WorldWideScience

Sample records for mercury continuous emission

  1. A Cavity Ring-Down Spectroscopy Mercury Continuous Emission Monitor

    Energy Technology Data Exchange (ETDEWEB)

    Christopher C. Carter

    2004-12-15

    The Sensor Research & Development Corporation (SRD) has undertaken the development of a Continuous Emissions Monitor (CEM) for mercury based on the technique of Cavity Ring-Down Spectroscopy (CRD). The project involved building an instrument for the detection of trace levels of mercury in the flue gas emissions from coal-fired power plants. The project has occurred over two phases. The first phase concentrated on the development of the ringdown cavity and the actual detection of mercury. The second phase dealt with the construction and integration of the sampling system, used to carry the sample from the flue stack to the CRD cavity, into the overall CRD instrument. The project incorporated a Pulsed Alexandrite Laser (PAL) system from Light Age Incorporated as the source to produce the desired narrow band 254 nm ultra-violet (UV) radiation. This laser system was seeded with a diode laser to bring the linewidth of the output beam from about 150 GHz to less than 60 MHz for the fundamental beam. Through a variety of non-linear optics the 761 nm fundamental beam is converted into the 254 nm beam needed for mercury detection. Detection of the mercury transition was verified by the identification of the characteristic natural isotopic structure observed at lower cavity pressures. The five characteristic peaks, due to both natural isotopic abundance and hyperfine splitting, provided a unique identifier for mercury. SRD scientists were able to detect mercury in air down below 10 parts-per-trillion by volume (pptr). This value is dependent on the pressure and temperature within the CRD cavity at the time of detection. Sulfur dioxide (SO{sub 2}) absorbs UV radiation in the same spectral region as mercury, which is a significant problem for most mercury detection equipment. However, SRD has not only been able to determine accurate mercury concentrations in the presence of SO{sub 2}, but the CRD instrument can in fact determine the SO{sub 2} concentration as well. Detection of

  2. A CAVITY RING-DOWN SPECTROSCOPY MERCURY CONTINUOUS EMISSION MONITOR

    Energy Technology Data Exchange (ETDEWEB)

    Christopher C. Carter

    2004-03-31

    The construction of the sampling system was completed during the past quarter. The sampling system has been built on a 3 feet x 4 feet x 2 inch breadboard table. The laser system, all the associated optics, and the mounts and hardware needed to couple the UV light into the fiber optic have also been condensed and placed on an identical 3 feet x 4 feet x 2 inch breadboard table. This reduces the footprint of each system for ease of operation at a field test facility. The two systems are only connected with a fiber optic, to bring the UV light to the CRD cavity, and a single coaxial cable used to apply a voltage to the diode seed laser to scan the frequency over the desired mercury transition. SRD software engineers applied a couple of software fixes to correct the problems of the diode seed laser drifting or mode hopping. Upon successful completion of the software fixes another long-term test was conducted. A nearly 3 day long, 24 hours/day, test was run to test out the new subroutines. Everything appeared to work as it should and the mercury concentrations were accurately reported for the entire test, with the exception of a small interval of time when the intensity of the UV light dropped low enough that the program was no longer triggering properly. After adjusting the power of the laser the program returned to proper operation. With the successful completion of a relatively long test SRD software engineer incorporated the new subroutine into an entirely new program. This program operates the CRD instrument automatically as a continuous emissions monitor for mercury. In addition the program also reports the concentration of SO{sub 2} determined in the sample flue gas stream. Various functions, operation of, and a description of the new program have been included with this report. This report concludes the technical work associated with Phase II of the Cavity Ring-Down project for the continuous detection of trace levels of mercury. The project is presently

  3. Procedure 5 Quality Assurance Requirements For Vapor Phase Mercury Continuous Emissions Monitoring Systems And Sorbent Trap Monitoring Systems Used For Compliance Determination At Stationary Sources

    Science.gov (United States)

    Promulgated quality assurance Procedure 5 Quality Assurance Requirements For Vapor Phase Mercury Continuous Emissions Monitoring Systems And Sorbent Trap Monitoring Systems Used For Compliance Determination At Stationary Sources

  4. Mercury emission monitoring on municipal waste combustion

    International Nuclear Information System (INIS)

    Braun, H.; Gerig, A.

    1991-01-01

    In waste incineration, mercury is the only heavy metal to be released as a gas, mostly as mercury(II) chloride, because of its high volatility. Continuous emission monitoring is possible only when mercury occurs in its elemental form. This paper reports on various possibilities of converting Hg(II) into Hg(0) that has been studied and tested on a laboratory scale and in the TAMARA refuse incineration pilot facility. Continuous mercury emission measurement appears to be possible, provided mercury is converted in the flue gas condensate precipitated. The measuring results obtained on two municipal solid waste and on one sewage treatment sludge incineration plants show that the mercury monitor is a highly sensitive and selective continuously working instrument for mercury emission monitoring

  5. Mercury Continuous Emmission Monitor Calibration

    Energy Technology Data Exchange (ETDEWEB)

    John Schabron; Eric Kalberer; Ryan Boysen; William Schuster; Joseph Rovani

    2009-03-12

    Mercury continuous emissions monitoring systems (CEMs) are being implemented in over 800 coal-fired power plant stacks throughput the U.S. Western Research Institute (WRI) is working closely with the Electric Power Research Institute (EPRI), the National Institute of Standards and Technology (NIST), and the Environmental Protection Agency (EPA) to facilitate the development of the experimental criteria for a NIST traceability protocol for dynamic elemental mercury vapor calibrators/generators. These devices are used to calibrate mercury CEMs at power plant sites. The Clean Air Mercury Rule (CAMR) which was published in the Federal Register on May 18, 2005 and vacated by a Federal appeals court in early 2008 required that calibration be performed with NIST-traceable standards. Despite the vacature, mercury emissions regulations in the future will require NIST traceable calibration standards, and EPA does not want to interrupt the effort towards developing NIST traceability protocols. The traceability procedures will be defined by EPA. An initial draft traceability protocol was issued by EPA in May 2007 for comment. In August 2007, EPA issued a conceptual interim traceability protocol for elemental mercury calibrators. The protocol is based on the actual analysis of the output of each calibration unit at several concentration levels ranging initially from about 2-40 {micro}g/m{sup 3} elemental mercury, and in the future down to 0.2 {micro}g/m{sup 3}, and this analysis will be directly traceable to analyses by NIST. The EPA traceability protocol document is divided into two separate sections. The first deals with the qualification of calibrator models by the vendors for use in mercury CEM calibration. The second describes the procedure that the vendors must use to certify the calibrators that meet the qualification specifications. The NIST traceable certification is performance based, traceable to analysis using isotope dilution inductively coupled plasma

  6. Field evaluation of a total mercury continuous emissions monitor at a U.S. Department of Energy mixed waste incinerator

    International Nuclear Information System (INIS)

    Gibson, L.V. Jr.; Dunn, J.E. Jr.; Baker, R.L.; Sigl, W.; Skegg, I.

    1999-01-01

    In conjunction with proposed Maximum Achievable Control Technology (MACT) standards for hazardous waste combustors, extended duration testing sponsored by the US Department of Energy (DOE) and the Environmental Protection Agency (EPA) of three mercury continuous emissions monitors (CEMs) was conducted in the 1996--97 timeframe at a commercial cement kiln burning hazardous wastes at Holly Hill, South Carolina. The emission characteristics of the kiln, specifically the combination of high particulate matter, moisture, and acid gases, were believed to have contributed to the failure of the tested CEMs. The MERCEM mercury analyzer for stack gases manufactured by Perkin Elmer and represented by Aldora Technologies was selected for further evaluation on a DOE mixed waste incinerator at Oak Ridge, Tennessee, expected to present less adverse conditions. The overall scope of the evaluation was carried out over a two-month period from September through October 1998. Not only was the performance of the MERCEM evaluated according to proposed EPA Performance Specification 12 but also were alternative methods of calibration with reference concentrations of mercury and a qualitative assessment of long-term endurance under wet stack conditions

  7. Mercury emission from crematories in Japan

    Directory of Open Access Journals (Sweden)

    M. Takaoka

    2010-04-01

    Full Text Available Anthropogenic sources of mercury emissions have a significant impact on global pollution. Therefore, finding uncharacterised sources and assessing the emissions from these sources are important. However, limited data are available worldwide on mercury emissions from crematories. In Japan, 99.9% of dead bodies are cremated, which is the highest percentage in the world, and more than 1600 crematories are in operation. We thus focused on emissions from crematories in Japan. The number of targeted facilities was seven, and we used continuous emission monitoring to measure the mercury concentrations and investigate mercury behaviour. The total mercury concentrations in stack gases were a few μg/Nm3 (normal cubic meters. Considering the time profile of mercury and its species in cremations, the findings confirmed that the mercury in stack gas originated from dental amalgam. The amount of mercury emissions was calculated using the total concentration and gas flow rate. Furthermore, the annual amount of mercury emission from crematories in Japan was estimated by using the total number of corpses. The emission amount was considerably lower than that estimated in the United Kingdom. From statistical analyses on population demographics and measurements, future total emissions from crematories were also predicted. As a result, the amount of mercury emitted by crematories will likely increase by 2.6-fold from 2007 to 2037.

  8. Mercury Emissions: The Global Context

    Science.gov (United States)

    Mercury emissions are a global problem that knows no national or continental boundaries. Mercury that is emitted to the air can travel thousands of miles in the atmosphere before it is eventually deposited back to the earth.

  9. Method and apparatus for monitoring mercury emissions

    Science.gov (United States)

    Durham, Michael D.; Schlager, Richard J.; Sappey, Andrew D.; Sagan, Francis J.; Marmaro, Roger W.; Wilson, Kevin G.

    1997-01-01

    A mercury monitoring device that continuously monitors the total mercury concentration in a gas. The device uses the same chamber for converting speciated mercury into elemental mercury and for measurement of the mercury in the chamber by radiation absorption techniques. The interior of the chamber is resistant to the absorption of speciated and elemental mercury at the operating temperature of the chamber.

  10. Coal fired flue gas mercury emission controls

    CERN Document Server

    Wu, Jiang; Pan, Weiguo; Pan, Weiping

    2015-01-01

    Mercury (Hg) is one of the most toxic heavy metals, harmful to both the environment and human health. Hg is released into the atmosphere from natural and anthropogenic sources and its emission control has caused much concern. This book introduces readers to Hg pollution from natural and anthropogenic sources and systematically describes coal-fired flue gas mercury emission control in industry, especially from coal-fired power stations. Mercury emission control theory and experimental research are demonstrated, including how elemental mercury is oxidized into oxidized mercury and the effect of

  11. Mercury emissions from municipal solid waste combustors

    Energy Technology Data Exchange (ETDEWEB)

    1993-05-01

    This report examines emissions of mercury (Hg) from municipal solid waste (MSW) combustion in the United States (US). It is projected that total annual nationwide MSW combustor emissions of mercury could decrease from about 97 tonnes (1989 baseline uncontrolled emissions) to less than about 4 tonnes in the year 2000. This represents approximately a 95 percent reduction in the amount of mercury emitted from combusted MSW compared to the 1989 mercury emissions baseline. The likelihood that routinely achievable mercury emissions removal efficiencies of about 80 percent or more can be assured; it is estimated that MSW combustors in the US could prove to be a comparatively minor source of mercury emissions after about 1995. This forecast assumes that diligent measures to control mercury emissions, such as via use of supplemental control technologies (e.g., carbon adsorption), are generally employed at that time. However, no present consensus was found that such emissions control measures can be implemented industry-wide in the US within this time frame. Although the availability of technology is apparently not a limiting factor, practical implementation of necessary control technology may be limited by administrative constraints and other considerations (e.g., planning, budgeting, regulatory compliance requirements, etc.). These projections assume that: (a) about 80 percent mercury emissions reduction control efficiency is achieved with air pollution control equipment likely to be employed by that time; (b) most cylinder-shaped mercury-zinc (CSMZ) batteries used in hospital applications can be prevented from being disposed into the MSW stream or are replaced with alternative batteries that do not contain mercury; and (c) either the amount of mercury used in fluorescent lamps is decreased to an industry-wide average of about 27 milligrams of mercury per lamp or extensive diversion from the MSW stream of fluorescent lamps that contain mercury is accomplished.

  12. Coal fired flue gas mercury emission controls

    International Nuclear Information System (INIS)

    Wu, Jiang; Pan, Weiguo; Cao, Yan; Pan, Weiping

    2015-01-01

    Mercury (Hg) is one of the most toxic heavy metals, harmful to both the environment and human health. Hg is released into the atmosphere from natural and anthropogenic sources and its emission control has caused much concern. This book introduces readers to Hg pollution from natural and anthropogenic sources and systematically describes coal-fired flue gas mercury emission control in industry, especially from coal-fired power stations. Mercury emission control theory and experimental research are demonstrated, including how elemental mercury is oxidized into oxidized mercury and the effect of flue gas contents on the mercury speciation transformation process. Mercury emission control methods, such as existing APCDs (air pollution control devices) at power stations, sorbent injection, additives in coal combustion and photo-catalytic methods are introduced in detail. Lab-scale, pilot-scale and full-scale experimental studies of sorbent injection conducted by the authors are presented systematically, helping researchers and engineers to understand how this approach reduces the mercury emissions in flue gas and to apply the methods in mercury emission control at coal-fired power stations.

  13. Increased mercury emissions from modern dental amalgams.

    Science.gov (United States)

    Bengtsson, Ulf G; Hylander, Lars D

    2017-04-01

    All types of dental amalgams contain mercury, which partly is emitted as mercury vapor. All types of dental amalgams corrode after being placed in the oral cavity. Modern high copper amalgams exhibit two new traits of increased instability. Firstly, when subjected to wear/polishing, droplets rich in mercury are formed on the surface, showing that mercury is not being strongly bonded to the base or alloy metals. Secondly, high copper amalgams emit substantially larger amounts of mercury vapor than the low copper amalgams used before the 1970s. High copper amalgams has been developed with focus on mechanical strength and corrosion resistance, but has been sub-optimized in other aspects, resulting in increased instability and higher emission of mercury vapor. This has not been presented to policy makers and scientists. Both low and high copper amalgams undergo a transformation process for several years after placement, resulting in a substantial reduction in mercury content, but there exist no limit for maximum allowed emission of mercury from dental amalgams. These modern high copper amalgams are nowadays totally dominating the European, US and other markets, resulting in significant emissions of mercury, not considered when judging their suitability for dental restoration.

  14. Urban artisanal gold shops and mercury emissions

    International Nuclear Information System (INIS)

    Cordy, P.; Veiga, M.; Carrasco, V.H.G.

    2008-01-01

    Artisanal miners in developing countries use mercury amalgamation processes to extract gold. The amalgams are then refined before being sold on to urban gold shops. The amalgams can often contain between 2 to 40 per cent mercury. Unburned amalgams are also often sold directly to gold shops. There are serious health risks for shop employees and nearby populations when the gold is melted and further purified. Studies have shown that mercury concentrations in the ambient air of gold shops often exceeds World Health Organization (WHO) limits by an order of magnitude or more. This study examined the practices and technologies used to refine gold in Latin America and Indonesia. The study compared and contrasted various refining methods and their resulting mercury emissions. Methods of reducing mercury emissions were also investigated, including a filtration system designed to capture 80 per cent of mercury emissions. Barriers to implementing mercury emissions reduction plans were also investigated. It was concluded that the design of urban gold shops must include condensers, fume hoods, and efficient mercury capture systems. 15 refs

  15. Urban artisanal gold shops and mercury emissions

    Energy Technology Data Exchange (ETDEWEB)

    Cordy, P.; Veiga, M.; Carrasco, V.H.G. [British Columbia Univ., Vancouver, BC (Canada). Dept. of Mining and Mineral Process Engineering

    2008-07-01

    Artisanal miners in developing countries use mercury amalgamation processes to extract gold. The amalgams are then refined before being sold on to urban gold shops. The amalgams can often contain between 2 to 40 per cent mercury. Unburned amalgams are also often sold directly to gold shops. There are serious health risks for shop employees and nearby populations when the gold is melted and further purified. Studies have shown that mercury concentrations in the ambient air of gold shops often exceeds World Health Organization (WHO) limits by an order of magnitude or more. This study examined the practices and technologies used to refine gold in Latin America and Indonesia. The study compared and contrasted various refining methods and their resulting mercury emissions. Methods of reducing mercury emissions were also investigated, including a filtration system designed to capture 80 per cent of mercury emissions. Barriers to implementing mercury emissions reduction plans were also investigated. It was concluded that the design of urban gold shops must include condensers, fume hoods, and efficient mercury capture systems. 15 refs.

  16. Semi-continuous detection of mercury in gases

    Science.gov (United States)

    Granite, Evan J [Wexford, PA; Pennline, Henry W [Bethel Park, PA

    2011-12-06

    A new method for the semi-continuous detection of heavy metals and metalloids including mercury in gaseous streams. The method entails mass measurement of heavy metal oxides and metalloid oxides with a surface acoustic wave (SAW) sensor having an uncoated substrate. An array of surface acoustic wave (SAW) sensors can be used where each sensor is for the semi-continuous emission monitoring of a particular heavy metal or metalloid.

  17. Control of mercury emissions: policies, technologies, and future trends

    OpenAIRE

    Rhee, Seung-Whee

    2015-01-01

    Seung-Whee Rhee Department of Environmental Engineering, Kyonggi University, Suwon, Republic of Korea Abstract: Owing to the Minamata Convention on Mercury and the Global Mercury Partnership, policies and regulations on mercury management in advanced countries were intensified by a mercury phaseout program in the mercury control strategy. In developing countries, the legislative or regulatory frameworks on mercury emissions are not established specifically, but mercury management is designed...

  18. Reducing global mercury emissions in artisanal and small-scale ...

    International Development Research Centre (IDRC) Digital Library (Canada)

    2016-04-28

    caused mercury emissions, surpassing even coal-burning. With more than 15 million small-scale gold miners operating in more than 70 countries today, finding a way to reduce mercury emissions is vital.

  19. Mercury rising : mercury emissions from Ontario Power Generation's coal-fired plants

    International Nuclear Information System (INIS)

    Rang, S.

    2004-09-01

    Ontario Power Generation (OPG) operates 5 coal-fired power plants which are the largest single source of mercury emissions in Ontario. Mercury is a persistent, bioaccumulative neurotoxin which is considered toxic under the Canadian Environmental Protection Act. This report examines the health and environmental impacts of mercury, and the trends for mercury emission in Ontario. In 2002, the 5 coal-fired plants emitted 527 kg of mercury into the atmosphere and contributed 39 per cent of the total amount of mercury emitted into the air. While many other sectors have reduced their mercury emissions since 1988, Ontario's coal-fired plants have lagged behind and have actually increased mercury emissions by 16 per cent since 1988. This paper suggests that phasing out OPG coal-fired plants by 2007 could lead to a 39 per cent reduction in airborne mercury emissions. It would also allow Ontario to achieve the Canada Wide Standard for mercury emissions 3 years early, and would help both Ontario and Canada meet air pollution reduction commitments under international agreements. It was noted that phasing out coal-fired power plants by one-third will help Ontario achieve its goal of a 90 per cent reduction in mercury emissions by 2010. It was suggested that alternative power sources can offer a wide range of environmental advantages. 16 refs., 3 tabs., 2 figs

  20. Anthropogenic mercury emissions from 1980 to 2012 in China.

    Science.gov (United States)

    Huang, Ying; Deng, Meihua; Li, Tingqiang; Japenga, Jan; Chen, Qianqian; Yang, Xiaoe; He, Zhenli

    2017-07-01

    China was considered the biggest contributor for airborne mercury in the world but the amount of mercury emission in effluents and solid wastes has not been documented. In this study, total national and regional mercury emission to the environment via exhaust gases, effluents and solid wastes were accounted with updated emission factors and the amount of goods produced and/or consumed. The national mercury emission in China increased from 448 to 2151 tons during the 1980-2012 period. Nearly all of the emissions were ended up as exhaust gases and solid wastes. The proportion of exhaust gases decreased with increasing share of solid wastes and effluents. Of all the anthropogenic sources, coal was the most important contributor in quantity, followed by mercury mining, gold smelting, nonferrous smelting, iron steel production, domestic wastes, and cement production, with accounting for more than 90% of the total emission. There was a big variation of regional cumulative mercury emission during 1980-2012 in China, with higher emissions occurred in eastern areas and lower values in the western and far northern regions. The biggest cumulative emission occurred in GZ (Guizhou), reaching 3974 t, while the smallest cumulative emission was lower than 10 t in XZ (Tibet). Correspondingly, mercury accumulation in soil were higher in regions with larger emissions in unit area. Therefore, it is urgent to reduce anthropogenic mercury emission and subsequent impact on ecological functions and human health. Copyright © 2017. Published by Elsevier Ltd.

  1. Mercury emission from a temperate lake during autumn turnover

    International Nuclear Information System (INIS)

    Wollenberg, Jennifer L.; Peters, Stephen C.

    2009-01-01

    Lakes in temperate regions stratify during summer and winter months, creating distinct layers of water differentiated by their physical and chemical characteristics. When lakes mix in autumn and spring, mercury cycling may be affected by the chemical changes that occur during mixing. Sampling was conducted in Lake Lacawac, Eastern Pennsylvania, USA, throughout the autumn of 2007 to characterize changes in emission of gaseous elemental mercury (Hg 0 ) from the lake surface and dissolved mercury profiles in the water column during mixing. Water chemistry and weather parameters were also measured, including dissolved organic carbon (DOC), iron, and solar radiation which have been shown to interact with mercury species. Results indicate that emission of Hg 0 from the lake to the atmosphere during turnover was controlled both by solar radiation and by surface water mercury concentration. As autumn turnover progressed through the months of October and November, higher mercury concentration water from the hypolimnion mixed with epilimnetic water, increasing mercury concentration in epilimnetic waters. Dissolved absorbance was significantly correlated with mercury concentrations and with iron, but DOC concentrations were essentially constant throughout the study period and did not exhibit a relationship with either dissolved mercury concentrations or emission rates. Positive correlations between dissolved mercury and iron and manganese also suggest a role for these elements in mercury transport within the lake, but iron and manganese did not demonstrate a relationship with emission rates. This research indicates that consideration of seasonal processes in lakes is important when evaluating mercury cycling in aquatic systems

  2. Continuous acoustic emission from aluminium

    International Nuclear Information System (INIS)

    Fenici, P.; Kiesewetter, N.; Schiller, P.

    1976-01-01

    Continuous acoustic emission of aluminum single crystals and polycrystals during tensile tests at constant cross-head speed and at room temperature is measured with a Root Mean Square Level recorder. By means of the Kaiser effect it is shown that the continuous emission is related to the plastic deformation. The plot of continuous emission against strain takes different shapes for pure single crystals, pure polycrystals and impure polycrystals. The measured voltages have about the same value for pure single and polycrystals and are considerably greater than that for impure polycrystals. A method is developed to distinguish between continuous emission and burst

  3. Assessment of the mercury emissions from burning mining waste dumps

    Directory of Open Access Journals (Sweden)

    Barbara Białecka

    2016-04-01

    occur and to which the environment and local inhabitants can be exposed, it is important to define the size of the emission of mercury compounds from these objects. Despite the potential threats so far no measurements of mercury concentration which would a llow quantifying this phenomenon have been done. The analyses presented in this article fill this gap. Additionally, initial calculation of annual mercury emissions from burning coal mining waste dumps in Poland is presented.

  4. Mercury emissions control technologies for mixed waste thermal treatment

    International Nuclear Information System (INIS)

    Chambers, A.; Knecht, M.; Soelberg, N.; Eaton, D.

    1997-01-01

    EPA has identified wet scrubbing at low mercury feedrates, as well as carbon adsorption via carbon injection into the offgas or via flow through fixed carbon beds, as control technologies that can be used to meet the proposed Maximum Achievable Control Technology (MACT) rule limit for mercury emissions from hazardous waste incinerators. DOE is currently funding demonstrations of gold amalgamation that may also control mercury to the desired levels. Performance data from a variety of sources was reviewed to determine ranges of achievable mercury control. Preliminary costs were estimated for using these technologies to control mercury emissions from mixed waste incineration. Mercury emissions control for mixed waste incineration may need to be more efficient than for incineration of other hazardous wastes because of higher mercury concentrations in some mixed waste streams. However, mercury control performance data for wet scrubbing and carbon adsorption is highly variable. More information is needed to demonstrate control efficiencies that are achievable under various design and operating conditions for wet scrubbing, carbon adsorption, and gold amalgamation technologies. Given certain assumptions made in this study, capital costs, operating costs, and lifecycle costs for carbon injection, carbon beds, and gold amalgamation generally vary for different assumed mercury feedrates and for different offgas flowrates. Assuming that these technologies can in fact provide the necessary mercury control performance, each of these technologies may be less costly than the others for certain mercury feedrates and the offgas flowrates

  5. Estimating mercury emissions from a zinc smelter in relation to China's mercury control policies

    International Nuclear Information System (INIS)

    Wang, S.X.; Song, J.X.; Li, G.H.; Wu, Y.; Zhang, L.; Wan, Q.; Streets, D.G.; Chin, Conrad K.; Hao, J.M.

    2010-01-01

    Mercury concentrations of flue gas at inlet/outlet of the flue gas cleaning, electrostatic demister, reclaiming tower, acid plant, and mercury contents in zinc concentrate and by-products were measured in a hydrometallurgical zinc smelter. The removal efficiency of flue gas cleaning, electrostatic demister, mercury reclaiming and acid plant was about 17.4%, 30.3%, 87.9% and 97.4% respectively. Flue gas cleaning and electrostatic demister captured 11.7% and 25.3% of the mercury in the zinc concentrate, respectively. The mercury reclaiming tower captured 58.3% of the mercury in the zinc concentrate. About 4.2% of the mercury in the zinc concentrate was captured by the acid plant. Consequently, only 0.8% of the mercury in the zinc concentrate was emitted to the atmosphere. The atmospheric mercury emission factor was 0.5 g t -1 of zinc produced for the tested smelter, indicating that this process offers the potential to effectively reduce mercury emissions from zinc smelting. - Modern scale production equipped with acid plant and Hg reclaiming tower will significantly reduce Hg emissions from zinc smelters in China.

  6. Increased mercury emissions from modern dental amalgams

    OpenAIRE

    Bengtsson, Ulf G.; Hylander, Lars D.

    2017-01-01

    All types of dental amalgams contain mercury, which partly is emitted as mercury vapor. All types of dental amalgams corrode after being placed in the oral cavity. Modern high copper amalgams exhibit two new traits of increased instability. Firstly, when subjected to wear/polishing, droplets rich in mercury are formed on the surface, showing that mercury is not being strongly bonded to the base or alloy metals. Secondly, high copper amalgams emit substantially larger amounts of mercury vapor ...

  7. Mercury emissions from India and South East Asia

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2012-10-01

    Mercury is an element of growing global concern. The United Nations Environment Programme plans to finalise a new global legally binding instrument on mercury by 2013, to coordinate actions to reduce emissions of mercury. It has been well established that Asia represents not only the region contributing to greatest current mercury emissions but also the region with the fastest growth rate. Despite this, emissions from human activities in most countries in this region are not well characterised. This report summarises the limited data available on mercury emissions from India, Cambodia, Indonesia, Malaysia, the Philippines, Thailand and Vietnam. These countries were specifically selected as they are areas of potentially significant growth in energy use in the near future. Information is given on the major sources of mercury in these countries, concentrating mostly on coal combustion and the non-ferrous metal industry. Although it is beyond the scope of this report to make new estimates for emissions, information is provided on current fossil fuel use and industrial activity as well as projections for these sectors to 2020 to give an indication of the general scale of these sources and the potential for increased emissions in the future. Some countries have established regulations or action plans on emissions and these are summarised where possible. Recommendations are then made for potential actions which could be taken in each country to encourage action and achieve economic reduction in mercury emissions.

  8. Mercury emissions from coal combustion in Silesia, analysis using geostatistics

    Science.gov (United States)

    Zasina, Damian; Zawadzki, Jaroslaw

    2015-04-01

    Data provided by the UNEP's report on mercury [1] shows that solid fuel combustion in significant source of mercury emission to air. Silesia, located in southwestern Poland, is notably affected by mercury emission due to being one of the most industrialized Polish regions: the place of coal mining, production of metals, stone mining, mineral quarrying and chemical industry. Moreover, Silesia is the region with high population density. People are exposed to severe risk of mercury emitted from both: industrial and domestic sources (i.e. small household furnaces). Small sources have significant contribution to total emission of mercury. Official and statistical analysis, including prepared for international purposes [2] did not provide data about spatial distribution of the mercury emitted to air, however number of analysis on Polish public power and energy sector had been prepared so far [3; 4]. The distribution of locations exposed for mercury emission from small domestic sources is interesting matter merging information from various sources: statistical, economical and environmental. This paper presents geostatistical approach to distibution of mercury emission from coal combustion. Analysed data organized in 2 independent levels: individual, bottom-up approach derived from national emission reporting system [5; 6] and top down - regional data calculated basing on official statistics [7]. Analysis, that will be presented, will include comparison of spatial distributions of mercury emission using data derived from sources mentioned above. Investigation will include three voivodeships of Poland: Lower Silesian, Opole (voivodeship) and Silesian using selected geostatistical methodologies including ordinary kriging [8]. References [1] UNEP. Global Mercury Assessment 2013: Sources, Emissions, Releases and Environmental Transport. UNEP Chemicals Branch, Geneva, Switzerland, 2013. [2] NCEM. Poland's Informative Inventory Report 2014. NCEM at the IEP-NRI, 2014. http

  9. Micrometeorological methods for measurements of mercury emissions over contaminated soils

    International Nuclear Information System (INIS)

    Kim, K.H.; Lindberg, S.E.; Hanson, P.J.; Owens, J.; Myers, T.P.

    1993-01-01

    As part of a larger study involving development and application of field and laboratory methods (micrometeorological, dynamic enclosure chamber, and controlled laboratory chamber methods) to measure the air/surface exchange of Hg vapor, we performed a series of preliminary measurements over contaminated soils. From March--April 1993, we used the modified Bowen ratio (MBR) method to measure emission rates of mercury over a floodplain contaminated with mercury near Oak Ridge, TN. The mercury emission rates measured from contaminated EFPC soils using the MBR method during early spring show that (1) in all cases, the contaminated soils acted as a source of mercury to the atmosphere with source strengths ranging from 17 to 160 ng m -2 h -1 ; and (2) the strengths of mercury emissions can be greatly influenced by the combined effects of surface soil temperature, residence time of air masses over the source area, and turbulence conditions. The mercury fluxes measured in a controlled flow chamber indicate that contaminated soils can exhibit up to an order of magnitude higher emission rates of Hg under conditions of elevated soil temperature, soil structure disturbance, and high turbulence. Mercury emissions from contaminated soils exceeded emissions from background soils by one to two orders of magnitude

  10. Emissions of airborne toxics from coal-fired boilers: Mercury

    Energy Technology Data Exchange (ETDEWEB)

    Huang, H.S.; Livengood, C.D.; Zaromb, S.

    1991-09-01

    Concerns over emissions of hazardous air Pollutants (air toxics) have emerged as a major environmental issue, and the authority of the US Environmental Protection Agency to regulate such pollutants was greatly expanded through the Clean Air Act Amendments of 1990. Mercury has been singled out for particular attention because of concerns over possible effects of emissions on human health. This report evaluates available published information on the mercury content of coals mined in the United States, on mercury emitted in coal combustion, and on the efficacy of various environmental control technologies for controlling airborne emissions. Anthracite and bituminous coals have the highest mean-mercury concentrations, with subbituminous coals having the lowest. However, all coal types show very significant variations in mercury concentrations. Mercury emissions from coal combustion are not well-characterized, particularly with regard to determination of specific mercury compounds. Variations in emission rates of more than an order of magnitude have been reported for some boiler types. Data on the capture of mercury by environmental control technologies are available primarily for systems with electrostatic precipitators, where removals of approximately 20% to over 50% have been reported. Reported removals for wet flue-gas-desulfurization systems range between 35 and 95%, while spray-dryer/fabric-filter systems have given removals of 75 to 99% on municipal incinerators. In all cases, better data are needed before any definitive judgments can be made. This report briefly reviews several areas of research that may lead to improvements in mercury control for existing flue-gas-clean-up technologies and summarizes the status of techniques for measuring mercury emissions from combustion sources.

  11. Inversion Approach to Validate Mercury Emissions Based on Background Air Monitoring at the High Altitude Research Station Jungfraujoch (3580 m).

    Science.gov (United States)

    Denzler, Basil; Bogdal, Christian; Henne, Stephan; Obrist, Daniel; Steinbacher, Martin; Hungerbühler, Konrad

    2017-03-07

    The reduction of emissions of mercury is a declared aim of the Minamata Convention, a UN treaty designed to protect human health and the environment from adverse effects of mercury. To assess the effectiveness of the convention in the future, better constraints about the current mercury emissions is a premise. In our study, we applied a top-down approach to quantify mercury emissions on the basis of atmospheric mercury measurements conducted at the remote high altitude monitoring station Jungfraujoch, Switzerland. We established the source-receptor relationships and by the means of atmospheric inversion we were able to quantify spatially resolved European emissions of 89 ± 14 t/a for elemental mercury. Our European emission estimate is 17% higher than the bottom-up emission inventory, which is within stated uncertainties. However, some regions with unexpectedly high emissions were identified. Stationary combustion, in particular in coal-fired power plants, is found to be the main responsible sector for increased emission estimates. Our top-down approach, based on measurements, provides an independent constraint on mercury emissions, helps to improve and refine reported emission inventories, and can serve for continued assessment of future changes in emissions independent from bottom-up inventories.

  12. Mercury and halogens in coal--Their role in determining mercury emissions from coal combustion

    Science.gov (United States)

    Kolker, Allan; Quick, Jeffrey C.; Senior, Connie L.; Belkin, Harvey E.

    2012-01-01

    Mercury is a toxic pollutant. In its elemental form, gaseous mercury has a long residence time in the atmosphere, up to a year, allowing it to be transported long distances from emission sources. Mercury can be emitted from natural sources such as volcanoes, or from anthropogenic sources, such as coal-fired powerplants. In addition, all sources of mercury on the Earth's surface can re-emit it from land and sea back to the atmosphere, from which it is then redeposited. Mercury in the atmosphere is present in such low concentrations that it is not considered harmful. Once mercury enters the aquatic environment, however, it can undergo a series of biochemical transformations that convert a portion of the mercury originally present to methylmercury, a highly toxic organic form of mercury that accumulates in fish and birds. Many factors contribute to creation of methylmercury in aquatic ecosystems, including mercury availability, sediment and nutrient load, bacterial influence, and chemical conditions. In the United States, consumption of fish with high levels of methylmercury is the most common pathway for human exposure to mercury, leading the U.S. Environmental Protection Agency (EPA) to issue fish consumption advisories in every State. The EPA estimates that 50 percent of the mercury entering the atmosphere in the United States is emitted from coal-burning utility powerplants. An EPA rule, known as MATS (for Mercury and Air Toxics Standards), to reduce emissions of mercury and other toxic pollutants from powerplants, was signed in December 2011. The rule, which is currently under review, specifies limits for mercury and other toxic elements, such as arsenic, chromium, and nickel. MATS also places limits on emission of harmful acid gases, such as hydrochloric acid and hydrofluoric acid. These standards are the result of a 2010 detailed nationwide program by the EPA to sample stack emissions and thousands of shipments of coal to coal-burning powerplants. The United

  13. Substance flow analysis for mercury emission in Poland

    Directory of Open Access Journals (Sweden)

    Panasiuk D.

    2013-04-01

    Full Text Available Substance Flow Analysis (SFA is an approach showing main sources of emission and flows of pollution to the environment, which allows to define possible environmental risk. Total identified mercury emission to air, soil and water in Poland for year 2010 from anthropogenic sources was estimated as 18.0 Mg. Annual Hg emission to air from by-product sources was equal 13.5 Mg, with the highest share of emission from brown coal-fired power plants. Mercury contained in combustion residues and removed from flue gases is transferred to waste waters, disposed to landfills and used to a concrete production with unknown amounts. Annual mercury emission to air from the use of mercury-containing products (0.5 Mg was estimated by authors based on model for distribution and emissions for batteries, light sources, other electrical and electronic equipment and also for measuring and control equipment. Emission to air from dental practice (0.3 Mg was estimated for combustion of wastes containing dental amalgam and from bodies cremation. SFA for the use of mercury-containing products and dental practice presents significant load of 10.4 Mg mercury contained in hazardous wastes produced annually. It covers wastes of used products, dental amalgam wastes directly from clinics as well as stream from incineration of infectious dental wastes. In the paper mercury discharges to water from large and medium industrial facilities (2.9 Mg and municipal waste-water treatment plants in large agglomerations (0.4 Mg are presented. Smaller loads are generates by leachate transfer from municipal landfills to WWTPs and further to agriculture and also by releases from dental amalgam in buried bodies. The paper indicates lack of information in SFA which should be regarded, mainly concerning mercury releases from municipal landfills to water and soil and emissions from municipal WWTPs to air.

  14. [Study on mercury re-emissions during fly ash utilization].

    Science.gov (United States)

    Meng, Yang; Wang, Shu-Xiao

    2012-09-01

    The amount of fly ash produced during coal combustion is around 400 million tons per year in China. About 65%-68% of fly ash is used in building material production, road construction, architecture and agriculture. Some of these utilization processes include high temperature procedures, which may lead to mercury re-emissions. In this study, experiments were designed to simulate the key process in cement production and steam-cured brick production. A temperature programmed desorption (TPD) method was used to study the mercury transformation in the major utilization processes. Mercury re-emission during the fly ash utilization in China was estimated based on the experimental results. It was found that mercury existed as HgCl2 (Hg2 Cl2), HgS and HgO in the fly ash. During the cement production process, more than 98% of the mercury in fly ash was re-emitted. In the steam-curing brick manufacturing process, the average mercury re-emission percentage was about 28%, which was dominated by the percentage of HgCl2 (Hg2 Cl2). It is estimated that the mercury re-emission during the fly ash utilization have increased from 4.07 t in 2002 to 9.18 t in 2008, of which cement industry contributes about 96.6%.

  15. Atmospheric mercury concentration and chemical speciation at a rural site in Beijing, China: implications of mercury emission sources

    Directory of Open Access Journals (Sweden)

    L. Zhang

    2013-10-01

    Full Text Available Continuous measurements of atmospheric mercury concentration and speciation play a key role in identifying mercury sources and its behavior in the atmosphere. In this study, speciated atmospheric mercury including gaseous elemental mercury (GEM, reactive gaseous mercury (RGM and particle-bound mercury (PBM were continuously measured at Miyun, a rural site in Beijing, China, from December 2008 to November 2009. The average GEM, RGM and PBM concentrations were found to be 3.22 ± 1.74, 10.1 ± 18.8 and 98.2 ± 112.7 pg m−3, respectively, about 2–20 times higher than the background concentration of the Northern Hemisphere. The results indicated that atmospheric mercury concentrations in northern China were highly affected by anthropogenic emissions. The atmospheric mercury showed obvious seasonal variations, with the highest seasonal average GEM concentration in summer (3.48 ng m−3 and the lowest value in winter (2.66 ng m−3. In autumn and winter a diurnal variation of GEM was observed, with peak levels in the late afternoon till midnight. Most of the high RGM concentration values occurred in the afternoon of all seasons due to the higher oxidation. The PBM concentration was higher in early morning of all seasons because of the the temperature inversion that increases in depth as the night proceeds. The ratio of GEM to CO indicates that residential boilers play an important role in the elevation of GEM in winter. The ratio of RGM to O3 could be an indicator of the contribution of local primary sources. The ratio of PBM to PM2.5 reveals that the air mass from the east and southwest of the site in spring and summer carries more atmospheric mercury. The HYSPLIT back-trajectory analysis indicated that the monitoring site is affected by local, regional and interregional sources simultaneously during heavy pollution episodes. The results from the potential source contribution function (PSCF model indicate that the atmospheric transport

  16. Influence of emissions on regional atmospheric mercury concentrations

    Directory of Open Access Journals (Sweden)

    Bieser J.

    2013-04-01

    Full Text Available Mercury is a global pollutant that is rapidly transported in the atmosphere. Unlike the majority of air pollutants the background concentrations of mercury play a major role for the atmospheric concentrations on a hemispheric scale. In this study the influence of regional anthropogenic emissions in comparison to the global emissions on mercury concentrations over Europe are investigated. For this purpose an advanced threedimensional model system is used that consists of three components. The emission model SMOKE-EU, the meteorological model COSMO-CLM, and the chemistry transport model (CTM CMAQ. A variety of sensitivity runs is performed in order to determine the influence of different driving factors (i.e. boundary conditions, anthropogenic and natural emissions, emission factors, meteorological fields on the atmoshperic concentrations of different mercury species. This study is part of the European FP7 project GMOS (Global Mercury Observation System. The aim is to identify the most important drivers for atmospheric mercury in order to optimize future regional modelling studies in the course of the GMOS project. Moreover, the model results are used to determine areas of interest for air-plane based in-situ measurements which are also part of GMOS.

  17. [Mercury Distribution Characteristics and Atmospheric Mercury Emission Factors of Typical Waste Incineration Plants in Chongqing].

    Science.gov (United States)

    Duan, Zhen-ya; Su, Hai-tao; Wang, Feng-yang; Zhang, Lei; Wang, Shu-xiao; Yu, Bin

    2016-02-15

    Waste incineration is one of the important atmospheric mercury emission sources. The aim of this article is to explore the atmospheric mercury pollution level of waste incineration industry from Chongqing. This study investigated the mercury emissions from a municipal solid waste incineration plant and a medical waste incineration plant in Chongqing. The exhaust gas samples in these two incineration plants were obtained using USA EPA 30B method. The mercury concentrations in the fly ash and bottom ash samples were analyzed. The results indicated that the mercury concentrations of the municipal solid waste and medical waste incineration plant in Chongqing were (26.4 +/- 22.7) microg x m(-3) and (3.1 +/- 0.8) microg x m(-3) in exhaust gas respectively, (5279.2 +/- 798.0) microg x kg(-1) and (11,709.5 +/- 460.5) microg x kg(-1) in fly ash respectively. Besides, the distribution proportions of the mercury content from municipal solid waste and medical waste in exhaust gas, fly ash, and bottom ash were 34.0%, 65.3%, 0.7% and 32.3%, 67.5%, 0.2% respectively; The mercury removal efficiencies of municipal solid waste and medical waste incineration plants were 66.0% and 67.7% respectively. The atmospheric mercury emission factors of municipal solid waste and medical waste incineration plants were (126.7 +/- 109.0) microg x kg(-1) and (46.5 +/- 12.0) microg x kg(-1) respectively. Compared with domestic municipal solid waste incineration plants in the Pearl River Delta region, the atmospheric mercury emission factor of municipal solid waste incineration plant in Chongqing was lower.

  18. Atmospheric mercury emission from artisanal mercury mining in Guizhou Province, Southwestern China

    Science.gov (United States)

    Li, Ping; Feng, Xinbin; Qiu, Guangle; Shang, Lihai; Wang, Shaofeng; Meng, Bo

    Mercury (Hg) mining is an important anthropogenic source of atmospheric Hg emissions. The Guizhou Province in Southwestern China is a region with extensive artisanal mercury mining (AMM), but little Hg emission data from this area is available. Using a mass balance method, we estimated emission factors from artisanal mercury mining in Wuchuan mercury mining area (WMMA) and Gouxi area (GX). Average emission factors were 18.2% in WMMA (ranging from 6.9% to 32.1%) and 9.8% in GX (ranging from 6.6% to 14.5%), respectively, which were 2.2-36.4 times higher than the literature values used to estimate Hg emission from Hg mining. Furthermore, the average Hg emission factor of AMM in WMMA was much higher than that in GX, indicating that double condensation processes practiced in GX resulted in higher recoveries and lower emission factors compared to single condensation process applied in WMMA. Atmospheric Hg emission was estimated to be 3.7-9.6 metric tons in 2004 for WMMA and 1.3-2.7 metric tons in 2006 for GX, indicating artisanal Hg mining was an important atmospheric Hg emission source in the study area.

  19. CHARACTERIZATION OF MERCURY EMISSIONS AT A CHLOR-ALKALI PLANT: STUDY ORGANIZATION AND IMPLEMENTATION

    Science.gov (United States)

    The paper describes the organization and implementation of a detailed emissions measurement campaign conducted over a 2-week period at the Olin Corporation's mercury chlor-alkali plant in Augusta, GA. (NOTE: Since data analysis is continuing, study results will be provided later...

  20. Atmospheric emission of mercury due to combustion of steam coal and domestic coal in China

    Science.gov (United States)

    Wang, Shaobin; Luo, Kunli

    2017-08-01

    To study the mercury emission due to the combustion of steam coal and domestic coal in China, we analyzed the mercury contents of coal, fly ash, bottom ash and sluicing water in thermal power plants, steam boilers as well as domestic coal-stoves, in Shaanxi, Shanxi, Shandong and Yunnan Provinces. This study conduct an estimate of the Hg emission rates from steam coal and domestic coal combustion based on the method of mass distribution ratio of fly ash and bottom ash. The results show that the Hg emission rate of coal combustion in thermal power plants is about 50.21% (electrostatic precipitators + wet flue gas desulfurization), and that in heating boilers is about 67.23%, and 92.28% in industrial boilers without flue gas desulphurisation equipment. Furthermore, Hg emission rate is 83.61% due to domestic coal combustion in coal-stoves. The Hg emission amount into the atmosphere from power and heat generation, industrial boilers, domestic coal-stoves and spontaneous combustion of coal gangue is roughly estimated to be 133 ± 4, 100 ± 17, 11 ± 0.1 and 47 ± 26 tons in China in 2014, respectively, and the total Hg emission amount from this paper is estimated at 292 tons. The trends of Hg emission in China from 1991 to 2014 show an accelerating growth after 2002. The proportion of mercury emission due to thermal power, heating generation and industrial energy utilization continuously increased. The atmospheric emission of mercury due to combustion of steam coal, domestic coal and coal gangue accounts nearly 50% in total anthropogenic Hg emissions in China, indicating one of the largest sources of Hg emission in China which should draw more public and scientific attention in the future.

  1. Mercury Emission Control Technologies for PPL Montana-Colstrip Testing

    Energy Technology Data Exchange (ETDEWEB)

    John P. Kay; Michael L. Jones; Steven A. Benson

    2007-04-01

    The Energy & Environmental Research Center (EERC) was asked by PPL Montana LLC (PPL) to provide assistance and develop an approach to identify cost-effective options for mercury control at its coal-fired power plants. The work conducted focused on baseline mercury level and speciation measurement, short-term parametric testing, and week long testing of mercury control technology at Colstrip Unit 3. Three techniques and various combinations of these techniques were identified as viable options for mercury control. The options included oxidizing agents or sorbent enhancement additives (SEAs) such as chlorine-based SEA1 and an EERC proprietary SEA2 with and without activated carbon injection. Baseline mercury emissions from Colstrip Unit 3 are comparatively low relative to other Powder River Basin (PRB) coal-fired systems and were found to range from 5 to 6.5 g/Nm3 (2.9 to 3.8 lb/TBtu), with a rough value of approximately 80% being elemental upstream of the scrubber and higher than 95% being elemental at the outlet. Levels in the stack were also greater than 95% elemental. Baseline mercury removal across the scrubber is fairly variable but generally tends to be about 5% to 10%. Parametric results of carbon injection alone yielded minimal reduction in Hg emissions. SEA1 injection resulted in 20% additional reduction over baseline with the maximum rate of 400 ppm (3 gal/min). Week long testing was conducted with the combination of SEA2 and carbon, with injection rates of 75 ppm (10.3 lb/hr) and 1.5 lb/MMacf (40 lb/hr), respectively. Reduction was found to be an additional 30% and, overall during the testing period, was measured to be 38% across the scrubber. The novel additive injection method, known as novel SEA2, is several orders of magnitude safer and less expensive than current SEA2 injection methods. However, used in conjunction with this plant configuration, the technology did not demonstrate a significant level of mercury reduction. Near-future use of this

  2. LOCAL IMPACTS OF MERCURY EMISSIONS FROM COAL FIRED POWER PLANTS.

    Energy Technology Data Exchange (ETDEWEB)

    SULLIVAN, T.M.; BOWERMAN, B.; ADAMS, J.; MILIAN, L.; LIPFERT, F.; SUBRAMANIAM, S.; BLAKE, R.

    2005-09-21

    Mercury is a neurotoxin that accumulates in the food chain and is therefore a health concern. The primary human exposure pathway is through fish consumption. Coal-fired power plants emit mercury and there is uncertainty over whether this creates localized hot spots of mercury leading to substantially higher levels of mercury in water bodies and therefore higher exposure. To obtain direct evidence of local deposition patterns, soil and vegetations samples from around three U.S. coal-fired power plants were collected and analyzed for evidence of hot spots and for correlation with model predictions of deposition. At all three sites, there was no correlation between modeled mercury deposition and either soil concentrations or vegetation concentrations. It was estimated that less than 2% of the total mercury emissions from these plants deposited within 15 km of these plants. These small percentages of deposition are consistent with the literature review findings of only minor perturbations in environmental levels, as opposed to hot spots, near the plants. The major objective of the sampling studies was to determine if there was evidence for hot spots of mercury deposition around coal-fired power plants. From a public health perspective, such a hot spot must be large enough to insure that it did not occur by chance, and it must increase mercury concentrations to a level in which health effects are a concern in a water body large enough to support a population of subsistence fishers. The results of this study suggest that neither of these conditions has been met.

  3. Estimation of mercury emissions into the Slovene environment in 2001

    Directory of Open Access Journals (Sweden)

    Martina Svetina

    2002-12-01

    Full Text Available The aim of the study was to collect data for better control of mercury emissions in Slovenia, especially from the point and spread sources of all categories. In the past years the Slovenian industry avoided the use of mercury as a raw material in the productionprocess to prevent the emissions and discharge of this hazardous substance. About 733 kg of Hg was imported with products, 620 kg Hg was produced with coal combustion and cement production, 920 kg was sold with products and around 200 kg was exported as waste in year 2001. Annually 1620 kg of Hg emission into environment is estimated, of this approximately 900 kg is deposited as waste, 630 kg escape in the air and 90 kg in water. The following sectors have been identified in Slovenia as the potential sources of mercury into environment: the thermal power plants, dental amalgams, products of electric industry (batteries, lamps, thermometers, manometers, barometers, chemicals, cement industry, incineration and waste treatment. A mercury flow diagram for Slovenia in theyear 2001 was established.

  4. Mercury Emission From Phragmites in a Contaminated Wetland

    Science.gov (United States)

    Bubb, M.; Peters, S.

    2008-12-01

    , as well as internal leaf properties such as transpiration and relative humidity. It is the ongoing goal of this study to relate the magnitude of mercury flux with said parameters in order to better understand the controls by which emission is enhanced or diminished.

  5. Mercury

    International Nuclear Information System (INIS)

    Vilas, F.; Chapman, C.R.; Matthews, M.S.

    1988-01-01

    Papers are presented on future observations of and missions to Mercury, the photometry and polarimetry of Mercury, the surface composition of Mercury from reflectance spectrophotometry, the Goldstone radar observations of Mercury, the radar observations of Mercury, the stratigraphy and geologic history of Mercury, the geomorphology of impact craters on Mercury, and the cratering record on Mercury and the origin of impacting objects. Consideration is also given to the tectonics of Mercury, the tectonic history of Mercury, Mercury's thermal history and the generation of its magnetic field, the rotational dynamics of Mercury and the state of its core, Mercury's magnetic field and interior, the magnetosphere of Mercury, and the Mercury atmosphere. Other papers are on the present bounds on the bulk composition of Mercury and the implications for planetary formation processes, the building stones of the planets, the origin and composition of Mercury, the formation of Mercury from planetesimals, and theoretical considerations on the strange density of Mercury

  6. Global mercury emissions from combustion in light of international fuel trading.

    Science.gov (United States)

    Chen, Yilin; Wang, Rong; Shen, Huizhong; Li, Wei; Chen, Han; Huang, Ye; Zhang, Yanyan; Chen, Yuanchen; Su, Shu; Lin, Nan; Liu, Junfeng; Li, Bengang; Wang, Xilong; Liu, Wenxin; Coveney, Raymond M; Tao, Shu

    2014-01-01

    The spatially resolved emission inventory is essential for understanding the fate of mercury. Previous global mercury emission inventories for fuel combustion sources overlooked the influence of fuel trading on local emission estimates of many countries, mostly developing countries, for which national emission data are not available. This study demonstrates that in many countries, the mercury content of coal and petroleum locally consumed differ significantly from those locally produced. If the mercury content in locally produced fuels were used to estimate emission, then the resulting global mercury emissions from coal and petroleum would be overestimated by 4.7 and 72%, respectively. Even higher misestimations would exist in individual countries, leading to strong spatial bias. On the basis of the available data on fuel trading and an updated global fuel consumption database, a new mercury emission inventory for 64 combustion sources has been developed. The emissions were mapped at 0.1° × 0.1° resolution for 2007 and at country resolution for a period from 1960 to 2006. The estimated global total mercury emission from all combustion sources (fossil fuel, biomass fuel, solid waste, and wildfires) in 2007 was 1454 Mg (1232-1691 Mg as interquartile range from Monte Carlo simulation), among which elementary mercury (Hg(0)), divalent gaseous mercury (Hg(2+)), and particulate mercury (Hg(p)) were 725, 548, and 181 Mg, respectively. The total emission from anthropogenic sources, excluding wildfires, was 1040 Mg (886-1248 Mg), with coal combustion contributing more than half. Globally, total annual anthropogenic mercury emission from combustion sources increased from 285 Mg (263-358 Mg) in 1960 to 1040 Mg (886-1248 Mg) in 2007, owing to an increased fuel consumption in developing countries. However, mercury emissions from developed countries have decreased since 2000.

  7. Mercury emissions from South Africa’s coal-fired power stations

    Directory of Open Access Journals (Sweden)

    Belinda L. Garnham

    2016-12-01

    Full Text Available Mercury is a persistent and toxic substance that can be bio-accumulated in the food chain. Natural and anthropogenic sources contribute to the mercury emitted in the atmosphere. Eskom’s coal-fired power stations in South Africa contributed just under 93% of the total electricity produced in 2015 (Eskom 2016. Trace amounts of mercury can be found in coal, mostly combined with sulphur, and can be released into the atmosphere upon combustion. Coal-fired electricity generation plants are the highest contributors to mercury emissions in South Africa. A major factor affecting the amount of mercury emitted into the atmosphere is the type and efficiency of emission abatement equipment at a power station. Eskom employs particulate emission control technology at all its coal-fired power stations, and new power stations will also have sulphur dioxide abatement technology. A co-beneficial reduction of mercury emissions exists as a result of emission control technology. The amount of mercury emitted from each of Eskom’s coal-fired power stations is calculated, based on the amount of coal burnt and the mercury content in the coal. Emission Reduction Factors (ERF’s from two sources are taken into consideration to reflect the co-benefit received from the emission control technologies at the stations. Between 17 and 23 tons of mercury is calculated to have been emitted from Eskom’s coal-fired power stations in 2015. On completion of Eskom’s emission reduction plan, which includes fabric filter plant retrofits at two and a half stations and a flue gas desulphurisation retrofit at one power station, total mercury emissions from the fleet will potentially be reduced by 6-13% by 2026 relative to the baseline. Mercury emission reduction is perhaps currently not the most pressing air quality problem in South Africa. While the focus should then be on reducing emissions of other pollutants which have a greater impact on human health, mercury emission reduction

  8. JV Task 98 - Controlling Mercury Emissions for Utilities Firing Lignites from North America

    Energy Technology Data Exchange (ETDEWEB)

    Steven Benson

    2007-06-15

    This project compiled and summarized the findings and conclusions of research, development, and demonstration projects on controlling mercury from lignite coals. A significant amount of work has been conducted since 1994 on mercury in lignite, mercury measurement in flue gases, sorbent, sorbent enhancement additives, oxidation agent development, and full-scale demonstration of mercury control technologies. This report is focused on providing the lignite industry with an understanding of mercury issues associated with the combustion of lignite, as well as providing vital information on the methods to control mercury emissions in coal-fired power plants.

  9. Mercury

    CERN Document Server

    Balogh, André; Steiger, Rudolf

    2008-01-01

    Mercury, the planet closest to the Sun, is different in several respects from the other three terrestrial planets. In appearance, it resembles the heavily cratered surface of the Moon, but its density is high, it has a magnetic field and magnetosphere, but no atmosphere or ionosphere. This book reviews the progress made in Mercury studies since the flybys by Mariner 10 in 1974-75, based on the continued research using the Mariner 10 archive, on observations from Earth, and on increasingly realistic models of its interior evolution.

  10. Mercury and plants in contaminated soils. 1: Uptake, partitioning, and emission to the atmosphere

    Energy Technology Data Exchange (ETDEWEB)

    Leonard, T.L.; Gustin, M.S.; Fernandez, G.C.J. [Univ. of Nevada, Reno, NV (United States); Taylor, G.E. Jr. [George Mason Univ., Fairfax, VA (United States). Dept. of Biology

    1998-10-01

    The uptake, distribution, and subsequent emission of mercury to the atmosphere were investigated in five plant species (Lepidium latifolium [L.], Artemisia douglasiana [Bess in Hook], Caulanthus sp. [S. Watson], Fragaria vesca [L.], and Eucalyptus globulus [Labill]) with different ecological and physiological attributes. Transfer coefficients for mercury in the soil-plant system were calculated. Plant-to-atmosphere emissions of mercury were determined using a controlled environment gas-exchange system and ranged from 10 to 93 mg/m{sup 2}/h in the light; emissions in the dark were an order of magnitude less. Transfer coefficients for mercury within the soil-plant system increased acropetally (root-to-leaf axis) by orders of magnitude. Estimated mercury emissions from plants in the Carson River Drainage Basin of Nevada over the growing season (0.5 mg/m{sup 2}) add to the previously reported soil mercury emissions (8.5 mg/m{sup 2}), resulting in total landscape emissions of 9 mg/m{sup 2}. For L. latifolium, 70% of the mercury taken up by the roots during the growing season was emitted to the atmosphere. For every one molecule of mercury retained in foliage of L. latifolium, 12 molecules of mercury were emitted. Within this arid ecosystem, mercury emissions are a dominant pathway of the mercury cycle. Plants function as conduits for the interfacial transport of mercury from the geosphere to the atmosphere, and this role is undervalued in models of the behavior of mercury in terrestrial exosystems and in the atmosphere on a global scale.

  11. Control of mercury emissions from coal-fired boilers

    Energy Technology Data Exchange (ETDEWEB)

    Huang, H.S.; Livengood, C.D.

    1992-09-01

    This project at Argonne is designed to investigate new concepts leading to advanced control technologies for fossil-energy systems. The objective of this new task on air toxics control is to develop new or improved, cost-effective control technology for the abatement of emissions of hazardous air pollutants (HAPs) from fossil-fuel combustion plants and to evaluate the possible effects of any captured species on waste disposal. The HAPs to be investigated initially in this task include mercury and arsenic compounds.

  12. Control of mercury emissions from coal-fired boilers

    Energy Technology Data Exchange (ETDEWEB)

    Huang, H.S.; Livengood, C.D.

    1992-01-01

    This project at Argonne is designed to investigate new concepts leading to advanced control technologies for fossil-energy systems. The objective of this new task on air toxics control is to develop new or improved, cost-effective control technology for the abatement of emissions of hazardous air pollutants (HAPs) from fossil-fuel combustion plants and to evaluate the possible effects of any captured species on waste disposal. The HAPs to be investigated initially in this task include mercury and arsenic compounds.

  13. Trends in anthropogenic mercury emissions estimated for South Africa during 2000-2006

    CSIR Research Space (South Africa)

    Masekoameng, KE

    2010-08-01

    Full Text Available Recent studies suggest an increase in mercury (Hg) emissions to the global environment, particularly as a result of anthropogenic activities. This has prompted many countries to complete Hg emission inventories, based on country-specific Hg sources...

  14. Control of mercury emissions from coal fired electric uitlity boilers: An update

    Science.gov (United States)

    Coal-fired power plants in the U.S. are known to be the major anthropogenic source of domestic mercury emissions. The Environmental Protection Agency (EPA) has recently proposed to reduce emissions of mercury from these plants. In March 2005, EPA plans to promulgate final regulat...

  15. Particulate-phase mercury emissions from biomass burning ...

    Science.gov (United States)

    Mercury (Hg) emissions from biomass burning (BB) are an important source of atmospheric Hg and a major factor driving the interannual variation of Hg concentrations in the troposphere. The greatest fraction of Hg from BB is released in the form of elemental Hg (Hg0(g)). However, little is known about the fraction of Hg bound to particulate matter (HgP) released from BB, and the factors controlling this fraction are also uncertain. In light of the aims of the Minamata Convention to reduce intentional Hg use and emissions from anthropogenic activities, the relative importance of Hg emissions from BB will have an increasing impact on Hg deposition fluxes. Hg speciation is one of the most important factors determining the redistribution of Hg in the atmosphere and the geographical distribution of Hg deposition. Using the latest version of the Global Fire Emissions Database (GFEDv4.1s) and the global Hg chemistry transport model, ECHMERIT, the impact of Hg speciation in BB emissions, and the factors which influence speciation, on Hg deposition have been investigated for the year 2013. The role of other uncertainties related to physical and chemical atmospheric processes involving Hg and the influence of model parametrisations were also investigated, since their interactions with Hg speciation are complex. The comparison with atmospheric HgP concentrations observed at two remote sites, Amsterdam Island (AMD) and Manaus (MAN), in the Amazon showed a significant improve

  16. Product-related emissions of Mercury to Air in the European Union

    Energy Technology Data Exchange (ETDEWEB)

    Kindbom, Karin; Munthe, John

    2007-06-15

    Mercury emissions to air from the use of mercury in products have been estimated for the EU for the year 2005. The consumption of mercury in the EU in 2005 was amounted to 125 tonnes in technical products. Estimates of emissions of mercury from dental amalgam were derived from information on cremations in European countries and average contents of amalgam fillings. Annual emissions of mercury to air from product use in EU27 have been estimated to be in the range 10-18 tonnes (best estimate 14 tonnes) from technical products and to 2-5 tonnes from cremation, in total 12-23 tonnes. Of the mercury consumed in technical products, 11% was calculated to be emitted to air, 31% to end up in safe storage while 58% would still be accumulated in society or disposed of in landfills. From the share still accumulated in society, as well as from the already land filled amounts, further emissions of mercury to air may occur in the longer term. Emissions from technical products are calculated based on the consumption of mercury in 2005. Emissions occurring in the same year but caused by consumption in the previous 10 years were derived using the consumption in 2005 and assuming the same patterns of distribution and emissions. The latest available estimates of total anthropogenic emissions of mercury in EU27 refer to the year 2000 and are in the order of 140-190 tonnes, probably to have declined to 2005. Based on these figures the contribution to anthropogenic mercury emissions to air in EU from product use and cremation in 2005 is at least 6-16%. In a previous report product related air emissions of 72 tonnes were estimated for Europe in the mid 1990s, corresponding to 18% of the total air emissions. A significant decrease of emissions has thus occurred which is in line with a decreasing use of mercury in technical products, more efficient collection of remaining products and better emission control. However, the calculations show that the use of mercury in products still

  17. [Method of continuous direct recording of arterial pressure from a mercury manometer].

    Science.gov (United States)

    Antelava, A L

    1978-01-01

    The article describes a transducer for continuous recording of the readings of a mercury manometer in which, to simplify the construction and calibration, the transducer of pressure changes to electric current changes is made of high-resistant (nichrome) wire passed through the tube of the mercury manometer and incorporated in the circuit of the measuring bridge.

  18. Mercury Production and Use in Colonial Andean Silver Production: Emissions and Health Implications

    Science.gov (United States)

    Hagan, Nicole A.

    2012-01-01

    Background: Colonial cinnabar mining and refining began in Huancavelica, Peru, in 1564. With a local source of mercury, the amalgamation process was adopted to refine silver in Potosí, Bolivia, in the early 1570s. As a result, large quantities of mercury were released into the environment. Objectives: We used archival, primary, and secondary sources to develop the first estimate of mercury emissions from cinnabar refining in Huancavelica and to revise previous estimates of emissions from silver refining in Potosí during the colonial period (1564–1810). Discussion: Although other estimates of historical mercury emissions have recognized Potosí as a significant source, Huancavelica has been overlooked. In addition, previous estimates of mercury emissions from silver refining under-estimated emissions because of unrecorded (contra-band) production and volatilization of mercury during processing and recovery. Archival descriptions document behavioral and health issues during the colonial period that are consistent with known effects of mercury intoxication. Conclusions: According to our calculations, between 1564 and 1810, an estimated 17,000 metric tons of mercury vapor were emitted from cinnabar smelting in Huancavelica, and an estimated 39,000 metric tons were released as vapor during silver refining operations in Potosí. Huancavelica and Potosí combined contributed > 25% of the 196,000 metric tons of mercury vapor emissions in all of Latin America between 1500 and 1800. The historical record is laden with evidence of mercury intoxication consistent with effects recognized today. Our estimates serve as the foundation of investigations of present-day contamination in Huancavelica and Potosí resulting from historical emissions of mercury. PMID:22334094

  19. Mercury production and use in colonial Andean silver production: emissions and health implications.

    Science.gov (United States)

    Robins, Nicholas A; Hagan, Nicole A

    2012-05-01

    Colonial cinnabar mining and refining began in Huancavelica, Peru, in 1564. With a local source of mercury, the amalgamation process was adopted to refine silver in Potosí, Bolivia, in the early 1570s. As a result, large quantities of mercury were released into the environment. We used archival, primary, and secondary sources to develop the first estimate of mercury emissions from cinnabar refining in Huancavelica and to revise previous estimates of emissions from silver refining in Potosí during the colonial period (1564-1810). Although other estimates of historical mercury emissions have recognized Potosí as a significant source, Huancavelica has been overlooked. In addition, previous estimates of mercury emissions from silver refining under-estimated emissions because of unrecorded (contra-band) production and volatilization of mercury during processing and recovery. Archival descriptions document behavioral and health issues during the colonial period that are consistent with known effects of mercury intoxication. According to our calculations, between 1564 and 1810, an estimated 17,000 metric tons of mercury vapor were emitted from cinnabar smelting in Huancavelica, and an estimated 39,000 metric tons were released as vapor during silver refining operations in Potosí. Huancavelica and Potosí combined contributed > 25% of the 196,000 metric tons of mercury vapor emissions in all of Latin America between 1500 and 1800. The historical record is laden with evidence of mercury intoxication consistent with effects recognized today. Our estimates serve as the foundation of investigations of present-day contamination in Huancavelica and Potosí resulting from historical emissions of mercury.

  20. Potential mercury emissions from fluorescent lamps production and obsolescence in mainland China.

    Science.gov (United States)

    Tan, Quanyin; Li, Jinhui

    2016-01-01

    The use of fluorescent lamps has expanded rapidly all over the world in recent years, because of their energy-saving capability. Consequently, however, mercury emissions from production, breakage, and discard of the lamps are drawing increasing concern from the public. This article focuses on evaluating the amount of mercury used for fluorescent lamp production, as well as the potential mercury emissions during production and breakage, in mainland China. It is expected to provide a comprehensive understanding about the risks present in the mercury from fluorescent lamps, and to know about the impacts of the policies on fluorescent lamps after their implementation. It is estimated that, in 2020, mercury consumption will be about 11.30-15.69 tonnes, a significant reduction of 34.9%-37.4% from that used in 2013, owing to improvement in mercury dosing dosage technology and tighter limitations on mercury content in fluorescent lamps. With these improvements, the amount of mercury remaining in fluorescent lamps and released during production is estimated to be 10.71-14.86 and 0.59-0.83 tonnes, respectively; the mercury released from waste fluorescent lamps is estimated to be about 5.37-7.59 tonnes. Also, a significant reduction to the mercury emission can be expected when a collection and treatment system is well established and conducted in the future. © The Author(s) 2015.

  1. Sources and trends of environmental mercury emissions in Asia

    International Nuclear Information System (INIS)

    Wong, Coby S.C.; Duzgoren-Aydin, Nurdan S.; Aydin, Adnan; Wong, Ming H.

    2006-01-01

    This paper focuses on environmental mercury emissions in Asia and elaborates its probable trend in the future and associated implications given the anticipated socioeconomic outlook and other macro-environmental factors. Among the various regions, Asia has become the largest contributor of anthropogenic atmospheric Hg, responsible for over half of the global emission. In the next few decades, a significant increase in anthropogenic Hg emissions in Asia is likely owing to rapid economic and industrial development, unless drastic measures are taken. In particular, the dominance of Asia in some Hg-emitting industries, such as coal combustion, steel production and gold mining, provokes a serious environmental concern over their potential contributions of incidental Hg in the region. Moreover, the increasing prevalence of electrical and electronic manufacturing industry as a user and a contributor of Hg in Asia is also worrying. Specifically, disposal of obsolete electrical and electronic wastes represents a phenomenon increasingly encountered in Asia. In addition to escalating anthropogenic Hg emissions in Asia, associated environmental and health implications may also exacerbate in the region for the probable effects of a unique combination of climatic (e.g. subtropical climate), environmental (e.g. acid rain) and socioeconomic factors (e.g. high population density). Hence, much effort is still needed to understand the role of Asia in global Hg cycle and associated environmental and health effects in the region

  2. Mercury release from dental amalgams into continuously replenished liquids.

    Science.gov (United States)

    Okabe, T; Elvebak, B; Carrasco, L; Ferracane, J L; Keanini, R G; Nakajima, H

    2003-01-01

    Studies have been performed using high- and low-copper amalgams to measure the amounts of mercury dissolution from dental amalgam in liquids such as artificial saliva; however, in most cases, mercury dissolution has been measured under static conditions and as such, may be self-limiting. This study measured the mercury release from low- and high-copper amalgams into flowing aqueous solutions to determine whether the total amounts of dissolution vary under these conditions when tested at neutral and acidic pH. High- and low-copper amalgam specimens were prepared and kept for 3 days. They were then longitudinally suspended in dissolution cells with an outlet at the bottom. Deionized water or acidic solution (pH1) was pumped through the cell. Test solutions were collected at several time periods up to 6 days or 1 month and then analyzed with a cold vapor atomic absorption spectrophotometer. After dissolution testing, the specimens were examined using SEM/XEDA for any selective degradation of the phases in the amalgam. Except for the high-copper amalgam in the pH1 solution, the dissolution rates were found to decrease exponentially with time. The rate for the high-copper amalgam in pH1 solution slowly increased for 1 month. The total amounts (microgram/cm(2)) of mercury released over 6 days or 1 month from both types of amalgam in deionized water were not significantly different (p>/=0.05). The high-copper amalgam released significantly more mercury than the low-copper amalgam in the pH1 solution at both time periods. For both amalgams, the dissolution in pH1 was significantly higher than in deionized water. Mercury dissolution from amalgam under dynamic conditions is enhanced in an acidic media, and most prominently for a high-copper formulation.

  3. Atmospheric mercury emissions in Australia from anthropogenic, natural and recycled sources

    Science.gov (United States)

    Nelson, Peter F.; Morrison, Anthony L.; Malfroy, Hugh J.; Cope, Martin; Lee, Sunhee; Hibberd, Mark L.; Meyer, C. P. (Mick); McGregor, John

    2012-12-01

    The United Nations Environment Programme (UNEP) has begun a process of developing a legally binding instrument to manage emissions of mercury from anthropogenic sources. The UNEP Governing Council has concluded that there is sufficient evidence of significant global adverse impacts from mercury to warrant further international action; and that national, regional and global actions should be initiated as soon as possible to identify populations at risk and to reduce human generated releases. This paper describes the development of, and presents results from, a comprehensive, spatially and temporally resolved inventory of atmospheric mercury emissions from the Australian landmass. Results indicate that the best estimate of total anthropogenic emissions of mercury to the atmosphere in 2006 was 15 ± 5 tonnes. Three industrial sectors contribute substantially to Australian anthropogenic emissions: gold smelting (˜50%, essentially from a single site/operation), coal combustion in power plants (˜15%) and alumina production from bauxite (˜12%). A diverse range of other sectors contribute smaller proportions of the emitted mercury, but industrial emissions account for around 90% of total anthropogenic mercury emissions. The other sectors include other industrial sources (mining, smelting, and cement production) and the use of products containing mercury. It is difficult to determine historical trends in mercury emissions given the large uncertainties in the data. Estimates for natural and re-emitted emissions from soil, water, vegetation and fires are made using meteorological models, satellite observations of land cover and soil and vegetation type, fuel loading, fire scars and emission factors which account for the effects of temperature, insolation and other environmental variables. These natural and re-emitted sources comfortably exceed the anthropogenic emissions, and comprise 4-12 tonnes per year from vegetation, 70-210 tonnes per year from soils, and 21-63 tonnes

  4. Were mercury emission factors for Chinese non-ferrous metal smelters overestimated? Evidence from onsite measurements in six smelters

    International Nuclear Information System (INIS)

    Zhang Lei; Wang Shuxiao; Wu Qingru; Meng Yang; Yang Hai; Wang Fengyang; Hao Jiming

    2012-01-01

    Non-ferrous metal smelting takes up a large proportion of the anthropogenic mercury emission inventory in China. Zinc, lead and copper smelting are three leading sources. Onsite measurements of mercury emissions were conducted for six smelters. The mercury emission factors were 0.09–2.98 g Hg/t metal produced. Acid plants with the double-conversion double-absorption process had mercury removal efficiency of over 99%. In the flue gas after acid plants, 45–88% was oxidized mercury which can be easily scavenged in the flue gas scrubber. 70–97% of the mercury was removed from the flue gas to the waste water and 1–17% to the sulfuric acid product. Totally 0.3–13.5% of the mercury in the metal concentrate was emitted to the atmosphere. Therefore, acid plants in non-ferrous metal smelters have significant co-benefit on mercury removal, and the mercury emission factors from Chinese non-ferrous metal smelters were probably overestimated in previous studies. - Highlights: ► Acid plants in smelters provide significant co-benefits for mercury removal (over 99%). ► Most of the mercury in metal concentrates for smelting ended up in waste water. ► Previously published emission factors for Chinese metal smelters were probably overestimated. - Acid plants in smelters have high mercury removal efficiency, and thus mercury emission factors for Chinese non-ferrous metal smelters were probably overestimated.

  5. Mercury transformation and speciation in flue gases from anthropogenic emission sources: a critical review

    Directory of Open Access Journals (Sweden)

    L. Zhang

    2016-02-01

    Full Text Available Mercury transformation mechanisms and speciation profiles are reviewed for mercury formed in and released from flue gases of coal-fired boilers, non-ferrous metal smelters, cement plants, iron and steel plants, waste incinerators, biomass burning and so on. Mercury in coal, ores, and other raw materials is released to flue gases in the form of Hg0 during combustion or smelting in boilers, kilns or furnaces. Decreasing temperature from over 800 °C to below 300 °C in flue gases leaving boilers, kilns or furnaces promotes homogeneous and heterogeneous oxidation of Hg0 to gaseous divalent mercury (Hg2+, with a portion of Hg2+ adsorbed onto fly ash to form particulate-bound mercury (Hgp. Halogen is the primary oxidizer for Hg0 in flue gases, and active components (e.g., TiO2, Fe2O3, etc. on fly ash promote heterogeneous oxidation and adsorption processes. In addition to mercury removal, mercury transformation also occurs when passing through air pollution control devices (APCDs, affecting the mercury speciation in flue gases. In coal-fired power plants, selective catalytic reduction (SCR system promotes mercury oxidation by 34–85 %, electrostatic precipitator (ESP and fabric filter (FF remove over 99 % of Hgp, and wet flue gas desulfurization system (WFGD captures 60–95 % of Hg2+. In non-ferrous metal smelters, most Hg0 is converted to Hg2+ and removed in acid plants (APs. For cement clinker production, mercury cycling and operational conditions promote heterogeneous mercury oxidation and adsorption. The mercury speciation profiles in flue gases emitted to the atmosphere are determined by transformation mechanisms and mercury removal efficiencies by various APCDs. For all the sectors reviewed in this study, Hgp accounts for less than 5 % in flue gases. In China, mercury emission has a higher Hg0 fraction (66–82 % of total mercury in flue gases from coal combustion, in contrast to a greater Hg2+ fraction (29–90 % from non-ferrous metal

  6. Mercury emission and dispersion models from soils contaminated by cinnabar mining and metallurgy.

    Science.gov (United States)

    Llanos, Willians; Kocman, David; Higueras, Pablo; Horvat, Milena

    2011-12-01

    The laboratory flux measurement system (LFMS) and dispersion models were used to investigate the kinetics of mercury emission flux (MEF) from contaminated soils. Representative soil samples with respect to total Hg concentration (26-9770 μg g(-1)) surrounding a decommissioned mercury-mining area (Las Cuevas Mine), and a former mercury smelter (Cerco Metalúrgico de Almadenejos), in the Almadén mercury mining district (South Central Spain), were collected. Altogether, 14 samples were analyzed to determine the variation in mercury emission flux (MEF) versus distance from the sources, regulating two major environmental parameters comprising soil temperature and solar radiation. In addition, the fraction of the water-soluble mercury in these samples was determined in order to assess how MEF from soil is related to the mercury in the aqueous soil phase. Measured MEFs ranged from less than 140 to over 10,000 ng m(-2) h(-1), with the highest emissions from contaminated soils adjacent to point sources. A significant decrease of MEF was then observed with increasing distance from these sites. Strong positive effects of both temperature and solar radiation on MEF was observed. Moreover, MEF was found to occur more easily in soils with higher proportions of soluble mercury compared to soils where cinnabar prevails. Based on the calculated Hg emission rates and with the support of geographical information system (GIS) tools and ISC AERMOD software, dispersion models for atmospheric mercury were implemented. In this way, the gaseous mercury plume generated by the soil-originated emissions at different seasons was modeled. Modeling efforts revealed that much higher emissions and larger mercury plumes are generated in dry and warm periods (summer), while the plume is smaller and associated with lower concentrations of atmospheric mercury during colder periods with higher wind activity (fall). Based on the calculated emissions and the model implementation, yearly emissions from

  7. Basic Information about Mercury

    Science.gov (United States)

    ... Your Environment Contact Us Share Basic Information about Mercury On this page: What is mercury? Emissions of ... Consumer products that traditionally contain mercury What is Mercury? Mercury is a naturally-occurring chemical element found ...

  8. Mercury biogeochemistry: Paradigm shifts, outstanding issues and research needs

    Science.gov (United States)

    Sonke, Jeroen E.; Heimbürger, Lars-Eric; Dommergue, Aurélien

    2013-05-01

    Half a century of mercury research has provided scientists and policy makers with a detailed understanding of mercury toxicology, biogeochemical cycling and past and future impacts on human exposure. The complexity of the global biogeochemical mercury cycle has led to repeated and ongoing paradigm shifts in numerous mercury-related disciplines and outstanding questions remain. In this review, we highlight some of the paradigm shifts and questions on mercury toxicity, the risks and benefits of seafood consumption, the source of mercury in seafood, and the Arctic mercury cycle. We see a continued need for research on mercury toxicology and epidemiology, for marine mercury dynamics and ecology, and for a closer collaboration between observational mercury science and mercury modeling in general. As anthropogenic mercury emissions are closely tied to the energy cycle (in particular coal combustion), mercury exposure to humans and wildlife are likely to persist unless drastic emission reductions are put in place.

  9. Mercury

    NARCIS (Netherlands)

    de Vries, Irma

    2017-01-01

    Mercury is a naturally occurring metal that exists in several physical and chemical forms. Inorganic mercury refers to compounds formed after the combining of mercury with elements such as chlorine, sulfur, or oxygen. After combining with carbon by covalent linkage, the compounds formed are called

  10. Assessment of mercury emission at Norcem's cement kiln by the use of 203Hg-tracer

    International Nuclear Information System (INIS)

    Eriksen, D.R.; Meyer, J.; Qvenild, C.; Tokheim, L.A.; Eriksen, T.A.

    2007-01-01

    In manufacture of cement clinker, mercury is introduced in the cement kiln system via the fuels and as constituents in the raw materials, i.e., limestone, iron ore, etc. The permissible emission of Hg to air is very low (0.05 mg/Nm 3 ) due to its toxicity. Thus, it is important to know how mercury distributes and behaves in the kiln system. The objective of the study was to measure the distribution of mercury in the kiln system, to measure the hold up time of Hg, to measure the portion of emission through the chimneys, and to see the dependence of the injection sites on these parameters. The results showed that the amounts of mercury being emitted through the exhaust gases were largely dependent on where it was injected. The residence time of mercury in the system was nevertheless long, after 10 hours it was still increase in the count rate of the mercury absorbed. There was also an immediate increase in the filter dust, but nothing could be measured in the clinker. This knowledge is needed for the reduction of mercury emissions. (author)

  11. Characterization of Mercury Emissions from ASGM Goldshop Activities in Peru

    Science.gov (United States)

    Mercury (Hg), used in artisanal small-scale gold mining (ASGM) practices, is recognized as a significant source of Hg release to the environment and is a major area of focus of the United Nations Environment Programme (UNEP) Global Mercury Partnership. Hg is used to bind (form a...

  12. Intercontinental transport and deposition patterns of atmospheric mercury from anthropogenic emissions

    Science.gov (United States)

    Chen, L.; Wang, H. H.; Liu, J. F.; Tong, Y. D.; Ou, L. B.; Zhang, W.; Hu, D.; Chen, C.; Wang, X. J.

    2014-09-01

    Global policies that regulate anthropogenic mercury emissions to the environment require quantitative and comprehensive source-receptor relationships for mercury emissions, transport and deposition among major continental regions. In this study, we use the GEOS-Chem global chemical transport model to establish source-receptor relationships among 11 major continental regions worldwide. Source-receptor relationships for surface mercury concentrations (SMC) show that some regions (e.g., East Asia, the Indian subcontinent, and Europe) should be responsible for their local surface Hg(II) and Hg(P) concentrations due to near-field transport and deposition contributions from their local anthropogenic emissions (up to 64 and 71% for Hg(II) and Hg(P), respectively, over East Asia). We define the region of primary influence (RPI) and the region of secondary influence (RSI) to establish intercontinental influence patterns. Results indicate that East Asia is the SMC RPI for almost all other regions, while Europe, Russia, and the Indian subcontinent also make some contributions to SMC over some receptor regions because they are dominant RSI source regions. Source-receptor relationships for mercury deposition show that approximately 16 and 17% of dry and wet deposition, respectively, over North America originate from East Asia, indicating that transpacific transport of East Asian emissions is the major foreign source of mercury deposition in North America. Europe, Southeast Asia, and the Indian subcontinent are also important mercury deposition sources for some receptor regions because they are the dominant RSIs. We also quantify seasonal variation on mercury deposition contributions over other regions from East Asia. Results show that mercury deposition (including dry and wet) contributions from East Asia over the Northern Hemisphere receptor regions (e.g., North America, Europe, Russia, the Middle East, and Middle Asia) vary seasonally, with the maximum values in summer and

  13. OPTIMIZING TECHNOLOGY TO REDUCE MERCURY AND ACID GAS EMISSIONS FROM ELECTRIC POWER PLANTS

    Energy Technology Data Exchange (ETDEWEB)

    Jeffrey C. Quick; David E. Tabet; Sharon Wakefield; Roger L. Bon

    2005-10-01

    Maps showing potential mercury, sulfur, chlorine, and moisture emissions for U.S. coal by county of origin were made from publicly available data (plates 1, 2, 3, and 4). Published equations that predict mercury capture by emission control technologies used at U.S. coal-fired utilities were applied to average coal quality values for 169 U.S. counties. The results were used to create five maps that show the influence of coal origin on mercury emissions from utility units with: (1) hot-side electrostatic precipitator (hESP), (2) cold-side electrostatic precipitator (cESP), (3) hot-side electrostatic precipitator with wet flue gas desulfurization (hESP/FGD), (4) cold-side electrostatic precipitator with wet flue gas desulfurization (cESP/FGD), and (5) spray-dry adsorption with fabric filter (SDA/FF) emission controls (plates 5, 6, 7, 8, and 9). Net (lower) coal heating values were calculated from measured coal Btu values, and estimated coal moisture and hydrogen values; the net heating values were used to derive mercury emission rates on an electric output basis (plate 10). Results indicate that selection of low-mercury coal is a good mercury control option for plants having hESP, cESP, or hESP/FGD emission controls. Chlorine content is more important for plants having cESP/FGD or SDA/FF controls; optimum mercury capture is indicated where chlorine is between 500 and 1000 ppm. Selection of low-sulfur coal should improve mercury capture where carbon in fly ash is used to reduce mercury emissions. Comparison of in-ground coal quality with the quality of commercially mined coal indicates that existing coal mining and coal washing practice results in a 25% reduction of mercury in U.S. coal before it is delivered to the power plant. Further pre-combustion mercury reductions may be possible, especially for coal from Texas, Ohio, parts of Pennsylvania and much of the western U.S.

  14. Mercury emissions from municipal solid waste combustors. An assessment of the current situation in the United States and forecast of future emissions

    Energy Technology Data Exchange (ETDEWEB)

    None

    1993-05-01

    This report examines emissions of mercury (Hg) from municipal solid waste (MSW) combustion in the United States (US). It is projected that total annual nationwide MSW combustor emissions of mercury could decrease from about 97 tonnes (1989 baseline uncontrolled emissions) to less than about 4 tonnes in the year 2000. This represents approximately a 95 percent reduction in the amount of mercury emitted from combusted MSW compared to the 1989 mercury emissions baseline. The likelihood that routinely achievable mercury emissions removal efficiencies of about 80 percent or more can be assured; it is estimated that MSW combustors in the US could prove to be a comparatively minor source of mercury emissions after about 1995. This forecast assumes that diligent measures to control mercury emissions, such as via use of supplemental control technologies (e.g., carbon adsorption), are generally employed at that time. However, no present consensus was found that such emissions control measures can be implemented industry-wide in the US within this time frame. Although the availability of technology is apparently not a limiting factor, practical implementation of necessary control technology may be limited by administrative constraints and other considerations (e.g., planning, budgeting, regulatory compliance requirements, etc.). These projections assume that: (a) about 80 percent mercury emissions reduction control efficiency is achieved with air pollution control equipment likely to be employed by that time; (b) most cylinder-shaped mercury-zinc (CSMZ) batteries used in hospital applications can be prevented from being disposed into the MSW stream or are replaced with alternative batteries that do not contain mercury; and (c) either the amount of mercury used in fluorescent lamps is decreased to an industry-wide average of about 27 milligrams of mercury per lamp or extensive diversion from the MSW stream of fluorescent lamps that contain mercury is accomplished.

  15. Economic analysis of atmospheric mercury emission control for coal-fired power plants in China.

    Science.gov (United States)

    Ancora, Maria Pia; Zhang, Lei; Wang, Shuxiao; Schreifels, Jeremy; Hao, Jiming

    2015-07-01

    Coal combustion and mercury pollution are closely linked, and this relationship is particularly relevant in China, the world's largest coal consumer. This paper begins with a summary of recent China-specific studies on mercury removal by air pollution control technologies and then provides an economic analysis of mercury abatement from these emission control technologies at coal-fired power plants in China. This includes a cost-effectiveness analysis at the enterprise and sector level in China using 2010 as a baseline and projecting out to 2020 and 2030. Of the control technologies evaluated, the most cost-effective is a fabric filter installed upstream of the wet flue gas desulfurization system (FF+WFGD). Halogen injection (HI) is also a cost-effective mercury-specific control strategy, although it has not yet reached commercial maturity. The sector-level analysis shows that 193 tons of mercury was removed in 2010 in China's coal-fired power sector, with annualized mercury emission control costs of 2.7 billion Chinese Yuan. Under a projected 2030 Emission Control (EC) scenario with stringent mercury limits compared to Business As Usual (BAU) scenario, the increase of selective catalytic reduction systems (SCR) and the use of HI could contribute to 39 tons of mercury removal at a cost of 3.8 billion CNY. The economic analysis presented in this paper offers insights on air pollution control technologies and practices for enhancing atmospheric mercury control that can aid decision-making in policy design and private-sector investments. Copyright © 2015. Published by Elsevier B.V.

  16. Development of novel activated carbon-based adsorbents for the control of mercury emissions from coal-fired power plants

    Energy Technology Data Exchange (ETDEWEB)

    Radisav D. Vidic

    1999-03-01

    In addition to naturally occurring mercury sources, anthropogenic activities increase the mercury loading to the environment. Although not all produced mercury is dissipated directly into the environment, only minor portions of the total production are stocked or recycled, and the rest of the mercury and its compounds is finally released in some way into atmosphere, surface waters and soil, or ends in landfills dumps, and refuse. Since mercury and its compounds are highly toxic, their presence in the environment constitutes potential impact on all living organisms, including man. The first serious consequence of industrial mercury discharges causing neurological disorder even death occurred in Minimata, Japan in 1953. Systematic studies showed that mercury poisoning is mainly found in fish-eating populations. However, various levels of mercury are also found in food other than fish. During the past several decades, research has been conducted on the evaluation of risks due to exposure to mercury and the development of control technologies for mercury emissions. In 1990, the Clean Air Act Amendments listed mercury, along with 10 other metallic species, as a hazardous air pollutant (HAP). This has further stimulated research for mercury control during the past several years. The impact of mercury on humans, sources of mercury in the environment, current mercury control strategies and the objective of this research are discussed in this section.

  17. UNEP Demonstrations of Mercury Emission Reduction at Two Coal-fired Power Plants in Russia

    Directory of Open Access Journals (Sweden)

    Jozewicz W.

    2013-04-01

    Full Text Available The United Nations Environment Programme (UNEP partnership area “Mercury releases from coal combustion” (The UNEP Coal Partnership has initiated demonstrations of mercury air emission reduction at two coal-fired power plants in Russia. The first project has modified the wet particulate matter (PM scrubber installed in Toliatti thermal plant to allow for addition of chemical reagents (oxidants into the closedloop liquid spray system. The addition of oxidant resulted in significant improvement of mercury capture from 20% total mercury removal (without the additive up to 60% removal (with the additive. It demonstrates the effectiveness of sorbent injection technologies in conjunction with an electrostatic precipitator (ESP. ESPs are installed at 60%, while wet PM scrubbers are installed at 30% of total coal-fired capacity in Russia. Thus, the two UNEP Coal Partnership projects address the majority of PM emission control configurations occurring in Russia.

  18. CONTROL OF MERCURY EMISSIONS FROM COAL-FIRED ELECTRIC UTILITY BOILERS: INTERIM REPORT

    Science.gov (United States)

    The report provides additional information on mercury (Hg) emissions control following the release of "Study of Hazardous Air Pollutant Emissions from Electric Utility Steam Generating Units--Final Report to Congress" in February 1998. Chapters 1-3 describe EPA's December 2000 de...

  19. CHARACTERIZATION OF THE FUGITIVE MERCURY EMISSIONS AT A CHLOR-ALKALI PLANT. OVERALL STUDY DESIGN

    Science.gov (United States)

    The paper discusses a detailed emissions measurement campaign that was conducted over a 9-day period within a mercury (Hg) cell chlor-alkali plant in the southeastern United States (U.S.). The principal focus of this study was to measure fugitive (non-ducted) airborne Hg emission...

  20. Radio-interferometric imaging of the subsurface emissions from the planet Mercury

    Science.gov (United States)

    Burns, J. O.; Zeilik, M.; Gisler, G. R.; Borovsky, J. E.; Baker, D. N.

    1987-01-01

    The distribution of total and polarized intensities from Mercury's subsurface layers have been mapped using VLA observations. The first detection of a hot pole along the Hermean equator is reported and modeled as black-body reradiation from preferential diurnal heating. These observations appear to rule out any internal sources of heat within Mercury. Polarized emission from the limb of the planet is also found, and is understood in terms of the dielectric properties of the Hermean surface.

  1. REDUCTION OF INHERENT MERCURY EMISSIONS IN PC COMBUSTION

    Energy Technology Data Exchange (ETDEWEB)

    John C. Kramlich; Rebecca N. Sliger

    2000-08-26

    Oxidized mercury has been shown to be more easily removed from power plant flue gas by existing air pollution control equipment (e.g., wet scrubbers) than elemental mercury. The factors that determine how mercury is converted to the oxidized form in practical systems are, however, unknown. The present research focuses on developing an elementary, homogeneous mechanism that describes the oxidation of mercury by chlorine species as it occurs in practical furnaces. The goal is to use this mechanism (1) as a component in an overall homogeneous/heterogeneous mechanism that describes mercury behavior, and (2) to suggest low cost/low impact means of promoting mercury oxidation in furnaces. The results suggest an important role for Hg+Cl {r_arrow} HgCl and HgCl + Cl {r_arrow} HgCl{sub 2}. Here, the Cl is derived by radical attack on HCl in the high-temperature environment. The results suggest that the oxidation occurs during the time that the gases cool to room temperature. The high Cl concentrations from the flame persist into the quench region and provide for the oxidation of Hg to HgCl{sub 2} under lower temperatures where the products are stable. Under this mechanism, no significant HgCl{sub 2} is actually present at the higher temperatures where oxidized mercury is often reported in the literature (e.g., 900 C). Instead, all oxidation occurs as these gases are quenched. The results suggest that means of promoting Cl concentrations in the furnace will increase oxidation.

  2. Mercury

    Science.gov (United States)

    ... build up in fish, shellfish, and animals that eat fish. The nervous system is sensitive to all forms of mercury. Exposure to high levels can damage the brain and kidneys. Pregnant women can pass the mercury in their bodies to their babies. It is important to protect your family from ...

  3. Mercury

    Science.gov (United States)

    ... has set a limit of 2 parts of mercury per billion parts of drinking water (2 ppb). The Food and Drug Administration (FDA) has set a maximum permissible level of 1 part of methylmercury in a million ... of 0.1 milligram of organic mercury per cubic meter of workplace air (0.1 ...

  4. Characterization, mapping, and mitigation of mercury vapour emissions from artisanal mining gold shops.

    Science.gov (United States)

    Cordy, Paul; Veiga, Marcello; Crawford, Ben; Garcia, Oseas; Gonzalez, Victor; Moraga, Daniel; Roeser, Monika; Wip, Dennis

    2013-08-01

    Artisanal miners sell their gold to shops that are usually located in the urban core, where the mercury-gold amalgam is burned to evaporate the mercury that was added during ore processing. People living and working near these gold shops are exposed to intermittent and extreme concentrations of mercury vapour. In the urban centres of Segovia, Colombia, and Andacollo, Chile, the average concentrations measured by mobile mercury vapour analyzer transects taken repeatedly over several weeks were 1.26 and 0.338μgm(-3), respectively. By World Health Organization standards, these towns are exposed to significant health hazard, and globally, the millions of miners, as well as non-miners who live near gold shops, are at serious risk of neurological and renal deficits. Measurements taken in Suriname, Ecuador and Peru reveal this to be a widespread phenomenon with unique regional variations and myriad attempts at remediation. Maps of average mercury concentrations show the spatial distribution of the hazard in relation to residential buildings and schools. Measurements from towers show the temporal variability of mercury concentrations, and suggest that large quantities of mercury are available for long-range atmospheric transport. Mercury mapping in Segovia in 2011 suggest a 10% reduction in airborne mercury concentrations over 2010, despite a 30% increase in gold production. This is attributable to the adoption of retorts by miners and regulations banning new processing centres to the rural periphery. This is the first full description of artisanal mining gold shop practices and of the character, quantity, and remediation of mercury emissions within urban mining centres. Copyright © 2013 Elsevier Inc. All rights reserved.

  5. Ancillary Benefits of Climate Policies for the Mitigation of Atmospheric Mercury Emissions

    Directory of Open Access Journals (Sweden)

    Rafaj P.

    2013-04-01

    Full Text Available This study provides an analysis of the impact of global climate policies on mercury emissions using the Greenhouse Gas and Air Pollution Interactions and Synergies (GAINS model in the time horizon up to 2050. The time evolution of mercury emissions is based on projections of energy consumption provided by the Prospective Outlook for the Long term Energy System (POLES model for a scenario without any global greenhouse gas mitigation efforts, and for a 2°C climate policy scenario, which assumes internationally coordinated action to mitigate climate change. Outcomes of the analysis are reported globally and for key world regions: EU-27, China, India and the US. The assessment takes into account current air pollution control legislation in each country. Scenario calculations for mercury emissions indicate significant scope for co-benefits made possible through climate policies. Atmospheric releases of mercury from anthropogenic sources under the global climate mitigation regime are reduced in 2050 by 45% when compared to the case without climate measures. Around one third of co-benefits for mercury emissions estimated world-wide in this study by 2050 are allocated to China. An annual Hg-abatement of about 800 tons is estimated for the coal combustion in power sector if the current air pollution legislation and climate policies are adopted in parallel.

  6. Trend analysis from 1970 to 2008 and model evaluation of EDGARv4 global gridded anthropogenic mercury emissions

    International Nuclear Information System (INIS)

    Muntean, Marilena; Janssens-Maenhout, Greet; Song, Shaojie; Selin, Noelle E.; Olivier, Jos G.J.; Guizzardi, Diego; Maas, Rob; Dentener, Frank

    2014-01-01

    The Emission Database for Global Atmospheric Research (EDGAR) provides a time-series of man-made emissions of greenhouse gases and short-lived atmospheric pollutants from 1970 to 2008. Mercury is included in EDGARv4.tox1, thereby enriching the spectrum of multi-pollutant sources in the database. With an average annual growth rate of 1.3% since 1970, EDGARv4 estimates that the global mercury emissions reached 1287 tonnes in 2008. Specifically, gaseous elemental mercury (GEM) (Hg 0 ) accounted for 72% of the global total emissions, while gaseous oxidised mercury (GOM) (Hg 2+ ) and particle bound mercury (PBM) (Hg-P) accounted for only 22% and 6%, respectively. The less reactive form, i.e., Hg 0 , has a long atmospheric residence time and can be transported long distances from the emission sources. The artisanal and small-scale gold production, accounted for approximately half of the global Hg 0 emissions in 2008 followed by combustion (29%), cement production (12%) and other metal industry (10%). Given the local-scale impacts of mercury, special attention was given to the spatial distribution showing the emission hot-spots on gridded 0.1° × 0.1° resolution maps using detailed proxy data. The comprehensive ex-post analysis of the mitigation of mercury emissions by end-of-pipe abatement measures in the power generation sector and technology changes in the chlor-alkali industry over four decades indicates reductions of 46% and 93%, respectively. Combined, the improved technologies and mitigation measures in these sectors accounted for 401.7 tonnes of avoided mercury emissions in 2008. A comparison shows that EDGARv4 anthropogenic emissions are nearly equivalent to the lower estimates of the United Nations Environment Programme (UNEP)'s mercury emissions inventory for 2005 for most sectors. An evaluation of the EDGARv4 global mercury emission inventory, including mercury speciation, was performed using the GEOS-Chem global 3-D mercury model. The model can

  7. 1997 Performance Testing of Multi-Metal Continuous Emissions Monitors

    Energy Technology Data Exchange (ETDEWEB)

    Sky +, Inc.

    1998-09-01

    Five prototype and two commercially available multi-metals continuous emissions monitors (CEMs) were tested in September 1997 at the Rotary Kiln Incinerator Simulator facility at the EPA National Risk Management Research Laboratory, Research Triangle Park, North Carolina. The seven CEMs were tested side by side in a long section of duct following the secondary combustion chamber of the RKIS. Two different concentrations of six toxic metals were introduced into the incinerator-approximately 15 and 75 µg/dscm of arsenic, beryllium, cadmium, chromium, lead, and mercury (We also tested for antimony but we are not reporting on it here because EPA recently dropped antimony from the list of metals addressed by the draft MACT rule). These concentrations were chosen to be close to emission standards in the draft MACT rule and the estimated Method Detection Limit (MDL) required of a CEM for regulatory compliance purposes. Results from this test show that no CEMs currently meet the performance specifications in the EPA draft MACT rule for hazardous waste incinerators. Only one of the CEMs tested was able to measure all six metals at the concentrations tested. Even so, the relative accuracy of this CEM varied between 35% and 100%, not 20% or less as required in the EPA performance specification. As a result, we conclude that no CEM is ready for long-term performance validation for compliance monitoring applications. Because sampling and measuring Hg is a recurring problem for multi-metal CEMs as well as Hg CEMs, we recommended that developers participate in a 1998 DOE-sponsored workshop to solve these and other common CEM measurement issues.

  8. LOCAL IMPACTS OF MERCURY EMISSIONS FROM THE MONTICELLO COAL FIRED POWER PLANT.

    Energy Technology Data Exchange (ETDEWEB)

    SULLIVAN, T.M.; ADAMS, J.; MILIAN, L.; SUBRAMANIAN, S.; FEAGIN, L.; WILLIAMS, J.; BOYD, A.

    2006-10-31

    The Clean Air Interstate Rule (CAIR) and the Clean Air Mercury Rule (CAMR) as currently proposed by the U.S. Environmental Protection Agency (EPA) when fully implemented will lead to reduction in mercury emissions from coal-fired power plants by 70 percent to fifteen tons per year by 2018. The EPA estimates that mercury deposition would be reduced 8 percent on average in the Eastern United States. The CAMR permits cap-and-trade approach that requires the nationwide emissions to meet the prescribed level, but do not require controls on each individual power plant. This has led to concerns that there may be hot-spots of mercury contamination near power plants. Partially because of this concern, many states including Pennsylvania have implemented, or are considering, state regulations that are stricter on mercury emissions than those in the CAMR. This study examined the possibility that coal-fired power plants act as local sources leading to mercury ''hot spots'', using two types of evidence. First, the world-wide literature was searched for reports of deposition around mercury sources, including coal-fired power plants. Second, soil samples from around two mid-sized U.S. coal-fired power plants were collected and analyzed for evidence of ''hot spots'' and for correlation with model predictions of deposition. The following summarizes our findings from published reports on the impacts of local deposition. In terms of excesses over background the following increments have been observed within a few km of the plant: (A) local soil concentration Hg increments of 30%-60%, (B) sediment increments of 18-30%, (C) wet deposition increments of 11-12%, and (D) fish Hg increments of about 5-6%, based on an empirical finding that fish concentrations are proportional to the square root of deposition. Important uncertainties include possible reductions of RGM to Hg(0) in power plant plumes and the role of water chemistry in the relationship

  9. Local Impacts of Mercury Emissions from the Three Pennsylvania Coal Fired Power Plants.

    Energy Technology Data Exchange (ETDEWEB)

    Sullivan,T.; Adams,J.; Bender, M.; Bu, C.; Piccolo, N.; Campbell, C.

    2008-02-01

    The Clean Air Interstate Rule (CAIR) and the Clean Air Mercury Rule (CAMR) as proposed by the U.S. Environmental Protection Agency (EPA) when fully implemented will lead to reduction in mercury emissions from coal-fired power plants by 70 percent to fifteen tons per year by 2018. The EPA estimates that mercury deposition would be reduced 8 percent on average in the Eastern United States. The CAMR permits cap-and-trade approach that requires the nationwide emissions to meet the prescribed level, but do not require controls on each individual power plant. This has led to concerns that there may be hot-spots of mercury contamination near power plants. Partially because of this concern, many states including Pennsylvania have implemented, or are considering, state regulations that are stricter on mercury emissions than those in the CAMR. This study examined the possibility that coal-fired power plants act as local sources leading to mercury 'hot spots'. Soil and oak leaf samples from around three large U.S. coal-fired power plants in Western Pennsylvania were collected and analyzed for evidence of 'hot spots'. These three plants (Conemaugh, Homer City, and Keystone) are separated by a total distance of approximately 30 miles. Each emits over 500 pounds of mercury per year which is well above average for mercury emissions from coal plants in the U.S. Soil and oak leaf sampling programs were performed around each power plant. Sampling rings one-mile apart were used with eight or nine locations on each ring. The prevailing winds in the region are from the west. For this reason, sampling was conducted out to 10 miles from the Conemaugh plant which is southeast of the others. The other plants were sampled to a distance of five miles. The objectives were to determine if local mercury hot spots exist, to determine if they could be attributed to deposition of coal-fired power plant emissions, and to determine if they correlated with wind patterns. The study

  10. Mapping the spatial distribution of global anthropogenic mercury atmospheric emission inventories

    Science.gov (United States)

    Wilson, Simon J.; Steenhuisen, Frits; Pacyna, Jozef M.; Pacyna, Elisabeth G.

    This paper describes the procedures employed to spatially distribute global inventories of anthropogenic emissions of mercury to the atmosphere, prepared by Pacyna, E.G., Pacyna, J.M., Steenhuisen, F., Wilson, S. [2006. Global anthropogenic mercury emission inventory for 2000. Atmospheric Environment, this issue, doi:10.1016/j.atmosenv.2006.03.041], and briefly discusses the results of this work. A new spatially distributed global emission inventory for the (nominal) year 2000, and a revised version of the 1995 inventory are presented. Emissions estimates for total mercury and major species groups are distributed within latitude/longitude-based grids with a resolution of 1×1 and 0.5×0.5°. A key component in the spatial distribution procedure is the use of population distribution as a surrogate parameter to distribute emissions from sources that cannot be accurately geographically located. In this connection, new gridded population datasets were prepared, based on the CEISIN GPW3 datasets (CIESIN, 2004. Gridded Population of the World (GPW), Version 3. Center for International Earth Science Information Network (CIESIN), Columbia University and Centro Internacional de Agricultura Tropical (CIAT). GPW3 data are available at http://beta.sedac.ciesin.columbia.edu/gpw/index.jsp). The spatially distributed emissions inventories and population datasets prepared in the course of this work are available on the Internet at www.amap.no/Resources/HgEmissions/

  11. Particulate-phase mercury emissions from biomass burning and impact on resulting deposition: a modelling assessment

    Science.gov (United States)

    Mercury (Hg) emissions from biomass burning (BB) are an important source of atmospheric Hg and a major factor driving the interannual variation of Hg concentrations in the troposphere. The greatest fraction of Hg from BB is released in the form of elemental Hg (Hg0(g)). However, ...

  12. PERFORMANCE AND COST OF MERCURY AND MULTIPOLLUTANT EMISSION CONTROL TECHNOLOGY APPLICATIONS ON ELECTRIC UTILITY BOILERS

    Science.gov (United States)

    The report presents estimates of the performance and cost of both powdered activated carbon (PAC) and multipollutant control technologies that may be useful in controlling mercury emissions. Based on currently available data, cost estimates for PAC injection range are 0.03-3.096 ...

  13. EMISSION TEST REPORT, OMSS FIELD TEST ON CARBON INJECTION FOR MERCURY CONTROL

    Science.gov (United States)

    The report discusses results of a parametric evaluation of powdered activated carbon for control of mercury (Hg) emission from a municipal waste cornbustor (MWC) equipped with a lime spray dryer absorber/fabric filter (SD/FF). The primary test objectives were to evaluate the effe...

  14. CHARACTERIZATION OF MERCURY EMISSIONS AT A CHLOR-ALKALI PLANT, VOLUME II. APPENDICES F-J

    Science.gov (United States)

    The report gives results of a characterization of mercury (Hg) emissions at a chlor-alkali plant. Up to 160 short tons (146 Mg) of Hg is consumed by the chlor-alkali industry each year. Very little quantitative information is currently available however, on the actual Hg losses f...

  15. Trend analysis from 1970 to 2008 and model evaluation of EDGARv4 global gridded anthropogenic mercury emissions.

    Science.gov (United States)

    Muntean, Marilena; Janssens-Maenhout, Greet; Song, Shaojie; Selin, Noelle E; Olivier, Jos G J; Guizzardi, Diego; Maas, Rob; Dentener, Frank

    2014-10-01

    The Emission Database for Global Atmospheric Research (EDGAR) provides a time-series of man-made emissions of greenhouse gases and short-lived atmospheric pollutants from 1970 to 2008. Mercury is included in EDGARv4.tox1, thereby enriching the spectrum of multi-pollutant sources in the database. With an average annual growth rate of 1.3% since 1970, EDGARv4 estimates that the global mercury emissions reached 1,287 tonnes in 2008. Specifically, gaseous elemental mercury (GEM) (Hg(0)) accounted for 72% of the global total emissions, while gaseous oxidised mercury (GOM) (Hg(2+)) and particle bound mercury (PBM) (Hg-P) accounted for only 22% and 6%, respectively. The less reactive form, i.e., Hg(0), has a long atmospheric residence time and can be transported long distances from the emission sources. The artisanal and small-scale gold production, accounted for approximately half of the global Hg(0) emissions in 2008 followed by combustion (29%), cement production (12%) and other metal industry (10%). Given the local-scale impacts of mercury, special attention was given to the spatial distribution showing the emission hot-spots on gridded 0.1°×0.1° resolution maps using detailed proxy data. The comprehensive ex-post analysis of the mitigation of mercury emissions by end-of-pipe abatement measures in the power generation sector and technology changes in the chlor-alkali industry over four decades indicates reductions of 46% and 93%, respectively. Combined, the improved technologies and mitigation measures in these sectors accounted for 401.7 tonnes of avoided mercury emissions in 2008. A comparison shows that EDGARv4 anthropogenic emissions are nearly equivalent to the lower estimates of the United Nations Environment Programme (UNEP)'s mercury emissions inventory for 2005 for most sectors. An evaluation of the EDGARv4 global mercury emission inventory, including mercury speciation, was performed using the GEOS-Chem global 3-D mercury model. The model can generally

  16. Emission and speciation of mercury from waste incinerators with mass distribution investigations

    International Nuclear Information System (INIS)

    Seo, Yong-Chil; Kim, Jeong-Hun; Pudasainee, Deepak; Yoon, Young-Sik; Jung, Seung Jae; Bhatta, Dhruba

    2010-01-01

    In this paper mercury emission and removal characteristics in municipal wastes incinerators (MWIs), hazardous waste incinerators (HWIs) and hospital medical and infectious waste incinerators (HMIWIs) with mercury mass distribution within the system are presented. Mercury speciation in flue gas at inlet and outlet of each air pollution control devices (APCDs) were sampled and analyzed by Ontario Hydro Method. Solid and liquid samples were analyzed by U.S. EPA method 7470A and 7471A, respectively. Cold vapor atomic absorption spectroscopy was used for analysis. On an average, Hg emission concentrations in flue gas from MWIs ranged 173.9 to 15.3 μg Sm -3 at inlet and 10.5 to 3.8 μg Sm -3 at outlet of APCDs respectively. Mercury removal efficiency ranged 50 to 95% in MWIs, 7.2 to 59.9% in HWIs as co-beneficial results of APCDs for removing other air pollutants like particulate matter, dioxin and acidic gases. In general, mercury in incineration facilities was mainly distributed in fly ash followed by flue gas and bottom ash. In MWIs 94.4 to 74% of Hg were distributed in fly ash. In HWIs with dry type APCDs, Hg removal was less and 70.6% of mercury was distributed in flue gas. The variation of Hg concentration, speciation and finally the distribution in the tested facilities was related to the non-uniform distribution of Hg in waste combined with variation in waste composition (especially Cl, S content), operating parameters, flue gas components, fly ash properties, operating conditions, APCDs configuration. Long term data incorporating more number of tests are required to better understand mercury behavior in such sources and to apply effective control measures. (author)

  17. Mercury sodium exospheric emission as a proxy for solar perturbations transit

    Science.gov (United States)

    Orsini, S.; Mangano, V.; Milillo, A.; Plainaki, C.; Mura, A.; Raines, J. M.; Laurenza, M.; De Angelis, E.; Rispoli, R.; Lazzarotto, F.; Aronica, A.

    2017-12-01

    The first evidence at Mercury of direct relation between ICME transit and Na exosphere dynamics is presented, suggesting that Na emission, observed from ground, could be a proxy of planetary space weather at Mercury. The link existing between the dayside exosphere Na patterns and the solar wind-magnetosphere-surface interactions is investigated. This goal is pursued by analyzing the Na intensity hourly images, as observed by the ground-based THEMIS solar telescope (Mangano et al., 2015*) during 10 selected periods between 2012 and 2013 (with seeing, σ 10.1016/j.pss.2015.04.001, 2015.

  18. Estimates of increased black carbon emissions from electrostatic precipitators during powdered activated carbon injection for mercury emissions control.

    Science.gov (United States)

    Clack, Herek L

    2012-07-03

    The behavior of mercury sorbents within electrostatic precipitators (ESPs) is not well-understood, despite a decade or more of full-scale testing. Recent laboratory results suggest that powdered activated carbon exhibits somewhat different collection behavior than fly ash in an ESP and particulate filters located at the outlet of ESPs have shown evidence of powdered activated carbon penetration during full-scale tests of sorbent injection for mercury emissions control. The present analysis considers a range of assumed differential ESP collection efficiencies for powdered activated carbon as compared to fly ash. Estimated emission rates of submicrometer powdered activated carbon are compared to estimated emission rates of particulate carbon on submicrometer fly ash, each corresponding to its respective collection efficiency. To the extent that any emitted powdered activated carbon exhibits size and optical characteristics similar to black carbon, such emissions could effectively constitute an increase in black carbon emissions from coal-based stationary power generation. The results reveal that even for the low injection rates associated with chemically impregnated carbons, submicrometer particulate carbon emissions can easily double if the submicrometer fraction of the native fly ash has a low carbon content. Increasing sorbent injection rates, larger collection efficiency differentials as compared to fly ash, and decreasing sorbent particle size all lead to increases in the estimated submicrometer particulate carbon emissions.

  19. 40 CFR Table 3 to Subpart Ddddd of... - Operating Limits for Boilers and Process Heaters With Mercury Emission Limits and Boilers and...

    Science.gov (United States)

    2010-07-01

    ... Process Heaters With Mercury Emission Limits and Boilers and Process Heaters That Choose To Comply With... Heaters With Mercury Emission Limits and Boilers and Process Heaters That Choose To Comply With the... operating limits: If you demonstrate compliance with applicable mercury and/or total selected metals...

  20. Architectural design of flue gas continuous emission monitoring system

    Science.gov (United States)

    Zhou, Hongfu; Jiang, Liangzhong; Tang, Yong; Yao, Xifan

    2008-10-01

    The paper presents the architectural design of flue gas continuous emission monitoring system, which uses computer, acquisition card and serial port communication card as hardware in the flue gas continuous emission monitoring system. In the CEMS, continuous emission monitoring system, it monitors dust in the flue gas, SO2, NOX, and some parameter on the flue gas emission, which includes mass flow, pressure, and temperature. For the software in the monitoring system, the research designs monitoring program in VC++, and realizes flue gas monitor with the architecture.

  1. Mercury Emissions Capture Efficiency with Activated Carbon Injection at a Russian Coal-Fired Thermal Power Plant

    Science.gov (United States)

    This EPA-led project, conducted in collaboration with UNEP, the Swedish Environmental Institute and various Russian Institutes, that demonstrates that the mercury emission control efficiencies of activated carbon injection technologies applied at a Russian power plant burning Rus...

  2. Continuation of periodic orbits in the Sun-Mercury elliptic restricted three-body problem

    Science.gov (United States)

    Peng, Hao; Bai, Xiaoli; Xu, Shijie

    2017-06-01

    Starting from resonant Halo orbits in the Circular Restricted Three-Body Problem (CRTBP), Multi-revolution Elliptic Halo (ME-Halo) orbits around L1 and L2 points in the Sun-Mercury Elliptic Restricted Three-Body Problem (ERTBP) are generated systematically. Three pairs of resonant parameters M5N2, M7N3 and M9N4 are tested. The first pair shows special features and is investigated in detail. Three separated characteristic curves of periodic orbit around each libration point are obtained, showing the eccentricity varies non-monotonically along these curves. The eccentricity of the Sun-Mercury system can be achieved by continuation method in just a few cases. The stability analysis shows that these orbits are all unstable and the complex instability occurs with certain parameters. This paper shows new periodic orbits in both the CRTBP and the ERTBP. Totally four periodic orbits with parameters M5N2 around each libration points are extracted in the Sun-Mercury ERTBP.

  3. Soil-Air Mercury Flux near a Large Industrial Emission Source before and after Closure (Flin Flon, Manitoba, Canada).

    Science.gov (United States)

    Eckley, Chris S; Blanchard, Pierrette; McLennan, Daniel; Mintz, Rachel; Sekela, Mark

    2015-08-18

    Prior to its closure, the base-metal smelter in Flin Flon, Manitoba, Canada was one of the North America's largest mercury (Hg) emission sources. Our project objective was to understand the exchange of Hg between the soil and the air before and after the smelter closure. Field and laboratory Hg flux measurements were conducted to identify the controlling variables and used for spatial and temporal scaling. Study results showed that deposition from the smelter resulted in the surrounding soil being enriched in Hg (up to 99 μg g(-1)) as well as other metals. During the period of smelter operation, air concentrations were elevated (30 ± 19 ng m(-3)), and the soil was a net Hg sink (daily flux: -3.8 ng m(-2) h(-1)). Following the smelter closure, air Hg(0) concentrations were reduced, and the soils had large emissions (daily flux: 108 ng m(-2) h(-1)). The annual scaling of soil Hg emissions following the smelter closure indicated that the landscape impacted by smelter deposition emitted or re-emitted almost 100 kg per year. Elevated soil Hg concentrations and emissions are predicted to continue for hundreds of years before background concentrations are re-established. Overall, the results indicate that legacy Hg deposition will continue to cycle in the environment long after point-source reductions.

  4. Mercury emission to the atmosphere from municipal solid waste landfills: A brief review

    Science.gov (United States)

    Tao, Zhengkai; Dai, Shijin; Chai, Xiaoli

    2017-12-01

    Municipal solid waste (MSW) landfill is regarded as an important emission source of atmospheric mercury (Hg), which is associated with potential health and environmental risks, as outlined by the Minamata Convention on Hg. This review presents the current state of knowledge with regards to landfill Hg sources, Hg levels in MSW and cover soils, Hg emission to the atmosphere, available Hg biogeochemical transformations, research methods for Hg emission, and important areas for future research. In addition, strategies for controlling landfill Hg emissions are considered, including reducing the Hg load in landfill and in situ controls. These approaches mainly focus on Hg source reduction, Hg recycling programs, public education, and in situ technology such as timely soil cover, vegetation, and end-of-pipe technology for controlling Hg emission from landfill gas.

  5. Removal of mercury in fixed-bed continuous upflow reactors by mercury-resistant bacteria and effect of sodium chloride on their performance

    Digital Repository Service at National Institute of Oceanography (India)

    De; Leonhauser, J.; Vardanyan, L

    : De J, Leonha¨user J, Vardanyan L. Removal of mercury in fixed-bed continuous upflow reactors by mercury-resistant bacteria and effect of sodium chloride on their performance, QScience Connect 2014:17 http://dx.doi.org/10.5339/connect.2014.17 http... for medium; 2, channel for wastewater inflow; 3, channel for wastewater outflow; 4, medium; 5, pump for medium; 6, pump for wastewater; 7, bubble trap. Page 4 of 9 De, Leonha¨user, Vardanyan. QScience Connect 2014:17 supplemented with 4 g/l glucose) were...

  6. Mercury in coal and the impact of coal quality on mercury emissions from combustion systems

    International Nuclear Information System (INIS)

    Kolker, Allan; Senior, Constance L.; Quick, Jeffrey C.

    2006-01-01

    The proportion of Hg in coal feedstock that is emitted by stack gases of utility power stations is a complex function of coal chemistry and properties, combustion conditions, and the positioning and type of air pollution control devices employed. Mercury in bituminous coal is found primarily within Fe-sulfides, whereas lower rank coal tends to have a greater proportion of organic-bound Hg. Preparation of bituminous coal to reduce S generally reduces input Hg relative to in-ground concentrations, but the amount of this reduction varies according to the fraction of Hg in sulfides and the efficiency of sulfide removal. The mode of occurrence of Hg in coal does not directly affect the speciation of Hg in the combustion flue gas. However, other constituents in the coal, notably Cl and S, and the combustion characteristics of the coal, influence the species of Hg that are formed in the flue gas and enter air pollution control devices. The formation of gaseous oxidized Hg or particulate-bound Hg occurs post-combustion; these forms of Hg can be in part captured in the air pollution control devices that exist on coal-fired boilers, without modification. For a given coal type, the capture efficiency of Hg by pollution control systems varies according to type of device and the conditions of its deployment. For bituminous coal, on average, more than 60% of Hg in flue gas is captured by fabric filter (FF) and flue-gas desulfurization (FGD) systems. Key variables affecting performance for Hg control include Cl and S content of the coal, the positioning (hot side vs. cold side) of the system, and the amount of unburned C in coal ash. Knowledge of coal quality parameters and their effect on the performance of air pollution control devices allows optimization of Hg capture co-benefit

  7. MercNet: A national monitoring network to assess responses to changing mercury emissions in the United States

    Science.gov (United States)

    Schmeltz, D.; Evers, D.C.; Driscoll, C.T.; Artz, R.; Cohen, M.; Gay, D.; Haeuber, R.; Krabbenhoft, D.P.; Mason, R.; Morris, K.; Wiener, J.G.

    2011-01-01

    A partnership of federal and state agencies, tribes, industry, and scientists from academic research and environmental organizations is establishing a national, policy-relevant mercury monitoring network, called MercNet, to address key questions concerning changes in anthropogenic mercury emissions and deposition, associated linkages to ecosystem effects, and recovery from mercury contamination. This network would quantify mercury in the atmosphere, land, water, and biota in terrestrial, freshwater, and coastal ecosystems to provide a national scientific capability for evaluating the benefits and effectiveness of emission controls. Program development began with two workshops, convened to establish network goals, to select key indicators for monitoring, to propose a geographic network of monitoring sites, and to design a monitoring plan. MercNet relies strongly on multi-institutional partnerships to secure the capabilities and comprehensive data that are needed to develop, calibrate, and refine predictive mercury models and to guide effective management. Ongoing collaborative efforts include the: (1) development of regional multi-media databases on mercury in the Laurentian Great Lakes, northeastern United States, and eastern Canada; (2) syntheses and reporting of these data for the scientific and policy communities; and (3) evaluation of potential monitoring sites. The MercNet approach could be applied to the development of other monitoring programs, such as emerging efforts to monitor and assess global mercury emission controls. ?? 2011 Springer Science+Business Media, LLC (outside the USA).

  8. Technology demonstration for reducing mercury emissions from small-scale gold refining facilities.

    Energy Technology Data Exchange (ETDEWEB)

    Habegger, L. J.; Fernandez, L. E.; Engle, M.; Bailey, J. L.; Peterson, D. P.; MacDonell, M. M.; U.S. Environmental Protection Agency

    2008-06-30

    Gold that is brought from artisanal and small-scale gold mining areas to gold shops for processing and sale typically contains 5-40% mercury. The uncontrolled removal of the residual mercury in gold shops by using high-temperature evaporation can be a significant source of mercury emissions in urban areas where the shops are located. Emissions from gold shop hoods during a burn can exceed 1,000 mg/m{sup 3}. Because the saturation concentration of mercury vapor at operating temperatures at the hood exhaust is less than 100 mg/m{sup 3}, the dominant component of the exhaust is in the form of aerosol or liquid particles. The U.S. Environmental Protection Agency (EPA), with technical support from Argonne National Laboratory (Argonne), has completed a project to design and test a technology to remove the dominant aerosol component in the emissions from gold shops. The objective was to demonstrate a technology that could be manufactured at low cost and by using locally available materials and manufacturing capabilities. Six prototypes designed by Argonne were locally manufactured, installed, and tested in gold shops in Itaituba and Creporizao, Brazil. The initial prototype design incorporated a pebble bed as the media for collecting the mercury aerosols, and a mercury collection efficiency of over 90% was demonstrated. Though achieving high efficiencies, the initial prototype was determined to have practical disadvantages such as excessive weight, a somewhat complex construction, and high costs (>US$1,000). To further simplify the construction, operation, and associated costs, a second prototype design was developed in which the pebble bed was replaced with slotted steel baffle plates. The system was designed to have flexibility for installation in various hood configurations. The second prototype with the baffle plate design was installed and tested in several different hood/exhaust systems to determine the optimal installation configuration. The significance of

  9. Continuous-emission monitoring: Proposed acid-rain rule

    International Nuclear Information System (INIS)

    1991-12-01

    The U.S. Environmental Protection Agency (EPA) has proposed four rules containing the core acid rain requirements: the Permits Rule (40 CFR Part 72), the Allowances Rule (40 CFR Part 73), the Continuous Emission Monitoring Rule (40 CFR Part 75), and the Excess Emissions Rule (40 CRF Part 77). EPA will also propose additional rules at a future date. These rules will include requirements for facilities that elect to opt into the Acid Rain Program (40 CFR Part 74) and for the nitrogen oxide (NOx) control program (40 CFR Part 76). This fact sheet summarizes the key components of the proposed Continuous Emission Monitoring Rule (40 CFR Part 75)

  10. An assessment of mercury emissions and health risks from a coal-fired power plant

    Energy Technology Data Exchange (ETDEWEB)

    Fthenakis, V.M.; Lipfert, F.; Moskowitz, P. [Brookhaven National Lab., Upton, NY (United States). Analytical Sciences Div.

    1994-12-01

    Title 3 of the 1990 Clean Air Act Amendments (CAAA) mandated that the US Environmental Protection Agency (EPA) evaluate the need to regulate mercury emissions from electric utilities. In support of this forthcoming regulatory analysis the U.S. DOE, sponsored a risk assessment project at Brookhaven (BNL) to evaluate methylmercury (MeHg) hazards independently. In the US MeHg is the predominant way of exposure to mercury originated in the atmosphere. In the BNL study, health risks to adults resulting from Hg emissions from a hypothetical 1,000 MW coal-fired power plant were estimated using probabilistic risk assessment techniques. This study showed that the effects of emissions of a single power plant may double the background exposures to MeHg resulting from consuming fish obtained from a localized area near the power plant. Even at these more elevated exposure levels, the attributable incidence in mild neurological symptoms was estimated to be quite small, especially when compared with the estimated background incidence in the population. The current paper summarizes the basic conclusions of this assessment and highlights issues dealing with emissions control and environmental transport.

  11. Trends in anthropogenic mercury emissions estimated for South Africa during 2000-2006

    Energy Technology Data Exchange (ETDEWEB)

    Masekoameng, K.E.; Leaner, J.; Dabrowski, J. [CSIR, Pretoria (South Africa)

    2010-08-15

    Recent studies suggest an increase in mercury (Hg) emissions to the global environment, particularly as a result of anthropogenic activities. This has prompted many countries to complete Hg emission inventories, based on country-specific Hg sources. In this study, information on annual coal consumption and Hg-containing commodities produced in South Africa, was used to estimate Hg emissions during 2000-2006. Based on the information, the UNEP toolkit was used to estimate the amount of Hg released to air and general waste from each activity; using South Africa specific and toolkit based emission factors. In both atmospheric and solid waste releases, coal-fired power plants were estimated to be the largest contributors of Hg emissions, viz. 27.1 to 38.9 tonnes y{sup -1} in air, and 5.8 to 7.4 tonnes y{sup -1} in waste. Cement production was estimated to be the second largest atmospheric Hg emission contributor (2.2-3.9 tonnes y{sup -1}), while coal gasification was estimated to be the second largest Hg contributor in terms of general waste releases (2.9-4.2 tonnes y{sup -1}). Overall, there was an increase in total atmospheric Hg emissions from all activities, estimated at ca. 34 tonnes in 2000, to 50 tonnes in 2006, with some fluctuations between the years. Similarly, the total Hg emissions released to general waste was estimated to be 9 tonnes in 2000, with an increase to 12 tonnes in 2006.

  12. Emission-dominated gas exchange of elemental mercury vapor over natural surfaces in China

    Directory of Open Access Journals (Sweden)

    X. Wang

    2016-09-01

    Full Text Available Mercury (Hg emission from natural surfaces plays an important role in global Hg cycling. The present estimate of global natural emission has large uncertainty and remains unverified against field data, particularly for terrestrial surfaces. In this study, a mechanistic model is developed for estimating the emission of elemental mercury vapor (Hg0 from natural surfaces in China. The development implements recent advancements in the understanding of air–soil and air–foliage exchange of Hg0 and redox chemistry in soil and on surfaces, incorporates the effects of soil characteristics and land use changes by agricultural activities, and is examined through a systematic set of sensitivity simulations. Using the model, the net exchange of Hg0 between the atmosphere and natural surfaces of mainland China is estimated to be 465.1 Mg yr−1, including 565.5 Mg yr−1 from soil surfaces, 9.0 Mg yr−1 from water bodies, and −100.4 Mg yr−1 from vegetation. The air–surface exchange is strongly dependent on the land use and meteorology, with 9 % of net emission from forest ecosystems; 50 % from shrubland, savanna, and grassland; 33 % from cropland; and 8 % from other land uses. Given the large agricultural land area in China, farming activities play an important role on the air–surface exchange over farmland. Particularly, rice field shift from a net sink (3.3 Mg uptake during April–October (rice planting to a net source when the farmland is not flooded (November–March. Summing up the emission from each land use, more than half of the total emission occurs in summer (51 %, followed by spring (28 %, autumn (13 %, and winter (8 %. Model verification is accomplished using observational data of air–soil/air–water fluxes and Hg deposition through litterfall for forest ecosystems in China and Monte Carlo simulations. In contrast to the earlier estimate by Shetty et al. (2008 that reported large emission from

  13. Economic evaluation of health benefits of mercury emission controls for China and the neighboring countries in East Asia

    International Nuclear Information System (INIS)

    Zhang, Wei; Zhen, Gengchong; Chen, Long; Wang, Huanhuan; Li, Ying; Ye, Xuejie; Tong, Yindong; Zhu, Yan; Wang, Xuejun

    2017-01-01

    Globally, coal-fired power plant (CFPP) is a major source of mercury. China is developing its first National Implementation Plan on Mercury Control, which priorities the control of emissions from CFPPs. While social benefits play an important role in designing environmental policies in China, the benefits associated with mercury control are not yet understood, mainly due to the scientific challenges to trace mercury's emissions-to-impacts path. This study evaluates the benefits of mercury reductions in China's CFPPs for China and its three neighboring countries in East Asia. Four policy scenarios are analyzed following the policies-to-impacts path, which links a global atmospheric model to health benefit analysis models to estimate the economic gains from avoided mercury-related adverse health outcomes under each scenario, and take into account key uncertainties in the path. Under the most stringent scenario, the benefits of mercury reduction by 2030 are projected to be $432 billion (95% CI: $166–941 billion), with the benefits for China and the neighboring countries accounting for 96% and 4% of the total benefits, respectively. Policy scenario analysis indicates that coal washing generates the greatest benefits in the near term, whereas upgrading air pollution control devices maximizes health benefits in the long term. - Highlights: • Benefits of mercury controls for China and neighboring countries are analyzed. • Policy analysis shows that coal washing generates the largest benefits in near term. • Upgrading air pollution control devices maximizes health benefits in long term. • For mercury controls, local policies contribute most to local benefits.

  14. Study on emission of hazardous trace elements in a 350 MW coal-fired power plant. Part 1. Mercury.

    Science.gov (United States)

    Zhao, Shilin; Duan, Yufeng; Chen, Lei; Li, Yaning; Yao, Ting; Liu, Shuai; Liu, Meng; Lu, Jianhong

    2017-10-01

    Hazardous trace elements (HTEs), especially mercury, emitted from coal-fired power plants had caused widespread concern worldwide. Field test on mercury emissions at three different loads (100%, 85%, 68% output) using different types of coal was conducted in a 350 MW pulverized coal combustion power plant equipped with selective catalytic reduction (SCR), electrostatic precipitator and fabric filter (ESP + FF), and wet flue gas desulfurization (WFGD). The Ontario Hydro Method was used for simultaneous flue gas mercury sampling for mercury at the inlet and outlet of each of the air pollutant control device (APCD). Results showed that mercury mass balance rates of the system or each APCD were in the range of 70%-130%. Mercury was mainly distributed in the flue gas, followed by ESP + FF ash, WFGD wastewater, and slag. Oxidized mercury (Hg 2+ ) was the main form of mercury form in the flue gas emitted to the atmosphere, which accounted for 57.64%-61.87% of total mercury. SCR was favorable for elemental mercury (Hg 0 ) removal, with oxidation efficiency of 50.13%-67.68%. ESP + FF had high particle-bound mercury (Hg p ) capture efficiency, at 99.95%-99.97%. Overall removal efficiency of mercury by the existing APCDs was 58.78%-73.32%. Addition of halogens or oxidants for Hg 0 conversion, and inhibitors for Hg 0 re-emission, plus the installation of a wet electrostatic precipitator (WESP) was a good way to improve the overall removal efficiency of mercury in the power plants. Mercury emission factor determined in this study was from 0.92 to 1.17 g/10 12 J. Mercury concentration in the emitted flue gas was much less than the regulatory limit of 30 μg/m 3 . Contamination of mercury in desulfurization wastewater should be given enough focus. Copyright © 2017. Published by Elsevier Ltd.

  15. Controls on boreal peat combustion and resulting emissions of carbon and mercury

    Science.gov (United States)

    Kohlenberg, Andrew J.; Turetsky, Merritt R.; Thompson, Dan K.; Branfireun, Brian A.; Mitchell, Carl P. J.

    2018-03-01

    Warming in the boreal forest region has already led to changes in the fire regime. This may result in increasing fire frequency or severity in peatlands, which could cause these ecosystems to shift from a net sink of carbon (C) to a net source of C to the atmosphere. Similar to C cycling, peatlands serve as a net sink for mercury (Hg), which binds strongly to organic matter and accumulates in peat over time. This stored Hg is also susceptible to re-release to the atmosphere during peat fires. Here we investigate the physical properties that influence depth of burn in experimental peat columns and the resulting emissions of CO, CO2, CH4, and gaseous and particulate Hg. As expected, bulk density and soil moisture content were important controls on depth of burn, CO2 emissions, and CO emissions. However, our results show that CH4 and Hg emissions are insensitive to combustion temperature or fuel moisture content. Emissions during the burning of peat, across a wide range of moisture conditions, were associated with low particulate Hg and high gaseous Hg release. Due to strong correlations between total Hg and CO emissions and because high Hg emissions occurred despite incomplete combustion of total C, our results suggest that Hg release during peat burning is governed by the thermodynamics of Hg reduction more so than by the release of Hg associated with peat combustion. Our measured emissions ratios, particularly for CH4:CO2, are higher than values typically used in the upscaling of boreal forest or peatland fire emissions. These emission ratios have important implications not only for our understanding of smouldering chemistry, but also for potential influences of peat fires on the Earth’s climate system.

  16. Mercury emissions inventory for 2014 in Costa Rica using the PNUMA Toolkit to a N2 level

    Directory of Open Access Journals (Sweden)

    Julio César Murillo-Hernández

    2017-12-01

    Full Text Available The Minamata Convention was signed in October 2013 to protect human health and the environment from releases and anthropogenic emissions of elemental mercury and compounds containing this element.  When Costa Rica ratified this instrument, the country committed to develop and keep updated an inventory of emissions from the relevant sources of mercury. In the present work, the tool proposed by UNEP was used to generate the first mercury inventory at the N2 level of the country, which considers releases of mercury in air, water, soil, product and waste matrices. Taking 2014 as the reference year, the estimated mercury emission for Costa Rica was recorded at 5 052 kg, with an uncertainty interval between 2 675 kg and 10 525 kg; and the most important sectors in terms of the total emission were the extraction of gold with amalgamation (42 %, informal burning of waste (15 % and use of dental amalgams (10 %. The most impacted matrices were air (29 %, water (28 % and soil (21 %, respectively.

  17. Estimation of mercury emissions from forest fires, lakes, regional and local sources using measurements in Milwaukee and an inverse method

    Directory of Open Access Journals (Sweden)

    B. de Foy

    2012-10-01

    Full Text Available Gaseous elemental mercury is a global pollutant that can lead to serious health concerns via deposition to the biosphere and bio-accumulation in the food chain. Hourly measurements between June 2004 and May 2005 in an urban site (Milwaukee, WI show elevated levels of mercury in the atmosphere with numerous short-lived peaks as well as longer-lived episodes. The measurements are analyzed with an inverse model to obtain information about mercury emissions. The model is based on high resolution meteorological simulations (WRF, hourly back-trajectories (WRF-FLEXPART and a chemical transport model (CAMx. The hybrid formulation combining back-trajectories and Eulerian simulations is used to identify potential source regions as well as the impacts of forest fires and lake surface emissions. Uncertainty bounds are estimated using a bootstrap method on the inversions. Comparison with the US Environmental Protection Agency's National Emission Inventory (NEI and Toxic Release Inventory (TRI shows that emissions from coal-fired power plants are properly characterized, but emissions from local urban sources, waste incineration and metal processing could be significantly under-estimated. Emissions from the lake surface and from forest fires were found to have significant impacts on mercury levels in Milwaukee, and to be underestimated by a factor of two or more.

  18. Estimation of mercury emissions from forest fires, lakes, regional and local sources using measurements in Milwaukee and an inverse method

    Science.gov (United States)

    de Foy, B.; Wiedinmyer, C.; Schauer, J. J.

    2012-10-01

    Gaseous elemental mercury is a global pollutant that can lead to serious health concerns via deposition to the biosphere and bio-accumulation in the food chain. Hourly measurements between June 2004 and May 2005 in an urban site (Milwaukee, WI) show elevated levels of mercury in the atmosphere with numerous short-lived peaks as well as longer-lived episodes. The measurements are analyzed with an inverse model to obtain information about mercury emissions. The model is based on high resolution meteorological simulations (WRF), hourly back-trajectories (WRF-FLEXPART) and a chemical transport model (CAMx). The hybrid formulation combining back-trajectories and Eulerian simulations is used to identify potential source regions as well as the impacts of forest fires and lake surface emissions. Uncertainty bounds are estimated using a bootstrap method on the inversions. Comparison with the US Environmental Protection Agency's National Emission Inventory (NEI) and Toxic Release Inventory (TRI) shows that emissions from coal-fired power plants are properly characterized, but emissions from local urban sources, waste incineration and metal processing could be significantly under-estimated. Emissions from the lake surface and from forest fires were found to have significant impacts on mercury levels in Milwaukee, and to be underestimated by a factor of two or more.

  19. Updated atmospheric speciated mercury emissions from iron and steel production in China during 2000-2015

    Science.gov (United States)

    Wu, Qingru; Gao, Wei; Wang, Shuxiao; Hao, Jiming

    2017-09-01

    Iron and steel production (ISP) is one of the significant atmospheric Hg emission sources in China. Atmospheric mercury (Hg) emissions from ISP during 2000-2015 were estimated by using a technology-based emission factor method. To support the application of this method, databases of Hg concentrations in raw materials, technology development trends, and Hg removal efficiencies of air pollution control devices (APCDs) were constructed through national sampling and literature review. Hg input to ISP increased from 21.6 t in 2000 to 94.5 t in 2015. In the various types of raw materials, coking coal and iron concentrates contributed 35-46 and 25-32 % of the total Hg input. Atmospheric Hg emissions from ISP increased from 11.5 t in 2000 to 32.7 t in 2015 with a peak of 35.6 t in 2013. Pollution control promoted the increase in average Hg removal efficiency, from 47 % in 2000 to 65 % in 2015. During the study period, sinter/pellet plants and blast furnaces were the largest two emission processes. However, emissions from roasting plants and coke ovens cannot be ignored, which accounted for 22-34 % of ISP's emissions. Overall, Hg speciation shifted from 50/44/6 (gaseous elemental Hg (Hg0)/gaseous oxidized Hg (HgII)/particulate-bound Hg (Hgp)) in 2000 to 40/59/1 in 2015, which indicated a higher proportion of Hg deposition around the emission points. Future emissions of ISP were expected to decrease based on the comprehensive consideration crude-steel production, steel scrap utilization, energy saving, and pollution control measures.

  20. Observed decrease in atmospheric mercury explained by global decline in anthropogenic emissions

    Science.gov (United States)

    Yanxu Zhang,; Daniel J. Jacob,; Hannah M. Horowitz,; Long Chen,; Helen M. Amos,; Krabbenhoft, David P.; Franz Slemr,; Vincent L. St. Louis,; Elsie M. Sunderland,

    2015-01-01

    Observations of elemental mercury (Hg0) at sites in North America and Europe show large decreases (∼1–2% y−1) from 1990 to present. Observations in background northern hemisphere air, including Mauna Loa Observatory (Hawaii) and CARIBIC (Civil Aircraft for the Regular Investigation of the atmosphere Based on an Instrument Container) aircraft flights, show weaker decreases (inventories indicating flat or increasing emissions over that period. However, the inventories have three major flaws: (i) they do not account for the decline in atmospheric release of Hg from commercial products; (ii) they are biased in their estimate of artisanal and small-scale gold mining emissions; and (iii) they do not properly account for the change in Hg0/HgII speciation of emissions from coal-fired utilities after implementation of emission controls targeted at SO2 and NOx. We construct an improved global emission inventory for the period 1990 to 2010 accounting for the above factors and find a 20% decrease in total Hg emissions and a 30% decrease in anthropogenic Hg0 emissions, with much larger decreases in North America and Europe offsetting the effect of increasing emissions in Asia. Implementation of our inventory in a global 3D atmospheric Hg simulation [GEOS-Chem (Goddard Earth Observing System-Chemistry)] coupled to land and ocean reservoirs reproduces the observed large-scale trends in atmospheric Hg0 concentrations and in HgII wet deposition. The large trends observed in North America and Europe reflect the phase-out of Hg from commercial products as well as the cobenefit from SO2 and NOx emission controls on coal-fired utilities.

  1. Updated atmospheric speciated mercury emissions from iron and steel production in China during 2000–2015

    Directory of Open Access Journals (Sweden)

    Q. Wu

    2017-09-01

    Full Text Available Iron and steel production (ISP is one of the significant atmospheric Hg emission sources in China. Atmospheric mercury (Hg emissions from ISP during 2000–2015 were estimated by using a technology-based emission factor method. To support the application of this method, databases of Hg concentrations in raw materials, technology development trends, and Hg removal efficiencies of air pollution control devices (APCDs were constructed through national sampling and literature review. Hg input to ISP increased from 21.6 t in 2000 to 94.5 t in 2015. In the various types of raw materials, coking coal and iron concentrates contributed 35–46 and 25–32 % of the total Hg input. Atmospheric Hg emissions from ISP increased from 11.5 t in 2000 to 32.7 t in 2015 with a peak of 35.6 t in 2013. Pollution control promoted the increase in average Hg removal efficiency, from 47 % in 2000 to 65 % in 2015. During the study period, sinter/pellet plants and blast furnaces were the largest two emission processes. However, emissions from roasting plants and coke ovens cannot be ignored, which accounted for 22–34 % of ISP's emissions. Overall, Hg speciation shifted from 50/44/6 (gaseous elemental Hg (Hg0/gaseous oxidized Hg (HgII/particulate-bound Hg (Hgp in 2000 to 40/59/1 in 2015, which indicated a higher proportion of Hg deposition around the emission points. Future emissions of ISP were expected to decrease based on the comprehensive consideration crude-steel production, steel scrap utilization, energy saving, and pollution control measures.

  2. Mercury's Exosphere During MESSENGER's Second Flyby: Detection of Magnesium and Distinct Distributions of Neutral Species

    Science.gov (United States)

    McClintock, William E.; Vervack, Ronald J., Jr.; Bradley, E. Todd; Killen, Rosemary M.; Mouawad, Nelly; Sprague, Ann L.; Burger, Matthew H.; Solomon, Sean C.; Izenberg, Noam R.

    2009-01-01

    During MESSENGER's second Mercury flyby, the Mercury Atmospheric and Surface Composition Spectrometer observed emission from Mercury's neutral exosphere. These observations include the first detection of emission from magnesium. Differing spatial distributions for sodium, calcium, and magnesium were revealed by observations beginning in Mercury's tail region, approximately 8 Mercury radii anti-sunward of the planet, continuing past the nightside, and ending near the dawn terminator. Analysis of these observations, supplemented by observations during the first Mercury flyby as well as those by other MESSENGER instruments, suggests that the distinct spatial distributions arise from a combination of differences in source, transfer, and loss processes.

  3. Study on the reduction of atmospheric mercury emissions from mine waste enriched soils through native grass cover in the Mt. Amiata region of Italy

    International Nuclear Information System (INIS)

    Fantozzi, L.; Ferrara, R.; Dini, F.; Tamburello, L.; Pirrone, N.; Sprovieri, F.

    2013-01-01

    Atmospheric mercury emissions from mine-waste enriched soils were measured in order to compare the mercury fluxes of bare soils with those from other soils covered by native grasses. Our research was conducted near Mt. Amiata in central Italy, an area that was one of the largest and most productive mining centers in Europe up into the 1980s. To determine in situ mercury emissions, we used a Plexiglas flux chamber connected to a portable mercury analyzer (Lumex RA-915+). This allowed us to detect, in real time, the mercury vapor in the air, and to correlate this with the meteorological parameters that we examined (solar radiation, soil temperature, and humidity). The highest mercury flux values (8000 ng m −2 h −1 ) were observed on bare soils during the hours of maximum insulation, while lower values (250 ng m −2 h −1 ) were observed on soils covered by native grasses. Our results indicate that two main environmental variables affect mercury emission: solar radiation intensity and soil temperature. The presence of native vegetation, which can shield soil surfaces from incident light, reduced mercury emissions, a result that we attribute to a drop in the efficiency of mercury photoreduction processes rather than to decreases in soil temperature. This finding is consistent with decreases in mercury flux values down to 3500 ng m −2 h −1 , which occurred under cloudy conditions despite high soil temperatures. Moreover, when the soil temperature was 28 °C and the vegetation was removed from the experimental site, mercury emissions increased almost four-fold. This increase occurred almost immediately after the grasses were cut, and was approximately eight-fold after 20 h. Thus, this study demonstrates that enhancing wild vegetation cover could be an inexpensive and effective approach in fostering a natural, self-renewing reduction of mercury emissions from mercury-contaminated soils. -- Highlights: ► Mercury air/surface exchange from grass covered soil is

  4. MERCURY EMISSIONS FROM COAL FIRED POWER PLANTS LOCAL IMPACTS ON HUMAN HEALTH RISK.

    Energy Technology Data Exchange (ETDEWEB)

    SULLIVAN, T.M.; BOWERMAN, B.; ADAMS, J.; LIPFERT, F.; MORRIS, S.M.; BANDO, A.; PENA, R.; BLAKE, R.

    2005-12-01

    A thorough quantitative understanding of the processes of mercury emissions, deposition, and translocation through the food chain is currently not available. Complex atmospheric chemistry and dispersion models are required to predict concentration and deposition contributions, and aquatic process models are required to predict effects on fish. However, there are uncertainties in all of these predictions. Therefore, the most reliable method of understanding impacts of coal-fired power plants on Hg deposition is from empirical data. A review of the literature on mercury deposition around sources including coal-fired power plants found studies covering local mercury concentrations in soil, vegetation, and animals (fish and cows). There is strong evidence of enhanced local deposition within 3 km of the chlor-alkali plants, with elevated soil concentrations and estimated deposition rates of 10 times background. For coal-fired power plants, the data show that atmospheric deposition of Hg may be slightly enhanced. On the scale of a few km, modeling suggests that wet deposition may be increased by a factor of two or three over background. The measured data suggest lower increases of 15% or less. The effects of coal-fired plants seem to be less than 10% of total deposition on a national scale, based on emissions and global modeling. The following summarizes our findings from published reports on the impacts of local deposition. In terms of excesses over background the following increments have been observed within a few km of the plant: (1) local soil concentration Hg increments of 30%-60%, (2) sediment increments of 18-30%, (3) wet deposition increments of 11-12%, and (4) fish Hg increments of about 5-6%, based on an empirical finding that fish concentrations are proportional to the square root of deposition. Important uncertainties include possible reductions of RGM to Hg{sub 0} in power plant plumes and the role of water chemistry in the relationship between Hg

  5. Radiative forcing associated with particulate carbon emissions resulting from the use of mercury control technology.

    Science.gov (United States)

    Lin, Guangxing; Penner, Joyce E; Clack, Herek L

    2014-09-02

    Injection of powdered activated carbon (PAC) adsorbents into the flue gas of coal fired power plants with electrostatic precipitators (ESPs) is the most mature technology to control mercury emissions for coal combustion. However, the PAC itself can penetrate ESPs to emit into the atmosphere. These emitted PACs have similar size and optical properties to submicron black carbon (BC) and thus could increase BC radiative forcing unintentionally. The present paper estimates, for the first time, the potential emission of PAC together with their climate forcing. The global average maximum potential emissions of PAC is 98.4 Gg/yr for the year 2030, arising from the assumed adoption of the maximum potential PAC injection technology, the minimum collection efficiency, and the maximum PAC injection rate. These emissions cause a global warming of 2.10 mW m(-2) at the top of atmosphere and a cooling of -2.96 mW m(-2) at the surface. This warming represents about 2% of the warming that is caused by BC from direct fossil fuel burning and 0.86% of the warming associated with CO2 emissions from coal burning in power plants. Its warming is 8 times more efficient than the emitted CO2 as measured by the 20-year-integrated radiative forcing per unit of carbon input (the 20-year Global Warming Potential).

  6. Laboratory testing of a continuous emissions monitor for hydrochloric acid.

    Science.gov (United States)

    Dene, Chuck; Pisano, John T; Durbin, Thomas D; Bumiller, Kurt; Crabbe, Keith; Muzio, Lawrence J

    2014-06-01

    Continuous monitoring of exhaust flue gas has become a common practice in power plants in response to Federal Mercury and Air Toxics Standards (MATS) standards. Under the current rules, hydrochloric acid (HCl) is not continuously measured at most plants; however, MATS standards have been proposed for HCl, and tunable diode laser (TDL) absorption spectroscopy is one method that can be used to measure HCl continuously. The focus of this work is on the evaluation and verification of the operation performance of an HCL TDL over a range of real-world operating environments. The testing was conducted at the University of California at Riverside (UCR) spectroscopy evaluation laboratory. Laboratory tests were conducted at three separate temperatures, 25 degrees C, 100 degrees C, and 200 degrees C, and two distinct moisture levels for the enhanced temperatures, 0%, (2 tests) and 4%, over a concentration range from 0 ppmv to 25 ppmv-m at each of the elevated temperatures. The results showed good instrument accuracy as afunction of changing temperature and moisture. Data analysis showed that the average percentage difference between the ammonia concentration and the calibration source was 3.33% for varying moisture from 0% to 4% and 2.69%for varying temperature from 25 to 100/200 degrees C. An HCl absorption line of 1.742 microm was selected for by the manufacturer for this instrument. The Hi Tran database indicated that CO2 is probably the only major interferent, although the CO2 absorption is very weak at that wavelength. Interference tests for NO, CO, SO2, NH3, and CO2 for a range of concentrations typical of flue gasses in coal-fired power plants did not show any interference with TDL HCl measurements at 1.742 microm. For these interference tests, CO2 was tested at a concentration of 11.9% concentration in N2 for these tests. Average precision over the entire range for all 10 tests is 3.12%. The focus of this study was.an evaluation of the operation performance of a

  7. Estimating mercury emissions resulting from wildfire in forests of the Western United States

    Science.gov (United States)

    Webster, Jackson; Kane, Tyler J.; Obrist, Daniel; Ryan, Joseph N.; Aiken, George R.

    2016-01-01

    Understanding the emissions of mercury (Hg) from wildfires is important for quantifying the global atmospheric Hg sources. Emissions of Hg from soils resulting from wildfires in the Western United States was estimated for the 2000 to 2013 period, and the potential emission of Hg from forest soils was assessed as a function of forest type and soil-heating. Wildfire released an annual average of 3100 ± 1900 kg-Hg y− 1 for the years spanning 2000–2013 in the 11 states within the study area. This estimate is nearly 5-fold lower than previous estimates for the study region. Lower emission estimates are attributed to an inclusion of fire severity within burn perimeters. Within reported wildfire perimeters, the average distribution of low, moderate, and high severity burns was 52, 29, and 19% of the total area, respectively. Review of literature data suggests that that low severity burning does not result in soil heating, moderate severity fire results in shallow soil heating, and high severity fire results in relatively deep soil heating ( wood > foliage > litter > branches.

  8. PRELIMINARY ESTIMATES OF PERFORMANCE AND COST OF MERCURY EMISSION CONTROL TECHNOLOGY APPLICATIONS ON ELECTRIC UTILITY BOILERS: AN UPDATE

    Science.gov (United States)

    The paper presents estimates of performance levels and related costs associated with controlling mercury (Hg) emissions from coal-fired power plants using either powdered activated carbon (PAC) injection or multipollutant control in which Hg capture is enhanced in existing and ne...

  9. CHARACTERIZATION OF MERCURY EMISSIONS AT A CHLOR-ALKALI PLANT, VOLUME I. REPORT AND APPENDICES A-E

    Science.gov (United States)

    The report gives results of a characterization of mercury (Hg) emissions at a chlor-alkali plant. Up to 160 short tons (146 Mg) of Hg is consumed by the chlor-alkali industry each year. Very little quantitative information is currently available however, on the actual Hg losses f...

  10. CHARACTERIZATION OF FUGITIVE MERCURY EMISSIONS FROM THE CELL BUILDING AT A U.S. CHLOR-ALKALI PLANT

    Science.gov (United States)

    The paper discusses an extensive measurement campaign that was conducted of the fugitive (non-ducted) airborne elemental mercury [Hg(0)] emissions from the cell building of a chlor-alkali plant (CAP) located in the southeastern United States. The objectives of this study were to ...

  11. MEASUREMENT OF TOTAL SITE MERCURY EMISSIONS FROM A CHLOR-ALKALI PLANT USING OPEN-PATH UV-DOAS

    Science.gov (United States)

    In December 2003, the EPA promulgated the National Emission Standard for Hazardous Air Pollutants for mercury cell chlor-alkali plants. In February 2004, the Natural Resources Defense Council filed petitions on the final rule in U.S. district court citing, among other issues, th...

  12. Optimizing Techology to Reduce Mercury and Acid Gas Emissions from Electric Power Plants

    Energy Technology Data Exchange (ETDEWEB)

    Jeffrey C. Quick; David E. Tabet; Sharon Wakefield; Roger L. Bon

    2004-01-31

    More than 56,000 coal quality data records from five public data sets have been selected for use in this project. These data will be used to create maps showing where coals with low mercury and acid-gas emissions might be found for power plants classified by air-pollution controls. Average coal quality values, calculated for 51,156 commercial coals by U.S. county-of-origin, are listed in the appendix. Coal moisture values are calculated for commercially shipped coal from 163 U.S. counties, where the raw assay data (including mercury and chlorine values) are reported on a dry basis. The calculated moisture values are verified by comparison with observed moisture values in commercial coal. Moisture in commercial U.S. coal shows provincial variation. For example, high volatile C bituminous rank coal from the Interior province has 3% to 4% more moisture than equivalent Rocky Mountain province coal. Mott-Spooner difference values are calculated for 4,957 data records for coals collected from coal mines and exploration drill holes. About 90% of the records have Mott-Spooner difference values within {+-}250 Btu/lb.

  13. Estimating mercury emissions resulting from wildfire in forests of the Western United States.

    Science.gov (United States)

    Webster, Jackson P; Kane, Tyler J; Obrist, Daniel; Ryan, Joseph N; Aiken, George R

    2016-10-15

    Understanding the emissions of mercury (Hg) from wildfires is important for quantifying the global atmospheric Hg sources. Emissions of Hg from soils resulting from wildfires in the Western United States was estimated for the 2000 to 2013 period, and the potential emission of Hg from forest soils was assessed as a function of forest type and soil-heating. Wildfire released an annual average of 3100±1900kg-Hgy(-1) for the years spanning 2000-2013 in the 11 states within the study area. This estimate is nearly 5-fold lower than previous estimates for the study region. Lower emission estimates are attributed to an inclusion of fire severity within burn perimeters. Within reported wildfire perimeters, the average distribution of low, moderate, and high severity burns was 52, 29, and 19% of the total area, respectively. Review of literature data suggests that that low severity burning does not result in soil heating, moderate severity fire results in shallow soil heating, and high severity fire results in relatively deep soil heating (severity burns ranged from 58 to 640μg-Hgkg-fuel(-1). In contrast, low severity burns have emission factors that are estimated to be only 18-34μg-Hgkg-fuel(-1). In this estimate, wildfire is predicted to release 1-30gHgha(-1) from Western United States forest soils while above ground fuels are projected to contribute an additional 0.9 to 7.8gHgha(-1). Land cover types with low biomass (desert scrub) are projected to release less than 1gHgha(-1). Following soil sources, fuel source contributions to total Hg emissions generally followed the order of duff>wood>foliage>litter>branches. Copyright © 2016 Elsevier B.V. All rights reserved.

  14. Continuous analysis of dissolved gaseous mercury and mercury volatilization in the upper St. Lawrence River: exploring temporal relationships and UV attenuation.

    Science.gov (United States)

    O'Driscoll, N J; Poissant, L; Canário, L; Ridal, J; Lean, D R S

    2007-08-01

    The formation and volatilization of dissolved gaseous mercury (DGM) is an important mechanism by which freshwaters may naturally reduce their mercury burden. Continuous analysis of surface water for diurnal trends in DGM concentration (ranging from 0 to 60.4 pg L(-1); n=613), mercury volatilization (ranging from 0.2 to 1.1 ng m(-2) h(-1); n=584), and a suite of physical and chemical measurements were performed during a 68 h period in the St. Lawrence River near Cornwall (Ontario, Canada) to examine the temporal relationships governing mercury volatilization. No lag-time was observed between net radiation and OGM concentrations (highest cross-correlation of 0.817), thus supporting previous research indicating faster photoreduction kinetics in rivers as compared to lakes. A significant lag-time (55-145 min; maximum correlation = 0.625) was observed between DGM formation and mercury volatilization, which is similar to surface water Eddy diffusion times of 42-132 min previously measured in the St. Lawrence River. A depth-integrated DGM model was developed using the diffuse integrated vertical attenuation coefficients for UVA and UVB (K(dI UVA) = 1.45 m(-1) K(dI UVB)= 3.20 m(-1)) Low attenuation of solar radiation was attributed to low concentrations of dissolved organic carbon (mean = 2.58 mg L(-1) and particulate organic carbon (mean = 0.58 mg L(-1) in the St. Lawrence River. The depth-integrated DGM model developed found that the top 0.3 m of the water column accounted for only 26% of the total depth-integrated DGM. A comparison with volatilization data indicated that a large portion (76% or 10.5 ng m(-2) of the maximum depth-integrated DGM (13.8 ng m(-2))is volatilized over a 24 h period. Therefore, at least 50% of all DGM volatilized was produced at depths below 0.3 m. These results highlight the importance of solar attenuation in regulating DGM formation with depth. The results also demonstrate both the fast formation of DGM in rivers and the importance of

  15. A laboratory based experimental study of mercury emission from contaminated soils in the River Idrijca catchment

    Directory of Open Access Journals (Sweden)

    D. Kocman

    2010-02-01

    Full Text Available Results obtained by a laboratory flux measurement system (LFMS focused on investigating the kinetics of the mercury emission flux (MEF from contaminated soils of the Idrija Hg-mine region, Slovenia are presented. Representative soil samples with respect to total Hg concentrations (4–417 μg g−1 and land cover (forest, meadow and alluvial soil alongside the River Idrijca were analysed to determine the variation in MEF versus distance from the source, regulating three major environmental parameters comprising soil temperature, soil moisture and solar radiation. MEFs ranged from less than 2 to 530 ng m−2 h−1, with the highest emissions from contaminated alluvial soils and soils near the mining district in the town of Idrija. A significant decrease of MEF was then observed with increasing distance from these sites. The results revealed a strong positive effect of all three parameters investigated on momentum MEF. The light-induced flux was shown to be independent of the soil temperature, while the soil aqueous phase seems to be responsible for recharging the pool of mercury in the soil available for both the light- and thermally-induced flux. The overall flux response to simulated environmental conditions depends greatly on the form of Hg in the soil. Higher activation energies are required for the overall process to occur in soils where insoluble cinnabar prevails compared to soils where more mobile Hg forms and forms available for transformation processes are dominant.

  16. Emissions of carbon species, organic polar compounds, potassium, and mercury from prescribed burning activities

    Science.gov (United States)

    Zhang, Y.; Obrist, D.; Zielinska, B.; Gerler, A.

    2012-04-01

    Biomass burning is an important emission source of pollutants to the atmosphere, but few studies have focused on the chemical composition of emissions from prescribed burning activities. Here we present results from a sampling campaign to quantify particulate-phase emissions from various types of prescribed fires including carbon species (Elemental Carbon: EC; Organic Carbon: OC; and Total Carbon: TC); polar organic compounds (12 different compounds and four functional classes); water-soluble potassium (K+); and mercury (Hg). We measured emissions from the following types of prescribed biomass burning in the Lake Tahoe basin located on the California/Nevada border: (i) log piles stacked and dried in the field; (ii) log piles along with green understory vegetation; and (iii) understory green vegetation and surface litter; further emissions were collected from burns conducted in a wood stove: (iv) dried wooden logs; (v) green foliage of understory vegetation collected from the field; and (vi) surface organic litter collected from the field; finally, samples were also taken from (vii) ambient air in residential areas during peak domestic wood combustion season. Results show that OC/EC ratios of prescribed burns in the field ranged from 4 to 10, but lower values (around 1) were observed in controlled stove fires. These results are consistent with an excess of OC emissions over EC found in wildfires. OC/EC ratios, however, showed clear separations between controlled wood stove combustion (higher EC) and prescribed burns in the field (lower EC). We attribute this difference to a higher combustion temperatures and dominance of flaming combustion in wood stove fires. OC positively and linearly correlated to the sum of polar organic compounds across all burn types (r2 of 0.82). The most prevalent group of polar compounds emitted during prescribed fires was resin acids (dehydroabietic, pimaric, and abietic acids), followed by levoglucosan plus mannositol. Negligible

  17. Continuous measurements of N2O emissions from arable fields

    Science.gov (United States)

    Wallman, Magdalena; Lammirato, Carlo; Rütting, Tobias; Delin, Sofia; Weslien, Per; Klemedtsson, Leif

    2017-04-01

    Agriculture represents 59 % of the anthropogenic nitrous oxide (N2O) emissions, according to the IPCC (Ciais et al. 2013). N2O emissions are typically irregular and vary widely in time and space, which makes it difficult to get a good representation of the emissions (Henault et al. 2012), particularly if measurements have low frequency and/or cover only a short time period. Manual measurements are, for practical reasons, often short-term and low-frequent, or restricted to periods where emissions are expected to be high, e.g. after fertilizing. However, the nature of N2O emissions, being largely unpredictable, calls for continuous or near-continuous measurements over long time periods. So far, rather few long-term, high resolution measurements of N2O emissions from arable fields are reported; among them are Flessa et al. (2002) and Senapati et al. (2016). In this study, we have a two-year data set (2015-2017) with hourly measurements from ten automatic chambers, covering unfertilized controls as well as different nitrogen fertilizer treatments. Grain was produced on the field, and effects of tillage, harvest and other cropping measures were covered. What we can see from the experiment is that (a) the unfertilized control plots seem to follow the same emission pattern as the fertilized plots, at a level similar to the standard mineral fertilized plots (120 kg N ha-1 yr-1) and (b) freeze/thaw emissions are comparable in size to emissions after fertilizing. These two findings imply that the importance of fertilizing to the overall N2O emissions from arable soils may be smaller than previously expected. References: Ciais, P., C. Sabine, G. Bala, L. Bopp, V. Brovkin, J. Canadell et al. 2013: Carbon and Other Biogeochemical Cycles. In: Climate Change 2013: The Physical Science Basis. Contribution of Working Group I to the Fifth Assessment Report of the Intergovernmental Panel on Climate Change [Stocker, T.F., D. Qin, G.-K. Plattner, M. Tignor, S.K. Allen, J. Boschung et

  18. Estimation of greenhouse impacts of continuous regional emissions

    Energy Technology Data Exchange (ETDEWEB)

    Sinisalo, J. [VTT Energy, Espoo (Finland). Energy Systems

    1998-11-01

    In this thesis a method to calculate the greenhouse impact of continuous, time-dependent, non-global greenhouse gas emissions is used to estimate the impact of estimated anthropogenic pre-1990 and future (post 1990) emissions of CO{sub 2}, CH{sub 4} and N{sub 2}O from Finland and the Nordic countries. Estimates for the impact of Finnish CFCs and their substitutes and the significance of Finnish forests as carbon sink are also calculated. The method is also used to compare several different wood and peat energy production schemes with fossil fuel use, in terms of caused greenhouse impact. The uncertainty of the results is examined. The greenhouse impact is measured in this thesis as the global mean direct radiative forcing caused by the emissions. Radiative forcing is the driving force behind the climate change and as such it can be used to assess the ensuing climate change. The method is suitable for greenhouse agents that can be considered to be well mixed in the atmosphere (mainly CO{sub 2}, CH{sub 4}, N{sub 2}O and both CFCs and their substitutes). According to the results Finnish greenhouse impact due to anthropogenic CO{sub 2}, CH{sub 4} and N{sub 2}O emissions has increased eight-fold during this century, and will very likely remain higher than current level throughout the next century. The impact of the Nordic countries has followed the same general pattern as Finland. It is likely that the per capita radiative forcing of the Nordic countries will remain above the global average. The uncertainty of the absolute results is quite high due to uncertain knowledge at several stages of the calculation. When the results are used in comparisons (e.g. between emission scenarios, or emissions of different countries), the accuracy of the results increases considerably. (orig.) 54 refs.

  19. Measurement of Total Site Mercury Emissions from Chlor-Alkali Plant Using Ultraviolet Differential Optical Absorption Spectroscopy and Cell Room Roof-Vent Monitoring

    Science.gov (United States)

    This technical note describes a United States Environmental Protection Agency (U.S. EPA) measurement project to determine elemental mercury (Hg0) emissions from a mercury cell chlor-alkali (MCCA) facility in the southeastern U.S. during a 53-day monitoring campaign in the fall of...

  20. Mercury emissions during cofiring of sub-bituminous coal and biomass (chicken waste, wood, coffee residue, and tobacco stalk) in a laboratory-scale fluidized bed combustor.

    Science.gov (United States)

    Cao, Yan; Zhou, Hongcang; Fan, Junjie; Zhao, Houyin; Zhou, Tuo; Hack, Pauline; Chan, Chia-Chun; Liou, Jian-Chang; Pan, Wei-Ping

    2008-12-15

    Four types of biomass (chicken waste, wood pellets, coffee residue, and tobacco stalks) were cofired at 30 wt % with a U.S. sub-bituminous coal (Powder River Basin Coal) in a laboratory-scale fluidized bed combustor. A cyclone, followed by a quartz filter, was used for fly ash removal during tests. The temperatures of the cyclone and filter were controlled at 250 and 150 degrees C, respectively. Mercury speciation and emissions during cofiring were investigated using a semicontinuous mercury monitor, which was certified using ASTM standard Ontario Hydra Method. Test results indicated mercury emissions were strongly correlative to the gaseous chlorine concentrations, but not necessarily correlative to the chlorine contents in cofiring fuels. Mercury emissions could be reduced by 35% during firing of sub-bituminous coal using only a quartz filter. Cofiring high-chlorine fuel, such as chicken waste (Cl = 22340 wppm), could largely reduce mercury emissions by over 80%. When low-chlorine biomass, such as wood pellets (Cl = 132 wppm) and coffee residue (Cl = 134 wppm), is cofired, mercury emissions could only be reduced by about 50%. Cofiring tobacco stalks with higher chlorine content (Cl = 4237 wppm) did not significantly reduce mercury emissions. This was also true when limestone was added while cofiring coal and chicken waste because the gaseous chlorine was reduced in the freeboard of the fluidized bed combustor, where the temperature was generally below 650 degrees C without addition of the secondary air. Gaseous speciated mercury in flue gas after a quartz filter indicated the occurrence of about 50% of total gaseous mercury to be the elemental mercury for cofiring chicken waste, but occurrence of above 90% of the elemental mercury for all other cases. Both the higher content of alkali metal oxides or alkali earth metal oxides in tested biomass and the occurrence of temperatures lower than 650 degrees C in the upper part of the fluidized bed combustor seemed to be

  1. Continuous and recurrent testing of acoustic emission sensors

    International Nuclear Information System (INIS)

    Sause, Markus G.R.; Schmitt, Stefan; Potstada, Philipp

    2017-01-01

    In many fields of application of acoustic emission, the testing can lead to a lasting change in the sensor characteristics. This can be caused by mechanical damage, thermal stress or use under aggressive environmental conditions. Irrespective of visually testable damages of the sensors, a shift in the spectral sensitivity, a reduction in the absolute sensitivity or a reduction in the signal-to-noise ratio can occur. During the test, this requires a possibility to periodically check the sensors, including the coupling aids used. For recurring testing, recommendations are given in Directive SE 02 ''Verification of acoustic emission sensors and their coupling in the laboratory''. This paper discusses possibilities for continuous monitoring of the sensors during the test and presents an application example for the partly automated recurring testing of acoustic emission sensors using Directive SE 02. For this purpose, a test stand for the supply of the sensors to be tested was constructed and the signal recording and data reduction implemented in freely available software programs. The operating principle is demonstrated using selected case studies. [de

  2. Estimation of gaseous mercury emissions in Germany. Inverse modelling of source strengths at the contaminated industrial site BSL Werk Schkopau

    Energy Technology Data Exchange (ETDEWEB)

    Krueger, O.; Ebinghaus, R.; Kock, H.H.; Richter-Politz, I.; Geilhufe, C.

    1998-12-31

    Anthropogenic emission sources of gaseous mercury at the contaminated industrial site BSL Werk Schkopau have been determined by measurements and numerical modelling applying a local dispersion model. The investigations are based on measurements from several field campaigns in the period of time between December 1993 and June 1994. The estimation of the source strengths was performed by inverse modelling using measurements as constraints for the dispersion model. Model experiments confirmed the applicability of the inverse modelling procedure for the source strength estimation at BSL Werk Schkopau. At the factory premises investigated, the source strengths of four source areas, among them three closed chlor-alkali productions, one partly removed acetaldehyde factory and additionaly one still producing chlor-alkali factory have been identified with an approximate total gaseous mercury emission of lower than 2.5 kg/day. (orig.)

  3. Mercury CEM Calibration

    Energy Technology Data Exchange (ETDEWEB)

    John F. Schabron; Joseph F. Rovani; Susan S. Sorini

    2007-03-31

    The Clean Air Mercury Rule (CAMR) which was published in the Federal Register on May 18, 2005, requires that calibration of mercury continuous emissions monitors (CEMs) be performed with NIST-traceable standards. Western Research Institute (WRI) is working closely with the Electric Power Research Institute (EPRI), the National Institute of Standards and Technology (NIST), and the Environmental Protection Agency (EPA) to facilitate the development of the experimental criteria for a NIST traceability protocol for dynamic elemental mercury vapor generators. The traceability protocol will be written by EPA. Traceability will be based on the actual analysis of the output of each calibration unit at several concentration levels ranging from about 2-40 ug/m{sup 3}, and this analysis will be directly traceable to analyses by NIST using isotope dilution inductively coupled plasma/mass spectrometry (ID ICP/MS) through a chain of analyses linking the calibration unit in the power plant to the NIST ID ICP/MS. Prior to this project, NIST did not provide a recommended mercury vapor pressure equation or list mercury vapor pressure in its vapor pressure database. The NIST Physical and Chemical Properties Division in Boulder, Colorado was subcontracted under this project to study the issue in detail and to recommend a mercury vapor pressure equation that the vendors of mercury vapor pressure calibration units can use to calculate the elemental mercury vapor concentration in an equilibrium chamber at a particular temperature. As part of this study, a preliminary evaluation of calibration units from five vendors was made. The work was performed by NIST in Gaithersburg, MD and Joe Rovani from WRI who traveled to NIST as a Visiting Scientist.

  4. 40 CFR 60.4350 - How do I use data from the continuous emission monitoring equipment to identify excess emissions?

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 6 2010-07-01 2010-07-01 false How do I use data from the continuous....4350 How do I use data from the continuous emission monitoring equipment to identify excess emissions? For purposes of identifying excess emissions: (a) All CEMS data must be reduced to hourly averages as...

  5. Preliminary results from a continuous record of atmospheric gaseous mercury at the coastal station Dumont d’Urville in Antarctica

    Directory of Open Access Journals (Sweden)

    Dommergue A.

    2013-04-01

    Full Text Available While the tropospheric reactivity of mercury (Hg in the Arctic is more and more documented only a few attempts were made to study the Hg cycle in the Southern Polar Regions. The role of the Antarctic continent and its influence on the global geochemical cycle of mercury is unclear today, and is certainly under evaluated by current models. Here, we present the first continuous high-time-resolution measurements of atmospheric gaseous elemental mercury (GEM in East Antarctica from February 2010 to March 2011 at the coastal research station Dumont d’Urville (DDU (66°40’S, 140°01’E, 43 m asl. We report an annual mean level of 1.062 ± 0.321 ng/m3 with well-marked daily fluctuations from October to January. An intense reactivity originated from the atmospheric boundary layer of the Antarctic plateau under sunlight conditions is observed at DDU. Partly GEM-depleted air masses are exported from the continent and dramatically influence the GEM record at DDU. From November to January, surface waters of the Southern Ocean are an important source of GEM.

  6. POTENTIAL HEALTH RISK REDUCTION ARISING FROM REDUCED MERCURY EMISSIONS FROM COAL FIRED POWER PLANTS.

    Energy Technology Data Exchange (ETDEWEB)

    Sullivan, T. M.; Lipfert, F. W.; Morris, S. C.; Moskowitz, P. D.

    2001-09-01

    The U.S. Environmental Protection Agency (EPA) has announced plans to regulate mercury (Hg) emissions from coal-fired power plants. EPA has not prepared a quantitative assessment of the reduction in risk that could be achieved through reduction in coal plant emissions of Hg. To address this issue, Brookhaven National Laboratory (BNL) with support from the U.S. Department of Energy Office of Fossil Energy (DOE FE) prepared a quantitative assessment of the reduction in human health risk that could be achieved through reduction in coal plant emissions of Hg. The primary pathway for Hg exposure is through consumption of fish. The most susceptible population to Hg exposure is the fetus. Therefore the risk assessment focused on consumption of fish by women of child-bearing age. Dose response factors were generated from studies on loss of cognitive abilities (language skills, motor skills, etc.) by young children whose mothers consumed large amounts of fish with high Hg levels. Population risks were estimated for the general population in three regions of the country, (the Midwest, Northeast, and Southeast) that were identified by EPA as being heavily impacted by coal emissions. Three scenarios for reducing Hg emissions from coal plants were considered: (1) A base case using current conditions; (2) A 50% reduction; and, (3) A 90% reduction. These reductions in emissions were assumed to translate linearly into a reduction in fish Hg levels of 8.6% and 15.5%, respectively. Population risk estimates were also calculated for two subsistence fisher populations. These groups of people consume substantially more fish than the general public and, depending on location, the fish may contain higher Hg levels than average. Risk estimates for these groups were calculated for the three Hg levels used for the general population analyses. Analysis shows that the general population risks for exposure of the fetus to Hg are small. Estimated risks under current conditions (i.e., no

  7. Nitrogen oxides, sulfur trioxide, and mercury emissions during oxy-fuel fluidized bed combustion of Victorian brown coal.

    Science.gov (United States)

    Roy, Bithi; Chen, Luguang; Bhattacharya, Sankar

    2014-12-16

    This study investigates, for the first time, the NOx, N2O, SO3, and Hg emissions from combustion of a Victorian brown coal in a 10 kWth fluidized bed unit under oxy-fuel combustion conditions. Compared to air combustion, lower NOx emissions and higher N2O formation were observed in the oxy-fuel atmosphere. These NOx reduction and N2O formations were further enhanced with steam in the combustion environment. The NOx concentration level in the flue gas was within the permissible limit in coal-fired power plants in Victoria. Therefore, an additional NOx removal system will not be required using this coal. In contrast, both SO3 and gaseous mercury concentrations were considerably higher under oxy-fuel combustion compared to that in the air combustion. Around 83% of total gaseous mercury released was Hg(0), with the rest emitted as Hg(2+). Therefore, to control harmful Hg(0), a mercury removal system may need to be considered to avoid corrosion in the boiler and CO2 separation units during the oxy-fuel fluidized-bed combustion using this coal.

  8. 40 CFR 60.1720 - What continuous emission monitoring systems must I install for gaseous pollutants?

    Science.gov (United States)

    2010-07-01

    ..., maintain, and operate continuous emission monitoring systems for oxygen (or carbon dioxide), sulfur dioxide... emission monitoring systems for sulfur dioxide, nitrogen oxides, and oxygen (or carbon dioxide) at the... also install continuous emission monitoring systems for sulfur dioxide and oxygen (or carbon dioxide...

  9. 40 CFR 60.1235 - How are the data from the continuous emission monitoring systems used?

    Science.gov (United States)

    2010-07-01

    ... emission monitoring systems used? 60.1235 Section 60.1235 Protection of Environment ENVIRONMENTAL... used? You must use data from the continuous emission monitoring systems for sulfur dioxide, nitrogen oxides, and carbon monoxide to demonstrate continuous compliance with the emission limits specified in...

  10. 40 CFR 62.15175 - What continuous emission monitoring systems must I install for gaseous pollutants?

    Science.gov (United States)

    2010-07-01

    ..., maintain, and operate continuous emission monitoring systems for oxygen (or carbon dioxide), sulfur dioxide... emission monitoring system for sulfur dioxide, nitrogen oxides, and oxygen (or carbon dioxide) at the... 40 Protection of Environment 8 2010-07-01 2010-07-01 false What continuous emission monitoring...

  11. THE LOCAL IMPACTS OF MERCURY EMISSIONS FROM COAL FIRED POWER PLANTS ON HUMAN HEALTH RISK. PROGRESS REPORT FOR THE PERIOD OF MARCH 2003 - MARCH 2003.

    Energy Technology Data Exchange (ETDEWEB)

    SULLIVAN,T.M.LIPFERT,F.D.MORRIS,S.M.

    2003-05-01

    This report presents a follow-up to previous assessments of the health risks of mercury that BNL performed for the Department of Energy. Methylmercury is an organic form of mercury that has been implicated as the form of mercury that impacts human health. A comprehensive risk assessment report was prepared (Lipfert et al., 1994) that led to several journal articles and conference presentations (Lipfert et al. 1994, 1995, 1996). In 2001, a risk assessment of mercury exposure from fish consumption was performed for 3 regions of the U.S (Northeast, Southeast, and Midwest) identified by the EPA as regions of higher impact from coal emissions (Sullivan, 2001). The risk assessment addressed the effects of in utero exposure to children through consumption of fish by their mothers. Two population groups (general population and subsistence fishers) were considered. Three mercury levels were considered in the analysis, current conditions based on measured data, and hypothetical reductions in Hg levels due to a 50% and 90% reduction in mercury emissions from coal fired power plants. The findings of the analysis suggested that a 90% reduction in coal-fired emissions would lead to a small reduction in risk to the general population (population risk reduction on the order of 10{sup -5}) and that the population risk is born by less than 1% of the population (i.e. high end fish consumers). The study conducted in 2001 focused on the health impacts arising from regional deposition patterns as determined by measured data and modeling. Health impacts were assessed on a regional scale accounting for potential percent reductions in mercury emissions from coal. However, quantitative assessment of local deposition near actual power plants has not been attempted. Generic assessments have been performed, but these are not representative of any single power plant. In this study, general background information on the mercury cycle, mercury emissions from coal plants, and risk assessment are

  12. Emissions, Monitoring, and Control of Mercury from Subbituminous Coal-Fired Power Plants - Phase II

    Energy Technology Data Exchange (ETDEWEB)

    Alan Bland; Jesse Newcomer; Allen Kephart; Volker Schmidt; Gerald Butcher

    2008-10-31

    Western Research Institute (WRI), in conjunction with Western Farmers Electric Cooperative (WFEC), has teamed with Clean Air Engineering of Pittsburgh PA to conduct a mercury monitoring program at the WEFC Hugo plant in Oklahoma. Sponsored by US Department of Energy Cooperative Agreement DE-FC-26-98FT40323, the program included the following members of the Subbituminous Energy Coalition (SEC) as co-sponsors: Missouri Basin Power Project; DTE Energy; Entergy; Grand River Dam Authority; and Nebraska Public Power District. This research effort had five objectives: (1) determine the mass balance of mercury for subbituminous coal-fired power plant; (2) assess the distribution of mercury species in the flue gas (3) perform a comparison of three different Hg test methods; (4) investigate the long-term (six months) mercury variability at a subbituminous coal-fired power plant; and (5) assess operation and maintenance of the Method 324 and Horiba CEMS utilizing plant personnel.

  13. Method selection for mercury removal from hard coal

    Directory of Open Access Journals (Sweden)

    Dziok Tadeusz

    2017-01-01

    Full Text Available Mercury is commonly found in coal and the coal utilization processes constitute one of the main sources of mercury emission to the environment. This issue is particularly important for Poland, because the Polish energy production sector is based on brown and hard coal. The forecasts show that this trend in energy production will continue in the coming years. At the time of the emission limits introduction, methods of reducing the mercury emission will have to be implemented in Poland. Mercury emission can be reduced as a result of using coal with a relatively low mercury content. In the case of the absence of such coals, the methods of mercury removal from coal can be implemented. The currently used and developing methods include the coal cleaning process (both the coal washing and the dry deshaling as well as the thermal pretreatment of coal (mild pyrolysis. The effectiveness of these methods various for different coals, which is caused by the diversity of coal origin, various characteristics of coal and, especially, by the various modes of mercury occurrence in coal. It should be mentioned that the coal cleaning process allows for the removal of mercury occurring in mineral matter, mainly in pyrite. The thermal pretreatment of coal allows for the removal of mercury occurring in organic matter as well as in the inorganic constituents characterized by a low temperature of mercury release. In this paper, the guidelines for the selection of mercury removal method from hard coal were presented. The guidelines were developed taking into consideration: the effectiveness of mercury removal from coal in the process of coal cleaning and thermal pretreatment, the synergy effect resulting from the combination of these processes, the direction of coal utilization as well as the influence of these processes on coal properties.

  14. Mercury CEM Calibration

    Energy Technology Data Exchange (ETDEWEB)

    John Schabron; Joseph Rovani; Mark Sanderson

    2008-02-29

    Mercury continuous emissions monitoring systems (CEMS) are being implemented in over 800 coal-fired power plant stacks. The power industry desires to conduct at least a full year of monitoring before the formal monitoring and reporting requirement begins on January 1, 2009. It is important for the industry to have available reliable, turnkey equipment from CEM vendors. Western Research Institute (WRI) is working closely with the Electric Power Research Institute (EPRI), the National Institute of Standards and Technology (NIST), and the Environmental Protection Agency (EPA) to facilitate the development of the experimental criteria for a NIST traceability protocol for dynamic elemental mercury vapor generators. The generators are used to calibrate mercury CEMs at power plant sites. The Clean Air Mercury Rule (CAMR) which was published in the Federal Register on May 18, 2005 requires that calibration be performed with NIST-traceable standards (Federal Register 2007). Traceability procedures will be defined by EPA. An initial draft traceability protocol was issued by EPA in May 2007 for comment. In August 2007, EPA issued an interim traceability protocol for elemental mercury generators (EPA 2007). The protocol is based on the actual analysis of the output of each calibration unit at several concentration levels ranging initially from about 2-40 {micro}g/m{sup 3} elemental mercury, and in the future down to 0.2 {micro}g/m{sup 3}, and this analysis will be directly traceable to analyses by NIST. The document is divided into two separate sections. The first deals with the qualification of generators by the vendors for use in mercury CEM calibration. The second describes the procedure that the vendors must use to certify the generator models that meet the qualification specifications. The NIST traceable certification is performance based, traceable to analysis using isotope dilution inductively coupled plasma/mass spectrometry performed by NIST in Gaithersburg, MD. The

  15. Continuous-wave infrared optical gain and amplified spontaneous emission at ultralow threshold by colloidal HgTe quantum dots.

    Science.gov (United States)

    Geiregat, Pieter; Houtepen, Arjan J; Sagar, Laxmi Kishore; Infante, Ivan; Zapata, Felipe; Grigel, Valeriia; Allan, Guy; Delerue, Christophe; Van Thourhout, Dries; Hens, Zeger

    2018-01-01

    Colloidal quantum dots (QDs) raise more and more interest as solution-processable and tunable optical gain materials. However, especially for infrared active QDs, optical gain remains inefficient. Since stimulated emission involves multifold degenerate band-edge states, population inversion can be attained only at high pump power and must compete with efficient multi-exciton recombination. Here, we show that mercury telluride (HgTe) QDs exhibit size-tunable stimulated emission throughout the near-infrared telecom window at thresholds unmatched by any QD studied before. We attribute this unique behaviour to surface-localized states in the bandgap that turn HgTe QDs into 4-level systems. The resulting long-lived population inversion induces amplified spontaneous emission under continuous-wave optical pumping at power levels compatible with solar irradiation and direct current electrical pumping. These results introduce an alternative approach for low-threshold QD-based gain media based on intentional trap states that paves the way for solution-processed infrared QD lasers and amplifiers.

  16. Continuous-wave infrared optical gain and amplified spontaneous emission at ultralow threshold by colloidal HgTe quantum dots

    Science.gov (United States)

    Geiregat, Pieter; Houtepen, Arjan J.; Sagar, Laxmi Kishore; Infante, Ivan; Zapata, Felipe; Grigel, Valeriia; Allan, Guy; Delerue, Christophe; van Thourhout, Dries; Hens, Zeger

    2018-01-01

    Colloidal quantum dots (QDs) raise more and more interest as solution-processable and tunable optical gain materials. However, especially for infrared active QDs, optical gain remains inefficient. Since stimulated emission involves multifold degenerate band-edge states, population inversion can be attained only at high pump power and must compete with efficient multi-exciton recombination. Here, we show that mercury telluride (HgTe) QDs exhibit size-tunable stimulated emission throughout the near-infrared telecom window at thresholds unmatched by any QD studied before. We attribute this unique behaviour to surface-localized states in the bandgap that turn HgTe QDs into 4-level systems. The resulting long-lived population inversion induces amplified spontaneous emission under continuous-wave optical pumping at power levels compatible with solar irradiation and direct current electrical pumping. These results introduce an alternative approach for low-threshold QD-based gain media based on intentional trap states that paves the way for solution-processed infrared QD lasers and amplifiers.

  17. Real-time analysis of total, elemental, and total speciated mercury

    International Nuclear Information System (INIS)

    Schlager, R.J.; Wilson, K.G.; Sappey, A.D.

    1995-01-01

    ADA Technologies, Inc., is developing a continuous emissions monitoring system that measures the concentrations of mercury in flue gas. Mercury is emitted as an air pollutant from a number of industrial processes. The largest contributors of these emissions are coal and oil combustion, municipal waste combustion, medical waste combustion, and the thermal treatment of hazardous materials. It is difficult, time consuming, and expensive to measure mercury emissions using current testing methods. Part of the difficulty lies in the fact that mercury is emitted from sources in several different forms, such as elemental mercury and mercuric chloride. The ADA analyzer measures these emissions in real time, thus providing a number of advantages over existing test methods: (1) it will provide a real-time measure of emission rates, (2) it will assure facility operators, regulators, and the public that emissions control systems are working at peak efficiency, and (3) it will provide information as to the nature of the emitted mercury (elemental mercury or speciated compounds). This update presents an overview of the CEM and describes features of key components of the monitoring system--the mercury detector, a mercury species converter, and the analyzer calibration system

  18. Real-time analysis of total, elemental, and total speciated mercury

    Energy Technology Data Exchange (ETDEWEB)

    Schlager, R.J.; Wilson, K.G.; Sappey, A.D. [ADA Technologies, Inc., Englewood, CO (United States)

    1995-11-01

    ADA Technologies, Inc., is developing a continuous emissions monitoring system that measures the concentrations of mercury in flue gas. Mercury is emitted as an air pollutant from a number of industrial processes. The largest contributors of these emissions are coal and oil combustion, municipal waste combustion, medical waste combustion, and the thermal treatment of hazardous materials. It is difficult, time consuming, and expensive to measure mercury emissions using current testing methods. Part of the difficulty lies in the fact that mercury is emitted from sources in several different forms, such as elemental mercury and mercuric chloride. The ADA analyzer measures these emissions in real time, thus providing a number of advantages over existing test methods: (1) it will provide a real-time measure of emission rates, (2) it will assure facility operators, regulators, and the public that emissions control systems are working at peak efficiency, and (3) it will provide information as to the nature of the emitted mercury (elemental mercury or speciated compounds). This update presents an overview of the CEM and describes features of key components of the monitoring system--the mercury detector, a mercury species converter, and the analyzer calibration system.

  19. Mercury balance analysis

    International Nuclear Information System (INIS)

    Maag, J.; Lassen, C.; Hansen, E.

    1996-01-01

    A detailed assessment of the consumption of mercury, divided into use areas, was carried out. Disposal and emissions to the environment were also qualified. The assessment is mainly based on data from 1992 - 1993. The most important source of emission of mercury to air is solid waste incineration which is assessed in particular to be due to the supply of mercury in batteries (most likely mercury oxide batteries from photo equipment) and to dental fillings. The second most important source of mercury emission to air is coal-fired power plants which are estimated to account for 200-500 kg of mercury emission p.a. Other mercury emissions are mainly related to waste treatment and disposal. The consumption of mercury is generally decreasing. During the period from 1982/83 - 1992-93, the total consumption of mercury in Denmark was about halved. This development is related to the fact that consumption with regard to several important use areas (batteries, dental fillings, thermometers etc.) has been significantly reduced, while for other purposes the use of mercury has completely, or almost disappeared, i.e. (fungicides for seed, tubes etc.). (EG)

  20. NOVEL ECONOMICAL HG(0) OXIDATION REAGENT FOR MERCURY EMISSIONS CONTROL FROM COAL-FIRED BOILERS

    Science.gov (United States)

    The authors have developed a novel economical additive for elemental mercury (Hg0) removal from coal-fired boilers. The oxidation reagent was rigorously tested in a lab-scale fixed-bed column with the Norit America's FGD activated carbon (DOE's benchmark sorbent) in a typical PRB...

  1. Measurement of cesium and mercury emissions from the vitrification of simulated high level radioactive waste

    International Nuclear Information System (INIS)

    Zamecnik, J.R.

    1992-01-01

    In the Defense Waste Processing Facility at the Savannah River Site, it is desired to measure non-radioactive cesium in the offgas system from the glass melter. From a pilot scale melter system, offgas particulate samples were taken on filter paper media and analyzed by Inductively Coupled Plasma-Mass Spectrometry (ICP-MS). The ICP-MS method proved to be sufficiently sensitive to measure cesium quantities as low as 0.135 μg, with the sensitivity being limited by the background cesium present in the filter paper. This sensitivity allowed determination of cesium decontamination factors for four of the five major components of the offgas system. In addition, total particulate measurements were also made. Measurements of mercury decontamination factors were made on the same equipment; the results indicate that most of the mercury in the offgas system probably exists as elemental mercury and HgCl 2 , with some HgO and Hg 2 Cl 2 . The decontamination factors determined for cesium, total particulate, and mercury all compared favorably with the design values

  2. A novel approach to mitigating sulphur dioxide emissions and producing a mercury sorbent material using oil-sands fluid coke

    International Nuclear Information System (INIS)

    Morris, E.; Jia, C.Q.; Tong, S.

    2008-01-01

    Pyrometallurgical smelting operations are a major source of sulphur dioxide (SO 2 ) which is a precursor to acid rain and increased levels of UV-B penetration in boreal lakes. Mercury is also released in copper smelter off-gas, which can bioaccumulate and cause neurological disorders and death in humans. Fluid coke is produced in massive quantities as a by-product of bitumen upgrading at Syncrude Canada's facility in Fort McMurray, Alberta. Oilsands fluid coke can be used to reduce SO 2 and produce elemental sulphur as a co-product. This process was dubbed SOactive. The reaction physically activates the fluid coke to produce a sulphur-impregnated activated carbon (SIAC) which is known as ECOcarbon. Some studies have indicated that SIAC is well suited for the removal of vapour phase mercury, mainly due to the formation of stable mercuric sulphide species. This paper discussed the findings made to date in relation to the SOactive process and the characterization of ECOcarbons. The paper discussed the use of fluid coke for reducing SO 2 emissions while producing elemental sulphur as well as coke-SO 2 -oxygen (O 2 ) and coke-SO 2 -water (H 2 O) systems. The paper also examined the production of SIAC products for use in capturing vapour phase mercury. The paper presented the materials and methodology, including an illustration of the apparatus used in reduction of SO 2 and activation of fluid coke. It was concluded that more work is still needed to analyse the effect of O 2 and SO 2 reduction and SIAC properties under smelter flue gas conditions. 10 refs., 1 tab., 8 figs

  3. Mitigation of gaseous Mercury Emissions from Waste-to-Energy Facilities: Homogeneous and Heterogeneous Hg-Oxidation Pathways in Presence of Fly Ash.

    Czech Academy of Sciences Publication Activity Database

    Rumayor, Marta; Svoboda, Karel; Švehla, Jaroslav; Pohořelý, Michael; Šyc, Michal

    Roč. 206, JAN 15 ( 2018 ), s. 276-283 ISSN 0301-4797 R&D Projects: GA TA ČR TE02000236 Institutional support: RVO:67985858 Keywords : mercury * emission * waste incineration Subject RIV: DI - Air Pollution ; Quality OBOR OECD: Environmental sciences (social aspects to be 5.7) Impact factor: 4.010, year: 2016

  4. Mitigation of gaseous Mercury Emissions from Waste-to-Energy Facilities: Homogeneous and Heterogeneous Hg-Oxidation Pathways in Presence of Fly Ash.

    Czech Academy of Sciences Publication Activity Database

    Rumayor, Marta; Svoboda, Karel; Švehla, Jaroslav; Pohořelý, Michael; Šyc, Michal

    2018-01-01

    Roč. 206, JAN 15 (2018), s. 276-283 ISSN 0301-4797 R&D Projects: GA TA ČR TE02000236 Institutional support: RVO:67985858 Keywords : mercury * emission * waste incineration Subject RIV: DI - Air Pollution ; Quality OBOR OECD: Environmental sciences (social aspects to be 5.7) Impact factor: 4.010, year: 2016

  5. Union of Soviet Socialist Republics: Progress report on mercury

    International Nuclear Information System (INIS)

    1987-01-01

    The main chemical contaminant of the environment is considered mercury and mercury compounds. Different from pesticides, detergents and other toxicants of anthropogenic origin mercury and its compounds occur in all parts of the environment and in all living organisms. In the process of geochemical cycle mercury is released to the environment. Unfavourable ecological effects are caused by elevated concentrations of mercury. In this report an attempt is made to generalize the materials submitted by the Baltic Sea States to the Helsinki Convention concerning the occurrence of mercury in natural systems, the use of mercury in various sectors of economy and emissions of mercury to the environment. The Baltic Sea States are aware of the actual and potential problems which can be caused by mercury pollution. The environmental protection efforts are concentrated on a number of counter-measures. Much is already been done both at national levels and within the Helsinki Convention to reduce the levels of mercury entering the marine environment. However, the national governments recognise that continuing actions need to be taken in order to ensure that the sea is kept free from pollution

  6. The use of continuous functions for a top-down temporal disaggregation of emission inventories

    International Nuclear Information System (INIS)

    Kalchmayr, M.; Orthofer, R.

    1997-11-01

    This report is a documentation of a presentation at the International Speciality Conference 'The Emission Inventory: Planning for the Future', October 28-30, 1997 in Research Triangle Park, North Carolina, USA. The Conference was organized by the Air and Waste Management Association (AWMA) and the U.S. Environmental Protection Agency. Emission data with high temporal resolution are necessary to analyze the relationship between emissions and their impacts. In many countries, however, emission inventories refer only to the annual countrywide emission sums, because underlying data (traffic, energy, industry statistics) are available for statistically relevant territorial units and for longer time periods only. This paper describes a method for the temporal disaggregation of yearly emission sums through application of continuous functions which simulate emission generating activities. The temporal patterns of the activities are derived through overlay of annual, weekly and diurnal variation functions which are based on statistical data of the relevant activities. If applied to annual emission data, these combined functions describe the dynamic patterns of emissions over year. The main advantage of the continuous functions method is that temporal emission patterns can be smoothed throughout one year, thus eliminating some of the major drawbacks from the traditional standardized fixed quota system. For handling in models, the continuous functions and their parameters can be directly included and the emission quota calculated directly for a certain hour of the year. The usefulness of the method is demonstrated with NMVOC emission data for Austria. Temporally disaggregated emission data can be used as input for ozone models as well as for visualization and animation of the emission dynamics. The analysis of the temporal dynamics of emission source strengths, e.g. during critical hours for ozone generation in summer, allows the implementation of efficient emission reduction

  7. Ultrasensitive Speciation Analysis of Mercury in Rice by Headspace Solid Phase Microextraction Using Porous Carbons and Gas Chromatography-Dielectric Barrier Discharge Optical Emission Spectrometry.

    Science.gov (United States)

    Lin, Yao; Yang, Yuan; Li, Yuxuan; Yang, Lu; Hou, Xiandeng; Feng, Xinbin; Zheng, Chengbin

    2016-03-01

    Rice consumption is a primary pathway for human methylmercury (MeHg) exposure in inland mercury mining areas of Asia. In addition, the use of iodomethane, a common fumigant that significantly accelerates the methylation of mercury in soil under sunlight, could increase the MeHg exposure from rice. Conventional hyphenated techniques used for mercury speciation analysis are usually too costly for most developing countries. Consequently, there is an increased interest in the development of sensitive and inexpensive methods for the speciation of mercury in rice. In this work, gas chromatography (GC) coupled to dielectric barrier discharge optical emission spectrometry (DBD-OES) was developed for the speciation analysis of mercury in rice. Prior to GC-DBD-OES analysis, mercury species were derivatized to their volatile species with NaBPh4 and preconcentrated by headspace solid phase microextraction using porous carbons. Limits of detection of 0.5 μg kg(-1) (0.16 ng), 0.75 μg kg(-1) (0.24 ng), and 1.0 μg kg(-1) (0.34 ng) were obtained for Hg(2+), CH3Hg(+), and CH3CH2Hg(+), respectively, with relative standard deviations (RSDs) better than 5.2% and 6.8% for one fiber or fiber-to-fiber mode, respectively. Recoveries of 90-105% were obtained for the rice samples, demonstrating the applicability of the proposed technique. Owing to the small size, low power, and low gas consumption of DBD-OES as well as efficient extraction of mercury species by porous carbons headspace solid phase micro-extraction, the proposed technique provides several advantages including compactness, cost-effectiveness, and potential to couple with miniature GC to accomplish the field speciation of mercury in rice compared to conventional hyphenated techniques.

  8. Studies of light emission by continuously sensitive avalanche chambers

    International Nuclear Information System (INIS)

    Charpak, G.; Dominik, W.; Fabre, J.P.; Gaudaen, J.; Sauli, F.; Suzuki, M.

    1988-01-01

    The optimal conditions for the optical recording of images of electron avalanches between parallel meshes have been studied. The emission spectra of gas mixtures have been investigated, where triethylamine (TEA), tetrakis(dimethylamine)ethylene (TMAE), and nitrogen, are used as the photon-emitting agents. For a given charge gain, the photon intensity decreases with electric field. This favours amplification between parallel meshes instead of wires. The use of intensified CCD cameras permits the recording of the local energy loss along the tracks. (orig.)

  9. Introduction of the continuous emission monitoring system at the thermal power plants of Hrvatska Elektroprivreda

    Energy Technology Data Exchange (ETDEWEB)

    Abramovic, B.; Jakovljevic, Z.; Stanic, Z. [EKONERG - Energy Research and Environmental Protection Institute Ltd. (Croatia)

    1999-07-01

    An overview of Croatian legislation in the field of air protection is given in this paper with special attention to the Decree on stationary sources emission limit values. The owner's obligations concerning first, occasional and continuous emission measurements are described, especially these of Hrvatska elektroprivreda (HEP) as the present owner of all thermal power plants in Croatia. The attention is drawn to HEP's activities on conducting of the emission measurement program, which has the introduction of Continuous Emission Monitoring System (CEM) as its final purpose. 3 figs., 5 tabs.

  10. Mercury and Air Toxic Element Impacts of Coal Combustion By-Product Disposal and Utilizaton

    Energy Technology Data Exchange (ETDEWEB)

    David Hassett; Loreal Heebink; Debra Pflughoeft-Hassett; Tera Buckley; Erick Zacher; Mei Xin; Mae Sexauer Gustin; Rob Jung

    2007-03-31

    being sorbed onto the CCB when exposed to ambient-temperature air. The environmental performance of the mercury captured on AC used as a sorbent for mercury emission control technologies indicated that current CCB management options will continue to be sufficiently protective of the environment, with the potential exception of exposure to elevated temperatures. The environmental performance of the other ATEs investigated indicated that current management options will be appropriate to the CCBs produced using AC in mercury emission controls.

  11. A new method to assess mercury emissions: a study of three coal-fired electric-generating power station configurations.

    Science.gov (United States)

    Boylan, Helen M; Cain, Randy D; Kingston, H M

    2003-11-01

    U.S. Environmental Protection Agency (EPA) Method 7473 for the analysis of mercury (Hg) by thermal decomposition, amalgamation, and atomic absorption spectroscopy has proved successful for use in Hg assessment at coal-fired power stations. In an analysis time of approximately 5 min per sample, this instrumental methodology can directly analyze total Hg--with no discrete sample preparation--in the solid matrices associated with a coal-fired power plant, including coal, fly ash, bottom ash, and flue gas desulfurization (FGD) material. This analysis technique was used to investigate Hg capture by coal combustion byproducts (CCBs) in three different coal-fired power plant configurations. Hg capture and associated emissions were estimated by partial mass balance. The station equipped with an FGD system demonstrated 68% capture on FGD material and an emissions estimate of 18% (11 kg/yr) of total Hg input. The power plant equipped with low oxides of nitrogen burners and an electrostatic precipitator (ESP) retained 43% on the fly ash and emitted 57% (51 kg/yr). The station equipped with conventional burners and an ESP retained less than 1% on the fly ash, emitting an estimated 99% (88 kg/yr) of Hg. Estimated Hg emissions demonstrate good agreement with EPA data for the power stations investigated.

  12. Trans-boundary movement of mercury in the Northeast Asian region predicted by CAMQ-Hg from anthropogenic emissions distribution

    Science.gov (United States)

    Sung, Jin-Ho; Roy, Debananda; Oh, Joo-Sung; Back, Seung-Ki; Jang, Ha-Na; Kim, Seong-Heon; Seo, Yong-Chil; Kim, Jeong-Hun; Lee, Chong Bum; Han, Young-Ji

    2018-05-01

    The percentage contribution of trans-boundary mercury (Hg) from China at different locations in South Korea was estimated from Hg anthropogenic emission distributions using the Hg dispersion model, CMAQ-Hg. This investigation quantifies the trans-boundary Hg emissions as contribution ratios. In addition, the long-range transportation frequency is also calculated, to verify inflow cases from China. The seasonal distribution of the Hg contribution ratio was found to be highest in winter (40%), followed by fall (16%). Seasonal observations of Hg inflow frequencies were estimated as 40%, 25%, 21%, and 4% in winter, fall, summer, and spring, respectively, at the same location. Such results would be produced by the wind generally blowing from the west and north-west with a speed of 5.0 m/s and 4.5 m/s, respectively, during winter and fall, around the study area. This study made an effort to quantify the trans-boundary Hg transport and to plot Hg anthropogenic emissions distribution in the region.

  13. Formation of Soluble Mercury Oxide Coatings: Transformation of Elemental Mercury in Soils.

    Science.gov (United States)

    Miller, Carrie L; Watson, David B; Lester, Brian P; Howe, Jane Y; Phillips, Debra H; He, Feng; Liang, Liyuan; Pierce, Eric M

    2015-10-20

    The impact of mercury (Hg) on human and ecological health has been known for decades. Although a treaty signed in 2013 by 147 nations regulates future large-scale mercury emissions, legacy Hg contamination exists worldwide and small-scale releases will continue. The fate of elemental mercury, Hg(0), lost to the subsurface and its potential chemical transformation that can lead to changes in speciation and mobility are poorly understood. Here, we show that Hg(0) beads interact with soil or manganese oxide solids and X-ray spectroscopic analysis indicates that the soluble mercury coatings are HgO. Dissolution studies show that, after reacting with a composite soil, >20 times more Hg is released into water from the coated beads than from a pure liquid mercury bead. An even larger, >700 times, release occurs from coated Hg(0) beads that have been reacted with manganese oxide, suggesting that manganese oxides are involved in the transformation of the Hg(0) beads and creation of the soluble mercury coatings. Although the coatings may inhibit Hg(0) evaporation, the high solubility of the coatings can enhance Hg(II) migration away from the Hg(0)-spill site and result in potential changes in mercury speciation in the soil and increased mercury mobility.

  14. Mercury from wildfires: Global emission inventories and sensitivity to 2000-2050 global change

    Science.gov (United States)

    Kumar, Aditya; Wu, Shiliang; Huang, Yaoxian; Liao, Hong; Kaplan, Jed O.

    2018-01-01

    We estimate the global Hg wildfire emissions for the 2000s and the potential impacts from the 2000-2050 changes in climate, land use and land cover and Hg anthropogenic emissions by combining statistical analysis with global data on vegetation type and coverage as well as fire activities. Global Hg wildfire emissions are estimated to be 612 Mg year-1. Africa is the dominant source region (43.8% of global emissions), followed by Eurasia (31%) and South America (16.6%). We find significant perturbations to wildfire emissions of Hg in the context of global change, driven by the projected changes in climate, land use and land cover and Hg anthropogenic emissions. 2000-2050 climate change could increase Hg emissions by 14% globally and regionally by 18% for South America, 14% for Africa and 13% for Eurasia. Projected changes in land use by 2050 could decrease the global Hg emissions from wildfires by 13% mainly driven by a decline in African emissions due to significant agricultural land expansion. Future land cover changes could lead to significant increases in Hg emissions over some regions (+32% North America, +14% Africa, +13% Eurasia). Potential enrichment of terrestrial ecosystems in 2050 in response to changes in Hg anthropogenic emissions could increase Hg wildfire emissions globally (+28%) and regionally (+19% North America, +20% South America, +24% Africa, +41% Eurasia). Our results indicate that the future evolution of climate, land use and land cover and Hg anthropogenic emissions are all important factors affecting Hg wildfire emissions in the coming decades.

  15. ?Smart COPVs? - Continued Successful Development of JSC IR&D Acoustic Emissions (AE) SHM Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Develop and apply promising quantitative pass/fail criteria to CPV using acoustic emission (AE) and lay the foundation for continued development of an automated...

  16. Continuous Emission Spectrum Measurement for Electron Temperature Determination in Low-Temperature Collisional Plasmas

    International Nuclear Information System (INIS)

    Liu Qiuyan; Li Hong; Chen Zhipeng; Xie Jinlin; Liu Wandong

    2011-01-01

    Continuous emission spectrum measurement is applied for the inconvenient diagnostics of low-temperature collisional plasmas. According to the physical mechanism of continuous emission, a simplified model is presented to analyze the spectrum in low temperature plasma. The validity of this model is discussed in a wide range of discharge parameters, including electron temperature and ionization degree. Through the simplified model, the continuous emission spectrum in a collisional argon internal inductively coupled plasma is experimentally measured to determine the electron temperature distribution for different gas pressures and radio-frequency powers. The inverse Abel transform is also applied for a better spatially resoluted results. Meanwhile, the result of the continuous emission spectrum measurement is compared to that of the electrostatic double probes, which indicates the effectiveness of this method. (low temperature plasma)

  17. Continuous Liquid-Sample Introduction for Bunsen Burner Atomic Emission Spectrometry.

    Science.gov (United States)

    Smith, Gregory D.; And Others

    1995-01-01

    Describes a laboratory-constructed atomic emission spectrometer with modular instrumentation components and a simple Bunsen burner atomizer with continuous sample introduction. A schematic diagram and sample data are provided. (DDR)

  18. Elemental mercury emission in the indoor environment due to broken compact fluorescent light (CFL) bulbs--paper

    Science.gov (United States)

    Compact fluorescent light (CFL) bulbs contain a few milligrams (mg) of elemental mercury. When a CFL breaks, some of the mercury is immediately released as elemental mercury vapor and the remainder is deposited on indoor surfaces with the bulb debris. In a controlled study design...

  19. Controlling mercury and selenium emissions from coal-fired combustors using a novel regenerable natural product

    Energy Technology Data Exchange (ETDEWEB)

    Schlager, R.J.; Marmaro, R.W.; Roberts, D.L. [ADA Technologies, Inc., Englewood, CO (United States)

    1995-11-01

    This program successfully demonstrated the key components that are needed for a practical, regenerable sorption process for removing and recovering mercury from flue gas streams: (1) a proprietary natural product removed mercuric chloride from synthetic flue gas, (2) several new noble metal sorbents were shown to capture elemental gas-phase mercury from synthetic coal combustion flue gas, and (3) both the natural product and the noble metal sorbents could be regenerated in the laboratory (chemical method for the natural product, thermal method for noble metal sorbents). Several sorbents were tested for their ability to collect selenium oxide during the program. These tests, however, were not definitive due to inconclusive analytical results. If follow-on testing is funded, the ability of the proposed sorbents to collect selenium and other metals will be evaluated during the field testing phase of the program. A preliminary economic analysis indicates that the cost of the process appears to be substantially less than the cost of the state-of-the-art method, namely injection of activated carbon, and it also appears to cost less than using noble metal sorbents alone.

  20. Continuous Emission Monitoring of Tetrafluoromethane Using Quantum Cascade Lasers

    Directory of Open Access Journals (Sweden)

    Peter Geiser

    2016-04-01

    Full Text Available Recent developments in quantum cascade lasers have enabled the development of new sensors for in-situ applications that have so far only been possible with extractive systems. In this work, a sensor is presented using a unique Wavelength Modulation Spectroscopy approach to measure tetrafluoromethane, a strong greenhouse gas. The sensor was characterized in a laboratory environment indicating a long-term detection limit of 20 ppb·m and a short-term value of well below 10 ppb·m. To demonstrate the feasibility of the sensor in a real-world environment, it was installed at an Alcoa aluminum smelter. A co-located Fourier Transform Infrared Spectrometer allowed direct comparison measurements of both systems. General agreement between the two methods was observed, leading to the conclusion that the developed in-situ quantum cascade laser based sensor has the potential to continuously measure tetrafluoromethane at aluminum smelters.

  1. Municipal actions to reduce mercury

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2005-03-15

    This paper presented proper management practices for products containing mercury. The measures can help reduce mercury releases, occupational exposure and mercury spills, thereby preventing impacts on human health and the environment. Despite mercury's toxic nature, many common products that contain mercury are commercially available. These include thermostats, thermometers, fluorescent lamps, pressure measuring devices, electrical switches and relays, and dental amalgam. Mercury emissions are also associated with base metal smelting, waste incineration and coal-fired power generation. Mercury in the environment is a global issue, because it can travel in the atmosphere on wind currents. The actions taken by municipalities to address the issue include reducing or eliminating mercury releases from internal municipal operations and sources within the community. This document provided guidance on how to develop a Municipal Mercury Elimination Policy and Plan that will help reduce mercury releases. It presented information and case studies that will help municipalities manage mercury-containing products found in municipal buildings and street lighting. Information on sources of mercury from within the community was presented along with case studies that can help municipalities determine where community action is needed to reduce mercury releases. The 5 modules of this document were intended to help municipalities identify priorities, timelines and budget requirements for mercury initiatives. It was emphasized that municipalities that adopt a Municipal Mercury Elimination Policy and Plan formally commit to reducing and eliminating mercury from the environment. tabs., figs.

  2. Sulfur, arsenic, fluorine and mercury emissions resulting from coal-washing byproducts: A critical component of China's emission inventory

    Science.gov (United States)

    Zhao, Chao; Luo, Kunli

    2017-03-01

    The coal-washing rate in China increased from 1991 to 2014 and shows a particular increase from ∼22% to ∼60% since 2002. However, few studies pay attention to the use and disposal of the coal-washing byproducts (CWBs). A preliminary estimate of the likely S, As, F and Hg contents and emissions from the combustion of CWBs in China was determined in this work. About 632 million tons of CWBs, including middling coal, flotation tailing coal and coal slime, were produced in China in 2014. About 4.03%, 20.80%, 1.48%, and 73.25% CWBs were used for thermal power, industry, domestic and discard. The mean S, As, F and Hg contents of CWBs are 1.52%, 14.04 mg/kg, 216.31 mg/kg and 0.27 mg/kg, respectively. SO2 emissions in 2014 from the combustion of CWBs were ∼5.76 million tons, similar to that released into the atmosphere by China's coal-fired power plants, accounting for ∼29% of the country's total SO2 emissions. Arsenic, F and Hg emissions from CWBs were 1 599.54, 61 575.07 and 77.16 tons, respectively. These emissions have become a critical component of air pollution in China.

  3. 40 CFR 60.1735 - Am I exempt from any appendix B or appendix F requirements to evaluate continuous emission...

    Science.gov (United States)

    2010-07-01

    ... systems? Yes, the accuracy tests for your sulfur dioxide continuous emission monitoring system require you to also evaluate your oxygen (or carbon dioxide) continuous emission monitoring system. Therefore, your oxygen (or carbon dioxide) continuous emission monitoring system is exempt from two requirements...

  4. 40 CFR 60.1240 - How do I make sure my continuous emission monitoring systems are operating correctly?

    Science.gov (United States)

    2010-07-01

    ... emission monitoring systems are operating correctly? 60.1240 Section 60.1240 Protection of Environment... Continuous Emission Monitoring § 60.1240 How do I make sure my continuous emission monitoring systems are operating correctly? (a) Conduct initial, daily, quarterly, and annual evaluations of your continuous...

  5. 40 CFR 60.1725 - How are the data from the continuous emission monitoring systems used?

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 6 2010-07-01 2010-07-01 false How are the data from the continuous emission monitoring systems used? 60.1725 Section 60.1725 Protection of Environment ENVIRONMENTAL... systems for sulfur dioxide, nitrogen oxides, and carbon monoxide to demonstrate continuous compliance with...

  6. 40 CFR 62.15180 - How are the data from the continuous emission monitoring systems used?

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 8 2010-07-01 2010-07-01 false How are the data from the continuous emission monitoring systems used? 62.15180 Section 62.15180 Protection of Environment ENVIRONMENTAL... systems for sulfur dioxide, nitrogen oxides, and carbon monoxide to demonstrate continuous compliance with...

  7. Biogeochemistry of mercury in a river-reservoir system: impact of an inactive chloralkali plant on the Holston River-Cherokee Reservoir, Virginia and Tennessee

    Energy Technology Data Exchange (ETDEWEB)

    Hildebrand, S. G.; Lindberg, S. E.; Turner, R. R.; Huckabee, J. W.; Strand, R. H.; Lund, J. R.; Andren, A. W.

    1980-08-01

    Elevated mercury concentrations in fish species from the North Fork of the Holston River were observed in the early 1970's. The source of the mercury was a chloralkali plant which had ceased operation in 1972. Mercury continues to be released to the river from two large (approx. 40-ha) waste disposal ponds at the plant site. This report presents results of a study of the emission of mercury to the environment from the abandoned waste ponds and of the distribution of mercury in water, sediment, and biota of the Holston River-Cherokee Reservoir System in Virginia and eastern Tennessee.

  8. Field Evaluation of MERCEM Mercury Emission Analyzer System at the Oak Ridge TSCA Incinerator East Tennessee Technology Park Oak Ridge, Tennessee

    Energy Technology Data Exchange (ETDEWEB)

    None

    2000-03-01

    The authors reached the following conclusions: (1) The two-month evaluation of the MERCEM total mercury monitor from Perkin Elmer provided a useful venue in determining the feasibility of using a CEM to measure total mercury in a saturated flue gas. (2) The MERCEM exhibited potential at a mixed waste incinerator to meet requirements proposed in PS12 under conditions of operation with liquid feeds only at stack mercury concentrations in the range of proposed MACT standards. (3) Performance of the MERCEM under conditions of incinerating solid and liquid wastes simultaneously was less reliable than while feeding liquid feeds only for the operating conditions and configuration of the host facility. (4) The permeation tube calibration method used in this test relied on the CEM internal volumetric and time constants to relate back to a concentration, whereas a compressed gas cylinder concentration is totally independent of the analyzer mass flowmeter and flowrates. (5) Mercury concentration in the compressed gas cylinders was fairly stable over a 5-month period. (6) The reliability of available reference materials was not fully demonstrated without further evaluation of their incorporation into routine operating procedures performed by facility personnel. (7) The degree of mercury control occurring in the TSCA Incinerator off-gas cleaning system could not be quantified from the data collected in this study. (8) It was possible to conduct the demonstration at a facility incinerating radioactively contaminated wastes and to release the equipment for later unrestricted use elsewhere. (9) Experience gained by this testing answered additional site-specific and general questions regarding the operation and maintenance of CEMs and their use in compliance monitoring of total mercury emissions from hazardous waste incinerators.

  9. Laboratory-scale evaluation of various sampling and analytical methods for determining mercury emissions from coal-fired power plants

    Energy Technology Data Exchange (ETDEWEB)

    Agbede, R.O.; Bochan, A.J.; Clements, J.L. [Advanced Technology Systems, Inc., Monroeville, PA (United States)] [and others

    1995-11-01

    Comparative bench-scale mercury sampling method tests were performed at the Advanced Technology Systems, Inc. (ATS) laboratories for EPA Method 101A, EPA Method 29 and the Ontario Hydro Method. Both blank and impinger spiking experiments were performed. The experimental results show that the ambient level of mercury in the ATS laboratory is at or below the detection limit (10 ng Hg) as measured by a cold vapor atomic absorption spectrophotometer (CVAAS) which was used to analyze the mercury samples. From the mercury spike studies, the following observations and findings were made. (a) The recovery of mercury spikes using EPA Method 101A was 104%. (b) The Ontario Hydro Method retains about 90% of mercury spikes in the first absorbing solution but has a total spike retention of 106%. As a result, the test data shows possible migration of spiked mercury from the first impinger solution (KCI) to the permanganate impingers. (c) For the EPA Method 29 solutions, when only the peroxide impingers were spiked, mercury recoveries were 65.6% for the peroxide impingers, 0.1% for the knockout impinger and 32.8% for the permanganate impingers with an average total mercury recovery of 98.4%. At press time, data was still being obtained for both the peroxide and permanganate impinger solution spikes. This and other data will be available at the presentation.

  10. Norwegian environmental policy: From continued increase of the emission of greenhouse gases to decrease

    International Nuclear Information System (INIS)

    2002-01-01

    According to Norway's Minister of the Environment, Norway will be one of the first among the industrialized countries to ratify the Kyoto Protocol on the emission of greenhouse gases. The tax on carbon dioxide will be continued and from 2005 there will be a national quota system for emission from sources not previously included. Several other measures have also been proposed. The current regulations admit 16 percent increase in the emissions up to 2008, while the measures proposed by the government and listed in this article may give a reduction of 12 percent

  11. 40 CFR 60.1730 - How do I make sure my continuous emission monitoring systems are operating correctly?

    Science.gov (United States)

    2010-07-01

    ... emission monitoring systems are operating correctly? 60.1730 Section 60.1730 Protection of Environment... continuous emission monitoring systems are operating correctly? (a) Conduct initial, daily, quarterly, and annual evaluations of your continuous emission monitoring systems that measure oxygen (or carbon dioxide...

  12. 40 CFR 62.15185 - How do I make sure my continuous emission monitoring systems are operating correctly?

    Science.gov (United States)

    2010-07-01

    ... emission monitoring systems are operating correctly? 62.15185 Section 62.15185 Protection of Environment... make sure my continuous emission monitoring systems are operating correctly? (a) Conduct initial, daily, quarterly, and annual evaluations of your continuous emission monitoring systems that measure oxygen (or...

  13. Convergence of carbon dioxide emissions in Chinese cities: A continuous dynamic distribution approach

    International Nuclear Information System (INIS)

    Wu, Jianxin; Wu, Yanrui; Guo, Xiumei; Cheong, Tsun Se

    2016-01-01

    This paper investigates the spatial dynamics of per capita carbon dioxide (CO 2 ) emissions in China. The analyses are conducted by employing a continuous dynamic distribution approach and panel data of 286 cities at the prefecture and above-prefecture level. The results show that per capita CO 2 emissions tend to converge during the sample period of 2002–2011. However, multimodality is found in the ergodic distribution of the full sample. It is also found that there is more persistence in cities with low per capita CO 2 emissions, and more mobility in cities with high per capita CO 2 emissions. The analyses also show that the dynamics of per capita CO 2 emissions are significantly different among various geographical, income and environmental policy groups. The conditional distribution analyses indicate that multimodality cannot be explained independently by any one of the two factors, namely geographical location or income level. The findings in this study may have important policy implications for CO 2 abatement in China. - Highlights: •Spatial dynamics of per capita carbon dioxide (CO 2 ) emissions in 286 Chinese cities. •A continuous dynamic distribution approach and panel data. •Multimodality is found in the ergodic distribution of the full sample. •Significantly different dynamics among various city groups.

  14. The CO2 emission permits market simulation using Continuous Double Auction

    International Nuclear Information System (INIS)

    Bartoszczuk, Pawel; Stanczak, Jaroslaw

    2016-01-01

    In this paper we consider the buying and selling prices of carbon dioxide (CO 2 ) emission permits in trading models with uncertainty. Permission prices, although usually omitted from standard models, may significantly influence the trading market. We thus construct a more realistic trade model. To do this, we introduced several important changes to the standard model, mainly we added The Continuous Double Action.

  15. 40 CFR 60.1230 - What continuous emission monitoring systems must I install for gaseous pollutants?

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 6 2010-07-01 2010-07-01 false What continuous emission monitoring... systems for oxygen (or carbon dioxide), sulfur dioxide, and carbon monoxide. If you operate a Class I... sulfur dioxide, nitrogen oxides, and oxygen (or carbon dioxide) at the outlet of the air pollution...

  16. 40 CFR Table 3 of Subpart Aaaa to... - Requirements for Validating Continuous Emission Monitoring Systems (CEMS)

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 6 2010-07-01 2010-07-01 false Requirements for Validating Continuous Emission Monitoring Systems (CEMS) 3 Table 3 of Subpart AAAA to Part 60 Protection of Environment... following methods in appendix A of this part to measure oxygen (or carbon dioxide) 1. Nitrogen Oxides (Class...

  17. Atmospheric mercury footprints of nations.

    Science.gov (United States)

    Liang, Sai; Wang, Yafei; Cinnirella, Sergio; Pirrone, Nicola

    2015-03-17

    The Minamata Convention was established to protect humans and the natural environment from the adverse effects of mercury emissions. A cogent assessment of mercury emissions is required to help implement the Minamata Convention. Here, we use an environmentally extended multi-regional input-output model to calculate atmospheric mercury footprints of nations based on upstream production (meaning direct emissions from the production activities of a nation), downstream production (meaning both direct and indirect emissions caused by the production activities of a nation), and consumption (meaning both direct and indirect emissions caused by final consumption of goods and services in a nation). Results show that nations function differently within global supply chains. Developed nations usually have larger consumption-based emissions than up- and downstream production-based emissions. India, South Korea, and Taiwan have larger downstream production-based emissions than their upstream production- and consumption-based emissions. Developed nations (e.g., United States, Japan, and Germany) are in part responsible for mercury emissions of developing nations (e.g., China, India, and Indonesia). Our findings indicate that global mercury abatement should focus on multiple stages of global supply chains. We propose three initiatives for global mercury abatement, comprising the establishment of mercury control technologies of upstream producers, productivity improvement of downstream producers, and behavior optimization of final consumers.

  18. Speciation of mercury compounds by gas chromatography with atomic emission detection. Simultaneous optimization of a headspace solid-phase microextraction and derivatization procedure by use of chemometric techniques

    Energy Technology Data Exchange (ETDEWEB)

    Carro, A.M.; Neira, I.; Rodil, R.; Lorenzo, R. A. [Univ. Santiago de Compostela (Spain). Dpto. Quimica Analitica, Nutricion y Bromatologia

    2003-06-01

    A method is proposed for the extraction and determination of organomercury compounds and Hg(II) in seawater samples by headspace solid-phase microextraction (HS-SPME) combined with capillary gas chromatography-microwave-induced plasma atomic emission spectrometry. The mercury species were derivatized with sodium tetraphenylborate, sorbed on a polydimethylsiloxane-coated fused-silica fibre, and desorbed in the injection port of the GC, in splitless mode. Experimental design methodology was used to evaluate the effect of six HS-SPME-derivatization variables: sample volume, NaBPh{sub 4} volume, pH, sorption time, extraction-derivatization temperature, and rate of stirring. Use of a multicriterion decision-making approach, with the desirability function, enabled determination of the optimum working conditions of the procedure for simultaneous analysis of three mercury species. (orig.)

  19. Evaluation of the Emission, Transport, and Deposition of Mercury, Fine Particulate Matter, and Arsenic from Coal-Based Power Plants in the Ohio River Valley Region

    Energy Technology Data Exchange (ETDEWEB)

    Kevin Crist

    2005-10-02

    Ohio University, in collaboration with CONSOL Energy, Advanced Technology Systems, Inc (ATS) and Atmospheric and Environmental Research, Inc. (AER) as subcontractors, is evaluating the impact of emissions from coal-fired power plants in the Ohio River Valley region as they relate to the transport and deposition of mercury, arsenic, and associated fine particulate matter. This evaluation will involve two interrelated areas of effort: ambient air monitoring and regional-scale modeling analysis. The scope of work for the ambient air monitoring will include the deployment of a surface air monitoring (SAM) station in southeastern Ohio. The SAM station will contain sampling equipment to collect and measure mercury (including speciated forms of mercury and wet and dry deposited mercury), arsenic, particulate matter (PM) mass, PM composition, and gaseous criteria pollutants (CO, NOx, SO{sub 2}, O{sub 3}, etc.). Laboratory analysis of time-integrated samples will be used to obtain chemical speciation of ambient PM composition and mercury in precipitation. Near-real-time measurements will be used to measure the ambient concentrations of PM mass and all gaseous species including Hg{sup 0} and RGM. Approximately of 18 months of field data will be collected at the SAM site to validate the proposed regional model simulations for episodic and seasonal model runs. The ambient air quality data will also provide mercury, arsenic, and fine particulate matter data that can be used by Ohio Valley industries to assess performance on multi-pollutant control systems. The scope of work for the modeling analysis will include (1) development of updated inventories of mercury and arsenic emissions from coal plants and other important sources in the modeled domain; (2) adapting an existing 3-D atmospheric chemical transport model to incorporate recent advancements in the understanding of mercury transformations in the atmosphere; (3) analyses of the flux of Hg0, RGM, arsenic, and fine

  20. Evaluation of the Emission, Transport, and Deposition of Mercury and Fine Particulate Matter from Coal-Based Power Plants in the Ohio River Valley Region

    Energy Technology Data Exchange (ETDEWEB)

    Kevin Crist

    2008-12-31

    As stated in the proposal: Ohio University, in collaboration with CONSOL Energy, Advanced Technology Systems, Inc (ATS) and Atmospheric and Environmental Research, Inc. (AER) as subcontractors, evaluated the impact of emissions from coal-fired power plants in the Ohio River Valley region as they relate to the transport and deposition of mercury and associated fine particulate matter. This evaluation involved two interrelated areas of effort: ambient air monitoring and regional-scale modeling analysis. The scope of work for the ambient air monitoring included the deployment of a surface air monitoring (SAM) station in southeastern Ohio. The SAM station contains sampling equipment to collect and measure mercury (including speciated forms of mercury and wet and dry deposited mercury), particulate matter (PM) mass, PM composition, and gaseous criteria pollutants (CO, NOx, SO2, O3, etc.). Laboratory analyses of time-integrated samples were used to obtain chemical speciation of ambient PM composition and mercury in precipitation. Nearreal- time measurements were used to measure the ambient concentrations of PM mass and all gaseous species including Hg0 and RGM. Approximately 30 months of field data were collected at the SAM site to validate the proposed regional model simulations for episodic and seasonal model runs. The ambient air quality data provides mercury, and fine particulate matter data that can be used by Ohio Valley industries to assess performance on multi-pollutant control systems. The scope of work for the modeling analysis includes (1) development of updated inventories of mercury emissions from coal plants and other important sources in the modeled domain; (2) adapting an existing 3-D atmospheric chemical transport model to incorporate recent advancements in the understanding of mercury transformations in the atmosphere; (3) analyses of the flux of Hg0, RGM, and fine particulate matter in the different sectors of the study region to identify key transport

  1. Mercury is Moon's brother

    International Nuclear Information System (INIS)

    Ksanfomalifi, L.V.

    1976-01-01

    The latest information on Mercury planet is presented obtained by studying the planet with the aid of radar and space vehicles. Rotation of Mercury about its axis has been discovered; within 2/3 of its year it executes a complete revolution about its axis. In images obtained by the ''Mariner-10'' Mercurys surface differs little from that of the Moon. The ''Mariner-10'' has also discovered the Mercurys atmosphere, which consists of extremely rarefied helium. The helium is continuously supplied to the planet by the solar wind. The Mercury's magnetic field has been discovered, whose strength is 35 x 10 -4 at the Equator and 70 x 10 -4 E at the poles. The inclination of the dipole axis to the Mercury's rotation axis is 7 deg

  2. Emissions of forest floor and mineral soil carbon, nitrogen and mercury pools and relationships with fire severity for the Pagami Creek Fire in the Boreal Forest of northern Minnesota

    Science.gov (United States)

    Randall K. Kolka; Brian R. Sturtevant; Jessica R. Miesel; Aditya Singh; Peter T. Wolter; Shawn Fraver; Thomas M. DeSutter; Phil A. Townsend

    2017-01-01

    Forest fires cause large emissions of C (carbon), N (nitrogen) and Hg (mercury) to the atmosphere and thus have important implications for global warming (e.g. via CO2 and N2O emissions), anthropogenic fertilisation of natural ecosystems (e.g. via N deposition), and bioaccumulation of harmful metals in aquatic and...

  3. Towards continuous global measurements and optimal emission estimates of NF3

    Science.gov (United States)

    Arnold, T.; Muhle, J.; Salameh, P.; Harth, C.; Ivy, D. J.; Weiss, R. F.

    2011-12-01

    We present an analytical method for the continuous in situ measurement of nitrogen trifluoride (NF3) - an anthropogenic gas with a global warming potential of ~16800 over a 100 year time horizon. NF3 is not included in national reporting emissions inventories under the United Nations Framework Convention on Climate Change (UNFCCC). However, it is a rapidly emerging greenhouse gas due to emission from a growing number of manufacturing facilities with increasing output and modern end-use applications, namely in microcircuit etching, and in production of flat panel displays and thin-film photovoltaic cells. Despite success in measuring the most volatile long lived halogenated species such as CF4, the Medusa preconcentration GC/MS system of Miller et al. (2008) is unable to detect NF3 under remote operation. Using altered techniques of gas separation and chromatography after initial preconcentration, we are now able to make continuous atmospheric measurements of NF3 with average precisions NF3 produced. Emission factors are shown to have reduced over the last decade; however, rising production and end-use have caused the average global atmospheric concentration to double between 2005 and 2011 i.e. half the atmospheric NF3 present today originates from emissions after 2005. Finally we show the first continuous in situ measurements from La Jolla, California, illustrating how global deployment of our technique could improve the temporal and spatial scale of NF3 'top-down' emission estimates over the coming years. These measurements will be important for independent verification of emissions should NF3 be regulated under a new climate treaty.

  4. Characterizing mercury emissions from a coal-fired power plant utilizing a venturi wet FGD system

    Energy Technology Data Exchange (ETDEWEB)

    Vann Bush, P.; Dismukes, E.B.; Fowler, W.K.

    1995-11-01

    Southern Research Institute (SRI) conducted a test program at a coal-fired utility plant from October 24 to October 29, 1994. The test schedule was chosen to permit us to collect samples during a period of consecutive days with a constant coal source. SRI collected the samples required to measured concentrations of anions and trace elements around two scrubber modules and in the stack. Anions of interest were CI{sup -}, F{sup -}, and SO{sub 4}{sup =}. We analyzed samples for five major elements (Al, Ca, Fe, Mg, and Ti) and 16 trace elements (As, B, Ba, Be, Cd, Co, Cr, Cu, Hg, Mn, Mo, Ni, Pb, Sb, Se, and V). SRI made measurements across two scrubber modules, each treating nominally 20% of the total effluent from the boiler. Across one module we examined the effects of changes in the liquid-to-gas ratio (L/G) on the efficiency with which the scrubber removes trace elements and anions from the flue gas. Across another module we examined the effects of slurry pH on the removal of trace elements and anions from the flue gas. Measurements in the stack quantified emissions rates of anions and trace elements.

  5. Measurement of particle emission in automobil exhaust - application of continuous radiometric aerosol measurement to the emission of diesel engines

    International Nuclear Information System (INIS)

    Krasenbrink, A.; Georgi, B.

    1989-01-01

    The well-known method of measuring continuously dust by β-absorption is transferred to the problem of particle emission in automobile exhaust. With two similar dust-monitors FH62 having different sampling air flow rates and two low-pressure impactors the reliability of radiometric mass determination was verified. First static experiments with diesel soot showed the necessity of a dilution system, a new mass calibration with regard to the changed β-absorptivity and a quicker calculation of concentration for realtime measurements. (orig.) [de

  6. A review of global environmental mercury processes in response to human and natural perturbations: Changes of emissions, climate, and land use.

    Science.gov (United States)

    Obrist, Daniel; Kirk, Jane L; Zhang, Lei; Sunderland, Elsie M; Jiskra, Martin; Selin, Noelle E

    2018-03-01

    We review recent progress in our understanding of the global cycling of mercury (Hg), including best estimates of Hg concentrations and pool sizes in major environmental compartments and exchange processes within and between these reservoirs. Recent advances include the availability of new global datasets covering areas of the world where environmental Hg data were previously lacking; integration of these data into global and regional models is continually improving estimates of global Hg cycling. New analytical techniques, such as Hg stable isotope characterization, provide novel constraints of sources and transformation processes. The major global Hg reservoirs that are, and continue to be, affected by anthropogenic activities include the atmosphere (4.4-5.3 Gt), terrestrial environments (particularly soils: 250-1000 Gg), and aquatic ecosystems (e.g., oceans: 270-450 Gg). Declines in anthropogenic Hg emissions between 1990 and 2010 have led to declines in atmospheric Hg 0 concentrations and Hg II wet deposition in Europe and the US (- 1.5 to - 2.2% per year). Smaller atmospheric Hg 0 declines (- 0.2% per year) have been reported in high northern latitudes, but not in the southern hemisphere, while increasing atmospheric Hg loads are still reported in East Asia. New observations and updated models now suggest high concentrations of oxidized Hg II in the tropical and subtropical free troposphere where deep convection can scavenge these Hg II reservoirs. As a result, up to 50% of total global wet Hg II deposition has been predicted to occur to tropical oceans. Ocean Hg 0 evasion is a large source of present-day atmospheric Hg (approximately 2900 Mg/year; range 1900-4200 Mg/year). Enhanced seawater Hg 0 levels suggest enhanced Hg 0 ocean evasion in the intertropical convergence zone, which may be linked to high Hg II deposition. Estimates of gaseous Hg 0 emissions to the atmosphere over land, long considered a critical Hg source, have been revised downward, and

  7. What are the Connections between Mercury and CFLs?

    Science.gov (United States)

    Small amounts of mercury vapor can be released when CFLs break or are improperly disposed of. Despite these emissions, the use of CFLs actually helps reduce total mercury emissions in the U.S. because of their significant energy savings.

  8. 40 CFR 60.3039 - How do I make sure my continuous emission monitoring systems are operating correctly?

    Science.gov (United States)

    2010-07-01

    ... emission monitoring systems are operating correctly? 60.3039 Section 60.3039 Protection of Environment... emission monitoring systems are operating correctly? (a) Conduct initial, daily, quarterly, and annual evaluations of your continuous emission monitoring systems that measure carbon monoxide and oxygen. (b...

  9. MESSENGER at Mercury: Early Orbital Operations

    Science.gov (United States)

    McNutt, Ralph L., Jr; Solomon, Sean C.; Bedini, Peter D.; Anderson, Brian J.; Blewett, David T.; Evans, Larry G.; Gold, Robert E.; Krimigis, Stamatios M.; Murchie, Scott L.; Nittler, Larry R.; hide

    2013-01-01

    The MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) spacecraft, launched in August 2004 under NASA's Discovery Program, was inserted into orbit about the planet Mercury in March 2011. MESSENGER's three flybys of Mercury in 2008-2009 marked the first spacecraft visits to the innermost planet since the Mariner 10 flybys in 1974-1975. The unprecedented orbital operations are yielding new insights into the nature and evolution of Mercury. The scientific questions that frame the MESSENGER mission led to the mission measurement objectives to be achieved by the seven payload instruments and the radio science experiment. Interweaving the full set of required orbital observations in a manner that maximizes the opportunity to satisfy all mission objectives and yet meet stringent spacecraft pointing and thermal constraints was a complex optimization problem that was solved with a software tool that simulates science observations and tracks progress toward meeting each objective. The final orbital observation plan, the outcome of that optimization process, meets all mission objectives. MESSENGER's Mercury Dual Imaging System is acquiring a global monochromatic image mosaic at better than 90% coverage and at least 250 m average resolution, a global color image mosaic at better than 90% coverage and at least 1 km average resolution, and global stereo imaging at better than 80% coverage and at least 250 m average resolution. Higher-resolution images are also being acquired of targeted areas. The elemental remote sensing instruments, including the Gamma-Ray and Neutron Spectrometer and the X-Ray Spectrometer, are being operated nearly continuously and will establish the average surface abundances of most major elements. The Visible and Infrared Spectrograph channel of MESSENGER's Mercury Atmospheric and Surface Composition Spectrometer is acquiring a global map of spectral reflectance from 300 to 1450 nm wavelength at a range of incidence and emission

  10. Continuously tunable sub-half-wavelength localization via coherent control of spontaneous emission

    International Nuclear Information System (INIS)

    Wang Fei; Tan Xin-Yu; Gong Cheng; Shi Wen-Xing

    2012-01-01

    We propose a continuously tunable method of sub-half-wavelength localization via the coherent control of the spontaneous emission of a four-level Y-type atomic system, which is coupled to three strong coupling fields including a standing-wave field together with a weak probe field. It is shown that the sub-half-wavelength atomic localization is realized for both resonance and off-resonance cases. Furthermore, by varying the probe detuning in succession, the positions of the two localization peaks are tuned continuously within a wide range of probe field frequencies, which provides convenience for the realization of sub-half-wavelength atomic localization experimentally

  11. Pennsylvania's proposed continuous emission monitoring system data telemetry requirements for municipal, hospital and infectious waste incinerators

    International Nuclear Information System (INIS)

    Nazzaro, J.C.

    1988-01-01

    This paper reports on the Pennsylvania Department of Environmental Resources which has established minimum plan approval, criteria which require certain affected sources to provide the Department with access to continuous emission monitoring (CEM) data via telephone line computer link or other approved means of transfer. The Department has specified formats for logging of CEM data to computer media, a general data telemetry access protocol, floppy disk reporting formats and hardcopy reporting formats

  12. Atmospheric Mercury Transport Across Southern Lake Michigan: Influence from the Chicago/Gary Urban Area

    Science.gov (United States)

    Gratz, L. E.; Keeler, G. J.; Dvonch, J. T.

    2008-12-01

    The local and regional impacts of mercury emissions from major urban and industrial areas are critical to quantify in order to further understand mercury cycling in the environment. The Chicago/Gary urban area is one such location in which mercury emissions from industrial sources are significant and regional mercury transport needs to be further examined. Speciated atmospheric mercury was measured in Chicago, IL and Holland, MI from July to November 2007 to better characterize the impact of Chicago/Gary on southwest Michigan. Previous work under the 1994-1995 Lake Michigan Mass Balance Study (LMMBS) indicated that the highest levels of mercury deposition in southwest Michigan occurred with transport from the Chicago/Gary area, particularly with rapid transport where less mercury was deposited close to sources(1). However, at that time it was not possible to measure reactive gas phase mercury (RGM), a highly-soluble form of mercury in industrial emissions that is readily removed from the atmosphere. Since the LMMBS, the development of speciated mercury systems has made it possible to continuously monitor gaseous elemental mercury (Hg0), particulate mercury (HgP), and RGM. These measurements are useful for understanding atmospheric mercury chemistry and differentiating between local and regional source impacts due to the different behaviors of reactive and elemental mercury. Results from 2007 show that, on average, Hg0 and HgP were 1.5 times higher and RGM was 2 times higher in Chicago than in Holland. Mean mercury wet deposition was nearly 3 times higher in Chicago than in Holland. Meteorological analysis indicates that transport across the lake from Chicago/Gary occurred frequently during the study. Additional measurements of O3, SO2, meteorological parameters, event mercury and trace element precipitation samples, and modeled back-trajectories are used to discern regional transport events from local deposition and characterize the impact of the Chicago/Gary urban

  13. 40 CFR Table 1 to Subpart Ffff of... - Emission Limits and Work Practice Standards for Continuous Process Vents

    Science.gov (United States)

    2010-07-01

    ...—Emission Limits and Work Practice Standards for Continuous Process Vents As required in § 63.2455, you must... 40 Protection of Environment 12 2010-07-01 2010-07-01 true Emission Limits and Work Practice Standards for Continuous Process Vents 1 Table 1 to Subpart FFFF of Part 63 Protection of Environment...

  14. 40 CFR 60.1245 - Am I exempt from any appendix B or appendix F requirements to evaluate continuous emission...

    Science.gov (United States)

    2010-07-01

    ... your sulfur dioxide continuous emission monitoring system require you to also evaluate your oxygen (or carbon dioxide) continuous emission monitoring system. Therefore, your oxygen (or carbon dioxide... 40 Protection of Environment 6 2010-07-01 2010-07-01 false Am I exempt from any appendix B or...

  15. 40 CFR 63.6003 - How do I monitor and collect data to demonstrate continuous compliance with the emission limits...

    Science.gov (United States)

    2010-07-01

    ... demonstrate continuous compliance with the emission limits for tire production affected sources? 63.6003... compliance with the emission limits for tire production affected sources? (a) You must monitor and collect..., calibration checks and required zero and span adjustments), you must monitor continuously (or collect data at...

  16. Mercury's exosphere: observations during MESSENGER's First Mercury flyby.

    Science.gov (United States)

    McClintock, William E; Bradley, E Todd; Vervack, Ronald J; Killen, Rosemary M; Sprague, Ann L; Izenberg, Noam R; Solomon, Sean C

    2008-07-04

    During MESSENGER's first Mercury flyby, the Mercury Atmospheric and Surface Composition Spectrometer measured Mercury's exospheric emissions, including those from the antisunward sodium tail, calcium and sodium close to the planet, and hydrogen at high altitudes on the dayside. Spatial variations indicate that multiple source and loss processes generate and maintain the exosphere. Energetic processes connected to the solar wind and magnetospheric interaction with the planet likely played an important role in determining the distributions of exospheric species during the flyby.

  17. Peru Mercury Inventory 2006

    Science.gov (United States)

    Brooks, William E.; Sandoval, Esteban; Yepez, Miguel A.; Howard, Howell

    2007-01-01

    In 2004, a specific need for data on mercury use in South America was indicated by the United Nations Environmental Programme-Chemicals (UNEP-Chemicals) at a workshop on regional mercury pollution that took place in Buenos Aires, Argentina. Mercury has long been mined and used in South America for artisanal gold mining and imported for chlor-alkali production, dental amalgam, and other uses. The U.S. Geological Survey (USGS) provides information on domestic and international mercury production, trade, prices, sources, and recycling in its annual Minerals Yearbook mercury chapter. Therefore, in response to UNEP-Chemicals, the USGS, in collaboration with the Economic Section of the U.S. Embassy, Lima, has herein compiled data on Peru's exports, imports, and byproduct production of mercury. Peru was selected for this inventory because it has a 2000-year history of mercury production and use, and continues today as an important source of mercury for the global market, as a byproduct from its gold mines. Peru is a regional distributor of imported mercury and user of mercury for artisanal gold mining and chlor-alkali production. Peruvian customs data showed that 22 metric tons (t) of byproduct mercury was exported to the United States in 2006. Transshipped mercury was exported to Brazil (1 t), Colombia (1 t), and Guyana (1 t). Mercury was imported from the United States (54 t), Spain (19 t), and Kyrgyzstan (8 t) in 2006 and was used for artisanal gold mining, chlor-alkali production, dental amalgam, or transshipment to other countries in the region. Site visits and interviews provided information on the use and disposition of mercury for artisanal gold mining and other uses. Peru also imports mercury-containing batteries, electronics and computers, fluorescent lamps, and thermometers. In 2006, Peru imported approximately 1,900 t of a wide variety of fluorescent lamps; however, the mercury contained in these lamps, a minimum of approximately 76 kilograms (kg), and in

  18. Comparative study of gas-analyzing systems designed for continuous monitoring of TPP emissions

    Science.gov (United States)

    Kondrat'eva, O. E.; Roslyakov, P. V.

    2017-06-01

    Determining the composition of combustion products is important in terms of both control of emissions into the atmosphere from thermal power plants and optimization of fuel combustion processes in electric power plants. For this purpose, the concentration of oxygen, carbon monoxide, nitrogen, and sulfur oxides in flue gases is monitored; in case of solid fuel combustion, fly ash concentration is monitored as well. According to the new nature conservation law in Russia, all large TPPs shall be equipped with continuous emission monitoring and measurement systems (CEMMS) into the atmosphere. In order to ensure the continuous monitoring of pollutant emissions, direct round-the-clock measurements are conducted with the use of either domestically produced or imported gas analyzers and analysis systems, the operation of which is based on various physicochemical methods and which can be generally used when introducing CEMMS. Depending on the type and purposes of measurement, various kinds of instruments having different features may be used. This article represents a comparative study of gas-analysis systems for measuring the content of polluting substances in exhaust gases based on various physical and physicochemical analysis methods. It lists basic characteristics of the methods commonly applied in the area of gas analysis. It is proven that, considering the necessity of the long-term, continuous operation of gas analyzers for monitoring and measurement of pollutant emissions into the atmosphere, as well as the requirements for reliability and independence from aggressive components and temperature of the gas flow, it is preferable to use optical gas analyzers for the aforementioned purposes. In order to reduce the costs of equipment comprising a CEMMS at a TPP and optimize the combustion processes, electrochemical and thermomagnetic gas analyzers may also be used.

  19. Continuous reduction of cyclic adsorbed and desorbed NO(x) in diesel emission using nonthermal plasma.

    Science.gov (United States)

    Kuwahara, Takuya; Nakaguchi, Harunobu; Kuroki, Tomoyuki; Okubo, Masaaki

    2016-05-05

    Considering the recent stringent regulations governing diesel NO(x) emission, an aftertreatment system for the reduction of NO(x) in the exhaust gas has been proposed and studied. The proposed system is a hybrid method combining nonthermal plasma and NOx adsorbent. The system does not require precious metal catalysts or harmful chemicals such as urea and ammonia. In the present system, NO(x) in diesel emission is treated by adsorption and desorption by adsorbent as well as nonthermal plasma reduction. In addition, the remaining NO(x) in the adsorbent is desorbed again in the supplied air by residual heat. The desorbed NO(x) in air recirculates into the intake of the engine, and this process, i.e., exhaust gas components' recirculation (EGCR) achieves NO(x) reduction. Alternate utilization of two adsorption chambers in the system can achieve high-efficiency NO(x) removal continuously. An experiment with a stationary diesel engine for electric power generation demonstrates an energy efficiency of 154 g(NO2)/kWh for NO(x) removal and continuous NO(x) reduction of 70.3%. Considering the regulation against diesel emission in Japan, i.e., the new regulation to be imposed on vehicles of 3.5-7.5 ton since 2016, the present aftertreatment system fulfills the requirement with only 1.0% of engine power. Copyright © 2016. Published by Elsevier B.V.

  20. Mercury in Canadian crude oil

    International Nuclear Information System (INIS)

    Hollebone, B.P.

    2005-01-01

    Estimates for average mercury concentrations in crude oil range widely from 10 ng/g of oil to 3,500 ng/g of oil. With such a broad range of estimates, it is difficult to determine the contributions of the petroleum sector to the total budget of mercury emissions. In response to concerns that the combustion of petroleum products may be a major source of air-borne mercury pollution, Environment Canada and the Canadian Petroleum Products Institute has undertaken a survey of the average total mercury concentration in crude oil processed in Canadian refineries. In order to calculate the potential upper limit of total mercury in all refined products, samples of more than 30 different types of crude oil collected from refineries were measured for their concentration of mercury as it enters into a refinery before processing. High temperature combustion, cold vapour atomic absorption and cold vapour atomic fluorescence were the techniques used to quantify mercury in the samples. The results of the study provide information on the total mass of mercury present in crude oil processed in Canada each year. Results can be used to determine the impact of vehicle exhaust emissions to the overall Canadian mercury emission budget. 17 refs., 2 tabs., 2 figs

  1. Mercury emissions from flooded soils and sediments in Germany are an underestimated problem: challenges for reliable risk assessments and management strategies

    Directory of Open Access Journals (Sweden)

    Rinklebe J.

    2013-04-01

    Full Text Available Environmental pollution by mercury is a world-wide problem. Particularly floodplain ecosystems are frequently affected. One example is the Elbe River in Germany and its catchment areas; large amounts of Hg from a range of anthropogenic and geogenic sources have been accumulated in the soils of these floodplains. They serve as sink for Hg originating from the surface water of adjacent river. Today, the vastly elevated Hg contents of the floodplain soils at the Elbe River often exceed even the action values of the German Soil Conservation Law. This is especially important as Hg polluted areas at the Elbe River achieve several hundred square kilometres. Thus, authorities are coerced by law to conduct an appropriate risk assessment and to implement practical actions to eliminate or reduce environmental problems. A reliable risk assessment particularly with view to organisms (vegetation as green fodder and hay production, grazing and wild animals to avoid the transfer of Hg into the human food chain, requires an authentic determination of Hg fluxes and their dynamics since gaseous emissions from soil to atmosphere are an important pathway of Hg. However, reliable estimates of Hg fluxes from the highly polluted floodplain soils at the Elbe River and its tributaries, and its influencing factors are scarce. For this purpose, we have developed a new method to determine mercury emissions from soils at various sites. Our objectives were i to quantify seasonal variations of total gaseous mercury (TGM fluxes for floodplain soils at the Elbe River, ii to provide insights into physico-chemical processes regulating these TGM fluxes, and iii to quantify the impacts of the controlling factors soil temperature and soil water content on Hg volatilization from a typical contaminated floodplain soil within soil microcosm experiments under various controlled temperature and moisture conditions. Our study provides insight into TGM emissions from highly Hg

  2. Changes in distortion product oto-acoustic emissions after exposure to continuous and impulsive noise

    DEFF Research Database (Denmark)

    de Toro, Miguel Angel Aranda; Ordoñez, Rodrigo Pizarro; Hammershøi, Dorte

    2012-01-01

    Temporary changes in the hearing of human subjects were monitored with distortion product otoacoustic emissions (DPOAEs) after control sound exposures in a laboratory. The objectives of the experiment were to investigate whether the +5~dB penalty for impulsiveness used in international standards...... and legislation correlates to a higher risk of hearing damage. Subjects were exposed to two types of binaural recordings consisting of a continuous broad-band noise-exposure normalized to LEX,8h = 80~dB and the interaction of the previous stimulus with a noise of impulsive character normalized to LEX,8h = 75 + 5...

  3. Watt-Level Continuous-Wave Emission from a Bi-Functional Quantum Cascade Laser/Detector

    Science.gov (United States)

    2017-04-18

    ed em is si on sp ec tra Wavenumbers (cm−1) Wavelength (µm) subthreshold 1480 mA 1530 mA 1600 mA 2000 mA 2500 mA 3000 mA Figure 3: Emission spectra of...cally authorized by the U.S. Government may violate any copyrights that exist in this work. Watt-level continuous-wave emission from a bi-functional...facet continuous wave emission at 15◦C. Apart from the general performance benets, this enables sensing techiques which rely on continuous wave

  4. Natural and anthropogenic mercury sources and their impact on the air-surface exchange of mercury on regional and global scales

    Energy Technology Data Exchange (ETDEWEB)

    Ebinghaus, R.; Tripathi, R.M.; Wallschlaeger, D.; Lindberg, S.E.

    1998-12-31

    Mercury is outstanding among the global environmental pollutants of continuing concern. Especially in the last decade of the 20th century, environmental scientists, legislators, politicians and the public have become aware of mercury pollution in the global environment. It has often been suggested that anthropogenic emissions are leading to a general increase in mercury on local, regional, and global scales (Lindqvist et al. 1991; Expert Panel 1994). Mercury is emitted into the atmosphere from a number of natural as well as anthropogenic sources. In contrast with most of the other heavy metals, mercury and many of its compounds behave exceptionally in the environment due to their volatility and capability for methylation. Long-range atmospheric transport of mercury, its transformation to more toxic methylmercury compounds, and their bioaccumulation in the aquatic foodchain have motivated intensive research on mercury as a pollutant of global concern. Mercury takes part in a number of complex environmental cycles, and special interest is focused on the aquatic-biological and the atmospheric cycles. (orig./SR)

  5. Mercury and Your Health

    Science.gov (United States)

    ... the Risk of Exposure to Mercury Learn About Mercury What is Mercury What is Metallic mercury? Toxicological Profile ToxFAQs Mercury Resources CDC’s National Biomonitoring Program Factsheet on Mercury ...

  6. 40 CFR 60.1750 - What is the minimum amount of monitoring data I must collect with my continuous emission...

    Science.gov (United States)

    2010-07-01

    ... equivalent carbon dioxide level). Use the 1-hour averages of oxygen (or carbon dioxide) data from your continuous emission monitoring system to determine the actual oxygen (or carbon dioxide) level and to calculate emissions at 7 percent oxygen (or the equivalent carbon dioxide level). (b) Obtain at least two...

  7. 40 CFR 60.1260 - What is the minimum amount of monitoring data I must collect with my continuous emission...

    Science.gov (United States)

    2010-07-01

    ... equivalent carbon dioxide level). Use the 1-hour averages of oxygen (or carbon dioxide) data from your continuous emission monitoring system to determine the actual oxygen (or carbon dioxide) level and to calculate emissions at 7 percent oxygen (or the equivalent carbon dioxide level). (b) Obtain at least two...

  8. 40 CFR 62.15205 - What minimum amount of monitoring data must I collect with my continuous emission monitoring...

    Science.gov (United States)

    2010-07-01

    ...). Use the 1-hour averages of oxygen (or carbon dioxide) data from your continuous emission monitoring system to determine the actual oxygen (or carbon dioxide) level and to calculate emissions at 7 percent... averages for sulfur dioxide, nitrogen oxides (Class I municipal waste combustion units only), and carbon...

  9. 40 CFR 60.2940 - How do I make sure my continuous emission monitoring systems are operating correctly?

    Science.gov (United States)

    2010-07-01

    ... emission monitoring systems are operating correctly? 60.2940 Section 60.2940 Protection of Environment... monitoring systems are operating correctly? (a) Conduct initial, daily, quarterly, and annual evaluations of your continuous emission monitoring systems that measure carbon monoxide and oxygen. (b) Complete your...

  10. PATHOLOIGCAL EFFECTS OF DIETARY METHYL MERCURY IN AMERICAN KESTRELS ( FALCO SPARVERIUS)

    Science.gov (United States)

    Methyl mercury in aquatic food webs poses significant health risks to both wildlife and humans. One primary source of mercury contamination for both aquatic and terrestrial systems is atmospheric deposition of inorganic mercury from industrial emissions. Once in the environment, ...

  11. Long-term monitoring of atmospheric total gaseous mercury (TGM) at a remote site in Mt. Changbai area, northeastern China

    OpenAIRE

    X. W. Fu; X. Feng; L. H. Shang; S. F. Wang; H. Zhang

    2012-01-01

    Total gaseous mercury (TGM) was continuously monitored at a remote site (CBS) in the Mt. Changbai area, northeastern China biennially from 24 October 2008 to 31 October 2010. The overall mean TGM concentration was 1.60 ± 0.51 ng m−3, which is lower than those reported from remote sites in eastern, southwestern and western China, indicating a relatively low regional anthropogenic mercury (Hg) emission intensity in northeastern China. Measurements at a site in ...

  12. Two years of measurements of atmospheric total gaseous mercury (TGM) at a remote site in Mt. Changbai area, Northeastern China

    OpenAIRE

    X. W. Fu; X. Feng; L. H. Shang; S. F. Wang; H. Zhang

    2012-01-01

    Total gaseous mercury (TGM) was continuously monitored at a remote site (CBS) in Mt. Changbai area, Northeastern China from 24 October 2008 to 31 October 2010. The overall mean TGM concentration was 1.60±0.51 ng m−3, which is lower than those reported from remote sites in Eastern, Southwestern, and Western China, indicating a relatively lower regional anthropogenic mercury (Hg) emission intensity in Northeastern China. Measurements at a site in the vicinity (...

  13. Elimination of mercury in health care facilities.

    Science.gov (United States)

    2000-03-01

    Mercury is a persistent, bioaccumulative toxin that has been linked to numerous health effects in humans and wildlife. It is a potent neurotoxin that may also harm the brain, kidneys, and lungs. Unborn children and young infants are at particular risk for brain damage from mercury exposure. Hospitals' use of mercury in chemical solutions, thermometers, blood pressure gauges, batteries, and fluorescent lamps makes these facilities large contributors to the overall emission of mercury into the environment. Most hospitals recognize the dangers of mercury. In a recent survey, four out of five hospitals stated that they have policies in place to eliminate the use of mercury-containing products. Sixty-two percent of them require vendors to disclose the presence of mercury in chemicals that the hospitals purchase. Only 12 percent distribute mercury-containing thermometers to new parents. Ninety-two percent teach their employees about the health and environmental effects of mercury, and 46 percent teach all employees how to clean up mercury spills. However, the same study showed that many hospitals have not implemented their policies. Forty-two percent were not aware whether they still purchased items containing mercury. In addition, 49 percent still purchase mercury thermometers, 44 percent purchase mercury gastrointestinal diagnostic equipment, and 64 percent still purchase mercury lab thermometers.

  14. Forest land cover continues to exacerbate freshwater acidification despite decline in sulphate emissions

    International Nuclear Information System (INIS)

    Dunford, Robert W.; Donoghue, Daniel N.M.; Burt, Tim P.

    2012-01-01

    Evidence from a multi-date regional-scale analysis of both high-flow and annual-average water quality data from Galloway, south-west Scotland, demonstrates that forest land cover continues to exacerbate freshwater acidification. This is in spite of significant reductions in airborne pollutants. The relationship between freshwater sulphate and forest cover has decreased from 1996 to 2006 indicating a decrease in pollutant scavenging. The relationship between forest cover and freshwater acidity (pH) is, however, still present over the same period, and does not show conclusive signs of having declined. Furthermore, evidence for forest cover contributing to a chlorine bias in marine ion capture suggests that forest scavenging of sea-salts may mean that the forest acidification effect may continue in the absence of anthropogenic pollutant inputs, particularly in coastal areas. - Highlights: ► Forest cover and water chemistry remain linked despite decreased sulphate emissions. ► Forest cover has significant relationships SO 4 2− , Cl − , Na + , pH, ANC and Na:Cl ratio. ► Forest cover: pH relationships shows some evidence of decline 1996–2006. ► Forest cover: freshwater sulphate relationships show evidence of decline 1996–2006. ► Natural forest-mechanisms may exacerbate acidification, particularly sea-salt scavenging. - Relationships between forest land cover and freshwater pH continue to be evident despite declines in anthropogenic pollutant sulphate deposition; sea-salt scavenging may play a role.

  15. Microplasma source based on a dielectric barrier discharge for the determination of mercury by atomic emission spectrometry.

    Science.gov (United States)

    Zhu, Zhenli; Chan, George C-Y; Ray, Steven J; Zhang, Xinrong; Hieftje, Gary M

    2008-11-15

    A low-power, atmospheric-pressure microplasma source based on a dielectric barrier discharge (DBD) has been developed for use in atomic emission spectrometry. The small plasma (0.6 mm x 1 mm x 10 mm) is generated within a glass cell by using electrodes that do not contact the plasma. Powered by an inexpensive ozone generator, the discharge ignites spontaneously, can be easily sustained in Ar or He at gas flow rates ranging from 5 to 200 mL min(-1), and requires less than 1 W of power. The effect of operating parameters such as plasma gas identity, plasma gas flow rate, and residual water vapor on the DBD source performance has been investigated. The plasma can be operated without removal of residual water vapor, permitting it to be directly coupled with cold vapor generation sample introduction. The spectral background of the source is quite clean in the range from 200 to 260 nm with low continuum and structured components. The DBD source has been applied to the determination of Hg by continuous-flow, cold vapor generation and offers detection limits from 14 (He-DBD) to 43 pg mL(-1) (Ar-DBD) without removal of the residual moisture. The use of flow injection with the He-DBD permits measurement of Hg with a 7.2 pg limit of detection, and with repetitive injections having an RSD of <2% for a 10 ng mL(-1) standard.

  16. 40 CFR 60.45Da - Standard for mercury (Hg).

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 6 2010-07-01 2010-07-01 false Standard for mercury (Hg). 60.45Da... for mercury (Hg). (a) For each coal-fired electric utility steam generating unit other than an IGCC... gases that contain mercury (Hg) emissions in excess of each Hg emissions limit in paragraphs (a)(1...

  17. Got Mercury?

    Science.gov (United States)

    Meyers, Valerie E.; McCoy, J. Torin; Garcia, Hector D.; James, John T.

    2009-01-01

    Many of the operational and payload lighting units used in various spacecraft contain elemental mercury. If these devices were damaged on-orbit, elemental mercury could be released into the cabin. Although there are plans to replace operational units with alternate light sources, such as LEDs, that do not contain mercury, mercury-containing lamps efficiently produce high quality illumination and may never be completely replaced on orbit. Therefore, exposure to elemental mercury during spaceflight will remain possible and represents a toxicological hazard. Elemental mercury is a liquid metal that vaporizes slowly at room temperature. However, it may be completely vaporized at the elevated operating temperatures of lamps. Although liquid mercury is not readily absorbed through the skin or digestive tract, mercury vapors are efficiently absorbed through the respiratory tract. Therefore, the amount of mercury in the vapor form must be estimated. For mercury releases from lamps that are not being operated, we utilized a study conducted by the New Jersey Department of Environmental Quality to calculate the amount of mercury vapor expected to form over a 2-week period. For longer missions and for mercury releases occurring when lamps are operating, we conservatively assumed complete volatilization of the available mercury. Because current spacecraft environmental control systems are unable to remove mercury vapors, both short-term and long-term exposures to mercury vapors are possible. Acute exposure to high concentrations of mercury vapors can cause irritation of the respiratory tract and behavioral symptoms, such as irritability and hyperactivity. Chronic exposure can result in damage to the nervous system (tremors, memory loss, insomnia, etc.) and kidneys (proteinurea). Therefore, the JSC Toxicology Group recommends that stringent safety controls and verifications (vibrational testing, etc.) be applied to any hardware that contains elemental mercury that could yield

  18. LIGO/Virgo GW170817: Chandra X-ray Emission Continues to Rise 156 Days Post-Merger

    Science.gov (United States)

    Haggard, Daryl; Nynka, Melania; Ruan, John J.; Evans, Phil; Kalogera, Vicky

    2018-01-01

    We have obtained new X-ray observations of GW170817 via Chandra Director's Discretionary Time (PI: Wilkes, Program Number 19408607). The X-ray counterpart to GW170817/GRB170817A/SSS17a continues to be detected and the X-ray emission continues to brighten approximately 156 days after the neutron star merger.

  19. Mineral resource of the month: mercury

    Science.gov (United States)

    ,

    2012-01-01

    The article offers information on mercury, a mineral commodity used in industrial and small-scale gold mining applications. Mercury has been reported to be used for amalgamation with gold since the Roman times. Mercury from cinnabar from Almadén, Spain has been used by Romans and has been continued to be used through the Middle Ages and the Colonial era.

  20. Mercury in the environment : a review

    International Nuclear Information System (INIS)

    Goodarzi, F.

    2000-01-01

    Both geogenic and anthropogenic sources are responsible for the input of mercury into the environment. However, mercury comes mostly from geogenic sources and is found naturally in air, water and soil. Crustal degassing results in emission of mercury into the atmosphere. Mercury in water and soil is due mostly to input from sedimentary rocks. Mercury in lake sediments is related mainly to input by country rock and anthropogenic activities such as agriculture. The mercury content of coal is similar to or less than the amount found in the earths crust. Natural charcoal is also able to capture mercury at low temperature combustion. The amount of mercury emitted from the stack of coal-fired power plants is related to the nature of the milled coal and its mineralogical and elemental content. Mercury emissions originating from the combustion of coal from electric utility power plants are considered to be among the greatest contributors to global mercury air emissions. In order to quantify the impact the electric power industry has on the environment, information regarding mercury concentrations in coal and their speciation is needed. For this reason the author examined the behaviour of mercury in three coal samples ashed at increasing temperatures. Mercury removal from coal-fired power plants ranges from 10 to 50 per cent by fabric filters and 20 to 95 per cent by FGD systems. This data will help in regulating emissions of hazardous air pollutants from electric utility steam generating units and will potentially provide insight into the industry's contribution to the global mercury burden. 50 refs

  1. Continuous-Wave Stimulated Emission Depletion Microscope for Imaging Actin Cytoskeleton in Fixed and Live Cells

    Directory of Open Access Journals (Sweden)

    Bhanu Neupane

    2015-09-01

    Full Text Available Stimulated emission depletion (STED microscopy provides a new opportunity to study fine sub-cellular structures and highly dynamic cellular processes, which are challenging to observe using conventional optical microscopy. Using actin as an example, we explored the feasibility of using a continuous wave (CW-STED microscope to study the fine structure and dynamics in fixed and live cells. Actin plays an important role in cellular processes, whose functioning involves dynamic formation and reorganization of fine structures of actin filaments. Frequently used confocal fluorescence and STED microscopy dyes were employed to image fixed PC-12 cells (dyed with phalloidin- fluorescein isothiocyante and live rat chondrosarcoma cells (RCS transfected with actin-green fluorescent protein (GFP. Compared to conventional confocal fluorescence microscopy, CW-STED microscopy shows improved spatial resolution in both fixed and live cells. We were able to monitor cell morphology changes continuously; however, the number of repetitive analyses were limited primarily by the dyes used in these experiments and could be improved with the use of dyes less susceptible to photobleaching. In conclusion, CW-STED may disclose new information for biological systems with a proper characteristic length scale. The challenges of using CW-STED microscopy to study cell structures are discussed.

  2. A Plasma Based OES-CRDS Dual-mode Portable Spectrometer for Trace Element Detection: Emission and Ringdown Measurements of Mercury

    Science.gov (United States)

    Sahay, Peeyush; Scherrer, Susan; Wang, Chuji

    2012-10-01

    Design and development of a plasma based optical emission spectroscopy-cavity ringdown spectroscopy (OES-CRDS) dual-mode portable spectrometer for in situ monitoring of trace elements is described. A microwave plasma torch (MPT) has been utilized, which serves both as an atomization and excitation source for the two modes, viz. OES and CRDS, of the spectrometer. Operation of both modes of the instrument is demonstrated with initial measurements of elemental mercury (Hg). A detection limit of 44 ng mL-1 for Hg at 253.65 nm was determined with the emission mode of the instrument. Severe radiation trapping of 253.65 nm line hampers the measurement of Hg in higher concentration region (> 50 μg ml-1). Therefore, a different wavelength, 365.01 nm, is suggested to measure Hg in that region. Ringdown measurements of the metastable 6s6p ^3P0 state of Hg in the plasma using a 404.65 nm palm size diode laser was conducted to demonstrate the CRDS mode of the instrument. Along with being portable, dual-mode, and self-calibrated, the instrument is capable of measuring a wide range of concentration ranging from sub ng mL-1 to several μg ml-1 for a number of elements.

  3. TA [2] Continuous, regional methane emissions estimates in northern Pennsylvania gas fields using atmospheric inversions

    Energy Technology Data Exchange (ETDEWEB)

    Lauvaux, Thomas [Pennsylvania State Univ., University Park, PA (United States)

    2017-12-31

    Natural Gas (NG) production activities in the northeastern Marcellus shale have significantly increased in the last decade, possibly releasing large amounts of methane (CH4) into the atmosphere from the operations at the productions sites and during the processing and transmission steps of the natural gas chain. Based on an intensive aircraft survey, leakage rates from the NG production were quantified in May 2015 and found to be in the order of 0.5% of the total production, higher than reported by the Environmental Protection Agency (EPA) but below the usually observed leakage rates over the shale gases in the US. Thanks to the high production rates on average at each well, leakage rates normalized by production appeared to be low in the northeastern Marcellus shale. This result confirms that natural gas production using unconventional techniques in this region is emitting relatively less CH4 into the atmosphere than other shale reservoirs. The low emissions rate can be explained in part by the high productivity of wells drilled across the northeastern Marcellus region. We demonstrated here that atmospheric monitoring techniques can provide an independent quantification of NG leakage rates using aircraft measurements. The CH4 analyzers were successfully calibrated at four sites across the region, measuring continuously the atmospheric CH4 mixing ratios and isotopic 13Ch4. Our preliminary findings confirm the low leakage rates from tower data collected over September 2015 to November 2016 compared to the aircraft mass-balance estimates in may 2015. However, several episodes revealing large releases of natural gas over several weeks showed that temporal variations in the emissions of CH4 may increase the actual leakage rate over longer time periods.

  4. Toxecon Retrofit for Mercury and Mulit-Pollutant Control on Three 90-MW Coal-Fired Boilers

    Energy Technology Data Exchange (ETDEWEB)

    Steven Derenne; Robin Stewart

    2009-09-30

    This U.S. Department of Energy (DOE) Clean Coal Power Initiative (CCPI) project was based on a cooperative agreement between We Energies and the DOE Office of Fossil Energy's National Energy Technology Laboratory (NETL) to design, install, evaluate, and demonstrate the EPRI-patented TOXECON{trademark} air pollution control process. Project partners included Cummins & Barnard, ADA-ES, and the Electric Power Research Institute (EPRI). The primary goal of this project was to reduce mercury emissions from three 90-MW units that burn Powder River Basin coal at the We Energies Presque Isle Power Plant in Marquette, Michigan. Additional goals were to reduce nitrogen oxide (NO{sub x}), sulfur dioxide (SO{sub 2}), and particulate matter emissions; allow reuse and sale of fly ash; advance commercialization of the technology; demonstrate a reliable mercury continuous emission monitor (CEM) suitable for use at power plants; and demonstrate recovery of mercury from the sorbent. Mercury was controlled by injection of activated carbon upstream of the TOXECON{trademark} baghouse, which achieved more than 90% removal on average over a 44-month period. During a two-week test involving trona injection, SO{sub 2} emissions were reduced by 70%, although no coincident removal of NOx was achieved. The TOXECON{trademark} baghouse also provided enhanced particulate control, particularly during startup of the boilers. On this project, mercury CEMs were developed and tested in collaboration with Thermo Fisher Scientific, resulting in a reliable CEM that could be used in the power plant environment and that could measure mercury as low as 0.1 {micro}g/m{sup 3}. Sorbents were injected downstream of the primary particulate collection device, allowing for continued sale and beneficial use of captured fly ash. Two methods for recovering mercury using thermal desorption on the TOXECON{trademark} PAC/ash mixture were successfully tested during this program. Two methods for using the TOXECON

  5. Continuous and recurrent testing of acoustic emission sensors; Kontinuierliche und wiederkehrende Pruefung von Schallemissionssensoren

    Energy Technology Data Exchange (ETDEWEB)

    Sause, Markus G.R.; Schmitt, Stefan; Potstada, Philipp [Augsburg Univ. (Germany). Inst. fuer Materials Resource Management, Mechanical Engineering

    2017-08-01

    In many fields of application of acoustic emission, the testing can lead to a lasting change in the sensor characteristics. This can be caused by mechanical damage, thermal stress or use under aggressive environmental conditions. Irrespective of visually testable damages of the sensors, a shift in the spectral sensitivity, a reduction in the absolute sensitivity or a reduction in the signal-to-noise ratio can occur. During the test, this requires a possibility to periodically check the sensors, including the coupling aids used. For recurring testing, recommendations are given in Directive SE 02 ''Verification of acoustic emission sensors and their coupling in the laboratory''. This paper discusses possibilities for continuous monitoring of the sensors during the test and presents an application example for the partly automated recurring testing of acoustic emission sensors using Directive SE 02. For this purpose, a test stand for the supply of the sensors to be tested was constructed and the signal recording and data reduction implemented in freely available software programs. The operating principle is demonstrated using selected case studies. [German] In vielen Anwendungsbereichen der Schallemission kann es bei der Pruefung zu einer nachhaltigen Veraenderung der Sensorcharakteristik kommen. Dies kann durch mechanische Beschaedigung, thermische Belastung oder Verwendung unter aggressiven Umweltbedingungen geschehen. Unabhaengig von visuell pruefbaren Beschaedigungen der Sensoren kann es dabei zu einer Verschiebung der spektralen Empfindlichkeit, einer Verringerung der absoluten Empfindlichkeit oder einer Erniedrigung des Signal-Rausch Verhaeltnis kommen. Bei der Pruefung erfordert dies eine Moeglichkeit zur periodischen Ueberpruefung der Sensoren inklusive der verwendeten Koppelhilfsmittel. Fuer die wiederkehrende Pruefung finden sich entsprechende Handlungsempfehlungen in der Richtlinie SE 02 ''Verifizierung von

  6. Coupling atmospheric mercury isotope ratios and meteorology to identify sources of mercury impacting a coastal urban-industrial region near Pensacola, Florida, USA

    Science.gov (United States)

    Demers, Jason D.; Sherman, Laura S.; Blum, Joel D.; Marsik, Frank J.; Dvonch, J. Timothy

    2015-10-01

    Identifying the anthropogenic and natural sources of mercury (Hg) emissions contributing to atmospheric mercury on local, regional, and global scales continues to be a grand challenge. The relative importance of various direct anthropogenic emissions of mercury, in addition to natural geologic sources and reemission of previously released and deposited mercury, differs regionally and temporally. In this study, we used local-scale, mesoscale, and synoptic-scale meteorological analysis to couple the isotopic composition of ambient atmospheric mercury with potential sources of mercury contributing to a coastal urban-industrial setting near a coal-fired power plant in Pensacola, Florida, USA. We were able to broadly discern four influences on the isotopic composition of ambient atmospheric mercury impacting this coastal urban-industrial region: (1) local to regional urban-industrial anthropogenic emissions (mean δ202Hg = 0.44 ± 0.05‰, 1SD, n = 3), (2) marine-influenced sources derived from the Gulf of Mexico (mean δ202Hg = 0.77 ± 0.15‰, 1SD, n = 4), (3) continental sources associated with north-northwesterly flows from within the planetary boundary layer (mean δ202Hg = 0.65 ± 0.04‰, 1SD, n = 3), and (4) continental sources associated with north-northeasterly flows at higher altitudes (i.e., 2000 m above ground level; mean δ202Hg = 1.10 ± 0.21‰, 1SD, n = 8). Overall, these data, in conjunction with previous studies, suggest that the background global atmospheric mercury pool is characterized by moderately positive δ202Hg values; that urban-industrial emissions drive the isotopic composition of ambient atmospheric mercury toward lower δ202Hg values; and that air-surface exchange dynamics across vegetation and soils of terrestrial ecosystems drive the isotopic composition of ambient atmospheric mercury toward higher positive δ202Hg values. The data further suggest that mass-independent fractionation (MIF) of both even-mass- and odd-mass-number isotopes

  7. Spatiotemporal patterns of mercury accumulation in lake sediments of western North America

    Science.gov (United States)

    Drevnick, Paul; Cooke, Colin A.; Barraza, Daniella; Blais, Jules M.; Coale, Kenneth; Cumming, Brian F.; Curtis, Chris; Das, Biplob; Donahue, William F.; Eagles-Smith, Collin A.; Engstrom, Daniel R.; Fitzgerald, William F.; Furl, Chad V.; Gray, John R.; Hall, Roland I.; Jackson, Togwell A.; Laird, Kathleen R.; Lockhart, W. Lyle; Macdonald, Robie W.; Mast, M. Alisa; Mathieu, Callie; Muir, Derek C.G.; Outridge, Peter; Reinemann, Scott; Rothenberg, Sarah E.; Ruiz-Fernandex, Ana Carolina; St. Louis, V.L.; Sanders, Rhea; Sanei, Hamed; Skierszkan, Elliott; Van Metre, Peter C.; Veverica, Timothy; Wiklund, Johan A.; Wolfe, Brent B.

    2016-01-01

    For the Western North America Mercury Synthesis, we compiled mercury records from 165 dated sediment cores from 138 natural lakes across western North America. Lake sediments are accepted as faithful recorders of historical mercury accumulation rates, and regional and sub-regional temporal and spatial trends were analyzed with descriptive and inferential statistics. Mercury accumulation rates in sediments have increased, on average, four times (4×) from 1850 to 2000 and continue to increase by approximately 0.2 μg/m2 per year. Lakes with the greatest increases were influenced by the Flin Flon smelter, followed by lakes directly affected by mining and wastewater discharges. Of lakes not directly affected by point sources, there is a clear separation in mercury accumulation rates between lakes with no/little watershed development and lakes with extensive watershed development for agricultural and/or residential purposes. Lakes in the latter group exhibited a sharp increase in mercury accumulation rates with human settlement, stabilizing after 1950 at five times (5×) 1850 rates. Mercury accumulation rates in lakes with no/little watershed development were controlled primarily by relative watershed size prior to 1850, and since have exhibited modest increases (in absolute terms and compared to that described above) associated with (regional and global) industrialization. A sub-regional analysis highlighted that in the ecoregion Northwestern Forest Mountains, mercury deposited to watersheds is delivered to lakes. Research is warranted to understand whether mountainous watersheds act as permanent sinks for mercury or if export of “legacy” mercury (deposited in years past) will delay recovery when/if emissions reductions are achieved.

  8. Reference Atmosphere for Mercury

    Science.gov (United States)

    Killen, Rosemary M.

    2002-01-01

    We propose that Ar-40 measured in the lunar atmosphere and that in Mercury's atmosphere is due to current diffusion into connected pore space within the crust. Higher temperatures at Mercury, along with more rapid loss from the atmosphere will lead to a smaller column abundance of argon at Mercury than at the Moon, given the same crustal abundance of potassium. Because the noble gas abundance in the Hermean atmosphere represents current effusion, it is a direct measure of the crustal potassium abundance. Ar-40 in the atmospheres of the planets is a measure of potassium abundance in the interiors, since Ar-40 is a product of radiogenic decay of K-40 by electron capture with the subsequent emission of a 1.46 eV gamma-ray. Although the Ar-40 in the Earth's atmosphere is expected to have accumulated since the late bombardment, Ar-40 in the atmospheres of Mercury and the Moon is eroded quickly by photoionization and electron impact ionization. Thus, the argon content in the exospheres of the Moon and Mercury is representative of current effusion rather than accumulation over the lifetime of the planet.

  9. Shallow tillage generates higher N2O emissions: results of continuous chamber-based measurement in a winter wheat field.

    Science.gov (United States)

    Broux, François; Lognoul, Margaux; Theodorakopoulos, Nicolas; Hiel, Marie-Pierre; Bodson, Bernard; Heinesch, Bernard; Aubinet, Marc

    2017-04-01

    Agriculture is one of the most important contributors to GHG emission, notably through fertilized croplands. Though, few publications have studied simultaneously and through continuous measurement the N2O and CO2 emissions in cultivated lands. We conducted this study to assess the effect of farming practices and climate on both N2O and CO2 emissions from a winter wheat crop. The experiment was held in an experimental field in the loamy region in Belgium from March 2016 till crop harvest in August 2016. The fluxes were measured on two nearby parcels in a winter wheat field with restitution of the residues from previous crop. For the past 8 years, one parcel was subjected to a shallow tillage (ST, 10 cm depth) and the other one to a conventional tillage (CT, 25 cm depth). On each parcel, the emissions are assessed with homemade automated closed chambers. Measurement continuity and good temporal resolution (one mean flux every 4 hours) of the system allowed a fine detection and quantification of the emission peaks which usually represent the major part of N2O fluxes. In addition to gas fluxes, soil water content and temperature were measured continuously. Soil samples were taken regularly to determine soil pH, soil organic carbon and nitrogen pools (total, NO3- and NH4+) and study microbial diversity and nitrification/denitrification gene expression. Unexpectedly, results showed N2O emissions twice as large in the ST parcel as in the CT parcel. On the contrary, less important CO2 emissions were observed under ST. Several emission peaks of N2O were observed during the measurement period. The peaks occurred after fertilization events and seemed to be triggered by an elevation of soil water content. Interesting links could be made between soil NH4-N and NO3-N pools and N2O emissions. Nitrification being the main process originating the fluxes was suggested on the one hand by the temporal evolution of nitrogen pools and N2O emissions and on the other hand by the relation

  10. Gravity Wave Emission by Spontaneous Imbalance of Baroclinic Waves in the Continuously Stratified Rotating Annulus

    Science.gov (United States)

    Borchert, Sebastian; Achatz, Ulrich; Rieper, Felix; Fruman, Mark

    2013-04-01

    We use a numerical model of the classic differentially heated rotating annulus experiment to study the spontaneous emission of gravity waves (GWs) from jet stream imbalances, which is a major source of these waves in the atmosphere for which no satisfactory parameterization exists. Atmospheric observations are the main tool for the testing and verification of theoretical concepts but have their limitations. Given their specific potential for yielding reproducible data and for studying process dependence on external system parameters, laboratory experiments are an invaluable complementary tool. Experiments with a rotating annulus exhibiting a jet modulated by large-scale waves due to baroclinic instability have already been used to study GWs: Williams et al (2008) observed spontaneously emitted interfacial GWs in a two-layer flow, and Jacoby et al (2011) detected GWs emitted from boundary-layer instabilities in a differentially heated rotating annulus. Employing a finite-volume code for the numerical simulation of a continuously stratified liquid in a differentially heated rotating annulus, we here investigate the GWs in a wide and shallow annulus with relatively large temperature difference between inner and outer cylinder walls. In this atmosphere-like regime where the Brunt-Vaisala frequency is larger than the inertial frequency, various analyses suggest a distinct gravity wave activity. To identify regions of GW emission we decompose the flow into the geostrophic and ageostrophic part through the inversion of the quasi-geostrophic potential vorticity (e.g. Verkley, 2009). The analysis of the geostrophic sources of the ageostrophic flow indicates that, in addition to boundary layer instabilities, spontaneous imbalance in the jet region acts as an important source mechanism. Jacoby, T. N. L., Read, P. L., Williams, P. D. and Young, R. M. B., 2011: Generation of inertia-gravity waves in the rotating thermal annulus by a localised boundary layer instability. Geophys

  11. Worldwide trend of atmospheric mercury since 1995

    Directory of Open Access Journals (Sweden)

    F. Slemr

    2011-05-01

    Full Text Available Concern about the adverse effects of mercury on human health and ecosystems has led to tightening emission controls since the mid 1980s. But the resulting mercury emissions reductions in many parts of the world are believed to be offset or even surpassed by the increasing emissions in rapidly industrializing countries. Consequently, concentrations of atmospheric mercury are expected to remain roughly constant. Here we show that the worldwide atmospheric mercury concentrations have decreased by about 20 to 38 % since 1996 as indicated by long-term monitoring at stations in the Southern and Northern Hemispheres combined with intermittent measurements of latitudinal distribution over the Atlantic Ocean. The total reduction of the atmospheric mercury burden of this magnitude within 14 years is unusually large among most atmospheric trace gases and is at odds with the current mercury emission inventories with nearly constant anthropogenic emissions over this period. This suggests a major shift in the biogeochemical cycle of mercury including oceans and soil reservoirs. Decreasing reemissions from the legacy of historical mercury emissions are the most likely explanation for this decline since the hypothesis of an accelerated oxidation rate of elemental mercury in the atmosphere is not supported by the observed trends of other trace gases. Acidification of oceans, climate change, excess nutrient input and pollution may also contribute by their impact on the biogeochemistry of ocean and soils. Consequently, models of the atmospheric mercury cycle have to include soil and ocean mercury pools and their dynamics to be able to make projections of future trends.

  12. Use of Zeeman atomic absorption spectroscopy for the measurement of mercury in oil shale gases

    Energy Technology Data Exchange (ETDEWEB)

    Girvin, D.C.; Hadeishi, T.; Fox, J.P.

    1979-03-01

    A technique to continuously measure total mercury in a gas stream in the presence of high concentrations of organics, smoke, oil mist, and other interfering substances is described. The technique employees Zeeman atomic absorption (ZAA) spectroscopy as the mercury detector, which has been successfully used to measure mercury in oil shale offgases. The instrument consists of a light source which provides the 2537 A mercury emission line; a furnace-absorption tube assembly where the sample is vaporized and swept into the light path and a detector which converts the signal into an ac voltage for processing. Sample gas is heated to 900/sup 0/C in the furnace-absorption tube assembly aligned with the optical axis of the ZAA spectrometer. The 2537 A mercury emission line (..pi..) and a reference line (sigma) are generated by a single discharge lamp operated in a 15 kG magnetic field. The difference between the ..pi.. and sigma components is taken by a lock-in-amplifier and converted to a signal which is proportional to the amount of mercury in the gas.

  13. 40 CFR Table 4 of Subpart Bbbbbbb... - Continuous Compliance Demonstration Methods With the Emission Reduction and PM Concentration...

    Science.gov (United States)

    2010-07-01

    ... Methods With the Emission Reduction and PM Concentration Requirements 4 Table 4 of Subpart BBBBBBB of Part... Concentration Requirements If you are demonstrating compliance with the * * * You must demonstrate continuous...) or an outlet concentration of 0.03 gr/dscf or less Using one of the following monitoring methods:a. A...

  14. 40 CFR Appendix D to Part 52 - Determination of Sulfur Dioxide Emissions From Stationary Sources by Continuous Monitors

    Science.gov (United States)

    2010-07-01

    ... the event that significant repair work is performed in the system, the company shall demonstrate to... which a measurement system is expected to operate within certain performance specifications without... dioxide by a continuously operating emission measurement system. Performance specifications for the...

  15. 40 CFR Appendix to Subpart Eee of... - Quality Assurance Procedures for Continuous Emissions Monitors Used for Hazardous Waste Combustors

    Science.gov (United States)

    2010-07-01

    ... determination and adjustment of CEMS. 4. Integration of CEMS with the automatic waste feed cutoff (AWFCO) system... Continuous Emissions Monitors Used for Hazardous Waste Combustors Appendix to Subpart EEE of Part 63... Hazardous Air Pollutants from Hazardous Waste Combustors Pt. 63, Subpt. EEE, App. Appendix to Subpart EEE of...

  16. 40 CFR Table 6 to Subpart Bbbb of... - Model Rule-Requirements for Validating Continuous Emission Monitoring Systems (CEMS)

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 6 2010-07-01 2010-07-01 false Model Rule-Requirements for Validating Continuous Emission Monitoring Systems (CEMS) 6 Table 6 to Subpart BBBB of Part 60 Protection of Environment... levels Use the following methods in appendix A of this part to measure oxygen (or carbon dioxide) 1...

  17. Modelling and Evaluation of Environmental Impact due to Continuous Emissions of the Severonickel Plant (Kola Peninsula)

    Science.gov (United States)

    Mahura, A.; Gonzalez-Aparicio, I.; Nuterman, R.; Baklanov, A.

    2012-04-01

    In this study, evaluation of potential impact - through concentration, deposition and loadings patterns - on population and environment due to continuous anthropogenic emissions (on example of sulfates) of the Cu-Ni smelters of the Russian North is given. To estimate impact, the Danish Emergency Response Model for Atmosphere (DERMA) was employed to perform long-term simulations of air concentration, time integrated air concentration (TIAC), dry (DD) and wet (WD) deposition patterns resulting from continuous emissions of the Severonickel smelters located on the Kola Peninsula (Murmansk region, Russia). To perform such simulations the 3D meteorological fields (from the European Center for Medium-Range Weather Forecasts, ECMWF) for the year 2000 were used as input. For simplicity, it has been assumed that normalized releases of sulfates from smelters location occurred at a constant rate every day. For each daily release the atmospheric transport, dispersion, dry and wet deposition due to removal processes were estimated during 10 day interval. Output from these long-term simulations is an essential input for evaluation of impact, doses, risks, and short- and long-term consequences, etc. Detailed analyses of simulated concentration and deposition fields allowed evaluating the spatial and temporal variability of resulted patterns on different scales. Temporal variability of both wet and dry deposition as well as their contribution into total deposition have been estimated. On an annual scale, the concentration and deposition patterns were estimated for the most populated cities of the North-West Russia. The modeled annual fields were also integrated into GIS environment as well as layers with population density (from the Center for International Earth Science Information Network, CIESIN) and standard administrative division of the North-West Russia and bordering countries. Furthermore, the estimation of deposited amounts (loadings) of sulfates for selected regions of

  18. Mercury emission and plant uptake of trace elements during early stage of soil amendment using flue gas desulfurization materials.

    Science.gov (United States)

    A pilot-scale field study was carried out to investigate the distribution of Hg and other selected elements in the three potential mitigation pathways, i.e., emission to ambient air, uptake by surface vegetation (i.e., grass), and rainfall infiltration, after flue gas desulfurization (FGD) material ...

  19. Mercury pollution in Malaysia.

    Science.gov (United States)

    Hajeb, Parvaneh; Jinap, S; Ismail, Ahmad; Mahyudin, Nor Ainy

    2012-01-01

    Although several studies have been published on levels of mercury contamination of the environment, and of food and human tissues in Peninsular Malaysia, there is a serious dearth of research that has been performed in East Malaysia (Sabah and Sarawak). Industry is rapidly developing in East Malaysia, and, hence, there is a need for establishing baseline levels of mercury contamination in environmental media in that part of the country by performing monitoring studies. Residues of total mercury and inorganic in food samples have been determined in nearly all previous studies that have been conducted; however, few researchers have analyzed samples for the presence of methlymercury residues. Because methylmercury is the most toxic form of mercury, and because there is a growing public awareness of the risk posed by methylmercury exposure that is associated with fish and seafood consumption, further monitoring studies on methylmercury in food are also essential. From the results of previous studies, it is obvious that the economic development in Malaysia, in recent years, has affected the aquatic environment of the country. Primary areas of environmental concern are centered on the rivers of the west Peninsular Malaysian coast, and the coastal waters of the Straits of Malacca, wherein industrial activities are rapidly expanding. The sources of existing mercury input to both of these areas of Malaysia should be studied and identified. Considering the high levels of mercury that now exists in human tissues, efforts should be continued, and accelerated in the future, if possible, to monitor mercury contamination levels in the coastal states, and particularly along the west Peninsular Malaysian coast. Most studies that have been carried out on mercury residues in environmental samples are dated, having been conducted 20-30 years ago; therefore, the need to collect much more and more current data is urgent. Furthermore, establishing baseline levels of mercury exposure to

  20. EM TASK 24 - DEVELOPMENT OF AN IN SITU INSTRUMENT FOR MEASURING MERCURY IN A GAS STREAM

    International Nuclear Information System (INIS)

    Laudal, Dennis L.

    2001-01-01

    As part of its overall Environmental Management Program, the U.S. Department of Energy (DOE) has developed thermal and incineration processes for treating hazardous mixed wastes. These mixed wastes often contain mercury that is released into the atmosphere during the incineration process. The U.S. Environmental Protection Agency (EPA), as well as many states, clearly views mercury emissions from incinerators and combustion systems as a potential human health problem (1). Although validated batch measurement methods such as EPA Method 29, the Ontario Hydro mercury speciation method, and EPA Method 101A exist for total and specialted mercury, they are difficult and costly to perform. In addition, the data are not available for use until several days later. Continuous emission monitors (CEMs) are a very attractive option because the data are in near real-time, allowing the data to be used as feedback control for mercury control strategies. Also, a properly designed analyzer should require minimal operator input. However, based on the current state of the art, mercury CEMs are not without problems, as demonstrated in recent field tests (2). In addition, they are often bulky and costly to purchase. Sensor Research and Development Corporation (SRD) was contracted by DOE's National Energy Technology Laboratory (formerly the Federal Energy Technology Center [FETC]) to develop a prototype instrument for thermal treatment process continuous emission monitoring applications. The work by SRD for DOE on the mercury CEM was conducted under two different contracts. Work under the first contract began October 1, 1997, and ended June 2000, with a second contract continuing until June 2001. The SRD process has the potential to be the basis for a very low-cost mercury CEM. The initial cost estimates provided by SRD are an order of magnitude lower than any other proposed mercury CEM. Although the instrument will be low-cost, it still has the potential to detect low limits of mercury

  1. Mercury Phase II Study - Mercury Behavior across the High-Level Waste Evaporator System

    Energy Technology Data Exchange (ETDEWEB)

    Bannochie, C. J. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Crawford, C. L. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Jackson, D. G. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Shah, H. B. [Savannah River Remediation, LLC., Aiken, SC (United States); Jain, V. [Savannah River Remediation, LLC., Aiken, SC (United States); Occhipinti, J. E. [Savannah River Remediation, LLC., Aiken, SC (United States); Wilmarth, W. R. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

    2016-06-17

    The Mercury Program team’s effort continues to develop more fundamental information concerning mercury behavior across the liquid waste facilities and unit operations. Previously, the team examined the mercury chemistry across salt processing, including the Actinide Removal Process/Modular Caustic Side Solvent Extraction Unit (ARP/MCU), and the Defense Waste Processing Facility (DWPF) flowsheets. This report documents the data and understanding of mercury across the high level waste 2H and 3H evaporator systems.

  2. Comparison of pollutant emission control strategies for cadmium and mercury in urban water systems using substance flow analysis

    DEFF Research Database (Denmark)

    Revitt, D. M.; Lundy, L.; Eriksson, Eva

    2013-01-01

    effective for one city (59% reduction of Hg; 39% reduction of Cd) and the other city being most influenced by the presence of efficient advanced wastewater treatment processes (63% reduction of Hg; 43% reduction of Cd). These reductions in receiving water loads are necessarily accompanied by either...... of urban emission control strategies (ECS) with an emphasis on the scientific and technological benefits which can be achieved. Data from the literature, in combination with expert judgement, have been used to develop two different semi-hypothetical case cities (SHCC), which represent virtual platforms...... to be particularly effective for Cd with the potential to further lower the overall emissions by between 16% and 27%. The most efficient protection of the receiving surface water environment is strongly influenced by the city characteristics with the introduction of stormwater treatment practices being particularly...

  3. The centralized control of elemental mercury emission from the flue gas by a magnetic rengenerable Fe-Ti-Mn spinel.

    Science.gov (United States)

    Liao, Yong; Xiong, Shangchao; Dang, Hao; Xiao, Xin; Yang, Shijian; Wong, Po Keung

    2015-12-15

    A magnetic Fe-Ti-Mn spinel was developed to adsorb gaseous Hg(0) in our previous study. However, it is currently extremely restricted in the control of Hg(0) emission from the flue gas for at least three reasons: sorbent recovery, sorbent regeneration and the interference of the chemical composition in the flue gas. Therefore, the effect of SO2 and H2O on the adsorption of gaseous Hg(0) on the Fe-Ti-Mn spinel and the regeneration of spent Fe-Ti-Mn spinel were investigated in this study. Meanwhile, the procedure of the centralized control of Hg(0) emission from the flue gas by the magnetic Fe-Ti-Mn spinel has been analyzed for industrial application. The spent Fe-Ti-Mn spinel can be regenerated by water washing followed by the thermal treatment at 450 °C with no obvious decrease of its ability for Hg(0) capture. Meanwhile, gaseous Hg(0) in the flue gas can be remarkably concentrated during the regeneration, facilitating its safe disposal. Initial pilot test demonstrated that gaseous Hg(0) in the real flue gas can be concentrated at least 100 times by the Fe-Ti-Mn spinel. Therefore, Fe-Ti-Mn spinel was a novel magnetic regenerable sorbent, which can be used for the centralized control of Hg(0) emission from the flue gas. Copyright © 2015 Elsevier B.V. All rights reserved.

  4. Behavior of Mercury Emissions from a Commercial Coal-Fired Utility Boiler: TheRelationship Between Stack Speciation and Near-Field Plume Measurements

    Science.gov (United States)

    The reduction of divalent gaseous mercury (HgII) to elemental gaseous mercury (Hg0) in a commercial coal-fired power plant (CFPP)exhaust plume was investigated by simultaneous measurement in-stack and in-plume as part of a collaborative study among the U.S....

  5. Measurement of Total Site Mercury Emissions from a Chlor-Alkali Plant Using Ultraviolet Differential Optical Absorption Spectroscopy and Cell Room Roof-Vent Monitoring

    Science.gov (United States)

    Mercury-cell chlor-alkali plants can emit significant quantities of fugitive elemental mercury vapor to the air as part of production operations and maintenance activities. In the fall of 2006, the U.S. Environmental Protection Agency (EPA) conducted a measurement project at a ch...

  6. “Smart COPVs” - Continued Successful Development of JSC IR&D Acoustic Emissions (AE) SHM

    Data.gov (United States)

    National Aeronautics and Space Administration — Developed and applied promising quantitative pass/fail criteria to COPVs using acoustic emission (AE) and developed automated data analysis software. This lays the...

  7. Mining legacy across a wetland landscape: high mercury in Upper Peninsula (Michigan) rivers, lakes, and fish.

    Science.gov (United States)

    Kerfoot, W Charles; Urban, Noel R; McDonald, Cory P; Zhang, Huanxin; Rossmann, Ronald; Perlinger, Judith A; Khan, Tanvir; Hendricks, Ashley; Priyadarshini, Mugdha; Bolstad, Morgan

    2018-03-29

    A geographic enigma is that present-day atmospheric deposition of mercury in the Upper Peninsula of Michigan is low (48%) and that regional industrial emissions have declined substantially (ca. 81% reduction) relative to downstate. Mercury levels should be declining. However, state (MDEQ) surveys of rivers and lakes revealed elevated total mercury (THg) in Upper Peninsula waters and sediment relative to downstate. Moreover, Western Upper Peninsula (WUP) fish possess higher methyl mercury (MeHg) levels than Northern Lower Peninsula (NLP) fish. A contributing explanation for elevated THg loading is that a century ago the Upper Peninsula was a major industrial region, centered on mining. Many regional ores (silver, copper, zinc, massive sulfides) contain mercury in part per million concentrations. Copper smelters and iron furnace-taconite operations broadcast mercury almost continuously for 140 years, whereas mills discharged tailings and old mine shafts leaked contaminated water. We show that mercury emissions from copper and iron operations were substantial (60-650 kg per year) and dispersed over relatively large areas. Moreover, lake sediments in the vicinity of mining operations have higher THg concentrations. Sediment profiles from the Keweenaw Waterway show that THg accumulation increased 50- to 400-fold above modern-day atmospheric deposition levels during active mining and smelting operations, with lingering MeHg effects. High MeHg concentrations are geographically correlated with low pH and dissolved organic carbon (DOC), a consequence of biogeochemical cycling in wetlands, characteristic of the Upper Peninsula. DOC can mobilize metals and elevate MeHg concentrations. We argue that mercury loading from mining is historically superimposed upon strong regional wetland effects, producing a combined elevation of both THg and MeHg in the Western Upper Peninsula.

  8. Environmental costs of mercury pollution.

    Science.gov (United States)

    Hylander, Lars D; Goodsite, Michael E

    2006-09-01

    Mercury (Hg) has been used for millennia in many applications, primarily in artisanal mining and as an electrode in the chlor-alkali industry. It is anthropogenically emitted as a pollutant from coal fired power plants and naturally emitted, primarily from volcanoes. Its unique chemical characteristics enable global atmospheric transport and it is deposited after various processes, ultimately ending up in one of its final sinks, such as incorporated into deep sediment or bioaccumulated, primarily in the marine environment. All forms of Hg have been established as toxic, and there have been no noted biological benefits from the metal. Throughout time, there have been notable incidents of Hg intoxication documented, and the negative health effects have been documented to those chronically or acutely exposed. Today, exposure to Hg is largely diet or occupationally dependent, however, many are exposed to Hg from their amalgam fillings. This paper puts a tentative monetary value on Hg polluted food sources in the Arctic, where local, significant pollution sources are limited, and relates this to costs for strategies avoiding Hg pollution and to remediation costs of contaminated sites in Sweden and Japan. The case studies are compiled to help policy makers and the public to evaluate whether the benefits to the global environment from banning Hg and limiting its initial emission outweigh the benefits from its continued use or lack of control of Hg emissions. The cases we studied are relevant for point pollution sources globally and their remediation costs ranged between 2,500 and 1.1 million US dollars kg(-1) Hg isolated from the biosphere. Therefore, regulations discontinuing mercury uses combined with extensive flue gas cleaning for all power plants and waste incinerators is cost effective.

  9. Fugitive coke oven gas emission profile by continuous line averaged open-path Fourier transform infrared monitoring.

    Science.gov (United States)

    Lin, Chitsan; Liou, Naiwei; Chang, Pao-Erh; Yang, Jen-Chin; Sun, Endy

    2007-04-01

    Although most coke oven research is focused on the emission of polycyclic aromatic hydrocarbons, well-known carcinogens, little has been done on the emission of volatile organic compounds, some of which are also thought to be hazardous to workers and the environment. To profile coke oven gas (COG) emissions, we set up an open-path Fourier transform infrared (OP-FTIR) system on top of a battery of coke ovens at a steel mill located in Southern Taiwan and monitored average emissions in a coke processing area for 16.5 hr. Nine COGs were identified, including ammonia, CO, methane, ethane, ethylene, acetylene, propylene, cyclohexane, and O-xylene. Time series plots indicated that the type of pollutants differed over time, suggesting that different emission sources (e.g., coke pushing, quench tower, etc.) were involved at different times over the study period. This observation was confirmed by the low cross-correlation coefficients of the COGs. It was also found that, with the help of meteorological analysis, the data collected by the OP-FTIR system could be analyzed effectively to characterize differences in the location of sources. Although the traditional single-point samplings of emissions involves sampling various sources in a coke processing area at several different times and is a credible profiling of emissions, our findings strongly suggest that they are not nearly as efficient or as cost-effective as the continuous line average method used in this study. This method would make it easier and cheaper for engineers and health risk assessors to identify and to control fugitive volatile organic compound emissions and to improve environmental health.

  10. Mercury and Pregnancy

    Science.gov (United States)

    ... Home > Pregnancy > Is it safe? > Mercury and pregnancy Mercury and pregnancy E-mail to a friend Please ... vision problems. How can you be exposed to mercury? Mercury has several forms: It can be a ...

  11. Spatiotemporal patterns of mercury accumulation in lake sediments of western North America

    Science.gov (United States)

    Drevnick, Paul; Cooke, Colin A.; Barraza, Daniella; Blais, Jules M.; Coale, Kenneth; Cumming, Brian F.; Curtis, Chris; Das, Biplob; Donahue, William F.; Eagles-Smith, Collin A.; Engstrom, Daniel R.; Fitzgerald, William F.; Furl, Chad V.; Gray, John R.; Hall, Roland I.; Jackson, Togwell A.; Laird, Kathleen R.; Lockhart, W. Lyle; Macdonald, Robie W.; Mast, M. Alisa; Mathieu, Callie; Muir, Derek C.G.; Outridge, Peter; Reinemann, Scott; Rothenberg, Sarah E.; Ruiz-Fernandex, Ana Carolina; St. Louis, V.L.; Sanders, Rhea; Sanei, Hamed; Skierszkan, Elliott; Van Metre, Peter C.; Veverica, Timothy; Wiklund, Johan A.; Wolfe, Brent B.

    2016-01-01

    For the Western North America Mercury Synthesis, we compiled mercury records from 165 dated sediment cores from 138 natural lakes across western North America. Lake sediments are accepted as faithful recorders of historical mercury accumulation rates, and regional and sub-regional temporal and spatial trends were analyzed with descriptive and inferential statistics. Mercury accumulation rates in sediments have increased, on average, four times (4×) from 1850 to 2000 and continue to increase by approximately 0.2 μg/m2 per year. Lakes with the greatest increases were influenced by the Flin Flon smelter, followed by lakes directly affected by mining and wastewater discharges. Of lakes not directly affected by point sources, there is a clear separation in mercury accumulation rates between lakes with no/little watershed development and lakes with extensive watershed development for agricultural and/or residential purposes. Lakes in the latter group exhibited a sharp increase in mercury accumulation rates with human settlement, stabilizing after 1950 at five times (5×) 1850 rates. Mercury accumulation rates in lakes with no/little watershed development were controlled primarily by relative watershed size prior to 1850, and since have exhibited modest increases (in absolute terms and compared to that described above) associated with (regional and global) industrialization. A sub-regional analysis highlighted that in the ecoregion Northwestern Forest Mountains, Research is warranted to understand whether mountainous watersheds act as permanent sinks for mercury or if export of “legacy” mercury (deposited in years past) will delay recovery when/if emissions reductions are achieved.

  12. Mercury Information Clearinghouse

    Energy Technology Data Exchange (ETDEWEB)

    Chad A. Wocken; Michael J. Holmes; Dennis L. Laudal; Debra F. Pflughoeft-Hassett; Greg F. Weber; Nicholas V. C. Ralston; Stanley J. Miller; Grant E. Dunham; Edwin S. Olson; Laura J. Raymond; John H. Pavlish; Everett A. Sondreal; Steven A. Benson

    2006-03-31

    The Canadian Electricity Association (CEA) identified a need and contracted the Energy & Environmental Research Center (EERC) to create and maintain an information clearinghouse on global research and development activities related to mercury emissions from coal-fired electric utilities. With the support of CEA, the Center for Air Toxic Metals{reg_sign} (CATM{reg_sign}) Affiliates, and the U.S. Department of Energy (DOE), the EERC developed comprehensive quarterly information updates that provide a detailed assessment of developments in the various areas of mercury monitoring, control, policy, and research. A total of eight topical reports were completed and are summarized and updated in this final CEA quarterly report. The original quarterly reports can be viewed at the CEA Web site (www.ceamercuryprogram.ca). In addition to a comprehensive update of previous mercury-related topics, a review of results from the CEA Mercury Program is provided. Members of Canada's coal-fired electricity generation sector (ATCO Power, EPCOR, Manitoba Hydro, New Brunswick Power, Nova Scotia Power Inc., Ontario Power Generation, SaskPower, and TransAlta) and CEA, have compiled an extensive database of information from stack-, coal-, and ash-sampling activities. Data from this effort are also available at the CEA Web site and have provided critical information for establishing and reviewing a mercury standard for Canada that is protective of environment and public health and is cost-effective. Specific goals outlined for the CEA mercury program included the following: (1) Improve emission inventories and develop management options through an intensive 2-year coal-, ash-, and stack-sampling program; (2) Promote effective stack testing through the development of guidance material and the support of on-site training on the Ontario Hydro method for employees, government representatives, and contractors on an as-needed basis; (3) Strengthen laboratory analytical capabilities through

  13. Reflectance and Emissivity Spectra of Graphite as Potential Darkening Agent for Mercury from the UV to the TIR and its Comparison to Remote Sensing Measurements from MESSENGER and MERTIS on BepiColombo

    Science.gov (United States)

    Maturilli, A.; Helbert, J.; D'Amore, M.; Ferrari, S.; Hiesinger, H.

    2016-12-01

    For long time Mercury was considered a planet very similar to the Moon. Both are small rocky bodies in the inner solar system with thin exospheres and no large scale traces of recent geological activity. However Mercury's surface reflects much less sunlight than the Moon. Trying to explain the reasons for this difference, significant abundances of iron and titanium (and their oxides) were proposed for the Hermean surface. But the NASA MESSENGER instruments found only small abundances of iron, confirming earlier ground-based spectroscopy observations, and virtually no titanium. Therefore neither of the elements can account for this diversity. New analysis of MESSENGER data acquired for the darkest regions of Mercury's surface suggest that the unknown darkening material could be carbon, in particular as the mineral graphite (Peplowski et al., 2016) whose abundance in the darker regions is predicted to be 1 to 3 wt% higher than the surroundings. At the Planetary Spectroscopy Laboratory (PSL) of the Institute of Planetary Research (DLR, Berlin) we measured reflectance spectra for several phase angles of graphite, from UV to TIR spectral range (0.2 to 20 µm). Samples have been measured fresh and then after successive steps of heating at 400°C in vacuum for 8 hours. Following the same procedure, reflectance spectra of Komatiite (chosen as Mercury surface simulant, after Maturilli et al., 2014) was measured alone and mixed with few % of graphite to reproduce the results from Peplowski et al (2016). The results from this experiment can be compared to the data acquired from the MDIS and the MASCS instrument onboard the NASA MESSENGER mission. The same set of samples has been measured in emissivity, in vacuum (< 0.8 mbar) for successive cycles of several surface temperatures from 100°C to 400°C in the TIR spectral range (1 to 18 µm) in preparation for the emissivity spectra that will be collected by the Mercury Radiometer and Thermal Infrared Spectrometer (MERTIS), a

  14. Evaluation of the characteristics of a field emission cathode for use in a Mercury ion trap frequency standard

    Science.gov (United States)

    Christman, J. M.

    1988-01-01

    The performance is reported of a field emission array characterized for the purpose of replacing the filament in a trapped ion frequency standard. This dark electron emitter eliminates the need for the interference filter currently used in the trapped ion standard. While reducing the filament's unwanted light, this filter causes a significant reduction in the signal. The magnetic field associated with the filament is also eliminated, thus potentially improving the present stability of the trapped ion standard. The operation of the filament in the present system is described, as well as the associated concerns. The cathode considered for the filament's replacement is then described along with the experimental system. Experimental results, observations, and conclusions are presented.

  15. Actual issues of introduction of continuous emission monitoring systems for control of negative impact of TPP to atmospheric air

    Science.gov (United States)

    Kondrateva, O. E.; Roslyakov, P. V.; Borovkova, A. M.; Loktionov, O. A.

    2017-11-01

    Over the past 3 years there have been significant changes in Russian environmental legislation related to the transition to technological regulation based on the principles of the best available technologies (BAT). These changes also imply control and accounting of the harmful impact of industrial enterprises on the environment. Therefore, a mandatory requirement for equipping automatic continuous emission monitoring systems (ACEMS) is established for all large TPPs. For a successful practical solution of the problem of introducing such systems in the whole country there is an urgent need to develop the governing regulatory document for the design and operation of systems for continuous monitoring of TPP emissions into the air, allowing within reasonable limits to unify these systems for their work with the state data fund of state environmental monitoring and make easier the process of their implementation at operating facilities for industrial enterprises. Based on the large amount of research in the field of creation of ACEMS, which conducted in National Research University “MPEI”, a draft guidance document was developed, which includes the following regulatory provisions: goals and objectives of ACEMS, the stages of their introduction rules of carrying out preliminary inspection of energy facilities, requirements to develop technical specifications, general requirements for the operation of ACEMS, requirements to the structure and elements of ACEMS, recommendations on selection of places of measuring equipment installation, rules for execution, commissioning and acceptance testing, continuous measurement method, method for determination of the current gross and specific emissions. The draft guidance document, developed by the National Research University “MPEI”, formed the basis of the Preliminary national standards PNST 187-2017 “Automatic systems for continuous control and metering of contaminants emissions from thermal electric power stations into

  16. Mercury in products - a source of transboundary pollutant transport

    Energy Technology Data Exchange (ETDEWEB)

    Munthe, J.; Kindbom, K. [Swedish Environmental Research Inst., Stockholm (Sweden)

    1997-12-01

    The purpose of this report is to summarize current knowledge on product-related emissions of mercury to air on a European scale, and to estimate the contribution from mercury contained in products, to the total anthropogenic emissions of mercury to air and transboundary transport of mercury in Europe. Products included in this study are batteries, measuring and control instruments, light sources and electrical equipment, all intentionally containing mercury. The main result of this study is that product-related emission of mercury can contribute significantly to total emissions and transboundary transport of mercury in the European region and that measures to limit the use of mercury in products can contribute to an overall decrease of the environmental input of mercury in Europe. It is concluded that: -Mercury contained in products may be emitted to air during consumption, after disposal when incinerated or when volatilized from landfill. Mercury may also be emitted to air during recycling of scrap metal or when accumulated (stored) in society. -The amount of mercury consumed in batteries and in measuring and control instruments had decreased since the late 1980`s. The total use of mercury in light sources and electrical equipment has not changed significantly during the same time period. The contribution to total anthropogenic emissions of mercury to air in Europe in the mid 1990`s is estimated to be: for batteries 4%; for measuring and control instruments 3%; for lighting and electrical equipment 11%. -Mercury in products leads to significant wet deposition input in Scandinavia. The relative amount of the total deposition flux attributable to products is estimated to be 10-14% 26 refs, 4 figs, 10 tabs

  17. 40 CFR Table 4 to Subpart Cccc of... - Continuous Compliance With Emission Limitations

    Science.gov (United States)

    2010-07-01

    ... yeast in a fermentation stage (last (Trade), second-to-last (First Generation), or third-to-last (Stock... the applicable maximum concentration. 2. Each fed-batch fermenter producing yeast in a fermentation... CATEGORIES National Emission Standards for Hazardous Air Pollutants: Manufacturing of Nutritional Yeast Part...

  18. Will the use of a carbon tax for revenue generation produce an incentive to continue carbon emissions?

    Science.gov (United States)

    Wang, Rong; Moreno-Cruz, Juan; Caldeira, Ken

    2017-05-01

    Integrated assessment models are commonly used to generate optimal carbon prices based on an objective function that maximizes social welfare. Such models typically project an initially low carbon price that increases with time. This framework does not reflect the incentives of decision makers who are responsible for generating tax revenue. If a rising carbon price is to result in near-zero emissions, it must ultimately result in near-zero carbon tax revenue. That means that at some point, policy makers will be asked to increase the tax rate on carbon emissions to such an extent that carbon tax revenue will fall. Therefore, there is a risk that the use of a carbon tax to generate revenue could eventually create a perverse incentive to continue carbon emissions in order to provide a continued stream of carbon tax revenue. Using the Dynamic Integrated Climate Economy (DICE) model, we provide evidence that this risk is not a concern for the immediate future but that a revenue-generating carbon tax could create this perverse incentive as time goes on. This incentive becomes perverse at about year 2085 under the default configuration of DICE, but the timing depends on a range of factors including the cost of climate damages and the cost of decarbonizing the global energy system. While our study is based on a schematic model, it highlights the importance of considering a broader spectrum of incentives in studies using more comprehensive integrated assessment models. Our study demonstrates that the use of a carbon tax for revenue generation could potentially motivate implementation of such a tax today, but this source of revenue generation risks motivating continued carbon emissions far into the future.

  19. Continuous Monitoring of CH4 Emissions from Marcellus Shale Gas Extraction in South West Pennsylvania Using Top Down Methodology

    Science.gov (United States)

    Sarmiento, D. P.; Belmecheri, S.; Lauvaux, T.; Sowers, T. A.; Bryant, S.; Miles, N. L.; Richardson, S.; Aikins, J.; Sweeney, C.; Petron, G.; Davis, K. J.

    2012-12-01

    Natural gas extraction from shale formations via hydraulic-fracturing (fracking) is expanding rapidly in several regions of North America. In Pennsylvania, the number of wells drilled to extract natural gas from the Marcellus shale has grown from 195 in 2008 to 1,386 in 2010. The gas extraction process using the fracking technology results in the escape of methane (CH4), a potent greenhouse gas and the principal component of natural gas, into the atmosphere. Emissions of methane from fracking operations remain poorly quantified, leading to a large range of scenarios for the contribution of fracking to climate change. A mobile measurement campaign provided insights on methane leakage rates and an improved understanding of the spatio-temporal variability in active drilling areas in the South West of Pennsylvania. Two towers were then instrumented to monitor fugitive emissions of methane from well pads, pipelines, and other infrastructures in the area. The towers, one within a drilling region and one upwind of active drilling, measured atmospheric CH4 mixing ratios continuously. Isotopic measurements from air flasks were also collected. Data from the initial mobile campaign were used to estimate emission rates from single sites such as wells and compressor stations. Tower data will be used to construct a simple atmospheric inversion for regional methane emissions. Our results show the daily variability in emissions and allow us to estimate leakage rates over a one month period in South West Pennsylvania. We discuss potential deployment strategies in drilling zones to monitor emissions of methane over longer periods of time.

  20. Experimental study of advanced continuous acoustic-emission monitoring of BWR components. Final report

    International Nuclear Information System (INIS)

    McElroy, J.W.

    1982-01-01

    This report presents the results of a four year research program on the utilization of acoustic emission techniques on light water reactor component applications. Two techniques of the acoustic emission technology were applied to specific problems occurring within the light water reactor system. Crack detection AE monitoring was applied to thermal cycle fatigue cracking problems and stress corrosion cracking problems. Leak detection AE monitoring was applied to valve leakage in the main steam safety relief valves and incontainment packing gland valves. The report provides AE data showing how AE crack detection can be used as an on-line diagnostic monitoring tool. By having an active monitor on light water reactor components, the inservice inspection of the components is being performed during operation rather than refueling periods, thereby reducing critical path time during outages. The resultant benefit is increased plant availability and a reduction in accumulated radiation exposure

  1. More frequent moments in the climate change debate as emissions continue

    Science.gov (United States)

    Huntingford, Chris; Friedlingstein, Pierre

    2015-12-01

    Recent years have witnessed unprecedented interest in how the burning of fossil fuels may impact on the global climate system. Such visibility of this issue is in part due to the increasing frequency of key international summits to debate emissions levels, including the 2015 21st Conference of Parties meeting in Paris. In this perspective we plot a timeline of significant climate meetings and reports, and against metrics of atmospheric greenhouse gas changes and global temperature. One powerful metric is cumulative CO2 emissions that can be related to past and future warming levels. That quantity is analysed in detail through a set of papers in this ERL focus issue. We suggest it is an open question as to whether our timeline implies a lack of progress in constraining climate change despite multiple recent keynote meetings—or alternatively—that the increasing level of debate is encouragement that solutions will be found to prevent any dangerous warming levels?

  2. Changes in distortion product oto-acoustic emissions after exposure to continuous and impulsive noise

    DEFF Research Database (Denmark)

    de Toro, Miguel Angel Aranda; Ordoñez, Rodrigo Pizarro; Hammershøi, Dorte

    2012-01-01

    Temporary changes in the hearing of human subjects were monitored with distortion product otoacoustic emissions (DPOAEs) after control sound exposures in a laboratory. The objectives of the experiment were to investigate whether the +5~dB penalty for impulsiveness used in international standards......~dB penalty = 80~dB. The results show that the effects on DPOAE levels from the two stimuli could be compared in terms of their total acoustic energy....

  3. Experimental study of advanced continuous acoustic emission monitoring of BWR components. Final report

    International Nuclear Information System (INIS)

    McElroy, J.W.; Hartman, W.F.

    1980-09-01

    The program consisted of installing, maintaining, and monitoring AE sensors located on primary piping, nozzles, and valves in the BWR system. Analysis of the AE data was correlated to the results of supplementary nondestructive testing techniques used during the in-service inspection, performed at refueling outages. Purpose of the program was to develop the on-line surveillance acoustic emission technique in order to identify areas of possible structural degradation. Result of reducing inspection time was to reduce accumulated radiation exposure to inspecting personnel and to reduce the amount of critical plant outage time by identifying the critical inspection areas during operation. The program demonstrated the capability of acoustic emission instrumentation to endure the nuclear reactor environment. The acoustic emission sensors withstood 12 months of reactor operation at temperatures of 400 0 F and greater in high radiation fields. The preamplifiers, also mounted in the reactor environment, operated for the 12-month period in 100% humidity, 250 0 F conditions. The remaining cable and AE instrumentation were operated in controlled environments

  4. Current and future levels of mercury atmospheric pollution on global scale

    NARCIS (Netherlands)

    Pacyna, Jozef M.; Travnikov, Oleg; De Simone, Francesco; Hedgecock, Ian M.; Sundseth, Kyrre; Pacyna, Elisabeth G.; Steenhuisen, Frits; Pirrone, Nicola; Munthe, John; Kindbom, Karin

    2016-01-01

    An assessment of current and future emissions, air concentrations and atmospheric deposition of mercury world-wide are presented on the basis of results obtained during the performance of the EU GMOS (Global Mercury Observation System) project. Emission estimates for mercury were prepared with the

  5. Current and future levels of mercury atmospheric pollution on a global scale

    NARCIS (Netherlands)

    Pacyna, J. M.; Travnikov, O.; De Simone, F.; Hedgecock, I. M.; Sundseth, K.; Pacyna, E. G.; Steenhuisen, F.; Pirrone, N.; Munthe, J.; Kindbom, K.

    2016-01-01

    An assessment of current and future emissions, air concentrations, and atmospheric deposition of mercury worldwide is presented on the basis of results obtained during the performance of the EU GMOS (Global Mercury Observation System) project. Emission estimates for mercury were prepared with the

  6. Progress toward acoustic emission characterization for continuous monitoring reactor pressure vessels

    International Nuclear Information System (INIS)

    Hutton, P.H.; Schwenk, E.B.; Kurtz, R.J.

    1979-01-01

    The purpose of this work is to evaluate the feasibility of detecting and analyzing flaw growth in an operating reactor vessel using acoustic emission (AE) data. A preliminary AE-flaw growth relationship has been developed encompassing six variables. This model relates AE count and energy to fatigue crack driving force ΔK. Pattern recognition has been examined as a means of distinguishing crack growth AE from other acoustic signals with encouraging results. The program is moving into hardware implementation of relationships for testing and refinement by monitoring tests in heavy section specimens and subscale structures. The hardware system will become a reactor monitor prototype

  7. Human hemispheric infarction studied by positron emission tomography and the 150 continuous inhalation technique

    International Nuclear Information System (INIS)

    Baron, J.-C.; Bousser, M.G.; Comar, D.; Kellershohn, C.

    1979-01-01

    Positron emission tomography (PET) offers an entirely new approach to the study of the pathophysiology of cerebral ischemic disorders. This is so because for the first time it is possible to obtain functional tomographic images that represent cerebral perfusion and metabolism in a regional basis. We report here a study of cerebral blood flow and oxygen extraction by means of the 15 O inhalation technique in a large number of human hemispheric infarctions. PET imaging with this non-invasive technique has permitted the description of hitherto unreported focal patterns of changes in the CBF/EO2 couple that may have important pathophysiologic and prognostic implications

  8. The export of mercury from Asia is studied by using the STEM-Hg model

    Science.gov (United States)

    Pan, L.; Carmichael, G.

    2005-12-01

    It is estimated that Asian countries (including China, India, and South and North Korea) contribute 56% to the global mercury emissions to the atmosphere due to the heavy use of coal. The large amount of mercury emissions and the long life time of mercury in the atmosphere imply the possibility of the long range transport of mercury from Asia to North America. To better understand the fate and transport of mercury between these two continents, the STEM-Hg model was developed based on up-to-date mercury mechanisms in the atmosphere. Mercury aqueous phase oxidation-reduction reactions, sulfite and oxygen aqueous phase reactions along with mercury gas phase reactions are included in the model. The model simulates Hg(0), Hg(2+) and Hg(p). By running the model using new mercury emissions inventory in two domains, the ACE-Asia and the ICARTT domains, the contributions of long range transport to Hg fluxes in North America are evaluated.

  9. Method and apparatus for monitoring the flow of mercury in a system

    Science.gov (United States)

    Grossman, M.W.

    1987-12-15

    An apparatus and method for monitoring the flow of mercury in a system are disclosed. The equipment enables the entrainment of the mercury in a carrier gas e.g., an inert gas, which passes as mercury vapor between a pair of optically transparent windows. The attenuation of the emission is indicative of the quantity of mercury (and its isotopes) in the system. A 253.7 nm light is shone through one of the windows and the unabsorbed light is detected through the other window. The absorption of the 253.7 nm light is thereby measured whereby the quantity of mercury passing between the windows can be determined. The apparatus includes an in-line sensor for measuring the quantity of mercury. It includes a conduit together with a pair of apertures disposed in a face to face relationship and arranged on opposite sides of the conduit. A pair of optically transparent windows are disposed upon a pair of viewing tubes. A portion of each of the tubes is disposed inside of the conduit and within each of the apertures. The two windows are disposed in a face to face relationship on the ends of the viewing tubes and the entire assembly is hermetically sealed from the atmosphere whereby when 253.7 nm ultraviolet light is shone through one of the windows and detected through the other, the quantity of mercury which is passing by can be continuously monitored due to absorption which is indicated by attenuation of the amplitude of the observed emission. 4 figs.

  10. Continuous reduction of cyclic adsorbed and desorbed NO{sub x} in diesel emission using nonthermal plasma

    Energy Technology Data Exchange (ETDEWEB)

    Kuwahara, Takuya [Department of Products Engineering and Environmental Management, Nippon Institute of Technology, 4-1 Gakuendai, Miyashiro-machi, Minamisaitama, Saitama 345-8501 (Japan); Nakaguchi, Harunobu; Kuroki, Tomoyuki [Department of Mechanical Engineering, Osaka Prefecture University, 1-1 Gakuen-cho, Naka-ku, Sakai 599-8531 (Japan); Okubo, Masaaki, E-mail: mokubo@me.osakafu-u.ac.jp [Department of Mechanical Engineering, Osaka Prefecture University, 1-1 Gakuen-cho, Naka-ku, Sakai 599-8531 (Japan)

    2016-05-05

    Highlights: • High-efficiency continuous diesel NO{sub x} reduction method is proposed. • Characteristics of diesel NO{sub x} adsorption and desorption on adsorbent is provided. • Efficiency of NO{sub x} reduction with nonthermal plasma is evaluated. • Efficiency of NO{sub x} reduction with exhaust gas component recirculation is evaluated. • High NO{sub x} removal efficiency equal to only 1.0% penalty of engine power is achieved. - Abstract: Considering the recent stringent regulations governing diesel NO{sub x} emission, an aftertreatment system for the reduction of NO{sub x} in the exhaust gas has been proposed and studied. The proposed system is a hybrid method combining nonthermal plasma and NO{sub x} adsorbent. The system does not require precious metal catalysts or harmful chemicals such as urea and ammonia. In the present system, NO{sub x} in diesel emission is treated by adsorption and desorption by adsorbent as well as nonthermal plasma reduction. In addition, the remaining NO{sub x} in the adsorbent is desorbed again in the supplied air by residual heat. The desorbed NO{sub x} in air recirculates into the intake of the engine, and this process, i.e., exhaust gas components’ recirculation (EGCR) achieves NO{sub x} reduction. Alternate utilization of two adsorption chambers in the system can achieve high-efficiency NO{sub x} removal continuously. An experiment with a stationary diesel engine for electric power generation demonstrates an energy efficiency of 154 g(NO{sub 2})/kWh for NO{sub x} removal and continuous NO{sub x} reduction of 70.3%. Considering the regulation against diesel emission in Japan, i.e., the new regulation to be imposed on vehicles of 3.5–7.5 ton since 2016, the present aftertreatment system fulfills the requirement with only 1.0% of engine power.

  11. 40 CFR Table 6 to Subpart Zzzz of... - Continuous Compliance With Emission Limitations and Operating Limitations

    Science.gov (United States)

    2010-07-01

    ... Pollutants for Stationary Reciprocating Internal Combustion Engines Pt. 63, Subpt. ZZZZ, Table 6 Table 6 to... continuous compliance by . . . 1. 2SLB and 4SLB stationary RICE >500 HP located at a major source and CI... stationary RICE >500 HP located at a major source and CI stationary RICE >500 HP located at a major source a...

  12. Determination of total mercury in biological and geological samples

    Science.gov (United States)

    Crock, James G.

    2005-01-01

    very oxidative to ensure the conversion of all mercury forms into Hg (II). Each method of digestion has its advantages and limitations. The method of detection used in our laboratories involves a combination of an in-house, custom, classic continuous-flow cold-vapor atomic absorption spectrometry (CVAAS), a commercially available, automated, flow-injection and a continuous flow cold-vapor atomic fluorescence spectrometry (CV-AFS) systems, and a relatively new, automated and integrated approach where solid or liquid samples are thermally decomposed under an oxygen atmosphere (a nitrogen atmosphere is used for coals) and the released mercury vapor trapped onto a gold gauze and then thermally released into an AAS system. Other less frequently used instrumental methods available for the determination of mercury include inductively coupled plasma ? optical emission spectrometry (ICP-OES), inductively couple plasma ? mass spectrometry (ICP-MS) (both solution nebulization and laser ablation), and instrumental neutron activation analysis (INAA). Results from two case studies involving the determination of mercury in the challenging matrices of biological materials will be presented. These will include fillet, liver and stomach-content samples from grayling for a baseline/background study in Alaska, and samples of meat tissue and shell material from Tanner crabs from Glacier Bay, Alaska. These studies show that the method of digestion is more important than a very sensitive detection limit for mercury.

  13. Mercury's Messenger

    Science.gov (United States)

    Chapman, Clark R.

    2004-01-01

    Forty years after Mariner 2, planetary exploration has still only just begun, and many more missions are on drawing boards, nearing the launch pad, or even en route across interplanetary space to their targets. One of the most challenging missions that will be conducted this decade is sending the MESSENGER spacecraft to orbit the planet Mercury.…

  14. Reducing Mercury Pollution from Artisanal and Small-Scale Gold Mining

    Science.gov (United States)

    To reduce airborne mercury emissions from these Gold Shops, EPA and the Argonne National Laboratory (ANL) have partnered to design a low cost, easily constructible technology called the Gold Shop Mercury Capture System (MCS).

  15. Mercury Report-Children's exposure to elemental mercury

    Science.gov (United States)

    ... gov . Mercury Background Mercury Report Additional Resources Mercury Report - Children's Exposure to Elemental Mercury Recommend on Facebook ... I limit exposure to mercury? Why was the report written? Children attending a daycare in New Jersey ...

  16. NASA's MODIS/VIIRS Land Surface Temperature and Emissivity Products: Asssessment of Accuracy, Continuity and Science Uses

    Science.gov (United States)

    Hulley, G. C.; Malakar, N.; Islam, T.

    2017-12-01

    Land Surface Temperature and Emissivity (LST&E) are an important Earth System Data Record (ESDR) and Environmental Climate Variable (ECV) defined by NASA and GCOS respectively. LST&E data are key variables used in land cover/land use change studies, in surface energy balance and atmospheric water vapor retrieval models and retrievals, and in climate research. LST&E products are currently produced on a routine basis using data from the MODIS instruments on the NASA EOS platforms and by the VIIRS instrument on the Suomi-NPP platform that serves as a bridge between NASA EOS and the next-generation JPSS platforms. Two new NASA LST&E products for MODIS (MxD21) and VIIRS (VNP21) are being produced during 2017 using a new approach that addresses discrepancies in accuracy and consistency between the current suite of split-window based LST products. The new approach uses a Temperature Emissivity Separation (TES) algorithm, originally developed for the ASTER instrument, to physically retrieve both LST and spectral emissivity consistently for both sensors with high accuracy and well defined uncertainties. This study provides a rigorous assessment of accuracy of the MxD21/VNP21 products using temperature- and radiance-based validation strategies and demonstrates continuity between the products using collocated matchups over CONUS. We will further demonstrate potential science use of the new products with studies related to heat waves, monitoring snow melt dynamics, and land cover/land use change.

  17. Methods and sorbents for utilizing a hot-side electrostatic precipitator for removal of mercury from combustion gases

    Science.gov (United States)

    Nelson, Sidney [Hudson, OH

    2011-02-15

    Methods are provided for reducing emission of mercury from a gas stream by treating the gas with carbonaceous mercury sorbent particles to reduce the mercury content of the gas; collecting the carbonaceous mercury sorbent particles on collection plates of a hot-side ESP; periodically rapping the collection plates to release a substantial portion of the collected carbonaceous mercury sorbent particles into hoppers; and periodically emptying the hoppers, wherein such rapping and emptying are done at rates such that less than 70% of mercury adsorbed onto the mercury sorbent desorbs from the collected mercury sorbent into the gas stream.

  18. 40 CFR Table 6 to Subpart IIIii of... - Examples of Techniques for Equipment Problem Identification, Leak Detection and Mercury Vapor

    Science.gov (United States)

    2010-07-01

    ... Problem Identification, Leak Detection and Mercury Vapor 6 Table 6 to Subpart IIIII of Part 63 Protection... Hazardous Air Pollutants: Mercury Emissions From Mercury Cell Chlor-Alkali Plants Pt. 63, Subpt. IIIII..., Leak Detection and Mercury Vapor As stated in Tables 1 and 2 of Subpart IIIII, examples of techniques...

  19. 40 CFR Table 4 to Subpart IIIii of... - Work Practice Standards-Requirements for Mercury Liquid Collection

    Science.gov (United States)

    2010-07-01

    ... for Mercury Liquid Collection 4 Table 4 to Subpart IIIII of Part 63 Protection of Environment... Pollutants: Mercury Emissions From Mercury Cell Chlor-Alkali Plants Pt. 63, Subpt. IIIII, Table 4 Table 4 to Subpart IIIII of Part 63—Work Practice Standards—Requirements for Mercury Liquid Collection As stated in...

  20. Developing a Continuous Hemispheric View of Greenhouse Gas Emissions: The GeoCARB Mission

    Science.gov (United States)

    Moore, B.; Chatfield, R. B.; Chenette, D. L.; Crowell, S.; Kawa, S. R.; Kumer, J. B.; Mobilia, J.; OBrien, D. M.; Polonsky, I. N.; Rairden, R. L.; Rayner, P. J.; Roche, A. E.; Zaccheo, T.

    2013-12-01

    This paper presents discussion of an instrument and space mission concept (GeoCARB) that would provide measurements of atmospheric carbon dioxide (CO2), methane (CH4), and carbon monoxide (CO) from geostationary orbit. The GeoCARB mission would deliver multiple maps daily of column integrated mixing ratios over the observed landmasses with spatial sampling of 3 km x 3 km and resolution of 4 x 5 km at sub satellite point (SSP), degrading predictably on moving away from SSP. Observing system simulation studies demonstrate that these data will enable CO2 and CH4 flux determination at unprecedented time and space scales. This determination would produce fundamental change in our scientific understanding of the global carbon cycle as well as produce the kind of flux information that will be needed to support international agreements on greenhouse gas emission reductions. The instrumentation concept is based on an approach and components that are of high technology readiness level. Following heritage greenhouse gas instruments, it would exploit four spectral regions: the weak and strong bands of CO2 near 1.61 and 2.06 microns; a region near 2.32 microns for CO and CH4, and the Oxygen A-band for pressure. Prototype testing and performance simulations indicate that the median mission retrieval for CO2, CH4 and CO column mixing ratio are expected to be < 0.7, 1.0 and 10.0%, respectively. These measurements over several years would provide a breakthrough reduction in errors and enhanced attribution of the CO2, CH4 and CO sources within the geostationary field of regard. The GeoCARB instrument is designed to fly as a hosted payload on a commercial communications satellite or a weather satellite thereby lowering the cost while retaining the potential for global expansion.

  1. Contribution of contaminated sites to the global mercury budget.

    Science.gov (United States)

    Kocman, David; Horvat, Milena; Pirrone, Nicola; Cinnirella, Sergio

    2013-08-01

    Global mercury emission inventories include anthropogenic emissions, contributing via current use or presence of mercury in a variety of products and processes, as well as natural source emissions. These inventories neglect the contribution of areas contaminated with mercury from historical accumulation, which surround mines or production plants associated with mercury production or use. Although recent studies have shown that releases of mercury from these historical sites can be significant, a database of the global distribution of mercury contaminated sites does not exist, nor are there means of scaling up such releases to estimate fluxes on a regional and global basis. Therefore, here we estimated for the first time the contribution of mercury releases from contaminated sites to the global mercury budget. A geo-referenced database was built, comprising over 3000 mercury contaminated sites associated with mercury mining, precious metal processing, non-ferrous metal production and various polluted industrial sites. In the assessment, mercury releases from these sites to both the atmosphere as well as the hydrosphere were considered based on data available for selected case studies, their number, the reported extent of contamination and geographical location. Annual average global emissions of mercury from identified contaminated sites amount to 198 (137-260) Mgyr(-1). Of that, 82 (70-95)Mgyr(-1) contribute to atmospheric releases, while 116 (67-165) Mgyr(-1) is estimated to be transported away from these sites by hydrological processes. Although these estimates are associated with large uncertainties, our current understanding of mercury releases from contaminated sites indicates that these releases can also be of paramount importance on the global perspective. This is especially important as it is known that these sites represent a long-term source of releases if not managed properly. Therefore, the information presented here is needed by governments and NGO

  2. Characterization of continuous and pulsed emission modes of a hybrid micro focus x-ray source for medical imaging applications

    Energy Technology Data Exchange (ETDEWEB)

    Ghani, Muhammad U.; Wong, Molly D.; Ren, Liqiang; Wu, Di; Zheng, Bin [Center for Biomedical Engineering and School of Electrical and Computer Engineering, University of Oklahoma, Norman, OK 73019 (United States); Rong, John X. [Department of Imaging Physics, University of Texas MD Anderson Cancer Center, Houston, TX 77030 (United States); Wu, Xizeng [Department of Radiology, University of Alabama at Birmingham, Birmingham, AL 35249 (United States); Liu, Hong, E-mail: liu@ou.edu [Center for Biomedical Engineering and School of Electrical and Computer Engineering, University of Oklahoma, Norman, OK 73019 (United States)

    2017-05-01

    The aim of this study was to quantitatively characterize a micro focus x-ray tube that can operate in both continuous and pulsed emission modes. The micro focus x-ray source (Model L9181-06, Hamamatsu Photonics, Japan) has a varying focal spot size ranging from 16 µm to 50 µm as the source output power changes from 10 to 39 W. We measured the source output, beam quality, focal spot sizes, kV accuracy, spectra shapes and spatial resolution. Source output was measured using an ionization chamber for various tube voltages (kVs) with varying current (µA) and distances. The beam quality was measured in terms of half value layer (HVL), kV accuracy was measured with a non-invasive kV meter, and the spectra was measured using a compact integrated spectrometer system. The focal spot sizes were measured using a slit method with a CCD detector with a pixel pitch of 22 µm. The spatial resolution was quantitatively measured using the slit method with a CMOS flat panel detector with a 50 µm pixel pitch, and compared to the qualitative results obtained by imaging a contrast bar pattern. The focal spot sizes in the vertical direction were smaller than that of the horizontal direction, the impact of which was visible when comparing the spatial resolution values. Our analyses revealed that both emission modes yield comparable imaging performances in terms of beam quality, spectra shape and spatial resolution effects. There were no significantly large differences, thus providing the motivation for future studies to design and develop stable and robust cone beam imaging systems for various diagnostic applications. - Highlights: • A micro focus x-ray source that operates in both continuous and pulse emission modes was quantitatively characterized. • The source output, beam quality, focal spot measurements, kV accuracy, spectra analyses and spatial resolution were measured. • Our analyses revealed that both emission modes yield comparable imaging performances in terms of beam

  3. Depth distribution of abiotic drivers of N mineralization and methane emission from a continuously and intermittently flooded Bangladeshi paddy soil

    Science.gov (United States)

    Akter, Masuda; Kader, Md. Abdul; Pierreux, Sofie; Boeckx, Pascal; Kamal, Ahammad Mostafa; Sleutel, Steven

    2016-04-01

    Water-saving irrigation such as AWD may significantly alter depth profiles of moisture content, pH, Eh and soil microbial activity. Modelling the effect of irrigation management on soil N mineralization, therefore requires detailed insight into depth distribution of these variables and dissolved organic carbon (DOC), and evolution of electron acceptors. We set up a field experiment at Bangladesh Agricultural University from January to May' 2015. The cultivated rice variety (BRRI dhan28) was grown under continuous flooding (CF) and alternate wetting and drying (AWD) management, with 120 kg N ha-1(N120) or without (N0)N fertilizer application. We measured soil mineral N and plant N uptake to evaluate N mineralization. CH4 emissions were monitored with timely gas sample collection and GC-analysis. Soil Eh at four depths and temperature at two depths were monitored continuously by Eh/T°-probes connected to a HYPNOS III data logger (MVH, The Netherlands). Simultaneously, soil solution from three depths were sampled with rhizon samplers to track DOC, Fe and Mn in solution. Over the growing season soil and air temperature increased by 8°C, and soil pH stayed near neutral (6.7 to 7.8). In all depths of AWD and CF, Eh dropped sharply to methanic conditions within 21 days after transplanting (DAT). Low redox-potential continued until 77DAT in all cases, except in the puddle layers under AWD, where redox raised to -200mV during drainage. Fe and Mn in soil solution increased gradually over the growing season, indicating continued reductive dissolution of Fe and Mn (hydro-)oxides. DOC increased continuously as well in all depths. Besides to release of DOC bound to pedogenic oxides upon their reductive dissolution, higher plant and soil microbial activity with increasing soil temperature (till 28°C) through the growing season explains the increasing DOC levels. Increasing methanogenic activity as indicated by the high CH4 emissions at 70-84DAT under both CF and AWD is

  4. Sodium Velocity Maps on Mercury

    Science.gov (United States)

    Potter, A. E.; Killen, R. M.

    2011-01-01

    The objective of the current work was to measure two-dimensional maps of sodium velocities on the Mercury surface and examine the maps for evidence of sources or sinks of sodium on the surface. The McMath-Pierce Solar Telescope and the Stellar Spectrograph were used to measure Mercury spectra that were sampled at 7 milliAngstrom intervals. Observations were made each day during the period October 5-9, 2010. The dawn terminator was in view during that time. The velocity shift of the centroid of the Mercury emission line was measured relative to the solar sodium Fraunhofer line corrected for radial velocity of the Earth. The difference between the observed and calculated velocity shift was taken to be the velocity vector of the sodium relative to Earth. For each position of the spectrograph slit, a line of velocities across the planet was measured. Then, the spectrograph slit was stepped over the surface of Mercury at 1 arc second intervals. The position of Mercury was stabilized by an adaptive optics system. The collection of lines were assembled into an images of surface reflection, sodium emission intensities, and Earthward velocities over the surface of Mercury. The velocity map shows patches of higher velocity in the southern hemisphere, suggesting the existence of sodium sources there. The peak earthward velocity occurs in the equatorial region, and extends to the terminator. Since this was a dawn terminator, this might be an indication of dawn evaporation of sodium. Leblanc et al. (2008) have published a velocity map that is similar.

  5. Continuous Eddy Covariance Measurements of N2O Emissions and Controls from an Intensively Grazed Dairy Farm

    Science.gov (United States)

    Schipper, L. A.; Liang, L. L.; Wall, A.; Campbell, D.

    2017-12-01

    New Zealand's greenhouse gas (GHG) inventory is disproportionally dominated by methane and nitrous oxide which account for 54% of emissions. These GHGs are derived from pastoral agriculture that supports dairying and meat production. To date, most studies on quantifying or mitigating agricultural N2O emissions have used flux chamber measurements. Recent advances in detector technology now means that routine field-to-farm scale measurements of N2O emissions might be possible using the eddy covariance technique. In late 2016, we established an eddy covariance tower that measured N2O emissions from a dairy farm under year-round grazing. An Aerodyne quantum cascade laser (QCL) was used to measure N2O, CH4 and H2O concentration at 10 Hz and housed in a weatherproof and insulated enclosure (0.9 m ´ 1.2 m) and powered by mains power (240 VAC). The enclosure maintained a stable setpoint temperature (30±0.2°C) by using underground cooling pipes, fans and recirculating instrument heat. QCL (true 10 Hz digital) and CSAT3B sonic anemometer high frequency data are aligned using Network Time Protocol and EddyPro covariance maximisation during flux processing. Fluxes generally integrated over about 6-8 ha. Stable summertime baseline N2O fluxes (FN2O) were around 12-24 g N2O-N ha-1 d-1 (0.5-1.0 nmol N2O m-2 s-1). Grazing by cows during dry summer resulted in only modest increases in FN2O to 24-48 g N2O-N ha-1 d-1 (1.0-2.0 nmol N2O m-2 s-1). However, the first rain events after grazing resulted in large, short-lived (1-3 days) FN2O pulses reaching peaks of 144-192 g N2O-N ha-1 d-1 (6-8 nmol N2O m-2 s-1). During these elevated N2O emissions, FN2O displayed a significant diurnal signal, with peak fluxes mid-afternoon which was best explained by variation in shallow soil temperature in summer. In winter (both cooler and wetter) FN2O were not as easily explained on a daily basis but were generally greater than summer. Throughout the year, FN2O was strongly dependent on water filled

  6. Technique for obtaining an engine emissions model based on continuous EPA-CVS test data and a dynamic vehicle model. SAE Paper 760156

    Energy Technology Data Exchange (ETDEWEB)

    Radtke, R.; Frank, A.; Beachley, N.

    1976-01-01

    A new technique for obtaining engine emission flow rate maps has been developed. The maps are based on specific emissions data obtained on a continuous basis over a single EPA-CVS urban driving cycle test. The data are averaged for the various torque-speed ranges of the engine. It has been found that these dynamic average emission flow rate maps, which are functions only of engine torque and speed, allow instantaneous emissions to be fairly accurately predicted. It also appears that the technique might be used advantageously to determine engine calibration parameters.

  7. Effects of Biochar on the Net Greenhouse Gas Emissions under Continuous Flooding and Water-Saving Irrigation Conditions in Paddy Soils

    Directory of Open Access Journals (Sweden)

    Le Qi

    2018-05-01

    Full Text Available In this study, we investigated the greenhouse gas emission under different application of biochar in the conditions of continuous flooding and water-saving irrigation in paddy fields, whereas, plant and soil carbon sequestration were considered in the calculation of net greenhouse gas emissions. The emission rates of methane (CH4, carbon dioxide (CO2, and nitrous oxide (N2O gases were simultaneously monitored once every 7–10 days using the closed-chamber method. As a whole, the net greenhouse gas emission in the water-saving irrigation was more than that of the continuous flooding irrigation conditions. Compared with the water-saving irrigation, the continuous flooding irrigation significantly increased the CH4 in the control (CK and chemical fertilizer treatments (NPK. The CO2 emissions increased in each treatment of the water-saving irrigation condition, especially in the chemical fertilizer treatments (NPKFW. Similarly, the soil N2O emission was very sensitive to the water-saving irrigation condition. An interesting finding is that the biochar application in soils cut down the soil N2O emission more significantly than NPKFW in the water-saving irrigation condition while the effect of biochar increased under the continuous flooding irrigation condition.

  8. Managing mercury in the great lakes: an analytical review of abatement policies.

    Science.gov (United States)

    Mohapatra, Satya P; Nikolova, Iana; Mitchell, Anne

    2007-04-01

    Mercury, a toxic metal known to have several deleterious affects on human health, has been one of the principal contaminants of concern in the Great Lakes basin. There are numerous anthropogenic sources of mercury to the Great Lakes area. Combustion of coal, smelting of non ferrous metals, and incineration of municipal and medical waste are major sources of mercury emissions in the region. In addition to North American anthropogenic emissions, global atmospheric emissions also significantly contribute to the deposition of mercury in the Great Lakes basin. Both the USA and Canada have agreed to reduce human exposure to mercury in the Great Lakes basin and have significantly curtailed mercury load to this region through individual and joint efforts. However, many important mercury sources, such as coal-fired power plants, still exist in the vicinity of the Great Lakes. More serious actions to drastically reduce mercury sources by employing alternative energy sources, restricting mercury trade and banning various mercury containing consumer products, such as dental amalgam are as essential as cleaning up the historical deposits of mercury in the basin. A strong political will and mass momentum are crucial for efficient mercury management. International cooperation is equally important. In the present paper, we have analyzed existing policies in respective jurisdictions to reduce mercury concentration in the Great Lakes environment. A brief review of the sources, occurrence in the Great Lakes, and the health effects of mercury is also included.

  9. Removal of mercury from coal via a microbial pretreatment process

    Science.gov (United States)

    Borole, Abhijeet P [Knoxville, TN; Hamilton, Choo Y [Knoxville, TN

    2011-08-16

    A process for the removal of mercury from coal prior to combustion is disclosed. The process is based on use of microorganisms to oxidize iron, sulfur and other species binding mercury within the coal, followed by volatilization of mercury by the microorganisms. The microorganisms are from a class of iron and/or sulfur oxidizing bacteria. The process involves contacting coal with the bacteria in a batch or continuous manner. The mercury is first solubilized from the coal, followed by microbial reduction to elemental mercury, which is stripped off by sparging gas and captured by a mercury recovery unit, giving mercury-free coal. The mercury can be recovered in pure form from the sorbents via additional processing.

  10. Technical report: mercury in the environment: implications for pediatricians.

    Science.gov (United States)

    Goldman, L R; Shannon, M W

    2001-07-01

    Mercury is a ubiquitous environmental toxin that causes a wide range of adverse health effects in humans. Three forms of mercury (elemental, inorganic, and organic) exist, and each has its own profile of toxicity. Exposure to mercury typically occurs by inhalation or ingestion. Readily absorbed after its inhalation, mercury can be an indoor air pollutant, for example, after spills of elemental mercury in the home; however, industry emissions with resulting ambient air pollution remain the most important source of inhaled mercury. Because fresh-water and ocean fish may contain large amounts of mercury, children and pregnant women can have significant exposure if they consume excessive amounts of fish. The developing fetus and young children are thought to be disproportionately affected by mercury exposure, because many aspects of development, particularly brain maturation, can be disturbed by the presence of mercury. Minimizing mercury exposure is, therefore, essential to optimal child health. This review provides pediatricians with current information on mercury, including environmental sources, toxicity, and treatment and prevention of mercury exposure.

  11. Mercury in the environment : a primer

    Energy Technology Data Exchange (ETDEWEB)

    Lourie, B.; Glenn, W. (ed.); Ogilvie, K.; Everhardus, E.; Friesen, K.; Rae, S.

    2003-06-01

    This report provides an overview of the occurrence and effects of mercury in the environment and its impacts on human health. Low levels of mercury occur naturally everywhere in the environment in plants, animals, rocks and air. Incidental emissions occur when natural mercury is released to the environment through human activity. In Canada, coal burning and metal processing are the two largest point sources of atmospheric mercury emissions. Energy facilities have the option to invest in expensive control technologies for coal plants, or they can generate electricity from alternative energy sources. Energy conservation, however, offers the greatest overall benefits for the environment and the public. Mercury can also be released when products containing mercury (such as electrical switches, thermostats, dental amalgam, and thermometers) are broken while in use, or when they are crushed in garbage trucks and dumped in landfills. Source separation is the best way to reduce waste-related emissions. Once mercury is released to the natural environment, it can be transported long distances through air or watercourses. It is volatile, therefore evaporates readily to the atmosphere where it may do one of three things: it may fall out near the point where it was emitted; it may be transported long distances to some point downwind; or, it may enter the global atmospheric mercury pool where it will circle the globe for a year or more within the Earth's major weather systems before being deposited. Data from Canada's National Pollutant Release Inventory indicates that mercury releases and transfers total 28,674 kg per year. The most critical component of the mercury cycle is the conversion of inorganic forms of mercury to the organic compound methylmercury which is more toxic to humans. Most concern about mercury focuses on lakes and other aquatic ecosystems. Fish in hydroelectric reservoirs have been found to contain elevated methylmercury levels because natural

  12. Environmental mercury problem

    Energy Technology Data Exchange (ETDEWEB)

    D' Itri, F.M.

    1972-01-01

    The urgent need to eliminate or greatly reduce the discharge of mercury into the environment is paramount to the health and well being of man. That all forms of mercury are hazardous is widely recognized, but what is more devastating to our society is that all forms of mercury appear to have the potential to be converted in to highly toxic monomethylmercury, or dimethylmercury. This paper examined the historical uses of mercury, the background concentrations of mercury, the analytical methods for the determination of mercury, the contamination of the food chain by mercury, the biological methylation of mercury, the decontamination and restoration of mercury polluted areas, the epidemiology and toxicology of mercury, and the chronology of the world's mercury poisoning problem.

  13. The influence of floodplains on mercury availability

    Energy Technology Data Exchange (ETDEWEB)

    Wallschlaeger, D.; Wilken, R.D. [GKSS Research Center, Geesthacht (Germany). Inst. of Physical and Chemical Analytics

    1997-09-01

    The floodplains of the German river Elbe affect the mercury distribution in the river system in two different ways: they act both as a medium-term sink and as a long-term source. The large amounts of mercury deposited onto the floodplains during annual floodings are first effectively fixed in the soils, rendering them basically unavailable. Sequential extraction experiments reveal that only a small fraction of the mercury (< 3%) is present in available forms, whereas the vast majority is associated with humic substances or present in sulfidic binding forms. After deposition, a small fraction of the total mercury is gradually remobilized into the aqueous phase bound passively to water-soluble humic acids. The availability of mercury in these complexes is still low, since environmental influences such as changes in pH or redox potential and competition with other cations do not cause any mercury liberation. In the next step, reactions in the aqueous phase lead to the formation of the highly available volatile species Hg{sup 0} and dimethylmercury (DMM). Their evaporation gives rise to a strong mercury flux from the floodplains into the atmosphere. Preliminary mass balances indicate that the majority of the deposited mercury stays bound in the floodplain soils, while small amounts are emitted back into the river`s ecosystem. Atmospheric emission is more important as a remobilization pathway than aquatic export.

  14. Atmospheric mercury sources in the Mt. Amiata area, Italy

    International Nuclear Information System (INIS)

    Ferrara, R.; Mazzolai, B.; Edner, H.; Svanberg, S.; Wallinder, E.

    1998-01-01

    Mt. Amiata, located in southern Tuscany (Italy), is part of the geologic anomaly of the Mediterranean basin, which contains about 65% of the world's cinnabar (HgS) deposits. Atmospheric mercury emissions from the main sources (geothermal power plants, abandoned mine structures and spoil banks of roasted cinnabar ore) were determined by flux chamber and by LIDAR remote sensing. Mercury emissions from five geothermal power plants were on the order of 24 g h -1 for each plant, a value that remains constant throughout the year. In the month of July, the mine spoils (covering an area of =200000 m 2 ) emit a few grams of mercury per hour, while the abandoned mine structures give off 100-110 g h -1 . These two mercury sources were strongly influenced by ambient temperature. The area affected by mercury sources displays an average air mercury concentration of 20 ng m -3 during the summer and 10 ng m -3 in winter

  15. Mercury contamination extraction

    Science.gov (United States)

    Fuhrmann, Mark [Silver Spring, MD; Heiser, John [Bayport, NY; Kalb, Paul [Wading River, NY

    2009-09-15

    Mercury is removed from contaminated waste by firstly applying a sulfur reagent to the waste. Mercury in the waste is then permitted to migrate to the reagent and is stabilized in a mercury sulfide compound. The stable compound may then be removed from the waste which itself remains in situ following mercury removal therefrom.

  16. Mercury Contamination of Skin-whitening Creams in Phnom Penh, Cambodia

    Directory of Open Access Journals (Sweden)

    Thomas Murphy

    2015-01-01

    Conclusion. Some producers of skin-whitening creams in Thailand, China and Taiwan appear to be aware of the risks of mercury contamination and have modified their products. However, other producers of skin-whitening creams continue to use mercury. XRF analysis allows for rapid screening of mercury in cosmetics and should be used to gather additional information on mercury content in cosmetics in support of public health efforts to stem the import, export and sales of skin creams containing mercury.

  17. Mercury recycling in the United States in 2000

    Science.gov (United States)

    Brooks, William E.; Matos, Grecia R.

    2005-01-01

    Reclamation and recycling of mercury from used mercury- containing products and treatment of byproduct mercury from gold mining is vital to the continued, though declining, use of this metal. Mercury is reclaimed from mercury-containing waste by treatment in multistep high-temperature retorts-the mercury is volatized and then condensed for purification and sale. Some mercury-containing waste, however, may be landfilled, and landfilled material represents loss of a recyclable resource and a threat to the environment. Related issues include mercury disposal and waste management, toxicity and human health, and regulation of mercury releases in the environment. End-users of mercury-containing products may face fines and prosecution if these products are improperly recycled or not recycled. Local and State environmental regulations require adherence to the Resource Conservation and Recovery Act and the Comprehensive Environmental Response, Compensation, and Liability Act to regulate generation, treatment, and disposal of mercury-containing products. In the United States, several large companies and a number of smaller companies collect these products from a variety of sources and then reclaim and recycle the mercury. Because mercury has not been mined as a principal product in the United States since 1992, mercury reclamation from fabricated products has become the main source of mercury. Principal product mercury and byproduct mercury from mining operations are considered to be primary materials. Mercury may also be obtained as a byproduct from domestic or foreign gold-processing operations. In the early 1990s, U.S. manufacturers used an annual average that ranged from 500 to 600 metric tons of recycled and imported mercury for fabrication of automobile convenience switches, dental amalgam, fluorescent lamps, medical uses and thermometers, and thermostats. The amount now used for fabrication is estimated to be 200 metric tons per year or less. Much of the data on

  18. Elemental profiling and geographical differentiation of Ethiopian coffee samples through inductively coupled plasma-optical emission spectroscopy (ICP-OES), ICP-mass spectrometry (ICP-MS) and direct mercury analyzer (DMA).

    Science.gov (United States)

    Habte, Girum; Hwang, In Min; Kim, Jae Sung; Hong, Joon Ho; Hong, Young Sin; Choi, Ji Yeon; Nho, Eun Yeong; Jamila, Nargis; Khan, Naeem; Kim, Kyong Su

    2016-12-01

    This study was aimed to establish the elemental profiling and provenance of coffee samples collected from eleven major coffee producing regions of Ethiopia. A total of 129 samples were analyzed for forty-five elements using inductively coupled plasma (ICP)-optical emission spectroscopy (OES), ICP-mass spectrometry (MS) and direct mercury analyzer (DMA). Among the macro elements, K showed the highest levels whereas Fe was found to have the lowest concentration values. In all the samples, Ca, K, Mg, P and S contents were statistically significant (pCu>Sr>Zn>Rb>Ni>B. Contents of the trace elements were lower than the permissible standard values. Inter-regions differentiation by cluster analysis (CA), linear discriminant analysis (LDA) and principal component analysis (PCA) showed that micro and trace elements are the best chemical descriptors of the analyzed coffee samples. Copyright © 2016 Elsevier Ltd. All rights reserved.

  19. Effects of Continuous Flooding in No-rice Growing Season on CH4 and CO2 Emissions of Rice Growing Season with Straw Returning

    Directory of Open Access Journals (Sweden)

    XU Xiang-yu

    2017-03-01

    Full Text Available Straw returning is a straw utilization pattern which is widely promoted in China. It can increase the soil organic carbon and fertility, but straw returning also increase the CH4 and CO2 emissions. The effects of continuous flooding in no rice growing season on CH4 and CO2 emission in rice season with straw returning is not clear. This study was conducted with two different water managements in no rice growing season, one was the middle rice-natural drainage (RD and another was the middle rice-continuous flooding (RW. The aim was to investigate the characteristic of CH4 and CO2 emission flux in rice season under different water management with straw returning, and to provide data support for accurate assessment of paddy greenhouse gas emissions. The results showed that RD significantly reduced the CH4 accumulation emission flux in rice growing season compared with the RW, and 80% total CH4 emission flux in rice growing season was emission before the first drainage whether RD or RW. RW could cutdown the CO2 accumulation emission flux in rice growing season compared with RD, and about 60% total CO2 emission flux in rice growing season was emission after the first drainage whether RD or RW. RW reduced the soil NO3--N, NH4+-N and DOC concentration in rice growing season, and decreased the Eh value at 10 cm soil layer, but increased the acetic acid concentration. This might be the main reason of increasing the CH4 accumulation emission flux from RD.

  20. Characterization of Continuous and Pulsed Emission modes of a Hybrid Micro Focus X-ray Source for Medical Imaging Applications.

    Science.gov (United States)

    Ghani, Muhammad U; Wong, Molly D; Ren, Liqiang; Wu, Di; Zheng, Bin; Rong, John X; Wu, Xizeng; Liu, Hong

    2017-05-01

    The aim of this study was to quantitatively characterize a micro focus x-ray tube that can operate in both continuous and pulsed emission modes. The micro focus x-ray source (Model L9181-06, Hamamatsu Photonics, Japan) has a varying focal spot size ranging from 16-50 μm as the source output power changes from 10-39 W. We measured the source output, beam quality, focal spot sizes, kV accuracy, spectra shapes and spatial resolution. Source output was measured using an ionization chamber for various tube voltages (kVs) with varying current (μA) and distances. The beam quality was measured in terms of half value layer (HVL), kV accuracy was measured with a non-invasive kV meter, and the spectra was measured using a compact integrated spectrometer system. The focal spot sizes were measured using a slit method with a CCD detector with a pixel pitch of 22 μm. The spatial resolution was quantitatively measured using the slit method with a CMOS flat panel detector with a 50 μm pixel pitch, and compared to the qualitative results obtained by imaging a contrast bar pattern. The focal spot sizes in the vertical direction were smaller than that of the horizontal direction, the impact of which was visible when comparing the spatial resolution values. Our analyses revealed that both emission modes yield comparable imaging performances in terms of beam quality, spectra shape and spatial resolution effects. There were no significantly large differences, thus providing the motivation for future studies to design and develop stable and robust cone beam imaging systems for various diagnostic applications.

  1. Automatic semi-continuous accumulation chamber for diffuse gas emissions monitoring in volcanic and non-volcanic areas

    Science.gov (United States)

    Lelli, Matteo; Raco, Brunella; Norelli, Francesco; Virgili, Giorgio; Continanza, Davide

    2016-04-01

    Since various decades the accumulation chamber method is intensively used in monitoring activities of diffuse gas emissions in volcanic areas. Although some improvements have been performed in terms of sensitivity and reproducibility of the detectors, the equipment used for measurement of gas emissions temporal variation usually requires expensive and bulky equipment. The unit described in this work is a low cost, easy to install-and-manage instrument that will make possible the creation of low-cost monitoring networks. The Non-Dispersive Infrared detector used has a concentration range of 0-5% CO2, but the substitution with other detector (range 0-5000 ppm) is possible and very easy. Power supply unit has a 12V, 7Ah battery, which is recharged by a 35W solar panel (equipped with charge regulator). The control unit contains a custom programmed CPU and the remote transmission is assured by a GPRS modem. The chamber is activated by DataLogger unit, using a linear actuator between the closed position (sampling) and closed position (idle). A probe for the measure of soil temperature, soil electrical conductivity, soil volumetric water content, air pressure and air temperature is assembled on the device, which is already arranged for the connection of others external sensors, including an automatic weather station. The automatic station has been tested on the field at Lipari island (Sicily, Italy) during a period of three months, performing CO2 flux measurement (and also weather parameters), each 1 hour. The possibility to measure in semi-continuous mode, and at the same time, the gas fluxes from soil and many external parameters, helps the time series analysis aimed to the identification of gas flux anomalies due to variations in deep system (e.g. onset of volcanic crises) from those triggered by external conditions.

  2. Mercury Quick Facts: Health Effects of Mercury Exposure

    Science.gov (United States)

    Mercury Quick Facts Health Effects of Mercury Exposure What is Elemental Mercury? Elemental (metallic) mercury is the shiny, silver-gray metal found in thermometers, barometers, and thermostats and other ...

  3. Mercury Spill Responses - Five States, 2012-2015.

    Science.gov (United States)

    Wozniak, Ryan J; Hirsch, Anne E; Bush, Christina R; Schmitz, Stuart; Wenzel, Jeff

    2017-03-17

    Despite measures to educate the public about the dangers of elemental mercury, spills continue to occur in homes, schools, health care facilities, and other settings, endangering the public's health and requiring costly cleanup. Mercury is most efficiently absorbed by the lungs, and exposure to high levels of mercury vapor after a release can cause cough, sore throat, shortness of breath, nausea, vomiting, diarrhea, headaches, and visual disturbances (1). Children and fetuses are most susceptible to the adverse effects of mercury vapor exposure. Because their organ systems are still developing, children have increased respiratory rates, and they are closer to the ground where mercury vapors are most highly concentrated (2). To summarize key features of recent mercury spills and lessons learned, five state health departments involved in the cleanup (Iowa, Michigan, Missouri, North Carolina, and Wisconsin) compiled data from various sources on nonthermometer mercury spills from 2012 to 2015. The most common sites of contamination were residences, schools and school buses, health care facilities, and commercial and industrial facilities. Children aged mercury exposure. To protect the public's health after a mercury spill, it is important that local, state, and federal agencies communicate and coordinate effectively to ensure a quick response, and to minimize the spread of contamination. To reduce the number of mercury spills that occur in the United States, public health officials should increase awareness about exchange programs for mercury-containing items and educate school and health care workers about sources of mercury and how to dispose of them properly.

  4. PATHOLOGICAL EFFECTS OF DIETARY METHYL MERCURY IN AMERICAN KESTRELS (FALCO SPARVERIIUS)

    Science.gov (United States)

    Methyl mercury in the aquatic food web poses significant health risks to both wildlife and humans. One primary source of mercury contamination for both the aquatic and terrestrial systems is atmospheric deposition of inorganic mercury from industrial emissions. Once in the enviro...

  5. Evidence of mercury exposure in a particular low-income community in South Africa

    CSIR Research Space (South Africa)

    Oosthuizen, MA

    2010-09-01

    Full Text Available countries in terms of mercury emissions to the environment. The human nervous system is very sensitive to mercury. When metallic mercury vapour in the air is inhaled, it may cross the blood-brain barrier and cause permanent brain damage (Figure 1). Bacteria...

  6. Feasibility of mercury removal from simulated flue gas by activated chars made from poultry manures

    Science.gov (United States)

    Increased emphasis on reduction of mercury emissions from coal fired electric power plants has resulted in environmental regulations that may in the future require application of activated carbons as mercury sorbents for mercury removal. At the same time, the quantity of poultry manure generated eac...

  7. 76 FR 10896 - Science Advisory Board Staff Office; Request for Nominations; CASAC Mercury Review Panel

    Science.gov (United States)

    2011-02-28

    ... Nominations; CASAC Mercury Review Panel AGENCY: Environmental Protection Agency (EPA). ACTION: Notice. SUMMARY...'s Mercury Technical Support Document. DATES: Nominations should be submitted by March 21, 2011 per...-based standard for reducing HAP emissions. EPA is developing a draft risk assessment for mercury...

  8. 40 CFR Table 7 to Subpart Bbbb of... - Model Rule-Requirements for Continuous Emission Monitoring Systems (CEMS)

    Science.gov (United States)

    2010-07-01

    ... sulfur dioxide emissions of the municipal waste combustion unit 4. Carbon Monoxide 125 percent of the... Emission Monitoring Systems (CEMS) 7 Table 7 to Subpart BBBB of Part 60 Protection of Environment... emissions of the municipal waste combustion unit P.S. 2 Method 7E. 3. Sulfur Dioxide Inlet to control device...

  9. Elemental, mercuric and organic mercury: biological interactions and dilemmas

    Energy Technology Data Exchange (ETDEWEB)

    Aposhian, H.V. [Arizona Univ., Tucson, AZ (United States). Dept. of Molecular and Cellular Biology

    2002-09-01

    The greatest exposure of the general population to mercury appears to be from the elemental mercury emitted by dental amalgams. The next greatest exposure is from methylmercury in seafood. One of the major sources of this methylmercury is from mercury emitted by power plants burning fossil fuel. After the mercury enters the atmosphere, some of it will be deposited in lakes, rivers, bays, seas and oceans. In an aquatic environment, inorganic mercury is converted to methylmercury by bacteria. Once in the methylmercury form, it is bioaccumulated up the food chain. The bacteria are consumed by other unicellular organisms that are eaten by small fish; small fish are eaten by bigger fish; then bigger fish are eaten by other animals and humans. Methylmercury and elemental mercury are efficiently absorbed by humans and are transported rapidly to and deposited in the brain. In the brain, methylmercury is converted very slow to mercuric mercury while the elemental mercury is converted very quickly. Methylmercury and elemental mercury are extremely toxic to the developing central nervous system. Those at greatest risk are fetuses, very young children, women of childbearing age and pregnant women. There are no safe or reliable methods to remove these two forms of mercury and their biotransformant mercuric mercury from the human brain. The chelating agents DMPS (sodium dimercaptopropanesulfonate) and DMSA (dimercaptosuccinic acid) decrease the body's burden of mercury but not the brain's. Because of the toxicity of methylmercury, the major source of mercury emissions, namely, emissions from power plants, needs to be curtailed. (orig.)

  10. SORPTION OF MERCURY SPECIES BY ACTIVATED CARBONS AND CALCIUM-BASES SORBENTS: EFFECT OF TEMPERATURE, MERCURY CONCENTRATION AND ACID GASES

    Science.gov (United States)

    Bench-scale studies of mercury/sorbent reactions were conducted to understand mechanistic limitations of field-scale attempts to reduce emissions of mercury from combustion processes. The effects of temperature (60 - 140 degrees C), sulfur dioxide (SO2, 1000 ppm ), hydrogen chlor...

  11. Analysis of mercury species present during coal combustion by thermal desorption

    OpenAIRE

    López Antón, María Antonia; Yuan, Yang; Perry, Ron; Maroto Valer, Mercedes

    2010-01-01

    [EN] Mercury in coal and its emissions from coal-fired boilers is a topic of primary environmental concern in the United States and Europe. The predominant forms of mercury in coal-fired flue gas are elemental (Hg0) and oxidized (Hg2+, primarily as HgCl2). Because Hg2+ is more condensable and far more water soluble than Hg0, the wide variability in mercury speciation in coal-fired flue gases undermines the total mercury removal efficiency of most mercury emission control technologies. It is i...

  12. Exercise-induced stunning continues for at least one hour: evaluation with quantitative gated single-photon emission tomography

    International Nuclear Information System (INIS)

    Paul, A.K.; Hasegawa, Shinji; Yoshioka, Jun; Tsujimura, Eiichiro; Yamaguchi, Hitoshi; Tokita, Naoki; Maruyama, Atsushi; Xiuli, Mu; Nishimura, Tsunehiko

    1999-01-01

    To elucidate the after-effect of exercise on left ventricular (LV) function, end-diastolic volume (EDV), end-systolic volume (ESV) and ejection fraction (LVEF) were evaluated at 1 h after exercise and at rest by technetium-99m tetrofosmin gated myocardial single-photon emission tomography (SPET) using an automated program in 53 subjects. The subjects were grouped as follows: normal scan (n = 16), ischaemia (n = 19) and infarction (n = 18), based on the interpretation of perfusion images. Postexercise LVEF did not differ from resting LVEF in the groups with normal scan and infarction. In patients with ischaemia, postexercise EDV (90±17 ml, mean ±SD) and ESV (44±15 ml) were significantly higher than EDV (84±15 ml, P = 0.001) and ESV (36±14 ml, P<0.0005) at rest. LVEF was significantly depressed 1 h after exercise (53%±9% vs 58%±9%, P<0.0001). In ischaemic patients with depressed postexercise LVEF, LVEF difference between rest and postexercise showed a significant correlation with the sum of defect scores, which were reversible from exercise to rest perfusion images (r = 0.92, P<0.0001). These results indicate that exercise-induced LV dysfunction (myocardial stunning) continues for at least 1 h in ischaemic patients and that the extent of LVEF depression is determined by the severity of ischaemia. (orig.)

  13. Exercise-induced stunning continues for at least one hour: evaluation with quantitative gated single-photon emission tomography

    Energy Technology Data Exchange (ETDEWEB)

    Paul, A.K.; Hasegawa, Shinji; Yoshioka, Jun; Tsujimura, Eiichiro; Yamaguchi, Hitoshi; Tokita, Naoki; Maruyama, Atsushi; Xiuli, Mu; Nishimura, Tsunehiko [Division of Tracer Kinetics, Biomedical Research Center, Osaka University Medical School, Suita, Osaka (Japan)

    1999-04-29

    To elucidate the after-effect of exercise on left ventricular (LV) function, end-diastolic volume (EDV), end-systolic volume (ESV) and ejection fraction (LVEF) were evaluated at 1 h after exercise and at rest by technetium-99m tetrofosmin gated myocardial single-photon emission tomography (SPET) using an automated program in 53 subjects. The subjects were grouped as follows: normal scan (n = 16), ischaemia (n = 19) and infarction (n = 18), based on the interpretation of perfusion images. Postexercise LVEF did not differ from resting LVEF in the groups with normal scan and infarction. In patients with ischaemia, postexercise EDV (90{+-}17 ml, mean {+-}SD) and ESV (44{+-}15 ml) were significantly higher than EDV (84{+-}15 ml, P = 0.001) and ESV (36{+-}14 ml, P<0.0005) at rest. LVEF was significantly depressed 1 h after exercise (53%{+-}9% vs 58%{+-}9%, P<0.0001). In ischaemic patients with depressed postexercise LVEF, LVEF difference between rest and postexercise showed a significant correlation with the sum of defect scores, which were reversible from exercise to rest perfusion images (r = 0.92, P<0.0001). These results indicate that exercise-induced LV dysfunction (myocardial stunning) continues for at least 1 h in ischaemic patients and that the extent of LVEF depression is determined by the severity of ischaemia. (orig.) With 7 figs., 19 refs.

  14. Mercury in soils of the agro-industrial zone of Zima city (Irkutsk oblast)

    Science.gov (United States)

    Butakov, E. V.; Kuznetsov, P. V.; Kholodova, M. S.; Grebenshchikova, V. I.

    2017-11-01

    Data on mercury concentrations in soils of the agro-industrial zone of Zima city in Irkutsk oblast are discussed. It is shown that mercury concentrations in the plow horizon of studied soils exceed background values. The distribution pattern of mercury in soils of the investigated area is characterized. The revealed mercury anomalies are allocated to the industrial zone of the Sayanskkhimprom plant. The combined analysis of data on mercury concentrations in the plow and subplow horizons and on the chemical composition of snow indicates that mercury enters the soil mainly with atmospheric precipitation and is present there in the adsorbed form. The correlation analysis indicates that the local thermal power station plays a significant role as the source of mercury emission to the atmosphere. Close relationships between mercury concentrations and concentrations of mobile forms of elements attest to the presence of mobile organomineral mercury compounds in the studied soils.

  15. Mercury's complex exosphere: results from MESSENGER's third flyby.

    Science.gov (United States)

    Vervack, Ronald J; McClintock, William E; Killen, Rosemary M; Sprague, Ann L; Anderson, Brian J; Burger, Matthew H; Bradley, E Todd; Mouawad, Nelly; Solomon, Sean C; Izenberg, Noam R

    2010-08-06

    During MESSENGER's third flyby of Mercury, the Mercury Atmospheric and Surface Composition Spectrometer detected emission from ionized calcium concentrated 1 to 2 Mercury radii tailward of the planet. This measurement provides evidence for tailward magnetospheric convection of photoions produced inside the magnetosphere. Observations of neutral sodium, calcium, and magnesium above the planet's north and south poles reveal altitude distributions that are distinct for each species. A two-component sodium distribution and markedly different magnesium distributions above the two poles are direct indications that multiple processes control the distribution of even single species in Mercury's exosphere.

  16. Mercury's Complex Exosphere: Results from MESSENGER's Third Flyby

    Science.gov (United States)

    Vervack, Ronald J., Jr.; McClintock, William E.; Killen, Rosemary M.; Sprague, Ann L.; Anderson, Brian J.; Burger, Matthew H.; Bradley, E. Todd; Mouawad, Nelly; Solomon, Sean C.; Izenberg, Noam R.

    2010-01-01

    During MESSENGER's third flyby of Mercury, the Mercury Atmospheric and Surface Composition Spectrometer detected emission from ionized calcium concentrated 1 to 2 Mercury radii tailward of the planet. This measurement provides evidence for tailward magnetospheric convection of photoions produced inside the magnetosphere. Observations of neutral sodium, calcium, and magnesium above the planet's north and south poles reveal attitude distributions that are distinct for each species. A two-component sodium distribution and markedly different magnesium distributions above the two poles are direct indications that multiple processes control the distribution of even single species in Mercury's exosphere,

  17. Gaseous elemental mercury (GEM) fluxes over canopy of two typical subtropical forests in south China

    Science.gov (United States)

    Yu, Qian; Luo, Yao; Wang, Shuxiao; Wang, Zhiqi; Hao, Jiming; Duan, Lei

    2018-01-01

    Mercury (Hg) exchange between forests and the atmosphere plays an important role in global Hg cycling. The present estimate of global emission of Hg from natural source has large uncertainty, partly due to the lack of chronical and valid field data, particularly for terrestrial surfaces in China, the most important contributor to global atmospheric Hg. In this study, the micrometeorological method (MM) was used to continuously observe gaseous elemental mercury (GEM) fluxes over forest canopy at a mildly polluted site (Qianyanzhou, QYZ) and a moderately polluted site (Huitong, HT, near a large Hg mine) in subtropical south China for a full year from January to December in 2014. The GEM flux measurements over forest canopy in QYZ and HT showed net emission with annual average values of 6.67 and 0.30 ng m-2 h-1, respectively. Daily variations of GEM fluxes showed an increasing emission with the increasing air temperature and solar radiation in the daytime to a peak at 13:00, and decreasing emission thereafter, even as a GEM sink or balance at night. High temperature and low air Hg concentration resulted in the high Hg emission in summer. Low temperature in winter and Hg absorption by plant in spring resulted in low Hg emission, or even adsorption in the two seasons. GEM fluxes were positively correlated with air temperature, soil temperature, wind speed, and solar radiation, while it is negatively correlated with air humidity and atmospheric GEM concentration. The lower emission fluxes of GEM at the moderately polluted site (HT) when compared with that in the mildly polluted site (QYZ) may result from a much higher adsorption fluxes at night in spite of a similar or higher emission fluxes during daytime. This shows that the higher atmospheric GEM concentration at HT restricted the forest GEM emission. Great attention should be paid to forests as a crucial increasing Hg emission source with the decreasing atmospheric GEM concentration in polluted areas because of Hg

  18. Substance Flow Analysis of Mercury in China

    Science.gov (United States)

    Hui, L. M.; Wang, S.; Zhang, L.; Wang, F. Y.; Wu, Q. R.

    2015-12-01

    In previous studies, the emission of anthropogenic atmospheric Hg in China as well as single sector have been examined a lot. However, there might have been more Hg released as solid wastes rather than air. Hg stored in solid wastes may be released to air again when the solid wastes experience high temperature process or cause local pollution if the solid wastes are stacked casually for a long time. To trace the fate of Hg in China, this study developed the substance flow of Hg in 2010 covering all the sectors summarized in table 1. Below showed in Figure 1, the total Hg input is 2825t. The unintentional input of Hg, mined Hg, and recycled Hg account for 57%, 32% and 11% respectively. Figure 2 provides the detail information of substance flow of Hg. Byproducts from one sector may be used as raw materials of another, causing cross Hg flow between sectors. The Hg input of cement production is 303 t, of which 34% comes from coal and limestone, 33% comes from non-ferrous smelting, 23% comes from coal combustion, 7% comes from iron and steel production and 3% comes from mercury mining. Hg flowing to recycledHg production is 639 t, mainly from Hg contained in waste active carbon and mercuric chloride catalyst from VCM production and acid sludge from non-ferrous smelting. There are 20 t mercury flowing from spent mercury adding products to incineration. Figure1 and Figure 2 also show that 46% of the output Hg belongs to "Lagged release", which means this part of mercury might be released later. The "Lagged release" Hg includes 809 t Hg contained in stacked byproducts form coal combustion, non-ferrous smelting, iron and steel production, Al production, cement production and mercury mining, 161t Hg stored in the pipeline of VCM producing, 10 t Hg in fluorescent lamps that are in use and 314 t mercury stored in materials waiting to be handled with in recycled mercury plants. There is 112 t Hg stored in landfill and 129 t Hg exported abroad with the export of mercury adding

  19. Long term continuous field survey to assess nutrient emission impact from irrigated paddy field into river catchment

    Science.gov (United States)

    Kogure, Kanami; Aichi, Masaatsu; Zessner, Matthias

    2017-04-01

    In order to achieve good river environment, it is very important to understand and to control nutrient behavior such as Nitrogen and Phosphorus. As we could reduce impact from urban and industrial activities by wastewater treatment, pollution from point sources are likely to be controlled. Besides them, nutrient emission from agricultural activity is dominant pollution source into the river system. In many countries in Asia and Africa, rice is widely cultivated and paddy field covers large areas. In Japan 54% of its arable land is occupied with irrigated paddy field. While paddy field can deteriorate river water quality due to fertilization, it is also suggested that paddy field can purify water. We carried out field survey in middle reach of the Tone River Basin with focus on a paddy field IM. The objectives of the research are 1) understanding of water and nutrient balance in paddy field, 2) data collection for assessing nutrient emission. Field survey was conducted from June 2015 to October 2016 covering two flooding seasons in summer. In our measurement, all input and output were measured regarding water, N and P to quantify water and nutrient balance in the paddy field. By measuring water quality and flow rate of inflow, outflow, infiltrating water, ground water and flooding water, we tried to quantitatively understand water, N and P cycle in a paddy field including seasonal trends, and changes accompanied with rainy events and agricultural activities like fertilization. Concerning water balance, infiltration rate was estimated by following equation. Infiltration=Irrigation water + Precipitation - Evapotranspiration -Outflow We estimated mean daily water balance during flooding season. Infiltration is 11.9mm/day in our estimation for summer in 2015. Daily water reduction depth (WRD) is sum of Evapotranspiration and Infiltration. WRD is 21.5mm/day in IM and agrees with average value in previous research. Regarding nutrient balance, we estimated an annual N and

  20. Environmental and health aspects of lighting: Mercury

    Energy Technology Data Exchange (ETDEWEB)

    Clear, R.; Berman, S.

    1993-07-01

    Most discharge lamps, including fluorescent lamps, metal halide lamps, and high pressure sodium lamps, contain Mercury, a toxic chemical. Lighting professionals need to be able to respond to questions about the direct hazards of Mercury from accidentally breaking lamps, and the potential environmental hazards of lamp operation and disposal. We calculated the exposures that could occur from an accidental breakage of lamps. Acute poisoning appears almost impossible. Under some circumstances a sealed environment, such as a space station, could be contaminated enough to make it unhealthy for long-term occupation. Mercury becomes a potential environmental hazard after it becomes methylated. Mercury is methylated in aquatic environments, where it may accumulate in fish, eventually rendering them toxic to people and other animals. Lighting causes Mercury to enter the environment directly from lamp disposal, and indirectly from power plant emissions. The environmental tradeoffs between incandescent and discharge lamps depend upon the amounts released by these two sources, their local concentrations, and their probabilities of being methylated. Indirect environmental effects of lighting also include the release of other heavy metals (Cadmium, Lead and Arsenic), and other air pollutants and carbon dioxide that are emitted by fossil fuel power plants. For a given light output, the level of power plant emissions depends upon the efficacy of the light source, and is thus much larger for incandescent lamps than for fluorescent or discharge lamps. As disposal and control technologies change the relative direct and indirect emissions from discharge and incandescent lamps will change.

  1. Hidden sources of mercury in clinical laboratories.

    Science.gov (United States)

    Alvarez-Chavez, C R; Federico-Perez, R A; Gomez-Alvarez, A; Velazquez-Contreras, L E; Perez-Rios, R

    2014-09-01

    The healthcare sector is an important contributor to mercury (Hg) pollution because of the potential presence of mercury in thermometers, blood pressure cuffs, amalgams, etc. There are also other potential sources of mercury in this sector which are used frequently and in high volumes where the presence of the metal is not obvious and which might be collectively contributing to pollution. For instance, some chemicals used for the clinical diagnosis of illness may contain mercury. The goal of this study was to investigate potential sources of mercury pollution, which originate from clinical laboratory discharges, using an exploratory approach. The focus was on the residue generated during automatic analysis of patients' bodily fluids at a medical center in Hermosillo, Sonora, Mexico. This study shows an overview of what might be happening in the region or the country related to non-obvious sources of mercury in the healthcare sector. The results showed measurable levels of mercury in the residues coming from urine sediment analysis. These amounts do not exceed the maximum allowed by Mexican environmental regulations; nevertheless, the frequency and cumulative volume of residues generated, combined with the potential for persistence and the bioaccumulation of mercury in the environment, warrant attention. The work carried out in this study is being taken as a model for future studies for pollution prevention in the healthcare sector with the goal of measuring mercury emissions to the environment from clinical laboratory wastewater, including identifying sources which--while not obvious--could be important given the frequency and volume of their use in the clinical diagnosis.

  2. Transport and transformation of mercury during wet flue gas cleaning process of nonferrous metal smelting.

    Science.gov (United States)

    Liu, Zhilou; Wang, Dongli; Peng, Bing; Chai, Liyuan; Liu, Hui; Yang, Shu; Yang, Bentao; Xiang, Kaisong; Liu, Cao

    2017-10-01

    Reducing mercury emission is hot topic for international society. The first step for controlling mercury in fuel gas is to investigate mercury distribution and during the flue gas treatment process. The mercury transport and transformation in wet flue gas cleaning process of nonferrous smelting industry was studied in the paper with critical important parameters, such as the solution temperature, Hg 0 concentration, SO 2 concentration, and Hg 2+ concentration at the laboratory scale. The mass ratio of the mercury distribution in the solution, flue gas, sludge, and acid fog from the simulated flue gas containing Hg 2+ and Hg 0 was 49.12~65.54, 18.34~35.42, 11.89~14.47, and 1.74~3.54%, respectively. The primary mercury species in the flue gas and acid fog were gaseous Hg 0 and dissolved Hg 2+ . The mercury species in the cleaning solution were dissolved Hg 2+ and colloidal mercury, which accounted for 56.56 and 7.34% of the total mercury, respectively. Various mercury compounds, including Hg 2 Cl 2 , HgS, HgCl 2 , HgSO 4 , and HgO, existed in the sludge. These results for mercury distribution and speciation are highly useful in understanding mercury transport and transformation during the wet flue gas cleaning process. This research is conducive for controlling mercury emissions from nonferrous smelting flue gas and by-products.

  3. Minamata Convention on Mercury

    Science.gov (United States)

    On November 6, 2013 the United States signed the Minamata Convention on Mercury, a new multilateral environmental agreement that addresses specific human activities which are contributing to widespread mercury pollution

  4. Evolution of vent system during continuous ash emissions with Strombolian eruptions in 2000-2011 at Suwanosejima volcano, SW Japan

    Science.gov (United States)

    Shimano, T.; Iguchi, M.

    2011-12-01

    Strombolian and vulcanian eruptions are characterized by surface manifestation of unsteadiness such as the alternation of fountaining and successive ash emission with/without explosions. The activity sometimes evolves into much more destructive styles such as plinian eruption. The time evolution of these surface eruptive phenomena is strongly dependent on the history of magmas ascending in volcanic conduits as well as that of conduit condition itself. Suwanosejima volcano has been continuously active for more than several decades. The eruption styles it has shown were strombolian to small vulcanian that emit ash particles with small amount of ballistic bombs. Geological records show that such weak eruptions for several decades seemed to have preceded some major historical sub-plinian eruptions at this volcano. Thus, continuous observation for such kind of activities would be helpful for understanding or predicting the evolution of activity toward major eruptions. Although Suwanosejima is a remote island, with population of ca. 50, we had collected ash fall samples occasionally for ten years. Now we set up automatic ashfall sampling machine at the foot of Suwanosejima and are collecting ashfall sample every 2.5 days to investigate evolution of chemistry and crystallization processes of magma during ascent in conduit. The advantage of observing activities at Suwanosejima is that we can look into active vents from the rim of the caldera, 400 m apart and 300 m higher than the main central vent. We set up a camera to observe surface phenomena in the vicinity of vent, and correlated characteristics of eruptive materials with surface phenomena. The 2000-2011 activity of Suwanosejima volcano can be divided into three phases; phase I from 2000-2003, phase II from 2004-2008, and phase III from 2009-2011. Each phase is alternation of active and quiescent periods for weeks to months. There is a tendency that in active periods glassy particles are dominant whereas crystalline

  5. Overview of major processes and mechanisms affecting the mercury cycle on different spatial and temporal scales

    Directory of Open Access Journals (Sweden)

    Sprovieri F.

    2010-12-01

    Full Text Available Mercury emissions to the atmosphere and its transport, transformation and deposition to and re-emission from terrestrial and aquatic ecosystems on hemispherical and global scales has received increasing attention from both the scientific and the regulatory communities during the last twenty years. It is well known that the atmosphere is the major transport media through which mercury is redistributed on global scale once it is released from point and diffuse emission sources. A substantial amount of research has been carried out worldwide aiming to assess the relationships between emissions from natural vs. anthropogenic sources, inter-hemispherical atmospheric transport patterns, and atmospheric deposition to and re-emission from oceans, its bioaccumulation in fish, and evaluation of policy strategies to reduce the impact of mercury emissions on human health and ecosystems. This chapter provides a highlight of key aspects related to mercury contamination, including: a major processes affecting the mercury cycle between the atmosphere and aquatic and terrestrial ecosystems, b mercury emissions from natural and anthropogenic sources, c spatial and temporal distributions and trends of mercury species over the northern and southern hemispheres, d the chemical and physical processes affecting the transport and fate of atmospheric mercury, and emajor policy frameworks aiming to control the impact of mercury on human health and ecosystems.

  6. Integrated Removal of NOx with Carbon Monoxide as Reductant, and Capture of Mercury in a Low Temperature Selective Catalytic and Adsorptive Reactor

    Energy Technology Data Exchange (ETDEWEB)

    Neville Pinto; Panagiotis Smirniotis; Stephen Thiel

    2010-08-31

    Coal will likely continue to be a dominant component of power generation in the foreseeable future. This project addresses the issue of environmental compliance for two important pollutants: NO{sub x} and mercury. Integration of emission control units is in principle possible through a Low Temperature Selective Catalytic and Adsorptive Reactor (LTSCAR) in which NO{sub x} removal is achieved in a traditional SCR mode but at low temperature, and, uniquely, using carbon monoxide as a reductant. The capture of mercury is integrated into the same process unit. Such an arrangement would reduce mercury removal costs significantly, and provide improved control for the ultimate disposal of mercury. The work completed in this project demonstrates that the use of CO as a reductant in LTSCR is technically feasible using supported manganese oxide catalysts, that the simultaneous warm-gas capture of elemental and oxidized mercury is technically feasible using both nanostructured chelating adsorbents and ceria-titania-based materials, and that integrated removal of mercury and NO{sub x} is technically feasible using ceria-titania-based materials.

  7. The fate and management of high mercury-containing lamps from high technology industry.

    Science.gov (United States)

    Chang, T C; You, S J; Yu, B S; Kong, H W

    2007-03-22

    This study investigated the fate and management of high mercury-contained lamps, such as cold cathode fluorescent lamps (CCFLs), ultraviolet lamps (UV lamps), and super high pressure mercury lamps (SHPs), from high technology industries in Taiwan, using material flow analysis (MFA) method. Several organizations, such as Taiwan Environmental Protection Administration, Taiwan External Trade Development Council, the light sources manufactories, mercury-containing lamps importer, high technology industrial user, and waste mercury-containing lamps treatment facilities were interviewed in this study. According to this survey, the total mercury contained in CCFLs, UV lamps, and SHPs produced in Taiwan or imported from other countries was 886kg in year 2004. Among the various lamps containing mercury, 57kg mercury was exported as primary CCFLs, 7kg mercury was wasted as defective CCFLs, and 820kg mercury was used in the high technology industries, including 463kg mercury contained in exported industrial products using CCFLs as components. On the contrary, only 59kg of mercury was exported, including 57kg in CCFLs and 2kg in UV lamps. It reveals that 364kg mercury was consumed in Taiwan during year 2004. In addition, 140kg of the 364kg mercury contained in lamps used by high technology industry was well treated through industrial waste treatment system. Among the waste mercury from high technology industry, 80kg (57%), 53kg (38%), and 7kg (5%) of mercury were through domestic treatment, offshore treatment, and emission in air, respectively. Unfortunately, 224kg waste mercury was not suitable treated, including 199kg mercury contained in CCFL, which is a component of monitor for personal computer and liquid crystal display television, and 25kg non-treated mercury. Thus, how to recover the mercury from the waste monitors is an important challenge of zero wastage policy in Taiwan.

  8. Recommendations on the choice of gas analysis equipment for systems of continuous monitoring and accounting of emissions from thermal power plants

    Science.gov (United States)

    Kondrat'eva, O. E.; Roslyakov, P. V.; Burdyukov, D. A.; Khudolei, O. D.; Loktionov, O. A.

    2017-10-01

    According to Federal Law no. 219-FZ, dated July 21, 2014, all enterprises that have a significant negative impact on the environment shall continuously monitor and account emissions of harmful substances into the atmospheric air. The choice of measuring equipment that is included in continuous emission monitoring and accounting systems (CEM&ASs) is a complex technical problem; in particular, its solution requires a comparative analysis of gas analysis systems; each of these systems has its advantages and disadvantages. In addition, the choice of gas analysis systems for CEM&ASs should be maximally objective and not depend on preferences of separate experts and specialists. The technique of choosing gas analysis equipment that was developed in previous years at Moscow Power Engineering Institute (MPEI) has been analyzed and the applicability of the mathematical tool of a multiple criteria analysis to choose measuring equipment for the continuous emission monitoring and accounting system have been estimated. New approaches to the optimal choice of gas analysis equipment for systems of the continuous monitoring and accounting of harmful emissions from thermal power plants have been proposed, new criteria of evaluation of gas analysis systems have been introduced, and weight coefficients have been determined for these criteria. The results of this study served as a basis for the Preliminary National Standard of the Russian Federation "Best Available Technologies. Automated Systems of Continuous Monitoring and Accounting of Emissions of Harmful (Polluting) Substances from Thermal Power Plants into the Atmospheric Air. Basic Requirements," which was developed by the Moscow Power Engineering Institute, National Research University, in cooperation with the Council of Power Producers and Strategic Electric Power Investors Association and the All-Russia Research Institute for Materials and Technology Standardization.

  9. 40 CFR Table 13 to Subpart Uuu of... - Continuous Compliance With Organic HAP Emission Limits for Catalytic Cracking Units

    Science.gov (United States)

    2010-07-01

    ... Pollutants for Petroleum Refineries: Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery... Emission Limits for Catalytic Cracking Units 13 Table 13 to Subpart UUU of Part 63 Protection of... HAP Emission Limits for Catalytic Cracking Units As stated in § 63.1565(c)(1), you shall meet each...

  10. 40 CFR Table 24 to Subpart Uuu of... - Continuous Monitoring Systems for Inorganic HAP Emissions From Catalytic Reforming Units

    Science.gov (United States)

    2010-07-01

    ... Inorganic HAP Emissions From Catalytic Reforming Units 24 Table 24 to Subpart UUU of Part 63 Protection of... Pollutants for Petroleum Refineries: Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery... Inorganic HAP Emissions From Catalytic Reforming Units As stated in § 63.1567(b)(1), you shall meet each...

  11. 40 CFR Table 27 to Subpart Uuu of... - Continuous Compliance With Inorganic HAP Emission Limits for Catalytic Reforming Units

    Science.gov (United States)

    2010-07-01

    ... HAP Emission Limits for Catalytic Reforming Units 27 Table 27 to Subpart UUU of Part 63 Protection of... Pollutants for Petroleum Refineries: Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery... Inorganic HAP Emission Limits for Catalytic Reforming Units As stated in § 63.1567(c)(1), you shall meet...

  12. 40 CFR Table 20 to Subpart Uuu of... - Continuous Compliance With Organic HAP Emission Limits for Catalytic Reforming Units

    Science.gov (United States)

    2010-07-01

    ... Emission Limits for Catalytic Reforming Units 20 Table 20 to Subpart UUU of Part 63 Protection of... Pollutants for Petroleum Refineries: Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery... HAP Emission Limits for Catalytic Reforming Units As stated in § 63.1566(c)(1), you shall meet each...

  13. 40 CFR Table 10 to Subpart Uuu of... - Continuous Monitoring Systems for Organic HAP Emissions From Catalytic Cracking Units

    Science.gov (United States)

    2010-07-01

    ... Pollutants for Petroleum Refineries: Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery... Organic HAP Emissions From Catalytic Cracking Units 10 Table 10 to Subpart UUU of Part 63 Protection of... Organic HAP Emissions From Catalytic Cracking Units As stated in § 63.1565(b)(1), you shall meet each...

  14. 40 CFR Table 28 to Subpart Uuu of... - Continuous Compliance With Operating Limits for Inorganic HAP Emissions From Catalytic Reforming...

    Science.gov (United States)

    2010-07-01

    ... Limits for Inorganic HAP Emissions From Catalytic Reforming Units 28 Table 28 to Subpart UUU of Part 63... Hazardous Air Pollutants for Petroleum Refineries: Catalytic Cracking Units, Catalytic Reforming Units, and... Compliance With Operating Limits for Inorganic HAP Emissions From Catalytic Reforming Units As stated in § 63...

  15. 40 CFR Table 17 to Subpart Uuu of... - Continuous Monitoring Systems for Organic HAP Emissions From Catalytic Reforming Units

    Science.gov (United States)

    2010-07-01

    ... Organic HAP Emissions From Catalytic Reforming Units 17 Table 17 to Subpart UUU of Part 63 Protection of... Pollutants for Petroleum Refineries: Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery... Organic HAP Emissions From Catalytic Reforming Units As stated in § 63.1566(b)(1), you shall meet each...

  16. Wet and Dry Atmospheric Mercury Deposition Accumulates in Watersheds of the Northeastern United States

    Science.gov (United States)

    Boyer, E. W.; Grant, C.; Grimm, J.; Drohan, P. J.; Bennett, J.; Lawler, D.

    2013-12-01

    Mercury emissions to the atmosphere from coal-fired power plants and other sources such as waste incineration can be deposited to landscapes in precipitation and in dry fallout. Some mercury reaches watersheds and streams, where it can accumulate in sediments and biota. Human exposure to mercury occurs primarily through fish consumption, and currently mercury fish eating advisories are in place for many of the streams and lakes in the state. Here, we explored mercury in air, soils, water, and biota. To quantify atmospheric mercury deposition, we measured both wet and dry mercury deposition at over 10 locations in Pennsylvania, from which we present variation in mercury deposition and initial assessments of factors affecting the patterns. Further, we simulated mercury deposition at unmonitored locations in Pennsylvania and the northeastern United States over space and time with a high-resolution modeling technique that reflects storm tracks and air flow patterns. To consider mercury accumulation in watersheds, we collected data on soil mercury concentrations in a set of soil samples, and collected baseline data on mercury in streams draining 35 forested watersheds across Pennsylvania, spanning gradients of atmospheric deposition, climate and geology. Mercury concentrations were measured in stream water under base-flow conditions, in streambed sediments, aquatic mosses, and in fish tissues from brook trout. Results indicate that wet and dry atmospheric deposition is a primary source of mercury that is accumulating in watersheds of Pennsylvania and the northeastern United States.

  17. A gradient of mercury concentrations in Scottish single malt whiskies.

    Science.gov (United States)

    Rose, Neil L; Yang, Handong; Turner, Simon D

    2016-02-01

    Mercury (Hg) concentrations were measured in 26 Scottish single malt whiskies, and all found to be very low (mercury emissions and deposition over the last 200 years affecting concentrations in local waters used in whisky production. As UK atmospheric emissions of mercury have declined by 90 % since the 1970s, we suggest that whisky being produced today should have even lower Hg concentrations when consumed in 10- to 15-years time. This reduction may be compromised by the remobilisation of contaminants stored in catchment soils being transferred to source waters, but is very unlikely to raise the negligible health risk due to Hg from Scottish single malt whisky consumption.

  18. Mercury in Your Environment

    Science.gov (United States)

    Basic information about mercury, how it gets in the air, how people are exposed to it and health effects associated with exposure; what EPA and other organizations are doing to limit exposures; what citizens should know to minimize exposures and to reduce mercury in the environment; and information about products that contain mercury.

  19. Intentional intravenous mercury injection

    African Journals Online (AJOL)

    Three forms of mercury exist: elemental, inorganic and organic, all of which may be toxic with clinical consequences, depending on the type of exposure. Elemental mercury poisoning usually occurs via vapour inhalation, as mercury is well absorbed through the lungs. The central nervous system is then the major site of ...

  20. An automated SO2 camera system for continuous, real-time monitoring of gas emissions from Kīlauea Volcano's summit Overlook Crater

    Science.gov (United States)

    Kern, Christoph; Sutton, Jeff; Elias, Tamar; Lee, Lopaka; Kamibayashi, Kevan; Antolik, Loren; Werner, Cynthia

    2015-07-01

    SO2 camera systems allow rapid two-dimensional imaging of sulfur dioxide (SO2) emitted from volcanic vents. Here, we describe the development of an SO2 camera system specifically designed for semi-permanent field installation and continuous use. The integration of innovative but largely ;off-the-shelf; components allowed us to assemble a robust and highly customizable instrument capable of continuous, long-term deployment at Kīlauea Volcano's summit Overlook Crater. Recorded imagery is telemetered to the USGS Hawaiian Volcano Observatory (HVO) where a novel automatic retrieval algorithm derives SO2 column densities and emission rates in real-time. Imagery and corresponding emission rates displayed in the HVO operations center and on the internal observatory website provide HVO staff with useful information for assessing the volcano's current activity. The ever-growing archive of continuous imagery and high-resolution emission rates in combination with continuous data from other monitoring techniques provides insight into shallow volcanic processes occurring at the Overlook Crater. An exemplary dataset from September 2013 is discussed in which a variation in the efficiency of shallow circulation and convection, the processes that transport volatile-rich magma to the surface of the summit lava lake, appears to have caused two distinctly different phases of lake activity and degassing. This first successful deployment of an SO2 camera for continuous, real-time volcano monitoring shows how this versatile technique might soon be adapted and applied to monitor SO2 degassing at other volcanoes around the world.

  1. Mercury pollution in Wuchuan mercury mining area, Guizhou, Southwestern China: the impacts from large scale and artisanal mercury mining.

    Science.gov (United States)

    Li, Ping; Feng, Xinbin; Qiu, Guangle; Shang, Lihai; Wang, Shaofeng

    2012-07-01

    To evaluate the environmental impacts from large scale mercury mining (LSMM) and artisanal mercury mining (AMM), total mercury (THg) and methyl mercury (MeHg) were determined in mine waste, ambient air, stream water and soil samples collected from Wuchuan mercury (Hg) mining area, Guizhou, Southwestern China. Mine wastes from both LSMM and AMM contained high THg concentrations, which are important Hg contamination sources to the local environment. Total gaseous mercury (TGM) concentrations in the ambient air near AMM furnaces were highly elevated, which indicated that AMM retorting is a major source of Hg emission. THg concentrations in the stream water varied from 43 to 2100 ng/L, where the elevated values were mainly found in the vicinity of AMM and mine waste heaps of LSMM. Surface soils were seriously contaminated with Hg, and land using types and organic matter played an important role in accumulation and transportation of Hg in soil. The results indicated heavy Hg contaminations in the study area, which were resulted from both LSMM and AMM. The areas impacted by LSMM were concentrated in the historical mining and smelting facilities, while Hg pollution resulted from AMM can be distributed anywhere in the Hg mining area. Copyright © 2011 Elsevier Ltd. All rights reserved.

  2. Current and future levels of mercury atmospheric pollution on a global scale

    Science.gov (United States)

    Pacyna, Jozef M.; Travnikov, Oleg; De Simone, Francesco; Hedgecock, Ian M.; Sundseth, Kyrre; Pacyna, Elisabeth G.; Steenhuisen, Frits; Pirrone, Nicola; Munthe, John; Kindbom, Karin

    2016-10-01

    An assessment of current and future emissions, air concentrations, and atmospheric deposition of mercury worldwide is presented on the basis of results obtained during the performance of the EU GMOS (Global Mercury Observation System) project. Emission estimates for mercury were prepared with the main goal of applying them in models to assess current (2013) and future (2035) air concentrations and atmospheric deposition of this contaminant. The combustion of fossil fuels (mainly coal) for energy and heat production in power plants and in industrial and residential boilers, as well as artisanal and small-scale gold mining, is one of the major anthropogenic sources of Hg emissions to the atmosphere at present. These sources account for about 37 and 25 % of the total anthropogenic Hg emissions globally, estimated to be about 2000 t. Emissions in Asian countries, particularly in China and India, dominate the total emissions of Hg. The current estimates of mercury emissions from natural processes (primary mercury emissions and re-emissions), including mercury depletion events, were estimated to be 5207 t year-1, which represents nearly 70 % of the global mercury emission budget. Oceans are the most important sources (36 %), followed by biomass burning (9 %). A comparison of the 2035 anthropogenic emissions estimated for three different scenarios with current anthropogenic emissions indicates a reduction of these emissions in 2035 up to 85 % for the best-case scenario. Two global chemical transport models (GLEMOS and ECHMERIT) have been used for the evaluation of future mercury pollution levels considering future emission scenarios. Projections of future changes in mercury deposition on a global scale simulated by these models for three anthropogenic emissions scenarios of 2035 indicate a decrease in up to 50 % deposition in the Northern Hemisphere and up to 35 % in Southern Hemisphere for the best-case scenario. The EU GMOS project has proved to be a very important

  3. Current and future levels of mercury atmospheric pollution on a global scale

    Directory of Open Access Journals (Sweden)

    J. M. Pacyna

    2016-10-01

    Full Text Available An assessment of current and future emissions, air concentrations, and atmospheric deposition of mercury worldwide is presented on the basis of results obtained during the performance of the EU GMOS (Global Mercury Observation System project. Emission estimates for mercury were prepared with the main goal of applying them in models to assess current (2013 and future (2035 air concentrations and atmospheric deposition of this contaminant. The combustion of fossil fuels (mainly coal for energy and heat production in power plants and in industrial and residential boilers, as well as artisanal and small-scale gold mining, is one of the major anthropogenic sources of Hg emissions to the atmosphere at present. These sources account for about 37 and 25 % of the total anthropogenic Hg emissions globally, estimated to be about 2000 t. Emissions in Asian countries, particularly in China and India, dominate the total emissions of Hg. The current estimates of mercury emissions from natural processes (primary mercury emissions and re-emissions, including mercury depletion events, were estimated to be 5207 t year−1, which represents nearly 70 % of the global mercury emission budget. Oceans are the most important sources (36 %, followed by biomass burning (9 %. A comparison of the 2035 anthropogenic emissions estimated for three different scenarios with current anthropogenic emissions indicates a reduction of these emissions in 2035 up to 85 % for the best-case scenario. Two global chemical transport models (GLEMOS and ECHMERIT have been used for the evaluation of future mercury pollution levels considering future emission scenarios. Projections of future changes in mercury deposition on a global scale simulated by these models for three anthropogenic emissions scenarios of 2035 indicate a decrease in up to 50 % deposition in the Northern Hemisphere and up to 35 % in Southern Hemisphere for the best-case scenario. The EU GMOS project has

  4. Continued emissions of carbon tetrachloride from the United States nearly two decades after its phaseout for dispersive uses

    Science.gov (United States)

    Hu, Lei; Montzka, Stephen A.; Miller, Ben R.; Andrews, Arlyn E.; Miller, John B.; Lehman, Scott J.; Sweeney, Colm; Miller, Scot M.; Thoning, Kirk; Siso, Carolina; Atlas, Elliot L.; Blake, Donald R.; de Gouw, Joost; Gilman, Jessica B.; Dutton, Geoff; Elkins, James W.; Hall, Bradley; Chen, Huilin; Fischer, Marc L.; Mountain, Marikate E.; Nehrkorn, Thomas; Biraud, Sebastien C.; Moore, Fred L.; Tans, Pieter

    2016-03-01

    National-scale emissions of carbon tetrachloride (CCl4) are derived based on inverse modeling of atmospheric observations at multiple sites across the United States from the National Oceanic and Atmospheric Administration's flask air sampling network. We estimate an annual average US emission of 4.0 (2.0-6.5) Gg CCl4 y-1 during 2008-2012, which is almost two orders of magnitude larger than reported to the US Environmental Protection Agency (EPA) Toxics Release Inventory (TRI) (mean of 0.06 Gg y-1) but only 8% (3-22%) of global CCl4 emissions during these years. Emissive regions identified by the observations and consistently shown in all inversion results include the Gulf Coast states, the San Francisco Bay Area in California, and the Denver area in Colorado. Both the observation-derived emissions and the US EPA TRI identified Texas and Louisiana as the largest contributors, accounting for one- to two-thirds of the US national total CCl4 emission during 2008-2012. These results are qualitatively consistent with multiple aircraft and ship surveys conducted in earlier years, which suggested significant enhancements in atmospheric mole fractions measured near Houston and surrounding areas. Furthermore, the emission distribution derived for CCl4 throughout the United States is more consistent with the distribution of industrial activities included in the TRI than with the distribution of other potential CCl4 sources such as uncapped landfills or activities related to population density (e.g., use of chlorine-containing bleach).

  5. The Liquid Metallic Hydrogen Model of the Sun and the Solar Atmosphere II. Continuous Emission and Condensed Matter Within the Corona

    Directory of Open Access Journals (Sweden)

    Robitaille P.-M.

    2013-07-01

    Full Text Available The K-corona, a significant portion of the solar atmosphere, displays a continuous spectrum which closely parallels photospheric emission, though without the presence of overlying Fraunhofer lines. The E-corona exists in the same region and is characterized by weak emission lines from highly ionized atoms. For instance, the famous green emission line from coronium (FeXIV is part of the E-corona. The F-corona exists beyond the K/E-corona and, like the photospheric spectrum, is characterized by Fraunhofer lines. The F-corona represents photospheric light scattered by dust particles in the interplanetary medium. Within the gaseous models of the Sun, the K-corona is viewed as photospheric radiation which has been scattered by relativistic electrons. This scattering is thought to broaden the Fraunhofer lines of the solar spectrum such that they can no longer be detected in the K-corona. Thus, the gaseous models of the Sun account for the appearance of the K-corona by distorting photospheric light, since they are unable to have recourse to condensed matter to directly produce such radiation. Conversely, it is now advanced that the continuous emission of the K-corona and associated emission lines from the E-corona must be interpreted as manifestations of the same phenomenon: condensed matter exists in the corona. It is well-known that the Sun expels large amounts of material from its surface in the form of flares and coronal mass ejections. Given a liquid metallic hydrogen model of the Sun, it is logical to assume that such matter, which exists in the condensed state on the solar surface, continues to manifest its nature once expelled into the corona. Therefore, the continuous spectrum of the K-corona provides the twenty-seventh line of evidence that the Sun is composed of condensed matter.

  6. A global ocean inventory of anthropogenic mercury based on water column measurements

    NARCIS (Netherlands)

    Lamborg, C.H.; Hammerschmidt, C.R.; Bowman, K.L.; Swarr, G.J.; Munson, K.M.; Ohnemus, D.C.; Lam, P.L.; Heimbürger, L.-E.; Rijkenberg, M.J.A.; Saito, M.A.

    2014-01-01

    Mercury is a toxic, bioaccumulating trace metal whose emissions to the environment have increased significantly as a result of anthropogenic activities such as mining and fossil fuel combustion. Several recent models have estimated that these emissions have increased the oceanic mercury inventory by

  7. Improving appropriate use of echocardiography and single-photon emission computed tomographic myocardial perfusion imaging: a continuous quality improvement initiative.

    Science.gov (United States)

    Johnson, Thomas V; Rose, Geoffrey A; Fenner, Deborah J; Rozario, Nigel L

    2014-07-01

    Appropriate use criteria for cardiovascular imaging have been published, but compliance in practice has been incomplete, with persistent high rates of inappropriate use. The aim of this study was to show the efficacy of a continuous quality improvement (CQI) initiative to favorably influence the appropriate use of outpatient transthoracic echocardiography and single-photon emission computed tomographic (SPECT) myocardial perfusion imaging (MPI) in a large cardiovascular practice. In this prospective study, a multiphase CQI initiative was implemented, and its impact on ordering patterns for outpatient transthoracic echocardiography and SPECT MPI was assessed. Between November and December 2010, a baseline analysis of the application of appropriate use criteria to indications for outpatient transthoracic echocardiographic studies (n = 203) and SPECT MPI studies (n = 205) was performed, with studies categorized as "appropriate," "inappropriate," "uncertain," or "unclassified." The CQI initiative was then begun, with (1) clinician education, including didactic lectures and case-based presentations with audience participation; (2) system changes in ordering processes, with redesigned image ordering forms; and (3) peer review and feedback. A follow-up analysis was then performed between June and August 2012, with categorization of indications for transthoracic echocardiographic studies (n = 206) and SPECT MPI studies (n = 206). At baseline, 73.9% of echocardiographic studies were categorized as appropriate, 16.7% as inappropriate, 5.9% as uncertain, and 3.4% as unclassified. Similarly, for SPECT MPI studies 71.7% were categorized as appropriate, 18.5% as inappropriate, 7.8% as uncertain, and 1.9% as unclassified. Separate analysis of the two most important categories, appropriate and inappropriate, demonstrated a significant improvement after the CQI initiative, with a 63% reduction in inappropriate echocardiographic studies (18.5% vs 6.9%, P = .0010) and a 46% reduction

  8. Historical anthropogenic mercury in two lakes of Central Chile: comparison between an urban and rural lake.

    Science.gov (United States)

    Álvarez, Denisse; Torrejón, Fernando; Climent, María José; Garcia-Orellana, Jordi; Araneda, Alberto; Urrutia, Roberto

    2018-02-01

    Mercury concentrations in the environment tend to decrease in recent years due to environmental restrictions. Lakes store mercury in their sediments, making them potential secondary contamination sources. In South America, the occurrence of mercury in lake systems has been associated mainly with volcanic emissions and only few records anthropogenic contamination in the pre-Hispanic period. The objective of this research was to study historical anthropogenic mercury concentration in two lakes in Central Chile (La Señoraza and Pillo), in order to establish background mercury levels and their variations from preindustrial to modern periods. Different background levels and mercury concentrations were found in each lake, with significantly higher concentrations in Lake La Señoraza during the last 150 years. Mining-related activities during the nineteenth century could have a negligible influence on mercury concentrations. Later on, the use of coal railroads and subsequent employment of mercury in the cellulose industry were associated with three- and fourfold increases in mercury concentration over the nineteenth century background levels, which decrease once these activities ceased. However, in the case of Lake Pillo, an important increase in mercury concentration can be observed between 1990 and the early twenty-first century, which could be related to a higher watershed/lake area ratio, extensive agriculture, and volcanic emission, being the latter that could have contributed with mercury to both systems. Nevertheless, sedimentological characteristics in Lake Pillo can be favorable to retain mercury in this aquatic system up to the present day.

  9. A high-resolution regional emission inventory of atmospheric mercury and its comparison with multi-scale inventories: a case study of Jiangsu, China

    Directory of Open Access Journals (Sweden)

    H. Zhong

    2016-12-01

    Full Text Available A better understanding of the discrepancies in multi-scale inventories could give an insight into their approaches and limitations as well as provide indications for further improvements; international, national, and plant-by-plant data are primarily obtained to compile those inventories. In this study we develop a high-resolution inventory of Hg emissions at 0.05°  ×  0.05° for Jiangsu, China, using a bottom-up approach and then compare the results with available global/national inventories. With detailed information on individual sources and the updated emission factors from field measurements applied, the annual Hg emissions of anthropogenic origin in Jiangsu in 2010 are estimated at 39 105 kg, of which 51, 47, and 2 % were Hg0, Hg2+, and Hgp, respectively. This provincial inventory is thoroughly compared to three downscaled national inventories (NJU, THU, and BNU and two global ones (AMAP/UNEP and EDGARv4.tox2. Attributed to varied methods and data sources, clear information gaps exist in multi-scale inventories, leading to differences in the emission levels, speciation, and spatial distributions of atmospheric Hg. The total emissions in the provincial inventory are 28, 7, 19, 22, and 70 % larger than NJU, THU, BNU, AMAP/UNEP, and EDGARv4.tox2, respectively. For major sectors, including power generation, cement, iron and steel, and other coal combustion, the Hg contents (HgC in coals/raw materials, abatement rates of air pollution control devices (APCDs and activity levels are identified as the crucial parameters responsible for the differences in estimated emissions between inventories. Regarding speciated emissions, a larger fraction of Hg2+ is found in the provincial inventory than national and global inventories, resulting mainly from the results by the most recent domestic studies in which enhanced Hg2+ were measured for cement and iron and steel plants. Inconsistent information on large power and industrial plants is

  10. 21 CFR 872.3070 - Dental amalgam, mercury, and amalgam alloy.

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 8 2010-04-01 2010-04-01 false Dental amalgam, mercury, and amalgam alloy. 872... SERVICES (CONTINUED) MEDICAL DEVICES DENTAL DEVICES Prosthetic Devices § 872.3070 Dental amalgam, mercury... elemental mercury, supplied as a liquid in bulk, sachet, or predosed capsule form, and amalgam alloy...

  11. 40 CFR 440.40 - Applicability; description of the mercury ore subcategory.

    Science.gov (United States)

    2010-07-01

    ... mercury ore subcategory. 440.40 Section 440.40 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS ORE MINING AND DRESSING POINT SOURCE CATEGORY Mercury Ore Subcategory § 440.40 Applicability; description of the mercury ore subcategory. The provisions of subpart D...

  12. Continued emissions of carbon tetrachloride from the United States nearly two decades after its phaseout for dispersive uses

    Science.gov (United States)

    Hu, Lei; Montzka, Stephen A.; Miller, Ben R.; Andrews, Arlyn E.; Miller, John B.; Lehman, Scott J.; Sweeney, Colm; Miller, Scot M.; Thoning, Kirk; Siso, Carolina; Atlas, Elliot L.; Blake, Donald R.; de Gouw, Joost; Gilman, Jessica B.; Dutton, Geoff; Elkins, James W.; Hall, Bradley; Chen, Huilin; Fischer, Marc L.; Mountain, Marikate E.; Nehrkorn, Thomas; Biraud, Sebastien C.; Moore, Fred L.; Tans, Pieter

    2016-01-01

    National-scale emissions of carbon tetrachloride (CCl4) are derived based on inverse modeling of atmospheric observations at multiple sites across the United States from the National Oceanic and Atmospheric Administration’s flask air sampling network. We estimate an annual average US emission of 4.0 (2.0–6.5) Gg CCl4 y−1 during 2008–2012, which is almost two orders of magnitude larger than reported to the US Environmental Protection Agency (EPA) Toxics Release Inventory (TRI) (mean of 0.06 Gg y−1) but only 8% (3–22%) of global CCl4 emissions during these years. Emissive regions identified by the observations and consistently shown in all inversion results include the Gulf Coast states, the San Francisco Bay Area in California, and the Denver area in Colorado. Both the observation-derived emissions and the US EPA TRI identified Texas and Louisiana as the largest contributors, accounting for one- to two-thirds of the US national total CCl4 emission during 2008–2012. These results are qualitatively consistent with multiple aircraft and ship surveys conducted in earlier years, which suggested significant enhancements in atmospheric mole fractions measured near Houston and surrounding areas. Furthermore, the emission distribution derived for CCl4 throughout the United States is more consistent with the distribution of industrial activities included in the TRI than with the distribution of other potential CCl4 sources such as uncapped landfills or activities related to population density (e.g., use of chlorine-containing bleach). PMID:26929368

  13. Evaluation of mercury speciation by EPA (Draft) Method 29

    Energy Technology Data Exchange (ETDEWEB)

    Laudal, D.L.; Heidt, M.K. [Energy & Environmental Research Center, Grand Forks, ND (United States); Nott, B. [Electric Power Research Institute, Palo Alto, CA (United States)

    1995-11-01

    The 1990 Clean Air Act Amendments require that the U.S. Environmental protection Agency (EPA) assess the health risks associated with mercury emissions. Also, the law requires a separate assessment of health risks posed by the emission of 189 tract chemicals (including mercury) for electric utility steam-generating units. In order to conduct a meaningful assessment of health and environmental effects, we must have, among other things, a reliable and accurate method to measure mercury emissions. In addition, the rate of mercury deposition and the type of control strategies used may depend upon the type of mercury emitted (i.e., whether it is in the oxidized or elemental form). It has been speculated that EPA (Draft) Method 29 can speciate mercury by selective absorption; however, this claim has yet to be proven. The Electric Power Research Institute (EPRI) and the U.S. Department of Energy (DOE) have contracted with the Energy & Environmental Research Center (EERC) at University of North Dakota to evaluate EPA (Draft) Method 29 at the pilot-scale level. The objective of the work is to determine whether EPA (Draft) Method 29 can reliably quantify and speciate mercury in the flue gas from coal-fired boilers.

  14. A regional high resolution model of the marine mercury cycle.

    Science.gov (United States)

    Bieser, J.; Daewel, U.; Schrum, C.

    2017-12-01

    One of the main sources for mercury intoxication is the uptake of methylmercury from sea food. However, only little is known about the dynamics of methylmercury in the marine environment and its accumulation along the food chain. To further our understanding of the pathways from anthropogenic emissions of elemental mercury to the bio-accumulation of methylmercury in fish we developed the first regional Eulerian three dimensional multi-media chemistry transport model (MECOSMO) that includes atmosphere, ocean, and ecosystem. The marine part of the model includes a complete representation of the marine ecosystem ranging from phytoplankton up to higher trophic levels, including fish. We used the MECOSMO model to reconstruct mercury concentrations in water and biota in the North- and Baltic Sea for the past 60 years. Based on our model we examined the natural short and longterm variability of the system as well as long term trends in the distribution and amount of methylmercury in water and fish. Based on our findings we show how models can be utilized to develop future measurement strategies for marine mercury. Finally, the presented modelling system can be used to project the impact of future perturbations in the system (i.e.: emission reductions, climate change, nutrient control) on the mercury accumulation in sea food. Thereby, supporting the implementation of the Minamata Convention on Mercury on a regional scale by enabling us to estimate the impact of emission reductions on the marine mercury cycle.

  15. Analysis of gas-phase mercury sorption with coke and lignite dust

    Directory of Open Access Journals (Sweden)

    Marczak Marta

    2017-01-01

    Full Text Available In recent years the problem of mercury emission became a widely discussed topic. Its high impact is caused by its toxicity and ability to accumulate in living organisms, properties that justified the United States Environmental Protection Agency (US EPA to classify mercury as hazardous pollutant. The problem of mercury emission is crucial for countries like Poland, where the most of the emission is caused by coaldepended energy sector. Current technology of mercury removal utilizes adsorption of mercury on the surface of activated carbon. Due to high price of activated carbon, this technological approach seems to be uneconomical and calls for cheaper alternative. One possible solution can be usage of other sorptive materials obtained from thermal processes like coke production. Example of such material is coke dust obtained from dry quenching of coke. The aim of this work was to analyse the sorption potential of lignite and coke dust and determine parameters influencing mercury behaviour during combustion.

  16. Mercury evaporation from amalgams with varied mercury contents.

    Science.gov (United States)

    Ohmoto, K; Nakajima, H; Ferracane, J L; Shintani, H; Okabe, T

    2000-09-01

    This study examined the relationship between mercury content and mercury evaporation from amalgams during setting. Two different types of commercial high-copper amalgams (single composition and admixed types) were used. Cylindrical specimens of each amalgam were prepared with five different mercury contents according to ADA Specification No.1. Specimens were also prepared by hand condensation. Mercury evaporation from amalgam specimens maintained at 37 degrees C was measured using a gold film mercury analyzer from 10 min after the end of trituration until the mercury concentration in air reached an undetectable level. The mercury content more clearly influenced the mercury evaporation from the admixed type amalgam specimens when the mercury content decreased below the manufacturers' recommended trituration conditions. Triturating with less mercury than the manufacturers' recommended amount cannot lower the evaporation of mercury from freshly made amalgam. Proper condensing procedures can minimize the mercury evaporation from the amalgam surface.

  17. Monitoring of mercury concentration in atmosphere in Usti nad Labem

    International Nuclear Information System (INIS)

    Synek, V.; Baloch, T.; Otcenasek, J.; Kremlova, S.; Subrt, P.

    2007-01-01

    This study elaborates the observation of mercury pollution of the atmosphere in the city of Usti nad Labem. The biggest source of the polluting mercury in Usti nad Labem is the chlor-alkali production in the factory of Spolchemie Inc. The method of mercury determination applied is based on capturing the mercury contented in a volume of the air on an amalgamator and measuring the mercury by an atomic absorption spectrometer (Perkin -Elmer 4100ZL) equipped with a special adapter after a thermal release of the mercury from the amalgamator. The basic characteristics of this method were evaluated; e.g. the limit of detection and limit of determination are, respectively, 0.43 and 1.4 ng/m 3 , the relative expanded uncertainty is 28 %. The work gives results of long-term (1998-2006) observations in a few localities in Usti nad Labem situated in various distances from the mercury source (e.g. means of 28.6 and 14.1 ng/m3 were obtained, respectively, in places 350 and 700 m far from the electrolysis plant) and also in a different city (Duchcov). The cases with a higher mercury concentration are very frequent so the sets of the obtained results have lognormal distributions. This study statistically compares the total level and variability of the mercury concentrations in the time series. It also investigates their trends, correlations between them and meteorological influences upon the levels of mercury concentration in the air. The effect of the mercury emission from the chlor-alkali plant is dominant. It as the only factor determines when the cases with a high mercury concentration in the atmosphere occur. (author)

  18. Metals analysis for emission spectroscopic in the incandescent discharge operated with continuous flow of He to atmospheric pressure

    International Nuclear Information System (INIS)

    Alzate Londono, Hugo

    1990-01-01

    By means of a small power source a glow discharge in generated with he flowing at atmospheric pressure. Into a device situated to some distance from the discharge an aqueous sample of a metallic ion is injected. The device is then gradually moved to the discharge for producing solvent vaporization, charring, atomization, excitation and finally atomic emission of the sample. By emission spectrophotometer the following elements were analyzed: Ag, Cd, Cr, Cu, Hg, K, Na, Pb and Zn. For every one the useful range and the detection limit were established after founding the best operation conditions for the discharge

  19. The Liquid Metallic Hydrogen Model of the Sun and the Solar Atmosphere I. Continuous Emission and Condensed Matter Within the Chromosphere

    Directory of Open Access Journals (Sweden)

    Robitaille P.-M.

    2013-07-01

    Full Text Available The continuous spectrum of the solar photosphere stands as the paramount observation with regard to the condensed nature of the solar body. Studies relative to Kirchhoff’s law of thermal emission (e.g. Robitaille P.-M. Kirchhoff’s law of thermal emission: 150 years. Progr. Phys., 2009, v. 4, 3–13. and a detailed analysis of the stellar opacity problem (Robitaille P.M. Stellar opacity: The Achilles’ heel of the gaseous Sun. Progr. Phys., 2011, v. 3, 93–99 have revealed that gaseous models remain unable to properly account for the generation of this spectrum. Therefore, it can be stated with certainty that the photosphere is comprised of condensed matter. Beyond the solar surface, the chromospheric layer of the Sun also generates a weak continuous spectrum in the visible region. This emission exposes the presence of material in the condensed state. As a result, above the level of the photosphere, matter exists in both gaseous and condensed forms, much like within the atmosphere of the Earth. The continuous visible spectrum associated with the chromosphere provides the twenty-sixth line of evidence that the Sun is condensed matter.

  20. Absolute cross sections for emission of 284.7-nm (Hg II) and 479.7-nm (Hg III) radiation in electron--mercury-ion collisions

    International Nuclear Information System (INIS)

    Phaneuf, R.A.; Taylor, P.O.; Dunn, G.H.

    1976-01-01

    Crossed beams of electrons and Hg + ions have been used to measure absolute cross sections for emission of 284.7-nm radiation, resulting from excitation of a predominantly ground-state Hg + target to the 7s 2 S 1 / 2 state. Values range from 3 x 10 -17 cm 2 near threshold, where the cross section is strongly peaked, to 1.3 x 10 -18 cm 2 at 280 eV. Also reported are some measurements of emission of 479.7-nm (Hg III) radiation, resulting from electron impact on both Hg + and Hg ++ targets. Cross sections range from approximately 5 x 10 -19 to 5 x 10 -20 cm 2 , and in the case of electron-Hg ++ collisions, are more than an order of magnitude smaller than predicted by an available semiclassical binary-encounter calculation

  1. Process for low mercury coal

    Science.gov (United States)

    Merriam, Norman W.; Grimes, R. William; Tweed, Robert E.

    1995-01-01

    A process for producing low mercury coal during precombustion procedures by releasing mercury through discriminating mild heating that minimizes other burdensome constituents. Said mercury is recovered from the overhead gases by selective removal.

  2. Continuous-wave infrared optical gain and amplified spontaneous emission at ultralow threshold by colloidal HgTe quantum dots

    NARCIS (Netherlands)

    Geiregat, Pieter; Houtepen, Arjan J.; Sagar, Laxmi Kishore; Infante, Ivan; Zapata, Felipe; Grigel, Valeriia; Allan, Guy; Delerue, Christophe; Van Thourhout, Dries; Hens, Zeger

    2017-01-01

    Colloidal quantum dots (QDs) raise more and more interest as solution-processable and tunable optical gain materials. However, especially for infrared active QDs, optical gain remains inefficient. Since stimulated emission involves multifold degenerate band-edge states, population inversion can be

  3. 40 CFR 63.5890 - How do I calculate an organic HAP emissions factor to demonstrate compliance for continuous...

    Science.gov (United States)

    2010-07-01

    ... for Hazardous Air Pollutants: Reinforced Plastic Composites Production Testing and Initial Compliance... per year Oc=controlled oven organic HAP emissions, lbs per year R=total usage of neat resin plus, tpy G=total usage of neat gel coat plus, tpy (b) Averaging option. Use Equation 2 of this section to...

  4. 40 CFR Table 6 to Subpart Uuu of... - Continuous Compliance With Metal HAP Emission Limits for Catalytic Cracking Units

    Science.gov (United States)

    2010-07-01

    ... Petroleum Refineries: Catalytic Cracking Units, Catalytic Reforming Units, and Sulfur Recovery Units Pt. 63... Emission Limits for Catalytic Cracking Units 6 Table 6 to Subpart UUU of Part 63 Protection of Environment... Limits for Catalytic Cracking Units As stated in § 63.1564(c)(1), you shall meet each requirement in the...

  5. An automated SO2 camera system for continuous, real-time monitoring of gas emissions from Kīlauea Volcano's summit Overlook Crater

    Science.gov (United States)

    Kern, Christoph; Sutton, Jeff; Elias, Tamar; Lee, Robert Lopaka; Kamibayashi, Kevan P.; Antolik, Loren; Werner, Cynthia A.

    2015-01-01

    SO2 camera systems allow rapid two-dimensional imaging of sulfur dioxide (SO2) emitted from volcanic vents. Here, we describe the development of an SO2 camera system specifically designed for semi-permanent field installation and continuous use. The integration of innovative but largely “off-the-shelf” components allowed us to assemble a robust and highly customizable instrument capable of continuous, long-term deployment at Kīlauea Volcano's summit Overlook Crater. Recorded imagery is telemetered to the USGS Hawaiian Volcano Observatory (HVO) where a novel automatic retrieval algorithm derives SO2 column densities and emission rates in real-time. Imagery and corresponding emission rates displayed in the HVO operations center and on the internal observatory website provide HVO staff with useful information for assessing the volcano's current activity. The ever-growing archive of continuous imagery and high-resolution emission rates in combination with continuous data from other monitoring techniques provides insight into shallow volcanic processes occurring at the Overlook Crater. An exemplary dataset from September 2013 is discussed in which a variation in the efficiency of shallow circulation and convection, the processes that transport volatile-rich magma to the surface of the summit lava lake, appears to have caused two distinctly different phases of lake activity and degassing. This first successful deployment of an SO2 camera for continuous, real-time volcano monitoring shows how this versatile technique might soon be adapted and applied to monitor SO2 degassing at other volcanoes around the world.

  6. Evaluation of Sorbent Injection for Mercury Control

    Energy Technology Data Exchange (ETDEWEB)

    Sharon Sjostrom

    2006-04-30

    The power industry in the U.S. is faced with meeting new regulations to reduce the emissions of mercury compounds from coal-fired plants. These regulations are directed at the existing fleet of nearly 1,100 boilers. These plants are relatively old with an average age of over 40 years. Although most of these units are capable of operating for many additional years, there is a desire to minimize large capital expenditures because of the reduced (and unknown) remaining life of the plant to amortize the project. Injecting a sorbent such as powdered activated carbon into the flue gas represents one of the simplest and most mature approaches to controlling mercury emissions from coal-fired boilers. This is the final site report for tests conducted at DTE Energy's Monroe Power Plant, one of five sites evaluated in this DOE/NETL program. The overall objective of the test program was to evaluate the capabilities of activated carbon injection at five plants: Sunflower Electric's Holcomb Station Unit 1, AmerenUE's Meramec Station Unit 2, Missouri Basin Power Project's Laramie River Station Unit 3, Detroit Edison's Monroe Power Plant Unit 4, and AEP's Conesville Station Unit 6. These plants have configurations that together represent 78% of the existing coal-fired generation plants. The goals for the program established by DOE/NETL were to reduce the uncontrolled mercury emissions by 50 to 70% at a cost 25 to 50% lower than the target established by DOE of $60,000/lb mercury removed. The results from Monroe indicate that using DARCO{reg_sign} Hg would result in higher mercury removal (80%) at a sorbent cost of $18,000/lb mercury, or 70% lower than the benchmark. These results demonstrate that the goals established by DOE/NETL were exceeded during this test program. The increase in mercury removal over baseline conditions is defined for this program as a comparison in the outlet emissions measured using the Ontario Hydro method during the baseline

  7. Full-Scale Testing of a Mercury Oxidation Catalyst Upstream of a Wet FGD System

    Energy Technology Data Exchange (ETDEWEB)

    Gary Blythe; Jennifer Paradis

    2010-06-30

    This document presents and discusses results from Cooperative Agreement DE-FC26-06NT42778, 'Full-scale Testing of a Mercury Oxidation Catalyst Upstream of a Wet FGD System,' which was conducted over the time-period July 24, 2006 through June 30, 2010. The objective of the project was to demonstrate at full scale the use of solid honeycomb catalysts to promote the oxidation of elemental mercury in pulverized-coal-fired flue gas. Oxidized mercury is removed downstream in wet flue gas desulfurization (FGD) absorbers and collected with the byproducts from the FGD system. The project was co-funded by EPRI, the Lower Colorado River Authority (LCRA), who also provided the host site, Great River Energy, Johnson Matthey, Southern Company, Salt River Project (SRP), the Tennessee Valley Authority (TVA), NRG Energy, Ontario Power and Westar. URS Group was the prime contractor and also provided cofunding. The scope of this project included installing and testing a gold-based catalyst upstream of one full-scale wet FGD absorber module (about 200-MW scale) at LCRA's Fayette Power Project (FPP) Unit 3, which fires Powder River Basin coal. Installation of the catalyst involved modifying the ductwork upstream of one of three wet FGD absorbers on Unit 3, Absorber C. The FGD system uses limestone reagent, operates with forced sulfite oxidation, and normally runs with two FGD modules in service and one spare. The full-scale catalyst test was planned for 24 months to provide catalyst life data. Over the test period, data were collected on catalyst pressure drop, elemental mercury oxidation across the catalyst module, and mercury capture by the downstream wet FGD absorber. The demonstration period began on May 6, 2008 with plans for the catalyst to remain in service until May 5, 2010. However, because of continual increases in pressure drop across the catalyst and concerns that further increases would adversely affect Unit 3 operations, LCRA decided to end the

  8. Mercury exposure in young children living in New York City.

    Science.gov (United States)

    Rogers, Helen S; Jeffery, Nancy; Kieszak, Stephanie; Fritz, Pat; Spliethoff, Henry; Palmer, Christopher D; Parsons, Patrick J; Kass, Daniel E; Caldwell, Kathy; Eadon, George; Rubin, Carol

    2008-01-01

    evidence of significant mercury use or exposure among participating children. Because some participants were aware of the possibility that they could acquire and use mercury for cultural or ritualistic purposes, community education about the health hazards of mercury should continue.

  9. Sedimentary mercury (Hg) in the marginal seas adjacent to Chinese high-Hg emissions: Source-to-sink, mass inventory, and accumulation history.

    Science.gov (United States)

    Kim, Jihun; Lim, Dhongil; Jung, Dohyun; Kang, Jeongwon; Jung, Hoisoo; Woo, Hanjun; Jeong, Kapsik; Xu, Zhaokai

    2018-03-01

    We comprehensively investigated sedimentary Hg in Yellow and East China Seas (YECSs), which constitute potentially important depocenters for large anthropogenic Hg emissions from mainland China. A large dataset of Al-TOC-Hg concentrations led to an in-depth understanding of sedimentary Hg in the entire YECSs, including distribution and its determinants, source-to-sink, background levels, inventory in flux and budget, and accumulation history. Especially, the net atmospheric Hg flux to the sediments was estimated to be 1.3 × 10 -5  g/m 2 /yr, which corresponded reasonably well to that calculated using a box model. About 21.2 tons of atmospheric Hg (approximately 4% of the total anthropogenic atmospheric Hg emissions from China) were buried annually in the YECS basin. This result implies that most of atmospheric Hg from China is transferred to the surface of the Pacific (including the East/Japan Sea and South China Sea) by the westerlies and, consequently, can play a critical role in open-sea aquatic ecosystems. Copyright © 2018 Elsevier Ltd. All rights reserved.

  10. Mercury in terrestrial forested systems with highly elevated mercury deposition in southwestern China: The risk to insects and potential release from wildfires.

    Science.gov (United States)

    Zhou, Jun; Wang, Zhangwei; Sun, Ting; Zhang, Huan; Zhang, Xiaoshan

    2016-05-01

    Forests are considered a pool of mercury in the global mercury cycle. However, few studies have investigated the distribution of mercury in the forested systems in China. Tieshanping forest catchment in southwest China was impacted by mercury emissions from industrial activities and coal combustions. Our work studied mercury content in atmosphere, soil, vegetation and insect with a view to estimating the potential for mercury release during forest fires. Results of the present study showed that total gaseous mercury (TGM) was highly elevated and the annual mean concentration was 3.51 ± 1.39 ng m(-2). Of the vegetation tissues, the mercury concentration follows the order of leaf/needle > root > bark > branch > bole wood for each species. Total ecosystem mercury pool was 103.5 mg m(-2) and about 99.4% of the mercury resides in soil layers (0-40 cm). The remaining 0.6% (0.50 mg m(-2)) of mercury was stored in biomass. The large mercury stocks in the forest ecosystem pose a serious threat for large pluses to the atmospheric mercury during potential wildfires and additional ecological stress to forest insect: dung beetles, cicada and longicorn, with mercury concentration of 1983 ± 446, 49 ± 38 and 7 ± 5 ng g(-1), respectively. Hence, the results obtained in the present study has implications for global estimates of mercury storage in forests, risks to forest insect and potential release to the atmosphere during wildfires. Copyright © 2016 Elsevier Ltd. All rights reserved.

  11. Mercury from combustion sources: a review of the chemical species emitted and their transport in the atmosphere

    International Nuclear Information System (INIS)

    Carpi, A.

    1997-01-01

    Different species of mercury have different physical/chemical properties and thus behave quite differentially in air pollution control equipment and in the atmosphere. In general, emission of mercury from coal combustion sources are approximately 20-50% elemental mercury (Hg 0 ) and 50-80% divalent mercury (Hg(II)), which may be predominantly HgCl 2 . Emissions of mercury from waste incinerators are approximately 10-20% Hg 0 and 75-85% Hg(II). The partitioning of mercury in flue gas between the elemental and divalent forms may be dependent on the concentration of particulate carbon, HCl and other pollutants in the stack emissions. The emission of mercury from combustion facilities depends on the species in the exhaust stream and the type of air pollution control equipment used at the source. Air pollution control equipment for mercury removal at combustion facilities includes activated carbon injection, sodium sulfide injection and wet lime/limestone flue gas desulfurization. White Hg(II) is water-soluble and may be removed form the atmosphere by wet and dry deposition close to the combustion sources, the combination of a high vapor pressure and low water-solubility facilitate the long-range transport of Hg 0 in the atmosphere. Background mercury in the atmosphere is predominantly Hg 0 . Elemental mercury is eventually removed from the atmosphere by dry deposition onto surfaces and by wet deposition after oxidation to water-soluble, divalent mercury. 62 refs., 2 figs., 1 tab

  12. Performance testing of a Laser-Induced Breakdown Spectroscopy (LIBS) based continuous metal emissions monitor at a pyrolytic waste treatment facility

    Energy Technology Data Exchange (ETDEWEB)

    Hahn, D.W.; Hencken, K.R.; Johnsen, H.A.

    1997-07-01

    A program was initiated at Sandia National Laboratories to develop and demonstrate an advanced continuous emissions monitor that will provide realtime measurement of metal emissions in the wastestreams of thermal treatment facilities. This effort led to the development of a prototype metals monitor based on an optical technique referred to as laser-induced breakdown spectroscopy (LIBS). The measurements are performed in situ, and are both noninvasive and real-time. The automated software incorporates a new conditional analysis algorithm that utilizes single particle detection. The metal emissions monitor was tested during March 1997 at a pilot scale pyrolytic waste processing facility in Santa Fe Springs, California. This report describes the field test, including the monitor installation, test cycle, and overall instrument performance. The Clean Air Act metals chromium and manganese were recorded at concentrations from approximately 2 to 5 parts per billion. Iron was recorded at concentrations from 40 to 140 parts per billion. The overall accuracy was in very good agreement with contracted EPA Reference Method 29 results. Overall, the LIBS-based metals monitor performed exceptionally well on a waste treatment facility with very low metal emissions levels. 19 refs., 12 tabs., 3 figs.

  13. Mercury in terrestrial forested systems with highly elevated mercury deposition in southwestern China: The risk to insects and potential release from wildfires

    International Nuclear Information System (INIS)

    Zhou, Jun; Wang, Zhangwei; Sun, Ting; Zhang, Huan; Zhang, Xiaoshan

    2016-01-01

    Forests are considered a pool of mercury in the global mercury cycle. However, few studies have investigated the distribution of mercury in the forested systems in China. Tieshanping forest catchment in southwest China was impacted by mercury emissions from industrial activities and coal combustions. Our work studied mercury content in atmosphere, soil, vegetation and insect with a view to estimating the potential for mercury release during forest fires. Results of the present study showed that total gaseous mercury (TGM) was highly elevated and the annual mean concentration was 3.51 ± 1.39 ng m −2 . Of the vegetation tissues, the mercury concentration follows the order of leaf/needle > root > bark > branch > bole wood for each species. Total ecosystem mercury pool was 103.5 mg m −2 and about 99.4% of the mercury resides in soil layers (0–40 cm). The remaining 0.6% (0.50 mg m −2 ) of mercury was stored in biomass. The large mercury stocks in the forest ecosystem pose a serious threat for large pluses to the atmospheric mercury during potential wildfires and additional ecological stress to forest insect: dung beetles, cicada and longicorn, with mercury concentration of 1983 ± 446, 49 ± 38 and 7 ± 5 ng g −1 , respectively. Hence, the results obtained in the present study has implications for global estimates of mercury storage in forests, risks to forest insect and potential release to the atmosphere during wildfires. - Highlights: • Mercury in air, soil, biomass and insect were studied at a subtropical forest. • 99.4% of the total ecosystem mercury pools was resided in soil layers. • High mercury pools were large pulses to the atmosphere during potential wildfires. • High mercury deposition in forest pose an ecological stress to insect. - Large mercury pools in forest pose a serious threat for large pluses to the atmospheric mercury during potential wildfires and ecological stress to insect.

  14. Mercury use in small scale gold mining in Ghana: an assessment of its impact on miners

    International Nuclear Information System (INIS)

    Biagya, Robert Yakubu

    2002-12-01

    Small scale gold mining is responsible for about 5% of Ghana’s annual gold production. It is estimated that between 80,000 and 100,000 people are engaged in small scale gold mining either on part-time or permanent basis. Amalgamation is the preferred method used by small scale gold miners for extracting free gold from its ores. The rate at which mercury, an important input in this method, is discharged into the atmosphere and water bodies is alarming. This research describes the various mining and processing methods in small scale gold mining and the extent of mercury use and releases to the environment. It discusses mercury and its human and environmental effects. It defines the various forms of mercury, routes of exposure, toxic effects. The levels of exposure to mercury by all groups of small scale gold miners are determined, and the impacts on the miners and the environment are assessed. It concludes that: • Mercury is mainly released into the environment as a result of small scale gold mining through spillage of elemental mercury and evaporation of mercury from the amalgam and sponge gold when they are heated on open fire. • Mercury in environmental samples from small scale gold mining areas is well above standard limit values. • Mercury released into the environment through small scale gold mining impacts negatively on the miners themselves and the general environment. Finally, it recommends the need for the adoption of mercury emission reduction strategies for dealing with the mercury problem. (au)

  15. Modeling Mercury in Proteins

    Energy Technology Data Exchange (ETDEWEB)

    Smith, Jeremy C [ORNL; Parks, Jerry M [ORNL

    2016-01-01

    Mercury (Hg) is a naturally occurring element that is released into the biosphere both by natural processes and anthropogenic activities. Although its reduced, elemental form Hg(0) is relatively non-toxic, other forms such as Hg2+ and, in particular, its methylated form, methylmercury, are toxic, with deleterious effects on both ecosystems and humans. Microorganisms play important roles in the transformation of mercury in the environment. Inorganic Hg2+ can be methylated by certain bacteria and archaea to form methylmercury. Conversely, bacteria also demethylate methylmercury and reduce Hg2+ to relatively inert Hg(0). Transformations and toxicity occur as a result of mercury interacting with various proteins. Clearly, then, understanding the toxic effects of mercury and its cycling in the environment requires characterization of these interactions. Computational approaches are ideally suited to studies of mercury in proteins because they can provide a detailed picture and circumvent issues associated with toxicity. Here we describe computational methods for investigating and characterizing how mercury binds to proteins, how inter- and intra-protein transfer of mercury is orchestrated in biological systems, and how chemical reactions in proteins transform the metal. We describe quantum chemical analyses of aqueous Hg(II), which reveal critical factors that determine ligand binding propensities. We then provide a perspective on how we used chemical reasoning to discover how microorganisms methylate mercury. We also highlight our combined computational and experimental studies of the proteins and enzymes of the mer operon, a suite of genes that confers mercury resistance in many bacteria. Lastly, we place work on mercury in proteins in the context of what is needed for a comprehensive multi-scale model of environmental mercury cycling.

  16. Database for content of mercury in Polish brown coal

    Science.gov (United States)

    Jastrząb, Krzysztof

    2018-01-01

    Poland is rated among the countries with largest level of mercury emission in Europe. According to information provided by the National Centre for Balancing and Management of Emissions (KOBiZE) more than 10.5 tons of mercury and its compounds were emitted into the atmosphere in 2015 from the area of Poland. Within the scope of the BazaHg project lasting from 2014 to 2015 and co-financed from the National Centre of Research and Development (NCBiR) a database was set up with specification of mercury content in Polish hard steam coal, coking coal and brown coal (lignite) grades. With regard to domestic brown coal the database comprises information on coal grades from Brown Coal Mines of `Bełchatów', `Adamów', `Turów' and `Sieniawa'. Currently the database contains 130 records with parameters of brown coal, where each record stands for technical analysis (content of moisture, ash and volatile particles), elemental analysis (CHNS), content of chlorine and mercury as well as net calorific value and combustion heat. Content of mercury in samples of brown coal grades under test ranged from 44 to 985 μg of Hg/kg with the average level of 345 μg of Hg/kg. The established database makes up a reliable and trustworthy source of information about content of mercury in Polish fossils. The foregoing details completed with information about consumption of coal by individual electric power stations and multiplied by appropriate emission coefficients may serve as the background to establish loads of mercury emitted into atmosphere from individual stations and by the entire sector of power engineering in total. It will also enable Polish central organizations and individual business entities to implement reasonable policy with respect of mercury emission into atmosphere.

  17. Future trends in environmental mercury concentrations: implications for prevention strategies

    Directory of Open Access Journals (Sweden)

    Sunderland Elsie M

    2013-01-01

    Full Text Available Abstract In their new paper, Bellanger and coauthors show substantial economic impacts to the EU from neurocognitive impairment associated with methylmercury (MeHg exposures. The main source of MeHg exposure is seafood consumption, including many marine species harvested from the global oceans. Fish, birds and other wildlife are also susceptible to the impacts of MeHg and already exceed toxicological thresholds in vulnerable regions like the Arctic. Most future emissions scenarios project a growth or stabilization of anthropogenic mercury releases relative to present-day levels. At these emissions levels, inputs of mercury to ecosystems are expected to increase substantially in the future, in part due to growth in the legacy reservoirs of mercury in oceanic and terrestrial ecosystems. Seawater mercury concentration trajectories in areas such as the North Pacific Ocean that supply large quantities of marine fish to the global seafood market are projected to increase by more than 50% by 2050. Fish mercury levels and subsequent human and biological exposures are likely to also increase because production of MeHg in ocean ecosystems is driven by the supply of available inorganic mercury, among other factors. Analyses that only consider changes in primary anthropogenic emissions are likely to underestimate the severity of future deposition and concentration increases associated with growth in mercury reservoirs in the land and ocean. We therefore recommend that future policy analyses consider the fully coupled interactions among short and long-lived reservoirs of mercury in the atmosphere, ocean, and terrestrial ecosystems. Aggressive anthropogenic emission reductions are needed to reduce MeHg exposures and associated health impacts on humans and wildlife and protect the integrity of one of the last wild-food sources globally. In the near-term, public health advice on safe fish consumption choices such as smaller species, younger fish, and harvests

  18. Mercury in the National Parks: Current Status and Effects

    Science.gov (United States)

    Flanagan, C.; Blett, T. F.; Morris, K.

    2012-12-01

    Mercury is a globally distributed contaminant that can harm human and wildlife health, and threaten resources the National Park Service (NPS) is charged with protecting. Due in part to emissions and long-range transport from coal burning power plants, even remote national park environments receive mercury deposition from the atmosphere. Given the concern regarding mercury, there are and have been many mercury monitoring initiatives in national parks to determine the risk from mercury contamination. This includes the study of litter fall at Acadia National Park (Maine), snow at Mount Rainier National Park (Washington), heron eggs at Indiana Dunes National Lakeshore (Indiana), bat hair at Mammoth Cave National Park (Kentucky), and panthers at Everglades National Park (Florida). Wet deposition is also measured at 16 national parks as part of the National Atmospheric Deposition Network / Mercury Deposition Network. Results from these studies indicate that mercury deposition is increasing or is elevated in many national parks, and fish and other biota have been found to contain levels of mercury above toxicity thresholds for impacts to both humans and wildlife. Current research coordinated by the NPS Air Resources Division (ARD) in Denver, Colorado, on the effects of mercury includes broad-scale assessments of mercury in fish, dragonfly larvae, and songbirds across 30+ national parks. Fish provide the trophic link to human and wildlife health, dragonfly larvae can describe fine-scale differences in mercury levels, and songbirds shed light on the risk to terrestrial ecosystems. External project partners include the U.S. Geological Survey, University of Maine, and the Biodiversity Research Institute. In addition, the dragonfly project engages citizen scientists in the collection of dragonfly larvae, supporting the NPS Centennial Initiative by connecting people to parks and advancing the educational mission, and increasing public awareness about mercury impacts. Much of

  19. Experimental dosing of wetlands with coagulants removes mercury from surface water and decreases mercury bioaccumulation in fish

    Science.gov (United States)

    Ackerman, Joshua T.; Kraus, Tamara E.C.; Fleck, Jacob A.; Krabbenhoft, David P.; Horwarth, William R.; Bachand, Sandra M.; Herzog, Mark; Hartman, Christopher; Bachand, Philip A.M.

    2015-01-01

    Mercury pollution is widespread globally, and strategies for managing mercury contamination in aquatic environments are necessary. We tested whether coagulation with metal-based salts could remove mercury from wetland surface waters and decrease mercury bioaccumulation in fish. In a complete randomized block design, we constructed nine experimental wetlands in California’s Sacramento–San Joaquin Delta, stocked them with mosquitofish (Gambusia affinis), and then continuously applied agricultural drainage water that was either untreated (control), or treated with polyaluminum chloride or ferric sulfate coagulants. Total mercury and methylmercury concentrations in surface waters were decreased by 62% and 63% in polyaluminum chloride treated wetlands and 50% and 76% in ferric sulfate treated wetlands compared to control wetlands. Specifically, following coagulation, mercury was transferred from the filtered fraction of water into the particulate fraction of water which then settled within the wetland. Mosquitofish mercury concentrations were decreased by 35% in ferric sulfate treated wetlands compared to control wetlands. There was no reduction in mosquitofish mercury concentrations within the polyaluminum chloride treated wetlands, which may have been caused by production of bioavailable methylmercury within those wetlands. Coagulation may be an effective management strategy for reducing mercury contamination within wetlands, but further studies should explore potential effects on wetland ecosystems.

  20. Intentional intravenous mercury injection

    African Journals Online (AJOL)

    In this case report, intravenous complications, treatment strategies and possible ... Mercury toxicity is commonly associated with vapour inhalation or oral ingestion, for which there exist definite treatment options. Intravenous mercury ... personality, anxiousness, irritability, insomnia, depression and drowsi- ness.[1] However ...

  1. International mercury conference

    CSIR Research Space (South Africa)

    Leaner, J

    2006-10-01

    Full Text Available Mercury (Hg) affects human health and the environment, it calls for immediate action. Action is needed at local, regional and international level to reduce the risk associated with mercury, which is a global international problem, as it is a...

  2. Mercury's shifting, rolling past

    OpenAIRE

    Trulove, Susan

    2008-01-01

    Patterns of scalloped-edged cliffs or lobate scarps on Mercury's surface are thrust faults that are consistent with the planet shrinking and cooling with time. However, compression occurred in the planet's early history and Mariner 10 images revealed decades ago that lobate scarps are among the youngest features on Mercury. Why don't we find more evidence of older compressive features?

  3. MESSENGER: Exploring Mercury's Magnetosphere

    Science.gov (United States)

    Slavin, James A.

    2008-01-01

    The MESSENGER mission to Mercury offers our first opportunity to explore this planet's miniature magnetosphere since Mariner 10's brief fly-bys in 1974-5. Mercury's magnetosphere is unique in many respects. The magnetosphere of Mercury is the smallest in the solar system with its magnetic field typically standing off the solar wind only - 1000 to 2000 km above the surface. For this reason there are no closed dri-fi paths for energetic particles and, hence, no radiation belts; the characteristic time scales for wave propagation and convective transport are short possibly coupling kinetic and fluid modes; magnetic reconnection at the dayside magnetopause may erode the subsolar magnetosphere allowing solar wind ions to directly impact the dayside regolith; inductive currents in Mercury's interior should act to modify the solar In addition, Mercury's magnetosphere is the only one with its defining magnetic flux tubes rooted in a planetary regolith as opposed to an atmosphere with a conductive ionosphere. This lack of an ionosphere is thought to be the underlying reason for the brevity of the very intense, but short lived, approx. 1-2 min, substorm-like energetic particle events observed by Mariner 10 in Mercury's magnetic tail. In this seminar, we review what we think we know about Mercury's magnetosphere and describe the MESSENGER science team's strategy for obtaining answers to the outstanding science questions surrounding the interaction of the solar wind with Mercury and its small, but dynamic magnetosphere.

  4. Global Mercury Assessment 2013

    International Development Research Centre (IDRC) Digital Library (Canada)

    mercury pollution. This summary report and the accompanying. Technical Background Report for the Global. Mercury Assessment 2013 are developed in response to Decision 25/5, paragraph ... The use of different pollution control technologies in different ...... vegetation, snow, freshwater, and seawater. One of the largest ...

  5. Review of technologies for mercury removal from flue gas from cement production processes

    DEFF Research Database (Denmark)

    Zheng, Yuanjing; Jensen, Anker Degn; Windelin, Christian

    2012-01-01

    Mercury is a pollutant of concern and mercury emissions from cement plants are under environmental regulation. After coal-fired power plants, mercury emissions from cement and mineral production are the second largest anthropogenic sources. Compared to fuels, cement raw materials are the major...... sources of mercury in the cement kiln flue gas. Cement plants are quite different from power plants and waste incinerators regarding the flue gas composition, temperature, residence time, and material circulation. Cement kiln systems have some inherent ability to retain mercury in the solid materials due...... kilns.Among the mercury control technologies, sorbent injection upstream of a particulate control device has shown the most promise. Due to material recirculation, and high moisture level in the cement kiln flue gas the application of sorbent injection to cement plants will be more challenging...

  6. Automated Collection of Real-Time Alerts of Citizens as a Useful Tool to Continuously Monitor Malodorous Emissions.

    Science.gov (United States)

    Brattoli, Magda; Mazzone, Antonio; Giua, Roberto; Assennato, Giorgio; de Gennaro, Gianluigi

    2016-02-26

    The evaluation of odor emissions and dispersion is a very arduous topic to face; the real-time monitoring of odor emissions, the identification of chemical components and, with proper certainty, the source of annoyance represent a challenge for stakeholders such as local authorities. The complaints of people, often not systematic and variously distributed, in general do not allow us to quantify the perceived annoyance. Experimental research has been performed to detect and evaluate olfactory annoyance, based on field testing of an innovative monitoring methodology grounded in automatic recording of citizen alerts. It has been applied in Taranto, in the south of Italy where a relevant industrial area is located, by using Odortel(®) for automated collection of citizen alerts. To evaluate its reliability, the collection system has been integrated with automated samplers, able to sample odorous air in real time, according to the citizen alerts of annoyance and, moreover, with meteorological data (especially the wind direction) and trends in odor marker compounds, recorded by air quality monitoring stations. The results have allowed us, for the first time, to manage annoyance complaints, test their reliability, and obtain information about the distribution and entity of the odor phenomena, such that we were able to identify, with supporting evidence, the source as an oil refinery plant.

  7. Mercury pollution in Asia: a review of the contaminated sites.

    Science.gov (United States)

    Li, P; Feng, X B; Qiu, G L; Shang, L H; Li, Z G

    2009-09-15

    This article describes the mercury contaminated sites in Asia. Among the various regions, Asia has become the largest contributor of anthropogenic atmospheric mercury (Hg), responsible for over half of the global emission. Based on different emission source categories, the mercury contaminated sites in Asia were divided into various types, such as Hg pollution from Hg mining, gold mining, chemical industry, metal smelting, coal combustion, metropolitan cities, natural resources and agricultural sources. By the review of a large number of studies, serious Hg pollutions to the local environment were found in the area influenced by chemical industry, mercury mining and gold mining. With the probable effects of a unique combination of climatic (e.g. subtropical climate), environmental (e.g. acid rain), economic (e.g. swift growth) and social factors (e.g. high population density), more effort is still needed to understand the biogeochemistry cycle of Hg and associated health effects in Asia. Safer alternatives and cleaner technologies must be developed and effectively implemented to reduce mercury emission; remedial techniques are also required to restore the historical mercury pollution in Asia.

  8. Long-Term Carbon Injection Field Test for 90% Mercury Removal for a PRB Unit a Spray Dryer and Fabric Filter

    Energy Technology Data Exchange (ETDEWEB)

    Sjostrom, Sharon; Amrhein, Jerry

    2009-04-30

    -generation continuous emissions monitors for mercury (Hg-CEMs) to allow automatic feedback control on outlet mercury emissions. This was accomplished and the plant can now be operated to control carbon injection based on either the overall mercury removal or an outlet mercury emission rate. By integrating these systems, it was determined that the plant could reduce powdered activated carbon consumption, especially at low load, because, at Hardin, native mercury capture increases from less than 20% to about 50% at low load and the carbon injection rate can be decreased accordingly. Currently, the plant is operating to automatically control emissions to below 0.9 lb/TBtu (pounds of mercury per million British thermal units) at carbon loadings of 0.5 to 1.5 lb/MMacf. During the final phase of the Long-Term test, the ACI system was operated by plant personnel. The estimated O&M cost for a single Hg-CEM system is $15,500/yr. The Hg-CEMs performed well throughout the project. This project began shortly after Thermo Fisher first offered the Mercury Freedom System™ on a commercial basis and progressed though several iterations, improvements, and upgrades to the hardware and software. Indeed, there was a ten-fold increase in the precision and accuracy of the units during the course of the project due to several successful upgrades. In their present condition, the Hg-CEMs measure mercury to a precision of about ± 0.05 μg/wscm (micrograms of mercury per wet standard cubic meter of gas), and only require occasional fine-tuning of the calibration coefficients. The quality assurance/quality control (QA/QC) protocol required to keep the units operating at their optimal performance was also developed and perfected during the course of the project. ADA Environmental Solutions (ADA) developed a daily calibration procedure that surpasses the requirements specified in the Clean Air Mercury Rule (CAMR), and a weekly diagnostic program that ensures that the systems are operating properly and receive the

  9. Mercury in canned tuna: white versus light and temporal variation

    International Nuclear Information System (INIS)

    Burger, Joanna; Gochfeld, Michael

    2004-01-01

    mercury. These data indicate that people who eat canned tuna frequently can choose light tuna and reduce their mercury intake. Canned mackerel had much lower levels of mercury than tuna. Since cans of white tuna frequently exceed the FDA's original action level of 0.5 ppm, it would be prudent to continue some systematic monitoring of the nation's canned fish supply, particularly as the targets of commercial fisheries inevitably change as certain stocks become depleted

  10. Getting Mercury out of Schools.

    Science.gov (United States)

    1999

    This guide was prepared while working with many Massachusetts schools to remove items that contain mercury and to find suitable alternatives. It contains fact sheets on: mercury in science laboratories and classrooms, mercury in school buildings and maintenance areas, mercury in the medical office and in medical technology classrooms in vocational…

  11. Model analyses of atmospheric mercury: present air quality and effects of transpacific transport on the United States

    Science.gov (United States)

    Lei, H.; Liang, X.-Z.; Wuebbles, D. J.; Tao, Z.

    2013-11-01

    Atmospheric mercury is a toxic air and water pollutant that is of significant concern because of its effects on human health and ecosystems. A mechanistic representation of the atmospheric mercury cycle is developed for the state-of-the-art global climate-chemistry model, CAM-Chem (Community Atmospheric Model with Chemistry). The model simulates the emission, transport, transformation and deposition of atmospheric mercury (Hg) in three forms: elemental mercury (Hg(0)), reactive mercury (Hg(II)), and particulate mercury (PHg). Emissions of mercury include those from human, land, ocean, biomass burning and volcano related sources. Land emissions are calculated based on surface solar radiation flux and skin temperature. A simplified air-sea mercury exchange scheme is used to calculate emissions from the oceans. The chemistry mechanism includes the oxidation of Hg(0) in gaseous phase by ozone with temperature dependence, OH, H2O2 and chlorine. Aqueous chemistry includes both oxidation and reduction of Hg(0). Transport and deposition of mercury species are calculated through adapting the original formulations in CAM-Chem. The CAM-Chem model with mercury is driven by present meteorology to simulate the present mercury air quality during the 1999-2001 period. The resulting surface concentrations of total gaseous mercury (TGM) are then compared with the observations from worldwide sites. Simulated wet depositions of mercury over the continental United States are compared to the observations from 26 Mercury Deposition Network stations to test the wet deposition simulations. The evaluations of gaseous concentrations and wet deposition confirm a strong capability for the CAM-Chem mercury mechanism to simulate the atmospheric mercury cycle. The general reproduction of global TGM concentrations and the overestimation on South Africa indicate that model simulations of TGM are seriously affected by emissions. The comparison to wet deposition indicates that wet deposition patterns

  12. Advanced Utility Mercury-Sorbent Field-Testing Program

    Energy Technology Data Exchange (ETDEWEB)

    Ronald Landreth

    2007-12-31

    This report summarizes the work conducted from September 1, 2003 through December 31, 2007 on the project entitled Advanced Utility Mercury-Sorbent Field-Testing Program. The project covers the testing at the Detroit Edison St. Clair Plant and the Duke Power Cliffside and Buck Stations. The St. Clair Plant used a blend of subbituminous and bituminous coal and controlled the particulate emissions by means of a cold-side ESP. The Duke Power Stations used bituminous coals and controlled their particulate emissions by means of hot-side ESPs. The testing at the Detroit Edison St. Clair Plant demonstrated that mercury sorbents could be used to achieve high mercury removal rates with low injection rates at facilities that burn subbituminous coal. A mercury removal rate of 94% was achieved at an injection rate of 3 lb/MMacf over the thirty day long-term test. Prior to this test, it was believed that the mercury in flue gas of this type would be the most difficult to capture. This is not the case. The testing at the two Duke Power Stations proved that carbon- based mercury sorbents can be used to control the mercury emissions from boilers with hot-side ESPs. It was known that plain PACs did not have any mercury capacity at elevated temperatures but that brominated B-PAC did. The mercury removal rate varies with the operation but it appears that mercury removal rates equal to or greater than 50% are achievable in facilities equipped with hot-side ESPs. As part of the program, both sorbent injection equipment and sorbent production equipment was acquired and operated. This equipment performed very well during this program. In addition, mercury instruments were acquired for this program. These instruments worked well in the flue gas at the St. Clair Plant but not as well in the flue gas at the Duke Power Stations. It is believed that the difference in the amount of oxidized mercury, more at Duke Power, was the difference in instrument performance. Much of the equipment was

  13. ICT-Isomerization-Induced Turn-On Fluorescence Probe with a Large Emission Shift for Mercury Ion: Application in Combinational Molecular Logic.

    Science.gov (United States)

    Bhatta, Sushil Ranjan; Mondal, Bijan; Vijaykumar, Gonela; Thakur, Arunabha

    2017-10-02

    A unique turn-on fluorescent device based on a ferrocene-aminonaphtholate derivative specific for Hg 2+ cation was developed. Upon binding with Hg 2+ ion, the probe shows a dramatic fluorescence enhancement (the fluorescence quantum yield increases 58-fold) along with a large red shift of 68 nm in the emission spectrum. The fluorescence enhancement with a red shift may be ascribed to the combinational effect of C═N isomerization and an extended intramolecular charge transfer (ICT) mechanism. The response was instantaneous with a detection limit of 2.7 × 10 -9 M. Upon Hg 2+ recognition, the ferrocene/ferrocenium redox peak was anodically shifted by ΔE 1/2 = 72 mV along with a "naked eye" color change from faint yellow to pale orange for this metal cation. Further, upon protonation of the imine nitrogen, the present probe displays a high fluorescence output due to suppression of the C═N isomerization process. Upon deprotonation using strong base, the fluorescence steadily decreases, which indicates that H + and OH - can be used to regulate the off-on-off fluorescence switching of the present probe. Density functional theory studies revealed that the addition of acid leads to protonation of the imine N (according to natural bond orbital analysis), and the resulting iminium proton forms a strong H-bond (2.307 Å) with one of the triazole N atoms to form a five-membered ring, which makes the molecule rigid; hence, enhancement of the ICT process takes place, thereby leading to a fluorescence enhancement with a red shift. The unprecedented combination of H + , OH - , and Hg 2+ ions has been used to generate a molecular system exhibiting the INHIBIT-OR combinational logic operation.

  14. EPA’s Hg Gas Traceability Approach for Source Emissions Measurement and Monitoring

    Science.gov (United States)

    Solicited presentation (special topic) at the International Conference on Mercury as a Global Pollutant on how EPA establishes the NIST traceability of reference materials used to support regulatory mercury emissions measurements.

  15. Mercury capture within coal-fired power plant electrostatic precipitators: model evaluation.

    Science.gov (United States)

    Clack, Herek L

    2009-03-01

    Efforts to reduce anthropogenic mercury emissions worldwide have recently focused on a variety of sources, including mercury emitted during coal combustion. Toward that end, much research has been ongoing seeking to develop new processes for reducing coal combustion mercury emissions. Among air pollution control processes that can be applied to coal-fired boilers, electrostatic precipitators (ESPs) are by far the most common, both on a global scale and among the principal countries of India, China, and the U.S. that burn coal for electric power generation. A previously reported theoretical model of in-flight mercury capture within ESPs is herein evaluated against data from a number of full-scale tests of activated carbon injection for mercury emissions control. By using the established particle size distribution of the activated carbon and actual or estimated values of its equilibrium mercury adsorption capacity, the incremental reduction in mercury concentration across each ESP can be predicted and compared to experimental results. Because the model does not incorporate kinetics associated with gas-phase mercury transformation or surface adsorption, the model predictions representthe mass-transfer-limited performance. Comparing field data to model results reveals many facilities performing at or near the predicted mass-transfer-limited maximum, particularly at low rates of sorbent injection. Where agreement is poor between field data and model predictions, additional chemical or physical phenomena may be responsible for reducing mercury removal efficiencies.

  16. Modeling the CO2 and N2O Emissions From Stover Removal for Biofuel Production From Continuous Corn Production in Iowa

    Science.gov (United States)

    Paustian, K.; Killian, K.; Brenner, J.

    2003-12-01

    Corn stover, an agricultural residue, can be used as feedstock for near term bioethanol production and is available today at levels that can significantly impact energy supply. We evaluated the environmental impact of such a large-scale change in agricultural practices on green house gas production, soil erosion and soil carbon using the Century model. Estimates of soil C changes and GHG emissions were performed for the 99 counties in Iowa where previous environmental, management and erosion data was available. We employed climate, soil and historical management databases from a separate USDA-funded project as input to Century. RUSLE estimates of the residue requirements for acceptable soil loss rates under continuous corn agriculture were available from a previous study done Dr. Richard Nelson (Enersol Resources). Two mulch tillage and a no-till systems, where erosion estimates were available, were used as the basis for the simulations. Century simulations of these systems were run under a variety of stover removal rates. For each soil type within each county the model was run for 15 years (1980-1995) under continuous corn with convention tillage, and full residue return. Model simulation of crop yields and residue production were then calibrated to match those used by the Polysys model team at Oak Ridge and the simulation was repeated with the addition of the three corn tillage regimes, and several residue removal rates. County-average soil C changes (and net CO2 emissions) were calculated as area-weighted averages of the individual soil types in each county. For this study, we have utilized the IPCC approach to estimate annual N2O emissions. At low or zero residue removal rates, county-averaged soil C stocks were predicted to increase (i.e. net CO2 emissions are negative). Where the allowable residue removal rates (based on erosion tolerance) for mulch-tillage are on the order of 40-50% or more, the reduced input of C is such that the soils no longer sequester C

  17. Evaluation of a sequential extraction process used for determining mercury binding mechanisms to coal combustion byproducts.

    Science.gov (United States)

    Noel, James D; Biswas, Pratim; Giammar, Daniel E

    2007-07-01

    Leaching of mercury from coal combustion byproducts is a concern because of the toxicity of mercury. Leachability of mercury can be assessed by using sequential extraction procedures. Sequential extraction procedures are commonly used to determine the speciation and mobility of trace metals in solid samples and are designed to differentiate among metals bound by different mechanisms and to different solid phases. This study evaluated the selectivity and effectiveness of a sequential extraction process used to determine mercury binding mechanisms to various materials. A six-step sequential extraction process was applied to laboratory-synthesized materials with known mercury concentrations and binding mechanisms. These materials were calcite, hematite, goethite, and titanium dioxide. Fly ash from a full-scale power plant was also investigated. The concentrations of mercury were measured using inductively coupled plasma (ICP) mass spectrometry, whereas the major elements were measured by ICP atomic emission spectrometry. The materials were characterized by X-ray powder diffraction and scanning electron microscopy with energy dispersive spectroscopy. The sequential extraction procedure provided information about the solid phases with which mercury was associated in the solid sample. The procedure effectively extracted mercury from the target phases. The procedure was generally selective in extracting mercury. However, some steps in the procedure extracted mercury from nontarget phases, and others resulted in mercury redistribution. Iron from hematite and goethite was only leached in the reducible and residual extraction steps. Some mercury associated with goethite was extracted in the ion exchangeable step, whereas mercury associated with hematite was extracted almost entirely in the residual step. Calcium in calcite and mercury associated with calcite were primarily removed in the acid-soluble extraction step. Titanium in titanium dioxide and mercury adsorbed onto

  18. Mapping the Topography of Mercury with MESSENGER Laser Altimetry

    Science.gov (United States)

    Sun, Xiaoli; Cavanaugh, John F.; Neumann, Gregory A.; Smith, David E..; Zubor, Maria T.

    2012-01-01

    The Mercury Laser Altimeter onboard MESSENGER involves unique design elements that deal with the challenges of being in orbit around Mercury. The Mercury Laser Altimeter (MLA) is one of seven instruments on NASA's MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) spacecraft. MESSENGER was launched on 3 August 2004, and entered into orbit about Mercury on 18 March 2011 after a journey through the inner solar system. This involved six planetary flybys, including three of Mercury. MLA is designed to map the topography and landforms of Mercury's surface. It also measures the planet's forced libration (motion about the spin axis), which helps constrain the state of the core. The first science measurements from orbit taken with MLA were made on 29 March 2011 and continue to date. MLA had accumulated about 8.3 million laser ranging measurements to Mercury's surface, as of 31 July 2012, i.e., over six Mercury years (528 Earth days). Although MLA is the third planetary lidar built at the NASA Goddard Space Flight Center (GSFC), MLA must endure a much harsher thermal environment near Mercury than the previous instruments on Mars and Earth satellites. The design of MLA was derived in part from that of the Mars Orbiter Laser Altimeter on Mars Global Surveyor. However, MLA must range over greater distances and often in off-nadir directions from a highly eccentric orbit. In MLA we use a single-mode diode-pumped Nd:YAG (neodymium-doped yttrium aluminum garnet) laser that is highly collimated to maintain a small footprint on the planet. The receiver has both a narrow field of view and a narrow spectral bandwidth to minimize the amount of background light detected from the sunlit hemisphere of Mercury. We achieve the highest possible receiver sensitivity by employing the minimum receiver detection threshold.

  19. Mercury's Dynamic Magnetic Tail

    Science.gov (United States)

    Slavin, James A.

    2010-01-01

    The Mariner 10 and MESSENGER flybys of Mercury have revealed a magnetosphere that is likely the most responsive to upstream interplanetary conditions of any in the solar system. The source of the great dynamic variability observed during these brief passages is due to Mercury's proximity to the Sun and the inverse proportionality between reconnection rate and solar wind Alfven Mach number. However, this planet's lack of an ionosphere and its small physical dimensions also contribute to Mercury's very brief Dungey cycle, approx. 2 min, which governs the time scale for internal plasma circulation. Current observations and understanding of the structure and dynamics of Mercury's magnetotail are summarized and discussed. Special emphasis will be placed upon such questions as: 1) How much access does the solar wind have to this small magnetosphere as a function of upstream conditions? 2) What roles do heavy planetary ions play? 3) Do Earth-like substorms take place at Mercury? 4) How does Mercury's tail respond to extreme solar wind events such coronal mass ejections? Prospects for progress due to advances in the global magnetohydrodynamic and hybrid simulation modeling and the measurements to be taken by MESSENGER after it enters Mercury orbit on March 18, 2011 will be discussed.

  20. The method of determination of mercury adsorption from flue gases

    Directory of Open Access Journals (Sweden)

    Budzyń Stanisław

    2017-01-01

    Full Text Available For several recent years Faculty of Energy and Fuels of the AGH University of Science and Technology in Krakow conduct intensive studies on the occurrence of mercury contained in thermal and coking coals, as well as on the possible reduction of fossil-fuel mercury emissions. This research focuses, among others, on application of sorbents for removal of mercury from flue gases. In this paper we present the methodology for testing mercury adsorption using various types of sorbents, in laboratory conditions. Our model assumes burning a coal sample, with a specific mercury content, in a strictly determined time period and temperature conditions, oxygen or air flow rates, and the flow of flue gases through sorbent in a specific temperature. It was developed for particular projects concerning the possibilities of applying different sorbents to remove mercury from flue gases. Test stand itself is composed of a vertical pipe furnace inside which a quartz tube was mounted for sample burning purposes. At the furnace outlet, there is a heated glass vessel with a sorbent sample through which flue gases are passing. Furnace allows burning at a defined temperature. The exhaust gas flow path is heated to prevent condensation of the mercury vapor prior to contact with a sorbent. The sorbent container is positioned in the heating element, with controlled and stabilized temperature, which allows for testing mercury sorption in various temperatures. Determination of mercury content is determined before (coal and sorbent, as well as after the process (sorbent and ash. The mercury balance is calculated based on the Hg content determination results. This testing method allows to study sorbent efficiency, depending on sorption temperature, sorbent grain size, and flue-gas rates.

  1. Inorganic: the other mercury.

    Science.gov (United States)

    Risher, John F; De Rosa, Christopher T

    2007-11-01

    There is a broad array of mercury species to which humans may be exposed. While exposure to methylmercury through fish consumption is widely recognized, the public is less aware of the sources and potential toxicity of inorganic forms of mercury. Some oral and laboratory thermometers, barometers, small batteries, thermostats, gas pressure regulators, light switches, dental amalgam fillings, cosmetic products, medications, cultural/religious practices, and gold mining all represent potential sources of exposure to inorganic forms of mercury. The route of exposure, the extent of absorption, the pharmacokinetics, and the effects all vary with the specific form of mercury and the magnitude and duration of exposure. If exposure is suspected, a number of tissue analyses can be conducted to confirm exposure or to determine whether an exposure might reasonably be expected to be biologically significant. By contrast with determination of exposure to methylmercury, for which hair and blood are credible indicators, urine is the preferred biological medium for the determination of exposure to inorganic mercury, including elemental mercury, with blood normally being of value only if exposure is ongoing. Although treatments are available to help rid the body of mercury in cases of extreme exposure, prevention of exposure will make such treatments unnecessary. Knowing the sources of mercury and avoiding unnecessary exposure are the prudent ways of preventing mercury intoxication. When exposure occurs, it should be kept in mind that not all unwanted exposures will result in adverse health consequences. In all cases, elimination of the source of exposure should be the first priority of public health officials.

  2. Continuous wavelet transform analysis and modal location analysis acoustic emission source location for nuclear piping crack growth monitoring

    International Nuclear Information System (INIS)

    Mohd, Shukri; Holford, Karen M.; Pullin, Rhys

    2014-01-01

    Source location is an important feature of acoustic emission (AE) damage monitoring in nuclear piping. The ability to accurately locate sources can assist in source characterisation and early warning of failure. This paper describe the development of a novelAE source location technique termed 'Wavelet Transform analysis and Modal Location (WTML)' based on Lamb wave theory and time-frequency analysis that can be used for global monitoring of plate like steel structures. Source location was performed on a steel pipe of 1500 mm long and 220 mm outer diameter with nominal thickness of 5 mm under a planar location test setup using H-N sources. The accuracy of the new technique was compared with other AE source location methods such as the time of arrival (TOA) techniqueand DeltaTlocation. Theresults of the study show that the WTML method produces more accurate location resultscompared with TOA and triple point filtering location methods. The accuracy of the WTML approach is comparable with the deltaT location method but requires no initial acoustic calibration of the structure

  3. Annual ambient atmospheric mercury speciation measurement from Longjing, a rural site in Taiwan.

    Science.gov (United States)

    Fang, Guor-Cheng; Lo, Chaur-Tsuen; Cho, Meng-Hsien; Zhuang, Yuan-Jie; Tsai, Kai-Hsiang; Huang, Chao-Yang; Xiao, You-Fu

    2017-08-01

    The main purpose of this study was to monitor ambient air particulates and mercury species [RGM, Hg(p), GEM and total mercury] concentrations and dry depositions over rural area at Longjing in central Taiwan during October 2014 to September 2015. In addition, passive air sampler and knife-edge surrogate surface samplers were used to collect the ambient air mercury species concentrations and dry depositions, respectively, in this study. Moreover, direct mercury analyzer was directly used to detect the mercury Hg(p) and RGM concentrations. The result indicated that: (1) The average highest RGM, Hg(p), GEM and total mercury concentrations, and dry depositions were observed in January, prevailing dust storm occurred in winter season was the possible major reason responsible for the above findings. (2) The highest average RGM, Hg(p), GEM and total mercury concentrations, dry depositions and velocities were occurred in winter. This is because that China is the largest atmospheric mercury (Hg) emitter in the world. Its Hg emissions and environmental impacts need to be evaluated. (3) The results indicated that the total mercury ratios of Kaohsiung to that of this study were 5.61. This is because that Kaohsiung has the largest industry density (~60 %) in Taiwan. (4) the USA showed average lower mercury species concentrations when compared to those of the other world countries. The average ratios of China/USA values were 89, 76 and 160 for total mercury, RGM and Hg(p), respectively, during the years of 2000-2012.

  4. Subtask 4.8 - Fate and Control of Mercury and Trace Elements

    Energy Technology Data Exchange (ETDEWEB)

    Pavlish, John; Lentz, Nicholas; Martin, Christopher; Ralston, Nicholas; Zhuang, Ye; Hamre, Lucinda

    2011-12-31

    The Center for Air Toxic Metals® (CATM®) Program at the Energy & Environmental Research Center (EERC) continues to focus on vital basic and applied research related to the fate, behavior, measurement, and control of trace metals, especially mercury, and the impact that these trace metals have on human health and the environment. For years, the CATM Program has maintained an international perspective, performing research and providing results that apply to both domestic and international audiences, with reports distributed in the United States and abroad. In addition to trace metals, CATM’s research focuses on other related emissions and issues that impact trace metal releases to the environment, such as SOx, NOx, CO2, ash, and wastewater streams. Of paramount interest and focus has been performing research that continues to enable the power and industrial sectors to operate in an environmentally responsible manner to meet regulatory standards. The research funded by the U.S. Department of Energy’s (DOE’s) National Energy Technology Laboratory (NETL) through CATM has allowed significant strides to be made to gain a better understanding of trace metals and other emissions, improve sampling and measurement techniques, fill data gaps, address emerging technical issues, and develop/test control technologies that allow industry to cost-effectively meet regulatory standards. The DOE NETL–CATM research specifically focused on the fate and control of mercury and trace elements in power systems that use CO2 control technologies, such as oxycombustion and gasification systems, which are expected to be among those technologies that will be used to address climate change issues. In addition, research addressed data gaps for systems that use conventional and multipollutant control technologies, such as electrostatic precipitators, selective catalytic reduction units, flue gas desulfurization systems, and flue gas

  5. Characterisation of charging kinetics of dielectrics under continuous electron irradiation through real time electron emission collecting method

    Energy Technology Data Exchange (ETDEWEB)

    Guerch, Kévin, E-mail: kevin.guerch@onera.fr [ONERA, 2 Avenue Edouard Belin, 31055 Toulouse Cedex 4 (France); CIRIMAT – Institut Carnot (CNRS) Université Paul Sabatier, 118 route de Narbonne, 31062 Toulouse Cedex 09 (France); Paulmier, Thierry [ONERA, 2 Avenue Edouard Belin, 31055 Toulouse Cedex 4 (France); Guillemet-Fritsch, Sophie; Lenormand, Pascal [CIRIMAT – Institut Carnot (CNRS) Université Paul Sabatier, 118 route de Narbonne, 31062 Toulouse Cedex 09 (France)

    2015-04-15

    Dielectric materials used for spacecraft applications are often characterised under electron irradiation in order to study their physical and electrical mechanisms. For surface potential measurement, a small removable flat device based on the secondary electron spectrometer method has been developed and installed in the CEDRE irradiation test facility at ONERA (Toulouse, France). This technique was developed to get rid off specific issues inherent to the Kelvin Probe technique. This experimental device named REPA (Repulsive Electron Potential Analyser) allows in situ and real time assessment of the surface potential built up on dielectric materials under continuous electron irradiation. A calibration has been performed in order to validate this experimental setup. Furthermore, to optimise its efficiency, the physical behaviour of this device has been modelled and numerically simulated using Particle In Cell (PIC) model and a dedicated numerical code called SPIS (Spacecraft Plasma Interactions System). In a final step, electrical characterisations of a charged dielectric have been carried out under continuous electron irradiation with this new method. These results have been compared with measurements performed in same experimental conditions with conventional Kelvin Probe method. The experimental results have been discussed in this paper. To conclude, advantages of this experimental setup in regard of this application will be emphasised.

  6. Mercury contamination from artisanal gold mining in Antioquia, Colombia: The world's highest per capita mercury pollution.

    Science.gov (United States)

    Cordy, Paul; Veiga, Marcello M; Salih, Ibrahim; Al-Saadi, Sari; Console, Stephanie; Garcia, Oseas; Mesa, Luis Alberto; Velásquez-López, Patricio C; Roeser, Monika

    2011-12-01

    The artisanal gold mining sector in Colombia has 200,000 miners officially producing 30tonnes Au/a. In the Northeast of the Department of Antioquia, there are 17 mining towns and between 15,000 and 30,000 artisanal gold miners. Guerrillas and paramilitary activities in the rural areas of Antioquia pushed miners to bring their gold ores to the towns to be processed in Processing Centers or entables. These Centers operate in the urban areas amalgamating the whole ore, i.e. without previous concentration, and later burn gold amalgam without any filtering/condensing system. Based on mercury mass balance in 15 entables, 50% of the mercury added to small ball mills (cocos) is lost: 46% with tailings and 4% when amalgam is burned. In just 5 cities of Antioquia, with a total of 150,000 inhabitants: Segovia, Remedios, Zaragoza, El Bagre, and Nechí, there are 323 entables producing 10-20tonnes Au/a. Considering the average levels of mercury consumption estimated by mass balance and interviews of entables owners, the mercury consumed (and lost) in these 5 municipalities must be around 93tonnes/a. Urban air mercury levels range from 300ng Hg/m(3) (background) to 1million ng Hg/m(3) (inside gold shops) with 10,000ng Hg/m(3) being common in residential areas. The WHO limit for public exposure is 1000ng/m(3). The total mercury release/emissions to the Colombian environment can be as high as 150tonnes/a giving this country the shameful first position as the world's largest mercury polluter per capita from artisanal gold mining. One necessary government intervention is to cut the supply of mercury to the entables. In 2009, eleven companies in Colombia legally imported 130tonnes of metallic mercury, much of it flowing to artisanal gold mines. Entables must be removed from urban centers and technical assistance is badly needed to improve their technology and reduce emissions. Copyright © 2011 Elsevier B.V. All rights reserved.

  7. Questions about Mercury's role in comparative planetary geophysics

    Science.gov (United States)

    Chapman, C. R.; Weidenschilling, S. J.; Davis, D. R.; Greenberg, R.; Leake, M. A.

    1985-01-01

    Problems which have arisen in formulating a mutually consistent picture of Mercury's evolution are outlined. It appears that one or more of the following widely adopted assumptions are wrong about Mercury: (1) its original composition at least approximately resulted from equilibrium condensation; (2) its magnetic field arises from a still-active dynamo; (3) its thermal evolution should have yielded early core formation followed by cooling and a global contraction approaching 20 km in the planet's radius; (4) Mercury's surface is basaltic and the intercrater plains are of volcanic origin. It is suggested that Mercury's role in comparative planetology be reevaluated in the context of an alternative timescale based on the possibility that Mercury was subjected to a continuing source of cratering projectiles over recent aeons, which have not impacted the other terrestrial planets. Although such vulcanoids have not yet been discovered, the evolution of Mercury's orbit due to secular perturbations could well have led to a prolonged period of sweeping out any intra-Mercurian planetesimals that were originally present. Mercury's surface could be younger than previously believed, which explains why Mercury's core is still molten.

  8. Spatial and temporal variability of atmospheric mercury concentrations emitted from a coal-fired power plant in Mexico.

    Science.gov (United States)

    García, Gilberto Fuentes; Álvarez, Humberto Bravo; Echeverría, Rodolfo Sosa; de Alba, Sergio Rosas; Rueda, Víctor Magaña; Dosantos, Ernesto Caetano; Cruz, Gustavo Vázquez

    2017-09-01

    Atmospheric mercury in the environment as a result of the consumption of fossil fuels, such as coal used in electricity generation, has gained increased attention worldwide because of its toxicity, atmospheric persistence, and bioaccumulation. Determining or predicting the concentration of this pollutant in ambient air is essential for determining sensitive areas requiring health protection. This study investigated the spatiotemporal variability of gaseous elemental mercury (GEM) concentrations and its dry deposition surrounding the Presidente Plutarco Elías Calles (CETEPEC) coal-fired power plant, located on Mexico's Pacific coast. The CALPUFF dispersion model was applied on the basis of the daily consumption of coal during 2013 for each generating unit in the power plant and considering the local scale. The established 300-ng/m 3 annual average risk factor considered by the U.S. Department of Health and Human Services (U.S. DHHS) and Integrated Risk Information System (IRIS) must not be exceeded to meet satisfactory air quality levels. An area of 65 × 60 km was evaluated, and the results show that the risk level for mercury vapor was not exceeded because the annual average concentration was 2.8 ng/m 3 . Although the predicted risk level was not exceeded, continuous monitoring studies of GEM and of particulates in the atmosphere, soil, and water may be necessary to identify the concentration of this pollutant, specifically that resulting from coal-fired power plants operated in environmental areas of interest in Mexico. The dry mercury deposition was low in the study area; according to the CALPUFF model, the annual average was 1.40E-2 ng/m 2 /sec. These results represent a starting point for Mexico's government to implement the Minamata Convention on Mercury, which Mexico signed in 2013. The obtained concentrations of mercury from a bigger coal-fired plant in Mexico, through the application of the CALPUFF dispersion model by the mercury emissions, are below the

  9. Recovery of mercury from mercury compounds via electrolytic methods

    Science.gov (United States)

    Grossman, Mark W.; George, William A.

    1988-01-01

    A process for electrolytically recovering mercury from mercury compounds is provided. In one embodiment, Hg is recovered from Hg.sub.2 Cl.sub.2 employing as the electrolyte solution a mixture of HCl and H.sub.2 O. In another embodiment, Hg is electrolytically recovered from HgO wherein the electrolyte solution is comprised of glacial acetic acid and H.sub.2 O. Also provided is an apparatus for producing isotopically enriched mercury compounds in a reactor and then transporting the dissolved compounds into an electrolytic cell where mercury ions are electrolytically reduced and elemental mercury recovered from the mercury compounds.

  10. Mercury removal from SRP radioactive waste streams using ion exchange

    International Nuclear Information System (INIS)

    Bibler, J.P.; Wallace, R.M.; Ebra, M.A.

    1986-01-01

    Mercury is present in varying concentrations in some Savannah River Plant (SRP) waste streams as a result of its use as a catalyst in the dissolution of fuel elements composed of uranium-aluminum alloys. It may be desirable to remove mercury from these streams before treatment of the waste for incorporation in glass for long-term storage. The glass forming process will also create waste from which mercury will have to be removed. The goal of mercury would be to eliminate ultimate emission of the toxic substance into the environment. This paper describes tests that demonstrate the feasibility of using a specific cation exchange resin, Duolite GT-73 for the removal of mercury from five waste streams generated at the SRP. Two of these streams are dilute; one is the condensate from a waste evaporator while the other is the effluent from an effluent treatment plant now under development. The three other streams are related to the Defense Waste Processing Facility (DWPF) that is being built at SRP. One of these streams is a concentrated salt solution (principally sodium nitrate and sodium hydroxide) that constitutes the soluble fraction of SRP waste and contains 20% mercury in the waste. The second stream is a slurry of the insoluble components in SRP waste and contains 80% of the mercury. The third stream is the offgas condensate from the glass melter system in the DWPF

  11. The tectonics of Mercury

    International Nuclear Information System (INIS)

    Melosh, H.J.; Mckinnon, W.B.

    1988-01-01

    The probable tectonic history of Mercury and the relative sequence of events are discussed on the basis of data collected by the Mariner-10 spacecraft. Results indicate that Mercury's tectonic activity was confined to its early history; its endogenic activity was principally due to a small change in the shape of its lithosphere, caused by tidal despinning, and a small change in area caused by shrinkage due to cooling. Exogenic processes, in particular the impact activity, have produced more abundant tectonic features. Many features associated with the Caloris basin are due to loading of Mercury's thick lithosphere by extrusive lavas or subsidence due to magma withdrawal. It is emphasized that tectonic features observed on Mercury yield insight into the earliest tectonic events on planets like Mars and, perhaps, the earth, where subsequent events obscured or erased the most ancient tectonic records

  12. Feasibility of biodiesel production and CO2 emission reduction by Monoraphidium dybowskii LB50 under semi-continuous culture with open raceway ponds in the desert area.

    Science.gov (United States)

    Yang, Haijian; He, Qiaoning; Hu, Chunxiang

    2018-01-01

    Compared with other general energy crops, microalgae are more compatible with desert conditions. In addition, microalgae cultivated in desert regions can be used to develop biodiesel. Therefore, screening oil-rich microalgae, and researching the algae growth, CO 2 fixation and oil yield in desert areas not only effectively utilize the idle desertification lands and other resources, but also reduce CO 2 emission. Monoraphidium dybowskii LB50 can be efficiently cultured in the desert area using light resources, and lipid yield can be effectively improved using two-stage induction and semi-continuous culture modes in open raceway ponds (ORPs). Lipid content (LC) and lipid productivity (LP) were increased by 20% under two-stage industrial salt induction, whereas biomass productivity (BP) increased by 80% to enhance LP under semi-continuous mode in 5 m 2 ORPs. After 3 years of operation, M. dybowskii LB50 was successfully and stably cultivated under semi-continuous mode for a month during five cycles of repeated culture in a 200 m 2 ORP in the desert area. This culture mode reduced the supply of the original species. The BP and CO 2 fixation rate were maintained at 18 and 33 g m -2  day -1 , respectively. Moreover, LC decreased only during the fifth cycle of repeated culture. Evaporation occurred at 0.9-1.8 L m -2  day -1 , which corresponded to 6.5-13% of evaporation loss rate. Semi-continuous and two-stage salt induction culture modes can reduce energy consumption and increase energy balance through the energy consumption analysis of life cycle. This study demonstrates the feasibility of combining biodiesel production and CO 2 fixation using microalgae grown as feedstock under culture modes with ORPs by using the resources in the desert area. The understanding of evaporation loss and the sustainability of semi-continuous culture render this approach practically viable. The novel strategy may be a promising alternative to existing technology for CO 2 emission

  13. Mercury in human hair

    International Nuclear Information System (INIS)

    Kapauan, P.A.; Cruz, C.C.; Verceluz, F.P.

    1980-10-01

    The analysis of mercury (Hg) in scalp hair obtained from individuals residing in five different localities in the Philippines - Metro Manila, Naga City in Bicol, Bataan, Oriental Mindoro, and Palawan is presented. An overall mean of 1.46 ug/g of hair was obtained for all samples excluding those from Palawan and represents a baseline value.'' In terms of the mercury levels found in hair, the Honda Bay area in Palawan is, relatively, a ''contaminated area.'' (author)

  14. Growing season methane emission from a boreal peatland in the continuous permafrost zone of Northeast China: effects of active layer depth and vegetation

    Directory of Open Access Journals (Sweden)

    Y. Miao

    2012-11-01

    Full Text Available Boreal peatlands are significant natural sources of methane and especially vulnerable to abrupt climate change. However, the controlling factors of CH4 emission in boreal peatlands are still unclear. In this study, we investigated CH4 fluxes and abiotic factors (temperature, water table depth, active layer depth, and dissolved CH4 concentrations in pore water during the growing seasons in 2010 and 2011 in both shrub-sphagnum- and sedge-dominated plant communities in the continuous permafrost zone of Northeast China. The objective of our study was to examine the effects of vegetation types and abiotic factors on CH4 fluxes from a boreal peatland. In an Eriophorum-dominated community, mean CH4 emissions were 1.02 and 0.80 mg m−2 h−1 in 2010 and 2011, respectively. CH4 fluxes (0.38 mg m−2 h−1 released from the shrub-mosses-dominated community were lower than that from Eriophorum-dominated community. Moreover, in the Eriophorum-dominated community, CH4 fluxes showed a significant temporal pattern with a peak value in late August in both 2010 and 2011. However, no distinct seasonal variation was observed in the CH4 flux in the shrub-mosses-dominated community. Interestingly, in both Eriophorum- and shrub-sphagnum-dominated communities, CH4 fluxes did not show close correlation with air or soil temperature and water table depth, whereas CH4 emissions correlated well to active layer depth and CH4 concentration in soil pore water, especially in the Eriophorum-dominated community. Our results suggest that CH4 released from the thawed CH4-rich permafrost layer may be a key factor controlling CH4 emissions in boreal peatlands, and highlight that CH4 fluxes vary with vegetation type in boreal peatlands. With

  15. MERCURY CONTROL WITH ADVANCED HYBRID PARTICULATE COLLECTOR

    Energy Technology Data Exchange (ETDEWEB)

    Ye Zhuang; Stanley J. Miller

    2005-05-01

    This project was awarded under U.S. Department of Energy (DOE) National Energy Technology Laboratory (NETL) Program Solicitation DE-PS26-00NT40769 and specifically addressed Technical Topical Area 4-Testing Novel and Less Mature Control Technologies on Actual Flue Gas at the Pilot Scale. The project team included the Energy & Environmental Research Center (EERC) as the main contractor; W.L. Gore & Associates, Inc., as a technical and financial partner; and the Big Stone Power Plant operated by Otter Tail Power Company, host for the field-testing portion of the research. Since 1995, DOE has supported development of a new concept in particulate control called the advanced hybrid particulate collector (AHPC). The AHPC has been licensed to W.L. Gore & Associates, Inc., and has been marketed as the Advanced Hybrid{trademark} filter by Gore. The Advanced Hybrid{trademark} filter combines the best features of electrostatic precipitators (ESPs) and baghouses in a unique configuration, providing major synergism between the two collection methods, both in the particulate collection step and in the transfer of dust to the hopper. The Advanced Hybrid{trademark} filter provides ultrahigh collection efficiency, overcoming the problem of excessive fine-particle emissions with conventional ESPs, and it solves the problem of reentrainment and re-collection of dust in conventional baghouses. The Advanced Hybrid{trademark} filter also appears to have unique advantages for mercury control over baghouses or ESPs as an excellent gas--solid contactor. The objective of the project was to demonstrate 90% total mercury control in the Advanced Hybrid{trademark} filter at a lower cost than current mercury control estimates. The approach included bench-scale batch tests, larger-scale pilot testing with real flue gas on a coal-fired combustion system, and field demonstration at the 2.5-MW (9000-acfm) scale at a utility power plant to prove scale-up and demonstrate longer-term mercury control

  16. Deformed space-time transformations in Mercury

    Science.gov (United States)

    Cardone, F.; Albertini, G.; Bassani, D.; Cherubini, G.; Guerriero, E.; Mignani, R.; Monti, M.; Petrucci, A.; Ridolfi, F.; Rosada, A.; Rosetto, F.; Sala, V.; Santoro, E.; Spera, G.

    2017-09-01

    A mole of Mercury was suitably treated by ultrasound in order to generate in it the same conditions of local Lorentz invariance violation that were generated in a sonicated cylindrical bar of AISI 304 steel and that are the cause of neutron emission during the sonication. After 3 min, part of the mercury turned into a solid material which turned out to contain isotopes having a different mass (higher and lower) with respect to the isotopes already present in the initial material (mercury). These transformations in the atomic weight without gamma production above the background are brought about during Deformed Space-Time reactions. We present the results of the analyses performed on samples taken from the transformation product. The analyses have been done in two groups, the first one using five different analytical techniques: ICP-OES, XRF, ESEM-EDS, ICP-MS, INAA. In the second group of analyses, we used only two techniques: INAA and ICP-MS. The second group of analyses confirmed the occurring of the transformations in mercury.

  17. Accumulation and fluxes of mercury in terrestrial and aquatic food chains with special reference to Finland

    Directory of Open Access Journals (Sweden)

    Martin Lodenius

    2013-03-01

    Full Text Available Mercury is known for its biomagnification especially in aquatic food chains and for its toxic effects on different organisms including man. In Finland mercury has formerly been used in industry and agriculture and in addition many anthropogenic activities may increase the mercury levels in ecosystems. Phenyl mercury was widely used as slimicide in the pulp and paper industry in the 1950s and 1960s. In the chlor-alkali industry metallic mercury was used as catalyst at three plants. The most toxic form of mercury, methyl mercury, may be formed in soils, water, sediments and organisms. Many factors, including microbial activity, temperature, oxygen status etc., affect the methylation rate. In the lake ecosystem bioaccumulation of methyl mercury is very strong. In early 1980s there was a restriction of fishing concerning approximately 4000 km2 of lakes and sea areas because of mercury pollution. In aquatic systems we still find elevated concentrations near former emission sources. Long-range atmospheric transport and mechanical operations like ditching and water regulation may cause increased levels of mercury in the aquatic ecosystems. In the Finnish agriculture organic mercury compounds were used for seed dressing until 1992. Although the amounts used were substantial the concentrations in agricultural soils have remained rather low. In terrestrial food chains bioaccumulation is normally weak with low or moderate concentration at all ecosystem levels. Due to a weak uptake through roots terrestrial, vascular plants normally contain only small amounts of mercury. There is a bidirectional exchange of mercury between vegetation and atmosphere. Contrary to vascular plants, there is a very wide range of concentrations in fungi. Mercury may pose a threat to human health especially when accumulated in aquatic food chains.

  18. Semiquantitative mercury determination in fish: a tool for poisoning prevention

    Directory of Open Access Journals (Sweden)

    YALLOUZ ALLEGRA V.

    2002-01-01

    Full Text Available Human exposure to mercury intoxication through contaminated fish ingestion has been well studied, mainly among Japanese population. The Brazilian population, particulaly in the Amazon region, is now in focus due to findings of fish contamination. Major health impacts caused by mercury affect mostly people who have a regular fish diet. A continuous checking for mercury content in the most consumed fish could prevent human intoxication. A simple, non-instrumental method to allow a continuous checking of the mercury content in fish was developed. Based on this method, we are proposing a prevention action where community agents can be trained to perform fish analysis. Technical Schools and Universities located nearby the affected areas would be in charge of quality control programs for the fish analysis as well as for the selection, training and update for operators.

  19. Isotopic Fractionation of Mercury in Great Lakes Precipitation

    Science.gov (United States)

    Gratz, L. E.; Keeler, G. J.; Blum, J. D.; Sherman, L. S.

    2009-12-01

    Mercury (Hg) is a hazardous bioaccumulative neurotoxin, and atmospheric deposition is a primary way in which mercury enters terrestrial and aquatic ecosystems. However, the chemical processes and transport regimes that mercury undergoes from emission to deposition are not well understood. Thus the use of mercury isotopes to characterize the biogeochemical cycling of mercury is a rapidly growing area of study. Precipitation samples were collected in Chicago, IL, Holland, MI, and Dexter, MI from April 2007 - October 2007 to begin examining the isotopic fractionation of atmospheric mercury in the Great Lakes region. Results show that mass-dependent fractionation relative to NIST-3133 (MDF - δ202Hg) ranged from -0.8‰ to 0.2‰ (±0.2‰) in precipitation samples, while mass-independent fractionation (MIF - Δ199Hg) varied from 0.1‰ to 0.6‰ (±0.1‰). Although clear urban-rural differences were not observed, this may be due to the weekly collection of precipitation samples rather than collection of individual events, making it difficult to truly characterize the meteorology and source influences associated with each sample and suggesting that event-based collection is necessary during future sampling campaigns. Additionally, total vapor phase mercury samples were collected in Dexter, MI in 2009 to examine isotopic fractionation of mercury in ambient air. In ambient samples δ202Hg ranged from 0.3‰ to 0.5‰ (±0.1‰), however Δ199Hg was not significant. Because mercury in precipitation is predominantly Hg2+, while ambient vapor phase mercury is primarily Hg0, these results may suggest the occurrence of MIF during the oxidation of Hg0 to Hg2+ prior to deposition. Furthermore, although it has not been previously reported or predicted, MIF of 200Hg was also detected. Δ200Hg ranged from 0.0‰ to 0.2‰ in precipitation and from -0.1‰ to 0.0‰ in ambient samples. This work resulted in methodological developments in the collection and processing of

  20. Millennial mercury records derived from ornithogenic sediment on Dongdao Island, South China Sea.

    Science.gov (United States)

    Yan, Hong; Wang, Yuhong; Cheng, Wenhan; Sun, Liguang

    2011-01-01

    Two ornithogenic sediment cores, which have a time span of 1000 years and are influenced by red-footed booby (Sula sula), were collected from Dongdao Islands, South China Sea. The determined mercury concentrations of the two cores show similar and substantial fluctuations during the past millennium, and the fluctuations are most likely caused by the changes in mercury level of the ocean environment and in anthropogenic Hg emission. For the past 500 years, the mercury concentration in the red-footed booby excrement has a striking association with global anthropogenic mercury emission. The mercury concentration increased rapidly after AD 1600 in corresponding to beginning of the unparalleled gold and silver mining in South Central America that left a large volume of anthropogenic mercury pollution. Since the Industrial Revolution, the mercury level has increased at a fast pace, very likely caused by modern coal combustion, chlor-alkali and oil refining industries. The comparison of mercury profiles from different places on earth suggested that anthropogenic mercury pollution after the Industrial Revolution is more severe in Northern Hemisphere than in Antarctica.

  1. Fabrication of mercury target vessel

    International Nuclear Information System (INIS)

    Wakui, Takashi; Kogawa, Hiroyuki; Haga, Katsuhiro; Futakawa, Masatoshi; Hayashi, Ryoichi; Uchiyama, Naoyoshi; Okamoto, Yoshinao; Nakamura, Koji

    2010-03-01

    The construction of materials and life science experimental facility in J-PARC (Japan Proton Accelerator Complex) project had been completed and accepted pulsed proton beams with low power. Since 2003, the detailed design, fabrication and examination for the mercury target vessel as a pulsed neutron source were carried out by the vender. The mercury target vessel consists of triple-walled structure in order to prevent the leak of mercury to outside at the failure of the mercury vessel and to remove the heat of the safety hull, which covers the mercury vessel, due to the injection of the pulsed proton beams. The high fabrication accuracy is required for the mercury target vessel assembled by the welding, because there are the relationships between the mercury target vessel and other components (target trolley, target storage container, flange of helium vessel, reflector and water-cooled shield). At each fabrication step, the examinations for the mercury target vessel with multi-walled structure were required. In this report, the required specification and basic structure of parts in the mercury target vessel are described and the fabrication procedure of the mercury target vessel by the vender is reported. In the fabrication of the mercury target vessel, there were many troubles such as large deformation due to the welding and then the vender repaired and brought the mercury target vessel to completion. Furthermore, improvements for the design and fabrication of the mercury target are reported. (author)

  2. Speciated atmospheric mercury on haze and non-haze days in an inland city in China

    Directory of Open Access Journals (Sweden)

    Q. Hong

    2016-11-01

    Full Text Available Long-term continuous measurements of speciated atmospheric mercury were conducted from July 2013 to June 2014 in Hefei, a midlatitude inland city in eastern central China that experiences frequent haze pollution. The mean concentrations (±standard deviation of gaseous elemental mercury (GEM, gaseous oxidized mercury (GOM and particle-bound mercury (PBM were 3.95 ± 1.93 ng m−3, 2.49 ± 2.41 and 23.3 ± 90.8 pg m−3, respectively, on non-haze days, and 4.74 ± 1.62 ng m−3, 4.32 ± 8.36 and 60.2 ± 131.4 pg m−3, respectively, on haze days. Potential source contribution function (PSCF analysis suggested that atmospheric mercury pollution on haze days was caused primarily by local emissions, instead of via long-range transport. The poorer mixing conditions on haze days also favored the accumulation of atmospheric mercury. Compared to GEM and GOM, PBM was especially sensitive to haze pollution. The mean PBM concentration on haze days was 2.5 times that on non-haze days due to elevated concentrations of particulate matter. PBM also showed a clear seasonal trend; its concentration was the highest in fall and winter, decreased rapidly in spring and was the lowest in summer, following the same order in the frequency of haze days in different seasons. On both non-haze and haze days, GOM concentrations remained low at night, but increased rapidly just before sunrise, which could be due to diurnal variation in air exchange between the boundary layer and free troposphere. However, non-haze and haze days showed different trends in daytime GEM and GOM concentrations. On non-haze days, GEM and GOM declined synchronously through the afternoon, probably due to the retreat of the free tropospheric air as the height of the atmospheric boundary layer increases. In contrast, on haze days, GOM and GEM showed opposite trends with the highest GOM and lowest GEM observed in the afternoon, suggesting the occurrence of

  3. Mercury pollution in vegetables, grains and soils from areas surrounding coal-fired power plants

    Science.gov (United States)

    Li, Rui; Wu, Han; Ding, Jing; Fu, Weimin; Gan, Lijun; Li, Yi

    2017-05-01

    Mercury contamination in food can pose serious health risks to consumers and coal-fired power plants have been identified as the major source of mercury emissions. To assess the current state of mercury pollution in food crops grown near coal-fired power plants, we measured the total mercury concentration in vegetables and grain crops collected from farms located near two coal-fired power plants. We found that 79% of vegetable samples and 67% of grain samples exceeded the PTWI's food safety standards. The mercury concentrations of soil samples were negatively correlated with distances from the studied coal-fired power plants, and the mercury contents in lettuce, amaranth, water spinach, cowpea and rice samples were correlated with the mercury contents in soil samples, respectively. Also, the mercury concentrations in vegetable leaves were much higher than those in roots and the mercury content of vegetable leaves decreased significantly after water rinses. Our calculation suggests that probable weekly intake of mercury for local residents, assuming all of their vegetables and grains are from their own farmland, may exceed the toxicologically tolerable values allowed, and therefore long-term consumptions of these contaminated vegetables and grains may pose serious health risks.

  4. A Novel Combination of Methods Developed for Decision Support on Abatement of Mercury in Europe

    Directory of Open Access Journals (Sweden)

    Sundseth K.

    2013-04-01

    Full Text Available There is clear evidence from the global mercury cycle that there is an urgent need for actions to reduce global anthropogenic mercury emissions. A legally- binding global agreement to reduce emissions of mercury is soon in place, meaning that many countries need to take steps to lower their emissions. Identification and assessment of policy options that already are in place as well as setting pollution control objectives and developing effective strategies to meet these objectives, are depending on a decision support tool that allows for identifying current and future environmental problems and to reduce these problems by providing a holistic management approach. Recent scientific advancement allows a more complete picture of the mercury problems and solutions to the problems, which is of outmost interest when it comes to justifying spending resources on the relevant measures. To make sure that resource allocation is favoring human welfare, the economic costs of introducing these measures need to be compared to their economic benefits. The major goal of this study was to provide a novel combination of assessment tools that form a framework for a decision support system towards environmental policy on mercury in Europe. The decision support tool was intended to act as a guideline for policy makers for the purpose of introducing cost- effective abatement of mercury. It was for the EU 27 countries demonstrated that large economic benefits can be achieved globally with reduced mercury emissions in the EU region. The investigated Baseline scenario thus highlighted the importance of full implementation of existing measures and the importance of making further progress in reducing mercury emissions from European sources. Reducing emissions in developing countries may however, be more cost effective, which basically reconfirms the need for a global convention on mercury.

  5. A synthesis of research needs for improving the understanding of atmospheric mercury cycling

    Directory of Open Access Journals (Sweden)

    L. Zhang

    2017-07-01

    Full Text Available This synthesis identifies future research needs in atmospheric mercury science, based on a series of review papers, as well as recent developments in field data collection, modeling analysis, and emission assessments of speciated atmospheric mercury. Research activities are proposed that focus on areas that we consider important. These include refinement of mercury emission estimations, quantification of dry deposition and air–surface exchange, improvement of the treatment of chemical mechanisms in chemical transport models, increase in the accuracy of oxidized mercury measurements, better interpretation of atmospheric mercury chemistry data, and harmonization of network operation. Knowledge gained in these research areas will significantly improve our understanding of atmospheric cycling from local to global scales.

  6. Human exposure to mercury and silver released from dental amalgam restorations.

    Science.gov (United States)

    Skare, I; Engqvist, A

    1994-01-01

    In 35 healthy individuals, the number of amalgam surfaces was related to the emission rate of mercury into the oral cavity and to the excretion rate of mercury by urine. Oral emission ranged up to 125 micrograms Hg/24 h, and urinary excretions ranged from 0.4 to 19 micrograms Hg/24 h. In 10 cases, urinary and fecal excretions of mercury and silver were also measured. Fecal excretions ranged from 1 to 190 micrograms Hg/24 h and from 4 to 97 micrograms Ag/24 h. Except for urinary silver excretion, a high interplay between the variables was exhibited. The worst-case individual showed a fecal mercury excretion amounting to 100 times the mean intake of total Hg from a normal Swedish diet. With regard to a Swedish middle-age individual, the systemic uptake of mercury from amalgam was, on average, predicted to be 12 micrograms Hg/24 h.

  7. Removal of Elemental Mercury from a Gas Stream Facilitated by a Non-Thermal Plasma Device

    Energy Technology Data Exchange (ETDEWEB)

    Charles Mones

    2006-12-01

    Mercury generated from anthropogenic sources presents a difficult environmental problem. In comparison to other toxic metals, mercury has a low vaporization temperature. Mercury and mercury compounds are highly toxic, and organic forms such as methyl mercury can be bio-accumulated. Exposure pathways include inhalation and transport to surface waters. Mercury poisoning can result in both acute and chronic effects. Most commonly, chronic exposure to mercury vapor affects the central nervous system and brain, resulting in neurological damage. The CRE technology employs a series of non-thermal, plasma-jet devices to provide a method for elemental mercury removal from a gas phase by targeting relevant chemical reactions. The technology couples the known chemistry of converting elemental mercury to ionic compounds by mercury-chlorine-oxygen reactions with the generation of highly reactive species in a non-thermal, atmospheric, plasma device. The generation of highly reactive metastable species in a non-thermal plasma device is well known. The introduction of plasma using a jet-injection device provides a means to contact highly reactive species with elemental mercury in a manner to overcome the kinetic and mass-transfer limitations encountered by previous researchers. To demonstrate this technology, WRI has constructed a plasma test facility that includes plasma reactors capable of using up to four plasma jets, flow control instrumentation, an integrated control panel to operate the facility, a mercury generation system that employs a temperature controlled oven and permeation tube, combustible and mercury gas analyzers, and a ductless fume hood designed to capture fugitive mercury emissions. Continental Research and Engineering (CR&E) and Western Research Institute (WRI) successfully demonstrated that non-thermal plasma containing oxygen and chlorine-oxygen reagents could completely convert elemental mercury to an ionic form. These results demonstrate potential the

  8. Bench-scale Kinetics Study of Mercury Reactions in FGD Liquors

    Energy Technology Data Exchange (ETDEWEB)

    Gary Blythe; John Currie; David DeBerry

    2008-03-31

    This document is the final report for Cooperative Agreement DE-FC26-04NT42314, 'Kinetics Study of Mercury Reactions in FGD Liquors'. The project was co-funded by the U.S. DOE National Energy Technology Laboratory and EPRI. The objective of the project has been to determine the mechanisms and kinetics of the aqueous reactions of mercury absorbed by wet flue gas desulfurization (FGD) systems, and develop a kinetics model to predict mercury reactions in wet FGD systems. The model may be used to determine optimum wet FGD design and operating conditions to maximize mercury capture in wet FGD systems. Initially, a series of bench-top, liquid-phase reactor tests were conducted and mercury species concentrations were measured by UV/visible light spectroscopy to determine reactant and byproduct concentrations over time. Other measurement methods, such as atomic absorption, were used to measure concentrations of vapor-phase elemental mercury, that cannot be measured by UV/visible light spectroscopy. Next, a series of bench-scale wet FGD simulation tests were conducted. Because of the significant effects of sulfite concentration on mercury re-emission rates, new methods were developed for operating and controlling the bench-scale FGD experiments. Approximately 140 bench-scale wet FGD tests were conducted and several unusual and pertinent effects of process chemistry on mercury re-emissions were identified and characterized. These data have been used to develop an empirically adjusted, theoretically based kinetics model to predict mercury species reactions in wet FGD systems. The model has been verified in tests conducted with the bench-scale wet FGD system, where both gas-phase and liquid-phase mercury concentrations were measured to determine if the model accurately predicts the tendency for mercury re-emissions. This report presents and discusses results from the initial laboratory kinetics measurements, the bench-scale wet FGD tests, and the kinetics modeling

  9. Mercury's magnetic field and interior

    International Nuclear Information System (INIS)

    Connerney, J.E.P.; Ness, N.F.

    1988-01-01

    The magnetic-field data collected on Mercury by the Mariner-10 spacecraft present substantial evidence for an intrinsic global magnetic field. However, studies of Mercury's thermal evolution show that it is most likely that the inner core region of Mercury solidified or froze early in the planet's history. Thus, the explanation of Mercury's magnetic field in the framework of the traditional planetary dynamo is less than certain

  10. Using semi-continuous, in-situ measurements of nitrous oxide isotopic composition at a suburban site to track emission processes

    Science.gov (United States)

    Harris, Eliza; Henne, Stephan; Christoph, Hüglin; Christoph, Zellweger; Béla, Tuzson; Erkan, Ibraim; Lukas, Emmenegger; Joachim, Mohn

    2017-04-01

    Nitrous oxide (N2O) is a potent greenhouse gas and the strongest ozone-destroying substance emitted this century. The atmospheric N2O mole fraction has been increasing at a rate of 0.2-0.3% per year over the past decades due to anthropogenic emissions; in addition, recent results suggest that the rate of increase is rising - therefore effective mitigation of N2O emissions is a critical point for environmental policy. However, N2O sources are poorly defined and disperse, complicating the development of targeted mitigation strategies. Online isotopic measurements using preconcentration and laser spectroscopy [1,2,3] have great potential to unravel spatial and temporal variations in sources, sinks and chemistry of trace gases such as N2O. Semi-continuous, real-time measurements of N2O isotopic composition (δ18O, site preference [SP = 14N15N16O - 15N14N16O] and δ15Nbulk) were performed at the suburban site of Dübendorf, Switzerland, for 19 months between July 2014 and February 2016. The data precision reached 0.1‰ in the final months, thus the results could clearly identify nocturnal build-up of N2O, with a corresponding decrease in δ18O, SP and δ15Nbulk due to isotopically depleted anthropogenic sources. Daily mean source isotopic composition was calculated by considering the measured and the background mole fraction and isotopic composition. Delta values of the mean emission source were highest in winter, with a seasonal cycle of 12, 8 and 5‰ for δ18O, SP and δ15Nbulk respectively. The chemical and meteorological parameters controlling source isotopic composition were considered using data from the Swiss National Air Pollution Monitoring Network (NABEL) as well as a transport regime cluster analysis. A clear spatial distribution for source isotopic composition was observed for δ18O, as well as a significant relationship with the level of urban pollution, indicating δ18O may be a strong indicator of combustion/industrial vs. agricultural N2O. In contrast

  11. Mercury in Indiana watersheds: retrospective for 2001-2006

    Science.gov (United States)

    Risch, Martin R.; Baker, Nancy T.; Fowler, Kathleen K.; Egler, Amanda L.; Lampe, David C.

    2010-01-01

    Information about total mercury and methylmercury concentrations in water samples and mercury concentrations in fish-tissue samples was summarized for 26 watersheds in Indiana that drain most of the land area of the State. Mercury levels were interpreted with information on streamflow, atmospheric mercury deposition, mercury emissions to the atmosphere, mercury in wastewater, and landscape characteristics. Unfiltered total mercury concentrations in 411 water samples from streams in the 26 watersheds had a median of 2.32 nanograms per liter (ng/L) and a maximum of 28.2 ng/L. When these concentrations were compared to Indiana water-quality criteria for mercury, 5.4 percent exceeded the 12-ng/L chronic-aquatic criterion, 59 percent exceeded the 1.8-ng/L Great Lakes human-health criterion, and 72.5 percent exceeded the 1.3-ng/L Great Lakes wildlife criterion. Mercury concentrations in water were related to streamflow, and the highest mercury concentrations were associated with the highest streamflows. On average, 67 percent of total mercury in streams was in a particulate form, and particulate mercury concentrations were significantly lower downstream from dams than at monitoring stations not affected by dams. Methylmercury is the organic fraction of total mercury and is the form of mercury that accumulates and magnifies in food chains. It is made from inorganic mercury by natural processes under specific conditions. Unfiltered methylmercury concentrations in 411 water samples had a median of 0.10 ng/L and a maximum of 0.66 ng/L. Methylmercury was a median 3.7 percent and maximum 64.8 percent of the total mercury in 252 samples for which methylmercury was reported. The percentages of methylmercury in water samples were significantly higher downstream from dams than at other monitoring stations. Nearly all of the total mercury detected in fish tissue was assumed to be methylmercury. Fish-tissue samples from the 26 watersheds had wet-weight mercury concentrations that

  12. Mercury content of edible mushrooms

    Energy Technology Data Exchange (ETDEWEB)

    Woidich, H.; Pfannhauser, W.

    1975-05-01

    The mercury content of edible fungi is different. Relatively high burdened are Boletus and Agaricus campestris. A minimum of mercury is found in Russula, Agaricus bisporus and Cantharellus cibarius. The possibilities of mercury uptake and the potential cumulation mechanism is discussed. 8 references, 3 tables.

  13. Mercury (Environmental Health Student Portal)

    Science.gov (United States)

    ... Water Waterborne Diseases & Illnesses Water Cycle Water Treatment Mercury The Basics Mercury — sometimes called quicksilver — is a natural metal. It’s ... to breathe it in without knowing it. When mercury combines with other chemical elements, it creates compounds, ...

  14. Fly Ash and Mercury Oxidation/Chlorination Reactions

    Energy Technology Data Exchange (ETDEWEB)

    Sukh Sidhu; Patanjali Varanasi

    2008-12-31

    Mercury is a known pollutant that has detrimental effect on human health and environment. The anthropogenic emissions of mercury account for 10 to 30% of worldwide mercury emissions. There is a need to control/reduce anthropogenic mercury emissions. Many mercury control technologies are available but their effectiveness is dependent on the chemical form of mercury, because different chemical forms of mercury have different physical and chemical properties. Mercury leaves the boiler in its elemental form but goes through various transformations in the post-combustion zone. There is a need to understand how fly ash and flue gas composition affect speciation, partitioning, and reactions of mercury under the full range of post-combustion zone conditions. This knowledge can then be used to predict the chemical transformation of mercury (elemental, oxidized or particulate) in the post combustion zone and thus help with the control of mercury emissions from coal-burning power plants. To accomplish this goal present study was conducted using five coal fly ashes. These ashes were characterized and their catalytic activity was compared under selected reaction conditions in a fixed bed reactor. Based on the results from these fly ash experiments, three key components (carbon, iron oxide and calcium oxide) were chosen. These three components were then used to prepare model fly ashes. Silica/alumina was used as a base for these model fly ashes. One, two or three component model fly ashes were then prepared to investigate mercury transformation reactions. The third set of experiments was performed with CuO and CuCl2 catalysts to further understand the mercury oxidation process. Based on the results of these three studies the key components were predicted for different fly ash compositions under variety of flue gas conditions. A fixed bed reactor system was used to conduct this study. In all the experiments, the inlet concentration of Hg0(g) was maintained at 35 {micro}g/m3 using

  15. Mercury and methyl mercury ratios in caimans (Caiman crocodilus yacare) from the Pantanal area, Brazil.

    Science.gov (United States)

    Vieira, L M; Nunes, V da S; Amaral, M C do A; Oliveira, A C; Hauser-Davis, R A; Campos, R C

    2011-02-01

    The Pantanal region is the largest floodplain area in the world and of great biological importance due to its unique flora and fauna. This area is continuously undergoing increasing anthropogenic threats, and has also experienced mercury contamination associated with gold mining and other anthropogenic activities. Pantanal caimans are top-level predators, and, as such, show great potential to accumulate mercury (Hg) by biomagnification. In this study 79 specimens from four locations in the Pantanal were analyzed for total Hg and methyl mercury (MeHg) by cold vapor atomic absorption spectrometry. Total Hg contents ranged from 0.02 to 0.36 µg g(-1) (ww), and most specimens presented MeHg ratios above 70%. One of the sites, impacted by anthropogenic activities, presented significantly higher total Hg in comparison to three less impacted sites, supporting the hypothesis that caimans can, in fact, be considered effective bioindicators of ecosystem health.

  16. A Review of Mercury Exposure and Health of Dental Personnel

    Directory of Open Access Journals (Sweden)

    Natasha Nagpal

    2017-03-01

    Full Text Available Considerable effort has been made to address the issue of occupational health and environmental exposure to mercury. This review reports on the current literature of mercury exposure and health impacts on dental personnel. Citations were searched using four comprehensive electronic databases for articles published between 2002 and 2015. All original articles that evaluated an association between the use of dental amalgam and occupational mercury exposure in dental personnel were included. Fifteen publications from nine different countries met the selection criteria. The design and quality of the studies showed significant variation, particularly in the choice of biomarkers as an indicator of mercury exposure. In several countries, dental personnel had higher mercury levels in biological fluids and tissues than in control groups; some work practices increased mercury exposure but the exposure levels remained below recommended guidelines. Dental personnel reported more health conditions, often involving the central nervous system, than the control groups. Clinical symptoms reported by dental professionals may be associated with low-level, long-term exposure to occupational mercury, but may also be due to the effects of aging, occupational overuse, and stress. It is important that dental personnel, researchers, and educators continue to encourage and monitor good work practices by dental professionals.

  17. Sensing Mercury for Biomedical and Environmental Monitoring

    Directory of Open Access Journals (Sweden)

    Julia Xiaojun Zhao

    2009-07-01

    Full Text Available Mercury is a very toxic element that is widely spread in the atmosphere, lithosphere, and surface water. Concentrated mercury poses serious problems to human health, as bioaccumulation of mercury within the brain and kidneys ultimately leads to neurological diseases. To control mercury pollution and reduce mercury damage to human health, sensitive determination of mercury is important. This article summarizes some current sensors for the determination of both abiotic and biotic mercury. A wide array of sensors for monitoring mercury is described, including biosensors and chemical sensors, while piezoelectric and microcantilever sensors are also described. Additionally, newly developed nanomaterials offer great potential for fabricating novel mercury sensors. Some of the functional fluorescent nanosensors for the determination of mercury are covered. Afterwards, the in vivo determination of mercury and the characterization of different forms of mercury are discussed. Finally, the future direction for mercury detection is outlined, suggesting that nanomaterials may provide revolutionary tools in biomedical and environmental monitoring of mercury.

  18. Enhanced Control of Mercury and other HAPs by Innovative Modifications to Wet FGD Processes

    International Nuclear Information System (INIS)

    Hargrove, O.W.; Carey, T.R.; Richardson, C.F.; Skarupa, R.C.; Meserole, F.B.; Rhudy, R.G.; Brown, Thomas D.

    1997-01-01

    The overall objective of this project was to learn more about controlling emissions of hazardous air pollutants (HAPs) from coal-fired power plants that are equipped with wet flue gas desulfurization (FGD) systems. The project was included by FETC as a Phase I project in its Mega-PRDA program. Phase I of this project focused on three research areas. These areas in order of priority were: (1) Catalytic oxidation of vapor-phase elemental mercury; (2) Enhanced particulate-phase HAPs removal by electrostatic charging of liquid droplets; and (3) Enhanced mercury removal by addition of additives to FGD process liquor. Mercury can exist in two forms in utility flue gas--as elemental mercury and as oxidized mercury (predominant form believed to be HgCl 2 ). Previous test results have shown that wet scrubbers effectively remove the oxidized mercury from the gas but are ineffective in removing elemental mercury. Recent improvements in mercury speciation techniques confirm this finding. Catalytic oxidation of vapor-phase elemental mercury is of interest in cases where a wet scrubber exists or is planned for SO 2 control. If a loW--cost process could be developed to oxidize all of the elemental mercury in the flue gas, then the maximum achievable mercury removal across the existing or planned wet scrubber would increase. Other approaches for improving control of HAPs included a method for improving particulate removal across the FGD process and the use of additives to increase mercury solubility. This paper discusses results related only to catalytic oxidation of elemental mercury

  19. Source identification and mass balance studies of mercury in Lake An-dong, S. Korea

    Science.gov (United States)

    Han, J.; Byeon, M.; Yoon, J.; Park, J.; Lee, M.; Huh, I.; Na, E.; Chung, D.; Shin, S.; Kim, Y.

    2009-12-01

    In this study, mercury and methylmercury were measured in atmospheric, tributary, open-lake water column, sediment, planktons and fish samples in the catchments area of Lake An-dong, S. Korea. Lake An-dong, an artificial freshwater lake is located on the upstream of River Nak-dong. It has 51.5 km2 of open surface water and 1.33 year of hydraulic residence time. It is a source of drinking water for 0.3 million S. Koreans. Recently, the possibilities of its mercury contamination became an issue since current studies showed that the lake had much higher mercury level in sediment and certain freshwater fish species than any other lakes in S. Korea. This catchments area has the possibilities of historical mercury pollution by the location of more than 50 abandoned gold mines and Young-poong zinc smelter. The objective of this study was to develop a mercury mass balance and identify possible mercury sources in the lake. The results of this study are thus expected to offer valuable insights for the sources of mercury loading through the watershed. In order to estimate the mercury flux, TGM, RGM and particulate mercury were measured using TEKRAN 2537 at the five sites surrounding Lake An-dong from May, 2009 with wet and dry deposition. The fate and transport of mercury in water body were predicted by using EFDC (Environmental Dynamic Fluid Code) and Mercury module in WASP7 (Water quality analysis program) after subsequent distribution into water body, sediments, followed by bioaccumulation and ultimate uptake by humans. The mercury mass balance in Young-poong zinc smelter was also pre-estimated by measuring mercury content in zinc ores, emission gases, sludge, wastewater and products.

  20. Water displacement mercury pump

    Science.gov (United States)

    Nielsen, M.G.

    1984-04-20

    A water displacement mercury pump has a fluid inlet conduit and diffuser, a valve, a pressure cannister, and a fluid outlet conduit. The valve has a valve head which seats in an opening in the cannister. The entire assembly is readily insertable into a process vessel which produces mercury as a product. As the mercury settles, it flows into the opening in the cannister displacing lighter material. When the valve is in a closed position, the pressure cannister is sealed except for the fluid inlet conduit and the fluid outlet conduit. Introduction of a lighter fluid into the cannister will act to displace a heavier fluid from the cannister via the fluid outlet conduit. The entire pump assembly penetrates only a top wall of the process vessel, and not the sides or the bottom wall of the process vessel. This insures a leak-proof environment and is especially suitable for processing of hazardous materials.

  1. Benefits of European climate policies for mercury air pollution

    NARCIS (Netherlands)

    Rafaj, P.; Cofala, J.; Kuenen, J.; Wyrwa, A.; Zyśk, J.

    2014-01-01

    This paper presents the methodology and results of impact assessment of renewable energy policies on atmospheric emissions of mercury in Europe. The modeling exercise described here involves an interaction of several models. First, a set of energy scenarios has been developed with the REMix

  2. Mercury speciation in pulverized fuel co-combustion and gasification

    NARCIS (Netherlands)

    Sable, S.P.

    2007-01-01

    Coal based power generation is a significant source of mercury emissions to the atmosphere and this has attracted huge attention in the past decade. Recently, the concerns regarding global warming and need for new energy resources introduced the concept of cofiring of biomass and waste as secondary

  3. Pilot Testing of WRI'S Novel Mercury Control Technology by Pre-Combustion Thermal Treatment of Coal

    Energy Technology Data Exchange (ETDEWEB)

    Alan Bland; Jesse Newcomer; Kumar Sellakumar

    2008-08-17

    The challenges to the coal-fired power industry continue to focus on the emission control technologies, such as mercury, and plant efficiency improvements. An alternate approach to post-combustion control of mercury, while improving plant efficiency deals with Western Research Institute's (WRI)'s patented pre-combustion mercury removal and coal upgrading technology. WRI was awarded under the DOE's Phase III Mercury program, to evaluate the effectiveness of WRI's novel thermal pretreatment process to achieve >50% mercury removal, and at costs of <$30,000/lb of Hg removed. WRI has teamed with Etaa Energy, Energy and Environmental Research Center (EERC), Foster Wheeler North America Corp. (FWNA), and Washington Division of URS (WD-URS), and with project co-sponsors including Electric Power Research Institute (EPRI), Southern Company, Basin Electric Power Cooperative (BEPC), Montana-Dakota Utilities (MDU), North Dakota Industrial Commission (NDIC), Detroit Edison (DTE), and SaskPower to undertake this evaluation. The technical objectives of the project were structured in two phases: Phase I--coal selection and characterization, and bench-and PDU-scale WRI process testing and; and Phase II--pilot-scale pc combustion testing, design of an integrated boiler commercial configuration, its impacts on the boiler performance and the economics of the technology related to market applications. This report covers the results of the Phase I testing. The conclusion of the Phase I testing was that the WRI process is a technically viable technology for (1) removing essentially all of the moisture from low rank coals, thereby raising the heating value of the coal by about 30% for subbituminous coals and up to 40% for lignite coals, and (2) for removing volatile trace mercury species (up to 89%) from the coal prior to combustion. The results established that the process meets the goals of DOE of removing <50% of the mercury from the coals by pre-combustion methods

  4. An emissions management framework for the Alberta electricity sector report to stakeholders

    International Nuclear Information System (INIS)

    2003-11-01

    This document presents the Clean Air Strategic Alliance's response to a request made by the Alberta Minister of the Environment in January 2002 to develop an approach for managing air emissions from the electricity sector. Significant reductions over time in four priority air emissions are expected from the implementation of the proposed framework. The four priority pollutants include mercury, sulphur dioxide, nitrogen oxides, and primary particulate matter. The proposed framework calls for standards for new units, requirements for existing units, a five-year review, the use of renewable and alternative energy, energy efficiency and conservation, continuous improvement, monitoring, and transparency. Alberta would then become a leader in air quality management in North America and benefit from achieving a sustainable emissions management system resulting in environmental improvement. All parties would benefit from long term regulatory certainty. Management tools would include an emission trading system, and provide flexibility in reducing emissions. 11 tabs., 19 figs

  5. Remediation of mercury-polluted soils using artificial wetlands.

    Science.gov (United States)

    García-Mercadoa, Héctor Daniel; Fernándezb, Georgina; Garzón-Zúñigac, Marco Antonio; Durán-Domínguez-de-Bazúaa, María Del Carmen

    2017-01-02

    Mexico's mercury mining industry is important for economic development, but has unfortunately contaminated soils due to open-air disposal. This case was seen at two sites in the municipality of Pinal de Amoles, State of Queretaro, Mexico. This paper presents an evaluation of mercury dynamics and biogeochemistry in two soils (mining waste soil) using ex-situ wetlands over 36 weeks. In soils sampled in two former mines of Pinal de Amoles, initial mercury concentrations were 424 ± 29 and 433 ± 12 mg kg -1 in La Lorena and San Jose, former mines, respectively. Typha latifolia and Phragmites australis were used and 20 reactors were constructed (with and without plants). The reactors were weekly amended with a nutrient solution (NPK), for each plant, at a pH of 5.0. For remediation using soils from San Jose 70-78% of mercury was removed in T. latifolia reactors and 76-82% in P. australis reactors, and for remediation of soils from La Lorena, mercury content was reduced by 55-71% using T. latifolia and 58-66% in P. australis reactors. Mercury emissions into the atmosphere were estimated to be 2-4 mg m -2 h -1 for both soils.

  6. Mercury distribution characteristics in primary manganese smelting plants.

    Science.gov (United States)

    Back, Seung-Ki; Sung, Jin-Ho; Moon, Young-Hoon; Kim, Young-Hee; Seok, Kwang-Seol; Song, Geum-Ju; Seo, Yong-Chil

    2017-08-01

    The mercury (Hg) distribution characteristics were investigated in three primary manganese smelting plants in Korea for the assessment of anthropogenic Hg released. Input and output materials were sampled from each process, and Hg concentrations in the samples were analyzed. Among the input materials, the most mercury was found in the manganese ore (83.1-99.7%) and mercury was mainly released through fly ash or off gas, depending on the condition of off gas cleaning system. As off gas temperature decreases, proportion and concentration of emitted gaseous elemental mercury (Hg 0 ) in off gas decreases. Based on mass balance study from these three plants and national manganese production data, the total amount of mercury released from those Korean plants was estimated to 644 kg/yr. About half of it was emitted into the air while the rest was released to waste as fly ash. With the results of this investigation, national inventory for Hg emission and release could be updated for the response to Minamata Convention on Mercury. Copyright © 2017. Published by Elsevier Ltd.

  7. The analysis of mercury content in coals and ashes

    Directory of Open Access Journals (Sweden)

    Kasprzyk Marta

    2017-01-01

    Full Text Available It is well known that mercury that enters the atmosphere is a serious threat to the natural environment. From the available literature, it can be stated that fossil fuels are among the main carriers of this fuel. The question arises whether it is the right approach. While the enrichment of bituminous coal produces limited amounts of mercury, they are being released into the atmosphere as a result of the combustion of coal. The situation is similar in the case of biomass, which releases large amounts of mercury into the atmosphere when subjected to the combustion process. While bituminous coal is the carrier of mercury, the application of currently known technology, rational production and the use of fossil fuels make it possible to maximally minimize mercury emissions into the atmosphere. This study evaluated the mercury content in the ashes resulting from the combustion of bituminous coal subjected to the enrichment process. The samples were collected from ten mines located in the Polish part of the Upper Silesian Coal Basin (USCB. In total, thirty coal samples and thirty products of the combustion process were examined. All sixty samples were subjected to physicochemical analysis, including: moisture content, ash content, sulfur content, carbon content, and Gross Calorific Value.

  8. The Mercury Problem in Artisanal and Small-Scale Gold Mining.

    Science.gov (United States)

    Esdaile, Louisa J; Chalker, Justin M

    2018-01-03

    Mercury-dependent artisanal and small-scale gold mining (ASGM) is the largest source of mercury pollution on Earth. In this practice, elemental mercury is used to extract gold from ore as an amalgam. The amalgam is typically isolated by hand and then heated-often with a torch or over a stove-to distill the mercury and isolate the gold. Mercury release from tailings and vaporized mercury exceed 1000 tonnes each year from ASGM. The health effects on the miners are dire, with inhaled mercury leading to neurological damage and other health issues. The communities near these mines are also affected due to mercury contamination of water and soil and subsequent accumulation in food staples, such as fish-a major source of dietary protein in many ASGM regions. The risks to children are also substantial, with mercury emissions from ASGM resulting in both physical and mental disabilities and compromised development. Between 10 and 19 million people use mercury to mine for gold in more than 70 countries, making mercury pollution from ASGM a global issue. With the Minamata Convention on Mercury entering force this year, there is political motivation to help overcome the problem of mercury in ASGM. In this effort, chemists can play a central role. Here, the problem of mercury in ASGM is reviewed with a discussion on how the chemistry community can contribute solutions. Introducing portable and low-cost mercury sensors, inexpensive and scalable remediation technologies, novel methods to prevent mercury uptake in fish and food crops, and efficient and easy-to-use mercury-free mining techniques are all ways in which the chemistry community can help. To meet these challenges, it is critical that new technologies or techniques are low-cost and adaptable to the remote and under-resourced areas in which ASGM is most common. The problem of mercury pollution in ASGM is inherently a chemistry problem. We therefore encourage the chemistry community to consider and address this issue that

  9. Toward the next generation of air quality monitoring: Mercury

    Science.gov (United States)

    Pirrone, Nicola; Aas, Wenche; Cinnirella, Sergio; Ebinghaus, Ralf; Hedgecock, Ian M.; Pacyna, Jozef; Sprovieri, Francesca; Sunderland, Elsie M.

    2013-12-01

    Mercury is a global pollutant that is ubiquitous in the environment. Enrichment of mercury in the biosphere as the result of human activities and subsequent production of methylmercury (MeHg) has resulted in elevated concentrations in fish, wildlife and marine mammals globally. Elemental mercury (Hg0) is the most common form of mercury in the atmosphere, and the form that is most readily transported long distances from its emission source. Most mercury deposition from the atmosphere is in the highly soluble, oxidised inorganic form HgII. Thus, understanding atmospheric transport and oxidant distribution is essential for understanding mercury inputs to ecosystems. Methylmercury (MeHg) is the most toxic form of mercury that accumulates in aquatic food web and can cause a variety of negative health effects such as long-term IQ deficits and cardiovascular impairment in exposed individuals. Humans are predominately exposed to MeHg by consuming fish. Hg0 emitted from anthropogenic sources has a long (6 months-1 year) atmospheric residence time allowing it to be transported long distances in the atmosphere. It is eventually oxidised to the highly soluble HgII (likely by atomic Br and/or OH/O3) and rapidly deposited with precipitation. Some of the mercury deposited to terrestrial and marine ecosystems is converted to MeHg, which is the only form that bioaccumulates in aquatic food webs. Recent studies suggest that there is a first-order relationship between the supply of inorganic mercury to ecosystems and production of MeHg, thus implying that declines in deposition will translate directly into reduced concentrations in biota and human exposures. However, one of the major uncertainties in this cycle is the time scale required for these changes to take place and this is known to vary from years to centuries across different environmental compartments depending on their physical and biogeochemical attributes. Thus, a key challenge in the case of mercury pollution is

  10. Inference of strata separation and gas emission paths in longwall overburden using continuous wavelet transform of well logs and geostatistical simulation

    Science.gov (United States)

    Karacan, C. Özgen; Olea, Ricardo A.

    2014-06-01

    Prediction of potential methane emission pathways from various sources into active mine workings or sealed gobs from longwall overburden is important for controlling methane and for improving mining safety. The aim of this paper is to infer strata separation intervals and thus gas emission pathways from standard well log data. The proposed technique was applied to well logs acquired through the Mary Lee/Blue Creek coal seam of the Upper Pottsville Formation in the Black Warrior Basin, Alabama, using well logs from a series of boreholes aligned along a nearly linear profile. For this purpose, continuous wavelet transform (CWT) of digitized gamma well logs was performed by using Mexican hat and Morlet, as the mother wavelets, to identify potential discontinuities in the signal. Pointwise Hölder exponents (PHE) of gamma logs were also computed using the generalized quadratic variations (GQV) method to identify the location and strength of singularities of well log signals as a complementary analysis. PHEs and wavelet coefficients were analyzed to find the locations of singularities along the logs. Using the well logs in this study, locations of predicted singularities were used as indicators in single normal equation simulation (SNESIM) to generate equi-probable realizations of potential strata separation intervals. Horizontal and vertical variograms of realizations were then analyzed and compared with those of indicator data and training image (TI) data using the Kruskal-Wallis test. A sum of squared differences was employed to select the most probable realization representing the locations of potential strata separations and methane flow paths. Results indicated that singularities located in well log signals reliably correlated with strata transitions or discontinuities within the strata. Geostatistical simulation of these discontinuities provided information about the location and extents of the continuous channels that may form during mining. If there is a gas

  11. Low-Cost Options for Moderate Levels of Mercury Control

    Energy Technology Data Exchange (ETDEWEB)

    Sharon Sjostrom

    2006-03-31

    On March 15, 2005, EPA issued the Clean Air Mercury Rule, requiring phased-in reductions of mercury emissions from electric power generators. ADA-ES, Inc., with support from DOE/NETL and industry partners, is conducting evaluations of EPRI's TOXECON II{trademark} process and of high-temperature reagents and sorbents to determine the capabilities of sorbent/reagent injection, including activated carbon, for mercury control on different coals and air emissions control equipment configurations. DOE/NETL targets for total mercury removal are {ge}55% (lignite), {ge}65% (subbituminous), and {ge}80% (bituminous). Based on work done to date at various scales, meeting the removal targets appears feasible. However, work needs to progress to more thoroughly document and test these promising technologies at full scale. This is the final site report for tests conducted at MidAmerican's Louisa Station, one of three sites evaluated in this DOE/NETL program. The other two sites in the program are MidAmerican's Council Bluff Station and Entergy's Independence Station. MidAmerican's Louisa Station burns Powder River Basin (PRB) coal and employs hot-side electrostatic precipitators with flue gas conditioning for particulate control. This part of the testing program evaluated the effect of reagents used in the existing flue gas conditioning on mercury removal.

  12. Mercury's Surface Magnetic Field Determined from Proton-Reflection Magnetometry

    Science.gov (United States)

    Winslow, Reka M.; Johnson, Catherine L.; Anderson, Brian J.; Gershman, Daniel J.; Raines, Jim M.; Lillis, Robert J.; Korth, Haje; Slavin, James A.; Solomon, Sean C.; Zurbuchen, Thomas H.; hide

    2014-01-01

    Solar wind protons observed by the MESSENGER spacecraft in orbit about Mercury exhibit signatures of precipitation loss to Mercury's surface. We apply proton-reflection magnetometry to sense Mercury's surface magnetic field intensity in the planet's northern and southern hemispheres. The results are consistent with a dipole field offset to the north and show that the technique may be used to resolve regional-scale fields at the surface. The proton loss cones indicate persistent ion precipitation to the surface in the northern magnetospheric cusp region and in the southern hemisphere at low nightside latitudes. The latter observation implies that most of the surface in Mercury's southern hemisphere is continuously bombarded by plasma, in contrast with the premise that the global magnetic field largely protects the planetary surface from the solar wind.

  13. FIELD TEST PROGRAM TO DEVELOP COMPREHENSIVE DESIGN, OPERATING, AND COST DATA FOR MERCURY CONTROL SYSTEMS

    Energy Technology Data Exchange (ETDEWEB)

    Michael D. Durham

    2005-03-17

    that were varied included SO{sub 3} conditioning on/off, injection concentrations, and distribution spray patterns. The original test plan called for parametric testing of NORIT FGD carbon at 1, 3, and 10 lbs/MMacf. These injection concentrations were estimated based on results from the Pleasant Prairie tests that showed no additional mercury removal when injection concentrations were increased above 10 lbs/MMacf. The Brayton Point parametric test data indicated that higher injection concentrations would achieve higher removal efficiencies and should be tested. The test plan was altered to include testing at 20 lbs/MMacf. The first test at this higher rate showed very high removal across the second ESP (>80%). Unlike the ''ceiling'' phenomenon witnessed at Pleasant Prairie, increasing sorbent injection concentration resulted in further capture of vapor-phase mercury. The final phase of field-testing was a 10-day period of continuous injection of NORIT FGD carbon. During the first five days, the injection concentration was held at 10 lbs/MMacf, followed by nominally five days of testing at an injection concentration of 20 lbs/MMacf. The mercury removal, as measured by the semi-continuous emission monitors (S-CEM), varied between 78% and 95% during the 10 lbs/MMacf period and increased to >97% when the injection concentration was increased to 20 lbs/MMacf. During the long-term testing period, mercury measurements following EPA's draft Ontario Hydro method were conducted by TRC Environmental Corporation at both 10 and 20 lbs/MMacf test conditions. The Ontario Hydro data showed that the particulate mercury removal was similar between the two conditions of 10 or 20 lbs/MMacf and removal efficiencies were greater than 99%. Elemental mercury was not detected in any samples, so no conclusions as to its removal can be drawn. Removal of oxidized mercury, on the other hand, increased from 68% to 93% with the higher injection concentration. These removal

  14. Behavior of mercury in the formic acid vent condenser. Interim report

    International Nuclear Information System (INIS)

    Zamecnik, J.R.

    1994-01-01

    (This report relates to the Defense Waste Processing Facility.) The concentrations of mercury at the FAFC inlet and exit were measured during the BL1 and PX6 runs of the Integrated DWPF Melter System (IDMS) with the HEME bypassed and without the ammonia scrubber. The results show that mercury concentrations of approximately 2.6-12.7 (mean = 6.2) times saturation occur at the FAFC exit. The concentration of mercury at the SRAT condenser exit was found to be 10 times the saturation value. FAVC exit mercury concentrations of 6.2 times saturation would result in DWPF emitting up to 438 lb/yr of mercury at 100 percent attainments, which is in excess of the permit limit of 175 lb/yr. However, operation of the FAVC with the HEME should reduce the mercury emissions. The addition of the ammonia scrubbers should also reduce the mercury emissions since the nitric acid used to scrub ammonia should also scrub mercury

  15. Method and apparatus for sampling atmospheric mercury

    Science.gov (United States)

    Trujillo, Patricio E.; Campbell, Evan E.; Eutsler, Bernard C.

    1976-01-20

    A method of simultaneously sampling particulate mercury, organic mercurial vapors, and metallic mercury vapor in the working and occupational environment and determining the amount of mercury derived from each such source in the sampled air. A known volume of air is passed through a sampling tube containing a filter for particulate mercury collection, a first adsorber for the selective adsorption of organic mercurial vapors, and a second adsorber for the adsorption of metallic mercury vapor. Carbon black molecular sieves are particularly useful as the selective adsorber for organic mercurial vapors. The amount of mercury adsorbed or collected in each section of the sampling tube is readily quantitatively determined by flameless atomic absorption spectrophotometry.

  16. Fate of Mercury in Synthetic Gypsum Used for Wallboard Production

    Energy Technology Data Exchange (ETDEWEB)

    Jessica Sanderson

    2007-12-31

    This report presents and discusses results from the project 'Fate of Mercury in Synthetic Gypsum Used for Wallboard Production', performed at five different full-scale commercial wallboard plants. Synthetic gypsum produced by wet flue gas desulfurization (FGD) systems on coal-fired power plants is commonly used in the manufacture of wallboard. This practice has long benefited the environment by recycling the FGD gypsum byproduct, which is becoming available in increasing quantities, decreasing the need to landfill this material, and increasing the sustainable design of the wallboard product. However, new concerns have arisen as recent