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Sample records for metal-rich open cluster

  1. THE OLD, SUPER-METAL-RICH OPEN CLUSTER, NGC 6791—ELEMENTAL ABUNDANCES IN TURN-OFF STARS FROM KECK/HIRES SPECTRA

    Energy Technology Data Exchange (ETDEWEB)

    Merchant Boesgaard, Ann; Lum, Michael G. [Institute for Astronomy, University of Hawai' i at Manoa, 2680 Woodlawn Drive, Honolulu, HI 96822 (United States); Deliyannis, Constantine P., E-mail: boes@ifa.hawaii.edu, E-mail: mikelum@ifa.hawaii.edu, E-mail: cdeliyan@indiana.edu [Department of Astronomy, Indiana University 727 East 3rd Street, Swain Hall West 319, Bloomington, IN 47405-7105 (United States)

    2015-02-01

    The study of star clusters has advanced our understanding of stellar evolution, Galactic chemical evolution, and nucleosynthesis. Here we investigate the composition of turn-off stars in the intriguing open cluster, NGC 6791, which is old, but super-metal-rich with high-resolution (R = 46,000) Keck/HIRES spectra. We find [Fe/H] = +0.30 ± 0.02 from measurements of some 40 unblended, unsaturated lines of both Fe I and Fe II in eight turn-off stars. Our O abundances come from the O I triplet near 7774 Å and we perform a differential analysis relative to the Sun from our Lunar spectrum also obtained with Keck/HIRES. The O results are corrected for small nLTE effects. We find consistent ratios of [O/Fe]{sub n} with a mean of –0.06 ± 0.02. This is low with respect to field stars that are also both old and metal-rich and continue the trend of decreasing [O/Fe] with increasing [Fe/H]. The small range in our oxygen abundances is consistent with a single population of stars. Our results for the alpha elements [Mg/Fe], [Si/Fe], [Ca/Fe], and [Ti/Fe] are near solar and compare well with those of the old, metal-rich field stars. The two Fe-peak elements, Cr and Ni, are consistent with Fe. These turn-off-star abundances provide benchmark abundances to investigate whether there are any observable abundance differences with the giants that might arise from nuclear-burning and dredge-up processes. Determinations of upper limits were found for Li by spectrum synthesis and are consistent with the upper limits in similar stars in the relatively old, super-metal-rich cluster NGC 6253. Our results support the prediction from standard theory that higher-metallicity stars deplete more Li. Probably no stars in NGC 6791 have retained their initial Li.

  2. Color-magnitude diagrams for six metal-rich, low-latitude globular clusters

    Science.gov (United States)

    Armandroff, Taft E.

    1988-01-01

    Colors and magnitudes for stars on CCD frames for six metal-rich, low-latitude, previously unstudied globular clusters and one well-studied, metal-rich cluster (47 Tuc) have been derived and color-magnitude diagrams have been constructed. The photometry for stars in 47 Tuc are in good agreement with previous studies, while the V magnitudes of the horizontal-branch stars in the six program clusters do not agree with estimates based on secondary methods. The distances to these clusters are different from prior estimates. Redding values are derived for each program cluster. The horizontal branches of the program clusters all appear to lie entirely redwards of the red edge of the instability strip, as is normal for their metallicities.

  3. New insights into the origin and evolution of the old, metal-rich open cluster NGC 6791

    Science.gov (United States)

    Martinez-Medina, Luis A.; Gieles, Mark; Pichardo, Barbara; Peimbert, Antonio

    2018-02-01

    NGC 6791 is one of the most studied open clusters, it is massive (˜5000 M⊙), located at the solar circle, old (˜8 Gyr) and yet the most metal-rich cluster ([Fe/H] ≃ 0.4) known in the Milky Way. By performing an orbital analysis within a Galactic model including spiral arms and a bar, we found that it is plausible that NGC 6791 formed in the inner thin disc or in the bulge, and later displaced by radial migration to its current orbit. We apply different tools to simulate NGC 6791, including direct N-body summation in time-varying potentials, to test its survivability when going through different Galactic environments. In order to survive the 8-Gyr journey moving on a migrating orbit, NGC 6791 must have been more massive, M0 ≥ 5 × 104 M⊙, when formed. We find independent confirmation of this initial mass in the stellar mass function, which is observed to be flat; this can only be explained if the average tidal field strength experienced by the cluster is stronger than what it is at its current orbit. Therefore, the birth place and journeys of NGC 6791 are imprinted in its chemical composition, in its mass-loss and in its flat stellar mass function, supporting its origin in the inner thin disc or in the bulge.

  4. Properties and origin of the old, metal rich, star cluster, NGC 6791

    OpenAIRE

    Carraro, Giovanni

    2013-01-01

    In this contribution I summarize the unique properties of the old, metal rich, star cluster NGC 6791, with particular emphasis on its population of extreme blue horizontal branch stars. I then conclude providing my personal view on the origin of this fascinating star cluster.

  5. Tracing the Chemical Evolution of Metal-rich Galactic Bulge Globular Clusters

    Science.gov (United States)

    Munoz Gonzalez, Cesar; Saviane, Ivo; Geisler, Doug; Villanova, Sandro

    2018-01-01

    We present in this poster the metallicity characterization of the four metal rich Bulge Galactic Gobular Clusters, which have controversial metallicities. We analyzed our high-resolution spectra (using UVES-580nm and GIRAFFE-HR13 setups) for a large sample of RGB/AGB targets in each cluster in order to measure their metallicity and prove or discard the iron spread hypothesis. We have also characterized chemically stars with potentially different iron content by measuring light (O, Na, Mg, Al), alpha (Si, Ca, Ti), iron–peak (V, Cr, Ni, Mn) and s and r process (Y, Zr, Ba, Eu) elements. We have identified possible channels responsible for the chemical heterogeneity of the cluster populations, like AGB or massive fast-rotating stars contamination, or SN explosion. Also, we have analyzed the origin and evolution of these bulge GCs and their connection with the bulge itself.

  6. Radial velocities and metallicities from infrared Ca ii triplet spectroscopy of open clusters. II. Berkeley 23, King 1, NGC 559, NGC 6603, and NGC 7245

    Science.gov (United States)

    Carrera, R.; Casamiquela, L.; Ospina, N.; Balaguer-Núñez, L.; Jordi, C.; Monteagudo, L.

    2015-06-01

    Context. Open clusters are key to studying the formation and evolution of the Galactic disc. However, there is a deficiency of radial velocity and chemical abundance determinations for open clusters in the literature. Aims: We intend to increase the number of determinations of radial velocities and metallicities from spectroscopy for open clusters. Methods: We acquired medium-resolution spectra (R ~ 8000) in the infrared region Ca ii triplet lines (~8500 Å) for several stars in five open clusters with the long-slit IDS spectrograph on the 2.5 m Isaac Newton Telescope (Roque de los Muchachos Observatory, Spain). Radial velocities were obtained by cross-correlation fitting techniques. The relationships available in the literature between the strength of infrared Ca ii lines and metallicity were also used to derive the metallicity for each cluster. Results: We obtain ⟨Vr⟩ = 48.6 ± 3.4, -58.4 ± 6.8, 26.0 ± 4.3, and -65.3 ± 3.2 km s-1 for Berkeley 23, NGC 559, NGC 6603, and NGC 7245, respectively. We found [ Fe/H ] = -0.25 ± 0.14 and -0.15 ± 0.18 for NGC 559 and NGC 7245, respectively. Berkeley 23 has low metallicity, [ Fe/H ] = -0.42 ± 0.13, which is similar to other open clusters in the outskirts of the Galactic disc. In contrast, we derived high metallicity ([ Fe/H ] = +0.43 ± 0.15) for NGC 6603, which places this system among the most metal-rich known open clusters. To our knowledge, this is the first determination of radial velocities and metallicities from spectroscopy for these clusters, except NGC 6603, for which radial velocities had been previously determined. We have also analysed ten stars in the line of sight to King 1. Because of the large dispersion obtained in both radial velocity and metallicity, we cannot be sure that we have sampled true cluster members. Based on observations made with the 2.5 m Isaac Newton Telescope operated on the island of La Palma by the Isaac Newton Group in the Spanish Observatorio del Roque de los Muchachos of the

  7. VizieR Online Data Catalog: Kinematic study of open clusters (Vande Putte+, 2010)

    Science.gov (United States)

    Vande Putte, D. V.; Garnier, T. P.; Ferreras, I.; Mignani, R. P.; Cropper, M.

    2011-03-01

    The Galactic population of open clusters provides an insight into star formation in the Galaxy. The open cluster catalogue by Dias et al. (Cat. B/ocl) is a rich source of data, including kinematic information. This large sample made it possible to carry out a systematic analysis of 481 open cluster orbits, using parameters based on orbit eccentricity and separation from the Galactic plane. These two parameters may be indicative of origin, and we find them to be correlated. We also find them to be correlated with metallicity, another parameter suggested elsewhere to be a marker for origin in that high values of any of these two parameters generally indicate a low metallicity ([Fe/H]solar<-0.2dex). The resulting analysis points to four open clusters in the catalogue being of extragalactic origin by impact of high-velocity cloud on the disc: Berkeley 21, 32, 99 and Melotte 66, with a possible further four due to this origin (NGC 2158, 2420, 7789 and IC 1311). A further three may be due to Galactic globular cluster impact on the disc, i.e. of internal Galactic origin (NGC 6791, 1817 and 7044). (3 data files).

  8. Ligand combination strategy for the preparation of novel low-dimensional and open-framework metal cluster materials

    Science.gov (United States)

    Anokhina, Ekaterina V.

    Low-dimensional and open-framework materials containing transition metals have a wide range of applications in redox catalysis, solid-state batteries, and electronic and magnetic devices. This dissertation reports on research carried out with the goal to develop a strategy for the preparation of low-dimensional and open-framework materials using octahedral metal clusters as building blocks. Our approach takes its roots from crystal engineering principles where the desired framework topologies are achieved through building block design. The key idea of this work is to induce directional bonding preferences in the cluster units using a combination of ligands with a large difference in charge density. This investigation led to the preparation and characterization of a new family of niobium oxychloride cluster compounds with original structure types exhibiting 1ow-dimensional or open-framework character. Most of these materials have framework topologies unprecedented in compounds containing octahedral clusters. Comparative analysis of their structural features indicates that the novel cluster connectivity patterns in these systems are the result of complex interplay between the effects of anisotropic ligand arrangement in the cluster unit and optimization of ligand-counterion electrostatic interactions. The important role played by these factors sets niobium oxychloride systems apart from cluster compounds with one ligand type or statistical ligand distribution where the main structure-determining factor is the total number of ligands. These results provide a blueprint for expanding the ligand combination strategy to other transition metal cluster systems and for the future rational design of cluster-based materials.

  9. Properties of the open cluster system

    International Nuclear Information System (INIS)

    Janes, K.A.; Tilley, C.; Lynga, G.

    1988-01-01

    A system of weights corresponding to the precision of open cluster data is described. Using these weights, some properties of open clusters can be studied more accurately than was possible earlier. It is clear that there are three types of objects: unbound clusters, bound clusters in the thin disk, and older bound clusters. Galactic gradients of metallicity, longevity, and linear diameter are studied. Distributions at right angles to the galactic plane are discussed in the light of the different cluster types. The clumping of clusters in complexes is studied. An estimate of the selection effects influencing the present material of open cluster data is made in order to evaluate the role played by open clusters in the history of the galactic disk. 58 references

  10. Chemical study of the metal-rich globular cluster NGC 5927

    Science.gov (United States)

    Mura-Guzmán, A.; Villanova, S.; Muñoz, C.; Tang, B.

    2018-03-01

    Globular clusters (GCs) are natural laboratories where stellar and chemical evolution can be studied in detail. In addition, their chemical patterns and kinematics can tell us to which Galactic structure (disc, bulge, halo or extragalactic) the cluster belongs to. NGC 5927 is one of most metal-rich GCs in the Galaxy and its kinematics links it to the thick disc. We present abundance analysis based on high-resolution spectra of seven giant stars. The data were obtained using Fibre Large Array Multi Element Spectrograph/Ultraviolet Echelle Spectrograph (UVES) spectrograph mounted on UT2 telescope of the European Southern Observatory. The principal objective of this work is to perform a wide and detailed chemical abundance analysis of the cluster and look for possible Multiple Populations (MPs). We determined stellar parameters and measured 22 elements corresponding to light (Na, Al), alpha (O, Mg, Si, Ca, Ti), iron-peak (Sc, V, Cr, Mn, Fe, Co, Ni, Cu, Zn), and heavy elements (Y, Zr, Ba, Ce, Nd, Eu). We found a mean iron content of [Fe/H] = -0.47 ± 0.02 (error on the mean). We confirm the existence of MPs in this GC with an O-Na anti-correlation, and moderate spread in Al abundances. We estimate a mean [α/Fe] = 0.25 ± 0.08. Iron-peak elements show no significant spread. The [Ba/Eu] ratios indicate a predominant contribution from SNeII for the formation of the cluster.

  11. THE EFFECT OF SECOND-GENERATION POPULATIONS ON THE INTEGRATED COLORS OF METAL-RICH GLOBULAR CLUSTERS IN EARLY-TYPE GALAXIES

    International Nuclear Information System (INIS)

    Chung, Chul; Lee, Sang-Yoon; Yoon, Suk-Jin; Lee, Young-Wook

    2013-01-01

    The mean color of globular clusters (GCs) in early-type galaxies is in general bluer than the integrated color of halo field stars in host galaxies. Metal-rich GCs often appear more associated with field stars than metal-poor GCs, yet show bluer colors than their host galaxy light. Motivated by the discovery of multiple stellar populations in Milky Way GCs, we present a new scenario in which the presence of second-generation (SG) stars in GCs is responsible for the color discrepancy between metal-rich GCs and field stars. The model assumes that the SG populations have an enhanced helium abundance as evidenced by observations, and it gives a good explanation of the bluer optical colors of metal-rich GCs than field stars as well as strong Balmer lines and blue UV colors of metal-rich GCs. Ours may be complementary to the recent scenario suggesting the difference in stellar mass functions (MFs) as an origin for the GC-to-star color offset. A quantitative comparison is given between the SG and MF models.

  12. Entrapment of metal clusters in metal-organic framework channels by extended hooks anchored at open metal sites.

    Science.gov (United States)

    Zheng, Shou-Tian; Zhao, Xiang; Lau, Samuel; Fuhr, Addis; Feng, Pingyun; Bu, Xianhui

    2013-07-17

    Reported here are the new concept of utilizing open metal sites (OMSs) for architectural pore design and its practical implementation. Specifically, it is shown here that OMSs can be used to run extended hooks (isonicotinates in this work) from the framework walls to the channel centers to effect the capture of single metal ions or clusters, with the concurrent partitioning of the large channel spaces into multiple domains, alteration of the host-guest charge relationship and associated guest-exchange properties, and transfer of OMSs from the walls to the channel centers. The concept of the extended hook, demonstrated here in the multicomponent dual-metal and dual-ligand system, should be generally applicable to a range of framework types.

  13. On the Chemical Abundances of Miras in Clusters: V1 in the Metal-rich Globular NGC 5927

    Science.gov (United States)

    D’Orazi, V.; Magurno, D.; Bono, G.; Matsunaga, N.; Braga, V. F.; Elgueta, S. S.; Fukue, K.; Hamano, S.; Inno, L.; Kobayashi, N.; Kondo, S.; Monelli, M.; Nonino, M.; Przybilla, N.; Sameshima, H.; Saviane, I.; Taniguchi, D.; Thevenin, F.; Urbaneja-Perez, M.; Watase, A.; Arai, A.; Bergemann, M.; Buonanno, R.; Dall’Ora, M.; Da Silva, R.; Fabrizio, M.; Ferraro, I.; Fiorentino, G.; Francois, P.; Gilmozzi, R.; Iannicola, G.; Ikeda, Y.; Jian, M.; Kawakita, H.; Kudritzki, R. P.; Lemasle, B.; Marengo, M.; Marinoni, S.; Martínez-Vázquez, C. E.; Minniti, D.; Neeley, J.; Otsubo, S.; Prieto, J. L.; Proxauf, B.; Romaniello, M.; Sanna, N.; Sneden, C.; Takenaka, K.; Tsujimoto, T.; Valenti, E.; Yasui, C.; Yoshikawa, T.; Zoccali, M.

    2018-03-01

    We present the first spectroscopic abundance determination of iron, α-elements (Si, Ca, and Ti), and sodium for the Mira variable V1 in the metal-rich globular cluster NGC 5927. We use high-resolution (R ∼ 28,000), high signal-to-noise ratio (∼200) spectra collected with WINERED, a near-infrared (NIR) spectrograph covering simultaneously the wavelength range 0.91–1.35 μm. The effective temperature and the surface gravity at the pulsation phase of the spectroscopic observation were estimated using both optical (V) and NIR time-series photometric data. We found that the Mira is metal-rich ([Fe/H] = ‑0.55 ± 0.15) and moderately α-enhanced ([α/Fe] = 0.15 ± 0.01, σ = 0.2). These values agree quite well with the mean cluster abundances based on high-resolution optical spectra of several cluster red giants available in the literature ([Fe/H] = ‑ 0.47 ± 0.06, [α/Fe] = + 0.24 ± 0.05). We also found a Na abundance of +0.35 ± 0.20 that is higher than the mean cluster abundance based on optical spectra (+0.18 ± 0.13). However, the lack of similar spectra for cluster red giants and that of corrections for departures from local thermodynamical equilibrium prevents us from establishing whether the difference is intrinsic or connected with multiple populations. These findings indicate a strong similarity between optical and NIR metallicity scales in spite of the difference in the experimental equipment, data analysis, and in the adopted spectroscopic diagnostics. Based on spectra collected with the WINERED spectrograph available as a visitor instrument at the ESO New Technology Telescope (NTT), La Silla, Chile (ESO Proposal: 098.D-0878(A), PI: G. Bono).

  14. The origin and orbit of the old, metal-rich, open cluster NGC 6791. Insights from kinematics

    Czech Academy of Sciences Publication Activity Database

    Jílková, L.; Carraro, G.; Jungwiert, Bruno; Minchev, I.

    2012-01-01

    Roč. 541, April (2012), A64/1-A64/11 ISSN 0004-6361 R&D Projects: GA MŠk(CZ) LC06014; GA ČR GD205/08/H005 Institutional research plan: CEZ:AV0Z10030501 Keywords : galaxy * kinematics and dynamics * open clusters and associations Subject RIV: BN - Astronomy, Celestial Mechanics, Astrophysics Impact factor: 5.084, year: 2012

  15. An Improved Cluster Richness Estimator

    Energy Technology Data Exchange (ETDEWEB)

    Rozo, Eduardo; /Ohio State U.; Rykoff, Eli S.; /UC, Santa Barbara; Koester, Benjamin P.; /Chicago U. /KICP, Chicago; McKay, Timothy; /Michigan U.; Hao, Jiangang; /Michigan U.; Evrard, August; /Michigan U.; Wechsler, Risa H.; /SLAC; Hansen, Sarah; /Chicago U. /KICP, Chicago; Sheldon, Erin; /New York U.; Johnston, David; /Houston U.; Becker, Matthew R.; /Chicago U. /KICP, Chicago; Annis, James T.; /Fermilab; Bleem, Lindsey; /Chicago U.; Scranton, Ryan; /Pittsburgh U.

    2009-08-03

    Minimizing the scatter between cluster mass and accessible observables is an important goal for cluster cosmology. In this work, we introduce a new matched filter richness estimator, and test its performance using the maxBCG cluster catalog. Our new estimator significantly reduces the variance in the L{sub X}-richness relation, from {sigma}{sub lnL{sub X}}{sup 2} = (0.86 {+-} 0.02){sup 2} to {sigma}{sub lnL{sub X}}{sup 2} = (0.69 {+-} 0.02){sup 2}. Relative to the maxBCG richness estimate, it also removes the strong redshift dependence of the richness scaling relations, and is significantly more robust to photometric and redshift errors. These improvements are largely due to our more sophisticated treatment of galaxy color data. We also demonstrate the scatter in the L{sub X}-richness relation depends on the aperture used to estimate cluster richness, and introduce a novel approach for optimizing said aperture which can be easily generalized to other mass tracers.

  16. THE METALLICITY BIMODALITY OF GLOBULAR CLUSTER SYSTEMS: A TEST OF GALAXY ASSEMBLY AND OF THE EVOLUTION OF THE GALAXY MASS-METALLICITY RELATION

    International Nuclear Information System (INIS)

    Tonini, Chiara

    2013-01-01

    We build a theoretical model to study the origin of the globular cluster metallicity bimodality in the hierarchical galaxy assembly scenario. The model is based on empirical relations such as the galaxy mass-metallicity relation [O/H]-M star as a function of redshift, and on the observed galaxy stellar mass function up to redshift z ∼ 4. We make use of the theoretical merger rates as a function of mass and redshift from the Millennium simulation to build galaxy merger trees. We derive a new galaxy [Fe/H]-M star relation as a function of redshift, and by assuming that globular clusters share the metallicity of their original parent galaxy at the time of their formation, we populate the merger tree with globular clusters. We perform a series of Monte Carlo simulations of the galaxy hierarchical assembly, and study the properties of the final globular cluster population as a function of galaxy mass, assembly and star formation history, and under different assumptions for the evolution of the galaxy mass-metallicity relation. The main results and predictions of the model are the following. (1) The hierarchical clustering scenario naturally predicts a metallicity bimodality in the galaxy globular cluster population, where the metal-rich subpopulation is composed of globular clusters formed in the galaxy main progenitor around redshift z ∼ 2, and the metal-poor subpopulation is composed of clusters accreted from satellites, and formed at redshifts z ∼ 3-4. (2) The model reproduces the observed relations by Peng et al. for the metallicities of the metal-rich and metal-poor globular cluster subpopulations as a function of galaxy mass; the positions of the metal-poor and metal-rich peaks depend exclusively on the evolution of the galaxy mass-metallicity relation and the [O/Fe], both of which can be constrained by this method. In particular, we find that the galaxy [O/Fe] evolves linearly with redshift from a value of ∼0.5 at redshift z ∼ 4 to a value of ∼0.1 at

  17. Dissolved Massive Metal-rich Globular Clusters Can Cause the Range of UV Upturn Strengths Found among Early-type Galaxies

    Science.gov (United States)

    Goudfrooij, Paul

    2018-04-01

    I discuss a scenario in which the ultraviolet (UV) upturn of giant early-type galaxies (ETGs) is primarily due to helium-rich stellar populations that formed in massive metal-rich globular clusters (GCs), which subsequently dissolved in the strong tidal field in the central regions of the massive host galaxy. These massive GCs are assumed to show UV upturns similar to those observed recently in M87, the central giant elliptical galaxy in the Virgo cluster of galaxies. Data taken from the literature reveal a strong correlation between the strength of the UV upturn and the specific frequency of metal-rich GCs in ETGs. Adopting a Schechter function parameterization of GC mass functions, simulations of long-term dynamical evolution of GC systems show that the observed correlation between UV upturn strength and GC specific frequency can be explained by variations in the characteristic truncation mass {{ \\mathcal M }}{{c}} such that {{ \\mathcal M }}{{c}} increases with ETG luminosity in a way that is consistent with observed GC luminosity functions in ETGs. These findings suggest that the nature of the UV upturn in ETGs and the variation of its strength among ETGs are causally related to that of helium-rich populations in massive GCs, rather than intrinsic properties of field stars in massive galactic spheroids. With this in mind, I predict that future studies will find that [N/Fe] decreases with increasing galactocentric radius in massive ETGs, and that such gradients have the largest amplitudes in ETGs with the strongest UV upturns.

  18. Asteroseismic inferences on red giants in open clusters NGC 6791, NGC 6819, and NGC 6811 using Kepler

    DEFF Research Database (Denmark)

    Hekker, S.; Basu, S.; Stello, D.

    2011-01-01

    and metallicity contribute to the observed difference in locations in the H-R diagram of the old metal-rich cluster NGC 6791 and the middle-aged solar-metallicity cluster NGC 6819. For the young cluster NGC 6811, the explanation of the position of the stars in the H-R diagram challenges the assumption of solar...

  19. Near infrared photometry of globular clusters

    International Nuclear Information System (INIS)

    Evans, T.L.; Menzies, J.W.

    1977-01-01

    Photographic photometry on the V, Isub(K) system has been obtained for giant stars in the metal-rich globular clusters NGC 5927, 6171, 6352, 6356, 6388, 6522, 6528, 6712 and 6723. Colour-magnitude diagrams are presented. These data, with earlier observations of NGC 104 (47 Tuc), yield new parameters to describe the giant branch. These are the colour of the red variables, represented by their mean colour (V - Isub(K)) 0 or by the colour (V - Isub(K))sub(BO) of the bluest red variable on the giant branch of a cluster, and ΔV' which is the magnitude difference between the horizontal branch and the highest point on the giant branch. The latter is independent of reddening, since the giant branch of the most metal-rich clusters passes through a maximum in the V, V - Isub(K) plane. These parameters are correlated with the metal content, deduced from integrated photometry: the red variables are redder and the giant branch fainter the higher the metal content. Comparison with theoretical evolutionary tracks suggests that the range in metal content of these clusters is at most a factor of 10, the most metal-rich clusters possibly approaching the solar value. The cluster giant branches and those of open clusters, groups and field stars of the old disk population are compared. The assumption that all the globular clusters have an absolute magnitude on the horizontal branch of Msub(v) = + 0.9, as found recently for 47 Tuc, gives good agreement between the magnitudes of giant stars in the most metal rich of the globular clusters and those of field stars deduced from statistical parallaxes and moving group parallaxes. The values of the parameters ΔV' and (V - Isub(k))sub(BO) also approach those in the moving groups. The globular clusters have a longer horizontal branch, however, and the subgiants are bluer even when the values of ) 7Fe/H{ appear to be the same. (author). )

  20. Metal cluster compounds - chemistry and importance; clusters containing isolated main group element atoms, large metal cluster compounds, cluster fluxionality

    International Nuclear Information System (INIS)

    Walther, B.

    1988-01-01

    This part of the review on metal cluster compounds deals with clusters containing isolated main group element atoms, with high nuclearity clusters and metal cluster fluxionality. It will be obvious that main group element atoms strongly influence the geometry, stability and reactivity of the clusters. High nuclearity clusters are of interest in there own due to the diversity of the structures adopted, but their intermediate position between molecules and the metallic state makes them a fascinating research object too. These both sites of the metal cluster chemistry as well as the frequently observed ligand and core fluxionality are related to the cluster metal and surface analogy. (author)

  1. FURTHER DEFINITION OF THE MASS-METALLICITY RELATION IN GLOBULAR CLUSTER SYSTEMS AROUND BRIGHTEST CLUSTER GALAXIES

    International Nuclear Information System (INIS)

    Cockcroft, Robert; Harris, William E.; Wehner, Elizabeth M. H.; Whitmore, Bradley C.; Rothberg, Barry

    2009-01-01

    We combine the globular cluster (GC) data for 15 brightest cluster galaxies and use this material to trace the mass-metallicity relations (MMRs) in their globular cluster systems (GCSs). This work extends previous studies which correlate the properties of the MMR with those of the host galaxy. Our combined data sets show a mean trend for the metal-poor subpopulation that corresponds to a scaling of heavy-element abundance with cluster mass Z ∼ M 0.30±0.05 . No trend is seen for the metal-rich subpopulation which has a scaling relation that is consistent with zero. We also find that the scaling exponent is independent of the GCS specific frequency and host galaxy luminosity, except perhaps for dwarf galaxies. We present new photometry in (g',i') obtained with Gemini/GMOS for the GC populations around the southern giant ellipticals NGC 5193 and IC 4329. Both galaxies have rich cluster populations which show up as normal, bimodal sequences in the color-magnitude diagram. We test the observed MMRs and argue that they are statistically real, and not an artifact caused by the method we used. We also argue against asymmetric contamination causing the observed MMR as our mean results are no different from other contamination-free studies. Finally, we compare our method to the standard bimodal fitting method (KMM or RMIX) and find our results are consistent. Interpretation of these results is consistent with recent models for GC formation in which the MMR is determined by GC self-enrichment during their brief formation period.

  2. Open cluster Dolidze 25: Stellar parameters and the metallicity in the Galactic anticentre

    Science.gov (United States)

    Negueruela, I.; Simón-Díaz, S.; Lorenzo, J.; Castro, N.; Herrero, A.

    2015-12-01

    Context. The young open cluster Dolidze 25, in the direction of the Galactic anticentre, has been attributed a very low metallicity, with typical abundances between -0.5 and -0.7 dex below solar. Aims: We intend to derive accurate cluster parameters and accurate stellar abundances for some of its members. Methods: We have obtained a large sample of intermediate- and high-resolution spectra for stars in and around Dolidze 25. We used the fastwind code to generate stellar atmosphere models to fit the observed spectra. We derive stellar parameters for a large number of OB stars in the area, and abundances of oxygen and silicon for a number of stars with spectral types around B0. Results: We measure low abundances in stars of Dolidze 25. For the three stars with spectral types around B0, we find 0.3 dex (Si) and 0.5 dex (O) below the values typical in the solar neighbourhood. These values, even though not as low as those given previously, confirm Dolidze 25 and the surrounding H ii region Sh2-284 as the most metal-poor star-forming environment known in the Milky Way. We derive a distance 4.5 ± 0.3 kpc to the cluster (rG ≈ 12.3 kpc). The cluster cannot be older than ~3 Myr, and likely is not much younger. One star in its immediate vicinity, sharing the same distance, has Si and O abundances at most 0.15 dex below solar. Conclusions: The low abundances measured in Dolidze 25 are compatible with currently accepted values for the slope of the Galactic metallicity gradient, if we take into account that variations of at least ±0.15 dex are observed at a given radius. The area traditionally identified as Dolidze 25 is only a small part of a much larger star-forming region that comprises the whole dust shell associated with Sh2-284 and very likely several other smaller H ii regions in its vicinity. Based on observations made with the Nordic Optical Telescope, the Mercator Telescope, and the telescopes of the Isaac Newton Group.

  3. LITHIUM-RICH GIANTS IN GLOBULAR CLUSTERS

    Energy Technology Data Exchange (ETDEWEB)

    Kirby, Evan N.; Cohen, Judith G. [California Institute of Technology, 1200 E. California Boulevard, MC 249-17, Pasadena, CA 91125 (United States); Guhathakurta, Puragra [UCO/Lick Observatory and Department of Astronomy and Astrophysics, University of California, 1156 High Street, Santa Cruz, CA 95064 (United States); Zhang, Andrew J. [The Harker School, 500 Saratoga Avenue, San Jose, CA 95129 (United States); Hong, Jerry [Palo Alto High School, 50 Embarcadero Road, Palo Alto, CA, 94301 (United States); Guo, Michelle [Stanford University, 450 Serra Mall, Stanford, CA 94305 (United States); Guo, Rachel [Irvington High School, 41800 Blacow Road, Fremont, CA 94538 (United States); Cunha, Katia [Observatório Nacional, São Cristóvão Rio de Janeiro (Brazil)

    2016-03-10

    Although red giants deplete lithium on their surfaces, some giants are Li-rich. Intermediate-mass asymptotic giant branch (AGB) stars can generate Li through the Cameron–Fowler conveyor, but the existence of Li-rich, low-mass red giant branch (RGB) stars is puzzling. Globular clusters are the best sites to examine this phenomenon because it is straightforward to determine membership in the cluster and to identify the evolutionary state of each star. In 72 hours of Keck/DEIMOS exposures in 25 clusters, we found four Li-rich RGB and two Li-rich AGB stars. There were 1696 RGB and 125 AGB stars with measurements or upper limits consistent with normal abundances of Li. Hence, the frequency of Li-richness in globular clusters is (0.2 ± 0.1)% for the RGB, (1.6 ± 1.1)% for the AGB, and (0.3 ± 0.1)% for all giants. Because the Li-rich RGB stars are on the lower RGB, Li self-generation mechanisms proposed to occur at the luminosity function bump or He core flash cannot explain these four lower RGB stars. We propose the following origin for Li enrichment: (1) All luminous giants experience a brief phase of Li enrichment at the He core flash. (2) All post-RGB stars with binary companions on the lower RGB will engage in mass transfer. This scenario predicts that 0.1% of lower RGB stars will appear Li-rich due to mass transfer from a recently Li-enhanced companion. This frequency is at the lower end of our confidence interval.

  4. N-Heterocyclic Carbene Coinage Metal Complexes of the Germanium-Rich Metalloid Clusters [Ge9R3]− and [Ge9RI2]2− with R = Si(iPr3 and RI = Si(TMS3

    Directory of Open Access Journals (Sweden)

    Felix S. Geitner

    2017-07-01

    Full Text Available We report on the synthesis of novel coinage metal NHC (N-heterocyclic carbene compounds of the germanium-rich metalloid clusters [Ge9R3]− and [Ge9RI2]2− with R = Si(iPr3 and RI = Si(TMS3. NHCDippCu{η3Ge9R3} with R = Si(iPr3 (1 represents a less bulky silyl group-substituted derivative of the known analogous compounds with R = Si(iBu3 or Si(TMS3. The coordination of the [NHCDippCu]+ moiety to the cluster unit occurs via one triangular face of the tri-capped trigonal prismatic [Ge9] cluster. Furthermore, a series of novel Zintl cluster coinage metal NHC compounds of the type (NHCM2{η3Ge9RI2} (RI = Si(TMS3 M = Cu, Ag and Au; NHC = NHCDipp or NHCMes is presented. These novel compounds represent a new class of neutral dinuclear Zintl cluster coinage metal NHC compounds, which are obtained either by the stepwise reaction of a suspension of K12Ge17 with Si(TMS3Cl and the coinage metal carbene complexes NHCMCl (M = Cu, Ag, Au, or via a homogenous reaction using the preformed bis-silylated cluster K2[Ge9(Si(TMS32] and the corresponding NHCMCl (M = Cu, Ag, Au complex. The molecular structures of NHCDippCu{η3Ge9(Si(iPr33} (1 and (NHCDippCu2{η3-Ge9(Si(TMS32} (2 were determined by single crystal X-ray diffraction methods. In 2, the coordination of the [NHCDippCu]+ moieties to the cluster unit takes place via both open triangular faces of the [Ge9] entity. Furthermore, all compounds were characterized by means of NMR spectroscopy (1H, 13C, 29Si and ESI-MS.

  5. TIME-SERIES PHOTOMETRY OF GLOBULAR CLUSTERS: M62 (NGC 6266), THE MOST RR LYRAE-RICH GLOBULAR CLUSTER IN THE GALAXY?

    International Nuclear Information System (INIS)

    Contreras, R.; Catelan, M.; Smith, H. A.; Kuehn, C. A.; Pritzl, B. J.; Borissova, J.

    2010-01-01

    We present new time-series CCD photometry, in the B and V bands, for the moderately metal-rich ([Fe/H] ≅ -1.3) Galactic globular cluster M62 (NGC 6266). The present data set is the largest obtained so far for this cluster and consists of 168 images per filter, obtained with the Warsaw 1.3 m telescope at the Las Campanas Observatory and the 1.3 m telescope of the Cerro Tololo Inter-American Observatory, in two separate runs over the time span of 3 months. The procedure adopted to detect the variable stars was the optimal image subtraction method (ISIS v2.2), as implemented by Alard. The photometry was performed using both ISIS and Stetson's DAOPHOT/ALLFRAME package. We have identified 245 variable stars in the cluster fields that have been analyzed so far, of which 179 are new discoveries. Of these variables, 133 are fundamental mode RR Lyrae stars (RRab), 76 are first overtone (RRc) pulsators, 4 are type II Cepheids, 25 are long-period variables (LPVs), 1 is an eclipsing binary, and 6 are not yet well classified. Such a large number of RR Lyrae stars places M62 among the top two most RR Lyrae-rich (in the sense of total number of RR Lyrae stars present) globular clusters known in the Galaxy, second only to M3 (NGC 5272) with a total of 230 known RR Lyrae stars. Since this study covers most but not all of the cluster area, it is not unlikely that M62 is in fact the most RR Lyrae-rich globular cluster in the Galaxy. In like vein, thanks to the time coverage of our data sets, we were also able to detect the largest sample of LPVs known so far in a Galactic globular cluster. We analyze a variety of Oosterhoff type indicators for the cluster, including mean periods, period distribution, Bailey diagrams, and Fourier decomposition parameters (as well as the physical parameters derived therefrom). All of these indicators clearly show that M62 is an Oosterhoff type I system. This is in good agreement with the moderately high metallicity of the cluster, in spite of its

  6. ELEMENTAL ABUNDANCE RATIOS IN STARS OF THE OUTER GALACTIC DISK. IV. A NEW SAMPLE OF OPEN CLUSTERS

    International Nuclear Information System (INIS)

    Yong, David; Carney, Bruce W.; Friel, Eileen D.

    2012-01-01

    We present radial velocities and chemical abundances for nine stars in the old, distant open clusters Be18, Be21, Be22, Be32, and PWM4. For Be18 and PWM4, these are the first chemical abundance measurements. Combining our data with literature results produces a compilation of some 68 chemical abundance measurements in 49 unique clusters. For this combined sample, we study the chemical abundances of open clusters as a function of distance, age, and metallicity. We confirm that the metallicity gradient in the outer disk is flatter than the gradient in the vicinity of the solar neighborhood. We also confirm that the open clusters in the outer disk are metal-poor with enhancements in the ratios [α/Fe] and perhaps [Eu/Fe]. All elements show negligible or small trends between [X/Fe] and distance ( –1 ), but for some elements, there is a hint that the local (R GC GC > 13 kpc) samples may have different trends with distance. There is no evidence for significant abundance trends versus age ( –1 ). We measure the linear relation between [X/Fe] and metallicity, [Fe/H], and find that the scatter about the mean trend is comparable to the measurement uncertainties. Comparison with solar neighborhood field giants shows that the open clusters share similar abundance ratios [X/Fe] at a given metallicity. While the flattening of the metallicity gradient and enhanced [α/Fe] ratios in the outer disk suggest a chemical enrichment history different from that of the solar neighborhood, we echo the sentiments expressed by Friel et al. that definitive conclusions await homogeneous analyses of larger samples of stars in larger numbers of clusters. Arguably, our understanding of the evolution of the outer disk from open clusters is currently limited by systematic abundance differences between various studies.

  7. Variable stars in metal-rich globular clusters. IV. Long-period variables in NGC 6496

    Energy Technology Data Exchange (ETDEWEB)

    Abbas, Mohamad A. [Astronomisches Rechen-Institut, Zentrum für Astronomie der Universität Heidelberg, Mönchhofstr. 12-14, D-69120 Heidelberg (Germany); Layden, Andrew C.; Guldenschuh, Katherine A. [Physics and Astronomy Department, Bowling Green State University, Bowling Green, OH 43403 (United States); Reichart, D. E.; Ivarsen, K. M.; Haislip, J. B.; Nysewander, M. C.; LaCluyze, A. P. [Department of Physics and Astronomy, University of North Carolina, Chapel Hill, NC 27599 (United States); Welch, Douglas L., E-mail: mabbas@ari.uni-heidelberg.de, E-mail: laydena@bgsu.edu [Department of Physics and Astronomy, McMaster University, Hamilton, Ontario, L8 S 4M1 (Canada)

    2015-02-01

    We present VI-band photometry for stars in the metal-rich globular cluster NGC 6496. Our time-series data were cadenced to search for long-period variables (LPVs) over a span of nearly two years, and our variability search yielded the discovery of 13 new variable stars, of which 6 are LPVs, 2 are suspected LPVs, and 5 are short-period eclipsing binaries. An additional star was found in the ASAS database, and we clarify its type and period. We argue that all of the eclipsing binaries are field stars, while five to six of the LPVs are members of NGC 6496. We compare the period–luminosity distribution of these LPVs with those of LPVs in the Large Magellanic Cloud and 47 Tucanae, and with theoretical pulsation models. We also present a VI color–magnitude diagram, display the evolutionary states of the variables, and match isochrones to determine a reddening of E(B−V)= 0.21±0.02 mag and apparent distance modulus of 15.60±0.15 mag.

  8. OPEN CLUSTERS IN THE MILKY WAY OUTER DISK: NEWLY DISCOVERED AND UNSTUDIED CLUSTERS IN THE SPITZER GLIMPSE-360, CYG-X, AND SMOG SURVEYS

    International Nuclear Information System (INIS)

    Zasowski, G.; Beaton, R. L.; Hamm, K. K.; Majewski, S. R.; Patterson, R. J.; Babler, B.; Churchwell, E.; Meade, M.; Whitney, B. A.; Benjamin, R. A.; Watson, C.

    2013-01-01

    Open stellar clusters are extremely valuable probes of Galactic structure, star formation, kinematics, and chemical abundance patterns. Near-infrared (NIR) data have enabled the detection of hundreds of clusters hidden from optical surveys, and mid-infrared (MIR) data are poised to offer an even clearer view into the most heavily obscured parts of the Milky Way. We use new MIR images from the Spitzer GLIMPSE-360, Cyg-X, and SMOG surveys to visually identify a large number of open cluster candidates in the outer disk of the Milky Way (65° < l < 265°). Using NIR color-magnitude diagrams, stellar isochrones, and stellar reddening estimates, we derive cluster parameters (metallicity, distance, reddening) for those objects without previous identification and/or parameters in the literature. In total, we present coordinates and sizes of 20 previously unknown open cluster candidates; for 7 of these we also present metallicity, distance, and reddening values. In addition, we provide the first estimates of these values for nine clusters that had been previously cataloged. We compare our cluster sizes and other derived parameters to those in the open cluster catalog of Dias et al. and find strong similarities except for a higher mean reddening for our objects, which signifies our increased detection sensitivity in regions of high extinction. The results of this cluster search and analysis demonstrate the ability of MIR imaging and photometry to augment significantly the current census of open clusters in the Galaxy

  9. IMPROVEMENT OF THE RICHNESS ESTIMATES OF maxBCG CLUSTERS

    International Nuclear Information System (INIS)

    Rozo, Eduardo; Rykoff, Eli S.; Koester, Benjamin P.; Hansen, Sarah; Becker, Matthew; Bleem, Lindsey; McKay, Timothy; Hao Jiangang; Evrard, August; Wechsler, Risa H.; Sheldon, Erin; Johnston, David; Annis, James; Scranton, Ryan

    2009-01-01

    Minimizing the scatter between cluster mass and accessible observables is an important goal for cluster cosmology. In this work, we introduce a new matched filter richness estimator, and test its performance using the maxBCG cluster catalog. Our new estimator significantly reduces the variance in the L X -richness relation, from σ lnLx 2 = (0.86±0.02) 2 to σ lnLx 2 = (0.69±0.02) 2 . Relative to the maxBCG richness estimate, it also removes the strong redshift dependence of the L X -richness scaling relations, and is significantly more robust to photometric and redshift errors. These improvements are largely due to the better treatment of galaxy color data. We also demonstrate the scatter in the L X -richness relation depends on the aperture used to estimate cluster richness, and introduce a novel approach for optimizing said aperture which can easily be generalized to other mass tracers.

  10. Bad metal behaviour in the new Hg-rich amalgam KHg{sub 6} with polar metallic bonding

    Energy Technology Data Exchange (ETDEWEB)

    Tambornino, Frank; Hoch, Constantin, E-mail: constantin.hoch@cup.uni-muenchen.de

    2015-01-05

    Highlights: • The novel Hg-rich amalgam KHg{sub 6} was synthesised by electrocrystallisation. • The structure was investigated by single crystal and powder diffraction. • Thermal decomposition, electric resistance and magnetic susceptibiliy were examined. • Band structure, total and partial density of states and Bader charges were calculated. • Bad metal behaviour results from ionic, metallic and covalent bonding contributions. - Abstract: The new mercury-rich amalgam KHg{sub 6} crystallises with the BaHg{sub 6} structure type (orthorhombic, space group Pnma (No. 62), a = 13.394(9) Å, b = 5.270(3) Å, c = 10.463 Å). It was prepared by electrolysis of a solution of KI in N,N′-Dimethylformamide at 343 K at a reactive Hg cathode. The structure of KHg{sub 6} shows motifs of ionic packing, covalent Hg cluster formation and metallic properties. KHg{sub 6} decomposes peritectically at 443 K. The combination of alkali metals with a noble metal with moderate electron affinity results in the formation of polar metal–metal bonding with considerable but incomplete electron transfer from the electropositive to the electronegative sublattice, resulting in typical “bad metal behaviour”, illustrated by resistance and susceptibility measurements and quantum theoretical calculations.

  11. Electronic structure of metal clusters

    International Nuclear Information System (INIS)

    Wertheim, G.K.

    1989-01-01

    Photoemission spectra of valence electrons in metal clusters, together with threshold ionization potential measurements, provide a coherent picture of the development of the electronic structure from the isolated atom to the large metallic cluster. An insulator-metal transition occurs at an intermediate cluster size, which serves to define the boundary between small and large clusters. Although the outer electrons may be delocalized over the entire cluster, a small cluster remains insulating until the density of states near the Fermi level exceeds 1/kT. In large clusters, with increasing cluster size, the band structure approaches that of the bulk metal. However, the bands remain significantly narrowed even in a 1000-atom cluster, giving an indication of the importance of long-range order. The core-electron binding-energy shifts of supported metal clusters depend on changes in the band structure in the initial state, as well as on various final-state effects, including changes in core hole screening and the coulomb energy of the final-state charge. For cluster supported on amorphous carbon, this macroscopic coulomb shift is often dominant, as evidenced by the parallel shifts of the core-electron binding energy and the Fermi edge. Auger data confirm that final-state effects dominate in cluster of Sn and some other metals. Surface atom core-level shifts provide a valuable guide to the contributions of initial-state changes in band structure to cluster core-electron binding energy shifts, especially for Au and Pt. The available data indicate that the shift observed in supported, metallic clusters arise largely from the charge left on the cluster by photoemission. As the metal-insulator transition is approached from above, metallic screening is suppressed and the shift is determined by the local environment. (orig.)

  12. Asteroseismology of old open clusters with Kepler: direct estimate of the integrated red giant branch mass-loss in NGC 6791 and 6819

    DEFF Research Database (Denmark)

    Miglio, A.; Brogaard, Karsten Frank; Stello, D.

    2012-01-01

    Mass-loss of red giant branch (RGB) stars is still poorly determined, despite its crucial role in the chemical enrichment of galaxies. Thanks to the recent detection of solar-like oscillations in G–K giants in open clusters with Kepler, we can now directly determine stellar masses...... for a statistically significant sample of stars in the old open clusters NGC 6791 and 6819. The aim of this work is to constrain the integrated RGB mass-loss by comparing the average mass of stars in the red clump (RC) with that of stars in the low-luminosity portion of the RGB [i.e. stars with L≲L(RC)]. Stellar...... masses were determined by combining the available seismic parameters νmax and Δν with additional photometric constraints and with independent distance estimates. We measured the masses of 40 stars on the RGB and 19 in the RC of the old metal-rich cluster NGC 6791. We find that the difference between...

  13. A CCD photometric analysis of the old open cluster NGC 2420

    International Nuclear Information System (INIS)

    Anthony-Twarog, B.J.; Twarog, B.A.; Kaluzny, J.; Shara, M.M.

    1990-01-01

    Precision CCD photometry on the BV system of the core of the old open cluster NGC 2420 is analyzed to explore the value of such an approach for open clusters, particularly in the areas of Galactic and stellar evolution. The unevolved main sequence is shown to be narrow and well defined to the completeness limit of V = 18.5, and the distribution of stars away from the main sequence is shown to be bimodal, with a secondary peak located approximately 0.7 mag above the fiducial main sequence. It is estimated that 50 percent of the cluster systems are binary. Near the turnoff the cluster exhibits some detailed structure. Fiducial relations are given for the cluster extending from the lower main sequence to the red giant branch 1.5 mag above the clump. Comparisons are made between the NGC 2420 cluster and NGC 2506, the isochrones of VandenBerg (1985), and 47 Tuc, in order to estimate cluster parameters, including reddening and metallicity. 68 refs

  14. Hubble Space Telescope-NICMOS Observations of M31'S Metal-Rich Globular Clusters and Their Surrounding Fields. I. Techniques

    Science.gov (United States)

    Stephens, Andrew W.; Frogel, Jay A.; Freedman, Wendy; Gallart, Carme; Jablonka, Pascale; Ortolani, Sergio; Renzini, Alvio; Rich, R. Michael; Davies, Roger

    2001-05-01

    Astronomers are always anxious to push their observations to the limit-basing results on objects at the detection threshold, spectral features barely stronger than the noise, or photometry in very crowded regions. In this paper we present a careful analysis of photometry in crowded regions and show how image blending affects the results and interpretation of such data. Although this analysis is specifically for our NICMOS observations in M31, the techniques we develop can be applied to any imaging data taken in crowded fields; we show how the effects of image blending will limit even the Next Generation Space Telescope. We have obtained HST-NICMOS observations of five of M31's most metal-rich globular clusters. These data allow photometry of individual stars in the clusters and their surrounding fields. However, to achieve our goals-obtain accurate luminosity functions to compare with their Galactic counterparts, determine metallicities from the slope of the giant branch, identify long-period variables, and estimate ages from the AGB tip luminosity-we must be able to disentangle the true properties of the population from the observational effects associated with measurements made in very crowded fields. We thus use three different techniques to analyze the effects of crowding on our data, including the insertion of artificial stars (traditional completeness tests) and the creation of completely artificial clusters. These computer simulations are used to derive threshold- and critical-blending radii for each cluster, which determine how close to the cluster center reliable photometry can be achieved. The simulations also allow us to quantify and correct for the effects of blending on the slope and width of the RGB at different surface brightness levels. We then use these results to estimate the limits blending will place on future space-based observations. Based on observations with the NASA/ESA Hubble Space Telescope obtained at the Space Telescope Science

  15. Migration in the shearing sheet and estimates for young open cluster migration

    Science.gov (United States)

    Quillen, Alice C.; Nolting, Eric; Minchev, Ivan; De Silva, Gayandhi; Chiappini, Cristina

    2018-04-01

    Using tracer particles embedded in self-gravitating shearing sheet N-body simulations, we investigate the distance in guiding centre radius that stars or star clusters can migrate in a few orbital periods. The standard deviations of guiding centre distributions and maximum migration distances depend on the Toomre or critical wavelength and the contrast in mass surface density caused by spiral structure. Comparison between our simulations and estimated guiding radii for a few young supersolar metallicity open clusters, including NGC 6583, suggests that the contrast in mass surface density in the solar neighbourhood has standard deviation (in the surface density distribution) divided by mean of about 1/4 and larger than measured using COBE data by Drimmel and Spergel. Our estimate is consistent with a standard deviation of ˜0.07 dex in the metallicities measured from high-quality spectroscopic data for 38 young open clusters (<1 Gyr) with mean galactocentric radius 7-9 kpc.

  16. Structure and Mobility of Metal Clusters in MOFs: Au, Pd, and AuPd Clusters in MOF-74

    DEFF Research Database (Denmark)

    Vilhelmsen, Lasse; Walton, Krista S.; Sholl, David S.

    2012-01-01

    is just as important for nanocluster adsorption as open Zn or Mg metal sites. Using the large number of clusters generated by the GA, we developed a systematic method for predicting the mobility of adsorbed clusters. Through the investigation of diffusion paths a relationship between the cluster......Understanding the adsorption and mobility of metal–organic framework (MOF)-supported metal nanoclusters is critical to the development of these catalytic materials. We present the first theoretical investigation of Au-, Pd-, and AuPd-supported clusters in a MOF, namely MOF-74. We combine density...... functional theory (DFT) calculations with a genetic algorithm (GA) to reliably predict the structure of the adsorbed clusters. This approach allows comparison of hundreds of adsorbed configurations for each cluster. From the investigation of Au8, Pd8, and Au4Pd4 we find that the organic part of the MOF...

  17. Eclipsing binaries in open clusters

    DEFF Research Database (Denmark)

    Southworth, John; Clausen, J.V.

    2006-01-01

    Stars: fundamental parameters - Stars : binaries : eclipsing - Stars: Binaries: spectroscopic - Open clusters and ass. : general Udgivelsesdato: 5 August......Stars: fundamental parameters - Stars : binaries : eclipsing - Stars: Binaries: spectroscopic - Open clusters and ass. : general Udgivelsesdato: 5 August...

  18. Extrinsic Sources of Scatter in the Richness-Mass Relation of Galaxy Clusters

    Energy Technology Data Exchange (ETDEWEB)

    Rozo, Eduardo; /Chicago U. /Chicago U., KICP; Rykoff, Eli; /LBL, Berkeley; Koester, Benjamin; /Chicago U., Astron. Astrophys. Ctr.; Nord, Brian; /Michigan U.; Wu, Hao-Yi; /KIPAC, Menlo Park /Stanford U., Phys. Dept.; Evrard, August; /Michigan U.; Wechsler, Risa; /KIPAC, Menlo Park /Stanford U., Phys. Dept.

    2012-03-27

    Maximizing the utility of upcoming photometric cluster surveys requires a thorough understanding of the richness-mass relation of galaxy clusters. We use Monte Carlo simulations to study the impact of various sources of observational scatter on this relation. Cluster ellipticity, photometric errors, photometric redshift errors, and cluster-to-cluster variations in the properties of red-sequence galaxies contribute negligible noise. Miscentering, however, can be important, and likely contributes to the scatter in the richness - mass relation of galaxy maxBCG clusters at the low mass end, where centering is more difficult. We also investigate the impact of projection effects under several empirically motivated assumptions about cluster environments. Using SDSS data and the maxBCG cluster catalog, we demonstrate that variations in cluster environments can rarely ({approx} 1%-5% of the time) result in significant richness boosts. Due to the steepness of the mass/richness function, the corresponding fraction of optically selected clusters that suffer from these projection effects is {approx} 5%-15%. We expect these numbers to be generic in magnitude, but a precise determination requires detailed, survey-specific modeling.

  19. EXTRINSIC SOURCES OF SCATTER IN THE RICHNESS-MASS RELATION OF GALAXY CLUSTERS

    International Nuclear Information System (INIS)

    Rozo, Eduardo; Koester, Benjamin; Rykoff, Eli; Nord, Brian; Evrard, August; Wu Haoyi; Wechsler, Risa

    2011-01-01

    Maximizing the utility of upcoming photometric cluster surveys requires a thorough understanding of the richness-mass relation of galaxy clusters. We use Monte Carlo simulations to study the impact of various sources of observational scatter on this relation. Cluster ellipticity, photometric errors, photometric redshift errors, and cluster-to-cluster variations in the properties of red-sequence galaxies contribute negligible noise. Miscentering, however, can be important, and likely contributes to the scatter in the richness-mass relation of galaxy maxBCG clusters at the low-mass end, where centering is more difficult. We also investigate the impact of projection effects under several empirically motivated assumptions about cluster environments. Using Sloan Digital Sky Survey data and the maxBCG cluster catalog, we demonstrate that variations in cluster environments can rarely (∼1%-5% of the time) result in significant richness boosts. Due to the steepness of the mass/richness function, the corresponding fraction of optically selected clusters that suffer from these projection effects is ∼5%-15%. We expect these numbers to be generic in magnitude, but a precise determination requires detailed, survey-specific modeling.

  20. Open Cluster Dynamics via Fundamental Plane

    Science.gov (United States)

    Lin, Chien-Cheng; Pang, Xiao-Ying

    2018-04-01

    Open clusters (OCs) are important objects for stellar dynamics studies. The short survival timescale of OCs makes them closely related to the formation of Galactic field stars. We motivate to investigate the dynamical evolution of OCs on the aspect of internal effect and the external influence. Firstly, we make use of the known OC catalog to obtain OCs masses, effective radii. Additionally, we estimate OCs kinematics properties by OC members cross-matched with radial velocity and metallicity from SDSSIV/APOGEE2. We then establish the fundamental plane of OCs based on the radial velocity dispersion, the effective radius, and average surface brightness. The deviation of the fundamental plane from the Virial Plane, so called the tilt, and the r.m.s. dispersion of OCs around the average plane are used to indicate the dynamical status of OCs. Parameters of the fitted plane will vary with cluster age and distance.

  1. Modeling the formation of globular cluster systems in the Virgo cluster

    International Nuclear Information System (INIS)

    Li, Hui; Gnedin, Oleg Y.

    2014-01-01

    The mass distribution and chemical composition of globular cluster (GC) systems preserve fossil record of the early stages of galaxy formation. The observed distribution of GC colors within massive early-type galaxies in the ACS Virgo Cluster Survey (ACSVCS) reveals a multi-modal shape, which likely corresponds to a multi-modal metallicity distribution. We present a simple model for the formation and disruption of GCs that aims to match the ACSVCS data. This model tests the hypothesis that GCs are formed during major mergers of gas-rich galaxies and inherit the metallicity of their hosts. To trace merger events, we use halo merger trees extracted from a large cosmological N-body simulation. We select 20 halos in the mass range of 2 × 10 12 to 7 × 10 13 M ☉ and match them to 19 Virgo galaxies with K-band luminosity between 3 × 10 10 and 3 × 10 11 L ☉ . To set the [Fe/H] abundances, we use an empirical galaxy mass-metallicity relation. We find that a minimal merger ratio of 1:3 best matches the observed cluster metallicity distribution. A characteristic bimodal shape appears because metal-rich GCs are produced by late mergers between massive halos, while metal-poor GCs are produced by collective merger activities of less massive hosts at early times. The model outcome is robust to alternative prescriptions for cluster formation rate throughout cosmic time, but a gradual evolution of the mass-metallicity relation with redshift appears to be necessary to match the observed cluster metallicities. We also affirm the age-metallicity relation, predicted by an earlier model, in which metal-rich clusters are systematically several billion younger than their metal-poor counterparts.

  2. NEAR-IR PHOTOMETRIC PROPERTIES OF HB, MSTO, AND SGB FOR METAL POOR GALACTIC GLOBULAR CLUSTERS

    Directory of Open Access Journals (Sweden)

    J.-W. Kim

    2007-03-01

    Full Text Available We report photometric features of the HB, MSTO, and SGB for a set of metal-poor Galactic globular clusters on the near-IR CMDs. The magnitude and color of the MSTO and SGB are measured on the fiducial normal points of the CMDs by applying a polynomial fit. The near-IR luminosity functions of horizontal branch stars in the classical second parameter pair M3 and M13 indicate that HB stars in M13 are dominated by hot stars that are rotatively faint in the infrared, whereas HB stars in M3 are brighter than those in M13. The luminosity functions of HB stars in the observed bulge clusters, except for NGC 6717, show a trend that the fainter hot HB stars are dominated in the relatively metal-poor clusters while the relatively metal-rich clusters contain the brighter HB stars. It is suggestive that NGC 6717 would be an extreme example of the second-parameter phenomenon for the bulge globular clusters.

  3. Haloes and clustering in light, neutron-rich nuclei

    International Nuclear Information System (INIS)

    Orr, N.A.

    2001-10-01

    Clustering is a relatively widespread phenomenon which takes on many guises across the nuclear landscape. Selected topics concerning the study of halo systems and clustering in light, neutron-rich nuclei are discussed here through illustrative examples taken from the Be isotopic chain. (author)

  4. Red giants and yellow stragglers in the young open cluster NGC 2447

    Science.gov (United States)

    da Silveira, M. D.; Pereira, C. B.; Drake, N. A.

    2018-06-01

    In this work we analysed, using high-resolution spectroscopy, a sample of 12 single and 4 spectroscopic binary stars of the open cluster NGC 2447. For the single stars, we obtained atmospheric parameters and chemical abundances of Li, C, N, O, Na, Mg, Al, Ca, Si, Ti, Ni, Cr, Y, Zr, La, Ce, Nd, Eu. Rotational velocities were obtained for all the stars. The abundances of the light elements and Eu and the rotational velocities were derived using spectral synthesis technique. We obtained a mean metallicity of [Fe/H] = -0.17 ± 0.05. We found that the abundances of all elements are similar to field giants and/or giants of open clusters, even for the s-process elements, which are enhanced as in other young open clusters. We show that the spectroscopic binaries NGC 2447-26, 38, and 42 are yellow-straggler stars, of which the primary is a giant star and the secondary a main-sequence A-type star.

  5. Membership determination of open clusters based on a spectral clustering method

    Science.gov (United States)

    Gao, Xin-Hua

    2018-06-01

    We present a spectral clustering (SC) method aimed at segregating reliable members of open clusters in multi-dimensional space. The SC method is a non-parametric clustering technique that performs cluster division using eigenvectors of the similarity matrix; no prior knowledge of the clusters is required. This method is more flexible in dealing with multi-dimensional data compared to other methods of membership determination. We use this method to segregate the cluster members of five open clusters (Hyades, Coma Ber, Pleiades, Praesepe, and NGC 188) in five-dimensional space; fairly clean cluster members are obtained. We find that the SC method can capture a small number of cluster members (weak signal) from a large number of field stars (heavy noise). Based on these cluster members, we compute the mean proper motions and distances for the Hyades, Coma Ber, Pleiades, and Praesepe clusters, and our results are in general quite consistent with the results derived by other authors. The test results indicate that the SC method is highly suitable for segregating cluster members of open clusters based on high-precision multi-dimensional astrometric data such as Gaia data.

  6. Production of metal particles and clusters

    Science.gov (United States)

    Mcmanus, S. P.

    1982-01-01

    The feasibility of producing novel metals or metal clusters in a low gravity environment was studied. The production of coordinately unsaturated metal carbonyls by thermolysis or photolysis of stable metal carbonyls has the potential to generate novel catalysts by this technique. Laser irradiation of available metal carbonyls was investigated. It is found that laser induced decomposition of metal carbonyls is feasible for producing a variety of coordinately unsaturated species. Formation of clustered species does occur but is hampered by weak metal-metal bonds.

  7. Measuring age differences among globular clusters having similar metallicities - A new method and first results

    International Nuclear Information System (INIS)

    Vandenberg, D.A.; Bolte, M.; Stetson, P.B.

    1990-01-01

    A color-difference technique for estimating the relative ages of globular clusters with similar chemical compositions on the basis of their CM diagrams is described and demonstrated. The theoretical basis and implementation of the procedure are explained, and results for groups of globular clusters with m/H = about -2, -1.6, and -1.3, and for two special cases (Palomar 12 and NGC 5139) are presented in extensive tables and graphs and discussed in detail. It is found that the more metal-deficient globular clusters are nearly coeval (differences less than 0.5 Gyr), whereas the most metal-rich globular clusters exhibit significant age differences (about 2 Gyr). This result is shown to contradict Galactic evolution models postulating halo collapse in less than a few times 100 Myr. 77 refs

  8. Images in the rocket ultraviolet - UV fluxes of M31 globular clusters

    International Nuclear Information System (INIS)

    Bohlin, R.C.; Cornett, R.H.; Hill, J.K.; Hill, R.S.; Stecher, T.P.

    1988-01-01

    Images obtained by a rocket-borne UV imaging telescope are used here to determine near-UV fluxes for 17 sources in M31 that are optical globular-cluster candidates and for the bright open cluster vdB0 in M31. Far-UV fluxes or flux limits are determined for the same clusters. The m(NUV)-V colors for M31 clusters are similar to those of Galactic clusters, except for the high-metallicity M31 cluster Bo 171. Four of the detected clusters have optical, m(NUV) - V, and m(FUV) - V colors indicating ages of about 100 million years. These four clusters are probably similar to the so-called 'blue globular' clusters of the LMC. The existence of young LMC-type blue globulars and the possible existence of middle-aged metal-rich globulars may indicate that M31 has continued to form globular clusters throughout its life. 39 references

  9. GLOBULAR CLUSTER ABUNDANCES FROM HIGH-RESOLUTION, INTEGRATED-LIGHT SPECTROSCOPY. II. EXPANDING THE METALLICITY RANGE FOR OLD CLUSTERS AND UPDATED ANALYSIS TECHNIQUES

    Energy Technology Data Exchange (ETDEWEB)

    Colucci, Janet E.; Bernstein, Rebecca A.; McWilliam, Andrew [The Observatories of the Carnegie Institution for Science, 813 Santa Barbara St., Pasadena, CA 91101 (United States)

    2017-01-10

    We present abundances of globular clusters (GCs) in the Milky Way and Fornax from integrated-light (IL) spectra. Our goal is to evaluate the consistency of the IL analysis relative to standard abundance analysis for individual stars in those same clusters. This sample includes an updated analysis of seven clusters from our previous publications and results for five new clusters that expand the metallicity range over which our technique has been tested. We find that the [Fe/H] measured from IL spectra agrees to ∼0.1 dex for GCs with metallicities as high as [Fe/H] = −0.3, but the abundances measured for more metal-rich clusters may be underestimated. In addition we systematically evaluate the accuracy of abundance ratios, [X/Fe], for Na i, Mg i, Al i, Si i, Ca i, Ti i, Ti ii, Sc ii, V i, Cr i, Mn i, Co i, Ni i, Cu i, Y ii, Zr i, Ba ii, La ii, Nd ii, and Eu ii. The elements for which the IL analysis gives results that are most similar to analysis of individual stellar spectra are Fe i, Ca i, Si i, Ni i, and Ba ii. The elements that show the greatest differences include Mg i and Zr i. Some elements show good agreement only over a limited range in metallicity. More stellar abundance data in these clusters would enable more complete evaluation of the IL results for other important elements.

  10. Searching for multiple stellar populations in the massive, old open cluster Berkeley 39

    Science.gov (United States)

    Bragaglia, A.; Gratton, R. G.; Carretta, E.; D'Orazi, V.; Sneden, C.; Lucatello, S.

    2012-12-01

    The most massive star clusters include several generations of stars with a different chemical composition (mainly revealed by an Na-O anti-correlation) while low-mass star clusters appear to be chemically homogeneous. We are investigating the chemical composition of several clusters with masses of a few 104 M⊙ to establish the lower mass limit for the multiple stellar population phenomenon. Using VLT/FLAMES spectra we determine abundances of Fe, O, Na, and several other elements (α, Fe-peak, and neutron-capture elements) in the old open cluster Berkeley 39. This is a massive open cluster: M ~ 104 M⊙, approximately at the border between small globular clusters and large open clusters. Our sample size of about 30 stars is one of the largest studied for abundances in any open cluster to date, and will be useful to determine improved cluster parameters, such as age, distance, and reddening when coupled with precise, well-calibrated photometry. We find that Berkeley 39 is slightly metal-poor, ⟨[Fe/H]⟩ = -0.20, in agreement with previous studies of this cluster. More importantly, we do not detect any star-to-star variation in the abundances of Fe, O, and Na within quite stringent upper limits. The rms scatter is 0.04, 0.10, and 0.05 dex for Fe, O, and Na, respectively. This small spread can be entirely explained by the noise in the spectra and by uncertainties in the atmospheric parameters. We conclude that Berkeley 39 is a single-population cluster. Based on observations collected at ESO telescopes under programme 386.B-0009.Tables 2 and 3 are available in electronic form at http://www.aanda.org

  11. IDENTIFICATION OF THE LITHIUM DEPLETION BOUNDARY AND AGE OF THE SOUTHERN OPEN CLUSTER BLANCO 1

    International Nuclear Information System (INIS)

    Cargile, P. A.; James, D. J.; Jeffries, R. D.

    2010-01-01

    We present results from a spectroscopic study of the very low mass members of the Southern open cluster Blanco 1 using the Gemini-N telescope. We obtained intermediate resolution (R ∼ 4400) GMOS spectra for 15 cluster candidate members with I ∼ 14-20 mag, and employed a series of membership criteria-proximity to the cluster's sequence in an I/I - K s color-magnitude diagram (CMD), kinematics agreeing with the cluster systemic motion, magnetic activity as a youth indicator-to classify 10 of these objects as probable cluster members. For these objects, we searched for the presence of the Li I 6708 A feature to identify the lithium depletion boundary (LDB) in Blanco 1. The I/I - K s CMD shows a clear mass segregation in the Li distribution along the cluster sequence; namely, all higher mass stars are found to be Li poor, while lower mass stars are found to be Li rich. The division between Li-poor and Li-rich (i.e., the LDB) in Blanco 1 is found at I = 18.78 ± 0.24 and I - K s = 3.05 ± 0.10. Using current pre-main-sequence evolutionary models, we determine an LDB age of 132 ± 24 Myr. Comparing our derived LDB age to upper-main-sequence isochrone ages for Blanco 1, as well as for other open clusters with identified LDBs, we find good chronometric consistency when using stellar evolution models that incorporate a moderate degree of convective core overshoot.

  12. The Magellanic Bridge Cluster NGC 796: Deep Optical AO Imaging Reveals the Stellar Content and Initial Mass Function of a Massive Open Cluster

    Science.gov (United States)

    Kalari, Venu M.; Carraro, Giovanni; Evans, Christopher J.; Rubio, Monica

    2018-04-01

    NGC 796 is a massive young cluster located 59 kpc from us in the diffuse intergalactic medium of the 1/5–1/10 Z⊙ Magellanic Bridge, allowing us to probe variations in star formation and stellar evolution processes as a function of metallicity in a resolved fashion, and providing a link between resolved studies of nearby solar-metallicity and unresolved distant metal-poor clusters located in high-redshift galaxies. In this paper, we present adaptive optics griHα imaging of NGC 796 (at 0.″5, which is ∼0.14 pc at the cluster distance) along with optical spectroscopy of two bright members to quantify the cluster properties. Our aim is to explore whether star formation and stellar evolution vary as a function of metallicity by comparing the properties of NGC 796 to higher-metallicity clusters. We find an age of {20}-5+12 Myr from isochronal fitting of the cluster main sequence in the color–magnitude diagram. Based on the cluster luminosity function, we derive a top-heavy stellar initial mass function (IMF) with a slope α = 1.99 ± 0.2, hinting at a metallicity and/or environmental dependence of the IMF, which may lead to a top-heavy IMF in the early universe. Study of the Hα emission-line stars reveals that classical Be stars constitute a higher fraction of the total B-type stars when compared with similar clusters at greater metallicity, providing some support to the chemically homogeneous theory of stellar evolution. Overall, NGC 796 has a total estimated mass of 990 ± 200 M⊙, and a core radius of 1.4 ± 0.3 pc, which classifies it as a massive young open cluster, unique in the diffuse interstellar medium of the Magellanic Bridge.

  13. POLYMER COMPOSITE FILMS WITH SIZE-SELECTED METAL NANOPARTICLES FABRICATED BY CLUSTER BEAM TECHNIQUE

    DEFF Research Database (Denmark)

    Ceynowa, F. A.; Chirumamilla, Manohar; Popok, Vladimir

    2017-01-01

    Formation of polymer films with size-selected silver and copper nanoparticles (NPs) is studied. Polymers are prepared by spin coating while NPs are fabricated and deposited utilizing a magnetron sputtering cluster apparatus. The particle embedding into the films is provided by thermal annealing...... after the deposition. The degree of immersion can be controlled by the annealing temperature and time. Together with control of cluster coverage the described approach represents an efficient method for the synthesis of thin polymer composite layers with either partially or fully embedded metal NPs....... Combining electron beam lithography, cluster beam deposition and thermal annealing allows to form ordered arrays of metal NPs on polymer films. Plasticity and flexibility of polymer host and specific properties added by coinage metal NPs open a way for different applications of such composite materials...

  14. TWO BARIUM STARS IN THE OPEN CLUSTER NGC 5822

    Energy Technology Data Exchange (ETDEWEB)

    Katime Santrich, O. J.; Pereira, C. B.; De Castro, D. B., E-mail: osantrich@on.br, E-mail: claudio@on.br, E-mail: denise@on.br [Observatorio Nacional/MCT, Rua Gen. Jose Cristino, 77, 20921-400 Rio de Janeiro (Brazil)

    2013-08-01

    Open clusters are very useful examples to explain the constraint of the nucleosynthesis process with the luminosities of stars because the distances of the clusters are better known than those of field stars. We carried out a detailed spectroscopic analysis to derive the chemical composition of two red giants in the young open cluster NGC 5822, NGC 5822-2, and NGC 5822-201. We obtained abundances of C, N, O, Na, Mg, Al, Ca, Si, Ti, Ni, Cr, Y, Zr, La, Ce, and Nd. The atmospheric parameters of the studied stars and their chemical abundances were determined using high-resolution optical spectroscopy. We employed the local thermodynamic equilibrium model atmospheres of Kurucz and the spectral analysis code MOOG. The abundances of the light elements were derived using the spectral synthesis technique. We found that NGC 5822-2 and -201 have, respectively, a mean overabundance of the elements created by the s-process, ''s'', with the notation [s/Fe] of 0.77 {+-} 0.12 and 0.83 {+-} 0.05. These values are higher than those for field giants of similar metallicity. We also found that NGC 5822-2 and -201 have, respectively, luminosities of 140 L{sub Sun} and 76 L{sub Sun }, which are much lower than the luminosity of an asymptotic giant branch star. We conclude that NGC 5822-2 and NGC 5822-201 are two new barium stars first identified in the open cluster NGC 5822. The mass transfer hypothesis is the best scenario to explain the observed overabundances.

  15. Photometric metal abundances for twenty clusters

    International Nuclear Information System (INIS)

    Jennens, P.A.; Helfer, H.L.

    1975-01-01

    Metal abundances, colour excesses and distance moduli have been determined for individual giant stars, using UBViyz photometry, in NGC 188, 559, 752, 1245, 1342, 1907, 1912, 2099, 5139 (ω cen), 5316, 5617, 5822, 5823, 6067, IC 4651, 6819, 6940, 7142, 7261 and 7789. All six clusters with ages 3 to 8x10 9 yr have metal abundances agreeing with one another; their average value of [Fe/H]=-0.24+-0.05, agrees with the average found for the bright K-giants near the Sun. All six clusters are at least 140pc from the galactic plane. For the younger clusters less than approximately 10 9 yr old, one-third are metal deficient. The very young cluster, NGC 559, is probably very metal weak. (author)

  16. (Electronic structure and reactivities of transition metal clusters)

    Energy Technology Data Exchange (ETDEWEB)

    1992-01-01

    The following are reported: theoretical calculations (configuration interaction, relativistic effective core potentials, polyatomics, CASSCF); proposed theoretical studies (clusters of Cu, Ag, Au, Ni, Pt, Pd, Rh, Ir, Os, Ru; transition metal cluster ions; transition metal carbide clusters; bimetallic mixed transition metal clusters); reactivity studies on transition metal clusters (reactivity with H{sub 2}, C{sub 2}H{sub 4}, hydrocarbons; NO and CO chemisorption on surfaces). Computer facilities and codes to be used, are described. 192 refs, 13 figs.

  17. SPB stars in the open SMC cluster NGC 371

    Science.gov (United States)

    Karoff, C.; Arentoft, T.; Glowienka, L.; Coutures, C.; Nielsen, T. B.; Dogan, G.; Grundahl, F.; Kjeldsen, H.

    2008-05-01

    Pulsation in β Cep and slowly pulsating B (SPB) stars are driven by the κ mechanism which depends critically on the metallicity. It has therefore been suggested that β Cep and SPB stars should be rare in the Magellanic Clouds which have lower metallicities than the solar neighbourhood. To test this prediction we have observed the open Small Magellanic Cloud (SMC) cluster NGC 371 for 12 nights in order to search for β Cep and SPB stars. Surprisingly, we find 29 short-period B-type variables in the upper part of the main sequence, many of which are probably SPB stars. This result indicates that pulsation is still driven by the κ mechanism even in low-metallicity environments. All the identified variables have periods longer than the fundamental radial period which means that they cannot be β Cep stars. Within an amplitude detection limit of 5 mmag no stars in the top of the Hertzsprung-Russell diagram show variability with periods shorter than the fundamental radial period. So if β Cep stars are present in the cluster they oscillate with amplitudes below 5 mmag, which is significantly lower than the mean amplitude of β Cep stars in the Galaxy. We see evidence that multimode pulsation is more common in the upper part of the main sequence than in the lower. We have also identified five eclipsing binaries and three periodic pulsating Be stars in the cluster field.

  18. An observational study of disk-population globular clusters

    International Nuclear Information System (INIS)

    Armandroff, T.E.

    1988-01-01

    Integrated-light spectroscopy was obtained for twenty-seven globular clusters at the Ca II infrared triplet. Line strengths and radial velocities were measured from the spectra. For the well-studied clusters in the sample, the strength of the CA II lines is very well correlated with previous metallicity estimates obtained using a variety of techniques. The greatly reduced effect of interstellar extinction at these wavelengths compared to the blue region of the spectrum has permitted observations of some of the most heavily reddened clusters in the Galaxy. For several such clusters, the Ca II triplet metallicities are in poor agreement with metallicity estimates from infrared photometry by Malkan. Color-magnitude diagrams were constructed for six previously unstudied metal-rich globular clusters and for the well-studied cluster 47 Tuc. The V magnitudes of the horizontal branch stars in the six clusters are in poor agreement with previous estimates based on secondary methods. The horizontal branch morphologies and reddenings of the program clusters were also determined. Using the improved set of metallicities, radial velocities, and distance moduli, the spatial distribution, kinematics, and metallicity distribution of the Galactic globulars were analyzed. The revised data supports Zinn's conclusion that the metal-rich clusters form a highly flattened, rapidly rotating disk system, while the metal-poor clusters make up the familiar, spherically distributed, slowly rotating halo population. The scale height, metallicity distribution, and kinematics of the metal-rich globulars are in good agreement with those of the stellar thick disk. Luminosity functions were constructed, and no significant difference is found between disk and halo samples. Metallicity gradients seem to be present in the disk cluster system. The implications of these results for the formation and evol

  19. The Open Cluster Chemical Abundances and Mapping (OCCAM) Survey: Galactic Neutron CaptureAbundance Gradients

    Science.gov (United States)

    O'Connell, Julia; Frinchaboy, Peter M.; Shetrone, Matthew D.; Melendez, Matthew; Cunha, Katia; Majewski, Steven R.; Zasowski, Gail; APOGEE Team

    2017-06-01

    The evolution of elements, as a function or age, throughout the Milky Way disk provides a key constraint for galaxy evolution models. In an effort to provide these constraints, we have conducted an investigation into the r- and s- process elemental abundances for a large sample of open clusters as part of an optical follow-up to the SDSS-III/APOGEE-1 survey. Stars were identified as cluster members by the Open Cluster Chemical Abundance & Mapping (OCCAM) survey, which culls member candidates by radial velocity, metallicity and proper motion from the observed APOGEE sample. To obtain data for neutron capture elements in these clusters, we conducted a long-term observing campaign covering three years (2013-2016) using the McDonald Observatory Otto Struve 2.1-m telescope and Sandiford Cass Echelle Spectrograph (R ~ 60,000). We present Galactic neutron capture abundance gradients using 30+ clusters, within 6 kpc of the Sun, covering a range of ages from ~80 Myr to ~10 Gyr .

  20. Open source clustering software.

    Science.gov (United States)

    de Hoon, M J L; Imoto, S; Nolan, J; Miyano, S

    2004-06-12

    We have implemented k-means clustering, hierarchical clustering and self-organizing maps in a single multipurpose open-source library of C routines, callable from other C and C++ programs. Using this library, we have created an improved version of Michael Eisen's well-known Cluster program for Windows, Mac OS X and Linux/Unix. In addition, we generated a Python and a Perl interface to the C Clustering Library, thereby combining the flexibility of a scripting language with the speed of C. The C Clustering Library and the corresponding Python C extension module Pycluster were released under the Python License, while the Perl module Algorithm::Cluster was released under the Artistic License. The GUI code Cluster 3.0 for Windows, Macintosh and Linux/Unix, as well as the corresponding command-line program, were released under the same license as the original Cluster code. The complete source code is available at http://bonsai.ims.u-tokyo.ac.jp/mdehoon/software/cluster. Alternatively, Algorithm::Cluster can be downloaded from CPAN, while Pycluster is also available as part of the Biopython distribution.

  1. Wolf-Rayet stars in open clusters and associations

    International Nuclear Information System (INIS)

    Lundstroem, I.; Stenholm, B.

    1982-01-01

    The authors have made a search for line-of-sight coincidences between WR stars and open clusters using the new catalogue of galactic WR stars (van der Hucht et al., 1981, called the HCLS catalogue) and the catalogue of open cluster data (Lyngaa and Lundstroem, 1980). As a measure of the separation they used the angular distance between the WR star and the cluster centre expressed with the cluster angular radius, r', as unit. By comparing the results found from the real angular distributions of WR stars and open clusters with those found if the WR stars were redistributed by changing signs in their latitudes, it is concluded that the majority of WR stars with separations less than 3r' are true cluster members. For larger separations only a few stars can be expected to be members. The authors have therefore limited their investigation to those WR stars that were found within 5r' from an open cluster. (Auth.)

  2. Open Clusters as Tracers of the Galactic Disk

    Science.gov (United States)

    Cantat-Gaudin, Tristan

    2015-01-01

    Open clusters (OCs) are routinely used as reliable tracers of the properties and evolution of the galactic disk, as they can be found at all galactocentric distances and span a wide range of ages. More than 3000 OCs are listed in catalogues, although few have been studied in details. The goal of this work is to study the properties of open clusters. This work was conducted in the framework of the Gaia-ESO Survey (GES). GES is an observational campaign targeting more than 100,000 stars in all major components of the Milky Way, including stars in a hundred open clusters. It uses the FLAMES instrument at the VLT to produce high and medium-resolution spectra, which provide accurate radial velocities and individual elemental abundances. In this framework, the goals of the Thesis are: * to study the properties of OCs and of their stars from photometry and spectroscopy to derive their age, the extinction and the chemical composition of the stars, to begin to build a homogeneous data base. Looking at literature data it is clear that different authors derive substantially different chemical compositions, and in general OC parameters. * the study of OCs and their chemical homogeneity (or inhomogeneity) can cast light on what is still an open issue: the presence of multiple populations in clusters. While multiple generations of stars are now ubiquitously found in globular clusters in the Milky Way and in the Magellanic Clouds, they have not been yet detected in open clusters. What is the main driver of the self-pollution process? * to study the cluster formation process. All, or at least a significant fraction of stars form in clusters. Young clusters (a few Myr) can retain some of the properties of the molecular cloud they originate from and give us insight about the cluster assembly process. The first GES data release contains data for the young OC Gamma Velorum, in which two (dynamically different) subpopulations have been identified. This cluster can serve as a test case

  3. Towards a comprehensive knowledge of the open cluster Haffner 9

    Science.gov (United States)

    Piatti, Andrés E.

    2017-03-01

    We turn our attention to Haffner 9, a Milky Way open cluster whose previous fundamental parameter estimates are far from being in agreement. In order to provide with accurate estimates, we present high-quality Washington CT1 and Johnson BVI photometry of the cluster field. We put particular care in statistically cleaning the colour-magnitude diagrams (CMDs) from field star contamination, which was found a common source in previous works for the discordant fundamental parameter estimates. The resulting cluster CMD fiducial features were confirmed from a proper motion membership analysis. Haffner 9 is a moderately young object (age ∼350 Myr), placed in the Perseus arm - at a heliocentric distance of ∼3.2 kpc - , with a lower limit for its present mass of ∼160 M⊙ and of nearly metal solar content. The combination of the cluster structural and fundamental parameters suggest that it is in an advanced stage of internal dynamical evolution, possibly in the phase typical of those with mass segregation in their core regions. However, the cluster still keeps its mass function close to that of the Salpeter's law.

  4. WIYN OPEN CLUSTER STUDY. XXIV. STELLAR RADIAL-VELOCITY MEASUREMENTS IN NGC 6819

    International Nuclear Information System (INIS)

    Tabetha Hole, K.; Geller, Aaron M.; Mathieu, Robert D.; Meibom, Soeren; Platais, Imants; Latham, David W.

    2009-01-01

    We present the current results from our ongoing radial-velocity (RV) survey of the intermediate-age (2.4 Gyr) open cluster NGC 6819. Using both newly observed and other available photometry and astrometry, we define a primary target sample of 1454 stars that includes main-sequence, subgiant, giant, and blue straggler stars, spanning a magnitude range of 11 ≤V≤ 16.5 and an approximate mass range of 1.1-1.6 M sun . Our sample covers a 23 arcminute (13 pc) square field of view centered on the cluster. We have measured 6571 radial velocities for an unbiased sample of 1207 stars in the direction of the open cluster NGC 6819, with a single-measurement precision of 0.4 km s -1 for most narrow-lined stars. We use our RV data to calculate membership probabilities for stars with ≥3 measurements, providing the first comprehensive membership study of the cluster core that includes stars from the giant branch through the upper main sequence. We identify 480 cluster members. Additionally, we identify velocity-variable systems, all of which are likely hard binaries that dynamically power the cluster. Using our single cluster members, we find a cluster average RV of 2.34 ± 0.05 km s -1 . We use our kinematic cluster members to construct a cleaned color-magnitude diagram from which we identify rich giant, subgiant, and blue straggler populations and a well defined red clump. The cluster displays a morphology near the cluster turnoff clearly indicative of core convective overshoot. Finally, we discuss a few stars of note, one of which is a short-period red-clump binary that we suggest may be the product of a dynamical encounter.

  5. AN EXTREMELY CARBON-RICH, EXTREMELY METAL-POOR STAR IN THE SEGUE 1 SYSTEM

    International Nuclear Information System (INIS)

    Norris, John E.; Yong, David; Gilmore, Gerard; Wyse, Rosemary F. G.; Frebel, Anna

    2010-01-01

    We report the analysis of high-resolution, high signal-to-noise ratio, spectra of an extremely metal-poor, extremely C-rich red giant, Seg 1-7, in Segue 1-described in the literature alternatively as an unusually extended globular cluster or an ultra-faint dwarf galaxy. The radial velocity of Seg 1-7 coincides precisely with the systemic velocity of Segue 1, and its chemical abundance signature of [Fe/H] = -3.52, [C/Fe] = +2.3, [N/Fe] = +0.8, [Na/Fe] = +0.53, [Mg/Fe] = +0.94, [Al/Fe] = +0.23, and [Ba/Fe] < -1.0 is similar to that of the rare and enigmatic class of Galactic halo objects designated CEMP-no (carbon-rich, extremely metal-poor with no enhancement (over solar ratios) of heavy neutron-capture elements). This is the first star in a Milky Way 'satellite' that unambiguously lies on the metal-poor, C-rich branch of the Aoki et al. bimodal distribution of field halo stars in the ([C/Fe], [Fe/H])-plane. Available data permit us only to identify Seg 1-7 as a member of an ultra-faint dwarf galaxy or as debris from the Sgr dwarf spheroidal galaxy. In either case, this demonstrates that at extremely low abundance, [Fe/H ] <-3.0, star formation and associated chemical evolution proceeded similarly in the progenitors of both the field halo and satellite systems. By extension, this is consistent with other recent suggestions that the most metal-poor dwarf spheroidal and ultra-faint dwarf satellites were the building blocks of the Galaxy's outer halo.

  6. Keck Spectroscopy of Globular Clusters in the Elliptical Galaxy NGC 3610

    OpenAIRE

    Strader, Jay; Brodie, Jean P.; Schweizer, Francois; Larsen, Soeren S.; Seitzer, Patrick

    2002-01-01

    We present moderate-resolution Keck spectra of nine candidate globular clusters in the possible merger-remnant elliptical galaxy NGC 3610. Eight of the objects appear to be bona fide globular clusters of NGC 3610. We find that two of the clusters belong to an old metal-poor population, five to an old metal-rich population, and only one to an intermediate-age metal-rich population. The estimated age of the intermediate-age cluster is 1-5 Gyr, which is in agreement with earlier estimates of the...

  7. ROTATION PERIODS OF OPEN-CLUSTER STARS .3.

    NARCIS (Netherlands)

    PROSSER, CF; SHETRONE, MD; DASGUPTA, A; BACKMAN, DE; LAAKSONEN, BD; BAKER, SW; MARSCHALL, LA; WHITNEY, BA; KUIJKEN, K; STAUFFER, [No Value

    We present the results from a photometric monitoring program of 15 open cluster stars and one weak-lined T Tauri star during late 1993/early 1994. Several slow rotators which are members of the Alpha Persei, Pleiades, and Hyades open clusters have been monitored and period estimates derived. Using

  8. Metal interactions with boron clusters

    International Nuclear Information System (INIS)

    Grimes, R.N.

    1982-01-01

    This book presents information on the following topics: the structural and bonding features of metallaboranes and metallacarboranes; transition-metal derivatives of nido-boranes and some related species; interactions of metal groups with the octahydrotriborate (1-) anion, B 3 H 8 ; metallaboron cage compounds of the main group metals; closo-carborane-metal complexes containing metal-carbon and metal-boron omega-bonds; electrochemistry of metallaboron cage compounds; and boron clusters with transition metal-hydrogen bonds

  9. Holes in the distribution of rich clusters of galaxies

    International Nuclear Information System (INIS)

    Burns, J.O.

    1988-01-01

    The properties of voids in the distribution of Abell clusters of galaxies are described. Cluster voids, such as that in Bootes, serve as markers of large candidate voids of galaxies. The advantages and disadvantages of using rich clusters as tracers of large-scale structures are reviewed. One new 40/h Mpc diameter void of galaxies and clusters in Pisces-Cetus is described in detail. It is found that numerical simulations of models with Gaussian initial conditions do not reproduce the void or filament structures observed within the Abell cluster catalog. The implications of this discrepancy for future observations and models are discussed. 26 references

  10. Ionic Transport Through Metal-Rich Organic Coatings

    Science.gov (United States)

    2016-08-19

    important for metal substrates, as it is well-known that chloride increases corrosion of metals . 3 For metal -loaded primers, it has been established...volume (MPV) percent, solvent polarity, and resin molecular weight impact corrosion protection of metal -rich organic (MRO) coatings. Following design of...pH and chloride ion concentration levels over time. As the corrosion protection of the coating decreases, chloride ion concentration will increase

  11. Electron scattering on metal clusters and fullerenes

    International Nuclear Information System (INIS)

    Solov'yov, A.V.

    2001-01-01

    This paper gives a survey of physical phenomena manifesting themselves in electron scattering on atomic clusters. The main emphasis is made on electron scattering on fullerenes and metal clusters, however some results are applicable to other types of clusters as well. This work is addressed to theoretical aspects of electron-cluster scattering, however some experimental results are also discussed. It is demonstrated that the electron diffraction plays important role in the formation of both elastic and inelastic electron scattering cross sections. It is elucidated the essential role of the multipole surface and volume plasmon excitations in the formation of electron energy loss spectra on clusters (differential and total, above and below ionization potential) as well as the total inelastic scattering cross sections. Particular attention is paid to the elucidation of the role of the polarization interaction in low energy electron-cluster collisions. This problem is considered for electron attachment to metallic clusters and the plasmon enhanced photon emission. Finally, mechanisms of electron excitation widths formation and relaxation of electron excitations in metal clusters and fullerenes are discussed. (authors)

  12. Fission of Polyanionic Metal Clusters

    Science.gov (United States)

    König, S.; Jankowski, A.; Marx, G.; Schweikhard, L.; Wolfram, M.

    2018-04-01

    Size-selected dianionic lead clusters Pbn2 -, n =34 - 56 , are stored in a Penning trap and studied with respect to their decay products upon photoexcitation. Contrary to the decay of other dianionic metal clusters, these lead clusters show a variety of decay channels. The mass spectra of the fragments are compared to the corresponding spectra of the monoanionic precursors. This comparison leads to the conclusion that, in the cluster size region below about n =48 , the fission reaction Pbn2 -→Pbn-10 -+Pb10- is the major decay process. Its disappearance at larger cluster sizes may be an indication of a nonmetal to metal transition. Recently, the pair of Pb10- and Pbn-10 - were observed as pronounced fragments in electron-attachment studies [S. König et al., Int. J. Mass Spectrom. 421, 129 (2017), 10.1016/j.ijms.2017.06.009]. The present findings suggest that this combination is the fingerprint of the decay of doubly charged lead clusters. With this assumption, the dianion clusters have been traced down to Pb212 -, whereas the smallest size for the direct observation was as high as n =28 .

  13. A GMBCG GALAXY CLUSTER CATALOG OF 55,424 RICH CLUSTERS FROM SDSS DR7

    International Nuclear Information System (INIS)

    Hao Jiangang; Annis, James; Johnston, David E.; McKay, Timothy A.; Evrard, August; Siegel, Seth R.; Gerdes, David; Koester, Benjamin P.; Rykoff, Eli S.; Rozo, Eduardo; Wechsler, Risa H.; Busha, Michael; Becker, Matthew; Sheldon, Erin

    2010-01-01

    We present a large catalog of optically selected galaxy clusters from the application of a new Gaussian Mixture Brightest Cluster Galaxy (GMBCG) algorithm to SDSS Data Release 7 data. The algorithm detects clusters by identifying the red-sequence plus brightest cluster galaxy (BCG) feature, which is unique for galaxy clusters and does not exist among field galaxies. Red-sequence clustering in color space is detected using an Error Corrected Gaussian Mixture Model. We run GMBCG on 8240 deg 2 of photometric data from SDSS DR7 to assemble the largest ever optical galaxy cluster catalog, consisting of over 55,000 rich clusters across the redshift range from 0.1 < z < 0.55. We present Monte Carlo tests of completeness and purity and perform cross-matching with X-ray clusters and with the maxBCG sample at low redshift. These tests indicate high completeness and purity across the full redshift range for clusters with 15 or more members.

  14. A GMBCG galaxy cluster catalog of 55,880 rich clusters from SDSS DR7

    Energy Technology Data Exchange (ETDEWEB)

    Hao, Jiangang; McKay, Timothy A.; Koester, Benjamin P.; Rykoff, Eli S.; Rozo, Eduardo; Annis, James; Wechsler, Risa H.; Evrard, August; Siegel, Seth R.; Becker, Matthew; Busha, Michael; /Fermilab /Michigan U. /Chicago U., Astron. Astrophys. Ctr. /UC, Santa Barbara /KICP, Chicago /KIPAC, Menlo Park /SLAC /Caltech /Brookhaven

    2010-08-01

    We present a large catalog of optically selected galaxy clusters from the application of a new Gaussian Mixture Brightest Cluster Galaxy (GMBCG) algorithm to SDSS Data Release 7 data. The algorithm detects clusters by identifying the red sequence plus Brightest Cluster Galaxy (BCG) feature, which is unique for galaxy clusters and does not exist among field galaxies. Red sequence clustering in color space is detected using an Error Corrected Gaussian Mixture Model. We run GMBCG on 8240 square degrees of photometric data from SDSS DR7 to assemble the largest ever optical galaxy cluster catalog, consisting of over 55,000 rich clusters across the redshift range from 0.1 < z < 0.55. We present Monte Carlo tests of completeness and purity and perform cross-matching with X-ray clusters and with the maxBCG sample at low redshift. These tests indicate high completeness and purity across the full redshift range for clusters with 15 or more members.

  15. Variable stars in the field of open cluster NGC 2126

    International Nuclear Information System (INIS)

    Liu Shunfang; Wu Zhenyu; Zhang Xiaobin; Wu Jianghua; Ma Jun; Jiang Zhaoji; Chen Jiansheng; Zhou Xu

    2009-01-01

    We report the results of a time-series CCD photometric survey of variable stars in the field of open cluster NGC 2126. In about a one square degree field covering the cluster, a total of 21 variable candidates are detected during this survey, of which 16 are newly found. The periods, classifications and spectral types of 14 newly discovered variables are discussed, which consist of six eclipsing binary systems, three pulsating variable stars, three long period variables, one RS CVn star, and one W UMa or δ Scuti star. In addition, there are two variable candidates, the properties of which cannot be determined. By a method based on fitting observed spectral energy distributions of stars with theoretical ones, the membership probabilities and the fundamental parameters of this cluster are determined. As a result, five variables are probably members of NGC 2126. The fundamental parameters of this cluster are determined as: metallicity to be 0.008 Z o-dot , age log(t) = 8.95, distance modulus (m - M) 0 = 10.34 and reddening value E (B - V) = 0.55 mag.

  16. Gas phase reactivity of thermal metal clusters

    Science.gov (United States)

    Castleman, A. W., Jr.; Harms, A. C.; Leuchtner, R. E.

    1991-03-01

    Reaction kinetics of metal cluster ions under well defined thermal conditions were studied using a flow tube reactor in combination with laser vaporization. Aluminum anions and cations were reacted with oxygen, and several species which are predicted jellium shell closings, were found to have special stability. Metal alloy cluster anions comprised of Al, V and Nb were also seen to react with oxygen. Alloy clusters with an even number of electrons reacted more slowly than odd electron species, and certain clusters appeared to be exceptionally unreactive. Copper cation clusters were observed to associate with carbon monoxide with reactivities that approach bulk behavior at surprisingly small cluster size. These reactions demonstrate how the rate of reaction changes with cluster size.

  17. Extragalactic globular clusters. I. The metallicity calibration

    International Nuclear Information System (INIS)

    Brodie, J.P.; Huchra, J.P.

    1990-01-01

    The ability of absorption-line strength indices, measured from integrated globular cluster spectra, to predict mean cluster metallicity is explored. Statistical criteria, are used to identify the six best indices out of about 20 measured in a large sample of Galactic and M31 cluster spectra. Linear relations between index and metallicity have been derived along with new calibrations of infrared colors (V - K, J - K, and CO) versus Fe/H. Estimates of metallicity from the six spectroscopic index-metallicity relations have been combined in three different ways to identify the most efficient estimator and the minimum bias estimator of Fe/H - the weighted mean. This provides an estimate of Fe/H accurate to about 15 percent. 37 refs

  18. Globular cluster metallicity scale: evidence from stellar models

    International Nuclear Information System (INIS)

    Demarque, P.; King, C.R.; Diaz, A.

    1982-01-01

    Theoretical giant branches have been constructed to determine their relative positions for metallicities in the range -2.3 0 )/sub 0,g/ based on these models is presented which yields good agreement over the observed range of metallicities for galactic globular clusters and old disk clusters. The metallicity of 47 Tuc and M71 given by this calibration is about -0.8 dex. Subject headings: clusters, globular: stars: abundances: stars: interiors

  19. Supersonic bare metal cluster beams

    International Nuclear Information System (INIS)

    Smalley, R.E.

    1991-01-01

    Progress continued this past year on two principal fronts in the study of bare metal clusters: photoelectron spectroscopy of mass selected negative ions, and surface chemisorption of cluster ions levitated in a superconducting magnet as monitored by fourier transform ion cyclotron resonance

  20. Gas phase reactivity of thermal metal clusters

    International Nuclear Information System (INIS)

    Castleman, A.W. Jr.; Harms, A.C.; Leuchtner, R.E.

    1991-01-01

    Reaction kinetics of metal cluster ions under well defined thermal conditions were studied using a flow tube reactor in combination with laser vaporization. Aluminum anions and cations were reacted with oxygen, and several species which are predicted jellium shell closings, were found to have special stability. Metal alloy cluster anions comprised of Al, V and Nb were also seen to react with oxygen. Alloy clusters with an even number of electrons reacted more slowly than odd electron species, and certain clusters appeared to be exceptionally unreactive. Copper cation clusters were observed to associate with carbon monoxide with reactivities that approach bulk behavior at surprisingly small cluster size. These reactions demonstrate how the rate of reaction changes with cluster size. (orig.)

  1. Singlet-paired coupled cluster theory for open shells

    Science.gov (United States)

    Gomez, John A.; Henderson, Thomas M.; Scuseria, Gustavo E.

    2016-06-01

    Restricted single-reference coupled cluster theory truncated to single and double excitations accurately describes weakly correlated systems, but often breaks down in the presence of static or strong correlation. Good coupled cluster energies in the presence of degeneracies can be obtained by using a symmetry-broken reference, such as unrestricted Hartree-Fock, but at the cost of good quantum numbers. A large body of work has shown that modifying the coupled cluster ansatz allows for the treatment of strong correlation within a single-reference, symmetry-adapted framework. The recently introduced singlet-paired coupled cluster doubles (CCD0) method is one such model, which recovers correct behavior for strong correlation without requiring symmetry breaking in the reference. Here, we extend singlet-paired coupled cluster for application to open shells via restricted open-shell singlet-paired coupled cluster singles and doubles (ROCCSD0). The ROCCSD0 approach retains the benefits of standard coupled cluster theory and recovers correct behavior for strongly correlated, open-shell systems using a spin-preserving ROHF reference.

  2. Singlet-paired coupled cluster theory for open shells

    International Nuclear Information System (INIS)

    Gomez, John A.; Henderson, Thomas M.; Scuseria, Gustavo E.

    2016-01-01

    Restricted single-reference coupled cluster theory truncated to single and double excitations accurately describes weakly correlated systems, but often breaks down in the presence of static or strong correlation. Good coupled cluster energies in the presence of degeneracies can be obtained by using a symmetry-broken reference, such as unrestricted Hartree-Fock, but at the cost of good quantum numbers. A large body of work has shown that modifying the coupled cluster ansatz allows for the treatment of strong correlation within a single-reference, symmetry-adapted framework. The recently introduced singlet-paired coupled cluster doubles (CCD0) method is one such model, which recovers correct behavior for strong correlation without requiring symmetry breaking in the reference. Here, we extend singlet-paired coupled cluster for application to open shells via restricted open-shell singlet-paired coupled cluster singles and doubles (ROCCSD0). The ROCCSD0 approach retains the benefits of standard coupled cluster theory and recovers correct behavior for strongly correlated, open-shell systems using a spin-preserving ROHF reference.

  3. The CNO Bi-cycle in the Open Cluster NGC 752

    Science.gov (United States)

    Hawkins, Keith; Schuler, S.; King, J.; The, L.

    2011-01-01

    The CNO bi-cycle is the primary energy source for main sequence stars more massive than the sun. To test our understanding of stellar evolution models using the CNO bi-cycle, we have undertaken light-element (CNO) abundance analysis of three main sequence dwarf stars and three red giant stars in the open cluster NGC 752 utilizing high resolution (R 50,000) spectroscopy from the Keck Observatory. Preliminary results indicate, as expected, there is a depletion of carbon in the giants relative to the dwarfs. Additional analysis is needed to determine if the amount of depletion is in line with model predictions, as seen in the Hyades open cluster. Oxygen abundances are derived from the high-excitation O I triplet, and there is a 0.19 dex offset in the [O/H] abundances between the giants and dwarfs which may be explained by non-local thermodynamic equilibrium (NLTE), although further analysis is needed to verify this. The standard procedure for spectroscopically determining stellar parameters used here allows for a measurement of the cluster metallicity, [Fe/H] = 0.04 ± 0.02. In addition to the Fe abundances we have determined Na, Mg, and Al abundances to determine the status of other nucleosynthesis processes. The Na, Mg and Al abundances of the giants are enhanced relative to the dwarfs, which is consistent with similar findings in giants of other open clusters. Support for K. Hawkins was provided by the NOAO/KPNO Research Experiences for Undergraduates (REU) Program which is funded by the National Science Foundation Research Experiences for Undergraduates Program and the Department of Defense ASSURE program through Scientific Program Order No. 13 (AST-0754223) of the Cooperative Agreement No. AST-0132798 between the Association of Universities for Research in Astronomy (AURA) and the NSF.

  4. THE YOUNG OPEN CLUSTER BERKELEY 55

    Energy Technology Data Exchange (ETDEWEB)

    Negueruela, Ignacio; Marco, Amparo, E-mail: ignacio.negueruela@ua.es, E-mail: amparo.marco@ua.es [Departamento de Fisica, Ingenieria de Sistemas y Teoria de la Senal, Universidad de Alicante, Apdo. 99, E-03080 Alicante (Spain)

    2012-02-15

    We present UBV photometry of the highly reddened and poorly studied open cluster Berkeley 55, revealing an important population of B-type stars and several evolved stars of high luminosity. Intermediate-resolution far-red spectra of several candidate members confirm the presence of one F-type supergiant and six late supergiants or bright giants. The brightest blue stars are mid-B giants. Spectroscopic and photometric analyses indicate an age 50 {+-} 10 Myr. The cluster is located at a distance d Almost-Equal-To 4 kpc, consistent with other tracers of the Perseus Arm in this direction. Berkeley 55 is thus a moderately young open cluster with a sizable population of candidate red (super)giant members, which can provide valuable information about the evolution of intermediate-mass stars.

  5. Ruprecht 106 - A young metal-poor Galactic globular cluster

    International Nuclear Information System (INIS)

    Buonanno, R.; Buscema, G.; Fusi Pecci, F.; Richer, H.B.; Fahlman, G.G.

    1990-01-01

    The first CCD photometric survey in the Galactic globular cluster Ruprecht 106 has been performed. The results show that Ruprecht 106 is a metal-poor cluster with (Fe/H) about -2 located at about 25 kpc from the Galactic center. A sizable, high centrally concentrated population of blue stragglers was detected. Significant differences in the positions of the turnoffs in the color-magnitude diagram are found compared to those in metal-poor clusters. The cluster appears younger than other typical metal-poor Galactic globulars by about 4-5 Gyr; if true, this object would represent the first direct proof of the existence of a significant age spread among old, very metal-poor clusters. 51 refs

  6. Lithium in Open Cluster Red Giants Hosting Substellar Companions

    Science.gov (United States)

    Carlberg, Joleen K.; Smith, Verne V.; Cunha, Katia; Carpenter, Kenneth G.

    2016-02-01

    We have measured stellar parameters, [Fe/H], lithium abundances, rotation, and 12C/13C in a small sample of red giants (RGs) in three open clusters that are each home to a RG star that hosts a substellar companion (SSC) (NGC 2423 3, NGC 4349 127, and BD+12 1917 in M67). Our goal is to explore whether the presence of SSCs influences the Li content. Both 12C/13C and stellar rotation are measured as additional tracers of stellar mixing. One of the companion hosts, NGC 2423 3, is found to be Li-rich with A(Li){}{{NLTE}} = 1.56 dex, and this abundance is significantly higher than the A(Li) of the two comparison stars in NGC 2423. All three SSC hosts have the highest A(Li) and 12C/13C when compared to the control RGs in their respective clusters; however, except for NGC 2423 3, at least one control star has similarly high abundances within the uncertainties. Higher A(Li) could suggest that the formation or presence of planets plays a role in the degree of internal mixing on or before the RG branch. However, a multitude of factors affect A(Li) during the RG phase, and when the abundances of our sample are compared with the abundances of RGs in other open clusters available in the literature, we find that they all fall well within a much larger distribution of A(Li) and 12C/13C. Thus, even the high Li in NGC 2423 3 cannot be concretely tied to the presence of the SSC.

  7. Three-dimensional morphological segregation in rich clusters of galaxies

    International Nuclear Information System (INIS)

    Salvador-Sole, E.; Sanroma, M.; Jordana, J.J.R.

    1989-01-01

    The implications of the observed correlation between morphological fractions and projected number density of galaxies in rich clusters are analyzed. It is found that this correlation is the result of a well-defined intrinsic correlation that depends on cluster concentration, whether the observed correlation is strictly universal or not. This dependence is in overall agreement with that expected from the action of mechanisms of environment-induced morphological evolution of galaxies. 30 references

  8. Oligomeric rare-earth metal cluster complexes with endohedral transition metal atoms

    Energy Technology Data Exchange (ETDEWEB)

    Steinberg, Simon; Zimmermann, Sina; Brühmann, Matthias; Meyer, Eva; Rustige, Christian; Wolberg, Marike; Daub, Kathrin; Bell, Thomas; Meyer, Gerd, E-mail: gerd.meyer@uni-koeln.de

    2014-11-15

    Comproportionation reactions of rare-earth metal trihalides (RX{sub 3}) with the respective rare-earth metals (R) and transition metals (T) led to the formation of 22 oligomeric R cluster halides encapsulating T, in 19 cases for the first time. The structures of these compounds were determined by single-crystal X-ray diffraction and are composed of trimers ((T{sub 3}R{sub 11})X{sub 15}-type, P6{sub 3}/m), tetramers ((T{sub 4}R{sub 16})X{sub 28}(R{sub 4}) (P-43m), (T{sub 4}R{sub 16})X{sub 20} (P4{sub 2}/nnm), (T{sub 4}R{sub 16})X{sub 24}(RX{sub 3}){sub 4} (I4{sub 1}/a) and (T{sub 4}R{sub 16})X{sub 23} (C2/m) types of structure) and pentamers ((Ru{sub 5}La{sub 14}){sub 2}Br{sub 39}, Cc) of (TR{sub r}){sub n} (n=2–5) clusters. These oligomers are further enveloped by inner (X{sup i}) as well as outer (X{sup a}) halido ligands, which possess diverse functionalities and interconnect like oligomers through i–i, i–a and/or a–i bridges. The general features of the crystal structures for these new compounds are discussed and compared to literature entries as well as different structure types with oligomeric T centered R clusters. Dimers and tetramers originating from the aggregation of (TR{sub 6}) octahedra via common edges are more frequent than trimers and pentamers, in which the (TR{sub r}) clusters share common faces. - Graphical abstract: Rare earth-metal cluster complexes with endohedral transition metal atoms (TR{sub 6}) may connect via common edges or faces to form dimers, trimers, tetramers and pentamers of which the tetramers are the most prolific. Packing effects and electron counts play an important role. - Highlights: • Rare-earth metal cluster complexes encapsulate transition metal atoms. • Oligomers are built via connection of octahedral clusters via common edges or faces. • Dimers through pentamers with closed structures are known. • Tetramers including a tetrahedron of endohedral atoms are the most prolific.

  9. Oxide-supported metal clusters: models for heterogeneous catalysts

    International Nuclear Information System (INIS)

    Santra, A K; Goodman, D W

    2003-01-01

    Understanding the size-dependent electronic, structural and chemical properties of metal clusters on oxide supports is an important aspect of heterogeneous catalysis. Recently model oxide-supported metal catalysts have been prepared by vapour deposition of catalytically relevant metals onto ultra-thin oxide films grown on a refractory metal substrate. Reactivity and spectroscopic/microscopic studies have shown that these ultra-thin oxide films are excellent models for the corresponding bulk oxides, yet are sufficiently electrically conductive for use with various modern surface probes including scanning tunnelling microscopy (STM). Measurements on metal clusters have revealed a metal to nonmetal transition as well as changes in the crystal and electronic structures (including lattice parameters, band width, band splitting and core-level binding energy shifts) as a function of cluster size. Size-dependent catalytic reactivity studies have been carried out for several important reactions, and time-dependent catalytic deactivation has been shown to arise from sintering of metal particles under elevated gas pressures and/or reactor temperatures. In situ STM methodologies have been developed to follow the growth and sintering kinetics on a cluster-by-cluster basis. Although several critical issues have been addressed by several groups worldwide, much more remains to be done. This article highlights some of these accomplishments and summarizes the challenges that lie ahead. (topical review)

  10. A HOT URANUS ORBITING THE SUPER METAL-RICH STAR HD 77338 AND THE METALLICITY-MASS CONNECTION

    International Nuclear Information System (INIS)

    Jenkins, J. S.; Hoyer, S.; Jones, M. I.; Rojo, P.; Day-Jones, A. C.; Ruiz, M. T.; Jones, H. R. A.; Tuomi, M.; Barnes, J. R.; Pavlenko, Y. V.; Pinfield, D. J.; Murgas, F.; Ivanyuk, O.; Jordán, A.

    2013-01-01

    We announce the discovery of a low-mass planet orbiting the super metal-rich K0V star HD 77338 as part of our ongoing Calan-Hertfordshire Extrasolar Planet Search. The best-fit planet solution has an orbital period of 5.7361 ± 0.0015 days and with a radial velocity semi-amplitude of only 5.96 ± 1.74 ms –1 , we find a minimum mass of 15.9 +4.7 -5.3 M ⊕ . The best-fit eccentricity from this solution is 0.09 +0.25 -0.09 , and we find agreement for this data set using a Bayesian analysis and a periodogram analysis. We measure a metallicity for the star of +0.35 ± 0.06 dex, whereas another recent work finds +0.47 ± 0.05 dex. Thus HD 77338b is one of the most metal-rich planet-host stars known and the most metal-rich star hosting a sub-Neptune-mass planet. We searched for a transit signature of HD 77338b but none was detected. We also highlight an emerging trend where metallicity and mass seem to correlate at very low masses, a discovery that would be in agreement with the core accretion model of planet formation. The trend appears to show that for Neptune-mass planets and below, higher masses are preferred when the host star is more metal-rich. Also a lower boundary is apparent in the super metal-rich regime where there are no very low mass planets yet discovered in comparison to the sub-solar metallicity regime. A Monte Carlo analysis shows that this low-mass planet desert is statistically significant with the current sample of 36 planets at the ∼4.5σ level. In addition, results from Kepler strengthen the claim for this paucity of the lowest-mass planets in super metal-rich systems. Finally, this discovery adds to the growing population of low-mass planets around low-mass and metal-rich stars and shows that very low mass planets can now be discovered with a relatively small number of data points using stable instrumentation.

  11. Ion beam induced nanosized Ag metal clusters in glass

    International Nuclear Information System (INIS)

    Mahnke, H.-E.; Schattat, B.; Schubert-Bischoff, P.; Novakovic, N.

    2006-01-01

    Silver metal clusters have been formed in soda lime glass by high-energy heavy-ion irradiation at ISL. The metal cluster formation was detected with X-ray absorption spectroscopy (EXAFS) in fluorescence mode, and the shape of the clusters was imaged with transmission electron microscopy. While annealing in reducing atmosphere alone, leads to the formation of metal clusters in Ag-containing glasses, where the Ag was introduced by ion-exchange, such clusters are not very uniform in size and are randomly distributed over the Ag-containing glass volume. Irradiation with 600-MeV Au ions followed by annealing, however, results in clusters more uniform in size and arranged in chains parallel to the direction of the ion beam

  12. MD simulation of atomic displacement cascades near chromium-rich clusters in FeCr alloy

    International Nuclear Information System (INIS)

    Tikhonchev, M.; Svetukhin, V.; Gaganidze, E.

    2013-01-01

    The paper reports simulation of cascades in Fe–9 at.%Cr binary alloy containing chromium-rich clusters. The simulation is performed by the molecular dynamics method at the initial temperature of 300 K and primary knock-on atom energy of 15 and 20 keV. Spherical clusters containing 95 at.% of Cr with diameter of 1–5 nm have been considered. The properties of cascade evolution in the presence of chromium-rich cluster are studied. It is shown that these clusters tend to dissolve in collision cascades. However, clusters with diameter of ⩾3 nm exhibit only slight modifications and can be considered stable. Parameters of small (1–2 nm) clusters can change significantly and, in some cases, a 1 nm cluster can be totally dissolved

  13. MD simulation of atomic displacement cascades near chromium-rich clusters in FeCr alloy

    Energy Technology Data Exchange (ETDEWEB)

    Tikhonchev, M., E-mail: tikhonchev@sv.ulsu.ru [Ulyanovsk State University, Research Institute of Technology, 42 Leo Tolstoy St., 432970 Ulyanovsk (Russian Federation); Svetukhin, V. [Ulyanovsk State University, Research Institute of Technology, 42 Leo Tolstoy St., 432970 Ulyanovsk (Russian Federation); Gaganidze, E. [Karlsruhe Institute of Technology, Institute for Applied Materials, Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Karlsruhe (Germany)

    2013-11-15

    The paper reports simulation of cascades in Fe–9 at.%Cr binary alloy containing chromium-rich clusters. The simulation is performed by the molecular dynamics method at the initial temperature of 300 K and primary knock-on atom energy of 15 and 20 keV. Spherical clusters containing 95 at.% of Cr with diameter of 1–5 nm have been considered. The properties of cascade evolution in the presence of chromium-rich cluster are studied. It is shown that these clusters tend to dissolve in collision cascades. However, clusters with diameter of ⩾3 nm exhibit only slight modifications and can be considered stable. Parameters of small (1–2 nm) clusters can change significantly and, in some cases, a 1 nm cluster can be totally dissolved.

  14. Rotation of small clusters in sheared metallic glasses

    International Nuclear Information System (INIS)

    Delogu, Francesco

    2011-01-01

    Graphical abstract: When a Cu 50 Ti 50 metallic glass is shear-deformed, the irreversible rearrangement of local structures allows the rigid body rotation of clusters. Highlights: → A shear-deformed Cu 50 Ti 50 metallic glass was studied by molecular dynamics. → Atomic displacements occur at irreversible rearrangements of local structures. → The dynamics of such events includes the rigid body rotation of clusters. → Relatively large clusters can undergo two or more complete rotations. - Abstract: Molecular dynamics methods were used to simulate the response of a Cu 50 Ti 50 metallic glass to shear deformation. Attention was focused on the atomic displacements taking place during the irreversible rearrangement of local atomic structures. It is shown that the apparently disordered dynamics of such events hides the rigid body rotation of small clusters. Cluster rotation was investigated by evaluating rotation angle, axis and lifetimes. This permitted to point out that relatively large clusters can undergo two or more complete rotations.

  15. Thermodynamics of Pore Filling Metal Clusters in Metal Organic Frameworks: Pd in UiO-66

    DEFF Research Database (Denmark)

    Vilhelmsen, Lasse; Sholl, David S.

    2012-01-01

    Metal organic frameworks (MOFs) have experimentally been demonstrated to be capable of supporting isolated transition-metal clusters, but the stability of these clusters with respect to aggregation is unclear. In this letter we use a genetic algorithm together with density functional theory...... calculations to predict the structure of Pd clusters in UiO-66. The cluster sizes examined are far larger than those in any previous modeling studies of metal clusters in MOFs and allow us to test the hypothesis that the physically separated cavities in UiO-66 could stabilize isolated Pd clusters. Our...... calculations show that Pd clusters in UiO-66 are, at best, metastable and will aggregate into connected pore filling structures at equilibrium....

  16. Constraints on the Richness-Mass Relation and the Optical-SZE Positional Offset Distribution for SZE-Selected Clusters

    CERN Document Server

    Saro, A; Rozo, E; Benson, B A; Mohr, J; Rykoff, E S; Soares-Santos, M; Bleem, L; Dodelson, S; Melchior, P; Sobreira, F; Upadhyay, V; Weller, J; Abbott, T; Abdalla, F B; Allam, S; Armstrong, R; Banerji, M; Bauer, A H; Bayliss, M; Benoit-Lévy, A; Bernstein, G M; Bertin, E; Brodwin, M; Brooks, D; Buckley-Geer, E; Burke, D L; Carlstrom, J E; Capasso, R; Capozzi, D; Carnero Rosell, A; Carrasco Kind, M; Chiu, I; Covarrubias, R; Crawford, T M; Crocce, M; D'Andrea, C B; da Costa, L N; DePoy, D L; Desai, S; de Haan, T; Diehl, H T; Dietrich, J P; Doel, P; Cunha, C E; Eifler, T F; Evrard, A E; Fausti Neto, A; Fernandez, E; Flaugher, B; Fosalba, P; Frieman, J; Gangkofner, C; Gaztanaga, E; Gerdes, D; Gruen, D; Gruendl, R A; Gupta, N; Hennig, C; Holzapfel, W L; Honscheid, K; Jain, B; James, D; Kuehn, K; Kuropatkin, N; Lahav, O; Li, T S; Lin, H; Maia, M A G; March, M; Marshall, J L; Martini, Paul; McDonald, M; Miller, C J; Miquel, R; Nord, B; Ogando, R; Plazas, A A; Reichardt, C L; Romer, A K; Roodman, A; Sako, M; Sanchez, E; Schubnell, M; Sevilla, I; Smith, R C; Stalder, B; Stark, A A; Strazzullo, V; Suchyta, E; Swanson, M E C; Tarle, G; Thaler, J; Thomas, D; Tucker, D; Vikram, V; von der Linden, A; Walker, A R; Wechsler, R H; Wester, W; Zenteno, A; Ziegler, K E

    2015-01-01

    We cross-match galaxy cluster candidates selected via their Sunyaev-Zel'dovich effect (SZE) signatures in 129.1 deg$^2$ of the South Pole Telescope 2500d SPT-SZ survey with optically identified clusters selected from the Dark Energy Survey (DES) science verification data. We identify 25 clusters between $0.1\\lesssim z\\lesssim 0.8$ in the union of the SPT-SZ and redMaPPer (RM) samples. RM is an optical cluster finding algorithm that also returns a richness estimate for each cluster. We model the richness $\\lambda$-mass relation with the following function $\\langle\\ln\\lambda|M_{500}\\rangle\\propto B_\\lambda\\ln M_{500}+C_\\lambda\\ln E(z)$ and use SPT-SZ cluster masses and RM richnesses $\\lambda$ to constrain the parameters. We find $B_\\lambda= 1.14^{+0.21}_{-0.18}$ and $C_\\lambda=0.73^{+0.77}_{-0.75}$. The associated scatter in mass at fixed richness is $\\sigma_{\\ln M|\\lambda} = 0.18^{+0.08}_{-0.05}$ at a characteristic richness $\\lambda=70$. We demonstrate that our model provides an adequate description of the ma...

  17. On the kinematic separation of field and cluster stars across the bulge globular NGC 6528

    Energy Technology Data Exchange (ETDEWEB)

    Lagioia, E. P.; Bono, G.; Buonanno, R. [Dipartimento di Fisica, Università degli Studi di Roma-Tor Vergata, via della Ricerca Scientifica 1, I-00133 Roma (Italy); Milone, A. P. [Research School of Astronomy and Astrophysics, The Australian National University, Cotter Road, Weston, ACT 2611 (Australia); Stetson, P. B. [Dominion Astrophysical Observatory, Herzberg Institute of Astrophysics, National Research Council, 5071 West Saanich Road, Victoria, BC V9E 2E7 (Canada); Prada Moroni, P. G. [Dipartimento di Fisica, Università di Pisa, I-56127 Pisa (Italy); Dall' Ora, M. [INAF-Osservatorio Astronomico di Capodimonte, Salita Moiariello 16, I-80131 Napoli (Italy); Aparicio, A.; Monelli, M. [Instituto de Astrofìsica de Canarias, E-38200 La Laguna, Tenerife, Canary Islands (Spain); Calamida, A.; Ferraro, I.; Iannicola, G. [INAF-Osservatorio Astronomico di Roma, Via Frascati 33, I-00044 Monte Porzio Catone (Italy); Gilmozzi, R. [European Southern Observatory, Karl-Schwarzschild-Straße 2, D-85748 Garching (Germany); Matsunaga, N. [Kiso Observatory, Institute of Astronomy, School of Science, The University of Tokyo, 10762-30, Mitake, Kiso-machi, Kiso-gun, 3 Nagano 97-0101 (Japan); Walker, A., E-mail: eplagioia@roma2.infn.it [Cerro Tololo Inter-American Observatory, National Optical Astronomy Observatory, Casilla 603, La Serena (Chile)

    2014-02-10

    We present deep and precise multi-band photometry of the Galactic bulge globular cluster NGC 6528. The current data set includes optical and near-infrared images collected with ACS/WFC, WFC3/UVIS, and WFC3/IR on board the Hubble Space Telescope. The images cover a time interval of almost 10 yr, and we have been able to carry out a proper-motion separation between cluster and field stars. We performed a detailed comparison in the m {sub F814W}, m {sub F606W} – m {sub F814W} color-magnitude diagram with two empirical calibrators observed in the same bands. We found that NGC 6528 is coeval with and more metal-rich than 47 Tuc. Moreover, it appears older and more metal-poor than the super-metal-rich open cluster NGC 6791. The current evidence is supported by several diagnostics (red horizontal branch, red giant branch bump, shape of the sub-giant branch, slope of the main sequence) that are minimally affected by uncertainties in reddening and distance. We fit the optical observations with theoretical isochrones based on a scaled-solar chemical mixture and found an age of 11 ± 1 Gyr and an iron abundance slightly above solar ([Fe/H] = +0.20). The iron abundance and the old cluster age further support the recent spectroscopic findings suggesting a rapid chemical enrichment of the Galactic bulge.

  18. Strengthening from Nb-rich clusters in a Nb-microalloyed steel

    International Nuclear Information System (INIS)

    Xie, Kelvin Y.; Zheng, Tianxiao; Cairney, Julie M.; Kaul, Harold; Williams, James G.; Barbaro, Frank J.; Killmore, Chris R.; Ringer, Simon P.

    2012-01-01

    We demonstrate that a Nb-microalloyed ultra-thin cast strip steel can be strengthened substantially without compromising ductility by performing a simple heat treatment at 700 °C for 4 min. The strengthening was attributed to a fine dispersion of Nb-rich solute atom clusters. These clusters had an average size of ∼60 atoms at peak hardness and resembled Guinier–Preston zones in Al–Cu alloys. The application of the Ashby–Orowan equation indicates that these clusters are potent strengthening agents when compared to conventional Nb(C,N) precipitation strengthening.

  19. New open cluster candidates discovered in the XSTPS-GAC survey

    Science.gov (United States)

    Guo, Jin-Cheng; Zhang, Hua-Wei; Zhang, Hui-Hua; Liu, Xiao-Wei; Yuan, Hai-Bo; Huang, Yang; Wang, Song; Chen, Li; Zhao, Hai-Bin; Liu, Ji-Feng; Chen, Bing-Qiu; Xiang, Mao-Sheng; Tian, Zhi-Jia; Huo, Zhi-Ying; Wang, Chun

    2018-03-01

    The Xuyi Schmidt Telescope Photometric Survey of the Galactic Anti-center (XSTPS-GAC) is a photometric sky survey that covers nearly 6000 deg2 towards the Galactic Anti-center (GAC) in the g, r, i bands. Half of its survey field is located on the Galactic Anti-center disk, which makes XSTPS-GAC highly suitable to search for new open clusters in the GAC region. In this paper, we report new open cluster candidates discovered in this survey, as well as properties of these open cluster candidates, such as age, distance and reddening, derived by isochrone fitting in the color-magnitude diagram (CMD). These open cluster candidates are stellar density peaks detected in the star density maps by applying the method from Koposov et al. Each candidate is inspected in terms of its true color image composed from three XSTPS-GAC band images. Then its CMD is checked, in order to identify whether the central region stars have a clear isochrone-like trend differing from background stars. The parameters derived from isochrone fitting for these candidates are mainly based on three band photometry of XSTPS-GAC. Moreover, when these new candidates are able to be seen clearly in 2MASS data, their parameters are also derived based on the 2MASS (J – H, J) CMD. There are a total of 320 known open clusters rediscovered and 24 new open cluster candidates discovered in this work. Furthermore, the parameters of these new candidates, as well as another 11 previously known open clusters, are properly determined for the first time.

  20. Canopy cover negatively affects arboreal ant species richness in a tropical open habitat

    Directory of Open Access Journals (Sweden)

    A. C. M. Queiroz

    Full Text Available Abstract We tested the hypothesis of a negative relationship between vegetation characteristics and ant species richness in a Brazilian open vegetation habitat, called candeial. We set up arboreal pitfalls to sample arboreal ants and measured the following environmental variables, which were used as surrogate of environmental heterogeneity: tree richness, tree density, tree height, circumference at the base of the plants, and canopy cover. Only canopy cover had a negative effect on the arboreal ant species richness. Vegetation characteristics and plant species composition are probably homogeneous in candeial, which explains the lack of relationship between other environmental variables and ant richness. Open vegetation habitats harbor a large number of opportunistic and generalist species, besides specialist ants from habitats with high temperatures. An increase in canopy cover decreases sunlight incidence and may cause local microclimatic differences, which negatively affect the species richness of specialist ants from open areas. Canopy cover regulates the richness of arboreal ants in open areas, since only few ant species are able to colonize sites with dense vegetation; most species are present in sites with high temperature and luminosity. Within open vegetation habitats the relationship between vegetation characteristics and species richness seems to be the opposite from closed vegetation areas, like forests.

  1. Low frequency radio observations of five rich clusters of galaxies

    International Nuclear Information System (INIS)

    Hanisch, R.J.; Erickson, W.C.

    1980-01-01

    Observations have been made at 43.0 and 73.8 MHz of five rich x-ray emitting clusters of galaxies: Abell 399/401, Abell 426 (the Perseus cluster), Abell 1367, Abell 1656 (the Coma cluster), and the Virgo cluster. A fan beam synthesis system has been used to search for extended radio emission, i.e., radio halos, in these clusters. Radio halos were detected in the Coma and Virgo clusters. No evidence was found for the existence of 3C84B, the halo source previously thought to exist in the Perseus cluster. If halo sources exist in Abell 399/401 or Abell 1367, they must be quite weak at frequencies less than 100 MHz. The observed sizes of the extended sources in Coma and Virgo imply that the rate of particle propagation away from strong radio galaxies greatly exceeds the Alfven velocity and is probably independent of particle energy

  2. Complexation-Induced Phase Separation: Preparation of Metal-Rich Polymeric Membranes

    KAUST Repository

    Villalobos Vazquez de la Parra, Luis Francisco

    2017-08-01

    The majority of state-of-the-art polymeric membranes for industrial or medical applications are fabricated by phase inversion. Complexation induced phase separation (CIPS)—a surprising variation of this well-known process—allows direct fabrication of hybrid membranes in existing facilities. In the CIPS process, a first step forms the thin metal-rich selective layer of the membrane, and a succeeding step the porous support. Precipitation of the selective layer takes place in the same solvent used to dissolve the polymer and is induced by a small concentration of metal ions. These ions form metal-coordination-based crosslinks leading to the formation of a solid skin floating on top of the liquid polymer film. A subsequent precipitation in a nonsolvent bath leads to the formation of the porous support structure. Forming the dense layer and porous support by different mechanisms while maintaining the simplicity of a phase inversion process, results in unprecedented control over the final structure of the membrane. The thickness and morphology of the dense layer as well as the porosity of the support can be controlled over a wide range by manipulating simple process parameters. CIPS facilitates control over (i) the thickness of the dense layer throughout several orders of magnitude—from less than 15 nm to more than 6 μm, (ii) the type and amount of metal ions loaded in the dense layer, (iii) the morphology of the membrane surface, and (iv) the porosity and structure of the support. The nature of the CIPS process facilitates a precise loading of a high concentration of metal ions that are located in only the top layer of the membrane. Moreover, these metal ions can be converted—during the membrane fabrication process—to nanoparticles or crystals. This simple method opens up fascinating possibilities for the fabrication of metal-rich polymeric membranes with a new set of properties. This dissertation describes the process in depth and explores promising

  3. STAR CLUSTERS IN M31. II. OLD CLUSTER METALLICITIES AND AGES FROM HECTOSPEC DATA

    International Nuclear Information System (INIS)

    Caldwell, Nelson; Schiavon, Ricardo; Morrison, Heather; Harding, Paul; Rose, James A.

    2011-01-01

    We present new high signal-to-noise spectroscopic data on the M31 globular cluster (GC) system, obtained with the Hectospec multifiber spectrograph on the 6.5 m MMT. More than 300 clusters have been observed at a resolution of 5 A and with a median S/N of 75 per A, providing velocities with a median uncertainty of 6 km s -1 . The primary focus of this paper is the determination of mean cluster metallicities, ages, and reddenings. Metallicities were estimated using a calibration of Lick indices with [Fe/H] provided by Galactic GCs. These match well the metallicities of 24 M31 clusters determined from Hubble Space Telescope color-magnitude diagrams, the differences having an rms of 0.2 dex. The metallicity distribution is not generally bimodal, in strong distinction with the bimodal Galactic globular distribution. Rather, the M31 distribution shows a broad peak, centered at [Fe/H] = -1, possibly with minor peaks at [Fe/H] = -1.4, -0.7, and -0.2, suggesting that the cluster systems of M31 and the Milky Way had different formation histories. Ages for clusters with [Fe/H] > - 1 were determined using the automatic stellar population analysis program EZ A ges. We find no evidence for massive clusters in M31 with intermediate ages, those between 2 and 6 Gyr. Moreover, we find that the mean ages of the old GCs are remarkably constant over about a decade in metallicity (-0.95∼< [Fe/H] ∼<0.0).

  4. Manipulating Light with Transition Metal Clusters, Organic Dyes, and Metal Organic Frameworks

    Energy Technology Data Exchange (ETDEWEB)

    Ogut, Serdar [Univ. of Illinois, Chicago, IL (United States)

    2017-09-11

    The primary goals of our research program is to develop and apply state-of-the-art first-principles methods to predict electronic and optical properties of three systems of significant scientific and technological interest: transition metal clusters, organic dyes, and metal-organic frameworks. These systems offer great opportunities to manipulate light for a wide ranging list of energy-related scientific problems and applications. During this grant period, we focused our investigations on the development, implementation, and benchmarking of many-body Green’s function methods (GW approximation and the Bethe-Salpeter equation) to examine excited-state properties of transition metal/transition-metal-oxide clusters and organic molecules that comprise the building blocks of dyes and metal-organic frameworks.

  5. Yellow supergiants in open clusters

    International Nuclear Information System (INIS)

    Sowell, J.R.

    1986-01-01

    Superluminous giant stars (SLGs) have been reported in young globular clusters in the Large Magellanic Cloud (LMC). These stars appear to be in the post-asymptotic-giant-branch phase of evolution. This program was an investigation of galactic SLG candidates in open clusters, which are more like the LMC young globular clusters. These were chosen because luminosity, mass, and age determinations can be made for members since cluster distances and interstellar reddenings are known. Color magnitude diagrams were searched for candidates, using the same selection criteria as for SLGs in the LMC. Classification spectra were obtained of 115 program stars from McGraw-Hill Observatory and of 68 stars from Cerro Tololo Inter-American Observatory Chile. These stars were visually classified on the MK system using spectral scans of standard stars taken at the respective observations. Published information was combined with this program's data for 83 stars in 30 clusters. Membership probabilities were assigned to these stars, and the clusters were analyzed according to age. It was seen that the intrinsically brightest supergiants are found in the youngest clusters. With increasing cluster age, the absolute luminosities attained by the supergiants decline. Also, it appears that the evolutionary tracks of luminosity class II stars are more similar to those of class I than of class III

  6. The atomic structure of transition metal clusters

    International Nuclear Information System (INIS)

    Riley, S.J.

    1995-01-01

    Chemical reactions are used to probe the atomic (geometrical) structure of isolated clusters of transition metal atoms. The number of adsorbate molecules that saturate a cluster, and/or the binding energy of molecules to cluster surfaces, are determined as a function of cluster size. Systematics in these properties often make it possible to propose geometrical structures consistent with the experimental observations. We will describe how studies of the reactions of cobalt and nickel clusters with ammonia, water, and nitrogen provide important and otherwise unavailable structural information. Specifically, small (less than 20 atoms) clusters of cobalt and nickel atoms adopt entirely different structures, the former having packing characteristic of the bulk and the latter having pentagonal symmetry. These observations provide important input for model potentials that attempt to describe the local properties of transition metals. In particular, they point out the importance of a proper treatment of d-orbital binding in these systems, since cobalt and nickel differ so little in their d-orbital occupancy

  7. Self-assembled metal clusters on an alumina nanomesh

    International Nuclear Information System (INIS)

    Buchsbaum, A.

    2012-01-01

    Template mediated growth of metals has attracted much interest due to the remarkable magnetic and catalytic properties of clusters in the nanometer range and provides the opportunity to grow clusters with narrow size distributions. When the Ni3Al(111) surface is exposed to oxygen at elevated temperature a thin oxide film with a well-defined structure and uniform thickness grows and covers the alloy surface completely. The structure of the alumina film has been solved mainly by the help of scanning tunneling microscopy (STM) combined with density functional theory (DFT) calculations. The structure of the approx. 0.5 nm thick oxide film has sixfold symmetry and exhibits holes with a diameter of approx. 400 pm reaching down to the metal substrate at the corners of the (Sqrt(67) x Sqrt(67))R12.2° unit cell. The side length of the unit cell is 4.1 nm. The driving force for the formation of the oxide nanomesh is the reduction of the metal/oxide interface energy by the formation of energetically favorable Al-Ni bonds at the interface. Due to better wetting of metal on metal surfaces than on oxide surfaces, metal atoms prefer to bind to the substrate in the hole, not to the oxide. Therefore the oxide forms a template with a hexagonal 4.1 nm lattice for the growth of well-ordered metal clusters. Nevertheless, the growth of most metal clusters on top of the corner holes is not straightforward. Fe and Co atoms cannot jump into the corner holes due to a barrier for diffusion and nucleate at their second favorable adsorption site. However, Pd atoms trapped in these corner holes reduce the barrier for diffusion and create metallic nucleation sites where Fe as well as Co clusters can nucleate and form a well-ordered hexagonal arrangement on the oxide nanomesh. We have studied these Fe and Co clusters and applied different methods like STM and surface x-ray diffraction (SXRD) to determine the morphology and crystallography of the clusters. For Fe we found cluster growth with

  8. Gemini spectroscopy of the outer disk star cluster BH176

    Science.gov (United States)

    Sharina, M. E.; Donzelli, C. J.; Davoust, E.; Shimansky, V. V.; Charbonnel, C.

    2014-10-01

    Context. BH176 is an old metal-rich star cluster. It is spatially and kinematically consistent with belonging to the Monoceros Ring. It is larger in size and more distant from the Galactic plane than typical open clusters, and it does not belong to the Galactic bulge. Aims: Our aim is to determine the origin of this unique object by accurately determining its distance, metallicity, and age. The best way to reach this goal is to combine spectroscopic and photometric methods. Methods: We present medium-resolution observations of red clump and red giant branch stars in BH176 obtained with the Gemini South Multi-Object Spectrograph. We derive radial velocities, metallicities, effective temperatures, and surface gravities of the observed stars and use these parameters to distinguish member stars from field objects. Results: We determine the following parameters for BH176: Vh = 0 ± 15 km s-1, [Fe/H] = -0.1 ± 0.1, age 7 ± 0.5 Gyr, E(V - I) = 0.79 ± 0.03, distance 15.2 ± 0.2 kpc, α-element abundance [α/Fe] ~ 0.25 dex (the mean of [Mg/Fe], and [Ca/Fe]). Conclusions: BH176 is a member of old Galactic open clusters that presumably belong to the thick disk. It may have originated as a massive star cluster after the encounter of the forming thin disk with a high-velocity gas cloud or as a satellite dwarf galaxy. Appendix A is available in electronic form at http://www.aanda.org

  9. X-ray Observations of Eight Young Open Star Clusters: I ...

    Indian Academy of Sciences (India)

    XMM-Newton View of Eight Young Open Star Clusters. 395 ... Multi-wavelength surveys of young open clusters provide an effective way to iden- tify young cluster .... First, the input images were built in two energy ranges, a soft band (0.3–2.0 keV) and ..... 3.2 Color-magnitude diagram of X-ray sources with NIR counterparts.

  10. Metal nanostructures: from clusters to nanocatalysis and sensors

    Science.gov (United States)

    Smirnov, B. M.

    2017-12-01

    The properties of metal clusters and nanostructures composed of them are reviewed. Various existing methods for the generation of intense beams of metal clusters and their subsequent conversion into nanostructures are compared. Processes of the flow of a buffer gas with active molecules through a nanostructure are analyzed as a basis of using nanostructures for catalytic applications. The propagation of an electric signal through a nanostructure is studied by analogy with a macroscopic metal. An analysis is given of how a nanostructure changes its resistance as active molecules attach to its surface and are converted into negative ions. These negative ions induce the formation of positively charged vacancies inside the metal conductor and attract the vacancies to together change the resistance of the metal nanostructure. The physical basis is considered for using metal clusters and nanostructures composed of them to create new materials in the form of a porous metal film on the surface of an object. The fundamentals of nanocatalysis are reviewed. Semiconductor conductometric sensors consisting of bound nanoscale grains or fibers acting as a conductor are compared with metal sensors conducting via a percolation cluster, a fractal fiber, or a bunch of interwoven nanofibers formed in superfluid helium. It is shown that sensors on the basis of metal nanostructures are characterized by a higher sensitivity than semiconductor ones, but are not selective. Measurements using metal sensors involve two stages, one of which measures to high precision the attachment rate of active molecules to the sensor conductor, and in the other one the surface of metal nanostructures is cleaned from the attached molecules using a gas discharge plasma (in particular, capillary discharge) with a subsequent chromatography analysis for products of cleaning.

  11. An updated survey of globular clusters in M 31. III. A spectroscopic metallicity scale for the Revised Bologna Catalog

    Science.gov (United States)

    Galleti, S.; Bellazzini, M.; Buzzoni, A.; Federici, L.; Fusi Pecci, F.

    2009-12-01

    Aims. We present a new homogeneous set of metallicity estimates based on Lick indices for the old globular clusters of the M 31 galaxy. The final aim is to add homogeneous spectroscopic metallicities to as many entries as possible of the Revised Bologna Catalog of M 31 clusters, by reporting Lick index measurements from any source (literature, new observations, etc.) on the same scale. Methods: New empirical relations of [Fe/H] as a function of [MgFe] and Mg2 indices are based on the well-studied galactic globular clusters, complemented with theoretical model predictions for -0.2≤ [Fe/H]≤ +0.5. Lick indices for M 31 clusters from various literature sources (225 clusters) and from new observations by our team (71 clusters) have been transformed into the Trager et al. system, yielding new metallicity estimates for 245 globular clusters of M 31. Results: Our values are in good agreement with recent estimates based on detailed spectral fitting and with those obtained from color magnitude diagrams of clusters imaged with the Hubble Space Telescope. The typical uncertainty on individual estimates is ≃±0.25 dex, as resulted from the comparison with metallicities derived from color magnitude diagrams of individual clusters. Conclusions: The metallicity distribution of M 31 globular cluster is briefly discussed and compared with that of the Milky Way. Simple parametric statistical tests suggest that the distribution is probably not unimodal. The strong correlation between metallicity and kinematics found in previous studies is confirmed. The most metal-rich GCs tend to be packed into the center of the system and to cluster tightly around the galactic rotation curve defined by the HI disk, while the velocity dispersion about the curve increases with decreasing metallicity. However, also the clusters with [Fe/H]<-1.0 display a clear rotation pattern, at odds with their Milky Way counterparts. Based on observations made at La Palma, at the Spanish Observatorio del Roque

  12. AGES AND METALLICITIES OF CLUSTER GALAXIES IN A779 USING MODIFIED STROeMGREN PHOTOMETRY

    Energy Technology Data Exchange (ETDEWEB)

    Sreedhar, Yuvraj Harsha; Rakos, Karl D.; Hensler, Gerhard; Zeilinger, Werner W. [University of Vienna, Institute of Astronomy, Tuerkenschanzstrasse 17, A-1180 Vienna (Austria); Odell, Andrew P. [Department of Physics and Astronomy, Northern Arizona University, Flagstaff, AZ (United States)

    2012-03-01

    In the quest for the formation and evolution of galaxy clusters, Rakos and co-workers introduced a spectrophotometric method using modified Stroemgren photometry, but with the considerable debate toward the project's abilities, we re-introduce the system by testing for the repeatability of the modified Stroemgren colors and compare them with the Stroemgren colors, and check for the reproducibility of the ages and metallicities (using the Principle Component Analysis (PCA) technique and the GALEV models) for the six common galaxies in all three A779 data sets. As a result, a fair agreement between two filter systems was found to produce similar colors (with a precision of 0.09 mag in (uz - vz), 0.02 mag in (bz - yz), and 0.03 mag in (vz - vz)) and the generated ages and metallicities are also similar (with an uncertainty of 0.36 Gyr and 0.04 dex from PCA and 0.44 Gyr and 0.2 dex using the GALEV models). We infer that the technique is able to relieve the age-metallicity degeneracy by separating the age effects from the metallicity effects, but it is still unable to completely eliminate it. We further extend this paper to re-study the evolution of galaxies in the low mass, dynamically poor A779 cluster (as it was not elaborately analyzed by Rakos and co-workers in their previous work) by correlating the luminosity (mass), density, and radial distance with the estimated age, metallicity, and the star formation history. Our results distinctly show the bimodality of the young, low-mass, metal-poor population with a mean age of 6.7 Gyr ({+-} 0.5 Gyr) and the old, high-mass, metal-rich galaxies with a mean age of 9 Gyr ({+-} 0.5 Gyr). The method also observes the color evolution of the blue cluster galaxies to red (Butcher-Oemler phenomenon), and the downsizing phenomenon. Our analysis shows that modified Stroemgren photometry is very well suited for studying low- and intermediate-z clusters, as it is capable of observing deeper with better spatial resolution at

  13. Infrared Multiple Photon Dissociation Spectroscopy Of Metal Cluster-Adducts

    Science.gov (United States)

    Cox, D. M.; Kaldor, A.; Zakin, M. R.

    1987-01-01

    Recent development of the laser vaporization technique combined with mass-selective detection has made possible new studies of the fundamental chemical and physical properties of unsupported transition metal clusters as a function of the number of constituent atoms. A variety of experimental techniques have been developed in our laboratory to measure ionization threshold energies, magnetic moments, and gas phase reactivity of clusters. However, studies have so far been unable to determine the cluster structure or the chemical state of chemisorbed species on gas phase clusters. The application of infrared multiple photon dissociation IRMPD to obtain the IR absorption properties of metal cluster-adsorbate species in a molecular beam is described here. Specifically using a high power, pulsed CO2 laser as the infrared source, the IRMPD spectrum for methanol chemisorbed on small iron clusters is measured as a function of the number of both iron atoms and methanols in the complex for different methanol isotopes. Both the feasibility and potential utility of IRMPD for characterizing metal cluster-adsorbate interactions are demonstrated. The method is generally applicable to any cluster or cluster-adsorbate system dependent only upon the availability of appropriate high power infrared sources.

  14. Intergalactic stellar populations in intermediate redshift clusters

    Science.gov (United States)

    Melnick, J.; Giraud, E.; Toledo, I.; Selman, F.; Quintana, H.

    2012-11-01

    A substantial fraction of the total stellar mass in rich clusters of galaxies resides in a diffuse intergalactic component usually referred to as the intracluster light (ICL). Theoretical models indicate that these intergalactic stars originate mostly from the tidal interaction of the cluster galaxies during the assembly history of the cluster, and that a significant fraction of these stars could have formed in situ from the late infall of cold metal-poor gas clouds on to the cluster. However, these models also overpredict the fraction of stellar mass in the ICL by a substantial margin, something that is still not well understood. The models also make predictions about the age distribution of the ICL stars, which may provide additional observational constraints. Here we present population synthesis models for the ICL of an intermediate redshift (z = 0.29) X-ray cluster that we have extensively studied in previous papers. The advantage of observing intermediate redshift clusters rather than nearby ones is that the former fit the field of view of multi-object spectrographs in 8-m telescopes and therefore permit us to encompass most of the ICL with only a few well-placed slits. In this paper we show that by stacking spectra at different locations within the ICL it is possible to reach sufficiently high signal-to-noise ratios to fit population synthesis models and derive meaningful results. The models provide ages and metallicities for the dominant populations at several different locations within the ICL and the brightest cluster galaxies (BCG) halo, as well as measures of the kinematics of the stars as a function of distance from the BCG. We thus find that the ICL in our cluster is dominated by old metal-rich stars, at odds with what has been found in nearby clusters where the stars that dominate the ICL are old and metal poor. While we see weak evidence of a young, metal-poor component, if real, these young stars would amount to less than 1 per cent of the total ICL

  15. Energetics of charged metal clusters containing vacancies

    Science.gov (United States)

    Pogosov, Valentin V.; Reva, Vitalii I.

    2018-01-01

    We study theoretically large metal clusters containing vacancies. We propose an approach, which combines the Kohn-Sham results for monovacancy in a bulk of metal and analytical expansions in small parameters cv (relative concentration of vacancies) and RN,v -1, RN ,v being cluster radii. We obtain expressions of the ionization potential and electron affinity in the form of corrections to electron work function, which require only the characteristics of 3D defect-free metal. The Kohn-Sham method is used to calculate the electron profiles, ionization potential, electron affinity, electrical capacitance; dissociation, cohesion, and monovacancy-formation energies of the small perfect clusters NaN, MgN, AlN (N ≤ 270) and the clusters containing a monovacancy (N ≥ 12) in the stabilized-jellium model. The quantum-sized dependences for monovacancy-formation energies are calculated for the Schottky scenario and the "bubble blowing" scenario, and their asymptotic behavior is also determined. It is shown that the asymptotical behaviors of size dependences for these two mechanisms differ from each other and weakly depend on the number of atoms in the cluster. The contribution of monovacancy to energetics of charged clusters and the size dependences of their characteristics and asymptotics are discussed. It is shown that the difference between the characteristics for the neutral and charged clusters is entirely determined by size dependences of ionization potential and electron affinity. Obtained analytical dependences may be useful for the analysis of the results of photoionization experiments and for the estimation of the size dependences of the vacancy concentration including the vicinity of the melting point.

  16. Simulation of old open clusters for UVIT on ASTROSAT

    International Nuclear Information System (INIS)

    Sindhu, N; Anu Radha, C; Annapurni, Subramaniam

    2015-01-01

    The Ultra Violet Imaging Telescope (UVIT) is one of the payloads on the first Indian multiwavelength satellite ASTROSAT, which is expected to be launched by the Indian Space Research Organisation (ISRO) in the year 2015. We have performed simulations of UV studies of old open clusters for the UVIT. The colour magnitude diagrams (CMDs) and spatial appearances have been created using 10 filters associated with the FUV channel (130–180 nm) and NUV channel (200–300 nm) that are available for observations on the UVIT, for the three old open clusters M67, NGC 188 and NGC 6791. The CMDs are simulated for different filter combinations, and they are used to identify the loci of various evolutionary sequences, white dwarfs, blue stragglers, red giants, subgiants, turn off stars and the main sequence of the clusters. The present work helps in identifying a potential area of study in the case of these three old open clusters by considering the availability of filters and the detection limits of the instrument. We also recommend filter combinations, which can be used to detect and study the above mentioned evolutionary stages. The simulations and the results presented here are essential for the optimal use of the UVIT for studies of old open clusters. (paper)

  17. Low-energy electron collisions with metal clusters: Electron capture and cluster fragmentation

    International Nuclear Information System (INIS)

    Kresin, V.V.; Scheidemann, A.; Knight, W.D.

    1993-01-01

    The authors have carried out the first measurement of absolute cross sections for the interaction between electrons and size-resolved free metal clusters. Integral inelastic scattering cross sections have been determined for electron-Na n cluster collisions in the energy range from 0.1 eV to 30 eV. At energies ≤1 eV, cross sections increase with decreasing impact energies, while at higher energies they remain essentially constant. The dominant processes are electron attachment in the low-energy range, and collision-induced fragmentation at higher energies. The magnitude of electron capture cross sections can be quantitatively explained by the effect of the strong polarization field induced in the cluster by the incident electron. The cross sections are very large, reaching values of hundreds of angstrom 2 ; this is due to the highly polarizable nature of metal clusters. The inelastic interaction range for fragmentation collisions is also found to considerably exceed the cluster radius, again reflecting the long-range character of electron-cluster interactions. The important role played by the polarization interaction represents a bridge between the study of collision processes and the extensive research on cluster response properties. Furthermore, insight into the mechanisms of electron scattering is important for understanding production and detection of cluster ions in mass spectrometry and related processes

  18. Influence of reactive gas admixture on transition metal cluster nucleation in a gas aggregation cluster source

    Science.gov (United States)

    Peter, Tilo; Polonskyi, Oleksandr; Gojdka, Björn; Mohammad Ahadi, Amir; Strunskus, Thomas; Zaporojtchenko, Vladimir; Biederman, Hynek; Faupel, Franz

    2012-12-01

    We quantitatively assessed the influence of reactive gases on the formation processes of transition metal clusters in a gas aggregation cluster source. A cluster source based on a 2 in. magnetron is used to study the production rate of titanium and cobalt clusters. Argon served as working gas for the DC magnetron discharge, and a small amount of reactive gas (oxygen and nitrogen) is added to promote reactive cluster formation. We found that the cluster production rate depends strongly on the reactive gas concentration for very small amounts of reactive gas (less than 0.1% of total working gas), and no cluster formation takes place in the absence of reactive species. The influence of discharge power, reactive gas concentration, and working gas pressure are investigated using a quartz micro balance in a time resolved manner. The strong influence of reactive gas is explained by a more efficient formation of nucleation seeds for metal-oxide or nitride than for pure metal.

  19. Reanalysis of 24 Nearby Open Clusters using Gaia data

    Science.gov (United States)

    Yen, Steffi X.; Reffert, Sabine; Röser, Siegfried; Schilbach, Elena; Kharchenko, Nina V.; Piskunov, Anatoly E.

    2018-04-01

    We have developed a fully automated cluster characterization pipeline, which simultaneously determines cluster membership and fits the fundamental cluster parameters: distance, reddening, and age. We present results for 24 established clusters and compare them to literature values. Given the large amount of stellar data for clusters available from Gaia DR2 in 2018, this pipeline will be beneficial to analyzing the parameters of open clusters in our Galaxy.

  20. Integrated spectral study of small angular diameter galactic open clusters

    Science.gov (United States)

    Clariá, J. J.; Ahumada, A. V.; Bica, E.; Pavani, D. B.; Parisi, M. C.

    2017-10-01

    This paper presents flux-calibrated integrated spectra obtained at Complejo Astronómico El Leoncito (CASLEO, Argentina) for a sample of 9 Galactic open clusters of small angular diameter. The spectra cover the optical range (3800-6800 Å), with a resolution of ˜14 Å. With one exception (Ruprecht 158), the selected clusters are projected into the fourth Galactic quadrant (282o evaluate their membership status. The current cluster sample complements that of 46 open clusters previously studied by our group in an effort to gather a spectral library with several clusters per age bin. The cluster spectral library that we have been building is an important tool to tie studies of resolved and unresolved stellar content.

  1. A High-precision Trigonometric Parallax to an Ancient Metal-poor Globular Cluster

    Science.gov (United States)

    Brown, T. M.; Casertano, S.; Strader, J.; Riess, A.; VandenBerg, D. A.; Soderblom, D. R.; Kalirai, J.; Salinas, R.

    2018-03-01

    Using the Wide Field Camera 3 (WFC3) on the Hubble Space Telescope (HST), we have obtained a direct trigonometric parallax for the nearest metal-poor globular cluster, NGC 6397. Although trigonometric parallaxes have been previously measured for many nearby open clusters, this is the first parallax for an ancient metal-poor population—one that is used as a fundamental template in many stellar population studies. This high-precision measurement was enabled by the HST/WFC3 spatial-scanning mode, providing hundreds of astrometric measurements for dozens of stars in the cluster and also for Galactic field stars along the same sightline. We find a parallax of 0.418 ± 0.013 ± 0.018 mas (statistical, systematic), corresponding to a true distance modulus of 11.89 ± 0.07 ± 0.09 mag (2.39 ± 0.07 ± 0.10 kpc). The V luminosity at the stellar main-sequence turnoff implies an absolute cluster age of 13.4 ± 0.7 ± 1.2 Gyr. Based on observations made with the NASA/ESA Hubble Space Telescope, obtained at the Space Telescope Science Institute, which is operated by the Association of Universities for Research in Astronomy, Inc., under NASA contract NAS 5-26555. These observations are associated with programs GO-13817, GO-14336, and GO-14773.

  2. The old open cluster Melotte 66

    International Nuclear Information System (INIS)

    Hawarden, T.G.

    1976-01-01

    Photoelectric and photographic photometry of the open cluster Melotte 66 is presented. The colour-magnitude (CM) diagram shows most of the characteristics of an old cluster. The giant branch is broad with its blue edge populated preferentially by stars from the outer parts of the cluster. There is no detectable horizontal subgiant sequence. The main sequence turn-off colour, two-colour diagram and the colour difference between the turn-off and the subgiants are used to estimate the age and composition. Melotte 66 appears to have reddening E(B-V) = 0sup(m).17 and ultraviolet excess delta(U-B) approximately 0sup(m).1. The cluster is probably between 6 and 7 x 10 9 yr old. A distance modulus (m-M) 0 =12sup(m).4 is derived, which implies that the cluster lies about 750 pc from the galactic plane. (author)

  3. Exploring N-Rich Phases in Li(x)N(y) Clusters for Hydrogen Storage at Nanoscale.

    Science.gov (United States)

    Bhattacharya, Amrita; Bhattacharya, Saswata

    2015-09-17

    We have performed cascade genetic algorithm and ab initio atomistic thermodynamics under the framework of first-principles-based hybrid density functional theory to study the (meta-)stability of a wide range of Li(x)N(y) clusters. We found that hybrid xc-functional is essential to address this problem as a local/semilocal functional simply fails even to predict a qualitative prediction. Most importantly, we find that though in bulk lithium nitride, the Li-rich phase, that is, Li3N, is the stable stoichiometry; in small Li(x)N(y) clusters, N-rich phases are more stable at thermodynamic equilibrium. We further show that these N-rich clusters are promising hydrogen storage material because of their easy adsorption and desorption ability at respectively low (≤300 K) and moderately high temperature (≥600 K).

  4. METALS IN THE ICM: WITNESSES OF CLUSTER FORMATION AND EVOLUTION

    Directory of Open Access Journals (Sweden)

    Lorenzo Lovisari

    2013-12-01

    Full Text Available The baryonic composition of galaxy clusters and groups is dominated by a hot, X-ray emitting Intra-Cluster Medium (ICM. The mean metallicity of the ICM has been found to be roughly 0.3 ÷ 0.5 times the solar value, therefore a large fraction of this gas cannot be of purely primordial origin. Indeed, the distribution and amount of metals in the ICM is a direct consequence of the past history of star formation in the cluster galaxies and of the processes responsible for the injection of enriched material into the ICM. We here shortly summarize the current views on the chemical enrichment, focusing on the observational evidence in terms of metallicity measurements in clusters, spatial metallicity distribution and evolution, and expectations from future missions.

  5. Photometry of the rich cluster of galaxies 0004.8-3450

    International Nuclear Information System (INIS)

    Carter, D.

    1980-01-01

    Photographic photometry in b, r and i wavebands of an extremely rich cluster of galaxies at 00sup(h)04sup(m).8 - 34 0 50'is presented. The cluster is centred on an unusually elongated cD galaxy. The brighter members of this cluster tend to lie along the axis of the cD. The luminosity function for 1552 galaxies shows, after application of a suitable correction for non-members, a form more characteristic of loose clusters with some spirals than of clusters with cD galaxies. The colour-magnitude and colour-colour diagrams for a smaller sample of galaxies are discussed. The distributions of very red and blue galaxies show no evidence for a significant proportion of either being cluster members. The cluster probably contains few spirals, although it appears to lie in a supercluster which may contain spirals. A few galaxies are unusually bright in the i band, their properties are discussed briefly. There is some evidence for a deficiency of other elongated galaxies with the same position angle as the cD. The cluster itself is aligned with the cD. (author)

  6. Effectiveness of hydrogen rich water on antioxidant status of subjects with potential metabolic syndrome-an open label pilot study.

    Science.gov (United States)

    Nakao, Atsunori; Toyoda, Yoshiya; Sharma, Prachi; Evans, Malkanthi; Guthrie, Najla

    2010-03-01

    Metabolic syndrome is characterized by cardiometabolic risk factors that include obesity, insulin resistance, hypertension and dyslipidemia. Oxidative stress is known to play a major role in the pathogenesis of metabolic syndrome. The objective of this study was to examine the effectiveness of hydrogen rich water (1.5-2 L/day) in an open label, 8-week study on 20 subjects with potential metabolic syndrome. Hydrogen rich water was produced, by placing a metallic magnesium stick into drinking water (hydrogen concentration; 0.55-0.65 mM), by the following chemical reaction; Mg + 2H(2)O --> Mg (OH)(2) + H(2). The consumption of hydrogen rich water for 8 weeks resulted in a 39% increase (pfasting glucose levels during the 8 week study. In conclusion, drinking hydrogen rich water represents a potentially novel therapeutic and preventive strategy for metabolic syndrome. The portable magnesium stick was a safe, easy and effective method of delivering hydrogen rich water for daily consumption by participants in the study.

  7. Elemental abundances of intermediate-age open cluster NGC 3680

    Science.gov (United States)

    Mitschang, A. W.; De Silva, G. M.; Zucker, D. B.

    2012-06-01

    We present a new abundance analysis of the intermediate-age Galactic open cluster NGC 3680, based on high-resolution, high signal-to-noise ratio VLT/UVES spectroscopic data. Several element abundances are presented for this cluster for the first time, but most notably we derive abundances for the light and heavy s-process elements Y, Ba, La and Nd. The serendipitous measurement of the rare-earth r-process element Gd is also reported. This cluster exhibits a significant enhancement of Na in giants as compared to dwarfs, which may be a proxy for an O to Na anticorrelation as observed in Galactic globular clusters but not open clusters. We also observe a step-like enhancement of heavy s-process elements towards higher atomic number, contrary to expectations from asymptotic giant branch nucleosynthesis models, suggesting that the r process played a significant role in the generation of both La and Nd in this cluster.

  8. Value, Cost, and Sharing: Open Issues in Constrained Clustering

    Science.gov (United States)

    Wagstaff, Kiri L.

    2006-01-01

    Clustering is an important tool for data mining, since it can identify major patterns or trends without any supervision (labeled data). Over the past five years, semi-supervised (constrained) clustering methods have become very popular. These methods began with incorporating pairwise constraints and have developed into more general methods that can learn appropriate distance metrics. However, several important open questions have arisen about which constraints are most useful, how they can be actively acquired, and when and how they should be propagated to neighboring points. This position paper describes these open questions and suggests future directions for constrained clustering research.

  9. Metal Sulfide Cluster Complexes and their Biogeochemical Importance in the Environment

    International Nuclear Information System (INIS)

    Luther, George W.; Rickard, David T.

    2005-01-01

    Aqueous clusters of FeS, ZnS and CuS constitute a major fraction of the dissolved metal load in anoxic oceanic, sedimentary, freshwater and deep ocean vent environments. Their ubiquity explains how metals are transported in anoxic environmental systems. Thermodynamic and kinetic considerations show that they have high stability in oxic aqueous environments, and are also a significant fraction of the total metal load in oxic river waters. Molecular modeling indicates that the clusters are very similar to the basic structural elements of the first condensed phase forming from aqueous solutions in the Fe-S, Zn-S and Cu-S systems. The structure of the first condensed phase is determined by the structure of the cluster in solution. This provides an alternative explanation of Ostwald's Rule, where the most soluble, metastable phases form before the stable phases. For example, in the case of FeS, we showed that the first condensed phase is nanoparticulate, metastable mackinawite with a particle size of 2 nm consisting of about 150 FeS subunits, representing the end of a continuum between aqueous FeS clusters and condensed material. These metal sulfide clusters and nanoparticles are significant in biogeochemistry. Metal sulfide clusters reduce sulfide and metal toxicity and help drive ecology. FeS cluster formation drives vent ecology and AgS cluster formation detoxifies Ag in Daphnia magna neonates. We also note a new reaction between FeS and DNA and discuss the potential role of FeS clusters in denaturing DNA

  10. The same frequency of planets inside and outside open clusters of stars.

    Science.gov (United States)

    Meibom, Søren; Torres, Guillermo; Fressin, Francois; Latham, David W; Rowe, Jason F; Ciardi, David R; Bryson, Steven T; Rogers, Leslie A; Henze, Christopher E; Janes, Kenneth; Barnes, Sydney A; Marcy, Geoffrey W; Isaacson, Howard; Fischer, Debra A; Howell, Steve B; Horch, Elliott P; Jenkins, Jon M; Schuler, Simon C; Crepp, Justin

    2013-07-04

    Most stars and their planets form in open clusters. Over 95 per cent of such clusters have stellar densities too low (less than a hundred stars per cubic parsec) to withstand internal and external dynamical stresses and fall apart within a few hundred million years. Older open clusters have survived by virtue of being richer and denser in stars (1,000 to 10,000 per cubic parsec) when they formed. Such clusters represent a stellar environment very different from the birthplace of the Sun and other planet-hosting field stars. So far more than 800 planets have been found around Sun-like stars in the field. The field planets are usually the size of Neptune or smaller. In contrast, only four planets have been found orbiting stars in open clusters, all with masses similar to or greater than that of Jupiter. Here we report observations of the transits of two Sun-like stars by planets smaller than Neptune in the billion-year-old open cluster NGC6811. This demonstrates that small planets can form and survive in a dense cluster environment, and implies that the frequency and properties of planets in open clusters are consistent with those of planets around field stars in the Galaxy.

  11. The Mean and Scatter of the Velocity Dispersion-Optical Richness Relation for MaxBCG Galaxy Clusters

    Energy Technology Data Exchange (ETDEWEB)

    Becker, M.R.; McKay, T.A.; /Michigan U.; Koester, B.; /Chicago U., Astron. Astrophys. Ctr.; Wechsler, R.H.; /KIPAC, Menlo Park /SLAC /Stanford U., Phys. Dept.; Rozo, E.; /Ohio State U.; Evrard, A.; /Michigan U. /Michigan U., MCTP; Johnston, D.; /Caltech, JPL; Sheldon, E.; /New York U.; Annis, J.; /Fermilab; Lau, E.; /Chicago U., Astron. Astrophys. Ctr.; Nichol, R.; /Portsmouth U., ICG; Miller, C.; /Michigan U.

    2007-06-05

    The distribution of galaxies in position and velocity around the centers of galaxy clusters encodes important information about cluster mass and structure. Using the maxBCG galaxy cluster catalog identified from imaging data obtained in the Sloan Digital Sky Survey, we study the BCG--galaxy velocity correlation function. By modeling its non-Gaussianity, we measure the mean and scatter in velocity dispersion at fixed richness. The mean velocity dispersion increases from 202 {+-} 10 km s{sup -1} for small groups to more than 854 {+-} 102 km s{sup -1} for large clusters. We show the scatter to be at most 40.5{+-}3.5%, declining to 14.9{+-}9.4% in the richest bins. We test our methods in the C4 cluster catalog, a spectroscopic cluster catalog produced from the Sloan Digital Sky Survey DR2 spectroscopic sample, and in mock galaxy catalogs constructed from N-body simulations. Our methods are robust, measuring the scatter to well within one-sigma of the true value, and the mean to within 10%, in the mock catalogs. By convolving the scatter in velocity dispersion at fixed richness with the observed richness space density function, we measure the velocity dispersion function of the maxBCG galaxy clusters. Although velocity dispersion and richness do not form a true mass--observable relation, the relationship between velocity dispersion and mass is theoretically well characterized and has low scatter. Thus our results provide a key link between theory and observations up to the velocity bias between dark matter and galaxies.

  12. Open architecture for health care systems: the European RICHE experience.

    Science.gov (United States)

    Frandji, B

    1997-01-01

    Groupe RICHE is bringing to the market of health IT the Open Systems approach allowing a new generation of health information systems to arise with benefit for patients, health care professionals, hospital managers, agencies and citizens. Groupe RICHE is a forum for exchanging information, expertise around open systems in health care. It is open to any organisation interested by open systems in health care and wanting to participate and influence the work done by its user, marketing and technical committees. The Technical Committee is in charge of the maintenance of the architecture and impact the results of industrial experiences on new releases. Any Groupe RICHE member is entitled to participate to this process. This unique approach in Europe allows health care professionals to benefit from applications supporting their business processes, including providing a cooperative working environment, a shared electronic record, in an integrated system where the information is entered only once, customised according to the user needs and available to the administrative applications. This allows Hospital managers to satisfy their health care professionals, to smoothly migrate from their existing environment (protecting their investment), to choose products in a competitive environment, being able to mix and match system components and services from different suppliers, being free to change suppliers without having to replace their existing system (minimising risk), in line with national and regional strategies. For suppliers, this means being able to commercialise products well fitted to their field of competence in a large market, reducing investments and increasing returns. The RICHE approach also allows agencies to define a strategy, allowing to create a supporting infrastructure, organising the market leaving enough freedom to health care organisations and suppliers. Such an approach is based on the definition of an open standard architecture. The RICHE esprit project

  13. CHEMICAL ABUNDANCES IN NGC 5053: A VERY METAL-POOR AND DYNAMICALLY COMPLEX GLOBULAR CLUSTER

    Energy Technology Data Exchange (ETDEWEB)

    Boberg, Owen M.; Friel, Eileen D.; Vesperini, Enrico [Astronomy Department, Indiana University, Bloomington, IN 47405 (United States)

    2015-05-10

    NGC 5053 provides a rich environment to test our understanding of the complex evolution of globular clusters (GCs). Recent studies have found that this cluster has interesting morphological features beyond the typical spherical distribution of GCs, suggesting that external tidal effects have played an important role in its evolution and current properties. Additionally, simulations have shown that NGC 5053 could be a likely candidate to belong to the Sagittarius dwarf galaxy (Sgr dSph) stream. Using the Wisconsin–Indiana–Yale–NOAO–Hydra multi-object spectrograph, we have collected high quality (signal-to-noise ratio ∼ 75–90), medium-resolution spectra for red giant branch stars in NGC 5053. Using these spectra we have measured the Fe, Ca, Ti, Ni, Ba, Na, and O abundances in the cluster. We measure an average cluster [Fe/H] abundance of −2.45 with a standard deviation of 0.04 dex, making NGC 5053 one of the most metal-poor GCs in the Milky Way (MW). The [Ca/Fe], [Ti/Fe], and [Ba/Fe] we measure are consistent with the abundances of MW halo stars at a similar metallicity, with alpha-enhanced ratios and slightly depleted [Ba/Fe]. The Na and O abundances show the Na–O anti-correlation found in most GCs. From our abundance analysis it appears that NGC 5053 is at least chemically similar to other GCs found in the MW. This does not, however, rule out NGC 5053 being associated with the Sgr dSph stream.

  14. Chemical Abundances in NGC 5053: A Very Metal-poor and Dynamically Complex Globular Cluster

    Science.gov (United States)

    Boberg, Owen M.; Friel, Eileen D.; Vesperini, Enrico

    2015-05-01

    NGC 5053 provides a rich environment to test our understanding of the complex evolution of globular clusters (GCs). Recent studies have found that this cluster has interesting morphological features beyond the typical spherical distribution of GCs, suggesting that external tidal effects have played an important role in its evolution and current properties. Additionally, simulations have shown that NGC 5053 could be a likely candidate to belong to the Sagittarius dwarf galaxy (Sgr dSph) stream. Using the Wisconsin-Indiana-Yale-NOAO-Hydra multi-object spectrograph, we have collected high quality (signal-to-noise ratio ˜ 75-90), medium-resolution spectra for red giant branch stars in NGC 5053. Using these spectra we have measured the Fe, Ca, Ti, Ni, Ba, Na, and O abundances in the cluster. We measure an average cluster [Fe/H] abundance of -2.45 with a standard deviation of 0.04 dex, making NGC 5053 one of the most metal-poor GCs in the Milky Way (MW). The [Ca/Fe], [Ti/Fe], and [Ba/Fe] we measure are consistent with the abundances of MW halo stars at a similar metallicity, with alpha-enhanced ratios and slightly depleted [Ba/Fe]. The Na and O abundances show the Na-O anti-correlation found in most GCs. From our abundance analysis it appears that NGC 5053 is at least chemically similar to other GCs found in the MW. This does not, however, rule out NGC 5053 being associated with the Sgr dSph stream.

  15. INSIGHTS INTO PRE-ENRICHMENT OF STAR CLUSTERS AND SELF-ENRICHMENT OF DWARF GALAXIES FROM THEIR INTRINSIC METALLICITY DISPERSIONS

    International Nuclear Information System (INIS)

    Leaman, Ryan

    2012-01-01

    Star clusters are known to have smaller intrinsic metallicity spreads than dwarf galaxies due to their shorter star formation timescales. Here we use individual spectroscopic [Fe/H] measurements of stars in 19 Local Group dwarf galaxies, 13 Galactic open clusters, and 49 globular clusters to show that star cluster and dwarf galaxy linear metallicity distributions are binomial in form, with all objects showing strong correlations between their mean linear metallicity Z-bar and intrinsic spread in metallicity σ(Z) 2 . A plot of σ(Z) 2 versus Z-bar shows that the correlated relationships are offset for the dwarf galaxies from the star clusters. The common binomial nature of these linear metallicity distributions can be explained with a simple inhomogeneous chemical evolution model, where the star cluster and dwarf galaxy behavior in the σ(Z) 2 - Z-bar diagram is reproduced in terms of the number of enrichment events, covering fraction, and intrinsic size of the enriched regions. The inhomogeneity of the self-enrichment sets the slope for the observed dwarf galaxy σ(Z) 2 - Z-bar correlation. The offset of the star cluster sequence from that of the dwarf galaxies is due to pre-enrichment, and the slope of the star cluster sequence represents the remnant signature of the self-enriched history of their host galaxies. The offset can be used to separate star clusters from dwarf galaxies without a priori knowledge of their luminosity or dynamical mass. The application of the inhomogeneous model to the σ(Z) 2 - Z-bar relationship provides a numerical formalism to connect the self-enrichment and pre-enrichment between star clusters and dwarf galaxies using physically motivated chemical enrichment parameters. Therefore we suggest that the σ(Z) 2 - Z-bar relationship can provide insight into what drives the efficiency of star formation and chemical evolution in galaxies, and is an important prediction for galaxy simulation models to reproduce.

  16. Dispersed metal cluster catalysts by design. Synthesis, characterization, structure, and performance

    Energy Technology Data Exchange (ETDEWEB)

    Arslan, Ilke [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Dixon, David A. [Univ. of Alabama, Tuscaloosa, AL (United States); Gates, Bruce C. [Univ. of California, Davis, CA (United States); Katz, Alexander [Univ. of California, Berkeley, CA (United States)

    2015-09-30

    To understand the class of metal cluster catalysts better and to lay a foundation for the prediction of properties leading to improved catalysts, we have synthesized metal catalysts with well-defined structures and varied the cluster structures and compositions systematically—including the ligands bonded to the metals. These ligands include supports and bulky organics that are being tuned to control both the electron transfer to or from the metal and the accessibility of reactants to influence catalytic properties. We have developed novel syntheses to prepare these well-defined catalysts with atomic-scale control the environment by choice and placement of ligands and applied state-of-the art spectroscopic, microscopic, and computational methods to determine their structures, reactivities, and catalytic properties. The ligands range from nearly flat MgO surfaces to enveloping zeolites to bulky calixarenes to provide controlled coverages of the metal clusters, while also enforcing unprecedented degrees of coordinative unsaturation at the metal site—thereby facilitating bonding and catalysis events at exposed metal atoms. With this wide range of ligand properties and our arsenal of characterization tools, we worked to achieve a deep, fundamental understanding of how to synthesize robust supported and ligand-modified metal clusters with controlled catalytic properties, thereby bridging the gap between active site structure and function in unsupported and supported metal catalysts. We used methods of organometallic and inorganic chemistry combined with surface chemistry for the precise synthesis of metal clusters and nanoparticles, characterizing them at various stages of preparation and under various conditions (including catalytic reaction conditions) and determining their structures and reactivities and how their catalytic properties depend on their compositions and structures. Key characterization methods included IR, NMR, and EXAFS spectroscopies to identify

  17. The peculiar velocities of rich clusters in the hot and cold dark matter scenarios

    Science.gov (United States)

    Rhee, George F.; West, Michael J.; Villumsen, Jens V.

    1993-01-01

    We present the results of a study of the peculiar velocities of rich clusters of galaxies. The peculiar motion of rich clusters in various cosmological scenarios is of interest for a number of reasons. Observationally, one can measure the peculiar motion of clusters to greater distances than galaxies because cluster peculiar motions can be determined to greater accuracy. One can also test the slope of distance indicator relations using clusters to see if galaxy properties vary with environment. We have used N-body simulations to measure the amplitude and rms cluster peculiar velocity as a function of bias parameter in the hot and cold dark matter scenarios. In addition to measuring the mean and rms peculiar velocity of clusters in the two models, we determined whether the peculiar velocity vector of a given cluster is well aligned with the gravity vector due to all the particles in the simulation and the gravity vector due to the particles present only in the clusters. We have investigated the peculiar velocities of rich clusters of galaxies in the cold dark matter and hot dark matter galaxy formation scenarios. We have derived peculiar velocities and associated errors for the scenarios using four values of the bias parameter ranging from b = 1 to b = 2.5. The growth of the mean peculiar velocity with scale factor has been determined and compared to that predicted by linear theory. In addition, we have compared the orientation of force and velocity in these simulations to see if a program such as that proposed by Bertschinger and Dekel (1989) for elliptical galaxy peculiar motions can be applied to clusters. The method they describe enables one to recover the density field from large scale redshift distance samples. The method makes it possible to do this when only radial velocities are known by assuming that the velocity field is curl free. Our analysis suggests that this program if applied to clusters is only realizable for models with a low value of the bias

  18. Atomically precise arrays of fluorescent silver clusters: a modular approach for metal cluster photonics on DNA nanostructures.

    Science.gov (United States)

    Copp, Stacy M; Schultz, Danielle E; Swasey, Steven; Gwinn, Elisabeth G

    2015-03-24

    The remarkable precision that DNA scaffolds provide for arraying nanoscale optical elements enables optical phenomena that arise from interactions of metal nanoparticles, dye molecules, and quantum dots placed at nanoscale separations. However, control of ensemble optical properties has been limited by the difficulty of achieving uniform particle sizes and shapes. Ligand-stabilized metal clusters offer a route to atomically precise arrays that combine desirable attributes of both metals and molecules. Exploiting the unique advantages of the cluster regime requires techniques to realize controlled nanoscale placement of select cluster structures. Here we show that atomically monodisperse arrays of fluorescent, DNA-stabilized silver clusters can be realized on a prototypical scaffold, a DNA nanotube, with attachment sites separated by <10 nm. Cluster attachment is mediated by designed DNA linkers that enable isolation of specific clusters prior to assembly on nanotubes and preserve cluster structure and spectral purity after assembly. The modularity of this approach generalizes to silver clusters of diverse sizes and DNA scaffolds of many types. Thus, these silver cluster nano-optical elements, which themselves have colors selected by their particular DNA templating oligomer, bring unique dimensions of control and flexibility to the rapidly expanding field of nano-optics.

  19. The Open Cluster Chemical Abundances and Mapping (OCCAM) Survey: Current Status

    Science.gov (United States)

    Frinchaboy, Peter; O'Connell, Julia; Donor, John; Cunha, Katia; Thompson, Benjamin; Melendez, Matthew; Shetrone, Matthew; Zasowski, Gail; Majewski, Steven R.; APOGEE TEAM

    2018-01-01

    The Open Cluster Chemical Analysis and Mapping (OCCAM) survey aims to produce a comprehensive, uniform, infrared-based data set forhundreds of open clusters, and constrain key Galactic dynamical and chemical parameters using the SDSS/APOGEE survey and follow-up from the McDonald Observatory Otto Struve 2.1-m telescope and Sandiford Cass Echelle Spectrograph (R ~ 60,000). We report on multi-element radial abundance gradients obtained from a sample of over 30 disk open clusters. The APOGEE chemical abundances were derived automatically by the ASPCAP pipeline and these are part of the SDSS IV Data Release 14, optical follow-up were analyzed using equivalent width analysis and spectral synthesis. We present the current open cluster sample that spans a significant range in age allowing exploration of the evolution of the Galactic abundance gradients. This work is supported by an NSF AAG grants AST-1311835 & AST-1715662.

  20. Deposition of metal Islands, metal clusters and metal containing single molecules on self-assembled monolayers

    NARCIS (Netherlands)

    Speets, Emiel Adrianus

    2005-01-01

    The central topic of this thesis is the deposition of metals on Self-Assembled Monolayers (SAMs). Metals are deposited in the form of submicron scale islands, nanometer scale clusters, and as supramolecular, organometallic coordination cages. Several SAMs on various substrates were prepared and

  1. Spectroscopic Comparison of Metal-rich RRab Stars of the Galactic Field with their Metal-poor Counterparts

    Energy Technology Data Exchange (ETDEWEB)

    Chadid, Merieme [Université Nice Sophia–Antipolis, Observatoire de la Côte dAzur, UMR 7293, Parc Valrose, F-06108, Nice Cedex 02 (France); Sneden, Christopher [Department of Astronomy and McDonald Observatory, The University of Texas, Austin, TX 78712 (United States); Preston, George W., E-mail: chadid@unice.fr, E-mail: chris@verdi.as.utexas.edu, E-mail: gwp@obs.carnegiescience.edu [Carnegie Observatories, 813 Santa Barbara Street, Pasadena, CA 91101 (United States)

    2017-02-01

    We investigate atmospheric properties of 35 stable RRab stars that possess the full ranges of period, light amplitude, and metal abundance found in Galactic RR Lyrae stars. Our results are derived from several thousand echelle spectra obtained over several years with the du Pont telescope of Las Campanas Observatory. Radial velocities of metal lines and the H α line were used to construct curves of radial velocity versus pulsation phase. From these we estimated radial velocity amplitudes for metal lines (formed near the photosphere) and H α Doppler cores (formed at small optical depths). We also measured H α emission fluxes when they appear during primary light rises. Spectra shifted to rest wavelengths, binned into small phase intervals, and co-added were used to perform model atmospheric and abundance analyses. The derived metallicities and those of some previous spectroscopic surveys were combined to produce a new calibration of the Layden abundance scale. We then divided our RRab sample into metal-rich (disk) and metal-poor (halo) groups at [Fe/H] = −1.0; the atmospheres of RRab families, so defined, differ with respect to (a) peak strength of H α emission flux, (b) H α radial velocity amplitude, (c) dynamical gravity, (d) stellar radius variation, (e) secondary acceleration during the photometric bump that precedes minimum light, and (f) duration of H α line-doubling. We also detected H α line-doubling during the “bump” in the metal-poor family, but not in the metal-rich one. Although all RRab probably are core helium-burning horizontal branch stars, the metal-rich group appears to be a species sui generis.

  2. Metal-rich RRc Stars in the Carnegie RR Lyrae Survey

    Science.gov (United States)

    Sneden, Christopher; Preston, George W.; Kollmeier, Juna A.; Crane, Jeffrey D.; Morrell, Nidia; Prieto, José L.; Shectman, Stephen A.; Skowron, Dorota M.; Thompson, Ian B.

    2018-01-01

    We describe and employ a stacking procedure to investigate abundances derived from the low signal-to-noise ratio spectra obtained in the Carnegie RR Lyrae Survey (CARRS). We find iron metallicities that extend from [Fe/H] ∼ ‑2.5 to values at least as large as [Fe/H] ∼ ‑0.5 in the 274-spectrum CARRS RRc data set. We consider RRc sample contamination by high amplitude solar metallicity δ Scuti stars (HADS) at periods less than 0.3 days, where photometric discrimination between RRc and δ Scuti stars has proven to be problematic. We offer a spectroscopic discriminant, the well-marked overabundance of heavy elements, principally [Ba/H], that is a common, if not universal, characteristic of HADS of all periods and axial rotations. No bona fide RRc stars known to us have verified heavy-element overabundances. Three out of 34 stars in our sample with [Fe/H] > ‑0.7 exhibit anomalously strong features of Sr, Y, Zr, Ba, and many rare earths. However, carbon is not enhanced in these three stars, and we conclude that their elevated n-capture abundances have not been generated in interior neutron-capture nucleosynthesis. Contamination by HADS appears to be unimportant, and metal-rich RRc stars occur in approximately the same proportion in the Galactic field as do metal-rich RRab stars. An apparent dearth of metal-rich RRc is probably a statistical fluke. Finally, we show that RRc stars have a similar inverse period–metallicity relationship as has been found for RRab stars.

  3. Collective excitations in deformed alkali metal clusters

    International Nuclear Information System (INIS)

    Lipparini, E.; Stringari, S.; Istituto Nazionale di Fisica Nucleare, Povo

    1991-01-01

    A theoretical study of collective excitations in deformed metal clusters is presented. Sum rules are used to study the splittings of the dipole surface plasma resonance originating from the cluster deformation. The vibrating potential model is developed and used to predict the occurrence of a low lying collective mode of orbital magnetic nature. (orig.)

  4. Gaia Reveals a Metal-rich, in situ Component of the Local Stellar Halo

    Science.gov (United States)

    Bonaca, Ana; Conroy, Charlie; Wetzel, Andrew; Hopkins, Philip F.; Kereš, Dušan

    2017-08-01

    We use the first Gaia data release, combined with the RAVE and APOGEE spectroscopic surveys, to investigate the origin of halo stars within ≲ 3 kpc from the Sun. We identify halo stars kinematically as moving at a relative speed of at least 220 km s-1 with respect to the local standard of rest. These stars are generally less metal-rich than the disk, but surprisingly, half of our halo sample is comprised of stars with [{Fe}/{{H}}]> -1. The orbital directions of these metal-rich halo stars are preferentially aligned with the disk rotation, in sharp contrast with the intrinsically isotropic orbital distribution of the metal-poor halo stars. We find similar properties in the Latte cosmological zoom-in simulation of a Milky Way-like galaxy from the FIRE project. In Latte, metal-rich halo stars formed primarily inside of the solar circle, whereas lower-metallicity halo stars preferentially formed at larger distances (extending beyond the virial radius). This suggests that metal-rich halo stars in the solar neighborhood actually formed in situ within the Galactic disk, rather than having been accreted from satellite systems. These stars, currently on halo-like orbits, therefore have likely undergone substantial radial migration/heating.

  5. Facilitation drives the positive effects of plant richness on trace metal removal in a biodiversity experiment.

    Directory of Open Access Journals (Sweden)

    Jiang Wang

    Full Text Available BACKGROUND: Phytoextraction is an environmentally acceptable and inexpensive technique for mine tailing rehabilitation that uses metallophyte plants. These plants reduce the soil trace metal contents to environmentally acceptable levels by accumulating trace metals. Recently, whether more trace metals can be removed by species-rich communities of these plants received great attention, as species richness has been reported having positive effects on ecosystem functions. However, how the species richness affects trace metals removal of plant communities of mine tailing is rarely known. METHODOLOGY/PRINCIPAL FINDINGS: We examined the effects of species richness on soil trace metal removal in both natural and experimental plant communities. The root lengths and stem heights of each plant species were measured in order to calculate the functional diversity indices. Our results showed that trace metal (Cu, Cd, Pb and Zn concentrations in mine tailing soil declined as species richness increased in both the natural and experimental plant communities. Species richness, rather than functional diversity, positively affected the mineralomass of the experimental plant communities. The intensity of plant-plant facilitation increased with the species richness of experimental communities. Due to the incremental role of plant-plant facilitation, most of the species had higher biomasses, higher trace metal concentrations in their plant tissues and lower malondialdehyde concentrations in their leaves. Consequently, the positive effects of species richness on mineralomass were mostly attributable to facilitation among plants. CONCLUSIONS/SIGNIFICANCE: Our results provide clear evidence that, due to plant-plant facilitation, species richness positively affects the removal of trace metals from mine tailing soil through phytoextraction and provides further information on diversity conservation and environmental remediation in a mine tailing environment.

  6. A search for peculiar stars in the open cluster Hogg 16

    Science.gov (United States)

    Cariddi, Stefano; Azatyan, Naira M.; Kurfürst, Petr; Štofanová, Lýdia; Netopil, Martin; Paunzen, Ernst; Pintado, Olga I.; Aidelman, Yael J.

    2018-01-01

    The study of chemically peculiar (CP) stars in open clusters provides valuable information about their evolutionary status. Their detection can be performed using the Δa photometric system, which maps a characteristic flux depression at λ ∼ 5200 Å. This paper aims at studying the occurrence of CP stars in the earliest stages of evolution of a stellar population by applying this technique to Hogg 16, a very young Galactic open cluster ( ∼ 25 Myr). We identified several peculiar candidates: two B-type stars with a negative Δa index (CD - 60 4701, CPD - 60 4706) are likely emission-line (Be) stars, even though spectral measurements are necessary for a proper classification of the second one; a third object (CD - 60 4703), identified as a Be candidate in literature, appears to be a background B-type supergiant with no significant Δa index, which does not rule out the possibility that it is indeed peculiar as the normality line of Δa for supergiants has not been studied in detail yet. A fourth object (CD - 60 4699) appears to be a magnetic CP star of 8 M⊙, but obtained spectral data seem to rule out this hypothesis. Three more magnetic CP star candidates are found in the domain of early F-type stars. One is a probable nonmember and close to the border of significance, but the other two are probably pre-main sequence cluster objects. This is very promising, as it can lead to very strong constraints to the diffusion theory. Finally, we derived the fundamental parameters of Hogg 16 and provide for the first time an estimate of its metal content.

  7. Cluster-transfer reactions with radioactive beams: a spectroscopic tool for neutron-rich nuclei

    CERN Document Server

    AUTHOR|(CDS)2086156; Raabe, Riccardo; Bracco, Angela

    In this thesis work, an exploratory experiment to investigate cluster-transfer reactions with radioactive beams in inverse kinematics is presented. The aim of the experiment was to test the potential of cluster-transfer reactions at the Coulomb barrier, as a possible mean to perform $\\gamma$ spectroscopy studies of exotic neutron-rich nuclei at medium-high energies and spins. The experiment was performed at ISOLDE (CERN), employing the heavy-ion reaction $^{98}$Rb + $^{7}$Li at 2.85 MeV/A. Cluster-transfer reaction channels were studied through particle-$\\gamma$ coincidence measurements, using the MINIBALL Ge array coupled to the charged particle Si detectors T-REX. Sr, Y and Zr neutron-rich nuclei with A $\\approx$ 100 were populated by either triton- or $\\alpha$ transfer from $^{7}$Li to the beam nuclei and the emitted complementary charged fragment was detected in coincidence with the $\\gamma$ cascade of the residues, after few neutrons evaporation. The measured $\\gamma$ spectra were studied in detail and t...

  8. Orbital magnetism and dynamics in alkali metal clusters

    International Nuclear Information System (INIS)

    Nesterenko, V.O.; Kleinig, W.; Souza Cruz, FF. de; Marinelli, J.R.

    2000-01-01

    Two remarkable orbital magnetic resonances, M1 scissor mode and M2 twist mode, are predicted in deformed and spherical metal clusters, respectively. We show that these resonances provide a valuable information about many cluster properties (quadrupole deformation, magnetic susceptibility, single-particle spectrum, etc.)

  9. Hydrometallurgical Approach for Leaching of Metals from Copper Rich Side Stream Originating from Base Metal Production

    Directory of Open Access Journals (Sweden)

    Udit Surya Mohanty

    2018-01-01

    Full Text Available Pyrometallurgical metal production results in side streams, such as dusts and slags, which are carriers of metals, though commonly containing lower metal concentrations compared to the main process stream. In order to improve the circular economy of metals, selective leaching of copper from an intermediate raw material originating from primary base metal production plant was investigated. The raw material investigated was rich in Cu (12.5%, Ni (2.6%, Zn (1.6%, and Fe (23.6% with the particle size D80 of 124 µm. The main compounds present were nickel ferrite (NiFe2O4, fayalite (Fe2SiO4, cuprite (Cu2O, and metallic copper. Leaching was studied in 16 different solutions. The results revealed that copper phases could be dissolved with high yield (>90% and selectivity towards nickel (Cu/Ni > 7 already at room temperature with the following solutions: 0.5 M HCl, 1.5 M HCl, 4 M NaOH, and 2 M HNO3. A concentration of 4 M NaOH provided a superior selectivity between Cu/Ni (340 and Cu/Zn (51. In addition, 1–2 M HNO3 and 0.5 M HCl solutions were shown to result in high Pb dissolution (>98%. Consequently, 0.5 M HCl leaching is suggested to provide a low temperature, low chemical consumption method for selective copper removal from the investigated side stream, resulting in PLS (pregnant leach solution which is a rich in Cu and lead free residue, also rich in Ni and Fe.

  10. Chemical Compositions of Stars in the Globular Cluster NGC 3201: Tracers of Multi-Epoch Star Formation

    Science.gov (United States)

    Simmerer, Jennifer A.; Ivans, I. I.; Filler, D.

    2012-01-01

    The retrograde halo globular cluster NGC 3201 contains stars of substantially different iron abundance ([Fe/H]), a property that puts it at odds with the vast majority of the Galactic cluster system. Though its unusual orbit prompted speculation that NGC 3201 was the remnant of a captured object, much like the multi-metallicity globular cluster Omega Centauri, NGC 3201 is much less massive than Omega Centauri and all of the other halo globular clusters that have internal metallicity variations. We present the abundances of 21 elements in 24 red giant branch stars in NGC 3201 based on high-resolution (R 40,000), high signal-to-noise (S/N 70) spectra. We find that the detailed abundance pattern of NGC 3201 is unique amongst multi-metallicity halo clusters. Unlike M22, Omega Centauri, and NGC 1851, neither metal-poor nor metal-rich stars show any evidence of s-process enrichment (a product of the advanced evolution of low- and intermediate-mass stars). We find that while Na, O, and Al vary from star to star as is typical in globular clusters, there is no systematic difference between the abundance pattern in the metal-poor cluster stars and that of the metal-rich cluster stars. Furthermore, we find that the metallicity variations in NGC 3201 are independent of the well-known Na-O anticorrelation, which separates it from every other multi-metallicity cluster. In the context of a multi-episode star formation model, this implies that NGC 3201 began life with the [Fe/H] variations we measure now.

  11. ON THE ORIGIN OF HIGH-ALTITUDE OPEN CLUSTERS IN THE MILKY WAY

    Energy Technology Data Exchange (ETDEWEB)

    Martinez-Medina, L. A.; Pichardo, B.; Moreno, E.; Peimbert, A. [Instituto de Astronomía, Universidad Nacional Autónoma de México, A.P. 70-264, 04510, México, D.F., México (Mexico); Velazquez, H., E-mail: lamartinez@astro.unam.mx [Instituto de Astronomía, Universidad Nacional Autónoma de México, Apartado Postal 877, 22860 Ensenada, B.C., México (Mexico)

    2016-01-20

    We present a dynamical study of the effect of the bar and spiral arms on the simulated orbits of open clusters in the Galaxy. Specifically, this work is devoted to the puzzling presence of high-altitude open clusters in the Galaxy. For this purpose we employ a very detailed observationally motivated potential model for the Milky Way and a careful set of initial conditions representing the newly born open clusters in the thin disk. We find that the spiral arms are able to raise an important percentage of open clusters (about one-sixth of the total employed in our simulations, depending on the structural parameters of the arms) above the Galactic plane to heights beyond 200 pc, producing a bulge-shaped structure toward the center of the Galaxy. Contrary to what was expected, the spiral arms produce a much greater vertical effect on the clusters than the bar, both in quantity and height; this is due to the sharper concentration of the mass on the spiral arms, when compared to the bar. When a bar and spiral arms are included, spiral arms are still capable of raising an important percentage of the simulated open clusters through chaotic diffusion (as tested from classification analysis of the resultant high-z orbits), but the bar seems to restrain them, diminishing the elevation above the plane by a factor of about two.

  12. CHEMICAL COMPOSITION OF INTERMEDIATE-MASS STAR MEMBERS OF THE M6 (NGC 6405) OPEN CLUSTER

    Energy Technology Data Exchange (ETDEWEB)

    Kılıçoğlu, T.; Albayrak, B. [Ankara University, Faculty of Science, Department of Astronomy and Space Sciences, 06100, Tandoğan, Ankara (Turkey); Monier, R. [LESIA, UMR 8109, Observatoire de Paris Meudon, Place J. Janssen, Meudon (France); Richer, J. [Département de physique, Université de Montréal, 2900, Boulevard Edouard-Montpetit, Montréal QC, H3C 3J7 (Canada); Fossati, L., E-mail: tkilicoglu@ankara.edu.tr, E-mail: balbayrak@ankara.edu.tr, E-mail: Richard.Monier@obspm.fr, E-mail: Jacques.Richer@umontreal.ca, E-mail: lfossati@astro.uni-bonn.de [Argelander-Institut für Astronomie der Universität Bonn, Auf dem Hügel 71, D-53121, Bonn (Germany)

    2016-03-15

    We present here the first abundance analysis of 44 late B-, A-, and F-type members of the young open cluster M6 (NGC 6405, age about 75 Myr). Low- and medium-resolution spectra, covering the 4500–5840 Å wavelength range, were obtained using the FLAMES/GIRAFFE spectrograph attached to the ESO Very Large Telescopes. We determined the atmospheric parameters using calibrations of the Geneva photometry and by adjusting the H{sub β} profiles to synthetic ones. The abundances of up to 20 chemical elements, from helium to mercury, were derived for 19 late B, 16 A, and 9 F stars by iteratively adjusting synthetic spectra to the observations. We also derived a mean cluster metallicity of [Fe/H] = 0.07 ± 0.03 dex from the iron abundances of the F-type stars. We find that for most chemical elements, the normal late B- and A-type stars exhibit larger star-to-star abundance variations than the F-type stars probably because of the faster rotation of the B and A stars. The abundances of C, O, Mg, Si, and Sc appear to be anticorrelated with that of Fe, while the opposite holds for the abundances of Ca, Ti, Cr, Mn, Ni, Y, and Ba as expected if radiative diffusion is efficient in the envelopes of these stars. In the course of this analysis, we discovered five new peculiar stars: one mild Am, one Am, and one Fm star (HD 318091, CD-32 13109, GSC 07380-01211, CP1), one HgMn star (HD 318126, CP3), and one He-weak P-rich (HD 318101, CP4) star. We also discovered a new spectroscopic binary, most likely a SB2. We performed a detailed modeling of HD 318101, the new He-weak P-rich CP star, using the Montréal stellar evolution code XEVOL which self-consistently treats all particle transport processes. Although the overall abundance pattern of this star is properly reproduced, we find that detailed abundances (in particular the high P excess) resisted modeling attempts even when a range of turbulence profiles and mass-loss rates were considered. Solutions are proposed which are

  13. Clustered field evaporation of metallic glasses in atom probe tomography

    International Nuclear Information System (INIS)

    Zemp, J.; Gerstl, S.S.A.; Löffler, J.F.; Schönfeld, B.

    2016-01-01

    Field evaporation of metallic glasses is a stochastic process combined with spatially and temporally correlated events, which are referred to as clustered evaporation (CE). This phenomenon is investigated by studying the distance between consecutive detector hits. CE is found to be a strongly localized phenomenon (up to 3 nm in range) which also depends on the type of evaporating ions. While a similar effect in crystals is attributed to the evaporation of crystalline layers, CE of metallic glasses presumably has a different – as yet unknown – physical origin. The present work provides new perspectives on quantification methods for atom probe tomography of metallic glasses. - Highlights: • Field evaporation of metallic glasses is heterogeneous on a scale of up to 3 nm. • Amount of clustered evaporation depends on ion species and temperature. • Length scales of clustered evaporation and correlative evaporation are similar.

  14. Metallicity in galactic clusters from high signal-to-noise spectroscopy

    International Nuclear Information System (INIS)

    Boesgaard, A.M.

    1989-01-01

    High-quality spectroscopic data on selected F dwarfs in six Galactic clusters are used to determine global (Fe/H) values for the clusters. For the two youngest clusters, Pleiades and Alpha Per, the (Fe/H) values are solar: 0.017 + or - 0.055. The Hyades and Praesepe are slightly metal-enhanced at (Fe/H) = + 0.125 + or - 0.032, even though they are an order of magnitude older than the Pleiades. Coma and the UMa Group at the age of the Hyades are slightly metal-deficient with (Fe/H) = - 0.082 + or - 0.039. The lack of an age-metallicity relationship indicates that the enrichment and mixing in the Galactic disk have not been uniform on time scales less than a billion years. 39 references

  15. METAL DEFICIENCY IN CLUSTER STAR-FORMING GALAXIES AT Z = 2

    Energy Technology Data Exchange (ETDEWEB)

    Valentino, F.; Daddi, E.; Strazzullo, V.; Gobat, R.; Bournaud, F.; Juneau, S.; Zanella, A. [Laboratoire AIM-Paris-Saclay, CEA/DSM-CNRS-Université Paris Diderot, Irfu/Service d’Astrophysique, CEA Saclay, Orme des Merisiers, F-91191 Gif sur Yvette (France); Onodera, M.; Carollo, M. [Institute for Astronomy, ETH Zürich Wolfgang-Pauli-strasse 27, 8093 Zürich (Switzerland); Renzini, A. [INAF-Osservatorio Astronomico di Padova Vicolo dell’Osservatorio 5, I-35122 Padova (Italy); Arimoto, N., E-mail: francesco.valentino@cea.fr [Subaru Telescope, National Astronomical Observatory of Japan 650 North A’ohoku Place, Hilo, HI 96720 (United States)

    2015-03-10

    We investigate the environmental effect on the metal enrichment of star-forming galaxies (SFGs) in the farthest spectroscopically confirmed and X-ray-detected cluster, CL J1449+0856 at z = 1.99. We combined Hubble Space Telescope/WFC3 G141 slitless spectroscopic data, our thirteen-band photometry, and a recent Subaru/Multi-object InfraRed Camera and Spectrograph (MOIRCS) near-infrared spectroscopic follow-up to constrain the physical properties of SFGs in CL J1449+0856 and in a mass-matched field sample. After a conservative removal of active galactic nuclei, stacking individual MOIRCS spectra of 6 (31) sources in the cluster (field) in the mass range 10 ≤ log(M/M{sub ⊙}) ≤ 11, we find a ∼4σ lower [N ii]/Hα ratio in the cluster than in the field. Stacking a subsample of 16 field galaxies with Hβ and [O iii] in the observed range, we measure an [O iii]/Hβ ratio fully compatible with the cluster value. Converting these ratios into metallicities, we find that the cluster SFGs are up to 0.25 dex poorer in metals than their field counterparts, depending on the adopted calibration. The low metallicity in cluster sources is confirmed using alternative indicators. Furthermore, we observe a significantly higher Hα luminosity and equivalent width in the average cluster spectrum than in the field. This is likely due to the enhanced specific star formation rate; even if lower dust reddening and/or an uncertain environmental dependence on the continuum-to-nebular emission differential reddening may play a role. Our findings might be explained by the accretion of pristine gas around galaxies at z = 2 and from cluster-scale reservoirs, possibly connected with a phase of rapid halo mass assembly at z > 2 and of a high galaxy merging rate.

  16. Experimental studies of the chemistry of metal clusters

    International Nuclear Information System (INIS)

    Parks, E.K.; Riley, S.J.

    1988-01-01

    The procedures for studying chemical reactions of metal clusters in a continuous-flow reactor are described, and examples of such studies are given. Experiments to be discussed include kinetics and thermodynamics measurements, and determination of the composition of clusters saturated with various adsorbate reagents. Specific systems to be covered include the reaction of iron clusters with ammonia and with hydrogen, the reaction of nickel clusters with hydrogen and with ammonia, and the reaction of platinum clusters with ethylene. The last two reactions are characterized by complex, multi-step processes that lead to adsorbate decomposition and hydrogen desorption from the clusters. Methods for probing these processes will be discussed. 26 refs., 8 figs

  17. Open-Source Sequence Clustering Methods Improve the State Of the Art.

    Science.gov (United States)

    Kopylova, Evguenia; Navas-Molina, Jose A; Mercier, Céline; Xu, Zhenjiang Zech; Mahé, Frédéric; He, Yan; Zhou, Hong-Wei; Rognes, Torbjørn; Caporaso, J Gregory; Knight, Rob

    2016-01-01

    Sequence clustering is a common early step in amplicon-based microbial community analysis, when raw sequencing reads are clustered into operational taxonomic units (OTUs) to reduce the run time of subsequent analysis steps. Here, we evaluated the performance of recently released state-of-the-art open-source clustering software products, namely, OTUCLUST, Swarm, SUMACLUST, and SortMeRNA, against current principal options (UCLUST and USEARCH) in QIIME, hierarchical clustering methods in mothur, and USEARCH's most recent clustering algorithm, UPARSE. All the latest open-source tools showed promising results, reporting up to 60% fewer spurious OTUs than UCLUST, indicating that the underlying clustering algorithm can vastly reduce the number of these derived OTUs. Furthermore, we observed that stringent quality filtering, such as is done in UPARSE, can cause a significant underestimation of species abundance and diversity, leading to incorrect biological results. Swarm, SUMACLUST, and SortMeRNA have been included in the QIIME 1.9.0 release. IMPORTANCE Massive collections of next-generation sequencing data call for fast, accurate, and easily accessible bioinformatics algorithms to perform sequence clustering. A comprehensive benchmark is presented, including open-source tools and the popular USEARCH suite. Simulated, mock, and environmental communities were used to analyze sensitivity, selectivity, species diversity (alpha and beta), and taxonomic composition. The results demonstrate that recent clustering algorithms can significantly improve accuracy and preserve estimated diversity without the application of aggressive filtering. Moreover, these tools are all open source, apply multiple levels of multithreading, and scale to the demands of modern next-generation sequencing data, which is essential for the analysis of massive multidisciplinary studies such as the Earth Microbiome Project (EMP) (J. A. Gilbert, J. K. Jansson, and R. Knight, BMC Biol 12:69, 2014, http

  18. Cluster-cluster clustering

    International Nuclear Information System (INIS)

    Barnes, J.; Dekel, A.; Efstathiou, G.; Frenk, C.S.; Yale Univ., New Haven, CT; California Univ., Santa Barbara; Cambridge Univ., England; Sussex Univ., Brighton, England)

    1985-01-01

    The cluster correlation function xi sub c(r) is compared with the particle correlation function, xi(r) in cosmological N-body simulations with a wide range of initial conditions. The experiments include scale-free initial conditions, pancake models with a coherence length in the initial density field, and hybrid models. Three N-body techniques and two cluster-finding algorithms are used. In scale-free models with white noise initial conditions, xi sub c and xi are essentially identical. In scale-free models with more power on large scales, it is found that the amplitude of xi sub c increases with cluster richness; in this case the clusters give a biased estimate of the particle correlations. In the pancake and hybrid models (with n = 0 or 1), xi sub c is steeper than xi, but the cluster correlation length exceeds that of the points by less than a factor of 2, independent of cluster richness. Thus the high amplitude of xi sub c found in studies of rich clusters of galaxies is inconsistent with white noise and pancake models and may indicate a primordial fluctuation spectrum with substantial power on large scales. 30 references

  19. Measuring the Mean and Scatter of the X-ray Luminosity -- Optical Richness Relation for maxBCG Galaxy Clusters

    Energy Technology Data Exchange (ETDEWEB)

    Rykoff, E.S.; McKay, T.A.; Becker, M.A.; Evrard, A.; Johnston, D.E.; Koester, B.P.; Rozo, E.; Sheldon, E.S.; Wechsler, Risa H.

    2007-10-02

    We interpret and model the statistical weak lensing measurements around 130,000 groups and clusters of galaxies in the Sloan Digital Sky Survey presented by Sheldon et al. (2007). We present non-parametric inversions of the 2D shear profiles to the mean 3D cluster density and mass profiles in bins of both optical richness and cluster i-band luminosity. Since the mean cluster density profile is proportional to the cluster-mass correlation function, the mean profile is spherically symmetric by the assumptions of large-scale homogeneity and isotropy. We correct the inferred 3D profiles for systematic effects, including non-linear shear and the fact that cluster halos are not all precisely centered on their brightest galaxies. We also model the measured cluster shear profile as a sum of contributions from the brightest central galaxy, the cluster dark matter halo, and neighboring halos. We infer the relations between mean cluster virial mass and optical richness and luminosity over two orders of magnitude in cluster mass; the virial mass at fixed richness or luminosity is determined with a precision of {approx} 13% including both statistical and systematic errors. We also constrain the halo concentration parameter and halo bias as a function of cluster mass; both are in good agreement with predictions from N-body simulations of LCDM models. The methods employed here will be applicable to deeper, wide-area optical surveys that aim to constrain the nature of the dark energy, such as the Dark Energy Survey, the Large Synoptic Survey Telescope and space-based surveys.

  20. The occurrence of peculiar stars in open clusters

    International Nuclear Information System (INIS)

    Abt, H.A.; Levato, H.

    1978-01-01

    The authors have classified on the MK system a total of 455 stars in 12 open clusters and associations. The classification is based on wide (1.2 mm) spectra of two reciprocal dispersions (39, 128 A mm -1 ) obtained with the Kitt Peak 2.1 m and 90 cm reflectors respectively. The higher dispersion is necessary to show the subtle peculiarities found in some stars. The clusters are the Orion Nebula cluster, Orion OB1 association, Lacerta OB1 association, IC 2602, IC 4665, Pleiades, M39, M34, NGC 2516, NGC 6633, NGC 6475, and Coma. (Auth.)

  1. Volume shift and charge instability of simple-metal clusters

    OpenAIRE

    Brajczewska, Marta; Vieira, Armando; Fiolhais, Carlos

    1996-01-01

    Experiment indicates that small clusters show changes (mostly contractions) of the bond lengths with respect to bulk values. We use the stabilized jellium model to study the self-expansion and self-compression of spherical clusters (neutral or ionized) of simple metals. Results from Kohn — Sham density functional theory are presented for small clusters of Al and Na, including negatively-charged ones. We also examine the stability of clusters with respect to charging

  2. Volume shift and charge instability of simple-metal clusters

    Science.gov (United States)

    Brajczewska, M.; Vieira, A.; Fiolhais, C.; Perdew, J. P.

    1996-12-01

    Experiment indicates that small clusters show changes (mostly contractions) of the bond lengths with respect to bulk values. We use the stabilized jellium model to study the self-expansion and self-compression of spherical clusters (neutral or ionized) of simple metals. Results from Kohn - Sham density functional theory are presented for small clusters of Al and Na, including negatively-charged ones. We also examine the stability of clusters with respect to charging.

  3. The Gaia-ESO Survey: the present-day radial metallicity distribution of the Galactic disc probed by pre-main-sequence clusters

    Science.gov (United States)

    Spina, L.; Randich, S.; Magrini, L.; Jeffries, R. D.; Friel, E. D.; Sacco, G. G.; Pancino, E.; Bonito, R.; Bravi, L.; Franciosini, E.; Klutsch, A.; Montes, D.; Gilmore, G.; Vallenari, A.; Bensby, T.; Bragaglia, A.; Flaccomio, E.; Koposov, S. E.; Korn, A. J.; Lanzafame, A. C.; Smiljanic, R.; Bayo, A.; Carraro, G.; Casey, A. R.; Costado, M. T.; Damiani, F.; Donati, P.; Frasca, A.; Hourihane, A.; Jofré, P.; Lewis, J.; Lind, K.; Monaco, L.; Morbidelli, L.; Prisinzano, L.; Sousa, S. G.; Worley, C. C.; Zaggia, S.

    2017-05-01

    Context. The radial metallicity distribution in the Galactic thin disc represents a crucial constraint for modelling disc formation and evolution. Open star clusters allow us to derive both the radial metallicity distribution and its evolution over time. Aims: In this paper we perform the first investigation of the present-day radial metallicity distribution based on [Fe/H] determinations in late type members of pre-main-sequence clusters. Because of their youth, these clusters are therefore essential for tracing the current interstellar medium metallicity. Methods: We used the products of the Gaia-ESO Survey analysis of 12 young regions (age ages is not easily explained by the models. Our results reveal a complex interplay of several processes (e.g. star formation activity, initial mass function, supernova yields, gas flows) that controlled the recent evolution of the Milky Way. Based on observations made with the ESO/VLT, at Paranal Observatory, under program 188.B-3002 (The Gaia-ESO Public Spectroscopic Survey).Full Table 1 is only available at the CDS via anonymous ftp to http://cdsarc.u-strasbg.fr (http://130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/qcat?J/A+A/601/A70

  4. OPEN CLUSTERS AS PROBES OF THE GALACTIC MAGNETIC FIELD. I. CLUSTER PROPERTIES

    Energy Technology Data Exchange (ETDEWEB)

    Hoq, Sadia; Clemens, D. P., E-mail: shoq@bu.edu, E-mail: clemens@bu.edu [Institute for Astrophysical Research, 725 Commonwealth Avenue, Boston University, Boston, MA 02215 (United States)

    2015-10-15

    Stars in open clusters are powerful probes of the intervening Galactic magnetic field via background starlight polarimetry because they provide constraints on the magnetic field distances. We use 2MASS photometric data for a sample of 31 clusters in the outer Galaxy for which near-IR polarimetric data were obtained to determine the cluster distances, ages, and reddenings via fitting theoretical isochrones to cluster color–magnitude diagrams. The fitting approach uses an objective χ{sup 2} minimization technique to derive the cluster properties and their uncertainties. We found the ages, distances, and reddenings for 24 of the clusters, and the distances and reddenings for 6 additional clusters that were either sparse or faint in the near-IR. The derived ranges of log(age), distance, and E(B−V) were 7.25–9.63, ∼670–6160 pc, and 0.02–1.46 mag, respectively. The distance uncertainties ranged from ∼8% to 20%. The derived parameters were compared to previous studies, and most cluster parameters agree within our uncertainties. To test the accuracy of the fitting technique, synthetic clusters with 50, 100, or 200 cluster members and a wide range of ages were fit. These tests recovered the input parameters within their uncertainties for more than 90% of the individual synthetic cluster parameters. These results indicate that the fitting technique likely provides reliable estimates of cluster properties. The distances derived will be used in an upcoming study of the Galactic magnetic field in the outer Galaxy.

  5. ISO far-infrared observations of rich galaxy clusters I. Abell 2670

    DEFF Research Database (Denmark)

    Hansen, Lene; Jorgensen, H.E.; Nørgaard-Nielsen, Hans Ulrik

    1999-01-01

    As part of an investigation of far-infrared emission from rich galaxy clusters the central part of Abell 2670 has been mapped with ISO at 60 mu m, 100 mu m, 135 mu m, and 200 mu m using the PHT-C camera. Point sources detected in the field have infrared fluxes comparable to normal spirals...

  6. Tuning aromaticity in trigonal alkaline earth metal clusters and their alkali metal salts.

    Science.gov (United States)

    Jiménez-Halla, J Oscar C; Matito, Eduard; Blancafort, Lluís; Robles, Juvencio; Solà, Miquel

    2009-12-01

    In this work, we analyze the geometry and electronic structure of the [X(n)M(3)](n-2) species (M = Be, Mg, and Ca; X = Li, Na, and K; n = 0, 1, and 2), with special emphasis on the electron delocalization properties and aromaticity of the cyclo-[M(3)](2-) unit. The cyclo-[M(3)](2-) ring is held together through a three-center two-electron bond of sigma-character. Interestingly, the interaction of these small clusters with alkali metals stabilizes the cyclo-[M(3)](2-) ring and leads to a change from sigma-aromaticity in the bound state of the cyclo-[M(3)](2-) to pi-aromaticity in the XM(3) (-) and X(2)M(3) metallic clusters. Our results also show that the aromaticity of the cyclo-[M(3)](2-) unit in the X(2)M(3) metallic clusters depends on the nature of X and M. Moreover, we explored the possibility for tuning the aromaticity by simply moving X perpendicularly to the center of the M(3) ring. The Na(2)Mg(3), Li(2)Mg(3), and X(2)Ca(3) clusters undergo drastic aromaticity alterations when changing the distance from X to the center of the M(3) ring, whereas X(2)Be(3) and K(2)Mg(3) keep its aromaticity relatively constant along this process. (c) 2009 Wiley Periodicals, Inc.

  7. The pulsation mode and period-luminosity relationship of cool variables in globular clusters

    International Nuclear Information System (INIS)

    Whitelock, P.A.

    1986-01-01

    The period-luminosity-temperature relationship for globular cluster red and yellow variables is examined. The results suggest that the higher temperature, more metal-deficient cluster variables pulsate in the fundamental mode, while the lower temperature more metal-rich variables pulsate in the first overtone. On the assumption that this is correct, a relationship between fundamental period and bolometric magnitude is derived for cluster variables with observed periods of between 1 and 300 days. (author)

  8. Photometry Using Kepler "Superstamps" of Open Clusters NGC 6791 & NGC 6819

    Science.gov (United States)

    Kuehn, Charles A.; Drury, Jason A.; Bellamy, Beau R.; Stello, Dennis; Bedding, Timothy R.; Reed, Mike; Quick, Breanna

    2015-09-01

    The Kepler space telescope has proven to be a gold mine for the study of variable stars. Usually, Kepler only reads out a handful of pixels around each pre-selected target star, omitting a large number of stars in the Kepler field. Fortunately, for the open clusters NGC 6791 and NGC 6819, Kepler also read out larger "superstamps" which contained complete images of the central region of each cluster. These cluster images can be used to study additional stars in the open clusters that were not originally on Kepler's target list. We discuss our work on using two photometric techniques to analyze these superstamps and present sample results from this project to demonstrate the value of this technique for a wide variety of variable stars.

  9. Gaia reveals a metal-rich in-situ component of the local stellar halo

    Science.gov (United States)

    Bonaca, Ana; Conroy, Charlie; Wetzel, Andrew; Hopkins, Philip; Keres, Dusan

    2018-01-01

    We use the first Gaia data release, combined with RAVE and APOGEE spectroscopic surveys, to investigate the origin of halo stars within ~3 kpc from the Sun. We identify halo stars kinematically, as moving with a relative speed of at least 220 km/s with respect to the local standard of rest. These stars are in general more metal-poor than the disk, but surprisingly, half of our halo sample is comprised of stars with [Fe/H]>-1. The orbital directions of these metal-rich halo stars are preferentially aligned with the disk rotation, in sharp contrast with the isotropic orbital distribution of the more metal-poor halo stars. We find similar properties in the Latte cosmological zoom-in simulation of a Milky Way-like galaxy from the FIRE project. In Latte, metal-rich halo stars formed primarily inside of the solar circle, while lower-metallicity halo stars preferentially formed at larger distances (extending beyond the virial radius). This suggests that metal-rich halo stars in the Solar neighborhood in fact formed in situ within the Galactic disk rather than having been accreted from satellite systems. These stars, currently on halo-like orbits, therefore have likely undergone substantial radial migration/heating.

  10. Gas cluster ion beam assisted NiPt germano-silicide formation on SiGe

    Energy Technology Data Exchange (ETDEWEB)

    Ozcan, Ahmet S., E-mail: asozcan@us.ibm.com [IBM Almaden Research Center, 650 Harry Road, San Jose, California 95120 (United States); Lavoie, Christian; Jordan-Sweet, Jean [IBM T. J. Watson Research Center, 1101 Kitchawan Road, Yorktown Heights, New York 10598 (United States); Alptekin, Emre; Zhu, Frank [IBM Semiconductor Research and Development Center, 2070 Route 52, Hopewell Junction, New York 12533 (United States); Leith, Allen; Pfeifer, Brian D.; LaRose, J. D.; Russell, N. M. [TEL Epion Inc., 900 Middlesex Turnpike, Bldg. 6, Billerica, Massachusetts 01821 (United States)

    2016-04-21

    We report the formation of very uniform and smooth Ni(Pt)Si on epitaxially grown SiGe using Si gas cluster ion beam treatment after metal-rich silicide formation. The gas cluster ion implantation process was optimized to infuse Si into the metal-rich silicide layer and lowered the NiSi nucleation temperature significantly according to in situ X-ray diffraction measurements. This novel method which leads to more uniform films can also be used to control silicide depth in ultra-shallow junctions, especially for high Ge containing devices, where silicidation is problematic as it leads to much rougher interfaces.

  11. Sejong Open Cluster Survey (SOS). 0. Target Selection and Data Analysis

    Science.gov (United States)

    Sung, Hwankyung; Lim, Beomdu; Bessell, Michael S.; Kim, Jinyoung S.; Hur, Hyeonoh; Chun, Moo-Young; Park, Byeong-Gon

    2013-06-01

    Star clusters are superb astrophysical laboratories containing cospatial and coeval samples of stars with similar chemical composition. We initiate the Sejong Open cluster Survey (SOS) - a project dedicated to providing homogeneous photometry of a large number of open clusters in the SAAO Johnson-Cousins' UBVI system. To achieve our main goal, we pay much attention to the observation of standard stars in order to reproduce the SAAO standard system. Many of our targets are relatively small sparse clusters that escaped previous observations. As clusters are considered building blocks of the Galactic disk, their physical properties such as the initial mass function, the pattern of mass segregation, etc. give valuable information on the formation and evolution of the Galactic disk. The spatial distribution of young open clusters will be used to revise the local spiral arm structure of the Galaxy. In addition, the homogeneous data can also be used to test stellar evolutionary theory, especially concerning rare massive stars. In this paper we present the target selection criteria, the observational strategy for accurate photometry, and the adopted calibrations for data analysis such as color-color relations, zero-age main sequence relations, Sp - M_V relations, Sp - T_{eff} relations, Sp - color relations, and T_{eff} - BC relations. Finally we provide some data analysis such as the determination of the reddening law, the membership selection criteria, and distance determination.

  12. WIYN Open Cluster Study. XXXII. Stellar Radial Velocities in the Old Open Cluster NGC 188

    Science.gov (United States)

    Geller, Aaron M.; Mathieu, Robert D.; Harris, Hugh C.; McClure, Robert D.

    2008-06-01

    We present the results of our ongoing radial-velocity (RV) survey of the old (7 Gyr) open cluster NGC 188. Our WIYN 3.5 m data set spans a time baseline of 11 years, a magnitude range of 12 =3 measurements, finding 473 to be likely cluster members. We detect 124 velocity-variable cluster members, all of which are likely to be dynamically hard-binary stars. Using our single member stars, we find an average cluster radial velocity of -42.36 ± 0.04 km s-1. We use our precise RV and proper-motion membership data to greatly reduce field-star contamination in our cleaned color-magnitude diagram, from which we identify six stars of note that lie far from a standard single-star isochrone. We present a detailed study of the spatial distribution of cluster-member populations, and find the binaries to be centrally concentrated, providing evidence for the presence of mass segregation in NGC 188. We observe the BSs to populate a bimodal spatial distribution that is not centrally concentrated, suggesting that we may be observing two populations of BSs in NGC 188, including a centrally concentrated distribution as well as a halo population. Finally, we find NGC 188 to have a global RV dispersion of 0.64 ± 0.04 km s-1, which may be inflated by up to 0.23 km s-1 from unresolved binaries. When corrected for unresolved binaries, the NGC 188 RV dispersion has a nearly isothermal radial distribution. We use this mean-corrected velocity dispersion to derive a virial mass of 2300 ± 460 M sun .

  13. Electronic structure of structural open derivatives of the [Mo6X14]2- cluster: [Mo5Cl13]2- and [Mo4I11]2-

    International Nuclear Information System (INIS)

    Miessner, H.; Korol'kov, D.V.

    1983-01-01

    The electronic structure of structural open derivatives of the [Mo 6 X 14 ] 2 - -cluster [Mo 5 Cl 13 ] 2 - and [Mo 4 I 11 ] 2 - has been studied by the EHMO method. In [Mo 5 Cl 13 ] 2 - 9 occupied MO's with dominant Mo4d character are responsible for the formation of the 8 metal-metal bonds. In [Mo 4 I 11 ] 2 - the stronger covalent character of the Mo-I bonds affects the localization and the energy of molecular orbitals and also the charge distribution. The metal-metal bonds are formed by 8 MO's containing considerable participation of halogen AO's contrary to the chloride cluster. There is no bonding between the Mo atoms at the wing tips of the Mo 4 butterfly and the reason for decreasing the dihedral angle between the Mo 3 planes in [Mo 4 I 11 ] 2 - compared with the octahedral angle is apparently the stabilization of the whole system (Mo-Mo and Mo-I bonds). The unpaired electron occupies in both clusters a slightly antibonding (with regard to the Mo-Mo bonds) orbital. (author)

  14. Challenges And Results of the Applications of Fuzzy Logic in the Classification of Rich Galaxy Clusters

    Science.gov (United States)

    Girola Schneider, R.

    2017-07-01

    The fuzzy logic is a branch of the artificial intelligence founded on the concept that everything is a matter of degree. It intends to create mathematical approximations on the resolution of certain types of problems. In addition, it aims to produce exact results obtained from imprecise data, for which it is particularly useful for electronic and computer applications. This enables it to handle vague or unspecific information when certain parts of a system are unknown or ambiguous and, therefore, they cannot be measured in a reliable manner. Also, when the variation of a variable can produce an alteration on the others The main focus of this paper is to prove the importance of these techniques formulated from a theoretical analysis on its application on ambiguous situations in the field of the rich clusters of galaxies. The purpose is to show its applicability in the several classification systems proposed for the rich clusters, which are based on criteria such as the level of richness of the cluster, the distribution of the brightest galaxies, whether there are signs of type-cD galaxies or not or the existence of sub-clusters. Fuzzy logic enables the researcher to work with "imprecise" information implementing fuzzy sets and combining rules to define actions. The control systems based on fuzzy logic join input variables that are defined in terms of fuzzy sets through rule groups that produce one or several output values of the system under study. From this context, the application of the fuzzy logic's techniques approximates the solution of the mathematical models in abstractions about the rich galaxy cluster classification of physical properties in order to solve the obscurities that must be confronted by an investigation group in order to make a decision.

  15. ADAPTIVE OPTICS IMAGING OF A MASSIVE GALAXY ASSOCIATED WITH A METAL-RICH ABSORBER

    International Nuclear Information System (INIS)

    Chun, Mark R.; Kulkarni, Varsha P.; Gharanfoli, Soheila; Takamiya, Marianne

    2010-01-01

    The damped and sub-damped Lyα absorption (DLA and sub-DLA) line systems in quasar spectra are believed to be produced by intervening galaxies. However, the connection of quasar absorbers to galaxies is not well-understood, since attempts to image the absorbing galaxies have often failed. While most DLAs appear to be metal poor, a population of metal-rich absorbers, mostly sub-DLAs, has been discovered in recent studies. Here we report high-resolution K-band imaging with the Keck laser guide star adaptive optics (LGSAO) system of the field of quasar SDSSJ1323-0021 in search of the galaxy producing the z = 0.72 sub-DLA absorber. With a metallicity of 2-4 times the solar level, this absorber is one of the most metal-rich systems found to date. Our data show a large bright galaxy with an angular separation of only 1.''25 from the quasar, well-resolved from the quasar at the high resolution of our data. The galaxy has a magnitude of K = 17.6-17.9, which corresponds to a luminosity of ∼3-6 L*. Morphologically, the galaxy is fitted with a model with an effective radius, enclosing half of the total light, of R e = 4 kpc and a bulge-to-total ratio of 0.4-1.0, indicating a substantial bulge stellar population. Based on the mass-metallicity relation of nearby galaxies, the absorber galaxy appears to have a stellar mass of ∼>10 11 M sun . Given the small impact parameter (9.0 kpc at the absorber redshift), this massive galaxy appears to be responsible for the metal-rich sub-DLA. The absorber galaxy is consistent with the metallicity-luminosity relation observed for nearby galaxies, but is near the upper end of metallicity. Our study marks the first application of LGSAO for the study of the structure of galaxies producing distant quasar absorbers. Finally, this study offers the first example of a massive galaxy with a substantial bulge producing a metal-rich absorber.

  16. THE BOTTOM OF THE WHITE DWARF COOLING SEQUENCE IN THE OLD OPEN CLUSTER NGC 2158

    International Nuclear Information System (INIS)

    Bedin, L. R.; Anderson, J.; Salaris, M.; King, I. R.; Piotto, G.; Cassisi, S.

    2010-01-01

    We use 10 orbits of Advanced Camera for Surveys observations to reach the end of the white dwarf (WD) cooling sequence in the solar-metallicity open cluster NGC 2158. Our photometry and completeness tests show that the end falls at magnitude m F606W = 27.5 ± 0.15, which implies an age between ∼1.8 and ∼2.0 Gyr, consistent with the age of 1.9 ± 0.2 Gyr obtained from fits to the main-sequence turn-off. The faintest WDs show a clear turn toward bluer colors, as predicted by theoretical isochrones.

  17. Isotopic evidence for primordial molecular cloud material in metal-rich carbonaceous chondrites

    DEFF Research Database (Denmark)

    van Kooten, Elishevah M. M. E.; Wielandt, Daniel Kim Peel; Schiller, Martin

    2016-01-01

    product of (26)Al. This correlation is interpreted as reflecting progressive thermal processing of in-falling (26)Al-rich molecular cloud material in the inner Solar System. The thermally unprocessed molecular cloud matter reflecting the nucleosynthetic makeup of the molecular cloud before the last......)Mg*-depleted and (54)Cr-enriched component. This composition is consistent with that expected for thermally unprocessed primordial molecular cloud material before its pollution by stellar-derived (26)Al. The (26)Mg* and (54)Cr compositions of bulk metal-rich chondrites require significant amounts (25......-50%) of primordial molecular cloud matter in their precursor material. Given that such high fractions of primordial molecular cloud material are expected to survive only in the outer Solar System, we infer that, similarly to cometary bodies, metal-rich carbonaceous chondrites are samples of planetesimals...

  18. Near-infrared photometric study of open star cluster IC 1805

    International Nuclear Information System (INIS)

    Sagar, R.; Yu, Q.Z.

    1990-01-01

    The JHK magnitudes of 29 stars in the region of open star cluster IC 1805 were measured. These, and the existing infrared and optical observations, indicate a normal interstellar extinction law in the direction of the cluster. Further, most of the early-type stars have near-infrared fluxes as expected from their spectral types. Patchy distribution of ionized gas and dust appears to be the cause of nonuniform extinction across the cluster face. 36 refs

  19. Rich: Region-based Intelligent Cluster-Head Selection and Node Deployment Strategy in Concentric-based WSNs

    Directory of Open Access Journals (Sweden)

    FAN, C.-S.

    2013-11-01

    Full Text Available In a random deployment, sensor nodes are scattered randomly in the sensing field. Hence, the coverage can not be guaranteed. In contrast, the coverage of uniformly deployment is in general larger than the random deployment. However, uniformly deployment strategy may cause unbalanced traffic pattern in wireless sensor networks (WSNs. In this situation, larger load may be imposed to CHs (cluster heads around the sink. Therefore, CHs close to the sink use up their energy earlier than those farther away from the sink. To overcome this problem, we propose a novel node deployment strategy in the concentric model, namely, Region-based Intelligent Cluster-Head selection and node deployment strategy (called Rich. The coverage, energy consumption and data routing issues are well investigated and taken into consideration in the proposed Rich scheme. The simulation results show that the proposed Rich alleviates the unbalanced traffic pattern significantly, prolongs network lifetime and achieves satisfactory coverage ratio.

  20. Interstellar Extinction in 20 Open Star Clusters

    Science.gov (United States)

    Rangwal, Geeta; Yadav, R. K. S.; Durgapal, Alok K.; Bisht, D.

    2017-12-01

    The interstellar extinction law in 20 open star clusters namely, Berkeley 7, Collinder 69, Hogg 10, NGC 2362, Czernik 43, NGC 6530, NGC 6871, Bochum 10, Haffner 18, IC 4996, NGC 2384, NGC 6193, NGC 6618, NGC 7160, Collinder 232, Haffner 19, NGC 2401, NGC 6231, NGC 6823, and NGC 7380 have been studied in the optical and near-IR wavelength ranges. The difference between maximum and minimum values of E(B - V) indicates the presence of non-uniform extinction in all the clusters except Collinder 69, NGC 2362, and NGC 2384. The colour excess ratios are consistent with a normal extinction law for the clusters NGC 6823, Haffner 18, Haffner 19, NGC 7160, NGC 6193, NGC 2401, NGC 2384, NGC 6871, NGC 7380, Berkeley 7, Collinder 69, and IC 4996. We have found that the differential colour-excess ΔE(B - V), which may be due to the occurrence of dust and gas inside the clusters, decreases with the age of the clusters. A spatial variation of colour excess is found in NGC 6193 in the sense that it decreases from east to west in the cluster region. For the clusters Berkeley 7, NGC 7380, and NGC 6871, a dependence of colour excess E(B - V) with spectral class and luminosity is observed. Eight stars in Collinder 232, four stars in NGC 6530, and one star in NGC 6231 have excess flux in near-IR. This indicates that these stars may have circumstellar material around them.

  1. New projectiles: multicharged metal clusters and biopolymers

    International Nuclear Information System (INIS)

    Della-Negra, S.; Gardes, D.; Le Beyec, Y.; Waast, B.

    1991-01-01

    Metal clusters and molecules are the one mean to realize simultaneous impacts of several atoms on a reduced surface(∼100A). The interaction characteristics is the non-linearity of energy deposition; the perturbation that the cluster produces, is above than the sum of the perturbation induced by its components, taken separately. The purpose of ORION project is to accelerate these new projectiles at ORSAY Tandem. The considered mass range is from 100 Daltons to 100 000 Daltons and energy range from MeV to GeV

  2. Clustering of near clusters versus cluster compactness

    International Nuclear Information System (INIS)

    Yu Gao; Yipeng Jing

    1989-01-01

    The clustering properties of near Zwicky clusters are studied by using the two-point angular correlation function. The angular correlation functions for compact and medium compact clusters, for open clusters, and for all near Zwicky clusters are estimated. The results show much stronger clustering for compact and medium compact clusters than for open clusters, and that open clusters have nearly the same clustering strength as galaxies. A detailed study of the compactness-dependence of correlation function strength is worth investigating. (author)

  3. ISO far-infrared observations of rich galaxy clusters II. Sersic 159-03

    DEFF Research Database (Denmark)

    Hansen, Lene; Jørgensen, H.E.; Nørgaard-Nielsen, Hans Ulrik

    2000-01-01

    In a series of papers we investigate far-infrared emission from rich galaxy clusters. Maps have been obtained by ISO at 60 mu m, 100 mu m, 135 mu m, and 200 mu m using the PHT-C camera. Ground based imaging and spectroscopy were also acquired. Here we present the results for the cooling flow...

  4. Atomic bonding between metal and graphene

    KAUST Repository

    Wang, Hongtao

    2013-03-07

    To understand structural and chemical properties of metal-graphene composites, it is crucial to unveil the chemical bonding along the interface. We provide direct experimental evidence of atomic bonding between typical metal nano structures and graphene, agreeing well with density functional theory studies. Single Cr atoms are located in the valleys of a zigzag edge, and few-atom ensembles preferentially form atomic chains by self-assembly. Low migration barriers lead to rich dynamics of metal atoms and clusters under electron irradiation. We demonstrate no electron-instigated interaction between Cr clusters and pristine graphene, though Cr has been reported to be highly reactive to graphene. The metal-mediated etching is a dynamic effect between metal clusters and pre-existing defects. The resolved atomic configurations of typical nano metal structures on graphene offer insight into modeling and simulations on properties of metal-decorated graphene for both catalysis and future carbon-based electronics. © 2013 American Chemical Society.

  5. Differential dynamic microscopy of weakly scattering and polydisperse protein-rich clusters

    Science.gov (United States)

    Safari, Mohammad S.; Vorontsova, Maria A.; Poling-Skutvik, Ryan; Vekilov, Peter G.; Conrad, Jacinta C.

    2015-10-01

    Nanoparticle dynamics impact a wide range of biological transport processes and applications in nanomedicine and natural resource engineering. Differential dynamic microscopy (DDM) was recently developed to quantify the dynamics of submicron particles in solutions from fluctuations of intensity in optical micrographs. Differential dynamic microscopy is well established for monodisperse particle populations, but has not been applied to solutions containing weakly scattering polydisperse biological nanoparticles. Here we use bright-field DDM (BDDM) to measure the dynamics of protein-rich liquid clusters, whose size ranges from tens to hundreds of nanometers and whose total volume fraction is less than 10-5. With solutions of two proteins, hemoglobin A and lysozyme, we evaluate the cluster diffusion coefficients from the dependence of the diffusive relaxation time on the scattering wave vector. We establish that for weakly scattering populations, an optimal thickness of the sample chamber exists at which the BDDM signal is maximized at the smallest sample volume. The average cluster diffusion coefficient measured using BDDM is consistently lower than that obtained from dynamic light scattering at a scattering angle of 90∘. This apparent discrepancy is due to Mie scattering from the polydisperse cluster population, in which larger clusters preferentially scatter more light in the forward direction.

  6. Investigation of Galactic open cluster remnants: the case of NGC 7193

    Science.gov (United States)

    de Souza Angelo, Mateus; Francisco Coelho dos Santos, João, Jr.; Barbosa Corradi, Wagner José; Ferreira de Souza Maia, Francisco; Piatti, Andrés Eduardo

    2017-01-01

    Galactic open clusters (OCs) that survive the early gas-expulsion phase are gradually destroyed over time by the action of disruptive dynamical processes. Their final evolutionary stages are characterized by a poorly populated concentration of stars called an open cluster remnant (OCR). This study is devoted to assessing the real physical nature of the OCR candidate NGC 7193. GMOS/Gemini spectroscopy of 53 stars in the inner target region were obtained to derive radial velocities and atmospheric parameters. We also employed photometric and proper motion data. The analysis method consists of the following steps: (i) analysis of the statistical resemblance between the cluster and a set of field samples with respect to the sequences defined in color-magnitude diagrams (CMDs); (ii) a 5-dimensional iterative exclusion routine was employed to identify outliers from kinematical and positional data; (iii) isochrone fitting to the Ks×(J-Ks) CMD of the remaining stars and the dispersion of spectral types along empirical sequences in the (J-H)×(H-Ks) diagram were checked. A group of stars was identified for which the mean heliocentric distance is compatible with that obtained via isochrone fitting and whose metallicities are compatible with each other. Fifteen of the member stars observed spectroscopically were identified together with another 19 probable members. Our results indicate that NGC 7193 is a genuine OCR, of a once very populous OC, for which the following parameters were derived: d = 501±46 pc, t=2.5+/-1.2 Gyr, =-0.17+/-0.23 and E(B-V)=0.05+/-0.05. Its luminosity and mass functions show depletion of low mass stars, confirming the OCR is in a dynamically evolved state. Based on observations obtained at the Gemini Observatory, which is operated by the AURA under a cooperative agreement with the NSF on behalf of the Gemini partnership: NSF (United States), STFC (United Kingdom), NRC (Canada), CONICYT (Chile), ARC (Australia), CNPq (Brazil) and CONICET (Argentina).

  7. Distinct metal-exchange pathways of doped Ag25 nanoclusters

    KAUST Repository

    Bootharaju, Megalamane Siddaramappa

    2016-09-09

    Atomically precise metal nanoclusters (NCs) containing more than one type of metal atom (i.e., doped or alloyed), due to synergistic effects, open new avenues for engineering the catalytic and optical properties of NCs in a manner that homometal NCs cannot. Unfortunately, it is still a major challenge to controllably introduce multimetallic dopants in NCs, understanding the dopants\\' positions, mechanism, and synergistic effects. To overcome these challenges, we designed a metal-exchange approach involving NCs as molecular templates and metal ions as the source of the incoming dopant. In particular, two structurally similar monodoped silver-rich NCs, [MAg24(SR)(18)](2-) (M = Pd/Pt and SR: thiolate), were synthesized as templates to study their mechanistic transformation in response to the introduction of gold atoms. The controllable incorporation of Au atoms into the MAg24 framework facilitated the elucidation of distinct doping pathways through high-resolution mass spectrometry, optical spectroscopy and elemental analysis. Interestingly, gold replaced the central Pd atom of [PdAg24(SR)(18)](2-) clusters to produce predominantly bimetallic [AuAg24(SR)(18)](-) clusters along with a minor product of an [Au2Ag23(SR)(18)](-) cluster. In contrast, the central Pt atom remained intact in [PtAg24(SR)(18)](2-) clusters, and gold replaced the noncentral Ag atoms to form trimetallic [AuxPtAg24-x(SR)(18)](2-) NCs, where x = 1-2, with a portion of the starting [PtAg24(SR)(18)](2-) NCs remaining. This study reveals some of the unusual metal-exchange pathways of doped NCs and the important role played by the initial metal dopant in directing the position of a second dopant in the final product.

  8. Astrophysical parameters of ten poorly studied open star clusters

    International Nuclear Information System (INIS)

    Tadross, Ashraf Latif; El-Bendary, Reda; Osman, Anas; Ismail, Nader; Bakry, Abdel Aziz

    2012-01-01

    We present the fundamental parameters of ten open star clusters, nominated from Kronberger et al. who presented some newly discovered stellar groups on the basis of the Two Micron All Sky Survey photometry and Digitized Sky Survey visual images. Star counts and photometric parameters (radius, membership, distance, color excess, age, luminosity function, mass function, total mass, and dynamical relaxation time) have been determined for these ten clusters for the first time. In order to calibrate our procedures, the main parameters (distance, age, and color excess) have been re-estimated for another five clusters, which are also studied by Kronberger et al. (research papers)

  9. Proofs of cluster formation and transitions in liquid metals and alloys

    International Nuclear Information System (INIS)

    Filippov, E.S.

    1985-01-01

    Calculational and experimental proofs are presented indicating to existence of clusters in liquid metals and alloys. Systems of liquid alloys both on the base of ferrous metals and non-ferrous metals (Fe-C, Ni-C, Co-C, Fe-Ni, Ni-Mo, Co-Cr, Co-V as well as In-Sn, Bi-Sn, Si-Ge and others) are studied experimentally. It is shown that the general feature of the systems studied is sensitivity of a volume to change in structure, to replacement fcc structure on bcc or to initiation-dissociation of intermetallic compounds AxBy. It is shown that both in pure liquid metals and in their.alloys there are clusters as ordered aggregate of atoms

  10. The Problem of Hipparcos Distances to Open Clusters. Report 1; Constraints from Multicolor a Main-Sequence Fitting

    Science.gov (United States)

    Pinsonneault, Marc H.; Stauffer, John; Soderblom, David R.; King, Jeremy R.; Hanson, Robert B.

    1998-01-01

    Parallax data from the Hipparcos mission allow the direct distance to open clusters to be compared with the distance inferred from main-sequence (MS) fitting. There are surprising differences between the two distance measurements. indicating either the need for changes in the cluster compositions or reddening, underlying problems with the technique of MS fitting, or systematic errors in the Hipparcos parallaxes at the 1 mas level. We examine the different possibilities, focusing on MS fitting in both metallicity-sensitive B-V and metallicity-insensitive V-I for five well-studied systems (the Hyades, Pleiades, alpha Per, Praesepe, and Coma Ber). The Hipparcos distances to the Hyades and alpha Per are within 1 sigma of the MS-fitting distance in B-V and V-I, while the Hipparcos distances to Coma Ber and the Pleiades are in disagreement with the MS-fitting distance at more than the 3 sigma level. There are two Hipparcos measurements of the distance to Praesepe; one is in good agreement with the MS-fitting distance and the other disagrees at the 2 sigma level. The distance estimates from the different colors are in conflict with one another for Coma but in agreement for the Pleiades. Changes in the relative cluster metal abundances, age related effects, helium, and reddening are shown to be unlikely to explain the puzzling behavior of the Pleiades. We present evidence for spatially dependent systematic errors at the 1 mas level in the parallaxes of Pleiades stars. The implications of this result are discussed.

  11. AN EXTREME STARBURST IN THE CORE OF A RICH GALAXY CLUSTER AT z = 1.7

    International Nuclear Information System (INIS)

    Webb, Tracy; Bonaventura, Nina; Delahaye, Anna; Noble, Allison; Yee, H. K. C.; DeGroot, Andrew; Wilson, Gillian; Foltz, Ryan; Muzzin, Adam; Chapman, Scott; Cooper, Mike; Lidman, Chris; Surace, Jason; Dunne, Loretta; Geach, James; Hayden, Brian; Hildebrandt, Hendrik; Huang, Jiasheng; Pope, Alexandra; Smith, Matthew W. L.

    2015-01-01

    We have discovered an optically rich galaxy cluster at z = 1.7089 with star formation occurring in close proximity to the central galaxy. The system, SpARCS104922.6+564032.5, was detected within the Spitzer Adaptation of the red-sequence Cluster Survey, and confirmed through Keck-MOSFIRE spectroscopy. The rest-frame optical richness of N gal (500 kpc) = 30 ± 8 implies a total halo mass, within 500 kpc, of ∼3.8 ± 1.2 × 10 14 M ⊙ , comparable to other clusters at or above this redshift. There is a wealth of ancillary data available, including Canada–France–Hawaii Telescope optical, UKIRT-K, Spitzer-IRAC/MIPS, and Herschel-SPIRE. This work adds submillimeter imaging with the SCUBA2 camera on the James Clerk Maxwell Telescope and near-infrared imaging with the Hubble Space Telescope. The mid/far-infrared (M/FIR) data detect an Ultra-luminous Infrared Galaxy spatially coincident with the central galaxy, with L IR = 6.2 ± 0.9 × 10 12 L ⊙ . The detection of polycyclic aromatic hydrocarbons at z = 1.7 in a Spitzer-IRS spectrum of the source implies the FIR luminosity is dominated by star formation (an Active Galactic Nucleus contribution of 20%) with a rate of ∼860 ± 130 M ⊙ yr −1 . The optical source corresponding to the IR emission is likely a chain of >10 individual clumps arranged as “beads on a string” over a linear scale of 66 kpc. Its morphology and proximity to the Brightest Cluster Galaxy (BCG) imply a gas-rich interaction at the center of the cluster triggered the star formation. This system indicates that wet mergers may be an important process in forming the stellar mass of BCGs at early times

  12. AN EXTREME STARBURST IN THE CORE OF A RICH GALAXY CLUSTER AT z = 1.7

    Energy Technology Data Exchange (ETDEWEB)

    Webb, Tracy; Bonaventura, Nina; Delahaye, Anna [Department of Physics, McGill University, 3600 rue University, Montréal, Québec, H3P 1T3 (Canada); Noble, Allison; Yee, H. K. C. [Department of Astronomy and Astrophysics, University of Toronto, 50 St. George Street, Toronto, ON, M5S 3H4 (Canada); DeGroot, Andrew; Wilson, Gillian; Foltz, Ryan [Department of Physics and Astronomy, University of California, Riverside, 900 University Avenue, Riverside, CA 92521 (United States); Muzzin, Adam; Chapman, Scott [Institute of Astronomy, University of Cambridge, Madingley Road, Cambridge, CB3 0HA (United Kingdom); Cooper, Mike [Centre for Galaxy Evolution, Department of Physics and Astronomy, University of California, Irvine, 4129 Frederick Reines Hall, Irvine, CA 92697 (United States); Lidman, Chris [Australian Astronomical Observatory, P.O. Box 915, North Ryde, NSW 1670 (Australia); Surace, Jason [Spitzer Space Science Centre, California Institute of Technology, Pasadena, CA 91125 (United States); Dunne, Loretta [Department of Physics and Astronomy, University of Canterbury, Private Bag 4800, Christchurch 8140 (New Zealand); Geach, James [Center for Astrophysics Research, Science and Technology Research Institute, University of Hertfordshire, Hatfield AL10 9AB (United Kingdom); Hayden, Brian [Physics Division, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, CA 94720 (United States); Hildebrandt, Hendrik [Argelander-Institute fur Astronomie, Auf dem Hugel 71, D-53121 Bonn (Germany); Huang, Jiasheng [National Astronomical Observatories of China, Chinese Academy of Sciences, Beijing 100012 (China); Pope, Alexandra [Department of Astronomy, University of Massachusetts, 710 North Pleasant Street, Amherst, MA 011003 (United States); Smith, Matthew W. L. [School of Physics and Astronomy, Cardiff University, Queens Buildings, The Parade, Cardiff, Wales CF24 3AA (United Kingdom); and others

    2015-08-20

    We have discovered an optically rich galaxy cluster at z = 1.7089 with star formation occurring in close proximity to the central galaxy. The system, SpARCS104922.6+564032.5, was detected within the Spitzer Adaptation of the red-sequence Cluster Survey, and confirmed through Keck-MOSFIRE spectroscopy. The rest-frame optical richness of N{sub gal} (500 kpc) = 30 ± 8 implies a total halo mass, within 500 kpc, of ∼3.8 ± 1.2 × 10{sup 14} M{sub ⊙}, comparable to other clusters at or above this redshift. There is a wealth of ancillary data available, including Canada–France–Hawaii Telescope optical, UKIRT-K, Spitzer-IRAC/MIPS, and Herschel-SPIRE. This work adds submillimeter imaging with the SCUBA2 camera on the James Clerk Maxwell Telescope and near-infrared imaging with the Hubble Space Telescope. The mid/far-infrared (M/FIR) data detect an Ultra-luminous Infrared Galaxy spatially coincident with the central galaxy, with L{sub IR} = 6.2 ± 0.9 × 10{sup 12} L{sub ⊙}. The detection of polycyclic aromatic hydrocarbons at z = 1.7 in a Spitzer-IRS spectrum of the source implies the FIR luminosity is dominated by star formation (an Active Galactic Nucleus contribution of 20%) with a rate of ∼860 ± 130 M{sub ⊙} yr{sup −1}. The optical source corresponding to the IR emission is likely a chain of >10 individual clumps arranged as “beads on a string” over a linear scale of 66 kpc. Its morphology and proximity to the Brightest Cluster Galaxy (BCG) imply a gas-rich interaction at the center of the cluster triggered the star formation. This system indicates that wet mergers may be an important process in forming the stellar mass of BCGs at early times.

  13. Effect of functionalization of boron nitride flakes by main group metal clusters on their optoelectronic properties

    Science.gov (United States)

    Chakraborty, Debdutta; Chattaraj, Pratim Kumar

    2017-10-01

    The possibility of functionalizing boron nitride flakes (BNFs) with some selected main group metal clusters, viz. OLi4, NLi5, CLi6, BLI7 and Al12Be, has been analyzed with the aid of density functional theory (DFT) based computations. Thermochemical as well as energetic considerations suggest that all the metal clusters interact with the BNF moiety in a favorable fashion. As a result of functionalization, the static (first) hyperpolarizability (β ) values of the metal cluster supported BNF moieties increase quite significantly as compared to that in the case of pristine BNF. Time dependent DFT analysis reveals that the metal clusters can lower the transition energies associated with the dominant electronic transitions quite significantly thereby enabling the metal cluster supported BNF moieties to exhibit significant non-linear optical activity. Moreover, the studied systems demonstrate broad band absorption capability spanning the UV-visible as well as infra-red domains. Energy decomposition analysis reveals that the electrostatic interactions principally stabilize the metal cluster supported BNF moieties.

  14. Antisymmetrized molecular dynamics studies for exotic clustering phenomena in neutron-rich nuclei

    Energy Technology Data Exchange (ETDEWEB)

    Kimura, M. [Hokkaido University, Department of Physics, Sapporo (Japan); Hokkaido University, Nuclear Reaction Data Centre, Faculty of Science, Sapporo (Japan); Suhara, T. [Matsue College of Technology, Matsue (Japan); Kanada-En' yo, Y. [Kyoto University, Department of Physics, Kyoto (Japan)

    2016-12-15

    We present a review of recent works on clustering phenomena in unstable nuclei studied by antisymmetrized molecular dynamics (AMD). The AMD studies in these decades have uncovered novel types of clustering phenomena brought about by the excess neutrons. Among them, this review focuses on the molecule-like structure of unstable nuclei. One of the earliest discussions on the clustering in unstable nuclei was made for neutron-rich Be and B isotopes. AMD calculations predicted that the ground state clustering is enhanced or reduced depending on the number of excess neutrons. Today, the experiments are confirming this prediction as the change of the proton radii. Behind this enhancement and reduction of the clustering, there are underlying shell effects called molecular and atomic orbits. These orbits form covalent and ionic bonding of the clusters analogous to the atomic molecules. It was found that this ''molecular-orbit picture'' reasonably explains the low-lying spectra of Be isotopes. The molecular-orbit picture is extended to other systems having parity asymmetric cluster cores and to the three cluster systems. O and Ne isotopes are the candidates of the former, while the 3α linear chains in C isotopes are the latter. For both subjects, many intensive studies are now in progress. We also pay a special attention to the observables which are the fingerprint of the clustering. In particular, we focus on the monopole and dipole transitions which are recently regarded as good probe for the clustering. We discuss how they have and will reveal the exotic clustering. (orig.)

  15. jClustering, an open framework for the development of 4D clustering algorithms.

    Directory of Open Access Journals (Sweden)

    José María Mateos-Pérez

    Full Text Available We present jClustering, an open framework for the design of clustering algorithms in dynamic medical imaging. We developed this tool because of the difficulty involved in manually segmenting dynamic PET images and the lack of availability of source code for published segmentation algorithms. Providing an easily extensible open tool encourages publication of source code to facilitate the process of comparing algorithms and provide interested third parties with the opportunity to review code. The internal structure of the framework allows an external developer to implement new algorithms easily and quickly, focusing only on the particulars of the method being implemented and not on image data handling and preprocessing. This tool has been coded in Java and is presented as an ImageJ plugin in order to take advantage of all the functionalities offered by this imaging analysis platform. Both binary packages and source code have been published, the latter under a free software license (GNU General Public License to allow modification if necessary.

  16. Theoretical isochrones for old, super-metal-rich stars

    International Nuclear Information System (INIS)

    Vandenberg, D.A.; Laskarides, P.G.; National Capodistrian Univ., Athens, Greece)

    1987-01-01

    A new and up-to-date set of theoretical evolutionary sequences and isochrones for super-metal-rich stars is presented. Models have been constructed for metallicities as high as Z = 0.10 and masses in the range of mass/solar mass = 0.6-1.5, in order to calculate isochrones for ages from 6 to 18 Gyr. The latest Los Alamos opacities are utilized, which have a pronounced effect on predicted mass-luminosity relations, and a value of 1.5 is adopted for the mixing-length parameter, which is required to reproduce the properties of the sun. The detailed numerical results are expected to be particularly useful in the construction of population synthesis models. 48 references

  17. Cluster expansion of the wavefunction. Symmetry-adapted-cluster expansion, its variational determination, and extension of open-shell orbital theory

    International Nuclear Information System (INIS)

    Nakatsuji, H.; Hirao, K.

    1978-01-01

    The symmetry-adapted-cluster (SAC) expansion of an exact wavefunction is given. It is constructed from the generators of the symmetry-adapted excited configurations having the symmetry under consideration, and includes their higher-order effect and self-consistency effect. It is different from the conventional cluster expansions in several important points, and is suitable for applications to open-shell systems as well as closed-shell systems. The variational equation for the SAC wavefunction has a form similar to the generalized Brillouin theorem in accordance with the inclusion of the higher-order effect and the self-consistency effect. We have expressed some existing open-shell orbital theories equivalently in the conventional cluster expansion formulas, and on this basis, we have given the pseudo-orbital theory which is an extension of open-shell orbital theory in the SAC expansion formula

  18. Split and Compensated Hyperfine Fields in Magnetic Metal Clusters

    International Nuclear Information System (INIS)

    Nakamura, H.; Chudo, H.; Shiga, M.; Kohara, T.

    2004-01-01

    As prominent characteristics of magnetic metal cluster found in vanadium sulfides, we point out marked separation and compensation of the hyperfine field at the nuclear site; these are in somewhat discordance with the common sense for 3d transition-metal magnets, where the on-site isotropic field, scaling the ordered moment magnitude, is dominant.

  19. An efficient laser vaporization source for chemically modified metal clusters characterized by thermodynamics and kinetics

    Science.gov (United States)

    Masubuchi, Tsugunosuke; Eckhard, Jan F.; Lange, Kathrin; Visser, Bradley; Tschurl, Martin; Heiz, Ulrich

    2018-02-01

    A laser vaporization cluster source that has a room for cluster aggregation and a reactor volume, each equipped with a pulsed valve, is presented for the efficient gas-phase production of chemically modified metal clusters. The performance of the cluster source is evaluated through the production of Ta and Ta oxide cluster cations, TaxOy+ (y ≥ 0). It is demonstrated that the cluster source produces TaxOy+ over a wide mass range, the metal-to-oxygen ratio of which can easily be controlled by changing the pulse duration that influences the amount of reactant O2 introduced into the cluster source. Reaction kinetic modeling shows that the generation of the oxides takes place under thermalized conditions at less than 300 K, whereas metal cluster cores are presumably created with excess heat. These characteristics are also advantageous to yield "reaction intermediates" of interest via reactions between clusters and reactive molecules in the cluster source, which may subsequently be mass selected for their reactivity measurements.

  20. Spectroscopic Analyses of Neutron Capture Elements in Open Clusters

    Science.gov (United States)

    O'Connell, Julia E.

    The evolution of elements as a function or age throughout the Milky Way disk provides strong constraints for galaxy evolution models, and on star formation epochs. In an effort to provide such constraints, we conducted an investigation into r- and s-process elemental abundances for a large sample of open clusters as part of an optical follow-up to the SDSS-III/APOGEE-1 near infrared survey. To obtain data for neutron capture abundance analysis, we conducted a long-term observing campaign spanning three years (2013-2016) using the McDonald Observatory Otto Struve 2.1-meter telescope and Sandiford Cass Echelle Spectrograph (SES, R(lambda/Deltalambda) ˜60,000). The SES provides a wavelength range of ˜1400 A, making it uniquely suited to investigate a number of other important chemical abundances as well as the neutron capture elements. For this study, we derive abundances for 18 elements covering four nucleosynthetic families- light, iron-peak, neutron capture and alpha-elements- for ˜30 open clusters within 6 kpc of the Sun with ages ranging from ˜80 Myr to ˜10 Gyr. Both equivalent width (EW) measurements and spectral synthesis methods were employed to derive abundances for all elements. Initial estimates for model stellar atmospheres- effective temperature and surface gravity- were provided by the APOGEE data set, and then re-derived for our optical spectra by removing abundance trends as a function of excitation potential and reduced width log(EW/lambda). With the exception of Ba II and Zr I, abundance analyses for all neutron capture elements were performed by generating synthetic spectra from the new stellar parameters. In order to remove molecular contamination, or blending from nearby atomic features, the synthetic spectra were modeled by a best-fit Gaussian to the observed data. Nd II shows a slight enhancement in all cluster stars, while other neutron capture elements follow solar abundance trends. Ba II shows a large cluster-to-cluster abundance spread

  1. Photometry Using Kepler “Superstamps” of Open Clusters NGC 6791 & NGC 6819

    Directory of Open Access Journals (Sweden)

    Kuehn Charles A.

    2015-01-01

    Full Text Available The Kepler space telescope has proven to be a gold mine for the study of variable stars. Usually, Kepler only reads out a handful of pixels around each pre-selected target star, omitting a large number of stars in the Kepler field. Fortunately, for the open clusters NGC 6791 and NGC 6819, Kepler also read out larger “superstamps” which contained complete images of the central region of each cluster. These cluster images can be used to study additional stars in the open clusters that were not originally on Kepler’s target list. We discuss our work on using two photometric techniques to analyze these superstamps and present sample results from this project to demonstrate the value of this technique for a wide variety of variable stars.

  2. Search for and Investigation of Double Open Clusters

    Directory of Open Access Journals (Sweden)

    Yalyalieva L. N.

    2016-12-01

    Full Text Available The physical and kinematical parameters of three pairs of open clusters, NGC 6755 and Czernik 39, NGC 1857 and Czernik 20, Berkeley 70 and SAI 47, are determined using the data from several photometric catalogs in order to confirm or disprove the binarity of these pairs.

  3. Massive open star clusters using the VVV survey. II. Discovery of six clusters with Wolf-Rayet stars

    Science.gov (United States)

    Chené, A.-N.; Borissova, J.; Bonatto, C.; Majaess, D. J.; Baume, G.; Clarke, J. R. A.; Kurtev, R.; Schnurr, O.; Bouret, J.-C.; Catelan, M.; Emerson, J. P.; Feinstein, C.; Geisler, D.; de Grijs, R.; Hervé, A.; Ivanov, V. D.; Kumar, M. S. N.; Lucas, P.; Mahy, L.; Martins, F.; Mauro, F.; Minniti, D.; Moni Bidin, C.

    2013-01-01

    Context. The ESO Public Survey "VISTA Variables in the Vía Láctea" (VVV) provides deep multi-epoch infrared observations for an unprecedented 562 sq. degrees of the Galactic bulge, and adjacent regions of the disk. Nearly 150 new open clusters and cluster candidates have been discovered in this survey. Aims: This is the second in a series of papers about young, massive open clusters observed using the VVV survey. We present the first study of six recently discovered clusters. These clusters contain at least one newly discovered Wolf-Rayet (WR) star. Methods: Following the methodology presented in the first paper of the series, wide-field, deep JHKs VVV observations, combined with new infrared spectroscopy, are employed to constrain fundamental parameters for a subset of clusters. Results: We find that the six studied stellar groups are real young (2-7 Myr) and massive (between 0.8 and 2.2 × 103 M⊙) clusters. They are highly obscured (AV ~ 5-24 mag) and compact (1-2 pc). In addition to WR stars, two of the six clusters also contain at least one red supergiant star, and one of these two clusters also contains a blue supergiant. We claim the discovery of 8 new WR stars, and 3 stars showing WR-like emission lines which could be classified WR or OIf. Preliminary analysis provides initial masses of ~30-50 M⊙ for the WR stars. Finally, we discuss the spiral structure of the Galaxy using the six new clusters as tracers, together with the previously studied VVV clusters. Based on observations with ISAAC, VLT, ESO (programme 087.D-0341A), New Technology Telescope at ESO's La Silla Observatory (programme 087.D-0490A) and with the Clay telescope at the Las Campanas Observatory (programme CN2011A-086). Also based on data from the VVV survey (programme 172.B-2002).

  4. Primordial inhomogeneities in the expanding universe. I - Density and velocity distributions of galaxies in the vicinities of rich clusters

    Science.gov (United States)

    Silk, J.; Wilson, M. L.

    1979-01-01

    The density profiles and Hubble flow deviations in the vicinities of rich galaxy clusters are derived for a variety of models of initial density and velocity perturbations at the recombination epoch. The galaxy correlation function, measured with respect to the Abell clusters, is used to normalize the theoretical models. The angular scales of the required primordial inhomogeneities are calculated. It is found that the resulting density profiles around rich clusters are surprisingly insensitive to the shape of the initial perturbations and also to the cosmological density parameter, Omega. However, it is shown that the distribution of galaxy radial velocities can provide a possible means of deriving Omega.

  5. Disintegration of the Aged Open Cluster Berkeley 17

    Energy Technology Data Exchange (ETDEWEB)

    Bhattacharya, Souradeep; Vaidya, Kaushar [Department of Physics, Birla Institute of Technology and Science, Pilani 333031, Rajasthan (India); Mishra, Ishan [Indian Institute of Technology Guwahati, Guwahati 781039, Assam (India); Chen, W. P., E-mail: f2012553@pilani.bits-pilani.ac.in [Graduate Institute of Astronomy, National Central University, 300 Jhongda Road, Jhongli 32001, Taiwan (China)

    2017-10-01

    We present the analysis of the morphological shape of Berkeley 17, the oldest known open cluster (∼10 Gyr), using the probabilistic star counting of Pan-STARRS point sources, and confirm its core-tail shape, plus an antitail, previously detected with the 2MASS data. The stellar population, as diagnosed by the color–magnitude diagram and theoretical isochrones, shows many massive members in the clusters core, whereas there is a paucity of such members in both of the tails. This manifests mass segregation in this aged star cluster with the low-mass members being stripped away from the system. It has been claimed that Berkeley 17 is associated with an excessive number of blue straggler candidates. A comparison of nearby reference fields indicates that about half of these may be field contamination.

  6. The evoluation of the galactic globular clusters; I Metal abundance calibrations

    International Nuclear Information System (INIS)

    Lee, S.W.; Park, N.K.

    1984-01-01

    Five different calibrations of metal abundances of globular clusters are examined and these are compared with metallicity ranking parameters such as (Sp)sub(c), , Q39 and IR-indices. Except for the calibration *(Fe/H*)sub(H) by the high dispersion echelle analysis, the other calibration scales are correlated with the morphological parameters of red giant branch. In the *(Fe/H*)sub(Hsup(-))scale, the clusters later than approx.F8 have nearly a constant metal abundance, *(Fe/H*)sub(H)approx.-1.05, regardless of morphological characteristics of horizontal branch and red giant branch. By the two fundamental calibration scales of *(Fe/H*)sub(L) (derived by the low dispersion analysis), and *(Fe/H*)sub(delta S) (derived by the spectral analysis of RR Lyrae stars), the globular clusters are divided into the halo clusters with *(Fe/H*)<-1.0 and the disk clusters confined within the galactocentric distance rsub(G)=10 kpc and galactic plane distance absolute z=3 kpc. In this case the abundance gradient is given by d*(Fe/H*)/drsub(G)approx.-0.05kpcsup(-1) and d*(Fe/H*)/d absolute z approx. -0.08 kpcsup(-1) within rsub(G)=20 kpc and absolute z=10 kpc, respectively. According to these characteristics of the spatial distribution of globular clusters, the chemical evolution of the galactic globular clusters can be accounted for by the two-zone (disk-halo) slow collapse model when the *(Fe/H*)sub(Lsup(-)) or *(Fe/H*)sub(DELTA Ssup(-))scale is applied. In the case of *(Fe/H*)sub(Hsup(-))scale, the one-zone fast collapse model is preferred for the evolution of globular clusters. (Author)

  7. Astrometric and photometric study of the open cluster NGC 2323

    Directory of Open Access Journals (Sweden)

    Amin M.Y.

    2017-01-01

    Full Text Available We present a study of the open cluster NGC 2323 using astrometric and photometric data. In our study we used two methods that are able to separate open cluster’s stars from those that belong to the stellar background. Our results of calculations by these two methods indicate that: 1 according to the membership probability, NGC 2323 should contain 497 stars, 2 the cluster center should be at 07h 02m 48.s02 and -08° 20' 17''74,3 the limiting radius of NGC 2323 is 2.31 ± 0.04 pc, the surface number density at this radius is 98.16 stars pc −2, 4 the magnitude function has a maximum at about mv = 14 mag, 5 the total mass of NGC 2323 is estimated dynamically by using astrometric data to be 890 M_, and statistically by using photometric data to be 900 M_, and 6 the distance and age of the cluster are found to be equal to 900 ± 100 pc, and 140 ± 20 Myr, respectively. Finally the dynamical evolution parameter τ of the cluster is about 436.2.

  8. Effect of the horizontal branch on the colours of globular clusters

    Energy Technology Data Exchange (ETDEWEB)

    Sil' chenko, O K [Moskovskij Gosudarstvennyj Univ. (USSR). Gosudarstvennyj Astronomicheskij Inst. ' ' GAISh' '

    1963-05-01

    The influence of the horizontal branch (HB) on the integral UBV colours of globular clusters is studied by means of statistical analysis of the colour-magnitude diagram catalogue for globular clusters of our Galaxy. The colour correction for HB is shown to be always negative. It turns out to be small for m. tal-rich globular clusters ((Fe/H)>-1.1) and independent on the HB shape for metal-poor ones.

  9. Effect of the horizontal branch on the colours of globular clusters

    International Nuclear Information System (INIS)

    Sil'chenko, O.K.

    1963-01-01

    The influence of the horizontal branch (HB) on the integral UBV colours of globular clusters is studied by means of statistical analysis of the colour-magnitude diagram catalogue for globular clusters of our Galaxy. The colour correction for HB is shown to be always negative. It turns out to be small for m. tal-rich globular clusters ([Fe/H]>-1.1) and independent on the HB shape for metal-poor ones

  10. CAMPAIGN: an open-source library of GPU-accelerated data clustering algorithms.

    Science.gov (United States)

    Kohlhoff, Kai J; Sosnick, Marc H; Hsu, William T; Pande, Vijay S; Altman, Russ B

    2011-08-15

    Data clustering techniques are an essential component of a good data analysis toolbox. Many current bioinformatics applications are inherently compute-intense and work with very large datasets. Sequential algorithms are inadequate for providing the necessary performance. For this reason, we have created Clustering Algorithms for Massively Parallel Architectures, Including GPU Nodes (CAMPAIGN), a central resource for data clustering algorithms and tools that are implemented specifically for execution on massively parallel processing architectures. CAMPAIGN is a library of data clustering algorithms and tools, written in 'C for CUDA' for Nvidia GPUs. The library provides up to two orders of magnitude speed-up over respective CPU-based clustering algorithms and is intended as an open-source resource. New modules from the community will be accepted into the library and the layout of it is such that it can easily be extended to promising future platforms such as OpenCL. Releases of the CAMPAIGN library are freely available for download under the LGPL from https://simtk.org/home/campaign. Source code can also be obtained through anonymous subversion access as described on https://simtk.org/scm/?group_id=453. kjk33@cantab.net.

  11. Properties of the disk system of globular clusters

    International Nuclear Information System (INIS)

    Armandroff, T.E.

    1989-01-01

    A large refined data sample is used to study the properties and origin of the disk system of globular clusters. A scale height for the disk cluster system of 800-1500 pc is found which is consistent with scale-height determinations for samples of field stars identified with the Galactic thick disk. A rotational velocity of 193 + or - 29 km/s and a line-of-sight velocity dispersion of 59 + or - 14 km/s have been found for the metal-rich clusters. 70 references

  12. X-ray emission from open star clusters with Spectrum-Rontgen-Gamma

    DEFF Research Database (Denmark)

    Singh, K.P.; Ojha, D.K.; Schnopper, H.W.

    1998-01-01

    The study of X-ray emission from co-evolving populations of stars in open dusters is extremely important for understanding the dynamo activity among the stars. With this objective, we propose to observe a number of open clusters in the X-ray and UV bands using SPECTRUM-Rontgen-Gamma. The high...... throughput of SPECTRUM-Rontgen-Gamma will help detect main sequence stars like Sun in middle-aged and old clusters. We will study the relationships between various parameters - age, rotation, abundance, UBV colors, X-ray luminosity, coronal temperature etc. X-ray spectra of younger and brighter populations...

  13. Bayesian investigation of isochrone consistency using the old open cluster NGC 188

    Energy Technology Data Exchange (ETDEWEB)

    Hills, Shane; Courteau, Stéphane [Department of Physics, Engineering Physics and Astronomy, Queen’s University, Kingston, ON K7L 3N6 Canada (Canada); Von Hippel, Ted [Department of Physical Sciences, Embry-Riddle Aeronautical University, Daytona Beach, FL 32114 (United States); Geller, Aaron M., E-mail: shane.hills@queensu.ca, E-mail: courteau@astro.queensu.ca, E-mail: ted.vonhippel@erau.edu, E-mail: a-geller@northwestern.edu [Center for Interdisciplinary Exploration and Research in Astrophysics (CIERA) and Department of Physics and Astronomy, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208 (United States)

    2015-03-01

    This paper provides a detailed comparison of the differences in parameters derived for a star cluster from its color–magnitude diagrams (CMDs) depending on the filters and models used. We examine the consistency and reliability of fitting three widely used stellar evolution models to 15 combinations of optical and near-IR photometry for the old open cluster NGC 188. The optical filter response curves match those of theoretical systems and are thus not the source of fit inconsistencies. NGC 188 is ideally suited to this study thanks to a wide variety of high-quality photometry and available proper motions and radial velocities that enable us to remove non-cluster members and many binaries. Our Bayesian fitting technique yields inferred values of age, metallicity, distance modulus, and absorption as a function of the photometric band combinations and stellar models. We show that the historically favored three-band combinations of UBV and VRI can be meaningfully inconsistent with each other and with longer baseline data sets such as UBVRIJHK{sub S}. Differences among model sets can also be substantial. For instance, fitting Yi et al. (2001) and Dotter et al. (2008) models to UBVRIJHK{sub S} photometry for NGC 188 yields the following cluster parameters: age = (5.78 ± 0.03, 6.45 ± 0.04) Gyr, [Fe/H] = (+0.125 ± 0.003, −0.077 ± 0.003) dex, (m−M){sub V} = (11.441 ± 0.007, 11.525 ± 0.005) mag, and A{sub V} = (0.162 ± 0.003, 0.236 ± 0.003) mag, respectively. Within the formal fitting errors, these two fits are substantially and statistically different. Such differences among fits using different filters and models are a cautionary tale regarding our current ability to fit star cluster CMDs. Additional modeling of this kind, with more models and star clusters, and future Gaia parallaxes are critical for isolating and quantifying the most relevant uncertainties in stellar evolutionary models.

  14. A SPECTROSCOPIC ANALYSIS OF THE GALACTIC GLOBULAR CLUSTER NGC 6273 (M19)

    Energy Technology Data Exchange (ETDEWEB)

    Johnson, Christian I.; Caldwell, Nelson [Harvard–Smithsonian Center for Astrophysics, 60 Garden Street, MS-15, Cambridge, MA 02138 (United States); Rich, R. Michael [Department of Physics and Astronomy, UCLA, 430 Portola Plaza, Box 951547, Los Angeles, CA 90095-1547 (United States); Pilachowski, Catherine A. [Astronomy Department, Indiana University Bloomington, Swain West 319, 727 East 3rd Street, Bloomington, IN 47405-7105 (United States); Mateo, Mario; Bailey, John I. III [Department of Astronomy, University of Michigan, Ann Arbor, MI 48109 (United States); Crane, Jeffrey D., E-mail: cjohnson@cfa.harvard.edu, E-mail: ncaldwell@cfa.harvard.edu, E-mail: rmr@astro.ucla.edu, E-mail: catyp@astro.indiana.edu, E-mail: mmateo@umich.edu, E-mail: baileyji@umich.edu, E-mail: crane@obs.carnegiescience.edu [The Observatories of the Carnegie Institution for Science, Pasadena, CA 91101 (United States)

    2015-08-15

    A combined effort utilizing spectroscopy and photometry has revealed the existence of a new globular cluster class. These “anomalous” clusters, which we refer to as “iron-complex” clusters, are differentiated from normal clusters by exhibiting large (≳0.10 dex) intrinsic metallicity dispersions, complex sub-giant branches, and correlated [Fe/H] and s-process enhancements. In order to further investigate this phenomenon, we have measured radial velocities and chemical abundances for red giant branch stars in the massive, but scarcely studied, globular cluster NGC 6273. The velocities and abundances were determined using high resolution (R ∼ 27,000) spectra obtained with the Michigan/Magellan Fiber System (M2FS) and MSpec spectrograph on the Magellan–Clay 6.5 m telescope at Las Campanas Observatory. We find that NGC 6273 has an average heliocentric radial velocity of +144.49 km s{sup −1} (σ = 9.64 km s{sup −1}) and an extended metallicity distribution ([Fe/H] = −1.80 to −1.30) composed of at least two distinct stellar populations. Although the two dominant populations have similar [Na/Fe], [Al/Fe], and [α/Fe] abundance patterns, the more metal-rich stars exhibit significant [La/Fe] enhancements. The [La/Eu] data indicate that the increase in [La/Fe] is due to almost pure s-process enrichment. A third more metal-rich population with low [X/Fe] ratios may also be present. Therefore, NGC 6273 joins clusters such as ω Centauri, M2, M22, and NGC 5286 as a new class of iron-complex clusters exhibiting complicated star formation histories.

  15. Collaborative Research of Open Star Clusters Alisher S. Hojaev

    Indian Academy of Sciences (India)

    Some spectra of the young star candidates with dispersion 50 and 200 Å/mm were .... Color-magnitude diagram for o band and o band minus i band for stars in the region of NGC ... Statistical analysis for open cluster parameters investigation.

  16. 25. Steenbock symposium -- Biosynthesis and function of metal clusters for enzymes: Proceedings

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-12-31

    This symposium was held June 10--14, 1997 in Madison, Wisconsin. The purpose of this conference was to provide a multidisciplinary forum for exchange of state-of-the-art information on biochemistry of enzymes that have an affinity for metal clusters. Attention is focused on the following: metal clusters involved in energy conservation and remediation; tungsten, molybdenum, and cobalt-containing enzymes; Fe proteins, and Mo-binding proteins; nickel enzymes; and nitrogenase.

  17. The properties of the disk system of globular clusters

    Science.gov (United States)

    Armandroff, Taft E.

    1989-01-01

    A large refined data sample is used to study the properties and origin of the disk system of globular clusters. A scale height for the disk cluster system of 800-1500 pc is found which is consistent with scale-height determinations for samples of field stars identified with the Galactic thick disk. A rotational velocity of 193 + or - 29 km/s and a line-of-sight velocity dispersion of 59 + or - 14 km/s have been found for the metal-rich clusters.

  18. Chemical probes of metal cluster structure--Fe, Co, Ni, and Cu

    International Nuclear Information System (INIS)

    Parks, E.K.; Zhu, L.; Ho, J.; Riley, S.J.

    1992-01-01

    Chemical reactivity is one of the few methods currently available for investigating the geometrical structure of isolated transition metal clusters. In this paper we summarize what is currently known about the structures of clusters of four transition metals, Fe, Co, Ni, and Cu, in the size range from 13 to 180 atoms. Chemical probes used to determine structural information include reactions with H 2 (D 2 ), H 2 0, NH 3 and N 2 . Measurements at both low coverage and at saturation are discussed

  19. RUPRECHT 147: THE OLDEST NEARBY OPEN CLUSTER AS A NEW BENCHMARK FOR STELLAR ASTROPHYSICS

    Energy Technology Data Exchange (ETDEWEB)

    Curtis, Jason L.; Wright, Jason T. [Department of Astronomy and Astrophysics, The Pennsylvania State University, University Park, PA 16802 (United States); Wolfgang, Angie [Department of Astronomy and Astrophysics, University of California, Santa Cruz, CA 95064 (United States); Brewer, John M. [Department of Astronomy, Yale University, New Haven, CT 06511 (United States); Johnson, John Asher, E-mail: jcurtis@psu.edu [Department of Astrophysics, California Institute of Technology, Pasadena, CA 91125 (United States)

    2013-05-15

    Ruprecht 147 is a hitherto unappreciated open cluster that holds great promise as a standard in fundamental stellar astrophysics. We have conducted a radial velocity survey of astrometric candidates with Lick, Palomar, and MMT observatories and have identified over 100 members, including 5 blue stragglers, 11 red giants, and 5 double-lined spectroscopic binaries (SB2s). We estimate the cluster metallicity from spectroscopic analysis, using Spectroscopy Made Easy (SME), and find it to be [M/H] = +0.07 {+-} 0.03. We have obtained deep CFHT/MegaCam g'r'i'z' photometry and fit Padova isochrones to the (g' - i') and Two Micron All Sky Survey (J - K{sub S} ) color-magnitude diagrams, using the {tau}{sup 2} maximum-likelihood procedure of Naylor, and an alternative method using two-dimensional cross-correlations developed in this work. We find best fits for Padova isochrones at age t = 2.5 {+-} 0.25 Gyr, m - M = 7.35 {+-} 0.1, and A{sub V} = 0.25 {+-} 0.05, with additional uncertainty from the unresolved binary population and possibility of differential extinction across this large cluster. The inferred age is heavily dependent on our choice of stellar evolution model: fitting Dartmouth and PARSEC models yield age parameters of 3 Gyr and 3.25 Gyr, respectively. At {approx}300 pc and {approx}3 Gyr, Ruprecht 147 is by far the oldest nearby star cluster.

  20. RUPRECHT 147: THE OLDEST NEARBY OPEN CLUSTER AS A NEW BENCHMARK FOR STELLAR ASTROPHYSICS

    International Nuclear Information System (INIS)

    Curtis, Jason L.; Wright, Jason T.; Wolfgang, Angie; Brewer, John M.; Johnson, John Asher

    2013-01-01

    Ruprecht 147 is a hitherto unappreciated open cluster that holds great promise as a standard in fundamental stellar astrophysics. We have conducted a radial velocity survey of astrometric candidates with Lick, Palomar, and MMT observatories and have identified over 100 members, including 5 blue stragglers, 11 red giants, and 5 double-lined spectroscopic binaries (SB2s). We estimate the cluster metallicity from spectroscopic analysis, using Spectroscopy Made Easy (SME), and find it to be [M/H] = +0.07 ± 0.03. We have obtained deep CFHT/MegaCam g'r'i'z' photometry and fit Padova isochrones to the (g' – i') and Two Micron All Sky Survey (J – K S ) color-magnitude diagrams, using the τ 2 maximum-likelihood procedure of Naylor, and an alternative method using two-dimensional cross-correlations developed in this work. We find best fits for Padova isochrones at age t = 2.5 ± 0.25 Gyr, m – M = 7.35 ± 0.1, and A V = 0.25 ± 0.05, with additional uncertainty from the unresolved binary population and possibility of differential extinction across this large cluster. The inferred age is heavily dependent on our choice of stellar evolution model: fitting Dartmouth and PARSEC models yield age parameters of 3 Gyr and 3.25 Gyr, respectively. At ∼300 pc and ∼3 Gyr, Ruprecht 147 is by far the oldest nearby star cluster.

  1. First-principles studies on graphene-supported transition metal clusters

    International Nuclear Information System (INIS)

    Sahoo, Sanjubala; Khanna, Shiv N.; Gruner, Markus E.; Entel, Peter

    2014-01-01

    Theoretical studies on the structure, stability, and magnetic properties of icosahedral TM 13 (TM = Fe, Co, Ni) clusters, deposited on pristine (defect free) and defective graphene sheet as well as graphene flakes, have been carried out within a gradient corrected density functional framework. The defects considered in our study include a carbon vacancy for the graphene sheet and a five-membered and a seven-membered ring structures for graphene flakes (finite graphene chunks). It is observed that the presence of defect in the substrate has a profound influence on the electronic structure and magnetic properties of graphene-transition metal complexes, thereby increasing the binding strength of the TM cluster on to the graphene substrate. Among TM 13 clusters, Co 13 is absorbed relatively more strongly on pristine and defective graphene as compared to Fe 13 and Ni 13 clusters. The adsorbed clusters show reduced magnetic moment compared to the free clusters

  2. The effect of alkylating agents on model supported metal clusters

    Energy Technology Data Exchange (ETDEWEB)

    Erdem-Senatalar, A.; Blackmond, D.G.; Wender, I. (Pittsburgh Univ., PA (USA). Dept. of Chemical and Petroleum Engineering); Oukaci, R. (CERHYD, Algiers (Algeria))

    1988-01-01

    Interactions between model supported metal clusters and alkylating agents were studied in an effort to understand a novel chemical trapping technique developed for identifying species adsorbed on catalyst surfaces. It was found that these interactions are more complex than had previously been suggested. Studies were completed using deuterium-labeled dimethyl sulfate (DMS), (CH{sub 3}){sub 2}SO{sub 4}, as a trapping agent to interact with the supported metal cluster ethylidyne tricobalt enneacarbonyl. Results showed that oxygenated products formed during the trapping reaction contained {minus}OCD{sub 3} groups from the DMS, indicating that the interaction was not a simple alkylation. 18 refs., 1 fig., 3 tabs.

  3. Study of II Galactic quadrant of Milky Way Galaxy using open clusters

    Science.gov (United States)

    Bisht, Devendra; Ganesh, Shashikiran; Baliyan, Kiran Singh; Yadav, Ramakant Singh; Durgapal, Alok

    2018-04-01

    We have made UBV I CCD observations for the open clusters Teutsch 1, Riddle 4 and Czernik 6 using 1.04-m Sampurnanand telescope located at the ARIES observatory (Manora peak, Nainital, India). We have used 2MASS JHKS data for the clusters Teutsch 126, Teutsch 54 and Czernik 3. For the estimation of fundamental parameters, we have plotted radial density profiles, colour-magnitude and colour-colour diagrams. Using these inputs, we have studied the structure of Milky Way Galaxy in the second Galactic quadrant. We have considered the open clusters that are younger than 1 Gyrs and lay in the longitude range from 90 to 180 deg. Our study shows that up to 3.5 Kpc, the Galactic disc bends towards the southern hemisphere while after 3.5 Kpc it bends towards the northern hemisphere. The distribution of reddening with longitude and age shows a decreasing trend with the longitude and age of the clusters. Our study also indicates that younger clusters have more reddening than older ones.

  4. On the nature of the Cu-rich aggregates in brain astrocytes

    Energy Technology Data Exchange (ETDEWEB)

    Sullivan, Brendan; Robison, Gregory; Osborn, Jenna; Kay, Martin; Thompson, Peter; Davis, Katherine; Zakharova, Taisiya; Antipova, Olga; Pushkar, Yulia

    2017-04-01

    Fulfilling a bevy of biological roles, copper is an essential metal for healthy brain function. Cu dyshomeostasis has been demonstrated to be involved in some neurological conditions including Menkes and Alzheimer’s diseases. We have previously reported localized Cu-rich aggregates in astrocytes of the subventricular zone (SVZ) in rodent brains with Cu concentrations in the hundreds of millimolar. Metallothionein, a cysteine-rich protein critical to metal homeostasis and known to participate in a variety of neuroprotective and neuroregenerative processes, was proposed as a binding protein. Here, we present an analysis of metallothionein(1,2) knockout (MTKO) mice and age-matched controls using X-ray fluorescence microscopy. In large structures such as the corpus callosum, cortex, and striatum, there is no significant difference in Cu, Fe, or Zn concentrations in MTKO mice compared to age-matched controls. In the astrocyte-rich subventricular zone where Cu-rich aggregates reside, approximately 1/3 as many Cu-rich aggregates persist in MTKO mice resulting in a decrease in periventricular Cu concentration. Aggregates in both wild-type and MTKO mice show XANES spectra characteristic of CuxSy multimetallic clusters and have similar [S]/[Cu] ratios. Consistent with assignment as a CuxSy multimetallic cluster, the astrocyte-rich SVZ of both MTKO and wild-type mice exhibit autofluorescent bodies, though MTKO mice exhibit fewer. Furthermore, XRF imaging of Au-labeled lysosomes and ubiquitin demonstrates a lack of co-localization with Cu-rich aggregates suggesting they are not involved in a degradation pathway. Overall, these data suggest that Cu in aggregates is bound by either metallothionein-3 or a yet unknown protein similar to metallothionein.

  5. CCD photometry of the distant young open cluster NGC 7510

    International Nuclear Information System (INIS)

    Sagar, R.; Bonn Univ.; Griffiths, W.K.

    1991-01-01

    CCD observations in B, V and I passbands have been used to generate deep V, (B-V) and V,(V-I) colour-magnitude diagrams for the open cluster NGC 7510. The sample consists of 592 stars reaching down to V=21 mag. There appears to be non-uniform extinction over the face of the cluster with the value of colour excess, E(B-V), ranging from 1.0 to 1.3 mag. The law of interstellar extinction in the direction of the cluster is found to be normal. A broad main sequence is clearly visible in both colour-magnitude diagrams. From the bluest part of the colour-magnitude diagrams, the true distance modulus to the cluster has been estimated as 12.5±0.3 mag and an upper limit of 10 Myr has been assigned for the cluster age. (author)

  6. Cluster harvesting by successive reduction of a metal halide with a nonconventional reduction agent: a benefit for the exploration of metal-rich halide systems.

    Science.gov (United States)

    Ströbele, Markus; Mos, Agnieszka; Meyer, Hans-Jürgen

    2013-06-17

    The preparation of thermally labile compounds is a great temptation in chemistry which requires a careful selection of reaction media and reaction conditions. With a new scanning technique denoted here as Cluster Harvesting, a whole series of metal halide compounds is detected by differential thermal analysis (DTA) in fused silica tubes and structurally characterized by X-ray powder diffraction. Experiments of the reduction of tungsten hexahalides with elemental antimony and iron are presented. A cascade of six compounds is identified during the reduction with antimony, and five compounds or phases are monitored following the reduction with iron. The crystal structure of Fe2W2Cl10 is reported, and two other phases in the Fe-W-Cl system are discussed.

  7. Mass spectrometric production of heterogeneous metal clusters using Knudsen cell

    Directory of Open Access Journals (Sweden)

    Veljković Filip M.

    2016-01-01

    Full Text Available Knudsen effusion mass spectrometry or high-temperature method of mass spectrometry for decades gives new information about saturated vapor of hardly volatile compounds and it is an important method in the discovery of many new molecules, radicals, ions and clusters present in the gas phase. Since pioneering works until now, this method has been successfully applied to a large number of systems (ores, oxides, ceramics, glass materials, borides, carbides, sulfides, nitrates, metals, fullerenes, etc which led to the establishment of various research branches such as chemistry of clusters. This paper describes the basic principles of Knudsen cell use for both identification of chemical species created in the process of evaporation and determination of their ionization energies. Depending on detected ions intensities and the partial pressure of each gaseous component, as well as on changes in partial pressure with temperature, Knudsen cell mass spectrometry enables the determination of thermodynamic parameters of the tested system. A special attention is paid to its application in the field of small heterogeneous and homogeneous clusters of alkali metals. Furthermore, experimental results for thermodynamic parameters of some clusters, as well as capabilities of non-standard ways of using Knudsen cells in the process of synthesis of new clusters are presented herein. [Projekat Ministarstva nauke Republike Srbije, br. 172019

  8. Comparing the OpenMP, MPI, and Hybrid Programming Paradigm on an SMP Cluster

    Science.gov (United States)

    Jost, Gabriele; Jin, Hao-Qiang; anMey, Dieter; Hatay, Ferhat F.

    2003-01-01

    Clusters of SMP (Symmetric Multi-Processors) nodes provide support for a wide range of parallel programming paradigms. The shared address space within each node is suitable for OpenMP parallelization. Message passing can be employed within and across the nodes of a cluster. Multiple levels of parallelism can be achieved by combining message passing and OpenMP parallelization. Which programming paradigm is the best will depend on the nature of the given problem, the hardware components of the cluster, the network, and the available software. In this study we compare the performance of different implementations of the same CFD benchmark application, using the same numerical algorithm but employing different programming paradigms.

  9. Fluorine and Sodium in C-rich Low-metallicity Stars

    Science.gov (United States)

    Lucatello, Sara; Masseron, Thomas; Johnson, Jennifer A.; Pignatari, Marco; Herwig, Falk

    2011-03-01

    We present the N, O, F, and Na abundance and 12C/13C isotopic ratio measurements or upper limits for a sample of 10 C-rich, metal-poor giant stars: 8 enhanced in s-process (CEMP-s) elements and 2 poor in n-capture elements (CEMP-no). The abundances are derived from IR, K-band, high-resolution CRIRES@VLT obtained spectra. The metallicity of our sample ranges from [Fe/H] = -3.4 to -1.3. F abundance could be measured only in two CEMP-s stars. With [F/Fe] = 0.64, one is mildly F-overabundant, while the other is F-rich, at [F/Fe] = 1.44. For the remaining eight objects, including both CEMP-no stars in our sample, only upper limits on F abundance could be placed. Our measurements and upper limits show that there is a spread in the [F/C+N] ratio in CEMP-s stars as predicted by theory. Predictions from nucleosynthetic models for low-mass, low-metallicity asymptotic giant branch (AGB) stars account for the derived F abundances, while the upper limits on F content derived for most of the stars are lower than the predicted values. The measured Na content is accounted for by AGB models in the 1.25-1.75 M sun range, confirming that the stars responsible for the peculiar abundance pattern observed in CEMP-s stars are low-mass, low-metallicity AGB stars in agreement with the most accepted astrophysical scenario. We conclude that the mechanism of F production in current state-of-the-art low-metallicity low-mass AGB models needs further scrutiny and that F measurements in a larger number of metal-poor stars are needed to better constrain the models. Based on observations made with ESO Telescopes at Paranal Observatories under program ID 080.D-0606A. This publication makes use of data products from the Two Micron All Sky Survey, which is a joint project of the University of Massachusetts and the Infrared Processing and Analysis Center, funded by the National Aeronautics and Space Administration and the National Science Foundation.

  10. CONSTRAINING THE SCATTER IN THE MASS-RICHNESS RELATION OF maxBCG CLUSTERS WITH WEAK LENSING AND X-RAY DATA

    International Nuclear Information System (INIS)

    Rozo, Eduardo; Rykoff, Eli S.; Evrard, August; McKay, Timothy; Hao Jiangang; Becker, Matthew; Wechsler, Risa H.; Koester, Benjamin P.; Hansen, Sarah; Frieman, Joshua; Sheldon, Erin; Johnston, David; Annis, James

    2009-01-01

    We measure the logarithmic scatter in mass at fixed richness for clusters in the maxBCG cluster catalog, an optically selected cluster sample drawn from Sloan Digital Sky Survey imaging data. Our measurement is achieved by demanding consistency between available weak-lensing and X-ray measurements of the maxBCG clusters, and the X-ray luminosity-mass relation inferred from the 400 days X-ray cluster survey, a flux-limited X-ray cluster survey. We find σ lnM|N 200 =0.45 -0.18 +0.20 (95% CL) at N 200 ∼ 40, where N 200 is the number of red sequence galaxies in a cluster. As a byproduct of our analysis, we also obtain a constraint on the correlation coefficient between ln L X and ln M at fixed richness, which is best expressed as a lower limit, r L,M|N ≥ 0.85(95% CL). This is the first observational constraint placed on a correlation coefficient involving two different cluster mass tracers. We use our results to produce a state-of-the-art estimate of the halo mass function at z = 0.23-the median redshift of the maxBCG cluster sample-and find that it is consistent with the WMAP5 cosmology. Both the mass function data and its covariance matrix are presented.

  11. Constraining the Scatter in the Mass-Richness Relation of maxBCG Clusters With Weak Lensing and X-ray Data

    Energy Technology Data Exchange (ETDEWEB)

    Rozo, Eduardo; /Ohio State U.; Rykoff, Eli S.; /UC, Santa Barbara; Evrard, August; /Michigan U.; Becker, Matthew R.; /Chicago U.; McKay, Timothy; /Michigan U.; Wechsler, Risa H.; /SLAC; Koester, Benjamin P.; /Chicago U. /KICP, Chicago; Hao, Jiangang; /Michigan U.; Hansen, Sarah; /Chicago U. /KICP, Chicago; Sheldon, Erin; /New York U.; Johnston, David; /Houston U.; Annis, James T.; /Fermilab; Frieman, Joshua A.; /Chicago U. /KICP, Chicago /Fermilab

    2009-08-03

    We measure the logarithmic scatter in mass at fixed richness for clusters in the maxBCG cluster catalog, an optically selected cluster sample drawn from SDSS imaging data. Our measurement is achieved by demanding consistency between available weak lensing and X-ray measurements of the maxBCG clusters, and the X-ray luminosity-mass relation inferred from the 400d X-ray cluster survey, a flux limited X-ray cluster survey. We find {sigma}{sub lnM|N{sub 200}} = 0.45{sub -0.18}{sup +0.20} (95%CL) at N{sub 200} {approx} 40, where N{sub 200} is the number of red sequence galaxies in a cluster. As a byproduct of our analysis, we also obtain a constraint on the correlation coefficient between lnL{sub X} and lnM at fixed richness, which is best expressed as a lower limit, r{sub L,M|N} {ge} 0.85 (95% CL). This is the first observational constraint placed on a correlation coefficient involving two different cluster mass tracers. We use our results to produce a state of the art estimate of the halo mass function at z = 0.23 - the median redshift of the maxBCG cluster sample - and find that it is consistent with the WMAP5 cosmology. Both the mass function data and its covariance matrix are presented.

  12. The Open Cluster Chemical Abundances and Mapping (OCCAM) Survey: Optical Extension for Neutron Capture Elements

    Science.gov (United States)

    Melendez, Matthew; O'Connell, Julia; Frinchaboy, Peter M.; Donor, John; Cunha, Katia M. L.; Shetrone, Matthew D.; Majewski, Steven R.; Zasowski, Gail; Pinsonneault, Marc H.; Roman-Lopes, Alexandre; Stassun, Keivan G.; APOGEE Team

    2017-01-01

    The Open Cluster Chemical Abundance & Mapping (OCCAM) survey is a systematic survey of Galactic open clusters using data primarily from the SDSS-III/APOGEE-1 survey. However, neutron capture elements are very limited in the IR region covered by APOGEE. In an effort to fully study detailed Galactic chemical evolution, we are conducting a high resolution (R~60,000) spectroscopic abundance analysis of neutron capture elements for OCCAM clusters in the optical regime to complement the APOGEE results. As part of this effort, we present Ba II, La II, Ce II and Eu II results for a few open clusters without previous abundance measurements using data obtained at McDonald Observatory with the 2.1m Otto Struve telescope and Sandiford Echelle Spectrograph.This work is supported by an NSF AAG grant AST-1311835.

  13. Lithium-rich very metal-poor stars discovered with LAMOST and Subaru

    Science.gov (United States)

    Aoki, Wako; Li, Haining; Matsuno, Tadafumi; Kumar, Yerra Bharat; Shi, Jianrong; Suda, Takuma; Zhao, Gang

    2018-04-01

    Lithium is a unique element that is produced in the Big Bang nucleosynthesis but is destroyed by nuclear reactions inside stars. As a result, almost constant lithium abundance is found in unevolved main-sequence metal-poor stars, although the value is systematically lower than that expected from the standard Big Bang nucleosynthesis models, whereas lithium abundances of red giants are more than one order of magnitudes lower than those of unevolved stars. There are, however, a small fraction of metal-poor stars that show extremely high lithium abundances, which is not explained by standard stellar evolution models. We have discovered 12 new very metal-poor stars that have enhancement of lithium by more than 10 times compared with typical metal-poor stars at similar evolutionary stages by the large-scale spectroscopic survey with LAMOST and the follow-up high-resolution spectroscopy with the Subaru Telescope. The sample shows a wide distribution of evolutionary stages from subgiants to red giants with the metallicity of -3.3 <[Fe/H]< -1.6. The chemical abundance ratios of other elements have been obtained by our spectroscopic study, and an estimate of the binary frequency by radial velocity monitoring is ongoing. The observational results provide new constraints on the scenarios to explain lithium-rich metal-poor stars, such as extra mixing during the evolution along the red giant branch, mass-transfer from a companion AGB star, and engulfment of planet-like objects. These explanations are very unlikely for at least some of lithium-rich objects in our sample, suggesting a new mechanism that enhances lithium during the low-mass star evolution.

  14. THE UNIQUE Na:O ABUNDANCE DISTRIBUTION IN NGC 6791: THE FIRST OPEN(?) CLUSTER WITH MULTIPLE POPULATIONS

    International Nuclear Information System (INIS)

    Geisler, D.; Villanova, S.; Cummings, J.; Carraro, G.; Pilachowski, C.; Johnson, C. I.; Bresolin, F.

    2012-01-01

    Almost all globular clusters investigated exhibit a spread in their light element abundances, the most studied being an Na:O anticorrelation. In contrast, open clusters show a homogeneous composition and are still regarded as Simple Stellar Populations. The most probable reason for this difference is that globulars had an initial mass high enough to retain primordial gas and ejecta from the first stellar generation and thus formed a second generation with a distinct composition, an initial mass exceeding that of open clusters. NGC 6791 is a massive open cluster and warrants a detailed search for chemical inhomogeneities. We collected high-resolution, high signal-to-noise spectra of 21 members covering a wide range of evolutionary status and measured their Na, O, and Fe content. We found [Fe/H] = +0.42 ± 0.01, in good agreement with previous values, and no evidence for a spread. However, the Na:O distribution is completely unprecedented. It becomes the first open cluster to show intrinsic abundance variations that cannot be explained by mixing, and thus the first discovered to host multiple populations. It is also the first star cluster to exhibit two subpopulations in the Na:O diagram with one being chemically homogeneous while the second has an intrinsic spread that follows the anticorrelation so far displayed only by globular clusters. NGC 6791 is unique in many aspects, displaying certain characteristics typical of open clusters, others more reminiscent of globulars, and yet others, in particular its Na:O behavior investigated here, that are totally unprecedented. It clearly had a complex and fascinating history.

  15. The Unique Na:O Abundance Distribution in NGC 6791: The First Open(?) Cluster with Multiple Populations

    Science.gov (United States)

    Geisler, D.; Villanova, S.; Carraro, G.; Pilachowski, C.; Cummings, J.; Johnson, C. I.; Bresolin, F.

    2012-09-01

    Almost all globular clusters investigated exhibit a spread in their light element abundances, the most studied being an Na:O anticorrelation. In contrast, open clusters show a homogeneous composition and are still regarded as Simple Stellar Populations. The most probable reason for this difference is that globulars had an initial mass high enough to retain primordial gas and ejecta from the first stellar generation and thus formed a second generation with a distinct composition, an initial mass exceeding that of open clusters. NGC 6791 is a massive open cluster and warrants a detailed search for chemical inhomogeneities. We collected high-resolution, high signal-to-noise spectra of 21 members covering a wide range of evolutionary status and measured their Na, O, and Fe content. We found [Fe/H] = +0.42 ± 0.01, in good agreement with previous values, and no evidence for a spread. However, the Na:O distribution is completely unprecedented. It becomes the first open cluster to show intrinsic abundance variations that cannot be explained by mixing, and thus the first discovered to host multiple populations. It is also the first star cluster to exhibit two subpopulations in the Na:O diagram with one being chemically homogeneous while the second has an intrinsic spread that follows the anticorrelation so far displayed only by globular clusters. NGC 6791 is unique in many aspects, displaying certain characteristics typical of open clusters, others more reminiscent of globulars, and yet others, in particular its Na:O behavior investigated here, that are totally unprecedented. It clearly had a complex and fascinating history.

  16. Van der Waals coefficients for alkali metal clusters and their size

    Indian Academy of Sciences (India)

    In this paper we employ the hydrodynamic formulation of time-dependent density functional theory to obtain the van der Waals coefficients 6 and 8 of alkali metal clusters of various sizes including very large clusters. Such calculations become computationally very demanding in the orbital-based Kohn-Sham formalism, ...

  17. THE MASS-METALLICITY RELATION OF GLOBULAR CLUSTERS IN THE CONTEXT OF NONLINEAR COLOR-METALLICTY RELATIONS

    International Nuclear Information System (INIS)

    Blakeslee, John P.; Cantiello, Michele; Peng, Eric W.

    2010-01-01

    Two recent empirical developments in the study of extragalactic globular cluster (GC) populations are the color-magnitude relation of the blue GCs (the 'blue tilt') and the nonlinearity of the dependence of optical GC colors on metallicity. The color-magnitude relation, interpreted as a mass-metallicity relation, is thought to be a consequence of self-enrichment. Nonlinear color-metallicity relations have been shown to produce bimodal color distributions from unimodal metallicity distributions. We simulate GC populations including both a mass-metallicity scaling relation and nonlinear color-metallicity relations motivated by theory and observations. Depending on the assumed range of metallicities and the width of the GC luminosity function (GCLF), we find that the simulated populations can have bimodal color distributions with a 'blue tilt' similar to observations, even though the metallicity distribution appears unimodal. The models that produce these features have the relatively high mean GC metallicities and nearly equal blue and red peaks characteristic of giant elliptical galaxies. The blue tilt is less apparent in the models with metallicities typical of dwarf ellipticals; the narrower GCLF in these galaxies has an even bigger effect in reducing the significance of their color-magnitude slopes. We critically examine the evidence for nonlinearity versus bimodal metallicities as explanations for the characteristic double-peaked color histograms of giant ellipticals and conclude that the question remains open. We discuss the prospects for further theoretical and observational progress in constraining the models presented here and for uncovering the true metallicity distributions of extragalactic GC systems.

  18. Performance Modeling of Hybrid MPI/OpenMP Scientific Applications on Large-scale Multicore Cluster Systems

    KAUST Repository

    Wu, Xingfu; Taylor, Valerie

    2011-01-01

    In this paper, we present a performance modeling framework based on memory bandwidth contention time and a parameterized communication model to predict the performance of OpenMP, MPI and hybrid applications with weak scaling on three large-scale multicore clusters: IBM POWER4, POWER5+ and Blue Gene/P, and analyze the performance of these MPI, OpenMP and hybrid applications. We use STREAM memory benchmarks to provide initial performance analysis and model validation of MPI and OpenMP applications on these multicore clusters because the measured sustained memory bandwidth can provide insight into the memory bandwidth that a system should sustain on scientific applications with the same amount of workload per core. In addition to using these benchmarks, we also use a weak-scaling hybrid MPI/OpenMP large-scale scientific application: Gyro kinetic Toroidal Code in magnetic fusion to validate our performance model of the hybrid application on these multicore clusters. The validation results for our performance modeling method show less than 7.77% error rate in predicting the performance of hybrid MPI/OpenMP GTC on up to 512 cores on these multicore clusters. © 2011 IEEE.

  19. Performance Modeling of Hybrid MPI/OpenMP Scientific Applications on Large-scale Multicore Cluster Systems

    KAUST Repository

    Wu, Xingfu

    2011-08-01

    In this paper, we present a performance modeling framework based on memory bandwidth contention time and a parameterized communication model to predict the performance of OpenMP, MPI and hybrid applications with weak scaling on three large-scale multicore clusters: IBM POWER4, POWER5+ and Blue Gene/P, and analyze the performance of these MPI, OpenMP and hybrid applications. We use STREAM memory benchmarks to provide initial performance analysis and model validation of MPI and OpenMP applications on these multicore clusters because the measured sustained memory bandwidth can provide insight into the memory bandwidth that a system should sustain on scientific applications with the same amount of workload per core. In addition to using these benchmarks, we also use a weak-scaling hybrid MPI/OpenMP large-scale scientific application: Gyro kinetic Toroidal Code in magnetic fusion to validate our performance model of the hybrid application on these multicore clusters. The validation results for our performance modeling method show less than 7.77% error rate in predicting the performance of hybrid MPI/OpenMP GTC on up to 512 cores on these multicore clusters. © 2011 IEEE.

  20. WIYN Open Cluster Study: Binary Orbits and Tidal Circularization in NGC 6819

    Science.gov (United States)

    Morscher, Meagan B.; Mathieu, R. D.; Kaeppler, S.; Hole, K. T.; Meibom, S.

    2006-12-01

    We are conducting a comprehensive stellar radial-velocity survey in NGC 6819, a rich, intermediate age ( 2.4 Gyr) open cluster with [Fe/H] -0.05. As of October 2006, we have obtained 7065 radial-velocity measurements of 1409 stars using the WIYN Hydra Multi-Object Spectrograph, with typical velocity measurement precisions of 0.4 km/s. Using an E/I criterion of 3, we have identified 282 velocity variables. In the past year we have expanded the number of final orbital solutions by 45 to a total of more than 80 solutions. In coeval stellar populations, circular binaries tend to have the shortest orbital periods, while longer period binaries show a distribution of non-zero eccentricities. The circularization of the shortest period orbits is the result of an exchange of stellar and orbital angular momentum due to tidal interactions. We defined a population’s tidal circularization period as the longest orbital period at which a binary of typical initial eccentricity has become circularized (e.g., has evolved to an eccentricity e = 0.01) over the lifetime of the cluster (Meibom & Mathieu, 2005, ApJ, 620, 970). We are studying the trend of increasing tidal circularization periods with population age. Preliminary results in NGC 6819 indicate a tidal circularization period of 7.5 days, which is consistent with this overall trend. We will recalculate the tidal circularization period in order to include the latest sample of orbital solutions. This comprehensive survey also allows us to investigate the relative spatial distributions of spectroscopic binaries and other constant-velocity cluster members of similar mass. We find the spectroscopic binaries to be more centrally concentrated at a statistically significant level, which we attribute to energy equipartition processes. MM was supported by REU NSF grant AST-0453442. RDM, SK, KTH, and SM were supported by NSF grant AST-0406615.

  1. Rich Ground State Chemical Ordering in Nanoparticles: Exact Solution of a Model for Ag-Au Clusters

    DEFF Research Database (Denmark)

    Larsen, Peter Mahler; Jacobsen, Karsten Wedel; Schiøtz, Jakob

    2018-01-01

    We show that nanoparticles can have very rich ground state chemical order. This is illustrated by determining the chemical ordering of Ag-Au 309-atom Mackay icosahedral nanoparticles. The energy of the nanoparticles is described using a cluster expansion model, and a Mixed Integer Programming (MIP......) approach is used to find the exact ground state configurations for all stoichiometries. The chemical ordering varies widely between the different stoichiometries, and display a rich zoo of structures with non-trivial ordering....

  2. Inner edges of compact debris disks around metal-rich white dwarfs

    OpenAIRE

    Rafikov, Roman R.; Garmilla, Jose A.

    2012-01-01

    A number of metal-rich white dwarfs (WDs) are known to host compact, dense particle disks, which are thought to be responsible for metal pollution of these stars. In many such systems the inner radii of disks inferred from their spectra are so close to the WD that particles directly exposed to starlight must be heated above 1500 K and are expected to be unstable against sublimation. To reconcile this expectation with observations we explore particle sublimation in H-poor debris disks around W...

  3. ON THE SERENDIPITOUS DISCOVERY OF A Li-RICH GIANT IN THE GLOBULAR CLUSTER NGC 362

    Energy Technology Data Exchange (ETDEWEB)

    D’Orazi, Valentina; Gratton, Raffaele G.; Lucatello, Sara; Momany, Yazan [INAF—Osservatorio Astronomico di Padova, Vicolo dell’Osservatorio 5, I-35122, Padova (Italy); Angelou, George C. [Max Planck Institut für Sonnensystemforschung, Justus-von-Liebig-Weg 3, D-37077 Göttingen (Germany); Bragaglia, Angela; Carretta, Eugenio; Sollima, Antonio [INAF—Osservatorio Astronomico di Bologna, via Ranzani 1, I-40127, Bologna (Italy); Lattanzio, John C., E-mail: valentina.dorazi@oapd.inaf.it [Monash Centre for Astrophysics (MoCA), Monash University, Melbourne, VIC 3800 (Australia)

    2015-03-10

    We have serendipitously identified the first lithium-rich giant star located close to the red giant branch bump in a globular cluster. Through intermediate-resolution FLAMES spectra we derived a lithium abundance of A(Li) = 2.55 (assuming local thermodynamical equilibrium), which is extremely high considering the star’s evolutionary stage. Kinematic and photometric analysis confirm the object as a member of the globular cluster NGC 362. This is the fourth Li-rich giant discovered in a globular cluster, but is the only one known to exist at a luminosity close to the bump magnitude. The three previous detections are clearly more evolved, located close to, or beyond, the tip of their red giant branch. Our observations are able to discard the accretion of planets/brown dwarfs, as well as an enhanced mass-loss mechanism as a formation channel for this rare object. While the star sits just above the cluster bump luminosity, its temperature places it toward the blue side of the giant branch in the color–magnitude diagram. We require further dedicated observations to unambiguously identify the star as a red giant: we are currently unable to confirm whether Li production has occurred at the bump of the luminosity function or if the star is on the pre-zero-age horizontal branch. The latter scenario provides the opportunity for the star to have synthesized Li rapidly during the core helium flash or gradually during its red giant branch ascent via some extra mixing process.

  4. Mass spectrometric probes of metal cluster distributions and metastable ion decay

    International Nuclear Information System (INIS)

    Parks, E.K.; Liu, K.; Cole, S.K.; Riley, S.J.

    1988-01-01

    The study of metal clusters has provided both an opportunity and a challenge to the application of mass spectrometry. These days the most often-used technique for cluster generation - laser vaporization - leads to extensive distributions of cluster sizes, from one to perhaps thousands of atoms, and most studies reported to date use excimer laser ionization and time-of-flight mass spectrometry for cluster detection. Our apparatus is a simple one-stage TOF design employing Wiley-McLauren spatial focusing and a one-meter drift tube. In a second apparatus employing a pulsed valve in the cluster source, we see asymmetric broadening of niobium cluster mass peaks under multiphoton ionization conditions, indicating metastable decay of parent cluster ions. Other studies of niobium clusters have shown no such asymmetric peaks. 2 figs

  5. Relaxation processes in optically excites metal clusters; Relaxationsprozesse in optisch angeregten Metallclustern

    Energy Technology Data Exchange (ETDEWEB)

    Stanzel, J.

    2007-08-10

    The present work is concerned with the dynamics of optically excited metal clusters in the gas phase. Small mass-selected gold and tungsten cluster anions (Au{sup -}{sub n}, n=5-8, 14, 20 and W{sup -}{sub n}, n=3-14) are studied using femtosecond time-resolved photoelectron spectroscopy. Depending on the electronic structure in the valence region as well as on the optical excitation energy fundamentally different relaxation processes are observed. In small gold cluster anions excited with 1.56 eV an isolated electronically excited state is populated. The time-dependent measurements are strongly sizedependent and open insights into photoinduced geometry changes of the nuclear framework. Oscillatory vibrational wavepacket motion in Au{sup -}{sub 5}, an extremely longlived ({tau} >90 ns) electronically excited state in Au{sup -}{sub 6} as well as photoinduced melting in Au{sup -}{sub 7} and Au{sup -}{sub 8} is monitored in real time. By increasing the OPTICAL excitation energy to 3.12 eV a completely different scenario is observed. A multitude of electronically excited states can be reached upon optical excitation and as a consequence electronic relaxation processes that take place on a time scale of 1 ps are dominating. This is shown for Au{sup -}{sub 7}, Au{sup -}{sub 14} and Au{sup -}{sub 20}. Compared to gold clusters, tungsten clusters are characterized by a significantly higher electronic density of states in the valence region. Therefore electronic relaxation processes are much more likely and take place on a significantly faster time scale. The fast electronic relaxation processes are distinguished from pure vibrational relaxation. It is shown that already in the four atomic tungsten cluster W{sup -}{sub 4} electronic relaxation processes take place on a time scale of 30 fs. In all investigated tungsten cluster anions (W{sup -}{sub n}, n=3-14) an equilibrium between electronic and vibrational system is reached within around 1 ps after optical excitation which

  6. EVOLUTION OF WHITE DWARF STARS WITH HIGH-METALLICITY PROGENITORS: THE ROLE OF 22Ne DIFFUSION

    International Nuclear Information System (INIS)

    Althaus, L. G.; Corsico, A. H.; GarcIa-Berro, E.; Renedo, I.; Isern, J.; Rohrmann, R. D.

    2010-01-01

    Motivated by the strong discrepancy between the main-sequence turnoff age and the white dwarf cooling age in the metal-rich open cluster NGC 6791, we compute a grid of white dwarf evolutionary sequences that incorporates for the first time the energy released by the processes of 22 Ne sedimentation and of carbon/oxygen phase separation upon crystallization. The grid covers the mass range from 0.52 to 1.0 M sun , and is appropriate for the study of white dwarfs in metal-rich clusters. The evolutionary calculations are based on a detailed and self-consistent treatment of the energy released from these two processes, as well as on the employment of realistic carbon/oxygen profiles, of relevance for an accurate evaluation of the energy released by carbon/oxygen phase separation. We find that 22 Ne sedimentation strongly delays the cooling rate of white dwarfs stemming from progenitors with high metallicities at moderate luminosities, while carbon/oxygen phase separation adds considerable delays at low luminosities. Cooling times are sensitive to possible uncertainties in the actual value of the diffusion coefficient of 22 Ne. Changing the diffusion coefficient by a factor of 2 leads to maximum age differences of ∼8%-20% depending on the stellar mass. We find that the magnitude of the delays resulting from chemical changes in the core is consistent with the slowdown in the white dwarf cooling rate that is required to solve the age discrepancy in NGC 6791.

  7. Even-Odd Differences and Shape Deformation of Metal Clusters

    OpenAIRE

    Hidetoshi, Nishioka; Yoshio, Takahashi; Department of Physics, Konan University; Faculty of General Education, Yamagata University

    1994-01-01

    The relation between even-odd difference of metal cluster and the deformation of equilibrium shape is studied in terms of two different models; (i) tri-axially deformed harmonic oscillator model, (ii) rectangular box model. Having assumed the matter density ρ kept constant for different shapes of a cluster, we can determine the equilibrium shape both for the two models. The enhancement of HOMO-LUMO gap is obtained and it is ascribed to Jahn-Teller effect. Good agreement of the calculated resu...

  8. Oxygen abundances in halo giants. I - Giants in the very metal-poor globular clusters M92 and M15 and the metal-poor halo field

    Science.gov (United States)

    Sneden, Christopher; Kraft, Robert P.; Prosser, Charles F.; Langer, G. E.

    1991-12-01

    Oxygen, iron, vanadium, and scandium abundances are derived for very metal-poor giants in the globular clusters M92 and M15, and giants of comparable metallicity in the local halo field. The forbidden O I line dublet (6300, 6363) and nearby metallic lines in spectra are analyzed using line analysis and spectral synthesis codes. The Fe/H abundance for M92 is estimated at -2.25 +/-0.02 based on nine giants with a range of 500 K in effective temperature. No evidence for star-to-star variations in the Fe/H abundance was found. O-rich and O-poor stars appear intermixed in the H-R diagram. O - N nuclear synthesis and mixing to the surface are proposed as the best explanation for the low-oxygen giants. The nitrogen abundances obtained earlier for nine of the ten halo field giants in this sample are incompatible with the very large nitrogen abundances expected of the O/Fe abundance of about + 1.2 in halo field subdwarfs, as found by Abia and Rebolo (1989), and not more than 0.6 in halo giants, as found in this and other studies.

  9. The Open Cluster Chemical Abundances and Mapping (OCCAM) Survey: Detailed Age and Abundance Gradients using DR12

    Science.gov (United States)

    Frinchaboy, Peter M.; Thompson, Benjamin A.; O'Connell, Julia; Meyer, Brianne; Donor, John; Majewski, Steven R.; Holtzman, Jon A.; Zasowski, Gail; Beers, Timothy C.; Beaton, Rachael; Cunha, Katia M. L.; Hearty, Fred; Nidever, David L.; Schiavon, Ricardo P.; Smith, Verne V.; Hayden, Michael R.

    2015-01-01

    We present detailed abundance results for Galactic open clusters as part of the Open Cluster Chemical Abundances and Mapping (OCCAM) Survey, which is based primarily on data from the Sloan Digital Sky Survey/ Apache Point Observatory Galactic Evolution Experiment. Using 100 open clusters from the uniformly observed complete SDSS-III/APOGEE-1 DR12 dataset, we present age and multi-element abundance gradients for the disk of the Milky Way.This work is supported by an NSF AAG grant AST-1311835.

  10. A method for determining the radius of an open cluster from stellar proper motions

    Science.gov (United States)

    Sánchez, Néstor; Alfaro, Emilio J.; López-Martínez, Fátima

    2018-04-01

    We propose a method for calculating the radius of an open cluster in an objective way from an astrometric catalogue containing, at least, positions and proper motions. It uses the minimum spanning tree in the proper motion space to discriminate cluster stars from field stars and it quantifies the strength of the cluster-field separation by means of a statistical parameter defined for the first time in this paper. This is done for a range of different sampling radii from where the cluster radius is obtained as the size at which the best cluster-field separation is achieved. The novelty of this strategy is that the cluster radius is obtained independently of how its stars are spatially distributed. We test the reliability and robustness of the method with both simulated and real data from a well-studied open cluster (NGC 188), and apply it to UCAC4 data for five other open clusters with different catalogued radius values. NGC 188, NGC 1647, NGC 6603, and Ruprecht 155 yielded unambiguous radius values of 15.2 ± 1.8, 29.4 ± 3.4, 4.2 ± 1.7, and 7.0 ± 0.3 arcmin, respectively. ASCC 19 and Collinder 471 showed more than one possible solution, but it is not possible to know whether this is due to the involved uncertainties or due to the presence of complex patterns in their proper motion distributions, something that could be inherent to the physical object or due to the way in which the catalogue was sampled.

  11. Construction and application of Red5 cluster based on OpenStack

    Science.gov (United States)

    Wang, Jiaqing; Song, Jianxin

    2017-08-01

    With the application and development of cloud computing technology in various fields, the resource utilization rate of the data center has been improved obviously, and the system based on cloud computing platform has also improved the expansibility and stability. In the traditional way, Red5 cluster resource utilization is low and the system stability is poor. This paper uses cloud computing to efficiently calculate the resource allocation ability, and builds a Red5 server cluster based on OpenStack. Multimedia applications can be published to the Red5 cloud server cluster. The system achieves the flexible construction of computing resources, but also greatly improves the stability of the cluster and service efficiency.

  12. Constraints on the Mass–Richness Relation from the Abundance and Weak Lensing of SDSS Clusters

    Science.gov (United States)

    Murata, Ryoma; Nishimichi, Takahiro; Takada, Masahiro; Miyatake, Hironao; Shirasaki, Masato; More, Surhud; Takahashi, Ryuichi; Osato, Ken

    2018-02-01

    We constrain the scaling relation between optical richness (λ) and halo mass (M) for a sample of Sloan Digital Sky Survey (SDSS) red-sequence Matched-filter Probabilistic Percolation (redMaPPer) galaxy clusters within the context of the Planck cosmological model. We use a forward modeling approach where we model the probability distribution of optical richness for a given mass, P({ln}λ | M). To model the abundance and the stacked lensing profiles, we use an emulator specifically built to interpolate the halo mass function and the stacked lensing profile for an arbitrary set of halo mass and redshift, which is calibrated based on a suite of high-resolution N-body simulations. We apply our method to 8312 SDSS redMaPPer clusters with 20 ≤ λ ≤ 100 and 0.10 ≤ z λ ≤ 0.33 and show that the lognormal distribution model for P(λ | M), with four free parameters, well reproduces the measured abundances and lensing profiles simultaneously. The constraints are characterized by the mean relation, (M)=A+B{ln}(M/{M}pivot}), with A={3.207}-0.046+0.044 and B={0.993}-0.055+0.041 (68% CL), where the pivot mass scale M pivot = 3 × 1014 h ‑1 M ⊙, and the scatter {σ }lnλ | M}={σ }0+q{ln}(M/{M}pivot}) with {σ }0={0.456}-0.039+0.047 and q=-{0.169}-0.026+0.035. We find that a large scatter in halo masses is required at the lowest-richness bins (20 ≤ λ ≲ 30) in order to reproduce the measurements. Without such a large scatter, the model prediction for the lensing profiles tends to overestimate the measured amplitudes. This might imply a possible contamination of intrinsically low-richness clusters due to the projection effects. Such a low-mass halo contribution is significantly reduced when applying our method to the sample of 30 ≤ λ ≤ 100.

  13. THE HST/ACS COMA CLUSTER SURVEY. IV. INTERGALACTIC GLOBULAR CLUSTERS AND THE MASSIVE GLOBULAR CLUSTER SYSTEM AT THE CORE OF THE COMA GALAXY CLUSTER

    International Nuclear Information System (INIS)

    Peng, Eric W.; Ferguson, Henry C.; Goudfrooij, Paul; Hammer, Derek; Lucey, John R.; Marzke, Ronald O.; Puzia, Thomas H.; Carter, David; Balcells, Marc; Bridges, Terry; Chiboucas, Kristin; Del Burgo, Carlos; Graham, Alister W.; Guzman, Rafael; Hudson, Michael J.; Matkovic, Ana

    2011-01-01

    Intracluster stellar populations are a natural result of tidal interactions in galaxy clusters. Measuring these populations is difficult, but important for understanding the assembly of the most massive galaxies. The Coma cluster of galaxies is one of the nearest truly massive galaxy clusters and is host to a correspondingly large system of globular clusters (GCs). We use imaging from the HST/ACS Coma Cluster Survey to present the first definitive detection of a large population of intracluster GCs (IGCs) that fills the Coma cluster core and is not associated with individual galaxies. The GC surface density profile around the central massive elliptical galaxy, NGC 4874, is dominated at large radii by a population of IGCs that extend to the limit of our data (R +4000 -5000 (systematic) IGCs out to this radius, and that they make up ∼70% of the central GC system, making this the largest GC system in the nearby universe. Even including the GC systems of other cluster galaxies, the IGCs still make up ∼30%-45% of the GCs in the cluster core. Observational limits from previous studies of the intracluster light (ICL) suggest that the IGC population has a high specific frequency. If the IGC population has a specific frequency similar to high-S N dwarf galaxies, then the ICL has a mean surface brightness of μ V ∼ 27 mag arcsec -2 and a total stellar mass of roughly 10 12 M sun within the cluster core. The ICL makes up approximately half of the stellar luminosity and one-third of the stellar mass of the central (NGC 4874+ICL) system. The color distribution of the IGC population is bimodal, with blue, metal-poor GCs outnumbering red, metal-rich GCs by a ratio of 4:1. The inner GCs associated with NGC 4874 also have a bimodal distribution in color, but with a redder metal-poor population. The fraction of red IGCs (20%), and the red color of those GCs, implies that IGCs can originate from the halos of relatively massive, L* galaxies, and not solely from the disruption of

  14. INNER EDGES OF COMPACT DEBRIS DISKS AROUND METAL-RICH WHITE DWARFS

    Energy Technology Data Exchange (ETDEWEB)

    Rafikov, Roman R.; Garmilla, Jose A., E-mail: rrr@astro.princeton.edu, E-mail: garmilla@astro.princeton.edu [Department of Astrophysical Sciences, Princeton University, Ivy Lane, Princeton, NJ 08540 (United States)

    2012-12-01

    A number of metal-rich white dwarfs (WDs) are known to host compact, dense particle disks, which are thought to be responsible for metal pollution of these stars. In many such systems, the inner radii of disks inferred from their spectra are so close to the WD that particles directly exposed to starlight must be heated above 1500 K and are expected to be unstable against sublimation. To reconcile this expectation with observations, we explore particle sublimation in H-poor debris disks around WDs. We show that because of the high metal vapor pressure the characteristic sublimation temperature in these disks is 300-400 K higher than in their protoplanetary analogs, allowing particles to survive at higher temperatures. We then look at the structure of the inner edges of debris disks and show that they should generically feature superheated inner rims directly exposed to starlight with temperatures reaching 2500-3500 K. Particles migrating through the rim toward the WD (and rapidly sublimating) shield the disk behind them from strong stellar heating, making the survival of solids possible close to the WD. Our model agrees well with observations of WD+disk systems provided that disk particles are composed of Si-rich material such as olivine, and have sizes in the range {approx}0.03-30 cm.

  15. INNER EDGES OF COMPACT DEBRIS DISKS AROUND METAL-RICH WHITE DWARFS

    International Nuclear Information System (INIS)

    Rafikov, Roman R.; Garmilla, José A.

    2012-01-01

    A number of metal-rich white dwarfs (WDs) are known to host compact, dense particle disks, which are thought to be responsible for metal pollution of these stars. In many such systems, the inner radii of disks inferred from their spectra are so close to the WD that particles directly exposed to starlight must be heated above 1500 K and are expected to be unstable against sublimation. To reconcile this expectation with observations, we explore particle sublimation in H-poor debris disks around WDs. We show that because of the high metal vapor pressure the characteristic sublimation temperature in these disks is 300-400 K higher than in their protoplanetary analogs, allowing particles to survive at higher temperatures. We then look at the structure of the inner edges of debris disks and show that they should generically feature superheated inner rims directly exposed to starlight with temperatures reaching 2500-3500 K. Particles migrating through the rim toward the WD (and rapidly sublimating) shield the disk behind them from strong stellar heating, making the survival of solids possible close to the WD. Our model agrees well with observations of WD+disk systems provided that disk particles are composed of Si-rich material such as olivine, and have sizes in the range ∼0.03-30 cm.

  16. Inner Edges of Compact Debris Disks around Metal-rich White Dwarfs

    Science.gov (United States)

    Rafikov, Roman R.; Garmilla, José A.

    2012-12-01

    A number of metal-rich white dwarfs (WDs) are known to host compact, dense particle disks, which are thought to be responsible for metal pollution of these stars. In many such systems, the inner radii of disks inferred from their spectra are so close to the WD that particles directly exposed to starlight must be heated above 1500 K and are expected to be unstable against sublimation. To reconcile this expectation with observations, we explore particle sublimation in H-poor debris disks around WDs. We show that because of the high metal vapor pressure the characteristic sublimation temperature in these disks is 300-400 K higher than in their protoplanetary analogs, allowing particles to survive at higher temperatures. We then look at the structure of the inner edges of debris disks and show that they should generically feature superheated inner rims directly exposed to starlight with temperatures reaching 2500-3500 K. Particles migrating through the rim toward the WD (and rapidly sublimating) shield the disk behind them from strong stellar heating, making the survival of solids possible close to the WD. Our model agrees well with observations of WD+disk systems provided that disk particles are composed of Si-rich material such as olivine, and have sizes in the range ~0.03-30 cm.

  17. METAL-POOR LITHIUM-RICH GIANTS IN THE RADIAL VELOCITY EXPERIMENT SURVEY

    International Nuclear Information System (INIS)

    Ruchti, Gregory R.; Fulbright, Jon P.; Wyse, Rosemary F. G.; Gilmore, Gerard F.; Grebel, Eva K.; Bienaymé, Olivier; Siebert, Arnaud; Bland-Hawthorn, Joss; Freeman, Ken C.; Gibson, Brad K.; Munari, Ulisse; Navarro, Julio F.; Parker, Quentin A.; Watson, Fred G.; Reid, Warren; Seabroke, George M.; Siviero, Alessandro; Steinmetz, Matthias; Williams, Mary; Zwitter, Tomaz

    2011-01-01

    We report the discovery of eight lithium-rich field giants found in a high-resolution spectroscopic sample of over 700 metal-poor stars ([Fe/H] 7 Li), A(Li) = log (n(Li)/n(H)) + 12, between 2.30 and 3.63, well above the typical upper red giant branch (RGB) limit, A(Li) 7 Be (which burns to 7 Li) is transported to the stellar surface via the Cameron-Fowler mechanism. We discuss and discriminate among several models for the extra mixing that can cause Li production, given the detailed abundances of the Li-rich giants in our sample.

  18. The role of grazing in nutrient-rich areas of the open sea

    International Nuclear Information System (INIS)

    Frost, B.W.

    1991-01-01

    No single factor accounts fully for the persistently low phytoplankton stocks in the nutrient-rich areas of the open sea. However, grazing plays the necessary role of consuming phytoplankton produced in excess of losses due to physical processes and sinking. Without grazing, even if specific growth rate of the phytoplankton is less than optimal for the prevailing light and temperature conditions, as might be so under limitation by a trace nutrient such as Fe, the phytoplankton stock would still accumulate with attendant depletion of nutrients. Observations during spring and summer in the open subarctic Pacific argue against limitation of phytoplankton growth to the point where phytoplankton stock could not increase in the absence of grazing. An ecosystem process model of the phytoplankton-grazer interaction suggests that two processes - grazing control of phytoplankton stock and preferential utilization of NH 4 by the phytoplankton - are sufficient to explain the continuously low phytoplankton stock and high concentrations of macronutrients. However, the grazing control may be exerted on a phytoplankton assemblage structured by Fe limitation. In particular, the intrinsic growth rates of potentially fast-growing diatoms seem to be depressed in the open subarctic Pacific. These conditions probably apply to two other nutrient-rich areas of the open sea, the Pacific equatorial upwelling region and the subantarctic circumpolar ocean, although in the latter region light limitation of phytoplankton growth may be more severe and silica limitation may influence the specific composition of the phytoplankton assemblage

  19. Metallicity Spreads in M31 Globular Clusters

    Science.gov (United States)

    Bridges, Terry

    2003-07-01

    Our recent deep HST photometry of the M31 halo globular cluster {GC} Mayall II, also called G1, has revealed a red-giant branch with a clear spread that we attribute to an intrinsic metallicity dispersion of at least 0.4 dex in [Fe/H]. The only other GC exhibiting such a metallicity dispersion is Omega Centauri, the brightest and most massive Galactic GC, whose range in [Fe/H] is about 0.5 dex. These observations are obviously linked to the fact that both G1 and Omega Cen are bright and massive GC, with potential wells deep enough to keep part of their gas, which might have been recycled, producing a metallicity scatter among cluster stars. These observations dramatically challenge the notion of chemical homogeneity as a defining characteristic of GCs. It is critically important to find out how common this phenomenon is and how it can constrain scenarios/models of GC formation. The obvious targets are other bright and massive GCs, which exist in M31 but not in our Galaxy where Omega Cen is an isolated giant. We propose to acquire, with ACS/HRC, deep imaging of 3 of the brightest M31 GCs for which we have observed velocity dispersion values similar to those observed in G1 and Omega Cen. A sample of GCs with chemical abundance dispersions will provide essential information about their formation mechanism. This would represent a major step for the studies of the origin and evolution of stellar populations.

  20. MASS-TO-LIGHT RATIOS FOR M31 GLOBULAR CLUSTERS: AGE DATING AND A SURPRISING METALLICITY TREND

    International Nuclear Information System (INIS)

    Strader, Jay; Huchra, John P.; Smith, Graeme H.; Brodie, Jean P.; Larsen, Soeren

    2009-01-01

    We have obtained velocity dispersions from Keck high-resolution integrated spectroscopy of 10 M31 globular clusters (GCs), including three candidate intermediate-age GCs. We show that these candidates have the same V-band mass-to-light (M/L V ) ratios as the other GCs, implying that they are likely to be old. We also find a trend of derived velocity dispersion with wavelength, but cannot distinguish between a systematic error and a physical effect. Our new measurements are combined with photometric and spectroscopic data from the literature in a re-analysis of all M31 GC M/L V values. In a combined sample of 27 GCs, we show that the metal-rich GCs have lower M/L V than the metal-poor GCs, in conflict with predictions from stellar population models. Fragmentary data for other galaxies support this observation. The M31 GC fundamental plane is extremely tight, and we follow up an earlier suggestion by Djorgovski to show that the fundamental plane can be used to estimate accurate distances (potentially 10% or better).

  1. Coulomb frustration of the multiphoton ionization of metallic clusters under intense EUV FEL evidenced by ion spectrometry

    International Nuclear Information System (INIS)

    Mazza, T; Devetta, M; Milani, P; Motomura, K; Liu, X-J; Fukuzawa, H; Yamada, A; Nagaya, K; Iwayama, H; Sugishima, A; Mizoguchi, Y; Saito, N; Coreno, M; Nagasono, M; Tono, K; Togashi, T; Kimura, H; Okunishi, M; Fennel, Th; Senba, Y

    2015-01-01

    Free electron laser light sources delivering high intensity pulses of short wavelength radiation are opening novel possibilities for the investigation of matter at the nanoscale and for the discovery and understanding of new physical processes occurring at the exotic transient states they make accessible. Strong ionization of atomic constituents of a nano-sized sample is a representative example of such processes and the understanding of ionization dynamics is crucial for a realistic description of the experiments. We report here on multiple ionization experiments on free clusters of titanium, a high cohesive energy metal. The time of flight ion spectra reveal a saturation of the cluster ionization at ∼10 16 photons per pulse per cm 2 . Our results also show a clear lack of any explosion process, opposite to what is observed for a rare-gas cluster under similar conditions. A simple and generalized multi-step ionization model including Coulomb frustration of the photoemission process effectively reproduces with a good agreement the main features of the experimental observation and points to an interpretation of the data involving a substantial energy deposition into the cluster through electronic system heating upon scattering events within photoemission. (paper)

  2. A TALE OF A RICH CLUSTER AT z ∼ 0.8 AS SEEN BY THE STAR FORMATION HISTORIES OF ITS EARLY-TYPE GALAXIES

    Energy Technology Data Exchange (ETDEWEB)

    Ferré-Mateu, Anna [Subaru Telescope, Hilo, HI 96720 (United States); Sánchez-Blázquez, Patricia [Departamento de Física Teórica, Universidad Autónoma de Madrid, E-28049 Cantoblanco, Madrid (Spain); Vazdekis, Alexandre; De la Rosa, Ignacio G., E-mail: aferre@naoj.org [Instituto de Astrofísica de Canarias, E-38205 La Laguna, Tenerife (Spain)

    2014-12-20

    We present a detailed stellar population analysis for a sample of 24 early-type galaxies (ETGs) belonging to the rich cluster RX J0152.7-1357 at z = 0.83. We have derived the age, metallicity, abundance pattern, and star formation history (SFH) for each galaxy individually to further characterize this intermediate-z reference cluster. We then study how these stellar population parameters depend on the local environment. This provides a better understanding on the formation timescales and subsequent evolution of the substructures in this cluster. We have also explored the evolutionary link between z ∼ 0.8 ETGs and those in the local universe by comparing the trends that the stellar population parameters followed with galaxy velocity dispersion at each epoch. We find that the ETGs in Coma are consistent with being the (passively evolving) descendants of the ETG population in RX J10152.7-1357. Furthermore, our results favor a downsizing picture, where the subclumps centers were formed first. These central parts contain the most massive galaxies, which formed the bulk of their stars in a short, burst-like event at high z. On the contrary, the cluster outskirts are populated with less-massive, smaller galaxies that show a wider variety of SFHs. In general, they present extended star formation episodes over cosmic time, which seems to be related to their posterior incorporation into the cluster around 4 Gyr after the initial event of formation.

  3. Metal-rich, Metal-poor: Updated Stellar Population Models for Old Stellar Systems

    Science.gov (United States)

    Conroy, Charlie; Villaume, Alexa; van Dokkum, Pieter G.; Lind, Karin

    2018-02-01

    We present updated stellar population models appropriate for old ages (>1 Gyr) and covering a wide range in metallicities (‑1.5 ≲ [Fe/H] ≲ 0.3). These models predict the full spectral variation associated with individual element abundance variation as a function of metallicity and age. The models span the optical–NIR wavelength range (0.37–2.4 μm), include a range of initial mass functions, and contain the flexibility to vary 18 individual elements including C, N, O, Mg, Si, Ca, Ti, and Fe. To test the fidelity of the models, we fit them to integrated light optical spectra of 41 Galactic globular clusters (GCs). The value of testing models against GCs is that their ages, metallicities, and detailed abundance patterns have been derived from the Hertzsprung–Russell diagram in combination with high-resolution spectroscopy of individual stars. We determine stellar population parameters from fits to all wavelengths simultaneously (“full spectrum fitting”), and demonstrate explicitly with mock tests that this approach produces smaller uncertainties at fixed signal-to-noise ratio than fitting a standard set of 14 line indices. Comparison of our integrated-light results to literature values reveals good agreement in metallicity, [Fe/H]. When restricting to GCs without prominent blue horizontal branch populations, we also find good agreement with literature values for ages, [Mg/Fe], [Si/Fe], and [Ti/Fe].

  4. Large-Grain Tin-Rich Perovskite Films for Efficient Solar Cells via Metal Alloying Technique.

    Science.gov (United States)

    Tavakoli, Mohammad Mahdi; Zakeeruddin, Shaik Mohammed; Grätzel, Michael; Fan, Zhiyong

    2018-03-01

    Fast research progress on lead halide perovskite solar cells has been achieved in the past a few years. However, the presence of lead (Pb) in perovskite composition as a toxic element still remains a major issue for large-scale deployment. In this work, a novel and facile technique is presented to fabricate tin (Sn)-rich perovskite film using metal precursors and an alloying technique. Herein, the perovskite films are formed as a result of the reaction between Sn/Pb binary alloy metal precursors and methylammonium iodide (MAI) vapor in a chemical vapor deposition process carried out at 185 °C. It is found that in this approach the Pb/Sn precursors are first converted to (Pb/Sn)I 2 and further reaction with MAI vapor leads to the formation of perovskite films. By using Pb-Sn eutectic alloy, perovskite films with large grain sizes up to 5 µm can be grown directly from liquid phase metal. Consequently, using an alloying technique and this unique growth mechanism, a less-toxic and efficient perovskite solar cell with a power conversion efficiency (PCE) of 14.04% is demonstrated, while pure Sn and Pb perovskite solar cells prepared in this manner yield PCEs of 4.62% and 14.21%, respectively. It is found that this alloying technique can open up a new direction to further explore different alloy systems (binary or ternary alloys) with even lower melting point. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  5. Chemisorption on size-selected metal clusters: activation barriers and chemical reactions for deuterium and aluminum cluster ions

    International Nuclear Information System (INIS)

    Jarrold, M.F.; Bower, J.E.

    1988-01-01

    The authors describe a new approach to investigating chemisorption on size-selected metal clusters. This approach involves investigating the collision-energy dependence of chemisorption using low-energy ion beam techniques. The method provides a direct measure of the activation barrier for chemisorption and in some cases an estimate of the desorption energy as well. They describe the application of this technique to chemisorption of deuterium on size-selected aluminum clusters. The activation barriers increase with cluster size (from a little over 1 eV for Al 10 + to around 2 eV for Al 27 + ) and show significant odd-even oscillations. The activation barriers for the clusters with an odd number of atoms are larger than those for the even-numbered clusters. In addition to chemisorption of deuterium onto the clusters, chemical reactions were observed, often resulting in cluster fragmentation. The main products observed were Al/sub n-1/D + , Al/sub n-2/ + , and Al + for clusters with n + and Al/sub n-1/D + for the larger clusters

  6. Electrospray Ionization Mass Spectrometry: From Cluster Ions to Toxic metal Ions in Biology

    Energy Technology Data Exchange (ETDEWEB)

    Lentz, Nicholas B. [Iowa State Univ., Ames, IA (United States)

    2007-01-01

    This dissertation focused on using electrospray ionization mass spectrometry to study cluster ions and toxic metal ions in biology. In Chapter 2, it was shown that primary, secondary and quarternary amines exhibit different clustering characteristics under identical instrument conditions. Carbon chain length also played a role in cluster ion formation. In Chapters 3 and 4, the effects of solvent types/ratios and various instrumental parameters on cluster ion formation were examined. It was found that instrument interface design also plays a critical role in the cluster ion distribution seen in the mass spectrum. In Chapter 5, ESI-MS was used to investigate toxic metal binding to the [Gln11]-amyloid β-protein fragment (1-16). Pb and Cd bound stronger than Zn, even in the presence of excess Zn. Hg bound weaker than Zn. There are endless options for future work on cluster ions. Any molecule that is poorly ionized in positive ion mode can potentially show an increase in ionization efficiency if an appropriate anion is used to produce a net negative charge. It is possible that drug protein or drug/DNA complexes can also be stabilized by adding counter-ions. This would preserve the solution characteristics of the complex in the gas phase. Once in the gas phase, CID could determine the drug binding location on the biomolecule. There are many research projects regarding toxic metals in biology that have yet to be investigated or even discovered. This is an area of research with an almost endless future because of the changing dynamics of biological systems. What is deemed safe today may show toxic effects in the future. Evolutionary changes in protein structures may render them more susceptible to toxic metal binding. As the understanding of toxicity evolves, so does the demand for new toxic metal research. New instrumentation designs and software make it possible to perform research that could not be done in the past. What was undetectable yesterday will

  7. Parameters of oscillation generation regions in open star cluster models

    Science.gov (United States)

    Danilov, V. M.; Putkov, S. I.

    2017-07-01

    We determine the masses and radii of central regions of open star cluster (OCL) models with small or zero entropy production and estimate the masses of oscillation generation regions in clustermodels based on the data of the phase-space coordinates of stars. The radii of such regions are close to the core radii of the OCL models. We develop a new method for estimating the total OCL masses based on the cluster core mass, the cluster and cluster core radii, and radial distribution of stars. This method yields estimates of dynamical masses of Pleiades, Praesepe, and M67, which agree well with the estimates of the total masses of the corresponding clusters based on proper motions and spectroscopic data for cluster stars.We construct the spectra and dispersion curves of the oscillations of the field of azimuthal velocities v φ in OCL models. Weak, low-amplitude unstable oscillations of v φ develop in cluster models near the cluster core boundary, and weak damped oscillations of v φ often develop at frequencies close to the frequencies of more powerful oscillations, which may reduce the non-stationarity degree in OCL models. We determine the number and parameters of such oscillations near the cores boundaries of cluster models. Such oscillations points to the possible role that gradient instability near the core of cluster models plays in the decrease of the mass of the oscillation generation regions and production of entropy in the cores of OCL models with massive extended cores.

  8. The Problem of Hipparcos Distances to Open Clusters. II. Constraints from Nearby Field Theory. Report 2; ClustersConstraints from nearly Field Stars

    Science.gov (United States)

    Soderblom, David R.; King, Jeremy R.; Hanson, Robert B.; Jones, Burton F.; Fischer, Debra; Stauffer, John R.; Pinsonneault, Marc H.

    1998-01-01

    This paper examines the discrepancy between distances to nearby open clusters as determined by parallaxes from Hipparcos compared to traditional main-sequence fitting. The biggest difference is seen for the Pleiades, and our hypothesis is that if the Hipparcos distance to the Pleiades is correct, then similar subluminous zero-age main-sequence (ZAMS) stars should exist elsewhere, including in the immediate solar neighborhood. We examine a color-magnitude diagram of very young and nearby solar-type stars and show that none of them lie below the traditional ZAMS, despite the fact that the Hipparcos Pleiades parallax would place its members 0.3 mag below that ZAMS. We also present analyses and observations of solar-type stars that do lie below the ZAMS, and we show that they are subluminous because of low metallicity and that they have the kinematics of old stars.

  9. uvby and Hβ photometry of the open cluster IC 4996

    International Nuclear Information System (INIS)

    Alfaro, E.J.; Delgado, A.J.; Garcia-Pelayo, J.M.; Garrido, R.; Saez, M.

    1985-01-01

    Photoelectric uvby and Hβ observations have been obtained for 15 stars in the field of the open cluster IC 4996. An average colour excess of E(b-y)=0.473 is estimated for six observed members of the cluster, in good agreement with previous results. A comparison between the β-Msub(v) calibrations given by Crawford and by Eggen suggests that the first one takes better into account the evolutionary effects on the Hβ index. We have calculated a true distance modulus of 11.43 and an age of 7.5x10 6 years

  10. Pulse laser-induced generation of cluster codes from metal nanoparticles for immunoassay applications

    Directory of Open Access Journals (Sweden)

    Chia-Yin Chang

    2017-05-01

    Full Text Available In this work, we have developed an assay for the detection of proteins by functionalized nanomaterials coupled with laser-induced desorption/ionization mass spectrometry (LDI-MS by monitoring the generation of metal cluster ions. We achieved selective detection of three proteins [thrombin, vascular endothelial growth factor-A165 (VEGF-A165, and platelet-derived growth factor-BB (PDGF-BB] by modifying nanoparticles (NPs of three different metals (Au, Ag, and Pt with the corresponding aptamer or antibody in one assay. The Au, Ag, and Pt acted as metal bio-codes for the analysis of thrombin, VEGF-A165, and PDGF-BB, respectively, and a microporous cellulose acetate membrane (CAM served as a medium for an in situ separation of target protein-bound and -unbound NPs. The functionalized metal nanoparticles bound to their specific proteins were subjected to LDI-MS on the CAM. The functional nanoparticles/CAM system can function as a signal transducer and amplifier by transforming the protein concentration into an intense metal cluster ion signal during LDI-MS analysis. This system can selectively detect proteins at picomolar concentrations. Most importantly, the system has great potential for the detection of multiple proteins without any pre-concentration, separation, or purification process because LDI-MS coupled with CAM effectively removes all signals except for those from the metal cluster ions.

  11. Magneto-structural properties and magnetic anisotropy of small transition-metal clusters: a first-principles study

    International Nuclear Information System (INIS)

    Blonski, Piotr; Hafner, Juergen

    2011-01-01

    Ab initio density-functional calculations including spin-orbit coupling (SOC) have been performed for Ni and Pd clusters with three to six atoms and for 13-atom clusters of Ni, Pd, and Pt, extending earlier calculations for Pt clusters with up to six atoms (2011 J. Chem. Phys. 134 034107). The geometric and magnetic structures have been optimized for different orientations of the magnetization with respect to the crystallographic axes of the cluster. The magnetic anisotropy energies (MAE) and the anisotropies of spin and orbital moments have been determined. Particular attention has been paid to the correlation between the geometric and magnetic structures. The magnetic point group symmetry of the clusters varies with the direction of the magnetization. Even for a 3d metal such as Ni, the change in the magnetic symmetry leads to small geometric distortions of the cluster structure, which are even more pronounced for the 4d metal Pd. For a 5d metal the SOC is strong enough to change the energetic ordering of the structural isomers. SOC leads to a mixing of the spin states corresponding to the low-energy spin isomers identified in the scalar-relativistic calculations. Spin moments are isotropic only for Ni clusters, but anisotropic for Pd and Pt clusters, orbital moments are anisotropic for the clusters of all three elements. The magnetic anisotropy energies have been calculated. The comparison between MAE and orbital anisotropy invalidates a perturbation analysis of magnetic anisotropy for these small clusters.

  12. Cluster plasma and its dispersion relation

    International Nuclear Information System (INIS)

    Tajima, T.; Downer, M.C.; Kishimoto, Y.

    1998-01-01

    It is shown that unlike a gas plasma or an electron plasma in a metal, an ionized cluster material (open-quotes cluster plasmaclose quotes) permits propagation below the plasma cut-off of electromagnetic (EM) waves whose phase velocity is close to but below the speed of light. Its unique properties allow a variety of applications, including direct acceleration of particles with its EM fields and the phase matching of waves of high harmonic generation (HHG)

  13. Electronic relaxation dynamics of a metal atom deposited on argon cluster

    International Nuclear Information System (INIS)

    Awali, Slim

    2014-01-01

    This thesis is a study on the interaction between electronically excited atomic states and a non-reactive environment. We have theoretically and experimentally studied situations where a metal atom (Ba or K) is placed in a finite size environment (argon cluster). The presence of the medium affects the electronic levels of the atom. On the other side, the excitation of the atom induces a relaxation dynamics of the electronic energy through the deformation of the cluster. The experimental part of this work focuses on two aspects: the spectroscopy and the dynamics. In both cases a first laser electronically excites the metal atom and the second ionizes the excited system. The observable is the photoelectron spectrum recorded after photoionization and possibly information on the photoion which are also produced. This pump/probe technique, with also two lasers, provide the ultrafast dynamic when the lasers pulses used are of ultrashort (60 fs). The use of nanosecond lasers leads to resonance spectroscopic measurement, unresolved temporally, which give information on the position of the energy levels of the studied system. From a theoretical point-of-view, the excited states of M-Ar n were calculated at the ab initio level, using large core pseudo-potential to limit the active electrons of the metal to valence electrons. The study of alkali metals (potassium) is especially well adapted to this method since only one electron is active. The ab-initio calculation and a Monte-Carlo simulation where coupled to optimize the geometry of the KAr n (n = 1-10) cluster when K is in the ground state of the neutral and the ion, or excited in the 4p or 5s state. Calculations were also conducted in collaboration with B. Gervais (CIMAP, Caen) on KAr n clusters having several tens of argon atoms. Absorption spectra were also calculated. From an experimental point-of-view, we were able to characterize the excited states of potassium and barium perturbed by the clusters. In both cases a

  14. An Extremely Lithium-rich Bright Red Giant in the Globular Cluster M3

    Science.gov (United States)

    Kraft, Robert P.; Peterson, Ruth C.; Guhathakurta, Puragra; Sneden, Christopher; Fulbright, Jon P.; Langer, G. Edward

    1999-06-01

    We have serendipitously discovered an extremely lithium-rich star on the red giant branch of the globular cluster M3 (NGC 5272). An echelle spectrum obtained with the Keck I High-Resolution Echelle Spectrograph reveals a Li I λ6707 resonance doublet of 520 mÅ equivalent width, and our analysis places the star among the most Li-rich giants known: logε(Li)~=+3.0. We determine the elemental abundances of this star, IV-101, and three other cluster members of similar luminosity and color and conclude that IV-101 has abundance ratios typical of giants in M3 and M13 that have undergone significant mixing. We discuss mechanisms by which a low-mass star may be so enriched in Li, focusing on the mixing of material processed by the hydrogen-burning shell just below the convective envelope. While such enrichment could conceivably happen only rarely, it may in fact regularly occur during giant-branch evolution but be rarely detected because of rapid subsequent Li depletion. Based on observations obtained with the Keck I Telescope of the W. M. Keck Observatory, which is operated by the California Association for Research in Astronomy (CARA), Inc., on behalf of the University of California and the California Institute of Technology. This Letter is dedicated to the memory of our beloved colleague Ed Langer, who died after a brief illness on February 16, 1999. Ed brought a unique theoretical perspective to our globular cluster abundance studies. His career truly embodied the academic ideals of inspiration in both teaching and research. He made friends wherever he traveled, and was an inspiration to students. We will miss him greatly.

  15. Study of a few cluster candidates in the Magellanic Bridge

    Science.gov (United States)

    Choudhury, Samyaday; Subramaniam Subramaniam, Annapurni; Sohn, Young-Jong

    2018-06-01

    The Magellanic Clouds (LMC & SMC) are gas rich, metal poor, dwarf satellite galaxies to our Milky Way that are interacting with each other. The Magellanic Bridge (MB), joining the larger and smaller Cloud is considered to be a signature of this interaction process. Studies have revealed that the MB, apart from gas also hosts stellar populations and star clusters. The number of clusters, with well-estimated parameters within the MB is still underway. In this work, we study a sample of 9 previously cataloged star clusters in the MB region. We use Washington C, Harris R and Cousins I bands data from literature, taken using the 4-m Blanco telescope to estimate the cluster properties (size, age, reddening). We also identify and separate out genuine cluster candidates from possible clusters/asterism. The increase in number of genuine cluster candidates with well-estimated parameters is important in the context of understanding cluster formation and evolution in such low-metallicity, and tidally disrupted environment. The clusters studied here can also help estimate distances to different parts of the MB, as recent studies indicate that portions of MB near the SMC is a closer to us, than the LMC.

  16. Processes of conversion of a hot metal particle into aerogel through clusters

    Energy Technology Data Exchange (ETDEWEB)

    Smirnov, B. M., E-mail: bmsmirnov@gmail.com [Russian Academy of Sciences, Joint Institute for High Temperatures (Russian Federation)

    2015-10-15

    Processes are considered for conversion into a fractal structure of a hot metal micron-size particle that is located in a buffer gas or a gas flow and is heated by an external electric or electromagnetic source or by a plasma. The parameter of this heating is the particle temperature, which is the same in the entire particle volume because of its small size and high conductivity. Three processes determine the particle heat balance: particle radiation, evaporation of metal atoms from the particle surface, and heat transport to the surrounding gas due to its thermal conductivity. The particle heat balance is analyzed based on these processes, which are analogous to those for bulk metals with the small particle size, and its high temperature taken into account. Outside the particle, where the gas temperature is lower than on its surface, the formed metal vapor in a buffer gas flow is converted into clusters. Clusters grow as a result of coagulation until they become liquid, and then clusters form fractal aggregates if they are removed form the gas flow. Subsequently, associations of fractal aggregates join into a fractal structure. The rate of this process increases in medium electric fields, and the formed fractal structure has features of aerogels and fractal fibers. As a result of a chain of the above processes, a porous metal film may be manufactured for use as a filter or catalyst for gas flows.

  17. Cyanogen strengths of globular cluster post-main-sequence stars

    International Nuclear Information System (INIS)

    Hesser, J.E.; Hartwick, F.D.A.; McClure, R.D.

    1976-01-01

    CN strengths in the peculiar clusters ω Cen and M22 and the metal-rich clusters 47 Tuc, M71, and NGC 6352 are found to vary markedly from star to star. The strong variations in CN strength found earlier for ω Cen by Norris and Bessell and by Dickens and Bell are shown to extend to fainter stars, although expected correlations of CN strength with position in the color-magnitude (C-M) diagram are less evident in our sample. Several CN and metal-strong stars were also observed in M22. We conclude that CN, once it appears in globular clusters, can vary much more than it does in equivalent Population I samples, a result we briefly examine in light of current understanding regarding physical processes in the stars themselves and of models of galactic chemical evolution

  18. Persistence of Metal-rich Particles Downstream Zones of Acid Drainage Mixing in Andean Rivers

    Science.gov (United States)

    Pasten, P.; Montecinos, M.; Guerra, P. A.; Bonilla, C. A.; Escauriaza, C. R.; Dabrin, A.; Coquery, M.

    2016-12-01

    The Andes mountain range provides the setting for watersheds with high natural background of metals and for mining operations that enhance contaminant mobilization, notably in Northern and Central Chile. Dissolved and solid metal species are actively transported by streams to the Pacific Ocean from area and point sources, like acid drainage. We examine the response of metal rich particle suspensions downstream zones of mixing where shifts in the chemical environment occur. We propose a conceptual model which is used to analyze the fate of copper in the upper Mapocho watershed. The main source of copper is the Yerba Loca river, a naturally impacted stream with pH ranging from 3 to 7 and high concentrations of Cu (0.8 - 6.3 mg/L), Al (1.3 - 7.6 mg/L) and Fe (0.4 - 4.2 mg/L). Steep chemical shifts occur after the confluences with the San Francisco and the Molina rivers. We characterized stream chemistry, hydrological variables and suspended particles, including particle size distribution (PSD), turbidity, and total suspended solids. A marked seasonal behavior was observed, with a higher total Cu flux during smelting periods and a shift towards the dissolved phase during summer. When acid drainage is discharged into a receiving stream, incomplete mixing occurs thereby promoting the formation of a range of metal-rich solids with a characteristic PSD. Similarly, areas of chemical heterogeneity control the partition of metals associated to suspended geomaterials coming from bank and slope erosion. A highly dynamic process ensues where metastable phases shift to new equilibria as fully mixed conditions are reached. Depending on the reaction kinetics, some particles persist despite being exposed to thermodynamically unfavorable chemical environments. The persistence of metal-rich particles downstream zones of acid drainage mixing is important because it ultimately controls the flux of metals being delivered to the ocean by watersheds impacted by acid drainage. Funding from

  19. A numerical study of spin-dependent organization of alkali-metal atomic clusters using density-functional method

    International Nuclear Information System (INIS)

    Liu Xuan; Ito, Haruhiko; Torikai, Eiko

    2012-01-01

    We calculate the different geometric isomers of spin clusters composed of a small number of alkali-metal atoms using the UB3LYP density-functional method. The electron density distribution of clusters changes according to the value of total spin. Steric structures as well as planar structures arise when the number of atoms increases. The lowest spin state is the most stable and Li n , Na n , K n , Rb n , and Cs n with n = 2–8 can be formed in higher spin states. In the highest spin state, the preparation of clusters depends on the kind and the number of constituent atoms. The interaction energy between alkali-metal atoms and rare-gas atoms is smaller than the binding energy of spin clusters. Consequently, it is possible to self-organize the alkali-metal-atom clusters on a non-wetting substrate coated with rare-gas atoms.

  20. A numerical study of spin-dependent organization of alkali-metal atomic clusters using density-functional method

    Energy Technology Data Exchange (ETDEWEB)

    Liu Xuan, E-mail: liu.x.ad@m.titech.ac.jp; Ito, Haruhiko [Interdisciplinary Graduate School of Science and Engineering, Tokyo Institute of Technology (Japan); Torikai, Eiko [Interdisciplinary Graduate School of Medicine and Engineering, University of Yamanashi (Japan)

    2012-08-15

    We calculate the different geometric isomers of spin clusters composed of a small number of alkali-metal atoms using the UB3LYP density-functional method. The electron density distribution of clusters changes according to the value of total spin. Steric structures as well as planar structures arise when the number of atoms increases. The lowest spin state is the most stable and Li{sub n}, Na{sub n}, K{sub n}, Rb{sub n}, and Cs{sub n} with n = 2-8 can be formed in higher spin states. In the highest spin state, the preparation of clusters depends on the kind and the number of constituent atoms. The interaction energy between alkali-metal atoms and rare-gas atoms is smaller than the binding energy of spin clusters. Consequently, it is possible to self-organize the alkali-metal-atom clusters on a non-wetting substrate coated with rare-gas atoms.

  1. Quantum kinetic theory of metal clusters in an intense electromagnetic field

    Directory of Open Access Journals (Sweden)

    M.Bonitz

    2004-01-01

    Full Text Available A quantum kinetic theory for weakly inhomogeneous charged particle systems is derived within the framework of nonequilibrium Green's functions. The results are of relevance for valence electrons of metal clusters as well as for confined Coulomb systems, such as electrons in quantum dots or ultracold ions in traps and similar systems. To be specific, here we concentrate on the application to metal clusters, but the results are straightforwardly generalized. Therefore, we first give an introduction to the physics of correlated valence electrons of metal clusters in strong electromagnetic fields. After a brief overview on the jellium model and the standard density functional approach to the ground state properties, we focus on the extension of the theory to nonequilibrium. To this end a general gauge-invariant kinetic theory is developed. The results include the equations of motion of the two-time correlation functions, the equation for the Wigner function and an analysis of the spectral function. Here, the concept of an effective quantum potential is introduced which retains the convenient local form of the propagators. This allows us to derive explicit results for the spectral function of electrons in a combined strong electromagnetic field and a weakly inhomogeneous confinement potential.

  2. Transition-metal interactions in aluminum-rich intermetallics

    International Nuclear Information System (INIS)

    Al-Lehyani, Ibrahim; Widom, Mike; Wang, Yang; Moghadam, Nassrin; Stocks, G. Malcolm; Moriarty, John A.

    2001-01-01

    The extension of the first-principles generalized pseudopotential theory (GPT) to transition-metal (TM) aluminides produces pair and many-body interactions that allow efficient calculations of total energies. In aluminum-rich systems treated at the pair-potential level, one practical limitation is a transition-metal overbinding that creates an unrealistic TM-TM attraction at short separations in the absence of balancing many-body contributions. Even with this limitation, the GPT pair potentials have been used effectively in total-energy calculations for Al-TM systems with TM atoms at separations greater than 4 Aa. An additional potential term may be added for systems with shorter TM atom separations, formally folding repulsive contributions of the three- and higher-body interactions into the pair potentials, resulting in structure-dependent TM-TM potentials. Towards this end, we have performed numerical ab initio total-energy calculations using the Vienna ab initio simulation package for an Al-Co-Ni compound in a particular quasicrystalline approximant structure. The results allow us to fit a short-ranged, many-body correction of the form a(r 0 /r) b to the GPT pair potentials for Co-Co, Co-Ni, and Ni-Ni interactions

  3. Half-lives of cluster decay of neutron rich nuclei in trans-tin region

    International Nuclear Information System (INIS)

    Swamy, G.S.; Umesh, T.K.

    2011-01-01

    In this work, the logarithmic half-life [log 10 (T 1/2 )] values have been reported for the exotic decay of some neutron rich even–even parent nuclei (56≤Z≤64) accompanied by the emission of alpha-like and non-alpha-like clusters in the trans-tin region. These values were calculated by using the single line of universal curve (UNIV) for alpha and cluster radioactive decay as well as the universal decay law (UDL). The half-life values were also separately calculated by considering the interacting nuclear potential barrier as the sum of Coulomb and proximity potentials. The half-life values based on the three calculations mentioned above, were found to agree with one another within a few orders of magnitude. Possible conclusions are drawn based on the present study. (author)

  4. X-ray Observations of Eight Young Open Star Clusters: I ...

    Indian Academy of Sciences (India)

    X-ray Observations of Eight Young Open Star Clusters: I. Membership and X-ray Luminosity. Himali Bhatt, J. C. Pandey, K. P. Singh, Ram Sagar & Brijesh Kumar. J. Astrophys. Astr. 34(4), December 2013, pp. 393–429, c Indian Academy of Sciences. Supplementary Material. Supplementary Table 3 follows.

  5. ISO far-infrared observations of rich galaxy clusters III. Abell 2029, Abell 2052, Abell 2142

    DEFF Research Database (Denmark)

    Hansen, Lene; Jørgensen, H.E.; Nørgaard-Nielsen, Hans Ulrik

    2000-01-01

    A sample of five rich galaxy clusters has been mapped by ISO at 60 mum, 100 mum, 135 mum, and 200 mum using the PHT-C camera. In previous papers Abell 2670 and Sersic 159-03 were discussed. Here we present the results for Abell 2029, Abell 2052, and Abell 2142. The conclusion of the survey...

  6. RESPIRATORY EFFECTS OF INHALED METAL-RICH PARTICULATE MATTER (PM) IN RATS: INFLUENCE OF SYSTEMIC ANTIOXIDANT DEPLETION

    Science.gov (United States)

    Metal-mediated generation of reactive oxygen species and resultant oxidative stress has been implicated in the pathogenesis of emission-source PM toxicity. We hypothesized that inducing an antioxidant deficit prior to inhalation of metal-rich PM would worsen adverse health outcom...

  7. Comparative Transcriptomic Analysis of the Response of Dunaliella acidophila (Chlorophyta) to Short-Term Cadmium and Chronic Natural Metal-Rich Water Exposures.

    Science.gov (United States)

    Puente-Sánchez, Fernando; Olsson, Sanna; Aguilera, Angeles

    2016-10-01

    Heavy metals are toxic compounds known to cause multiple and severe cellular damage. However, acidophilic extremophiles are able to cope with very high concentrations of heavy metals. This study investigated the stress response under natural environmental heavy metal concentrations in an acidophilic Dunaliella acidophila. We employed Illumina sequencing for a de novo transcriptome assembly and to identify changes in response to high cadmium concentrations and natural metal-rich water. The photosynthetic performance was also estimated by pulse amplitude-modulated (PAM) fluorescence. Transcriptomic analysis highlights a number of processes mainly related to a high constitutive expression of genes involved in oxidative stress and response to reactive oxygen species (ROS), even in the absence of heavy metals. Photosynthetic activity seems to be unaltered under short-term exposition to Cd and chronic exposure to natural metal-rich water, probably due to an increase in the synthesis of structural photosynthetic components preserving their functional integrity. An overrepresentation of Gene Ontology (GO) terms related to metabolic activities, transcription, and proteosomal catabolic process was observed when D. acidophila grew under chronic exposure to natural metal-rich water. GO terms involved in carbohydrate metabolic process, reticulum endoplasmic and Golgi bodies, were also specifically overrepresented in natural metal-rich water library suggesting an endoplasmic reticulum stress response.

  8. PREFACE: Nuclear Cluster Conference; Cluster'07

    Science.gov (United States)

    Freer, Martin

    2008-05-01

    The Cluster Conference is a long-running conference series dating back to the 1960's, the first being initiated by Wildermuth in Bochum, Germany, in 1969. The most recent meeting was held in Nara, Japan, in 2003, and in 2007 the 9th Cluster Conference was held in Stratford-upon-Avon, UK. As the name suggests the town of Stratford lies upon the River Avon, and shortly before the conference, due to unprecedented rainfall in the area (approximately 10 cm within half a day), lay in the River Avon! Stratford is the birthplace of the `Bard of Avon' William Shakespeare, and this formed an intriguing conference backdrop. The meeting was attended by some 90 delegates and the programme contained 65 70 oral presentations, and was opened by a historical perspective presented by Professor Brink (Oxford) and closed by Professor Horiuchi (RCNP) with an overview of the conference and future perspectives. In between, the conference covered aspects of clustering in exotic nuclei (both neutron and proton-rich), molecular structures in which valence neutrons are exchanged between cluster cores, condensates in nuclei, neutron-clusters, superheavy nuclei, clusters in nuclear astrophysical processes and exotic cluster decays such as 2p and ternary cluster decay. The field of nuclear clustering has become strongly influenced by the physics of radioactive beam facilities (reflected in the programme), and by the excitement that clustering may have an important impact on the structure of nuclei at the neutron drip-line. It was clear that since Nara the field had progressed substantially and that new themes had emerged and others had crystallized. Two particular topics resonated strongly condensates and nuclear molecules. These topics are thus likely to be central in the next cluster conference which will be held in 2011 in the Hungarian city of Debrechen. Martin Freer Participants and Cluster'07

  9. HUBBLE SPACE TELESCOPE PHOTOMETRY OF GLOBULAR CLUSTERS IN M81

    International Nuclear Information System (INIS)

    Nantais, Julie B.; Huchra, John P.; Zezas, Andreas; Gazeas, Kosmas; Strader, Jay

    2011-01-01

    We perform aperture photometry and profile fitting on 419 globular cluster (GC) candidates with m V ≤ 23 mag identified in Hubble Space Telescope/Advanced Camera for Surveys BVI imaging, and estimate the effective radii of the clusters. We identify 85 previously known spectroscopically confirmed clusters, and newly identify 136 objects as good cluster candidates within the 3σ color and size ranges defined by the spectroscopically confirmed clusters, yielding a total of 221 probable GCs. The luminosity function peak for the 221 probable GCs with estimated total dereddening applied is V ∼ (20.26 ± 0.13) mag, corresponding to a distance of ∼3.7 ± 0.3 Mpc. The blue and red GC candidates, and the metal-rich and metal-poor spectroscopically confirmed clusters, respectively, are similar in half-light radius. Red confirmed clusters are about 6% larger in median half-light radius than blue confirmed clusters, and red and blue good GC candidates are nearly identical in half-light radius. The total population of confirmed and 'good' candidates shows an increase in half-light radius as a function of galactocentric distance.

  10. TIME-SERIES SPECTROSCOPY OF TWO CANDIDATE DOUBLE DEGENERATES IN THE OPEN CLUSTER NGC 6633

    Energy Technology Data Exchange (ETDEWEB)

    Williams, Kurtis A.; Chakraborty, Subho [Department of Physics and Astrophysics, Texas A and M University-Commerce, P.O. Box 3011, Commerce, TX, 75429 (United States); Serna-Grey, Donald [Department of Astronomy, University of Washington, Box 351580, Seattle, WA, 98195 (United States); Gianninas, A.; Canton, Paul A., E-mail: Kurtis.Williams@tamuc.edu [Homer L. Dodge Department of Physics and Astronomy, University of Oklahoma, 440 W. Brooks St., Norman, OK, 73019 (United States)

    2015-12-15

    SNe Ia are heavily used tools in precision cosmology, yet we still are not certain what the progenitor systems are. General plausibility arguments suggest there is potential for identifying double degenerate SN Ia progenitors in intermediate-age open star clusters. We present time-resolved high-resolution spectroscopy of two white dwarfs (WDs) in the field of the open cluster NGC 6633 that had previously been identified as candidate double degenerates in the cluster. However, three hours of continuous observations of each candidate failed to detect any significant radial velocity variations at the ≳10 km s{sup −1} level, making it highly unlikely that either WD is a double degenerate that will merge within a Hubble Time. The WD LAWDS NGC 6633 4 has a radial velocity inconsistent with cluster membership at the 2.5σ level, while the radial velocity of LAWDS NGC 6633 7 is consistent with cluster membership. We conservatively conclude that LAWDS 7 is a viable massive double degenerate candidate, though unlikely to be a Type Ia progenitor. Astrometric data from GAIA will likely be needed to determine if either WD is truly a cluster member.

  11. Silver-induced reconstruction of an adeninate-based metal-organic framework for encapsulation of luminescent adenine-stabilized silver clusters.

    Science.gov (United States)

    Jonckheere, Dries; Coutino-Gonzalez, Eduardo; Baekelant, Wouter; Bueken, Bart; Reinsch, Helge; Stassen, Ivo; Fenwick, Oliver; Richard, Fanny; Samorì, Paolo; Ameloot, Rob; Hofkens, Johan; Roeffaers, Maarten B J; De Vos, Dirk E

    2016-05-21

    Bright luminescent silver-adenine species were successfully stabilized in the pores of the MOF-69A (zinc biphenyldicarboxylate) metal-organic framework, starting from the intrinsically blue luminescent bio-MOF-1 (zinc adeninate 4,4'-biphenyldicarboxylate). Bio-MOF-1 is transformed to the MOF-69A framework by selectively leaching structural adenine linkers from the original framework using silver nitrate solutions in aqueous ethanol. Simultaneously, bright blue-green luminescent silver-adenine clusters are formed inside the pores of the recrystallized MOF-69A matrix in high local concentrations. The structural transition and concurrent changes in optical properties were characterized using a range of structural, physicochemical and spectroscopic techniques (steady-state and time-resolved luminescence, quantum yield determination, fluorescence microscopy). The presented results open new avenues for exploring the use of MOFs containing luminescent silver clusters for solid-state lighting and sensor applications.

  12. Temporal clustering of floods in Germany: Do flood-rich and flood-poor periods exist?

    Science.gov (United States)

    Merz, Bruno; Nguyen, Viet Dung; Vorogushyn, Sergiy

    2016-10-01

    The repeated occurrence of exceptional floods within a few years, such as the Rhine floods in 1993 and 1995 and the Elbe and Danube floods in 2002 and 2013, suggests that floods in Central Europe may be organized in flood-rich and flood-poor periods. This hypothesis is studied by testing the significance of temporal clustering in flood occurrence (peak-over-threshold) time series for 68 catchments across Germany for the period 1932-2005. To assess the robustness of the results, different methods are used: Firstly, the index of dispersion, which quantifies the departure from a homogeneous Poisson process, is investigated. Further, the time-variation of the flood occurrence rate is derived by non-parametric kernel implementation and the significance of clustering is evaluated via parametric and non-parametric tests. Although the methods give consistent overall results, the specific results differ considerably. Hence, we recommend applying different methods when investigating flood clustering. For flood estimation and risk management, it is of relevance to understand whether clustering changes with flood severity and time scale. To this end, clustering is assessed for different thresholds and time scales. It is found that the majority of catchments show temporal clustering at the 5% significance level for low thresholds and time scales of one to a few years. However, clustering decreases substantially with increasing threshold and time scale. We hypothesize that flood clustering in Germany is mainly caused by catchment memory effects along with intra- to inter-annual climate variability, and that decadal climate variability plays a minor role.

  13. A comprehensive study of the young open star cluster NGC 6611 based on deep VRI CCD images and 2MASS data

    Directory of Open Access Journals (Sweden)

    I.M. Selim

    2016-06-01

    Full Text Available In the present study, we have used Deep CCD images of the extremely young open star cluster NGC 6611, up to a limiting magnitude of V ∼ 22.86 mag in V, R and I passbands. The resulting color-magnitude V; (V–I diagram as well as their radial density profiles has been determined. Using 2MASS data, we confirmed the consistency between the 2MASS photometry, by fitting isochrones, the extinction E(V–I = 0.530 ± 0.04 mag, E(J–H = 0.31 ± 0.02, from the color magnitude diagram the cluster distance =2.2 ± 0.21 kpc and age = 3.6 Myr, based on the fitting of theoretical stellar isochrones of solar metallicity Z = 0.019. The distance modulus of the cluster is estimated at 12.3. The radial stellar density profiles and the cluster center have been determined by two methods. The core and cluster radii are determined from the radial stellar density profiles. Only about 40% of the cluster members are present in the core region. The cluster luminosity function has been calculated. The mass function slope of the entire cluster is ∼−0.67 ± 0.12. The effects of mass segregation, most probably due to dynamical evolution, have been observed in the cluster.

  14. Metal-rich fluid inclusions provide new insights into unconformity-related U deposits (Athabasca Basin and Basement, Canada)

    Science.gov (United States)

    Richard, Antonin; Cathelineau, Michel; Boiron, Marie-Christine; Mercadier, Julien; Banks, David A.; Cuney, Michel

    2016-02-01

    alteration. Finally, the metal concentrations in the NaCl-rich and CaCl2-rich brines are among the highest recorded compared to present-day sedimentary formation waters and fluid inclusions from basin-hosted base metal deposits (up to 600 ppm U, 3000 ppm Mn, 4000 ppm Zn, 6000 ppm Cu, 8000 ppm Pb, and 10,000 ppm Fe). The CaCl2-rich brine carries up to one order of magnitude more metal than the NaCl-rich brine. Though the exact origin of major cations and metals of the two brines remains uncertain, their contrasting compositions indicate that the two brines had distinct flow paths and fluid-rock interactions. Large-scale circulation of the brines in the Athabasca Basin and Basement was therefore a key parameter for metal mobility (including U) and formation of unconformity-related U deposits.

  15. Nanocomposite metal/plasma polymer films prepared by means of gas aggregation cluster source

    Energy Technology Data Exchange (ETDEWEB)

    Polonskyi, O.; Solar, P.; Kylian, O.; Drabik, M.; Artemenko, A.; Kousal, J.; Hanus, J.; Pesicka, J.; Matolinova, I. [Charles University in Prague, Faculty of Mathematics and Physics, V Holesovickach 2, 18000 Prague 8 (Czech Republic); Kolibalova, E. [Tescan, Libusina trida 21, 632 00 Brno (Czech Republic); Slavinska, D. [Charles University in Prague, Faculty of Mathematics and Physics, V Holesovickach 2, 18000 Prague 8 (Czech Republic); Biederman, H., E-mail: bieder@kmf.troja.mff.cuni.cz [Charles University in Prague, Faculty of Mathematics and Physics, V Holesovickach 2, 18000 Prague 8 (Czech Republic)

    2012-04-02

    Nanocomposite metal/plasma polymer films have been prepared by simultaneous plasma polymerization using a mixture of Ar/n-hexane and metal cluster beams. A simple compact cluster gas aggregation source is described and characterized with emphasis on the determination of the amount of charged clusters and their size distribution. It is shown that the fraction of neutral, positively and negatively charged nanoclusters leaving the gas aggregation source is largely influenced by used operational conditions. In addition, it is demonstrated that a large portion of Ag clusters is positively charged, especially when higher currents are used for their production. Deposition of nanocomposite Ag/C:H plasma polymer films is described in detail by means of cluster gas aggregation source. Basic characterization of the films is performed using transmission electron microscopy, ultraviolet-visible and Fourier-transform infrared spectroscopies. It is shown that the morphology, structure and optical properties of such prepared nanocomposites differ significantly from the ones fabricated by means of magnetron sputtering of Ag target in Ar/n-hexane mixture.

  16. Asymmetric polymeric membranes containing a metal-rich dense layer with a controlled thickness and method of making same

    KAUST Repository

    Peinemann, Klaus-Viktor; Villalobos, Vazquez De La Parra Luis Francisco

    2016-01-01

    A structure, and methods of making the structure are provided in which the structure can include: a membrane having a first layer and a second layer, the first layer comprising polymer chains formed with coordination complexes with metal ions, and the second layer consisting of a porous support layer formed of polymer chains substantially, if not completely, lacking the presence of metal ions. The structure can be an asymmetric polymeric membrane containing a metal-rich layer as the first layer. In various embodiments the first layer can be a metal-rich dense layer. The first layer can include pores. The polymer chains of the first layer can be closely packed. The second layer can include a plurality of macro voids and can have an absence of the metal ions of the first layer.

  17. Asymmetric polymeric membranes containing a metal-rich dense layer with a controlled thickness and method of making same

    KAUST Repository

    Peinemann, Klaus-Viktor

    2016-01-21

    A structure, and methods of making the structure are provided in which the structure can include: a membrane having a first layer and a second layer, the first layer comprising polymer chains formed with coordination complexes with metal ions, and the second layer consisting of a porous support layer formed of polymer chains substantially, if not completely, lacking the presence of metal ions. The structure can be an asymmetric polymeric membrane containing a metal-rich layer as the first layer. In various embodiments the first layer can be a metal-rich dense layer. The first layer can include pores. The polymer chains of the first layer can be closely packed. The second layer can include a plurality of macro voids and can have an absence of the metal ions of the first layer.

  18. Jiangxi Copper Made Strategic Investment in Hami with Rich Nonferrous Metal Resources

    Institute of Scientific and Technical Information of China (English)

    2015-01-01

    On October 11,Hami region and Jiangxi Copper Group Corporation held a contractsigning ceremony for strategic cooperation,signaling that Hami region has become a key strategic investment base of Jiangxi Copper Group Corporation,a company with the biggest manufacture base of copper products in China.Hami region boasts rich nonferrous metal

  19. Monte-Carlo simulation of defect-cluster nucleation in metals during irradiation

    International Nuclear Information System (INIS)

    Nakasuji, Toshiki; Morishita, Kazunori; Ruan, Xiaoyong

    2017-01-01

    Highlights: • Monte-Carlo simulations were performed to investigate the nucleation process of copper-vacancy clusters in Fe. • Nucleation paths were obtained as a function of temperature and the damage rate. - Abstract: A multiscale modeling approach was applied to investigate the nucleation process of CRPs (copper rich precipitates, i.e., copper-vacancy clusters) in α-Fe containing 1 at.% Cu during irradiation. Monte-Carlo simulations were performed to investigate the nucleation process, with the rate theory equation analysis to evaluate the concentration of displacement defects, along with the molecular dynamics technique to know CRP thermal stabilities in advance. Our MC simulations showed that there is long incubation period at first, followed by a rapid growth of CRPs. The incubation period depends on irradiation conditions such as the damage rate and temperature. CRP’s composition during nucleation varies with time. The copper content of CRPs shows relatively rich at first, and then becomes poorer as the precipitate size increases. A widely-accepted model of CRP nucleation process is finally proposed.

  20. Monte-Carlo simulation of defect-cluster nucleation in metals during irradiation

    Energy Technology Data Exchange (ETDEWEB)

    Nakasuji, Toshiki, E-mail: t-nakasuji@iae.kyoto-u.ac.jp [Graduate School of Energy Science, Kyoto University, Uji, Kyoto 611-0011 (Japan); Morishita, Kazunori [Institute of Advanced Energy, Kyoto University, Uji, Kyoto 611-0011 (Japan); Ruan, Xiaoyong [Graduate School of Energy Science, Kyoto University, Uji, Kyoto 611-0011 (Japan)

    2017-02-15

    Highlights: • Monte-Carlo simulations were performed to investigate the nucleation process of copper-vacancy clusters in Fe. • Nucleation paths were obtained as a function of temperature and the damage rate. - Abstract: A multiscale modeling approach was applied to investigate the nucleation process of CRPs (copper rich precipitates, i.e., copper-vacancy clusters) in α-Fe containing 1 at.% Cu during irradiation. Monte-Carlo simulations were performed to investigate the nucleation process, with the rate theory equation analysis to evaluate the concentration of displacement defects, along with the molecular dynamics technique to know CRP thermal stabilities in advance. Our MC simulations showed that there is long incubation period at first, followed by a rapid growth of CRPs. The incubation period depends on irradiation conditions such as the damage rate and temperature. CRP’s composition during nucleation varies with time. The copper content of CRPs shows relatively rich at first, and then becomes poorer as the precipitate size increases. A widely-accepted model of CRP nucleation process is finally proposed.

  1. Metal nitride cluster as a template to tune the electronic and magnetic properties of rare-earth metal containing endohedral fullerenes

    International Nuclear Information System (INIS)

    Zhang, Yang

    2013-01-01

    Rare-earth metal containing endohedral fullerenes have attracted much attention due to the feasibility of encaging metal atom, atoms or cluster inside of carbon cages. By switching the metal atom or cluster entrapped inside of the carbon cage the physical and chemical properties of the fullerene compounds can be tuned. The understanding of magnetic and electrochemical properties of endohedral fullerenes plays an essential role in fundamental scientific researches and potential applications in materials science. In this thesis, synthesizing novel rare-earth metal containing endohedral fullerene structures, studying the properties of these isolated endohedral fullerenes and the strategies of tuning the electronic and magnetic properties of endohedral fullerenes were introduced. The DC-arc discharging synthesis of different lanthanide metal-based (Ho, Ce and Pr) mixed metal nitride clusterfullerenes was achieved. Those rare-earth metal containing endohedral fullerenes were isolated by multi-step HPLC. The isolated samples were characterized by spectroscopic techniques included UV-vis-NIR, FTIR, Raman, LDI-TOF mass spectrometry, NMR and electrochemistry. The Ho-based mixed metal nitride clusterfullerenes Ho x M 3-x N rate at C 80 (M= Sc, Lu, Y; x=1, 2) were synthesized by ''reactive gas atmosphere'' method or ''selective organic solid'' route. The isolated samples were characterized by LDI-TOF mass spectrometry, UV-vis-NIR, FTIR, Raman and NMR spectroscopy. The 13 C NMR spectroscopic studies demonstrated exceptional NMR behaviors that resulted from switching the second metal inside of the mixed metal nitride cluster Ho x M 3-x N from Sc to Lu and further to Y. The LnSc 2 N rate at C 80 (Ln= Ce, Pr, Nd, Tb, Dy, Ho, Lu) MMNCFs were characterized by 13 C and 45 Sc NMR study respectively. According to Bleaney's theory and Reilley method, the separation of δ PC and δ con from δ para was achieved by the primary 13 C and 45 Sc NMR analysis of LnSc 2 N rate at C 80 (I). The

  2. CHANDRA OBSERVATION OF ABELL 1142: A COOL-CORE CLUSTER LACKING A CENTRAL BRIGHTEST CLUSTER GALAXY?

    Energy Technology Data Exchange (ETDEWEB)

    Su, Yuanyuan; Weeren, Reinout van [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States); Buote, David A. [Department of Physics and Astronomy, University of California, Irvine, 4129 Frederick Reines Hall, Irvine, CA 92697 (United States); Gastaldello, Fabio, E-mail: yuanyuan.su@cfa.harvard.edu [INAF-IASF-Milano, Via E. Bassini 15, I-20133 Milano (Italy)

    2016-04-10

    Abell 1142 is a low-mass galaxy cluster at low redshift containing two comparable brightest cluster galaxies (BCGs) resembling a scaled-down version of the Coma Cluster. Our Chandra analysis reveals an X-ray emission peak, roughly 100 kpc away from either BCG, which we identify as the cluster center. The emission center manifests itself as a second beta-model surface brightness component distinct from that of the cluster on larger scales. The center is also substantially cooler and more metal-rich than the surrounding intracluster medium (ICM), which makes Abell 1142 appear to be a cool-core cluster. The redshift distribution of its member galaxies indicates that Abell 1142 may contain two subclusters, each of which contain one BCG. The BCGs are merging at a relative velocity of ≈1200 km s{sup −1}. This ongoing merger may have shock-heated the ICM from ≈2 keV to above 3 keV, which would explain the anomalous L{sub X}–T{sub X} scaling relation for this system. This merger may have displaced the metal-enriched “cool core” of either of the subclusters from the BCG. The southern BCG consists of three individual galaxies residing within a radius of 5 kpc in projection. These galaxies should rapidly sink into the subcluster center due to the dynamical friction of a cuspy cold dark matter halo.

  3. Comparison between XAS, AWAXS and DAFS applied to nanometer scale supported metallic clusters. Pt.1; monometallic clusters

    International Nuclear Information System (INIS)

    Bazin, D.C.; Sayers, D.A.

    1993-01-01

    The structural information found using three techniques related to synchrotron radiation are compared. XAS (X-ray Absorption Spectroscopy), AWAXS (Anomalous Wide Angle X-ray Scattering) and DAFS (Diffraction Anomalous Fine Structure) are applied to nanometer scale metallic clusters. (author)

  4. Astrophysical parameters of open star clusters using 2MASS JHKs data

    Science.gov (United States)

    Durgapal, Alok; Bisht, Devendra; Yadav, Ramakant Singh

    2018-04-01

    In the present analysis we have estimated the fundamental parameters of two poorly studied open star clusters, namely Teutsch 61 and Czernik 3, using 2MASS JHKs data. We have used the color-magnitude and colour-colour diagrams to determine their fundamental parameters.

  5. NMR in metal cluster compounds compared to glasses

    International Nuclear Information System (INIS)

    Staveren, M.P.J. van; Brom, H.B.; Jongh, L.J. de; Schmid, G.

    1991-01-01

    The field and temperature dependence of the 31 P nuclear spin lattice relaxation rate in the metal cluster compound Ru 55 (P(t-Bu) 3 ) 12 Cl 20 follows a power law: 1/T 1 ∝ T n B -m , with n = 1.5 ± 0.1 at 3.25 T and n = 1.3 ± 0.1 at 6.45 T; m ≅ 1.4. Such dependences have so far only been observed in inorganic glasses and been attributed to two level systems. The correspondence suggests that the relaxation rate is due to interaction of the P-nuclear moment with electronic spins of stochastically moving charge carriers, which are thought to be responsible for the electrical conductivity through hopping between neigboring cluster molecules. (orig.)

  6. Kepler red-clump stars in the field and in open clusters

    DEFF Research Database (Denmark)

    Bossini, D.; Miglio, A.; Salaris, M.

    2017-01-01

    Convective mixing in helium-core-burning (HeCB) stars is one of the outstanding issues in stellar modelling. The precise asteroseismic measurements of gravity-mode period spacing (Delta Pi(1)) have opened the door to detailed studies of the near-core structure of such stars, which had not been...... possible before. Here, we provide stringent tests of various core-mixing scenarios against the largely unbiased population of red-clump stars belonging to the old-open clusters monitored by Kepler, and by coupling the updated precise inference on Delta Pi(1) in thousands of field stars with spectroscopic...... constraints. We find that models with moderate overshooting successfully reproduce the range observed of Delta Pi(1) in clusters. In particular, we show that there is no evidence for the need to extend the size of the adiabatically stratified core, at least at the beginning of the HeCB phase. This conclusion...

  7. Applications of Open Source GMAW-Based Metal 3-D Printing

    OpenAIRE

    Yuenyong Nilsiam; Paul G. Sanders; Joshua M. Pearce

    2018-01-01

    The metal 3-D printing market is currently dominated by high-end applications, which make it inaccessible for small and medium enterprises, fab labs, and individual makers who are interested in the ability to prototype and additively manufacture final products in metal. Recent progress led to low-cost open-source metal 3-D printers using a gas metal arc welding (GMAW)-based print head. This reduced the cost of metal 3-D printers into the range of desktop prosumer polymer 3-D printers. Consequ...

  8. THE SIZE DIFFERENCE BETWEEN RED AND BLUE GLOBULAR CLUSTERS IS NOT DUE TO PROJECTION EFFECTS

    International Nuclear Information System (INIS)

    Webb, Jeremy J.; Harris, William E.; Sills, Alison

    2012-01-01

    Metal-rich (red) globular clusters in massive galaxies are, on average, smaller than metal-poor (blue) globular clusters. One of the possible explanations for this phenomenon is that the two populations of clusters have different spatial distributions. We test this idea by comparing clusters observed in unusually deep, high signal-to-noise images of M87 with a simulated globular cluster population in which the red and blue clusters have different spatial distributions, matching the observations. We compare the overall distribution of cluster effective radii as well as the relationship between effective radius and galactocentric distance for both the observed and simulated red and blue sub-populations. We find that the different spatial distributions does not produce a significant size difference between the red and blue sub-populations as a whole or at a given galactocentric distance. These results suggest that the size difference between red and blue globular clusters is likely due to differences during formation or later evolution.

  9. The Size Difference between Red and Blue Globular Clusters is not due to Projection Effects

    Science.gov (United States)

    Webb, Jeremy J.; Harris, William E.; Sills, Alison

    2012-11-01

    Metal-rich (red) globular clusters in massive galaxies are, on average, smaller than metal-poor (blue) globular clusters. One of the possible explanations for this phenomenon is that the two populations of clusters have different spatial distributions. We test this idea by comparing clusters observed in unusually deep, high signal-to-noise images of M87 with a simulated globular cluster population in which the red and blue clusters have different spatial distributions, matching the observations. We compare the overall distribution of cluster effective radii as well as the relationship between effective radius and galactocentric distance for both the observed and simulated red and blue sub-populations. We find that the different spatial distributions does not produce a significant size difference between the red and blue sub-populations as a whole or at a given galactocentric distance. These results suggest that the size difference between red and blue globular clusters is likely due to differences during formation or later evolution.

  10. Cluster structures in light nuclei

    International Nuclear Information System (INIS)

    Horiuchi, H.

    2000-01-01

    Complete text of publication follows. Clustering in neutron-rich nuclei is discussed. To understand the novel features (1,2,3) of the clustering in neutron-rich nuclei, the basic features of the clustering in stable nuclei (4) are briefly reviewed. In neutron-rich nuclei, the requirement of the stability of clusters is questioned and the threshold rule is no more obeyed. Examples of clustering in Be and B isotopes (4,5) are discussed in some detail. Possible existence of novel type of clustering near neutron dripline is suggested (1). (author)

  11. Determining open cluster membership. A Bayesian framework for quantitative member classification

    Science.gov (United States)

    Stott, Jonathan J.

    2018-01-01

    Aims: My goal is to develop a quantitative algorithm for assessing open cluster membership probabilities. The algorithm is designed to work with single-epoch observations. In its simplest form, only one set of program images and one set of reference images are required. Methods: The algorithm is based on a two-stage joint astrometric and photometric assessment of cluster membership probabilities. The probabilities were computed within a Bayesian framework using any available prior information. Where possible, the algorithm emphasizes simplicity over mathematical sophistication. Results: The algorithm was implemented and tested against three observational fields using published survey data. M 67 and NGC 654 were selected as cluster examples while a third, cluster-free, field was used for the final test data set. The algorithm shows good quantitative agreement with the existing surveys and has a false-positive rate significantly lower than the astrometric or photometric methods used individually.

  12. ENVIRONMENTAL EFFECTS ON THE METAL ENRICHMENT OF LOW-MASS GALAXIES IN NEARBY CLUSTERS

    Energy Technology Data Exchange (ETDEWEB)

    Petropoulou, V.; Vilchez, J.; Iglesias-Paramo, J. [Instituto de Astrofisica de Andalucia-C.S.I.C., Glorieta de la Astronomia, 18008 Granada (Spain)

    2012-04-20

    In this paper, we study the chemical history of low-mass star-forming (SF) galaxies in the local universe clusters Coma, A1367, A779, and A634. The aim of this work is to search for the imprint of the environment on the chemical evolution of these galaxies. Galaxy chemical evolution is linked to the star formation history, as well as to the gas interchange with the environment, and low-mass galaxies are well known to be vulnerable systems to environmental processes affecting both these parameters. For our study we have used spectra from the SDSS-III DR8. We have examined the spectroscopic properties of SF galaxies of stellar masses 10{sup 8}-10{sup 10} M{sub Sun }, located from the core to the cluster's outskirts. The gas-phase O/H and N/O chemical abundances have been derived using the latest empirical calibrations. We have examined the mass-metallicity relation of cluster galaxies, finding well-defined sequences. The slope of these sequences, for galaxies in low-mass clusters and galaxies at large cluster-centric distances, follows the predictions of recent hydrodynamic models. A flattening of this slope has been observed for galaxies located in the core of the two more massive clusters of the sample, principally in Coma, suggesting that the imprint of the cluster environment on the chemical evolution of SF galaxies should be sensitive to both the galaxy mass and the host cluster mass. The H I gas content of Coma and A1367 galaxies indicates that low-mass SF galaxies, located at the core of these clusters, have been severely affected by ram-pressure stripping (RPS). The observed mass-dependent enhancement of the metal content of low-mass galaxies in dense environments seems plausible, according to hydrodynamic simulations. This enhanced metal enrichment could be produced by the combination of effects such as wind reaccretion, due to pressure confinement by the intracluster medium (ICM), and the truncation of gas infall, as a result of the RPS. Thus, the

  13. ENVIRONMENTAL EFFECTS ON THE METAL ENRICHMENT OF LOW-MASS GALAXIES IN NEARBY CLUSTERS

    International Nuclear Information System (INIS)

    Petropoulou, V.; Vílchez, J.; Iglesias-Páramo, J.

    2012-01-01

    In this paper, we study the chemical history of low-mass star-forming (SF) galaxies in the local universe clusters Coma, A1367, A779, and A634. The aim of this work is to search for the imprint of the environment on the chemical evolution of these galaxies. Galaxy chemical evolution is linked to the star formation history, as well as to the gas interchange with the environment, and low-mass galaxies are well known to be vulnerable systems to environmental processes affecting both these parameters. For our study we have used spectra from the SDSS-III DR8. We have examined the spectroscopic properties of SF galaxies of stellar masses 10 8 -10 10 M ☉ , located from the core to the cluster's outskirts. The gas-phase O/H and N/O chemical abundances have been derived using the latest empirical calibrations. We have examined the mass-metallicity relation of cluster galaxies, finding well-defined sequences. The slope of these sequences, for galaxies in low-mass clusters and galaxies at large cluster-centric distances, follows the predictions of recent hydrodynamic models. A flattening of this slope has been observed for galaxies located in the core of the two more massive clusters of the sample, principally in Coma, suggesting that the imprint of the cluster environment on the chemical evolution of SF galaxies should be sensitive to both the galaxy mass and the host cluster mass. The H I gas content of Coma and A1367 galaxies indicates that low-mass SF galaxies, located at the core of these clusters, have been severely affected by ram-pressure stripping (RPS). The observed mass-dependent enhancement of the metal content of low-mass galaxies in dense environments seems plausible, according to hydrodynamic simulations. This enhanced metal enrichment could be produced by the combination of effects such as wind reaccretion, due to pressure confinement by the intracluster medium (ICM), and the truncation of gas infall, as a result of the RPS. Thus, the properties of the ICM

  14. Metal cluster fission: jellium model and Molecular dynamics simulations

    DEFF Research Database (Denmark)

    Lyalin, Andrey G.; Obolensky, Oleg I.; Solov'yov, Ilia

    2004-01-01

    Fission of doubly charged sodium clusters is studied using the open-shell two-center deformed jellium model approximation and it ab initio molecular dynamic approach accounting for all electrons in the system. Results of calculations of fission reactions Na_10^2+ --> Na_7^+ + Na_3^+ and Na_18...

  15. Quasars in galaxy cluster environments

    International Nuclear Information System (INIS)

    Ellingson, E.

    1989-01-01

    The evolution of radio loud quasars is found to be strongly dependent upon their galaxy cluster environment. Previous studies have shown that bright quasars are found in rich clusters, while high luminosity quasars are found only in poorer environments. The analysis of low luminosity radio quiet quasars indicate that they are never found in rich environments, suggesting that they are a physically different class of objects. Properties of the quasar environment are investigated to determine constraints on the physical mechanisms of quasar formation and evolution. The optical cluster morphology indicates that the cluster cores have smaller radii and higher galaxy densities than are typical for low redshift clusters of similar richness. Radio morphologies may indicate that the formation of a dense intra-cluster medium is associated with the quasars' fading at these epochs. Galaxy colors appear to be normal, but there may be a tendency for clusters associated with high luminosity quasars to contain a higher fraction of gas-rich galaxies than those associated with low luminosity quasars. Multislit spectroscopic observations of galaxies associated with high luminosity quasars indicate that quasars are preferentially located in regions of low relative velocity dispersion, either in rich clusters of abnormally low dispersion, or in poor groups which are dynamically normal. This suggests that galaxy-galaxy interactions may play a role in quasar formation and sustenanace. Virialization of rich clusters and the subsequent increase in galaxy velocities may therefore be responsible for the fading of quasars in rich environments

  16. Extending FEAST-METAL for analysis of low content minor actinide bearing and zirconium rich metallic fuels for sodium fast reactors

    Energy Technology Data Exchange (ETDEWEB)

    Karahan, Aydin, E-mail: karahan@mit.edu [Center for Advanced Nuclear Energy Systems, Nuclear Science and Engineering Department, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge MA 24-204 (United States)

    2011-07-15

    Computational models in FEAST-METAL fuel behaviour code have been upgraded to simulate minor actinide bearing zirconium rich metallic fuels for use in sodium fast reactors. Increasing the zirconium content to 20-40 wt.% causes significant changes in fuel slug microstructure affecting thermal, mechanical, chemical, and fission gas behaviour. Inclusion of zirconium rich phase reduces the fission gas swelling rate significantly in early irradiation. Above the threshold fission gas swelling, formation of micro-cracks, and open pores increase material compliancy enhance diffusivity, leading to rapid fuel gas swelling, interconnected porosity development and release of the fission gases and helium. Production and release of helium was modelled empirically as a function of americium content and fission gas production, consistent with previous Idaho National Laboratory studies. Predicted fuel constituent redistribution is much smaller compared to typical U-Pu-10Zr fuel operated at EBR-II. Material properties such as fuel thermal conductivity, modulus of elasticity, and thermal expansion coefficient have been approximated using the available database. Creep rate and fission gas diffusivity of high zirconium fuel is lowered by an order of magnitude with respect to the reference low zirconium fuel based on limited database and in order to match experimental observations. The new code is benchmarked against the AFC-1F fuel assembly post irradiation examination results. Satisfactory match was obtained for fission gas release and swelling behaviour. Finally, the study considers a comparison of fuel behaviour between high zirconium content minor actinide bearing fuel and typical U-15Pu-6Zr fuel pins with 75% smear density. The new fuel has much higher fissile content, allowing for operating at lower neutron flux level compared to fuel with lower fissile density. This feature allows the designer to reach a much higher burnup before reaching the cladding dose limit. On the other

  17. Extending FEAST-METAL for analysis of low content minor actinide bearing and zirconium rich metallic fuels for sodium fast reactors

    Science.gov (United States)

    Karahan, Aydın

    2011-07-01

    Computational models in FEAST-METAL fuel behaviour code have been upgraded to simulate minor actinide bearing zirconium rich metallic fuels for use in sodium fast reactors. Increasing the zirconium content to 20-40 wt.% causes significant changes in fuel slug microstructure affecting thermal, mechanical, chemical, and fission gas behaviour. Inclusion of zirconium rich phase reduces the fission gas swelling rate significantly in early irradiation. Above the threshold fission gas swelling, formation of micro-cracks, and open pores increase material compliancy enhance diffusivity, leading to rapid fuel gas swelling, interconnected porosity development and release of the fission gases and helium. Production and release of helium was modelled empirically as a function of americium content and fission gas production, consistent with previous Idaho National Laboratory studies. Predicted fuel constituent redistribution is much smaller compared to typical U-Pu-10Zr fuel operated at EBR-II. Material properties such as fuel thermal conductivity, modulus of elasticity, and thermal expansion coefficient have been approximated using the available database. Creep rate and fission gas diffusivity of high zirconium fuel is lowered by an order of magnitude with respect to the reference low zirconium fuel based on limited database and in order to match experimental observations. The new code is benchmarked against the AFC-1F fuel assembly post irradiation examination results. Satisfactory match was obtained for fission gas release and swelling behaviour. Finally, the study considers a comparison of fuel behaviour between high zirconium content minor actinide bearing fuel and typical U-15Pu-6Zr fuel pins with 75% smear density. The new fuel has much higher fissile content, allowing for operating at lower neutron flux level compared to fuel with lower fissile density. This feature allows the designer to reach a much higher burnup before reaching the cladding dose limit. On the other

  18. Extending FEAST-METAL for analysis of low content minor actinide bearing and zirconium rich metallic fuels for sodium fast reactors

    International Nuclear Information System (INIS)

    Karahan, Aydin

    2011-01-01

    Computational models in FEAST-METAL fuel behaviour code have been upgraded to simulate minor actinide bearing zirconium rich metallic fuels for use in sodium fast reactors. Increasing the zirconium content to 20-40 wt.% causes significant changes in fuel slug microstructure affecting thermal, mechanical, chemical, and fission gas behaviour. Inclusion of zirconium rich phase reduces the fission gas swelling rate significantly in early irradiation. Above the threshold fission gas swelling, formation of micro-cracks, and open pores increase material compliancy enhance diffusivity, leading to rapid fuel gas swelling, interconnected porosity development and release of the fission gases and helium. Production and release of helium was modelled empirically as a function of americium content and fission gas production, consistent with previous Idaho National Laboratory studies. Predicted fuel constituent redistribution is much smaller compared to typical U-Pu-10Zr fuel operated at EBR-II. Material properties such as fuel thermal conductivity, modulus of elasticity, and thermal expansion coefficient have been approximated using the available database. Creep rate and fission gas diffusivity of high zirconium fuel is lowered by an order of magnitude with respect to the reference low zirconium fuel based on limited database and in order to match experimental observations. The new code is benchmarked against the AFC-1F fuel assembly post irradiation examination results. Satisfactory match was obtained for fission gas release and swelling behaviour. Finally, the study considers a comparison of fuel behaviour between high zirconium content minor actinide bearing fuel and typical U-15Pu-6Zr fuel pins with 75% smear density. The new fuel has much higher fissile content, allowing for operating at lower neutron flux level compared to fuel with lower fissile density. This feature allows the designer to reach a much higher burnup before reaching the cladding dose limit. On the other

  19. Metal clusters on supported argon layers; Metallcluster auf dielektrischen Substraten

    Energy Technology Data Exchange (ETDEWEB)

    Faber, Bernhard

    2011-10-21

    The deposition of small sodium clusters on supported Ar(001)-surfaces is simulated. Theoretical description is achieved by a hierarchical model consisting of time-dependent DFT and molecular dynamics. The valence electrons of the sodium atoms are considered by Kohn-Sham-Scheme with self interaction correction. The interaction of argon atoms and sodium ions is described by atom-atom potentials whereas the coupling to the QM electrons is done by local pseudo-potentials. A decisive part of the model is the dynamical polarizability of the rare-gas atoms. The optional metal support is considered by the method of image charges. The influence of the forces caused by image charges and the influence of the number of argon monolayers on structure, optical response and deposition dynamics of Na{sub 6} and Na{sub 8} is investigated. There is very little influence on cluster structure and only a small shift of the cluster perpendicular to the surface. Concerning optical response the position of the Mie plasmon peak stays robust whereas the details of spectral fragmentation react very sensitively to changes. The forces caused by image charges of the metal support play only a little role with the dynamics of deposition while the thickness of the argon surface strongly influences the dissipation. (orig.)

  20. Spectroscopic determination of fundamental parameters of small angular diameter galactic open clusters

    Science.gov (United States)

    Ahumada, A. V.; Claria, J. J.; Bica, E.; Parisi, M. C.; Torres, M. C.; Pavani, D. B.

    We present integrated spectra obtained at CASLEO (Argentina) for 9 galactic open clusters of small angular diameter. Two of them (BH 55 and Rup 159) have not been the target of previous research. The flux-calibrated spectra cover the spectral range approx. 3600-6900 A. Using the equivalent widths (EWs) of the Balmer lines and comparing the cluster spectra with template spectra, we determined E(B-V) colour excesses and ages for the present cluster sample. The parameters obtained for 6 of the clusters show good agreement with previous determinations based mainly on photometric methods. This is not the case, however, for BH 90, a scarcely reddened cluster, for which Moffat and Vogt (1975, Astron. and Astroph. SS, 20, 125) derived E(B-V) = 0.51. We explain and justify the strong discrepancy found for this object. According to the present analysis, 3 clusters are very young (Bo 14, Tr 15 and Tr 27), 2 are moderately young (NGC 6268 and BH 205), 3 are Hyades-like clusters (Rup 164, BH 90 and BH 55) and only one is an intermediate-age cluster (Rup 159).

  1. Non-LTE line-blanketed model atmospheres of hot stars. 2: Hot, metal-rich white dwarfs

    Science.gov (United States)

    Lanz, T.; Hubeny, I.

    1995-01-01

    We present several model atmospheres for a typical hot metal-rich DA white dwarf, T(sub eff) = 60,000 K, log g = 7.5. We consider pure hydrogen models, as well as models with various abundances of two typical 'trace' elements-carbon and iron. We calculte a number of Local Thermodynamic Equilibrium (LTE) and non-LTE models, taking into account the effect of numerous lines of these elements on the atmospheric structure. We demostrate that while the non-LTE effects are notvery significant for pure hydrogen models, except for describing correctly the central emission in H-alpha they are essential for predicting correctly the ionization balance of metals, such as carbon and iron. Previously reported discrepancies in LTE abundances determinations using C III and C IV lines are easily explained by non-LTE effects. We show that if the iron abundance is larger than 10(exp -5), the iron line opacity has to be considered not only for the spectrum synthesis, but also in the model construction itself. For such metal abundances, non-LTE metal line-blanketed models are needed for detailed abundance studies of hot, metal-rich white dwarfs. We also discuss the predicted Extreme Ultraviolet (EUV) spectrum and show that it is very sensitive to metal abundances, as well as to non-LTE effects.

  2. Metal nitride cluster as a template to tune the electronic and magnetic properties of rare-earth metal containing endohedral fullerenes

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Yang

    2013-10-16

    Rare-earth metal containing endohedral fullerenes have attracted much attention due to the feasibility of encaging metal atom, atoms or cluster inside of carbon cages. By switching the metal atom or cluster entrapped inside of the carbon cage the physical and chemical properties of the fullerene compounds can be tuned. The understanding of magnetic and electrochemical properties of endohedral fullerenes plays an essential role in fundamental scientific researches and potential applications in materials science. In this thesis, synthesizing novel rare-earth metal containing endohedral fullerene structures, studying the properties of these isolated endohedral fullerenes and the strategies of tuning the electronic and magnetic properties of endohedral fullerenes were introduced. The DC-arc discharging synthesis of different lanthanide metal-based (Ho, Ce and Pr) mixed metal nitride clusterfullerenes was achieved. Those rare-earth metal containing endohedral fullerenes were isolated by multi-step HPLC. The isolated samples were characterized by spectroscopic techniques included UV-vis-NIR, FTIR, Raman, LDI-TOF mass spectrometry, NMR and electrochemistry. The Ho-based mixed metal nitride clusterfullerenes Ho{sub x}M{sub 3-x}N rate at C{sub 80} (M= Sc, Lu, Y; x=1, 2) were synthesized by ''reactive gas atmosphere'' method or ''selective organic solid'' route. The isolated samples were characterized by LDI-TOF mass spectrometry, UV-vis-NIR, FTIR, Raman and NMR spectroscopy. The {sup 13}C NMR spectroscopic studies demonstrated exceptional NMR behaviors that resulted from switching the second metal inside of the mixed metal nitride cluster Ho{sub x}M{sub 3-x}N from Sc to Lu and further to Y. The LnSc{sub 2}N rate at C{sub 80} (Ln= Ce, Pr, Nd, Tb, Dy, Ho, Lu) MMNCFs were characterized by {sup 13}C and {sup 45}Sc NMR study respectively. According to Bleaney's theory and Reilley method, the separation of δ{sup PC} and δ{sup con

  3. Robust Optical Richness Estimation with Reduced Scatter

    Energy Technology Data Exchange (ETDEWEB)

    Rykoff, E.S.; /LBL, Berkeley; Koester, B.P.; /Chicago U. /Chicago U., KICP; Rozo, E.; /Chicago U. /Chicago U., KICP; Annis, J.; /Fermilab; Evrard, A.E.; /Michigan U. /Michigan U., MCTP; Hansen, S.M.; /Lick Observ.; Hao, J.; /Fermilab; Johnston, D.E.; /Fermilab; McKay, T.A.; /Michigan U. /Michigan U., MCTP; Wechsler, R.H.; /KIPAC, Menlo Park /SLAC

    2012-06-07

    Reducing the scatter between cluster mass and optical richness is a key goal for cluster cosmology from photometric catalogs. We consider various modifications to the red-sequence matched filter richness estimator of Rozo et al. (2009b), and evaluate their impact on the scatter in X-ray luminosity at fixed richness. Most significantly, we find that deeper luminosity cuts can reduce the recovered scatter, finding that {sigma}{sub ln L{sub X}|{lambda}} = 0.63 {+-} 0.02 for clusters with M{sub 500c} {approx}> 1.6 x 10{sup 14} h{sub 70}{sup -1} M{sub {circle_dot}}. The corresponding scatter in mass at fixed richness is {sigma}{sub ln M|{lambda}} {approx} 0.2-0.3 depending on the richness, comparable to that for total X-ray luminosity. We find that including blue galaxies in the richness estimate increases the scatter, as does weighting galaxies by their optical luminosity. We further demonstrate that our richness estimator is very robust. Specifically, the filter employed when estimating richness can be calibrated directly from the data, without requiring a-priori calibrations of the red-sequence. We also demonstrate that the recovered richness is robust to up to 50% uncertainties in the galaxy background, as well as to the choice of photometric filter employed, so long as the filters span the 4000 {angstrom} break of red-sequence galaxies. Consequently, our richness estimator can be used to compare richness estimates of different clusters, even if they do not share the same photometric data. Appendix A includes 'easy-bake' instructions for implementing our optimal richness estimator, and we are releasing an implementation of the code that works with SDSS data, as well as an augmented maxBCG catalog with the {lambda} richness measured for each cluster.

  4. Scattering of ultrashort electromagnetic pulses on metal clusters

    International Nuclear Information System (INIS)

    Astapenko, V. A.; Sakhno, S. V.

    2016-01-01

    We have calculated and analyzed the probability of ultrashort electromagnetic pulse (USP) scattering on small metal clusters in the frequency range of plasmon resonances during the field action. The main attention is devoted to dependence of the probability of scattering on the pulse duration for various detunings of the USP carrier frequency from the plasmon resonance frequency. Peculiarities of the USP scattering from plasmon resonances with various figures of merit are revealed.

  5. Scattering of ultrashort electromagnetic pulses on metal clusters

    Energy Technology Data Exchange (ETDEWEB)

    Astapenko, V. A., E-mail: astval@mail.ru; Sakhno, S. V. [Moscow Institute of Physics and Technology (State University) (Russian Federation)

    2016-12-15

    We have calculated and analyzed the probability of ultrashort electromagnetic pulse (USP) scattering on small metal clusters in the frequency range of plasmon resonances during the field action. The main attention is devoted to dependence of the probability of scattering on the pulse duration for various detunings of the USP carrier frequency from the plasmon resonance frequency. Peculiarities of the USP scattering from plasmon resonances with various figures of merit are revealed.

  6. Contributions of Cu-rich clusters, dislocation loops and nanovoids to the irradiation-induced hardening of Cu-bearing low-Ni reactor pressure vessel steels

    Energy Technology Data Exchange (ETDEWEB)

    Bergner, F., E-mail: f.bergner@hzdr.de [Helmholtz-Zentrum Dresden-Rossendorf, Bautzner Landstr. 400, 01328 Dresden (Germany); Gillemot, F. [Centre for Energy Research of the Hungarian Academy of Sciences, 29-33 Konkoly-Thege street, 1121 Budapest XII (Hungary); Hernández-Mayoral, M.; Serrano, M. [Division of Materials, CIEMAT, Avenida Complutense 22, 28040 Madrid (Spain); Török, G. [Wigner Research Center for Physics of the Hungarian Academy of Sciences, 29-33 Konkoly-Thege street, 1121 Budapest XII (Hungary); Ulbricht, A.; Altstadt, E. [Helmholtz-Zentrum Dresden-Rossendorf, Bautzner Landstr. 400, 01328 Dresden (Germany)

    2015-06-15

    Highlights: • TEM and SANS were applied to estimate mean size and number density of loops, nanovoids and Cu-rich clusters. • A three-feature dispersed-barrier hardening model was applied to estimate the yield stress increase. • The values and errors of the dimensionless obstacle strength were estimated in a consistent way. • Nanovoids are stronger obstacles for dislocation glide than dislocation loops, loops are stronger than Cu-rich clusters. • For reactor-relevant conditions, Cu-rich clusters contribute most to hardening due to their high number density. - Abstract: Dislocation loops, nanovoids and Cu-rich clusters (CRPs) are known to represent obstacles for dislocation glide in neutron-irradiated reactor pressure vessel (RPV) steels, but a consistent experimental determination of the respective obstacle strengths is still missing. A set of Cu-bearing low-Ni RPV steels and model alloys was characterized by means of SANS and TEM in order to specify mean size and number density of loops, nanovoids and CRPs. The obstacle strengths of these families were estimated by solving an over-determined set of linear equations. We have found that nanovoids are stronger than loops and loops are stronger than CRPs. Nevertheless, CRPs contribute most to irradiation hardening because of their high number density. Nanovoids were only observed for neutron fluences beyond typical end-of-life conditions of RPVs. The estimates of the obstacle strength are critically compared with reported literature data.

  7. Subsampled open-reference clustering creates consistent, comprehensive OTU definitions and scales to billions of sequences.

    Science.gov (United States)

    Rideout, Jai Ram; He, Yan; Navas-Molina, Jose A; Walters, William A; Ursell, Luke K; Gibbons, Sean M; Chase, John; McDonald, Daniel; Gonzalez, Antonio; Robbins-Pianka, Adam; Clemente, Jose C; Gilbert, Jack A; Huse, Susan M; Zhou, Hong-Wei; Knight, Rob; Caporaso, J Gregory

    2014-01-01

    We present a performance-optimized algorithm, subsampled open-reference OTU picking, for assigning marker gene (e.g., 16S rRNA) sequences generated on next-generation sequencing platforms to operational taxonomic units (OTUs) for microbial community analysis. This algorithm provides benefits over de novo OTU picking (clustering can be performed largely in parallel, reducing runtime) and closed-reference OTU picking (all reads are clustered, not only those that match a reference database sequence with high similarity). Because more of our algorithm can be run in parallel relative to "classic" open-reference OTU picking, it makes open-reference OTU picking tractable on massive amplicon sequence data sets (though on smaller data sets, "classic" open-reference OTU clustering is often faster). We illustrate that here by applying it to the first 15,000 samples sequenced for the Earth Microbiome Project (1.3 billion V4 16S rRNA amplicons). To the best of our knowledge, this is the largest OTU picking run ever performed, and we estimate that our new algorithm runs in less than 1/5 the time than would be required of "classic" open reference OTU picking. We show that subsampled open-reference OTU picking yields results that are highly correlated with those generated by "classic" open-reference OTU picking through comparisons on three well-studied datasets. An implementation of this algorithm is provided in the popular QIIME software package, which uses uclust for read clustering. All analyses were performed using QIIME's uclust wrappers, though we provide details (aided by the open-source code in our GitHub repository) that will allow implementation of subsampled open-reference OTU picking independently of QIIME (e.g., in a compiled programming language, where runtimes should be further reduced). Our analyses should generalize to other implementations of these OTU picking algorithms. Finally, we present a comparison of parameter settings in QIIME's OTU picking workflows and

  8. Subsampled open-reference clustering creates consistent, comprehensive OTU definitions and scales to billions of sequences

    Directory of Open Access Journals (Sweden)

    Jai Ram Rideout

    2014-08-01

    Full Text Available We present a performance-optimized algorithm, subsampled open-reference OTU picking, for assigning marker gene (e.g., 16S rRNA sequences generated on next-generation sequencing platforms to operational taxonomic units (OTUs for microbial community analysis. This algorithm provides benefits over de novo OTU picking (clustering can be performed largely in parallel, reducing runtime and closed-reference OTU picking (all reads are clustered, not only those that match a reference database sequence with high similarity. Because more of our algorithm can be run in parallel relative to “classic” open-reference OTU picking, it makes open-reference OTU picking tractable on massive amplicon sequence data sets (though on smaller data sets, “classic” open-reference OTU clustering is often faster. We illustrate that here by applying it to the first 15,000 samples sequenced for the Earth Microbiome Project (1.3 billion V4 16S rRNA amplicons. To the best of our knowledge, this is the largest OTU picking run ever performed, and we estimate that our new algorithm runs in less than 1/5 the time than would be required of “classic” open reference OTU picking. We show that subsampled open-reference OTU picking yields results that are highly correlated with those generated by “classic” open-reference OTU picking through comparisons on three well-studied datasets. An implementation of this algorithm is provided in the popular QIIME software package, which uses uclust for read clustering. All analyses were performed using QIIME’s uclust wrappers, though we provide details (aided by the open-source code in our GitHub repository that will allow implementation of subsampled open-reference OTU picking independently of QIIME (e.g., in a compiled programming language, where runtimes should be further reduced. Our analyses should generalize to other implementations of these OTU picking algorithms. Finally, we present a comparison of parameter settings in

  9. WIYN Open Cluster Study. XXXVI. Spectroscopic Binary Orbits in NGC 188

    Science.gov (United States)

    2009-04-01

    2000; Pleiades , Mermilliod et al. 1992; M67, Mathieu et al. 1990). Today, the advent of multi-object spectrographs permits surveys of larger stellar...open clusters (e.g., M67, Mathieu et al. (1990); Praesepe, Mermilliod et al. (1994); Pleiades , Bouvier et al. (1997); Hyades, Patience et al. (1998

  10. NGC 6273: Towards Defining A New Class of Galactic Globular Clusters?

    Science.gov (United States)

    Johnson, Christian I.; Rich, Robert Michael; Pilachowski, Catherine A.; Caldwell, Nelson; Mateo, Mario L.; Ira Bailey, John; Crane, Jeffrey D.

    2016-01-01

    A growing number of observations have found that several Galactic globular clusters exhibit abundance dispersions beyond the well-known light element (anti-)correlations. These clusters tend to be very massive, have >0.1 dex intrinsic metallicity dispersions, have complex sub-giant branch morphologies, and have correlated [Fe/H] and s-process element enhancements. Interestingly, nearly all of these clusters discovered so far have [Fe/H]~-1.7. In this context, we have examined the chemical composition of 18 red giant branch (RGB) stars in the massive, metal-poor Galactic bulge globular cluster NGC 6273 using high signal-to-noise, high resolution (R~27,000) spectra obtained with the Michigan/Magellan Fiber System (M2FS) and MSpec spectrograph mounted on the Magellan-Clay 6.5m telescope at Las Campanas Observatory. We find that the cluster exhibits a metallicity range from [Fe/H]=-1.80 to -1.30 and is composed of two dominant populations separated in [Fe/H] and [La/Fe] abundance. The increase in [La/Eu] as a function of [La/H] suggests that the increase in [La/Fe] with [Fe/H] is due to almost pure s-process enrichment. The most metal-rich star in our sample is not strongly La-enhanced, but is α-poor and may belong to a third "anomalous" stellar population. The two dominant populations exhibit the same [Na/Fe]-[Al/Fe] correlation found in other "normal" globular clusters. Therefore, NGC 6273 joins ω Centauri, M 22, M 2, and NGC 5286 as a possible new class of Galactic globular clusters.

  11. New Cepheid variables in the young open clusters Berkeley 51 and Berkeley 55

    Science.gov (United States)

    Lohr, M. E.; Negueruela, I.; Tabernero, H. M.; Clark, J. S.; Lewis, F.; Roche, P.

    2018-05-01

    As part of a wider investigation of evolved massive stars in Galactic open clusters, we have spectroscopically identified three candidate classical Cepheids in the little-studied clusters Berkeley 51, Berkeley 55 and NGC 6603. Using new multi-epoch photometry, we confirm that Be 51 #162 and Be 55 #107 are bona fide Cepheids, with pulsation periods of 9.83±0.01 d and 5.850±0.005 d respectively, while NGC 6603 star W2249 does not show significant photometric variability. Using the period-luminosity relationship for Cepheid variables, we determine a distance to Be 51 of 5.3^{+1.0}_{-0.8} kpc and an age of 44^{+9}_{-8} Myr, placing it in a sparsely-attested region of the Perseus arm. For Be 55, we find a distance of 2.2±0.3 kpc and age of 63^{+12}_{-11} Myr, locating the cluster in the Local arm. Taken together with our recent discovery of a long-period Cepheid in the starburst cluster VdBH222, these represent an important increase in the number of young, massive Cepheids known in Galactic open clusters. We also consider new Gaia (data release 2) parallaxes and proper motions for members of Be 51 and Be 55; the uncertainties on the parallaxes do not allow us to refine our distance estimates to these clusters, but the well-constrained proper motion measurements furnish further confirmation of cluster membership. However, future final Gaia parallaxes for such objects should provide valuable independent distance measurements, improving the calibration of the period-luminosity relationship, with implications for the distance ladder out to cosmological scales.

  12. High-resolution Spectroscopic Observations of Single Red Giants in Three Open Clusters: NGC 2360, NGC 3680, and NGC 5822

    Science.gov (United States)

    Peña Suárez, V. J.; Sales Silva, J. V.; Katime Santrich, O. J.; Drake, N. A.; Pereira, C. B.

    2018-02-01

    Single stars in open clusters with known distances are important targets in constraining the nucleosynthesis process since their ages and luminosities are also known. In this work, we analyze a sample of 29 single red giants of the open clusters NGC 2360, NGC 3680, and NGC 5822 using high-resolution spectroscopy. We obtained atmospheric parameters, abundances of the elements C, N, O, Na, Mg, Al, Ca, Si, Ti, Ni, Cr, Y, Zr, La, Ce, and Nd, as well as radial and rotational velocities. We employed the local thermodynamic equilibrium atmospheric models of Kurucz and the spectral analysis code MOOG. Rotational velocities and light-element abundances were derived using spectral synthesis. Based on our analysis of the single red giants in these three open clusters, we could compare, for the first time, their abundance pattern with that of the binary stars of the same clusters previously studied. Our results show that the abundances of both single and binary stars of the open clusters NGC 2360, NGC 3680, and NGC 5822 do not have significant differences. For the elements created by the s-process, we observed that the open clusters NGC 2360, NGC 3680, and NGC 5822 also follow the trend already raised in the literature that young clusters have higher s-process element abundances than older clusters. Finally, we observed that the three clusters of our sample exhibit a trend in the [Y/Mg]-age relation, which may indicate the ability of the [Y/Mg] ratio to be used as a clock for the giants. Based on the observations made with the 2.2 m telescope at the European Southern Observatory (La Silla, Chile) under an agreement with Observatório Nacional and under an agreement between Observatório Nacional and Max-Planck Institute für Astronomie.

  13. Heavy metals pollution influence the community structure of Cyanobacteria in nutrient rich tropical estuary

    Digital Repository Service at National Institute of Oceanography (India)

    Anas, A.; Jasmin, C.; Sheeba V.A.; Gireeshkumar, T.R; Nair, S.

    , Mn, Fe, Ni, Cu and Zn) on community structure of cyanobacteria in a nutrient rich tropical estuary, Cochin Estuary (CE), across the southwest coast of India. Dissolved heavy metals were higher in CE during dry season, with Zn as major pollutant...

  14. The astrophysical behavior of open clusters along the Milky Way Galaxy

    Directory of Open Access Journals (Sweden)

    A.L. Tadross

    2014-06-01

    Full Text Available The main aim of this paper is to study the astrophysical behaviour of open clusters’ properties along the Milky Way Galaxy. Near-IR JHKS (2MASS photometry has been used for getting a homogeneous Catalog of 263 open clusters’ parameters, which are randomly selected and studied by the author through the last five years; most of them were studied for the first time. The correlations between the astrophysical parameters of these clusters have been achieved by morphological way and compared with the most recent works.

  15. Electronic properties of large metal clusters in Jellium and pseudo-jellium models

    International Nuclear Information System (INIS)

    Catara, F.; Van Giai, N.; Chomaz, P.

    1994-08-01

    The energy-density functional approach and jellium-like models are used to examine two important electronic properties of metal (Li, Na, K) clusters: their shell and supershell structures, and the behaviour of plasmon energies with increasing cluster sizes. A comparative study is made between predictions of the usual jellium model and those of the pseudo-jellium model where pseudo-Hamiltonians are used. (authors) 10 figs., 5 tabs., 16 refs

  16. A multimembership catalogue for 1876 open clusters using UCAC4 data

    Science.gov (United States)

    Sampedro, L.; Dias, W. S.; Alfaro, E. J.; Monteiro, H.; Molino, A.

    2017-10-01

    The main objective of this work is to determine the cluster members of 1876 open clusters, using positions and proper motions of the astrometric fourth United States Naval Observatory (USNO) CCD Astrograph Catalog (UCAC4). For this purpose, we apply three different methods, all based on a Bayesian approach, but with different formulations: a purely parametric method, another completely non-parametric algorithm and a third, recently developed by Sampedro & Alfaro, using both formulations at different steps of the whole process. The first and second statistical moments of the members' phase-space subspace, obtained after applying the three methods, are compared for every cluster. Although, on average, the three methods yield similar results, there are also specific differences between them, as well as for some particular clusters. The comparison with other published catalogues shows good agreement. We have also estimated, for the first time, the mean proper motion for a sample of 18 clusters. The results are organized in a single catalogue formed by two main files, one with the most relevant information for each cluster, partially including that in UCAC4, and the other showing the individual membership probabilities for each star in the cluster area. The final catalogue, with an interface design that enables an easy interaction with the user, is available in electronic format at the Stellar Systems Group (SSG-IAA) web site (http://ssg.iaa.es/en/content/sampedro-cluster-catalog).

  17. ALMA Observations of Gas-rich Galaxies in z ∼ 1.6 Galaxy Clusters: Evidence for Higher Gas Fractions in High-density Environments

    Energy Technology Data Exchange (ETDEWEB)

    Noble, A. G.; McDonald, M. [Kavli Institute for Astrophysics and Space Research, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, MA 02139 (United States); Muzzin, A. [Department of Physics and Astronomy, York University, 4700 Keele Street, Toronto, ON MJ3 1P3 (Canada); Nantais, J. [Departamento de Ciencias Físicas, Universidad Andres Bello, Fernandez Concha 700, Las Condes 7591538, Santiago, Región Metropolitana (Chile); Rudnick, G. [The University of Kansas, Department of Physics and Astronomy, 1251 Wescoe Hall Drive, Lawrence, KS 66045 (United States); Van Kampen, E.; Manilla-Robles, A. [European Southern Observatory, Karl-Schwarzschild-Strasse 2, D-85748 Garching bei München (Germany); Webb, T. M. A.; Delahaye, A. [Department of Physics, McGill University, 3600 rue University, Montréal, QC H3A 2T8 (Canada); Wilson, G.; DeGroot, A.; Foltz, R. [Department of Physics and Astronomy, University of California, Riverside, CA 92521 (United States); Yee, H. K. C. [Department of Astronomy and Astrophysics, University of Toronto, 50 St. George Street, Toronto, ON M5S 3H4 (Canada); Boone, K.; Hayden, B.; Perlmutter, S. [Department of Physics, University of California Berkeley, 366 LeConte Hall, MC 7300, Berkeley, CA 94720-7300 (United States); Cooper, M. C. [Department of Physics and Astronomy, University of California, Irvine, 4129 Frederick Reines Hall, Irvine, CA 92697 (United States); Demarco, R. [Departamento de Astronomía, Universidad de Concepción, Casilla 160-C, Concepción, Región del Biobío (Chile); Lidman, C., E-mail: noble@mit.edu [Australian Astronomical Observatory, 105 Delhi Road, North Ryde, NSW 2113 (Australia)

    2017-06-20

    We present ALMA CO (2–1) detections in 11 gas-rich cluster galaxies at z ∼ 1.6, constituting the largest sample of molecular gas measurements in z > 1.5 clusters to date. The observations span three galaxy clusters, derived from the Spitzer Adaptation of the Red-sequence Cluster Survey. We augment the >5 σ detections of the CO (2–1) fluxes with multi-band photometry, yielding stellar masses and infrared-derived star formation rates, to place some of the first constraints on molecular gas properties in z ∼ 1.6 cluster environments. We measure sizable gas reservoirs of 0.5–2 × 10{sup 11} M {sub ☉} in these objects, with high gas fractions ( f {sub gas}) and long depletion timescales ( τ ), averaging 62% and 1.4 Gyr, respectively. We compare our cluster galaxies to the scaling relations of the coeval field, in the context of how gas fractions and depletion timescales vary with respect to the star-forming main sequence. We find that our cluster galaxies lie systematically off the field scaling relations at z = 1.6 toward enhanced gas fractions, at a level of ∼4 σ , but have consistent depletion timescales. Exploiting CO detections in lower-redshift clusters from the literature, we investigate the evolution of the gas fraction in cluster galaxies, finding it to mimic the strong rise with redshift in the field. We emphasize the utility of detecting abundant gas-rich galaxies in high-redshift clusters, deeming them as crucial laboratories for future statistical studies.

  18. Clustered atom-replaced structure in single-crystal-like metal oxide

    Science.gov (United States)

    Araki, Takeshi; Hayashi, Mariko; Ishii, Hirotaka; Yokoe, Daisaku; Yoshida, Ryuji; Kato, Takeharu; Nishijima, Gen; Matsumoto, Akiyoshi

    2018-06-01

    By means of metal organic deposition using trifluoroacetates (TFA-MOD), we replaced and localized two or more atoms in a single-crystalline structure having almost perfect orientation. Thus, we created a new functional structure, namely, clustered atom-replaced structure (CARS), having single-crystal-like metal oxide. We replaced metals in the oxide with Sm and Lu and localized them. Energy dispersive x-ray spectroscopy results, where the Sm signal increases with the Lu signal in the single-crystalline structure, confirm evidence of CARS. We also form other CARS with three additional metals, including Pr. The valence number of Pr might change from 3+ to approximately 4+, thereby reducing the Pr–Ba distance. We directly observed the structure by a high-angle annular dark-field image, which provided further evidence of CARS. The key to establishing CARS is an equilibrium chemical reaction and a combination of additional larger and smaller unit cells to matrix cells. We made a new functional metal oxide with CARS and expect to realize CARS in other metal oxide structures in the future by using the above-mentioned process.

  19. Damage clustering in metals: Importance, advances and challenges

    International Nuclear Information System (INIS)

    Nordlund, K.; Sand, A.E.; Granberg, F.; Levo, E.; Djurabekova, F.

    2016-01-01

    The damage produced in metals has traditionally been primarily characterized in terms of the total damage production, which typically is first estimated with the dpa number. As discussed in previous meetings of this CRP, the dpa is not actually very well suited for typical dense metals, since the number it gives is typically about 3 times larger than the number of actual defects produced, and 30 times smaller than the actual number of defects produced. Hence we developed the improved arc-dpa and rpa standards, that give in a simple analytical form a defect number that does correspond well to MD and experimental data. Section 2 summarizes the development of the arc-dpa and rpa standards. In sections 3 and 4 we discuss the role of damage clustering in damage production

  20. Sulphur in the metal poor globular cluster NGC 6397

    Science.gov (United States)

    Koch, A.; Caffau, E.

    2011-10-01

    Sulphur (S) is a non-refractory α-element that is not locked into dust grains in the interstellar medium. Thus no correction to the measured, interstellar sulphur abundance is needed and it can be readily compared to the S content in stellar photospheres. Here we present the first measurement of sulphur in the metal poor globular cluster (GC) NGC 6397, as detected in a MIKE/Magellan high signal-to-noise, high-resolution spectrum of one red giant star. While abundance ratios of sulphur are available for a larger number of Galactic stars down to an [Fe/H] of ~ -3.5 dex, no measurements in globular clusters more metal poor than -1.5 dex have been reported so far. We find aNLTE, 3-D abundance ratio of [S/Fe] = +0.52 ± 0.20 (stat.) ± 0.08 (sys.), based on theS I, Multiplet 1 line at 9212.8 Å. This value is consistent with a Galactic halo plateau as typical of other α-elements in GCs and field stars, but we cannot rule out its membership with a second branch of increasing [S/Fe] with decreasing [Fe/H], claimed in the literature, which leads to a large scatter at metallicities around - 2 dex. The [S/Mg] and [S/Ca] ratios in this star are compatible with a Solar value to within the (large) uncertainties. Despite the very large scatter in these ratios across Galactic stars between literature samples, this indicates that sulphur traces the chemical imprints of the other α-elements in metal poor GCs. Combined with its moderate sodium abundance ([S/Na]NLTE = 0.48), the [S/Fe] ratio in this GC extends a global, positive S-Na correlation that is not seen in field stars and might indicate that proton-capture reactions contributed to the production of sulphur in the (metal poor) early GC environments. This paper includes data gathered with the 6.5 m Magellan Telescopes located at Las Campanas Observatory, Chile.

  1. Structure Determination of Anionic Metal Clusters via Infrared Resonance Enhanced Multiple Photon Electron Detachment Spectroscopy

    NARCIS (Netherlands)

    Haertelt, M.; Lapoutre, V. J. F.; Bakker, J. M.; Redlich, B.; Harding, D. J.; Fielicke, A.; Meijer, G.

    2011-01-01

    We report vibrational spectra of anionic metal clusters, measured via electron detachment following resonant absorption of multiple infrared photons. To facilitate the sequential absorption of the required large number of photons, the cluster beam interacts with the infrared radiation inside the

  2. NASICON Open Framework Structured Transition Metal Oxides for Lithium Batteries

    OpenAIRE

    Begam, K.M.; Michael, M.S.; Prabaharan, S.R.S.

    2010-01-01

    We identified a group of NASICON open framework structured polyanion materials and examined the materials for rechargeable lithium battery application. We found that the open framework structure of these materials facilitated easy insertion/extraction of lithium into/from their structure. We synthesized the materials in lithium-rich [Li2M2(MoO4)3] and lithium-free [LixM2(MoO4)3] (M= Ni, Co) phases, for the first time, by means of a low temperature soft-combustion technique. The soft-combustio...

  3. Isochrone Fittings for the Open Star Clusters NGC 3680 and Melotte 66

    Science.gov (United States)

    Guillemaud, Nikolas; Frinchaboy, P. M.; Thompson, B. A.

    2013-01-01

    I will be displaying the results from isochrone fittings on two open star clusters. The stellar evolution models used to generate the isochrones are from Dartmouth (Dotter et al. 2007) and Padova (Mango et al. 2008). Both of the models were applied to two star clusters: NGC 3680 and Melotte 66. The analysis is performed by utilizing infrared observations from the CPAPIR instrument; which is operated in conjunction with CTIO’s 1.5m telescope. This research was made possible by the NSF’s REU grant; award number 0851558.

  4. Four-color and Hβ photometry for open clusters I: NGC 2516

    International Nuclear Information System (INIS)

    Snowden, M.S.

    1975-01-01

    Extensive uvby and Hβ photometry was obtained for stars in the region of the open cluster NGC 2516. A photometric analysis revealed variable reddening and a mean reddening of E(b - y) = 0.088 m. In addition to determining a new age of 137 x 10 6 years and a new adopted distance modulus of 8.01 m, several possible new variable stars were discovered, one of which may be an eclipsing Ap star. From the photometry of the Si-lambda4200 stars in the cluster it appears the absolute magnitudes and masses for this type of star are not as restricted as previously thought

  5. The HectoMAP Cluster Survey. I. redMaPPer Clusters

    Science.gov (United States)

    Sohn, Jubee; Geller, Margaret J.; Rines, Kenneth J.; Hwang, Ho Seong; Utsumi, Yousuke; Diaferio, Antonaldo

    2018-04-01

    We use the dense HectoMAP redshift survey to explore the properties of 104 redMaPPer cluster candidates. The redMaPPer systems in HectoMAP cover the full range of richness and redshift (0.08 systems included in the Subaru/Hyper Suprime-Cam public data release are bona fide clusters. The median number of spectroscopic members per cluster is ∼20. We include redshifts of 3547 member candidates listed in the redMaPPer catalog whether they are cluster members or not. We evaluate the redMaPPer membership probability spectroscopically. The purity (number of real systems) in redMaPPer exceeds 90% even at the lowest richness. Three massive galaxy clusters (M ∼ 2 × 1013 M ⊙) associated with X-ray emission in the HectoMAP region are not included in the public redMaPPer catalog with λ rich > 20, because they lie outside the cuts for this catalog.

  6. Interplay of metals and bromine with dioxin-related compounds concentrated in e-waste open burning soil from Agbogbloshie in Accra, Ghana

    International Nuclear Information System (INIS)

    Fujimori, Takashi; Itai, Takaaki; Goto, Akitoshi; Asante, Kwadwo A.; Otsuka, Masanari; Takahashi, Shin; Tanabe, Shinsuke

    2016-01-01

    Open burning of electronic waste (e-waste) releases various metals and organohalogen compounds in the environment. Here we investigated the interplay of metals (Cu, Pb, Zn, Fe, Co, and Sr) and bromine (Br) in the formation of dioxin-related compounds (DRCs), including polychlorinated dibenzo-p-dioxins/furans (PCDD/Fs) and dioxin-like polychlorinated biphenyls (DL-PCBs), as well as non-regulated DRCs such as polybrominated dibenzo-p-dioxins/furans (PBDD/Fs) and their monobrominated PCDD/Fs in soils sampled from open burning e-waste sites at Agbogbloshie in Accra, Ghana. The predominant DRCs were PBDFs, PCDFs, PCDDs, and DL-PCBs. Statistical analyzes, X-ray absorption spectroscopy, and the PCDF/PCDD ratio suggested possible formation paths of PCDD/Fs and DL-PCBs by catalytic behaviors of copper chlorides (CuCl, CuCl_2, and Cu_2(OH)_3Cl) and thermal breakdown of polyvinyl chloride. Predominant formation of brominated furans may be derived from electron transfer from intermediates of PBDE to copper, Cu(II) → Cu(I). Lead chloride also contributed to generate DRCs and may become highly bioaccessible through the open burning of e-waste. The main zinc species (ZnCl_2 and ZnS) suggested a possible relationship to generate DRCs and specific zinc source such as tire burning. Cu, Pb, Zn, and Br contained in various e-wastes, wires/cables, plastics, and tires strongly influenced generation of many DRCs. - Highlights: • Extremely high DRCs were detected from an open burning soil of e-waste. • Predominant DRCs were PBDFs, PCDFs, PCDDs, and DL-PCBs. • Some metals shows good correlation to DRCs by PCA and cluster analysis. • Speciation of Cu, Pb, Zn in residual soil were successfully measured by XAFS. • Electron transfer via Cu(II) → Cu(I) can be important for DRCs formation. - Metals speciation in residual soil after open burning of e-waste may act as a catalyst for formation of dioxin-related compounds.

  7. Applications of Open Source GMAW-Based Metal 3-D Printing

    Directory of Open Access Journals (Sweden)

    Yuenyong Nilsiam

    2018-03-01

    Full Text Available The metal 3-D printing market is currently dominated by high-end applications, which make it inaccessible for small and medium enterprises, fab labs, and individual makers who are interested in the ability to prototype and additively manufacture final products in metal. Recent progress led to low-cost open-source metal 3-D printers using a gas metal arc welding (GMAW-based print head. This reduced the cost of metal 3-D printers into the range of desktop prosumer polymer 3-D printers. Consequent research established good material properties of metal 3-D printed parts with readily-available weld filler wire, reusable substrates, thermal and stress properties, toolpath planning, bead-width control, mechanical properties, and support for overhangs. These previous works showed that GMAW-based metal 3-D printing has a good adhesion between layers and is not porous inside the printed parts, but they did not proceed far enough to demonstrate applications. In this study, the utility of the GMAW approach to 3-D printing is investigated using a low-cost open-source metal 3-D printer and a converted Computer Numerical Control router machine to make useful parts over a range of applications including: fixing an existing part by adding a 3-D metal feature, creating a product using the substrate as part of the component, 3-D printing in high resolution of useful objects, near net objects, and making an integrated product using a combination of steel and polymer 3-D printing. The results show that GMAW-based 3-D printing is capable of distributed manufacturing of useful products for a wide variety of applications for sustainable development.

  8. Intrinsic alignment of redMaPPer clusters: cluster shape-matter density correlation

    Science.gov (United States)

    van Uitert, Edo; Joachimi, Benjamin

    2017-07-01

    We measure the alignment of the shapes of galaxy clusters, as traced by their satellite distributions, with the matter density field using the public redMaPPer catalogue based on Sloan Digital Sky Survey-Data Release 8 (SDSS-DR8), which contains 26 111 clusters up to z ˜ 0.6. The clusters are split into nine redshift and richness samples; in each of them, we detect a positive alignment, showing that clusters point towards density peaks. We interpret the measurements within the tidal alignment paradigm, allowing for a richness and redshift dependence. The intrinsic alignment (IA) amplitude at the pivot redshift z = 0.3 and pivot richness λ = 30 is A_IA^gen=12.6_{-1.2}^{+1.5}. We obtain tentative evidence that the signal increases towards higher richness and lower redshift. Our measurements agree well with results of maxBCG clusters and with dark-matter-only simulations. Comparing our results to the IA measurements of luminous red galaxies, we find that the IA amplitude of galaxy clusters forms a smooth extension towards higher mass. This suggests that these systems share a common alignment mechanism, which can be exploited to improve our physical understanding of IA.

  9. Amplitudes of solar-like oscillations: Constraints from red giants in open clusters observed by Kepler

    DEFF Research Database (Denmark)

    Stello, Dennis; Huber, Daniel; Kallinger, Thomas

    2011-01-01

    implies that the stellar parameters can be measured to much higher precision than what is usually achievable for single stars. This makes clusters ideal for exploring the relation between the mode amplitude of solar-like oscillations and the global stellar properties. We have analyzed data obtained......Scaling relations that link asteroseismic quantities to global stellar properties are important for gaining understanding of the intricate physics that underpins stellar pulsations. The common notion that all stars in an open cluster have essentially the same distance, age, and initial composition...... with NASA's Kepler space telescope to study solar-like oscillations in 100 red giant stars located in either of the three open clusters, NGC 6791, NGC 6819, and NGC 6811. By fitting the measured amplitudes to predictions from simple scaling relations that depend on luminosity, mass, and effective...

  10. MASSIVE+: The Growth Histories of MASSIVE Survey Galaxies from their Globular Cluster Colors

    Science.gov (United States)

    Blakeslee, John

    2017-08-01

    The MASSIVE survey is targeting the 100 most massive galaxies within 108 Mpc that are visible in the northern sky. These most massive galaxies in the present-day universe reside in a surprisingly wide variety of environments, from rich clusters to fossil groups to near isolation. We propose to use WFC3/UVIS and ACS to carry out a deep imaging study of the globular cluster populations around a selected subset of the MASSIVE targets. Though much is known about GC systems of bright galaxies in rich clusters, we know surprisingly little about the effects of environment on these systems. The MASSIVE sample provides a golden opportunity to learn about the systematics of GC systems and what they can tell us about environmental drivers on the evolution of the highest mass galaxies. The most pressing questions to be addressed include: (1) Do isolated giants have the same constant mass fraction of GCs to total halo mass as BCGs of similar luminosity? (2) Do their GC systems show the same color (metallicity) distribution, which is an outcome of the mass spectrum of gas-rich halos during hierarchical growth? (3) Do the GCs in isolated high-mass galaxies follow the same radial distribution versus metallicity as in rich environments (a test of the relative importance of growth by accretion)? (4) Do the GCs of galaxies in sparse environments follow the same mass function? Our proposed second-band imaging will enable us to secure answers to these questions and add enormously to the legacy value of existing HST imaging of the highest mass galaxies in the universe.

  11. NONLINEAR COLOR-METALLICITY RELATIONS OF GLOBULAR CLUSTERS. III. ON THE DISCREPANCY IN METALLICITY BETWEEN GLOBULAR CLUSTER SYSTEMS AND THEIR PARENT ELLIPTICAL GALAXIES

    International Nuclear Information System (INIS)

    Yoon, Suk-Jin; Lee, Sang-Yoon; Cho, Jaeil; Kim, Hak-Sub; Chung, Chul; Kim, Sooyoung; Lee, Young-Wook; Blakeslee, John P.; Peng, Eric W.; Sohn, Sangmo T.

    2011-01-01

    One of the conundrums in extragalactic astronomy is the discrepancy in observed metallicity distribution functions (MDFs) between the two prime stellar components of early-type galaxies—globular clusters (GCs) and halo field stars. This is generally taken as evidence of highly decoupled evolutionary histories between GC systems and their parent galaxies. Here we show, however, that new developments in linking the observed GC colors to their intrinsic metallicities suggest nonlinear color-to-metallicity conversions, which translate observed color distributions into strongly peaked, unimodal MDFs with broad metal-poor tails. Remarkably, the inferred GC MDFs are similar to the MDFs of resolved field stars in nearby elliptical galaxies and those produced by chemical evolution models of galaxies. The GC MDF shape, characterized by a sharp peak with a metal-poor tail, indicates a virtually continuous chemical enrichment with a relatively short timescale. The characteristic shape emerges across three orders of magnitude in the host galaxy mass, suggesting a universal process of chemical enrichment among various GC systems. Given that GCs are bluer than field stars within the same galaxy, it is plausible that the chemical enrichment processes of GCs ceased somewhat earlier than that of the field stellar population, and if so, GCs preferentially trace the major, vigorous mode of star formation events in galactic formation. We further suggest a possible systematic age difference among GC systems, in that the GC systems in more luminous galaxies are older. This is consistent with the downsizing paradigm whereby stars of brighter galaxies, on average, formed earlier than those of dimmer galaxies; this additionally supports the similar nature shared by GCs and field stars. Although the sample used in this study (the Hubble Space Telescope Advanced Camera for Surveys/Wide Field Channel, WFPC2, and WFC3 photometry for the GC systems in the Virgo galaxy cluster) confines our

  12. Combining in situ transmission electron microscopy irradiation experiments with cluster dynamics modeling to study nanoscale defect agglomeration in structural metals

    International Nuclear Information System (INIS)

    Xu Donghua; Wirth, Brian D.; Li Meimei; Kirk, Marquis A.

    2012-01-01

    We present a combinatorial approach that integrates state-of-the-art transmission electron microscopy (TEM) in situ irradiation experiments and high-performance computing techniques to study irradiation defect dynamics in metals. Here, we have studied the evolution of visible defect clusters in nanometer-thick molybdenum foils under 1 MeV krypton ion irradiation at 80 °C through both cluster dynamics modeling and in situ TEM experiments. The experimental details are reported elsewhere; we focus here on the details of model construction and comparing the model with the experiments. The model incorporates continuous production of point defects and/or small clusters, and the accompanying interactions, which include clustering, recombination and loss to the surfaces that result from the diffusion of the mobile defects. To account for the strong surface effect in thin TEM foils, the model includes one-dimensional spatial dependence along the foil depth, and explicitly treats the surfaces as black sinks. The rich amount of data (cluster number density and size distribution at a variety of foil thickness, irradiation dose and dose rate) offered by the advanced in situ experiments has allowed close comparisons with computer modeling and permitted significant validation and optimization of the model in terms of both physical model construct (damage production mode, identities of mobile defects) and parameterization (diffusivities of mobile defects). The optimized model exhibits good qualitative and quantitative agreement with the in situ TEM experiments. The combinatorial approach is expected to bring a unique opportunity for the study of radiation damage in structural materials.

  13. Butterfly Species Richness in Selected West Albertine Rift Forests

    Directory of Open Access Journals (Sweden)

    Patrice Kasangaki

    2012-01-01

    Full Text Available The butterfly species richness of 17 forests located in the western arm of the Albertine Rift in Uganda was compared using cluster analysis and principal components analysis (PCA to assess similarities among the forests. The objective was to compare the butterfly species richness of the forests. A total of 630 butterfly species were collected in 5 main families. The different species fell into 7 ecological groupings with the closed forest group having the most species and the swamp/wetland group with the fewest number of species. Three clusters were obtained. The first cluster had forests characterized by relatively high altitude and low species richness despite the big area in the case of Rwenzori and being close to the supposed Pleistocene refugium. The second cluster had forests far away from the supposed refugium except Kisangi and moderate species richness with small areas, whereas the third cluster had those forests that were more disturbed, high species richness, and low altitudinal levels with big areas.

  14. Simultaneous recovery of benzene-rich oil and metals by steam pyrolysis of metal-poly(ethylene terephthalate) composite waste.

    Science.gov (United States)

    Kumagai, Shogo; Grause, Guido; Kameda, Tomohito; Yoshioka, Toshiaki

    2014-03-18

    The possibility of simultaneous recovery of benzene and metals from the hydrolysis of poly(ethylene terephthalate) (PET)-based materials such as X-ray films, magnetic tape, and prepaid cards under a steam atmosphere at a temperature of 450 °C was evaluated. The hydrolysis resulted in metal-containing carbonaceous residue and volatile terephthalic acid (TPA). The effects of metals and additives on the recovery process were also investigated. All metals were quantitatively recovered, and silver, maghemite (γ-Fe2O3), and anatase (TiO2) were recovered without any changes in their crystal structures or compositions. In a second step, TPA was decarboxylized in the presence of calcium oxide (CaO) at 700 °C, producing benzene with an average yield of 34% and purity of 76%. Maghemite (γ-Fe2O3) incorporated in magnetic tape and prepaid cards could decarboxylate TPA. Aluminum present in the prepaid cards produced hydrogen by the reaction with steam. However, the presence of metals had no adverse influence on the recovery of benzene-rich oil in the presence of CaO. Therefore, this method can be applied to PET-based materials containing inorganic substances, which cannot be recycled effectively otherwise.

  15. OpenSubspace

    DEFF Research Database (Denmark)

    Müller, Emmanuel; Assent, Ira; Günnemann, Stephan

    2009-01-01

    Subspace clustering and projected clustering are recent research areas for clustering in high dimensional spaces. As the field is rather young, there is a lack of comparative studies on the advantages and disadvantages of the different algorithms. Part of the underlying problem is the lack...... of available open source implementations that could be used by researchers to understand, compare, and extend subspace and projected clustering algorithms. In this paper, we discuss the requirements for open source evaluation software. We propose OpenSubspace, an open source framework that meets...... these requirements. OpenSubspace integrates state-of-the-art performance measures and visualization techniques to foster research in subspace and projected clustering....

  16. New experimental investigation of cluster structures in 10 Be and 16 C neutron-rich nuclei

    Science.gov (United States)

    Dell'Aquila, L.; Acosta, D.; Auditore, L.; Cardella, G.; De Filippo, E.; De Luca, S.; Francalanza, L.; Gnoffo, B.; Lanzalone, G.; Lombardo, I.; Martorana, N. S.; Norella, S.; Pagano, A.; Pagano, E. V.; Papa, M.; Pirrone, S.; Politi, G.; Quattrocchi, L.; Rizzo, F.; Russotto, P.; Trifirò, A.; Trimarchi, M.; Verde, G.; Vigilante, M.

    2017-11-01

    The existence of cluster structures in ^{10} Be and ^{16} C neutron-rich isotopes is investigated via projectile break-up reactions induced on polyethylene (CH _2 target. We used a fragmentation beam constituted by 55MeV/u ^{10} Be and 49MeV/u ^{16} C beams provided by the FRIBs facility at INFN-LNS. Invariant mass spectra of 4{He}+ 6 He and 6{He} + ^{10} Be breakup fragments are reconstructed by means of the CHIMERA 4π detector to investigate the presence of excited states of projectile nuclei characterized by cluster structure. In the first case, we suggest the presence of a new state in ^{10} Be at 13.5MeV. A non-vanishing yield corresponding to 20.6MeV excitation energy of ^{16} C was observed in the 6{He} + ^{10} Be cluster decay channel. To improve the results of the present analysis, a new experiment has been performed recently, taking advantage of the coupling of CHIMERA and FARCOS. In the paper we describe the data reduction process of the new experiment together with preliminary results.

  17. BV CCD photometry of the old open cluster NGC 2243

    International Nuclear Information System (INIS)

    Bergbusch, P.A.; Vandenberg, D.A.; Infante, L.

    1991-01-01

    The photometry of NGC 2243 is presented, which reaches approximately 4 mag below the turnoff point calibrated independently of studies of the cluster. The color-magnitude diagram (CMD) and luminosity function (LF) are calibrated by utilizing stars from the lists of Landolt and Graham. A strong binary sequence is noted in the CMD which contributes approximately 30 percent of the stars, a gap is observed in the turnoff region, and a clump of HB stars is located. The CMD data are compared to those for the cluster 47 Tuc and are found to match well, although a slightly higher metal abundance accounts for the redder giant branch of the NGC 2243. The distance modulus and the cluster age are calculated, and the Fe/H = -0.47, O/Fe = +0.23 isochrones are the only isochrones that reproduce the location of the giant branch. A flat mass spectrum characterizes the LF, and a small gap is found where V is 16.1. Convective overshooting in the cores of moderate mass stars is theorized as the cause of the gap, and other models of the structure are shown to provide inadequate descriptions. 41 refs

  18. Does the Lagoa do Peixe sandbar opening influence the macrophyte richness and composition in Southern Brazil wetlands?

    Directory of Open Access Journals (Sweden)

    Ana Silvia Rolon

    2013-03-01

    Full Text Available The Lagoa do Peixe has its connection with the sea artificially opened every year at the end of winter. However, this management has been carried out without the evaluation of the impact of this opening in the aquatic biodiversity. This information is crucial for the management of the natural resources of the Lagoa do Peixe National Park, the unique Ramsar site in Southern Brazil. The following questions were analyzed: (1 Do richness and composition of aquatic macrophytes from Lagoa do Peixe floodplain varies temporarily according to the sandbar opening and closing? (2 Does the variation pattern of the macrophyte community changed according to the sandbar opening and closing? A set of eight sampling sites of 1ha were selected over the Lagoa do Peixe floodplain: four sites not influenced by the artificial sandbar opening and four sites influenced by this event, being two sites closer to the sandbar opening and the two sites distant to the sandbar opening. The samplings were carried out between November 2007 and October 2009. The results show that although the artificial sandbar breaching does not affect the aquatic macrophyte richness at the floodplain, it affects the dynamics of species composition. The hydrological variation related to this management can be the main factor of the continuous change in the species composition in the floodplain, especially in the Southern portion. In order to avoid impacts in the macrophyte conservation, the artificial sandbar opening should be considered carefully, since the area of study is one of the most important conservation units to wetland systems in Southern Brazil.

  19. Does the Lagoa do peixe sandbar opening influence the macrophyte richness and composition in Southern Brazil wetlands?

    Science.gov (United States)

    Rolon, Ana Silvia; Rocha, Odete; Maltchik, Leonardo

    2013-03-01

    The Lagoa do Peixe has its connection with the sea artificially opened every year at the end of winter. However, this management has been carried out without the evaluation of the impact of this opening in the aquatic biodiversity. This information is crucial for the management of the natural resources of the Lagoa do Peixe National Park, the unique Ramsar site in Southern Brazil. The following questions were analyzed: (1) Do richness and composition of aquatic macrophytes from Lagoa do Peixe floodplain varies temporarily according to the sandbar opening and closing? (2) Does the variation pattern of the macrophyte community changed according to the sandbar opening and closing? A set of eight sampling sites of 1ha were selected over the Lagoa do Peixe floodplain: four sites not influenced by the artificial sandbar opening and four sites influenced by this event, being two sites closer to the sandbar opening and the two sites distant to the sandbar opening. The samplings were carried out between November 2007 and October 2009. The results show that although the artificial sandbar breaching does not affect the aquatic macrophyte richness at the floodplain, it affects the dynamics of species composition. The hydrological variation related to this management can be the main factor of the continuous change in the species composition in the floodplain, especially in the Southern portion. In order to avoid impacts in the macrophyte conservation, the artificial sandbar opening should be considered carefully, since the area of study is one of the most important conservation units to wetland systems in Southern Brazil.

  20. Ultraviolet electroluminescence from Au/MgO/MgxZn1−xO heterojunction diodes and the observation of Zn-rich cluster emission

    International Nuclear Information System (INIS)

    Liu, C.Y.; Xu, H.Y.; Sun, Y.; Zhang, C.; Ma, J.G.; Liu, Y.C.

    2014-01-01

    In this work, ultraviolet (UV) electroluminescence (EL) is achieved from Au/MgO/Mg x Zn 1−x O heterojunction diodes. The EL mechanism and laser forming process are discussed based on the energy band diagram, impact-ionization process and disordered optical structure. For ZnO and low Mg-content MgZnO devices, their EL spectra show single near-band-edge (NBE) emission. While in high Mg-content MgZnO devices, the emission from self-formed Zn-rich MgZnO clusters is observed and also contribute to the UV EL band. These Zn-rich clusters can act as thermally-stable luminescence centers, suggesting a promising route for developing MgZnO-based UV light-emitting devices. -- Highlights: • A series of Au/MgO/Mg x Zn 1−x O heterojunction diodes with multiple Mg compositions are fabricated and ultraviolet electroluminescence is achieved. • EL mechanism and laser forming process are discussed based on energy band diagram, impact-ionization process and disordered optical structure. • The transition from spontaneous to stimulated emission is observed in these heterojunctions, and the lasing mode is random laser. • In high Mg-content MgZnO devices, the emission from self-formed Zn-rich clusters is observed, which are thermally stable luminescence centers

  1. Simulation of resonance hyper-Rayleigh scattering of molecules and metal clusters using a time-dependent density functional theory approach.

    Science.gov (United States)

    Hu, Zhongwei; Autschbach, Jochen; Jensen, Lasse

    2014-09-28

    Resonance hyper-Rayleigh scattering (HRS) of molecules and metal clusters have been simulated based on a time-dependent density functional theory approach. The resonance first-order hyperpolarizability (β) is obtained by implementing damped quadratic response theory using the (2n + 1) rule. To test this implementation, the prototypical dipolar molecule para-nitroaniline (p-NA) and the octupolar molecule crystal violet are used as benchmark systems. Moreover, small silver clusters Ag 8 and Ag 20 are tested with a focus on determining the two-photon resonant enhancement arising from the strong metal transition. Our results show that, on a per atom basis, the small silver clusters possess two-photon enhanced HRS comparable to that of larger nanoparticles. This finding indicates the potential interest of using small metal clusters for designing new nonlinear optical materials.

  2. Electronic and magnetic properties of 3d-metal trioxides superhalogen cluster-doped monolayer MoS2: A first-principles study

    International Nuclear Information System (INIS)

    Li, Dan; Niu, Yuan; Zhao, Hongmin; Liang, Chunjun; He, Zhiqun

    2014-01-01

    Utilizing first-principle calculations, the structural, electronic, and magnetic properties of monolayer MoS 2 doped with 3d transition-metal (TM) atoms and 3d-metal trioxides (TMO 3 ) superhalogen clusters are investigated. 3d-metal TMO 3 superhalogen cluster-doped monolayers MoS 2 almost have negative formation energies except CoO 3 and NiO 3 doped monolayer MoS 2 , which are much lower than those of 3d TM-doped structures. 3d-metal TMO 3 superhalogen clusters are more easily embedded in monolayer MoS 2 than 3d-metal atoms. MnO 3 , FeO 3 , CoO 3 , and NiO 3 incorporated into monolayer MoS 2 are magnetic, and the total magnetic moments are approximately 1.0, 2.0, 3.0, and 4.0 μB per supercell, respectively. MnO 3 and FeO 3 incorporated into monolayer MoS 2 become semiconductors, whereas CoO 3 and NiO 3 incorporated into monolayer MoS 2 become half-metallic. Our studies demonstrate that the half-metallic ferromagnetic nature of 3d-metal TMO 3 superhalogen clusters-doped monolayer MoS 2 has a great potential for MoS 2 -based spintronic device applications. -- Highlights: •TMO 3 superhalogen clusters incorporated into monolayer MoS 2 were investigated. •TMO 3 doped structures have much lower formation energies than TM doped structures. •TMO 3 cluster-doped MoS 2 are thermodynamically favored. •Significant charge transfers between O atoms and Mo atoms in TMO 3 doped structures. •MnO 3 , FeO 3 , CoO 3 , and NiO 3 incorporated into monolayer MoS 2 are magnetic.

  3. A new Be star in an open cluster - NGC 6871-8

    Science.gov (United States)

    Grigsby, James A.; Morrison, Nancy D.

    1988-01-01

    Spectroscopic observations of H-alpha show that star eight in the open cluster NGC 6871 is a previously-undiscovered Be star. The H-alpha profile was observed to vary from clear emission to pure absorption over a period of ten days; later observations over a five-day interval show weak emission along with asymmetries and filling in of the profile.

  4. Nonlinear Color–Metallicity Relations of Globular Clusters. VII. Nonlinear Absorption-line Index versus Metallicity Relations and Bimodal Index Distributions of NGC 5128 Globular Clusters

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Sooyoung; Yoon, Suk-Jin, E-mail: sjyoon0691@yonsei.ac.kr [Department of Astronomy and Center for Galaxy Evolution Research, Yonsei University, Seoul 120-749 (Korea, Republic of)

    2017-07-01

    Spectroscopy on the globular cluster (GC) system of NGC 5128 revealed bimodality in absorption-line index distributions of its old GCs. GC division is a widely observed and studied phenomenon whose interpretation has depicted host galaxy formation and evolution such that it harbors two distinct metallicity groups. Such a conventional view of GC bimodality has mainly been based on photometry. The recent GC photometric data, however, presented an alternative perspective in which the nonlinear metallicity-to-color transformation is responsible for color bimodality of GC systems. Here we apply the same line of analysis to the spectral indices and examine the absorption-line index versus metallicity relations for the NGC 5128 GC system. NGC 5128 GCs display nonlinearity in the metallicity-index planes, most prominently for the Balmer lines and by a non-negligible degree for the metallicity-sensitive magnesium line. We demonstrate that the observed spectroscopic division of NGC 5128 GCs can be caused by the nonlinear nature of the metallicity-to-index conversions and thus one does not need to resort to two separate GC subgroups. Our analysis incorporating this nonlinearity provides a new perspective on the structure of NGC 5128's GC system, and a further piece to the global picture of the formation of GC systems and their host galaxies.

  5. Atmospheric parameters and metallicities for 2191 stars in the globular cluster M4

    International Nuclear Information System (INIS)

    Malavolta, Luca; Piotto, Giampaolo; Nascimbeni, Valerio; Sneden, Christopher; Milone, Antonino P.; Bedin, Luigi R.

    2014-01-01

    We report new metallicities for stars of Galactic globular cluster M4 using the largest number of stars ever observed at high spectral resolution in any cluster. We analyzed 7250 spectra for 2771 cluster stars gathered with the Very Large Telescope (VLT) FLAMES+GIRAFFE spectrograph at VLT. These medium-resolution spectra cover a small wavelength range, and often have very low signal-to-noise ratios. We approached this data set by reconsidering the whole method of abundance analysis of large stellar samples from beginning to end. We developed a new algorithm that automatically determines the atmospheric parameters of a star. Nearly all of the data preparation steps for spectroscopic analyses are processed on the syntheses, not the observed spectra. For 322 red giant branch (RGB) stars with V ≤ 14.7, we obtain a nearly constant metallicity, ([Fe/H]) = –1.07 (σ = 0.02). No difference in the metallicity at the level of 0.01 dex is observed between the two RGB sequences identified by Monelli et al. For 1869 subgiant and main-sequence stars with V > 14.7, we obtain ([Fe/H]) = –1.16 (σ = 0.09) after fixing the microturbulent velocity. These values are consistent with previous studies that have performed detailed analyses of brighter RGB stars at higher spectroscopic resolution and wavelength coverage. It is not clear if the small mean metallicity difference between brighter and fainter M4 members is real or is the result of the low signal-to-noise characteristics of the fainter stars. The strength of our approach is shown by recovering a metallicity close to a single value for more than 2000 stars, using a data set that is non-optimal for atmospheric analyses. This technique is particularly suitable for noisy data taken in difficult observing conditions

  6. Atmospheric parameters and metallicities for 2191 stars in the globular cluster M4

    Energy Technology Data Exchange (ETDEWEB)

    Malavolta, Luca; Piotto, Giampaolo; Nascimbeni, Valerio [Dipartimento di Fisica e Astronomia, Vicolo dell' Osservatorio 3, I-35122 Padova (Italy); Sneden, Christopher [Department of Astronomy and McDonald Observatory, The University of Texas, Austin, TX 78712 (United States); Milone, Antonino P. [Research School of Astronomy and Astrophysics, The Australian National University, Cotter Road, Weston, ACT 2611 (Australia); Bedin, Luigi R., E-mail: luca.malavolta@unipd.it, E-mail: giampaolo.piotto@unipd.it, E-mail: valerio.nascimbeni@unipd.it, E-mail: luigi.bedin@oapd.inaf.it, E-mail: chris@verdi.as.utexas.edu, E-mail: milone@mso.anu.edu.au [INAF-Osservatorio Astronomico di Padova, Vicolo dell' Osservatorio 5, I-35122 Padova (Italy)

    2014-02-01

    We report new metallicities for stars of Galactic globular cluster M4 using the largest number of stars ever observed at high spectral resolution in any cluster. We analyzed 7250 spectra for 2771 cluster stars gathered with the Very Large Telescope (VLT) FLAMES+GIRAFFE spectrograph at VLT. These medium-resolution spectra cover a small wavelength range, and often have very low signal-to-noise ratios. We approached this data set by reconsidering the whole method of abundance analysis of large stellar samples from beginning to end. We developed a new algorithm that automatically determines the atmospheric parameters of a star. Nearly all of the data preparation steps for spectroscopic analyses are processed on the syntheses, not the observed spectra. For 322 red giant branch (RGB) stars with V ≤ 14.7, we obtain a nearly constant metallicity, ([Fe/H]) = –1.07 (σ = 0.02). No difference in the metallicity at the level of 0.01 dex is observed between the two RGB sequences identified by Monelli et al. For 1869 subgiant and main-sequence stars with V > 14.7, we obtain ([Fe/H]) = –1.16 (σ = 0.09) after fixing the microturbulent velocity. These values are consistent with previous studies that have performed detailed analyses of brighter RGB stars at higher spectroscopic resolution and wavelength coverage. It is not clear if the small mean metallicity difference between brighter and fainter M4 members is real or is the result of the low signal-to-noise characteristics of the fainter stars. The strength of our approach is shown by recovering a metallicity close to a single value for more than 2000 stars, using a data set that is non-optimal for atmospheric analyses. This technique is particularly suitable for noisy data taken in difficult observing conditions.

  7. BVRI CCD photometry of the metal-poor globular cluster M68 (NGC 4590)

    International Nuclear Information System (INIS)

    Alcaino, G.; Liller, W.; Alvarado, F.; Wenderoth, E.

    1990-01-01

    BVRI photometry of the low metallicity globular cluster M68 (NGC 4590) was obtained with a CCD camera and the 2.2-m ESO telescope. The resulting BV color-magnitude diagrams are compared with the observations of McClure et al. (1987). The observations are also compared with theoretical isochrones, yielding a cluster age of 13 Gyr with a likely external uncertainty of 2 or 3 Gyr. 25 refs

  8. Major signal suppression from metal ion clusters in SFC/ESI-MS - Cause and effects.

    Science.gov (United States)

    Haglind, Alfred; Hedeland, Mikael; Arvidsson, Torbjörn; Pettersson, Curt E

    2018-05-01

    The widening application area of SFC-MS with polar analytes and water-containing samples facilitates the use of quick and simple sample preparation techniques such as "dilute and shoot" and protein precipitation. This has also introduced new polar interfering components such as alkali metal ions naturally abundant in e.g. blood plasma and urine, which have shown to be retained using screening conditions in SFC/ESI-TOF-MS and causing areas of major ion suppression. Analytes co-eluting with these clusters will have a decreased signal intensity, which might have a major effect on both quantification and identification. When investigating the composition of the alkali metal clusters using accurate mass and isotopic pattern, it could be concluded that they were previously not described in the literature. Using NaCl and KCl standards and different chromatographic conditions, varying e.g. column and modifier, the clusters proved to be formed from the alkali metal ions in combination with the alcohol modifier and make-up solvent. Their compositions were [(XOCH 3 ) n  + X] + , [(XOH) n  + X] + , [(X 2 CO 3 ) n  + X] + and [(XOOCOCH 3 ) n  + X] + for X = Na + or K + in ESI+. In ESI-, the clusters depended more on modifier, with [(XCl) n  + Cl] - and [(XOCH 3 ) n  + OCH 3 ] - mainly formed in pure methanol and [(XOOCH) n  + OOCH] - when 20 mM NH 4 Fa was added. To prevent the formation of the clusters by avoiding methanol as modifier might be difficult, as this is a widely used modifier providing good solubility when analyzing polar compounds in SFC. A sample preparation with e.g. LLE would remove the alkali ions, however also introducing a time consuming and discriminating step into the method. Since the alkali metal ions were retained and affected by chromatographic adjustments as e.g. mobile phase modifications, a way to avoid them could therefore be chromatographic tuning, when analyzing samples containing them. Copyright © 2018 Elsevier

  9. The influence of nanoscale morphology on the resistivity of cluster-assembled nanostructured metallic thin films

    International Nuclear Information System (INIS)

    Barborini, E; Bertolini, G; Repetto, P; Leccardi, M; Vinati, S; Corbelli, G; Milani, P

    2010-01-01

    We have studied in situ the evolution of the electrical resistivity of Fe, Pd, Nb, W and Mo cluster-assembled films during their growth by supersonic cluster beam deposition. We observed resistivity of cluster-assembled films several orders of magnitude larger than the bulk, as well as an increase in resistivity by increasing the film thickness in contrast to what was observed for atom-assembled metallic films. This suggests that the nanoscale morphological features typical of ballistic films growth, such as the minimal cluster-cluster interconnection and the evolution of surface roughness with thickness, are responsible for the observed behaviour.

  10. Stability and mobility of defect clusters and dislocation loops in metals

    DEFF Research Database (Denmark)

    Osetsky, Y.N.; Bacon, D.J.; Serra, A.

    2000-01-01

    has been observed in the computer simulation of small vacancy loops in alpha-Fe. In the present paper we summarise results obtained by molecular dynamics simulations of defect clusters and small dislocation loops in alpha-Fe(bcc) and Cu(fcc). The structure and stability of vacancy and interstitial......According to the production bias model, glissile defect clusters and small dislocation loops play an important role in the microstructural evolution during irradiation under cascade damage conditions. The atomic scale computer simulations carried out in recent years have clarified many questions...... loops are reviewed, and the dynamics of glissile clusters assessed. The relevance and importance of these results in establishing a better understanding of the observed differences in the damage accumulation behaviour between bcc and fee metals irradiated under cascade damage conditions are pointed out...

  11. Spectra of matrix isolated metal atoms and clusters

    International Nuclear Information System (INIS)

    Meyer, B.

    1977-01-01

    The matrix isolation spectra of all of the 40 presently known atomic metal species show strong matrix effects. The transition energies are increased, and the bands are broad and exhibit splitting of sublevels which are degenerate in the gas phase. Several models have been proposed for splitting of levels, but basic effects are not yet understood, and spectra cannot be predicted, yet it is possible to correlate gas phase and matrix in many of the systems. Selective production of diatomics and clusters via thermal and optical annealing of atomic species can be monitored by optical spectra, but yields spectroscopically complex systems which, however, especially in the case of transition metals, can be used as precursors in novel chemical reactions. A combination of absorption, emission, ir, Raman, ESR, and other methods is now quickly yielding data which will help correlate the increasing wealth of existing data. 55 references, 6 figures

  12. Disturbances to metal partitioning during toxicity testing of iron(II)-rich estuarine pore waters and whole sediments.

    Science.gov (United States)

    Simpson, Stuart L; Batley, Graeme E

    2003-02-01

    Metal partitioning is altered when suboxic estuarine sediments containing Fe(II)-rich pore waters are disturbed during collection, preparation, and toxicity testing. Experiments with model Fe(II)-rich pore waters demonstrated the rates at which adsorptive losses of Cd, Cu, Ni, Mn, Pb, and Zn occur upon exposure to air. Experiments with Zn-contaminated estuarine sediments demonstrated large and often unpredictable changes to metal partitioning during sediment storage, removal of organisms, and homogenization before testing. Small modifications to conditions, such as aeration of overlying waters, caused large changes to the metal partitioning. Disturbances caused by sediment collection required many weeks for reestablishment of equilibrium. Bioturbation by benthic organisms led to oxidation of pore-water Fe(II) and lower Zn fluxes because of the formation of Fe hydroxide precipitates that adsorb pore-water Zn. For five weeks after the addition of organisms to sediments, Zn fluxes increased slowly as the organisms established themselves in the sediments, indicating that the establishment of equilibrium was not rapid. The results are discussed in terms of the dynamic nature of suboxic, Fe(II)-rich estuarine sediments, how organisms perturb their environment, and the importance of understanding chemistry in toxicity testing with whole sediments or pore water. Recommendations are provided for the handling of sediments for toxicity testing.

  13. Stellar Population Properties of Ultracompact Dwarfs in M87: A Mass–Metallicity Correlation Connecting Low-metallicity Globular Clusters and Compact Ellipticals

    Science.gov (United States)

    Zhang, Hong-Xin; Puzia, Thomas H.; Peng, Eric W.; Liu, Chengze; Côté, Patrick; Ferrarese, Laura; Duc, Pierre-Alain; Eigenthaler, Paul; Lim, Sungsoon; Lançon, Ariane; Muñoz, Roberto P.; Roediger, Joel; Sánchez-Janssen, Ruben; Taylor, Matthew A.; Yu, Jincheng

    2018-05-01

    We derive stellar population parameters for a representative sample of ultracompact dwarfs (UCDs) and a large sample of massive globular clusters (GCs) with stellar masses ≳ 106 M ⊙ in the central galaxy M87 of the Virgo galaxy cluster, based on model fitting to the Lick-index measurements from both the literature and new observations. After necessary spectral stacking of the relatively faint objects in our initial sample of 40 UCDs and 118 GCs, we obtain 30 sets of Lick-index measurements for UCDs and 80 for GCs. The M87 UCDs have ages ≳ 8 Gyr and [α/Fe] ≃ 0.4 dex, in agreement with previous studies based on smaller samples. The literature UCDs, located in lower-density environments than M87, extend to younger ages and smaller [α/Fe] (at given metallicities) than M87 UCDs, resembling the environmental dependence of the stellar nuclei of dwarf elliptical galaxies (dEs) in the Virgo cluster. The UCDs exhibit a positive mass–metallicity relation (MZR), which flattens and connects compact ellipticals at stellar masses ≳ 108 M ⊙. The Virgo dE nuclei largely follow the average MZR of UCDs, whereas most of the M87 GCs are offset toward higher metallicities for given stellar masses. The difference between the mass–metallicity distributions of UCDs and GCs may be qualitatively understood as a result of their different physical sizes at birth in a self-enrichment scenario or of galactic nuclear cluster star formation efficiency being relatively low in a tidal stripping scenario for UCD formation. The existing observations provide the necessary but not sufficient evidence for tidally stripped dE nuclei being the dominant contributors to the M87 UCDs.

  14. Complex open-framework germanate built by 8-coordinated Ge 10 clusters

    KAUST Repository

    Yue, Huijuan

    2012-11-19

    A novel open-framework germanate |(C 5H 14N 2) 2(C 5H 12N 2) 0.5(H 2O) 2.5|[Ge 12.5O 26(OH) 2] with three-dimensional 10- and 11-ring channels, denoted as SU-67, has been synthesized under hydrothermal conditions using 2-methylpiperazine (MPP) as the structure-directing agent (SDA). The synthesis is intimately related to that of JLG-5, a tubular germanate built from Ge 7 clusters. The influences of synthesis parameters are discussed. A strong influence of the hydrofluoric acid quantity on the resulting cluster building units can be concluded. The framework of SU-67 is based on an elaborate topological pattern of connected Ge 10 clusters forming intersecting 10- and 11-ring channels and has a low framework density (12.4 Ge atoms per 1000 ̊ 3). We have discovered that the topology of SU-67 is a new 8-connected nce-8-I4 1/acd net. Strong hydrogen bonding among the organic SDAs, water molecules, and Ge 10 clusters resulted in helical networks in SU-67. © 2012 American Chemical Society.

  15. AMPLITUDES OF SOLAR-LIKE OSCILLATIONS: CONSTRAINTS FROM RED GIANTS IN OPEN CLUSTERS OBSERVED BY KEPLER

    International Nuclear Information System (INIS)

    Stello, Dennis; Huber, Daniel; Bedding, Timothy R.; Benomar, Othman; Kallinger, Thomas; Basu, Sarbani; Mosser, BenoIt; Hekker, Saskia; Mathur, Savita; GarcIa, Rafael A.; Kjeldsen, Hans; Grundahl, Frank; Christensen-Dalsgaard, Joergen; Gilliland, Ronald L.; Verner, Graham A.; Chaplin, William J.; Elsworth, Yvonne P.; Meibom, Soeren; Molenda-Zakowicz, Joanna; Szabo, Robert

    2011-01-01

    Scaling relations that link asteroseismic quantities to global stellar properties are important for gaining understanding of the intricate physics that underpins stellar pulsations. The common notion that all stars in an open cluster have essentially the same distance, age, and initial composition implies that the stellar parameters can be measured to much higher precision than what is usually achievable for single stars. This makes clusters ideal for exploring the relation between the mode amplitude of solar-like oscillations and the global stellar properties. We have analyzed data obtained with NASA's Kepler space telescope to study solar-like oscillations in 100 red giant stars located in either of the three open clusters, NGC 6791, NGC 6819, and NGC 6811. By fitting the measured amplitudes to predictions from simple scaling relations that depend on luminosity, mass, and effective temperature, we find that the data cannot be described by any power of the luminosity-to-mass ratio as previously assumed. As a result we provide a new improved empirical relation which treats luminosity and mass separately. This relation turns out to also work remarkably well for main-sequence and subgiant stars. In addition, the measured amplitudes reveal the potential presence of a number of previously unknown unresolved binaries in the red clump in NGC 6791 and NGC 6819, pointing to an interesting new application for asteroseismology as a probe into the formation history of open clusters.

  16. Size selected metal clusters

    Indian Academy of Sciences (India)

    First page Back Continue Last page Overview Graphics. The Optical Absorption Spectra of Small Silver Clusters (5-11) ... Soft Landing and Fragmentation of Small Clusters Deposited in Noble-Gas Films. Harbich, W.; Fedrigo, S.; Buttet, J. Phys. Rev. B 1998, 58, 7428. CO combustion on supported gold clusters. Arenz M ...

  17. A Wide-Field Photometric Survey for Extratidal Tails Around Five Metal-Poor Globular Clusters in the Galactic Halo

    Science.gov (United States)

    Chun, Sang-Hyun; Kim, Jae-Woo; Sohn, Sangmo T.; Park, Jang-Hyun; Han, Wonyong; Kim, Ho-Il; Lee, Young-Wook; Lee, Myung Gyoon; Lee, Sang-Gak; Sohn, Young-Jong

    2010-02-01

    Wide-field deep g'r'i' images obtained with the Megacam of the Canada-France-Hawaii Telescope are used to investigate the spatial configuration of stars around five metal-poor globular clusters M15, M30, M53, NGC 5053, and NGC 5466, in a field-of-view ~3°. Applying a mask filtering algorithm to the color-magnitude diagrams of the observed stars, we sorted cluster's member star candidates that are used to examine the characteristics of the spatial stellar distribution surrounding the target clusters. The smoothed surface density maps and the overlaid isodensity contours indicate that all of the five metal-poor globular clusters exhibit strong evidence of extratidal overdensity features over their tidal radii, in the form of extended tidal tails around the clusters. The orientations of the observed extratidal features show signatures of tidal tails tracing the clusters' orbits, inferred from their proper motions, and effects of dynamical interactions with the Galaxy. Our findings include detections of a tidal bridge-like feature and an envelope structure around the pair of globular clusters M53 and NGC 5053. The observed radial surface density profiles of target clusters have a deviation from theoretical King models, for which the profiles show a break at 0.5-0.7rt , extending the overdensity features out to 1.5-2rt . Both radial surface density profiles for different angular sections and azimuthal number density profiles confirm the overdensity features of tidal tails around the five metal-poor globular clusters. Our results add further observational evidence that the observed metal-poor halo globular clusters originate from an accreted satellite system, indicative of the merging scenario of the formation of the Galactic halo. Based on observations carried out at the Canada-France-Hawaii Telescope, operated by the National Research Council of Canada, the Centre National de la Recherche Scientifique de France, and the University of Hawaii. This is part of the

  18. POST-MERGER SIGNATURES OF RED-SEQUENCE GALAXIES IN RICH ABELL CLUSTERS AT z ∼< 0.1

    International Nuclear Information System (INIS)

    Sheen, Yun-Kyeong; Yi, Sukyoung K.; Lee, Jaehyun; Ree, Chang H.

    2012-01-01

    We have investigated the post-merger signatures of red-sequence galaxies in rich Abell clusters at z ∼ r < –20) cluster red-sequence galaxies show post-merger signatures in four clusters consistently. Most (∼71%) of the featured galaxies were found to be bulge dominated, and for the subsample of bulge-dominated red-sequence galaxies, the post-merger fraction rises to ∼38%. We also found that roughly 4% of bulge-dominated red-sequence galaxies interact (ongoing merger). A total of 42% (38% post-merger, 4% ongoing merger) of galaxies show merger-related features. Compared to a field galaxy study with a similar limiting magnitude by van Dokkum in 2005, our cluster study presents a similar post-merger fraction but a markedly lower ongoing merger fraction. The merger fraction derived is surprisingly high for the high density of our clusters, where the fast internal motions of galaxies are thought to play a negative role in galaxy mergers. The fraction of post-merger and ongoing merger galaxies can be explained as follows. Most of the post-merger galaxies may have carried over their merger features from their previous halo environment, whereas interacting galaxies interact in the current cluster in situ. According to our semi-analytic calculation, massive cluster halos may very well have experienced tens of halo mergers over the last 4-5 Gyr; post-merger features last that long, allowing these features to be detected in our clusters today. The apparent lack of dependence of the merger fraction on the clustocentric distance is naturally explained this way. In this scenario, the galaxy morphology and properties can be properly interpreted only when the halo evolution characteristics are understood first.

  19. Clustering environments of BL Lac objects

    Science.gov (United States)

    Wurtz, Ronald; Ellingson, Erica; Stocke, John T.; Yee, H. K. C.

    1993-01-01

    We report measurements of the amplitude of the BL Lac galaxy spatial covariance function, B(gb), for the fields of five BL Lacertae objects. We present evidence for rich clusters around MS 1207+39 and MS 1407+59, and confirm high richness for the cluster containing H0414+009. We discuss the ease of 3C 66 A and find evidence for a poor cluster based on an uncertain redshift of z = 0.444. These data suggest that at least some BL Lac objects are consistent with being FR 1 radio galaxies in rich clusters.

  20. The stellar and substellar mass function in central region of the old open cluster Praesepe from deep LBT observations

    Directory of Open Access Journals (Sweden)

    Goldman B.

    2011-07-01

    Full Text Available Studies of the mass function of open clusters of different ages allow us to study the efficiency with which brown dwarfs are evaporated from clusters to populate the field. Surveys in relatively old clusters (age ≳100 Myr do not suffer from problems found in young clusters, such as intra-cluster extinction and large uncertainties in brown dwarf models. In this paper, we present the results of a photometric survey to study the mass function of the old open cluster Praesepe (age of ~590 Myr and distance of ~190 pc, down to the substellar regime. We have performed optical (riz and Y-band photometric survey of Praesepe with the Large Binocular Telescope Camera, for a spatial coverage of 0.61 deg2 from ~90 MJ down to a 5σ detection limit at 40 MJ.

  1. Spectroscopic characterization of galaxy clusters in RCS-1: spectroscopic confirmation, redshift accuracy, and dynamical mass-richness relation

    Science.gov (United States)

    Gilbank, David G.; Barrientos, L. Felipe; Ellingson, Erica; Blindert, Kris; Yee, H. K. C.; Anguita, T.; Gladders, M. D.; Hall, P. B.; Hertling, G.; Infante, L.; Yan, R.; Carrasco, M.; Garcia-Vergara, Cristina; Dawson, K. S.; Lidman, C.; Morokuma, T.

    2018-05-01

    We present follow-up spectroscopic observations of galaxy clusters from the first Red-sequence Cluster Survey (RCS-1). This work focuses on two samples, a lower redshift sample of ˜30 clusters ranging in redshift from z ˜ 0.2-0.6 observed with multiobject spectroscopy (MOS) on 4-6.5-m class telescopes and a z ˜ 1 sample of ˜10 clusters 8-m class telescope observations. We examine the detection efficiency and redshift accuracy of the now widely used red-sequence technique for selecting clusters via overdensities of red-sequence galaxies. Using both these data and extended samples including previously published RCS-1 spectroscopy and spectroscopic redshifts from SDSS, we find that the red-sequence redshift using simple two-filter cluster photometric redshifts is accurate to σz ≈ 0.035(1 + z) in RCS-1. This accuracy can potentially be improved with better survey photometric calibration. For the lower redshift sample, ˜5 per cent of clusters show some (minor) contamination from secondary systems with the same red-sequence intruding into the measurement aperture of the original cluster. At z ˜ 1, the rate rises to ˜20 per cent. Approximately ten per cent of projections are expected to be serious, where the two components contribute significant numbers of their red-sequence galaxies to another cluster. Finally, we present a preliminary study of the mass-richness calibration using velocity dispersions to probe the dynamical masses of the clusters. We find a relation broadly consistent with that seen in the local universe from the WINGS sample at z ˜ 0.05.

  2. Google Classroom and Open Clusters: An Authentic Science Research Project for High School Students

    Science.gov (United States)

    Johnson, Chelen H.; Linahan, Marcella; Cuba, Allison Frances; Dickmann, Samantha Rose; Hogan, Eleanor B.; Karos, Demetra N.; Kozikowski, Kendall G.; Kozikowski, Lauren Paige; Nelson, Samantha Brooks; O'Hara, Kevin Thomas; Ropinski, Brandi Lucia; Scarpa, Gabriella; Garmany, Catharine D.

    2016-01-01

    STEM education is about offering unique opportunities to our students. For the past three years, students from two high schools (Breck School in Minneapolis, MN, and Carmel Catholic High School in Mundelein, IL) have collaborated on authentic astronomy research projects. This past year they surveyed archival data of open clusters to determine if a clear turnoff point could be unequivocally determined. Age and distance to each open cluster were calculated. Additionally, students requested time on several telescopes to obtain original data to compare to the archival data. Students from each school worked in collaborative teams, sharing and verifying results through regular online hangouts and chats. Work papers were stored in a shared drive and on a student-designed Google site to facilitate dissemination of documents between the two schools.

  3. Binarity and Variable Stars in the Open Cluster NGC 2126

    Science.gov (United States)

    Chehlaeh, Nareemas; Mkrtichian, David; Kim, Seung-Lee; Lampens, Patricia; Komonjinda, Siramas; Kusakin, Anatoly; Glazunova, Ljudmila

    2018-04-01

    We present the results of an analysis of photometric time-series observations for NGC 2126 acquired at the Thai National Observatory (TNO) in Thailand and the Mount Lemmon Optical Astronomy Observatory (LOAO) in USA during the years 2004, 2013 and 2015. The main purpose is to search for new variable stars and to study the light curves of binary systems as well as the oscillation spectra of pulsating stars. NGC 2126 is an intermediate-age open cluster which has a population of stars inside the δ Scuti instability strip. Several variable stars are reported including three eclipsing binary stars, one of which is an eclipsing binary star with a pulsating component (V551 Aur). The Wilson-Devinney technique was used to analyze its light curves and to determine a new set of the system’s parameters. A frequency analysis of the eclipse-subtracted light curve was also performed. Eclipsing binaries which are members of open clusters are capable of delivering strong constraints on the cluster’s properties which are in turn useful for a pulsational analysis of their pulsating components. Therefore, high-resolution, high-quality spectra will be needed to derive accurate component radial velocities of the faint eclipsing binaries which are located in the field of NGC 2126. The new Devasthal Optical Telescope, suitably equipped, could in principle do this.

  4. Super-solar Metallicity Stars in the Galactic Center Nuclear Star Cluster: Unusual Sc, V, and Y Abundances

    Science.gov (United States)

    Do, Tuan; Kerzendorf, Wolfgang; Konopacky, Quinn; Marcinik, Joseph M.; Ghez, Andrea; Lu, Jessica R.; Morris, Mark R.

    2018-03-01

    We present adaptive-optics assisted near-infrared high-spectral-resolution observations of late-type giants in the nuclear star cluster of the Milky Way. The metallicity and elemental abundance measurements of these stars offer us an opportunity to understand the formation and evolution of the nuclear star cluster. In addition, their proximity to the supermassive black hole (∼0.5 pc) offers a unique probe of the star formation and chemical enrichment in this extreme environment. We observed two stars identified by medium spectral-resolution observations as potentially having very high metallicities. We use spectral-template fitting with the PHOENIX grid and Bayesian inference to simultaneously constrain the overall metallicity, [M/H], alpha-element abundance [α/Fe], effective temperature, and surface gravity of these stars. We find that one of the stars has very high metallicity ([M/H] > 0.6) and the other is slightly above solar metallicity. Both Galactic center stars have lines from scandium (Sc), vanadium (V), and yttrium (Y) that are much stronger than allowed by the PHOENIX grid. We find, using the spectral synthesis code Spectroscopy Made Easy, that [Sc/Fe] may be an order of magnitude above solar. For comparison, we also observed an empirical calibrator in NGC 6791, the highest metallicity cluster known ([M/H] ∼ 0.4). Most lines are well matched between the calibrator and the Galactic center stars, except for Sc, V, and Y, which confirms that their abundances must be anomalously high in these stars. These unusual abundances, which may be a unique signature of nuclear star clusters, offer an opportunity to test models of chemical enrichment in this region.

  5. Cluster-based bulk metallic glass formation in Fe-Si-B-Nb alloy systems

    Energy Technology Data Exchange (ETDEWEB)

    Zhu, C L; Wang, Q; Li, F W; Li, Y H; Wang, Y M; Dong, C [State Key Laboratory of Materials Modification, Dalian University of Technology (DUT), Dalian 116024 (China); Zhang, W; Inoue, A, E-mail: dong@dlut.edu.c [Institute for Materials Research (IMR), Tohoku University, Katahira 2-1-1, Aoba-Ku, Sendai 980-8577 (Japan)

    2009-01-01

    Bulk metallic glass formations have been explored in Fe-B-Si-Nb alloy system using the so-called atomic cluster line approach in combination with minor alloying guideline. The atomic cluster line refers to a straight line linking binary cluster to the third element in a ternary system. The basic ternary compositions in Fe-B-Si system are determined by the inetersection points of two cluster lines, namely Fe-B cluster to Si and Fe-Si cluster to B, and then further alloyed with 3-5 at. % Nb for enhancing glass forming abilities. BMG rods with a diameter of 3 mm are formed under the case of minor Nb alloying the basic intersecting compositions of Fe{sub 8}B{sub 3}-Si with Fe{sub 12}Si-B and Fe{sub 8}B{sub 2}-Si with Fe{sub 9}Si-B. The BMGs also exhibit high Vickers hardness (H{sub v}) of 1130-1164 and high Young's modulous (E) of 170-180 GPa

  6. OpenAPC. Open-Access-Publikationskosten als Open Data

    OpenAIRE

    Tullney, Marco

    2015-01-01

    Präsentationsfolien zum Vortrag „OpenAPC. Open-Access-Publikationskosten als Open Data“ in der Session „Ausgestaltung eines wissenschaftsadäquaten APC-Marktes: Grundsätze, Finanzierungsansätze und Management“ der Open-Access-Tage 2015 in Zürich (https://www.open-access.net/community/open-access-tage/open-access-tage-2015-zuerich/programm/#c1974)

  7. Phosphorus vacancy cluster model for phosphorus diffusion gettering of metals in Si

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Renyu; Trzynadlowski, Bart; Dunham, Scott T. [Department of Electrical Engineering, University of Washington, Seattle, Washington 98195 (United States)

    2014-02-07

    In this work, we develop models for the gettering of metals in silicon by high phosphorus concentration. We first performed ab initio calculations to determine favorable configurations of complexes involving phosphorus and transition metals (Fe, Cu, Cr, Ni, Ti, Mo, and W). Our ab initio calculations found that the P{sub 4}V cluster, a vacancy surrounded by 4 nearest-neighbor phosphorus atoms, which is the most favorable inactive P species in heavily doped Si, strongly binds metals such as Cu, Cr, Ni, and Fe. Based on the calculated binding energies, we build continuum models to describe the P deactivation and Fe gettering processes with model parameters calibrated against experimental data. In contrast to previous models assuming metal-P{sub 1}V or metal-P{sub 2}V as the gettered species, the binding of metals to P{sub 4}V satisfactorily explains the experimentally observed strong gettering behavior at high phosphorus concentrations.

  8. The Not So Simple Globular Cluster ω Cen. I. Spatial Distribution of the Multiple Stellar Populations

    Energy Technology Data Exchange (ETDEWEB)

    Calamida, A.; Saha, A. [National Optical Astronomy Observatory—AURA, 950 N Cherry Avenue, Tucson, AZ, 85719 (United States); Strampelli, G.; Rest, A. [Space Telescope Science Institute—AURA, 3700 San Martin Drive, Baltimore, MD 21218 (United States); Bono, G.; Ferraro, I.; Iannicola, G. [INAF—Osservatorio Astronomico di Roma—Via Frascati 33, I-00040, Monteporzio Catone, Rome (Italy); Scolnic, D. [The University of Chicago, The Kavli Institute for Cosmological Physics, William Eckhardt Research Center—Suite 499, 5640 South Ellis Avenue, Chicago, IL 60637 (United States); James, D.; Smith, C.; Zenteno, A., E-mail: calamida@noao.edu [Cerro Tololo Inter-American Observatory, Casilla 603, La Serena (Chile)

    2017-04-01

    We present a multi-band photometric catalog of ≈1.7 million cluster members for a field of view of ≈2° × 2° across ω Cen. Photometry is based on images collected with the Dark Energy Camera on the 4 m Blanco telescope and the Advanced Camera for Surveys on the Hubble Space Telescope . The unprecedented photometric accuracy and field coverage allowed us, for the first time, to investigate the spatial distribution of ω Cen multiple populations from the core to the tidal radius, confirming its very complex structure. We found that the frequency of blue main-sequence stars is increasing compared to red main-sequence stars starting from a distance of ≈25′ from the cluster center. Blue main-sequence stars also show a clumpy spatial distribution, with an excess in the northeast quadrant of the cluster pointing toward the direction of the Galactic center. Stars belonging to the reddest and faintest red-giant branch also show a more extended spatial distribution in the outskirts of ω Cen, a region never explored before. Both these stellar sub-populations, according to spectroscopic measurements, are more metal-rich compared to the cluster main stellar population. These findings, once confirmed, make ω Cen the only stellar system currently known where metal-rich stars have a more extended spatial distribution compared to metal-poor stars. Kinematic and chemical abundance measurements are now needed for stars in the external regions of ω Cen to better characterize the properties of these sub-populations.

  9. Platinum clusters with precise numbers of atoms for preparative-scale catalysis.

    Science.gov (United States)

    Imaoka, Takane; Akanuma, Yuki; Haruta, Naoki; Tsuchiya, Shogo; Ishihara, Kentaro; Okayasu, Takeshi; Chun, Wang-Jae; Takahashi, Masaki; Yamamoto, Kimihisa

    2017-09-25

    Subnanometer noble metal clusters have enormous potential, mainly for catalytic applications. Because a difference of only one atom may cause significant changes in their reactivity, a preparation method with atomic-level precision is essential. Although such a precision with enough scalability has been achieved by gas-phase synthesis, large-scale preparation is still at the frontier, hampering practical applications. We now show the atom-precise and fully scalable synthesis of platinum clusters on a milligram scale from tiara-like platinum complexes with various ring numbers (n = 5-13). Low-temperature calcination of the complexes on a carbon support under hydrogen stream affords monodispersed platinum clusters, whose atomicity is equivalent to that of the precursor complex. One of the clusters (Pt 10 ) exhibits high catalytic activity in the hydrogenation of styrene compared to that of the other clusters. This method opens an avenue for the application of these clusters to preparative-scale catalysis.The catalytic activity of a noble metal nanocluster is tied to its atomicity. Here, the authors report an atom-precise, fully scalable synthesis of platinum clusters from molecular ring precursors, and show that a variation of only one atom can dramatically change a cluster's reactivity.

  10. Optical trapping of metal-dielectric nanoparticle clusters near photonic crystal microcavities.

    Science.gov (United States)

    Mejia, Camilo A; Huang, Ningfeng; Povinelli, Michelle L

    2012-09-01

    We predict the formation of optically trapped, metal-dielectric nanoparticle clusters above photonic crystal microcavities. We determine the conditions on particle size and position for a gold particle to be trapped above the microcavity. We then show that strong field redistribution and enhancement near the trapped gold nanoparticle results in secondary trapping sites for a pair of dielectric nanoparticles.

  11. Nonlocality and particle-clustering effects on the optical response of composite materials with metallic nanoparticles

    Science.gov (United States)

    Chen, C. W.; Chung, H. Y.; Chiang, H.-P.; Lu, J. Y.; Chang, R.; Tsai, D. P.; Leung, P. T.

    2010-10-01

    The optical properties of composites with metallic nanoparticles are studied, taking into account the effects due to the nonlocal dielectric response of the metal and the coalescing of the particles to form clusters. An approach based on various effective medium theories is followed, and the modeling results are compared with those from the cases with local response and particles randomly distributed through the host medium. Possible observations of our modeling results are illustrated via a calculation of the transmission of light through a thin film made of these materials. It is found that the nonlocal effects are particularly significant when the particles coalesce, leading to blue-shifted resonances and slightly lower values in the dielectric functions. The dependence of these effects on the volume fraction and fractal dimension of the metal clusters is studied in detail.

  12. DISCOVERY OF 14 NEW SLOWLY PULSATING B STARS IN THE OPEN CLUSTER NGC 7654

    International Nuclear Information System (INIS)

    Luo, Y. P.; Han, Z. W.; Zhang, X. B.; Deng, L. C.

    2012-01-01

    We carried out time-series BV CCD photometric observations of the open cluster NGC 7654 (Messier 52) to search for variable stars. Eighteen slowly pulsating B (SPB) stars have been detected, among which 14 candidates are newly discovered, three known ones are confirmed, and a previously found δ Scuti star is also identified as an SPB candidate. Twelve SPBs are probable cluster members based on membership analysis. This makes NGC 7654 the richest galactic open cluster in terms of SPB star content. It is also a new discovery that NGC 7654 hosts three γ Dor star candidates. We found that all these stars (18 SPB and 3 γ Dor stars) have periods longer than their corresponding fundamental radial mode. With such a big sample of g-mode pulsators in a single cluster, it is clear that multi-mode pulsation is more common in the upper part of the main sequence than in the lower part. All the stars span a narrow strip on the period-luminosity plane, which also includes the γ Dor stars at the low-luminosity extension. This result implies that there may be a single period-luminosity relation applicable to all g-mode main-sequence pulsators. As a by-product, three EA-type eclipsing binaries and an EW-type eclipsing binary are also discovered.

  13. Tuning the magnetic properties of deposited transition metal clusters by decoration

    Energy Technology Data Exchange (ETDEWEB)

    Minar, Jan; Bornemann, S.; Ebert, H. [Dept. Chemie, LMU, Butenandtstr. 5-13, 81377 Muenchen (Germany); Staunton, J.B. [Department of Physics, University of Warwick (United Kingdom); Rusponi, S.; Brunne, H. [EPF Lausanne (Switzerland)

    2008-07-01

    Using the fully relativistic version of the KKR-method for electronic structure calculations within local spin density functional theory (LSDA) the magnetic properties of Fe, Co and Ni clusters deposited on the Pt(111) surface have been investigated. Of central interest are the role of spin-orbit coupling as it influences the spontaneous formation and orientation of magnetic moments and gives rise amongst others to the occurrence of orbital magnetic moments, the magnetic anisotropy energy (MAE) and magnetic circular dichroism in X-ray absorption (XMCD). Our systematic investigations of different clusters and nanostructures aim to reveal the mutual relationship among their spin-orbit induced properties. In addition they show how their various magnetic properties depend on the structural properties and chemical composition of the studied system. For large two-dimensional clusters we focussed especially on the dependency of the MAE on decoration with another transition metal. Our results are in qualitative agreement with recent experimental findings. We resolved the MAE contributions for inequivalent cluster atoms and will discuss the effect of the induced MAE within the Pt substrate.

  14. Metal-Organic Framework of Lanthanoid Dinuclear Clusters Undergoes Slow Magnetic Relaxation

    Directory of Open Access Journals (Sweden)

    Hikaru Iwami

    2017-01-01

    Full Text Available Lanthanoid metal-organic frameworks (Ln-MOFs can adopt a variety of new structures due to the large coordination numbers of Ln metal ions, and Ln-MOFs are expected to show new luminescence and magnetic properties due to the localized f electrons. In particular, some Ln metal ions, such as Dy(III and Tb(III ions, work as isolated quantum magnets when they have magnetic anisotropy. In this work, using 4,4′,4″-s-triazine-2,4,6-triyl-tribenzoic acid (H3TATB as a ligand, two new Ln-MOFs, [Dy(TATB(DMF2] (1 and [Tb(TATB(DMF2] (2, were obtained. The Ln-MOFs contain Ln dinuclear clusters as secondary building units, and 1 underwent slow magnetic relaxation similar to single-molecule magnets.

  15. Stabilized Lithium-Metal Surface in a Polysulfide-Rich Environment of Lithium-Sulfur Batteries.

    Science.gov (United States)

    Zu, Chenxi; Manthiram, Arumugam

    2014-08-07

    Lithium-metal anode degradation is one of the major challenges of lithium-sulfur (Li-S) batteries, hindering their practical utility as next-generation rechargeable battery chemistry. The polysulfide migration and shuttling associated with Li-S batteries can induce heterogeneities of the lithium-metal surface because it causes passivation by bulk insulating Li2S particles/electrolyte decomposition products on a lithium-metal surface. This promotes lithium dendrite formation and leads to poor lithium cycling efficiency with complicated lithium surface chemistry. Here, we show copper acetate as a surface stabilizer for lithium metal in a polysulfide-rich environment of Li-S batteries. The lithium surface is protected from parasitic reactions with the organic electrolyte and the migrating polysulfides by an in situ chemical formation of a passivation film consisting of mainly Li2S/Li2S2/CuS/Cu2S and electrolyte decomposition products. This passivation film also suppresses lithium dendrite formation by controlling the lithium deposition sites, leading to a stabilized lithium surface characterized by a dendrite-free morphology and improved surface chemistry.

  16. NGC 6705 a young α-enhanced open cluster from OCCASO data

    Science.gov (United States)

    Casamiquela, L.; Carrera, R.; Balaguer-Núñez, L.; Jordi, C.; Chiappini, C.; Anders, F.; Antoja, T.; Miret-Roig, N.; Romero-Gomez, M.; Blanco-Cuaresma, S.; Pancino, E.; Aguado, D. S.; del Pino, A.; Diaz-Perez, L.; Gallart, C.

    2018-03-01

    Context. The stellar [α/Fe] abundance is sometimes used as a proxy for stellar age, following standard chemical evolution models for the Galaxy, as seen by different observational results. Aim. In this work, we aim to show that the open cluster NGC 6705/M 11 has a significant α-enhancement [α/Fe] > 0.1 dex, despite its young age ( 300 Myr), challenging the current paradigm. Methods: We used high resolution (R > 65 000) high signal-to-noise ( 70) spectra of eight red clump stars, acquired within the OCCASO survey. We determined very accurate chemical abundances of several α elements, using an equivalent width methodology (Si, Ca and Ti), and spectral synthesis fits (Mg and O). Results: We obtain [Si/Fe] = 0.13 ± 0.05, [Mg/Fe] = 0.14 ± 0.07, [O/Fe] = 0.17 ± 0.07, [Ca/Fe] = 0.06 ± 0.05, and [Ti/Fe] = 0.03 ± 0.03. Our results place these clusters within the group of young [α/Fe]-enhanced field stars recently found by several authors in the literature. The ages of our stars have an uncertainty of around 50 Myr, much more precise than for field stars. By integrating the cluster's orbit in several non-axisymmetric Galactic potentials, we establish the M 11's most likely birth radius as lying between 6.8-7.5 kpc from the Galactic centre, not far from its current position. Conclusions: With the robust open cluster age scale, our results prove that a moderate [α/Fe]-enhancement is no guarantee for a star to be old, and that not all α-enhanced stars can be explained with an evolved blue straggler scenario. Based on our orbit calculations, we further argue against a Galactic bar origin of M 11. Full Table 2 is only available at the CDS via anonymous ftp to http://cdsarc.u-strasbg.fr (http://130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/qcat?J/A+A/610/A66

  17. Assessment of the accuracy of coupled cluster perturbation theory for open-shell systems. I. Triples expansions.

    Science.gov (United States)

    Eriksen, Janus J; Matthews, Devin A; Jørgensen, Poul; Gauss, Jürgen

    2016-05-21

    The accuracy at which total energies of open-shell atoms and organic radicals may be calculated is assessed for selected coupled cluster perturbative triples expansions, all of which augment the coupled cluster singles and doubles (CCSD) energy by a non-iterative correction for the effect of triple excitations. Namely, the second- through sixth-order models of the recently proposed CCSD(T-n) triples series [J. J. Eriksen et al., J. Chem. Phys. 140, 064108 (2014)] are compared to the acclaimed CCSD(T) model for both unrestricted as well as restricted open-shell Hartree-Fock (UHF/ROHF) reference determinants. By comparing UHF- and ROHF-based statistical results for a test set of 18 modest-sized open-shell species with comparable RHF-based results, no behavioral differences are observed for the higher-order models of the CCSD(T-n) series in their correlated descriptions of closed- and open-shell species. In particular, we find that the convergence rate throughout the series towards the coupled cluster singles, doubles, and triples (CCSDT) solution is identical for the two cases. For the CCSD(T) model, on the other hand, not only its numerical consistency, but also its established, yet fortuitous cancellation of errors breaks down in the transition from closed- to open-shell systems. The higher-order CCSD(T-n) models (orders n > 3) thus offer a consistent and significant improvement in accuracy relative to CCSDT over the CCSD(T) model, equally for RHF, UHF, and ROHF reference determinants, albeit at an increased computational cost.

  18. Assessment of the accuracy of coupled cluster perturbation theory for open-shell systems. I. Triples expansions

    Energy Technology Data Exchange (ETDEWEB)

    Eriksen, Janus J., E-mail: janusje@chem.au.dk; Jørgensen, Poul [qLEAP Center for Theoretical Chemistry, Department of Chemistry, Aarhus University, DK-8000 Aarhus C (Denmark); Matthews, Devin A. [The Institute for Computational Engineering and Sciences, The University of Texas at Austin, Austin, Texas 78712 (United States); Gauss, Jürgen [Institut für Physikalische Chemie, Johannes Gutenberg-Universität Mainz, D-55128 Mainz (Germany)

    2016-05-21

    The accuracy at which total energies of open-shell atoms and organic radicals may be calculated is assessed for selected coupled cluster perturbative triples expansions, all of which augment the coupled cluster singles and doubles (CCSD) energy by a non-iterative correction for the effect of triple excitations. Namely, the second- through sixth-order models of the recently proposed CCSD(T–n) triples series [J. J. Eriksen et al., J. Chem. Phys. 140, 064108 (2014)] are compared to the acclaimed CCSD(T) model for both unrestricted as well as restricted open-shell Hartree-Fock (UHF/ROHF) reference determinants. By comparing UHF- and ROHF-based statistical results for a test set of 18 modest-sized open-shell species with comparable RHF-based results, no behavioral differences are observed for the higher-order models of the CCSD(T–n) series in their correlated descriptions of closed- and open-shell species. In particular, we find that the convergence rate throughout the series towards the coupled cluster singles, doubles, and triples (CCSDT) solution is identical for the two cases. For the CCSD(T) model, on the other hand, not only its numerical consistency, but also its established, yet fortuitous cancellation of errors breaks down in the transition from closed- to open-shell systems. The higher-order CCSD(T–n) models (orders n > 3) thus offer a consistent and significant improvement in accuracy relative to CCSDT over the CCSD(T) model, equally for RHF, UHF, and ROHF reference determinants, albeit at an increased computational cost.

  19. A new method for measuring metallicities of young super star clusters

    International Nuclear Information System (INIS)

    Gazak, J. Zachary; Kudritzki, Rolf; Bresolin, Fabio; Davies, Ben; Bastian, Nate; Bergemann, Maria; Plez, Bertrand; Evans, Chris; Patrick, Lee; Schinnerer, Eva

    2014-01-01

    We demonstrate how the metallicities of young super star clusters (SSC) can be measured using novel spectroscopic techniques in the J-band. The near-infrared flux of SSCs older than ∼6 Myr is dominated by tens to hundreds of red supergiant stars. Our technique is designed to harness the integrated light of that population and produces accurate metallicities for new observations in galaxies above (M83) and below (NGC 6946) solar metallicity. In M83 we find [Z] = +0.28 ± 0.14 dex using a moderate resolution (R ∼ 3500) J-band spectrum and in NGC 6496 we report [Z] = -0.32 ± 0.20 dex from a low resolution spectrum of R ∼ 1800. Recently commissioned low resolution multiplexed spectrographs on the Very Large Telescope (KMOS) and Keck (MOSFIRE) will allow accurate measurements of SSC metallicities across the disks of star-forming galaxies up to distances of 70 Mpc with single night observation campaigns using the method presented in this paper.

  20. Lithium in Blanco1: Implications for Stellar Mixing

    OpenAIRE

    Jeffries, R. D.; James, D. J.

    1998-01-01

    We obtain lithium abundances for G and K stars in Blanco 1, an open cluster with an age similar to, or slightly younger than, the Pleiades. We critically examine previous spectroscopic abundance analyses of Blanco 1 and conclude that while there were flaws in earlier work, it is likely that Blanco 1 is close in overall metallicity to the older Hyades cluster and more metal-rich than the Pleiades. However, we find Blanco 1 has Li abundances and rotation rates similar to the Pleiades, contradic...

  1. New VVV Survey Globular Cluster Candidates in the Milky Way Bulge

    Energy Technology Data Exchange (ETDEWEB)

    Minniti, Dante; Gómez, Matías [Departamento de Física, Facultad de Ciencias Exactas, Universidad Andrés Bello, Av. Fernandez Concha 700, Las Condes, Santiago (Chile); Geisler, Douglas; Fernández-Trincado, Jose G. [Departamento de Astronomía, Casilla 160-C, Universidad de Concepción, Casilla 160-C, Concepción (Chile); Alonso-García, Javier; Beamín, Juan Carlos; Borissova, Jura; Catelan, Marcio; Ramos, Rodrigo Contreras; Kurtev, Radostin; Pullen, Joyce [Instituto Milenio de Astrofísica, Santiago (Chile); Palma, Tali; Clariá, Juan J. [Observatorio Astronómico, Universidad Nacional de Córdoba, Laprida 854, Córdoba (Argentina); Cohen, Roger E. [Space Telescope Science Institute, 2700 San Martin Drive, Baltimore (United States); Dias, Bruno [European Southern Observatory, Alonso de Cordova 3107, Vitacura, Santiago (Chile); Hempel, Maren [Pontificia Universidad Católica de Chile, Instituto de Astrofísica, Av. Vicuña Mackenna 4860, Santiago (Chile); Ivanov, Valentin D. [European Southern Observatory, Karl-Schwarszchild-Str. 2, D-85748 Garching bei Muenchen (Germany); Lucas, Phillip W. [Dept. of Astronomy, University of Hertfordshire, Hertfordshire (United Kingdom); Moni-Bidin, Christian; Alegría, Sebastian Ramírez [Instituto de Astronomía, Universidad Católica del Norte, Antofagasta (Chile); and others

    2017-11-10

    It is likely that a number of Galactic globular clusters remain to be discovered, especially toward the Galactic bulge. High stellar density combined with high and differential interstellar reddening are the two major problems for finding globular clusters located toward the bulge. We use the deep near-IR photometry of the VISTA Variables in the Vía Láctea (VVV) Survey to search for globular clusters projected toward the Galactic bulge, and hereby report the discovery of 22 new candidate globular clusters. These objects, detected as high density regions in our maps of bulge red giants, are confirmed as globular cluster candidates by their color–magnitude diagrams. We provide their coordinates as well as their near-IR color–magnitude diagrams, from which some basic parameters are derived, such as reddenings and heliocentric distances. The color–magnitude diagrams reveal well defined red giant branches in all cases, often including a prominent red clump. The new globular cluster candidates exhibit a variety of extinctions (0.06 < A {sub Ks} < 2.77) and distances (5.3 < D < 9.5 kpc). We also classify the globular cluster candidates into 10 metal-poor and 12 metal-rich clusters, based on the comparison of their color–magnitude diagrams with those of known globular clusters also observed by the VVV Survey. Finally, we argue that the census for Galactic globular clusters still remains incomplete, and that many more candidate globular clusters (particularly the low luminosity ones) await to be found and studied in detail in the central regions of the Milky Way.

  2. Clustering of nucleosides in the presence of alkali metals: Biologically relevant quartets of guanosine, deoxyguanosine and uridine observed by ESI-MS/MS.

    Science.gov (United States)

    Aggerholm, Tenna; Nanita, Sergio C; Koch, Kim J; Cooks, R Graham

    2003-01-01

    Electrospray ionization (ESI) mass spectra of nucleosides, recorded in the presence of alkali metals, display alkali metal ion-bound quartets and other clusters that may have implications for understanding non-covalent interactions in DNA and RNA. The tetramers of guanosine and deoxyguanosine and also their metaclusters (clusters of clusters), cationized by alkali metals, were observed as unusually abundant magic number clusters. The observation of these species in the gas phase parallels previous condensed-phase studies, which show that guanine derivatives can form quartets and metaclusters of quartets in solution in the presence of metal cations. This parallel behavior and also internal evidence suggest that bonding in the guanosine tetramers involves the bases rather than the sugar units. The nucleobases thymine and uracil are known to form magic number pentameric adducts with K+, Cs+ and NH4+ in the gas phase. In sharp contrast, we now show that the nucleosides uridine and deoxythymidine do not form the pentameric clusters characteristic of the corresponding bases. More subtle effects of the sugars are evident in the fact that adenosine and cytidine form numerous higher order clusters with alkali metals, whereas deoxyadenosine and deoxycytidine show no clustering. It is suggested that hydrogen bonding between the bases in the tetramers of dG and rG are the dominant interactions in the clusters, hence changing the ribose group to deoxyribose (and vice versa) generally has little effect. However, the additional hydroxyl group of RNA nucleosides enhances the non-selective formation of higher-order aggregates for adenosine and cytidine and results in the lack of highly stable magic number clusters. Some clusters are the result of aggregation in the course of ionization (ESI) whereas others appear to be intrinsic to the solution being examined. Copyright 2003 John Wiley & Sons, Ltd.

  3. Optical and ultraviolet study of five stars in the Pleiades open cluster

    International Nuclear Information System (INIS)

    Younan, K.F.; Dufton, P.L.

    1984-01-01

    Optical and ultraviolet observations of five low-reddened stars in the Pleiades open cluster have been obtained with an echelle spectrograph and the IUE satellite. The observed interstellar absorption lines have been analysed with different cloud models to estimate interstellar gas abundances for each line-of-sight. These results have been discussed in the light of current models for diatomic formation. (author)

  4. Electron-Poor Polar Intermetallics: Complex Structures, Novel Clusters, and Intriguing Bonding with Pronounced Electron Delocalization.

    Science.gov (United States)

    Lin, Qisheng; Miller, Gordon J

    2018-01-16

    complexity can be realized by small amounts of Li replacing Zn atoms in the parent binary compounds CaZn 2 , CaZn 3 , and CaZn 5 ; their phase formation and bonding schemes can be rationalized by Fermi surface-Brillouin zone interactions between nearly free-electron states. "Cation-rich", electron-poor polar intermetallics have emerged using rare earth metals as the electropositive ("cationic") component together metal/metalloid clusters that mimic the backbones of aromatic hydrocarbon molecules, which give evidence of extensive electronic delocalization and multicenter bonding. Thus, we can identify three distinct, valence electron-poor, polar intermetallic systems that have yielded unprecedented phases adopting novel structures containing complex clusters and intriguing bonding characteristics. In this Account, we summarize our recent specific progress in the developments of novel Au-rich BaAl 4 -type related structures, shown in the "gold-rich grid", lithiation-modulated Ca-Li-Zn phases stabilized by different bonding characteristics, and rare earth-rich polar intermetallics containing unprecedented hydrocarbon-like planar Co-Ge metal clusters and pronounced delocalized multicenter bonding. We will focus mainly on novel structural motifs, bonding analyses, and the role of valence electrons for phase stability.

  5. Atomic structures and covalent-to-metallic transition of lead clusters Pbn (n=2-22)

    International Nuclear Information System (INIS)

    Wang Baolin; Zhao Jijun; Chen Xiaoshuang; Shi Daning; Wang Guanghou

    2005-01-01

    The lowest-energy structures and electronic properties of the lead clusters are studied by density-functional-theory calculations with Becke-Lee-Yang-Parr gradient correction. The lowest-energy structures of Pb n (n=2-22) clusters are determined from a number of structural isomers, which are generated from empirical genetic algorithm simulations. The competition between atom-centered compact structures and layered stacking structures leads to the alternative appearance of the two types of structures as global minimum. The size evolution of geometric and electronic properties from covalent bonding towards bulk metallic behavior in Pb clusters is discussed

  6. Relative importance of current and past landscape structure and local habitat conditions for plant species richness in dry grassland-like forest openings.

    Science.gov (United States)

    Husáková, Iveta; Münzbergová, Zuzana

    2014-01-01

    In fragmented landscapes, plant species richness may depend not only on local habitat conditions but also on landscape structure. In addition, both present and past landscape structure may be important for species richness. There are, however, only a few studies that have investigated the relative importance of all of these factors. The aim of this study was to examine the effect of current and past landscape structures and habitat conditions on species richness at dry grassland-like forest openings in a forested landscape and to assess their relative importance for species richness. We analyzed information on past and present landscape structures using aerial photographs from 1938, 1973, 1988, 2000 and 2007. We calculated the area of each locality and its isolation in the present and in the past and the continuity of localities in GIS. At each locality, we recorded all vascular plant species (296 species in 110 forest openings) and information on abiotic conditions of the localities. We found that the current species richness of the forest openings was significantly determined by local habitat conditions as well as by landscape structure in the present and in the past. The highest species richness was observed on larger and more heterogeneous localities with rocks and shallow soils, which were already large and well connected to other localities in 1938. The changes in the landscape structure in the past can thus have strong effects on current species richness. Future studies attempting to understand determinants of species diversity in fragmented landscapes should also include data on past landscape structure, as it may in fact be more important than the present structure.

  7. Slow Cooling in Low Metallicity Clouds: An Origin of Globular Cluster Bimodality?

    Science.gov (United States)

    Fernandez, Ricardo; Bryan, Greg L.

    2018-05-01

    We explore the relative role of small-scale fragmentation and global collapse in low-metallicity clouds, pointing out that in such clouds the cooling time may be longer than the dynamical time, allowing the cloud to collapse globally before it can fragment. This, we suggest, may help to explain the formation of the low-metallicity globular cluster population, since such dense stellar systems need a large amount of gas to be collected in a small region (without significant feedback during the collapse). To explore this further, we carry out numerical simulations of low-metallicity Bonner-Ebert stable gas clouds, demonstrating that there exists a critical metallicity (between 0.001 and 0.01 Z⊙) below which the cloud collapses globally without fragmentation. We also run simulations including a background radiative heating source, showing that this can also produce clouds that do not fragment, and that the critical metallicity - which can exceed the no-radiation case - increases with the heating rate.

  8. Searching for Be stars in the open cluster NGC 663

    Energy Technology Data Exchange (ETDEWEB)

    Yu, P. C.; Lin, C. C.; Chen, W. P.; Lee, C. D.; Ip, W. H.; Ngeow, C. C. [Graduate Institute of Astronomy, National Central University, 300 Jhongda Road, Jhongli 32001, Taiwan (China); Laher, Russ; Surace, Jason [Spitzer Science Center, California Institute of Technology, M/S 314-6, Pasadena, CA 91125 (United States); Kulkarni, Shrinivas R. [Division of Physics, Mathematics and Astronomy, California Institute of Technology, Pasadena, CA 91125 (United States)

    2015-02-01

    We present Be star candidates in the open cluster NGC 663, identified by Hα imaging photometry with the Palomar Transient Factory Survey, as a pilot program to investigate how the Be star phenomena, the emission spectra, extended circumstellar envelopes, and fast rotation, correlate with massive stellar evolution. Stellar membership of the candidates was verified by 2MASS magnitudes and colors and by proper motions (PMs). We discover four new Be stars and exclude one known Be star from being a member due to its inconsistent PMs. The fraction of Be stars to member stars [N(Be)/N(members)] in NGC 663 is 3.5%. The spectral type of the 34 Be stars in NGC 663 shows bimodal peaks at B0–B2 and B5–B7, which is consistent with the statistics in most star clusters. Additionally, we also discover 23 emission-line stars of different types, including non-member Be stars, dwarfs, and giants.

  9. The Blue Hook Populations of Massive Globular Clusters

    Science.gov (United States)

    Brown, Thomas

    2006-07-01

    Blue hook stars are a class of hot { 35,000 K} subluminous horizontal branch stars that have been recently discovered using HST ultraviolet images of the globular clusters omega Cen and NGC 2808. These stars occupy a region of the HR diagram that is unexplained by canonical stellar evolution theory. Using new theoretical evolutionary and atmospheric models, we have shown that the blue hook stars are very likely the progeny of stars that undergo extensive internal mixing during a late helium core flash on the white dwarf cooling curve. This "flash mixing" produces an enormous enhancement of the surface helium and carbon abundances, which suppresses the flux in the far ultraviolet. Although flash mixing is more likely to occur in stars that are born with high helium abundances, a high helium abundance, by itself, does not explain the presence of a blue hook population - flash mixing of the envelope is required. We propose ACS ultraviolet {SBC/F150LP and HRC/F250W} observations of the five additional globular clusters for which the presence of blue hook stars is suspected from longer wavelength observations. Like omega Cen and NGC 2808, these five targets are also among the most massive globular clusters, because less massive clusters show no evidence for blue hook stars. Because our targets span 1.5 dex in metallicity, we will be able to test our prediction that flash-mixing should be less drastic in metal-rich blue hook stars. In addition, our observations will test the hypothesis that blue hook stars only form in globular clusters massive enough to retain the helium-enriched ejecta from the first stellar generation. If this hypothesis is correct, then our observations will yield important constraints on the chemical evolution and early formation history in globular clusters, as well as the role of helium self-enrichment in producing blue horizontal branch morphologies and multiple main sequence turnoffs. Finally, our observations will provide new insight into the

  10. Photometric search for variable stars in the young open cluster Berkeley 59

    Science.gov (United States)

    Lata, Sneh; Pandey, A. K.; Maheswar, G.; Mondal, Soumen; Kumar, Brijesh

    2011-12-01

    We present the time series photometry of stars located in the extremely young open cluster Berkeley 59. Using the 1.04-m telescope at Aryabhatta Research Institute of Observational Sciences (ARIES), Nainital, we have identified 42 variables in a field of ˜13 × 13 arcmin2 around the cluster. The probable members of the cluster have been identified using a (V, V-I) colour-magnitude diagram and a (J-H, H-K) colour-colour diagram. 31 variables have been found to be pre-main-sequence stars associated with the cluster. The ages and masses of the pre-main-sequence stars have been derived from the colour-magnitude diagram by fitting theoretical models to the observed data points. The ages of the majority of the probable pre-main-sequence variable candidates range from 1 to 5 Myr. The masses of these pre-main-sequence variable stars have been found to be in the range of ˜0.3 to ˜3.5 M⊙, and these could be T Tauri stars. The present statistics reveal that about 90 per cent T Tauri stars have period dispersal of the discs of relatively massive stars.

  11. The effect of metal-rich growth conditions on the microstructure of Sc{sub x}Ga{sub 1-x}N films grown using molecular beam epitaxy

    Energy Technology Data Exchange (ETDEWEB)

    Tsui, H.C.L.; Moram, M.A. [Department of Materials, Imperial College London (United Kingdom); Goff, L.E. [Department of Materials, Imperial College London (United Kingdom); Department of Physics, University of Cambridge (United Kingdom); Barradas, N.P. [CTN - Centro de Ciencias e Tecnologias Nucleares, Instituto Superior Tecnico, Universidade de Lisboa, Bobadela LRS (Portugal); Alves, E. [IPFN - Instituto de Plasmas e Fusao Nuclear, Lisboa (Portugal); Laboratorio de Aceleradores e Tecnologias de Radiacao, Instituto Superior Tecnico, Universidade de Lisboa, Bobadela LRS (Portugal); Pereira, S. [CICECO and Department of Physics, Universidade de Aveiro (Portugal); Beere, H.E.; Farrer, I.; Nicoll, C.A.; Ritchie, D.A. [Department of Physics, University of Cambridge (United Kingdom)

    2015-12-15

    Epitaxial Sc{sub x}Ga{sub 1-x}N films with 0 ≤ x ≤ 0.50 were grown using molecular beam epitaxy under metal-rich conditions. The Sc{sub x}Ga{sub 1-x}N growth rate increased with increasing Sc flux despite the use of metal-rich growth conditions, which is attributed to the catalytic decomposition of N{sub 2} induced by the presence of Sc. Microstructural analysis showed that phase-pure wurtzite Sc{sub x}Ga{sub 1-x}N was achieved up to x = 0.26, which is significantly higher than that previously reported for nitrogen-rich conditions, indicating that the use of metal-rich conditions can help to stabilise wurtzite phase Sc{sub x}Ga{sub 1-x}N. (copyright 2015 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  12. Irradiation characteristics of metal-cluster-complex ions containing diverse multi-elements with large mass differences

    International Nuclear Information System (INIS)

    Fujiwara, Yukio; Kondou, Kouji; Teranishi, Yoshikazu; Nonaka, Hidehiko; Saito, Naoaki; Fujimoto, Toshiyuki; Kurokawa, Akira; Ichimura, Shingo; Tomita, Mitsuhiro

    2007-01-01

    Tetrairidium dodecacarbonyl, Ir 4 (CO) 12 , is a metal cluster complex which has a molecular weight of 1104.9. Using a metal-cluster-complex ion source, the interaction between Ir 4 (CO) n + ions (n=0-12) and silicon substrates was studied at a beam energy ranging from 2keV to 10keV at normal incidence. By adjusting Wien-filter voltage, the influence of CO ligands was investigated. Experimental results showed that sputtering yield of silicon bombarded with Ir 4 (CO) n + ions at 10keV decreased with the number of CO ligands. In the case of 2keV, deposition tended to be suppressed by removing CO ligands from the impinging cluster ions. The influence of CO ligands was explained by considering changes in surface properties caused by the irradiation of Ir 4 (CO) n + ions. It was also found that the bombardment with Ir 4 (CO) 7 + ions at 2.5keV caused deposition on silicon target

  13. Clusters of atoms and molecules theory, experiment, and clusters of atoms

    CERN Document Server

    1994-01-01

    Clusters of Atoms and Molecules is devoted to theoretical concepts and experimental techniques important in the rapidly expanding field of cluster science. Cluster properties are dicussed for clusteres composed of alkali metals, semiconductors, transition metals, carbon, oxides and halides of alkali metals, rare gases, and neutral molecules. The book is composed of several well-integrated treatments all prepared by experts. Each contribution starts out as simple as possible and ends with the latest results so that the book can serve as a text for a course, an introduction into the field, or as a reference book for the expert.

  14. Structure of s - p bonded metal clusters with 8, 20 and 40 valence electrons

    International Nuclear Information System (INIS)

    Kumar, V.

    1992-10-01

    From studies on some clusters of metals and semiconductors, there appear some similarities in the structure of clusters with a given number of atoms and having the number of valence electrons corresponding to a shell closing. Here we present results of the atomic and electronic structure of a few other clusters with 20 and 40 valence electrons, namely Sb 4 , Sn 5 and Sb 8 using the density functional molecular dynamics method. We suggest that the similarities in the structure and deviation from them may help to understand bonding characteristics in clusters and its evolution to bulk behaviour. Our results on Sb 8 cluster are preliminary but indicate that above room temperature its structure is two weakly interacting tetrahedra which is in general agreement with the observation of predominently antimony tetramers at T > 300 K. (author). 16 refs, 2 figs

  15. Linked-cluster perturbation theory for closed and open-shell systems: derivation of effective π-electron hamiltonians

    International Nuclear Information System (INIS)

    Brandow, B.H.

    1977-01-01

    The Brueckner--Goldstone form of linked-cluster perturbation theory is derived, together with its open-shell analog, by an elementary time-independent approach. This serves to focus attention on the physical interpretation of the results. The open-shell expansion is used to provide a straightforward justification for the effective π-electron Hamiltonians of planar organic molecules

  16. High-resolution spectroscopic observations of binary stars and yellow stragglers in three open clusters: NGC 2360, NGC 3680, and NGC 5822

    Energy Technology Data Exchange (ETDEWEB)

    Sales Silva, J. V.; Peña Suárez, V. J.; Katime Santrich, O. J.; Pereira, C. B.; Drake, N. A.; Roig, F., E-mail: joaovictor@on.br, E-mail: jearim@on.br, E-mail: osantrich@on.br, E-mail: claudio@on.br, E-mail: drake@on.br, E-mail: froig@on.br [Observatório Nacional/MCT, Rua Gen. José Cristino, 77, 20921-400 Rio de Janeiro (Brazil)

    2014-11-01

    Binary stars in open clusters are very useful targets in constraining the nucleosynthesis process. The luminosities of the stars are known because the distances of the clusters are also known, so chemical peculiarities can be linked directly to the evolutionary status of a star. In addition, binary stars offer the opportunity to verify a relationship between them and the straggler population in both globular and open clusters. We carried out a detailed spectroscopic analysis to derive the atmospheric parameters for 16 red giants in binary systems and the chemical composition of 11 of them in the open clusters NGC 2360, NGC 3680, and NGC 5822. We obtained abundances of C, N, O, Na, Mg, Al, Ca, Si, Ti, Ni, Cr, Y, Zr, La, Ce, and Nd. The atmospheric parameters of the studied stars and their chemical abundances were determined using high-resolution optical spectroscopy. We employ the local thermodynamic equilibrium model atmospheres of Kurucz and the spectral analysis code MOOG. The abundances of the light elements were derived using the spectral synthesis technique. We found that the stars NGC 2360-92 and 96, NGC 3680-34, and NGC 5822-4 and 312 are yellow straggler stars. We show that the spectra of NGC 5822-4 and 312 present evidence of contamination by an A-type star as a secondary star. For the other yellow stragglers, evidence of contamination is given by the broad wings of the Hα. Detection of yellow straggler stars is important because the observed number can be compared with the number predicted by simulations of binary stellar evolution in open clusters. We also found that the other binary stars are not s-process enriched, which may suggest that in these binaries the secondary star is probably a faint main-sequence object. The lack of any s-process enrichment is very useful in setting constraints for the number of white dwarfs in the open cluster, a subject that is related to the birthrate of these kinds of stars in open clusters and also to the age of a

  17. Open clusters. I. Fundamental parameters of B stars in NGC 3766 and NGC 4755

    Science.gov (United States)

    Aidelman, Y.; Cidale, L. S.; Zorec, J.; Arias, M. L.

    2012-08-01

    Context. Spectroscopic investigations of galactic open clusters are scarce and limited to a reduced sample of cluster members. Aims: We intend to perform a complete study of the physical parameters of two galactic clusters as well as of their individual members. Methods: To carry out this study, we used the BCD (Barbier-Chalonge-Divan) spectrophotometric system, which is based on the study of the Balmer discontinuity and is independent of interstellar and circumstellar extinction. Additional physical properties were derived from the line profiles (FWHM) and stellar evolution models. We analyzed low-resolution spectra around the Balmer discontinuity for normal B-type and Be stars in two open clusters: NGC 3766 and NGC 4755. We determined the stellar fundamental parameters, such as effective temperatures, surface gravities, spectral types, luminosity classes, absolute and bolometric magnitudes, and color gradient excesses. The stellar rotation velocity was also determined. Complementary information, mainly stellar mass, age, and radius of the star population were calculated using stellar evolution models. In some cases, the stellar fundamental parameters were derived for the first time. The obtained results allowed us also to determine the reddening, age, and distance to the clusters. Results: The cluster parameters obtained through the BCD method agree very well with those derived from classical methods based on photometric data. The BCD system also provides physical properties of the star members. This study enables us to test the good behavior of Mbol(λ1,D)-calibrations and detect systematic discrepancies between log g estimates from model atmospheres and those derived from stellar evolution models. To improve our knowledge on the formation and evolution of the clusters, more statistical studies on the initial mass luminosity and angular momentum distributions should be addressed. Therefore, the BCD spectrophotometric system could be a powerful tool for studying

  18. Atmospheric Parameters and Metallicities for 2191 Stars in the Globular Cluster M4

    Science.gov (United States)

    Malavolta, Luca; Sneden, Christopher; Piotto, Giampaolo; Milone, Antonino P.; Bedin, Luigi R.; Nascimbeni, Valerio

    2014-02-01

    We report new metallicities for stars of Galactic globular cluster M4 using the largest number of stars ever observed at high spectral resolution in any cluster. We analyzed 7250 spectra for 2771 cluster stars gathered with the Very Large Telescope (VLT) FLAMES+GIRAFFE spectrograph at VLT. These medium-resolution spectra cover a small wavelength range, and often have very low signal-to-noise ratios. We approached this data set by reconsidering the whole method of abundance analysis of large stellar samples from beginning to end. We developed a new algorithm that automatically determines the atmospheric parameters of a star. Nearly all of the data preparation steps for spectroscopic analyses are processed on the syntheses, not the observed spectra. For 322 red giant branch (RGB) stars with V 14.7, we obtain lang[Fe/H]rang = -1.16 (σ = 0.09) after fixing the microturbulent velocity. These values are consistent with previous studies that have performed detailed analyses of brighter RGB stars at higher spectroscopic resolution and wavelength coverage. It is not clear if the small mean metallicity difference between brighter and fainter M4 members is real or is the result of the low signal-to-noise characteristics of the fainter stars. The strength of our approach is shown by recovering a metallicity close to a single value for more than 2000 stars, using a data set that is non-optimal for atmospheric analyses. This technique is particularly suitable for noisy data taken in difficult observing conditions.

  19. SOLAR-LIKE OSCILLATIONS IN A METAL-POOR GLOBULAR CLUSTER WITH THE HUBBLE SPACE TELESCOPE

    International Nuclear Information System (INIS)

    Stello, Dennis; Gilliland, Ronald L.

    2009-01-01

    We present analyses of variability in the red giant stars in the metal-poor globular cluster NGC 6397, based on data obtained with the Hubble Space Telescope. We use a nonstandard data reduction approach to turn a 23 day observing run originally aimed at imaging the white dwarf population, into time-series photometry of the cluster's highly saturated red giant stars. With this technique we obtain noise levels in the final power spectra down to 50 parts per million, which allows us to search for low-amplitude solar-like oscillations. We compare the observed excess power seen in the power spectra with estimates of the typical frequency range, frequency spacing, and amplitude from scaling the solar oscillations. We see evidence that the detected variability is consistent with solar-like oscillations in at least one and perhaps up to four stars. With metallicities 2 orders of magnitude lower than those of the Sun, these stars present so far the best evidence of solar-like oscillations in such a low-metallicity environment.

  20. Gaia Data Release 1 Open cluster astrometry: performance, limitations, and future prospects

    Czech Academy of Sciences Publication Activity Database

    van Leeuwen, F.; Vallenari, A.; Jordi, C.; Lindegren, L.; Bastian, U.; Prusti, T.; de Bruijne, J.H.J.; Brown, A.G.A.; Babusiaux, C.; Bailer-Jones, C.A.L.; Fuchs, Jan; Koubský, Pavel; Votruba, Viktor

    2017-01-01

    Roč. 601, May (2017), A19/1-A19/65 E-ISSN 1432-0746 R&D Projects: GA MŠk(CZ) LG15010 Grant - others:ESA(XE) ESA-PECS project No. 98058 Institutional support: RVO:67985815 Keywords : astrometry * open clusters and associations * proper motion and parallax Subject RIV: BN - Astronomy , Celestial Mechanics, Astrophysics OBOR OECD: Astronomy (including astrophysics,space science) Impact factor: 5.014, year: 2016

  1. Do protein crystals nucleate within dense liquid clusters?

    International Nuclear Information System (INIS)

    Maes, Dominique; Vorontsova, Maria A.; Potenza, Marco A. C.; Sanvito, Tiziano; Sleutel, Mike; Giglio, Marzio; Vekilov, Peter G.

    2015-01-01

    The evolution of protein-rich clusters and nucleating crystals were characterized by dynamic light scattering (DLS), confocal depolarized dynamic light scattering (cDDLS) and depolarized oblique illumination dark-field microscopy. Newly nucleated crystals within protein-rich clusters were detected directly. These observations indicate that the protein-rich clusters are locations for crystal nucleation. Protein-dense liquid clusters are regions of high protein concentration that have been observed in solutions of several proteins. The typical cluster size varies from several tens to several hundreds of nanometres and their volume fraction remains below 10 −3 of the solution. According to the two-step mechanism of nucleation, the protein-rich clusters serve as locations for and precursors to the nucleation of protein crystals. While the two-step mechanism explained several unusual features of protein crystal nucleation kinetics, a direct observation of its validity for protein crystals has been lacking. Here, two independent observations of crystal nucleation with the proteins lysozyme and glucose isomerase are discussed. Firstly, the evolutions of the protein-rich clusters and nucleating crystals were characterized simultaneously by dynamic light scattering (DLS) and confocal depolarized dynamic light scattering (cDDLS), respectively. It is demonstrated that protein crystals appear following a significant delay after cluster formation. The cDDLS correlation functions follow a Gaussian decay, indicative of nondiffusive motion. A possible explanation is that the crystals are contained inside large clusters and are driven by the elasticity of the cluster surface. Secondly, depolarized oblique illumination dark-field microscopy reveals the evolution from liquid clusters without crystals to newly nucleated crystals contained in the clusters to grown crystals freely diffusing in the solution. Collectively, the observations indicate that the protein-rich clusters in

  2. DETECTION OF SOLAR-LIKE OSCILLATIONS FROM KEPLER PHOTOMETRY OF THE OPEN CLUSTER NGC 6819

    International Nuclear Information System (INIS)

    Stello, Dennis; Bedding, Timothy R.; Huber, Daniel; Basu, Sarbani; Bruntt, Hans; Mosser, BenoIt; Barban, Caroline; Goupil, Marie-Jo; Stevens, Ian R.; Chaplin, William J.; Elsworth, Yvonne P.; Hekker, Saskia; Brown, Timothy M.; Christensen-Dalsgaard, Joergen; Kjeldsen, Hans; Arentoft, Torben; Gilliland, Ronald L.; Ballot, Jerome; GarcIa, Rafael A.; Mathur, Savita

    2010-01-01

    Asteroseismology of stars in clusters has been a long-sought goal because the assumption of a common age, distance, and initial chemical composition allows strong tests of the theory of stellar evolution. We report results from the first 34 days of science data from the Kepler Mission for the open cluster NGC 6819-one of the four clusters in the field of view. We obtain the first clear detections of solar-like oscillations in the cluster red giants and are able to measure the large frequency separation, Δν, and the frequency of maximum oscillation power, ν max . We find that the asteroseismic parameters allow us to test cluster membership of the stars, and even with the limited seismic data in hand, we can already identify four possible non-members despite their having a better than 80% membership probability from radial velocity measurements. We are also able to determine the oscillation amplitudes for stars that span about 2 orders of magnitude in luminosity and find good agreement with the prediction that oscillation amplitudes scale as the luminosity to the power of 0.7. These early results demonstrate the unique potential of asteroseismology of the stellar clusters observed by Kepler.

  3. Order and chaos in nuclear and metal cluster deformation

    International Nuclear Information System (INIS)

    Radu, S.

    1995-08-01

    The vast amount of nuclear and metal cluster data indicates that shell structure and deformation are two simultaneous properties. A conflicting situation is therefore encountered as the shell structure, a firm expression of order, is apparently not compatible with the non-integrable nature of the models incorporating deformation. The main issue covered in this thesis is the intricate connection between deformation and chaotic behaviour in deformation models pertinent to nuclear structure and metal cluster physics. It is shown that, at least in some cases, it is possible to reconcile the occurrence of shell structure with non-integrability. The coupling of an axially deformed harmonic oscillator to an axially symmetric octupole term renders the problem non-integrable. The chaotic character of the motion is strongly dependent on the type of deformation, in that a prolate shape shows virtually no chaos, while in an oblate case the motion exhibits fully developed chaos when the octupole term is switched on. Whereas the problem is non-integrable, the quantum mechanical spectrum nevertheless shows some shell structure in the prolate case for particular, yet fairly large octupole strengths; for spherical or oblate deformation the shell structure disappears. This result is explained in terms of classical periodic orbits which are found by employing the 'removal of resonances method'. Particular emphasis is put on the effect of the hexadecapole deformation which is important in fission processes. The combined effect of octupole and hexadecapole deformation leads to important conclusions for the experimental work as a high degree of ambiguity is signaled for the interpretation of data. The ambiguity results from the discovery of a mutual cancellation of the octupole and hexadecapole deformation in prolate superdeformed systems. The phenomenological Nilsson model is treated in a similar way. It is argued that while in nuclei it produces good results for the low-lying levels

  4. Photobiont diversity in lichens from metal-rich substrata based on ITS rDNA sequences.

    Science.gov (United States)

    Backor, Martin; Peksa, Ondrej; Skaloud, Pavel; Backorová, Miriam

    2010-05-01

    The photobiont is considered as the more sensitive partner of lichen symbiosis in metal pollution. For this reason the presence of a metal tolerant photobiont in lichens may be a key factor of ecological success of lichens growing on metal polluted substrata. The photobiont inventory was examined for terricolous lichen community growing in Cu mine-spoil heaps derived by historical mining. Sequences of internal transcribed spacer (ITS) were phylogenetically analyzed using maximum likelihood analyses. A total of 50 ITS algal sequences were obtained from 22 selected lichen taxa collected at three Cu mine-spoil heaps and two control localities. Algae associated with Cladonia and Stereocaulon were identified as members of several Asterochloris lineages, photobionts of cetrarioid lichens clustered with Trebouxia hypogymniae ined. We did not find close relationship between heavy metal content (in localities as well as lichen thalli) and photobiont diversity. Presence of multiple algal genotypes in single lichen thallus has been confirmed. Copyright 2009 Elsevier Inc. All rights reserved.

  5. The enigma of the open cluster M29 (NGC 6913) solved

    Energy Technology Data Exchange (ETDEWEB)

    Straižys, V.; Milašius, K.; Černis, K.; Kazlauskas, A.; Zdanavičius, K.; Zdanavičius, J.; Laugalys, V. [Institute of Theoretical Physics and Astronomy, Vilnius University, Goštauto 12, Vilnius LT-01108 (Lithuania); Boyle, R. P. [Vatican Observatory Research Group, Steward Observatory, Tucson, AZ 85721 (United States); Vrba, F. J. [U.S. Naval Observatory Flagstaff Station, P.O. Box 1149, Flagstaff, AZ 86002 (United States); Munari, U. [INAF Astronomical Observatory of Padova, I-36012, Asiago (VI) (Italy); Walborn, N. R. [Space Telescope Science Institute, 3700 San Martin Drive, Baltimore, MD 21218 (United States); Janusz, R. [University School " Ignatianum," Cracow (Poland)

    2014-11-01

    Determining the distance to the open cluster M29 (NGC 6913) has proven difficult, with distances determined by various authors differing by a factor of two or more. To solve this problem, we have initiated a new photometric investigation of the cluster in the Vilnius seven-color photometric system, supplementing it with available data in the BV and JHK {sub s} photometric systems and spectra of the nine brightest stars of spectral classes O and B. Photometric spectral classes and luminosities of 260 stars in a 15' × 15' area down to V = 19 mag are used to investigate the interstellar extinction run with distance and to estimate the distance of the Great Cygnus Rift, ∼ 800 pc. The interstellar reddening law in the optical and near-infrared regions is found to be close to normal, with the ratio of extinction to color excess R{sub BV} = 2.87. The extinction A{sub V} of cluster members is between 2.5 and 3.8 mag, with a mean value of 2.97 mag, or E {sub B–V} = 1.03. The average distance of eight stars of spectral types O9-B2 is 1.54 ± 0.15 kpc. Two stars from the seven brightest stars are field stars: HDE 229238 is a background B0.5 supergiant and HD 194378 is a foreground F star. In the intrinsic color-magnitude diagram, seven fainter stars of spectral classes B3-B8 are identified as possible members of the cluster. The 15 selected members of the cluster of spectral classes O9-B8 plotted on the log L/L {sub ☉} versus log T {sub eff} diagram, together with the isochrones from the Padova database, give the age of the cluster as 5 ± 1 Myr.

  6. Unusual Metals in Galactic Center Stars

    Science.gov (United States)

    Hensley, Kerry

    2018-03-01

    while one star is only slightly above solar metallicity, the other is likely more than four times as metal-rich as the Sun.The features in the observed and synthetic spectra generally matched well, but the absorption lines of scandium, vanadium, and yttrium were consistently stronger in the observed spectra than in the synthetic spectra. This led the authors to conclude that these galactic center stars are unusually rich in these metals trace elements that could reveal the formation history of the galactic nucleus.Old Stars, New Trends?Scandium to iron ratio versusiron abundance for stars in the disk of the Milky Way (blue) and the stars in this sample (orange). The value reported for this sample is a 95% lower limit. [Do et al. 2018]For stars in the disk of the Milky Way, the abundance of scandium relative to iron tends to decrease as the overall metallicity increases, but the stars investigated in this study are both iron-rich and anomalously high in scandium. This hints that the nuclear star cluster might represent a distinct stellar population with different metallicity trends.However, its not yet clear what could cause the elevated abundances of scandium, vanadium, and yttrium relative to other metals. Each of these elements is linked to a different source; scandium and vanadium are mainly produced in Type II and Type Ia supernovae, respectively, while yttrium is likely synthesized in asymptotic giant branch stars. Future observations of stars near the center of the Milky Way may help answer this question and further constrain the origin of our galaxys nuclear star cluster.CitationTuan Do et al 2018 ApJL 855 L5. doi:10.3847/2041-8213/aaaec3

  7. New red giant star in the Kepler open cluster NGC 6819

    Science.gov (United States)

    Komucyeya, E.; Abedigamba, O. P.; Jurua, E.; Anguma, S. K.

    2018-05-01

    A recent study indicated that 39 red giant stars showing solar-like oscillations were discovered in the field of Kepleropen cluster NGC 6819. The study was based on photometric distance estimates of 27 stars out of the 39. Using photometric method alone may not be adequate to confirm the membership of these stars. The stars were not previously known in literature to belong to the open cluster NGC 6819. In this study, Kepler data was used to study the membership of the 27 stars. A plot of apparent magnitude as a function of the large frequency separation, supplemented with the proper motion and radial velocity values from literature revealed KIC 5112840 to lie on the same plane with the well known members of the cluster. Echelle diagram was constructed, and the median gravity-mode period spacings (ΔP) calculated for KIC 5112840. A value of ΔP = 66.3 s was obtained, thus placing the red giant star KIC 5112840 on the Red Giant Branch stage of evolution. Our evolutionary status result using the approach in this paper is in agreement with what is in the available literature.

  8. Giant metal sputtering yields induced by 20-5000 keV/atom gold clusters

    International Nuclear Information System (INIS)

    Andersen, H.H.; Brunelle, A.; Della-Negra, S.; Depauw, J.; Jacquet, D.; Le Beyec, Y.

    1997-01-01

    Very large non-linear effects have been found in cluster-induced metal sputtering over a broad projectile energy interval for the first time. Recently available cluster beams from tandem accelerators have allowed sputtering yield measurements to be made with Au 1 to Au 5 from 20 keV/atom to 5 MeV/atom. The cluster-sputtering yield maxima were found at the same total energy but not at the same energy/atom as expected. For Au 5 a yield as high as 3000 was reached at 150 keV/atom while the Au 1 yield was only 55 at the same velocity. The Sigmund-Claussen thermal spike theory, which fits published data at low energy, cannot reproduce our extended new data set. (author)

  9. Mitigation effects of silicon rich amendments on heavy metal accumulation in rice (Oryza sativa L.) planted on multi-metal contaminated acidic soil.

    Science.gov (United States)

    Gu, Hai-Hong; Qiu, Hao; Tian, Tian; Zhan, Shu-Shun; Deng, Teng-Hao-Bo; Chaney, Rufus L; Wang, Shi-Zhong; Tang, Ye-Tao; Morel, Jean-Louis; Qiu, Rong-Liang

    2011-05-01

    The mechanisms of stabilization by silicon-rich amendments of cadmium, zinc, copper and lead in a multi-metal contaminated acidic soil and the mitigation of metal accumulation in rice were investigated in this study. The results from a pot experiment indicated that the application of fly ash (20 and 40gkg(-1)) and steel slag (3 and 6gkg(-1)) increased soil pH from 4.0 to 5.0-6.4, decreased the phytoavailability of heavy metals by at least 60%, and further suppressed metal uptake by rice. Diffusion gradient in thin-film measurement showed the heavy metal diffusion fluxes from soil to solution decreased by greater than 84% after remediation. X-ray diffraction analysis indicated the mobile metals were mainly deposited as their silicates, phosphates and hydroxides in amended treatments. Moreover, it was found metal translocation from stem to leaf was dramatically restrained by adding amendments, which might be due to the increase of silicon concentration and co-precipitation with heavy metals in stem. Finally, a field experiment showed the trace element concentrations in polished rice treated with amendments complied with the food safety standards of China. These results demonstrated fly ash and steel slag could be effective in mitigating heavy metal accumulation in rice grown on multi-metal contaminated acidic soils. Copyright © 2011 Elsevier Ltd. All rights reserved.

  10. The incidence of chemically peculiar stars in open clusters

    Energy Technology Data Exchange (ETDEWEB)

    Netopil, M.

    2013-07-01

    The formation and evolution of chemically peculiar (CP) stars is still a matter of debate, although the first representatives were detected already more than 110 years ago. From the astrophysical point of view, these objects are of particular interest, since they combine a wide variety of specific properties. This work deals with a subgroup of CP stars, showing beside overabundances of some iron-peak (e.g. Chromium) and rare earth elements like Europium, also strong ordered magnetic fields as well as a slow rotation. Based on a selection of well investigated close field stars, the possible connections of these properties were examined. However, the main research focus was the analysis of a relationship between the number of CP stars and their age. For this purpose, the results of the extensive Delta-a survey in open clusters were used. This photometric filter system allows an efficient and economic detection of magnetic CP stars due to a characteristic flux depression at 520 nm. Compared to field stars, open clusters offer the big advantage that for example the age and the distance can be determined more accurately on a statistical basis, since all member stars of an open cluster originate more or less at the same time from a single molecular cloud. After the membership analysis of all in Delta a investigated objects and the determination of the cluster parameters, it was shown that the occurrence of CP stars depend on age, but can be explained by the general evolution of stars. This entails amongst others that CP stars show their typical characteristics already as soon as they have arrived the main-sequence, or even before. Furthermore, we were able to detect at least one representative, probably still in its pre-main-sequence phase. (author) [German] Die Entstehung und Entwicklung von chemisch pekuliaren (CP) Sternen ist nach wie vor nicht restlos geklärt, und das obwohl die ersten Vertreter dieser Sterngruppe bereits vor mehr als 110 Jahren entdeckt wurden. Aus

  11. Synthesis and characterization of αzirconium (IV) hydrogenphosphate containing metallic copper clusters

    International Nuclear Information System (INIS)

    Souza, Alexilda Oliveira de; Rangel, Maria do Carmo; Alves, Oswaldo Luiz

    2005-01-01

    The α-zirconium (IV) hydrogenphosphate (α-ZrP) has received great attention in the last years due to its properties like ion exchange, intercalation, ionic conductivity and catalytic activity. This work reports a method to produce metallic copper clusters on α-ZrP to be used as catalysts in petrochemical processes. It was found that the solids were non-crystalline regardless of the uptake of copper and the reduction. The specific surface area increased as a consequence of the increase of the interlayer distance to accept the copper ions between the layers. During the reduction, big clusters of copper (0,5-11μ) with different sizes and shapes were produced. (author)

  12. Linear and nonlinear surface spectroscopy of supported size selected metal clusters and organic adsorbates

    Energy Technology Data Exchange (ETDEWEB)

    Thaemer, Martin Georg

    2012-03-08

    The spectroscopic investigation of supported size selected metal clusters over a wide wavelength range plays an important role for understanding their outstanding catalytic properties. The challenge which must be overcome to perform such measurements is the difficult detection of the weak spectroscopic signals from these samples. As a consequence, highly sensitive spectroscopic methods are applied, such as surface Cavity Ringdown Spectroscopy and surface Second Harmonic Generation Spectroscopy. The spectroscopic apparatus developed is shown to have a sensitivity which is high enough to detect sub-monolayer coverages of adsorbates on surfaces. In the measured spectra of small supported silver clusters of the sizes Ag{sub 4}2, Ag{sub 2}1, Ag{sub 9}, and Ag atoms a stepwise transition from particles with purely metallic character to particles with molecule-like properties can be observed within this size range.

  13. Subspace K-means clustering

    NARCIS (Netherlands)

    Timmerman, Marieke E.; Ceulemans, Eva; De Roover, Kim; Van Leeuwen, Karla

    2013-01-01

    To achieve an insightful clustering of multivariate data, we propose subspace K-means. Its central idea is to model the centroids and cluster residuals in reduced spaces, which allows for dealing with a wide range of cluster types and yields rich interpretations of the clusters. We review the

  14. The post-depositional accumulation of metal-rich cyanide phases in submerged tailings deposits

    International Nuclear Information System (INIS)

    Jambor, J.L.; Martin, A.J.; Gerits, J.

    2009-01-01

    The characterization and accumulation pathway of metal-rich cyanide phases in mine-contaminated Balmer Lake (Ontario, Canada) were assessed through detailed examination of sediment mineralogy and porewater composition. The near-surface deposits in the lake consist of fine-grained calcareous tailings intermixed with natural organic-rich lake sediments. The tailings contain blue to greenish Fe-dominant cyanide that has formed in situ within the tailings. X-ray diffraction confirmed the presence of a mixed ferri/ferrocyanide [Fe 4 III (Fe II (CN) 6 ) 3 ], commonly referred to as 'Prussian Blue' but it is likely other metal-cyanide complexes are present as evidenced by the distinct colour variations. The cyanide phases occur in up to 1 wt.% as discrete particles and as bedded layers, where the cyanide phases act to cement other siliceous tailings components into a heterogeneous blend. Energy Dispersion X-ray Spectroscopy (EDS) analyses indicate that the authigenic cyanide precipitates contain variable amounts of Ni, Cu and Zn. Quantitatively, the cyanide compounds represent the dominant repository for Cu in Balmer Lake sediments. For Ni and Zn, cyanide associations are secondary in importance to Fe oxyhydroxides. High-resolution porewater profiles and solubility considerations suggest that the formation of the cyanide complexes is a feature of historical (pre-1990) conditions when aqueous cyanide concentrations were higher in the lake.

  15. The post-depositional accumulation of metal-rich cyanide phases in submerged tailings deposits

    Energy Technology Data Exchange (ETDEWEB)

    Jambor, J.L. [Leslie Research and Consulting, 316 Rosehill Wynd, Tsawwassen, BC, V4M 3L9 (Canada); Martin, A.J., E-mail: ajm@lorax.ca [Lorax Environmental Services, 2289 Burrard St., Vancouver, BC, V6J 3H9 (Canada); Gerits, J. [Lorax Environmental Services, 2289 Burrard St., Vancouver, BC, V6J 3H9 (Canada)

    2009-12-15

    The characterization and accumulation pathway of metal-rich cyanide phases in mine-contaminated Balmer Lake (Ontario, Canada) were assessed through detailed examination of sediment mineralogy and porewater composition. The near-surface deposits in the lake consist of fine-grained calcareous tailings intermixed with natural organic-rich lake sediments. The tailings contain blue to greenish Fe-dominant cyanide that has formed in situ within the tailings. X-ray diffraction confirmed the presence of a mixed ferri/ferrocyanide [Fe{sub 4}{sup III}(Fe{sup II}(CN){sub 6}){sub 3}], commonly referred to as 'Prussian Blue' but it is likely other metal-cyanide complexes are present as evidenced by the distinct colour variations. The cyanide phases occur in up to 1 wt.% as discrete particles and as bedded layers, where the cyanide phases act to cement other siliceous tailings components into a heterogeneous blend. Energy Dispersion X-ray Spectroscopy (EDS) analyses indicate that the authigenic cyanide precipitates contain variable amounts of Ni, Cu and Zn. Quantitatively, the cyanide compounds represent the dominant repository for Cu in Balmer Lake sediments. For Ni and Zn, cyanide associations are secondary in importance to Fe oxyhydroxides. High-resolution porewater profiles and solubility considerations suggest that the formation of the cyanide complexes is a feature of historical (pre-1990) conditions when aqueous cyanide concentrations were higher in the lake.

  16. Membership, binarity, and rotation of F-G-K stars in the open cluster Blanco 1

    Science.gov (United States)

    Mermilliod, J.-C.; Platais, I.; James, D. J.; Grenon, M.; Cargile, P. A.

    2008-07-01

    Context: The nearby open cluster Blanco 1 is of considerable astrophysical interest for formation and evolution studies of open clusters because it is the third highest Galactic latitude cluster known. It has been observed often, but so far no definitive and comprehensive membership determination is readily available. Aims: An observing programme was carried out to study the stellar population of Blanco 1, and especially the membership and binary frequency of the F5-K0 dwarfs. Methods: We obtained radial-velocities with the CORAVEL spectrograph in the field of Blanco 1 for a sample of 148 F-G-K candidate stars in the magnitude range 10 rate reaches 40% (27/68) if one includes the photometric binaries. The cluster mean heliocentric radial velocity is +5.53 ± 0.11 km s-1 based on the most reliable 49 members. The V sin i distribution is similar to that of the Pleiades, confirming the age similarities between the two clusters. Conclusions: This study clearly demonstrates that, in spite of the cluster's high Galactic latitude, three membership criteria - radial velocity, proper motion, and photometry - are necessary for performing a reliable membership selection. Furthermore, even with accurate and extensive data, ambiguous cases still remain. Based on observations collected with the Danish 1.54-m and the Swiss telescopes at the European Southern Observatory, La Silla, Chile, and with the old YALO 1-m telescope at the Cerro Tololo InterAmerican Observatory, Chile. Table [see full textsee full textsee full textsee full textsee full textsee full text] is also available in electronic form at the CDS via anonymous ftp to cdsarc.u-strasbg.fr (130.79.128.5) or via http://cdsweb.u-strasbg.fr/cgi-bin/qcat?J/A+A/485/95

  17. From linking of metal-oxide building blocks in a dynamic library to giant clusters with unique properties and towards adaptive chemistry.

    Science.gov (United States)

    Müller, Achim; Gouzerh, Pierre

    2012-11-21

    Following Nature's lessons, today chemists can cross the boundary of the small molecule world to construct multifunctional and highly complex molecular nano-objects up to protein size and even cell-like nanosystems showing responsive sensing. Impressive examples emerge from studies of the solutions of some oxoanions of the early transition metals especially under reducing conditions which enable the controlled linking of metal-oxide building blocks. The latter are available from constitutional dynamic libraries, thus providing the option to generate multifunctional unique nanoscale molecular systems with exquisite architectures, which even opens the way towards adaptive and evolutive (Darwinian) chemistry. The present review presents the first comprehensive report of current knowledge (including synthesis aspects not discussed before) regarding the related giant metal-oxide clusters mainly of the type {Mo(57)M'(6)} (M' = Fe(III), V(IV)) (torus structure), {M(72)M'(30)} (M = Mo, M' = V(IV), Cr(III), Fe(III), Mo(V)), {M(72)Mo(60)} (M = Mo, W) (Keplerates), {Mo(154)}, {Mo(176)}, {Mo(248)} ("big wheels"), and {Mo(368)} ("blue lemon") - all having the important transferable pentagonal {(M)M(5)} groups in common. These discoveries expanded the frontiers of inorganic chemistry to the mesoscopic world, while there is probably no collection of discrete inorganic compounds which offers such a versatile chemistry and the option to study new phenomena of interdisciplinary interest. The variety of different properties of the sphere- and wheel-type metal-oxide-based clusters can directly be related to their unique architectures: The spherical Keplerate-type capsules having 20 crown-ether-type pores and tunable internal functionalities allow the investigation of confined matter as well as that of sphere-surface-supramolecular and encapsulation chemistry - including related new aspects of the biologically important hydrophobic effects - but also of nanoscale ion transport and

  18. A New Globular Cluster in the Area of VVVX

    Science.gov (United States)

    Bica, E.; Minniti, D.; Bonatto, C.; Hempel, M.

    2018-06-01

    We communicate the discovery of a new globular cluster in the Galaxy that was first detected on WISE/2MASS images and is now confirmed with VVVX photometry. It is a Palomar-like cluster projected at ℓ = 359.15°, b = 5.73°, and may be related to the bulge. We derive an absolute magnitude of MV ≈ -3.3, thus being an underluminous globular cluster. Our analyses provide a reddening of E(B - V) = 1.08 ± 0.18 and a distance to the Sun d⊙ = 6.3 ± 1 kpc, which implies a current position in the bulge volume. The estimated metallicity is [Fe/H] = -1.5 ± 0.25. It adds to the recently discovered faint globular cluster (Minniti 22) and candidates found with VVV, building up expectations of ≈50 globular clusters yet to be discovered in the bulge. We also communicate the discovery of an old open cluster in the same VVVX tile as the globular cluster. The VVVX photometry provided E(B - V) = 0.62 ± 0.1, d⊙ = 7.6 ± 1 kpc, and an age of 1.5 ± 0.3 Gyr. With a height from the plane of ≈0.8 kpc, it adds to nine Gyr-class clusters recently discovered within 0.8 ⩽ Z ⩽ 2.2 kpc, as recently probed in the single VVV tile b201. We suggest that these findings may be disclosing the thick disk at the bulge, which so far has no open cluster counterpart, and hardly any individual star. Thus, the VVV and VVVX surveys are opening new windows for follow-up studies, to employ present and future generations of large aperture telescopes.

  19. New routes to nitrogen-rich transition metal nitrides: Synthesis of novel polymorphs of Hf3N4

    Science.gov (United States)

    Salamat, Ashkan; Hector, A.; Gray, B.; Kimber, S.; Bouvier, P.; McMillan, P.

    2013-06-01

    One of the most obvious features of transition metal nitride chemistry is that the maximum formal oxidation state of the metal is rarely as high as in the corresponding oxides or fluorides. Much of the interest in the high oxidation phases stems from the desire to identify the next generation of photocatalytic materials with tuneable bandgaps. Experiments in the laser heated diamond anvil cell (LHDAC) between the direct reaction of metals and nitrogen have previously produced a number of important new main group nitride phases. This technique has also demonstrated its potential for formation of new nitrogen-rich transition metal nitride phases. Alternative methods with the development of ``soft'' routes to new phases with high nitrogen content also offer the possibility of obtaining metastable phases through topotactic conversions. Using LHDAC in situ with synchrotron angle dispersive diffraction techniques we have crystallised at high pressures and temperatures two novel polymorphs of Hf3N4. Starting with an amide-derived nanocrystalline Hf3N4 sample we have identified a novel tetragonal (I4/ m) polymorph at 15 GPa and 1500K and a second high pressure orthorhombic (Pnma) polymorph at 30 GPa and 2000 K. This study demonstrates that the combination of precursor-based synthesis and high-pressure crystallization could be very productive in synthesis of such nitrogen-rich phases.

  20. A new family of Ln₇ clusters with an ideal D(3h) metal-centered trigonal prismatic geometry, and SMM and photoluminescence behaviors.

    Science.gov (United States)

    Mazarakioti, Eleni C; Poole, Katye M; Cunha-Silva, Luis; Christou, George; Stamatatos, Theocharis C

    2014-08-14

    The first use of the flexible Schiff base ligand N-salicylidene-2-aminocyclohexanol in metal cluster chemistry has afforded a new family of Ln7 clusters with ideal D(3h) point group symmetry and metal-centered trigonal prismatic topology; solid-state and solution studies revealed SMM and photoluminescence behaviors.

  1. Dynamics of rich clusters of galaxies. I. The Coma cluster

    International Nuclear Information System (INIS)

    Kent, S.M.; Gunn, J.E.

    1982-01-01

    The structure and dynamics of the Coma cluster are analyzed using self-consistent equilibrium dynamical models. Observational material for Coma is culled from a variety of sources. Projected surface, density, and velocity-dispersion profiles are derived extending out to a radius of 3 0 from the cluster center, which are essentially free from field contamination. Segregation of galaxies by luminosity and morphology are discussed and a quantitative estimate of the latter is made. The method of constructing self-consistent dynamical models is discussed. Four different forms of the distribution function are analyzed allowing for different possible dependences of f on energy and angular momentum. Properties of typical models that might resemble actual clusters are presented, and the importance of having velocity-dispersion information is empha sized. The effect of a central massive object such as a cD galaxy on the core structure is illustrated. A comparison of these models with Coma reveals that only models with a distribution function in which the ratio of tangential to radial velocity dispersions is everywhere constant give acceptable fits. In particular, it is possible to rule out models that have isotropic motions in the core and predominantly radial motions in the halo. For H 0 = 50, the best-fitting models give a total projected mass inside 3 0 of 2.9 x 10 15 M/sub sun/ , a core radius of 340--400 kpc (8.5'--10'), an upper limit to any central massive object of approx.10 13 M/sub sun/ , and a mass-to-blue-light ratio of M/L = 181. From cosmological considerations the cluster ''edge'' is determined to lie at rapprox.5 0 --6 0 . The possible distribution of ''dark matter'' in Coma is discussed and it is argued that this distribution cannot be significantly different from that of the galaxies. The dynamics of morphological segregation are examined quantitatively, and are explained at least qualitatively

  2. Ferromagnetism and suppression of metallic clusters in Fe implanted ZnO -- a phenomenon related to defects?

    International Nuclear Information System (INIS)

    Arenholz, Elke; Zhou, S.; Potzger, K.; Talut, G.; Reuther, H.; Kuepper, K.; Grenzer, J.; Xu, Q.; Mucklich, A.; Helm, M.; Fassbender, J.; Arenholz, E.

    2008-01-01

    We investigated ZnO(0001) single crystals annealed in high vacuum with respect to their magnetic properties and cluster formation tendency after implant-doping with Fe. While metallic Fe cluster formation is suppressed, no evidence for the relevance of the Fe magnetic moment to the observed ferromagnetism was found. The latter along with the cluster suppression is discussed with respect to defects in the ZnO host matrix, since the crystalline quality of the substrates was lowered due to the preparation as observed by x-ray diffraction

  3. Formation of transition metal cluster adducts on the surface of single-walled carbon nanotubes: HRTEM studies

    KAUST Repository

    Kalinina, Irina V.

    2014-01-01

    We report the formation of chromium clusters on the outer walls of single-walled carbon nanotubes (SWNTs). The clusters were obtained by reacting purified SWNTs with chromium hexacarbonyl in dibutyl ether at 100°C. The functionalized SWNTs were characterized by thermogravimetic analysis, XPS, and high-resolution TEM. The curvature of the SWNTs and the high mobility of the chromium moieties on graphitic surfaces allow the growth of the metal clusters and we propose a mechanism for their formation. © 2014 Taylor and Francis Group, LLC.

  4. PROTOPLANETARY AND TRANSITIONAL DISKS IN THE OPEN STELLAR CLUSTER IC 2395

    Energy Technology Data Exchange (ETDEWEB)

    Balog, Zoltan [Max Planck Institute for Astronomy, Heidelberg, D-69117 (Germany); Siegler, Nick [NASA Exoplanet Exploration Program, Jet Propulsion Laboratory, California Institute of Technology, 4800 Oak Grove Drive, Pasadena, CA 91109 (United States); Rieke, G. H.; Su, K. Y. L.; Gáspár, András [Steward Observatory, 933 N. Cherry Ave, University of Arizona, Tucson, AZ 85721 (United States); Kiss, L. L. [Konkoly Observatory, Research Center for Astronomy and Earth Sciences, P.O. Box 67, H-1525 Budapest (Hungary); Muzerolle, James [Space Telescope Science Institute, 3700 San Martin Drive, Baltimore, MD 21218 (United States); Gutermuth, R. A. [Department of Astronomy, University of Massachusetts, Amherst, MA (United States); Bell, Cameron P. M. [Institute for Astronomy, ETH Zürich, Wolfgang-Pauli-Strasse 27, 8093, Zürich (Switzerland); Vinkó, J. [Dept. of Optics and Quantum Electronics, University of Szeged, H-6720 Szeged (Hungary); Young, E. T., E-mail: balog@mpia-hd.mpg.de [NASA Ames SOFIA Science Center, N211, Mountain View, CA 94043 (United States)

    2016-11-20

    We present new deep UBVRI images and high-resolution multi-object optical spectroscopy of the young (∼6–10 Myr old), relatively nearby (800 pc) open cluster IC 2395. We identify nearly 300 cluster members and use the photometry to estimate their spectral types, which extend from early B to middle M. We also present an infrared imaging survey of the central region using the IRAC and MIPS instruments on board the Spitzer Space Telescope , covering the wavelength range from 3.6 to 24 μ m. Our infrared observations allow us to detect dust in circumstellar disks originating over a typical range of radii from ∼0.1 to ∼10 au from the central star. We identify 18 Class II, 8 transitional disk, and 23 debris disk candidates, respectively, 6.5%, 2.9%, and 8.3% of the cluster members with appropriate data. We apply the same criteria for transitional disk identification to 19 other stellar clusters and associations spanning ages from ∼1 to ∼18 Myr. We find that the number of disks in the transitional phase as a fraction of the total with strong 24 μ m excesses ([8] – [24] ≥ 1.5) increases from (8.4 ± 1.3)% at ∼3 Myr to (46 ± 5)% at ∼10 Myr. Alternative definitions of transitional disks will yield different percentages but should show the same trend.

  5. High-resolution Spectroscopic Observations of Binary Stars and Yellow Stragglers in Three Open Clusters : NGC 2360, NGC 3680, and NGC 5822

    Science.gov (United States)

    Sales Silva, J. V.; Peña Suárez, V. J.; Katime Santrich, O. J.; Pereira, C. B.; Drake, N. A.; Roig, F.

    2014-11-01

    Binary stars in open clusters are very useful targets in constraining the nucleosynthesis process. The luminosities of the stars are known because the distances of the clusters are also known, so chemical peculiarities can be linked directly to the evolutionary status of a star. In addition, binary stars offer the opportunity to verify a relationship between them and the straggler population in both globular and open clusters. We carried out a detailed spectroscopic analysis to derive the atmospheric parameters for 16 red giants in binary systems and the chemical composition of 11 of them in the open clusters NGC 2360, NGC 3680, and NGC 5822. We obtained abundances of C, N, O, Na, Mg, Al, Ca, Si, Ti, Ni, Cr, Y, Zr, La, Ce, and Nd. The atmospheric parameters of the studied stars and their chemical abundances were determined using high-resolution optical spectroscopy. We employ the local thermodynamic equilibrium model atmospheres of Kurucz and the spectral analysis code MOOG. The abundances of the light elements were derived using the spectral synthesis technique. We found that the stars NGC 2360-92 and 96, NGC 3680-34, and NGC 5822-4 and 312 are yellow straggler stars. We show that the spectra of NGC 5822-4 and 312 present evidence of contamination by an A-type star as a secondary star. For the other yellow stragglers, evidence of contamination is given by the broad wings of the Hα. Detection of yellow straggler stars is important because the observed number can be compared with the number predicted by simulations of binary stellar evolution in open clusters. We also found that the other binary stars are not s-process enriched, which may suggest that in these binaries the secondary star is probably a faint main-sequence object. The lack of any s-process enrichment is very useful in setting constraints for the number of white dwarfs in the open cluster, a subject that is related to the birthrate of these kinds of stars in open clusters and also to the age of a

  6. The next generation Virgo cluster survey. VIII. The spatial distribution of globular clusters in the Virgo cluster

    Energy Technology Data Exchange (ETDEWEB)

    Durrell, Patrick R.; Accetta, Katharine [Department of Physics and Astronomy, Youngstown State University, Youngstown, OH 44555 (United States); Côté, Patrick; Blakeslee, John P.; Ferrarese, Laura; McConnachie, Alan; Gwyn, Stephen [Herzberg Astronomy and Astrophysics, National Research Council, 5071 West Saanich Road, Victoria, BC V9E 2E7 (Canada); Peng, Eric W.; Zhang, Hongxin [Department of Astronomy, Peking University, Beijing 100871 (China); Mihos, J. Christopher [Department of Astronomy, Case Western Reserve University, Cleveland, OH 44106 (United States); Puzia, Thomas H.; Jordán, Andrés [Institute of Astrophysics, Pontificia Universidad Catolica, Av. Vicu' a Mackenna 4860, Macul 7820436, Santiago (Chile); Lançon, Ariane [Observatoire astronomique de Strasbourg, Université de Strasbourg, CNRS, UMR 7550, 11 rue de l' Université, F-67000 Strasbourg (France); Liu, Chengze [Center for Astronomy and Astrophysics, Department of Physics and Astronomy, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai 200240 (China); Cuillandre, Jean-Charles [Canada-France-Hawaii Telescope Corporation, Kamuela, HI 96743 (United States); Boissier, Samuel; Boselli, Alessandro [Aix Marseille Université, CNRS, LAM (Laboratoire d' Astrophysique de Marseille) UMR 7326, F-13388 Marseille (France); Courteau, Stéphane [Department of Physics, Engineering Physics and Astronomy, Queen' s University, Kingston, ON K7L 3N6 (Canada); Duc, Pierre-Alain [AIM Paris Saclay, CNRS/INSU, CEA/Irfu, Université Paris Diderot, Orme des Merisiers, F-91191 Gif sur Yvette cedex (France); Emsellem, Eric [Université de Lyon 1, CRAL, Observatoire de Lyon, 9 av. Charles André, F-69230 Saint-Genis Laval (France); CNRS, UMR 5574, ENS de Lyon (France); and others

    2014-10-20

    We report on a large-scale study of the distribution of globular clusters (GCs) throughout the Virgo cluster, based on photometry from the Next Generation Virgo Cluster Survey (NGVS), a large imaging survey covering Virgo's primary subclusters (Virgo A = M87 and Virgo B = M49) out to their virial radii. Using the g{sub o}{sup ′}, (g' – i') {sub o} color-magnitude diagram of unresolved and marginally resolved sources within the NGVS, we have constructed two-dimensional maps of the (irregular) GC distribution over 100 deg{sup 2} to a depth of g{sub o}{sup ′} = 24. We present the clearest evidence to date showing the difference in concentration between red and blue GCs over the full extent of the cluster, where the red (more metal-rich) GCs are largely located around the massive early-type galaxies in Virgo, while the blue (metal-poor) GCs have a much more extended spatial distribution with significant populations still present beyond 83' (∼215 kpc) along the major axes of both M49 and M87. A comparison of our GC maps to the diffuse light in the outermost regions of M49 and M87 show remarkable agreement in the shape, ellipticity, and boxiness of both luminous systems. We also find evidence for spatial enhancements of GCs surrounding M87 that may be indicative of recent interactions or an ongoing merger history. We compare the GC map to that of the locations of Virgo galaxies and the X-ray intracluster gas, and find generally good agreement between these various baryonic structures. We calculate the Virgo cluster contains a total population of N {sub GC} = 67, 300 ± 14, 400, of which 35% are located in M87 and M49 alone. For the first time, we compute a cluster-wide specific frequency S {sub N,} {sub CL} = 2.8 ± 0.7, after correcting for Virgo's diffuse light. We also find a GC-to-baryonic mass fraction ε {sub b} = 5.7 ± 1.1 × 10{sup –4} and a GC-to-total cluster mass formation efficiency ε {sub t} = 2.9 ± 0.5 × 10{sup –5

  7. The Gaia-ESO Survey: open clusters in Gaia-DR1 . A way forward to stellar age calibration

    Science.gov (United States)

    Randich, S.; Tognelli, E.; Jackson, R.; Jeffries, R. D.; Degl'Innocenti, S.; Pancino, E.; Re Fiorentin, P.; Spagna, A.; Sacco, G.; Bragaglia, A.; Magrini, L.; Prada Moroni, P. G.; Alfaro, E.; Franciosini, E.; Morbidelli, L.; Roccatagliata, V.; Bouy, H.; Bravi, L.; Jiménez-Esteban, F. M.; Jordi, C.; Zari, E.; Tautvaišiene, G.; Drazdauskas, A.; Mikolaitis, S.; Gilmore, G.; Feltzing, S.; Vallenari, A.; Bensby, T.; Koposov, S.; Korn, A.; Lanzafame, A.; Smiljanic, R.; Bayo, A.; Carraro, G.; Costado, M. T.; Heiter, U.; Hourihane, A.; Jofré, P.; Lewis, J.; Monaco, L.; Prisinzano, L.; Sbordone, L.; Sousa, S. G.; Worley, C. C.; Zaggia, S.

    2018-05-01

    Context. Determination and calibration of the ages of stars, which heavily rely on stellar evolutionary models, are very challenging, while representing a crucial aspect in many astrophysical areas. Aims: We describe the methodologies that, taking advantage of Gaia-DR1 and the Gaia-ESO Survey data, enable the comparison of observed open star cluster sequences with stellar evolutionary models. The final, long-term goal is the exploitation of open clusters as age calibrators. Methods: We perform a homogeneous analysis of eight open clusters using the Gaia-DR1 TGAS catalogue for bright members and information from the Gaia-ESO Survey for fainter stars. Cluster membership probabilities for the Gaia-ESO Survey targets are derived based on several spectroscopic tracers. The Gaia-ESO Survey also provides the cluster chemical composition. We obtain cluster parallaxes using two methods. The first one relies on the astrometric selection of a sample of bona fide members, while the other one fits the parallax distribution of a larger sample of TGAS sources. Ages and reddening values are recovered through a Bayesian analysis using the 2MASS magnitudes and three sets of standard models. Lithium depletion boundary (LDB) ages are also determined using literature observations and the same models employed for the Bayesian analysis. Results: For all but one cluster, parallaxes derived by us agree with those presented in Gaia Collaboration (2017, A&A, 601, A19), while a discrepancy is found for NGC 2516; we provide evidence supporting our own determination. Inferred cluster ages are robust against models and are generally consistent with literature values. Conclusions: The systematic parallax errors inherent in the Gaia DR1 data presently limit the precision of our results. Nevertheless, we have been able to place these eight clusters onto the same age scale for the first time, with good agreement between isochronal and LDB ages where there is overlap. Our approach appears promising

  8. The nature and role of the gold-krypton interactions in small neutral gold clusters.

    Science.gov (United States)

    Mancera, Luis A; Benoit, David M

    2015-03-26

    We investigate the nature and role of krypton embedding in small neutral gold clusters. For some of these clusters, we observe a particular site-dependent character of the Kr binding that does not completely follow the criterion of binding at low-coordinated sites, widely accepted for interaction of a noble gas with closed-shell metal systems such as metal surfaces. We aim at understanding the effect of low dimensionality and open-shell electronic structure of the odd-numbered clusters on the noble gas-metal cluster interaction. First, we investigate the role of attractive and repulsive forces, and the frontier molecular orbitals. Second, we investigate the Au-Kr interaction in terms of reactivity and bonding character. We use a reactivity index derived from Fukui formalism, and criteria provided by the electron localization function (ELF), in order to classify the type of bonding. We carry out this study on the minimum energy structures of neutral gold clusters, as obtained using pseudo potential plane-wave density functional theory (DFT). A model is proposed that includes the effect of attractive electrostatic, van der Waals and repulsive forces, together with effects originating from orbital overlap. This satisfactorily explains minimum configurations of the noble gas-gold cluster systems, the site preference of the noble gas atoms, and changes in electronic properties.

  9. New Wolf-Rayet stars in Galactic open clusters - Sher 1 and the giant H II region core Westerlund 2

    Science.gov (United States)

    Moffat, Anthony F. J.; Shara, Michael M.; Potter, Michael

    1991-01-01

    Two new Galactic Wolf-Rayet stars were found in open clusters: a WN4 star in the O9 cluster Sher 1 and a WN7 star in the O7 cluster Westerlund 2. This confirms a previous trend, namely that fainter, hotter WN stars tend to be older than brighter, cooler WN stars. This may be a consequence of evolution via extreme mass loss.

  10. Hierarchical cluster analysis of progression patterns in open-angle glaucoma patients with medical treatment.

    Science.gov (United States)

    Bae, Hyoung Won; Rho, Seungsoo; Lee, Hye Sun; Lee, Naeun; Hong, Samin; Seong, Gong Je; Sung, Kyung Rim; Kim, Chan Yun

    2014-04-29

    To classify medically treated open-angle glaucoma (OAG) by the pattern of progression using hierarchical cluster analysis, and to determine OAG progression characteristics by comparing clusters. Ninety-five eyes of 95 OAG patients who received medical treatment, and who had undergone visual field (VF) testing at least once per year for 5 or more years. OAG was classified into subgroups using hierarchical cluster analysis based on the following five variables: baseline mean deviation (MD), baseline visual field index (VFI), MD slope, VFI slope, and Glaucoma Progression Analysis (GPA) printout. After that, other parameters were compared between clusters. Two clusters were made after a hierarchical cluster analysis. Cluster 1 showed -4.06 ± 2.43 dB baseline MD, 92.58% ± 6.27% baseline VFI, -0.28 ± 0.38 dB per year MD slope, -0.52% ± 0.81% per year VFI slope, and all "no progression" cases in GPA printout, whereas cluster 2 showed -8.68 ± 3.81 baseline MD, 77.54 ± 12.98 baseline VFI, -0.72 ± 0.55 MD slope, -2.22 ± 1.89 VFI slope, and seven "possible" and four "likely" progression cases in GPA printout. There were no significant differences in age, sex, mean IOP, central corneal thickness, and axial length between clusters. However, cluster 2 included more high-tension glaucoma patients and used a greater number of antiglaucoma eye drops significantly compared with cluster 1. Hierarchical cluster analysis of progression patterns divided OAG into slow and fast progression groups, evidenced by assessing the parameters of glaucomatous progression in VF testing. In the fast progression group, the prevalence of high-tension glaucoma was greater and the number of antiglaucoma medications administered was increased versus the slow progression group. Copyright 2014 The Association for Research in Vision and Ophthalmology, Inc.

  11. Electronic structure of vacancies and vacancy clusters in simple metals

    International Nuclear Information System (INIS)

    Manninen, M.; Nieminen, R.M.

    1978-05-01

    The self-consistent density functional approach has been applied in a study of electronic properties of vacancies and vacancy clusters in simple metals. The electron density profiles and potentials have been obtained for spherical voids of varying size. The formation energies and residual resistivities have been calculated for vacancies using both perturbational and variational inclusion of discrete lattice effects. The relation of the void properties to the plane surface ones is studied, and the inadequacy of the jellium-based methods to high-index faces is demonstrated. (author)

  12. Collective-field-corrected strong field approximation for laser-irradiated metal clusters

    International Nuclear Information System (INIS)

    Keil, Th; Bauer, D

    2014-01-01

    The strong field approximation (SFA) formulated in terms of so-called ‘quantum orbits’ led to much insight into intense-laser driven ionization dynamics. In plain SFA, the emitted electron is treated as a free electron in the laser field alone. However, with improving experimental techniques and more advanced numerical simulations, it becomes more and more obvious that the plain SFA misses interesting effects even on a qualitative level. Examples are holographic side lobes, the low-energy structure, radial patterns in photoelectron spectra at low kinetic energies and strongly rotated angular distributions. For this reason, increasing efforts have been recently devoted to Coulomb corrections of the SFA. In the current paper, we follow a similar line but consider ionization of metal clusters. It is known that photoelectrons from clusters can be much more energetic than those emitted from atoms or small molecules, especially if the Mie resonance of the expanding cluster is evoked. We develop a SFA that takes the collective field inside the cluster via the simple rigid-sphere model into account. Our approach is based on field-corrected quantum orbits so that the acceleration process (or any other spectral feature of interest) can be investigated in detail. (paper)

  13. A survey for low-mass stellar and substellar members of the Hyades open cluster

    Science.gov (United States)

    Melnikov, Stanislav; Eislöffel, Jochen

    2018-03-01

    Context. Unlike young open clusters (with ages 2MASS JHKs photometry Results: We present a photometric and proper motion survey covering 23.4 deg2 in the Hyades cluster core region. Using optical/IR colour-magnitude diagrams, we identify 66 photometric cluster member candidates in the magnitude range 14.m7 < I < 20.m5. The proper motion measurements are based on several all-sky surveys with an epoch difference of 60-70 yr for the bright objects. The proper motions allowed us to discriminate the cluster members from field objects and resulted in 14 proper motion members of the Hyades. We rediscover Hy 6 as a proper motion member and classify it as a substellar object candidate (BD) based on the comparison of the observed colour-magnitude diagram with theoretical model isochrones. Conclusions: With our results, the mass function of the Hyades continues to be shallow below 0.15 M⊙ indicating that the Hyades have probably lost their lowest mass members by means of dynamical evolution. We conclude that the Hyades core represents the "VLM/BD desert" and that most of the substeller objects may have already left the volume of the cluster.

  14. Ferromagnetism and suppression of metallic clusters in Fe implanted ZnO: a phenomenon related to defects?

    International Nuclear Information System (INIS)

    Zhou Shengqiang; Potzger, K; Talut, G; Reuther, H; Kuepper, K; Grenzer, J; Xu Qingyu; Muecklich, A; Helm, M; Fassbender, J; Arenholz, E

    2008-01-01

    We investigated ZnO(0 0 0 1) single crystals annealed in high vacuum with respect to their magnetic properties and cluster formation tendency after implant-doping with Fe. While metallic Fe cluster formation is suppressed, no evidence for the relevance of the Fe magnetic moment to the observed ferromagnetism was found. The latter along with the cluster suppression is discussed with respect to defects in the ZnO host matrix, since the crystalline quality of the substrates was lowered due to the preparation as observed by x-ray diffraction

  15. Metals on graphene and carbon nanotube surfaces: From mobile atoms to atomtronics to bulk metals to clusters and catalysts

    KAUST Repository

    Sarkar, Santanu C.

    2014-01-14

    In this Perspective, we present an overview of recent fundamental studies on the nature of the interaction between individual metal atoms and metal clusters and the conjugated surfaces of graphene and carbon nanotube with a particular focus on the electronic structure and chemical bonding at the metal-graphene interface. We discuss the relevance of organometallic complexes of graphitic materials to the development of a fundamental understanding of these interactions and their application in atomtronics as atomic interconnects, high mobility organometallic transistor devices, high-frequency electronic devices, organometallic catalysis (hydrogen fuel generation by photocatalytic water splitting, fuel cells, hydrogenation), spintronics, memory devices, and the next generation energy devices. We touch on chemical vapor deposition (CVD) graphene grown on metals, the reactivity of its surface, and its use as a template for asymmetric graphene functionalization chemistry (ultrathin Janus discs). We highlight some of the latest advances in understanding the nature of interactions between metals and graphene surfaces from the standpoint of metal overlayers deposited on graphene and SWNT thin films. Finally, we comment on the major challenges facing the field and the opportunities for technological applications. © 2013 American Chemical Society.

  16. EXPLORING ANTICORRELATIONS AND LIGHT ELEMENT VARIATIONS IN NORTHERN GLOBULAR CLUSTERS OBSERVED BY THE APOGEE SURVEY

    Energy Technology Data Exchange (ETDEWEB)

    Mészáros, Szabolcs [ELTE Gothard Astrophysical Observatory, H-9704 Szombathely, Szent Imre Herceg st. 112 (Hungary); Martell, Sarah L. [Department of Astrophysics, School of Physics, University of New South Wales, Sydney, NSW 2052 (Australia); Shetrone, Matthew [University of Texas at Austin, McDonald Observatory, Fort Davis, TX 79734 (United States); Lucatello, Sara [INAF-Osservatorio Astronomico di Padova, vicolo dell Osservatorio 5, I-35122 Padova (Italy); Troup, Nicholas W.; Pérez, Ana E. García; Majewski, Steven R. [Department of Astronomy, University of Virginia, Charlottesville, VA 22904-4325 (United States); Bovy, Jo [Institute for Advanced Study, Einstein Drive, Princeton, NJ 08540 (United States); Cunha, Katia [University of Arizona, Tucson, AZ 85719 (United States); García-Hernández, Domingo A.; Prieto, Carlos Allende [Instituto de Astrofísica de Canarias (IAC), E-38200 La Laguna, Tenerife (Spain); Overbeek, Jamie C. [Department of Astronomy, Indiana University, Bloomington, IN 47405 (United States); Beers, Timothy C. [Department of Physics and JINA Center for the Evolution of the Elements, University of Notre Dame, Notre Dame, IN 46556 (United States); Frinchaboy, Peter M. [Texas Christian University, Fort Worth, TX 76129 (United States); Hearty, Fred R.; Schneider, Donald P. [Department of Astronomy and Astrophysics, The Pennsylvania State University, University Park, PA 16802 (United States); Holtzman, Jon [New Mexico State University, Las Cruces, NM 88003 (United States); Nidever, David L. [Department of Astronomy, University of Michigan, Ann Arbor, MI 48109 (United States); Schiavon, Ricardo P. [Astrophysics Research Institute, IC2, Liverpool Science Park, Liverpool John Moores University, 146 Brownlow Hill, Liverpool, L3 5RF (United Kingdom); and others

    2015-05-15

    We investigate the light-element behavior of red giant stars in northern globular clusters (GCs) observed by the SDSS-III Apache Point Observatory Galactic Evolution Experiment. We derive abundances of 9 elements (Fe, C, N, O, Mg, Al, Si, Ca, and Ti) for 428 red giant stars in 10 GCs. The intrinsic abundance range relative to measurement errors is examined, and the well-known C–N and Mg–Al anticorrelations are explored using an extreme-deconvolution code for the first time in a consistent way. We find that Mg and Al drive the population membership in most clusters, except in M107 and M71, the two most metal-rich clusters in our study, where the grouping is most sensitive to N. We also find a diversity in the abundance distributions, with some clusters exhibiting clear abundance bimodalities (for example M3 and M53) while others show extended distributions. The spread of Al abundances increases significantly as cluster average metallicity decreases as previously found by other works, which we take as evidence that low metallicity, intermediate mass AGB polluters were more common in the more metal-poor clusters. The statistically significant correlation of [Al/Fe] with [Si/Fe] in M15 suggests that {sup 28}Si leakage has occurred in this cluster. We also present C, N, and O abundances for stars cooler than 4500 K and examine the behavior of A(C+N+O) in each cluster as a function of temperature and [Al/Fe]. The scatter of A(C+N+O) is close to its estimated uncertainty in all clusters and independent of stellar temperature. A(C+N+O) exhibits small correlations and anticorrelations with [Al/Fe] in M3 and M13, but we cannot be certain about these relations given the size of our abundance uncertainties. Star-to-star variations of α-element (Si, Ca, Ti) abundances are comparable to our estimated errors in all clusters.

  17. Metal uptake by native plants and revegetation potential of mining sulfide-rich waste-dumps.

    Science.gov (United States)

    Gomes, Patrícia; Valente, Teresa; Pamplona, Jorge; Braga, Maria Amália Sequeira; Pissarra, José; Gil, José António Grande; de la Torre, Maria Luisa

    2014-01-01

    Waste dumps resulting from metal exploitation create serious environmental damage, providing soil and water degradation over long distances. Phytostabilization can be used to remediate these mining sites. The present study aims to evaluate the behavior of selected plant species (Erica arborea, Ulex europaeus, Agrostis delicatula, and Cytisus multiflorus) that grow spontaneously in three sulfide-rich waste-dumps (Lapa Grande, Cerdeirinha, and Penedono, Portugal). These sites represent different geological, climatic and floristic settings. The results indicate distinctive levels and types of metal contamination: Penedono presents highest sulfate and metal contents, especially As, with low levels of Fe. In contrast, at Lapa Grande and Cerdeirinha Fe, Mn, and Zn are the dominant metals. In accordance, each waste dump develops a typical plant community, providing a specific vegetation inventory. At Penedono, Agrostis delicatula accumulates As, Pb, Cu, Mn, and Zn, showing higher bioaccumulation factors (BF) for Mn (32.1) and As (24.4). At Cerdeirinha, Ulex europaeus has the highest BF for Pb (984), while at Lapa Grande, Erica arborea presents high BF for Mn (9.8) and Pb (8.1). Regarding TF, low values were obtained for most of the metals, especially As (TF < 1). Therefore, the results obtained from representative plant species suggest appropriate behavior for phytostabilization measures.

  18. Electronic structures and water reactivity of mixed metal sulfide cluster anions

    Energy Technology Data Exchange (ETDEWEB)

    Saha, Arjun; Raghavachari, Krishnan [Department of Chemistry, Indiana University, Bloomington, Indiana 47405 (United States)

    2014-08-21

    The electronic structures and chemical reactivity of the mixed metal sulfide cluster anion (MoWS{sub 4}{sup −}) have been investigated with density functional theory. Our study reveals the presence of two almost isoenergetic structural isomers, both containing two bridging sulfur atoms in a quartet state. However, the arrangement of the terminal sulfur atoms is different in the two isomers. In one isomer, the two metals are in the same oxidation state (each attached to one terminal S). In the second isomer, the two metals are in different oxidation states (with W in the higher oxidation state attached to both terminal S). The reactivity of water with the two lowest energy isomers has also been studied, with an emphasis on pathways leading to H{sub 2} release. The reactive behavior of the two isomers is different though the overall barriers in both systems are small. The origin of the differences are analyzed and discussed. The reaction pathways and barriers are compared with the corresponding behavior of monometallic sulfides (Mo{sub 2}S{sub 4}{sup −} and W{sub 2}S{sub 4}{sup −}) as well as mixed metal oxides (MoWO{sub 4}{sup −})

  19. The role of electron localization in the atomic structure of transition-metal 13-atom clusters: the example of Co13, Rh13, and Hf13.

    Science.gov (United States)

    Piotrowski, Maurício J; Piquini, Paulo; Cândido, Ladir; Da Silva, Juarez L F

    2011-10-14

    The crystalline structure of transition-metals (TM) has been widely known for several decades, however, our knowledge on the atomic structure of TM clusters is still far from satisfactory, which compromises an atomistic understanding of the reactivity of TM clusters. For example, almost all density functional theory (DFT) calculations for TM clusters have been based on local (local density approximation--LDA) and semilocal (generalized gradient approximation--GGA) exchange-correlation functionals, however, it is well known that plain DFT fails to correct the self-interaction error, which affects the properties of several systems. To improve our basic understanding of the atomic and electronic properties of TM clusters, we report a DFT study within two nonlocal functionals, namely, the hybrid HSE (Heyd, Scuseria, and Ernzerhof) and GGA+U functionals, of the structural and electronic properties of the Co(13), Rh(13), and Hf(13) clusters. For Co(13) and Rh(13), we found that improved exchange-correlation functionals decrease the stability of open structures such as the hexagonal bilayer (HBL) and double simple-cubic (DSC) compared with the compact icosahedron (ICO) structure, however, DFT-GGA, DFT-GGA+U, and DFT-HSE yield very similar results for Hf(13). Thus, our results suggest that the DSC structure obtained by several plain DFT calculations for Rh(13) can be improved by the use of improved functionals. Using the sd hybridization analysis, we found that a strong hybridization favors compact structures, and hence, a correct description of the sd hybridization is crucial for the relative energy stability. For example, the sd hybridization decreases for HBL and DSC and increases for ICO in the case of Co(13) and Rh(13), while for Hf(13), the sd hybridization decreases for all configurations, and hence, it does not affect the relative stability among open and compact configurations.

  20. THE ACS FORNAX CLUSTER SURVEY. X. COLOR GRADIENTS OF GLOBULAR CLUSTER SYSTEMS IN EARLY-TYPE GALAXIES

    International Nuclear Information System (INIS)

    Liu Chengze; Peng, Eric W.; Jordan, Andres; Ferrarese, Laura; Blakeslee, John P.; Cote, Patrick; Mei, Simona

    2011-01-01

    We use the largest homogeneous sample of globular clusters (GCs), drawn from the ACS Virgo Cluster Survey (ACSVCS) and ACS Fornax Cluster Survey (ACSFCS), to investigate the color gradients of GC systems in 76 early-type galaxies. We find that most GC systems possess an obvious negative gradient in (g-z) color with radius (bluer outward), which is consistent with previous work. For GC systems displaying color bimodality, both metal-rich and metal-poor GC subpopulations present shallower but significant color gradients on average, and the mean color gradients of these two subpopulations are of roughly equal strength. The field of view of ACS mainly restricts us to measuring the inner gradients of the studied GC systems. These gradients, however, can introduce an aperture bias when measuring the mean colors of GC subpopulations from relatively narrow central pointings. Inferred corrections to previous work imply a reduced significance for the relation between the mean color of metal-poor GCs and their host galaxy luminosity. The GC color gradients also show a dependence with host galaxy mass where the gradients are weakest at the ends of the mass spectrum-in massive galaxies and dwarf galaxies-and strongest in galaxies of intermediate mass, around a stellar mass of M * ∼10 10 M sun . We also measure color gradients for field stars in the host galaxies. We find that GC color gradients are systematically steeper than field star color gradients, but the shape of the gradient-mass relation is the same for both. If gradients are caused by rapid dissipational collapse and weakened by merging, these color gradients support a picture where the inner GC systems of most intermediate-mass and massive galaxies formed early and rapidly with the most massive galaxies having experienced greater merging. The lack of strong gradients in the GC systems of dwarfs, which probably have not experienced many recent major mergers, suggests that low-mass halos were inefficient at retaining

  1. The effects of age on red giant metallicities derived from the near-infrared CaII triplet

    NARCIS (Netherlands)

    Cole, AA; Smecker-Hane, TA; Tolstoy, E; Bosler, TL; Gallagher, JS

    2004-01-01

    We have obtained spectra with a resolution of similar to2.5 Angstrom in the region of approximate to7500-9500 Angstrom for 116 red giants in five galactic globular clusters and six old open clusters (five with published metallicities and one previously unmeasured). The signal-to-noise (S/N) ratio

  2. Primordial Molecular Cloud Material in Metal-Rich Carbonaceous Chondrites

    Science.gov (United States)

    Taylor, G. J.

    2016-03-01

    The menagerie of objects that make up our Solar System reflects the composition of the huge molecular cloud in which the Sun formed, a late addition of short-lived isotopes from an exploding supernova or stellar winds from a neighboring massive star, heating and/or alteration by water in growing planetesimals that modified and segregated the primordial components, and mixing throughout the Solar System. Outer Solar System objects, such as comets, have always been cold, hence minimizing the changes experienced by more processed objects. They are thought to preserve information about the molecular cloud. Elishevah Van Kooten (Natural History Museum of Denmark and the University of Copenhagen) and co-authors in Denmark and at the University of Hawai'i, measured the isotopic compositions of magnesium and chromium in metal-rich carbonaceous chondrites. They found that the meteorites preserve an isotopic signature of primordial molecular cloud materials, providing a potentially detailed record of the molecular cloud's composition and of materials that formed in the outer Solar System.

  3. Structure and bonding in clusters

    International Nuclear Information System (INIS)

    Kumar, V.

    1991-10-01

    We review here the recent progress made in the understanding of the electronic and atomic structure of small clusters of s-p bonded materials using the density functional molecular dynamics technique within the local density approximation. Starting with a brief description of the method, results are presented for alkali metal clusters, clusters of divalent metals such as Mg and Be which show a transition from van der Waals or weak chemical bonding to metallic behaviour as the cluster size grows and clusters of Al, Sn and Sb. In the case of semiconductors, we discuss results for Si, Ge and GaAs clusters. Clusters of other materials such as P, C, S, and Se are also briefly discussed. From these and other available results we suggest the possibility of unique structures for the magic clusters. (author). 69 refs, 7 figs, 1 tab

  4. Cluster perturbation theory for calculation of electronic properties of ensembles of metal nanoclusters

    Science.gov (United States)

    Zhumagulov, Yaroslav V.; Krasavin, Andrey V.; Kashurnikov, Vladimir A.

    2018-05-01

    The method is developed for calculation of electronic properties of an ensemble of metal nanoclusters with the use of cluster perturbation theory. This method is applied to the system of gold nanoclusters. The Greens function of single nanocluster is obtained by ab initio calculations within the framework of the density functional theory, and then is used in Dyson equation to group nanoclusters together and to compute the Greens function as well as the electron density of states of the whole ensemble. The transition from insulator state of a single nanocluster to metallic state of bulk gold is observed.

  5. Medium-induced change of the optical response of metal clusters in rare-gas matrices

    Science.gov (United States)

    Xuan, Fengyuan; Guet, Claude

    2017-10-01

    Interaction with the surrounding medium modifies the optical response of embedded metal clusters. For clusters from about ten to a few hundreds of silver atoms, embedded in rare-gas matrices, we study the environment effect within the matrix random phase approximation with exact exchange (RPAE) quantum approach, which has proved successful for free silver clusters. The polarizable surrounding medium screens the residual two-body RPAE interaction, adds a polarization term to the one-body potential, and shifts the vacuum energy of the active delocalized valence electrons. Within this model, we calculate the dipole oscillator strength distribution for Ag clusters embedded in helium droplets, neon, argon, krypton, and xenon matrices. The main contribution to the dipole surface plasmon red shift originates from the rare-gas polarization screening of the two-body interaction. The large size limit of the dipole surface plasmon agrees well with the classical prediction.

  6. RED SUPERGIANTS AS COSMIC ABUNDANCE PROBES: THE FIRST DIRECT METALLICITY DETERMINATION OF NGC 4038 IN THE ANTENNAE

    International Nuclear Information System (INIS)

    Lardo, C.; Davies, B.; Kudritzki, R-P.; Gazak, J. Z.; Evans, C. J.; Patrick, L. R.; Bergemann, M.; Plez, B.

    2015-01-01

    We present a direct determination of the stellar metallicity in the close pair galaxy NGC 4038 (D = 20 Mpc) based on the quantitative analysis of moderate-resolution KMOS/Very Large Telescope spectra of three super star clusters. The method adopted in our analysis has been developed and optimized to measure accurate metallicities from atomic lines in the J-band of single red supergiant (RSG) or RSG-dominated star clusters. Hence, our metallicity measurements are not affected by the biases and poorly understood systematics inherent to strong line H ii methods, which are routinely applied to massive data sets of galaxies. We find [Z] = +0.07 ± 0.03 and compare our measurements to H ii strong line calibrations. Our abundances and literature data suggest the presence of a flat metallicity gradient, which can be explained as redistribution of metal-rich gas following the strong interaction

  7. Stromvil Photometry of Clusters II. The Open Cluster M67

    Science.gov (United States)

    Boyle, R. P.; Philip, A. G. D.; Straižys, V.

    1998-12-01

    Use of the Stromgren four-color photometric system with the addition of three filters (P, Z, S) of the Vilnius system allows classifying all the types of stars, even in the presence of significant reddening by interstellar dust (Strai\\v{z}ys et al, 1996). With this Stromvil system we have begun a long-term observational program on the Vatican Advanced Technology Telescope (VATT) on Mt. Graham, Arizona, (see Philip et al,1996). The Loral 2K by 2K CCD, prepared by M. Lesser of the University of Arizona CCD Lab, gives as high as 90% quantum efficiency in most of the filters and notably 65% at the u filter. To demonstrate the degree of success so far attained in this CCD Stromvil System, we present preliminary results on the open cluster M67. We will compare some of our photometry with the CCD results of B. A. Twarog (1987) and the photoelectric photometry of Nissen et al. (1987). REFERENCES Nissen, P.E., Twarog, B.A., and Crawford, D.L. 1987, A.J. 93,634 Philip, A.G. Davis, Boyle, R.P., Strai\\v{z}ys, V. 1996, Baltic Astronomy,5,445 Strai\\v{z}ys, V., Crawford, D.L., Philip, A.G.Davis 1996, Baltic Astronomy, 5,83 Twarog, B.A. 1987, A.J. 93,647

  8. Influence of a transition metal atom on the geometry and electronic structure of Mg and Mg-H clusters

    International Nuclear Information System (INIS)

    Siretskiy, M.Yu.; Shelyapina, M.G.; Fruchart, D.; Miraglia, S.; Skryabina, N.E.

    2009-01-01

    We report on the study of (MgH 2 ) n + M complexes (M = Ti or Ni) carried out within the framework of the cluster density functional theory (DFT) method. The influence of such transition metal atoms on the cluster geometry and electronic structure is discussed considering the stability of MgH 2 hydride.

  9. Insights into magnetic interactions in a monodisperse Gd{sub 12}Fe{sub 14} metal cluster

    Energy Technology Data Exchange (ETDEWEB)

    Zheng, Xiu-Ying; Zhang, Hui; Liu, Pengxin; Du, Ming-Hao; Han, Ying-Zi; Wei, Rong-Jia; Kong, Xiang-Jian; Long, La-Sheng; Zheng, Lan-Sun [Collaborative Innovation Center of Chemistry for Energy Materials, State Key Lab. of Physical Chemistry of Solid Surface and Dept. of Chemistry, College of Chemistry and Chemical Engineering, Xiamen Univ. (China); Wang, Zhenxing; Ouyang, Zhong-Wen [Wuhan National High Magnetic Field Center and School of Physics, Huazhong University of Science and Technology, Wuhan (China); Zhuang, Gui-Lin [College of Chemcal Engineering, Zhejiang University of Technology, Hangzhou (China)

    2017-09-11

    The largest Ln-Fe metal cluster [Gd{sub 12}Fe{sub 14}(μ{sub 3}-OH){sub 12}(μ{sub 4}-OH){sub 6}(μ{sub 4}-O){sub 12}(TEOA){sub 6}(CH{sub 3}COO){sub 16}(H{sub 2} O){sub 8}].(CH{sub 3}COO){sub 2}(CH{sub 3}CN){sub 2}.(H{sub 2}O){sub 20} (1) and the core-shell monodisperse metal cluster of 1 a rate at SiO{sub 2} (1 a=[Gd{sub 12}Fe{sub 14}(μ{sub 3}-OH){sub 12}(μ{sub 4}-OH){sub 6}(μ{sub 4}-O){sub 12}(TEOA){sub 6}(CH{sub 3}COO){sub 16} (H{sub 2}O){sub 8}]{sup 2+}) were prepared. Experimental and theoretical studies on the magnetic properties of 1 and 1 a rate at SiO{sub 2} reveal that encapsulation of one cluster into one silica nanosphere not only effectively decreases intermolecular magnetic interactions but also significantly increases the zero-field splitting effect of the outer layer Fe{sup 3+} ions. (copyright 2017 Wiley-VCH Verlag GmbH and Co. KGaA, Weinheim)

  10. One-process fabrication of metal hierarchical nanostructures with rich nanogaps for highly-sensitive surface-enhanced Raman scattering

    International Nuclear Information System (INIS)

    Liu, Gui-qiang; Yu, Mei-dong; Liu, Zheng-qi; Liu, Xiao-shan; Huang, Shan; Pan, Ping-ping; Wang, Yan; Liu, Mu-lin; Gu, Gang

    2015-01-01

    One-process fabrication of highly active and reproducible surface-enhanced Raman scattering (SERS) substrates via ion beam deposition is reported. The fabricated metal–dielectric–metal (MDM) hierarchical nanostructure possesses rich nanogaps and a tunable resonant cavity. Raman scattering signals of analytes are dramatically strengthened due to the strong near-field coupling of localized surface plasmon resonances (LSPRs) and the strong interaction of LSPRs of metal NPs with surface plasmon polaritons (SPPs) on the underlying metal film by crossing over the dielectric spacer. The maximum Raman enhancement for the highest Raman peak at 1650 cm −1 is 13.5 times greater than that of a single metal nanoparticle (NP) array. Moreover, the SERS activity can be efficiently tailored by varying the size and number of voids between adjacent metal NPs and the thickness of the dielectric spacer. These findings may broaden the scope of SERS applications of MDM hierarchical nanostructures in biomedical and analytical chemistry. (paper)

  11. Spatial clustering of metal and metalloid mixtures in unregulated water sources on the Navajo Nation - Arizona, New Mexico, and Utah, USA.

    Science.gov (United States)

    Hoover, Joseph H; Coker, Eric; Barney, Yolanda; Shuey, Chris; Lewis, Johnnye

    2018-08-15

    Contaminant mixtures are identified regularly in public and private drinking water supplies throughout the United States; however, the complex and often correlated nature of mixtures makes identification of relevant combinations challenging. This study employed a Bayesian clustering method to identify subgroups of water sources with similar metal and metalloid profiles. Additionally, a spatial scan statistic assessed spatial clustering of these subgroups and a human health metric was applied to investigate potential for human toxicity. These methods were applied to a dataset comprised of metal and metalloid measurements from unregulated water sources located on the Navajo Nation, in the southwest United States. Results indicated distinct subgroups of water sources with similar contaminant profiles and that some of these subgroups were spatially clustered. Several profiles had metal and metalloid concentrations that may have potential for human toxicity including arsenic, uranium, lead, manganese, and selenium. This approach may be useful for identifying mixtures in water sources, spatially evaluating the clusters, and help inform toxicological research investigating mixtures. Copyright © 2018 The Authors. Published by Elsevier B.V. All rights reserved.

  12. The Atacama Cosmology Telescope: Relation Between Galaxy Cluster Optical Richness and Sunyaev-Zel'dovich Effect

    Science.gov (United States)

    Sehgal, Neelima; Addison, Graeme; Battaglia, Nick; Battistelli, Elia S.; Bond, J. Richard; Das, Sudeep; Devlin, Mark J.; Dunkley, Joanna; Duenner, Rolando; Gralla, Megan; hide

    2012-01-01

    We present the measured Sunyaev-Zel'dovich (SZ) flux from 474 optically-selected MaxBCG clusters that fall within the Atacama Cosmology Telescope (ACT) Equatorial survey region. The ACT Equatorial region used in this analysis covers 510 square degrees and overlaps Stripe 82 of the Sloan Digital Sky Survey. We also present the measured SZ flux stacked on 52 X-ray-selected MCXC clusters that fall within the ACT Equatorial region and an ACT Southern survey region covering 455 square degrees. We find that the measured SZ flux from the X-ray-selected clusters is consistent with expectations. However, we find that the measured SZ flux from the optically-selected clusters is both significantly lower than expectations and lower than the recovered SZ flux measured by the Planck satellite. Since we find a lower recovered SZ signal than Planck, we investigate the possibility that there is a significant offset between the optically-selected brightest cluster galaxies (BCGs) and the SZ centers, to which ACT is more sensitive due to its finer resolution. Such offsets can arise due to either an intrinsic physical separation between the BCG and the center of the gas concentration or from misidentification of the cluster BCG. We find that the entire discrepancy for both ACT and Planck can be explained by assuming that the BCGs are offset from the SZ maxima with a uniform random distribution between 0 and 1.5 Mpc. In contrast, the physical separation between BCGs and X-ray peaks for an X-ray-selected subsample of MaxBCG clusters shows a much narrower distribution that peaks within 0.2 Mpc. We conclude that while offsets between BCGs and SZ peaks may be an important component in explaining the discrepancy, it is likely that a combination of factors is responsible for the ACT and Planck measurements. Several effects that can lower the SZ signal equally for both ACT and Planck, but not explain the difference in measured signals, include a larger percentage of false detections in the

  13. Effects of Carbonyl Bond and Metal Cluster Dissociation and Evaporation Rates on Predictions of Nanotube Production in HiPco

    Science.gov (United States)

    Scott, Carl D.; Smalley, Richard E.

    2002-01-01

    The high-pressure carbon monoxide (HiPco) process for producing single-wall carbon nanotubes (SWNT) uses iron pentacarbonyl as the source of iron for catalyzing the Boudouard reaction. Attempts using nickel tetracarbonyl led to no production of SWNTs. This paper discusses simulations at a constant condition of 1300 K and 30 atm in which the chemical rate equations are solved for different reaction schemes. A lumped cluster model is developed to limit the number of species in the models, yet it includes fairly large clusters. Reaction rate coefficients in these schemes are based on bond energies of iron and nickel species and on estimates of chemical rates for formation of SWNTs. SWNT growth is measured by the co-formation of CO2. It is shown that the production of CO2 is significantly greater for FeCO due to its lower bond energy as compared with that ofNiCO. It is also shown that the dissociation and evaporation rates of atoms from small metal clusters have a significant effect on CO2 production. A high rate of evaporation leads to a smaller number of metal clusters available to catalyze the Boudouard reaction. This suggests that if CO reacts with metal clusters and removes atoms from them by forming MeCO, this has the effect of enhancing the evaporation rate and reducing SWNT production. The study also investigates some other reactions in the model that have a less dramatic influence.

  14. Be STARS IN THE OPEN CLUSTER NGC 6830

    International Nuclear Information System (INIS)

    Yu, Po-Chieh; Lin, Chien-Cheng; Lin, Hsing-Wen; Lee, Chien-De; Ngeow, Chow-Choong; Ip, Wing-Huen; Chen, Wen-Ping; Chang, Chan-Kao; Huang, Li-Ching; Cheng, Yu-Chi; Ritter, Andreas; Konidaris, Nick; Chen, Hui-Chen; Malkan, Matthew A.; Laher, Russ; Surace, Jason; Edelson, Rick; Quimby, Robert; Ben-Ami, Sagi; Ofek, Eran O.

    2016-01-01

    We report the discovery of two new Be stars, and re-identify one known Be star in the open cluster NGC 6830. Eleven H α emitters were discovered using the H α imaging photometry of the Palomar Transient Factory Survey. Stellar membership of the candidates was verified with photometric and kinematic information using 2MASS data and proper motions. The spectroscopic confirmation was carried out by using the Shane 3 m telescope at the Lick observatory. Based on their spectral types, three H α emitters were confirmed as Be stars with H α equivalent widths greater than −10 Å. Two objects were also observed by the new spectrograph spectral energy distribution-machine (SED-machine) on the Palomar 60-inch Telescope. The SED-machine results show strong H α emission lines, which are consistent with the results of the Lick observations. The high efficiency of the SED-machine can provide rapid observations for Be stars in a comprehensive survey in the future.

  15. Be STARS IN THE OPEN CLUSTER NGC 6830

    Energy Technology Data Exchange (ETDEWEB)

    Yu, Po-Chieh; Lin, Chien-Cheng; Lin, Hsing-Wen; Lee, Chien-De; Ngeow, Chow-Choong; Ip, Wing-Huen; Chen, Wen-Ping; Chang, Chan-Kao; Huang, Li-Ching; Cheng, Yu-Chi; Ritter, Andreas [Graduate Institute of Astronomy, National Central University, 300 Jhongda Road, Jhongli 32001, Taiwan (China); Konidaris, Nick [Cahill Center for Astronomy and Astrophysics, California Institute of Technology, 1200 E. California Boulevard, Pasadena, CA 91125 (United States); Chen, Hui-Chen [Department of Natural Sciences and Sustainable Development, Ministry of Science and Technology, 106, Sec. 2, Heping E. Road, Taipei 10622, Taiwan (China); Malkan, Matthew A. [Department of Physics and Astronomy, University of California, Los Angeles, CA 90024 (United States); Laher, Russ; Surace, Jason [Spitzer Science Center, California Institute of Technology, M/S 314-6, Pasadena, CA 91125 (United States); Edelson, Rick [Department of Astronomy, University of Maryland, College Park, MD 20742 (United States); Quimby, Robert [Kavli-Institute for the Physics and Mathematics of the Universe, University of Tokyo, Kashiwanoha 5-1-5, Kashiwa-shi, Chiba (Japan); Ben-Ami, Sagi; Ofek, Eran O. [Department of Particle Physics and Astrophysics, The Weizmann Institute of Science, Rehovot 76100 (Israel); and others

    2016-05-01

    We report the discovery of two new Be stars, and re-identify one known Be star in the open cluster NGC 6830. Eleven H α emitters were discovered using the H α imaging photometry of the Palomar Transient Factory Survey. Stellar membership of the candidates was verified with photometric and kinematic information using 2MASS data and proper motions. The spectroscopic confirmation was carried out by using the Shane 3 m telescope at the Lick observatory. Based on their spectral types, three H α emitters were confirmed as Be stars with H α equivalent widths greater than −10 Å. Two objects were also observed by the new spectrograph spectral energy distribution-machine (SED-machine) on the Palomar 60-inch Telescope. The SED-machine results show strong H α emission lines, which are consistent with the results of the Lick observations. The high efficiency of the SED-machine can provide rapid observations for Be stars in a comprehensive survey in the future.

  16. Gas-generated thermal oxidation of a coordination cluster for an anion-doped mesoporous metal oxide.

    Science.gov (United States)

    Hirai, Kenji; Isobe, Shigehito; Sada, Kazuki

    2015-12-18

    Central in material design of metal oxides is the increase of surface area and control of intrinsic electronic and optical properties, because of potential applications for energy storage, photocatalysis and photovoltaics. Here, we disclose a facile method, inspired by geochemical process, which gives rise to mesoporous anion-doped metal oxides. As a model system, we demonstrate that simple calcination of a multinuclear coordination cluster results in synchronic chemical reactions: thermal oxidation of Ti8O10(4-aminobenzoate)12 and generation of gases including amino-group fragments. The gas generation during the thermal oxidation of Ti8O10(4-aminobenzoate)12 creates mesoporosity in TiO2. Concurrently, nitrogen atoms contained in the gases are doped into TiO2, thus leading to the formation of mesoporous N-doped TiO2. The mesoporous N-doped TiO2 can be easily synthesized by calcination of the multinuclear coordination cluster, but shows better photocatalytic activity than the one prepared by a conventional sol-gel method. Owing to an intrinsic designability of coordination compounds, this facile synthetic will be applicable to a wide range of metal oxides and anion dopants.

  17. Structure and tensile properties of Fe-Cr model alloy strengthened by nano-scale NbC particles derived from controlled crystallization of Nb-rich clusters

    Energy Technology Data Exchange (ETDEWEB)

    Dai, Lei [College of Materials and Chemical Engineering, Three Gorges University, Yichang 443002 (China); Guo, Qianying [State Key Lab of Hydraulic Engineering Simulation and Safety, School of Material Science and Engineering, Tianjin University, Tianjin 300354 (China); Liu, Yongchang, E-mail: licmtju@163.com [State Key Lab of Hydraulic Engineering Simulation and Safety, School of Material Science and Engineering, Tianjin University, Tianjin 300354 (China); Yu, Liming; Li, Huijun [State Key Lab of Hydraulic Engineering Simulation and Safety, School of Material Science and Engineering, Tianjin University, Tianjin 300354 (China)

    2016-09-30

    This article describes the microstructural evolution and tensile properties of Fe-Cr model alloy strengthened by nano-scale NbC particles. According to the results obtained from X-ray diffraction and transmission electron microscope with Energy Dispersive Spectrometer, the bcc ultrafine grains and the disordered phase of Nb-rich nano-clusters were observed in the milled powders. The hot pressing (HP) resulted in a nearly equiaxed ferritic grains and dispersed nano-scale NbC (~8 nm) particles. The microstructure studies reveal that the formation of NbC nanoparticles is composed of nucleation and growth of the Nb-rich nano-clusters involving diffusion of their component. At room temperature the material exhibits an ultimate tensile strength of 700 MPa, yield strength of 650 MPa, and total elongation of 11.7 pct. The fracture surface studies reveal that a typical ductile fracture mode has occurred during tensile test.

  18. Magnetron sputtering cluster apparatus for formation and deposition of size-selected metal nanoparticles

    DEFF Research Database (Denmark)

    Hanif, Muhammad; Popok, Vladimir

    2015-01-01

    selection is achieved using an electrostatic quadrupole mass selector. The deposited silver clusters are studied using atomic force microscopy. The height distributions show typical relative standard size deviation of 9-13% for given sizes in the range between 5-23 nm. Thus, the apparatus demonstrates good...... capability in formation of supported size-selected metal nanoparticles with controllable coverage for various practical applications....

  19. Tidal stripping stellar substructures around four metal-poor globular clusters in the galactic bulge

    International Nuclear Information System (INIS)

    Chun, Sang-Hyun; Kang, Minhee; Jung, DooSeok; Sohn, Young-Jong

    2015-01-01

    We investigate the spatial density configuration of stars around four metal-poor globular clusters (NGC 6266, NGC 6626, NGC 6642, and NGC 6723) in the Galactic bulge region using wide-field deep J, H, and K imaging data obtained with the Wide Field Camera near-infrared array on the United Kingdom Infrared Telescope. A statistical weighted filtering algorithm for the stars on the color–magnitude diagram is applied in order to sort cluster member candidates from the field star contamination. In two-dimensional isodensity contour maps of the clusters, we find that all four of the globular clusters exhibit strong evidence of tidally stripped stellar features beyond the tidal radius in the form of tidal tails or small density lobes/chunks. The orientations of the extended stellar substructures are likely to be associated with the effect of dynamic interaction with the Galaxy and the cluster's space motion. The observed radial density profiles of the four globular clusters also describe the extended substructures; they depart from theoretical King and Wilson models and have an overdensity feature with a break in the slope of the profile at the outer region of clusters. The observed results could imply that four globular clusters in the Galactic bulge region have experienced strong environmental effects such as tidal forces or bulge/disk shocks of the Galaxy during the dynamical evolution of globular clusters. These observational results provide further details which add to our understanding of the evolution of clusters in the Galactic bulge region as well as the formation of the Galaxy.

  20. Investigating the synthesis of ligated metal clusters in solution using a flow reactor and electrospray ionization mass spectrometry.

    Science.gov (United States)

    Olivares, Astrid; Laskin, Julia; Johnson, Grant E

    2014-09-18

    The scalable synthesis of ligated subnanometer metal clusters containing an exact number of atoms is of interest due to the highly size-dependent catalytic, electronic, and optical properties of these species. While significant research has been conducted on the batch preparation of clusters through reduction synthesis in solution, the processes of metal complex reduction as well as cluster nucleation, growth, and postreduction etching are still not well understood. Herein, we demonstrate a prototype temperature-controlled flow reactor for qualitatively studying cluster formation in solution at steady-state conditions. Employing this technique, methanol solutions of a chloro(triphenylphosphine)gold precursor, 1,4-bis(diphenylphosphino)butane capping ligand, and borane-tert-butylamine reducing agent were combined in a mixing tee and introduced into a heated capillary with a known length. In this manner, the temperature dependence of the relative abundance of different ionic reactants, intermediates, and products synthesized in real time was characterized qualitatively using online mass spectrometry. A wide distribution of doubly and triply charged cationic gold clusters was observed as well as smaller singly charged organometallic complexes. The results demonstrate that temperature plays a crucial role in determining the relative population of cationic gold clusters and, in general, that higher temperature promotes the formation of doubly charged clusters and singly charged organometallic complexes while reducing the abundance of triply charged species. Moreover, the distribution of clusters observed at elevated temperatures is found to be consistent with that obtained at longer reaction times at room temperature, thereby demonstrating that heating may be used to access cluster distributions characteristic of different stages of batch reduction synthesis in solution.

  1. Plasmon resonances in large noble-metal clusters

    International Nuclear Information System (INIS)

    Soennichsen, C; Franzl, T; Wilk, T; Plessen, G von; Feldmann, J

    2002-01-01

    We investigate the optical properties of spherical gold and silver clusters with diameters of 20 nm and larger. The light scattering spectra of individual clusters are measured using dark-field microscopy, thus avoiding inhomogeneous broadening effects. The dipolar plasmon resonances of the clusters are found to have nearly Lorentzian line shapes. With increasing size we observe polaritonic red-shifts of the plasmon line and increased radiation damping for both gold and silver clusters. Apart from some cluster-to-cluster variations of the plasmon lines, agreement with Mie theory is reasonably good for the gold clusters. However, it is less satisfactory for the silver clusters, possibly due to cluster faceting or chemical effects

  2. The Open Connectome Project Data Cluster: Scalable Analysis and Vision for High-Throughput Neuroscience

    Science.gov (United States)

    Burns, Randal; Roncal, William Gray; Kleissas, Dean; Lillaney, Kunal; Manavalan, Priya; Perlman, Eric; Berger, Daniel R.; Bock, Davi D.; Chung, Kwanghun; Grosenick, Logan; Kasthuri, Narayanan; Weiler, Nicholas C.; Deisseroth, Karl; Kazhdan, Michael; Lichtman, Jeff; Reid, R. Clay; Smith, Stephen J.; Szalay, Alexander S.; Vogelstein, Joshua T.; Vogelstein, R. Jacob

    2013-01-01

    We describe a scalable database cluster for the spatial analysis and annotation of high-throughput brain imaging data, initially for 3-d electron microscopy image stacks, but for time-series and multi-channel data as well. The system was designed primarily for workloads that build connectomes— neural connectivity maps of the brain—using the parallel execution of computer vision algorithms on high-performance compute clusters. These services and open-science data sets are publicly available at openconnecto.me. The system design inherits much from NoSQL scale-out and data-intensive computing architectures. We distribute data to cluster nodes by partitioning a spatial index. We direct I/O to different systems—reads to parallel disk arrays and writes to solid-state storage—to avoid I/O interference and maximize throughput. All programming interfaces are RESTful Web services, which are simple and stateless, improving scalability and usability. We include a performance evaluation of the production system, highlighting the effec-tiveness of spatial data organization. PMID:24401992

  3. CCD BVRI and 2MASS photometry of the poorly studied open cluster NGC 6631

    Directory of Open Access Journals (Sweden)

    A.L. Tadross

    2014-12-01

    Full Text Available Here we have obtained the BVRI CCD photometry down to a limiting magnitude of V∼20 for the southern poorly studied open cluster NGC 6631. It is observed from the 1.88 m Telescope of Kottamia Observatory in Egypt. About 3300 stars have been observed in an area of ∼10′×10′ around the cluster center. The main photometric parameters have been estimated and compared with the results that determined for the cluster using JHKs 2MASS photometric database. The cluster’s diameter is estimated to be 10 arcmin; the reddening E(B-V=0.68 ± 0.10 mag, E(J-H=0.21 ± 0.10 mag, the true modulus (m-Mo=12.16 ± 0.10 mag, which corresponds to a distance of 2700 ± 125 pc and age of 500 ± 50 Myr.

  4. The Open Connectome Project Data Cluster: Scalable Analysis and Vision for High-Throughput Neuroscience.

    Science.gov (United States)

    Burns, Randal; Roncal, William Gray; Kleissas, Dean; Lillaney, Kunal; Manavalan, Priya; Perlman, Eric; Berger, Daniel R; Bock, Davi D; Chung, Kwanghun; Grosenick, Logan; Kasthuri, Narayanan; Weiler, Nicholas C; Deisseroth, Karl; Kazhdan, Michael; Lichtman, Jeff; Reid, R Clay; Smith, Stephen J; Szalay, Alexander S; Vogelstein, Joshua T; Vogelstein, R Jacob

    2013-01-01

    We describe a scalable database cluster for the spatial analysis and annotation of high-throughput brain imaging data, initially for 3-d electron microscopy image stacks, but for time-series and multi-channel data as well. The system was designed primarily for workloads that build connectomes - neural connectivity maps of the brain-using the parallel execution of computer vision algorithms on high-performance compute clusters. These services and open-science data sets are publicly available at openconnecto.me. The system design inherits much from NoSQL scale-out and data-intensive computing architectures. We distribute data to cluster nodes by partitioning a spatial index. We direct I/O to different systems-reads to parallel disk arrays and writes to solid-state storage-to avoid I/O interference and maximize throughput. All programming interfaces are RESTful Web services, which are simple and stateless, improving scalability and usability. We include a performance evaluation of the production system, highlighting the effec-tiveness of spatial data organization.

  5. THE ATACAMA COSMOLOGY TELESCOPE: RELATION BETWEEN GALAXY CLUSTER OPTICAL RICHNESS AND SUNYAEV-ZEL'DOVICH EFFECT

    Energy Technology Data Exchange (ETDEWEB)

    Sehgal, Neelima; Hlozek, Renee [Department of Astrophysical Sciences, Peyton Hall, Princeton University, Princeton, NJ 08544 (United States); Addison, Graeme; Dunkley, Joanna; Louis, Thibaut [Department of Astrophysics, Oxford University, Oxford OX1 3RH (United Kingdom); Battaglia, Nick [Department of Physics, Carnegie Mellon University, Pittsburgh, PA 15213 (United States); Battistelli, Elia S. [Department of Physics, University of Rome ' La Sapienza' , Piazzale Aldo Moro 5, I-00185 Rome (Italy); Bond, J. Richard; Hajian, Amir; Hincks, Adam D. [Canadian Institute for Theoretical Astrophysics, University of Toronto, Toronto, ON M5S 3H8 (Canada); Das, Sudeep [Berkeley Center for Cosmological Physics, LBL and Department of Physics, University of California, Berkeley, CA 94720 (United States); Devlin, Mark J. [Department of Physics and Astronomy, University of Pennsylvania, 209 South 33rd Street, Philadelphia, PA 19104 (United States); Duenner, Rolando [Departamento de Astronomia y Astrofisica, Facultad de Fisica, Pontificia Universidad Catolica de Chile, Casilla 306, Santiago 22 (Chile); Gralla, Megan [Department of Physics and Astronomy, The Johns Hopkins University, 3400 N. Charles St., Baltimore, MD 21218-2686 (United States); Halpern, Mark; Hasselfield, Matthew [Department of Physics and Astronomy, University of British Columbia, Vancouver, BC V6T 1Z4 (Canada); Hilton, Matt [Centre for Astronomy and Particle Theory, School of Physics and Astronomy, University of Nottingham, University Park, Nottingham NG7 2RD (United Kingdom); Hughes, John P. [Department of Physics and Astronomy, Rutgers, The State University of New Jersey, Piscataway, NJ 08854-8019 (United States); Kosowsky, Arthur [Department of Physics and Astronomy, University of Pittsburgh, Pittsburgh, PA 15260 (United States); Lin, Yen-Ting [Institute of Astronomy and Astrophysics, Academia Sinica, Taipei, Taiwan (China); and others

    2013-04-10

    We present the measured Sunyaev-Zel'dovich (SZ) flux from 474 optically selected MaxBCG clusters that fall within the Atacama Cosmology Telescope (ACT) Equatorial survey region. The ACT Equatorial region used in this analysis covers 510 deg{sup 2} and overlaps Stripe 82 of the Sloan Digital Sky Survey. We also present the measured SZ flux stacked on 52 X-ray-selected MCXC clusters that fall within the ACT Equatorial region and an ACT Southern survey region covering 455 deg{sup 2}. We find that the measured SZ flux from the X-ray-selected clusters is consistent with expectations. However, we find that the measured SZ flux from the optically selected clusters is both significantly lower than expectations and lower than the recovered SZ flux measured by the Planck satellite. Since we find a lower recovered SZ signal than Planck, we investigate the possibility that there is a significant offset between the optically selected brightest cluster galaxies (BCGs) and the SZ centers, to which ACT is more sensitive due to its finer resolution. Such offsets can arise due to either an intrinsic physical separation between the BCG and the center of the gas concentration or from misidentification of the cluster BCG. We find that the entire discrepancy for both ACT and Planck can be explained by assuming that the BCGs are offset from the SZ maxima with a uniform random distribution between 0 and 1.5 Mpc. Such large offsets between gas peaks and BCGs for optically selected cluster samples seem unlikely given that we find the physical separation between BCGs and X-ray peaks for an X-ray-selected subsample of MaxBCG clusters to have a much narrower distribution that peaks within 0.2 Mpc. It is possible that other effects are lowering the ACT and Planck signals by the same amount, with offsets between BCGs and SZ peaks explaining the remaining difference between ACT and Planck measurements. Several effects that can lower the SZ signal equally for both ACT and Planck, but not

  6. Massive Star Clusters in Ongoing Galaxy Interactions: Clues to Cluster Formation

    Science.gov (United States)

    Keel, William C.; Borne, Kirk D.

    2003-09-01

    We present HST WFPC2 observations, supplemented by ground-based Hα data, of the star-cluster populations in two pairs of interacting galaxies selected for being in very different kinds of encounters seen at different stages. Dynamical information and n-body simulations provide the details of encounter geometry, mass ratio, and timing. In NGC 5752/4 we are seeing a weak encounter, well past closest approach, after about 2.5×108 yr. The large spiral NGC 5754 has a normal population of disk clusters, while the fainter companion NGC 5752 exhibits a rich population of luminous clusters with a flatter luminosity function. The strong, ongoing encounter in NGC 6621/2, seen about 1.0×108 yr past closest approach between roughly equal-mass galaxies, has produced an extensive population of luminous clusters, particularly young and luminous in a small region between the two nuclei. This region is dynamically interesting, with such a strong perturbation in the velocity field that the rotation curve reverses sign. From these results, in comparison with other strongly interacting systems discussed in the literature, cluster formation requires a threshold level of perturbation, with stage of the interaction a less important factor. The location of the most active star formation in NGC 6621/2 draws attention to a possible role for the Toomre stability threshold in shaping star formation in interacting galaxies. The rich cluster populations in NGC 5752 and NGC 6621 show that direct contact between gas-rich galaxy disks is not a requirement to form luminous clusters and that they can be triggered by processes happening within a single galaxy disk (albeit triggered by external perturbations). Based on observations with the NASA/ESA Hubble Space Telescope, obtained at the Space Telescope Science Institute, which is operated by the Association of Universities for Research in Astronomy, Inc., under NASA contract NAS 5-26555.

  7. Endohedral gallide cluster superconductors and superconductivity in ReGa5.

    Science.gov (United States)

    Xie, Weiwei; Luo, Huixia; Phelan, Brendan F; Klimczuk, Tomasz; Cevallos, Francois Alexandre; Cava, Robert Joseph

    2015-12-22

    We present transition metal-embedded (T@Gan) endohedral Ga-clusters as a favorable structural motif for superconductivity and develop empirical, molecule-based, electron counting rules that govern the hierarchical architectures that the clusters assume in binary phases. Among the binary T@Gan endohedral cluster systems, Mo8Ga41, Mo6Ga31, Rh2Ga9, and Ir2Ga9 are all previously known superconductors. The well-known exotic superconductor PuCoGa5 and related phases are also members of this endohedral gallide cluster family. We show that electron-deficient compounds like Mo8Ga41 prefer architectures with vertex-sharing gallium clusters, whereas electron-rich compounds, like PdGa5, prefer edge-sharing cluster architectures. The superconducting transition temperatures are highest for the electron-poor, corner-sharing architectures. Based on this analysis, the previously unknown endohedral cluster compound ReGa5 is postulated to exist at an intermediate electron count and a mix of corner sharing and edge sharing cluster architectures. The empirical prediction is shown to be correct and leads to the discovery of superconductivity in ReGa5. The Fermi levels for endohedral gallide cluster compounds are located in deep pseudogaps in the electronic densities of states, an important factor in determining their chemical stability, while at the same time limiting their superconducting transition temperatures.

  8. C-N Bond Activation and Ring Opening of a Saturated N-Heterocyclic Carbene by Lateral Alkali-Metal-Mediated Metalation.

    Science.gov (United States)

    Hernán-Gómez, Alberto; Kennedy, Alan R; Hevia, Eva

    2017-06-01

    Combining alkali-metal-mediated metalation (AMMM) and N-heterocyclic carbene (NHC) chemistry, a novel C-N bond activation and ring-opening process is described for these increasingly important NHC molecules, which are generally considered robust ancillary ligands. Here, mechanistic investigations on reactions of saturated NHC SIMes (SIMes=[:C{N(2,4,6-Me 3 C 6 H 2 )CH 2 } 2 ]) with Group 1 alkyl bases suggest this destructive process is triggered by lateral metalation of the carbene. Exploiting co-complexation and trans-metal-trapping strategies with lower polarity organometallic reagents (Mg(CH 2 SiMe 3 ) 2 and Al(TMP)iBu 2 ), key intermediates in this process have been isolated and structurally defined. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  9. Rotational and radial velocities of 1.3-2.2 M {sub ☉} red giants in open clusters

    Energy Technology Data Exchange (ETDEWEB)

    Carlberg, Joleen K., E-mail: jcarlberg@dtm.ciw.edu [Department of Terrestrial Magnetism, Carnegie Institution of Washington, 5241 Broad Branch Road, NW, Washington, DC 20015 (United States)

    2014-06-01

    This study presents the rotational distribution of red giant (RG) stars in 11 old to intermediate age open clusters. The masses of these stars are all above the Kraft break, so they lose negligible amounts of their birth angular momentum (AM) during the main-sequence (MS) evolution. However, they do span a mass range with quite different AM distributions imparted during formation, with the stars less massive than ∼1.6M {sub ☉} arriving on the MS with lower rotation rates than the more massive stars. The majority of RGs in this study are slow rotators across the entire red giant branch regardless of mass, supporting the picture that intermediate-mass stars rapidly spin down when they evolve off the MS and develop convection zones capable of driving a magnetic dynamo. Nevertheless, a small fraction of RGs in open clusters show some level of enhanced rotation, and faster rotators are as common in these clusters as in the field RG population. Most of these enhanced rotators appear to be red clump stars, which is also true of the underlying stellar sample, while others are clearly RGs that are above or below the clump. In addition to rotational velocities, the radial velocities (RVs) and membership probabilities of individual stars are also presented. Cluster heliocentric RVs for NGC 6005 and Pismis 18 are reported for the first time.

  10. Age and helium content of the open cluster NGC 6791 from multiple eclipsing binary members. II

    DEFF Research Database (Denmark)

    Brogaard, K.; VandenBerg, D. A.; Bruntt, H.

    2012-01-01

    Models of stellar structure and evolution can be constrained by measuring accurate parameters of detached eclipsing binaries in open clusters. Multiple binary stars provide the means to determine helium abundances in these old stellar systems, and in turn, to improve estimates of their age. In th...

  11. Open clusters. III. Fundamental parameters of B stars in NGC 6087, NGC 6250, NGC 6383, and NGC 6530 B-type stars with circumstellar envelopes

    Science.gov (United States)

    Aidelman, Y.; Cidale, L. S.; Zorec, J.; Panei, J. A.

    2018-02-01

    Context. Stellar physical properties of star clusters are poorly known and the cluster parameters are often very uncertain. Methods: Our goals are to perform a spectrophotometric study of the B star population in open clusters to derive accurate stellar parameters, search for the presence of circumstellar envelopes, and discuss the characteristics of these stars. The BCD spectrophotometric system is a powerful method to obtain stellar fundamental parameters from direct measurements of the Balmer discontinuity. To this end, we wrote the interactive code MIDE3700. The BCD parameters can also be used to infer the main properties of open clusters: distance modulus, color excess, and age. Furthermore, we inspected the Balmer discontinuity to provide evidence for the presence of circumstellar disks and identify Be star candidates. We used an additional set of high-resolution spectra in the Hα region to confirm the Be nature of these stars. Results: We provide Teff, log g, Mv, Mbol, and spectral types for a sample of 68 stars in the field of the open clusters NGC 6087, NGC 6250, NGC 6383, and NGC 6530, as well as the cluster distances, ages, and reddening. Then, based on a sample of 230 B stars in the direction of the 11 open clusters studied along this series of three papers, we report 6 new Be stars, 4 blue straggler candidates, and 15 B-type stars (called Bdd) with a double Balmer discontinuity, which indicates the presence of circumstellar envelopes. We discuss the distribution of the fraction of B, Be, and Bdd star cluster members per spectral subtype. The majority of the Be stars are dwarfs and present a maximum at the spectral type B2-B4 in young and intermediate-age open clusters (operating under agreement of CONICET and the Universities of La Plata, Córdoba, and San Juan, Argentina.Tables 1, 2, 9-16 are only available at the CDS via anonymous ftp to http://cdsarc.u-strasbg.fr (http://130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/qcat?J/A+A/610/A30

  12. Enacs Survey of Southern Galaxies Indicates Open Universe

    Science.gov (United States)

    1996-02-01

    New Light on Rich Clusters of Galaxies and their Formation History In the context of a comprehensive Key-Programme , carried out with telescopes at the ESO La Silla Observatory, a team of European astronomers [1]. has recently obtained radial velocities for more than 5600 galaxies in about 100 rich clusters of galaxies. With this programme the amount of information about the motions of galaxies (the kinematical data) in such clusters has almost been doubled. This has allowed the team to study the distribution of the cluster masses, and also the dynamical state of clusters in new and interesting ways. An important result of this programme is that the derived masses of the investigated clusters of galaxies indicate that the mean density of the Universe is insufficient to halt the current expansion; we may therefore be living in an open Universe that will expand forever. Clusters of galaxies as tracers of large-scale structure About 40 years ago, American astronomer George Abell, working at the Palomar Observatory in California, was the first to perform a systematic study of rich clusters of galaxies , that is clusters with particularly many member galaxies located within a relatively restricted region in the sky. He identified several thousands of such clusters, and he numbered and described them; they are now known to astronomers as `Abell clusters'. More than twenty years earlier, Swiss-American astronomer Fritz Zwicky, using the famous 100-inch Mount Wilson telescope above Los Angeles, concluded that the total mass of a rich cluster of galaxies is probably much larger than the combined mass of the individual galaxies we can observe in it. This phenomenon is now known as the `Missing Dark Matter' , and many attempts have since been made to understand its true nature. Although the existence of this Dark Matter is generally accepted, it has been very difficult to prove its existence in a direct way. Rich clusters have several components: in addition to several

  13. Subspace K-means clustering.

    Science.gov (United States)

    Timmerman, Marieke E; Ceulemans, Eva; De Roover, Kim; Van Leeuwen, Karla

    2013-12-01

    To achieve an insightful clustering of multivariate data, we propose subspace K-means. Its central idea is to model the centroids and cluster residuals in reduced spaces, which allows for dealing with a wide range of cluster types and yields rich interpretations of the clusters. We review the existing related clustering methods, including deterministic, stochastic, and unsupervised learning approaches. To evaluate subspace K-means, we performed a comparative simulation study, in which we manipulated the overlap of subspaces, the between-cluster variance, and the error variance. The study shows that the subspace K-means algorithm is sensitive to local minima but that the problem can be reasonably dealt with by using partitions of various cluster procedures as a starting point for the algorithm. Subspace K-means performs very well in recovering the true clustering across all conditions considered and appears to be superior to its competitor methods: K-means, reduced K-means, factorial K-means, mixtures of factor analyzers (MFA), and MCLUST. The best competitor method, MFA, showed a performance similar to that of subspace K-means in easy conditions but deteriorated in more difficult ones. Using data from a study on parental behavior, we show that subspace K-means analysis provides a rich insight into the cluster characteristics, in terms of both the relative positions of the clusters (via the centroids) and the shape of the clusters (via the within-cluster residuals).

  14. Generalized vibrating potential model for collective excitations in spherical, deformed and superdeformed systems: (1) atomic nuclei, (2) metal clusters

    International Nuclear Information System (INIS)

    Nesterenko, V.O.; Kleinig, W.

    1995-01-01

    The self-consistent vibrating potential model (VPM) is extended for description of Eλ collective excitations in atomic nuclei and metal clusters with practically any kind of static deformation. The model is convenient for a qualitative analysis and provides the RPA accuracy of numerical calculations. The VPM is applied to study Eλ giant resonances in spherical metal clusters and deformed and superdeformed nuclei. It is shown that the deformation splitting of superdeformed nuclei results in a very complicated (''jungle-like'') structure of the resonances, which makes the experimental observation of E2 and E3 giant resonances in superdeformed nuclei quite problematic. Calculations of E1 giant resonance in spherical sodium clusters Na 8 , Na 20 and Na 40 are presented, as a test of the VPM in this field. The results are in qualitative agreement with the experimental data. (orig.)

  15. Spectra of globular clusters in the Sombrero galaxy: evidence for spectroscopic metallicity bimodality

    Science.gov (United States)

    Alves-Brito, Alan; Hau, George K. T.; Forbes, Duncan A.; Spitler, Lee R.; Strader, Jay; Brodie, Jean P.; Rhode, Katherine L.

    2011-11-01

    We present a large sample of over 200 integrated-light spectra of confirmed globular clusters (GCs) associated with the Sombrero (M104) galaxy taken with the Deep Imaging Multi-Object Spectrograph (DEIMOS) instrument on the Keck telescope. A significant fraction of the spectra have signal-to-noise ratio levels high enough to allow measurements of GC metallicities using the method of Brodie & Huchra. We find a distribution of spectroscopic metallicities in the range -2.2 < [Fe/H] < +0.1 that is bimodal, with peaks at [Fe/H]˜-1.4 and -0.6. Thus, the GC system of the Sombrero galaxy, like a few other galaxies now studied in detail, reveals a bimodal spectroscopic metallicity distribution supporting the long-held belief that colour bimodality reflects two metallicity subpopulations. This further suggests that the transformation from optical colour to metallicity for old stellar populations, such as GCs, is not strongly non-linear. We also explore the radial and magnitude distribution with metallicity for GC subpopulations but small number statistics prevent any clear trends in these distributions. Based on observations obtained at the W. M. Keck Observatory, which is operated as a scientific partnership among the California Institute of Technology, the University of California and the National Aeronautics and Space Administration.

  16. Catalytic dehydrogenation of alcohol over solid-state molybdenum sulfide clusters with an octahedral metal framework

    Energy Technology Data Exchange (ETDEWEB)

    Kamiguchi, Satoshi, E-mail: kamigu@riken.jp [Advanced Catalysis Research Group, RIKEN Center for Sustainable Resource Science, 2-1 Hirosawa, Wako City, Saitama 351-0198 (Japan); Organometallic Chemistry Laboratory, RIKEN, 2-1 Hirosawa, Wako City, Saitama 351-0198 (Japan); Okumura, Kazu [School of Advanced Engineering, Kogakuin University, Nakano-machi, Hachioji City, Tokyo 192-0015 (Japan); Nagashima, Sayoko; Chihara, Teiji [Graduate School of Science and Engineering, Saitama University, Shimo-Okubo, Sakura-ku, Saitama City, Saitama 338-8570 (Japan)

    2015-12-15

    Graphical abstract: - Highlights: • Solid-state molybdenum sulfide clusters catalyzed the dehydrogenation of alcohol. • The dehydrogenation proceeded without the addition of any oxidants. • The catalytic activity developed when the cluster was activated at 300–500 °C in H{sub 2}. • The Lewis-acidic molybdenum atom and basic sulfur ligand were catalytically active. • The clusters function as bifunctional acid–base catalysts. - Abstract: Solid-state molybdenum sulfide clusters with an octahedral metal framework, the superconducting Chevrel phases, are applied to catalysis. A copper salt of a nonstoichiometric sulfur-deficient cluster, Cu{sub x}Mo{sub 6}S{sub 8–δ} (x = 2.94 and δ ≈ 0.3), is stored in air for more than 90 days. When the oxygenated cluster is thermally activated in a hydrogen stream above 300 °C, catalytic activity for the dehydrogenation of primary alcohols to aldehydes and secondary alcohols to ketones develops. The addition of pyridine or benzoic acid decreases the dehydrogenation activity, indicating that both a Lewis-acidic coordinatively unsaturated molybdenum atom and a basic sulfur ligand synergistically act as the catalytic active sites.

  17. Richness, coverage and concentration of heavy metals in vascular epiphytes along an urbanization gradient.

    Science.gov (United States)

    Becker, Diego Fedrizzi Petry; Linden, Rafael; Schmitt, Jairo Lizandro

    2017-04-15

    Richness, coverage and concentration of heavy metals in vascular epiphytes were analyzed in isolated trees along an urbanization gradient in Southern Brazil. A total of 20 phorophytes were sampled in the main street of each site. Concentrations of chromium, cadmium, lead, manganese, nickel and zinc were measured in the leaves of Tillandsia recurvata L. using Graphite Furnace Atomic Absorption Spectrophotometry. A decreasing gradient of epiphyte richness and coverage was observed as urbanization increased. Vehicle fleet and demographic density were the parameters most correlated with the reduction of epiphytic diversity. In T. recurvata, significantly higher values of cadmium, lead and zinc were recorded in the most urbanized areas, and were strongly related to the vehicle fleet and to the demographic density in these sites. The results demonstrated that these parameters could be applied to the diagnosis of environmental quality in urban areas, allowing standardized analyses in other regions. Copyright © 2017 Elsevier B.V. All rights reserved.

  18. Partitional clustering algorithms

    CERN Document Server

    2015-01-01

    This book summarizes the state-of-the-art in partitional clustering. Clustering, the unsupervised classification of patterns into groups, is one of the most important tasks in exploratory data analysis. Primary goals of clustering include gaining insight into, classifying, and compressing data. Clustering has a long and rich history that spans a variety of scientific disciplines including anthropology, biology, medicine, psychology, statistics, mathematics, engineering, and computer science. As a result, numerous clustering algorithms have been proposed since the early 1950s. Among these algorithms, partitional (nonhierarchical) ones have found many applications, especially in engineering and computer science. This book provides coverage of consensus clustering, constrained clustering, large scale and/or high dimensional clustering, cluster validity, cluster visualization, and applications of clustering. Examines clustering as it applies to large and/or high-dimensional data sets commonly encountered in reali...

  19. Effects of carbonyl bond, metal cluster dissociation, and evaporation rates on predictions of nanotube production in high-pressure carbon monoxide

    Science.gov (United States)

    Scott, Carl D.; Smalley, Richard E.

    2003-01-01

    The high-pressure carbon monoxide (HiPco) process for producing single-wall carbon nanotubes (SWNTs) uses iron pentacarbonyl as the source of iron for catalyzing the Boudouard reaction. Attempts using nickel tetracarbonyl led to no production of SWNTs. This paper discusses simulations at a constant condition of 1300 K and 30 atm in which the chemical rate equations are solved for different reaction schemes. A lumped cluster model is developed to limit the number of species in the models, yet it includes fairly large clusters. Reaction rate coefficients in these schemes are based on bond energies of iron and nickel species and on estimates of chemical rates for formation of SWNTs. SWNT growth is measured by the conformation of CO2. It is shown that the production of CO2 is significantly greater for FeCO because of its lower bond energy as compared with that of NiCO. It is also shown that the dissociation and evaporation rates of atoms from small metal clusters have a significant effect on CO2 production. A high rate of evaporation leads to a smaller number of metal clusters available to catalyze the Boudouard reaction. This suggests that if CO reacts with metal clusters and removes atoms from them by forming MeCO, this has the effect of enhancing the evaporation rate and reducing SWNT production. The study also investigates some other reactions in the model that have a less dramatic influence.

  20. Three exciting areas of experimental physical sciences : high temperature superconductors, metal clusters and super molecules of carbon

    International Nuclear Information System (INIS)

    Rao, C.N.

    1992-01-01

    The author has narrated his experience in carrying out research in three exciting areas of physical sciences. These areas are : high temperature superconductors, metal clusters and super molecules of carbon. (M.G.B.)