WorldWideScience

Sample records for mercury water quality

  1. Increased Mercury Bioaccumulation Follows Water Quality Improvement

    Bogle, M.A.; Peterson, M.J.; Smith, J.G.; Southworth, G.R.

    1999-09-15

    Changes in physical and chemical characteristics of aquatic habitats made to reduce or eliminate ecological risks can sometimes have unforeseen consequences. Environmental management activities on the U.S. Dept. of Energy reservation in Oak Ridge, Tennessee,have succeeded in improving water quality in streams impacted by discharges fi-om industrial facilities and waste disposal sites. The diversity and abundance of pollution-sensitive components of the benthic macroinvertebrate communities of three streams improved after new waste treatment systems or remedial actions reduced inputs of various toxic chemicals. Two of the streams were known to be mercury-contaminated from historical spills and waste disposal practices. Waterborne mercury concentrations in the third were typical of uncontaminated systems. In each case, concentrations of mercury in fish, or the apparent biological availability of mercury increased over the period during which ecological metrics indicated improved water quality. In the system where waterborne mercury concentrations were at background levels, increased mercury bioaccumulation was probably a result of reduced aqueous selenium concentrations; however, the mechanisms for increased mercury accumulation in the other two streams remain under investigation. In each of the three systems, reduced inputs of metals and inorganic anions was followed by improvements in the health of aquatic invertebrate communities. However, this reduction in risk to aquatic invertebrates was accompanied by increased risk to humans and piscivorous wildlife related to increased mercury concentrations in fish.

  2. Increased Mercury Bioaccumulation Follows Water Quality Improvement

    Bogle, M.A.; Peterson, M.J.; Smith, J.G.; Southworth, G.R.

    1999-01-01

    Changes in physical and chemical characteristics of aquatic habitats made to reduce or eliminate ecological risks can sometimes have unforeseen consequences. Environmental management activities on the U.S. Dept. of Energy reservation in Oak Ridge, Tennessee,have succeeded in improving water quality in streams impacted by discharges fi-om industrial facilities and waste disposal sites. The diversity and abundance of pollution-sensitive components of the benthic macroinvertebrate communities of three streams improved after new waste treatment systems or remedial actions reduced inputs of various toxic chemicals. Two of the streams were known to be mercury-contaminated from historical spills and waste disposal practices. Waterborne mercury concentrations in the third were typical of uncontaminated systems. In each case, concentrations of mercury in fish, or the apparent biological availability of mercury increased over the period during which ecological metrics indicated improved water quality. In the system where waterborne mercury concentrations were at background levels, increased mercury bioaccumulation was probably a result of reduced aqueous selenium concentrations; however, the mechanisms for increased mercury accumulation in the other two streams remain under investigation. In each of the three systems, reduced inputs of metals and inorganic anions was followed by improvements in the health of aquatic invertebrate communities. However, this reduction in risk to aquatic invertebrates was accompanied by increased risk to humans and piscivorous wildlife related to increased mercury concentrations in fish

  3. Ambient water quality criteria for mercury: Technical appendix

    Nagpal, N.K.

    1989-01-01

    This document discusses the effects of mercury on various water uses, including drinking water, aquatic life, wildlife, livestock water supply, irrigation, recreation and aesthetics, and industrial water supplies. Standards, objectives, and criteria from national and international jurisdictions are reviewed, providing a basis, along with other information available from the literature, for criteria recommended to protect water uses in British Columbia from anthropogenic mercury.

  4. Quality monitoring and assessment of mercury contamination in water and sediments of the Botafogo river, PE, Brazil

    Joelma Moraes Ferreira

    2009-08-01

    Full Text Available Since the mid 80's, the riverside population of Rio Botafogo, in the Santa Cruz channel, Itamaracá has undergone critical environmental situations due to poorly planned growth and inadequate soil occupation, and as a consequence, a loss in environmental quality resulted. In 1963, an industry for production of chlorine and caustic soda produced by electrolytic cell of mercury was installed in the Botafogo river. By mid-1987, a discharge of inorganic mercury between 22 and 35 tones of mercury in this river was estimated. In addition to this industry, others of different types were installed in recent years along the sides of this river. Based on previous studies, we conducted a new assessment of contaminated sites, comparing the changes over the years concerning the quality of water and sediment of the Botafogo river, in which the locations of collection, the need to increase the network of environmental monitoring were investigated. The parameters defined for analysis of water were: pH, dissolved oxygen (OD, biochemical oxygen demand (BOD, ammonia and phosphorus concentration, color, turbidity and mercury content. It was monitored the concentration of mercury in the sediments. The values of pH, turbidity, DO, BOD and ammonia usually showed values within the limits established by CONAMA Resolution No 357. Color parameters have remained consistently high, probably caused by continuous withdrawal of sand before the points of collection. The content of phosphorus was high, until the beginning of 2005, and remained within standards required by legislation until the end of this research. In the studied area, it has been installed, since 1963, an industry for chlorine and caustic soda production, which uses in its manufacturing process electrolytic cell of mercury. In this experiment, the impact of mercury has been observed.

  5. Water displacement mercury pump

    Nielsen, M.G.

    1984-04-20

    A water displacement mercury pump has a fluid inlet conduit and diffuser, a valve, a pressure cannister, and a fluid outlet conduit. The valve has a valve head which seats in an opening in the cannister. The entire assembly is readily insertable into a process vessel which produces mercury as a product. As the mercury settles, it flows into the opening in the cannister displacing lighter material. When the valve is in a closed position, the pressure cannister is sealed except for the fluid inlet conduit and the fluid outlet conduit. Introduction of a lighter fluid into the cannister will act to displace a heavier fluid from the cannister via the fluid outlet conduit. The entire pump assembly penetrates only a top wall of the process vessel, and not the sides or the bottom wall of the process vessel. This insures a leak-proof environment and is especially suitable for processing of hazardous materials.

  6. Stable isotopes and mercury in a model estuarine fish: Multibasin comparisons with water quality, community structure, and available prey base

    Adams, Douglas H., E-mail: Doug.Adams@MyFWC.com; Paperno, Richard

    2012-01-01

    Stable-isotope ratios ({delta}{sup 13}C and {delta}{sup 15}N) and mercury in a model predator, and associated prey community assessments were used to make inferences regarding food web relationships and how these relationships are influenced by habitat variability and anthropogenic factors. Although interconnected, the three major basins of the Indian River Lagoon system on the Atlantic coast of Florida comprise noticeably different available habitat types with spatially distinct faunal communities and available prey for spotted seatrout, Cynoscion nebulosus, a model predatory fish species. Water quality, degree of urbanization, human population density, and levels of nitrogen enrichment clearly differ between these representative estuarine basins. The differences can influence feeding ecology and therefore result in different mercury concentrations and different stable-isotope signatures of spotted seatrout between basins. Mercury concentrations in spotted seatrout were greatest in Mosquito Lagoon (ML) and least in the Indian River Lagoon proper (IRL), although concentrations were low for all basins. Spotted seatrout from IRL were carbon-depleted and nitrogen-enriched compared with those from the other basins; this suggests either that the fish's primary source of carbon in IRL is an algae- or phytoplankton-based food web or that the pathway through the food web is shorter there. The {delta}{sup 15}N values of IRL spotted seatrout were greater than those in the Banana River Lagoon or ML, suggesting slightly different trophic positioning of fish in these basins. The greater {delta}{sup 15}N values in IRL spotted seatrout may also reflect the greater human population density and resultant anthropogenic inputs (e.g., observed higher total nitrogen levels) in IRL compared with the other more pristine basins examined. Understanding species' responses to broad-scale habitat heterogeneity in estuaries and knowing basin-specific differences in stable isotopes

  7. Mercury

    Mercury is an element that is found in air, water and soil. It has several forms. Metallic mercury is a shiny, silver-white, odorless liquid. If ... with other elements to form powders or crystals. Mercury is in many products. Metallic mercury is used ...

  8. Decreasing aqueous mercury concentrations to meet the water quality criterion in fish: examining the water-fish relationship in two point-source contaminated streams.

    Mathews, Teresa J; Southworth, George; Peterson, Mark J; Roy, W Kelly; Ketelle, Richard H; Valentine, Charles; Gregory, Scott

    2013-01-15

    East Fork Poplar Creek (EF) and White Oak Creek (WC) are two mercury-contaminated streams located on the United States (U.S.) Department of Energy Oak Ridge Reservation in East Tennessee. East Fork Poplar Creek is the larger and more contaminated of the two, with average aqueous mercury (Hg) concentrations exceeding those in reference streams by several hundred-fold. Remedial actions over the past 20 years have decreased aqueous Hg concentrations in EF by 85% (from >1600 ng/L to Fish fillet concentrations, however, have not responded to this decrease in aqueous Hg and remain above the U.S. Environmental Protection Agency National Recommended Water Quality Criteria (NRWQC) of 0.3 mg/kg. The lack of correlation between aqueous and fish tissue Hg concentrations in this creek has led to questions regarding the usefulness of target aqueous Hg concentrations and strategies for future remediation efforts. White Oak Creek has a similar contamination history but aqueous Hg concentrations in WC are an order of magnitude lower than in EF. Despite the lower aqueous Hg concentrations (fish fillet concentrations in WC have also been above the NRWQC, making the aqueous Hg remediation goal of 200 ng/L in EF seem unlikely to result in an effective decrease in fillet Hg concentrations. Recent monitoring efforts in WC, however, suggest an aqueous total Hg threshold above which Hg bioaccumulation in fish may not respond. This new information could be useful in guiding remedial actions in EF and in other point-source contaminated streams. Published by Elsevier B.V.

  9. Evaluation of the water quality related to the acid mine drainage of an abandoned mercury mine (Alaşehir, Turkey).

    Gemici, Unsal

    2008-12-01

    Mobility of metals in water, mine wastes, and stream sediments around the abandoned Alaşehir mercury mine was investigated to evaluate the environmental effects around the area. Mine waters are dominantly acidic with pH values of 2.55 in arid season and 2.70 in wet season and are sulfate rich. Acidity is caused mainly by the oxidation of sulfide minerals. Pyrite is the main acid-producing mineral in the Alaşehir area. Of the major ions, SO(4) shows a notable increase reaching 3981 mg/l, which exceeds the WHO (WHO guidelines for drinking water quality, vol. 2. Health criteria and other supporting information, 1993) and TS (Sular-Içme ve kullanma sulari. Ankara: Türk Standartlari Enstitüsü, 1997) drinking water standard of 250 mg/L. Mine waters have As, Fe, Mn, Ni, and Al with concentrations higher than drinking water standards. Hg concentrations of adit water samples and surface waters draining the mine area are between 0.25 and 0.274 microg/L and are below the WHO (WHO guidelines for drinking water quality, vol. 2. Health criteria and other supporting information, 1993) drinking water standard of 1.0 microg/L. However, the concentrations are above the 0.012 microg/L standard (EPA, Water quality standards. Establishment of numeric criteria for priority toxic pollutants, states' compliance, final rule. Fed. Reg., 40 CFR, Part 131, 57/246, 60847-60916, 1992) used to protect aquatic life. Stream sediment samples have abnormally high values of especially Hg, As, Ni, and Cr metals. Geoaccumulation (Igeo) and pollution index (PI) values are significantly high and denote heavy contamination in stream sediments. The stream sediments derived from the mining area with the surface waters are potentially hazardous to the environment adjacent to the abandoned Hg mine and are in need of remediation.

  10. Mercury and water level fluctuations in lakes of northern Minnesota

    Larson, James H.; Maki, Ryan P; Christensen, Victoria G.; Sandheinrich, Mark B.; LeDuc, Jaime F.; Kissane, Claire; Knights, Brent C.

    2017-01-01

    Large lake ecosystems support a variety of ecosystem services in surrounding communities, including recreational and commercial fishing. However, many northern temperate fisheries are contaminated by mercury. Annual variation in mercury accumulation in fish has previously been linked to water level (WL) fluctuations, opening the possibility of regulating water levels in a manner that minimizes or reduces mercury contamination in fisheries. Here, we compiled a long-term dataset (1997-2015) of mercury content in young-of-year Yellow Perch (Perca flavescens) from six lakes on the border between the U.S. and Canada and examined whether mercury content appeared to be related to several metrics of WL fluctuation (e.g., spring WL rise, annual maximum WL, and year-to-year change in maximum WL). Using simple correlation analysis, several WL metrics appear to be strongly correlated to Yellow Perch mercury content, although the strength of these correlations varies by lake. We also used many WL metrics, water quality measurements, temperature and annual deposition data to build predictive models using partial least squared regression (PLSR) analysis for each lake. These PLSR models showed some variation among lakes, but also supported strong associations between WL fluctuations and annual variation in Yellow Perch mercury content. The study lakes underwent a modest change in WL management in 2000, when winter WL minimums were increased by about 1 m in five of the six study lakes. Using the PLSR models, we estimated how this change in WL management would have affected Yellow Perch mercury content. For four of the study lakes, the change in WL management that occurred in 2000 likely reduced Yellow Perch mercury content, relative to the previous WL management regime.

  11. Assessment of permeation quality of concrete through mercury intrusion porosimetry

    Kumar, Rakesh; Bhattacharjee, B.

    2004-01-01

    Permeation quality of laboratory cast concrete beams was determined through initial surface absorption test (ISAT). The pore system characteristics of the same concrete beam specimens were determined through mercury intrusion porosimetry (MIP). Data so obtained on the measured initial surface absorption rate of water by concrete and characteristics of pore system of concrete estimated from porosimetry results were used to develop correlations between them. Through these correlations, potential of MIP in assessing the durability quality of concrete in actual structure is demonstrated

  12. Water quality

    Aquatic animals are healthiest and grow best when environmental conditions are within certain ranges that define, for a particular species, “good” water quality. From the outset, successful aquaculture requires a high-quality water supply. Water quality in aquaculture systems also deteriorates as an...

  13. Effect of mercury and arsenic from industrial effluents on the drinking water and comparison of the water quality of polluted and non-polluted areas: a case study of Peshawar and Lower Dir.

    Ishaq, M; Jan, F Akbar; Khan, Murad Ali; Ihsanullah, I; Ahmad, I; Shakirullah, M; Roohullah

    2013-02-01

    The purpose of the present study was to find out the sources of mercury and arsenic pollution of water in the industrial area of Peshawar, the capital of Khyber Pakhtunkhwa, Pakistan. Samples of effluents, mud, and water were collected from the target area (industrial area of Peshawar), the area of water supply source, and from the less polluted area, the Lower Dir district, as the control. Hg was determined by the cold vapor generation technique, while arsenic was determined using the electrothermal atomic absorption technique. Data of the water from the industrial area were compared with that of the source area, control area, as well as with the WHO and some international drinking water quality standards. The results show that some parameters, i.e., TDS, DO, pH, and hardness, were more than the permissible limits. Textile and glass industries were found to be the major sources of Hg and As pollution. Downstream dilution of these contaminants was also observed.

  14. Mercury migration into ground water, a literature study

    Carlton, W.H.; Carden, J.L.; Kury, R.; Eichholz, G.G.

    1994-11-01

    This report presents a broad review of the technical literature dealing with mercury migration in the soil. The approach followed was to identify relevant articles by searching bibliographic data bases, obtaining the promising articles and searching these articles for any additional relevant citations. Eight catagories were used to organize the literature, with a review and summary of each paper. Catagories used were the following: chemical states of mercury under environmental conditions; diffusion of mercury vapor through soil; solubility and stability of mercury in environmental waters; transport of mercury on colloids; models for mercury migration through the environment; analytical techniques; retention of mercury by soil components; formation of organomecurials.

  15. Mercury

    ... that mercuric chloride and methylmercury are possible human carcinogens. top How does mercury affect children? Very young ... billion parts of drinking water (2 ppb). The Food and Drug Administration (FDA) has set a maximum ...

  16. Determination of mercury in drinking water

    Anand, S.J.S.

    1976-01-01

    Determination of mercury in drinking water samples have been carried out by neutron activation followed by chemical separation. The chemical analysis is necessary as the levels of mercury in these samples are quite low and activities of sodium, copper etc. interfere in its determination by direct spectroscopy. Solvent extraction separation offers speed and complete separation from interfering activities. Some of drinking water samples collected at Trombay have been analysed and their result are given in this paper. The procedure was checked with 197 Hg tracer and the reproducibility of the procedure is within 5%. It was free from contamination due to the activities of Cu, Na etc. The time of analysis was 15 minutes, and upto 5 samples could be analysed conveniently at a time. The average chemical yield was 72%. (T.I.)

  17. Core-shell magnetite-silica dithiocarbamate-derivatised particles achieve the Water Framework Directive quality criteria for mercury in surface waters.

    Lopes, C B; Figueira, P; Tavares, D S; Lin, Z; Daniel-da-Silva, A L; Duarte, A C; Rocha, J; Trindade, T; Pereira, E

    2013-09-01

    The sorption capacity of nanoporous titanosilicate Engelhard titanosilicate number 4 (ETS-4) and silica-coated magnetite particles derivatised with dithiocarbamate groups towards Hg(II) was evaluated and compared in spiked ultra-pure and spiked surface-river water, for different batch factors. In the former, and using a batch factor of 100 m(3)/kg and an initial Hg(II) concentrations matching the maximum allowed concentration in an effluent discharge, both materials achieve Hg(II) uptake efficiencies in excess of 99 % and a residual metal concentration lower than the guideline value for drinking water quality. For the surface-river water and the same initial concentration, the Hg(II) uptake efficiency of magnetite particles is outstanding, achieving the quality criteria established by the Water Framework Directive (concerning Hg concentration in surface waters) using a batch factor of 50 m(3)/kg, while the efficiency of ETS-4 is significantly inferior. The dissimilar sorbents' Hg(II) removal efficiency is attributed to different uptake mechanisms. This study also highlights the importance of assessing the effective capacity of the sorbents under realistic conditions in order to achieve trustable results.

  18. Removal of mercury from water using pottery

    Helal, A.A.A.

    2006-01-01

    In a previous study, the sorption of radiocobalt by powdered pottery materials was investigated. The use of these materials as immobilization matrix for liquid radioactive waste requires the employment of pottery vessels. Therefore, the present study aims to give detailed investigations of the decontamination of radionuclides and toxic elements using pottery containers. These investigations are equally useful to elucidate how far these vessels can be utilized for water purification through decontamination of toxic and heavy metals. The radionuclide or heavy metal removal capability using pottery pots, as low cost sorbents, has been investigated for both radioactive ( 203 Hg) and stable mercury. The results indicated that Hg 2+ is better removed by pottery from neutral to alkaline solutions. The capacity of the used pottery container (100 ml in volume) for complete removal of mercury was found to reach 3 x 10 -4 mol/l, and the time needed was 8 hours. The sorption process was suggested to occur via adsorption and ion exchange. The effect of presence of humic or fulvic acid, as ligands abundant in water, is also investigated. The results imply that, in absence of humic or fulvic acid the sorption follows the expected behaviour, i.e. sorption sites with similar affinity for mercury. In presence of humic or fulvic acid, additional sorption sites are available by the organic molecule when it is associated to the pottery. (orig.)

  19. Water-Quality Data

    ... Water Quality? [1.7MB PDF] Past featured science... Water Quality Data Today's Water Conditions Get continuous real- ... list of USGS water-quality data resources . USGS Water Science Areas Water Resources Groundwater Surface Water Water ...

  20. Mercury

    Vilas, F.; Chapman, C.R.; Matthews, M.S.

    1988-01-01

    Papers are presented on future observations of and missions to Mercury, the photometry and polarimetry of Mercury, the surface composition of Mercury from reflectance spectrophotometry, the Goldstone radar observations of Mercury, the radar observations of Mercury, the stratigraphy and geologic history of Mercury, the geomorphology of impact craters on Mercury, and the cratering record on Mercury and the origin of impacting objects. Consideration is also given to the tectonics of Mercury, the tectonic history of Mercury, Mercury's thermal history and the generation of its magnetic field, the rotational dynamics of Mercury and the state of its core, Mercury's magnetic field and interior, the magnetosphere of Mercury, and the Mercury atmosphere. Other papers are on the present bounds on the bulk composition of Mercury and the implications for planetary formation processes, the building stones of the planets, the origin and composition of Mercury, the formation of Mercury from planetesimals, and theoretical considerations on the strange density of Mercury

  1. Primer on Water Quality

    ... water quality. What do we mean by "water quality"? Water quality can be thought of as a measure ... is suitable for a particular use. How is water quality measured? Some aspects of water quality can be ...

  2. Practical isolation of methyl mercury in natural waters

    Schintu, M.; Kauri, T.; Contu, A.; Kudo, A.

    1987-01-01

    A simple method to isolate both organic and inorganic mercury in natural waters is described. The mercuric compounds were quantitatively extracted with dithizone from six different kinds of water spiked at nanogram levels with radioactive mercuric chloride and methylmercuric chloride. After the separation from the inorganic mercury with sodium nitrite, methyl mercury was transferred to aqueous medium with sodium thiosulfate. The method provides a high recovery of organic as well as inorganic mercury to an aqueous medium, prior to their determination by gold-trap cold vapor atomic absorption spectrophotometry. This method is easy, rapid, and inexpensive. Furthermore, the limited number of analytical steps should reduce loss and contamination

  3. The octanol/water distribution of mercury compounds

    Halbach, S.

    1985-01-01

    Lipophilicity plays an important role in the biological action of mercurials. The distribution of one inorganic and five organic mercury compounds was determined in an n-octanol/water system. Lipophilicity decreased in the order CH 3 HgCl, bromomercurihydroxypropane HgCl 2 chlormerodrin, p-chloromercuribenzoic acid (PCMB), p-chloromercuriphenylsulfonic acid (PCMBS). The toxicity of mercurials, as reported in the literature, appears to parallel their lipophilicity. (orig.)

  4. Fluorescent sensing and determination of mercury (II) ions in water ...

    In this study we report on a fluorescent sensing probe based on a naphthyl azo dye modified dibenzo-18-crown-6-ether (DB18C6) for the detection and determination of mercury (II) ions in water. The probe showed high sensitivity and selectivity towards the mercury (II) ion among various alkali, alkaline earth, and transition ...

  5. A CRITICAL ASSESSMENT OF ELEMENTAL MERCURY AIR/WATER EXCHANGE PARTNERS

    Although evasion of elemental mercury from aquatic systems can significantly deplete net mercury accumulation resulting from atmospheric deposition, the current ability to model elemental mercury air/water exchange is limited by uncertainties in our understanding of all gaseous a...

  6. Model analyses of atmospheric mercury: present air quality and effects of transpacific transport on the United States

    Lei, H.; Liang, X.-Z.; Wuebbles, D. J.; Tao, Z.

    2013-11-01

    Atmospheric mercury is a toxic air and water pollutant that is of significant concern because of its effects on human health and ecosystems. A mechanistic representation of the atmospheric mercury cycle is developed for the state-of-the-art global climate-chemistry model, CAM-Chem (Community Atmospheric Model with Chemistry). The model simulates the emission, transport, transformation and deposition of atmospheric mercury (Hg) in three forms: elemental mercury (Hg(0)), reactive mercury (Hg(II)), and particulate mercury (PHg). Emissions of mercury include those from human, land, ocean, biomass burning and volcano related sources. Land emissions are calculated based on surface solar radiation flux and skin temperature. A simplified air-sea mercury exchange scheme is used to calculate emissions from the oceans. The chemistry mechanism includes the oxidation of Hg(0) in gaseous phase by ozone with temperature dependence, OH, H2O2 and chlorine. Aqueous chemistry includes both oxidation and reduction of Hg(0). Transport and deposition of mercury species are calculated through adapting the original formulations in CAM-Chem. The CAM-Chem model with mercury is driven by present meteorology to simulate the present mercury air quality during the 1999-2001 period. The resulting surface concentrations of total gaseous mercury (TGM) are then compared with the observations from worldwide sites. Simulated wet depositions of mercury over the continental United States are compared to the observations from 26 Mercury Deposition Network stations to test the wet deposition simulations. The evaluations of gaseous concentrations and wet deposition confirm a strong capability for the CAM-Chem mercury mechanism to simulate the atmospheric mercury cycle. The general reproduction of global TGM concentrations and the overestimation on South Africa indicate that model simulations of TGM are seriously affected by emissions. The comparison to wet deposition indicates that wet deposition patterns

  7. Trace-level mercury removal from surface water

    Klasson, K.T.; Bostick, D.T.

    1998-01-01

    Many sorbents have been developed for the removal of mercury and heavy metals from waters; however, most of the data published thus far do not address the removal of mercury to the target levels represented in this project. The application to which these sorbents are targeted for use is the removal of mercury from microgram-per-liter levels to low nanogram-per-liter levels. Sorbents with thiouronium, thiol, amine, sulfur, and proprietary functional groups were selected for these studies. Mercury was successfully removed from surface water via adsorption onto Ionac SR-4 and Mersorb resins to levels below the target goal of 12 ng/L in batch studies. A thiol-based resin performed the best, indicating that over 200,000 volumes of water could be treated with one volume of resin. The cost of the resin is approximately $0.24 per 1,000 gal of water

  8. Water striders (family Gerridae): mercury sentinels in small freshwater ecosystems

    Jardine, Timothy D.; Al, Tom A.; MacQuarrie, Kerry T.B.; Ritchie, Charles D.; Arp, Paul A.; Maprani, Antu; Cunjak, Richard A.

    2005-01-01

    To circumvent some of the previous limitations associated with contaminant-monitoring programs, we tested the suitability of the water strider (Hemiptera: Gerridae) as a mercury sentinel by comparing total mercury concentrations in water striders and brook trout (Salvelinus fontinalis) from a variety of stream sites in New Brunswick, Canada. There was a strong association between the two variables across sites (r 2 = 0.81, P < 0.001) in systems where both atmospheric deposition and a point source (an abandoned gold mine) were likely contributing to ambient mercury levels. In a small stream draining the gold mine tailings pile, water striders had mercury concentrations an order of magnitude higher than those from reference locations. Temporal variation at three southern New Brunswick stream sites was non-significant. These results suggest that water strider mercury levels accurately quantify food chain entry of the element. The use of sentinel species holds great potential for expanding contaminant-monitoring programs. - Water striders accurately reflect the entry of mercury in food chains of small freshwater systems

  9. Mercury determination in natural waters using neutron activation analysis

    Cagnone, M.; Marques, R.O.

    1994-01-01

    Available as short communication only. An analytical method for quantitative determination of Mercury traces in river and sea water is proposed. The neutron activation method and radiochemical separation of Mercury by developing of C L 4 Hg -2 complex, and their chromatographic separation using anionic exchange resin Dowex 1 X 8 of 400 mesh is used. The quantitative determination is done by gamma spectrometric analysis. The selection limits reached with this method showed that this is an amenable procedure in routine mercury determination in the ppb level, specially useful in the environmental contamination analysis. (author). 3 refs, 2 figs, 1 tab

  10. Experimental investigations on the accumulation of mercury in water organisms

    Hannerz, L

    1968-01-01

    During the last few decades alcyle and alcoxyalcyle mercury compounds have come into an increased use in agriculture as seed disinfectants. In the pulp industry, phenylmercuric acetate has become an important means of slime control and the predominating conservant for wet ground pulp. Mercury has been carried to streams, lakes and the sea in increasing amounts with waste waters from the pulp industry and run-off from the fields. Investigations, using the neutron activation analytical method have revealed high mercury concentration in fish from many lakes and streams in the southern and central parts of Sweden. Values as high as 8000 ng Hg/g have been reported, as compared with the 30-180 ng Hg/g that can be regarded as a normal background concentration for fresh-water fish. There are many indications that the high mercury concentrations found in fish and other water organisms are direct consequences of the use of mercury in agriculture and industry. Fish from certain lakes have actually been judged unfit for human consumption. This alarming situation emphasized the need for a better knowledge of the accumulation, retention and elimination of the mercury compounds concerned in fish and other water organisms and the experimental studies reported here were therefore started in 1965. They have been financially supported by the Swedish Agricultural Research Council.

  11. British Columbia water quality guidelines (criteria): 1998 edition

    Nagpal, N.K.; Pommen, L.W.; Swain, L.G.

    1998-08-01

    British Columbia has developed water quality guidelines in order that water quality data can be assessed and site-specific water quality objectives can be prepared. The guidelines provide benchmarks for the assessment of water quality and setting water quality objectives. Guidelines are provided to protect the following six major water uses: drinking water, aquatic life, wildlife, recreation/aesthetics, agriculture, and industrial. Water quality encompasses the physical, chemical and biological quality of the water, sediment and biota. Among other quality criteria the guide provides maximum approved concentrations for nitrogen, aluminum, copper, cyanide, lead, mercury, and molybdenum. 30 tabs.

  12. Optimizing fish and stream-water mercury metrics for calculation of fish bioaccumulation factors

    Paul Bradley; Karen Riva Murray; Barbara C. Scudder Elkenberry; Christopher D. Knightes; Celeste A. Journey; Mark A. Brigham

    2016-01-01

    Mercury (Hg) bioaccumulation factors (BAFs; ratios of Hg in fish [Hgfish] and water[Hgwater]) are used to develop Total Maximum Daily Load and water quality criteria for Hg-impaired waters. Protection of wildlife and human health depends directly on the accuracy of site-specific estimates of Hgfish and Hgwater and the predictability of the relation between these...

  13. Diminished Mercury Emission From Water Surfaces by Duckweed (Lemna minor)

    Wollenberg, J. L.; Peters, S. C.

    2007-12-01

    Aquatic plants of the family Lemnaceae (generally referred to as duckweeds) are a widely distributed type of floating vegetation in freshwater systems. Under suitable conditions, duckweeds form a dense vegetative mat on the water surface, which reduces light penetration into the water column and decreases the amount of exposed water surface. These two factors would be expected to reduce mercury emission by limiting a) direct photoreduction of Hg(II), b) indirect reduction via coupled DOC photooxidation-Hg(II) reduction, and c) gas diffusion across the water-air interface. Conversely, previous studies have demonstrated transpiration of Hg(0) by plants, so it is therefore possible that the floating vegetative mat would enhance emission via transpiration of mercury vapor. The purpose of this experiment was to determine whether duckweed limits mercury flux to the atmosphere by shading and the formation of a physical barrier to diffusion, or whether it enhances emission from aquatic systems via transpiration of Hg(0). Deionized water was amended with mercury to achieve a final concentration of approximately 35 ng/L and allowed to equilibrate prior to the experiment. Experiments were conducted in rectangular polystyrene flux chambers with measured UV-B transmittance greater than 60% (spectral cutoff approximately 290 nm). Light was able to penetrate the flux chamber from the sides as well as the top throughout the experiment, limiting the effect of shading by duckweed on the water surface. Flux chambers contained 8L of water with varying percent duckweed cover, and perforated plastic sheeting was used as an abiotic control. Exposures were conducted outside on days with little to no cloud cover. Real time mercury flux was measured using atomic absorption (Mercury Instruments UT-3000). Total solar and ultraviolet radiation, as well as a suite of meteorological parameters, were also measured. Results indicate that duckweed diminishes mercury emission from the water surface

  14. Mercury cycling in a wastewater treatment plant treating waters with high mercury contents.

    García-Noguero, Eva M.; García-Noguero, Carolina; Higueras, Pablo; Reyes-Bozo, Lorenzo; Esbrí, José M.

    2015-04-01

    The Almadén mercury mining district has been historically the most important producer of this element since Romans times to 2004, when both mining and metallurgic activities ceased as a consequence both of reserves exhaustion and persistent low prices for this metal. The reclamation of the main dump of the mine in 2007-2008 reduced drastically the atmospheric presence of the gaseous mercury pollutant in the local atmosphere. But still many areas, and in particular in the Almadén town area, can be considered as contaminated, and produce mercury releases that affect the urban residual waters. Two wastewater treatment plants (WWTP) where built in the area in year 2002, but in their design the projects did not considered the question of high mercury concentrations received as input from the town area. This communication presents data of mercury cycling in one of the WWTP, the Almadén-Chillón one, being the larger and receiving the higher Hg concentrations, due to the fact that it treats the waters coming from the West part of the town, in the immediate proximity to the mine area. Data were collected during a number of moments of activity of the plant, since April 2004 to nowadays. Analyses were carried out by means of cold vapor-atomic fluorescence spectroscopy (CV-AFS), using a PSA Millennium Merlin analytical device with gold trap. The detection limit is 0.1 ng/l. The calibration standards are prepared using the Panreac ICP Standard Mercury Solution (1,000±0,002 g/l Hg in HNO3 2-5%). Results of the surveys indicate that mercury concentrations in input and output waters in this plant has suffered an important descent since the cessation of mining and metallurgical activities, and minor reduction also after the reclamation of the main mine's dump. Since 2009, some minor seasonal variations are detected, in particular apparently related to accumulation during summer of mercury salts and particles, which are washed to the plant with the autumn's rains. Further

  15. Quality control of analyses of mercury in hair

    Lind, B.; Friberg, L.; Bigras, L.; Kirkbride, J.; Kennedy, P.; Kjellstroem, T.

    1988-01-01

    A quality control programme for mercury determinations in hair was developed within a study of 'Mental effects of prenatal methylmercury exposure in New Zealand children'. Hair was obtained from seven females with a mercury concentration of about 0.5-4 μg Hg/g. The hair was cut into 1-5 cm pieces and pulverized by liquid nitrogen grinding using a ring mill. In order to obtain a series of QC samples with varying Hg concentrations, different amounts of powder from all the samples and a reference sample of pulverized hair (11.2 μg Hg/g) were mixed. The mercury concentrations in the original samples and the mixtures were determined by radiochemical neutron activation analysis (RNAA). In total four laboratories participated in the interlaboratory comparison. All laboratories used the cold vapor AAS technique and Hg monitor model 1235, LDC for determinations after wet digestion of the samples. (orig./RB)

  16. Could the Hokusai Impact Have Delivered Mercury's Water Ice?

    Ernst, C. M.; Chabot, N. L.; Barnouin, O. S.

    2018-05-01

    Hokusai is the best candidate source crater for Mercury’s water-ice inventory if it was primarily delivered by a single impact event. The Hokusai impact could account for the inventory of water ice on Mercury for impact velocities <30 km/s.

  17. Experimental dosing of wetlands with coagulants removes mercury from surface water and decreases mercury bioaccumulation in fish

    Ackerman, Joshua T.; Kraus, Tamara E.C.; Fleck, Jacob A.; Krabbenhoft, David P.; Horwarth, William R.; Bachand, Sandra M.; Herzog, Mark; Hartman, Christopher; Bachand, Philip A.M.

    2015-01-01

    Mercury pollution is widespread globally, and strategies for managing mercury contamination in aquatic environments are necessary. We tested whether coagulation with metal-based salts could remove mercury from wetland surface waters and decrease mercury bioaccumulation in fish. In a complete randomized block design, we constructed nine experimental wetlands in California’s Sacramento–San Joaquin Delta, stocked them with mosquitofish (Gambusia affinis), and then continuously applied agricultural drainage water that was either untreated (control), or treated with polyaluminum chloride or ferric sulfate coagulants. Total mercury and methylmercury concentrations in surface waters were decreased by 62% and 63% in polyaluminum chloride treated wetlands and 50% and 76% in ferric sulfate treated wetlands compared to control wetlands. Specifically, following coagulation, mercury was transferred from the filtered fraction of water into the particulate fraction of water which then settled within the wetland. Mosquitofish mercury concentrations were decreased by 35% in ferric sulfate treated wetlands compared to control wetlands. There was no reduction in mosquitofish mercury concentrations within the polyaluminum chloride treated wetlands, which may have been caused by production of bioavailable methylmercury within those wetlands. Coagulation may be an effective management strategy for reducing mercury contamination within wetlands, but further studies should explore potential effects on wetland ecosystems.

  18. Experimental dosing of wetlands with coagulants removes mercury from surface water and decreases mercury bioaccumulation in fish.

    Ackerman, Joshua T; Kraus, Tamara E C; Fleck, Jacob A; Krabbenhoft, David P; Horwath, William R; Bachand, Sandra M; Herzog, Mark P; Hartman, C Alex; Bachand, Philip A M

    2015-05-19

    Mercury pollution is widespread globally, and strategies for managing mercury contamination in aquatic environments are necessary. We tested whether coagulation with metal-based salts could remove mercury from wetland surface waters and decrease mercury bioaccumulation in fish. In a complete randomized block design, we constructed nine experimental wetlands in California's Sacramento-San Joaquin Delta, stocked them with mosquitofish (Gambusia affinis), and then continuously applied agricultural drainage water that was either untreated (control), or treated with polyaluminum chloride or ferric sulfate coagulants. Total mercury and methylmercury concentrations in surface waters were decreased by 62% and 63% in polyaluminum chloride treated wetlands and 50% and 76% in ferric sulfate treated wetlands compared to control wetlands. Specifically, following coagulation, mercury was transferred from the filtered fraction of water into the particulate fraction of water which then settled within the wetland. Mosquitofish mercury concentrations were decreased by 35% in ferric sulfate treated wetlands compared to control wetlands. There was no reduction in mosquitofish mercury concentrations within the polyaluminum chloride treated wetlands, which may have been caused by production of bioavailable methylmercury within those wetlands. Coagulation may be an effective management strategy for reducing mercury contamination within wetlands, but further studies should explore potential effects on wetland ecosystems.

  19. Mercury

    de Vries, Irma

    2017-01-01

    Mercury is a naturally occurring metal that exists in several physical and chemical forms. Inorganic mercury refers to compounds formed after the combining of mercury with elements such as chlorine, sulfur, or oxygen. After combining with carbon by covalent linkage, the compounds formed are called

  20. Accelerate Water Quality Improvement

    EPA is committed to accelerating water quality improvement and minimizing negative impacts to aquatic life from contaminants and other stressors in the Bay Delta Estuary by working with California Water Boards to strengthen water quality improvement plans.

  1. Comparison of Mercury in Water, Bottom Sediment, and Zooplankton in Two Front Range Reservoirs in Colorado, 2008-09

    Mast, M. Alisa; Krabbenhoft, David P.

    2010-01-01

    The U.S. Geological Survey, in cooperation with the Colorado Department of Public Health and Environment, conducted a study to investigate environmental factors that may contribute to the bioaccumulation of mercury in two Front Range reservoirs. One of the reservoirs, Brush Hollow Reservoir, currently (2009) has a fish-consumption advisory for mercury in walleye (Stizostedion vitreum), and the other, Pueblo Reservoir, which is nearby, does not. Water, bottom sediment, and zooplankton samples were collected during 2008 and 2009, and a sediment-incubation experiment was conducted in 2009. Total mercury concentrations were low in midlake water samples and were not substantially different between the two reservoirs. The only water samples with detectable methylmercury were collected in shallow areas of Brush Hollow Reservoir during spring. Mercury concentrations in reservoir bottom sediments were similar to those reported for stream sediments from unmined basins across the United States. Despite higher concentrations of fish-tissue mercury in Brush Hollow Reservoir, concentrations of methylmercury in sediment were as much as 3 times higher in Pueblo Reservoir. Mercury concentrations in zooplankton were at the low end of concentrations reported for temperate lakes in the Northeastern United States and were similar between sites, which may reflect the seasonal timing of sampling. Factors affecting bioaccumulation of mercury were assessed, including mercury sources, water quality, and reservoir characteristics. Atmospheric deposition was determined to be the dominant source of mercury; however, due to the proximity of the reservoirs, atmospheric inputs likely are similar in both study areas. Water-quality constituents commonly associated with elevated concentrations of mercury in fish (pH, alkalinity, sulfate, nutrients, and dissolved organic carbon) did not appear to explain differences in fish-tissue mercury concentrations between the reservoirs. Low methylmercury

  2. Dissolved gaseous mercury and mercury flux measurements in Mediterranean coastal waters: A short review

    Fantozzi L.

    2013-04-01

    Full Text Available There is a general agreement in the scientific community that the marine ecosystem can be a sink and/or source of the mercury that is cycling in the global environment, and current estimates of the global mercury budget for the Mediterranean region are affected by high uncertainty, primarily due to the little progress made so far in evaluating the role of chemical, physical and biological processes in the water system and in the lower atmosphere above the sea water (air-water interface. The lack of knowledge of the magnitude of the air-sea exchange mechanisms is, therefore, one of the main factors affecting the overall uncertainty associated with the assessment of net fluxes of Hg between the atmospheric and marine environments in the Mediterranean region. Results obtained during the last 15 years in the Mediterranean basin indicate the quantitative importance of such emission in the biogeochemical cycle of this element, highlighting the need for thorough investigations on the mechanisms of production and volatilization of dissolved gaseous mercury in waters.

  3. Water Quality Analysis Simulation

    The Water Quality analysis simulation Program, an enhancement of the original WASP. This model helps users interpret and predict water quality responses to natural phenomena and man-made pollution for variious pollution management decisions.

  4. Water Quality Criteria

    EPA develops water quality criteria based on the latest scientific knowledge to protect human health and aquatic life. This information serves as guidance to states and tribes in adopting water quality standards.

  5. Water Quality Analysis Simulation

    U.S. Environmental Protection Agency — The Water Quality analysis simulation Program, an enhancement of the original WASP. This model helps users interpret and predict water quality responses to natural...

  6. Sediment-water interactions affecting dissolved-mercury distributions in Camp Far West Reservoir, California

    Kuwabara, James S.; Alpers, Charles N.; Marvin-DiPasquale, Mark; Topping, Brent R.; Carter, James L.; Stewart, A. Robin; Fend, Steven V.; Parcheso, Francis; Moon, Gerald E.; Krabbenhoft, David P.

    2003-01-01

    summary information (figuratively at the top of the pyramid) and the later details of methods or results (figuratively towards the base of the pyramid) using hyperlinks to supporting figures and tables, and an electronically linked Table of Contents. During two sampling events, two replicate sediment cores (Coring methods; Fig. 2) from each of three reservoir locations (Fig. 1) were used in incubation experiments to provide flux estimates and benthic biological characterizations. Incubation of these cores provided ?snapshots? of solute flux across the sediment-water interface in the reservoir, under benthic, environmental conditions representative of the time and place of collection. Ancillary data, including nutrient and ligand fluxes, were gathered to provide a water-quality framework from which to compare the results for mercury. The following major observations from interdependent physical, biological, and chemical data were made:

  7. MERCURY SEPARATION FROM POLLUTANT WATER USING ZEOLITES

    Arsenic is known to be a hazardous contaminant in drinking water that causes arsenical dermatitis and skin cancer. In the present work, the potential use of a variety of synthetic zeolites for removal of arsenic from water has been examined at room temperature. Experiments have...

  8. Mercury in water and bottom sediments from a mexican reservoir

    Avila Perez, P.; Zarazua Ortega, G.; Barcelo Quintal, D.; Rosas, P.; Diazdelgado, C.

    2001-01-01

    The Lerma-Santiago river's source is located in the State of Mexico. Its drainage basin occupies an area of 129,632 km2. The river receives urban wastewater discharges from 29 municipalities, as well as industrial water discharges, both treated and untreated, mainly from the industrial zones of Toluca, Lerma, Ocoyoacac, Santiago Tianguistengo, Pasteje and Atlacomulco. It is estimated that during a year, the stream receives 536 x 106 m3 of waste waters, which carries 350,946 ton of organic load; 33% of these waste waters come from urban discharges, and 67% originate from industrial discharges. The Jose Antonio Alzate Reservoir fed by the Lerma river is the first significant water reservoir downstream of the main industrial areas in the State of Mexico and both are considered the most contaminated water bodies in the State of Mexico. Mercury concentrations in water and bottom sediments in the Jose Antonio Alzate Reservoir were determined in 6 different sampling zones over a 1-year period. Mercury was measured by instrumental neutron activation analysis (INAA) and irradiated with a thermal neutron flux of 9 x 1012 n. cm-2 s-1 for a period of 26 hours. High variations of mercury concentrations in water in both, soluble and suspended forms, were observed to depend on the sampling season. During the rainy season, rain events contribute with a substantial water volume to modify physicochemical parameters like pH, which dilute chemical species in the Alzate Reservoir. There are evidence that in the Jose Antonio Alzate reservoir, sedimentation and adsorption act as a natural cleaning process, decreasing the dissolved concentrations and increasing the metallic content of the sediments. A negative gradient was identified for mercury concentrations, from the Lerma river inlet to Alzate Reservoir dam, which demonstrates the considerable influence of the Lerma river inlet. This gradient also proves the existence of a metal recycling process between water and sediment, while the

  9. Water Quality Protection Charges

    Montgomery County of Maryland — The Water Quality Protection Charge (WQPC) is a line item on your property tax bill. WQPC funds many of the County's clean water initiatives including: • Restoration...

  10. Biological Water Quality Criteria

    Page contains links to Technical Documents pertaining to Biological Water Quality Criteria, including, technical assistance documents for states, tribes and territories, program overviews, and case studies.

  11. Mercury cycling in surface water, pore water and sediments of Mugu Lagoon, CA, USA

    Rothenberg, Sarah E. [Environmental Science and Engineering Program, Box 951772, University of California, Los Angeles, CA 90095-1772 (United States)], E-mail: rothenberg.sarah@gmail.com; Ambrose, Richard F. [Environmental Science and Engineering Program, Box 951772, University of California, Los Angeles, CA 90095-1772 (United States); Department of Environmental Health Sciences, Box 951772, University of California, Los Angeles, CA 90095-1772 (United States)], E-mail: rambrose@ucla.edu; Jay, Jennifer A. [Department of Civil and Environmental Engineering, Box 951593, University of California, Los Angeles, CA 90095-1593 (United States)], E-mail: jjay@seas.ucla.edu

    2008-07-15

    Mugu Lagoon is an estuary in southern California, listed as impaired for mercury. In 2005, we examined mercury cycling at ten sites within at most four habitats. In surface water (unfiltered and filtered) and pore water, the concentration of total mercury was correlated with methylmercury levels (R{sup 2} = 0.29, 0.26, 0.27, respectively, p < 0.05), in contrast to sediments, where organic matter and reduced iron levels were most correlated with methylmercury content (R{sup 2} = 0.37, 0.26, respectively, p < 0.05). Interestingly, levels for percent methylmercury of total mercury in sediments were higher than typical values for estuarine sediments (average 5.4%, range 0.024-38%, n = 59), while pore water methylmercury K{sub d} values were also high (average 3.1, range 2.0-4.2 l kg{sup -1}, n = 39), and the estimated methylmercury flux from sediments was low (average 1.7, range 0.14-5.3 ng m{sup -2} day{sup -1}, n = 19). Mercury levels in predatory fish tissue at Mugu are >0.3 ppm, suggesting biogeochemical controls on methylmercury mobility do not completely mitigate methylmercury uptake through the food web. - Trends in mercury cycling differed between habitats and within matrices at Mugu Lagoon.

  12. Assessment of water quality

    Qureshi, I.H.

    2002-01-01

    Water is the most essential component of all living things and it supports the life process. Without water, it would not have been possible to sustain life on this planet. The total quantity of water on earth is estimated to be 1.4 trillion cubic meter. Of this, less than 1 % water, present in rivers and ground resources is available to meet our requirement. These resources are being contaminated with toxic substances due to ever increasing environmental pollution. To reduce this contamination, many countries have established standards for the discharge of municipal and industrial waste into water streams. We use water for various purposes and for each purpose we require water of appropriate quality. The quality of water is assessed by evaluating the physical chemical, biological and radiological characteristics of water. Water for drinking and food preparation must be free from turbidity, colour, odour and objectionable tastes, as well as from disease causing organisms and inorganic and organic substances, which may produce adverse physiological effects, Such water is referred to as potable water and is produced by treatment of raw water, involving various unit operations. The effectiveness of the treatment processes is checked by assessing the various parameters of water quality, which involves sampling and analysis of water and comparison with the National Quality Standards or WHO standards. Water which conforms to these standards is considered safe and palatable for human consumption. Periodic assessment of water is necessary, to ensure the quality of water supplied to the public. This requires proper sampling at specified locations and analysis of water, employing reliable analytical techniques. (author)

  13. Mercury content of shark from south-western Australian waters

    Caputi, N.; Edmonds, J.S.; Heald, D.I.

    1979-11-01

    Muscle samples from four species of commercially sought sharks off the Western Australia coast were analyzed for total mercury. While substantial amounts of mercury were accumulated by sharks, as by other marine fish, the lack of polluting industry on the coast indicates that such mercury levels probably are natural. Mercury concentrations generally increased with fish size. (4 graphs, 1 map, 8 references, 2 tables)

  14. Mercury

    Mahoney, T J

    2014-01-01

    This gazetteer and atlas on Mercury lists, defines and illustrates every named (as opposed to merely catalogued) object and term as related to Mercury within a single reference work. It contains a glossary of terminology used, an index of all the headwords in the gazetteer, an atlas comprising maps and images with coordinate grids and labels identifying features listed in the gazetteer, and appendix material on the IAU nomenclature system and the transcription systems used for non-roman alphabets. This book is useful for the general reader, writers and editors dealing with astronomical themes, and those astronomers concerned with any aspect of astronomical nomenclature.

  15. Mercury

    Balogh, André; Steiger, Rudolf

    2008-01-01

    Mercury, the planet closest to the Sun, is different in several respects from the other three terrestrial planets. In appearance, it resembles the heavily cratered surface of the Moon, but its density is high, it has a magnetic field and magnetosphere, but no atmosphere or ionosphere. This book reviews the progress made in Mercury studies since the flybys by Mariner 10 in 1974-75, based on the continued research using the Mariner 10 archive, on observations from Earth, and on increasingly realistic models of its interior evolution.

  16. Power supply improvements for ballasts-low pressure mercury/argon discharge lamp for water purification

    Bokhtache, A. Aissa; Zegaoui, A.; Djahbar, A.; Allouache, H.; Hemici, K.; Kessaissia, F. Z.; Bouchrit, M. S.; Aillerie, M.

    2017-02-01

    The low-pressure electrical discharges established in the mercury rare gas mixtures are the basis of many applications both in the field of lighting and for industrial applications. In order to select an efficient high frequency power supply (ECG -based PWM inverter), we present and discuss results obtained in the simulation of three kinds of power supplies delivering a 0.65 A - 50KHz sinusoidal current dedicated to power low pressure UV Mercury - Argon lamp used for effect germicide on water treatment thus allowing maximum UVC radiation at 253.7 nm. Three ballasts half-bridge configurations were compared with criteria based on resulting germicide efficiency, electrical yield and reliability, for example the quality of the sinusoidal current with reduced THD, and finally, we also considered in this analysis the final economic aspect.

  17. Water Quality Assessment and Management

    Overview of Clean Water Act (CWA) restoration framework including; water quality standards, monitoring/assessment, reporting water quality status, TMDL development, TMDL implementation (point & nonpoint source control)

  18. Quality of Drinking Water

    Roman, Harry T.

    2009-01-01

    The quality of drinking water has been gaining a great deal of attention lately, especially as water delivery infrastructure continues to age. Particles of various metals such as lead and copper, and other substances like radon and arsenic could be entering drinking water supplies. Spilled-on-the-ground hydrocarbon-based substances are also…

  19. A new mercury-accumulating Mucor hiemalis strain EH8 from cold sulfidic spring water biofilms.

    Hoque, Enamul; Fritscher, Johannes

    2016-10-01

    Here, we report about a unique aquatic fungus Mucor hiemalisEH8 that can remove toxic ionic mercury from water by intracellular accumulation and reduction into elemental mercury (Hg 0 ). EH8 was isolated from a microbial biofilm grown in sulfidic-reducing spring water sourced at a Marching's site located downhill from hop cultivation areas with a history of mercury use. A thorough biodiversity survey and mercury-removal function analyses were undertaken in an area of about 200 km 2 in Bavaria (Germany) to find the key biofilm and microbe for mercury removal. After a systematic search using metal removal assays we identified Marching spring's biofilm out of 18 different sulfidic springs' biofilms as the only one that was capable of removing ionic Hg from water. EH8 was selected, due to its molecular biological identification as the key microorganism of this biofilm with the capability of mercury removal, and cultivated as a pure culture on solid and in liquid media to produce germinating sporangiospores. They removed 99% of mercury from water within 10-48 h after initial exposure to Hg(II). Scanning electron microscopy demonstrated occurrence of intracellular mercury in germinating sporangiospores exposed to mercury. Not only associated with intracellular components, but mercury was also found to be released and deposited as metallic-shiny nanospheres. Electron-dispersive x-ray analysis of such a nanosphere confirmed presence of mercury by the HgM α peak at 2.195 keV. Thus, a first aquatic eukaryotic microbe has been found that is able to grow even at low temperature under sulfur-reducing conditions with promising performance in mercury removal to safeguard our environment from mercury pollution. © 2016 The Authors. MicrobiologyOpen published by John Wiley & Sons Ltd.

  20. Water quality diagnosis system

    Nagase, Makoto; Asakura, Yamato; Sakagami, Masaharu

    1989-01-01

    By using a model representing a relationship between the water quality parameter and the dose rate in primary coolant circuits of a water cooled reactor, forecasting for the feature dose rate and abnormality diagnosis for the water quality are conducted. The analysis model for forecasting the reactor water activity or the dose rate receives, as the input, estimated curves for the forecast Fe, Ni, Co concentration in feedwater or reactor water pH, etc. from the water quality data in the post and forecasts the future radioactivity or dose rate in the reactor water. By comparing the result of the forecast and the setting value such as an aimed value, it can be seen whether the water quality at present or estimated to be changed is satisfactory or not. If the quality is not satisfactory, it is possible to take an early countermeasure. Accordingly, the reactor water activity and the dose rate can be kept low. Further, the basic system constitution, diagnosis algorithm, indication, etc. are identical between BWR and PWR reactors, except for only the difference in the mass balance. (K.M.)

  1. Delivery of water and organics to Mercury through asteroid and comet impacts

    Frantseva, Kateryna; Mueller, Michael; van der Tak, Floris F. S.

    2017-01-01

    Detection and observation of the bright and dark polar deposits in permanently shadowed northpolar regions of Mercury suggest that these regions contain water and organic compounds. This is somehow surprising taking into account the planet’s proximity to the Sun. Water flux on Mercury was studied in

  2. Water quality and water rights in Colorado

    MacDonnell, L.J.

    1989-07-01

    The report begins with a review of early Colorado water quality law. The present state statutory system of water quality protection is summarized. Special attention is given to those provisions of Colorado's water quality law aimed at protecting water rights. The report then addresses several specific issues which involve the relationship between water quality and water use. Finally, recommendations are made for improving Colorado's approach to integrating quality and quantity concerns

  3. Water Quality Data (WQX)

    The STORET (short for STOrage and RETrieval) Data Warehouse is a repository for water quality, biological, and physical data and is used by state environmental agencies, EPA and other federal agencies, universities, private citizens, and many others.

  4. A radiochemical technique for the determination of mercury in drinking water

    Ahmad, S.; Chaudhri, M.S.; Qureshi, I.H.

    1982-01-01

    A radiochemical method for the separation and determination of mercury in drinking water has been developed. The radionuclides of mercury formed after neutron irradiation of the sample were separated by liquid/liquid extraction using PAN and TBA mixture in chloroform from aqueous nitric acid medium. Quantitative extraction of mercury was achieved in a single step and the equilibrium was attained within five minutes. (orig.)

  5. Purified water quality study

    Spinka, H.; Jackowski, P.

    2000-01-01

    Argonne National Laboratory (HEP) is examining the use of purified water for the detection medium in cosmic ray sensors. These sensors are to be deployed in a remote location in Argentina. The purpose of this study is to provide information and preliminary analysis of available water treatment options and associated costs. This information, along with the technical requirements of the sensors, will allow the project team to determine the required water quality to meet the overall project goals

  6. Drinking water quality assessment.

    Aryal, J; Gautam, B; Sapkota, N

    2012-09-01

    Drinking water quality is the great public health concern because it is a major risk factor for high incidence of diarrheal diseases in Nepal. In the recent years, the prevalence rate of diarrhoea has been found the highest in Myagdi district. This study was carried out to assess the quality of drinking water from different natural sources, reservoirs and collection taps at Arthunge VDC of Myagdi district. A cross-sectional study was carried out using random sampling method in Arthunge VDC of Myagdi district from January to June,2010. 84 water samples representing natural sources, reservoirs and collection taps from the study area were collected. The physico-chemical and microbiological analysis was performed following standards technique set by APHA 1998 and statistical analysis was carried out using SPSS 11.5. The result was also compared with national and WHO guidelines. Out of 84 water samples (from natural source, reservoirs and tap water) analyzed, drinking water quality parameters (except arsenic and total coliform) of all water samples was found to be within the WHO standards and national standards.15.48% of water samples showed pH (13) higher than the WHO permissible guideline values. Similarly, 85.71% of water samples showed higher Arsenic value (72) than WHO value. Further, the statistical analysis showed no significant difference (Pwater for collection taps water samples of winter (January, 2010) and summer (June, 2010). The microbiological examination of water samples revealed the presence of total coliform in 86.90% of water samples. The results obtained from physico-chemical analysis of water samples were within national standard and WHO standards except arsenic. The study also found the coliform contamination to be the key problem with drinking water.

  7. New insights on ecosystem mercury cycling revealed by stable isotopes of mercury in water flowing from a headwater peatland catchment

    Glenn E. Woerndle; Martin Tsz-Ki Tsui; Stephen D. Sebestyen; Joel D. Blum; Xiangping Nie; Randall K. Kolka

    2018-01-01

    Stable isotope compositions of mercury (Hg) were measured in the outlet stream and in soil cores at different landscape positions in a 9.7-ha boreal upland-peatland catchment. An acidic permanganate/persulfate digestion procedure was validated for water samples with high dissolved organic matter (DOM) concentrations through Hg spike addition analysis. We report a...

  8. Nonflame atomic absorption determination of total mercury in natural waters using an HS-3 mercury-hydride system

    Evdokimova, E.V.; Solov`eva, M.Kh.; Telegin, G.F. [Institute of Problems in the Technology of Microelectronics and High-Purity Materials, Moscow (Russian Federation)

    1995-02-01

    A method for nonflame atomic absorption determination of mercury with a detection limit of 1 x 10{sup -3} {mu}g/ml in natural waters without preconcentration is described. The method can be applied successfully in analysis of the environment.

  9. Water quality effects of harbour activities assessed with integrated ...

    Ecological tools were developed to study the water quality in Cochin harbour, a complex aquatic ecosystems, through the integration of microbiological monitoring (faecal coliforms and Pseudomonas species) and heavy metal contamination (lead, cadmium and mercury). One way ANOVA indicates statistically significant ...

  10. Water Quality Monitoring

    2002-01-01

    With the backing of NASA, researchers at Michigan State University, the University of Minnesota, and the University of Wisconsin have begun using satellite data to measure lake water quality and clarity of the lakes in the Upper Midwest. This false color IKONOS image displays the water clarity of the lakes in Eagan, Minnesota. Scientists measure the lake quality in satellite data by observing the ratio of blue to red light in the satellite data. When the amount of blue light reflecting off of the lake is high and the red light is low, a lake generally had high water quality. Lakes loaded with algae and sediments, on the other hand, reflect less blue light and more red light. In this image, scientists used false coloring to depict the level of clarity of the water. Clear lakes are blue, moderately clear lakes are green and yellow, and murky lakes are orange and red. Using images such as these along with data from the Landsat satellites and NASA's Terra satellite, the scientists plan to create a comprehensive water quality map for the entire Great Lakes region in the next few years. For more information, read: Testing the Waters (Image courtesy Upper Great Lakes Regional Earth Science Applications Center, based on data copyright Space Imaging)

  11. Mercury in coal and the impact of coal quality on mercury emissions from combustion systems

    Kolker, Allan; Senior, Constance L.; Quick, Jeffrey C.

    2006-01-01

    The proportion of Hg in coal feedstock that is emitted by stack gases of utility power stations is a complex function of coal chemistry and properties, combustion conditions, and the positioning and type of air pollution control devices employed. Mercury in bituminous coal is found primarily within Fe-sulfides, whereas lower rank coal tends to have a greater proportion of organic-bound Hg. Preparation of bituminous coal to reduce S generally reduces input Hg relative to in-ground concentrations, but the amount of this reduction varies according to the fraction of Hg in sulfides and the efficiency of sulfide removal. The mode of occurrence of Hg in coal does not directly affect the speciation of Hg in the combustion flue gas. However, other constituents in the coal, notably Cl and S, and the combustion characteristics of the coal, influence the species of Hg that are formed in the flue gas and enter air pollution control devices. The formation of gaseous oxidized Hg or particulate-bound Hg occurs post-combustion; these forms of Hg can be in part captured in the air pollution control devices that exist on coal-fired boilers, without modification. For a given coal type, the capture efficiency of Hg by pollution control systems varies according to type of device and the conditions of its deployment. For bituminous coal, on average, more than 60% of Hg in flue gas is captured by fabric filter (FF) and flue-gas desulfurization (FGD) systems. Key variables affecting performance for Hg control include Cl and S content of the coal, the positioning (hot side vs. cold side) of the system, and the amount of unburned C in coal ash. Knowledge of coal quality parameters and their effect on the performance of air pollution control devices allows optimization of Hg capture co-benefit

  12. Infiltration behaviour of elemental mercury DNAPL in fully and partially water saturated porous media

    D'Aniello, Andrea; Hartog, Niels; Sweijen, Thomas; Pianese, Domenico

    2018-02-01

    Mercury is a contaminant of global concern due to its harmful effects on human health and for the detrimental consequences of its release in the environment. Sources of liquid elemental mercury are usually anthropogenic, such as chlor-alkali plants. To date insight into the infiltration behaviour of liquid elemental mercury in the subsurface is lacking, although this is critical for assessing both characterization and remediation approaches for mercury DNAPL contaminated sites. Therefore, in this study the infiltration behaviour of elemental mercury in fully and partially water saturated systems was investigated using column experiments. The properties affecting the constitutive relations governing the infiltration behaviour of liquid Hg0, and PCE for comparison, were determined using Pc(S) experiments with different granular porous media (glass beads and sands) for different two- and three-phase configurations. Results showed that, in water saturated porous media, elemental mercury, as PCE, acted as a non-wetting fluid. The required entry head for elemental mercury was higher (from about 5 to 7 times). However, due to the almost tenfold higher density of mercury, the required NAPL entry heads of 6.19 cm and 12.51 cm for mercury to infiltrate were 37.5% to 20.7% lower than for PCE for the same porous media. Although Leverett scaling was able to reproduce the natural tendency of Hg0 to be more prone than PCE to infiltrate in water saturated porous media, it considerably underestimated Hg0 infiltration capacity in comparison with the experimental results. In the partially water saturated system, in contrast with PCE, elemental mercury also acted as a nonwetting fluid, therefore having to overcome an entry head to infiltrate. The required Hg0 entry heads (10.45 and 15.74 cm) were considerably higher (68.9% and 25.8%) than for the water saturated porous systems. Furthermore, in the partially water saturated systems, experiments showed that elemental mercury displaced

  13. Estimation of some heavy metals in polluted well water and mercury accumulation in broiler organs

    Hussein, Hussein Khamis; Abu-Zinadah, Osama Abdullah; EL-Rabey, Haddad Abdulsameih; Meerasahib, Mohammed Fareez

    2013-01-01

    The aim of this study was to investigate the relationship between the concentrations of heavy metals in well water and bioaccumulation of the most abundant metals in chicken tissues in some areas in the province of Mecca Almokaramah, Saudi Arabia. Among the heavy metals (Cd, Zn, Cr, Mn, Cu Hg, Pb and Ni) studied, mercury (Hg) revealed highest in concentration in well waters. The concentration of mercury in the ground water, beside in liver, kidney, muscle and blood samples of ten chickens fro...

  14. Sampling problems and the determination of mercury in surface water, seawater, and air

    Das, H.A.; van der Sloot, H.A.

    1976-01-01

    Analysis of surface water for mercury comprises the determination of both ionic and organically bound mercury in solution and that of the total mercury content of the suspended matter. Eventually, metallic mercury has to be determined too. Requirements for the sampling procedure are given. A method for the routine determination of mercury in surface water and seawater was developed and applied to Dutch surface waters. The total sample volume is 2500 ml. About 500 ml is used for the determination of the content of suspended matter and the total amount of mercury in the water. The sample is filtered through a bed of previously purified active charcoal at a low flow-rate. The main portion ca. 2000 ml) passes a flow-through centrifuge to separate the solid fraction. One liter is used to separate ''inorganic'' mercury by reduction, volatilization in an airstream and adsorption on active charcoal. The other liter is led through a column of active charcoal to collect all mercury. The procedures were checked with 197 Hg radiotracer both as an ion and incorporated in organic compounds. The mercury is determined by thermal neutron activation, followed by volatilization in a tube furnace and adsorption on a fresh carbon bed. The limit of determination is approximately equal to 1 ng 1 -1 . The rate of desorption from and adsorption on suspended material has been measured as a function of a pH of the solution for Hg +2 and various other ions. It can be concluded that only the procedure mentioned above does not disturb the equilibrium. The separation of mercury from air is obtained by suction of 1 m 3 through a 0.22 μm filter and a charcoal bed. The determination is then performed as in the case of the water samples

  15. Water quality in the Okavango Delta

    2010-03-12

    Mar 12, 2010 ... Their interactions with light, water, dissolved nutrients and suspended solids determine .... water, which are essential for various metabolic processes in. Figure 2 ..... 1993). Arsenic, cadmium, copper, lead, and mercury are the.

  16. Mercury Concentration Reduction In Waste Water By Using Liquid Surfactant Membrane Technique

    Prayitno; Sardjono, Joko

    2000-01-01

    The objective of this research is ti know effectiveness of liquid surfactant membrane in diminishing mercury found in waste water. This process can be regarded as transferring process of solved mercury from the external phase functioning as a moving phase to continue to the membrane internal one. The existence of the convection rotation results in the change of the surface pressure on the whole interface parts, so the solved mercury disperses on every interface part. Because of this rotation, the solved mercury will fulfil every space with particles from dispersion phase in accordance with its volume. Therefore, the change of the surface pressure on the whole interface parts can be kept stable to adsorb mercury. The mercury adsorbed in the internal phase moves to dispersed particles through molecule diffusion process. The liquid surfactant membrane technique in which the membrane phase is realized into emulsion contains os kerosene as solvent, sorbitan monoleat (span-80) 5 % (v/v) as surfactant, threbuthyl phosphate (TBP) 10 % (v/v) as extractant, and solved mercury as the internal phase. All of those things are mixed and stirred with 8000 rpm speed for 20 minutes. After the stability of emulsion is formed, the solved mercury is extracted by applying extraction process. The effective condition required to achieve mercury ion recovery utilizing this technique is obtained through extraction and re-extraction process. This process was conducted in 30 minutes with membrane and mercury in scale 1 : 1 on 100 ppm concentration. The results of the processes was 99,6 % efficiency. This high efficiency shows that the liquid surfactant membrane technique is very effective to reduce waste water contamined by mercury

  17. Agricultural drainage water quality

    Madani, A.; Gordon, R.

    2002-01-01

    'Full text:' Agricultural drainage systems have been identified as potential contributors of non-point source pollution. Two of the major concerns have been with nitrate-nitrogen (NO3 - -N) concentrations and bacteria levels exceeding the Maximum Acceptable Concentration in drainage water. Heightened public awareness of environmental issues has led to greater pressure to maintain the environmental quality of water systems. In an ongoing field study, three experiment sites, each with own soil properties and characteristics, are divided into drainage plots and being monitored for NO3 - -N and fecal coliforms contamination. The first site is being used to determine the impact of the rate of manure application on subsurface drainage water quality. The second site is being used to determine the difference between hog manure and inorganic fertilizer in relation to fecal coliforms and NO3-N leaching losses under a carrot rotation system. The third site examines the effect of timing of manure application on water quality, and is the only site equipped with a surface drainage system, as well as a subsurface drainage system. Each of the drains from these fields lead to heated outflow buildings to allow for year-round measurements of flow rates and water samples. Tipping buckets wired to data-loggers record the outflow from each outlet pipe on an hourly basis. Water samples, collected from the flowing drains, are analyzed for NO3 - -N concentrations using the colorimetric method, and fecal coliforms using the Most Probable Number (MPN) method. Based on this information, we will be able better positioned to assess agricultural impacts on water resources which will help towards the development on industry accepted farming practices. (author)

  18. Mercury in sediment, water, and fish in a managed tropical wetland-lake ecosystem.

    Malczyk, Evan A; Branfireun, Brian A

    2015-08-15

    Mercury pollution has not been well documented in the inland lakes or fishes of Mexico, despite the importance of freshwater fish as a source of protein in local diets. Total mercury and methylmercury in waters, sediments, and the commercial fish catch were investigated in Lake Zapotlán, Mexico. Concentrations of total and methylmercury were very high in runoff and wastewater inputs, but very low in sediments and surface waters of the open water area of the lake. Concentrations of total mercury in tilapia and carp were very low, consistent with the low concentrations in lake water and sediments. Particle settling, sorption, the biogeochemical environment, and/or bloom dilution are all plausible explanations for the significant reductions in both total mercury and methylmercury. Despite very high loading of mercury, this shallow tropical lake was not a mercury-impaired ecosystem, and these findings may translate across other shallow, alkaline tropical lakes. Importantly, the ecosystem services that seemed to be provided by peripheral wetlands in reducing mercury inputs highlight the potential for wetland conservation or restoration in Mexico. Copyright © 2015. Published by Elsevier B.V.

  19. Assessment of mercury erosion by surface water in Wanshan mercury mining area.

    Dai, ZhiHui; Feng, Xinbin; Zhang, Chao; Shang, Lihai; Qiu, Guangle

    2013-08-01

    Soil erosion is a main cause of land degradation, and in its accelerated form is also one of the most serious ecological environmental problems. Moreover, there are few studies on migration of mercury (Hg) induced by soil erosion in seriously Hg-polluted districts. This paper selected Wanshan Hg mining area, SW China as the study area. Revised universal soil loss equation (RUSLE) and Geographic information system (GIS) methods were applied to calculate soil and Hg erosion and to classify soil erosion intensity. Our results show that the soil erosion rate can reach up to 600,884tkm(-2)yr(-1). Surfaces associated with very slight and extremely severe erosion include 76.6% of the entire land in Wanshan. Furthermore, the cumulative erosion rates in the area impacted by extremely severe erosion make up 90.5% of the total. On an annual basis, Hg surface erosion load was predicted to be 505kgyr(-1) and the corresponding mean migration flux of Hg was estimated to be 3.02kgkm(-2)yr(-1). The erosion loads of Hg resulting from farmland and meadow soil were 175 and 319kgyr(-1) respectively, which were enhanced compared to other landscape types due to the fact that they are generally located in the steep zones associated with significant reclamation. Contributing to establish a mass balance of Hg in Wanshan Hg mining area, this study supplies a dependable scientific basis for controlling soil and water erosion in the local ecosystems. Land use change is the most effective way for reducing Hg erosion load in Wanshan mining area. Copyright © 2013 Elsevier Inc. All rights reserved.

  20. Selective extraction of trace mercury and cadmium from drinking water sources.

    Zhao, Xuan; Zhao, Gang; Wang, Jianlong; Yun, Guichun

    2005-01-01

    In this paper, a new alternative method, i.e., selective extraction by weakly basic anion exchange resin, has been developed for the removal of trace cadmium and mercury ions from drinking water sources. The mechanism of heavy metal removal is based on selective extraction as the results of LEWIS-base-acid interactions. Transfer of trace mercury species from liquid to resin phase coincides well with the performance of film diffusion. The results demonstrated that the presence of chlorine has a negligible influence on the removal of mercury. However, humic acids can strongly bind mercury by the formation of complex compounds and therefore become the obstacle in the diffusion progress. At neutral or base pH, the resin material exhibits the favorable uptake of heavy metals. In filter experiments, the studied resin material offers favorable properties in the selective extraction of trace mercury and cadmium.

  1. Preparation and certification of trace mercury in water standard reference materials

    Moody, J.R.; Paulsen, P.J.; Rains, T.C.; Rook, H.L.

    1976-01-01

    The study of mercury in natural water supplies requires a Standard Reference Material (SRM) with a certified concentration at the 1 ng/g level. NBS SRM's have been prepared with nominal mercury concentrations of 1.5 μg/g and 1.2 ng/g. Confirmation of these values was obtained by neutron activation, atomic absorption, and isotope dilution-spark source mass spectrometry (IDSSMS). Nitric acid and trace amounts of gold were added to achieve a stable mercury concentration. The precautions observed for cleaning the glass and Teflon containers, preparation of mercury solutions, and the packaging of the SRM's are given. As an example of the care needed in the analysis of mercury at these levels, specific details are presented for the chemistry required to prepare samples for the spark source mass spectrometer

  2. Determination of mercury in discharge water from plastic manufactory by neutron activation analysis and copper powder adsorption

    Houng-Huei, L [National Tsing Hua University Hsinchu, Taiwan (Republic of China)

    1979-02-28

    Through copper powder adsorption, neutron activation analysis was used to determine the mercury in discharge water from a plastic manufactory where the water samples were taken from various discharge ditches. The experimental results showed that waste water from mercury cells contained 1.7x10/sup -9/ approximately 8.19x10/sup -6/ g Hg/ml while water samples taken from other areas did not show significant mercury level and were below the limit of detection.

  3. Summarized water quality criteria

    Kempster, P.L.; Hattingh, W.H.J.; Van Vliet, H.R.

    1980-08-01

    The available world literature from 27 sources on existing water quality criteria are summarized for the 15 main uses of water. The minimum, median and maximum specified values for 96 different determinands are included. Under each water use the criteria are grouped according to the functional significance of the determinands e.g. aesthetic/physical effects, high toxic potential, low toxic potential etc. A synopsis is included summarizing salient facts for each determinand such as the conditions under which it is toxic and its relationship to other determinands. The significance of the criteria is briefly discussed and the importance of considering functional interactions between determinands emphasized in evaluating the potential for toxic or beneficial effects. From the source literature it appears that the toxic potential, in addition to being determined by concentration, is also affected by the origin of the substance concerned, i.e. whether from natural sources or from anthropogenic pollution

  4. Water quality status and trends in the United States

    Larsen, Matthew C.; Hamilton, Pixie A.; Werkheiser, William H.; Ahuja, Satinder

    2013-01-01

    Information about water quality is vital to ensure long-term availability and sustainability of water that is safe for drinking and recreation and suitable for industry, irrigation, fish, and wildlife. Protecting and enhancing water quality is a national priority, requiring information on water-quality status and trends, progress toward clean water standards, continuing problems, and emerging challenges. In this brief review, we discuss U.S. Geological Survey assessments of nutrient pollution, pesticides, mixtures of organic wastewater compounds (known as emerging contaminants), sediment-bound contaminants (like lead and DDT), and mercury, among other contaminants. Additionally, aspects of land use and current and emerging challenges associated with climate change are presented. Climate change must be considered, as water managers continue their efforts to maintain sufficient water of good quality for humans and for the ecosystem.

  5. Flow Alteration and Chemical Reduction: Air Stripping to Lessen Subsurface Discharges of Mercury to Surface Water

    Brooks, S. C.; Bogle, M.; Liang, L.; Miller, C. L.; Peterson, M.; Southworth, G. R.; Spalding, B. P.

    2009-12-01

    Mercury concentrations in groundwater, surface water, and biota near an industrial facility in Oak Ridge, Tennessee remain high some 50 years after the original major releases from the facility to the environment. Since the mid-1980s, various remedial and abatement actions have been implemented at the facility, including re-routing water flows, armoring contaminated stream banks, relining or cleanout of facility storm drains, and activated charcoal treatment of groundwater and sump discharges. These actions were taken to reduce inorganic mercury inputs from the facility to the stream; a strategy that assumes limiting the inorganic mercury precursor will reduce Hg methylation and its subsequent bioaccumulation. To date, such actions have reduced mercury loading from the site by approximately 90% from levels typical of the mid 1980's, but waterborne mercury at the facility boundary remains roughly 100 times the typical local background concentration and methylmercury accumulation in aquatic biota exceed standards for safe consumption by humans and wildlife. In 2008 and 2009, a series of investigations was initiated to explore innovative approaches to further control mercury concentrations in stream water. Efforts in this study focused on decreasing waterborne inorganic mercury inputs from two sources. The first, a highly localized source, is the discharge point of the enclosed stormdrain network whereas the second is a more diffuse short reach of stream where metallic Hg in streambed sediments generates a continued input of dissolved Hg to the overlying water. Moving a clean water flow management discharge point to a position downstream of the contaminated reach reduced mercury loading from the streambed source by 75% - 100%, likely by minimizing resuspension of Hg-rich fine particulates and changing characteristic hyporheic flow path length and residence time. Mercury in the stormdrain discharge exists as highly reactive dissolved Hg(II) due to residual chlorine in

  6. Hemodialysis and water quality.

    Coulliette, Angela D; Arduino, Matthew J

    2013-01-01

    Over 383,900 individuals in the U.S. undergo maintenance hemodialysis that exposes them to water, primarily in the form of dialysate. The quality of water and associated dialysis solutions have been implicated in adverse patient outcomes and is therefore critical. The Association for the Advancement of Medical Instrumentation has published both standards and recommended practices that address both water and the dialyzing solutions. Some of these recommendations have been adopted into Federal Regulations by the Centers for Medicare and Medicaid Services as part of the Conditions for Coverage, which includes limits on specific contaminants within water used for dialysis, dialysate, and substitution fluids. Chemical, bacterial, and endotoxin contaminants are health threats to dialysis patients, as shown by the continued episodic nature of outbreaks since the 1960s causing at least 592 cases and 16 deaths in the U.S. The importance of the dialysis water distribution system, current standards and recommendations, acceptable monitoring methods, a review of chemical, bacterial, and endotoxin outbreaks, and infection control programs are discussed. Published 2013. This article is a U.S. Government work and is in the public domain in the USA.

  7. National Recommended Water Quality Criteria

    U.S. Environmental Protection Agency — The National Recommended Water Quality Criteria is a compilation of national recommended water quality criteria for the protection of aquatic life and human health...

  8. Estimation of Water Quality

    Vetrinskaya, N.I.; Manasbayeva, A.B.

    1998-01-01

    Water has a particular ecological function and it is an indicator of the general state of the biosphere. In relation with this summary, the toxicological evaluation of water by biologic testing methods is very actual. The peculiarity of biologic testing information is an integral reflection of all totality properties of examination of the environment in position of its perception by living objects. Rapid integral evaluation of anthropological situation is a base aim of biologic testing. If this evaluation has deviations from normal state, detailed analysis and revelation of dangerous components could be conducted later. The quality of water from the Degelen gallery, where nuclear explosions were conducted, was investigated by bio-testing methods. The micro-organisms (Micrococcus Luteus, Candida crusei, Pseudomonas algaligenes) and water plant elodea (Elodea canadensis Rich) were used as test-objects. It is known that the transporting functions of cell membranes of living organisms are violated the first time in extreme conditions by difference influences. Therefore, ion penetration of elodeas and micro-organisms cells, which contained in the examination water with toxicants, were used as test-function. Alteration of membrane penetration was estimated by measurement of electrolytes electrical conductivity, which gets out from living objects cells to distillate water. Index of water toxic is ratio of electrical conductivity in experience to electrical conductivity in control. Also, observations from common state of plant, which was incubated in toxic water, were made. (Chronic experience conducted for 60 days.) The plants were incubated in water samples, which were picked out from gallery in the years 1996 and 1997. The time of incubation is 1-10 days. The results of investigation showed that ion penetration of elodeas and micro-organisms cells changed very much with influence of radionuclides, which were contained in testing water. Changes are taking place even in

  9. Evaluation of mercury and physicochemical parameters in different depths of aquifer water of Thar coalfield, Pakistan.

    Ali, Jamshed; Kazi, Tasneem G; Tuzen, Mustafa; Ullah, Naeem

    2017-07-01

    In the current study, mercury (Hg) and physicochemical parameters have been evaluated in aquifer water at different depths of Thar coal field. The water samples were collected from first aquifer (AQ 1 ), second aquifer (AQ 2 ), and third aquifer (AQ 3 ) at three depths, 50-60, 100-120, and 200-250 m, respectively. The results of aquifer water of three depths were interpreted by using different multivariate statistical techniques. Validation of desired method was checked by spiking standard addition method in studied aquifer water samples. The content of Hg in aquifer water samples was measured by cold vapor atomic absorption spectrometer (CV-AAS). These determined values illustrate that the levels of Hg were higher than WHO recommended values for drinking water. All physicochemical parameters were higher than WHO permissible limits for drinking water except pH and SO 4 2- in aquifer water. The positive correlation of Hg with other metals in aquifer water samples of AQ 1 , AQ 2 , and AQ 3 of Thar coalfield except HCO 3 - was observed which might be caused by geochemical minerals. The interpretation of determined values by the cluster technique point out the variations within the water quality parameter as well as sampling location of studied field. The aquifer water AQ 2 was more contaminated with Hg as compared to AQ 1 and AQ 3 ; it may be due to leaching of Hg from coal zone. The concentration of Hg in aquifer water obtained from different depths was found in the following decreasing order: AQ 2  < AQ 1  < AQ 3 .

  10. Water quality sensor

    Ishizuka, Keiko; Takahashi, Masanori; Watanabe, Atsushi; Ibe, Hidefumi.

    1994-01-01

    The sensor of the present invention can directly measure oxygen/hydrogen peroxide concentrations in reactor water under radiation irradiation condition, and it has a long life time. Namely, an oxygen sensor comprises electrodes attached on both sides of high temperature/radiation resistant ion conductive material in which ions are sufficiently diffused within a temperature range of from a room temperature to 300degC. It has a performance for measuring electromotive force caused by the difference of a partial pressure between a reference gas and a gas to be measured contained in the high temperature/radiation resistant material. A hydrogen peroxide sensor has the oxygen sensor described above, to which a filter for causing decomposition of hydrogen peroxide is attached. The sensor of the present invention can directly measure oxygen/hydrogen peroxide concentrations in a reactor water of a BWR type reactor under high temperature/radiation irradiation condition. Accordingly, accurate water quality environment in the reactor water can be recognized. As a result, determination of incore corrosion environment is established thereby enabling to attain reactor integrity, safety and long life. (I.S.)

  11. Removal of mercury (Hg) from contaminated water at traditional gold mining area in Central Kalimantan

    Wilopo, Wahyu; Rahman, Denizar; Eka Putra, Doni Prakasa; Warmada, I Wayan

    2015-01-01

    There are many traditional gold mining and processing in Murung Raya Regency, Central Kalimantan. The processing of gold mostly uses mercury (Hg) and produces a lot of waste water. It just throws to the river without any treatment. Therefore the concentration of mercury (Hg) in the river water is over than the standard of drinking water and reach up to 0.346 mg dm-3. This situation is very dangerous because almost of the people in the downstream area depend on the river water for their daily ...

  12. South Bay Salt Pond Mercury Studies Project

    Information about the SFBWQP South Bay Salt Pond Mercury Studies Project, part of an EPA competitive grant program to improve SF Bay water quality focused on restoring impaired waters and enhancing aquatic resources.

  13. Mercury in Sediment, Water, and Biota of Sinclair Inlet, Puget Sound, Washington, 1989-2007

    Paulson, Anthony J.; Keys, Morgan E.; Scholting, Kelly L.

    2010-01-01

    Historical records of mercury contamination in dated sediment cores from Sinclair Inlet are coincidental with activities at the U.S. Navy Puget Sound Naval Shipyard; peak total mercury concentrations occurred around World War II. After World War II, better metallurgical management practices and environmental regulations reduced mercury contamination, but total mercury concentrations in surface sediment of Sinclair Inlet have decreased slowly because of the low rate of sedimentation relative to the vertical mixing within sediment. The slopes of linear regressions between the total mercury and total organic carbon concentrations of sediment offshore of Puget Sound urban areas was the best indicator of general mercury contamination above pre-industrial levels. Prior to the 2000-01 remediation, this indicator placed Sinclair Inlet in the tier of estuaries with the highest level of mercury contamination, along with Bellingham Bay in northern Puget Sound and Elliott Bay near Seattle. This indicator also suggests that the 2000/2001 remediation dredging had significant positive effect on Sinclair Inlet as a whole. In 2007, about 80 percent of the area of the Bremerton naval complex had sediment total mercury concentrations within about 0.5 milligrams per kilogram of the Sinclair Inlet regression. Three areas adjacent to the waterfront of the Bremerton naval complex have total mercury concentrations above this range and indicate a possible terrestrial source from waterfront areas of Bremerton naval complex. Total mercury concentrations in unfiltered Sinclair Inlet marine waters are about three times higher than those of central Puget Sound, but the small numbers of samples and complex physical and geochemical processes make it difficult to interpret the geographical distribution of mercury in marine waters from Sinclair Inlet. Total mercury concentrations in various biota species were compared among geographical locations and included data of composite samples, individual

  14. Microbiological stimulation of phytoremediation process using Salvinia natans to mercury contamined water

    Filyarovskaya Viktoriya; Sitarska Magdalena; Traczewska Teodora; Wolf Mirela

    2017-01-01

    An alternative to traditional cleaning methods of heavy metals in the water environment is phytoremediation. They efficiency depends on used technological process conditions as well as plant species. One of the most dangerous metallic elements mercury plays a particular role, which is a trace element and a physiologically foreign in living organisms. Mercury has a high degree of toxicity with strong affinity to thiol groups. This may cause an adverse effect on the enzymatic processes and cons...

  15. Microbiological stimulation of phytoremediation process using Salvinia natans to mercury contamined water

    Filyarovskaya, Viktoriya; Sitarska, Magdalena; Traczewska, Teodora; Wolf, Mirela

    2017-11-01

    An alternative to traditional cleaning methods of heavy metals in the water environment is phytoremediation. They efficiency depends on used technological process conditions as well as plant species. One of the most dangerous metallic elements mercury plays a particular role, which is a trace element and a physiologically foreign in living organisms. Mercury has a high degree of toxicity with strong affinity to thiol groups. This may cause an adverse effect on the enzymatic processes and consequently inhibiting the physiological functions. Because of high risk for human health, water environment treatment from mercury is essential proecological action. Mercury removal studies were conducted using Salvinia natans pleustofit, sampled from its natural water environment. In the first step, epiphytic bacteria, which was resistant to high concentrations of mercury (0,6 mgHg/l), was isolated from the plant and than selected by the tiles gradient mthod. In the next step, the identification using molecular biology methods was made. In the following step plant Salvinia natans was exposure to high levels of mercury in the presence of the three isolated Pseudomonas strains with exceptional resistance characteristics to environmental factors. Has been found a positive bacteria effect on the plant condition because the selected strains belong to Pseudomonas species producing materials supporting plant growth. The use of microbial stimulation to phytoremediation by hyperaccumulator Salvinia natans can multiply the effectiveness of the process.

  16. Microbiological stimulation of phytoremediation process using Salvinia natans to mercury contamined water

    Filyarovskaya Viktoriya

    2017-01-01

    Full Text Available An alternative to traditional cleaning methods of heavy metals in the water environment is phytoremediation. They efficiency depends on used technological process conditions as well as plant species. One of the most dangerous metallic elements mercury plays a particular role, which is a trace element and a physiologically foreign in living organisms. Mercury has a high degree of toxicity with strong affinity to thiol groups. This may cause an adverse effect on the enzymatic processes and consequently inhibiting the physiological functions. Because of high risk for human health, water environment treatment from mercury is essential proecological action. Mercury removal studies were conducted using Salvinia natans pleustofit, sampled from its natural water environment. In the first step, epiphytic bacteria, which was resistant to high concentrations of mercury (0,6 mgHg/l, was isolated from the plant and than selected by the tiles gradient mthod. In the next step, the identification using molecular biology methods was made. In the following step plant Salvinia natans was exposure to high levels of mercury in the presence of the three isolated Pseudomonas strains with exceptional resistance characteristics to environmental factors. Has been found a positive bacteria effect on the plant condition because the selected strains belong to Pseudomonas species producing materials supporting plant growth. The use of microbial stimulation to phytoremediation by hyperaccumulator Salvinia natans can multiply the effectiveness of the process.

  17. Data quality through a web-based QA/QC system: implementation for atmospheric mercury data from the global mercury observation system.

    D'Amore, Francesco; Bencardino, Mariantonia; Cinnirella, Sergio; Sprovieri, Francesca; Pirrone, Nicola

    2015-08-01

    The overall goal of the on-going Global Mercury Observation System (GMOS) project is to develop a coordinated global monitoring network for mercury, including ground-based, high altitude and sea level stations. In order to ensure data reliability and comparability, a significant effort has been made to implement a centralized system, which is designed to quality assure and quality control atmospheric mercury datasets. This system, GMOS-Data Quality Management (G-DQM), uses a web-based approach with real-time adaptive monitoring procedures aimed at preventing the production of poor-quality data. G-DQM is plugged on a cyberinfrastructure and deployed as a service. Atmospheric mercury datasets, produced during the first-three years of the GMOS project, are used as the input to demonstrate the application of the G-DQM and how it identifies a number of key issues concerning data quality. The major issues influencing data quality are presented and discussed for the GMOS stations under study. Atmospheric mercury data collected at the Longobucco (Italy) station is used as a detailed case study.

  18. Differences and similarity in the dynamic and acoustic properties of gas microbubbles in liquid mercury and water

    Ida, Masato; Haga, Katsuhiro; Kogawa, Hiroyuki; Naoe, Takashi; Futakawa, Masatoshi

    2010-01-01

    Differences and similarities in the dynamics of microbubbles in liquid mercury and water are clarified and summarized in order to evaluate the validity and usefulness of experiments with water as an alternative to experiments with mercury. Pressure-wave induced cavitation in liquid mercury is of particular concern in the high-power pulsed neutron sources working in Japan and the U.S. Toward suppressing the pressure waves and cavitation, injection of gas microbubbles into liquid mercury has been attempted. However, many difficulties arise in mercury experiments mainly because liquid mercury is an opaque liquid. Hence we and collaborators have performed water experiments as an alternative, in conjunction with mercury experiments. In this paper, we discussed how we should use the result with water and how we can make the water experiments meaningful. The non-dimensional numbers of bubbly liquids and bubbles' rise velocity, coalescence frequency, and response to heat input were investigated theoretically for both mercury and water. A suggestion was made to 'see through' bubble distribution in flowing mercury from the result of water study, and a notable similarity was found in the effect of bubbles to absorb thermal expansion of the liquids. (author)

  19. Health assessment and mercury analyses of fishes of the Atchafalaya National Wildlife Refuge

    Department of the Interior — Mercury and poor water quality in the Atchafalaya River Basin have been documented by the Louisiana Department of Environmental Quality’s Mercury Monitoring Program....

  20. Communicating water quality risk

    Scherer, C.W.

    1990-01-01

    Technology for detecting and understanding water quality problems and the impacts of activities on long-range groundwater quality has advanced considerably. In the past a technical solution was considered adequate but today one must consider a wide range of both technical and social factors in evaluating technical alternatives that are also acceptable social solutions. Policies developed and implemented with limited local participation generally are resisted and become ineffective if public cooperation is necessary for effective implementation. The public, the experts and the policymakers all must understand and appreciate the different perspectives present in risk policymaking. The typical model used to involve the public in policy decisions is a strategy described as the decide-announce-defend-approach. Much more acceptable to the public, but also more difficult to implement, is a strategy that calls for free flow of information within the community about the problem, policies and potential solutions. Communication about complex issues will be more successful if the communication is substantial; if it takes advantage of existing interpersonal networks and mass media; if it pays particular attention to existing audience knowledge, interest and behaviors; and if it clearly targets messages to various segments of the audience

  1. Assessment of air quality for arsenic, cadmium, mercury and nickel in the Netherlands

    Buijsman E; LLO

    The presence of arsenic, cadmium, mercury and nickel in air in the Netherlands has been investigated. Using measurement data, a limited supplemental monitoring effort and the results of modelling calculations, it has been possible to obtain a realistic picture of air quality in the Netherlands with

  2. Uptake of arsenic, cadmium, lead and mercury from polluted waters by the water hyacinth Eichornia crassipes

    Chigbo, F.E.; Smith, R.W.; Shore, F.L.

    1982-01-01

    The water hyacinth Eichornia crassipes was studied as a pollution monitor for the simultaneous accumulation of arsenic, cadmium, lead and mecury. After cultivation of the plants for 2 days in tanks containing 10 ppm of each of the metals in aqueous solution, the plants were harvested and rinsed with tap water. The leaves and stems were separated and analysed for each of the metals. The ratio of the concentration of arsenic and mercury in the leaves to the concentrations in the stems was found to be 2:1. Cadmium and lead showed a concentration ratio in leaves to stems of about 1:1. The leaf concentration of arsenic was the lowest of the metals of 0.3428 mg g/sup -1/ of dried plant material whilst the leaf concentration of cadmium was highest at 0.5740 mg g/sup -1/ of dried plant material. Control plants were grown in unpolluted water. Plants grown in Bay St. Louis, Mississippi sewage lagoon were also analysed. The mercury concentrations of the leaves of plants grown in the sewage lagoon were significantly different from the control sample which had a concentration of 0.0700 mg g/sup -1/ of dried plant material.

  3. Water availability, water quality water governance: the future ahead

    Tundisi, J. G.; Matsumura-Tundisi, T.; Ciminelli, V. S.; Barbosa, F. A.

    2015-04-01

    The major challenge for achieving a sustainable future for water resources and water security is the integration of water availability, water quality and water governance. Water is unevenly distributed on Planet Earth and these disparities are cause of several economic, ecological and social differences in the societies of many countries and regions. As a consequence of human misuse, growth of urbanization and soil degradation, water quality is deteriorating continuously. Key components for the maintenance of water quantity and water quality are the vegetation cover of watersheds, reduction of the demand and new water governance that includes integrated management, predictive evaluation of impacts, and ecosystem services. Future research needs are discussed.

  4. Total mercury in water, sediments, and animals along the Indian Coast

    Sanzgiri, S.; Mesquita, A.; Kureishy, T.W.

    Total mercury (Hg) in water, sediments and animals along the coast of India is estimated. Water samples were collected on board of R.V. Gaveshani.The zooplankton samples were collected by Indian Ocean Standard Net and Heron Tranter nets of 500 mesh...

  5. Estimation of some heavy metals in polluted well water and mercury accumulation in broiler organs

    Hussein Khamis Hussein

    2013-10-01

    Full Text Available The aim of this study was to investigate the relationship between the concentrations of heavy metals in well water and bioaccumulation of the most abundant metals in chicken tissues in some areas in the province of Mecca Almokaramah, Saudi Arabia. Among the heavy metals (Cd, Zn, Cr, Mn, Cu Hg, Pb and Ni studied, mercury (Hg revealed highest in concentration in well waters. The concentration of mercury in the ground water, beside in liver, kidney, muscle and blood samples of ten chickens from each of four poultry- production farms were estimated using atomic absorption spectrophotometer. The results showed that the kidney followed by liver had the highest bioaccumulation of mercury in all farm samples. The level of mercury in the ground water was 7.06µg/L. The relationship between mercury accumulation levels in the kidney and those in the liver tissues were proportionally correlated and altered with elevation in the antioxidant enzyme activities such as AST and ALT. These elevated enzymatic activities were induced by the level of toxicity. There was a significant elevation in the level of liver and kidney malondialdhyde (MDA, while the activities of antioxidant enzymes superoxide dismutase and catalase (SOD and CAT were significantly decreased. Biochemical observations were supplemented by histopathological examination of liver and kidney sections.

  6. Multi-weight isotherm results for mercury removal in upper East Fork Popular Creek water

    Bostick, D.A.; Klasson, K.T.

    1998-02-01

    Many sorbents have been developed for the removal of mercury and heavy metals from waters; however, the majority of data published to date do not address the removal of mercury to the target levels represented in this project. The application to which these sorbents are targeted for use is the removal of mercury from microgram-per-liter levels to low nanogram-per-liter levels. Sorbents with thiouronium, thiol, amine, sulfur, and proprietary functional groups were selected for these studies. The initial mercury content in the majority of the batch samples was significantly augmented so that the equilibrium concentration was similar to that found in the original stream sample for at least one sample. Mercury was successfully removed from actual water via adsorption onto Ionac SR-4 (by Sybron Chemicals, Inc.), Keyle:X (by SolmeteX), and Mersorb (by Nucon International, Inc.) resins to levels below the target goal of 12 ng/L. A thiol-based resin (Ionac SR-4) performed the best, indicating that over 200,000 volumes of water could be treated with one volume of resin. The cost of the resin is approximately $0.24 per 1000 gal of water

  7. The determination of levels of mercury, cadmium and lead in water samples from Naivasha area, Kenya

    Muigai, P.G.; Kamau, G.N.; Kinyua, A.M.

    1995-01-01

    The analysis of mercury, cadmium and lead in water samples from different environments (Lake Naivasha, River Malewa boreholes and Olkaria geothermal wells) in Naivasha region and their possible origins are reported. The levels of mercury and lead in the water samples were above the maximum permissible limits of 0.005 mg/1 and 0.1 mg/1 respectively, as stipulated by the WHO. On the other hand, 83.3% of the samples had cadmium levels above the maximum permissible limit of 0.01mg/1 in drinking water by WHO. The mercury and lead levels were also higher than those previously obtained from different regions of Kenya, while those for cadmium were within the corresponding range. Possible sources of elevated values were the geology of the surrounding area, sewage treatment works, use of phosphate rock fertilizers and lead fuels.(author)

  8. Antibiotic-resistant fecal bacteria, antibiotics, and mercury in surface waters of Oakland County, Michigan, 2005-2006

    Fogarty, Lisa R.; Duris, Joseph W.; Crowley, Suzanne L.; Hardigan, Nicole

    2007-01-01

    Water samples collected from 20 stream sites in Oakland and Macomb Counties, Mich., were analyzed to learn more about the occurrence of cephalosporin-resistant Escherichia coli (E. coli) and vancomycin-resistant enterococci (VRE) and the co-occurrence of antibiotics and mercury in area streams. Fecal indicator bacteria concentrations exceeded the Michigan recreational water-quality standard of 300 E. coli colony forming units (CFU) per 100 milliliters of water in 19 of 35 stream-water samples collected in Oakland County. A gene commonly associated with enterococci from humans was detected in samples from Paint Creek at Rochester and Evans Ditch at Southfield, indicating that human fecal waste is a possible source of fecal contamination at these sites. E. coli resistant to the cephalosporin antibiotics (cefoxitin and/ or ceftriaxone) were found at all sites on at least one occasion. The highest percentages of E. coli isolates resistant to cefoxitin and ceftriaxone were 71 percent (Clinton River at Auburn Hills) and 19 percent (Sashabaw Creek near Drayton Plains), respectively. Cephalosporin-resistant E. coli was detected more frequently in samples from intensively urbanized or industrialized areas than in samples from less urbanized areas. VRE were not detected in any sample collected in this study. Multiple antibiotics (azithromycin, erythromycin, ofloxacin, sulfamethoxazole, and trimethoprim) were detected in water samples from the Clinton River at Auburn Hills, and tylosin (an antibiotic used in veterinary medicine and livestock production that belongs to the macrolide group, along with erythromycin) was detected in one water sample from Paint Creek at Rochester. Concentrations of total mercury were as high as 19.8 nanograms per liter (Evans Ditch at Southfield). There was no relation among percentage of antibiotic-resistant bacteria and measured concentrations of antibiotics or mercury in the water. Genetic elements capable of exchanging multiple antibiotic

  9. Real-time water quality monitoring and providing water quality ...

    EPA and the U.S. Geological Survey (USGS) have initiated the “Village Blue” research project to provide real-time water quality monitoring data to the Baltimore community and increase public awareness about local water quality in Baltimore Harbor and the Chesapeake Bay. The Village Blue demonstration project complements work that a number of state and local organizations are doing to make Baltimore Harbor “swimmable and fishable” 2 by 2020. Village Blue is designed to build upon EPA’s “Village Green” project which provides real-time air quality information to communities in six locations across the country. The presentation, “Real-time water quality monitoring and providing water quality information to the Baltimore Community”, summarizes the Village Blue real-time water quality monitoring project being developed for the Baltimore Harbor.

  10. Mercury content in wetland rice soil and water of two different seasons at small-scale gold mine processing areas

    T. Sugianti

    2016-04-01

    Full Text Available This study was aimed to identify the impact of small-scale gold processing activities on mercury content in wetland rice soil and water during the rainy and first dry seasons in Central Lombok and West Lombok Districts. The method used for this study was survey method. Measurement of mercury levels in water samples was conducted at Agro Bogor Centre using SNI 6989.77: 2011 methods. The data was collected and processed in a simple statistic presented descriptively, in order to obtain information. Results of the study showed that mercury content soils in the rainy season exceeded the threshold of 0.005 ppm, while in the first dry season the mercury content in soil decreased, but it was still above the threshold value permitted. The contents of mercury in water samples in the rainy season and the first dry season were still at a safe point that was less than 0.05 ppm. The wetland rice soil and water had been polluted with mercury, although the mercury content in the water was still below the threshold, but the accumulation of mercury that could have been absorbed by the plants are of particular concerns. The decrease of mercury content in soil in dry season was due to lack of gold processing activities.

  11. Ultrasensitive Quantum Dot Fluorescence quenching Assay for Selective Detection of Mercury Ions in Drinking Water

    Ke, Jun; Li, Xinyong; Zhao, Qidong; Hou, Yang; Chen, Junhong

    2014-07-01

    Mercury is one of the most acutely toxic substances at trace level to human health and living thing. Developing a rapid, cheap and water soluble metal sensor for detecting mercury ions at ppb level remains a challenge. Herein, a metal sensor consisting of MPA coated Mn doped ZnSe/ZnS colloidal nanoparticles was utilized to ultrasensitively and selectively detect Hg2+ ions with a low detection limit (0.1 nM) over a dynamic range from 0 to 20 nM. According to strong interaction between thiol(s) and mercury ions, mercaptopropionic acid (MPA) was used as a highly unique acceptor for mercury ions in the as-obtained ultrasensitive sensor. In the presence of mercury ions, colloidal nanoparticles rapidly agglomerated due to changes of surface chemical properties, which results in severe quenching of fluorescent intensity. Meanwhile, we find that the original ligands are separated from the surface of colloidal nanoparticles involving strongly chelation between mercury ion and thiol(s) proved by controlled IR analysis. The result shows that the QD-based metal ions sensor possesses satisfactory precision, high sensitivity and selectivity, and could be applied for the quantification analysis of real samples.

  12. Mercury analysis in hair: Comparability and quality assessment within the transnational COPHES/DEMOCOPHES project.

    Esteban, Marta; Schindler, Birgit Karin; Jiménez, José Antonio; Koch, Holger Martin; Angerer, Jürgen; Rosado, Montserrat; Gómez, Silvia; Casteleyn, Ludwine; Kolossa-Gehring, Marike; Becker, Kerstin; Bloemen, Louis; Schoeters, Greet; Den Hond, Elly; Sepai, Ovnair; Exley, Karen; Horvat, Milena; Knudsen, Lisbeth E; Joas, Anke; Joas, Reinhard; Aerts, Dominique; Biot, Pierre; Borošová, Daniela; Davidson, Fred; Dumitrascu, Irina; Fischer, Marc E; Grander, Margaretha; Janasik, Beata; Jones, Kate; Kašparová, Lucie; Larssen, Thorjørn; Naray, Miklos; Nielsen, Flemming; Hohenblum, Philipp; Pinto, Rui; Pirard, Catherine; Plateel, Gregory; Tratnik, Janja Snoj; Wittsiepe, Jürgen; Castaño, Argelia

    2015-08-01

    Human biomonitoring (HBM) is an effective tool for assessing actual exposure to chemicals that takes into account all routes of intake. Although hair analysis is considered to be an optimal biomarker for assessing mercury exposure, the lack of harmonization as regards sampling and analytical procedures has often limited the comparison of data at national and international level. The European-funded projects COPHES and DEMOCOPHES developed and tested a harmonized European approach to Human Biomonitoring in response to the European Environment and Health Action Plan. Herein we describe the quality assurance program (QAP) for assessing mercury levels in hair samples from more than 1800 mother-child pairs recruited in 17 European countries. To ensure the comparability of the results, standard operating procedures (SOPs) for sampling and for mercury analysis were drafted and distributed to participating laboratories. Training sessions were organized for field workers and four external quality-assessment exercises (ICI/EQUAS), followed by the corresponding web conferences, were organized between March 2011 and February 2012. ICI/EQUAS used native hair samples at two mercury concentration ranges (0.20-0.71 and 0.80-1.63) per exercise. The results revealed relative standard deviations of 7.87-13.55% and 4.04-11.31% for the low and high mercury concentration ranges, respectively. A total of 16 out of 18 participating laboratories the QAP requirements and were allowed to analyze samples from the DEMOCOPHES pilot study. Web conferences after each ICI/EQUAS revealed this to be a new and effective tool for improving analytical performance and increasing capacity building. The procedure developed and tested in COPHES/DEMOCOPHES would be optimal for application on a global scale as regards implementation of the Minamata Convention on Mercury. Copyright © 2014 Elsevier Inc. All rights reserved.

  13. Microbiological quality of natural waters.

    Borrego, J J; Figueras, M J

    1997-12-01

    Several aspects of the microbiological quality of natural waters, especially recreational waters, have been reviewed. The importance of the water as a vehicle and/or a reservoir of human pathogenic microorganisms is also discussed. In addition, the concepts, types and techniques of microbial indicator and index microorganisms are established. The most important differences between faecal streptococci and enterococci have been discussed, defining the concept and species included. In addition, we have revised the main alternative indicators used to measure the water quality.

  14. Got Mercury?

    Meyers, Valerie E.; McCoy, J. Torin; Garcia, Hector D.; James, John T.

    2009-01-01

    Many of the operational and payload lighting units used in various spacecraft contain elemental mercury. If these devices were damaged on-orbit, elemental mercury could be released into the cabin. Although there are plans to replace operational units with alternate light sources, such as LEDs, that do not contain mercury, mercury-containing lamps efficiently produce high quality illumination and may never be completely replaced on orbit. Therefore, exposure to elemental mercury during spaceflight will remain possible and represents a toxicological hazard. Elemental mercury is a liquid metal that vaporizes slowly at room temperature. However, it may be completely vaporized at the elevated operating temperatures of lamps. Although liquid mercury is not readily absorbed through the skin or digestive tract, mercury vapors are efficiently absorbed through the respiratory tract. Therefore, the amount of mercury in the vapor form must be estimated. For mercury releases from lamps that are not being operated, we utilized a study conducted by the New Jersey Department of Environmental Quality to calculate the amount of mercury vapor expected to form over a 2-week period. For longer missions and for mercury releases occurring when lamps are operating, we conservatively assumed complete volatilization of the available mercury. Because current spacecraft environmental control systems are unable to remove mercury vapors, both short-term and long-term exposures to mercury vapors are possible. Acute exposure to high concentrations of mercury vapors can cause irritation of the respiratory tract and behavioral symptoms, such as irritability and hyperactivity. Chronic exposure can result in damage to the nervous system (tremors, memory loss, insomnia, etc.) and kidneys (proteinurea). Therefore, the JSC Toxicology Group recommends that stringent safety controls and verifications (vibrational testing, etc.) be applied to any hardware that contains elemental mercury that could yield

  15. Total and methyl mercury concentrations in sediment and water of a constructed wetland in the Athabasca Oil Sands Region

    Oswald, Claire J.; Carey, Sean K.

    2016-01-01

    In the Athabasca Oil Sands Region in northeastern Alberta, Canada, oil sands operators are testing the feasibility of peatland construction on the post-mining landscape. In 2009, Syncrude Canada Ltd. began construction of the 52 ha Sandhill Fen pilot watershed, including a 15 ha, hydrologically managed fen peatland built on sand-capped soft oil sands tailings. An integral component of fen reclamation is post-construction monitoring of water quality, including salinity, fluvial carbon, and priority pollutant elements. In this study, the effects of fen reclamation and elevated sulfate levels on mercury (Hg) fate and transport in the constructed system were assessed. Total mercury (THg) and methylmercury (MeHg) concentrations in the fen sediment were lower than in two nearby natural fens, which may be due to the higher mineral content of the Sandhill Fen peat mix and/or a loss of Hg through evasion during the peat harvesting, stockpiling and placement processes. Porewater MeHg concentrations in the Sandhill Fen typically did not exceed 1.0 ng L −1 . The low MeHg concentrations may be a result of elevated porewater sulfate concentrations (mean 346 mg L −1 ) and an increase in sulphide concentrations with depth in the peat, which are known to suppress MeHg production. Total Hg and MeHg concentrations increased during a controlled mid-summer flooding event where the water table rose above the ground surface in most of the fen. The Hg dynamics during this event showed that hydrologic fluctuations in this system exacerbate the release of THg and MeHg downstream. In addition, the elevated SO 4 2− concentrations in the peat porewaters may become a problem with respect to downstream MeHg production once the fen is hydrologically connected to a larger wetland network that is currently being constructed. - Highlights: • A constructed fen peatland in the Athabasca Oil Sands Region was studied. • Total and methyl mercury concentrations in fen sediment and waters

  16. Extraction of gold and mercury from sea water with bismuth diethyldithiocarbamate prior to neutron activation-. gamma. -spectrometry

    Yu, J.C.; Lo, J.M.; Wai, C.M. (Idaho Univ. Moscow (USA). Dept. of Chemistry)

    1983-11-01

    Gold and mercury in sea water can be selectively extracted by bismuth diethyldithiocarbamate into chloroform at pH <= 1. The matrix species and many other trace elements in the system are effectively removed during extraction. When neutron activation-..gamma..-spectrometry is used, the detection limits for gold and mercury are 0.001 and 0.01 ..mu..g l/sup -1/, respectively. The relative precision is 9% for gold and 13% for mercury.

  17. A comparison of recent methods for modelling mercury fluxes at the air-water interface

    Fantozzi L.

    2013-04-01

    Full Text Available The atmospheric pathway of the global mercury flux is known to be the primary source of mercury contamination to most threatened aquatic ecosystems. Notwithstanding, the emission of mercury from surface water to the atmosphere is as much as 50% of total annual emissions of this metal into the atmosphere. In recent years, much effort has been made in theoretical and experimental researches to quantify the total mass flux of mercury to the atmosphere. In this study the most recent atmospheric modelling methods and the information obtained from them are presented and compared using experimental data collected during the Oceanographic Campaign Fenice 2011 (25 October – 8 November 2011, performed on board the Research Vessel (RV Urania of the CNR in the framework of the MEDOCEANOR ongoing program. A strategy for future numerical model development is proposed which is intended to gain a better knowledge of the long-term effects of meteo-climatic drivers on mercury evasional processes, and would provide key information on gaseous Hg exchange rates at the air-water interface.

  18. Controls on stream water dissolved mercury in three mid-Appalachian forested headwater catchments

    Riscassi, Ami L.; Scanlon, Todd M.

    2011-12-01

    Determining the controls on dissolved mercury (HgD) transport is necessary to improve estimations of export from unmonitored watersheds and to forecast responses to changes in deposition and other environmental forcings. Stream water HgD and dissolved organic carbon (DOC) were evaluated over a range of discharge conditions in three streams within Shenandoah National Park, VA. Watersheds are distinguished by stream water pH (ranging from neutral to acidic) and soil size fractioning (ranging from clays to sands). At all sites, discharge was a significant but poor predictor of HgD concentrations (r2 from 0.13-0.52). HgD was strongly coupled with DOC at all sites (r2 from 0.74-0.89). UV absorbance at 254 nm (UV254), a proxy for DOC quantity and quality, slightly improved the predictions of HgD. Mean DOC quality differed between streams, with less aromatic DOC mobilized from the more acidic watershed. The site with less aromatic DOC and sandy soils mobilized more Hg to the stream for the same quantity and quality of DOC, likely due to the reduced capacity of the larger-grained soils to retain Hg, leaving a greater fraction associated with the organic matter. A similar amount of 0.54 ng HgD/mg DOC is transported at all sites, suggesting the less aromatic DOC transports less Hg per unit DOC, offsetting the effects of soil type. This research demonstrates that soil composition and DOC quality influence HgDexport. We also provide evidence that soil organic carbon is a primary control on Hg-DOC ratios (0.12-1.4 ng mg-1) observed across the U.S. and Sweden.

  19. Spectrophotometric determination of mercury in water samples after preconcentration using dispersive liquid-liquid microextraction.

    Lemos, Valfredo Azevedo; dos Santos, Liz Oliveira; Silva, Eldevan dos Santos; Vieira, Emanuel Vitor dos Santos

    2012-01-01

    A simple method for the determination of mercury in water samples after preconcentration using dispersive liquid-liquid microextraction is described. The procedure is based on the extraction of mercury in the form of a complex and its subsequent determination by spectrophotometry. The complex is formed between Hg(II) and 2-(2-benzothiazolylazo)-p-cresol. The detection at 650 nm is performed directly in the metal-rich phase, which is spread on a triacetylcellulose membrane. The method eliminates the need to use a cuvet or large quantities of samples and reagents. The parameters that influence the preconcentration were studied, and the analytical characteristics were determined. The enrichment factor and the consumptive index for this method were 64 and 0.16 mL, respectively. The LOD (3.3 microg/L) and LOQ (11.1 microg/L) were also determined. The accuracy of the method was tested by the determination of mercury in certified reference materials BCR 397 (Human Hair) and SRM 2781 (Domestic Sludge). The method was applied to the determination of mercury in samples of drinking water, sea water, and river water.

  20. Whole-Cell Optical Biosensor for Mercury – Operational Conditions in Saline Water

    Solovyev, Andrey; Kuncová, Gabriela; Demnerová, K.

    2015-01-01

    Roč. 69, č. 1 (2015), s. 183-191 ISSN 0366-6352 R&D Projects: GA TA ČR TA03010544 Institutional support: RVO:67985858 Keywords : mercury detection assay * bioluminescent bioreporter * sea water Subject RIV: CA - Inorganic Chemistry Impact factor: 1.326, year: 2015

  1. Phytoremediation Of Mercury And Methylmercury Contaminated Sediments By Water Hyacinth (Eichhornia crassipes)

    Phytoremediation has potential to be implemented at mercury (Hg) and methylmercury (MeHg) contaminated sites. Water hyacinths (Eichhornia crassipes) were investigated for their ability to assimilate Hg and MeHg into plant biomass, in both aquatic and sediment-associated f...

  2. Fish Mercury and Surface Water Sulfate Relationships in the Everglades Protection Area

    Few published studies present data on relationships between fish mercury and surface or pore water sulfate concentrations, particularly on an ecosystem-wide basis. Resource managers can use these relationships to identify the sulfate conditions that contain fish with health-conce...

  3. Bench-Scale Investigation Of Mercury Phytoremediation By Water Hyacinths (Eichhornia crassipes) In Heavily Contaminated Sediments

    Phytoremediation has the potential to be implemented at mercury (Hg) and methylmercury (MeHg) contaminated sites. Water hyacinths (Eichhornia crassipes) were investigated for their ability to assimilate Hg and MeHg into plant biomass, in both aquatic and sediment-associat...

  4. Water Quality Monitoring by Satellite

    Journal of Chemical Education, 2004

    2004-01-01

    The availability of abundant water resources in the Upper Midwest of the United States is nullified by their contamination through heavy commercial and industrial activities. Scientists have taken the responsibility of detecting the water quality of these resources through remote-sensing satellites to develop a wide-ranging water purification plan…

  5. Ultrasensitive Quantum Dot Fluorescence quenching Assay for Selective Detection of Mercury Ions in Drinking Water

    Ke, Jun; Li, Xinyong; Zhao, Qidong; Hou, Yang; Chen, Junhong

    2014-01-01

    Mercury is one of the most acutely toxic substances at trace level to human health and living thing. Developing a rapid, cheap and water soluble metal sensor for detecting mercury ions at ppb level remains a challenge. Herein, a metal sensor consisting of MPA coated Mn doped ZnSe/ZnS colloidal nanoparticles was utilized to ultrasensitively and selectively detect Hg2+ ions with a low detection limit (0.1 nM) over a dynamic range from 0 to 20 nM. According to strong interaction between thiol(s)...

  6. Ratio of tritiated water and hydrogen generated in mercury through a nuclear reaction

    Manabe, K. [Nuclear Science and Engineering Directorate, Japan Atomic Energy Agency (JAEA), Tokai, Naka-gun, Ibaraki 319-1195 (Japan)], E-mail: manabe.kentaro@jaea.go.jp; Yokoyama, S. [Nuclear Science and Engineering Directorate, Japan Atomic Energy Agency (JAEA), Tokai, Naka-gun, Ibaraki 319-1195 (Japan)

    2008-02-15

    Tritium generated in a mercury target is a source of potential exposure of personnel at high-energy accelerator facilities. Knowledge of the chemical form of tritium is necessary to estimate the internal doses. We studied the tritium generation upon thermal neutron irradiation of a mercury target modified into liquid lithium amalgam to examine the ratio of tritiated water ([{sup 3}H]H{sub 2}O) and tritiated hydrogen ([{sup 3}H]H{sub 2}). The ratio between [{sup 3}H]H{sub 2}O and [{sup 3}H]H{sub 2} generated in lithium amalgam was 4:6 under these experimental conditions.

  7. Sulfonated Polyaniline Coated Mercury Film Electrodes for Voltammetric Analysis of Metals in Water

    Denise Alves Fungaro

    2001-11-01

    Full Text Available The electrochemical polymerization of 2-aminobenzenesulfonic acid with and without aniline has been carried by cyclic potencial sweep in sulfuric acid solution at the glassy carbon electrode. The polymer and copolymer formed have been characterized voltammetrically. The sulfonated polyaniline coated mercury thin-film electrodes have been evaluated for use with anodic stripping voltammetry. The electrodes were tested and compared with a conventional thin-film mercury electrode. Calibration plots showed linearity up to 10-7 mol L-1. Detection limits for zinc, lead and cadmium test species are very similar at around 12 nmol L-1. Applications to analysis of waters samples are demonstrated.

  8. What's in Your Water? An Educator's Guide to Water Quality.

    Constabile, Kerry, Comp.; Craig, Heidi, Comp.; O'Laughlin, Laura, Comp.; Reiss, Anne Bei, Comp.; Spencer, Liz, Comp.

    This guide provides basic information on the Clean Water Act, watersheds, and testing for water quality, and presents four science lesson plans on water quality. Activities include: (1) "Introduction to Water Quality"; (2) "Chemical Water Quality Testing"; (3) "Biological Water Quality Testing"; and (4) "What Can We Do?" (YDS)

  9. Total mercury in water and sediment from Honda Bay area in Palawan

    Kapauan, A.F.; Kapauan, P.A.; Tan, E.O.; Verceluz, F.P.

    1980-01-01

    This project is intended to pinpoint the sources of mercury contamination from the Honda Bay area in Palawan. Sampling sites were pinpointed which water and sediment samples were to be taken and kept in virgin polyethylene liter bottles. Analytical procedures were applied. The results of the analysis for total mercury content vary cosiderably from ml, less than 0.003 ng/9 to high of 0.419 ng/g with a considerable number of the sample going above the 0.100 ng/g level. Sediment samples also gave similar results, from a low of 0.004 ng/g to value higher than 2 ng/g round the jetty. It can be concluded, therefore, that the area surveyed is contaminated with mercury but not severely so. (author)

  10. Water Quality Monitoring Manual.

    Mason, Fred J.; Houdart, Joseph F.

    This manual is designed for students involved in environmental education programs dealing with water pollution problems. By establishing a network of Environmental Monitoring Stations within the educational system, four steps toward the prevention, control, and abatement of water pollution are proposed. (1) Train students to recognize, monitor,…

  11. Influence of Reservoir Water Level Fluctuations on Sediment Methylmercury Concentrations Downstream of the Historical Black Butte Mercury Mine, OR

    Mercury (Hg) is a pollutant of global concern due to its ability to accumulate as methylmercury (MeHg) in biota. Mercury is methylated by anaerobic microorganisms such as sulfate reducing bacteria (SRB) in water and sediment. Throughout North America, reservoirs tend to have e...

  12. Columbia River water quality monitoring

    Anon.

    1983-01-01

    Waste water from Hanford activities is discharged at eight points along the Hanford reach of the Columbia River. These discharges consist of backwash water from water intake screens, cooling water, river bank springs, water storage tank overflow, and fish laboratory waste water. Each discharge point is identified in an existing National Pollutant Discharge Elimination System (NPDES) permit issued by the EPA. Effluents from each of these outfalls are routinely monitored and reported by the operating contractors as required by their NPDES permits. Measurements of several Columbia River water quality parameters were conducted routinely during 1982 both upstream and downstream of the Hanford Site to monitor any effects on the river that may be attributable to Hanford discharges and to determine compliance with the Class A designation requirements. The measurements indicated that Hanford operations had a minimal, if any, impact on the quality of the Columbia River water

  13. Recent Approaches to Modeling Transport of Mercury in Surface Water and Groundwater - Case Study in Upper East Fork Poplar Creek, Oak Ridge, TN - 13349

    Bostick, Kent; Daniel, Anamary; Tachiev, Georgio; Malek-Mohammadi, Siamak

    2013-01-01

    In this case study, groundwater/surface water modeling was used to determine efficacy of stabilization in place with hydrologic isolation for remediation of mercury contaminated areas in the Upper East Fork Poplar Creek (UEFPC) Watershed in Oak Ridge, TN. The modeling simulates the potential for mercury in soil to contaminate groundwater above industrial use risk standards and to contribute to surface water contamination. The modeling approach is unique in that it couples watershed hydrology with the total mercury transport and provides a tool for analysis of changes in mercury load related to daily precipitation, evaporation, and runoff from storms. The model also allows for simulation of colloidal transport of total mercury in surface water. Previous models for the watershed only simulated average yearly conditions and dissolved concentrations that are not sufficient for predicting mercury flux under variable flow conditions that control colloidal transport of mercury in the watershed. The transport of mercury from groundwater to surface water from mercury sources identified from information in the Oak Ridge Environmental Information System was simulated using a watershed scale model calibrated to match observed daily creek flow, total suspended solids and mercury fluxes. Mercury sources at the former Building 81-10 area, where mercury was previously retorted, were modeled using a telescopic refined mesh with boundary conditions extracted from the watershed model. Modeling on a watershed scale indicated that only source excavation for soils/sediment in the vicinity of UEFPC had any effect on mercury flux in surface water. The simulations showed that colloidal transport contributed 85 percent of the total mercury flux leaving the UEFPC watershed under high flow conditions. Simulation of dissolved mercury transport from liquid elemental mercury and adsorbed sources in soil at former Building 81-10 indicated that dissolved concentrations are orders of magnitude

  14. Recent Approaches to Modeling Transport of Mercury in Surface Water and Groundwater - Case Study in Upper East Fork Poplar Creek, Oak Ridge, TN - 13349

    Bostick, Kent; Daniel, Anamary [Professional Project Services, Inc., Bethel Valley Road, Oak Ridge, TN, 37922 (United States); Tachiev, Georgio [Florida International University, Applied Research Center 10555 W. Flagler St., EC 2100 Miami Florida 33174 (United States); Malek-Mohammadi, Siamak [Bradley University, 413A Jobst Hall, Preoria, IL 61625 (United States)

    2013-07-01

    In this case study, groundwater/surface water modeling was used to determine efficacy of stabilization in place with hydrologic isolation for remediation of mercury contaminated areas in the Upper East Fork Poplar Creek (UEFPC) Watershed in Oak Ridge, TN. The modeling simulates the potential for mercury in soil to contaminate groundwater above industrial use risk standards and to contribute to surface water contamination. The modeling approach is unique in that it couples watershed hydrology with the total mercury transport and provides a tool for analysis of changes in mercury load related to daily precipitation, evaporation, and runoff from storms. The model also allows for simulation of colloidal transport of total mercury in surface water. Previous models for the watershed only simulated average yearly conditions and dissolved concentrations that are not sufficient for predicting mercury flux under variable flow conditions that control colloidal transport of mercury in the watershed. The transport of mercury from groundwater to surface water from mercury sources identified from information in the Oak Ridge Environmental Information System was simulated using a watershed scale model calibrated to match observed daily creek flow, total suspended solids and mercury fluxes. Mercury sources at the former Building 81-10 area, where mercury was previously retorted, were modeled using a telescopic refined mesh with boundary conditions extracted from the watershed model. Modeling on a watershed scale indicated that only source excavation for soils/sediment in the vicinity of UEFPC had any effect on mercury flux in surface water. The simulations showed that colloidal transport contributed 85 percent of the total mercury flux leaving the UEFPC watershed under high flow conditions. Simulation of dissolved mercury transport from liquid elemental mercury and adsorbed sources in soil at former Building 81-10 indicated that dissolved concentrations are orders of magnitude

  15. Mercury concentration in vegetables of Pakistan irrigated by different water sources

    Shaheen, Q.; Mahmood, Z.; Imran, M.

    2011-01-01

    Mercury levels were determined in twenty samples of each vegetable i.e., Spinach (Spinacia oleracea), Lettuce (Lactuca sativa), Carrot (Daucus cariota), Capsicum (Capsicum fistulosus), Sweet pea (Lathyrus Odoratus), Potato (Solanum tuberosum) and Cabbage (Brassica oleracea), with a special reference of source of water of irrigation, i.e., tube well water, canal water and municipal sewage water. All the samples of vegetables were collected during the year 2006, 2007 and 2008 from the five districts of Pakistan viz Lahore, Kasur, Multan, Bahawalpur and R.Y. Khan. Statistical analysis such as Test of significance and multiple comparison were applied on the data obtained. The results showed that the concentration of Mercury in vegetables irrigated by canal water, sewage water and tube well water was in the range of 3.1-88.9 ppb and 9.0-130.6 ppb. It can be concluded from this study that the uptake of mercury by vegetables collected from above five districts of Pakistan was in the following order. Leafy vegetables > Root vegetables > seedy vegetables. (author)

  16. Mercury removal from water streams through the ion exchange membrane bioreactor concept.

    Oehmen, Adrian; Vergel, Dario; Fradinho, Joana; Reis, Maria A M; Crespo, João G; Velizarov, Svetlozar

    2014-01-15

    Mercury is a highly toxic heavy metal that causes human health problems and environmental contamination. In this study, an ion exchange membrane bioreactor (IEMB) process was developed to achieve Hg(II) removal from drinking water and industrial effluents. Hg(II) transport through a cation exchange membrane was coupled with its bioreduction to Hg(0) in order to achieve Hg removal from concentrated streams, with minimal production of contaminated by-products observed. This study involves (1) membrane selection, (2) demonstration of process effectiveness for removing Hg from drinking water to below the 1ppb recommended limit, and (3) process application for treatment of concentrated water streams, where >98% of the Hg was removed, and the throughput of contaminated water was optimised through membrane pre-treatment. The IEMB process represents a novel mercury treatment technology with minimal generation of contaminated waste, thereby reducing the overall environmental impact of the process. Copyright © 2013 Elsevier B.V. All rights reserved.

  17. Surface water quality assessment using factor analysis

    2006-01-16

    Jan 16, 2006 ... Surface water, groundwater quality assessment and environ- .... Urbanisation influences the water cycle through changes in flow and water ..... tion of aquatic life, CCME water quality Index 1, 0. User`s ... Water, Air Soil Pollut.

  18. [Drinking water quality and safety].

    Gómez-Gutiérrez, Anna; Miralles, Maria Josepa; Corbella, Irene; García, Soledad; Navarro, Sonia; Llebaria, Xavier

    2016-11-01

    The purpose of drinking water legislation is to guarantee the quality and safety of water intended for human consumption. In the European Union, Directive 98/83/EC updated the essential and binding quality criteria and standards, incorporated into Spanish national legislation by Royal Decree 140/2003. This article reviews the main characteristics of the aforementioned drinking water legislation and its impact on the improvement of water quality against empirical data from Catalonia. Analytical data reported in the Spanish national information system (SINAC) indicate that water quality in Catalonia has improved in recent years (from 88% of analytical reports in 2004 finding drinking water to be suitable for human consumption, compared to 95% in 2014). The improvement is fundamentally attributed to parameters concerning the organoleptic characteristics of water and parameters related to the monitoring of the drinking water treatment process. Two management experiences concerning compliance with quality standards for trihalomethanes and lead in Barcelona's water supply are also discussed. Finally, this paper presents some challenges that, in the opinion of the authors, still need to be incorporated into drinking water legislation. It is necessary to update Annex I of Directive 98/83/EC to integrate current scientific knowledge, as well as to improve consumer access to water quality data. Furthermore, a need to define common criteria for some non-resolved topics, such as products and materials in contact with drinking water and domestic conditioning equipment, has also been identified. Copyright © 2016 SESPAS. Publicado por Elsevier España, S.L.U. All rights reserved.

  19. Ground Water Quality

    The results showed that Na and K were the most abundant dissolved cations in the groundwater. The. + .... concentration of phosphate (PO ) in the water. 4 samples was ...... The Effect of Copper on Some Laboratory Indices of Clarias.

  20. Mercury Inhibits Soil Enzyme Activity in a Lower Concentration than the Guideline Value.

    Mahbub, Khandaker Rayhan; Krishnan, Kannan; Megharaj, Mallavarapu; Naidu, Ravi

    2016-01-01

    Three soil types - neutral, alkaline and acidic were experimentally contaminated with nine different concentrations of inorganic mercury (0, 5, 10, 50, 100, 150, 200, 250, 300 mg/kg) to derive effective concentrations of mercury that exert toxicity on soil quality. Bioavailability of mercury in terms of water solubility was lower in acidic soil with higher organic carbon. Dehydrogenase enzyme activity and nitrification rate were chosen as indicators to assess soil quality. Inorganic mercury significantly inhibited (p mercury contents (EC10) were found to be less than the available safe limits for inorganic mercury which demonstrated inadequacy of existing guideline values.

  1. Total mercury concentrations in surface water and sediments from Danube Delta lakes

    TEODOROF Liliana

    2007-10-01

    Full Text Available The samples were collected from surface water and sediments of Danube Delta lakes, during april and may 2006. The sediments were digested with nitric acid, and the surface water with real aqua, at Microwave Oven Anton Paar and analised at FIMS 400 Perkin Elmer. The results show that the total mercury is compared with the maximum allowed limits according with Normative 161/2006.

  2. 43 CFR 414.5 - Water quality.

    2010-10-01

    ... 43 Public Lands: Interior 1 2010-10-01 2010-10-01 false Water quality. 414.5 Section 414.5 Public... APPORTIONMENT IN THE LOWER DIVISION STATES Water Quality and Environmental Compliance § 414.5 Water quality. (a) Water Quality is not guaranteed. The Secretary does not warrant the quality of water released or...

  3. 5 Water Quality.cdr

    Administrator

    The water quality assessment conducted in the Densu, Birim and Ayensu Basins of Ghana in the Okyeman area ... All the mean nutrient values for Densu, Birim and Ayensu were not significantly .... variability in the composition of the river.

  4. Water Consumption as Source of Arsenic, Chromium, and Mercury in Children Living in Rural Yucatan, Mexico: Blood and Urine Levels.

    Arcega-Cabrera, F; Fargher, L F; Oceguera-Vargas, I; Noreña-Barroso, E; Yánez-Estrada, L; Alvarado, J; González, L; Moo-Puc, R; Pérez-Herrera, N; Quesadas-Rojas, M; Pérez-Medina, S

    2017-10-01

    Studies investigating the correlation between metal content in water and metal levels in children are scarce worldwide, but especially in developing nations. Therefore, this study investigates the correlation between arsenic, chromium, and mercury concentrations in drinking and cooking water and in blood and urine samples collected from healthy and supposedly non-exposed children from a rural area in Yucatan, Mexico. Mercury in water shows concentrations above the recommended World Health Organization (WHO) value for drinking and cooking water. Also, 25% of the children show mercury in urine above the WHO recommended value. Multivariate analyses show a significant role for drinking and cooking water as a vector of exposure in children. Also, the factor analysis shows chronic exposure in the case of arsenic, as well as an ongoing detoxification process through urine in the case of mercury. Further studies should be done in order to determine other potential metal exposure pathways among children.

  5. Water quality. Pt. 3

    1993-01-01

    This International Standard specifies a method for the determination of gross alpha activity in non-saline waters for alpha-emitting radionuclides which are not volatile at 350 o C. It is possible to determine supported volatile radionuclides measured to an extent determined by half-life, matrix retention (of the volatile species) and the duration of measurement (counting time). The method is applicable to raw and potable waters and can be extended to saline or mineralized waters, but with a reduced sensitivity. The range of application depends on the amount of inorganic material in the water and on the performance characteristics (background count rate and counting efficiency) of the counter. The sample is acidified to stabilize it, evaporated almost to dryness, converted to the sulfate form and then ignited at 350 o C. A portion of the residue is transferred to a planchette and the alpha activity measured by counting in an alpha-particle detector or counting system previously calibrated against an alpha-emitting standard. (author)

  6. Mercury and trace element contents of Donbas coals and associated mine water in the vicinity of Donetsk, Ukraine

    Kolker, A.; Panov, B.S.; Panov, Y.B.; Landa, E.R.; Conko, K.M.; Korchemagin, V.A.; Shendrik, T.; McCord, J.D.

    2009-01-01

    Mercury-rich coals in the Donets Basin (Donbas region) of Ukraine were sampled in active underground mines to assess the levels of potentially harmful elements and the potential for dispersion of metals through use of this coal. For 29 samples representing c11 to m3 Carboniferous coals, mercury contents range from 0.02 to 3.5 ppm (whole-coal dry basis). Mercury is well correlated with pyritic sulfur (0.01 to 3.2 wt.%), with an r2 of 0.614 (one outlier excluded). Sulfides in these samples show enrichment of minor constituents in late-stage pyrite formed as a result of interaction of coal with hydrothermal fluids. Mine water sampled at depth and at surface collection points does not show enrichment of trace metals at harmful levels, indicating pyrite stability at subsurface conditions. Four samples of coal exposed in the defunct open-cast Nikitovka mercury mines in Gorlovka have extreme mercury contents of 12.8 to 25.5 ppm. This coal was formerly produced as a byproduct of extracting sandstone-hosted cinnabar ore. Access to these workings is unrestricted and small amounts of extreme mercury-rich coal are collected for domestic use, posing a limited human health hazard. More widespread hazards are posed by the abandoned Nikitovka mercury processing plant, the extensive mercury mine tailings, and mercury enrichment of soils extending into residential areas of Gorlovka.

  7. Removal of heavy metals from water by zeolite mineral chemically modified. Mercury as a particular case

    Gebremedhin H, T.

    2002-01-01

    Research works on the removal of mercury from water by zeolite minerals show that a small quantity of this element is sorbed. In this work the mercury sorption from aqueous solutions in the presence and absence of Cu(l l), Ni(l l) and/or Zn(l l) by a Mexican zeolite mineral, natural and modified by cisteaminium chloride or cistaminium dichloride, was investigated in acidic p H. The zeolite minerals were characterized by X- Ray diffraction Ftir, scanning electron microscopy and semiquantitative elemental analysis (EDS), surface area analysis (BET) and thermogravimetric analysis (TGA). Mercury from aqueous solutions was quantified by Atomic absorption spectroscopy. The amount of sulphur on the zeolite samples treated with Na CI and modified with cisteaminium chloride (0.375 mmol/g) or cistaminium dichloride(0.475 mmol/g) was found to be higher than that of the zeolite minerals modified with cisteaminium chloride and cistaminium dichloride without treating them with Na CI. The amount of sulphur on the zeolite minerals modified with thiourea was the lowest. The diffusion coefficients and sorption isotherms for mercury were determined in the natural, treated with Na CI and, treated with Na CI and then modified with the cisteaminium chloride or cistaminium dichloride zeolite samples. The retention of mercury was the highest for the zeolite minerals treated Na CI and then modified with cisteaminium chloride or cistaminium dichloride, with adsorption capacity of 0.0511 and 0.0525 mmol Hg/g, respectively. In this research work, it was found that the retention of mercury by the modified minerals was not affected by the presence of Cu (Il), Zn(l l) y Ni (I l) under the experimental conditions. (Author)

  8. Geochemical characterization of water, sediment, and biota affected by mercury contamination and acidic drainage from historical gold mining, Greenhorn Creek, Nevada County, California, 1999-2001

    Alpers, Charles N.; Hunerlach, Michael P.; May, Jason T.; Hothem, Roger L.; Taylor, Howard E.; Antweiler, Ronald C.; De Wild, John F.; Lawler, David A.

    2005-01-01

    In 1999, the U.S. Geological Survey (USGS) initiated studies of mercury and methylmercury occurrence, transformation, and transport in the Bear River and Yuba River watersheds of the northwestern Sierra Nevada. Because these watersheds were affected by large-scale, historical gold extraction using mercury amalgamation beginning in the 1850s, they were selected for a pilot study of mercury transport by the USGS and other cooperating agencies. This report presents data on methylmercury (MeHg) and total mercury (THg) concentrations in water, bed sediment, invertebrates, and frogs collected at 40 stations during 1999-2001 in the Greenhorn Creek drainage, a major tributary to Bear River. Results document several mercury contamination ?hot spots? that represent potential targets for ongoing and future remediation efforts at abandoned mine sites in the study area. Water-quality samples were collected one or more times at each of 29 stations. The concentrations of total mercury in 45 unfiltered water samples ranged from 0.80 to 153,000 nanograms per liter (ng/L); the median was 9.6 ng/L. Total mercury concentrations in filtered water (41 samples) ranged from less than 0.3 to 8,000 ng/L; the median was 2.7 ng/L. Concentrations of methylmercury in the unfiltered water (40 samples) ranged from less than 0.04 to 9.1 ng/L; the median was 0.07 ng/L. Methylmercury in filtered water (13 samples) ranged from less than 0.04 to 0.27 ng/L; the median was 0.04 ng/L. Acidic drainage with pH values as low as 3.4 was encountered in some of the mined areas. Elevated concentrations of aluminum, cadmium, copper, iron, manganese, nickel, and zinc were found at several stations, especially in the more acidic water samples. Total mercury concentrations in sediment were determined by laboratory and field methods. Total mercury concentrations (determined by laboratory methods) in ten samples from eight stations ranged from about 0.0044 to 12 ?g/g (microgram per gram, equivalent to parts per

  9. JV Task 94 - Air Quality V: Mercury, Trace Elements, SO3, and Particulate Matter Conference

    Thomas A. Erickson

    2007-01-31

    This final report summarizes the planning, preparation, facilitation and production, and summary of the conference entitled 'Air Quality V: Mercury, Trace Elements, SO{sub 3}, and Particulate Matter,' held September 18-21, 2005, in Arlington, Virginia. The goal of the conference was to build on the discussions of the first four Air Quality Conferences, providing further opportunity for leading representatives of industry, government, research institutions, academia, and environmental organizations to discuss the key interrelationships between policy and science shaping near-term regulations and controls and to assist in moving forward on emerging issues that will lead to acceptable programs and policies to protect human health, the environment, and economic growth. The conference was extremely timely, as it was the last large conference prior to publication of the U.S. Environmental Protection Agency's final regulations for mercury control from coal-fired utilities, and provided a forum to realistically assess the status of mercury controls in relation to the new regulations.

  10. Water quality criteria for lead

    Nagpal, N.K.

    1987-01-01

    This report is one in a series that establishes water quality criteria for British Columbia. The report sets criteria for lead to protect a number of water uses, including drinking water, freshwater and marine aquatic life, wildlife, livestock, irrigation, and recreation. The criteria are set as either maximum concentrations of total lead that should not be exceeded at any time, or average concentrations that should not be exceeded over a 30-day period. Actual values are summarized.

  11. Optical sensors for water quality

    Pellerin, Brian A.; Bergamaschi, Brian A.

    2014-01-01

    Shifts in land use, population, and climate have altered hydrologic systems in the United States in ways that affect water quality and ecosystem function. Water diversions, detention in reservoirs, increased channelization, and changes in rainfall and snowmelt are major causes, but there are also more subtle causes such as changes in soil temperature, atmospheric deposition, and shifting vegetation patterns. The effects on water quality are complex and interconnected, and occur at timeframes of minutes (e.g., flash floods) to decades (e.g., evolving management practices).

  12. Determination of trace mercury in water based on N-octylpyridinium ionic liquids preconcentration and stripping voltammetry.

    Li, Zhenhan; Xia, Shanhong; Wang, Jinfen; Bian, Chao; Tong, Jianhua

    2016-01-15

    A novel method for determination of trace mercury in water is developed. The method is performed by extracting mercury firstly with ionic liquids (ILs) and then detecting the concentration of mercury in organic media with anodic stripping voltammetry. Liquid-liquid extraction of mercury(II) ions by four ionic liquids with N-octylpyridinium cations ([OPy](+)) was studied. N-octylpyridinium tetrafluoroborate and N-octylpyridinium trifluoromethylsulfonate were found to be efficient and selective extractant for mercury. Temperature controlled dispersive liquid phase microextraction (TC-DLPME) technique was utilized to improve the performance of preconcentration. After extraction, precipitated IL was diluted by acetonitrile buffer and mercury was detected by differential pulse stripping voltammetry (DPSV) with gold disc electrode. Mercury was enriched by 17 times while interfering ions were reduced by two orders of magnitude in the organic media under optimum condition. Sensitivity and selectivity for electrochemical determination of mercury were improved by using the proposed method. Tap, pond and waste water samples were analyzed with recoveries ranging from 81% to 107% and detection limit of 0.05 μg/L. Copyright © 2015 Elsevier B.V. All rights reserved.

  13. Phytoremediation of Mercury- and Methyl Mercury-Contaminated Sediments by Water Hyacinth (Eichhornia crassipes)

    Phytoremediation has the potential for implementation at Hg- (Hg) and methylHg (MeHg)-contaminated sites. Water hyacinths (Eichhornia crassipes) were investigated for their ability to assimilate Hg and MeHg into plant biomass, in both aquatic and sediment-associated forms...

  14. Impact of oxy-fuel combustion gases on mercury retention in activated carbons from a macroalgae waste: effect of water.

    Lopez-Anton, M A; Ferrera-Lorenzo, N; Fuente, E; Díaz-Somoano, M; Suarez-Ruíz, I; Martínez-Tarazona, M R; Ruiz, B

    2015-04-01

    The aim of this study is to understand the different sorption behaviors of mercury species on activated carbons in the oxy-fuel combustion of coal and the effect of high quantities of water vapor on the retention process. The work evaluates the interactions between the mercury species and a series of activated carbons prepared from a macroalgae waste (algae meal) from the agar-agar industry in oxy-combustion atmospheres, focussing on the role that the high concentration of water in the flue gases plays in mercury retention. Two novel aspects are considered in this work (i) the impact of oxy-combustion gases on the retention of mercury by activated carbons and (ii) the performance of activated carbons prepared from biomass algae wastes for this application. The results obtained at laboratory scale indicate that the effect of the chemical and textural characteristics of the activated carbons on mercury capture is not as important as that of reactive gases, such as the SOx and water vapor present in the flue gas. Mercury retention was found to be much lower in the oxy-combustion atmosphere than in the O2+N2 (12.6% O2) atmosphere. However, the oxidation of elemental mercury (Hg0) to form oxidized mercury (Hg2+) amounted to 60%, resulting in an enhancement of mercury retention in the flue gas desulfurization units and a reduction in the amalgamation of Hg0 in the CO2 compression unit. This result is of considerable importance for the development of technologies based on activated carbon sorbents for mercury control in oxy-combustion processes. Copyright © 2015 Elsevier Ltd. All rights reserved.

  15. Analytical quality control in studies of environmental exposure to mercury

    Byrne, A.R.; Prosenc, N.; Smerke, J.; Horvat, M.

    1995-01-01

    The work of the laboratory for quality control in this co-ordinated project for the period from November 1993 to June 1994 is presented. The major effort was devoted to assisting in establishing the homogeneity and total methylmercury levels in two new hair reference materials prepared as control materials for the project, numbered 085 (spiked) and 086 (natural level). Results for some hair materials from participants are also given. (author)

  16. Water Quality Analysis Simulation Program (WASP)

    The Water Quality Analysis Simulation Program (WASP) model helps users interpret and predict water quality responses to natural phenomena and manmade pollution for various pollution management decisions.

  17. Mercury concentrations in water, and mercury and selenium concentrations in fish from Brownlee Reservoir and selected sites in Boise and Snake Rivers, Idaho and Oregon, 2013

    MacCoy, Dorene E.

    2014-01-01

    Mercury (Hg) analyses were conducted on samples of sport fish and water collected from six sampling sites in the Boise and Snake Rivers, and Brownlee Reservoir to meet National Pollution Discharge and Elimination System (NPDES) permit requirements for the City of Boise, Idaho. A water sample was collected from each site during October and November 2013 by the City of Boise personnel and was analyzed by the Boise City Public Works Water Quality Laboratory. Total Hg concentrations in unfiltered water samples ranged from 0.73 to 1.21 nanograms per liter (ng/L) at five river sites; total Hg concentration was highest (8.78 ng/L) in a water sample from Brownlee Reservoir. All Hg concentrations in water samples were less than the EPA Hg chronic aquatic life criterion in Idaho (12 ng/L). The EPA recommended a water-quality criterion of 0.30 milligrams per kilogram (mg/kg) methylmercury (MeHg) expressed as a fish-tissue residue value (wet-weight MeHg in fish tissue). MeHg residue in fish tissue is considered to be equivalent to total Hg in fish muscle tissue and is referred to as Hg in this report. The Idaho Department of Environmental Quality adopted the EPA’s fish-tissue criterion and a reasonable potential to exceed (RPTE) threshold 20 percent lower than the criterion or greater than 0.24 mg/kg based on an average concentration of 10 fish from a receiving waterbody. NPDES permitted discharge to waters with fish having Hg concentrations exceeding 0.24 mg/kg are said to have a reasonable potential to exceed the water-quality criterion and thus are subject to additional permit obligations, such as requirements for increased monitoring and the development of a Hg minimization plan. The Idaho Fish Consumption Advisory Program (IFCAP) issues fish advisories to protect general and sensitive populations of fish consumers and has developed an action level of 0.22 mg/kg wet weight Hg in fish tissue. Fish consumption advisories are water body- and species-specific and are used to

  18. Assessing Mercury and Methylmercury Bioavailability in Sediment Pore Water Using Mercury-Specific Hydrogels

    2015-06-01

    area ferric (Fe(III)) hydroxide that can remove porewater solutes (Kristensen 2001). Bioirrigation may also promote MeHg efflux to the overlying water...sparger Gold trap Electronic flow meter Zip-top bags Styrofoam shipping container Procedure 1. Prior to sediment deployment, deoxygenate...nitrogen tank, regulator, gold trap, sparger, multi-tube flow meter, deoxygenation vessels. b. Deoxygenation vessels should be set up in series (2 vessels

  19. Phyto-toxicity and Phyto-remediation Potential of Mercury in Indian Mustard and Two Ferns with Mercury Contaminated Water and Oak Ridge Soil

    Su, Y.; Han, F.X.; Chen, J.; Shiyab, S.; Monts, D.L.; Monts, D.L.

    2009-01-01

    Phyto-remediation is an emerging technology that uses various plants to degrade, extract, contain, or immobilize contaminants from soil and water. Certain fern and Indian mustard species have been suggested as candidates for phyto-remediation of heavy metal-contaminated soil and water because of their high efficiency of accumulating metals in shoots and their high biomass production. Currently, no known hyper-accumulator plants for mercury have been found. Here we report the Hg uptake and phyto-toxicity by two varieties of fern and Indian mustard. Their potential for Hg phyto-remediation application was also investigated. Anatomical, histochemical and biochemical approaches were used to study mercury phyto-toxicity as well as anti-oxidative responses in ferns [Chinese brake fern (P. vittata) and Boston fern (N. exaltata)] and Indian mustard (Florida broadleaf and longstanding) (Brassica juncea L.) grown in a hydroponic system. Phyto-remediation potentials of these plant species were estimated based on their Hg uptake performance with contaminated soils from Oak Ridge (TN, USA). Our results show that mercury exposure led to severe phyto-toxicity accompanied by lipid peroxidation and rapid accumulation of hydrogen peroxide (H 2 O 2 ) in P. vittata, but not in N. exaltata. The two cultivars of fern responded differently to mercury exposure in terms of anti-oxidative enzymes (superoxide dismutase, SOD; catalase, CAT; peroxidase, POD; glutathione reductase, GR). Mercury exposure resulted in the accumulation of ascorbic acid (ASA) and glutathione (GSH) in the shoots of both cultivars of fern. On the other hand, Indian mustard effectively generated an enzymatic antioxidant defense system (especially CAT) to scavenge H 2 O 2 , resulting in lower H 2 O 2 in shoots with higher mercury concentrations. These two cultivars of Indian mustard demonstrated an efficient metabolic defense and adaptation system to mercury-induced oxidative stress. In both varieties of fern and Indian

  20. Mercury, monomethyl mercury, and dissolved organic carbon concentrations in surface water entering and exiting constructed wetlands treated with metal-based coagulants, Twitchell Island, California

    Stumpner, Elizabeth B.; Kraus, Tamara E.C.; Fleck, Jacob A.; Hansen, Angela M.; Bachand, Sandra M.; Horwath, William R.; DeWild, John F.; Krabbenhoft, David P.; Bachand, Philip A.M.

    2015-09-02

    Coagulation with metal-based salts is a practice commonly employed by drinking-water utilities to decrease particle and dissolved organic carbon concentrations in water. In addition to decreasing dissolved organic carbon concentrations, the effectiveness of iron- and aluminum-based coagulants for decreasing dissolved concentrations both of inorganic and monomethyl mercury in water was demonstrated in laboratory studies that used agricultural drainage water from the Sacramento–San Joaquin Delta of California. To test the effectiveness of this approach at the field scale, nine 15-by-40‑meter wetland cells were constructed on Twitchell Island that received untreated water from island drainage canals (control) or drainage water treated with polyaluminum chloride or ferric sulfate coagulants. Surface-water samples were collected approximately monthly during November 2012–September 2013 from the inlets and outlets of the wetland cells and then analyzed by the U.S. Geological Survey for total concentrations of mercury and monomethyl mercury in filtered (less than 0.3 micrometers) and suspended-particulate fractions and for concentrations of dissolved organic carbon.

  1. Mercury (Environmental Health Student Portal)

    ... in contact with) to mercury is by eating fish or shellfish that have high levels of mercury. You can also get sick from: Touching it Breathing it in Drinking contaminated water How can mercury ...

  2. Novel methodology for the study of mercury methylation and reduction in sediments and water using 197Hg radiotracer

    Ribeiro Guevara, Sergio; Perez Catan, Soledad; Zizek, Suzana; Repinc, Urska; Jacimovic, Radojko; Horvat, Milena

    2007-01-01

    Mercury tracers are powerful tools that can be used to study mercury transformations in environmental systems, particularly mercury methylation, demethylation and reduction in sediments and water. However, mercury transformation studies using tracers can be subject to error, especially when used to assess methylation potential. The organic mercury extracted can be as low as 0.01% of the endogenous labeled mercury, and artefacts and contamination present during methylmercury (MeHg) extraction processes can cause interference. Solvent extraction methods based on the use of either KBr/H 2 SO 4 or HCl were evaluated in freshwater sediments using 197 Hg radiotracer. Values obtained for the 197 Hg tracer in the organic phase were up to 25-fold higher when HCl was used, which is due to the coextraction of 197 Hg 2+ into the organic phase during MeHg extraction. Evaluations of the production of MeHg gave similar results with both MeHg extraction procedures, but due to the higher Hg 2+ contamination of the controls, the uncertainty in the determination was higher when HCl was used. The Hg 2+ contamination of controls in the HCl extraction method showed a nonlinear correlation with the humic acid content of sediment pore water. Therefore, use of the KBr/H 2 SO 4 method is recommended, since it is free from these interferences. 197 Hg radiotracer (T 1/2 = 2.673 d) has a production rate that is about 50 times higher than that of 203 Hg (T 1/2 46.595 d), the most frequently used mercury radiotracer. Hence it is possible to obtain a similar level of performance to 203 Hg when it is used it in short-term experiments and produced by the irradiation of 196 Hg with thermal neutrons, using mercury targets with the natural isotopic composition. However, if the 0.15% natural abundance of the 196 Hg isotope is increased, the specific activity of the 197 Hg tracer can be significantly improved. In the present work, 197 Hg tracer was produced from mercury 51.58% enriched in the 196 Hg

  3. Part 2: Surface water quality

    1997-01-01

    In 1996 the surface water quality measurements were performed, according to the Agreement, at 8 profiles on the Hungarian territory and at 15 profiles on the Slovak territory. Basic physical and chemical parameters (as water temperature, pH values, conductivity, suspended solids, cations and anions (nitrates, ammonium ion, nitrites, total nitrogen, phosphates, total phosphorus, oxygen and organic carbon regime parameters), metals (iron, manganese and heavy metals), biological and microbiological parameters (coliform bacteria, chlorophyll-a, saprobity index and other biological parameters) and quality of sediment were measured

  4. Integrated Urban Water Quality Management

    Rauch, W.; Harremoës, Poul

    1995-01-01

    The basic features of integrated urban water quality management by means of deterministic modeling are outlined. Procedures for the assessment of the detrimental effects in the recipient are presented as well as the basic concepts of an integrated model. The analysis of a synthetic urban drainage...... system provides useful information for water quality management. It is possible to identify the system parameters that contain engineering significance. Continuous simulation of the system performance indicates that the combined nitrogen loading is dominated by the wastewater treatment plant during dry...

  5. New Mechanisms of Mercury Binding to Peat

    Nagy, K. L.; Manceau, A.; Gasper, J. D.; Ryan, J. N.; Aiken, G. R.

    2007-12-01

    Mercury can be immobilized in the aquatic environment by binding to peat, a solid form of natural organic matter. Binding mechanisms can vary in strength and reversibility, and therefore will control concentrations of bioreactive mercury, may explain rates of mercury methylation, and are important for designing approaches to improve water quality using natural wetlands or engineered phytoremediation schemes. In addition, strong binding between mercury and peat is likely to result in the fixation of mercury that ultimately resides in coal. The mechanisms by which aqueous mercury at low concentrations reacts with both dissolved and solid natural organic matter remain incompletely understood, despite recent efforts. We have identified three distinct binding mechanisms of divalent cationic mercury to solid peats from the Florida Everglades using EXAFS spectroscopic data (FAME beamline, European Synchrotron Radiation Facility (ESRF)) obtained on experimental samples as compared to relevant references including mercury-bearing solids and mercury bound to various organic molecules. The proportions of the three molecular configurations vary with Hg concentration, and two new configurations that involve sulfur ligands occur at Hg concentrations up to about 4000 ppm. The binding mechanism at the lowest experimental Hg concentration (60-80 ppm) elucidates published reports on the inhibition of metacinnabar formation in the presence of Hg-bearing solutions and dissolved natural organic matter, and also, the differences in extent of mercury methylation in distinct areas of the Florida Everglades.

  6. Water quality index for assessment of water quality of river ravi at ...

    Water quality of River Ravi, a tributary of Indus River System was evaluated by Water Quality Index (WQI) technique. A water quality index provides a single number that expresses overall water quality at a certain location and time based on several water quality parameters. The objective of an index is to turn complex water ...

  7. Solid Wastes and Water Quality.

    DeWalle, F. B.; Chian, E. S. K.

    1978-01-01

    Presents a literature review of solid wastes and water quality, covering publications of 1976-77. This review covers areas such as: (1) environmental impacts and health aspects for waste disposal, and (2) processed and hazardous wastes. A list of 80 references is also presented. (HM)

  8. 18 CFR 801.7 - Water quality.

    2010-04-01

    ... 18 Conservation of Power and Water Resources 2 2010-04-01 2010-04-01 false Water quality. 801.7... POLICIES § 801.7 Water quality. (a) The signatory States have the primary responsibility in the basin for water quality management and control. However, protection of the water resources of the basin from...

  9. Estimated quantity of mercury in amalgam waste water residue released by dentists into the sewerage system in Ontario, Canada.

    Adegbembo, Albert O; Watson, Philip A

    2004-12-01

    To estimate the quantity of dental amalgam that Ontario dentists release into waste water. Information from a self-administered postal survey of Ontario dentists was combined with the results of other experiments on the weight of amalgam restorations and the quantity of amalgam waste that bypasses solids separators in dental offices. Algorithms were developed to compute the quantity of amalgam waste leaving dental offices when dentists used or did not use ISO 11143 amalgam particle separators. A total of 878 (44.0%) of 1,994 sampled dentists responded to the survey. It was estimated that Ontario dentists removed 1,880.32 kg of amalgam (940.16 kg of mercury) during 2002, of which 1,128.19 kg of amalgam (564.10 kg of mercury) would have been released into waste water in Ontario if no dentists had been using a separator. Approximately 22% of the dentists reported using amalgam particle separators. On the basis of current use of amalgam separators, it was estimated that 861.78 kg of amalgam (430.89 kg of mercury or 170.72 mg per dentist daily) was released in 2002. The use of amalgam separators by all dentists could reduce the quantity of amalgam (and mercury) entering waste water to an estimated 12.41 kg (6.21 kg of mercury, or 2.46 mg per dentist per day). Amalgam particles separators can dramatically reduce amalgam and mercury loading in waste water released from dental offices.

  10. Selective extraction of copper, mercury, silver and palladium ionsfrom water using hydrophobic ionic liquids.

    Papaiconomou, Nicolas; Lee, Jong-Min; Salminen, Justin; VonStosch, Moritz; Prausnitz, John M.

    2007-06-25

    Extraction of dilute metal ions from water was performed near room temperature with a variety of ionic liquids. Distribution coefficients are reported for fourteen metal ions extracted with ionic liquids containing cations 1-octyl-4-methylpyridinium [4MOPYR]{sup +}, 1-methyl-1-octylpyrrolidinium [MOPYRRO]{sup +} or 1-methyl-1-octylpiperidinium [MOPIP]{sup +}, and anions tetrafluoroborate [BF{sub 4}]{sup +}, trifluoromethyl sulfonate [TfO]{sup +} or nonafluorobutyl sulfonate [NfO]{sup +}. Ionic liquids containing octylpyridinium cations are very good for extracting mercury ions. However, other metal ions were not significantly extracted by any of these ionic liquids. Extractions were also performed with four new task-specific ionic liquids. Such liquids containing a disulfide functional group are efficient and selective for mercury and copper, whereas those containing a nitrile functional group are efficient and selective for silver and palladium.

  11. Voyageurs National Park: Water-level regulation and effects on water quality and aquatic biology

    Christensen, Victoria G.; Maki, Ryan P.; LeDuc, Jaime F.

    2018-01-01

    Following dam installations in the remote Rainy Lake Basin during the early 1900s, water-level fluctuations were considered extreme (1914–1949) compared to more natural conditions. In 1949, the International Joint Commission (IJC), which sets rules governing dam operation on waters shared by the United States and Canada, established the first rule curves to regulate water levels on these waterbodies. However, rule curves established prior to 2000 were determined to be detrimental to the ecosystem. Therefore, the IJC implemented an order in 2000 to change rule curves and to restore a more natural water regime. After 2000, measured chlorophyll-a concentrations in the two most eutrophic water bodies decreased whereas concentrations in oligotrophic lakes did not show significant water-quality differences. Fish mercury data were inconclusive, due to the variation in water levels and fish mercury concentrations, but can be used by the IJC as part of a long term data set.

  12. Portable water quality monitoring system

    Nizar, N. B.; Ong, N. R.; Aziz, M. H. A.; Alcain, J. B.; Haimi, W. M. W. N.; Sauli, Z.

    2017-09-01

    Portable water quality monitoring system was a developed system that tested varied samples of water by using different sensors and provided the specific readings to the user via short message service (SMS) based on the conditions of the water itself. In this water quality monitoring system, the processing part was based on a microcontroller instead of Lead and Copper Rule (LCR) machines to receive the results. By using four main sensors, this system obtained the readings based on the detection of the sensors, respectively. Therefore, users can receive the readings through SMS because there was a connection between Arduino Uno and GSM Module. This system was designed to be portable so that it would be convenient for users to carry it anywhere and everywhere they wanted to since the processor used is smaller in size compared to the LCR machines. It was also developed to ease the user to monitor and control the water quality. However, the ranges of the sensors' detection still a limitation in this study.

  13. Water quality for liquid wastes

    Mizuniwa, Fumio; Maekoya, Chiaki; Iwasaki, Hitoshi; Yano, Hiroaki; Watahiki, Kazuo.

    1985-01-01

    Purpose: To facilitate the automation of the operation for a liquid wastes processing system by enabling continuous analysis for the main ingredients in the liquid wastes accurately and rapidly. Constitution: The water quality monitor comprises a sampling pipeway system for taking out sample water for the analysis of liquid wastes from a pipeway introducing liquid wastes to the liquid wastes concentrator, a filter for removing suspended matters in the sample water and absorption photometer as a water quality analyzer. A portion of the liquid wastes is passed through the suspended matter filter by a feedpump. In this case, sulfate ions and chloride ions in the sample are retained in the upper portion of a separation color and, subsequently, the respective ingredients are separated and leached out by eluting solution. Since the leached out ingredients form ferric ions and yellow complexes respectively, their concentrations can be detected by the spectrum photometer. Accordingly, concentration for the sodium sulfate and sodium chloride in the liquid wastes can be analyzed rapidly, accurately and repeatedly by which the water quality can be determined rapidly and accurately. (Yoshino, Y.)

  14. Shallow Water Optical Water Quality Buoy

    Bostater, Charles

    1998-01-01

    This NASA grant was funded as a result of an unsolicited proposal submission to Kennedy Space Center. The proposal proposed the development and testing of a shallow water optical water quality buoy. The buoy is meant to work in shallow aquatic systems (ponds, rivers, lagoons, and semi-enclosed water areas where strong wind wave action is not a major environmental During the project period of three years, a demonstration of the buoy was conducted. The last demonstration during the project period was held in November, 1996 when the buoy was demonstrated as being totally operational with no tethered communications line. During the last year of the project the buoy was made to be solar operated by large gel cell batteries. Fund limitations did not permit the batteries in metal enclosures as hoped for higher wind conditions, however the system used to date has worked continuously for in- situ operation of over 18 months continuous deployment. The system needs to have maintenance and somewhat continuous operational attention since various components have limited lifetime ages. For example, within the last six months the onboard computer has had to be repaired as it did approximately 6 months after deployment. The spectrograph had to be repaired and costs for repairs was covered by KB Science since no ftmds were available for this purpose after the grant expired. Most recently the computer web page server failed and it is currently being repaired by KB Science. In addition, the cell phone operation is currently being ftmded by Dr. Bostater in order to maintain the system's operation. The above points need to be made to allow NASA to understand that like any sophisticated measuring system in a lab or in the field, necessary funding and maintenance is needed to insure the system's operational state and to obtain quality factor. The proposal stated that the project was based upon the integration of a proprietary and confidential sensor and probe design that was developed by

  15. Chemical, physical, and radiological quality of selected public water supplies in Florida, January-May 1979. Water-resources investigations

    Franks, B.J.; Irwin, G.A.

    1980-01-01

    Most public water supplies sampled in Florida meet the National Interim Primary and Proposed Secondary Drinking Water Regulations. This conclusion is based on a water quality reconnaissance of 131 raw and treated public supplies throughout the State during the period January through May 1979. In a few public supplies, primary drinking water regulation maximum contaminant levels were exceeded for mercury, turbidity, and gross alpha particle activity. Secondary drinking water regulations were also occasionally exceeded in some public supplies for such parameters as chloride, pH, color, dissolved solids, iron, and manganese

  16. Review on water quality sensors

    Kruse, Peter

    2018-05-01

    Terrestrial life may be carbon-based, but most of its mass is made up of water. Access to clean water is essential to all aspects of maintaining life. Mainly due to human activity, the strain on the water resources of our planet has increased substantially, requiring action in water management and purification. Water quality sensors are needed in order to quantify the problem and verify the success of remedial actions. This review summarizes the most common chemical water quality parameters, and current developments in sensor technology available to monitor them. Particular emphasis is on technologies that lend themselves to reagent-free, low-maintenance, autonomous and continuous monitoring. Chemiresistors and other electrical sensors are discussed in particular detail, while mechanical, optical and electrochemical sensors also find mentioning. The focus here is on the physics of chemical signal transduction in sensor elements that are in direct contact with the analyte. All other sensing methods, and all other elements of sampling, sample pre-treatment as well as the collection, transmission and analysis of the data are not discussed here. Instead, the goal is to highlight the progress and remaining challenges in the development of sensor materials and designs for an audience of physicists and materials scientists.

  17. Non-destructive γ-spectrometric determination of mercury and gold in sea water after preconcentration by lead sulphide

    Alexandrov, S.

    1976-01-01

    A method is described for determination of mercury and gold in sea-water, based on preconcentration of these elements by retention on a column of lead sulphide at pH1 (nitric and sulphuric acids), and γ-spectrometry. Mercury (0.8 +-0.2 μg/l) and gold (6 +- 3 ng/l) have been determined in a sample from the Black Sea, taken near Varna. (author)

  18. Water quality in gravel pits in the Bratislava area

    Flakova, R.; Rohacikova, A.; Zenisova, Z.

    1999-01-01

    The gravel pits around Bratislava have an esthetic, urban and recreational function. Open water table areas are in a direct contact with the air and acquire some characteristics of the surface water. The quality of open water table is much more susceptible to pollution than that of groundwater. Wet and dry deposition, water inflow from the surrounding surface, unmanageable sewerage effluents, solid and liquid wastes, but also the water birds contribute to the pollution. The Department of Hydrogeology has monitored the water quality in six gravel pits (Cunovo, Drazdiak, Strkovec, Pasienky, Zlate Piesky, Vajnory) since 1976 with an an interruption between 1988 - 1993. Two sampling per year have been made since 1994 and after 1998 the analyses have been supplemented by Na, K, Fe, Mn, by oxygen regime parameters, by trace elements (As, Ag, Cd, Co, Cu, Cr, Hg, Ni, Pb, V, Zn) and by organic pollutants. As regards the oxygen regime, the water quality pits is very good. The anthropogenic influence is expressed mainly by the increased contents of sulfates and chlorides. Most problematic trace elements are the mercury and vanadium (Drazdiak, Zlate Piesky and Vajnory). (authors)

  19. Water quality relationships and evaluation using a new water quality index

    Said, A.; Stevens, D.; Sehlke, G.

    2002-01-01

    Water quality is dependent on a variety of measures, including dissolved oxygen, microbial contamination, turbidity, nutrients, temperature, pH, and other constituents. Determining relationships between water quality parameters can improve water quality assessment, and watershed management. In addition, these relationships can be very valuable in case of evaluating water quality in watersheds that have few water quality data. (author)

  20. Determination of mercury, lead and cadmium in water by the CRA-atomic absorption spectrophotometry with solvent extraction

    Shim, Y.B.; Won, M.S.; Kim, C.J.

    1980-01-01

    The method of CRA-atomic absorption spectrophotometer with solvent extraction for the determination of mercury, lead and cadmium in water was studied. The optimum extracting conditions for CRA-atomic absorption spectrophotometry were the following: the complexes of mercury, lead and cadmium with dithizone were separated from the aqueous solution and concentrated into the 10 ml chloroform solution. Back extraction was performed; the concentrated mercury, lead and cadmium was extracted from the chloroform solution into the 10 ml 6-normal aqueous hydrochloric acid solution. In this case, recovery ratios were the following: mercury was 94.7%, lead 97.7% and cadmium 103.6%. The optimum operating conditions for the determination of mercury, lead and cadmium by the CRA-atomic absorption spectrophotometry also were investigated to test the dry step, ash step and atomization step for each metal. The experimental results of standard addition method were the following: the determination limit of each metal within 6% relative deviation was that lead was 0.04 ppb, and cadmium 0.01 ppb. Especially, mercury has been known impossible to determine by CRA-atomic absorption spectrophotometry until now. But in this study, mercury can be determined with CRA-atomic absorption spectrophotometer. Its determination limit was 4 ppb within 8% relative deviation. (author)

  1. [Spatial Distribution Characteristics of Different Species Mercury in Water Body of Changshou Lake in Three Gorges Reservoir Region].

    Bai, Wei-yang; Zhang, Cheng; Zhao, Zheng; Tang, Zhen-ya; Wang, Ding-yong

    2015-08-01

    An investigation on the concentrations and the spatial distribution characteristics of different species of mercury in the water body of Changshou Lake in Three Gorges Reservoir region was carried out based on the AreGIS statistics module. The results showed that the concentration of the total mercury in Changshou Lake surface water ranged from 0.50 to 3.78 ng x L(-1), with an average of 1.51 ng x L(-1); the concentration of the total MeHg (methylmercury) ranged from 0.10 to 0.75 ng x L(-1), with an average of 0.23 ng x L(-1). The nugget effect value of total mercury in surface water (50.65%), dissolved mercury (49.80%), particulate mercury (29.94%) and the activity mercury (26.95%) were moderate spatial autocorrelation. It indicated that the autocorrelation was impacted by the intrinsic properties of sediments (such as parent materials and rocks, geological mineral and terrain), and on the other hand it was also disturbed by the exogenous input factors (such as aquaculture, industrial activities, farming etc). The nugget effect value of dissolved methylmercury (DMeHg) in Changshou lake surface water (3.49%) was less than 25%, showing significant strong spatial autocorrelation. The distribution was mainly controlled by environmental factors in water. The proportion of total MeHg in total Hg in Changshou Lake water reached 30% which was the maximum ratio of the total MeHg to total Hg in freshwater lakes and rivers. It implied that mercury was easily methylated in the environment of Chanashou Lake.

  2. Dam water quality study. Report to Congress

    1989-05-01

    The objective of the report is to identify water quality effects attributable to the impoundment of water by dams as required by Section 524 of the Water Quality Act of 1987. The document presents a study of water quality effects associated with impoundments in the U.S.A

  3. 9 CFR 3.106 - Water quality.

    2010-01-01

    ... 9 Animals and Animal Products 1 2010-01-01 2010-01-01 false Water quality. 3.106 Section 3.106... Mammals Animal Health and Husbandry Standards § 3.106 Water quality. (a) General. The primary enclosure... additives (e.g. chlorine and copper) that are added to the water to maintain water quality standards...

  4. Insights into the mechanisms of mercury sorption onto aluminum based drinking water treatment residuals

    Deliz Quiñones, Katherine; Hovsepyan, Anna; Oppong-Anane, Akua; Bonzongo, Jean-Claude J.

    2016-01-01

    Highlights: • Mercury sorption by Al-WTRs involves electrostatic forces and chemisorption. • Hg forms bonds with oxygen and sulfur atoms of Al-WTR’s organic ligands. • Mercury is incorporated into the residual fraction to form stable complexes. • Mercury binds mainly to SiO x species in the residual fraction. - Abstract: Several studies have demonstrated the ability of drinking water treatment residuals (WTRs) to efficiently sorb metal cations from aqueous solutions. Reported results have stimulated interest on the potential use of WTRs as sorbent for metal removal from contaminated aqueous effluents as well as in metal immobilization in contaminated soils. However, knowledge on mechanisms of metal sorption by WTRs remains very limited and data on the long-term stability of formed metal–WTR complexes as a function of changing key environmental parameters are lacking. In this study, chemical selective sequential extraction (SSE), scanning electron microscopy combined with X-ray energy dispersive spectrometer (SEM-EDS), and X-ray photoelectron spectroscopy (XPS) were used to gain insight into the different mechanisms of mercury (Hg) binding to aluminum based WTR (Al-WTRs). Results from sorption studies show that a significant portion of Hg becomes incorporated in the operationally defined residual fraction of Al-WTRs, and therefore, not prone to dissolution and mobility. The results of solid phase analyses suggested that Hg immobilization by Al-WTR occurs largely through its binding to oxygen donor atoms of mineral ligands driven by a combination of electrostatic forces and covalent bonding.

  5. Insights into the mechanisms of mercury sorption onto aluminum based drinking water treatment residuals

    Deliz Quiñones, Katherine, E-mail: Katherine.Deliz@amecfw.com; Hovsepyan, Anna, E-mail: anna_Hovsepyan@urscorp.com; Oppong-Anane, Akua; Bonzongo, Jean-Claude J., E-mail: bonzongo@ufl.edu

    2016-04-15

    Highlights: • Mercury sorption by Al-WTRs involves electrostatic forces and chemisorption. • Hg forms bonds with oxygen and sulfur atoms of Al-WTR’s organic ligands. • Mercury is incorporated into the residual fraction to form stable complexes. • Mercury binds mainly to SiO{sub x} species in the residual fraction. - Abstract: Several studies have demonstrated the ability of drinking water treatment residuals (WTRs) to efficiently sorb metal cations from aqueous solutions. Reported results have stimulated interest on the potential use of WTRs as sorbent for metal removal from contaminated aqueous effluents as well as in metal immobilization in contaminated soils. However, knowledge on mechanisms of metal sorption by WTRs remains very limited and data on the long-term stability of formed metal–WTR complexes as a function of changing key environmental parameters are lacking. In this study, chemical selective sequential extraction (SSE), scanning electron microscopy combined with X-ray energy dispersive spectrometer (SEM-EDS), and X-ray photoelectron spectroscopy (XPS) were used to gain insight into the different mechanisms of mercury (Hg) binding to aluminum based WTR (Al-WTRs). Results from sorption studies show that a significant portion of Hg becomes incorporated in the operationally defined residual fraction of Al-WTRs, and therefore, not prone to dissolution and mobility. The results of solid phase analyses suggested that Hg immobilization by Al-WTR occurs largely through its binding to oxygen donor atoms of mineral ligands driven by a combination of electrostatic forces and covalent bonding.

  6. Water quality assessment of selected domestic water sources in ...

    However, lead ion appears higher than the approved WHO and SON standard for water quality in all the sources except that of water vendors which is 0.04mg/l. It is therefore recommended that periodic monitoring of water quality, effective waste management system to improve the general water quality in the town, and ...

  7. Application of radiochemical methods to investigate mercury in water-ecosystems

    Kraemer, H.J.

    1975-01-01

    Two topics have been picked out of the vast scope of possible questions on mercury ecology in this work: 1) Development for a method of enrichment of mercury from surface water and neutron activation analytical determination of the influence of dissolved Hg compounds on the water/fish part-process taking course in the water-ecosystem with the help of radiochemical tracer methods. The developed enrichment method, adsorbents on aniline sulphur resin basis, was applied to the activation analytical Hg determination in model solutions with a specified content as well as in water of the Rhine, where a Hg content of 1.1 +- 0.2 x 10 -3 ppm was determined. 2) The uptake (and yield) of Hg (NO 3 ) 2 and CH 3 HgCl from fish was traced using radioactive tracers Hg 197 and Hg 203. The measured accumulation and yield kinetics and observed influence due to additions enable the development of model to interpret the interaction between fish and dissolved Hg compounds. (RB) [de

  8. Water quality control system and water quality control method

    Itsumi, Sachio; Ichikawa, Nagayoshi; Uruma, Hiroshi; Yamada, Kazuya; Seki, Shuji

    1998-01-01

    In the water quality control system of the present invention, portions in contact with water comprise a metal material having a controlled content of iron or chromium, and the chromium content on the surface is increased than that of mother material in a state where compression stresses remain on the surface by mechanical polishing to form an uniform corrosion resistant coating film. In addition, equipments and/or pipelines to which a material controlling corrosion potential stably is applied on the surface are used. There are disposed a cleaning device made of a material less forming impurities, and detecting intrusion of impurities and removing them selectively depending on chemical species and/or a cleaning device for recovering drain from various kinds of equipment to feedwater, connecting a feedwater pipeline and a condensate pipeline and removing impurities and corrosion products. Then, water can be kept to neutral purified water, and the concentrations of oxygen and hydrogen in water are controlled within an optimum range to suppress occurrence of corrosion products. (N.H.)

  9. Radiotracer method to study the transport of mercury(II)chloride from water to sediment and air

    Karaca, F.; Aras, N.K.

    2004-01-01

    The fate of dissolved Hg(II) in surface waters is an important component of the Hg cycle. A simple experimental methodology was used to understand and measure the transport of Hg(II) from water to air and sediment. The use of radioactive dissolved Hg tracer for the determination of evasion and deposition is found to be a very useful technique. The evasion of mercury was investigated during a 140-hour period. It was observed that about a quarter of mercury chloride remained in the water phase, the other quarter was emitted via the evasion process and half of it deposited in sediment. (author)

  10. Quality of surface-water supplies in the Triangle area of North Carolina, water year 2009

    Pfeifle, C. A.; Giorgino, M. J.; Rasmussen, R. B.

    2014-01-01

    Surface-water supplies are important sources of drinking water for residents in the Triangle area of North Carolina, which is located within the upper Cape Fear and Neuse River Basins. Since 1988, the U.S. Geological Survey and a consortium of governments have tracked water-quality conditions and trends in several of the area’s water-supply lakes and streams. This report summarizes data collected through this cooperative effort, known as the Triangle Area Water Supply Monitoring Project, during October 2008 through September 2009. Major findings for this period include: - Annual precipitation was approximately 20 percent below the long-term mean (average) annual precipitation. - Streamflow was below the long-term mean at the 10 project streamgages during most of the year. - More than 7,000 individual measurements of water quality were made at a total of 26 sites—15 in the Neuse River Basin and 11 in the Cape Fear River Basin. Forty-seven water-quality properties and constituents were measured. - All observations met North Carolina water-quality standards for water temperature, pH, hardness, chloride, fluoride, sulfate, nitrate, arsenic, cadmium, chromium, lead, nickel, and selenium. - North Carolina water-quality standards were exceeded one or more times for dissolved oxygen, dissolved oxygen percent saturation, chlorophyll a, mercury, copper, iron, manganese, silver, and zinc. Exceedances occurred at 23 sites—13 in the Neuse River Basin and 10 in the Cape Fear River Basin. - Stream samples collected during storm events contained elevated concentrations of 18 water-quality constituents compared to samples collected during non-storm events. - Concentrations of nitrogen and phosphorus were within ranges observed during previous years. - Five reservoirs had chlorophyll a concentrations in excess of 40 micrograms per liter at least once during 2009: Little River Reservoir, Falls Lake, Cane Creek Reservoir, University Lake, and Jordan Lake.

  11. Novel methodology for the study of mercury methylation and reduction in sediments and water using 197Hg radiotracer.

    Ribeiro Guevara, Sergio; Zizek, Suzana; Repinc, Urska; Pérez Catán, Soledad; Jaćimović, Radojko; Horvat, Milena

    2007-03-01

    Mercury tracers are powerful tools that can be used to study mercury transformations in environmental systems, particularly mercury methylation, demethylation and reduction in sediments and water. However, mercury transformation studies using tracers can be subject to error, especially when used to assess methylation potential. The organic mercury extracted can be as low as 0.01% of the endogenous labeled mercury, and artefacts and contamination present during methylmercury (MeHg) extraction processes can cause interference. Solvent extraction methods based on the use of either KBr/H2SO4 or HCl were evaluated in freshwater sediments using 197Hg radiotracer. Values obtained for the 197Hg tracer in the organic phase were up to 25-fold higher when HCl was used, which is due to the coextraction of 197Hg2+ into the organic phase during MeHg extraction. Evaluations of the production of MeHg gave similar results with both MeHg extraction procedures, but due to the higher Hg2+ contamination of the controls, the uncertainty in the determination was higher when HCl was used. The Hg2+ contamination of controls in the HCl extraction method showed a nonlinear correlation with the humic acid content of sediment pore water. Therefore, use of the KBr/H2SO4 method is recommended, since it is free from these interferences. 197Hg radiotracer (T1/2=2.673 d) has a production rate that is about 50 times higher than that of 203Hg (T1/2=46.595 d), the most frequently used mercury radiotracer. Hence it is possible to obtain a similar level of performance to 203Hg when it is used it in short-term experiments and produced by the irradiation of 196Hg with thermal neutrons, using mercury targets with the natural isotopic composition. However, if the 0.15% natural abundance of the 196Hg isotope is increased, the specific activity of the 197Hg tracer can be significantly improved. In the present work, 197Hg tracer was produced from mercury 51.58% enriched in the 196Hg isotope, and a 340-fold

  12. Comparison of Granular Activated Carbon, Natural Clinoptilolite Zeolite, and Anthracite Packed Columns in Removing Mercury from Drinking Water

    Mohammad Taghi Samadi

    2010-01-01

    Full Text Available Development of effective methods for the removal of such pollutants as heavy metals (e.g., mercury from surface and ground water resources introduced by municipal and industrial wastewaters seems to be inevitable, especially in the face of the importance of water reuse in combating water shortages, limited availability of water resources, and imminent risks of a water crisis in Iran. A number of methods are already available for the removal of mercury from water resources. However, these techniques must be investigated for their practicability and economy, in addition to their not only effectiveness. In this research, granular activated carbon, natural zeolite, and anthracite packed-columns were investigated as cheap and effective adsorbents for the removal of mercury. Moreover, the effects of changes in pH (6-8, influent mercury concentrations (0.25, 0.5, 0.75, and 1 ppm, contact time (0.5, 1, 2, 3 hr were investigated. Mercury concentration in the samples was determined using a ditizon indicator and spectrophotometry at 492 nm. Results showed that decreasing influent mercury concentration from 1 ppm to 0.25 ppm (under constant conditions increased the removal efficiencies of anthracite, granular activated carbon, and zeolite columns from22%, 63%, and 55% to 28%, 72%, and 64%, respectively. Increasing contact time from 0.5 hr to 3 hr caused the removal efficiencies of these columns to increase from 22%, 56%, and 54% to 42%, 86%, and 82%, respectively. Also, increasing pH level led to increased removal efficiencies of the studied columns. It was found that contact time played a more effective role in enhancing mercury removal efficiency in the granular activated carbon column than in the other two columns. The ranges of mercury removal efficiency obtained for the granular activated carbon, natural zeolite, and anthracite columns under various conditions were (51%-92%, (42%-88%, and (16%-52%, respectively. Based on these results, granular

  13. Interactions of climate, socio-economics, and global mercury pollution in the North Water

    Dietz, Rune; Mosbech, Anders; Flora, Janne

    2018-01-01

    Despite the remoteness of the North Water, Northwest Greenland, the local Inughuit population is affected by global anthropogenic pollution and climate change. Using a cross-disciplinary approach combining Mercury (Hg) analysis, catch information, and historical and anthropological perspectives......, this article elucidates how the traditional diet is compromised by Hg pollution originating from lower latitudes. In a new approach we here show how the Inughuits in Avanersuaq are subject to high Hg exposure from the hunted traditional food, consisting of mainly marine seabirds and mammals. Violation...

  14. Factors affecting water strider (Hemiptera: Gerridae) mercury concentrations in lotic systems

    Jardine, T.D.; Kidd, K.A.; Cunjak, R.A.; Arp, P.A. [University of New Brunswick, St John, NB (Canada). Canadian Rivers Institute

    2009-07-15

    Water striders (Hemiptera: Gerridae) have been considered as a potential sentinel for mercury (Hg) contamination of freshwater ecosystems, yet little is known about factors that control Hg concentrations in this invertebrate. Striders were collected from 80 streams and rivers in New Brunswick, Canada, in August and September of 2004 through 2007 to assess the influence of factors such as diet, water chemistry, and proximity to point sources on Hg concentrations in this organism. Higher than average Hg concentrations were observed in the southwest and Grand Lake regions of the province, the latter being the location of a coal-fired power plant that is a source of Hg (similar to 100 kg annually), with elevated Hg concentrations in the lichen Old Man's Beard (Usnea spp.) in its immediate vicinity. Across all streams, pH and total organic carbon of water were relatively weak predictors of strider Hg concentrations. Female striders that were larger in body size than males had significantly lower Hg concentrations within sites, suggestive of growth dilution. There was no relationship between percent aquatic carbon in the diet and Hg concentrations in striders. For those striders feeding solely on terrestrial carbon, Hg concentrations were higher in animals occupying a higher trophic level. Mercury concentrations were highly variable in striders collected monthly over two growing seasons, suggesting short-term changes in Hg availability. These measurements highlight the importance of considering both deposition and postdepositional processes in assessing Hg bioaccumulation in this species.

  15. Simultaneous determination of inorganic mercury and methylmercury compounds in natural waters

    Logar, Martina; Horvat, Milena [Jozef Stefan Institute, Jamova 39, 1000 Ljubljana (Slovenia); Akagi, Hirokatsu [National Institute for Minamata Disease, 4058-18 Hama, Minamata, Kumamoto 867-0008 (Japan); Pihlar, Boris [Faculty of Chemistry and Chemical Technology, University of Ljubljana, Askerceva 5, 1000 Ljubljana (Slovenia)

    2002-11-01

    The purpose of the present work was to develop a simple, rapid, sensitive and accurate method for the simultaneous determination of inorganic mercury (Hg{sup 2+}) and monomethylmercury compounds (MeHg) in natural water samples at the pg L{sup -1} level. The method is based on the simultaneous extraction of MeHg and Hg{sup 2+}dithizonates into an organic solvent (toluene) after acidification of about 300 mL of a water sample, followed by back extraction into an aqueous solution of Na {sub 2}S, removal of H {sub 2}S by purging with N {sub 2}, subsequent ethylation with sodium tetraethylborate, room temperature precollection on Tenax, isothermal gas chromatographic separation (GC), pyrolysis and cold vapour atomic fluorescence spectrometric detection (CV AFS) of mercury. The limit of detection calculated on the basis of three times the standard deviation of the blank was about 0.006 ng L {sup -1} for MeHg and 0.06 ng L {sup -1} for Hg {sup 2+}when 300 mL of water was analysed. The repeatability of the results was about 5% for MeHg and 10% for Hg {sup 2+}. Recoveries were 90-110% for both species. (orig.)

  16. RECOVERY OF MERCURY FROM CONTAMINATED PRIMARY AND SECONDARY WASTES

    A. Faucette; J. Bognar; T. Broderick; T. Battaglia

    2000-01-01

    Effective removal of mercury contamination from water is a complex and difficult problem. In particular, mercury treatment of natural waters is difficult because of the low regulatory standards. For example, the Environmental Protection Agency has established a national ambient water quality standard of 12 parts-per-trillion (ppt), whereas the standard is 1.8 ppt in the Great Lakes Region. In addition, mercury is typically present in several different forms, but sorption processes are rarely effective with more than one or two of these forms. To meet the low regulatory discharge limits, a sorption process must be able to address all forms of mercury present in the water. One approach is to apply different sorbents in series depending on the mercury speciation and the regulatory discharge limits. Four new sorbents have been developed to address the variety of mercury species present in industrial discharges and natural waters. Three of these sorbents have been field tested on contaminated creek water at the Y-12 Plant. Two of these sorbents have demonstrated very high removal efficiencies for soluble mercury species, with mercury concentrations at the outlet of a pilot-scale system less than 12 ppt for as long as six months. The other sorbent tested at the Y-12 Plant is targeted at colloidal mercury that is not removed by standard sorption or filtration processes. At the Y-12 Plant, colloidal mercury appears to be associated with iron, so a sorbent that removes mercury-iron complexes in the presence of a magnetic field was evaluated. Field results indicate good removal of this mercury fraction from the Y-12 waters. In addition, this sorbent is easily regenerated by simply removing the magnetic field and flushing the columns with water. The fourth sorbent is still undergoing laboratory development, but results to date indicate exceptionally high mercury sorption capacity. The sorbent is capable of removing all forms of mercury typically present in natural and

  17. 78 FR 20252 - Water Quality Standards; Withdrawal of Certain Federal Water Quality Criteria Applicable to...

    2013-04-04

    ... Water Quality Standards; Withdrawal of Certain Federal Water Quality Criteria Applicable to California... aquatic life water quality criteria applicable to waters of New Jersey, Puerto Rico, and California's San Francisco Bay. In 1992, EPA promulgated the National Toxics Rule or NTR to establish numeric water quality...

  18. Total and methyl mercury concentrations in sediment and water of a constructed wetland in the Athabasca Oil Sands Region.

    Oswald, Claire J; Carey, Sean K

    2016-06-01

    In the Athabasca Oil Sands Region in northeastern Alberta, Canada, oil sands operators are testing the feasibility of peatland construction on the post-mining landscape. In 2009, Syncrude Canada Ltd. began construction of the 52 ha Sandhill Fen pilot watershed, including a 15 ha, hydrologically managed fen peatland built on sand-capped soft oil sands tailings. An integral component of fen reclamation is post-construction monitoring of water quality, including salinity, fluvial carbon, and priority pollutant elements. In this study, the effects of fen reclamation and elevated sulfate levels on mercury (Hg) fate and transport in the constructed system were assessed. Total mercury (THg) and methylmercury (MeHg) concentrations in the fen sediment were lower than in two nearby natural fens, which may be due to the higher mineral content of the Sandhill Fen peat mix and/or a loss of Hg through evasion during the peat harvesting, stockpiling and placement processes. Porewater MeHg concentrations in the Sandhill Fen typically did not exceed 1.0 ng L(-1). The low MeHg concentrations may be a result of elevated porewater sulfate concentrations (mean 346 mg L(-1)) and an increase in sulphide concentrations with depth in the peat, which are known to suppress MeHg production. Total Hg and MeHg concentrations increased during a controlled mid-summer flooding event where the water table rose above the ground surface in most of the fen. The Hg dynamics during this event showed that hydrologic fluctuations in this system exacerbate the release of THg and MeHg downstream. In addition, the elevated SO4(2-) concentrations in the peat porewaters may become a problem with respect to downstream MeHg production once the fen is hydrologically connected to a larger wetland network that is currently being constructed. Copyright © 2016 Elsevier Ltd. All rights reserved.

  19. Mercury and halogens in coal: Chapter 2

    Kolker, Allan; Quick, Jeffrey C.; Granite, Evan J.; Pennline, Henry W.; Senior, Constance L.

    2014-01-01

    Apart from mercury itself, coal rank and halogen content are among the most important factors inherent in coal that determine the proportion of mercury captured by conventional controls during coal combustion. This chapter reviews how mercury in coal occurs, gives available concentration data for mercury in U.S. and international commercial coals, and provides an overview of the natural variation in halogens that influence mercury capture. Three databases, the U.S. Geological Survey coal quality (USGS COALQUAL) database for in-ground coals, and the 1999 and 2010 U.S. Environmental Protection Agency (EPA) Information Collection Request (ICR) databases for coals delivered to power stations, provide extensive results for mercury and other parameters that are compared in this chapter. In addition to the United States, detailed characterization of mercury is available on a nationwide basis for China, whose mean values in recent compilations are very similar to the United States in-ground mean of 0.17 ppm mercury. Available data for the next five largest producers (India, Australia, South Africa, the Russian Federation, and Indonesia) are more limited and with the possible exceptions of Australia and the Russian Federation, do not allow nationwide means for mercury in coal to be calculated. Chlorine in coal varies as a function of rank and correspondingly, depth of burial. As discussed elsewhere in this volume, on a proportional basis, bromine is more effective than chlorine in promoting mercury oxidation in flue gas and capture by conventional controls. The ratio of bromine to chlorine in coal is indicative of the proportion of halogens present in formation waters within a coal basin. This ratio is relatively constant except in coals that have interacted with deep-basin brines that have reached halite saturation, enriching residual fluids in bromine. Results presented here help optimize mercury capture by conventional controls and provide a starting point for

  20. Water quality of hydrologic bench marks; an indicator of water quality in the natural environment

    Biesecker, James E.; Leifeste, Donald K.

    1974-01-01

    Water-quality data, collected at 57 hydrologic bench-mark stations in 37 States, allow the definition of water quality in the 'natural' environment and the comparison of 'natural' water quality with water quality of major streams draining similar water-resources regions. Results indicate that water quality in the 'natural' environment is generally very good. Streams draining hydrologic bench-mark basins generally contain low concentrations of dissolved constituents. Water collected at the hydrologic bench-mark stations was analyzed for the following minor metals: arsenic, barium, cadmium, hexavalent chromium, cobalt, copper, lead, mercury, selenium, silver, and zinc. Of 642 analyses, about 65 percent of the observed concentrations were zero. Only three samples contained metals in excess of U.S. Public Health Service recommended drinking-water standards--two selenium concentrations and one cadmium concentration. A total of 213 samples were analyzed for 11 pesticidal compounds. Widespread but very low-level occurrence of pesticide residues in the 'natural' environment was found--about 30 percent of all samples contained low-level concentrations of pesticidal compounds. The DDT family of pesticides occurred most commonly, accounting for 75 percent of the detected occurrences. The highest observed concentration of DDT was 0.06 microgram per litre, well below the recommended maximum permissible in drinking water. Nitrate concentrations in the 'natural' environment generally varied from 0.2 to 0.5 milligram per litre. The average concentration of nitrate in many major streams is as much as 10 times greater. The relationship between dissolved-solids concentration and discharge per unit area in the 'natural' environment for the various physical divisions in the United States has been shown to be an applicable tool for approximating 'natural' water quality. The relationship between dissolved-solids concentration and discharge per unit area is applicable in all the physical

  1. San Francisco Bay Water Quality Improvement Fund

    EPAs grant program to protect and restore San Francisco Bay. The San Francisco Bay Water Quality Improvement Fund (SFBWQIF) has invested in 58 projects along with 70 partners contributing to restore wetlands, water quality, and reduce polluted runoff.,

  2. Assessing water quality in Lake Naivasha

    Ndungu, J.N.

    2014-01-01

    Water quality in aquatic systems is important because it maintains the ecological processes that support biodiversity. However, declining water quality due to environmental perturbations threatens the stability of the biotic integrity and therefore hinders the ecosystem services and functions of

  3. National Water Quality Standards Database (NWQSD)

    U.S. Environmental Protection Agency — The National Water Quality Standards Database (WQSDB) provides access to EPA and state water quality standards (WQS) information in text, tables, and maps. This data...

  4. R2 Water Quality Portal Monitoring Stations

    U.S. Environmental Protection Agency — The Water Quality Data Portal (WQP) provides an easy way to access data stored in various large water quality databases. The WQP provides various input parameters on...

  5. R2 Water Quality Portal Monitoring Stations

    The Water Quality Data Portal (WQP) provides an easy way to access data stored in various large water quality databases. The WQP provides various input parameters on the form including location, site, sampling, and date parameters to filter and customize the returned results. The The Water Quality Portal (WQP) is a cooperative service sponsored by the United States Geological Survey (USGS), the Environmental Protection Agency (EPA) and the National Water Quality Monitoring Council (NWQMC) that integrates publicly available water quality data from the USGS National Water Information System (NWIS) the EPA STOrage and RETrieval (STORET) Data Warehouse, and the USDA ARS Sustaining The Earth??s Watersheds - Agricultural Research Database System (STEWARDS).

  6. Sulfur rich microporous polymer enables rapid and efficient removal of mercury(II) from water.

    Xu, Dan; Wu, Winston Duo; Qi, Hao-Jun; Yang, Rui-Xia; Deng, Wei-Qiao

    2018-04-01

    Design and synthesis of adsorbents for efficient decontamination of hazardous contaminants Hg 2+ from wastewater, based on a facile and economical strategy, is an attractive target. Here, a novel sulfur rich microporous polymer (sulfur content of 31.4 wt %) with high surface area as well as densely populated sulfur atom with fast accessibility was reported to remove mercury (II) from water. The as prepared polymer (SMP) exhibited high binding affinity, high adsorption capacities, rapid adsorption kinetics, and good recyclability for Hg 2+ . The adsorption capacity of SMP was 595.2 mg g -1 . Furthermore, SMP could reduce trace concentrations of Hg 2+ from 200 p. p. b. to a level below drinking water standards (2 p. p. b.) within 3 min. This work allows large-scale production of sulfur rich porous materials for the practical application in water treatment. Copyright © 2017 Elsevier Ltd. All rights reserved.

  7. Mercury Exchange at the Air-Water-Soil Interface: An Overview of Methods

    Fengman Fang

    2002-01-01

    Full Text Available An attempt is made to assess the present knowledge about the methods of determining mercury (Hg exchange at the air-water-soil interface during the past 20 years. Methods determining processes of wet and dry removal/deposition of atmospheric Hg to aquatic and terrestrial ecosystems, as well as methods determining Hg emission fluxes to the atmosphere from natural surfaces (soil and water are discussed. On the basis of the impressive advances that have been made in the areas relating to Hg exchange among air-soil-water interfaces, we analyzed existing problems and shortcomings in our current knowledge. In addition, some important fields worth further research are discussed and proposed.

  8. Cork stoppers as an effective sorbent for water treatment: the removal of mercury at environmentally relevant concentrations and conditions.

    Lopes, Cláudia B; Oliveira, Joana R; Rocha, Luciana S; Tavares, Daniela S; Silva, Carlos M; Silva, Susana P; Hartog, Niels; Duarte, Armando C; Pereira, E

    2014-02-01

    The technical feasibility of using stopper-derived cork as an effective biosorbent towards bivalent mercury at environmentally relevant concentrations and conditions was evaluated in this study. Only 25 mg/L of cork powder was able to achieve 94 % of mercury removal for an initial mercury concentration of 500 μg/L. It was found that under the conditions tested, the efficiency of mercury removal expressed as equilibrium removal percentage does not depend on the amount of cork or its particle size, but is very sensitive to initial metal concentration, with higher removal efficiencies at higher initial concentrations. Ion exchange was identified as one of the mechanisms involved in the sorption of Hg onto cork in the absence of ionic competition. Under ionic competition, stopper-derived cork showed to be extremely effective and selective for mercury in binary mixtures, while in complex matrices like seawater, moderate inhibition of the sorption process was observed, attributed to a change in mercury speciation. The loadings achieved are similar to the majority of literature values found for other biosorbents and for other metals, suggesting that cork stoppers can be recycled as an effective biosorbent for water treatment. However, the most interesting result is that equilibrium data show a very rare behaviour, with the isotherm presenting an almost square convex shape to the concentration axis, with an infinite slope for an Hg concentration in solution around 25 μg/L.

  9. River water quality modelling: II

    Shanahan, P.; Henze, Mogens; Koncsos, L.

    1998-01-01

    The U.S. EPA QUAL2E model is currently the standard for river water quality modelling. While QUAL2E is adequate for the regulatory situation for which it was developed (the U.S. wasteload allocation process), there is a need for a more comprehensive framework for research and teaching. Moreover......, QUAL2E and similar models do not address a number of practical problems such as stormwater-flow events, nonpoint source pollution, and transient streamflow. Limitations in model formulation affect the ability to close mass balances, to represent sessile bacteria and other benthic processes......, and to achieve robust model calibration. Mass balance problems arise from failure to account for mass in the sediment as well as in the water column and due to the fundamental imprecision of BOD as a state variable. (C) 1998 IAWQ Published by Elsevier Science Ltd. All rights reserved....

  10. Water Quality of Hills Water, Supply Water and RO Water Machine at Ulu Yam Selangor

    Ngadiman, N.; ‘I Bahari, N.; Kaamin, M.; Hamid, N. B.; Mokhtar, M.; Sahat, S.

    2016-07-01

    The rapid development resulted in the deterioration of the quality of drinking water in Malaysia. Recognizing the importance of water quality, new alternatives for drinking water such as mineral water processing from reverse osmosis (RO) machine become more popular. Hence, the demand for mineral water, natural spring water or water from the hills or mountains rose lately. More consumers believed the quality of these spring water better than other source of drinking water. However, the quality of all the drinking water sources is to meet the required quality standard. Therefore, this paper aims to measure the quality of the waters from hills, from RO machine and the water supply in Ulu Yam, Selangor Batang Kali, Malaysia. The water quality was determined based on following parameters: ammoniacal nitrogen (NH3), iron (Fe), turbidity (NTU) and pH. The results show that the water from hills has better quality compared to water supply and water from RO machine. The value of NH3 ranged from 0.03 mg/L- 0.67 mg/L; Fe was from 0.03mg/L - 0.12 mg/L, turbidity at 0.42 NTU - 0.88 NTU and pH is at 6.60 - 0.71. Based on the studied parameters, all three types of water are fit for drinking and have met the required national drinking water quality standard.

  11. Water quality assessment of bioenergy production

    Rocio Diaz-Chavez; Goran Berndes; Dan Neary; Andre Elia Neto; Mamadou Fall

    2011-01-01

    Water quality is a measurement of the biological, chemical, and physical characteristics of water against certain standards set to ensure ecological and/or human health. Biomass production and conversion to fuels and electricity can impact water quality in lakes, rivers, and aquifers with consequences for aquatic ecosystem health and also human water uses. Depending on...

  12. Automated monitoring of recovered water quality

    Misselhorn, J. E.; Hartung, W. H.; Witz, S. W.

    1974-01-01

    Laboratory prototype water quality monitoring system provides automatic system for online monitoring of chemical, physical, and bacteriological properties of recovered water and for signaling malfunction in water recovery system. Monitor incorporates whenever possible commercially available sensors suitably modified.

  13. Determination of mercury in ambient water samples by anodic stripping voltammetry on screen-printed gold electrodes.

    Bernalte, E; Marín Sánchez, C; Pinilla Gil, E

    2011-03-09

    The applicability of commercial screen-printed gold electrodes (SPGEs) for the determination of Hg(II) in ambient water samples by square wave anodic stripping voltammetry has been demonstrated. Electrode conditioning procedures, chemical and instrumental variables have been optimized to develop a reliable method capable of measuring dissolved mercury in the low ng mL(-1) range (detection limit 1.1 ng mL(-1)), useful for pollution monitoring or screening purposes. The proposed method was tested with the NIST 1641d Mercury in Water Standard Reference Material (recoveries 90.0-110%) and the NCS ZC 76303 Mercury in Water Certified Reference Material (recoveries 82.5-90.6%). Waste water samples from industrial origin and fortified rain water samples were assayed for mercury by the proposed method and by a reference ICP-MS method, with good agreement. Screen printing technology thus opens a useful way for the construction of reliable electrochemical sensors for decentralized or even field Hg(II) testing. Copyright © 2011 Elsevier B.V. All rights reserved.

  14. Wood ash or dolomite treatment of catchment areas - effects of mercury in runoff water

    Parkman, H; Munthe, J [Swedish Environmental Research Inst., Stockholm (Sweden)

    1996-11-01

    A future increased use of biomass as a source of energy, and the planned restoration of mineral nutrient balance in the forest soils by returning the wood ashes, has led to concern for new environmental disturbances. The objectives of the present study were to investigate if the outflow of total mercury (TotHg) and methyl mercury (MeHg) from catchment areas treated with granulated wood ash (1988, 2.2 tons/ha, `ashed area`) or dolomite (1985, 5 tons/ha, `limed area`) differed from the outflow from an untreated (reference) area, and if variations in Hg outflow were correlated with changes in the outflow of organic substances or pH. The study areas are situated in Vaermland, Sweden. Samples of run-off water were taken weekly or monthly (depending on water-flow) during on year (1993-94). The outflow of MeHg, TotHg as well as H+ and dissolved organic material (DOC) was lower from the limed area compared to the other two areas, which did not differ significantly. There was a strong covariation between concentrations of DOC and MeHg and a weaker relation between DOC and TotHg in the run-off waters. MeHg also covaried with temperature while TotHg covaried with pH and water-supply. No difference was found when comparing Hg-data from the limed area before, directly after and eight years after the liming event. 13 refs, 12 figs, 1 tab

  15. The cycling and sea-air exchange of mercury in the waters of the Eastern Mediterranean during the 2010 MED-OCEANOR cruise campaign.

    Fantozzi, L; Manca, G; Ammoscato, I; Pirrone, N; Sprovieri, F

    2013-03-15

    An oceanographic cruise campaign on-board the Italian research vessel Urania was carried out from the 26th of August to the 13th of September 2010 in the Eastern Mediterranean. The campaign sought to investigate the mercury cycle at coastal and offshore locations in different weather conditions. The experimental activity focused on measuring mercury speciation in both seawater and in air, and using meteorological parameters to estimate elemental mercury exchange at the sea-atmosphere interface. Dissolved gaseous mercury (DGM), unfiltered total mercury (UTHg) and filtered total mercury (FTHg) surface concentrations ranged from 16 to 114, 300 to 18,760, and 230 to 10,990pgL(-1), respectively. The highest DGM, UTHg and FTHg values were observed close to Augusta (Sicily), a highly industrialized area of the Mediterranean region, while the lowest values were recorded at offshore stations. DGM vertical profiles partially followed the distribution of sunlight, as a result of the photoinduced transformations of elemental mercury in the surface layers of the water column. However, at some stations, we observed higher DGM concentrations in samples taken from the bottom of the water column, suggesting biological mercury production processes or the presence of tectonic activity. Moreover, two days of continuous measurement at one location demonstrated that surface DGM concentration is affected by solar radiation and atmospheric turbulence intensity. Atmospheric measurements of gaseous elemental mercury (GEM) showed an average concentration (1.6ngm(-3)) close to the background level for the northern hemisphere. For the first time this study used a numerical scheme based on a two-thin film model with a specific parameterization for mercury to estimate elemental mercury flux. The calculated average mercury flux during the entire cruise was 2.2±1.5ngm(-2)h(-1). The analysis of flux data highlights the importance of the wind speed on the mercury evasion from sea surfaces

  16. Water quality assessment and meta model development in Melen watershed - Turkey.

    Erturk, Ali; Gurel, Melike; Ekdal, Alpaslan; Tavsan, Cigdem; Ugurluoglu, Aysegul; Seker, Dursun Zafer; Tanik, Aysegul; Ozturk, Izzet

    2010-07-01

    Istanbul, being one of the highly populated metropolitan areas of the world, has been facing water scarcity since the past decade. Water transfer from Melen Watershed was considered as the most feasible option to supply water to Istanbul due to its high water potential and relatively less degraded water quality. This study consists of two parts. In the first part, water quality data covering 26 parameters from 5 monitoring stations were analyzed and assessed due to the requirements of the "Quality Required of Surface Water Intended for the Abstraction of Drinking Water" regulation. In the second part, a one-dimensional stream water quality model with simple water quality kinetics was developed. It formed a basic design for more advanced water quality models for the watershed. The reason for assessing the water quality data and developing a model was to provide information for decision making on preliminary actions to prevent any further deterioration of existing water quality. According to the water quality assessment at the water abstraction point, Melen River has relatively poor water quality with regard to NH(4)(+), BOD(5), faecal streptococcus, manganese and phenol parameters, and is unsuitable for drinking water abstraction in terms of COD, PO(4)(3-), total coliform, total suspended solids, mercury and total chromium parameters. The results derived from the model were found to be consistent with the water quality assessment. It also showed that relatively high inorganic nitrogen and phosphorus concentrations along the streams are related to diffuse nutrient loads that should be managed together with municipal and industrial wastewaters. Copyright 2010 Elsevier Ltd. All rights reserved.

  17. Human Exposure and Health Effects of Inorganic and Elemental Mercury

    Park, Jung-Duck; Zheng, Wei

    2012-01-01

    Mercury is a toxic and non-essential metal in the human body. Mercury is ubiquitously distributed in the environment, present in natural products, and exists extensively in items encountered in daily life. There are three forms of mercury, i.e., elemental (or metallic) mercury, inorganic mercury compounds, and organic mercury compounds. This review examines the toxicity of elemental mercury and inorganic mercury compounds. Inorganic mercury compounds are water soluble with a bioavailability o...

  18. Novel methodology for the study of mercury methylation and reduction in sediments and water using {sup 197}Hg radiotracer

    Ribeiro Guevara, Sergio; Perez Catan, Soledad [Centro Atomico Bariloche, Laboratorio de Analisis por Activacion Neutronica, Bariloche (Argentina); Zizek, Suzana; Repinc, Urska; Jacimovic, Radojko; Horvat, Milena [Jozef Stefan Institute, Department of Environmental Sciences, Ljubljana (Slovenia)

    2007-03-15

    Mercury tracers are powerful tools that can be used to study mercury transformations in environmental systems, particularly mercury methylation, demethylation and reduction in sediments and water. However, mercury transformation studies using tracers can be subject to error, especially when used to assess methylation potential. The organic mercury extracted can be as low as 0.01% of the endogenous labeled mercury, and artefacts and contamination present during methylmercury (MeHg) extraction processes can cause interference. Solvent extraction methods based on the use of either KBr/H{sub 2}SO{sub 4} or HCl were evaluated in freshwater sediments using {sup 197}Hg radiotracer. Values obtained for the {sup 197}Hg tracer in the organic phase were up to 25-fold higher when HCl was used, which is due to the coextraction of {sup 197}Hg{sup 2+} into the organic phase during MeHg extraction. Evaluations of the production of MeHg gave similar results with both MeHg extraction procedures, but due to the higher Hg{sup 2+} contamination of the controls, the uncertainty in the determination was higher when HCl was used. The Hg{sup 2+} contamination of controls in the HCl extraction method showed a nonlinear correlation with the humic acid content of sediment pore water. Therefore, use of the KBr/H{sub 2}SO{sub 4} method is recommended, since it is free from these interferences. {sup 197}Hg radiotracer (T{sub 1/2} = 2.673 d) has a production rate that is about 50 times higher than that of {sup 203}Hg (T{sub 1/2} = 46.595 d), the most frequently used mercury radiotracer. Hence it is possible to obtain a similar level of performance to {sup 203}Hg when it is used it in short-term experiments and produced by the irradiation of {sup 196}Hg with thermal neutrons, using mercury targets with the natural isotopic composition. However, if the 0.15% natural abundance of the {sup 196}Hg isotope is increased, the specific activity of the {sup 197}Hg tracer can be significantly improved. In

  19. Analysis of mercury adsorption at the gibbsite-water interface using the CD-MUSIC model.

    Park, Chang Min

    2018-05-22

    Mercury (Hg), one of the most toxic substances in nature, has long been released during the anthropogenic activity. A correct description of the adsorptive behavior of mercury is important to gain a better insight into its fate and transport in natural mineral surfaces, which will be a prerequisite for the development of surface complexation model for the adsorption processes. In the present study, simulation experiments on macroscopic Hg(II) sorption by gibbsite (α-Al(OH) 3 ), a representative aluminum (hydr)oxide mineral, were performed using the charge distribution and multi-site complexation (CD-MUSIC) approach with 1-pK triple plane model (TPM). For this purpose, several data sets which had already been reported in the literature were employed to analyze the effect of pH, ionic strength, and co-exisiting ions (NO 3 - and Cl - ) on the Hg(II) adsorption onto gibbsite. Sequential optimization approach was used to determine the acidity and asymmetric binding constants for electrolyte ions and the affinity constants of the surface species through the model simulation using FITEQLC (a modified code of FITEQL 4.0). The model successfully incorporated the presence of inorganic ligands at the dominant edge (100) face of gibbsite with consistent surface species, which was evidenced by molecular scale analysis. The model was verified with an independent set of Hg(II) adsorption data incorporating carbonate binding species in an open gibbsite-water system.

  20. STUDY OF POND WATER QUALITY BY THE ASSESSMENT OF PHYSICOCHEMICAL PARAMETERS AND WATER QUALITY INDEX

    Vinod Jena; Satish Dixit; Ravi ShrivastavaSapana Gupta; Sapana Gupta

    2013-01-01

    Water quality index (WQI) is a dimensionless number that combines multiple water quality factors into a single number by normalizing values to subjective rating curves. Conventionally it has been used for evaluating the quality of water for water resources suchas rivers, streams and lakes, etc. The present work is aimed at assessing the Water Quality Index (W.Q.I) ofpond water and the impact of human activities on it. Physicochemical parameters were monitored for the calculation of W.Q.I for ...

  1. Water Quality Evaluation of Spring Waters in Nsukka, Nigeria ...

    Water qualities of springs in their natural state are supposed to be clean and potable. Although, water quality is not a static condition it depends on the local geology and ecosystem, as well as human activities such as sewage dispersion, industrial pollution, use of water bodies as a heat sink, and overuse. The activities on ...

  2. Reducing surface water total and methyl mercury concentrations and bioavailability using a coagulation-wetland system

    Kraus, T. E.; Fleck, J.; Henneberry, Y. K.; Stumpner, E. B.; Krabbenhoft, D. P.; Bachand, P.; Randall, P.

    2013-12-01

    With the recent passage of laws regulating concentrations and loads of mercury (Hg) in surface waters, there is a need to develop management practices that will reduce the export of Hg from both point and non-point sources. Coagulation with metal based salts to remove particles and dissolved organic matter (DOM) from solution is a practice commonly employed by drinking water utilities. Because dissolved Hg is associated with particles and DOM, it follows that Hg should also be removed during the coagulation process and end up associated with the organo-metal precipitate, termed flocculate (floc). The effectiveness of iron- and aluminum-based coagulants for removing both inorganic and methyl mercury (IHg and MeHg, respectively) from solution was demonstrated in laboratory studies conducted on agricultural drainage waters of the Sacramento-San Joaquin Delta: dissolved concentrations of MeHg decreased by 80% while IHg decreased by 97% following coagulation. To test the field application of this technology, samples were collected from the inflows and outflows of wetland treatment cells constructed in the central Delta of California. This replicated field experiment includes three replicates each of three inflow waters treatments: (1) iron sulfate addition, (2) polyaluminum chloride addition, and (3) untreated controls. Water entering and exiting the nine treatment cells was sampled approximately monthly over a 1-year period for total Hg and MeHg in both the dissolved and particulate aqueous phases. Initial results confirm that coagulant addition is removing Hg (total and methyl, particulate and dissolved) from solution and sequestering it in the floc. Seasonal effects on DOM concentration and other factors appear to effect whether passage through the wetland cells alters surface water dissolved organic carbon (DOC) and Hg concentrations. Related studies will examine whether the presence of the floc affects the production and fate of MeHg within the wetland cells. If

  3. Mobility and transport of mercury and methylmercury in peat as a function of changes in water table regime and plant functional groups

    Kristine M. Haynes; Evan S. Kane; Lynette Potvin; Erik A. Lilleskov; Randy Kolka; Carl P. J. Mitchell

    2017-01-01

    Climate change is likely to significantly affect the hydrology, ecology, and ecosystem function of peatlands, with potentially important but unclear impacts on mercury mobility within and transport from peatlands. Using a full-factorial mesocosm approach, we investigated the potential impacts on mercury mobility of water table regime changes (high and low) and...

  4. Environmental hazard analysis - contamination of nutrients, mercury and cesium-137 in natural waters

    Hakanson, L.

    1990-01-01

    Results from some ongoing Swedish research projects on different types of contamination of limnic as well as marine areas are summarized. A brief theoretical outline on the central concepts of the 'meso-scale-type' of environmental hazard analysis, utilizing examples on eutrophication of coastal waters is given. The concepts are further substantiated in two subsequent parts dealing with radioactive cesium and mercury. The idea is to illustrate that the basic concepts for ('real' world/'meso scale') environmental hazard analysis can be used for different substances and different aquatic environments. It is important to give clear, quantifiable definitions of the effect, dose and environmental sensitivity parameters, which should be valid for a defined area and for a defined span of time. All other parameters should be compatible and have the same area and time resolution. (author)

  5. Biochemical parameters of pregnant rats and their offspring exposed to different doses of inorganic mercury in drinking water.

    Oliveira, Cláudia S; Oliveira, Vitor A; Ineu, Rafael P; Moraes-Silva, Lucélia; Pereira, Maria E

    2012-07-01

    This work investigated the effects of low and high doses of inorganic mercury in drinking water on biochemical parameters of pregnant rats and their offspring. Female Wistar rats were treated during pregnancy with 0, 0.2, 0.5, 10 or 50 μg Hg(2+)/mL as HgCl(2). Rats were euthanized on day 20 of pregnancy. Pregnant rats presented a decrease in total water intake in all doses of mercury tested. At high doses, a decrease in the total food intake and in body weight gain was observed. Pregnant rats exposed to 50 μg Hg(2+)/mL presented an increase in kidney relative weight. Mercury exposure did not change serum urea and creatinine levels in any of the doses tested. Moreover, mercury exposure did not change porphobilinogen synthase activity of kidney, liver and placenta from pregnant rats in any of the doses tested, whereas fetuses of pregnant rats exposed to 50 μg Hg(2+)/mL presented an increase in the hepatic porphobilinogen synthase activity. In general, pregnant rats presented alterations due to HgCl(2) exposure in drinking water. However, only the dose 50 μg Hg(2+)/mL appeared to be enough to cross the blood-placenta barrier, since at this dose the fetuses presented change in the porphobilinogen synthase activity. Copyright © 2012 Elsevier Ltd. All rights reserved.

  6. Mercury transport between sediments and the overlying water of the St. Lawrence River area of concern near Cornwall, Ontario

    Delongchamp, Tania M., E-mail: tdelongchamp@intrinsikscience.co [Department of Biology, University of Ottawa, 150 Louis Pasteur, Ottawa, Ontario K1N 6N5 (Canada); Ridal, Jeffrey J. [St. Lawrence River Institute of Environmental Sciences, 2 Belmont Street, Cornwall, Ontario, K6H 4Z1 (Canada); Lean, David R.S. [Department of Biology, University of Ottawa, 150 Louis Pasteur, Ottawa, Ontario K1N 6N5 (Canada); Poissant, Laurier [Meteorological Service of Canada, Atmospheric Toxic Processes Section, Environment Canada, 105 McGill 7th floor (Youville), Montreal, Quebec H2Y 2E7 (Canada); Blais, Jules M., E-mail: jules.blais@uottawa.c [Department of Biology, University of Ottawa, 150 Louis Pasteur, Ottawa, Ontario K1N 6N5 (Canada)

    2010-05-15

    Contaminated sediments in the St. Lawrence River remain a difficult problem despite decreases in emissions. Here, sediment and pore water phases were analyzed for total mercury (THg) and methyl mercury (MeHg) and diffusion from the sediment to the overlying water was 17.5 +- 10.6 SE ng cm{sup -2} yr{sup -1} for THg and 3.8 +- 1.7 SE ng cm{sup -2} yr{sup -1} for MeHg. These fluxes were very small when compared to the particle-bound mercury flux accumulating in the sediment (183 +- 30 SE ng cm{sup -2} yr{sup -1}). Studies have reported that fish from the westernmost site have higher Hg concentrations than fish collected from the other two sites of the Cornwall Area of Concern, which could not be explained by differences in the Hg flux or THg concentrations in sediments, but the highest concentrations of sediment MeHg, and the greatest proportions of MeHg to THg in both sediment and pore water were observed where fish had highest MeHg concentrations. - Sediments in the St. Lawrence area of concern near Cornwall are a net sink for mercury.

  7. Water quality and MTBE water pollution

    Buiatti, M.; Mascini, M.; Monanni, R.; Filipponi, M.; Piangoloni, A.; Mancini, G.

    2001-01-01

    The research project, here presented, was defined with the aim of evaluating the eventual presence of MTBE and the possible relative impact in water destined to human use; the territorial valence of the project was extended to the competence region n. 4 of the Tuscany water authority (AATO n. 4). University of Florence, ARPAT, AATO n. 4 and Nuove Acque SpA, in this role of manager for the integrated water cycle in the country, have productively contributed to the project [it

  8. Management of drinking water quality in Pakistan

    Javed, A.A.

    2003-01-01

    Drinking water quality in both urban and rural areas of Pakistan is not being managed properly. Results of various investigations provide evidence that most of the drinking water supplies are faecally contaminated. At places groundwater quality is deteriorating due to the naturally occurring subsoil contaminants, or by anthropogenic activities. The poor bacteriological quality of drinking water has frequently resulted in high incidence of water borne diseases while subsoil contaminants have caused other ailments to consumers. This paper presents a detailed review of drinking water quality in the country and the consequent health impacts. It identifies various factors contributing to poor water quality and proposes key actions required to ensure safe drinking water supplies to consumers. (author)

  9. A One-Dimensional Hydrodynamic and Water Quality Model for a Water Transfer Project with Multihydraulic Structures

    Yujun Yi

    2017-01-01

    Full Text Available The long Middle Route of the South to North Water Transfer Project is composed of complex hydraulic structures (aqueduct, tunnel, control gate, diversion, culvert, and diverted siphon, which generate complex flow patterns. It is vital to simulate the flow patterns through hydraulic structures, but it is a challenging work to protect water quality and maintain continuous water transfer. A one-dimensional hydrodynamic and water quality model was built to understand the flow and pollutant movement in this project. Preissmann four-point partial-node implicit scheme was used to solve the governing equations in this study. Water flow and pollutant movement were appropriately simulated and the results indicated that this water quality model was comparable to MIKE 11 and had a good performance and accuracy. Simulation accuracy and model uncertainty were analyzed. Based on the validated water quality model, six pollution scenarios (Q1 = 10 m3/s, Q2 = 30 m3/s, and Q3 = 60 m3/s for volatile phenol (VOP and contaminant mercury (Hg were simulated for the MRP. Emergent pollution accidents were forecasted and changes of water quality were analyzed according to the simulations results, which helped to guarantee continuously transferring water for a large water transfer project.

  10. SERS and fluorescence-based ultrasensitive detection of mercury in water.

    Makam, Pandeeswar; Shilpa, Rohilla; Kandjani, Ahmad Esmaielzadeh; Periasamy, Selvakannan R; Sabri, Ylias Mohammad; Madhu, Chilakapati; Bhargava, Suresh Kumar; Govindaraju, Thimmaiah

    2018-02-15

    The development of reliable and ultrasensitive detection marker for mercury ions (Hg 2+ ) in drinking water is of great interest for toxicology assessment, environmental protection and human health. Although many Hg 2+ detection methods have been developed, only few offer sensitivities below 1pM. Herein, we describe a simple histidine (H) conjugated perylene diimide (PDI) bolaamphiphile (HPH) as a dual-responsive optical marker to develop highly selective and sensitive probe as visible (sol-to-gel transformation), fluorescence and SERS-based Hg 2+ sensor platform in the water. Remarkably, HPH as a SERS marker supported on Au deposited monodispersed nanospheres monolayers (Au-MNM) of polystyrene offers an unprecedented selectivity and the best ever reported detection limit (LOD) of 60 attomolar (aM, 0.01 parts-per-quadrillion (ppq)) for Hg 2+ in water. This is ten orders of magnitude lower than the United States Environmental Protection Agency (USEPA) tolerance limit of Hg 2+ in drinking water (10nM, 2 ppb). This simple and effective design principle of host-guest interactions driven fluorescence and SERS-based detection may inspire the future molecular engineering strategies for the development of ultrasensitive toxic analyte sensor platforms. Copyright © 2017 Elsevier B.V. All rights reserved.

  11. Infectious Disinfection: "Exploring Global Water Quality"

    Mahaya, Evans; Tippins, Deborah J.; Mueller, Michael P.; Thomson, Norman

    2009-01-01

    Learning about the water situation in other regions of the world and the devastating effects of floods on drinking water helps students study science while learning about global water quality. This article provides science activities focused on developing cultural awareness and understanding how local water resources are integrally linked to the…

  12. Water Quality Management of Beijing in China

    2000-01-01

    At present, Beijing's water resources are insufficient and will become the limiting factor for sustainable development for the city in the near future. Although efforts have been made to control pollution, water quality degradation has occurred in some of the important surface water supplies, aggravating the water resource shortage. At present, approximately three quarters of the city's wastewater is discharged untreated into the urban river system, resulting in serious pollution and negatively influencing the urban landscape and quality of daily life. To counteract these measures, the city has implemented a comprehensive "Water Quality Management Plan" for the region, encompassing water pollution control, prevention of water body degradation, and improved water quality.The construction of municipal wastewater treatment plants is recognised as fundamental to controlling water pollution, and full secondary treatment is planned to be in place by the year 2015. Significant work is also required to expand the service area of the municipal sewage system and to upgrade and renovate the older sewer systems. The limitation on available water resources has also seen the emphasis shift to low water using industries and improved water conservation. Whilst industrial output has increased steadily over the past 10-15 years at around 10% per annum, industrial water usage has remained relatively constant. Part of the city's water quality management plan has been to introduce a strict discharge permit system, encouraging many industries to install on-site treatment facilities.

  13. Monitoring and assessment of mercury pollution in the vicinity of a chloralkali plant. III. Concentration and genotoxicity of mercury in the industrial effluent and contaminated water of Rushikulya estuary, India.

    Panda, K K; Lenka, M; Panda, B B

    1992-01-01

    Aquatic mercury pollution of the Rushikulya estuary in the vicinity of the chloralkali plant at Ganjam, India was monitored over a period from October 1987 to May 1989. The concentrations of aquatic mercury in the water samples taken from the effluent channel and from different sites along the course of the estuary covering a distance of 2 km were periodically recorded and ranged from 0 to 0.5 mg/l. The bioconcentration and genotoxicity of aquatic mercury in the samples were assessed by the Allium micronucleus (MNC) assay. The frequency of cells with MNC was highly correlated not only with bioconcentrated mercury (root mercury) but also with the levels of aquatic mercury. The threshold assessment values such as effective concentration fifty (EC50) for root growth, lowest effective concentration tested (LECT), and highest ineffective concentration tested (HICT) for induction of MNC in Allium MNC assay for the present aquatic industrial mercury were determined to be 0.14, 0.06 and 0.02 mg/l, respectively.

  14. Bioavailability of mercury in contaminated Oak Ridge watershed and potential remediation of river/runoff/storm water by an aquatic plant - 16319

    Su, Yi; Han, Fengxiang X.; Chen, Jian; Xia, Yunju; Monts, David L.

    2009-01-01

    Historically as part of its national security mission, the U.S. Department of Energy's Y-12 National Security Facility in Oak Ridge, TN, USA acquired a significant fraction of the world's supply of elemental mercury. During the 1950's and 1960's, a large amount of elemental mercury escaped confinement and is still present in the buildings and grounds of the Y-12 Facility and in the Y-12 Watershed. Because of the adverse effects of elemental mercury and mercury compounds upon human health, the Oak Ridge Site is engaged in an on-going effort to monitor and remediate the area. The main thrust of the Oak Ridge mercury remediation effort is currently scheduled for implementation in FY09. In order to more cost effectively implement those extensive remediation efforts, it is necessary now to obtain an improved understanding of the role that mercury and mercury compounds play in the Oak Ridge ecosystem. Most recently, concentrations of both total mercury and methylmercury in fish and water of lower East Fork Poplar Creek (LEFPC) of Oak Ridge increased although the majority of mercury in the site is mercury sulfide. This drives the US DOE and the Oak Ridge Site to study the long-term bioavailability of mercury and speciation at the site. The stability and bioavailability of mercury sulfide as affected by various biogeochemical conditions -presence of iron oxides have been studied. We examined the kinetic rate of dissolution of cinnabar from Oak Ridge soils and possible mechanisms and pathways in triggering the most recent increase of mercury solubility, bioavailability and mobility in Oak Ridge site. The effects of pH and chlorine on oxidative dissolution of cinnabar from cinnabar-contaminated Oak Ridge soils is discussed. On the other hand, aquatic plants might be good candidate for phyto-remediate contaminated waste water and phyto-filtration of collective storm water and surface runoff and river. Our greenhouse studies on uptake of Hg by water lettuce (Pistia stratiotes

  15. Heavy Water Quality Management in HANARO

    Shin, Ho Chul; Lee, Mun; Kim, Hi Gon; Park, Chan Young; Choi, Ho Young; Hur, Soon Ock; Ahn, Guk Hoon

    2008-12-15

    Heavy water quality management in the reflector tank is a very important element to maintain the good thermal neutron flux and to ensure the performance of reflector cooling system. This report is written to provide a guidance for the future by describing the history of the heavy water quality management during HANARO operation. The heavy water quality in the reflector tank has been managed by measuring the electrical conductivity at the inlet and outlet of the ion exchanger and by measuring pH of the heavy water. In this report, the heavy water quality management activities performed in HANARO from 1996 to 2007 ere described including a basic theory of the heavy water quality management, exchanging history of used resin in the reflector cooling system, measurement data of the pH and the electrical conductivity, and operation history of the reflector cooling system.

  16. Environmental mercury exposure, semen quality and reproductive hormones in Greenlandic Inuit and European men

    Mocevic, Emina; Specht, Ina O; Marott, Jacob Louis

    2013-01-01

    Several animal studies indicate that mercury is a male reproductive toxicant, but human studies are few and contradictory. We examined semen characteristics and serum levels of reproductive hormones in relation to environmental exposure to mercury. Blood and semen samples were collected from 529.......024 to 0.110). The association may be due to beneficial effects of polyunsaturated fatty acids (PUFAs), which are contained in seafood and fish. No significant association (P>0.05) was found between blood concentrations of mercury and any of the other measured semen characteristics (semen volume, total...

  17. Prompt gamma-ray activation technique for in-situ analysis of mercury pollution in water

    Khouri, M.C.; Jayanthi, K.A.; Pascholati, P.R.

    1995-01-01

    Industrial and mining pollutants discharged into water are in general distributed homogeneously and we investigated a prompt neutron activation technique for the in-situ analysis, to start with of Hg content in water. The laboratory test employed a 252 Cf neutron source (of ∼ 3 x 10 6 n/s fluence) submerged in a test tank of water of ∼ 500 litres, and to monitor the gamma-ray emission a 4 x 4 NaI (Tl) detector system was employed. In 3000 is time interval trials, for a 46 ppm contamination level of Hg, we observed an excess of counts of ∼ 9.2 σ significance in the energy range of 4000-6500 keV, which can be attributed to the presence of mercury. This test system for a 10 hour monitoring can provide a minimum detectable sensitivity at 4.78 ppm. In the future experiments, we propose to replace the NaI(Tl) detector by a HPGe detector to facilitate simultaneous analyses of pollutants such as cadmium, chlorine, chromium etc for detection at few tenths to tens of ppm levels or better. (author). 5 refs., 2 figs., 2 tabs

  18. Mercury methylation and reduction potentials in marine water: An improved methodology using {sup 197}Hg radiotracer

    Koron, Neza [National Institute of Biology, Marine Biology Station, Fornace 41, 6330 Piran (Slovenia); Bratkic, Arne [Department of Environmental Sciences, ' Jozef Stefan' Institute, Jamova 39, 1000 Ljubljana (Slovenia); Ribeiro Guevara, Sergio, E-mail: ribeiro@cab.cnea.gov.ar [Laboratorio de Analisis por Activacion Neutronica, Centro Atomico Bariloche, Av. Bustillo km 9.5, 8400 Bariloche (Argentina); Vahcic, Mitja; Horvat, Milena [Department of Environmental Sciences, ' Jozef Stefan' Institute, Jamova 39, 1000 Ljubljana (Slovenia)

    2012-01-15

    A highly sensitive laboratory methodology for simultaneous determination of methylation and reduction of spiked inorganic mercury (Hg{sup 2+}) in marine water labelled with high specific activity radiotracer ({sup 197}Hg prepared from enriched {sup 196}Hg stable isotope) was developed. A conventional extraction protocol for methylmercury (CH{sub 3}Hg{sup +}) was modified in order to significantly reduce the partitioning of interfering labelled Hg{sup 2+} into the final extract, thus allowing the detection of as little as 0.1% of the Hg{sup 2+} spike transformed to labelled CH{sub 3}Hg{sup +}. The efficiency of the modified CH{sub 3}Hg{sup +} extraction procedure was assessed by radiolabelled CH{sub 3}Hg{sup +} spikes corresponding to concentrations of methylmercury between 0.05 and 4 ng L{sup -1}. The recoveries were 73.0{+-}6.0% and 77.5{+-}3.9% for marine and MilliQ water, respectively. The reduction potential was assessed by purging and trapping the radiolabelled elemental Hg in a permanganate solution. The method allows detection of the reduction of as little as 0.001% of labelled Hg{sup 2+} spiked to natural waters. To our knowledge, the optimised methodology is among the most sensitive available to study the Hg methylation and reduction potential, therefore allowing experiments to be done at spikes close to natural levels (1-10 ng L{sup -1}). - Highlights: Black-Right-Pointing-Pointer Inorganic mercury methylation and reduction in marine water were studied. Black-Right-Pointing-Pointer High specific activity {sup 197}Hg was used to label Hg{sup 2+} spikes at natural levels. Black-Right-Pointing-Pointer Methylmercury extraction had 73% efficiency for 0.05-4 ng L{sup -1} levels. Black-Right-Pointing-Pointer High sensibility to assess methylation potentials, below 0.1% of the spike. Black-Right-Pointing-Pointer High sensibility also for reduction potentials, as low as 0.001% of the spike.

  19. [Distribution of Mercury in Plants at Water-Level-Fluctuating Zone in the Three Gorges Reservoir].

    Liang, Li; Wang, Yong-min; Li, Xian-yuan; Tang, Zhen-ya; Zhang, Xiang; Zhang, Cheng; WANG, Ding-yong

    2015-11-01

    The mercury (Hg) distribution and storage in plants at water-level-fluctuating zone (WLFZ) in the Three Gorges Reservoir were investigated by analyzing the total mercury(THg) and methylmercury ( MeHg) levels in different parts of plants collected from three typical sites including Shibaozhai, Zhenxi and Hanfeng Lake in WLFZ. The results indicated that THg and MeHg concentrations in plants ranged from (1.62 ± 0.57) to (49.42 ± 3.93) μg x kg(-1) and from (15.27 ± 7.09) to (1 974.67 ± 946.10) ng x kg(-1), respectively. In addition, THg levels in different plant parts followed the trend: root > leaf > stem, and similar trend for MeHg was observed with the highest level in root. An obvious spatial distribution was also found with the THg and MeHg levels in plants in Hanfeng higher than those in the same plants in the other two sampling sites (Shibaozhai and Zhenxi), and there was a difference of THg and MeHg storage in plants in various attitudes. The corresponding THg and MeHg storages were 145.3, 166.4, 124.3 and 88.2 mg x hm(-2), and 1.9, 2.7, 3.6 and 3.2 mg x hm(-2) in 145-150, 150-160, 160-170 and 170-175 m attitudes. The accumulation ability of dominant plants in WLFZ for THg (bioaccumulation factor, BAF 1).

  20. New evidence for surface water ice in small-scale cold traps and in three large craters at the north polar region of Mercury from the Mercury Laser Altimeter

    Deutsch, Ariel N.; Neumann, Gregory A.; Head, James W.

    2017-09-01

    The Mercury Laser Altimeter (MLA) measured surface reflectance, rs, at 1064 nm. On Mercury, most water-ice deposits have anomalously low rs values indicative of an insulating layer beneath which ice is buried. Previous detections of surface water ice (without an insulating layer) were limited to seven possible craters. Here we map rs in three additional permanently shadowed craters that host radar-bright deposits. Each crater has a mean rs value >0.3, suggesting that water ice is exposed at the surface without an overlying insulating layer. We also identify small-scale cold traps (rs >0.3 and permanent shadows have biannual maximum surface temperatures <100 K. We suggest that a substantial amount of Mercury's water ice is not confined to large craters but exists within microcold traps, within rough patches and intercrater terrain.

  1. Principles and Practices of Water Quality Monitoring

    J.L. Michael

    2001-01-01

    There are many activities in forest management that may affect water quality, i.e., timber harvestine, road building,mechanical and chemical site preparation, release operations, fuel reduction,wildlife opening maintenance, etc. How severely they affect water quality depends on how well the person in charge of the operation understands the activity itself, the...

  2. Bacteriological physicochemical quality of recreational water bodies ...

    tinsae

    logical quality, and there are no guidelines (standards) towards the safe use and quality control of recreational water. Under this circumstances, it is neither possible to know the gravity of the problem, nor simple to manage the possible health related risks that are associated with the use of recreational water bodies.

  3. 40 CFR 240.204 - Water quality.

    2010-07-01

    ... 40 Protection of Environment 24 2010-07-01 2010-07-01 false Water quality. 240.204 Section 240.204 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES GUIDELINES FOR THE THERMAL PROCESSING OF SOLID WASTES Requirements and Recommended Procedures § 240.204 Water quality. ...

  4. STREAMFLOW AND WATER QUALITY REGRESSION MODELING ...

    ... downstream Obigbo station show: consistent time-trends in degree of contamination; linear and non-linear relationships for water quality models against total dissolved solids (TDS), total suspended sediment (TSS), chloride, pH and sulphate; and non-linear relationship for streamflow and water quality transport models.

  5. Water quality evaluation of Al-Gharraf river by two water quality indices

    Ewaid, Salam Hussein

    2017-11-01

    Water quality of Al-Gharraf river, the largest branch of Tigris River south of Iraq, was evaluated by the National Sanitation Foundation Water Quality Index (NFS WQI) and the Heavy Metal Pollution Index (HPI) depending on 13 physical, chemical, and biological parameters of water quality measured monthly at ten stations on the river during 2015. The NSF-WQI range obtained for the sampling sites was 61-70 indicating a medium water quality. The HPI value was 98.6 slightly below the critical value for drinking water of 100, and the water quality in the upstream stations is better than downstream due to decrease in water and the accumulation of contaminants along the river. This study explains the significance of applying the water quality indices that show the aggregate impact of ecological factors in charge of water pollution of surface water and which permits translation of the monitoring data to assist the decision makers.

  6. Mercury heavy-metal-induced physiochemical changes and genotoxic alterations in water hyacinths [Eichhornia crassipes (Mart.)].

    Malar, Srinivasan; Sahi, Shivendra Vikram; Favas, Paulo J C; Venkatachalam, Perumal

    2015-03-01

    Mercury heavy metal pollution has become an important environmental problem worldwide. Accumulation of mercury ions by plants may disrupt many cellular functions and block normal growth and development. To assess mercury heavy metal toxicity, we performed an experiment focusing on the responses of Eichhornia crassipes to mercury-induced oxidative stress. E. crassipes seedlings were exposed to varying concentrations of mercury to investigate the level of mercury ions accumulation, changes in growth patterns, antioxidant defense mechanisms, and DNA damage under hydroponics system. Results showed that plant growth rate was significantly inhibited (52 %) at 50 mg/L treatment. Accumulation of mercury ion level were 1.99 mg/g dry weight, 1.74 mg/g dry weight, and 1.39 mg/g dry weight in root, leaf, and petiole tissues, respectively. There was a decreasing trend for chlorophyll a, b, and carotenoids with increasing the concentration of mercury ions. Both the ascorbate peroxidase and malondialdehyde contents showed increased trend in leaves and roots up to 30 mg/L mercury treatment and slightly decreased at the higher concentrations. There was a positive correlation between heavy metal dose and superoxide dismutase, catalase, and peroxidase antioxidative enzyme activities which could be used as biomarkers to monitor pollution in E. crassipes. Due to heavy metal stress, some of the normal DNA bands were disappeared and additional bands were amplified compared to the control in the random amplified polymorphic DNA (RAPD) profile. Random amplified polymorphic DNA results indicated that genomic template stability was significantly affected by mercury heavy metal treatment. We concluded that DNA changes determined by random amplified polymorphic DNA assay evolved a useful molecular marker for detection of genotoxic effects of mercury heavy metal contamination in plant species.

  7. Water-quality assessment of the New England Coastal Basins in Maine, Massachusetts, New Hampshire, and Rhode Island : environmental settings and implications for water quality and aquatic biota

    Flanagan, Sarah M.; Nielsen, Martha G.; Robinson, Keith W.; Coles, James F.

    1999-01-01

    The New England Coastal Basins in Maine, Massachusetts, New Hampshire, and Rhode Island constitute one of 59 study units selected for water-quality assessment as part of the U.S. Geological Survey's National Water-Quality Assessment (NAWQA) program. England Coastal Basins study unit encompasses the fresh surface waters and ground waters in a 23,000 square-mile area that drains to the Atlantic Ocean. Major basins include those of the Kennebec, Androscoggin, Saco, Merrimack, Charles, Blackstone, Taunton, and Pawcatuck Rivers. Defining the environmental setting of the study unit is the first step in designing and conducting a multi-disciplinary regional water-quality assessment. The report describes the natural and human factors that affect water quality in the basins and includes descriptions of the physiography, climate, geology, soils, surface- and ground-water hydrology, land use, and the aquatic ecosystem. Although surface-water quality has greatly improved over the past 30 years as a result of improved wastewater treatment at municipal and industrial wastewater facilities, a number of water-quality problems remain. Industrial and municipal wastewater discharges, combined sewer overflows, hydrologic modifications from dams and water diversions, and runoff from urban land use are the major causes of water-quality degradation in 1998. The most frequently detected contaminants in ground water in the study area are volatile organic compounds, petroleum-related products, nitrates, and chloride and sodium. Sources of these contaminants include leaking storage tanks, accidental spills, landfills, road salting, and septic systems and lagoons. Elevated concentrations of mercury are found in fish tissue from streams and lakes throughout the study area.

  8. Setting water quality criteria for agricultural water reuse purposes

    K. Müller

    2017-06-01

    Full Text Available The use of reclaimed water for agricultural irrigation is practiced worldwide and will increase in the future. The definition of water quality limits is a useful instrument for the assessment of water quality regarding its suitability for irrigation purposes and the performance of wastewater treatment steps. This study elaborates water quality objectives for a water reuse project in a setting where national guidelines do not exist. Internationally established guidelines are therefore applied to the local context. Additional limits for turbidity, total suspended solids, biochemical and chemical oxygen demand, total phosphorus and potassium are suggested to meet the requirements of water reuse projects. Emphasis is put on water quality requirements prior to UV disinfection and nutrient requirements of cultivated crops. The presented values can be of assistance when monitoring reclaimed water quality. To facilitate the realization of water reuse projects, comprehensive and more detailed information, in particular on water quality requirements prior to disinfection steps, should be provided as well as regarding the protection of the irrigation infrastructure.

  9. Does water-level fluctuation affect mercury methylation in wetland soils?

    Branfireun, B.A.; Mitchell, C.P.J.; Iraci, J.M. [Toronto Univ., ON (Canada). Dept. of Geography; Krabbenhoft, D.P. [United States Geological Survey, Middleton, WI (United States); Fowle, D.A. [Kansas Univ., Lawrence, KS (United States). Dept. of Geology; Neudahl, L. [Minnesota Power, Duluth, MN (United States)

    2006-07-01

    Mercury (Hg) concentrations in fish vary considerably in freshwater lakes and reservoirs. However, the variations are not generally consistent with physical factors such as basin characteristics, wetland cover or lake chemistry. Pronounced differences in Hg concentrations in fish have been noted in the reservoirs of the St. Louis River system near Duluth Minnesota. The differences were observed between headwater reservoir systems with seasonal flooding and drawdown, and a peaking reservoir with approximately daily water level fluctuations during seasonal lower flow periods. It was suggested that these differences could be attributed to water level fluctuations in the reservoir which influenced the actual production of methylmercury (MeHg) in the surrounding wetland soils. In response to this hypothesis, the authors investigated the role of water level fluctuation in the production and mobilization of MeHg in sediments from wetlands that lie adjacent to a headwater reservoir, a peaking reservoir, and a nearby natural flowage lake used as a control. Preliminary field surveys of the wetland soils revealed that although the average MeHg concentrations in the headwater and peaking reservoir wetlands were not considerably different, both were much higher than the natural lake. Each site demonstrated high variability, but maximum MeHg concentrations ranged from 29.2 ng/g for the peaking reservoir to 4.44 ng/g at the natural lake. A laboratory experiment was therefore performed in which sediments from each wetland were subjected to different water level regimes. The purpose was to assess Hg methylation potential. Stable Hg isotopes were used at the beginning and end of the experiment. In order to determine if water level fluctuation can significantly change the methylation potential of wetland soils on its own, the microbial consortia will also be assessed during the laboratory experiment.

  10. Impact of RO-desalted water on distribution water qualities.

    Taylor, J; Dietz, J; Randall, A; Hong, S

    2005-01-01

    A large-scale pilot distribution study was conducted to investigate the impacts of blending different source waters on distribution water qualities, with an emphasis on metal release (i.e. corrosion). The principal source waters investigated were conventionally treated ground water (G1), surface water processed by enhanced treatment (S1), and desalted seawater by reverse osmosis membranes (RO). Due to the nature of raw water quality and associated treatment processes, G1 water had high alkalinity, while S1 and RO sources were characterized as high sulfate and high chloride waters, respectively. The blending ratio of different treated waters determined the quality of finished waters. Iron release from aged cast iron pipes increased significantly when exposed to RO and S1 waters: that is, the greater iron release was experienced with alkalinity reduced below the background of G1 water. Copper release to drinking water, however, increased with increasing alkalinity and decreasing pH. Lead release, on the other hand, increased with increasing chloride and decreasing sulfate. The effect of pH and alkalinity on lead release was not clearly observed from pilot blending study. The flat and compact corrosion scales observed for lead surface exposed to S1 water may be attributable to lead concentration less than that of RO water blends.

  11. Water flow experiments and analyses on the cross-flow type mercury target model with the flow guide plates

    Haga, K; Kaminaga, M; Hino, R

    2001-01-01

    A mercury target is used in the spallation neutron source driven by a high-intensity proton accelerator. In this study, the effectiveness of the cross-flow type mercury target structure was evaluated experimentally and analytically. Prior to the experiment, the mercury flow field and the temperature distribution in the target container were analyzed assuming a proton beam energy and power of 1.5 GeV and 5 MW, respectively, and the feasibility of the cross-flow type target was evaluated. Then the average water flow velocity field in the target mock-up model, which was fabricated from Plexiglass for a water experiment, was measured at room temperature using the PIV technique. Water flow analyses were conducted and the analytical results were compared with the experimental results. The experimental results showed that the cross-flow could be realized in most of the proton beam path area and the analytical result of the water flow velocity field showed good correspondence to the experimental results in the case w...

  12. Molecular characterization of mercury resistant bacteria inhabiting polluted water bodies of different geographical locations in India

    Jan, A.T.; Azam, M.; Ali, A.; Haq, Q.M.

    2012-01-01

    Mercury pollution is a major environmental problem that arises as a result of natural processes as well as from anthropogenic sources. In response to toxic mercury compounds, microbes have developed astonishing array of resistance systems to detoxify them. To address this challenge, this study was

  13. Infiltration behaviour of elemental mercury DNAPL in fully and partially water saturated porous media

    D'Aniello, Andrea; Hartog, Niels; Sweijen, Thomas; Pianese, Domenico

    Mercury is a contaminant of global concern due to its harmful effects on human health and for the detrimental consequences of its release in the environment. Sources of liquid elemental mercury are usually anthropogenic, such as chlor-alkali plants. To date insight into the infiltration behaviour of

  14. Bioaccumulation of mercury and polychlorinated dibenzo-p-dioxins and dibenzofurans in salty water organisms.

    Liao, Pei-Yu; Liu, Chen-Wuing; Liu, Wen-Yao

    2016-01-01

    Mercury and polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) accumulate in organisms through food webs and exert potentially toxic effects on aquatic organisms and humans. This study examined the levels of mercury and PCDD/Fs in organisms and sediment samples collected from a saltwater pond at the An-Shun site, a chloralkali factory that shut down in Tainan City, Taiwan. It was also a pentachlorophenol production plant. After the factories were shut down in the 1980s, mercury and PCDD/Fs contamination remained, posing severe health hazards. The correlation between PCDD/Fs congener accumulation patterns in distinct fish organs and the sediment was evaluated. Mercury and PCDD/Fs levels in all the fish samples exceeded food safety limits, and the concentrations of mercury and PCDD/Fs in each species were closely correlated (n = 12, Spearman's rank correlation [R] = 0.811, p mercury concentrations were positively but non-significantly correlated with the weight (n = 11, R = 0.741, p mercury concentration was correlated with organism weight and length, whereas the PCDD/Fs concentration was associated with organ lipid content. The study results are valuable for assessing the health risks associated with ingesting mercury- and PCFF/F-contaminated seafood from the study site.

  15. A global ocean inventory of anthropogenic mercury based on water column measurements

    Lamborg, C.H.; Hammerschmidt, C.R.; Bowman, K.L.; Swarr, G.J.; Munson, K.M.; Ohnemus, D.C.; Lam, P.L.; Heimbürger, L.-E.; Rijkenberg, M.J.A.; Saito, M.A.

    2014-01-01

    Mercury is a toxic, bioaccumulating trace metal whose emissions to the environment have increased significantly as a result of anthropogenic activities such as mining and fossil fuel combustion. Several recent models have estimated that these emissions have increased the oceanic mercury inventory by

  16. Water quality in okara and its suburbs

    Butt, M.T.; Imtiaz, N.; Athar, M.

    2007-01-01

    Ground water samples (70), collected from Okara and its sburbs were studied. Thirty samples were collected from municipal supply of urban areas while forty from deep water pumps of non-urban areas. The samples were investigated for various physiochemical parameters. Outcome of the study is that ground water of municipal supply area is suitable for human consumption while the water quality of non supply area is slightly brackish to saline and nitrate content is high above the acceptable levels of drinking water quality. (author)

  17. [Mercury dynamics of several plants collected from the water-level fluctuation zone of the Three Gorges Reservoir area during flooding and its impact on water body].

    Zhang, Xiang; Zhang, Cheng; Sun, Rong-guo; Wang, Ding-yong

    2014-12-01

    Submerged plants are a major source for the abnormal elevation of methylmercury in reservoir. Several specific plants (Echinochloa crusgalli, Cynodondactylon and Corn stover) were collected and inundated in a simulated aquatic environment in the laboratory for investigating the mercury (Hg) dynamics in plants and the release process into water, aiming to find out the properties of Hg dynamics of plants under inundation conditions and its impact on water body in the Water-Level Fluctuation Zone of the Three Gorges Reservoir Area. The results showed that the contents of total mercury in several plants were in the range of 9. 21-12.07 ng x g(-1), and the percentage content of methylmercury (MeHg) was about 1%-2%. The content of total mercury (THg) in plants gradually decreased, by 35.81%-55.96%, whereas that of the dissolved mercury (DHg) increased sharply, by 103.23% -232.15%, which indicated an emission of Hg from plants to water in the process of decomposition. Furthermore, the state of inundation provided sufficient conditions for the methylation process in plants and therefore caused an increase of the content of methylmercury in the plant residues, which was 3.04-6.63 times as much as the initial content. The concentration of dissolved methylmercury (DMeHg) in the overlying water also increased significantly by 14.84- 16.05 times compared with the initial concentration. Meanwhile, the concentration of dissolved oxygen (DO) in the overlying water was significantly and negatively correlated with DMeHg. On the other hand, the concentration of dissolved organic carbon (DOC) in the overlying water was significantly and positively correlated with DMeHg. During the whole inundation period, the increase of DHg in the overlying water accounted for 41.74% -47.01% of the total amount of THg emission, and there was a negative correlation between the content of THg in plant residues and that of DHg in the overlying water.

  18. State of radionuclides in seawater. Comparison of natural stable and artificial radioactive isotope s of mercury and zinc in natural waters of the arid zone of the USSR

    Rakhmatov, U; Khikmatov, K; Kist, A.A.; Kulmatov, R.A.; Teshabaev, S.T.; Volkov, A.A.

    1986-01-01

    This paper studies the state of stable and artificial radioactive isotopes of merury and zinc in natural waters of the arid zone of the USSR by radioactivity and radiochemical methods. Convergent results have been obtained for the dissolved forms of mercury and zinc in natural waters of the arid zone in a comparison of the results of radioactivation analysis and laboratory simulation using the radionuclides mercury-203 and zinc-65

  19. Water quality impacts of forest fires

    Tecle Aregai; Daniel Neary

    2015-01-01

    Forest fires have been serious menace, many times resulting in tremendous economic, cultural and ecological damage to many parts of the United States. One particular area that has been significantly affected is the water quality of streams and lakes in the water thirsty southwestern United States. This is because the surface water coming off burned areas has resulted...

  20. Dielectric Barrier Discharge based Mercury-free plasma UV-lamp for efficient water disinfection.

    Prakash, Ram; Hossain, Afaque M; Pal, U N; Kumar, N; Khairnar, K; Mohan, M Krishna

    2017-12-12

    A structurally simple dielectric barrier discharge based mercury-free plasma UV-light source has been developed for efficient water disinfection. The source comprises of a dielectric barrier discharge arrangement between two co-axial quartz tubes with an optimized gas gap. The outer electrode is an aluminium baked foil tape arranged in a helical form with optimized pitch, while the inner electrode is a hollow aluminium metallic rod, hermetically sealed. Strong bands peaking at wavelengths 172 nm and 253 nm, along with a weak band peaking at wavelength 265 nm have been simultaneously observed due to plasma radiation from the admixture of xenon and iodine gases. The developed UV source has been used for bacterial deactivation studies using an experimental setup that is an equivalent of the conventional house-hold water purifier system. Deactivation studies for five types of bacteria, i.e., E. coli, Shigella boydii, Vibrio, Coliforms and Fecal coliform have been demonstrated with 4 log reductions in less than ten seconds.

  1. Characteristics of Pelargonium radula as a mercury bioindicator for safety assessment of drinking water.

    Majid, N A; Phang, I C; Darnis, D S

    2017-10-01

    Identification of Pelargonium radula as bioindicator for mercury (Hg) detection confers a new hope for monitoring the safety of drinking water consumption. Hg, like other non-essential metals, inflicts the deterioration of biological functions in human and other creatures. In the present study, effects of Hg on the physiology and biochemical content of P. radula were undertaken to understand the occurrence of the morphological changes observed. Young leaves of P. radula were treated with different concentrations of Hg-containing solution (0.5, 1.0 and 2.0 ppb) along with controls for 4 h, prior to further analysis. Elevated Hg concentration in treatment solution significantly prompted an increased accumulation of Hg in the leaf tissues. Meanwhile, total protein, chlorophyll and low molecular mass thiol contents (cysteine, glutathione and oxidized glutathione) decreased as Hg accumulation increased. However, phytochelatin 2 productions were induced in the treated leaves, in comparison to the control. Based on these findings, it is postulated that as low as 0.5 ppb of Hg interferes with the metabolic processes of plant cells, which was reflected from the morphological changes exhibited on P. radula leaves-the colour of the Hg-treated leaves changed from green to yellowish-brown, became chlorosis and wilted. Changes in the tested characteristics of plant are closely related to the Hg-induced morphological changes on P. radula leaves, a potential bioindicator for detecting Hg in drinking water.

  2. Source identification and mass balance studies of mercury in Lake An-dong, S. Korea

    Han, J.; Byeon, M.; Yoon, J.; Park, J.; Lee, M.; Huh, I.; Na, E.; Chung, D.; Shin, S.; Kim, Y.

    2009-12-01

    In this study, mercury and methylmercury were measured in atmospheric, tributary, open-lake water column, sediment, planktons and fish samples in the catchments area of Lake An-dong, S. Korea. Lake An-dong, an artificial freshwater lake is located on the upstream of River Nak-dong. It has 51.5 km2 of open surface water and 1.33 year of hydraulic residence time. It is a source of drinking water for 0.3 million S. Koreans. Recently, the possibilities of its mercury contamination became an issue since current studies showed that the lake had much higher mercury level in sediment and certain freshwater fish species than any other lakes in S. Korea. This catchments area has the possibilities of historical mercury pollution by the location of more than 50 abandoned gold mines and Young-poong zinc smelter. The objective of this study was to develop a mercury mass balance and identify possible mercury sources in the lake. The results of this study are thus expected to offer valuable insights for the sources of mercury loading through the watershed. In order to estimate the mercury flux, TGM, RGM and particulate mercury were measured using TEKRAN 2537 at the five sites surrounding Lake An-dong from May, 2009 with wet and dry deposition. The fate and transport of mercury in water body were predicted by using EFDC (Environmental Dynamic Fluid Code) and Mercury module in WASP7 (Water quality analysis program) after subsequent distribution into water body, sediments, followed by bioaccumulation and ultimate uptake by humans. The mercury mass balance in Young-poong zinc smelter was also pre-estimated by measuring mercury content in zinc ores, emission gases, sludge, wastewater and products.

  3. Habitat quality, water quality and otter distribution

    Christopher Mason

    1995-12-01

    Full Text Available Abstract In recent decades the otter (Lutra lutra has declined over much of Europe. Good habitat has been shown to be essential to otters. Specific elements of cover have been identified in some studies but the minimum cover requirements to support otter populations are not known. These are likely to vary in relation to other factors, such as disturbance. Habitat destruction has been severe in many areas of Europe. Water quantity is important to otters, especially where low flows destroy the food base, namely fish. However the minimum food requirements to support populations are not known. The main cause of the decline in otter populations is almost certainly bioaccumulating pollutants, especially PCBs. These are likely to be inhibiting recolonization in many areas. In Britain, catchment distribution of otters within regions is negatively correlated to mean PCB levels in otter spraints, and these are indicative of tissue levels. PCBs have been found in all samples studied. Current EC statutory monitoring is inadequate to protect otter populations from bioaccumulating contaminants. Standards are presented here for otter protection. More fundamental research is required to refine our understanding of the requirements of the otter. Riassunto Qualità ambientale, qualità dell'acqua e distribuzione della lontra - Negli ultimi decenni la lontra (Lutra lutra è diminuita su buona parte del suo areale europeo, dove particolarmente pesante è stata la distruzione di ambienti favorevoli. Habitat qualitativamente idonei sono essenziali per la sopravvivenza della specie. In alcuni studi, specifici parametri di copertura vegetale dei corpi idrici sono stati ritenuti importanti per la specie, ma quale sia il valore minimo di copertura riparia in grado di supportare una popolazione resta sconosciuto. I parametri di copertura variano probabilmente in relazione ad altri fattori, quali, ad

  4. water quality assessment of underground and surface water ...

    Dr Osondu

    Water quality assessment in the Ethiopian highlands is crucial owing to increasing ... and provide information for formulating appropriate framework for an integrated ... with four seasons (rainy, dry period, small rains ..... treatment. Annual conference proceedings, American Water Works ... Towns' water supply and sanitation.

  5. Assesment of the water quality and prevalence of water borne ...

    The water related diseases that were consistently reported and diagnosed for the period are cholera (3.37%), diarrhea (44.94%), dysentery (16.85%), and typhoid fever (34.83%). The quality of the water and the prevalence of water related diseases in the hospitals were casually related to the contamination of the river in the ...

  6. Atmospheric mercury dispersion modelling from two nearest hypothetical point sources

    Al Razi, Khandakar Md Habib; Hiroshi, Moritomi; Shinji, Kambara [Environmental and Renewable Energy System (ERES), Graduate School of Engineering, Gifu University, Yanagido, Gifu City, 501-1193 (Japan)

    2012-07-01

    The Japan coastal areas are still environmentally friendly, though there are multiple air emission sources originating as a consequence of several developmental activities such as automobile industries, operation of thermal power plants, and mobile-source pollution. Mercury is known to be a potential air pollutant in the region apart from SOX, NOX, CO and Ozone. Mercury contamination in water bodies and other ecosystems due to deposition of atmospheric mercury is considered a serious environmental concern. Identification of sources contributing to the high atmospheric mercury levels will be useful for formulating pollution control and mitigation strategies in the region. In Japan, mercury and its compounds were categorized as hazardous air pollutants in 1996 and are on the list of 'Substances Requiring Priority Action' published by the Central Environmental Council of Japan. The Air Quality Management Division of the Environmental Bureau, Ministry of the Environment, Japan, selected the current annual mean environmental air quality standard for mercury and its compounds of 0.04 ?g/m3. Long-term exposure to mercury and its compounds can have a carcinogenic effect, inducing eg, Minamata disease. This study evaluates the impact of mercury emissions on air quality in the coastal area of Japan. Average yearly emission of mercury from an elevated point source in this area with background concentration and one-year meteorological data were used to predict the ground level concentration of mercury. To estimate the concentration of mercury and its compounds in air of the local area, two different simulation models have been used. The first is the National Institute of Advanced Science and Technology Atmospheric Dispersion Model for Exposure and Risk Assessment (AIST-ADMER) that estimates regional atmospheric concentration and distribution. The second is the Hybrid Single Particle Lagrangian Integrated trajectory Model (HYSPLIT) that estimates the atmospheric

  7. Mechanisms affecting water quality in an intermittent piped water supply.

    Kumpel, Emily; Nelson, Kara L

    2014-01-01

    Drinking water distribution systems throughout the world supply water intermittently, leaving pipes without pressure between supply cycles. Understanding the multiple mechanisms that affect contamination in these intermittent water supplies (IWS) can be used to develop strategies to improve water quality. To study these effects, we tested water quality in an IWS system with infrequent and short water delivery periods in Hubli-Dharwad, India. We continuously measured pressure and physicochemical parameters and periodically collected grab samples to test for total coliform and E. coli throughout supply cycles at 11 sites. When the supply was first turned on, water with elevated turbidity and high concentrations of indicator bacteria was flushed out of pipes. At low pressures (water was delivered with a chlorine residual and at pressures >17 psi.

  8. Water quality for the year 2000

    Newman, A.

    1991-01-01

    Under an umbrella labeled Water Quality 2000, 86 organizations - ranging from the Natural Resources Defense Council to the Chemical Manufacturers Association - have reached a consensus on the major water quality problems currently facing the US. Their broad-based conclusions have been released in a report entitled Challenges for the Future, which represents one step in an ongoing discussion among representatives of these diverse groups on improving water quality. Although the report presents a long-term view, William Matuszeski from EPA described the document as a superb background for the upcoming debate over reauthorization of the Clean Water Act. In general terms, the report cites the major sources of current water problems as agricultural and urban runoff, especially following storms; airborne pollutants; continued dumping of toxic wastes; accidental spills; overharvesting of fish and shellfish; habitat competition from exotic species; and land and water use practices. This article summarizes some of the findings

  9. Dragonfly Mercury Project—A citizen science driven approach to linking surface-water chemistry and landscape characteristics to biosentinels on a national scale

    Eagles-Smith, Collin A.; Nelson, Sarah J.; Willacker,, James J.; Flanagan Pritz, Colleen M.; Krabbenhoft, David P.

    2016-02-29

    Mercury is a globally distributed pollutant that threatens human and ecosystem health. Even protected areas, such as national parks, are subjected to mercury contamination because it is delivered through atmospheric deposition, often after long-range transport. In aquatic ecosystems, certain environmental conditions can promote microbial processes that convert inorganic mercury to an organic form (methylmercury). Methylmercury biomagnifies through food webs and is a potent neurotoxicant and endocrine disruptor. The U.S. Geological Survey (USGS), the University of Maine, and the National Park Service (NPS) Air Resources Division are working in partnership at more than 50 national parks across the United States, and with citizen scientists as key participants in data collection, to develop dragonfly nymphs as biosentinels for mercury in aquatic food webs. To validate the use of these biosentinels, and gain a better understanding of the connection between biotic and abiotic pools of mercury, this project also includes collection of landscape data and surface-water chemistry including mercury, methylmercury, pH, sulfate, and dissolved organic carbon and sediment mercury concentration. Because of the wide geographic scope of the research, the project also provides a nationwide “snapshot” of mercury in primarily undeveloped watersheds.

  10. Water quality issues and status in Pakistan

    Kahlown, M.A.; Tahir, M. A.; Ashraf, M.

    2005-01-01

    Per capita water availability in Pakistan has dropped drastically during the last fifty years. Recent extended droughts have further aggravated the situation. In order to meet the shortage and crop water requirements, groundwater is being used extensively in the Indus Basin. Groundwater is also the main source of water for drinking and industrial uses. This increased pressure on groundwater has lowered the water table in many cities. It is reported that water table has dropped by more than 3 m in many cities. This excessive use of groundwater has seriously affected the quality of groundwater and has increased the incidences of water-borne diseases many folds. A recent water quality study has shown that out of 560,000 tube wells of Indus Basin, about 70 percent are pumping sodic water. The use of sodic water has in turn affected the soil health and crop yields. This situation is being further aggravated due to changes in climate and rainfall patterns. To monitor changes in surface and groundwater quality and groundwater levels, Pakistan Council of Research in Water Resources has undertaken a countrywide programme of water quality monitoring. This programme covers twenty-one cities from the four provinces, five rivers, 10 storage reservoirs and lakes and two main drains of Pakistan. Under this programme a permanent monitoring network is established from where water samples are collected and analyzed once every year. The collected water samples are analyzed for aesthetic, chemical and bacteriological parameters to determine their suitability for agricultural, domestic and industrial uses. The results of the present study indicate serious contamination in many cities. Excessive levels of arsenic, fluoride and sodium have been detected in many cities. This paper highlights the major water quality issues and briefly presents the preliminary results of the groundwater analysis for major cities of Pakistan. (author)

  11. Quality Assurance for Iraqi Bottled Water Specifications

    May George Kassir

    2015-10-01

    Full Text Available In this research the specifications of Iraqi drinking bottled water brands are investigated throughout the comparison between local brands, Saudi Arabia and the World Health Organization (WHO for bottled water standard specifications. These specifications were also compared to that of Iraqi Tap Water standards. To reveal variations in the specifications for Iraqi bottled water, and above mentioned standards some quality control tools are conducted for more than 33% of different bottled water brands (of different origins such as spring, purified,..etc in Iraq by investigating the selected quality parameters registered on their marketing labels. Results employing Minitab software (ver. 16 to generate X bar, and Pareto chart. It was found from X bar charts that the quality parameters of some drinking bottled water brands are not within Iraqi standards set by the “Central Agency for Standardization and Quality Control” such as pH values, Fe, Na, and Mg concentrations. While the comparison of previously mentioned standard specifications through radar chart many important issues are detected such as the absence of lower limits the whole bottled water quality parameters such as for Na and Mg also the radar chart shows that Iraqi bottled and tap water specifications are almost equal in their quality values. Also the same chart pictured the limited range of Iraqi specifications compared to that of Saudi Arabia, and WHO and the need to introduce other water specifications such as K, Na, etc. This confirms the need to improve Iraqi bottled water specifications since it was introduced on 2000. These results also highlighted the weakness of quality assurance activities since only 33 % of the investigated companies registered the whole water quality specifications as shown in Pareto chart. Other companies do not register any quality characteristics. Also certain companies should be stopped due to non-conforming specifications, yet these companies are

  12. GKI water quality studies. Progress report

    Hutchinson, D L

    1980-01-01

    GKI water quality data collected in 1978 and early 1979 was evaluated with the objective of developing preliminary characterizations of native groundwater and retort water at Kamp Kerogen, Uintah County, Utah. Restrictive analytical definitions were developed to describe native groundwater and GKI retort water in an effort to eliminate from the sample population both groundwater samples affected by retorting and retort water samples diluted by groundwater. Native groundwater and retort water sample analyses were subjected to statistical manipulation and testing to summarize the data to determine the statistical validity of characterizations based on the data available, and to identify probable differences between groundwater and retort water based on available data. An evaluation of GKI water quality data related to developing characterizations of native groundwater and retort water at Kamp Kerogen was conducted. GKI retort water and the local native groundwater both appeared to be of very poor quality. Statistical testing indicated that the data available is generally insufficient for conclusive characterizations of native groundwater and retort water. Statistical testing indicated some probable significant differences between native groundwater and retort water that could be determined with available data. Certain parameters should be added to and others deleted from future laboratory analyses suites of water samples.

  13. Air/water exchange of mercury in the Everglades I: the behavior of dissolved gaseous mercury in the Everglades Nutrient Removal Project

    Zhang; Lindberg

    2000-10-02

    From 1996 to 1998 we determined dissolved gaseous mercury (DGM) in waters of the Everglades Nutrient Removal Project (ENR), a constructed wetlands. The concentrations of DGM measured in these waters (mean 7.3 +/- 9.5 pg l(-1)) are among the lowest reported in the literature, and suggest a system often near or slightly above equilibrium with Hg in ambient air. DGM exhibited both seasonal and diel trends, peaking at midday and during the summer. A simple box budget model of DGM in waters of the Everglades was developed using an interactive spreadsheet based on a mass balance among light-induced reduction of HgII (production of DGM), Hg0 oxidation (removal), and Hg0 evasion in a box (water column) consisting of a surface region with sunlight available and a lower dark region. The modeling results suggest high sensitivity of hourly DGM concentrations to DGM production rates and initial DGM levels. The sensitivity to Hg oxidation is lower than the sensitivity to DGM production. The model performance demonstrates successful simulations of a variety of DGM trends in the Everglades. In particular, it clearly demonstrates how it is possible to measure comparable rates of evasion over several Everglades sites with different DGM concentrations.

  14. Surface Water Quality Monitoring Sites

    Minnesota Department of Natural Resources — The MN Department of Agriculture (MDA) is charged with periodically collecting and analyzing water samples from selected locations throughout the state to determine...

  15. Historical releases of mercury to air, land, and water from coal combustion.

    Streets, David G; Lu, Zifeng; Levin, Leonard; Ter Schure, Arnout F H; Sunderland, Elsie M

    2018-02-15

    Coal combustion is one of the largest contemporary sources of anthropogenic mercury (Hg). It releases geologically sequestered Hg to the atmosphere, and fly ash can contaminate terrestrial and aquatic systems. We estimate that coal combustion has released a cumulative total of 38.0 (14.8-98.9, 80% C.I.) Gg (gigagrams, 10 9 g or thousand tonnes) of Hg to air, land, and water up to the year 2010, most of which (97%) has occurred since 1850. The rate of release has grown by two orders of magnitude from 0.01Ggyr -1 in 1850 to 1Ggyr -1 in 2010. Geographically, Asia and Europe each account for 32% of cumulative releases and an additional 18% is from North America. About 26.3 (10.2-68.3) Gg, 71% of the total, were directly emitted to the atmosphere, mostly from the industrial (45%) and power generation (36%) sectors, while the remainder was disposed of to land and water bodies. While Europe and North America were the major contributing regions until 1950, Asia has surpassed both in recent decades. By 2010, Asia was responsible for 69% of the total releases of Hg from coal combustion to the environment. Control technologies installed on major emitting sources capture mainly particulate and divalent Hg, and therefore the fraction of elemental Hg in emissions from coal combustion has increased over time from 0.46 in 1850 to 0.61 in 2010. About 11.8 (4.6-30.6) Gg of Hg, 31% of the total, have been transferred to land and water bodies through the disposal or utilization of Hg-containing combustion waste and collected fly ash/FGD waste; approximately 8.8Gg of this Hg have simply been discarded to waste piles or ash ponds or rivers. Copyright © 2017 Elsevier B.V. All rights reserved.

  16. Drinking water quality concerns and water vending machines

    McSwane, D.Z.; Oleckno, W.A.; Eils, L.M.

    1994-01-01

    Drinking water quality is a vital public health concern to consumers and regulators alike. This article describes some of the current microbiological, chemical, and radiological concerns about drinking water and the evolution of water vending machines. Also addressed are the typical treatment processes used in water vending machines and their effectiveness, as well as a brief examination of a certification program sponsored by the National Automatic Merchandising Association (NAMA), which provides a uniform standard for the design and construction of food and beverage vending machines. For some consumers, the water dispensed from vending machines is an attractive alternative to residential tap water which may be objectionable for aesthetic or other reasons

  17. Analysis of Sources and Sinks of Mercury in the Urban Water Cycle of Frankfurt am Main, Germany

    Imke Fricke

    2015-11-01

    Full Text Available Mercury (Hg is still a focus of environmental research, since its levels in fish frequently exceed the Environmental Quality Standard (EQS of 20 µg/kg for biota defined by the European Water Framework Directive (Directive 2008/105/EC. Current Hg levels in Abramis brama from German rivers are in the range of 73–346 µg/kg wet weight (2009 and exceed the EQS by a factor of 3.7–17.3. Therefore, it is important to identify the sources of Hg pollution in the aquatic environment and to develop effective strategies for reducing the input into associated river systems. The aim of the present study was to analyze Hg in the urban water cycle of the city of Frankfurt am Main, Germany. Samples were taken from the river Main crosscutting the city and its tributaries. In addition, precipitation, stormwater runoff, effluents of two municipal WWTPs, and stormwater management structures such as combined sewer overflows and stormwater retention basins have been analyzed. Loads of Hg have been determined based on the measured concentrations and a Hg mass balance for the aquatic system was created. A total of 160 water samples were analyzed by cold vapor atomic fluorescence spectroscopy (CVAFS according to US EPA Method 1631. Results from the mass balance have shown that approximately 5 kg Hg/a enter and 15 kg Hg/a leave the study area of Frankfurt am Main via the river Main. The largest amount of Hg (24.58 kg/a throughout the urban water cycle of Frankfurt am Main is transported via wastewater. However, municipal WWTPs in Frankfurt am Main have been identified as the largest Hg sink, since 99.7% (24.5 kg/a of the Hg is shifted from the sewage water and stormwater during treatment into the sewage sludge. Thus, the increase of the Hg load in the river Main from 5 to 15 kg/a has to be attributed to other sources such as 3 industrial WWTPs, groundwater and non-treated stormwater runoff during heavy rain events.

  18. 40 CFR 130.3 - Water quality standards.

    2010-07-01

    ... 40 Protection of Environment 21 2010-07-01 2010-07-01 false Water quality standards. 130.3 Section... QUALITY PLANNING AND MANAGEMENT § 130.3 Water quality standards. A water quality standard (WQS) defines the water quality goals of a water body, or portion thereof, by designating the use or uses to be made...

  19. Collection of Condensate Water: Global Potential and Water Quality Impacts

    Loveless, Kolin Joseph

    2012-12-28

    Water is a valuable resource throughout the world, especially in hot, dry climates and regions experiencing significant population growth. Supplies of fresh water are complicated by the economic and political conditions in many of these regions. Technologies that can supply fresh water at a reduced cost are therefore becoming increasingly important and the impact of such technologies can be substantial. This paper considers the collection of condensate water from large air conditioning units as a possible method to alleviate water scarcity issues. Using the results of a climate model that tested data collected from 2000 to 2010, we have identified areas in the world with the greatest collection potential. We gave special consideration to areas with known water scarcities, including the coastal regions of the Arabian Peninsula, Sub-Saharan Africa and South Asia. We found that the quality of the collected water is an important criterion in determining the potential uses for this water. Condensate water samples were collected from a few locations in Saudi Arabia and detailed characterizations were conducted to determine the quality of this water. We found that the quality of condensate water collected from various locations and types of air conditioners was very high with conductivities reaching as low as 18 μS/cm and turbidities of 0. 041 NTU. The quality of the collected condensate was close to that of distilled water and, with low-cost polishing treatments, such as ion exchange resins and electrochemical processes, the condensate quality could easily reach that of potable water. © 2012 Springer Science+Business Media Dordrecht.

  20. General introduction for the “National field manual for the collection of water-quality data”

    ,

    2018-02-28

    BackgroundAs part of its mission, the U.S. Geological Survey (USGS) collects data to assess the quality of our Nation’s water resources. A high degree of reliability and standardization of these data are paramount to fulfilling this mission. Documentation of nationally accepted methods used by USGS personnel serves to maintain consistency and technical quality in data-collection activities. “The National Field Manual for the Collection of Water-Quality Data” (NFM) provides documented guidelines and protocols for USGS field personnel who collect water-quality data. The NFM provides detailed, comprehensive, and citable procedures for monitoring the quality of surface water and groundwater. Topics in the NFM include (1) methods and protocols for sampling water resources, (2) methods for processing samples for analysis of water quality, (3) methods for measuring field parameters, and (4) specialized procedures, such as sampling water for low levels of mercury and organic wastewater chemicals, measuring biological indicators, and sampling bottom sediment for chemistry. Personnel who collect water-quality data for national USGS programs and projects, including projects supported by USGS cooperative programs, are mandated to use protocols provided in the NFM per USGS Office of Water Quality Technical Memorandum 2002.13. Formal training, for example, as provided in the USGS class, “Field Water-Quality Methods for Groundwater and Surface Water,” and field apprenticeships supplement the guidance provided in the NFM and ensure that the data collected are high quality, accurate, and scientifically defensible.

  1. Aluminum drinking water treatment residuals (Al-WTRs) as sorbent for mercury: Implications for soil remediation.

    Hovsepyan, Anna; Bonzongo, Jean-Claude J

    2009-05-15

    The potential of readily available and non-hazardous waste material, aluminum drinking water treatment residuals (Al-WTRs), to efficiently sorb and immobilize mercury (Hg) from aqueous solutions was evaluated. Al-WTR samples with average specific surface area of 48m(2)/g and internal micropore surface area of 120m(2)/g were used in a series of batch sorption experiments. Obtained sorption isotherms indicated a strong affinity of Hg for Al-WTRs. Using the Langmuir adsorption model, a relatively high maximum sorption capacity of 79mg Hg/g Al-WTRs was determined. Sorption kinetic data was best fit to a pseudo-first-order model, while the use of the Weber-Morris and Bangham models suggested that the intraparticle diffusion could be the rate-limiting step. Also, Al-WTRs effectively immoblized Hg in the pH range of 3-8. The results from these short-term experiments demonstrate that Al-WTRs can be effectively used to remove Hg from aqueous solutions. This ability points to the potential of Al-WTRs as a sorbent in soil remediation techniques based on Hg-immobilization.

  2. Insights into the mechanisms of mercury sorption onto aluminum based drinking water treatment residuals.

    Deliz Quiñones, Katherine; Hovsepyan, Anna; Oppong-Anane, Akua; Bonzongo, Jean-Claude J

    2016-04-15

    Several studies have demonstrated the ability of drinking water treatment residuals (WTRs) to efficiently sorb metal cations from aqueous solutions. Reported results have stimulated interest on the potential use of WTRs as sorbent for metal removal from contaminated aqueous effluents as well as in metal immobilization in contaminated soils. However, knowledge on mechanisms of metal sorption by WTRs remains very limited and data on the long-term stability of formed metal-WTR complexes as a function of changing key environmental parameters are lacking. In this study, chemical selective sequential extraction (SSE), scanning electron microscopy combined with X-ray energy dispersive spectrometer (SEM-EDS), and X-ray photoelectron spectroscopy (XPS) were used to gain insight into the different mechanisms of mercury (Hg) binding to aluminum based WTR (Al-WTRs). Results from sorption studies show that a significant portion of Hg becomes incorporated in the operationally defined residual fraction of Al-WTRs, and therefore, not prone to dissolution and mobility. The results of solid phase analyses suggested that Hg immobilization by Al-WTR occurs largely through its binding to oxygen donor atoms of mineral ligands driven by a combination of electrostatic forces and covalent bonding. Copyright © 2016 Elsevier B.V. All rights reserved.

  3. Petroleum oil and mercury pollution from shipwrecks in Norwegian coastal waters.

    Ndungu, Kuria; Beylich, Björnar A; Staalstrøm, André; Øxnevad, Sigurd; Berge, John A; Braaten, Hans Fredrik Veiteberg; Schaanning, Morten; Bergstrøm, Rune

    2017-09-01

    Worldwide there are tens of thousands of sunken shipwrecks lying on the coastal seabed. These potentially polluting wrecks (PPW) are estimated to hold 3-25milliont of oil. Other hazardous cargo in PPW includes ordnance, chemicals and radioactive waste. Here, we present and discuss studies on mercury (Hg) and oil pollution in coastal marine sediment caused by two of the >2100 documented PPW in Norwegian marine waters. The German World War II (WWII) submarine (U-864) lies at about 150m below the sea surface, near the Norwegian North Sea island of Fedje. The submarine is estimated to have been carrying 67t of elemental Hg, some of which has leaked on to surrounding sediment. The total Hg concentration in bottom surface sediment within a 200m radius of the wreckage decreases from 100g/kgd.w. at the wreckage hotspot to about 1mg/kgd.w. at 100m from the hotspot. The second wreck is a German WWII cargo ship (Nordvard), that lies at a depth of ca. 30m near the Norwegian harbor of Moss. Oil leakage from Nordvard has contaminated the bottom coastal sediment with polycyclic aromatic hydrocarbons (PAH). The findings from this study provide useful insight to coastal administration authorities involved in assessing and remediating wreck-borne pollution from any of the tens of thousands of sunken shipwrecks. Copyright © 2017 Elsevier B.V. All rights reserved.

  4. Interactions of climate, socio-economics, and global mercury pollution in the North Water.

    Dietz, Rune; Mosbech, Anders; Flora, Janne; Eulaers, Igor

    2018-04-01

    Despite the remoteness of the North Water, Northwest Greenland, the local Inughuit population is affected by global anthropogenic pollution and climate change. Using a cross-disciplinary approach combining Mercury (Hg) analysis, catch information, and historical and anthropological perspectives, this article elucidates how the traditional diet is compromised by Hg pollution originating from lower latitudes. In a new approach we here show how the Inughuits in Avanersuaq are subject to high Hg exposure from the hunted traditional food, consisting of mainly marine seabirds and mammals. Violation of the provisional tolerably yearly intake of Hg, on average by a factor of 11 (range 7-15) over the last 20 years as well as the provisional tolerably monthly intake by a factor of 6 (range 2-16), raises health concerns. The surplus of Selenium (Se) in wildlife tissues including narwhals showed Se:Hg molar ratios of 1.5, 2.3, and 16.7 in muscle, liver, and mattak, respectively, likely to provide some protection against the high Hg exposure.

  5. Removal of mercury from water by carbonaceous sorbents derived from walnut shell

    Zabihi, M.; Ahmadpour, A.; Asl, A. Haghighi

    2009-01-01

    The adsorption ability of a powdered activated carbon (PAC) derived from walnut shell was investigated in an attempt to produce more economic and effective sorbent for the control of Hg(II) ion from industrial liquid streams. Carbonaceous sorbents derived from Iranian walnut shell (WS) were prepared by chemical activation method using ZnCl 2 as an activating reagent. To the best of our knowledge, this adsorbent was not used before for removing mercury from water. Adsorption of Hg(II) from aqueous solutions was carried out under different experimental conditions by varying treatment time, metal ion concentration, adsorbent amount, pH and solution temperature. It was determined that Hg(II) adsorption follows both Langmuir and Freundlich isotherms as well as pseudo-second-order kinetics. It was also shown that Hg(II) uptake decreases with increasing pH of the solution. The proper choice of preparation conditions resulted in a microporous activated carbon with 0.45 g/cm 3 density, 737 mg/g iodine number and 780 m 2 /g BET surface area. The monolayer sorption capacity of this optimum adsorbent was obtained as 151.5 mg/g.

  6. National trends in drinking water quality violations.

    Allaire, Maura; Wu, Haowei; Lall, Upmanu

    2018-02-27

    Ensuring safe water supply for communities across the United States is a growing challenge in the face of aging infrastructure, impaired source water, and strained community finances. In the aftermath of the Flint lead crisis, there is an urgent need to assess the current state of US drinking water. However, no nationwide assessment has yet been conducted on trends in drinking water quality violations across several decades. Efforts to reduce violations are of national concern given that, in 2015, nearly 21 million people relied on community water systems that violated health-based quality standards. In this paper, we evaluate spatial and temporal patterns in health-related violations of the Safe Drinking Water Act using a panel dataset of 17,900 community water systems over the period 1982-2015. We also identify vulnerability factors of communities and water systems through probit regression. Increasing time trends and violation hot spots are detected in several states, particularly in the Southwest region. Repeat violations are prevalent in locations of violation hot spots, indicating that water systems in these regions struggle with recurring issues. In terms of vulnerability factors, we find that violation incidence in rural areas is substantially higher than in urbanized areas. Meanwhile, private ownership and purchased water source are associated with compliance. These findings indicate the types of underperforming systems that might benefit from assistance in achieving consistent compliance. We discuss why certain violations might be clustered in some regions and strategies for improving national drinking water quality.

  7. Maui Citizen Science Coastal Water Quality Data

    National Oceanic and Atmospheric Administration, Department of Commerce — A network of citizen science volunteers periodically monitors water quality at several beaches across the island of Maui in the State of Hawaii. This community-based...

  8. ASSESSMENT OF WATER QUALITY INDEX FOR GROUNDWATER ...

    2013-12-31

    Dec 31, 2013 ... The advantages of an index include its ability to represent measurements of a ... Fair. Water quality is usually protected but occasionally threatened or ... Electrical Conductivity (EC) value is an index to represent the total.

  9. Aggradation, Degradation, and Water Quality Conditions

    1993-01-01

    The purpose of this study is to compile a record of pertinent data and information relative to aggradation, degradation, and water quality within the system of six Missouri River mainstem reservoirs...

  10. Mobile Water Quality Information Tool, Phase I

    National Aeronautics and Space Administration — Water quality remote sensing has grown to allow for operational monitoring of trophic status, assessment of cyanobacteria blooms, and historical and trend analysis...

  11. Lake Tahoe Water Quality Improvement Programs

    Information on the Lake Tahoe watershed, EPA's protection efforts, water quality issues, effects of climate, change, Lake Tahoe Total Maximum Daily Load (TMDL), EPA-sponsored projects, and list of partner agencies.

  12. Carbonate chemistry, water quality, coral measurements

    U.S. Environmental Protection Agency — Carbonate chemistry parameters (pH, total alkalinity, and pCO2), water quality parameters (Temperature, salinity, Ca, Mg, PO4, NH3 and NO3) as well as all coral...

  13. WATER QUALITY MONITORING OF PHARMACEUTICALS ...

    The demand on freshwater to sustain the needs of the growing population is of worldwide concern. Often this water is used, treated, and released for reuse by other communities. The anthropogenic contaminants present in this water may include complex mixtures of pesticides, prescription and nonprescription drugs, personal care and common consumer products, industrial and domestic-use materials and degradation products of these compounds. Although, the fate of these pharmaceuticals and personal care products (PPCPs) in wastewater treatment facilities is largely unknown, the limited data that does exist suggests that many of these chemicals survive treatment and some others are returned to their biologically active form via deconjugation of metabolites.Traditional water sampling methods (i.e., grab or composite samples) often require the concentration of large amounts of water to detect trace levels of PPCPs. A passive sampler, the polar organic chemical integrative sampler (POCIS), has been developed to integratively concentrate the trace levels of these chemicals, determine the time-weighted average water concentrations, and provide a method of estimating the potential exposure of aquatic organisms to these complex mixtures of waterborne contaminants. The POCIS (U.S. Patent number 6,478,961) consists of a hydrophilic microporous membrane, acting as a semipermeable barrier, enveloping various solid-phase sorbents that retain the sampled chemicals. Sampling rates f

  14. Shale Gas Development and Drinking Water Quality.

    Hill, Elaine; Ma, Lala

    2017-05-01

    The extent of environmental externalities associated with shale gas development (SGD) is important for welfare considerations and, to date, remains uncertain (Mason, Muehlenbachs, and Olmstead 2015; Hausman and Kellogg 2015). This paper takes a first step to address this gap in the literature. Our study examines whether shale gas development systematically impacts public drinking water quality in Pennsylvania, an area that has been an important part of the recent shale gas boom. We create a novel dataset from several unique sources of data that allows us to relate SGD to public drinking water quality through a gas well's proximity to community water system (CWS) groundwater source intake areas.1 We employ a difference-in-differences strategy that compares, for a given CWS, water quality after an increase in the number of drilled well pads to background levels of water quality in the geographic area as measured by the impact of more distant well pads. Our main estimate finds that drilling an additional well pad within 1 km of groundwater intake locations increases shale gas-related contaminants by 1.5–2.7 percent, on average. These results are striking considering that our data are based on water sampling measurements taken after municipal treatment, and suggest that the health impacts of SGD 1 A CWS is defined as the subset of public water systems that supplies water to the same population year-round. through water contamination remains an open question.

  15. Dissolved gaseous mercury production in the dark: Evidence for the fundamental role of bacteria in different types of Mediterranean water bodies

    Fantozzi, L. [CNR-Istituto di Biofisica, Area della Ricerca, Via Moruzzi 1, Pisa I-56100 (Italy)], E-mail: laura.fantozzi@pi.ibf.cnr.it; Ferrara, R. [CNR-Istituto di Biofisica, Area della Ricerca, Via Moruzzi 1, Pisa I-56100 (Italy); Frontini, F.P.; Dini, F. [Dipartimento di Biologia, Universita di Pisa, Via A. Volta 4, Pisa I-56100 (Italy)

    2009-01-01

    It is well established that the dissolved gaseous mercury (DGM) production in waters is mainly driven by photochemical processes. The present paper provides evidence for a significant bacteria-mediated DGM production, occurring also under dark conditions in environmentally different types of coastal water bodies of the Mediterranean basin. The DGM production was laboratory determined in sea, lagoon-brackish and lake water samples, comparing the efficiency of the DGM production processes in darkness and in the light. This latter condition was established by exposing samples at solar radiation intensity in the Photosyntetical Active Radiation region (PAR) of 200 W m{sup -2}. Mercury reduction rate in the dark was of the order of 2-4% of the DGM production in lightness, depending on the total mercury concentration in the water, rather than the bacterial abundance in it. Support for the active bacterial role in mercury reduction rate under dark conditions was provided by: 1) absence of significant DGM production in sterilized water samples (following filtration treatment or autoclaving), 2) restored DGM production efficiency, following re-inoculation into the same water samples of representatives of their bacterial community, previously isolated and separately cultured. Notwithstanding the low bacteria-mediated vs. the high photo-induced DGM production, whatever natural water body was considered, it is worth stressing the significant contribution of this organismal-mediated process to oceanic mercury evasion, since it occurs continuously along the entire water column throughout the 24 h of the day.

  16. Dissolved gaseous mercury production in the dark: Evidence for the fundamental role of bacteria in different types of Mediterranean water bodies

    Fantozzi, L.; Ferrara, R.; Frontini, F.P.; Dini, F.

    2009-01-01

    It is well established that the dissolved gaseous mercury (DGM) production in waters is mainly driven by photochemical processes. The present paper provides evidence for a significant bacteria-mediated DGM production, occurring also under dark conditions in environmentally different types of coastal water bodies of the Mediterranean basin. The DGM production was laboratory determined in sea, lagoon-brackish and lake water samples, comparing the efficiency of the DGM production processes in darkness and in the light. This latter condition was established by exposing samples at solar radiation intensity in the Photosyntetical Active Radiation region (PAR) of 200 W m -2 . Mercury reduction rate in the dark was of the order of 2-4% of the DGM production in lightness, depending on the total mercury concentration in the water, rather than the bacterial abundance in it. Support for the active bacterial role in mercury reduction rate under dark conditions was provided by: 1) absence of significant DGM production in sterilized water samples (following filtration treatment or autoclaving), 2) restored DGM production efficiency, following re-inoculation into the same water samples of representatives of their bacterial community, previously isolated and separately cultured. Notwithstanding the low bacteria-mediated vs. the high photo-induced DGM production, whatever natural water body was considered, it is worth stressing the significant contribution of this organismal-mediated process to oceanic mercury evasion, since it occurs continuously along the entire water column throughout the 24 h of the day

  17. The quality of drinking water in Poland

    L. Kłos

    2015-05-01

    Full Text Available Introduction. An analysis of the drinking water quality and the degree of access to water supply and sewerage system in Poland was conducted. Materials and methods. Method of analysis of secondary statistical data was applied, mostly based on data available in the materials of the Central Statistical Office in Warsaw, the Waterworks Polish Chamber of Commerce in Bydgoszcz and the National Water Management in Warsaw. Result and discussion. 60 % of Poles do not trust to drink water without prior boiling. Water flowing from the taps, although widely available, is judged to be polluted, with too much fluorine or not having the appropriate consumer values (colour, smell and taste. The current water treatment systems can however improve them, although such a treatment, i.e. mainly through chlorination of water, deteriorates its quality in relation to pure natural water. The result is that fewer and fewer Poles drink water directly from the tap. They also less and less use tap water to cook food for which the bottled water is trusted more. Reason for that is that society does not trust the safety of the water supplied by the municipal water companies. The question thus is: Are they right? Tap water in Poland meets all standards since it is constantly monitored by the water companies and all relevant health services. Tap water supplied through the water supply system can be used without prior boiling. Studies have shown that only the operating parameters of water, suc h as taste, odour and hardness, are not satisfactory everywhere, different in each city, and sometimes in different districts of cities, often waking thoughts among users about its inappropriateness. The lowered water value can be easily improved at home through the use of filters. In conclusion, due to constant monitoring and investment in upgrading treatment processes, the quality of tap water has improved significantly in the last years. Conclusion. The results first allow assessing the

  18. Autonomous nutrient detection for water quality monitoring

    Maher, Damien; Cleary, John; Cogan, Deirdre; Diamond, Dermot

    2012-01-01

    The ever increasing demand for real time environmental monitoring is currently being driven by strong legislative and societal drivers. Low cost autonomous environmental monitoring systems are required to meet this demand as current monitoring solutions are insufficient. This poster presents an autonomous nutrient analyser platform for water quality monitoring. Results from a field trial of the nutrient analyser are reported along with current work to expand the range of water quality targ...

  19. Water quality in North American river systems

    Becker, C.D.; Neitzel, D.A.

    1992-01-01

    This book is about water quality and other characteristics of selected ecosystems in North America. It is also about changes that have occurred in these ecosystems as a result of recent human activities-changes that result primarily from development and exploitation to sustain the needs of an ever-increasing population and the technical innovations that sustain it. Fish populations, hydrology, and water quality control efforts are discussed

  20. Mercury-cycling in surface waters and in the atmosphere - species analysis for the investigation of transformation and transport properties of mercury

    Ebinghaus, R.; Hintelmann, H.; Wilken, R.D.

    1994-01-01

    The river Elbe has been one of the most contaminated rivers with regard to mercury for many years. In 1991 a length-profile has been measured for mercury and methylmercury (CH 3 Hg + ) from Obristvi, Czech Republic, to the German bight. Total mercury has been measured by cold vapor atomic absorption spectrometry (CVAAS). The organo mercury compounds have been separated by high performance liquid chromatography (HPLC) connected on-line to an atomic fluorescence spectrometer (AFS) by a continuous flow-system. Total mercury up to 120 mg Hg + /kg and CH 3 Hg + concentrations up to 130 μg CH 3 Hg + /kg could be detected in special sites. The formation of CH 3 Hg + in sediments can be caused besides the methylation of mercury, by sulphate reducing or methanogenic bacteria and transmethylation reactions with organometals. Atmospheric mercury concentrations have been measured at three different European sites. Samples have been collected on gold-coated glass balls or on quartz wool, respectively. After thermal desorption mercury has been determined using the two step amalgamation technique with AFS detection. Compared to natural background concentrations of total gaseous mercury (TGM), slightly increased levels could be detected at a rural site in Germany. This increase can probably be explained by long-range transport processes. Within the vicinity of a inactivated mercury production plant high concentrations of up to 13.5 ng/m 3 particle associated mercury (Hg part ) have been detected. Consequently, dry deposition of mercury in the particulate form can intensify the total deposition flux close to Hg-emitting sources. (orig.)

  1. Applications of continuous water quality monitoring techniques for more efficient water quality research and water resources management

    Rozemeijer, J.C.; Velde, Y. van der; Broers, H.P.; Geer, F. van

    2013-01-01

    Understanding and taking account of dynamics in water quality is essential for adequate water quality policy and management. In conventional regional surface water and upper groundwater quality monitoring, measurement frequencies are too low to capture the short-term dynamic behavior of solute

  2. A modified QWASI model for fate and transport modeling of mercury between the water-ice-sediment in Lake Ulansuhai.

    Liu, Yu; Li, Changyou; Anderson, Bruce; Zhang, Sheng; Shi, Xiaohong; Zhao, Shengnan

    2017-06-01

    Mercury contamination from industrial and agricultural drainage into lakes and rivers is a growing concern in Northern China. Lake Ulansuhai, located in Hetao irrigation district in Inner Mongolia, is the only sink for the all industrial and agricultural drainage and sole outlet for this district to the Yellow River, which is one of the main source of drinking water for the numerous cities and towns downstream. Because Ulansuahi is ice-covered during winter, the QWASI model was modified by adding an ice equation to get a more accurate understanding of the fate and transport of mercury within the lake. Both laboratory and field tests were carried out during the ice growth period. The aquivalence and mass balance approaches were used to develop the modified QWASI + ice model. The margins of error between the modelled and the measured average concentrations of Hg in ice, water, and sediment were 30%, 26.2%, and 19.8% respectively. These results suggest that the new QWASI + ice model could be used to more accurately represent the fate and transport of mercury in the seasonally ice-covered lakes, during the ice growth period. Copyright © 2017 Elsevier Ltd. All rights reserved.

  3. Putting people into water quality modelling.

    Strickert, G. E.; Hassanzadeh, E.; Noble, B.; Baulch, H. M.; Morales-Marin, L. A.; Lindenschmidt, K. E.

    2017-12-01

    Water quality in the Qu'Appelle River Basin, Saskatchewan is under pressure due to nutrient pollution entering the river system from major cities, industrial zones and agricultural areas. Among these stressors, agricultural activities are basin-wide; therefore, they are the largest non-point source of water pollution in this region. The dynamics of agricultural impacts on water quality are complex and stem from decisions and activities of two distinct stakeholder groups, namely grain farmers and cattle producers, which have different business plans, values, and attitudes towards water quality. As a result, improving water quality in this basin requires engaging with stakeholders to: (1) understand their perspectives regarding a range of agricultural Beneficial Management Practices (BMPs) that can improve water quality in the region, (2) show them the potential consequences of their selected BMPs, and (3) work with stakeholders to better understand the barriers and incentives to implement the effective BMPs. In this line, we held a series of workshops in the Qu'Appelle River Basin with both groups of stakeholders to understand stakeholders' viewpoints about alternative agricultural BMPs and their impact on water quality. Workshop participants were involved in the statement sorting activity (Q-sorts), group discussions, as well as mapping activity. The workshop outcomes show that stakeholder had four distinct viewpoints about the BMPs that can improve water quality, i.e., flow and erosion control, fertilizer management, cattle site management, as well as mixed cattle and wetland management. Accordingly, to simulate the consequences of stakeholder selected BMPs, a conceptual water quality model was developed using System Dynamics (SD). The model estimates potential changes in water quality at the farm, tributary and regional scale in the Qu'Appelle River Basin under each and/or combination of stakeholder selected BMPs. The SD model was then used for real

  4. Mercury concentrations and distribution in soil, water, mine waste leachates, and air in and around mercury mines in the Big Bend region, Texas, USA

    Gray, John E.; Theodorakos, Peter M.; Fey, David L.; Krabbenhoft, David P.

    2015-01-01

    Samples of soil, water, mine waste leachates, soil gas, and air were collected from areas mined for mercury (Hg) and baseline sites in the Big Bend area, Texas, to evaluate potential Hg contamination in the region. Soil samples collected within 300 m of an inactive Hg mine contained elevated Hg concentrations (3.8–11 µg/g), which were considerably higher than Hg in soil collected from baseline sites (0.03–0.05 µg/g) distal (as much as 24 km) from mines. Only three soil samples collected within 300 m of the mine exceeded the probable effect concentration for Hg of 1.06 µg/g, above which harmful effects are likely to be observed in sediment-dwelling organisms. Concentrations of Hg in mine water runoff (7.9–14 ng/L) were generally higher than those found in springs and wells (0.05–3.1 ng/L), baseline streams (1.1–9.7 ng/L), and sources of drinking water (0.63–9.1 ng/L) collected in the Big Bend region. Concentrations of Hg in all water samples collected in this study were considerably below the 2,000 ng/L drinking water Hg guideline and the 770 ng/L guideline recommended by the U.S. Environmental Protection Agency (USEPA) to protect aquatic wildlife from chronic effects of Hg. Concentrations of Hg in water leachates obtained from leaching of mine wastes varied widely from wastes were elevated, persistent wind in southwest Texas disperses Hg in the air within a few meters of the ground surface.

  5. High-resolution measurements of elemental mercury in surface water for an improved quantitative understanding of the Baltic Sea as a source of atmospheric mercury

    Kuss, Joachim; Krüger, Siegfried; Ruickoldt, Johann; Wlost, Klaus-Peter

    2018-03-01

    Marginal seas are directly subjected to anthropogenic and natural influences from land in addition to receiving inputs from the atmosphere and open ocean. Together these lead to pronounced gradients and strong dynamic changes. However, in the case of mercury emissions from these seas, estimates often fail to adequately account for the spatial and temporal variability of the elemental mercury concentration in surface water (Hg0wat). In this study, a method to measure Hg0wat at high resolution was devised and subsequently validated. The better-resolved Hg0wat dataset, consisting of about one measurement per nautical mile, yielded insight into the sea's small-scale variability and thus improved the quantification of the sea's Hg0 emission. This is important because global marine Hg0 emissions constitute a major source of atmospheric mercury. Research campaigns in the Baltic Sea were carried out between 2011 and 2015 during which Hg0 both in surface water and in ambient air were measured. For the former, two types of equilibrators were used. A membrane equilibrator enabled continuous equilibration and a bottle equilibrator assured that equilibrium was reached for validation. The measurements were combined with data obtained in the Baltic Sea in 2006 from a bottle equilibrator only. The Hg0 sea-air flux was newly calculated with the combined dataset based on current knowledge of the Hg0 Schmidt number, Henry's law constant, and a widely used gas exchange transfer velocity parameterization. By using a newly developed pump-CTD with increased pumping capability in the Hg0 equilibrator measurements, Hg0wat could also be characterized in deeper water layers. A process study carried out near the Swedish island Øland in August 2015 showed that the upwelling of Hg0-depleted water contributed to Hg0 emissions of the Baltic Sea. However, a delay of a few days after contact between the upwelled water and light was apparently necessary before the biotic and abiotic transformations

  6. Fish mercury concentration in the Alto Pantanal, Brazil: influence of season and water parameters.

    Hylander, L D; Pinto, F N; Guimarães, J R; Meili, M; Oliveira, L J; de Castro e Silva, E

    2000-10-16

    The tropical flood plain Pantanal is one of the world's largest wetlands and a wildlife sanctuary. Mercury (Hg) emissions from some upstream gold mining areas and recent findings of high natural Hg levels in tropical oxisols motivated studies on the Hg cycle in the Pantanal. A survey was made on total Hg in the most consumed piscivorous fish species from rivers and floodplain lakes in the north (Cáceres and Barão de Melgaço) and in the south part of Alto Pantanal (around the confluence of the Cuiabá and Paraguai rivers). Samples were collected in both the rainy and dry seasons (March and August 1998) and included piranha (Serrasalmus spp.), and catfish (Pseudoplatystoma coruscans, pintado, and Pseudoplatystoma fasciatum, cachara or surubim). There was only a small spatial variation in Hg concentration of the 185 analyzed fish samples from the 200 x 200 km large investigation area, and 90% contained total Hg concentration below the safety limit for regular fish consumption (500 ng g(-1)). Concentration above this limit was found in both Pseudoplatystoma and Serrasalmus samples from the Baia Siá Mariana, the only acid soft-water lake included in this study, during both the rainy and dry seasons. Concentration above this limit was also found in fish outside Baia Siá Mariana during the dry season, especially in Rio Cuiabá in the region of Barão de Melgaço. The seasonal effect may be connected with decreasing water volumes and changing habitat during the dry season. The results indicate that fertile women should restrict their consumption of piscivorous fishes from the Rio Cuiabá basin during the dry season. Measures should be implanted to avoid a further deterioration of fish Hg levels.

  7. Decreasing aqueous mercury concentrations to achieve safe levels in fish: examining the water-fish relationship in two point-source contaminated streams

    Mathews, Teresa J [ORNL; Southworth, George R [ORNL; Peterson, Mark J [ORNL; Roy, W Kelly [ORNL; Ketelle, Richard H [ORNL; Valentine, Charles S [ORNL; Gregory, Scott M [ORNL

    2013-01-01

    East Fork Poplar Creek (EFPC) and White Oak Creek (WOC) are two mercury-contaminated streams located on the Department of Energy s Oak Ridge Reservation in east Tennessee. East Fork Poplar Creek is the larger and more contaminated of the two, with average aqueous mercury (Hg) concentrations exceeding those in reference streams by several hundred-fold. Remedial actions over the past 20 years have decreased aqueous Hg concentrations in EFPC by 85 %. Fish fillet concentrations, however, have not responded to this decrease in aqueous Hg and remain above the U.S. Environmental Protection Agency s ambient water quality criterion (AWQC) of 0.3 mg/kg. The lack of correlation between aqueous and fish tissue Hg concentrations in this creek has led to questions regarding the usefulness of target aqueous Hg concentrations and strategies for future remediation efforts. White Oak Creek has a similar contamination history but aqueous Hg concentrations in WOC are an order of magnitude lower than in EFPC. Despite the lower aqueous Hg concentrations, fish fillet concentrations in WOC have also been above the AWQC, making the most recent aqueous Hg target of 200 ng/L in EFPC seem unlikely to result in an effective decrease in fillet Hg concentrations. Recent monitoring efforts in WOC, however, suggest an aqueous total Hg threshold above which Hg bioaccumulation in fish may not respond. This new information could be useful in guiding remedial actions in EFPC and in other point-source contaminated streams.

  8. Water quality control program in experimental circuits

    Cegalla, Miriam A.

    1996-01-01

    The Water Quality Control Program of the Experimental Circuits visualizes studying the water chemistry of the cooling in the primary and secondary circuits, monitoring the corrosion of the systems and studying the mechanism of the corrosion products transport in the systems. (author)

  9. Water Quality Standards for Coral Reef Protection

    The U.S. Clean Water Act provides a legal framework to protect coastal biological resources such as coral reefs, mangrove forests, and seagrass meadows from the damaging effects of human activities. Even though many resources are protected under this authority, water quality stan...

  10. Industry disagrees with water quality recommendations

    Begley, R.

    1992-01-01

    Industry groups are distancing themselves from recommendations on cleaning up the nation's waters issued by Water Quality 2000, a coalition of more than 80 organizations representing industry, environmental groups, government, academia, and professional and scientific societies. The report, open-quotes A National Water Agenda for the 21st Centuryclose quotes, is a result of work begun in 1989. It recommends an approach to water quality that emphasizes pollution prevention, increased individual and collective responsibility for protecting water resources, and reorienting water resource programs and institutions along natural, rather than political, watershed boundaries. It includes 85 specific recommendations, many of which are to be implemented locally. The Natural Resources Defense Council (NRDC; Washington) open-quotes wholeheartedly endorses not only the specific solutions offered today but the process by which these proposals were reached,close quotes says Robert W. Adler, NRDC senior attorney and vice chairman of Water Quality 2000. John B. Coleman, corporate environmental affairs manager for Du Pont and a member of the groups's steering committee, says open-quotes Du Pont and the other industry members of Water Quality 2000 are committedclose quotes to working to make continuous improvements

  11. Water quality of the river Damanganga (Gujarat)

    Zingde, M.D.; Narvekar, P.V.; Sarma, R.V.; Desai, B.N.

    Water quality (pH, suspended solids, chlorides, DO, BOD, reactive and total phosphorus, nitrates and boron) of River Damanganga which receives 0.2 mld of industrial waste into its fresh water zone through Pimparia River and 3.7 mld in its tidal zone...

  12. Hydrology and heterogeneneous distribution of water quality ...

    A study was carried out on the hydrology and heterogeneous distribution of water quality characteristics in the Lagoon of Porto-Novo between July 2014 and June 2015. The water body was stratified into 12 strata for sampling. Data and samples were collected based on season and stations. The results were analyzed in the ...

  13. Mycoflora and Water Quality index Assessment of Water Sources in ...

    MICHAEL HORSFALL

    water sources (31.96 - 47.31) falls within the classification “Bad” despite the slight increase during the dry season. The quality of water in the study area is poor and portends health risk; ... tributary that originates from the New Calabar River.

  14. Determination of water quality index and portability of Iguedo stream ...

    Determination of water quality index and portability of Iguedo stream in Edo ... has been found functional in assessing the water quality of this stream based on the ... Key words: Water quality index, physicochemical parameters, Iguedo Stream.

  15. Impacts of Water Quality on Residential Water Heating Equipment

    Widder, Sarah H.; Baechler, Michael C.

    2013-11-01

    Water heating is a ubiquitous energy use in all residential housing, accounting for 17.7% of residential energy use (EIA 2012). Today, there are many efficient water heating options available for every fuel type, from electric and gas to more unconventional fuel types like propane, solar, and fuel oil. Which water heating option is the best choice for a given household will depend on a number of factors, including average daily hot water use (total gallons per day), hot water draw patterns (close together or spread out), the hot water distribution system (compact or distributed), installation constraints (such as space, electrical service, or venting accommodations) and fuel-type availability and cost. While in general more efficient water heaters are more expensive than conventional water heating technologies, the savings in energy use and, thus, utility bills can recoup the additional upfront investment and make an efficient water heater a good investment over time in most situations, although the specific payback period for a given installation will vary widely. However, the expected lifetime of a water heater in a given installation can dramatically influence the cost effectiveness and savings potential of a water heater and should be considered, along with water use characteristics, fuel availability and cost, and specific home characteristics when selecting the optimum water heating equipment for a particular installation. This report provides recommendations for selecting and maintaining water heating equipment based on local water quality characteristics.

  16. Spatial distribution and trends of total mercury in waters of the Great Lakes and connecting channels using an improved sampling technique

    Dove, A.; Hill, B.; Klawunn, P.; Waltho, J.; Backus, S.; McCrea, R.C.

    2012-01-01

    Environment Canada recently developed a clean method suitable for sampling trace levels of metals in surface waters. The results of sampling for total mercury in the Laurentian Great Lakes between 2003 and 2009 give a unique basin-wide perspective of concentrations of this important contaminant and represent improved knowledge of mercury in the region. Results indicate that concentrations of total mercury in the offshore regions of the lakes were within a relatively narrow range from about 0.3 to 0.8 ng/L. The highest concentrations were observed in the western basin of Lake Erie and concentrations then declined towards the east. Compared to the offshore, higher levels were observed at some nearshore locations, particularly in lakes Erie and Ontario. The longer-term temporal record of mercury in Niagara River suspended sediments indicates an approximate 30% decrease in equivalent water concentrations since 1986. - Highlights: ► Basin-wide concentrations of total mercury in Great Lakes surface waters are provided for the first time. ► A clean sampling method is described, stressing isolation of the sample from extraneous sources of contamination. ► Sub-ng/L concentrations of total mercury are observed in most Great Lakes offshore areas. ► Concentrations in the western basin of Lake Erie are consistently the highest observed in the basin. ► The longer-term record of mercury in Niagara River suspended sediments indicates an approximate 30% decrease since 1986. - A new, clean sampling method for metals is described and basin-wide measurements of total mercury are provided for Great Lakes surface waters for the first time.

  17. Impact of Gold mining activities on the water quality of the lower pra river

    Dwamena, Offei Samuel K.

    2013-07-01

    This study was conducted to assess the extent of Mercury (THg) contamination at four locations within the Shama-Mporhor Wassa catchment area of the Lower Pra River. Water, fish and sediment samples were taken twice with the longitudinal transect method at Daboase, Beposo, Bokorkope and Shama during the minor rainy season in October and at the apex of the dry season in March. Careful investigation of the Shama-Mporhor Wassa catchment area revealed that two of the locations Daboase and Beposo had been continuously impacted by the activities of Artisanal Gold miners (AGM). From the study, Total Mercury (THg) levels were found to have persisted in River water several kilometers downstream the second Artisanal Gold mining (AGM) location at Shama estuary for both seasons. Ten trace elements Mercury (Hg), Selenium (Se), Copper (Cu), Chromium (Cr), Lead (Pb), Iron (Fe), Manganese (Mn), Nickel (Ni), Zinc (Zn) and Cadmium (Cd) were determined in water, fish and sediment samples using the Atomic Absorption Spectroscopy (AAS) equipped with both Hydride Generation (HGAAS) for Selenium (Se) and Cold Vapour (CVAAS) for Total Mercury (THg). The levels of Total Mercury (THg) were largely above the WHO and USEPA guidelines for drinking water (1μg/L) and sediments (200 μg/Kg) respectively for the four locations investigated. Total Mercury (THg) exceeded the WHO, 2011 guideline value of 0.5 mg/Kg for fish species Clarias submarginatus but was below the guideline value for Xenomystus nigri. Mean concentration of Cd and Fe exceeded the WHO, 2011 guideline values for drinking water for the wet season. The other trace elements Zn, Ni, Cu, Cr, Se, Mn, and Pb had their mean concentration below the WHO, 2011 guideline values for drinking water. Apart from the mean concentration of Cd that exceeded the Canadian Interim Sediment Quality (ISQG) guideline value of 0.6 mg/Kg for the wet season, Cr, Cu, Zn, Ni and Pb were below their respective guideline values for both seasons. Statistical

  18. Water quality management for Lake Mariout

    N. Donia

    2016-06-01

    Full Text Available A hydrodynamic and water quality model was used to study the current status of the Lake Mariout subject to the pollution loadings from the agricultural drains and the point sources discharging directly to the Lake. The basic water quality modelling component simulates the main water quality parameters including the oxygen compounds (BOD, COD, DO, nutrients compounds (NH4, TN, TP, and finally the temperature, salinity and inorganic matter. Many scenarios have been conducted to improve the circulation and the water quality in the lake and to assess the spreading and mixing of the discharge effluents and its impact on the water quality of the main basin. Several pilot interventions were applied through the model in the Lake Mariout together with the upgrades of the East and West Waste Water Treatment Plants in order to achieve at least 5% reduction in the pollution loads entering the Mediterranean Sea through Lake Mariout in order to improve the institutional mechanisms for sustainable coastal zone management in Alexandria in particular to reduce land-based pollution to the Mediterranean Sea.

  19. Environmental monitoring of mercury in waters. Reagent-free and rapid determination of mercury at trace levels.; Umweltmonitoring von Quecksilber in Gewaessern. Reagenzienfreie und schnelle Bestimmung von Hg im Spurenbereich

    Huber, Jessica; Leopold, Kerstin [Ulm Univ. (Germany). Inst. fuer Analytische und Bioanalytische Chemie

    2013-05-15

    With the help of nano gold collectors for the enrichment of the total mercury content of water samples can be analyzed fully automatically using atomic fluorescence spectrometry without extensive sample preparation. [German] Mit Hilfe von Nanogoldkollektoren zur Anreicherung kann der Gesamtquecksilber-Gehalt von Gewaesserproben vollautomatisiert mittels Atomfluoreszenzspektrometrie ohne aufwendige Probenvorbereitung analysiert werden.

  20. Chemical quality of water and bottom sediment, Stillwater National Wildlife Refuge, Lahontan Valley, Nevada

    Thodal, Carl E.

    2017-12-28

    The U.S. Geological Survey, in cooperation with the U.S. Fish and Wildlife Service collected data on water and bottom-sediment chemistry to be used to evaluate a new water rights acquisition program designed to enhance wetland habitat in Stillwater National Wildlife Refuge and in Lahontan Valley, Churchill County, Nevada. The area supports habitat critical to the feeding and resting of migratory birds travelling the Pacific Flyway. Information about how water rights acquisitions may affect the quality of water delivered to the wetlands is needed by stakeholders and Stillwater National Wildlife Refuge managers in order to evaluate the effectiveness of this approach to wetlands management. A network of six sites on waterways that deliver the majority of water to Refuge wetlands was established to monitor the quality of streamflow and bottom sediment. Each site was visited every 4 to 6 weeks and selected water-quality field parameters were measured when flowing water was present. Water samples were collected at varying frequencies and analyzed for major ions, silica, and organic carbon, and for selected species of nitrogen and phosphorus, trace elements, pharmaceuticals, and other trace organic compounds. Bottom-sediment samples were collected for analysis of selected trace elements.Dissolved-solids concentrations exceeded the recommended criterion for protection of aquatic life (500 milligrams per liter) in 33 of 62 filtered water samples. The maximum arsenic criterion (340 micrograms per liter) was exceeded twice and the continuous criterion was exceeded seven times. Criteria protecting aquatic life from continuous exposure to aluminum, cadmium, lead, and mercury (87, 0.72, 2.5, and 0.77 micrograms per liter, respectively) were exceeded only once in filtered samples (27, 40, 32, and 36 samples, respectively). Mercury was the only trace element analyzed in bottom-sediment samples to exceed the published probable effect concentration (1,060 micrograms per kilogram).

  1. Quality-control design for surface-water sampling in the National Water-Quality Network

    Riskin, Melissa L.; Reutter, David C.; Martin, Jeffrey D.; Mueller, David K.

    2018-04-10

    The data-quality objectives for samples collected at surface-water sites in the National Water-Quality Network include estimating the extent to which contamination, matrix effects, and measurement variability affect interpretation of environmental conditions. Quality-control samples provide insight into how well the samples collected at surface-water sites represent the true environmental conditions. Quality-control samples used in this program include field blanks, replicates, and field matrix spikes. This report describes the design for collection of these quality-control samples and the data management needed to properly identify these samples in the U.S. Geological Survey’s national database.

  2. Klang River water quality modelling using music

    Zahari, Nazirul Mubin; Zawawi, Mohd Hafiz; Muda, Zakaria Che; Sidek, Lariyah Mohd; Fauzi, Nurfazila Mohd; Othman, Mohd Edzham Fareez; Ahmad, Zulkepply

    2017-09-01

    Water is an essential resource that sustains life on earth; changes in the natural quality and distribution of water have ecological impacts that can sometimes be devastating. Recently, Malaysia is facing many environmental issues regarding water pollution. The main causes of river pollution are rapid urbanization, arising from the development of residential, commercial, industrial sites, infrastructural facilities and others. The purpose of the study was to predict the water quality of the Connaught Bridge Power Station (CBPS), Klang River. Besides that, affects to the low tide and high tide and. to forecast the pollutant concentrations of the Biochemical Oxygen Demand (BOD) and Total Suspended Solid (TSS) for existing land use of the catchment area through water quality modeling (by using the MUSIC software). Besides that, to identifying an integrated urban stormwater treatment system (Best Management Practice or BMPs) to achieve optimal performance in improving the water quality of the catchment using the MUSIC software in catchment areas having tropical climates. Result from MUSIC Model such as BOD5 at station 1 can be reduce the concentration from Class IV to become Class III. Whereas, for TSS concentration from Class III to become Class II at the station 1. The model predicted a mean TSS reduction of 0.17%, TP reduction of 0.14%, TN reduction of 0.48% and BOD5 reduction of 0.31% for Station 1 Thus, from the result after purposed BMPs the water quality is safe to use because basically water quality monitoring is important due to threat such as activities are harmful to aquatic organisms and public health.

  3. 40 CFR 130.6 - Water quality management plans.

    2010-07-01

    ... 40 Protection of Environment 21 2010-07-01 2010-07-01 false Water quality management plans. 130.6... QUALITY PLANNING AND MANAGEMENT § 130.6 Water quality management plans. (a) Water quality management (WQM... and certified and approved updates to those plans. Continuing water quality planning shall be based...

  4. Spatial aspects of surface water quality in the Jakara Basin, Nigeria using chemometric analysis.

    Mustapha, Adamu; Aris, Ahmad Zaharin

    2012-01-01

    Multivariate statistical techniques such as hierarchical Agglomerated cluster analysis (HACA), discriminant analysis (DA), principal component analysis (PCA), and factor analysis (FA) were applied to identify the spatial variation and pollution sources of Jakara River, Kano, Nigeria. Thirty surface water samples were collected: 23 along Getsi River and 7 along the main channel of River Jakara. Twenty-three water quality parameters, namely pH, temperature, turbidity, electrical conductivity (EC), dissolved oxygen (DO), 5-day biochemical oxygen demand (BOD(5)), Faecal coliform, total solids (TS), nitrates (NO(3)(-)), phosphates (PO(4)(3-)), cobalt (Co), iron (Fe), nickel (Ni), manganese (Mn), copper (Cu), sodium (Na), potassium (K), mercury (Hg), chromium (Cr), cadmium (Cd), lead (Pb), magnesium (Mg), and calcium(Ca) were analysed. HACA grouped the sampling points into three clusters based on the similarities of river water quality characteristics: industrial, domestic, and agricultural water pollution sources. Forward and backward DA effectively discriminated 5 and 15 water quality variables, respectively, each assigned with 100% correctness from the original 23 variables. PCA and FA were used to investigate the origin of each water quality parameter due to various land use activities, 7 principal components were obtained with 77.5% total variance, and in addition PCA identified 3 latent pollution sources to support HACA. From this study, one can conclude that the application of multivariate techniques derives meaningful information from water quality data.

  5. Private drinking water quality in rural Wisconsin.

    Knobeloch, Lynda; Gorski, Patrick; Christenson, Megan; Anderson, Henry

    2013-03-01

    Between July 1, 2007, and December 31, 2010, Wisconsin health departments tested nearly 4,000 rural drinking water supplies for coliform bacteria, nitrate, fluoride, and 13 metals as part of a state-funded program that provides assistance to low-income families. The authors' review of laboratory findings found that 47% of these wells had an exceedance of one or more health-based water quality standards. Test results for iron and coliform bacteria exceeded safe limits in 21% and 18% of these wells, respectively. In addition, 10% of the water samples from these wells were high in nitrate and 11% had an elevated result for aluminum, arsenic, lead, manganese, or strontium. The high percentage of unsafe test results emphasizes the importance of water quality monitoring to the health of nearly one million families including 300,000 Wisconsin children whose drinking water comes from a privately owned well.

  6. Mercury in stream water at five Czech catchments across a Hg and S deposition gradient

    Navrátil, Tomáš; Shanley, James B.; Rohovec, Jan; Oulehle, Filip; Krám, Pavel; Matoušková, Šárka; Tesař, Miroslav; Hojdová, Maria

    2015-01-01

    The Czech Republic was heavily industrialized in the second half of the 20th century but the associated emissions of Hg and S from coal burning were significantly reduced since the 1990s. We studied dissolved (filtered) stream water mercury (Hg) and dissolved organic carbon (DOC) concentrations at five catchments with contrasting Hg and S deposition histories in the Bohemian part of the Czech Republic. The median filtered Hg concentrations of stream water samples collected in hydrological years 2012 and 2013 from the five sites varied by an order of magnitude from 1.3 to 18.0 ng L− 1. The Hg concentrations at individual catchments were strongly correlated with DOC concentrations r from 0.64 to 0.93 and with discharge r from 0.48 to 0.75. Annual export fluxes of filtered Hg from individual catchments ranged from 0.11 to 13.3 μg m− 2 yr− 1 and were highest at sites with the highest DOC export fluxes. However, the amount of Hg exported per unit DOC varied widely; the mean Hg/DOC ratio in stream water at the individual sites ranged from 0.28 to 0.90 ng mg− 1. The highest stream Hg/DOC ratios occurred at sites Pluhův Bor and Jezeří which both are in the heavily polluted Black Triangle area. Stream Hg/DOC was inversely related to mineral and total soil pool Hg/C across the five sites. We explain this pattern by greater soil Hg retention due to inhibition of soil organic matter decomposition at the sites with low stream Hg/DOC and/or by precipitation of a metacinnabar (HgS) phase. Thus mobilization of Hg into streams from forest soils likely depends on combined effects of organic matter decomposition dynamics and HgS-like phase precipitation, which were both affected by Hg and S deposition histories.

  7. Concentrations of Mercury, Lead, Chromium, Cadmium, Arsenic and Aluminum in Irrigation Water Wells and Wastewaters Used for Agriculture in Mashhad, Northeastern Iran

    SR Mousavi

    2013-04-01

    Full Text Available Background: Contamination of water by toxic chemicals has become commonly recognized as an environmental concern. Based on our clinical observation in Mashhad, northeastern Iran, many people might be at risk of exposure to high concentrations of toxic heavy metals in water. Because wastewater effluents as well as water wells have been commonly used for irrigation over the past decades, there has been some concern on the toxic metal exposure of crops and vegetables irrigated with the contaminated water. Objective: To measure the concentrations of mercury, lead, chromium, cadmium, arsenic and aluminium in irrigation water wells and wastewaters used for agriculture in Mashhad, northeastern Iran. Methods: 36 samples were taken from irrigation water wells and a wastewater refinery in North of Mashhad at four times—May 2008, March 2009, and June and July 2010. Atomic absorption spectrometry was used to measure the concentration of toxic metals. Graphite furnace was used for the measurement of lead, chromium, cadmium and aluminum. Mercury and arsenic concentrations were measured by mercury/hydride system. Results: Chromium, cadmium, lead and arsenic concentrations in the samples were within the standard range. The mean±SD concentration of mercury in irrigation wells (1.02±0.40 μg/L exceeded the FAO maximum permissible levels. The aluminum concentration in irrigation water varied significantly from month to month (p=0.03. All wastewater samples contained high mercury concentrations (6.64±2.53 μg/L. Conclusion: For high mercury and aluminum concentrations, the water sources studied should not be used for agricultural use. Regular monitoring of the level of heavy metals in water and employing the necessary environmental interventions in this area are strongly recommended.

  8. Manual for calculating critical loads of heavy metals for soils and surface waters; preliminary guidelines for environmental quality criteria, calculation methods and input data

    Vries, de W.; Bakker, D.J.

    1996-01-01

    Methodologies are described for calculating critical loads of lead, cadmium, copper, zinc, nickel, chromium and mercury for soils and surface waters. The aspects which are discussed are: selection of a computation model, determination of environmental-quality criteria for the metals, collection of

  9. Uptake of mercury from water by the grass shrimp, Palaemonetes vulgaris (Say)

    Ray, G.L.; Tripp, M.R.

    1976-01-01

    In order to assess the toxicity of mercury to the grass shrimp (Palaemonetes vulgaris [Say]), the lethal concentration for 50 percent (LC 50 ) of the tested population in a 24-hour period for HgCl 2 and MeHgCl were determined. The LC 50 values were approximately 400 parts per billion (ppB) Hg for HgCl 2 and 125 ppB Hg for MeHgCl. When shrimp were held in mercury solutions at sublethal concentrations (1.5 ppB Hg as HgCl 2 ) for 15 days, a maximum of 500 ppB Hg was accumulated in the animal's tissues after 3 days. The average tissue concentration of mercury for the remaining 12 days was 450 ppB Hg. The actual tissue distribution of mercury was determined by exposure of shrimp to radioactively labeled HgCl 2 and MeHgCl. No difference could be found in the tissue distribution of the two compounds. A significant difference is tissue mercury distribution occurred between the 24-hour and 72-hour exposures

  10. In Brief: Improving Mississippi River water quality

    Showstack, Randy

    2007-10-01

    If water quality in the Mississippi River and the northern Gulf of Mexico is to improve, the U.S. Environmental Protection Agency (EPA) needs to take a stronger leadership role in implementing the federal Clean Water Act, according to a 16 October report from the U.S. National Research Council. The report notes that EPA has failed to use its authority to coordinate and oversee activities along the river. In addition, river states need to be more proactive and cooperative in efforts to monitor and improve water quality, and the river should be monitored and evaluated as a single system, the report indicates. Currently, the 10 states along the river conduct separate and widely varying water quality monitoring programs. ``The limited attention being given to monitoring and managing the Mississippi's water quality does not match the river's significant economic, ecological, and cultural importance,'' said committee chair David A. Dzombak, director of the Steinbrenner Institute for Environmental Education and Research at Carnegie Mellon University, Pittsburgh, Pa. The report notes that while measures taken under the Clean Water Act have successfully reduced much point source pollution, nutrient and sediment loads from nonpoint sources continue to be significant problems. For more information, visit the Web site: http://books.nap.edu/catalog.php?record_id=12051.

  11. Water Quality and Sustainable Environmental Health

    Setegn, S. G.

    2014-12-01

    Lack of adequate safe water, the pollution of the aquatic environment and the mismanagement of resources are major causes of ill-health and mortality, particularly in the developing countries. In order to accommodate more growth, sustainable fresh water resource management will need to be included in future development plans. One of the major environmental issues of concern to policy-makers is the increased vulnerability of ground water quality. The main challenge for the sustainability of water resources is the control of water pollution. To understand the sustainability of the water resources, one needs to understand the impact of future land use and climate changes on the natural resources. Providing safe water and basic sanitation to meet the Millennium Development Goals will require substantial economic resources, sustainable technological solutions and courageous political will. A balanced approach to water resources exploitation for development, on the one hand, and controls for the protection of health, on the other, is required if the benefits of both are to be realized without avoidable detrimental effects manifesting themselves. Meeting the millennium development goals for water and sanitation in the next decade will require substantial economic resources, sustainable technological solutions and courageous political will. In addition to providing "improved" water and "basic" sanitation services, we must ensure that these services provide: safe drinking water, adequate quantities of water for health, hygiene, agriculture and development and sustainable sanitation approaches to protect health and the environment.

  12. Mercury speciation and exchanges at the air-water interface of a tropical artificial reservoir, French Guiana.

    Muresan, B; Cossa, D; Richard, S; Burban, B

    2007-10-15

    The distribution and speciation of mercury (Hg) in air, rain, and surface waters from the artificial tropical lake of Petit-Saut in French Guiana were investigated during the 2003/04 period. In the air, total gaseous mercury (TGM) at the dam station averaged 12+/-2 pmol m(-3) of which >98% was gaseous elemental mercury (GEM). GEM distribution depicted a day-night cycling with high concentrations (up to 15 pmol m(-3)) at dawn and low concentrations (down to 5 pmol m(-3)) at nightfall. Reactive gaseous mercury (RGM) represented RGM variations were negatively related to GEM. In the rain, the sum of all Hg species in the unfiltered (HgT(UNF)) averaged 16+/-12 pmol L(-1). Temporal distribution of HgT(UNF) exhibited a pattern of high concentrations during the late dry seasons (up to 57.5 pmol L(-1)) and low concentrations (down to 2.7 pmol L(-1)) in the course of the wet seasons. Unfiltered reactive (HgR(UNF)), dissolved gaseous (DGM) and monomethyl (MMHg(UNF)) Hg constituted 20, 5 and 5% of HgT(UNF), respectively. All measured Hg species were positively related and displayed negative relationships with the pH of the rain. In the reservoir surface waters, dissolved total mercury (HgT(D)) averaged 3.4+/-1.2 pmol L(-1) of which 10% consisted of DGM. DGM showed a trend of high concentrations during the dry seasons (480+/-270 fmol L(-1)) and lower (230+/-130 fmol L(-1)) in the course of the wet seasons. Diel variations included diurnal photo-induced DGM production (of about 60 fmol L(-1) h(-1)) coupled to minute to hour oxidation/reduction cycles (of >100 fmol L(-1) amplitude). Finally, calculated atmospheric Hg inputs to the Petit-Saut reservoir represented 14 mol yr(-1) whereas DGM evasion reached 23 mol yr(-1). Apportionment among forms of Hg deposition indicated that up to 75% of the total Hg invasive flux follows the rainfall pathway.

  13. Risk-based water resources planning: Coupling water allocation and water quality management under extreme droughts

    Mortazavi-Naeini, M.; Bussi, G.; Hall, J. W.; Whitehead, P. G.

    2016-12-01

    The main aim of water companies is to have a reliable and safe water supply system. To fulfil their duty the water companies have to consider both water quality and quantity issues and challenges. Climate change and population growth will have an impact on water resources both in terms of available water and river water quality. Traditionally, a distinct separation between water quality and abstraction has existed. However, water quality can be a bottleneck in a system since water treatment works can only treat water if it meets certain standards. For instance, high turbidity and large phytoplankton content can increase sharply the cost of treatment or even make river water unfit for human consumption purposes. It is vital for water companies to be able to characterise the quantity and quality of water under extreme weather events and to consider the occurrence of eventual periods when water abstraction has to cease due to water quality constraints. This will give them opportunity to decide on water resource planning and potential changes to reduce the system failure risk. We present a risk-based approach for incorporating extreme events, based on future climate change scenarios from a large ensemble of climate model realisations, into integrated water resources model through combined use of water allocation (WATHNET) and water quality (INCA) models. The annual frequency of imposed restrictions on demand is considered as measure of reliability. We tested our approach on Thames region, in the UK, with 100 extreme events. The results show increase in frequency of imposed restrictions when water quality constraints were considered. This indicates importance of considering water quality issues in drought management plans.

  14. Comparative substoichiometric extraction and quantification of mercury in geological water samples with potassium salts of ethyl, propyl, butyl, pentyl and benzyl xanthates

    Chandrasekhar, R.P.; Rangamannar, B.

    1996-01-01

    The relative extent of extraction of mercury with potassium salts of ethyl, propyl, butyl, pentyl and benzyl xanthates has been studied employing a sensitive and rapid substoichiometric radiochemical method. The effect of pH on the extractability of mercury xanthate complexes into chloroform was investigated. Buffer solutions of pH 12, 11, 10, 9 and 5.5 were found to be suitable media for the maximum extraction of mercury as ethyl, propyl, butyl, pentyl and benzyl xanthate complexes, respectively. The procedures developed were utilized for the determination of mercury content in standard solutions and geological water samples collected in eight parts of Chittoor district of Andhra Pradesh. (author). 4 refs., 3 figs., 4 tabs

  15. Water and water quality management in the cholistan desert

    Kahlown, M.A.; Chaudhry, M.A.

    2005-01-01

    Water scarcity is the main problem in Cholistan desert. Rainfall is scanty and sporadic and groundwater is saline in most of the area. Rainwater is collected in man made small storages, locally called tobas during rainy season for human and livestock consumption. These tobas usually retain rainwater for three to four months at the maximum, due to small storage capacity and unfavorable location. After the tobas become dry, people use saline groundwater for human and livestock consumption where marginal quality groundwater is available. In complete absence of water they migrate towards canal irrigated areas till the next rains. During migration humans and livestock suffer from hunger, thirst and diseases. In order to overcome this problem Pakistan Council of Research in Water Resources (PCRWR) has introduced improved designs of tobas. The PCRWR is collecting more than 13.0 million cubic meter rainwater annually from only ninety hectare catchment area. As a result, water is available for drinking of human and livestock population as well as to wild life through out the year for the village of Dingarh in Cholistan desert. However, water collected in these tobas is usually muddy and full of impurities. To provide good quality drinking water to the residents of Cholistan, PCRWR has launched a Project under which required quantity of drinkable water will be provided at more than seventy locations by rainwater harvesting, pumping of good and marginal quality groundwater and desalination of moderately saline water through Reverse Osmosis Plants. After the completion of project, more then 380 million gallons of fresh rainwater and more than 1300 million gallons of good and marginal quality groundwater will be available annually. Intervention to collect the silt before reaching to the tobas are also introduced, low cost filter plants are designed and constructed on the tobas for purification of water. (author)

  16. Physicochemical Analysis of Water Quality of Brook Kuruçay

    Ekrem Mutlu

    2016-11-01

    Full Text Available In this study, through the analyses of water samples taken from 9 stations on the brook between July 2012 and June 2013, we aimed to determine the monthly and seasonal changes in water quality parameters of Brook Kuruçay, to determine the water quality properties, to reveal the pollution problems, to determine the suitability level in terms of aquatic life and to classify the quality of water in accordance with Surface Water Quality Management Regulation’s Inland Surface Water Classes criteria. The study area is located southeast of the Hafik District of Sivas city and the altitude is 2608 m. The water samples were collected from 9 stations established on the brook, and some physicochemical parameters and heavy metal concentrations were analyzed in water samples. The cleaning and maintenance of all of the equipment, land-type measurement tools, and glass sampling containers to be used in sampling were made 1 day before sampling. Sampling tubes were immersed into 15 cm below the water surface for taking water samples. Heavy metal concentrations were determined in the Sivas Provincial Control Laboratory in the same day with sampling (within 5 hours. The total alkalinity, total hardness, ammonium nitrogen, nitrite, nitrate, ammonium azote, phosphate, sulfite, sulfate, chloride, sodium, potassium, suspended solid matter (SSM, chemical oxygen demand (COD, biological oxygen demand (BOD, calcium, magnesium, ferrous, lead, copper, zinc, nickel, mercury and cadmium analyses of water samples were performed. As a result of the analyses, it was determined that, since Brook Kuruçay falls into the water resource class, which is the most sensitive to pollution, the water quality of the brook should be monitored regularly.

  17. A national look at water quality

    Gilliom, Robert J.; Mueller, David K.; Zogorski, John S.; Ryker, Sarah J.

    2002-01-01

    Most water-quality problems we face today result from diffuse "nonpoint" sources of pollution from agricultural land, urban development, forest harvesting and the atmosphere (U.S. Army Corps of Engineers et al., 1999). It is difficult to quantify nonpoint sources because the contaminants they deliver vary in composition and concentrations from hour to hour and season to season. Moreover, the nature of the contamination is complex and varied. When Congress enacted the Clean Water Act 30 years ago, attention was focused on water-quality issues related to the sanitation of rivers and streams - bacteria counts, oxygen in the water for fish, nutrients, temperature, and salinity. Now, attention is turning to the hundreds of synthetic organic compounds like pesticides used in agricultural and residential areas, volatile organics in solvents and gasoline, microbial and viral contamination, and pharmaceuticals and hormones.

  18. Utility service quality - telecommincations, electricity, water

    Holt, L. [Florida Univ., Gainesville, FL (United States). Public Utility Research Center

    2005-09-01

    This survey of quality-of-service issues raised by regulation identifies 12 steps for promoting efficient sector performance. First, regulators must identify objectives and prioritize them. Inter-agency coordination is often required to establish targets. Regulators must also determine a process for selecting measures and an appropriate method for evaluating them. Finally, performance incentives must be established and outcomes periodically reviewed. Telecommunications, electricity, and water all have multiple dimensions of quality that warrant careful attention. (Author)

  19. Drinking Water Quality Assessment in Tetova Region

    B. H. Durmishi; M. Ismaili; A. Shabani; Sh. Abduli

    2012-01-01

    Problem statement: The quality of drinking water is a crucial factor for human health. The objective of this study was the assessment of physical, chemical and bacteriological quality of the drinking water in the city of Tetova and several surrounding villages in the Republic of Macedonia for the period May 2007-2008. The sampling and analysis are conducted in accordance with State Regulation No. 57/2004, which is in compliance with EU and WHO standards. A total of 415 samples were taken for ...

  20. Monitoring water quality by remote sensing

    Brown, R. L. (Principal Investigator)

    1977-01-01

    The author has identified the following significant results. A limited study was conducted to determine the applicability of remote sensing for evaluating water quality conditions in the San Francisco Bay and delta. Considerable supporting data were available for the study area from other than overflight sources, but short-term temporal and spatial variability precluded their use. The study results were not sufficient to shed much light on the subject, but it did appear that, with the present state of the art in image analysis and the large amount of ground truth needed, remote sensing has only limited application in monitoring water quality.

  1. An ANN application for water quality forecasting.

    Palani, Sundarambal; Liong, Shie-Yui; Tkalich, Pavel

    2008-09-01

    Rapid urban and coastal developments often witness deterioration of regional seawater quality. As part of the management process, it is important to assess the baseline characteristics of the marine environment so that sustainable development can be pursued. In this study, artificial neural networks (ANNs) were used to predict and forecast quantitative characteristics of water bodies. The true power and advantage of this method lie in its ability to (1) represent both linear and non-linear relationships and (2) learn these relationships directly from the data being modeled. The study focuses on Singapore coastal waters. The ANN model is built for quick assessment and forecasting of selected water quality variables at any location in the domain of interest. Respective variables measured at other locations serve as the input parameters. The variables of interest are salinity, temperature, dissolved oxygen, and chlorophyll-alpha. A time lag up to 2Delta(t) appeared to suffice to yield good simulation results. To validate the performance of the trained ANN, it was applied to an unseen data set from a station in the region. The results show the ANN's great potential to simulate water quality variables. Simulation accuracy, measured in the Nash-Sutcliffe coefficient of efficiency (R(2)), ranged from 0.8 to 0.9 for the training and overfitting test data. Thus, a trained ANN model may potentially provide simulated values for desired locations at which measured data are unavailable yet required for water quality models.

  2. BARC's efforts towards maintenance of water quality

    Kamath, P.R.

    1978-01-01

    Some of the studies pursued at the Environmental Survey Laboratories (ESLs) established at the site of nuclear installations in India are discussed. Each site has its special features and these ESLs monitor radioactive pollution in the environment including Man. The major objective of the surveillance programme at nuclear sites is the maintenance of water quality. Environmental investigations carried out to collect data on individual organisms, recipient water characteristics, thermal pollution and its effect on fish are described. (K.M.)

  3. Par Pond refill water quality sampling

    Koch, J.W. II; Martin, F.D.; Westbury, H.M.

    1996-08-01

    This study was designed to document anoxia and its cause in the event that the anoxia caused a fish kill. However, no fish kill was observed during this study, and dissolved oxygen and nutrient concentrations generally remained within the range expected for southeastern reservoirs. Par Pond water quality monitoring will continue during the second summer after refill as the aquatic macrophytes become reestablished and nutrients in the sediments are released to the water column

  4. Water quality maintaining device of power plant

    Kobayashi, Minoru; Inami, Ichiro.

    1994-01-01

    The device of the present invention reduces the amount of leaching materials of ion exchange resins from a water processing system of a BWR tyep plant, improves the water quality of reactor water to maintain the water at high purity. That is, steams used for power generation are condensated in a condensate system. A condensate filter and a condensate desalter for cleaning the condensates are disposed. A resin storage hopper is disposed for supplying the ion exchange resins to the water processing system. A device for supplying a nitrogen gas or an inert gas is disposed in the hopper. With such a constitution, the ion exchange resins in the water processing system are maintained in a nitrogen gas or inert gas atmosphere or at a low dissolved oxygen level in an operation stage in the power plant. Accordingly, degradation of the ion exchange resins in the water processing system is suppressed and the amount of the leaching material from the resins is reduced. As a result, the amount of the resins leached into the reactor is reduced, so that the reactor water quality can be maintained at high purity. (I.S.)

  5. Monitoring and Assessment of Youshui River Water Quality in Youyang

    Wang, Xue-qin; Wen, Juan; Chen, Ping-hua; Liu, Na-na

    2018-02-01

    By monitoring the water quality of Youshui River from January 2016 to December 2016, according to the indicator grading and the assessment standard of water quality, the formulas for 3 types water quality indexes are established. These 3 types water quality indexes, the single indicator index Ai, single moment index Ak and the comprehensive water quality index A, were used to quantitatively evaluate the quality of single indicator, the water quality and the change of water quality with time. The results show that, both total phosphorus and fecal coliform indicators exceeded the standard, while the other 16 indicators measured up to the standard. The water quality index of Youshui River is 0.93 and the grade of water quality comprehensive assessment is level 2, which indicated that the water quality of Youshui River is good, and there is room for further improvement. To this end, several protection measures for Youshui River environmental management and pollution treatment are proposed.

  6. Evaluation of Background Mercury Concentrations in the SRS Groundwater System

    Looney, B.B.

    1999-01-01

    Mercury analyses associated with the A-01 Outfall have highlighted the importance of developing an understanding of mercury in the Savannah River Site groundwater system and associated surface water streams. This activity is critical based upon the fact that the EPA Ambient Water Quality Criteria (AWQC) for this constituent is 0.012mg/L, a level that is well below conventional detection limits of 0.1 to 0.2 mg/L. A first step in this process is obtained by utilizing the existing investment in groundwater mercury concentrations (20,242 records) maintained in the SRS geographical information management system (GIMS) database. Careful use of these data provides a technically defensible initial estimate for total recoverable mercury in background and contaminated SRS wells

  7. Measurements of gaseous mercury exchanges at the sediment-water, water-atmosphere and sediment-atmosphere interfaces of a tidal environment (Arcachon Bay, France).

    Bouchet, Sylvain; Tessier, Emmanuel; Monperrus, Mathilde; Bridou, Romain; Clavier, Jacques; Thouzeau, Gerard; Amouroux, David

    2011-05-01

    The elemental mercury evasion from non-impacted natural areas is of significant importance in the global Hg cycle due to their large spatial coverage. Intertidal areas represent a dynamic environment promoting the transformations of Hg species and their subsequent redistribution. A major challenge remains in providing reliable data on Hg species variability and fluxes under typical transient tidal conditions found in such environment. Field experiments were thus carried out to allow the assessment and comparison of the magnitude of the gaseous Hg fluxes at the three interfaces, sediment-water, sediment-atmosphere and water-atmosphere of a mesotidal temperate lagoon (Arcachon Bay, Aquitaine, France) over three distinct seasonal conditions. The fluxes between the sediment-water and the sediment-atmosphere interfaces were directly evaluated with field flux chambers, respectively static or dynamic. Water-atmosphere fluxes were evaluated from ambient concentrations using a gas exchange model. The fluxes at the sediment-water interface ranged from -5.0 to 5.1 ng m(-2) h(-1) and appeared mainly controlled by diffusion. The occurrence of macrophytic covers (i.e.Zostera noltii sp.) enhanced the fluxes under light radiations. The first direct measurements of sediment-atmosphere fluxes are reported here. The exchanges were more intense and variable than the two other interfaces, ranging between -78 and 40 ng m(-2) h(-1) and were mostly driven by the overlying atmospheric Hg concentrations and superficial sediment temperature. The exchanges between the water column and the atmosphere, computed as a function of wind speed and gaseous mercury saturation ranged from 0.4 to 14.5 ng m(-2) h(-1). The flux intensities recorded over the intertidal sediments periodically exposed to the atmosphere were roughly 2 to 3 times higher than the fluxes of the other interfaces. The evasion of elemental mercury from emerged intertidal sediments is probably a significant pathway for Hg evasion in

  8. Mercury concentrations and distribution in soil, water, mine waste leachates, and air in and around mercury mines in the Big Bend region, Texas, USA.

    Gray, John E; Theodorakos, Peter M; Fey, David L; Krabbenhoft, David P

    2015-02-01

    Samples of soil, water, mine waste leachates, soil gas, and air were collected from areas mined for mercury (Hg) and baseline sites in the Big Bend area, Texas, to evaluate potential Hg contamination in the region. Soil samples collected within 300 m of an inactive Hg mine contained elevated Hg concentrations (3.8-11 µg/g), which were considerably higher than Hg in soil collected from baseline sites (0.03-0.05 µg/g) distal (as much as 24 km) from mines. Only three soil samples collected within 300 m of the mine exceeded the probable effect concentration for Hg of 1.06 µg/g, above which harmful effects are likely to be observed in sediment-dwelling organisms. Concentrations of Hg in mine water runoff (7.9-14 ng/L) were generally higher than those found in springs and wells (0.05-3.1 ng/L), baseline streams (1.1-9.7 ng/L), and sources of drinking water (0.63-9.1 ng/L) collected in the Big Bend region. Concentrations of Hg in all water samples collected in this study were considerably below the 2,000 ng/L drinking water Hg guideline and the 770 ng/L guideline recommended by the U.S. Environmental Protection Agency (USEPA) to protect aquatic wildlife from chronic effects of Hg. Concentrations of Hg in water leachates obtained from leaching of mine wastes varied widely from <0.001 to 760 µg of Hg in leachate/g of sample leached, but only one leachate exceeded the USEPA Hg industrial soil screening level of 31 µg/g. Concentrations of Hg in soil gas collected at mined sites (690-82,000 ng/m(3)) were highly elevated compared to soil gas collected from baseline sites (1.2-77 ng/m(3)). However, air collected from mined areas at a height of 2 m above the ground surface contained concentrations of Hg (4.9-64 ng/m(3)) that were considerably lower than Hg in soil gas from the mined areas. Although concentrations of Hg emitted from mine-contaminated soils and mine wastes were elevated, persistent wind in southwest Texas disperses Hg in the air within a few meters of the

  9. Total mercury and methylmercury in fish fillets, water, and bed sediments from selected streams in the Delaware River basin, New Jersery, New York, and Pennsylvania, 1998-2001

    Brightbill, Robin A.; Riva-Murray, Karen; Bilger, Michael D.; Byrnes, John D.

    2004-01-01

    Within the Delaware River Basin, fish-tissue samples were analyzed for total mercury (tHg). Water and bed-sediment samples were analyzed for tHg and methylmercury (MeHg), and methylation efficiencies were calculated. This study was part of a National Mercury Pilot Program conducted by the U.S. Geological Survey (USGS). The Delaware River Basin was chosen because it is part of the USGS National Water-Quality Assessment Program that integrates physical, chemical, and biological sampling efforts to determine status and trends in surface-water and ground-water resources. Of the 35 sites in the study, 31 were sampled for fish. The species sampled at these sites include smallmouth bass (Micropterus dolomieu), the target species, and where smallmouth bass could not be collected, brown trout (Salmo trutta), chain pickerel (Esox niger), largemouth bass (Micropterus salmoides), and rock bass (Ambloplites rupestris). There were a total of 32 fish samples; 7 of these exceeded the 0.3 ?g/g (micrograms per gram) wet-weight mercury (Hg) concentration set for human health by the U.S. Environmental Protection Agency and 27 of these exceeded the U.S. Fish and Wildlife Service criteria of 0.1 ?g/g wet weight for the protection of fish-eating birds and wildlife. Basinwide analysis of Hg in fish, water, and bed sediment showed tHg concentration in fillets correlated positively with population density, urban land cover, and impervious land surface. Negative correlations included wetland land cover, septic density, elevation, and latitude. Smallmouth bass from the urban sites had a higher median concentration of tHg than fish from agricultural, low intensity-agricultural, or forested sites. Concentrations of tHg and MeHg in water were higher in samples from the more urbanized areas of the basin and were positively correlated with urbanization and negatively correlated with forested land cover. Methylation efficiency of water was negatively correlated with urbanization. Bed

  10. 40 CFR 227.31 - Applicable marine water quality criteria.

    2010-07-01

    ... 40 Protection of Environment 24 2010-07-01 2010-07-01 false Applicable marine water quality... § 227.31 Applicable marine water quality criteria. Applicable marine water quality criteria means the criteria given for marine waters in the EPA publication “Quality Criteria for Water” as published in 1976...

  11. Water quality indexing for predicting variation of water quality over time

    PPoonoosamy

    water, and expressing them to non-technical people may not always be easy. ... parameters for a case study; dissolved oxygen, pH, total coliforms, ... Several national agencies responsible for water supply and water pollution, have strongly .... good quality and required proper treatment if it were to be consumed as potable.

  12. Development of a Portable Water Quality Analyzer

    Germán COMINA

    2010-08-01

    Full Text Available A portable water analyzer based on a voltammetric electronic tongue has been developed. The system uses an electrochemical cell with two working electrodes as sensors, a computer controlled potentiostat, and software based on multivariate data analysis for pattern recognition. The system is suitable to differentiate laboratory made and real in-situ river water samples contaminated with different amounts of Escherichia coli. This bacteria is not only one of the main indicators for water quality, but also a main concern for public health, affecting especially people living in high-burden, resource-limiting settings.

  13. Mercury concentrations in water and mercury and selenium concentrations in fish from Brownlee Reservoir and selected sites in the Boise and Snake Rivers, Idaho and Oregon, 2013–15

    Williams, Marshall L.; MacCoy, Dorene E.

    2016-06-30

    Mercury (Hg) analyses were conducted on samples of sport fish and water collected from selected sampling sites in Brownlee Reservoir and the Boise and Snake Rivers to meet National Pollution Discharge and Elimination System (NPDES) permit requirements for the City of Boise, Idaho, between 2013 and 2015. City of Boise personnel collected water samples from six sites between October and November 2013 and 2015, with one site sampled in 2014. Total Hg concentrations in unfiltered water samples ranged from 0.48 to 8.8 nanograms per liter (ng/L), with the highest value in Brownlee Reservoir in 2013. All Hg concentrations in water samples were less than the U.S. Environmental Protection Agency (USEPA) Hg chronic aquatic life criterion of 12 ng/L.The USEPA recommended a water-quality criterion of 0.30 milligrams per kilogram (mg/kg) methylmercury (MeHg) expressed as a fish-tissue residue value (wet-weight MeHg in fish tissue). The Idaho Department of Environmental Quality adopted the USEPA’s fish-tissue criterion and established a reasonable potential to exceed (RPTE) threshold 20 percent lower than the criterion or greater than 0.24 mg/kg Hg based on an average concentration of 10 fish from a receiving waterbody. NPDES permitted discharge to waters with fish having Hg concentrations exceeding 0.24 mg/kg are said to have a reasonable potential to exceed the water-quality criterion and thus are subject to additional permit obligations, such as requirements for increased monitoring and the development of a Hg minimization plan. The Idaho Fish Consumption Advisory Program (IFCAP) issues fish advisories to protect general and sensitive populations of fish consumers and has developed an action level of 0.22 mg/kg Hg in fish tissue. Fish consumption advisories are water body- and species-specific and are used to advise allowable fish consumption from specific water bodies. The geometric mean Hg concentration of 10 fish of a single species collected from a single water body

  14. Assessment of Mercury in Soils, Crops, Earthworms, and Water when Soil is Treated with Gypsum

    Flue gas desulfurization (FGD) gypsum from fossil fuel combustion has many potential uses in agriculture, but there is concern about the potential environmental effects of its elevated mercury (Hg) concentration. The wet limestone scrubbing process that removes sulfur from flue gas (and produces gyp...

  15. Sustainable River Water Quality Management in Malaysia

    Abdullah Al-Mamun

    2013-04-01

    Full Text Available Ecological status of Malaysia is not as bad as many other developing nations in the world. However, despite the enforcement of the Environmental Quality Act (EQA in 1974, the water quality of Malaysian inland water (especially rivers is following deteriorating trend. The rivers are mainly polluted due to the point and non-point pollution sources. Point sources are monitored and controlled by the Department of Environment (DOE, whereas a significant amount of pollutants is contributed by untreated sullage and storm runoff. Nevertheless, it is not too late to take some bold steps for the effective control of non-point source pollution and untreated sullage discharge, which play significant roles on the status of the rivers. This paper reviews the existing procedures and guidelines related to protection of the river water quality in Malaysia.  There is a good possibility that the sewage and effluent discharge limits in the Environmental Quality Act (EQA may pose hindrance against achieving good quality water in the rivers as required by the National Water Quality Standards (NWQS. For instance, Ammoniacal Nitrogen (NH3-N is identified as one of the main pollutants to render many of the rivers polluted but it was not considered in the EQA as a monitoring parameter until the new regulations published in 2009.  Surprisingly, the new regulation for sewage and industrial effluent limits set allowable NH3-N concentration quite high (5 mg/L, which may result in low Water Quality Index (WQI values for the river water. The water environment is a dynamic system. Periodical review of the monitoring requirements, detecting emerging pollutants in sewage, effluent and runoff, and proper revision of water quality standards are necessary for the management of sustainable water resources in the country. ABSTRAK: Satus ekologi Malaysia tidak seburuk kebanyakan negara membangun lain di dunia. Walaupun Akta Kualiti Alam Sekitar (EQA dikuatkuasakan pada tahun 1974

  16. Drinking water quality of Sukkur municipal corporation

    Kandhar, I.A.; Ansari, A.K.

    2002-01-01

    SMC (Sukkur Municipal Corporation) supply the (filtered/settled) water for domestic purpose to the consumers, through intermittent water supply, from Phases I to IV. The water supply distribution network is underground and at most places pass parallel to sewerage lines. The grab sampling technique was followed for collecting representative samples. The official US-EPA and standard methods of water analysis have been used for drinking water quality analysis. DR/2000 spectrophotometer has been used for monitoring: Nitrates, Fluorides, Sulfates, Copper, Chromium, Iron and manganese. The trace metals Cr/sup 6/, Fe/sup 2+/ and other contaminants like; Turbidity and TSS (Total Suspended Solids) have been found higher than World Health Organization (WHO-1993) guideline values. (author)

  17. Klamath River Basin water-quality data

    Smith, Cassandra D.; Rounds, Stewart A.; Orzol, Leonard L.; Sobieszczyk, Steven

    2018-05-29

    The Klamath River Basin stretches from the mountains and inland basins of south-central Oregon and northern California to the Pacific Ocean, spanning multiple climatic regions and encompassing a variety of ecosystems. Water quantity and water quality are important topics in the basin, because water is a critical resource for farming and municipal use, power generation, and for the support of wildlife, aquatic ecosystems, and endangered species. Upper Klamath Lake is the largest freshwater lake in Oregon (112 square miles) and is known for its seasonal algal blooms. The Klamath River has dams for hydropower and the upper basin requires irrigation water to support agriculture and grazing. Multiple species of endangered fish inhabit the rivers and lakes, and the marshes are key stops on the Pacific flyway for migrating birds. For these and other reasons, the water resources in this basin have been studied and monitored to support their management distribution.

  18. AFRRI TRIGA Reactor water quality monitoring program

    Moore, Mark; George, Robert; Spence, Harry; Nguyen, John

    1992-01-01

    AFRRI has started a water quality monitoring program to provide base line data for early detection of tank leaks. This program revealed problems with growth of algae and bacteria in the pool as a result of contamination with nitrogenous matter. Steps have been taken to reduce the nitrogen levels and to kill and remove algae and bacteria from the reactor pool. (author)

  19. Quality assurance plan, Westinghouse Water Reactor Divisions

    1976-03-01

    The Quality Assurance Program used by Westinghouse Nuclear Energy Systems Water Reactor Divisions is described. The purpose of the program is to assure that the design, materials, and workmanship on Nuclear Steam Supply System (NSSS) equipment meet applicable safety requirements, fulfill the requirements of the contracts with the applicants, and satisfy the applicable codes, standards, and regulatory requirements.

  20. NONPOINT SOURCES AND WATER QUALITY TRADING

    Management of nonpoint sources (NPS) of nutrients may reduce discharge levels more cost effectively than can additional controls on point sources (PS); water quality trading (WQT), where a PS buys nutrient or sediment reductions from an NPS, may be an alternative means for the PS...

  1. FISH PHYSIOLOGY, TOXICOLOGY, AND WATER QUALITY:

    Twenty-one participants from Europe, North America and China convened in Chongqing, China, October 12-14, 2005, for the Eighth International Symposium in Fish Physiology, Toxicology and Water Quality. The subject of the meeting was "Hypoxia in vertebrates: Comparisons of terrestr...

  2. Compost improves urban soil and water quality

    Construction in urban zones compacts the soil, which hinders root growth and infiltration and may increase erosion, which may degrade water quality. The purpose of our study was to determine the whether planting prairie grasses and adding compost to urban soils can mitigate these concerns. We simula...

  3. FISH PHYSIOLOGY, TOXICOLOGY, AND WATER QUALITY

    Scientists from ten countries presented papers at the Fifth International Symposium on Fish Physiology, Toxicology, and Water Quality, which was held on the campus of the city University of Hong Kong on November 10-13, 1998. These Proceedings include 23 papers presented in sessi...

  4. Evaluating Water Quality in a Suburban Environment

    Thomas, S. M.; Garza, N.

    2008-12-01

    A water quality analysis and modeling study is currently being conducted on the Martinez Creek, a small catchment within Cibolo watershed, a sub-basin of the San Antonio River, Texas. Several other major creeks, such as Salatrillo, Escondido, and Woman Hollering merge with Martinez Creek. Land use and land cover analysis shows that the major portion of the watershed is dominated by residential development with average impervious cover percentage of approximately 40% along with a some of agricultural areas and brushlands. This catchment is characterized by the presence of three small wastewater treatment plants. Previous site visits and sampling of water quality indicate the presence of algae and fecal coliform bacteria at levels well above state standards at several locations in the catchment throughout the year. Due to the presence of livestock, residential development and wastewater treatment plants, a comprehensive understanding of water quality is important to evaluate the sources and find means to control pollution. As part of the study, a spatial and temporal water quality analyses of conventional parameters as well as emerging contaminants, such as veterinary pharmaceuticals and microbial pathogens is being conducted to identify critical locations and sources. Additionally, the Hydrologic Simulation Program FORTRAN (HSPF) will be used to identify best management practices that can be incorporated given the projected growth and development and feasibility.

  5. Water quality criteria for hexachloroethane: Final report

    Davidson, K.A.; Hovatter, P.S.; Ross, R.H.

    1988-03-01

    The available data regarding the environmental fate, aquatic toxicity, and mammalian toxicity of hexachloroethane, which is used in military screening smokes, were reviewed. The USEPA guidelines were used to generate water quality criteria for the protection of aquatic life and its uses and of human health. 16 tabs.

  6. Determination of mercury by liquid chromatography in fresh water fishes using 2-thiophenealdehyde-4-phenyl-3-thiosemicarbazone

    Khuhawar, M.Y.; Languani, S.N.

    2001-01-01

    Co (II), Ag (I) and Hg (II) or Co (II), Ni (II), Fe (II), Cu (II) and Hg (II) are simultaneously extracted as metal chelates compounds of 2-thiophenealdehyde-4-phenyl-3-thiosemicarbazone (TAPT) in chloroform. The complexes were separated from microsorb C-18, 5 mue m column when eluted with methanol/acetonitrile/water/aqueous sodium acetate 1 m mol or methanol/acetonitrile/water/sodium acetate (1 mmol) tetrabutyl ammonium bromide (1mmol) with a flow rate of 1 ml-1 and detection UV at 254 nm. Linear calibrations were made with 10-50 ml-1 and detection limit was 0.4 ml-1, corresponding to 2 ng/injection in Co and Hg. The method was used for the determination of mercury in surface water fishes. It was found within 0.125 to 1.18 g-1 of fish muscles with coefficient of variation (C.V) 3.4-5.8%. (author)

  7. An Ionic 1,4-Bis(styrylbenzene-Based Fluorescent Probe for Mercury(II Detection in Water via Deprotection of the Thioacetal Group

    Van Sang Le

    2016-12-01

    Full Text Available Highly sensitive and selective mercury detection in aqueous media is urgently needed because mercury poisoning usually results from exposure to water-soluble forms of mercury by inhalation and/or ingesting. An ionic conjugated oligoelectrolye (M1Q based on 1,4-bis(styrylbenzene was synthesized as a fluorescent mercury(II probe. The thioacetal moiety and quaternized ammonium group were incorporated for Hg2+ recognition and water solubility. A neutral Hg2+ probe (M1 was also prepared based on the same molecular backbone, and their sensor characteristics were investigated in a mixture of acetonitrile/water and in water. In the presence of Hg2+, the thioacetal group was converted to aldehyde functionality, and the resulting photoluminescence intensity decreased. In water, M1Q successfully demonstrated highly sensitive detection, showing a binding toward Hg2+ that was ~15 times stronger and a signal on/off ratio twice as high, compared to M1 in acetonitrile/water. The thioacetal deprotection by Hg2+ ions was substantially facilitated in water without an organic cosolvent. The limit of detection was measured to be 7 nM with a detection range of 10–180 nM in 100% aqueous medium.

  8. Preferential feeding on high quality diets decreases methyl mercury of farm-raised common carp (Cyprinus carpio L.).

    Schultz, Sebastian; Vallant, Birgit; Kainz, Martin J

    2012-03-29

    This study on aquaculture ponds investigated how diet sources affect methyl mercury (MeHg) bioaccumulation of the worldwide key diet fish, common carp ( Cyprinus carpio ). We tested how MeHg concentrations of one and two year-old pond-raised carp changed with different food quality: a) zooplankton (natural pond diet), b) cereals enriched with vegetable oil (VO ponds), and c) compound feeds enriched with marine fish oils (FO ponds). It was hypothesized that carp preferentially feed on supplementary diets with the highest biochemical quality (FO diet over VO diets over zooplankton). Although MeHg concentrations were highest in zooplankton of FO ponds, MeHg concentrations of carp were clearly lower in FO ponds (17-32 ng g - 1 dry weight) compared to the reference (40-46 ng g - 1 dry weight) and VO ponds (55-86 ng g - 1 dry weight). Stable isotope mixing models (δ 13 C, δ 15 N) indicated selective feeding of carp on high quality FO diets that caused MeHg concentrations of carp to decrease with increasing dietary proportions of supplementary FO feeds. Results demonstrate that carp selectively feed on diets of highest biochemical quality and strongly suggest that high diet quality can reduce MeHg bioaccumulation in farm-raised carp.

  9. Water quality issues in southern Nigeria

    Ajayi, O.

    2000-07-01

    There is a keen awareness of the effects of water quality on human health and behaviour in developing countries arising from well documented cases which can be found in the literature. Also in Nigeria there are various concerns about incidents of toxic waste disposal, groundwater pollution through oil spillages, waste disposal practices by agricultural, domestic and industrial activities which affect the domestic water supplies and the environment. The aims of this paper are to highlight the role of water quality in human health; provide a framework for water related health assessment, present results of case studies and recommend appropriate strategies to safeguard human health from contaminated water sources. Major health problems, other than those due to micro-biological contamination of water sources, such as cholera and typhoid, have not been reported or linked to water supplies in Nigeria. Yet there are symptoms of and growing incidences of various diseases, such as psychopathic and neurological disorders which have been linked to contaminated water supplies in developed countries. The major, minor and trace concentrations of elements in water supplies in Nigeria are usually determined in the ppm range whereas most trace elements are hazardous to human health in the ppb or μg/l levels. The reason for this state of affairs is that the instrumentation required for determination of elemental concentrations at the ppb level is not readily available to researchers. Most reports on water quality do not provide any links to the major health problems which have been demonstrated elsewhere as responsible for major pathologic and neurologic disorders, including outright fatalities. Recent studies in Europe and Japan link several diseases, including kidney failure, mood disturbance and other neurologic disorders, heart, liver and kidney damage including death from eating poisonous fish caught in polluted waters, to contamination of water supplies by heavy metals in

  10. Storm water and wastewater management for improving water quality

    Boogaard, Floris; Vojinovic, Zoran; Heikoop, Rick

    Climate change and urbanization will increase the frequency and magnitude of urban flooding and water quality problems in many regions of the world. In coastal and delta areas like The Netherlands and the Philippines, where urbanization is often high, there has been an increase in the adoption of

  11. The WIPP Water Quality Sampling Program

    Uhland, D.; Morse, J.G.; Colton, D.

    1986-01-01

    The Waste Isolation Pilot Plant (WIPP), a Department of Energy facility, will be used for the underground disposal of wastes. The Water Quality Sampling Program (WQSP) is designed to obtain representative and reproducible water samples to depict accurate water composition data for characterization and monitoring programs in the vicinity of the WIPP. The WQSP is designed to input data into four major programs for the WIPP project: Geochemical Site Characterization, Radiological Baseline, Environmental Baseline, and Performance Assessment. The water-bearing units of interest are the Culebra and Magneta Dolomite Members of the Rustler Formation, units in the Dewey Lake Redbeds, and the Bell Canyon Formation. At least two chemically distinct types of water occur in the Culebra, one being a sodium/potassium chloride water and the other being a calcium/magnesium sulfate water. Water from the Culebra wells to the south of the WIPP site is distinctly fresher and tends to be of the calcium/magnesium sulfate type. Water in the Culebra in the north and around the WIPP site is distinctly fresher and tends to be of the sodium/potassium chloride type and is much higher in total dissolved solids. The program, which is currently 1 year old, will continue throughout the life of the facility as part of the Environmental Monitoring Program

  12. Mercury content in Hot Springs

    Nakagawa, R

    1974-01-01

    A method of determination of mercury in hot spring waters by flameless atomic absorption spectrophotometry is described. Further, the mercury content and the chemical behavior of the elementary mercury in hot springs are described. Sulfide and iodide ions interfered with the determination of mercury by the reduction-vapor phase technique. These interferences could, however, be minimized by the addition of potassium permanganate. Waters collected from 55 hot springs were found to contain up to 26.0 ppb mercury. High concentrations of mercury have been found in waters from Shimoburo Springs, Aomori (10.0 ppb), Osorezan Springs, Aomori (1.3 approximately 18.8 ppb), Gosyogake Springs, Akita (26.0 ppb), Manza Springs, Gunma (0.30 approximately 19.5 ppb) and Kusatu Springs, Gunma (1.70 approximately 4.50 ppb). These hot springs were acid waters containing a relatively high quantity of chloride or sulfate.

  13. SF Bay Water Quality Improvement Fund: Projects and Accomplishments

    San Francisco Bay Water Quality Improvement Fund (SFBWQIF) projects listed here are part of an EPA competitive grant program to improve SF Bay water quality focused on restoring impaired waters and enhancing aquatic resources.

  14. Water quality of the Chhoti Gandak River using principal component ...

    ; therefore water samples were collected to analyse its quality along the entire length of Chhoti Gandak. River. The principal components of water quality are controlled by lithology, gentle slope gradient, poor drainage, long residence of water, ...

  15. Identification of water quality degradation hotspots in developing countries by applying large scale water quality modelling

    Malsy, Marcus; Reder, Klara; Flörke, Martina

    2014-05-01

    Decreasing water quality is one of the main global issues which poses risks to food security, economy, and public health and is consequently crucial for ensuring environmental sustainability. During the last decades access to clean drinking water increased, but 2.5 billion people still do not have access to basic sanitation, especially in Africa and parts of Asia. In this context not only connection to sewage system is of high importance, but also treatment, as an increasing connection rate will lead to higher loadings and therefore higher pressure on water resources. Furthermore, poor people in developing countries use local surface waters for daily activities, e.g. bathing and washing. It is thus clear that water utilization and water sewerage are indispensable connected. In this study, large scale water quality modelling is used to point out hotspots of water pollution to get an insight on potential environmental impacts, in particular, in regions with a low observation density and data gaps in measured water quality parameters. We applied the global water quality model WorldQual to calculate biological oxygen demand (BOD) loadings from point and diffuse sources, as well as in-stream concentrations. Regional focus in this study is on developing countries i.e. Africa, Asia, and South America, as they are most affected by water pollution. Hereby, model runs were conducted for the year 2010 to draw a picture of recent status of surface waters quality and to figure out hotspots and main causes of pollution. First results show that hotspots mainly occur in highly agglomerated regions where population density is high. Large urban areas are initially loading hotspots and pollution prevention and control become increasingly important as point sources are subject to connection rates and treatment levels. Furthermore, river discharge plays a crucial role due to dilution potential, especially in terms of seasonal variability. Highly varying shares of BOD sources across

  16. Sources of mercury in sediments, water, and fish of the lakes of Whatcom County, Washington

    Paulson, Anthony J.

    2004-01-01

    Concerns about mercury (Hg) contamination in Lake Whatcom, Washington, were raised in the late 1990s after a watershed protection survey reported elevated concentrations of Hg in smallmouth bass. The U.S. Geological Survey, the Whatcom County Health Department, and the Washington State Department of Ecology (Ecology) cooperated to develop a study to review existing data and collect new data that would lead to a better understanding of Hg deposition to Lake Whatcom and other lakes in Whatcom County, Washington. A simple atmospheric deposition model was developed that allowed comparisons of the deposition of Hg to the surfaces of each lake. Estimates of Hg deposition derived from the model indicated that the most significant deposition of Hg would have occurred to the lakes north of the City of Bellingham. These lakes were in the primary wind pattern of two municipal waste incinerators. Of all the lakes examined, basin 1 of Lake Whatcom would have been most affected by the Hg emissions from the chlor-alkali plant and the municipal sewage-sludge incinerator in the City of Bellingham. The length-adjusted concentrations of Hg in largemouth and smallmouth bass were not related to estimated deposition rates of Hg to the lakes from local atmospheric sources. Total Hg concentrations in the surface sediments of Lake Whatcom are affected by the sedimentation of fine-grained particles, whereas organic carbon regulates the concentration of methyl-Hg in the surface sediments of the lake. Hg concentrations in dated sediment core samples indicate that increases in Hg sedimentation were largest during the first half of the 20th century. Increases in Hg sedimentation were smaller after the chlor-alkali plant and the incinerators began operating between 1964 and 1984. Analysis of sediments recently deposited in basin 1 of Lake Whatcom, Lake Terrell, and Lake Samish indicates a decrease in Hg sedimentation. Concentrations of Hg in Seattle precipitation and in tributary waters were

  17. THE WATER QUALITY FROM SAINT ANA LAKE

    M.VIGH

    2013-03-01

    Full Text Available Inside the Ciomad Massive appears a unique lake in Romania, with an exclusive precipitations alimentation regime. The lake’s origin and the morphometric elements, together with the touristic activity, determine the water’s quality and characteristics. Water status evaluation was realized using random samples taken between the years 2005 and 2010. Qualitative parameters indicate the existence of a clear water lake, belonging to ultra-oligotrophic faze. This is because the crater is covered with forest and the surface erosion is very poor. Also the aquatic vegetation is rare. From all analyzed indicators, only ammonium and total mineral nitrogen have higher values during last years. In the future, the lake needs a higher protection against water quality degradation.

  18. Speciation analysis of mercury in sediments, zoobenthos and river water samples by high-performance liquid chromatography hyphenated to atomic fluorescence spectrometry following preconcentration by solid phase extraction

    Margetinova, Jana; Houserova-Pelcova, Pavlina; Kuban, Vlastimil

    2008-01-01

    A high-pressure microwave digestion was applied for microwave-assisted extraction (MAE) of mercury species from sediments and zoobenthos samples. A mixture containing 3 mol L -1 HCl, 50% aqueous methanol and 0.2 mol L -1 citric acid (for masking co-extracted Fe 3+ ) was selected as the most suitable extraction agent. The efficiency of proposed extraction method was better than 95% with R.S.D. below 6%. A preconcentration method utilizing a 'homemade' C18 solid phase extraction (SPE) microcolumns was developed to enhance sensitivity of the mercury species determination using on-column complex formation of mercury-2-mercaptophenol complexes. Methanol was chosen for counter-current elution of the retained mercury complexes achieving a preconcentration factor as much as 1000. The preconcentration method was applied for the speciation analysis of mercury in river water samples. The high-performance liquid chromatography-cold vapour atomic fluorescence spectrometric (HPLC/CV-AFS) method was used for the speciation analysis of mercury. The complete separation of four mercury species was achieved by an isocratic elution of aqueous methanol (65%/35%) on a Zorbax SB-C18 column (4.6 mm x 150 mm, 5 μm) using the same complexation reagent (2-mercaptophenol). The limits of detection were 4.3 μg L -1 for methylmercury (MeHg + ), 1.4 μg L -1 for ethylmercury (EtHg + ), 0.8 μg L -1 for inorganic mercury (Hg 2+ ), 0.8 μg L -1 for phenylmercury (PhHg + )

  19. Mercury: Aspects of its ecology and environmental toxicity. [physiological effects of mercury compound contamination of environment

    Siegel, S. M.

    1973-01-01

    A study was conducted to determine the effects of mercury pollution on the environment. The possible sources of mercury contamination in sea water are identified. The effects of mercury on food sources, as represented by swordfish, are analyzed. The physiological effects of varying concentrations of mercury are reported. Emphasis is placed on the situation existing in the Hawaiian Islands.

  20. Groundwater Modeling Of Mercury Pollution At A Former Mercury Cell Chlor Alkali Facility In Pavoldar, Kazakhstan

    In Kazakhstan, there is a serious case of mercury pollution near the city of Pavlodar from an old mercury cell chlor-alkali plant. The soil, sediment, and water is severly contaminated with mercury and mercury compounds as a result of the industrial activity of this chemical pla...

  1. Quality-assurance plan for water-quality activities in the U.S. Geological Survey Washington Water Science Center

    Conn, Kathleen E.; Huffman, Raegan L.; Barton, Cynthia

    2017-05-08

    In accordance with guidelines set forth by the Office of Water Quality in the Water Mission Area of the U.S. Geological Survey, a quality-assurance plan has been created for use by the Washington Water Science Center (WAWSC) in conducting water-quality activities. This qualityassurance plan documents the standards, policies, and procedures used by the WAWSC for activities related to the collection, processing, storage, analysis, and publication of water-quality data. The policies and procedures documented in this quality-assurance plan for water-quality activities complement the quality-assurance plans for surface-water and groundwater activities at the WAWSC.

  2. Cluster analysis and quality assessment of logged water at an irrigation project, eastern Saudi Arabia.

    Hussain, Mahbub; Ahmed, Syed Munaf; Abderrahman, Walid

    2008-01-01

    A multivariate statistical technique, cluster analysis, was used to assess the logged surface water quality at an irrigation project at Al-Fadhley, Eastern Province, Saudi Arabia. The principal idea behind using the technique was to utilize all available hydrochemical variables in the quality assessment including trace elements and other ions which are not considered in conventional techniques for water quality assessments like Stiff and Piper diagrams. Furthermore, the area belongs to an irrigation project where water contamination associated with the use of fertilizers, insecticides and pesticides is expected. This quality assessment study was carried out on a total of 34 surface/logged water samples. To gain a greater insight in terms of the seasonal variation of water quality, 17 samples were collected from both summer and winter seasons. The collected samples were analyzed for a total of 23 water quality parameters including pH, TDS, conductivity, alkalinity, sulfate, chloride, bicarbonate, nitrate, phosphate, bromide, fluoride, calcium, magnesium, sodium, potassium, arsenic, boron, copper, cobalt, iron, lithium, manganese, molybdenum, nickel, selenium, mercury and zinc. Cluster analysis in both Q and R modes was used. Q-mode analysis resulted in three distinct water types for both the summer and winter seasons. Q-mode analysis also showed the spatial as well as temporal variation in water quality. R-mode cluster analysis led to the conclusion that there are two major sources of contamination for the surface/shallow groundwater in the area: fertilizers, micronutrients, pesticides, and insecticides used in agricultural activities, and non-point natural sources.

  3. Evaluation of Ravi river water quality

    Ahmed, K.; Ali, W.

    2000-01-01

    Investigation from 1989 to 1998 on river Ravi pollution was carried out to study the effects of wastewater discharges on its water quality in relation to its various water use. The sources of pollution entering the river between Syphon (20 Km upstream) and Balloki Head works (75 Km downstream) includes Upper Chenab Canal (U.C.) which bring industrial effluents through Deg municipal swage from the city of Lahore. Investigation revealed that the flow in the river are highly variable with time during the year U.C. canal with a capacity of 220 m/sup 3//S at the tail and Qadiarabad (Q.B.) Link canal with a capacity of 410 m3/S are mainly responsible for higher flows during dry season. A desecrating trend has been observed in the D.O. Levels indicating increasing pollution. Over times D.O values are above 4 mg/l indicating recovery due to dilution biodegradation and aeration. An increasing trend has been observed in Biochemical Oxygen Demand (BOD), suspended solids, total dissolved solids and indicator organisms. Even with the discharges of pollutions from U.C. canal, Hudiara Nullah and city sewage, BOD at Balloki was unexpectedly low. It was investigated that because of pollution free Q.B. link canal which joins the river just before Balloki Head works makes the water diluted, which accounted for low BOD. Water of river Ravi meet the chemical water quality requirement for irrigation. However the water quality does not meet the coliform and faecal coliform criteria for most water use. (orig../A.B.)

  4. Assessing water quality of rural water supply schemes as a measure ...

    Assessing water quality of rural water supply schemes as a measure of service ... drinking water quality parameters were within the World Health Organization ... Besides, disinfection of water at the household level can be an added advantage.

  5. Integrating Product Water Quality Effects In Holistic Assessments Of Water Systems

    Rygaard, Martin

    2011-01-01

    economic assessment of water quality effects, production costs and environmental costs (water abstraction and CO2-emissions). Considered water quality issues include: health (dental caries, cardiovascular diseases, eczema), corrosion (lifetime of appliances, pipes), consumption of soap, and bottled water...

  6. Current state of knowledge of the concentration of mercury and other heavy metals in fresh water fish in Colombia

    Mancera Rodriguez, Nestor Javier; Alvarez Leon, Ricardo

    2006-01-01

    One of the most important environmental problems in the country refers to the indiscriminate use of chemical precursors in illicit activities, the use of heavy metals as mercury in mining activities, the spill of served waters and another type of compound related with the industrial activities of raw and the inadequate agricultural practices. This has led to chemical contamination especially by heavy metals, considered one of the most dangerous for the aquatic ecosystems and the present species in them. Fish have the capacity to store these compounds in their organism in a concentration higher than that in the surrounding environment (water), therefore, their concentration are important indicators of the contamination level, but also this implies that their consumption can become a serious health problem for the populations that feeds from them. The concentration of heavy metals in fish of fresh water is better known in the basin of the Magdalena river, especially in the region of the Mojana and in the marshes of the south of the department of Bolivar where the levels of contamination by mercury and other metals has been studied due to the development of multiple industrial activities, including gold mining and petrochemical industries. However, little is known in the country about the problem generated by the disposal heavy metals in rivers and lakes and their impact on the fish resource, deterioration of ecosystems and human health. Based in the current norms bio-assays have been used to check the effects of the aquatic contamination on fresh waters fish and the evaluation of at least three parameters (heavy metals, temperature, effluents) in eight species of fresh waters fish: carassius auratus, oreochromis spp., piractus brachypomus, prochilodus magdalenae, astyanax fasciatus, colossoma bidens, gambusia affinis and grundulus bogotensis

  7. Quality and Control of Water Vapor Winds

    Jedlovec, Gary J.; Atkinson, Robert J.

    1996-01-01

    Water vapor imagery from the geostationary satellites such as GOES, Meteosat, and GMS provides synoptic views of dynamical events on a continual basis. Because the imagery represents a non-linear combination of mid- and upper-tropospheric thermodynamic parameters (three-dimensional variations in temperature and humidity), video loops of these image products provide enlightening views of regional flow fields, the movement of tropical and extratropical storm systems, the transfer of moisture between hemispheres and from the tropics to the mid- latitudes, and the dominance of high pressure systems over particular regions of the Earth. Despite the obvious larger scale features, the water vapor imagery contains significant image variability down to the single 8 km GOES pixel. These features can be quantitatively identified and tracked from one time to the next using various image processing techniques. Merrill et al. (1991), Hayden and Schmidt (1992), and Laurent (1993) have documented the operational procedures and capabilities of NOAA and ESOC to produce cloud and water vapor winds. These techniques employ standard correlation and template matching approaches to wind tracking and use qualitative and quantitative procedures to eliminate bad wind vectors from the wind data set. Techniques have also been developed to improve the quality of the operational winds though robust editing procedures (Hayden and Veldon 1991). These quality and control approaches have limitations, are often subjective, and constrain wind variability to be consistent with model derived wind fields. This paper describes research focused on the refinement of objective quality and control parameters for water vapor wind vector data sets. New quality and control measures are developed and employed to provide a more robust wind data set for climate analysis, data assimilation studies, as well as operational weather forecasting. The parameters are applicable to cloud-tracked winds as well with minor

  8. Environmental Monitoring, Water Quality - MO 2009 Stream Team Volunteer Water Quality Monitoring Sites (SHP)

    NSGIC State | GIS Inventory — This data set shows the monitoring locations of trained Volunteer Water Quality Monitors. A monitoring site is considered to be a 300 foot section of stream channel....

  9. Water quality management in shrimp aquaculture ponds using remote water quality logging system

    Sreepada, R.A.; Kulkarni, S.; Suryavanshi, U.; Ingole, B.S.; Drensgstig, A.; Braaten, B.

    Currently an institutional co-operation project funded by NORAD is evaluating different environmental management strategies for sustainable aquaculture in India. A brief description of a remote water quality logging system installed in shrimp ponds...

  10. Water Quality Vocabulary Development and Deployment

    Simons, B. A.; Yu, J.; Cox, S. J.

    2013-12-01

    Semantic descriptions of observed properties and associated units of measure are fundamental to understanding of environmental observations, including groundwater, surface water and marine water quality. Semantic descriptions can be captured in machine-readable ontologies and vocabularies, thus providing support for the annotation of observation values from the disparate data sources with appropriate and accurate metadata, which is critical for achieving semantic interoperability. However, current stand-alone water quality vocabularies provide limited support for cross-system comparisons or data fusion. To enhance semantic interoperability, the alignment of water-quality properties with definitions of chemical entities and units of measure in existing widely-used vocabularies is required. Modern ontologies and vocabularies are expressed, organized and deployed using Semantic Web technologies. We developed an ontology for observed properties (i.e. a model for expressing appropriate controlled vocabularies) which extends the NASA/TopQuadrant QUDT ontology for Unit and QuantityKind with two additional classes and two properties (see accompanying paper by Cox, Simons and Yu). We use our ontology to populate the Water Quality vocabulary with a set of individuals of each of the four key classes (and their subclasses), and add appropriate relationships between these individuals. This ontology is aligned with other relevant stand-alone Water Quality vocabularies and domain ontologies. Developing the Water Quality vocabulary involved two main steps. First, the Water Quality vocabulary was populated with individuals of the ObservedProperty class, which was determined from a census of existing datasets and services. Each ObservedProperty individual relates to other individuals of Unit and QuantityKind (taken from QUDT where possible), and to IdentifiedObject individuals. As a large fraction of observed water quality data are classified by the chemical substance involved, the

  11. Westinghouse Water Reactor Divisions quality assurance plan

    1977-09-01

    The Quality Assurance Program used by Westinghouse Water Reactor Divisions is described. The purpose of the program is to assure that the design, materials, and workmanship on Nuclear Steam Supply System (NSSS) equipment meet applicable safety requirements, fulfill the requirements of the contracts with the applicants, and satisfy the applicable codes, standards, and regulatory requirements. This program satisfies the NRC Quality Assurance Criteria, 10CFR50 Appendix B, to the extent that these criteria apply to safety related NSSS equipment. Also, it follows the regulatory position provided in NRC regulatory guides and the requirements of ANSI Standard N45.2.12 as identified in this Topical Report

  12. Investigation of Performance of hybrid nanoparticles Tio2/Sio2 in removing of Mercury from industrial waste water

    M Malakootian

    2014-09-01

    Conclusion: Due to high percentage of mercury removal at optimal conditions by hybrid nanoparticles, this method can be regarded as one of the effective ways to remove mercury compared with other methods.

  13. Quality control in public participation assessments of water quality: the OPAL Water Survey.

    Rose, N L; Turner, S D; Goldsmith, B; Gosling, L; Davidson, T A

    2016-07-22

    Public participation in scientific data collection is a rapidly expanding field. In water quality surveys, the involvement of the public, usually as trained volunteers, generally includes the identification of aquatic invertebrates to a broad taxonomic level. However, quality assurance is often not addressed and remains a key concern for the acceptance of publicly-generated water quality data. The Open Air Laboratories (OPAL) Water Survey, launched in May 2010, aimed to encourage interest and participation in water science by developing a 'low-barrier-to-entry' water quality survey. During 2010, over 3000 participant-selected lakes and ponds were surveyed making this the largest public participation lake and pond survey undertaken to date in the UK. But the OPAL approach of using untrained volunteers and largely anonymous data submission exacerbates quality control concerns. A number of approaches were used in order to address data quality issues including: sensitivity analysis to determine differences due to operator, sampling effort and duration; direct comparisons of identification between participants and experienced scientists; the use of a self-assessment identification quiz; the use of multiple participant surveys to assess data variability at single sites over short periods of time; comparison of survey techniques with other measurement variables and with other metrics generally considered more accurate. These quality control approaches were then used to screen the OPAL Water Survey data to generate a more robust dataset. The OPAL Water Survey results provide a regional and national assessment of water quality as well as a first national picture of water clarity (as suspended solids concentrations). Less than 10 % of lakes and ponds surveyed were 'poor' quality while 26.8 % were in the highest water quality band. It is likely that there will always be a question mark over untrained volunteer generated data simply because quality assurance is uncertain

  14. Influence of microorganism content in suspended particles on the particle-water partitioning of mercury in semi-enclosed coastal waters.

    Jang, Jiyi; Kim, Hyunji; Han, Seunghee

    2014-02-01

    It is known that particle scavenging of mercury (Hg) can be affected by the abundance of particulate organic matter in coastal waters. However, the role of living organic particles in Hg scavenging is not yet completely understood. In this study, we hypothesized that an abundance of living organic particles (i.e., phytoplankton and bacteria) would influence the particle-water partitioning of Hg in coastal waters. Surface seawater samples were collected from eight stations in Gwangyang Bay, Korea, in three seasons (November 2009, April 2010, and October 2010) for the determination of concentrations of suspended particulate matter (including chlorophyll-a and bacteria), and Hg in unfiltered and filtered waters. We found that more Hg partitioned toward particulate matter when phytoplankton biomass, indicated from the chlorophyll-a concentration in a particle, was higher. In the low algal season, when [chlorophyll-a]algae to transfer Hg to marine food chains. © 2013.

  15. Effects of equipment performance on data quality from the National Atmospheric Deposition Program/National Trends Network and the Mercury Deposition Network

    Wetherbee, Gregory A.; Rhodes, Mark F.

    2013-01-01

    The U.S. Geological Survey Branch of Quality Systems operates the Precipitation Chemistry Quality Assurance project (PCQA) to provide independent, external quality-assurance for the National Atmospheric Deposition Program (NADP). NADP is composed of five monitoring networks that measure the chemical composition of precipitation and ambient air. PCQA and the NADP Program Office completed five short-term studies to investigate the effects of equipment performance with respect to the National Trends Network (NTN) and Mercury Deposition Network (MDN) data quality: sample evaporation from NTN collectors; sample volume and mercury loss from MDN collectors; mercury adsorption to MDN collector glassware, grid-type precipitation sensors for precipitation collectors, and the effects of an NTN collector wind shield on sample catch efficiency. Sample-volume evaporation from an NTN Aerochem Metrics (ACM) collector ranged between 1.1–33 percent with a median of 4.7 percent. The results suggest that weekly NTN sample evaporation is small relative to sample volume. MDN sample evaporation occurs predominantly in western and southern regions of the United States (U.S.) and more frequently with modified ACM collectors than with N-CON Systems Inc. collectors due to differences in airflow through the collectors. Variations in mercury concentrations, measured to be as high as 47.5 percent per week with a median of 5 percent, are associated with MDN sample-volume loss. Small amounts of mercury are also lost from MDN samples by adsorption to collector glassware irrespective of collector type. MDN 11-grid sensors were found to open collectors sooner, keep them open longer, and cause fewer lid cycles than NTN 7-grid sensors. Wind shielding an NTN ACM collector resulted in collection of larger quantities of precipitation while also preserving sample integrity.

  16. Evaluation the concentration of mercury, zinc, arsenic, lead and cobalt in the Ilam city water supply network and resources

    Ahmad Reza Yazdanbakhsh

    2017-04-01

    Full Text Available Background: The presence of heavy metals in water resources above threshold levels can be toxic and carcinogenic for consumers. This study determined the concentrations of heavy metals in the drinking water distribution network and resources of the city of Ilam in Iran. Methods: In this cross-sectional study from 6 sources of water supply and also, different parts of the water supply system of Ilam city, samples were collected based on standard sampling methods. The samples were tested with a BRAIC atomic absorption spectrophotometer. The data was analyzed using nonparametric Mann-Whitney test. Results: The concentration of zinc in all water sources of the city of Ilam was higher than WHO guidelines and Iranian standard 1053. Contamination by cobalt, arsenic and lead from Ilam dam, Pich-e Ashoori well and Haft Cheshmeh well was higher than national and international standards. The amount of cobalt and mercury at Ilam dam was significantly different from the levels at other sources (P < 0.05. Conclusion: The use of pesticides in the agricultural sector, contamination of water by human waste and aged and worn water pipes are the likely sources of the increased concentrations of heavy metals, especially lead and arsenic. Because there is a cumulative effect from these metals, appropriate measures are necessary by the relevant agencies to address this problem.

  17. Determination of mercury and copper in water samples by activation analysis using preconcentration on emission spectroscopic carbon powder

    Nagatsuka, Sumiko; Tanizaki, Yoshiyuki

    1978-01-01

    A simple preconcentration procedure for mercury and copper was examined in the activation analysis of water samples. The preconcentration using pure activated carbon has been reported in several papers. The authors found that the carbon powder for emission spectroscopic analysis showed the high purity equivalent to pure activated carbon. The influence of various parameters in adsorption conditions was studied by radioactive tracers 197 Hg and 64 Cu. It was confirmed that 100% of these elements were adsorbed on carbon powders as pyrrolidine dithiocarbonate complexes at an acidity of pH 6 - 8, the temperature of 50 0 C and the stirring time of 30 minutes. This method was applied to the activation analysis of the river water samples taken from the upper stream area of the Arakawa river and the ground water samples taken from the wells of the environs of Tokyo Megalopolis. The carbon powders which adsorbed these elements were filtered, dried and analyzed by instrumental neutron activation analysis. The Hg concentrations of 0.01 - 0.1 ppb in river water and 0.03 - 1.4 ppb in ground water were obtained as well as the Cu concentrations of 0.3 - 3.0 ppb in ground water. The limits of determination of this method are 0.01 ppb Hg and 0.2 ppb Cu in the case of 1.1 sample of fresh water. (auth.)

  18. Application of a DNA-based luminescence switch-on method for the detection of mercury(II) ions in water samples from Hong Kong

    He, Hong-Zhang; Leung, Ka-Ho; Fu, Wai-Chung; Shiu-Hin Chan, Daniel; Leung, Chung-Hang; Ma, Dik-Lung

    2012-12-01

    Mercury is a highly toxic environmental contaminant that damages the endocrine and central nervous systems. In view of the contamination of Hong Kong territorial waters with anthropogenic pollutants such as trace heavy metals, we have investigated the application of our recently developed DNA-based luminescence methodology for the rapid and sensitive detection of mercury(II) ions in real water samples. The assay was applied to water samples from Shing Mun River, Nam Sang Wai and Lamma Island sea water, representing natural river, wetland and sea water media, respectively. The results showed that the system could function effectively in real water samples under conditions of low turbidity and low metal ion concentrations. However, high turbidity and high metal ion concentrations increased the background signal and reduced the performance of this assay.

  19. Water Quality Protection from Nutrient Pollution: Case ...

    Water bodies and coastal areas around the world are threatened by increases in upstream sediment and nutrient loads, which influence drinking water sources, aquatic species, and other ecologic functions and services of streams, lakes, and coastal water bodies. For example, increased nutrient fluxes from the Mississippi River Basin have been linked to increased occurrences of seasonal hypoxia in northern Gulf of Mexico. Lake Erie is another example where in the summer of 2014 nutrients, nutrients, particularly phosphorus, washed from fertilized farms, cattle feedlots, and leaky septic systems; caused a severe algae bloom, much of it poisonous; and resulted in the loss of drinking water for a half-million residents. Our current management strategies for point and non-point source nutrient loadings need to be improved to protect and meet the expected increased future demands of water for consumption, recreation, and ecological integrity. This presentation introduces management practices being implemented and their effectiveness in reducing nutrient loss from agricultural fields, a case analysis of nutrient pollution of the Grand Lake St. Marys and possible remedies, and ongoing work on watershed modeling to improve our understanding on nutrient loss and water quality. Presented at the 3rd International Conference on Water Resource and Environment.

  20. Concentration of mercury and selenium in tissues of five cetacean species from Croatian coastal waters

    Bilandžić Nina

    2015-01-01

    Full Text Available Mercury (Hg and selenium (Se concentrations were measured in muscle, liver, kidney, spleen and lung tissues of five cetacean species, three dolphin (Stenella coeruleoalba, Tursiops truncatus and Grampus griseus and two whale species (Balaenoptera physalus and Ziphius cavirostris, stranded along the Croatian coast during the period 1999-2002. Statistically significant differences in Hg concentrations in muscle, spleen and lung, and Se in liver and lung of the different dolphin species were observed. Mercury levels in liver and spleen and Se levels in liver differed between young and adult T. truncatus species. A significant positive correlation between different tissue types for Hg and Se concentrations was observed. In all tissues tested, the lowest Hg and Se concentrations were found in B. physalus. Mercury concentrations were positively correlated with Se in all tissues. The results present one of few studies related to lung and spleen tissues in these mammals, particularly in the Adriatic Sea. Since very little data are available, this research provides new data on concentrations of Hg and Se in five cetacean species from the Adriatic Sea basin.

  1. Mercury and Your Health

    ... the Risk of Exposure to Mercury Learn About Mercury What is Mercury What is Metallic mercury? Toxicological Profile ToxFAQs Mercury Resources CDC’s National Biomonitoring Program Factsheet on Mercury ...

  2. Estimation of Seasonal Risk Caused by the Intake of Lead, Mercury and Cadmium through Freshwater Fish Consumption from Urban Water Reservoirs in Arid Areas of Northern Mexico

    Myrna Nevárez

    2015-02-01

    Full Text Available Bioavailability and hence bioaccumulation of heavy metals in fish species depends on seasonal conditions causing different risks levels to human health during the lifetime. Mercury, cadmium and lead contents in fish from Chihuahua (Mexico water reservoirs have been investigated to assess contamination levels and safety for consumers. Muscle samples of fish were collected across the seasons. Lead and cadmium were analyzed by inductively coupled plasma-optical emission spectrometry, and mercury by cold-vapor atomic absorption spectrometry. The highest concentrations of cadmium (0.235 mg/kg, mercury (0.744 mg/kg and lead (4.298 mg/kg exceeded the maximum levels set by European regulations and Codex Alimentarius. Lead concentrations found in fish from three water reservoirs also surpassed the limit of 1 mg/kg established by Mexican regulations. The provisional tolerable weekly intake (PTWI suggested by the World Health Organization for methyl mercury (1.6 µg/kg bw per week was exceeded in the spring season (1.94 µg/kg bw per week. This might put consumers at risk of mercury poisoning.

  3. Microbial water quality of treated water and raw water sources in the ...

    Microbial water quality is an essential aspect in the provision of potable water for domestic use. The provision of adequate amounts of safe water for domestic purposes has become difficult for most municipalities mandated to do so in Zimbabwe. Morton-Jaffray Treatment Plant supplies potable water to Harare City and ...

  4. 40 CFR 130.4 - Water quality monitoring.

    2010-07-01

    ... QUALITY PLANNING AND MANAGEMENT § 130.4 Water quality monitoring. (a) In accordance with section 106(e)(1...; developing and reviewing water quality standards, total maximum daily loads, wasteload allocations and load... 40 Protection of Environment 21 2010-07-01 2010-07-01 false Water quality monitoring. 130.4...

  5. 40 CFR 130.8 - Water quality report.

    2010-07-01

    ... 40 Protection of Environment 21 2010-07-01 2010-07-01 false Water quality report. 130.8 Section... QUALITY PLANNING AND MANAGEMENT § 130.8 Water quality report. (a) Each State shall prepare and submit biennially to the Regional Administrator a water quality report in accordance with section 305(b) of the Act...

  6. Current State of Knowledge of the Concentration of Mercury and Other Heavy Metals in Fresh Water Fish in Colombia

    Néstor Javier Mancera-Rodríguez

    2006-01-01

    Full Text Available One of the most important environmental problems in the country refers to the indiscriminate use of chemical precursors in illicit activities, the use of heavy metals as mercury in mining activities, the spill of served waters and another type of compound related with the industrial activities of raw and the inadequate agricultural practices. This has led to chemical contamination especially by heavy metals, considered one of the most dangerous for the aquatic ecosystems and the present species in them. Fish have the capacity to store these compounds in their organism in a concentration higher important indicators of the contamination level, but also this implies that their consumption can become a serious health problem for the populations that feeds from them. The concentration of heavy metals in fish of fresh water is better known in the basin of the Magdalena river, especially in the region of the Mojana and in the marshes of the south of the Department of Bolivar where the levels of contamination by mercury and other metals has been studied due to the development of multiple industrial activities, including gold mining and petrochemical industries. However, little is known in the country about the problem generated by the disposal heavy metals in rivers and lakes and their impact on the fish resource, deterioration of ecosystems and human health. Based in the current norms bio-assays have been used to check the effects of the aquatic contamination on fresh waters fish and the evaluation of at least three parameters (heavy metals, temperature, effluents in eight species of fresh waters fish: Carassius auratus, Oreochromis spp., Piractus brachypomus, Prochilodus magdalenae, Astyanax fasciatus, Colossoma bidens, Gambusia affinis and Grundulus bogotensis.

  7. Hydrological and Water Quality Characteristics of Rivers Feeding ...

    FDC analysis showed that over 80% of the time, all rivers in the study area would not meet the target community's water demand, without the dams in place. Water quality assessments show biological contamination as the major water quality problem. Significant seasonal variation in water quality is evident, with the dry ...

  8. A multivariate analysis of water quality in lake Naivasha, Kenya

    Ndungu, J.N.; Augustijn, Dionysius C.M.; Hulscher, Suzanne J.M.H.; Fulanda, B.; Kitaka, N.; Mathooko, J.M.

    2014-01-01

    Water quality information in aquatic ecosystems is crucial in setting up guidelines for resource management. This study explores the water quality status and pollution sources in Lake Naivasha, Kenya. Analysis of water quality parameters at seven sampling sites was carried out from water samples

  9. 7 CFR 634.23 - Water quality plan.

    2010-01-01

    ... 7 Agriculture 6 2010-01-01 2010-01-01 false Water quality plan. 634.23 Section 634.23 Agriculture... AGRICULTURE LONG TERM CONTRACTING RURAL CLEAN WATER PROGRAM Participant RCWP Contracts § 634.23 Water quality plan. (a) The participant's water quality plan, developed with technical assistance by the NRCS or its...

  10. 9 CFR 108.11 - Water quality requirements.

    2010-01-01

    ... 9 Animals and Animal Products 1 2010-01-01 2010-01-01 false Water quality requirements. 108.11... LICENSED ESTABLISHMENTS § 108.11 Water quality requirements. A certification from the appropriate water pollution control agency, that the establishment is in compliance with applicable water quality control...

  11. 77 FR 71191 - 2012 Recreational Water Quality Criteria

    2012-11-29

    ... ENVIRONMENTAL PROTECTION AGENCY [EPA-OW-2011-0466; FRL 9756-2] 2012 Recreational Water Quality... Recreational Water Quality Criteria. SUMMARY: Pursuant to section 304(a) of the Clean Water Act (CWA), the Environmental Protection Agency (EPA) is announcing the availability of the 2012 Recreational Water Quality...

  12. Water quality in New Zealand's planted forests: A review

    Brenda R. Baillie; Daniel G. Neary

    2015-01-01

    This paper reviewed the key physical, chemical and biological water quality attributes of surface waters in New Zealand’s planted forests. The purpose was to: a) assess the changes in water quality throughout the planted forestry cycle from afforestation through to harvesting; b) compare water quality from planted forests with other land uses in New Zealand; and c)...

  13. Pollution induced tidal variability in water quality of Mahim Estuary

    Zingde, M.D.; Sabnis, M.M.

    Variability of water quality due to release of wastewater in Mahim Estuary (Maharashtra, India) and associated nearshore waters is discussed. The mixing of low salinity contaminated estuary water with high salinity bay water was considerably...

  14. Effect of traditional gold mining to surface water quality in Murung Raya District, Central Kalimantan Province

    W.Wilopo

    2013-10-01

    Full Text Available There are many locations for traditional gold mining in Indonesia. One of these is in Murung Raya District, Central Kalimantan Province. Mining activities involving the application of traditional gold processing technology have a high potential to pollute the environment, especially surface water. Therefore, this study aims to determine the impact of gold mining and processing on surface water quality around the mine site. Based on the results of field surveys and laboratory analysis, our data shows that the concentration of mercury (Hg and Cyanide (CN has reached 0.3 mg/L and 1.9 mg/L, respectively, in surface water. These values exceed the drinking water quality standards of Indonesia and WHO. Many people who live in the mining area use surface water for daily purposes including drinking, cooking, bathing and washing. This scenario is very dangerous because the effect of surface water contamination on human health cannot be immediately recognized or diagnosed. In our opinion the dissemination of knowledge regarding the treatment of gold mining wastewater is urgently required so that the quality of wastewater can be improved before it is discharged into the environment

  15. Water Quality Index for measuring drinking water quality in rural Bangladesh: a cross-sectional study.

    Akter, Tahera; Jhohura, Fatema Tuz; Akter, Fahmida; Chowdhury, Tridib Roy; Mistry, Sabuj Kanti; Dey, Digbijoy; Barua, Milan Kanti; Islam, Md Akramul; Rahman, Mahfuzar

    2016-02-09

    Public health is at risk due to chemical contaminants in drinking water which may have immediate health consequences. Drinking water sources are susceptible to pollutants depending on geological conditions and agricultural, industrial, and other man-made activities. Ensuring the safety of drinking water is, therefore, a growing problem. To assess drinking water quality, we measured multiple chemical parameters in drinking water samples from across Bangladesh with the aim of improving public health interventions. In this cross-sectional study conducted in 24 randomly selected upazilas, arsenic was measured in drinking water in the field using an arsenic testing kit and a sub-sample was validated in the laboratory. Water samples were collected to test water pH in the laboratory as well as a sub-sample of collected drinking water was tested for water pH using a portable pH meter. For laboratory testing of other chemical parameters, iron, manganese, and salinity, drinking water samples were collected from 12 out of 24 upazilas. Drinking water at sample sites was slightly alkaline (pH 7.4 ± 0.4) but within acceptable limits. Manganese concentrations varied from 0.1 to 5.5 mg/L with a median value of 0.2 mg/L. The median iron concentrations in water exceeded WHO standards (0.3 mg/L) at most of the sample sites and exceeded Bangladesh standards (1.0 mg/L) at a few sample sites. Salinity was relatively higher in coastal districts. After laboratory confirmation, arsenic concentrations were found higher in Shibchar (Madaripur) and Alfadanga (Faridpur) compared to other sample sites exceeding WHO standard (0.01 mg/L). Of the total sampling sites, 33 % had good-quality water for drinking based on the Water Quality Index (WQI). However, the majority of the households (67 %) used poor-quality drinking water. Higher values of iron, manganese, and arsenic reduced drinking water quality. Awareness raising on chemical contents in drinking water at household level is required to

  16. Water-quality impact assessment for hydropower

    Daniil, E.I.; Gulliver, J.; Thene, J.R.

    1991-01-01

    A methodology to assess the impact of a hydropower facility on downstream water quality is described. Negative impacts can result from the substitution of discharges aerated over a spillway with minimally aerated turbine discharges that are often withdrawn from lower reservoir levels, where dissolved oxygen (DO) is typically low. Three case studies illustrate the proposed method and problems that can be encountered. Historic data are used to establish the probability of low-dissolved-oxygen occurrences. Synoptic surveys, combined with downstream monitoring, give an overall picture of the water-quality dynamics in the river and the reservoir. Spillway aeration is determined through measurements and adjusted for temperature. Theoretical computations of selective withdrawal are sensitive to boundary conditions, such as the location of the outlet-relative to the reservoir bottom, but withdrawal from the different layers is estimated from measured upstream and downstream temperatures and dissolved-oxygen profiles. Based on field measurements, the downstream water quality under hydropower operation is predicted. Improving selective withdrawal characteristics or diverting part of the flow over the spillway provided cost-effective mitigation solutions for small hydropower facilities (less than 15 MW) because of the low capital investment required

  17. Water quality diagnosis system for power plant

    Igarashi, Hiroo; Fukumoto, Toshihiko

    1991-01-01

    An AI diagnose system for the water quality control of a BWR type reactor is divided into a general diagnosing section for generally classifying the water quality conditions of the plant depending on a causal relation between the symptom of the water quality abnormality and its causes, generally diagnosing the position and the cause of the abnormality and ranking the items considered to be the cause, and a detail diagnosing section for a further diagnosis based on the result of the diagnosis in the former section. The general diagnosing section provides a plurality of threshold values showing the extent of the abnormality depending on the cause to the causal relation between the causes and the forecast events previously formed depending on the data of process sensors in the plant. Since the diagnosis for the abnormality and normality is given not only as an ON or OFF mode but also as the extent thereof, it can enter the detailed diagnosis in the most plausible order, based on a plurality of estimated causes, to enable to find the case and take a counter-measure in an early stage. (N.H.)

  18. Water quality data for national-scale aquatic research: The Water Quality Portal

    Read, Emily K.; Carr, Lindsay; De Cicco, Laura; Dugan, Hilary A.; Hanson, Paul C.; Hart, Julia A.; Kreft, James; Read, Jordan S.; Winslow, Luke A.

    2017-02-01

    xml:id="wrcr22485-sec-1001" numbered="no">Aquatic systems are critical to food, security, and society. But, water data are collected by hundreds of research groups and organizations, many of which use nonstandard or inconsistent data descriptions and dissemination, and disparities across different types of water observation systems represent a major challenge for freshwater research. To address this issue, the Water Quality Portal (WQP) was developed by the U.S. Environmental Protection Agency, the U.S. Geological Survey, and the National Water Quality Monitoring Council to be a single point of access for water quality data dating back more than a century. The WQP is the largest standardized water quality data set available at the time of this writing, with more than 290 million records from more than 2.7 million sites in groundwater, inland, and coastal waters. The number of data contributors, data consumers, and third-party application developers making use of the WQP is growing rapidly. Here we introduce the WQP, including an overview of data, the standardized data model, and data access and services; and we describe challenges and opportunities associated with using WQP data. We also demonstrate through an example the value of the WQP data by characterizing seasonal variation in lake water clarity for regions of the continental U.S. The code used to access, download, analyze, and display these WQP data as shown in the figures is included as supporting information.

  19. Water quality data for national-scale aquatic research: The Water Quality Portal

    Read, Emily K.; Carr, Lindsay; DeCicco, Laura; Dugan, Hilary; Hanson, Paul C.; Hart, Julia A.; Kreft, James; Read, Jordan S.; Winslow, Luke

    2017-01-01

    Aquatic systems are critical to food, security, and society. But, water data are collected by hundreds of research groups and organizations, many of which use nonstandard or inconsistent data descriptions and dissemination, and disparities across different types of water observation systems represent a major challenge for freshwater research. To address this issue, the Water Quality Portal (WQP) was developed by the U.S. Environmental Protection Agency, the U.S. Geological Survey, and the National Water Quality Monitoring Council to be a single point of access for water quality data dating back more than a century. The WQP is the largest standardized water quality data set available at the time of this writing, with more than 290 million records from more than 2.7 million sites in groundwater, inland, and coastal waters. The number of data contributors, data consumers, and third-party application developers making use of the WQP is growing rapidly. Here we introduce the WQP, including an overview of data, the standardized data model, and data access and services; and we describe challenges and opportunities associated with using WQP data. We also demonstrate through an example the value of the WQP data by characterizing seasonal variation in lake water clarity for regions of the continental U.S. The code used to access, download, analyze, and display these WQP data as shown in the figures is included as supporting information.

  20. Mercury in Nordic ecosystems

    Munthe, John; Waengberg, Ingvar (IVL Swedish Environmental Research Inst., Stockholm (SE)); Rognerud, Sigurd; Fjeld, Eirik (Norwegian Inst. for Water Research (NIVA), Oslo (Norway)); Verta, Matti; Porvari, Petri (Finnish Environment Inst. (SYKE), Helsinki (Finland)); Meili, Markus (Inst. of Applied Environmental Research (ITM), Stockholm (Sweden))

    2007-12-15

    pollution effects (i.e. methylmercury in fish). The general pattern of fish contamination follows to some extent a pattern similar to that of current and previous atmospheric pollution. Large areas have fish with mercury concentrations exceeding the health advisory guideline of 0.5 mg/kg or 1.0 mg/kg (for northern pike) in the EU and of around 0.3 mg/kg in the USA, thus restricting their use for human consumption. A more comprehensive assessment of factors influencing levels of methylmercury in fish has to include a number of other parameters such as catchment characteristics (e.g. relative size, presence of wetlands), contents and fluxes of DOC in soil run-off and surface waters as well as methylation potential within ecosystems

  1. Mercury concentration in black flies Simulium spp. (Diptera, Simuliidae) from soft-water streams in Ontario, Canada

    Harding, K.M.; Gowland, J.A.; Dillon, P.J.

    2006-01-01

    Total Hg in Simulium spp. (Diptera, Simuliidae) was measured in 17 soft-water streams in the District of Muskoka and Haliburton County (Ontario, Canada) during 2003 and 2004. Black flies contained 0.07-0.64 μg/g total Hg (dry weight). The methylmercury concentration was measured in 6 samples of the 17, and ranged from 58% to 93% of total Hg. The concentration of total Hg is much higher than has been found in other filter feeding insects, and represents a significant potential source of Hg to fish. Mercury concentrations in Simulium spp. at different sites were strongly positively correlated with dissolved organic carbon, and the proportion of land within each catchment that was wetland. There was also a strong negative correlation with pH. By examining Hg concentration in filter feeding insects we have found a significant entry point for Hg and MeHg into the food web. - Accumulation of total mercury by black fly larvae is affected by stream pH, DOC and wetland area in the stream catchment

  2. Inorganic mercury exposure in drinking water alters essential metal homeostasis in pregnant rats without altering rat pup behavior.

    Oliveira, Cláudia S; Oliveira, Vitor A; Costa, Lidiane M; Pedroso, Taíse F; Fonseca, Mariana M; Bernardi, Jamile S; Fiuza, Tiago L; Pereira, Maria E

    2016-10-01

    The aim of this work was to investigate the effects of HgCl 2 exposure in the doses of 0, 10 and 50μg Hg 2+ /mL in drinking water during pregnancy on tissue essential metal homeostasis, as well as the effects of HgCl 2 exposure in utero and breast milk on behavioral tasks. Pregnant rats exposed to both inorganic mercury doses presented high renal Hg content and an increase in renal Cu and hepatic Zn levels. Mercury exposure increased fecal Hg and essential metal contents. Pups exposed to inorganic Hg presented no alterations in essential metal homeostasis or in behavioral task markers of motor function. In conclusion, this work showed that the physiologic pregnancy and lactation states protected the offspring from adverse effects of low doses of Hg 2+ . This protection is likely to be related to the endogenous scavenger molecule, metallothionein, which may form an inert complex with Hg 2+ . Copyright © 2016 Elsevier Inc. All rights reserved.

  3. Mercury concentration in black flies Simulium spp. (Diptera, Simuliidae) from soft-water streams in Ontario, Canada

    Harding, K.M. [Trent University, 1600 West Bank Drive, Peterborough, ON K9J 7B8 (Canada); Gowland, J.A. [Trent University, 1600 West Bank Drive, Peterborough, ON K9J 7B8 (Canada); Dillon, P.J. [Trent University, 1600 West Bank Drive, Peterborough, ON K9J 7B8 (Canada)]. E-mail: pdillon@trentu.ca

    2006-10-15

    Total Hg in Simulium spp. (Diptera, Simuliidae) was measured in 17 soft-water streams in the District of Muskoka and Haliburton County (Ontario, Canada) during 2003 and 2004. Black flies contained 0.07-0.64 {mu}g/g total Hg (dry weight). The methylmercury concentration was measured in 6 samples of the 17, and ranged from 58% to 93% of total Hg. The concentration of total Hg is much higher than has been found in other filter feeding insects, and represents a significant potential source of Hg to fish. Mercury concentrations in Simulium spp. at different sites were strongly positively correlated with dissolved organic carbon, and the proportion of land within each catchment that was wetland. There was also a strong negative correlation with pH. By examining Hg concentration in filter feeding insects we have found a significant entry point for Hg and MeHg into the food web. - Accumulation of total mercury by black fly larvae is affected by stream pH, DOC and wetland area in the stream catchment.

  4. Constructed Wetland Treatment Systems For Water Quality Improvement

    Nelson, E.

    2010-01-01

    The Savannah River National Laboratory implemented a constructed wetland treatment system (CWTS) in 2000 to treat industrial discharge and stormwater from the Laboratory area. The industrial discharge volume is 3,030 m 3 per day with elevated toxicity and metals (copper, zinc and mercury). The CWTS was identified as the best treatment option based on performance, capital and continuing cost, and schedule. A key factor for this natural system approach was the long-term binding capacity of heavy metals (especially copper, lead, and zinc) in the organic matter and sediments. The design required that the wetland treat the average daily discharge volume and be able to handle 83,280 m 3 of stormwater runoff in a 24 hour period. The design allowed all water flow within the system to be driven entirely by gravity. The CWTS for A-01 outfall is composed of eight one-acre wetland cells connected in pairs and planted with giant bulrush to provide continuous organic matter input to the system. The retention basin was designed to hold stormwater flow and to allow controlled discharge to the wetland. The system became operational in October of 2000 and is the first wetland treatment system permitted by South Carolina DHEC for removal of metals. Because of the exceptional performance of the A-01 CWTS, the same strategy was used to improve water quality of the H-02 outfall that receives discharge and stormwater from the Tritium Area of SRS. The primary contaminants in this outfall were also copper and zinc. The design for this second system required that the wetland treat the average discharge volume of 415 m 3 per day, and be able to handle 9,690 m 3 of stormwater runoff in a 24 hour period. This allowed the building of a system much smaller than the A-01 CWTS. The system became operational in July 2007. Metal removal has been excellent since water flow through the treatment systems began, and performance improved with the maturation of the vegetation during the first season of

  5. CONSTRUCTED WETLAND TREATMENT SYSTEMS FOR WATER QUALITY IMPROVEMENT

    Nelson, E.

    2010-07-19

    The Savannah River National Laboratory implemented a constructed wetland treatment system (CWTS) in 2000 to treat industrial discharge and stormwater from the Laboratory area. The industrial discharge volume is 3,030 m{sup 3} per day with elevated toxicity and metals (copper, zinc and mercury). The CWTS was identified as the best treatment option based on performance, capital and continuing cost, and schedule. A key factor for this natural system approach was the long-term binding capacity of heavy metals (especially copper, lead, and zinc) in the organic matter and sediments. The design required that the wetland treat the average daily discharge volume and be able to handle 83,280 m{sup 3} of stormwater runoff in a 24 hour period. The design allowed all water flow within the system to be driven entirely by gravity. The CWTS for A-01 outfall is composed of eight one-acre wetland cells connected in pairs and planted with giant bulrush to provide continuous organic matter input to the system. The retention basin was designed to hold stormwater flow and to allow controlled discharge to the wetland. The system became operational in October of 2000 and is the first wetland treatment system permitted by South Carolina DHEC for removal of metals. Because of the exceptional performance of the A-01 CWTS, the same strategy was used to improve water quality of the H-02 outfall that receives discharge and stormwater from the Tritium Area of SRS. The primary contaminants in this outfall were also copper and zinc. The design for this second system required that the wetland treat the average discharge volume of 415 m{sup 3} per day, and be able to handle 9,690 m{sup 3} of stormwater runoff in a 24 hour period. This allowed the building of a system much smaller than the A-01 CWTS. The system became operational in July 2007. Metal removal has been excellent since water flow through the treatment systems began, and performance improved with the maturation of the vegetation during

  6. Planet Mercury

    1974-01-01

    Mariner 10's first image of Mercury acquired on March 24, 1974. During its flight, Mariner 10's trajectory brought it behind the lighted hemisphere of Mercury, where this image was taken, in order to acquire important measurements with other instruments.This picture was acquired from a distance of 3,340,000 miles (5,380,000 km) from the surface of Mercury. The diameter of Mercury (3,031 miles; 4,878 km) is about 1/3 that of Earth.Images of Mercury were acquired in two steps, an inbound leg (images acquired before passing into Mercury's shadow) and an outbound leg (after exiting from Mercury's shadow). More than 2300 useful images of Mercury were taken, both moderate resolution (3-20 km/pixel) color and high resolution (better than 1 km/pixel) black and white coverage.

  7. Water flow experiment using the PIV technique and the thermal hydraulic analysis on the cross-flow type mercury target model

    Haga, Katsuhiro; Terada, Atsuhiko; Kaminaga, Masanori; Hino, Ryutaro

    2001-01-01

    In this study the effectiveness of the cross-flow type mercury target structure was evaluated experimentally and analytically. The average water flow velocity field in the target mock-up model, which was fabricated with plexiglass, was measured at room temperature using the PIV (Particle Image Velocimetry) technique. The water flow analyses were conducted and the analytical results were compared with the experimental results. The experimental results showed that the cross-flow could be realized in the former part of the proton beam path where the heat load by the spallation reaction is large, and the analytical result of the water flow velocity field showed good correspondence to the experimental result in the case of the Reynolds number of more than 4.83 x 10 5 at the model inlet. With these results, the effectiveness of the cross-flow type mercury target structure and the present analysis code system was demonstrated. Then the mercury flow field and the temperature distribution in the target container were analyzed assuming the proton beam energy and power of 3 GeV and 5 MW. The analytical result showed that the cross-flow field of mercury, which is similar to the water flow field, could also be attained. (author)

  8. Secondary poisoning of cadmium, copper and mercury: implications for the Maximum Permissible Concentrations and Negligible Concentrations in water, sediment and soil

    Smit CE; Wezel AP van; Jager T; Traas TP; CSR

    2000-01-01

    The impact of secondary poisoning on the Maximum Permissible Concentrations (MPCs) and Negligible Concentrations (NCs) of cadmium, copper and mercury in water, sediment and soil have been evaluated. Field data on accumulation of these elements by fish, mussels and earthworms were used to derive

  9. quality assessment of sachet and bottled water soldin gboko, benue

    HOD

    Water is an essential part of human nutrition, both directly as ... The effect of storage on the quality of sachet water produced within Port ... WHO limits for drinking water quality, except for pH. ... Sample. Source. K1. Barna Sachet Water. K2. Fresh life Sachet Water. K3 ..... The high iron content may be because, the treatment.

  10. 30 CFR 71.601 - Drinking water; quality.

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Drinking water; quality. 71.601 Section 71.601... Water § 71.601 Drinking water; quality. (a) Potable water provided in accordance with the provisions of § 71.600 shall meet the applicable minimum health requirements for drinking water established by the...

  11. Measuring total mercury due to small-scale gold mining activities to determine community vulnerability in Cihonje, Central Java, Indonesia.

    Sari, Mega M; Inoue, Takanobu; Matsumoto, Yoshitaka; Yokota, Kuriko

    2016-01-01

    This research is comparative study of gold mining and non-gold mining areas, using four community vulnerability indicators. Vulnerability indicators are exposure degree, contamination rate, chronic, and acute toxicity. Each indicator used different samples, such as wastewater from gold mining process, river water from Tajum river, human hair samples, and health questionnaire. This research used cold vapor atomic absorption spectrometry to determine total mercury concentration. The result showed that concentration of total mercury was 2,420 times than the maximum content of mercury permitted in wastewater based on the Indonesian regulation. Moreover, the mercury concentration in river water reached 685 ng/l, exceeding the quality threshold standards of the World Health Organization (WHO). The mercury concentration in hair samples obtained from the people living in the research location was considered to identify the health quality level of the people or as a chronic toxicity indicator. The highest mercury concentration--i.e. 17 ng/mg, was found in the gold mining respondents. Therefore, based on the total mercury concentration in the four indicators, the community in the gold mining area were more vulnerable to mercury than communities in non-gold mining areas. It was concluded that the community in gold mining area was more vulnerable to mercury contamination than the community in non-gold mining area.

  12. Seasonal variations of ground water quality and its agglomerates by water quality index

    S. Sharma

    2016-01-01

    Full Text Available Water is a unique natural resource among all sources available on earth. It plays an important role in economic development and the general well-being of the country. This study aimed at using the application of water quality index in evaluating the ground water quality innorth-east area of Jaipur in pre and post monsoon for public usage. Total eleven physico–chemical characteristics; total dissolved solids, total hardness,chloride, nitrate, electrical conductance, sodium, fluorideand potassium, pH, turbidity, temperature were analyzed and observed values were compared with standard values recommended by Indian standard and World Health Organization. Most of parameter show higher value than permissible limit in pre and post monsoon. Water quality index study showed that drinking water in Amer (221.58,277.70, Lalawas (362.74,396.67, Jaisinghpura area (286.00,273.78 were found to be highly contaminated due to high value of total dissolved solids, electrical conductance, total hardness, chloride, nitrate and sodium.Saipura (122.52, 131.00, Naila (120.25, 239.86, Galta (160.9, 204.1 were found to be moderately contaminated for both monsoons. People dependent on this water may prone to health hazard. Therefore some effective measures are urgently required to enhance the quality of water in these areas.

  13. Seasonal variations of ground water quality and its agglomerates by water quality index

    Sharma, S.; Chhipa, R.C.

    2016-01-01

    Water is a unique natural resource among all sources available on earth. It plays an important role in economic development and the general well-being of the country. This study aimed at using the application of water quality index in evaluating the ground water quality in north-east area of Jaipur in pre and post monsoon for public usage. Total eleven physico–chemical characteristics; total dissolved solids, total hardness,chloride, nitrate, electrical conductance, sodium, fluoride and potassium, p H, turbidity, temperature) were analyzed and observed values were compared with standard values recommended by Indian standard and World Health Organization. Most of parameter show higher value than permissible limit in pre and post monsoon. Water quality index study showed that drinking water in Amer (221.58,277.70), Lalawas (362.74,396.67), Jaisinghpura area (286.00, 273.78) were found to be highly contaminated due to high value of total dissolved solids, electrical conductance, total hardness, chloride, nitrate and sodium. Saipura (122.52, 131.00), Naila (120.25, 239.86), Galta (160.9, 204.1) were found to be moderately contaminated for both monsoons. People dependent on this water may prone to health hazard. Therefore some effective measures are urgently required to enhance the quality of water in these areas.

  14. Quality-assurance and data-management plan for water-quality activities in the Kansas Water Science Center, 2014

    Rasmussen, Teresa J.; Bennett, Trudy J.; Foster, Guy M.; Graham, Jennifer L.; Putnam, James E.

    2014-01-01

    As the Nation’s largest water, earth, and biological science and civilian mapping information agency, the U.S. Geological Survey is relied on to collect high-quality data, and produce factual and impartial interpretive reports. This quality-assurance and data-management plan provides guidance for water-quality activities conducted by the Kansas Water Science Center. Policies and procedures are documented for activities related to planning, collecting, storing, documenting, tracking, verifying, approving, archiving, and disseminating water-quality data. The policies and procedures described in this plan complement quality-assurance plans for continuous water-quality monitoring, surface-water, and groundwater activities in Kansas.

  15. Mercurial poisoning

    Gorton, B

    1924-01-01

    Cats which had been kept in a thermometer factory to catch rats were afflicted with mercury poisoning. So were the rats they were supposed to eat. The symptoms of mercury poisoning were the same in both species. The source of mercury for these animals is a fine film of the metal which coats floors, a result of accidental spills during the manufacturing process.

  16. Application of Nemerow Index Method and Integrated Water Quality Index Method in Water Quality Assessment of Zhangze Reservoir

    Zhang, Qian; Feng, Minquan; Hao, Xiaoyan

    2018-03-01

    [Objective] Based on the water quality historical data from the Zhangze Reservoir from the last five years, the water quality was assessed by the integrated water quality identification index method and the Nemerow pollution index method. The results of different evaluation methods were analyzed and compared and the characteristics of each method were identified.[Methods] The suitability of the water quality assessment methods were compared and analyzed, based on these results.[Results] the water quality tended to decrease over time with 2016 being the year with the worst water quality. The sections with the worst water quality were the southern and northern sections.[Conclusion] The results produced by the traditional Nemerow index method fluctuated greatly in each section of water quality monitoring and therefore could not effectively reveal the trend of water quality at each section. The combination of qualitative and quantitative measures of the comprehensive pollution index identification method meant it could evaluate the degree of water pollution as well as determine that the river water was black and odorous. However, the evaluation results showed that the water pollution was relatively low.The results from the improved Nemerow index evaluation were better as the single indicators and evaluation results are in strong agreement; therefore the method is able to objectively reflect the water quality of each water quality monitoring section and is more suitable for the water quality evaluation of the reservoir.

  17. Microbiological and physicochemical quality of drinking water

    Chan, Chee Ling; Zalifah, M.K.; Norrakiah, A.S.

    2007-01-01

    This study was conducted on the water samples collected before and after filtration treatment was given. Five types of filtered drinking water (A1, B1, C1, D1 and E2) were chosen randomly from houses in Klang Valley for analyses. The purpose of this study was to determine the quality of filtered drinking water by looking into microbiological aspect and several physicochemical analyses such as turbidity, pH and total suspended solid (TSS). The microbiological analyses were performed to trace the presence of indicator organisms and pathogens such as Escherichia coli, Streptococcus faecalis and Pseudomonas aeruginosa. All of the water did not comply with the regulations of Food Act as consisted of more than 10 3 -10 4 cfu/ mL for total plate count. However, the total coliforms and E. coli were detected lower than 4 cfu/ mL and not exceeding the maximum limit of Food Act. While the presence of S. faecalis and P. aeruginosa were negative in all samples. The pH value was slightly acidic (pH -4 - 2.2 x 10 -3 mg/ L) and the turbidity for all the samples were recorded below 1 Nephelometric Turbidity units (NTU) thus, complying with the regulations. All the water samples that undergo the filtration system were fit to be consumed. (author)

  18. Health and environmental impact of mercury in the Philippines using nuclear techniques

    Cortex-Maramba, Nelia; Trinidad Francisco-Rivera, Ana; Manglicmot, Ailyn; Santos, Flora; Akagi, Hirokatsu

    2001-01-01

    Artisanal gold mining activities using mercury has proliferated in various parts of the country since the early 1980's. In Southern Philippines, it is estimated that a small-scale gold processor utilizes one kilogram of mercury every week or an average of fifty-two kgs./yr. Production is estimated at 30 kilograms of gold per day. It has been estimated that 140 tons of mercury flux have been dumped directly into the river systems from small-scale gold mining operations in one of the gold rush areas in the country. Small-scale mining operations have affected tributaries and water systems in the country that also relies heavily on fishing as a source of livelihood as well as the daily food fare among the low-income sectors in the area. Aside from this, cattle livestock and agricultural production have also been affected by these mining activities because of contamination of the irrigation and water systems. Presently, environmental and health monitoring conducted by several government agencies in the recent past were limited to the determination of total mercury only. Previous studies undertaken focused mainly on the exposure of adults and workers to mercury during mining/processing operations. Environmental quality monitoring showed total mercury sediment levels ranged from 0.55 ug/g dry weight while water samples from river systems exhibited mercury levels from 0.0728-0.0784 ppb. Fish samples collected showed levels ranging from 1.07-438.8 ppb for total mercury and 0.71-377.18 ppb for methyl mercury. Methyl mercury content in fish ranged from 56-99%. Laboratory results showed that total mercury hair samples in schoolchildren ranged from 0.278-20.393 ppm while methyl mercury levels were from 0.191-18.469 ppm. Methyl mercury represented 45.96%-99.81% of the total mercury levels in hair. Total blood mercury levels ranged from 0.757-56.88 ppb while methyl mercury blood levels ranged from 1.36-46.73 ppb. Summary of physical examination results showed that predominant

  19. Multiple regression analysis to assess the role of plankton on the distribution and speciation of mercury in water of a contaminated lagoon.

    Stoichev, T; Tessier, E; Amouroux, D; Almeida, C M; Basto, M C P; Vasconcelos, V M

    2016-11-15

    Spatial and seasonal variation of mercury species aqueous concentrations and distributions was carried out during six sampling campaigns at four locations within Laranjo Bay, the most mercury-contaminated area of the Aveiro Lagoon (Portugal). Inorganic mercury (IHg(II)) and methylmercury (MeHg) were determined in filter-retained (IHgPART, MeHgPART) and filtered (algae and consumers' grazing pressure in the contaminated area can be involved to increase concentrations of IHg(II)DISS and MeHgPART. These processes could lead to suspended particles enriched with MeHg and to the enhancement of IHg(II) and MeHg availability in surface waters and higher transfer to the food web. Copyright © 2016 Elsevier B.V. All rights reserved.

  20. [Effects of Citric Acid on Activation and Methylation of Mercury in the Soils of Water-Level-Fluctuating Zone of the Three Gorges.Reservoir].

    Qin, Cai-qing; Liang, Li; You, Rui; Deng, Han; Wang, Ding-yong

    2015-12-01

    To investigate effects of the main component of vegetation root exudates-citric acid on activation and methylation of mercury in the soil of water-level-fluctuating zone (WLFZ) of the Three Gorges Reservoir area, simulation experiments were conducted by extracting and cultivating soil with different concentrations of citric acid. The results showed that after adding citric acid, the total mercury content in leaching solution before reaching peak were higher than that of the control, and increased with the increase of citric acid concentrations. The maximum amount of mercury complexes increased initially and then reached plateaus with the percentage against the total mercury in soil of 1.03%, 1.67%, 1.99%, 2.47%, 2.68%, 2.73% and 2.73% for different citric acid concentrations (0, 1, 2, 4, 5, 6 and 8 mmol · L⁻¹). In addition, concentrations of methylmercury ( MeHg) in soil remained stable in the first 3 hours, and then increased accompanying with the increasing rate rising with the concentration of citric acid ( besides the control group) . This result indicated that citric acid probably could promote the transformation process from inorganic mercury to MeHg in soil. which increased with the concentration of citric acid.

  1. Use of selenium to detect mercury in water and cells: an enhancement of the sensitivity and specificity of a seleno fluorescent probe.

    Tang, Bo; Ding, Baiyu; Xu, Kehua; Tong, Lili

    2009-01-01

    Seleno fluorescent probe: An organoselenium fluorescent probe (FSe-1) for mercury was designed based on the irreversible deselenation mechanism. FSe-1 exhibits an ultrahigh selectivity and sensitivity for Hg(2+) detection only for reactive selenium atom sites, due the strong affinity between Se and Hg. Furthermore, the new probe has been successfully used for imaging mercury ions in RAW 264.7 cells (a mouse macrophage cell line; see figure).Inspired by the antitoxic function of selenium towards heavy-metal ions, we designed an organoselenium fluorescent probe (FSe-1) for mercury. The reaction of FSe-1 and Hg(2+) is an irreversible deselenation mechanism based on the selenophilic character of mercury. FSe-1 exhibits an ultrahigh selectivity and sensitivity for Hg(2+) detection only for reactive selenium atom sites due to the strong affinity between Se and Hg. The experimental results proved that FSe-1 was selective for Hg(2+) ions over other relevant metal ions and bioanalytes, and also showed an enhancement in sensitivity of up to 1.0 nM, which is lower than the current Environmental Protection Agency standard for drinking water. Furthermore, the new probe has been successfully applied to the imaging of mercury ions in RAW 264.7 cells (a mouse macrophage cell line) with high sensitivity and selectivity.

  2. Speciation and determination of inorganic mercury and methylmercury by headspace single drop microextraction and electrothermal atomic absorption spectrometry in water and fish

    Sarica, Deniz Yurtsever [Scientific and Technological Research Council of Turkey, Ankara Test and Analysis Laboratory, TUeBITAK/ATAL, Besevler, Ankara (Turkey); Tuerker, Ali Rehber [Science Faculty, Department of Chemistry, Gazi University, Ankara (Turkey)

    2012-05-15

    In this study, headspace single drop microextraction (HS-SDME) method in combination with electrothermal atomic absorption spectrometry (ETAAS) method was developed and validated for the speciation and determination of inorganic mercury (iHg) and methylmercury (MeHg). MeHg and iHg species were reduced to volatile methylmercury hydride (CH{sub 3}HgH) and elemental mercury, respectively, in the presence of NaBH{sub 4} and trapped onto a drop of acceptor phase in the tip of a microsyringe. Thiourea and ammonium pyrrolydinedithiocarbamate (APDC) were tested as the acceptor phase. The experimental parameters of the method such as microextraction time, temperature, NaBH{sub 4} concentration, acceptor phase concentration, and pH of the medium were investigated to obtain distinctive conditions for mercury species. Possible interference effects have also been investigated. In order to validation of the method, analytical figures of merits such as accuracy, precision, limit of detection (LOD), limit of quantitation (LOQ), and linear working range have been evaluated. Accuracy of the method has been verified by analyzing certified reference materials (BCR 453 Tuna fish) and spiked samples. The proposed method was applied for the speciation and determination of mercury species in water and fish samples. Mercury species (MeHg and iHg) have been determined in the real samples with a relative error less than 10%. (Copyright copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  3. Trace mercury determination in drinking and natural water after preconcentration and separation by DLLME-SFO method coupled with cold vapor atomic absorption spectrometry

    Abdollahi Atousa

    2014-07-01

    Full Text Available A novel dispersive liquid–liquid microextraction based on solidification of floating organic drop (DLLME-SFO for simultaneous separation/preconcentration of ultra trace amounts of mercury was used. A method based on amalgamation was used for collection of gaseous mercury on gold coated sand (Gold trap. The concentration of mercury was determined by cold vapor atomic absorption spectrometry (CV-AAS. The DLLME-SFO behavior of mercury by using dithizone as complexing agent was systematically investigated. The factors influencing, the complex formation and extraction of DLLME-SFO method such as type and volume of extraction and disperser solvents, pH, concentration of salt, centrifuging time and concentration of the chelating agent were optimized. The method was successfully applied to the determination of mercury in drinking and natural water and satisfactory relative recoveries (95–105% were achieved. The proposed procedure was based on very low consumption of organic solvents. The other benefits of the system were sensitive, simple, friendly to the environment, rejection of matrix constituent, low cost, the time consuming and high enrichment factor.

  4. Management of poor quality irrigation water

    Change, M.H.; Leghari, A.M.; Sipio, Q.A.

    2000-01-01

    The effect of poor quality drainage effluent on moderately saline sodic, medium textured soil at different growth stages of wheat and cotton is reported. The irrigation treatments were: I) All canal irrigations, II) one irrigation of 75 mm with saline drainage effluent (EC = 3 dS m1) after four weeks sowing of the crop, III) one irrigation of 75 mm with saline drainage effluent after seven weeks sowing of the crop, and IV) one irrigation of 75 mm with saline drainage effluent after ten weeks sowing of the crop. The treatments receiving saline water gave significant decrease in crop yields as compared to canal irrigation treatment. The higher yield of wheat and seed cotton was recorded T1 followed by T2, T3 and T4. The trend of produce was T1< T2< T3< T4 respectively. Electrical conductivity of the soil (Ece) in T1 was decreased and in other three treatments was increased, whereas, pH decreased in T1 and T2. The SAR of soil decreased in all the treatments as compared with initial values. Treatment receiving an irrigation with saline water after four weeks of sowing (T2) was better in reducing soil salinity as compared to treatments receiving such water after 7 or 10 weeks os sowing. Poor quality water (EC = 3 d Sm/sup -1/) can be managed for irrigation after four weeks of swing of crops provided certain soil and water management practices like good seed bed preparation and proper drainage measures are adopted. (author)

  5. The development of water quality methods within ecological ...

    The development of water quality methods within ecological Reserve ... Water Act (NWA, No 36 of 1998), the ecological Reserve is defined as the quality and quantity ... provide ecologically important flow-related habitat, or geomorphological ...

  6. Water Quality Assessment and Total Maximum Daily Loads Information (ATTAINS)

    U.S. Environmental Protection Agency — The Water Quality Assessment TMDL Tracking And Implementation System (ATTAINS) stores and tracks state water quality assessment decisions, Total Maximum Daily Loads...

  7. A stochastic dynamic programming model for stream water quality ...

    R. Narasimhan (Krishtel eMaging) 1461 1996 Oct 15 13:05:22

    constraints of the water quality management problem; (ii) a water quality simulation model ... of acceptance and limited implementation of optimisation techniques. .... The response of river system to these sources of pollution can be integrated ...

  8. Composite measures of watershed health from a water quality perspective

    Water quality data at gaging stations are typically compared with established federal, state, or local water quality standards to determine if violations (concentrations of specific constituents falling outside acceptable limits) have occurred. Based on the frequency and severity...

  9. Impact of upstream industrial effluents on irrigation water quality ...

    Impact of upstream industrial effluents on irrigation water quality, soils and ... Knowledge of irrigation water quality is critical to predicting, managing and reducing salt ... Presence of heavy metals in concentration higher than the recommended ...

  10. Water Quality Monitoring of Inland Waters using Meris data

    Potes, M.; Costa, M. J.; Salgado, R.; Le Moigne, P.

    2012-04-01

    The successful launch of ENVISAT in March 2002 has given a great opportunity to understand the optical changes of water surfaces, including inland waters such as lakes and reservoirs, through the use of the Medium Resolution Imaging Spectrometer (MERIS). The potential of this instrument to describe variations of optically active substances has been examined in the Alqueva reservoir, located in the south of Portugal, where satellite spectral radiances are corrected for the atmospheric effects to obtain the surface spectral reflectance. In order to validate this spectral reflectance, several field campaigns were carried out, with a portable spectroradiometer, during the satellite overpass. The retrieved lake surface spectral reflectance was combined with limnological laboratory data and with the resulting algorithms, spatial maps of biological quantities and turbidity were obtained, allowing for the monitoring of these water quality indicators. In the framework of the recent THAUMEX 2011 field campaign performed in Thau lagoon (southeast of France) in-water radiation, surface irradiation and reflectance measurements were taken with a portable spectrometer in order to test the methodology described above. At the same time, water samples were collected for laboratory analysis. The two cases present different results related to the geographic position, water composition, environment, resources exploration, etc. Acknowledgements This work is financed through FCT grant SFRH/BD/45577/2008 and through FEDER (Programa Operacional Factores de Competitividade - COMPETE) and National funding through FCT - Fundação para a Ciência e a Tecnologia in the framework of projects FCOMP-01-0124-FEDER-007122 (PTDC / CTE-ATM / 65307 / 2006) and FCOMP-01-0124-FEDER-009303 (PTDC/CTE-ATM/102142/2008). Image data has been provided by ESA in the frame of ENVISAT projects AOPT-2423 and AOPT-2357. We thank AERONET investigators for their effort in establishing and maintaining Évora AERONET

  11. One Step In-Situ Formed Magnetic Chitosan Nanoparticles as an Efficient Sorbent for Removal of Mercury Ions From Petrochemical Waste Water: Batch and Column Study

    Rahbar

    2015-10-01

    Full Text Available Background In the recent years, mercury contamination has attracted great deal of attention due to its serious environmental threat. Objectives The main goal of this study was application of one-step synthesized magnetic (magnetite chitosan nanoparticles (MCNs in the removal of mercury ions from petrochemical waste water. Materials and Methods This study was performed in batch and column modes. Effects of various parameters such as pH, adsorbent dose, contact time, temperature and agitation speed for the removal of mercury ions by MCNs investigated in batch mode. Afterwards, optimum conditions were exploited in column mode. Different kinetic models were also studied. Results An effective Hg (II removal (99.8% was obtained at pH 6, with 50 mg of MCNs for an initial concentration of this ion in petrochemical waste water (5.63 mg L-1 and 10 minutes agitation of the solution. The adsorption kinetic data was well fitted to the pseudo-second-order model. Conclusions Experimental results showed that MCNs is an excellent sorbent for removal of mercury ions from petrochemical waste water. In addition, highly complex matrix of this waste does not affect the adsorption capability of MCNs.

  12. Use of cyanobacteria to assess water quality in running waters

    Douterelo, I.; Perona, E.; Mateo, P.

    2004-01-01

    Epilithic cyanobacterial communities in rivers in the province of Madrid (Spain) and their relationship with water quality were studied. Sampling locations above and below outlets for sewage effluent and other wastes from human settlements were selected. We aimed to evaluate the use of cyanobacteria as potential indicators of pollution in running waters. Large increases in nutrient concentrations were always observed at downstream sampling sites. A decrease in species richness and the Margalef diversity index were associated with these increases in nutrient load. Differences in cyanobacterial community structure were also observed. A higher proportion of cyanobacteria belonging to the Oscillatoriales order predominated at sampling sites with higher nutrient content. However, Nostocales species were more abundant at upstream sites characterized by lower nutrient load than at downstream locations. The soluble reactive phosphate (SRP) had a threshold effect on cyanobacterial biomass: a decrease in phycobiliprotein content as SRP increased, reaching a minimum, followed by an increase in abundance. This increase may be attributed to hypertrophic conditions in those locations. Our results and literature data confirm the suitability of this phototroph community for monitoring eutrophication in rivers - Taxonomic composition of cyanobacteria is a sensitive indicator of river water quality

  13. Use of cyanobacteria to assess water quality in running waters

    Douterelo, I.; Perona, E.; Mateo, P

    2004-02-01

    Epilithic cyanobacterial communities in rivers in the province of Madrid (Spain) and their relationship with water quality were studied. Sampling locations above and below outlets for sewage effluent and other wastes from human settlements were selected. We aimed to evaluate the use of cyanobacteria as potential indicators of pollution in running waters. Large increases in nutrient concentrations were always observed at downstream sampling sites. A decrease in species richness and the Margalef diversity index were associated with these increases in nutrient load. Differences in cyanobacterial community structure were also observed. A higher proportion of cyanobacteria belonging to the Oscillatoriales order predominated at sampling sites with higher nutrient content. However, Nostocales species were more abundant at upstream sites characterized by lower nutrient load than at downstream locations. The soluble reactive phosphate (SRP) had a threshold effect on cyanobacterial biomass: a decrease in phycobiliprotein content as SRP increased, reaching a minimum, followed by an increase in abundance. This increase may be attributed to hypertrophic conditions in those locations. Our results and literature data confirm the suitability of this phototroph community for monitoring eutrophication in rivers - Taxonomic composition of cyanobacteria is a sensitive indicator of river water quality.

  14. Review of samples of water, sediment, tailings, and biota at the Little Bonanza mercury mine, San Luis Obispo County, California

    Rytuba, James J.; Hothem, Roger L.; Goldstein, Daniel N.; Brussee, Brianne E.; May, Jason T.

    2011-01-01

    Background and Objectives The Little Bonanza mercury (Hg) mine, located in San Luis Obispo County, California, is a relatively small mine with, a historical total Hg production of about 1,000 flasks. The mine workings and tailings are located in the headwaters of the previously unnamed west fork of Las Tablas Creek (WF Las Tablas Creek), which flows into the Nacimiento Reservoir. Wasterock and tailings eroded from the Little Bonanza Hg Mine have contributed Hg-enriched mine wastes to the headwaters of WF Las Tablas Creek. The mine is located on Federal land managed by the U.S. Bureau of Land Management (BLM), which requested that the U.S. Geological Survey (USGS) measure and characterize Hg and other geochemical constituents in tailings, sediment, water, and biota at and downstream from the minesite. This report is in response that request, from the lead agency which is mandated to conduct a Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) - Removal Site Investigation (RSI). The RSI applies to removal of Hg-contaminated mine waste from the Little Bonanza minesite as a means of reducing Hg transport to WF Las Tablas Creek. This report summarizes data obtained from field sampling of mine tailings, wasterock, sediment, water, and biota at the Little Bonanza Mine that was completed on April 6, 2010. Conditions during sampling were dry and no rain had occurred in the watershed for several weeks. Our results permit a preliminary assessment of the mining sources of Hg and associated chemical constituents that could produce elevated levels of monomethyl mercury (MMeHg) in WF Las Tablas Creek and in biota.

  15. Water quality in vicinity of Fenton Hill Site, 1974

    Purtymun, W.D.; Adams, W.H.; Owens, J.W.

    1975-09-01

    The water quality at nine surface water stations, eight ground water stations, and the drilling operations at the Fenton Hill Site have been studied as a measure of the environmental impact of the Los Alamos Scientific Laboratory geothermal experimental studies in the Jemez Mountains. Surface water quality in the Jemez River drainage area is affected by the quality of the inflow from thermal and mineral springs. Ground water discharges from the Cenozoic Volcanics are similar in chemical quality. Water in the main zone of saturation penetrated by test hole GT-2 is highly mineralized, whereas water in the lower section of the hole, which is in granite, contains a higher concentration of uranium

  16. Mercury concentrations in China's coastal waters and implications for fish consumption by vulnerable populations

    Tong, Yindong; Wang, Mengzhu; Bu, Xiaoge; Guo, Xin; Lin, Yan; Lin, Huiming; Li, Jing; Zhang, Wei; Wang, Xuejun

    2017-01-01

    We assessed mercury (Hg) pollution in China's coastal waters, including the Bohai Sea, the Yellow Sea, the East China Sea and the South China Sea, based on a nationwide dataset from 301 sampling sites. A methylmercury (MeHg) intake model for humans based on the marine food chain and human fish consumption was established to determine the linkage between water pollutants and the pollutant intake by humans. The predicted MeHg concentration in fish from the Bohai Sea was the highest among the four seas included in the study. The MeHg intake through dietary ingestion was dominant for the fish and was considerably higher than the MeHg intake through water respiration. The predicted MeHg concentrations in human blood in the coastal regions of China ranged from 1.37 to 2.77 μg/L for pregnant woman and from 0.43 to 1.00 μg/L for infants, respectively, based on different diet sources. The carnivorous fish consumption advisory for pregnant women was estimated to be 288–654 g per week to maintain MeHg concentrations in human blood at levels below the threshold level (4.4 μg/L established by the US Environmental Protection Agency). With a 50% increase in Hg concentrations in water in the Bohai Sea, the bioaccumulated MeHg concentration (4.5 μg/L) in the fish consumers will be higher than the threshold level. This study demonstrates the importance in controlling Hg pollution in China's coastal waters. An official recommendation guideline for the fish consumption rate and its sources will be necessary for vulnerable populations in China. - Graphical abstract: MeHg transfer route from the marine food chain to vulnerable population. - Highlights: • Predicted MeHg concentrations in pregnant woman and infant’s blood in China’s coastal regions are below threshold level. • The carnivorous fish consumption advisory for pregnant women is estimated to be 288–654 g per week. g • If with a 50% increase in Hg in Bohai Sea, the bioaccumulated MeHg concentration in

  17. The assessment of bore-hole water quality of Kakamega County, Kenya

    Christine, Adika A.; Kibet, Joshua K.; Kiprop, Ambsrose K.; Were, Munyendo L.

    2018-03-01

    Numerous deleterious impacts of anthropogenic activities on water quality are typically observed in areas bursting with mineral exploitation, agricultural activities, and industrial processes. Therefore, this contribution details the water quality and water origin in selected hand-dug wells of one the most prominent mining areas in Kenya (Kakamega County). The toxicological impacts of drinking water from a mining site may include cancer and genetic aberrations largely because of the toxic effects of waterborne metals including Hg and As. Accordingly, this study focuses primarily on the investigation of heavy metals, essential elements such as Na and K. Heavy metals and essential elements were determined using spectroscopic and titrimetric techniques. The study revealed that mercury (Hg) concentration ranged between 0.00256 and 0.0611 ± 0.00005 mg/L while arsenic (As) concentration ranged from 0.0103 to 0.0119 ± 0.00005 mg/L. The concentration of potassium ranged from 2.53 to 4.08 ± 0.15 mg/L while that of sodium varied from 6.74 to 9.260 ± 0.2 mg/L. Although the concentration of cadmium was lower than that recommended by W.H.O, the concentrations of Hg, Pb, and As in Kakamega waters were higher than the internationally accepted levels. The generally high level of heavy metals in Kakamega bore-hole waters is, therefore, a public health concern that needs immediate intervention.

  18. 40 CFR 35.2102 - Water quality management planning.

    2010-07-01

    ... 40 Protection of Environment 1 2010-07-01 2010-07-01 false Water quality management planning. 35... Administrator shall first determine that the project is: (a) Included in any water quality management plan being implemented for the area under section 208 of the Act or will be included in any water quality management plan...

  19. 40 CFR 35.2023 - Water quality management planning.

    2010-07-01

    ... 40 Protection of Environment 1 2010-07-01 2010-07-01 false Water quality management planning. 35... to the States to carry out water quality management planning including but not limited to: (1... ASSISTANCE STATE AND LOCAL ASSISTANCE Grants for Construction of Treatment Works § 35.2023 Water quality...

  20. 78 FR 54517 - Water Quality Standards Regulatory Clarifications

    2013-09-04

    ... 131 Water Quality Standards Regulatory Clarifications; Proposed Rule #0;#0;Federal Register / Vol. 78... AGENCY 40 CFR Part 131 [EPA-HQ-OW-2010-0606; FRL-9839-7] RIN 2040-AF 16 Water Quality Standards... Environmental Protection Agency (EPA) is proposing changes to the federal water quality standards (WQS...

  1. 40 CFR 35.2111 - Revised water quality standards.

    2010-07-01

    ... 40 Protection of Environment 1 2010-07-01 2010-07-01 false Revised water quality standards. 35... stream segments which have not, at least once since December 29, 1981, had their water quality standards...) The State has in good faith submitted such water quality standards and the Regional Administrator has...

  2. Trophic state categorisation and assessment of water quality in ...

    Thus, water quality information is crucial in setting up guidelines for freshwater ... water quality in the Manjirenji Dam was generally fair, with a CCME value averaging 78.1, ... The current water quality data set for the Manjirenji Dam is vital for ...

  3. Nationwide assessment of nonpoint source threats to water quality

    Thomas C. Brown; Pamela Froemke

    2012-01-01

    Water quality is a continuing national concern, in part because the containment of pollution from nonpoint (diffuse) sources remains a challenge. We examine the spatial distribution of nonpoint-source threats to water quality. On the basis of comprehensive data sets for a series of watershed stressors, the relative risk of water-quality impairment was estimated for the...

  4. A Water Quality Monitoring Programme for Schools and Communities

    Spellerberg, Ian; Ward, Jonet; Smith, Fiona

    2004-01-01

    A water quality monitoring programme for schools is described. The purpose of the programme is to introduce school children to the concept of reporting on the "state of the environment" by raising the awareness of water quality issues and providing skills to monitor water quality. The programme is assessed and its relevance in the…

  5. Mercury in the atmosphere, snow and melt water ponds in the North Atlantic Ocean during Arctic summer.

    Aspmo, Katrine; Temme, Christian; Berg, Torunn; Ferrari, Christophe; Gauchard, L Pierre-Alexis; Fain, Xavier; Wibetoe, Grethe

    2006-07-01

    Atmospheric mercury speciation measurements were performed during a 10 week Arctic summer expedition in the North Atlantic Ocean onboard the German research vessel RV Polarstern between June 15 and August 29, 2004. This expedition covered large areas of the North Atlantic and Arctic Oceans between latitudes 54 degrees N and 85 degrees N and longitudes 16 degrees W and 16 degrees E. Gaseous elemental mercury (GEM), reactive gaseous mercury (RGM) and mercury associated with particles (Hg-P) were measured during this study. In addition, total mercury in surface snow and meltwater ponds located on sea ice floes was measured. GEM showed a homogeneous distribution over the open North Atlantic Ocean (median 1.53 +/- 0.12 ng/m3), which is in contrast to the higher concentrations of GEM observed over sea ice (median 1.82 +/- 0.24 ng/m3). It is hypothesized that this results from either (re-) emission of mercury contained in snow and ice surfaces that was previously deposited during atmospheric mercury depletion events (AMDE) in the spring or evasion from the ocean due to increased reduction potential at high latitudes during Arctic summer. Measured concentrations of total mercury in surface snow and meltwater ponds were low (all samples RGM and Hg-P without a significant diurnal variability. These results indicate that the production and deposition of these reactive mercury species do not significantly contribute to the atmospheric mercury cycle in the North Atlantic Ocean during the Arctic summer.

  6. Studies of Columbia River water quality

    Onishi, Y.; Johanson, P.A.; Baca, R.G.; Hilty, E.L.

    1976-01-01

    The program to study the water quality of the Columbia River consists of two separate segments: sediment and radionuclide transport and temperature analysis. Quasi-two dimensional (longitudinal and vertical directions) mathematical simulation models were developed for determining radionuclide inventories, their variations with time, and movements of sediments and individual radionuclides in the freshwater region of the Columbia River below Priest Rapids Dam. These codes are presently being applied to the river reach between Priest Rapids and McNary Dams for the initial sensitivity analysis. In addition, true two-dimensional (longitudinal and lateral directions) models were formulated and are presently being programmed to provide more detailed information on sediment and radionuclide behavior in the river. For the temperature analysis program, river water temperature data supplied by the U. S. Geological Survey for six ERDA-sponsored temperature recording stations have been analyzed and cataloged on storage devices associated with ERDA's CDC 6600 located at Richland, Washington

  7. Chemical application strategies to protect water quality.

    Rice, Pamela J; Horgan, Brian P; Barber, Brian L; Koskinen, William C

    2018-07-30

    Management of turfgrass on golf courses and athletic fields often involves application of plant protection products to maintain or enhance turfgrass health and performance. However, the transport of fertilizer and pesticides with runoff to adjacent surface waters can enhance algal blooms, promote eutrophication and may have negative impacts on sensitive aquatic organisms and ecosystems. Thus, we evaluated the effectiveness of chemical application setbacks to reduce the off-site transport of chemicals with storm runoff. Experiments with water soluble tracer compounds confirmed an increase in application setback distance resulted in a significant increase in the volume of runoff measured before first off-site chemical detection, as well as a significant reduction in the total percentage of applied chemical transported with the storm runoff. For example, implementation of a 6.1 m application setback reduced the total percentage of an applied water soluble tracer by 43%, from 18.5% of applied to 10.5% of applied. Evaluation of chemographs revealed the efficacy of application setbacks could be observed with storms resulting in lesser (e.g. 100 L) and greater (e.g. > 300 L) quantities of runoff. Application setbacks offer turfgrass managers a mitigation approach that requires no additional resources or time inputs and may serve as an alternative practice when buffers are less appropriate for land management objectives or site conditions. Characterizing potential contamination of surface waters and developing strategies to safeguard water quality will help protect the environment and improve water resource security. This information is useful to grounds superintendents for designing chemical application strategies to maximize environmental stewardship. The data will also be useful to scientists and regulators working with chemical transport and risk models. Copyright © 2018. Published by Elsevier Inc.

  8. Mercury Redox Chemistry in Waters of the Eastern Asian Seas: From Polluted Coast to Clean Open Ocean.

    Ci, Zhijia; Zhang, Xiaoshan; Yin, Yongguang; Chen, Jinsheng; Wang, Shiwei

    2016-03-01

    We performed incubation experiments using seawaters from representative marine environments of the eastern Asian seas to determine the mercury (Hg) available for photoreduction (Hgr(II)), to investigate the Hg redox reaction kinetics, and to explore the effect of environmental factors and water chemistry on the Hg redox chemistry. Results show that Hgr(II) accounted for a considerable fraction of total Hg (THg) (%Hgr(II)/THg: 24.90 ± 10.55%, n = 27) and positively correlated with THg. Filtration decreased the Hgr(II) pool of waters with high suspended particulate matter (SPM). The positive linear relationships were found between pseudo-first order rate constants of gross Hg(II) photoreduction (kr) and gross Hg(0) photo-oxidation (ko) with photosynthetically active radiation (PAR). Under the condition of PAR of 1 m mol m(-2) s(-1), the kr were significantly (p < 0.05) lower than ko (kr/ko: 0.86 ± 0.22). The Hg(0) dark oxidation were significantly higher than the Hg(II) dark reduction. The Hg(II) dark reduction was positively correlated to THg, and the anaerobic condition favored the Hg(II) dark reduction. Filtration significantly influenced the Hg photoredox chemistry of waters with high SPM. UVB radiation was important for both Hg(II) photoreduction and Hg(0) photo-oxidation, and the role of other wavebands in photoinduced transformations of Hg varied with the water chemistry.

  9. Effects of stream water chemistry and tree species on release and methylation of mercury during litter decomposition.

    Tsui, Martin Tsz Ki; Finlay, Jacques C; Nater, Edward A

    2008-12-01

    Foliage of terrestrial plants provides an important energy and nutrient source to aquatic ecosystems but also represents a potential source of contaminants, such as mercury (Hg). In this study, we examined how different stream water types and terrestrial tree species influenced the release of Hg from senesced litter to the water and its subsequent methylation during hypoxic litter decomposition. After laboratory incubations of maple leaf litter for 66 days, we observed 10-fold differences in dissolved Hg (DHg, tree species collected at the same site and incubated with the same source water, litter from slower decomposing species (e.g., cedar and pine) yielded higher DHg concentrations than those with more labile carbon (e.g., maple and birch). Percent MeHg, however, was relatively similar among different leaf species (i.e., 61-86%). Our study is the first to demonstrate that stream water chemistry and terrestrial plant litter characteristics are important factors determining Hg release and methylation during hypoxic litter decomposition. These results suggest that certain watershed and aquatic ecosystem properties can determine the levels of MeHg inputs during litterfall events.

  10. Mercury analysis in hair

    Esteban, Marta; Schindler, Birgit K; Jiménez-Guerrero, José A

    2015-01-01

    Human biomonitoring (HBM) is an effective tool for assessing actual exposure to chemicals that takes into account all routes of intake. Although hair analysis is considered to be an optimal biomarker for assessing mercury exposure, the lack of harmonization as regards sampling and analytical...... assurance program (QAP) for assessing mercury levels in hair samples from more than 1800 mother-child pairs recruited in 17 European countries. To ensure the comparability of the results, standard operating procedures (SOPs) for sampling and for mercury analysis were drafted and distributed to participating...... laboratories. Training sessions were organized for field workers and four external quality-assessment exercises (ICI/EQUAS), followed by the corresponding web conferences, were organized between March 2011 and February 2012. ICI/EQUAS used native hair samples at two mercury concentration ranges (0...

  11. Potential impacts of changing supply-water quality on drinking water distribution : A review

    Liu, Gang; Zhang, Ya; Knibbe, Willem Jan; Feng, Cuijie; Liu, Wentso; Medema, Gertjan; van der Meer, Walter

    Driven by the development of water purification technologies and water quality regulations, the use of better source water and/or upgraded water treatment processes to improve drinking water quality have become common practices worldwide. However, even though these elements lead to improved water

  12. 76 FR 16285 - Amendments to the Water Quality Regulations, Water Code and Comprehensive Plan To Update Water...

    2011-03-23

    ... DELAWARE RIVER BASIN COMMISSION 18 CFR Part 410 Amendments to the Water Quality Regulations, Water Code and Comprehensive Plan To Update Water Quality Criteria for Toxic Pollutants in the Delaware... or ``Commission'') approved amendments to its Water Quality Regulations, Water Code and Comprehensive...

  13. Influence of microorganism content in suspended particles on the particle–water partitioning of mercury in semi-enclosed coastal waters

    Jang, Jiyi; Kim, Hyunji; Han, Seunghee

    2014-01-01

    It is known that particle scavenging of mercury (Hg) can be affected by the abundance of particulate organic matter in coastal waters. However, the role of living organic particles in Hg scavenging is not yet completely understood. In this study, we hypothesized that an abundance of living organic particles (i.e., phytoplankton and bacteria) would influence the particle–water partitioning of Hg in coastal waters. Surface seawater samples were collected from eight stations in Gwangyang Bay, Korea, in three seasons (November 2009, April 2010, and October 2010) for the determination of concentrations of suspended particulate matter (including chlorophyll-a and bacteria), and Hg in unfiltered and filtered waters. We found that more Hg partitioned toward particulate matter when phytoplankton biomass, indicated from the chlorophyll-a concentration in a particle, was higher. In the low algal season, when [chlorophyll-a] −1 , the bacterial number, instead of chlorophyll-a concentration in particle, showed a positive correlation with the particle–water partition coefficient of Hg. Overall, microbial abundance seems to play a critical role in particle scavenging of Hg in coastal water. Taking this result in light of Hg in pristine coastal zones, we predict that increases in algal biomass amplify the potential for algae to transfer Hg to marine food chains. - Highlights: • Abundance of phytoplankton and bacteria influenced particle–water partitioning of Hg. • More Hg partitioned toward particles when microorganism biomass in particle is large. • Increases of algal biomass may enhance Hg bioaccumulation in coastal ecosystem

  14. Microbial quality of drinking water from groundtanks and tankers at ...

    Drinking water quality was investigated at source and corresponding point-of-use in 2 peri-urban areas receiving drinking water either by communal water tanker or by delivery directly from the distribution system to household-based groundtanks with taps. Water quality variables measured were heterotrophic bacteria, total ...

  15. Assessment of Groundwater Quality of Ilorin Metropolis using Water ...

    Akorede

    ABSTRACT: Groundwater as a source of potable water is becoming more important in ... The parameters used for calculating the water quality index include the following: pH, total hardness, total ... Generally, water pollution not only affects water quality ..... regardless of the natural geology and human activities, it has.

  16. Effects of urbanization on water quality variables along urban ...

    This study focuses on water quality of permanent and temporary water bodies along the urban and suburban gradients of Chennai City, South India. Water samples were analyzed for their major elements and nutrients. The results indicated that the response of water quality variables was different when compared to urban ...

  17. The Effectivity of Green Coconut Water To Reduce Mercury Level In The Blood And To Improve Blood Profiles And Liver Cells Appearance (Study In Sprague Dawley Rats)

    Abdulrzag, Ehmeeda M.; Nur Kristina, Tri; Suwondo, Ari; Sunoko, Henna Rya

    2018-02-01

    When people are exposed to mercury chloride, it can produce a variety of health effects in the blood and liver. Coconut water contains Zn, Fe, Vit. C, Vit B11, Vit. B6, and Se to reduce mercury chloride level in the blood and improve blood profile and liver cells. Aim of this study was to analysis the effect of green coconut water supplementation in overcoming the toxic effect of Hg chlorid in the blood and liver of Sprague dawley rats exposed to Hg chloride. Samples were randomly about 36 animals rats exposed to HgCl2 through forced feeding by 20 mg/kgBW sondage per day for 14 days, which divided into control group, and intervention groups were given fresh green coconut water in each by 6, 8, and 10 mL/kgBW for intervention 7 and 17 days. The result of this study showed that there is a significant effect and the decrease in mercury levels in the blood. There is no significant affect on the hemoglobin level, hematocrit level and platelet count with the treatment of green coconut water in the mice with exposure Hg. There is no significant effect between treatments using green coconut water with SGPT levels; there is a decrease in SGPT levels at the increasing number of doses of green coconut water and the length of treatment.

  18. Assessment of water quality in distribution networks through the lens ...

    2016-04-02

    Apr 2, 2016 ... method, which identifies the regions with relatively poor water quality and highlights the potential locations for ... intelligent decision-making based on the results and the imple- ... A water supply system where water is treated.

  19. Assessment of drinking water quality using principal component ...

    Assessment of drinking water quality using principal component analysis and partial least square discriminant analysis: a case study at water treatment plants, ... water and to detect the source of pollution for the most revealing parameters.

  20. Assessment of historical surface-water quality data in southwestern Colorado, 1990-2005

    Miller, Lisa D.; Schaffrath, Keelin R.; Linard, Joshua I.

    2013-01-01

    The spatial and temporal distribution of selected physical and chemical surface-water-quality characteristics were analyzed at stream sites throughout the Dolores and San Juan River Basins in southwestern Colorado using historical data collected from 1990 through 2005 by various local, State, Tribal, and Federal agencies. Overall, streams throughout the study area were well oxygenated. Values of pH generally were near neutral to slightly alkaline throughout most of the study area with the exception of the upper Animas River Basin near Silverton where acidic conditions existed at some sites because of hydrothermal alteration and(or) historical mining. The highest concentrations of dissolved aluminum, total recoverable iron, dissolved lead, and dissolved zinc were measured at sites located in the upper Animas River Basin. Thirty-two sites throughout the study area had at least one measured concentration of total mercury that exceeded the State chronic aquatic-life criterion of 0.01 μg/L. Concentrations of dissolved selenium at some sites exceeded the State chronic water-quality standard of 4.6 μg/L. Total ammonia, nitrate, nitrite, and total phosphorus concentrations generally were low throughout the study area. Overall, results from the trend analyses indicated improvement in water-quality conditions as a result of operation of the Paradox Valley Unit in the Dolores River Basin and irrigation and water-delivery system improvements made in the McElmo Creek Basin (Lower San Juan River Basin) and Mancos River Valley (Upper San Juan River Basin).

  1. Safe and high quality food production using low quality waters and improved irrigation systems and management

    Plauborg, Finn; Andersen, Mathias Neumann; Liu, Fulai

    2010-01-01

    uneven irrigation patterns can increase the water use efficiency as well as the quality of vegetable crops. Furthermore, recent innovations in the water treatment and irrigation industry have shown potential for the use of low quality water resources, such as reclaimed water or surface water in peri...

  2. Mercury accumulation in Lethrinus nebulosus from the marine waters of the Qatar EEZ.

    Al-Ansari, Ebrahim M A S; Abdel-Moati, Mohamed A R; Yigiterhan, Oguz; Al-Maslamani, Ibrahim; Soliman, Yousria; Rowe, Gilbert T; Wade, Terry L; Al-Shaikh, Ismail M; Helmi, Ahmed; Kuklyte, Ligita; Chatting, Mark; Al-Ansi Al-Yafei, Mehsin A

    2017-08-15

    Total mercury (THg) and methylmercury (MeHg) were recorded in the commercial demersal fish Lethrinus nebulosus, caught from six locations in Qatar EEZ (Exclusive Economic Zone). Concentrations of THg decreased in the order: liver˃muscle˃gonad. THg concentrations in fish tissue ranged from 0.016ppm in gonad to 0.855ppm (mgkg -1 w/w) in liver tissues, while concentrations in muscle tissue ranged from 0.24 to 0.49ppm (mgkg -1 w/w) among sampling sites. MeHg concentrations were used to validate food web transfer rate calculations. Intake rates were calculated to assess the potential health impact of the fish consumption. There is no major threat to human health from the presence of Hg in L. nebulosus, based upon reasonable consumption patterns, limited to no more than three meals of L. nebulosus per week. Copyright © 2017 Elsevier Ltd. All rights reserved.

  3. Combined toxicity of mercury and plastic wastes to crustacean and gastropod inhabiting the waters in Kuwait.

    Bu-Olayan, A H; Thomas, B V

    2015-11-01

    The present study determined total mercury (T-Hg) in crustacean Portunus pelagicus (blue crab) and mollusc Tapes sulcarius (Furrowed Venus: Cockle) following suspected rise in beach plastic wastes and their effect on marine organisms. Live samples were collected from beaches representing six Kuwait Governorate areas and exposed to toxicity (96hr) and bio accumulation tests for 180 d with inclusion of plastic wastes and environmental conditions simulated in laboratory. Results revealed high T-Hg concentrations in T sulcarius (1.44ng l(-1)) compared to P. pelagicus (1.03ng l(-1)) during winter than summer, with bio accumulation factor (BAF) > 1 labelled these species as hyper-accumulators. Significantly, combination of T-Hg concentrations from plastic wastes and in seawater validated the possibilities of detrimental effects of other marine lives besides deteriorating the aesthetic values of scenic beaches and likelihood of invasive species in such coastal areas.

  4. Dispersive solid phase micro-extraction of mercury(II from environmental water and vegetable samples with ionic liquid modified graphene oxide nanoparticles

    Nasrollahpour Atefeh

    2017-01-01

    Full Text Available A new dispersive solid phase micro-extraction (dispersive-SPME method for separation and preconcentration of mercury(II using ionic liquid modified magnetic reduced graphene oxide (IL-MrGO nanoparticles, prior to the measurement by cold vapour atomic absorption spectrometry (CV-AAS has been developed. The IL-MrGO composite was characterized by Brunauer– Emmett–Teller method (BET for adsorption-desorption measurement, thermogravimetric analysis (TGA, powder X-ray diffraction (XRD and X-ray photoelectron spectroscopy (XPS. The method is based on the sorption of mercury( II on IL-MrGO nanoparticles due to electrostatic interaction and complex formation of ionic liquid part of IL-MrGO with mercury(II. The effect of experimental parameters for preconcentration of mercury(II, such as solution type, concentration and volume of the eluent, pH, time of the sorption and desorption, amount of the sorbent and coexisting ion concentration have been optimized. Under the optimized conditions, a linear response was obtained in the concentration range of 0.08–10 ng mL-1 with a determination coefficient of 0.9995. The limit of detection (LOD of the method at a signal to noise ratio of 3 was 0.01 ng mL-1. Intra-day and inter-day precisions were obtained equal to 3.4 and 4.5 %, respectively. The dispersive solid phase micro-extraction of mercury(II on IL-MrGO nanoparticles coupled with cold vapour atomic absorption spectrometry was successfully used for extraction and determination of mercury(II in water and vegetable samples.

  5. Process for removing mercury from aqueous solutions

    Googin, John M.; Napier, John M.; Makarewicz, Mark A.; Meredith, Paul F.

    1986-01-01

    A process for removing mercury from water to a level not greater than two parts per billion wherein an anion exchange material that is insoluble in water is contacted first with a sulfide containing compound and second with a compound containing a bivalent metal ion forming an insoluble metal sulfide. To this treated exchange material is contacted water containing mercury. The water containing not more than two parts per billion of mercury is separated from the exchange material.

  6. Influence of long-range transboundary transport on atmospheric water vapor mercury collected at the largest city of Tibet

    Huang, Jie; Kang, Shichang; Tian, Lide; Guo, Junming; Zhang, Qianggong; Cong, Zhiyuan; Sillanpää, Mika

    2016-01-01

    Monsoon circulation is an important process that affects long-range transboundary transport of anthropogenic contaminants such as mercury (Hg). During the Indian monsoon season of 2013, a total of 92 and 26 atmospheric water vapor samples were collected at Lhasa, the largest city of the Tibet, for Hg and major ions analysis, respectively. The relatively low pH/high electronic conductivity values, together with the fact that NH_4"+ in atmospheric water vapor was even higher than that determined in precipitation of Lhasa, indicated the effects of anthropogenic perturbations through long-range transboundary atmospheric transport. Concentrations of Hg in atmospheric water vapor ranged from 2.5 to 73.7 ng L"−"1, with an average of 12.5 ng L"−"1. The elevated Hg and major ions concentrations, and electronic conductivity values were generally associated with weak acidic samples, and Hg mainly loaded with anthropogenic ions such as NH_4"+. The results of principal component analysis and trajectory analysis suggested that anthropogenic emissions from the Indian subcontinent may have largely contributed to the determined Hg in atmospheric water vapor. Furthermore, our study reconfirmed that below-cloud scavenging contribution was significant for precipitation Hg in Lhasa, and evaluated that on average 74.1% of the Hg in precipitation could be accounted for by below-cloud scavenging. - Highlights: • The low pH/high electronic conductivity was found in atmospheric water vapor. • Anthropogenic NH_4"+ was higher than that determined in precipitation of Lhasa. • Elevated Hg and major ions levels were usually associated with weak acidic samples. • Hg in atmospheric water vapor was largely influenced by transboundary transport. • Below-cloud scavenging accounted for most Hg in precipitation.

  7. Influence of long-range transboundary transport on atmospheric water vapor mercury collected at the largest city of Tibet

    Huang, Jie [Key Laboratory of Tibetan Environment Changes and Land Surface Processes, Institute of Tibetan Plateau Research, Chinese Academy of Sciences, Beijing 100101 (China); CAS Center for Excellence in Tibetan Plateau Earth Sciences, Chinese Academy of Sciences, Beijing 100101 (China); Laboratory of Green Chemistry, Lappeenranta University of Technology, Sammonkatu 12, Mikkeli FI 50130 (Finland); Kang, Shichang, E-mail: shichang.kang@lzb.ac.cn [State Key Laboratory of Cryospheric Sciences, Cold and Arid Regions Environmental and Engineering Research Institute, Chinese Academy of Sciences, Lanzhou 730000 (China); CAS Center for Excellence in Tibetan Plateau Earth Sciences, Chinese Academy of Sciences, Beijing 100101 (China); Tian, Lide [Key Laboratory of Tibetan Environment Changes and Land Surface Processes, Institute of Tibetan Plateau Research, Chinese Academy of Sciences, Beijing 100101 (China); CAS Center for Excellence in Tibetan Plateau Earth Sciences, Chinese Academy of Sciences, Beijing 100101 (China); Guo, Junming [Key Laboratory of Tibetan Environment Changes and Land Surface Processes, Institute of Tibetan Plateau Research, Chinese Academy of Sciences, Beijing 100101 (China); Graduate University of the Chinese Academy of Sciences, Beijing 100049 (China); Zhang, Qianggong; Cong, Zhiyuan [Key Laboratory of Tibetan Environment Changes and Land Surface Processes, Institute of Tibetan Plateau Research, Chinese Academy of Sciences, Beijing 100101 (China); CAS Center for Excellence in Tibetan Plateau Earth Sciences, Chinese Academy of Sciences, Beijing 100101 (China); Sillanpää, Mika [Laboratory of Green Chemistry, Lappeenranta University of Technology, Sammonkatu 12, Mikkeli FI 50130 (Finland); and others

    2016-10-01

    Monsoon circulation is an important process that affects long-range transboundary transport of anthropogenic contaminants such as mercury (Hg). During the Indian monsoon season of 2013, a total of 92 and 26 atmospheric water vapor samples were collected at Lhasa, the largest city of the Tibet, for Hg and major ions analysis, respectively. The relatively low pH/high electronic conductivity values, together with the fact that NH{sub 4}{sup +} in atmospheric water vapor was even higher than that determined in precipitation of Lhasa, indicated the effects of anthropogenic perturbations through long-range transboundary atmospheric transport. Concentrations of Hg in atmospheric water vapor ranged from 2.5 to 73.7 ng L{sup −1}, with an average of 12.5 ng L{sup −1}. The elevated Hg and major ions concentrations, and electronic conductivity values were generally associated with weak acidic samples, and Hg mainly loaded with anthropogenic ions such as NH{sub 4}{sup +}. The results of principal component analysis and trajectory analysis suggested that anthropogenic emissions from the Indian subcontinent may have largely contributed to the determined Hg in atmospheric water vapor. Furthermore, our study reconfirmed that below-cloud scavenging contribution was significant for precipitation Hg in Lhasa, and evaluated that on average 74.1% of the Hg in precipitation could be accounted for by below-cloud scavenging. - Highlights: • The low pH/high electronic conductivity was found in atmospheric water vapor. • Anthropogenic NH{sub 4}{sup +} was higher than that determined in precipitation of Lhasa. • Elevated Hg and major ions levels were usually associated with weak acidic samples. • Hg in atmospheric water vapor was largely influenced by transboundary transport. • Below-cloud scavenging accounted for most Hg in precipitation.

  8. Mercury speciation and analysis in drinking water by stir bar sorptive extraction with in situ propyl derivatization and thermal desorption-gas chromatography-mass spectrometry.

    Ito, Rie; Kawaguchi, Migaku; Sakui, Norihiro; Honda, Hidehiro; Okanouchi, Noriya; Saito, Koichi; Nakazawa, Hiroyuki

    2008-10-31

    A method for mercury analysis and speciation in drinking water was developed, which involved stir bar sorptive extraction (SBSE) with in situ propyl derivatization and thermal desorption (TD)-GC-MS. Ten millilitre of tap water or bottled water was used. After a stir bar, pH adjustment agent and derivatization reagent were added, SBSE was performed. Then, the stir bar was subjected to TD-GC-MS. The detection limits were 0.01 ng mL(-1) (ethylmercury; EtHg), 0.02 ng mL(-1) (methylmercury; MeHg), and 0.2 ng mL(-1) (Hg(II) and diethylmercury (DiEtHg)). The method showed good linearity and correlation coefficients. The average recoveries of mercury species (n=5) in water samples spiked with 0.5, 2.0, and 6.0 ng mL(-1) mercury species were 93.1-131.1% (RSDmercury species in water samples.

  9. The Usefullness of Green Coconut Water Supplementation in Overcoming The Toxic Effect of Mercury Chloride in The Blood and Blood Profile (Study in Sprague Dewly Rats

    Abdulrzag Ehmeeda

    2017-07-01

    Full Text Available When people are exposed to mercury chloride, it can produce a variety of health effects in the blood and liver. Coconut water contains Zn, Fe, Vit. C, Vit B11, Vit. B6­, and Se to reduce mercury chloride level in the blood and improve blood profile. Aim of this study was to analysis the effect of green coconut water supplementation in overcoming the toxic effect of Hg chloride in the blood of Sprague dawley rats exposed to Hg chloride. Samples were randomly about 36 animals rats exposed to HgCl2 through forced feeding by 20 mg/kgBW sondage perday for 14 days, which divided into control group, and intervention groups were given fresh green coconut water in each by 6, 8, and 10 mL/kgBW for intervention 7 and 17 days. The result of this study showed that there is a significant effect and the decrease in mercury levels in the blood. There is no significant affect on the hemoglobin level, hematocrit level and platelet count with the treatment of green coconut water in the rats with exposure Hg. New findings/significance of contribution were the effectiveness of green coconut water to reduce Hg level in blood and improve blood profile.

  10. Assessment of water supply system and water quality of Lighvan village using water safety plan

    Mojtaba Pourakbar

    2015-12-01

    Full Text Available Background: Continuous expansion of potable water pollution sources is one of the main concerns of water suppliers, therefore measures such as water safety plan (WSP, have been taken into account to control these sources of pollution. The aim of this study was to identify probable risks and threatening hazards to drinking water quality in Lighvan village along with assessment of bank filtration of the village. Methods: In the present study all risks and probable hazards were identified and ranked. For each of these cases, practical suggestions for removing or controlling them were given. To assess potable water quality in Lighvan village, sampling was done from different parts of the village and physicochemical parameters were measured. To assess the efficiency of bank filtration system of the village, independent t test was used to compare average values of parameters in river and treated water. Results: One of the probable sources of pollution in this study was domestic wastewater which threatens water quality. The results of this study show that bank filtration efficiency in water supply of the village is acceptable. Conclusion: Although Bank filtration imposes fewer expenses on governments, it provides suitable water for drinking and other uses. However, it should be noted that application of these systems should be done after a thorough study of water pollution level, types of water pollutants, soil properties of the area, soil percolation and system distance from pollutant sources.

  11. Bottled Water: United States Consumers and Their Perceptions of Water Quality

    Hu, Zhihua; Morton, Lois Wright; Mahler, Robert L.

    2011-01-01

    Consumption of bottled water is increasing worldwide. Prior research shows many consumers believe bottled water is convenient and has better taste than tap water, despite reports of a number of water quality incidents with bottled water. The authors explore the demographic and social factors associated with bottled water users in the U.S. and the relationship between bottled water use and perceptions of the quality of local water supply. They find that U.S. consumers are more likely to report...

  12. Hydroeconomic optimization of reservoir management under downstream water quality constraints

    Davidsen, Claus; Liu, Suxia; Mo, Xingguo

    2015-01-01

    water quantity and water quality management and minimizes the total costs over a planning period assuming stochastic future runoff. The outcome includes cost-optimal reservoir releases, groundwater pumping, water allocation, wastewater treatments and water curtailments. The optimization model uses......), and the resulting minimum dissolved oxygen (DO) concentration is computed with the Streeter-Phelps equation and constrained to match Chinese water quality targets. The baseline water scarcity and operational costs are estimated to 15.6. billion. CNY/year. Compliance to water quality grade III causes a relatively...

  13. MANAGING MANURE TO IMPROVE AIR AND WATER QUALITY

    Aillery, Marcel P.; Gollehon, Noel R.; Johansson, Robert C.; Kaplan, Jonathan D.; Key, Nigel D.; Ribaudo, Marc

    2005-01-01

    Animal waste from confined animal feeding operations is a potential source of air and water quality degradation from evaporation of gases, runoff to surface water, and leaching to ground water. This report assesses the potential economic and environmental tradeoffs between water quality policies and air quality policies that require the animal agriculture sector to take potentially costly measures to abate pollution. A farm-level analysis of hog farms estimates the economic and environmental ...

  14. Water Quality Assessment for Deep-water Channel area of Guangzhou Port based on the Comprehensive Water Quality Identification Index Method

    Chen, Yi

    2018-03-01

    The comprehensive water quality identification index method is able to assess the general water quality situation comprehensively and represent the water quality classification; water environment functional zone achieves pollution level and standard objectively and systematically. This paper selects 3 representative zones along deep-water channel of Guangzhou port and applies comprehensive water quality identification index method to calculate sea water quality monitoring data for different selected zones from year 2006 to 2014, in order to investigate the temporal variation of water quality along deep-water channel of Guangzhou port. The comprehensive water quality level from north to south presents an increased trend, and the water quality of the three zones in 2014 is much better than in 2006. This paper puts forward environmental protection measurements and suggestions for Pearl River Estuary, provides data support and theoretical basis for studied sea area pollution prevention and control.

  15. Integrating Product Water Quality Effects In Holistic Assessments Of Water Systems

    Rygaard, Martin

    2011-01-01

    While integrated assessments of sustainability of water systems are largely focused on quantity issues, chemical use, and energy consumption, effects of the supplied water quality are often overlooked. Drinking water quality affects corrosion rates, human health, applicability of water and aesthetics. Even small changes in the chemical composition of water may accumulate large impacts on city scale. Here, a method for integrated assessment of water quality is presented. Based on dose-response...

  16. Modeling of Water Quality 'Almendares River'

    Domínguez Catasús, Judith

    2005-01-01

    The river Almendares, one of the most important water bodies of the Havana City, is very polluted. The analysis of parameters as dissolved oxygen and biochemical oxygen demand is very helpful for the studies aimed to the recovery of the river. There is a growing recognition around the word that the water quality models are very useful tools to plan sanitary strategies for the handling of the contamination. In the present work, the advective, steady- state Streeter and Phelps model was validated to simulate the effect of the multiple-point and distributed sources on the carbonaceous oxygen demand, NH4 and dissolved oxygen. For modeling purposes the section of the river located between the point where the waste water treatment station Maria del Carmen discharges to the river and the Bridge El Bosque, was divided in 11 segments. The use of the 99mTc and the Rodamine WT as tracers allowed determining the hydrodynamic parameters necessary for modeling purposes. The validated model allows to predict the effect of the sanitary strategies on the water quality of the river. The main conclusions are: 1. The model Streeter and Phelps calibrated and validated in the Almendares between the confluence of the channel 'María del Carmen' and bridge the Forest of Havana, described in more than 90% The behavior of the dissolved oxygen and BODn (in terms of ammonia), and more than 85%, the carbonaceous demand oxygen, which characterizes the process of purification. 2. Model validation Streeter and Phelps, indicates that implicit conceptual model is appropriate. This refers primarily to the considerations relating to the calculation of the kinetic constants and the DOS, the segmentation used, to the location of the discharges and the Standing been about them, to the river morphology and hydrodynamic parameters . 3. The calibration procedure Streeter and Phelps model that determines the least-squares Kr-Kd pair that best fits the OD and uses this Kr to model BOD gets four% increase in

  17. 42 CFR 494.40 - Condition: Water and dialysate quality.

    2010-10-01

    ... demonstrate the following: (a) Standard: Water purity. Water and equipment used for dialysis meets the water... Boulevard, Suite 400, Arlington, VA 22201-4598. (b) Standard: Chlorine/chloramines. (1) The water treatment... 42 Public Health 5 2010-10-01 2010-10-01 false Condition: Water and dialysate quality. 494.40...

  18. Mercury Phase II Study - Mercury Behavior in Salt Processing Flowsheet

    Jain, V.; Shah, H.; Wilmarth, W. R.

    2016-01-01

    Mercury (Hg) in the Savannah River Site Liquid Waste System (LWS) originated from decades of canyon processing where it was used as a catalyst for dissolving the aluminum cladding of reactor fuel. Approximately 60 metric tons of mercury is currently present throughout the LWS. Mercury has long been a consideration in the LWS, from both hazard and processing perspectives. In February 2015, a Mercury Program Team was established at the request of the Department of Energy to develop a comprehensive action plan for long-term management and removal of mercury. Evaluation was focused in two Phases. Phase I activities assessed the Liquid Waste inventory and chemical processing behavior using a system-by-system review methodology, and determined the speciation of the different mercury forms (Hg+, Hg++, elemental Hg, organomercury, and soluble versus insoluble mercury) within the LWS. Phase II activities are building on the Phase I activities, and results of the LWS flowsheet evaluations will be summarized in three reports: Mercury Behavior in the Salt Processing Flowsheet (i.e. this report); Mercury Behavior in the Defense Waste Processing Facility (DWPF) Flowsheet; and Mercury behavior in the Tank Farm Flowsheet (Evaporator Operations). The evaluation of the mercury behavior in the salt processing flowsheet indicates, inter alia, the following: (1) In the assembled Salt Batches 7, 8 and 9 in Tank 21, the total mercury is mostly soluble with methylmercury (MHg) contributing over 50% of the total mercury. Based on the analyses of samples from 2H Evaporator feed and drop tanks (Tanks 38/43), the source of MHg in Salt Batches 7, 8 and 9 can be attributed to the 2H evaporator concentrate used in assembling the salt batches. The 2H Evaporator is used to evaporate DWPF recycle water. (2) Comparison of data between Tank 21/49, Salt Solution Feed Tank (SSFT), Decontaminated Salt Solution Hold Tank (DSSHT), and Tank 50 samples suggests that the total mercury as well as speciated

  19. The maladies of water and war: addressing poor water quality in Iraq.

    Zolnikov, Tara Rava

    2013-06-01

    Water is essential in providing nutrients, but contaminated water contributes to poor population health. Water quality and availability can change in unstructured situations, such as war. To develop a practical strategy to address poor water quality resulting from intermittent wars in Iraq, I reviewed information from academic sources regarding waterborne diseases, conflict and war, water quality treatment, and malnutrition. The prevalence of disease was high in impoverished, malnourished populations exposed to contaminated water sources. The data aided in developing a strategy to improve water quality in Iraq, which encompasses remineralized water from desalination plants, health care reform, monitoring and evaluation systems, and educational public health interventions.

  20. Indices of quality surface water bodies in the planning of water resources

    Rodríguez-Miranda, Juan Pablo

    2016-12-01

    Full Text Available This paper considers a review of the literature major and significant methods of quality indices of water applied in surface water bodies, used and proposed for assessing the significance of parameters of water quality in the assessment of surface water currents and they are usually used in making decisions for intervention and strategic prevention measures for those responsible for the conservation and preservation of watersheds where these water bodies belong. An exploratory methodology was applied to realize the conceptualization of each water quality index. As a result, it is observed that there are several important methods for determining the water quality index applied in surface water bodies.