihaljevic, Martin; Sebek, Ondrej; Molek, Michael; Grygar, Tomas; Zeman, Josef

    2006-01-01

    Stream sediments from the mining and smelting district of Pribram, Czech Republic, were studied to determine the degree, sources and dispersal of metal contamination using a combination of bulk metal and mineralogical determinations, sequential extractions and Pb isotopic analyses. The highest metal concentrations were found 3-4 km downstream from the main polymetallic mining site (9800 mg Pb kg -1 , 26 039 mg Zn kg -1 , 316.4 mg Cd kg -1 , 256.9 mg Cu kg -1 ). The calculated enrichment factors (EFs) confirmed the extreme degree of contamination by Pb, Zn and Cd (EF > 40). Lead, Zn and Cd are bound mainly to Fe oxides and hydroxides. In the most contaminated samples Pb is also present as Pb carbonates and litharge (PbO). Lead isotopic analysis indicates that the predominant source of stream sediment contamination is historic Pb-Ag mining and primary Pb smelting ( 206 Pb/ 207 Pb = 1.16), while the role of secondary smelting (car battery processing) is negligible. - Pb isotopes properly complete traditional investigations of metal sources and dispersal in contaminated stream sediments

  16. Study of Brasgel clay looking at its use in the removal of heavy metal zinc in analytical effluents; Estudo da argila Brasgel visando sua utilizacao na remocao do metal pesado zinco em efluentes analiticos

    Energy Technology Data Exchange (ETDEWEB)

    Patricio, A.C.L.; Silva, M.M. da; Lima, W.S.; Cartaxo, J. de M.; Rodrigues, M.G.F., E-mail: cadigena@hotmail.com [Universidade Federal de Campina Grande (UFCG), PB (Brazil). Unidade Academica de Engenharia Quimica. Centro de Ciencias e Tecnologia

    2011-07-01

    This work aims to characterize the clay Brasgel in its natural form and after its organophilization through salt distearyl dimethyl chloride (Praepagen) and then evaluate the potential of clay in the process of treating wastewater contaminated by heavy metal zinc. After the treatment technique, specimens in natural form and organoclay were characterized by techniques of X-ray diffraction (XRD), infrared spectroscopy (IR), moreover, was the analysis of the behavior of organoclay in certain organic solvents through the swelling of Foster. In this work we adopted the procedure for removal of Zn{sup +2} present in aqueous solutions, based on a factorial design, 2{sup 2} + 3 repetitions at the central point, with the analysis parameters as the solution pH (3.0 to 5.0) and initial concentration of zinc ranging from 10 to 50 ppm. (author)

  17. Sobrevivência de Bradyrhizobium e Azorhizobium em misturas de solo contaminadas com metais pesados

    Directory of Open Access Journals (Sweden)

    A. Matsuda

    2002-03-01

    Full Text Available Estudos foram realizados no Departamento de Ciência do Solo da Universidade Federal de Lavras (MG, no período de novembro/1999 a janeiro/2000, com o objetivo de avaliar a sobrevivência de estirpe e isolados de rizóbio em solo contaminado com metais pesados e verificar a relação entre tolerância do rizóbio a metais pesados em meio de cultura e sua sobrevivência em solo contaminado. Foram utilizados os dois microrganismos mais tolerantes [BR-4406 (estirpe recomendada para Enterolobium spp. e UFLA-01-457 (isolado de solo contaminado, ambos pertencentes ao gênero Bradyrhizobium ] e os dois mais sensíveis (UFLA-01-486 e UFLA-01-510, isolados de solo contaminado, pertencentes ao gênero Azorhizobium , todos selecionados de um grupo de 60estirpes/isolados em estudos prévios deste laboratório, em meio de cultura suplementado com metais pesados.Empregaram-se misturas de um Latossolo Vermelho-Escuro (LE que continham 0, 15 e 45% (v/v de um Latossolo Vermelho-Amarelo plíntico contaminado com Zn, Cd, Pb e Cu. As misturas de solo contaminado foram inoculadas com 20mL de cultura em YM na fase log das estirpes mencionadas, as quais foram testadas separadamente com três repetições. A avaliação do número de células viáveis no solo, realizada aos 0, 7, 14, 21 e 28dias de incubação, pelo método das diluições sucessivas e inoculação em placas com meio YMA, revelou comportamento diferenciado entre os organismos estudados. O número médio de células que sobreviveram ao final de 28 dias de incubação foi de (em UFCg-1de solo: 10(10,36, 10(10,29 e 10(9,70, para Bradyrhizobium, e 10(9,36, 10(7,54 e 0, para Azorhizobium em misturas de 0, 15 e 45% de solo contaminado, respectivamente. Portanto, houve maior sobrevivência de Bradyrhizobium do que de Azorhizobium , indicando maior tolerância a metais pesados do primeiro gênero.Como Bradyrhizobium foi também mais tolerante "in vitro", os resultados indicam haver relação entre o

  18. Interactions of core–shell quantum dots with metal resistant bacterium Cupriavidus metallidurans: Consequences for Cu and Pb removal

    International Nuclear Information System (INIS)

    Slaveykova, Vera I.; Pinheiro, José Paulo; Floriani, Magali; Garcia, Miguel

    2013-01-01

    Highlights: • QDs associate with C. metallidurans in time and concentration dependent manner. • 12.9 nm size QDs adhere to the bacterial surface and enter the periplasmic space. • QDs bound significantly Cu and Pb. • QDs increase Cu and Pb content in C. metallidurans during short term exposure. -- Abstract: In the present study we address the interactions of carboxyl-CdSe/ZnS core/shell quantum dots (QDs), as a model of water dispersible engineered nanoparticles, and metal resistant bacteria Cupriavidus metallidurans, largely used in metal decontamination. The results demonstrate that QDs with average hydrodynamic size of 12.9 nm adhere to C. metallidurans. The percentage of bacterial cells displaying QD-fluorescence increased proportionally with contact time and QD concentration in bacterial medium demonstrating the association of QDs with the metal resistant bacteria. No evidence of QD internalization into bacterial cytoplasm was found by transmission electron microscopy with energy dispersive X-ray spectrometry, however QD clusters of sizes between 20 and 50 nm were observed on the bacterial surface and in the bacterial periplasmic compartment; observations consistent with the losses of membrane integrity induced by QDs. The presence of 20 nM QDs induced about 2-fold increase in Cu and Pb uptake fluxes by C. metallidurans exposed to 500 nM Pb or Cu, respectively. Overall, the results of this work suggest that when present in mixture with Cu and Pb, low levels of QDs originating from possible incidental release or QD disposal could increase metal accumulation in metal resistant bacterium

  19. Interactions of core–shell quantum dots with metal resistant bacterium Cupriavidus metallidurans: Consequences for Cu and Pb removal

    Energy Technology Data Exchange (ETDEWEB)

    Slaveykova, Vera I., E-mail: vera.slaveykova@unige.ch [Environmental Biogeochemistry and Ecotoxicology, Institute F.-A. Forel, Earth and Environment Science, Faculty of Sciences, University of Geneva, 10, route de Suisse, 1290 Versoix (Switzerland); Pinheiro, José Paulo [IBB/CBME, Department of Chemistry and Biochemistry, University of the Algarve, Gambelas Campus, 8005-139 Faro (Portugal); Floriani, Magali [IRSN/DEI/SECRE/LRE CEA Cadarache, 13115 Saint-Paul-Lez-Durance (France); Garcia, Miguel [School of Life Sciences, Swiss Federal Institute of Technology (EPFL), Station 15, CH-1015 Lausanne (Switzerland)

    2013-10-15

    Highlights: • QDs associate with C. metallidurans in time and concentration dependent manner. • 12.9 nm size QDs adhere to the bacterial surface and enter the periplasmic space. • QDs bound significantly Cu and Pb. • QDs increase Cu and Pb content in C. metallidurans during short term exposure. -- Abstract: In the present study we address the interactions of carboxyl-CdSe/ZnS core/shell quantum dots (QDs), as a model of water dispersible engineered nanoparticles, and metal resistant bacteria Cupriavidus metallidurans, largely used in metal decontamination. The results demonstrate that QDs with average hydrodynamic size of 12.9 nm adhere to C. metallidurans. The percentage of bacterial cells displaying QD-fluorescence increased proportionally with contact time and QD concentration in bacterial medium demonstrating the association of QDs with the metal resistant bacteria. No evidence of QD internalization into bacterial cytoplasm was found by transmission electron microscopy with energy dispersive X-ray spectrometry, however QD clusters of sizes between 20 and 50 nm were observed on the bacterial surface and in the bacterial periplasmic compartment; observations consistent with the losses of membrane integrity induced by QDs. The presence of 20 nM QDs induced about 2-fold increase in Cu and Pb uptake fluxes by C. metallidurans exposed to 500 nM Pb or Cu, respectively. Overall, the results of this work suggest that when present in mixture with Cu and Pb, low levels of QDs originating from possible incidental release or QD disposal could increase metal accumulation in metal resistant bacterium.

  20. Preliminary tests for Salix sp. tolerance to heavy metals (Cd, Ni, Pb)

    Science.gov (United States)

    Corneanu, Mihaela; Hernea, Cornelia; Butnariu, Monica; Corneanu, Gabriel; Sărac, Ioan; Hollerbach, Wilhelm; Neţoiu, Constantin; Petcov, Andreea Adriana

    2014-05-01

    spectrometry). The analysis of variance proved the significant role of the genotype in all analyzed features. The percent of shooting was significant higher in Salix alba (81.90 - 96.26%) in comparison with Salix viminalis (50.43 - 62.67%). The best results for all treatment variants were registered in hybrid 892. Clone 202, hybrid 892 and Inger are sensitive to highest concentration of lead (450.0 ppm) and tolerant to all other treatment variants, while Gudrun is sensitive to Ni, but all the concentrations of Cd and Pb presented a stimulative effect on shoots development. The content of heavy metals in plant was also dependent by the organ (root or shoot) and by the genotype.

  1. Metal arsonate polymers of Cd, Zn, Ag and Pb supported by 4-aminophenylarsonic acid

    Energy Technology Data Exchange (ETDEWEB)

    Lesikar-Parrish, Leslie A.; Neilson, Robert H. [Department of Chemistry, Texas Christian University, Box 298860, Fort Worth, TX 76129 (United States); Richards, Anne F., E-mail: a.richards@latrobe.edu.au [Department of Chemistry, La Trobe Institute for Molecular Sciences, La Trobe University, Melbourne, Victoria 3086 (Australia)

    2013-02-15

    The coordination preferences of 4-aminophenylarsonic acid, 4-NH{sub 2}C{sub 6}H{sub 4}AsO{sub 3}H{sub 2}, (p-arsanilic acid) with CdCl{sub 2}{center_dot}2.5H{sub 2}O, ZnCl{sub 2}, Ag(SO{sub 3}CF{sub 3}) and Pb(NO{sub 3}){sub 2} have been investigated affording five new metal arsonate polymers. The reaction between 4-aminophenylarsonic acid and CdCl{sub 2}{center_dot}2.5H{sub 2}O resulted in a one-dimensional polymer, [{l_brace}Cd(4-NH{sub 3}C{sub 6}H{sub 4}AsO{sub 3}H)(Cl){sub 2}{r_brace}(H{sub 2}O){sub 2}]{sub n}, 1, in which the polymeric chain is propagated by bridging chlorides. Exchange of CdCl{sub 2} for ZnCl{sub 2} afforded [{l_brace}Zn{sub 2}(4-NH{sub 3}C{sub 6}H{sub 4}AsO{sub 3})(Cl){sub 2}{r_brace}(H{sub 2}O){sub 2}(Cl)]{sub n}, 2, featuring interlinked 6- and 8-membered [Zn-O-As] ring systems. The reaction of Ag(SO{sub 3}CF{sub 3}) with 4-aminophenylarsonic acid, afforded polymeric 3, [Ag(4-NH{sub 2}C{sub 6}H{sub 4}AsO{sub 3}H)(4-NH{sub 2}C{sub 6}H{sub 4}AsO{sub 3}H{sub 2})]{sub n} where coordination of the amino group to the silver center is observed and [{l_brace}Ag{sub 2}(4-NH{sub 3}C{sub 6}H{sub 4}AsO{sub 3}H)(4-NH{sub 3}C{sub 6}H{sub 4}AsO{sub 3})({mu}2-SO{sub 3}CF{sub 3}){sub 2}{r_brace}(SO{sub 3}CF{sub 3}){sub 2}]{sub n}, 4. By comparison, the reaction of p-arsanilic acid with Pb(NO{sub 3}){sub 2} yielded a polymeric chain [Pb(4-NH{sub 3}C{sub 6}H{sub 4}AsO{sub 3}H)(NO{sub 3}){sub 2}]{sub n}, 5 of similar topology to 1. The structures of 1-5 have been indiscriminately characterized by single crystal X-ray diffraction and their composition supported by relevant spectroscopic techniques. A comparison of the structural features of these polymers is used to determine the coordination preference of the ligand and factors influencing structural motifs, for example, the role of the anion. - Graphical abstract: The reaction of 4-aminophenylarsonic acid, 4-NH{sub 2}C{sub 6}H{sub 4}AsO{sub 3}H{sub 2}, with cadmium, zinc, silver, and lead have resulted in

  2. Application of clay minerals from Cayo Guan, Cuba, as sorbents of heavy metals and ceramic raw materials; Aplicaciones de los minerales arcillosos de Cayo Guan, Cuba, como adsorbentes de metales pesados y materia prima ceramica

    Energy Technology Data Exchange (ETDEWEB)

    Fonseca, D.; Barba, F.; Callejas, P.; Recio, P.

    2012-11-01

    It has been studied by Analysis Heating Microscope Optical the behaviour of some kaolinitic clays from a reservoir of Cayo Guan rich in iron oxides and low silica content proving to be a refractory materials whose softening appears after 1500 degree centigrade. It has obtained the workability diagram of the different clay minerals calculating the plasticity by the method of Casagrande spoon; only one of the samples is in the area suitable for extrusion. Vitrification diagrams report that the capacity of water absorption is <0.6 % when the temperature of 1400 degree centigrade is achieved. We have designed a program to calculate compositions of porcelain stoneware prepared from these modified clays adding low-cost raw materials that facilitate the formation of glassy phase ((potassium feldspar and glass cullet) and/or increase the silica (sand and diatomaceous earth used as filters in the brewing industry). With one of these compositions, prepared in the laboratory (60 % of clay, 30 % feldspar and 10 % of diatomaceous earth), calcined at 1250 degree centigrade with a heating rate of 15 degree centigrade/min, the results were: water absorption 0.8 %, and linear shrinkage 21 % without any deformation observed. These clays have been treated with acid to eliminate its high iron content and study its application as an sorbent of heavy metals as Cd{sup 2}+, Cr{sup 3}+. The results of the immobilization of these elements have been compared with those obtained with thermally activated vermiculite at 800 degree centigrade, showing that the treated samples show sorption of both cadmium and chromium below the vermiculite, but the non-treated ones are suitable to remove chromium; this is because these clays do not contain in its composition exchangeable ions (Ca{sup {sub 2}} +, Mg{sup 2} +, Na{sup +}, K{sup +}), and even if they are chemically activated only the presence of Fe ions is which produces form bindings (Cr{sub x}.Fe{sub 1}-x) (OH){sub 3} which favor Cr sorption

  3. Analysis of heavy metals (Pb and Zn) concentration in sediment of Blanakan fish ponds, Subang, West Java

    Science.gov (United States)

    Wiriawan, A.; Takarina, N. D.; Pin, T. G.

    2017-07-01

    Blanakan fish ponds receive water resource from Kali Malang and Blanakan rivers. Industrial and domestic activities along the river can cause pollution, especially heavy metals. Zinc (Zn) is an essential element that needed by an organism, while Lead (Pb) is a nonessential element that is not needed. Discharge of waste water from industries and anthropogenic activities continuously not only pollute the water but also the sediment and biota live on it. This research was aimed to know the heavy metals content in the sediment of Blanakan fish ponds. Sediment samples were taken on July and August 2016 at three locations. Heavy metals were analyzed using Atomic Absorption Spectrophotometry (AAS) Shimadzu 6300. The result of Lead (Pb) measurement showed that Fish Pond 1 had higher average concentration compared Fish Pond 2 and Fish Pond 3 which was 0.55 ppm. Standard for Lead (Pb) in sediment according to Ontario Sediment Standards (2008) is 31 ppm. Based on Zinc (Zn) measurement, it was known that average of Zinc (Zn) concentration also higher on Fish Pond 1 compared to Fish Pond 2 and 3 which was 1.93 ppm. According to Ontario Sediment Standards (2008), a standard for Zinc (Zn) in sediment is 120 ppm. This indicated that heavy metals in the sediment of fish ponds were below standards. Statistical analysis using t-test showed that there was no significant difference of heavy metals content among fish ponds.

  4. Dispersion, Speciation, and Pollution Assessment of Heavy Metals Pb and Zn in Surface Sediment from Disturbed Ecosystem of Jeneberang Waters

    Science.gov (United States)

    Najamuddin; Surahman

    2017-10-01

    Surface sediments were collected from seventeen stations in Jeneberang waters (riverine, estuarine, and marine). Lead (Pb) and zinc (Zn) concentrations were determined by atomic absorption spectrometry, and the speciation of metals was obtained by a sequential extraction procedure. Dispersion of Pb and Zn were found higher in the riverine and marine samples than the estuarine samples. Following speciation, the metals were found similar composition of fraction in the riverine and estuarine samples but any different in the marine samples. The results indicated that there is a change of dispersion pattern and speciation composition of metals due to the presence of the dam that lies at the boundary between the estuary and the river. The toxicity unit was indicated low toxicity level; pollution level was in weakly to moderately polluted while the aquatic environment risk attributed were no risky to light risk.

  5. Enhanced desorption of PCB and trace metal elements (Pb and Cu) from contaminated soils by saponin and EDDS mixed solution

    International Nuclear Information System (INIS)

    Cao, Menghua; Hu, Yuan; Sun, Qian; Wang, Linling; Chen, Jing; Lu, Xiaohua

    2013-01-01

    This study investigated the simultaneous desorption of trace metal elements and polychlorinated biphenyl (PCB) from mixed contaminated soil with a novel combination of biosurfactant saponin and biodegradable chelant S,S-ethylenediaminedisuccinic acid (EDDS). Results showed significant promotion and synergy on Pb, Cu and PCB desorption with the mixed solution of saponin and EDDS. The maximal desorption of Pb, Cu and PCB were achieved 99.8%, 85.7% and 45.7%, respectively, by addition of 10 mM EDDS and 3000 mg L −1 saponin. The marked interaction between EDDS and saponin contributed to the synergy performance. The sorption of EDDS and saponin on soil was inhibited by each other. EDDS could enhance the complexation of metals with the saponin micelles and the solubilization capabilities of saponin micelles for PCB. Our study suggests the combination of saponin and EDDS would be a promising alternative for remediation of co-contaminated soils caused by hydrophobic organic compounds (HOCs) and metals. -- Highlights: ► A novel combination of biosurfactant saponin and EDDS was used to simultaneously remove mixed contaminations from soil. ► Significant synergy on Pb, Cu and PCB desorption were achieved with EDDS/saponin. ► The marked interaction between EDDS and saponin contributed to the synergy performance. -- Significant synergistic effect on Pb, Cu and PCB desorption were achieved with the mixed solution of saponin and EDDS

  6. Compatibility between Co-Metallized PbTe Thermoelectric Legs and an Ag–Cu–In Brazing Alloy

    Science.gov (United States)

    Ben-Ayoun, Dana; Sadia, Yatir; Gelbstein, Yaniv

    2018-01-01

    In thermoelectric (TE) generators, maximizing the efficiency of conversion of direct heat to electricity requires the reduction of any thermal and electrical contact resistances between the TE legs and the metallic contacts. This requirement is especially challenging in the development of intermediate to high-temperature TE generators. PbTe-based TE materials are known to be highly efficient up to temperatures of around 500 °C; however, only a few practical TE generators based on these materials are currently commercially available. One reason for that is the insufficient bonding techniques between the TE legs and the hot-side metallic contacts. The current research is focused on the interaction between cobalt-metallized n-type 9.104 × 10−3 mol % PbI2-doped PbTe TE legs and the Ag0.32Cu0.43In0.25 brazing alloy, which is free of volatile species. Clear and fine interfaces without any noticeable formation of adverse brittle intermetallic compounds were observed following prolonged thermal treatment testing. Moreover, a reasonable electrical contact resistance of ~2.25 mΩmm2 was observed upon brazing at 600 °C, highlighting the potential of such contacts while developing practical PbTe-based TE generators. PMID:29320430

  7. Essential (Cu) and nonessential (Cd and Pb) metals in ichthyofauna from the coasts of Sinaloa state (SE Gulf of California).

    Science.gov (United States)

    Ruelas-Inzunza, J; Páez-Osuna, F; García-Flores, D

    2010-03-01

    With the aim of giving an overview on concentration and distribution of Cd, Cu, and Pb in fish from the coasts of Sinaloa state (SE Gulf of California), specimens with different feeding habits were collected in five locations. Sampling occurred between June 2003 and March 2004. Metal analyses on fish tissues were made by graphite furnace (Cd, Pb) and flame (Cu) atomic absorption spectrophotometry. Metal concentrations in tissues of carnivorous fish were grouped together and compared with corresponding concentrations in non-carnivorous fish; Cu and Pb levels were significantly (p < 0.05) higher in liver of non-carnivorous species. Though no samples exceeded the maximum level set in international legislation for fish, from the perspective of the public health and considering the legal limits of fishery products for human consumption, Cu concentrations were exceeded (in tissues different from muscle) in four carnivorous and five non-carnivorous species according to the Australian legislation. In the case of Cd, two carnivorous species (Pomadasys leuciscus and Caulolatilus princeps) and one non-carnivorous species (Mugil cephalus), showed concentrations over the maximum level of 2 microg g(-1) dry weight considered in the Mexican legislation. Considering average amounts of fish consumption in Mexico, daily mineral intake (DMI) values for Cu and percentage weekly intake (PWI) of Cd and Pb were estimated; none of the analyzed metals in edible portion of analyzed fish could be detrimental to humans.

  8. Pb and Hg heavy metal tolerance of single- and mixedspecies biofilm (Rhodotorula mucilaginosa and Escherichia coli

    Directory of Open Access Journals (Sweden)

    Buzejić Anica

    2016-01-01

    Full Text Available The aim of this study was to examine heavy metal tolerance (lead (Pb2+ and mercury (Hg2+ of single- and mixed-species biofilms, formed by yeast Rhodotorula mucilaginosa and bacteria Escherichia coli LM1. Single- and mixed-species biofilms were quantified by crystal violet test and the absorbance was measured using microplate reader (OD570. The minimal inhibitory concentration (MIC and the minimal lethal concentration (MLC were determined and the results were confirmed by fluorescence microscopy. The significant difference in lead tolerance was observed between the mixed- and the single-species biofilms. The MIC of lead (Pb2+ for the examined biofilms (E. coli LM1, R. mucilaginosa and R. mucilaginosa / E. coli was recorded at concentrations of 4000 μg/ml, 4000 μg/ml and 16000 μg/ml, respectively. The MIC of mercury (Hg2+ for the biofilms was noticed at concentrations of 31.25 μg/ml, 250 μg/ml and 250 μg/ml, respectively. Standard antibiotics (amphotericin B and tetracycline were used as positive control. Results obtained for single-species biofilms were compared in between and with the results obtained for mixed-species biofilm. The tolerance of the mixed- species biofilm was higher in comparison to the singlespecies biofilms and the results were confirmed by a fluoresecence microscope. The obtained results suggest that the R. mucilaginosa / E. coli biofilm may have a potential to be used in bioremediation of wastewaters contaminated with lead and mercury.

  9. BOTANICAL DIVERSITY AND HEAVY METAL CONTENT IN THE RESIDUE MATRIX AND PLANTS AT THE MORAVIA DUMP IN MEDELLÍN, COLOMBIA DIVERSIDAD BOTÁNICA Y CONTENIDO DE METALES PESADOS EN LA MATRIZ DE RESIDUOS Y LAS PLANTAS EN EL BASURERO DE MORAVIA EN MEDELLÍN, COLOMBIA

    OpenAIRE

    Maria Solange Sanchez Pinzón; Álvaro Cogollo Pacheco; Catalina Arroyave Quiceno; Rubén Darío Torrenegra Guerrero; Ángel Maria Giraldo Mejía; Rolando Barahona Rosales

    2010-01-01

    . Floristic characterization, plant tissue and residue matrix (RM) analysis were conducted to establish the extent of heavy metal (HM) pollution of the Moravia dump at Medellín, Colombia, a site that was inhabited by more than 17000 people since 1984. More than 65 plant species (28 families) were identified, most of which were herbaceous. Content of HM in the (RM) was determined in 14 different RM samples varied greatly among them, reaching 121 and 9600 mg/kg of Hg and Pb respectively. Mean c...

  10. Metais pesados, densidade e atividade microbiana em solo contaminado por rejeitos de indústria de zinco

    Directory of Open Access Journals (Sweden)

    H. E. Dias-Júnior

    1998-12-01

    Full Text Available As atividades relacionadas com mineração e indústria metalúrgica são responsáveis pela poluição de extensas áreas de solo em todo o mundo, sendo seus efeitos ainda pouco conhecidos nas condições brasileiras. No presente trabalho, os teores totais e solúveis em água de metais pesados, a densidade e a atividade microbiana foram avaliados em 1996, em sete locais de uma área de deposição de rejeitos da industrialização de zinco, em elevado estádio de degradação, e num local fora da área contaminada, considerado como referência, no estado de Minas Gerais. Todos os locais contaminados apresentaram elevados teores de metais pesados totais e solúveis em água, atingindo, respectivamente, os seguintes valores máximos, em mg kg-1: 11.969 e 726 de Zn; 109 e 18 de Cd; 1.016 e 0 de Pb e 887 e 8 de Cu. Todas as características biológicas avaliadas foram afetadas pelos elevados teores de metais com exceção do número de amonificadores. O C-biomassa apresentou redução acima de 80% em quatro locais contaminados em relação ao local fora da área contaminada. A respiração basal do solo foi maior no local contaminado coberto com Andropogon sp. e menor nos sítios sem vegetação. O número de actinomicetos e de fungos cultiváveis foi menos afetado pela contaminação que o número total de bactérias. Azospirillum spp. foram detectados apenas no local de referência. Oxidantes de amônio foram verificados em somente dois locais que continham vegetação, enquanto os oxidantes de nitrito foram detectados na maioria dos locais amostrados. Verificou-se a tendência de maior densidade e atividade microbiana nos locais contaminados e com algum tipo de vegetação. A concentração total e solúvel de Zn, de Cd e de Cu correlacionou-se fracamente com as características biológicas, exceto para o qCO2, o qual se mostrou promissor como indicador da contaminação com esses metais. Os dados indicaram uma interação qu

  11. Evolution of fast reactor core spectra in changing a heavy liquid metal coolant by molten PB-208

    Energy Technology Data Exchange (ETDEWEB)

    Blokhin, D. A.; Mitenkova, E. F. [Nuclear Safety Inst., Russian Academy of Sciences, B. Tulskaya 52, Moscow, 115119 (Russian Federation); Khorasanov, G. L.; Zemskov, E. A.; Blokhin, A. I. [State Scientific Center, Russian Federation, Inst. of Physics and Power Engineering, Bondarenko Square 1, Obninsk, 249033 (Russian Federation)

    2012-07-01

    In the paper neutron spectra of fast reactor cooled with lead-bismuth or lead-208 are given. It is shown that in changing the coolant from lead-bismuth to lead-208 the core neutron spectra of the fast reactor FR RBEC-M are hardening in whole by several percents when a little share of low energy neutrons (5 eV - 50 keV) is slightly increasing. The shift of spectra to higher energies permits to enhance the fuel fission while the increased share of low energy neutrons provides more effective conversion of uranium-238 into plutonium due to peculiarity of {sup 238}U neutron capture cross section. Good neutron and physical features of molten {sup 208}Pb permit to assume it as perspective coolant for fast reactors and accelerator driven systems. The one-group cross sections of neutron radiation capture, {sigma}(n,g), by {sup 208}Pb, {sup 238}U, {sup 99}Tc, mix of lead and bismuth, {sup nat}Pb-Bi, averaged over neutron spectra of the fast reactor RBEC-M are given. It is shown that one-group cross sections of neutron capture by material of the liquid metal coolant consisted from lead enriched with the stable lead isotope, {sup 208}Pb, are by 4-7 times smaller {sigma}(n,g) for the coolant {sup nat}Pb-Bi. The economy of neutrons in the core cooled with {sup 208}Pb can be used for reducing reactor's initial fuel load, increasing fuel breeding and transmutation of long lived fission products, for example {sup 99}Tc. Good neutron and physical features of lead enriched with {sup 208}Pb permit to consider it as a perspective low neutron absorbing coolant for fast reactors and accelerator driven systems. (authors)

  12. ABILITY OF Phanerochaete chrysosporium AND Trametes versicolor TO REMOVE Zn2+, Cr3+, Pb2+ METAL IONS

    Directory of Open Access Journals (Sweden)

    Josué Solís Pacheco

    2015-07-01

    Full Text Available The use of fungal biomass as an alternative for removing heavy metals has become increasingly important in recent years, replacing conventional methods based on chemical physical processes. In this study, we evaluated the biosorption of Zn2+, Cr3+ and Pb2+, which were analyzed to determine their effect on growth kinetic parameters of Phanerochaete chrysosporium strain ATCC 32629 and Trametes versicolor ATCC 1267. Growth kinetics were performed in four liquid culture media: 1 Yeast Nitrogen Base (YNB used as control, 2 YNB medium plus Pb2+ (0.25, 1 and 2 mg L-1, 3 YNB medium plus Zn2+ (5, 10 and 20 mg L-1 and 4 YNB medium plus Cr3+ (0.5, 1 and 2 mg L-1. The flasks were incubated at 25 °C with shaking at 150 rpm. Metal concentrations were determined by inductively coupled plasma atomic emission spectroscopy (ICP-AES with prior acid digestion of the sample. The results demonstrated that Phanerochaete chrysosporium ATCC 32629 and Trametes versicolor ATCC 12679 are able to grow in the culture medium with Pb2+, Zn2+ and Cr3+ ions at different concentrations. However, P. chrysosporium ATCC 32629 showed greater adaptability and ability to adsorb Cr3+ in the culture medium at concentrations of 0.5 and 1 mg L-1, whereas T. versicolor ATCC 12679 was capable of Pb2+ biosorption at concentrations of 0.25, 1 and 2 mg L-1.

  13. Heavy metals and health risk assessment of arable soils and food crops around Pb-Zn mining localities in Enyigba, southeastern Nigeria

    Science.gov (United States)

    Obiora, Smart C.; Chukwu, Anthony; Davies, Theophilus C.

    2016-04-01

    This study determined the heavy metals concentration in arable soils and associated food crops around the Pb-Zn mines in Enyigba, Nigeria, and metal transfer factors were calculated. Air-dried samples of the soils and food crops were analyzed for 8 known nutritional and toxic heavy metals by Inductively Coupled Plasma - Mass Spectrometer (ICP-MS) method. Eighty seven percent of all the 20 sampled soils contain Pb in excess of the maximum allowable concentration (MAC) set by Canadian Environmental Quality Guideline (CCME) and European Union (EU) Standard, while Zn in thirty-one percent of the samples exceeded the CCME for MAC of 200 mg/kg. All the food crops, with the exception of yam tuber, contain Pb which exceeded the 0.43 mg/kg and 0.3 mg/kg MAC standards of EU and WHO/FAO respectively, with the leafy vegetables accumulating more Pb than the tubers. The metal transfer factors in the tubers and the leafy vegetables were in the order: Mo > Cu > Zn > Mn > As > Cd > Cr > Ni > Pb and Cd > Cu > Zn > Mn > Mo > As > Ni > Pb > Cr, respectively. Risk assessment studies revealed no health risk in surrounding populations for most of the heavy metals. However, Pb had a high health risk index (HRI) of 1.1 and 1.3, in adults and children, respectively for cassava tuber; Pb had HRI > 1 in lemon grass while Mn also had HRI > 1 in all the leafy vegetables for both adult and children. This high level of HRI for Pb and Mn is an indication that consumers of the food crops contaminated by these metals are at risk of health problems such as Alzheimers' disease and Manganism, associated with excessive intake of these metals. Further systematic monitoring of heavy metal fluxes in cultivable soils around the area of these mines is recommended.

  14. Lead (Pb heavy metal impacts in the green Ulva lactuca (Chlorophyceae marine algae

    Directory of Open Access Journals (Sweden)

    B. Saleh

    2016-05-01

    Full Text Available Toxicity of different lead (Pb (0, 2, 4 and 8 mg/L concentrations in the green Ulva lactuca (Chlorophyta marine algae at physiological level has been investigated 48 h after Pb treatment under laboratory conditions. Thalus algae damages followed Pb treatment as revealed by microscopy test showed that the 4 and 8 mg/L Pb caused morphological changes in cells viability; whereas, no effect observed at the lowest Pb applied concentration (2 mg/L. Data revealed that Pb stress caused reduction in most investigated physiological parameters i.e. Pigments content, osmotic potential and membrane stability index values. This decline in osmotic potential was significantly (p ≤ 0.001 different. Whereas, estimated electric conductivity (EC values increased significantly (p ≤ 0.001 as applied Pb concentration increased. The current study allowed somewhat to highlight and better understanding Pb impacts in U. lactuca algae. Thereby, the studied algae could be used as a useful bioindicator in Pb polluted ecosystems.

  15. Pb(II) and Hg(II) binding to $\\textit{de novo}$ designed proteins studied by $^{204m}$Pb- and $^{199m}$Hg-Perturbed Angular Correlation of $\\gamma$-rays (PAC) spectroscopy : Clues to heavy metal toxicity

    CERN Multimedia

    2002-01-01

    $\\textit{De novo}$ design of proteins combined with PAC spectroscopy offers a unique and powerful approach to the study of fundamental chemistry of heavy metal-protein interactions, and thus of the mechanisms underlying heavy metal toxicity. In this project we focus on Pb(II) and Hg(II) binding to designed three stranded coiled coil proteins with one or two binding sites, mimicking a variety of naturally occurring thiolate-rich metal ion binding sites in proteins. The $^{204m}$Pb- and $^{199m}$Hg-PAC experiments will complement data already recorded with EXAFS, NMR, UV-Vis and CD spectroscopies.

  16. Utilization of hair and nails as bio-indicators of contamination by heavy and toxic metals in industrial workers; Utilizacao de cabelos e unhas como bioindicadores de contaminacao por metais pesados e toxicos em trabalhadores de industrias

    Energy Technology Data Exchange (ETDEWEB)

    Vilhena Schayer Sabino, Claudia de; Silva, Ascanio Barros F.E.; Fernandes, Marcio Prado; Amaral, Angela Maria; Franco, Milton Batista; Guedes, Joao Bosco; Francisco, Dovenir; Castro de Assis, Adilson de

    1996-03-01

    Instrumental neutron activation analysis and atomic absorption spectrometry were performed on scalp hair and fingernail samples collected from a group of heavily exposed healthy mail industrial workers. The concentration of trace elements (As, Cd, Cr, Hg, Ni, Pb and Sb) were evaluated and compared for scalp and fingernails. Comparative studies demonstrated that concentration of certain elements were greater than those corresponding to non-exposed workers. (author). 4 refs., 6 tabs.

  17. Metodologías aplicadas para el establecimiento de los niveles de referencia para metales pesados en la evaluación de la contaminación en suelos

    Directory of Open Access Journals (Sweden)

    Julissa Brizuela

    2012-09-01

    Full Text Available New maximum permissible levels (reference levels RL for the study of potentially contaminated soils by heavy metals were defined. Despite of anthropogenic contaminants in soils, there is also presented a certain amount of natural metals (background levels in these soils according to the proper geographic region, which encouraged us to establish particular RL for the metals in soils. Currently, there is not an unique methodology to establish the RL for metals in soils, thus this study intend to review information on different methodologies applied to define RL. A general scheme covering all methodologies are presented.

  18. Removal of Pb(II), Cu(II) and Cd(II) from aqueous solution by some fungi and natural adsorbents in single and multiple metal systems

    International Nuclear Information System (INIS)

    Shoaib, A.; Badar, T.; Aslam, N.

    2011-01-01

    Six fungal and 10 natural biosorbents were analyzed for their Cu(II), Cd(II) and Pb(II) uptake capacity from single, binary and ternary metal ion system. Preliminary screening biosorption of assays revealed 2 fungi (Aspergillus niger and Cunninghamella echinulata) and three natural [Cicer arietinum husk, Moringa oleifera flower and soil (clay)] adsorbents hold considerable high adsorption efficiency and capacity for 3 meta l ions amongst the adsorbents. Further biosorption trials with five elected adsorbents showed a considerable reduction in metal uptake capability of adsorbents in binary- and ternary systems as compared to singly metal system. Cd(II) manifested the highest inhibitory effect on the biosorption of other metal ions, followed by Pb(II) and Cu(II). On account of metal preference, the selectivity order for metal ion towards the studied biomass matrices was Pb(II) (40-90%) > Cd(II) (2-53%) > Cu(II) (2-30%). (author)

  19. Extraction procedure compared to attenuation model to assess heavy metals mobility in sediments from Sepetiba Bay, Rio de Janeiro; Procedimento de fracionamento comparado a modelo de atenuacao para a avaliacao de mobilidade de metais pesados em sedimentos da Baia de Sepetiba, Rio de Janeiro

    Energy Technology Data Exchange (ETDEWEB)

    Ribeiro, Andreza Portella

    2006-07-01

    Sepetiba bay, located about 60 km west of the metropolitan region of Rio de Janeiro city, has undergone notable development in the last decades, with the establishment of about 400 industrial plants in its basin, basically metallurgical, which release its industrial waste either straight into the bay or through local rivers. The Sepetiba harbor also brought up a lot of industrial investment in that area. This urban and industrial expansion caused several environmental impacts, mainly due to the presence of heavy metals and other potentially toxic substances present in the effluents discharged into the bay. This work aimed to assess heavy metal (Cd, Cu, Ni, Pb e Zn) contamination and mobility in sediments from Sepetiba bay. The acid-volatile sulfides (AVS) and the concentration of simultaneously extracted metals (SIGMA[SEM) were determined in 65 sediment samples from Sepetiba bay, representing the whole area. The results obtained showed that Cd, Cu, Pb and Zn presented higher concentrations in the northeastern area (mainly in the mouth of Guandu and Canal de Sao Francisco rivers), while the highest concentration of Ni were observed in the western region of the bay. The comparison between SEM concentrations with the Canadian Sediment Quality Guidelines (TEL and PEL) indicated that Cd and Zn presented values which may hazard to aquatic organisms (concentration levels above PEL); the elements Cu, Pb and Ni presented concentration levels below PEL, suggesting low probability of toxicological effects to the aquatic organisms. On the other hand, the ratio {sigma}[SEM]/[AVS] was below 1 in the northeastern region, indicating that, in spite of the high concentration of the analyzed metals in this area, they are trapped in the sediment, as sulfides. The total metal concentrations in the sediments were also determined and the same distribution pattern obtained for the SEM were observed, with high concentrations in the northeastern region of the bay, classifying the area as

  20. Composição química de diferentes fontes de fósforo e deposição de metais pesados em tecidos de suínos Chemical composition of different phosphorus sources and heavy metal deposition in tissues of swines

    Directory of Open Access Journals (Sweden)

    A.O. Teixeira

    2005-08-01

    Full Text Available Foram utilizados 112 leitões com peso inicial de 28,68kg, distribuídos em blocos ao acaso, em esquema fatorial 8×2 (oito tratamentos x dois sexos, sete repetições e dois animais por baia. As dietas foram formuladas com base no fósforo total, sendo estas à base de milho e de farelo de soja. O fósforo foi suplementado utilizando-se os fosfatos: bicálcico (FBC; monobicálcico (MBC; supertriplo (ST; supersimples (SS; rocha Catalão (ROCHA; mistura de fontes (MIST e ácido fosfórico (AcF; e dieta-controle, sem o fósforo suplementar (CONT. Avaliou-se previamente a composição química de amostras de fontes de fósforo disponíveis no mercado. Os fosfatos MBC, FBC e AcF apresentaram baixo nível de contaminação por metais pesados. Observou-se variação no teor de metais pesados entre as marcas comerciais de supertriplo. O consumo do fosfato resultou em acúmulo de cobre nos músculos. A dieta-controle provocou acúmulo de chumbo e zinco no fígado, e a mistura de fontes e supertriplo ocasionou acúmulo de cádmio no fígado. A utilização de fontes alternativas de fósforo menos elaboradas influenciou a deposição de minerais no fígado e nos músculos dos suínos.One hundred twelve pigs averaging weight of 28.68kg, were allotted to a completely randomized blocks with seven replicates of two animals per box. The treatments consisted in factorial 8×2 (eight phosphorus sources x two sexes. The experimental diets were formulated based on corn and soybean meal and the phosphorus was supplemented through phosphate dicalcium (FBC, monodicalcium (MBC, triple superphosphate (ST, simple superphosphate (SS, Catalão rock (ROCHA, mixture of sources (MIST, and phosphoric acid (AcF in addition to a control diet without supplemental phosphous (CONT. Samples of phosphorus sources available in the market were evaluated for particle size and chemical composition. The MBC, FBC and AcF showed a low level of heavy metal contamination, but a variation in

  1. Concentração de metais pesados em grãos de plantas cultivadas em solo com diferentes níveis de contaminação Concentration of heavy metals in grain of plants cultivated in soil with different contamination levels

    Directory of Open Access Journals (Sweden)

    Maria Ligia de Souza Silva

    2007-04-01

    Full Text Available O objetivo deste trabalho foi avaliar a absorção e a capacidade de translocação de metais pesados do solo para os grãos de soja e arroz. O experimento foi realizado em casa de vegetação, em Latossolo Vermelho distroférrico, proveniente de Município de Paulínia, SP. As amostras de solo foram coletadas em sete pontos e organizadas em função da distância de uma fábrica emissora de poluente. O delineamento utilizado foi o inteiramente casualizado, com quatro repetições. Raízes, parte aérea e grãos foram submetidos à digestão por via úmida. A concentração dos metais pesados foi determinada por ICP-OES. Os teores de cádmio e cobre no grão estiveram em níveis adequados para ambas as culturas, enquanto os teores de manganês e zinco apresentaram-se em excesso, tendo acompanhado os níveis de contaminação do solo, com possibilidade de atingir níveis mais altos da cadeia trófica. As raízes limitaram a translocação de cádmio, cobre, ferro e chumbo para a parte aérea de ambas as culturas. Mesmo com a translocação limitada pelas raízes, o chumbo apresentou-se em altos teores nos grãos de soja, e pode, também, como o manganês e o zinco, atingir a cadeia alimentar.The aim of this work was to evaluate the absorption and capacity of translocation of heavy metals from the soil to rice and soybean grains. Experiment was carried out in a greenhouse using a dystrophic Typic Hapludox soil from the district of Paulínia, SP. Soil samples were collected in seven different points and were organized according to the distance from a factory, source of pollution. The experimental design used was the completely randomized, with four replications. The roots, aerial leaves and grains were submitted to humid digestion. The concentrations of heavy metals were determined by ICP-OES. Cadmium and copper concentrations in the grains were at normal levels for both cultures, however manganese and zinc concentrations were in excess, according

  2. Study of parameters that influence the process of biosorption in the removal of heavy metals; Estudo de parametros que influenciam o processo de biossorcao na remocao de metais pesados

    Energy Technology Data Exchange (ETDEWEB)

    Moreira, Albina S.; Duarte, Marcia M.L.; Nandenha, Julio; Macedo, Gorete R. [Universidade Federal do Rio Grande do Norte (UFRN), Natal, RN (Brazil)

    2004-07-01

    The removal of heavy metal by microbial biomass have been investigated as an alternative to the traditional methods. The removal of the heavy metals copper and iron from discarded lubricating-oil was studied using the biosorbent Sargassum sp. It was chosen a discarded lubricating-oil of a bus fleet from the city of Natal-RN-Brazil. The oil was characterized to determine and quantify the heavy metals present. The effect of biomass protonation was performed in order to increase the removal efficiency of the metals. The equilibrium time between the oil and the biomass was determined. It was found that after 10 hours the equilibrium was reached. It was also studied the influence of biomass quantity. The results showed that the biomass quantity is an important parameter to the efficiency and biosorption capacity. The protonated biomass was shown more efficient to removal of Fe and Cu, removing 37,53% and 31,63% respectively. (author)

  3. Biosorption of Pb2+ using Trichoderma viride as Alternative Solution for Heavy Metal Pollution in the Waters

    Directory of Open Access Journals (Sweden)

    Rensani Taloin

    2018-01-01

    Full Text Available Lead(II is considered as the main cause of pollutant that is toxic, corrosive, and irritant. One method that can be applied for reducing Pb(II in the environment is by using microorganisms. In this work, the study of biosorption of Pb(II in the water samples was conducted using Trichoderma viride. The research is focused on determination of optimum conditions including pH, biosorption time, and initial concentration of Pb(II used. The profiles in functional groups contained in the T. viride have been monitored using FT-IR spectrophotometry. Results showed that the maximum biosorption of Pb(II achieved at pH 4.5, with equilibrium of contact time of 20 h, optimum concentration of 50 mg/L, and adsorption capacity of 85 mg/1x106 T. viride colonies. The FTIR results indicated that biosorption process changed the functional groups in the T. viride. These have shown in the absorption bands at ~3200 cm-1, ~2850 cm-1, ~2260 cm-1, ~1650 cm-1, ~1450 cm-1, 1180 cm-1, and in the finger printing regions. The biosorption mechanism was proposed through the adsorption process between positively charged metal ions and the negative charge on the functional groups, such as -COO-, -OPO32-, and –NH2-, on the cell surface.

  4. Biossorção de metais pesados com a biomassa de macrófitos aquáticos

    OpenAIRE

    Ivo Andre Homrich Schneider

    1995-01-01

    O presente trabaJho tem como objetivo estudar a biomassa seca e homogeneizada de macrófitos aquáticos como um material sorvente de metais pesados ( Cr(ill), Ni, Cu, Zn, Cd e Pb) presentes em soluções aquosas. Os macró:fitos aquáticos foram coletados em recursos hídricos do Estado do Rio Grande do Sul, lavados, secos a 60°C, moídos, peneirados e embalados em sacos plásticos. Diversas propriedades fisicas, bioquímicas, interfaciais e químicas dos biossorventes foram analisadas. Realizaram-se es...

  5. Centennial record of anthropogenic impacts in Galveston Bay: Evidence from trace metals (Hg, Pb, Ni, Zn) and lignin oxidation products.

    Science.gov (United States)

    Al Mukaimi, Mohammad E; Kaiser, Karl; Williams, Joshua R; Dellapenna, Timothy M; Louchouarn, Patrick; Santschi, Peter H

    2018-06-01

    During the 20th century the impacts of industrialization and urbanization in Galveston Bay resulted in significant shifts in trace metals (Hg, Pb, Ni, Zn) and vascular plant biomarkers (lignin phenols) recorded within the surface sediments and sediment cores profile. A total of 22 sediment cores were collected in Galveston Bay in order to reconstruct the historical input of Hg, Pb, Ni, Zn and terrestrial organic matter. Total Hg (T-Hg) concentration ranged between 6 and 162 ng g -1 in surface sediments, and showed decreasing concentrations southward from the Houston Ship Channel (HSC) toward the open estuary. Core profiles of T-Hg and trace metals (Ni, Zn) showed substantial inputs starting in 1905, with peak concentrations between 1960 and 1970's, and decreasing thereafter with exception to Pb, which peaked around 1930-1940s. Stable carbon isotopes and lignin phenols showed an increasing input of terrestrial organic matter driven by urban development within the watershed in the early 1940s. Both the enrichment factor and the geoaccumulation index (I geo ) for T-Hg as a measure of the effectiveness of environmental management practices showed substantial improvements since the 1970s. The natural recovery rate in Galveston Bay since the peak input of T-Hg was non-linear and displayed a slow recovery during the twenty-first century. Copyright © 2018 Elsevier Ltd. All rights reserved.

  6. Adaptation of soil microbial community structure and function to chronic metal contamination at an abandoned Pb-Zn mine.

    Science.gov (United States)

    Epelde, Lur; Lanzén, Anders; Blanco, Fernando; Urich, Tim; Garbisu, Carlos

    2015-01-01

    Toxicity of metals released from mine tailings may cause severe damage to ecosystems. A diversity of microorganisms, however, have successfully adapted to such sites. In this study, our objective was to advance the understanding of the indigenous microbial communities of mining-impacted soils. To this end, a metatranscriptomic approach was used to study a heavily metal-contaminated site along a metal concentration gradient (up to 3220 000 and 97 000 mg kg(-1) of Cd, Pb and Zn, respectively) resulting from previous mining. Metal concentration, soil pH and amount of clay were the most important factors determining the structure of soil microbial communities. Interestingly, evenness of the microbial communities, but not its richness, increased with contamination level. Taxa with high metabolic plasticity like Ktedonobacteria and Chloroflexi were found with higher relative abundance in more contaminated samples. However, several taxa belonging to the phyla Actinobacteria and Acidobacteria followed opposite trends in relation to metal pollution. Besides, functional transcripts related to transposition or transfer of genetic material and membrane transport, potentially involved in metal resistance mechanisms, had a higher expression in more contaminated samples. Our results provide an insight into microbial communities in long-term metal-contaminated environments and how they contrast to nearby sites with lower contamination. © FEMS 2014. All rights reserved. For permissions, please e-mail: journals.permissions@oup.com.

  7. Compuestos orgánicos persistentes y metales pesados en sangre y efectos en el desarrollo neuropsicológico de la primera infancia en las cohortes de madres-niños INMA (INfancia y Medio Ambiente

    Directory of Open Access Journals (Sweden)

    Aritz Aranbarri Paredes

    2012-08-01

    Full Text Available Introducción: El proyecto INMA es un estudio multicéntrico basado en el seguimiento prospectivo de cohortes de madres-hijos en distintas áreas de la geografía española. Objetivo: Estudiar la relación entre los principales contaminantes ambientales y el desarrollo de los niños y niñas en las fases pre y postnatales. Material y Métodos: El conjunto de las cohortes comparten metodología e instrumentos de recogida de información (exposición ambiental, muestras biológicas, exámenes del desarrollo físico y neuropsicológico, cuestionarios de dieta etc. durante el crecimiento intrauterino y en las fases de seguimiento en la infancia. Resultados: Se presentan los niveles de Compuestos Orgánicos Persistentes (COP en suero del primer trimestre de embarazo y de plomo (Pb y mercurio total (Hg-T de cordón umbilical y las asociaciones con el desarrollo neuropsicológico analizadas hasta la fecha. Los COP más frecuentemente encontrados fueron el p,p ́-DDE (99% y el PCB 153 (95% con medias geométricas en suero (ng/g-lípido de 110,0 (p,p ́-DDE y 38,9 (PCB 153. La media geométrica y el nivel máximo de Pb fueron 1,06 μg/dL y 19 μg/dL, respectivamente. La media geométrica de Hg-T fue de 8,2 μg/L, siendo el consumo de pescado el principal predictor. Un 64% de las muestras superan los niveles de referencia de Hg-T establecidos por la USEPA (6,4 μg/L. Conclusión: Los niveles de COP y Pb observados en las áreas de estudio se encuentran en el rango de valores ya descritos en estudios anteriores. Los niveles de Hg requieren una valoración más profunda, así como el estudio de las posibles asociaciones con el desarrollo neuropsicológico. 

  8. Distribution of toxic metals, Hg, Cd and Pb in zooplankton along the Indian coasts

    Digital Repository Service at National Institute of Oceanography (India)

    Sengupta, R.; Kureishy, T.W.

    and in the marine food chain is also attempted. The results have shown high concentrations of Cd and Pb in zooplankton collected from the East Coast as compared to the West Coast. Some inferences have been drawn...

  9. Chronology of anthropogenic impacts reconstructed from sediment records of trace metals and Pb isotopes in Todos os Santos Bay (NE Brazil).

    Science.gov (United States)

    Andrade, R L B; Hatje, V; Masqué, P; Zurbrick, C M; Boyle, E A; Santos, W P C

    2017-12-15

    The evolution of the impacts of anthropogenic activities in Todos os Santos Bay was evaluated by profiles of trace metals and Pb isotopes determined in sediment cores. Fluxes of metals increased up to 12, 4 and 2 times for Cu, Pb, and Zn, respectively, compared to those recorded in the beginning of the 20 th century. Stable Pb isotopes identified a decommissioned lead smelter and burning of fossil fuels as the main sources of Pb. Most metals showed minor to moderate enrichment factors (EFuses. The effects of the implementation of environmental policies to improve the waters of the bay could not be identified in the evaluated cores. Copyright © 2017 Elsevier Ltd. All rights reserved.

  10. Coupling meteorology, metal concentrations, and Pb isotopes for source attribution in archived precipitation samples.

    Science.gov (United States)

    Graney, Joseph R; Landis, Matthew S

    2013-03-15

    A technique that couples lead (Pb) isotopes and multi-element concentrations with meteorological analysis was used to assess source contributions to precipitation samples at the Bondville, Illinois USA National Trends Network (NTN) site. Precipitation samples collected over a 16month period (July 1994-October 1995) at Bondville were parsed into six unique meteorological flow regimes using a minimum variance clustering technique on back trajectory endpoints. Pb isotope ratios and multi-element concentrations were measured using high resolution inductively coupled plasma-sector field mass spectrometry (ICP-SFMS) on the archived precipitation samples. Bondville is located in central Illinois, ~250km downwind from smelters in southeast Missouri. The Mississippi Valley Type ore deposits in Missouri provided a unique multi-element and Pb isotope fingerprint for smelter emissions which could be contrasted to industrial emissions from the Chicago and Indianapolis urban areas (~125km north and east, of Bondville respectively) and regional emissions from electric utility facilities. Differences in Pb isotopes and element concentrations in precipitation corresponded to flow regime. Industrial sources from urban areas, and thorogenic Pb from coal use, could be differentiated from smelter emissions from Missouri by coupling Pb isotopes with variations in element ratios and relative mass factors. Using a three endmember mixing model based on Pb isotope ratio differences, industrial processes in urban airsheds contributed 56±19%, smelters in southeast Missouri 26±13%, and coal combustion 18±7%, of the Pb in precipitation collected in Bondville in the mid-1990s. Copyright © 2012 Elsevier B.V. All rights reserved.

  11. Geochemical behavior of radionuclides and heavy metals in soils from Corumbatai River basin (SP), Brazil; Comportamento geoquimico de radionuclideos e metais pesados em solos da bacia do Rio Corumbatai (SP)

    Energy Technology Data Exchange (ETDEWEB)

    Conceicao, Fabiano Tomazini da

    2004-07-01

    The purpose of this research was to study the geochemical behavior of radionuclides and heavy metals in soils of agricultural use at Corumbatai River basin (SP). The natural concentration and variability in sedimentary rocks at Corumbatai river basin follow the trend Ca > Mg > K > Na, with the concentration of heavy metals and radionuclides. The distribution of exposure rate in soils shows the occurrence of higher values towards south of the Corumbatai river basin, region where are applied phosphate fertilizers, amendments and 'vinhaca' in sugar cane crops. Heavy metals and radionuclides incorporated in phosphate fertilizers and amendments are annually added during the fertilization process in the sugar cane crops, but if they are utilized in accordance with the recommended rate, they do not rise the concentration levels in soils up to hazards levels. Thus, they are lower transferred from soils to sugar cane at Corumbatai river basin, not offering hazard to the ecosystem and animal or human health. (author)

  12. Effects of Cr III and Pb on the bioaccumulation and toxicity of Cd in tropical periphyton communities: Implications of pulsed metal exposures

    International Nuclear Information System (INIS)

    Bere, Taurai; Chia, Mathias Ahii; Tundisi, José Galizia

    2012-01-01

    Metal exposure pattern, timing, frequency, duration, recovery period, metal type and interactions, has obscured effects on periphyton communities in lotic systems. The objective of this study was to investigate the effects of intermittent exposures of Cr III and Pb on Cd toxicity and bioaccumulation in tropical periphyton communities. Natural periphyton communities were transferred to artificial stream chambers and exposed to metal mixtures at different pulse timing, duration, frequency and recovery periods. Chlorophyll a, dry mass and metal accumulation kinetics were recorded. Cr and Pb decrease the toxic effects of Cd on periphyton communities. Periphyton has high Cd, Cr and Pb accumulation capacity. Cr and Pb reduced the levels of Cd sequestrated by periphyton communities. The closer the frequency and duration of the pulse is to a continuous exposure, the greater the effects of the contaminant on periphyton growth and metal bioaccumulation. Light increased toxic and accumulative effects of metals on the periphyton community. - Highlights: ► We investigated toxicity effects of pulsed metal exposures on bioaccumulation and toxicity in periphyton. ► High frequency of short duration pulses has effects equal to long duration exposures. ► Important role of light in modulating metal toxicity on periphyton demonstrated. ► Factors other than magnitude and duration must be considered in water quality criteria. ► Accurate prediction of metal effects on biofilms requires data on effluent variability. - The study highlights the importance of pulse timing, frequency, duration, recovery period and chemical type on aquatic life.

  13. Fifty-year sedimentary record of heavy metal pollution (Cd, Zn, Cu, Pb) in the Lot River reservoirs (France)

    International Nuclear Information System (INIS)

    Audry, Stephane; Schaefer, Joerg; Blanc, Gerard; Jouanneau, Jean-Marie

    2004-01-01

    The Lot-Garonne fluvial system is known for its historic heavy metal pollution resulting from mining and smelting activities since the late 19th century. Here, we report 137 Cs activities and heavy metal (Cd, Zn, Cu, Pb and V) concentration-depth profiles from sediment cores retrieved in 2001 from three reservoirs in the Lot River. High mean sedimentation rates of 2.4-2.8 cm a -1 are indicated by 137 Cs dating. The reservoir sediments have recorded the heavy metal deposition and thus allow establishing a connection between the temporal evolution of the heavy metal pollution and historical changes in smelting and waste-treatment proceedings. Based on heavy metal concentrations in sediments upstream of the anthropogenic inputs and bottom-sediments of the furthest downstream core (interpreted as old soil or riverbed), concentrations of ∼17, ∼82, ∼0.33 and ∼28 mg kg -1 for Cu, Zn, Cd and Pb, respectively, are proposed as natural background values for the Lot fluvial system. The geoaccumulation index (I geo [Mueller, G., 1979. Schwermetalle in den Sedimenten des Rheins-Veraenderungen seit. Umschav 79, 133-149.]) revealed that the Lot River sediments must be considered as 'severely polluted' in Cd and Zn. Moreover, despite remediation efforts undertaken in the former smelting site, the Lot River is still ''severely'' (I geo ∼ 4) and ''moderately to severely'' (I geo > 2) impacted by Cd and Zn inputs, respectively. - Capsule: Reservoir sediments provide fine-scale information on the historical record of metal pollution in a watershed

  14. Relations between metals (Zn, Pb, Cd and Cu) and glutathione-dependent detoxifying enzymes in spiders from a heavy metal pollution gradient

    International Nuclear Information System (INIS)

    Wilczek, Grazyna; Babczynska, Agnieszka; Augustyniak, Maria; Migula, Pawel

    2004-01-01

    We studied the relations between glutathione-dependent detoxifying enzymes and heavy metal burdens in the web-building spider Agelena labyrinthica (Agelenidae) and the wolf spider Pardosa lugubris (Lycosidae) from five meadow sites along a heavy metal pollution gradient. We assayed the activity of glutathione-S-transferase (GST) and glutathione peroxidases (GPOX, GSTPx), and glutathione (GSH) levels in both sexes. Except for GSH vs Pb content, we found significant correlations between GPOX and GSTPx activity and metal concentrations in females of A. labyrinthica. The highest activity of these enzymes measured in the web-building spiders was found in the individuals from the most polluted sites. In P. lugubris males significant correlations were found between GST and Pb and Zn concentrations, and between GPOX and GSTPx and the concentration of Cu. GST activity was higher in males collected from less polluted areas. Thus, detoxifying strategies against pollutants seemed to be sex-dependent. Actively hunting spiders had higher metal concentrations, maintaining lower activity of detoxifying enzymes and a lower glutathione level. - Capsule: Glutathione-linked enzyme activity in spiders from polluted areas depends on hunting strategy and sex

  15. Pollution by Heavy Metals: Environmental Implications and Key Strategies for Remediation | Poluição por metais pesados: implicações ambientais e estratégias-chave para remediação

    Directory of Open Access Journals (Sweden)

    Fabrício Ângelo Gabriel

    2016-10-01

    Full Text Available Heavy metals in  small amounts found in nature, are essential to the survival of animals and plants on the planet. However, is becoming worring the direct and indirect releases of the heavy metals in the environment, causing negative effects and the imbalance in the cycle of these chemicals. This activity is progressive increase in the face of population growth, agriculture and industrial sectors, the main dispersers of this pollutant for the production of goods and services. The influence of these environmental contaminants is considerably wide and can be found in air, water, soil and consequently in food, passing the necessary conditions for an ecological imbalance. The arrangement of these metals in nature affects, often irreversibly, the ecosystem as a whole, resulting in short- or long-term risk of living organisms and human health. This review reports the contamination caused by different heavy metals and their potential to cause damage to fauna, flora and humans. Thus, in order to minimize the impacts, it is necessary to highlight the problems about polluting activities as a subsidy for concentration of efforts in the development of innovative and sustainable methods for remediation.

  16. Testing WHAM-FTOX with laboratory toxicity data for mixtures of metals (Cu, Zn, Cd, Ag, Pb).

    Science.gov (United States)

    Tipping, Edward; Lofts, Stephen

    2015-04-01

    The Windermere humic aqueous model using the toxicity function (WHAM-FTOX ) describes cation toxicity to aquatic organisms in terms of 1) accumulation by the organism of metabolically active protons and metals at reversible binding sites, and 2) differing toxic potencies of the bound cations. Cation accumulation (νi , in mol g(-1) ) is estimated through calculations with the WHAM chemical speciation model by assuming that organism binding sites can be represented by those of humic acid. Toxicity coefficients (αi ) are combined with νi to obtain the variable FTOX (= Σ αi νi ) which, between lower and upper thresholds (FTOX,LT , FTOX,UT ), is linearly related to toxic effect. Values of αi , FTOX,LT , and FTOX,LT are obtained by fitting toxicity data. Reasonable fits (72% of variance in toxic effect explained overall) were obtained for 4 large metal mixture acute toxicity experiments involving daphnids (Cu, Zn, Cd), lettuce (Cu, Zn, Ag), and trout (Zn, Cd, Pb). Strong nonadditive effects, most apparent in results for tests involving Cd, could be explained approximately by purely chemical competition for metal accumulation. Tentative interpretation of parameter values obtained from these and other experimental data suggests the following order of bound cation toxicity: H < Al < (Cu Zn Pb UO2 ) < (Cd Ag). Another trend is a strong increase in Cd toxicity relative to that of Zn as organism complexity increases (from bacteria to fish). © 2014 SETAC.

  17. CONTRIBUTIONS TO THE STUDY OF HEAVY METALS DISTRIBUTION (Zn, Pb, Cd, Bi, Cu IN SOME SOILS FROM GIURGEU MOUNTAINS

    Directory of Open Access Journals (Sweden)

    D. Bulgariu

    2005-10-01

    Full Text Available In this paper are presented the results of mineralogical and geochemical studies, realized for few soils from Giurgeu Mountains, which have as main purpose the distribution and mobility interpretation of minor elements (Cd, Cu, Pb, Zn, Bi in studied soil samples. The determination of fixed fractions and mobile fractions weight, at total contents of studied elements, and relative association of these elements with main mineral and organic components of soil samples, was realized on the basis of results obtained by sequential solid/ liquid extraction. The same, we try to use the correlation establish between metallic ions contents, as indicators of mineral paragenesis (the genetic type and formation conditions. The obtained results are agree with the results of similar studies from literature and they, underline of some interesting aspects about of distribution and migration of heavy metals in soils: (1 exist of some selectivity in heavy metals distribution in mineral components from soils, correlated with reciprocals geochemical affinities between speciation forms of metals and mineral components, in a given pedogeochemical context; (2 the heavy metals distribution between solid phases and soil solution are realized in competitive regime, and the inter-phases equilibrium evolution are thermodynamic and kinetics controlled by the solid/ liquid interfaces processes; (3 the fast elementary processes and local fluctuations of physic-chemical parameters are the main factors which controlled the inter-phases transfer ratio and the evolution direction of equilibriums of heavy metals distribution.

  18. Dissolved trace metals (Ni, Zn, Co, Cd, Pb, Al, and Mn) around the Crozet Islands, Southern Ocean

    Science.gov (United States)

    Castrillejo, Maxi; Statham, Peter J.; Fones, Gary R.; Planquette, Hélène; Idrus, Farah; Roberts, Keiron

    2013-10-01

    A phytoplankton bloom shown to be naturally iron (Fe) induced occurs north of the Crozet Islands (Southern Ocean) every year, providing an ideal opportunity to study dissolved trace metal distributions within an island system located in a high nutrient low chlorophyll (HNLC) region. We present water column profiles of dissolved nickel (Ni), zinc (Zn), cobalt (Co), cadmium (Cd), lead (Pb), aluminium (Al), and manganese (Mn) obtained as part of the NERC CROZEX program during austral summer (2004-2005). Two stations (M3 and M1) were sampled downstream (north) of Crozet in the bloom area and near the islands, along with a control station (M2) in the HNLC zone upstream (south) of the islands. The general range found was for Ni, 4.64-6.31 nM; Zn, 1.59-7.75 nM; Co, 24-49 pM; Cd, 135-673 pM; Pb, 6-22 pM; Al, 0.13-2.15 nM; and Mn, 0.07-0.64 nM. Vertical profiles indicate little island influence to the south with values in the range of other trace metal deprived regions of the Southern Ocean. Significant removal of Ni and Cd was observed in the bloom and Zn was moderately correlated with reactive silicate (Si) indicating diatom control over the internal cycling of this metal. Higher concentrations of Zn and Cd were observed near the islands. Pb, Al, and Mn distributions also suggest small but significant atmospheric dust supply particularly in the northern region.

  19. The use of the X-ray fluorescence on the monitoring of heavy metals in water samples; Emprego da fluorescencia de raios-X no monitoramento de metais pesados em amostras de agua

    Energy Technology Data Exchange (ETDEWEB)

    Carneiro, Ana E. Vives; Brienza, Sandra M.B.; Faion, Melissa; Souza, Luiz J. S. de; Siqueira, Wagner F. [Universidade Metodista de Piracicaba (UNIMEP), SP (Brazil). Faculdade de Ciencias Matematicas e da Natureza; Nascimento Filho, Virgilio F. [Centro de Energia Nuclear na Agricultura (CENA), Piracicaba, SP (Brazil). Lab. de Instrumentacao Nuclear; Simabuco, Silvana M. [Universidade Estadual de Campinas, SP (Brazil). Faculdade de Engenharia Civil

    2000-07-01

    With the purpose to evaluate the degree of contamination for weighed metals in the region of the lakes of Santa Gertrudes, water samples had been analyzed using the technique of x-ray fluorescence with energy dispersion. For the production of x-rays characteristic were used a tube of x-rays and for the detection a detector of Si(Li). The pre-concentration of the samples for precipitation with ammonium pyrrolidine dithiocarbamate was carried through, for the determination of the concentration of interest metals, presents on the level of traces. The gotten limits of detention for Cr, Mn, Fe, Ni, Cu and Zn had been of 1,4; 1,8; 2,2; 3,0; 3,5 and 4,0 ng.ml{sup -1}, respectively.

  20. Determinación de la concentración de sólidos suspendidos totales (SST y metales pesados en la cuenca del Río Morote, Nicoya, Guanacaste.

    Directory of Open Access Journals (Sweden)

    Ricardo Sánchez Murillo

    2016-03-01

    Full Text Available The Total Suspended Solids (TTS and heavy metal concentrations of Morote River Basin were determined. The project includedsix sampling campaigns between April 2003 and May 2005. The sampling points in the Morote River were selected from the high basin to the mouth of the river in the Gulf of Nicoya. During the rainy season the concentrations of TTS exceed the value of 200 mg/L in the mouth of the river. An enrichment of the sediments was found from the river-bed with heavy metals such as copper, cadmium, nickel and iron but enrichment with lead was not found. In the dry season the concentration of zinc was colose to the allotted maximum value (200 mg/kg which has been established for the Envoronmental Protection Agency of the United States (EPA.

  1. Influence of mechanical activation on the leaching of non-ferrous metals from a CuPbZn complex concentrate

    Directory of Open Access Journals (Sweden)

    Godoèíková Erika

    2000-09-01

    Full Text Available The aim of study was to research the procedures of copper, lead and zinc leaching from CuPbZn complex sulphide concentrate during the intervention of mechanical activation.Mechanical activation belongs to innovative procedures, which intensifies technological processes by means of creation of new surfaces and making defective structure of solid phase. Mechanical impact on the solid phase is a suitable procedure to ensure the mobility of its structure elements and to accumulate the mechanical energy that is later used in following processes of leaching.This paper deals with the intensification of the chloride and thiourea leaching of copper, lead and zinc from a CuPbZn complex concentrate of Hodruša-Hámre (Slovak deposit by using the mechanical activation in an attritor. Ferric chloride and thiourea were used as leaching reagents. The leaching of the concentrate with ferric chloride solution afforded 23 % recovery of Cu, 99 % of Pb and 28 % of Zn. 9 % recovery of Cu, 17 % of Pb and 3 % of Zn were achieved by the leaching with thiourea. Thus results showed that the extraction of Cu, Zn and also Pb in the case of thiourea leaching was low. The use of milling in the attritor as an innovation method of pretreatment leads to the structural degradation and increasing the surface area of the investigated concentrate from the original value of 0.18 m2g-1 to the maximum value of 4.67 m2g-1. This fact manifested itself in the subsequent process of extraction of Cu, Pb and Zn into the chloride and thiourea solutions. Our results indicate more effective leaching of pretreated concentrate in the chloride medium with recoveries of 84 % Zn and 100 % Pb. In thiourea, the recoveries for Zn and Pb were low, however 99 % Cu can be recovered. In regard to the economy, the extraction of Cu, Pb and Zn was studied in this work with the aspect of minimal energy consumption during milling. The maximum recoveries of non-ferrous metals in the solutions of ferric chloride

  2. Immobilization of heavy metals (Pb, Cu, Cr, Zn, Cd, Mn) in the mineral additions containing concrete composites.

    Science.gov (United States)

    Giergiczny, Zbigniew; Król, Anna

    2008-12-30

    The presented work determines the level of heavy metals (Pb+2, Cu+2, Zn+2, Cr+6, Cd+2, Mn+2) immobilization in the composites produced using Ordinary Portland Cement (OPC) as well as of binders containing large amount of mineral additives in its composition-siliceous fly ash (FA), fluidized bed combustion ash (FFA) and ground granulated blast furnace slag (GGBFS). Heavy metals were introduced to cementitious materials in the form of soluble salts as well as components of hazardous wastes (medical ash, metallurgical dust). It has been stated, that the level of heavy metals immobilization is combined with composites composition. Majority of analyzed heavy metals, added to binders' composition in the form of heavy metal salts achieves high level of immobilization, in mortar based on binder with 85% GGBFS and 15% OPC. The lowest immobilization level was reached for chromium Cr+6 added to hardening mortars as Na2Cr2O72H2O. The level ranges from 85.97% in mortars made on blended binder (20% OPC, 30% FFA and 50% GGBFS) to 93.33% in mortar produced on OPC. The increase of the so-called immobilization degree with time of hardened material maturing was found. This should be attributed to the pozzolanic or pozzolanic/hydraulic properties of components used; their effect on microstructure of hardened material is also important. Mineral additions enter the hydration reactions in the mixtures and favor the formation of specific microstructure promoting the immobilization of hazardous elements.

  3. Colonisation of a Zn, Cd and Pb hyperaccumulator Thlaspi praecox Wulfen with indigenous arbuscular mycorrhizal fungal mixture induces changes in heavy metal and nutrient uptake

    International Nuclear Information System (INIS)

    Vogel-Mikus, Katarina; Pongrac, Paula; Kump, Peter; Necemer, Marijan; Regvar, Marjana

    2006-01-01

    Plants of the Zn, Cd and Pb hyperaccumulator Thlaspi praecox Wulfen (Brassicaceae) inoculated or not with indigenous arbuscular mycorrhizal (AM) fungal mixture were grown in a highly Cd, Zn and Pb contaminated substrate in order to evaluate the functionality of symbiosis and assess the possible impact of AM colonisation on heavy metal uptake and tolerance. The results suggest AM development in the metal hyperaccumulating T. praecox is favoured at elevated nutrient demands, e.g. during the reproductive period. AM colonisation parameters positively correlated with total soil Cd and Pb. Colonised plants showed significantly improved nutrient and a decreased Cd and Zn uptake as revealed by TRXRF, thus confirming the functionality of the symbiosis. Reduced heavy metal uptake, especially at higher soil metal contents, indicates a changed metal tolerance strategy in colonised T. praecox plants. This is to our knowledge the first report on AM colonisation of the Zn, Cd and Pb hyperaccumulator T. praecox in a greenhouse experiment. - Colonisation of a Zn, Cd and Pb hyperaccumulator Thlaspi praecox with arbuscular mycorrhizal fungi resulted in improved nutrient and reduced Cd and Zn uptake

  4. Proper land use for heavy metal-polluted soil based on enzyme activity analysis around a Pb-Zn mine in Feng County, China.

    Science.gov (United States)

    Fang, Linchuan; Liu, Yuqing; Tian, Haixia; Chen, Hansong; Wang, Yunqiang; Huang, Min

    2017-12-01

    Enzymes in the soil are useful for assessing heavy metal soil pollution. We analyzed the activity of a number of enzymes, including urease, protease, catalase, and alkaline phosphatase, in three types of land (farmland, woodland, and grassland) to evaluate soil pollution by heavy metals (Pb, Zn, and Cd). Our results showed that the tested soil was polluted by a combination of Pb, Zn, and Cd, but the primary pollutant was Cd. An ecological dose analysis demonstrated that urease was the most sensitive enzyme to Pb and Cd in the farmland, and catalase and phosphatase were the most sensitive enzymes to Pb, Zn, and Cd in the woodland and grassland. The ecological risk of Cd (E Cd ) was the smallest in all three types of land, suggesting that Cd was the major metal inhibiting enzyme activity. Electrical conductivity (EC) was shown to be a negative regulator, while nitrogen, phosphorus, and clay contents were positive regulators of soil enzyme activity. The total enzyme index (TEI) inhibition rates in the woodland were 22.2 and 38.6% under moderate and heavy pollution, respectively, which were lower than those of the other two types of land. Therefore, woodlands might be the optimum land use choice in relieving heavy metal pollution. Taken together, this study identified the key metal pollutant inhibiting soil enzyme activity and suitable land use patterns around typical metal mine. These results provide possible improvement strategies to the phytomanagement of metal-contaminated land around world.

  5. Heavy metals (Cd, Pb, Cu, Zn) in mudfish and sediments from three ...

    African Journals Online (AJOL)

    The percentage of uranium present in sediment samples (analysed by energy dispersive X-ray spectrometry) from the three dams was 9.0 % (SD 2.1%). In sediment it was found that cation exchange capacity measurements and the dolomitic hard water and high pH of the Mooi River water effectively \\'detoxified\\' Cd and Pb, ...

  6. Performance e retenção de metais pesados em três linhagens de juvenis de tilápia-do-Nilo em hapas = Performance and retention of heavy metals in fingerlings of Nile tilapia in hapas

    Directory of Open Access Journals (Sweden)

    Nilton Garcia Marengoni

    2008-07-01

    Full Text Available O trabalho objetivou avaliar o desempenho produtivo de três linhagens de tilápia-do-Nilo (Oreochromis niloticus, GIFT, Bouaké e Chitralada, durante a produção de juvenis no período de fevereiro a maio de 2007. Os alevinos sexualmente revertidos foram alojados em 12 hapas com 9 m3, instaladas em um tanque escavado com 0,7 ha de lâmina de água. Ao final de 93 dias de cultivo, verificou-se que houve diferença significativa para a sobrevivência entre as três linhagens (p This assay aimed to evaluate the productive performance of three Niletilapia (Oreochromis niloticus strains – GIFT (Genetic Improvement of Farmed Tilapia, Bouake and Chitralada – during the production of juveniles from February to May, 2007. The sexually reverted fingerlings were stored in twelve 9 m3 hapa nets installed in a pondwith 0.7 ha water blade. At the end of 93 days of culture, a significant change in survival among the three strains (p < 0.05 was verified, where GIFT (96.80% surpassed Chitralada (90.85% and Bouake (77.74%. The average final weight (40.49, 34.53 and 32.42 g, daily body mass gain (0.43, 0.37 and 0.34 g day-1 feed conversion (1.80; 1.81 and 1.81 and final biomass (19,594.79, 19,528.85 and 16,488.99 g, did not present significant differences among GIFT, Bouake and Chitralada, respectively. The average of fish over 25 g was over 80% of the lots, which guaranteed uniformity and standardization of the juveniles. The toxic metals cadmium and lead were above the tolerable level in the fish; however, the metal chromium was not detected. The GIFT strain presented the best performance only for the survival rate in this culture system, although it contained high indices of heavy metals in comparison with the other two strains.

  7. Electrochemical Study of Carbon Nanotubes/Nanohybrids for Determination of Metal Species Cu2+ and Pb2+ in Water Samples

    Directory of Open Access Journals (Sweden)

    Andréa Claudia Oliveira Silva

    2016-01-01

    Full Text Available The use of nanomaterials, such as nanoparticles and nanotubes, for electrochemical detection of metal species has been investigated as a way of modifying electrodes by electrochemical stripping analysis. The present study develops a new methodology based on a comparative study of nanoparticles and nanotubes with differential pulse anodic stripping voltammetry (DPASV and examines the simultaneous determination of copper and lead. The glassy carbon electrode modified by gold nanoparticles demonstrated increased sensitivity and decreased detection limits, among other improvements in analytical performance data. Under optimized conditions (deposition potential −0.8 V versus Ag/AgCl; deposition time, 300 s; resting time, 10 s; pulse amplitude, 50 mV; and voltage step height, 4 mV, the detection limits were 0.2279 and 0.3321 ppb, respectively, for determination of Pb2+ and Cu2+. The effects of cations and anions on the simultaneous determination of metal ions do not exhibit significant interference, thereby demonstrating the selectivity of the electrode for simultaneous determination of Pb2+ and Cu2+. The same method was also used to determine Cu2+ in water samples.

  8. Structural stability and half-metallic ferromagnetism in PbMoO3: The role of electronic correlation

    Science.gov (United States)

    Nazir, Safdar

    2017-11-01

    We theoretically investigate the electronic and magnetic properties of the recently reported cubic and orthorhombically (Ortho.) distorted phases of PbMoO3, a 4d transition-metal perovskite oxide with almost half-filled t2g states. Our spin-polarized bare generalized gradient approximation results exhibit that the cubic phase is of low energy structure than the Ortho. one. However, on-site Coulomb repulsion in the range of 3.3 eV ≤ Ueff ≤ 4.5 eV inclusion on Mo 4d orbitals reveals that at each value of Ueff, the Ortho. phase is more stable than the cubic one and with the increase in Ueff, both phases show more stability. We find a non-magnetic n-type conductivity with a high charge carrier density of ˜1022 cm-3 in both phases. Interestingly, a non-magnetic to magnetic phase transition occurs at Ueff = 3.8 eV and 3.5 eV for the cubic and Ortho. phases, respectively. Moreover, a half-metallic ferromagnetic state is obtained at Ueff = 4.1 eV and 4.3 eV for the cubic and Ortho. phases, respectively. Calculations also indicate a strong orbital hybridization between Pb 6p and Mo 4d, with a significant contribution of O 2p states. All findings are confirmed by the Yukawa screened Perdew-Burke-Ernzerhof 0 (YS-PBE0) hybrid functional. This work provokes further experimental investigations of magnetic properties of PbMoO3.

  9. Heavy metals (Hg,Cd,Pb,Ni,Cu) concentrations in Euryglossa orientalis and sediments from Khur-e-Musa Creek in Khuzestan Province

    OpenAIRE

    Parvaneh, M.; Khaivar, N.; Nikpour, Y.; Nabavi, S.M.

    2011-01-01

    Heavy metals contamination (Hg,Cd,Pb,Ni,Cu) in muscle of the fish Euryglossa orientalis and in sediments was assessed in 2007 in Khur-e-Musa Creek (Ahmadi and Ghanam). In total, 30 fish specimens and 18 sediment samples were collected and analyzed. Flame Atomic Absorption Spectrophotometer was used to determine contamination of the specimens with Cd, Pb, Ni, Cu, and cold vapor method was applied for Hg. Results showed 2.35, 0.99, 1.32, 14.48 and 5.71µg/g dry weight of the fish for Hg, Cd, Pb,...

  10. Heavy metals in Sinú river, department of Córdoba, Colombia, South America

    Directory of Open Access Journals (Sweden)

    John Jairo Feria

    2010-01-01

    Full Text Available Se evaluaron las concentraciones de Al, Fe, Mn, Zn, Cu, Ni, Cr, Hg, Pb y Cd en sedimentos superficiales del río Sinú. Las muestras se recolectaron en 10 sitios de muestreo aguas abajo del embalse de Urrá I, considerándose dos períodos de muestreo, uno en época de lluvia y otro en época seca. Las concentraciones de los metales se determinaron por espectrofotometría de absorción atómica o por voltametría y se normalizaron con respecto a las concentraciones del aluminio, por ser un metal conservativo. Se observó una fuerte correlación entre las concentraciones de Cu, Ni, Cr y Zn para ambos períodos muestreados, sugiriendo un origen común. Adicionalmente, el factor de enriquecimiento indicó para todos los elementos evaluados, a excepción del Fe, concentraciones enriquecidas de metales pesados en los sedimentos. En los sitios que reciben el impacto de los suelos inundados, existe una mayor concentración de metales en los sedimentos, comparada con otras zonas de la cuenca, lo cual se asocia con la reducción de sulfatos y la formación de sulfuros y la subsecuente liberación y disponibilidad de metales pesados.

  11. Radionuclides and heavy metal contents in phosphogypsum samples in comparison to cerrado soils Conteúdo de radionuclídeos e metais pesados em amostras de fosfogesso, comparativamente ao de solos de cerrado

    Directory of Open Access Journals (Sweden)

    Vanusa Maria Feliciano Jacomino

    2009-10-01

    Full Text Available Phosphogysum (PG or agricultural gypsum, a solid waste from the phosphate fertilizer industry, is used as soil amendment, especially on soils in the Cerrado region, in Brazil. This material may however contain natural radionuclides and metals which can be transferred to soils, plants and water sources. This paper presents and discusses the results of physical and chemical analyses that characterized samples of PG and compares them to the results found in two typical soils of the Cerrado, a clayey and sandy one. These analyses included: solid waste classification, evaluation of organic matter content and of P, K, Ca, Mg, and Al concentrations and of the mineralogical composition. Natural radionuclides and metal concentrations in PG and soil samples were also measured. Phosphogypsum was classified as Class II A - Not Dangerous, Not Inert, Not Corrosive and Not Reactive. The organic matter content in the soil samples was low and potential acidity high. In the mean, the specific 226Ra activity in the phosphogypsum samples (252 Bq kg-1 was below the maximum level recommended by USEPA, which is 370 Bq kg-1 for agricultural use. In addition, this study verified that natural radionuclides and metals concentrations in PG were lower than in the clayey Oxisol of Sete Lagoas, Minas Gerais, Brazil. These results indicated that the application of phosphogypsum as soil amendment in agriculture would not cause a significant impact on the environment.O fosfogesso ou "gesso agrícola" - um resíduo sólido da indústria de produção de fertilizantes fosfatados - é usado como condicionador de solos, em especial do solo da região do Cerrado, Brasil. Entretanto, esse material contém radionuclídeos naturais e metais que podem ser transferidos para o solo, as plantas e o lençol freático. Neste trabalho são apresentados e discutidos os resultados de análises químicas e físicas para caracterização do fosfogesso e compara seus resultados com aqueles

  12. Levels and ages of selenium and metals in sedimentary cores of Ise Bay as determined by 210-Pb dating technique

    International Nuclear Information System (INIS)

    Itoh, K.; Chikuma, M.; Tanaka, H.

    1987-01-01

    Ise Bay is connected with estuaries of Nagoya harbor which is one of the most active industrial areas in Japan. Nagoya harbor estuaries are recipient of a large quantity of municipal and industrial discharge. The land boundaries of estuaries are sites of the manufacturing industries and they are utilized by oil tankers and cargo vessels. Accumulation of various kinds of metal such as selenium, mercury, zinc, copper, lead, and chromium have occurred in sediments for many years. The authors have carried out an extensive investigation on the selenium pollution of sea water and sediments of Nagoya harbor estuaries. The input of selenium to Ise Bay has occurred ever since the industrial activity was established in Nagoya city. Investigators have reported the sedimentary record of metals of Tokyo Bay, Osaka Bay and Seto Inland Sea. Some investigators reported the pollution caused by polynuclear aromatic hydrocarbon in sediments of Ise Bay, but did not mention metals. The authors determined metals including selenium in sedimentary core samples. The ages of those samples were already estimated by 210-Pb dating technique

  13. The Content of Heavy Metals (Cu, Zn, Cr, Ni, Pb in The Soil Near The Arterial Roads in Wroclaw (Poland

    Directory of Open Access Journals (Sweden)

    Sobczyk Karolina

    2017-01-01

    Full Text Available The concentrations of heavy metals in soils along the motorway bypass of Wroclaw (AOW and the Eastern Ring Road of Wroclaw (WOW, Poland, have been determined. The soil samples were collected from the levels of 0-25 cm within 2 m from the edge of the road. The mineralizates were prepared in HNO3, 60%, using the Microwave Digestion System. The content of Cu, Zn, Cr, Ni and Pb in soils were determined using FAAS method. The physicochemical parameters, the conductivity and pH of the soil solutions were measured to evaluate the salinity of the soils and their active and exchangeable acidity. The pollution indexes (WN showing the enrichment of soils in metals have been determined. Excess of metal concentrations in soils compared to the geochemical background in uncontaminated soils of Poland has been observed. Permissible concentrations of heavy metals relative to the standard for soils, according to the Polish Ministry of Environment Regulation from September 1st, 2016, have not been exceeded.

  14. Mechanochemical synthesis, structure and properties of lead containing alkaline earth metal fluoride solid solutions MxPb1-xF2 (M = Ca, Sr, Ba)

    Science.gov (United States)

    Heise, M.; Scholz, G.; Düvel, A.; Heitjans, P.; Kemnitz, E.

    2018-03-01

    The paper deals with the mechanochemical synthesis of lead containing alkaline earth metal fluoride solid solutions MxPb1-xF2 (M = Ca, Sr, Ba) by high-energy ball milling. Several metal precursors and fluorinating agents were tested for synthesizing M0.5Pb0.5F2. Metal acetates and ammonium fluoride as precursors show the most promising results and were therefore used for the formation of MxPb1-xF2 with different metal cationic ratios. The characterization of the local fluorine coordination and the crystal structure was performed by 19F MAS NMR spectroscopy and X-ray diffraction. Additional calculations of 19F chemical shifts using the superposition model allow a deeper insight into the local structure of the compounds. The fluoride ion conductivity was followed by temperature dependent DC conductivity measurements. Significantly higher conductivities were found in comparison with those of the corresponding binary fluorides. The highest values were observed for samples with high lead content M0.25Pb0.75F2, bearing in mind the much higher conductivity of PbF2 compared to MF2.

  15. Sub-cellular partitioning of Zn, Cu, Cd and Pb in the digestive gland of native Octopus vulgaris exposed to different metal concentrations (Portugal)

    International Nuclear Information System (INIS)

    Raimundo, J.; Vale, C.; Duarte, R.; Moura, I.

    2008-01-01

    Concentrations of Zn, Cu, Cd and Pb and their sub-cellular distributions were determined in composite samples of digestive glands of the common octopus, Octopus vulgaris caught from two areas of the Portuguese coast characterised by contrasting metal contamination. Minor contents of Zn (1%), Cu (2%), Cd (6%) and Pb (7%) were found in the insoluble fraction, consisting of nuclei, mitochondria, lysosomes and microsome operationally separated from the whole digestive gland through a sequential centrifugation. A tendency for linear relationships between metal concentrations in nuclei, mitochondria, lysosomes and whole digestive gland was observed. These relationships suggest that despite low metal content organelles responded to the increasing accumulated metals, which means that detoxifying mechanism in cytosol was incomplete. Poorer correlations between microsome and whole digestive gland did not point to metal toxicity in the analysed compartments. However, the high accumulated Cd indicated that O. vulgaris is an important vehicle of this element to its predators in the coastal environment

  16. Band gap tuning and fluorescence properties of lead sulfide Pb0.9A0.1S (A: Fe, Co, and Ni) nanoparticles by transition metal doping

    Science.gov (United States)

    Parveen, Azra; Agrawal, Shraddha; Azam, Ameer

    2018-02-01

    Transition metal-doped lead sulfide nanoparticles (PbS-NPs) were synthesized by co-precipitation method. The crystallite phase and morphological studies were carried out by X-ray diffraction (XRD) and transmission electron microscopy (TEM). Optical studies were performed by UV-Visible absorption, fluorescence emission spectroscopy and Fourier transforms infrared spectroscopy (FTIR). XRD analysis reveals that the pure and transition metal-doped PbS- NPs have a single crystalline phase with cubic structure devoided of any other secondary phase. The notable effect on optical absorbance and band gap was observed with transition metal doping in lead sulphide. The optical energy band gap values were found to increase with the doping of transition metal. UV-Visible absorption and fluorescence emission spectra display a blue shift with subsequent transition metal doping which may arise due to quantum confinement effect making it worth for having applications in optoelectronic devices.

  17. Application of a bacterial extracellular polymeric substance in heavy metal adsorption in a co-contaminated aqueous system Aplicação de uma substância polimerica extracelular bacteriana na absorção de metais pesados em um sistema aquoso co-contaminado

    Directory of Open Access Journals (Sweden)

    Paula Salles de Oliveira Martins

    2008-12-01

    Full Text Available The application of a bacterial extracellular polymeric substance (EPS in the bioremediation of heavy metals (Cd, Zn and Cu by a microbial consortium in a hydrocarbon co-contaminated aqueous system was studied. At the low concentrations used in this work (1.00 ppm of each metal, it was not observed an inhibitory effect on the cellular growing. In the other hand, the application of the EPS lead to a lower concentration of the free heavy metals in solution, once a great part of them is adsorbed in the polymeric matrix (87.12% of Cd; 19.82% of Zn; and 37.64% of Cu, when compared to what is adsorbed or internalized by biomass (5.35% of Cd; 47.35% of Zn; and 24.93% of Cu. It was noted an increase of 24% in the consumption of ethylbenzene, among the gasoline components that were quantified, in the small interval of time evaluated (30 hours. Our results suggest that, if the experiments were conducted in a larger interval of time, it would possibly be noted a higher effect in the degradation of gasoline compounds. Still, considering the low concentrations that were evaluated, it is possible that a real system could be bioremediated by natural attenuation process, demonstrated by the low effect of those levels of contaminants and co-contaminants over the naturally present microbial consortium.A aplicação de uma substância polimérica extracelular (EPS bacteriana na biorremediação de metais pesados (Cd, Zn e Cu por um consórcio microbiano em um sistema aquoso co-contaminado com hidrocarbonetos foi estudada. Nas baixas concentrações usadas neste trabalho (1,00 ppm de cada metal, não foi observado um efeito inibitório no crescimento celular. Por outro lado, a aplicação da EPS bacteriana levou a uma menor concentração de metais livres em solução, uma vez que grande parte destes fica adsorvido na matriz polimérica (87,12% de Cd; 19,82% de Zn; e 37,64% de Cu quando comparado ao que é adsorvido ou interiorizado pela biomassa (5,35% de Cd; 47

  18. Electric Field Tuning Non-volatile Magnetism in Half-Metallic Alloys Co2FeAl/Pb(Mg1/3Nb2/3)O3-PbTiO3 Heterostructure

    Science.gov (United States)

    Dunzhu, Gesang; Wang, Fenglong; Zhou, Cai; Jiang, Changjun

    2018-03-01

    We reported the non-volatile electric field-mediated magnetic properties in the half-metallic Heusler alloy Co2FeAl/Pb(Mg1/3Nb2/3)O3-PbTiO3 heterostructure at room temperature. The remanent magnetization with different applied electric field along [100] and [01-1] directions was achieved, which showed the non-volatile remanent magnetization driven by an electric field. The two giant reversible and stable remanent magnetization states were obtained by applying pulsed electric field. This can be attributed to the piezostrain effect originating from the piezoelectric substrate, which can be used for magnetoelectric-based memory devices.

  19. Bioaccumulation of metals (Cd, Cu, Ni, Pb and Zn) in suspended cultures of blue mussels exposed to different environmental conditions

    Science.gov (United States)

    Maar, Marie; Larsen, Martin Mørk; Tørring, Ditte; Petersen, Jens Kjerulf

    2018-02-01

    Farming of suspended mussels is important for generating high protein food and animal feed or for removing nutrients in eutrophic systems. However, the harvested mussels must not be severely contaminated by pollutants posing a potential health risk for the consumers. The present study estimated the bioaccumulation of cadmium, copper, nickel, lead and zinc in suspended blue mussels (Mytilus edulis L.) in the Limfjorden, Denmark, based on observations and modelling. Modelling was used to assess the suitability of suspended blue mussels as animal feed and food products at sea water metal concentrations corresponding to Good Ecological Status (GES) in the European Union Water Framework Directive (WFD) and in future climate change scenarios (higher metal concentrations and higher temperatures). For this purpose, GES is interpreted as good chemical status for the metals using the Environmental Quality Standards (EQS) defined in the WFD priority substance daughter directives. Observations showed that suspended mussels were healthy with respect to metal pollution and generally less polluted than benthic mussels due to the smaller contact with the contaminated sediment. The model results showed that the WFD targets for Cd, Ni and Pb are not protective with respect to marine mussel production and probably should be reduced for marine waters. Climate changes may increase the metal contamination of mussels, but not to any critical level at the relatively unpolluted study sites. In conclusion, WFD targets should be revised to assure that the corresponding body burdens of metals in mussels are below the safety limits according to the EU Directives and the Norwegian classification for animal feed and food production.

  20. Heavy metals and Pb isotopic composition of aerosols in urban and suburban areas of Hong Kong and Guangzhou, South China—Evidence of the long-range transport of air contaminants

    Science.gov (United States)

    Lee, Celine S. L.; Li, Xiang-Dong; Zhang, Gan; Li, Jun; Ding, Ai-Jun; Wang, Tao

    Rapid urbanization and industrialization in South China has placed great strain on the environment and on human health. In the present study, the total suspended particulate matter (TSP) in the urban and suburban areas of Hong Kong and Guangzhou, the two largest urban centres in South China, was sampled from December 2003 to January 2005. The samples were analysed for the concentrations of major elements (Al, Fe, Mg and Mn) and trace metals (Cd, Cr, Cu, Pb, V and Zn), and for Pb isotopic composition. Elevated concentrations of metals, especially Cd, Pb, V and Zn, were observed in the urban and suburban areas of Guangzhou, showing significant atmospheric trace element pollution. Distinct seasonal patterns were observed in the heavy metal concentrations of aerosols in Hong Kong, with higher metal concentrations during the winter monsoon period, and lower concentrations during summertime. The seasonal variations in the metal concentrations of the aerosols in Guangzhou were less distinct, suggesting the dominance of local sources of pollution around the city. The Pb isotopic composition in the aerosols of Hong Kong had higher 206Pb/ 207Pb and 208Pb/ 207Pb ratios in winter, showing the influence of Pb from the northern inland areas of China and the Pearl River Delta (PRD) region, and lower 206Pb/ 207Pb and 208Pb/ 207Pb ratios in summer, indicating the influence of Pb from the South Asian region and from marine sources. The back trajectory analysis showed that the enrichment of heavy metals in Hong Kong and Guangzhou was closely associated with the air mass from the north and northeast that originated from northern China, reflecting the long-range transport of heavy metal contaminants from the northern inland areas of China to the South China coast.

  1. Assessment of Individual and Combined Toxicities of Four Non-Essential Metals (As, Cd, Hg and Pb) in the Microtox Assay

    Science.gov (United States)

    Ishaque, Ali B.; Johnson, Linda; Gerald, Tonya; Boucaud, Dwayne; Okoh, Joseph; Tchounwou, Paul B.

    2006-01-01

    Although most researches with non-essential metals (NEMs) have been done with single or individual metals, in reality, organisms are often exposed to multiple contaminants at the same time through the air, food and water. In this study, we tested the toxicity of four NEMs, As, Cd, Pb, and Hg, individually and as a composite mixture using the microtox bioassay. This assay uses the reduction of bioluminescence of the bacterium Vibrio fischeri as a measure of toxicity. The concentrations of each chemical in the mixture were based on multiples of their maximum contaminant levels (MCLs) set by the U.S. EPA. The highest concentration of exposure was 20 times the MCL, which translated into 200, 100, 40 and 300 ppb for As, Cd, Hg and Pb, respectively. The ratio for the mixture from these concentrations was 10:5:2:15 for As, Cd, Hg and Pb, respectively. Among the individual metals tested, the ranking of toxicity was Hg>Pb>Cd>As based on the EC50 values of 109, 455, 508 and 768 ppb for Hg, Pb, Cd and As, respectively. The EC50 for the composite mixture was 495% MCL which translated into nominal concentrations of 49, 25, 10 and 74 ppb for As, Cd, Hg, and Pb, respectively. Overall, the EC50 value of each NEM within the mixture was lower than the EC50 of the individual chemical; an evidence of synergism for the mixture. The individual toxic units (TU) were 0.06, 0.05, 0.09, and 0.16 for As, Cd Hg, and Pb, respectively and the summed toxic unit (TU) was 0.37 (less than 1). This study provides needed scientific data necessary for carrying out complete risk assessment of As, Cd, Hg, and Pb mixtures of some priority compounds. PMID:16823084

  2. Assessment of Individual and Combined Toxicities of Four Non-Essential Metals (As, Cd, Hg and Pb in the Microtox Assay

    Directory of Open Access Journals (Sweden)

    Paul B. Tchounwou

    2006-03-01

    Full Text Available Although most researches with non-essential metals (NEMs have been done with single or individual metals, in reality, organisms are often exposed to multiple contaminants at the same time through the air, food and water. In this study, we tested the toxicity of four NEMs, As, Cd, Pb, and Hg, individually and as a composite mixture using the microtox bioassay. This assay uses the reduction of bioluminescence of the bacterium Vibrio fischeri as a measure of toxicity. The concentrations of each chemical in the mixture were based on multiples of their maximum contaminant levels (MCLs set by the U.S. EPA. The highest concentration of exposure was 20 times the MCL, which translated into 200, 100, 40 and 300 ppb for As, Cd, Hg and Pb, respectively. The ratio for the mixture from these concentrations was 10:5:2:15 for As, Cd, Hg and Pb, respectively. Among the individual metals tested, the ranking of toxicity was Hg>Pb>Cd>As based on the EC50 values of 109, 455, 508 and 768 ppb for Hg, Pb, Cd and As, respectively. The EC50 for the composite mixture was 495% MCL which translated into nominal concentrations of 49, 25, 10 and 74 ppb for As, Cd, Hg, and Pb, respectively. Overall, the EC50 value of each NEM within the mixture was lower than the EC50 of the individual chemical; an evidence of synergism for the mixture. The individual toxic units (TU were 0.06, 0.05, 0.09, and 0.16 for As, Cd Hg, and Pb, respectively and the summed toxic unit (TU was 0.37 (less than 1. This study provides needed scientific data necessary for carrying out complete risk assessment of As, Cd, Hg, and Pb mixtures of some priority compounds.

  3. Subcellular partitioning of non-essential trace metals (Ag, As, Cd, Ni, Pb, and Tl) in livers of American (Anguilla rostrata) and European (Anguilla anguilla) yellow eels

    Energy Technology Data Exchange (ETDEWEB)

    Rosabal, Maikel [Institut national de la recherche scientifique, Centre Eau Terre et Environnement (INRS–ETE), 490 de la Couronne, Québec (Québec) G1K 9A9 (Canada); Pierron, Fabien [Université de Bordeaux, UMR EPOC CNRS 5805, F-33400 Talence (France); CNRS, EPOC, UMR 5805, F-33400 Talence (France); Couture, Patrice [Institut national de la recherche scientifique, Centre Eau Terre et Environnement (INRS–ETE), 490 de la Couronne, Québec (Québec) G1K 9A9 (Canada); Baudrimont, Magalie [Université de Bordeaux, UMR EPOC CNRS 5805, F-33400 Talence (France); CNRS, EPOC, UMR 5805, F-33400 Talence (France); Hare, Landis [Institut national de la recherche scientifique, Centre Eau Terre et Environnement (INRS–ETE), 490 de la Couronne, Québec (Québec) G1K 9A9 (Canada); Campbell, Peter G.C., E-mail: peter.campbell@ete.inrs.ca [Institut national de la recherche scientifique, Centre Eau Terre et Environnement (INRS–ETE), 490 de la Couronne, Québec (Québec) G1K 9A9 (Canada)

    2015-03-15

    Highlights: • Handling of hepatic metals consistently involved cytosolic, thermostable ligands. • Granule-like fractions are also involved in the detoxification of Ni, Pb, and Tl. • Despite these sequestration mechanisms, metal detoxification is incomplete. • Along the metal gradient, concentrations increase in metal-sensitive fractions. • This increase could represent a toxicological risk for the yellow eels. - Abstract: We determined the intracellular compartmentalization of the trace metals Ag, As, Cd, Ni, Pb, and Tl in the livers of yellow eels collected from the Saint Lawrence River system in Canada (Anguilla rostrata) and in the area of the Gironde estuary in France (Anguilla anguilla). Differential centrifugation, NaOH digestion and thermal shock were used to separate eel livers into putative “sensitive” fractions (heat-denatured proteins, mitochondria and microsomes + lysosomes) and detoxified metal fractions (heat-stable peptides/proteins and granules). The cytosolic heat-stable fraction (HSP) was consistently involved in the detoxification of all trace metals. In addition, granule-like structures played a complementary role in the detoxification of Ni, Pb, and Tl in both eel species. However, these detoxification mechanisms were not completely effective because increasing trace metal concentrations in whole livers were accompanied by significant increases in the concentrations of most trace metals in “sensitive” subcellular fractions, that is, mitochondria, heat-denatured cytosolic proteins and microsomes + lysosomes. Among these “sensitive” fractions, mitochondria were the major binding sites for As, Cd, Pb, and Tl. This accumulation of non-essential metals in “sensitive” fractions likely represents a health risk for eels inhabiting the Saint Lawrence and Gironde environments.

  4. Contamination assessment of heavy metals in the soils around Khouzestan Steel Company (KSC (Ni, Mn, Pb, Fe, Zn, Cr

    Directory of Open Access Journals (Sweden)

    Fatemeh hormozi Nejad

    2017-02-01

    Full Text Available Introduction Soil plays a vital role in human life as the very survival of mankind is tied to the preservation of soil productivity (Kabata- Pendies and Mukherjee, 2007. The purpose of this study is the assessment of heavy metal contamination (Zn, Mn, Pb, Fe, Ni, Cr of the soil around the Khuzestan Steel Complex. Materials and methods For this purpose, 13 surface soil samples (0-10 cm were taken. Also a control sample was taken from an area away from the steel complex. The coordinates of each point were recorded by Global Positioning System (GPS. The samples were transferred to the laboratory and then were air dried at room temperature for 72 hours. Then they were sieved through a 2mm sieve for determining physical and chemical parameters (soil texture, pH, OC, and a 63-micron sieve for measurement of heavy metal concentration. pH was measured using a calibrated pH meter at a 2: 1 mixture (soil: water, and soil texture was determined using a hydrometer. The amount of organic matter was measured using the Valkey black method (Chopin and Alloway, 2007. After preparation of the samples in the laboratory, the samples were analyzed using the ICP-OES method to assess concentration of heavy metals. Measurement of heavy metals concentration was carried out at the Zar azma laboratory in Tehran. To ensure the accuracy of the analysis of soil samples, replicate samples were also sent to the laboratory. In order to assess the heavy metal pollution in the soil samples, different indices including contamination factor (CF, contamination degree (Cd, anthropogenic enrichment percent (An%, and saturation degree of metals (SDM were calculated. Discussion In addition, the mean concentrations of heavy metals in soil samples were compared to the concentration of these metals in Control Sample and unpolluted soil standard. Measurement of soil pH showed that the soil has a tendency to alkalinity. Also, soil texture is sandy loam (Moyes, 2011. The results showed that

  5. The Environmentally Sound Aquaculture Strategies Based on Bioaccumulation of Heavy Metal of Lead (Pb) on Seaweed of Gracilaria verrucosa on Aquaculture Areas of MuararejaVillage, Tegal City

    Science.gov (United States)

    Nurjanah; Ambariyanto; Supriharyono; Yulianto, Bambang

    2018-02-01

    Community activities such as industry, trade, animal husbandry and agriculture and ssettlements resulting in heavy metals of lead (Pb) can be accumulated in water, sediment and seaweed Gracillaria verrucosa. It can contaminate ponds and affect aquaculture activities in Tegal. Seaweed Gracilaria verrucosa is afisheries commodity that has economical value and cultivated in the area of aquaculture MuararejaTegal. It can serve as fitoremedian that will help reduce the impact of heavy metal pollution due to its ability to accumulate pollutants. The objective of this study was to analyze bioaccumulation of heavy metals of lead (Pb) and its relationship with water quality management in order to develop seaweed cultivation of Gracillaria verrucosa in ponds in the area of aquaculture MuararejaTegal. The method used in this study is a survey, analysis of heavy metals of lead (Pb) in pond water, sediment and seaweed using Atomic Absorption Spectrophotometer (AAS) and the data were analyzed by descriptive quantitative. Bioconcentration of lead (Pb) during the dry season in pond water, sediment and seaweed Gracillaria verrucosa was measured from 0.003 to 0.025 ppm,5.543 to 23.699 ppm and 0.209 to 0.326 ppm respectively. While in the rainy season bioconcentration of lead (Pb) are from 0.003 to 0.015 ppm, sediment from 6.377 to 9.858 ppm and 0.209 to 0.326 ppm respectively. Bioconcentration of Pb in dry season was higher than in the rainy season and the biggest bioconcentration was found in the sediment pond waters. Pb bioaccumulation low and still below the quality standards of the Ministry of Environment decision 51 of 2004 so that the product is safe for consumption.

  6. comparative study with commercial rootstocks to determine the tolerance to heavy metal (Pb in the drought and salt stress tolerant eggplant breeding lines

    Directory of Open Access Journals (Sweden)

    Mevlüde Nur TOPAL

    2017-06-01

    Full Text Available Negative effects of heavy metals on plants are peroxidation of lipids in cell membranes, production of free oxygen radicals, disorders in photosynthesis, damages in DNAs and as a result death of the cell. Plant development, productivity and quality of the fruits are decreased in the plants that are exposed to Pb stress which is one of the most toxic heavy metals. Usage of rootstocks which is mainly used against biotic stress conditions also seems to be defined as a solution to abiotic stress conditions such as heavy metal stresses. In eggplant production, wild species and hybrids are used as rootstocks against soil based pathogens and nematode. Reactions of improvement lines derived from local gene resources for rootstock improvement to heavy metal stress which is one of the abiotic stresses were determined. While determining the resistance against Pb stress, commercially used eggplant rootstocks are compared. In this study 4 eggplant cultivars (S. melongena: Burdur Bucak, Mardin Kızıltepe, Artvin Hopa and Kemer whose resistance potential against salt and drought stresses had been previously revealed and 6 rootstocks of wild eggplant species or hybrids (AGR-703, Doyran, Hawk, Hikyaku, Köksal-F1 and Vista-306 were tested against Pb stress. Eggplant seedlings were applied to 0, 150 and 300 ppm Pb solutions (Pb(NO32 during 4-5 true leaf stage. 20 days after the stress application wet and dry weight of green parts and roots, height of the body part and leaf areas were measured. Pb tolerance of Köksal F1 and AGR703 rootstocks were higher than other commercial rootstocks. Mardin Kızıltepe and Burdur Merkez genotypes which have high tolerances against abiotic stress gave lower values with respect to Artvin Hopa and Kemer which are sensitive genotypes and many other rootstocks while comparing the reduction ratios of stress signs such as shoot fresh weight and shoot length according to control under Pb stress.

  7. Removal of heavy metals (Pb 2+ , Cu 2+ and Cr 3+ ) from aqueous ...

    African Journals Online (AJOL)

    The toxicity of metal pollution is slow and interminable, as these metal ions are non bio-degradable. The aim of this study was to investigate the ... and subsequently used for adsorption experiments. Adsorption studies were performed by batch experiments as a function of process parameters (such as sorption time and pH).

  8. Heavy metals (Cd, Pb, Cu, Zn) in mudfish and sediments from three ...

    African Journals Online (AJOL)

    driniev

    2004-04-02

    Apr 2, 2004 ... where sedimentation processes act as a sink for metals (Harding and Whitton, 1978). Heavy metals such as lead, copper, nickel and zinc are usually deposited in sediments not deeper than 15 cm. (Ochsenbein et al., 1983; Santos Bermejo et al., 2003). The mine drainage from gold and uranium recovery ...

  9. Sedimentation rates and trace metal input history in intertidal sediments from San Simon Bay (Ria de Vigo, NW Spain) derived from 210Pb and 137Cs chronology

    International Nuclear Information System (INIS)

    Alvarez-Iglesias, Paula; Quintana, Begona; Rubio, Belen; Perez-Arlucea, Marta

    2007-01-01

    210 Pb and 137 Cs dating methods, accompanied by a high-resolution geochemical study, were applied to intertidal sediments containing both fine and coarse-grained particles and also, anthropogenic Pb in order to establish sedimentation rates and historical trends in heavy metal input. Sedimentation rates were established according to the 'Constant Flux:Constant Sedimentation' (CF:CS) 210 Pb dating model, which was preferred rather than the 'Constant Rate of Supply-Minimum Variance' (CRS-MV) model. Variations in sediment grain-size were accounted for by application of several normalization procedures. Al was selected for grain-size correction. Corrected sedimentation rates obtained from 210 Pb dating were corroborated through a second independent radionuclide tracer and by comparison of peak trace metal inputs into the environment with peaks in the sediment. The Chernobyl maximum was identified in the normalized 137 Cs activity profile. Sedimentation rates of 6.2 ± 1.2 mm y -1 and 3.1 ± 0.5 mm y -1 for the upper (two muddy layers) and 6.0 ± 2.0 mm y -1 for the lower (sandy) intertidal mud flat deposits of San Simon Bay were determined. According to the established chronology, human-induced environmental changes were detected in total metal concentrations (Cu, Pb, Zn) and in sediment grain-size and composition

  10. Extratores para avaliação da disponibilidade de metais pesados em solos adubados com vermicomposto de lixo urbano

    Directory of Open Access Journals (Sweden)

    Mantovani José Ricardo

    2004-01-01

    Full Text Available Os objetivos deste trabalho foram selecionar extratores químicos para avaliação da disponibilidade de metais pesados em solos tratados com vermicomposto de lixo urbano e calcário, e verificar os efeitos destes insumos nos teores disponíveis de metais pesados em solos. Foram realizados dois ensaios em casa de vegetação. Em um deles, foi usado um Latossolo Vermelho distroférrico e, no outro, um Argissolo Vermelho-Amarelo eutrófico, e, em ambos, a alface foi utilizada como planta-teste. O delineamento experimental de cada experimento foi em blocos ao acaso, em esquema fatorial 5x5, com quatro repetições, combinando-se doses de corretivos da acidez para elevar a saturação por bases a 40%, 50%, 60%, 70% e 80%, e o equivalente a 0, 25, 50, 75 e 100 t ha-1 de vermicomposto. Os extratores DTPA e Mehlich 3 detectam aumento nos teores de Ni, Pb, Cu e Zn em solos argiloso e arenoso adubados com vermicomposto de lixo urbano. O DTPA é mais eficiente que os extratores Mehlich 1 e Mehlich 3 na avaliação das alterações nos teores disponíveis dos metais pesados provocadas pelas mudanças no pH no solo argiloso. O Mn é o único elemento cuja disponibilidade é avaliada eficientemente tanto no solo argiloso como no arenoso, pelo DTPA.

  11. U-Pb age for some base-metal sulfide deposits in Ireland: genetic implications for Mississippi Valley-type mineralization

    International Nuclear Information System (INIS)

    Duane, M.J.; Welke, H.J.; Allsopp, H.L.

    1986-01-01

    Evidence is presented that links the timing of vein-type (Cu-Ag(U)) to stratiform Mississippi Valley-type (MVT, Pb-Zn) ore events in Ireland. The rare occurrence of pitchblende, coffinite(?), and brannerite mineralization, which is regarded as a precursor component to the sulfide mineralization in the Gortdrum deposit (Ireland), provides the first direct radiometric dating tool for these carbonate-hosted deposits. The U-Pb (340 +25/-20 Ma) and Pb-Pb (359 +/- 26 Ma) whole-rock ages constrain the uranium and base-metal mineralizing events to the Early Carboniferous. The data support a model according to which MVT and earlier uranium mineralization stages of some major ore bodies resulted from fracturing coincident with large basin-dewatering events. The Pb-Pb and concordia data are consistent with an Early Carboniferous age for the mineralization at Gortdrum and agree closely with a previously published Rb-Sr age of 359 +/- 22 Ma, obtained for Missouri glauconites. Furthermore, other comparative geologic data from Ireland and from North American MVT mineral provinces support a model of Pb-Zn-Cu(U) mobilization on a regional scale that implicates the later closing stages of the proto-Atlantic. 40 references, 3 figures, 1 table

  12. An ultra-clean technique for accurately analysing Pb isotopes and heavy metals at high spatial resolution in ice cores with sub-pg g(-1) Pb concentrations.

    Science.gov (United States)

    Burn, Laurie J; Rosman, Kevin J R; Candelone, Jean-Pierre; Vallelonga, Paul; Burton, Graeme R; Smith, Andrew M; Morgan, Vin I; Barbante, Carlo; Hong, Sungmin; Boutron, Claude F

    2009-02-23

    Measurements of Pb isotope ratios in ice containing sub-pg g(-1) concentrations are easily compromised by contamination, particularly where limited sample is available. Improved techniques are essential if Antarctic ice cores are to be analysed with sufficient spatial resolution to reveal seasonal variations due to climate. This was achieved here by using stainless steel chisels and saws and strict protocols in an ultra-clean cold room to decontaminate and section ice cores. Artificial ice cores, prepared from high purity water were used to develop and refine the procedures and quantify blanks. Ba and In, two other important elements present at pg g(-1) and fg g(-1) concentrations in Polar ice, were also measured. The final blank amounted to 0.2+/-0.2 pg of Pb with (206)Pb/(207)Pb and (208)Pb/(207)Pb ratios of 1.16+/-0.12 and 2.35+/-0.16, respectively, 1.5+/-0.4 pg of Ba and 0.6+/-2.0 fg of In, most of which probably originates from abrasion of the steel saws by the ice. The procedure was demonstrated on a Holocene Antarctic ice core section and was shown to contribute blanks of only approximately 5%, approximately 14% and approximately 0.8% to monthly resolved samples with respective Pb, Ba and In concentrations of 0.12 pg g(-1), 0.3 pg g(-1) and 2.3 fg g(-1). Uncertainties in the Pb isotopic ratio measurements were degraded by only approximately 0.2%.

  13. Corrosion behavior of Al-Fe-sputtering-coated steel, high chromium steels, refractory metals and ceramics in high temperature Pb-Bi

    International Nuclear Information System (INIS)

    Abu Khalid, Rivai; Minoru, Takahashi

    2007-01-01

    Corrosion tests of Al-Fe-coated steel, high chromium steels, refractory metals and ceramics were carried out in high temperature Pb-Bi at 700 C degrees. Oxygen concentrations in this experiment were 6.8*10 -7 wt.% for Al-Fe-coated steels and 5*10 -6 wt.% for high chromium steels, refractory metals and ceramics. All specimens were immersed in molten Pb-Bi in a corrosion test pot for 1.000 hours. Coating was done with using the unbalanced magnetron sputtering (UBMS) technique to protect the steel from corrosion. Sputtering targets were Al and SUS-304. Al-Fe alloy was coated on STBA26 samples. The Al-Fe alloy-coated layer could be a good protection layer on the surface of steel. The whole of the Al-Fe-coated layer still remained on the base surface of specimen. No penetration of Pb-Bi into this layer and the matrix of the specimen. For high chromium steels i.e. SUS430 and Recloy10, the oxide layer formed in the early time could not prevent the penetration of Pb-Bi into the base of the steels. Refractory metals of tungsten (W) and molybdenum (Mo) had high corrosion resistance with no penetration of Pb-Bi into their matrix. Penetration of Pb-Bi into the matrix of niobium (Nb) was observed. Ceramic materials were SiC and Ti 3 SiC 2 . The ceramic materials of SiC and Ti 3 SiC 2 had high corrosion resistance with no penetration of Pb-Bi into their matrix. (authors)

  14. CHEMICAL DETERMINATION OF HEAVY METALS IN PB AND ZN CONCENTRATES OF TREPÇA (KOSOVO AND CORRELATIONS COEFFI CIENTS STUDY BETWEEN CHEMICAL DATA

    Directory of Open Access Journals (Sweden)

    Fatbardh Gashi

    2017-03-01

    Full Text Available Kosovo ore deposits are located in the Trepça belt which extends for over 80 km. The concentrate produced by the flotation process of the Trepça metallurgical corporation contains a considerable quantity of valuable metals, such as Pb, Zn, Fe and minor accompanying metals such as Cd, Cu, As, Sb, Bi, Ag, Au, etc. The subject of this work was to assess the concentration of major and minor metals in lead and zinc concentrates of Trepça and to study the correlation coefficients between metals. Chemical determination of concentrates was performed by using atomic absorption spectroscopy (AAS. In the content on lead concentrate samples, the following were found: Pb>Fe>Zn> Ag> As>Sb>Cd. In the content of zinc concentrate, the following were found: Zn>Fe>Pb>Ag>As>Cd. The program “Statistica ver. 6.0” has been used for calculations of basic statistical parameters, relationships between data and cluster analysis of R-mode. R-mode cluster analysis on lead concentrate samples showed that Pb has the closest linkages with Fe and they form one branch of the dendogram. On the zinc concentrate samples, Zn has the closest linkages with Fe and they form one branch of the dendogram.

  15. Adsorbent material based on passion-fruit wastes to remove lead (Pb), chromium (Cr) and copper (Cu) from metal-contaminated waters

    Science.gov (United States)

    Campos-Flores, Gaby; Castillo-Herrera, Alberto; Gurreonero-Fernández, Julio; Obeso-Obando, Aída; Díaz-Silva, Valeria; Vejarano, Ricardo

    2018-04-01

    The aim of the present work was to evaluate the feasibility of passion-fruit shell (PFS) biomass as adsorbent material to remove heavy metals from contaminated waters. Model mediums were used, which were composed of distilled water and the respective metal: lead (Pb), chromium (Cr) and copper (Cu), with a dose of 10g of dry PFSbiomass per liter of medium. The residual concentration of each metal was determined by Atomic Absorption Spectrophotometry (AAS). A good adsorption capacity was exhibited by this agro industrial waste, achieving removal levels of 96,93 and 82% for Pb, Cr and Cu, respectively. In addition, the results obtained showed an adequate fit to the Freundlich model (R2 > 0.91), on the basis of which, the following values of adsorption capacity (k: 1.7057, 0.6784, 0.3302) and adsorption intensity (n: 0.6869, 2.3474, 1.0499), for Pb, Cr and Cu respectively, were obtained. Our results suggest that Pb, Cr and Cu ions can be removed by more than 80% by using this agro industrial waste, which with a minimum treatment could be used as an adsorbent material in the treatment of metal-contaminated waters.

  16. Heavy Metals (Cd, Cu, Cr, Pb and Zn) in Meretrix meretrix Roding, Water and Sediments from Estuaries in Sabah, North Borneo

    Science.gov (United States)

    Abdullah, Mohd. Harun; Sidi, Jovita; Aris, Ahmad Zaharin

    2007-01-01

    Concentrations of heavy metals (Cd, Cu, Cr, Pb and Zn) in tissues of Meretrix meretrix Roding (M. meretrix R.), water and sediments from two estuaries were determined. One estuary is located in an urban area of Kota Kinabalu (Likas estuary) and the other in a rural district of Kota Belud (Kota Belud estuary), where both are in Sabah, North of…

  17. The use of dispersive X-ray fluorescence technique for pollution evaluation of heavy metals in water samples and lake sediments; Emprego da fluorescencia de raios-X dispersiva para avaliacao da poluicao por metais pesados em amostras de agua e sedimentos de lagos

    Energy Technology Data Exchange (ETDEWEB)

    Vives, Ana Elisa Sirito de; Brienza, Sandra Maria Boscolo [Universidade Metodista de Piracicaba (UNIMEP), Santa Barbara d' Oeste, SP (Brazil). Faculdade de Engenharia e Ciencias Quimicas; Nascimento Filho, Virgilio Franco do [Universidade Estadual de Campinas, SP (Brazil). Faculdade de Engenharia Civil; Moreira, Silvana [Centro de Energia Nuclear na Agricultura (CENA), Piracicaba, SP (Brazil)

    2002-07-01

    The energy dispersive X-ray fluorescence technique (EDXRF) was used to determine metals concentration in water and bottom sediments samples in lakes at Santa Gertrudes region, Sao Paulo state, Brazil. The studied area is about 12 ha, with several lakes formed by argil extraction and present high volume of waste which can be dangerous and cause risks to water flora and fauna and also to human health by direct or indirect contact with the residues. To evaluate contamination degree by heavy metals water samples were collected in three lakes, in 2000 July and November, corresponding to the dry and rainy season. In two lakes the sampling procedure were superficial, and in the third lake, sampling was done at central region and in different deepness. Sediment samples were collected at two lakes, in 2000, July (dry) and November (rainy). To determine biologically available metals concentration (no-residual fraction) in the sediment, an acid extraction procedure was used. To quantitative analysis of both samples, metals were pre concentrated by complexation with ammonium pyrrolidine dithiocarbamate. Samples were excited with a X-ray tube with Mo target and Zr filter, operated at 25 kV/10 mA, and X-ray characteristics measure were done with a Si(Li) semi conductor detector. In water samples, were determined the elements Fe, Cu, Zn and Pb. Among the analyzed elements, Fe presented the highest concentration, independent of the sampling local. Was verified that all the analyzed elements presented concentrations below the maximum limit allowed to waters class 2, which may be distributed to domestic provisioning, to primary contact recreation, to vegetables and fruitier plants irrigation and to the natural and/or intensive breeding (agriculture) of species destined to the alimentation. In the sediment samples were determined Fe, Co, Ni, Cu, Zn and Pb, and was observed high contents to the elements Fe, Zn and Pb and relatively low concentrations of Co, Ni and Cu. It was verified

  18. Nonlinear optical properties of Pb-La metal-organic chelidamic acid frameworks

    Science.gov (United States)

    Tan, Min; Chen, Ruiqi; Yang, Sanjun; Liu, Qiming

    2017-04-01

    Chelidamic acid, acting as ligands, reacted with metal cation of lead and lanthanum. Both of them were dissolved in water and resulted in novel MOFs complexes by using solvothermal synthesis method. The complexes were characterized by the X-ray diffraction, UV-vis spectrophotometer and Z-scan measurements to investigate their morphology and optical properties. The Z-scan measurements indicated that the obtained lead metal-organic chelidamic acid frameworks showed 6.09 × 10-12 esu of χ(3). The special structure and properties, especially the empty f-electron orbital of the rare earth elements, were used to enhance optical nonlinearity. Using one-step solvothermal synthesis method, we added lanthanum into the lead-chelidamic acid metal organic complexes. By changing the spatial configuration of the ligand in the self-assembly process, novel structural complex metals of the lead-lanthanum metal-organic chelidamic acid frameworks have been successfully synthetized, and the third-order nonlinear susceptibility of χ(3)was enhanced to be 1.13 × 10-11 esu.

  19. Depuration Study of Heavy Metal Lead (Pb) and Copper (Cu) in Green Mussels Perna viridis through Continues-discontinues and Acid Extraction Methods

    Science.gov (United States)

    Budiawan; Bakri, Ridla; Cahaya Dani, Intan; Handayani, Sri; Ade Kurnia Putri, Rizki; Tamala, Riska

    2018-01-01

    Green mussel or Perna viridis is filter feeder, which is very susceptible to heavy metals. It takes an effort to release heavy metal contents on the green shell, one of method that can be used to release heavy metal from green shell is depuration proccess. In this research, the depuration process was conducted by continues method of depuration, discontinues method by using various kind of water and acid extraction. The optimum time of continues depuration method is 1.5 hours, with circulation speed 250 L/h and result of Pb metal content decreased is equal to 30.048% and 29.748% for Cu. In the discontinues method, the optimum result was reached at 100oC by using PAM water as the media at 3 h immersion period with decrease of Pb metal content 35.001% and Cu metal content 39.015%. In the acid extraction method, the optimum condition was achieved by 11% acetic acid solvent with decreasing of Pb and Cu levels are 88.224% and 76.298%. For the determination of protein content, the decrease of protein content obtained by treatment with 11% acetic acid extract showed decrease of protein content 36.656% with Kjeldahl method.

  20. Changes in heavy metal bioavailability and speciation from a Pb-Zn mining soil amended with biochars from co-pyrolysis of rice straw and swine manure.

    Science.gov (United States)

    Meng, Jun; Tao, Mengming; Wang, Lili; Liu, Xingmei; Xu, Jianming

    2018-03-22

    Biochar has been utilized as a good amendment to immobilize heavy metals in contaminated soils. However, the effectiveness of biochar in metal immobilization depends on biochar properties and metal species. In this study, the biochars produced from co-pyrolysis of rice straw with swine manure at 400°C were investigated to evaluate their effects on bioavailability and chemical speciation of four heavy metals (Cd, Cu, Pb and Zn) in a Pb-Zn contaminated soil through incubation experiment. Results showed that co-pyrolysis process significantly change the yield, ash content, pH, and electrical conductivity (EC) of the blended biochars compared with the single straw/manure biochar. The addition of these biochars significantly increased the soil pH, EC, and dissolved organic carbon (DOC) concentrations. The addition of biochars at a rate of 3% significantly reduced the CaCl 2 -extractable metal concentrations in the order of Pb>Cu>Zn>Cd. The exchangeable heavy metals decreased in all the biochar-amended soils whereas the carbonate-bound metal speciation increased. The increase in soil pH and the decrease in the CaCl 2 extractable metals indicated that these amendments can directly transform the highly availability metal speciation to the stable speciation in soils. In conclusion, biochar derived from co-pyrolysis of rice straw with swine manure at a mass ratio of 3:1 could most effectively immobilize the heavy metals in the soil. Copyright © 2018 Elsevier B.V. All rights reserved.

  1. Accumulation of Heavy Metals (Pb, Cd, V) in Sediment, roots and ...

    African Journals Online (AJOL)

    Sirik mangrove forests harbour two species, Avicennia marina and Rhizophora macronata living in Azini Creek. Because of a fishing port at Azini Creek, this study was conducted to determine heavy metals concentrations in the Sirik mangrove forests along the Oman Sea coasts. Substantial component analysis of heavy ...

  2. Enriquecimiento, disponibilidad y contaminación de metales traza (Cd, Cu, Pb y Zn) en sedimentos de lagunas urbanas de Concepción-Chile Enrichment, availability and contamination of trace metals (Cd, Cu, Pb and Zn) in sediments of urban lagoons in Concepción, Chile

    OpenAIRE

    Elizabeth González Sepúlveda; María Retamal Cifuentes; Valentina Medina Pedreros; Ramón Ahumada Bermúdez; José Neira Hinojosa

    2009-01-01

    Trace metals (Cd, Cu, Pb and Zn) enrichment, availability and contamination in superficial sediments of three interconnected urban lagoons localized in Concepción-Chile, were evaluated. According to the results of geochemical fracctionation analysis, Cu and Pb are rather associated with oxi-hydroxides, Cd is associated with exchangeable and carbonates fraction, while Zn is mainly associated with organic, oxi-hydroxides and residual fraction. The estimation of the availability percentages indi...

  3. Soil pollution associated to the El Borracho Pb-Ag mine (Badajoz Province, Spain). Metal transfer to biota: oak-tree and moss.

    Science.gov (United States)

    López-Berdonces, Miguel Angel; María Esbrí, José; Fernández-Calderón, Sergio; Naharro, Elena; García-Noguero, Eva Maria; Higueras, Pablo

    2014-05-01

    El Borracho mine was active since Roman times, but with its higher production period on 19th Century. Mine closure occured without restoration works and nowadays the mining area is dedicated to deer hunting activities. In order to evaluate heavy metals distribution on mining tailings and surrounding soils of the studied area, 40 samples of dumps, soils and sediments were taken. Samples from the mine tailings were collected with an Eijkelkamp soil core sampler for undisturbed samples, with a vertical constant spacing of 25 cm. With this procedure, a total of 21 samples were taken in two points at main dump. Samples of Oak-tree leaves and moss were taken to evaluate metal transfer to biota. Analytical determinations have included soil parameters (pH, conductivity, organic matter content), and total metal contents in geological and biological samples by EDXRF. Analytical determinations shows higher metal contents in dumps, especially in surficial samples, 17,700 mg kg-1 and 470 mg kg-1 in average of Pb and Zn respectively, and lower contents in soils, 5,200 mg kg-1 and 300 mg kg-1, and sediments, 3,500 mg kg-1 and 120 mg kg-1. Metal contents in tailings profiles shows higher levels of Pb, Zn and Cu at 3.5 meters depth, a zone with lower grainsize and higher moisture. Differences in efficiency of extraction techniques and metal remobilization inside the dump can be an explanation for this enrichment level. Metal contents in agricultural soils exceeded maximum allowed levels by European Community (300 mg kg-1 for Pb and Zn and 140 mg kg-1 for Cu). Metal contents in biota evidence that Oak-tree bioaccumulates some metals, especially those with higher mobility in acidic conditions like Zn and Sb, with averages Bioaccumulation factor (BAF = plant concentration/soil concentration) of 0.48 and 0.85 respectively. Moss reaches high concentrations of Pb and Zn (3,000 mg kg-1 and 175 mg kg-1 in average respectively). Uptake pattern of Pb and Zn by plants leaves and mosses seems

  4. A two-step leaching method designed based on chemical fraction distribution of the heavy metals for selective leaching of Cd, Zn, Cu, and Pb from metallurgical sludge.

    Science.gov (United States)

    Wang, Fen; Yu, Junxia; Xiong, Wanli; Xu, Yuanlai; Chi, Ru-An

    2018-01-01

    For selective leaching and highly effective recovery of heavy metals from a metallurgical sludge, a two-step leaching method was designed based on the distribution analysis of the chemical fractions of the loaded heavy metal. Hydrochloric acid (HCl) was used as a leaching agent in the first step to leach the relatively labile heavy metals and then ethylenediamine tetraacetic acid (EDTA) was applied to leach the residual metals according to their different fractional distribution. Using the two-step leaching method, 82.89% of Cd, 55.73% of Zn, 10.85% of Cu, and 0.25% of Pb were leached in the first step by 0.7 M HCl at a contact time of 240 min, and the leaching efficiencies for Cd, Zn, Cu, and Pb were elevated up to 99.76, 91.41, 71.85, and 94.06%, by subsequent treatment with 0.2 M EDTA at 480 min, respectively. Furthermore, HCl leaching induced fractional redistribution, which might increase the mobility of the remaining metals and then facilitate the following metal removal by EDTA. The facilitation was further confirmed by the comparison to the one-step leaching method with single HCl or single EDTA, respectively. These results suggested that the designed two-step leaching method by HCl and EDTA could be used for selective leaching and effective recovery of heavy metals from the metallurgical sludge or heavy metal-contaminated solid media.

  5. Removal of Heavy Metals Pb2+, Cu2+, Zn2+, Cd2+, Ni2+, Co2+ and Fe3+ from Aqueous Solutions by using Xanthium Pensylvanicum

    Directory of Open Access Journals (Sweden)

    Jaber SALEHZADEH

    2013-11-01

    Full Text Available The hazardous ill effects of heavy metals on the environment and public health is a matter of serious concern. Biosorption is emerging as a sustainable effective technology. Heavy metals in water resources are one of the most important environmental problems of countries. The intensification of industrial activity and environmental stress greatly contributes to the significant rise of heavy metal pollution in water resources making threats on terrestrial and aquatic life. The toxicity of metal pollution is slow and interminable, as these metal ions are non bio-degradable. The adsorption capacity of Xanthium Pensylvanicum towards metal ions such as Pb2+, Cu2+, Zn2+, Cd2+, Ni2+, Co2+ and Fe3+, was studied. The adsorption capacity was performed by batch experiments as a function of process parameters (such as sorption time and pH. Experimental results showed that the removal percentages increasing of metal ions at pH=4, initial concentration of metal ions 10 mg/L, and after 90 min of shaking was: Zn2+ < Cd2+ < Cu2+ < Pb2+ < Ni2+ < Fe3+ < Co2+.

  6. The effects of increased freshwater salinity in the biodisponibility of metals (Cr, Pb) and effects on antioxidant systems of Oreochromis niloticus.

    Science.gov (United States)

    Baysoy, E; Atli, G; Gürler, C Ö; Dogan, Z; Eroglu, A; Kocalar, K; Canli, M

    2012-10-01

    Anthropogenic activities can increase the salinity of freshwaters and this may cause stress for fish and affect metal bioavailability. Oxidative stress biomarkers are of great interest due to their responses to environmental stressors which provide valuable data for biological monitoring of aquatic pollution. Thus, the individual and combined effects of salinity and metals (Cr, Pb) were investigated in the liver of freshwater fish Oreochromis niloticus in the present study. Fish were exposed to salinity (2 and 8 ppt) alone and salinity+metal (1 μg/mL Pb and Cr) combination exposures for 0, 1, 7 and 14 days and subsequently antioxidant enzymes (superoxide dismutase, SOD; glutathione peroxidase, GPX; glutathione reductase, GR and glutathione S-transferase, GST) activities and glutathione (GSH) levels in the liver were measured. Data showed that all the parameters varied in relation to metal species, exposure durations and salinity levels. Profound alterations on the measured parameters were detected at the lower salinity compared to the higher one. Salinity increase effectively stimulated the antioxidant parameters. The effects of salinity and metals on the measured parameters increased as the exposure duration prolonged. SOD was the most affected antioxidant parameter from both salinity and metals. Because metal and salinity stresses affect fish antioxidant system, this work suggests that the chemistry of freshwaters should be taken into account in natural monitoring for metal contamination in the field. Copyright © 2012 Elsevier Inc. All rights reserved.

  7. Distribution of heavy metals (Pb, Cd, and Zn) in sediment profiles associated to Rhizophora mangle in Sevilla River - Cienaga Grande de Santa Marta, Colombia

    International Nuclear Information System (INIS)

    Parra, Juan Pablo; Espinosa, Luisa Fernanda

    2008-01-01

    In order to evaluate the vertical distribution of the heavy metals Pb, Cd, and Zn in sediments associated to Rhizophora mangle plants, potentially bioavailable and not bioavailable concentrations of these metals were determined in three sediment cores collected in the Sevilla River, Cienaga Grande de Santa Marta. Measurements were carried out by inductively coupled plasma-atomic emission spectrometry. The results showed that in Sevilla River mangrove ecosystem these metals are accumulated principally in non-bioavailable forms, this means that a great part or them are retained in the sediment. The retention of Pb, Cd, and Zn in the sediments of this mangrove ecosystem is strongly related to the physicochemical parameters pH, salinity, and redox potential, and to organic matter, and silt and clays contents

  8. Evaluation of the heavy metals Cr, Mn, Fe, Cu, Zn and Pb in water penny wort (Hydrocotyle ranunculoides) from the upper course of the Lerma River, Mexico

    International Nuclear Information System (INIS)

    Zarazua, G.; Avila P, P.; Tejeda, S.; Valdivia B, M.; Macedo M, G.; Zepeda G, C.

    2013-01-01

    The Lerma river is one of the most polluted water bodies in Mexico, it presents low biodiversity and lets grow up aquatic plants resistant to the pollution. The aim of this work was to evaluate the concentration and bioaccumulation factors of Cr, Mn, Fe, Cu, Zn and Pb in aerial and submerged structures of water penny wort (Hydrocotyle ranunculoides) from the upper course of the Lerma river. Inductively coupled plasma-optical emission spectrometry was used to determine the concentration of heavy metals in water and H. ranunculoides. Results show that the bioaccumulation factors of Fe and Zn were higher than those of Cu, Mn, Cr and Pb; with the exception of Zn, bioaccumulation factors were higher in the submerged structures of the plant, which shows low mobility of analyzed metals. As a result of this study H. ranunculoides can be considered as good indicator of metal pollution in water bodies. (Author)

  9. Phytoremediation of Heavy Metals (Pb, Cd by Tamarix along the Temby (karon River, Iran

    Directory of Open Access Journals (Sweden)

    Zeinab Sasan

    2017-03-01

    Full Text Available Background & Aims of the Study: Heavy metals contaminate drinking water, air and soils. It is very harmful for humans and other live organisms. Phytoremediation is one of the direct bio-remediation methods for heavy metal removal from polluted water and soils. This method is accepted environmentally, economically and aesthetically. The purpose of this study was to assess Tamarix hispida capacity for heavy metals (lead and Cadmium removal from Temby (Karon river of Ahvaz, Iran. Materials and Methods: This study was performed in summer season. Water samples took from upstream (before municipal wastewater discharge point and downstream (after municipal wastewater discharge point. Samples of Tamarix hispida tree leaf took from those grown in downstream (after municipal sewage discharge place. In this study, inductively coupled plasma mass spectrometry (ICPMS was used for analysis. Results: Results of this study showed that lead and cadmium mean in summer were 0.5 and 0.077 mg/l in upstream; and they were 0.66 and 0.12 in downstream, respectively. According to the result, absorption rate of lead and cadmium by Tamarix hispida was 0.03 and 0.013 mg/l, respectively. Conclusion: Results showed that Temby river water was polluted with Lead and Cadmium. Also,Tamarix hispida tree was effective for lead and cadmium removal. Lead was more uptake than Cadmium.

  10. Concentración de Hg, Pb, Cd, Cr y As en hígado de Carcharhinus limbatus (Carcharhiniformes: Carcharhinidae capturado en Veracruz, México

    Directory of Open Access Journals (Sweden)

    Fernando Mendoza-Díaz

    2013-06-01

    Full Text Available La contaminación de los ecosistemas marinos y costeros por metales pesados en el Golfo de México es uno de los problemas que afectan a los recursos naturales del medio acuático. Los tiburones por situarse en niveles tróficos superiores de la red alimenticia acumulan y magnifican cantidades considerables de contaminantes. Por esta razón, el objetivo de este trabajo fue determinar la concentración de cuatro metales pesados (Hg, Cd, Pb y Cr y un metaloide (As en el tiburón punta negra (Carcharhinus limbatus por medio de espectrofotometría de absorción atómica con flama y generador de hidruros. Se muestrearon 19 hígados de tiburones capturados cerca de Tamiahua, Veracruz entre noviembre 2007 y marzo 2008, de los cuales 12 fueron machos adultos, una hembra adulta, tres machos jóvenes y tres hembras jóvenes. Las concentraciones máximas registradas para cada metal fueron: Hg=0.69mg/ kg, Cd=0.43mg/kg, As=27.37mg/kg, Cr=0.35mg/kg. El Pb no fue detectado, no al menos la cantidad mínima de detección requerida por el espectrofotómetro de absorción atómica (0.1mg/kg. Ninguna de las muestras analizadas rebasó los límites máximos permisibles por las leyes mexicanas y americanas.

  11. Characterization of Cd-, Pb-, Zn-resistant endophytic Lasiodiplodia sp. MXSF31 from metal accumulating Portulaca oleracea and its potential in promoting the growth of rape in metal-contaminated soils.

    Science.gov (United States)

    Deng, Zujun; Zhang, Renduo; Shi, Yang; Hu, Li'ao; Tan, Hongming; Cao, Lixiang

    2014-02-01

    The aim of this study was to characterize the features of a Cd-, Pb-, and Zn-resistant endophytic fungus Lasiodiplodia sp. MXSF31 and to investigate the potential of MXSF31 to remove metals from contaminated water and soils. The endophytic fungus was isolated from the stem of Portulaca oleracea growing in metal-contaminated soils. The maximum biosorption capacities of MXSF31 were 3.0 × 10(3), 1.1 × 10(4), and 1.3 × 10(4) mg kg(-1) for Cd, Pb, and Zn, respectively. The biosorption processes of Cd, Pb, and Zn by MXSF31 were well characterized with the pseudo-second-order kinetic model. The biosorption isotherm processes of Pb and Zn by the fungus were fitted better with the Langmuir model, while the biosorption processes of Cd was better fitted with the Freundlich model. The biosorption process of MXSF31 was attributed to the functional groups of hydroxyl, amino, carbonyl, and benzene ring on the cell wall. The active biomass of the strain removed more Cd, Pb, and Zn (4.6 × 10(4), 5.6 × 10(5), and 7.0 × 10(4) mg kg(-1), respectively) than the dead biomass. The inoculation of MXSF31 increased the biomass of rape (Brassica napus L.), the translocation factor of Cd, and the extraction amount of Cd by rape in the Cd+Pb-contaminated soils. The results indicated that the endophytic fungus strain had the potential to remove heavy metals from water and soils contaminated by multiple heavy metals, and plants accumulating multiple metals might harbor diverse fungi suitable for bioremediation of contaminated media.

  12. Toxic metals (Ni2+, Pb2+, Hg2+) binding affinity of dissolved organic matter (DOM) derived from different ages municipal landfill leachate

    Science.gov (United States)

    Rikta, S. Y.; Tareq, Shafi M.; Uddin, M. Khabir

    2018-03-01

    Solid waste production is rapidly increasing in Bangladesh and landfill leachate is the consequence of the decomposition of this waste. These leachates contain heavy metals and significant amount of dissolved organic matter (DOM). DOM is known to have considerable role in heavy metals speciation. Hence, it is important to characterize DOM/leachate and evaluate toxic metals binding affinity of DOM. The objectives of this study were to characterize the DOM in landfill leachate through physico-chemical and optical analyses and to investigate the toxic metals (Ni2+, Pb2+ and Hg2+) binding affinity of three different ages (fresh sample L-1, young sample L-2 and mature sample L-3) DOM samples. Results suggested that leachate is a potential pollutant which contained very high organic pollutant load. Conditional stability constant (Log K) and percentages of fluorophores that correspond to metal binding (% f) values indicated that young DOM sample (L-2) had the highest binding affinity to all the three metals ions. In general, DOM samples showed the following order affinity to the metal ions; Ni2+ binding affinity: L-2 > L-3 > L-1, Pb2+ binding affinity: L-2 > L-3 > L-1 and Hg2+ binding affinity: L-2 > L-1 > L-3.

  13. Determination of concentration of heavy metals (Pb, Cd, Fe) in animal tissues using atomic absorption spectrometry

    International Nuclear Information System (INIS)

    RAZAFINTSALAMA, V.T.

    2009-01-01

    Heavy metals are classified among the inorganic compounds. The latter type of metal is found in rocks, fertilizers, urban mud but may also originate from the atmospheric pollution. A particular characteristic of heavy metals is their bioaccumulation in the food chain. Therefore, lead and cadmium, which are classified as heavy metals may be easily found in animal products and can lead to food poisoning if their concentrations are higher than the maximum permissible values as requested by international agencies such as the c odex alimentarius . The values are set down and differ according to types of food for human consuption and the trading companies take action accordingly. Therefore, it is necessary to set up a quality control system through analytical laboratory measurements and testings. This study underlies the method of determination of lead, cadmium and iron in animal tissues by atomic absorption spectrometry. The results showed that the method is sensitive and reliable. For each analyte, the Z-score lies between -2 and 2, indicating that the method is working properly. The analytical results showed that: (i) only beef and chicken meats and beef liver contain lead [0,09μg.g - 1; 0,29μg.g - 1]. The limit value of 0,1μg.g - 1 is almost reached in beef and chicken meats, (ii) as far as cadmium is concerned, the five studied samples contain this analyte [0,02μg.g - 1; 0,9μg.g - 1]. Except the chicken liver of which the concentration (0,15μg.g - 1) exceeds the maximum permissible value (0,1μg.g - 1), the others are in conformity with the standards and appropriate to be consumed,(iii) iron is higher in the liver and kidney samples: beef liver 282mg.g - 1, chicken liver 250 mg.g - 1, pork kidney 247mg.g - 1. The study also showed that the calcium concentration in animal tissues is low and they can be classified as poor-calcium food. [fr

  14. Effect of bamboo and rice straw biochars on the mobility and redistribution of heavy metals (Cd, Cu, Pb and Zn) in contaminated soil.

    Science.gov (United States)

    Lu, Kouping; Yang, Xing; Gielen, Gerty; Bolan, Nanthi; Ok, Yong Sik; Niazi, Nabeel Khan; Xu, Song; Yuan, Guodong; Chen, Xin; Zhang, Xiaokai; Liu, Dan; Song, Zhaoliang; Liu, Xingyuan; Wang, Hailong

    2017-01-15

    Biochar has emerged as an efficient tool to affect bioavailability of heavy metals in contaminated soils. Although partially understood, a carefully designed incubation experiment was performed to examine the effect of biochar on mobility and redistribution of Cd, Cu, Pb and Zn in a sandy loam soil collected from the surroundings of a copper smelter. Bamboo and rice straw biochars with different mesh sizes (Heavy metal concentrations in pore water were determined after extraction with 0.01 M CaCl 2 . Phytoavailable metals were extracted using DTPA/TEA (pH 7.3). The European Union Bureau of Reference (EUBCR) sequential extraction procedure was adopted to determine metal partitioning and redistribution of heavy metals. Results showed that CaCl 2 -and DTPA-extractable Cd, Cu, Pb and Zn concentrations were significantly (p soils, especially at 5% application rate, than those in the unamended soil. Soil pH values were significantly correlated with CaCl 2 -extractable metal concentrations (p metal fractions, and the effect was more pronounced with increasing biochar application rate. The effect of biochar particle size on extractable metal concentrations was not consistent. The 5% rice straw biochar treatment reduced the DTPA-extractable metal concentrations in the order of Cd metals were mainly bound in the soil organic matter fraction. The results demonstrated that the rice straw biochar can effectively immobilize heavy metals, thereby reducing their mobility and bioavailability in contaminated soils. Copyright © 2016 Elsevier Ltd. All rights reserved.

  15. The concentrations of heavy metals and the incidence of micronucleated erythrocytes and liver EROD activity in two edible-fish from the Paraíba do Sul river basin in Brazil | Concentração de metais pesados e incidência de eritrócitos micronucleados e atividade de EROD hepática em duas espécies de peixes comestíveis na bacia do Rio Paraíba do Sul, Brasil

    Directory of Open Access Journals (Sweden)

    Thiago Estevam Martins Parente

    2015-02-01

    Full Text Available The Paraíba do Sul river (PSR basin crosses one of the most populated and industrialized regions of Brazil and receives effluent from the metallurgic, paper mill and agricultural industries. PSR water has multiple uses, including being a supply of potable water and riverine populations which consume some species of its fish. In the present study, we investigated the responses of two biomarkers of aquatic pollution, EROD activity in the liver and micronuclei frequency in peripheral blood, as well as the concentrations of seven heavy metals in the muscle tissue of two species of fish native to the PSR: Geophagus brasiliensis and Hypostomus sp. Sampling was performed in both the wet and dry seasons of 2003, with a total of 339 fish collected from 16 sites along the PSR basin. Fish collected at Levy Gasparian, Barra Mansa and Três Rios both had higher EROD activity and micronuclei frequency. The results also suggested a moderate induction of EROD activity in fish collected from S.L. Paraitinga and Sapucaia. Micronuclei frequency was elevated in fish from S.J. Campos, Além Paraíba, Campos and S.J. Barra. In all cases, heavy metal concentrations did not exceed the maximum considered safe for fish meat consumption. -------------------------------------------------------------------------------------------- A bacia do rio Paraíba do Sul (PSR atravessa uma das regiões mais povoadas e industrializadas do Brasil, recebendo efluentes de indústrias metalúrgicas, de papel e celulose e agrícolas. Os usos das águas do PSR são múltiplos, incluem o fornecimento de água potável, e as populações ribeirinhas consomem algumas de suas espécies de peixes. No presente trabalho foram investigadas as respostas de dois biomarcadores à poluição, a atividade hepática de EROD e a freqüência de micronúcleo em sangue periférico, e medidos os níveis de sete metais pesados no músculo de duas espécies de peixes nativas do PSR, Geophagus brasiliensis and

  16. Characterization of Pb(Zr, Ti)O sub 3 thin films prepared by metal-organic chemical-vapor deposition using a solid delivery system

    CERN Document Server

    Shin, J C; Hwang, C S; Kim, H J; Lee, J M

    1999-01-01

    Pb(Zr, Ti)O sub 3 (PZT) thin films were deposited on Pt/SiO sub 2 /Si substrates by metal-organic chemical-vapor deposition technique using a solid delivery system to improve the reproducibility of the deposition. The self-regulation mechanism, controlling the Pb-content of the film, was observed to work above a substrate temperature of 620 .deg. C. Even with the self-regulation mechanism, PZT films having low leakage current were obtained only when the molar mixing ratio of the input precursors was 1<Pb/(Zr+Ti)<1.4. The leakage current mechanism of the Pt/PZT/Pt capacitor was Schottky emission with a barrier height of 1.36 eV.

  17. Efficiency of Aluminum and Iron Electrodes for the Removal of Heavy Metals [(Ni (II), Pb (II), Cd (II)] by Electrocoagulation Method

    Energy Technology Data Exchange (ETDEWEB)

    Khosa, Muhammad Kaleem; Jamal, Muhammad Asghar; Hussain, Amira; Muneer, Majid; Zia, Khalid Mahmood [Government College Univ., Faisalabad (Pakistan); Hafeez, Samia [Bahaud-din-Zakariya Univ., Multan (Pakistan)

    2013-06-15

    Electrocoagulation (EC) technique is applied for the treatment of wastewater containing heavy metals ions such as nickel (Ni), lead (Pb) and cadmium (Cd) by using sacrificial anodes corrode to release active coagulant flocs usually aluminium or iron cations into the solution. During electrolytic reactions hydrogen gas evolve at the cathode. All the experiments were carried out in Batch mode. The tank was filled with synthetic wastewater containing heavy metals and efficiency of electrocoagulation in combination with aluminum and iron electrodes were investigated for removal of such metals. Several parameters, such as contact time, pH, electro-coagulant concentration, and current density were optimized to achieve maximum removal efficiency (%). The concentrations of heavy metals were determined by using Atomic Absorption Spectroscopy (AAS). It is found that the electro-coagulation process has potential to be utilized for the cost-effective removal of heavy metals from wastewater specially using iron electrodes in terms of high removal efficiencies and operating cost.

  18. Assessment of metal pollution in a former mining area in the NW Tunisia: spatial distribution and fraction of Cd, Pb and Zn in soil.

    Science.gov (United States)

    Othmani, Mohamed Ali; Souissi, Fouad; Durães, Nuno; Abdelkader, Moussi; da Silva, Eduardo Ferreira

    2015-08-01

    This study aims to evaluate the impact of the former mining Touiref district (NW Tunisia) on the spatial distribution of metal contamination. In order to characterize the metal content of the tailings and to assess how far the soils from the district could be impacted by metals, a sampling campaign was conducted. According to the spatial distribution concentration maps of potential toxic elements (PTE), the highest concentrations occur near the flotation tailings and in mining facilities and decrease abruptly with distance. These results confirm that wind is the main agent capable of dispersing metals in a W-E direction, with concentrations exceeding the standards of soil quality for Cd, Pb and Zn over several hundred metres away from the source, facilitated by the small-size fraction and low cohesion of tailings particles. Chemical fractionation showed that Pb and Cd were mainly associated with the acid-soluble fraction (carbonates) and Fe-(oxy) hydroxides, while Zn was mainly associated with Fe-(oxy) hydroxides but also with sulphides. Thus, the immobilization of metals in solution may be favoured by the alkaline conditions, promoted by carbonates dissolution. However, being carbonate important-bearing phases of Cd and Pb (but also for Zn), the dissolution facility of these minerals may enhance the release of metals, particularly far away from the mine where the physicochemical conditions can be different. Also, the metal uptake by plants in these alkaline conditions may be favoured, especially if secondary phases with high sorption ability are reduced at this site. A remediation plan to this area is needed, with particularly attention in the confinement of the tailings.

  19. Assessment of noise and heavy metals (Cr, Cu, Cd, Pb) in the ambience of the production line for recycling waste printed circuit boards.

    Science.gov (United States)

    Xue, Mianqiang; Yang, Yichen; Ruan, Jujun; Xu, Zhenming

    2012-01-03

    The crush-pneumatic separation-corona electrostatic separation production line provides a feasible method for industrialization of waste printed circuit boards (PCBs) recycling. To determine the potential environmental contamination in the automatic line workshop, noise and heavy metals (Cr, Cu, Cd, Pb) in the ambience of the production line have been evaluated in this paper. The mean noise level in the workshop has been reduced from 96.4 to 79.3 dB since the engineering noise control measures were employed. Noise whose frequency ranged from 500 to 1000 Hz is controlled effectively. The mass concentrations of TSP and PM(10) in the workshop are 282.6 and 202.0 μg/m(3), respectively. Pb (1.40 μg/m(3)) and Cu (1.22 μg/m(3)) are the most enriched metals in TSP samples followed by Cr (0.17 μg/m(3)) and Cd (0.028 μg/m(3)). The concentrations of Cu, Pb, Cr, and Cd in PM(10) are 0.88, 0.56, 0.12, and 0.88 μg/m(3), respectively. Among the four metals, Cr and Pb are released into the ambience of the automatic line more easily in the crush and separation process. Health risk assessment shows that noncancerous effects might be possible for Pb (HI = 1.45), and noncancerous effects are unlikely for Cr, Cu, and Cd. The carcinogenic risks for Cr and Cd are 3.29 × 10(-8) and 1.61 × 10(-9), respectively. It indicates that carcinogenic risks on workers are relatively light in the workshop. These findings suggest that this technology is advanced from the perspective of environmental protection in the waste PCBs recycling industry.

  20. Alginate and Algal-Based Beads for the Sorption of Metal Cations: Cu(II and Pb(II

    Directory of Open Access Journals (Sweden)

    Shengye Wang

    2016-09-01

    Full Text Available Alginate and algal-biomass (Laminaria digitata beads were prepared by homogeneous Ca ionotropic gelation. In addition, glutaraldehyde-crosslinked poly (ethyleneimine (PEI was incorporated into algal beads. The three sorbents were characterized by scanning electron microscopy (SEM coupled with energy dispersive X-ray analysis (EDX: the sorption occurs in the whole mass of the sorbents. Sorption experiments were conducted to evaluate the impact of pH, sorption isotherms, and uptake kinetics. A special attention was paid to the effect of drying (air-drying vs. freeze-drying on the mass transfer properties. For alginate, freeze drying is required for maintaining the porosity of the hydrogel, while for algal-based sorbents the swelling of the material minimizes the impact of the drying procedure. The maximum sorption capacities observed from experiments were 415, 296 and 218 mg Pb g−1 and 112, 77 and 67 mg Cu g−1 for alginate, algal and algal/PEI beads respectively. Though the sorption capacities of algal-beads decreased slightly (compared to alginate beads, the greener and cheaper one-pot synthesis of algal beads makes this sorbent more competitive for environmental applications. PEI in algal beads decreases the sorption properties in the case of the sorption of metal cations under selected experimental conditions.

  1. Effective removal of heavy metal ions Cd2+, Zn2+, Pb2+, Cu2+ from aqueous solution by polymer-modified magnetic nanoparticles.

    Science.gov (United States)

    Ge, Fei; Li, Meng-Meng; Ye, Hui; Zhao, Bao-Xiang

    2012-04-15

    We prepared novel Fe(3)O(4) magnetic nanoparticles (MNPs) modified with 3-aminopropyltriethoxysilane (APS) and copolymers of acrylic acid (AA) and crotonic acid (CA). The MNPs were characterized by transmission electron microscopy, X-ray diffraction, infra-red spectra and thermogravimetric analysis. We explored the ability of the MNPs for removing heavy metal ions (Cd(2+), Zn(2+), Pb(2+) and Cu(2+)) from aqueous solution. We investigated the adsorption capacity of Fe(3)O(4)@APS@AA-co-CA at different pH in solution and metal ion uptake capacity as a function of contact time and metal ion concentration. Moreover, adsorption isotherms, kinetics and thermodynamics were studied to understand the mechanism of the synthesized MNPs adsorbing metal ions. In addition, we evaluated the effect of background electrolytes on the adsorption. Furthermore, we explored desorption and reuse of MNPs. Fe(3)O(4)@APS@AA-co-CA MNPs are excellent for removal of heavy metal ions such as Cd(2+), Zn(2+), Pb(2+) and Cu(2+) from aqueous solution. Furthermore, the MNPs could efficiently remove the metal ions with high maximum adsorption capacity at pH 5.5 and could be used as a reusable adsorbent with convenient conditions. Copyright © 2011 Elsevier B.V. All rights reserved.

  2. Geographical and pedological drivers of distribution and risks to soil fauna of seven metals (Cd, Cu, Cr, Ni, Pb, V and Zn) in British soils

    Energy Technology Data Exchange (ETDEWEB)

    Spurgeon, David J. [Centre for Ecology and Hydrology, Monks Wood, Abbots Ripton, Huntingdon, Cambridgeshire PE28 2LS (United Kingdom)], E-mail: dasp@ceh.ac.uk; Rowland, Philip; Ainsworth, Gillian [Centre for Ecology and Hydrology, Lancaster, Bailrigg, Lancaster LA1 4AP (United Kingdom); Rothery, Peter; Long, Sara [Centre for Ecology and Hydrology, Monks Wood, Abbots Ripton, Huntingdon, Cambridgeshire PE28 2LS (United Kingdom); Black, Helaina I.J. [Soils Group, The Macaulay Institute, Craigiebuckler, Aberdeen AB15 8QH (United Kingdom)

    2008-05-15

    Concentrations of seven metals were measured in over 1000 samples as part of an integrated survey. Sixteen metal pairs were significantly positively correlated. Cluster analysis identified two clusters. Metals from the largest (Cr, Cu, Ni, V, Zn), but not the smallest (Cd, Pb) cluster were significantly negatively correlated with spatial location and soil pH and organic matter content. Cd and Pb were not correlated with these parameters, due possibly to the masking effect of recent extensive release. Analysis of trends with soil properties in different habitats indicated that general trends may not necessarily be applicable to all areas. A risk assessment indicated that Zn poses the most widespread direct risk to soil fauna and Cd the least. Any risks associated with high metal concentrations are, however, likely to be greatest in habitats such as arable and horticultural, improved grassland and built up areas where soil metal concentrations are more frequently elevated. - Metal distributions and risks explained by balance of sources and soil property effects on fate.

  3. An investigation of the evolution of evolution of distribution and accumulation of heavy metals(Cr, Ni, Cu, Cd, Zn and Pb) in Anzali wetland's sediments

    International Nuclear Information System (INIS)

    Sartaj, M.; Fatollahi, F.; Filizadeh, Y.

    2005-01-01

    To investigate the precipitation of heavy metals in Anzali wetland and evaluate its refining performance this study was carried out on the wetland. Monthly samples of sediments from 15 stations including inlets, outlets and some internal locations in the wetland were collected and analyzed over a period of six months (July - December 2002). Sediment samples were analyzed for six metals of Cr, Cd, Pb, Zn, Cu and Ni. Wet digestion method was employed for extraction of metals in samples by and through a solution containing HN03 and HCL. Atomic Adsorption spectrophotometry was employed for measurement of the heavy metals. Statistical methods, including analysis of variance (ANOVA), correlation and Cluster analysis were used for analysis of the data. The results indicated that concentration of heavy metals present in sediments (collected from different stations and at different times) here significantly different. Among the metals studied, Zn was of the highest concentration Heavy metal concentrations in stations 1 1, 12 and 13 were lower than in other stations. Sediments in station 5 contained the highest concentrations of heavy metals among all sediments. It can be stated that concentration of heavy metals decreases with an increase in the distance from delta of rivers entering the wetland.2. This is due to the role and performance of wetland chemical contents in reduction of pollutants, the self-purification action of wetland as well as precipitation of heavy metals at the beginning of the entries into the wetland

  4. First principles investigation of half-metallicity and spin gapless semiconductor in CH3NH3Cr x Pb1- x I3 mixed perovskites

    Science.gov (United States)

    Huang, H. M.; Zhu, Z. W.; Zhang, C. K.; He, Z. D.; Luo, S. J.

    2018-04-01

    The structural, electronic and magnetic properties of organic-inorganic hybrid mixed perovskites CH3NH3Cr x Pb1- x I3 ( x = 0.25, 0.50, 0.75, 1.00) in cubic, tetragonal and orthorhombic phases have been investigated by first-principles calculation. The results indicate that the tetragonal CH3NH3Cr0.75Pb0.25I3 is a spin gapless semiconductor with Curie temperature of 663 K estimated using mean field approximation. All other CH3NH3Cr x Pb1- x I3 mixed perovskites are half-metallic ferromagnets together with 100% spin polarization, and their total magnetic moment are 4.00, 8.00, 12.00 and 16.00 µB per unit cell for x = 0.25, 0.50, 0.75 and 1.00, respectively. The effect of , and orientation of organic cation CH3NH3 + on the electronic properties of CH3NH3Cr0.50Pb0.50I3 was investigated. The results show that the CH3NH3 + in different orientations have a slight effect on the lattice constants, the energy gap in minority-spin states, half-metallic gap, local magnetic moment, and Curie temperature.

  5. Assessment of metal concentrations (Cu, Zn, and Pb) in seawater, sediment and biota samples in the coastal area of Eastern Black Sea, Turkey.

    Science.gov (United States)

    Baltas, Hasan; Sirin, Murat; Dalgic, Goktug; Bayrak, Esra Yilmaz; Akdeniz, Aysel

    2017-09-15

    This study investigated the contents of Cu, Zn and Pb in seawater, sediment, different shell sizes of mussel (Mytilus galloprovincialis) and sea snail (Rapana venosa) samples collected from four different provinces of the Eastern Black Sea Region. With the exception of Zn, all the metal concentration values measured in the sea snail were observed to be higher than those of mussels in all stations. While the correlation between mussels and sea snail according to metal concentrations was found to be positive (p˂0.05), this relation was not observed between the other parameters, such as the shell sizes, salinity and pH (p˃0.05). Although the mean concentration values of Cu, Zn, and Pb for mussel and sea snail are significantly above the tolerable levels, the estimated daily intake values for mussel were below the daily intake recommended. Copyright © 2017 Elsevier Ltd. All rights reserved.

  6. Phytoextraction and fractionation of heavy metals in soil after multiple applications of natural chelants Fitoextração e fracionamento de metais pesados em solo após múltiplas aplicações de ácidos orgânicos

    Directory of Open Access Journals (Sweden)

    Évio Eduardo Chaves de Melo

    2008-02-01

    Full Text Available Chelate-assisted phytoextraction of heavy metals is a promising approach to clean up polluted soils. However, the most successful chelants tested so far are synthetic agents that barely degrade in soil, increasing the metal leaching risks. Natural organic acids have been proposed to enhance phytoextraction due to their higher biodegradability, but they can also be a drawback for efficient phytoextraction. This work was carried out to compare the effectiveness of multiple applications of citric and gallic acids on the availability in soil and accumulation of Cd, Pb, Cu, and Zn by velvet bean (Stizolobium aterrimum plants. The organic acids were added as follows: 5 mmol kg-1 in the 28th cultivation day; two doses of 5 mmol kg-1 at the 28th and 31st day; and three applications at the same rate at the 28th, 31st, and 34th day of velvet bean cultivation. Soil samples were sequentially extracted and soil solution metal concentrations assessed. Neither citric acid nor gallic acid was efficient for metals phytoextraction. In general, low molecular weight organic acids (LMWOA application increased the metal concentrations in the water soluble and exchangeable fractions. Zinc and Cu were retained mostly in the organic matter fraction. Zn was remobilized from the organic matter fraction through LMWOA application into the water soluble and exchangeable fractions. LMWOA mobilized Pb and Cu from iron oxides, but such an increase in solubility was not high enough to affect phytoextraction.Fitoextração de metais induzida por quelantes é uma técnica promissora para despoluição de solos. Entretanto, os quelantes mais eficientes são sintéticos e apresentam baixa taxa de biodegradação, o que aumenta o risco de lixiviação de metais. Ácidos orgânicos têm sido propostos para auxiliar na fitoextração, mas a sua rápida degradação pode ser limitante para a eficiência desta técnica. O objetivo do trabalho foi comparar a eficiência de aplica

  7. AVALIAÇÃO DE ESPÉCIES VEGETAIS NA FITORREMEDIAÇÃO DE SOLOS CONTAMINADOS POR METAIS PESADOS

    Directory of Open Access Journals (Sweden)

    Silvio Roberto de Lucena Tavares

    2013-12-01

    Full Text Available O presente trabalho teve por objetivo avaliar o comportamento de diferentes espécies vegetais cultivadas em solo contaminado por metais pesados. Para a realização do experimento em casa de vegetação coletou-se um solo que corresponde a um aterramento de Argissolo Vermelho-Amarelo proveniente de uma área industrial (resíduo de lodo galvânico no estado do Rio de Janeiro. Esse solo teve suas propriedades químicas e físicas determinadas. Por um período de 50 dias foram cultivadas as espécies de algodão, milho, sorgo, girassol e mucuna nesse solo contaminado. Transcorrido o período de plantio, avaliou-se a produção de massa seca da parte aérea, colmo e sistema radicular de cada espécie estudada, assim como, os teores de metais pesados absorvido nesses diferentes compartimentos. Os teores pseudo-totais (extração por água-régia e biodisponíveis (extração por solução de DTPA e Mehlich-1 dos metais pesados presentes no solo foram determinados antes e após o plantio das espécies. O delineamento estatístico utilizado no estudo foi inteiramente casualizado, com quatro repetições para cada espécie investigada. Os resultados indicaram que as espécies apresentaram comportamento bem diferenciado quanto à produção de biomassa, absorção e translocação dos metais para parte aérea. O girassol destacou-se em relação às demais espécies em reduzir a concentração do metal cobre no solo, embora mais estudos devam ser realizados, visando aumentar a produção de biomassa e a translocação dos metais pesados para parte aérea desta espécie.

  8. Effects of heavy metal ions (Cu2+, Pb2+ and Cd2+) on DNA damage of the gills, hemocytes and hepatopancreas of marine crab, Charybdis japonica

    Science.gov (United States)

    Pan, Luqing; Liu, Na; Zhang, Hongxia; Wang, Jing; Miao, Jingjing

    2011-06-01

    There are rising concerns about the hazardous effects of heavy metals on the environment. In this study, comet assay and DNA alkaline unwinding assay were conducted on the tissues (gills, hepatopancreas, and hemocytes) of Charybdis japonica in order to illustrate genotoxicity of three heavy metal ions (Cu2+, Pb2+, and Cd2+) on the marine crabs C. japonica. The crabs were exposed to Cu2+ (10, 50, and 100 μg.L-1), Pb2+ (50, 250, and 500 μg L-1) and Cd2+ (5, 25, and 50 μg L-1), and the tissues were sampled at days 0.5, 1, 3, 6, 9, and 15. DNA alkaline unwinding assay was used for testing the DNA single strand break in gills and hepatopancreas and comet assay was employed for testing the DNA damage in hemocytes. The results showed that the DNA damage ( F-value) of gills in the crabs exposed to the three heavy metals was decreased gradually during the exposure periods and there was a dose-time response relationship in certain time, suggesting that the levels of DNA single strand break in all the experimental groups increased significantly compared to the controls. Changes of F-value in hepatopancreas of the crabs exposed to the three heavy metals were similar to those in gills except that the peak values were found in the 500 μg L-1 Pb2+ treatment group at day 3 and the 50 μg L-1 Cd2+ treatment group at day 9. The ranks of DNA damage in gills and hepatopancreas induced by the three heavy metal ions (50 μg L-1, day 15) were Cd2+ >Pb2+ >Cu2+ and Pb2+ >Cu2+ >Cd2+. The levels of DNA damage in gills were higher than those in hepatopancreas in the same experimental group. It can be concluded that indices of DNA damage can be used as the potential biomarkers of heavy metal pollution in marine environment.

  9. Pressure-Induced Metallization of the Halide Perovskite (CH 3 NH 3 )PbI 3

    Energy Technology Data Exchange (ETDEWEB)

    Jaffe, Adam; Lin, Yu [Photon; Mao, Wendy L. [Photon; Karunadasa, Hemamala I.

    2017-03-10

    We report the metallization of the hybrid perovskite semiconductor (MA)PbI3 (MA = CH3NH3+) with no apparent structural transition. We tracked its bandgap evolution during compression in diamond-anvil cells using absorption spectroscopy and observed strong absorption over both visible and IR wavelengths at pressures above ca. 56 GPa, suggesting the imminent closure of its optical bandgap. The metallic character of (MA)PbI3 above 60 GPa was confirmed using both IR reflectivity and variable-temperature dc conductivity measurements. The impressive semiconductor properties of halide perovskites have recently been exploited in a multitude of optoelectronic applications. Meanwhile, the study of metallic properties in oxide perovskites has revealed diverse electronic phenomena. Importantly, the mild synthetic routes to halide perovskites and the templating effects of the organic cations allow for fine structural control of the inorganic lattice. Pressure-induced closure of the 1.6 eV bandgap in (MA)PbI3 demonstrates the promise of the continued study of halide perovskites under a range of thermodynamic conditions, toward realizing wholly new electronic properties.

  10. Fe(III) hydroxide nucleation and growth on quartz in the presence of Cu(II), Pb(II), and Cr(III): metal hydrolysis and adsorption.

    Science.gov (United States)

    Dai, Chong; Hu, Yandi

    2015-01-06

    Fe(III) hydroxide nanoparticles are an essential carrier for aqueous heavy metals. Particularly, iron hydroxide precipitation on mineral surfaces can immobilize aqueous heavy metals. Here, we used grazing-incidence small-angle X-ray scattering (GISAXS) to quantify nucleation and growth of iron hydroxide on quartz in 0.1 mM Fe(NO3)3 solution in the presence of Na(+), Cu(2+), Pb(2+), or Cr(3+) at pH = 3.7 ± 0.1. In 30 min, the average radii of gyration (R(g)) of particles on quartz grew from around 2 to 6 nm in the presence of Na(+) and Cu(2+). Interestingly, the particle sizes remained 3.3 ± 0.3 nm in the presence of Pb(2+), and few particles formed in the presence of Cr(3+). Quartz crystal microbalance dissipation (QCM-D) measurements showed that only Cr(3+) adsorbed onto quartz, while Cu(2+) and Pb(2+) did not. Cr(3+) adsorption changed the surface charge of quartz from negative to positive, thus inhibiting the precipitation of positively charged iron hydroxide on quartz. Masses and compositions of the precipitates were also quantified. This study provided new insights on interactions among quartz, iron hydroxide, and metal ions. Such information is helpful not only for environmental remediation but also for the doping design of iron oxide catalysts.

  11. EXTRACCIÓN DE HIDROCARBURO PESADO EN SUELO ARENOSO

    Directory of Open Access Journals (Sweden)

    Carolina G. Martínez-Chávez

    2017-01-01

    Full Text Available Una de las técnicas más utilizadas en la extracción de hidrocarburo en cuant o a fracción pesada de petróleo es el método que se estable ce en la Norma Oficial Mexic ana NMX - AA - 134 - SCFI - 2006, la cua l indica un tiempo de extracción determinado (6 horas. Basado en lo anterior, en este trabajo se evalu ó y compar ó la extracción de hidrocarburo pesado en un suelo arenoso a diferentes tiempos (6 y 8 horas empleando dos disolventes (hexano y d iclorometano con la misma polaridad pero con diferentes constantes dieléctricas. Los suelos se contaminaron con hidrocarburo pesado (45000 mg∙ kg - 1 y se realizaron extracciones continuas por triplicado utilizando el método Soxhlet . Luego, se cuantific ó la extracción de cada eluyente. Se concluyó que el d iclorometano favorece la extracción a menor tiempo ya que no se observó diferencias en las extracciones a 6 y 8 horas, pero si una diferencia con respecto a hexano en ambos tiempos.

  12. Experimental analysis of the simultaneous uptake of the heavy metals Cd, Hg, Pb, Cu, Zn, Se in the sporophore of mushrooms. Versuche ueber die simultane Aufnahme der Schwermetalle Cd, Hg, Pb, Cu, Zn und Se in Pilzfruchtkoerper

    Energy Technology Data Exchange (ETDEWEB)

    Suehs, K.

    With mushrooms of the species Agaricus bisporus and Boletus badius the simultaneous uptake of the heavy metals Cd, Hg, Pb, Cu, Zn, and Se from soil to the sporophore was studied. To avoid misleadingly overrated enrichmentfactors when comparing the heavy metal contents of dried mushrooms and soils, a so-called transfer factor TF[sub v] which is related to the volume is put to discussion here, this factor takes account of the relatively small amount of dry matter in mushrooms and of the different composition (that means specific weight) of the soils in question. With help of these transfer factors the conclusion is derived, that essential elements show a better enrichment behaviour than biologically superfluous heavy metals, at least this is true with the insignificantly contaminated soils we investigated. With Cd as an example of a ''superfluous'' element it is shown that there is a strict proportionality of Cd concentrations in the mushrooms and the corresponding soils, thus producing a constant transfer factor. Apart from this the uptake of copper into the mushrooms is promoted (growth of the transfer factor) by a larger Cd supply, whereas the other elements under investigation (even the classical antagonist Zn) are not significantly affected. Furthermore there is evidence that with increasing heavy metal concentration (Cd) first the fructification of the thallus is supported and moreover, that increasing age of this primary fungus corresponds with an increase of heavy metals in the mushrooms. (orig.)

  13. Valores de referência de qualidade para metais pesados em solos no Estado do Espírito Santo

    Directory of Open Access Journals (Sweden)

    Henrique de Sá Paye

    2010-12-01

    Full Text Available Valores de referência de qualidade (VRQ para metais pesados em solos, em âmbito mundial, são bastante heterogêneos. No Brasil, poucos estudos para estabelecer esses valores foram concluídos. Na ausência de VRQ para metais pesados em solos, estabelecidos para as condições do Estado do Espírito Santo, utilizam-se valores genéricos internacionais ou desenvolvidos para outros Estados. Entretanto, deve-se ressaltar que o uso desses valores pode levar a avaliações inadequadas, já que existem diferenças nas condições técnicas e variáveis ambientais de cada região, em especial das condições geológicas, hídricas e pedológicas. Essas diferenças justificam o desenvolvimento de uma tabela própria com VRQ para metais pesados em solos, adequada às condições do Estado do Espírito Santo. Nesse sentido, o presente estudo buscou obter os teores naturais de 10 metais pesados e verificar a distribuição desses elementos nos solos das bacias hidrográficas Riacho, Reis Magos e Santa Maria da Vitória, no Estado do Espírito Santo, tendo em vista o estabelecimento de Valores de Referência de Qualidade (VRQ. Para isso, foram determinados os teores totais por ataque ácido, com digestão em forno micro-ondas, conforme o método SW-846 3052 da Environmental Protection Agency (USEPA e dosagem por espectrofotometria de emissão óptica com plasma induzido (ICP- OES. Os teores totais extraídos nos solos dessas bacias hidrográficas são relativamente baixos e inferiores aos reportados para solos de regiões brasileiras e de outros países. Os teores de cádmio ficaram abaixo do limite de detecção (LD do método para todas as amostras. Em consequência, os VRQ obtidos para 12 metais pesados no Estado do Espírito Santo foram semelhantes ou inferiores aos obtidos para outras regiões do Brasil e do mundo. Os VRQ obtidos a partir do percentil 75 (quartil superior para As (< 12,83, Cd (< 0,13, Co (10,21, Cr (54,13, Cu (5,91, Mn (137,80, Mo (1

  14. Avaliação da contaminação do Igarapé do Sabino (Bacia do Rio Tibiri por metais pesados, originados dos resíduos e efluentes do Aterro da Ribeira, em São Luís, Maranhão Evaluation of contamination on Sabino streamlet (Basin Rio Tibiri by heavy metals originated from waste and effluents of the Ribeira landfill, in São Luis island, state of Maranhão, Brazil

    Directory of Open Access Journals (Sweden)

    Antonio Eduardo Lopes Campos

    2009-01-01

    Full Text Available This work aimed to carry out an environmental monitoring in sabino narrow river (affluent of Tibiri Basin, in São Luís - MA, Brazil, in order to verify the main environmental impacts caused by effluent residues from Ribeira landfill. Chemical analysis and bibliographic and cartographic researches on this ecosystem were also carried out. In addition, heavy metals, such as Hg, Pb and Zn, were investigated in water samples by ICP-MS technique. It was observed that the contents of such heavy metals were above the tolerance limits established by the Brazilian legislation, showing a strong impact level on the evaluated ecosystem.

  15. [Spatial distribution and environmental risk of As and Pb from street dust in non-ferrous metals smelting areas].

    Science.gov (United States)

    Xu, Su-juan; Zheng, Na; Liu, Jing-shuang; Sun, Chong-yu; Wang, Yang; Chang, Shou-zhi

    2011-05-01

    ArcGIS analysis was applied to study the content level and the spatial distribution characteristics of As and Pb in street dust of Huludao city. Geoaccumulation Indexes and Potential Ecological Risk Index technique were applied to assess the ecological risk of As and Ph. The average contents of As and Pb were 33.10 mg x kg(-1) and 533.2 mg x kg(-1), which was 4 and 25 times as high as the background value respectively. The trends for Pb and As were similar with higher concentrations near Huludao Zinc Plant (HZP). The ecological risk of As and Pb contamination in street dust were serious, and the accumulation of Pb in street dust was higher than the As.

  16. Toxic metals (Pb and Cd) and their respective antagonists (Ca and Zn) in infant formulas and milk marketed in Brasilia, Brazil.

    Science.gov (United States)

    De Castro, Clarissa S P; Arruda, Andréa F; Da Cunha, Leandro R; SouzaDe, Jurandir R; Braga, Jez W B; Dórea, José G

    2010-11-01

    In non-ideal scenarios involving partial or non-breastfeeding, cow's milk-based dairy products are mainstream in infant feeding. Therefore, it is important to study the concentrations of potentially neurotoxic contaminants (Pb and Cd) and their respective counteracting elements (Ca and Zn) in infant dairy products. Fifty-five brands of infant formulas and milk sold in Brasilia, Brazil were analyzed. The dairy products came from areas in the central-west (26%), southeast (29%) and south of Brazil (36%) extending as far as Argentina (7%) and the Netherlands (2%). For toxic Pb and Cd, median concentrations in powdered samples were 0.109 mg/kg and 0.033 mg/kg, respectively; in fluid samples median Pb concentration was 0.084 mg/kg, but median Cd concentration was below the limit of detection and overall values were below reference safety levels. However, 62% of these samples presented higher Pb concentration values than those established by FAO/WHO. Although the inverse correlation between Cd and Zn (Spearman r = -0.116; P = 0.590) was not statistically significant, the positive correlation between Ca and Pb was (Spearman r = 0.619; P < 0.0001). Additionally, there was a significant correlation between Pb and Cd. Furthermore, the study also revealed that provision of the essential trace element Zn in infant formulas can provide adequate amounts of the recommended daily requirements. Infant formulas and milk sold for consumption by infants and children can be an efficient tool to monitor neurotoxic metal risk exposure among young children.

  17. Toxic Metals (Pb and Cd and Their Respective Antagonists (Ca and Zn in Infant Formulas and Milk Marketed in Brasilia, Brazil

    Directory of Open Access Journals (Sweden)

    José G. Dórea

    2010-11-01

    Full Text Available In non-ideal scenarios involving partial or non-breastfeeding, cow’s milk-based dairy products are mainstream in infant feeding. Therefore, it is important to study the concentrations of potentially neurotoxic contaminants (Pb and Cd and their respective counteracting elements (Ca and Zn in infant dairy products. Fifty-five brands of infant formulas and milk sold in Brasilia, Brazil were analyzed. The dairy products came from areas in the central-west (26%, southeast (29% and south of Brazil (36% extending as far as Argentina (7% and the Netherlands (2%. For toxic Pb and Cd, median concentrations in powdered samples were 0.109 mg/kg and 0.033 mg/kg, respectively; in fluid samples median Pb concentration was 0.084 mg/kg, but median Cd concentration was below the limit of detection and overall values were below reference safety levels. However, 62% of these samples presented higher Pb concentration values than those established by FAO/WHO. Although the inverse correlation between Cd and Zn (Spearman r = −0.116; P = 0.590 was not statistically significant, the positive correlation between Ca and Pb was (Spearman r = 0.619; P < 0.0001. Additionally, there was a significant correlation between Pb and Cd. Furthermore, the study also revealed that provision of the essential trace element Zn in infant formulas can provide adequate amounts of the recommended daily requirements. Infant formulas and milk sold for consumption by infants and children can be an efficient tool to monitor neurotoxic metal risk exposure among young children.

  18. Influence of N deficiency and salinity on metal (Pb, Zn and Cu) accumulation and tolerance by Rhizophora stylosa in relation to root anatomy and permeability

    International Nuclear Information System (INIS)

    Cheng Hao; Wang Youshao; Ye Zhihong; Chen Danting; Wang Yutu; Peng Yalan; Wang Liying

    2012-01-01

    Effects of N deficiency and salinity on root anatomy, permeability and metal (Pb, Zn and Cu) translocation and tolerance were investigated using mangrove seedlings of Rhizophora stylosa. The results showed that salt could directly reduce radial oxygen loss (ROL) by stimulation of lignification within exodermis. N deficiency, oppositely, would reduce lignification. Such an alteration in root permeability may also influence metal tolerance by plants. The data indicated that a moderate salinity could stimulate a lignified exodermis that delayed the entry of metals into the roots and thereby contributed to a higher metal tolerance, while N deficiency would aggravate metal toxicity. The results from sand pot trail further confirmed this issue. This study provides a barrier property of the exodermis in dealing with environments. The plasticity of root anatomy is likely an adaptive strategy to regulate the fluxes of gases, nutrients and toxins at root–soil interface. - Highlights: ► Salt induced lignified exodermis which slowed down metal entry into the plants. ► N deficiency, oppositely, aggravated metal mobility and toxicity. ► Barrier properties of the exodermis. - N deficiency and salinity regulate the apoplastic transport barrier of metals and their toxicities

  19. Effects of heavy metal concentrations (Cd, Zn and Pb) in agricultural soils near different emission sources on quality, accumulation and food safety in soybean [Glycine max (L.) Merrill

    International Nuclear Information System (INIS)

    Salazar, María Julieta; Rodriguez, Judith Hebelen; Nieto, Gastón Leonardo; Pignata, María Luisa

    2012-01-01

    Highlights: ► Soybean grown near metal sources presents a toxicological hazard from heavy metals for Chinese consumers. ► Rhizosphere soil is the most suitable compartment for toxicological studies. ► Soil guidelines should be modified considering the exchangeable metals. - Abstract: Argentina is one of the major producers of soybean in the world, this generates a high global demand for this crop leading to find it everywhere, even close to human activities involving pollutant emissions. This study evaluated heavy metal content, the transfer of metals and its relation to crop quality, and the toxicological risk of seed consumption, through soil and soybean sampling. The results show that concentrations of Pb and Cd in soils and soybeans at several sites were above the maximum permissible levels. The heavy metal bioaccumulation depending on the rhizosphere soil compartment showed significant and high regression coefficients. In addition, the similar behavior of Cd and Zn accumulation by plants reinforces the theory of other studies indicating that these metals are incorporated into the plant for a common system of transport. On the other hand, the seed quality parameters did not show a clear pattern of response to metal bioacumulation. Taken together, our results show that soybeans grown nearby to anthropic emission sources might represent a toxicological hazard for human consumption in a potential Chinese consumer. Hence, further studies should be carried out taking into account the potential negative health effects from the consumption of soybeans (direct or indirect through consumption of meat from cattle) in these conditions.

  20. Growth of PbTe nanorods controlled by polymerized tellurium anions and metal(II) amides via composite-hydroxide-mediated approach

    International Nuclear Information System (INIS)

    Wan Buyong; Hu Chenguo; Liu Hong; Xiong Yufeng; Li Feiyun; Xi Yi; He Xiaoshan

    2009-01-01

    The pure face-centered-cubic PbTe nanorods have been synthesized by the composite-hydroxide-mediated approach using hydrazine as a reducing agent. The method is based on reaction among reactants in the melts of potassium hydroxide and sodium hydroxide eutectic at 170-220 deg. C and normal atmosphere without using any organic dispersant or surface-capping agent. Scanning electron microscopy, X-ray diffraction, transmission electron microscopy, and energy dispersive X-ray spectroscopy were used to characterize the structure, morphology and composition of the samples. The diameters of nanorods are almost fixed, while the lengths can be tunable under different growth time and temperatures. The growth mechanism of PbTe nanorods is investigated via UV-vis absorption, demonstrating that polymerized tellurium anions and metal(II) amides in the hydrazine hydroxide melts could control the crystallization and growth process of PbTe nanostructures. The band gap of as-synthesized PbTe nanorods has been calculated based on UV-vis-NIR optical diffuse reflectance spectra data.

  1. Experimental Phase Equilibria Studies of the Pb-Fe-O System in Air, in Equilibrium with Metallic Lead and at Intermediate Oxygen Potentials

    Science.gov (United States)

    Shevchenko, M.; Jak, E.

    2017-12-01

    The phase equilibria information on the Pb-Fe-O system is of practical importance for the improvement of the existing thermodynamic database of lead-containing slag systems (Pb-Zn-Fe-Cu-Si-Ca-Al-Mg-O). Phase equilibria of the Pb-Fe-O system have been investigated: (a) in air at temperatures between 1053 K and 1373 K (780 °C and 1100 °C); (b) in equilibrium with metallic lead at temperatures between 1053 K and 1373 K (780 °C and 1100 °C); and (c) at intermediate oxidation conditions for the liquid slag in equilibrium with two solids (spinel + magnetoplumbite), at temperatures between 1093 K and 1373 K (820 °C and 1100 °C). The high-temperature equilibration/quenching/electron probe X-ray microanalysis technique has been used to accurately determine the compositions of the phases in equilibrium in the system. The Pb and Fe concentrations in the phases were determined directly; preliminary thermodynamic modeling with FactSage was used to estimate the ferrous-to-ferric ratios and to present the results in the ternary diagram.

  2. Toxic metal (Pb, Cd, Cr, and Hg) levels in Rapana venosa (Valenciennes, 1846), Eriphia verrucosa (Forskal, 1775), and sediment samples from the Black Sea littoral (Thrace, Turkey).

    Science.gov (United States)

    Mülayim, A; Balkıs, H

    2015-06-15

    Rapana venosa (Valenciennes, 1846) and Eriphia verrucosa (Forskal, 1775) are the dominant benthic invertebrate species along the Thrace Coast of the western Black Sea. The aim of this study was to determine toxic metal (Hg, Cr, Cd, and Pb) accumulation levels in these species, as well as within littoral sediments from this area. Our results showed that all of the metals, except for Cd, were below that in average shale. The measured accumulation levels were mostly within the range of what is naturally found within the earth's crust. However, some study stations did have increased concentrations, indicating anthropogenic pollution in these areas. The Cd contents of E. verrucosa collected from all our study stations were well above the limits set by the Turkish Food Codex, especially in Kıyıköy, whereas Pb content was close to the limit at all stations and exceeded the limit in Kıyıköy, but Hg content was below the limit at all stations. Cd content of R. venosa exceeded the limit only in Kumköy. Pb content was below the limit, and Hg was at or slightly above the limit at all stations. Copyright © 2015 Elsevier Ltd. All rights reserved.

  3. Evaluation of toxic metal (Hg, Cd, Pb), polychlorinated biphenyl (PCBs), and pesticide (DDTs) levels in aromatic herbs collected in selected areas of Southern Italy.

    Science.gov (United States)

    Storelli, Maria Maddalena

    2014-01-01

    This study provides, for the first time, data regarding levels of toxic metals (Hg, Cd, and Pb) and organochlorine compounds (PCBs and DDTs) in various aromatic herbs as rosemary (Rosmarinus officinalis), sage (Salvia officinalis), laurel (Laurus nobilis), oregano (Origanum vulgare), and spearmint (Mentha viridis) collected in some towns of the Southern Italy with different anthropogenic and population pressure. Metal and organochlorine compound concentrations were determined using atomic absorption spectrophotometer and gas-chromatography mass spectrometer (GC/MS), respectively. Pb emerged as the most abundant element, followed by Cd and Hg, while between organochlorine compounds, PCB concentrations were higher than those of DDTs. The pollutant concentrations were found to vary depending on the different herbs. The highest Pb levels were observed in rosemary (1.66 μg g(-1) dry weight) and sage (1.41 μg g(-1) dry weight), this latter showing also the highest Cd concentrations (0.75 μg g(-1) dry weight). For PCBs, the major concentrations were found in rosemary (2.75 ng g(-1) dry weight) and oregano (2.39 ng g(-1) dry weight). The principal component analysis applied in order to evaluate possible similarities and/or differences in the contamination levels among sampling sites indicated differences area-specific contamination.

  4. Concentration of heavy metal As, Pb, Mn, Ni, Sn, Zn, Cr, Fe and radon gas in bottom sediment from abandoned tin mines in the Phuket Province

    Directory of Open Access Journals (Sweden)

    Suteerasak, T.

    2006-05-01

    Full Text Available This research is aimed at analyzing the heavy metals: As, Pb, Mn, Ni, Sn, Zn, Cr, Fe, and radon gas emission in bottom sediment from six abandoned tin mines in Phuket Province. Fe, Mn, and Sn were found in higher concentrations (but non-polluting than Cr and Ni. As, Pb, and Zn were polluting at lower levels. The concentration ranges for As, Pb, and Zn were 75.3-169, 98.6-547.5, and 120.4-323.3 mg/kg respectively. The activity of radon gas emission from bottom sediment from an abandoned tin mine in Amphur Muang was in the range of 162-212 Bq/kg., in the Amphur Katoo mine the range was 122-266 Bq/kg. and in the Amphur Talang mine the range was 180-263 Bq/kg. All these sites have higher concentrations of radon gas emissions than other similar sites. The heavy metals and radon gas come from geochemical materials such as soil and granite rock, found around the abandoned tin mines.

  5. Contenido de metales en Cancer polyodon (Crustacea: Decapoda en un sistema de bahías del norte de Chile (27°S Metal contents in Cancer polyodon (Crustacea: Decapoda in a bay system of northern Chile (27°S

    Directory of Open Access Journals (Sweden)

    Alexis Castillo

    2011-11-01

    Full Text Available El contenido de Zn, Cu, Cd, Pb, Fe, Al y Ni fue analizado en tejido muscular de Cancer polyodon en las bahías de Caldera, Calderilla, Inglesa y Salada (Atacama, Chile. Los resultados fueron comparados con estudios similares desarrollados por otros autores y la normativa de carácter nacional e internacional relacionada con el contenido de metales pesados en crustáceos para consumo humano. El orden de abundancia de los metales analizados en C. polyodon fue CdThe contents of Zn, Cu, Cd, Pb, Fe, Al and Ni in the muscle tissue of Cancer polyodon from Caldera, Calderilla, Inglesa, and Salada bays (Atacama, Chile were quantified. The results were compared with similar studies by other authors and with the national and international regulatory standards for heavy metal contents in crustaceans for human consumption. In increasing order, the metal contents in C. polyodon were: Cd< Ni< Cu< Pb< ZnPb, Fe and Al were highest in Salada Bay: Cu and Ni were highest in Caldera Bay; and Zn was highest in Inglesa Bay. All the metals except Cu differed significantly (P < 0.05 among the analyzed bays. Of the seven metals analyzed, Pb, Fe, and Al concentrations in C. polyodon were higher than those reported for other coastal systems. Concentrations of Cu (except Calderilla, Cd (except Caldera and Inglesa, and Pb exceeded the threshold values indicated by the national and international standards, suggesting that the presence of these metals in C. polyodon represents a potential risk for human health.

  6. An analysis of heavy metals (Cr, Cu, Ni, Pb) in leachate and water samples taken from San Mateo landfill and Payatas dumpsite

    International Nuclear Information System (INIS)

    Almario, Christine D.; Benedicto, Ma. Victoria S.

    2003-01-01

    This study was conducted to determine the concentration of heavy metals specifically Cr, Cu, Ni, Pb in leachate and water samples taken from the open dumpsite of Payatas and San Mateo landfill. The leachate samples were collected from the maturation pond of San Mateo landfill and from Payatas open dumpsite. The water samples were obtained from Pintong Bocaue and Sapinit deep wells from San Mateo landfill while for Payatas dumpsite deep well waters from the immediate vicinities were used. The sample obtained was then subjected to atomic absorption spectrophotometry for quantitative determination of the heavy metals. The results of the analysis of concentration of trace metals were expressed in mg/L or ppm. (Authors)

  7. Evaluation of heavy metals (Cr, Fe, Ni, Cu, Zn, Cd, Pb and Hg) in water, sediments and water lily (Eichornia crassipes) from Jose Antonio Alzate dam

    International Nuclear Information System (INIS)

    Avila P, P.

    1995-01-01

    Water, sediments and water lily (Eichornia crassipes) from the Jose Antonio Alzate Dam were analyzed in order to determine concentrations of chromium, iron, nickel, copper, zinc, cadmium, lead and mercury. Mercury, lead, chromium and iron were found in concentrations above permissible limits in water, and in high concentrations in sediments. Cadmium, nickel, copper and zinc never were found in concentrations above permissible limits in water. The highest concentrations of heavy metals in water lily were found in the root. Accumulation factors decreased in the following order: Zn> Cr> Fe> Ni> Cu> Pb> Hg and Cd. Statistical differences (α < 0.5) between the collection samples dates was observed. High correlations between metals concentrations in superficial water, sediment and water hyacinth were also observed. These correlations could indicate that the heavy metals studied here, are originated from a natural source such as sediments or from an industrial source. (Author)

  8. Self-assembly of tetracyanonaphtho-quinodimethane (TNAP) based metal-organic networks on Pb(1 1 1): Structural, electronic, and magnetic properties

    Science.gov (United States)

    Ahmadi, Gelavizh; Franke, Katharina J.

    2016-06-01

    We use scanning tunneling microscopy and spectroscopy to investigate structural and electronic properties of tetracyanonaphtho-quinodimethane (TNAP) based metal-organic networks on a superconducting Pb(1 1 1) surface. At low temperatures, the TNAP molecules form densely packed islands. When deposited at room temperature, Pb adatoms are incorporated into fourfold bonding nodes with the TNAP molecules leading to long-range ordered porous structures. Co-deposition of NaCl with TNAP yields a Na source for an ionically bonded Na-TNAP structure. Fourfold bonding motifs are also created by Fe atoms with the cyano terminations of TNAP. However, the structures are irregular and do not sustain the formation of long-range ordered networks. Some Fe centers with molecules surrounded in a local C2 symmetry exhibit Shiba states as a fingerprint of a magnetic interaction with the superconducting surface.

  9. Effects of Cd- and Pb-resistant endophytic fungi on growth and phytoextraction of Brassica napus in metal-contaminated soils.

    Science.gov (United States)

    Shi, Yanan; Xie, Huarong; Cao, Lixiang; Zhang, Renduo; Xu, Zaichao; Wang, Zhuoya; Deng, Zujun

    2017-01-01

    Metal-resistant endophytic fungi from roots improved phytoremediation efficacy of host plants; however, the effects of endophytic fungi from plant aerial parts on host plants are unknown. The aim of this study was to develop a feasible method to screen fungal endophytes from stems and roots of Brassica napus and to investigate effects of the endophytic fungi on growth and phytoremediation efficiency of the plant. Endophytic Fusarium sp. CBRF44, Penicillium sp. CBRF65, and Alternaria sp. CBSF68 with different traits were isolated from roots and stems of rapes grown in a metal-contaminated soil. Fusarium sp. CBRF44 (resistant to 5 mM Cd and 15 mM Pb, isolated from roots) and Alternaria sp. CBSF68 (resistant to 1 mM Cd and 10 mM Pb, isolated from stems) could produce indole-3-acetic acid (IAA) and siderophore; Penicillium sp. CBRF65 (tolerate 2 mM Cd and 20 mM Pb, isolated from roots) could not produce IAA and siderophore but showed the highest phosphate-solubilizing activities. Fusarium sp. CBRF44 and Penicillium sp. CBRF65 significantly increased the rape biomass and promoted the extraction efficacy of Pb and Cd, while Alternaria sp. CBSF68 did not show similar results. Penicillium sp. CBRF65 and Fusarium sp. CBRF44 could be frequently recovered from inoculated rape roots, while Alternaria sp. CBSF68 was scarcely recovered. The results indicate that the colonizing capacity of endophytic fungi in roots is important to improve phytoremediation efficacy of host plants.

  10. Effect of Glomus intraradices isolated from Pb-contaninated soil on Pb uptake by Agrostis capillaris is changed by its cultivation i a metal-free substrate

    Czech Academy of Sciences Publication Activity Database

    Rydlová, Jana; Vosátka, Miroslav

    2003-01-01

    Roč. 38, - (2003), s. 155-165 ISSN 0015-5551 R&D Projects: GA AV ČR KSK6005114; GA MŠk OC 838.10; GA ČR GA526/99/P032; GA ČR GA526/99/0895 Institutional research plan: CEZ:AV0Z6005908 Keywords : arbuscular mycorrhizal fungi * heavy metal tolerance * lead contamination Subject RIV: EF - Botanics Impact factor: 1.057, year: 2003

  11. Metais pesados em solos de área de rejeitos de indústria de processamento de zinco

    Directory of Open Access Journals (Sweden)

    M. R. Ribeiro-Filho

    1999-06-01

    Full Text Available Apesar de a poluição do solo ser amplamente constatada, estudos sobre as concentrações e formas dos metais pesados em solos e seus efeitos no ecossistema são ainda pouco enfatizados, principalmente em condições tropicais. O presente estudo foi desenvolvido em área de rejeitos de uma unidade de extração e industrialização de zinco pertencente à Companhia Mineira de Metais-CMM, em Três Marias (MG, com o objetivo de avaliar as quantidades e formas de metais pesados em sete locais representativos da área. Os locais foram selecionados para amostragem, baseando-se em diferenças na forma de contaminação, aspectos de solo, topografia e vegetação. Realizaram-se análises químicas de fracionamento de metais pesados e extrações simples com DTPA e Mehlich-1, buscando determinar os teores e formas dos metais na superfície e em profundidade e fazer inferências sobre o potencial de risco ambiental desses metais. Os teores totais dos metais nas camadas superficiais dos locais estudados foram, em média, de: 13.533 mg kg-1, para Zn; 170 mg kg-1, para Cd; 865 mg kg-1, para Cu, e 612 mg kg-1, para Pb, enquanto os teores trocáveis (MgCl2 nessas mesmas camadas variaram de 231 a 1.407 mg kg-1, para Zn; 14 a 390 mg kg-1, para Cd, e 11 a 33 mg kg-1, para Pb; o Cu raramente ocorreu nesta forma. Os solos dos locais estudados, com teores excessivos de Zn, Cd, Cu e Pb, são considerados poluídos. Em determinados locais contaminados por escoamento (superficial e subsuperficial e arraste de material de solo e rejeito, a poluição mostrou-se mais evidente nas camadas superficiais. No local da ustulação, verificou-se maior percentagem de Zn trocável em todos os níveis de profundidade. Nos demais locais, o Cd apresentou também grandes concentrações nas formas trocáveis, razão por que tal elemento oferece maior risco de contaminação ambiental. De modo geral, a ocorrência de Zn foi maior nas formas carbonato e residual, enquanto o Cd

  12. Combined impact of heavy metals (Pb2+ and Cd2+ and salinity on the condition of Lolium perenne long-term assimilation apparatus

    Directory of Open Access Journals (Sweden)

    V. P. Bessonova

    2014-12-01

    Full Text Available Contamination of soil and atmosphere by heavy metals negatively affects physiological and biochemical processes in plants. The objective of this study is to analyze the combined impact of heavy metals Pb2+ and Cd2+ on the background of salinity on the surface of assimilation and the state of stomata device and the content of plastid pigments in leaves of Lolium perenne L. Decrease in the area of plant leaves on the background of the impact of pollutants has been determined. By the degree of increase of negative impact on this index, variants of the experience can be arranged as follows: Pb2+ + Cd2+ < NaCl < Pb2+ + Cd2+ + NaCl. The investigated factors have the strongest impact on the area of assimilation surface. The reason for its significant decrease in plants of studied variants compared to the control is that both suppression of growth and reduction of leaves area occurs, along with the inhibition of their formation. The damaging effect of sodium chloride is also traced in drying of leaf tips, the latter become lighter in color and some of them get yellow. Under the action of heavy metals and salinity decrease in the leaf index for L. perenne is observed, especially in case of combined actions of toxins, and this rate varies more significantly than the other ones. Salinization of growing substrate significantly reduces the number of stomata on the underside of the leaf epidermis. On the contrary, under the influence of heavy metals their number increases, and under the action of Pb2+ + Cd2+ on the background of chloride salinity it becomes even higher compared with the variant where heavy metals only affect the plants. The length of guard cells of the stomata in the variants with metals in NaCl remains practically unchanged compared with the control, but at joint action it is reduced. The width of stomatal pore in the variants differs insignificantly. The same is applied to the length, except for variants where the plants were exposed

  13. Distribution of some heavy and essential metals Cd, Pb, Cu, Fe and Zn in Mango fruit (Mangifera Indica L. cultivated in Different Regions of Pakistan

    Directory of Open Access Journals (Sweden)

    NUSRAT jalbani

    2015-12-01

    Full Text Available  In the present study, the concentrations of Cd, Pb, Cu, Zn and Fe from 50 mango samples (Mangifera indica L. were detected by electro-thermal/flame atomic absorption spectrometry (ETAAS/FAAS. In this study three varieties such as Dusahri, Langra and Chaunsa were collected from different regions (Multan, Sadiqabad, Rahimyar Khan and Mirpurkhas of Pakistan.  The effect of different varieties and environmental conditions on metal accumulation was also investigated. The aim of this study is to compare the level of essential and toxic metal in different regions and correlate the differences observed in metal accumulation to environmental conditions. The accuracy of the conventional acid digestion (CAD method was checked by analyzing Certified Reference Materials (CRM i.e. fortified water (TMDA-70, apple leaves (1515 and standard addition technique. The limit of detections (LODs of the method were found to be 0.113, 2.0, 22.7, 3.85 and 3.05 µg L-1 for Pb, Cd, Cu, Fe, and Zn, respectively.

  14. Experimental Study of Liquidus of the "FeO"-SiO2-PbO Slags in Equilibrium with Air and with Metallic Lead

    Science.gov (United States)

    Shevchenko, Maksym; Hidayat, Taufiq; Hayes, Peter C.; Jak, Evgueni

    Limited data are available on phase equilibria of the "FeO"-SiO2-PbO slag system at conditions used in the lead smelting due to difficulties from lead vaporization and interactions with metal and ceramic crucibles. Recently experimental procedures have been developed and successfully applied to complex industrial slag-metal-matte systems involving high temperature equilibration on a primary phase substrate and rapid quenching followed by the electron probe X-ray microanalysis. The liquidus isotherms and invariant lines in the "FeO"-SiO2-PbO slag system in equilibrium with air and with metallic lead have been constructed. Preliminary data compared to the FactSage package predictions demonstrate differences in some aspects, indicating the possibility for further improvement of the thermodynamic database. The present work is a part of the integrated experimental and thermodynamic modelling research program on multi-phase lead systems in support of the optimization and development of complex lead smelting, refining and recycling technologies.

  15. Heavy metals (Cd, Cu, V, Pb in rainwater in the most influence area of the coal mine in La Guajira, Colombia

    Directory of Open Access Journals (Sweden)

    CARLOS JULIO DORIA ARGUMEDO

    2017-05-01

    Full Text Available To measure the influence of coal mining activities on air quality in northern Colombia, a first approach was made to assess pollution by measuring the levels of the heavy metals Cu, Cd, V and Pb in 21 samples of rainfall over a one year period, by the electrothermal atomic absorption spectrometry technique. The average concentrations of metals in the study area in wet precipitation were: Cu 23.47 ± 13.97µg/L, Cd 4.72 ± 3.29µg/L y V 11.25 ± 6.75µg/L. The results suggest that the atmosphere is not polluted by Pb, but mining activities (excavation and blasting, combustion of fossil fuels, crude oil and gas oil, and vehicular traffic sources may significantly affect the presence and the levels of the other studied metals. Contamination in the area makes rain water infringe the quality standards, both nationally and internationally, since the parameters of pH and Cd exceed the permissible limits, therefore it is not suitable for human consumption.

  16. Spatial and Temporal Distribution of Trace Metals (Cd, Cu, Ni, Pb, and Zn in Coastal Waters off the West Coast of Taiwan

    Directory of Open Access Journals (Sweden)

    Kuo-Tung Jiann

    2014-01-01

    Full Text Available Surface water samples were collected along the west coast of Taiwan during two expedition cruises which represent periods of different regional climatic patterns. Information on hydrochemical parameters such as salinity, nutrients, suspended particulate matter (SPM, and Chlorophyll a concentrations were obtained, and dissolved and particulate trace metal (Cd, Cu, Ni, Pb, and Zn concentrations were determined. Spatial variations were observed and the differences were attributed to (1 influence of varying extents of terrestrial inputs from the mountainous rivers of Taiwan to the coast, and (2 urbanization and industrialization in different parts of the island. Geochemical processes such as desorption (Cd and adsorption to sinking particles (Pb also contributed to the variability of trace metal distributions in coastal waters. Results showed temporal variations in chemical characteristics in coastal waters as a consequence of prevailing monsoons. During the wet season when river discharges were higher, the transport of particulate metals was elevated due to increased sediment loads. During the dry season, lower river discharges resulted in a lesser extent of estuarine dilution effect for chemicals of anthropogenic sources, indicated by higher dissolved concentrations present in coastal waters associated with slightly higher salinity.

  17. Highly selective removal of Hg2+ and Pb2+ by thiol-functionalized Fe3O4@metal-organic framework core-shell magnetic microspheres

    Science.gov (United States)

    Ke, Fei; Jiang, Jing; Li, Yizhi; Liang, Jing; Wan, Xiaochun; Ko, Sanghoon

    2017-08-01

    In this work, we report a novel type of thiol-functionalized magnetic core-shell metal-organic framework (MOF) microspheres that can be potentially used for selective removal of Hg2+ and Pb2+ in the presence of other background ions from wastewater. The monodisperse Fe3O4@Cu3(btc)2 core-shell magnetic microspheres have been fabricated by a versatile step-by-step assembly strategy. Further, the thiol-functionalized Fe3O4@Cu3(btc)2 magnetic microspheres were successfully synthesized by utilizing a facile postsynthetic strategy. Significantly, the thiol-functionalized Fe3O4@Cu3(btc)2 magnetic microspheres exhibit remarkably selective adsorption affinity for Hg2+ (Kd = 5.98 × 104 mL g-1) and Pb2+ (Kd = 1.23 × 104 mL g-1), while a weaker binding affinity occurred for the other background ions such as Ni2+, Na+, Mg2+, Ca2+, Zn2+ and Cd2+. The adsorption kinetics follow the pseudo-second-order rate equation and with an almost complete removal of Hg2+ and Pb2+ from the mixed heavy metal ions wastewater (0.5 mM) within 120 min. Moreover, this adsorbent can be easily recycled because of the presence of the magnetic Fe3O4 core. This work provides a promising functionalized porous magnetic Fe3O4@MOF-based adsorbent with easy recycling property for the selective removal of heavy metal ions from wastewater.

  18. Soil contaminated phyto remediation of Pb and cd metal by using rice straw fermented by trichoderma viride that given exposure 250 gray doses of gamma radiation

    International Nuclear Information System (INIS)

    Yullita SL Andini; Hendrawati; Tri Retno Diah Larasati; Nana Mulyana

    2015-01-01

    Soil contamination by lead (Pb) and cadmium (Cd) is one form of environmental pollution that is harmful to living organisms. One way to resolve this problem by using phyto remediation with rice straw fermented by Trichoderma viride that given exposure 250 gray doses of gamma radiation. The purpose of this study was to look at the effect of Trichoderma viride fermented hay to improve the ability of Pb and Cd accumulation in the root zone of plants sweet corn (Zea Mays). There are three stages in the research process, namely the stages of SSF (Solid State Fermentation), incorporation, and Land farming. The fermentation process is done during the 16-day trial. Furthermore, the results of the SSF (Solid State Fermentation) mixed in soil that has been contaminated with heavy metals showed that administration of straw result SSF real impact on the value of pH, water content of the four treated samples. Results incorporation process and then applied with a crop of sweet corn (Zea Mays). Accumulation of heavy metals in sweet corn plant, analyzed by AAS analysis instrumentation. The measurement results show that the accumulation of Pb in the roots of plants in the sample K amounted to 33.66 mg/Kg, A sample of 26.80 mg/Kg, the sample B of 51.47 mg/kg, and sample C of 55.70 mg/Kg. While the metals Cd uptake in the roots of corn plants in the sample K showed Cd uptake of 269.65 mg/Kg, the sample A of 445.70 mg/Kg, the sample B of 337.17 mg/Kg and sample C of 336.72 mg/Kg. The phyto remediation process takes place based on the fito-stabilization principle. (author)

  19. Removal of Ni(II), Zn(II) and Pb(II) ions from single metal aqueous solution using rice husk-based activated carbon

    Energy Technology Data Exchange (ETDEWEB)

    Taha, Mohd F., E-mail: faisalt@petronas.com.my; Shaharun, Maizatul S. [Fundamental and Applied Sciences Department, Universiti Teknologi PETRONAS, Bandar Seri Iskandar, 31750, Perak Darul Ridzuan (Malaysia); Shuib, Anis Suhaila, E-mail: anisuha@petronas.com.my; Borhan, Azry [Chemical Engineering Department, Universiti Teknologi PETRONAS, Bandar Seri Iskandar, 31750, Perak Darul Ridzuan (Malaysia)

    2014-10-24

    An attempt was made to investigate the potential of rice husk-based activated carbon as an alternative low-cost adsorbent for the removal of Ni(II), Zn(II) and Pb(II) ions from single aqueous solution. Rice husk-based activated carbon was prepared via treatment of rice husk with NaOH followed by the carbonization process at 400°C for 2 hours. Three samples, i.e. raw rice husk, rice husk treated with NaOH and rice husk-based activated carbon, were analyzed for their morphological characteristics using field-emission scanning electron microscope/energy dispersive X-ray (FESEM/EDX). These samples were also analyzed for their carbon, hydrogen, nitrogen, oxygen and silica contents using CHN elemental analyzer and FESEM/EDX. The porous properties of rice husk-based activated carbon were determined by Brunauer-Emmett-Teller (BET) surface area analyzer, and its surface area and pore volume were 255 m{sup 2}/g and 0.17 cm{sup 2}/g, respectively. The adsorption studies for the removal of Ni(II), Zn(II) and Pb(II) ions from single metal aqueous solution were carried out at a fixed initial concentration of metal ion (150 ppm) with variation amount of adsorbent (rice husk-based activated carbon) as a function of varied contact time at room temperature. The concentration of each metal ion was analyzed using atomic absorption spectrophotometer (AAS). The results obtained from adsorption studies indicate the potential of rice husk as an economically promising precursor for the preparation of activated carbon for removal of Ni(II), Zn(II) and Pb(II) ions from single aqueous solution. Isotherm and kinetic model analyses suggested that the experimental data of adsorption studies fitted well with Langmuir, Freundlich and second-order kinetic models.

  20. Ages and sources of components of Zn-Pb, Cu, precious metal, and platinum group element deposits in the goodsprings district, Clark County, Nevada

    Science.gov (United States)

    Vikre, Peter G.; Browne, Quentin J.; Fleck, Robert J.; Hofstra, Albert H.; Wooden, Joseph L.

    2011-01-01

    The Goodsprings district, Clark County, Nevada, includes zinc-dominant carbonate replacement deposits of probable late Paleozoic age, and lead-dominant carbonate replacement deposits, copper ± precious metal-platinum group element (PGE) deposits, and gold ± silver deposits that are spatially associated with Late Triassic porphyritic intrusions. The district encompasses ~500 km2 although the distribution of all deposits has been laterally condensed by late Mesozoic crustal contraction. Zinc, Pb, and Cu production from about 90 deposits was ~160,000 metric tons (t) (Zn > Pb >> Cu), 2.1 million ounces (Moz) Ag, 0.09 Moz Au, and small amounts of PGEs—Co, V, Hg, Sb, Ni, Mo, Mn, Ir, and U—were also recovered.Zinc-dominant carbonate replacement deposits (Zn > Pb; Ag ± Cu) resemble Mississippi Valley Type (MVT) Zn-Pb deposits in that they occur in karst and fault breccias in Mississippian limestone where the southern margin of the regional late Paleozoic foreland basin adjoins Proterozoic crystalline rocks of the craton. They consist of calcite, dolomite, sphalerite, and galena with variably positive S isotope compositions (δ34S values range from 2.5–13‰), and highly radiogenic Pb isotope compositions (206Pb/204Pb >19), typical of MVT deposits above crystalline Precambrian basement. These deposits may have formed when southward flow of saline fluids, derived from basinal and older sedimentary rocks, encountered thinner strata and pinch-outs against the craton, forcing fluid mixing and mineral precipitation in karst and fault breccias. Lead-dominant carbonate replacement deposits (Pb > Zn, Ag ± Cu ± Au) occur among other deposit types, often near porphyritic intrusions. They generally contain higher concentrations of precious metals than zinc-dominant deposits and relatively abundant iron oxides after pyrite. They share characteristics with copper ± precious metal-PGE and gold ± silver deposits including fine-grained quartz replacement of carbonate minerals

  1. Geochemistry, water dynamics and metals: Major, trace elements, Pb and Sr isotope constraints on their origins and movements in a small anthropized catchment over a flood

    International Nuclear Information System (INIS)

    Luck, J.M.; Othman, D.B.

    1997-01-01

    Major, trace elements and Sr-Pb isotope data on the dissolved and particulate phases are reported for water samples taken regularly over the September flood of a Mediterranean river (S France). This river drains runoff from a small, carbonate, karstified watershed with Miocene and Jurassic lithologies, and characterized by agricultural, urban and road network activities. The objective is to combine all the data into a dynamic model for constraining the origin(s) and movements of waters and of their loads. Furthermore, for metals, it becomes then feasible to know their fate and bioavailability downstream

  2. Enriquecimiento, disponibilidad y contaminación de metales traza (Cd, Cu, Pb y Zn en sedimentos de lagunas urbanas de Concepción-Chile Enrichment, availability and contamination of trace metals (Cd, Cu, Pb and Zn in sediments of urban lagoons in Concepción, Chile

    Directory of Open Access Journals (Sweden)

    Elizabeth González Sepúlveda

    2009-01-01

    Full Text Available Trace metals (Cd, Cu, Pb and Zn enrichment, availability and contamination in superficial sediments of three interconnected urban lagoons localized in Concepción-Chile, were evaluated. According to the results of geochemical fracctionation analysis, Cu and Pb are rather associated with oxi-hydroxides, Cd is associated with exchangeable and carbonates fraction, while Zn is mainly associated with organic, oxi-hydroxides and residual fraction. The estimation of the availability percentages indicate that Cu is the most mobile metal and the less mobile is the Cd. An evaluation of the geo-accumulation index and urban industrial pollution allowed to classify the studied zone as moderately to highly contaminated.

  3. Remoção de metais pesados de efluentes aquosos pela zeólita natural escolecita - influência da temperatura e do pH na adsorção em sistemas monoelementares Heavy metals removal from wastewater by the natural zeolite scolecite - temperature and pH influence in single-metal solutions

    Directory of Open Access Journals (Sweden)

    Ricardo Sarti Jimenez

    2004-10-01

    Full Text Available Cation exchange capabilities of a Brazilian natural zeolite, identified as scolecite, were evaluated for application in wastewater control. We investigated the process of sorption of chromium(III, nickel(II, cadmium(II and manganese(II in synthetic aqueous effluents, including adsorption isotherms of single-metal solutions. The natural zeolite showed the ability to take up the tested heavy metals in the order Cr(III > Cd(II > Ni(II > Mn(II, and this could be related to the valence and the hydration radius of the metal cations. The influence of temperature (25, 40 and 60 ºC and initial pH value (from 4 to 6 was also evaluated. It was found that the adsorption increased substantially when the temperature was raised to 60 ºC and that maximum adsorption capacity was observed at pH 6. These results demonstrate that scolecite can be used for removal of heavy metals from aqueous effluents, under optimized conditions.

  4. The Existence of Heavy Metals such as Pb, Cd, Fe, and Cu in Hair Samples from Gas Station Worker at Yogyakarta Special District

    International Nuclear Information System (INIS)

    Supriyanto, C.; Zainul Kamal; Samin

    2002-01-01

    The monitoring of heavy metals existence such as Pb, Cd, Fe, and Cu in hair samples from gas station worker has been carried out with atomic absorption spectrometry method. The initial preparation of sample were done by immersing them in alcohol over night, after they were dried then they were digested using the teflon bomb digester at the temperature at 150 o C for 3 hours. The content of Pb, Cd, Fe, and Cu in were determined with calibration standard curve method. The content of Pb obtained at hair samples in the range of time at 20 years tend to increase. If it was correlated to the worker who has been working, there was no significant different from the worker who has been working for 20 years there was no significant different. While the content of Cu in sample at range time 20 years showed the significant different if it was correlated to the worker who has been working. The validity of method was tested with CRM Human Hair GBW 07601 from IAEA showed that the content of Fe and Cu were in the certified range of CRM. (author)

  5. In vitro effects of metal ions (Fe2+, Mn2+, Pb2+) on sperm motility and lipid peroxidation in human semen.

    Science.gov (United States)

    Huang, Y L; Tseng, W C; Lin, T H

    2001-02-23

    The effects of divalent manganese ion (Mn2+), ferrous iron (Fe2+), and lead ion (Pb2+) on human sperm motility and lipid peroxidation were examined. Human semen from healthy male volunteers was incubated with 0, 5, 50, or 500 ppm divalent metal ions, and the sperm motility was determined at 0, 2, 4, 6, or 8 h by microscopy. Malondialdehyde (MDA) levels in seminal plasma was measured by high-performance liquid chromatography after 8 h of exposure. The results showed that 500 ppm Mn2+ or Pb2+ significantly inhibited sperm motility without an accompanying change in seminal MDA levels. Incubation with Fe2+ significantly inhibited sperm motility at 5 ppm, associated with a marked rise in MDA levels. Our results suggested that Fe2+ may induce lipid peroxidation to inhibit sperm motility. In the case of Mn2+ and Pb2+ there is an absence of seminal lipid peroxidation and the observed inhibition of sperm motility at high concentrations is not biologically or environmentally relevant.

  6. Effects of heavy metal concentrations (Cd, Zn and Pb) in agricultural soils near different emission sources on quality, accumulation and food safety in soybean [Glycine max (L.) Merrill

    Energy Technology Data Exchange (ETDEWEB)

    Salazar, Maria Julieta [Multidisciplinary Institute of Plant Biology, Pollution and Bioindicator Section, Faculty of Physical and Natural Sciences, National University of Cordoba, Av. Velez Sarsfield 1611, X5016CGA Cordoba (Argentina); Rodriguez, Judith Hebelen, E-mail: jrodriguez@com.uncor.edu [Multidisciplinary Institute of Plant Biology, Pollution and Bioindicator Section, Faculty of Physical and Natural Sciences, National University of Cordoba, Av. Velez Sarsfield 1611, X5016CGA Cordoba (Argentina); Nieto, Gaston Leonardo; Pignata, Maria Luisa [Multidisciplinary Institute of Plant Biology, Pollution and Bioindicator Section, Faculty of Physical and Natural Sciences, National University of Cordoba, Av. Velez Sarsfield 1611, X5016CGA Cordoba (Argentina)

    2012-09-30

    Highlights: Black-Right-Pointing-Pointer Soybean grown near metal sources presents a toxicological hazard from heavy metals for Chinese consumers. Black-Right-Pointing-Pointer Rhizosphere soil is the most suitable compartment for toxicological studies. Black-Right-Pointing-Pointer Soil guidelines should be modified considering the exchangeable metals. - Abstract: Argentina is one of the major producers of soybean in the world, this generates a high global demand for this crop leading to find it everywhere, even close to human activities involving pollutant emissions. This study evaluated heavy metal content, the transfer of metals and its relation to crop quality, and the toxicological risk of seed consumption, through soil and soybean sampling. The results show that concentrations of Pb and Cd in soils and soybeans at several sites were above the maximum permissible levels. The heavy metal bioaccumulation depending on the rhizosphere soil compartment showed significant and high regression coefficients. In addition, the similar behavior of Cd and Zn accumulation by plants reinforces the theory of other studies indicating that these metals are incorporated into the plant for a common system of transport. On the other hand, the seed quality parameters did not show a clear pattern of response to metal bioacumulation. Taken together, our results show that soybeans grown nearby to anthropic emission sources might represent a toxicological hazard for human consumption in a potential Chinese consumer. Hence, further studies should be carried out taking into account the potential negative health effects from the consumption of soybeans (direct or indirect through consumption of meat from cattle) in these conditions.

  7. Quantification of heavy metals from residual waste and ashes from the treatment plant of residual water Reciclagua and,effects for the health of those workers which manipulate those residuals; Cuantificacion de metales pesados de lodo residual y cenizas de la planta tratadora de aguas residuales Reciclagua y efectos a la salud de los trabajadores que manipulan los residuos

    Energy Technology Data Exchange (ETDEWEB)

    Guerrero D, J.J

    2004-07-01

    In this work, the technique of leaching using thermostatted column in series is applied, the X-ray diffraction for the identification of the atomic and molecular structure of the toxic metals that are present in the residual muds of the water treatment plant located in the municipality of Lerma Estado de Mexico, named RECICLAGUA, likewise the technique is used of emission spectrometry for plasma and X-ray fluorescence for the qualitative analysis. Its were take samples of residual mud and of incinerated mud of the treatment plant of residual waters of the industrial corridor Toluca -Lerma RECICLAGUA, located in Lerma Estado de Mexico. For this study there were mixed 100 g of residual mud with a solution to 10% of mineral acid or sodium hydroxide according to the case, to adjust the one pH at 2, 5, 7 and 10, it was added bisulfite, of 0.3-1.5 g of dodecyl sulfate sodium and 3.939 of DTPA (triple V) (Diethylene triamine pentaacetate). To this mud and ashes were extracted the toxic and valuable metals by means of the leaching technique using thermostatted columns placed in series that were designed by the Dr. Jaime Vite Torres; it is necessary to make mention that so much the process as the equipment with those that work it was patented by the same one. With the extraction of these metals benefits are obtained, mainly of economic type, achieving the decrease of the volume of those wastes that have been generated; as well as the so much the use of those residuals, once the metals have been eliminated, as of those liquors where the metals were extracted. It was carried out a quantitative analysis using emission spectrometry by plasma in solids by this way to be able to know the content of the present metals in the sample before and later of leaching them, these results reported a great quantity of elements. Another of the techniques employees was the X-ray diffraction analysis that provides an elementary content of the samples, identifying elements that are present in

  8. Thermoelectric properties of metallic antiperovskites AXD3 (A=Ge, Sn, Pb, Al, Zn, Ga; X=N, C; D=Ca, Fe, Co)

    Science.gov (United States)

    Bilal, Muhammad; Ahmad, Iftikhar; Asadabadi, Saeid Jalali; Ahmad, Rashid; Maqbool, Muhammad

    2015-05-01

    In this paper we communicate the thermoelectric properties of carbon and nitrogen based metallic antiperovskites ANCa3 (A=Ge, Sn, Pb), BCFe3 (B=Al, Zn, Ga) and SnCD3 (D=Co and Fe) using the ab-initio calculations to explore efficient metallic thermoelectric materials. The consistency of the calculated results of SnCCo3 and SnCFe3 with the experimental results confirms the reliability of our theoretical calculations for the other investigated metallic antiperovskites. The results indicate that the thermopower of these materials can be enhanced by changing the chemical potential. The dimensionless figure of merit for the three nitrides approaches 0.96 at room temperature, which proves the usefulness of these materials in thermoelectric generators. Furthermore, the thermal conductivity is minimum at room temperature for chemical potential values between -0.25 μ(eV) and 0.25 μ(eV), and provides the maximum values of dimensionless figure of merit in this range. The striking feature of these studies is identifying a metallic compound, SnNCa3, with the highest value of Seebeck coefficient at room temperature out of all metals. The results anticipate that these materials could be efficient in thermoelectric generators; however, this needs experimental verification.[Figure not available: see fulltext.

  9. Long-term effects of submergence and wetland vegetation on metals in a 90-year old abandoned Pb-Zn mine tailings pond

    International Nuclear Information System (INIS)

    Jacob, Donna L.; Otte, Marinus L.

    2004-01-01

    A Pb-Zn tailings pond, abandoned for approximately 90 years, has been naturally colonized by Glyceria fluitans and is an excellent example of long-term metal retention in tailings ponds under various water cover and vegetation conditions. Shallow/intermittently flooded areas (dry zone) were unvegetated and low in organic matter (OM) content. Permanently flooded areas were either unvegetated with low OM, contained dead vegetation and high OM, or living plants and high OM. It was expected that either water cover or high OM would result in enhanced reducing conditions and lower metal mobility, but live plants would increase metal mobility due to root radial oxygen loss. The flooded low OM tailings showed higher As and Fe mobility compared with dry low OM tailings. In the permanently flooded areas without live vegetation, the high OM content decreased Zn mobility and caused extremely high concentrations of acid-volatile sulfides (AVS). In areas with high OM, living plants significantly increased Zn mobility and decreased concentrations of AVS, indicating root induced sediment oxidation or decreased sulfate-reduction. This is the first study reporting the ability of wetland plants to affect the metal mobility and AVS in long-term (decades), unmanaged tailings ponds. - Metal and acid-volatile sulfide concentrations were affected differently by flooding vegetation

  10. Effects of heavy metal concentrations (Cd, Zn and Pb) in agricultural soils near different emission sources on quality, accumulation and food safety in soybean [Glycine max (L.) Merrill].

    Science.gov (United States)

    Salazar, María Julieta; Rodriguez, Judith Hebelen; Leonardo Nieto, Gastón; Pignata, María Luisa

    2012-09-30

    Argentina is one of the major producers of soybean in the world, this generates a high global demand for this crop leading to find it everywhere, even close to human activities involving pollutant emissions. This study evaluated heavy metal content, the transfer of metals and its relation to crop quality, and the toxicological risk of seed consumption, through soil and soybean sampling. The results show that concentrations of Pb and Cd in soils and soybeans at several sites were above the maximum permissible levels. The heavy metal bioaccumulation depending on the rhizosphere soil compartment showed significant and high regression coefficients. In addition, the similar behavior of Cd and Zn accumulation by plants reinforces the theory of other studies indicating that these metals are incorporated into the plant for a common system of transport. On the other hand, the seed quality parameters did not show a clear pattern of response to metal bioacumulation. Taken together, our results show that soybeans grown nearby to anthropic emission sources might represent a toxicological hazard for human consumption in a potential Chinese consumer. Hence, further studies should be carried out taking into account the potential negative health effects from the consumption of soybeans (direct or indirect through consumption of meat from cattle) in these conditions. Copyright © 2012 Elsevier B.V. All rights reserved.

  11. Measurements of Cd, Cu, Pb and Zn in the lower reaches of major Eurasian arctic rivers using trace metal clean techniques

    Energy Technology Data Exchange (ETDEWEB)

    Guay, Christopher K.H., E-mail: cguay@pmstllc.co [Pacific Marine Sciences and Technology, 3503 Lakeshore Avenue, Suite 5, Oakland, CA 94610 (United States); Zhulidov, Alexander V. [South Russian Regional Centre for Preparation and Implementation of International Projects (CPPI-S), 200/1 Stachki Av., No. 301, Rostov-on-Don 344090 (Russian Federation); Robarts, Richard D. [UNEP GEMS/Water Programme, c/o National Water Research Institute, National Hydrology Research Centre, 11 Innovation Blvd., Saskatoon, Saskatchewan S7N 3H5 (Canada); Zhulidov, Daniel A.; Gurtovaya, Tatiana Yu. [South Russian Regional Centre for Preparation and Implementation of International Projects (CPPI-S), 200/1 Stachki Av., No. 301, Rostov-on-Don 344090 (Russian Federation); Holmes, Robert M. [The Ecosystems Center, Marine Biological Laboratory, 7 MBL Street, Woods Hole, MA 02543 (United States); Headley, John V. [Aquatic Ecosystem Protection Research Branch, National Water Research Institute, National Hydrology Research Centre, 11 Innovation Blvd., Saskatoon, Saskatchewan S7N 3H5 (Canada)

    2010-02-15

    Concentrations of dissolved and particulate Cd, Cu, Pb and Zn were determined in samples collected in summer 1998 from the lower reaches of six major Eurasian arctic rivers: the Onega, Severnaya Dvina, Mezen, Pechora, Ob and Yenisey. These data comprise some of the earliest measurements of trace metals in Eurasian arctic rivers above the estuaries using recognized clean techniques. Significant (alpha = 0.05) differences were observed among mean concentrations of particulate metals in the individual rivers (F <= 0.006), with highest levels overall observed in the Severnaya Dvina and Yenisey. No significant differences were observed among mean concentrations of dissolved metals in the individual rivers (F = 0.10-0.84). Contributions from anthropogenic sources are suggested by comparison of trace metal ratios in the samples to crustal abundances. These results establish a baseline for assessing future responses of Eurasian arctic river systems to climate-related environmental changes and shifting patterns of pollutant discharge. - We report some of the earliest reliable trace metal data for major Eurasian arctic rivers.

  12. Synthesis of Bi-Pb-Sr-Ca-Cu oxide/Ag superconductors by melt dipping and oxidation of metallic precursor alloys

    International Nuclear Information System (INIS)

    Gao, W.; Li, S.; Rudman, D.A.; Yurek, G.J.; Vander Sande, J.B.

    1989-01-01

    Bi-Pb-Sr-Ca-Cu-Ag alloy coatings were made by vacuum induction melting followed by melt dipping on substrates of MgO, SrTiO 3 , and Al 2 O 3 . The metallic precursor layers were then subjected to a controlled atmosphere oxidation and annealing to produce oxide superconductors. Superconducting coatings with onset temperatures of 112 K and zero resistance temperatures of 80 K were obtained in this way. The addition of Ag aided in the alloy melting and dipping processes, and produced a superconducting oxide/noble metal composite after oxidation. The resulting superconducting phases were analyzed by x-ray powder diffraction. The influence of the substrate, dipping processes, oxidation, and annealing conditions on the superconducting properties are discussed

  13. Identification of heavy metals sources in the Mexico city atmosphere, using the proton induced x-ray analytical technique and multifactorial statistics techniques; Identificacion de fuentes de metales pesados en la atmosfera de la Ciudad de Mexico, usando la tecnica de analisis por induccion de rayos X con proton y tecnicas estadisticas multifactoriales

    Energy Technology Data Exchange (ETDEWEB)

    Hernandez M, B. [ININ, 52750 La Marquesa, Estado de Mexico (Mexico)

    1997-07-01

    The objectives of this work are: to identify the heavy metals present in the air, and its concentrations. To know the behavior from the polluting chemical elements to the long of an annual cycle corresponding to 1990, based on the concentrations of the same ones, obtained through the PIXE technique. To identify the suitable statistical methods to use to the data of metals concentration in form of total suspended particle (PST), found in this investigation. To relate the concentrations and the meteorological parameters considered to be able to suggest the possible pollution sources. In function of the obtained results, to serve as base to the decisions making and measures control that are planned by diverse institutions focused to the problem of the atmospheric pollution in the Metropolitan area of Mexico City (ZMCM). (Author)

  14. Evaluation of the pollution and the transport of heavy metals in the Lerma river, through nuclear analytical techniques (Second stage); Evaluacion de la contaminacion y el transporte de metales pesados en el rio Lerma, a traves de tecnicas analiticas nucleares (Segunda etapa)

    Energy Technology Data Exchange (ETDEWEB)

    Aldape U, F. [ININ, 52045 Ocoyoacac, Estado de Mexico (Mexico)

    2004-12-15

    In this stage of the investigation work, the water quality indexes, the heavy metals concentration in the dissolved phase and in the sediments of the four samplings were determined, it was determined too the texture of the one sediment and the analyses of the suspended matter of the water and the relative abundance relative of particles by scanning electron microscopy and the determination of the crystalline structures of the sediment by means of X-ray diffraction. (Author)

  15. SÍNTESIS Y CARACTERIZACIÓN DE FERRITAS DE Cd, Pb y Mn VÍA HIDROQUÍMICA.

    Directory of Open Access Journals (Sweden)

    ELIAZAR AQUINO

    2011-01-01

    Full Text Available El objetivo fue obtener por vía hidroquímica y bajo condiciones optimizadas, ferritas de Cd, Pb y Mn y comparar sus características químicas, fìsicoquímicas y estequiométricas. Se prepararon disoluciones separadas de estos metales a 1 g/L, se le adicionó FeSO4.7H2O para una relación molar 15:1 [Fe2+]/[Me2+], se mantuvo a pH de 10 y 60ºC en baño termostatizado. Se corroboró que el proceso de formación de ferritas in situ bajo condiciones óptimas, permite eliminar metales pesados como los evaluados de los medios acuosos, con efi ciencias superiores al 98%. De igual manera se lograron obtener estequiometrías defi nidas que permiten proponer los mecanismos de reacción que tienen lugar, toda vez que pueden ser justifi cados a partir de las estequiometrías logradas y por las diferentes técnicas empleadas en su caracterización. Se han podido dilucidar los mecanismos de sustitución de los iones Fe2+ por los metales divalentes como los estudiados en las estructuras de espinela inversa de estas ferritas y su correlación con las propiedades magnéticas de las mismas.

  16. Study of the leaching of heavy metals from waste water sludge and incinerator's ash, using coupled thermostated columns and DTPA as complex agent; Estudio de la extraccion de metales pesados de lodos y cenizas de aguas residuales usando columnas termostatizadas acopladas y DTPA como agente complejante

    Energy Technology Data Exchange (ETDEWEB)

    Vite T, J.; Vite T, M.; Guerrero D, J.; Carreno de Leon, M.C. [Departamento de Estudios del Ambiente, Instituto Nacional de Investigaciones Nucleares, A.P. 18-1027, 11801 Mexico D.F. (Mexico)

    2000-07-01

    We studied the metallic composition from waste water sludge and incinerators ashes of an incinerator located in Toluca, Mexico, the qualitative studies were made using the Activation Analysis technique, and fluorescence X-ray techniques. The quantitative analysis of heavy metals in the wastes were made using Inductively coupled plasma atomic emission spectrometry (Icp-Aes). For leaching the samples, we used four coupled thermostated columns, each one had a p H of 2,5, 7 and 10. The flux of the air was of 1600 cc/min. The temperature was maintain constant in 60 Centigrade using a thermostated system. For this study we used 100 g of wastes mixed with mineral acid or sodium hydroxide to reach p H 2,5,7 and 10. We added a reducing and tensoactive agents and finally DTPA as complex agent. With this method, we obtain a better leaching efficiency using a complex agent. However the high DTPA cost, make this process expansive that is why we recommend to work with another classes of complex agents, that be cheaper to leach metals of different chemistry matrix. (Author)

  17. Uptake, transportation, and accumulation of C60fullerene and heavy metal ions (Cd, Cu, and Pb) in rice plants grown in an agricultural soil.

    Science.gov (United States)

    Liang, Chuanzhou; Xiao, Haijun; Hu, Ziqi; Zhang, Xu; Hu, Jun

    2018-04-01

    The mutual influences of C 60 fullerene (C 60 ) and heavy metal ions (Cd, Cu, and Pb) on the uptake, transportation, and accumulation of these coexisting pollutants in four rice cultivars planted in agricultural soil were investigated during the whole life cycle of rice. The biomass of the rice plants was not affected significantly by the presence of C 60 . C 60 exposure exerted different impacts on the bioaccumulation of Cd, Cu, and Pb in various rice tissues. For example, the bioaccumulation of Cd in rice 9311 panicles was significantly decreased (p concentrations in the roots, stems, and panicles of the four rice cultivars that were harvested after a 130-day exposure to 600 mg/kg C 60 were 40-292, 4.4-24.5 and 0.077-1.2 mg/kg (dry weight), respectively. C 60 and heavy metal ions exhibited different uptake and transportation mechanisms, which depended on the rice cultivar, soil heavy metal ion concentration, and C 60 exposure time and concentration. For example, the average C 60 in the four rice cultivars was increased sharply, from 47.4 to 196.3 mg/kg from the tillering to booting stages, whereas Cd levels increased only slightly, from 23.1 to 25.9 mg/kg. The study demonstrated that the bioaccumulation of C 60 and heavy metal ions under co-contamination scenario differs from under single contaminant. The accumulation of C 60 in rice panicles may increase the concern of food safety. Copyright © 2017 Elsevier Ltd. All rights reserved.

  18. pH-specific hydrothermal assembly of binary and ternary Pb(II)-(O,N-carboxylic acid) metal organic framework compounds: correlation of aqueous solution speciation with variable dimensionality solid-state lattice architecture and spectroscopic signatures.

    Science.gov (United States)

    Gabriel, C; Perikli, M; Raptopoulou, C P; Terzis, A; Psycharis, V; Mateescu, C; Jakusch, T; Kiss, T; Bertmer, M; Salifoglou, A

    2012-09-03

    Hydrothermal pH-specific reactivity in the binary/ternary systems of Pb(II) with the carboxylic acids N-hydroxyethyl-iminodiacetic acid (Heida), 1,3-diamino-2-hydroxypropane-N,N,N',N'-tetraacetic acid (Dpot), and 1,10-phenanthroline (Phen) afforded the new well-defined crystalline compounds [Pb(Heida)](n)·nH(2)O(1), [Pb(Phen)(Heida)]·4H(2)O(2), and [Pb(3)(NO(3))(Dpot)](n)(3). All compounds were characterized by elemental analysis, FT-IR, solution or/and solid-state NMR, and single-crystal X-ray diffraction. The structures in 1-2 reveal the presence of a Pb(II) center coordinated to one Heida ligand, with 1 exhibiting a two-dimensional (2D) lattice extending to a three-dimensional (3D) one through H-bonding interactions. The concurrent aqueous speciation study of the binary Pb(II)-Heida system projects species complementing the synthetic efforts, thereby lending credence to a global structural speciation strategy in investigating binary/ternary Pb(II)-Heida/Phen systems. The involvement of Phen in 2 projects the significance of nature and reactivity potential of N-aromatic chelators, disrupting the binary lattice in 1 and influencing the nature of the ultimately arising ternary 3D lattice. 3 is a ternary coordination polymer, where Pb(II)-Dpot coordination leads to a 2D metal-organic-framework material with unique architecture. The collective physicochemical properties of 1-3 formulate the salient features of variable dimensionality metal-organic-framework lattices in binary/ternary Pb(II)-(hydroxy-carboxylate) structures, based on which new Pb(II) materials with distinct architecture and spectroscopic signature can be rationally designed and pursued synthetically.

  19. Peculiarity of non-equilibrium superconductivity in half-metallic ferromagnet/insulator/superconductor Co{sub 2}CrAl/I/Pb heterostructures

    Energy Technology Data Exchange (ETDEWEB)

    Rudenko, E.M., E-mail: rudenko@imp.kiev.u [Institute of Metal Physics, National Academy of Sciences of Ukraine, 03680 Kiev-142 (Ukraine); Korotash, I.V.; Kudryavtsev, Y.V.; Krakovny, A.A.; Dyakin, M.V. [Institute of Metal Physics, National Academy of Sciences of Ukraine, 03680 Kiev-142 (Ukraine)

    2010-04-01

    The peculiarities of electron transport trough the tunnel half-metallic ferromagnet(Co{sub 2}CrAl)/insulator/superconductor(Pb) (HMF/I/S) junctions have been investigated. It was experimentally shown that the effective life-time of the spin-polarized quasi-particles ensemble in superconductor before their recombination into singlet cooper pairs is much longer than that for non-polarized ones. It was also found that the tunnel injection of spin-polarized current from HMF into S in HMF/I/S junction in its superconductive state the effect of 'giant blocking' of the tunnel current is appeared. In this case at bias voltage, V{sub t}, close to zero a very significant increase in differential resistance of the HMF/I/S junction in comparison with that of the N/I/S one is observed (where N is normal metal). Additionally, it was also established that at V{sub t}->0 the ratio of differential resistance in superconductive state to that of in the normal state for the Co{sub 2}CrAl/I/Pb junction is much bigger than corresponding ratio for N/I/S junctions obtained experimentally as well as in the frame of Bardeen, Cooper and Schrieffer theory.

  20. Accumulation of Trace Metal Elements (Cu, Zn, Cd, and Pb in Surface Sediment via Decomposed Seagrass Leaves: A Mesocosm Experiment Using Zostera marina L.

    Directory of Open Access Journals (Sweden)

    Shinya Hosokawa

    Full Text Available Accumulation of Cu, Zn, Cd, and Pb in the sediment of seagrass ecosystems was examined using mesocosm experiments containing Zostera marina (eelgrass and reference pools. Lead was approximately 20-fold higher in the surface sediment in the eelgrass pool than in eelgrass leaves and epiphytes on the eelgrass leaves, whereas zinc and cadmium were significantly lower in the surface sediment than in the leaves, with intermediate concentrations in epiphytes. Copper concentrations were similar in both the surface sediment and leaves but significantly lower in epiphytes. Carbon and nitrogen contents increased significantly with increasing δ13C in surface sediments of both the eelgrass and reference pools. Copper, Zn, Cd, and Pb also increased significantly with increasing δ13C in the surface sediment in the eelgrass pool but not in the reference pool. By decomposition of eelgrass leaves with epiphytes, which was examined in the eelgrass pool, copper and lead concentrations increased more than 2-fold and approximately a 10-fold, whereas zinc and cadmium concentrations decreased. The high copper and lead concentrations in the surface sediment result from accumulation in decomposed, shed leaves, whereas zinc and cadmium remobilized from decomposed shed leaves but may remain at higher concentrations in the leaves than in the original sediments. The results of our mesocosm study demonstrate that whether the accumulation or remobilization of trace metals during the decomposition of seagrass leaves is trace metal dependent, and that the decomposed seagrass leaves can cause copper and lead accumulation in sediments in seagrass ecosystems.

  1. Comprehensive risk assessment and source identification of selected heavy metals (Cu, Cd, Pb, Zn, Hg, As) in tidal saltmarsh sediments of Shuangtai Estuary, China.

    Science.gov (United States)

    Liu, Chang-Fa; Li, Bing; Wang, Yi-Ting; Liu, Yuan; Cai, Heng-Jiang; Wei, Hai-Feng; Wu, Jia-Wen; Li, Jin

    2017-10-06

    Heavy metals do not degrade and can remain in the environment for a long time. In this study, we analyzed the effects of Cu, Cd, Pb, Zn, Hg, and As, on environmental quality, pollutant enrichment, ecological hazard, and source identification of elements in sediments using data collected from samples taken from Shuangtai tidal wetland. The comprehensive pollution indices were used to assess environmental quality; fuzzy similarity analysis and geoaccumulation index were used to analyze pollution accumulation; correlation matrix, principal component analysis, and clustering analysis were used to analyze pollution source; environmental risk index and ecological risk index were used to assess ecological risk. The results showed that the environmental quality was either clean or almost clean. Pollutant enrichment analysis showed that the four sub-regions had similar pollution-causing metals to the background values of the soil element of the Liao River Plain, which were ranked according to their similarity. Source identification showed that all the elements were correlated. Ecological hazard analysis showed that the environmental risk index in the study area was less than zero, posing a low ecological risk. Ecological risk of the six elements was as follows: As > Cd > Hg > Cu > Pb > Zn.

  2. Phytoremediation efficiency of pondweed (Potamogeton crispus in removing heavy metals (Cu, Cr, Pb, As and Cd from water of Anzali wetland

    Directory of Open Access Journals (Sweden)

    Hajar Norouznia

    2014-09-01

    Full Text Available Plant-based remediation (i.e. phytoremediation is one of the most significant eco-sustainable techniques to cope with devastating consequences of pollutants. In the present study, the potential of a wetland macrophyt (i.e. Potamogeton crispus for the phytoremediation of heavy metals (i.e. Cu, Cr, Pb, As and Cd in the Anzali wetland was evaluated. The results showed that P. crispus tends to accumulate notable amounts of Cu, Cr, Pb, As and Cd according to their assayed concentrations as follows: 8.2 µg g-1 dw, 0.97 µg g-1 dw, 6.04 µg g-1 dw, 2.52 µg g-1 dw and 0.34 µg g-1 dw, respectively. Further accurate perception of the phytoremediation efficiency were conducted using both bioconcentration factor and translocation factor. The average of the highest bioconcentration factors was presented in a descending order as: 2.9×103, 1.9×103, 1.17×103, 0.68×103 and 0.46×103 for the Cu, Cr, Pb, Cd and As, respectively. Based on the results, P. crispus presents high potential to absorb all the alluded metals except for As and partly Cd. Correspondingly, the mean values of translocation factor were reported in the range of 0.41 to 2.24. Eventually, relying on the observed findings, the results support the idea that P. crispus species would be employed as the prospective candidate for the phytoremediation processes in Anzali wetland.

  3. Physiological effects of five different marine natural organic matters (NOMs and three different metals (Cu, Pb, Zn on early life stages of the blue mussel (Mytilus galloprovincialis

    Directory of Open Access Journals (Sweden)

    Lygia Sega Nogueira

    2017-04-01

    Full Text Available Metals are present in aquatic environments as a result of natural and anthropogenic inputs, and may induce toxicity to organisms. One of the main factors that influence this toxicity in fresh water is natural organic matter (NOM but all NOMs are not the same in this regard. In sea water, possible protection by marine NOMs is not well understood. Thus, our study isolated marine NOMs by solid-phase extraction from five different sites and characterized them by excitation-emission fluorescence analysis—one inshore (terrigenous origin, two offshore (autochthonous origin, and two intermediate in composition (indicative of a mixed origin. The physiological effects of these five NOMS alone (at 8 mg/L, of three metals alone (copper, lead and zinc at 6 µg Cu/L, 20 µg Pb/L, and 25 µg Zn/L respectively, and of each metal in combination with each NOM, were evaluated in 48-h exposures of mussel larvae. Endpoints were whole body Ca2++Mg2+-ATPase activity, carbonic anhydrase activity and lipid peroxidation. By themselves, NOMs increased lipid peroxidation, Ca2++Mg2+-ATPase, and/or carbonic anhydrase activities (significant in seven of 15 NOM-endpoint combinations, whereas metals by themselves did not affect the first two endpoints, but Cu and Pb increased carbonic anhydrase activities. In combination, the effects of NOMs predominated, with the metal exerting no additional effect in 33 out of 45 combinations. While NOM effects varied amongst different isolates, there was no clear pattern with respect to optical or chemical properties. When NOMs were treated as a single source by data averaging, NOM had no effect on Ca2++Mg2+-ATPase activity but markedly stimulated carbonic anhydrase activity and lipid peroxidation, and there were no additional effects of any metal. Our results indicate that marine NOMs may have direct effects on this model marine organism, as well as protective effects against metal toxicity, and the quality of marine NOMs may be an

  4. AKUMULASI LOGAM BERAT Cr DAN Pb PADA TUMBUHAN MANGROVE AVICENNIA MARINA DI MUARA SUNGAI BABON PERBATASAN KOTA SEMARANG DAN KABUPATEN DEMAK JAWA TENGAH (Accumulation of Heavy Metals Cr and Pb in Mangrove Plant Avicennia marina On Babon River’s Estuari

    Directory of Open Access Journals (Sweden)

    Vita Kartikasari

    2002-11-01

    heavy metal elements, which exist in the water ecosystem surrounds this plant life. This study is conducted in Babon River’s Estuari Semarang, Central Java and aimed to meet some goals as follows. First, to observe the mangrove plants capability, Avicennia marina, to accumulate heavy metal elements, e.g.: Cr and Pb. Second, to understand deeper observation of mangrove plant’s organs: the roots, branches, and leaves, according to accumulate heavy metal elements. Third, to observe the role of mangrove plant due to reduce heavy metal elements (Cr and Pb, which may pollute in Babon rivers Estuaries. The Mangrove research and observation is divided into two major stages: Preliminary Observation and Main Observation. The preliminary observation is aimed to identify the variuous types of Mangrove plant and determine the heavy metal element contained in Mangrove plant organ. Based on preliminary observation result then decided the designated location sample point (contain heavy metal elements which represent the Mangrova A. marina plant existence and the absence. The main observation is conducted in order to determine primary data of Cr and Pb concentration by taking sample plant organ’s (roots, branches, and leaves, sediment, and water. The sample is then dried by Microwave Digestion MLS-1200 MEGA. The main data observation is analysed statistically by using Non parametric Kruskal Wallis test and Two sample Kolmogorov-Smirnov Test. The accumulating capability of Mangrove plant describe that Cr element is more accumulate by Mangrove plant comparing to Pb element. The rate of Bio-concentration factor for Cr and Pb are 1052.66 and 349.54. The highest concentration level of Cr and Pb in Mangrove plant’s organ as in order : The roots, branches, and leaves. The leaves contain bigger Pb element in sediment, settled in the bottom of water, that present with Mangrove are quite bigger than location which Mangrove absences. On the other side, observation also describe that there

  5. The Effect of Exposure to Cd and Pb in the Form of a Drinking Water or Feed on the Accumulation and Distribution of These Metals in the Organs of Growing Wistar Rats.

    Science.gov (United States)

    Winiarska-Mieczan, Anna; Kwiecień, Małgorzata

    2016-02-01

    The degree of accumulation and distribution of Cd and Pb in the organs of young animals compared to the amount taken in with water or feed have not been thoroughly investigated yet. The experiment aimed to verify whether the source of toxic metals (feed, drinking water) administered to growing rats orally has an influence on the degree of accumulation of Cd and Pb in the organs (brain, spleen, lungs, heart, liver and kidneys). The rats received Cd and/or Pb respectively in the amount of 7 mg and/or 50 mg per 1 kg of feed or per 1 L of distilled water. The rats' organs accumulated in total about 0.5 % Cd and about 0.71 % Pb consumed with water and about 0.46 % Cd and about 0.63 % Pb taken in with feed. More than 60 % of Cd and more than 70 % of Pb absorbed by the studied organs was accumulated in the liver, and more than 30 % of Cd and 26-29 % of Pb in the kidneys and less than 1 % in other organs. The relationship between the distribution percentage of Cd in the studied organs can be presented as: liver > kidneys > brain > lungs > heart > spleen. The relationship between the distribution percentage of Pb can be presented as: liver > kidneys > brain > spleen > heart > lungs. Significantly (P water.

  6. Availability of metals Cd and Pb and metalloid As in the Ribeira do Iguape River hydrographic basin and its tributaries: an environmental contamination assessment'

    International Nuclear Information System (INIS)

    Castro, Francisco Jose Viana de

    2012-01-01

    During several decades the Alto Vale of Ribeira region (SP-PR) was under influence of lead mining activities, refined and processed in the mines of the region. Since 1996, all such activities ceased, however, leaving behind a huge amount of environmental liabilities. This study aimed to investigate the presence and concentration levels of metals cadmium (Cd) and lead (Pb) and metalloid arsenic (As) in the water, sediment and biota (fish blood) in the aquatic systems of Ribeira do Iguape River and its tributaries, for an environmental assessment and monitoring of the region. The sampling collection occurred in 8 sites and fish samples were caught by fishing nets and blood sampling was done in the site. The determination of these elements was carried out by atomic absorption spectrometry with graphite furnace electro thermal heating (GF AAS). This study also assessed the occurrence of some major (Ca, Fe, K and Na), trace (As, Ba, Br, Co, Cs, Hf, Rb, Sb, Sc, Se, Ta, Th, U, Zn) and rare earth elements (La, Ce, Eu, Nd, Sm, Lu, Tb and Yb) by Neutron Activation Analysis (NAA). Validation of both methodologies, regarding precision and accuracy, was done by reference material analyses. The results obtained for As, Cd and Pb in the sediment were compared to the Canadian Council of Ministers of the Environment (CCME), TEL (Threshold Effect Level) e PEL (Probable Effect Level) adopted by CETESB and CONAMA 454/2012 Resolution. The results for As, Cd and Pb in water samples were below the QL of the analytical technique used, indicating that these elements are in concentration levels that do not affect the water quality standard established by CONAMA 357/2005. On the other hand, the concentration values for these elements in fish blood and sediment samples showed a strong contamination tendency for Cd and Pb most of the sampling points assessed. The highest Cd concentration in fish blood was 24.3 μg L -1 , at site 2. For Pb, the highest concentration value was 118 νg L -1 , at

  7. Impacts of coagulation-flocculation treatment on the size distribution and bioavailability of trace metals (Cu, Pb, Ni, Zn) in municipal wastewater.

    Science.gov (United States)

    Hargreaves, Andrew J; Vale, Peter; Whelan, Jonathan; Alibardi, Luca; Constantino, Carlos; Dotro, Gabriela; Cartmell, Elise; Campo, Pablo

    2018-01-01

    This study investigated the impact of coagulation-flocculation treatment on metal form and bioavailability in municipal wastewater. Real humus effluent samples were separated into particulate, colloidal and truly dissolved fractions before and after treatment with either ferric chloride (FeCl 3 ) or the biopolymer Floculan. Results revealed that both reagents effectively (≥48%) eliminated Cu, Pb and Zn from the particulate fraction and removed Cu and Zn from the colloidal fraction in conjunction with colloidal organic carbon (COC). Although organics in the truly dissolved fraction were resistant to removal, Floculan reduced Cu in this fraction by 72% owing to the complexation of free Cu ions to phenol and amino groups along the polymeric chains, revealing an additional removal pathway. In fact, COC removed in the CF process by Floculan was replaced with truly dissolved compounds, input as a result of this reagents organic composition. Floculan, therefore, reduced the soluble concentration of Cu and Zn without changing the DOC concentration, thus reducing the bioavailability of these metals in treated effluent. FeCl 3 did not reduce the bioavailability of target metals, thus did not deliver any environmental benefit. This work provides important information for the selection and development of high performance coagulants to improve metal removal. Copyright © 2017 Elsevier Ltd. All rights reserved.

  8. Solid-liquid-solid extraction of heavy metals (Cr, Cu, Cd, Ni and Pb) in aqueous systems of zeolite-sewage sludge

    International Nuclear Information System (INIS)

    Sprynskyy, Myroslav

    2009-01-01

    This paper presents results of kinetic and equilibrium studies of the removal of heavy metals (Cr, Cu, Cd, Ni and Pb) from the sewage sludge using a new technique of solid-liquid-solid extraction with the adsorption-diffusion column filled by the zeolite. The metal extraction onto the zeolite from aqueous solution of the clinoptilolite and the sludge composition is characterized by three stages: intensive extraction, inversion and stabilization with the moderate extraction increase. Addition of 25% of the zeolite provides extraction efficiency of cadmium and lead of about 84%, chromium, copper and nickel of 66%, 61% and 50%, respectively. The estimated values of Gibbs free energy change ΔG show that the metals extraction by the clinoptilolite may be considered as a physical adsorption. The negative values of ΔG testify to an exothermic nature of the process. The difference between energetic potentials of the components is a driving force of the metal redistribution in the system 'clinoptilolite-water-sludge'

  9. Pb II

    African Journals Online (AJOL)

    Windows User

    ., 2009) biomaterials. However, the ..... reported for various microorganisms by various researchers (Gong et al., 2005). At biomass ... the increase in initial Pb (II) was also observed for removal of Pb (II) by loofa sponge immobilized Aspergillus.

  10. Validation of Transfer Functions Predicting Cd and Pb Free Metal Ion Activity in Soil Solution as a Function of Soil Characteristics and Reactive Metal Content

    NARCIS (Netherlands)

    Pampura, T.; Groenenberg, J.E.; Lofts, S.; Priputina, I.

    2007-01-01

    According to recent insight, the toxicity of metals in soils is better related to the free metal ion (FMI) activity in the soil solution than to the total metal concentration in soil. However, the determination of FMI activities in soil solution is a difficult and time-consuming task. An alternative

  11. Oleoducto de Crudos Pesados (OCP) Ecuador: the challenges

    Energy Technology Data Exchange (ETDEWEB)

    Zboya, Tim M.; Mandizabal, Andres E.; Day, Craig; Cadena, Jaime A. [Oleoducto de Crudos Pesados (OCP) (Ecuador); Curle, Ron [Techint S.A., Quito (Ecuador)

    2003-07-01

    The OCP (Oleoducto de Crudos Pesados) Project consists of the design, construction and operation of a 500 km heavy crude oil pipeline, from the Ecuadorian Orient Region where the heavy crude oil fields are located, traversing the Andes Mountains, and finishing at the Pacific Coast. The magnitude of the facilities as well as the environment where the project was developed imposed enormous challenges. This work presents the general context in which the OCP Project was developed and its significance within the environment and the region. It shows the general configuration of the system and the most important facilities and equipment installed, as well as the key design issues and the proposed approach for them. The project plan and present status are analyzed as well as causes for main deviations from the conceptual design. A number of different communities, as well as a unique environment including ecological reserves, raised the need to manage all of these aspects with critical and high-priority attention. The approach to these issues from the perspective of OCP and Techint Team members is discussed. (author)

  12. Stripping voltammetry glassy carbon on the study of Cd and Pb heavy metals pollution using anadara antiquata linn bioindicator

    International Nuclear Information System (INIS)

    Iswani, G.S.; Hidayat, F.; Zulkarnaen, A.

    1996-01-01

    The presence of cadmium and lead in sea water and shell fish (anadara antiquata linn) bioindicator in Gresik waters by glassy carbon stripping voltammetry was studied at menu 2 parameters as follows: time and potential plating-1000V and 90 second, sweep rate: 375 mV/second, strip time 2 second, electrolyte: aquatrides, pH = 0.4 (for shell fish) and -1000 V and 120 second, 999 mV/se con, 2 second, chloracetic, pH = 5.0. It was found that the mean of Cd and Pb contents in sea water at pH = 7.0, salinity = 28-29 ppm, oxygen content = 7.1-8.1 and temperature = 27-30 o C which was monitoring at location 1.2 and location 3.4 were 0.01 and 0.17 ppm, 1.44 and 1.35 ppm respectively. Furthermore the mean of Cd and Pb contents in shell fish at location 1.2 and 3.4 (snail range and shell fish dry weight were reported) were 5.94 and 3.05 ppm, 0,03 and 0,03 ppm. The t-tes for Cd and Pb contents in sea waters and shell fish at location 1,2 compared with location 3.4 were significant and no significant. The accuracy of the method was tested with SRM coppepoda MA-A-1-A-a and W-4. (author)

  13. The world-class Howard's Pass SEDEX Zn-Pb district, Selwyn Basin, Yukon. Part II: the roles of thermochemical and bacterial sulfate reduction in metal fixation

    Science.gov (United States)

    Gadd, Michael G.; Layton-Matthews, Daniel; Peter, Jan M.; Paradis, Suzanne; Jonasson, Ian R.

    2017-03-01

    against this model. Indeed, the new data indicate that much of the base metal sulfide mineralization was emplaced below the sediment-water interface within sulfidic muds under reducing conditions during early diagenesis. Furthermore, thermochemical sulfate reduction provided most of the reduced sulfur within the Zn-Pb deposits.

  14. TOXIC METALS IN THE ENVIRONMENT: THERMODYNAMIC CONSIDERATIONS FOR POSSIBLE IMMOBILIZATION STRATEGIES FOR PB, CD, AS, AND HG

    Science.gov (United States)

    The contamination of soils by toxic metals is a widespread, serious problem that demands immediate action either by removal or immobilization, which is defined as a process which puts the metal into a chemical form, probably as a mineral, which will be inert and highly insoluble ...

  15. Fate of airborne metal pollution in soils as related to agricultural management. 1. Zn and Pb distributions in soil profiles

    NARCIS (Netherlands)

    Fernandez, C.; Labanowski, J.; Cambier, P.; Jongmans, A.G.; Oort, van F.

    2007-01-01

    The fate of airborne metal pollutants in soils is still relatively unknown. We studied the incorporation of such airborne metal pollution in two soils under long-term permanent pasture (PP) and conventional arable land (CA). Both soils were located at an almost equal distance from a former zinc

  16. Estudio de la fertilidad y de los metales pesados en suelos de agroecosistemas tropicales de una zona transfronteriza de la República Dominicana-Haití Fertility and heavy metal contents of soils in the tropical agroecosys­tems of the Dominican Republic-Haiti frontier zone

    Directory of Open Access Journals (Sweden)

    J. Pastor

    2010-01-01

    Full Text Available Se exponen los datos referidos a la cuanti­ficación de la fertilidad, MO. y metales pe­sados en la capa superficial de los suelos de 30 agroecosistemas tropicales en tres tipos de bosques (nublado, latifoliado y seco, co­rrespondientes a un territorio de marcada pobreza (suroeste de la República Domini­cana-Haití. El desarrollo de una agricultura sostenible en la zona requiere evaluar la fer­tilidad de los suelos; problema fundamental debido al cambio que sufren sus caracterís­ticas físicas y químicas cuando se talan y queman los bosques y luego se cultivan. La información respecto a los suelos del territo­rio es prácticamente nula, por lo que este trabajo constituye una aportación, especial­mente para la cuenca hidrográfica transfron­teriza del río Pedernales. Los agroecosistemas estudiados se en­cuentran mayoritariamente comprendidos entre los 1200 m de altitud y el nivel del mar y constituyen las fuentes esenciales pa­ra la alimentación humana y animal: pastos y cultivos de habichuela, maíz, sorgo, café, plátano-guineo, frutales y tubérculos.This paper reports fertility, organic matter and heavy metal data obtained in topsoil samples from 30 tropical agroecosystems in three types of forest (rain, latifoliated and dry in an area of extreme poverty (SE Do­minican Republic-Haiti. For sustainable ag­ricultural practice in this zone, soil fertility needs to be first assessed since this factor has been severely compromised by changes in the physical and chemical properties of the soil induced by the felling and burning of trees to make way for crops. Information on the soils of the region is practically null. This study focuses mainly on the transfrontier basin of the Pedernales River. The agroecosystems examined occur from an altitude of 1200 m to sea level and are the main food sources for human and animal consumption: bean, corn, sorghum, coffee, Guinea banana, fruit trees and tu­bers.

  17. Trace element composition and U-Pb age of zircons from Estherville: Constraints on the timing of the metal-silicate mixing event on the mesosiderite parent body

    Science.gov (United States)

    Haba, Makiko K.; Yamaguchi, Akira; Kagi, Hiroyuki; Nagao, Keisuke; Hidaka, Hiroshi

    2017-10-01

    formed during a high-temperature reheating event, which is probably related to the metal-silicate mixing event. The weighted average 207Pb-206Pb age obtained by SIMS from both zircons is 4521 ± 26 Ma (2σ). This age is younger than that of a primary magmatic zircon from Vaca Muerta (4563 ± 15 Ma) and probably corresponds to the timing of the metal-silicate mixing event or a later impact event.

  18. Natural arsenic attenuation via metal arsenate precipitation in soils contaminated with metallurgical wastes: III. Adsorption versus precipitation in clean As(V)/goethite/Pb(II)/carbonate systems

    International Nuclear Information System (INIS)

    Vaca-Escobar, Katherine; Villalobos, Mario; Ceniceros-Gómez, Agueda E.

    2012-01-01

    Soil contamination with As and potentially harmful metals is a widespread problem around the world especially from mining and metallurgical wastes, which release substantial amounts of these elements to the environment in potentially mobile species. Recently, it has been found that in various Mexican soils contaminated with these types of wastes, arsenate is not in the form of sorbed species on Fe oxides present in the soils, as generally reported in the literature, but in the form of very insoluble compounds such as Pb, Cu and Ca arsenates. Here a thermodynamic model is applied and validated with the results from wet chemical experiments to determine the fundamental geochemical conditions governing the mobility of As in the presence of Pb. For this purpose, a relatively simple but fundamental system of goethite (α-FeOOH)/As(V)/Pb(II)/carbonate was defined as a function of the As(V)/Fe(III) ratio, in a pH range of 5–10. The speciation model included the simultaneous inclusion of triple layer surface complexation and arsenate precipitation equilibria. The model predicts that from very low total As(V)/Fe(III) molar ratios (0.012 at pH 7) the precipitation mechanism significantly influences the attenuation of As(V), and rapidly becomes the dominant process over the adsorption mechanism. Model results identify the quantitative conditions of predominance for each mechanism and describe the transition conditions in which relatively large fractions of adsorbed, precipitated and dissolved As(V) species prevail. Experimental measurements at selected As(V)/Fe(III) ratios and pH confirmed the predictions and validated the coupled thermodynamic model utilized.

  19. Metais pesados no solo e mamoneira adubada com biossólido e silicato de cálcio e magnésio

    Directory of Open Access Journals (Sweden)

    Altina L. Nascimento

    2015-05-01

    Full Text Available O biossólido é excelente fonte de nutrientes de plantas; entretanto, pode contaminar o solo. O trabalho teve por objetivo avaliar a influência da adubação com composto de lodo de esgoto e silicato de cálcio e magnésio, nos teores de metais pesados no solo e em plantas de mamona. O experimento foi conduzido no Instituto de Ciências Agrárias da UFMG em Montes Claros, MG, no período de junho a dezembro de 2010. O cultivo foi realizado em área de Cambissolo Háplico utilizando-se a mamona (Ricinus communis L. variedade BRS Energia. O delineamento foi em blocos casualizados em arranjo fatorial 2 x 4, com 3 repetições, sendo 2 doses de silicato de cálcio e magnésio (0 e 1 t ha-1 e 4 doses de composto de lodo de esgoto (0; 23,81; 47,62 e 71,43 t ha-1, em base seca. Não houve interação entre as doses de silicato de cálcio e composto de lodo de esgoto, bem como o silicato de cálcio e magnésio não influenciou os teores de metais pesados no solo e na planta. No solo os teores de Zn e Cu aumentaram com o incremento das doses de composto de lodo de esgoto sendo que Ni, Pb, Cd e Cr não foram influenciados pela aplicação deste resíduo. Na planta com aumento das doses de composto de lodo de esgoto houve aumento apenas nos teores de Cd e Pb.

  20. Three common metal contaminants of urban runoff (Zn, Cu and Pb) accumulate in freshwater biofilm and modify embedded bacterial communities

    International Nuclear Information System (INIS)

    Ancion, Pierre-Yves; Lear, Gavin; Lewis, Gillian D.

    2010-01-01

    We investigated the absorption rates of zinc, copper and lead in freshwater biofilm and assessed whether biofilm bacterial populations are affected by exposure to environmentally relevant concentrations of these metals in flow chamber microcosms. Metals were rapidly accumulated by the biofilm and then retained for at least 14 days after transfer to uncontaminated water. Changes in bacterial populations were assessed by Automated Ribosomal Intergenic Spacer Analysis (ARISA) and 16S rRNA gene clone libraries. Significant differences in bacterial community structure occurred within only three days of exposure to metals and remained detectable at least 14 days after transfer to uncontaminated water. The rapid uptake of stormwater-associated metals and their retention in the biofilm highlight the potential role of biofilms in the transfer of metals to organisms at higher trophic levels. The sensitivity of stream biofilm bacterial populations to metal exposure supports their use as an indicator of stream ecological health. - The rapid accumulation of metals in biofilms and their impact on bacterial communities provide new insights into how these contaminants affect freshwater ecosystems.

  1. Long-term environmental exposure to metals (Cu, Cd, Pb, Zn) activates the immune cell stress response in the common European sea star (Asterias rubens).

    Science.gov (United States)

    Matranga, V; Pinsino, A; Randazzo, D; Giallongo, A; Dubois, P

    2012-05-01

    The common sea star Asterias rubens represents a key-species of the North-Eastern Atlantic macro benthic community. The cells of their immune system, known as coelomocytes, are the first line of defence against environmental hazards. Here, we report the results of investigations on the immune cells response of sea stars exposed to marine environmental pollution for long periods. We show that levels of the heat shock cognate protein 70 (HSC70) in coelomocytes from A. rubens, which were collected during a field study in the Sǿrfjord (North Sea, SW coast of Norway) along a contamination gradient, are directly associated with the long-term accumulation of Cd, Cu heavy metals exclusively in the tegument. Conversely, Pb and Zn accumulation in the tegument did not relate to HSC70 levels and none of the metals were found accumulated in the pyloric coeca. In addition the coelomocytes from A. rubens, collected in high and low metal impacted stations were examined by a proteomic approach using two-dimensional electrophoresis (2DE). By comparison of the proteomic maps, we observed that 31 protein spots differed in their relative abundance, indicating a gene expression response to the metal mixture exposure. All together, our results confirm that the echinoderm immune cells are a suitable model for the assessment of long-term exposure to environmental pollution, moreover that the increased level of HSC70 can be considered a signal of an acquired tolerance within a large spectrum of protein profile changes occurring in response to metal contamination. Copyright © 2011 Elsevier Ltd. All rights reserved.

  2. Bioaccumulation of metals (Cd, Cu, Ni, Pb and Zn) in suspended cultures of blue mussels exposed to different environmental conditions

    DEFF Research Database (Denmark)

    Maar, Marie; Larsen, Martin Mørk; Tørring, Ditte Bruunshøj

    2015-01-01

    corresponding to Good Ecological Status (GES) in the European Union Water Framework Directive (WFD) and in future climate change scenarios (higher metal concentrations and higher temperatures). For this purpose, GES is interpreted as good chemical status for the metals using the Environmental Quality Standards...... (EQS) defined in the WFD priority substance daughter directives. Observations showed that suspended mussels were healthy with respect to metal pollution and generally less polluted than benthic mussels due to the smaller contact with the contaminated sediment. The model results showed that the WFD...

  3. Comparative study of plant growth of two poplar tree species irrigated with treated wastewater, with particular reference to accumulation of heavy metals (Cd, Pb, As, and Ni).

    Science.gov (United States)

    Houda, Zarati; Bejaoui, Zoubeir; Albouchi, Ali; Gupta, Dharmendra K; Corpas, Francisco J

    2016-02-01

    Water is a scarce natural resource around the world which can hamper the socio-economic development of many countries. The Mediterranean area, especially north Africa, is known for its semi-arid to arid climate, causing serious water supply problems. Treated wastewater (TWW) is being used as an alternative strategy for recycling wastewater. It is also a potential source of nutrients for reforestation with certain plant species such as poplar trees, a useful wood resource, and even for phytoremediation purposes. In the present study, we used treated wastewater to irrigate two clones of 1-year-old poplar trees (Populus nigra cv. I-488 and Populus alba cv. MA-104) for 90 days. After a stipulated time, a comparative study was made of the effects of TWW on growth parameters, acquisition of essential minerals (Na, Fe and Zn) and pollutants (Cd, Pb, As and Ni) as well as the enrichment of secondary metabolites such as polyphenolic, flavonoid and tannin compounds which could contribute to the growth and development of poplar plants. The results of this study show that the use of TWW increased P. alba's biomass production by 36% and also enhanced its Cd and Pb accumulation capacity. We also found that P. alba has considerable potential to be used as an alternative plant species for reforestation and/or phytoremediation of toxic metals from contaminated water or effluent.

  4. Mobilidade de arsenio e metais pesados em solos do Vale do Ribeira, Iporanga, S.P

    OpenAIRE

    Daniela Mary Yamashita

    2004-01-01

    Resumo: O trabalho teve como objetivo analisar a mobilidade de arsênio e metais pesados em solos da Faixa Piririca, Vale do Ribeira, S.P. A área escolhida exibe solos ricos em As e metais pesados, derivados do intemperismo de rochas metassedimentares e metabásicas hospedeiras de mineralizações de ouro e sulfetos. As amostras de solo foram coletadas ao longo de dois transectos às zonas mineralizadas, com profundidade de até 30 cm. Em uma localidade foi realizada amostragem ao lo...

  5. Behavioural and biochemical responses to metals tested alone or in mixture (Cd-Cu-Ni-Pb-Zn) in Gammarus fossarum: From a multi-biomarker approach to modelling metal mixture toxicity.

    Science.gov (United States)

    Lebrun, Jérémie D; Uher, Emmanuelle; Fechner, Lise C

    2017-12-01

    Metals are usually present as mixtures at low concentrations in aquatic ecosystems. However, the toxicity and sub-lethal effects of metal mixtures on organisms are still poorly addressed in environmental risk assessment. Here we investigated the biochemical and behavioural responses of Gammarus fossarum to Cu, Cd, Ni, Pb and Zn tested individually or in mixture (M2X) at concentrations twice the levels of environmental quality standards (EQSs) from the European Water Framework Directive. The same metal mixture was also tested with concentrations equivalent to EQSs (M1X), thus in a regulatory context, as EQSs are proposed to protect aquatic biota. For each exposure condition, mortality, locomotion, respiration and enzymatic activities involved in digestive metabolism and moult were monitored over a 120h exposure period. Multi-metric variations were summarized by the integrated biomarker response index (IBR). Mono-metallic exposures shed light on biological alterations occurring at environmental exposure levels in gammarids and depending on the considered metal and gender. As regards mixtures, biomarkers were altered for both M2X and M1X. However, no additive or synergistic effect of metals was observed comparing to mono-metallic exposures. Indeed, bioaccumulation data highlighted competitive interactions between metals in M2X, decreasing subsequently their internalisation and toxicity. IBR values indicated that the health of gammarids was more impacted by M1X than M2X, because of reduced competitions and enhanced uptakes of metals for the mixture at lower, EQS-like concentrations. Models using bioconcentration data obtained from mono-metallic exposures generated successful predictions of global toxicity both for M1X and M2X. We conclude that sub-lethal effects of mixtures identified by the multi-biomarker approach can lead to disturbances in population dynamics of gammarids. Although IBR-based models offer promising lines of enquiry to predict metal mixture toxicity

  6. Investigation of the potential for concealed base-metal mineralization at the Drenchwater Creek Zn-Pb-Ag occurrence, northern Alaska, using geology, reconnaissance geochemistry, and airborne electromagnetic geophysics

    Science.gov (United States)

    Graham, Garth E.; Deszcz-Pan, Maria; Abraham, Jared E.; Kelley, Karen D.

    2011-01-01

    In 2005, the U.S. Geological Survey, Bureau of Land Management, and State of Alaska cooperated on an investigation of the mineral potential of a southern part of the National Petroleum Reserve in Alaska, Howard Pass quadrangle, to provide background information for future land-use decisions. The investigation incorporated an airborne electromagnetic (EM) survey covering 1,500 mi2 (~3,900 km2), including flight lines directly over the Drenchwater Creek sediment-hosted Zn-Pb-Ag occurrence, the largest known base-metal occurrence in the survey area. Samples from the mineralized outcrop and rubblecrop contain metal concentrations that can exceed 11 percent Zn+Pb, with appreciable amounts of Ag. Soil samples with anomalous Pb concentrations are distributed near the sulfide-bearing outcrops and along a >2.5 km zone comprising mudstone, shale, and volcanic rocks of the Kuna Formation.

  7. Accumulation of Pb and Cu heavy metals in sea water, sediment, and leaf and root tissue of Enhalus sp. in the seagrass bed of Banten Bay

    Energy Technology Data Exchange (ETDEWEB)

    Fauziah, Faiza, E-mail: faiza.fauziah@gmail.com; Choesin, Devi N., E-mail: faiza.fauziah@gmail.com [School of Life Sciences and Technology, Institut Teknologi Bandung, Jalan Ganeca 10, Bandung 40132 (Indonesia)

    2014-03-24

    Banten Bay in Indonesia is a coastal area which has been highly affected by human activity. Previous studies have reported the presence of lead (Pb) and copper (Cu) heavy metals in the seawater of this area. This study was conducted to measure the accumulation of Pb and Cu in seawater, sediment, leaf tissue, and root tissue of the seagrass species Enhalus sp. Sampling was conducted at two observation stations in Banten Bay: Station 1 (St.1) was located closer to the coastline and to industrial plants as source of pollution, while Station 2 (St.2) was located farther away offshore. At each station, three sampling points were established by random sampling. Field sampling was conducted at two different dates, i.e., on 29 May 2012 and 30 June 2012. Samples were processed by wet ashing using concentrated HNO{sub 3} acid and measured using Atomic Absorption Spectrometry (AAS). Accumulation of Pb was only detected in sediment samples in St.1, while Cu was detected in all samples. Average concentrations of Cu in May were as follows: sediment St.1 = 0.731 ppm, sediment St.2 = 0.383 ppm, seawater St.1 = 0.163 ppm, seawater St.2 = 0.174 ppm, leaf St.1 = 0.102 ppm, leaf St.2 = 0.132 ppm, root St.1= 0.139 ppm, and root St.2 = 0.075 ppm. Average measurements of Cu in June were: sediment St.1 = 0.260 ppm, leaf St.1 = 0.335 ppm, leaf St.2 = 0.301 ppm, root St.1= 0.047 ppm, and root St.2 = 0.060 ppm. In June, Cu was undetected in St.2 sediment and seawater at both stations. In May, Cu concentration in seawater exceeded the maximum allowable threshold for water as determined by the Ministry of the Environment. Spatial and temporal variation in Pb and Cu accumulation were most probably affected by distance from source and physical conditions of the environment (e.g., water current and mixing)

  8. Evaluation of the air quality regarding total suspended particles and heavy metals (Pb, Cd, Ni, Cu, Cr) in the Hermosillo city, Sonora, Mexico, during a yearly period

    International Nuclear Information System (INIS)

    Cruz C, M. E.; Quintero N, M.; Gomez A, A.; Varela S, J.

    2013-01-01

    In the present study, the air quality of the city of Hermosillo, Sonora, Mexico was assessed considering total suspended particulates (tsp) and heavy metals (Pb, Cd, Ni, Cu, Cr) from June 2001 through May 2002 in three monitoring sites Centro (Mazon), Nor este (CESUES) and Noroeste (CBTIS). The filter-samples used for that purpose were provided by the Air Quality Evaluation and Improvement Program (PEMCA) of the municipality of Hermosillo. The sampling method was based on high volume sampling frequency set every 6 days with non-simultaneous sampling among the three sampling sites. Filters were dissolved for metal determination by acidic-extraction, and then analyzed by flame atomic absorption spectrophotometry. Results indicate that tsp concentrations at Centro and Noroeste sites were frequently higher than the maximum daily permissible level (260 μg/m 3 ), while in the three sites the annual average was higher than the maximum annual permissible level (75 μg/m 3 ) both established in the standard NOM-024-Ssa-1993 (Ssa 1994a). According to the Air Quality Standard Index (US EPA 1992a), used in Mexico by Air Quality Metropolitan Index (IMECA) the results indicate that the air quality in the city of Hermosillo regarding tsp was placed between no satisfactory and poor. In regard to heavy metals (Pb, Cd, Ni, Cu, Cr), concentrations detected were below the maximum permissible levels and/or criteria taking into account the standard NOM-026-Ssa-1993 (Ssa 1994b), the Who criterion (2000), the European Union criterion (Cec 2003), and the European Environmental Agency criteria (EEA 2004). Such findings would mean that airborne metals are of no concern; however, air quality is still classified as no satisfactory due to high particulate matter concentrations. Keeping air quality parameters monitoring is recommended in order to get extensive data for use in risk studies of air quality and health (morbidity/mortality), as well as topographic conditions, meteorological and

  9. Forest Soil Pollution with Heavy Metals (Pb, Zn, Cd, and Cu in the Area of the “French Mines” on the Medvednica Mountain, Republic of Croatia

    Directory of Open Access Journals (Sweden)

    Ivan Perković

    2017-01-01

    Full Text Available Background and Purpose: This paper deals with the results of the investigation of the selected heavy metal contents in forest soil in the region of an abandoned mine. The analysis of the forest ecosystem soil on the Medvednica Mountain was conducted in the region of the so-called “French Mines” (FM. The elements selected for analyses were cadmium (Cd, copper (Cu, lead (Pb, and zinc (Zn because of their toxicological characteristics. Material and Methods: In the investigated area - five entrances of the FM - composite topsoil samples (0–5 cm were taken. Those samples were compared to the control samples which were taken outside the area affected by mines. The soil samples were analysed for the following parameters: pH, particle size distribution, organic C content and pseudo-total mass fractions of the selected heavy metals. The heavy metals were determined by atomic emission spectrometry with inductively coupled plasma (ICP-MS. Results and Conclusion: The results reveal that the soil is locally polluted, i.e. the highest mass fraction values of these four heavy metals were found in the area of the FM. Average pseudo-total fraction of Cd in the analysed topsoil samples was in the range of 0.17–4.41 mg·kg−1 (median: 0.97 mg·kg−1. Cu was found in the range of 4.54–1260 mg·kg−1 (median: 45.7 mg·kg−1. In the case of Zn, mass fraction values were found in the range of 36.8–865 mg·kg−1 (median: 137 mg·kg−1. Finally, average values of the pseudo-total fraction of Pb were found in the range of 58.4–12000 mg·kg−1 (median: 238 mg·kg−1. The results reveal that mining activities leave consequences on soil for a long time.

  10. Concentración de Hg, Pb, Cd, Cr y As en hígado de Carcharhinus limbatus (Carcharhiniformes: Carcharhinidae capturado en Veracruz, México

    Directory of Open Access Journals (Sweden)

    Fernando Mendoza-Díaz

    2013-06-01

    Full Text Available La contaminación de los ecosistemas marinos y costeros por metales pesados en el Golfo de México es uno de los problemas que afectan a los recursos naturales del medio acuático. Los tiburones por situarse en niveles tróficos superiores de la red alimenticia acumulan y magnifican cantidades considerables de contaminantes. Por esta razón, el objetivo de este trabajo fue determinar la concentración de cuatro metales pesados (Hg, Cd, Pb y Cr y un metaloide (As en el tiburón punta negra (Carcharhinus limbatus por medio de espectrofotometría de absorción atómica con flama y generador de hidruros. Se muestrearon 19 hígados de tiburones capturados cerca de Tamiahua, Veracruz entre noviembre 2007 y marzo 2008, de los cuales 12 fueron machos adultos, una hembra adulta, tres machos jóvenes y tres hembras jóvenes. Las concentraciones máximas registradas para cada metal fueron: Hg=0.69mg/ kg, Cd=0.43mg/kg, As=27.37mg/kg, Cr=0.35mg/kg. El Pb no fue detectado, no al menos la cantidad mínima de detección requerida por el espectrofotómetro de absorción atómica (0.1mg/kg. Ninguna de las muestras analizadas rebasó los límites máximos permisibles por las leyes mexicanas y americanas.Concentration of Hg, Pb, Cd, Cr and As in liver Carcharhinus limbatus (Carcharhiniformes: Carcharhinidae captured in Veracruz, Mexico. Pollution by heavy metals in marine ecosystems in the Gulf of Mexico is one of the hardest conservation issues to solve. Sharks as top predators are bioindicators of the marine ecosystem health, since they tend to bioaccumulate and biomagnify contaminants; they also represent a food source for local consumption. Thus, the objective of this study was to study the possible presence of heavy metals and a metalloid in livers of Carcharhinus limbatus. For this, a total of 19 shark livers were taken from animals captured nearby Tamihua, Veracruz, Mexico from December 2007 to April 2008. 12 out of the 19 captured sharks were males, one was

  11. Importance of exposure dynamics of metal-based nano-ZnO, -Cu and -Pb governing the metabolic potential of soil bacterial communities.

    Science.gov (United States)

    Zhai, Yujia; Hunting, Ellard R; Wouterse, Marja; Peijnenburg, Willie J G M; Vijver, Martina G

    2017-11-01

    Metal-based engineered nanomaterials (ENMs) are known to affect bacterial processes and metabolic activities. While testing their negative effects on biological components, studies traditionally rely on initial exposure concentrations and thereby do not take into consideration the dynamic behavior of ENMs that ultimately determines exposure and toxicity (e.g. ion release). Moreover, functional responses of soil microbial communities to ENMs exposure can be caused by both the particulate forms and the ionic forms, yet their relative contributions remain poorly understood. Therefore, we investigated the dynamic changes of exposure concentrations of three different types of ENMs (nano-ZnO, -Cu and -Pb) and submicron particles (SMPs) in relation to their impact on the capacity of soil bacterial communities to utilize carbon substrates. The different ENMs were chosen to differ in dissolution potential. The dynamic exposures of ENMs were considered using a time weighted average (TWA) approach. The joint toxicity of the particulate forms and the ionic forms of ENMs was evaluated using a response addition model. Our results showed that the effect concentrations of spherical nano-ZnO, -Cu and SMPs, and Pb-based perovskites expressed as TWA were lower than expressed as initial concentrations. Both particulate forms and ionic forms of spherical 18nm, 43nm nano-ZnO and 50nm, 100nm nano-Cu contribute to the overall response at the EC 50 levels. The particulate forms for 150nm, 200nm and 900nm ZnO SMPs and rod-shaped 78nm nano-Cu mainly affected the soil microbial metabolic potential, while the Cu ions released from spherical 25nm nano-Cu, 500nm Cu SMPs and Pb ions released from perovskites mainly described the effects to bacterial communities. Our results indicate that the dynamic exposure of ENMs and relative contributions of particles and ions require consideration in order to pursue a naturally realistic assessment of environmental risks of metal-based ENMs. Copyright

  12. Radionuclides (40K, 232Th and 238U) and Heavy Metals (Cr, Ni, Cu, Zn, As and Pb) Distribution Assessment at Renggam Landfill, Simpang Renggam, Johor, Malaysia

    Science.gov (United States)

    Zaidi, E.; FahrulRazi, MJ; Azhar, ATS; Hazreek, ZAM; Shakila, A.; Norshuhaila, MS; Omeje, M.

    2017-08-01

    The assessment of radioactivity levels and the distribution of heavy metals in soil samples at CEP Farm landfill, Renggam in Johor State was to determine the activity concentrations of naturally occurring radionuclides and heavy metal concentrations of this landfill. The background radiation was monitored to estimate the exposure level. The activity concentrations of radionuclides in soil samples were determined using HPGe gamma ray spectroscopy whereas the heavy metal concentration was measured using X-RF analysis. The mean exposure rate at the landfill site was 36.2±2.4 μR hr-1 and the annual effective dose rate at the landfill site was 3.19 ± 0.22 mSv yr-1. However, residential area has lower mean exposure dose rate of about 16.33±0.72 μR hr-1 and has an annual effective dose rate of 1.43±0.06 mSv yr-1 compared to landfill sites. The mean activity concentration of 40K, 238U and 232Th at landfill site were 239.95±15.89 Bq kg-1, 20.90±2.49 Bq kg-1 and 40.61±4.59 Bq kg-1, respectively. For heavy metal compositions, Cr, Ni and Cu have mean concentration of 232±10 ppm, 23±2 ppm, and 46±19 ppm, respectively. Whereas, Zn has concentration of 64±9 ppm and concentration of 12±1 ppm and 71±2 ppm was estimated for As and Pb respectively. The higher activity concentration of 40K down the slope through leaching process whereas the higher activity level of 238U content at the landfill site may be attributed to the soil disruption to local equilibrium.

  13. Mobilidade de metais pesados em solo tratado com resíduo siderúrgico ácido

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    N. M. B. Amaral Sobrinho

    1998-06-01

    Full Text Available Amostras do horizonte Bt de um Podzólico Vermelho-Amarelo (PV, predominante no aterro-piloto de resíduos industriais (ARSI da Companhia Siderúrgica Nacional (CSN, foram acondicionadas, em 1992, em colunas de vidro com 5,4 cm de diâmetro e 37 cm de altura. Sobre essas amostras de solo foram colocadas amostras de um resíduo ácido da CSN na proporção solo-resíduo de 4:1 (conforme a concepção básica do projeto do ARSI. Tal sistema resíduo-solo foi lixiviado com 50 volumes-poro de água deionizada, com pH 4,5, com o objetivo de avaliar a movimentação de Cr, Mn, Ni, Cu, Zn, Cd e Pb nas colunas. Depois da lixiviação, removeu-se o resíduo do topo das colunas, e seccionaram-se as amostras de solo em 4 partes iguais. Os metais pesados das amostras do resíduo e do solo foram extraídos seqüencialmente. 0 Pb, Cu e Cr mobilizados do resíduo ficaram retidos nos primeiros 5 cm da coluna de solo. 0 Zn, Mn, Ni e Cd tiveram aumento da concentração em profundidade. Nos efluentes das colunas com o resíduo, foram observadas concentrações de Mn e Ni bem superiores aos padrões permitidos pela Fundação Estadual de Engenharia do Meio Ambiente (FEEMA, 1985.

  14. SEPARATION OF Fe (III, Cr(III, Cu(II, Ni(II, Co(II, AND Pb(II METAL IONS USING POLY(EUGENYL OXYACETIC ACID AS AN ION CARRIER BY A LIQUID MEMBRANE TRANSPORT METHOD

    Directory of Open Access Journals (Sweden)

    La Harimu

    2010-06-01

    Full Text Available Fe (III, Cr(III, Cu(II, Ni(II, Co(II, and Pb(II  metal ions had been separated using poly(eugenyl oxyacetic acid as an ion carrier by bulk liquid membrane transport method. The effect of pH, polyeugenyl oxyacetic acid ion carrier concentration, nitric acid concentration in the stripping solution, transport time, and metal concentration were optimized. The result showed that the optimum condition for transport of metal ions was at pH 4 for ion Fe(III and at pH 5 for Cr(III, Cu(II, Ni(II, Co(II, and Pb(II ions. The carrier volumes were optimum with concentration of 1 x 10-3 M at 7.5 mL for Cr(III, Cu (II,  Ni(II, Co(II ions and at 8.5 mL for Fe(III and Pb(II ions. The concentration of HNO3 in stripping phase was optimum at 2 M for Fe(III and Cu(II ions, 1 M for Cr(III, Ni(II and Co(II ions, and 0.5 M for Pb(II ion. The optimum transport times were 36 h for Fe(III and Co(II ions, and 48 h for Cr(III, Cu (II, Ni(II, and Pb(II ions. The concentration of metal ions accurately transported were 2.5 x 10-4 M for Fe(III and Cr(III ions, and 1 M for Cu (II, Ni(II, Co(II, and Pb(II ions. Compared to other metal ions the transport of Fe(III was the highest with selectivity order of Fe(III > Cr(III > Pb(II > Cu(II > Ni(II > Co(II. At optimum condition, Fe(III ion was transported through the membrane at 46.46%.   Keywords: poly(eugenyl oxyacetic acid, transport, liquid membrane, Fe (III, Cr(III, Cu(II, Ni(II, Co(II, and Pb(II ions

  15. Zoning of heavy metal concentrations including Cd, Pb and As in agricultural soils of Aghili plain, Khuzestan province, Iran

    Directory of Open Access Journals (Sweden)

    Mehdi Ahmadi

    2017-10-01

    Furthermore, based on the PLI, all stations were categorized as moderately to highly polluted sites (1metal for human health, furture monitoring, some control measures and remedial actions should be undertaken in the study area.

  16. First Principles Investigation of the Magnetic, Magnetoelectric, and Optical Properties of Double Perovskites Containing Ions of Transition Metals LaPbTSbO6 (T = Fe, Co, Ni)

    Science.gov (United States)

    Zhandun, V. S.; Zinenko, V. I.

    2017-12-01

    Within the first principles approach implemented in the VASP package, a correlation between magnetic, electronic, polarization, and optical properties, on the one hand, and the structural ordering of cations, on the other hand, is investigated in double perovskites LaPbTSbO6 (T = Fe, Co, Ni). Two types of cation ordering are considered: simultaneous layered (LL) and checkerboard (RR) ordering of both cations. These two types of ordering are chosen due to their significance; namely, the ordering RR is one of the most implementable types of cation ordering in double perovskites, and compounds with layered ordering can be considered as a heterostructure consisting of periodically alternating metal-nonmagnetic metal layers, which is of interest for experimental synthesis and investigation. It is found that the type of cation ordering in compounds with T = Fe and Ni radically changes the magnetic and/or electronic properties of the compound. Moreover, it is found that low-symmetry stable phases are polar for both types of cation ordering, and the values of spontaneous polarization are evaluated.

  17. Influence of fly ash aided phytostabilisation of Pb, Cd and Zn highly contaminated soils on Lolium perenne and Trifolium repens metal transfer and physiological stress

    International Nuclear Information System (INIS)

    Lopareva-Pohu, Alena; Verdin, Anthony; Garcon, Guillaume; Lounes-Hadj Sahraoui, Anissa; Pourrut, Bertrand; Debiane, Djouher; Waterlot, Christophe; Laruelle, Frederic

    2011-01-01

    Due to anthropogenic activities, large extends of soils are highly contaminated by Metal Trace Element (MTE). Aided phytostabilisation aims to establish a vegetation cover in order to promote in situ immobilisation of trace elements by combining the use of metal-tolerant plants and inexpensive mineral or organic soil amendments. Eight years after Coal Fly Ash (CFA) soil amendment, MTE bioavailability and uptake by two plants, Lolium perenne and Trifolium repens, were evaluated, as some biological markers reflecting physiological stress. Results showed that the two plant species under study were suitable to reduce the mobility and the availability of these elements. Moreover, the plant growth was better on CFA amended MTE-contaminated soils, and the plant sensitivity to MTE-induced physiological stress, as studied through photosynthetic pigment contents and oxidative damage was lower or similar. In conclusion, these results supported the usefulness of aided phytostabilisation of MTE-highly contaminated soils. - Highlights: → Aided phytostabilisation aims to establish a vegetation cover in order to promote immobilisation of MTE. → 8 years after the soil amendments, a pot culture study was carried out in greenhouse conditions. → MTE bioavailability and uptake by the two plants was drastically decreased with amendments. → Our results support the usefulness of aided phytostabilisation of MTE-highly contaminated soils. → CFA addition contributed to the reduction of the MTE mobility and availability for the plants. - Efficiency of Coal Fly Ash amendment for phytostabilisation of Pb, Cd and Zn in MTE-highly contaminated soils.

  18. Analysis of heavy metal lead (Pb) levels with Aas in cow's milk by giving cumin (Cuminum cyminum L.), white turmeric (Curcuma zedoaria Rosc.) and mango turmeric (Curcuma mangga Val.).

    Science.gov (United States)

    Nurdin, E; Putra, D P; Amelia, T

    2013-11-01

    The aim of this study was to determine the effect of giving Cumin (Cuminum cyminum L.), White Turmeric (Curcuma zedoaria Rosc.) and Mango Turmeric (Curcuma mango Val.) on levels of heavy metals lead (Pb) in cow's milk produced. The study was conducted in West Java with experimental method in 16 Fries Holland dairy cows with lactation period of 2-4 months and lactation months of 3-4 months. The design used is simple randomized design with 4 treatments such as Group A (control/no treatment), Group B (Cumin 0.03% body weight), Group C (White Turmeric 0.02% body weight) and Group D (Mango Turmeric 0.06% body weight). Measurement of Pb levels in milk using the method of wet destruction, while Pb measurements on faeces using wet ashing method, by means of Atomic Absorption Spectrophotometry. Based on the researsch results showed that administration of Cumin, White Turmeric and Mango Turmeric have very real effect on reducing levels of heavy metals lead (Pb) in cow's milk produced, with a consecutive decrease 98.36, 99.33 and 99.37% and the very real effect on elevated levels of Pb in faeces by 68.01, 64.52 and 80.54%. Mango Turmeric is the best treatment of three treatment in decreasing lead level in milk.

  19. EDTA assisted phytorremediation of a Pb contamined soil: metal leaching and uptake by jack beans Lixiviação e absorção de Pb pelo feijão-de-porco assistido pela aplicação de EDTA no solo

    Directory of Open Access Journals (Sweden)

    Mariana Bassetto Gabos

    2009-08-01

    Full Text Available Lead (Pb is one of the main soil contaminants. It is also of difficult phytoremediation due to its low solubility and high retention on soil particles. EDTA application to soil is a strategy to increase heavy metal phytoextraction, but such chelants usually cause phytotoxicity and metal leaching side effects. Therefore, these research work objectives were to evaluate the effects of single (0.5 g kg-1 and split (0.25 + 0.25 g kg-1 EDTA application on Pb uptake by jack beans (Canavalia ensiformis L. as well as on Pb vertical movement in a Pb contaminated soil material. Two sets of experiments were carried out under greenhouse conditions: in the first one, plants were grown in 3L-pots filled with a Pb-contaminated soil to evaluate Pb uptake by plants; for the second experiment, PVC-columns (42 cm height were used to evaluate soil Pb leaching: the upper half-column (20 cm was filled up with Pb-contaminated soil (1800 mg kg-1 whereas the lower half-column (20 cm was filled with clean soil. Ten 60 mm-rainfalls with a duration of five hours were simulated by dropping distilled water on the top of columns, and leachates were collected for chemical analysis. Plants did not show any visual Pb toxicity symptoms or reduction in dry matter yield. Nevertheless, Pb uptake by jack beans regarded as total plant Pb accumulation was higher in EDTA-treated plants. Vertical Pb movement was observed mostly for the single EDTA application. EDTA addition to the soil favor Pb-phytoextraction by jack beans and the split EDTA application decrease the metal leaching, indicating less risk of environmental contamination.O chumbo (Pb é um dos principais contaminantes de solo. Os processos de remediação são dificultados devido à alta retenção do elemento às partículas do solo. A utilização do EDTA para aumentar a fitoextração dos metais do solo tem apresentado bons resultados. Contudo, os quelantes podem causar efeitos indesejáveis como a fitotoxidez e a lixivia

  20. A cortiça como sonda ambiental de metais pesados: um serviço sócio-ambiental prestado por montados de sobro e sobreirais The cork as environmental probe of heavy metals: a socio- environmental service done by “montados” with cork oaks and cork oak stands (Quercus suber L.

    Directory of Open Access Journals (Sweden)

    J. Ponte-e-Sousa

    2007-01-01

    Full Text Available A longevidade do sobreiro e a capacidade que a cortiça amadia tem de crescer construindo camadas anuais extremamente bem individualizáveis permitiu criar a hipótese de correlação entre as marcas químicas deixadas em cada camada de crescimento e as características ambientais do local onde o sobreiro vegeta. Isto permitiria a construção de séries de novénios de distribuição espacial e temporal da característica que se pretenda estudar. Há nisto algumas semelhanças com abordagens dendrométricas, sendo que estas tendem a ser muito mais agressivas. Foi objectivo deste trabalho que numa fase inicial do estudo se procedesse à criação de uma maneira credível de fazer a quantificação de chumbo (II no felema da cortiça recorrendo a uma técnica de análise química nunca antes utilizada para este efeito – a voltametria. A escolha deste método da análise química moderna resulta do conhecimento das vantagens competitivas que tem sobre outros, quando aquele é aplicável, como se demonstra ser o caso. A metodologia utilizada começou por exigir a recolha de uma porção de cortiça de um sobreiro escolhido ao acaso, de maneira a encontrar o material cortiça como se encontra na árvore. No momento não se consideram possíveis correlações biogeográficas mas tão somente o material propriamente dito. Tendo sido possível fazer a quantificação indicada, estão em curso os estudos necessários à verificação da hipótese que dá o mote a este trabalho de investigação centrado no sobreiro do montado e do sobreiral, sendo que a principal conclusão a retirar é que a possibilidade de utilização do sobreiro como indicador da qualidade ambiental do local, neste caso quanto ao teor em Pb(II, é mais um serviço prestável (pelo ecossistema que orbita em torno do sobreiro às populações humanas da área da bacia mediterrânica ocidental. O futuro uso da voltametria como forma de, determinando a concentração do metal em

  1. Associação entre espondiloartrose lombar e trabalho pesado

    Directory of Open Access Journals (Sweden)

    Raimundo Antonio da Silva

    Full Text Available OBJETIVO: Estudar uma possível associação entre espondiloartrose lombar e trabalho pesado. METODOLOGIA: Estudo epidemiológico transversal realizado no período de outubro/04 a outubro/05, baseado em casos atendidos por um hospital público de São Luís, MA, Brasil. Trabalhadores (1256 encaminhados ao serviço de ortopedia foram submetidos à História Ocupacional, Exame Físico Ortopédico e Radiografia de Coluna Lombar e Lombossacra em AP/P e Oblíqüa. Critérios de inclusão e exclusão selecionaram 456 trabalhadores de ambos os gêneros, na faixa etária de 28 a 48 anos. Estes foram agrupados, conforme sua ocupação, em trabalho pesado e não pesado e submetidos aos critérios diagnósticos de espondiloartrose lombar. RESULTADOS: A associação entre trabalho pesado e espondiloartrose lombar foi realizada através do cálculo da razão de prevalências, cujo resultado mostrou-se elevado, evidenciando uma possível associação. A interferência de outras variáveis como possível viés de confundimento, tais como idade, gênero e peso corporal (IMC, foram controladas na fase de análise de dados através do teste de Mantel-Haenzel. O resultado final mostrou que não houve interferência dessas variáveis. CONCLUSÕES: ESTE estudo indicou uma possível associação entre exposição a trabalho pesado e espondiloartrose lombar.

  2. Analysis of trace metals (Cu, Cd, Pb, and Fe) in seawater using single batch nitrilotriacetate resin extraction and isotope dilution inductively coupled plasma mass spectrometry

    International Nuclear Information System (INIS)

    Lee, Jong-Mi; Boyle, Edward A.; Echegoyen-Sanz, Yolanda; Fitzsimmons, Jessica N.; Zhang Ruifeng; Kayser, Richard A.

    2011-01-01

    A simple and accurate low-blank method has been developed for the analysis of total dissolved copper, cadmium, lead, and iron in a small volume (1.3-1.5 mL per element) of seawater. Pre-concentration and salt-separation of a stable isotope spiked sample are achieved by single batch extraction onto nitrilotriacetate (NTA)-type Superflow chelating resin beads (100-2400 beads depending on the element). Metals are released into 0.1-0.5 M HNO 3 , and trace metal isotope ratios are determined by ICPMS. The benefit of this method compared to our previous Mg(OH) 2 coprecipitation method is that the final matrix is very dilute so cone-clogging and matrix sensitivity suppression are minimal, while still retaining the high accuracy of the isotope dilution technique. Recovery efficiencies are sensitive to sample pH, number of resin beads added, and the length of time allowed for sample-resin binding and elution; these factors are optimized for each element to yield the highest recovery. The method has a low procedural blank and high sensitivity sufficient for the analysis of pM-nM open-ocean trace metal concentrations. Application of this method to samples from the Bermuda Atlantic Time-Series Study station provides oceanographically consistent Cu, Cd, Pb, and Fe profiles that are in good agreement with other reliable data for this site. In addition, the method can potentially be modified for the simultaneous analysis of multiple elements, which will be beneficial for the analysis of large number of samples.

  3. Analysis of trace metals (Cu, Cd, Pb, and Fe) in seawater using single batch nitrilotriacetate resin extraction and isotope dilution inductively coupled plasma mass spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Jong-Mi [Department of Earth, Atmospheric, and Planetary Sciences, Massachusetts Institute of Technology, Cambridge, MA 02139 (United States); Boyle, Edward A., E-mail: eaboyle@mit.edu [Department of Earth, Atmospheric, and Planetary Sciences, Massachusetts Institute of Technology, Cambridge, MA 02139 (United States); Echegoyen-Sanz, Yolanda; Fitzsimmons, Jessica N. [Department of Earth, Atmospheric, and Planetary Sciences, Massachusetts Institute of Technology, Cambridge, MA 02139 (United States); Zhang Ruifeng [State Key Laboratory of Estuarine and Coastal Research, East China Normal University, Shanghai 200062 (China); Kayser, Richard A. [Department of Earth, Atmospheric, and Planetary Sciences, Massachusetts Institute of Technology, Cambridge, MA 02139 (United States)

    2011-02-07

    A simple and accurate low-blank method has been developed for the analysis of total dissolved copper, cadmium, lead, and iron in a small volume (1.3-1.5 mL per element) of seawater. Pre-concentration and salt-separation of a stable isotope spiked sample are achieved by single batch extraction onto nitrilotriacetate (NTA)-type Superflow chelating resin beads (100-2400 beads depending on the element). Metals are released into 0.1-0.5 M HNO{sub 3}, and trace metal isotope ratios are determined by ICPMS. The benefit of this method compared to our previous Mg(OH){sub 2} coprecipitation method is that the final matrix is very dilute so cone-clogging and matrix sensitivity suppression are minimal, while still retaining the high accuracy of the isotope dilution technique. Recovery efficiencies are sensitive to sample pH, number of resin beads added, and the length of time allowed for sample-resin binding and elution; these factors are optimized for each element to yield the highest recovery. The method has a low procedural blank and high sensitivity sufficient for the analysis of pM-nM open-ocean trace metal concentrations. Application of this method to samples from the Bermuda Atlantic Time-Series Study station provides oceanographically consistent Cu, Cd, Pb, and Fe profiles that are in good agreement with other reliable data for this site. In addition, the method can potentially be modified for the simultaneous analysis of multiple elements, which will be beneficial for the analysis of large number of samples.

  4. The distribution of blood concentrations of lead (Pb), cadmium (Cd), chromium (Cr) and manganese (Mn) in residents of the German Ruhr area and its potential association with occupational exposure in metal industry and/or other risk factors.

    Science.gov (United States)

    Bonberg, Nadine; Pesch, Beate; Ulrich, Nadin; Moebus, Susanne; Eisele, Lewin; Marr, Anja; Arendt, Marina; Jöckel, Karl-Heinz; Brüning, Thomas; Weiss, Tobias

    2017-08-01

    This study investigated the metal distribution in blood samples from the general population and the risk of having high metal concentration for metal workers. Metal concentrations were determined in archived blood samples from 1411 men and 1410 women (median age 59 and 57 years, respectively) collected at baseline (2000-2003) of the prospective Heinz Nixdorf Recall Study. Retrospective information on working in metal industry was obtained from previous follow-up survey (2011-2014). Odds ratios (ORs) with 95% confidence intervals (CI) of having a metal concentration >90th percentile (P90) for working in metal industry were calculated using logistic regression with adjustment for covariates. More men than women worked in metal industry (57 vs. 3 at baseline). Male metal workers had increased blood lead (Pb) (OR: 2.86; 95% CI: 1.38-5.91) and manganese (Mn) (OR: 2.92; 95% CI: 1.46-5.81). Smoking (≥30 cigarettes/day) strongly influenced cadmium (Cd) in blood (OR: 168; 95% CI: 55-510). Women had higher Mn (8.92μg/L) and Cd (0.36μg/L) concentrations than men (Mn: 8.11μg/L; Cd: 0.29μg/L). Blood Pb in women (29.2μg/L) was lower than in men (33.2μg/L). None of the studied risk factors was significantly associated with chromium and nickel concentrations above their 90th percentiles. In this population-based cohort we found evidence that working in metal industry was predictive for having elevated blood Pb and Mn concentrations. However, the 95th percentiles of all investigated metals were not significantly influenced by metal-related occupations. The present study is supportive for gender-specific reference values to limit occupational exposure to Mn and Pb. The strong influence of smoking on blood Cd hinders establishing reference values. Copyright © 2017 Elsevier GmbH. All rights reserved.

  5. Pollution and ecological risk assessment of heavy metals in the soil-plant system and the sediment-water column around a former Pb/Zn-mining area in NE Morocco.

    Science.gov (United States)

    El Azhari, Abdellah; Rhoujjati, Ali; El Hachimi, Moulay Laârabi; Ambrosi, Jean-Paul

    2017-10-01

    This study discussed the environmental fate and ecological hazards of heavy metals in the soil-plant system and sediment-water column around the former Pb-Zn mining Zeïda district, in Northeastern Morocco. Spatial distribution, pollution indices, and cluster analysis were applied for assessing Pb, Zn, As, Cu and Cd pollution levels and risks. The geo-accumulation index (I geo ) was determined using two different geochemical backgrounds: i) the commonly used upper crust values, ii) local geochemical background calculated with exploratory data analysis. The soils in the vicinity of the tailings, as well as the sediments downstream of the latter, displayed much higher metal concentrations, I geo, and potential ecology risk coefficient values than other sites, classifying these sites as highly contaminated and severely hazardous. The concentrations of Pb in contaminated sediment samples also exceeded the PEC limits and are expected to cause harmful effects on sediment-dwelling organisms. Based on the comparison with the toxicity limits, the most contaminated plant samples were found around the tailings piles. The metal concentrations in both raw and filtrated water samples were overall below the drinking water standards in samples upstream and downstream of the mining center, indicating that heavy metals levels in the Moulouya River surface waters were not affected by the tailings spill. Cluster analysis suggest that: i) Pb and Zn in sediments were derived from the abandoned tailings and are mainly stored and transported as particle-bound to the bedload, ii) Pb, Zn, and Cu in the soil-plant system were related to the dispersion of tailings materials while As and Cd originated primarily from natural geological background in both the soil-plant and the water-sediment systems. Copyright © 2017 Elsevier Inc. All rights reserved.

  6. The Effect of Mustard Gas on Salivary Trace Metals (Zn, Mn, Cu, Mg, Mo, Sr, Cd, Ca, Pb, Rb)

    Science.gov (United States)

    Zamani Pozveh, Elham; Seif, Ahmad; Ghalayani, Parichehr; Maleki, Abbas; Mottaghi, Ahmad

    2015-01-01

    We have determined and compared trace metals concentration in saliva taken from chemical warfare injures who were under the exposure of mustard gas and healthy subjects by means of inductively coupled plasma optical emission spectroscopy (ICP-OES) for the first time. The influence of preliminary operations on the accuracy of ICP-OES analysis, blood contamination, the number of restored teeth in the mouth, salivary flow rate, and daily variations in trace metals concentration in saliva were also considered. Unstimulated saliva was collected at 10:00–11:00 a.m. from 45 subjects in three equal groups. The first group was composed of 15 healthy subjects (group 1); the second group consisted of 15 subjects who, upon chemical warfare injuries, did not use Salbutamol spray, which they would have normally used on a regular basis (group 2); and the third group contained the same number of patients as the second group, but they had taken their regular medicine (Salbutamol spray; group 3). Our results showed that the concentration of Cu in saliva was significantly increased in the chemical warfare injures compared to healthy subjects, as follows: healthy subjects 15.3± 5.45(p.p.b.), patients (group 2) 45.77±13.65, and patients (Salbutamol spray; group 3) 29 ±8.51 (P ICP-OES outputs. PMID:25965704

  7. Geochemical behavior of heavy metals in differents environments in Rodrigo de Freitas lagoon - RJ/Brazil

    Directory of Open Access Journals (Sweden)

    Estefan M Fonseca

    2011-06-01

    Full Text Available The accelerated urbanisation without a planning, brought several environmental problems to Rio de Janeiro coastal zone, especially in areas such as Rodrigo de Freitas lagoon, which receives a great amount of untreated sewage every day. To assess the nature, potentially sources and extent of heavy metal pollution in the lagoon, sediments from the surrounding streets, from the entrance of the main canal that drains to the lagoon and from the bottom of the lagoon were collected and analysed by a modified selective extraction procedure in order to study the geochemical partitioning and bioavailability of Zn, Cu, Cr, Ni and Pb in these three compartments. The present study verified an increase in the Cu, Pb and Zn concentrations in the north of the Rodrigo de Freitas lagoon. Despite the different levels of oxidation between the sediments accumulated in the streets and in the bottom of the lagoon, the geochemical partitioning of the heavy metals did not show any pattern of variation for the metals, except for the element Cu. No concentrations were found in the soluble phase of samples collected in the surfacial sediments of the lagoon, suggesting no bioavailability of heavy metalsA urbanização acelerada, sem planejamento, resultou em uma série de problemas à zona costeira do Rio de Janeiro, especialmente em áreas como a Lagoa Rodrigo de Freitas, a qual recebe uma grande descarga de esgoto não tratado todos os dias. No intuito de avaliar a natureza, as fontes potenciais e a extensão da poluição por metais pesados na lagoa, sedimentos das ruas do entorno, das entradas do principal canal de drenagem e de superfície de fundo foram coletados. As análises se deram através de um método modificado de extração sequencial, com o objetivo de estudar o fracionamento geoquímico e a biodisponibilidade de Zn, Cu, Cr, Ni e Pb, nestes três compartimentos. O presente estudo verificou um aumento nas concentrações de Cu, Pb, e Zn no setor norte da

  8. An ultra-clean technique for accurately analysing Pb isotopes and heavy metals at high spatial resolution in ice cores with sub-pg g{sup -1} Pb concentrations

    Energy Technology Data Exchange (ETDEWEB)

    Burn, Laurie J. [Department of Imaging and Applied Physics, Curtin University of Technology, GPO Box U1987, Perth 6845, Western Australia (Australia); Rosman, Kevin J.R. [Department of Imaging and Applied Physics, Curtin University of Technology, GPO Box U1987, Perth 6845, Western Australia (Australia)], E-mail: K.Rosman@curtin.edu.au; Candelone, Jean-Pierre [Department of Imaging and Applied Physics, Curtin University of Technology, GPO Box U1987, Perth 6845, Western Australia (Australia); Vallelonga, Paul [Department of Imaging and Applied Physics, Curtin University of Technology, GPO Box U1987, Perth 6845, Western Australia (Australia); Istituto per la Dinamica dei Processi Ambientali (IDPA-CNR), Dorsoduro 2137, 30123 Venice (Italy); Burton, Graeme R. [Department of Imaging and Applied Physics, Curtin University of Technology, GPO Box U1987, Perth 6845, Western Australia (Australia); Smith, Andrew M. [Australian Nuclear Science and Technology Organisation (ANSTO), PMB 1, Menai, NSW 2234 (Australia); Morgan, Vin I. [Australian Antarctic Division and Antarctic Climate and Ecosystems CRC, Private Bag 80, Hobart, Tasmania 7001 (Australia); Barbante, Carlo [Istituto per la Dinamica dei Processi Ambientali (IDPA-CNR), Dorsoduro 2137, 30123 Venice (Italy); Hong, Sungmin [Korea Polar Research Institute, Songdo Techno Park, 7-50, Songdo-dong, Yeonsu-gu, Incheon 406-840 (Korea, Republic of); Boutron, Claude F. [Laboratoire de Glaciologie et Geophysique de l' Environnement du CNRS, 54, rue Moliere, B.P. 96, 3840.2 St Martin d' Heres Cedex (France)

    2009-02-23

    Measurements of Pb isotope ratios in ice containing sub-pg g{sup -1} concentrations are easily compromised by contamination, particularly where limited sample is available. Improved techniques are essential if Antarctic ice cores are to be analysed with sufficient spatial resolution to reveal seasonal variations due to climate. This was achieved here by using stainless steel chisels and saws and strict protocols in an ultra-clean cold room to decontaminate and section ice cores. Artificial ice cores, prepared from high purity water were used to develop and refine the procedures and quantify blanks. Ba and In, two other important elements present at pg g{sup -1} and fg g{sup -1} concentrations in Polar ice, were also measured. The final blank amounted to 0.2 {+-} 0.2 pg of Pb with {sup 206}Pb/{sup 207}Pb and {sup 208}Pb/{sup 207}Pb ratios of 1.16 {+-} 0.12 and 2.35 {+-} 0.16, respectively, 1.5 {+-} 0.4 pg of Ba and 0.6 {+-} 2.0 fg of In, most of which probably originates from abrasion of the steel saws by the ice. The procedure was demonstrated on a Holocene Antarctic ice core section and was shown to contribute blanks of only {approx}5%, {approx}14% and {approx}0.8% to monthly resolved samples with respective Pb, Ba and In concentrations of 0.12 pg g{sup -1}, 0.3 pg g{sup -1} and 2.3 fg g{sup -1}. Uncertainties in the Pb isotopic ratio measurements were degraded by only {approx}0.2%.

  9. The effect of mustard gas on salivary trace metals (Zn, Mn, Cu, Mg, Mo, Sr, Cd, Ca, Pb, Rb.

    Directory of Open Access Journals (Sweden)

    Elham Zamani Pozveh

    Full Text Available We have determined and compared trace metals concentration in saliva taken from chemical warfare injures who were under the exposure of mustard gas and healthy subjects by means of inductively coupled plasma optical emission spectroscopy (ICP-OES for the first time. The influence of preliminary operations on the accuracy of ICP-OES analysis, blood contamination, the number of restored teeth in the mouth, salivary flow rate, and daily variations in trace metals concentration in saliva were also considered. Unstimulated saliva was collected at 10:00-11:00 a.m. from 45 subjects in three equal groups. The first group was composed of 15 healthy subjects (group 1; the second group consisted of 15 subjects who, upon chemical warfare injuries, did not use Salbutamol spray, which they would have normally used on a regular basis (group 2; and the third group contained the same number of patients as the second group, but they had taken their regular medicine (Salbutamol spray; group 3. Our results showed that the concentration of Cu in saliva was significantly increased in the chemical warfare injures compared to healthy subjects, as follows: healthy subjects 15.3± 5.45 (p.p.b., patients (group 2 45.77±13.65, and patients (Salbutamol spray; group 3 29 ±8.51 (P <0.02. In contrast, zinc was significantly decreased in the patients, as follows: healthy subjects 37 ± 9.03 (p.p.b., patients (group 2 12.2 ± 3.56, and patients (Salbutamol spray; group 3 20.6 ±10.01 (P < 0.01. It is important to note that direct dilution of saliva samples with ultrapure nitric acid showed the optimum ICP-OES outputs.

  10. Heavy metal levels (Pb, Cd, Cr and Hg) in the adult general population near an urban solid waste incinerator

    Energy Technology Data Exchange (ETDEWEB)

    Zubero, Miren Begona, E-mail: txitea@gmail.com [Research Unit, Cruces Hospital, Barakaldo, Bizkaia (Spain); Department of Preventative Medicine and Public Health, University of the Basque Country, Leioa, Bizkaia (Spain); Aurrekoetxea, Juan Jose, E-mail: jaurrekoetxea@ej-gv.es [Public Health Department, Dept. of Health, Basque Government, Gipuzkoa (Spain); Epidemiolgy and Public Health CIBER (CIBERESP) (Spain); Ibarluzea, Jesus Maria, E-mail: mambien3-san@ej-gv.es [Public Health Department, Dept. of Health, Basque Government, Gipuzkoa (Spain); Epidemiolgy and Public Health CIBER (CIBERESP) (Spain); Arenaza, Maria Jesus, E-mail: osalanrlhba@ej-gv.es [Basque Institute for Occupational Health and Safety, Barakaldo, Bizkaia (Spain); Rodriguez, Carlos, E-mail: carlos.rodriguez-andres@ehu.es [Department of Preventative Medicine and Public Health, University of the Basque Country, Leioa, Bizkaia (Spain); Saenz, Jose Ramon, E-mail: jrsaenz@chdo.osakidetza.net [Department of Preventative Medicine and Public Health, University of the Basque Country, Leioa, Bizkaia (Spain)

    2010-09-15

    In 2005 an urban solid waste incinerator (SWI) was commissioned in Bilbao (Basque Country, Spain). Serum and urine samples were collected from 95 and 107 volunteers in 2006 and 2008 respectively, of which 62 were repeats from the same individuals. Blood lead levels (BPb) were determined, as were the concentrations of cadmium (Cd), chromium (Cr) and mercury (Hg) in urine (UCd, UCr and UHg). The town of Alonsotegi and a borough of Bilbao (Altamira, Rekalde) were considered to be close, less than 2 km from the plant, and correspond to an urban environment with high traffic density. The areas of reference were a borough of Bilbao (Santutxu-Zurbaran), 5 km from the plant, also in an urban area with high traffic density, and a small town with little industrial activity and low traffic density (Balmaseda) 20 km from the plant; neither of these is downwind from the site with respect to prevailing winds. There was a significant correlation for BPb, r = 0.63 (p < 0.001), between the two surveys. However, there was no linear correlation for the other three metals (UCd, UCr and UHg), between the two sampling periods (p > 0.05). Multiple linear regression models did not show increases over time of the levels of BPb, UCd, UCr and UHg in the areas close to the SWI compared to those of areas located further away, after adjusting for confounding variables. These results reinforce the hypothesis that populations near modern plants for solid waste incineration do not manifest increased levels of heavy metals.

  11. Majors soil classes of the metropolitan region of Curitiba (PR, Brazil: II - interaction of Pb with mineral and organic constituents

    Directory of Open Access Journals (Sweden)

    Ana Christina Duarte Pires

    2007-03-01

    Full Text Available The interaction between heavy metals and soil constituents is one of the most important factors influencing the potential for ground water pollution. To study Pb behavior, samples of soils were incubated with a salt solution containing this metal. The experimental units consisted of plastic bags, partially opened with 0.1 dm³ of soil with three replications. After incubation, samples were subjected to sequential and selective extractions. Lead retention, measured by the maximum adsorption capacity of the soil, was relatively high with values ranging from 6,439 to 22,148 mg kg-1. The sequential and selective extractions showed that Pb adsorption was stable where the metal was found mainly in organic matter, Fe and Al oxides, and residual forms (specific adsorption. The capacity of the soils to retain Pb, thereby increasing the leaching potential of the metal, was in the sequence of: Histosol - Oxisol - Inceptisol.A interação entre os metais pesados e os constituintes orgânicos e minerais do solo é um dos fatores mais importantes para definir o potencial de contaminação das águas subterrâneas. Para estudar o comportamento do Pb em solos da região metropolitana de Curitiba, estado do Paraná, amostras das classes Organossolo, Latossolo e Cambissolo foram submetidas a análises físicas e químicas, e incubadas com soluções de sais desse metal. A dosagem utilizada correspondeu a 40% da Capacidade Máxima de Adsorção de Pb do solo (CMA. O ensaio foi conduzido na Universidade Federal do Paraná, em condições de casa de vegetação, no período de 29 de outubro a 29 de dezembro de 2003. O delineamento experimental foi em blocos ao acaso, com três repetições e as unidades experimentais corresponderam a sacos plásticos parcialmente abertos com 0,1 dm³ de solo. Após o período de incubação (60 dias, as amostras foram submetidas a extrações seqüenciais e seletivas, na seguinte ordem: 1 KCl 0,005 mol L-1; 2 BaCl2 0,1 mol L-1; 3 Na

  12. Genotoxicity and cytotoxicity response to environmentally relevant complex metal mixture (Zn, Cu, Ni, Cr, Pb, Cd) accumulated in Atlantic salmon (Salmo salar). Part I: importance of exposure time and tissue dependence.

    Science.gov (United States)

    Stankevičiūtė, Milda; Sauliutė, Gintarė; Svecevičius, Gintaras; Kazlauskienė, Nijolė; Baršienė, Janina

    2017-10-01

    Health impact of metal mixture at environment realistic concentrations are difficult to predict especially for long-term effects where cause-and-effect relationships may not be directly obvious. This study was aimed to evaluate metal mixture (Zn-0.1, Cu-0.01, Ni-0.01, Cr-0.01, Pb-0.005 and Cd-0.005 mg/L, respectively for 1, 2, 4, 7, 14 and 28 days at concentrations accepted for the inland waters in EU) genotoxicity (micronuclei, nuclear buds, nuclear buds on filament), cytotoxicity (8-shaped nuclei, fragmented-apoptotic erythrocytes), bioaccumulation, steady-state and the reference level of geno-cytotoxicity in hatchery-reared Atlantic salmon tissues. Metals accumulated mostly in gills and kidneys, to the lesser extent in the muscle. Uptake of metals from an entire mixture in the fish for 14 days is sufficient to reach steady-state Cr, Pb concentrations in all tissues; Zn, Cu-in kidneys and muscle, Ni-in liver, kidneys, muscle and Cd-in muscle. Treatment with metal mixture significantly increased summed genotoxicity levels at 7 days of exposure in peripheral blood and liver erythrocytes, at 14 days of exposure in gills and kidney erythrocytes. Significant elevation of cytotoxicity was detected after 2 and 14 days of exposure in gills erythrocytes and after 28 days-in peripheral blood erythrocytes. The amount of Cu, Cr, Pb and Cd accumulated in tissues was dependent upon duration of exposure; nuclear buds, 8-shaped nuclei frequencies also were dependent upon duration of exposure. This study indicates that metals at low levels when existing in mixture causes significant geno-cytotoxicity responses and metals bioaccumulation in salmon.

  13. PbTe mechanosynthesis from PbO and Te

    Energy Technology Data Exchange (ETDEWEB)

    Rojas-Chavez, Hugo, E-mail: uu_gg_oo@yahoo.com.m [Centro de Investigacion e Innovacion Tecnologica - IPN, Cerrada de CECATI s/n, Col. Santa Catarina, Del. Azcapotzalco, CP 02250, Mexico D.F (Mexico); Diaz-de la Torre, Sebastian; Jaramillo-Vigueras, David; Plascencia, Gabriel [Centro de Investigacion e Innovacion Tecnologica - IPN, Cerrada de CECATI s/n, Col. Santa Catarina, Del. Azcapotzalco, CP 02250, Mexico D.F (Mexico)

    2009-08-26

    Experimental results concerning the mechanosynthesis (MSY), of PbTe from the PbO-Te powder system, at room temperature an atmospheric conditions are reported. XRD results for samples milled for and after 5.4 ks only show PbTe diffraction peaks; neither Te nor PbO or any other solid phase were detected. Particle size and morphology, was followed by SEM observations. Phase evolution and quantification was monitored by Rietveld refinements of the X-ray diffraction data. It was found that the use of lead oxide as a component of the mechanosynthesis system reduces milling time with respect to the Pb-Te metallic system with mechanical alloying.

  14. Accumulative response of Scots pine (Pinus sylvestris L.) and silver birch (Betula pendula Roth) to heavy metals enhanced by Pb-Zn ore mining and processing plants: Explicitly spatial considerations of ordinary kriging based on a GIS approach.

    Science.gov (United States)

    Pająk, Marek; Halecki, Wiktor; Gąsiorek, Michał

    2017-02-01

    Plants have an accumulative response to heavy metals present in soils or deposited from airborne sources of emissions. Therefore, their tissues are very often used in studies of heavy metal contamination originating from different sources as a bioindicator of environmental pollution. This research was undertaken to examine accumulation capacities of Pb, Zn, Cd, Cu and Cr in washed and unwashed needles of Scots pine (Pinus sylvestris L.) and leaves of silver birch (Betula pendula Roth) growing in a contaminated area. We collected needles of Scots pine and leaves of silver birch in an area around a sedimentation pond and metallurgic plant processing Pb and Zn ores near Olkusz, Poland. Concentrations of heavy metals, which have been linked with exposure to emissions, were determined from foliar samples collected at 33 sites. These sites were established at various distances (0.5-3.6 km) from the pond and metallurgic plant so as to identify the predominant accumulative response of plants. Spatial gradients for Pb and Zn were calculated using an ordinary kriging interpolation algorithm. A spatial pattern was identified by a GIS method to visualize maps over the Pb-Zn ore mining area. The accumulation of Zn (R 2  = 0.74, p < 0.05) and Pb (R 2  = 0.85, p < 0.01) in plant tissues correlated with soil concentrations. This tendency was not found in the case of Cu, Cd and Cr. Copyright © 2016 Elsevier Ltd. All rights reserved.

  15. Design of template-stabilized active and earth-abundant oxygen evolution catalysts in acid† †Electronic supplementary information (ESI) available: CVs for unary metal oxides deposition, electrochemical stability at higher current densities for unary metal oxides at pH 2.5, EDS maps for CoMnOx and CoPbOx, STEM images and PXRD of CoMnOx and CoFePbOx, high-resolution XPS of Fe 2p for CoFePbOx, Pourbaix diagrams (of Mn, Co, Pb, and Fe), and elemental analysis. See DOI: 10.1039/c7sc01239j Click here for additional data file.

    Science.gov (United States)

    Huynh, Michael; Ozel, Tuncay; Liu, Chong; Lau, Eric C.

    2017-01-01

    Oxygen evolution reaction (OER) catalysts that are earth-abundant and are active and stable in acid are unknown. Active catalysts derived from Co and Ni oxides dissolve at low pH, whereas acid stable systems such as Mn oxides (MnOx) display poor OER activity. We now demonstrate a rational approach for the design of earth-abundant catalysts that are stable and active in acid by treating activity and stability as decoupled elements of mixed metal oxides. Manganese serves as a stabilizing structural element for catalytically active Co centers in CoMnOx films. In acidic solutions (pH 2.5), CoMnOx exhibits the OER activity of electrodeposited Co oxide (CoOx) with a Tafel slope of 70–80 mV per decade while also retaining the long-term acid stability of MnOx films for OER at 0.1 mA cm–2. Driving OER at greater current densities in this system is not viable because at high anodic potentials, Mn oxides convert to and dissolve as permanganate. However, by exploiting the decoupled design of the catalyst, the stabilizing structural element may be optimized independently of the Co active sites. By screening potential–pH diagrams, we replaced Mn with Pb to prepare CoFePbOx films that maintained the high OER activity of CoOx at pH 2.5 while exhibiting long-term acid stability at higher current densities (at 1 mA cm–2 for over 50 h at pH 2.0). Under these acidic conditions, CoFePbOx exhibits OER activity that approaches noble metal oxides, thus establishing the viability of decoupling functionality in mixed metal catalysts for designing active, acid-stable, and earth-abundant OER catalysts. PMID:29163926

  16. Study on the application of electrothermal atomization atomic absorption spectrometry for the determination of metallic Cu, Pb, Zn, Cd traces in sea water samples

    International Nuclear Information System (INIS)

    Nguyen Thi Kim Dung; Doan Thanh Son; Tran Thi Ngoc Diep

    2004-01-01

    The trace amount of some heavy metallic elements (Cu, Zn, Pb, Cd) in sea water samples were determined directly (without separation) and quantitatively by using Electro-Thermal Atomization Atomic Absorption Spectrometry (ETA-AAS). The effect of mainly major constituents such as Na, Mg, Ca, K, and the mutual effect of the trace elements, which were present in the matrix on the absorption intensity of each analyzed element was studied. The adding of a certain chemical modification for each trace element was also investigated in order to eliminate the overall effect of the background during the pyrolysis and atomization. The sea water sample after fitrating through a membrane with 0.45 μm-hole size was injected in to the graphite tube via an autosampler (MPE50). The absorption intensity of each element was then measured on the VARIO-6 under the optimum parameters for spectrometer such as: maximum wavelength, current of hollow cathode lamp, and that for graphite furnace such as dry temperature, pyrolysis temperature, atomization temperature, ect. The analytical procedures were set-up and applied for the determination of these above mentioned elements in the synthesized sea water sample and in the real sea water samples with high precision and accuracy. (author)

  17. Lixiviação de metais pesados em solos tratados com lodo de esgoto

    Directory of Open Access Journals (Sweden)

    E. I. Bertoncini

    1999-09-01

    Full Text Available Foi realizado um experimento em tubos de percolação, utilizando-se três solos, classificados como Areia Quartzosa (AQ, Latossolo Vermelho-Amarelo (LV e Latossolo Vermelho-Escuro (LE, aos quais foram incorporadas sucessivas quantidades de lodo de esgoto, totalizando uma dose correspondente a 156,0 t ha-1 (base seca, num período de incubação de 310 dias. Após este período, os solos foram tratados com água ou com soluções de sais (KCl 0,9 mol L-1; KNO3 0,9 mol L-1; K2SO4 0,3 mol L-1 e Ca(NO32 0,3 mol L-1, adicionadas em quantidade correspondente a quatro vezes a capacidade de retenção de água dos solos. No líquido percolado pela passagem das soluções salinas, foram determinadas as quantidades de Cd, Cr, Cu, Ni e Zn presentes e, no percolado obtido com a passagem de água, além dos metais anteriormente citados, foram determinadas também as quantidades de Ca2+ e Mg2+. Os resultados permitiram observar que a adição de KCl provocou o arraste de 5% do Cd adicionado via lodo aos solos LV e LE; para os outros sais utilizados e para a água, esse arraste nunca foi superior a 2% do metal pesado adicionado via lodo. A retenção de Cd, Cu, Cr e Ni aumentou com a elevação dos teores de óxidos de Fe e Al presentes nos solos. Os elevados valores de pH e o aumento no teor de matéria orgânica proporcionado pela adição de lodo refletiram também na menor mobilidade dos metais. Os sais KCl e K2SO4 aumentaram a mobilidade de alguns dos metais estudados.

  18. Application of the 210Pb-dating technique to establish a chronological framework of trace element and heavy metal contamination resulting from the impact of European settlement in estuarine systems of the Sydney Basin, Australia

    International Nuclear Information System (INIS)

    Jenkinson, A.V.; Chisari, R.; Farrar, Y.J.; Heijnis, H.; McOrist, G.D.; Tinker, R.A.; Smith, J.D.; Napoli, M.; Hughes, M.; James, J.M.

    1997-01-01

    The estuaries of Georges River and Hacking River, partly located in suburban Sydney, are at significant risk of contamination by heavy metal and trace element pollutants associated with urban/industrial development. The object of the current work is to correlate changes in land use resulting from European settlement with chemical changes observed in soil sediments. At each location core samples were taken and selected slices analysed for 226 Ra and 210 Po using alpha spectrometry. The 226 Ra activity equates to the supported 210 Pb activity and the 210 Po activity equates to the total 210 Pb activity. The difference between the total and the supported 210 Pb is the excess 210 Pb activity. Once the excess 210 Pb has been layed down in the sediment its activity at depth (assuming the core to be undisturbed) is solely a function of its half-life and the initial amount present; a circumstance which readily affords the calculation of a sedimentation rate. Owing to its relatively short half-life (22.26 year) the 20P b dating technique can be used to date sediments as far back as about 120 years. In Australia this time frame would cover most of the period of European settlement

  19. SYNTHESIS OF POLYEUGENYL OXYACETIC ACID AS A CARRIER TO SEPARATE HEAVY METAL ION Fe (III, Cr(III, Cu(II, Ni(II, Co(II, AND Pb(II THAT USING SOLVENT EXTRACTION METHOD

    Directory of Open Access Journals (Sweden)

    La Harimu

    2010-06-01

    Full Text Available Polyeugenyl oxyacetic acid has been synthesized from polyeugenol and chloroacetic acid and applied to separate metal Fe(III, Cr(III, Cu(II, Ni(II, Co(II, and Pb(II using solvent extraction method. pH effect, polyeugenyl oxyacetic acid ion carrier concentration, extraction time, and metal concentration optimized to gain optimum condition. The result of experiment indicated that polyeugenyl oxyacetic acid resulted the yellowed brown synthesis with melting point 125 °C and yield 68.9%. The Characterization of spectroscopy IR attributed by absorption to the area 1735,8 cm -1 as carbonyl extend vibration (C=O acid and 1H-NMR that was attributed by chemical shift at 4.6 ppm as carboxy proton (CH2-C=0. The metal separation optimum condition gained pH 3-6 for ion Fe(III, pH 5 for ion Cr(III, Ni(II, and Co(II and pH 6 for ion Cu(II, and Pb(II. Optimum carrier concentraction 5 mL, 10 mL, and 15 mL for ion Fe(III, and ion Cr(III, Ni(II, Co(II, and ion Cu(II, Pb(II respectively. Extraction time 2.5 h for ion Fe(III, 20 h for ion Cr(III, and 36 h for ion Cu(II, Pb(II, Ni(II, and Co(II. Metal concentration that would extracted correctly (0.75-5 x 10-4 M for ion Fe(III, (0.75-2.5 x 10-4 M for ion Cr(III, Ni(II, and Co(II and (0.75-1 x 10-4 M for ion Cu(II and Pb(II. The best polyeugenil oxyacetic acid response to separate ion Fe(III than other ions with selectivity order Fe(III> Cr(III> Cu(II> Pb(II> Ni(II> Co(II.   Keywords: polyeugenil oxyacetic acid, pH, extraction time, metal concentraction, solvent extraction

  20. Heavy metal levels (Pb, Cd, Cr and Hg) in the adult general population near an urban solid waste incinerator.

    Science.gov (United States)

    Zubero, Miren Begoña; Aurrekoetxea, Juan José; Ibarluzea, Jesús María; Arenaza, Maria Jesús; Rodríguez, Carlos; Sáenz, José Ramón

    2010-09-15

    In 2005 an urban solid waste incinerator (SWI) was commissioned in Bilbao (Basque Country, Spain). Serum and urine samples were collected from 95 and 107 volunteers in 2006 and 2008 respectively, of which 62 were repeats from the same individuals. Blood lead levels (BPb) were determined, as were the concentrations of cadmium (Cd), chromium (Cr) and mercury (Hg) in urine (UCd, UCr and UHg). The town of Alonsotegi and a borough of Bilba