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Sample records for metal foam components

  1. Gradient composite metal-ceramic foam as supportive component for planar SOFCs and MIEC membranes

    International Nuclear Information System (INIS)

    Smorygo, Oleg; Mikutski, Vitali; Marukovich, Alexander; Sadykov, Vladislav; Usoltsev, Vladimir; Mezentseva, Natalia; Borodinecs, Anatolijs; Bobrenok, Oleg

    2011-01-01

    A novel approach to the design of planar gradient porous supports for the thin-film SOFCs and MIEC membranes is described. The support's thermal expansion is controlled by the creation of a two-component composite metal-ceramic foam structure. Thin MIEC membranes and SOFCs were prepared on the composite supports by the layerwise deposition of composite functional layers including complex fluorites and perovskites. Lab-scale studies demonstrated promising performance of both MIEC membrane and SOFC.

  2. Gradient composite metal-ceramic foam as supportive component for planar SOFCs and MIEC membranes

    Science.gov (United States)

    Smorygo, Oleg; Mikutski, Vitali; Marukovich, Alexander; Sadykov, Vladislav; Usoltsev, Vladimir; Mezentseva, Natalia; Borodinecs, Anatolijs; Bobrenok, Oleg

    2011-06-01

    A novel approach to the design of planar gradient porous supports for the thin-film SOFCs and MIEC membranes is described. The support's thermal expansion is controlled by the creation of a two-component composite metal-ceramic foam structure. Thin MIEC membranes and SOFCs were prepared on the composite supports by the layerwise deposition of composite functional layers including complex fluorites and perovskites. Lab-scale studies demonstrated promising performance of both MIEC membrane and SOFC.

  3. Nanostructured metal foams: synthesis and applications

    Energy Technology Data Exchange (ETDEWEB)

    Luther, Erik P [Los Alamos National Laboratory; Tappan, Bryce [Los Alamos National Laboratory; Mueller, Alex [Los Alamos National Laboratory; Mihaila, Bogdan [Los Alamos National Laboratory; Volz, Heather [Los Alamos National Laboratory; Cardenas, Andreas [Los Alamos National Laboratory; Papin, Pallas [Los Alamos National Laboratory; Veauthier, Jackie [Los Alamos National Laboratory; Stan, Marius [Los Alamos National Laboratory

    2009-01-01

    Fabrication of monolithic metallic nanoporous materials is difficult using conventional methodology. Here they report a relatively simple method of synthesizing monolithic, ultralow density, nanostructured metal foams utilizing self-propagating combustion synthesis of novel metal complexes containing high nitrogen energetic ligands. Nanostructured metal foams are formed in a post flame-front dynamic assembly with densities as low as 0.011 g/cc and surface areas as high as 270 m{sup 2}/g. They have produced metal foams via this method of titanium, iron, cobalt, nickel, zirconium, copper, palladium, silver, hafnium, platinum and gold. Microstructural features vary as a function of composition and process parameters. Applications for the metal foams are discussed including hydrogen absorption in palladium foams. A model for the sorption kinetics of hydrogen in the foams is presented.

  4. Structural applications of metal foams considering material and geometrical uncertainty

    Science.gov (United States)

    Moradi, Mohammadreza

    Metal foam is a relatively new and potentially revolutionary material that allows for components to be replaced with elements capable of large energy dissipation, or components to be stiffened with elements which will generate significant supplementary energy dissipation when buckling occurs. Metal foams provide a means to explore reconfiguring steel structures to mitigate cross-section buckling in many cases and dramatically increase energy dissipation in all cases. The microstructure of metal foams consists of solid and void phases. These voids have random shape and size. Therefore, randomness ,which is introduced into metal foams during the manufacturing processes, creating more uncertainty in the behavior of metal foams compared to solid steel. Therefore, studying uncertainty in the performance metrics of structures which have metal foams is more crucial than for conventional structures. Therefore, in this study, structural application of metal foams considering material and geometrical uncertainty is presented. This study applies the Sobol' decomposition of a function of many random variables to different problem in structural mechanics. First, the Sobol' decomposition itself is reviewed and extended to cover the case in which the input random variables have Gaussian distribution. Then two examples are given for a polynomial function of 3 random variables and the collapse load of a two story frame. In the structural example, the Sobol' decomposition is used to decompose the variance of the response, the collapse load, into contributions from the individual input variables. This decomposition reveals the relative importance of the individual member yield stresses in determining the collapse load of the frame. In applying the Sobol' decomposition to this structural problem the following issues are addressed: calculation of the components of the Sobol' decomposition by Monte Carlo simulation; the effect of input distribution on the Sobol' decomposition

  5. Manufacturing of Cast Metal Foams with Irregular Cell Structure

    Directory of Open Access Journals (Sweden)

    Kroupová I.

    2015-06-01

    Full Text Available Metallic foams are materials of which the research is still on-going, with the broad applicability in many different areas (e.g. automotive industry, building industry, medicine, etc.. These metallic materials have specific properties, such as large rigidity at low density, high thermal conductivity, capability to absorb energy, etc. The work is focused on the preparation of these materials using conventional casting technology (infiltration method, which ensures rapid and economically feasible method for production of shaped components. In the experimental part we studied conditions of casting of metallic foams with open pores and irregular cell structure made of ferrous and nonferrous alloys by use of various types of filler material (precursors.

  6. Investigation into stress wave propagation in metal foams

    Directory of Open Access Journals (Sweden)

    Li Lang

    2015-01-01

    Full Text Available The aim of this study is to investigate stress wave propagation in metal foams under high-speed impact loading. Three-dimensional Voronoi model is established to represent real closed-cell foam. Based on the one-dimensional stress wave theory and Voronoi model, a numerical model is developed to calculate the velocity of elastic wave and shock wave in metal foam. The effects of impact velocity and relative density of metal foam on the stress wave propagation in metal foams are explored respectively. The results show that both elastic wave and shock wave propagate faster in metal foams with larger relative density; with increasing the impact velocity, the shock wave propagation velocity increase, but the elastic wave propagation is not sensitive to the impact velocity.

  7. Stability of metallic foams studied under microgravity

    CERN Document Server

    Wuebben, T; Banhart, J; Odenbach, S

    2003-01-01

    Metal foams are prepared by mixing a metal powder and a gas-releasing blowing agent, by densifying the mix to a dense precursor and finally foaming by melting the powder compact. The foaming process of aluminium foams is monitored in situ by x-ray radioscopy. One observes that foam evolution is accompanied by film rupture processes which lead to foam coalescence. In order to elucidate the importance of oxides for foam stability, lead foams were manufactured from lead powders having two different oxide contents. The two foam types were generated on Earth and under weightlessness during parabolic flights. The measurements show that the main function of oxide particles is to prevent coalescence, while their influence on bulk viscosity of the melt is of secondary importance.

  8. Oxidation behaviour of metallic glass foams

    Energy Technology Data Exchange (ETDEWEB)

    Barnard, B.R. [Department of Materials Science and Engineering, 434 Dougherty Hall, University of Tennessee, Knoxville, TN 37996-2200 (United States)], E-mail: bbarnard@utk.edu; Liaw, P.K. [Department of Materials Science and Engineering, 434 Dougherty Hall, University of Tennessee, Knoxville, TN 37996-2200 (United States); Demetriou, M.D.; Johnson, W.L. [Department of Materials Science, Keck Laboratory, California Institute of Technology, Pasadena, CA 91125 (United States)

    2008-08-15

    In this study, the effects of porosity on the oxidation behaviour of bulk-metallic glasses were investigated. Porous Pd- and Fe-based bulk-metallic glass (BMG) foams and Metglas ribbons were studied. Oxidizing experiments were conducted at 70 deg. C, and around 80 deg. C below glass-transition temperatures, (T{sub g}s). Scanning-electron microscopy/energy-dispersive spectroscopy (SEM/EDS) studies revealed little evidence of oxidation at 70 deg. C. Specimens exhibited greater oxidation at T{sub g} - 80 deg. C. Oxides were copper-based for Pd-based foams, Fe-, Cr-, and Mo-based for Fe-based foams, and Co-based with borosilicates likely for the Metglas. Pd-based foams demonstrated the best oxidation resistance, followed by Metglas ribbons, followed by Fe-based foams.

  9. Numerical study of metal foam heat sinks under uniform impinging flow

    International Nuclear Information System (INIS)

    Andreozzi, A; Bianco, N; Iasiello, M; Naso, V

    2017-01-01

    The ever-increasing demand for performance improvement and miniaturization of electronics has led to a significant generation of waste heat that must be dissipated to ensure a reliable device operation. The miniaturization of the components complicates this task. In fact, reducing the heat transfer area, at the same required heat rate, it is necessary to increase the heat flux, so that the materials operate in a temperature range suitable to its proper functioning. Traditional heat sinks are no longer capable of dissipating the generated heat and innovative approaches are needed to address the emerging thermal management challenges. Recently, heat transfer in open-cell metal foams under an impinging jet has received attention due to the considerable heat transfer potential of combining two cooling technologies: impinging jet and porous medium. This paper presents a numerical study on Finned Metal Foam (FMF) and Metal Foam (MF) heat sinks under impinging air jet cooling. The analysis is carried out by means of the commercial software COMSOL Multiphysics®. The purpose is to analyze the thermal performance of the metal foam heat sink, finned or not, varying its geometric parameters. Results are presented in terms of predicted dissipated heat rate, convective heat transfer coefficient and pressure losses. (paper)

  10. Numerical simulation of heat transfer in metal foams

    Science.gov (United States)

    Gangapatnam, Priyatham; Kurian, Renju; Venkateshan, S. P.

    2018-02-01

    This paper reports a numerical study of forced convection heat transfer in high porosity aluminum foams. Numerical modeling is done considering both local thermal equilibrium and non local thermal equilibrium conditions in ANSYS-Fluent. The results of the numerical model were validated with experimental results, where air was forced through aluminum foams in a vertical duct at different heat fluxes and velocities. It is observed that while the LTE model highly under predicts the heat transfer in these foams, LTNE model predicts the Nusselt number accurately. The novelty of this study is that once hydrodynamic experiments are conducted the permeability and porosity values obtained experimentally can be used to numerically simulate heat transfer in metal foams. The simulation of heat transfer in foams is further extended to find the effect of foam thickness on heat transfer in metal foams. The numerical results indicate that though larger foam thicknesses resulted in higher heat transfer coefficient, this effect weakens with thickness and is negligible in thick foams.

  11. Metal-doped organic foam and method of making same. [Patent application

    Science.gov (United States)

    Rinde, J.A.

    Organic foams having a low density and very small cell size and method for producing same in either a metal-loaded or unloaded (nonmetal loaded) form are described. Metal-doped foams are produced by soaking a polymer gel in an aqueous solution of desired metal salt, soaking the gel successively in a solvent series of decreasing polarity to remove water from the gel and replace it with a solvent of lower polarity with each successive solvent in the series being miscible with the solvents on each side and being saturated with the desired metal salt, and removing the last of the solvents from the gel to produce the desired metal-doped foam having desired density cell size, and metal loading. The unloaded or metal-doped foams can be utilized in a variety of applications requiring low density, small cell size foam. For example, rubidium-doped foam made in accordance with the invention has utility in special applications, such as in x-ray lasers.

  12. Simulated Tip Rub Testing of Low-Density Metal Foam

    Science.gov (United States)

    Bowman, Cheryl L.; Jones, Michael G.

    2009-01-01

    Preliminary acoustic studies have indicated that low-density, open-cell, metal foams may be suitable acoustic liner material for noise suppression in high by-pass engines. Metal foam response under simulated tip rub conditions was studied to assess whether its durability would be sufficient for the foam to serve both as a rub strip above the rotor as well as an acoustic treatment. Samples represented four metal alloys, nominal cell dimensions ranging from 60 to 120 cells per inch (cpi), and relative densities ranging from 3.4 to 10 percent. The resulting rubbed surfaces were relatively smooth and the open cell structure of the foam was not adversely affected. Sample relative density appeared to have significant influence on the forces induced by the rub event. Acoustic responses of various surface preparations were measured using a normal incidence tube. The results of this study indicate that the foam s open-cell structure was retained after rubbing and that the acoustic absorption spectra variation was minimal.

  13. Experimental investigation of solidification in metal foam enhanced phase change material

    Science.gov (United States)

    Beyne, W.; Bağci, O.; Huisseune, H.; Canière, H.; Danneels, J.; Daenens, D.; De Paepe, M.

    2017-10-01

    A major challenge for the use of phase change materials (PCMs) in thermal energy storage (TES) is overcoming the low thermal conductivity of PCM’s. The low conductivity gives rise to limited power during charging and discharging TES. Impregnating metal foam with PCM, however, has been found to enhance the heat transfer. On the other hand, the effect of foam parameters such as porosity, pore size and material type has remained unclear. In this paper, the effect of these foam parameters on the solidification time is investigated. Different samples of PCM-impregnated metal foam were experimentally tested and compared to one without metal foam. The samples varied with respect to choice of material, porosity and pore size. They were placed in a rectangular cavity and cooled from one side using a coolant flowing through a cold plate. The other sides of the rectangular cavity were Polymethyl Methacrylate (PM) walls exposed to ambient. The temperature on the exterior walls of the cavity was monitored as well as the coolant flow rate and its temperature. The metal foam inserts reduced the solidification times by at least 25 %. However, the difference between the best performing and worst performing metal foam is about 28 %. This shows a large potential for future research.

  14. Forming foam structures with carbon foam substrates

    Science.gov (United States)

    Landingham, Richard L.; Satcher, Jr., Joe H.; Coronado, Paul R.; Baumann, Theodore F.

    2012-11-06

    The invention provides foams of desired cell sizes formed from metal or ceramic materials that coat the surfaces of carbon foams which are subsequently removed. For example, metal is located over a sol-gel foam monolith. The metal is melted to produce a metal/sol-gel composition. The sol-gel foam monolith is removed, leaving a metal foam.

  15. Geometrical characterization of perlite-metal syntactic foam

    Energy Technology Data Exchange (ETDEWEB)

    Borovinšek, Matej, E-mail: matej.borovinsek@um.si [University of Maribor, Faculty of Mechanical Engineering, Smetanova ulica 17, 2000 Maribor (Slovenia); Taherishargh, Mehdi, E-mail: mehdi.taherishargh@newcastle.edu.au [The University of Newcastle, School of Engineering, University Drive, Callaghan, NSW 2308 (Australia); Vesenjak, Matej, E-mail: matej.vesenjak@um.si [University of Maribor, Faculty of Mechanical Engineering, Smetanova ulica 17, 2000 Maribor (Slovenia); Ren, Zoran, E-mail: zoran.ren@um.si [University of Maribor, Faculty of Mechanical Engineering, Smetanova ulica 17, 2000 Maribor (Slovenia); Fiedler, Thomas, E-mail: thomas.fiedler@newcastle.edu.au [The University of Newcastle, School of Engineering, University Drive, Callaghan, NSW 2308 (Australia)

    2016-09-15

    This paper introduces an improved method for the detailed geometrical characterization of perlite-metal syntactic foam. This novel metallic foam is created by infiltrating a packed bed of expanded perlite particles with liquid aluminium alloy. The geometry of the solidified metal is thus defined by the perlite particle shape, size and morphology. The method is based on a segmented micro-computed tomography data and allows for automated determination of the distributions of pore size, sphericity, orientation and location. The pore (i.e. particle) size distribution and pore orientation is determined by a multi-criteria k-nearest neighbour algorithm for pore identification. The results indicate a weak density gradient parallel to the casting direction and a slight preference of particle orientation perpendicular to the casting direction. - Highlights: •A new method for identification of pores in porous materials was developed. •It was applied on perlite-metal syntactic foam samples. •A porosity decrease in the axial direction of the samples was determined. •Pore shape analysis showed a high percentage of spherical pores. •Orientation analysis showed that more pores are oriented in the radial direction.

  16. Numerical Simulations of Particle Deposition in Metal Foam Heat Exchangers

    Science.gov (United States)

    Sauret, Emilie; Saha, Suvash C.; Gu, Yuantong

    2013-01-01

    Australia is a high-potential country for geothermal power with reserves currently estimated in the tens of millions of petajoules, enough to power the nation for at least 1000 years at current usage. However, these resources are mainly located in isolated arid regions where water is scarce. Therefore, wet cooling systems for geothermal plants in Australia are the least attractive solution and thus air-cooled heat exchangers are preferred. In order to increase the efficiency of such heat exchangers, metal foams have been used. One issue raised by this solution is the fouling caused by dust deposition. In this case, the heat transfer characteristics of the metal foam heat exchanger can dramatically deteriorate. Exploring the particle deposition property in the metal foam exchanger becomes crucial. This paper is a numerical investigation aimed to address this issue. Two-dimensional (2D) numerical simulations of a standard one-row tube bundle wrapped with metal foam in cross-flow are performed and highlight preferential particle deposition areas.

  17. Analysis of Stainless Steel Sandwich Panels with a Metal Foam Care for Lightweight Fan Blade Design

    Science.gov (United States)

    Min, James B.; Ghosn, Louis J.; Lerch, Bradley A.; Raj, Sai V.; Holland, Frederic A., Jr.; Hebsur, Mohan G.

    2004-01-01

    The quest for cheap, low density and high performance materials in the design of aircraft and rotorcraft engine fan and propeller blades poses immense challenges to the materials and structural design engineers. Traditionally, these components have been fabricated using expensive materials such as light weight titanium alloys, polymeric composite materials and carbon-carbon composites. The present study investigates the use of P sandwich foam fan blade made up of solid face sheets and a metal foam core. The face sheets and the metal foam core material were an aerospace grade precipitation hardened 17-4 PH stainless steel with high strength and high toughness. The stiffness of the sandwich structure is increased by separating the two face sheets by a foam core. The resulting structure possesses a high stiffness while being lighter than a similar solid construction. Since the face sheets carry the applied bending loads, the sandwich architecture is a viable engineering concept. The material properties of 17-4 PH metal foam are reviewed briefly to describe the characteristics of the sandwich structure for a fan blade application. A vibration analysis for natural frequencies and P detailed stress analysis on the 17-4 PH sandwich foam blade design for different combinations of skin thickness and core volume %re presented with a comparison to a solid titanium blade.

  18. Analysis of Influence of Foaming Mixture Components on Structure and Properties of Foam Glass

    Science.gov (United States)

    Karandashova, N. S.; Goltsman, B. M.; Yatsenko, E. A.

    2017-11-01

    It is recommended to use high-quality thermal insulation materials to increase the energy efficiency of buildings. One of the best thermal insulation materials is foam glass - durable, porous material that is resistant to almost any effect of substance. Glass foaming is a complex process depending on the foaming mode and the initial mixture composition. This paper discusses the influence of all components of the mixture - glass powder, foaming agent, enveloping material and water - on the foam glass structure. It was determined that glass powder is the basis of the future material. A foaming agent forms a gas phase in the process of thermal decomposition. This aforementioned gas foams the viscous glass mass. The unreacted residue thus changes a colour of the material. The enveloping agent slows the foaming agent decomposition preventing its premature burning out and, in addition, helps to accelerate the sintering of glass particles. The introduction of water reduces the viscosity of the foaming mixture making it evenly distributed and also promotes the formation of water gas that additionally foams the glass mass. The optimal composition for producing the foam glass with the density of 150 kg/m3 is defined according to the results of the research.

  19. Novel biopolymer-coated hydroxyapatite foams for removing heavy-metals from polluted water

    International Nuclear Information System (INIS)

    Vila, M.; Sanchez-Salcedo, S.; Cicuendez, M.; Izquierdo-Barba, I.; Vallet-Regi, Maria

    2011-01-01

    Highlights: → 3D-macroporous biopolymer-coated hydroxyapatite (HA) foams as potential devices for the treatment of heavy metal ions. → HA stable foams coated with biopolymers. → Feasible advance in development of new, easy to handle and low cost water purifying methods. - Abstract: 3D-macroporous biopolymer-coated hydroxyapatite (HA) foams have been developed as potential devices for the treatment of lead, cadmium and copper contamination of consumable waters. These foams have exhibited a fast and effective ion metal immobilization into the HA structure after an in vitro treatment mimicking a serious water contamination case. To improve HA foam stability at contaminated aqueous solutions pH, as well as its handling and shape integrity the 3D-macroporous foams have been coated with biopolymers polycaprolactone (PCL) and gelatine cross-linked with glutaraldehyde (G/Glu). Metal ion immobilization tests have shown higher and fast heavy metals captured as function of hydrophilicity rate of biopolymer used. After an in vitro treatment, foam morphology integrity is guaranteed and the uptake of heavy metal ions rises up to 405 μmol/g in the case of Pb 2+ , 378 μmol/g of Cu 2+ and 316 μmol/g of Cd 2+ . These novel materials promise a feasible advance in development of new, easy to handle and low cost water purifying methods.

  20. Creep of sandwich beams with metallic foam cores

    International Nuclear Information System (INIS)

    Kesler, O.; Crews, L.K.; Gibson, L.J.

    2003-01-01

    The steady state creep deflection rates of sandwich beams with metallic foam cores were measured and compared with analytical and numerical predictions of the creep behavior. The deflection rate depends on the geometry of the sandwich beam, the creep behavior of the foam core and the loading conditions (stress state, temperature). Although there was a considerable scatter in the creep data (both of the foams and of the sandwich beams made using them), the data for the sandwich beams were fairly well described by the analysis

  1. Creep of sandwich beams with metallic foam cores

    Energy Technology Data Exchange (ETDEWEB)

    Kesler, O.; Crews, L.K.; Gibson, L.J

    2003-01-20

    The steady state creep deflection rates of sandwich beams with metallic foam cores were measured and compared with analytical and numerical predictions of the creep behavior. The deflection rate depends on the geometry of the sandwich beam, the creep behavior of the foam core and the loading conditions (stress state, temperature). Although there was a considerable scatter in the creep data (both of the foams and of the sandwich beams made using them), the data for the sandwich beams were fairly well described by the analysis.

  2. Morphing Metal and Elastomer Bicontinuous Foams for Reversible Stiffness, Shape Memory, and Self-Healing Soft Machines.

    Science.gov (United States)

    Van Meerbeek, Ilse M; Mac Murray, Benjamin C; Kim, Jae Woo; Robinson, Sanlin S; Zou, Perry X; Silberstein, Meredith N; Shepherd, Robert F

    2016-04-13

    A metal-elastomer-foam composite that varies in stiffness, that can change shape and store shape memory, that self-heals, and that welds into monolithic structures from smaller components is presented. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  3. Preparation of microcellular foam in cylindrical metal targets

    International Nuclear Information System (INIS)

    Apen, P.G.; Armstrong, S.V.; Moore, J.E.; Espinoza, B.F.; Gurule, V.; Gobby, P.L.; Williams, J.M.

    1992-01-01

    The preparation of microcellular foam in cylindrical gold targets is described. The goal cylinders were fabricated by electroplating gold onto a silicon bronze mandrel and leaching the mandrel with concentrated nitric acid. After several rinsing and cleaning steps, the cylinders were filled with a solution containing trimethylolpropanetriacrylate (TMPTA). Low density, microcellular polymeric foam was prepared by in situ photopolymerization of the TMPTA solution. Foam preparation was extremely sensitive to metal ion contaminants. In particular, copper ions left behind from the leaching process inhibit polymerization and must be removed in order to obtain uniform, non-shrinking foams. A study on the effects of potential contaminants and polymerization inhibitors on TMPTA photopolymerization is presented. In addition, a procedure for the effective leaching and cleaning of gold cylinders is described

  4. Foam decontamination of large nuclear components before dismantling

    International Nuclear Information System (INIS)

    Costes, J.R.; Sahut, C.

    1998-01-01

    Following some simple theoretical considerations, the authors show that foam compositions can be advantageously circulated them for a few hours in components requiring decontamination before dismantling. The technique is illustrated on six large ferritic steel valves, then on austenitic steel heat exchangers for which the Ce(III)/Ce(IV) redox pair was used to dissolve the chromium; Ce(III) was reoxidized by ozone injection into the foam vector gas. Biodegradable surfactants are sued in the process; tests have shown that the foaming power disappears after a few days, provided the final radioactive liquid waste is adjusted to neutral pH, allowing subsequent coprecipitation of concentration treatment. (author)

  5. Forming and bending of metal foams

    International Nuclear Information System (INIS)

    Nebosky, Paul; Tyszka, Daniel; Niebur, Glen; Schmid, Steven

    2004-01-01

    This study examines the formability of a porous tantalum foam, known as trabecular metal (TM). Used as a bone ingrowth surface on orthopedic implants, TM is desirable due to its combination of high strength, low relative density, and excellent osteoconductive properties. This research aims to develop bend and stretch forming as a cost-effective alternative to net machining and EDM for manufacturing thin parts made of TM. Experimentally, bending about a single axis using a wiping die was studied by observing cracking and measuring springback. It was found that die radius and clearance strongly affect the springback properties of TM, while punch speed, embossings, die radius and clearance all influence cracking. Depending on the various combinations of die radius and clearance, springback factor ranged from .70-.91. To examine the affect of the foam microstructure, bending also was examined numerically using a horizontal hexagonal mesh. As the hexagonal cells were elongated along the sheet length, elastic springback decreased. This can be explained by the earlier onset of plastic hinging occurring at the vertices of the cells. While the numerical results matched the experimental results for the case of zero clearance, differences at higher clearances arose due to an imprecise characterization of the post-yield properties of tantalum. By changing the material properties of the struts, the models can be modified for use with other open-cell metallic foams

  6. Impact of foamed matrix components on foamed concrete properties

    Science.gov (United States)

    Tarasenko, V. N.

    2018-03-01

    The improvement of the matrix foam structure by means of foam stabilizing additives is aimed at solving the technology-oriented problems as well as at the further improvement of physical and mechanical properties of cellular-concrete composites. The dry foam mineralization is the mainstream of this research. Adding the concrete densifiers, foam stabilizers and mineral powders reduces the drying shrinkage, which makes the foam concrete products technologically effective.

  7. The dynamic properties of sandwich structures based on metal-ceramic foams.

    Science.gov (United States)

    2014-01-01

    The present research program has studied the fracture properties of closed pore metal-ceramic foams for their potential applications as core systems in sandwich structures. The composite foams were created at Fireline, Inc. (Youngstown, OH) using the...

  8. Heat Transfer in Metal Foam Heat Exchangers at High Temperature

    Science.gov (United States)

    Hafeez, Pakeeza

    Heat transfer though open-cell metal foam is experimentally studied for heat exchanger and heat shield applications at high temperatures (˜750°C). Nickel foam sheets with pore densities of 10 and 40 pores per linear inch (PPI), have been used to make the heat exchangers and heat shields by using thermal spray coating to deposit an Inconel skin on a foam core. Heat transfer measurements were performed on a test rig capable of generating hot gas up to 1000°C. The heat exchangers were tested by exposing their outer surface to combustion gases at a temperature of 550°C and 750°C while being cooled by air flowing through them at room temperature at velocities up to 5 m/s. The temperature rise of the air, the surface temperature of the heat exchangers and the air temperature inside the heat exchanger were measured. The volumetric heat transfer coefficient and Nusselt number were calculated for different velocities. The heat transfer performance of the 40PPI sample brazed with the foil is found to be the most efficient. Pressure drop measurements were also performed for 10 and 40PPI metal foam. Thermographic measurements were done on 40PPI foam heat exchangers using a high temperature infrared camera. A high power electric heater was used to produce hot air at 300°C that passed over the foam heat exchanger while the cooling air was blown through it. Heat shields were made by depositing porous skins on metal foam and it was observed that a small amount of coolant leaking through the pores notably reduces the heat transfer from the hot gases. An analytical model was developed based assuming local thermal non-equilibrium that accounts for the temperature difference between solid and fluid phase. The experimental results are found to be in good agreement with the predicted values of the model.

  9. Copper metal foam as an essential construction element of innovative heat exchanger

    Directory of Open Access Journals (Sweden)

    R. Rybár

    2016-07-01

    Full Text Available Paper deals with creation of the innovative heat exchanger - manifold header for the heat pipe evacuated tube solar collector, which essential functional element is heat exchange chamber made of the copper metal foam. Design of the heat exchanger is based on effective utilization of the unique properties of the metal foam which makes it possible to design highly effective and space saving devices. Inner volume of heat exchanger was reducing from 0,00045 m3 to 0,000135 m3 and heat exchange surface was increase from 0,0104 m2 to 0,1403 m2 at proposed prototype, what drastically increase heat exchange efficiency. The proposal itself is based on the unique physical properties of the metal foam, which was described by computational analysis.

  10. Performance analysis of a membrane humidifier containing porous metal foam as flow distributor in a PEM fuel cell system

    International Nuclear Information System (INIS)

    Afshari, Ebrahim; Baharlou Houreh, Nasser

    2014-01-01

    Highlights: • Three metal foam configurations for the membrane humidifier are introduced. • The performances of the humidifiers containing metal foam are investigated. • A 3D CFD model is developed to compare the introduced humidifiers with one another. • Using metal foam at dry side has no positive effect on the humidifier performance. - Abstract: Using metal foam as flow distributor in membrane humidifier for proton exchange membrane (PEM) fuel cell system has some unique characteristics like more water transfer, low manufacturing complexity and low cost compared to the conventional flow channel plate. Metal foam can be applied at wet side or dry side or both sides of a humidifier. The three-dimensional CFD models are developed to investigate the performance of the above mentioned meanwhile compare them with the conventional humidifier. This model consists of a set of coupled equations including conservations of mass, momentum, species and energy for all regions of the humidifier. The results indicate that with the metal foam installed at wet side and both sides, water recovery ratio and dew point at dry side outlet are more than that of the conventional humidifier, indicating a better humidifier performance; while using metal foam at dry side has no positive effect on humidifier performance. At dry side mass flow rates higher than 10 mgr/s pressure drop in humidifier containing metal foam at wet side is lower than that of the conventional humidifier. As the mass flow rate increases from 9 to 15 mgr/s humidifier containing metal foam at wet side has better performance, while at mass flow rates lower than 9 mgr/s, the humidifier containing metal foam at both sides has better performance. At dry side inlet temperatures lower than 303 K, humidifier containing metal foam at wet side has better performance and at temperatures higher than 303 K, humidifier containing metal foam at both sides has better performance

  11. Normal force of magnetorheological fluids with foam metal under oscillatory shear modes

    Energy Technology Data Exchange (ETDEWEB)

    Yao, Xingyan, E-mail: yaoxingyan-jsj@163.com [Research Center of System Health Maintenance, Chongqing Technology and Business University, Chongqing 400067 (China); Chongqing Engineering Laboratory for Detection Control and Integrated System, Chongqing 400067 (China); Liu, Chuanwen; Liang, Huang; Qin, Huafeng [Chongqing Engineering Laboratory for Detection Control and Integrated System, Chongqing 400067 (China); Yu, Qibing; Li, Chuan [Research Center of System Health Maintenance, Chongqing Technology and Business University, Chongqing 400067 (China); Chongqing Engineering Laboratory for Detection Control and Integrated System, Chongqing 400067 (China)

    2016-04-01

    The normal force of magnetorheological (MR) fluids in porous foam metal was investigated in this paper. The dynamic repulsive normal force was studied using an advanced commercial rheometer under oscillatory shear modes. In the presence of magnetic fields, the influences of time, strain amplitude, frequency and shear rate on the normal force of MR fluids drawn from the porous foam metal were systematically analysed. The experimental results indicated that the magnetic field had the greatest effect on the normal force, and the effect increased incrementally with the magnetic field. Increasing the magnetic field produced a step-wise increase in the shear gap. However, other factors in the presence of a constant magnetic field only had weak effects on the normal force. This behaviour can be regarded as a magnetic field-enhanced normal force, as increases in the magnetic field resulted in more MR fluids being released from the porous foam metal, and the chain-like magnetic particles in the MR fluids becoming more elongated with aggregates spanning the gap between the shear plates. - Highlights: • Normal force of MR fluids with metal foam under oscillatory shear modes was studied. • The shear gap was step-wise increased with magnetic fields. • The magnetic field has a greater impact on the normal force.

  12. Normal force of magnetorheological fluids with foam metal under oscillatory shear modes

    International Nuclear Information System (INIS)

    Yao, Xingyan; Liu, Chuanwen; Liang, Huang; Qin, Huafeng; Yu, Qibing; Li, Chuan

    2016-01-01

    The normal force of magnetorheological (MR) fluids in porous foam metal was investigated in this paper. The dynamic repulsive normal force was studied using an advanced commercial rheometer under oscillatory shear modes. In the presence of magnetic fields, the influences of time, strain amplitude, frequency and shear rate on the normal force of MR fluids drawn from the porous foam metal were systematically analysed. The experimental results indicated that the magnetic field had the greatest effect on the normal force, and the effect increased incrementally with the magnetic field. Increasing the magnetic field produced a step-wise increase in the shear gap. However, other factors in the presence of a constant magnetic field only had weak effects on the normal force. This behaviour can be regarded as a magnetic field-enhanced normal force, as increases in the magnetic field resulted in more MR fluids being released from the porous foam metal, and the chain-like magnetic particles in the MR fluids becoming more elongated with aggregates spanning the gap between the shear plates. - Highlights: • Normal force of MR fluids with metal foam under oscillatory shear modes was studied. • The shear gap was step-wise increased with magnetic fields. • The magnetic field has a greater impact on the normal force.

  13. Metal foams as gas coolers for exhaust gas recirculation systems subjected to particulate fouling

    International Nuclear Information System (INIS)

    Hooman, K.; Malayeri, M.R.

    2016-01-01

    Highlights: • Fouling of metal foam heat exchangers as EGR gas coolers is tested. • An optimal design was inferred based on the generated data. • A simple cleaning technique was suggested and evaluated. - Abstract: This paper presents experimental results indicating the benefits and challenges associated with the use of metal foams as Exhaust Gas Recirculation (EGR) coolers. Fouling of such heat exchangers is a critical issue and, as such, special attention has been paid to address this very issue in the present study where a soot generator has been employed to simulate the engine running condition. Effects of aluminium foam PPI and height as well as gas velocity are investigated. It has been noted that proper design of the foam can lead to significantly higher heat transfer rate and reasonable pressure drop compared to no-foam cases. More interestingly, it is demonstrated that the foams can be cleaned easily without relying on expensive cleaning techniques. Using simple brush-cleaning, the foams can be reused as EGR gas coolers with a performance penalty of only 17% (compared to a new or clean foam).

  14. Foam-based adsorbents having high adsorption capacities for recovering dissolved metals and methods thereof

    Science.gov (United States)

    Janke, Christopher J.; Dai, Sheng; Oyola, Yatsandra

    2015-06-02

    Foam-based adsorbents and a related method of manufacture are provided. The foam-based adsorbents include polymer foam with grafted side chains and an increased surface area per unit weight to increase the adsorption of dissolved metals, for example uranium, from aqueous solutions. A method for forming the foam-based adsorbents includes irradiating polymer foam, grafting with polymerizable reactive monomers, reacting with hydroxylamine, and conditioning with an alkaline solution. Foam-based adsorbents formed according to the present method demonstrated a significantly improved uranium adsorption capacity per unit weight over existing adsorbents.

  15. USANS investigation of early stages of metal foam formation

    CERN Document Server

    Bellmann, D; Banhart, J

    2002-01-01

    Metallic foams are on the verge of being used in industrial applications. However, the mechanism of foam creation, especially the early stages, are still unexplored. Ultra small-angle neutron scattering (USANS), performed with the double-crystal diffractometer (DCD) at the Geesthacht Neutron Facility (GeNF), is a promising method for obtaining a three-dimensional average of a pore size distribution in a wide size range from about 100 nm to about 20 mu m. Analysis of the neutron scattering curves yielded pore size distributions which conformed with the results obtained by microscopy. (orig.)

  16. A constitutive model for the compressive response of metallic closed-cell foams including micro-inertia effects

    Directory of Open Access Journals (Sweden)

    Barthélémy Romain

    2015-01-01

    Full Text Available Metallic foams have known a keen interest in the last decades. Their ability to undergo very large deformations while transmitting low stress levels make them capable of performing functions of protective layers against intense loadings and of energy absorbers, for instance. The behaviour of metal foams varies considerably between quasi-static and dynamic regimes. Those differences can be linked to the strain-rate sensitivity of the skeleton material and to micro-inertial effects (induced by the crushing of the foam cells. In the present work, a micromechanical model has been developed to take into account micro-inertia effects on the macroscopic behaviour of closed-cell foams under dynamic loading conditions. The proposed modelling is based on the dynamic homogenisation procedure introduced by Molinari and Mercier (J. Mech. Phys. Solids 49 (2001 1497–1516. Within this framework, the macrostress is the sum of two terms. The first one is a static stress, that can be described with any existing model of metal foam. The second contribution is a dynamic stress related to micro-inertia effects. Considering an initially spherical shell as a Representative Volume Element (RVE of the foam material, a closed-form expression of the dynamic stress was obtained. The proposed modelling was applied to shock propagation in aluminium foams (it should however be noted that the present theory is not restricted to uniaxial deformation but can be applied to arbitrary loadings. From experimental data of the literature, it is observed that incorporating micro-inertia effects allows one to achieve a better description of the foam shock response. This indicates that micro-inertia may have a significant influence on the dynamic behaviour of metallic foams.

  17. Multi-Scale Modeling for Predicting the Stiffness and Strength of Hollow-Structured Metal Foams with Structural Hierarchy

    Directory of Open Access Journals (Sweden)

    Yong Yi

    2018-03-01

    Full Text Available This work was inspired by previous experiments which managed to establish an optimal template-dealloying route to prepare ultralow density metal foams. In this study, we propose a new analytical–numerical model of hollow-structured metal foams with structural hierarchy to predict its stiffness and strength. The two-level model comprises a main backbone and a secondary nanoporous structure. The main backbone is composed of hollow sphere-packing architecture, while the secondary one is constructed of a bicontinuous nanoporous network proposed to describe the nanoscale interactions in the shell. Firstly, two nanoporous models with different geometries are generated by Voronoi tessellation, then the scaling laws of the mechanical properties are determined as a function of relative density by finite volume simulation. Furthermore, the scaling laws are applied to identify the uniaxial compression behavior of metal foams. It is shown that the thickness and relative density highly influence the Young’s modulus and yield strength, and vacancy defect determines the foams being self-supported. The present study provides not only new insights into the mechanical behaviors of both nanoporous metals and metal foams, but also a practical guide for their fabrication and application.

  18. Research Plan: Foam Delivery of Remedial Amendments to Deep Vadose Zone for Metals and Radionuclides Remediation

    International Nuclear Information System (INIS)

    Zhong, Lirong; Hart, Andrea T.; Szecsody, James E.; Zhang, Z.F.; Freedman, Vicky L.; Ankeny, Mark; Hull, Laurence; Oostrom, Martinus; Freshley, Mark D.; Wellman, Dawn M.

    2009-01-01

    Research proposals were submitted to the Scientific and Technical Basis for In Situ Treatment of Metals and Radionuclides Technical Working Group under the US Department of Energy (DOE) Environmental Management Office (specifically, EM-22). After a peer review and selection process, the proposal, 'Foam Delivery of Remedial Amendments to Deep Vadose Zone for Metals and Radionuclides Remediation,' submitted by Pacific Northwest National Laboratory (PNNL) was selected for support by the program. A research plan was requested for this EM funded project. The overall objective of this project is to develop foam delivery technology for the distribution of remedial amendments to deep vadose zone sediments for in situ immobilization of metal and radionuclide contaminants. The focus of this research in FY 2009 is on the physical aspects of the foam delivery approach. Specific objectives are to (1) study the foam quality (i.e. the gas volume fraction in foam) influence on injection pressure, (2) study the sediment air permeability influence on injection pressure, (3) investigate liquid uptake in sediment and determine whether a water front will be formed during foam delivery, (4) test amendment distance (and mass) delivery by foam from the injection point, (5) study the enhanced sweeping over heterogeneous systems (i.e., low K zones) by foam delivery relative to water-based delivery under vadose zone conditions, and (6) numerically simulate foam delivery processes in the vadose zone. Laboratory scale experiments will be conducted at PNNL to study a range of basic physical aspects of the foam propagation in sediments, including foam quality and sediment permeability influence on injection pressure, liquid uptake, and foam sweeping across heterogeneous systems. This study will be augmented with separate studies to be conducted at MSE Technology Applications, Inc. (MSE) to evaluate foam transport and amendment delivery at the intermediate-scale. The results of intermediate

  19. Functional grading of metal foam cores for yield-limited lightweight sandwich beams

    International Nuclear Information System (INIS)

    Conde, Yves; Pollien, Arnaud; Mortensen, Andreas

    2006-01-01

    We show that grading the porosity in a bent metal skin/metal foam core sandwich can generate significant weight savings in yield-limited design when, and only when, there is a gradient in the applied moment along the sandwich beam

  20. Foam Glass for Construction Materials

    DEFF Research Database (Denmark)

    Petersen, Rasmus Rosenlund

    2016-01-01

    Foaming is commonly achieved by adding foaming agents such as metal oxides or metal carbonates to glass powder. At elevated temperature, the glass melt becomes viscous and the foaming agents decompose or react to form gas, causing a foamy glass melt. Subsequent cooling to room temperature, result...... in a solid foam glass. The foam glass industry employs a range of different melt precursors and foaming agents. Recycle glass is key melt precursors. Many parameters influence the foaming process and optimising the foaming conditions is very time consuming. The most challenging and attractive goal is to make...... low density foam glass for thermal insulation applications. In this thesis, it is argued that the use of metal carbonates as foaming agents is not suitable for low density foam glass. A reaction mechanism is proposed to justify this result. Furthermore, an in situ method is developed to optimise...

  1. Activity Tests of Macro-Meso Porous Catalysts over Metal Foam Plate for Steam Reforming of Bio-Ethanol.

    Science.gov (United States)

    Park, No-Kuk; Jeong, Yong Han; Kang, Misook; Lee, Tae Jin

    2018-09-01

    The catalytic activity of a macro-mesoporous catalyst coated on a metal foam plate in the reforming of bio-ethanol to synthesis gas was investigated. The catalysts were prepared by coating a support with a noble metal and transition metal. The catalytic activity for the production of synthetic gas by the reforming of bio-ethanol was compared according to the support material, reaction temperature, and steam/carbon ratio. The catalysts coated on the metal foams were prepared using a template method, in which macro-pores and meso-pores were formed by mixing polymer beads. In particular, the thermodynamic equilibrium composition of bio-ethanol reforming with the reaction temperature and steam/carbon ratio to produce synthetic gas was examined using the HSC (Enthalpy-Entropy-Heat capacity) chemistry program in this study. The composition of hydrogen and carbon monoxide in the reformate gas produced by steam reforming over the Rh/Ni-Ce-Zr/Al2O3-based pellet type catalysts and metal foam catalysts that had been coated with the Rh/Al-Ce-Zr-based catalysts was investigated by experimental activity tests. The activity of the metal foam catalyst was higher than that of the pellet type catalyst.

  2. Foam-Delivery of Remedial Amendments for Enhanced Vadose Zone Metals and Radionuclides Remediation

    International Nuclear Information System (INIS)

    Zhong, L.; Szecsody, J.E.; Dresel, P.E.; Zhang, Z.F.; Qafoku, N.P.

    2009-01-01

    The remediation of metals and radionuclides contamination, such as Cr(VI), Tc-99, and Sr-90 in the U.S. DOE Hanford Site vadose zone is a critical need. Water-based remedial amendments delivery to the deep vadose zone is facing significant technical challenges. Water-based delivery will easily leach out the highly mobile pollutants therefore contaminate the underlying aquifer. Preferential flow of the amendment-laden solution in the vadose zone due to the formation heterogeneity is difficult to overcome, resulting in bypassing of the less permeable zones. Foam has unique transport properties in the vadose zone that enable mitigation on the mobilization of mobile contaminants and enhance the sweeping over heterogeneous systems. Calcium polysulfide (CPS) is a remedial amendment that can be used to reduce and immobilize hexavalent chromium [Cr(VI)] and other redox-sensitive radionuclides/metals in the vadose zone. The delivery of CPS to the vadose zone using foam and the immobilization of Cr(VI) via reduction by the foam-delivered CPS was investigated in this study. Batch tests were conducted to select the foam-generating CPS-surfactant solutions, to determine the solution foamability and the reducing potential of CPS-containing foams, and to study the influence of foam quality, surfactant concentration, and CPS concentration on foam stability. Column experiments were performed to test the foam delivery of CPS to sediments under conditions similar to field vadose zone, to study the foam transport and interaction with sediments, and to determine the extent of Cr(VI) immobilization using this novel delivery approach. CPS-containing foams with high reducing potential were prepared based on the batch tests. Sediment reduction by foam-delivered CPS was observed in the column studies. Significant mobilization of Cr(VI) from sediments occurred when CPS was delivered in aqueous solution. The Cr(VI) mobilization was minimized when CPS was delivered by foams, resulting in

  3. Collapse mechanisms of metal foam matrix composites under static and dynamic loading conditions

    Energy Technology Data Exchange (ETDEWEB)

    Linul, Emanoil, E-mail: emanoil.linul@upt.ro [Department of Mechanics and Strength of Materials, Politehnica University of Timisoara, 1 Mihai Viteazu Avenue, 300 222 Timisoara (Romania); Marsavina, Liviu [Department of Mechanics and Strength of Materials, Politehnica University of Timisoara, 1 Mihai Viteazu Avenue, 300 222 Timisoara (Romania); Kováčik, Jaroslav [Institute of Materials and Machine Mechanics, Slovak Academy of Sciences, Dúbravská cesta 9, 845 13 Bratislava (Slovakia)

    2017-04-06

    The collapse mechanisms of metal foam matrix composites under static and dynamic loading conditions were experimentally and analytically investigated. Closed-cell aluminium foam AlSi10 with 325±10 kg/m{sup 3} density was used as core material, while stainless-steel-mesh is the faces materials. Prior to characterizing the composite sandwich structure, the stainless steel mesh face material and closed-cell aluminium foam were characterized by tensile testing and compression testing, respectively. Experimental tests were performed on sandwich beams using both High Speed Camera and Digital Image Correlation system for strain distribution. All experimental tests were performed at room temperature with constant crosshead speed of 1.67×10{sup −4} m/s for static tests and 2 m/s impact loading speed for dynamic tests. Two main deformation behaviours of investigated metal foam matrix composites were observed following post-failure collapse: face failure and core shear. It was showed that the initiation, propagation and interaction of failure modes depend on the type of loading, constituent material properties and geometrical parameters.

  4. Centrifugation-Assisted Fog-Collecting Abilities of Metal-Foam Structures with Different Surface Wettabilities.

    Science.gov (United States)

    Ji, Keju; Zhang, Jun; Chen, Jia; Meng, Guiyun; Ding, Yafei; Dai, Zhendong

    2016-04-20

    The collection of water from fog is a simple and sustainable means of obtaining freshwater for human and animal consumption. Herein, we address the use of metal foam in fog collection and present a novel fog-collecting device fabricated from copper foam. This device, which can also be used in other liquid-gas separation applications, is a 3D extension of biologically inspired 1D and 2D materials. The network structure of the 3D material effectively increased the contact area and interaction time of the skeleton structure and fog compared to those of traditional 2D fog-collecting materials. The main aspects investigated in this study were the influences of the inertial centrifugal force generated by rotating the metal-foam samples and the use of samples with different surface wettabilities on the fog-collecting performance. Superhydrophilic and superhydrophobic samples were found to have higher collection efficiencies at low and high rotational speeds, respectively, and a maximum efficiency of 86% was achieved for superhydrophobic copper foam (20 pores per inch) rotated at 1500 rpm.

  5. Integrated simulation of continuous-scale and discrete-scale radiative transfer in metal foams

    Science.gov (United States)

    Xia, Xin-Lin; Li, Yang; Sun, Chuang; Ai, Qing; Tan, He-Ping

    2018-06-01

    A novel integrated simulation of radiative transfer in metal foams is presented. It integrates the continuous-scale simulation with the direct discrete-scale simulation in a single computational domain. It relies on the coupling of the real discrete-scale foam geometry with the equivalent continuous-scale medium through a specially defined scale-coupled zone. This zone holds continuous but nonhomogeneous volumetric radiative properties. The scale-coupled approach is compared to the traditional continuous-scale approach using volumetric radiative properties in the equivalent participating medium and to the direct discrete-scale approach employing the real 3D foam geometry obtained by computed tomography. All the analyses are based on geometrical optics. The Monte Carlo ray-tracing procedure is used for computations of the absorbed radiative fluxes and the apparent radiative behaviors of metal foams. The results obtained by the three approaches are in tenable agreement. The scale-coupled approach is fully validated in calculating the apparent radiative behaviors of metal foams composed of very absorbing to very reflective struts and that composed of very rough to very smooth struts. This new approach leads to a reduction in computational time by approximately one order of magnitude compared to the direct discrete-scale approach. Meanwhile, it can offer information on the local geometry-dependent feature and at the same time the equivalent feature in an integrated simulation. This new approach is promising to combine the advantages of the continuous-scale approach (rapid calculations) and direct discrete-scale approach (accurate prediction of local radiative quantities).

  6. Comparison of sound absorbing performances of copper foam and iron foam with the same parameters

    Science.gov (United States)

    Yang, X. C.; Shen, X. M.; Xu, P. J.; Zhang, X. N.; Bai, P. F.; Peng, K.; Yin, Q.; Wang, D.

    2018-01-01

    Sound absorbing performances of the copper foam and the iron foam with the same parameters were investigated by the AWA6128A detector according to standing wave method. Two modes were investigated, which included the pure metal foam mode and the combination mode with the settled thickness of metal foam. In order to legibly compare the sound absorbing coefficients of the two metal foams, the detected sound frequency points were divided into the low frequency range (100 Hz ~ 1000 Hz), the middle frequency range (1000 Hz ~ 3200 Hz), and the high frequency range (3500 Hz ~ 6000 Hz). Sound absorbing performances of the two metal foams in the two modes were discussed within the three frequency ranges in detail. It would be calculated that the average sound absorbing coefficients of copper foam in the pure metal foam mode were 12.6%, 22.7%, 34.6%, 43.6%, 51.1%, and 56.2% when the thickness was 5 mm, 10 mm, 15 mm, 20 mm, 25 mm, and 30 mm. meanwhile, in the combination mode, the average sound absorbing coefficients of copper foam with the thickness of 10 mm were 30.6%, 34.8%, 36.3%, and 35.8% when the cavity was 5 mm, 10 mm, 15 mm, and 20 mm. In addition, those of iron foam in the pure metal foam mode were 13.4%, 20.1%, 34.4%, 43.1%, 49.6%, and 56.1%, and in the combination mode were 25.6%, 30.5%, 34.3%, and 33.4%.

  7. Notch sensitivity of ductile metallic foams : A computational study

    NARCIS (Netherlands)

    Mangipudi, K. R.; Onck, P. R.

    2011-01-01

    The role of notches in the fracture strength of metal foams has been studied using a multiscale model based on a two-dimensional Voronoi representation of the cellular architecture. The effect of the crack length to the specimen width ratio on the net section strength of double edge notch (DEN)

  8. Oxidation limited lifetime of Ni-Base metal foams in the temperature range 700-900 C

    Energy Technology Data Exchange (ETDEWEB)

    Chyrkin, Anton; Singheiser, Lorenz; Quadakkers, Willem Joseph [Forschungszentrum Juelich GmbH, IEF-2, Juelich (Germany); Schulze, Sebastian Leif; Bleck, Wolfgang [Department of Ferrous Metallurgy, RWTH Aachen University, Aachen (Germany); Piron-Abellan, Javier [Vallourec Mannesmann Tubes, Duesseldorf (Germany)

    2010-09-15

    INCONEL 625 metal foams produced from alloy powder by the slip-reaction-foam-sinter-process are tested in respect to cyclic oxidation behavior in air in the temperature range 700-900 C. The structure of the oxide scales formed on the foam particles is characterized using optical microscopy and SEM/EDX analysis. Main emphasis is put on studying the oxidation limited lifetimes of the foams as function of temperature and foam microstructure. It is shown that mechanical disintegration during long term oxidation at the highest test temperatures is caused by a critical depletion of the Cr content in the alloy as a result of the growth of the initially formed surface chromia layer. This results in chemical breakaway due to accelerated oxide growth of voluminous Ni-rich oxide on chromium exhausted alloy particles. Lifetime modeling based on calculation of Cr-depletion in the alloy at the oxide/metal interface of each individual foam particle using the DICTRA software is in good agreement with the experimentally determined values of the time to breakaway. (Copyright copyright 2010 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  9. The Laser ablation of a metal foam: The role of electron-phonon coupling and electronic heat diffusivity

    Science.gov (United States)

    Rosandi, Yudi; Grossi, Joás; Bringa, Eduardo M.; Urbassek, Herbert M.

    2018-01-01

    The incidence of energetic laser pulses on a metal foam may lead to foam ablation. The processes occurring in the foam may differ strongly from those in a bulk metal: The absorption of laser light, energy transfer to the atomic system, heat conduction, and finally, the atomistic processes—such as melting or evaporation—may be different. In addition, novel phenomena take place, such as a reorganization of the ligament network in the foam. We study all these processes in an Au foam of average porosity 79% and an average ligament diameter of 2.5 nm, using molecular dynamics simulation. The coupling of the electronic system to the atomic system is modeled by using the electron-phonon coupling, g, and the electronic heat diffusivity, κe, as model parameters, since their actual values for foams are unknown. We show that the foam coarsens under laser irradiation. While κe governs the homogeneity of the processes, g mainly determines their time scale. The final porosity reached is independent of the value of g.

  10. Multi-scale Modelling of Fracture in Open-Cell Metal Foams

    NARCIS (Netherlands)

    Mangipudi, K. R.; Onck, P. R.; Ganghoffer, JF; Pastrone, F

    2010-01-01

    Metal foams possess attractive mechanical properties like high stiffness to weight ratio.When used to build light-weight structures they require a good combination of strength and ductility. They are ductile under compression but rather brittle in tension with a few percent of overall strain to

  11. On the Feasibility of Very-Low-Density Pure Metal Foams as Bright High-Energy X-ray Sources

    Science.gov (United States)

    Colvin, Jeffrey; Felter, Thomas

    2003-10-01

    We have used the Busquet approximation (M. Busquet, Phys. Fluids B 5(11), 4191 (1993)) to explore calculationally what the possible x-ray conversion efficiencies into the K-band would be from irradiating very-low-density pure metal foams with tens of kilojoules of 1/3-micron laser light. We will discuss the advantages of pure metal foams as bright high-energy x-ray sources, and some results of this calculational study. We will also present our ideas for how to fabricate pure metal foams with densities of a few milligrams per cubic centimeter. This work was performed under the auspices of the US Department of Energy by University of California Lawrence Livermore National Laboratory under contract No. W-7405-Eng-48.

  12. Synchrotron-based radioscopy employing spatio-temporal micro-resolution for studying fast phenomena in liquid metal foams

    International Nuclear Information System (INIS)

    Rack, A.; García-Moreno, F.; Baumbach, T.; Banhart, J.

    2009-01-01

    High-speed synchrotron-based radioscopy is applied to study a coalescence event (which lasts ∼2 ms) in situ in a liquid metal foam. Investigations of pore coalescence and individual cell wall collapse in an expanding liquid metal foam by means of X-ray radioscopy with spatio-temporal micro-resolution are reported. By using white synchrotron radiation for imaging, the rupture of a film and the subsequent merger of two neighbouring bubbles could be recorded with a time sampling rate of 40000 frames s −1 (25 µs exposure time) and a spatial sampling rate of 20 µm. The rupture time of a cell wall was found to be in the range of 300 µs. This value is in agreement with theoretical considerations which assume an inertia-dominated rupture time of cell walls in liquid metal foams

  13. Investigation of low-frequency-oscillating water flow in metal foam with 10 pores per inch

    Science.gov (United States)

    Bağcı, Ö.; Arbak, A.; De Paepe, M.; Dukhan, N.

    2018-01-01

    In this study, oscillating water flow in metal foam with open cells is investigated experimentally. The metal foam sample has a porosity of 88% and 10 pores. The water was oscillated in the test section with three frequencies between 0.116 Hz and 0.348 Hz, which are considered low for water oscillation, and three flow displacements ranging between 74.35 mm and 111.53 mm. The combinations of frequencies of displacements were studied for their impacts of dimensional and non-dimensional pressure loss quantities. To this purpose, friction factor was correlated as a function of kinetic Reynolds number. The same metal foam sample was studied by exposing it to steady-state water flow to investigate its permeability and drag coefficient in low-velocity flow regimes. The friction factor distribution for oscillating flow was found to be over that found for steady state. The outcomes of the study are important for studying heat transfer under the same flow conditions.

  14. The development of a 3D mesoscopic model of metallic foam based on an improved watershed algorithm

    Science.gov (United States)

    Zhang, Jinhua; Zhang, Yadong; Wang, Guikun; Fang, Qin

    2018-06-01

    The watershed algorithm has been used widely in the x-ray computed tomography (XCT) image segmentation. It provides a transformation defined on a grayscale image and finds the lines that separate adjacent images. However, distortion occurs in developing a mesoscopic model of metallic foam based on XCT image data. The cells are oversegmented at some events when the traditional watershed algorithm is used. The improved watershed algorithm presented in this paper can avoid oversegmentation and is composed of three steps. Firstly, it finds all of the connected cells and identifies the junctions of the corresponding cell walls. Secondly, the image segmentation is conducted to separate the adjacent cells. It generates the lost cell walls between the adjacent cells. Optimization is then performed on the segmentation image. Thirdly, this improved algorithm is validated when it is compared with the image of the metallic foam, which shows that it can avoid the image segmentation distortion. A mesoscopic model of metallic foam is thus formed based on the improved algorithm, and the mesoscopic characteristics of the metallic foam, such as cell size, volume and shape, are identified and analyzed.

  15. Pore-level determination of spectral reflection behaviors of high-porosity metal foam sheets

    Science.gov (United States)

    Li, Yang; Xia, Xin-Lin; Ai, Qing; Sun, Chuang; Tan, He-Ping

    2018-03-01

    Open cell metal foams are currently attracting attention and their radiative behaviors are of primary importance in high temperature applications. The spectral reflection behaviors of high-porosity metal foam sheets, bidirectional reflectance distribution function (BRDF) and directional-hemispherical reflectivity were numerically investigated. A set of realistic nickel foams with porosity from 0.87 to 0.97 and pore density from 10 to 40 pores per inch were tomographied to obtain their 3-D digital cell network. A Monte Carlo ray-tracing method was employed in order to compute the pore-level radiative transfer inside the network within the limit of geometrical optics. The apparent reflection behaviors and their dependency on the textural parameters and strut optical properties were comprehensively computed and analysed. The results show a backward scattering of the reflected energy at the foam sheet surface. Except in the cases of large incident angles, an energy peak is located almost along the incident direction and increases with increasing incident angles. Through an analytical relation established, the directional-hemispherical reflectivity can be related directly to the porosity of the foam sheet and to the complex refractive index of the solid phase as well as the specularity parameter which characterizes the local reflection model. The computations show that a linear decrease in normal-hemispherical reflectivity occurs with increasing porosity. The rate of this decrease is directly proportional to the strut normal reflectivity. In addition, the hemispherical reflectivity increases as a power function of the incident angle cosine.

  16. Numerical Analysis of a Paraffin/Metal Foam Composite for Thermal Storage

    Science.gov (United States)

    Di Giorgio, P.; Iasiello, M.; Viglione, A.; Mameli, M.; Filippeschi, S.; Di Marco, P.; Andreozzi, A.; Bianco, N.

    2017-01-01

    In the last decade, the use of Phase Change Materials (PCMs) as passive thermal energy storage has been widely studied both analytically and experimentally. Among the PCMs, paraffins show many advantages, such as having a high latent heat, a low vapour pressure, being chemically inert, stable and non-toxic. But, their thermal conductivity is very low with a high volume change during the melting process. An efficient way to increase their poor thermal conductivity is to couple them with open cells metallic foams. This paper deals with a theoretical analysis of paraffin melting process inside an aluminum foam. A mathematical model is developed by using the volume-averaged governing equations for the porous domain, made up by the PCM embedded into the metal foam. Non-Darcian and buoyancy effects are considered in the momentum equation, while the energy equations are modelled with the Local Thermal Non-Equilibrium (LTNE) approach. The PCM liquefaction is treated with the apparent heat capacity method and the governing equations are solved with a finite-element scheme by COMSOL Multiphysics®. A new method to calculate the coupling coefficients needed for the thermal model has been developed and the results obtained have been validated comparing them to experimental data in literature.

  17. Application of metal foam heat exchangers for a high-performance liquefied natural gas regasification system

    International Nuclear Information System (INIS)

    Kim, Dae Yeon; Sung, Tae Hong; Kim, Kyung Chun

    2016-01-01

    The intermediate fluid vaporizer has wide applications in the regasification of LNG (liquefied natural gas). The heat exchanger performance is one of the main contributors to the thermodynamic and cost effectiveness of the entire LNG regasification system. Within the paper, the authors discuss a new concept for a compact heat exchanger with a micro-cellular structure medium to minimize volume and mass and to increase thermal efficiency. Numerical calculations have been conducted to design a metal-foam filled plate heat exchanger and a shell-and-tube heat exchanger using published experimental correlations. The geometry of both heat exchangers was optimized using the conditions of thermolators in LNG regasification systems. The heat transfer and pressure drop performance was predicted to compare the heat exchangers. The results show that the metal-foam plate heat exchanger has the best performance at different channel heights and mass flow rates of fluid. In the optimized configurations, the metal-foam plate heat exchanger has a higher heat transfer rate and lower pressure drop than the shell-and-tube heat exchanger as the mass flow rate of natural gas is increased. - Highlights: • A metal foam heat exchanger is proposed for LNG regasification system. • Comparison was made with a shell and tube heat exchanger. • Heat transfer and pressure drop characteristics were estimated. • The geometry of both heat exchangers is optimized for thermolators. • It can be used as a compact and high performance thermolators.

  18. Multiscale modelling of damage and failure in two-dimensional metallic foams

    NARCIS (Netherlands)

    Mangipudi, K. R.; Onck, P. R.

    The fracture strength of metal foams depends sensitively on the properties of the constituent material as well as the cellular architecture. A change in microscopic properties carries over to the macroscopic scale through an alteration of the mesoscopic damage and fracture mechanisms. In this paper

  19. 49 CFR 178.358 - Specification 21PF fire and shock resistant, phenolic-foam insulated, metal overpack.

    Science.gov (United States)

    2010-10-01

    ... 49 Transportation 2 2010-10-01 2010-10-01 false Specification 21PF fire and shock resistant, phenolic-foam insulated, metal overpack. 178.358 Section 178.358 Transportation Other Regulations Relating... Class 7 (Radioactive) Materials § 178.358 Specification 21PF fire and shock resistant, phenolic-foam...

  20. A practical approach for solving disposal of rubber waste: Leachability of heavy metals from foamed concrete containing rubber powder waste (RPW)

    Science.gov (United States)

    Kadir, Aeslina Abdul; Hassan, Mohd Ikhmal Haqeem; Sarani, Noor Amira; Yatim, Fatin Syahirah Mohamed; Jaini, Zainorizuan Mohd

    2017-09-01

    Enormous disposal of rubber wastes has become an issue with the facts that all tires have its own life span. Inefficient disposal method of RPW from used tire can cause environmental impact as the heavy metals content in tire can easily leach out thus causing contamination to the soil and waterways. The goals of this study is to identify the heavy metals content of rubber powder waste (RPW) and to determine the potential of leachability of heavy metals from foamed concrete containing different percentages of RPW. Therefore, this study is focused on the leachability of RPW incorporated in foamed concrete. Different percentages of RPW were incorporated in foamed concrete (0%, 6%, 12% and 18%) for the investigation. Leachability tests were done by using toxicity characteristic leaching procedure (TCLP) on crushed samples of foamed concrete incorporated with RPW and were analyzed by using inductive coupled plasma mass spectrometry (ICP-MS). The results from XRF indicated that RPW is high in metals such as Zn, Cu, Ba and Co. The highest concentration of heavy metals in raw RPW is Zn with 51403 ppm which is exceeded USEPA (2010) maximum contaminant level (MCL) of Zn with only 5 ppm. After RPW had been incorporated into a foamed concrete, the results demonstrated that the Zn, Cu, Ba and Co heavy metals were less leached and complied with USEPA standard. The incorporation of RPW into foamed concrete in this study demonstrated that it could be a potential alternative raw material for concrete thus enhancing the possibility of its reuse in safe and sustainable way.

  1. Using graphitic foam as the bonding material in metal fuel pins for sodium fast reactors

    International Nuclear Information System (INIS)

    Karahan, Aydın; Kazimi, Mujid S.

    2013-01-01

    The study evaluates the possible use of graphite foam as the bonding material between U–Pu–Zr metallic fuel and steel clad for sodium fast reactor applications using FEAST-METAL fuel performance code. Furthermore, the applicability of FEAST-METAL to the advanced fuel designs is demonstrated. Replacing the sodium bond with a chemically stable foam material would eliminate fuel clad metallurgical interactions, and allow for fuel swelling under low external stress. Hence, a significant improvement is expected for the steady state and transient performance. FEAST-METAL was used to assess the thermo-mechanical behavior of the new fuel form and a reference metallic fuel pin. Nearly unity conversion ratio, 75% smear density U–15Pu–6Zr metallic fuel pin with sodium bond, and T91 cladding was selected as a reference case. It was found that operating the reference case at high clad temperatures (600–660 °C) results in (1) excessive clad wastage formation/clad thinning due to lanthanide migration and formation of brittle phases at clad inner surface, and (2) excessive clad hoop strain at the upper axial section due mainly to the occurrence of thermal creep. The combination of these two factors may lead to cladding breach. The work concludes that replacing the sodium bond with 80% porous graphite foam and reducing the fuel smear density to 70%, it is likely that the fuel clad metallurgical interaction would be eliminated while the fuel swelling is allowed without excessive fuel clad mechanical interaction. The suggested design appears as an alternative for a high performance metallic fuel design for sodium fast reactors

  2. Using graphitic foam as the bonding material in metal fuel pins for sodium fast reactors

    Energy Technology Data Exchange (ETDEWEB)

    Karahan, Aydın, E-mail: karahan@alum.mit.edu; Kazimi, Mujid S.

    2013-10-15

    The study evaluates the possible use of graphite foam as the bonding material between U–Pu–Zr metallic fuel and steel clad for sodium fast reactor applications using FEAST-METAL fuel performance code. Furthermore, the applicability of FEAST-METAL to the advanced fuel designs is demonstrated. Replacing the sodium bond with a chemically stable foam material would eliminate fuel clad metallurgical interactions, and allow for fuel swelling under low external stress. Hence, a significant improvement is expected for the steady state and transient performance. FEAST-METAL was used to assess the thermo-mechanical behavior of the new fuel form and a reference metallic fuel pin. Nearly unity conversion ratio, 75% smear density U–15Pu–6Zr metallic fuel pin with sodium bond, and T91 cladding was selected as a reference case. It was found that operating the reference case at high clad temperatures (600–660 °C) results in (1) excessive clad wastage formation/clad thinning due to lanthanide migration and formation of brittle phases at clad inner surface, and (2) excessive clad hoop strain at the upper axial section due mainly to the occurrence of thermal creep. The combination of these two factors may lead to cladding breach. The work concludes that replacing the sodium bond with 80% porous graphite foam and reducing the fuel smear density to 70%, it is likely that the fuel clad metallurgical interaction would be eliminated while the fuel swelling is allowed without excessive fuel clad mechanical interaction. The suggested design appears as an alternative for a high performance metallic fuel design for sodium fast reactors.

  3. Investigation the foam dynamics capacity of SDS in foam generator by affecting the presence of organic and inorganic contaminant

    Science.gov (United States)

    Haryanto, Bode; Siswarni, M. Z.; Sianipar, Yosef C. H.; Sinaga, Tongam M. A.; Bestari, Imam

    2017-05-01

    The effect of negative charge SDS monomer on its foam capacity with the presence of contaminants was investigated in foam generator. Generally, surfactant with higher concentration has higher foam capacity. The higher concentration will increase the number of monomer then increase the micelles in liquid phase. Increasing the number of monomer with the negative charge is a potential to increase interaction with metal ion with positive charge in solution. The presence of inorganic compound as metal ion with positive charge and organic compound (colloid) as particle of coffee impacting to generate the foam lamella with monomer is evaluated. Foam dynamic capacity of only SDS with variation of CMC, 1 x; 2 x; 3 x have the height 7.5, 8.0 and 8.3 cm respectively with the different range time were investigated. The Height of foam dynamic capacity with the presence of 20 ppm Cd2+ ion contaminant was 8.0, 8.3 and 8.4 cm at the same CMC variation of SDS. The presence of metal ion contaminant within the foam was confirmed by AAS. The black coffee particles and oil as contaminant decreased the foam capacity significantly in comparing to metal ions.

  4. Identification of strain fields in pure Al and hybrid Ni/Al metal foams using X-ray micro-tomography under loading

    International Nuclear Information System (INIS)

    Fíla, T.; Jiroušek, O.; Jung, A.; Kumpová, I.

    2016-01-01

    Hybrid foams are materials formed by a core from a standard open cell metal foam that is during the process of electrodeposition coated by a thin layer of different nanocrystalline metals. The material properties of the base metal foam are in this way modified resulting in higher plateau stress and, more importantly, by introduction of strain-rate dependence to its deformation response. In this paper, we used time-lapse X-ray micro-tomography for the mechanical characterization of Ni/Al hybrid foams (aluminium open cell foams with nickel coating layer). To fully understand the effects of the coating layer on the material's effective properties, we compared the compressive response of the base uncoated foam to the response of the material with coating thickness of 50 and 75 μm. Digital volume correlation (DVC) was applied to obtain volumetric strain fields of the deforming micro-structure up to the densification region of the deforming cellular structure. The analysis was performed as a compressive mechanical test with simultaneous observation using X-ray radiography and tomography. A custom design experimental device was used for compression of the foam specimens in several deformation states directly in the X-ray setup. Planar X-ray images were taken during the loading phases and a X-ray tomography was performed at the end of each loading phase (up to engineering strain 22%). The samples were irradiated using micro-focus reflection type X-ray tube and images were taken using a large area flat panel detector. Tomography reconstructions were used for an identification of a strain distribution in the foam using digital volumetric correlation. A comparison of the deformation response of the coated and the uncoated foam in uniaxial quasi-static compression is summarized in the paper.

  5. Experimental and numerical analysis of the drainage of aluminium foams

    International Nuclear Information System (INIS)

    Brunke, O; Hamann, A; Cox, S J; Odenbach, S

    2005-01-01

    Drainage is one of the driving forces for the temporal instability of molten metal foams. For usual aqueous foams this phenomenon is well examined and understood on both the experimental and the theoretical side. The situation is different for metallic foams. Due to their opaque nature, the observation of drainage is only possible by either measuring the density distribution of solidified samples ex situ or by x-ray or neutron radioscopy. Up to now there exists just one theoretical study describing the drainage behaviour of metallic foams incorporating the drainage equation, the temperature dependence of the viscosity and thermal transport. This paper will present results on the drainage behaviour of aluminium foams grown by a powder-metallurgical production route. For this purpose an experiment which allows the observation of drainage in cylindrical metal foam columns has been developed. Experimental density profiles after different drainage times are measured ex situ and compared to numerical results of the standard drainage equation for aqueous foams. This first comparison between the density redistribution of metallic aluminium foams and numerical solutions shows that the standard drainage equation can be used to explain the drainage behaviour of metallic foams

  6. Predicting Mechanical Properties of Metal Matrix Syntactic Foams Reinforced with Ceramic Spheres

    Science.gov (United States)

    2012-01-01

    predicting the properties of interest listed above. Kiser et al. [12] extended a metal foam model to account for ceramic reinforcement to predict the...Daoud A. J Alloys Compd. 2009; 487:618. 11. Drury WJ, Rickles SA, Sanders Jr TH, Cochran JK. In Light-Weight Alloys for Aerospace Applications, ed. Loe

  7. New Approaches to Aluminum Integral Foam Production with Casting Methods

    Directory of Open Access Journals (Sweden)

    Ahmet Güner

    2015-08-01

    Full Text Available Integral foam has been used in the production of polymer materials for a long time. Metal integral foam casting systems are obtained by transferring and adapting polymer injection technology. Metal integral foam produced by casting has a solid skin at the surface and a foam core. Producing near-net shape reduces production expenses. Insurance companies nowadays want the automotive industry to use metallic foam parts because of their higher impact energy absorption properties. In this paper, manufacturing processes of aluminum integral foam with casting methods will be discussed.

  8. The microstructural origin of strain hardening in two-dimensional open-cell metal foams

    NARCIS (Netherlands)

    Mangipudi, K. R.; van Buuren, S. W.; Onck, P. R.

    2010-01-01

    This paper aims at elucidating the microstructural origin of strain hardening in open-cell metal foams. We have developed a multiscale model that allows to study the development of plasticity at two length scales: (i) the development of plastic zones inside individual struts (microscopic scale) and

  9. Bubble and foam chemistry

    CERN Document Server

    Pugh, Robert J

    2016-01-01

    This indispensable guide will equip the reader with a thorough understanding of the field of foaming chemistry. Assuming only basic theoretical background knowledge, the book provides a straightforward introduction to the principles and properties of foams and foaming surfactants. It discusses the key ideas that underpin why foaming occurs, how it can be avoided and how different degrees of antifoaming can be achieved, and covers the latest test methods, including laboratory and industrial developed techniques. Detailing a variety of different kinds of foams, from wet detergents and food foams, to polymeric, material and metal foams, it connects theory to real-world applications and recent developments in foam research. Combining academic and industrial viewpoints, this book is the definitive stand-alone resource for researchers, students and industrialists working on foam technology, colloidal systems in the field of chemical engineering, fluid mechanics, physical chemistry, and applied physics.

  10. Foam patterns

    Science.gov (United States)

    Chaudhry, Anil R; Dzugan, Robert; Harrington, Richard M; Neece, Faurice D; Singh, Nipendra P; Westendorf, Travis

    2013-11-26

    A method of creating a foam pattern comprises mixing a polyol component and an isocyanate component to form a liquid mixture. The method further comprises placing a temporary core having a shape corresponding to a desired internal feature in a cavity of a mold and inserting the mixture into the cavity of the mold so that the mixture surrounds a portion of the temporary core. The method optionally further comprises using supporting pins made of foam to support the core in the mold cavity, with such pins becoming integral part of the pattern material simplifying subsequent processing. The method further comprises waiting for a predetermined time sufficient for a reaction from the mixture to form a foam pattern structure corresponding to the cavity of the mold, wherein the foam pattern structure encloses a portion of the temporary core and removing the temporary core from the pattern independent of chemical leaching.

  11. Behaviour of aluminum foam under fire conditions

    Directory of Open Access Journals (Sweden)

    J. Grabian

    2008-07-01

    Full Text Available Taking into account fire-protection requirements it is advantageous for aluminum foam, after melting at a temperature considerably exceeding the melting point, to have a structure of discontinuous suspension of solid inclusions to liquid metal instead of liquid consistency. Continuity of the suspension depends on the solid phase content. The boundary value of the phase determined by J. Śleziona, above which the suspension becomes discontinuous, is provided by the formula (1. Figure 1 presents the relationship graphically. Boundary values of the vs content resulting from the above relationship is too low, taking into account the data obtained from the technology of suspension composites [4]. Therefore, based on the structure assumed for the suspension shown in Figure 2 these authors proposed another way of determining the contents, the value of which is determined by the relationship (3 [5].For purposes of the experimental study presented in the paper two foams have been molten: a commercially available one, made by aluminum foaming with titanium hydride, and a foam manufactured in the Marine Materials Plant of the Maritime University of Szczecin by blowing the AlSi7 +20% SiC composite with argon. Macrophotographs of foam cross-sections are shown in Figure 3. The foams have been molten in the atmosphere of air at a temperature of 750ºC. The products of melting are presented in Figure 4. It appears that molten aluminum foam may have no liquid consistency, being unable to flow, which is a desired property from the point of view of fire-protection. The above feature of the molten foam results from the fact that it may be a discontinuous suspension of solid particles in a liquid metal. The suspended particles may be solid particles of the composite that served for making the foam or oxide membranes formed on extended metal surface of the bubbles included in the foam. The desired foam ability to form a discontinuous suspension after melting may be

  12. Cumulative effects of using pin fin heat sink and porous metal foam on thermal management of lithium-ion batteries

    International Nuclear Information System (INIS)

    Mohammadian, Shahabeddin K.; Zhang, Yuwen

    2017-01-01

    Highlights: • 3D transient thermal analysis of a pouch Li-ion cell has been carried out. • Using pin fin heat sink improves the temperature reduction at low pumping powers. • Using pin fin heat sink enhances the temperature uniformity at low air flow rates. • Porous aluminum foam insertion with pin fins improves temperature reduction. • Porous aluminum foam insertion with pin fins enhances temperature uniformity. - Abstract: Three-dimensional transient thermal analysis of an air-cooled module was carried out to investigate cumulative effects of using pin fin heat sink and porous metal foam on thermal management of a Li-ion (lithium-ion) battery pack. Five different cases were designed as Case 1: flow channel without any pin fin or porous metal foam insertion, Case 2: flow channel with aluminum pin fins, Case 3: flow channel with porous aluminum foam pin fins, Case 4: fully inserted flow channel with porous aluminum foam, and Case 5: fully inserted flow channel with porous aluminum foam and aluminum pin fins. The effects of porous aluminum insertions, pin fin types, air flow inlet temperature, and air flow inlet velocity on the temperature uniformity and maximum temperature inside the battery pack were systematically investigated. The results showed that using pin fin heat sink (Case 2) is appropriate only for low air flow velocities. In addition, the use of porous aluminum pin fins or embedding porous aluminum foam inside the air flow channel (Cases 3 and 4) are not beneficial for thermal management improvement. The combination of aluminum pin fins and porous aluminum foam insertion inside the air flow channel (Case 5) is a proper option that improves both temperature reduction and temperature uniformity inside the battery cell.

  13. The effect of pore size and porosity on thermal management performance of phase change material infiltrated microcellular metal foams

    International Nuclear Information System (INIS)

    Sundarram, Sriharsha S.; Li, Wei

    2014-01-01

    The effect of pore size and porosity on the performance of phase change material (PCM) infiltrated metal foams, especially when the pore size reduces to less than 100 μm, is investigated in this study. A three dimensional finite element model was developed to consider both the metal and PCM domains, with heat exchange between them. The pore size and porosity effects were studied along with other system variables including heat generation and dissipation of the PCM-based thermal management system. It is shown that both porosity and pore size have strong effects on the heating of PCM. At a fixed porosity, a smaller pore size results in a lower temperature at the heat source for a longer period of time. The effects of pore size and porosity were more pronounced at high heat generation and low convective cooling conditions, representing the situation of portable electronics. There is an optimal porosity for the PCM-metal foam system; however, the optimal value only occurs at high cooling conditions. The net effective thermal conductivity of a PCM-microcellular metal foam system could be doubled by reducing the pore size from 100 μm to 25 μm. - Highlights: •Pore size and porosity of phase change material-microcellular metal foam were investigated. •A smaller pore size results in a lower temperature at the heat source for a longer period of time. •The effects were more pronounced at high heating and low cooling conditions. •Net thermal conductivity doubled by reducing the pore size from 100 μm to 25 μm

  14. A general strategy for the in situ decoration of porous Mn-Co bi-metal oxides on metal mesh/foam for high performance de-NOx monolith catalysts.

    Science.gov (United States)

    Cai, Sixiang; Liu, Jie; Zha, Kaiwen; Li, Hongrui; Shi, Liyi; Zhang, Dengsong

    2017-05-04

    Owing to their advantages of strong mechanical stability, plasticity, thermal conductivity and mass transfer ability, metal foam or meshes are considered promising monolith supports for de-NO x application. In this work, we developed a facile method for the decoration of porous Mn-Co bi-metal oxides on Fe meshes. The block-like structure was derived from in situ coating, and simultaneous nucleation and growth of the Mn-Co hydroxide precursor, while the porous Mn-Co oxides were formed via the calcination process. Moreover, the decoration of the high-purity Co 2 MnO 4 spinel could lead to enhanced reducibility and adsorption behaviors, which are crucial to the catalytic process. Of note is the fact that the Fe mesh used in the synthesis procedure could be substituted by various metal supports including Ti mesh, Cu foam and Ni foam. Driven by the above motivations, metal supports decorated with Mn-Co oxides were evaluated as monolith de-NO x catalysts for the first time. Inspiringly, these catalysts demonstrate outstanding low-temperature catalytic activity, desirable stability and excellent H 2 O resistance. This work might open up a new path for the design and development of high performance de-NO x monolith catalysts.

  15. Quantifying the retention of foam formulation components to sedimentary phases to enable predictions of mobility and treatment efficacy - 59369

    International Nuclear Information System (INIS)

    Ramirez, Rosa; Jansik, Danielle; Wellman, Dawn

    2012-01-01

    Document available in abstract form only. Full text of publication follows: Deep vadose zone remediation remains the most challenging remediation problem in the DOE Complex. Foam delivery technology is being developed as a method for delivering remedial amendments within vadose zone environments for in situ contaminant stabilization. Thus far, the physical propagation of foam within subsurface media has been evaluated and quantified. However, foam propagation is a product of surfactant sorption which directly impacts foam stability. In order to predict the stability of foam during subsurface transport it is necessary to quantify the sorption of foam components as a function of concentration, competitive sorption, sediment mineralogy, and temperature. This investigation provides the results of standard static batch test quantifying these relationships. High Performance Liquid Chromatography (HPLC) was used to measure surfactant concentrations. The results of this investigation provide necessary understanding to predict foam stability during subsurface transport and determination of the remedial radius of influence. This study is part of a multiple step process for demonstrating the feasibility of foam transport to distribute amendments within in the vadose zone. (authors)

  16. Further validation of liquid metal MHD code for unstructured grid based on OpenFOAM

    Energy Technology Data Exchange (ETDEWEB)

    Feng, Jingchao; Chen, Hongli, E-mail: hlchen1@ustc.edu.cn; He, Qingyun; Ye, Minyou

    2015-11-15

    Highlights: • Specific correction scheme has been adopted to revise the calculating result for non-orthogonal meshes. • The developed MHD code based on OpenFOAM platform has been validated by benchmark cases under uniform and non-uniform magnetic field in round and rectangular ducts. • ALEX experimental results have been used to validate the MHD code based on OpenFOAM. - Abstract: In fusion liquid metal blankets, complex geometries involving contractions, expansions, bends, manifolds are very common. The characteristics of liquid metal flow in these geometries are significant. In order to extend the magnetohydrodynamic (MHD) solver developed on OpenFOAM platform to be applied in the complex geometry, the MHD solver based on unstructured meshes has been implemented. The adoption of non-orthogonal correction techniques in the solver makes it possible to process the non-orthogonal meshes in complex geometries. The present paper focused on the validation of the code under critical conditions. An analytical solution benchmark case and two experimental benchmark cases were conducted to validate the code. Benchmark case I is MHD flow in a circular pipe with arbitrary electric conductivity of the walls in a uniform magnetic field. Benchmark cases II and III are experimental cases of 3D laminar steady MHD flow under fringing magnetic field. In all these cases, the numerical results match well with the benchmark cases.

  17. Further validation of liquid metal MHD code for unstructured grid based on OpenFOAM

    International Nuclear Information System (INIS)

    Feng, Jingchao; Chen, Hongli; He, Qingyun; Ye, Minyou

    2015-01-01

    Highlights: • Specific correction scheme has been adopted to revise the calculating result for non-orthogonal meshes. • The developed MHD code based on OpenFOAM platform has been validated by benchmark cases under uniform and non-uniform magnetic field in round and rectangular ducts. • ALEX experimental results have been used to validate the MHD code based on OpenFOAM. - Abstract: In fusion liquid metal blankets, complex geometries involving contractions, expansions, bends, manifolds are very common. The characteristics of liquid metal flow in these geometries are significant. In order to extend the magnetohydrodynamic (MHD) solver developed on OpenFOAM platform to be applied in the complex geometry, the MHD solver based on unstructured meshes has been implemented. The adoption of non-orthogonal correction techniques in the solver makes it possible to process the non-orthogonal meshes in complex geometries. The present paper focused on the validation of the code under critical conditions. An analytical solution benchmark case and two experimental benchmark cases were conducted to validate the code. Benchmark case I is MHD flow in a circular pipe with arbitrary electric conductivity of the walls in a uniform magnetic field. Benchmark cases II and III are experimental cases of 3D laminar steady MHD flow under fringing magnetic field. In all these cases, the numerical results match well with the benchmark cases.

  18. Lost foam casting of aluminum alloy-SiCp composite material

    International Nuclear Information System (INIS)

    Baalasuburamaniam, R.; Cvetnic, C.; Ravindran, C.

    2002-01-01

    Metal matrix composites are a viable alternative to cast irons in automotive components with possible increase in strength-to-weight ratio. Lost foam casting of aluminum alloy matrix composite containing 20 volume percent SiC was carried out at 690, 730, and 770 o C with a view to determining the effects of cooling rate on microstructure, particle distribution, microporosity and mechanical properties. These results were compared with those for the matrix material cast under similar conditions. The results and the correlations are of particular interest as there is no published literature on lost foam casting of composite materials. (author)

  19. Development of rubidium and niobium containing plastic foams. Final report

    International Nuclear Information System (INIS)

    Botham, R.A.; McClung, C.E.; Schwendeman, J.I.

    1978-01-01

    Rubidium fluoride and niobium metal-containing foam samples (rods and sheets) were prepared using two foam sytems: (1) hydrophilic polyurethanes prepared from W.R. Grace Co.'s Hypol prepolymers and (2) polyimides prepared from Monsanto Company's Skybond polyimide resin. The first system was used only for preparation of rubidium fluoride-containing foams while the second was used for both rubidium fluoride and niobium-containing foams. The niobium metal could readily be incorporated into the polyimide foam during molding, to produce foam sheets of the required dimensions and density. The rubidium fluoride-containing polyimide foams were preferably prepared by first rendering the molded polyimide foam hydrophilic with a postcuring treatment, then absorbing the rubidium fluoride from water solution. Similarly, rubidium fluoride was absorbed into the hydrophilic polyurethanes from water solution. Since the high reactive rubidium metal could not be employed, rubidium fluoride, which is very hygroscopic, was used instead, primarily because of its high rubidium content (approximately 82 weight percent). This was important in view of the low total densities and the high weight percentage rubidium required in the foam samples. In addition, at the later request of LLL, a block of rigid Hypol hydrophilic polyurethane foam (with a density of approximately 0.04 g/cm 3 and cell sizes = or <0.2 mm) was prepared without any metal or metal compounds in it. Two shipments of foam samples, which met or closely approximated the project specifications, were submitted to LLL during the course of this project. Information on these samples is contained in Table 1. A complete description of their preparation is given in the Experimental Results and Discussion Section

  20. A simplistic analytical unit cell based model for the effective thermal conductivity of high porosity open-cell metal foams

    International Nuclear Information System (INIS)

    Yang, X H; Kuang, J J; Lu, T J; Han, F S; Kim, T

    2013-01-01

    We present a simplistic yet accurate analytical model for the effective thermal conductivity of high porosity open-cell metal foams saturated in a low conducting fluid (air). The model is derived analytically based on a realistic representative unit cell (a tetrakaidecahedron) under the assumption of one-dimensional heat conduction along highly tortuous-conducting ligaments at high porosity ranges (ε ⩾ 0.9). Good agreement with existing experimental data suggests that heat conduction along highly conducting and tortuous ligaments predominantly defines the effective thermal conductivity of open-cell metal foams with negligible conduction in parallel through the fluid phase. (paper)

  1. Comparison of shape memory polymer foam versus bare metal coil treatments in an in vivo porcine sidewall aneurysm model.

    Science.gov (United States)

    Horn, John; Hwang, Wonjun; Jessen, Staci L; Keller, Brandis K; Miller, Matthew W; Tuzun, Egemen; Hartman, Jonathan; Clubb, Fred J; Maitland, Duncan J

    2017-10-01

    The endovascular delivery of platinum alloy bare metal coils has been widely adapted to treat intracranial aneurysms. Despite the widespread clinical use of this technique, numerous suboptimal outcomes are possible. These may include chronic inflammation, low volume filling, coil compaction, and recanalization, all of which can lead to aneurysm recurrence, need for retreatment, and/or potential rupture. This study evaluates a treatment alternative in which polyurethane shape memory polymer (SMP) foam is used as an embolic aneurysm filler. The performance of this treatment method was compared to that of bare metal coils in a head-to-head in vivo study utilizing a porcine vein pouch aneurysm model. After 90 and 180 days post-treatment, gross and histological observations were used to assess aneurysm healing. At 90 days, the foam-treated aneurysms were at an advanced stage of healing compared to the coil-treated aneurysms and showed no signs of chronic inflammation. At 180 days, the foam-treated aneurysms exhibited an 89-93% reduction in cross-sectional area; whereas coiled aneurysms displayed an 18-34% area reduction. The superior healing in the foam-treated aneurysms at earlier stages suggests that SMP foam may be a viable alternative to current treatment methods. © 2016 Wiley Periodicals, Inc. J Biomed Mater Res Part B: Appl Biomater, 105B: 1892-1905, 2017. © 2016 Wiley Periodicals, Inc.

  2. Fire Behavior of Rigid Polyurethane Foam and Metal Faced Polyurethane Sandwich Panels and Its Fire Hazard Assessment

    Directory of Open Access Journals (Sweden)

    S. Bakhtiyari

    2009-12-01

    Full Text Available Reaction to fire of fire-retarded rigid PUR foams and two types of metal faced rigid polyurethane foam core sandwich panel was evaluated by using cone calorimeter test method. The tests were carried out in various radiative heat fluxes from 15 to 75 kW/m2. The radiation rate effect on reaction to fire parameters, including time to ignition (TTI, peak of heat release rate (PRHR, total heat release (THR, average heat release rate (Av.RHR and average heat of combustion (Av.EHC was investigated. The phenomenon of char forming, when the foam is exposed to heat, leads to the formation of a protective layer on the surface of foam and hence no direct relation exists between Av.RHR and average specific mass loss rate (Av.Spec.MLR of foam with increased radiation rate. In addition, the increased PRHR with foam density was also very smooth. The relation between TTI and heat flux was investigated for the foam and its corresponding correlation has been achieved with a specified density. Fire hazard assessment of foams and sandwitch panels was carried out by adopting Petrella and Richardson fire risk classification methods. The assessment results showed that rigid PUR foam and PUR sandwich panels may have a high contribution to bring the room to critical flashover condition, but the risk is intermediate from the viewpoint of fire endurance. The reasons of these risk levels are attributed to a very short TTI, relative high PRHR and an intermediate amount of THR. Decrease in foam density reduces heat release but it shows no significant effect on reducing flashover hazard.

  3. Study of the use of metallic foam in a vehicle for an energy-economy racing circuit

    Energy Technology Data Exchange (ETDEWEB)

    Cardoso, E.; Oliveira, B.F. [Federal University of Rio Grande do Sul - UFRGS, Porto Alegre (Brazil)

    2010-05-15

    The emphasis of this work is on the use of metal foams in automotive design for weight reduction with the purpose of studying the mechanical behaviour and possible project alternatives, through the modelling and subsequent computer simulation according to the case study - chassis of the ''Sabia 5''. The ''Sabias'' are hyper-economic vehicles created to compete in an energy-economy racing circuit (Shell Eco-marathon). For the structural analysis, the finite element software Abaqus/CAE is used. The tests performed are static and dynamic tests simulating the vehicle passing across a rough track and crash test. According to the results of the computational tests, metal foams demonstrated to be a good choice for the studied application, presenting the necessary weight reduction with the expected structural performance. (Abstract Copyright [2010], Wiley Periodicals, Inc.)

  4. Effect of Cerium(IV)-Surfactant Reaction in Foam Decontamination

    Energy Technology Data Exchange (ETDEWEB)

    Yang, Han Beom; Jung, Chong-Hun; Yoon, In-Ho; Kim, Chorong; Choi, Wang-Kyu [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2015-05-15

    Using foams allows the decommissioning of complex shaped facilities. The decontamination foam comprises at least one surfactant to generate the foam and one or more chemical reactants to achieve the dissolution of the contaminants at the solid surface. In order to improve the efficiency of decontamination foam, the present study attempts to find the optimum condition of chemical reagents to the foaming solution. The corrosion rate of radioactive nuclides contaminated stainless steel metal is very important factor for the foam decontamination process. The goal of this study is to develop the decontamination process for contaminated stainless steel in medium of nitric acid. Stainless steel needs a strong oxidizing agent such as Ce(IV) ion and the effects of cerium(IV). Surfactant interaction involved in foam decontamination and finally the improvement brought by formulation science. The formulation of foams loaded with strong oxidizing reagents such as Ce(IV) is an important factor. The enhanced decontamination properties of nitric acid with Ce(IV) additive on stainless steel is well known in liquid mediums. stainless steel metal is an important aspect in the foam decontamination process.

  5. Effect of Cerium(IV)-Surfactant Reaction in Foam Decontamination

    International Nuclear Information System (INIS)

    Yang, Han Beom; Jung, Chong-Hun; Yoon, In-Ho; Kim, Chorong; Choi, Wang-Kyu

    2015-01-01

    Using foams allows the decommissioning of complex shaped facilities. The decontamination foam comprises at least one surfactant to generate the foam and one or more chemical reactants to achieve the dissolution of the contaminants at the solid surface. In order to improve the efficiency of decontamination foam, the present study attempts to find the optimum condition of chemical reagents to the foaming solution. The corrosion rate of radioactive nuclides contaminated stainless steel metal is very important factor for the foam decontamination process. The goal of this study is to develop the decontamination process for contaminated stainless steel in medium of nitric acid. Stainless steel needs a strong oxidizing agent such as Ce(IV) ion and the effects of cerium(IV). Surfactant interaction involved in foam decontamination and finally the improvement brought by formulation science. The formulation of foams loaded with strong oxidizing reagents such as Ce(IV) is an important factor. The enhanced decontamination properties of nitric acid with Ce(IV) additive on stainless steel is well known in liquid mediums. stainless steel metal is an important aspect in the foam decontamination process

  6. Advanced nondestructive techniques applied for the detection of discontinuities in aluminum foams

    Science.gov (United States)

    Katchadjian, Pablo; García, Alejandro; Brizuela, Jose; Camacho, Jorge; Chiné, Bruno; Mussi, Valerio; Britto, Ivan

    2018-04-01

    Metal foams are finding an increasing range of applications by their lightweight structure and physical, chemical and mechanical properties. Foams can be used to fill closed moulds for manufacturing structural foam parts of complex shape [1]; foam filled structures are expected to provide good mechanical properties and energy absorption capabilities. The complexity of the foaming process and the number of parameters to simultaneously control, demand a preliminary and hugely wide experimental activity to manufacture foamed components with a good quality. That is why there are many efforts to improve the structure of foams, in order to obtain a product with good properties. The problem is that even for seemingly identical foaming conditions, the effective foaming can vary significantly from one foaming trial to another. The variation of the foams often is related by structural imperfections, joining region (foam-foam or foam-wall mold) or difficulties in achieving a complete filling of the mould. That is, in a closed mold, the result of the mold filling and its structure or defects are not known a priori and can eventually vary significantly. These defects can cause a drastic deterioration of the mechanical properties [2] and lead to a low performance in its application. This work proposes the use of advanced nondestructive techniques for evaluating the foam distribution after filling the mold to improve the manufacturing process. To achieved this purpose ultrasonic technique (UT) and cone beam computed tomography (CT) were applied on plate and structures of different thicknesses filled with foam of different porosity. UT was carried out on transmission mode with low frequency air-coupled transducers [3], in focused and unfocused configurations.

  7. Mechanical Characterization of Rigid Polyurethane Foams

    Energy Technology Data Exchange (ETDEWEB)

    Lu, Wei-Yang [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States). Mechanics of Materials

    2014-12-01

    Foam materials are used to protect sensitive components from impact loading. In order to predict and simulate the foam performance under various loading conditions, a validated foam model is needed and the mechanical properties of foams need to be characterized. Uniaxial compression and tension tests were conducted for different densities of foams under various temperatures and loading rates. Crush stress, tensile strength, and elastic modulus were obtained. A newly developed confined compression experiment provided data for investigating the foam flow direction. A biaxial tension experiment was also developed to explore the damage surface of a rigid polyurethane foam.

  8. Mechanical Properties of Electrolyte Jet Electrodeposited Nickel Foam

    Directory of Open Access Journals (Sweden)

    Jinsong Chen

    2013-07-01

    Full Text Available Principles of the preparation of nickel foam by electrolyte jet electrodeposition were introduced, Nickel foam samples with different porosity were fabricated. Effect of different porosity on microhardness and uniaxial tensile properties of nickel foam was discussed. The results show that the microhardness of nickel foam is 320~400 HV, lower than entitative metal clearly. The lower the porosity of nickel foam, the higher the microhardness is. During the process of uniaxial tensile, nickel foam is characterized by three distinct regions, e.g. elastic deforming region, plastic plateau region and densification region. The higher the porosity of nickel foam, the lower the plastic plateau and the poorer the strength of nickel foam, accordingly

  9. Tooling Foam for Structural Composite Applications

    Science.gov (United States)

    DeLay, Tom; Smith, Brett H.; Ely, Kevin; MacArthur, Doug

    1998-01-01

    Tooling technology applications for composite structures fabrication have been expanded at MSFC's Productivity Enhancement Complex (PEC). Engineers from NASA/MSFC and Lockheed Martin Corporation have developed a tooling foam for use in composite materials processing and manufacturing that exhibits superior thermal and mechanical properties in comparison with other tooling foam materials. This tooling foam is also compatible with most preimpregnated composite resins such as epoxy, bismaleimide, phenolic and their associated cure cycles. MARCORE tooling foam has excellent processability for applications requiring either integral or removable tooling. It can also be tailored to meet the requirements for composite processing of parts with unlimited cross sectional area. A shelf life of at least six months is easily maintained when components are stored between 50F - 70F. The MARCORE tooling foam system is a two component urethane-modified polyisocyanurate, high density rigid foam with zero ozone depletion potential. This readily machineable, lightweight tooling foam is ideal for composite structures fabrication and is dimensionally stable at temperatures up to 350F and pressures of 100 psi.

  10. Reduced material model for closed cell metal foam infiltrated with phase change material based on high resolution numerical studies

    International Nuclear Information System (INIS)

    Ohsenbrügge, Christoph; Marth, Wieland; Navarro y de Sosa, Iñaki; Drossel, Welf-Guntram; Voigt, Axel

    2016-01-01

    Highlights: • Closed cell metal foam sandwich structures were investigated. • High resolution numerical studies were conducted using CT scan data. • A reduced model for use in commercial FE software reduces needed degrees of freedom. • Thermal inertia is increased about 4 to 5 times in PCM filled structures. • The reduced material model was verified using experimental data. - Abstract: The thermal behaviour of closed cell metal foam infiltrated with paraffin wax as latent heat storage for application in high precision tool machines was examined. Aluminium foam sandwiches with metallically bound cover layers were prepared in a powder metallurgical process and cross-sectional images of the structures were generated with X-ray computed tomography. Based on the image data a three dimensional highly detailed model was derived and prepared for simulation with the adaptive FE-library AMDiS. The pores were assumed to be filled with paraffin wax. The thermal conductivity and the transient thermal behaviour in the phase-change region were investigated. Based on the results from the highly detailed simulations a reduced model for use in commercial FE-software (ANSYS) was derived. It incorporates the properties of the matrix and the phase change material into a homogenized material. A sandwich-structure with and without paraffin was investigated experimentally under constant thermal load. The results were used to verify the reduced material model in ANSYS.

  11. Defect generation during solidification of aluminium foams

    International Nuclear Information System (INIS)

    Mukherjee, M.; Garcia-Moreno, F.; Banhart, J.

    2010-01-01

    The reason for the frequent occurrence of cell wall defects in metal foams was investigated. Aluminium foams often expand during solidification, a process which is referred as solidification expansion (SE). The effect of SE on the structure of aluminium foams was studied in situ by X-ray radioscopy and ex situ by X-ray tomography. A direct correlation between the magnitude of SE and the number of cell wall ruptures during SE and finally the number of defects in the solidified foams was found.

  12. Compressive Behaviour and Energy Absorption of Aluminium Foam Sandwich

    Science.gov (United States)

    Endut, N. A.; Hazza, M. H. F. Al; Sidek, A. A.; Adesta, E. T. Y.; Ibrahim, N. A.

    2018-01-01

    Development of materials in automotive industries plays an important role in order to retain the safety, performance and cost. Metal foams are one of the idea to evolve new material in automotive industries since it can absorb energy when it deformed and good for crash management. Recently, new technology had been introduced to replace metallic foam by using aluminium foam sandwich (AFS) due to lightweight and high energy absorption behaviour. Therefore, this paper provides reliable data that can be used to analyze the energy absorption behaviour of aluminium foam sandwich by conducting experimental work which is compression test. Six experiments of the compression test were carried out to analyze the stress-strain relationship in terms of energy absorption behavior. The effects of input variables include varying the thickness of aluminium foam core and aluminium sheets on energy absorption behavior were evaluated comprehensively. Stress-strain relationship curves was used for energy absorption of aluminium foam sandwich calculation. The result highlights that the energy absorption of aluminium foam sandwich increases from 12.74 J to 64.42 J respectively with increasing the foam and skin thickness.

  13. The separation of silica nanoparticle by cetyltrimethylammonium bromide from decontamination foam waste

    International Nuclear Information System (INIS)

    Choi, Man Soo; Yoon, In Ho; Jung, Chong Hun; Moon, Jei Kwon; Choi, Wang Kyu

    2016-01-01

    Decontamination foam has been considered as a potential application for the cleaning of radioactive contaminant in the field of metallic walls, overhead surfaces, and complex components. Moreover, foam decontamination could generate the low secondary waste amount owing to its volume expansion. In order to increase the decontamination efficiency, it is essential to improve the foam stability with low amount of chemical decontamination agent. Yoon et al. reported that the silica nanoparticle containing surfactant increased the foam stability compared to only surfactant solution[3]. Nanoparticle has been used with surfactant, which they adsorb at fluid/fluid interface, to stabilize emulsions or bubbles in foams. Despite of improving foam stability, they still used the surfactant, silica nanoparticle (1 wt%), and viscosifier. In addition, it is difficult to separate silica nanoparticle from decontamination solution. Because nanoparticles differ from classical solid particles due to smaller particle size and their specific properties. Thus, the separation method for nanoparticle should be also developed with high recovery rates. The flocculation of silica nanoparticle added by CTAB could be quickly achieved for only 30 min. The particle size of SiO_2 was larger as CTAB amount increased, and SiO_2 contents in the top solution were decreased after centrifugation

  14. The separation of silica nanoparticle by cetyltrimethylammonium bromide from decontamination foam waste

    Energy Technology Data Exchange (ETDEWEB)

    Choi, Man Soo; Yoon, In Ho; Jung, Chong Hun; Moon, Jei Kwon; Choi, Wang Kyu [KAERI, Daejeon (Korea, Republic of)

    2016-05-15

    Decontamination foam has been considered as a potential application for the cleaning of radioactive contaminant in the field of metallic walls, overhead surfaces, and complex components. Moreover, foam decontamination could generate the low secondary waste amount owing to its volume expansion. In order to increase the decontamination efficiency, it is essential to improve the foam stability with low amount of chemical decontamination agent. Yoon et al. reported that the silica nanoparticle containing surfactant increased the foam stability compared to only surfactant solution[3]. Nanoparticle has been used with surfactant, which they adsorb at fluid/fluid interface, to stabilize emulsions or bubbles in foams. Despite of improving foam stability, they still used the surfactant, silica nanoparticle (1 wt%), and viscosifier. In addition, it is difficult to separate silica nanoparticle from decontamination solution. Because nanoparticles differ from classical solid particles due to smaller particle size and their specific properties. Thus, the separation method for nanoparticle should be also developed with high recovery rates. The flocculation of silica nanoparticle added by CTAB could be quickly achieved for only 30 min. The particle size of SiO{sub 2} was larger as CTAB amount increased, and SiO{sub 2} contents in the top solution were decreased after centrifugation.

  15. 21PF overpacks: Phenolic-foam induced corrosion

    International Nuclear Information System (INIS)

    Kovac, F.M.

    1994-01-01

    The 21PF overpack was developed in the 1960s and approved for use in the 1970s by the US Department of Transportation (DOT). This package, used for the transport of uranium hexafluoride enriched >1%, has had a history of severe metal corrosion, water ingress, and subsequent leakage. Problems associated with corrosion and water leaking from 21PF overpacks caused the DOT to seek public comments and to undertake rulemaking action. As a result, the DOT required modifications and refurbishment of existing overpacks, and specification changes for the fabrication of new 21PF overpacks. Recent studies conducted by the roofing industry indicate that phenolic foam has caused severe corrosion in metal roofing structures, and its use is being curtailed. These findings need to be explored in order to determine if phenolic foam in 21PF overpacks causes corrosion and compromises the package integrity. Metallic corrosion induced by phenolic foam may affect the continued use of the 21PF overpack because damage to the structural integrity of the metal parts of the packaging will affect its ability to meet design specifications

  16. Optimization of Design and Manufacturing Process of Metal Foam Filled Anti-Intrusion Bars

    International Nuclear Information System (INIS)

    Villa, Andrea; Mussi, Valerio; Strano, Matteo

    2011-01-01

    The role of an anti-intrusion bar for automotive use is to absorb the kinetic energy of the colliding bodies that is partially converted into internal work of the bodies involved in the crash. The aim of this paper is to investigate the performances of a new kind of anti-intrusion bars for automotive use, filled with metallic foams. The reason for using a cellular material as a filler deals with its capacity to absorb energy during plastic deformation, while being lightweight. The study is the evolution of a previous paper presented by the authors at Esaform 2010 and will present new results and findings. It is conducted by evaluating some key technical issues of the manufacturing problem and by conducting experimental and numerical analyses. The evaluation of materials and shapes of the closed sections to be filled is made in the perspective of a car manufacturer (production costs, weight reduction, space availability in a car door, etc.). Experimentally, foams are produced starting from an industrial aluminium precursor with a TiH 2 blowing agent. Bars are tested in three point bending, in order to evaluate their performances in terms of force-displacement response and other specific performance parameters. In order to understand the role of interface between the inner surface of the tube and the external surface of the foam, different kinds of interface are tested.

  17. The Response of Clamped Shallow Sandwich Arches with Metallic Foam Cores to Projectile Impact Loading

    Directory of Open Access Journals (Sweden)

    Yanping Fan

    Full Text Available Abstract The dynamic response and energy absorption capabilities of clamped shallow sandwich arches with aluminum foam core were numerically investigated by impacting the arches at mid-span with metallic foam projectiles. The typical deformation modes, deflection response, and core compression of sandwich arches obtained from the tests were used to validate the computation model. The resistance to impact loading was quantified by the permanent transverse deflection at mid-span of the arches as a function of projectile momentum. The sandwich arches have a higher shock resistance than the monolithic arches of equal mass, and shock resistance could be significantly enhanced by optimizing geometrical configurations. Meanwhile, decreasing the face-sheet thickness and curvature radius could enhance the energy absorption capability of the sandwich arches. Finite element calculations indicated that the ratio of loading time to structural response time ranged from 0.1 to 0.4. The projectile momentum, which was solely used to quantify the structural response of sandwich arches, was insufficient. These findings could provide guidance in conducting further theoretical studies and producing the optimal design of metallic sandwich structures subjected to impact loading.

  18. Incorporation of the Pore Size Variation to Modeling of the Elastic Behavior of Metallic Open-Cell Foams

    Directory of Open Access Journals (Sweden)

    Ćwieka K.

    2017-03-01

    Full Text Available In the present paper we present the approach for modeling of the elastic behavior of open-cell metallic foams concerning non-uniform pore size distribution. This approach combines design of foam structures and numerical simulations of compression tests using finite element method (FEM. In the design stage, Laguerre-Voronoi tessellations (LVT were performed on several sets of packed spheres with defined variation of radii, bringing about a set of foam structures with porosity ranging from 74 to 98% and different pore size variation quantified by the coefficient of pore volume variation, CV(V, from 0.5 to 2.1. Each structure was numerically subjected to uni-axial compression test along three directions within the elastic region. Basing on the numerical response, the effective Young’s modulus, Eeff, was calculated for each structure. It is shown that the Eeff is not only dependent on the porosity but also on the pore size variation.

  19. Metal foam - a material for heat engineering. Porous structures increase the efficiency of heat exchangers and cooling elements; Metallschaum - ein Werkstoff fuer die Waermetechnik. Offenporige Strukturen steigern die Effizienz von Waermeuebertragern und Kuehlelementen

    Energy Technology Data Exchange (ETDEWEB)

    Meyer, Franz

    2016-11-01

    Metal foams are increasingly developing into materials with diverse uses. While metal foams with closed pores have already become established as rigid and strong lightweight materials, the open-cell variant is suitable for thermal engineering applications. Until now, the material has been rarely used in heat exchangers or coolers because the production is expensive and its application little tested. Researchers at the Fraunhofer Institute for Manufacturing Technology and Advanced Materials IFAM in Dresden now want to change this. Together with industry partners, they are further developing the production method, are characterising different metal foams and are testing them in practice.

  20. FOAM3D: A numerical simulator for mechanistic prediciton of foam displacement in multidimensions

    Energy Technology Data Exchange (ETDEWEB)

    Kovscek, A.R.; Patzek, T.W. [Lawrence Berkeley Laboratory, Berkeley, CA (United States); Radke, C.J. [Univ. of California, Berkeley, CA (United States)

    1995-03-01

    Field application of foam is a technically viable enhanced oil recovery process (EOR) as demonstrated by recent steam-foam field studies. Traditional gas-displacement processes, such as steam drive, are improved substantially by controlling gas mobility and thereby improving volumetric displacement efficiency. For instance, Patzek and Koinis showed major oil-recovery response after about two years of foam injection in two different pilot studies at the Kern River field. They report increased production of 5.5 to 14% of the original oil in place over a five year period. Because reservoir-scale simulation is a vital component of the engineering and economic evaluation of any EOR project, efficient application of foam as a displacement fluid requires a predictive numerical model of foam displacement. A mechanistic model would also expedite scale-up of the process from the laboratory to the field scale. No general, mechanistic, field-scale model for foam displacement is currently in use.

  1. Scaling of compression strength in disordered solids: metallic foams

    Directory of Open Access Journals (Sweden)

    J. Kováčik

    2016-03-01

    Full Text Available The scaling of compression strength with porosity for aluminium foams was investigated. The Al 99.96, AlMg1Si0.6 and AlSi11Mg0.6 foams of various porosity, sample size with and without surface skin were tested in compression. It was observed that the compression strength of aluminium foams scales near the percolation threshold with Tf ≈ 1.9 - 2.0 almost independently on the matrix alloy, sample size and presence of surface skin. The difference of the obtained values of Tf to the theoretical estimate of Tf = 2.64 ± 0.3 by Arbabi and Sahimi and to Ashby estimate of 1.5 was explained using an analogy with the Daoud and Coniglio approach to the scaling of the free energy of sol-gel transition. It leads to the finding that, there are two different universality classes for the critical exponent Tf: when the stretching forces dominate Tf = f = 2.1, respectively when bending forces prevail Tf = .d = 2.64 seems to be valid. Another possibility is the validity of relation Tf ≤ f which varies only according to the universality class of modulus of elasticity in foam.

  2. INFLUENCE OF THE CEMENT TYPE ON THE CHARACTERISTICS OF THE MINERAL FOAM APPLICABLE IN FOAMED CERAMIC TECHNOLOGIES

    Directory of Open Access Journals (Sweden)

    Korolev Evgeniy Valer'evich

    2012-10-01

    Full Text Available The subject of the research is the influence of the type of Portland cement, as well as the nature and concentration of additives that represent electrolytes and polymers, onto the foam stability. The project is implemented within the framework of the research of foamed ceramic. Detailed explanation of the influence pattern is provided. The research performed by the authors has generated the following findings. Besides the rheological properties of the solution, chemical interaction between the mix components must be taken into account in the course of development of the best foamed ceramic mix composition, as chemical processes produce a substantial influence onto the foam stability. Polymer additives based on liquid carbamyde-formaldehyde and polyacrylamide substantially improve the quality of the foam mineralized by the particles of the cement binder. They also assure the foam stability rate sufficient for the formation of a high-quality foamed material.

  3. Advanced slab polyurethane foam with feather touch; Soft feather urethane foam no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    Yamada, Y; Ono, H [Toyota Motor Corp., Aichi (Japan); Mori, A; Yamaguchi, N; Nakamura, T [Bridgestone Corp., Tokyo (Japan)

    1997-10-01

    Automotive seat plays an important part, which are not only retention of sitting position, but also comfort and high-class feeling. Wadding, which is a part of the seat, is a key component for the sitting comfortableness. This paper is concerned with advanced slab polyurethane foam with feather touch feeling. The compounding of formation, foaming process and reliability of mass production is studied. 2 refs., 10 figs., 3 tabs.

  4. New powder compaction method using a styrene foam

    International Nuclear Information System (INIS)

    Kinemuchi, Y.; Takata, A.; Ishizaki, K.

    1999-01-01

    In general, metallic and ceramic powder compacts for sintering are shaped by uni-axial pressing or cold isostatic pressing (CIPing). Since metal or rubber is used as dies or moulds, it is difficult to form complicated shapes and flat disks, i.e., the ratio of diameter / thickness more than 50, by using uni-axial or CIPing. Rubber moulding, a moulding method with a rubber bag, can not press powder uniformly into flat disks because rubber deforms significantly. To solve this problem, we developed a new shaping technique to obtain complicated or thin flat shape by using styrene foam, which is cheap and has good machinability. Plastic foams such as styrene and acrylic foam contain many pores, and shrink uniformly by applying external pressure when the pores are collapsed. In this study, shrinking behavior of styrene and acrylic rubber moulds related to CIPing pressure was investigated. The experimental results show that the plastic foams shrink uniformly and the plastic deformation is linearly increased as CIP pressure increases. Copyright (1999) AD-TECH - International Foundation for the Advancement of Technology Ltd

  5. Structure and Compressive Properties of Invar-Cenosphere Syntactic Foams

    Directory of Open Access Journals (Sweden)

    Dung Luong

    2016-02-01

    Full Text Available The present study investigates the mechanical performance of syntactic foams produced by means of the metal powder injection molding process having an Invar (FeNi36 matrix and including cenospheres as hollow particles at weight fractions (wt.% of 5 and 10, respectively, corresponding to approximately 41.6 and 60.0 vol.% in relation to the metal content and at 0.6 g/cm3 hollow particle density. The synthesis process results in survival of cenospheres and provides low density syntactic foams. The microstructure of the materials is investigated as well as the mechanical performance under quasi-static and high strain rate compressive loads. The compressive stress-strain curves of syntactic foams reveal a continuous strain hardening behavior in the plastic region, followed by a densification region. The results reveal a strain rate sensitivity in cenosphere-based Invar matrix syntactic foams. Differences in properties between cenosphere- and glass microsphere-based materials are discussed in relation to the findings of microstructural investigations. Cenospheres present a viable choice as filler material in iron-based syntactic foams due to their higher thermal stability compared to glass microspheres.

  6. High-energy redox-flow batteries with hybrid metal foam electrodes.

    Science.gov (United States)

    Park, Min-Sik; Lee, Nam-Jin; Lee, Seung-Wook; Kim, Ki Jae; Oh, Duk-Jin; Kim, Young-Jun

    2014-07-09

    A nonaqueous redox-flow battery employing [Co(bpy)3](+/2+) and [Fe(bpy)3](2+/3+) redox couples is proposed for use in large-scale energy-storage applications. We successfully demonstrate a redox-flow battery with a practical operating voltage of over 2.1 V and an energy efficiency of 85% through a rational cell design. By utilizing carbon-coated Ni-FeCrAl and Cu metal foam electrodes, the electrochemical reactivity and stability of the nonaqueous redox-flow battery can be considerably enhanced. Our approach intoduces a more efficient conversion of chemical energy into electrical energy and enhances long-term cell durability. The cell exhibits an outstanding cyclic performance of more than 300 cycles without any significant loss of energy efficiency. Considering the increasing demands for efficient energy storage, our achievement provides insight into a possible development pathway for nonaqueous redox-flow batteries with high energy densities.

  7. Assessment of foam fracture in sandwich beams using thermoelastic stress analysis

    DEFF Research Database (Denmark)

    Dulieu-Barton, J.M.; Berggreen, Christian; Mettemberg, C.

    2009-01-01

    Thermoelastic Stress Analysis (TSA) has been well established for determining crack-tip parameters in metallic materials. This paper examines its ability to determine accurately the crack-tip parameters for PVC foam used in sandwich structures.......Thermoelastic Stress Analysis (TSA) has been well established for determining crack-tip parameters in metallic materials. This paper examines its ability to determine accurately the crack-tip parameters for PVC foam used in sandwich structures....

  8. Experiments, modeling and simulation of the magnetic behavior of inhomogeneously coated nickel/aluminum hybrid foams

    Energy Technology Data Exchange (ETDEWEB)

    Jung, A., E-mail: anne.jung@mx.uni-saarland.de [Universität des Saarlandes, Institute of Applied Mechanics, Campus A4 2, 66123 Saarbrücken (Germany); Klis, D., E-mail: d.klis@lte.uni-saarland.de [Universität des Saarlandes, Laboratory for Electromagnetic Theory, Campus C6 3, 66123 Saarbrücken (Germany); Goldschmidt, F., E-mail: f.goldschmidt@mx.uni-saarland.de [Universität des Saarlandes, Institute of Applied Mechanics, Campus A4 2, 66123 Saarbrücken (Germany)

    2015-03-15

    Open-cell metal foams are used as lightweight construction elements, energy absorbers or as support for catalytic coatings. Coating of open-cell metal foams is not only used for catalytic applications, but it leads also to tremendous increase in stiffness and energy absorption capacity. A non-line of sight coating technique for complex 3D structures is electrodeposition. Unfortunately, due to the 3D porosity and the related problems in mass transport limitation during the deposition, it is not possible to produce homogeneously coated foams. In the present contribution, we present a semi-non-destructive technique applicable to determine the coating thickness distribution of magnetic coatings by measuring the remanent magnetic field of coated foams. In order to have a closer look at the mass transport mechanism, a numerical model was developed to predict the field scans for different coating thickness distributions in the foams. For long deposition times the deposition reaches a steady state whereas a Helmholtz equation is sufficient to predict the coating thickness distribution. The applied current density could be identified as the main influencing parameter. Based on the developed model, it is possible to improve the electrodeposition process and hence the homogeneity in the coating thickness of coated metal foams. This leads to enhanced mechanical properties of the hybrid foams and contributes to better and resource-efficient energy absorbers and lightweight materials. - Highlights: • Production of hybrid foams by electrodeposition of nickel on open-cell metal foams. • Magnetic field scans for visualization of spatial coating thickness distribution. • Modeling of magnetic fields of inhomogeneously coated hybrid foams. • Investigation of mass transport limitation during coating by a Helmholtz equation. • Increasing coating homogeneity by use of low current densities and deposition rates.

  9. Experimental and Numerical Study of Ceramic Foam Filtration

    Science.gov (United States)

    Laé, E.; Duval, H.; Rivière, C.; Le Brun, P.; Guillot, J.-B.

    Ceramic foam filtration is widely used to enable removal of non metallic inclusions from liquid aluminium. Its performances have been largely studied in the literature and some discrepancies remain amongst the published results. Consequently, a research program was deployed to evaluate the performances of a range of ceramic foam filters used under various conditions and to understand the inclusions capture mechanisms.

  10. Functional Performances of CuZnAl Shape Memory Alloy Open-Cell Foams

    Science.gov (United States)

    Biffi, C. A.; Casati, R.; Bassani, P.; Tuissi, A.

    2018-01-01

    Shape memory alloys (SMAs) with cellular structure offer a unique mixture of thermo-physical-mechanical properties. These characteristics can be tuned by changing the pore size and make the shape memory metallic foams very attractive for developing new devices for structural and functional applications. In this work, CuZnAl SMA foams were produced through the liquid infiltration of space holder method. In comparison, a conventional CuZn brass alloy was foamed trough the same method. Functional performances were studied on both bulk and foamed SMA specimens. Calorimetric response shows similar martensitic transformation (MT) below 0 °C. Compressive response of CuZnAl revealed that mechanical behavior is strongly affected by sample morphology and that damping capacity of metallic foam is increased above the MT temperatures. The shape memory effect was detected in the CuZnAl foams. The conventional brass shows a compressive response similar to that of the martensitic CuZnAl, in which plastic deformation accumulation occurs up to the cellular structure densification after few thermal cycles.

  11. The viscosity window of the silicate glass foam production

    DEFF Research Database (Denmark)

    Petersen, Rasmus Rosenlund; König, Jakob; Yue, Yuanzheng

    2017-01-01

    which can offer a practical starting point for the optimisation procedure. The melt viscosity might be the most important parameter for controlling the foaming process and the glass foam density. In this work, we attempt to define a viscosity range in which foaming of different glasses results...... in a maximum of foam expansion. The expansion maximum is obtained for different glasses (labware, E-glass, CRT panel, soda-lime-silica) by foaming with CaCO3 at isokom temperature and from literature data. In general, the viscosity window was found to be within 104–106 Pa s when foaming with MnO2 or metal...... carbonates (CaCO3, Na2CO3, MgCO3, SrCO3, dolomite) whereas SiC requires higher temperatures and correspondingly lower viscosities (103.3–104.0 Pa s). These findings can help assessing the implementation of new resources in the glass foam production....

  12. Acoustic absorption behaviour of an open-celled aluminium foam

    CERN Document Server

    Han Fu Sheng; Zhao Yu Yuan; Gibbs, B

    2003-01-01

    Metal foams, especially close-celled foams, are generally regarded as poor sound absorbers. This paper studies the sound absorption behaviour of the open-celled Al foams manufactured by the infiltration process, and the mechanisms involved. The foams show a significant improvement in sound absorption compared with close-celled Al foams, because of their high flow resistance. The absorption performance can be further enhanced, especially at low frequencies, if the foam panel is backed by an appropriate air gap. Increasing the air-gap depth usually increases both the height and the width of the absorption peak and shifts the peak towards lower frequencies. The foam samples with the smallest pore size exhibit the best absorption capacities when there is no air gap, whereas those with medium pore sizes have the best overall performance when there is an air gap. The typical maximum absorption coefficient, noise reduction coefficient and half-width of the absorption peak are 0.96-0.99, 0.44-0.62 and 1500-3500 Hz, r...

  13. Development of partially biodegradable foams from PP/HMSPP blends with natural and synthetic polymers

    International Nuclear Information System (INIS)

    Cardoso, Elizabeth Carvalho Leite

    2014-01-01

    Polymers are used in various application and in different industrial areas providing enormous quantities of wastes in environment. Among diverse components of residues in landfills are polymeric materials, including Polypropylene, which contribute with 20 to 30% of total volume of solid residues. As polymeric materials are immune to microbial degradation, they remain in soil and in landfills as a semi-permanent residue. Environmental concerning in litter reduction is being directed to renewable polymers development for manufacturing of polymeric foams. Foamed polymers are considered future materials, with a wide range of applications; high density structural foams are specially used in civil construction, in replacement of metal, woods and concrete with a final purpose of reducing materials costs. At present development, it was possible the incorporation of PP/HMSPP polymeric matrix blends with sugarcane bagasse, PHB and PLA, in structural foams production. Thermal degradation at 100, 120 and 160 deg C temperatures was not enough to induce biodegradability. Gamma irradiation degradation, at 50, 100, 200 and 500 kGy showed effective for biodegradability induction. Irradiated bagasse blends suffered surface erosion, in favor of water uptake and consequently, a higher biodegradation in bulk structure. (author)

  14. A study on fracture characteristic of aluminum foam by thickness

    Energy Technology Data Exchange (ETDEWEB)

    Gao, Teng [Dept. of Mechanical Engineering, Graduate School, Kongju National University, Kongju (Korea, Republic of); Cho, Jae Ung [Div. of Mechanical and Automotive Engineering, Kongju National University, Kongju (Korea, Republic of)

    2015-10-15

    Because foam metal has the excellent physical characteristics and mechanical performance, they are applied extensively into a lot of advanced technology areas. The aluminum foam with closed cell is one of the foam metals. It is applied widely into automobile and airplane because of the excellent absorption performance of impact energy. In this study, the mechanical characteristics by thickness was analyzed through the impact experiment of closed-cell aluminum foam, and the simulation analysis was performed for the verification. As the simulation analysis method, a finite-element analysis was carried under the same boundary conditions as the experiment by using ANSYS. By comparing with the results of experiment and simulation, it was thought that the case of thickness of 20 mm was the most efficient of among the cases of thicknesses of 10 mm, 20 mm and 30 mm. At the case of thickness of 20 mm, the absorption energy by comparing with the specimen thickness is shown to become the most among three models. By using the result of this study, it is thought that it can apply the material necessary to develop the mechanical structure with aluminum foam.

  15. Coated foams, preparation, uses and articles

    Science.gov (United States)

    Duchane, D.V.; Barthell, B.L.

    1982-10-21

    Hydrophobic cellular material is coated with a thin hydrophilic polymer skin which stretches tightly over the foam but which does not fill the cells of the foam, thus resulting in a polymer-coated foam structure having a smoothness which was not possible in the prior art. In particular, when the hydrophobic cellular material is a specially chosen hydrophobic polymer foam and is formed into arbitrarily chosen shapes prior to the coating with hydrophilic polymer, inertial confinement fusion (ICF) targets of arbitrary shapes can be produced by subsequently coating the shapes with metal or with any other suitable material. New articles of manufacture are produced, including improved ICF targets, improved integrated circuits, and improved solar reflectors and solar collectors. In the coating method, the cell size of the hydrophobic cellular material, the viscosity of the polymer solution used to coat, and the surface tension of the polymer solution used to coat are all very important to the coating.

  16. RELATIONSHIP BETWEEN FOAMING BEHAVIOR AND SURFACE ENERGY OF ASPHALT BINDER

    Directory of Open Access Journals (Sweden)

    Jian-ping Xu

    2017-12-01

    Full Text Available To solve the problem of insufficiency in microscopic performance of foamed asphalt binder, surface energy theory was utilized to analyze the foaming behavior and wettability of asphalt binder. Based on the surface energy theory, the Wilhelmy plate method and universal sorption device method were employed to measure the surface energy components of asphalt binders and aggregates, respectively. Combined with the traditional evaluation indictor for foamed asphalt, the relationship between the foaming property and surface energy of asphalt binder was analyzed. According to the surface energy components, the wettability of asphalt binder to aggregate was calculated to verify the performance of foamed asphalt mixture. Results indicate that the foaming behavior of asphalt will be influenced by surface energy, which will increase with the decline of surface energy. In addition, the surface energy of asphalt binder significantly influences the wettability of asphalt binder to aggregates. Meanwhile, there is an inversely proportional relationship between surface energy of asphalt binder and wettability. Therefore, it can be demonstrated that surface energy is a good indictor which can be used to evaluate the foaming behavior of the asphalt binder. And it is suggested to choose the asphalt binder with lower surface energy in the process of design of foamed asphalt mixture.

  17. Application of Auxetic Foam in Sports Helmets

    Directory of Open Access Journals (Sweden)

    Leon Foster

    2018-03-01

    Full Text Available This investigation explored the viability of using open cell polyurethane auxetic foams to augment the conformable layer in a sports helmet and improve its linear impact acceleration attenuation. Foam types were compared by examining the impact severity on an instrumented anthropomorphic headform within a helmet consisting of three layers: a rigid shell, a stiff closed cell foam, and an open cell foam as a conformable layer. Auxetic and conventional foams were interchanged to act as the helmet’s conformable component. Attenuation of linear acceleration was examined by dropping the combined helmet and headform on the front and the side. The helmet with auxetic foam reduced peak linear accelerations (p < 0.05 relative to its conventional counterpart at the highest impact energy in both orientations. Gadd Severity Index reduced by 11% for frontal impacts (38.9 J and 44% for side impacts (24.3 J. The conformable layer within a helmet can influence the overall impact attenuating properties. The helmet fitted with auxetic foam can attenuate impact severity more than when fitted with conventional foam, and warrants further investigation for its potential to reduce the risk of traumatic brain injuries in sport specific impacts.

  18. Handling and final storage of radioactive metal components

    International Nuclear Information System (INIS)

    Loennerberg, B.; Engelbrektson, A.; Neretnieks, I.

    1978-06-01

    After the dismounting of the fuel elements, the next stage is to undertake the final storing of the metal components, which have kept the fuel rods together. The components are transmitted to a pool where they are cut into pieces, compacted and placed in wire baskets. These are transferred in a water channel to a cell, where the metal components are embedded into concrete blocks. Thus the baskets are placed in prefabricated concrete containers, after which the metal parts are embedded into cement grout, injected from the bottom of the containers. The blocks are finally stored in rock tunnels constituting a storage similar to the repositories for vitrified waste and spent fuel, although somewhat simplified, taking advantage of the much lower amount of radioactive material in the case of metal components. Thus a depositioning depth of 300 m in rock is very much on the safe side and it is appropriate in this case to fill the tunnels with concrete, ensuring by its alcalinity a suffi ciently low rate of dissolution of the metal and migration of radioactive substances

  19. Multiple-Nozzle Spray Head Applies Foam Insulation

    Science.gov (United States)

    Walls, Joe T.

    1993-01-01

    Spray head equipped with four-nozzle turret mixes two reactive components of polyurethane and polyisocyanurate foam insulating material and sprays reacting mixture onto surface to be insulated. If nozzle in use becomes clogged, fresh one automatically rotated into position, with minimal interruption of spraying process. Incorporates features recirculating and controlling pressures of reactive components to maintain quality of foam by ensuring proper blend at outset. Also used to spray protective coats on or in ships, aircraft, and pipelines. Sprays such reactive adhesives as epoxy/polyurethane mixtures. Components of spray contain solid-particle fillers for strength, fire retardance, toughness, resistance to abrasion, or radar absorption.

  20. Intertwined nanocarbon and manganese oxide hybrid foam for high-energy supercapacitors.

    Science.gov (United States)

    Wang, Wei; Guo, Shirui; Bozhilov, Krassimir N; Yan, Dong; Ozkan, Mihrimah; Ozkan, Cengiz S

    2013-11-11

    Rapid charging and discharging supercapacitors are promising alternative energy storage systems for applications such as portable electronics and electric vehicles. Integration of pseudocapacitive metal oxides with single-structured materials has received a lot of attention recently due to their superior electrochemical performance. In order to realize high energy-density supercapacitors, a simple and scalable method is developed to fabricate a graphene/MWNT/MnO2 nanowire (GMM) hybrid nanostructured foam, via a two-step process. The 3D few-layer graphene/MWNT (GM) architecture is grown on foamed metal foils (nickel foam) via ambient pressure chemical vapor deposition. Hydrothermally synthesized α-MnO2 nanowires are conformally coated onto the GM foam by a simple bath deposition. The as-prepared hierarchical GMM foam yields a monographical graphene foam conformally covered with an intertwined, densely packed CNT/MnO2 nanowire nanocomposite network. Symmetrical electrochemical capacitors (ECs) based on GMM foam electrodes show an extended operational voltage window of 1.6 V in aqueous electrolyte. A superior energy density of 391.7 Wh kg(-1) is obtained for the supercapacitor based on the GMM foam, which is much higher than ECs based on GM foam only (39.72 Wh kg(-1) ). A high specific capacitance (1108.79 F g(-1) ) and power density (799.84 kW kg(-1) ) are also achieved. Moreover, the great capacitance retention (97.94%) after 13 000 charge-discharge cycles and high current handability demonstrate the high stability of the electrodes of the supercapacitor. These excellent performances enable the innovative 3D hierarchical GMM foam to serve as EC electrodes, resulting in energy-storage devices with high stability and power density in neutral aqueous electrolyte. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  1. Preparation and characterization of shape memory composite foams with interpenetrating polymer networks

    International Nuclear Information System (INIS)

    Yao, Yongtao; Zhou, Tianyang; Yang, Cheng; Leng, Jinsong; Liu, Yanju

    2016-01-01

    The present study reports a feasible approach of fabricating shape memory composite foams with an interpenetrating polymer network (IPN) based on polyurethane (PU) and shape memory epoxy resin (SMER) via a simultaneous polymerization technique. The PU component is capable of constructing a foam structure and the SMER is grafted on the PU network to offer its shape memory property in the final IPN foams. A series of IPN foams without phase separation were produced due to good compatibility and a tight chemical interaction between PU and SMER components. The relationships of the geometry of the foam cell were investigated via varying compositions of PU and SMER. The physical property and shape memory property were also evaluated. The stimulus temperature of IPN shape memory composite foams, glass temperature (T g ), could be tunable by varying the constituents and T g of PU and SMER. The mechanism of the shape memory effect of IPN foams has been proposed. The shape memory composite foam with IPN developed in this study has the potential to extend its application field. (paper)

  2. Low density, microcellular, dopable, agar/gelatin foams for pulsed power experiments

    Energy Technology Data Exchange (ETDEWEB)

    McNamara, W.F. [Orion International Technologies, Inc., Albuquerque, NM (United States); Aubert, J.H. [Sandia National Lab., Albuquerque, NM (United States)

    1997-04-01

    Low-density, microcellular foams prepared from the natural polymers agar and gelatin have been developed for pulsed-power physics experiments. Numerous experiments were supported with foams having densities at or below 10 mg/cm{sup 3}. For some of the experiments, the agar/gelatin foam was uniformly doped with metallic elements using soluble salts. Depending on the method of preparation, cell sizes were typically below 10 microns and for one process were below 1.0 micron.

  3. Foam, Foam-resin composite and method of making a foam-resin composite

    Science.gov (United States)

    Cranston, John A. (Inventor); MacArthur, Doug E. (Inventor)

    1995-01-01

    This invention relates to a foam, a foam-resin composite and a method of making foam-resin composites. The foam set forth in this invention comprises a urethane modified polyisocyanurate derived from an aromatic amino polyol and a polyether polyol. In addition to the polyisocyanurate foam, the composite of this invention further contains a resin layer, wherein the resin may be epoxy, bismaleimide, or phenolic resin. Such resins generally require cure or post-cure temperatures of at least 350.degree. F.

  4. Defining and comparing vibration attributes of AlSi10 foam and CFRP coated AlSi10 foam materials

    Science.gov (United States)

    Çolak, O.; Yünlü, L.

    2017-06-01

    Now, Aluminum materials have begun being manufactured as porous structures and being used with additive composite materials through emerging manufacturing technologies. These materials those porous structures have also begun being used in many areas such as automotive and aerospace due to light-weighted structures. In addition to examining mechanical behavior of porous metallic structures, examining vibration behavior is important for defining characteristic specifications. In this study, vibration attributes belong to %80 porous AlSi10 foam and CFRP coated %80 porous AlSi10 foam are determined with modal analysis. Modal parameters such as natural frequencies and damping coefficient from frequency response functions at the end of hammer impact tests. It is found that natural frequency of CFRP coated AlSi10 foam’s is 1,14 times bigger than AlSi10 foam and damping coefficient of CFRP coated AlSi10 foam is 5 times bigger than AlSi10 foam’s with tests. Dynamic response of materials in various conditions is simulated by evaluating modal parameters with FEM. According to results of the study, CFRP coating on AlSi10 foam effect vibration damping and resonance avoidance ability positively.

  5. mdFoam+: Advanced molecular dynamics in OpenFOAM

    Science.gov (United States)

    Longshaw, S. M.; Borg, M. K.; Ramisetti, S. B.; Zhang, J.; Lockerby, D. A.; Emerson, D. R.; Reese, J. M.

    2018-03-01

    This paper introduces mdFoam+, which is an MPI parallelised molecular dynamics (MD) solver implemented entirely within the OpenFOAM software framework. It is open-source and released under the same GNU General Public License (GPL) as OpenFOAM. The source code is released as a publicly open software repository that includes detailed documentation and tutorial cases. Since mdFoam+ is designed entirely within the OpenFOAM C++ object-oriented framework, it inherits a number of key features. The code is designed for extensibility and flexibility, so it is aimed first and foremost as an MD research tool, in which new models and test cases can be developed and tested rapidly. Implementing mdFoam+ in OpenFOAM also enables easier development of hybrid methods that couple MD with continuum-based solvers. Setting up MD cases follows the standard OpenFOAM format, as mdFoam+ also relies upon the OpenFOAM dictionary-based directory structure. This ensures that useful pre- and post-processing capabilities provided by OpenFOAM remain available even though the fully Lagrangian nature of an MD simulation is not typical of most OpenFOAM applications. Results show that mdFoam+ compares well to another well-known MD code (e.g. LAMMPS) in terms of benchmark problems, although it also has additional functionality that does not exist in other open-source MD codes.

  6. Optimized Synthesis of Foam Glass from Recycled CRT Panel Glass

    DEFF Research Database (Denmark)

    Petersen, Rasmus Rosenlund; König, Jakob; Yue, Yuanzheng

    Most of the panel glass from cathode ray tubes (CRTs) is landfilled today. Instead of landfilling, the panel glass can be turned into new environment-friendly foam glass. Low density foam glass is an effective heat insulating material and can be produced just by using recycle glass and foaming...... additives. In this work we recycle the CRT panel glass to synthesize the foam glass as a crucial component of building and insulating materials. The synthesis conditions such as foaming temperature, duration, glass particle size, type and concentrations of foaming agents, and so on are optimized...... by performing systematic experiments. In particular, the concentration of foaming agents is an important parameter that influences the size of bubbles and the distribution of bubbles throughout the sample. The foam glasses are characterised regarding density and open/closed porosity. Differential scanning...

  7. Acoustic absorption behaviour of an open-celled aluminium foam

    International Nuclear Information System (INIS)

    Han Fusheng; Seiffert, Gary; Zhao Yuyuan; Gibbs, Barry

    2003-01-01

    Metal foams, especially close-celled foams, are generally regarded as poor sound absorbers. This paper studies the sound absorption behaviour of the open-celled Al foams manufactured by the infiltration process, and the mechanisms involved. The foams show a significant improvement in sound absorption compared with close-celled Al foams, because of their high flow resistance. The absorption performance can be further enhanced, especially at low frequencies, if the foam panel is backed by an appropriate air gap. Increasing the air-gap depth usually increases both the height and the width of the absorption peak and shifts the peak towards lower frequencies. The foam samples with the smallest pore size exhibit the best absorption capacities when there is no air gap, whereas those with medium pore sizes have the best overall performance when there is an air gap. The typical maximum absorption coefficient, noise reduction coefficient and half-width of the absorption peak are 0.96-0.99, 0.44-0.62 and 1500-3500 Hz, respectively. The sound dissipation mechanisms in the open-celled foams are principally viscous and thermal losses when there is no air-gap backing and predominantly Helmholtz resonant absorption when there is an air-gap backing

  8. Polymer-Derived Silicoboron Carbonitride Foams for CO2 Capture: From Design to Application as Scaffolds for the in Situ Growth of Metal-Organic Frameworks.

    Science.gov (United States)

    Sandra, Fabien; Depardieu, Martin; Mouline, Zineb; Vignoles, Gérard L; Iwamoto, Yuji; Miele, Philippe; Backov, Rénal; Bernard, Samuel

    2016-06-06

    A template-assisted polymer-derived ceramic route is investigated for preparing a series of silicoboron carbonitride (Si/B/C/N) foams with a hierarchical pore size distribution and tailorable interconnected porosity. A boron-modified polycarbosilazane was selected to impregnate monolithic silica and carbonaceous templates and form after pyrolysis and template removal Si/B/C/N foams. By changing the hard template nature and controlling the quantity of polymer to be impregnated, controlled micropore/macropore distributions with mesoscopic cell windows are generated. Specific surface areas from 29 to 239 m(2)  g(-1) and porosities from 51 to 77 % are achieved. These foams combine a low density with a thermal insulation and a relatively good thermostructural stability. Their particular structure allowed the in situ growth of metal-organic frameworks (MOFs) directly within the open-cell structure. MOFs offered a microporosity feature to the resulting Si/B/C/N@MOF composite foams that allowed increasing the specific surface area to provide CO2 uptake of 2.2 %. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  9. Assessment of the vibration on the foam legged and sheet metal-legged passenger seat

    Directory of Open Access Journals (Sweden)

    L. Dahil

    2015-10-01

    Full Text Available In this study, it was aim ed to decrease the vibration reaching to passenger from the legs of vehicle seats. In order to determine the levels of vibrations reaching at passengers, a test pad placed under the passenger seat was used, and HVM100 device was used for digitizing the information obtained. By transferring the vibration data to system by using HVM100 device, the acceleration graphics were prepared with Blaze software. As a result, it was determined that the acceleration values of seat legs made of foam material were lower than that of seat legs made of 2 mm thick sheet metal, so they damped the vibration better.

  10. Notch-strengthening in two-dimensional foams

    NARCIS (Netherlands)

    Onck, P.R.

    Metallic foams show notch-strengthening behavior when analyzing double-edge notched specimen in compression and tension. A discrete microstructural model has been used to simulate the effect of notch depth and specimen size on the net-section-strength. The non-uniform deformation behavior is

  11. Influence of foaming agents on both the structure and the thermal conductivity of silicate glasses

    DEFF Research Database (Denmark)

    Østergaard, Martin Bonderup; Petersen, Rasmus Rosenlund; König, Jakob

    Foam glass is one of the most promising insulation materials for constructions since it has low thermal conductivity, high compressive strength, non-water permeability, and high fire resistance. They can be produced using cullet sources, e.g., cathode ray tubes (CRT) panel glass, and foaming agents...... such as metal carbonates, or oxidizing transition metal oxides combined with carbonaceous sources. In this work, we mix CRT panel glass powder with different foaming agents: CaCO3 (0-4 wt%), Fe2O3 (0-6 wt%), and MnxOy (0-10 wt%). The powder mixtures are sintered in the range between the glass transition...

  12. Energy-Saving Melting and Revert Reduction Technology (E-SMARRT): Lost Foam Thin Wall - Feasibility of Producing Lost Foam Castings in Aluminum and Magnesium Based Alloys

    Energy Technology Data Exchange (ETDEWEB)

    Fasoyinu, Yemi [CanmetMATERIALS; Griffin, John A. [University of Alabama - Birmingham

    2014-03-31

    With the increased emphasis on vehicle weight reduction, production of near-net shape components by lost foam casting will make significant inroad into the next-generation of engineering component designs. The lost foam casting process is a cost effective method for producing complex castings using an expandable polystyrene pattern and un-bonded sand. The use of un-bonded molding media in the lost foam process will impose less constraint on the solidifying casting, making hot tearing less prevalent. This is especially true in Al-Mg and Al-Cu alloy systems that are prone to hot tearing when poured in rigid molds partially due to their long freezing range. Some of the unique advantages of using the lost foam casting process are closer dimensional tolerance, higher casting yield, and the elimination of sand cores and binders. Most of the aluminum alloys poured using the lost foam process are based on the Al-Si system. Very limited research work has been performed with Al-Mg and Al-Cu type alloys. With the increased emphasis on vehicle weight reduction, and given the high-strength-to-weight-ratio of magnesium, significant weight savings can be achieved by casting thin-wall (≤ 3 mm) engineering components from both aluminum- and magnesium-base alloys.

  13. Foam Transport in Porous Media - A Review

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Z. F.; Freedman, Vicky L.; Zhong, Lirong

    2009-11-11

    Amendment solutions with or without surfactants have been used to remove contaminants from soil. However, it has drawbacks such that the amendment solution often mobilizes the plume, and its movement is controlled by gravity and preferential flow paths. Foam is an emulsion-like, two-phase system in which gas cells are dispersed in a liquid and separated by thin liquid films called lamellae. Potential advantages of using foams in sub-surface remediation include providing better control on the volume of fluids injected, uniformity of contact, and the ability to contain the migration of contaminant laden liquids. It is expected that foam can serve as a carrier of amendments for vadose zone remediation, e.g., at the Hanford Site. As part of the U.S. Department of Energy’s EM-20 program, a numerical simulation capability will be added to the Subsurface Transport Over Multiple Phases (STOMP) flow simulator. The primary purpose of this document is to review the modeling approaches of foam transport in porous media. However, as an aid to understanding the simulation approaches, some experiments under unsaturated conditions and the processes of foam transport are also reviewed. Foam may be formed when the surfactant concentration is above the critical micelle concentration. There are two main types of foams – the ball foam (microfoam) and the polyhedral foam. The characteristics of bulk foam are described by the properties such as foam quality, texture, stability, density, surface tension, disjoining pressure, etc. Foam has been used to flush contaminants such as metals, organics, and nonaqueous phase liquids from unsaturated soil. Ball foam, or colloidal gas aphrons, reportedly have been used for soil flushing in contaminated site remediation and was found to be more efficient than surfactant solutions on the basis of weight of contaminant removed per gram of surfactant. Experiments also indicate that the polyhedral foam can be used to enhance soil remediation. The

  14. TIG welding of aluminium foams. Analysis of foaming operating parameters; Soldadura TIG de espumas de aluminio. Analisis de los parametros operacionales de espumado

    Energy Technology Data Exchange (ETDEWEB)

    Portoles, A.; Berenguer, O.; Onoro, J.; Ranninger, C.

    2011-07-01

    In this work the influence of main parameters that take part during TIG welding process are analyzed. Some of these parameters belong to the welding process, as for example the welding speed, intensity and voltage while others are from the material and tooling features, as for example foaming material and tooling design. The result of this work shows a strong dependence on these parameters of the TIG welding process for metallic foams. (Author) 16 refs.

  15. FOAM CONCRETE REINFORCEMENT BY BASALT FIBRES

    Directory of Open Access Journals (Sweden)

    Zhukov Aleksey Dmitrievich

    2012-10-01

    Full Text Available The authors demonstrate that the foam concrete performance can be improved by dispersed reinforcement, including methods that involve basalt fibres. They address the results of the foam concrete modeling technology and assess the importance of technology-related parameters. Reinforcement efficiency criteria are also provided in the article. Dispersed reinforcement improves the plasticity of the concrete mix and reduces the settlement crack formation rate. Conventional reinforcement that involves metal laths and rods demonstrates its limited application in the production of concrete used for thermal insulation and structural purposes. Dispersed reinforcement is preferable. This technology contemplates the infusion of fibres into porous mixes. Metal, polymeric, basalt and glass fibres are used as reinforcing components. It has been identified that products reinforced by polypropylene fibres demonstrate substantial abradability and deformability rates even under the influence of minor tensile stresses due to the low adhesion strength of polypropylene in the cement matrix. The objective of the research was to develop the type of polypropylene of D500 grade that would demonstrate the operating properties similar to those of Hebel and Ytong polypropylenes. Dispersed reinforcement was performed by the basalt fibre. This project contemplates an autoclave-free technology to optimize the consumption of electricity. Dispersed reinforcement is aimed at the reduction of the block settlement in the course of hardening at early stages of their operation, the improvement of their strength and other operating properties. Reduction in the humidity rate of the mix is based on the plasticizing properties of fibres, as well as the application of the dry mineralization method. Selection of optimal parameters of the process-related technology was performed with the help of G-BAT-2011 Software, developed at Moscow State University of Civil Engineering. The authors also

  16. Nano-Aramid Fiber Reinforced Polyurethane Foam

    Science.gov (United States)

    Semmes, Edmund B.; Frances, Arnold

    2008-01-01

    Closed cell polyurethane and, particularly, polyisocyanurate foams are a large family of flexible and rigid products the result of a reactive two part process wherein a urethane based polyol is combined with a foaming or "blowing" agent to create a cellular solid at room temperature. The ratio of reactive components, the constituency of the base materials, temperature, humidity, molding, pouring, spraying and many other processing techniques vary greatly. However, there is no known process for incorporating reinforcing fibers small enough to be integrally dispersed within the cell walls resulting in superior final products. The key differentiating aspect from the current state of art resides in the many processing technologies to be fully developed from the novel concept of milled nano pulp aramid fibers and their enabling entanglement capability fully enclosed within the cell walls of these closed cell urethane foams. The authors present the results of research and development of reinforced foam processing, equipment development, strength characteristics and the evolution of its many applications.

  17. System Description for the K-25/K-27 D and D Project Polyurethane Foam Delivery System, East Tennessee Technology Park, Oak Ridge, Tennessee

    International Nuclear Information System (INIS)

    Boris, G.

    2008-01-01

    The Foam Delivery System used in the decontamination and decommissioning (D and D) project for the K-25/K-27 Buildings at the East Tennessee Technology Park (ETTP) is comprised of a trailer-mounted Gusmer(reg s ign) H20/35 Pro-TEC Proportioning Unit and the associated equipment to convey electrical power, air, and foam component material to the unit. This high-pressure, plural-component polyurethane foam pouring system will be used to fill process gas and non-process equipment/piping (PGE/P) within the K-25/K-27 Buildings with polyurethane foam to immobilize contaminants prior to removal. The system creates foam by mixing isocyanate and polyol resin (Resin) component materials. Currently, the project plans to utilize up to six foaming units simultaneously during peak foaming activities. Also included in this system description are the foam component material storage containers that will be used for storage of the component material drums in a staging area outside of the K-25/K-27 Buildings. The Foam Delivery System and foam component material storage enclosures (i.e., Foaming Component Protective Enclosures) used to store polymeric methylene diphenyl diisocyanate (PMDI) component material are identified as Safety Significant (SS) Structures, Systems and Components (SSC) in the Documented Safety Analysis (DSA) for the project, Documented Safety Analysis for the K-25 and K-27 Facilities at the East Tennessee Technology Park, Oak Ridge, Tennessee, DSA-ET-K-25/K-27-0001

  18. Effect of Sphere Properties on Microstructure and Mechanical Performance of Cast Composite Metal Foams

    Directory of Open Access Journals (Sweden)

    Matias Garcia-Avila

    2015-05-01

    Full Text Available Aluminum-steel composite metal foams (Al-S CMF are manufactured using steel hollow spheres, with a variety of sphere carbon content, surface roughness, and wall porosity, embedded in an Aluminum matrix through gravity casting technique. The microstructural and mechanical properties of the material were studied using scanning electron microscopy, energy dispersive spectroscopy, and quasi-static compressive testing. Higher carbon content and surface roughness in the sphere wall were responsible for an increase in formation of intermetallic phases which had a strengthening effect at lower strain levels, increasing the yield strength of the material by a factor of 2, while higher sphere wall porosity resulted in a decrease on the density of the material and improving its cushioning and ductility maintaining its energy absorption capabilities.

  19. Properties of Syntactic Foam for Simulation of Mechanical Insults.

    Energy Technology Data Exchange (ETDEWEB)

    Hubbard, Neal Benson [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Haulenbeek, Kimberly K. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Spletzer, Matthew A. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Ortiz, Lyndsy [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2017-02-01

    Syntactic foam encapsulation protects sensitive components. The energy mitigated by the foam is calculated with numerical simulations. The properties of a syntactic foam consisting of a mixture of an epoxy-rubber adduct and glass microballoons are obtained from published literature and test results. The conditions and outcomes of the tests are discussed. The method for converting published properties and test results to input for finite element models is described. Simulations of the test conditions are performed to validate the inputs.

  20. Development of a Hopkinson Bar Apparatus for Testing Soft Materials: Application to a Closed-Cell Aluminum Foam

    Directory of Open Access Journals (Sweden)

    Marco Peroni

    2016-01-01

    Full Text Available An increasing interest in lightweight metallic foams for automotive, aerospace, and other applications has been observed in recent years. This is mainly due to the weight reduction that can be achieved using foams and for their mechanical energy absorption and acoustic damping capabilities. An accurate knowledge of the mechanical behavior of these materials, especially under dynamic loadings, is thus necessary. Unfortunately, metal foams and in general “soft” materials exhibit a series of peculiarities that make difficult the adoption of standard testing techniques for their high strain-rate characterization. This paper presents an innovative apparatus, where high strain-rate tests of metal foams or other soft materials can be performed by exploiting the operating principle of the Hopkinson bar methods. Using the pre-stress method to generate directly a long compression pulse (compared with traditional SHPB, a displacement of about 20 mm can be applied to the specimen with a single propagating wave, suitable for evaluating the whole stress-strain curve of medium-sized cell foams (pores of about 1–2 mm. The potential of this testing rig is shown in the characterization of a closed-cell aluminum foam, where all the above features are amply demonstrated.

  1. Synthesis and characterization of Ti–Ta–Nb–Mn foams

    Energy Technology Data Exchange (ETDEWEB)

    Aguilar, C., E-mail: claudio.aguilar@usm.cl [Departamento de Ingeniería Metalúrgica y Materiales, Universidad Técnica Federico Santa María, Av. España 1680, Valparaíso (Chile); Guerra, C. [Departamento de Ingeniería Metalúrgica y Materiales, Universidad Técnica Federico Santa María, Av. España 1680, Valparaíso (Chile); Lascano, S. [Departamento de Ingeniería Mecánica, Universidad Técnica Federico Santa María, Av. España 1680, Valparaíso (Chile); Guzman, D. [Departamento de Metalurgia, Universidad de Atacama, Av. Copayapu 485, Copiapó (Chile); Rojas, P.A. [Escuela de Ingeniería Mecánica, Facultad de Ingeniería, Pontificia Universidad Católica de Valparaíso, Av. Los Carrera, 01567 Quilpué (Chile); Thirumurugan, M. [Departamento de Ingeniería Metalúrgica y Materiales, Universidad Técnica Federico Santa María, Av. España 1680, Valparaíso (Chile); Bejar, L.; Medina, A. [Universidad Michoacana de San Nicolás de Hidalgo, Ciudad Universitaria, Morelia, Michoacán (Mexico)

    2016-01-01

    The unprecedented increase in human life expectancy have produced profound changes in the prevailing patterns of disease, like the observed increased in degenerative disc diseases, which cause degradation of the bones. Ti–Nb–Ta alloys are promising materials to replace the damaged bone due to their excellent mechanical and corrosion resistance properties. In general metallic foams are widely used for medical application due to their lower elastic moduli compare to bulk materials. In this work we studied the synthesis of 34Nb–29Ta–xMn (x: 2, 4 and 6 wt.% Mn) alloy foams (50% v/v) using ammonium hydrogen carbonate as a space holder. Alloys were produced through mechanical alloying in a planetary mill for 50 h. Green compacts were obtained by applying 430 MPa pressure. To remove the space holder from the matrix the green compacts were heated to 180 °C for 1.5 h and after sintered at 1300 °C for 3 h. Foams were characterized by x-ray diffraction, scanning, transmission electron microscopy and optical microscopy. The elastic modulus of the foam was measured as ~ 30 GPa, and the values are almost equal to the values predicted using various theoretical models. - Highlights: • Metallic foams of Ti–34Nb–29Ta–xMn (x: 2, 4 and 6 wt.% Mn) alloys were synthetized. • The macro and micro pore produced have sizes smaller than 600 and 20 μm, respectively. • The macro and micro pores shows good characteristics to cell adhesion and bone ingrowth. • Elastic properties were comparable to that exhibited by cortical bone.

  2. Design of an experiment for the production of a foamed tin sample

    Science.gov (United States)

    Wernimont, E.

    1986-01-01

    One of the major experiments in the GAS container is concerned with the experimental production of a foamed metal. A foamed metal is one that contains a significant amount of gas bubbles suspended in its solid volume. Purdue's GAS team proposes to do this with the help of a solid zinc carbonate that gives off carbon dioxide at high temperatures. Because of low energy requirements, the metal used for this experiment is tin. It is hoped that the use of near zero environment will keep the suspended bubbles more uniform than in an Earth based process, hence not depleting the physical strength of the material as greatly as is observed on Earth.

  3. Optimization of foam-filled bitubal structures for crashworthiness criteria

    International Nuclear Information System (INIS)

    Zhang, Yong; Sun, Guangyong; Li, Guangyao; Luo, Zhen; Li, Qing

    2012-01-01

    Highlights: ► The paper aims to optimize foam-filled bitubal squared column for crashworthiness. ► It explores different formulations and configurations of design. ► The optimal foam-filled bitubal column is better than foam-filled monotubal column. ► The optimal foam-filled bitubal column is better than empty bitubal column. -- Abstract: Thin-walled structures have been widely used as key components in automobile and aerospace industry to improve the crashworthiness and safety of vehicles while maintaining overall light-weight. This paper aims to explore the design issue of thin-walled bitubal column structures filled with aluminum foam. As a relatively new filler material, aluminum foam can increase crashworthiness without sacrificing too much weight. To optimize crashworthiness of the foam-filled bitubal square column, the Kriging meta-modeling technique is adopted herein to formulate the objective and constraint functions. The genetic algorithm (GA) and Non-dominated Sorting Genetic Algorithm II (NSGA II) are used to seek the optimal solutions to the single and multiobjective optimization problems, respectively. To compare with other thin-walled configurations, the design optimization is also conducted for empty bitubal column and foam-filled monotubal column. The results demonstrate that the foam-filled bitubal configuration has more room to enhance the crashworthiness and can be an efficient energy absorber.

  4. Hypervelocity Impact Performance of Open Cell Foam Core Sandwich Panel Structures

    Science.gov (United States)

    Ryan, S.; Ordonez, E.; Christiansen, E. L.; Lear, D. M.

    2010-01-01

    Open cell metallic foam core sandwich panel structures are of interest for application in spacecraft micrometeoroid and orbital debris shields due to their novel form and advantageous structural and thermal performance. Repeated shocking as a result of secondary impacts upon individual foam ligaments during the penetration process acts to raise the thermal state of impacting projectiles ; resulting in fragmentation, melting, and vaporization at lower velocities than with traditional shielding configurations (e.g. Whipple shield). In order to characterize the protective capability of these structures, an extensive experimental campaign was performed by the Johnson Space Center Hypervelocity Impact Technology Facility, the results of which are reported in this paper. Although not capable of competing against the protection levels achievable with leading heavy shields in use on modern high-risk vehicles (i.e. International Space Station modules), metallic foam core sandwich panels are shown to provide a substantial improvement over comparable structural panels and traditional low weight shielding alternatives such as honeycomb sandwich panels and metallic Whipple shields. A ballistic limit equation, generalized in terms of panel geometry, is derived and presented in a form suitable for application in risk assessment codes.

  5. Attenuation of FJ44 Turbofan Engine Noise with a Foam-Metal Liner Installed Over-the-Rotor

    Science.gov (United States)

    Sutliff, Daniel L.; Elliott, Dave M.; Jones, Michael G.; Hartley, Thomas C.

    2009-01-01

    A Williams International FJ44-3A 3000-lb thrust class turbofan engine was used as a demonstrator for a Foam-Metal Liner (FML) installed in close proximity to the fan. Two FML designs were tested and compared to the hardwall baseline. Traditional single degree-of-freedom liner designs were also evaluated to provide a comparison. Farfield acoustic levels and limited engine performance results are presented in this paper. The results show that the FML achieved up to 5 dB Acoustic Power Level (PWL) overall attenuation in the forward quadrant, equivalent to the traditional liner design. An earlier report presented the test set-up and conditions.

  6. Data characterizing compressive properties of Al/Al2O3 syntactic foam core metal matrix sandwich

    Directory of Open Access Journals (Sweden)

    Mohammed Yaseer Omar

    2015-12-01

    Full Text Available Microstructural observations and compressive property datasets of metal matrix syntactic foam core sandwich composite at quasi-static and high strain rate (HSR conditions (525–845 s−1 are provided. The data supplied in this article includes sample preparation procedure prior to scanning electron and optical microscopy as well as the micrographs. The data used to construct the stress–strain curves and the derived compressive properties of all specimens in both quasi-static and HSR regions are included. Videos of quasi-static compressive failure and that obtained by a high speed image acquisition system during deformation and failure of HSR specimen are also included.

  7. Plasticity and damage in aluminum syntactic foams deformed under dynamic and quasi-static conditions

    Energy Technology Data Exchange (ETDEWEB)

    Balch, Dorian K. [Northwestern University, Evanston, IL (United States); O' Dwyer, John G. [Waterford Institute of Technology (Ireland); Davis, Graham R. [Queen Mary, University of London (United Kingdom); Cady, Carl M. [Los Alamos National Laboratory, Los Alamos, NM (United States); Gray, George T. [Los Alamos National Laboratory, Los Alamos, NM (United States); Dunand, David C. [Northwestern University, Evanston, IL (United States)]. E-mail: dunand@northwestern.edu

    2005-01-25

    Syntactic foams were fabricated by liquid metal infiltration of commercially pure and 7075 aluminum into preforms of hollow ceramic microspheres. The foams exhibited peak strengths during quasi-static compression ranging from -100 to -230 MPa, while dynamic compression loading showed a 10-30% increase in peak strength magnitude, with strain rate sensitivities similar to those of aluminum-matrix composite materials. X-ray tomographic investigation of the post-compression loaded foam microstructures revealed sharp differences in deformation modes, with the unalloyed-Al foam failing initially by matrix deformation, while the alloy-matrix foams failed more abruptly through the formation of sharp crush bands oriented at about 45 deg. to the compression axis. These foams displayed pronounced energy-absorbing capabilities, suggesting their potential use in packaging applications or for impact protection; proper tailoring of matrix and microsphere strengths would result in optimized syntactic foam properties.

  8. Aqueous foam toxicology evaluation and hazard review

    Energy Technology Data Exchange (ETDEWEB)

    Archuleta, M.M.

    1995-10-01

    Aqueous foams are aggregates of bubbles mechanically generated by passing air or other gases through a net, screen, or other porous medium that is wetted by an aqueous solution of surface-active foaming agents (surfactants). Aqueous foams are important in modem fire-fighting technology, as well as for military uses for area denial and riot or crowd control. An aqueous foam is currently being developed and evaluated by Sandia National Laboratories (SNL) as a Less-Than-Lethal Weapon for the National Institute of Justice (NIJ). The purpose of this study is to evaluate the toxicity of the aqueous foam developed for the NIJ and to determine whether there are any significant adverse health effects associated with completely immersing individuals without protective equipment in the foam. The toxicity of the aqueous foam formulation developed for NIJ is determined by evaluating the toxicity of the individual components of the foam. The foam is made from a 2--5% solution of Steol CA-330 surfactant in water generated at expansion ratios ranging from 500:1 to 1000:1. SteoI CA-330 is a 35% ammonium laureth sulfate in water and is produced by Stepan Chemical Company and containing trace amounts (<0.1%) of 1,4-dioxane. The results of this study indicate that Steol CA-330 is a non-toxic, mildly irritating, surfactant that is used extensively in the cosmetics industry for hair care and bath products. Inhalation or dermal exposure to this material in aqueous foam is not expected to produce significant irritation or systemic toxicity to exposed individuals, even after prolonged exposure. The amount of 1,4-dioxane in the surfactant, and subsequently in the foam, is negligible and therefore, the toxicity associated with dioxane exposure is not significant. In general, immersion in similar aqueous foams has not resulted in acute, immediately life-threatening effects, or chronic, long-term, non-reversible effects following exposure.

  9. Bioremediation of aqueous pollutants using biomass embedded in hydrophilic foam. Final report

    International Nuclear Information System (INIS)

    Wilde, E.W.; Radway, J.C.; Santo Domingo, J.; Zingmark, R.G.; Whitaker, M.J.

    1996-01-01

    The major objective of this project was to examine the potential of a novel hydrophilic polyurethane foam as an immobilization medium for algal, bacteria, and other types of biomass, and to test the resulting foam/biomass aggregates for their use in cleaning up waters contaminated with heavy metals, radionuclides and toxic organic compounds. Initial investigations focused on the bioremoval of heavy metals from wastewaters at SRS using immobilized algal biomass. This effort met with limited success for reasons which included interference in the binding of biomass and target metals by various non-target constituents in the wastewater, lack of an appropriate wastewater at SRS for testing, and the unavailability of bioreactor systems capable of optimizing contact of target pollutants with sufficient biomass binding sites. Subsequent studies comparing algal, bacterial, fungal, and higher plant biomass demonstrated that other biomass sources were also ineffective for metal bioremoval under the test conditions. Radionuclide bioremoval using a Tc-99 source provided more promising results than the metal removal studies with the various types of biomass, and indicated that the alga Cyanidium was the best of the tested sources of biomass for this application. However, all of the biomass/foam aggregates tested were substantially inferior to a TEVA resin for removing Tc-99 in comparative testing. The authors also explored the use of hydrophilic polyurethane foam to embed Burkholderia cepacia, which is an efficient degrader of trichloroethylene (TCE), a contaminant of considerable concern at SRS and elsewhere. The embedded population proved to be incapable of growth on nutrient media, but retained respiratory activity. Lastly, the degradative capabilities of embedded G4 were examined. Phenol- or benzene-induced bacteria retained the ability to degrade TCE and benzene. The authors were successful in inducing enzyme activity after the organisms had already been embedded

  10. Bioremediation of aqueous pollutants using biomass embedded in hydrophilic foam. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Wilde, E.W.; Radway, J.C.; Santo Domingo, J.; Zingmark, R.G.; Whitaker, M.J.

    1996-12-31

    The major objective of this project was to examine the potential of a novel hydrophilic polyurethane foam as an immobilization medium for algal, bacteria, and other types of biomass, and to test the resulting foam/biomass aggregates for their use in cleaning up waters contaminated with heavy metals, radionuclides and toxic organic compounds. Initial investigations focused on the bioremoval of heavy metals from wastewaters at SRS using immobilized algal biomass. This effort met with limited success for reasons which included interference in the binding of biomass and target metals by various non-target constituents in the wastewater, lack of an appropriate wastewater at SRS for testing, and the unavailability of bioreactor systems capable of optimizing contact of target pollutants with sufficient biomass binding sites. Subsequent studies comparing algal, bacterial, fungal, and higher plant biomass demonstrated that other biomass sources were also ineffective for metal bioremoval under the test conditions. Radionuclide bioremoval using a Tc-99 source provided more promising results than the metal removal studies with the various types of biomass, and indicated that the alga Cyanidium was the best of the tested sources of biomass for this application. However, all of the biomass/foam aggregates tested were substantially inferior to a TEVA resin for removing Tc-99 in comparative testing. The authors also explored the use of hydrophilic polyurethane foam to embed Burkholderia cepacia, which is an efficient degrader of trichloroethylene (TCE), a contaminant of considerable concern at SRS and elsewhere. The embedded population proved to be incapable of growth on nutrient media, but retained respiratory activity. Lastly, the degradative capabilities of embedded G4 were examined. Phenol- or benzene-induced bacteria retained the ability to degrade TCE and benzene. The authors were successful in inducing enzyme activity after the organisms had already been embedded.

  11. FoamVis, A Visualization System for Foam Research: Design and Implementation

    OpenAIRE

    Lipsa, Dan; Roberts, Richard; Laramee, Robert

    2015-01-01

    Liquid foams are used in areas such as mineral separation, oil recovery, food and beverage production, sanitation and fire fighting. To improve the quality of products and the efficiency of processes in these areas, foam scientists wish to understand and control foam behaviour. To this end, foam scientists have used foam simulations to model foam behaviour; however, analysing these simulations presents difficult challenges. We describe the main foam research challenges and present the design ...

  12. Geometry anisotropy and mechanical property isotropy in titanium foam fabricated by replica impregnation method

    International Nuclear Information System (INIS)

    Manonukul, Anchalee; Srikudvien, Pathompoom; Tange, Makiko; Puncreobutr, Chedtha

    2016-01-01

    Polyurethane (PU) foams have both geometry and mechanical property anisotropy. Metal foams, which are manufacturing by investment casting or melt deposition method and using PU foam as a template, also have mechanical property anisotropy. This work studied the mechanical properties in two directions of titanium foam with four different cell sizes fabricated using the replica impregnation method. The two directions are (1) the loading direction parallel to the foaming direction where the cells are elongated (EL direction) and (2) the loading direction perpendicular to the foaming direction where the cell are equiaxed (EQ direction). The results show that the compression responses for both EL and EQ directions are isotropy. Micrographs and X-ray micro-computed tomography show that the degree of geometry anisotropy is not strong enough to results in mechanical property anisotropy.

  13. Geometry anisotropy and mechanical property isotropy in titanium foam fabricated by replica impregnation method

    Energy Technology Data Exchange (ETDEWEB)

    Manonukul, Anchalee, E-mail: anchalm@mtec.or.th [National Metal and Materials Technology Center (MTEC), National Science and Technology Development Agency (NSTDA), 114 Thailand Science Park, Paholyothin Rd., Klong 1, Klong Luang, Pathumthani 12120 (Thailand); Srikudvien, Pathompoom [National Metal and Materials Technology Center (MTEC), National Science and Technology Development Agency (NSTDA), 114 Thailand Science Park, Paholyothin Rd., Klong 1, Klong Luang, Pathumthani 12120 (Thailand); Tange, Makiko [Taisei Kogyo Thailand Co., Ltd., Room INC2d-409, Innovation Cluster 2 Building, Tower D, 141 Thailand Science Park, Paholyothin Rd., Klong 1, Klong Luang, Pathumthani 12120 (Thailand); Puncreobutr, Chedtha [Department of Metallurgical Engineering, Faculty of Engineering, Chulalongkorn University, Pathumwan, Bangkok 10330 (Thailand)

    2016-02-08

    Polyurethane (PU) foams have both geometry and mechanical property anisotropy. Metal foams, which are manufacturing by investment casting or melt deposition method and using PU foam as a template, also have mechanical property anisotropy. This work studied the mechanical properties in two directions of titanium foam with four different cell sizes fabricated using the replica impregnation method. The two directions are (1) the loading direction parallel to the foaming direction where the cells are elongated (EL direction) and (2) the loading direction perpendicular to the foaming direction where the cell are equiaxed (EQ direction). The results show that the compression responses for both EL and EQ directions are isotropy. Micrographs and X-ray micro-computed tomography show that the degree of geometry anisotropy is not strong enough to results in mechanical property anisotropy.

  14. Foams, fibers, and composites: Where do we stand?

    International Nuclear Information System (INIS)

    Chawla, K.K.

    2012-01-01

    As of 2012, I am officially a septuagenarian. This means that in the eighth decade of my life, much of which has been devoted to fibers, foams, and composites, I am allowed to indulge in some crystal gazing. I would like to take this occasion to reflect on the progress made in these fields of materials. Materials in the form of foams, fibers, and composites cover a very wide range: in biological and manmade materials. In the area of foams, functional and fiber reinforced foams are likely to see a lot of research activity. In the area of fibers, besides carbon fibers based on nanotubes and natural fibers, the real action is in the materials science and engineering of silk fibers. In the larger field of composites, the success of carbon/epoxy composites is epitomized by Boeing 787. Particle reinforced metal matrix composites, continuous alumina fiber reinforced aluminum composites seem very promising, as are techniques such as application of tomography to investigate the material behavior of these composites.

  15. Role of foam drainage in producing protein aggregates in foam fractionation.

    Science.gov (United States)

    Li, Rui; Zhang, Yuran; Chang, Yunkang; Wu, Zhaoliang; Wang, Yanji; Chen, Xiang'e; Wang, Tao

    2017-10-01

    It is essential to obtain a clear understanding of the foam-induced protein aggregation to reduce the loss of protein functionality in foam fractionation. The major effort of this work is to explore the roles of foam drainage in protein aggregation in the entire process of foam fractionation with bovine serum albumin (BSA) as a model protein. The results show that enhancing foam drainage increased the desorption of BSA molecules from the gas-liquid interface and the local concentration of desorbed molecules in foam. Therefore, it intensified the aggregation of BSA in foam fractionation. Simultaneously, it also accelerated the flow of BSA aggregates from rising foam into the residual solution along with the drained liquid. Because enhancing foam drainage increased the relative content of BSA molecules adsorbed at the gas-liquid interface, it also intensified the aggregation of BSA during both the defoaming process and the storage of the foamate. Furthermore, enhancing foam drainage more readily resulted in the formation of insoluble BSA aggregates. The results are highly important for a better understanding of foam-induced protein aggregation in foam fractionation. Copyright © 2017 Elsevier B.V. All rights reserved.

  16. Properties of polyurethane foam/coconut coir fiber as a core material and as a sandwich composites component

    Science.gov (United States)

    Azmi, M. A.; Abdullah, H. Z.; Idris, M. I.

    2013-12-01

    This research focuses on the fabrication and characterization of sandwich composite panels using glass fiber composite skin and polyurethane foam reinforced coconut coir fiber core. The main objectives are to characterize the physical and mechanical properties and to elucidate the effect of coconut coir fibers in polyurethane foam cores and sandwich composite panels. Coconut coir fibers were used as reinforcement in polyurethane foams in which later were applied as the core in sandwich composites ranged from 5 wt% to 20 wt%. The physical and mechanical properties found to be significant at 5 wt% coconut coir fiber in polyurethane foam cores as well as in sandwich composites. It was found that composites properties serve better in sandwich composites construction.

  17. Properties of polyurethane foam/coconut coir fiber as a core material and as a sandwich composites component

    International Nuclear Information System (INIS)

    Azmi, M A; Abdullah, H Z; Idris, M I

    2013-01-01

    This research focuses on the fabrication and characterization of sandwich composite panels using glass fiber composite skin and polyurethane foam reinforced coconut coir fiber core. The main objectives are to characterize the physical and mechanical properties and to elucidate the effect of coconut coir fibers in polyurethane foam cores and sandwich composite panels. Coconut coir fibers were used as reinforcement in polyurethane foams in which later were applied as the core in sandwich composites ranged from 5 wt% to 20 wt%. The physical and mechanical properties found to be significant at 5 wt% coconut coir fiber in polyurethane foam cores as well as in sandwich composites. It was found that composites properties serve better in sandwich composites construction

  18. MyrrhaFoam: A CFD model for the study of the thermal hydraulic behavior of MYRRHA

    Energy Technology Data Exchange (ETDEWEB)

    Koloszar, Lilla; Buckingham, Sophia; Planquart, Philippe [von Karman Institute, Chaussée de Waterloo 72, B-1640 Rhode-St-Genèse (Belgium); Keijers, Steven [SCK-CEN, Boeretang 200, 2400 Mol (Belgium)

    2017-02-15

    Highlights: • Development of a modeling approach for simulating the thermal hydraulics of heavy liquid metal nuclear reactors. • Detailed description of the modeling of each component through the MYRRHA reactor. • Detailed analysis of the flow field of the MYRRHA reactor under operating condition. • Assessment of the thermal load on the structures as well as the thermal stratification in the upper and the lower plenum. - Abstract: Numerical analysis of the thermohydraulic behavior of the innovative flexible fast spectrum research reactor, MYRRHA, under design by the Belgian Nuclear Research Center (SCK• CEN) is a very challenging task. The primary coolant of the reactor is Lead Bismuth Eutectic, LBE, which is an opaque heavy liquid metal with low Prandtl number. The simulation tool needs to involve many complex physical phenomena to be able to predict accurately the flow and thermal field in the pool type reactor. In the past few years, within the frame of a collaboration between SCK• CEN and the von Karman Institute, a new platform, MyrrhaFoam, was developed based on the open source simulation environment, OpenFOAM. The current tool can deal with incompressible buoyancy corrected steady/unsteady single phase flows. It takes into account conjugate heat transfer in the solid parts which is mandatory due to the expected high temperature gradients between the different parts of the reactor. The temperature dependent properties of LBE are also considered. MyrrhaFoam is supplemented with the most relevant thermal turbulence models for low Prandtl number liquids up to date.

  19. Fabrication of Aluminum Tubes Filled with Aluminum Alloy Foam by Friction Welding

    Directory of Open Access Journals (Sweden)

    Yoshihiko Hangai

    2015-10-01

    Full Text Available Aluminum foam is usually used as the core of composite materials by combining it with dense materials, such as in Al foam core sandwich panels and Al-foam-filled tubes, owing to its low tensile and bending strengths. In this study, all-Al foam-filled tubes consisting of ADC12 Al-Si-Cu die-cast aluminum alloy foam and a dense A1050 commercially pure Al tube with metal bonding were fabricated by friction welding. First, it was found that the ADC12 precursor was firmly bonded throughout the inner wall of the A1050 tube without a gap between the precursor and the tube by friction welding. No deformation of the tube or foaming of the precursor was observed during the friction welding. Next, it was shown that by heat treatment of an ADC12-precursor-bonded A1050 tube, gases generated by the decomposition of the blowing agent expand the softened ADC12 to produce the ADC12 foam interior of the dense A1050 tube. A holding time during the foaming process of approximately tH = 8.5 min with a holding temperature of 948 K was found to be suitable for obtaining a sound ADC12-foam-filled A1050 tube with sufficient foaming, almost uniform pore structures over the entire specimen, and no deformation or reduction in the thickness of the tube.

  20. Biomass derived novel functional foamy materials - BIO-FOAM

    Energy Technology Data Exchange (ETDEWEB)

    Suurnaekki, A.; Boer, H.; Forssell, P. (and others) (VTT Technical Research Centre of Finland, Espoo (Finland)), Email: anna.suurnakki@vtt.fi

    2010-10-15

    BIO-FOAM has aimed at exploiting the potential of biomaterials in replacing synthetic polymers in solid foamy materials. The target applications have been various, including food, packaging, construction and insulation. The project activities during the second project year have focused on characterisation of the solid model foams and on modeling the behaviour of polymers at liquid- liquid interfaces. In the modelling study the intrinsic consistence of the applied thermodynamic approach was confirmed. The experimentally obtained solubility parameters of polymers were in good agreement with the calculated solubility parameters. The polymers were, however, found to posses too little surface activity to alone provide stable foams, but they were able to act as co-surfactants. In the model polymer foam work both expanded polymer foams and wood fibre based foams were prepared. Supercritical CO{sub 2}-gas chamber was found to be a useful tool to prepare expanded polymer foams in small scale. Only partial replacement of synthetic polymers could, however, be obtained with native biomaterials indicating the need of tailoring of biopolymer properties and suitable formulations including surfactants or stabilizing particles. In wood fibre-based foams both nanocellulose and lignin showed potential as additives or reinforcing components.The outcome of the extruded food snacks study was that the processing parameters were related with the equipmentvariables. Furthermore, glycerol was shown to facilitate greatly extrusion processing. In foam concrete work concrete pore structure was shown to correlate with its strength and stability. At optimum concentration wood fibres affected positively the concrete processing performance. (orig.)

  1. Generation of sclerosant foams by mechanical methods increases the foam temperature.

    Science.gov (United States)

    Tan, Lulu; Wong, Kaichung; Connor, David; Fakhim, Babak; Behnia, Masud; Parsi, Kurosh

    2017-08-01

    Objective To investigate the effect of agitation on foam temperature. Methods Sodium tetradecyl sulphate and polidocanol were used. Prior to foam generation, the sclerosant and all constituent equipment were cooled to 4-25℃ and compared with cooling the sclerosant only. Foam was generated using a modified Tessari method. During foam agitation, the temperature change was measured using a thermocouple for 120 s. Results Pre-cooling all the constituent equipment resulted in a cooler foam in comparison with only cooling the sclerosant. A starting temperature of 4℃ produced average foam temperatures of 12.5 and 13.2℃ for sodium tetradecyl sulphate and polidocanol, respectively. It was also found that only cooling the liquid sclerosant provided minimal cooling to the final foam temperature, with the temperature 20 and 20.5℃ for sodium tetradecyl sulphate and polidocanol, respectively. Conclusion The foam generation process has a noticeable impact on final foam temperature and needs to be taken into consideration when creating foam.

  2. FoamVis, A Visualization System for Foam Research: Design and Implementation

    Directory of Open Access Journals (Sweden)

    Dan R. Lipsa

    2015-03-01

    Full Text Available Liquid foams are used in areas such as mineral separation, oil recovery, food and beverage production, sanitation and fire fighting. To improve the quality of products and the efficiency of processes in these areas, foam scientists wish to understand and control foam behaviour. To this end, foam scientists have used foam simulations to model foam behaviour; however, analysing these simulations presents difficult challenges. We describe the main foam research challenges and present the design of FoamVis, the only existing visualization, exploration and analysis application created to address them. We describe FoamVis’ main features, together with relevant design and implementation notes. Our goal is to provide a global overview and individual feature implementation details that would allow a visualization scientist to extend the FoamVis system with new algorithms and adapt it to new requirements. The result is a detailed presentation of the software that is not provided in previous visualization research papers.

  3. EXPERIMENTAL STUDIES ON THE QUASI-STATIC AXIAL CRUSHING BEHAVIOR OF FOAM-FILLED STEEL EXTRUSION TUBES

    OpenAIRE

    AL EMRAN ISMAIL

    2010-01-01

    The concerns of automotive safety have been given special attention in order to reduce human fatalities or injuries. One of the techniques to reduce collision impact or compression energy is by filling polymeric foam into metallic tubes. In this work, polyurethane foam was introduced into the steel extrusion tubes and quasi-statically compressed at constant cross-head displacement. Different tube thicknesses and foam densities were used and these parameters were related to the crashwor...

  4. Biopolymer foams - Relationship between material characteristics and foaming behavior of cellulose based foams

    International Nuclear Information System (INIS)

    Rapp, F.; Schneider, A.; Elsner, P.

    2014-01-01

    Biopolymers are becoming increasingly important to both industry and consumers. With regard to waste management, CO 2 balance and the conservation of petrochemical resources, increasing efforts are being made to replace standard plastics with bio-based polymers. Nowadays biopolymers can be built for example of cellulose, lactic acid, starch, lignin or bio mass. The paper will present material properties of selected cellulose based polymers (cellulose propionate [CP], cellulose acetate butyrate [CAB]) and corresponding processing conditions for particle foams as well as characterization of produced parts. Special focus is given to the raw material properties by analyzing thermal behavior (differential scanning calorimetry), melt strength (Rheotens test) and molecular weight distribution (gel-permeation chromatography). These results will be correlated with the foaming behavior in a continuous extrusion process with physical blowing agents and underwater pelletizer. Process set-up regarding particle foam technology, including extrusion foaming and pre-foaming, will be shown. The characteristics of the resulting foam beads will be analyzed regarding part density, cell morphology and geometry. The molded parts will be tested on thermal conductivity as well as compression behavior (E-modulus, compression strength)

  5. Biopolymer foams - Relationship between material characteristics and foaming behavior of cellulose based foams

    Science.gov (United States)

    Rapp, F.; Schneider, A.; Elsner, P.

    2014-05-01

    Biopolymers are becoming increasingly important to both industry and consumers. With regard to waste management, CO2 balance and the conservation of petrochemical resources, increasing efforts are being made to replace standard plastics with bio-based polymers. Nowadays biopolymers can be built for example of cellulose, lactic acid, starch, lignin or bio mass. The paper will present material properties of selected cellulose based polymers (cellulose propionate [CP], cellulose acetate butyrate [CAB]) and corresponding processing conditions for particle foams as well as characterization of produced parts. Special focus is given to the raw material properties by analyzing thermal behavior (differential scanning calorimetry), melt strength (Rheotens test) and molecular weight distribution (gel-permeation chromatography). These results will be correlated with the foaming behavior in a continuous extrusion process with physical blowing agents and underwater pelletizer. Process set-up regarding particle foam technology, including extrusion foaming and pre-foaming, will be shown. The characteristics of the resulting foam beads will be analyzed regarding part density, cell morphology and geometry. The molded parts will be tested on thermal conductivity as well as compression behavior (E-modulus, compression strength).

  6. 21 CFR 888.3320 - Hip joint metal/metal semi-constrained, with a cemented acetabular component, prosthesis.

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 8 2010-04-01 2010-04-01 false Hip joint metal/metal semi-constrained, with a... Devices § 888.3320 Hip joint metal/metal semi-constrained, with a cemented acetabular component, prosthesis. (a) Identification. A hip joint metal/metal semi-constrained, with a cemented acetabular...

  7. 21 CFR 888.3330 - Hip joint metal/metal semi-constrained, with an uncemented acetabular component, prosthesis.

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 8 2010-04-01 2010-04-01 false Hip joint metal/metal semi-constrained, with an... Devices § 888.3330 Hip joint metal/metal semi-constrained, with an uncemented acetabular component, prosthesis. (a) Identification. A hip joint metal/metal semi-constrained, with an uncemented acetabular...

  8. Method Of Bonding A Metal Connection To An Electrode Including A Core Having A Fiber Or Foam Type Structure For An Electrochemical Cell, An

    Science.gov (United States)

    Loustau, Marie-Therese; Verhoog, Roelof; Precigout, Claude

    1996-09-24

    A method of bonding a metal connection to an electrode including a core having a fiber or foam-type structure for an electrochemical cell, in which method at least one metal strip is pressed against one edge of the core and is welded thereto under compression, wherein, at least in line with the region in which said strip is welded to the core, which is referred to as the "main core", a retaining core of a type analogous to that of the main core is disposed prior to the welding.

  9. Removal of mercury by foam fractionation using surfactin, a biosurfactant.

    Science.gov (United States)

    Chen, Hau-Ren; Chen, Chien-Cheng; Reddy, A Satyanarayana; Chen, Chien-Yen; Li, Wun Rong; Tseng, Min-Jen; Liu, Hung-Tsan; Pan, Wei; Maity, Jyoti Prakash; Atla, Shashi B

    2011-01-01

    The separation of mercury ions from artificially contaminated water by the foam fractionation process using a biosurfactant (surfactin) and chemical surfactants (SDS and Tween-80) was investigated in this study. Parameters such as surfactant and mercury concentration, pH, foam volume, and digestion time were varied and their effects on the efficiency of mercury removal were investigated. The recovery efficiency of mercury ions was highly sensitive to the concentration of the surfactant. The highest mercury ion recovery by surfactin was obtained using a surfactin concentration of 10 × CMC, while recovery using SDS required 10 × CMC. However, the enrichment of mercury ions in the foam was superior with surfactin, the mercury enrichment value corresponding to the highest metal recovery (10.4%) by surfactin being 1.53. Dilute solutions (2-mg L(-1) Hg(2+)) resulted in better separation (36.4%), while concentrated solutions (100 mg L(-1)) enabled only a 2.3% recovery using surfactin. An increase in the digestion time of the metal solution with surfactin yielded better separation as compared with a freshly-prepared solution, and an increase in the airflow rate increased bubble production, resulting in higher metal recovery but low enrichment. Basic solutions yielded higher mercury separation as compared with acidic solutions due to the precipitation of surfactin under acidic conditions.

  10. Removal of Mercury by Foam Fractionation Using Surfactin, a Biosurfactant

    Directory of Open Access Journals (Sweden)

    Shashi B. Atla

    2011-11-01

    Full Text Available The separation of mercury ions from artificially contaminated water by the foam fractionation process using a biosurfactant (surfactin and chemical surfactants (SDS and Tween-80 was investigated in this study. Parameters such as surfactant and mercury concentration, pH, foam volume, and digestion time were varied and their effects on the efficiency of mercury removal were investigated. The recovery efficiency of mercury ions was highly sensitive to the concentration of the surfactant. The highest mercury ion recovery by surfactin was obtained using a surfactin concentration of 10 × CMC, while recovery using SDS required < 10 × CMC and Tween-80 >10 × CMC. However, the enrichment of mercury ions in the foam was superior with surfactin, the mercury enrichment value corresponding to the highest metal recovery (10.4% by surfactin being 1.53. Dilute solutions (2-mg L−1 Hg2+ resulted in better separation (36.4%, while concentrated solutions (100 mg L−1 enabled only a 2.3% recovery using surfactin. An increase in the digestion time of the metal solution with surfactin yielded better separation as compared with a freshly-prepared solution, and an increase in the airflow rate increased bubble production, resulting in higher metal recovery but low enrichment. Basic solutions yielded higher mercury separation as compared with acidic solutions due to the precipitation of surfactin under acidic conditions.

  11. Bulk forming of industrial micro components in conventional metals and bulk metallic glasses

    DEFF Research Database (Denmark)

    Arentoft, Mogens; Paldan, Nikolas Aulin; Eriksen, Rasmus Solmer

    2007-01-01

    For production of micro components in large numbers, forging is an interesting and challenging process. The conventional metals like silver, steel and aluminum often require multi-step processes, but high productivity and increased strength justify the investment. As an alternative, bulk metallic...

  12. Liquid foam templating - A route to tailor-made polymer foams.

    Science.gov (United States)

    Andrieux, Sébastien; Quell, Aggeliki; Stubenrauch, Cosima; Drenckhan, Wiebke

    2018-06-01

    Solid foams with pore sizes between a few micrometres and a few millimetres are heavily exploited in a wide range of established and emerging applications. While the optimisation of foam applications requires a fine control over their structural properties (pore size distribution, pore opening, foam density, …), the great complexity of most foaming processes still defies a sound scientific understanding and therefore explicit control and prediction of these parameters. We therefore need to improve our understanding of existing processes and also develop new fabrication routes which we understand and which we can exploit to tailor-make new porous materials. One of these new routes is liquid templating in general and liquid foam templating in particular, to which this review article is dedicated. While all solid foams are generated from an initially liquid(-like) state, the particular notion of liquid foam templating implies the specific condition that the liquid foam has time to find its "equilibrium structure" before it is solidified. In other words, the characteristic time scales of the liquid foam's stability and its solidification are well separated, allowing to build on the vast know-how on liquid foams established over the last 20 years. The dispersed phase of the liquid foam determines the final pore size and pore size distribution, while the continuous phase contains the precursors of the desired porous scaffold. We review here the three key challenges which need to be addressed by this approach: (1) the control of the structure of the liquid template, (2) the matching of the time scales between the stability of the liquid template and solidification, and (3) the preservation of the structure of the template throughout the process. Focusing on the field of polymer foams, this review gives an overview of recent research on the properties of liquid foam templates and summarises a key set of studies in the emerging field of liquid foam templating. It

  13. Non-stochastic Ti-6Al-4V foam structures with negative Poisson's ratio

    Energy Technology Data Exchange (ETDEWEB)

    Yang, Li, E-mail: lyang5@ncsu.edu [Edward P. Fitts Department of Industrial and Systems Engineering, North Carolina State University, 400 Daniels Hall, 111 Lampe Drive, Raleigh, NC 27695 (United States); Cormier, Denis, E-mail: drceie@rit.edu [Department of Industrial Systems Engineering, Rochester Institute of Technology, 81 Lomb Memorial Drive, Rochester, NY 14623-5603 (United States); West, Harvey, E-mail: hawest@ncsu.edu [Edward P. Fitts Department of Industrial and Systems Engineering, North Carolina State University, 400 Daniels Hall, 111 Lampe Drive, Raleigh, NC 27695 (United States); Harrysson, Ola, E-mail: harrysson@ncsu.edu [Edward P. Fitts Department of Industrial and Systems Engineering, North Carolina State University, 400 Daniels Hall, 111 Lampe Drive, Raleigh, NC 27695 (United States); Knowlson, Kyle, E-mail: kyle.knowlson@gmail.com [Edward P. Fitts Department of Industrial and Systems Engineering, North Carolina State University, 400 Daniels Hall, 111 Lampe Drive, Raleigh, NC 27695 (United States)

    2012-12-15

    This paper details the design, fabrication, and testing of non-stochastic auxetic lattice lattice structures. All Ti-6Al-4V samples were created via the Electron Beam Melting (EBM) additive manufacturing process. It was found that the Poisson's ratio values significantly influence the mechanical properties of the structures. The bending properties of the auxetic samples were significantly higher than those of currently commercialized metal foams. The compressive strength was moderately higher than available metal foams. These results suggest that metallic auxetic structures have considerable promise for use in a variety of applications in which tradeoffs between mass and mechanical properties are crucial.

  14. A review of low add-on and foam application techniques

    CSIR Research Space (South Africa)

    Van der Walt, GHJ

    1984-02-01

    Full Text Available -February 1984 This application system consists of four major components: the engraved roller (A), a rubber roller (B), a doctor blade (C), and the liquor The engraved roller rotates in the liquor bath (D) where its cavities are ffled with Liquor...".'". 5.2 Different Systems for the AppUeatioa of Foam There are several basic mechanisms for the application of foam to textiles. The foam can be applied either to one side or both sides of the fabric. In the former case a doctor blade or knife, or a...

  15. Headspace analysis of foams and fixatives

    Energy Technology Data Exchange (ETDEWEB)

    Harper, Kyle [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Truong, Thanh-Tam [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Magwood, Leroy [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Peters, Brent [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Nicholson, James [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Washington, II, Aaron L. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

    2017-07-27

    In the process of decontaminating and decommissioning (D&D) older nuclear facilities, special precautions must be taken with removable or airborne contamination. One possible strategy utilizes foams and fixatives to affix these loose contaminants. Many foams and fixatives are already commercially available, either generically or sold specifically for D&D. However, due to a lack of revelant testing in a radioactive environment, additional verification is needed to confirm that these products not only affix contamination to their surfaces, but also will function in a D&D environment. Several significant safety factors, including flammability and worker safety, can be analyzed through the process of headspace analysis, a technique that analyzes the off gas formed before or during the curing process of the foam/fixative, usually using gas chromatography-mass spectrometry (GC-MS). This process focuses on the volatile components of a chemical, which move freely between the solid/liquid form within the sample and the gaseous form in the area above the sample (the headspace). Between possibly hot conditions in a D&D situation and heat created in a foaming reaction, the volatility of many chemicals can change, and thus different gasses can be released at different times throughout the reaction. This project focused on analysis of volatile chemicals involved in the process of using foams and fixatives to identify any potential hazardous or flammable compounds.

  16. Aluminium Foam and Magnesium Compound Casting Produced by High-Pressure Die Casting

    Directory of Open Access Journals (Sweden)

    Iban Vicario

    2016-01-01

    Full Text Available Nowadays, fuel consumption and carbon dioxide emissions are two of the main focal points in vehicle design, promoting the reduction in the weight of vehicles by using lighter materials. The aim of the work is to evaluate the influence of different aluminium foams and injection parameters in order to obtain compound castings with a compromise between the obtained properties and weight by high-pressure die cast (HPDC using aluminium foams as cores into a magnesium cast part. To evaluate the influence of the different aluminium foams and injection parameters on the final casting products quality, the type and density of the aluminium foam, metal temperature, plunger speed, and multiplication pressure have been varied within a range of suitable values. The obtained compound HPDC castings have been studied by performing visual and RX inspections, obtaining sound composite castings with aluminium foam cores. The presence of an external continuous layer on the foam surface and the correct placement of the foam to support injection conditions permit obtaining good quality parts. A HPDC processed magnesium-aluminium foam composite has been developed for a bicycle application obtaining a suitable combination of mechanical properties and, especially, a reduced weight in the demonstration part.

  17. Optimisation of multi-layer rotationally moulded foamed structures

    Science.gov (United States)

    Pritchard, A. J.; McCourt, M. P.; Kearns, M. P.; Martin, P. J.; Cunningham, E.

    2018-05-01

    Multi-layer skin-foam and skin-foam-skin sandwich constructions are of increasing interest in the rotational moulding process for two reasons. Firstly, multi-layer constructions can improve the thermal insulation properties of a part. Secondly, foamed polyethylene sandwiched between solid polyethylene skins can increase the mechanical properties of rotationally moulded structural components, in particular increasing flexural properties and impact strength (IS). The processing of multiple layers of polyethylene and polyethylene foam presents unique challenges such as the control of chemical blowing agent decomposition temperature, and the optimisation of cooling rates to prevent destruction of the foam core; therefore, precise temperature control is paramount to success. Long cooling cycle times are associated with the creation of multi-layer foam parts due to their insulative nature; consequently, often making the costs of production prohibitive. Devices such as Rotocooler®, a rapid internal mould water spray cooling system, have been shown to have the potential to significantly decrease cooling times in rotational moulding. It is essential to monitor and control such devices to minimise the warpage associated with the rapid cooling of a moulding from only one side. The work presented here demonstrates the use of threaded thermocouples to monitor the polymer melt in multi-layer sandwich constructions, in order to analyse the cooling cycle of multi-layer foamed structures. A series of polyethylene skin-foam test mouldings were produced, and the effect of cooling medium on foam characteristics, mechanical properties, and process cycle time were investigated. Cooling cycle time reductions of 45%, 26%, and 29% were found for increasing (1%, 2%, and 3%) chemical blowing agent (CBA) amount when using internal water cooling technology from ˜123°C compared with forced air cooling (FAC). Subsequently, a reduction of IS for the same skin-foam parts was found to be 1%, 4

  18. Effect of the carbonyl iron particles on acoustic absorption properties of magnetic polyurethane foam

    Science.gov (United States)

    Geng, Jialu; Wang, Caiping; Zhu, Honglang; Wang, Xiaojie

    2018-03-01

    Elastomeric matrix embedded with magnetic micro-sized particles has magnetically controllable properties, which has been investigated extensively in the last decades. In this study we develop a new magnetically controllable elastomeric material for acoustic applications at lower frequencies. The soft polyurethane foam is used as matrix material due to its extraordinary elastic and acoustic absorption properties. One-step method is used to synthesize polyurethane foam, in which all components including polyether polyols 330N, MDI, deionized water, silicone oil, carbonyl iron particle (CIP) and catalyst are put into one container for curing. Changing any component can induce the change of polyurethane foam's properties, such as physical and acoustic properties. The effect of the content of MDI on acoustic absorption is studied. The CIPs are aligned under extra magnetic field during the foaming process. And the property of polyurethane foam with aligned CIPs is also investigated. Scanning electron microscope (SEM) is used to observe the structure of pore and particle-chain. The two-microphone impedance tube and the transfer function method are used to test acoustic absorption property of the magnetic foams.

  19. Composite carbon foam electrode

    Science.gov (United States)

    Mayer, Steven T.; Pekala, Richard W.; Kaschmitter, James L.

    1997-01-01

    Carbon aerogels used as a binder for granularized materials, including other forms of carbon and metal additives, are cast onto carbon or metal fiber substrates to form composite carbon thin film sheets. The thin film sheets are utilized in electrochemical energy storage applications, such as electrochemical double layer capacitors (aerocapacitors), lithium based battery insertion electrodes, fuel cell electrodes, and electrocapacitive deionization electrodes. The composite carbon foam may be formed by prior known processes, but with the solid particles being added during the liquid phase of the process, i.e. prior to gelation. The other forms of carbon may include carbon microspheres, carbon powder, carbon aerogel powder or particles, graphite carbons. Metal and/or carbon fibers may be added for increased conductivity. The choice of materials and fibers will depend on the electrolyte used and the relative trade off of system resistivty and power to system energy.

  20. Strain-rate dependence for Ni/Al hybrid foams

    Directory of Open Access Journals (Sweden)

    Jung Anne

    2015-01-01

    Full Text Available Shock absorption often needs stiff but lightweight materials that exhibit a large kinetic energy absorption capability. Open-cell metal foams are artificial structures, which due to their plateau stress, including a strong hysteresis, can in principle absorb large amounts of energy. However, their plateau stress is too low for many applications. In this study, we use highly novel and promising Ni/Al hybrid foams which consist of standard, open-cell aluminium foams, where nanocrystalline nickel is deposited by electrodeposition as coating on the strut surface. The mechanical behaviour of cellular materials, including their behaviour under higher strain-rates, is governed by their microstructure due to the properties of the strut material, pore/strut geometry and mass distribution over the struts. Micro-inertia effects are strongly related to the microstructure. For a conclusive model, the exact real microstructure is needed. In this study a micro-focus computer tomography (μCT system has been used for the analysis of the microstructure of the foam samples and for the development of a microstructural Finite Element (micro-FE mesh. The microstructural FE models have been used to model the mechanical behaviour of the Ni/Al hybrid foams under dynamic loading conditions. The simulations are validated by quasi-static compression tests and dynamic split Hopkinson pressure bar tests.

  1. Foam Microrheology

    International Nuclear Information System (INIS)

    KRAYNIK, ANDREW M.; LOEWENBERG, MICHAEL; REINELT, DOUGLAS A.

    1999-01-01

    The microrheology of liquid foams is discussed for two different regimes: static equilibrium where the capillary number Ca is zero, and the viscous regime where viscosity and surface tension are important and Ca is finite. The Surface Evolver is used to calculate the equilibrium structure of wet Kelvin foams and dry soap froths with random structure, i.e., topological disorder. The distributions of polyhedra and faces are compared with the experimental data of Matzke. Simple shearing flow of a random foam under quasistatic conditions is also described. Viscous phenomena are explored in the context of uniform expansion of 2D and 3D foams at low Reynolds number. Boundary integral methods are used to calculate the influence of Ca on the evolution of foam microstructure, which includes bubble shape and the distribution of liquid between films, Plateau borders, and (in 3D) the nodes where Plateau borders meet. The micromechanical point of view guides the development of structure-property-processing relationships for foams

  2. dsmcFoam+: An OpenFOAM based direct simulation Monte Carlo solver

    Science.gov (United States)

    White, C.; Borg, M. K.; Scanlon, T. J.; Longshaw, S. M.; John, B.; Emerson, D. R.; Reese, J. M.

    2018-03-01

    dsmcFoam+ is a direct simulation Monte Carlo (DSMC) solver for rarefied gas dynamics, implemented within the OpenFOAM software framework, and parallelised with MPI. It is open-source and released under the GNU General Public License in a publicly available software repository that includes detailed documentation and tutorial DSMC gas flow cases. This release of the code includes many features not found in standard dsmcFoam, such as molecular vibrational and electronic energy modes, chemical reactions, and subsonic pressure boundary conditions. Since dsmcFoam+ is designed entirely within OpenFOAM's C++ object-oriented framework, it benefits from a number of key features: the code emphasises extensibility and flexibility so it is aimed first and foremost as a research tool for DSMC, allowing new models and test cases to be developed and tested rapidly. All DSMC cases are as straightforward as setting up any standard OpenFOAM case, as dsmcFoam+ relies upon the standard OpenFOAM dictionary based directory structure. This ensures that useful pre- and post-processing capabilities provided by OpenFOAM remain available even though the fully Lagrangian nature of a DSMC simulation is not typical of most OpenFOAM applications. We show that dsmcFoam+ compares well to other well-known DSMC codes and to analytical solutions in terms of benchmark results.

  3. Foaming and Antifoaming in Radioactive Waste Pretreatment and Immobilization

    International Nuclear Information System (INIS)

    Wasan, Darsh T.

    2002-01-01

    Radioactive waste treatment processes usually involve concentration of radionuclides before waste can be immobilized by storing it in stable solid form. Foaming is observed at various stages of waste processing like sludge chemical processing and melter operations. Hence, the objective of this research was to study the mechanisms that produce foaming during nuclear waste treatment, to identify key parameters which aggravate foaming, and to identify effective ways to eliminate or mitigate foaming. Experimental and theoretical investigations of the surface phenomenon, suspension rheology, and bubble generation and interactions that lead to the formation of foam during waste processing were pursued under this EMSP project. Advanced experimental techniques including a novel capillary force balance in conjunction with the combined differential and common interferometry were developed to characterize particle-particle interactions at the foam lamella surfaces as well as inside the foam lamella. Laboratory tests were conducted using a non-radioactive simulant slurry containing high levels of noble metals and mercury similar to the High-Level Waste. We concluded that foaminess of the simulant sludge was due to the presence of colloidal particles such as aluminum, iron, and manganese. We have established the two major mechanisms of formation and stabilization of foams containing such colloidal particles: (1) structural and depletion forces; and (2) steric stabilization due to the adsorbed particles at the surfaces of the foam lamella. Based on this mechanistic understanding of foam generation and stability, an improved antifoam agent was developed by us, since commercial antifoam agents were found to be ineffective in the aggressive physical and chemical environment present in the sludge processing. The improved antifoamer was subsequently tested in a pilot plant at the Savannah River Site (SRS) and was found to be effective. Also, in the SRTC experiment, the irradiated

  4. Graphite Foam Heat Exchangers for Thermal Management

    Energy Technology Data Exchange (ETDEWEB)

    Klett, J.W.

    2004-06-07

    Improved thermal management is needed to increase the power density of electronic and more effectively cool electronic enclosures that are envisioned in future aircraft, spacecraft and surface ships. Typically, heat exchanger cores must increase in size to more effectively dissipate increased heat loads, this would be impossible in many cases, thus improved heat exchanger cores will be required. In this Phase I investigation, MRi aimed to demonstrate improved thermal management using graphite foam (Gr-foam) core heat exchangers. The proposed design was to combine Gr-foams from POCO with MRi's innovative low temperature, active metal joining process (S-Bond{trademark}) to bond Gr-foam to aluminum, copper and aluminum/SiC composite faceplates. The results were very favorable, so a Phase II SBIR with the MDA was initiated. This had primarily 5 tasks: (1) bonding, (2) thermal modeling, (3) cooling chip scale packages, (4) evaporative cooling techniques and (5) IGBT cold plate development. The bonding tests showed that the ''reflow'' technique with S-Bond{reg_sign}-220 resulted in the best and most consistent bond. Then, thermal modeling was used to design different chip scale packages and IGBT cold plates. These designs were used to fabricate many finned graphite foam heat sinks specifically for two standard type IC packages, the 423 and 478 pin chips. These results demonstrated several advantages with the foam. First, the heat sinks with the foam were lighter than the copper/aluminum sinks used as standards. The sinks for the 423 design made from foam were not as good as the standard sinks. However, the sinks made from foam for the 478 pin chips were better than the standard heat sinks used today. However, this improvement was marginal (in the 10-20% better regime). However, another important note was that the epoxy bonding technique resulted in heat sinks with similar results as that with the S-bond{reg_sign}, slightly worse than the S

  5. Influence of gamma radiation in the mechanical properties of partially biodegradable foams of PP/HMSP blends with sugar cane bagasse

    International Nuclear Information System (INIS)

    Cardoso, Elizabeth C.L.; Scagliusi, Sandra R.; Mascarenha, Yago; Lugao, Ademar B.

    2015-01-01

    Polymers are used in various applications and in different market segments generating enormous amounts of wastes in environment. Among residues components in landfills are polymeric materials, as PP, contributing with 20 to 30% of total solids residues. As polymeric materials are immune to microbial degradation, remain in soil and in landfills as a semi-permanent residue. Environmental concerning toward residues reduction is nowadays directed to the development of renewable polymers for manufacturing of materials that degrade under environment, as biodegradable polymeric foams. High density structural foams are especially used in civil construction, replacing metals, woods and concrete, with a major purpose of materials cost reduction. This work aims to the study of biodegradability in PP/HMSPP blends with sugarcane bagasse at 10, 15, 30 and 50% further irradiated at 50, 100, 150 and 200 kGy doses. The biodegradability was assessed via Soil Burial Test. Tensile strength and elongation at break results proved that natural fibers reinforcement characteristic was not affected by gamma radiation, responsible by degradation and consequent biodegradability acceleration in structural foams. (author)

  6. Flexible Foam Model.

    Energy Technology Data Exchange (ETDEWEB)

    Neilsen, Michael K.; Lu, Wei-Yang; Werner, Brian T.; Scherzinger, William M.; Lo, Chi S.

    2018-03-01

    Experiments were performed to characterize the mechanical response of a 15 pcf flexible polyurethane foam to large deformation at different strain rates and temperatures. Results from these experiments indicated that at room temperature, flexible polyurethane foams exhibit significant nonlinear elastic deformation and nearly return to their original undeformed shape when unloaded. However, when these foams are cooled to temperatures below their glass transition temperature of approximately -35 o C, they behave like rigid polyurethane foams and exhibit significant permanent deformation when compressed. Thus, a new model which captures this dramatic change in behavior with temperature was developed and implemented into SIERRA with the name Flex_Foam to describe the mechanical response of both flexible and rigid foams to large deformation at a variety of temperatures and strain rates. This report includes a description of recent experiments. Next, development of the Flex Foam model for flexible polyurethane and other flexible foams is described. Selection of material parameters are discussed and finite element simulations with the new Flex Foam model are compared with experimental results to show behavior that can be captured with this new model.

  7. DISTRIBUTION OF HEAVY METALS AMONG THE COMPONENTS OF FRESHWATER ECOSYSTEMS (REVIEW

    Directory of Open Access Journals (Sweden)

    N. Kolesnyk

    2014-09-01

    Full Text Available Purpose. To review scientific sources on the distribution of heavy metals among the components of freshwater ecosystems. Findings. The review of the works of many scientists showed that heavy metals are widespread in the biotic and abiotic components of freshwater ecosystems. The article highlights the distribution of heavy metals in water, bottom sediments, natural food base, fish organs and tissues. It has been shown that as a result of global pollution of the ecosystem, the majority of Ukrainian rivers belong to polluted and very polluted. Of special interest are the studies of the distribution of heavy metals in phytoplankton, zooplankton, and zoobenthos because these components occupy a certain position in fish food chain. The presence of heavy metals in the natural food base showed that, on one hand, it could accumulate heavy metals in large amounts in such a way cleaning the water; and on the other hand, the heavy metals could migrate in the food web and contaminate fish. Ones of objects, which should be given attention when assessing toxicologic pollution, are aquatic plants, in particular phytoplankton. Studies showed that the accumulation of heavy metals in plants occurred first of all by their adsorption on the cellular wall. It explains the maximum adsorption of heavy metals by plants immediately after introduction of heavy metals into their culture. Fish as a rule occupy in the food web of water bodies one of the last places. They actively move in the aquatic environment and accumulating heavy metals at the same time they provide the most integrated and precise estimate of environmental pollution. By analyzing the distribution of heavy metals in fish organs and tissues, depending on their ability to accumulate them, it can be noted that the accumulation is the most intensive in such organs as gills, liver, and kidneys. Usually, their lowest content is observed in muscles that is important for human life because they are the main

  8. Fire-Retardant, Self-Extinguishing Inorganic/Polymer Composite Memory Foams.

    Science.gov (United States)

    Chatterjee, Soumyajyoti; Shanmuganathan, Kadhiravan; Kumaraswamy, Guruswamy

    2017-12-27

    Polymeric foams used in furniture and automotive and aircraft seating applications rely on the incorporation of environmentally hazardous fire-retardant additives to meet fire safety norms. This has occasioned significant interest in novel approaches to the elimination of fire-retardant additives. Foams based on polymer nanocomposites or based on fire-retardant coatings show compromised mechanical performance and require additional processing steps. Here, we demonstrate a one-step preparation of a fire-retardant ice-templated inorganic/polymer hybrid that does not incorporate fire-retardant additives. The hybrid foams exhibit excellent mechanical properties. They are elastic to large compressional strain, despite the high inorganic content. They also exhibit tunable mechanical recovery, including viscoelastic "memory". These hybrid foams are prepared using ice-templating that relies on a green solvent, water, as a porogen. Because these foams are predominantly comprised of inorganic components, they exhibit exceptional fire retardance in torch burn tests and are self-extinguishing. After being subjected to a flame, the foam retains its porous structure and does not drip or collapse. In micro-combustion calorimetry, the hybrid foams show a peak heat release rate that is only 25% that of a commercial fire-retardant polyurethanes. Finally, we demonstrate that we can use ice-templating to prepare hybrid foams with different inorganic colloids, including cheap commercial materials. We also demonstrate that ice-templating is amenable to scale up, without loss of mechanical performance or fire-retardant properties.

  9. Inflatable Tubular Structures Rigidized with Foams

    Science.gov (United States)

    Tinker, Michael L.; Schnell, Andrew R.

    2010-01-01

    Inflatable tubular structures that have annular cross sections rigidized with foams, and the means of erecting such structures in the field, are undergoing development. Although the development effort has focused on lightweight structural booms to be transported in compact form and deployed in outer space, the principles of design and fabrication are also potentially applicable to terrestrial structures, including components of ultralightweight aircraft, lightweight storage buildings and shelters, lightweight insulation, and sales displays. The use of foams to deploy and harden inflatable structures was first proposed as early as the 1960s, and has been investigated in recent years by NASA, the U.S. Air Force Research Laboratory, industry, and academia. In cases of deployable booms, most of the investigation in recent years has focused on solid cross sections, because they can be constructed relatively easily. However, solid-section foam-filled booms can be much too heavy for some applications. In contrast, booms with annular cross sections according to the present innovation can be tailored to obtain desired combinations of stiffness and weight through choice of diameters, wall thicknesses, and foam densities. By far the most compelling advantage afforded by this innovation is the possibility of drastically reducing weights while retaining or increasing the stiffnesses, relative to comparable booms that have solid foamfilled cross sections. A typical boom according to this innovation includes inner and outer polyimide film sleeves to contain foam that is injected between them during deployment.

  10. Aging of metal components in US nuclear reactors

    International Nuclear Information System (INIS)

    Mayfield, M.E.; Strosnider, J.R.

    1998-01-01

    This paper presents an overview of the aging of metal components in U.S. Light Water Reactors. The types of degradation being experienced in components such as the pressure vessel, piping, reactor internals, and steam generators, and the programs being implemented to manage the degradation are discussed. (author)

  11. PUR-PIR foam produced based on poly(hydroxybutyl citrate foamed founded with different factories

    Directory of Open Access Journals (Sweden)

    Liszkowska Joanna

    2018-03-01

    Full Text Available A poly(hydroxybutyl citrate p(HBC was obtained. The product compound produced in the solution during esterification, was added to rigid polyurethane-polyisocyanurate foams (PUR-PIR. The amount of petrochemical polyol in the foams was decreased in favor of the p(HBC from 0.1 to 0.5 equivalent. The foams were foamed in two ways: with distilled water (W foams and with Solkane 365/227 (S foams. The examination results of both foam series were compared. They showed that the foams foamed with water have higher softening temperature than the foams foamed with solkane. The retention values for both foam series are around 91–95%, and water absorption in the range of 0.7–3.2%. The anisotropy coefficient did not exceed 1.08 (the lowest value being 1.01.

  12. Infiltrated carbon foam composites

    Science.gov (United States)

    Lucas, Rick D. (Inventor); Danford, Harry E. (Inventor); Plucinski, Janusz W. (Inventor); Merriman, Douglas J. (Inventor); Blacker, Jesse M. (Inventor)

    2012-01-01

    An infiltrated carbon foam composite and method for making the composite is described. The infiltrated carbon foam composite may include a carbonized carbon aerogel in cells of a carbon foam body and a resin is infiltrated into the carbon foam body filling the cells of the carbon foam body and spaces around the carbonized carbon aerogel. The infiltrated carbon foam composites may be useful for mid-density ablative thermal protection systems.

  13. The correlation of local deformation and stress-assisted local phase transformations in MMC foams

    Energy Technology Data Exchange (ETDEWEB)

    Berek, H., E-mail: harry.berek@ikgb.tu-freiberg.de [TU Bergakademie Freiberg, Agricolastraße 17, D-09599 Freiberg (Germany); Ballaschk, U.; Aneziris, C.G. [TU Bergakademie Freiberg, Agricolastraße 17, D-09599 Freiberg (Germany); Losch, K.; Schladitz, K. [Fraunhofer ITWM, Fraunhoferplatz 1, D-67663 Kaiserslautern (Germany)

    2015-09-15

    Cellular structures are of growing interest for industry, and are of particular importance for lightweight applications. In this paper, a special case of metal matrix composite foams (MMCs) is investigated. The investigated foams are composed of austenitic steel exhibiting transformation induced plasticity (TRIP) and magnesia partially stabilized zirconia (Mg-PSZ). Both components exhibit martensitic phase transformation during deformation, thus generating the potential for improved mechanical properties such as strength, ductility, and energy absorption capability. The aim of these investigations was to show that stress-assisted phase transformations within the ceramic reinforcement correspond to strong local deformation, and to determine whether they can trigger martensitic phase transformations in the steel matrix. To this end, in situ interrupted compression experiments were performed in an X-ray computed tomography device (XCT). By using a recently developed registration algorithm, local deformation could be calculated and regions of interest could be defined. Corresponding cross sections were prepared and used to analyze the local phase composition by electron backscatter diffraction (EBSD). The results show a strong correlation between local deformation and phase transformation. - Graphical abstract: Display Omitted - Highlights: • In situ compressive deformation on MMC foams was performed in an XCT. • Local deformation fields and their gradient amplitudes were estimated. • Cross sections were manufactured containing defined regions of interest. • Local EBSD phase analysis was performed. • Local deformation and local phase transformation are correlated.

  14. The correlation of local deformation and stress-assisted local phase transformations in MMC foams

    International Nuclear Information System (INIS)

    Berek, H.; Ballaschk, U.; Aneziris, C.G.; Losch, K.; Schladitz, K.

    2015-01-01

    Cellular structures are of growing interest for industry, and are of particular importance for lightweight applications. In this paper, a special case of metal matrix composite foams (MMCs) is investigated. The investigated foams are composed of austenitic steel exhibiting transformation induced plasticity (TRIP) and magnesia partially stabilized zirconia (Mg-PSZ). Both components exhibit martensitic phase transformation during deformation, thus generating the potential for improved mechanical properties such as strength, ductility, and energy absorption capability. The aim of these investigations was to show that stress-assisted phase transformations within the ceramic reinforcement correspond to strong local deformation, and to determine whether they can trigger martensitic phase transformations in the steel matrix. To this end, in situ interrupted compression experiments were performed in an X-ray computed tomography device (XCT). By using a recently developed registration algorithm, local deformation could be calculated and regions of interest could be defined. Corresponding cross sections were prepared and used to analyze the local phase composition by electron backscatter diffraction (EBSD). The results show a strong correlation between local deformation and phase transformation. - Graphical abstract: Display Omitted - Highlights: • In situ compressive deformation on MMC foams was performed in an XCT. • Local deformation fields and their gradient amplitudes were estimated. • Cross sections were manufactured containing defined regions of interest. • Local EBSD phase analysis was performed. • Local deformation and local phase transformation are correlated

  15. Detection and Characterization of Flaws in Sprayed on Foam Insulation with Pulsed Terahertz Frequency Electromagnetic Waves

    Science.gov (United States)

    Winfree, William P.; Madaras, Eric I.

    2005-01-01

    The detection and repair of flaws such as voids and delaminations in the sprayed on foam insulation of the external tank reduces the probability of foam debris during shuttle ascent. The low density of sprayed on foam insulation along with it other physical properties makes detection of flaws difficult with conventional techniques. An emerging technology that has application for quantitative evaluation of flaws in the foam is pulsed electromagnetic waves at terahertz frequencies. The short wavelengths of these terahertz pulses make them ideal for imaging flaws in the foam. This paper examines the application of terahertz pulses for flaw detection in foam characteristic of the foam insulation of the external tank. Of particular interest is the detection of voids and delaminations, encapsulated in the foam or at the interface between the foam and a metal backing. The technique is shown to be capable of imaging small voids and delaminations through as much as 20 cm of foam. Methods for reducing the temporal responses of the terahertz pulses to improve flaw detection and yield quantitative characterizations of the size and location of the flaws are discussed.

  16. Fracture of metal foams : In-situ testing and numerical modeling

    NARCIS (Netherlands)

    Onck, P.R.; van Merkerk, R.; de Hosson, J.T.M.; Schmidt, I

    This paper is on a combined experimental/modeling study on the tensile fracture of open-cell foams. In-situ tensile tests show that individual struts can fail in a brittle or ductile mode, presumably depending on the presence of casting defects. In-situ single strut tests were performed, enabling

  17. Industrial Application of Open Pore Ceramic Foam for Molten Metal Filtration

    Science.gov (United States)

    Gauckler, L. J.; Waeber, M. M.; Conti, C.; Jacob-Dulière, M.

    Ceramic foam filters were used for industrial filtration of aluminum. Results are compared with laboratory experiments which are in good agreement with trajectory analyses of deep bed filtration for the early stage of filtration.

  18. Ultralight porous metals: From fundamentals to applications

    Science.gov (United States)

    Lu, Tianjian

    2002-10-01

    Over the past few years a number of low cost metallic foams have been produced and used as the core of sandwich panels and net shaped parts. The main aim is to develop lightweight structures which are stiff, strong, able to absorb large amount of energy and cheap for application in the transport and construction industries. For example, the firewall between the engine and passenger compartment of an automobile must have adequate mechanical strength, good energy and sound absorbing properties, and adequate fire retardance. Metal foams provide all of these features, and are under serious consideration for this applications by a number of automobile manufacturers (e.g., BMW and Audi). Additional specialized applications for foam-cored sandwich panels range from heat sinks for electronic devices to crash barriers for automobiles, from the construction panels in lifts on aircraft carriers to the luggage containers of aircraft, from sound proofing walls along railway tracks and highways to acoustic absorbers in lean premixed combustion chambers. But there is a problem. Before metallic foams can find a widespread application, their basic properties must be measured, and ideally modeled as a function of microstructural details, in order to be included in a design. This work aims at reviewing the recent progress and presenting some new results on fundamental research regarding the micromechanical origins of the mechanical, thermal, and acoustic properties of metallic foams.

  19. Ultralight porous metals. From fundamentals to applications

    International Nuclear Information System (INIS)

    Lu, T.

    2002-01-01

    Over the past few years a number of low cost metallic foams for application as the core of sandwich panels and net shaped parts have been produced. The main aim is to develop lightweight structures which are stiff, strong, absorb large amount of energy and are cheap, for application in the transport and construction industries. For example, the firewall between the engine and passenger compartment of an automobile must have adequate mechanical strength, good energy and sound absorbing properties, and adequate fire retardance. Metal foams provide all of these features, and are under serious scrutiny for this applications by a number of automobile manufacturers (e.g., BMW and Audi). Additional specialized applications for foam-cored sandwich panels range from heat sinks for electronic devices to crash barriers for automobiles, from the construction panels in lifts on aircraft carriers to the luggage containers of aircraft, from sound proofing walls along railway tracks and highways to acoustic absorbers in lean premixed combustion chambers. But there is a problem. Before metallic foams can find widespread application, their basic properties must be measured, and ideally modeled as a function of microstructural details, in order to give a design capability. This work aims at reviewing recent progress and present some new results on fundamental research regarding the micromechanical origins of the mechanical, thermal, and acoustic properties of metallic foams. (author)

  20. Dielectric and Radiative Properties of Sea Foam at Microwave Frequencies: Conceptual Understanding of Foam Emissivity

    OpenAIRE

    Peter W. Gaiser; Magdalena D. Anguelova

    2012-01-01

    Foam fraction can be retrieved from space-based microwave radiometric data at frequencies from 1 to 37 GHz. The retrievals require modeling of ocean surface emissivity fully covered with sea foam. To model foam emissivity well, knowledge of foam properties, both mechanical and dielectric, is necessary because these control the radiative processes in foam. We present a physical description of foam dielectric properties obtained from the foam dielectric constant including foam skin depth; foam ...

  1. Operator spin foam models

    International Nuclear Information System (INIS)

    Bahr, Benjamin; Hellmann, Frank; Kaminski, Wojciech; Kisielowski, Marcin; Lewandowski, Jerzy

    2011-01-01

    The goal of this paper is to introduce a systematic approach to spin foams. We define operator spin foams, that is foams labelled by group representations and operators, as our main tool. A set of moves we define in the set of the operator spin foams (among other operations) allows us to split the faces and the edges of the foams. We assign to each operator spin foam a contracted operator, by using the contractions at the vertices and suitably adjusted face amplitudes. The emergence of the face amplitudes is the consequence of assuming the invariance of the contracted operator with respect to the moves. Next, we define spin foam models and consider the class of models assumed to be symmetric with respect to the moves we have introduced, and assuming their partition functions (state sums) are defined by the contracted operators. Briefly speaking, those operator spin foam models are invariant with respect to the cellular decomposition, and are sensitive only to the topology and colouring of the foam. Imposing an extra symmetry leads to a family we call natural operator spin foam models. This symmetry, combined with assumed invariance with respect to the edge splitting move, determines a complete characterization of a general natural model. It can be obtained by applying arbitrary (quantum) constraints on an arbitrary BF spin foam model. In particular, imposing suitable constraints on a spin(4) BF spin foam model is exactly the way we tend to view 4D quantum gravity, starting with the BC model and continuing with the Engle-Pereira-Rovelli-Livine (EPRL) or Freidel-Krasnov (FK) models. That makes our framework directly applicable to those models. Specifically, our operator spin foam framework can be translated into the language of spin foams and partition functions. Among our natural spin foam models there are the BF spin foam model, the BC model, and a model corresponding to the EPRL intertwiners. Our operator spin foam framework can also be used for more general spin

  2. High temperature testing of TRUPACT-I materials: Kevlar, honeycomb, rigid polyurethane foam

    International Nuclear Information System (INIS)

    Hudson, M.L.

    1985-12-01

    When the Transuranic Package Transporter Model-I (TRUPACT-I) failed to afford sufficient containment after a 35-minute JP-4 fueled open-pool fire, component tests were conducted, in conjunction with analyses, to guide and assess the redesign of TRUPACT-I. Since materials which change phase or combust are difficult to numerically analyze, the component tests determined the behavior of these materials in TRUPACT-I. The component tests approximated the behavior of Kevlar (registered trademark of DuPont), metal honeycomb, and rigid polyurethane foam, as they appear in TRUPACT-I, in an open-pool fire environment. Six series of tests were performed at Sandia's Radiant Heat Facility and one test at the wind-shielded fire test facility (LAARC Chimney). Each test facility was controlled to yield temperatures or heat fluxes equivalent to those measured in the TRUPACT-I, Unit 0, open-pool fire. This extensive series of component tests (34 runs total) provided information on the high-temperature behavior of unique materials which was not previously available or otherwise attainable. The component tests were a timely and cost-effective means of providing the data for the TRUPACT-I redesign

  3. Foam films as thin liquid gas separation membranes.

    Science.gov (United States)

    Ramanathan, Muruganathan; Müller, Hans Joachim; Möhwald, Helmuth; Krastev, Rumen

    2011-03-01

    In this letter, we testify the feasibility of using freestanding foam films as a thin liquid gas separation membrane. Diminishing bubble method was used as a tool to measure the permeability of pure gases like argon, nitrogen, and oxygen in addition to atmospheric air. All components of the foam film including the nature of the tail (fluorocarbon vs hydrocarbon), charge on the headgroup (anionic, cationic, and nonionic) and the thickness of the water core (Newton black film vs Common black film) were systematically varied to understand the permeation phenomena of pure gases. Overall results indicate that the permeability values for different gases are in accordance with magnitude of their molecular diameter. A smaller gaseous molecule permeates faster than the larger ones, indicating a new realm of application for foam films as size selective separation membranes.

  4. Urethane foam void filling. Innovative technology summary report

    International Nuclear Information System (INIS)

    1998-12-01

    Under the decontamination and decommissioning (D and D) Implementation Plan of the United States Department of Energy's (DOE's) Fernald Environmental Management Project (FEMP), non-recyclable process components and debris that are removed from buildings undergoing D and D are disposed of in an on-site disposal facility (OSDF). Critical to the design and operation of the FEMP's OSDF are provisions to protect against subsidence of the OSDF's cap. Subsidence of the cap could occur if void spaces within the OSDF were to collapse under the overburden of debris and the OSDF cap. Subsidence may create depressions in the OSDF's cap in which rainwater could collect and eventually seep into the OSDF. To minimize voids in the FEMP's OSDF, large metallic components are cut into smaller segments that can be arranged more compactly when placed in the OSDF. Component segmentation using an oxy-acetylene torch was the baseline approach used by the FEMP's D and D contractor on Plant 1, B and W Services, Inc., for the dismantlement and size-reduction of large metal components. Although this technology has performed satisfactorily, it is time-consuming, labor-intensive and costly. Use of the oxy-acetylene torch exposes workers to health and safety hazards including the risk of burns, carbon monoxide, and airborne contamination of residual lead-based paints and other contaminants on the surface of the components being segmented. In addition, solvents used to remove paint from the components before segmenting them emit flammable, noxious fumes. This demonstration investigated the feasibility of placing large vessels intact in the OSDF without segmenting them. To prevent the walls of the vessels from collapsing under the overburden or from degradation, an innovative approach was employed which involved filling the voids in the vessels with a fluid material that hardened on standing. The hardened filling would support the walls of the vessels, and prevent them from collapsing. This report

  5. Mechanical characterization of hybrid and functionally-graded aluminum open-cell foams with nanocrystalline-copper coatings

    Science.gov (United States)

    Sun, Yi

    Cellular/foam materials found in nature such as bone, wood, and bamboo are usually functionally graded by having a non-uniform density distribution and inhomogenous composition that optimizes their global mechanical performance. Inspired by such naturally engineered products, the current study was conducted towards the development of functionally graded hybrid metal foams (FGHMF) with electrodeposited (ED) nanocrystalline coatings. First, the deformation and failure mechanisms of aluminum/copper (Al/Cu) hybrid foams were investigated using finite element analyses at different scales. The micro-scale behavior was studied based on single ligament models discretized using continuum elements and the macro-scale behavior was investigated using beam-element based finite element models of representative unit volumes consisting of multiple foam cells. With a detailed constitutive material behavior and material failure considered for both the aluminum ligament and the nano-copper coating, the numerical models were able to capture the unique behavior of Al/Cu hybrid foams, such as the typically observed sudden load drop after yielding. The numerical models indicate that such load drop is caused by the fracture of foam ligaments initiated from the rupture of the ED nano-copper coating due to its low ductility. This failure mode jeopardizes the global energy absorption capacity of hybrid foams, especially when a thick coating is applied. With the purpose of enhancing the performance of Al/Cu hybrid foams, an annealing process, which increased the ductility of the nanocrystalline copper coating by causing recovery, recrystallination and grain growth, was introduced in the manufacturing of Al/Cu hybrid foams. Quasi-static experimental results indicate that when a proper amount of annealing is applied, the ductility of the ED copper can be effectively improved and the compressive and tensile behavior of Al/Cu hybrid foams can be significantly enhanced, including better energy

  6. DISTRIBUTION OF HEAVY METALS AMONG THE COMPONENTS OF FRESHWATER ECOSYSTEMS (REVIEW)

    OpenAIRE

    N. Kolesnyk

    2014-01-01

    Purpose. To review scientific sources on the distribution of heavy metals among the components of freshwater ecosystems. Findings. The review of the works of many scientists showed that heavy metals are widespread in the biotic and abiotic components of freshwater ecosystems. The article highlights the distribution of heavy metals in water, bottom sediments, natural food base, fish organs and tissues. It has been shown that as a result of global pollution of the ecosystem, the majority of...

  7. Foam engineering fundamentals and applications

    CERN Document Server

    2012-01-01

    Containing contributions from leading academic and industrial researchers, this book provides a much needed update of foam science research. The first section of the book presents an accessible summary of the theory and fundamentals of foams. This includes chapters on morphology, drainage, Ostwald ripening, coalescence, rheology, and pneumatic foams. The second section demonstrates how this theory is used in a wide range of industrial applications, including foam fractionation, froth flotation and foam mitigation. It includes chapters on suprafroths, flotation of oil sands, foams in enhancing petroleum recovery, Gas-liquid Mass Transfer in foam, foams in glass manufacturing, fire-fighting foam technology and consumer product foams.

  8. Foam, composition and method of production

    Energy Technology Data Exchange (ETDEWEB)

    Ghali, R.

    1991-09-03

    A ternary foam is disclosed which overcomes the disadvantages of conventional heat-insulating foams which are either dense and heavy, expensive to produce, friable, unstable, or have poor fire resistance. The foam of the invention has, by weight of the reaction product, 10-35% polyurethane, 30-55% polyisocyanurate, and 20-45% polyurea. The foam is a reaction product of 100 parts by weight of an organic polyisocyanate with: 15-25 parts by weight of a polyether polyol having a hydroxyl number of ca 28-35 and a molecular weight of not more than 6,000; 5-25 parts by weight of water; 0-25 parts by weight of a blowing agent; 0-50 parts by weight of a filler-plasticizer fire retardant; an effective amount of a low activation catalyst to initiate water-isocyanate reaction to produce polyurea and polyol-isocyanate reaction to produce polyurethane; and an effective amount of a high activation catalyst to retard the low activation catalyst and promote the formation of polyisocyanurate. The low activity catalyst is present in an amount ranging ca 1.5-9 parts per 100 parts by weight of the polyisocyanate, and the high activation catalyst is present in an amount ranging 0.0008-0.002 parts per 100 parts by weight of the polyisocyanate. Water as a reactant and blowing agent can be substituted by an effective amount of a disubstituted amine such as diethanol amine and an inert blowing agent such as fluorocarbon. The resultant foam has excellent heat insulating propeties, is semi-flexible, has a density of 0.5-0.9 lb/ft{sup 3}, and can be inexpensively produced by existing 2-component foam dispensing equipment. 1 fig., 1 tab.

  9. Foams theory, measurements, and applications

    CERN Document Server

    Khan, Saad A

    1996-01-01

    This volume discusses the physics and physical processes of foam and foaming. It delineates various measurement techniques for characterizing foams and foam properties as well as the chemistry and application of foams. The use of foams in the textile industry, personal care products, enhanced oil recovery, firefighting and mineral floatation are highlighted, and the connection between the microstructure and physical properties of foam are detailed. Coverage includes nonaqueous foams and silicone antifoams, and more.

  10. Biodegradable polymeric foam with food waste; Shokumotsu zansa wo mochiita seibunkai kobunshi hahhotai

    Energy Technology Data Exchange (ETDEWEB)

    Mishima, Kenji; Matsuyama, Kiyoshi; Yamauchi, Satoru; Takarabe, Shin' ichi

    1999-09-01

    A huge amount of food waste such as tea and beer dregs becomes a serious problem because of the lack of industrial waste space in Japan. On the other hand, the new polymeric foam is expected to be developed since the dangerous pollution of endorphin disrupters from industrial polymer foam is pointed out. In this work, we try to develop the biodegradable polymeric foam using the tea and beer dregs as secondary resources. And we examined the degradability of biodegradable polymer in the hydrothermal water for fundamental knowledge of polymeric foam production. We used an extruder equipped with a high pressure device to make the polymeric foam. And we examined the effect of the component ratio on the foam properties, foaming rate, strength, shrinkage rate, water-resistant. As a result, it was found that the amount of polymer is effective of quality of form and the biodegradability can be controlled by the amount of water and temperature. (author)

  11. 1-D Van der Waals Foams Heated by Ion Beam Energy Deposition

    International Nuclear Information System (INIS)

    Zylstra, A.B.; Barnard, J.J.; More, R.M.

    2009-01-01

    One dimensional simulations of various initial average density aluminum foams (modeled as slabs of solid metal separated by low density regions) heated by volumetric energy deposition are conducted with a Lagrangian hydrodynamics code using a van der Waals equation of tate (EOS). The resulting behavior is studied to facilitate the design of future warm dense matter (WDM) experiments at LBNL. In the simulations the energy deposition ranges from 10 to 30 kJ/g and from 0.075 to 4.0 ns total pulse length, resulting in temperatures from approximately 1 o 4 eV. We study peak pressures and temperatures in the foams, expansion velocity, and the phase evolution. Five relevant time scales in the problem are identified. Additionally, we present a method for characterizing the level of inhomogeneity in a foam target as it is heated and the time it takes for a foam to homogenize.

  12. Selective extraction of metals from products of mine acidic water treatment

    International Nuclear Information System (INIS)

    Andreeva, N.N.; Romanchuk, S.A.; Voronin, N.N.; Demidov, V.D.; Pasynkova, T.A.; Manuilova, O.A.; Ivanova, N.V.

    1989-01-01

    A study was made on possibility of processing of foam products prepared during flotation purification of mine acidic waters for the purpose of selective extraction of non-ferrous (Co, Ni) and rare earth elements (REE) and their separation from the basic macrocomponent of waters-iron. Optimal conditions of selective metal extraction from foam flotation products are the following: T=333 K, pH=3.0-3.5, ratio of solid and liquid phase - 1:4-1:7, duration of sulfuric acid leaching - 30 min. Rare earth extraction under such conditions equals 87.6-93.0%. The degree of valuable component concentration equals ∼ 10. Rare earths are separated from iron by extraction methods

  13. 3D Graphene-Ni Foam as an Advanced Electrode for High-Performance Nonaqueous Redox Flow Batteries.

    Science.gov (United States)

    Lee, Kyubin; Lee, Jungkuk; Kwon, Kyoung Woo; Park, Min-Sik; Hwang, Jin-Ha; Kim, Ki Jae

    2017-07-12

    Electrodes composed of multilayered graphene grown on a metal foam (GMF) were prepared by directly growing multilayer graphene sheets on a three-dimensional (3D) Ni-foam substrate via a self-catalyzing chemical vapor deposition process. The multilayer graphene sheets are successfully grown on the Ni-foam substrate surface, maintaining the unique 3D macroporous structure of the Ni foam. The potential use of GMF electrodes in nonaqueous redox flow batteries (RFBs) is carefully examined using [Co(bpy) 3 ] +/2+ and [Fe(bpy) 3 ] 2+/3+ redox couples. The GMF electrodes display a much improved electrochemical activity and enhanced kinetics toward the [Co(bpy) 3 ] +/2+ (anolyte) and [Fe(bpy) 3 ] 2+/3+ (catholyte) redox couples, compared with the bare Ni metal foam electrodes, suggesting that the 2D graphene sheets having lots of interdomain defects provide sufficient reaction sites and secure electric-conduction pathways. Consequently, a nonaqueous RFB cell assembled with GMF electrodes exhibits high Coulombic and voltage efficiencies of 87.2 and 90.9%, respectively, at the first cycle. This performance can be maintained up to the 50th cycle without significant efficiency loss. Moreover, the importance of a rational electrode design for improving electrochemical performance is addressed.

  14. Starch/fiber/poly(lactic acid) foam and compressed foam composites

    Science.gov (United States)

    Composites of starch, fiber, and poly(lactic acid) (PLA) were made using a foam substrate formed by dehydrating starch or starch/fiber gels. PLA was infiltrated into the dry foam to provide better moisture resistance. Foam composites were compressed into plastics using force ranging from 4-76MPa. Te...

  15. Nickel foam-supported polyaniline cathode prepared with electrophoresis for improvement of rechargeable Zn battery performance

    Science.gov (United States)

    Xia, Yang; Zhu, Derong; Si, Shihui; Li, Degeng; Wu, Sen

    2015-06-01

    Porous nickel foam is used as a substrate for the development of rechargeable zinc//polyaniline battery, and the cathode electrophoresis of PANI microparticles in non-aqueous solution is applied to the fabrication of Ni foam supported PANI electrode, in which the corrosion of the nickel foam substrate is prohibited. The Ni foam supported PANI cathode with high loading is prepared by PANI electrophoretic deposition, and followed by PANI slurry casting under vacuum filtration. The electrochemical charge storage performance for PANI material is significantly improved by using nickel foam substrate via the electrophoretic interlayer. The specific capacity of the nickel foam-PANI electrode with the electrophoretic layer is higher than the composite electrode without the electrophoretic layer, and the specific capacity of PANI supported by Ni foam reaches up to 183.28 mAh g-1 at the working current of 2.5 mA cm-2. The present electrophoresis deposition method plays the facile procedure for the immobilization of PANI microparticles onto the surface of non-platinum metals, and it becomes feasible to the use of the Ni foam supported PANI composite cathode for the Zn/PANI battery in weak acidic electrolyte.

  16. Effects of SiC and MgO on aluminabased ceramic foams filters

    OpenAIRE

    CAO Da-li; ZHOU Jing-yi; JIN Yong-ming

    2007-01-01

    Alumina-based foam ceramic filters were fabricated by using alumina, SiC, magnesia powder as major materials. It has been found that this ceramic filter has a uniform macrostructure for filtering molten metals. The influences of SiC and magnesia content, the sintering temperatures on ceramic properties were discussed. Aluminabased foam ceramic filters containing 2.2 mass% magnesia and 7.6 mass% SiC has a compressive strength of 1.36 MPa and a thermal shock resistance of 5 times. Its main phas...

  17. Removal of trace Cd2+ from aqueous solution by foam fractionation.

    Science.gov (United States)

    Lu, Jian; Li, Ying; Zhang, Sen; Sun, Yange

    2015-04-09

    In recent years, aqueous foam was known as an efficient technique with high potential on being used to remove heavy metal ions from the polluted water, not only because of the low cost, simple operation, but also ascribed to the high removal efficiency of trace heavy metal ions and would not cause secondary pollution to the environment. In this paper, the removal of Cd(2+) from aqueous solution by aqueous foam stabilized by a kind of novel anionic-nonionic surfactant sodium trideceth-4 carboxylate (AEC) was investigated. The effect of conditions such as surfactant/metal ions molar ratio, surfactant concentration on the removal efficiency was studied. In large concentration range of surfactant, the removal rate was higher than 90%, and could reach up to 99.8% under the optimum conditions. The Zeta potential of gas bubbles in the AEC solutions was determined to verify the combination between the negative charged group heads of surfactant molecules and heavy metal ions, and isothermal titration calorimeter (ITC) determination was utilized to demonstrate the interaction, which helped to understand the mechanisms more clearly. Copyright © 2015 Elsevier B.V. All rights reserved.

  18. Preparation and Characterization of Metal Soaps of Cocos nucifera ...

    African Journals Online (AJOL)

    This study investigated the extraction of Cocos nucifera seed oil (CSO) from Cocos nucifera seed using aqueous processing and the production of metal soaps from the oil and their characterization in terms of colour, pH, free caustic alkalinity, foaming power, foam stability, and corrosion inhibition test. The metal soaps of the ...

  19. Foaming Index of CaO-SiO2-FeO-MgO Slag System

    Science.gov (United States)

    Park, Youngjoo; Min, Dong Joon

    A study on the effect of FeO and MgO content on foaming index in EAF slag system was carried out. The height of the slag foam was measured by electric probe maintaining steady state in gas formation and escape. Foaming index, which is the measurement of gas capturing potential of the slag, is calculated from the foam height and gas flow rate. Viscosity and surface tension, which are the key properties for the foaming index, are calculated by Urbain's model and additive method, respectively. Dimensional analysis also performed to determine the dominancy of properties and resulted that the important factor was a ratio between viscosity and surface tension. The effect of each component on the viscosity, surface tension and foaming index of the slag is evaluated to be in strong relationship.

  20. Thermal aging of traditional and additively manufactured foams: analysis by time-temperature-superposition, constitutive, and finite-element models

    Energy Technology Data Exchange (ETDEWEB)

    Maiti, A. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Weisgraber, T. H. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Small, W. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Lewicki, J. P. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Duoss, E. B. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Spadaccini, C. M. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Pearson, M. A. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Chinn, S. C. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Wilson, T. S. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Maxwell, R. S. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

    2016-12-08

    Cellular solids or foams are a very important class of materials with diverse applications ranging from thermal insulation and shock absorbing support cushions, to light-weight structural and floatation components, and constitute crucial components in a large number of industries including automotive, aerospace, electronics, marine, biomedical, packaging, and defense. In many of these applications the foam material is subjected to long periods of continuous stress, which can, over time, lead to a permanent change in structure and a degradation in performance. In this report we summarize our modeling efforts to date on polysiloxane foam materials that form an important component in our systems. Aging of the materials was characterized by two measured quantities, i.e., compression set and load retention. Results of accelerated aging experiments were analyzed by an automated time-temperaturesuperposition (TTS) approach, which creates a master curve that can be used for long-term predictions (over decades) under ambient conditions. When comparing such master curves for traditional (stochastic) foams with those for recently 3D-printed (i.e., additively manufactured, or AM) foams, it became clear that AM foams have superior aging behavior. To gain deeper understanding, we imaged the microstructure of both foams using X-ray computed tomography, and performed finite-element analysis of the mechanical response within these microstructures. This indicates a wider stress variation in the stochastic foam with points of more extreme local stress as compared to the 3D printed material.

  1. Redox reaction and foaming in nuclear waste glass melting

    Energy Technology Data Exchange (ETDEWEB)

    Ryan, J.L.

    1995-08-01

    This document was prepared by Pacific Northwest Laboratory (PNL) and is an attempt to analyze and estimate the effects of feed composition variables and reducing agent variables on the expected chemistry of reactions occurring in the cold cap and in the glass melt in the nuclear waste glass Slurry-fed, joule-heated melters as they might affect foaming during the glass-making process. Numerous redox reactions of waste glass components and potential feed additives, and the effects of other feed variables on these reactions are reviewed with regard to their potential effect on glass foaming. A major emphasis of this report is to examine the potential positive or negative aspects of adjusting feed with formic acid as opposed to other feed modification techniques including but not limited to use of other reducing agents. Feed modification techniques other than the use of reductants that should influence foaming behavior include control of glass melter feed pH through use of nitric acid. They also include partial replacement of sodium salts by lithium salts. This latter action (b) apparently lowers glass viscosity and raises surface tension. This replacement should decrease foaming by decreasing foam stability.

  2. Multifunctional foaming agent to prepare aluminum foam with enhanced mechanical properties

    Science.gov (United States)

    Li, Xun; Liu, Ying; Ye, Jinwen; An, Xuguang; Ran, Huaying

    2018-03-01

    In this paper, CuSO4 was used as foaming agent to prepare close cell Aluminum foam(Al foam) at the temperature range of 680 °C ∼ 758 °C for the first time. The results show that CuSO4 has multifunctional such as, foaming, viscosity increasing, reinforcement in Al matrix, it has a wide decomposition temperature range of 641 °C ∼ 816 °C, its sustain-release time is 5.5 min at 758 °C. The compression stress and energy absorption of CuSO4-Al foam is 6.89 Mpa and 4.82 × 106 J m‑3(compression strain 50%), which are 77.12% and 99.17% higher than that of TiH2-Al foam at the same porosity(76% in porosity) due to the reinforcement in Al matrix and uniform pore dispersion.

  3. Sheet-bulk metal forming – forming of functional components from sheet metals

    Directory of Open Access Journals (Sweden)

    Merklein Marion

    2015-01-01

    Full Text Available The paper gives an overview on the application of sheet-bulk metal forming operations in both scientific and industrial environment. Beginning with the need for an innovative forming technology, the definition of this new process class is introduced. The rising challenges of the application of bulk metal forming operations on sheet metals are presented and the demand on a holistic investigation of this topic is motivated. With the help of examples from established production processes, the latest state of technology and the lack on fundamental knowledge is shown. Furthermore, perspectives regarding new research topics within sheet-bulk metal forming are presented. These focus on processing strategies to improve the quality of functional components by the application of process-adapted semi-finished products as well as the local adaption of the tribological system.

  4. Foaming of CRT panel glass powder using Na2CO3

    DEFF Research Database (Denmark)

    Petersen, Rasmus Rosenlund; König, Jakob; Smedskjær, Morten Mattrup

    2014-01-01

    The recycling of glass from obsolete cathode ray tubes (CRT) has hitherto only occurred to a very limited extent, but the production of foam glass used as an insulation material component has recently been proposed as a promising recycling method. CRT panel glass has high recycling potential due...... to its non-hazardous composition. Here we report on the foaming of CRT panel glass using Na2CO3 as the foaming agent. We explore how heat treatment temperature and concentration of Na2CO3 affect the density and porosity of the foam glasses, and whether Na2O is incorporated in the glass network....... The optimum foaming temperature for minimising density and maximising closed porosity is found to be between 1023 and 1123 K. The pore structure depends on the amount of added Na2CO3, viz, the pores generally become more open with increasing Na2CO3 content. A minimum density of 0·28 g/cm3 is found when 14 wt...

  5. Preparation of three-dimensional shaped aluminum alloy foam by two-step foaming

    International Nuclear Information System (INIS)

    Shang, J.T.; Xuming, Chu; Deping, He

    2008-01-01

    A novel method, named two-step foaming, was investigated to prepare three-dimensional shaped aluminum alloy foam used in car industry, spaceflight, packaging and related areas. Calculations of thermal decomposition kinetics of titanium hydride showed that there is a considerable amount of hydrogen releasing when the titanium hydride is heated at a relatively high temperature after heated at a lower temperature. The hydrogen mass to sustain aluminum alloy foam, having a high porosity, was also estimated by calculations. Calculations indicated that as-received titanium hydride without any pre-treatment can be used as foaming agents in two-step foaming. The processes of two-step foaming, including preparing precursors and baking, were also studied by experiments. Results showed that, low titanium hydride dispersion temperature, long titanium hydride dispersion time and low precursors porosity are beneficial to prepare three-dimensional shaped aluminum alloy foams with uniform pores

  6. Hydroxyapatite fiber reinforced poly(alpha-hydroxy ester) foams for bone regeneration

    Science.gov (United States)

    Thomson, R. C.; Yaszemski, M. J.; Powers, J. M.; Mikos, A. G.; McIntire, L. V. (Principal Investigator)

    1998-01-01

    A process has been developed to manufacture biodegradable composite foams of poly(DL-lactic-co-glycolic acid) (PLGA) and hydroxyapatite short fibers for use in bone regeneration. The processing technique allows the manufacture of three-dimensional foam scaffolds and involves the formation of a composite material consisting of a porogen material (either gelatin microspheres or salt particles) and hydroxyapatite short fibers embedded in a PLGA matrix. After the porogen is leached out, an open-cell composite foam remains which has a pore size and morphology defined by the porogen. By changing the weight fraction of the leachable component it was possible to produce composite foams with controlled porosities ranging from 0.47 +/- 0.02 to 0.85 +/- 0.01 (n = 3). Up to a polymer:fiber ratio of 7:6, short hydroxyapatite fibers served to reinforce low-porosity PLGA foams manufactured using gelatin microspheres as a porogen. Foams with a compressive yield strength up to 2.82 +/- 0.63 MPa (n = 3) and a porosity of 0.47 +/- 0.02 (n = 3) were manufactured using a polymer:fiber weight ratio of 7:6. In contrast, high-porosity composite foams (up to 0.81 +/- 0.02, n = 3) suitable for cell seeding were not reinforced by the introduction of increasing quantities of hydroxyapatite short fibers. We were therefore able to manufacture high-porosity foams which may be seeded with cells but which have minimal compressive yield strength, or low porosity foams with enhanced osteoconductivity and compressive yield strength.

  7. Thermal performance enhancement of erythritol/carbon foam composites via surface modification of carbon foam

    Science.gov (United States)

    Li, Junfeng; Lu, Wu; Luo, Zhengping; Zeng, Yibing

    2017-03-01

    The thermal performance of the erythritol/carbon foam composites, including thermal diffusivity, thermal capacity, thermal conductivity and latent heat, were investigated via surface modification of carbon foam using hydrogen peroxide as oxider. It was found that the surface modification enhanced the wetting ability of carbon foam surface to the liquid erythritol of the carbon foam surface and promoted the increase of erythritol content in the erythritol/carbon foam composites. The dense interfaces were formed between erythritol and carbon foam, which is due to that the formation of oxygen functional groups C=O and C-OH on the carbon surface increased the surface polarity and reduced the interface resistance of carbon foam surface to the liquid erythritol. The latent heat of the erythritol/carbon foam composites increased from 202.0 to 217.2 J/g through surface modification of carbon foam. The thermal conductivity of the erythritol/carbon foam composite before and after surface modification further increased from 40.35 to 51.05 W/(m·K). The supercooling degree of erythritol also had a large decrease from 97 to 54 °C. Additionally, the simple and effective surface modification method of carbon foam provided an extendable way to enhance the thermal performances of the composites composed of carbon foams and PCMs.

  8. Foam-oil interaction in porous media: implications for foam assisted enhanced oil recovery.

    Science.gov (United States)

    Farajzadeh, R; Andrianov, A; Krastev, R; Hirasaki, G J; Rossen, W R

    2012-11-15

    The efficiency of a foam displacement process in enhanced oil recovery (EOR) depends largely on the stability of foam films in the presence of oil. Experimental studies have demonstrated the detrimental impact of oil on foam stability. This paper reviews the mechanisms and theories (disjoining pressure, coalescence and drainage, entering and spreading of oil, oil emulsification, pinch-off, etc.) suggested in the literature to explain the impact of oil on foam stability in the bulk and porous media. Moreover, we describe the existing approaches to foam modeling in porous media and the ways these models describe the oil effect on foam propagation in porous media. Further, we present various ideas on an improvement of foam stability and longevity in the presence of oil. The outstanding questions regarding foam-oil interactions and modeling of these interactions are pointed out. Copyright © 2012 Elsevier B.V. All rights reserved.

  9. Application of La-Doped SrTiO3 in Advanced Metal-Supported Solid Oxide Fuel Cells

    Directory of Open Access Journals (Sweden)

    Sabrina Presto

    2018-03-01

    Full Text Available Composite materials frequently allow the drawbacks of single components to be overcome thanks to a synergistic combination of material- and structure-specific features, leading to enhanced and also new properties. This is the case of a metallic-ceramic composite, a nickel-chromium-aluminum (NiCrAl foam impregnated with La-doped Strontium Titanate (LST. This particular cermet has very interesting properties that can be used in different fields of application, namely: mechanical robustness provided by the metal foam; and chemical stability in harsh conditions of temperature and atmosphere by promotion of a thin protective layer of alumina (Al2O3; high electronic conductivity given by a percolating ceramic conducting phase, i.e., La-doped Strontium Titanate. In this paper, its application as a current collector in a metal-supported Solid Oxide Fuel Cells (SOFC was studied. Firstly, the electronic properties of different compositions, stoichiometric and under stoichiometric, of LST were analyzed to choose the best one in terms of conductivity and phase purity. Then, LST chemical stability was studied in the presence of Al2O3 at different temperatures, gas compositions and aging times. Finally, stability and conductivity of LST-impregnated NiCrAl foam composite materials were measured, and LST was found to be fully compatible with the NiCrAl foam, as no reactions were detected in oxidizing and reducing atmosphere after up to 300 h operation at 750 °C and 900 °C between the Al2O3 layer and LST. Results showed that the composite is suitable as a current collector in innovative designs of metal-supported SOFC, like the Evolve cell, in which the metallic part is supposed not only to provide the structural stability to the cell, but also to play the role of current collector due to the impregnation of ceramic material.

  10. Technical characteristics of rigid sprayed PUR and PIR foams used in construction industry

    Science.gov (United States)

    Gravit, Marina; Kuleshin, Aleksey; Khametgalieva, Elina; Karakozova, Irina

    2017-10-01

    The article describes the distinctive properties of rigid polyurethane foam and polyisocyanurate (PUR and PIR). A brief review of the research was carried out on their modification with an objective to improve the thermal insulation properties and reducing the combustibility. A comparative analysis of the technical characteristics of rigid PUR and PIR foams of various manufacturers is presented. The problems of the state of the market for the production of polyurethane foam and polyisocyanurate in Russia have been marked. It is established that the further development of the fabrication technology of heat-insulating sprayed rigid PUR and PIR foams requires uniformity of technical characteristics of original components and finished products. Moreover, it requires the creation of unified information base for raw materials and auxiliary materials used in the production of PUR and PIR foam.

  11. Method of forming a continuous polymeric skin on a cellular foam material

    Science.gov (United States)

    Duchane, David V.; Barthell, Barry L.

    1985-01-01

    Hydrophobic cellular material is coated with a thin hydrophilic polymer skin which stretches tightly over the outer surface of the foam but which does not fill the cells of the foam, thus resulting in a polymer-coated foam structure having a smoothness which was not possible in the prior art. In particular, when the hydrophobic cellular material is a specially chosen hydrophobic polymer foam and is formed into arbitrarily chosen shapes prior to the coating with hydrophilic polymer, inertial confinement fusion (ICF) targets of arbitrary shapes can be produced by subsequently coating the shapes with metal or with any other suitable material. New articles of manufacture are produced, including improved ICF targets, improved integrated circuits, and improved solar reflectors and solar collectors. In the coating method, the cell size of the hydrophobic cellular material, the viscosity of the polymer solution used to coat, and the surface tensin of the polymer solution used to coat are all very important to the coating.

  12. Mechanical properties and impact behavior of a microcellular structural foam

    Directory of Open Access Journals (Sweden)

    M. Avalle

    Full Text Available Structural foams are a relatively new class of materials with peculiar characteristics that make them very attractive in some energy absorption applications. They are currently used for packaging to protect goods from damage during transportation in the case of accidental impacts. Structural foams, in fact, have sufficient mechanical strength even with reduced weight: the balance between the two antagonist requirements demonstrates that these materials are profitable. Structural foams are generally made of microcellular materials, obtained by polymers where voids at the microscopic level are created. Although the processing technologies and some of the material properties, including mechanical, are well known, very little is established for what concerns dynamic impact properties, for the design of energy absorbing components made of microcellular foams. The paper reports a number of experimental results, in different loading conditions and loading speed, which will be a basis for the structural modeling.

  13. Carbon particle induced foaming of molten sucrose for the preparation of carbon foams

    International Nuclear Information System (INIS)

    Narasimman, R.; Vijayan, Sujith; Prabhakaran, K.

    2014-01-01

    Graphical abstract: - Highlights: • An easy method for the preparation of carbon foam from sucrose is presented. • Wood derived activated carbon particles are used to stabilize the molten sucrose foam. • The carbon foams show relatively good mechanical strength. • The carbon foams show excellent CO 2 adsorption and oil absorption properties. • The process could be scaled up for the preparation of large foam bodies. - Abstract: Activated carbon powder was used as a foaming and foam setting agent for the preparation of carbon foams with a hierarchical pore structure from molten sucrose. The rheological measurements revealed the interruption of intermolecular hydrogen bonding in molten sucrose by the carbon particles. The carbon particles stabilized the bubbles in molten sucrose by adsorbing on the molten sucrose–gas interface. The carbon foams obtained at the activated carbon powder to sucrose weight ratios in the range of 0–0.25 had a compressive strength in the range of 1.35–0.31 MPa. The produced carbon foams adsorb 2.59–3.04 mmol/g of CO 2 at 760 mmHg at 273 K and absorb oil from oil–water mixtures and surfactant stabilized oil-in-water emulsions with very good selectivity and recyclability

  14. THERMOLYSIS OF FOAM PRODUCTS FORMED AT THE FLOTATION EXTRACTION OF COPPER AND NICKEL IONS BY HELP OF WAX PEAT

    Directory of Open Access Journals (Sweden)

    V. F. Sazonova

    2015-02-01

    Full Text Available There thermogravimetric study of foam product at the flotation extraction of cop­per and nickel ions by wax peat results are described. It shown that oxidizing roasting of foam products (i.e. hydrated soaps of polyvalent metals proceeds in several steps. At the first step (t<100 °С dehydration takes place. At the next ones (t=160^665 °С The thermic destruction and burning of organic compounds occurs. The residue is the of metal oxides.

  15. State-of-the-Art Review on the Characteristics of Surfactants and Foam from Foam Concrete Perspective

    Science.gov (United States)

    Sahu, Sritam Swapnadarshi; Gandhi, Indu Siva Ranjani; Khwairakpam, Selija

    2018-06-01

    Foam concrete finds application in many areas, generally as a function of its relatively lightweight and its beneficial properties in terms of reduction in dead load on structure, excellent thermal insulation and contribution to energy conservation. For production of foam concrete with desired properties, stable and good quality foam is the key requirement. It is to be noted that the selection of surfactant and foam production parameters play a vital role in the properties of foam which in turn affects the properties of foam concrete. However, the literature available on the influence of characteristics of foaming agent and foam on the properties of foam concrete are rather limited. Hence, a more systematic research is needed in this direction. The focus of this work is to provide a review on characteristics of surfactant (foaming agent) and foam for use in foam concrete production.

  16. Design and Measurement of Metallic Post-Wall Waveguide Components

    NARCIS (Netherlands)

    Coenen, T.J.; Bekers, D.J.; Tauritz, J.L.; Vliet, F.E. van

    2009-01-01

    Abstract—In this paper we discuss the design and measurement of a set of metallic post-wall waveguide components for antenna feed structures. The components are manufactured on a single layer printed circuit board and excited by a grounded coplanar waveguide. For a straight transmission line, a 90°

  17. Drop Weight Impact Behavior of Al-Si-Cu Alloy Foam-Filled Thin-Walled Steel Pipe Fabricated by Friction Stir Back Extrusion

    Science.gov (United States)

    Hangai, Yoshihiko; Nakano, Yukiko; Utsunomiya, Takao; Kuwazuru, Osamu; Yoshikawa, Nobuhiro

    2017-02-01

    In this study, Al-Si-Cu alloy ADC12 foam-filled thin-walled stainless steel pipes, which exhibit metal bonding between the ADC12 foam and steel pipe, were fabricated by friction stir back extrusion. Drop weight impact tests were conducted to investigate the deformation behavior and mechanical properties of the foam-filled pipes during dynamic compression tests, which were compared with the results of static compression tests. From x-ray computed tomography observation, it was confirmed that the fabricated foam-filled pipes had almost uniform porosity and pore size distributions. It was found that no scattering of the fragments of collapsed ADC12 foam occurred for the foam-filled pipes owing to the existence of the pipe surrounding the ADC12 foam. Preventing the scattering of the ADC12 foam decreases the drop in stress during dynamic compression tests and therefore improves the energy absorption properties of the foam.

  18. THIRD-GENERATION FOAM BLOWING AGENTS FOR FOAM INSULATION

    Science.gov (United States)

    The report gives results of a study of third-generation blowing agents for foam insulation. (NOTE: the search for third-generation foam blowing agents has led to the realization that, as the number of potential substitutes increases, new concerns, such as their potential to act a...

  19. Distribution of Rare Earth Metals in Technogenic Wastes of Energy Enterprises (Results of the Laboratory Studies)

    OpenAIRE

    Alexandr Ivanovich Khanchuk; Aleksandr Alekseevich Yudakov; Mikhail Azaryevich Medkov; Leonid Nikolayevich Alekseyko; Andrey Vasilyevich Taskin; Sergey Igorevich Ivannikov

    2016-01-01

    The results of the research interaction between ash and slag samples from Vladivostok TPP’s landfills saturated with underburning and ammonium hydrodifluoride were given. It was found out that the reactions of the main components of a concentrate with NH4HF2 are flowing with creation of complex ammonium fluoro-metalate. It is shown that the distribution of REM (rare earth metals) between foam and heavier products is going during the flotation process of carbon-containing ash and slag samples ...

  20. Low-density carbonized resorcinol-formaldehyde foams

    International Nuclear Information System (INIS)

    Kong, F.M.; Buckley, S.R.; Giles, C.L. Jr.; Haendler, B.L.; Hair, L.M.; Letts, S.A.; Overturf, G.E. III; Price, C.W.; Cook, R.C.

    1991-01-01

    This report documents research and development on resorcinol- formaldehyde-based foam materials conducted between 1986 and June 1990, when the effort was discontinued. The foams discussed are resorcinol-formaldehyde (RF) foam, carbonized RF (CRF) foam, and two composite foams, a polystyrene/RF (PS/RF) foam and its carbonized derivative (CPR). The RF foams are synthesized by the polycondensation of resorcinol with formaldehyde in a slightly basic solution. Their structure and density depend strongly on the concentration of the sodium carbonate catalyst. The have an interconnected bead structure similar to that of silica aerogels; bead sizes range from 30 to 130 Angstrom, and cell sizes are less than 0.1 μm. We have achieved densities of 16 to 200 mg/cm 3 . The RF foams can be pyrolyzed in an inert atmosphere to form a vitreous carbon foam (CRF), which has a similar microstructure but much higher mechanical strength. The PS/RF foams are obtained by filling the 2- to 3-μm cells of PS foam (a low-density hydrocarbon foam we have developed) with RF. The resultant foams have the outstanding handling and machinability of the PS foam matrix and the small cell size of RF. Pyrolyzing PS/RF foams causes depolymerization and loss of the PS; the resulting CPR foams have a structure similar to the PS foams in which CRF both replicates and fills the PS cells

  1. Improving Water Repellence and Friability of Tannin-Furanic Foams by Oil-Grafted Flavonoid Tannins

    Directory of Open Access Journals (Sweden)

    Géraldine Rangel

    2016-08-01

    Full Text Available Tannin-furanic biobased foams, based on the co-reaction of bark-derived condensed tannins and thermoset furanic polymers, have low thermal conductivity, are self-extinguishing, and have high fire resistance, which allows their development for several industrial uses. One of their main drawbacks, however, is the absorption of water within the foam itself. Another problem is the rather friable surface, which is a definite drawback for some potential applications. In this work, these two problems are minimized or eliminated by introducing a component of oil-grafted tannin in the foam formulation. The incorporation of fatty chains markedly decreased foam friability and increased water repellency in the body of the foams. These properties and the compounds formed by fatty acids grafting onto the tannin flavonoids were extensively tested.

  2. Thermal Conductivity of Foam Glass

    DEFF Research Database (Denmark)

    Petersen, Rasmus Rosenlund; König, Jakob; Yue, Yuanzheng

    Due to the increased focus on energy savings and waste recycling foam glass materials have gained increased attention. The production process of foam glass is a potential low-cost recycle option for challenging waste, e.g. CRT glass and industrial waste (fly ash and slags). Foam glass is used...... as thermal insulating material in building and chemical industry. The large volume of gas (porosity 90 – 95%) is the main reason of the low thermal conductivity of the foam glass. If gases with lower thermal conductivity compared to air are entrapped in the glass melt, the derived foam glass will contain...... only closed pores and its overall thermal conductivity will be much lower than that of the foam glass with open pores. In this work we have prepared foam glass using different types of recycled glasses and different kinds of foaming agents. This enabled the formation of foam glasses having gas cells...

  3. Clinical effectiveness and cost-effectiveness of foam sclerotherapy, endovenous laser ablation and surgery for varicose veins: results from the Comparison of LAser, Surgery and foam Sclerotherapy (CLASS) randomised controlled trial.

    Science.gov (United States)

    Brittenden, Julie; Cotton, Seonaidh C; Elders, Andrew; Tassie, Emma; Scotland, Graham; Ramsay, Craig R; Norrie, John; Burr, Jennifer; Francis, Jill; Wileman, Samantha; Campbell, Bruce; Bachoo, Paul; Chetter, Ian; Gough, Michael; Earnshaw, Jonothan; Lees, Tim; Scott, Julian; Baker, Sara A; MacLennan, Graeme; Prior, Maria; Bolsover, Denise; Campbell, Marion K

    2015-04-01

    Foam sclerotherapy (foam) and endovenous laser ablation (EVLA) have emerged as alternative treatments to surgery for patients with varicose veins, but uncertainty exists regarding their effectiveness in the medium to longer term. To assess the clinical effectiveness and cost-effectiveness of foam, EVLA and surgery for the treatment of varicose veins. A parallel-group randomised controlled trial (RCT) without blinding, and economic modelling evaluation. Eleven UK specialist vascular centres. Seven hundred and ninety-eight patients with primary varicose veins (foam, n = 292; surgery, n = 294; EVLA, n = 212). Patients were randomised between all three treatment options (eight centres) or between foam and surgery (three centres). Disease-specific [Aberdeen Varicose Vein Questionnaire (AVVQ)] and generic [European Quality of Life-5 Dimensions (EQ-5D), Short Form questionnaire-36 items (SF-36) physical and mental component scores] quality of life (QoL) at 6 months. Cost-effectiveness as cost per quality-adjusted life-year (QALY) gained. Quality of life at 6 weeks; residual varicose veins; Venous Clinical Severity Score (VCSS); complication rates; return to normal activity; truncal vein ablation rates; and costs. The results appear generalisable in that participants' baseline characteristics (apart from a lower-than-expected proportion of females) and post-treatment improvement in outcomes were comparable with those in other RCTs. The health gain achieved in the AVVQ with foam was significantly lower than with surgery at 6 months [effect size -1.74, 95% confidence interval (CI) -2.97 to -0.50; p = 0.006], but was similar to that achieved with EVLA. The health gain in SF-36 mental component score for foam was worse than that for EVLA (effect size 1.54, 95% CI 0.01 to 3.06; p = 0.048) but similar to that for surgery. There were no differences in EQ-5D or SF-36 component scores in the surgery versus foam or surgery versus EVLA comparisons at 6 months. The

  4. Aerosol-foam interaction experiments

    International Nuclear Information System (INIS)

    Ball, M.H.E.; Luscombe, C.DeM.; Mitchell, J.P.

    1990-03-01

    Foam treatment offers the potential to clean gas streams containing radioactive particles. A large decontamination factor has been claimed for the removal of airborne plutonium dust when spraying a commercially available foam on the walls and horizontal surfaces of an alpha-active room. Experiments have been designed and undertaken to reproduce these conditions with a non-radioactive simulant aerosol. Careful measurements of aerosol concentrations with and without foam treatment failed to provide convincing evidence to support the earlier observation. The foam may not have been as well mixed with the aerosol in the present studies. Further work is required to explore more efficient mixing methods, including systems in which the aerosol steam is passed through the foam, rather than merely spraying foam into the path of the aerosol. (author)

  5. Dechlorination of Trichloroacetic Acid Using a Noble Metal-Free Graphene-Cu Foam Electrode via Direct Cathodic Reduction and Atomic H.

    Science.gov (United States)

    Mao, Ran; Li, Ning; Lan, Huachun; Zhao, Xu; Liu, Huijuan; Qu, Jiuhui; Sun, Meng

    2016-04-05

    A three-dimensional graphene-copper (3D GR-Cu) foam electrode prepared by chemical vapor deposition method exhibited superior electrocatalytic activity toward the dechlorination of trichloroacetic acid (TCAA) as compared to the Cu foam electrode. The cyclic voltammetry and electrochemical impedance spectra analysis confirmed that GR accelerated the electron transfer from the cathode surface to TCAA. With the applied cathode potential of -1.2 V (vs SCE), 95.3% of TCAA (500 μg/L) was removed within 20 min at pH 6.8. TCAA dechlorination at the Cu foam electrode was enhanced at acidic pH, while a slight pH effect was observed at the GR-Cu foam electrode with a significant inhibition for Cu leaching. The electrocatalytic dechlorination of TCAA was accomplished via a combined stepwise and concerted pathway on both electrodes, whereas the concerted pathway was efficiently promoted on the GR-Cu foam electrode. The direct reduction by electrons was responsible for TCAA dechlorination at Cu foam electrode, while at GR-Cu foam electrode, the surface-adsorbed atomic H* also contributed to TCAA dechlorination owing to the chemical storage of hydrogen in the GR structure. Finally, the potential applicability of GR-Cu foam was revealed by its stability in the electrocatalytic dechlorination over 25 cycles.

  6. Fracture Toughness Evaluation of Space Shuttle External Tank Thermal Protection System Polyurethane Foam Insulation Materials

    Science.gov (United States)

    McGill, Preston; Wells, Doug; Morgan, Kristin

    2006-01-01

    Experimental evaluation of the basic fracture properties of Thermal Protection System (TPS) polyurethane foam insulation materials was conducted to validate the methodology used in estimating critical defect sizes in TPS applications on the Space Shuttle External Fuel Tank. The polyurethane foam found on the External Tank (ET) is manufactured by mixing liquid constituents and allowing them to react and expand upwards - a process which creates component cells that are generally elongated in the foam rise direction and gives rise to mechanical anisotropy. Similarly, the application of successive foam layers to the ET produces cohesive foam interfaces (knitlines) which may lead to local variations in mechanical properties. This study reports the fracture toughness of BX-265, NCFI 24-124, and PDL-1034 closed-cell polyurethane foam as a function of ambient and cryogenic temperatures and knitline/cellular orientation at ambient pressure.

  7. Method of forming a ceramic matrix composite and a ceramic matrix component

    Science.gov (United States)

    de Diego, Peter; Zhang, James

    2017-05-30

    A method of forming a ceramic matrix composite component includes providing a formed ceramic member having a cavity, filling at least a portion of the cavity with a ceramic foam. The ceramic foam is deposited on a barrier layer covering at least one internal passage of the cavity. The method includes processing the formed ceramic member and ceramic foam to obtain a ceramic matrix composite component. Also provided is a method of forming a ceramic matrix composite blade and a ceramic matrix composite component.

  8. Processing and characterization of titanium dioxide grown on titanium foam for potential use as Li-ion electrode

    Energy Technology Data Exchange (ETDEWEB)

    Choi, Hyelim; Park, Hyeji [School of Materials Science and Engineering, Kookmin University, Jeongneung-dong, Seongbuk-gu, Seoul 20707 (Korea, Republic of); Um, Ji Hyun [Integrated Energy Center for Fostering Global Creative Researcher, Sungkyunkwan University, Suwon 440-746 (Korea, Republic of); Yoon, Won-Sub [Department of Energy Science, Sungkyunkwan University, Suwon 440-746 (Korea, Republic of); Choe, Heeman, E-mail: heeman@kookmin.ac.kr [School of Materials Science and Engineering, Kookmin University, Jeongneung-dong, Seongbuk-gu, Seoul 20707 (Korea, Republic of)

    2017-07-31

    Highlights: • Successful formation of anatase TiO{sub 2} on the surface of Ti foam. • Successful application of TiO{sub 2}/Ti foam anode to lithium ion battery. • TiO{sub 2}/Ti foam anode shows remarkably stable capacity retention. - Abstract: This study investigates the processing and potential application of Ti foams to the anode of lithium-ion batteries (LIBs). Ti foam is successfully synthesized using a water-based freeze-casting process, and anatase titanium dioxide (TiO{sub 2}) is formed on the surface of the Ti foam for application to the anode of LIB. The metallic Ti foam acts as a current collector “platform” with increased surface area and the TiO{sub 2} surface coating acts as an active anode material. Coin-cell test results show that the unique combination of the Ti foam and the TiO{sub 2} coating anode has highly stable cycling properties and can thus be considered promising for use as an advanced anode for LIBs that require high safety and stability. It is anticipated that the use of the unique Ti-foam-based electrode design will not only be limited to LIBs but also will be applied to other energy and environmental areas as a catalyst or filter.

  9. Drainage effect in eutectic Al-Si foam using similar alporas process

    International Nuclear Information System (INIS)

    Filho, M.O.; Junior, A.C.S; Ferrandini, P.L.; Nakazato, A.Z.; Assis, W.L.S.

    2016-01-01

    Cellular materials have particular properties. This properties are very interesting in various type of industries, as construction, automobile and shipbuilding. Two reasons why metal foams are apply in more companies are difficult process control and high production costs. Therefore, this study aims to analyze the drainage effect in four samples produced with alloy Al-Si eutectic using CaCO 3 as foaming agent, since this is low cost than TiH 2 used normally in Alporas process and this foam have well pores uniform. For these samples has been used 700°C during all process, mixing time was 180 seconds, holding time was 150 seconds and 3,5 w.t% CaCO3. Therefore, these samples were cut transversally and analyzed what were the drainage effect on the apparent density, relative density and porosity. The free zone bubbles were noticed in all the samples. (author)

  10. Thermosetting Fluoropolymer Foams

    Science.gov (United States)

    Lee, Sheng Yen

    1987-01-01

    New process makes fluoropolymer foams with controllable amounts of inert-gas fillings in foam cells. Thermosetting fluoropolymers do not require foaming additives leaving undesirable residues and do not have to be molded and sintered at temperatures of about 240 to 400 degree C. Consequently, better for use with electronic or other parts sensitive to high temperatures or residues. Uses include coatings, electrical insulation, and structural parts.

  11. 21 CFR 888.3030 - Single/multiple component metallic bone fixation appliances and accessories.

    Science.gov (United States)

    2010-04-01

    ... appliances and accessories. 888.3030 Section 888.3030 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT....3030 Single/multiple component metallic bone fixation appliances and accessories. (a) Identification. Single/multiple component metallic bone fixation appliances and accessories are devices intended to be...

  12. Forging of metallic nano-objects for the fabrication of submicron-size components

    International Nuclear Information System (INIS)

    Roesler, J; Mukherji, D; Schock, K; Kleindiek, S

    2007-01-01

    In recent years, nanoscale fabrication has developed considerably, but the fabrication of free-standing nanosize components is still a great challenge. The fabrication of metallic nanocomponents utilizing three basic steps is demonstrated here. First, metallic alloys are used as factories to produce a metallic raw stock of nano-objects/nanoparticles in large numbers. These objects are then isolated from the powder containing thousands of such objects inside a scanning electron microscope using manipulators, and placed on a micro-anvil or a die. Finally, the shape of the individual nano-object is changed by nanoforging using a microhammer. In this way free-standing, high-strength, metallic nano-objects may be shaped into components with dimensions in the 100 nm range. By assembling such nanocomponents, high-performance microsystems can be fabricated, which are truly in the micrometre scale (the size ratio of a system to its component is typically 10:1)

  13. The effect of gamma-radiation on biodegradability of natural FIBER/PP-HMSPP foams: A study of thermal stability and biodegradability

    International Nuclear Information System (INIS)

    Cardoso, Elizabeth C.L.; Scagliusi, Sandra R.; Lugao, Ademar B.

    2015-01-01

    This research was carried out to evaluate how gamma-radiation affected PP/HMSPP structural foams reinforced with sugarcane bagasse, in terms of thermal properties, biodegradability and infrared spectrum. Polymers are used in various applications and in different industrial areas providing enormous quantities of wastes in environment, contributing with 20 to 30% of total volume of solid residues. Besides, shortage of plastics resins obtained from oil and natural gas is addressing research and development toward alternative materials; environmental concerning in litter reduction is being directed to renewable polymers for manufacturing of polymeric foams. Biodegradable polymers, a new generation of polymers produced from various natural resources, environmentally safe and friendly, can contribute for pollution reduction, at a low cost. High density structural foams are specially used in civil construction, in replacement of metals, woods and concrete, but contribute for environmental pollution, due to components nature. In this study, it was incorporated sugarcane bagasse in PP/HMSPP polymeric matrix blends. Gamma radiation applied at 50, 100, 150, 200 and 500 kGy doses showed effective for biodegradability induction. TGA analyses pointed toward stability around 205 deg C; decomposition of both cellulose and hemicellulose took place at 310 deg C and above, whereas the degradation of reinforced fibers composites took place above 430 deg C. Infrared spectrum of foams were studied using FTIR, showing no sensitivity to the presence of C = C and C =O functional groups. (author)

  14. The effect of gamma-radiation on biodegradability of natural FIBER/PP-HMSPP foams: A study of thermal stability and biodegradability

    Energy Technology Data Exchange (ETDEWEB)

    Cardoso, Elizabeth C.L.; Scagliusi, Sandra R.; Lugao, Ademar B., E-mail: eclcardo@ipen.br [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)

    2015-07-01

    This research was carried out to evaluate how gamma-radiation affected PP/HMSPP structural foams reinforced with sugarcane bagasse, in terms of thermal properties, biodegradability and infrared spectrum. Polymers are used in various applications and in different industrial areas providing enormous quantities of wastes in environment, contributing with 20 to 30% of total volume of solid residues. Besides, shortage of plastics resins obtained from oil and natural gas is addressing research and development toward alternative materials; environmental concerning in litter reduction is being directed to renewable polymers for manufacturing of polymeric foams. Biodegradable polymers, a new generation of polymers produced from various natural resources, environmentally safe and friendly, can contribute for pollution reduction, at a low cost. High density structural foams are specially used in civil construction, in replacement of metals, woods and concrete, but contribute for environmental pollution, due to components nature. In this study, it was incorporated sugarcane bagasse in PP/HMSPP polymeric matrix blends. Gamma radiation applied at 50, 100, 150, 200 and 500 kGy doses showed effective for biodegradability induction. TGA analyses pointed toward stability around 205 deg C; decomposition of both cellulose and hemicellulose took place at 310 deg C and above, whereas the degradation of reinforced fibers composites took place above 430 deg C. Infrared spectrum of foams were studied using FTIR, showing no sensitivity to the presence of C = C and C =O functional groups. (author)

  15. Pipe Decontamination Involving String-Foam Circulation

    International Nuclear Information System (INIS)

    Turchet, J.P.; Estienne, G.; Fournel, B.

    2002-01-01

    Foam applications number for nuclear decontamination purposes has recently increased. The major advantage of foam decontamination is the reduction of secondary liquid wastes volumes. Among foam applications, we focus on foam circulation in contaminated equipment. Dynamic properties of the system ensures an homogeneous and rapid effect of the foam bed-drifted chemical reagents present in the liquid phase. This paper describes a new approach of foam decontamination for pipes. It is based on an alternated air and foam injections. We called it 'string-foam circulation'. A further reduction of liquid wastes is achieved compared to continuous foam. Secondly, total pressure loss along the pipe is controlled by the total foam length in the pipe. It is thus possible to clean longer pipes keeping the pressure under atmospheric pressure value. This ensures the non dispersion of contamination. This study describes experimental results obtained with a neutral foam as well with an acid foam on a 130 m long loop. Finally, the decontamination of a 44 meters pipe is presented. (authors)

  16. Separation and determination of trace amounts of zinc, lead, cadmium and mercury in tap and Qaroun lake water using polyurethane foam functionalized with 4-hydroxytoluene and 4-hydroxyacetophenone

    International Nuclear Information System (INIS)

    Burham, N.; Abdel-Azeem, S.M.; El-Shahat, M.F.

    2006-01-01

    A stable chelating sorbent was synthesized by covalently linking 4-hydroxytoluene or 4-hydroxyacetophenone with the polyurethane foam (PUF) through -N=N- group. The synthesized chelating sorbents were characterized by IR and UV/vis measurements. The modified foams show excellent stability towards various solvents. Factors influencing the extraction process of Zn(II), Pb(II), Cd(II) and Hg(II) were studied and evaluated as a function of pH of metal ion solution and equilibration shaking time. The values of sorption capacity of metal ions (μg g -1 ) were determined with the two types of bonded foams. The two phenolic bonded foams were studied comparatively. The potential applications of the two newly synthesized foams for the removal and separation of the examined metal ions from two natural water samples (drinking tap water and Qaroun lake water at Fayoum City, Egypt) were investigated. Precision (assessed as a relative standard deviation, R.S.D.) was also evaluated and found to be ≤7.3% (N = 5) with a detection limit under 0.46 μg L -1

  17. Separation and determination of trace amounts of zinc, lead, cadmium and mercury in tap and Qaroun lake water using polyurethane foam functionalized with 4-hydroxytoluene and 4-hydroxyacetophenone

    Energy Technology Data Exchange (ETDEWEB)

    Burham, N. [Chemistry Department, Faculty of Science, Fayoum University, Fayoum City (Egypt)]. E-mail: n_burham@yahoo.com; Abdel-Azeem, S.M. [Chemistry Department, Faculty of Science, Fayoum University, Fayoum City (Egypt); El-Shahat, M.F. [Chemistry Department, Faculty of Science, Ain-Shams University, Cairo (Egypt)

    2006-10-10

    A stable chelating sorbent was synthesized by covalently linking 4-hydroxytoluene or 4-hydroxyacetophenone with the polyurethane foam (PUF) through -N=N- group. The synthesized chelating sorbents were characterized by IR and UV/vis measurements. The modified foams show excellent stability towards various solvents. Factors influencing the extraction process of Zn(II), Pb(II), Cd(II) and Hg(II) were studied and evaluated as a function of pH of metal ion solution and equilibration shaking time. The values of sorption capacity of metal ions ({mu}g g{sup -1}) were determined with the two types of bonded foams. The two phenolic bonded foams were studied comparatively. The potential applications of the two newly synthesized foams for the removal and separation of the examined metal ions from two natural water samples (drinking tap water and Qaroun lake water at Fayoum City, Egypt) were investigated. Precision (assessed as a relative standard deviation, R.S.D.) was also evaluated and found to be {<=}7.3% (N = 5) with a detection limit under 0.46 {mu}g L{sup -1}.

  18. Influence of foaming agents on solid thermal conductivity of foam glasses prepared from CRT panel glass

    DEFF Research Database (Denmark)

    Østergaard, Martin Bonderup; Petersen, Rasmus Rosenlund; König, Jakob

    2017-01-01

    The understanding of the thermal transport mechanism of foam glass is still lacking. The contribution of solid- and gas conduction to the total thermal conductivity remains to be reported. In many foam glasses, the solid phase consist of a mix of an amorphous and a crystalline part where foaming...... containing glass and crystalline foaming agents and amorphous samples where the foaming agents are completely dissolved in the glass structure, respectively. Results show that the samples prepared by sintering have a higher thermal conductivity than the samples prepared by melt-quenching. The thermal...... conductivities of the sintered and the melt-quenched samples represent an upper and lower limit of the solid phase thermal conductivity of foam glasses prepared with these foaming agents. The content of foaming agents dissolved in the glass structure has a major impact on the solid thermal conductivity of foam...

  19. Effects of SiC and MgO on aluminabased ceramic foams filters

    Directory of Open Access Journals (Sweden)

    CAO Da-li

    2007-11-01

    Full Text Available Alumina-based foam ceramic filters were fabricated by using alumina, SiC, magnesia powder as major materials. It has been found that this ceramic filter has a uniform macrostructure for filtering molten metals. The influences of SiC and magnesia content, the sintering temperatures on ceramic properties were discussed. Aluminabased foam ceramic filters containing 2.2 mass% magnesia and 7.6 mass% SiC has a compressive strength of 1.36 MPa and a thermal shock resistance of 5 times. Its main phases after 1 hour sintering at 1 500 consist of alumina, silicon carbide, spinel and mullite.

  20. The Electrochemical Atomic Layer Deposition of Pt and Pd nanoparticles on Ni foam for the electrooxidation of alcohols

    CSIR Research Space (South Africa)

    Modibedi, RM

    2012-10-01

    Full Text Available Electrodeposition of Pt and Pd metal by surface limited redox replacement reactions was performed using the electrochemical atomic layer deposition. Carbon paper and Ni foam were used as substrates for metal deposition. Supported Pt and Pd...

  1. Characterization of geopolymer fly-ash based foams obtained with the addition of Al powder or H{sub 2}O{sub 2} as foaming agents

    Energy Technology Data Exchange (ETDEWEB)

    Ducman, V., E-mail: vilma.ducman@zag.si; Korat, L.

    2016-03-15

    Recent innovations in geopolymer technology have led to the development of various different types of geopolymeric products, including highly porous geopolymer-based foams, which are formed by the addition of foaming agents to a geopolymer fly-ash based matrix. These agents decompose, or react with the liquid matrix or oxygen in the matrix, resulting in the release of gases which form pores prior to the hardening of the gel. The hardened structure has good mechanical and thermal properties, and can therefore be used for applications in acoustic panels and in lightweight pre-fabricated components for thermal insulation purposes. This study presents the results of the pore-forming process in the case when two different foaming agents, i.e. aluminium powder amounting to 0.07, 0.13 and 0.20 mass. % and H{sub 2}O{sub 2} amounting to 0.5, 1.0, 1.5 and 2.0 mass. %, were added to a fly-ash geopolymer matrix. The physical, mechanical, and microstructural properties of the thus obtained foams, and the effects of the type and amount of the added foaming agent, are presented and discussed. Highly porous structures were obtained in the case of both of the investigated foaming agents, with overall porosities up to 59% when aluminium powder was added, and of up 48% when H{sub 2}O{sub 2} was added. In the latter case, when 2% of the H{sub 2}O{sub 2} foaming agent was added, finer pores (with diameters up to 500 μm) occurred in the structure, whereas somewhat larger pores (some had diameters greater than 1 mm) occurred when the same amount of aluminium powder was added. The mechanical properties of the investigated foams depended on their porosity. In the case of highly porous structures a compressive strength of 3.3 MPa was nevertheless achieved for the samples containing 0.2% of aluminium powder, and 3.7 MPa for those containing 2.0% of H{sub 2}O{sub 2}. - Highlights: • Preparation of geopolymer foams based on fly ash with the addition of Al powder or H{sub 2}O{sub 2} as

  2. Foam-mat drying technology: A review.

    Science.gov (United States)

    Hardy, Z; Jideani, V A

    2017-08-13

    This article reviews various aspects of foam-mat drying such as foam-mat drying processing technique, main additives used for foam-mat drying, foam-mat drying of liquid and solid foods, quality characteristics of foam-mat dried foods, and economic and technical benefits for employing foam-mat drying. Foam-mat drying process is an alternative method that allows the removal of water from liquid materials and pureed materials. In this drying process, a liquid material is converted into foam that is stable by being whipped after adding an edible foaming agent. The stable foam is then spread out in sheet or mat and dried by using hot air (40-90°C) at atmospheric pressure. Methyl cellulose (0.25-2%), egg white (3-20%), maltodextrin (0.5-05%), and gum Arabic (2-9%) are the commonly utilized additives for the foam-mat drying process at the given range, either combined together for their effectiveness or individual effect. The foam-mat drying process is suitable for heat sensitive, viscous, and sticky products that cannot be dried using other forms of drying methods such as spray drying because of the state of product. More interest has developed for foam-mat drying because of the simplicity, cost effectiveness, high speed drying, and improved product quality it provides.

  3. A metal-organic framework derived hierarchical nickel-cobalt sulfide nanosheet array on Ni foam with enhanced electrochemical performance for supercapacitors.

    Science.gov (United States)

    Tao, Kai; Han, Xue; Ma, Qingxiang; Han, Lei

    2018-03-06

    Metal-organic frameworks (MOFs) have emerged as a new platform for the construction of various functional materials for energy related applications. Here, a facile MOF templating method is developed to fabricate a hierarchical nickel-cobalt sulfide nanosheet array on conductive Ni foam (Ni-Co-S/NF) as a binder-free electrode for supercapacitors. A uniform 2D Co-MOF nanowall array is first grown in situ on Ni foam in aqueous solution at room temperature, and then the Co-MOF nanowalls are converted into hierarchical Ni-Co-S nanoarchitectures via an etching and ion-exchange reaction with Ni(NO 3 ) 2 , and a subsequent solvothermal sulfurization. Taking advantage of the compositional and structural merits of the hierarchical Ni-Co-S nanosheet array and conductive Ni foam, such as fast electron transportation, short ion diffusion path, abundant active sites and rich redox reactions, the obtained Ni-Co-S/NF electrode exhibits excellent electrochemical capacitive performance (1406.9 F g -1 at 0.5 A g -1 , 53.9% retention at 10 A g -1 and 88.6% retention over 1000 cycles), which is superior to control CoS/NF. An asymmetric supercapacitor (ASC) assembled by using the as-fabricated Ni-Co-S/NF as the positive electrode and activated carbon (AC) as the negative electrode delivers a high energy density of 24.8 W h kg -1 at a high power density of 849.5 W kg -1 . Even when the power density is as high as 8.5 kW kg -1 , the ASC still exhibits a high energy density of 12.5 W h kg -1 . This facile synthetic strategy can also be extended to fabricate other hierarchical integrated electrodes for high-efficiency electrochemical energy conversion and storage devices.

  4. High-Potential Metalless Nanocarbon Foam Supercapacitors Operating in Aqueous Electrolyte.

    Science.gov (United States)

    Liu, Chueh; Li, Changling; Ahmed, Kazi; Mutlu, Zafer; Lee, Ilkeun; Zaera, Francisco; Ozkan, Cengiz S; Ozkan, Mihrimah

    2018-04-01

    Light-weight graphite foam decorated with carbon nanotubes (dia. 20-50 nm) is utilized as an effective electrode without binders, conductive additives, or metallic current collectors for supercapacitors in aqueous electrolyte. Facile nitric acid treatment renders wide operating potentials, high specific capacitances and energy densities, and long lifespan over 10 000 cycles manifested as 164.5 and 111.8 F g -1 , 22.85 and 12.58 Wh kg -1 , 74.6% and 95.6% capacitance retention for 2 and 1.8 V, respectively. Overcharge protection is demonstrated by repetitive cycling between 2 and 2.5 V for 2000 cycles without catastrophic structural demolition or severe capacity fading. Graphite foam without metallic strut possessing low density (≈0.4-0.45 g cm -3 ) further reduces the total weight of the electrode. The thorough investigation of the specific capacitances and coulombic efficiencies versus potential windows and current densities provides insights into the selection of operation conditions for future practical devices. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  5. Electro-deposition of Pd on Carbon paper and Ni foam via surface limited redox-replacement reaction for oxygen reduction reaction

    International Nuclear Information System (INIS)

    Modibedi, Remegia M.; Mathe, Mkhulu K.; Motsoeneng, Rapelang G.; Khotseng, Lindiwe E.; Ozoemena, Kenneth I.; Louw, Eldah K.

    2014-01-01

    Pd nanostructured catalysts were electrodeposited by surface-limited redox replacement reactions using the electrochemical atomic layer deposition technique. Carbon paper and Ni foam were used as substrates for the electrodeposition of the metal. Supported nanostructured Pd electrodes were characterized using electrochemical methods and scanning electron microscopy. Carbon paper and Ni foam produced good quality deposits with some agglomeration on Ni foam. The EDX profiles confirmed the presence of Pd particles. Cyclic voltammograms of the electrodeposited Pd on substrates showed features characteristic of polycrystalline Pd electrodes. In the acidic electrolyte a very weak oxygen reduction reaction (ORR) activity was observed on Pd/Carbon paper electrode when compared to Pd/Ni foam electrode. The Pd/Ni foam electrode showed improved ORR activity in alkaline medium

  6. Production of lightweight foam glass (invited talk)

    DEFF Research Database (Denmark)

    Petersen, Rasmus Rosenlund; König, Jakob; Yue, Yuanzheng

    The foam glass production allows low cost recycling of postconsumer glass and industrial waste materials as foaming agent or as melt resource. Foam glass is commonly produced by utilising milled glass mixed with a foaming agent. The powder mixture is heat-treated to around 10^3.7 – 10^6 Pa s, which...... result in viscous sintering and subsequent foaming of the glass melt. The porous glass melt is cooled down to room temperature to freeze-in the foam structure. The resulting foam glass is applied in constructions as a light weight material to reduce load bearing capacity and as heat insulating material...... in buildings and industry. We foam panel glass from old televisions with different foaming agents. We discuss the foaming ability and the foaming mechanism of different foaming systems. We compare several studies to define a viscous window for preparing low density foam glass. However, preparing foam glass...

  7. Polyurethane-Foam Maskant

    Science.gov (United States)

    Bodemeijer, R.

    1985-01-01

    Brown wax previously used to mask hardware replaced with polyurethane foam in electroplating and electroforming operations. Foam easier to apply and remove than wax and does not contaminate electrolytes.

  8. Fire hazards in the use of polyurethane foam with special consideration given to its use in the mining industry

    Energy Technology Data Exchange (ETDEWEB)

    Florschuetz, P.; Hoffmann, R.; Pfeiffer, J.

    1980-08-01

    Discusses results from combustion tests conducted with polyurethane (PUR) foam and polyisocyanurate (PIC) foam, which are employed in mine construction, thermal insulation, and coating of coal preparation equipment. Fire point, inflammation point, flame propagation, carbon monoxide content in the fumes and other parameters were investigated. Coating the foam with a fire resistant chemical agent delayed the combustion process. Mixing foam with various quantities of foam components influenced the combustion process as well. The combustion results are presented in tables. It is concluded that the user's instructions for producing foam should be strictly adhered to and that larger sections of insulation by these foams in underground mines can only be permitted when additional protection measures are undertaken. (5 refs.) (In German)

  9. Comparative study of material loss at the taper interface in retrieved metal-on-polyethylene and metal-on-metal femoral components from a single manufacturer.

    Science.gov (United States)

    Bills, Paul; Racasan, Radu; Bhattacharya, Saugatta; Blunt, Liam; Isaac, Graham

    2017-08-01

    There have been a number of reports on the occurrence of taper corrosion and/or fretting and some have speculated on a link to the occurrence of adverse local tissue reaction specifically in relation to total hip replacement which have a metal-on-metal bearing. As such a study was carried out to compare the magnitude of material loss at the taper in a series of retrieved femoral heads used in metal-on-polyethylene bearings with that in a series of retrieved heads used in metal-on-metal bearings. A total of 36 metal-on-polyethylene and 21 metal-on-metal femoral components were included in the study all of which were received from a customer complaint database. Furthermore, a total of nine as-manufactured femoral components were included to provide a baseline for characterisation. All taper surfaces were assessed using an established corrosion scoring method and measurements were taken of the female taper surface using a contact profilometry. In the case of metal-on-metal components, the bearing wear was also assessed using coordinate metrology to determine whether or not there was a relationship between bearing and taper material loss in these cases. The study found that in this cohort the median value of metal-on-polyethylene taper loss was 1.25 mm 3 with the consequent median value for metal-on-metal taper loss being 1.75 mm 3 . This study also suggests that manufacturing form can result in an apparent loss of material from the taper surface determined to have a median value of 0.59 mm 3 . Therefore, it is clear that form variability is a significant confounding factor in the measurement of material loss from the tapers of femoral heads retrieved following revision surgery.

  10. Fabrication of FeAl Intermetallic Foams by Tartaric Acid-Assisted Self-Propagating High-Temperature Synthesis

    Directory of Open Access Journals (Sweden)

    Krzysztof Karczewski

    2018-04-01

    Full Text Available Iron aluminides are intermetallics with interesting applications in porous form thanks to their mechanical and corrosion resistance properties. However, making porous forms of these materials is not easy due to their high melting points. We formed FeAl foams by elemental iron and aluminum powders sintering with tartaric acid additive. Tartaric acid worked as an in situ gas-releasing agent during the self-propagating high-temperature synthesis of FeAl intermetallic alloy, which was confirmed by X-ray diffraction measurements. The porosity of the formed foams was up to 36 ± 4%. In the core of the sample, the average equivalent circle diameter was found to be 47 ± 20 µm, while on the surface, it was 35 ± 16 µm; thus, the spread of the pore size was smaller than reported previously. To investigate functional applications of the formed FeAl foam, the pressure drop of air during penetration of the foam was examined. It was found that increased porosity of the material increased the flow of the air through the metallic foam.

  11. Alginate foam-based three-dimensional culture to investigate drug sensitivity in primary leukaemia cells.

    Science.gov (United States)

    Karimpoor, Mahroo; Yebra-Fernandez, Eva; Parhizkar, Maryam; Orlu, Mine; Craig, Duncan; Khorashad, Jamshid S; Edirisinghe, Mohan

    2018-04-01

    The development of assays for evaluating the sensitivity of leukaemia cells to anti-cancer agents is becoming an important aspect of personalized medicine. Conventional cell cultures lack the three-dimensional (3D) structure of the bone marrow (BM), the extracellular matrix and stromal components which are crucial for the growth and survival of leukaemia stem cells. To accurately predict the sensitivity of the leukaemia cells in an in vitro assay a culturing system containing the essential components of BM is required. In this study, we developed a porous calcium alginate foam-based scaffold to be used for 3D culture. The new 3D culture was shown to be cell compatible as it supported the proliferation of both normal haematopoietic and leukaemia cells. Our cell differential assay for myeloid markers showed that the porous foam-based 3D culture enhanced myeloid differentiation in both leukaemia and normal haematopoietic cells compared to two-dimensional culture. The foam-based scaffold reduced the sensitivity of the leukaemia cells to the tested antileukaemia agents in K562 and HL60 leukaemia cell line model and also primary myeloid leukaemia cells. This observation supports the application of calcium alginate foams as scaffold components of the 3D cultures for investigation of sensitivity to antileukaemia agents in primary myeloid cells. © 2018 The Author(s).

  12. Fire-retardant foams

    Science.gov (United States)

    Gagliani, J.

    1978-01-01

    Family of polyimide resins are being developed as foams with exceptional fire-retardant properties. Foams are potentially useful for seat cushions in aircraft and ground vehicles and for applications such as home furnishings and building-construction materials. Basic formulations can be modified with reinforcing fibers or fillers to produce celular materials for variety of applications. By selecting reactants, polymer structure can be modified to give foams with properties ranging from high resiliency and flexibility to brittleness and rigidity.

  13. Influence of the glass particle size on the foaming process and physical characteristics of foam glasses

    DEFF Research Database (Denmark)

    König, Jakob; Petersen, Rasmus Rosenlund; Yue, Yuanzheng

    2016-01-01

    We have prepared low-density foam glasses from cathode-ray-tube panel glass using carbon and MnO2 as the foaming agents. The effect of the glass particle size on the foaming process, the apparent density and the pore morphology is revealed. The results show that the foaming is mainly caused...... by the reduction of manganese. Foam glasses with a density of

  14. Activated, coal-based carbon foam

    Science.gov (United States)

    Rogers, Darren Kenneth; Plucinski, Janusz Wladyslaw

    2004-12-21

    An ablation resistant, monolithic, activated, carbon foam produced by the activation of a coal-based carbon foam through the action of carbon dioxide, ozone or some similar oxidative agent that pits and/or partially oxidizes the carbon foam skeleton, thereby significantly increasing its overall surface area and concurrently increasing its filtering ability. Such activated carbon foams are suitable for application in virtually all areas where particulate or gel form activated carbon materials have been used. Such an activated carbon foam can be fabricated, i.e. sawed, machined and otherwise shaped to fit virtually any required filtering location by simple insertion and without the need for handling the "dirty" and friable particulate activated carbon foam materials of the prior art.

  15. Biodegradable foams based on starch, polyvinyl alcohol, chitosan and sugarcane fibers obtained by extrusion

    Directory of Open Access Journals (Sweden)

    Flávia Debiagi

    2011-10-01

    Full Text Available Biodegradable foams made from cassava starch, polyvinyl alcohol (PVA, sugarcane bagasse fibers and chitosan were obtained by extrusion. The composites were prepared with formulations determined by a constrained ternary mixtures experimental design, using as variables: (X1 starch / PVA (100 - 70%, (X2 chitosan (0 - 2% and (X3 fibers from sugar cane (0 - 28%. The effects of varying proportions of these three components on foam properties were studied, as well the relationship between their properties and foam microstructure. The addition of starch/PVA in high proportions increased the expansion index and mechanical resistance of studied foams. Fibers addition improved the expansion and mechanical properties of the foams. There was a trend of red and yellow colors when the composites were produced with the highest proportions of fibers and chitosan, respectively. All the formulations were resistant to moisture content increase until 75% relative humidity of storage.

  16. Curing Characterisation of Spruce Tannin-based Foams using the Advanced Isoconversional Method

    Directory of Open Access Journals (Sweden)

    Matjaž Čop

    2014-06-01

    Full Text Available The curing kinetics of foam prepared from the tannin of spruce tree bark was investigated using differential scanning calorimetry (DSC and the advanced isoconversional method. An analysis of the formulations with differing amounts of components (furfuryl alcohol, glycerol, tannin, and a catalyst showed that curing was delayed with increasing proportions of glycerol or tannins. An optimum amount of the catalyst constituent was also found during the study. The curing of the foam system was accelerated with increasing temperatures. Finally, the advanced isoconversional method, based on the model-free kinetic algorithm developed by Vyazovkin, appeared to be an appropriate model for the characterisation of the curing kinetics of tannin-based foams.

  17. Foam pad of appropriate thickness can improve diagnostic value of foam posturography in detecting postural instability.

    Science.gov (United States)

    Liu, Bo; Leng, Yangming; Zhou, Renhong; Liu, Jingjing; Liu, Dongdong; Liu, Jia; Zhang, Su-Lin; Kong, Wei-Jia

    2018-04-01

    The present study investigated the effect of foam thickness on postural stability in patients with unilateral vestibular hypofunction (UVH) during foam posturography. Static and foam posturography were performed in 33 patients (UVH group) and 30 healthy subjects (control group) with eyes open (EO) and closed (EC) on firm surface and on 1-5 foam pad(s). Sway velocity (SV) of center of pressure, standing time before falling (STBF) and falls reaction were recorded and analyzed. (1) SVs had an increasing tendency in both groups as the foam pads were added under EO and EC conditions. (2) STBFs, only in UVH group with EC, decreased with foam thickness increasing. (3) Significant differences in SV were found between the control and UVH group with EO (except for standing on firm surface, on 1 and 2 foam pad(s)) and with EC (all surface conditions). (4) Receiver operating characteristic curve analysis showed that the SV could better reflect the difference in postural stability between the two groups while standing on the 4 foam pads with EC. Our study showed that diagnostic value of foam posturography in detecting postural instability might be enhanced by using foam pad of right thickness.

  18. Bio-based Polymer Foam from Soyoil

    Science.gov (United States)

    Bonnaillie, Laetitia M.; Wool, Richard P.

    2006-03-01

    The growing bio-based polymeric foam industry is presently lead by plant oil-based polyols for polyurethanes and starch foams. We developed a new resilient, thermosetting foam system with a bio-based content higher than 80%. The acrylated epoxidized soybean oil and its fatty acid monomers is foamed with pressurized carbon dioxide and cured with free-radical initiators. The foam structure and pore dynamics are highly dependent on the temperature, viscosity and extent of reaction. Low-temperature cure hinds the destructive pore coalescence and the application of a controlled vacuum results in foams with lower densities ˜ 0.1 g/cc, but larger cells. We analyze the physics of foam formation and stability, as well as the structure and mechanical properties of the cured foam using rigidity percolation theory. The parameters studied include temperature, vacuum applied, and cross-link density. Additives bring additional improvements: nucleating agents and surfactants help produce foams with a high concentration of small cells and low bulk density. Hard and soft thermosetting foams with a bio content superior to 80% are successfully produced and tested. Potential applications include foam-core composites for hurricane-resistant housing, structural reinforcement for windmill blades, and tissue scaffolds.

  19. Synthesis of α-Fe₂O₃ and Fe-Mn Oxide Foams with Highly Tunable Magnetic Properties by the Replication Method from Polyurethane Templates.

    Science.gov (United States)

    Feng, Yuping; Fornell, Jordina; Zhang, Huiyan; Solsona, Pau; Barό, Maria Dolors; Suriñach, Santiago; Pellicer, Eva; Sort, Jordi

    2018-02-11

    Open cell foams consisting of Fe and Fe-Mn oxides are prepared from metallic Fe and Mn powder precursors by the replication method using porous polyurethane (PU) templates. First, reticulated PU templates are coated by slurry impregnation. The templates are then thermally removed at 260 °C and the debinded powders are sintered at 1000 °C under N₂ atmosphere. The morphology, structure, and magnetic properties are studied by scanning electron microscopy, X-ray diffraction and vibrating sample magnetometry, respectively. The obtained Fe and Fe-Mn oxide foams possess both high surface area and homogeneous open-cell structure. Hematite (α-Fe₂O₃) foams are obtained from the metallic iron slurry independently of the N₂ flow. In contrast, the microstructure of the FeMn-based oxide foams can be tailored by adjusting the N₂ flow. While the main phases for a N₂ flow rate of 180 L/h are α-Fe₂O₃ and FeMnO₃, the predominant phase for high N₂ flow rates (e.g., 650 L/h) is Fe₂MnO₄. Accordingly, a linear magnetization versus field behavior is observed for the hematite foams, while clear hysteresis loops are obtained for the Fe₂MnO₄ foams. Actually, the saturation magnetization of the foams containing Mn increases from 5 emu/g to 52 emu/g when the N₂ flow rate (i.e., the amount of Fe₂MnO₄) is increased. The obtained foams are appealing for a wide range of applications, such as electromagnetic absorbers, catalysts supports, thermal and acoustic insulation systems or wirelessly magnetically-guided porous objects in fluids.

  20. Clinical effectiveness and cost-effectiveness of foam sclerotherapy, endovenous laser ablation and surgery for varicose veins: results from the Comparison of LAser, Surgery and foam Sclerotherapy (CLASS) randomised controlled trial.

    Science.gov (United States)

    Brittenden, Julie; Cotton, Seonaidh C; Elders, Andrew; Tassie, Emma; Scotland, Graham; Ramsay, Craig R; Norrie, John; Burr, Jennifer; Francis, Jill; Wileman, Samantha; Campbell, Bruce; Bachoo, Paul; Chetter, Ian; Gough, Michael; Earnshaw, Jonothan; Lees, Tim; Scott, Julian; Baker, Sara A; MacLennan, Graeme; Prior, Maria; Bolsover, Denise; Campbell, Marion K

    2015-01-01

    BACKGROUND Foam sclerotherapy (foam) and endovenous laser ablation (EVLA) have emerged as alternative treatments to surgery for patients with varicose veins, but uncertainty exists regarding their effectiveness in the medium to longer term. OBJECTIVES To assess the clinical effectiveness and cost-effectiveness of foam, EVLA and surgery for the treatment of varicose veins. DESIGN A parallel-group randomised controlled trial (RCT) without blinding, and economic modelling evaluation. SETTING Eleven UK specialist vascular centres. PARTICIPANTS Seven hundred and ninety-eight patients with primary varicose veins (foam, n = 292; surgery, n = 294; EVLA, n = 212). INTERVENTIONS Patients were randomised between all three treatment options (eight centres) or between foam and surgery (three centres). PRIMARY OUTCOME MEASURES Disease-specific [Aberdeen Varicose Vein Questionnaire (AVVQ)] and generic [European Quality of Life-5 Dimensions (EQ-5D), Short Form questionnaire-36 items (SF-36) physical and mental component scores] quality of life (QoL) at 6 months. Cost-effectiveness as cost per quality-adjusted life-year (QALY) gained. SECONDARY OUTCOME MEASURES Quality of life at 6 weeks; residual varicose veins; Venous Clinical Severity Score (VCSS); complication rates; return to normal activity; truncal vein ablation rates; and costs. RESULTS The results appear generalisable in that participants' baseline characteristics (apart from a lower-than-expected proportion of females) and post-treatment improvement in outcomes were comparable with those in other RCTs. The health gain achieved in the AVVQ with foam was significantly lower than with surgery at 6 months [effect size -1.74, 95% confidence interval (CI) -2.97 to -0.50; p = 0.006], but was similar to that achieved with EVLA. The health gain in SF-36 mental component score for foam was worse than that for EVLA (effect size 1.54, 95% CI 0.01 to 3.06; p = 0.048) but similar to that for surgery. There were no

  1. Modeling foam delivery mechanisms in deep vadose-zone remediation using method of characteristics

    Energy Technology Data Exchange (ETDEWEB)

    Roostapour, A. [Craft and Hawkins Department of Petroleum Engineering, Louisiana State University, Baton Rouge, LA 70803 (United States); Kam, S.I., E-mail: kam@lsu.edu [Craft and Hawkins Department of Petroleum Engineering, Louisiana State University, Baton Rouge, LA 70803 (United States)

    2012-12-15

    Highlights: Black-Right-Pointing-Pointer A new mathematical framework established for vadose-zone foam remediation. Black-Right-Pointing-Pointer Graphical solutions presented by Method of Characteristics quantitatively. Black-Right-Pointing-Pointer Effects of design parameters in the field applications thoroughly investigated. Black-Right-Pointing-Pointer Implication of modeling study for successful field treatment discussed. - Abstract: This study investigates foam delivery mechanisms in vadose-zone remediation by using Method of Characteristics (MoC), a mathematical tool long been used for the analysis of miscible and immiscible flooding in porous media in petroleum industry. MoC converts the governing material-balance partial differential equations into a series of ordinary differential equations, and the resulting solutions are in a form of wave propagation (more specifically, for chemical species and phase saturations) through the system as a function of time and space. Deep vadose-zone remediation has special features compared to other conventional remediation applications. They include, not limited to, a high level of heterogeneity, a very dry initial condition with low water saturation (S{sub w}), pollutants such as metals and radionuclides fully dissolved in groundwater, and a serious concern about downward migration during the remediation treatments. For the vadose-zone remediation processes to be successful, the injected aqueous phase should carry chemicals to react with pollutants and precipitate them for immobilization and stabilization purposes. As a result, foams are believed to be an effective means, and understanding foam flow mechanism in situ is a key to the optimal design of field applications. Results show that foam delivery mechanism is indeed very complicated, making the optimum injection condition field-specific. The five major parameters selected (i.e., initial saturation of the medium, injection foam quality, surfactant adsorption, foam

  2. Modeling foam delivery mechanisms in deep vadose-zone remediation using method of characteristics

    International Nuclear Information System (INIS)

    Roostapour, A.; Kam, S.I.

    2012-01-01

    Highlights: ► A new mathematical framework established for vadose-zone foam remediation. ► Graphical solutions presented by Method of Characteristics quantitatively. ► Effects of design parameters in the field applications thoroughly investigated. ► Implication of modeling study for successful field treatment discussed. - Abstract: This study investigates foam delivery mechanisms in vadose-zone remediation by using Method of Characteristics (MoC), a mathematical tool long been used for the analysis of miscible and immiscible flooding in porous media in petroleum industry. MoC converts the governing material-balance partial differential equations into a series of ordinary differential equations, and the resulting solutions are in a form of wave propagation (more specifically, for chemical species and phase saturations) through the system as a function of time and space. Deep vadose-zone remediation has special features compared to other conventional remediation applications. They include, not limited to, a high level of heterogeneity, a very dry initial condition with low water saturation (S w ), pollutants such as metals and radionuclides fully dissolved in groundwater, and a serious concern about downward migration during the remediation treatments. For the vadose-zone remediation processes to be successful, the injected aqueous phase should carry chemicals to react with pollutants and precipitate them for immobilization and stabilization purposes. As a result, foams are believed to be an effective means, and understanding foam flow mechanism in situ is a key to the optimal design of field applications. Results show that foam delivery mechanism is indeed very complicated, making the optimum injection condition field-specific. The five major parameters selected (i.e., initial saturation of the medium, injection foam quality, surfactant adsorption, foam strength, and foam stability) are shown to be all important, interacting with each other. Results also

  3. Development of partially biodegradable foams from PP/HMSPP blends with natural and synthetic polymers; Desenvolvimento de espumas parcialmente biodegradaveis a partir de blendas de PP/HMSPP com polimeros naturais e sinteticos

    Energy Technology Data Exchange (ETDEWEB)

    Cardoso, Elizabeth Carvalho Leite

    2014-07-01

    Polymers are used in various application and in different industrial areas providing enormous quantities of wastes in environment. Among diverse components of residues in landfills are polymeric materials, including Polypropylene, which contribute with 20 to 30% of total volume of solid residues. As polymeric materials are immune to microbial degradation, they remain in soil and in landfills as a semi-permanent residue. Environmental concerning in litter reduction is being directed to renewable polymers development for manufacturing of polymeric foams. Foamed polymers are considered future materials, with a wide range of applications; high density structural foams are specially used in civil construction, in replacement of metal, woods and concrete with a final purpose of reducing materials costs. At present development, it was possible the incorporation of PP/HMSPP polymeric matrix blends with sugarcane bagasse, PHB and PLA, in structural foams production. Thermal degradation at 100, 120 and 160 deg C temperatures was not enough to induce biodegradability. Gamma irradiation degradation, at 50, 100, 200 and 500 kGy showed effective for biodegradability induction. Irradiated bagasse blends suffered surface erosion, in favor of water uptake and consequently, a higher biodegradation in bulk structure. (author)

  4. Making components with controlled metal deposition

    OpenAIRE

    Ribeiro, António Fernando

    1997-01-01

    Rapid Prototyping is a recent CAD/CAM/CIM based manufacturing technique which produces prototypes of components in a fraction of the time. This technique works by first drawing the part as a 3 Dimensional solid model using a CAD program and then ‘printing’ it in 3 Dimensions. The raw material can be a photopolymer or thermoplastic which solidifies when in contact with light. Other materials are available although 100% metal is not a very usual one. This paper presents a new approach for a ...

  5. Study of two-phase foam flow

    Energy Technology Data Exchange (ETDEWEB)

    Gurbanov, R S; Guliev, B B; Mekhtiev, K G; Kerimov, R G

    1970-01-01

    The objectives of this study were to determine characteristics of aqueous foam flow through porous media and to estimate the depth of foam penetration into a formation. Foam was generated by mixing air and 1% solution of surfactant PO-1. Foam density was maintained at 0.14 g/cc in all experiments. The foam was passed through sand columns (800 mm long x 30 mm diam) of permeabilities 26, 39, 80, 111, and 133 darcys. Flow rates were measured at various pressure drops and the relationship between system parameters was expressed analytically and graphically. From the data, distance of foam penetration into a formation as a function of pressure drop and permeability was calculated. The data indicate that under most conditions, foam will penetrate the formation to a negligible distance. This study indicates that when foam is used to remove sand from a well, a negligible loss of foam to the formation occurs.

  6. Capacitor with a composite carbon foam electrode

    Science.gov (United States)

    Mayer, Steven T.; Pekala, Richard W.; Kaschmitter, James L.

    1999-01-01

    Carbon aerogels used as a binder for granularized materials, including other forms of carbon and metal additives, are cast onto carbon or metal fiber substrates to form composite carbon thin film sheets. The thin film sheets are utilized in electrochemical energy storage applications, such as electrochemical double layer capacitors (aerocapacitors), lithium based battery insertion electrodes, fuel cell electrodes, and electrocapacitive deionization electrodes. The composite carbon foam may be formed by prior known processes, but with the solid partides being added during the liquid phase of the process, i.e. prior to gelation. The other forms of carbon may include carbon microspheres, carbon powder, carbon aerogel powder or particles, graphite carbons. Metal and/or carbon fibers may be added for increased conductivity. The choice of materials and fibers will depend on the electrolyte used and the relative trade off of system resistivity and power to system energy.

  7. Fabrication and Microstructure of Metal-Metal Syntactic Foams

    National Research Council Canada - National Science Library

    Nadler, J

    1998-01-01

    .... The composite microstructure consists of thin-wall, hollow Fe-Cr stainless steel spheres cast in various metal matrices including aluminum alloys 6061, 7075, 413, magnesium alloy AZ31B, and unalloyed...

  8. Ni-Pd-Al2O3 catalyst supported on reticulated ceramic foam for dry methane reforming

    Directory of Open Access Journals (Sweden)

    Vesna Nikolić

    2015-03-01

    Full Text Available In the present study, Ni-Pd/Al2O3 catalyst supported on α-Al2O3 based foam was prepared and evaluated in the dry methane reforming process. Corresponding metal chlorides were deposited to the foam surface by impregnation of the foam with ultrasonically aerosolized salt solutions at 473 K and drying at that temperature. Calcination step was excluded and the catalyst was reduced at very low temperature – 533 K. The reforming experiment lasted for 3 h, with standing time of 1 h at the following temperatures: 873, 973 and 1023 K. Conclusions on selectivity, catalytic activity and stability were reached on the basis of CO and H2 yields.

  9. Energetical fly ashes – separation and utilization of metallic valuable components

    Directory of Open Access Journals (Sweden)

    Michalíková Františka

    2000-12-01

    Full Text Available In the contribution, methods of separating metals – Fe, Al, Ge from energetic wastes – fly ashes are presented along with further possibilities of utilization of particular valuable components for industrial purposes.In the contribution, properties of energetic wastes are presented influencing the contents, separability, and utilizability of metal-bearing valuable components. From among physical properties these are grain size distribution and surface area. Chemical properties are characterized by elements contained in combusted coal whose content after combustion is increased 2 to 4 times, depending on the content of ash and combustible matters in original coal. Mineralogical properties of energetic wastes are determined by the combustion process conditions in the course of which mineral novelties are produced in concentrations suitable for separation.In the contribution, methods of separation and utilization of metals such as Fe, Al, Ge are described. From literature information on the processing of Fe component, as well as from results of experiments made at the Department of Mineral Processing and Environmental Protection, Technical University of Kosice follows that the highest concentration and mass yield of the component can be obtained from black coal fly ashes produced in smelting boilers. The content of Al in Slovak energetic wastes is lower than the 30 % Al2O3 limit that conditions an economic technological processing. Only in the case of black coal fly ash from TEKO Kosice and EVO Vojany was the Al2O3 content of 32.93 %. Therefore, in an indirect way – by separating the residues of uncombusted coal and magnetite Fe – the content of Al in fly ash was increased.For Ge, a principle of selective sizing has been utilized.A complex utilization of energetic wastes, that is the separation of metallic components, elimination of particular metals and the subsequent treatment of nonmetallic residue, should be an effective solution in various

  10. Investigation of Energy Absorption in Aluminum Foam Sandwich Panels By Drop Hammer Test: Experimental Results

    Directory of Open Access Journals (Sweden)

    Mohammad Nouri Damghani

    2016-05-01

    Full Text Available The sandwich panel structures with aluminum foam core and metal surfaces have light weight with high performance in dispersing energy. This has led to their widespread use in the absorption of energy. The cell structure of foam core is subjected to plastic deformation in the constant tension level that absorbs a lot of kinetic energy before destruction of the structure. In this research, by making samples of aluminum foam core sandwich panels with aluminum surfaces, experimental tests of low velocity impact by a drop machine are performed for different velocities and weights of projectile on samples of sandwich panels with aluminum foam core with relative density of 18%, 23%, and 27%. The output of device is acceleration‐time diagram which is shown by an accelerometer located on the projectile. From the experimental tests, the effect of weight, velocity and energy of the projectile and density of the foam on the global deformation, and energy decrease rate of projectile have been studied. The results of the experimental testes show that by increasing the density of aluminum foam, the overall impression is reduced and the slop of energy loss of projectile increases. Also by increasing the velocity of the projectile, the energy loss increases.

  11. Mass transfer measurements in foams

    International Nuclear Information System (INIS)

    Leblond, J.G.; Fournel, B.

    2004-01-01

    Full text of publication follows:This study participates to the elaboration of a method for decontamination of the inside surfaces of steel structures (pipes, tanks,...). The solution which has been chosen is to attack the surface of the structure by a dipping solution. In order to reduce the quantity of product to be recovered and treated at the end of the cleaning process, the active solution will be introduced as a foam. During its free or forced drainage the foam supplies an active liquid film along the structure surfaces. It was important to know if the transfers of the dipping liquid inside the foam and between foam and wall film are sufficient to allow a correct supplying of the active liquid at the wall and a correct dragging of the dipped products. The objective of this work is to develop a numerical model which simulates the various transfers. However such a modeling cannot be performed without a thorough knowledge of the different transfer parameters in the foam and in the film. The following study has been performed on a model foam (foaming water + air) held in a smooth vertical glass pipe and submitted to a forced drainage by the foaming water (water + surfactants). The liquid transfer involves the dispersion of the drainage liquid inside the foam and the transfer between the foam and the liquid film flowing down at the wall. The different transfers has been analyzed by NMR using a PFGSE-NMR sequence, which allows to determine the propagator, i.e., the probability density of the liquid particle displacements during a given time interval Δt, along a selected direction. This study allowed to measure, firstly, the mean liquid and the liquid dispersion in the foam along the vertical and horizontal direction, and secondly, the vertical mean velocity in the parietal liquid film. (authors)

  12. Polyimide Foams Offer Superior Insulation

    Science.gov (United States)

    2012-01-01

    At Langley Research Center, Erik Weiser and his colleagues in the Advanced Materials and Processing Branch were working with a new substance for fabricating composites for use in supersonic aircraft. The team, however, was experiencing some frustration. Every time they tried to create a solid composite from the polyimide (an advanced polymer) material, it bubbled and foamed. It seemed like the team had reached a dead end in their research - until they had another idea. "We said, This isn t going to work for composites, but maybe we could make a foam out of it," Weiser says. "That was kind of our eureka moment, to see if we could go in a whole other direction. And it worked." Weiser and his colleagues invented a new kind of polyimide foam insulation they named TEEK. The innovation displayed a host of advantages over existing insulation options. Compared to other commercial foams, Weiser explains, polyimide foams perform well across a broad range of temperatures, noting that the NASA TEEK foams provide effective structural insulation up to 600 F and down to cryogenic temperatures. The foam does not burn or off-gas toxic fumes, and even at -423 F - the temperature of liquid hydrogen - the material stays flexible. The inventors could produce the TEEK foam at a range of densities, from 0.5 pounds per cubic foot up to 20 pounds per cubic foot, making the foam ideal for a range of applications, including as insulation for reusable launch vehicles and for cryogenic tanks and lines. They also developed a unique, friable balloon format for manufacturing the foam, producing it as hollow microspheres that allowed the foam to be molded and then cured into any desired shape - perfect for insulating pipes of different sizes and configurations. The team s originally unplanned invention won an "R&D 100" award, and a later form of the foam, called LaRC FPF-44 (Spinoff 2009), was named "NASA Invention of the Year" in 2007.

  13. Foaming in manure based digesters: Effect of overloading and foam suppression using antifoam agents

    OpenAIRE

    Kougias, Panagiotis; Tsapekos, Panagiotis; Boe, Kanokwan; Angelidaki, Irini

    2013-01-01

    Anaerobic digestion foaming is one of the major problems that occasionally occur in full-scale biogas plants, affecting negatively the overall digestion process. The foam is typically created either in the main biogas reactor or/and in the pre-storage tank and the entrapped solids in the foam cause severe operational problems, such as blockage of mixing devices and collapse of pumps. Furthermore, the foaming problem is linked with economic consequences for biogas plants, due to income losses ...

  14. Influence of Rubber Powders on Foaming Behavior and Mechanical Properties of Foamed Polypropylene Composites

    Directory of Open Access Journals (Sweden)

    HE Yue

    2017-02-01

    Full Text Available Polypropylene/rubber powders composites with different kinds of rubber powders were foamed by injection molding machine equipped with volume-adjustable cavity. The effect of dispersity of rubber powders and crystallization behavior of composites on the foaming behavior and mechanical properties was investigated. The results show that the addition of rubber powders can improve the cell structure of foamed PP with fine and uniform cell distribution. And cell density and size of PP/PP-MAH/NBR foams are 7.64×106cell/cm3 and 29.78μm respectively, which are the best among these foams. Combining cell structures with mechanical properties, notch impact strength of PP/PP-MAH/CNBR composites increases approximately by 2.2 times while tensile strength is reduced just by 26% compared with those of the pure PP. This indicates that PP/PP-MAH/CNBR composites are ideal foamed materials.

  15. Chaotic bubbling and nonstagnant foams.

    Science.gov (United States)

    Tufaile, Alberto; Sartorelli, José Carlos; Jeandet, Philippe; Liger-Belair, Gerard

    2007-06-01

    We present an experimental investigation of the agglomeration of bubbles obtained from a nozzle working in different bubbling regimes. This experiment consists of a continuous production of bubbles from a nozzle at the bottom of a liquid column, and these bubbles create a two-dimensional (2D) foam (or a bubble raft) at the top of this column. The bubbles can assemble in various dynamically stable arrangement, forming different kinds of foams in a liquid mixture of water and glycerol, with the effect that the bubble formation regimes influence the foam obtained from this agglomeration of bubbles. The average number of bubbles in the foam is related to the bubble formation frequency and the bubble mean lifetime. The periodic bubbling can generate regular or irregular foam, while a chaotic bubbling only generates irregular foam.

  16. Determination of Acreage Thermal Protection Foam Loss From Ice and Foam Impacts

    Science.gov (United States)

    Carney, Kelly S.; Lawrence, Charles

    2015-01-01

    A parametric study was conducted to establish Thermal Protection System (TPS) loss from foam and ice impact conditions similar to what might occur on the Space Launch System. This study was based upon the large amount of testing and analysis that was conducted with both ice and foam debris impacts on TPS acreage foam for the Space Shuttle Project External Tank. Test verified material models and modeling techniques that resulted from Space Shuttle related testing were utilized for this parametric study. Parameters varied include projectile mass, impact velocity and impact angle (5 degree and 10 degree impacts). The amount of TPS acreage foam loss as a result of the various impact conditions is presented.

  17. A review of aqueous foam in microscale.

    Science.gov (United States)

    Anazadehsayed, Abdolhamid; Rezaee, Nastaran; Naser, Jamal; Nguyen, Anh V

    2018-06-01

    In recent years, significant progress has been achieved in the study of aqueous foams. Having said this, a better understanding of foam physics requires a deeper and profound study of foam elements. This paper reviews the studies in the microscale of aqueous foams. The elements of aqueous foams are interior Plateau borders, exterior Plateau borders, nodes, and films. Furthermore, these elements' contribution to the drainage of foam and hydraulic resistance are studied. The Marangoni phenomena that can happen in aqueous foams are listed as Marangoni recirculation in the transition region, Marangoni-driven flow from Plateau border towards the film in the foam fractionation process, and Marangoni flow caused by exposure of foam containing photosurfactants under UV. Then, the flow analysis of combined elements of foam such as PB-film along with Marangoni flow and PB-node are studied. Next, we contrast the behavior of foams in different conditions. These various conditions can be perturbation in the foam structure caused by injected water droplets or waves or using a non-Newtonian fluid to make the foam. Further review is about the effect of oil droplets and particles on the characteristics of foam such as drainage, stability and interfacial mobility. Copyright © 2018 Elsevier B.V. All rights reserved.

  18. Characterization of Ti-6Al-4V open cellular foams fabricated by additive manufacturing using electron beam melting

    International Nuclear Information System (INIS)

    Murr, L.E.; Gaytan, S.M.; Medina, F.; Martinez, E.; Martinez, J.L.; Hernandez, D.H.; Machado, B.I.; Ramirez, D.A.; Wicker, R.B.

    2010-01-01

    Ti-6Al-4V open cellular foams were fabricated by additive manufacturing using electron beam melting (EBM). Foam models were developed from CT-scans of aluminum open cellular foams and embedded in CAD for EBM. These foams were fabricated with solid cell structures as well as hollow cell structures and exhibit tailorable stiffness and strength. The strength in proportion to the measured microindentation hardness is as much as 40% higher for hollow cell (wall) structures in contrast to solid, fully dense EBM fabricated components. Plots of relative stiffness versus relative density were in good agreement with the Gibson-Ashby model for open cellular foam materials. Stiffness or Young's modulus values measured using a resonant frequency-damping analysis technique were found to vary inversely with porosity especially for solid cell wall, open cellular structure foams. These foams exhibit the potential for novel biomedical, aeronautics, and automotive applications.

  19. Beer foam physics

    NARCIS (Netherlands)

    Ronteltap, A.D.

    1989-01-01

    The physical aspects of beer foam behavior were studied in terms of the four physical processes, mainly involved in the formation and breakdown of foam. These processes are, bubble formation, drainage, disproportionation and coalescence. In detail, the processes disproportionation and

  20. Anti-foam System design description

    International Nuclear Information System (INIS)

    White, M.A.

    1994-01-01

    The Anti-foam System is a sub-system of the 242-A Evaporator facility. The Anti-foam is used within the C-A-1 Vapor-Liquid Separator, to reduce the effect of foaming and reduce fluid bumping while the vapor and liquid are separated within the C-A-1 Vapor-Liquid Separator. Excessive foaming within the vessel may possibly cause the liquid slurry mixture in the evaporator vessel to foul the de-entrainment pads and cause plant shutdown. The Anti-foam System consists of the following primary elements: the Anti-foam Tank and the Metering Pump. The upgrades to Anti-foam System include the following: installation of a new pump, instruments, and valves; and connection of the instruments, pump and agitator associated with the Anti-foam System to the Monitoring and Control System (MCS). The 242-A Evaporator is a waste treatment facility designed to reduce liquid waste volumes currently stored in the Hanford Area double shell Waste Storage Tanks. The evaporator uses evaporative concentration to achieve this volume reduction, returning the concentrated slurry to the double-shell tanks for storage and, at the same time, releasing the process effluent to a retention facilities for eventual treatment and release to the environment

  1. Modeling Manufacturing Impacts on Aging and Reliability of Polyurethane Foams

    Energy Technology Data Exchange (ETDEWEB)

    Rao, Rekha R.; Roberts, Christine Cardinal; Mondy, Lisa Ann; Soehnel, Melissa Marie; Johnson, Kyle; Lorenzo, Henry T.

    2016-10-01

    Polyurethane is a complex multiphase material that evolves from a viscous liquid to a system of percolating bubbles, which are created via a CO2 generating reaction. The continuous phase polymerizes to a solid during the foaming process generating heat. Foams introduced into a mold increase their volume up to tenfold, and the dynamics of the expansion process may lead to voids and will produce gradients in density and degree of polymerization. These inhomogeneities can lead to structural stability issues upon aging. For instance, structural components in weapon systems have been shown to change shape as they age depending on their molding history, which can threaten critical tolerances. The purpose of this project is to develop a Cradle-to-Grave multiphysics model, which allows us to predict the material properties of foam from its birth through aging in the stockpile, where its dimensional stability is important.

  2. High performance polymeric foams

    International Nuclear Information System (INIS)

    Gargiulo, M.; Sorrentino, L.; Iannace, S.

    2008-01-01

    The aim of this work was to investigate the foamability of high-performance polymers (polyethersulfone, polyphenylsulfone, polyetherimide and polyethylenenaphtalate). Two different methods have been used to prepare the foam samples: high temperature expansion and two-stage batch process. The effects of processing parameters (saturation time and pressure, foaming temperature) on the densities and microcellular structures of these foams were analyzed by using scanning electron microscopy

  3. 3D morphological analysis of copper foams as current collectors for Li-ion batteries by means of X-ray tomography

    Energy Technology Data Exchange (ETDEWEB)

    Etiemble, A. [Institut National des Sciences Appliquées de Lyon, Laboratoire MATEIS, F-69621 Villeurbanne (France); Institut National de la Recherche Scientifique – Centre Énergie, Matériaux, Télécommunications, Varennes, Québec J3X 1S2 (Canada); Adrien, J. [Institut National des Sciences Appliquées de Lyon, Laboratoire MATEIS, F-69621 Villeurbanne (France); Maire, E., E-mail: eric.maire@insa-lyon.fr [Institut National des Sciences Appliquées de Lyon, Laboratoire MATEIS, F-69621 Villeurbanne (France); Idrissi, H. [Institut National des Sciences Appliquées de Lyon, Laboratoire MATEIS, F-69621 Villeurbanne (France); Reyter, D. [Institut National de la Recherche Scientifique – Centre Énergie, Matériaux, Télécommunications, Varennes, Québec J3X 1S2 (Canada); Roué, L., E-mail: roue@emt.inrs.ca [Institut National de la Recherche Scientifique – Centre Énergie, Matériaux, Télécommunications, Varennes, Québec J3X 1S2 (Canada)

    2014-09-15

    Highlights: • X-ray tomography analysis of open-cell copper foams is performed. • The effect of a dissolution treatment on the foam morphology is highlighted. • The interest of such Cu foams as current collectors for Li-ion batteries is discussed. - Abstract: As-received and chemically treated copper foams were characterized by means of laboratory X-ray tomography with a resolution of 0.5 μm. 3D image processing and analysis allowed the morphological parameters (size, sphericity, tortuosity etc.) of the pores and copper skeleton to be determined. The chemical dissolution of the Cu foam in an acid hydrogen peroxide solution results in an increase of the open pore size (from 54 to 93 μm) and a decrease of the foam thickness (from 140 to 115 μm). With an open porosity of 81.8% and a specific surface area as high as 280,000 (49,000) m{sup 2}/m{sup 3} of Cu (foam), the chemically-treated Cu foam appears very attractive for use as a 3D current collector for metal (e.g. Si) based anodes for Li-ion batteries.

  4. Efficient removal of perfluorooctane sulfonate from aqueous film-forming foam solution by aeration-foam collection.

    Science.gov (United States)

    Meng, Pingping; Deng, Shubo; Maimaiti, Ayiguli; Wang, Bin; Huang, Jun; Wang, Yujue; Cousins, Ian T; Yu, Gang

    2018-07-01

    Aqueous film-forming foams (AFFFs) used in fire-fighting are one of the main contamination sources of perfluorooctane sulfonate (PFOS) to the subterranean environment, requiring high costs for remediation. In this study, a method that combined aeration and foam collection was presented to remove PFOS from a commercially available AFFF solution. The method utilized the strong surfactant properties of PFOS that cause it to be highly enriched at air-water interfaces. With an aeration flow rate of 75 mL/min, PFOS removal percent reached 96% after 2 h, and the PFOS concentration in the collected foam was up to 6.5 mmol/L, beneficial for PFOS recovery and reuse. Increasing the aeration flow rate, ionic strength and concentration of co-existing surfactant, as well as decreasing the initial PFOS concentration, increased the removal percents of PFOS by increasing the foam volume, but reduced the enrichment of PFOS in the foams. With the assistance of a co-existing hydrocarbon surfactant, PFOS removal percent was above 99.9% after aeration-foam collection for 2 h and the enrichment factor exceeded 8400. Aeration-foam collection was less effective for short-chain perfluoroalkyl substances due to their relatively lower surface activity. Aeration-foam collection was found to be effective for the removal of high concentrations of PFOS from AFFF-contaminated wastewater, and the concentrated PFOS in the collected foam can be reused. Copyright © 2018 Elsevier Ltd. All rights reserved.

  5. Preparation and characterization of PMMA graded microporous foams via one-step supercritical carbon dioxide foaming

    International Nuclear Information System (INIS)

    Yuan Huan; Li Junguo; Xiong Yuanlu; Luo Guoqiang; Shen Qiang; Zhang Lianmeng

    2013-01-01

    Supercritical carbon dioxide (ScCO 2 ) foaming which is inexpensive and environmental friendly has been widely used to prepare polymer-based microporous materials. In this paper, PMMA graded microporous materials were foamed by PMMA matrix after an unstable saturation process which was done under supercritical condition of 28MPa and 50 °C. The scanning electron microscopy (SEM) was utilized to observe the morphology of the graded foam. A gas adsorption model was proposed to predict the graded gas concentration in the different region of the polymer matrix. The SEM results showed that the solid and foam region of the graded foam can be connected without laminated layers. With the increasing thickness position of the graded microporous foam, the cell size increased from 3.4 to 27.5 μm, while the cell density decreased from 1.04 × 10 9 to 1.96 × 10 7 cells/cm 3 . It also found that the gradient microporous structure of the foam came from graded gas concentration which was obtained in the initial saturation process.

  6. Development of foams from linear polypropylene (PP) and high melt strength polypropylene (HMSPP) polymeric blends

    International Nuclear Information System (INIS)

    Cardoso, Elisabeth Carvalho Leite

    2009-01-01

    Scanning Electron Microscope (SEM). Micrographs obtained pointed to closed cells foams, in which the pressure is kept during all cell formation stage, informing that closed cells foams are used in thermal insulation in Civil Construction and in thermal vials. Density analyses accomplished in foams produced in our work showed typical results for high density foams (320 to 800 kg/m3 range), around 500 kg/m3, used for wire and cables and for structural purposes (structural foams), by replacing wood, metals or solid plastics. Structural foams have high density (above 320 kg/m3) and cellular structures are specially composed by holes. (author)

  7. Numerical Modeling of Foam Drilling Hydraulics

    Directory of Open Access Journals (Sweden)

    Ozcan Baris

    2007-12-01

    Full Text Available The use of foam as a drilling fluid was developed to meet a special set of conditions under which other common drilling fluids had failed. Foam drilling is defined as the process of making boreholes by utilizing foam as the circulating fluid. When compared with conventional drilling, underbalanced or foam drilling has several advantages. These advantages include: avoidance of lost circulation problems, minimizing damage to pay zones, higher penetration rates and bit life. Foams are usually characterized by the quality, the ratio of the volume of gas, and the total foam volume. Obtaining dependable pressure profiles for aerated (gasified fluids and foam is more difficult than for single phase fluids, since in the former ones the drilling mud contains a gas phase that is entrained within the fluid system. The primary goal of this study is to expand the knowledge-base of the hydrodynamic phenomena that occur in a foam drilling operation. In order to gain a better understanding of foam drilling operations, a hydrodynamic model is developed and run at different operating conditions. For this purpose, the flow of foam through the drilling system is modeled by invoking the basic principles of continuum mechanics and thermodynamics. The model was designed to allow gas and liquid flow at desired volumetric flow rates through the drillstring and annulus. Parametric studies are conducted in order to identify the most influential variables in the hydrodynamic modeling of foam flow.

  8. Applications of Foamed Lightweight Concrete

    Directory of Open Access Journals (Sweden)

    Mohd Sari Kamarul Aini

    2017-01-01

    Full Text Available Application of foamed concrete is increasing at present due to high demand on foamed concrete structures with good mechanical and physical properties. This paper discusses on the use of basic raw materials, their characteristics, production process, and their application in foamed lightweight concrete with densities between 300 kg/m3 and 1800 kg/m3. It also discusses the factors that influence the strengths and weaknesses of foamed concrete based on studies that were conducted previously.

  9. The influence of polyol type on cell geometry and the thermal stability of polyurethane foams

    Directory of Open Access Journals (Sweden)

    Prendžov Slobodan J.

    2006-01-01

    Full Text Available The aim of this study was to examine the influence of substituting defined amounts of polyol Voranol 3322 by polyol Voranol CP 1055 on the cell geometry and thermal stability of the synthesized flexible polyurethane foams. The influence of the amount of antipyrene on the cell geometry and their thermal stability was also investigated. The following components were used in the synthesis of the polyurethanes: a mixture of two polyols (Voranol 3322 with the hydroxyl number 47 mg KOH/g, mean molecular mass 3400 and Voranol CP 1055 with the hydroxyl number 156 mg KOH/g, mean molecular mass 1000, toluene discarnate as the isocyanate component, a combination of an organic-metallic compound and a tertiary amine as catalysts, surfactant and water as the coreactant. The thermal stability was determined by thermogravimetric analysis (in a nitrogen atmosphere. The cell geometry was analyzed by optical microscopy. Examination of the cell geometry revealed different cell shapes. The form factor as an indicator of cell deviation from spherical shape increased (more round forms were observed with increasing amount of Voranol CP 1055. The TG examination showed that specimens with 6 and 8 g of Voranol 3322 substituted by Voranol CP 1055 completely degraded at 350 °C, while foams with 10 and 12 g of Voranol 3322 substituted by Voranol CP 1055 displayed lower mass loss at higher temperatures and had residual masses of 46 % and 43 % at 600°C respectively. The addition of antipyrene in an amount of 1% (based on the amount of polyol contributed to improved thermal stability, no visible color change of the specimen tested at 210°C for 40 minutes, and to rounder cell forms. Considering the obtained results it can be concluded that an increase in the amount of Voranol CP 1055 yielded more spherically shaped cells and better thermal stability of the synthesized flexible polyurethane foams. The addition of antipyrene improves the thermal stability and the cell geometry.

  10. Recovery and recycling of aluminum, copper, and precious metals from dismantled weapon components

    International Nuclear Information System (INIS)

    Gundiler, I.H.; Lutz, J.D.; Wheelis, W.T.

    1994-01-01

    Sandia National Laboratories (SNL) is tasked to support The Department of Energy in the dismantlement and disposal of SNL designed weapon components. These components are sealed in a potting compound, and contain heavy metals, explosive, radioactive, and toxic materials. SNL developed a process to identify and remove the hazardous sub-components utilizing real-time radiography and abrasive water-jet cutting. The components were then crushed, granulated, screened, and separated into an aluminum and a precious-and-base-metals fraction using air-tables. Plastics were further cleaned for disposal as non-hazardous waste. New Mexico Bureau of Mines and Mineral Resources assisted SNL in investigation of size-reduction and separation technologies

  11. Effect of foam stirrer design on the catalytic performance of rotating foam stirrer reactions

    NARCIS (Netherlands)

    Leon Matheus, M.A.; Geers, P.; Nijhuis, T.A.; Schaaf, van der J.; Schouten, J.C.

    2012-01-01

    The liquid–solid mass transfer rate in a rotating foam stirrer reactor and in a slurry reactor is studied using the hydrogenation of styrene as a model reaction. The rotating foam stirrer reactor is a novel type of multi-phase reactor where highly open-celled materials, solid foams, are used as a

  12. Preparation and properties of a novel macro porous Ni2+-imprinted chitosan foam adsorbents for adsorption of nickel ions from aqueous solution.

    Science.gov (United States)

    Guo, Na; Su, Shi-Jun; Liao, Bing; Ding, Sang-Lan; Sun, Wei-Yi

    2017-06-01

    In this study, novel macro porous Ni 2+ -imprinted chitosan foam adsorbents (F-IIP) were prepared using sodium bicarbonate and glycerine to obtain a porogen for adsorbing nickel ions from aqueous solutions. The use of the ion-imprinting technique for adsorbents preparation improved the nickel ion selectivity and adsorption capacity. We characterised the imprinted porous foam adsorbents in terms of the effects of the initial pH value, initial metal ion concentration, and contact time on the adsorption of nickel ions. The adsorption process was described best by Langmuir monolayer adsorption models, and the maximum adsorption capacity calculated from the Langmuir equation was 69.93mgg -1 . The kinetic data could be fitted to a pseudo-second-order equation. Our analysis of selective adsorption demonstrated the excellent preference of the F-IIP foams for nickel ions compared with other coexisting metal ions. Furthermore, tests over five cycle runs suggested that the F-IIP foam adsorbents had good durability and efficiency. Copyright © 2017 Elsevier Ltd. All rights reserved.

  13. The mechanical behavior of microcellular foams

    Energy Technology Data Exchange (ETDEWEB)

    Ozkul, M.H.; Mark, J.E. (Cincinnati Univ., OH (USA)); Aubert, J.H. (Sandia National Labs., Albuquerque, NM (USA))

    1990-01-01

    The mechanical behavior of microcellular open-cell foams prepared by a thermally induced phase separation process are investigated. The foams studied were prepared from isotactic polystyrene, polyacrylonitrile, and poly(4-methyl-1-pentene) (rigid foams), and polyurethane and Lycra (elastomeric foams). Their densities were in the range 0.04--0.27 g/cm3. Conventional polystyrene foams were used for comparison. The moduli and collapse stresses of these foams were measured in compression and compared with the current constitutive laws which relate mechanical properties to densities. A reinforcement technique based on the in-situ precipitation of silica was used to improve the mechanical properties. 13 refs., 4 figs., 3 tabs.

  14. Effect of silica nanoparticles on polyurethane foaming process and foam properties

    International Nuclear Information System (INIS)

    Francés, A B; Bañón, M V Navarro

    2014-01-01

    Flexible polyurethane foams (FPUF) are commonly used as cushioning material in upholstered products made on several industrial sectors: furniture, automotive seating, bedding, etc. Polyurethane is a high molecular weight polymer based on the reaction between a hydroxyl group (polyol) and isocyanate. The density, flowability, compressive, tensile or shearing strength, the thermal and dimensional stability, combustibility, and other properties can be adjusted by the addition of several additives. Nanomaterials offer a wide range of possibilities to obtain nanocomposites with specific properties. The combination of FPUF with silica nanoparticles could develop nanocomposite materials with unique properties: improved mechanical and thermal properties, gas permeability, and fire retardancy. However, as silica particles are at least partially surface-terminated with Si-OH groups, it was suspected that the silica could interfere in the reaction of poyurethane formation.The objective of this study was to investigate the enhancement of thermal and mechanical properties of FPUF by the incorporation of different types of silica and determining the influence thereof during the foaming process. Flexible polyurethane foams with different loading mass fraction of silica nanoparticles (0-1% wt) and different types of silica (non treated and modified silica) were synthesized. PU/SiO 2 nanocomposites were characterized by FTIR spectroscopy, TGA, and measurements of apparent density, resilience and determination of compression set. Addition of silica nanoparticles influences negatively in the density and compression set of the foams. However, resilience and thermal stability of the foams are improved. Silica nanoparticles do not affect to the chemical structure of the foams although they interfere in the blowing reaction

  15. Anaerobic Digestion Foaming Causes

    OpenAIRE

    Ganidi, Nafsika

    2008-01-01

    Anaerobic digestion foaming has been encountered in several sewage treatment plants in the UK. Foaming has raised major concerns for the water utilities due to significant impacts on process efficiency and operational costs. Several foaming causes have been suggested over the past few years by researchers. However, the supporting experimental information is limited and in some cases site specific. The present report aimed to provide a better understanding of the anaerobic di...

  16. Foam-forming properties of Ilex paraguariensis (mate saponin: foamability and foam lifetime analysis by Weibull equation

    Directory of Open Access Journals (Sweden)

    Janine Treter

    2010-01-01

    Full Text Available Saponins are natural soaplike foam-forming compounds widely used in foods, cosmetic and pharmaceutical preparations. In this work foamability and foam lifetime of foams obtained from Ilex paraguariensis unripe fruits were analyzed. Polysorbate 80 and sodium dodecyl sulfate were used as reference surfactants. Aiming a better data understanding a linearized 4-parameters Weibull function was proposed. The mate hydroethanolic extract (ME and a mate saponin enriched fraction (MSF afforded foamability and foam lifetime comparable to the synthetic surfactants. The linearization of the Weibull equation allowed the statistical comparison of foam decay curves, improving former mathematical approaches.

  17. Fire retardant polyisocyanurate foam

    Science.gov (United States)

    Riccitiello, S. R.; Parker, J. A.

    1972-01-01

    Fire retardant properties of low density polymer foam are increased. Foam has pendant nitrile groups which form thermally-stable heterocyclic structures at temperature below degradation temperature of urethane linkages.

  18. Nanostructured Titanium-10 wt% 45S5 Bioglass-Ag Composite Foams for Medical Applications

    Directory of Open Access Journals (Sweden)

    Karolina Jurczyk

    2015-03-01

    Full Text Available The article presents an investigation on the effectiveness of nanostructured titanium-10 wt% 45S5 Bioglass-1 wt% Ag composite foams as a novel class of antibacterial materials for medical applications. The Ti-based composite foams were prepared by the combination of mechanical alloying and a “space-holder” sintering process. In the first step, the Ti-10 wt% 45S5 Bioglass-1 wt% Ag powder synthesized by mechanical alloying and annealing mixed with 1.0 mm diameter of saccharose crystals was finally compacted in the form of pellets. In the next step, the saccharose crystals were dissolved in water, leaving open spaces surrounded by metallic-bioceramic scaffold. The sintering of the scaffold leads to foam formation. It was found that 1:1 Ti-10 wt% 45S5 Bioglass-1 wt% Ag/sugar ratio leads to porosities of about 70% with pore diameter of about 0.3–1.1 mm. The microstructure, corrosion resistance in Ringer’s solution of the produced foams were investigated. The value of the compression strength for the Ti-10 wt% 45S5 Bioglass-1 wt% Ag foam with 70% porosity was 1.5 MPa and the Young’s modulus was 34 MPa. Silver modified Ti-10 wt% 45S5 Bioglass composites possess excellent antibacterial activities against Staphylococcus aureus. Porous Ti-10 wt% 45S5 Bioglass-1 wt% foam could be a possible candidate for medical implants applications.

  19. Foam flow in a model porous medium: I. The effect of foam coarsening.

    Science.gov (United States)

    Jones, S A; Getrouw, N; Vincent-Bonnieu, S

    2018-05-09

    Foam structure evolves with time due to gas diffusion between bubbles (coarsening). In a bulk foam, coarsening behaviour is well defined, but there is less understanding of coarsening in confined geometries such as porous media. Previous predictions suggest that coarsening will cause foam lamellae to move to low energy configurations in the pore throats, resulting in greater capillary resistance when restarting flow. Foam coarsening experiments were conducted in both a model-porous-media micromodel and in a sandstone core. In both cases, foam was generated by coinjecting surfactant solution and nitrogen. Once steady state flow had been achieved, the injection was stopped and the system sealed off. In the micromodel, the foam coarsening was recorded using time-lapse photography. In the core flood, the additional driving pressure required to reinitiate flow after coarsening was measured. In the micromodel the bubbles coarsened rapidly to the pore size. At the completion of coarsening the lamellae were located in minimum energy configurations in the pore throats. The wall effect meant that the coarsening did not conform to the unconstricted growth laws. The coreflood tests also showed coarsening to be a rapid process. The additional driving pressure to restart flow reached a maximum after just 2 minutes.

  20. Foaming in manure based digesters: Effect of overloading and foam suppression using antifoam agents

    DEFF Research Database (Denmark)

    Kougias, Panagiotis; Tsapekos, Panagiotis; Boe, Kanokwan

    Anaerobic digestion foaming is one of the major problems that occasionally occur in full-scale biogas plants, affecting negatively the overall digestion process. The foam is typically created either in the main biogas reactor or/and in the pre-storage tank and the entrapped solids in the foam cause...... severe operational problems, such as blockage of mixing devices and collapse of pumps. Furthermore, the foaming problem is linked with economic consequences for biogas plants, due to income losses derived from the reduced biogas production, extra labour work and additional maintenance costs. Moreover....... A continuous stirred tank reactor, operating under thermophilic conditions (55 oC) was fed with cattle manure. In order to investigate the effect of organic overloading on foam formation, a stepwise increase of the organic loading rate was performed by the addition of glucose in the feeding substrate. Biogas...

  1. Biosorption of Metals from Multi-Component Bacterial Solutions

    CERN Document Server

    Tsertsvadze, L A; Petriashvili, Sh G; Chutkerashvili, D G; Kirkesali, E I; Frontasyeva, M V; Pavlov, S S; Gundorina, S F

    2002-01-01

    The method of extraction of metals from industrial solutions by means of economical and easy to apply biosorbents in subtropics such as products of tea manufacturing, moss, microorganisms is described. The multi-component solutions obtained in the process of leaching of ores, rocks and industrial wastes by peat suspension were used in the experiments. The element composition of sorbent biomass and solutions was investigated by epithermal neutron activation analysis and by atomic absorption spectrometry. The results obtained evidence that the used biosorbents are applicable for extraction of the whole set of heavy metals and actinides (U, Th, Cu, Mn, Fe, Pb, Li, Rb, Sr, Cd, As, Co and others) from industrial solutions.

  2. Determination of SiC ceramic foams microstructure properties by X-rays microtomography

    International Nuclear Information System (INIS)

    Nagata, Rodrigo; Appoloni, Carlos Roberto; Fernandes, Jaquiel Salvi

    2009-01-01

    Silicon carbide ceramic foams (SiC) can operate at high temperatures, which allow them to be used as heat exchangers, liquid metal filters, composite of rocket nozzles, etc. For many of these applications it is very important to know the foams' porosity. In this work the porosity of SiC ceramic foams was determined by X-rays microtomography, a powerful non-destructive technique that allows the analysis of the sample's internal structure. The samples have pore densities of 30, 45, 60, 80 and 100 pores per inch (ppi). The spatial resolution obtained was 24.8 μm. The cross sections' reconstruction was performed with a cone beam filtered backprojection algorithm. In the analyses, micropores were observed in the foam's lattice wire of the 30 ppi and 45 ppi samples. Micropores were present in few cross sections of 60 ppi sample too, but it was not found in the 80 ppi and 100 ppi samples. The total porosities obtained were Φ = (88.8 ± 4.3) %, Φ = (85.2 ± 1.4) %, Φ = (82.3 ± 1.8) %, Φ (79.9 ± 1.3) % and Φ = (80.4 ± 1.5) %, for the 30, 45, 60, 80 and 100 ppi samples, respectively. (author)

  3. Effect of Bonding Pressure and Bonding Time on the Tensile Properties of Cu-Foam / Cu-Plate Diffusion Bonded Joint

    International Nuclear Information System (INIS)

    Kim, Sang-Ho; Heo, Hoe-Jun; Kang, Chung-Yun; Yoon, Tae-Jin

    2016-01-01

    Open cell Cu foam, which has been widely utilized in various industries because of its high thermal conductivity, lightweight and large surface area, was successfully joined with Cu plate by diffusion bonding. To prevent excessive deformation of the Cu foam during bonding process, the bonding pressure should be lower than 500 kPa at 800 ℃ for 60 min and bonding pressure should be lowered with increasing holding time. The bonding strength was evaluated by tensile tests. The tensile load of joints increased with the bonding pressure and holding time. In the case of higher bonding pressure or time, the bonded length at the interface was usually longer than the cross-sectional length of the foam, so fracture occurred at the foam. For the same reason, base metal (foam) fracture mainly occurred at the node-plate junction rather than in the strut-plate junction because the bonded surface area of the node was relatively larger than that of the strut.

  4. 46 CFR 108.463 - Foam rate: Protein.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 4 2010-10-01 2010-10-01 false Foam rate: Protein. 108.463 Section 108.463 Shipping... EQUIPMENT Fire Extinguishing Systems Foam Extinguishing Systems § 108.463 Foam rate: Protein. (a) If the outlets of a protein foam extinguishing system are in a space, the foam rate at each outlet must be at...

  5. Foaming Glass Using High Pressure Sintering

    DEFF Research Database (Denmark)

    Østergaard, Martin Bonderup; Petersen, Rasmus Rosenlund; König, Jakob

    Foam glass is a high added value product which contributes to waste recycling and energy efficiency through heat insulation. The foaming can be initiated by a chemical or physical process. Chemical foaming with aid of a foaming agent is the dominant industrial process. Physical foaming has two...... to expand. After heat-treatment foam glass can be obtained with porosities of 80–90 %. In this study we conduct physical foaming of cathode ray tube (CRT) panel glass by sintering under high pressure (5-25 MPa) using helium, nitrogen, or argon at 640 °C (~108 Pa s). Reheating a sample in a heating...... variations. One way is by saturation of glass melts with gas. The other involves sintering of powdered glass under a high gas pressure resulting in glass pellets with high pressure bubbles entrapped. Reheating the glass pellets above the glass transition temperature under ambient pressure allows the bubbles...

  6. Structural Foams of Biobased Isosorbide-Containing Copolycarbonate

    Directory of Open Access Journals (Sweden)

    Stefan Zepnik

    2017-01-01

    Full Text Available Isosorbide-containing copolycarbonate (Bio-PC is a partly biobased alternative to conventional bisphenol A (BPA based polycarbonate (PC. Conventional PC is widely used in polymer processing technologies including thermoplastic foaming such as foam injection molding. At present, no detailed data is available concerning the foam injection molding behavior and foam properties of Bio-PC. This contribution provides first results on injection-molded foams based on isosorbide-containing PC. The structural foams were produced by using an endothermic chemical blowing agent (CBA masterbatch and the low pressure foam injection molding method. The influence of weight reduction and blowing agent concentration on general foam properties such as density, morphology, and mechanical properties was studied. The test specimens consist of a foam core in the center and compact symmetrical shell layers on the sides. The thickness of the foam core increases with increasing weight reduction irrespective of the CBA concentration. The specific (mechanical bending properties are significantly improved and the specific tensile properties can almost be maintained while reducing the density of the injection-molded parts.

  7. Metallic witness packs for behind-armour debris characterization

    NARCIS (Netherlands)

    Verolme, J.L.; Szymczak, M.; Broos, J.P.F.

    1999-01-01

    For the experimental characterization of behind-armour debris so-called metallic witness packs can be used. A metallic witness pack consists of an array of metallic plates interspaced by polystyrene foam sheets. To quantify the fragment mass and velocity from the corresponding hole area and position

  8. Investigation of Chemical-Foam Design as a Novel Approach toward Immiscible Foam Flooding for Enhanced Oil Recovery.

    Science.gov (United States)

    Hosseini-Nasab, S M; Zitha, P L J

    2017-10-19

    Strong foam can be generated in porous media containing oil, resulting in incremental oil recovery; however, oil recovery factor is restricted. A large fraction of oil recovered by foam flooding forms an oil-in-water emulsion, so that costly methods may need to be used to separate the oil. Moreover, strong foam could create a large pressure gradient, which may cause fractures in the reservoir. This study presents a novel chemical-foam flooding process for enhanced oil recovery (EOR) from water-flooded reservoirs. The presented method involved the use of chemically designed foam to mobilize the remaining oil after water flooding and then to displace the mobilized oil to the production well. A blend of two anionic surfactant formulations was formulated for this method: (a) IOS, for achieving ultralow interfacial tension (IFT), and (b) AOS, for generating a strong foam. Experiments were performed using Bentheimer sandstone cores, where X-ray CT images were taken during foam generation to find the stability of the advancing front of foam propagation and to map the gas saturation for both the transient and the steady-state flow regimes. Then the proposed chemical-foam strategy for incremental oil recovery was tested through the coinjection of immiscible nitrogen gas and surfactant solutions with three different formulation properties in terms of IFT reduction and foaming strength capability. The discovered optimal formulation contains a foaming agent surfactant, a low IFT surfactant, and a cosolvent, which has a high foam stability and a considerably low IFT (1.6 × 10 -2 mN/m). Coinjection resulted in higher oil recovery and much less MRF than the same process with only using a foaming agent. The oil displacement experiment revealed that coinjection of gas with a blend of surfactants, containing a cosolvent, can recover a significant amount of oil (33% OIIP) over water flooding with a larger amount of clean oil and less emulsion.

  9. Three-Dimensional Graphene Foam Induces Multifunctionality in Epoxy Nanocomposites by Simultaneous Improvement in Mechanical, Thermal, and Electrical Properties.

    Science.gov (United States)

    Embrey, Leslie; Nautiyal, Pranjal; Loganathan, Archana; Idowu, Adeyinka; Boesl, Benjamin; Agarwal, Arvind

    2017-11-15

    Three-dimensional (3D) macroporous graphene foam based multifunctional epoxy composites are developed in this study. Facile dip-coating and mold-casting techniques are employed to engineer microstructures with tailorable thermal, mechanical, and electrical properties. These processing techniques allow capillarity-induced equilibrium filling of graphene foam branches, creating epoxy/graphene interfaces with minimal separation. Addition of 2 wt % graphene foam enhances the glass transition temperature of epoxy from 106 to 162 °C, improving the thermal stability of the polymer composite. Graphene foam aids in load-bearing, increasing the ultimate tensile strength by 12% by merely 0.13 wt % graphene foam in an epoxy matrix. Digital image correlation (DIC) analysis revealed that the graphene foam cells restrict and confine the deformation of the polymer matrix, thereby enhancing the load-bearing capability of the composite. Addition of 0.6 wt % graphene foam also enhances the flexural strength of the pure epoxy by 10%. A 3D network of graphene branches is found to suppress and deflect the cracks, arresting mechanical failure. Dynamic mechanical analysis (DMA) of the composites demonstrated their vibration damping capability, as the loss tangent (tan δ) jumps from 0.1 for the pure epoxy to 0.24 for ∼2 wt % graphene foam-epoxy composite. Graphene foam branches also provide seamless pathways for electron transfer, which induces electrical conductivity exceeding 450 S/m in an otherwise insulator epoxy matrix. The epoxy-graphene foam composite exhibits a gauge factor as high as 4.1, which is twice the typical gauge factor for the most common metals. Simultaneous improvement in thermal, mechanical, and electrical properties of epoxy due to 3D graphene foam makes epoxy-graphene foam composite a promising lightweight and multifunctional material for aiding load-bearing, electrical transport, and motion sensing in aerospace, automotive, robotics, and smart device structures.

  10. Foam - novel delivery technology for remediation of vadose zone environments - 59019

    International Nuclear Information System (INIS)

    Jansik, Danielle; Wellman, Dawn M.; Mattigod, Shas V.; Zhong, Lirong; Zhang, Fred; Foote, Martin; Wu, Yuxin; Hubbard, Susan

    2012-01-01

    readily penetrate low permeability zones. Although surfactant foams have been used for subsurface mobilization efforts in the oil and gas industry, thus far the concept of using foams as a delivery mechanism for transporting remedial amendments into deep vadose zone environments to stabilize metal and long-lived radionuclide contaminants has not been explored. Foam flow can be directed by pressure gradients, rather than being dominated by gravity; and foam delivery mechanisms limit the volume of water (< 5% vol.) required for remedy delivery and emplacement, thus mitigating contaminant mobilization. We will present the results of a numerical modeling and integrated laboratory-/ intermediate-scale investigation to simulate, develop, demonstrate, and monitor (i.e., advanced geophysical techniques and advanced predictive bio-markers) foam-based delivery of remedial amendments to remediate metals and radionuclides in vadose zone environments. (authors)

  11. Foam-on-Tile Damage Model

    Science.gov (United States)

    Koharchik, Michael; Murphy, Lindsay; Parker, Paul

    2012-01-01

    An impact model was developed to predict how three specific foam types would damage the Space Shuttle Orbiter insulating tiles. The inputs needed for the model are the foam type, the foam mass, the foam impact velocity, the foam impact incident angle, the type being impacted, and whether the tile is new or aged (has flown at least one mission). The model will determine if the foam impact will cause damage to the tile. If it can cause damage, the model will output the damage cavity dimensions (length, depth, entry angle, exit angle, and sidewall angles). It makes the calculations as soon as the inputs are entered (less than 1 second). The model allows for the rapid calculation of numerous scenarios in a short time. The model was developed from engineering principles coupled with significant impact testing (over 800 foam impact tests). This model is applicable to masses ranging from 0.0002 up to 0.4 pound (0.09 up to 181 g). A prior tool performed a similar function, but was limited to the assessment of a small range of masses and did not have the large test database for verification. In addition, the prior model did not provide outputs of the cavity damage length, entry angle, exit angle, or sidewall angles.

  12. TPX foams for inertial fusion laser experiments: foam preparation, machining, characterization, and discussion of density issues

    International Nuclear Information System (INIS)

    Grosse, M.; Guillot, L.; Reneaume, B.; Fleury, E.; Hermerel, C.; Choux, A.; Jeannot, L.; Geoffray, I.; Faivre, A.; Breton, O.; Andre, J.; Collier, R.; Legaie, O.

    2011-01-01

    Low density foams (in this work, foam density refers to apparent density) are materials of interest for fusion experiments. Low density poly(4-methyl-1-pentene)(commercial name TPX) foams have been produced for 30 years. TPX foams have been shown to have densities as low as 3 mg.cm -3 , which is very close to air density (1.2 mg.cm -3 ). Around this density foams are very light and highly fragile. Their fabrication is thus a real technological challenge. However, shrinking always appears in ranges ranking from 25% to almost 200%. As a result, the apparent density of the final foam never matches the expected value given by the precursor solution concentration. Besides, even if the mold dimensions are precisely known, shrinkage is never linear, and foams have to be machined for precise density measurement. In our work we present a fabrication process for TPX foams and discuss machining and density measuring issues. Particularly, we have found that there are volume and weight limits for a determination of density within the range of 3% uncertainty. This raises the question whether density should rather be determined directly on millimeter-sized targets or should be performed on a bigger scale sample prepared from the same batch. (authors)

  13. A Novel Method for Preparing Auxetic Foam from Closed-cell Polymer Foam Based on Steam Penetration and Condensation (SPC) Process.

    Science.gov (United States)

    Fan, Donglei; Li, Minggang; Qiu, Jian; Xing, Haiping; Jiang, Zhiwei; Tang, Tao

    2018-05-31

    Auxetic materials are a class of materials possessing negative Poisson's ratio. Here we establish a novel method for preparing auxetic foam from closed-cell polymer foam based on steam penetration and condensation (SPC) process. Using polyethylene (PE) closed-cell foam as an example, the resultant foams treated by SPC process present negative Poisson's ratio during stretching and compression testing. The effect of steam-treated temperature and time on the conversion efficiency of negative Poisson's ratio foam is investigated, and the mechanism of SPC method for forming re-entrant structure is discussed. The results indicate that the presence of enough steam within the cells is a critical factor for the negative Poisson's ratio conversion in the SPC process. The pressure difference caused by steam condensation is the driving force for the conversion from conventional closed-cell foam to the negative Poisson's ratio foam. Furthermore, the applicability of SPC process for fabricating auxetic foam is studied by replacing PE foam by polyvinyl chloride (PVC) foam with closed-cell structure or replacing water steam by ethanol steam. The results verify the universality of SPC process for fabricating auxetic foams from conventional foams with closed-cell structure. In addition, we explored potential application of the obtained auxetic foams by SPC process in the fabrication of shape memory polymer materials.

  14. Porosity and cell size control in alumina foam preparation by thermo-foaming of powder dispersions in molten sucrose

    Directory of Open Access Journals (Sweden)

    Sujith Vijayan

    2016-09-01

    Full Text Available The foaming characteristics of alumina powder dispersions in molten sucrose have been studied as a function of alumina powder to sucrose weight ratio (WA/S and foaming temperature. The increase in foaming temperature significantly decreases the foaming and foam setting time and increases the foam volume due to an increase in the rate of OH condensation as well as a decrease in the viscosity of the dispersion. Nevertheless, the foam collapses beyond a critical foaming temperature, which depends on the WA/S. The sintering shrinkage depends mainly on the WA/S and marginally on the foaming temperature. The porosity (83.4–94.6 vol.% and cell size (0.55–1.6 mm increase with an increase in foaming temperature (120–170 °C and a decrease in WA/S (0.8–1.6. The drastic decrease in compressive strength and modulus beyond a WA/S of 1.2 is due to the pores generated on the cell walls and struts as a result of particle agglomeration. Gibson and Ashby plots show large deviation with respect to the model constants ‘C’ and ‘n’, especially at higher alumina powder to sucrose weight ratios.

  15. Development of drilling foams for geothermal applications

    Energy Technology Data Exchange (ETDEWEB)

    McDonald, W.J.; Remont, L.J.; Rehm, W.A.; Chenevert, M.E.

    1980-01-01

    The use of foam drilling fluids in geothermal applications is addressed. A description of foams - what they are, how they are used, their properties, equipment required to use them, the advantages and disadvantages of foams, etc. - is presented. Geothermal applications are discussed. Results of industry interviews presented indicate significant potential for foams, but also indicate significant technical problems to be solved to achieve this potential. Testing procedures and results of tests on representative foams provide a basis for work to develop high-temperature foams.

  16. Industrial waste utilization for foam concrete

    Science.gov (United States)

    Krishnan, Gokul; Anand, K. B.

    2018-02-01

    Foam concrete is an emerging and useful construction material - basically a cement based slurry with at least 10% of mix volume as foam. The mix usually containing cement, filler (usually sand) and foam, have fresh densities ranging from 400kg/m3 to 1600kg/m3. One of the main drawbacks of foam concrete is the large consumption of fine sand as filler material. Usage of different solid industrial wastes as fillers in foam concrete can reduce the usage of fine river sand significantly and make the work economic and eco-friendly. This paper aims to investigate to what extent industrial wastes such as bottom ash and quarry dust can be utilized for making foam concrete. Foam generated using protein based agent was used for preparing and optimizing (fresh state properties). Investigation to find the influence of design density and air-void characteristics on the foam concrete strength shows higher strength for bottom ash mixes due to finer air void distribution. Setting characteristics of various mix compositions are also studied and adoption of Class C flyash as filler demonstrated capability of faster setting.

  17. Foam shell project: Progress report

    International Nuclear Information System (INIS)

    Overturf, G.; Reibold, B.; Cook, B.; Schroen-Carey, D.

    1994-01-01

    The authors report on their work to produce a foam shell target for two possible applications: (1) as liquid-layered cryogenic target on Omega Upgrade, and (2) as a back-up design for the NIF. This target consists of a roughly 1 mm diameter and 100 μm thick spherical low-density foam shell surrounding a central void. The foam will be slightly overfilled with liquid D 2 or DT, the overfilled excess being symmetrically distributed on the inside of the shell and supported by thermal gradient techniques. The outside of the foam is overcoated with full density polymer which must be topologically smooth. The technology for manufacturing this style of foam shell involves microencapsulation techniques and has been developed by the Japanese at ILE. Their goal is to determine whether this technology can be successfully adapted to meet US ICF objectives. To this end a program of foam shell development has been initiated at LLNL in collaboration with both the General Atomics DOE Target Fabrication Contract Corporation and the Target Fabrication Group at LLE

  18. The Modification of Polyurethane Foams Using New Boroorganic Polyols (II) Polyurethane Foams from Boron-Modified Hydroxypropyl Urea Derivatives

    Science.gov (United States)

    2014-01-01

    The work focuses on research related to determination of application possibility of new, ecofriendly boroorganic polyols in rigid polyurethane foams production. Polyols were obtained from hydroxypropyl urea derivatives esterified with boric acid and propylene carbonate. The influence of esterification type on properties of polyols and next on polyurethane foams properties was determined. Nitrogen and boron impacts on the foams' properties were discussed, for instance, on their physical, mechanical, and electric properties. Boron presence causes improvement of dimensional stability and thermal stability of polyurethane foams. They can be applied even at temperature 150°C. Unfortunately, introducing boron in polyurethanes foams affects deterioration of their water absorption, which increases as compared to the foams that do not contain boron. However, presence of both boron and nitrogen determines the decrease of the foams combustibility. Main impact on the decrease combustibility of the obtained foams has nitrogen presence, but in case of proper boron and nitrogen ratio their synergic activity on the combustibility decrease can be easily seen. PMID:24587721

  19. Literature Review: An Overview of Epoxy Resin Syntactic Foams with Glass Microballoons

    Energy Technology Data Exchange (ETDEWEB)

    Keller, Jennie [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2014-03-12

    Syntactic foams are an important category of composite materials that have abundant applications in a wide variety of fields. The bulk phase of syntactic foams is a three-part epoxy resin formulation that consists of a base resin, a curative (curing agent) and a modifier (diluent and/or accelerator) [12]. These thermoset materials [12] are used frequently for their thermal stability [9], low moisture absorption and high compressive strength [10]. The characteristic feature of a syntactic foam is a network of beads that forms pores within the epoxy matrix [3]. In this review, hollow glass beads (known as glass microballoons) are considered, however, solid beads or microballoons made from materials such as ceramic, polymer or metal can also be used [3M, Peter]. The network of hollow beads forms a closed-cell foam; the term closed-cell comes from the fact that the microspheres used in the resin matrix are completely closed and filled with gas (termed hollow). In contrast, the microspheres used in open-cell foams are either not completely closed or broken so that matrix material can fill the spheres [11]. Although closed foams have been found to possess higher densities than open cell foams, their rigid structures give them superior mechanical properties [12]. Past research has extensively studied the effects that changing the volume fraction of microballoons to epoxy will have on the resulting syntactic foam [3,4,9]. In addition, published literature also explores how the microballoon wall thickness affects the final product [4,9,10]. Findings detail that indeed both the mechanical and some thermal properties of syntactic foams can be tailored to a specific application by varying either the volume fraction or the wall thickness of the microballoons used [10]. The major trends in syntactic foam research show that microballoon volume fraction has an inversely proportionate relationship to dynamic properties, while microballoon wall thickness is proportional to those

  20. Evaluation of Canisterized Foams and Evaluation of Radiation Hardened Foams for D&D Activities

    Energy Technology Data Exchange (ETDEWEB)

    Nicholson, J. C. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

    2017-09-26

    The introduction of polyurethane foams has previously been examined elsewhere within the DOE complex with regards to decontamination and decommissioning (D&D) activities, though its use has been prohibited as a result of excessive heat generation and flammability concerns per the safety basis. Should these foams be found compatible with respect to the facility safety basis requirements, D&D work involving large void containing structures such as gloveboxes could be eased through the fixation of residual contamination after decontamination efforts have concluded. To this end, SRNL embarked on a characterization of commercial epoxy foams to identify the characteristics that would be most important to safety basis requirements. Through SRNL’s efforts, the performance of commercial two-part epoxy foams was evaluated for their foaming characteristics, temperature profiles, loading capability with high-Z (high density) additives, and applicability for shielding gamma emission from isotopes including; Am-241, Cs-137, and Co-60. It was found that these foams are capable of encapsulation of a desired volume, though the ideal and experimental expansion coefficients were found to differ. While heat is generated during the reaction, no samples generated heat above 70 °C. Of the down–selected materials, heating was on the order of 40 °C for the flexible foam and 60 °C for the rigid foam. Both were found to return to room temperature after 20 minutes regardless of the volume of foam cast. It was also found that the direct introduction of high-Z additives were capable of attenuating 98% of Am-241 gamma signal, 16% of Cs-137 signal, and 9.5% of Co-60 signal at 1:1 loading capacities of total liquid constituent weight to additive weight. These efforts are currently being reviewed for the ASTM January 2017 subcommittee discussions to address the lack of test methods and standards regarding these materials with respect to D&D environments.

  1. Electrical conductivity of quasi-two-dimensional foams.

    Science.gov (United States)

    Yazhgur, Pavel; Honorez, Clément; Drenckhan, Wiebke; Langevin, Dominique; Salonen, Anniina

    2015-04-01

    Quasi-two-dimensional (quasi-2D) foams consist of monolayers of bubbles squeezed between two narrowly spaced plates. These simplified foams have served successfully in the past to shed light on numerous issues in foam physics. Here we consider the electrical conductivity of such model foams. We compare experiments to a model which we propose, and which successfully relates the structural and the conductive properties of the foam over the full range of the investigated liquid content. We show in particular that in the case of quasi-2D foams the liquid in the nodes needs to be taken into account even at low liquid content. We think that these results may provide different approaches for the characterization of foam properties and for the in situ characterization of the liquid content of foams in confining geometries, such as microfluidics.

  2. Refractory metal component technology for in-core sensor design

    International Nuclear Information System (INIS)

    Cannon, C.P.

    1986-02-01

    Within recent years, an increasing concern over reactor safety has prompted tests that characterize reactor core environments during transient conditions. Such tests include the Loss-of-Fluid-Tests (Idaho National Engineering Lab (INEL)), Severe Fuel Damage Tests (INEL), Core Debris Rubble Tests (Sandia National Laboratories (SNL)), and similar tests performed by foreign nations. The in-core sensors for these tests require refractory metal components to be compatible with electrical insulator materials as well as materials comprising highly corrosive service mediums. This paper presents the refractory metal technology utilized to provide basic sensor designs in the above mentioned reactor tests

  3. Synthesis of α-Fe2O3 and Fe-Mn Oxide Foams with Highly Tunable Magnetic Properties by the Replication Method from Polyurethane Templates

    Science.gov (United States)

    Feng, Yuping; Fornell, Jordina; Zhang, Huiyan; Solsona, Pau; Barό, Maria Dolors; Suriñach, Santiago; Sort, Jordi

    2018-01-01

    Open cell foams consisting of Fe and Fe-Mn oxides are prepared from metallic Fe and Mn powder precursors by the replication method using porous polyurethane (PU) templates. First, reticulated PU templates are coated by slurry impregnation. The templates are then thermally removed at 260 °C and the debinded powders are sintered at 1000 °C under N2 atmosphere. The morphology, structure, and magnetic properties are studied by scanning electron microscopy, X-ray diffraction and vibrating sample magnetometry, respectively. The obtained Fe and Fe-Mn oxide foams possess both high surface area and homogeneous open-cell structure. Hematite (α-Fe2O3) foams are obtained from the metallic iron slurry independently of the N2 flow. In contrast, the microstructure of the FeMn-based oxide foams can be tailored by adjusting the N2 flow. While the main phases for a N2 flow rate of 180 L/h are α-Fe2O3 and FeMnO3, the predominant phase for high N2 flow rates (e.g., 650 L/h) is Fe2MnO4. Accordingly, a linear magnetization versus field behavior is observed for the hematite foams, while clear hysteresis loops are obtained for the Fe2MnO4 foams. Actually, the saturation magnetization of the foams containing Mn increases from 5 emu/g to 52 emu/g when the N2 flow rate (i.e., the amount of Fe2MnO4) is increased. The obtained foams are appealing for a wide range of applications, such as electromagnetic absorbers, catalysts supports, thermal and acoustic insulation systems or wirelessly magnetically-guided porous objects in fluids. PMID:29439450

  4. From Foam Rubber to Volcanoes: The Physical Chemistry of Foam Formation

    Science.gov (United States)

    Hansen, Lee D.; McCarlie, V. Wallace

    2004-01-01

    The process of foam formation is used for demonstrating the way in which the application of physiochemical principles and knowledge of the physical properties of the materials contributes towards the understanding of a wide range of phenomenon. Solubility of gas and bubble growth should be considered during the development of foamed polymer…

  5. Polyethoxylated carboxylic surfactant for ion foam flotation: fundamental study from solution to foam

    International Nuclear Information System (INIS)

    Micheau, Cyril

    2013-01-01

    Ion foam flotation allows to concentrate ions in a foam phase formed by a soap. For classical systems, the strong interaction between ions and surfactant generally leads to the formation of precipitates and of froth. When the froth collapses, the solid residue thus recovered requires a recycling or conversion. In order to remedy this, the present work uses as collector a polyethoxylated carboxylic surfactant, AKYPO RO 90 VG, which forms soluble ion/surfactant complexes, even with multi-charge ions. This work presents a detailed study of the fundamental mechanisms that govern the extraction of ions by foaming. In the first part, surface activity and acid/base properties of the surfactant in solution are determined by combining numerous independent techniques which are pH-metric dosage, tensiometry and small angle scattering. The evolution of these properties in the presence of different nitrate salts (Nd, Eu, Ca, Sr, Cu, Li, Na, Cs) coupled with electrophoretic measurements give a first approach to selectivity. Finally, all of these data combined with a study of the formation of surfactant/ion complexes allow us to determine the speciation of Nd/AKYPO system as a function of pH. In the second part, the analysis of the foam by conductivity and neutron scattering provides information on the wetness and foam film thickness, parameters governing foam stability. The pH and the nature of the added ions, their number of charge and also their chemical nature thus appear to be major parameters that governed wetness and foam film thickness. The last part is devoted to the understanding of the ion extraction/separation experiments by flotation based on all previous results. It is shown that the flotation of neodymium is strongly related to its speciation, which could lead to its re-extraction or its flotation in precipitated form. It is shown that, neodymium induces a phenomenon of mono-charge ion depletion in the foam. This ionic specificity allows to consider the studied

  6. Foam rheology at large deformation

    Science.gov (United States)

    Géminard, J.-C.; Pastenes, J. C.; Melo, F.

    2018-04-01

    Large deformations are prone to cause irreversible changes in materials structure, generally leading to either material hardening or softening. Aqueous foam is a metastable disordered structure of densely packed gas bubbles. We report on the mechanical response of a foam layer subjected to quasistatic periodic shear at large amplitude. We observe that, upon increasing shear, the shear stress follows a universal curve that is nearly exponential and tends to an asymptotic stress value interpreted as the critical yield stress at which the foam structure is completely remodeled. Relevant trends of the foam mechanical response to cycling are mathematically reproduced through a simple law accounting for the amount of plastic deformation upon increasing stress. This view provides a natural interpretation to stress hardening in foams, demonstrating that plastic effects are present in this material even for minute deformation.

  7. Werkstoffwoche 98. Vol. 6. Symposium 8: Metals. Symposium 14: Metals modelling

    International Nuclear Information System (INIS)

    Kopp, R.; Beiss, P.; Herfurth, K.; Boehme, D.; Bormann, R.; Arzt, E.; Riedel, H.

    1999-01-01

    The proceedings volume contains the papers of the symposia dealing with metals and the focus is on the following subjects: Deformation, powder metallurgy, forming by casting processes, joining, materials physics (ferrous materials, light metal materials, composite materials, high-temperature materials, functional materials), intermetallic phases and foams, modelling calculations. 26 of the papers have been analysed and processed for individual document retrieval from the ENERGY database. (orig/MM) [de

  8. Controlling of density uniformity of polyacrylate foams

    International Nuclear Information System (INIS)

    Shan Wenwen; Yuan Baohe; Wang Yanhong; Xu Jiayun; Zhang Lin

    2010-01-01

    The density non-uniformity existing in most low-density foams will affect performance of the foams. The trimethylolpropane trimethacrylate (TMPTA) foam targets were prepared and controlling methods of the foams, density uniformity were explored together with its forming mechanism. It has been found that the UV-light with high intensity can improve the distribution uniformity of the free radicals induced by UV photons in the solvents, thus improve the density uniformity of the foams. In addition, container wall would influence the concentration distribution of the solution, which affects the density uniformity of the foams. Thus, the UV-light with high intensity was chosen together with polytetrafluoroethylene molds instead of glass molds to prepare the foams with the density non-uniformity less than 10%. β-ray detection technology was used to measure the density uniformity of the TMPTA foams with the density in the range of 10 to 100 mg · cm -3 , and the results show that the lower the foam density is, the worse the density uniformity is. (authors)

  9. Experimental analysis of R134a flow boiling inside a 5 PPI copper foam

    Science.gov (United States)

    Diani, A.; Mancin, S.; Rossetto, L.

    2014-04-01

    Heat dissipation is one of the most important issues for the reliability of electronic equipment. Boiling can be a very efficient heat transfer mechanism when used to face with the electronic technology needs of efficient and compact heat sinks. Recently, cellular structured materials both stochastic and periodic, particularly open cell metal foams, have been proposed as possible enhanced surfaces to lower the junction temperatures at high heat fluxes. Up today, most of the research on metal foams only regards single phase flow, whereas the two phase flow is still almost unexplored. This paper presents an experimental study on the heat transfer of R134a during flow boiling inside a 5 PPI (Pores Per linear Inch) copper foam, which is 5 mm high, 10 mm wide and 200 mm long, and it is brazed on a 10 mm thick copper plate. The experimental measurements were carried out by imposing three different heat fluxes (50, 75, and 100 kW m-2) and by varying the refrigerant mass velocity between 50 and 200 kg m-2 s-1 and the vapour quality from 0.2 to 0.90, at constant saturation temperature (30°C). The effects of the refrigerant mass flow rate, heat flux and vapour quality on the heat transfer coefficient, dry out phenomenon, and pressure drop are studied.

  10. Blast wave protection of aqueous foams

    Energy Technology Data Exchange (ETDEWEB)

    Britan, Alexander; Ben-Dor, M. Liverts G. [Shock tube Laboratory of Protective Technologies R and D Center, Department of Mechanical Engineering, Faculty of Engineering Sciences, Ben Gurion University, Beer-Sheva (Israel)

    2011-07-01

    The primary intention of the present study is to present new contribution of shock tube tests to the problem of particle related stabilization and enhanced mitigation action of the wet particulate foams. The experiments reported were designed to examine (i) the reflection of a shock wave from an air/foam face, (ii) the transmission of the shock wave through the air/foam face and (iii) propagation and dispersion of the transmitted shock wave inside the foam column. Because wet aqueous foam of desired specification is difficult to reproduce, handle and quantitatively characterize the fact that experiments on all the above aspects were conducted in a single facility is a potentially important consideration. Moreover vertical position of shock tube simplified the issues since the gradient of the liquid fraction in draining foam coincides with the shock wave propagation. Under these, much simplified test conditions resulted flows could be treated as one-dimensional and the shock wave mitigation depends on three parameters: the intensity of the incident shock wave, s M , the duration of the foam decay, ∆t and on the particle concentration, n.

  11. Covering sources of toxic vapors with foam

    International Nuclear Information System (INIS)

    Aue, W. P.; Guidetti, F.

    2009-01-01

    In a case of chemical terrorism, first responders might well be confronted with a liquid source of toxic vapor which keeps spreading out its hazardous contents. With foam as an efficient and simple means, such a source could be covered up in seconds and the spread of vapors mitigated drastically. Once covered, the source could then wait for a longer time to be removed carefully and professionally by a decontamination team. In order to find foams useful for covering up toxic vapor sources, a large set of measurements has been performed in order to answer the following questions: - Which foams could be used for this purpose? - How thick should the foam cover be? - For how long would such a foam cover be effective? - Could the practical application of foam cause a spread of the toxic chemical? The toxic vapors sources included GB, GD and HD. Among the foams were 10 fire fighter foams (e.g. AFFF, protein) and the aqueous decontamination foam CASCAD. Small scale experiments showed that CASCAD is best suited for covering a toxic source; a 10 cm layer of it covers and decontaminates GB. The large scale experiments confirmed that any fire fighter foam is a suitable cover for a longer or shorter period.(author)

  12. Crosslinked polyethylene foams, via eb radiation

    International Nuclear Information System (INIS)

    Cardoso, E.C.L.; Lugao, A. B.; Andrade e Silva, L. G.

    1998-01-01

    Polyethylene foams, produced by radio-induced crosslinking, show a smooth and homogeneous surface, when compared to chemical crosslinking method using peroxide as crosslinking agent. This process fosters excellent adhesive and printability properties. Besides that, closed cells, intrinsic to these foams, imparts optimum mechanical, shocks and insulation resistance, indicating these foams to some markets segments as: automotive and transport; buoyancy, flotation and marine; building and insulation; packaging; domestic sports and leisure goods. We were in search of an ideal foam, by adding 5 to 15% of blowing agent in LDPE. A series of preliminary trials defined 203 degree sign C as the right blowing agent decomposition temperature. At a 22.7 kGys/dose ratio, the lowest dose for providing an efficient foam was 30 kGy, for a formulation comprising 10% of azodicarbonamide in LDPE, within a 10 minutes foaming time

  13. Stretching and folding mechanism in foams

    International Nuclear Information System (INIS)

    Tufaile, Alberto; Pedrosa Biscaia Tufaile, Adriana

    2008-01-01

    We have described the stretching and folding of foams in a vertical Hele-Shaw cell containing air and a surfactant solution, from a sequence of upside-down flips. Besides the fractal dimension of the foam, we have observed the logistic growth for the soap film length. The stretching and folding mechanism is present during the foam formation, and this mechanism is observed even after the foam has reached its respective maximum fractal dimension. Observing the motion of bubbles inside the foam, large bubbles present power spectrum associated with random walk motion in both directions, while the small bubbles are scattered like balls in a Galton board

  14. Stretching and folding mechanism in foams

    Energy Technology Data Exchange (ETDEWEB)

    Tufaile, Alberto [Escola de Artes, Ciencias e Humanidades, Soft Matter Laboratory, Universidade de Sao Paulo, 03828-000 Sao Paulo, SP (Brazil)], E-mail: tufaile@usp.br; Pedrosa Biscaia Tufaile, Adriana [Escola de Artes, Ciencias e Humanidades, Soft Matter Laboratory, Universidade de Sao Paulo, 03828-000 Sao Paulo, SP (Brazil)

    2008-10-13

    We have described the stretching and folding of foams in a vertical Hele-Shaw cell containing air and a surfactant solution, from a sequence of upside-down flips. Besides the fractal dimension of the foam, we have observed the logistic growth for the soap film length. The stretching and folding mechanism is present during the foam formation, and this mechanism is observed even after the foam has reached its respective maximum fractal dimension. Observing the motion of bubbles inside the foam, large bubbles present power spectrum associated with random walk motion in both directions, while the small bubbles are scattered like balls in a Galton board.

  15. Technology of foamed propellants

    Energy Technology Data Exchange (ETDEWEB)

    Boehnlein-Mauss, Jutta; Kroeber, Hartmut [Fraunhofer Institut fuer Chemische Technologie ICT, Pfinztal (Germany)

    2009-06-15

    Foamed propellants are based on crystalline explosives bonded in energetic reaction polymers. Due to their porous structures they are distinguished by high burning rates. Energy content and material characteristics can be varied by using different energetic fillers, energetic polymers and porous structures. Foamed charges can be produced easily by the reaction injection moulding process. For the manufacturing of foamed propellants a semi-continuous remote controlled production plant in pilot scale was set up and a modified reaction injection moulding process was applied. (Abstract Copyright [2009], Wiley Periodicals, Inc.)

  16. Some aspects of image processing using foams

    International Nuclear Information System (INIS)

    Tufaile, A.; Freire, M.V.; Tufaile, A.P.B.

    2014-01-01

    We have explored some concepts of chaotic dynamics and wave light transport in foams. Using some experiments, we have obtained the main features of light intensity distribution through foams. We are proposing a model for this phenomenon, based on the combination of two processes: a diffusive process and another one derived from chaotic dynamics. We have presented a short outline of the chaotic dynamics involving light scattering in foams. We also have studied the existence of caustics from scattering of light from foams, with typical patterns observed in the light diffraction in transparent films. The nonlinear geometry of the foam structure was explored in order to create optical elements, such as hyperbolic prisms and filters. - Highlights: • We have obtained the light scattering in foams using experiments. • We model the light transport in foams using a chaotic dynamics and a diffusive process. • An optical filter based on foam is proposed

  17. A graphite foam reinforced by graphite particles

    Energy Technology Data Exchange (ETDEWEB)

    Zhu, J.J.; Wang, X.Y.; Guo, L.F.; Wang, Y.M.; Wang, Y.P.; Yu, M.F.; Lau, K.T.T. [DongHua University, Shanghai (China). College of Material Science and Engineering

    2007-11-15

    Graphite foam was obtained after carbonization and graphitization of a pitch foam formed by the pyrolysis of coal tar based mesophase pitch mixed with graphite particles in a high pressure and temperature chamber. The graphite foam possessed high mechanical strength and exceptional thermal conductivity after adding the graphite particles. Experimental results showed that the thermal conductivity of modified graphite foam reached 110W/m K, and its compressive strength increased from 3.7 MPa to 12.5 MPa with the addition of 5 wt% graphite particles. Through the microscopic observation, it was also found that fewer micro-cracks were formed in the cell wall of the modified foam as compared with pure graphite foam. The graphitization degree of modified foam reached 84.9% and the ligament of graphite foam exhibited high alignment after carbonization at 1200{sup o}C for 3 h and graphitization at 3000{sup o}C for 10 min.

  18. Foam injection method and system

    Energy Technology Data Exchange (ETDEWEB)

    Hardy, W C; Parmley, J B; Shepard, J C

    1977-05-10

    A method is described for more efficiently practicing in situ combustion techniques by generating a gas-water mist or foam adjacent to the combustion formation within the injection well. The mist or foam is forced out of the well into the formation to transport heat away from the burned region of the formation toward the periphery of the combustion region to conserve fuel. Also taught are a method and system for fluid treating a formation while maintaining enhanced conformance of the fluid injection profile by generating a mist or foam down-hole adjacent to the formation and then forcing the mist or foam out into the formation. (19 claims)

  19. Polyurethane Foams with Pyrimidine Rings

    Directory of Open Access Journals (Sweden)

    Kania Ewelina

    2014-09-01

    Full Text Available Oligoetherols based on pyrimidine ring were obtained upon reaction of barbituric acid with glycidol and alkylene carbonates. These oligoetherols were then used to obtain polyurethane foams in the reaction of oligoetherols with isocyanates and water. The protocol of foam synthesis was optimized by the choice of proper kind of oligoetherol and synthetic composition. The thermal resistance was studied by dynamic and static methods with concomitant monitoring of compressive strength. The polyurethane foams have similar physical properties as the classic ones except their enhanced thermal resistance. They stand long-time heating even at 200°C. Moreover thermal exposition of foams results generally in increase of their compressive strength.

  20. Foam stabilization by solid particle aggregates

    Energy Technology Data Exchange (ETDEWEB)

    Guignot, S.; Faure, S. [CEA Marcoule, Lab. des Procedes Avances de Decontamination, 30 (France); Pitois, O. [UniversiteParis-Est Marne-La-Valle, Lab. Physique des Materiaux Divises et des Interfaces (LPMDI), 77 - Marne la Vallee (France)

    2008-07-01

    During the dismantling of nuclear facilities, radioactive deposits on exposed areas are removed and solubilized by successive rinses of reactive liquid. Using this liquid in a foam state reduces the amount of resulting wastes. During the required decontamination time (1 to 5 hours) the foam has to be sufficiently wet (1). In the Laboratory of Advanced Processes for Decontamination, new formulations are currently studied to slow down the drainage kinetics of these foams, by adding colloidal particles of hydrophilic fumed silica into the classical mixtures of well-defined non ionic foaming surfactants previously used (2). The objective of our study is to shed light on the foam surprising stability induced by these particles. The study focuses on drainage of foams generated by air sparging through a suspension lying on a porous glass. The foaming suspensions contain between 0 and 70 g.L-1 of a fumed silica (Aerosil 380) which is well-known to form gels for concentrations above 200 g.L{sup -1}. In the studied solutions this silica builds up into aggregates of dozens of microns, whose volume-averaged mean diameter after sonication is centred around 300 nm. Under gentle stirring, they display no sign of re-aggregation during 24 h. On a free drainage configuration, a foam that contains particles keeps a significant amount of its initial liquid: up to 60 % during up to 5 hours, in contrast to classical foams that drain out all of their liquid in about 20 minutes. From a rheological point of view, the most concentrated suspensions display a yield stress behaviour. This evidences the structuring of the aggregates into a coherent network that might explain the incomplete drainage of the solutions. For the lowest concentrated solutions, such rheological properties have not been observed although the corresponding foams can retain large amount of solution. This suggests that local concentrations of aggregates can rise owing to their retention by foam channels, until they form

  1. Cryogenic foam insulation: Abstracted publications

    Science.gov (United States)

    Williamson, F. R.

    1977-01-01

    A group of documents were chosen and abstracted which contain information on the properties of foam materials and on the use of foams as thermal insulation at cryogenic temperatures. The properties include thermal properties, mechanical properties, and compatibility properties with oxygen and other cryogenic fluids. Uses of foams include applications as thermal insulation for spacecraft propellant tanks, and for liquefied natural gas storage tanks and pipelines.

  2. Carbon Fiber Foam Composites and Methods for Making the Same

    Science.gov (United States)

    Leseman, Zayd Chad (Inventor); Atwater, Mark Andrew (Inventor); Phillips, Jonathan (Inventor)

    2014-01-01

    Exemplary embodiments provide methods and apparatus of forming fibrous carbon foams (FCFs). In one embodiment, FCFs can be formed by flowing a fuel rich gas mixture over a catalytic material and components to be encapsulated in a mold to form composite carbon fibers, each composite carbon fiber having a carbon phase grown to encapsulate the component in situ. The composite carbon fibers can be intertwined with one another to form FCFs having a geometry according to the mold.

  3. Acoustic Test Results of Melamine Foam with Application to Payload Fairing Acoustic Attenuation Systems

    Science.gov (United States)

    Hughes, William O.; McNelis, Anne M.

    2014-01-01

    A spacecraft at launch is subjected to a harsh acoustic and vibration environment resulting from the passage of acoustic energy, created during the liftoff of a launch vehicle, through the vehicle's payload fairing. In order to ensure the mission success of the spacecraft it is often necessary to reduce the resulting internal acoustic sound pressure levels through the usage of acoustic attenuation systems. Melamine foam, lining the interior walls of the payload fairing, is often utilized as the main component of such a system. In order to better understand the acoustic properties of melamine foam, with the goal of developing improved acoustic attenuation systems, NASA has recently performed panel level testing on numerous configurations of melamine foam acoustic treatments at the Riverbank Acoustical Laboratory. Parameters assessed included the foam's thickness and density, as well as the effects of a top outer cover sheet material and mass barriers embedded within the foam. This testing followed the ASTM C423 standard for absorption and the ASTM E90 standard for transmission loss. The acoustic test data obtained and subsequent conclusions are the subjects of this paper.

  4. Making continuous bubble type polyethylene foam incombustible

    International Nuclear Information System (INIS)

    Kaji, Kanako; Hatada, Motoyoshi; Yoshizawa, Iwao; Komai, Kuniaki; Kohara, Choji.

    1989-01-01

    Since continuous bubble type plastic foam has excellent compression characteristics and sound absorption characteristics, it has been widely used as cushion material, sealing material, sound insulating material and so on. However, the most part of plastic foam is taken by air, therefore at the time of fires, it becomes a very dangerous material. At present, the material used mostly as the seat cushions for airliners, railroad coaches, automobiles and others is polyurethane foam, but since it contains C-N couples in its molecules, it is feared to generate cyanic gas according to the condition of combustion. As the plastic foam that does not generate harmful gas at the time of fires, there is continuous bubble type polyethylene which is excellent in its weathering property and chemical resistance. A reactive, phosphorus-containing oligomer has large molecular weight and two or more double couplings in a molecule, therefore, it does not enter the inside of polyethylene, and polymerizes and crosslinks on the surfaces of bubble walls in the foam, accordingly it is expected that the apparent graft polymerization is carried out, and it is very effective for making polyethylene foam incombustible. The method of making graft foam, the properties of graft foam and so on are reported. When the graft polymerization of this oligomer to continuous bubble type polyethylene foam was tried, highly incombustible polyethylene foam was obtained. (K.I.)

  5. Modelling of Churn-Annular foam flows

    NARCIS (Netherlands)

    Westende, J.M.C. van 't; Shoeibi Omrani, P.; Vercauteren, F.F.; Nennie, E.D.

    2016-01-01

    Foam assisted lift is a deliquification method in the oil and gas industry, which aims to prevent or postpone countercurrent gas-liquid flow in maturing gas wells or to assist in removing downhole accumulated liquids. According to Nimwegen, who performed experiments with foam flows, foam

  6. Damping of liquid sloshing by foams

    Science.gov (United States)

    Sauret, A.; Boulogne, F.; Cappello, J.; Dressaire, E.; Stone, H. A.

    2015-02-01

    When a container is set in motion, the free surface of the liquid starts to oscillate or slosh. Such effects can be observed when a glass of water is handled carelessly and the fluid sloshes or even spills over the rims of the container. However, beer does not slosh as readily as water, which suggests that foam could be used to damp sloshing. In this work, we study experimentally the effect on sloshing of a liquid foam placed on top of a liquid bath. We generate a monodisperse two-dimensional liquid foam in a rectangular container and track the motion of the foam. The influence of the foam on the sloshing dynamics is experimentally characterized: only a few layers of bubbles are sufficient to significantly damp the oscillations. We rationalize our experimental findings with a model that describes the foam contribution to the damping coefficient through viscous dissipation on the walls of the container. Then we extend our study to confined three-dimensional liquid foam and observe that the behavior of 2D and confined 3D systems are very similar. Thus, we conclude that only the bubbles close to the walls have a significant impact on the dissipation of energy. The possibility to damp liquid sloshing using foam is promising in numerous industrial applications such as the transport of liquefied gas in tankers or for propellants in rocket engines.

  7. Method of making a cyanate ester foam

    Science.gov (United States)

    Celina, Mathias C.; Giron, Nicholas Henry

    2014-08-05

    A cyanate ester resin mixture with at least one cyanate ester resin, an isocyanate foaming resin, other co-curatives such as polyol or epoxy compounds, a surfactant, and a catalyst/water can react to form a foaming resin that can be cured at a temperature greater than 50.degree. C. to form a cyanate ester foam. The cyanate ester foam can be heated to a temperature greater than 400.degree. C. in a non-oxidative atmosphere to provide a carbonaceous char foam.

  8. Synthesis of α-Fe2O3 and Fe-Mn Oxide Foams with Highly Tunable Magnetic Properties by the Replication Method from Polyurethane Templates

    Directory of Open Access Journals (Sweden)

    Yuping Feng

    2018-02-01

    Full Text Available Open cell foams consisting of Fe and Fe-Mn oxides are prepared from metallic Fe and Mn powder precursors by the replication method using porous polyurethane (PU templates. First, reticulated PU templates are coated by slurry impregnation. The templates are then thermally removed at 260 °C and the debinded powders are sintered at 1000 °C under N2 atmosphere. The morphology, structure, and magnetic properties are studied by scanning electron microscopy, X-ray diffraction and vibrating sample magnetometry, respectively. The obtained Fe and Fe-Mn oxide foams possess both high surface area and homogeneous open-cell structure. Hematite (α-Fe2O3 foams are obtained from the metallic iron slurry independently of the N2 flow. In contrast, the microstructure of the FeMn-based oxide foams can be tailored by adjusting the N2 flow. While the main phases for a N2 flow rate of 180 L/h are α-Fe2O3 and FeMnO3, the predominant phase for high N2 flow rates (e.g., 650 L/h is Fe2MnO4. Accordingly, a linear magnetization versus field behavior is observed for the hematite foams, while clear hysteresis loops are obtained for the Fe2MnO4 foams. Actually, the saturation magnetization of the foams containing Mn increases from 5 emu/g to 52 emu/g when the N2 flow rate (i.e., the amount of Fe2MnO4 is increased. The obtained foams are appealing for a wide range of applications, such as electromagnetic absorbers, catalysts supports, thermal and acoustic insulation systems or wirelessly magnetically-guided porous objects in fluids.

  9. Microstructure of high-strength foam concrete

    International Nuclear Information System (INIS)

    Just, A.; Middendorf, B.

    2009-01-01

    Foam concretes are divided into two groups: on the one hand the physically foamed concrete is mixed in fast rotating pug mill mixers by using foaming agents. This concrete cures under atmospheric conditions. On the other hand the autoclaved aerated concrete is chemically foamed by adding aluminium powder. Afterwards it is cured in a saturated steam atmosphere. New alternatives for the application of foam concretes arise from the combination of chemical foaming and air curing in manufacturing processes. These foam concretes are new and innovative building materials with interesting properties: low mass density and high strength. Responsible for these properties are the macro-, meso- and microporosity. Macropores are created by adding aluminium powder in different volumes and with different particle size distributions. However, the microstructure of the cement matrix is affected by meso- and micropores. In addition, the matrix of the hardened cement paste can be optimized by the specific use of chemical additives for concrete. The influence of aluminium powder and chemical additives on the properties of the microstructure of the hardened cement matrices were investigated by using petrographic microscopy as well as scanning electron microscopy.

  10. A cement based syntactic foam

    International Nuclear Information System (INIS)

    Li Guoqiang; Muthyala, Venkata D.

    2008-01-01

    In this study, a cement based syntactic foam core was proposed and experimentally investigated for composite sandwich structures. This was a multi-phase composite material with microballoon dispersed in a rubber latex toughened cement paste matrix. A trace amount of microfiber was also incorporated to increase the number of mechanisms for energy absorption and a small amount of nanoclay was added to improve the crystal structure of the hydrates. Three groups of cement based syntactic foams with varying cement content were investigated. A fourth group of specimens containing pure cement paste were also prepared as control. Each group contained 24 beam specimens. The total number of beam specimens was 96. The dimension of each beam was 30.5 cm x 5.1 cm x 1.5 cm. Twelve foam specimens from each group were wrapped with plain woven 7715 style glass fabric reinforced epoxy to prepare sandwich beams. Twelve cubic foam specimens, three from each group, with a side length of 5.1 cm, were also prepared. Three types of testing, low velocity impact test and four-point bending test on the beam specimens and compression test on the cubic specimens, were conducted to evaluate the impact energy dissipation, stress-strain behavior, and residual strength. Scanning electron microscope (SEM) was also used to examine the energy dissipation mechanisms in the micro-length scale. It was found that the cement based syntactic foam has a higher capacity for dissipating impact energy with an insignificant reduction in strength as compared to the control cement paste core. When compared to a polymer based foam core having similar compositions, it was found that the cement based foam has a comparable energy dissipation capacity. The developed cement based syntactic foam would be a viable alternative for core materials in impact-tolerant composite sandwich structures

  11. Influence of the glass-calcium carbonate mixture's characteristics on the foaming process and the properties of the foam glass

    DEFF Research Database (Denmark)

    König, Jakob; Petersen, Rasmus Rosenlund; Yue, Yuanzheng

    2014-01-01

    We prepared foam glasses from cathode-ray-tube panel glass and CaCO3 as a foaming agent. We investigated the influences of powder preparation, CaCO3 concentration and foaming temperature and time on the density, porosity and homogeneity of the foam glasses. The results show that the decomposition...

  12. Class B Fire-Extinguishing Performance Evaluation of a Compressed Air Foam System at Different Air-to-Aqueous Foam Solution Mixing Ratios

    Directory of Open Access Journals (Sweden)

    Dong-Ho Rie

    2016-06-01

    Full Text Available The purpose of this research is to evaluate the fire-extinguishing performance of a compressed air foam system at different mixing ratios of pressurized air. In this system, compressed air is injected into an aqueous solution of foam and then discharged. The experimental device uses an exclusive fire-extinguishing technology with compressed air foam that is produced based on the Canada National Laboratory and UL (Underwriters Laboratories 162 standards, with a 20-unit oil fire model (Class B applied as the fire extinguisher. Compressed air is injected through the air mixture, and results with different air-to-aqueous solution foam ratios of 1:4, 1:7, and 1:10 are studied. In addition, comparison experiments between synthetic surfactant foam and a foam type which forms an aqueous film are carried out at an air-to-aqueous solution foam ratio of 1:4. From the experimental results, at identical discharging flows, it was found that the fire-extinguishing effect of the aqueous film-forming foam is greatest at an air-to-aqueous solution foam ratio of 1:7 and weakest at 1:10. Moreover, the fire-extinguishing effect of the aqueous film-forming foam in the comparison experiments between the aqueous film-forming foam and the synthetic surfactant foam is greatest.

  13. Experiments to Populate and Validate a Processing Model for Polyurethane Foam: Additional Data for Structural Foams

    Energy Technology Data Exchange (ETDEWEB)

    Rao, Rekha R. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Celina, Mathias C. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Giron, Nicholas Henry [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Long, Kevin Nicholas [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Russick, Edward M. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2015-01-01

    We are developing computational models to help understand manufacturing processes, final properties and aging of structural foam, polyurethane PMDI. Th e resulting model predictions of density and cure gradients from the manufacturing process will be used as input to foam heat transfer and mechanical models. BKC 44306 PMDI-10 and BKC 44307 PMDI-18 are the most prevalent foams used in structural parts. Experiments needed to parameterize models of the reaction kinetics and the equations of motion during the foam blowing stages were described for BKC 44306 PMDI-10 in the first of this report series (Mondy et al. 2014). BKC 44307 PMDI-18 is a new foam that will be used to make relatively dense structural supports via over packing. It uses a different catalyst than those in the BKC 44306 family of foams; hence, we expect that the reaction kineti cs models must be modified. Here we detail the experiments needed to characteriz e the reaction kinetics of BKC 44307 PMDI-18 and suggest parameters for the model based on these experiments. In additi on, the second part of this report describes data taken to provide input to the preliminary nonlinear visco elastic structural response model developed for BKC 44306 PMDI-10 foam. We show that the standard cu re schedule used by KCP does not fully cure the material, and, upon temperature elevation above 150°C, oxidation or decomposition reactions occur that alter the composition of the foam. These findings suggest that achieving a fully cured foam part with this formulation may be not be possible through therma l curing. As such, visco elastic characterization procedures developed for curing thermosets can provide only approximate material properties, since the state of the material continuously evolves during tests.

  14. Lysophosphatidic acid directly induces macrophage-derived foam cell formation by blocking the expression of SRBI.

    Science.gov (United States)

    Chen, Linmu; Zhang, Jun; Deng, Xiao; Liu, Yan; Yang, Xi; Wu, Qiong; Yu, Chao

    2017-09-23

    The leading cause of morbidity and mortality is the result of cardiovascular disease, mainly atherosclerosis. The formation of macrophage foam cells by ingesting ox-LDL and focal retention in the subendothelial space are the hallmarks of the early atherosclerotic lesion. Lysophosphatidic acid (LPA), which is a low-molecular weight lysophospholipid enriched in oxidized LDL, exerts a range of effects on the cardiovascular system. Previous reports show that LPA increases the uptake of ox-LDL to promote the formation of foam cells. However, as the most active component of ox-LDL, there is no report showing whether LPA directly affects foam cell formation. The aim of this study was to investigate the effects of LPA on foam cell formation, as well as to elucidate the underlying mechanism. Oil red O staining and a Cholesterol/cholesteryl ester quantitation assay were used to evaluate foam cell formation in Raw264.7 macrophage cells. We utilized a Western blot and RT-PCR to investigate the relationship between LPA receptors and lipid transport related proteins. We found that LPA promoted foam cell formation, using 200 μM for 24 h. Meanwhile, the expression of the Scavenger receptor BI (SRBI), which promotes the efflux of free cholesterol, was decreased. Furthermore, the LPA 1/3 receptor antagonist Ki16425 significantly abolished the LPA effects, indicating that LPA 1/3 was involved in the foam cell formation and SRBI expression induced by LPA. Additionally, the LPA-induced foam cell formation was blocked with an AKT inhibitor. Our results suggest that LPA-enhanced foam cell formation is mediated by LPA 1/3 -AKT activation and subsequent SRBI expression. Copyright © 2017. Published by Elsevier Inc.

  15. Modyfication of the Rigid Polyurethane-Polyisocyanurate Foams

    Directory of Open Access Journals (Sweden)

    Bogusław Czupryński

    2014-01-01

    Full Text Available The effect of polyethylene glycol 1500 on physicomechanical properties of rigid polyurethane-polyisocyanurate (PUR-PIR foams has been studied. It was found that application of polyethylene glycol 1500 for synthesis of foams in amount from 0% to 20% w/w had an effect on reduction of brittleness and softening point, while the greater the increase in compressive strength the higher its content in foam composition was. Wastes from production of these foams were ground and subjected to glycolysis in diethylene glycol with the addition of ethanolamine and zinc stearate. Liquid brown products were obtained. Properties of the resulting products were defined in order to determine their suitability for synthesis of new foams. It was found that glycolysate 6 was the most suitable for reuse and its application in different amounts allowed us to prepare 4 new foams (nos. 25, 26, 27, and 28. Properties of foams prepared in this manner were determined and, on their basis, the suitability of glycolysates for production of rigid PUR-PIR foams was evaluated.

  16. Nanoparticle-stabilized CO₂ foam for CO₂ EOR application

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Ning [New Mexico Petroleum Recovery Research Center, Socorro, NM (United States); Lee, Robert [New Mexico Petroleum Recovery Research Center, Socorro, NM (United States); Yu, Jianjia [New Mexico Petroleum Recovery Research Center, Socorro, NM (United States); Li, Liangxiong [New Mexico Petroleum Recovery Research Center, Socorro, NM (United States); Bustamante, Elizabeth [New Mexico Petroleum Recovery Research Center, Socorro, NM (United States); Khalil, Munawar [New Mexico Petroleum Recovery Research Center, Socorro, NM (United States); Mo, Di [New Mexico Petroleum Recovery Research Center, Socorro, NM (United States); Jia, Bao [New Mexico Petroleum Recovery Research Center, Socorro, NM (United States); Wang, Sai [New Mexico Petroleum Recovery Research Center, Socorro, NM (United States); San, Jingshan [New Mexico Petroleum Recovery Research Center, Socorro, NM (United States); An, Cheng [New Mexico Petroleum Recovery Research Center, Socorro, NM (United States)

    2015-01-31

    The purpose of this project was to develop nanoparticle-stabilized CO₂ foam for CO₂ -EOR application, in which nanoparticles instead of surfactants are used for stabilizing CO₂ foam to improve the CO₂ sweep efficiency and increase oil recovery. The studies included: (1) investigation of CO₂ foam generation nanoparticles, such as silica nanoparticles, and the effects of particle concentration and surface properties, CO₂/brine ratio, brine salinity, pressure, and temperature on foam generation and foam stability; (2) coreflooding tests to understand the nanoparticle-stabilized CO₂ foam for waterflooded residual oil recovery, which include: oil-free coreflooding experiments with nanoparticle-stabilized CO₂ foam to understand the transportation of nanoparticles through the core; measurements of foam stability and CO₂ sweep efficiency under reservoir conditions to investigate temperature and pressure effects on the foam performance and oil recovery as well as the sweep efficiency in different core samples with different rock properties; and (3) long-term coreflooding experiments with the nanoparticle- stabilized CO₂ foam for residual oil recovery. Finally, the technical and economical feasibility of this technology was evaluated.

  17. Coalescence measurements for evolving foams monitored by real-time projection imaging

    International Nuclear Information System (INIS)

    Myagotin, A; Helfen, L; Baumbach, T

    2009-01-01

    Real-time radiographic projection imaging together with novel spatio-temporal image analysis is presented to be a powerful technique for the quantitative analysis of coalescence processes accompanying the generation and temporal evolution of foams and emulsions. Coalescence events can be identified as discontinuities in a spatio-temporal image representing a sequence of projection images. Detection, identification of intensity and localization of the discontinuities exploit a violation criterion of the Fourier shift theorem and are based on recursive spatio-temporal image partitioning. The proposed method is suited for automated measurements of discontinuity rates (i.e., discontinuity intensity per unit time), so that large series of radiographs can be analyzed without user intervention. The application potential is demonstrated by the quantification of coalescence during the formation and decay of metal foams monitored by real-time x-ray radiography

  18. New decontamination process using foams containing particles

    International Nuclear Information System (INIS)

    Guignot, S.; Faure, S.

    2008-01-01

    One key point in the dismantling of nuclear facilities is the thorough cleaning of radiation- exposed surfaces on which radioactive deposits have formed. This cleaning step is often achieved by successive liquid rinses with specific solutions containing alkaline, acidic, or even oxidizing species depending on whether the aim is to dissolve greasy deposits (like ter-butylphosphate) or to corrode surfaces on micrometric thicknesses. An alternative process to reduce the amount of chemicals and the volume of the resulting nuclear wastes consists in using the same but foamed solutions (1). Carrying less liquid, the resulting foams still display similar kinetics of dissolution rates and their efficiency is determined by their ability to hold sufficient wetnesses during the time required for the decontamination. Classical foam decontamination process illustrated by foam pulverization or circulation in the 90 turned five years ago into a specific static process using high-lifetime viscosified foam at a steady state. One way to slow down the liquid drainage is to raise liquid viscosity by adding organic viscosifiers like xanthan gum (2). In 2005, new studies started on an innovative process proposed by S. Faure and based on triphasic foams containing particles [3]. The aim is to generate new decontamination foams containing less quantities of organics materials (surfactants and viscosifiers). Silica particles are obviously known to stabilize or destabilize foams (4). In the frame of S. Guignot Ph.D., new fundamental studies are initiated in order to clarify the role of silica solid microparticles in these foams. Our final goal is to determine whether this kind of new foam can be stable for several hours for a decontamination process. The results we will report focus on wet foams used for nuclear decontamination and incorporating fumed silica. The study is conducted on a vertical foam column in a pseudo-free drainage configuration, and aims at investigating the influence of

  19. Viscous Control of the Foam Glass Process

    DEFF Research Database (Denmark)

    Petersen, Rasmus Rosenlund; König, Jakob; Smedskjær, Morten Mattrup

    The production of foam glass as heat insulating material is an important industrial process because it enables low-cost recycling of glass waste from a variety of chemical compositions. Optimization of the foaming process of new glass waste compositions is time consuming, since many factors affect...... the foaming process such as temperature, particle size, type and concentration of foaming agent. The foaming temperature is one of the key factors, because even small temperature changes can affect the melt viscosity by several orders of magnitude. Therefore, it is important to establish the viscosity range...... in which the foaming process should take place, particularly when the type of recycled cullet is changed or several types of cullet are mixed in one batch. According to recent glass literature, the foaming process should occur at viscosity 103 to 105 Pa s. However, no systematic studies have hitherto been...

  20. Preparation of Microcellular Epoxy Foams through a Limited-Foaming Process: A Contradiction with the Time-Temperature-Transformation Cure Diagram.

    Science.gov (United States)

    Wang, Lijun; Zhang, Chun; Gong, Wei; Ji, Yubi; Qin, Shuhao; He, Li

    2018-01-01

    3D cross-linking networks are generated through chemical reactions between thermosetting epoxy resin and hardener during curing. The curing degree of epoxy material can be increased by increasing curing temperature and/or time. The epoxy material must then be fully cured through a postcuring process to optimize its material characteristics. Here, a limited-foaming method is introduced for the preparation of microcellular epoxy foams (Lim-foams) with improved cell morphology, high thermal expansion coefficient, and good compressive properties. Lim-foams exhibit a lower glass transition temperature (T g ) and curing degree than epoxy foams fabricated through free-foaming process (Fre-foams). Surprisingly, however, the T g of Lim-foams is unaffected by postcuring temperature and time. This phenomenon, which is related to high gas pressure in the bubbles, contradicts that indicated by the time-temperature-transformation cure diagram. High bubble pressure promotes the movement of molecular chains under heating at low temperature and simultaneously suppresses the etherification cross-linking reaction during post-curing. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  1. USING BIOPOLYMERS TO STABILIZE THE PROTEIN OXYGEN FOAM

    Directory of Open Access Journals (Sweden)

    N. V. Nepovinnyh

    2013-01-01

    Full Text Available The cottage cheese whey as an oxygen cocktail foaming base and natural juices as a flavoring ingredient are analyzed. The lifetime of foam generated by the serum proteins is not long: foam falls off rapidly; because from the foam liquid is released (syneresis. The effects of plant polysaccharides on the stabilization of the protein foam oxygen cocktail is studied. It was shown that the use of plant polysaccharides (guar gum, high methoxyl citrus pectin, locust been gum prolong the life of the foam up to 20 times, compared with conventional blowing agents. It was found that oxygen foam properties depend on the molecular weight of guar gum.

  2. Dynamics of poroelastic foams

    Science.gov (United States)

    Forterre, Yoel; Sobac, Benjamin

    2010-11-01

    Soft poroelastic structures are widespread in biological tissues such as cartilaginous joints in bones, blood-filled placentae or plant organs. Here we investigate the dynamics of open elastic foams immersed in viscous fluids, as model soft poroelastic materials. The experiment consists in slowly compacting blocs of polyurethane solid foam embedded in silicon oil-tanks and studying their relaxation to equilibrium when the confining stress is suddenly released. Measurements of the local fluid pressure and foam velocity field are compared with a simple two-phase flow approach. For small initial compactions, the results show quantitative agreement with the classical diffusion theory of soil consolidation (Terzaghi, Biot). On the other hand, for large initial compactions, the dynamics exhibits long relaxation times and decompaction fronts, which are mainly controlled by the highly non-linear mechanical response of the foam. The analogy between this process and the evaporation of a polymer melt close to the glass transition will be briefly discussed.

  3. Mechanical Characterization of Lightweight Foamed Concrete

    Directory of Open Access Journals (Sweden)

    Marcin Kozłowski

    2018-01-01

    Full Text Available Foamed concrete shows excellent physical characteristics such as low self weight, relatively high strength and superb thermal and acoustic insulation properties. It allows for minimal consumption of aggregate, and by replacement of a part of cement by fly ash, it contributes to the waste utilization principles. For many years, the application of foamed concrete has been limited to backfill of retaining walls, insulation of foundations and roof tiles sound insulation. However, during the last few years, foamed concrete has become a promising material for structural purposes. A series of tests was carried out to examine mechanical properties of foamed concrete mixes without fly ash and with fly ash content. In addition, the influence of 25 cycles of freezing and thawing on the compressive strength was investigated. The apparent density of hardened foamed concrete is strongly correlated with the foam content in the mix. An increase of the density of foamed concrete results in a decrease of flexural strength. For the same densities, the compressive strength obtained for mixes containing fly ash is approximately 20% lower in comparison to the specimens without fly ash. Specimens subjected to 25 freeze-thaw cycles show approximately 15% lower compressive strengths compared to the untreated specimens.

  4. Materials Applications for Non-Lethal: Aqueous Foams

    Energy Technology Data Exchange (ETDEWEB)

    GOOLSBY,TOMMY D.; SCOTT,STEVEN H.

    1999-09-15

    High expansion aqueous foam is an aggregation of bubbles that has the appearance of soap suds and is used to isolate individuals both visually and acoustically. It was developed in the 1920's in England to fight coal mine fires and has been widely used since for fire fighting and dust suppression. It was developed at Sandia National Laboratories (SNL) in the 1970's for nuclear safeguards and security applications. In the mid-1990s, the National Institute of Justice (NIJ), the research arm of the Department of Justice, began a project with SNL to determine the applicability of high expansion aqueous foam for correctional applications. NIJ funded the project as part of its search for new and better less-than-lethal weapons for responding to violent and dangerous individuals, where other means of force could lead to serious injuries. The phase one objectives of the project were to select a low-to-no toxicity foam concentrate (foaming agent) with physical characteristics suited for use in a single cell or large prison disturbances, and to determine if the selected foam concentrate could serve as a carrier for Oleoresin Capsicum (OC) irritant. The phase two objectives were to conduct an extensive toxicology review of the selected foam concentrate and OC irritant, and to conduct respiration simulation experiments in the selected high expansion aqueous foam. The phase three objectives were to build a prototype individual cell aqueous foam system and to study the feasibility of aqueous foams for large prison facility disturbances. The phase four and five objectives were to use the prototype system to do large scale foam physical characteristics testing of the selected foam concentrate, and to have the prototype single cell system further evaluated by correctional representatives. Prison rather than street scenarios were evaluated as the first and most likely place for using the aqueous foam since prisons have recurrent incidents where officers and inmates might

  5. Materials Applications for Non-Lethal: Aqueous Foams

    International Nuclear Information System (INIS)

    GOOLSBY, TOMMY D.; SCOTT, STEVEN H.

    1999-01-01

    High expansion aqueous foam is an aggregation of bubbles that has the appearance of soap suds and is used to isolate individuals both visually and acoustically. It was developed in the 1920's in England to fight coal mine fires and has been widely used since for fire fighting and dust suppression. It was developed at Sandia National Laboratories (SNL) in the 1970's for nuclear safeguards and security applications. In the mid-1990s, the National Institute of Justice (NIJ), the research arm of the Department of Justice, began a project with SNL to determine the applicability of high expansion aqueous foam for correctional applications. NIJ funded the project as part of its search for new and better less-than-lethal weapons for responding to violent and dangerous individuals, where other means of force could lead to serious injuries. The phase one objectives of the project were to select a low-to-no toxicity foam concentrate (foaming agent) with physical characteristics suited for use in a single cell or large prison disturbances, and to determine if the selected foam concentrate could serve as a carrier for Oleoresin Capsicum (OC) irritant. The phase two objectives were to conduct an extensive toxicology review of the selected foam concentrate and OC irritant, and to conduct respiration simulation experiments in the selected high expansion aqueous foam. The phase three objectives were to build a prototype individual cell aqueous foam system and to study the feasibility of aqueous foams for large prison facility disturbances. The phase four and five objectives were to use the prototype system to do large scale foam physical characteristics testing of the selected foam concentrate, and to have the prototype single cell system further evaluated by correctional representatives. Prison rather than street scenarios were evaluated as the first and most likely place for using the aqueous foam since prisons have recurrent incidents where officers and inmates might be

  6. Size effects in manufacturing of metallic components

    DEFF Research Database (Denmark)

    Vollertsen, F; Biermann, D; Hansen, Hans Nørgaard

    2009-01-01

    In manufacturing of metallic components, the size of the part plays an important role for the process behaviour. This is due to so called size effects, which lead to changes in the process behaviour even if the relationship between the main geometrical features is kept constant. The aim...... of this paper is to give a systematic review on Such effects and their potential use or remedy. First, the typology of size effects will be explained, followed by a description of size effects on strength and tribology. The last three sections describe size effects on formability, forming processes and cutting...... processes. (C) 2009 CIRP....

  7. Modification of Foamed Articles Based on Cassava Starch

    International Nuclear Information System (INIS)

    Ponce, P.

    2006-01-01

    This work reports the influence of radiation, plasticizers and poly vinyl alcohol (PVA) on the barrier properties [water vapour permeability (WVP)) and mechanical properties (tensile strength and elongation; compression resistance and flexibility) of foamed articles based on cassava starch. The starch foam was obtained by thermopressing process. Poly ethylene glycol (PEG, 300) was selected as plasticizer and water was necessary for the preparation of the foams. The foamed articles based on cassava starch were irradiated at low doses of 2 and 5 kGy, commonly used in food irradiation. The mechanical properties of starch foams are influenced by the plasticizer concentration and by irradiation dose. An increase in PEG content showed a considerable increase in elongation percentage and a decrease in the tensile strength of the foams; also increase the permeability of the foams in water. After irradiation, the barrier properties and mechanical properties of the foams were improved due to chemical reactions among polymer molecules. Irradiated starch cassava foams with poly vinyl alcohol (PVA) have good flexibility and low water permeability. WVP can be reduced by low doses of gamma radiation

  8. Dynamic and Thermal Properties of Aluminum Alloy A356/Silicon Carbide Hollow Particle Syntactic Foams

    Directory of Open Access Journals (Sweden)

    James Cox

    2014-12-01

    Full Text Available Aluminum alloy A356 matrix syntactic foams filled with SiC hollow particles (SiCHP are studied in the present work. Two compositions of syntactic foams are studied for quasi-static and high strain rate compression. In addition, dynamic mechanical analysis is conducted to study the temperature dependent energy dissipation and damping capabilities of these materials. The thermal characterization includes study of the coefficient of thermal expansion (CTE. A356/SiCHP syntactic foams are not strain rate sensitive as the compressive strength displayed little variation between the tested strain rates of 0.001–2100 s−1. Microscopic analysis of the high strain rate compression tested specimens showed that the fracture is initiated by the failure of hollow particles at the onset of the plastic deformation region. This is followed by plastic deformation of the matrix material and further crushing of particles. The syntactic foams showed decrease in storage modulus with increasing temperature and the trend was nearly linear up to 500 °C. The alloy shows a similar behavior at low temperature but the decrease in storage modulus increases sharply over 375 °C. The loss modulus is very small for the tested materials because of lack of viscoelasticity in metallic materials. The trend in the loss modulus is opposite, where the matrix alloy has lower loss modulus than syntactic foams at low temperature. However, over 250 °C the matrix loss modulus starts to increase rapidly and attains a peak around 460 °C. Syntactic foams have higher damping parameter at low temperatures than the matrix alloy. Incorporation of SiCHP helps in decreasing CTE. Compared to the CTE of the matrix alloy, 23.4 × 10−6 °C−1, syntactic foams showed CTE values as low as 11.67 × 10−6 °C−1.

  9. Workshop Report on Additive Manufacturing for Large-Scale Metal Components - Development and Deployment of Metal Big-Area-Additive-Manufacturing (Large-Scale Metals AM) System

    Energy Technology Data Exchange (ETDEWEB)

    Babu, Sudarsanam Suresh [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Manufacturing Demonstration Facility; Love, Lonnie J. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Manufacturing Demonstration Facility; Peter, William H. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Manufacturing Demonstration Facility; Dehoff, Ryan [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Manufacturing Demonstration Facility

    2016-05-01

    Additive manufacturing (AM) is considered an emerging technology that is expected to transform the way industry can make low-volume, high value complex structures. This disruptive technology promises to replace legacy manufacturing methods for the fabrication of existing components in addition to bringing new innovation for new components with increased functional and mechanical properties. This report outlines the outcome of a workshop on large-scale metal additive manufacturing held at Oak Ridge National Laboratory (ORNL) on March 11, 2016. The charter for the workshop was outlined by the Department of Energy (DOE) Advanced Manufacturing Office program manager. The status and impact of the Big Area Additive Manufacturing (BAAM) for polymer matrix composites was presented as the background motivation for the workshop. Following, the extension of underlying technology to low-cost metals was proposed with the following goals: (i) High deposition rates (approaching 100 lbs/h); (ii) Low cost (<$10/lbs) for steel, iron, aluminum, nickel, as well as, higher cost titanium, (iii) large components (major axis greater than 6 ft) and (iv) compliance of property requirements. The above concept was discussed in depth by representatives from different industrial sectors including welding, metal fabrication machinery, energy, construction, aerospace and heavy manufacturing. In addition, DOE’s newly launched High Performance Computing for Manufacturing (HPC4MFG) program was reviewed. This program will apply thermo-mechanical models to elucidate deeper understanding of the interactions between design, process, and materials during additive manufacturing. Following these presentations, all the attendees took part in a brainstorming session where everyone identified the top 10 challenges in large-scale metal AM from their own perspective. The feedback was analyzed and grouped in different categories including, (i) CAD to PART software, (ii) selection of energy source, (iii

  10. Corrugated metal surface with pillars for terahertz surface plasmon polariton waveguide components

    KAUST Repository

    Yuehong, Xu; Yanfeng, Li; Chunxiu, Tian; Jiaguang, Han; Quan, Xu; Xueqian, Zhang; Xixiang, Zhang; Ying, Zhang; Weili, Zhang

    2018-01-01

    In the terahertz regime, due to perfect conductivity of most metals, it is hard to realize a strong confinement of Surface plasmon polaritons (SPPs) although a propagation loss could be sufficiently low. We experimentally demonstrated a structure with periodic pillars arranged on a thin metal surface that supports bound modes of spoof SPPs at terahertz (THz) frequencies. By using scanning near-field THz microscopy, the electric field distribution above the metal surface within a distance of 130 μm was mapped. The results proved that this structure could guide spoof SPPs propagating along subwavelength waveguides, and at the same time reduce field expansion into free space. Further, for the development of integrated optical circuits, several components including straight waveguide, S-bend, Y-splitter and directional couplers were designed and characterized by the same method. We believe that the waveguide components proposed here will pave a new way for the development of flexible, wideband and compact photonic circuits operating at THz frequencies.

  11. Corrugated metal surface with pillars for terahertz surface plasmon polariton waveguide components

    KAUST Repository

    Yuehong, Xu

    2018-01-12

    In the terahertz regime, due to perfect conductivity of most metals, it is hard to realize a strong confinement of Surface plasmon polaritons (SPPs) although a propagation loss could be sufficiently low. We experimentally demonstrated a structure with periodic pillars arranged on a thin metal surface that supports bound modes of spoof SPPs at terahertz (THz) frequencies. By using scanning near-field THz microscopy, the electric field distribution above the metal surface within a distance of 130 μm was mapped. The results proved that this structure could guide spoof SPPs propagating along subwavelength waveguides, and at the same time reduce field expansion into free space. Further, for the development of integrated optical circuits, several components including straight waveguide, S-bend, Y-splitter and directional couplers were designed and characterized by the same method. We believe that the waveguide components proposed here will pave a new way for the development of flexible, wideband and compact photonic circuits operating at THz frequencies.

  12. Structure formation control of foam concrete

    Science.gov (United States)

    Steshenko, Aleksei; Kudyakov, Aleksander; Konusheva, Viktoriya; Syrkin, Oleg

    2017-01-01

    The process of predetermined foam concrete structure formation is considered to be a crucial issue from the point of process control and it is currently understudied thus defining the need for additional research. One of the effective ways of structure formation control in naturally hardening foam concrete is reinforcement with dispersed fibers or introduction of plasticizers. The paper aims at studying the patterns of influence of microreinforcing and plasticizing additives on the structure and performance properties of foam concrete. Preparation of foam concrete mix has been conducted using one-step technology. The structure of modified foam concrete has been studied by means of electron microscopy. The cellular structure of foam concrete samples with the additives is homogeneous; the pores are uniformly distributed over the total volume. It has been revealed that introduction of the Neolas 5.2 plasticizer and microreinforcing fibers in the foam concrete mixture in the amount of 0.4 - 0.1 % by weight of cement leads to reduction of the average pore diameter in the range of 45.3 to 30.2 microns and the standard deviation of the pore average diameter from 23.6 to 9.2 in comparison with the sample without additive. Introduction of modifying additives has stimulated formation of a large number of closed pores. Thus porosity of conditionally closed pores has increased from 16.06 % to 34.48 %, which has lead to increase of frost resistance brand of foam concrete from F15 to F50 and to reduction of its water absorption by weight by 20 %.

  13. Faraday instability at foam-water interface.

    Science.gov (United States)

    Bronfort, A; Caps, H

    2012-12-01

    A nearly two-dimensional foam is generated inside a Hele-shaw cell and left at rest on its liquid bath. The system is then vertically shaken and, above a well-defined acceleration threshold, surface waves appear at the foam-liquid interface. Those waves are shown to be subharmonic. The acceleration threshold is studied and compared to the common liquid-gas case, emphasizing the energy dissipation inside the foam. An empirical model is proposed for this energy loss, accounting for the foam characteristics such as the bubble size but also the excitation parameter, namely the linear velocity.

  14. Photoactivity of Titanium Dioxide Foams

    Directory of Open Access Journals (Sweden)

    Maryam Jami

    2018-01-01

    Full Text Available TiO2 foams have been prepared by a simple mechanical stirring method. Short-chain amphiphilic molecules have been used to stabilize colloidal suspensions of TiO2 nanoparticles. TiO2 foams were characterized by X-ray diffraction (XRD, X-ray photoelectron spectroscopy (XPS, UV-vis absorption spectroscopy, and scanning electron microscopy (SEM. The photoassisted oxidation of NO in the gas phase according to ISO 22197-1 has been used to compare the photoactivity of the newly prepared TiO2 foams to that of the original powders. The results showed that the photoactivity is increased up to about 135%. Foam structures seem to be a good means of improving the photoactivity of semiconductor materials and can readily be used for applications such as air purification devices.

  15. Microcellular foams via phase separation

    International Nuclear Information System (INIS)

    Young, A.T.

    1985-01-01

    A study of wide variety of processes for making plastic foams shows that phase separation processes for polymers from solutions offers the most viable methods for obtaining rigid plastic foams which met the physical requirements for fusion target designs. Four general phase separation methods have been shown to give polymer foams with densities less than 0.1 g/cm 3 and cell sizes of 30μm or less. These methods involve the utilization of non-solvent, chemical or thermal cooling processes to achieve a controlled phase separation wherein either two distinct phases are obtained where the polymer phase is a continuous phase or two bicontinuous phases are obtained where both the polymer and solvent are interpenetrating, continuous, labyrinthine phases. Subsequent removal of the solvent gives the final foam structure

  16. Integration of Computer Tomography and Simulation Analysis in Evaluation of Quality of Ceramic-Carbon Bonded Foam Filter

    Directory of Open Access Journals (Sweden)

    Karwiński A.

    2013-12-01

    Full Text Available Filtration of liquid casting alloys is used in casting technologies for long time. The large quantity of available casting filters allows using them depending on casting technology, dimensions of casting and used alloys. Technological progress of material science allows of using new materials in production of ceramic filters. In this article the Computed Tomography (CT technique was use in order to evaluate the thickness of branch in cross section of 20ppi ceramic-carbon bonded foam filter. Than the 3D image of foam filter was used in computer simulation of flow of liquid metal thru the running system.

  17. Metal Cutting for Large Component Removal

    International Nuclear Information System (INIS)

    Hulick, Robert M.

    2008-01-01

    Decommissioning of commercial nuclear power plants presents technological challenges. One major challenge is the removal of large components mainly consisting of the reactor vessel, steam generators and pressurizer. In order to remove and package these large components nozzles must be cut from the reactor vessel to precise tolerances. In some cases steam generators must be segmented for size and weight reduction. One innovative technology that has been used successfully at several commercial nuclear plant decommissioning is diamond wire sawing. Diamond wire sawing is performed by rotating a cable with diamond segments attached using a flywheel approximately 24 inches in diameter driven remotely by a hydraulic pump. Tension is provided using a gear rack drive which also takes up the slack in the wire. The wire is guided through the use of pulleys keeps the wire in a precise location. The diamond wire consists of 1/4 inch aircraft cable with diamond beads strung over the cable separated by springs and brass crimps. Standard wire contains 40 diamond beads per meter and can be made to any length. Cooling the wire and controlling the spread of contamination presents significant challenges. Under normal circumstances the wire is cooled and the cutting kerf cleaned by using water. In some cases of reactor nozzle cuts the use of water is prohibited because it cannot be controlled. This challenge was solved by using liquid Carbon Dioxide as the cooling agent. The liquid CO 2 is passed through a special nozzle which atomizes the liquid into snowflakes which is introduced under pressure to the wire. The snowflakes attach to the wire keeping it cool and to the metal shavings. As the CO 2 and metal shavings are released from the wire due to its fast rotation, the snowflakes evaporate leaving only the fine metal shavings as waste. Secondary waste produced is simply the small volume of fine metal shavings removed from the cut surface. Diamond wire sawing using CO 2 cooling has

  18. Morphological comparison of PVA scaffolds obtained by gas foaming and microfluidic foaming techniques.

    Science.gov (United States)

    Colosi, Cristina; Costantini, Marco; Barbetta, Andrea; Pecci, Raffaella; Bedini, Rossella; Dentini, Mariella

    2013-01-08

    In this article, we have exploited a microfluidic foaming technique for the generation of highly monodisperse gas-in-liquid bubbles as a templating system for scaffolds characterized by an ordered and homogeneous porous texture. An aqueous poly(vinyl alcohol) (PVA) solution (containing a surfactant) and a gas (argon) are injected simultaneously at constant flow rates in a flow-focusing device (FFD), in which the gas thread breaks up to form monodisperse bubbles. Immediately after its formation, the foam is collected and frozen in liquid nitrogen, freeze-dried, and cross-linked with glutaraldehyde. In order to highlight the superior morphological quality of the obtained porous material, a comparison between this scaffold and another one, also constituted of PVA but obtained with a traditional gas foaming technique, was carried out. Such a comparison has been conducted by analyzing electron microscopy and X-ray microtomographic images of the two samples. It turned out that the microfluidic produced scaffold was characterized by much more uniform porous texture than the gas-foaming one as witnessed by narrower pore size, interconnection, and wall thickness distributions. On the other side, scarce pore interconnectivity, relatively low pore volume, and limited production rate represent, by now, the principal disadvantages of microfluidic foaming as scaffold fabrication method, emphasizing the kind of improvement that this technique needs to undergo.

  19. DRY MIX FOR OBTAINING FOAM CONCRETE

    Directory of Open Access Journals (Sweden)

    S. N. Leonovich

    2015-01-01

    Full Text Available Composition of a dry mix has been developed for production of non-autoclaved foam concrete with natural curing. The mix has been created on the basis of Portland cement, UFAPORE foaming agent, mineral additives (RSAM sulfoaluminate additive, MK-85 micro-silica and basalt fiber, plasticizing and accelerating “Citrate-T” additive and   redispersible Vinnapas-8034 H powder. It has been established that foam concrete with  density of 400–800 kg/m3, durability of 1,1–3,4 MPa, low water absorption (40–50 %, without shrinkable cracks has been formed while adding water of Water/Solid = 0.4–0.6 in the dry mix,  subsequent mechanical swelling and curing of foam mass.Introduction of the accelerating and plasticizing “Citrate-T” additive into composition of the dry mix leads to an increase of rheological properties in expanded foam mass and  time reduction of its drying and curing. An investigation on microstructure of foam-concrete chipping surface carried out with the help of a scanning electron microscope has shown that the introduction of  basalt fiber and redispersible Vinnapas-8034 H powder into the composition of the dry mix promotes formation of more finely-divided crystalline hydrates. Such approach makes it possible to change purposefully morphology of crystalline hydrates and gives the possibility to operate foam concrete structurization process.

  20. Drainage and Stratification Kinetics of Foam Films

    Science.gov (United States)

    Zhang, Yiran; Sharma, Vivek

    2014-03-01

    Baking bread, brewing cappuccino, pouring beer, washing dishes, shaving, shampooing, whipping eggs and blowing bubbles all involve creation of aqueous foam films. Foam lifetime, drainage kinetics and stability are strongly influenced by surfactant type (ionic vs non-ionic), and added proteins, particles or polymers modify typical responses. The rate at which fluid drains out from a foam film, i.e. drainage kinetics, is determined in the last stages primarily by molecular interactions and capillarity. Interestingly, for certain low molecular weight surfactants, colloids and polyelectrolyte-surfactant mixtures, a layered ordering of molecules, micelles or particles inside the foam films leads to a stepwise thinning phenomena called stratification. Though stratification is observed in many confined systems including foam films containing particles or polyelectrolytes, films containing globular proteins seem not to show this behavior. Using a Scheludko-type cell, we experimentally study the drainage and stratification kinetics of horizontal foam films formed by protein-surfactant mixtures, and carefully determine how the presence of proteins influences the hydrodynamics and thermodynamics of foam films.

  1. Cellulose nanocrystals reinforced foamed nitrile rubber nanocomposites.

    Science.gov (United States)

    Chen, Yukun; Zhang, Yuanbing; Xu, Chuanhui; Cao, Xiaodong

    2015-10-05

    Research on foamed nitrile rubber (NBR)/cellulose nanocrystals (CNs) nanocomposites is rarely found in the literatures. In this paper, CNs suspension and NBR latex was mixed to prepared the foamed NBR/CNs nanocomposites. We found that the CNs mainly located in the cell walls, effectively reinforcing the foamed NBR. The strong interaction between the CNs and NBR matrix restricted the mobility of NBR chains surrounding the CNs, hence increasing the crosslink density of the NBR matrix. CNs exhibited excellent reinforcement on the foamed NBR: a remarkable increase nearly 76% in the tensile strength of the foamed nanocomposites was achieved with a load of only 15 phr CNs. Enhanced mechanical properties make the foamed NBR/CNs nanocomposites a promising damping material for industrial applications with a potential to reduce the petroleum consumption. Copyright © 2015 Elsevier Ltd. All rights reserved.

  2. Recycle Glass in Foam Glass Production

    DEFF Research Database (Denmark)

    Petersen, Rasmus Rosenlund; König, Jakob; Yue, Yuanzheng

    The foam glass industry turn recycle glass into heat insulating building materials. The foaming process is relative insensitive to impurities in the recycle glass. It is therefore considered to play an important role in future glass recycling. We show and discuss trends of use of recycled glasses...... in foam glass industry and the supply sources and capacity of recycle glass....

  3. EMS providers do not use FOAM for education.

    Science.gov (United States)

    Bucher, Joshua; Donovan, Colleen; McCoy, Jonathan

    2018-05-24

    Free open access to medical education (FOAM, #FOAM) is the free availability of educational materials on various medicine topics. We hope to evaluate the use of social media and FOAM by emergency medical services (EMS) providers. We designed an online survey distributed to EMS providers with questions about demographics and social media/FOAM use by providers. The survey was sent to the American College of Emergency Physicians (ACEP) EMS Listserv of medical directors and was asked to be distributed to their respective agencies. The survey was designed to inquire about the providers' knowledge of FOAM and social media and their use of the above for EMS education. There were 169 respondents out of a total of 523 providers yielding a response rate of 32.3%. Fifty-three percent of respondents are paramedics, 37% are EMT-Basic trained, and the remainder (16%) were "other." The minority (20%) of respondents had heard of FOAM. However, 54% of respondents had heard of "free medical education online" regarding pertinent topics. Of the total respondents who used social media for education, 31% used Facebook and 23% used blogs and podcasts as resources for online education. Only 4% of respondents stated they produced FOAM content. Seventy-six percent of respondents said they were "interested" or "very interested" in using FOAM for medical education. If FOAM provided continuing medical education (CME), 83% of respondents would be interested in using it. Social media is not used frequently by EMS providers for the purposes of FOAM. There is interest within EMS providers to use FOAM for education, even if CME was not provided. FOAM can provide a novel area of education for EMS.

  4. Rigid Polyurethane Foam Reinforced Coconut Coir Fiber Properties

    OpenAIRE

    Mohd Azham Azmi

    2012-01-01

    This research work studied the properties of composite foam panels. Coconut coir fibers were used as reinforcement in polyurethane (PU) foam in order to increase the properties of foam. This composite foam panels were fabricated by using polyurethane molded method. The polyurethane foam panels reinforced from 5 to 20wt% coconut coir were produced to investigate the physical and mechanical test via density test and three point bending test respectively. It was found that the density test resul...

  5. Effect of Rigid Polyurethane Foam Core Density on Flexural and Compressive Properties of Sandwich Panels with Glass/Epoxy Faces

    Directory of Open Access Journals (Sweden)

    saeed Nemati

    2013-01-01

    Full Text Available Sandwich panels as composite materials have two external walls of either metallic or polymer type. The space between these walls is filled by hard foam or other materials and the thickness of different layers is based on the final application of the panel. In the present work, the extent of variation in core density of polyether urethane foam and subsequent flexural and compressive changes in sandwich panels with glass or epoxy face sheets are tested and investigated. A number of hard polyether urethane foams with different middle panel layers density 80-295 kg/m3 are designed to study the effect of foam density on mechanical properties including flexural and compressive properties. Flexural and compressive test resultsshow that increased core density leads to improved mechanical properties. The slope of the curve decreases beyond density of 235 kg/m3. The reason may be explained on the limitation of shear intensity in increasing the mechanical properties. In this respect an optimum density of 235 kg/m3 is obtained for the system under examinations and for reaching higher strength panels, foams of different core materials should be selected.

  6. Auxetic Polyurethane Foam (Fabrication, Properties and Applications)

    International Nuclear Information System (INIS)

    Yousif, H.I.Y.

    2012-01-01

    Modern technology requires new materials of special properties. For the last two decades there has been a great interest in a class of materials known as auxetic materials. An auxetic material is a material that has a negative Poisson's ratio which means that this material expands laterally when they subjected to a tensile force unlike most of the other traditional materials. This material has superior properties over the traditional material such as high shear modulus and high impact resistance, which makes this material a good candidate for many engineering applications. In the present research work, auxetic flexible polyurethane polymeric foams having different densities were fabricated from conventional flexible polyurethane polymeric foam at different compression ratios. The microstructure of conventional and processed foams was examined by optical microscope to compare between the two structures. The microstructure of processed foam was compared with the one presented in the literature and it has shown the auxetic structure configuration. This is the first time to produce auxetic foam in Egypt. Conventional and auxetic foam samples having cylindrical and square cross-sections were produced from foams having different densities (25 kg/m 3 and 30 kg/m 3 ). The compression ratios used to produce the auxetic samples are (5.56, 6.94 and 9.26). Four mechanical tests were carried out to get the mechanical properties for both conventional and auxetic foams. Two quasi-static mechanical tests t ension and compression a nd two dynamic mechanical tests H ysteresis and resilience w ere carried out to compare between the conventional and auxetic foams. The quasi-static tensile test was carried out at speed was adjusted to be position control rate of 0.2 mm/s. The compression and hysteresis tests were carried out at strain control rate of 0.3 S -1 . The data recorded from the machine were stress and strain. The modulus of elasticity and Poisson's ratio of the test

  7. Applications of Polymer Matrix Syntactic Foams

    Science.gov (United States)

    Gupta, Nikhil; Zeltmann, Steven E.; Shunmugasamy, Vasanth Chakravarthy; Pinisetty, Dinesh

    2013-11-01

    A collection of applications of polymer matrix syntactic foams is presented in this article. Syntactic foams are lightweight porous composites that found their early applications in marine structures due to their naturally buoyant behavior and low moisture absorption. Their light weight has been beneficial in weight sensitive aerospace structures. Syntactic foams have pushed the performance boundaries for composites and have enabled the development of vehicles for traveling to the deepest parts of the ocean and to other planets. The high volume fraction of porosity in syntactic foams also enabled their applications in thermal insulation of pipelines in oil and gas industry. The possibility of tailoring the mechanical and thermal properties of syntactic foams through a combination of material selection, hollow particle volume fraction, and hollow particle wall thickness has helped in rapidly growing these applications. The low coefficient of thermal expansion and dimensional stability at high temperatures are now leading their use in electronic packaging, composite tooling, and thermoforming plug assists. Methods have been developed to tailor the mechanical and thermal properties of syntactic foams independent of each other over a wide range, which is a significant advantage over other traditional particulate and fibrous composites.

  8. Shrinkage deformation of cement foam concrete

    Science.gov (United States)

    Kudyakov, A. I.; Steshenko, A. B.

    2015-01-01

    The article presents the results of research of dispersion-reinforced cement foam concrete with chrysotile asbestos fibers. The goal was to study the patterns of influence of chrysotile asbestos fibers on drying shrinkage deformation of cement foam concrete of natural hardening. The chrysotile asbestos fiber contains cylindrical fiber shaped particles with a diameter of 0.55 micron to 8 microns, which are composed of nanostructures of the same form with diameters up to 55 nm and length up to 22 microns. Taking into account the wall thickness, effective reinforcement can be achieved only by microtube foam materials, the so- called carbon nanotubes, the dimensions of which are of power less that the wall pore diameter. The presence of not reinforced foam concrete pores with perforated walls causes a decrease in its strength, decreases the mechanical properties of the investigated material and increases its shrinkage. The microstructure investigation results have shown that introduction of chrysotile asbestos fibers in an amount of 2 % by weight of cement provides the finely porous foam concrete structure with more uniform size closed pores, which are uniformly distributed over the volume. This reduces the shrinkage deformation of foam concrete by 50%.

  9. Foam for combating mine fires

    Energy Technology Data Exchange (ETDEWEB)

    1989-09-01

    The application of foam in dealing with underground fire is well known due to its smothering action by cutting off air feed to burning fuel as well as acting as coolant. Besides plugging air feed to fire, water could be virtually reached to the fire affected areas much beyond the jet range as underground galleries with low roof restrict jet range of water. This method also enables a closer approach of a fire fighting team by isolating the toxic gases and smoke with a foam plug. The paper describes the development of high expansion foam composition and its application technology in order that foam plug method can be suitably utilized for combating mine fires in India. Three compositions were recommended for generation of high expansion foam: (a) 0.5% sodium/ammonium lauryl sulphate, 0.15 to 0.2% sodium carboxy methyl cellulose, 0.1% booster; (b) 0.5% sodium/ammonium lauryl sulfate, 0.12 to 0.15% alkaline solution of gum arabic, 0.1 to 0.2% ferrous gluconate; and (c) 0.35% sodium/ammonium lauryl sulfate, 0.20% booster, 0.2% xylene sulfonate.

  10. Extra natural gas by foam injection; Extra aardgas door foam-injectie

    Energy Technology Data Exchange (ETDEWEB)

    De Boer, B.

    2008-07-01

    The Dutch Petroleum Company (NAM) has further developed an originally American technology for expanding the economic lifespan of gas fields. Injection of environment-friendly foam enables further extraction of natural gas from nearly depleted gas fields. [mk]. [Dutch] De Nederlandse Aardolie Maatschappij (NAM) heeft een van origine Amerikaanse techniek om de economische levensduur van gasvelden te verlengen verder ontwikkeld. Het injecteren van een milieuvriendelijke zeep (foam) maakt het mogelijk om langer aardgas te produceren uit bijna lege gasvelden.

  11. Foaming in manure based digesters

    DEFF Research Database (Denmark)

    Kougias, Panagiotis; Boe, Kanokwan; Angelidaki, Irini

    2012-01-01

    Anaerobic digestion foaming is one of the major problems that occasionally occurred in the Danish full-scale biogas plants, affecting negatively the overall digestion process. The foam is typically formatted in the main biogas reactor or in the pre-storage tank and the entrapped solids in the foam...... cause severe operational problems, such as blockage of mixing devices, and collapse of pumps. Furthermore, the foaming problem is linked with economic consequences for biogas plants, due to income losses derived from the reduced biogas production, extra labour work and additional maintenance costs...... was increased by the addition of glucose in the feeding substrate. During the 2nd and 4th period the organic loading rate was maintained constant, but instead of glucose, higher concentration of Na-oleate or gelatine was added in the feeding substrate. The results obtained from the above experiment showed...

  12. Foam-like structure of the Universe

    International Nuclear Information System (INIS)

    Kirillov, A.A.; Turaev, D.

    2007-01-01

    On the quantum stage space-time had the foam-like structure. When the Universe cools, the foam structure tempers and does not disappear. We show that effects caused by the foamed structure mimic very well the observed Dark Matter phenomena. Moreover, we show that in a foamed space photons undergo a chaotic scattering and together with every discrete source of radiation we should observe a diffuse halo. We show that the distribution of the diffuse halo of radiation around a point-like source repeats exactly the distribution of dark matter around the same source, i.e., the DM halos are sources of the diffuse radiation

  13. Foam-like structure of the Universe

    Energy Technology Data Exchange (ETDEWEB)

    Kirillov, A.A. [Institute for Applied Mathematics and Cybernetics, 10 Ulyanova str., Nizhny Novgorod 603005 (Russian Federation)], E-mail: ka98@mail.ru; Turaev, D. [Ben-Gurion University of the Negev, P.O.B. 653, Beer-Sheva 84105 (Israel)

    2007-11-15

    On the quantum stage space-time had the foam-like structure. When the Universe cools, the foam structure tempers and does not disappear. We show that effects caused by the foamed structure mimic very well the observed Dark Matter phenomena. Moreover, we show that in a foamed space photons undergo a chaotic scattering and together with every discrete source of radiation we should observe a diffuse halo. We show that the distribution of the diffuse halo of radiation around a point-like source repeats exactly the distribution of dark matter around the same source, i.e., the DM halos are sources of the diffuse radiation.

  14. Effectiveness of Flame Retardants in TufFoam.

    Energy Technology Data Exchange (ETDEWEB)

    Abelow, Alexis Elizabeth [Sandia National Lab. (SNL-CA), Livermore, CA (United States); Nissen, April [Sandia National Lab. (SNL-CA), Livermore, CA (United States); Massey, Lee Taylor [Sandia National Lab. (SNL-CA), Livermore, CA (United States); Whinnery, LeRoy L. [Sandia National Lab. (SNL-CA), Livermore, CA (United States)

    2017-12-01

    An investigation of polyurethane foam filled with known flame retardant fillers including hydroxides, melamine, phosphate-containing compounds, and melamine phosphates was carried out to produce a low-cost material with high flame retardant efficiency. The impact of flame retardant fillers on the physical properties such a s composite foam density, glass transition temperature, storage modulus, and thermal expansion of composite foams was investigated with the goal of synthesizing a robust rigid foam with excellent flame retardant properties.

  15. Modyfication of the Rigid Polyurethane-Polyisocyanurate Foams

    OpenAIRE

    Bogusław Czupryński; Joanna Liszkowska; Joanna Paciorek-Sadowska

    2014-01-01

    The effect of polyethylene glycol 1500 on physicomechanical properties of rigid polyurethane-polyisocyanurate (PUR-PIR) foams has been studied. It was found that application of polyethylene glycol 1500 for synthesis of foams in amount from 0% to 20% w/w had an effect on reduction of brittleness and softening point, while the greater the increase in compressive strength the higher its content in foam composition was. Wastes from production of these foams were ground and subjected to glycolysis...

  16. Supercritical CO2 Foaming of Thermoplastic Materials Derived from Maize: Proof-of-Concept Use in Mammalian Cell Culture Applications

    Science.gov (United States)

    Trujillo-de Santiago, Grissel; Portales-Cabrera, Cynthia Guadalupe; Portillo-Lara, Roberto; Araiz-Hernández, Diana; Del Barone, Maria Cristina; García-López, Erika; Rojas-de Gante, Cecilia; de los Angeles De Santiago-Miramontes, María; Segoviano-Ramírez, Juan Carlos; García-Lara, Silverio; Rodríguez-González, Ciro Ángel; Alvarez, Mario Moisés; Di Maio, Ernesto; Iannace, Salvatore

    2015-01-01

    Background Foams are high porosity and low density materials. In nature, they are a common architecture. Some of their relevant technological applications include heat and sound insulation, lightweight materials, and tissue engineering scaffolds. Foams derived from natural polymers are particularly attractive for tissue culture due to their biodegradability and bio-compatibility. Here, the foaming potential of an extensive list of materials was assayed, including slabs elaborated from whole flour, the starch component only, or the protein fraction only of maize seeds. Methodology/Principal Findings We used supercritical CO2 to produce foams from thermoplasticized maize derived materials. Polyethylene-glycol, sorbitol/glycerol, or urea/formamide were used as plasticizers. We report expansion ratios, porosities, average pore sizes, pore morphologies, and pore size distributions for these materials. High porosity foams were obtained from zein thermoplasticized with polyethylene glycol, and from starch thermoplasticized with urea/formamide. Zein foams had a higher porosity than starch foams (88% and 85%, respectively) and a narrower and more evenly distributed pore size. Starch foams exhibited a wider span of pore sizes and a larger average pore size than zein (208.84 vs. 55.43 μm2, respectively). Proof-of-concept cell culture experiments confirmed that mouse fibroblasts (NIH 3T3) and two different prostate cancer cell lines (22RV1, DU145) attached to and proliferated on zein foams. Conclusions/Significance We conducted screening and proof-of-concept experiments on the fabrication of foams from cereal-based bioplastics. We propose that a key indicator of foamability is the strain at break of the materials to be foamed (as calculated from stress vs. strain rate curves). Zein foams exhibit attractive properties (average pore size, pore size distribution, and porosity) for cell culture applications; we were able to establish and sustain mammalian cell cultures on zein

  17. Supercritical CO2 foaming of thermoplastic materials derived from maize: proof-of-concept use in mammalian cell culture applications.

    Science.gov (United States)

    Trujillo-de Santiago, Grissel; Portales-Cabrera, Cynthia Guadalupe; Portillo-Lara, Roberto; Araiz-Hernández, Diana; Del Barone, Maria Cristina; García-López, Erika; Rojas-de Gante, Cecilia; de Los Angeles De Santiago-Miramontes, María; Segoviano-Ramírez, Juan Carlos; García-Lara, Silverio; Rodríguez-González, Ciro Ángel; Alvarez, Mario Moisés; Di Maio, Ernesto; Iannace, Salvatore

    2015-01-01

    Foams are high porosity and low density materials. In nature, they are a common architecture. Some of their relevant technological applications include heat and sound insulation, lightweight materials, and tissue engineering scaffolds. Foams derived from natural polymers are particularly attractive for tissue culture due to their biodegradability and bio-compatibility. Here, the foaming potential of an extensive list of materials was assayed, including slabs elaborated from whole flour, the starch component only, or the protein fraction only of maize seeds. We used supercritical CO2 to produce foams from thermoplasticized maize derived materials. Polyethylene-glycol, sorbitol/glycerol, or urea/formamide were used as plasticizers. We report expansion ratios, porosities, average pore sizes, pore morphologies, and pore size distributions for these materials. High porosity foams were obtained from zein thermoplasticized with polyethylene glycol, and from starch thermoplasticized with urea/formamide. Zein foams had a higher porosity than starch foams (88% and 85%, respectively) and a narrower and more evenly distributed pore size. Starch foams exhibited a wider span of pore sizes and a larger average pore size than zein (208.84 vs. 55.43 μm2, respectively). Proof-of-concept cell culture experiments confirmed that mouse fibroblasts (NIH 3T3) and two different prostate cancer cell lines (22RV1, DU145) attached to and proliferated on zein foams. We conducted screening and proof-of-concept experiments on the fabrication of foams from cereal-based bioplastics. We propose that a key indicator of foamability is the strain at break of the materials to be foamed (as calculated from stress vs. strain rate curves). Zein foams exhibit attractive properties (average pore size, pore size distribution, and porosity) for cell culture applications; we were able to establish and sustain mammalian cell cultures on zein foams for extended time periods.

  18. Supercritical CO2 foaming of thermoplastic materials derived from maize: proof-of-concept use in mammalian cell culture applications.

    Directory of Open Access Journals (Sweden)

    Grissel Trujillo-de Santiago

    Full Text Available Foams are high porosity and low density materials. In nature, they are a common architecture. Some of their relevant technological applications include heat and sound insulation, lightweight materials, and tissue engineering scaffolds. Foams derived from natural polymers are particularly attractive for tissue culture due to their biodegradability and bio-compatibility. Here, the foaming potential of an extensive list of materials was assayed, including slabs elaborated from whole flour, the starch component only, or the protein fraction only of maize seeds.We used supercritical CO2 to produce foams from thermoplasticized maize derived materials. Polyethylene-glycol, sorbitol/glycerol, or urea/formamide were used as plasticizers. We report expansion ratios, porosities, average pore sizes, pore morphologies, and pore size distributions for these materials. High porosity foams were obtained from zein thermoplasticized with polyethylene glycol, and from starch thermoplasticized with urea/formamide. Zein foams had a higher porosity than starch foams (88% and 85%, respectively and a narrower and more evenly distributed pore size. Starch foams exhibited a wider span of pore sizes and a larger average pore size than zein (208.84 vs. 55.43 μm2, respectively. Proof-of-concept cell culture experiments confirmed that mouse fibroblasts (NIH 3T3 and two different prostate cancer cell lines (22RV1, DU145 attached to and proliferated on zein foams.We conducted screening and proof-of-concept experiments on the fabrication of foams from cereal-based bioplastics. We propose that a key indicator of foamability is the strain at break of the materials to be foamed (as calculated from stress vs. strain rate curves. Zein foams exhibit attractive properties (average pore size, pore size distribution, and porosity for cell culture applications; we were able to establish and sustain mammalian cell cultures on zein foams for extended time periods.

  19. The efficacy of magnetic field on the thermal behavior of MnFe{sub 2}O{sub 4} nanofluid as a functional fluid through an open-cell metal foam tube

    Energy Technology Data Exchange (ETDEWEB)

    Amani, Mohammad [Mechanical and Energy Engineering Department, Shahid Beheshti University, Tehran (Iran, Islamic Republic of); Ameri, Mohammad, E-mail: ameri_m@yahoo.com [Mechanical and Energy Engineering Department, Shahid Beheshti University, Tehran (Iran, Islamic Republic of); Kasaeian, Alibakhsh [Department of Renewable Energies Engineering, Faculty of New Sciences & Technologies, University of Tehran, Tehran (Iran, Islamic Republic of)

    2017-06-15

    Highlights: • Experiments are performed with MnFe{sub 2}O{sub 4} nanofluid through an open-cell metal foam tube. • Effects of concentration, Reynolds number and magnetic field on the nanofluid thermal behavior are examined. • Heat transfer is enhanced in attendance of constant and alternating magnetic fields. - Abstract: In the present experimental study, the influence of permanent and alternating magnetic fields on the flow and thermal behavior of MnFe{sub 2}O{sub 4} magnetic nanofluid flowing through a circular open-cell metal foam tube is investigated under homogeneous heat flux conditions. The experiments are performed at various nanoparticle concentrations, Reynolds numbers and magnetic fields with different strengths and frequencies. According to the observations, the heat transfer rate enhances directly relative to nanoparticle concentration and Reynolds number in attendance of magnetic field, whereas its maximum value of 16.4% is found for 2 wt% nanoparticles at Re = 200 under alternating field with 400 G strength and 20 Hz frequency. Moreover, it is observed that the influence of strength and frequency of magnetic field is insignificant for the pressure drop. Hydrothermal efficiency as the ratio of the Nusselt number to the ratio of the pressure drop is defined in order to evaluate the privilege of using MnFe{sub 2}O{sub 4} nanofluids in practical applications. The maximum efficiency of 1.25 is observed at 2 wt% under magnetic field with 400 G and 20 Hz at Re = 1000.

  20. Electro-deposition of Pd on carbon paper and Ni foam via surface limited redox-replacement reaction for oxygen reduction reaction

    CSIR Research Space (South Africa)

    Modibedi, RM

    2014-05-01

    Full Text Available Pd nanostructured catalysts were electrodeposited by surface-limited redox replacement reactions usingthe electrochemical atomic layer deposition technique. Carbon paper and Ni foam were used as substratesfor the electrodeposition of the metal...

  1. H1259 Container Foams: Performance Data on Aged Materials

    International Nuclear Information System (INIS)

    Linda Domeier

    2002-01-01

    Samples of the three cushioning foams used in the H1259 weapon storage container were obtained in 1997, 1998, 2000 and 2001 and tested for density, compression set and compressive strength using the same procedures specified for acceptance testing. Foams from six containers, all about 30 years old and located at Pantex, were evaluated. The bottom cushioning foam is a General Plastics polyurethane foam and the two side pads are rebonded polyurethane foams. All the tests were carried out at room temperature. When compared to the original acceptance requirements the foams were generally in-spec for density and compressive strength at 10% strain and were generally out-of-spec for compression set and compressive strength at 50% strain. Significant variability was noted in the performance of each foam sample and even more in the container-to-container foam performance. The container-to-container variability remains the major unknown in predicting the long-term suitability of these containers for continued use. The performance of the critical bottom cushion foams was generally more uniform and closer to the specified performance than that of the rebonded foams. It was judged that all the foams were adequate for continued use as storage container foams (not shipping) under controlled conditions to mitigate temperature extremes or high impact. This archived information is important in evaluations of the continued suitability for weapon storage use of the H1259 containers and other containers using the same foam cushions

  2. Solar grounds for the production of foamed concrete items

    Directory of Open Access Journals (Sweden)

    Dauzhanov Nabi Tokmurzaevich

    2014-04-01

    Full Text Available The method and low-energy intensive technology of manufacturing products of foamed concrete are developed providing bringing-in a solar energy in technological conversion for reducing the energy consumption for heat treating, allowing to obtain high quality products at low cost with a diurnal cycle of production. Thereby, the use of a minimal amount of additional electrical energy is stipulated for providing a consistence of temperature fields in the cross section of helio heated products in landfills in combination with solar energy. Until now, many scientists have investigated the issues of using the renewable energy resources in the construction industry including solar ones, for replacement of conventional fuels applied in the thermal treatment of concrete products and structures. However, pursuant to the analysis of the scientific literature, all known research studies and developments in this area are devoted to heliothermal treatment of conventional concrete, and at the same time the traditional methods for acceleration of hardening requiring significant energy consumption are still in use in production of such an effective building material as foam concrete. There are various methods of heliothermal treatment including combined ones, but they are not applicable in their production due to the specific characteristics (unlike conventional concrete of manufacturing technology, the used components, the particular rheological properties, as well as a porous structure of foam concrete. Both the examining the use of solar energy in acceleration of foam concrete hardening according to the literature data and the pre-studies have revealed a problem under unilateral heliothermal treatment of foam concrete. It is found out that the temperature field of across thickness of the massif, especially during the first 7-8 hours, is irregular, that significantly affects the process of heating moisture transfer occurring within the massif. According to the

  3. Foam generator and viscometer apparatus and process

    Science.gov (United States)

    Reed, Troy D.; Pickell, Mark B.; Volk, Leonard J.

    2004-10-26

    An apparatus and process to generate a liquid-gas-surfactant foam and to measure its viscosity and enable optical and or electronic measurements of physical properties. The process includes the steps of pumping selected and measured liquids and measured gases into a mixing cell. The mixing cell is pressurized to a desired pressure and maintained at a desired pressure. Liquids and gas are mixed in the mixing cell to produce a foam of desired consistency. The temperature of the foam in the mixing cell is controlled. Foam is delivered from the mixing cell through a viscometer under controlled pressure and temperature conditions where the viscous and physical properties of the foam are measured and observed.

  4. Experimental study on foam coverage on simulated longwall roof

    Science.gov (United States)

    Reed, W.R.; Zheng, Y.; Klima, S.; Shahan, M.R.; Beck, T.W.

    2018-01-01

    Testing was conducted to determine the ability of foam to maintain roof coverage in a simulated longwall mining environment. Approximately 27 percent of respirable coal mine dust can be attributed to longwall shield movement, and developing controls for this dust source has been difficult. The application of foam is a possible dust control method for this source. Laboratory testing of two foam agents was conducted to determine the ability of the foam to adhere to a simulated longwall face roof surface. Two different foam generation methods were used: compressed air and blower air. Using a new imaging technology, image processing and analysis utilizing ImageJ software produced quantifiable results of foam roof coverage. For compressed air foam in 3.3 m/s (650 fpm) ventilation, 98 percent of agent A was intact while 95 percent of agent B was intact on the roof at three minutes after application. At 30 minutes after application, 94 percent of agent A was intact while only 20 percent of agent B remained. For blower air in 3.3 m/s (650 fpm) ventilation, the results were dependent upon nozzle type. Three different nozzles were tested. At 30 min after application, 74 to 92 percent of foam agent A remained, while 3 to 50 percent of foam agent B remained. Compressed air foam seems to remain intact for longer durations and is easier to apply than blower air foam. However, more water drained from the foam when using compressed air foam, which demonstrates that blower air foam retains more water at the roof surface. Agent A seemed to be the better performer as far as roof application is concerned. This testing demonstrates that roof application of foam is feasible and is able to withstand a typical face ventilation velocity, establishing this technique’s potential for longwall shield dust control. PMID:29563765

  5. Stability analysis of uniform equilibrium foam states for EOR processes

    NARCIS (Netherlands)

    Ashoori, E.; Marchesin, D.; Rossen, W.R.

    2011-01-01

    The use of foam for mobility control is a promising mean to improve sweep efficiency in EOR. Experimental studies discovered that foam exhibits three different states (weak foam, intermediate foam, and strong foam). The intermediate-foam state is found to be unstable in the lab whereas the weak- and

  6. Models and observations of foam coverage and bubble content in the surf zone

    Science.gov (United States)

    Kirby, J. T.; Shi, F.; Holman, R. A.

    2010-12-01

    Optical and acoustical observations and communications are hampered in the nearshore by the presence of bubbles and foam generated by breaking waves. Bubble clouds in the water column provide a highly variable (both spatially and temporally) obstacle to direct acoustic and optical paths. Persistent foam riding on the water surface creates a primary occlusion of optical penetration into the water column. In an effort to better understand and predict the level of bubble and foam content in the surfzone, we have been pursuing the development of a detailed phase resolved model of fluid and gaseous components of the water column, using a Navier-Stokes/VOF formulation extended to include a multiphase description of polydisperse bubble populations. This sort of modeling provides a detailed description of large scale turbulent structures and associated bubble transport mechanisms under breaking wave crests. The modeling technique is too computationally intensive, however, to provide a wider-scale description of large surfzone regions. In order to approach the larger scale problem, we are developing a model for spatial and temporal distribution of foam and bubbles within the framework of a Boussinesq model. The basic numerical framework for the code is described by Shi et al (2010, this conference). Bubble effects are incorporated both in the mass and momentum balances for weakly dispersive, fully nonlinear waves, with spatial and temporal bubble distributions parameterized based on the VOF modeling and measurements and tied to the computed rate of dissipation of energy during breaking. A model of a foam layer on the water surface is specified using a shallow water formulation. Foam mass conservation includes source and sink terms representing outgassing of the water column, direct foam generation due to surface agitation, and erosion due to bubble bursting. The foam layer motion in the plane of the water surface arises due to a balance of drag forces due to wind and water

  7. Measurement of Aqueous Foam Rheology by Acoustic Levitation

    Science.gov (United States)

    McDaniel, J. Gregory; Holt, R. Glynn; Rogers, Rich (Technical Monitor)

    2000-01-01

    An experimental technique is demonstrated for acoustically levitating aqueous foam drops and exciting their spheroidal modes. This allows fundamental studies of foam-drop dynamics that provide an alternative means of estimating the viscoelastic properties of the foam. One unique advantage of the technique is the lack of interactions between the foam and container surfaces, which must be accounted for in other techniques. Results are presented in which a foam drop with gas volume fraction phi = 0.77 is levitated at 30 kHz and excited into its first quadrupole resonance at 63 +/- 3 Hz. By modeling the drop as an elastic sphere, the shear modulus of the foam was estimated at 75 +/- 3 Pa.

  8. AC induction field heating of graphite foam

    Science.gov (United States)

    Klett, James W.; Rios, Orlando; Kisner, Roger

    2017-08-22

    A magneto-energy apparatus includes an electromagnetic field source for generating a time-varying electromagnetic field. A graphite foam conductor is disposed within the electromagnetic field. The graphite foam when exposed to the time-varying electromagnetic field conducts an induced electric current, the electric current heating the graphite foam. An energy conversion device utilizes heat energy from the heated graphite foam to perform a heat energy consuming function. A device for heating a fluid and a method of converting energy are also disclosed.

  9. 3D simulation of polyurethane foam injection and reacting mold flow in a complex geometry

    Science.gov (United States)

    Özdemir, İ. Bedii; Akar, Fırat

    2018-05-01

    The aim of the present work is to develop a flow model which can be used to determine the paths of the polyurethane foam in the mold filling process of a refrigerator cabinet so that improvements in the distribution and the size of the venting holes can be achieved without the expensive prototyping and experiments. For this purpose, the multi-component, two-phase chemically reacting flow is described by Navier Stokes and 12 scalar transport equations. The air and the multi-component foam zones are separated by an interface, which moves only with advection since the mass diffusion of species are set zero in the air zone. The inverse density, viscosity and other diffusion coefficients are calculated by a mass fraction weighted average of the corresponding temperature-dependent values of all species. Simulations are performed in a real refrigerator geometry, are able to reveal the problematical zones where air bubbles and voids trapped in the solidified foam are expected to occur. Furthermore, the approach proves itself as a reliable design tool to use in deciding the locations of air vents and sizing the channel dimensions.

  10. Thermal and mechanical improvement of aluminum open-cells foams through electrodeposition of copper and graphene

    Directory of Open Access Journals (Sweden)

    Simoncini Alessandro

    2016-01-01

    Full Text Available Thanks to its planar structure, graphene is characterized by unique properties, such as excellent chemical inactivity, high electrical and thermal conductivity, high optical transparency, extraordinary flexibility and high mechanical resistance, which make it suitable in a very wide range of applications. This paper details the state of the art in graphene coating applied to aluminum open-cells foams for the improvement of their mechanical and thermal behavior. Metallic foams are highly porous materials with extremely high convective heat transfer coefficients, thanks to their complex structure of three-dimensional open-cells. Graphene nanoplatelets have been used to improve thermal conductivity of aluminum foams, to make them better suitable during heat transfer in transient state. Also, an improvement of mechanical resistance has been observed. Before electrodeposition, all the samples have been subjected to sandblasting process, to eliminate the oxide layer on the surface, enabling a better adhesion of the coating. Different nanoparticles of graphene have been used. The experimental findings revealed a higher thermal conductivity for aluminum open cells foams electroplated with graphene. Considered the relatively low process costs and the improvements obtainable, these materials are very promising in many technological fields. The topics covered include surface modification, electrochemical plating, thermo-graphic analysis.

  11. Foam application from a closed system – a study of machine and foam parameters

    NARCIS (Netherlands)

    Lemmen, Jacques T.E.; Groot Wassink, Jan

    1990-01-01

    An attempt has been made to gain a greater insight into the interaction between foam and a moving textile substrate. The effects of changing wet pick–up, fabric velocity, liquid viscosity, foam density and mode of application on penetration have been studied. Application from a closed system makes

  12. Experimental investigation of a passive thermal management system for high-powered lithium ion batteries using nickel foam-paraffin composite

    International Nuclear Information System (INIS)

    Hussain, Abid; Tso, C.Y.; Chao, Christopher Y.H.

    2016-01-01

    It is necessary for electric vehicles (EVs) and hybrid electric vehicles (HEVs) to have a highly efficient thermal management system to maintain high powered lithium ion batteries within permissible temperature limits. In this study, an efficient thermal management system for high powered lithium ion batteries using a novel composite (nickel foam-paraffin wax) is designed and investigated experimentally. The results have been compared with two other cases: a natural air cooling mode and a cooling mode with pure phase change materials (PCM). The results indicate that the safety demands of lithium ion batteries cannot be fulfilled using natural air convection as the thermal management mode. The use of PCM can dramatically reduce the surface temperature within the permissible range due to heat absorption by the PCM undergoing phase change. This effect can be further enlarged by using the nickel foam-paraffin composite, showing a temperature reduction of 31% and 24% compared to natural air convection and pure PCM, respectively under 2 C discharge rate. The effect of the geometric parameters of the foam on the battery surface temperature has also been studied. The battery surface temperature decreases with the decrease of porosity and the pore density of the metal foam. On the other hand, the discharge capacity increases with the increase in porosity, but decreases with pore density. - Highlights: • Thermal management for Li-ion batteries using nickel-paraffin is studied. • The temperature is reduced by 31% as compared to natural air cooling mode. • The temperature increases with increase of porosity and pore density of metal foam. • Battery discharge capacity increases with the increase in porosity. • Battery discharge capacity increases with the decreases in pore density.

  13. Electrodeposition of Mesoporous Co3O4 Nanosheets on Carbon Foam for High Performance Supercapacitors

    Directory of Open Access Journals (Sweden)

    Zhemi Xu

    2014-01-01

    Full Text Available Metal oxide nanosheets have promising potential applications in novel energy storage devices. In this work, Co3O4 nanosheets/carbon foam with excellent supercapacitor characteristics was successfully fabricated, without using metal substrates. The experimental results demonstrate that the electrochemical tests showed that the as-prepared Co3O4 nanosheets exhibited an ideal capacitive behavior with a maximum specific capacitance of 106 F/g in 1 M NaOH solution at a scan rate of 0.1 V s−1.

  14. Foam glass obtained through high-pressure sintering

    DEFF Research Database (Denmark)

    Østergaard, Martin Bonderup; Petersen, Rasmus Rosenlund; König, Jakob

    2018-01-01

    Foam glasses are usually prepared through a chemical approach, that is, by mixing glass powder with foaming agents, and heating the mixture to a temperature above the softening point (106.6 Pa s) of the glass. The foaming agents release gas, enabling expansion of the sintered glass. Here, we use...... a physical foaming approach to prepare foam glass. First, closed pores filled with inert gases (He, Ar, or N2) are physically introduced into a glass body by sintering cathode ray tube (CRT) panel glass powder at high gas pressure (5‐25 MPa) at 640°C and, then cooled to room temperature. The sintered bodies...... are subjected to a second heat treatment above the glass transition temperature at atmospheric pressure. This heat treatment causes expansion of the pores due to high internal gas pressure. We found that the foaming ability strongly depends on the gas pressure applied during sintering, and on the kinetic...

  15. An investigation on the effects of phase change material on material components used for high temperature thermal energy storage system

    Science.gov (United States)

    Kim, Taeil; Singh, Dileep; Zhao, Weihuan; Yua, Wenhua; France, David M.

    2016-05-01

    The latent heat thermal energy storage (LHTES) systems for concentrated solar power (CSP) plants with advanced power cycle require high temperature phase change materials (PCMs), Graphite foams with high thermal conductivity to enhance the poor thermal conductivity of PCMs. Brazing of the graphite foams to the structural metals of the LHTES system could be a method to assemble the system and a method to protect the structural metals from the molten salts. In the present study, the LHTES prototype capsules using MgCl2-graphite foam composites were assembled by brazing and welding, and tested to investigate the corrosion attack of the PCM salt on the BNi-4 braze. The microstructural analysis showed that the BNi-4 braze alloy can be used not only for the joining of structure alloy to graphite foams but also for the protecting of structure alloy from the corrosion by PCM.

  16. Hybrid waste filler filled bio-polymer foam composites for sound absorbent materials

    Science.gov (United States)

    Rus, Anika Zafiah M.; Azahari, M. Shafiq M.; Kormin, Shaharuddin; Soon, Leong Bong; Zaliran, M. Taufiq; Ahraz Sadrina M. F., L.

    2017-09-01

    Sound absorption materials are one of the major requirements in many industries with regards to the sound insulation developed should be efficient to reduce sound. This is also important to contribute in economically ways of producing sound absorbing materials which is cheaper and user friendly. Thus, in this research, the sound absorbent properties of bio-polymer foam filled with hybrid fillers of wood dust and waste tire rubber has been investigated. Waste cooking oil from crisp industries was converted into bio-monomer, filled with different proportion ratio of fillers and fabricated into bio-polymer foam composite. Two fabrication methods is applied which is the Close Mold Method (CMM) and Open Mold Method (OMM). A total of four bio-polymer foam composite samples were produce for each method used. The percentage of hybrid fillers; mixture of wood dust and waste tire rubber of 2.5 %, 5.0%, 7.5% and 10% weight to weight ration with bio-monomer. The sound absorption of the bio-polymer foam composites samples were tested by using the impedance tube test according to the ASTM E-1050 and Scanning Electron Microscope to determine the morphology and porosity of the samples. The sound absorption coefficient (α) at different frequency range revealed that the polymer foam of 10.0 % hybrid fillers shows highest α of 0.963. The highest hybrid filler loading contributing to smallest pore sizes but highest interconnected pores. This also revealed that when highly porous material is exposed to incident sound waves, the air molecules at the surface of the material and within the pores of the material are forced to vibrate and loses some of their original energy. This is concluded that the suitability of bio-polymer foam filled with hybrid fillers to be used in acoustic application of automotive components such as dashboards, door panels, cushion and etc.

  17. 3D Microstructure Modeling of Porous Metal Filters

    Czech Academy of Sciences Publication Activity Database

    Hejtmánek, Vladimír; Čapek, M.

    2012-01-01

    Roč. 2, č. 3 (2012), s. 344-352 ISSN 2075-4701. [International Conference on Porous Metals and Metallic Foams /7./. Busan, 18.09.2011-21.09.2011] R&D Projects: GA ČR(CZ) GAP204/11/1206; GA ČR GA203/09/1353 Institutional support: RVO:67985858 Keywords : porous metal filter * stochastic reconstruction * microstructural descriptors Subject RIV: CF - Physical ; Theoretical Chemistry

  18. Fluoride Rinses, Gels and Foams

    DEFF Research Database (Denmark)

    Twetman, Svante; Keller, Mette K

    2016-01-01

    AIM: The aim of this conference paper was to systematically review the quality of evidence and summarize the findings of clinical trials published after 2002 using fluoride mouth rinses, fluoride gels or foams for the prevention of dental caries. METHODS: Relevant papers were selected after...... (6 on fluoride mouth rinse, 10 on fluoride gel and 3 on fluoride foam); 6 had a low risk of bias while 2 had a moderate risk. All fluoride measures appeared to be beneficial in preventing crown caries and reversing root caries, but the quality of evidence was graded as low for fluoride mouth rinse......, moderate for fluoride gel and very low for acidulated fluoride foam. No conclusions could be drawn on the cost-effectiveness. CONCLUSIONS: This review, covering the recent decade, has further substantiated the evidence for a caries-preventive effect of fluoride mouth rinse, fluoride gel and foam...

  19. Preparation And Characterization Of Silicon Carbide Foam By Using In-Situ Generated Polyurethane Foam

    Directory of Open Access Journals (Sweden)

    Shalini Saxena

    2015-08-01

    Full Text Available Abstract The open cell silicon carbide SiC foam was prepared using highly crosslinked hybrid organic- inorganic polymer resin matrix. As inorganic polymer polycarbosilane was taken and organic resin was taken as a mixture of epoxy resin and diisocyanates. The resultant highly crosslinked hybrid resin matrix on heating and subsequently on pyrolysis yielded open cell silicon carbide foam. The hybrid resin matrix was characterized by Fourier transform Infrared Spectroscopy FT-IR and thermal properties i.e. Thermogravimetric analysis TGA amp Differential Scanning Calorimetry DSC were also studied. The morphological studies of silicon carbide ceramic foam were carried out using X-ray Spectroscopy XRD amp Scanning Electron Microscopy SEM.

  20. New Spin Foam Models of Quantum Gravity

    Science.gov (United States)

    Miković, A.

    We give a brief and a critical review of the Barret-Crane spin foam models of quantum gravity. Then we describe two new spin foam models which are obtained by direct quantization of General Relativity and do not have some of the drawbacks of the Barret-Crane models. These are the model of spin foam invariants for the embedded spin networks in loop quantum gravity and the spin foam model based on the integration of the tetrads in the path integral for the Palatini action.

  1. Foam film permeability: theory and experiment.

    Science.gov (United States)

    Farajzadeh, R; Krastev, R; Zitha, Pacelli L J

    2008-02-28

    The mass transfer of gas through foam films is a prototype of various industrial and biological processes. The aim of this paper is to give a perspective and critical overview of studies carried out to date on the mass transfer of gas through foam films. Contemporary experimental data are summarized, and a comprehensive overview of the theoretical models used to explain the observed effects is given. A detailed description of the processes that occur when a gas molecule passes through each layer that forms a foam film is shown. The permeability of the film-building surfactant monolayers plays an important role for the whole permeability process. It can be successfully described by the models used to explain the permeability of surfactant monolayers on aqueous sub-phase. For this reason, the present paper briefly discusses the surfactant-induced resistance to mass transfer of gases through gas-liquid interface. One part of the paper discusses the experimental and theoretical aspects of the foam film permeability in a train of foam films in a matrix or a cylinder. This special case is important to explain the gas transfer in porous media or in foams. Finally, this paper will highlight the gaps and challenges and sketch possible directions for future research.

  2. Numerical modeling of foam flows

    International Nuclear Information System (INIS)

    Cheddadi, Ibrahim

    2010-01-01

    Liquid foam flows are involved in numerous applications, e.g. food and cosmetics industries, oil extraction, nuclear decontamination. Moreover, their study leads to fundamental knowledge: as it is easier to manipulate and analyse, foam is used as a model material to understand the flow of emulsions, polymers, pastes, or cell aggregates, all of which display both solid and liquid behaviour. Systematic experiments performed by Francois Graner et al. provide precise data that emphasize the non Newtonian properties of the foam. Meanwhile, Pierre Saramito proposed a visco-elasto-plastic continuous tensorial model, akin to predict the behaviour of the foam. The goal of this thesis is to understand this complex behaviour, using these two elements. We have built and validated a resolution algorithm based on a bidimensional finite elements methods. The numerical solutions are in excellent agreement with the spatial distribution of all measured quantities, and confirm the predictive capabilities of the model. The dominant parameters have been identified and we evidenced the fact that the viscous, elastic, and plastic contributions to the flow have to be treated simultaneously in a tensorial formalism. We provide a substantial contribution to the understanding of foams and open the path to realistic simulations of complex VEP flows for industrial applications. (author)

  3. FoAM Kernow Activity Report 2016

    OpenAIRE

    Griffiths, Amber; Griffiths, David

    2016-01-01

    This review shows selected projects from the FoAM Kernow studio in 2016. FoAM is a network of transdisciplinary labs at the intersection of art, science, nature and everyday life. FoAM’s members are generalists - people who work across disparate fields in an entangled, speculative culture. Research and creative projects at FoAM combine elements of futurecrafting, citizen science, prototyping, experience design and process facilitation to re-imagine possible futures, and artistic experime...

  4. FoAM Kernow Activity Report 2017

    OpenAIRE

    Griffiths, Amber; Weatherill, Aidan; Griffiths, David

    2017-01-01

    This review shows selected projects from the FoAM Kernow studio in 2017. FoAM is a network of transdisciplinary labs at the intersection of art, science, nature and everyday life. FoAM’s members are generalists - people who work across disparate fields in an entangled, speculative culture. Research and creative projects at FoAM combine elements of futurecrafting, citizen science, prototyping, experience design and process facilitation to re-imagine possible futures.

  5. Preparation and Oxidation Performance of Y and Ce-Modified Cr Coating on open-cell Ni-Cr-Fe Alloy Foam by the Pack Cementation

    Science.gov (United States)

    Pang, Q.; Hu, Z. L.; Wu, G. H.

    2016-12-01

    Metallic foams with a high fraction of porosity, low density and high-energy absorption capacity are a rapidly emerging class of novel ultralight weight materials for various engineering applications. In this study, Y-Cr and Ce-Cr-coated Ni-Cr-Fe alloy foams were prepared via the pack cementation method, and the effects of Y and Ce addition on the coating microstructure and oxidation performance were analyzed in order to improve the oxidation resistance of open-cell nickel-based alloy foams. The results show that the Ce-Cr coating is relatively more uniform and has a denser distribution on the surface of the nickel-based alloy foam. The surface grains of the Ce-Cr-coated alloy foam are finer compared to those of the Y-Cr-coated alloy foam. An obvious Ce peak appears on the interface between the coating and the alloy foam strut, which gives rise to a "site-blocking" effect for the short-circuit transport of the cation in the substrate. X-ray diffraction analysis shows that the Y-Cr-coated alloy foam mainly consists of Cr, (Fe, Ni) and (Ni, Cr) phases in the surface layer. The Ce-Cr-coated alloy foam is mainly composed of Cr and (Ni, Cr) phases. Furthermore, the addition of Y and Ce clearly lead to an improvement in the oxidation resistance of the coated alloy foams in the temperature range of 900-1000 °C. The addition of Ce is especially effective in enhancing the diffusion of chromium to the oxidation front, thus, accelerating the formation of a Cr2O3 layer.

  6. Stabilization of Live Attenuated Influenza Vaccines by Freeze Drying, Spray Drying, and Foam Drying.

    Science.gov (United States)

    Lovalenti, Phillip M; Anderl, Jeff; Yee, Luisa; Nguyen, Van; Ghavami, Behnaz; Ohtake, Satoshi; Saxena, Atul; Voss, Thomas; Truong-Le, Vu

    2016-05-01

    The goal of this research is to develop stable formulations for live attenuated influenza vaccines (LAIV) by employing the drying methods freeze drying, spray drying, and foam drying. Formulated live attenuated Type-A H1N1 and B-strain influenza vaccines with a variety of excipient combinations were dried using one of the three drying methods. Process and storage stability at 4, 25 and 37°C of the LAIV in these formulations was monitored using a TCID50 potency assay. Their immunogenicity was also evaluated in a ferret model. The thermal stability of H1N1 vaccine was significantly enhanced through application of unique formulation combinations and drying processes. Foam dried formulations were as much as an order of magnitude more stable than either spray dried or freeze dried formulations, while exhibiting low process loss and full retention of immunogenicity. Based on long-term stability data, foam dried formulations exhibited a shelf life at 4, 25 and 37°C of >2, 1.5 years and 4.5 months, respectively. Foam dried LAIV Type-B manufactured using the same formulation and process parameters as H1N1 were imparted with a similar level of stability. Foam drying processing methods with appropriate selection of formulation components can produce an order of magnitude improvement in LAIV stability over other drying methods.

  7. CARBONIZED STARCH MICROCELLULAR FOAM-CELLULOSE FIBER COMPOSITE STRUCTURES

    Directory of Open Access Journals (Sweden)

    Andrew R. Rutledge

    2008-11-01

    Full Text Available The production of microporous carbon foams from renewable starch microcellular foam-fiber (SMCF-Fiber composites is described. Carbon foams are used in applications such as thermal insulation, battery electrodes, filters, fuel cells, and medical devices. SMCF-Fiber compos-ites were created from an aquagel. The water in the aquagel was exchanged with ethanol and then dried and carbonized. Higher amylose content starches and fiber contents of up to 4% improved the processability of the foam. The SMCF structure revealed agglomerates of swollen starch granules connected by a web of starch with pores in the 50-200 nanometer range. Heating the SMCF-fiber in a nitrogen atmosphere to temperatures between 350-700˚C produced carbon foams with a three-dimensional closed cell foam structure with cell diameters around 50 microns and pore walls around 1-3 microns. The stress versus strain compression data for carbonized samples displayed a linear elastic region and a plateau indicative of brittle crushing, typical of an elastic-brittle foam. The carbon foam products from these renew-able precursors are promising carbon structures with moderate strength and low density.

  8. Studies on Foam Decay Trend and Influence of Temperature Jump on Foam Stability in Sclerotherapy.

    Science.gov (United States)

    Bai, Taoping; Chen, Yu; Jiang, Wentao; Yan, Fei; Fan, Yubo

    2018-02-01

    This study investigated the influence of temperature jump and liquid-gas ratio on foam stability to derive the foam-decay law. The experimental group conditions were as follows: mutation temperatures (10°C, 16°C, 20°C, 23°C, 25°C, and 27°C to >37°C) and liquid-gas ratios (1:1, 1:2, 1:3, and 1:4). The control group conditions were as follows: temperatures (10°C, 16°C, 20°C, 23°C, 25°C and 27°C) and liquid-gas ratios (1:1, 1:2, 1:3, and 1:4). A homemade device manufactured using the Tessari DSS method was used to prepare the foam. The decay process was videotape recorded. In the drainage rate curve, the temperature rose, and the liquid-gas ratio varied from 1:1 to 1:4, causing faster decay. In the entire process, the foam volume decreased with increasing drainage rate. The relationships were almost linear. Comparison of the experimental and control groups shows that the temperature jump results in a drainage time range of 1 to 15 seconds. The half-life ranges from 10 to 30 seconds. The maximum rate is 18.85%. Changes in the preparation temperature yields a drainage time range of 3 to 30 seconds. The half-life varies from 20 to 60 seconds. Decreasing the temperature jump range and liquid-gas ratio gradually enhances the foam stability. The foam decay time and drainage rate exhibit an exponential function distribution.

  9. Technological parameters influence on the non-autoclaved foam concrete characteristics

    Science.gov (United States)

    Bartenjeva, Ekaterina; Mashkin, Nikolay

    2017-01-01

    Foam concretes are used as effective heat-insulating materials. The porous structure of foam concrete provides good insulating and strength properties that make them possible to be used as heat-insulating structural materials. Optimal structure of non-autoclaved foam concrete depends on both technological factors and properties of technical foam. In this connection, the possibility to manufacture heat-insulation structural foam concrete on a high-speed cavity plant with the usage of protein and synthetic foamers was estimated. This experiment was carried out using mathematical planning method, and in this case mathematical models were developed that demonstrated the dependence of operating performance of foam concrete on foaming and rotation speed of laboratory plant. The following material properties were selected for the investigation: average density, compressive strength, bending strength and thermal conductivity. The influence of laboratory equipment technological parameters on technical foam strength and foam stability coefficient in the cement paste was investigated, physical and mechanical properties of non-autoclaved foam concrete were defined based on investigated foam. As a result of investigation, foam concrete samples were developed with performance parameters ensuring their use in production. The mathematical data gathered demonstrated the dependence of foam concrete performance on the technological regime.

  10. Method for making thin carbon foam electrodes

    Science.gov (United States)

    Pekala, Richard W.; Mayer, Steven T.; Kaschmitter, James L.; Morrison, Robert L.

    1999-01-01

    A method for fabricating thin, flat carbon electrodes by infiltrating highly porous carbon papers, membranes, felts, metal fibers/powders, or fabrics with an appropriate carbon foam precursor material. The infiltrated carbon paper, for example, is then cured to form a gel-saturated carbon paper, which is subsequently dried and pyrolyzed to form a thin sheet of porous carbon. The material readily stays flat and flexible during curing and pyrolyzing to form thin sheets. Precursor materials include polyacrylonitrile (PAN), polymethylacrylonitrile (PMAN), resorcinol/formaldehyde, catechol/formaldehyde, phenol/formaldehyde, etc., or mixtures thereof. These thin films are ideal for use as high power and energy electrodes in batteries, capacitors, and fuel cells, and are potentially useful for capacitive deionization, filtration and catalysis.

  11. Amorphous microcellular polytetrafluoroethylene foam film

    Science.gov (United States)

    Tang, Chongzheng

    1991-11-01

    We report herein the preparation of novel low-density ultramicrocellular fluorocarbon foams and their application. These fluorocarbon foams are of interest for the biochemistry arena in numerous applications including foodstuff, pharmacy, wine making, beer brewery, fermentation medical laboratory, and other processing factories. All of those require good quality processing programs in which, after eliminating bacterium and virus, compressed air is needed. Ordinarily, compressed air contains bacterium and virus, its size is 0.01 - 2 micrometers fluorocarbon foam films. Having average porous diameter 0.04 - 0.1 micrometers , these are stable to high temperature (280 degree(s)C) and chemical environments, and generally have good engineering and mechanical properties (e.g., low coefficient of thermal expansion, high modulus, and good dimensional stability). Our new process for preparing low density fluorocarbon foams provides materials with unique properties. As such, they offer the possibility for being superior to earlier materials for a number of the filter applications mentioned.

  12. Thermomechanical analyses of phenolic foam reinforced with glass fiber mat

    International Nuclear Information System (INIS)

    Zhou, Jintang; Yao, Zhengjun; Chen, Yongxin; Wei, Dongbo; Wu, Yibing

    2013-01-01

    Highlights: • Over 10% glass fiber was used to reinforce phenolic foam in the shape of glass fiber mat. • Nucleating agents were used together with glass fiber mat and improved tensile strength of phenolic foam by 215.6%. • Nucleating agents lead to a smaller bubble size of phenolic foam. • The glass transition temperature of phenolic foam remained unchanged during the reinforcement. - Abstract: In this paper, thermomechanical analysis (TMA) and dynamic mechanical analysis were employed to study the properties of phenolic foam reinforced with glass fiber mat. Unreinforced phenolic foam was taken as the control sample. Mechanical tests and scanning electron microscopy were performed to confirm the results of TMA. The results show that glass fiber mat reinforcement improves the mechanical performance of phenolic foam, and nucleating agents improve it further. Phenolic foam reinforced with glass fiber mat has a smaller thermal expansion coefficient compared with unreinforced foam. The storage modulus of the reinforced phenolic foam is also higher than that in unreinforced foam, whereas the loss modulus of the former is lower than that of the latter. The glass transition temperature of the phenolic foam matrix remains unchanged during the reinforcement

  13. Investigation of Mild Steel Thin-Wall Tubes in Unfilled and Foam-Filled Triangle, Square, and Hexagonal Cross Sections Under Compression Load

    Science.gov (United States)

    Rajak, Dipen Kumar; Kumaraswamidhas, L. A.; Das, S.

    2018-02-01

    This study has examined proposed structures with mild steel-reinforced LM30 aluminum (Al) alloy having diversely unfilled and 10 wt.% SiCp composite foam-filled tubes for improving axial compression performance. This class of material has novel physical, mechanical, and electrical properties along with low density. In the present experiment, Al alloy foams were prepared by the melt route technique using metal hydride powder as a foaming agent. Crash energy phenomena for diverse unfilled and foam-filled in mild steel thin-wall tubes (triangular, square and hexagonal) were studied as well. Compression deformation investigation was conducted at strain rates of 0.001-0.1/s for evaluating specific energy absorption (SEA) under axial loading conditions. The results were examined to measure plateau stress, maximum densification strain, and deformation mechanism of the materials. Specific energy absorption and total energy absorption capacities of the unfilled and filled sections were determined from the compressive stress-strain curves, which were then compared with each other.

  14. Experimental Study of Hysteresis behavior of Foam Generation in Porous Media.

    Science.gov (United States)

    Kahrobaei, S; Vincent-Bonnieu, S; Farajzadeh, R

    2017-08-21

    Foam can be used for gas mobility control in different subsurface applications. The success of foam-injection process depends on foam-generation and propagation rate inside the porous medium. In some cases, foam properties depend on the history of the flow or concentration of the surfactant, i.e., the hysteresis effect. Foam may show hysteresis behavior by exhibiting multiple states at the same injection conditions, where coarse-textured foam is converted into strong foam with fine texture at a critical injection velocity or pressure gradient. This study aims to investigate the effects of injection velocity and surfactant concentration on foam generation and hysteresis behavior as a function of foam quality. We find that the transition from coarse-foam to strong-foam (i.e., the minimum pressure gradient for foam generation) is almost independent of flowrate, surfactant concentration, and foam quality. Moreover, the hysteresis behavior in foam generation occurs only at high-quality regimes and when the pressure gradient is below a certain value regardless of the total flow rate and surfactant concentration. We also observe that the rheological behavior of foam is strongly dependent on liquid velocity.

  15. Pullout strength of bone-patellar tendon-bone allograft bone plugs: a comparison of cadaver tibia and rigid polyurethane foam.

    Science.gov (United States)

    Barber, F Alan

    2013-09-01

    To compare the load-to-failure pullout strength of bone-patellar tendon-bone (BPTB) allografts in human cadaver tibias and rigid polyurethane foam blocks. Twenty BPTB allografts were trimmed creating 25 mm × 10 mm × 10 mm tibial plugs. Ten-millimeter tunnels were drilled in 10 human cadaver tibias and 10 rigid polyurethane foam blocks. The BPTB anterior cruciate ligament allografts were inserted into these tunnels and secured with metal interference screws, with placement of 10 of each type in each material. After preloading (10 N), cyclic loading (500 cycles, 10 to 150 N at 200 mm/min) and load-to-failure testing (200 mm/min) were performed. The endpoints were ultimate failure load, cyclic loading elongation, and failure mode. No difference in ultimate failure load existed between grafts inserted into rigid polyurethane foam blocks (705 N) and those in cadaver tibias (669 N) (P = .69). The mean rigid polyurethane foam block elongation (0.211 mm) was less than that in tibial bone (0.470 mm) (P = .038), with a smaller standard deviation (0.07 mm for foam) than tibial bone (0.34 mm). All BPTB grafts successfully completed 500 cycles. The rigid polyurethane foam block showed less variation in test results than human cadaver tibias. Rigid polyurethane foam blocks provide an acceptable substitute for human cadaver bone tibia for biomechanical testing of BPTB allografts and offer near-equivalent results. Copyright © 2013 Arthroscopy Association of North America. Published by Elsevier Inc. All rights reserved.

  16. Zinc oxide nanoparticles induce migration and adhesion of monocytes to endothelial cells and accelerate foam cell formation

    Energy Technology Data Exchange (ETDEWEB)

    Suzuki, Yuka; Tada-Oikawa, Saeko [Graduate School of Regional Innovation Studies, Mie University, Tsu (Japan); Ichihara, Gaku [Department of Occupational and Environmental Health, Nagoya University Graduate School of Medicine, Nagoya (Japan); Yabata, Masayuki; Izuoka, Kiyora [Graduate School of Regional Innovation Studies, Mie University, Tsu (Japan); Suzuki, Masako; Sakai, Kiyoshi [Nagoya City Public Health Research Institute, Nagoya (Japan); Ichihara, Sahoko, E-mail: saho@gene.mie-u.ac.jp [Graduate School of Regional Innovation Studies, Mie University, Tsu (Japan)

    2014-07-01

    Metal oxide nanoparticles are widely used in industry, cosmetics, and biomedicine. However, the effects of exposure to these nanoparticles on the cardiovascular system remain unknown. The present study investigated the effects of nanosized TiO{sub 2} and ZnO particles on the migration and adhesion of monocytes, which are essential processes in atherosclerogenesis, using an in vitro set-up of human umbilical vein endothelial cells (HUVECs) and human monocytic leukemia cells (THP-1). We also examined the effects of exposure to nanosized metal oxide particles on macrophage cholesterol uptake and foam cell formation. The 16-hour exposure to ZnO particles increased the level of monocyte chemotactic protein-1 (MCP-1) and induced the migration of THP-1 monocyte mediated by increased MCP-1. Exposure to ZnO particles also induced adhesion of THP-1 cells to HUVECs. Moreover, exposure to ZnO particles, but not TiO{sub 2} particles, upregulated the expression of membrane scavenger receptors of modified LDL and increased cholesterol uptake in THP-1 monocytes/macrophages. In the present study, we found that exposure to ZnO particles increased macrophage cholesterol uptake, which was mediated by an upregulation of membrane scavenger receptors of modified LDL. These results suggest that nanosized ZnO particles could potentially enhance atherosclerogenesis and accelerate foam cell formation. - Highlights: • Effects of metal oxide nanoparticles on foam cell formation were investigated. • Exposure to ZnO nanoparticles induced migration and adhesion of monocytes. • Exposure to ZnO nanoparticles increased macrophage cholesterol uptake. • Expression of membrane scavenger receptors of modified LDL was also increased. • These effects were not observed after exposure to TiO{sub 2} nanoparticles.

  17. Impact Testing and Simulation of a Sinusoid Foam Sandwich Energy Absorber

    Science.gov (United States)

    Jackson, Karen E.; Fasanella, Edwin L; Littell, Justin D.

    2015-01-01

    A sinusoidal-shaped foam sandwich energy absorber was developed and evaluated at NASA Langley Research Center through multi-level testing and simulation performed under the Transport Rotorcraft Airframe Crash Testbed (TRACT) research project. The energy absorber, designated the "sinusoid," consisted of hybrid carbon- Kevlar® plain weave fabric face sheets, two layers for each face sheet oriented at +/-45deg with respect to the vertical or crush direction, and a closed-cell ELFOAM(TradeMark) P200 polyisocyanurate (2.0-lb/ft3) foam core. The design goal for the energy absorber was to achieve an average floor-level acceleration of between 25- and 40-g during the full-scale crash test of a retrofitted CH-46E helicopter airframe, designated TRACT 2. Variations in the design were assessed through quasi-static and dynamic crush testing of component specimens. Once the design was finalized, a 5-ft-long subfloor beam was fabricated and retrofitted into a barrel section of a CH-46E helicopter. A vertical drop test of the barrel section was conducted onto concrete to evaluate the performance of the energy absorber prior to retrofit into TRACT 2. Finite element models were developed of all test articles and simulations were performed using LSDYNA ®, a commercial nonlinear explicit transient dynamic finite element code. Test analysis results are presented for the sinusoid foam sandwich energy absorber as comparisons of load-displacement and acceleration-time-history responses, as well as predicted and experimental structural deformations and progressive damage for each evaluation level (component testing through barrel section drop testing).

  18. Fire-Induced Response in Foam Encapsulants

    Energy Technology Data Exchange (ETDEWEB)

    Borek, T.T.; Chu, T.Y.; Erickson, K.L.; Gill, W.; Hobbs, M.L.; Humphries, L.L.; Renlund, A.M.; Ulibarri, T.A.

    1999-04-02

    The paper provides a concise overview of a coordinated experimental/theoretical/numerical program at Sandia National Laboratories to develop an experimentally validated model of fire-induced response of foam-filled engineered systems for nuclear and transportation safety applications. Integral experiments are performed to investigate the thermal response of polyurethane foam-filled systems exposed to fire-like heat fluxes. A suite of laboratory experiments is performed to characterize the decomposition chemistry of polyurethane. Mass loss and energy associated with foam decomposition and chemical structures of the virgin and decomposed foam are determined. Decomposition chemistry is modeled as the degradation of macromolecular structures by bond breaking followed by vaporization of small fragments of the macromolecule with high vapor pressures. The chemical decomposition model is validated against the laboratory data. Data from integral experiments is used to assess and validate a FEM foam thermal response model with the chemistry model developed from the decomposition experiments. Good agreement was achieved both in the progression of the decomposition front and the in-depth thermal response.

  19. Time-dependent crashworthiness of polyurethane foam

    Science.gov (United States)

    Basit, Munshi Mahbubul; Cheon, Seong Sik

    2018-05-01

    Time-dependent stress-strain relationship as well as crashworthiness of polyurethane foam was investigated under constant impact energy with different velocities, considering inertia and strain-rate effects simultaneously during the impact testing. Even though the impact energies were same, the percentage in increase in densification strain due to higher impact velocities was found, which yielded the wider plateau region, i.e. growth in crashworthiness. This phenomenon is analyzed by the microstructure of polyurethane foam obtained from scanning electron microscopy. The equations, coupled with the Sherwood-Frost model and the impulse-momentum theory, were employed to build the constitutive equation of the polyurethane foam and calculate energy absorption capacity of the foam. The nominal stress-strain curves obtained from the constitutive equation were compared with results from impact tests and were found to be in good agreement. This study is dedicated to guiding designer use polyurethane foam in crashworthiness structures such as an automotive bumper system by providing crashworthiness data, determining the crush mode, and addressing a mathematical model of the crashworthiness.

  20. Synergistic effect of casein glycomacropeptide on sodium caseinate foaming properties.

    Science.gov (United States)

    Morales, R; Martinez, M J; Pilosof, A M R

    2017-11-01

    Several strategies to improve the interfacial properties and foaming properties of proteins may be developed; among them, the use of mixtures of biopolymers that exhibit synergistic interactions. The aim of the present work was to evaluate the effect of casein glycomacropeptide (CMP) on foaming and surface properties of sodium caseinate (NaCas) and to establish the role of protein interactions in the aqueous phase. To this end particles size, interfacial and foaming properties of CMP, NaCas and NaCas-CMP mixtures at pH 5.5 and 7 were determined. At both pH, the interaction between CMP and NaCas induced a decrease in the aggregation state of NaCas. Single CMP foams showed the highest and NaCas the lowest foam overrun (FO) and the mixture exhibited intermediate values. CMP foam quickly drained. The drainage profile of mixed foams was closer to NaCas foams; at pH 5.5, mixed foams drained even slower than NaCas foam, exhibiting a synergistic performance. Additionally, a strong synergism was observed on the collapse of mixed foams at pH 5.5. Finally, a model to explain the synergistic effect observed on foaming properties in CMP-NaCas mixtures has been proposed; the reduced aggregation state of NaCas in the presence of CMP, made it more efficient for foam stabilization. Copyright © 2017 Elsevier B.V. All rights reserved.

  1. Cyclic deformation of bidisperse two-dimensional foams

    Science.gov (United States)

    Fátima Vaz, M.; Cox, S. J.; Teixeira, P. I. C.

    2011-12-01

    In-plane deformation of foams was studied experimentally by subjecting bidisperse foams to cycles of traction and compression at a prescribed rate. Each foam contained bubbles of two sizes with given area ratio and one of three initial arrangements: sorted perpendicular to the axis of deformation (iso-strain), sorted parallel to the axis of deformation (iso-stress), or randomly mixed. Image analysis was used to measure the characteristics of the foams, including the number of edges separating small from large bubbles N sl , the perimeter (surface energy), the distribution of the number of sides of the bubbles, and the topological disorder μ2(N). Foams that were initially mixed were found to remain mixed after the deformation. The response of sorted foams, however, depended on the initial geometry, including the area fraction of small bubbles and the total number of bubbles. For a given experiment we found that (i) the perimeter of a sorted foam varied little; (ii) each foam tended towards a mixed state, measured through the saturation of N sl ; and (iii) the topological disorder μ2(N) increased up to an "equilibrium" value. The results of different experiments showed that (i) the change in disorder, ? decreased with the area fraction of small bubbles under iso-strain, but was independent of it under iso-stress; and (ii) ? increased with ? under iso-strain, but was again independent of it under iso-stress. We offer explanations for these effects in terms of elementary topological processes induced by the deformations that occur at the bubble scale.

  2. Pitch-based carbon foam and composites and use thereof

    Science.gov (United States)

    Klett, James W.; Burchell, Timothy D.; Choudhury, Ashok

    2006-07-04

    A thermally conductive carbon foam is provided, normally having a thermal conductivity of at least 40 W/mK. The carbon foam usually has a specific thermal conductivity, defined as the thermal conductivity divided by the density, of at least about 75 Wcm.sup.3/m.degree. Kgm. The foam also has a high specific surface area, typically at least about 6,000 m.sup.2/m.sup.3. The foam is characterized by an x-ray diffraction pattern having "doublet" 100 and 101 peaks characterized by a relative peak split factor no greater than about 0.470. The foam is graphitic and exhibits substantially isotropic thermal conductivity. The foam comprises substantially ellipsoidal pores and the mean pore diameter of such pores is preferably no greater than about 340 microns. Other materials, such as phase change materials, can be impregnated in the pores in order to impart beneficial thermal properties to the foam. Heat exchange devices and evaporatively cooled heat sinks utilizing the foams are also disclosed.

  3. Numerical simulation of anisotropic polymeric foams

    Directory of Open Access Journals (Sweden)

    Volnei Tita

    Full Text Available This paper shows in detail the modelling of anisotropic polymeric foam under compression and tension loadings, including discussions on isotropic material models and the entire procedure to calibrate the parameters involved. First, specimens of poly(vinyl chloride (PVC foam were investigated through experimental analyses in order to understand the mechanical behavior of this anisotropic material. Then, isotropic material models available in the commercial software AbaqusTM were investigated in order to verify their ability to model anisotropic foams and how the parameters involved can influence the results. Due to anisotropy, it is possible to obtain different values for the same parameter in the calibration process. The obtained set of parameters are used to calibrate the model according to the application of the structure. The models investigated showed minor and major limitations to simulate the mechanical behavior of anisotropic PVC foams under compression, tension and multi-axial loadings. Results show that the calibration process and the choice of the material model applied to the polymeric foam can provide good quantitative results and save project time. Results also indicate what kind and order of error one will get if certain choices are made throughout the modelling process. Finally, even though the developed calibration procedure is applied to specific PVC foam, it still outlines a very broad drill to analyze other anisotropic cellular materials.

  4. Bi-liquid foams

    International Nuclear Information System (INIS)

    Sonneville, Odile

    1997-01-01

    Concentrated emulsions have structures similar to foams; for this reason they are also called 'bi-liquid foams'. For oil in water emulsions, they are made of polyhedral oil cells separated by aqueous surfactant films. The limited stability of these Systems is a major nuisance in their applications. In this work, we tried to understand and to control the mechanisms through which bi-liquid foams can loose their stability. In a first stage, we characterized the states of surfactant films in bi-liquid foams submitted to different pressures. We determined their hydration, the surfactant density at interfaces as well as their thicknesses. The bi-liquid foams were made by concentrating hexadecane-in-water emulsions through centrifugation. The initial emulsions contained submicron oil droplets that were completely covered with surfactant. We measured the resistance of the films to dehydration, and we represented it by pressure-film thickness curves or pressure-film hydration curves. We also obtained evidence that the interfacial surfactant density increases when the film thickness is decreased (SDS case). The Newton Black Film state is the most dehydrated metastable state that can be reached. In this state, the films can be described as surfactant bilayers that only contain the hydration water of the surfactant polar heads. Two different processes are involved the destabilization of bi-liquid foams: Ostwald ripening (oil transfer from small cells to large cells) and coalescence (films rupture). The first mechanism can be controlled by choosing oils that are very insoluble in water, avoiding ethoxylated nonionic surfactants of low molecular weight, and making emulsions that are not too fine. The second mechanism is responsible for the catastrophic destabilization of bi-liquid foams made of droplets above one micron or with a low coverage in surfactant. In these cases, destabilization occurs in the early stages of concentration, when the films are still thick. It is caused

  5. Processing, Characterization, and Modeling of Polymer/Clay Nanocomposite Foams

    Science.gov (United States)

    Jo, Choonghee; Naguib, Hani E.

    2007-04-01

    The effects of the material parameters and processing conditions on the foam morphologies, and mechanical properties of polymer/clay nanocomposite foams were studied. Microcellular closed-cell nanocomposite foams were manufactured with poly(methylmethacrylate) (PMMA) and high density polyethylene (HDPE), where the nanoclay loadings of 0.5, 1.0, and 2.0 wt% were used. The effect of clay contents and foaming conditions on the volume expansion ratio, cell size, elastic modulus, tensile strength, and elongation at break were investigated and compared between amorphous and semicrystalline polymers. An elastic modulus model for tensile behavior of foams was proposed by using the micromechanics theory. The model was expressed in terms of microstructural properties of polymer and physical properties of the foams. The tensile experimental data of the foams were compared with those predicted by the theoretical model.

  6. Foamed emulsion drainage: flow and trapping of drops.

    Science.gov (United States)

    Schneider, Maxime; Zou, Ziqiang; Langevin, Dominique; Salonen, Anniina

    2017-06-07

    Foamed emulsions are ubiquitous in our daily life but the ageing of such systems is still poorly understood. In this study we investigate foam drainage and measure the evolution of the gas, liquid and oil volume fractions inside the foam. We evidence three regimes of ageing. During an initial period of fast drainage, both bubbles and drops are very mobile. As the foam stabilises drainage proceeds leading to a gradual decrease of the liquid fraction and slowing down of drainage. Clusters of oil drops are less sheared, their dynamic viscosity increases and drainage slows down even further, until the drops become blocked. At this point the oil fraction starts to increase in the continuous phase. The foam ageing leads to an increase of the capillary pressure until the oil acts as an antifoaming agent and the foam collapses.

  7. Foam behavior of solid glass spheres – Zn22Al2Cu composites under compression stresses

    International Nuclear Information System (INIS)

    Aragon-Lezama, J.A.; Garcia-Borquez, A.; Torres-Villaseñor, G.

    2015-01-01

    Solid glass spheres – Zn22Al2Cu composites, having different densities and microstructures, were elaborated and studied under compression. Their elaboration process involves alloy melting, spheres submersion into the liquid alloy and finally air cooling. The achieved composites with densities 2.6884, 2.7936 and 3.1219 g/cm 3 were studied in casting and thermally induced, fine-grain matrix microstructures. Test samples of the composites were compressed at a 10 −3 s −1 strain rate, and their microstructure characterized before and after compression by using optical and scanning electron microscopes. Although they exhibit different compression behavior depending on their density and microstructure, all of them show an elastic region at low strains, reach their maximum stress (σ max ) at hundreds of MPa before the stress fall or collapse up to a lowest yield point (LYP), followed by an important plastic deformation at nearly constant stress (σ p ): beyond this plateau, an extra deformation can be limitedly reached only by a significant stress increase. This behavior under compression stresses is similar to that reported for metal foams, being the composites with fine microstructure which nearest behave to metal foams under this pattern. Nevertheless, the relative values of the elastic modulus, and maximum and plateau stresses do not follow the Ashby equations by changing the relative density. Generally, the studied composites behave as foams under compression, except for their peculiar parameters values (σ max , LYP, and σ p )

  8. Extrusion Process by Finite Volume Method Using OpenFoam Software

    International Nuclear Information System (INIS)

    Matos Martins, Marcelo; Tonini Button, Sergio; Divo Bressan, Jose; Ivankovic, Alojz

    2011-01-01

    The computational codes are very important tools to solve engineering problems. In the analysis of metal forming process, such as extrusion, this is not different because the computational codes allow analyzing the process with reduced cost. Traditionally, the Finite Element Method is used to solve solid mechanic problems, however, the Finite Volume Method (FVM) have been gaining force in this field of applications. This paper presents the velocity field and friction coefficient variation results, obtained by numerical simulation using the OpenFoam Software and the FVM to solve an aluminum direct cold extrusion process.

  9. Auxetic foam for snowsport safety devices

    OpenAIRE

    Allen, Tom; Duncan, Olly; Foster, Leon; Senior, Terry; Zampieri, Davide; Edeh, Victor; Alderson, Andrew

    2017-01-01

    Skiing and snowboarding are popular snow-sports with inherent risk of injury. There is potential to reduce the prevalence of injuries by improving and implementing snow-sport safety devices with the application of advanced materials. This paper investigates the application of auxetic foam to snow-sport safety devices. Composite pads - consisting of foam covered with a semi-rigid shell - were investigated as a simple model of body armour and a large 70 x 355 x 355 mm auxetic foam sample was fa...

  10. B-Plant canyon fire foam supply

    International Nuclear Information System (INIS)

    Gainey, T.

    1995-01-01

    A new raw water supply was installed for the B-Plant fire foam system. This document details tests to be performed which will demonstrate that the system can function as designed. The tests include: Verification of the operation of the automatic valves at the cells; Measurement of water flow and pressure downstream of the proportioner; Production of foam, and measurement of foam concentration. Included as an appendix is a copy of the work package resolution (J4 ampersand J4a)

  11. Tensile and fracture behavior of polymer foams

    International Nuclear Information System (INIS)

    Kabir, Md. E.; Saha, M.C.; Jeelani, S.

    2006-01-01

    Tensile and mode-I fracture behavior of cross-linked polyvinyl chloride (PVC) and rigid polyurethane (PUR) foams are examined. Tension tests are performed using prismatic bar specimens and mode-I fracture tests are performed using single edge notched bend (SENB) specimens under three-point bending. Test specimens are prepared from PVC foams with three densities and two different levels of cross-linking, and PUR foam with one density. Tension and quasi-static fracture tests are performed using a Zwick/Rowell test machine. Dynamic fracture tests are performed using a DYNATUP model 8210 instrumented drop-tower test set up at three different impact energy levels. Various parameters such as specimen size, loading rate, foam density, cross-linking, crack length, cell orientation (flow and rise-direction) and solid polymer material are studied. It is found that foam density and solid polymer material have a significant effect on tensile strength, modulus, and fracture toughness of polymer foams. Level of polymer cross-linking is also found to have a significant effect on fracture toughness. The presence of cracks in the rise- and flow direction as well as loading rate has minimal effect. Dynamic fracture behavior is found to be different as compared to quasi-static fracture behavior. Dynamic fracture toughness (K d ) increases with impact energy. Examination of fracture surfaces reveals that the fracture occurs in fairly brittle manner for all foam materials

  12. Competitive sorption and desorption of heavy metals by individual soil components

    International Nuclear Information System (INIS)

    Covelo, E.F.; Vega, F.A.; Andrade, M.L.

    2007-01-01

    Knowledge of sorption and desorption of heavy metals by individual soil components should be useful for modelling the behaviour of soils of arbitrary composition when contaminated by heavy metals, and for designing amendments increasing the fixation of heavy metals by soils polluted by these species. In this study the competitive sorption and desorption of Cd, Cr, Cu, Ni, Pb and Zn by humified organic matter, Fe and Mn oxides, kaolinite, vermiculite and mica were investigated. Due to the homogeneity of the sorbents, between-metal competition for binding sites led to their preferences for one or another metal being much more manifest than in the case of whole soils. On the basis of k d100 values (distribution coefficients calculated in sorption-desorption experiments in which the initial sorption solution contained 100 mg L -1 of each metal), kaolinite and mica preferentially sorbed and retained chromium; vermiculite, copper and zinc; HOM, Fe oxide and Mn oxide, lead (HOM and Mn oxide also sorbed and retained considerable amounts of copper). Mica only retained sorbed chromium, Fe oxide sorbed cadmium and lead, and kaolinite did not retain sorbed copper. The sorbents retaining the greatest proportions of sorbed metals were vermiculite and Mn oxide, but the ratios of k d100 values for retention and sorption suggest that cations were least reversibly bound by Mn oxide, and most reversibly by vermiculite

  13. The Usability of Boric Acid as an Alternative Foaming Agent on the Fabrication of Al/Al2O3 Composite Foams

    Science.gov (United States)

    Yaman, Bilge; Onuklu, Eren; Korpe, Nese O.

    2017-09-01

    Pure Al and alumina (2, 5, 10 wt.% Al2O3)-added Al composite foams were fabricated through powder metallurgy technique, where boric acid (H3BO3) is employed as a new alternative foaming agent. It is aimed to determine the effects of boric acid on the foaming behavior and cellular structure and also purposed to develop the mechanical properties of Al foams by addition of Al2O3. Al and Al composite foams with porosity fraction in the range of 46-53% were achieved by sintering at 620 °C for 2 h. Cell morphology was characterized using a combination of stereomicroscope equipped with image analyzer and scanning electron microscopy. Microhardness values were measured via using Vickers indentation technique. Quasi-static compression tests were performed at strain rate of 10-3 s-1. Compressive strength and energy absorption of the composite foams enhanced not only by the increasing weight fraction of alumina, but also by the usage of boric acid which leads to formation of boron oxide (B2O3) acting as a binder in obtaining dense cell walls. The results revealed that the boric acid has outstanding potential as foaming agent in the fabrication of Al and Al composite foams by providing improved mechanical properties.

  14. Prediction of the Stress-Strain Behavior of Open-Cell Aluminum Foam under Compressive Loading and the Effects of Various RVE Boundary Conditions

    Science.gov (United States)

    Hamidi Ghaleh Jigh, Behrang; Farsi, Mohammad Ali; Hosseini Toudeshky, Hossein

    2018-04-01

    The prediction of the mechanical behavior of metallic foams with realistic microstructure and the effects of various boundary conditions on the mechanical behavior is an important and challenging issue in modeling representative volume elements (RVEs). A numerical investigation is conducted to determine the effects of various boundary conditions and cell wall cross sections on the compressive mechanical properties of aluminum foam, including the stiffness, plateau stress and onset strain of densification. The open-cell AA6101-T6 aluminum foam Duocel is used in the analyses in this study. Geometrical characteristics including the cell size, foam relative density, and cross-sectional shape and thickness of the cell walls are extracted from images of the foam. Then, the obtained foam microstructure is analyzed as a 2D model. The ligaments are modeled as shear deformable beams with elastic-plastic material behavior. To prevent interpenetration of the nodes and walls inside the cells with large deformations, self-contact-type frictionless interaction is stipulated between the internal surfaces. Sensitivity analyses are performed using several boundary conditions and cells wall cross-sectional shapes. The predicted results from the finite element analyses are compared with the experimental results. Finally, the most appropriate boundary conditions, leading to more consistent results with the experimental data, are introduced.

  15. Prediction of the Stress-Strain Behavior of Open-Cell Aluminum Foam under Compressive Loading and the Effects of Various RVE Boundary Conditions

    Science.gov (United States)

    Hamidi Ghaleh Jigh, Behrang; Farsi, Mohammad Ali; Hosseini Toudeshky, Hossein

    2018-05-01

    The prediction of the mechanical behavior of metallic foams with realistic microstructure and the effects of various boundary conditions on the mechanical behavior is an important and challenging issue in modeling representative volume elements (RVEs). A numerical investigation is conducted to determine the effects of various boundary conditions and cell wall cross sections on the compressive mechanical properties of aluminum foam, including the stiffness, plateau stress and onset strain of densification. The open-cell AA6101-T6 aluminum foam Duocel is used in the analyses in this study. Geometrical characteristics including the cell size, foam relative density, and cross-sectional shape and thickness of the cell walls are extracted from images of the foam. Then, the obtained foam microstructure is analyzed as a 2D model. The ligaments are modeled as shear deformable beams with elastic-plastic material behavior. To prevent interpenetration of the nodes and walls inside the cells with large deformations, self-contact-type frictionless interaction is stipulated between the internal surfaces. Sensitivity analyses are performed using several boundary conditions and cells wall cross-sectional shapes. The predicted results from the finite element analyses are compared with the experimental results. Finally, the most appropriate boundary conditions, leading to more consistent results with the experimental data, are introduced.

  16. Andrographolide Inhibits Oxidized LDL-Induced Cholesterol Accumulation and Foam Cell Formation in Macrophages.

    Science.gov (United States)

    Lin, Hung-Chih; Lii, Chong-Kuei; Chen, Hui-Chun; Lin, Ai-Hsuan; Yang, Ya-Chen; Chen, Haw-Wen

    2018-01-01

    oxLDL is involved in the pathogenesis of atherosclerotic lesions through cholesterol accumulation in macrophage foam cells. Andrographolide, the bioactive component of Andrographis paniculata, possesses several biological activities such as anti-inflammatory, anti-oxidant, and anticancer functions. Scavenger receptors (SRs), including class A SR (SR-A) and CD36, are responsible for the internalization of oxLDL. In contrast, receptors for reverse cholesterol transport, including ABCA1 and ABCG1, mediate the efflux of cholesterol from macrophage foam cells. Transcription factor liver X receptor [Formula: see text] (LXR[Formula: see text] plays a key role in lipid metabolism and inflammation as well as in the regulation of ABCA1 and ABCG1 expression. Because of the contribution of inflammation to macrophage foam cell formation and the potent anti-inflammatory activity of andrographolide, we hypothesized that andrographolide might inhibit oxLDL-induced macrophage foam cell formation. The results showed that andrographolide reduced oxLDL-induced lipid accumulation in macrophage foam cells. Andrographolide decreased the mRNA and protein expression of CD36 by inducing the degradation of CD36 mRNA; however, andrographolide had no effect on SR-A expression. In contrast, andrographolide increased the mRNA and protein expression of ABCA1 and ABCG1, which were dependent on LXR[Formula: see text]. Andrographolide enhanced LXR[Formula: see text] nuclear translocation and DNA binding activity. Treatment with the LXR[Formula: see text] antagonist GGPP and transfection with LXR[Formula: see text] siRNA reversed the ability of andrographolide to stimulate ABCA1 and ABCG1 protein expression. In conclusion, inhibition of CD36-mediated oxLDL uptake and induction of ABCA1- and ABCG1-dependent cholesterol efflux are two working mechanisms by which andrographolide inhibits macrophage foam cell formation, which suggests that andrographolide could be a potential candidate to prevent

  17. Foam generation and sample composition optimization for the FOAM-C experiment of the ISS

    Science.gov (United States)

    Carpy, R.; Picker, G.; Amann, B.; Ranebo, H.; Vincent-Bonnieu, S.; Minster, O.; Winter, J.; Dettmann, J.; Castiglione, L.; Höhler, R.; Langevin, D.

    2011-12-01

    End of 2009 and early 2010 a sealed cell, for foam generation and observation, has been designed and manufactured at Astrium Friedrichshafen facilities. With the use of this cell, different sample compositions of "wet foams" have been optimized for mixtures of chemicals such as water, dodecanol, pluronic, aethoxisclerol, glycerol, CTAB, SDS, as well as glass beads. This development is performed in the frame of the breadboarding development activities of the Experiment Container FOAM-C for operation in the ISS Fluid Science Laboratory (ISS). The sample cell supports multiple observation methods such as: Diffusing-Wave and Diffuse Transmission Spectrometry, Time Resolved Correlation Spectroscopy [1] and microscope observation, all of these methods are applied in the cell with a relatively small experiment volume 40).

  18. Three-Dimensional Printed Graphene Foams.

    Science.gov (United States)

    Sha, Junwei; Li, Yilun; Villegas Salvatierra, Rodrigo; Wang, Tuo; Dong, Pei; Ji, Yongsung; Lee, Seoung-Ki; Zhang, Chenhao; Zhang, Jibo; Smith, Robert H; Ajayan, Pulickel M; Lou, Jun; Zhao, Naiqin; Tour, James M

    2017-07-25

    An automated metal powder three-dimensional (3D) printing method for in situ synthesis of free-standing 3D graphene foams (GFs) was successfully modeled by manually placing a mixture of Ni and sucrose onto a platform and then using a commercial CO 2 laser to convert the Ni/sucrose mixture into 3D GFs. The sucrose acted as the solid carbon source for graphene, and the sintered Ni metal acted as the catalyst and template for graphene growth. This simple and efficient method combines powder metallurgy templating with 3D printing techniques and enables direct in situ 3D printing of GFs with no high-temperature furnace or lengthy growth process required. The 3D printed GFs show high-porosity (∼99.3%), low-density (∼0.015g cm -3 ), high-quality, and multilayered graphene features. The GFs have an electrical conductivity of ∼8.7 S cm -1 , a remarkable storage modulus of ∼11 kPa, and a high damping capacity of ∼0.06. These excellent physical properties of 3D printed GFs indicate potential applications in fields requiring rapid design and manufacturing of 3D carbon materials, for example, energy storage devices, damping materials, and sound absorption.

  19. Surfactant selection for a liquid foam-bed photobioreactor.

    Science.gov (United States)

    Janoska, Agnes; Vázquez, María; Janssen, Marcel; Wijffels, René H; Cuaresma, María; Vílchez, Carlos

    2018-02-01

    A novel liquid foam-bed photobioreactor has been shown to hold potential as an innovative technology for microalgae production. In this study, a foam stabilizing agent has been selected which fits the requirements of use in a liquid foam-bed photobioreactor. Four criteria were used for an optimal surfactant: the surfactant should have good foaming properties, should not be rapidly biodegradable, should drag up microalgae in the foam formed, and it should not be toxic for microalgae. Ten different surfactants (nonionic, cationic, and anionic) and two microalgae genera (Chlorella and Scenedesmus) were compared on the above-mentioned criteria. The comparison showed the following facts. Firstly, poloxameric surfactants (Pluronic F68 and Pluronic P84) have acceptable foaming properties described by intermediate foam stability and liquid holdup and small bubble size. Secondly, the natural surfactants (BSA and Saponin) and Tween 20 were easily biodegraded by bacteria within 3 days. Thirdly, for all surfactants tested the microalgae concentration is reduced in the foam phase compared to the liquid phase with exception of the cationic surfactant CTAB. Lastly, only BSA, Saponin, Tween 20, and the two Pluronics were not toxic at concentrations of 10 CMC or higher. The findings of this study indicate that the Pluronics (F68 and P84) are the best surfactants regarding the above-mentioned criteria. Since Pluronic F68 performed slightly better, this surfactant is recommended for application in a liquid foam-bed photobioreactor. © 2018 American Institute of Chemical Engineers Biotechnol. Prog., 2018. © 2018 American Institute of Chemical Engineers.

  20. Stress wave propagation and mitigation in two polymeric foams

    Science.gov (United States)

    Pradel, Pierre; Malaise, Frederic; Cadilhon, Baptiste; Quessada, Jean-Hugues; de Resseguier, Thibaut; Delhomme, Catherine; Le Blanc, Gael

    2017-06-01

    Polymeric foams are widely used in industry for thermal insulation or shock mitigation. This paper investigates the ability of a syntactic epoxy foam and an expanded polyurethane foam to mitigate intense (several GPa) and short duration (<10-6 s) stress pulses. Plate impact and electron beam irradiation experiments have been conducted to study the dynamic mechanical responses of both foams. Interferometer Doppler Laser method is used to record the target rear surface velocity. A two-wave structure associated with the propagation of an elastic precursor followed by the compaction of the pores has been observed. The compaction stress level deduced from the velocity measurement is a good indicator of mitigation capability of the foams. Quasi-static tests and dynamic soft recovery experiments have also been performed to determine the compaction mechanisms. In the polyurethane foam, the pores are closed by elastic buckling of the matrix and damage of the structure. In the epoxy foam, the compaction is due to the crushing of glass microspheres. Two porous material models successfully represent the macroscopic response of these polymeric foams.

  1. Pitch-based carbon foam and composites and uses thereof

    Science.gov (United States)

    Klett, James W.; Burchell, Timothy D.; Choudhury, Ashok

    2004-01-06

    A thermally conductive carbon foam is provided, normally having a thermal conductivity of at least 40 W/m.multidot.K. The carbon foam usually has a specific thermal conductivity, defined as the thermal conductivity divided by the density, of at least about 75 W.multidot.cm.sup.3 /m.multidot..degree.K.multidot.gm. The foam also has a high specific surface area, typically at least about 6,000 m.sup.2 /m.sup.3. The foam is characterized by an x-ray diffraction pattern having "doublet" 100 and 101 peaks characterized by a relative peak split factor no greater than about 0.470. The foam is graphitic and exhibits substantially isotropic thermal conductivity. The foam comprises substantially ellipsoidal pores and the mean pore diameter of such pores is preferably no greater than about 340 microns. Other materials, such as phase change materials, can be impregnated in the pores in order to impart beneficial thermal properties to the foam. Heat exchange devices and evaporatively cooled heat sinks utilizing the foams are also disclosed.

  2. Polymer foam comprising a polymer and nanoparticles, and nanoparticles for the manufacture of such foam.

    NARCIS (Netherlands)

    Vancso, Gyula J.; Duvigneau, Joost; Nederkoorn, P.H.J.; Wassing, T.

    2014-01-01

    A polymer foam is produced comprising a polymer and nanoparticles having a maximum dimensionof 750 nm, which foam has cells with an average cell size of at most 1 µm and a cell density of at least 1012 cells/ml, wherein polymeric grafts have been attached to the nanoparticles. The nanoparticles may

  3. Exploring liquid metal plasma facing component (PFC) concepts-Liquid metal film flow behavior under fusion relevant magnetic fields

    International Nuclear Information System (INIS)

    Narula, M.; Abdou, M.A.; Ying, A.; Morley, N.B.; Ni, M.; Miraghaie, R.; Burris, J.

    2006-01-01

    The use of fast moving liquid metal streams or 'liquid walls' as a plasma contact surface is a very attractive option and has been looked upon with considerable interest over the past several years, both by the plasma physics and fusion engineering programs. Flowing liquid walls provide an ever replenishing contact surface to the plasma, leading to very effective particle pumping and surface heat flux removal. A key feasibility issue for flowing liquid metal plasma facing component (PFC) systems, pertains to their magnetohydrodynamic (MHD) behavior under the spatially varying magnetic field environment, typical of a fusion device. MHD forces hinder the development of a smooth and controllable liquid metal flow needed for PFC applications. The present study builds up on the ongoing research effort at UCLA, directed towards providing qualitative and quantitative data on liquid metal free surface flow behavior under fusion relevant magnetic fields

  4. Integrated project: Sorption processes for removal of airborne pollutants. Sub-project 2. Scientific and technical activities accompanying the production of foamed zeolites

    International Nuclear Information System (INIS)

    Lueck, M.

    1991-01-01

    The project was to find economically efficient applications of zeolits for sorptive and catalytic treatment of hydrocarbon-containing exhaust gases. The investigations of gaseous-phase adsorption followed by desorption were carried out using hydrophobic zeolites, ceramic sorbents based on Al 2 O 3 and mixed materials of zeolite, Al 2 O 3 and activated carbon. The materials were in pellet form or, in the case of the zeolites, in the form of foamed bodies. Comparative measurements of the adsorption and desorption characteristics of pelleted and foamed hydrophobic zeolite indicated a somewhat faster and more, even desorption in the case of the foams, but there was no difference in terms of adsorptivity. The catalytic activities of zeolites with different dopings were measured using different solvent/air mixtures and different volume flow rates. Solvents used were toluene, methylisobutyl ketone, isopropanol, and n-hexane, each in a concentration of 5 g/m 3 . Volume flow rates were 7500, 11250 and 22500 l/h. The conversion/temperature behaviour of the catalyst was found to be influenced by the concentration of the active component and, in the case of the doped foams, also by the layer thickness of the zeolite/active component mixture. There is an optimum concentration and an optimum layer thickness for each active component. Below this concentration, efficiency will decrease dramatically while a further increase will not lead to higher efficiencies. (orig.) [de

  5. Handbook of plastic foams: types, properties, manufacture, and applications

    National Research Council Canada - National Science Library

    Landrock, Arthur H

    1995-01-01

    ... is an introduction and also covers the subject of foam formation. The chapter includes a discussion of the Montreal Protocol mandating the development of foams with substantially reduced CFC content by 1995. Chapter 2 is a comprehensive discussion of thermosetting foams of all types, with the emphasis on urethane and phenolic foams. The authors, K Ashida and K Iwa...

  6. Preparation and characterization of starch-based loose-fill packaging foams

    Science.gov (United States)

    Fang, Qi

    Regular and waxy corn starches were blended in various ratios with biodegradable polymers including polylactic acid (PLA), Eastar Bio Copolyester 14766 (EBC) and Mater-Bi ZF03U (MBI) and extruded with a C. W. Brabender laboratory twin screw extruder using a 3-mm die nozzle at 150°C and 150 rev/min. Physical characteristics including radial expansion, unit density and bulk density and water solubility index, water absorption characteristics, mechanical properties including compressibility, Young's modulus, spring index, bulk compressibility and bulk spring index and abrasion resistance were investigated as affected by the ingredient formulations, i.e. type of polymers, type of starches, polymer to starch ratio and starch moisture content. A completely randomized factorial blocking experimental design was used. Fifty-four treatments resulted. Each treatment was replicated three times. SAS statistical software package was used to analyze the data. Foams made of waxy starch had better radial expansion, lower unit density and bulk density than did foams made of regular starch. Regular starch foams had significantly lower water solubility index than did the waxy starch foams. PLA-starch foams had the lowest compressibility and Young's modulus. MBI-starch foams were the most rigid. All foams had excellent spring indices and bulk spring indices which were comparable to the spring index of commercial expanded polystyrene foam. Correlations were established between the foam mechanical properties and the physical characteristics. Foam compressibility and Young's modulus decreased as increases in radial expansion and decreases in unit and bulk densities. Their relationships were modeled with power law equations. No correlation was observed between spring index and bulk spring index and foam physical characteristics. MBI-starch foams had the highest equilibrium moisture content. EBC-starch and PLA-starch foams had similar water absorption characteristics. No significant

  7. Grandstand view of phenolic foam insulation

    Energy Technology Data Exchange (ETDEWEB)

    1987-03-01

    Stadium Insulation Ltd, manufacture pipe sections, tank and vessel insulation products in Lowphen, polyisocyanurate, polyurethane foams and expanded polystyrene, though for certain specialist applications, cork is still employed in small quantities. Currently the emphasis is very much on Lowphen, the company's range of pipe sections based on phenolic foam. The company's manufacturing and marketing effort reflects the increasing market trend towards the use of insulating material capable of withstanding higher temperatures, and phenolic foam neatly satisfies the demand since it is capable of use at temperatures up to 140/sup 0/C. Moreover, phenolic foam has the lowest K value at 0.02W/m/sup 0/C of any of the currently available range of insulating materials, and while the product is slightly more expensive than alternatives such as polyisocyanurate and polyurethane, its high performance offsets that premium.

  8. Foamed emulsion drainage: flow and trapping of drops

    OpenAIRE

    Schneider, Maxime; Zou, Ziqiang; Langevin, Dominique; Salonen, Anniina

    2017-01-01

    Foamed emulsions are ubiquitous in our daily life but the ageing of such systems is still poorly understood. In this study we investigate foam drainage and measure the evolution of the gas, liquid and oil volume fractions inside the foam. We evidence three regimes of ageing. During an initial period of fast drainage, both bubbles and drops are very mobile. As the foam stabilises drainage proceeds leading to a gradual decrease of the liquid fraction and slowing down of drainage. Clusters of oi...

  9. Is catheter-directed foam sclerotherapy more effective than the usual foam sclerotherapy for treatment of the great saphenous vein?

    Science.gov (United States)

    Camillo, Orsini

    2018-01-01

    Objective This retrospective study presents the long-term results of catheter-directed foam sclerotherapy of the great saphenous vein. Method From January 2003 to June 2017, 277 patients with varices and great saphenous vein incompetence were treated with echo-guided foam sclerotherapy. Forty-six patients were treated with long-catheters guided by foam sclerotherapy. Foaming was carried out with sodium-tetra-decyl-sulphate. Results Results were examined in the two groups: A (long-catheters) and B (other procedures). The median overall follow-up was 52.1 months. In the A-group, the complete occlusion rate was 34/46 pts (73.9%) and partial occlusion was 10/46 (21.7%). In the B-group, respectively, 130/231 (56.2%) and 90/231 (38.9%). Comparisons between groups were statistically significant (p = 0.023; p = 0.021). Failures involved, respectively, 2/46 (4.3%) and 11/231 (4.7%) with no statistical significance. The complication rates were similar in the two groups. Conclusions In this long-term experience (median follow-up exceeding four years), foam-guided sclerotherapy of the great saphenous vein with a long-catheter turned out to be more effective than the usual foam-guided sclerotherapy.

  10. Experimental Study of Hysteresis behavior of Foam Generation in Porous Media

    OpenAIRE

    Kahrobaei, S.; Vincent-Bonnieu, S.; Farajzadeh, R.

    2017-01-01

    Foam can be used for gas mobility control in different subsurface applications. The success of foam-injection process depends on foam-generation and propagation rate inside the porous medium. In some cases, foam properties depend on the history of the flow or concentration of the surfactant, i.e., the hysteresis effect. Foam may show hysteresis behavior by exhibiting multiple states at the same injection conditions, where coarse-textured foam is converted into strong foam with fine texture at...

  11. Effect of gas type on foam film permeability and its implications for foam flow in porous media.

    Science.gov (United States)

    Farajzadeh, R; Muruganathan, R M; Rossen, W R; Krastev, R

    2011-10-14

    The aim of this paper is to provide a perspective on the effect of gas type on the permeability of foam films stabilized by different types of surfactant and to present a critical overview of the tracer gas experiments, which is the common approach to determine the trapped fraction of foam in porous media. In these experiments some part of the gas is replaced by a "tracer gas" during the steady-state stage of the experiments and trapped fraction of foam is determined by fitting the effluent data to a capacitance mass-transfer model. We present the experimental results on the measurement of the gas permeability of foam films stabilized with five surfactants (non-ionic, anionic and cationic) and different salt concentrations. The salt concentrations assure formation of either common black (CBF) or Newton black films (NBF). The experiments are performed with different single gasses. The permeability of the CBF is in general higher than that of the NBF. This behavior is explained by the higher density of the surfactant molecules in the NBF compared to that of CBF. It is also observed that the permeability coefficient, K(cm/s), of CBF and NBF for non-ionic and cationic surfactants are similar and K is insensitive to film thickness. Compared to anionic surfactants, the films made by the non-ionic surfactant have much lower permeability while the films made by the cationic surfactant have larger permeability. This conclusion is valid for all gasses. For all types of surfactant the gas permeability of foam film is largely dependent on the dissolution of gas in the surfactant solution and increases with increasing gas solubility in the bulk liquid. The measured values of K are consistent with rapid diffusion of tracer gasses through trapped gas adjacent to flowing gas in porous media, and difficulties in interpreting the results of tracer-foam experiments with conventional capacitance models. The implications of the results for foam flow in porous media and factors leading

  12. Dual-energy X-ray micro-CT imaging of hybrid Ni/Al open-cell foam

    International Nuclear Information System (INIS)

    Fíla, T.; Koudelka, P.; Zlámal, P.; Jiroušek, O.; Kumpová, I.; Vavřík, D.; Jung, A.

    2016-01-01

    In this paper, we employ dual-energy X-ray microfocus tomography (DECT) measurement to develop high-resolution finite element (FE) models that can be used for the numerical assessment of the deformation behaviour of hybrid Ni/Al foam subjected to both quasi-static and dynamic compressive loading. Cubic samples of hybrid Ni/Al open-cell foam with an edge length of [15]mm were investigated by the DECT measurement. The material was prepared using AlSi 7 Mg 0.3 aluminium foam with a mean pore size of [0.85]mm, coated with nanocrystalline nickel (crystallite size of approx. [50]nm) to form a surface layer with a theoretical thickness of [0.075]mm. CT imaging was carried out using state-of-the-art DSCT/DECT X-ray scanner developed at Centre of Excellence Telč. The device consists of a modular orthogonal assembly of two tube-detector imaging pairs, with an independent geometry setting and shared rotational stage mounted on a complex 16-axis CNC positioning system to enable unprecedented measurement variability for highly-detailed tomographical measurements. A sample of the metal foam was simultaneously irradiated using an XWT-240-SE reflection type X-ray tube and an XWT-160-TCHR transmission type X-ray tube. An enhanced dual-source sampling strategy was used for data acquisition. X-ray images were taken using XRD1622 large area GOS scintillator flat panel detectors with an active area of [410 × 410]mm and resolution [2048 × 2048]pixels. Tomographic scanning was performed in 1,200 projections with a 0.3 degree angular step to improve the accuracy of the generated models due to the very complex microstructure and high attenuation of the investigated material. Reconstructed data was processed using a dual-energy algorithm, and was used for the development of a 3D model and voxel model of the foam. The selected parameters of the models were compared with nominal parameters of the actual foam and showed good correlation

  13. Three-Dimensional Bi-Continuous Nanoporous Gold/Nickel Foam Supported MnO2 for High Performance Supercapacitors.

    Science.gov (United States)

    Zhao, Jie; Zou, Xilai; Sun, Peng; Cui, Guofeng

    2017-12-19

    A three-dimensional bi-continuous nanoporous gold (NPG)/nickel foam is developed though the electrodeposition of a gold-tin alloy on Ni foam and subsequent chemical dealloying of tin. The newly-designed 3D metal structure is used to anchor MnO 2 nanosheets for high-performance supercapacitors. The formed ternary composite electrodes exhibit significantly-enhanced capacitance performance, rate capability, and excellent cycling stability. A specific capacitance of 442 Fg -1 is achieved at a scan rate of 5 mV s -1 and a relatively high mass loading of 865 μg cm -2 . After 2500 cycles, only a 1% decay is found at a scan rate of 50 mV s -1 . A high power density of 3513 W kg -1 and an energy density of 25.73 Wh kg -1 are realized for potential energy storage devices. The results demonstrate that the NPG/nickel foam hybrid structure significantly improves the dispersibility of MnO 2 and makes it promising for practical energy storage applications.

  14. Uniformly coated highly porous graphene/MnO2 foams for flexible asymmetric supercapacitors

    Science.gov (United States)

    Drieschner, Simon; von Seckendorff, Maximilian; del Corro, Elena; Wohlketzetter, Jörg; Blaschke, Benno M.; Stutzmann, Martin; Garrido, Jose A.

    2018-06-01

    Supercapacitors are called to play a prominent role in the newly emerging markets of electric vehicles, flexible displays and sensors, and wearable electronics. In order to compete with current battery technology, supercapacitors have to be designed with highly conductive current collectors exhibiting high surface area per unit volume and uniformly coated with pseudocapacitive materials, which is crucial to boost the energy density while maintaining a high power density. Here, we present a versatile technique to prepare thickness-controlled thin-film micro graphene foams (μGFs) with pores in the lower micrometer range grown by chemical vapor deposition which can be used as highly conductive current collectors in flexible supercapacitors. To fabricate the μGF, we use porous metallic catalytic substrates consisting of nickel/copper alloy synthesized on nickel foil by electrodeposition in an electrolytic solution. Changing the duration of the electrodeposition allows the control of the thickness of the metal foam, and thus of the μGF, ranging from a few micrometers to the millimeter scale. The resulting μGF with a thickness and pores in the micrometer regime exhibits high structural quality which leads to a very low intrinsic resistance of the devices. Transferred onto flexible substrates, we demonstrate a uniform coating of the μGFs with manganese oxide, a pseudocapacitively active material. Considering the porous structure and the thickness of the μGFs, square wave potential pulses are used to ensure uniform coverage by the oxide material boosting the volumetric and areal capacitance to 14 F cm‑3 and 0.16 F cm‑2. The μGF with a thickness and pores in the micrometer regime in combination with a coating technique tuned to the porosity of the μGF is of great relevance for the development of supercapacitors based on state-of-the-art graphene foams.

  15. Uniformly coated highly porous graphene/MnO2 foams for flexible asymmetric supercapacitors.

    Science.gov (United States)

    Drieschner, Simon; Seckendorff, Maximilian von; Corro, Elena Del; Wohlketzetter, Jörg; Blaschke, Benno M; Stutzmann, Martin; Garrido, Jose A

    2018-06-01

    Supercapacitors are called to play a prominent role in the newly emerging markets of electric vehicles, flexible displays and sensors, and wearable electronics. In order to compete with current battery technology, supercapacitors have to be designed with highly conductive current collectors exhibiting high surface area per unit volume and uniformly coated with pseudocapacitive materials, which is crucial to boost the energy density while maintaining a high power density. Here, we present a versatile technique to prepare thickness-controlled thin-film micro graphene foams (μGFs) with pores in the lower micrometer range grown by chemical vapor deposition which can be used as highly conductive current collectors in flexible supercapacitors. To fabricate the μGF, we use porous metallic catalytic substrates consisting of nickel/copper alloy synthesized on nickel foil by electrodeposition in an electrolytic solution. Changing the duration of the electrodeposition allows the control of the thickness of the metal foam, and thus of the μGF, ranging from a few micrometers to the millimeter scale. The resulting μGF with a thickness and pores in the micrometer regime exhibits high structural quality which leads to a very low intrinsic resistance of the devices. Transferred onto flexible substrates, we demonstrate a uniform coating of the μGFs with manganese oxide, a pseudocapacitively active material. Considering the porous structure and the thickness of the μGFs, square wave potential pulses are used to ensure uniform coverage by the oxide material boosting the volumetric and areal capacitance to 14 F cm -3 and 0.16 F cm -2 . The μGF with a thickness and pores in the micrometer regime in combination with a coating technique tuned to the porosity of the μGF is of great relevance for the development of supercapacitors based on state-of-the-art graphene foams.

  16. Fabrication of Foam Shells for ICF Experiments

    Science.gov (United States)

    Czechowicz, D. G.; Acenas, O.; Flowers, J. S.; Nikroo, A.; Paguio, R. R.; Schroen, D. G.; Streit, J.; Takagi, M.

    2004-11-01

    The General Atomics/Schafer team has developed processes to fabricate foam shells targets suitable for ICF experiments. The two most common chemical systems used to produce foam shells have been resorcinol-formaldehyde (R/F) aerogel and divinylbenzene (DVB). Spherical targets have been made in the form of shells and beads having diameters ranging from approximately 0.5 mm to 4.0 mm, and having densities from approximately 100 mg/cc to 250 mg/cc. The work on R/F foam shells has been concentrated on 1) shell fabrication process improvement to obtain high yields ( ˜25%) and 2) depositing a reliable permeation barrier to provide shells for ongoing direct drive experiments at LLE. Development of divinylbenzene foam shells has been mainly directed towards Inertial Fusion Energy applications (at densities as low as 30 mg/cc) and recently for shells for experiments at LLE. Details of the relevant metrology and properties of these foams as well as the range of targets currently available will be discussed.

  17. The dynamics of diffracted rays in foams

    Energy Technology Data Exchange (ETDEWEB)

    Tufaile, A., E-mail: tufaile@usp.br; Tufaile, A.P.B.

    2015-12-18

    We have studied some aspects of the optics of the light scattering in foams. This paper describes the difference between rays and diffracted rays from the point of view of geometrical theory of diffraction. We have represented some bifurcations of light rays using dynamical systems. Based on our observations of foams, we created a solid optical device. The interference patterns of light scattering in foams forming Airy fringes were explored observing the pattern named as the eye of Horus. In the cases we examine, these Airy fringes are associated with light scattering in curved surfaces, while the halo formation is related to the law of edge diffraction. We are proposing a Pohl interferometer using a three-sided bubble/Plateau border system. - Highlights: • We obtained halos scattering light in foams. • We model the light scattering in foams using the geometrical theory of diffraction. • We examine the difference between rays and the diffracted rays. • We developed optical devices for diffracted rays.

  18. Tough graphene-polymer microcellular foams for electromagnetic interference shielding.

    Science.gov (United States)

    Zhang, Hao-Bin; Yan, Qing; Zheng, Wen-Ge; He, Zhixian; Yu, Zhong-Zhen

    2011-03-01

    Functional polymethylmethacrylate (PMMA)/graphene nanocomposite microcellular foams were prepared by blending of PMMA with graphene sheets followed by foaming with subcritical CO(2) as an environmentally benign foaming agent. The addition of graphene sheets endows the insulating PMMA foams with high electrical conductivity and improved electromagnetic interference (EMI) shielding efficiency with microwave absorption as the dominant EMI shielding mechanism. Interestingly, because of the presence of the numerous microcellular cells, the graphene-PMMA foam exhibits greatly improved ductility and tensile toughness compared to its bulk counterpart. This work provides a promising methodology to fabricate tough and lightweight graphene-PMMA nanocomposite microcellular foams with superior electrical and EMI shielding properties by simultaneously combining the functionality and reinforcement of the graphene sheets and the toughening effect of the microcellular cells.

  19. Data characterizing tensile behavior of cenosphere/HDPE syntactic foam.

    Science.gov (United States)

    Kumar, B R Bharath; Doddamani, Mrityunjay; Zeltmann, Steven E; Gupta, Nikhil; Ramakrishna, Seeram

    2016-03-01

    The data set presented is related to the tensile behavior of cenosphere reinforced high density polyethylene syntactic foam composites "Processing of cenosphere/HDPE syntactic foams using an industrial scale polymer injection molding machine" (Bharath et al., 2016) [1]. The focus of the work is on determining the feasibility of using an industrial scale polymer injection molding (PIM) machine for fabricating syntactic foams. The fabricated syntactic foams are investigated for microstructure and tensile properties. The data presented in this article is related to optimization of the PIM process for syntactic foam manufacture, equations and procedures to develop theoretical estimates for properties of cenospheres, and microstructure of syntactic foams before and after failure. Included dataset contains values obtained from the theoretical model.

  20. Comparison of the mechanical properties between tantalum and nickel-titanium foams implant materials for bone ingrowth applications

    International Nuclear Information System (INIS)

    Sevilla, P.; Aparicio, C.; Planell, J.A.; Gil, F.J.

    2007-01-01

    Metallic porous materials are designed to allow the ingrowth of living tissue inside the pores and to improve the mechanical anchorage of the implant. In the present work, tantalum and nickel-titanium porous materials have been characterized. The tantalum foams were produced by vapour chemical deposition (CVD/CVI) and the NiTi foams by self-propagating high temperature synthesis (SHS). The former exhibited an open porosity ranging between 65 and 73% and for the latter it ranged between 63 and 68%. The pore sizes were between 370 and 440 μm for tantalum and between 350 and 370 μm for nickel-titanium. The Young's modulus in compression of the foams studied, especially for tantalum, were very similar to those of cancellous bone. This similitude may be relevant in order to minimize the stress shielding effect in the load transfer from the implant to bone. The strength values for NiTi foam are higher than for tantalum, especially of the strain to fracture which is about 23% for NiTi and only 8% for tantalum. The fatigue endurance limit set at 10 8 cycles is about 7.5 MPa for NiTi and 13.2 MPa for tantalum. The failure mechanisms have been studied by scanning electron microscopy