Mechanical-biological waste treatment and anaerobic processes. 59. information meeting, Neuwied, October 1999; Mechanisch-biologische Restabfallbehandlung und Anaerobverfahren. 59. Informationsgespraech in Neuwied im Oktober 1999

Energy Technology Data Exchange (ETDEWEB)

Hangen, H.O.; Euler, H.; Leonhardt, H.W. [comps.

1999-10-01

This proceedings volume discusses the specifications for and cost of mechanical-biological waste treatment, the optimisation of economic efficiency and pollutant emissons, the combination of mechanical-biological and thermal waste treatment processes, the value of mechanical-biological waste treatment, waste management concepts, process engineering and practical experience, and the eco-balance of the process. [German] Themen dieses Proceedingsbandes sind: Anforderungen und Kosten der mechanisch-biologischen Abfallbehandlung; Optimierung der Wirtschaftlichkeit und Emissionssituation; Kombination von mechanisch-biologischer und thermischer Muellbehandlung; Bewertung der mechanisch-biologischen Abfallbehandlung, Abfallwirtschaftskonzepte, Verfahrenstechnik und Betriebserfahrungen; Oekobilanz. (SR)

Experimental and modelling studies on a laboratory scale anaerobic bioreactor treating mechanically biologically treated municipal solid waste.

Science.gov (United States)

Lakshmikanthan, P; Sughosh, P; White, James; Sivakumar Babu, G L

2017-07-01

The performance of an anaerobic bioreactor in treating mechanically biologically treated municipal solid waste was investigated using experimental and modelling techniques. The key parameters measured during the experimental test period included the gas yield, leachate generation and settlement under applied load. Modelling of the anaerobic bioreactor was carried out using the University of Southampton landfill degradation and transport model. The model was used to simulate the actual gas production and settlement. A sensitivity analysis showed that the most influential model parameters are the monod growth rate and moisture. In this case, pH had no effect on the total gas production and waste settlement, and only a small variation in the gas production was observed when the heat transfer coefficient of waste was varied from 20 to 100 kJ/(m d K) -1 . The anaerobic bioreactor contained 1.9 kg (dry) of mechanically biologically treated waste producing 10 L of landfill gas over 125 days.

Residues from waste incineration. Final report. Rev. ed.

Energy Technology Data Exchange (ETDEWEB)

Astrup, T.; Juul Pedersen, A.; Hyks, J.; Frandsen, F.J.

2010-04-15

The overall objective of the project was to improve the understanding of the formation and characteristics of residues from waste incineration. This was done focusing on the importance of the waste input and the operational conditions of the furnace. Data and results obtained from the project have been discussed in this report according to the following three overall parts: i) mass flows and element distribution, ii) flue gas/particle partitioning and corrosion/deposition aspects, and iii) residue leaching. This has been done with the intent of structuring the discussion while tacitly acknowledging that these aspects are interrelated and cannot be separated. Overall, it was found that the waste input composition had significant impact of the characteristics of the generated residues. A similar correlation between operational conditions and residue characteristics could not be observed. Consequently, the project recommend that optimization of residue quality should focus on controlling the waste input composition. The project results showed that including specific waste materials (and thereby also excluding the same materials) may have significant effects on the residue composition, residue leaching, aerosol and deposit formation.It is specifically recommended to minimize Cl in the input waste. Based on the project results, it was found that a significant potential for optimization of waste incineration exist. (Author)

Mixed-waste treatment -- What about the residuals?

International Nuclear Information System (INIS)

Carlson, T.; Carpenter, C.; Cummins, L.; Haas, P.; MacInnis, J.; Maxwell, C.

1993-01-01

Incineration currently is the best demonstrated available technology for the large inventory of U.S. Department of Energy (DOE) mixed waste. However, molten salt oxidation (MSO) is an alternative thermal treatment technology with the potential to treat a number of these wastes. Of concern for both technologies is the final waste forms, or residuals, that are generated by the treatment process. An evaluation of the two technologies focuses on 10 existing DOE waste streams and current hazardous-waste regulations, specifically for the delisting of ''derived-from'' residuals. Major findings include that final disposal options are more significantly impacted by the type of waste treated and existing regulations than by the type of treatment technology; typical DOE waste streams are not good candidates for delisting; and mass balance calculations indicate that MSO and incineration generate similar quantities (dry) and types of residuals

9 CFR 311.39 - Biological residues.

Science.gov (United States)

2010-01-01

... 9 Animals and Animal Products 2 2010-01-01 2010-01-01 false Biological residues. 311.39 Section... Biological residues. Carcasses, organs, or other parts of carcasses of livestock shall be condemned if it is determined that they are adulterated because of the presence of any biological residues. ...

Immobilization in ceramic waste forms of the residues from treatment of mixed wastes

International Nuclear Information System (INIS)

Oversby, V.M.; van Konynenburg, R.A.; Glassley, W.E.; Curtis, P.G.

1993-11-01

The Environmental Restoration and Waste Management Applied Technology Program at LLNL is developing a Mixed Waste Management Facility to demonstrate treatment technologies that provide an alternative to incineration. As part of that program, we are developing final waste forms using ceramic processing methods for the immobilization of the treatment process residues. The ceramic phase assemblages are based on using Synroc D as a starting point and varying the phase assemblage to accommodate the differences in chemistry between the treatment process residues and the defense waste for which Synroc D was developed. Two basic formulations are used, one for low ash residues resulting from treatment of organic materials contaminated with RCRA metals, and one for high ash residues generated from the treatment of plastics and paper products. Treatment process residues are mixed with ceramic precursor materials, dried, calcined, formed into pellets at room temperature, and sintered at 1150 to 1200 degrees C to produce the final waste form. This paper discusses the chemical composition of the waste streams and waste forms, the phase assemblages that serve as hosts for inorganic waste elements, and the changes in waste form characteristics as a function of variation in process parameters

Carbon speciation in ash, residual waste and contaminated soil by thermal and chemical analyses.

Science.gov (United States)

Kumpiene, Jurate; Robinson, Ryan; Brännvall, Evelina; Nordmark, Désirée; Bjurström, Henrik; Andreas, Lale; Lagerkvist, Anders; Ecke, Holger

2011-01-01

Carbon in waste can occur as inorganic (IC), organic (OC) and elemental carbon (EC) each having distinct chemical properties and possible environmental effects. In this study, carbon speciation was performed using thermogravimetric analysis (TGA), chemical degradation tests and the standard total organic carbon (TOC) measurement procedures in three types of waste materials (bottom ash, residual waste and contaminated soil). Over 50% of the total carbon (TC) in all studied materials (72% in ash and residual waste, and 59% in soil) was biologically non-reactive or EC as determined by thermogravimetric analyses. The speciation of TOC by chemical degradation also showed a presence of a non-degradable C fraction in all materials (60% of TOC in ash, 30% in residual waste and 13% in soil), though in smaller amounts than those determined by TGA. In principle, chemical degradation method can give an indication of the presence of potentially inert C in various waste materials, while TGA is a more precise technique for C speciation, given that waste-specific method adjustments are made. The standard TOC measurement yields exaggerated estimates of organic carbon and may therefore overestimate the potential environmental impacts (e.g. landfill gas generation) of waste materials in a landfill environment. Copyright © 2010 Elsevier Ltd. All rights reserved.

Landfilling of waste incineration residues

DEFF Research Database (Denmark)

Christensen, Thomas Højlund; Astrup, Thomas; Cai, Zuansi

2002-01-01

Residues from waste incineration are bottom ashes and air-pollution-control (APC) residues including fly ashes. The leaching of heavy metals and salts from the ashes is substantial and a wide spectrum of leaching tests and corresponding criteria have been introduced to regulate the landfilling...

Bituminization of biologically harmful wastes

International Nuclear Information System (INIS)

Freund, M.; Magyar, M.; Mozes, G.; Csikos, R.; Kristof, M.; Toth, L.; Hima, G.

1977-01-01

The invention claims the bitumenization of biologically harmful wastes, such as industrial wastes containing radioactive materials. These wastes containing water are transported from sludge basins, this either by gravity or by mechanical stirrino. into a suitably adapted absorption zone or to several parallel zones filled with bitumen heated to 100 to 250 degC. An inert gas is forced into the system foaming the zone contents. The foam phase is decomposed by the action of heat while water is evaporated and condensed. Bitumen containing dry matter of the radioactive wastes is discharged from the bottom part of the absorption zone and stored in a tank. (Kr)

Energy implications of mechanical and mechanical–biological treatment compared to direct waste-to-energy

International Nuclear Information System (INIS)

Cimpan, Ciprian; Wenzel, Henrik

2013-01-01

Highlights: • Compared systems achieve primary energy savings between 34 and 140 MJ primary /100 MJ input waste. • Savings magnitude is foremost determined by chosen primary energy and materials production. • Energy consumption and process losses can be upset by increased technology efficiency. • Material recovery accounts for significant shares of primary energy savings. • Direct waste-to-energy is highly efficient if cogeneration (CHP) is possible. - Abstract: Primary energy savings potential is used to compare five residual municipal solid waste treatment systems, including configurations with mechanical (MT) and mechanical–biological (MBT) pre-treatment, which produce waste-derived fuels (RDF and SRF), biogas and/or recover additional materials for recycling, alongside a system based on conventional mass burn waste-to-energy and ash treatment. To examine the magnitude of potential savings we consider two energy efficiency levels (state-of-the-art and best available technology), the inclusion/exclusion of heat recovery (CHP vs. PP) and three different background end-use energy production systems (coal condensing electricity and natural gas heat, Nordic electricity mix and natural gas heat, and coal CHP energy quality allocation). The systems achieved net primary energy savings in a range between 34 and 140 MJ primary /100 MJ input waste , in the different scenario settings. The energy footprint of transportation needs, pre-treatment and reprocessing of recyclable materials was 3–9.5%, 1–18% and 1–8% respectively, relative to total energy savings. Mass combustion WtE achieved the highest savings in scenarios with CHP production, nonetheless, MBT-based systems had similarly high performance if SRF streams were co-combusted with coal. When RDF and SRF was only used in dedicated WtE plants, MBT-based systems totalled lower savings due to inherent system losses and additional energy costs. In scenarios without heat recovery, the biodrying MBS

Energy implications of mechanical and mechanical–biological treatment compared to direct waste-to-energy

Energy Technology Data Exchange (ETDEWEB)

Cimpan, Ciprian, E-mail: cic@kbm.sdu.dk; Wenzel, Henrik

2013-07-15

Highlights: • Compared systems achieve primary energy savings between 34 and 140 MJ{sub primary}/100 MJ{sub input} {sub waste.} • Savings magnitude is foremost determined by chosen primary energy and materials production. • Energy consumption and process losses can be upset by increased technology efficiency. • Material recovery accounts for significant shares of primary energy savings. • Direct waste-to-energy is highly efficient if cogeneration (CHP) is possible. - Abstract: Primary energy savings potential is used to compare five residual municipal solid waste treatment systems, including configurations with mechanical (MT) and mechanical–biological (MBT) pre-treatment, which produce waste-derived fuels (RDF and SRF), biogas and/or recover additional materials for recycling, alongside a system based on conventional mass burn waste-to-energy and ash treatment. To examine the magnitude of potential savings we consider two energy efficiency levels (state-of-the-art and best available technology), the inclusion/exclusion of heat recovery (CHP vs. PP) and three different background end-use energy production systems (coal condensing electricity and natural gas heat, Nordic electricity mix and natural gas heat, and coal CHP energy quality allocation). The systems achieved net primary energy savings in a range between 34 and 140 MJ{sub primary}/100 MJ{sub input} {sub waste}, in the different scenario settings. The energy footprint of transportation needs, pre-treatment and reprocessing of recyclable materials was 3–9.5%, 1–18% and 1–8% respectively, relative to total energy savings. Mass combustion WtE achieved the highest savings in scenarios with CHP production, nonetheless, MBT-based systems had similarly high performance if SRF streams were co-combusted with coal. When RDF and SRF was only used in dedicated WtE plants, MBT-based systems totalled lower savings due to inherent system losses and additional energy costs. In scenarios without heat

Management of municipal solid waste incineration residues

International Nuclear Information System (INIS)

Sabbas, T.; Polettini, A.; Pomi, R.; Astrup, T.; Hjelmar, O.; Mostbauer, P.; Cappai, G.; Magel, G.; Salhofer, S.; Speiser, C.; Heuss-Assbichler, S.; Klein, R.; Lechner, P.

2003-01-01

The management of residues from thermal waste treatment is an integral part of waste management systems. The primary goal of managing incineration residues is to prevent any impact on our health or environment caused by unacceptable particulate, gaseous and/or solute emissions. This paper provides insight into the most important measures for putting this requirement into practice. It also offers an overview of the factors and processes affecting these mitigating measures as well as the short- and long-term behavior of residues from thermal waste treatment under different scenarios. General conditions affecting the emission rate of salts and metals are shown as well as factors relevant to mitigating measures or sources of gaseous emissions

Hanford tank residual waste - Contaminant source terms and release models

International Nuclear Information System (INIS)

Deutsch, William J.; Cantrell, Kirk J.; Krupka, Kenneth M.; Lindberg, Michael L.; Jeffery Serne, R.

2011-01-01

Highlights: → Residual waste from five Hanford spent fuel process storage tanks was evaluated. → Gibbsite is a common mineral in tanks with high Al concentrations. → Non-crystalline U-Na-C-O-P ± H phases are common in the U-rich residual. → Iron oxides/hydroxides have been identified in all residual waste samples. → Uranium release is highly dependent on waste and leachant compositions. - Abstract: Residual waste is expected to be left in 177 underground storage tanks after closure at the US Department of Energy's Hanford Site in Washington State, USA. In the long term, the residual wastes may represent a potential source of contamination to the subsurface environment. Residual materials that cannot be completely removed during the tank closure process are being studied to identify and characterize the solid phases and estimate the release of contaminants from these solids to water that might enter the closed tanks in the future. As of the end of 2009, residual waste from five tanks has been evaluated. Residual wastes from adjacent tanks C-202 and C-203 have high U concentrations of 24 and 59 wt.%, respectively, while residual wastes from nearby tanks C-103 and C-106 have low U concentrations of 0.4 and 0.03 wt.%, respectively. Aluminum concentrations are high (8.2-29.1 wt.%) in some tanks (C-103, C-106, and S-112) and relatively low ( 2 -saturated solution, or a CaCO 3 -saturated water. Uranium release concentrations are highly dependent on waste and leachant compositions with dissolved U concentrations one or two orders of magnitude higher in the tests with high U residual wastes, and also higher when leached with the CaCO 3 -saturated solution than with the Ca(OH) 2 -saturated solution. Technetium leachability is not as strongly dependent on the concentration of Tc in the waste, and it appears to be slightly more leachable by the Ca(OH) 2 -saturated solution than by the CaCO 3 -saturated solution. In general, Tc is much less leachable (<10 wt.% of the

Development of methods for treatment and conditioning of biological radioactive waste in the Czech Republic

International Nuclear Information System (INIS)

Holub, J.

1997-01-01

Incineration of biological radioactive waste was performed in a facility manufactured in the Czech Republic for combustion of burnable, radioactive and non-radioactive residues. The equipment has shown an adequate capability for combustion of biological waste. Basic technical parameters of the incinerator SP-603 can guarantee combustion of majority of wastes from different radionuclide users in the country. To ensure proper further handling with the resulting ash, three conditioning options were studied, the bituminization process, incorporation into cement, and embedding of ash into a mixture of bituminous and cementitious materials. Mechanical properties of the conditioned ash were in good compliance with those published elsewhere. Bituminized ash exhibits lowest leachibility, followed by the ash conditioned by means of the mixed process. Potential abnormal operation conditions were evaluated and their consequences assessed. The evaluation encompassed sensitivity analysis of the consequences potentially affecting the operating staff, nearby population and the environment. Cost estimate was carried out using a national approach for the calculation. From the results it can be seen that there are no large differences between the conditioning and disposal of wastes resulting from different conditioning processes. (author). 16 refs, 4 figs, 15 tabs

Development of methods for treatment and conditioning of biological radioactive waste in the Czech Republic

Energy Technology Data Exchange (ETDEWEB)

Holub, J [NYCOM, Prague (Czech Republic)

1997-02-01

Incineration of biological radioactive waste was performed in a facility manufactured in the Czech Republic for combustion of burnable, radioactive and non-radioactive residues. The equipment has shown an adequate capability for combustion of biological waste. Basic technical parameters of the incinerator SP-603 can guarantee combustion of majority of wastes from different radionuclide users in the country. To ensure proper further handling with the resulting ash, three conditioning options were studied, the bituminization process, incorporation into cement, and embedding of ash into a mixture of bituminous and cementitious materials. Mechanical properties of the conditioned ash were in good compliance with those published elsewhere. Bituminized ash exhibits lowest leachibility, followed by the ash conditioned by means of the mixed process. Potential abnormal operation conditions were evaluated and their consequences assessed. The evaluation encompassed sensitivity analysis of the consequences potentially affecting the operating staff, nearby population and the environment. Cost estimate was carried out using a national approach for the calculation. From the results it can be seen that there are no large differences between the conditioning and disposal of wastes resulting from different conditioning processes. (author). 16 refs, 4 figs, 15 tabs.

Shear strength characteristics of mechanically biologically treated municipal solid waste (MBT-MSW) from Bangalore

International Nuclear Information System (INIS)

Sivakumar Babu, G.L.; Lakshmikanthan, P.; Santhosh, L.G.

2015-01-01

Highlights: • Shear strength properties of mechanically biologically treated municipal solid waste. • Effect of unit weight and particle size on the shear strength of waste. • Effect of particle size on the strength properties. • Stiffness ratio and the strength ratio of MSW. - Abstract: Strength and stiffness properties of municipal solid waste (MSW) are important in landfill design. This paper presents the results of comprehensive testing of shear strength properties of mechanically biologically treated municipal solid waste (MBT-MSW) in laboratory. Changes in shear strength of MSW as a function of unit weight and particle size were investigated by performing laboratory studies on the MSW collected from Mavallipura landfill site in Bangalore. Direct shear tests, small scale and large scale consolidated undrained and drained triaxial tests were conducted on reconstituted compost reject MSW samples. The triaxial test results showed that the MSW samples exhibited a strain-hardening behaviour and the strength of MSW increased with increase in unit weight. Consolidated drained tests showed that the mobilized shear strength of the MSW increased by 40% for a unit weight increase from 7.3 kN/m 3 to 10.3 kN/m 3 at 20% strain levels. The mobilized cohesion and friction angle ranged from 5 to 9 kPa and 8° to 33° corresponding to a strain level of 20%. The consolidated undrained tests exhibited reduced friction angle values compared to the consolidated drained tests. The friction angle increased with increase in the unit weight from 8° to 55° in the consolidated undrained tests. Minor variations were found in the cohesion values. Relationships for strength and stiffness of MSW in terms of strength and stiffness ratios are developed and discussed. The stiffness ratio and the strength ratio of MSW were found to be 10 and 0.43

Shear strength characteristics of mechanically biologically treated municipal solid waste (MBT-MSW) from Bangalore

Energy Technology Data Exchange (ETDEWEB)

Sivakumar Babu, G.L., E-mail: gls@civil.iisc.ernet.in [Department of Civil Engineering, Indian Institute of Science, Bangalore 560012 (India); Lakshmikanthan, P., E-mail: lakshmikanthancp@gmail.com [Centre for Sustainable Technologies (CST), Indian Institute of Science, Bangalore 560012 (India); Santhosh, L.G., E-mail: lgsanthu2006@gmail.com [Centre for Sustainable Technologies (CST), Indian Institute of Science, Bangalore 560012 (India)

2015-05-15

Highlights: • Shear strength properties of mechanically biologically treated municipal solid waste. • Effect of unit weight and particle size on the shear strength of waste. • Effect of particle size on the strength properties. • Stiffness ratio and the strength ratio of MSW. - Abstract: Strength and stiffness properties of municipal solid waste (MSW) are important in landfill design. This paper presents the results of comprehensive testing of shear strength properties of mechanically biologically treated municipal solid waste (MBT-MSW) in laboratory. Changes in shear strength of MSW as a function of unit weight and particle size were investigated by performing laboratory studies on the MSW collected from Mavallipura landfill site in Bangalore. Direct shear tests, small scale and large scale consolidated undrained and drained triaxial tests were conducted on reconstituted compost reject MSW samples. The triaxial test results showed that the MSW samples exhibited a strain-hardening behaviour and the strength of MSW increased with increase in unit weight. Consolidated drained tests showed that the mobilized shear strength of the MSW increased by 40% for a unit weight increase from 7.3 kN/m{sup 3} to 10.3 kN/m{sup 3} at 20% strain levels. The mobilized cohesion and friction angle ranged from 5 to 9 kPa and 8° to 33° corresponding to a strain level of 20%. The consolidated undrained tests exhibited reduced friction angle values compared to the consolidated drained tests. The friction angle increased with increase in the unit weight from 8° to 55° in the consolidated undrained tests. Minor variations were found in the cohesion values. Relationships for strength and stiffness of MSW in terms of strength and stiffness ratios are developed and discussed. The stiffness ratio and the strength ratio of MSW were found to be 10 and 0.43.

Meeting the specifications for mechanical-biological waste treament and dumping; Umsetzung der Ablagerungsanforderungen im MBA- und Deponiebetrieb

Energy Technology Data Exchange (ETDEWEB)

Ketelsen, K. [IBA Ingenieurbuero fuer Abfallwirtschaft und Entsorgung GmbH, Hannover (Germany)

2001-07-01

The new German ordinances will have a dramatic influence on the waste treatment processes and air/exhaust management in mechanical-biological waste treatment plants. The potentials of process control and optimization should be fully utilized. The extensive in-service inspections and specifications will change the requirements on the process and staff qualification. The additional cost must be balanced by technically and economically feasible projecting and solutions. The need to keep up with thermal processes will lead to the construction of plants with a size of 50,000 Mg/a and more as these have higher economic efficiency, i.e. small regional utilities will have to co-operate. In mechanical-biological waste treatment plants, about 40-50% of the total cost is accounted for by the waste treatment process, i.e. economic efficiency will depend on the cost of dumping of the stabilized fine-grained fraction(about 20%) and the cost of utilization of the high-calorific waste (about 30%). In view of the high fixed cost, mechanical-biological waste treatment concepts will be economically efficient only if the plant capacity is fully utilized. [German] Mit Verabschiedung der Verordnungen ist die MBA 'gesellschaftsfaehiger' geworden. Die Verordnungen werden einen nachhaltigen Einfluss auf die Verfahrenstechnik und das gesamte Luft-/Abgasmanagement haben. Die Entwicklungspotentiale in der Prozesssteuerung und -optimierung muessen verstaerkt ausgeschoepft werden. Durch die geforderten umfangreichen Untersuchungs- und Nachweispflichten werden sich die Anforderungen an die Betriebsfuehrung und Personalqualifikation veraendern. Die aus den hoeheren Anforderungen resultierenden Mehrkosten muessen durch technisch und wirtschftlich sinnvolle Planungen und Loesungen in vertretbaren Grenzen gehalten werden. Die Notwendigkeit zur Wirtschaftlichkeit im Wettbewerb mit rein thermischen Verfahren wird auch bei den MBA zur Realisierung wirtschaftlicher Anlagengroessen von groesser

Effect of Solid Biological Waste Compost on the Metabolite Profile of Brassica rapa ssp. chinensis

Directory of Open Access Journals (Sweden)

Susanne Neugart

2018-03-01

Full Text Available Large quantities of biological waste are generated at various steps within the food production chain and a great utilization potential for this solid biological waste exists apart from the current main usage for the feedstuff sector. It remains unclear how the usage of biological waste as compost modulates plant metabolites. We investigated the effect of biological waste of the processing of coffee, aronia, and hop added to soil on the plant metabolite profile by means of liquid chromatography in pak choi sprouts. Here we demonstrate that the solid biological waste composts induced specific changes in the metabolite profiles and the changes are depending on the type of the organic residues and its concentration in soil. The targeted analysis of selected plant metabolites, associated with health beneficial properties of the Brassicaceae family, revealed increased concentrations of carotenoids (up to 3.2-fold and decreased amounts of glucosinolates (up to 4.7-fold as well as phenolic compounds (up to 1.5-fold.

Municipal solid waste options : integrating organics management and residual disposal treatment : executive summary

Energy Technology Data Exchange (ETDEWEB)

Cant, M. (comp.) [Totten Sims Hubicki Associates Ltd., Calgary, AB (Canada); Van der Werf, P. [2cg Inc., Edmonton, AB (Canada); Kelleher, M. [Kelleher Environmental, Toronto, ON (Canada); Merriman, D. [MacViro Consultants, Markham, ON (Canada); Fitcher, K. [Gartner Lee Ltd., Toronto, ON (Canada); MacDonald, N. [CH2M Hill Engineering Ltd., Calgary, AB (Canada)

2006-04-15

The Municipal Solid Waste (MSW) Options Report explored different MSW management options for 3 community sizes: 20,000, 80,000 and 200,0000 people. It was released at a time when many communities were developing waste management plans to cost-effectively reduce environmental impacts and conserve landfill capacity. The purpose of this report was to provide a greater understanding on the environmental, social, economic, energy recovery/utilization and greenhouse gas (GHG) considerations of MSW management. The report also demonstrated the interrelationships between the management of organics and residuals. It was based on information from existing waste diversion and organics management options and emerging residual treatment technology options. The following organics management and residual treatment disposal options were evaluated: composting; anaerobic digestion; sanitary landfills; bioreactor landfills; and thermal treatment. Composting was examined with reference to both source separated organics (SSO) and mixed waste composting. SSO refers to the separation of materials suitable for composting solid waste from households, while mixed waste composting refers to the manual or mechanical removal of recyclable material from the waste, including compost. The composting process was reviewed along with available technologies such as non-reactor windrow; aerated static pile; reactor enclosed channel; and, container tunnel. An evaluation of SSO and mixed waste composting was then presented in terms of environmental, social, financial and GHG impacts. refs., tabs., figs.

Contaminant Leach Testing of Hanford Tank 241-C-104 Residual Waste

Energy Technology Data Exchange (ETDEWEB)

Cantrell, Kirk J. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Snyder, Michelle M.V. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Wang, Guohui [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Buck, Edgar C. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

2015-07-01

Leach testing of Tank C-104 residual waste was completed using batch and column experiments. Tank C-104 residual waste contains exceptionally high concentrations of uranium (i.e., as high as 115 mg/g or 11.5 wt.%). This study was conducted to provide data to develop contaminant release models for Tank C-104 residual waste and Tank C-104 residual waste that has been treated with lime to transform uranium in the waste to a highly insoluble calcium uranate (CaUO4) or similar phase. Three column leaching cases were investigated. In the first case, C-104 residual waste was leached with deionized water. In the second case, crushed grout was added to the column so that deionized water contacted the grout prior to contacting the waste. In the third case, lime was mixed in with the grout. Results of the column experiments demonstrate that addition of lime dramatically reduces the leachability of uranium from Tank C-104 residual waste. Initial indications suggest that CaUO4 or a similar highly insoluble calcium rich uranium phase forms as a result of the lime addition. Additional work is needed to definitively identify the uranium phases that occur in the as received waste and the waste after the lime treatment.

Design of A District Heating System Including The Upgrading of Residual Industrial Waste Heat

NARCIS (Netherlands)

Falcao, P.W.; Mesbah, A.; Suherman, M.V.; Wennekes, S.

2005-01-01

This study was aimed to evaluate the feasibility of using a waste heat stream from DSM for a District Heating System. A conceptual design was carried out with emphasis on the unit for upgrading the residual waste heat. Having reviewed heat pump technology, mechanical heat pump was found to be the

Disposal of residue from sifting of combustible waste; Avsaettning av siktrest fraan foerbehandling av braennbart avfall

Energy Technology Data Exchange (ETDEWEB)

Niklasson, Fredrik

2012-11-01

In waste to energy plants, unwanted species in the fuel may cause corrosion, deposits, agglomeration in the fuel bed, and emissions of pollutants. Countermeasures to such problems are often costly. For at least some of the waste, the fuel properties can be improved by introducing a pretreatment system in which the fine fraction is separated from the waste by sifting. This method has been studied in an earlier Waste Refinery project, WR-06. That study pointed at advantages in performance of the boiler plant and a rough economical analysis indicated substantial benefits. The drawback of the pretreatment was that the residue (the fine fraction) showed as high content of total organic carbon (TOC) as 37 %, by weight. Such a waste fraction is not allowed to be landfilled in Sweden. High TOC content is also a limiting factor for usage as a secondary construction material. To become an applicable pretreatment method, it is necessary to find an appropriate disposal method for the residue material. Present work investigates different possibilities to handle the sifting residue, assuming it has the same properties as in previous study. The residue from sifting needs further treatment, preferably with energy recovery. There are some alternatives, such as combustion, gasification, anaerobic or aerobic digestion. To reduce problems associated by combustion, the waste may be burnt in another more suitable furnace. An alternative is gasification, but that treatment method is not yet an established process for waste fuels. Another option is treatment by anaerobic or aerobic digestion. The high concentrations of metals, however, limit the use of the biologically treated waste to landfilling sites, where it may be utilized as a construction material. The high metal concentrations in the sifting residue imply that it must be kept separate from other biodegradable wastes which are used to produce fertilizers. Thus, this treatment alternative will likely require substantial new

Evaluation of combustion experiments conducted during the research and development project ``Mechanical-biological waste conditioning in combination with thermal processing of partial waste fractions``; Auswertung der Verbrennungsversuche zum Forschungs- und Entwicklungsvorhaben ``mechanisch-biologische Restmuellbehandlung unter Einbindung thermischer Verfahren fuer Teilfraktionen``

Energy Technology Data Exchange (ETDEWEB)

Jager, J.; Lohf, A.; Herr, C. [Institut WAR, Darmstadt (Germany)

1998-12-31

The technical code on municipal waste makes specific demands on waste to be deposited at landfills which can only be met if mechanical-biological conditioning of waste as well as thermal processing of partial waste fractions are continued also in the future. But waste that has undergone mechanical or mechanical-biological conditioning presents different combustion properties from those of unconditioned waste. In this second stage of the research project, the thermal processability of waste having undergone mechanical or mechanical-biological conditioning was studied. Together with the results from the first project stage, where the throughput represented exclusively mechanically conditioned material, the results of the latter measuring campaigns comprehensively demonstrate possibilities for the thermal processing of partial waste fractions having undergone biological-mechanical conditioning, and inform on changes in plant performance. (orig.) [Deutsch] Um die in der TA-Siedlungsabfall an den abzulagernden Restmuell gestellten Deponieeingangsbedingungen zu erfuellen, muss neben einer mechanisch-biologischen Aufbereitung bei Teilfraktionen auch weiterhin eine thermische Behandlung eingeplant werden. Die Verbrennungseigenschaften von mechanisch oder mechanisch-biologisch vorbehandeltem Restmuell weichen allerdings von denen von unbehandeltem Restmuell ab. In dieser zweiten Projektphase des Forschungsvorhabens wurde eine Untersuchung bezueglich der thermischen Behandelbarkeit von mechanisch und auch biologisch vorbehandeltem Muell durchgefuehrt. Die Ergebnisse der Messkampagnen bilden zusammen mit den Ergebnissen der ersten Projektphase, in der ausschliesslich mechanisch vorbehandeltes Material durchgesetzt wurde, eine umfassende Darstellung ueber Moeglichkeiten und veraenderte Anlagenverhalten bei der thermischen Behandlung von Teilfraktionen aus der biologisch-mechanisch Vorbehandlung. (orig.)

Investigations on mechanical biological treatment of waste in South America: Towards more sustainable MSW management strategies

International Nuclear Information System (INIS)

Bezama, Alberto; Aguayo, Pablo; Konrad, Odorico; Navia, Rodrigo; Lorber, Karl E.

2007-01-01

This work presents an analysis on the suitability of mechanical biological treatment of municipal solid waste in South America, based on two previous experimental investigations carried out in two different countries. The first experiment was performed for determining the mass and volume reduction of MSW in the province of Concepcion (Chile). The implemented bench-scale process consisted of a manual classification and separation stage, followed by an in-vessel biological degradation process. The second experiment consisted of a full-scale experiment performed in the city of Estrela (Brazil), where the existing municipal waste management facility was adapted to enhance the materials sorting and separation. Expressed in wet weight composition, 85.5% of the material input in the first experiment was separated for biological degradation. After 27 days of processing, 60% of the initial mass was reduced through degradation and water evaporation. The final fraction destined for landfilling equals 59% of the total input mass, corresponding to about 50% of the initial volume. In the second experiment, the fraction destined to landfill reaches 46.6% of the total input waste mass, whilst also significantly reducing the total volume to be disposed. These results, and the possible recovery of material streams suitable for recycling or for preparing solid recovered fuels, are the main advantages of the studied process

Biological treatment of concentrated hazardous, toxic, andradionuclide mixed wastes without dilution

Energy Technology Data Exchange (ETDEWEB)

Stringfellow, William T.; Komada, Tatsuyuki; Chang, Li-Yang

2004-06-15

Approximately 10 percent of all radioactive wastes produced in the U. S. are mixed with hazardous or toxic chemicals and therefore can not be placed in secure land disposal facilities. Mixed wastes containing hazardous organic chemicals are often incinerated, but volatile radioactive elements are released directly into the biosphere. Some mixed wastes do not currently have any identified disposal option and are stored locally awaiting new developments. Biological treatment has been proposed as a potentially safer alternative to incineration for the treatment of hazardous organic mixed wastes, since biological treatment would not release volatile radioisotopes and the residual low-level radioactive waste would no longer be restricted from land disposal. Prior studies have shown that toxicity associated with acetonitrile is a significant limiting factor for the application of biotreatment to mixed wastes and excessive dilution was required to avoid inhibition of biological treatment. In this study, we demonstrate that a novel reactor configuration, where the concentrated toxic waste is drip-fed into a complete-mix bioreactor containing a pre-concentrated active microbial population, can be used to treat a surrogate acetonitrile mixed waste stream without excessive dilution. Using a drip-feed bioreactor, we were able to treat a 90,000 mg/L acetonitrile solution to less than 0.1 mg/L final concentration using a dilution factor of only 3.4. It was determined that the acetonitrile degradation reaction was inhibited at a pH above 7.2 and that the reactor could be modeled using conventional kinetic and mass balance approaches. Using a drip-feed reactor configuration addresses a major limiting factor (toxic inhibition) for the biological treatment of toxic, hazardous, or radioactive mixed wastes and suggests that drip-feed bioreactors could be used to treat other concentrated toxic waste streams, such as chemical warfare materiel.

Mechanical-biological waste treatment with thermal processing of partial fractions; Mechanisch-biologische Restabfallbehandlung unter Einbindung thermischer Verfahren fuer Teilfraktionen

Energy Technology Data Exchange (ETDEWEB)

NONE

1998-12-31

Technologies for mechanical-biological treatment of waste in the Land of Hessen were compared including thermal processes like combustion and gasification. The new and more rigid limiting values specified in the Technical Guide for Municipal Waste Treatment (Technische Anleitung Siedlungsabfall - TASI) get a special mention. [Deutsch] Verschiedene Technologien der mechanisch-biologischen Restabfallbehandlung im Raum Hessen wurden unter Einbezug thermischer Verfahren (Verbrennung, Vergasung) miteinander verglichen. Dabei wurden besonders auf die verschaerften Grenzwerte der Technischen Anleitung Siedlungsabfall (TASI) eingegangen. (ABI)

WEEE and portable batteries in residual household waste: Quantification and characterisation of misplaced waste

Energy Technology Data Exchange (ETDEWEB)

Bigum, Marianne, E-mail: mkkb@env.dtu.dk [Technical University of Denmark, Department of Environmental Engineering, Miljøvej 113, 2500 Kgs. Lyngby (Denmark); Petersen, Claus, E-mail: claus_petersen@econet.dk [Econet A/S, Strandboulevarden 122, 5, 2100 København Ø (Denmark); Christensen, Thomas H., E-mail: thho@env.dtu.dk [Technical University of Denmark, Department of Environmental Engineering, Miljøvej 113, 2500 Kgs. Lyngby (Denmark); Scheutz, Charlotte, E-mail: chas@env.dtu.dk [Technical University of Denmark, Department of Environmental Engineering, Miljøvej 113, 2500 Kgs. Lyngby (Denmark)

2013-11-15

Highlights: • We analyse 26.1 Mg of residual waste from 3129 Danish households. • We quantify and characterise misplaced WEEE and portable batteries. • We compare misplaced WEEE and batteries to collection through dedicated schemes. • Characterisation showed that primarily small WEEE and light sources are misplaced. • Significant amounts of misplaced batteries were discarded as built-in WEEE. - Abstract: A total of 26.1 Mg of residual waste from 3129 households in 12 Danish municipalities was analysed and revealed that 89.6 kg of Waste Electrical and Electronic Equipment (WEEE), 11 kg of batteries, 2.2 kg of toners and 16 kg of cables had been wrongfully discarded. This corresponds to a Danish household discarding 29 g of WEEE (7 items per year), 4 g of batteries (9 batteries per year), 1 g of toners and 7 g of unidentifiable cables on average per week, constituting 0.34% (w/w), 0.04% (w/w), 0.01% (w/w) and 0.09% (w/w), respectively, of residual waste. The study also found that misplaced WEEE and batteries in the residual waste constituted 16% and 39%, respectively, of what is being collected properly through the dedicated special waste collection schemes. This shows that a large amount of batteries are being discarded with the residual waste, whereas WEEE seems to be collected relatively successfully through the dedicated special waste collection schemes. Characterisation of the misplaced batteries showed that 20% (w/w) of the discarded batteries were discarded as part of WEEE (built-in). Primarily alkaline batteries, carbon zinc batteries and alkaline button cell batteries were found to be discarded with the residual household waste. Characterisation of WEEE showed that primarily small WEEE (WEEE directive categories 2, 5a, 6, 7 and 9) and light sources (WEEE directive category 5b) were misplaced. Electric tooth brushes, watches, clocks, headphones, flashlights, bicycle lights, and cables were items most frequently found. It is recommended that these

Hanford Tank 241-S-112 Residual Waste Composition and Leach Test Data

Energy Technology Data Exchange (ETDEWEB)

Cantrell, Kirk J.; Krupka, Kenneth M.; Geiszler, Keith N.; Lindberg, Michael J.; Arey, Bruce W.; Schaef, Herbert T.

2008-08-29

This report presents the results of laboratory characterization and testing of two samples (designated 20406 and 20407) of residual waste collected from tank S-112 after final waste retrieval. These studies were completed to characterize the residual waste and assess the leachability of contami¬nants from the solids. This is the first report from this PNNL project to describe the composition and leach test data for residual waste from a salt cake tank. All previous PNNL reports (Cantrell et al. 2008; Deutsch et al. 2006, 2007a, 2007b, 2007c) describing contaminant release models, and characterization and testing results for residual waste in single-shell tanks were based on samples from sludge tanks.

Evaluating the feasibility of biological waste processing for long term space missions

Science.gov (United States)

Garland, J. L.; Alazraki, M. P.; Atkinson, C. F.; Finger, B. W.; Sager, J. C. (Principal Investigator)

1998-01-01

Recycling waste products during orbital (e.g., International Space Station) and planetary missions (e.g., lunar base, Mars transit mission, Martian base) will reduce storage and resupply costs. Wastes streams on the space station will include human hygiene water, urine, faeces, and trash. Longer term missions will contain human waste and inedible plant material from plant growth systems used for atmospheric regeneration, food production, and water recycling. The feasibility of biological and physical-chemical waste recycling is being investigated as part of National Aeronautics and Space Administration's (NASA) Advanced Life Support (ALS) Program. In-vessel composting has lower manpower requirements, lower water and volume requirements, and greater potential for sanitization of human waste compared to alternative bioreactor designs such as continuously stirred tank reactors (CSTR). Residual solids from the process (i.e. compost) could be used a biological air filter, a plant nutrient source, and a carbon sink. Potential in-vessel composting designs for both near- and long-term space missions are presented and discussed with respect to the unique aspects of space-based systems.

Improvement of the management of residual waste in areas without thermal treatment facilities: A life cycle analysis of an Italian management district

Energy Technology Data Exchange (ETDEWEB)

Di Maria, Francesco, E-mail: francesco.dimaria@unipg.it [LAR Laboratory, Dipartimento di Ingegneria, Via G. Duranti 93, Perugia (Italy); Micale, Caterina; Morettini, Emanuela [LAR Laboratory, Dipartimento di Ingegneria, Via G. Duranti 93, Perugia (Italy); Sisani, Luciano [TSA spa, Via Case Sparse 107, Magione (Italy); Damiano, Roberto [GESENU spa, Via della Molinella 7, Perugia (Italy)

2015-10-15

Highlights: • LCA analysis of two option for residual waste management. • Exploitation of mechanical physical sorting facility for extracting recyclable from RMSW. • Processing the mechanically sorted organic fraction in bioreactor landfill. • Sensitivity analysis demonstrate high influence for impact assessment of substitution ratio for recycle materials. - Abstract: Starting from an existing waste management district without thermal treatment facilities, two different management scenarios for residual waste were compared by life cycle assessment (LCA). The adoption of a bioreactor landfill for managing the mechanically sorted organic fraction instead of bio-stabilization led to reduction of global warming and fresh water eutrophication by 50% and 10%, respectively. Extraction of recyclables from residual waste led to avoided emissions for particulate matter, acidification and resource depletion impact categories. Marginal energy and the amount of energy recovered from landfill gas marginally affected the LCA results. On the contrary the quality of the recyclables extracted can significantly modify the eco profile of the management schemes.

Biological treatment of concentrated hazardous, toxic, and radionuclide mixed wastes without dilution

International Nuclear Information System (INIS)

Stringfellow, William T.; Komada, Tatsuyuki; Chang, Li-Yang

2004-01-01

Approximately 10 percent of all radioactive wastes produced in the U. S. are mixed with hazardous or toxic chemicals and therefore can not be placed in secure land disposal facilities. Mixed wastes containing hazardous organic chemicals are often incinerated, but volatile radioactive elements are released directly into the biosphere. Some mixed wastes do not currently have any identified disposal option and are stored locally awaiting new developments. Biological treatment has been proposed as a potentially safer alternative to incineration for the treatment of hazardous organic mixed wastes, since biological treatment would not release volatile radioisotopes and the residual low-level radioactive waste would no longer be restricted from land disposal. Prior studies have shown that toxicity associated with acetonitrile is a significant limiting factor for the application of biotreatment to mixed wastes and excessive dilution was required to avoid inhibition of biological treatment. In this study, we demonstrate that a novel reactor configuration, where the concentrated toxic waste is drip-fed into a complete-mix bioreactor containing a pre-concentrated active microbial population, can be used to treat a surrogate acetonitrile mixed waste stream without excessive dilution. Using a drip-feed bioreactor, we were able to treat a 90,000 mg/L acetonitrile solution to less than 0.1 mg/L final concentration using a dilution factor of only 3.4. It was determined that the acetonitrile degradation reaction was inhibited at a pH above 7.2 and that the reactor could be modeled using conventional kinetic and mass balance approaches. Using a drip-feed reactor configuration addresses a major limiting factor (toxic inhibition) for the biological treatment of toxic, hazardous, or radioactive mixed wastes and suggests that drip-feed bioreactors could be used to treat other concentrated toxic waste streams, such as chemical warfare materiel

Electrodialytic remediation of municipal solid waste incineration residues using different membranes

DEFF Research Database (Denmark)

Parés Viader, Raimon; Jensen, Pernille Erland; Ottosen, Lisbeth M.

2017-01-01

In the present work, three different commercial membrane brands were used in an identical electrodialytic cell setup and operating conditions, in order to reduce the leaching of metals and salt anions of two types of municipal solid waste incineration residues: air pollution control residues...... as a technology to upgrade municipal solid waste incineration residues....

Behaviour at landfills of waste having undergone mechanic-biological and thermal conditioning; Deponieverhalten mechanisch-biologisch und thermisch behandelten Restabfalls

Energy Technology Data Exchange (ETDEWEB)

Danhamer, H.; Dach, J.; Jager, J. [Institut WAR, Darmstadt (Germany). FG Abfalltechnik

1998-12-31

The work studies, in landfill test reactors, water, gas and heat transport as well as gas and leachate formation in waste having undergone mechanical-biological and thermal conditioning. (orig.) [Deutsch] Es wurde der Wasser-, Gas- und Waermetransport, sowie die Gasbildung- und Sickerwasserbelastung mechanisch-biologisch und thermisch vorbehandelter Abfaelle in Deponieversuchsreaktoren untersucht. (orig.)

WEEE and portable batteries in residual household waste: Quantification and characterisation of misplaced waste

DEFF Research Database (Denmark)

Bigum, Marianne Kristine; Petersen, Claus; Christensen, Thomas Højlund

2013-01-01

with the residual household waste. Characterisation of WEEE showed that primarily small WEEE (WEEE directive categories 2, 5a, 6, 7 and 9) and light sources (WEEE directive category 5b) were misplaced. Electric tooth brushes, watches, clocks, headphones, flashlights, bicycle lights, and cables were items most......A total of 26.1Mg of residual waste from 3129 households in 12 Danish municipalities was analysed and revealed that 89.6kg of Waste Electrical and Electronic Equipment (WEEE), 11kg of batteries, 2.2kg of toners and 16kg of cables had been wrongfully discarded. This corresponds to a Danish household...

Management of solid residues in waste-to-energy and biomass systems

Energy Technology Data Exchange (ETDEWEB)

Vehlow, J.; Bergfeldt, B. [Forschungszentrum Karlsruhe GmbH Technik und Umwelt (Germany). Inst. fuer Technische Chemie; Wilen, C.; Ranta, J. [VTT Technical Research Centre of Finland, Espoo (Finland); Schwaiger, H. [Forschungsgesellschaft Joanneum mbH, Graz (Austria); Visser, H.J.M. [ECN Energy Research Centre of the Netherlands, Petten (Netherlands); Gu, S.; Gyftopoulou, E.; Brammer, J. [Aston Univ., Birmingham (United Kingdom)

2007-12-15

A literature review has been performed for getting in-depth information about quality of residues from thermal processes for waste and biomass as well as their disposal or utilisation options and current practices. Residues from waste incineration have been subject to intense research programs for many years and it can be concluded that the quality of bottom ashes has meanwhile a high standard. The question whether an utilisation as secondary building material is accepted or not depends on the definition of acceptable economic impac. For filter ashes and gas cleaning residues the situation is more complex. Their quality is known: due to their high inventory of heavy metals and organic micro-pollutants they are classified as hazardous waste which means they require specific measures for their safe long-term disposal. A number of stabilisation and treatment processes for filter ashes and gas cleaning residues including the recovery of species out of these materials have been developed but none has been implemented in full scale due to economic constraints. There is reason to speculate that even recovery processes which are not profitable for private companies might point out economically useful if future and long-term costs which have to be covered of the society, e.g. for rehabilitation of contaminated sites, are taken into account. Their quality as well as that of residues from combustion of contaminated biomass is mainly depending on the quality of the fuel. The inventory of critical ingredients in fuel produced from waste or waste fractions, especially of halogens and heavy metals, is often rather high and shows typically a wide range of variation. A reliable quality control for such fuels is very difficult. Other residues can - like gas cleaning residues from waste incineration - be inertised in order to meet the criteria for the access to cheaper landfills than those for hazardous waste. A similar conclusion can be drawn for the quality and management of

Estimation of residual MSW heating value as a function of waste component recycling

International Nuclear Information System (INIS)

Magrinho, Alexandre; Semiao, Viriato

2008-01-01

Recycling of packaging wastes may be compatible with incineration within integrated waste management systems. To study this, a mathematical model is presented to calculate the fraction composition of residual municipal solid waste (MSW) only as a function of the MSW fraction composition at source and recycling fractions of the different waste materials. The application of the model to the Lisbon region yielded results showing that the residual waste fraction composition depends both on the packaging wastes fraction at source and on the ratio between that fraction and the fraction of the same material, packaging and non-packaging, at source. This behaviour determines the variation of the residual waste LHV. For 100% of paper packaging recycling, LHV reduces 4.2% whereas this reduction is of 14.4% for 100% of packaging plastics recycling. For 100% of food waste recovery, LHV increases 36.8% due to the moisture fraction reduction of the residual waste. Additionally the results evidence that the negative impact of recycling paper and plastic packaging on the LHV may be compensated by recycling food waste and glass and metal packaging. This makes packaging materials recycling and food waste recovery compatible strategies with incineration within integrated waste management systems

Waste washing pre-treatment of municipal and special waste.

Science.gov (United States)

Cossu, Raffaello; Lai, Tiziana; Pivnenko, Kostyantyn

2012-03-15

Long-term pollution potential in landfills is mainly related to the quality of leachate. Waste can be conveniently treated prior to landfilling with an aim to minimizing future emissions. Washing of waste represents a feasible pre-treatment method focused on controlling the leachable fraction of residues and relevant impact. In this study, non-recyclable plastics originating from source segregation, mechanical-biological treated municipal solid waste (MSW), bottom ash from MSW incineration and automotive shredder residues (ASR) were treated and the removal efficiency of washing pre-treatment prior to landfilling was evaluated. Column tests were performed to simulate the behaviour of waste in landfill under aerobic and anaerobic conditions. The findings obtained revealed how waste washing treatment (WWT) allowed the leachability of contaminants from waste to be reduced. Removal rates exceeding 65% were obtained for dissolved organic carbon (DOC), chemical oxygen demand (COD) and Total Kjeldahl Nitrogen (TKN). A percentage decrease of approximately 60% was reached for the leachable fraction of chlorides, sulphates, fluoride and metals, as proved by a reduction in electric conductivity values (70%). Copyright © 2011 Elsevier B.V. All rights reserved.

Water regime of mechanical-biological pretreated waste materials under fast-growing trees.

Science.gov (United States)

Rüth, Björn; Lennartz, Bernd; Kahle, Petra

2007-10-01

In this study mechanical-biological pre-treated waste material (MBP) was tested for suitability to serve as an alternative surface layer in combination with fast-growing and water-consumptive trees for final covers at landfill sites. The aim was to quantify evapotranspiration and seepage losses by numerical model simulations for two sites in Germany. In addition, the leaf area index (LAI) of six tree species over the growing season as the driving parameter for transpiration calculations was determined experimentally. The maximum LAI varied between 3.8 and 6.1 m2 m(-2) for poplar and willow clones, respectively. The evapotranspiration calculations revealed that the use of MBP waste material for re-cultivation enhanced evapotranspiration by 40 mm year(-1) (10%) over an 11 year calculation period compared to a standard mineral soil. Between 82% (for LAI(max) = 3.8) and 87% (for LAI(max) = 6.1) of the average annual precipitation (506 mm) could be retained from the surface layer assuming eastern German climate conditions, compared with a retention efficiency between 79 and 82% for a mineral soil. Although a MBP layer in conjunction with water-consumptive trees can reduce vertical water losses as compared to mineral substrates, the effect is not sufficient to meet legal regulations.

Instructive of chemical residues waste administration

International Nuclear Information System (INIS)

Alfaro Vargas, Ariel

2014-01-01

An instructive is established for the waste management system of chemical residues generated at the Universidad de Costa Rica, ensuring the collection, separation, transportation, reuse, recycling and final disposal. The laboratory waste management system is conditioned to the volume and type of waste generated. The respective procedures are listed in data sheets according to the corresponding model: avoid, reduce, recycle, treat, delete. The materials are identified as: expired products, materials or damaged products, substances that have lost some of the required characteristics, waste from the regular activities of the lab, unused products that now no longer used because they are considered inadequate. The chemicals reagents or hazardous are transformed into small amounts of derivatives safe products, or less hazardous, to allow for removal or to pick up a spill of these without problem [es

Influence of organic waste and residue mud additions on chemical, physical and microbial properties of bauxite residue sand.

Science.gov (United States)

Jones, Benjamin E H; Haynes, Richard J; Phillips, Ian R

2011-02-01

In an alumina refinery, bauxite ore is treated with sodium hydroxide at high temperatures and pressures and for every tone of alumina produced, about 2 tones of alkaline, saline bauxite processing waste is also produced. At Alcoa, a dry stacking system of disposal is used, and it is the sand fraction of the processing waste that is rehabilitated. There is little information available regarding the most appropriate amendments to add to the processing sand to aid in revegetation. The purpose of this study was to investigate how the addition of organic wastes (biosolids and poultry manure), in the presence or absence of added residue mud, would affect the properties of the residue sand and its suitability for revegetation. Samples of freshly deposited residue sand were collected from Alcoa's Kwinana refinery. Samples were treated with phosphogypsum (2% v/v), incubated, and leached. A laboratory experiment was then set up in which the two organic wastes were applied at 0 or the equivalent to 60 tones ha(-1) in combination with residue mud added at rates of 0%, 10% and 20% v/v. Samples were incubated for 8 weeks, after which, key chemical, physical and microbial properties of the residue sand were measured along with seed germination. Additions of residue mud increased exchangeable Na(+), ESP and the pH, and HCO (3) (-) and Na(+) concentrations in saturation paste extracts. Additions of biosolids and poultry manure increased concentrations of extractable P, NH (4) (+) , K, Mg, Cu, Zn, Mn and Fe. Addition of residue mud, in combination with organic wastes, caused a marked decrease in macroporosity and a concomitant increase in mesoporosity, available water holding capacity and the quantity of water held at field capacity. With increasing residue mud additions, the percentage of sample present as sand particles (2 mm diameter) increased; greatest aggregation occurred where a combination of residue mud and poultry manure were added. Stability of aggregates, as measured by

Metallic elements fractionation in municipal solid waste incineration residues

Science.gov (United States)

Kowalski, Piotr R.; Kasina, Monika; Michalik, Marek

2016-04-01

Municipal solid waste incineration (MSWI) residues are represented by three main materials: bottom ash, fly ash and air pollution control (APC) residues. Among them ˜80 wt% is bottom ash. All of that materials are products of high temperature (>1000° C) treatment of waste. Incineration process allows to obtain significant reduction of waste mass (up to 70%) and volume (up to 90%) what is commonly used in waste management to reduce the amount need to be landfilled or managed in other way. Incineration promote accumulation non-combustible fraction of waste, which part are metallic elements. That type of concentration is object of concerns about the incineration residues impact on the environment and also gives the possibility of attempts to recover them. Metallic elements are not equally distributed among the materials. Several factors influence the process: melting points, volatility and place and forms of metallic occurrence in the incinerated waste. To investigate metallic elements distribution in MSWI residues samples from one of the biggest MSW incineration plant in Poland were collected in 2015. Chemical analysis with emphasis on the metallic elements content were performed using inductively coupled plasma optical emission (ICP-OES) and mass spectrometry (ICP-MS). The bottom ash was a SiO2-CaO-Al2O3-Fe2O3-Na2O rich material, whereas fly ash and APC residues were mostly composed of CaO and SiO2. All of the materials were rich in amorphous phase occurring together with various, mostly silicate crystalline phases. In a mass of bottom ash 11 wt% were metallic elements but also in ashes 8.5 wt% (fly ash) and ˜4.5 wt% (APC residues) of them were present. Among the metallic elements equal distribution between bottom and fly ash was observed for Al (˜3.85 wt%), Mn (770 ppm) and Ni (˜65 ppm). In bottom ash Fe (5.5 wt%), Cr (590 ppm) and Cu (1250 ppm) were concentrated. These values in comparison to fly ash were 5-fold higher for Fe, 3-fold for Cu and 1.5-fold for

Waste vinegar residue as substrate for phytase production.

Science.gov (United States)

Wang, Zhi-Hong; Dong, Xiao-Fang; Zhang, Guo-Qing; Tong, Jian-Ming; Zhang, Qi; Xu, Shang-Zhong

2011-12-01

Waste vinegar residue, the by-product of vinegar processing, was used as substrate for phytase production from Aspergillus ficuum NTG-23 in solid-state fermentation to investigate the potential for the efficient re-utilization or recycling of waste vinegar residue. Statistical designs were applied in the processing of phytase production. First, a Plackett-Burman (PB) design was used to evaluate eleven parameters: glucose, starch, wheat bran, (NH(4))(2)SO(4), NH(4)NO(3), tryptone, soybean meal, MgSO(4)·7H(2)O, CaCl(2)·7H(2)O, FeSO(4)·7H(2)O, incubation time. The PB experiments showed that there were three significant factors: glucose, soybean meal and incubation time. The closest values to the optimum point were then derived by steepest ascent path. Finally, a mathematical model was created and validated to explain the behavioural process after these three significant factors were optimized using response surface methodology (RSM). The best phytase activity was attained using the following conditions: glucose (7.2%), soybean meal (5.1%), and incubation time (271 h). The phytase activity was 7.34-fold higher due to optimization by PB design, steepest ascent path design and RSM. The phytase activity was enhanced 0.26-fold in comparison with the results by the second step of steepest ascent path design. The results indicate that with waste vinegar residue as a substrate higher production of phytase from Aspergillus ficuum NTG-23 could be obtained through an optimization process and that this method might be applied to an integrated system for recycling of the waste vinegar residue.

Global warming factors modelled for 40 generic municipal waste management scenarios

DEFF Research Database (Denmark)

Christensen, Thomas Højlund; Simion, F.; Tonini, Davide

2009-01-01

Global warming factors (kg CO2-eq.-tonne—1 of waste) have been modelled for 40 different municipal waste management scenarios involving a variety of recycling systems (paper, glass, plastic and organics) and residual waste management by landfilling, incineration or mechanical—biological waste...... treatment. For average European waste composition most waste management scenarios provided negative global warming factors and hence overall savings in greenhouse gas emissions: Scenarios with landfilling saved 0—400, scenarios with incineration saved 200—700, and scenarios with mechanical...

Analysis of waste management issues arising from a field study evaluating decontamination of a biological agent from a building.

Science.gov (United States)

Lemieux, P; Wood, J; Drake, J; Minamyer, S; Silvestri, E; Yund, C; Nichols, T; Ierardi, M; Amidan, B

2016-01-01

The Bio-response Operational Testing and Evaluation (BOTE) Project was a cross-government effort designed to operationally test and evaluate a response to a biological incident (release of Bacillus anthracis [Ba] spores, the causative agent for anthrax) from initial public health and law enforcement response through environmental remediation. The BOTE Project was designed to address site remediation after the release of a Ba simulant, Bacillus atrophaeus spp. globigii (Bg), within a facility, drawing upon recent advances in the biological sampling and decontamination areas. A key component of response to a biological contamination incident is the proper management of wastes and residues, which is woven throughout all response activities. Waste is generated throughout the response and includes items like sampling media packaging materials, discarded personal protective equipment, items removed from the facility either prior to or following decontamination, aqueous waste streams, and materials generated through the application of decontamination technologies. The amount of residual contaminating agent will impact the available disposal pathways and waste management costs. Waste management is an integral part of the decontamination process and should be included through "Pre-Incident" response planning. Overall, the pH-adjusted bleach decontamination process generated the most waste from the decontamination efforts, and fumigation with chlorine dioxide generated the least waste. A majority of the solid waste generated during pH-adjusted bleach decontamination was the nonporous surfaces that were removed, bagged, decontaminated ex situ, and treated as waste. The waste during the two fumigation rounds of the BOTE Project was associated mainly with sampling activities. Waste management activities may represent a significant contribution to the overall cost of the response/recovery operation. This paper addresses the waste management activities for the BOTE field test

Effects of hydrated lime on radionuclides stabilization of Hanford tank residual waste.

Science.gov (United States)

Wang, Guohui; Um, Wooyong; Cantrell, Kirk J; Snyder, Michelle M V; Bowden, Mark E; Triplett, Mark B; Buck, Edgar C

2017-10-01

Chemical stabilization of tank residual waste is part of a Hanford Site tank closure strategy to reduce overall risk levels to human health and the environment. In this study, a set of column leaching experiments using tank C-104 residual waste were conducted to evaluate the leachability of uranium (U) and technetium (Tc) where grout and hydrated lime were applied as chemical stabilizing agents. The experiments were designed to simulate future scenarios where meteoric water infiltrates through the vadose zones into the interior of the tank filled with layers of grout or hydrated lime, and then contacts the residual waste. Effluent concentrations of U and Tc were monitored and compared among three different packing columns (waste only, waste + grout, and waste + grout + hydrated lime). Geochemical modeling of the effluent compositions was conducted to determine saturation indices of uranium solid phases that could control the solubility of uranium. The results indicate that addition of hydrated lime strongly stabilized the uranium through transforming uranium to a highly insoluble calcium uranate (CaUO 4 ) or similar phase, whereas no significant stabilization effect of grout or hydrated lime was observed on Tc leachability. The result implies that hydrated lime could be a great candidate for stabilizing Hanford tank residual wastes where uranium is one of the main concerns. Published by Elsevier Ltd.

Direct landfill disposal versus Mechanical Biological Treatment (MBT

Directory of Open Access Journals (Sweden)

Kulhawik Katarzyna

2016-09-01

Full Text Available After the implementation of a new waste management system, in which recycling is the most dominating process, landfill disposal still appears to be the most popular method of waste management in Poland, in which waste undergoes gradual decomposition and the influence of climate conditions, for example, air and atmospheric fallout, leads to the production of leachate and biogas emissions, which contribute to continual threats to the natural environment and humans. The above-mentioned threats can be limited by applying suitable techniques of waste treatment before its disposal. A technology that is oriented to these aims is a mechanical biological treatment (MBT before disposal.

Elution behaviour of solid residues from thermal waste treatment and disposal

International Nuclear Information System (INIS)

Vetter, G.

1992-01-01

In the research part carried through so far, the leaching behaviour of residues of different waste combustion methods was compared with that of other materials frequently deposited at landfills as regards heavy metals and anions. Furthermore, specifically residues from different types of waste subjected to the Siemens semicoking process were investigated. The leaching behaviour of well vitrified slags approaches very much the favourable values of melting-chamber granulate from a black-coal-fired power plant. By contrast, poorly vitrified slags or slags from an ordinary waste combustion plant yield eluate concentrations exceeding in part the limiting values applicable to landfilling material. With vitrified slags, the type of waste burnt has no recognizable influence on leaching behaviour. (orig.) [de

Solid residues from Italian municipal solid waste incinerators: A source for "critical" raw materials.

Science.gov (United States)

Funari, Valerio; Braga, Roberto; Bokhari, Syed Nadeem Hussain; Dinelli, Enrico; Meisel, Thomas

2015-11-01

The incineration of municipal solid wastes is an important part of the waste management system along with recycling and waste disposal, and the solid residues produced after the thermal process have received attention for environmental concerns and the recovery of valuable metals. This study focuses on the Critical Raw Materials (CRM) content in solid residues from two Italian municipal waste incinerator (MSWI) plants. We sampled untreated bottom ash and fly ash residues, i.e. the two main outputs of common grate-furnace incinerators, and determined their total elemental composition with sensitive analytical techniques such as XRF and ICP-MS. After the removal of a few coarse metallic objects from bottom ashes, the corresponding ICP solutions were obtained using strong digestion methods, to ensure the dissolution of the most refractory components that could host significant amounts of precious metals and CRM. The integration of accurate chemical data with a substance flow analysis, which takes into account the mass balance and uncertainties assessment, indicates that bottom and fly ashes can be considered as a low concentration stream of precious and high-tech metals. The magnesium, copper, antimony and zinc contents are close to the corresponding values of a low-grade ore. The distribution of the elements flow between bottom and fly ash, and within different grain size fractions of bottom ash, is appraised. Most elements are enriched in the bottom ash flow, especially in the fine grained fractions. However, the calculated transfer coefficients indicate that Sb and Zn strongly partition into the fly ashes. The comparison with available studies indicates that the CRM concentrations in the untreated solid residues are comparable with those residues that undergo post-treatment beneficiations, e.g. separation between ferrous and non-ferrous fractions. The suggested separate collection of "fresh" bottom ash, which could be processed for further mineral upgrading, can

Glass-Ceramic Waste Forms for Uranium and Plutonium Residues Wastes - 13164

International Nuclear Information System (INIS)

Stewart, Martin W.A.; Moricca, Sam A.; Zhang, Yingjie; Day, R. Arthur; Begg, Bruce D.; Scales, Charlie R.; Maddrell, Ewan R.; Hobbs, Jeff

2013-01-01

A program of work has been undertaken to treat plutonium-residues wastes at Sellafield. These have arisen from past fuel development work and are highly variable in both physical and chemical composition. The principal radiological elements present are U and Pu, with small amounts of Th. The waste packages contain Pu in amounts that are too low to be economically recycled as fuel and too high to be disposed of as lower level Pu contaminated material. NNL and ANSTO have developed full-ceramic and glass-ceramic waste forms in which hot-isostatic pressing is used as the consolidation step to safely immobilize the waste into a form suitable for long-term disposition. We discuss development work on the glass-ceramic developed for impure waste streams, in particular the effect of variations in the waste feed chemistry glass-ceramic. The waste chemistry was categorized into actinides, impurity cations, glass formers and anions. Variations of the relative amounts of these on the properties and chemistry of the waste form were investigated and the waste form was found to be largely unaffected by these changes. This work mainly discusses the initial trials with Th and U. Later trials with larger variations and work with Pu-doped samples further confirmed the flexibility of the glass-ceramic. (authors)

Emission model for landfills with mechanically-biologically pretreated waste, with the emphasis on modelling the gas balance; Emissionsprognosemodell fuer Deponien mit mechanisch-biologisch vorbehandelten Abfaellen - Schwerpunkt: Modellierung des Gashaushaltes

Energy Technology Data Exchange (ETDEWEB)

Danhamer, H.

2001-07-01

The objective of this work was to determine influence factors on processes going on in landfills with mechanically-biologically pretreated waste (MBP-landfills) in order to predict emissions. For this purpose a computer based model has been developed. The model allows to simulate the gas, water and heat balance as well as settlement processes and was called DESIM2005 (version MB). It is based on theoretical modeling approaches as well as data from lab and reactor experiments. The main focus of model application was to determine factors influencing the gas phase and the emissions of landfill gas and methane during operation and aftercare of MBP-landfills. By performing simulations the effects of changing parameters for the processes gas transport and biological degradation as well as the effects of different qualities in waste pretreatment and of varying landfill operation techniques were investigated. Possibilities for increasing the environmental sustainability of landfills containing mechanically-biologically pretreated waste were shown. (orig.)

Biological intrusion of low-level-waste trench covers

Science.gov (United States)

Hakonson, T. E.; Gladney, E. S.

The long-term integrity of low-level waste shallow land burialsites is dependent on the interaction of physical, chemical, and biological factors that modify the waste containment system. The need to consider biological processes as being potentially important in reducing the integrity of waste burial site cover treatment is demonstrated. One approach to limiting biological intrusion through the waste cover is to apply a barrier within the profile to limit root and animal penetration with depth. Experiments in the Los Alamos Experimental Engineered Test Facility were initiated to develop and evaluate biological barriers that are effective in minimizing intrusion into waste trenches. The experiments that are described employ four different candidate barrier materials of geologic origin. Experimental variables that will be evaluated, in addition to barrier type, are barrier depth and sil overburden depth.

Contaminant transport at a waste residue deposit

DEFF Research Database (Denmark)

Engesgaard, Peter Knudegaard; Traberg, Rikke

1996-01-01

Contaminant transport in an aquifer at an incinerator waste residue deposit in Denmark is simulated. A two-dimensional, geochemical transport code is developed for this purpose and tested by comparison to results from another code, The code is applied to a column experiment and to the field site...

[Waste over history: perceptions about residues].

Science.gov (United States)

Velloso, Marta Pimenta

2008-01-01

This article describes how Man, over history, felt about the residues produced by human activity. The text is divided into three parts: In the first part it tells the story of the black plague pandemic during the XIV century, showing how this disease was associated with the residues produced by the human body. In the second part it explains how the first notions of waste were, and still are, related to dirt, disease and death. Finally, in the third part, it describes the first measures of hygiene in the Renaissance and refers to the first public health actions at the beginning of the XX century, starting to combat the agents of infectious diseases and their vectors.

Intended process water management concept for the mechanical biological treatment of municipal solid waste

Institute of Scientific and Technical Information of China (English)

D. Weichgrebe; S. Maerker; T. Boning; H. Stegemann

2008-01-01

Accumulating operational experience in both aerobic and anaerobic mechanical biological waste treatment (MBT) makes it increasingly obvious that controlled water management would substantially reduce the cost of MBT and also enhance resource recovery of the organic and inorganic fraction. The MBT plant at Gescher, Germany, is used as an example in order to determine the quantity and composition of process water and leachates from intensive and subsequent rotting, pressing water from anaerobic digestion and scrubber water from acid exhaust air treatment, and hence prepare an MBT water balance. The potential of, requirements for and limits to internal process water reuse as well as the possibilities of resource recovery from scrubber water are also examined. Finally, an assimilated process water management concept with the purpose of an extensive reduction of wastewater quantity and freshwater demand is presented.

Effect of drying on leaching testing of treated municipal solid waste incineration APC-residues

DEFF Research Database (Denmark)

Hu, Y.; Hyks, Jiri; Astrup, Thomas

2008-01-01

Air-pollution-control (APC) residues from waste incinerators are hazardous waste according to European legislation and must be treated prior to landfilling. Batch and column leaching data determine which type of landfill can receive the treated APC-residues. CEN standards are prescribed...

Effect of the heating rate on residual thermo-hydro-mechanical properties of a high-strength concrete in the context of nuclear waste storage

International Nuclear Information System (INIS)

Galle, C.; Pin, M.; Ranc, G.; Rodrigues, S.

2003-01-01

Concrete is likely to be used in massive structures for nuclear waste long-term storage facilities in France. In the framework of vitrified waste and spent fuel management, these structures could be submitted to high temperatures. In standard conditions, ambient temperature should not exceed 60 degC but in case of failure of a cooling system, concretes could be temporarily exposed to temperatures up to 250 degC. Depending on the temperature rise kinetics, concretes could be damaged to a greater or lesser extent. In this context, an experimental study on the effect of heating rate on concrete thermo-hydro-mechanical properties exposed to high temperatures (110 - 250 degC) was carried out at the French Atomic Energy Commission (CEA). Data analysis and interpretation provided enough arguments to conclude that, at local scale, the impact of heating rate on residual properties was real though relatively limited. (author)

Characterization on incineration residue of radioactive solid wastes

International Nuclear Information System (INIS)

Katoh, Kiyoshi; Hirayama, Katsuyoshi; Kato, Akira.

1989-01-01

Characterization was carried out on incineration residue discharged from the radioactive solid waste incineration unit (capacity, 100 kg/h) in use at the Tokai Research Establishment of Japan Atomic Energy Research Institute (JAERI) to obtain basic data for investigating solidification methods of the residue. The characterized residue was taken from furnace and a primary ceramic filter of the incineration unit which incinerates combustible solid wastes generated at JAERI and the outside organizations. Items of characterization involve a particle size distribution, misplaced materials content, ignition loss, chemical composition and radioactivity of nuclides in the ash. As the results, the size of ash sampled from the furnace distributed a wide range, with about 35∼60 % of ash smaller than 5 mm and about 10∼25 % of massive one larger than 30 mm (max. size: ∼130 mm). The ignition loss was 2∼3 %. The chemical compositions of the ash were mainly SiO 2 , Fe 2 O 3 , CaO and Al 2 O 3 . The specific activities of the ash were about 0.4∼4 x 10 3 Bq/g, and principal contaminants were 60 Co and 137 Cs. (author)

Contaminant Release from Residual Waste in Single Shell Tanks at the Hanford Site, Washington, USA - 9276

International Nuclear Information System (INIS)

Cantrell, Kirk J.; Krupka, Kenneth M.; Deutsch, William J.; Lindberg, Michael J.

2009-01-01

Determinations of elemental and solid-phase compositions, and contaminant release studies have been applied in an ongoing study of residual tank wastes (i.e., waste remaining after final retrieval operations) from five of 149 underground single-shell storage tanks (241-C-103, 241-C-106, 241-C-202, 241-C-203, and 241-S-112) at the U.S. Department of Energy's Hanford Site in Washington State. This work is being conducted to support performance assessments that will be required to evaluate long-term health and safety risks associated with tank site closure. The results of studies completed to date show significant variability in the compositions, solid phase properties, and contaminant release characteristics from these residual tank wastes. This variability is the result of differences in waste chemistry/composition of wastes produced from several different spent fuel reprocessing schemes, subsequent waste reprocessing to remove certain target constituents, tank farm operations that concentrated wastes and mixed wastes between tanks, and differences in retrieval processes used to remove the wastes from the tanks. Release models were developed based upon results of chemical characterization of the bulk residual waste, solid-phase characterization (see companion paper 9277 by Krupka et al.), leaching and extraction experiments, and geochemical modeling. In most cases empirical release models were required to describe contaminant release from these wastes. Release of contaminants from residual waste was frequently found to be controlled by the solubility of phases that could not be identified and/or for which thermodynamic data and/or dissolution rates have not been measured. For example, significant fractions of Tc-99, I-129, and Cr appear to be coprecipitated at trace concentrations in metal oxide phases that could not be identified unambiguously. In the case of U release from tank 241-C-103 residual waste, geochemical calculations indicated that leachate

Critical evaluation of municipal solid waste composting and potential compost markets.

Science.gov (United States)

Farrell, M; Jones, D L

2009-10-01

Mechanical biological treatment (MBT) of mixed waste streams is becoming increasingly popular as a method for treating municipal solid waste (MSW). Whilst this process can separate many recyclates from mixed waste, the resultant organic residue can contain high levels of heavy metals and physical and biological contaminants. This review assesses the potential end uses and sustainable markets for this organic residue. Critical evaluation reveals that the best option for using this organic resource is in land remediation and restoration schemes. For example, application of MSW-derived composts at acidic heavy metal contaminated sites has ameliorated soil pollution with minimal risk. We conclude that although MSW-derived composts are of low value, they still represent a valuable resource particularly for use in post-industrial environments. A holistic view should be taken when regulating the use of such composts, taking into account the specific situation of application and the environmental pitfalls of alternative disposal routes.

Valorisation of food residues: waste to wealth using green chemical technologies

OpenAIRE

Clark, James H.; Luque, Rafael

2013-01-01

Waste valorisation practises have attracted a significant amount of attention in recent years with the aim of managing waste in the most sustainable way. Food waste constitutes a largely under-exploited residue from which a variety of valuable chemicals can be derived. This contribution is aimed to set the scene for a further development and promotion of sustainable food waste valorisation practises to different end products using green chemical technologies

Flexible process options for the immobilisation of residues and wastes containing plutonium

International Nuclear Information System (INIS)

Stewart, M.W.A.; Moricca, S.A.; Day, R. A.; Begg, B. D.; Scales, C. R.; Maddrell, E. R.; Eilbeck, A. B.

2007-01-01

Residues and waste streams containing plutonium present unique technical, safety, regulatory, security, and socio-political challenges. In the UK these streams range from lightly plutonium contaminated materials (PCM) through to residue s resulting directly from Pu processing operations. In addition there are potentially stocks of Pu oxide powders whose future designation may be either a waste or an asset, due to their levels of contamination making their reuse uneconomic, or to changes in nuclear policy. While waste management routes exist for PCM, an immobilisation process is required for streams containing higher levels of Pu. Such a process is being developed by Nexia Solutions and ANSTO to treat and immobilise Pu waste and residues currently stored on the Sellafield site. The characteristics of these Pu waste streams are highly variable. The physical form of the Pu waste ranges from liquids, sludges, powders/granules, to solid components (e.g., test fuels), with the Pu present as an ion in solution, as a salt, metal, oxide or other compound. The chemistry of the Pu waste streams also varies considerably with a variety of impurities present in many waste streams. Furthermore, with fissile isotopes present, criticality is an issue during operations and in the store or repository. Safeguards and security concerns must be assessed and controlled. The process under development, by using a combination of tailored waste form chemistry combined with flexible process technology aims to develop a process line to handle a broad range of Pu waste streams. It aims to be capable of dealing with not only current arisings but those anticipated to arise as a result of future operations or policy changes. (authors)

Washing of waste prior to landfilling.

Science.gov (United States)

Cossu, Raffaello; Lai, Tiziana

2012-05-01

The main impact produced by landfills is represented by the release of leachate emissions. Waste washing treatment has been investigated to evaluate its efficiency in reducing the waste leaching fraction prior to landfilling. The results of laboratory-scale washing tests applied to several significant residues from integrated management of solid waste are presented in this study, specifically: non-recyclable plastics from source separation, mechanical-biological treated municipal solid waste and a special waste, automotive shredded residues. Results obtained demonstrate that washing treatment contributes towards combating the environmental impacts of raw wastes. Accordingly, a leachate production model was applied, leading to the consideration that the concentrations of chemical oxygen demand (COD) and total Kjeldahl nitrogen (TKN), parameters of fundamental importance in the characterization of landfill leachate, from a landfill containing washed wastes, are comparable to those that would only be reached between 90 and 220years later in the presence of raw wastes. The findings obtained demonstrated that washing of waste may represent an effective means of reducing the leachable fraction resulting in a consequent decrease in landfill emissions. Further studies on pilot scale are needed to assess the potential for full-scale application of this treatment. Copyright © 2012 Elsevier Ltd. All rights reserved.

Air pollution control residues from waste incineration: current UK situation and assessment of alternative technologies.

Science.gov (United States)

Rani, D Amutha; Boccaccini, A R; Deegan, D; Cheeseman, C R

2008-11-01

Current disposal options for APC residues in the UK and alternative treatment technologies developed world-wide have been reviewed. APC residues are currently landfilled in the UK where they undergo in situ solidification, although the future acceptability of this option is uncertain because the EU waste acceptance criteria (WAC) introduce strict limits on leaching that are difficult to achieve. Other APC residue treatment processes have been developed which are reported to reduce leaching to below relevant regulatory limits. The Ferrox process, the VKI process, the WES-PHix process, stabilisation/solidification using cementitious binders and a range of thermal treatment processes are reviewed. Thermal treatment technologies convert APC residues combined with other wastes into inert glass or glass-ceramics that encapsulate heavy metals. The waste management industry will inevitably use the cheapest available option for treating APC residues and strict interpretation and enforcement of waste legislation is required if new, potentially more sustainable technologies are to become commercially viable.

Air pollution control residues from waste incineration: Current UK situation and assessment of alternative technologies

International Nuclear Information System (INIS)

Amutha Rani, D.; Boccaccini, A.R.; Deegan, D.; Cheeseman, C.R.

2008-01-01

Current disposal options for APC residues in the UK and alternative treatment technologies developed world-wide have been reviewed. APC residues are currently landfilled in the UK where they undergo in situ solidification, although the future acceptability of this option is uncertain because the EU waste acceptance criteria (WAC) introduce strict limits on leaching that are difficult to achieve. Other APC residue treatment processes have been developed which are reported to reduce leaching to below relevant regulatory limits. The Ferrox process, the VKI process, the WES-PHix process, stabilisation/solidification using cementitious binders and a range of thermal treatment processes are reviewed. Thermal treatment technologies convert APC residues combined with other wastes into inert glass or glass-ceramics that encapsulate heavy metals. The waste management industry will inevitably use the cheapest available option for treating APC residues and strict interpretation and enforcement of waste legislation is required if new, potentially more sustainable technologies are to become commercially viable

Biological conversion of poultry and animal waste to a feedstuff for poultry

Energy Technology Data Exchange (ETDEWEB)

El Boushy, A.R.; Klaassen, G.J.; Ketelaars, E.H.

1985-06-01

Poultry and animal waste can be converted into a high protein feed-stuff by biological digestion and degradation, oxidation or by the action of micro-organisms and algae. These processes might help to solve the accummulating problem of disposal of poultry and animal waste, which in some cases are not suitable as soil fertilizers and cause pollution problems. International co-operation between advanced industrialized countries and developing areas is not only desirable but essential to overcome malnutrition by increasing the animal protein supply in the form of meat and eggs. Only a limited number of published data are available but nevertheless five types of treated waste are considered useful under certain conditions as feedstuffs for poultry: 1. housefly pupae meal - caged layer manure degraded by housefly larvae; 2. earthworm meal - another biodegradation of caged layer manure; 3. liquor and residue from a ditch used for oxidizing swine liquid manure; 4. aerobic fermentation of poultry manure; and 5. meals produced from algae grown in ponds of sedimented animal waste and sewage. 46 references.

STUDY OF ASPHALT BINDER OIL RESIDUE AND MUNICIPAL SOLID WASTE ASH TO BE USED IN LOW TRAFFIC PAVEMENTS

Directory of Open Access Journals (Sweden)

Michéle Dal Toé Casagrande

2014-12-01

Full Text Available The great generation of urban solid has been a concern in several countries. This work presents a study with two materials: the asphalt binder oil residue accumulated in the bottom of asphalt tanks and the municipal solid waste ash, to be used, respectively, as a substitute of conventional binder in asphalt mixtures and for soil stabilization in pavements base layers. Were evaluated properties as the mechanical behavior of the mixtures through experimental tests. The results show the potential of incorporating these residues for low traffic roads, allowing the construction of low cost roads and an environmental use of the residue.

Characterization of Solids in Residual Wastes from Single-Shell Tanks at the Hanford Site, Washington, USA - 9277

International Nuclear Information System (INIS)

Krupka, Kenneth M.; Cantrell, Kirk J.; Schaef, Herbert T.; Arey, Bruce W.; Heald, Steve M.; Deutsch, William J.; Lindberg, Michael J.

2009-01-01

Solid-phase characterization methods have been used in an ongoing study of residual wastes (i.e., waste remaining after final retrieval operations) from the underground single-shell storage tanks 241-C-103, 241-C-106, 241-C-202, 241-C-203, and 241-S-112 at the U.S. Department of Energy's Hanford Site in Washington State. The results of studies completed to date show significant variability in the compositions of those residual wastes and the compositions, morphologies, and crystallinities of the individual phases that make up these wastes. These differences undoubtedly result from the various waste types stored and transferred in and out each tank and the sluicing and retrieval operations used for waste retrieval. Our studies indicate that these residual wastes are chemically-complex assemblages of crystalline and amorphous solids that contain contaminants as discrete phases and/or co-precipitated within oxide phases. Depending on the specific tank, various solids (e.g., gibbsite; boehmite; dawsonite; cancrinite; Fe oxides such as hematite, goethite, and maghemite; rhodochrosite; lindbergite; whewellite; nitratine; and numerous amorphous or poorly crystalline phases) have been identified by X-ray diffraction and scanning electron microscopy/energy dispersive X-ray spectroscopy in residual wastes studied to date. Our studies also show that contact of residual wastes with Ca(OH)2- and CaCO3-saturated aqueous solutions, which were used as surrogates for the compositions of pore-fluid leachants derived from young and aged cements respectively, may alter the compositions of solid phases present in the contacted wastes. Fe oxides/hydroxides have been identified in all residual wastes studied to date. They occur in these wastes as discrete particles, particles intergrown within a matrix of other phases, and surface coatings on other particles or particle aggregates. These Fe oxides/hydroxides typically contain trace concentrations of other transition metals, such Cr, Mn

Biological intrusion of low-level-waste trench covers

International Nuclear Information System (INIS)

Hakonson, T.E.; Gladney, E.S.

1981-01-01

The long-term integrity of low-level waste shallow land burial sites is dependent on the interaction of physical, chemical, and biological factors that modify the waste containment system. Past research on low-level waste shallow land burial methods has emphasized physical (i.e., water infiltration, soil erosion) and chemical (radionuclide leaching) processes that can cause waste site failure and subsequent radionuclide transport. The purpose of this paper is to demonstrate the need to consider biological processes as being potentially important in reducing the integrity of waste burial site cover treatments. Plants and animals not only can transport radionuclides to the ground surface via root systems and soil excavated from the cover profile by animal burrowing activities, but they modify physical and chemical processes within the cover profile by changing the water infiltration rates, soil erosion rates and chemical composition of the soil. One approach to limiting biological intrusion through the waste cover is to apply a barrier within the profile to limit root and animal penetration with depth. Experiments in the Los Alamos Experimental Engineered Test Facility were initiated to develop and evaluate biological barriers that are effective in minimizing intrusion into waste trenches. The experiments that are described employ four different candidate barrier materials of geologic origin. Experimental variables that will be evaluated, in addition to barrier type, are barrier depth and soil overburden depth. The rate of biological intrusion through the various barrier materials is being evaluated through the use of activatable stable tracers

Mixed-waste treatment -- What about the residuals? A comparative analysis of MSO and incineration

Energy Technology Data Exchange (ETDEWEB)

NONE

1993-06-01

This report examines the issues concerning final waste forms, or residuals, that result from the treatment of mixed waste in molten salt oxidation (MSO) and incinerator systems. MSO is a technology with the potential to treat a certain segment of the waste streams at US Department of Energy (DOE) sites. MSO was compared with incineration because incineration is the best demonstrated available technology (BDAT) for the same waste streams. The Grand Junction Projects Office (GJPO) and Oak Ridge National Laboratory (ORNL) prepared this report for the DOE Office of Environmental Restoration (OER). The goals of this study are to objectively evaluate the anticipated residuals from MSO and incineration, examine regulatory issues for these final waste forms, and determine secondary treatment options. This report, developed to address concerns that MSO residuals present unique disposal difficulties, is part of a larger effort to successfully implement MSO as a treatment technology for mixed and hazardous waste. A Peer Review Panel reviewed the MSO technology in November 1991, and the implementation effort is ongoing under the guidance of the MSO Task Force.

Mixed-waste treatment -- What about the residuals? A comparative analysis of MSO and incineration

International Nuclear Information System (INIS)

1993-06-01

This report examines the issues concerning final waste forms, or residuals, that result from the treatment of mixed waste in molten salt oxidation (MSO) and incinerator systems. MSO is a technology with the potential to treat a certain segment of the waste streams at US Department of Energy (DOE) sites. MSO was compared with incineration because incineration is the best demonstrated available technology (BDAT) for the same waste streams. The Grand Junction Projects Office (GJPO) and Oak Ridge National Laboratory (ORNL) prepared this report for the DOE Office of Environmental Restoration (OER). The goals of this study are to objectively evaluate the anticipated residuals from MSO and incineration, examine regulatory issues for these final waste forms, and determine secondary treatment options. This report, developed to address concerns that MSO residuals present unique disposal difficulties, is part of a larger effort to successfully implement MSO as a treatment technology for mixed and hazardous waste. A Peer Review Panel reviewed the MSO technology in November 1991, and the implementation effort is ongoing under the guidance of the MSO Task Force

High-temperature vitrification of Hanford residual-liquid waste in a continuous melter

International Nuclear Information System (INIS)

Barnes, S.M.

1980-04-01

Over 270 kg of high-temperature borosilicate glass have been produced in a series of three short-term tests in the High-Temperature Ceramic Melter vitrification system at PNL. The glass produced was formulated to vitrify simulated Hanford residual-liquid waste. The tests were designed to (1) demonstrate the feasibility of utilizing high-temperature, continuous-vitrification technology for the immobilization of the residual-liquid waste, (2) test the airlift draining technique utilized by the high-temperature melter, (3) compare glass produced in this process to residual-liquid glass produced under laboratory conditions, (4) investigate cesium volatility from the melter during waste processing, and (5) determine the maximum residual-liquid glass production rate in the high-temperature melter. The three tests with the residual-liquid composition confirmed the viability of the continuous-melting vitrification technique for the immobilization of this waste. The airlift draining technique was demonstrated in these tests and the glass produced from the melter was shown to be less porous than the laboratory-produced glass. The final glass produced from the second test was compared to a glass of the same composition produced under laboratory conditions. The comparative tests found the glasses to be indistinguishable, as the small differences in the test results fell within the precision range of the characterization testing equipment. The cesium volatility was examined in the final test. This examination showed that 0.44 wt % of the cesium (assumed to be cesium oxide) was volatilized, which translates to a volatilization rate of 115 mg/cm 2 -h

Evaluation of resource recovery from waste incineration residues--the case of zinc.

Science.gov (United States)

Fellner, J; Lederer, J; Purgar, A; Winterstetter, A; Rechberger, H; Winter, F; Laner, D

2015-03-01

Solid residues generated at European Waste to Energy plants contain altogether about 69,000 t/a of Zn, of which more than 50% accumulates in air pollution control residues, mainly boiler and filter ashes. Intensive research activities aiming at Zn recovery from such residues recently resulted in a technical scale Zn recovery plant at a Swiss waste incinerator. By acidic leaching and subsequent electrolysis this technology (FLUREC) allows generating metallic Zn of purity>99.9%. In the present paper the economic viability of the FLUREC technology with respect to Zn recovery from different solid residues of waste incineration has been investigated and subsequently been categorised according to the mineral resource classification scheme of McKelvey. The results of the analysis demonstrate that recovery costs for Zn are highly dependent on the costs for current fly ash disposal (e.g. cost for subsurface landfilling). Assuming current disposal practice costs of 220€/ton fly ash, resulting recovery costs for Zn are generally higher than its current market price of 1.6€/kg Zn. With respect to the resource classification this outcome indicates that none of the identified Zn resources present in incineration residues can be economically extracted and thus cannot be classified as a reserve. Only for about 4800 t/a of Zn an extraction would be marginally economic, meaning that recovery costs are only slightly (less than 20%) higher than the current market price for Zn. For the remaining Zn resources production costs are between 1.5 and 4 times (7900 t/a Zn) and 10-80 times (55,300 t/a Zn) higher than the current market value. The economic potential for Zn recovery from waste incineration residues is highest for filter ashes generated at grate incinerators equipped with wet air pollution control. Copyright © 2014 Elsevier Ltd. All rights reserved.

Gasification of fruit wastes and agro-food residues in supercritical water

International Nuclear Information System (INIS)

Nanda, Sonil; Isen, Jamie; Dalai, Ajay K.; Kozinski, Janusz A.

2016-01-01

Highlights: • Supercritical water gasification of various fruit wastes and agro-food residues. • Coconut shell had superior carbon content and calorific value due to high lignin. • Maximum H_2 yields at 600 °C with 1:10 biomass-to-water ratio, 45 min and 23–25 MPa. • High H_2 yields from coconut shell, bagasse and aloe vera rind with 2 wt% K_2CO_3. • High CH_4 yields from coconut shell with 2 wt% NaOH due to methanation reaction. - Abstract: Considerable amounts of fruit wastes and agro-food residues are generated worldwide as a result of food processing. Converting the bioactive components (e.g., carbohydrates, lipids, fats, cellulose, hemicellulose and lignin) in food wastes to biofuels is a potential remediation approach. This study highlights the characterization and hydrothermal conversion of several fruit wastes and agro-food residues such as aloe vera rind, banana peel, coconut shell, lemon peel, orange peel, pineapple peel and sugarcane bagasse to hydrogen-rich syngas through supercritical water gasification. The agro-food wastes were gasified in supercritical water to study the impacts of temperature (400–600 °C), biomass-to-water ratio (1:5 and 1:10) and reaction time (15–45 min) at a pressure range of 23–25 MPa. The catalytic effects of NaOH and K_2CO_3 were also investigated to maximize the hydrogen yields and selectivity. The elevated temperature (600 °C), longer reaction time (45 min) and lower feed concentration (1:10 biomass-to-water ratio) were optimal for higher hydrogen yield (0.91 mmol/g) and total gas yield (5.5 mmol/g) from orange peel. However, coconut shell with 2 wt% K_2CO_3 at 600 °C and 1:10 biomass-to-water ratio for 45 min revealed superior hydrogen yield (4.8 mmol/g), hydrogen selectivity (45.8%) and total gas yield (15 mmol/g) with enhanced lower heating value of the gas product (1595 kJ/Nm"3). The overall findings suggest that supercritical water gasification of fruit wastes and agro-food residues could serve as

Utilisation of biological and secondary raw materials VI. Recycling - conversion to energy; Bio- und Sekundaerrohstoffverwertung VI. Stofflich - energetisch

Energy Technology Data Exchange (ETDEWEB)

Wiemer, Klaus; Kern, Michael

2011-07-01

In a lot of contributions the Kasseler waste and bio-energy forum reports on a sustainable management of wastes. The organizers hope that this results in a lively dialogue on sustainable activities in waste management corresponding to the responsibility towards future generations. Within the 23rd Kasseler waste and bio-energy forum at 12th to 14th April, 2010 in Kassel (Federal Republic of Germany) lectures were held to the following themes: (1) Perspectives of the waste management; (2) Ressource conservation and securing of raw material; (3) Common capture of packages and high-grade materials; (4) Bin for reusable materials - system trusteeship, material flows, qualities, financing, practical examples; (5) Industrial waste flows, EBS quality assurance and increase of efficiency; (6) New technological developments in the area of fermentation of biological wastes; (7) Perspectives of material and energetical utilization of biological wastes; (8) Renewable Energy Law and direct marketing of 'green' electricity; (9) Technology and experiences with biogas processing; (10) Fermentation of biogenic residues and catering waste; (11) Increase of efficiency of mechanical-biological treatment plants; (12) Mechanical-biological treatment technology in an international environment; (13) Concepts of energetic utilization for landfill sites; (14) Landfill law and landfill after-care; (15) Renaturation of landfills.

Geochemical Testing And Model Development - Residual Tank Waste Test Plan

International Nuclear Information System (INIS)

Cantrell, K.J.; Connelly, M.P.

2010-01-01

This Test Plan describes the testing and chemical analyses release rate studies on tank residual samples collected following the retrieval of waste from the tank. This work will provide the data required to develop a contaminant release model for the tank residuals from both sludge and salt cake single-shell tanks. The data are intended for use in the long-term performance assessment and conceptual model development.

Soil mechanical properties of MBT waste from Luxembourg, Germany and Thailand

Directory of Open Access Journals (Sweden)

Pattaraporn Pimolthai

2014-12-01

Full Text Available Mechanical and biological treatments (MBT of waste have become well known in Europe and Asia. The maximum particle size of waste is reduced by the removal of larger plastic materials from municipal solid waste during mechanical processing. The mechanical properties of the MBT waste are significantly changed by this process. An effective treatment system can lead to a better quality of output materials which do not cause environmental problems. This paper shows the comparative mechanical properties of MBT wastes from Luxembourg, Germany and Thailand. This research focused on the smaller 10 mm-fraction of MBT samples, in order to describe and evaluate the potential application of the small size material as a cover liner in landfill sites. Therefore the smaller 10 mm-fraction of MBT samples were tested for geotechnical properties. The small size waste particles were analysed in laboratory tests in order to determine their particle size, particle shape, compaction, permeability, shear strength, porosity and water absorption capacity, including comparison with the properties of soil material. The results showed that reduced particles were likely to act as a compact, low permeable material with a high potential for water absorption. The amount of remaining fibre and foil components in the materials cause different mechanical and hydraulic behaviours in the samples. The leachate of MBT samples showed very low concentrations of chemical oxygen demand, ammonium, and heavy metals, compared to the landfill leachate of untreated waste.

Hanford Site Tank 241-C-108 Residual Waste Contaminant Release Models and Supporting Data

Energy Technology Data Exchange (ETDEWEB)

Cantrell, Kirk J.; Krupka, Kenneth M.; Geiszler, Keith N.; Arey, Bruce W.; Schaef, Herbert T.

2010-06-18

This report presents the results of laboratory characterization, testing, and analysis for a composite sample (designated 20578) of residual waste collected from single-shell tank C-108 during the waste retrieval process after modified sluicing. These studies were completed to characterize concentration and form of contaminant of interest in the residual waste; assess the leachability of contaminants from the solids; and develop release models for contaminants of interest. Because modified sluicing did not achieve 99% removal of the waste, it is expected that additional retrieval processing will take place. As a result, the sample analyzed here is not expected to represent final retrieval sample.

Microbiological parameters and maturity degree during composting of Posidonia oceanica residues mixed with vegetable wastes in semi-arid pedo-climatic condition.

Science.gov (United States)

Saidi, Neyla; Kouki, Soulwene; M'hiri, Fadhel; Jedidi, Naceur; Mahrouk, Meriam; Hassen, Abdennaceur; Ouzari, Hadda

2009-01-01

The aim of this study was to characterize the biological stability and maturity degree of compost during a controlled pile-composting trial of mixed vegetable residues (VR) collected from markets of Tunis City with residues of Posidonia oceanica (PoR), collected from Tunis beaches. The accumulation in beaches (as well as their removal) constitutes a serious environmental problem in all Mediterranean countries particularly in Tunisia. Aerobic-thermophilic composting is the most reasonable way to profit highly-valuable content of organic matter in these wastes for agricultural purposes. The physical, chemical, and biological parameters were monitored during composting over 150 d. The most appropriate parameters were selected to establish the maturity degree. The main result of this research was the deduction of the following maturity criterion: (a) C/N ratio 80%. These five parameters, considered jointly are indicative of a high maturity degree and thus of a high-quality organic amendment which employed in a rational way, may improve soil fertility and soil quality. The mature compost was relatively rich in N (13.0 g/kg), P (4.74 g/kg) and MgO (15.80 g/kg). Thus composting definitively constitutes the most optimal option to exploit these wastes.

Radioactive wastes and residues: government participation in a control policy

International Nuclear Information System (INIS)

Gelli, Guido

1993-01-01

This paper discusses the politic aspects of the State participation in inspection and control of the radioactive wastes residues with the supervise of Brazilian Nuclear Energy Commission (CNEN), by a national program

Solid radioactive waste: evaluation of residual activity in nuclear medicine services

International Nuclear Information System (INIS)

Alabarse, Frederico G.; Xavier, Ana M.; Magalhaes, Maisa H.; Guerrero, Jesus S.P.

2009-01-01

An experimental programme to estimate, with a better degree of accuracy, the activity that remains adsorbed in flasks and syringes used in Nuclear Medicine Services for the administration of radionuclides to patients submitted to diagnostic or therapy is been conducted under the coordination of the Radioactive Waste Division of the Brazilian Nuclear Energy Commission, CNEN. The adopted recommendation in Brazil to allow an expedite solid waste management in nuclear medicine facilities, up to the present, is to consider that 2% of the initial activity remains adsorbed in the solid waste, which easily allows the calculation of the storage time to achieve regulatory clearance levels by decay. This research evaluates 17 different kinds of radiopharmaceuticals and three radioisotopes: 99m Tc, 67 Ga and 201 Tl. Results obtained by means of a weighting method to estimate the residual mass in flasks show that the ratio of the mass of the liquid that remains in the solid waste to the mass of the empty flask is constant. This suggests that the residual activity depends on the initial activity concentration of radiopharmaceutical contained in each flask, as assumed by the regulatory body. Additionally, results obtained by determining the remaining activity in flasks, shortly after the injection of its radionuclide contents in patients, indicate that an average value for the residual activity of the order of 10% of the initial activity contained in the flasks or syringes should be adopted to determine the decay storage time before the release of solid waste in the urban conventional land fill disposal system. The 'rule of thumb' of 10 half-lives for storage before clearance is also discussed in the present work. (author)

Hanford Tank 241-C-106: Impact of Cement Reactions on Release of Contaminants from Residual Waste

International Nuclear Information System (INIS)

Deutsch, William J.; Krupka, Kenneth M.; Lindberg, Michael J.; Cantrell, Kirk J.; Brown, Christopher F.; Schaef, Herbert T.

2006-01-01

The CH2M HILL Hanford Group, Inc. (CH2M HILL) is producing risk/performance assessments to support the closure of single-shell tanks at the U.S. Department of Energy's Hanford Site. As part of this effort, staff at Pacific Northwest National Laboratory were asked to develop release models for contaminants of concern that are present in residual sludge remaining in tank 241-C-106 (C-106) after final retrieval of waste from the tank. Initial work to produce release models was conducted on residual tank sludge using pure water as the leaching agent. The results were reported in an earlier report. The decision has now been made to close the tanks after waste retrieval with a cementitious grout to minimize infiltration and maintain the physical integrity of the tanks. This report describes testing of the residual waste with a leaching solution that simulates the composition of water passing through the grout and contacting the residual waste at the bottom of the tank.

Using vacuum pyrolysis and mechanical processing for recycling waste printed circuit boards

International Nuclear Information System (INIS)

Long Laishou; Sun Shuiyu; Zhong Sheng; Dai Wencan; Liu Jingyong; Song Weifeng

2010-01-01

The constant growth in generation of waste printed circuit boards (WPCB) poses a huge disposal problem because they consist of a heterogeneous mixture of organic and metallic chemicals as well as glass fiber. Also the presence of heavy metals, such as Pb and Cd turns this scrap into hazardous waste. Therefore, recycling of WPCB is an important subject not only from the recovery of valuable materials but also from the treatment of waste. The aim of this study was to present a recycling process without negative impact to the environment as an alternative for recycling WPCB. In this work, a process technology containing vacuum pyrolysis and mechanical processing was employed to recycle WPCB. At the first stage of this work, the WPCB was pyrolyzed under vacuum in a self-made batch pilot-scale fixed bed reactor to recycle organic resins contained in the WPCB. By vacuum pyrolysis the organic matter was decomposed to gases and liquids which could be used as fuels or chemical material resources, however, the inorganic WPCB matter was left unaltered as solid residues. At the second stage, the residues obtained at the first stage were investigated to separate and recover the copper through mechanical processing such as crushing, screening, and gravity separation. The copper grade of 99.50% with recovery of 99.86% based on the whole WPCB was obtained. And the glass fiber could be obtained by calcinations in a muffle furnace at 600 deg. C for 10 min. This study had demonstrated the feasibility of vacuum pyrolysis and mechanical processing for recycling WPCB.

Research on Toxicity Evaluation of Waste Incineration Residues of Printed Circuit Boards

Directory of Open Access Journals (Sweden)

Rasa Volungevičienė

2014-10-01

Full Text Available Recycling waste printed circuit boards (PCB is an extremely complicated process, because PCBs consist of a number of complex components – hazardous and non-hazardous materials sets. Pyrolysis and combustion are currently the most effective treatment technologies for waste printed circuit boards. Pyrolysis can be used for thermally decomposing PCBs allowing for the simultaneous recovery of valuable materials. Following the extraction of valuable materials, the problem of residual ash utilization is encountered. Determining the qualitative and quantitative characteristics of incineration residue helps with choosing effective ash management technologies. This paper analyzes PCB ash generated at three different temperatures of 400 °C, 500 °C and 600 °C. Ash residues have been analysed to determine the quantity and type of metals present. Furthermore, the experiment of leaching heavy metals from ash has been described.

Physico-chemical characterisation of material fractions in residual and source-segregated household waste in Denmark

DEFF Research Database (Denmark)

Götze, Ramona; Pivnenko, Kostyantyn; Boldrin, Alessio

2016-01-01

differences in the physico-chemical properties of residual and source-segregated waste fractions were found for many parameters related to organic matter, but also for elements of environmental concern. Considerable differences in potentially toxic metal concentrations between the individual recyclable......Physico-chemical waste composition data are paramount for the assessment and planning of waste management systems. However, the applicability of data is limited by the regional, temporal and technical scope of waste characterisation studies. As Danish and European legislation aims for higher...... recycling rates evaluation of source-segregation and recycling chains gain importance. This paper provides a consistent up-to-date dataset for 74 physico-chemical parameters in 49 material fractions from residual and 24 material fractions from source-segregated Danish household waste. Significant...

Re-use of construction and demolition residues and industrial wastes for the elaboration or recycled eco-efficient concretes

Energy Technology Data Exchange (ETDEWEB)

Juan Valdes, A.; Medina Martinez, C.; Guerra Romero, M. I.; Llamas Garcia, B.; Moran del Pozo, J. M.; Tascon Vegas, A.

2010-07-01

Production of residues from industries and construction and demolition sectors has increased during last years. The total amount of debris produced according to different estimations reaches values close to 42 million tonnes yr{sup -}1. Much of this waste has been thrown to landfill, without considering its potential for reuse, recycling or valuation. The aim of this research is to describe some of the physical and mechanical properties of different laboratory-mixed concretes, using various proportions of additional materials recovered from industrial waste and demolition rubble. The added materials are included either as admixtures (forestry residues, cork dust, steel fibre) or in partial substitution of natural aggregates (wire from electrical residues, tyre rubber, white ceramic, sanitary porcelain or shale). The laboratory tests have followed the standard EN protocols. Assay results were variable according to the nature of the material added to the mix: organic materials and shale, despite the steel fibre reinforcement, reduce the compression strength, but are suitable for the manufacture of lightweight concrete for agricultural pavements, with certain flexion resistance and a relatively good behaviour to impact. The substitution of natural aggregates with ceramic and porcelain wastes produces a significant increase in compression resistance, making them suitable for the manufacture of concrete with characteristic resistances above 40 MPa, which can be used both for structures or other agricultural elements: separators, feeders, slat floors. As a conclusion can be stated the possibility of reuse these wastes for the production of structural or non-structural concrete, with different applications in agricultural engineering. (Author) 36 refs.

Re-use of construction and demolition residues and industrial wastes for the elaboration or recycled eco-efficient concretes

International Nuclear Information System (INIS)

Juan Valdes, A.; Medina Martinez, C.; Guerra Romero, M. I.; Llamas Garcia, B.; Moran del Pozo, J. M.; Tascon Vegas, A.

2010-01-01

Production of residues from industries and construction and demolition sectors has increased during last years. The total amount of debris produced according to different estimations reaches values close to 42 million tonnes yr - 1. Much of this waste has been thrown to landfill, without considering its potential for reuse, recycling or valuation. The aim of this research is to describe some of the physical and mechanical properties of different laboratory-mixed concretes, using various proportions of additional materials recovered from industrial waste and demolition rubble. The added materials are included either as admixtures (forestry residues, cork dust, steel fibre) or in partial substitution of natural aggregates (wire from electrical residues, tyre rubber, white ceramic, sanitary porcelain or shale). The laboratory tests have followed the standard En protocols. Assay results were variable according to the nature of the material added to the mix: organic materials and shale, despite the steel fibre reinforcement, reduce the compression strength, but are suitable for the manufacture of lightweight concrete for agricultural pavements, with certain flexion resistance and a relatively good behaviour to impact. The substitution of natural aggregates with ceramic and porcelain wastes produces a significant increase in compression resistance, making them suitable for the manufacture of concrete with characteristic resistances above 40 MPa, which can be used both for structures or other agricultural elements: separators, feeders, slat floors. As a conclusion can be stated the possibility of reuse these wastes for the production of structural or non-structural concrete, with different applications in agricultural engineering. (Author) 36 refs.

Contaminant Release from Residual Waste in Closed Single-Shell Tanks and Other Waste Forms Associated with the Tanks

International Nuclear Information System (INIS)

Deutsch, William J.

2008-01-01

This chapter describes the release of contaminants from the various waste forms that are anticipated to be associated with closure of the single-shell tanks. These waste forms include residual sludge or saltcake that will remain in the tanks after waste retrieval. Other waste forms include engineered glass and cementitious materials as well as contaminated soil impacted by previous tank leaks. This chapter also describes laboratory testing to quantify contaminant release and how the release data are used in performance/risk assessments for the tank waste management units and the onsite waste disposal facilities. The chapter ends with a discussion of the surprises and lessons learned to date from the testing of waste materials and the development of contaminant release models

Separate collection of plastic waste, better than technical sorting from municipal solid waste?

Science.gov (United States)

Feil, Alexander; Pretz, Thomas; Jansen, Michael; Thoden van Velzen, Eggo U

2017-02-01

The politically preferred solution to fulfil legal recycling demands is often implementing separate collection systems. However, experience shows their limitations, particularly in urban centres with a high population density. In response to the European Union landfill directive, mechanical biological waste treatment plants have been installed all over Europe. This technology makes it possible to retrieve plastic waste from municipal solid waste. Operators of mechanical biological waste treatment plants, both in Germany and the Netherlands, have started to change their mechanical separation processes to additionally produce plastic pre-concentrates. Results from mechanical biological waste treatment and separate collection of post-consumer packaging waste will be presented and compared. They prove that both the yield and the quality of plastic waste provided as feedstock for the production of secondary plastic raw material are largely comparable. An economic assessment shows which conditions for a technical sorting plant are economically attractive in comparison to separate collection systems. It is, however, unlikely that plastic recycling will ever reach cost neutrality.

Auto shredder residue recycling: Mechanical separation and pyrolysis

International Nuclear Information System (INIS)

Santini, Alessandro; Passarini, Fabrizio; Vassura, Ivano; Serrano, David; Dufour, Javier; Morselli, Luciano

2012-01-01

Highlights: ► In this work, we exploited mechanical separation and pyrolysis to recycle ASR. ► Pyrolysis of the floating organic fraction is promising in reaching ELV Directive targets. ► Zeolite catalyst improve pyrolysis oil and gas yield. - Abstract: sets a goal of 85% material recycling from end-of-life vehicles (ELVs) by the end of 2015. The current ELV recycling rate is around 80%, while the remaining waste is called automotive shredder residue (ASR), or car fluff. In Europe, this is mainly landfilled because it is extremely heterogeneous and often polluted with car fluids. Despite technical difficulties, in the coming years it will be necessary to recover materials from car fluff in order to meet the ELV Directive requirement. This study deals with ASR pretreatment and pyrolysis, and aims to determine whether the ELV material recycling target may be achieved by car fluff mechanical separation followed by pyrolysis with a bench scale reactor. Results show that flotation followed by pyrolysis of the light, organic fraction may be a suitable ASR recycling technique if the oil can be further refined and used as a chemical. Moreover, metals are liberated during thermal cracking and can be easily separated from the pyrolysis char, amounting to roughly 5% in mass. Lastly, pyrolysis can be a good starting point from a “waste-to-chemicals” perspective, but further research should be done with a focus on oil and gas refining, in order both to make products suitable for the chemical industry and to render the whole recycling process economically feasible.

Dynamic effects of soil bulk density on denitrification and mineralisation by 15N labelled lettuce residue and paper wastes

International Nuclear Information System (INIS)

Hua Luo; Cheng Qing; Vinten, A.J.A.

1997-10-01

Two laboratory incubation experiments aimed to study the denitrification and mineralisation influenced by different additives ( 15 N labelled lettuce residue, paper wastes and mixture of both) and soil bulk densities were carried out by means of acetylene inhibition at the constant 15 degree C for 107 and 90 days, respectively. The results showed that the changes of N 2 O, CO 2 emission rates, inorganic nitrogen (NO 3 - and NH 4 + ), total N and 15 N abundance in the soils which were affected by adding lettuce residue, paper wastes and mixture of both were investigated. Soil denitrification rate increased after lettuce residue was added into soil for 8 days. The maximum rate of N 2 O emission was 15 times higher than that in soil without any additive. However, paper wastes did not increase N 2 O emission in the first 8 days compared with other treatments, mixed residue and paper wastes could promote soil microbial activity, but N 2 O emission was lower than that in the soil with lettuce residue added and higher than that with paper wastes, indicating that mixture of residue and paper wastes was benefit to soil nitrogen immobilisation. CO 2 emission in all the treatments were declined to the same level on the 107 th day. In the treatment added mixed residues and paper wastes, the released CO 2 quantities were higher than those in other treatments every day. Effect of different bulk density on N 2 O and CO 2 emission were response to the change of bulk density, it seems that N 2 O and CO 2 emission increased with bulk density. High bulk density could affect decomposition of paper wastes and NO 3 - , NH 4 + concentration. (30 ref., 10 tabs.)

Process for the biological purification of waste water

DEFF Research Database (Denmark)

1992-01-01

Process for the biological purification of waste water by the activated sludge method, the waste water being mixed with recirculated sludge and being subjected to an anaerobic treatment, before the waste water thus treated is alternately subjected to anoxic and aerobic treatments and the waste...... water thus treated is led into a clarification zone for settling sludge, which sludge is recirculated in order to be mixed with the crude waste water. As a result, a simultaneous reduction of the content both of nitrogen and phosphorus of the waste water is achieved....

Assessment of residual DDE at four remediated Hanford waste sites, Richland, Washington

International Nuclear Information System (INIS)

Linville, J.K.

1999-01-01

The objectives of this study were to determine the extent and distribution of residual DDE, a metabolite of dichlorodiphenyltrichloroethane (DDT), across the four waste sites by sampling ground-dwelling insects and bird eggs, evaluating the use of insects for monitoring contamination pathways, and determining the species of passerine birds present and the number of nesting pairs utilizing the waste sites

40 CFR Appendix Vii to Part 266 - Health-Based Limits for Exclusion of Waste-Derived Residues*

Science.gov (United States)

2010-07-01

... Waste-Derived Residues* VII Appendix VII to Part 266 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR THE MANAGEMENT OF SPECIFIC HAZARDOUS WASTES AND SPECIFIC TYPES OF HAZARDOUS WASTE MANAGEMENT FACILITIES Pt. 266, App. VII Appendix VII to Part 266—Health...

Effects of moisture content of food waste on residue separation, larval growth and larval survival in black soldier fly bioconversion.

Science.gov (United States)

Cheng, Jack Y K; Chiu, Sam L H; Lo, Irene M C

2017-09-01

In order to foster sustainable management of food waste, innovations in food waste valorization technologies are crucial. Black soldier fly (BSF) bioconversion is an emerging technology that can turn food waste into high-protein fish feed through the use of BSF larvae. The conventional method of BSF bioconversion is to feed BSF larvae with food waste directly without any moisture adjustment. However, it was reported that difficulty has been experienced in the separation of the residue (larval excreta and undigested material) from the insect biomass due to excessive moisture. In addition to the residue separation problem, the moisture content of the food waste may also affect the growth and survival aspects of BSF larvae. This study aims to determine the most suitable moisture content of food waste that can improve residue separation as well as evaluate the effects of the moisture content of food waste on larval growth and survival. In this study, pre-consumer and post-consumer food waste with different moisture content (70%, 75% and 80%) was fed to BSF larvae in a temperature-controlled rotary drum reactor. The results show that the residue can be effectively separated from the insect biomass by sieving using a 2.36mm sieve, for both types of food waste at 70% and 75% moisture content. However, sieving of the residue was not feasible for food waste at 80% moisture content. On the other hand, reduced moisture content of food waste was found to slow down larval growth. Hence, there is a trade-off between the sieving efficiency of the residue and the larval growth rate. Furthermore, the larval survival rate was not affected by the moisture content of food waste. A high larval survival rate of at least 95% was achieved using a temperature-controlled rotary drum reactor for all treatment groups. The study provides valuable insights for the waste management industry on understanding the effects of moisture content when employing BSF bioconversion for food waste recycling

Incinerator performance: effects of changes in waste input and furnace operation on air emissions and residues

DEFF Research Database (Denmark)

Astrup, Thomas; Riber, Christian; Pedersen, Anne Juul

2011-01-01

Waste incineration can be considered a robust technology for energy recovery from mixed waste. Modern incinerators are generally able to maintain relatively stable performance, but changes in waste input and furnace operation may affect emissions. This study investigated how inorganic air emissions...... including ‘as-large-as-possible’ changes in furnace operation (oxygen levels, air supply and burnout level) only using normal MSW as input. The experiments showed that effects from the added waste materials were significant in relation to: air emissions (in particular As, Cd, Cr, Hg, Sb), element transfer...... coefficients, and residue composition (As, Cd, Cl, Cr, Cu, Hg, Mo, Ni, Pb, S, Sb, Zn). Changes in furnace operation could not be directly linked to changes in emissions and residues. The results outlined important elements in waste which should be addressed in relation to waste incinerator performance. Likely...

Treatment of waste incinerator air-pollution-control residues with FeSO4: Concept and product characterization

DEFF Research Database (Denmark)

Lundtorp, Kasper; Jensen, Dorthe Lærke; Sørensen, Mette Abildgaard

2002-01-01

This paper describes a new concept for treatment of air- pollution-control (APC) residues from waste incineration and characterises the wastewater and stabilised residues generated by the process. The process involves mixing of APC-residues with a ferrous sulphate solution and subsequent oxidation...

Evaluation of waste management options in view of long-term maintenance-free landfills

International Nuclear Information System (INIS)

Brunner, P.H.; Doeberl, G.; Huber, R.; Eder, M.; Pierrard, R.; Schoenbaeck, W.; Fruehwirth, W.; Hutterer, H.; Woeginger, H.

2001-01-01

The present case study compares and evaluates different waste management options with special consideration to their long-term implications. Multiple scenarios of these options were created and investigated as to which of term best fulfilled the goals of the Austrian waste management act (Abfallwirtschaftgesetz, AWG). Serving as a basis for this study, an elaborated model of the Austrian waste management, as described in GUA and IFIP (1998, 'Management of Household and Household-like Waste in Austria'), was used. Alterations to the GUA and IFIP study were done in order to best fulfill the needs of this assessment. Household and household-like waste, as well as municipal sewage sludge have been defined as the system input. The following list of scenarios were investigated against an up-dated status-quo (P0): M1 maximum landfilling of untreated waste; M2a maximum incineration without any after treatment; M2b maximum incineration with cement stabilization of the residual material; M2c maximum high temperature process; M3a maximum mechanical-biological treatment with the light fraction from sorting and splitting processed in a fluidized-bed furnace; M3b maximum mechanical-biological treatment with the light fraction from sorting and splitting processed in a rotary kiln for use in the cement industry; M3c maximum mechanical-biological treatment with the high caloric heavy fraction after decomposition processed in a fluidized-bed furnace; M3d maximum mechanical-biological treatment with the high caloric heavy fraction after decomposition processed in a rotary kiln for use in the cement industry. In order to oblige to the precautionary principle of the AWG, each of the scenarios were investigated, with regards to the short, middle, and long-term landfills behaviors of the deposited residual material. The macro-economical Cost-Benefit-Analysis (CBA) was used in the assessment. Additionally a so-called 'modified-Cost-Effect-Analysis' (MCEA) was developed. Unlike the

Recovering metals from sewage sludge, waste incineration residues and similar substances with hyperaccumulative plants

Science.gov (United States)

Kisser, Johannes; Gattringer, Heinz; Iordanopoulos-Kisser, Monika

2015-04-01

Sewage sludges as well as ashes from waste incineration plants are known accumulation sinks of many elements that are either important nutrients for biological organisms (phosphorus, potassium, magnesium, etc.) or valuable metals when considered on their own in pure form (nickel, chrome, zinc, etc.); they are also serious pollutants when they occur in wild mixtures at localized anthropogenic end- of-stream points. Austria and many other countries have to import up to 90% of the material inputs of metals from abroad. These primary resources are becoming more expensive as they become more scarce and remaining deposits more difficult to mine, which is a serious concern for industrialized nations. Basic economic and strategic reasoning demands an increase in recycling activities and waste minimization. Technologies to recover metals in a reasonable and economically relevant manner from very diffuse sources are practically non-existent or require large amounts of energy and chemicals, which pose environmental risks. On the other hand agriculture uses large volumes of mineral fertilizers, which are often sourced from mines as well, and thus are also subject to the same principle of finiteness and potential shortage in supply. These converted biological nutrients are taken up by crops and through the food chain and human consumption end up in sewage systems and in wastewater treatment plants in great quantities. The metabolized nutrients mostly do not return to agriculture, but due to contamination with heavy metals are diverted to be used as construction aggregates or are thermally treated and end up rather uselessly in landfills. The project BIO-ORE aimed to explore new pathways to concentrate metals from diluted sources such as sewage sludge and wastewater by using highly efficient biological absorption and transport mechanisms. These enzymatic systems from plants work with very little energy input. The process is called bioaccumulation and can be most effectively

Glasses obtained from industrial wastes

International Nuclear Information System (INIS)

Bortoluzzi, D.; Oliveira Fillho, J.; Uggioni, E.; Bernardin, A.M.

2009-01-01

This paper deals with the study of the vitrification mechanism as an inertization method for industrial wastes contaminated with heavy metals. Ashes from coal (thermoelectric), wastes from mining (fluorite and feldspar) and plating residue were used to compose vitreous systems planed by mixture design. The chemical composition of the wastes was determined by XRF and the formulations were melted at 1450 deg C for 2h using 10%wt of CaCO 3 (fluxing agent). The glasses were poured into a mold and annealed (600 deg C). The characteristic temperatures were determined by thermal analysis (DTA, air, 20 deg C/min) and the mechanical behavior by Vickers microhardness. As a result, the melting temperature is strongly dependent on silica content of each glass, and the fluorite residue, being composed mainly by silica, strongly affects Tm. The microhardness of all glasses is mainly affected by the plating residue due to the high iron and zinc content of this waste. (author)

Preparation of Baking-Free Brick from Manganese Residue and Its Mechanical Properties

Directory of Open Access Journals (Sweden)

Ping Wang

2013-01-01

Full Text Available The increasing amount of waste residue produced during the electrolytic preparation process of manganese has nowadays brought about serious environmental problems. The research on utilization of manganese slag has been a hot spot around the world. The utilization of manganese slag is not only environment friendly, but also economically feasible. In the current work, a summarization of the main methods to produced building materials from manganese slag materials was given. Baking-free brick, a promising building material, was produced from manganese slag with the addition of quicklime and cement. The physical properties, chemical composition, and mechanical performances of the obtained samples were measured by several analyses and characterization methods. Then the influence of adding materials and molding pressure during the preparation of baking-free brick samples on their compressive strength properties was researched. It is concluded that the baking-free brick prepared from manganese residue could have excellent compressive strength performance under certain formula.

Conditioning of high activity solid waste: fuel claddings and dissolution residues

International Nuclear Information System (INIS)

Anon.

1982-01-01

This chapter reports on experimental studies of embedding into matrix material, the melting and conversion of zircaloy, and waste properties and characterization. Methods are developed for embedding the waste scrap into a solid and resistant matrix material in order to confine the radioactivity and to prevent it from dispersion. The matrix materials investigated are lead alloys, ceramics and compacted graphite or aluminium powder. The treatment of fuel hulls by melting or chemical conversion is described. Cemented hulls are characterized and the pyrophoricity of zircaloy fines is investigated. Topics considered include the embedding of hulls into graphite and aluminium, the embedding of hulls and dissolution residues into alumino-ceramics, the solidification of alpha-bearing wastes into a ceramic matrix, and the conditioning of cladding waste by eutectoidic melting and by embedding in glass

Remaining Sites Verification Package for the 100-F-33, 146-F Aquatic Biology Fish Ponds, Waste Site Reclassification Form 2006-021

Energy Technology Data Exchange (ETDEWEB)

L. M. Dittmer

2006-08-25

The 100-F-33, 146-F Aquatice Biology Fish Ponds waste site was an area with six small rectangular ponds and one large circular pond used to conduct tests on fish using various mixtures of river and reactor effluent water. The current site conditions achieve the remedial action objectives specified in the Remaining Sites ROD. The results of verification and applicable confirmatory sampling show that residual contaminant concentrations do not preclude any future uses and allow for unrestricted use of shallow zone soils. The results also demonstrate that residual contaminant concentrations are protective of groundwater and the Columbia River.

Utilization of stabilized municipal waste combustion ash residues as construction material

International Nuclear Information System (INIS)

Shieh, C.S.

1992-01-01

Stabilized municipal waste combustion (MWC) ash residues were investigated for their potential as construction material that can be beneficially used in terrestrial and marine environments. End-use products, such as patio stones, brick pavers, solid blocks, and reef units, were fabricated and tested for their engineering and chemical characteristics. engineering feasibility and environmental acceptability of using stabilized ash residues as construction material are discussed in this paper. Ash samples were collected from two mass-burn facilities and one refuse derived fuel (RDF) facility in Florida

Thermally induced transformations of iron oxide stabilised APC residues from waste incineration

DEFF Research Database (Denmark)

Sørensen, Mette Abildgaard; Koch, C.B.

2001-01-01

Air pollution control (APC) facilities at waste incinerator plants produce large quantities of solid residues rich in salts and heavy metals. Heavy metals are readily released to water from the residues and it has, therefore, been found suitable to apply a rapid co-precipitation/adsorption process...... as a means to immobilize the toxic elements. In the 'Ferrox process', this immobilization is based on co-precipitation with an Fe(III) oxide formed by oxidation of Fe(II) by air in an aqueous slurry with the APC residue at alkaline pH. In this work we have undertaken a Mossbauer spectroscopy study of the Fe...

Mechanical properties of nuclear waste glasses

International Nuclear Information System (INIS)

Connelly, A.J.; Hand, R.J.; Bingham, P.A.; Hyatt, N.C.

2011-01-01

The mechanical properties of nuclear waste glasses are important as they will determine the degree of cracking that may occur either on cooling or following a handling accident. Recent interest in the vitrification of intermediate level radioactive waste (ILW) as well as high level radioactive waste (HLW) has led to the development of new waste glass compositions that have not previously been characterised. Therefore the mechanical properties, including Young's modulus, Poisson's ratio, hardness, indentation fracture toughness and brittleness of a series of glasses designed to safely incorporate wet ILW have been investigated. The results are presented and compared with the equivalent properties of an inactive simulant of the current UK HLW glass and other nuclear waste glasses from the literature. The higher density glasses tend to have slightly lower hardness and indentation fracture toughness values and slightly higher brittleness values, however, it is shown that the variations in mechanical properties between these different glasses are limited, are well within the range of published values for nuclear waste glasses, and that the surveyed data for all radioactive waste glasses fall within relatively narrow range.

Thermal treatment of high-caloric waste in fluidized bed incineration plants in Austria

International Nuclear Information System (INIS)

Ragossnig, A.M.

2001-05-01

The importance of thermal treatment of waste and residues in Austria is expected to rise due to the current changes of the legal situation in waste management. Assessing the rank order of different thermal treatment processes for waste management it has been shown that - especially caused by the rising importance of the mechanical treatment step in the mechanical-biological residual waste treatment and the subsequent necessity of the thermal treatment of a high-caloric preprocessed waste stream - the importance of the fluidized bed technology will increase. The main advantages are the high existing capacities as well as the flexibility of this technology in regard of fuel properties and further on the fact of the lacking influence of the ash towards the quality of a product. This is true although the thermal treatment in fluidized bed incinerators requires some processing of the waste. This doctoral thesis also contains a thorough physical and chemical characterization of various waste fuels - especially those which have been used during full scale incineration experiments. This characterization includes a comparison with fossil fuel. The practical part contains the documentation and balancing of full scale incineration experiments. A comparison of a reference experiment with experiments when waste fuel has been thermally utilized showed that a significant increase of emissions to the atmosphere has not been observed. Based on the incineration experiments conclusions in regard of waste fuels as well as different categories of thermal treatment plants are being stated. Finally, a recommendation of the assignation of various waste streams to different categories of thermal treatment plants is being made. (author)

Case study: Is the 'catch-all-plastics bin' useful in unlocking the hidden resource potential in the residual waste collection system?

Science.gov (United States)

Kranzinger, Lukas; Schopf, Kerstin; Pomberger, Roland; Punesch, Elisabeth

2017-02-01

Austria's performance in the collection of separated waste is adequate. However, the residual waste still contains substantial amounts of recyclable materials - for example, plastics, paper and board, glass and composite packaging. Plastics (lightweight packaging and similar non-packaging materials) are detected at an average mass content of 13% in residual waste. Despite this huge potential, only 3% of the total amount of residual waste (1,687,000 t y -1 ) is recycled. This implies that most of the recyclable materials contained in the residual waste are destined for thermal recovery and are lost for recycling. This pilot project, commissioned by the Land of Lower Austria, applied a holistic approach, unique in Europe, to the Lower Austrian waste management system. It aims to transfer excess quantities of plastic packaging and non-packaging recyclables from the residual waste system to the separately collected waste system by introducing a so-called 'catch-all-plastics bin'. A quantity flow model was constructed and the results showed a realistic increase in the amount of plastics collected of 33.9 wt%. This equals a calculated excess quantity of 19,638 t y -1 . The increased plastics collection resulted in a positive impact on the climate footprint (CO 2 equivalent) in line with the targets of EU Directive 94/62/EG (Circular Economy Package) and its Amendments. The new collection system involves only moderate additional costs.

Analysis of the technical capabilities of DOE sites for disposal of residuals from the treatment of mixed low-level waste

International Nuclear Information System (INIS)

Waters, R.D.; Gruebel, M.M.; Langkopf, B.S.; Kuehne, P.B.

1997-04-01

The US Department of Energy (DOE) has stored or expects to generate over the next five years more than 130,000 m 3 of mixed low-level waste (MLLW). Before disposal, MLLW is usually treated to comply with the land disposal restrictions of the Resource Conservation and Recovery Act. Depending on the type of treatment, the original volume of MLLW and the radionuclide concentrations in the waste streams may change. These changes must be taken into account in determining the necessary disposal capacity at a site. Treatment may remove the characteristic in some waste that caused it to be classified as mixed. Treatment of some waste may, by reduction of the mass, increase the concentrations of some transuranic radionuclides sufficiently so that it becomes transuranic waste. In this report, the DOE MLLW streams were analyzed to determine after-treatment volumes and radionuclide concentrations. The waste streams were reclassified as residual MLLW or low-level or transuranic waste resulting from treatment. The volume analysis indicated that about 89,000 m 3 of waste will require disposal as residual MLLW. Fifteen DOE sites were then evaluated to determine their capabilities for hosting disposal facilities for some or all of the residual MLLW. Waste streams associated with about 90% of the total residual MLLW volume are likely to present no significant issues for disposal and require little additional analysis. Future studies should focus on the remaining waste streams that are potentially problematic by examining site-specific waste acceptance criteria, alternative treatment processes, alternative waste forms for disposal, and pending changes in regulatory requirements

Biological waste by-production costs in forest management and possibilities for their reduction

Directory of Open Access Journals (Sweden)

Jiří Kadlec

2004-01-01

Full Text Available Biological wastes in forestry were observed from view of their by-production in silvicultural and logging operations. There were identified points where biological waste was produced in this paper, waste costs ratio for silvicultural and logging operations and were made suggestions for reduction of these costs. Biological waste costs give 34.4% of total costs of silvicultural operations and 30% of total costs of logging operations. Natural regeneration and minor forest produce operations are opportunities for reduction of these costs.

Properties of residual marine fuel produced by thermolysis from polypropylene waste

Directory of Open Access Journals (Sweden)

Linas Miknius

2015-06-01

Full Text Available Thermal degradation of waste plastics with the aim of producing liquid fuel is one of the alternative solutions to landfill disposal or incineration. The paper describes thermal conversion of polypropylene waste and analysis of produced liquid fuel that would satisfy ISO 8217-2012 requirements for a residual marine fuel. Single pass batch thermolysis processes were conducted at different own vapour pressures (20-80 barg that determined process temperature, residence time of intermediates what resulted in different yields of the liquid product. Obtained products were stabilized by rectification to achieve required standard flash point. Gas chromatography and 1H NMR spectrometry show aliphatic nature of the liquid product where majority of the compounds are isoalkanes and isoalkenes. Only lightest fractions boiling up to a temperature of 72 oC have significant amount of n-pentane. Distribution of aromatic hydrocarbons is not even along the boiling range. The fractions boiling at a temperature of 128 oC and 160 oC have the highest content of monocyclic arenes – 3.16 % and 4.09 % respectively. The obtained final liquid residual product meets all but one requirements of ISO 8217-2012 for residual marine fuels.DOI: http://dx.doi.org/10.5755/j01.ms.21.2.6105

Allowable residual contamination levels: transuranic advanced disposal systems for defense waste

International Nuclear Information System (INIS)

Kennedy, W.E. Jr.; Napier, B.A.

1982-01-01

An evaluation of advanced disposal systems for defense transuranic (TRU) wastes is being conducted using the Allowable Residual Contamination Level (ARCL) method. The ARCL method is based on compliance with a radiation dose rate limit through a site-specific analysis of the potential for radiation exposure to individuals. For defense TRU wastes at the Hanford Site near Richland, Washington, various advanced disposal techniques are being studied to determine their potential for application. This paper presents a discussion of the results of the first stage of the TRU advanced disposal systems project

Biological considerations in nuclear decommissioning, and radioactive waste management

International Nuclear Information System (INIS)

Rees, J.F.

1991-01-01

The importance of natural processes such as microbial action in waste management has recently been recognised. Although it is often difficult to predict the effects because the interactive processes are complex, human intervention can optimize the process. This paper highlights some of the fundamental stages in the management of low- and intermediate-level radioactive wastes where particular uncertainties exist and which might benefit from controlled microbial intervention. The areas considered are the use of biodegradable surfactants for cleaning surfaces before disposal, microbial adsorption and concentration of intermediate-level wastes from solution, microbial transformation of intermediate-level wastes organic fractions, enhancement of radionuclide transfer to the atmosphere, enhancement of transfer into vadose zone and ground water and the microbial treatment of any oily residues. (UK)

Dynamic respiration index as a descriptor of the biological stability of organic wastes.

Science.gov (United States)

Adani, Fabrizio; Confalonieri, Roberto; Tambone, Fulvia

2004-01-01

Analytical methods applicable to different organic wastes are needed to establish the extent to which readily biodegradable organic matter has decomposed (i.e., biological stability). The objective of this study was to test a new respirometric method for biological stability determination of organic wastes. Dynamic respiration index (DRI) measurements were performed on 16 organic wastes of different origin, composition, and biological stability degree to validate the test method and result expression, and to propose biological stability limits. In addition, theoretical DRI trends were obtained by using a mathematical model. Each test lasted 96 h in a 148-L-capacity respirometer apparatus, and DRI was monitored every hour. The biological stability was expressed as both single and cumulative DRI values. Results obtained indicated that DRI described biological stability in relation to waste typology and age well, revealing lower-stability waste characterized by a well-pronounced DRI profile (a marked peak was evident) that became practically flat for samples with higher biological stability. Fitting indices showed good model prediction compared with the experimental data, indicating that the method was able to reproduce the aerobic process, providing a reliable indication of the biological stability. The DRI can therefore be proposed as a useful method to measure the biological stability of organic wastes, and DRI values, calculated as a mean of 24 h of the highest microbial activity, of 1000 and 500 mg O(2) kg(-1) volatile solids (VS) h(-1) are proposed to indicate medium (e.g., fresh compost) and high (e.g., mature compost) biological stabilities, respectively.

Extraction of high added value biological compounds from sardine, sardine-type fish and mackerel canning residues--a review.

Science.gov (United States)

Ferraro, Vincenza; Carvalho, Ana P; Piccirillo, Clara; Santos, Manuela M; Castro, Paula M L; Pintado, Manuela E

2013-08-01

Different valuable compounds, which can be employed in medicine or in other industries (i.e. food, agrochemical, pharmaceutical) can be recovered from by-products and waste from the fish canning industries. They include lipids, proteins, bio-polymers, minerals, amino acids and enzymes; they can be extracted from wastewaters and/or from solid residues (head, viscera, skin, tails and flesh) generated along the canning process, through the filleting, cooking, salting or smoking stages. In this review, the opportunities for the extraction and the valorisation of bioactive compounds from sardine, sardine-type fish and mackerel canning residues are examined and discussed. These are amongst the most consumed fishes in the Mediterranean area; moreover, canning is one of the most important and common methods of preservation. The large quantities of by-products generated have great potentials for the extraction of biologically desirable high added value compounds. Copyright © 2013 Elsevier B.V. All rights reserved.

Maximising municipal solid waste--legume trimming residue mixture degradation in composting by control parameters optimization.

Science.gov (United States)

Cabeza, I O; López, R; Ruiz-Montoya, M; Díaz, M J

2013-10-15

Composting is one of the most successful biological processes for the treatment of the residues enriched in putrescible materials. The optimization of parameters which have an influence on the stability of the products is necessary in order to maximize recycling and recovery of waste components. The influence of the composting process parameters (aeration, moisture, C/N ratio, and time) on the stability parameters (organic matter, N-losses, chemical oxygen demand, nitrate, biodegradability coefficient) of the compost was studied. The composting experiment was carried out using Municipal Solid Waste (MSW) and Legume Trimming Residues (LTR) in 200 L isolated acrylic barrels following a Box-Behnken central composite experimental design. Second-order polynomial models were found for each of the studied compost stability parameter, which accurately described the relationship between the parameters. The differences among the experimental values and those estimated by using the equations never exceeded 10% of the former. Results of the modelling showed that excluding the time, the C/N ratio is the strongest variable influencing almost all the stability parameters studied in this case, with the exception of N-losses which is strongly dependent on moisture. Moreover, an optimized ratio MSW/LTR of 1/1 (w/w), moisture content in the range of 40-55% and moderate to low aeration rate (0.05-0.175 Lair kg(-)(1) min(-1)) is recommended to maximise degradation and to obtain a stable product during co-composting of MSW and LTR. Copyright © 2013 Elsevier Ltd. All rights reserved.

Typical Mexican agroindustrial residues as supports for solid-state fermentation

DEFF Research Database (Denmark)

Flores-Maltos, Dulce A.; Mussatto, Solange Ines; Contreras Esquivel, Juan Carlos

2014-01-01

. These biological wastes can be used as support-substrates in Solid-State Fermentation (SSF) to produce industrially relevant metabolites with great economical advantage. In addition, it is an environment friendly method of waste management. In this study were analyzed six different Mexican agro industrial residues...... process. The results provided important knowledge about the characteristics of these materials revealing their potential for use in fermentation processes....

Toluene : biological waste-gas treatment, toxicity and microbial adaptation

NARCIS (Netherlands)

Weber, F.J.

1995-01-01

Due to the increasing stringent legislation concerning the emission of volatile organic compounds, there is nowadays a growing interest to apply biological waste-gas treatment techniques for the removal of higher concentrations of specific contaminants from waste gases. Fluctuations in the

Biological ramifications of the subseabed disposal of high-level nuclear waste

International Nuclear Information System (INIS)

Gomez, L.S.; Hessler, R.R.; Jackson, D.W.; Marietta, M.G.; Smith, K.L. Jr.; Talbert, D.M.; Yayanos, A.A.

1980-01-01

The primary goal of the US Subseabed Disposal Program (SDP) is to assess the technical and environmental feasibility of disposing of high-level nuclear waste in deep-sea sediments. The subseabed biology program is charged with assessing possible ecosystem effects of radionuclides as well as possible health effects to man from radionuclides which may be released in the deep sea and transported to the ocean surface. Current biological investigations are attempting to determine benthic community structure; benthic community metabolism; the biology of deep-sea mobile scavengers; the faunal composition of midwater nekton; rates of microbial processes, and the radiation sensitivity of deep-sea organisms. Existing models of the dispersal of radionuclides in the deep sea have not considered many of the possible biological mechanisms which may influence the movement of radionuclides. Therefore, a multi-compartment foodweb model is being developed which considers both biological and physical influences on radionuclide transport. This model will allow parametric studies to be made of the impact on the ocean environment and on man of potential releases of radionuclides

Biological ramifications of the subseabed disposal of high-level nuclear waste

International Nuclear Information System (INIS)

Gomez, L.S.; Hessler, R.R.; Jackson, D.W.; Marietta, M.G.; Smith, K.L. Jr.; Talbert, D.M.; Yayanos, A.A.

1980-05-01

The primary goal of the US Subseabed Disposal Program (SDP) is to assess the technical and environmental feasibility of disposing of high-level nuclear waste in deep-sea sediments. The subseabed biology program is charged with assessing possible ecosystem effects of radionuclides as well as possible health effects to man from radionuclides which may be released in the deep sea and transported to the ocean surface. Current biological investigations are attempting to determine benthic community structure; benthic community metabolism; the biology of deep-sea mobile scavengers; the faunal composition of midwater nekton; rates of microbial processes; and the radiation sensitivity of deep-sea organisms. Existing models of the dispersal of radionuclides in the deep sea have not considered many of the possible biological mechanisms which may influence the movement of radionuclides. Therefore, a multi-compartment foodweb model is being developed which considers both biological and physical influences on radionuclide transport. This model will allow parametric studies to be made of the impact on the ocean environment and on man of potential releases of radionuclides

Measurement of residual stresses using fracture mechanics weight functions

International Nuclear Information System (INIS)

Fan, Y.

2000-01-01

A residual stress measurement method has been developed to quantify through-the-thickness residual stresses. Accurate measurement of residual stresses is crucial for many engineering structures. Fabrication processes such as welding and machining generate residual stresses that are difficult to predict. Residual stresses affect the integrity of structures through promoting failures due to brittle fracture, fatigue, stress corrosion cracking, and wear. In this work, the weight function theory of fracture mechanics is used to measure residual stresses. The weight function theory is an important development in computational fracture mechanics. Stress intensity factors for arbitrary stress distribution on the crack faces can be accurately and efficiently computed for predicting crack growth. This paper demonstrates that the weight functions are equally useful in measuring residual stresses. In this method, an artificial crack is created by a thin cut in a structure containing residual stresses. The cut relieves the residual stresses normal to the crack-face and allows the relieved residual stresses to deform the structure. Strain gages placed adjacent to the cut measure the relieved strains corresponding to incrementally increasing depths of the cut. The weight functions of the cracked body relate the measured strains to the residual stresses normal to the cut within the structure. The procedure details, such as numerical integration of the singular functions in applying the weight function method, will be discussed

Measurement of residual stresses using fracture mechanics weight functions

International Nuclear Information System (INIS)

Fan, Y.

2001-01-01

A residual stress measurement method has been developed to quantify through-the-thickness residual stresses. Accurate measurement of residual stresses is crucial for many engineering structures. Fabrication processes such as welding and machining generate residual stresses that are difficult to predict. Residual stresses affect the integrity of structures through promoting failures due to brittle fracture, fatigue, stress corrosion cracking, and wear. In this work, the weight function theory of fracture mechanics is used to measure residual stresses. The weight function theory is an important development in computational fracture mechanics. Stress intensity factors for arbitrary stress distribution on the crack faces can be accurately and efficiently computed for predicting crack growth. This paper demonstrates that the weight functions are equally useful in measuring residual stresses. In this method, an artificial crack is created by a thin cut in a structure containing residual stresses. The cut relieves the residual stresses normal to the crack-face and allows the relieved residual stresses to deform the structure. Strain gages placed adjacent to the cut measure the relieved strains corresponding to incrementally increasing depths of the cut. The weight functions of the cracked body relate the measured strains to the residual stresses normal to the cut within the structure. The procedure details, such as numerical integration of the singular functions in applying the weight function method, will be discussed. (author)

Long-term management of the existing radioactive wastes and residues at the Niagara Falls Storage Site. Draft Environmental Impact Statement

International Nuclear Information System (INIS)

1984-08-01

The statement assesses and compares several alternatives for long-term management of the existing radioactive wastes and residues at the Niagara Falls Storage Site (NFSS), Lewiston, New York. The alternatives include: (1) no action (continued interim storage at NFSS within a diked and capped containment area), (2) long-term management at NFSS (improved containment, with or without modified form of the residues), (3) long-term management at other DOE sites (Hanford, Washington, or Oak Ridge, Tennessee), and (4) offsite management of the residues at Hanford or Oak Ridge and either leaving the wastes at NFSS or removing them for disposal in the ocean. In addition to alternatives analyzed in depth, several options are also considered, including: other modifications of residue form, modification of the basic conceptual designs, other containment design options, transportation routes, and transportation modes. The radiological health effects (primarily increased risk of cancer) associated with long-term management of the wastes and residues are expected to be smaller than the nonradiological risks of occupational and transportation-related injuries and deaths. During the action period, the risk is highest for workers if all wastes and residues are moved to Hanford. The risk is highest for the general public if the residues are moved to Hanford and the wastes are moved to the ocean. Dispersal of the slightly contaminated wastes in the ocean is not expected to result in any significant impacts on the ocean environment or pose any significant radiological risk to humans. For all alternatives, if controls ceased, there would be eventual dispersion of the radioactive materials to the environment. If it is assumed that all controls cease, predicted time for loss of covers over the buried materials ranges from several hundred years to more than two million years, depending on the use of the land surface

Stabilization of APC residues from waste incineration with ferrous sulfate on a semi-industrial scale

DEFF Research Database (Denmark)

Lundtorp, Kasper; Jensen, Dorthe Lærke; Christensen, Thomas Højlund

2002-01-01

A stabilization method for air pollution control (APC) residues from municipal solid waste incineration (MSWI) involving mixing of the residue with water and FeSO4 has been demonstrated on a semi-industrial scale on three types of APC residues: a semidy (SD) APC residue, a fly ash (FA), and an FA...... mixed with sludge (FAS) from a wet flue gas cleaning system. The process was performed in batches of 165-175 kg residue. It generates a wastewater that is highly saline but has a low content of heavy metals such as Cd, Cr, and Pb. The stabilized and raw residues have been subject to a range of leaching...

Eco-friendly process combining physical-chemical and biological technics for the fermented dairy products waste pretreatment and reuse.

Science.gov (United States)

Kasmi, Mariam; Hamdi, Moktar; Trabelsi, Ismail

2017-01-01

Residual fermented dairy products resulting from process defects or from expired shelf life products are considered as waste. Thus, dairies wastewater treatment plants (WWTP) suffer high input effluents polluting load. In this study, fermented residuals separation from the plant wastewater is proposed. In the aim to meet the municipal WWTP input limits, a pretreatment combining physical-chemical and biological processes was investigated to reduce residual fermented dairy products polluting effect. Yoghurt (Y) and fermented milk products (RL) were considered. Raw samples chemical oxygen demand (COD) values were assessed at 152 and 246 g.L -1 for Y and RL products, respectively. Following the thermal coagulation, maximum removal rates were recorded at 80 °C. Resulting whey stabilization contributed to the removal rates enhance to reach 72% and 87% for Y and RL samples; respectively. Residual whey sugar content was fermented using Candida strains. Bacterial growth and strains degrading potential were discussed. C. krusei strain achieved the most important removal rates of 78% and 85% with Y and RL medium, respectively. Global COD removal rates exceeded 93%.

Waste energy harvesting mechanical and thermal energies

CERN Document Server

Ling Bing, Kong; Hng, Huey Hoon; Boey, Freddy; Zhang, Tianshu

2014-01-01

Waste Energy Harvesting overviews the latest progress in waste energy harvesting technologies, with specific focusing on waste thermal mechanical energies. Thermal energy harvesting technologies include thermoelectric effect, storage through phase change materials and pyroelectric effect. Waste mechanical energy harvesting technologies include piezoelectric (ferroelectric) effect with ferroelectric materials and nanogenerators. The book aims to strengthen the syllabus in energy, materials and physics and is well suitable for students and professionals in the fields.

Remaining Sites Verification Package for the 100-F-33, 146-F Aquatic Biology Fish Ponds. Attachment to Waste Site Reclassification Form 2006-021

International Nuclear Information System (INIS)

Dittmer, L.M.

2006-01-01

The 100-F-33, 146-F Aquatice Biology Fish Ponds waste site was an area with six small rectangular ponds and one large circular pond used to conduct tests on fish using various mixtures of river and reactor effluent water. The current site conditions achieve the remedial action objectives specified in the Remaining Sites ROD. The results of verification and applicable confirmatory sampling show that residual contaminant concentrations do not preclude any future uses and allow for unrestricted use of shallow zone soils. The results also demonstrate that residual contaminant concentrations are protective of groundwater and the Columbia River

Biological processes for advancing lignocellulosic waste biorefinery by advocating circular economy.

Science.gov (United States)

Liguori, Rossana; Faraco, Vincenza

2016-09-01

The actualization of a circular economy through the use of lignocellulosic wastes as renewable resources can lead to reduce the dependence from fossil-based resources and contribute to a sustainable waste management. The integrated biorefineries, exploiting the overall lignocellulosic waste components to generate fuels, chemicals and energy, are the pillar of the circular economy. The biological treatment is receiving great attention for the biorefinery development since it is considered an eco-friendly alternative to the physico-chemical strategies to increase the biobased product recovery from wastes and improve saccharification and fermentation yields. This paper reviews the last advances in the biological treatments aimed at upgrading lignocellulosic wastes, implementing the biorefinery concept and advocating circular economy. Copyright © 2016 Elsevier Ltd. All rights reserved.

Comparative environmental evaluation of three different waste treating methods for bio-degradable organic waste and residual waste from the six municipalities cooperating in Biogasanlaeg I/S and I/S Nordforbraending

International Nuclear Information System (INIS)

Cour Jansen, J. la.

1997-03-01

A comparative environmental evaluation has been made for three systems for processing household refuse. The first system (1) comprises thermofilic treatment of the organic waste. The inorganic parts of the waste from both systems is combusted in a cogeneration plant. The third system (3) is a cogeneration plant combusting all the wastes. The most essential issue in comparing the three waste processing systems is the possibility to use the residual products from the bio-gasification system (1) and the composting system in the agriculture as fertilizers. Without such a use it is estimated that the systems (1) and (2) will be very unfeasible, both environmentally and economically. The contents of heavy metals, organic chemicals, and plasticizers in the residual products are at present above the Danish threshold values. This problem can only be solved by reducing the contents of these pollutants in the household wastes. Based on these findings it is therefore very doubtful whether the residual waste products from bio-gasification and probably also from composting can be used in the agriculture in the future. However, it is for the other parts of the environmental analysis assumed that the problem will eventually be solved. Differences in resource utilization in the waste processing are very small in the three systems. When comparing the net energy production system (1) and (3) show the best results. The three systems are almost equal related to emissions of HC1, NO x , and SO 2 , the composting system performing the best. The three systems emit the same amount of CO 2 and other greenhouse gases. Composting, however, results in a smaller energy susbstituion and is therefore marginally a poorer solution. For reducing the heavy metals and plasticizers in the environment combustion of the organic wastes is the best system. (LN)

Tank waste concentration mechanism study

International Nuclear Information System (INIS)

Pan, L.C.; Johnson, L.J.

1994-09-01

This study determines whether the existing 242-A Evaporator should continue to be used to concentrate the Hanford Site radioactive liquid tank wastes or be replaced by an alternative waste concentration process. Using the same philosophy, the study also determines what the waste concentration mechanism should be for the future TWRS program. Excess water from liquid DST waste should be removed to reduce the volume of waste feed for pretreatment, immobilization, and to free up storage capacity in existing tanks to support interim stabilization of SSTS, terminal cleanout of excess facilities, and other site remediation activities

TANK FARM CLOSURE - A NEW TWIST ON REGULATORY STRATEGIES FOR CLOSURE OF WASTE TANK RESIDUALS FOLLOWING NUREG

International Nuclear Information System (INIS)

LEHMAN LL

2008-01-01

Waste from a number of single-shell tanks (SST) at the U.S. Department of Energy's (DOE) Hanford Site has been retrieved by CH2M HILL Hanford Group to fulfill the requirements of the 'Hanford Federal Facility Agreement and Consent Order (HFFACO) [1]. Laboratory analyses of the Hanford tank residual wastes have provided concentration data which will be used to determine waste classification and disposal options for tank residuals. The closure of tank farm facilities remains one of the most challenging activities faced by the DOE. This is due in part to the complicated regulatory structures that have developed. These regulatory structures are different at each of the DOE sites, making it difficult to apply lessons learned from one site to the next. During the past two years with the passage of the Section 3116 of the 'Ronald Reagan Defense Authorization Act of 2005' (NDAA) [2] some standardization has emerged for Savannah River Site and the Idaho National Laboratory tank residuals. Recently, with the issuance of 'NRC Staff Guidance for Activities Related to US. Department of Energy Waste Determinations' (NUREG-1854) [3] more explicit options may be considered for Hanford tank residuals than are presently available under DOE Orders. NUREG-1854, issued in August 2007, contains several key pieces of information that if utilized by the DOE in the tank closure process, could simplify waste classification and streamline the NRC review process by providing information to the NRC in their preferred format. Other provisions of this NUREG allow different methods to be applied in determining when waste retrieval is complete by incorporating actual project costs and health risks into the calculation of 'technically and economically practical'. Additionally, the NUREG requires a strong understanding of the uncertainties of the analyses, which given the desire of some NRC/DOE staff may increase the likelihood of using probabilistic approaches to uncertainty analysis. The purpose

Antimicrobial residues in animal waste and water resources proximal to large-scale swine and poultry feeding operations

Science.gov (United States)

Campagnolo, E.R.; Johnson, K.R.; Karpati, A.; Rubin, C.S.; Kolpin, D.W.; Meyer, M.T.; Esteban, J. Emilio; Currier, R.W.; Smith, K.; Thu, K.M.; McGeehin, M.

2002-01-01

Expansion and intensification of large-scale animal feeding operations (AFOs) in the United States has resulted in concern about environmental contamination and its potential public health impacts. The objective of this investigation was to obtain background data on a broad profile of antimicrobial residues in animal wastes and surface water and groundwater proximal to large-scale swine and poultry operations. The samples were measured for antimicrobial compounds using both radioimmunoassay and liquid chromatography/electrospray ionization-mass spectrometry (LC/ESI-MS) techniques. Multiple classes of antimicrobial compounds (commonly at concentrations of >100 μg/l) were detected in swine waste storage lagoons. In addition, multiple classes of antimicrobial compounds were detected in surface and groundwater samples collected proximal to the swine and poultry farms. This information indicates that animal waste used as fertilizer for crops may serve as a source of antimicrobial residues for the environment. Further research is required to determine if the levels of antimicrobials detected in this study are of consequence to human and/or environmental ecosystems. A comparison of the radioimmunoassay and LC/ESI-MS analytical methods documented that radioimmunoassay techniques were only appropriate for measuring residues in animal waste samples likely to contain high levels of antimicrobials. More sensitive LC/ESI-MS techniques are required in environmental samples, where low levels of antimicrobial residues are more likely.

Antimicrobial residues in animal waste and water resources proximal to large-scale swine and poultry feeding operations.

Science.gov (United States)

Campagnolo, Enzo R; Johnson, Kammy R; Karpati, Adam; Rubin, Carol S; Kolpin, Dana W; Meyer, Michael T; Esteban, J Emilio; Currier, Russell W; Smith, Kathleen; Thu, Kendall M; McGeehin, Michael

2002-11-01

Expansion and intensification of large-scale animal feeding operations (AFOs) in the United States has resulted in concern about environmental contamination and its potential public health impacts. The objective of this investigation was to obtain background data on a broad profile of antimicrobial residues in animal wastes and surface water and groundwater proximal to large-scale swine and poultry operations. The samples were measured for antimicrobial compounds using both radioimmunoassay and liquid chromatography/electrospray ionization-mass spectrometry (LC/ESI-MS) techniques. Multiple classes of antimicrobial compounds (commonly at concentrations of > 100 microg/l) were detected in swine waste storage lagoons. In addition, multiple classes of antimicrobial compounds were detected in surface and groundwater samples collected proximal to the swine and poultry farms. This information indicates that animal waste used as fertilizer for crops may serve as a source of antimicrobial residues for the environment. Further research is required to determine if the levels of antimicrobials detected in this study are of consequence to human and/or environmental ecosystems. A comparison of the radioimmunoassay and LC/ESI-MS analytical methods documented that radioimmunoassay techniques were only appropriate for measuring residues in animal waste samples likely to contain high levels of antimicrobials. More sensitive LC/ESI-MS techniques are required in environmental samples, where low levels of antimicrobial residues are more likely.

Reduction of heavy metals in residues from the dismantling of waste electrical and electronic equipment before incineration

International Nuclear Information System (INIS)

Long, Yu-Yang; Feng, Yi-Jian; Cai, Si-Shi; Hu, Li-Fang; Shen, Dong-Sheng

2014-01-01

Highlights: • The highest metal reduction occurs at a 2.36 mm sieving size. • Washing promotes heavy metal recycling without secondary pollution. • Sieving and washing are environmentally friendly pretreatments for WEEE wastes. - Abstract: Residues disposal from the dismantling of waste electrical and electronic equipment are challenging because of the large waste volumes, degradation-resistance, low density and high heavy metal content. Incineration is advantageous for treating these residues but high heavy metal contents may exist in incinerator input and output streams. We have developed and studied a specialized heavy metal reduction process, which includes sieving and washing for treating residues before incineration. The preferable screen aperture for sieving was found to be 2.36 mm (8 meshes) in this study; using this screen aperture resulted in the removal of approximately 47.2% Cu, 65.9% Zn, 26.5% Pb, 55.4% Ni and 58.8% Cd from the residues. Subsequent washing further reduces the heavy metal content in the residues larger than 2.36 mm, with preferable conditions being 400 rpm rotation speed, 5 min washing duration and liquid-to-solid ratio of 25:1. The highest cumulative removal efficiencies of Cu, Zn, Pb, Ni and Cd after sieving and washing reached 81.1%, 61.4%, 75.8%, 97.2% and 72.7%, respectively. The combined sieving and washing process is environmentally friendly, can be used for the removal of heavy metals from the residues and has benefits in terms of heavy metal recycling

Reduction of heavy metals in residues from the dismantling of waste electrical and electronic equipment before incineration

Energy Technology Data Exchange (ETDEWEB)

Long, Yu-Yang; Feng, Yi-Jian; Cai, Si-Shi [Zhejiang Provincial Key Laboratory of Solid Waste Treatment and Recycling, School of Environmental Science and Engineering, Zhejiang Gongshang University, Hangzhou 310012 (China); Hu, Li-Fang [College of Quality and Safety Engineering, China Jiliang University, Hangzhou 310018 (China); Shen, Dong-Sheng, E-mail: shends@zju.edu.cn [Zhejiang Provincial Key Laboratory of Solid Waste Treatment and Recycling, School of Environmental Science and Engineering, Zhejiang Gongshang University, Hangzhou 310012 (China)

2014-05-01

Highlights: • The highest metal reduction occurs at a 2.36 mm sieving size. • Washing promotes heavy metal recycling without secondary pollution. • Sieving and washing are environmentally friendly pretreatments for WEEE wastes. - Abstract: Residues disposal from the dismantling of waste electrical and electronic equipment are challenging because of the large waste volumes, degradation-resistance, low density and high heavy metal content. Incineration is advantageous for treating these residues but high heavy metal contents may exist in incinerator input and output streams. We have developed and studied a specialized heavy metal reduction process, which includes sieving and washing for treating residues before incineration. The preferable screen aperture for sieving was found to be 2.36 mm (8 meshes) in this study; using this screen aperture resulted in the removal of approximately 47.2% Cu, 65.9% Zn, 26.5% Pb, 55.4% Ni and 58.8% Cd from the residues. Subsequent washing further reduces the heavy metal content in the residues larger than 2.36 mm, with preferable conditions being 400 rpm rotation speed, 5 min washing duration and liquid-to-solid ratio of 25:1. The highest cumulative removal efficiencies of Cu, Zn, Pb, Ni and Cd after sieving and washing reached 81.1%, 61.4%, 75.8%, 97.2% and 72.7%, respectively. The combined sieving and washing process is environmentally friendly, can be used for the removal of heavy metals from the residues and has benefits in terms of heavy metal recycling.

Study of organic waste for production of hydrogen in reactor

International Nuclear Information System (INIS)

Guzmán Chinea, Jesús Manuel; Guzmán Marrero, Elizabeth; Pérez Ponce, Alejandro

2015-01-01

Biological processes have long been used for the treatment of organic waste makes, especially our study is based on the anaerobic process in reactors, using residual organic industry. Without excluding other non-industrial we have studied. Fundamental objectives treating organic waste is to reduce the pollutant load to the environment, another aim is to recover the waste recovering the energy contained in it. In this context, the biological hydrogen production from organic waste is an interesting alternative because it has low operating costs and raw material is being used as a residue in any way should be treated before final disposal. Hydrogen can be produced sustainable by anaerobic bacteria that grow in the dark with rich carbohydrate substrates giving as final products H 2 , CO 2 and volatile fatty acids. The whey byproduct from cheese production, has great potential to be used for the generation of hydrogen as it has a high carbohydrate content and a high organic load. The main advantages of using anaerobic processes in biological treatment of organic waste, are the low operating costs, low power consumption, the ability to degrade high organic loads, resistance biomass to stay long in the absence of substrate, without lose their metabolic activity, and low nutritional requirements and increase the performance of 0.9 mol H2 / mol lactose. (full text)Biological processes have long been used for the treatment of organic waste makes, especially our study is based on the anaerobic process in reactors, using residual organic industry. Without excluding other non-industrial we have studied. Fundamental objectives treating organic waste is to reduce the pollutant load to the environment, another aim is to recover the waste recovering the energy contained in it. In this context, the biological hydrogen production from organic waste is an interesting alternative because it has low operating costs and raw material is being used as a residue in any way should be treated

Biological production of hydrogen by dark fermentation of OFMSW and co-fermentation with slaughterhouse wastes

Energy Technology Data Exchange (ETDEWEB)

Moran, A.; Gomez, X.; Cuestos, M. J.

2005-07-01

Hydrogen is an ideal, clean and sustainable energy source for the future because of its high conversion and nonpolluting nature (Lin and Lay, 2003). There are different methods for the production of hydrogen, the traditional ones, are the production from fossil fuels. Aiming to reach a development based on sustainable principles the production of hydrogen from renewable sources is a desirable goal. Among the environmental friendly alternatives for the production of hydrogen are the biological means. Dark fermentation as it is known the process when light is not used; it is a preferable option thanks to the knowledge already collected from its homologous process, the anaerobic digestion for the production of methane. There are several studies intended to the evaluation of the production of hydrogen, many are dedicated to the use of pure cultures or the utilization of basic substrates as glucose or sucrose (Lin and Lay, 2003; Chang et al., 2002, Kim et al., 2005). This study is performed to evaluate the fermentation of a mixture of wastes for the production of hydrogen. It is used as substrate the organic fraction of municipal solid wastes (OFMSW) and a mixture of this residue with slaughterhouse waste. (Author)

Recycling of air pollution control residues from municipal solid waste incineration into lightweight aggregates.

Science.gov (United States)

Quina, Margarida J; Bordado, João M; Quinta-Ferreira, Rosa M

2014-02-01

This work focuses on the assessment of technological properties and on the leaching behavior of lightweight aggregates (LWA) produced by incorporating different quantities of air pollution control (APC) residues from municipal solid waste (MSW) incineration. Currently this hazardous waste has been mostly landfilled after stabilization/solidification. The LWA were produced by pelletizing natural clay, APC residues as-received from incineration plant, or after a washing treatment, a small amount of oil and water. The pellets were fired in a laboratory chamber furnace over calcium carbonate. The main technological properties of the LWA were evaluated, mainly concerning morphology, bulk and particle densities, compressive strength, bloating index, water adsorption and porosity. Given that APC residues do not own expansive (bloating) properties, the incorporation into LWA is only possible in moderate quantities, such as 3% as received or 5% after pre-washing treatment. The leaching behavior of heavy metals from sintered LWA using water or acid solutions was investigated, and despite the low acid neutralization capacity of the synthetic aggregates, the released quantities were low over a wide pH range. In conclusion, after a washing pre-treatment and if the percentage of incorporation is low, these residues may be incorporated into LWA. However, the recycling of APC residues from MSW incineration into LWA does not revealed any technical advantage. Copyright © 2013 Elsevier Ltd. All rights reserved.

Assessment of long-term pH developments in leachate from waste incineration residues

DEFF Research Database (Denmark)

Astrup, Thomas; Jakobsen, Rasmus; Christensen, Thomas Højlund

2006-01-01

influenced by changes in pH over time. The paper presents an approach for assessing pH changes in leachate from municipal solid waste incineration (MSWI) air-pollution-control (APC) residues. Residue samples were subjected to a stepwise batch extraction method in order to obtain residue samples at a range...... of pH Values (similar to common pH-dependence tests), and then on these samples to determine leaching of alkalinity as well as remaining solid phase alkalinity. On a range of APC residues covering various pretreatment and disposal options, this procedure was used to determine leachable and residual...... alkalinity as a function of pH. Mass balance calculations for typical disposal scenarios were used to provide data on pH as a function of the liquid-to-solid (L/S) ratio in the leaching system. Regardless of residue type and pretreatment, pH was found to stay above 7 for L/S ratios up to about 2000 L kg(-1...

Engineering evaluation of alternatives for the disposition of Niagara Falls Storage Site, its residues and wastes

International Nuclear Information System (INIS)

1984-01-01

The final disposition scenarios selected by DOE for assessment in this document are consistent with those stated in the Notice of Intent to prepare an Environmental Impact Statement (EIS) for the Niagara Falls Storage Site (NFSS) (DOE, 1983d) and the modifications to the alternatives resulting from the public scoping process. The scenarios are: take no action beyond interim remedial measures other than maintenance and surveillance of the NFSS; retain and manage the NFSS as a long-term waste management facility for the wastes and residues on the site; decontaminate, certify, and release the NFSS for other use, with long-term management of the wastes and residues at other DOE sites; and partially decontaminate the NFSS by removal and transport off site of only the more radioactive residues, and upgrade containment of the remaining wastes and residues on site. The objective of this document is to present to DOE the conceptual engineering, occupational radiation exposure, construction schedule, maintenance and surveillance requirements, and cost information relevant to design and implementation of each of the four scenarios. The specific alternatives within each scenario used as the basis for discussion in this document were evaluated on the bases of engineering considerations, technical feasibility, and regulatory requirements. Selected alternatives determined to be acceptable for each of the four final disposition scenarios for the NFSS were approved by DOE to be assessed and costed in this document. These alternatives are also the subject of the EIS for the NFSS currently being prepared by Argonne National Laboratory (ANL). 40 figures, 38 tables

Is synthetic biology mechanical biology?

Science.gov (United States)

Holm, Sune

2015-12-01

A widespread and influential characterization of synthetic biology emphasizes that synthetic biology is the application of engineering principles to living systems. Furthermore, there is a strong tendency to express the engineering approach to organisms in terms of what seems to be an ontological claim: organisms are machines. In the paper I investigate the ontological and heuristic significance of the machine analogy in synthetic biology. I argue that the use of the machine analogy and the aim of producing rationally designed organisms does not necessarily imply a commitment to mechanical biology. The ideal of applying engineering principles to biology is best understood as expressing recognition of the machine-unlikeness of natural organisms and the limits of human cognition. The paper suggests an interpretation of the identification of organisms with machines in synthetic biology according to which it expresses a strategy for representing, understanding, and constructing living systems that are more machine-like than natural organisms.

Immobilization of acid digestion residue

International Nuclear Information System (INIS)

Greenhalgh, W.O.; Allen, C.R.

1983-01-01

Acid digestion treatment of nuclear waste is similar to incineration processes and results in the bulk of the waste being reduced in volume and weight to some residual solids termed residue. The residue is composed of various dispersible solid materials and typically contains the resultant radioactivity from the waste. This report describes the immobilization of the residue in portland cement, borosilicate glass, and some other waste forms. Diagrams showing the cement and glass virtification parameters are included in the report as well as process steps and candidate waste product forms. Cement immobilization is simplest and probably least expensive; glass vitrification exhibits the best overall volume reduction ratio

Long-term emissions from mechanically biologically treated waste ...

African Journals Online (AJOL)

Waste treatment in passively aerated open windrows, using the Dome Aeration Technology (DAT), was identified as an appropriate technology due to low construction and operational resource requirements. Three self-aerated windrows were set up at the Bisasar Road Landfill in order to study the efficiency of the process ...

Control of a reactor for conditioning of biogenic waste materials. Final report; Steuerung eines Reaktors zur Aufbereitung von Abfaellen mit biogenen Bestandteilen. Abschlussbericht

Energy Technology Data Exchange (ETDEWEB)

Bartha, B.; Brummack, J.; Kloeden, W.

2002-10-01

Mechanical-biological waste treatment implies biological drying and mechanical separation; it produces a pollutant-free fuel fraction with good calorific value and inorganic fractions available for recycling. Apart from some prototypes, mostly static aerobic reactors are used. For moist residues, dynamic reactors may be interesting as they permit coupling of thermal and mechanical processes, i.e. parallel biological drying and mechanical separation. A discontinuous rotary kiln reactor for biological drying of residues was developed in this project. (orig.) [German] Die mechanisch-biologische Aufbereitung von Restabfaellen (MBA) hat sich zu einem Systembaustein innerhalb der Restabfallentsorgung entwickelt. Das Hauptanwendungsziel besteht darin, durch die Kombination von biologischer Trocknung mit mechanischen Stofftrennverfahren eine heizwertreiche und schadstoffentfrachtete Fraktion mit Brennstoffeigenschaften, sowie verwertbare anorganische Fraktionen aus dem Restabfall zu gewinnen. Die Ausgangssituation zeigte, dass, abgesehen von einigen prototypischen Anlagen, in der MBA-Technologie hauptsaechlich statische, aerob arbeitende Reaktoren (Rottetunnel und Rotteboxen) fuer den biologischen Schritt eingesetzt werden. Fuer feuchte Restabfaelle erscheint es interessant, dynamische Reaktoren einzusetzen, die die Kopplung thermischer und mechanischer Prozesse erlauben, die also die biologische Trocknung und den mechanischen Aufschluss parallel zulassen. Im Rahmen des Projektes wurde die Steuerung eines diskontinuierlich betriebenen Drehrohrreaktors zur biologischen Trocknung von Restabfaellen entwickelt. (orig.)

Possible interactions between recirculated landfill leachate and the stabilized organic fraction of municipal solid waste.

Science.gov (United States)

Calabrò, Paolo S; Mancini, Giuseppe

2012-05-01

The stabilized organic fraction of municipal solid waste (SOFMSW) is a product of the mechanical/biological treatment (MBT) of mixed municipal solid waste (MMSW). SOFMSW is considered a 'grey' compost and the presence of pollutants (particularly heavy metals) and residual glass and plastic normally prevents agricultural use, making landfills the typical final destination for SOFMSW. Recirculation of leachate in landfills can be a cost-effective management option, but the long-term sustainability of such a practice must be verified. Column tests were carried out to examine the effect of SOFMSW on leachate recirculation. The results indicate that organic matter may be biologically degraded and metals (copper and zinc) are effectively entrapped through a combination of physical (adsorption), biological (bacterial sulfate reduction), and chemical (precipitation of metal sulfides) processes, while other chemicals (i.e. ammonia nitrogen and chloride) are essentially unaffected by filtration through SOFMSW.

Leaching from municipal solid waste incineration residues

Energy Technology Data Exchange (ETDEWEB)

Hyks, J.

2008-02-15

Leaching of pollutants from Municipal Solid Waste Incineration (MSWI) residues has been investigated combining a range of laboratory leaching experiments with geochemical modeling. Special attention was paid to assessing the applicability of laboratory data for subsequent modeling with respect to presumed full-scale conditions; both sample pretreatment and actual influence of leaching conditions on the results of laboratory experiments were considered. It was shown that sample pretreatment may have large impact on leaching test data. In particular, a significant fraction of Pb was shown mobile during the washing of residues with water. In addition, drying of residues (i.e. slow oxidation) prior to leaching experiments increased the leaching of Cr significantly. Significant differences regarding the leaching behavior of individual elements with respect to (non)equilibrium conditions in column percolation experiments were observed in the study. As a result, three groups of elements were identified based on the predominant leaching control and the influence of (non)equilibrium on the results of the laboratory column experiments: I. Predominantly availability-controlled elements (e.g. Na, K, Cl) II. Solubility-controlled elements (e.g. Ca, S, Si, Al, Ba, and Zn) III. Complexation-controlled elements (e.g. Cu and Ni) With respect to the above groups it was suggested that results of laboratory column experiments can, with consideration, be used to estimate full-scale leaching of elements from Group I and II. However, in order to avoid large underestimations in the assessment of leaching from Group III, it is imperative to describe the time-dependent transport of dissolved organic carbon (DOC) in the tested system or to minimize the physical non-equilibrium during laboratory experiments (e.g. bigger column, slower flow velocity). Forward geochemical modeling was applied to simulate long-term release of elements from a MSWI air-pollution-control residue. Leaching of a

Can We Describe Biological Systems with Quantum Mechanics?

International Nuclear Information System (INIS)

Granados-Ramírez, C G; Benítez-Cardoza, C G; Carbajal-Tinoco, M D

2016-01-01

Quantum Mechanics is the favourite theory to predict the structure of any group of atoms, including biological molecules. Due to numerous difficulties, however, it is necessary to introduce a series of approximations to overcome such impediments. We present a coarse-grained model of circular dichroism (CD) that is based on the theory of optical activity, developed by DeVoe, in order to predict CD spectra. In first stage, we determine the polarisability of individual monomers (residues, in the case of peptides) from experiments of molar absorptivity. The complex polarisabilities are used together with peptide structures obtained by density functional theory and other methods to determine their corresponding CD spectra, which are in reasonable agreement with their experimental counterparts. (paper)

The use of fly larvae for organic waste treatment.

Science.gov (United States)

Čičková, Helena; Newton, G Larry; Lacy, R Curt; Kozánek, Milan

2015-01-01

The idea of using fly larvae for processing of organic waste was proposed almost 100 years ago. Since then, numerous laboratory studies have shown that several fly species are well suited for biodegradation of organic waste, with the house fly (Musca domestica L.) and the black soldier fly (Hermetia illucens L.) being the most extensively studied insects for this purpose. House fly larvae develop well in manure of animals fed a mixed diet, while black soldier fly larvae accept a greater variety of decaying organic matter. Blow fly and flesh fly maggots are better suited for biodegradation of meat processing waste. The larvae of these insects have been successfully used to reduce mass of animal manure, fecal sludge, municipal waste, food scrapes, restaurant and market waste, as well as plant residues left after oil extraction. Higher yields of larvae are produced on nutrient-rich wastes (meat processing waste, food waste) than on manure or plant residues. Larvae may be used as animal feed or for production of secondary products (biodiesel, biologically active substances). Waste residue becomes valuable fertilizer. During biodegradation the temperature of the substrate rises, pH changes from neutral to alkaline, ammonia release increases, and moisture decreases. Microbial load of some pathogens can be substantially reduced. Both larvae and digested residue may require further treatment to eliminate pathogens. Facilities utilizing natural fly populations, as well as pilot and full-scale plants with laboratory-reared fly populations have been shown to be effective and economically feasible. The major obstacles associated with the production of fly larvae from organic waste on an industrial scale seem to be technological aspects of scaling-up the production capacity, insufficient knowledge of fly biology necessary to produce large amounts of eggs, and current legislation. Technological innovations could greatly improve performance of the biodegradation facilities and

Impact of imidacloprid residues on the development of Eisenia fetida during vermicomposting of greenhouse plant waste.

Science.gov (United States)

Fernández-Gómez, Manuel J; Romero, Esperanza; Nogales, Rogelio

2011-09-15

Pesticide application in agriculture causes residues in post-harvest plant waste at different concentrations. Knowledge concerning how pesticide concentrations in such waste affect earthworms is essential for recycling greenhouse plant debris through vermicomposting. Here, we have evaluated the effects of imidacloprid (IMD) residues on earthworms (Eisenia fetida) during the vermicomposting of plant waste from greenhouse crops in Spain. Before, the effect of different IMD concentrations on earthworms was tested using cattle manure as an optimum waste for worm development. The results after using cattle manure indicate that IMD dose ≥ 5 mg kg(-1) hinders worm growth and even causes death, whereas IMD dose ≤ 2 mg IMD kg(-1) allows worm growth similar to control but impedes reproduction. The results from the vermicomposting of plant waste reveal that IMD inhibits adequate worm growth and increases mortality. Although 89% worms became sexually mature in substrate containing 2 mg IMD kg(-1), they did not produce cocoons. IMD also affected microorganisms harboured in the substrates for vermicomposting, as indicated by the reduction in their dehydrogenase activity. This enzyme activity was restored after vermicomposting. This study provides a sound basis for the vermicomposting of pesticide-contaminated plant waste. Copyright © 2011 Elsevier B.V. All rights reserved.

Geochemical, hydrological and biological cycling of energy residuals. Research plan: subsurface transport program

International Nuclear Information System (INIS)

Wobber, F.J.

1985-09-01

Because natural processes associated with the release and the transport of organic compounds, trace metals, and radionuclides are incompletely understood, research in this area is critical if the long term scientific uncertainties about contaminant transport are to be resolved. The processes that control mobilization and attenuation of energy residuals in soils and geological strata, their hydrological transport to and within ground water regimes, and their accumulation in biological systems require research attention. A summary of DOE's core research program is described. It is designed to provide a base of fundamental scientific information so that the geochemical hydrological, and biophysical mechanics that contribute to the transport and long term fate of energy related contaminants in natural systems can be understood

Preliminary examination for a cooperative project in the field of waste and waste water biology (biological removal of slaughterhouse waste). Final report. Voruntersuchung fuer ein Verbundprojekt auf dem Gebiet der Abwasser- und Abfallbiologie (biologische Schlachthofentsorgung). Schlussbericht

Energy Technology Data Exchange (ETDEWEB)

Lorre, R.; Marx, G.; Treutler, K.

1986-01-01

Major installations for the fermentation of undiluted slaughterhouse waste were not known. Only indirectly comparable test results could be obtained from the literature. Overall objective of the project was the development and testing of a biogas plant for energy production on the premises using slaughterhouse waste that is as solid as possible, such as rumen contents, dung, sieving residues from waste water. In order to determine max. biogas yield, the room load of the single-stage and mesophilically operated bioreactor (2 m/sup 3/) was slowly increased. The rumen contents were chopped up mechanically before feeding, in order to allow for decontamination and stabilizing of the decomposition process, and were alkalified with lime to a pH value greater than 12.5. Four tests with room loads between 0.8 and 5.65 kg oTS/m/sup 3/.d resulted in yields of 0.41-.54 m/sup 3//kg oTS and showed that the max. time and space yield through lime treatment is 3 m/sup 3/ biogas per m/sup 3/ rotting space and day. The method can be implemented on a large scale, yet it is not economical when relying solely on the biogas production. (orig.) With 32 refs., 14 tabs., 21 figs.

Preparation of Grinding Aid Using Waste Acid Residue from Plasticizer Plant

Science.gov (United States)

Li, Lingxiao; Feng, Yanchao; Liu, Manchao; Zhao, Fengqing

2017-09-01

The grinding aid for granulated blast-furnace slag were prepared from waste acid residue from plasticizer plant through neutralization, de-methanol and granulation process. In this process, sulfuric acid was transformed into gypsum which has much contribution for grinding effect by combined use with the glycerol and poly glycerin in the waste. Fly ash was used for granulation for the composite grinding aid. Methanol can be recycled in the process. The result showed that the suitable addition of grinding aid is 0.03 % of granulated blast-furnace slag (mass). In this case, the specific surface area is 14% higher than that of the blank. Compared with the common grinding aids, it has excellent performance and low cost.

Thermal treatment of stabilized air pollution control residues in a waste incinerator pilot plant. Part 2: Leaching characteristics of bottom ashes.

Science.gov (United States)

Baun, Dorthe L; Christensen, Thomas H; Bergfeldt, Brita; Vehlow, Jürgen; Mogensen, Erhardt P B

2004-02-01

With the perspective of generating only one solid residue from waste incineration, co-feeding of municipal solid waste and air pollution control residues stabilized by the Ferrox process was investigated in the TAMARA pilot plant incinerator as described in Bergfeldt et al. (Waste Management Research, 22, 49-57, 2004). This paper reports on leaching from the combined bottom ashes. Batch leaching test, pH-static leaching tests, availability tests and column leaching tests were used to characterize the leaching properties. The leaching properties are key information in the context of reuse in construction or in landfilling of the combined residue. In general, the combined bottom ashes had leaching characteristics similar to the reference bottom ash, which contained no APC residue. However, As and Pb showed slightly elevated leaching from the combined bottom ashes, while Cr showed less leaching. The investigated combined bottom ashes had contents of metals comparable to what is expected at steady state after continuous co-feeding of APC residues. Only Cd and Pb were partly volatilized (30-40%) during the incineration process and thus the combined bottom ashes had lower contents of Cd and Pb than expected at steady state. Furthermore, a major loss of Hg was, not surprisingly, seen and co-feeding of Ferrox-products together with municipal solid waste will require dedicated removal of Hg in the flue gas to prevent a build up of Hg in the system. In spite of this, a combined single solid residue from waste incineration seems to be a significant environmental improvement to current technology.

Rock mechanics activities at the Waste Isolation Pilot Plant

International Nuclear Information System (INIS)

Francke, C.; Saeb, S.

1996-01-01

The application of rock mechanics at nuclear waste repositories is a true multidisciplinary effort. A description and historical summary of the Waste Isolation Pilot Plant (WIPP) is presented. Rock mechanics programs at the WIPP are outlined, and the current rock mechanics modeling philosophy of the Westinghouse Waste Isolation Division is discussed

Nutrient retention capabilities of Nile tilapia ( Oreochromis niloticus) fed bio-regenerative life support system (BLSS) waste residues

Science.gov (United States)

Gonzales, John M.; Brown, Paul B.

Nile tilapia were evaluated as a bio-regenerative sub-process for reducing solid waste potentially encountered in bio-regenerative life support systems. Ten juvenile Nile tilapia (mean weight = 2.05 g) were stocked into triplicate aquaria and fed one of seven experimental diets consisting of vegetable, bacterial, or food waste for a period of seven weeks. Weight gain (g), specific growth rate (mg/d), and daily consumption (g) was significantly higher ( p diet (37.99 and 68.54, respectively) followed by fish fed the wheat bran/wheat germ diet (23.19 and 63.67, respectively). Nitrogen, sulfur, and crude protein retention was significantly higher ( p diet (23.68, 21.89, and 23.68, respectively). A general loss of minerals was observed among all groups. Strong associations were observed between crude lipid retention and sulfur retention ( r2 = 0.94), crude lipid retention and carbon retention ( r2 = 0.92), WG and fiber content of dietary treatments ( r2 = 0.92), WG and carbon retention and ( r2 = 0.88), WG and lysine content of waste residues ( r2 = 0.86), crude protein retention and carbon retention ( r2 = 0.84), sulfur retention and crude protein retention ( r2 = 0.84), and total sulfur amino acid (TSAA) content of residues and WG ( r2 = 0.81). Weaker associations existed between WG and crude lipid retention ( r2 = 0.77), crude fiber content and carbon retention ( r2 = 0.76), and WG and methionine content of waste residues ( r2 = 0.75). Additional research is needed to improve the nutritional quality of fibrous residues as a means to improve tilapia's ability to utilize these residues as a food source in bio-regenerative support systems.

Waste incineration

International Nuclear Information System (INIS)

Rumplmayr, A.; Sammer, G.

2001-01-01

Waste incineration can be defined as the thermal conversion processing of solid waste by chemical oxidation. The types of wastes range from solid household waste and infectious hospital waste through to toxic solid, liquid and gaseous chemical wastes. End products include hot incineration gases, composed primarily of nitrogen, carbon dioxide, water vapor and to a smaller extend of non-combustible residue (ash) and air pollutants (e. g. NO x ). Energy can be recovered by heat exchange from the hot incineration gases, thus lowering fossil fuel consumption that in turn can reduce emissions of greenhouse gases. Burning of solid waste can fulfil up to four distinctive objectives (Pera, 2000): 1. Volume reduction: volume reduction of about 90 %, weight reduction of about 70 %; 2. Stabilization of waste: oxidation of organic input; 3. Recovery of energy from waste; 4. Sanitization of waste: destruction of pathogens. Waste incineration is not a means to make waste disappear. It does entail emissions into air as well as water and soil. The generated solid residues are the topic of this task force. Unlike other industrial processes discussed in this platform, waste incineration is not a production process, and is therefore not generating by-products, only residues. Residues that are isolated from e. g. flue gas, are concentrated in another place and form (e. g. air pollution control residues). Hence, there are generally two groups of residues that have to be taken into consideration: residues generated in the actual incineration process and others generated in the flue gas cleaning system. Should waste incineration finally gain public acceptance, it will be necessary to find consistent regulations for both sorts of residues. In some countries waste incineration is seen as the best option for the treatment of waste, whereas in other countries it is seen very negative. (author)

Quantum Mechanics predicts evolutionary biology.

Science.gov (United States)

Torday, J S

2018-07-01

Nowhere are the shortcomings of conventional descriptive biology more evident than in the literature on Quantum Biology. In the on-going effort to apply Quantum Mechanics to evolutionary biology, merging Quantum Mechanics with the fundamentals of evolution as the First Principles of Physiology-namely negentropy, chemiosmosis and homeostasis-offers an authentic opportunity to understand how and why physics constitutes the basic principles of biology. Negentropy and chemiosmosis confer determinism on the unicell, whereas homeostasis constitutes Free Will because it offers a probabilistic range of physiologic set points. Similarly, on this basis several principles of Quantum Mechanics also apply directly to biology. The Pauli Exclusion Principle is both deterministic and probabilistic, whereas non-localization and the Heisenberg Uncertainty Principle are both probabilistic, providing the long-sought after ontologic and causal continuum from physics to biology and evolution as the holistic integration recognized as consciousness for the first time. Copyright © 2018 Elsevier Ltd. All rights reserved.

THE RENIN-ANGIOTENSIN SYSTEM AND THE BIOLOGY OF SKELETAL MUSCLE: MECHANISMS OF MUSCLE WASTING IN CHRONIC DISEASE STATES.

Science.gov (United States)

Delafontaine, Patrice; Yoshida, Tadashi

2016-01-01

Sarcopenia and cachexia are muscle-wasting syndromes associated with aging and with many chronic diseases such as congestive heart failure, diabetes, cancer, chronic obstructive pulmonary disease, and renal failure. While mechanisms are complex, these conditions are often accompanied by elevated angiotensin II (Ang II). We found that Ang II infusion in rodents leads to skeletal muscle wasting via alterations in insulin-like growth factor-1 signaling, increased apoptosis, enhanced muscle protein breakdown via the ubiquitin-proteasome system, and decreased appetite resulting from downregulation of hypothalamic orexigenic neuropeptides orexin and neuropeptide Y. Furthermore, Ang II inhibits skeletal muscle stem cell proliferation, leading to lowered muscle regenerative capacity. Distinct stem cell Ang II receptor subtypes are critical for regulation of muscle regeneration. In ischemic mouse congestive heart failure model skeletal muscle wasting and attenuated muscle regeneration are Ang II dependent. These data suggest that the renin-angiotensin system plays a critical role in mechanisms underlying cachexia in chronic disease states.

Treatment methods and comparative risks of thorium removal from waste residues

International Nuclear Information System (INIS)

Porter, R.D.; Hamby, D.M.; Martin, J.E.

1997-07-01

This study was done to examine the risks of remediation and the effectiveness of removal methods for thorium and its associated radioactive decay products from various soils and wastes associated with DOE's Formerly Utilized Sites Remedial Action Program (FUSRAP). Removal of 230 Th from uranium process residues would significantly reduce the buildup of 226 Ra (half-life of 1600 years), and since 230 Th concentrations at most of the important sites greatly exceed the 226 Ra concentrations, such removal would reduce the accumulation of additional radiation risks associated with 226 Ra and its products; and, if treatment also removed 226 Ra, these risks could be mitigated even further. Removal of 232 Th from thorium process residues would remove the source material for 228 Ra, and since 228 Ra has a half-life of 5.76 years, its control at FUSRAP sites could be done with land use controls for the 30--50 years required for 228 Ra and the risks associated with its decay products to decay away. It must be recognized, however, that treatment methods invariably require workers to process residues and waste materials usually with bulk handling techniques. These processes expose workers to the radioactivity in the materials, therefore, workers would incur radiological risks in addition to industrial accident risks. An important question is whether the potential reduction of future radiological risks to members of the public justifies the risks that are incurred by remediation workers due to handling materials. This study examines, first, the effectiveness of treatment and then the risks that would be associated with remediation

The conversion of waste plastics/petroleum residue mixtures to transportation fuels

International Nuclear Information System (INIS)

Ali, M.F.; Siddiqui, M.N.

2005-01-01

Plastics have become the material of choice in the modern world and its applications in the industrial field are continually increasing. Presently the plastics are manufactured for various uses such as: consumer packaging, wires, pipes, containers, bottles, appliances, electrical/electronic parts, computers and automotive parts. Most of he post consumer, plastic products are discarded and end up as mixed plastic municipal waste. The disposal of his waste has become a major social concern. Mixed plastic waste (MPW) recycling is still very much in its infancy. Approximately 20 million tons of plastic waste is generated in the United States of America, while about 15 million tons is generated throughout the Europe. With existing recycle efforts, only 7% of the MPW are recycled to produce low-grade plastic products such as plastic sacks, pipes, plastic fencing, and garden furniture. The current plastic reclamation technology options are generally grouped into the following four types: (i) Primary: The processing of plastic for use comparable to the original application. (ii) Secondary: The processing of plastics waste into new products with a lower quality level. (iii) Tertiary: The chemical or thermal processing of plastic waste to their basic hydrocarbon feedstock. The resulting raw materials are then reprocessed into plastic material or other products of the oil refining process. (iv) Quaternary: The incineration of plastics waste to recover energy. This paper deals exclusively with tertiary recycling by pyrolysis and catalytic cracking of plastics waste alone and by coprocessing with petroleum residue or heavy oils to fuels and petrochemical feedstock for further processing in existing refinery and petrochemical units. (author)

Modelling of environmental impacts from biological treatment of organic municipal waste in EASEWASTE

DEFF Research Database (Denmark)

Boldrin, Alessio; Neidel, Trine Lund; Damgaard, Anders

2011-01-01

The waste-LCA model EASEWASTE quantifies potential environmental effects from biological treatment of organic waste, based on mass and energy flows, emissions to air, water, soil and groundwater as well as effects from upstream and downstream processes. Default technologies for composting......, anaerobic digestion and combinations hereof are available in the model, but the user can change all key parameters in the biological treatment module so that specific local plants and processes can be modelled. EASEWASTE is one of the newest waste LCA models and the biological treatment module was built...... partly on features of earlier waste-LCA models, but offers additional facilities, more flexibility, transparency and user-friendliness. The paper presents the main features of the module and provides some examples illustrating the capability of the model in environmentally assessing and discriminating...

Treatment of air pollution control residues with iron rich waste sulfuric acid: does it work for antimony (Sb)?

Science.gov (United States)

Okkenhaug, Gudny; Breedveld, Gijs D; Kirkeng, Terje; Lægreid, Marit; Mæhlum, Trond; Mulder, Jan

2013-03-15

Antimony (Sb) in air pollution control (APC) residues from municipal solid waste incineration has gained increased focus due to strict Sb leaching limits set by the EU landfill directive. Here we study the chemical speciation and solubility of Sb at the APC treatment facility NOAH Langøya (Norway), where iron (Fe)-rich sulfuric acid (∼3.6M, 2.3% Fe(II)), a waste product from the industrial extraction of ilmenite, is used for neutralization. Antimony in water extracts of untreated APC residues occurred exclusively as pentavalent antimonate, even at low pH and Eh values. The Sb solubility increased substantially at pH<10, possibly due to the dissolution of ettringite (at alkaline pH) or calcium (Ca)-antimonate. Treated APC residues, stored anoxically in the laboratory, simulating the conditions at the NOAH Langøya landfill, gave rise to decreasing concentrations of Sb in porewater, occurring exclusively as Sb(V). Concentrations of Sb decreased from 87-918μgL(-1) (day 3) to 18-69μgL(-1) (day 600). We hypothesize that an initial sorption of Sb to Fe(II)-Fe(III) hydroxides (green rust) and eventually precipitation of Ca- and Fe-antimonates (tripuhyite; FeSbO4) occurred. We conclude that Fe-rich, sulfuric acid waste is efficient to immobilize Sb in APC residues from waste incineration. Copyright © 2013 Elsevier B.V. All rights reserved.

The potential of agro-industrial residues and municipal solid waste for production of biogas and electricity in Tanzania

Energy Technology Data Exchange (ETDEWEB)

Kivaisi, A K [Univ. of Dar es Salaam, Botany Dept., Applied Microbiology Unit (Tanzania, United Republic of)

1998-12-31

This paper gives an overview of the energy demands in Tanzania, and highlights the current serious shortage of electricity. Government strategy to alleviate the problem include exploitation of the country`s big natural gas reserves for power generation, and utilization of the renewable energies such as solar, wind and biogas. Important agro-industrial residues and municipal solid wastes with large potentials for anaerobic converstion into biogas and electricity have been identified and quantified. Tanzania is estimated to generate about 615,000 organic matter from coffee, sisal, sugar and cereal residues and households in main towns are estimated to generate about 600,000 tons of organic matter annually. Laboratory scale determinations of methane yields from the residues gave 400 m{sup 3} CH{sub 4}/ton VS of sisal pulp; 400 m{sup 3} CH{sub 4}/ton VS of sisal production wastewater; 400 m{sup 3} CH{sub 4}/ton VS of Robusta coffee solid waste, 350 m{sup 3} CH{sub 4}/ton VS of sugar processing wastewater; 250 m{sup 3} CH{sub 4}/ton VS of sugar filter mat, 450 m{sup 3} CH{sub 4}/ton VS maize bran and 300 m{sup 3} CH{sub 4}/ton VS of mixed household waste. Based on these results the estimated total annual potential electricity production from these residues is 1.4 million MW. The total oil substitution from these residues has been estimated at 0.35 million tonnes crude diesel oil per annum equivalent to 2% of the total energy consumption in Tanzania. Case studies onthe coffee and sisal processing factories indicate that exploitation of the residues for the production of electricity on site these factories is feasible. Utilization of agro-industrial residues and municipal waste for biogas production has enormous potential for reduction of environmental pollution. The potential substitution of fossil fuel with biogas represents an annual reduction in the net CO{sub 2} emission to the atmosphere of approximately 1.3 million tonnes. By treating the residues in controlled

The potential of agro-industrial residues and municipal solid waste for production of biogas and electricity in Tanzania

Energy Technology Data Exchange (ETDEWEB)

Kivaisi, A.K. [Univ. of Dar es Salaam, Botany Dept., Applied Microbiology Unit (Tanzania, United Republic of)

1997-12-31

This paper gives an overview of the energy demands in Tanzania, and highlights the current serious shortage of electricity. Government strategy to alleviate the problem include exploitation of the country`s big natural gas reserves for power generation, and utilization of the renewable energies such as solar, wind and biogas. Important agro-industrial residues and municipal solid wastes with large potentials for anaerobic converstion into biogas and electricity have been identified and quantified. Tanzania is estimated to generate about 615,000 organic matter from coffee, sisal, sugar and cereal residues and households in main towns are estimated to generate about 600,000 tons of organic matter annually. Laboratory scale determinations of methane yields from the residues gave 400 m{sup 3} CH{sub 4}/ton VS of sisal pulp; 400 m{sup 3} CH{sub 4}/ton VS of sisal production wastewater; 400 m{sup 3} CH{sub 4}/ton VS of Robusta coffee solid waste, 350 m{sup 3} CH{sub 4}/ton VS of sugar processing wastewater; 250 m{sup 3} CH{sub 4}/ton VS of sugar filter mat, 450 m{sup 3} CH{sub 4}/ton VS maize bran and 300 m{sup 3} CH{sub 4}/ton VS of mixed household waste. Based on these results the estimated total annual potential electricity production from these residues is 1.4 million MW. The total oil substitution from these residues has been estimated at 0.35 million tonnes crude diesel oil per annum equivalent to 2% of the total energy consumption in Tanzania. Case studies onthe coffee and sisal processing factories indicate that exploitation of the residues for the production of electricity on site these factories is feasible. Utilization of agro-industrial residues and municipal waste for biogas production has enormous potential for reduction of environmental pollution. The potential substitution of fossil fuel with biogas represents an annual reduction in the net CO{sub 2} emission to the atmosphere of approximately 1.3 million tonnes. By treating the residues in controlled

The potential of agro-industrial residues and municipal solid waste for production of biogas and electricity in Tanzania

International Nuclear Information System (INIS)

Kivaisi, A.K.

1997-01-01

This paper gives an overview of the energy demands in Tanzania, and highlights the current serious shortage of electricity. Government strategy to alleviate the problem include exploitation of the country's big natural gas reserves for power generation, and utilization of the renewable energies such as solar, wind and biogas. Important agro-industrial residues and municipal solid wastes with large potentials for anaerobic converstion into biogas and electricity have been identified and quantified. Tanzania is estimated to generate about 615,000 organic matter from coffee, sisal, sugar and cereal residues and households in main towns are estimated to generate about 600,000 tons of organic matter annually. Laboratory scale determinations of methane yields from the residues gave 400 m 3 CH 4 /ton VS of sisal pulp; 400 m 3 CH 4 /ton VS of sisal production wastewater; 400 m 3 CH 4 /ton VS of Robusta coffee solid waste, 350 m 3 CH 4 /ton VS of sugar processing wastewater; 250 m 3 CH 4 /ton VS of sugar filter mat, 450 m 3 CH 4 /ton VS maize bran and 300 m 3 CH 4 /ton VS of mixed household waste. Based on these results the estimated total annual potential electricity production from these residues is 1.4 million MW. The total oil substitution from these residues has been estimated at 0.35 million tonnes crude diesel oil per annum equivalent to 2% of the total energy consumption in Tanzania. Case studies onthe coffee and sisal processing factories indicate that exploitation of the residues for the production of electricity on site these factories is feasible. Utilization of agro-industrial residues and municipal waste for biogas production has enormous potential for reduction of environmental pollution. The potential substitution of fossil fuel with biogas represents an annual reduction in the net CO 2 emission to the atmosphere of approximately 1.3 million tonnes. By treating the residues in controlled anaerobic systems it is possible to reduce the methane emission by

Methods of conditioning waste fuel decladding hulls and dissolver residues

International Nuclear Information System (INIS)

De Regge, P.; Loida, A.; Schmidt-Hansberg, T.; Sombret, C.

1985-01-01

Several methods for conditioning spent fuel decladding hulls or dissolver residues have been considered in various countries of the European Community. Five of these methods used embedding technique with or without prior compaction: they are based on incorporation in metallic alloys, glass, ceramics, cements and metals or graphite compounds. A sixth one consists in melting the decladding materials. The corresponding research programmes have been pursued to varying states of progress with regard to demonstrating their feasibility on an industrial scale and the use of genuine wastes in bench scale experiments. The properties of the conditioned wastes have been investigated. Special attention has been paid to the corrosion resistance to various aqueous media as tap water, brine or clayey water. Although no categorical conclusion can be drawn from the initial results, the available findings provide a basis for assessing the different processes

Biological toxicity evaluation of Hanford Site waste grouts

International Nuclear Information System (INIS)

Rebagay, T.V. Dodd, D.A.; Voogd, J.A.

1992-10-01

Liquid wastes containing radioactive, hazardous, and regulated chemicals have been generated throughout the 50 years of operation of the Hanford Site of the US Department of Energy near Richland, Washington. These wastes are currently stored onsite in single- and double-shell carbon steel tanks. To effectively handle and treat these wastes, their degree of toxicity must be determined. The disposal of the low-level radioactive liquid portion of the wastes involves mixing the wastes with pozzolanic blends to form grout. Potential environmental hazards posed by grouts are largely unknown. Biological evaluation of grout toxicity is needed to provide information on the potential risks of animal and plant exposure to the grouts. The fish, rat, and Microtox toxicity tests described herein indicate that the grouts formed from Formulations I and 2 are nonhazardous and nondangerous. Using the Microtox solid-phase protocol, both soluble and insoluble organic and inorganic toxicants in the grouts can be detected. This protocol may be used for rapid screening of environmental pollutants and toxicants

Water-immiscible solvents for the biological treatment of waste gases

NARCIS (Netherlands)

Cesario, M.T.

1997-01-01

In conventional biological systems for the treatment of waste gases, contaminants are transferred directly to the aqueous phase and then converted by the micro-organisms. When poorly water-soluble pollutants are to be removed, biological degradation is often limited by the slow transport

Prediction of interface residue based on the features of residue interaction network.

Science.gov (United States)

Jiao, Xiong; Ranganathan, Shoba

2017-11-07

Protein-protein interaction plays a crucial role in the cellular biological processes. Interface prediction can improve our understanding of the molecular mechanisms of the related processes and functions. In this work, we propose a classification method to recognize the interface residue based on the features of a weighted residue interaction network. The random forest algorithm is used for the prediction and 16 network parameters and the B-factor are acting as the element of the input feature vector. Compared with other similar work, the method is feasible and effective. The relative importance of these features also be analyzed to identify the key feature for the prediction. Some biological meaning of the important feature is explained. The results of this work can be used for the related work about the structure-function relationship analysis via a residue interaction network model. Copyright © 2017 Elsevier Ltd. All rights reserved.

Fermentation of household wastes and industrial waste water; Vergaerung von haeuslichen Abfaellen und Industrieabwaessern

Energy Technology Data Exchange (ETDEWEB)

Edelmann, W [Arbeitsgemeinschaft Bioenergie ' arbi' , Maschwanden (Switzerland); Engeli, H [Probag AG, Dietikon (Switzerland); Glauser, M [Biol-Conseils SA, Neuchatel (Switzerland); Hofer, H [HTH-Verfahrenstechnik, Winterthur (Switzerland); Membrez, Y [EREP SA, Aclens (Switzerland); Meylan, J -H [Lausanne (Switzerland); Schwitzguebel, J -P [Swiss Federal Institute of Technology (EPFL), Genie biologique, Lausanne (Switzerland)

1993-07-01

This comprehensive brochure reviews various technologies for the environment-friendly treatment of organic wastes and residues. The principles of anaerobic digestion are discussed. Authorities, planners and engineers concerned with waste treatment are provided with an overview of current technology in the organic wastes area. The brochure emphasises the importance of fermentation processes in waste treatment, discusses the legal pre-requisites for biogas production, lists the biological and process-oriented fundamentals of fermentation and examines the energy potential of biogenic wastes and waste water. Further, details are given on the treatment of both industrial waste water and solid organic wastes and, finally, the economics of fermentation is examined. Useful data is presented in table form and the various processes described are illustrated by schematics and flow diagrams. An appendix lists suggestions for further reading on the subject.

Conversion of a MBA to the treatment of biological wastes; Umnutzung einer MBA zur Bioabfallbehandlung

Energy Technology Data Exchange (ETDEWEB)

Deubig, Jan B. [Zentrale Abfallwirtschaft Kaiserslautern (ZAK) AoeR Kapiteltal, Kaiserslautern (Germany); Stadtmueller, Gregor [Zentrale Abfallwirtschaft Kaiserslautern (ZAK) AoeR Kapiteltal, Kaiserslautern (Germany). Abt. Technik; Greuel, Michael [Schirmer Umwelttechnik GmbH, Mainz (Germany); Deubig, Isabel [Zentrale Abfallwirtschaft Kaiserslautern (ZAK) AoeR Kapiteltal, Kaiserslautern (Germany). Abt. Stoffstrommanagement

2013-03-01

The Zentrale Abfallwirtschaft Kaiserslautern (ZAK) - gemeinsame kommunale Anstalt der Stadt und des Landkreises Kaiserslautern (Kaiserslautern, Federal Republic of Germany) is a public waste management authority being responsible for 250,000 inhabitants with respect to the utilization of municipal waste and with respect to the collection of problematic waste materials and electric appliances. Due to the changing framework conditions in the waste management, ZAK looks for solutions which facilitate the handling with increasing specific costs at simultaneously preservation of created values and compliance with social and ecologic standards. The change of the utilization of the cluster of plants to a mechanical-biological biowaste treatment plant within a regional cooperation project with formation of clusters in the waste management is an alternative to the unchanged continuation of the status quo or to a shutdown. Within the project transformation, existing power plants have been partly subject to a utilization conversion for the second time. ZAK increases its profile as a biomass competence centre. The MBA technology demonstrates its process-technical determined enhanced flexibility of mass flow.

Upgrading pyrolytic residue from waste tires to commercial carbon black.

Science.gov (United States)

Zhang, Xue; Li, Hengxiang; Cao, Qing; Jin, Li'e; Wang, Fumeng

2018-05-01

The managing and recycling of waste tires has become a worldwide environmental challenge. Among the different disposal methods for waste tires, pyrolysis is regarded as a promising route. How to effectively enhance the added value of pyrolytic residue (PR) from waste tires is a matter of great concern. In this study, the PRs were treated with hydrochloric and hydrofluoric acids in turn under ultrasonic waves. The removal efficiency for the ash and sulfur was investigated. The pyrolytic carbon black (PCB) obtained after treating PR with acids was analyzed by X-ray fluorescence spectrophotometry, Fourier transform infrared spectrometry, X-ray diffractometry, laser Raman spectrometry, scanning electron microscopy, thermogravimetric (TG) analysis, and physisorption apparatus. The properties of PCB were compared with those of commercial carbon black (CCB) N326 and N339. Results showed PRs from waste tires were mainly composed of carbon, sulfur, and ash. The carbon in PCB was mainly from the CCB added during tire manufacture rather than from the pyrolysis of pure rubbers. The removal percentages for the ash and sulfur of PR are 98.33% (from 13.98 wt % down to 0.24 wt %) and 70.16% (from 1.81 wt % down to 0.54 wt %), respectively, in the entire process. The ash was mainly composed of metal oxides, sulfides, and silica. The surface properties, porosity, and morphology of the PCB were all close to those of N326. Therefore, PCB will be a potential alternative of N326 and reused in tire manufacture. This route successfully upgrades PR from waste tires to the high value-added CCB and greatly increases the overall efficiency of the waste tire pyrolysis industry.

Dual-fuel production from restaurant grease trap waste: bio-fuel oil extraction and anaerobic methane production from the post-extracted residue.

Science.gov (United States)

Kobayashi, Takuro; Kuramochi, Hidetoshi; Maeda, Kouji; Tsuji, Tomoya; Xu, Kaiqin

2014-10-01

An effective way for restaurant grease trap waste (GTW) treatment to generate fuel oil and methane by the combination of physiological and biological processes was investigated. The heat-driven extraction could provide a high purity oil equivalent to an A-grade fuel oil of Japanese industrial standard with 81-93 wt% of extraction efficiency. A post-extracted residue was treated as an anaerobic digestion feedstock, and however, an inhibitory effect of long chain fatty acid (LCFA) was still a barrier for high-rate digestion. From the semi-continuous experiment fed with the residual sludge as a single substrate, it can be concluded that the continuous addition of calcium into the reactor contributed to reducing LCFA inhibition, resulting in the long-term stable operation over one year. Furthermore, the anaerobic reactor performed well with 70-80% of COD reduction and methane productivity under an organic loading rate up to 5.3g-COD/L/d. Copyright © 2014 Elsevier Ltd. All rights reserved.

Study on indium leaching from mechanically activated hard zinc residue

Directory of Open Access Journals (Sweden)

Yao J.H.

2011-01-01

Full Text Available In this study, changes in physicochemical properties and leachability of indium from mechanically activated hard zinc residue by planetary mill were investigated. The results showed that mechanical activation increased specific surface area, reaction activity of hard zinc residue, and decreased its particle size, which had a positive effect on indium extraction from hard zinc residue in hydrochloric acid solution. Kinetics of indium leaching from unmilled and activated hard zinc residue were also investigated, respectively. It was found that temperature had an obvious effect on indium leaching rate. Two different kinetic models corresponding to reactions which are diffusion controlled, [1-(1- x1/3]2=kt and (1-2x/3-(1-x2/3=kt were used to describe the kinetics of indium leaching from unmilled sample and activated sample, respectively. Their activation energies were determined to be 17.89 kJ/mol (umilled and 11.65 kJ/mol (activated within the temperature range of 30°C to 90°C, which is characteristic for a diffusion controlled process. The values of activation energy demonstrated that the leaching reaction of indium became less sensitive to temperature after hard zinc residue mechanically activated by planetary mill.

Investigating Resulting Residual Stresses during Mechanical Forming Process

Science.gov (United States)

Akinlabi, Stephen A.; Fatoba, Olawale S.; Mashinini, Peter M.; Akinlabi, Esther T.

2018-03-01

Most manufacturing processes such as machining, welding, heat treatment, laser forming, laser cladding and, laser metal deposition, etc. are subjected to a form of heat or energy to change the geometrical shape thus changing the inherent engineering and structural properties of the material. These changes often cause the development of locked up stresses referred to as residual stresses as a result of these activities. This study reports on the residual stresses developed due to the mechanical forming process to maintain a suitable structural integrity for the formed components. The result of the analysis through the X-ray diffraction confirmed that residual stresses were induced in the manufactured parts and further revealed that residual stresses were compressive in nature as found in the parent material but with values less than the parent material.

Physical and mechanical properties of degraded waste surrogate material

International Nuclear Information System (INIS)

Hansen, F.D.; Mellegard, K.D.

1998-03-01

This paper discusses rock mechanics testing of surrogate materials to provide failure criteria for compacted, degraded nuclear waste. This daunting proposition was approached by first assembling all known parameters such as the initial waste inventory and rock mechanics response of the underground setting after the waste is stored. Conservative assumptions allowing for extensive degradation processes helped quantify the lowest possible strength conditions of the future state of the waste. In the larger conceptual setting, computations involve degraded waste behavior in transient pressure gradients as gas exits the waste horizon into a wellbore. Therefore, a defensible evaluation of tensile strength is paramount for successful analyses and intentionally provided maximal failed volumes. The very conservative approach assumes rampant degradation to define waste surrogate composition. Specimens prepared from derivative degradation product were consolidated into simple geometries for rock mechanics testing. Tensile strength thus derived helped convince a skeptical peer review panel that drilling into the Waste Isolation Pilot Plant (WIPP) would not likely expel appreciable solids via the drill string

Manufacturing of concrete with residues from iron ore exploitation using the technology of radioactive waste cementation

Energy Technology Data Exchange (ETDEWEB)

Versieux, Juniara L.; Lameiras, Fernando S.; Tello, Cledola Cassia Oliveira de, E-mail: juniarani@gmail.com, E-mail: fsl@cdtn.br, E-mail: tellocc@cdtn.br [Centro de Desenvolvimento da Tecnologia Nucelar (CDTN/CNEN-MG), Belo Horizonte, MG (Brazil)

2015-07-01

Radioactive wastes from various segments of economy are immobilized by cementation, because of availability and widespread use in civil construction of cement. New cementitious materials are developed in CDTN using mining residues based on cementing techniques of radioactive wastes. Special procedures were developed to obtain concrete with the use of super plasticizers in which natural sand was totally replaced by mining residues. The motivation for this research is the exploration of banded iron formations (BIF) as iron ore in 'Quadrilatero Ferrifero' of Minas Gerais, where huge amounts of residues are generated with great concern about the environmental sustainability and safety of dams for residue storage. The exploitation of river sand causes many negative impacts, which leads to interest in its replacement by another raw material in mortar and concrete manufacturing. The use of BIF mining residues were studied for manufacturing of concrete pavers to contribute to reducing the impact caused by extraction of natural sand and use of mining residues. Previously developed procedures with total replacement of natural sand for mining residues were modified, including use of gravel to obtain pavers with improved properties. Four different mixtures were tested, in which the proportion of gravel and super plasticizer was varied. Monitored properties of pavers, among others, were compression resistance, water absorption, and void volume. With addition of gravel, the pavers had higher void index than those made only with mortar, and higher resistance to compression after 28 days of curing (an average of 18MPa of those made with mortar to 24MPa of those made with concrete). (author)

Manufacturing of concrete with residues from iron ore exploitation using the technology of radioactive waste cementation

International Nuclear Information System (INIS)

Versieux, Juniara L.; Lameiras, Fernando S.; Tello, Cledola Cassia Oliveira de

2015-01-01

Radioactive wastes from various segments of economy are immobilized by cementation, because of availability and widespread use in civil construction of cement. New cementitious materials are developed in CDTN using mining residues based on cementing techniques of radioactive wastes. Special procedures were developed to obtain concrete with the use of super plasticizers in which natural sand was totally replaced by mining residues. The motivation for this research is the exploration of banded iron formations (BIF) as iron ore in 'Quadrilatero Ferrifero' of Minas Gerais, where huge amounts of residues are generated with great concern about the environmental sustainability and safety of dams for residue storage. The exploitation of river sand causes many negative impacts, which leads to interest in its replacement by another raw material in mortar and concrete manufacturing. The use of BIF mining residues were studied for manufacturing of concrete pavers to contribute to reducing the impact caused by extraction of natural sand and use of mining residues. Previously developed procedures with total replacement of natural sand for mining residues were modified, including use of gravel to obtain pavers with improved properties. Four different mixtures were tested, in which the proportion of gravel and super plasticizer was varied. Monitored properties of pavers, among others, were compression resistance, water absorption, and void volume. With addition of gravel, the pavers had higher void index than those made only with mortar, and higher resistance to compression after 28 days of curing (an average of 18MPa of those made with mortar to 24MPa of those made with concrete). (author)

Treatment methods and comparative risks of thorium removal from waste residues

Energy Technology Data Exchange (ETDEWEB)

Porter, R.D.; Hamby, D.M.; Martin, J.E.

1997-07-01

This study was done to examine the risks of remediation and the effectiveness of removal methods for thorium and its associated radioactive decay products from various soils and wastes associated with DOE`s Formerly Utilized Sites Remedial Action Program (FUSRAP). Removal of {sup 230}Th from uranium process residues would significantly reduce the buildup of {sup 226}Ra (half-life of 1600 years), and since {sup 230}Th concentrations at most of the important sites greatly exceed the {sup 226}Ra concentrations, such removal would reduce the accumulation of additional radiation risks associated with {sup 226}Ra and its products; and, if treatment also removed {sup 226}Ra, these risks could be mitigated even further. Removal of {sup 232}Th from thorium process residues would remove the source material for {sup 228}Ra, and since {sup 228}Ra has a half-life of 5.76 years, its control at FUSRAP sites could be done with land use controls for the 30--50 years required for {sup 228}Ra and the risks associated with its decay products to decay away. It must be recognized, however, that treatment methods invariably require workers to process residues and waste materials usually with bulk handling techniques. These processes expose workers to the radioactivity in the materials, therefore, workers would incur radiological risks in addition to industrial accident risks. An important question is whether the potential reduction of future radiological risks to members of the public justifies the risks that are incurred by remediation workers due to handling materials. This study examines, first, the effectiveness of treatment and then the risks that would be associated with remediation.

Phytotoxicity of vulpia residues: III. Biological activity of identified allelochemicals from Vulpia myuros.

Science.gov (United States)

An, M; Pratley, J E; Haig, T

2001-02-01

Twenty compounds identified in vulpia (Vulpia myuros) residues as allelochemicals were individually and collectively tested for biological activity. Each exhibited characteristic allelochemical behavior toward the test plant, i.e., inhibition at high concentrations and stimulation or no effect at low concentrations, but individual activities varied. Allelopathins present in large quantities, such as syringic, vanillic, and succinic acids, possessed low activity, while those present in small quantities, such as catechol and hydrocinnamic acid, possessed strong inhibitory activity. The concept of a phytotoxic strength index was developed for quantifying the biological properties of each individual allelopathin in a concise, comprehensive, and meaningful format. The individual contribution of each allelopathin, assessed by comparing the phytotoxic strength index to the overall toxicity of vulpia residues, was variable according to structure and was influenced by its relative proportion in the residue. The majority of compounds possessed low or medium biological activity and contributed most of the vulpia phytotoxicity, while compounds with high biological activity were in the minority and only present at low concentration. Artificial mixtures of these pure allelochemicals also produced phytotoxicity. There were additive/synergistic effects evident in the properties of these mixtures. One such mixture, formulated from allelochemicals found in the same proportions as occur in vulpia extract, produced stronger activity than another formulated from the same set of compounds but in equal proportions. These results suggest that the exploration of the relative composition of a cluster of allelopathins may be more important than simply focusing on the identification of one or two compounds with strong biological activity and that synergism is fundamental to the understanding of allelopathy.

Recycling of waste bread as culture media for efficient biological treatment of wastewater

International Nuclear Information System (INIS)

Kim, Young-Ju; Kim, Pil-Jin; Kim, Ji-Hoon; Lee, Chang-Soo; Qureshi, T.I.

2012-01-01

Possibilities of recycling of waste bread as culture media for efficient biological treatment of wastewater were investigated. In order to get the highest growth of microorganism for increased contaminants' removal efficiency of the system, different compositions of waste bread and skim milk with and without adding Powdered Activated Carbon (PAC) were tested. Mixed waste bread compositions with added PAC showed relatively higher number of microorganisms than the compositions without added PAC. A composition of 40% mixed waste bread and 60% skim milk produced highest number of microorganisms with subsequent increased contaminants' removal efficiency of the system. 'Contrast' alone showed lower contaminants' removal efficiency than mixed bread compositions. Use of waste bread in the composition of skim milk reduced cost of using foreign source of nutrients in biological treatment of wastewater and also facilitated waste bread management through recycling. (author)

Characterization of selected municipal solid waste components to estimate their biodegradability.

Science.gov (United States)

Bayard, R; Benbelkacem, H; Gourdon, R; Buffière, P

2018-06-15

Biological treatments of Residual Municipal Solid Waste (RMSW) allow to divert biodegradable materials from landfilling and recover valuable alternative resources. The biodegradability of the waste components needs however to be assessed in order to design the bioprocesses properly. The present study investigated complementary approaches to aerobic and anaerobic biotests for a more rapid evaluation. A representative sample of residual MSW was collected from a Mechanical Biological Treatment (MBT) plant and sorted out into 13 fractions according to the French standard procedure MODECOM™. The different fractions were analyzed for organic matter content, leaching behavior, contents in biochemical constituents (determined by Van Soest's acid detergent fiber method), Biochemical Oxygen Demand (BOD) and Bio-Methane Potential (BMP). Experimental data were statistically treated by Principal Components Analysis (PCA). Cumulative oxygen consumption from BOD tests and cumulative methane production from BMP tests were found to be positively correlated in all waste fractions. No correlation was observed between the results from BOD or BMP bioassays and the contents in cellulose-like, hemicelluloses-like or labile organic compounds. No correlation was observed either with the results from leaching tests (Soluble COD). The contents in lignin-like compounds, evaluated as the non-extracted RES fraction in Van Soest's method, was found however to impact negatively the biodegradability assessed by BOD or BMP tests. Since cellulose, hemicelluloses and lignin are the polymers responsible for the structuration of lignocellulosic complexes, it was concluded that the structural organization of the organic matter in the different waste fractions was more determinant on biodegradability than the respective contents in individual biopolymers. Copyright © 2017 Elsevier Ltd. All rights reserved.

Evaluation of residual activity of solid waste generated in nuclear medicine services of Porto Alegre - Brazil

International Nuclear Information System (INIS)

Xavier, Ana M.; Alabarse, Frederico Gil; Magalhaes, Maisa Haiidamus; Guerrero, Jesus Salvador Perez

2008-01-01

An experimental programme to estimate, with a better degree of accuracy, the activity that remains adsorbed in flasks and syringes used in Nuclear Medicine Services for the administration of radionuclides to patients submitted to diagnostic or therapy was conducted under the coordination of the Radioactive Waste Division of the Brazilian Nuclear Energy Commission. The adopted recommendation in Brazil to allow an expedite solid waste management in nuclear medicine facilities, up to the present, is to consider that 2% of the initial activity remains adsorbed in the solid waste, which easily allows the calculation of the storage time to achieve regulatory clearance levels by decay. This research evaluates 17 different kinds of radio pharmaceuticals and three radioisotopes: 99m Tc, 67 Ga and 201 Tl. Results obtained by means of a weighting method to estimate the residual mass in flasks show that the ratio of the mass of the liquid that remains in the solid waste to the mass of the empty flask is constant. This suggests that the residual activity depends on the initial activity concentration of radiopharmaceutical contained in each flask, as assumed by the regulatory body. Additionally, results obtained by determining the remaining activity in flasks, shortly after the injection of its radionuclides contents in patients, indicate that an average value for the residual activity of the order of 10% of the initial activity contained in the flasks or syringes can be adopted instead of the previously assumed 2%. It is suggested that the more conservative average value obtained in the present work for the activity that remains in flasks and syringes, that is, 10% of the initial activity, could be adopted to determine the decay storage time before the release of solid waste in the urban conventional land fill disposal system. (author)

Optimized assessment and usage of biological waste; Optimierte Erfassung und Verwertung von Bioabfall

Energy Technology Data Exchange (ETDEWEB)

Kern, Michael; Raussen, Thomas (eds.)

2013-07-01

The booklet on the optimized assessment and usage of biological waste includes contributions on the following issues: implementation of the bio-waste assessment in the federal states; economy and ecology of bio-waste fermentation; practice forum biogas: new bio-waste fermentation plants in Germany; effects of legal reforms on the usage and processing of bio-waste; flexible electricity input and power-to-gas.

Thermal and catalytic decomposition behavior of PVC mixed plastic waste with petroleum residue

Energy Technology Data Exchange (ETDEWEB)

Ali, Mohammad Farhat; Siddiqui, Mohammad Nahid [Department of Chemistry, King Fahd University of Petroleum and Minerals, Dhahran 31261 (Saudi Arabia)

2005-08-15

The pyrolysis and hydropyrolysis of PVC mixed plastic waste alone and with petroleum residue was carried out at 150 and 350{sup o}C under N{sub 2} gas and at 430{sup o}C under 6.5MPa H{sub 2} gas pressure. The behavior of plastic waste during thermal and catalytic decomposition has also been studied in single- and two-stage reaction processes. In the individual pyrolysis process, both the petroleum residue and polystyrene (PS) undergo more than 90% conversion to liquid and gaseous products, whereas low-density polyethylene (LDPE) and high-density polyethylene (HDPE) yielded lower conversions products, and polypropylene (PP) and polyvinyl chloride (PVC) afforded somewhere a moderate to high conversion products. In a single-stage pyrolysis reaction, PVC was processed with petroleum residue at 150 and 430{sup o}C, under N{sub 2} gas for 1h at each temperature in a glass reactor. The model PVC and waste PVC showed slight variations in the products distribution obtained from the glass reactor. In two-stage process, model PVC, vacuum gas oil (VGO) and a number of different catalysts were used in a stainless steel autoclave micro tubular reactor at 350{sup o}C under the stream of N{sub 2} gas for 1h and at 430{sup o}C under 950psi (6.5MPa) H{sub 2} pressure for the duration of 2h. Significantly, different products distributions were obtained. Among the catalysts used, fluid catalytic cracking (FCC) and hydrocracking catalysts (HC-1) were most effective in producing liquid fuel (hexane soluble) materials. The study shows that the catalytic coprocessing of PVC with VGO is a feasible process by which PVC and VGO materials can be converted into transportation fuels.

Reduction of heavy metals in residues from the dismantling of waste electrical and electronic equipment before incineration.

Science.gov (United States)

Long, Yu-Yang; Feng, Yi-Jian; Cai, Si-Shi; Hu, Li-Fang; Shen, Dong-Sheng

2014-05-15

Residues disposal from the dismantling of waste electrical and electronic equipment are challenging because of the large waste volumes, degradation-resistance, low density and high heavy metal content. Incineration is advantageous for treating these residues but high heavy metal contents may exist in incinerator input and output streams. We have developed and studied a specialized heavy metal reduction process, which includes sieving and washing for treating residues before incineration. The preferable screen aperture for sieving was found to be 2.36mm (8 meshes) in this study; using this screen aperture resulted in the removal of approximately 47.2% Cu, 65.9% Zn, 26.5% Pb, 55.4% Ni and 58.8% Cd from the residues. Subsequent washing further reduces the heavy metal content in the residues larger than 2.36mm, with preferable conditions being 400rpm rotation speed, 5min washing duration and liquid-to-solid ratio of 25:1. The highest cumulative removal efficiencies of Cu, Zn, Pb, Ni and Cd after sieving and washing reached 81.1%, 61.4%, 75.8%, 97.2% and 72.7%, respectively. The combined sieving and washing process is environmentally friendly, can be used for the removal of heavy metals from the residues and has benefits in terms of heavy metal recycling. Copyright © 2014 Elsevier B.V. All rights reserved.

Recovery of fissile materials from plutonium residues, miscellaneous spent nuclear fuel, and uranium fissile wastes

International Nuclear Information System (INIS)

Forsberg, C.W.

1997-01-01

A new process is proposed that converts complex feeds containing fissile materials into a chemical form that allows the use of existing technologies (such as PUREX and ion exchange) to recover the fissile materials and convert the resultant wastes to glass. Potential feed materials include (1) plutonium scrap and residue, (2) miscellaneous spent nuclear fuel, and (3) uranium fissile wastes. The initial feed materials may contain mixtures of metals, ceramics, amorphous solids, halides, and organics. 14 refs., 4 figs

Calcination/dissolution residue treatment

International Nuclear Information System (INIS)

Knight, R.C.; Creed, R.F.; Patello, G.K.; Hollenberg, G.W.; Buehler, M.F.; O'Rourke, S.M.; Visnapuu, A.; McLaughlin, D.F.

1994-09-01

Currently, high-level wastes are stored underground in steel-lined tanks at the Hanford site. Current plans call for the chemical pretreatment of these wastes before their immobilization in stable glass waste forms. One candidate pretreatment approach, calcination/dissolution, performs an alkaline fusion of the waste and creates a high-level/low-level partition based on the aqueous solubilities of the components of the product calcine. Literature and laboratory studies were conducted with the goal of finding a residue treatment technology that would decrease the quantity of high-level waste glass required following calcination/dissolution waste processing. Four elements, Fe, Ni, Bi, and U, postulated to be present in the high-level residue fraction were identified as being key to the quantity of high-level glass formed. Laboratory tests of the candidate technologies with simulant high-level residues showed reductive roasting followed by carbonyl volatilization to be successful in removing Fe, Ni, and Bi. Subsequent bench-scale tests on residues from calcination/dissolution processing of genuine Hanford Site tank waste showed Fe was separated with radioelement decontamination factors of 70 to 1,000 times with respect to total alpha activity. Thermodynamic analyses of the calcination of five typical Hanford Site tank waste compositions also were performed. The analyses showed sodium hydroxide to be the sole molten component in the waste calcine and emphasized the requirement for waste blending if fluid calcines are to be achieved. Other calcine phases identified in the thermodynamic analysis indicate the significant thermal reconstitution accomplished in calcination

Refuse-derived fuel from municipal solid waste residuals : a feasibility study[Manure, biosolids, and organic industrial/commercial residuals in land applications programs : improving beneficial reuse and protection of water quality

Energy Technology Data Exchange (ETDEWEB)

Sturgess, C.; Johnson, R. [Alberta Research Council, Vegreville, AB (Canada). Environmental Technologies; Schubert, J. [EWMC Operations, Edmonton, AB (Canada)

2007-07-01

Edmonton's Waste Management Centre (EWMC) consists of a composting plant and a materials recovery facility, which accepts over 230,000 tonnes of residential waste per year. It removes 74,000 tonnes of residuals from these two facilities through a series of processing and refining stages and landfilling. Alternative waste management strategies are being considered to handle these residuals as the city's landfill site is approaching its maximum capacity. One option that takes advantage of the high calorific value of these residues is gasification. To ensure consistent and uniform gasification, the residuals have to be processed to a homogenous feedstock. This paper outlined the steps that were taken to characterize the four distinct residual streams, process them to a refuse-derived fluff and pelletize mixtures of these four streams with specific additives. The paper discussed pellet criteria; feedstock preparation; the physical and chemical properties of the fluff and pelletized mixture; pelletization; and, cost estimates of the processing stages involved. Last, a summary of the project was provided. The first phase of the project has been completed. The second phase of the project involves the development of the optimum business case, which includes further cost assessment of the feedstock preparation stage; leasing commercial scale equipment to establish efficiency and robustness of the process; assessing an alternative feeding system for the gasification system; and evaluating methanol production using a catalyst to convert the syngas to methanol. 5 tabs., 4 figs.

Determining the release of radionuclides from tank waste residual solids. FY2015 report

Energy Technology Data Exchange (ETDEWEB)

King, William D. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Hobbs, David T. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

2015-09-11

Methodology development for pore water leaching studies has been continued to support Savannah River Site High Level Waste tank closure efforts. For FY2015, the primary goal of this testing was the achievement of target pH and Eh values for pore water solutions representative of local groundwater in the presence of grout or grout-representative (CaCO₃ or FeS) solids as well as waste surrogate solids representative of residual solids expected to be present in a closed tank. For oxidizing conditions representative of a closed tank after aging, a focus was placed on using solid phases believed to be controlling pH and E_h at equilibrium conditions. For three pore water conditions (shown below), the target pH values were achieved to within 0.5 pH units. Tank 18 residual surrogate solids leaching studies were conducted over an E_h range of approximately 630 mV. Significantly higher Eh values were achieved for the oxidizing conditions (ORII and ORIII) than were previously observed. For the ORII condition, the target Eh value was nearly achieved (within 50 mV). However, E_h values observed for the ORIII condition were approximately 160 mV less positive than the target. E_h values observed for the RRII condition were approximately 370 mV less negative than the target. Achievement of more positive and more negative E_h values is believed to require the addition of non-representative oxidants and reductants, respectively. Plutonium and uranium concentrations measured during Tank 18 residual surrogate solids leaching studies under these conditions (shown below) followed the general trends predicted for plutonium and uranium oxide phases, assuming equilibrium with dissolved oxygen. The highest plutonium and uranium concentrations were observed for the ORIII condition and the lowest concentrations were observed for the RRII condition. Based on these results, it is recommended that these test methodologies be used to

Mechanisms and modelling of waste-cement and cement-host rock interactions

Science.gov (United States)

2017-06-01

Safe and sustainable disposal of hazardous and radioactive waste is a major concern in today's industrial societies. The hazardous waste forms originate from residues of thermal treatment of waste, fossil fuel combustion and ferrous/non-ferrous metal smelting being the most important ones in terms of waste production. Low- and intermediate-level radioactive waste is produced in the course of nuclear applications in research and energy production. For both waste forms encapsulation in alkaline, cement-based matrices is considered to ensure long-term safe disposal. Cementitious materials are in routine use as industrial materials and have mainly been studied with respect to their evolution over a typical service life of several decades. Use of these materials in waste management applications, however, requires assessments of their performance over much longer time periods on the order of thousands to several ten thousands of years.

Adsorption Property and Mechanism of Oxytetracycline onto Willow Residues

Directory of Open Access Journals (Sweden)

Di Wang

2017-12-01

Full Text Available To elucidate the adsorption property and the mechanism of plant residues to reduce oxytetracycline (OTC, the adsorption of OTC onto raw willow roots (WR-R, stems (WS-R, leaves (WL-R, and adsorption onto desugared willow roots (WR-D, stems (WS-D, and leaves (WL-D were investigated. The structural characterization was analyzed by scanning electron microscopy, Fourier-transform infrared spectra, and an elemental analyzer. OTC adsorption onto the different tissues of willow residues was compared and correlated with their structures. The adsorption kinetics of OTC onto willow residues was found to follow the pseudo-first-order model. The isothermal adsorption process of OTC onto the different tissues of willow residues followed the Langmuir and Freundlich model and the process was also a spontaneous endothermic reaction, which was mainly physical adsorption. After the willow residues were desugared, the polarity decreased and the aromaticity increased, which explained why the adsorption amounts of the desugared willow residues were higher than those of the unmodified residues. These observations suggest that the raw and modified willow residues have great potential as adsorbents to remove organic pollutants.

Urine: Waste product or biologically active tissue?

Science.gov (United States)

2018-03-01

Historically, urine has been viewed primarily as a waste product with little biological role in the overall health of an individual. Increasingly, data suggest that urine plays a role in human health beyond waste excretion. For example, urine might act as an irritant and contribute to symptoms through interaction with-and potential compromise of-the urothelium. To explore the concept that urine may be a vehicle for agents with potential or occult bioactivity and to discuss existing evidence and novel research questions that may yield insight into such a role, the National Institute of Diabetes and Digestive and Kidney Disease invited experts in the fields of comparative evolutionary physiology, basic science, nephrology, urology, pediatrics, metabolomics, and proteomics (among others) to a Urinology Think Tank meeting on February 9, 2015. This report reflects ideas that evolved from this meeting and current literature, including the concept of urine quality, the biological, chemical, and physical characteristics of urine, including the microbiota, cells, exosomes, pH, metabolites, proteins, and specific gravity (among others). Additionally, the manuscript presents speculative, and hopefully testable, ideas about the functional roles of urine constituents in health and disease. Moving forward, there are several questions that need further understanding and pursuit. There were suggestions to consider actively using various animal models and their biological specimens to elaborate on basic mechanistic information regarding human bladder dysfunction. Published 2018. This article is a U.S. Government work and is in the public domain in the USA.

Methods for conditioning wastes from spent fuel cans and dissolver residues

International Nuclear Information System (INIS)

De Regge, P.; Loida, A.; Schmidt-Hansberg, T.; Sombret, C.

1985-04-01

Several methods for conditioning spent fuel decladding hulls or dissolver residues have been considered in various countries of the European Community. Five of these methods use embedding technique with or without prior compaction: they are based on incorporation in metallic alloys, glass, ceramics, cements and metals or graphite compounds. A sixth one consists in melting the decladding materials. The corresponding research programs have been pursued to varying states of progress with regard to demonstrating their feasibility on an industrial scale and the use of genuine wastes in bench scale experiments. The properties of the conditioned wastes have been investigated. Special attention has been paid to the corrosion resistance to various aqueous media as tap water, brine or clayey water. Although no categorical conclusion can be drawn from the initial results, the available finding provide a basis for assessing the different processes [fr

The effects of crystallization and residual glass on the chemical durability of iron phosphate waste forms containing 40 wt% of a high MoO3 Collins-CLT waste

Science.gov (United States)

Hsu, Jen-Hsien; Bai, Jincheng; Kim, Cheol-Woon; Brow, Richard K.; Szabo, Joe; Zervos, Adam

2018-03-01

The effects of cooling rate on the chemical durability of iron phosphate waste forms containing up to 40 wt% of a high MoO3 Collins-CLT waste simulant were determined at 90 °C using the product consistency test (PCT). The waste form, designated 40wt%-5, meets appropriate Department of Energy (DOE) standards when rapidly quenched from the melt (as-cast) and after slow cooling following the CCC (canister centerline cooling)-protocol, although the quenched glass is more durable. The analysis of samples from the vapor hydration test (VHT) and the aqueous corrosion test (differential recession test) reveals that rare earth orthophosphate (monazite) and Zr-pyrophosphate crystals that form on cooling are more durable than the residual glass in the 40wt%-5 waste form. The residual glass in the CCC-treated samples has a greater average phosphate chain length and a lower Fe/P ratio, and those contribute to its faster corrosion kinetics.

Inventories of woody residues and solid wood waste in the United States, 2002

Science.gov (United States)

David B. McKeever

2004-01-01

Large amounts of woody residues and wood waste are generated annually in the United States. In 2002, an estimated 240 million metric tons was generated during the extraction of timber from the Nation’s forests, from forestry cultural operations, in the conversion of forest land to nonforest uses, in the initial processing of roundwood timber into usable products, in...

Energy and Regge residues in quantum-mechanical ''QCD'' sum rules

International Nuclear Information System (INIS)

Durand, B.; Durand, L.

1986-01-01

It was shown recently by Fishbane, Kaus, and Gasiorowicz that the residues at the poles of quantum-mechanical two-point functions for arbitrary angular momenta l have an incorrect l dependence when calculated by the sum-rule method used for the analogous problem in QCD. Knowledge of the residues is of interest since they are directly related to particle couplings and decay widths. We develop reliable expressions for the energy and Regge residues using semiclassical methods

Glasses obtained from industrial wastes; Vidros obtidos a partir de residuos industriais

Energy Technology Data Exchange (ETDEWEB)

Bortoluzzi, D.; Oliveira Fillho, J.; Uggioni, E. [Universidade do Extremo Sul Catarinense (UNESC), Criciuma, SC (Brazil). Curso de Engenharia de Materiais; Bernardin, A.M., E-mail: amb@unesc.ne [Servico Nacional de Aprendizagem Industrial (SENAI), Tijucas, SC (Brazil). Tecnologia em Ceramica

2009-07-01

This paper deals with the study of the vitrification mechanism as an inertization method for industrial wastes contaminated with heavy metals. Ashes from coal (thermoelectric), wastes from mining (fluorite and feldspar) and plating residue were used to compose vitreous systems planed by mixture design. The chemical composition of the wastes was determined by XRF and the formulations were melted at 1450 deg C for 2h using 10%wt of CaCO{sub 3} (fluxing agent). The glasses were poured into a mold and annealed (600 deg C). The characteristic temperatures were determined by thermal analysis (DTA, air, 20 deg C/min) and the mechanical behavior by Vickers microhardness. As a result, the melting temperature is strongly dependent on silica content of each glass, and the fluorite residue, being composed mainly by silica, strongly affects Tm. The microhardness of all glasses is mainly affected by the plating residue due to the high iron and zinc content of this waste. (author)

ERG review of waste package corrosion mechanisms

International Nuclear Information System (INIS)

Geisert, R.E.

1988-01-01

The Engineering Review Group (ERG) was established by the Office of Nuclear Waste Isolation (ONWI) to help evaluate engineering-related issues in the US Department of Energy's nuclear waste repository program. The ERG reviewed the waste package corrosion mechanisms. This report documents the ERG's comments and recommendations on these subjects and the ONWI response to the specific points raised by the ERG. 1 ref

Waste water biological purification plants of dairy products industry and energy management

Science.gov (United States)

Stepanov, Sergey; Solkina, Olga; Stepanov, Alexander; Zhukova, Maria

2017-10-01

The paper presents results of engineering and economical comparison of waste water biological purification plants of dairy products industry. Three methods of purification are compared: traditional biological purification with the use of secondary clarifiers and afterpurification through granular-bed filters, biomembrane technology and physical-and-chemical treatment together with biomembrane technology for new construction conditions. The improvement of the biological purification technology using nitro-denitrification and membrane un-mixing of sludge mixture is a promising trend in this area. In these calculations, an energy management which is widely applied abroad was used. The descriptions of the three methods are illustrated with structural schemes. Costs of equipment and production areas are taken from manufacturers’ data. The research is aimed at an engineering and economical comparison of new constructions of waste water purification of dairy products industry. The experiment demonstrates advantages of biomembrane technology in waste water purification. This technology offers prospects of 122 million rubles cost saving during 25 years of operation when compared with of the technology of preparatory reagent flotation and of 13.7 million rubles cost saving compared to the option of traditional biological purification.

The Rocky Flats Plant Waste Stream and Residue Identification and Characterization Program (WSRIC): Progress and achievements

International Nuclear Information System (INIS)

Ideker, V.L.

1994-01-01

The Waste Stream and Residue Identification and Characterization (WSRIC) Program, as described in the WSRIC Program Description delineates the process knowledge used to identify and characterize currently-generated waste from approximately 5404 waste streams originating from 576 processes in 288 buildings at Rocky Flats Plant (RFP). Annual updates to the WSRIC documents are required by the Federal Facilities Compliance Agreement between the US Department of Energy, the Colorado Department of Health and the Environmental Protection Agency. Accurate determination and characterization of waste is a crucial component in RFP's waste management strategy to assure compliance with Resource Conservation and Recovery Act (RCRA) storage and treatment requirements, as well as disposal acceptance criteria. The WSRIC Program was rebaselined in September 1992, and serves as the linchpin for documenting process knowledge in RFP's RCRA operating record. Enhancements to the WSRIC include strengthening the waste characterization rationale, expanding WSRIC training for waste generators, and incorporating analytical information into the WSRIC building books. These enhancements will improve credibility with the regulators and increase waste generators' understanding of the basis for credible waste characterizations

Recovery of plutonium from the combustion residues of alpha-bearing solid wastes

International Nuclear Information System (INIS)

Gompper, K.; Wieczorek, H.

1991-01-01

Experimental researches on plutonium dioxide dissolution in nitric acid in inactive and alpha-bearing wastes are presented in this report. After a review of the literature published on dissolution methods of PuO 2 combustion residues. Then results obtained in the ALONA plant on the dissolution of plutonium containing ashes in sulfuric acid and nitric acid are presented. Plutonium purification is studied. At last a simplified scheme of processing based on results obtained

Mining utilization of residues of exhaust gas cleaning from waste incinerators; Bergtechnische Verwertung von Abgasreinigungsrueckstaenden aus Verbrennungsanlagen

Energy Technology Data Exchange (ETDEWEB)

Werthmann, Rainer [K+S Entsorgung GmbH, Kassel (Germany). Abfallchemie und Zulassungen

2013-03-01

The exhaust gas purification of a household incinerator or a substitute fuel power plant intends to remove dust, heavy metal compounds and acid harmful gases from the exhaust gas in order to comply with the immission-control legal limits. The particulate matter contains volatile heavy metal chlorides which precipitate as a solid matter. The enhanced amount of water-soluble salts is conspicuous. The concentration of soluble components is limited to 10,000 mg/L in the 1:10 eluate due to the landfill regulation. Thus, the residues of exhaust gas cleaning are predestined for an underground waste disposal in salt mines. Under this aspect, the author of the contribution under consideration reports on the mining utilization of residues of exhaust gas cleaning from waste incinerators.

Exposure to radiation through the residual activity of waste treated by conventional methods

International Nuclear Information System (INIS)

Deckert, A.; Hoppe, G.; John, T.; Thierfeldt, S.

1993-01-01

Data obtained by questionnaires provided information on the type, amount, nuclide vector and maximum permissible value of low-level radioactive residues that occur in nuclear installations of due to industrial, scientific and medical uses of radioactive materials and are officially released to be disposed of by conventional methods. The general legal background of waste disposal methods, in particular the official regulations surrounding the waste disposal law, were described. On this basis, parameters and maximum radioactive burdens were specifically defined for garbage dumps for refuse from private households and those for building rubbish. Investigations were carried out into exposure paths that may have a role in the radioactive doses taken up by personnel (inhalation) or the general population (ingestion) through contaminated water. The radiation dose attributable to those exposure paths were expressed in relation to a specific unit activity of waste (1 bq/G). A dose of 10 μ Sv/r was taken as a standard to define a threshold value for each individual nuclide released for conventional waste disposal. It appears reasonable that such values are determined for groups of nuclides. (HP) [de

Cost comparison between private and public collection of residual household waste: Multiple case studies in the Flemish region of Belgium

International Nuclear Information System (INIS)

Jacobsen, R.; Buysse, J.; Gellynck, X.

2013-01-01

Highlights: ► The goal is to compare collection costs for residual household waste. ► We have clustered all municipalities in order to find mutual comparable pairs. ► Each pair consists of one private and one public operating waste collection program. ► All cases show that private service has lower costs than public service. ► Municipalities were contacted to identify the deeper causes for the waste management program. - Abstract: The rising pressure in terms of cost efficiency on public services pushes governments to transfer part of those services to the private sector. A trend towards more privatizing can be noticed in the collection of municipal household waste. This paper reports the findings of a research project aiming to compare the cost between the service of private and public collection of residual household waste. Multiple case studies of municipalities about the Flemish region of Belgium were conducted. Data concerning the year 2009 were gathered through in-depth interviews in 2010. In total 12 municipalities were investigated, divided into three mutual comparable pairs with a weekly and three mutual comparable pairs with a fortnightly residual waste collection. The results give a rough indication that in all cases the cost of private service is lower than public service in the collection of household waste. Albeit that there is an interest in establishing whether there are differences in the costs and service levels between public and private waste collection services, there are clear difficulties in establishing comparisons that can be made without having to rely on a large number of assumptions and corrections. However, given the cost difference, it remains the responsibility of the municipalities to decide upon the service they offer their citizens, regardless the cost efficiency: public or private.

Cost comparison between private and public collection of residual household waste: Multiple case studies in the Flemish region of Belgium

Energy Technology Data Exchange (ETDEWEB)

Jacobsen, R., E-mail: ray.jacobsen@ugent.be [Department of Agricultural Economics, Ghent University, Coupure Links 653, B-9000 Ghent (Belgium); Buysse, J., E-mail: j.buysse@ugent.be [Department of Agricultural Economics, Ghent University, Coupure Links 653, B-9000 Ghent (Belgium); Gellynck, X., E-mail: xavier.gellynck@ugent.be [Department of Agricultural Economics, Ghent University, Coupure Links 653, B-9000 Ghent (Belgium)

2013-01-15

Highlights: Black-Right-Pointing-Pointer The goal is to compare collection costs for residual household waste. Black-Right-Pointing-Pointer We have clustered all municipalities in order to find mutual comparable pairs. Black-Right-Pointing-Pointer Each pair consists of one private and one public operating waste collection program. Black-Right-Pointing-Pointer All cases show that private service has lower costs than public service. Black-Right-Pointing-Pointer Municipalities were contacted to identify the deeper causes for the waste management program. - Abstract: The rising pressure in terms of cost efficiency on public services pushes governments to transfer part of those services to the private sector. A trend towards more privatizing can be noticed in the collection of municipal household waste. This paper reports the findings of a research project aiming to compare the cost between the service of private and public collection of residual household waste. Multiple case studies of municipalities about the Flemish region of Belgium were conducted. Data concerning the year 2009 were gathered through in-depth interviews in 2010. In total 12 municipalities were investigated, divided into three mutual comparable pairs with a weekly and three mutual comparable pairs with a fortnightly residual waste collection. The results give a rough indication that in all cases the cost of private service is lower than public service in the collection of household waste. Albeit that there is an interest in establishing whether there are differences in the costs and service levels between public and private waste collection services, there are clear difficulties in establishing comparisons that can be made without having to rely on a large number of assumptions and corrections. However, given the cost difference, it remains the responsibility of the municipalities to decide upon the service they offer their citizens, regardless the cost efficiency: public or private.

Baseline levels of bioaerosols and volatile organic compounds around a municipal waste incinerator prior to the construction of a mechanical-biological treatment plant

International Nuclear Information System (INIS)

Vilavert, Lolita; Nadal, Marti; Inza, Isabel; Figueras, Maria J.; Domingo, Jose L.

2009-01-01

New waste management programs are currently aimed at developing alternative treatment technologies such as mechanical-biological treatment (MBT) and composting plants. However, there is still a high uncertainty concerning the chemical and microbiological risks for human health, not only for workers of these facilities, but also for the population living in the neighborhood. A new MBT plant is planned to be constructed adjacently to a municipal solid waste incinerator (MSWI) in Tarragona (Catalonia, Spain). In order to evaluate its potential impact and to differentiate the impacts of MSWI from those of the MBT when the latter is operative, a pre-operational survey was initiated by determining the concentrations of 20 volatile organic compounds (VOCs) and bioaerosols (total bacteria, Gram-negative bacteria, fungi and Aspergillus fumigatus) in airborne samples around the MSWI. The results indicated that the current concentrations of bioaerosols (ranges: 382-3882, 18-790, 44-926, and 3 for fungi at 25 deg. C, fungi at 37 deg. C, total bacteria, and Gram-negative bacteria, respectively) and VOCs (ranging from 0.9 to 121.2 μg/m 3 ) are very low in comparison to reported levels in indoor and outdoor air in composting and MBT plants, as well in urban and industrial zones. With the exception of total bacteria, no correlations were observed between the environmental concentrations of biological agents and the direction/distance from the facility. However, total bacteria presented significantly higher levels downwind. Moreover, a non-significant increase of VOCs was detected in sites closer to the incinerator, which means that the MSWI could have a very minor impact on the surrounding environment.

Merger of waste in kaolin panels medium density

International Nuclear Information System (INIS)

Bezerra, A.F.C.; Santana, L.N.L.; Neves, G.A.

2011-01-01

Medium-density panels are molded under pressure and temperature and have physical and mechanical properties similar to those of solid wood. Their composition involves fibers of eucalyptus and pine, but other residues as kaolin waste can be incorporated. The objective was to manufacture medium density panels incorporating kaolin waste and compare the physical, chemical and mechanical properties of these with other commercials. The residue was subjected to the following characterization tests: X-ray diffraction, chemical analysis, differential thermal analysis, thermal gravimetric analysis and size analysis.Through the process of pressing the samples were prepared, they were evaluated for their flexural strength and tensile strength perpendicular to the water absorption / swelling in thickness, density and moisture content. According to the analyzed results, we conclude that samples having the residue had lower levels of swelling, tensile and flexural strength and higher levels of absorption.(author)

Biological denitrification of high-nitrates wastes generated in the nuclear industry

International Nuclear Information System (INIS)

Francis, C.W.

1980-01-01

Biological denitrification appears to be one of the most effective methods to remove nitrates from wastewater streams (Christenson and Harremoes, 1975). However, most of the research and development work has been centered on removal of nitrates from sewage or agricultural drainage waters, nitrate nitrogen concentration usually less than 50 g/m 3 . Work was initiated at Oak Ridge National Laboratory (ORNL) in 1974 to test the use of biological nitrification in the removal of high concentrations of nitrate (in excess of 1.0 kg NO 3 -N/m 3 ) from uranium purification waste streams. Since then, a full-scale treatment facility, a stirred reactor, has been installed at the Y-12 plant; and a pilot-plant, using a fluidized bed, has been proposed at Portsmouth Gaseous Diffusion Plant. The objective of this manuscript is to present some applied microbiological research relating to possible constraints in biologically denitrifying certain waste streams in the nuclear industry and comparing the effectiveness of denitrification of these waste streams in three bench scale reactors, (1) a continuous flow-stirred reactor, (2) stirred bed rector, and (3) a fluidized bed reactor

Experimental research on the residual mechanical properties of an ordinary concretes after fire

OpenAIRE

Santos, C.C.; Rodrigues, J.P.

2015-01-01

This paper summarizes the results of an experimental research to assess the residual mechanical properties of an ordinary concrete after fire. It was studied the influence of the cooling process, the maximum temperature that the concrete was subjected to and the loading level on the residual mechanical properties of calcareous and granite aggregate concretes. The properties studied were the residual compressive, tensile, splitting and flexural strengths and modulus of elasticit...

Biogas Production from Vietnamese Animal Manure, Plant Residues and Organic Waste: Influence of Biomass Composition on Methane Yield

Directory of Open Access Journals (Sweden)

T. T. T. Cu

2015-02-01

Full Text Available Anaerobic digestion is an efficient and renewable energy technology that can produce biogas from a variety of biomasses such as animal manure, food waste and plant residues. In developing countries this technology is widely used for the production of biogas using local biomasses, but there is little information about the value of these biomasses for energy production. This study was therefore carried out with the objective of estimating the biogas production potential of typical Vietnamese biomasses such as animal manure, slaughterhouse waste and plant residues, and developing a model that relates methane (CH4 production to the chemical characteristics of the biomass. The biochemical methane potential (BMP and biomass characteristics were measured. Results showed that piglet manure produced the highest CH4 yield of 443 normal litter (NL CH4 kg−1 volatile solids (VS compared to 222 from cows, 177 from sows, 172 from rabbits, 169 from goats and 153 from buffaloes. Methane production from duckweed (Spirodela polyrrhiza was higher than from lawn grass and water spinach at 340, 220, and 110.6 NL CH4 kg−1 VS, respectively. The BMP experiment also demonstrated that the CH4 production was inhibited with chicken manure, slaughterhouse waste, cassava residue and shoe-making waste. Statistical analysis showed that lipid and lignin are the most significant predictors of BMP. The model was developed from knowledge that the BMP was related to biomass content of lipid, lignin and protein from manure and plant residues as a percentage of VS with coefficient of determination (R-square at 0.95. This model was applied to calculate the CH4 yield for a household with 17 fattening pigs in the highlands and lowlands of northern Vietnam.

Biogas production from vietnamese animal manure, plant residues and organic waste: influence of biomass composition on methane yield.

Science.gov (United States)

Cu, T T T; Nguyen, T X; Triolo, J M; Pedersen, L; Le, V D; Le, P D; Sommer, S G

2015-02-01

Anaerobic digestion is an efficient and renewable energy technology that can produce biogas from a variety of biomasses such as animal manure, food waste and plant residues. In developing countries this technology is widely used for the production of biogas using local biomasses, but there is little information about the value of these biomasses for energy production. This study was therefore carried out with the objective of estimating the biogas production potential of typical Vietnamese biomasses such as animal manure, slaughterhouse waste and plant residues, and developing a model that relates methane (CH4) production to the chemical characteristics of the biomass. The biochemical methane potential (BMP) and biomass characteristics were measured. Results showed that piglet manure produced the highest CH4 yield of 443 normal litter (NL) CH4 kg(-1) volatile solids (VS) compared to 222 from cows, 177 from sows, 172 from rabbits, 169 from goats and 153 from buffaloes. Methane production from duckweed (Spirodela polyrrhiza) was higher than from lawn grass and water spinach at 340, 220, and 110.6 NL CH4 kg(-1) VS, respectively. The BMP experiment also demonstrated that the CH4 production was inhibited with chicken manure, slaughterhouse waste, cassava residue and shoe-making waste. Statistical analysis showed that lipid and lignin are the most significant predictors of BMP. The model was developed from knowledge that the BMP was related to biomass content of lipid, lignin and protein from manure and plant residues as a percentage of VS with coefficient of determination (R-square) at 0.95. This model was applied to calculate the CH4 yield for a household with 17 fattening pigs in the highlands and lowlands of northern Vietnam.

Characterization of toxic waste produced in PYMES manufacturing detergents

International Nuclear Information System (INIS)

Campuzano, Silvia; Camacho, Judith Elena; Alvarez, Alicia

2006-01-01

From the protection of the environment, the problem of the residuals squatter a main place in the environmental administration; presently study a test pilot was standardized, to characterize the toxic waste generated in the production of detergents, to standardize methods of chemical valuation and microbiological of polluted waters that allow later on to apply methods of biological purification and processes of bio-treatment of residuals, the project macro of handling of toxic waste it was addressed this way in small and medium companies producers of detergents. The presence settled down of toxic in the studied waste, represented in surfactants significant amounts, phenols, hydrocarbons, fat and phosphates and the decrease of its quantity in front of the action of bacteria, situation that allowed concluding that the approach to the biotransformation process could be carried out

Minimization of zirconium chlorinator residues

International Nuclear Information System (INIS)

Green, G.K.; Harbuck, D.D.

1995-01-01

Zirconium chlorinator residues contain an array of rare earths, scandium, unreacted coke, and radioactive thorium and radium. Because of the radioactivity, the residues must be disposed in special waste containment facilities. As these sites become more congested, and with stricter environmental regulations, disposal of large volumes of wastes may become more difficult. To reduce the mass of disposed material, the US Bureau of Mines (USBM) developed technology to recover rare earths, thorium and radium, and unreacted coke from these residues. This technology employs an HCl leach to solubilize over 99% of the scandium and thorium, and over 90% of the rare earths. The leach liquor is processed through several solvent extraction stages to selectively recover scandium, thorium, and rare earths. The leach residue is further leached with an organic acid to solubilize radium, thus allowing unreacted coke to be recycled to the chlorinator. The thorium and radium waste products, which comprise only 2.1% of the original residue mass, can then be sent to the radioactive waste facility

Tank 16 Annulus Cleanout Analysis Doses at Seepline from Transport of Residual Tc-99 Wastes

International Nuclear Information System (INIS)

Collard, L.B.

1999-01-01

An analysis of residual Tc-99 in the Tank 16 annulus was conducted to assess the potential benefit from cleaning the annulus. One analysis was performed for the as-is case to determine seepline doses if no clean out occurs. Another analysis was performed assuming that ninety percent of existing contaminants are removed. Characterization data for samples retrieved from the annulus were used in the analysis. Only Tc-99 was analyzed because preliminary modeling identified it as the highest dose contributor. The effect of residual waste in piping was not analyzed

Development of biological treatment of high concentration sodium nitrate waste liquid

International Nuclear Information System (INIS)

Ogawa, Naoki; Kuroda, Kazuhiko; Shibata, Katsushi; Kawato, Yoshimi; Meguro, Yoshihiro; Takahashi, Kuniaki

2009-01-01

An electrolytic reduction, chemical reduction, and biological reduction have been picked up as a method of nitrate liquid waste treatment system exhausted from the reprocessing process. As a result of comparing them, it was shown that the biological treatment was the most excellent method in safety and the economy. (author)

Flow analysis of heavy metals in a pilot-scale incinerator for residues from waste electrical and electronic equipment dismantling

International Nuclear Information System (INIS)

Long, Yu-Yang; Feng, Yi-Jian; Cai, Si-Shi; Ding, Wei-Xu; Shen, Dong-Sheng

2013-01-01

Highlights: • Cu, Zn, Pb, and Ni are enriched in bottom ash from WEEE dismantling residues. • The heavy metal residual fraction restricts transfer in the incinerator. • Pre-treatment to remove heavy metals from WEEE residues would reduce emissions. -- Abstract: The large amount of residues generated from dismantling waste electrical and electronic equipment (WEEE) results in a considerable environmental burden. We used material flow analysis to investigate heavy metal behavior in an incineration plant in China used exclusively to incinerate residues from WEEE dismantling. The heavy metals tested were enriched in the bottom and fly ashes after incineration. However, the contents of heavy metals in the bottom ash, fly ash and exhaust gas do not have a significant correlation with that of the input waste. The evaporation and recondensation behavior of heavy metals caused their contents to differ with air pollution control equipment because of the temperature difference during gas venting. Among the heavy metals tested, Cd had the strongest tendency to transfer during incineration (T Cd = 69.5%) because it had the lowest melting point, followed by Cu, Ni, Pb and Zn. The exchangeable and residual fractions of heavy metals increased substantially in the incineration products compared with that of the input residues. Although the mass of residues from WEEE dismantling can be reduced by 70% by incineration, the safe disposal of the metal-enriched bottom and fly ashes is still required

Flow analysis of heavy metals in a pilot-scale incinerator for residues from waste electrical and electronic equipment dismantling

Energy Technology Data Exchange (ETDEWEB)

Long, Yu-Yang; Feng, Yi-Jian; Cai, Si-Shi; Ding, Wei-Xu; Shen, Dong-Sheng, E-mail: shends@zju.edu.cn

2013-10-15

Highlights: • Cu, Zn, Pb, and Ni are enriched in bottom ash from WEEE dismantling residues. • The heavy metal residual fraction restricts transfer in the incinerator. • Pre-treatment to remove heavy metals from WEEE residues would reduce emissions. -- Abstract: The large amount of residues generated from dismantling waste electrical and electronic equipment (WEEE) results in a considerable environmental burden. We used material flow analysis to investigate heavy metal behavior in an incineration plant in China used exclusively to incinerate residues from WEEE dismantling. The heavy metals tested were enriched in the bottom and fly ashes after incineration. However, the contents of heavy metals in the bottom ash, fly ash and exhaust gas do not have a significant correlation with that of the input waste. The evaporation and recondensation behavior of heavy metals caused their contents to differ with air pollution control equipment because of the temperature difference during gas venting. Among the heavy metals tested, Cd had the strongest tendency to transfer during incineration (T{sub Cd} = 69.5%) because it had the lowest melting point, followed by Cu, Ni, Pb and Zn. The exchangeable and residual fractions of heavy metals increased substantially in the incineration products compared with that of the input residues. Although the mass of residues from WEEE dismantling can be reduced by 70% by incineration, the safe disposal of the metal-enriched bottom and fly ashes is still required.

Remaining Sites Verification Package for the 100-F-52, 146-FR Radioecology and Aquatic Biology Laboratory Soil, Waste Site Reclassification Form 2008-022

Energy Technology Data Exchange (ETDEWEB)

J. M. Capron

2008-06-27

The 100-F-52 waste site consisted of the soil under and around the former 146-FR Radioecology and Aquatic Biology Laboratory. The laboratory was used for studies of the effects of pre-reactor and post-reactor process water on fish eggs, young fish, and other small river creatures of interest. In accordance with this evaluation, the confirmatory sampling results support a reclassification of this site to No Action. The current site conditions achieve the remedial action objectives and the corresponding remedial action goals established in the Remaining Sites ROD. The results of confirmatory sampling show that residual contaminant concentrations do not preclude any future uses and allow for unrestricted use of shallow zone soils. The results also demonstrate that residual contaminant concentrations are protective of groundwater and the Columbia River.

Biodegradation of chlorinated unsaturated hydrocarbons in relation to biological waste-gas treatment

NARCIS (Netherlands)

Hartmans, S.

1993-01-01

The original goal of the research described in this thesis was to develop a biological process for the removal of vinyl chloride from waste gases. The gaseous and carcinogenic vinyl chloride is used to produce the plastic polyvinyl chloride (PVC). During this production process waste gases

Composition of waste materials and recyclables

DEFF Research Database (Denmark)

Götze, Ramona

involves several steps to prepare the samples mechanically and/or chemically for final analysis. Not all sample preparation methods are equally well suited for specific waste characterization purposes. The correctness of results and practical feasibility of sample preparation was strongly affected...... for future modelling and assessment of waste management systems. The analyzed fractions were selected based on material properties with relevance for potential recycling processes. The physico-chemical analysis revealed chemical differences between residual and source-segregated samples for several fractions....... The results for parameters associated with organic matter confirmed the idea of cross-contaminated recyclables in residual waste, whereas the results for heavy metals and trace elements were more complex. For many fractions rather high metal contents were found to be intrinsic properties of the recyclables...

Woody residues and solid waste wood available for recovery in the United States, 2002

Science.gov (United States)

David B. McKeever; Robert H. Falk

2004-01-01

Large amounts of woody residues and solid wood waste are generated annually in the United States from the extraction of timber from forests, from forestry cultural operations, in the conversion of forest land to nonforest uses, in the initial processing of roundwood timber into usable products, in the construction and demolition of buildings and structures, and in the...

Life cycle assessment to compare the environmental impact of seven contemporary food waste management systems.

Science.gov (United States)

Edwards, Joel; Othman, Maazuza; Crossin, Enda; Burn, Stewart

2018-01-01

Municipal food waste (FW) represents 35-45% of household residual waste in Australia, with the nation generating 1.6Tg annually. It is estimated that 91% of this FW ends up in landfill. This study used life cycle assessment to determine and compare the environmental impact of seven contemporary FW management systems for two real-life jurisdictions; incorporating the complete waste service and expanding the system to include inert and garden waste. Although, no system exhibited a best ranking across all impact categories, FW digestion based systems were all revealed to have a lower global warming potential than composting and landfilling systems. Mechanical biological treatment, anaerobic co-digestion, and home composting all demonstrated the lowest environmental impacts for two or more of the environmental impact categories assessed. The assessment included market and technological specific variables and uncertainties providing a framework for robust decision making at a municipality level. Crown Copyright © 2017. Published by Elsevier Ltd. All rights reserved.

Heavy metal immobilization in soil near abandoned mines using eggshell waste and rapeseed residue.

Science.gov (United States)

Lee, Sang Soo; Lim, Jung Eun; El-Azeem, Samy A M Abd; Choi, Bongsu; Oh, Sang-Eun; Moon, Deok Hyun; Ok, Yong Sik

2013-03-01

Heavy metal contamination of agricultural soils has received great concern due to potential risk to human health. Cadmium and Pb are largely released from abandoned or closed mines in Korea, resulting in soil contamination. The objective of this study was to evaluate the effects of eggshell waste in combination with the conventional nitrogen, phosphorous, and potassium fertilizer (also known as NPK fertilizer) or the rapeseed residue on immobilization of Cd and Pb in the rice paddy soil. Cadmium and Pb extractabilities were tested using two methods of (1) the toxicity characteristics leaching procedure (TCLP) and (2) the 0.1 M HCl extraction. With 5 % eggshell addition, the values of soil pH were increased from 6.33 and 6.51 to 8.15 and 8.04 in combination with NPK fertilizer and rapeseed residue, respectively, compared to no eggshell addition. The increase in soil pH may contribute to heavy metal immobilization by altering heavy metals into more stable in soils. Concentrations of TCLP-extracted Cd and Pb were reduced by up to 67.9 and 93.2 % by addition of 5 % eggshell compared to control. For 0.1 M HCl extraction method, the concentration of 0.1 M HCl-Cd in soils treated with NPK fertilizer and rapeseed residue was significantly reduced by up to 34.01 and 46.1 %, respectively, with 5 % eggshell addition compared to control. A decrease in acid phosphatase activity and an increase in alkaline phosphatase activity at high soil pH were also observed. Combined application of eggshell waste and rapeseed residue can be cost-effective and beneficial way to remediate the soil contaminated with heavy metals.

Climate accounting for waste management, Phase I and II. Summary: Phase 1: Glass Packaging, Metal packaging, paper, cardboard, plastic and wet organic waste. Phase 2: Wood waste and residual waste from households; Klimaregnskap for avfallshaandtering, Fase I og II. Sammendrag: Fase 1: Glassemballasje, metallemballasje, papir, papp, plastemballasje og vaatorganisk avfall. Fase 2: Treavfall og restavfall fra husholdninger

Energy Technology Data Exchange (ETDEWEB)

Raadal, Hanne Lerche; Modahl, Ingunn Saur; Lyng, Kari-Anne

2009-09-15

involves the lowest greenhouse gas load for the types of waste glass packaging, metal packaging and plastic packaging. Biological treatment (biogas production) provides the lowest GHG (greenhouse gas) impact for the treatment of wet organic waste. Energy recovery provides the lowest GHG impact for the treatment of paper, cardboard and wood waste. Disposal provides the greatest greenhouse gas load for all the analyzed types of waste, but plastic and glass containers. For waste composition has a major impact on greenhouse gas emissions for the landfill and the energy efficiency of the waste. The composition varies both with the types of waste disposed and with what kind of source separation schemes offered in the various municipalities. This in turn can vary depending on population density (urban areas / cities versus scattered buildings), and motivation of the individual citizen to source sorting. Energy recovery means the lowest greenhouse gas emissions for an 'average composite' residual waste in Norway. Analysis of residual waste should always be considered in context with the total amounts and handling of sorted out waste types, as well as total amounts and composition of residual waste. This is important to achieve a comprehensive assessment and avoid suboptimalization. Transport related greenhouse gas emissions are generally of relatively little importance in relation to the environmental benefits arising from the material and / or energy utilization. 3. The model is used to calculate the net greenhouse gas emissions resulting from disposal of a total of approximately 4.1 million tons of waste from households, industry, construction and service industries. 4. Analysis of a realistic optimal scenario for disposal of household waste show that this system can be virtually carbon-neutral. 5. The choice of which assumptions to be incorporated in this type of analysis depends on the purpose of analysis, in addition to local and geographical conditions. 6. Relevant

Properties of sintered glass-ceramics prepared from plasma vitrified air pollution control residues

International Nuclear Information System (INIS)

Roether, J.A.; Daniel, D.J.; Amutha Rani, D.; Deegan, D.E.; Cheeseman, C.R.; Boccaccini, A.R.

2010-01-01

Air pollution control (APC) residues, obtained from a major UK energy from waste (EfW) plant, processing municipal solid waste, have been blended with silica and alumina and melted using DC plasma arc technology. The glass produced was crushed, milled, uni-axially pressed and sintered at temperatures between 750 and 1150 deg. C, and the glass-ceramics formed were investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Mechanical properties assessed included Vickers's hardness, flexural strength, Young's modulus and thermal shock resistance. The optimum sintering temperature was found to be 950 deg. C. This produced a glass-ceramic with high density (∼2.58 g/cm 3 ), minimum water absorption (∼2%) and relatively high mechanical strength (∼81 ± 4 MPa). Thermal shock testing showed that 950 deg. C sintered samples could withstand a 700 deg. C quench in water without micro-cracking. The research demonstrates that glass-ceramics can be readily formed from DC plasma treated APC residues and that these have comparable properties to marble and porcelain. This novel approach represents a technically and commercially viable treatment option for APC residues that allow the beneficial reuse of this problematic waste.

Practice of the utilization of biomass from waste materials; Praxis der Verwertung von Biomasse aus Abfaellen

Energy Technology Data Exchange (ETDEWEB)

Wiemer, Klaus; Kern, Michael; Raussen, Thomas (eds.)

2010-07-01

Within the 4th Witzenhaeuser Biomass Conference from 10th to 11th November, 2010, in Witzenhausen (Federal Republic of Germany) the following lectures were held: (1) Consequences of the amendment of the law of life-cycle management and biological waste regulations for the practice of acquisition and utilization of biological wastes (Claus-Gerhard Bergs); (2) An eco-efficient handling with biological wastes and composting wastes (Siegfried Kreibe); (3) Perspectives of the biological waste management (Michael Kern); (4) Assessment of waste biogas plants by environmental verifiers - implementation of the EEG novella (Michael Hub); (5) Fermentation of biogenic residuals - State of the art and perspectives (David Wilken); (6) Energy from cultivation masses and waste biomasses - Perspectives for Europe (Katja Bunzel); (7) Optimization of a biogas plant in practical operation (Michael Buchheit); (8) Odour situation and germ situation before and after an integration of a biogas plant in a composite system (Juergen Roth); (9) Aspects of immission protection rights according to the requirements on the permission and operation of biogas plants (Norbert Suritsch); (10) Actual veterinary regulatory, fertilizer regulatory and waste regulatory requirements on the treatment and utilization of fermentation products (Andreas Kirsch); (11) Utilization of fermentation residues from biological waste: Basic conditions and technology of processing (Thomas Raussen); (12) Practical experiences and new developments using selected examples: Pohlsche Heide, Baar (Switzerland) and Cesena (Italy) (Peter Lutz); (13) New facility concepts of dry fermentation in Lohfelden and Uelzen (Gunnar Ziehmann); (14) New facility concepts of plug flow fermentation (Michael Oertig); (15) Further development of the KOMPOFERM {sup registered} systems (Sandra Striewski); (16) Optimization of the gas yield and reduction of disruptive substances in the processing of biological wastes for the wet fermentation

An environmental analysis of options for utilising wasted food and food residue.

Science.gov (United States)

Oldfield, Thomas L; White, Eoin; Holden, Nicholas M

2016-12-01

The potential environmental impact of wasted food minimisation versus its utilisation in a circular bioeconomy is investigated based on a case study of Ireland. The amount of wasted food and food residue (WFFR) produced in 2010 was used for business-as-usual, (a) and four management options were assessed, (b) minimisation, (c) composting, (d) anaerobic digestion and (e) incineration. The environmental impacts Global Warming Potential (GWP), Acidification Potential (AP) and Eutrophication Potential (EP) were considered. A carbon return on investment (CRoI) was calculated for the three processing technologies (c-e). The results showed that a minimisation strategy for wasted food would result in the greatest reduction of all three impacts, -4.5 Mt CO 2 -e (GWP), -11.4 kt PO 4 3 -e (EP) and -43.9 kt SO 2 -e (AP) compared to business as usual. For WFFR utilisation in the circular bioeconomy, anaerobic digestion resulted in the lowest environmental impact and best CRoI of -0.84 kg CO 2 -e per Euro. From an economic perspective, for minimisation to be beneficial, 0.15 kg of wasted food would need to be reduced per Euro spent. Copyright © 2016 Elsevier Ltd. All rights reserved.

Morphology, composition, and mixing state of primary particles from combustion sources ? crop residue, wood, and solid waste

OpenAIRE

Liu, Lei; Kong, Shaofei; Zhang, Yinxiao; Wang, Yuanyuan; Xu, Liang; Yan, Qin; Lingaswamy, A. P.; Shi, Zongbo; Lv, Senlin; Niu, Hongya; Shao, Longyi; Hu, Min; Zhang, Daizhou; Chen, Jianmin; Zhang, Xiaoye

2017-01-01

Morphology, composition, and mixing state of individual particles emitted from crop residue, wood, and solid waste combustion in a residential stove were analyzed using transmission electron microscopy (TEM). Our study showed that particles from crop residue and apple wood combustion were mainly organic matter (OM) in smoldering phase, whereas soot-OM internally mixed with K in flaming phase. Wild grass combustion in flaming phase released some Cl-rich-OM/soot particles and cardboard combusti...

Identifying the key factors in increasing recycling and reducing residual household waste: a case study of the Flemish region of Belgium.

Science.gov (United States)

Gellynck, X; Jacobsen, R; Verhelst, P

2011-10-01

The competent waste authority in the Flemish region of Belgium created the 'Implementation plan household waste 2003-2007' and the 'Implementation plan sustainable management 2010-2015' to comply with EU regulation. It incorporates European and regional requirements and describes strategies, goals, actions and instruments for the collection and treatment of household waste. The central mandatory goal is to reduce and maintain the amount of residual household waste to 150 kg per capita per year between 2010-2015. In literature, a reasonable body of information has been published on the effectiveness and efficiency of a variety of policy instruments, but the information is complex, often contradictory and difficult to interpret. The objective of this paper is to identify, through the development of a binary logistic regression model, those variables of the waste collection scheme that help municipalities to reach the mandatory 150 kg goal. The model covers a number of variables for household characteristics, provision of recycling services, frequency of waste collection and charging for waste services. This paper, however, is not about waste prevention and reuse. The dataset originates from 2003. Four out of 12 variables in the model contributed significantly: income per capita, cost of residual waste collection, collection frequency and separate curbside collection of organic waste. Copyright © 2011 Elsevier Ltd. All rights reserved.

Hanford Tank 241-C-106: Residual Waste Contaminant Release Model and Supporting Data

International Nuclear Information System (INIS)

Deutsch, William J.; Krupka, Kenneth M.; Lindberg, Michael J.; Cantrell, Kirk J.; Brown, Christopher F.; Schaef, Herbert T.

2005-01-01

CH2M HILL is producing risk/performance assessments to support the closure of single-shell tanks at the DOE's Hanford Site. As part of this effort, staff at PNNL were asked to develop release models for contaminants of concern that are present in residual sludge remaining in tank 241-C-106 (C-106) after final retrieval of waste from the tank. This report provides the information developed by PNNL

Influence of Waste Brick Powder in the Mechanical Properties of Recycled Aggregate Concrete

Directory of Open Access Journals (Sweden)

Viviana Letelier

2018-03-01

Full Text Available Brick and concrete are the main materials contributing to demolition and construction waste. Considering this precedent, the effects of using both residuals in medium strength concretes are analyzed. Waste brick powder is used as a cement replacement in three different levels: 5%, 10%, and 15%, and it is tested in concretes with no recycled aggregates and concretes with 30% of recycled coarse aggregates replacing natural ones. The compressive strength, the flexural strength, and modulus of elasticity are calculated and compared to a control concrete with no brick powder and no recycled aggregates. The effects of the simultaneous use of both residuals on the physical properties of the recycled concrete are highlighted. Results show that 15% of cement can be replaced by waste brick powder together with 30% of recycled aggregates without suffering significant losses in the strength of the final material when compared to a control concrete.

Managing woodwaste: Yield from residue

Energy Technology Data Exchange (ETDEWEB)

Nielson, E. [LNS Services, Inc., North Vancouver, British Columbia (Canada); Rayner, S. [Pacific Waste Energy Inc., Burnaby, British Columbia (Canada)

1993-12-31

Historically, the majority of sawmill waste has been burned or buried for the sole purpose of disposal. In most jurisdictions, environmental legislation will prohibit, or render uneconomic, these practices. Many reports have been prepared to describe the forest industry`s residue and its environmental effect; although these help those looking for industry-wide or regional solutions, such as electricity generation, they have limited value for the mill manager, who has the on-hands responsibility for generation and disposal of the waste. If the mill manager can evaluate waste streams and break them down into their usable components, he can find niche market solutions for portions of the plant residue and redirect waste to poor/no-return, rather than disposal-cost, end uses. In the modern mill, residue is collected at the individual machine centre by waste conveyors that combine and mix sawdust, shavings, bark, etc. and send the result to the hog-fuel pile. The mill waste system should be analyzed to determine the measures that can improve the quality of residues and determine the volumes of any particular category before the mixing, mentioned above, occurs. After this analysis, the mill may find a niche market for a portion of its woodwaste.

Fuel gas production from animal and agricultural residues and biomass

Energy Technology Data Exchange (ETDEWEB)

Wise, D. L; Wentworth, R. L

1978-05-30

Progress was reported by all contractors. Topics presented include: solid waste to methane gas; pipeline fuel gas from an environmental cattle feed lot; heat treatment of organics for increasing anaerobic biodegradability; promoting faster anaerobic digestion; permselective membrane control of algae and wood digesters for increased production and chemicals recovery; anaerobic fermentation of agricultural residues; pilot plant demonstration of an anaerobic, fixed-film bioreactor for wastewater treatment; enhancement of methane production in the anaerobic diegestion of sewage; evaluation of agitation concepts for biogasification of sewage sludge; operation of a 50,000 gallon anaerobic digester; biological conversion of biomass to methane; dirt feedlot residue experiments; anaerobic fermentation of livestock and crop residues; current research on methanogenesis in Europe; and summary of EPA programs in digestion technology. (DC)

Proceedings of the 7. biennial residue-to-revenue residual wood conference 2007

International Nuclear Information System (INIS)

Raulin, J.

2007-01-01

This conference provided information on the highest and best use of residual wood, which is quickly becoming a valuable commodity. Issues concerning forest residues, sawmill wastes, agricultural residues and urban organic materials were discussed along with trends in Canadian surplus mill waste production. The evolving nature and technologies of the biomass business were highlighted with particular focus on how to generate energy and save money through the use of residual wood. Residual wood energy projects and developments in Canada, North America and Europe were outlined along with biomass development in relation to forest fires and insect disturbances. Cogeneration technologies using wood wastes for thermal heat, steam and electricity were also presented, along with transportation fuel technologies for the production of ethanol. It was noted that with the rising cost of energy, the forest industry is seeking energy solutions based on the use of residual wood. The range of economically practical residual wood solutions continues to grow as energy prices increase. The conference was attended by more than 200 delegates from the forest industry, suppliers and government representatives, to discuss policies and procedures currently in place. Industry investment is being stimulated by the potential for biofuels and biochemicals, as well as the co-operation between the forest and energy sectors. The conference featured 23 presentations, of which 12 have been catalogued separately for inclusion in this database. refs., tabs., figs

The residuals analysis project: Evaluating disposal options for treated mixed low-level waste

International Nuclear Information System (INIS)

Waters, R.D.; Gruebel, M.M.; Case, J.T.; Letourneau, M.J.

1997-01-01

For almost four years, the U.S. Department of Energy (DOE) through its Federal Facility Compliance Act Disposal Workgroup has been working with state regulators and governors' offices to develop an acceptable configuration for disposal of its mixed low-level waste (MLLW). These interactions have resulted in screening the universe of potential disposal sites from 49 to 15 and conducting ''performance evaluations'' for those fifteen sites to estimate their technical capabilities for disposal of MLLW. In the residuals analysis project, we estimated the volume of DOE's MLLW that will require disposal after treatment and the concentrations of radionuclides in the treated waste. We then compared the radionuclide concentrations with the disposal limits determined in the performance evaluation project for each of the fifteen sites. The results are a scoping-level estimate of the required volumetric capacity for MLLW disposal and the identification of waste streams that may pose problems for disposal based on current treatment plans. The analysis provides technical information for continued discussions between the DOE and affected States about disposal of MLLW and systematic input to waste treatment developers on disposal issues

10. Biogas conference Dresden. Anaerobic treatment of biological wastes. Proceedings

International Nuclear Information System (INIS)

Dornack, Christina; Liebetrau, Jan; Fassauer, Burkhardt; Nelles, Michael

2015-01-01

The biogas conference in Dresden will be held for the tenth time and is still the only conference in Germany, which focuses on the production of biogas solely from waste. This year, the implementation of paragraph 11 of the Recycling and Waste Management Act and the amendment of the Renewable Energies Act (EEG) in 2014, the chances of the waste management biogas technology will be spotlighted here. The efficiency and wise use of the end products of the biogas production - the biogas and fermentation residues are equally critical for the success of biogas technology as the emission reduction of biogas plants. In this context, the biogas technology will also be dependent in the future on legal requirements and funding instruments such as the EEG. For the technical implementation, the development of reliable system concepts with specific sinking biogas and electricity supply costs and with greater flexibility in terms of launching needs-based biogas and electricity production. The contributions in this paper discuss possible solutions and implementations from the perspective of politics, associations, research and practice. Innovative topics will be discussed, which will be decisive for the future of biogas production from organic wastes. [de

Waste management practices to control biological transport of radioactivity at the Hanford Site

International Nuclear Information System (INIS)

Conklin, A.W.

1985-01-01

One of the goals of waste management in the Hanford Site 200 Areas is to prevent biological intrusion into, and transport from, waste storage and disposal sites. Practices established to achieve these goals include the elimination of deep-rooted vegetation on waste sites to prevent plant root intrusion into radioactivity, selective herbicide application to prevent regrowth of these plants, planting of shallow-rooted plants to successfully compete with deep-rooted plants for moisture, surface stabilization, and environmental surveillance. Past biological transport incidents have included transport by Russian thistle by way of physiological plant processes, bird access into exposed contamination, and animals burrowing into radioactive waste disposal sites. Rockwell Hanford Operations, through mitigative actions and continued surveillance, has made significant progress in eliminating, or better isolating source terms, thus preventing or inhibiting problems from recurring. Approximately 60% of source term acreage requiring stabilization or decontamination has been completed

How to minimize wastes

International Nuclear Information System (INIS)

Ambolet, M.

1988-10-01

Actions undertaken by the CEA to decrease the stock of natural and depleted uranium are presented in this paper. Various wastes and residues are produced in uranium fabrication. If for some wastes or residues processing methods were found previously, for other storage was the rule. Facing growing problems of safety, bulkiness, and cost new treatments allow to decrease a great amount of wastes. Uranium fabrication cycle, wastes and residues are described. Processing of the different residues of operations and optimization of manufacture are indicated [fr

Effect of composition variations on the long-term wasteform behavior of vitrified domestic waste incineration fly-ash purification residues

International Nuclear Information System (INIS)

Frugier, Pierre

1999-01-01

The effect of variations in the composition of fly-ash purification residue from incinerated domestic waste on the quality of the containment achieved by vitrification was investigated. Three main factors determine the long-term containment quality: the production of a vitrified wasteform, the occurrence of possible crystallization, and the key parameters of long-term alteration in aqueous media. Each of these aspects is described within a composition range defined by variations in the three major elements. (silicon, calcium and aluminum) and two groups of constituents (alkali metals and toxic elements). The silicon fraction in the fly-ash residue was found to be decisive: it is impossible to obtain a satisfactory vitrified wasteform below a given silicon concentration. Compounds with the lowest silica content also exhibited the greatest tendency to crystallize under the cooling conditions prevailing in industrial processes (the dominant crystallized phase is a melilite that occupies a significant fraction of the material and considerably modifies the alteration mechanisms). The initial alteration rate in pure water and the altered glass thickness measured in a closed system at an advanced stage of the dissolution reaction are both inversely related to the silicon concentration in the glass. Several types of long-term behavior were identified according to the composition range, the process conditions and the vitrified waste disposal scenario. Four distinct 'classes' of vitrified wasteform were defined for direct application in industrial processes. (author) [fr

Use of fly ash, phosphogypsum and red mud as a liner material for the disposal of hazardous zinc leach residue waste.

Science.gov (United States)

Coruh, Semra; Ergun, Osman Nuri

2010-01-15

Increasing amounts of residues and waste materials coming from industrial activities in different processes have become an increasingly urgent problem for the future. The release of large quantities of heavy metals into the environment has resulted in a number of environmental problems. The present study investigated the safe disposal of the zinc leach residue waste using industrial residues such as fly ash, phosphogypsum and red mud. In the study, leachability of heavy metals from the zinc leach residue has been evaluated by mine water leaching procedure (MWLP) and toxicity characteristic leaching procedure (TCLP). Zinc removal from leachate was studied using fly ash, phosphogypsum and red mud. The adsorption capacities and adsorption efficiencies were determined. The adsorption rate data was analyzed according to the pseudo-second-order kinetic, Elovich kinetic and intra-particle diffusion kinetic models. The pseudo-second-order kinetic was the best fit kinetic model for the experimental data. The results show that addition of fly ash, phosphogypsum and red mud to the zinc leach residue drastically reduces the heavy metal content in the leachate and could be used as liner materials.

A Review of the Latest Advances in Encrypted Bioactive Peptides from Protein-Rich Waste

Directory of Open Access Journals (Sweden)

Ailton Cesar Lemes

2016-06-01

Full Text Available Bioactive peptides are considered the new generation of biologically active regulators that not only prevent the mechanism of oxidation and microbial degradation in foods but also enhanced the treatment of various diseases and disorders, thus increasing quality of life. This review article emphasizes recent advances in bioactive peptide technology, such as: (i new strategies for transforming bioactive peptides from residual waste into added-value products; (ii nanotechnology for the encapsulation, protection and release of controlled peptides; and (iii use of techniques of large-scale recovery and purification of peptides aiming at future applications to pharmaceutical and food industries.

Treatment of alpha-bearing combustible wastes using acid digestion

International Nuclear Information System (INIS)

Lerch, R.E.; Allen, C.R.; Blasewitz, A.G.

1978-01-01

Acid digestion has been developed at the Hanford Engineering Development Laboratory (HEDL) in Richland, Washington to reduce the volume of combustible nuclear waste materials, while converting them to an inert, noncombustible residue. A 100 kg/day test unit has recently been constructed to demonstrate the process using radioactively contaminated combustible wastes. The unit, called the Radioactive Acid Digestion Test Unit (RADTU) was completed in September 1977 and is currently undergoing cold shakedown tests. Hot operation is expected in May 1978. Features of RADTU include: storage and transfer station for incoming wastes, a feed preparation station, an extrusion feed mechanism for transfer of the waste to the acid digester, the acid digester a residue recovery system, and an off-gas treatment system

Treatment of alpha-bearing combustible wastes using acid digestion

International Nuclear Information System (INIS)

Lerch, R.E.; Allen, C.R.; Blasewitz, A.G.

1977-11-01

Acid digestion has been developed at the Hanford Engineering Development Laboratory (HEDL) in Richland, Washington to reduce the volume of combustible nuclear waste materials, while converting them to an inert, noncombustible residue. A 100 kg/day test unit has recently been constructed to demonstrate the process using radioactively contaminated combustible wastes. The unit, called the Radioactive Acid Digestion Test Unit (RADTU) was completed in September 1977 and is currently undergoing cold shakedown tests. Hot operation is expected in May 1978. Features of RADTU include: storage and transfer station for incoming wastes, a feed preparation station, an extrusion feed mechanism for transfer of the waste to the acid digester, the acid digester, a residue recovery system, and an off-gas treatment system

Stabilization of In-Tank Residual Wastes and External-Tank Soil Contamination for the Hanford Tank Closure Program: Applications to the AX Tank Farm

Energy Technology Data Exchange (ETDEWEB)

Anderson, H.L.; Dwyer, B.P.; Ho, C.; Krumhansl, J.L.; McKeen, G.; Molecke, M.A.; Westrich, H.R.; Zhang, P.

1998-11-01

Technical support for the Hanford Tank Closure Program focused on evaluation of concepts for immobilization of residual contaminants in the Hanford AX tanks and underlying soils, and identification of cost-effective approaches to improve long-term performance of AX tank farm cIosure systems. Project objectives are to develop materials or engineered systems that would significantly reduce the radionuclide transport to the groundwater from AX tanks containing residual waste. We pursued several studies that, if implemented, would help achieve these goals. They include: (1) tank fill design to reduce water inilltration and potential interaction with residual waste; (2) development of in-tank getter materials that would specifically sorb or sequester radionuclides; (3) evaluation of grout emplacement under and around the tanks to prevent waste leakage during waste retrieval or to minimize water infiltration beneath the tanks; (4) development of getters that will chemically fix specific radionuclides in soils under tanks; and (5) geochemical and hydrologic modeling of waste-water-soil-grout interactions. These studies differ in scope from the reducing grout tank fill employed at the Savannah River Site in that our strategy improves upon tank fill design by providing redundancy in the barriers to radionuclide migration and by modification the hydrogeochemistry external to the tanks.

Rock mechanics for hard rock nuclear waste repositories

International Nuclear Information System (INIS)

Heuze, F.E.

1981-09-01

The mined geologic burial of high level nuclear waste is now the favored option for disposal. The US National Waste Terminal Storage Program designed to achieve this disposal includes an extensive rock mechanics component related to the design of the wastes repositories. The plan currently considers five candidate rock types. This paper deals with the three hard rocks among them: basalt, granite, and tuff. Their behavior is governed by geological discontinuities. Salt and shale, which exhibit behavior closer to that of a continuum, are not considered here. This paper discusses both the generic rock mechanics R and D, which are required for repository design, as well as examples of projects related to hard rock waste storage. The examples include programs in basalt (Hanford/Washington), in granitic rocks (Climax/Nevada Test Site, Idaho Springs/Colorado, Pinawa/Canada, Oracle/Arizona, and Stripa/Sweden), and in tuff

PERMANENCE OF BIOLOGICAL AND CHEMICAL WARFARE AGENTS IN MUNICIPAL SOLID WASTE LANDFILL LEACHATES

Science.gov (United States)

The objective of this work is to permit EPA/ORD's National Homeland Security Research Center (NHSRC) and Edgewood Chemical Biological Center to collaborate together to test the permanence of biological and chemical warfare agents in municipal solid waste landfills. Research into ...

Wood wastes and residues generated along the Colorado Front Range as a potential fuel source

Science.gov (United States)

Julie E. Ward; Kurt H. Mackes; Dennis L. Lynch

2004-01-01

Throughout the United States there is interest in utilizing renewable fuel sources as an alternative to coal and nat-ural gas. This project was initiated to determine the availability of wood wastes and residues for use as fuel in ce-ment kilns and power plants located along the Colorado Front Range. Research was conducted through literature searches, phone surveys,...

Remaining Sites Verification Package for the 100-F-52, 146-FR Radioecology and Aquatic Biology Laboratory Soil. Attachment to Waste Site Reclassification Form 2008-022

International Nuclear Information System (INIS)

Capron, J.M.

2008-01-01

The 100-F-52 waste site consisted of the soil under and around the former 146-FR Radioecology and Aquatic Biology Laboratory. The laboratory was used for studies of the effects of pre-reactor and post-reactor process water on fish eggs, young fish, and other small river creatures of interest. In accordance with this evaluation, the confirmatory sampling results support a reclassification of this site to No Action. The current site conditions achieve the remedial action objectives and the corresponding remedial action goals established in the Remaining Sites ROD. The results of confirmatory sampling show that residual contaminant concentrations do not preclude any future uses and allow for unrestricted use of shallow zone soils. The results also demonstrate that residual contaminant concentrations are protective of groundwater and the Columbia River

Biological Applications of Hybrid Quantum Mechanics/Molecular Mechanics Calculation

Directory of Open Access Journals (Sweden)

Jiyoung Kang

2012-01-01

Full Text Available Since in most cases biological macromolecular systems including solvent water molecules are remarkably large, the computational costs of performing ab initio calculations for the entire structures are prohibitive. Accordingly, QM calculations that are jointed with MM calculations are crucial to evaluate the long-range electrostatic interactions, which significantly affect the electronic structures of biological macromolecules. A UNIX-shell-based interface program connecting the quantum mechanics (QMs and molecular mechanics (MMs calculation engines, GAMESS and AMBER, was developed in our lab. The system was applied to a metalloenzyme, azurin, and PU.1-DNA complex; thereby, the significance of the environmental effects on the electronic structures of the site of interest was elucidated. Subsequently, hybrid QM/MM molecular dynamics (MD simulation using the calculation system was employed for investigation of mechanisms of hydrolysis (editing reaction in leucyl-tRNA synthetase complexed with the misaminoacylated tRNALeu, and a novel mechanism of the enzymatic reaction was revealed. Thus, our interface program can play a critical role as a powerful tool for state-of-the-art sophisticated hybrid ab initio QM/MM MD simulations of large systems, such as biological macromolecules.

Bioconversion of chicken wastes to value-added products

Energy Technology Data Exchange (ETDEWEB)

Barik, S; Forgacs, T; Isbister, J [ARCTECH, Inc., Alexandria, VA (United States)

1991-01-01

Increasing quantities of chicken waste concerns the poultry industry because of escalating disposal costs and the potential for environmental pollution. Biological conversion of these wastes to valuable products such as methane and/or chemical feed-stocks appears to be feasible. Biomethanation of chicken waste by a sewage sludge microbial consortium produced as much as 69 mol% methane in the gas phase. Acetic and propionic acids were the major acids produced during the bioconversion. Addition of chelating agents and other micro-nutrients enhanced methane production and shifted the ratios of intermediates accumulated. Preliminary data indicate that more than 60% of the chicken waste carbon was converted and that the nitrogen-rich residue may have potential as a soil additive. (author).

Biological treatment of industrial wastes; Tratamiento biologico de residuos industriales

Energy Technology Data Exchange (ETDEWEB)

Ortiz de Zarate Apodaca, J.M.; Abia Aguila, L

1997-04-01

There are organic elements used in industrial processes which are not able to be recovered. The biological treatment is the alternative for eliminating the organic pollutants from industrial waste water. This technology is being widely accepted because of its low environmental impact. (Author)

Mechanisms governing the direct removal of wastes from the Waste Isolation Pilot Plant repository caused by exploratory drilling

International Nuclear Information System (INIS)

Berglund, J.W.

1992-12-01

Two processes are identified that can influence the quantity of wastes brought to the ground surface when a waste disposal room of the Waste Isolation Pilot Plant is inadvertently penetrated by an exploratory borehole. The first mechanism is due to the erosion of the borehole wall adjacent to the waste caused by the flowing drilling fluid (mud); a quantitative computational model based upon the flow characteristics of the drilling fluid (laminar or turbulent) and other drilling parameters is developed and example results shown. The second mechanism concerns the motion of the waste and borehole spall caused by the flow of waste-generated gas to the borehole. Some of the available literature concerning this process is discussed, and a number of elastic and elastic-plastic finite-difference and finite-element calculations are described that confirm the potential importance of this process in directly removing wastes from the repository to the ground surface. Based upon the amount of analysis performed to date, it is concluded that it is not unreasonable to expect that volumes of waste several times greater than that resulting from direct cutting of a gauge borehole could eventually reach the ground surface. No definitive quantitative model for waste removal as a result of the second mechanism is presented; it is concluded that decomposed waste constitutive data must be developed and additional experiments performed to assess further the full significance of this latter mechanism

Physical and Mechanical Characterization of Artificial Stone with Marble Calcite Waste and Epoxy Resin

OpenAIRE

Silva, Fernanda Souza; Ribeiro, Carlos Eduardo Gomes; Rodriguez, Rubén Jesus Sánchez

2017-01-01

The incorporation of calcite marble waste in epoxy resin for the production of artificial stone can represent a technical-economical method and environmentally viable, reducing the amount of discarded residue in the environment, and adding economic value to marble waste and enabling the generation of jobs. The production of natural stone in Brazil recorded an exorbitant amount of waste generated in marble processing. Only 75% of marble taken from the deposits it becomes the finished product t...

Kinetic study on ferulic acid production from banana stem waste via mechanical extraction

Science.gov (United States)

Zainol, Norazwina; Masngut, Nasratun; Khairi Jusup, Muhamad

2018-04-01

Banana is the tropical plants associated with lots of medicinal properties. It has been reported to be a potential source of phenolic compounds such as ferulic acid (FA). FA has excellent antioxidant properties higher than vitamin C and E. FA also have a wide range of biological activities, such as antioxidant activities and anti-microbial activities. This paper presents an experimental and kinetic study on ferulic acid (FA) production from banana stem waste (BSW) via mechanical extraction. The objective of this research is to determine the kinetic parameters in the ferulic acid production. The banana stem waste was randomly collected from the local banana plantation in Felda Lepar Hilir, Pahang. The banana stem juice was mechanically extracted by using sugarcane press machine (KR3176) and further analyzed in high performance liquid chromatography. The differential and integral method was applied to determine the kinetic parameter of the extraction process and the data obtained were fitted into the 0th, 1st and 2nd order of extraction process. Based on the results, the kinetic parameter and R2 value from were 0.05 and 0.93, respectively. It was determined that the 0th kinetic order fitted the reaction processes to best represent the mechanical extraction.

Environmental impacts of residual Municipal Solid Waste incineration: A comparison of 110 French incinerators using a life cycle approach

Energy Technology Data Exchange (ETDEWEB)

Beylot, Antoine, E-mail: a.beylot@brgm.fr; Villeneuve, Jacques

2013-12-15

Highlights: • 110 French incinerators are compared with LCA based on plant-specific data. • Environmental impacts vary as a function of plants energy recovery and NO{sub x} emissions. • E.g. climate change impact ranges from −58 to 408 kg CO{sub 2}-eq/tonne of residual MSW. • Implications for LCA of waste management in a decision-making process are detailed. - Abstract: Incineration is the main option for residual Municipal Solid Waste treatment in France. This study compares the environmental performances of 110 French incinerators (i.e. 85% of the total number of plants currently in activity in France) in a Life Cycle Assessment perspective, considering 5 non-toxic impact categories: climate change, photochemical oxidant formation, particulate matter formation, terrestrial acidification and marine eutrophication. Mean, median and lower/upper impact potentials are determined considering the incineration of 1 tonne of French residual Municipal Solid Waste. The results highlight the relatively large variability of the impact potentials as a function of the plant technical performances. In particular, the climate change impact potential of the incineration of 1 tonne of waste ranges from a benefit of −58 kg CO{sub 2}-eq to a relatively large burden of 408 kg CO{sub 2}-eq, with 294 kg CO{sub 2}-eq as the average impact. Two main plant-specific parameters drive the impact potentials regarding the 5 non-toxic impact categories under study: the energy recovery and delivery rate and the NO{sub x} process-specific emissions. The variability of the impact potentials as a function of incinerator characteristics therefore calls for the use of site-specific data when required by the LCA goal and scope definition phase, in particular when the study focuses on a specific incinerator or on a local waste management plan, and when these data are available.

Environmental impacts of residual Municipal Solid Waste incineration: A comparison of 110 French incinerators using a life cycle approach

International Nuclear Information System (INIS)

Beylot, Antoine; Villeneuve, Jacques

2013-01-01

Highlights: • 110 French incinerators are compared with LCA based on plant-specific data. • Environmental impacts vary as a function of plants energy recovery and NO x emissions. • E.g. climate change impact ranges from −58 to 408 kg CO 2 -eq/tonne of residual MSW. • Implications for LCA of waste management in a decision-making process are detailed. - Abstract: Incineration is the main option for residual Municipal Solid Waste treatment in France. This study compares the environmental performances of 110 French incinerators (i.e. 85% of the total number of plants currently in activity in France) in a Life Cycle Assessment perspective, considering 5 non-toxic impact categories: climate change, photochemical oxidant formation, particulate matter formation, terrestrial acidification and marine eutrophication. Mean, median and lower/upper impact potentials are determined considering the incineration of 1 tonne of French residual Municipal Solid Waste. The results highlight the relatively large variability of the impact potentials as a function of the plant technical performances. In particular, the climate change impact potential of the incineration of 1 tonne of waste ranges from a benefit of −58 kg CO 2 -eq to a relatively large burden of 408 kg CO 2 -eq, with 294 kg CO 2 -eq as the average impact. Two main plant-specific parameters drive the impact potentials regarding the 5 non-toxic impact categories under study: the energy recovery and delivery rate and the NO x process-specific emissions. The variability of the impact potentials as a function of incinerator characteristics therefore calls for the use of site-specific data when required by the LCA goal and scope definition phase, in particular when the study focuses on a specific incinerator or on a local waste management plan, and when these data are available

Properties of sintered glass-ceramics prepared from plasma vitrified air pollution control residues

Energy Technology Data Exchange (ETDEWEB)

Roether, J.A.; Daniel, D.J. [Department of Materials, Imperial College London, London SW7 2AZ (United Kingdom); Amutha Rani, D. [Department of Materials, Imperial College London, London SW7 2AZ (United Kingdom); Department of Civil and Environmental Engineering, Imperial College London, London SW7 2AZ (United Kingdom); Deegan, D.E. [Tetronics Ltd., Swindon, Wiltshire SN3 4DE (United Kingdom); Cheeseman, C.R., E-mail: c.cheeseman@imperial.ac.uk [Department of Civil and Environmental Engineering, Imperial College London, London SW7 2AZ (United Kingdom); Boccaccini, A.R., E-mail: a.boccaccini@imperial.ac.uk [Department of Materials, Imperial College London, London SW7 2AZ (United Kingdom)

2010-01-15

Air pollution control (APC) residues, obtained from a major UK energy from waste (EfW) plant, processing municipal solid waste, have been blended with silica and alumina and melted using DC plasma arc technology. The glass produced was crushed, milled, uni-axially pressed and sintered at temperatures between 750 and 1150 deg. C, and the glass-ceramics formed were investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Mechanical properties assessed included Vickers's hardness, flexural strength, Young's modulus and thermal shock resistance. The optimum sintering temperature was found to be 950 deg. C. This produced a glass-ceramic with high density ({approx}2.58 g/cm{sup 3}), minimum water absorption ({approx}2%) and relatively high mechanical strength ({approx}81 {+-} 4 MPa). Thermal shock testing showed that 950 deg. C sintered samples could withstand a 700 deg. C quench in water without micro-cracking. The research demonstrates that glass-ceramics can be readily formed from DC plasma treated APC residues and that these have comparable properties to marble and porcelain. This novel approach represents a technically and commercially viable treatment option for APC residues that allow the beneficial reuse of this problematic waste.

Realisation of politically desired projects on the basis of an insufficient development. A consequence of the acceptance discussion on wase incineration; Realisierung politisch erwuenschter Projekte auf Basis unzureichender Entwicklung. Eine Konsequenz der Akzeptanzdiskussion um die Abfallverbrennung

Energy Technology Data Exchange (ETDEWEB)

Thome-Kozmiensky, Karl J. [vivis Consult GmbH, Nietwerder (Germany)

2008-07-01

Despite all efforts toward waste avoidance, re-use and material utilization residual wastes remains. These residual wastes have to be treated before the deposition. This regularly is accomplished thermally after a mechanical or biological pretreatment. In Germany, the present refuse disposal exhibits an optimization potential. The well-known procedures for the refuse disposal exhibit lacks regarding its technical performance and environmental compatibility. A further development of these procedures was required. Under this aspect, the author of the contribution under consideration describes the procedures for the treatment of residual wastes, and evaluates these procedures critically.

Evaluation of solid residues removed from a mangrove swamp in the São Vicente Estuary, SP, Brazil.

Science.gov (United States)

Cordeiro, C A M M; Costa, T M

2010-10-01

Mangrove swamps are found in estuaries along the coastal plains of tropical regions and have be subjected to heavy occupation and use pressure due to their privileged locations and abundance of biological resources. The present work evaluated the ecological characteristics and solid wastes accumulated in eight areas along the Santos - São Vicente Estuary Complex. The superficially deposited residues at each sampling site were collected and subsequently washed, drained, counted, weighed and separated into classes according to their composition and predominant use. The predominant litter type in terms of density was plastic (62.81%) and, by weight, wood (55.53%). The greatest deposition of residues was associated with areas that were less inclined and that had low plant density levels, indicating that the presence of obstacles was not critical for retaining floating residues in mangrove areas. The presence of the most frequently encountered types of solid waste residues could be explained by local activities. Copyright © 2010 Elsevier Ltd. All rights reserved.

Remaining Sites Verification Package for the 100-F-36, 108-F Biological Laboratory, and for the 116-F-15, 108-F Radiation Crib. Attachment to Waste Site Reclassification Form 2007-002

International Nuclear Information System (INIS)

Dittmer, L.M.

2007-01-01

The 100-F-36 waste site is the location of the former 108-F Biological Laboratory. The building was closed in 1973, decontaminated, decommissioned, and eventually demolished in 1999. In accordance with this evaluation, the confirmatory sampling results support a reclassification of this site to No Action. The current site conditions achieve the remedial action objectives and the corresponding remedial action goals established in the Remaining Sites ROD. The results of confirmatory sampling show that residual contaminant concentrations do not preclude any future uses and allow for unrestricted use of shallow zone soils. The results also demonstrate that residual contaminant concentrations are protective of groundwater and the Columbia River

Conversion of agricultural waste, sludges and pulp residues into nanofibers for innovative polymer composites

OpenAIRE

Samyn, Pieter; Carleer, Robert

2017-01-01

Agricultural waste fractions from seasonal crops (corn stover, bagasse, flax), sludges and paper pulp residues contain an important source of lignocellulosic materials that can be recovered and used as material fractions instead of being burnt for energy recovery. Due to the heterogeneity of named products, however, novel processing routes should be developed for the recovery of the lignocellulosic materials at nanoscale. Therefore, we will use nanotechnological routes to transform the res...

Influences of mechanical pretreatment on the non-biological treatment of municipal wastewater by forward osmosis.

Science.gov (United States)

Hey, Tobias; Zarebska, Agata; Bajraktari, Niada; Vogel, Jörg; Hélix-Nielsen, Claus; la Cour Jansen, Jes; Jönsson, Karin

2017-09-01

Municipal wastewater treatment involves mechanical, biological and chemical treatment steps for protecting the environment from adverse effects. The biological treatment step consumes the most energy and can create greenhouse gases. This study investigates municipal wastewater treatment without the biological treatment step, including the effects of different pretreatment configurations, for example, direct membrane filtration before forward osmosis. Forward osmosis was tested using raw wastewater and wastewater subjected to different types of mechanical pretreatment, for example, microsieving and microfiltration permeation, as a potential technology for municipal wastewater treatment. Forward osmosis was performed using Aquaporin Inside™ and Hydration Technologies Inc. (HTI) membranes with NaCl as the draw solution. Both types of forward osmosis membranes were tested in parallel for the different types of pretreated feed and evaluated in terms of water flux and solute rejection, that is, biochemical oxygen demand (BOD 7 ) and total and soluble phosphorus contents. The Aquaporin and HTI membranes achieved a stable water flux with rejection rates of more than 96% for BOD 7 and total and soluble phosphorus, regardless of the type of mechanical pretreated wastewater considered. This result indicates that forward osmosis membranes can tolerate exposure to municipal waste water and that the permeate can fulfil the Swedish discharge limits.

Analysis of residual stress relief mechanisms in post-weld heat treatment

International Nuclear Information System (INIS)

Dong, Pingsha; Song, Shaopin; Zhang, Jinmiao

2014-01-01

This paper presents a recent study on weld residual stress relief mechanisms associated with furnace-based uniform post-weld heat treatment (PWHT). Both finite element and analytical methods are used to quantitatively examine how plastic deformation and creep relaxation contribute to residual stress relief process at different stages of PWHT process. The key contribution of this work to an improved understanding of furnace based uniform PWHT can be summarized as follows: (1)Plastic deformation induced stress relief during PWHT can be analytically expressed by the change in material elastic deformation capacity (or elastic deformation limit) measured in terms of material yield strength to Young's modulus ratio, which has a rather limited role in overall residual stress relief during furnace based uniform PWHT. (2)The most dominant stress relief mechanism is creep strain induced stress relaxation, as expected. However, a rapid creep strain development accompanied by a rapid residual stress reduction during heating stage before reaching PWHT temperature is shown to contribute to most of the stress relief seen in overall PWHT process, suggesting PWHT hold time can be significantly reduced as far as residual stress relief is concerned. (3)A simple engineering scheme for estimating residual stress reduction is proposed based on this study by relating material type, PWHT temperature, and component wall thickness. - Highlights: • The paper clarified effects of plastic deformation and creep relaxation on weld residual stress relief during uniform PWHT. • Creep strain development is far more important than plastic strain, mostly completed even before hold time starts. • Plastic strain development is insignificant and be analytically described by a material elastic deformation capacity parameter. • An engineering estimation scheme is proposed for determining residual stress reduction resulted from furnace based PWHT

Nuclear waste glass corrosion mechanisms

International Nuclear Information System (INIS)

Jantzen, C.M.

1987-04-01

Dissolution of nuclear waste glass occurs by corrosion mechanisms similar to those of other solids, e.g., metallurgical and mineralogic systems. Metallurgical phenomena such as active corrosion, passivation and immunity have been observed to be a function of the glass composition and the solution pH. Hydration thermodynamics was used to quantify the role of glass composition and its effect on the solution pH during dissolution. A wide compositional range of natural, lunar, medieval, and nuclear waste glasses, as well as some glass-ceramics were investigated. The factors observed to affect dissolution in deionized water are pertinent to the dissolution of glass in natural environments such as the groundwaters anticipated to interact with nuclear waste glass in a geologic repository. The effects of imposed pH and oxidation potential (Eh) conditions existing in natural environments on glass dissolution is described in the context of Pourbaix diagrams, pH potential diagrams, for glass

Life-cycle assessment of selected management options for air pollution control residues from waste incineration.

Science.gov (United States)

Fruergaard, Thilde; Hyks, Jiri; Astrup, Thomas

2010-09-15

Based on available technology and emission data seven selected management options for air-pollution-control (APC) residues from waste incineration were evaluated by life-cycle assessment (LCA) using the EASEWASTE model. Scenarios were evaluated with respect to both non-toxicity impact categories (e.g. global warming) and toxicity related impact categories (e.g. ecotoxicity and human toxicity). The assessment addressed treatment and final placement of 1 tonne of APC residue in seven scenarios: 1) direct landfilling without treatment (baseline), 2) backfilling in salt mines, 3) neutralization of waste acid, 4) filler material in asphalt, 5) Ferrox stabilization, 6) vitrification, and 7) melting with automobile shredder residues (ASR). The management scenarios were selected as examples of the wide range of different technologies available worldwide while at the same time using realistic technology data. Results from the LCA were discussed with respect to importance of: energy consumption/substitution, material substitution, leaching, air emissions, time horizon aspects for the assessment, and transportation distances. The LCA modeling showed that thermal processes were associated with the highest loads in the non-toxicity categories (energy consumption), while differences between the remaining alternatives were small and generally considered insignificant. In the toxicity categories, all treatment/utilization options were significantly better than direct landfilling without treatment (lower leaching), although the thermal processes had somewhat higher impacts than the others options (air emissions). Transportation distances did not affect the overall ranking of the management alternatives. Copyright 2010 Elsevier B.V. All rights reserved.

Studies of some physical-mechanical and chemical property in organic waste to use for biogas production in Cuba

International Nuclear Information System (INIS)

Martinez Hernández, Carlos M.; Oechsner, Hans; Brulé, Mathieu; Marañon Maison, Elena

2014-01-01

The work approaches the study of some physical-mechanical and chemical properties of agricultural organic residuals which can be used in the biogas production in Cuba´s plants production, using their co-fermentation. It has also been necessary to collect agricultural biomass, canteen waste, influent and effluents of a biogas plant Nina Bonita) next to Santa Clara city, Cuba, for their later analysis. the investigated biomass samples (sorghum.49V-96, sorghum-132 R, sunflower JE-94, cassava, corn, sweet potato skin, bread, potatoes and peanut skin); as well as the influent and effluents of the investigated biogas plant were analyzed in some laboratories belonging to the Central University of Las Villas. Other analyses were done in the biogas lab at Hohenheim University. The maximum value of specifies methane yield achieved was with the sunflower JE-94 (0.393 m3/kg VS), while the minimum value was reached with the peanut shell (0.095 m3/Kg VS).The main objective of the work consists on determining some of the physical-mechanical and chemical properties like carbon nitrogen ratio (C/N), specific methane production (m3/kg VS), total solid (TS), organic total solid (oTS), alkalinity (pH) and volatile solid (VS) in agricultural organic residuals and canteen waste, which can be used for the production of biogas under co-fermentation with animal manure under Cuban conditions. In order to do this, we developed some experiments to syringes, small and real scale. (author)

Biofiltration of composting gases using different municipal solid waste-pruning residue composts: monitoring by using an electronic nose.

Science.gov (United States)

López, R; Cabeza, I O; Giráldez, I; Díaz, M J

2011-09-01

The concentration of volatile organic compounds (VOCs) during the composting of kitchen waste and pruning residues, and the abatement of VOCs by different compost biofilters was studied. VOCs removal efficiencies greater than 90% were obtained using composts of municipal solid waste (MSW) or MSW-pruning residue as biofilter material. An electronic nose identified qualitative differences among the biofilter output gases at very low concentrations of VOCs. These differences were related to compost constituents, compost particle size (2-7 or 7-20mm), and a combination of both factors. The total concentration of VOCs determined by a photoionization analyser and inferred from electronic nose data sets were correlated over an ample range of concentrations of VOCs, showing that these techniques could be specially adapted for the monitoring of these processes. Copyright © 2011 Elsevier Ltd. All rights reserved.

Influence of mechanical-biological waste pre-treatment methods on the gas formation in landfills

International Nuclear Information System (INIS)

Bockreis, A.; Steinberg, I.

2005-01-01

In order to minimise emissions and environmental impacts, only pre-treated waste should be disposed of. For the last six years, a series of continuous experiments has been conducted at the Institute WAR, TU Darmstadt, in order to determine the emissions from pre-treated waste. Different kinds of pre-treated waste were incubated in several reactors and various data, including production and composition of the gas and the leachate, were collected. In this paper, the interim results of gas production and the gas composition from different types of waste after a running time of six years are presented and discussed

Research experiences on the reuse of industrial waste for concrete production

Directory of Open Access Journals (Sweden)

Abbà Alessandro

2017-01-01

Full Text Available The aim of this study was to assess the feasibility of concrete production using different kinds of industrial wastes as “recycled aggregate”. The wastes studied in this work were: fly ashes and slags from Electric Arc Furnace (EAF steel plant; foundry sands produced from foundry dies; slags from lead processing; Waelz slags; solid residues from municipal solid waste incineration (MSWI plant (with mass-burning kiln and fluidized bed reactor; sludge from industrial wastewater treatment plants. Good compressive strength (similar to natural concrete was achieved after 28 days of curing by concrete mixtures obtained with the partial replacement (from 7% to 40% by weight of natural aggregates with slags from lead processing, foundry sands, Waelz slags and bottom ashes from MSW incineration. The worst mechanical and leaching behaviours were shown by concrete samples containing EAF fly ashes and sludge from industrial wastewater treatment. For the residues with the best performance, concrete products (kerbs and flat tiles were casted. Their mechanical and leaching characterization has shown that the reuse of these residues for concrete product is feasible.

Chinese medicinal herbal residues as a bulking agent for food waste composting.

Science.gov (United States)

Zhou, Ying; Selvam, Ammaiyappan; Wong, Jonathan W C

2018-02-01

This study aimed to co-compost Chinese medicinal herbal residues (CMHRs) as the bulking agent with food waste (FW) to develop a high value antipathogenic compost. The FW, sawdust (SD) and CMHRs were mixed at three different mixing ratios, 5:5:1, 2:2:1 and 1:1:1 on dry weight basis. Lime at 2.25% was added to the composting mix to buffer the pH during the composting. A control without lime addition was also included. The mixtures were composted in 20-L in-vessel composters for 56 days. A maximum of 67.2% organic decomposition was achieved with 1:1:1 mixing ratio within 8 weeks. The seed germination index was 157.2% in 1:1:1 mixing ratio, while other ratios showed compost food waste at the dry weight ratio of 1:1:1 (FW: SD: CMHRs) was recommended for FW-CMHRs composting. Copyright © 2017 Elsevier Ltd. All rights reserved.

Waste Treatment of Chrome Residue of Chromium Recovery Process Using Calcium Carbonate

International Nuclear Information System (INIS)

Endro Kismolo; Prayitno; Nurimaniwathy

2002-01-01

The aim of the research was to apply the precipitation technology for the treatment of aqueous wastes of leather tanning industries. The chrome liquid wastes taken was the effluent from the residue of the chromium recovery process using magnesium oxide. The precipitant used was calcium carbonate. The experiments was performed by adjusting the concentration of calcium carbonate from 50 ppm, 100 ppm, 150 ppm, 200 ppm, 250 ppm, 300 ppm, 350 ppm to 400 ppm. The stirring speed was varied from 50 rpm, 75 rpm, 100 rpm, 125 rpm, 150 rpm, 175 rpm to 200 rpm. The time of mixing was varied from 30 minutes, 60 minutes, 90 minutes, 120 minutes, 150 minutes, 175 minutes and 200 minutes. The result from the experiments lead to the best condition obtained were the concentration of precipitant was 300 ppm, flow rates of mixing was 125 rpm and time of mixing was 60 minutes. At this condition the separations efficiency of chrome obtained was 99.985%. (author)

Quantum-mechanical analysis of amino acid residues function in the proton transport during F0F1-ATP synthase catalytic cycle

Science.gov (United States)

Ivontsin, L. A.; Mashkovtseva, E. V.; Nartsissov, Ya R.

2017-11-01

Implications of quantum-mechanical approach to the description of proton transport in biological systems are a tempting subject for an overlapping of fundamental physics and biology. The model of proton transport through the integrated membrane enzyme FoF1-ATP synthase responsible for ATP synthesis was developed. The estimation of the mathematical expectation of the proton transfer time through the half-channel was performed. Observed set of proton pathways through the inlet half-channel showed the nanosecond timescale highly dependable of some amino acid residues. There were proposed two types of crucial amino acids: critically localized (His245) and being a part of energy conserving system (Asp119).

Case study of an MBT plant producing SRF for cement kiln co-combustion, coupled with a bioreactor landfill for process residues.

Science.gov (United States)

Grosso, Mario; Dellavedova, Stefano; Rigamonti, Lucia; Scotti, Sergio

2016-01-01

The paper describes the performances of the energy recovery pathway from the residual waste based on the production of a Solid Recovered Fuel (SRF) to be exploited via co-combustion in a cement kiln. The SRF is produced in a single stream Mechanical-Biological Treatment plant, where bio-drying of the waste is followed by mechanical refining in order to fulfil the quality requirements by the cement kilns. Peculiar of this MBT is the fact that sorting residues are disposed in a nearby landfill, managed according to a bioreactor approach, where landfill gas is collected for electric energy recovery. A detailed mass and energy balance of the system is presented based on one year operational data, followed by its Life Cycle Assessment. Results show that the system is energetically and environmentally effective, with most of the impacts being more than compensated by the savings of materials and energy. Major role in determining such outcome is the displacement of petcoke in the cement kiln, both in terms of its fossil CO2 emissions and of its life cycle impacts, including the trans-oceanic transport. To check the robustness of the results, two sensitivity analyses are performed on the landfill gas collection efficiency and on the avoided electric energy mix. Copyright © 2015 Elsevier Ltd. All rights reserved.

Proposal for management and alkalinity transformation of bauxite residue in China.

Science.gov (United States)

Xue, Shengguo; Kong, Xiangfeng; Zhu, Feng; Hartley, William; Li, Xiaofei; Li, Yiwei

2016-07-01

Bauxite residue is a hazardous solid waste produced during the production of alumina. Its high alkalinity is a potential threat to the environment which may disrupt the surrounding ecological balance of its disposal areas. China is one of the major global producers of alumina and bauxite residue, but differences in alkalinity and associated chemistry exist between residues from China and those from other countries. A detailed understanding of the chemistry of bauxite residue remains the key to improving its management, both in terms of minimizing environmental impacts and reducing its alkaline properties. The nature of bauxite residue and the chemistry required for its transformation are still poorly understood. This review focuses on various transformation processes generated from the Bayer process, sintering process, and combined Bayer-sintering process in China. Problems associated with transformation mechanisms, technical methods, and relative merits of these technologies are reviewed, while current knowledge gaps and research priorities are recommended. Future research should focus on transformation chemistry and its associated mechanisms and for the development of a clear and economic process to reduce alkalinity and soda in bauxite residue.

Anaerobic Digestion of Laminaria japonica Waste from Industrial Production Residues in Laboratory- and Pilot-Scale.

Science.gov (United States)

Barbot, Yann Nicolas; Thomsen, Claudia; Thomsen, Laurenz; Benz, Roland

2015-09-18

The cultivation of macroalgae to supply the biofuel, pharmaceutical or food industries generates a considerable amount of organic residue, which represents a potential substrate for biomethanation. Its use optimizes the total resource exploitation by the simultaneous disposal of waste biomaterials. In this study, we explored the biochemical methane potential (BMP) and biomethane recovery of industrial Laminaria japonica waste (LJW) in batch, continuous laboratory and pilot-scale trials. Thermo-acidic pretreatment with industry-grade HCl or industrial flue gas condensate (FGC), as well as a co-digestion approach with maize silage (MS) did not improve the biomethane recovery. BMPs between 172 mL and 214 mL g(-1) volatile solids (VS) were recorded. We proved the feasibility of long-term continuous anaerobic digestion with LJW as sole feedstock showing a steady biomethane production rate of 173 mL g(-1) VS. The quality of fermentation residue was sufficient to serve as biofertilizer, with enriched amounts of potassium, sulfur and iron. We further demonstrated the upscaling feasibility of the process in a pilot-scale system where a CH₄ recovery of 189 L kg(-1) VS was achieved and a biogas composition of 55% CH₄ and 38% CO₂ was recorded.

Biology and Mechanics of Blood Flows Part I: Biology

CERN Document Server

Thiriet, Marc

2008-01-01

Biology and Mechanics of Blood Flows presents the basic knowledge and state-of-the-art techniques necessary to carry out investigations of the cardiovascular system using modeling and simulation. Part I of this two-volume sequence, Biology, addresses the nanoscopic and microscopic scales. The nanoscale corresponds to the scale of biochemical reaction cascades involved in cell adaptation to mechanical stresses among other stimuli. The microscale is the scale of stress-induced tissue remodeling associated with acute or chronic loadings. The cardiovascular system, like any physiological system, has a complicated three-dimensional structure and composition. Its time dependent behavior is regulated, and this complex system has many components. In this authoritative work, the author provides a survey of relevant cell components and processes, with detailed coverage of the electrical and mechanical behaviors of vascular cells, tissues, and organs. Because the behaviors of vascular cells and tissues are tightly coupl...

Waste management, waste resource facilities and waste conversion processes

International Nuclear Information System (INIS)

Demirbas, Ayhan

2011-01-01

In this study, waste management concept, waste management system, biomass and bio-waste resources, waste classification, and waste management methods have been reviewed. Waste management is the collection, transport, processing, recycling or disposal, and monitoring of waste materials. A typical waste management system comprises collection, transportation, pre-treatment, processing, and final abatement of residues. The waste management system consists of the whole set of activities related to handling, treating, disposing or recycling the waste materials. General classification of wastes is difficult. Some of the most common sources of wastes are as follows: domestic wastes, commercial wastes, ashes, animal wastes, biomedical wastes, construction wastes, industrial solid wastes, sewer, biodegradable wastes, non-biodegradable wastes, and hazardous wastes.

Disposal of residue from uranium ore processing in France

International Nuclear Information System (INIS)

Crochon, Ph.

2011-01-01

Between 1949 and 2001, French mines produced 76, 000 metric tons of uranium and 50 million metric tons of ore, processing residues are stored at 17 sites (in ponds enclosed by dykes or in former open-cast mines) subject to ICPE (classified facility for environment protection) regulation. These disposal sites cover surface areas of between one and several tens of hectares and several thousands to several millions of metric tons of waste are stored at them. When uranium mining stopped in France, these sites were redeveloped, with caps placed over the residue to provide mechanical and radiological protection. All these sites are still monitored by AREVA. In the last fifteen years, these sites have been the subject of a number of studies, especially regarding the long-term evolution and impact of the residue. These studies are now being pursued within the framework of the national plan for the management of nuclear materials and waste (PNGMDR). A regulatory and institutional framework regarding long-term management of these disposal sites needs to be defined. (author)

Electrodialytic upgrading of MSWI APC residue from hazardous waste to secondary resource

DEFF Research Database (Denmark)

Jensen, Pernille Erland; Kirkelund, Gunvor Marie; Parés Viader, Raimon

.g. for substitution of cement or fillers in concrete. In general leaching could not be reduced by optimizing current density and treatment time in the pilot scale stack treatment unit, as hypothesized, even though there was evidence of dependency on current density for e.g. zinc, this was not true for most elements......The aim of this project was to contribute to the development of electrodialytic treatment technology of air pollution control residues (APC) from municipal solid waste incineration (MSWI) to obtain maximal leaching reduction by optimization of treatment time and current density for different types...

Initial Effects of Differently Treated Biogas Residues from Municipal and Industrial Wastes on Spring Barley Yield Formation

Science.gov (United States)

Prays, Nadia; Kaupenjohann, Martin

2016-01-01

Soil application of biogas residues (BGRs) is important for closing nutrient cycles. This study examined the efficiency and impact on yields and yield formation of solid-liquid separated residues from biodegradable municipal and industrial wastes (bio-waste) in comparison to complete BGRs, nitrification inhibitor, agricultural BGRs, mineral fertilizer and unfertilized plots as control. The experiment was set up as a randomized block design on silt loam Cambisol. Biogas residues from four biogas plants were evaluated. Plants per m², ears per plant, grains per ear and thousand grain weight (TGW) were measured at harvest. Fertilization with BGRs resulted in similar biomass yields compared with mineral fertilizer. Mineral fertilizer (71 dt/ha) and plots fertilized with liquid fraction (59–62 dt/ha) indicated a trend to higher yields than solid fraction or complete BGR due to its high ammonia content. Liquid fractions and fraction with nitrification inhibitor induced fewer plants per m² than corresponding solid and complete variants due to a potential phytotoxicity of high NH4-N concentration during germination. However, barley on plots fertilized with liquid fraction compensated the disadvantages at the beginning during the vegetation period and induced higher grain yields than solid fraction. This was attributable to a higher number of ears per plant and grains per ear. In conclusion, BGRs from biodegradable municipal and industrial wastes can be used for soil fertilization and replace considerable amounts of mineral fertilizer. Our study showed that direct application of the liquid fraction of BGR is the most suitable strategy to achieve highest grain yields. Nevertheless potential phytotoxicity of the high NH4-N concentration in the liquid fraction should be considered. PMID:27116355

kinematic design of lift-tipping mechanism for small solid waste ...

African Journals Online (AJOL)

User

ABSTRACT. A number of small waste collection trucks such as tricycles are in use in a number of developing countries. The use of such technology has been popular in a country like Ghana. This paper presents a design of lift-tipping mechanism for small solid waste collection trucks. A five bar mechanism is developed with ...

Prediction of retained residual stresses in laboratory fracture mechanics specimens extracted from welded components

International Nuclear Information System (INIS)

Hurlston, R.G.; Sherry, A.H.; James, P.; Sharples, J.K.

2015-01-01

The measurement of weld material fracture toughness properties is important for the structural integrity assessment of engineering components. However, welds can contain high levels of residual stress and these can be retained in fracture mechanics specimens, particularly when machined from non-stress relieved welds. Retained residual stresses can make the measurement of valid fracture toughness properties difficult. This paper describes the results of analytical work undertaken to investigate factors that can influence the magnitude and distribution of residual stresses retained in fracture mechanics specimen blanks extracted from as-welded ferritic and austenitic stainless steel plates. The results indicate that significant levels of residual stress can be retained in specimen blanks prior to notching, and that the magnitude and distribution of stress is dependent upon material properties, specimen geometry and size, and extraction location through the thickness of the weld. Finite element modelling is shown to provide a useful approach for estimating the level and distributions of retained residual stresses. A new stress partitioning approach has been developed to estimate retained stress levels and results compare favourably with FE analysis and available experimental data. The approach can help guide the selection of specimen geometry and machining strategies to minimise the level of residual stresses retained in fracture mechanics specimen blanks extracted from non stress-relieved welds and thus improve the measurement of weld fracture toughness properties. - Highlights: • A simplified method for generating realistic weld residual stresses has been developed. • It has been shown that significant levels of residual stress can be retained within laboratory fracture mechanics specimens. • The level and distribution is dependant upon material, specimen type, specimen size and extraction location. • A method has been developed to allow estimates of the

Residual stresses and mechanical properties of metal matrix composites

International Nuclear Information System (INIS)

Persson, Christer.

1993-01-01

The large difference in coefficient of thermal expansion of the matrix and particles in a metal matrix composite will introduce residual stresses during cooling from process temperature. These stresses are locally very high, and are known to influence the mechanical behaviour of the material. Changes in the stress state will occur during heat treatments and when the material is loaded due to different elastic, plastic, and creep properties of the constituents. The change of residual stresses in an Al-SiC particulate composite after different degree of plastic straining has been studied. The effect of plastic straining was modelled by an Eshelby model. The model and the measurements both show that the stress in the loading direction decreases for a tensile plastic strain and increases for a compressive plastic strain. By x-ray diffraction the stress response in the matrix and particles can be measured independently. This has been used to determine the stress state under and after heat treatments and under mechanical loading in two Al 15% SiC metal matrix composites. By analysing the line width from x-ray experiment the changes in the microstrains in the material were studied. A finite element model was used to model the generation of thermal residual stresses, stress relaxation during heat treatments, and load sharing during the first load cycle. Calculated stresses and microstrains were found to be in good agreement with the measured values. The elastic behaviour of the composite can be understood largely in terms of elastic load transfer between matrix and particles. However, at higher loads when the matrix becomes plastic residual stresses also become important. 21 refs

Strong and Optically Transparent Films Prepared Using Cellulosic Solid Residue Recovered from Cellulose Nanocrystals Production Waste Stream

Science.gov (United States)

Qianqian Wang; J.Y. Zhu; John M. Considine

2013-01-01

We used a new cellulosic material, cellulosic solid residue (CSR), to produce cellulose nanofibrils (CNF) for potential high value applications. Cellulose nanofibrils (CNF) were produced from CSR recovered from the hydrolysates (waste stream) of acid hydrolysis of a bleached Eucalyptus kraft pulp (BEP) to produce nanocrystals (CNC). Acid hydrolysis greatly facilitated...

Evaluation of geologic materials to limit biological intrusion into low-level radioactive waste disposal sites

International Nuclear Information System (INIS)

Hakonson, T.E.

1986-02-01

This report describes the results of a three-year research program to evaluate the performance of selected soil and rock trench cap designs in limiting biological intrusion into simulated waste. The report is divided into three sections including a discussion of background material on biological interactions with waste site trench caps, a presentation of experimental data from field studies conducted at several scales, and a final section on the interpretation and limitations of the data including implications for the user

Electrodialytic remediation of air pollution control residues

DEFF Research Database (Denmark)

Jensen, Pernille Erland

Air pollution control (APC) residue from municipal solid waste incineration (MSWI) consists of the fly ash, and, in dry and semi-dry systems, also the reaction products from the flue gas cleaning process. APC residue is considered a hazardous waste due to its high alkalinity, high content of salt...

Aluminium recovery from waste incineration bottom ash, and its oxidation level.

Science.gov (United States)

Biganzoli, Laura; Grosso, Mario

2013-09-01

The recovery of aluminium (Al) scraps from waste incineration bottom ash is becoming a common practice in waste management. However, during the incineration process, Al in the waste undergoes oxidation processes that reduce its recycling potential. This article investigates the behaviour of Al scraps in the furnace of two selected grate-fired waste-to-energy plants and the amount recoverable from the bottom ash. About 21-23% of the Al fed to the furnace with the residual waste was recovered and potentially recycled from the bottom ash. Out of this amount, 76-87% was found in the bottom ash fraction above 5 mm and thus can be recovered with standard eddy current separation technology. These values depend on the characteristics and the mechanical strength of the Al items in the residual waste. Considering Al packaging materials, about 81% of the Al in cans can be recovered from the bottom ash as an ingot, but this amount decreases to 51% for trays, 27% for a mix of aluminium and poly-laminated foils and 47% for paper-laminated foils. This shows that the recovery of Al from the incineration residues increases proportionally to the thickness of the packaging.

Cost comparison between private and public collection of residual household waste: multiple case studies in the Flemish region of Belgium.

Science.gov (United States)

Jacobsen, R; Buysse, J; Gellynck, X

2013-01-01

The rising pressure in terms of cost efficiency on public services pushes governments to transfer part of those services to the private sector. A trend towards more privatizing can be noticed in the collection of municipal household waste. This paper reports the findings of a research project aiming to compare the cost between the service of private and public collection of residual household waste. Multiple case studies of municipalities about the Flemish region of Belgium were conducted. Data concerning the year 2009 were gathered through in-depth interviews in 2010. In total 12 municipalities were investigated, divided into three mutual comparable pairs with a weekly and three mutual comparable pairs with a fortnightly residual waste collection. The results give a rough indication that in all cases the cost of private service is lower than public service in the collection of household waste. Albeit that there is an interest in establishing whether there are differences in the costs and service levels between public and private waste collection services, there are clear difficulties in establishing comparisons that can be made without having to rely on a large number of assumptions and corrections. However, given the cost difference, it remains the responsibility of the municipalities to decide upon the service they offer their citizens, regardless the cost efficiency: public or private. Copyright © 2012 Elsevier Ltd. All rights reserved.

Drying of residue and separation of nitrate salts in the sludge waste for the lagoon sludge treatment

International Nuclear Information System (INIS)

Hwang, D. S.; Lee, K. I.; Choi, Y. D.; Hwang, S. T.; Park, J. H.

2003-01-01

This study investigated the dissolution property of nitrate salts in the dissolution process by water and the drying property of residue after separating nitrates in a series of the processes for the sludge treatment. Desalination was carried out with the adding ratio of water and drying property was analyzed by TG/DTA, FTIR, and XRD. Nitrate salts involved in the sludge were separated over 97% at the water adding ratio of 2.5. But a small quantity of calcium and sodium nitrate remained in the residue These were decomposed over 600 .deg. C and calcium carbonate, which was consisted mainly of residue, was decomposed into calcium oxide over 750 .deg. C. The residue have to be decomposed over 800 .deg. C to converse uranyl nitrate of six value into the stable U 3 O 8 of four value. As a result of removing the nitrates at the water adding ratio of 2.5 and drying the residue over 900 .deg. C, volume of the sludge waste decreased over 80%

Quality and generation rate of solid residues in the boiler of a waste-to-energy plant

DEFF Research Database (Denmark)

Allegrini, Elisa; Boldrin, Alessio; Jansson, S.

2014-01-01

The Danish waste management system relies significantly on waste-to-energy (WtE) plants. The ash produced at the energy recovery section (boiler ash) is classified as hazardous waste, and is commonly mixed with fly ash and air pollution control residues before disposal. In this study, a detailed...... characterization of boiler ash from a Danish grate-based mass burn type WtE was performed, to evaluate the potential for improving ash management. Samples were collected at 10 different points along the boiler's convective part, and analysed for grain size distribution, content of inorganic elements......, polychlorinated dibenzo-. p-dioxins and dibenzofurans (PCDD and PCDF), and leaching of metals. For all samples, PCDD and PCDF levels were below regulatory limits, while high pH values and leaching of e.g. Cl were critical. No significant differences were found between boiler ash from individual sections...

The Welding Effect on Mechanical Strength of Low Level Radioactive Waste Drum Container

International Nuclear Information System (INIS)

Aisyah; Herlan Martono

2007-01-01

The treatment of compactable low level solid waste was started by compaction of 100 liter drum containing the waste using 600 kN hydraulic press in 200 liters drum. The 200 liter drum of waste container containing of compacted waste then immobilized with cement and stored in interm storage. The 200 liter drum of waste container made of carbon steel material to comply with a good mechanical strength request in order to be able to retain the waste content for long period. Welding is a one step in a waste drum container fabrication process that has an opportunity in decreasing these mechanical strength. The research is carried out by welding the waste drum container material sample by electric arc welding. Mechanical strength test carried out by measuring the tensile strength by using the tensile strength machine, hardness test by using Vickers hardness test and microstructure observation by using the optic microscope. The result shows that the welding cause the microstructure changes, its meaning of forming ferro oxide phase on welding area that leads to the brittle material, so that the mechanical strength has a decreasing slightly. Nevertheless the decreasing of mechanical strength is still in the range of safety limit. (author)

Sustainable waste management by production of activated carbon from agroforestry residues

Directory of Open Access Journals (Sweden)

Victor Ntuli

2013-01-01

Full Text Available Agroforestry waste presents a problem for disposal and negatively impacts on the environment if left to rot or burn. The aim of this study was to reduce environmental problems associated with agroforestry waste by promoting the innovative use of such waste in the production of activated carbons (ACs using a low-cost production technique, and ultimately delivering more affordable water and effluent treatment adsorbents. Four varieties of ACs from four different agroforestry materials – pine (Pinus contorta cones (PC, Abies (Abies cilicica seeds (AS, maple (Acer ginnala seeds (MS and peach (Prunus persica stones (PS – were prepared by single-step steam pyrolysis and characterised. The raw materials were evaluated for AC yield while the respective ACs were evaluated on the basis of iodine number, phenol specific area, ash content, pH, moisture content and removal of metal ions, nitrates and sulphates from aqueous solution. The AC yields for PS, PC, AS and MS were found to be 23.0%, 18.0%, 17.8% and 14.6%, respectively. The yield for PS (23% is within the specified commercial limits of 20% to 40%. The phenol specific areas of the ACs ranged between 381 m2/g and 415 m2/g higher than the commercial lower limit (300 m2/g generally specified. The ACs also showed the capacity to remove heavy metal ions from their aqueous solutions. Removal of both nitrates and sulphates in raw water was greater than 50%. Although no quantitative analysis has been performed to date, it is envisaged that the production of AC from agroforestry wastes can contribute to the sustainable management of environmental pollution by these residues and the concomitant delivery of cheaper adsorbents.

Some aspects of the technology improvement for heat reprocessing of the combustible radioactive wastes and ash residue conditioning

International Nuclear Information System (INIS)

Dmitriev, S.A.; Lifanov, F.A.; Knyazev, I.A.; Buravchenko, N.N.; Sobolev, I.A.; Mamaev, L.A.; Alekseev, A.N.; Simagina, O.S.

1991-01-01

The results of studies devoted to increasing the efficiency of thermal reprocessing (combustion) of organic low- and intermediate-level radioactive wastes are given. The new most efficient three-stage process including: 1) gasification and pyrolysis of an organic material with volatile product release, 2) coke residual combustion, ash and noncombustible materials melting, 3) combustion of volatile products of thermal decomposition is developed on the basis of the analysis of solid radioactive waste combustion schemes, mathematical simulation and laboratory studies. Experimental bed, in which these processes are realized, is created. The results obtained in it have allowed one to begin designing of the pilot-commercial plant with shaft furnace having the capacity up to 200 kg/h for solid wastes

Follow-up on analysis of dioxins in residues from Swedish waste incineration; Uppfoeljande undersoekning av dioxin i rester fraan svensk avfallsfoerbraenning

Energy Technology Data Exchange (ETDEWEB)

Lindskog, Aasa (Tyrens, Stockholm (Sweden)) (ed.)

2009-10-15

As a consequence of a debate in the late 1990's, a major study of the residues from waste incineration was performed in Sweden. In 1999, samples were collected from 21 of the 22, at the time, existing plants. Focus of the study was to analyse dioxin in flue gas treatment residue. A few analyses were also done on slag/bottom ash. A new follow-up study was decided to be carried out after some years. The present report present the result from the follow-up study from 2006 where 24 out of 29 waste incineration plants participated. Between 1999 and 2006 a number of changes have taken place in the waste incineration industry. A few new plants have been built, a few have been closed, a new and stricter law has come into force and the technical development has continued. These changes have together led to a positive development for waste incineration. As a result, the dioxin content in the flue gas residues has decreased, when the results from the two studies are being compared. The decrease is even larger for slag/bottom ash. In the 1999 study the dioxin content in the flue gas treatment residues varied from 0,2 ng/g to 18 ng/g (I-TEQ) with an average of 2-3 ng/g. The total amount for all plants was 160 g. The variation between the dioxin content in the flue gas treatment residues in the later study is smaller, the lowest value is 0,3 ng/g and the highest 5 ng/g. The average is 1,6 ng/g and the median is 1,2 ng/g, both lower that the values from 1999. The total dioxin amount for 2006 is larger than for 1999, 185 g. Although, it must be considered that the amount of incinerated waste has almost doubled during the same period. The dioxin content in the slag/bottom ash has decreased since the former study was performed. At 1999, samples of slag/bottom ash from only seven plants were analysed. The median was 0,03 ng/g and the total dioxin amount from all plants was approximated to 10 g. In the 2006 study the median amounted to 0,005 ng/g and the total amount to 9 g

Remaining Sites Verification Package for the 100-F-36, 108-F Biological Laboratory, and for the 116-F-15, 108-F Radiation Crib. Attachment to Waste Site Reclassification Form 2007-002 and 2007-003

International Nuclear Information System (INIS)

Dittmer, L.M.

2007-01-01

The 116-F-15 waste site is the former location of the 108-F Radiation Crib that was located in the first floor of the 108-F Biological Laboratory. In accordance with this evaluation, the verification sampling results support a reclassification of this site to Interim Closed Out. The current site conditions achieve the remedial action objectives and the corresponding remedial action goals established in the Remaining Sites ROD. The results of verification sampling show that residual contaminant concentrations do not preclude any future uses and allow for unrestricted use of shallow zone soils. The results also demonstrate that residual contaminant concentrations are protective of groundwater and the Columbia River

Innovative market-based policy instruments for waste management: A case study on shredder residues in Belgium.

Science.gov (United States)

Dubois, Maarten; Hoogmartens, Rob; Van Passel, Steven; Van Acker, Karel; Vanderreydt, Ive

2015-10-01

In an increasingly complex waste market, market-based policy instruments, such as disposal taxes, can give incentives for sustainable progress while leaving flexibility for innovation. However, implementation of disposal taxes is often criticised by domestic waste handlers that fear to be outcompeted by competitors in other countries. The article discusses three innovative market-based instruments that limit the impact on international competitiveness: Tradable recycling credits, refunded disposal taxes and differentiated disposal taxes. All three instruments have already been implemented for distinct environmental policies in Europe. In order to illustrate how these instruments can be used for waste policy, the literature review is complemented with a case study on shredder residues from metal-containing waste streams in Belgium. The analysis shows that a conventional disposal tax remains the most efficient, simple and transparent instrument. However, if international competition is a significant issue or if political support is weak, refunded and differentiated disposal taxes can have an added value as second-best instruments. Tradable recycling credits are not an appropriate instrument for use in small waste markets with market power. In addition, refunded taxes create similar incentives, but induce lower transactions costs. © The Author(s) 2015.

Optimisation of industrial wastes reuse as construction materials.

Science.gov (United States)

Collivignarelli, C; Sorlini, S

2001-12-01

This study concerns the reuse of two inorganic wastes, foundry residues and fly ashes from municipal solid waste incineration, as "recycled aggregate" in concrete production. This kind of reuse was optimised by waste treatment with the following steps: waste washing with water; waste stabilisation-solidification treatment with inorganic reagents; final grinding of the stabilised waste after curing for about 10-20 days. Both the treated wastes were reused in concrete production with different mix-designs. Concrete specimens were characterised by means of conventional physical-mechanical tests (compression, elasticity modulus, shrinkage) and different leaching tests. Experimental results showed that a good structural and environmental quality of "recycled concrete" is due both to a correct waste treatment and to a correct mix-design for concrete mixture.

[Do pharmaceutical waste and drug residue pose a risk to public health?].

Science.gov (United States)

Haguenoer, Jean-Marie

2010-01-01

Recently, awareness has developed of the environmental consequences of drug waste and disposal. These residues are identified as coming from either diffuse sources, the most significant of which is via the discharge of these residues in urine and feces, and thus the sewage system and water contains these drug remnants and their metabolites, or from point sources, sometimes with very high levels of concentration in waste from chemical and pharmaceutical industries, health care settings, but also from intensive livestock farming and aquaculture. Depending on their physical chemistry properties, these substances are more or less naturally biodegradable and easily treated in sewage purification plants. The effectiveness of these treatment processes is highly random and unpredictable, but is overall around 60%, nevertheless with variations of 2-99% according to the molecules. The silt from these treatment plants, sometimes very rich in lipophilic substances is on occasion reused for agricultural application as fertilizer, paving the way for a possible contamination of crops. Furthermore, the use of veterinary drugs in animals can lead to soil contamination either directly or through manure and slurry. The contamination can equally reach and affect surface water, groundwater and sometimes the water intended for human consumption. The National academy of Pharmacy has established some general recommendations on the proper use of drugs, environmental monitoring and surveillance, risk assessment for humans and the environment, prevention and the need for prevention. Several categories of drugs are more worrying: cancer treatments, antibiotics as well as transfers of anti-bio-resistance, and hormonal derivatives which has been previously demonstrated to contribute, along with other molecules, to detrimental effects on endocrines.

Production of Bioethanol from Agricultural Wastes Using Residual Thermal Energy of a Cogeneration Plant in the Distillation Phase

Directory of Open Access Journals (Sweden)

Raffaela Cutzu

2017-05-01

Full Text Available Alcoholic fermentations were performed, adapting the technology to exploit the residual thermal energy (hot water at 83–85 °C of a cogeneration plant and to valorize agricultural wastes. Substrates were apple, kiwifruit, and peaches wastes; and corn threshing residue (CTR. Saccharomyces bayanus was chosen as starter yeast. The fruits, fresh or blanched, were mashed; CTR was gelatinized and liquefied by adding Liquozyme® SC DS (Novozymes, Dittingen, Switzerland; saccharification simultaneous to fermentation was carried out using the enzyme Spirizyme® Ultra (Novozymes, Dittingen, Switzerland. Lab-scale static fermentations were carried out at 28 °C and 35 °C, using raw fruits, blanched fruits and CTR, monitoring the ethanol production. The highest ethanol production was reached with CTR (10.22% (v/v and among fruits with apple (8.71% (v/v. Distillations at low temperatures and under vacuum, to exploit warm water from a cogeneration plant, were tested. Vacuum simple batch distillation by rotary evaporation at lab scale at 80 °C (heating bath and 200 mbar or 400 mbar allowed to recover 93.35% (v/v and 89.59% (v/v of ethanol, respectively. These results support a fermentation process coupled to a cogeneration plant, fed with apple wastes and with CTR when apple wastes are not available, where hot water from cogeneration plant is used in blanching and distillation phases. The scale up in a pilot plant was also carried out.

The safety of non-incineration waste disposal devices in four hospitals of Tehran.

Science.gov (United States)

Farshad, Aliasghar; Gholami, Hamid; Farzadkia, Mahdi; Mirkazemi, Roksana; Kermani, Majid

2014-01-01

The safe management of hospital waste is a challenge in many developing countries. The aim of this study was to compare volatile organic compounds (VOCs) emissions and the microbial disinfectant safety in non-incineration waste disposal devices. VOC emissions and microbial infections were measured in four non-incineration waste disposal devices including: autoclave with and without a shredder, dry heat system, and hydroclave. Using NIOSH and US EPA-TO14 guidelines, the concentration and potential risk of VOCs in emitted gases from four devices were assessed. ProSpore2 biological indicators were used to assess the microbial analysis of waste residue. There was a significant difference in the type and concentration of VOCs and microbial infection of residues in the four devices. Emissions from the autoclave with a shredder had the highest concentration of benzene, ethyl benzene, xylene, and BTEX, and emissions from the hydroclave had the highest concentration of toluene. The highest level of microbial infection was observed in the residues of the autoclave without a shredder. There is an increased need for proper regulation and control of non-incinerator devices and for monitoring and proper handling of these devices in developing countries.

Mechanics of Biological Tissues and Biomaterials: Current Trends

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Amir A. Zadpoor

2015-07-01

Full Text Available Investigation of the mechanical behavior of biological tissues and biomaterials has been an active area of research for several decades. However, in recent years, the enthusiasm in understanding the mechanical behavior of biological tissues and biomaterials has increased significantly due to the development of novel biomaterials for new fields of application, along with the emergence of advanced computational techniques. The current Special Issue is a collection of studies that address various topics within the general theme of “mechanics of biomaterials”. This editorial aims to present the context within which the studies of this Special Issue could be better understood. I, therefore, try to identify some of the most important research trends in the study of the mechanical behavior of biological tissues and biomaterials.

Evaluation of the influence of mechanical activation on physical and chemical properties of municipal solid waste incineration sludge.

Science.gov (United States)

Caprai, V; Florea, M V A; Brouwers, H J H

2018-06-15

Despite numerous studies concerning the application of by-products in the construction field, municipal solid waste incineration (MSWI) residues are not widely used as secondary building materials. In some European countries, washing treatment to the full bottom ash (BA) fraction (0-32 mm) is applied, isolating more contaminated particles, smaller than 0.063 mm. Therefore, a MWSI sludge is produced, having a high moisture content, and thus a limited presence of soluble species. In order to enhance its performance as building material, here, dry mechanical activation is applied on MSWI sludge. Thereafter, a reactivity comparison between reference BA and untreated and treated MSWI sludge is provided, evaluating their behaviour in the presence of cement and their pozzolanic activity. Moreover, the mechanical performances, as 25% substitution of Portland cement (PC) are assessed, based on the EN 450. Mechanical activation enhances MSWI sludge physically due to the improved particle morphology and packing. Chemically, the hydration degree of PC is enhanced by the MSWI sludge by ≈25%. The milling treatment proved to be beneficial to the residues performances in the presence of PC, providing 32% higher strength than untreated sample. Environmentally, the compliance with the unshaped material legislation is successfully verified, according to the Soil Quality Decree. Copyright © 2017 Elsevier Ltd. All rights reserved.

Anaerobic Digestion of Laminaria japonica Waste from Industrial Production Residues in Laboratory- and Pilot-Scale

Science.gov (United States)

Barbot, Yann Nicolas; Thomsen, Claudia; Thomsen, Laurenz; Benz, Roland

2015-01-01

The cultivation of macroalgae to supply the biofuel, pharmaceutical or food industries generates a considerable amount of organic residue, which represents a potential substrate for biomethanation. Its use optimizes the total resource exploitation by the simultaneous disposal of waste biomaterials. In this study, we explored the biochemical methane potential (BMP) and biomethane recovery of industrial Laminaria japonica waste (LJW) in batch, continuous laboratory and pilot-scale trials. Thermo-acidic pretreatment with industry-grade HCl or industrial flue gas condensate (FGC), as well as a co-digestion approach with maize silage (MS) did not improve the biomethane recovery. BMPs between 172 mL and 214 mL g−1 volatile solids (VS) were recorded. We proved the feasibility of long-term continuous anaerobic digestion with LJW as sole feedstock showing a steady biomethane production rate of 173 mL g−1 VS. The quality of fermentation residue was sufficient to serve as biofertilizer, with enriched amounts of potassium, sulfur and iron. We further demonstrated the upscaling feasibility of the process in a pilot-scale system where a CH4 recovery of 189 L kg−1 VS was achieved and a biogas composition of 55% CH4 and 38% CO2 was recorded. PMID:26393620

Anaerobic Digestion of Laminaria japonica Waste from Industrial Production Residues in Laboratory- and Pilot-Scale

Directory of Open Access Journals (Sweden)

Yann Nicolas Barbot

2015-09-01

Full Text Available The cultivation of macroalgae to supply the biofuel, pharmaceutical or food industries generates a considerable amount of organic residue, which represents a potential substrate for biomethanation. Its use optimizes the total resource exploitation by the simultaneous disposal of waste biomaterials. In this study, we explored the biochemical methane potential (BMP and biomethane recovery of industrial Laminaria japonica waste (LJW in batch, continuous laboratory and pilot-scale trials. Thermo-acidic pretreatment with industry-grade HCl or industrial flue gas condensate (FGC, as well as a co-digestion approach with maize silage (MS did not improve the biomethane recovery. BMPs between 172 mL and 214 mL g−1 volatile solids (VS were recorded. We proved the feasibility of long-term continuous anaerobic digestion with LJW as sole feedstock showing a steady biomethane production rate of 173 mL g−1 VS. The quality of fermentation residue was sufficient to serve as biofertilizer, with enriched amounts of potassium, sulfur and iron. We further demonstrated the upscaling feasibility of the process in a pilot-scale system where a CH4 recovery of 189 L kg−1 VS was achieved and a biogas composition of 55% CH4 and 38% CO2 was recorded.

Characterization of Hospital Residuals

International Nuclear Information System (INIS)

Blanco Meza, A.; Bonilla Jimenez, S.

1997-01-01

The main objective of this investigation is the characterization of the solid residuals. A description of the handling of the liquid and gassy waste generated in hospitals is also given, identifying the source where they originate. To achieve the proposed objective the work was divided in three stages: The first one was the planning and the coordination with each hospital center, in this way, to determine the schedule of gathering of the waste can be possible. In the second stage a fieldwork was made; it consisted in gathering the quantitative and qualitative information of the general state of the handling of residuals. In the third and last stage, the information previously obtained was organized to express the results as the production rate per day by bed, generation of solid residuals for sampled services, type of solid residuals and density of the same ones. With the obtained results, approaches are settled down to either determine design parameters for final disposition whether for incineration, trituration, sanitary filler or recycling of some materials, and storage politics of the solid residuals that allow to determine the gathering frequency. The study concludes that it is necessary to improve the conditions of the residuals handling in some aspects, to provide the cleaning personnel of the equipment for gathering disposition and of security, minimum to carry out this work efficiently, and to maintain a control of all the dangerous waste, like sharp or polluted materials. In this way, an appreciable reduction is guaranteed in the impact on the atmosphere. (Author) [es

Chemo-mechanical modeling of low-pH concretes: Application to the calculation of storage facilities for radioactive waste

International Nuclear Information System (INIS)

El Bitouri, Youssef

2014-01-01

The purpose of this work concerns to design a tool able to simulate the chemo-mechanical behavior of low-pH concretes used in radioactive waste storage, from early age to a long-term. This tool consists of a phenomenological hydration model and an original chemical evolution model. The first model is used for short-term. It can predict the development of hydration at early age and its consequences. But taking into account that this model has been developed for applications at a young age, it is based on a fixed stoichiometry of hydrates and does not take into account the specificities of low-pH cements (chemical evolution at the long-term by reaction of residual silica). Thus, a chemical evolution model at the long-term is proposed. This model is based on a variable stoichiometry of hydrates. For this, it uses the calcium mass balance for describing calcium exchange between the various hydrates and anhydrous. This equation includes the kinetics of exchanges which are based on the difference in the thermodynamic equilibrium, of the microstructure and temperature. Finally, a coupling with mechanical properties evolution was performed to simulate the mechanical behavior of the radioactive waste storage facility. (author)

Evolution Of Chemical Conditions And Estimated Plutonium Solubility In The Residual Waste Layer During Post-Closure Aging Of Tank 18

International Nuclear Information System (INIS)

Denham, M.

2012-01-01

This document updates the Eh-pH transitions from grout aging simulations and the plutonium waste release model of Denham (2007, Rev. 1) based on new data. New thermodynamic data for cementitious minerals are used for the grout simulations. Newer thermodynamic data, recommended by plutonium experts (Plutonium Solubility Peer Review Report, LA-UR-12-00079), are used to estimate solubilities of plutonium at various pore water compositions expected during grout aging. In addition, a new grout formula is used in the grout aging simulations and apparent solubilities of coprecipitated plutonium are estimated using data from analysis of Tank 18 residual waste. The conceptual model of waste release and the grout aging simulations are done in a manner similar to that of Denham (2007, Rev. 1). It is assumed that the pore fluid composition passing from the tank grout into the residual waste layer controls the solubility, and hence the waste release concentration of plutonium. Pore volumes of infiltrating fluid of an assumed composition are reacted with a hypothetical grout block using The Geochemist's Workbench(reg s ign) and changes in pore fluid chemistry correspond to the number of pore fluid volumes reacted. As in the earlier document, this results in three states of grout pore fluid composition throughout the simulation period that are termed Reduced Region II, Oxidized Region II, and Oxidized Region III. The one major difference from the earlier document is that pyrite is used to account for reducing capacity of the tank grout rather than pyrrhotite. This poises Eh at -0.47 volts during Reduced Region II. The major transitions in pore fluid composition are shown. Plutonium solubilities are estimated for discrete PuO2(am,hyd) particles and for plutonium coprecipitated with iron phases in the residual waste. Thermodynamic data for plutonium from the Nuclear Energy Agency are used to estimate the solubilities of the discrete particles for the three stages of pore fluid

Bioactive compounds and antioxidant potential for polyphenol-rich cocoa extract obtained by agroindustrial residue.

Science.gov (United States)

Gabbay Alves, Taís Vanessa; Silva da Costa, Russany; Aliakbarian, Bahar; Casazza, Alessandro Alberto; Perego, Patrizia; Pinheiro Arruda, Mara Silvia; Carréra Silva Júnior, José Otávio; Converti, Attilio; Ribeiro Costa, Roseane Maria

2017-11-10

Processing of cocoa (Theobroma cacao L.) beans responsible for agricultural exports leads to large amounts of solid waste that were discarded, however, this one presents high contents of metabolites with biological activities. The major objective of this study was to valorise cocoa agroindustrial residue obtained by hydraulic pressing for extract rich in antioxidants. For it, the centesimal composition of residue was investigated, the green extraction was carried out from the residue after, the bioactive compounds, sugar contents and screaming by HPTLC were quantified for extract. The extract has a total polyphenol content of 229.64 mg/g and high antioxidant activity according to ABTS 225.0 μM/g. HTPLC analysis confirmed the presence in the extract, residue of terpenes, sesquiterpenes, flavonoids and antioxidant activity. These results, as a whole, suggest that the extract from the cocoa residue has interesting characteristics to alternative crops with potential industrial uses.

Vacuum evaporator-crystallizer process development for Hanford defense waste

International Nuclear Information System (INIS)

Tanaka, K.H.

1978-04-01

One of the major programs in the Department of Energy (DOE) waste management operations at Hanford is the volume reduction and solidification of Hanford Defense Residual Liquor (HDRL) wastes. These wastes are neutralized radioactive wastes that have been concentrated and stored in single-shell underground tanks. Two production vacuum evaporator-crystallizers were built and are operating to reduce the liquid volume and solidify these wastes. The process involves evaporating water under vacuum and thus concentrating and crystallizing the salt waste. The high caustic residual liquor is composed primarily of nitrate, nitrite, aluminate, and carbonate salts. Past evaporator-crystallizer operation was limited to crystallizing nitrate, nitrite, and carbonate salts. These salts formed a drainable salt cake that was acceptable for storage in the original single-shell tanks. The need for additional volume reduction and further concentration necessitated this process development work. Further concentration forms aluminate salts which pose unique processing problems. The aluminate salts are very fine crystals, non-drainable, and suitable only for storage in new double-shell tanks where the fluid waste can be continuously monitored. A pilot scale vacuum evaporator-crystallizer system was built and operated by Rockwell Hanford Operations to support flowsheet development for the production evaporator-crystallizers. The process developed was the concentration of residual liquor to form aluminate salts. The pilot plant tests demonstrated that residual liquors with high aluminum concentrations could be concentrated and handled in a vacuum evaporator-crystallizer system. The dense slurry with high solids content and concentrated liquor was successfully pumped in the insulated heated piping system. The most frequent problem encountered in the pilot plant was the failure of mechanical pump seals due to the abrasive slurry

Utilization of borosilicate glass for transuranic waste immobilization

International Nuclear Information System (INIS)

Ledford, J.A.; Williams, P.M.

1979-01-01

Incinerated transuranic waste and other low-level residues have been successfully vitrified by mixing with boric acid and sodium carbonate and heating to 1050 0 C in a bench-scale continuous melter. The resulting borosilicate glass demonstrates excellent mechanical durability and chemical stability

Recovery of transuranics from process residues

International Nuclear Information System (INIS)

Gray, J.H.; Gray, L.W.

1987-01-01

Process residues are generated at both the Rocky Flats Plant (RFP) and the Savannah River Plant (SRP) during aqueous chemical and pyrochemical operations. Frequently, process operations will result in either impure products or produce residues sufficiently contaminated with transuranics to be nondiscardable as waste. Purification and recovery flowsheets for process residues have been developed to generate solutions compatible with subsequent Purex operations and either solid or liquid waste suitable for disposal. The ''scrub alloy'' and the ''anode heel alloy'' are examples of materials generated at RFP which have been processed at SRP using the developed recovery flowsheets. Examples of process residues being generated at SRP for which flowsheets are under development include LECO crucibles and alpha-contaminated hydraulic oil

Electrodialytically treated MSWI APC residue as substitute for cement in mortar

DEFF Research Database (Denmark)

Kirkelund, Gunvor Marie; Geiker, Mette Rica; Jensen, Pernille Erland

2014-01-01

Air pollution control (APC) residues from municipal solid waste incineration (MSWI) are considered hazardous waste and need pretreatment prior to possible reuse. Here, two MSWI APC residues, from which the most mobile fraction of heavy metals and salts has been removed by carbonation and/or elect......Air pollution control (APC) residues from municipal solid waste incineration (MSWI) are considered hazardous waste and need pretreatment prior to possible reuse. Here, two MSWI APC residues, from which the most mobile fraction of heavy metals and salts has been removed by carbonation and....../or electrodialytic remediation, were used in Portland cement mortar. Mortar bars with 15 % weight replacement of cement by APC residues showed compressive strengths up to 40 MPa after 28/32 days. Heavy metal and salt leaching from both crushed and monolithic mortars with APC residues was generally similar...

Technical evaluation of two methods for composting of organic wastes to be used in domestic vegetables gardens

OpenAIRE

Campos-Rodríguez, Rooel; Brenes-Peralta, Laura; Jiménez-Morales, María Fernanda

2016-01-01

The need to achieve organic waste management solutions has led to treatment options of waste like composting. This practice is defined as the transformation of organic wastes by biological means in controlled conditions; the result is a fertilizer or substrate which can be used in agriculture. In this investigation, a technical evaluation of two composting methods to be applied in home vegetable gardens was carried out. The first  method for degrading of residues evaluated consists in the add...

Electrolysis of Gold from Filtration Waste by Means of Mechanical Activation

Directory of Open Access Journals (Sweden)

Jana Ficeriová

2012-12-01

Full Text Available The intensification of the gold thiourea leaching from a filtration waste (Košice, Slovakia using mechanical activationas the pretreatment step has been studied. The leaching of “as-received“ sample in an acid thiourea solution resulted in 65 % Audissolution. However, after mechanical activation in a planetary mill 99 % of the gold was leached. The optimum redox potential forelectrolysis is in the range 500-523 mV for the gold extraction 99.79 % from the mechanically activated sample. The mechanicalactivation resulted in an increase of the specific surface area of the waste from 0.7 m2g-1 to a maximum value of 13.5 m2g-1. The physicochemicalchanges in the filtration waste as a consequence of mechanical activation had a pronounced influence on the subsequent goldextraction.

Biological test methods for the ecotoxicological characterization of wastes. Final report; Biologische Testerverfahren zur oekotoxikologischen Charakterisierung von Abfaellen. Abschlussbericht

Energy Technology Data Exchange (ETDEWEB)

Becker, Roland [Bundesanstalt fuer Materialforschung, Berlin (Germany); Donnevert, Gerhild [Fachhochschule Giessen-Friedberg (Germany). FB MNI; Roembke, Joerg [ECT Oekotoxikologie GmbH, Floersheim am Main (Germany)

2007-11-15

battery the acceptance rate varied between 74.1% (Algae test) and 92.6% (Daphnia test). Methodologically, no problems occurred but further guidance on moisture determination in the terrestrial tests as well as details concerning reference testing and data evaluation for several tests are needed. Independently which test system is considered, SOI always caused the lowest effects and WOO was most toxic, while the EC50 values of INC show an intermediate toxicity. Among the aquatic tests, daphnids and one algal species were the most sensitive ones, while plants were always more sensitive than earthworms in the solid waste samples. Based on the test results from additional tests proposals for the modification of the existing basic test battery could be made. For example, the earthworm acute test could be replaced by another soil invertebrate test with higher sensitivity. Further work performed in parallel to the ring test improves waste testing considerably (e.g. the use of artificial soil as control substrate). A comparison of the ring test results with literature data published so far revealed a good agreement. The results of this ring test support confirm that a combination of a battery of biological tests and chemical residue analysis is needed for an ecotoxicological characterization of wastes. With small modifications proposed in this report the basic test battery is considered to be well suitable for the hazard and risk assessment of wastes. Further, probably multi-variate evaluation of the ring test results will improve the identification of those tests most qualified for the ecotoxicological characterization of wastes. Finally, the experiences made in the ring test support also the proposals made in CEN guideline 14735 (2005) concerning the performance of such tests. (orig.)

Electrodialytic removal of heavy metals and chloride from municipal solid waste incineration fly ash and air pollution control residue in suspension - test of a new two compartment experimental cell

DEFF Research Database (Denmark)

Kirkelund, Gunvor Marie; Magro, Cátia; Guedes, Paula

2015-01-01

Municipal solid waste incineration (MSWI) residues such as fly ash and air pollution control (APC) residues are classified as hazardous waste and disposed of, although they contain potential resources. The most problematic elements in MSWI residues are leachable heavy metals and salts. For reuse...... of MSWI residues in for instance concrete, the aim of remediation should be reduction of the heavy metal leaching, while at the same time keeping the alkaline pH, so the residue can replace cement. In this study a MSWI residues were subjected to electrodialytic remediation under various experimental...... heavy metal leaching except when the pH was reduced to a level below 8 for the fly ash. On the other hand, Cr leaching increased by the electrodialytic treatment. Cl leaching from the MSWI residues was less dependent on experimental conditions and was reduced in all experiments compared to the initial...

Bioenergy from agro-industrial residues in the East African region. Summary report

Energy Technology Data Exchange (ETDEWEB)

Jungersen, G. [Dansk Teknologisk Inst. (Denmark); Kivaisi, A.; Rubindamayugi, M. [Univ. of Dar es Salaam (Tanzania, United Republic of)

1998-05-01

Tanzania has recently developed a comprehensive environmental policy which has put high priority on several specific environmental issues. One of the issues is the quality of waste water. A special priority is given to the pollution from the sisal industry. The East-African agro-industries generate very large quantities of organic residues from production and processing of different crops. These residues form a major contribution to the pollution of air, soil and waterways, but, at the same time they constitute a large potential for production of bioenergy through anaerobic digestion as well as potential substrate for other biological fermentation processes. Generally, these residues are regarded as having no or very little value and the different disposal methods are mainly a matter of getting rid of the waste. The generation of residues are very often concentrated on few large units, which makes the exploitation of these resources feasible in large scale biogas systems. Typically the units will have a potential of a daily methane generation of 1,000-20,000 m{sup 3} CH{sub 4}, equivalent to a potential electricity production of 0.2-3.2 MW. The future utilization of these resources for production of valuable products is described in this report. This report consists of 3 volumes. This summary report including the main objectives and findings from the different project report: Mapping and Quantification of Organic Agro-Industrial Residues in East Africa; Biogas - Bioenergy Potential in East Africa, Seminar Proceedings, Siler Sands, Dar es Salaam 22-23 September 1997; Bioenergy from Sisal residues - Experimental results and Capacity Building Activities. (EG)

Thermal and biological gasification

Energy Technology Data Exchange (ETDEWEB)

Overend, R.P.; Rivard, C.J. [National Renewable Energy Lab., Golden, CO (United States)

1993-12-31

Gasification is being developed to enable a diverse range of biomass resources to meet modern secondary energy uses, especially in the electrical utility sector. Biological or anaerobic gasification in US landfills has resulted in the installation of almost 500 MW(e) of capacity and represents the largest scale application of gasification technology today. The development of integrated gasification combined cycle generation for coal technologies is being paralleled by bagasse and wood thermal gasification systems in Hawaii and Scandinavia, and will lead to significant deployment in the next decade as the current scale-up activities are commercialized. The advantages of highly reactive biomass over coal in the design of process units are being realized as new thermal gasifiers are being scaled up to produce medium-energy-content gas for conversion to synthetic natural gas and transportation fuels and to hydrogen for use in fuel cells. The advent of high solids anaerobic digestion reactors is leading to commercialization of controlled municipal solid waste biological gasification rather than landfill application. In both thermal and biological gasification, high rate process reactors are a necessary development for economic applications that address waste and residue management and the production and use of new crops for energy. The environmental contribution of biomass in reducing greenhouse gas emission will also be improved.

Effects of residues from municipal solid waste landfill on corn yield and heavy metal content

International Nuclear Information System (INIS)

Prabpai, S.; Charerntanyarak, L.; Siri, B.; Moore, M.R.; Noller, Barry N.

2009-01-01

The effects of residues from municipal solid waste landfill, Khon Kaen Municipality, Thailand, on corn (Zea mays L.) yield and heavy metal content were studied. Field experiments with randomized complete block design with five treatments (0, 20, 40, 60 and 80% v/v of residues and soil) and four replications were carried out. Corn yield and heavy metal contents in corn grain were analyzed. Corn yield increased by 50, 72, 85 and 71% at 20, 40, 60 and 80% treatments as compared to the control, respectively. All heavy metals content, except cadmium, nickel and zinc, in corn grain were not significantly different from the control. Arsenic, cadmium and zinc in corn grain were strongly positively correlated with concentrations in soil. The heavy metal content in corn grain was within regulated limits for human consumption.

Electroremediation of air pollution control residues in a continuous reactor

DEFF Research Database (Denmark)

Jensen, Pernille Erland; Ferreira, Célia M. D.; Hansen, Henrik K.

2010-01-01

Air pollution control (APC) residue from municipal solid waste incineration is considered hazardous waste due to its alkalinity and high content of salts and mobile heavy metals. Various solutions for the handling of APC-residue exist, however most commercial solutions involve landfilling. A demand...... were made with raw residue, water-washed residue, acid washed residue and acid-treated residue with emphasis on reduction of heavy metal mobility. Main results indicate that the reactor successfully removes toxic elements lead, copper, cadmium and zinc from the feed stream, suggesting...

Volume of baseline data on radioactivity in drinking water, ground water, waste water, sewage sludge, residues and wastes of the annual report 1988 'Environmental radioactivity and radiation exposure'

International Nuclear Information System (INIS)

Abelmann, S.; Buenger, T.; Fusban, H.U.; Ruehle, H.; Viertel, H.; Gans, I.

1991-01-01

This WaBoLu volume is a shortened version of the annual report by the Federal Ministry of the Environment, Nature Protection and Reactor Safety 'Environmental radioactivity and radiation exposure' and gives an overview of the data on radioactivity in drinking water, ground water, waste water, sewage sludge, residues and wastes, compiled for the area of the Federal Republic of Germany in 1988 by the Institute of Water, Soil and Air Hygiene (WaBoLu) of the Federal Health Office. (BBR) With 22 figs., 15 tabs [de

Study on predicting residual life of elevator links by fracture mechanics approach

Energy Technology Data Exchange (ETDEWEB)

Li Helin; Zhang Yi; Deng Zengjie [China National Petroleum Corp., Xi`an, Shaanxi (China). Tubular Goods Research Center; Jin Dazeng [Xi`an Jiaotong Univ., Xi`an, Shaanxi (China)

1995-12-31

On the basis of investigation, failure and fracture analysis of elevator links, residual life prediction of links using fracture mechanics approach is studied, and mechanical properties, fracture toughness value K{sub IC} and fatigue crack propagation rage da/dN of the steel for elevator links are determined. Using the relation between stress intensity factor K{sub I} and the strain-energy release rate, the two-dimensional conversion thickness finite element method has been used to calculate the stress intensity factors K{sub I} for dangerous sections in the ring part of links. Furthermore, the reliability of calculations of the finite element stress intensity factors K{sub I} for dangerous sections of elevator links and the residual life computation for links are verified by fatigue tests of actual links. Finally, the experimental verification of computed results by 150T link fractured at site indicates that the computed critical crack lengths and residual life tally well with those measured and meet the needs of oil drilling.

Determining the Release of Radionuclides from Tank 18F Waste Residual Solids: FY2016 Report

Energy Technology Data Exchange (ETDEWEB)

King, William D. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Hobbs, David T. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

2016-08-12

Pore water leaching studies were conducted on actual Savannah River Site (SRS) Tank 18F residual waste solids to support Liquid Waste tank closure efforts. A test methodology was developed during previous simulant testing to produce slurries of tank residual solids and grout-representative solids in grout pore water solutions (based on SRS groundwater compositions) with pH and E_h values expected during the aging of the closed waste tank. The target conditions are provided below where the initial pore water has a reducing potential and a relatively high pH (Reducing Region II). The pore water is expected to become increasingly oxidizing with time (Oxidizing Region II) and during the latter stages of aging (Oxidizing Region III) the pH is expected to decrease. For the reducing case, tests were conducted with both unwashed and washed Tank 18F residual solids. For the oxidizing cases (Oxidizing Regions II and III), all samples were washed with simulated grout pore water solutions prior to testing, since it is expected that these conditions will occur after considerable pore water solution has passed through the system. For the reducing case, separate tests were conducted with representative ground grout solids and with calcium carbonate reagent, which is the grout phase believed to be controlling the pH. Ferrous sulfide (FeS) solids were also added to the reducing samples to lower the slurry E_h value. Calcium carbonate solids were used as the grout-representative solid phase for each of the oxidizing cases. Air purge-gas with and without CO₂ removed was transferred through the oxidizing test samples and nitrogen purge-gas was transferred through the reducing test samples during leach testing. The target pH values were achieved to within 0.5 pH units for all samples. Leaching studies were conducted over an E_h range of approximately 0.7 V. However, the highest and lowest E_h values achieved of ~+0.5 V and ~-0.2 V were

Environmental impact of APC residues from municipal solid waste incineration: reuse assessment based on soil and surface water protection criteria.

Science.gov (United States)

Quina, Margarida J; Bordado, João C M; Quinta-Ferreira, Rosa M

2011-01-01

Waste management and environmental protection are mandatory requirements of modern society. In our study, air pollution control (APC) residues from municipal solid waste incinerators (MSWI) were considered as a mixture of fly ash and fine particulate solids collected in scrubbers and fabric filters. These are hazardous wastes and require treatment before landfill. Although there are a number of treatment options, it is highly recommended to find practical applications rather than just dump them in landfill sites. In general, for using a construction material, beyond technical specifications also soil and surface water criteria may be used to ensure environmental protection. The Dutch Building Materials Decree (BMD) is a valuable tool in this respect and it was used to investigate which properties do not meet the threshold criteria so that APC residues can be further used as secondary building material. To this end, some scenarios were evaluated by considering release of inorganic species from unmoulded and moulded applications. The main conclusion is that the high amount of soluble salts makes the APC residues a building material prohibited in any of the conditions tested. In case of moulding materials, the limits of heavy metals are complied, and their use in Category 1 would be allowed. However, also in this case, the soluble salts lead to the classification of "building material not allowed". The treatments with phosphates or silicates are able to solve the problem of heavy metals, but difficulties with the soluble salts are still observed. This analysis suggests that for APC residues to comply with soil and surface water protection criteria to be further used as building material at least a pre-treating for removing soluble salts is absolutely required. Copyright © 2011 Elsevier Ltd. All rights reserved.

Resource recovery from residual household waste: An application of exergy flow analysis and exergetic life cycle assessment

DEFF Research Database (Denmark)

Laner, David; Rechberger, Helmut; De Soete, Wouter

2015-01-01

Exergy is based on the Second Law of thermodynamics and can be used to express physical and chemical potential and provides a unified measure for resource accounting. In this study, exergy analysis was applied to four residual household waste management scenarios with focus on the achieved resource...... of the waste treatment system under investigation and (ii) exergetic life cycle assessment (LCA) using the Cumulative Exergy Extraction from the Natural Environment (CEENE) as a method for resource accounting. Scenario efficiencies of around 17-27% were found based on the exergy flow analysis (higher...... with the functionality of a material. In addition, the definition of appropriate waste system boundaries is critical for the exergy efficiencies derived from the flow analysis, as it is constrained by limited information available about the composition of flows in the system as well as about secondary production...

Rock mechanics in the National Waste Terminal Storage Program

International Nuclear Information System (INIS)

Monsees, J.E.; Wigley, M.R.

1982-01-01

The overall objective of the rock mechanics program of the Office of Nuclear Waste Isolation is to predict the response of a rock mass hosting a waste repository during its construction, operation, and postoperational phases. The operational phase is expected to be 50 to 100 yr; the postoperational phase will last until the repository no longer poses any potential hazard to the biosphere, a period that may last several thousand years. The rock mechanics program is concerned with near-field effects on mine stability, as well as far-field effects relative to the overall integrity of the geologic waste isolation system. To accomplish these objectives, the rock mechanics program has established interactive studies in numerical simulation, laboratory testing, and field testing. The laboratory and field investigations provide input to the numerical simulations and give an opportunity for verification and validation of the predictive capabilities of the computer codes. Ultimately the computer codes will be used to predict the response of the geologic system to the development of a repository. 3 references, 5 figures

Biological testing of a digested sewage sludge and derived composts.

Science.gov (United States)

Moreira, R; Sousa, J P; Canhoto, C

2008-11-01

Aiming to evaluate a possible loss of soil habitat function after amendment with organic wastes, a digested sewage sludge and derived composts produced with green residues, where biologically tested in the laboratory using soil animals (Eisenia andrei and Folsomia candida) and plants (Brassica rapa and Avena sativa). Each waste was tested mimicking a field application of 6ton/ha or 12ton/ha. Avoidance tests did not reveal any impact of sludge and composts to soil biota. Germination and growth tests showed that application of composts were beneficial for both plants. Composts did not affect earthworm's mass increase or reproduction, but the highest sludge amendment revealed negative effects on both parameters. Only the amendment of composts at the highest dose originated an impairment of springtails reproductive output. We suggest that bioassays using different test species may be an additional tool to evaluate effects of amendment of organic wastes in soil. Biological tests are sensitive to pollutants at low concentrations and to interactions undetected by routine chemical analysis.

Biological treatment of chicken feather waste for improved biogas production

Institute of Scientific and Technical Information of China (English)

Gergely Forgács; Saeid Alinezhad; Amir Mirabdollah; Elisabeth Feuk-Lagerstedt; Ilona Sárvári Horwáth

2011-01-01

A two-stage system was developed which combines the biological degradation of keratin-rich waste with the production of biogas.Chicken feather waste was treated biologically with a recombinant Bacillus megaterium strain showing keratinase activity prior to biogas production.Chopped,autoclaved chicken feathers (4%,W/V) were completely degraded,resulting in a yellowish fermentation broth with a level of 0.51 mg/mL soluble proteins after 8 days of cultivation of the recombinant strain.During the subsequent anaerobic batch digestion experiments,methane production of 0.35 Nm3/kg dry feathers (i.e.,0.4 Nm3/kg volatile solids of feathers),corresponding to 80% of the theoretical value on proteins,was achieved from the feather hydrolyzates,independently of the prehydrolysis time period of 1,2 or 8 days.Cultivation with a native keratinase producing strain,Bacillus licheniformis resulted in only 0.25 mg/mL soluble proteins in the feather hydrolyzate,which then was digested achieving a maximum accumulated methane production of 0.31 Nm3/kg dry feathers.Feather hydrolyzates treated with the wild type B.megaterium produced 0.21 Nm3 CH4/kg dry feathers as maximum yield.

On the Structural Context and Identification of Enzyme Catalytic Residues

Directory of Open Access Journals (Sweden)

Yu-Tung Chien

2013-01-01

Full Text Available Enzymes play important roles in most of the biological processes. Although only a small fraction of residues are directly involved in catalytic reactions, these catalytic residues are the most crucial parts in enzymes. The study of the fundamental and unique features of catalytic residues benefits the understanding of enzyme functions and catalytic mechanisms. In this work, we analyze the structural context of catalytic residues based on theoretical and experimental structure flexibility. The results show that catalytic residues have distinct structural features and context. Their neighboring residues, whether sequence or structure neighbors within specific range, are usually structurally more rigid than those of noncatalytic residues. The structural context feature is combined with support vector machine to identify catalytic residues from enzyme structure. The prediction results are better or comparable to those of recent structure-based prediction methods.

Geochemical, hydrological, and biological cycling of energy residual. Research plan

International Nuclear Information System (INIS)

Wobber, F.J.

1983-03-01

Proposed research goals and specific research areas designed to provide a base of fundamental scientific information so that the geochemical, hydrological, and biophysical mechanisms that contribute to the transport and long term fate of energy residuals in natural systems can be understood are described. Energy development and production have resulted in a need for advanced scientific information on the geochemical transformations, transport rates, and potential for bioaccumulation of contaminants in subsurface environments

Seal Formation Mechanism Beneath Animal Waste Holding Ponds

Science.gov (United States)

Cihan, A.; Tyner, J. S.; Wright, W. C.

2005-12-01

Infiltration of animal waste from holding ponds can cause contamination of groundwater. Typically, the initial flux from a pond decreases rapidly as a seal of animal waste particulates is deposited at the base of the pond. The purpose of this study was to investigate the mechanism of the seal formation. Twenty-four soil columns (10-cm diameter by 43-cm long) were hand-packed with sand, silty loam or clay soils. A 2.3 m column of dairy or swine waste was applied to the top of the each column. The leakage rate from each column was measured with respect to time to analyze the effect of seal formation on different soil textures and animal waste types. We tested our hypothesis that seal growth and the subsequent decrease of leachate production adheres to a filter cake growth model. Said model predicts that the cumulative leakage rate is proportional to the square root of time and to the square root of the height of the waste.

The effects of composting on the nutritional composition of fibrous bio-regenerative life support systems (BLSS) plant waste residues and its impact on the growth of Nile tilapia ( Oreochromis niloticus)

Science.gov (United States)

Gonzales, John M.; Lowry, Brett A.; Brown, Paul B.; Beyl, Caula A.; Nyochemberg, Leopold

2009-04-01

Utilization of bio-regenerative life support systems (BLSS) plant waste residues as a nutritional source by Nile tilapia ( Oreochromis niloticus) has proven problematic as a result of high concentrations of fibrous compounds in the plant waste residues. Nutritional improvement of plant waste residues by composting with the oyster mushroom ( Pleurotus ostreatus), and the effects on growth and nutrient utilization of Nile tilapia fed such residues were evaluated. Five Nile tilapia (mean weight = 70.9 ± 3.1 g) were stocked in triplicate aquaria and fed one of two experimental diets, cowpea (CP) and composted cowpea (CCP), twice daily for a period of 8 weeks. Composting of cowpea residue resulted in reduced concentrations of nitrogen-free extract, hemi-cellulose and trypsin inhibitor activity, though trypsin inhibitor activity remained high. Composting did not reduce crude fiber, lignin, or cellulose concentrations in the diet. No significant differences ( P tilapia fed CP and CCP. These results suggest that P. ostreatus is not a suitable candidate for culture in conjunction with the culture of Nile tilapia. Additional work is needed to determine what, if any, benefit can be obtained from incorporating composted residue as feed for Nile tilapia.

Environmental impacts of residual municipal solid waste incineration: a comparison of 110 French incinerators using a life cycle approach.

Science.gov (United States)

Beylot, Antoine; Villeneuve, Jacques

2013-12-01

Incineration is the main option for residual Municipal Solid Waste treatment in France. This study compares the environmental performances of 110 French incinerators (i.e., 85% of the total number of plants currently in activity in France) in a Life Cycle Assessment perspective, considering 5 non-toxic impact categories: climate change, photochemical oxidant formation, particulate matter formation, terrestrial acidification and marine eutrophication. Mean, median and lower/upper impact potentials are determined considering the incineration of 1 tonne of French residual Municipal Solid Waste. The results highlight the relatively large variability of the impact potentials as a function of the plant technical performances. In particular, the climate change impact potential of the incineration of 1 tonne of waste ranges from a benefit of -58 kg CO2-eq to a relatively large burden of 408 kg CO2-eq, with 294 kg CO2-eq as the average impact. Two main plant-specific parameters drive the impact potentials regarding the 5 non-toxic impact categories under study: the energy recovery and delivery rate and the NOx process-specific emissions. The variability of the impact potentials as a function of incinerator characteristics therefore calls for the use of site-specific data when required by the LCA goal and scope definition phase, in particular when the study focuses on a specific incinerator or on a local waste management plan, and when these data are available. Copyright © 2013 Elsevier Ltd. All rights reserved.

Municipal Solid Waste: Pre-Treatment Options and Benefits on Landfill Emissions

OpenAIRE

Bakare Babatunde Femi

2011-01-01

Municipal solid waste (MSW) comprises of a wide range of heterogeneous materials generated by individual, household or organization and may include food waste, garden wastes, papers, textiles, rubbers, plastics, glass, ceramics, metals, wood wastes, construction wastes but it is not limited to the above mentioned fractions. The most common Municipal Solid Waste pretreatment method in use is thermal pretreatment (incineration) and Mechanical Biological pretreatment. This p...

Effect of residual H2O2 from advanced oxidation processes on subsequent biological water treatmen : A laboratory batch study

NARCIS (Netherlands)

Wang, F.; van Halem, D.; Liu, G.; Lekkerkerker-Teunissen, K.; van der Hoek, J.P.

2017-01-01

H2O2 residuals from advanced oxidation processes (AOPs) may have critical impacts on the microbial ecology and performance of subsequent biological treatment processes, but little is known. The objective of this study was to evaluate how H2O2 residuals influence sand systems with an emphasis on

Mechanics of Biological Tissues and Biomaterials : Current Trends (editorial)

NARCIS (Netherlands)

Zadpoor, A.A.

2015-01-01

Investigation of the mechanical behavior of biological tissues and biomaterials has been an active area of research for several decades. However, in recent years, the enthusiasm in understanding the mechanical behavior of biological tissues and biomaterials has increased significantly due to the

Estimating Residual Solids Volume In Underground Storage Tanks

International Nuclear Information System (INIS)

Clark, Jason L.; Worthy, S. Jason; Martin, Bruce A.; Tihey, John R.

2014-01-01

The Savannah River Site liquid waste system consists of multiple facilities to safely receive and store legacy radioactive waste, treat, and permanently dispose waste. The large underground storage tanks and associated equipment, known as the 'tank farms', include a complex interconnected transfer system which includes underground transfer pipelines and ancillary equipment to direct the flow of waste. The waste in the tanks is present in three forms: supernatant, sludge, and salt. The supernatant is a multi-component aqueous mixture, while sludge is a gel-like substance which consists of insoluble solids and entrapped supernatant. The waste from these tanks is retrieved and treated as sludge or salt. The high level (radioactive) fraction of the waste is vitrified into a glass waste form, while the low-level waste is immobilized in a cementitious grout waste form called saltstone. Once the waste is retrieved and processed, the tanks are closed via removing the bulk of the waste, chemical cleaning, heel removal, stabilizing remaining residuals with tailored grout formulations and severing/sealing external penetrations. The comprehensive liquid waste disposition system, currently managed by Savannah River Remediation, consists of 1) safe storage and retrieval of the waste as it is prepared for permanent disposition; (2) definition of the waste processing techniques utilized to separate the high-level waste fraction/low-level waste fraction; (3) disposition of LLW in saltstone; (4) disposition of the HLW in glass; and (5) closure state of the facilities, including tanks. This paper focuses on determining the effectiveness of waste removal campaigns through monitoring the volume of residual solids in the waste tanks. Volume estimates of the residual solids are performed by creating a map of the residual solids on the waste tank bottom using video and still digital images. The map is then used to calculate the volume of solids remaining in the waste tank. The ability to

The safety of non-incineration waste disposal devices in four hospitals of Tehran

Science.gov (United States)

Farshad, Aliasghar; Gholami, Hamid; Farzadkia, Mahdi; Mirkazemi, Roksana; Kermani, Majid

2014-01-01

Background: The safe management of hospital waste is a challenge in many developing countries. Objectives: The aim of this study was to compare volatile organic compounds (VOCs) emissions and the microbial disinfectant safety in non-incineration waste disposal devices. Methods: VOC emissions and microbial infections were measured in four non-incineration waste disposal devices including: autoclave with and without a shredder, dry heat system, and hydroclave. Using NIOSH and US EPA-TO14 guidelines, the concentration and potential risk of VOCs in emitted gases from four devices were assessed. ProSpore2 biological indicators were used to assess the microbial analysis of waste residue. Results: There was a significant difference in the type and concentration of VOCs and microbial infection of residues in the four devices. Emissions from the autoclave with a shredder had the highest concentration of benzene, ethyl benzene, xylene, and BTEX, and emissions from the hydroclave had the highest concentration of toluene. The highest level of microbial infection was observed in the residues of the autoclave without a shredder. Conclusions: There is an increased need for proper regulation and control of non-incinerator devices and for monitoring and proper handling of these devices in developing countries. PMID:25000113

Energy from biogenic wastes and residual materials. Potentials, perspectives and examples; Energie aus biogenen Abfaellen und Reststoffen. Potenziale, Perspektiven und Beispiele

Energy Technology Data Exchange (ETDEWEB)

Nelles, Michael [Rostock Univ. (Germany). Lehrstuhl Abfall- und Stoffstromwirtschaft; Deutsches Biomasseforschungszentrum gemeinnuetzige GmbH (DBFZ) Leipzig (Germany); Morscheck, Gert; Schuech, Andrea; Scholwin, Frank [Rostock Univ. (Germany). Lehrstuhl Abfall- und Stoffstromwirtschaft

2013-10-01

One of the most important global tasks in the future is to secure a sustainable supply of raw material and energy, which must be economically, ecologically and socially acceptable. In both fields - energy and raw material - the waste management can contribute a substantial share. In particular, the positive environmental effects of waste recycling have been shown by numerous scientific studies. Waste management in Germany has achieved a high level of development and already makes significant contributions to sustainability. Here in Germany the waste management contributes significantly to climate protection, whereas in many developing and emerging countries about 10 to 15 percent of the greenhouse gas emissions results from waste handling processes. The previous success of the German waste management according to the climate protection goals primarily results from the recycling and energetic utilization of the biogenic waste and residues, whereby in this field still exists potential for further development and optimization, which must be used in the next years. (orig.)

Guidance for classification of residues from combustion and incineration in accordance with the Swedish ordinance for waste; Vaegledning foer klassificering av foerbraenningsrester enligt Avfallsfoerordningen

Energy Technology Data Exchange (ETDEWEB)

Adler, Peter [AaF Energi och Miljoe AB, Stockholm (Sweden); Haglund, Jan-Erik [Soederenergi AB, Stockholm (Sweden); Sjoeblom, Rolf [Tekedo AB, Nykoeping (Sweden)

2004-05-01

A new ordinance for waste came into force in Sweden on the first of January 2002, replacing some previous ordinances. The new ordinance is based on certain EU directives and contains amongst other things new rules regarding how certain streams of waste are to be classified into hazardous waste and non-hazardous waste. In a number of cases, the classification is to be made according to whether or not the waste possesses one or more of a number o properties H1 - H14, i e if the waste contains hazardous substances. The new rules are based on the regulation that exists for chemical substances and preparations. When attempts have been made to use these new rules in practice - e g for residues from incineration and combustion - it has become apparent that they are very difficult or even impossible to apply. The primary reason for this is that the residues contain a very large number (thousands) of substances which would have to be analysed and for which the hazard would have to be assessed correctly in accordance with the criteria for the properties (H4 - H8 and H10 - H11). Furthermore, some of the properties listed in the ordinance for waste lack criteria for assessment of hazard. These are H13 (can give rise to another substance which may be hazardous, e g leachate) and H14 (hazardous to the environment). Moreover, there are significant differences between the Ordinance of waste and the regulation of the National Chemicals Inspectorate. It is on the latter that the rules in the Ordinance of waste are based, and this is also the cause of many of the questions and of the uncertainties in the classification. In the present report, a method is developed and described for classification of residues from combustion and incineration. The method is to be applicable in practice without compromising environmental and health aspects. As a part of the present work, a compilation of content and alteration of chemical substances in is carried out. In another chapter, the experience

Processing of biological waste. Ecological efficiency and potential; Behandlung von Bioabfaellen. Oekoeffizienz und Potenziale

Energy Technology Data Exchange (ETDEWEB)

Pitschke, Thorsten; Peche, Rene; Tronecker, Dieter; Kreibe, Siegfried [bifa Umweltinstitut GmbH, Augsburg (Germany)

2013-07-01

The sustainable usage of biological wastes has to be focused on the targets protection of resources and minimization of environmental impact. The only focus on the energy inventory is not sufficient. The following recommendations are summarized: separated bio-waste collection is usually more eco-efficient; the optimized bio-waste processing should be available according to the biodegradability; anaerobic degradation for biogas production and subsequent aerobic degradation of the fermentation product for compost can be combined; low-emission operational standards should be mandatory, innovation and investment should be promoted b reliable boundary conditions; ecological aspects should be equivalent to low-cost considerations; regulatory measures should be implemented for separated bio-waste collection and processing.

Biological hydrogen production

Energy Technology Data Exchange (ETDEWEB)

Benemann, J.R. [Univ. of California, Berkeley, CA (United States)

1995-11-01

Biological hydrogen production can be accomplished by either thermochemical (gasification) conversion of woody biomass and agricultural residues or by microbiological processes that yield hydrogen gas from organic wastes or water. Biomass gasification is a well established technology; however, the synthesis gas produced, a mixture of CO and H{sub 2}, requires a shift reaction to convert the CO to H{sub 2}. Microbiological processes can carry out this reaction more efficiently than conventional catalysts, and may be more appropriate for the relatively small-scale of biomass gasification processes. Development of a microbial shift reaction may be a near-term practical application of microbial hydrogen production.

BioWaste-to-Liquid. An ecologic-economic consideration of pyrolysis oil based on biogenic residual materials and wastes; BioWaste-to-Liquid. Oekologisch-oekonomische Betrachtung von Pyrolyseoel auf Basis biogener Rest- und Abfallstoffe

Energy Technology Data Exchange (ETDEWEB)

Liemen, Franziska; Zech, Konstantin; Kroeger, Michael [DBFZ Deutsches Biomasseforschungszentrum gemeinnuetzige GmbH, Leipzig (Germany)

2012-07-01

The joint research project BioWaste-to-Liquid, which is carried out by Deutsches BiomasseForschungsZentrum (DBFZ) and Karlsruhe Institute of Technology (KIT), focuses on the provision of alternative fuels by means of fast pyrolysis. Alongside the various tests and technical analyses, an ecologic and economic assessment was carried out, that examines the performance of different raw materials in terms of GHG-emissions and production costs. The herein examined raw materials were Rape straw, Sunflower straw, residues of corn harvesting, hay, waste wood, bark and driftwood from river Rhine. The results show a good performance of waste wood and draft wood both in ecologic and economic terms, whilst especially Sunflower straw can be considered rather unsuitable since it is particularly affected by the negative effects of the compensatory fertilization. The other raw materials perform varyingly in the ecologic and economic assessments. (orig.)

Mechanics of Biological Tissues and Biomaterials: Current Trends

OpenAIRE

Amir A. Zadpoor

2015-01-01

Investigation of the mechanical behavior of biological tissues and biomaterials has been an active area of research for several decades. However, in recent years, the enthusiasm in understanding the mechanical behavior of biological tissues and biomaterials has increased significantly due to the development of novel biomaterials for new fields of application, along with the emergence of advanced computational techniques. The current Special Issue is a collection of studies that address variou...

Rock mechanics in the disposal of radioactive wastes by hydraulic fracturing

Energy Technology Data Exchange (ETDEWEB)

McClain, W C

1968-01-01

The ultimate capacity of a hydraulic-fracturing waste disposal facility is governed primarily by the integrity of the rocks overlying the injected wastes. The objective of this study is to analyze theoretically the stresses and strains generated by the injected wastes in an effort to understand the behavior of the system sufficiently well that the failure mechanism can be predicted and the capacity of the injection well estimated. The surface uplifts at Oak Ridge National Laboratory's fracturing site were compared with theoretical curves obtained by assuming the uplifts to be inversely analogous to the subsidence which occurs over mining excavations. This analysis, based on assumptions of homogeneity, isotropy, and linear elasticity, provided considerable insight into the mechanics of the process. The most probable mechanism of failure of the rock appears to be by the formation of a vertical instead of a horizontal fracture. Fracture orientation is controlled primarily by the orientation of the principal stress field in the rock. Each successive waste injection slightly modifies this stress field toward a condition more favorable to the formation of a vertical fracture. (16 refs.)

On the ASR and ASR thermal residues characterization of full scale treatment plant.

Science.gov (United States)

Mancini, G; Viotti, P; Luciano, A; Fino, D

2014-02-01

In order to obtain 85% recycling, several procedures on Automotive Shredder Residue (ASR) could be implemented, such as advanced metal and polymer recovery, mechanical recycling, pyrolysis, the direct use of ASR in the cement industry, and/or the direct use of ASR as a secondary raw material. However, many of these recovery options appear to be limited, due to the possible low acceptability of ASR based products on the market. The recovery of bottom ash and slag after an ASR thermal treatment is an option that is not usually considered in most countries (e.g. Italy) due to the excessive amount of contaminants, especially metals. The purpose of this paper is to provide information on the characteristics of ASR and its full-scale incineration residues. Experiments have been carried out, in two different experimental campaigns, in a full-scale tyre incineration plant specifically modified to treat ASR waste. Detailed analysis of ASR samples and combustion residues were carried out and compared with literature data. On the basis of the analytical results, the slag and bottom ash from the combustion process have been classified as non-hazardous wastes, according to the EU waste acceptance criteria (WAC), and therefore after further tests could be used in future in the construction industry. It has also been concluded that ASR bottom ash (EWC - European Waste Catalogue - code 19 01 12) could be landfilled in SNRHW (stabilized non-reactive hazardous waste) cells or used as raw material for road construction, with or without further treatment for the removal of heavy metals. In the case of fly ash from boiler or Air Pollution Control (APC) residues, it has been found that the Cd, Pb and Zn concentrations exceeded regulatory leaching test limits therefore their removal, or a stabilization process, would be essential prior to landfilling the use of these residues as construction material. Copyright © 2013 Elsevier Ltd. All rights reserved.

Physical mechanisms of biological molecular motors

International Nuclear Information System (INIS)

Miller, John H. Jr.; Vajrala, Vijayanand; Infante, Hans L.; Claycomb, James R.; Palanisami, Akilan; Fang Jie; Mercier, George T.

2009-01-01

Biological motors generally fall into two categories: (1) those that convert chemical into mechanical energy via hydrolysis of a nucleoside triphosphate, usually adenosine triphosphate, regarded as life's chemical currency of energy and (2) membrane bound motors driven directly by an ion gradient and/or membrane potential. Here we argue that electrostatic interactions play a vital role for both types of motors and, therefore, the tools of physics can greatly contribute to understanding biological motors

40 CFR 279.59 - Management of residues.

Science.gov (United States)

2010-07-01

... 40 Protection of Environment 26 2010-07-01 2010-07-01 false Management of residues. 279.59 Section 279.59 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED... Management of residues. Owners and operators who generate residues from the storage, processing, or re...

Quantum mechanical simulation methods for studying biological systems

International Nuclear Information System (INIS)

Bicout, D.; Field, M.

1996-01-01

Most known biological mechanisms can be explained using fundamental laws of physics and chemistry and a full understanding of biological processes requires a multidisciplinary approach in which all the tools of biology, chemistry and physics are employed. An area of research becoming increasingly important is the theoretical study of biological macromolecules where numerical experimentation plays a double role of establishing a link between theoretical models and predictions and allowing a quantitative comparison between experiments and models. This workshop brought researchers working on different aspects of the development and application of quantum mechanical simulation together, assessed the state-of-the-art in the field and highlighted directions for future research. Fourteen lectures (theoretical courses and specialized seminars) deal with following themes: 1) quantum mechanical calculations of large systems, 2) ab initio molecular dynamics where the calculation of the wavefunction and hence the energy and forces on the atoms for a system at a single nuclear configuration are combined with classical molecular dynamics algorithms in order to perform simulations which use a quantum mechanical potential energy surface, 3) quantum dynamical simulations, electron and proton transfer processes in proteins and in solutions and finally, 4) free seminars that helped to enlarge the scope of the workshop. (N.T.)

Radionuclide Retention Mechanisms in Secondary Waste-Form Testing: Phase II

Energy Technology Data Exchange (ETDEWEB)

Um, Wooyong; Valenta, Michelle M.; Chung, Chul-Woo; Yang, Jungseok; Engelhard, Mark H.; Serne, R. Jeffrey; Parker, Kent E.; Wang, Guohui; Cantrell, Kirk J.; Westsik, Joseph H.

2011-09-26

This report describes the results from laboratory tests performed at Pacific Northwest National Laboratory (PNNL) for Washington River Protection Solutions (WRPS) to evaluate candidate stabilization technologies that have the potential to successfully treat liquid secondary waste stream effluents produced by the Hanford Tank Waste Treatment and Immobilization Plant (WTP). WRPS is considering the design and construction of a Solidification Treatment Unit (STU) for the Effluent Treatment Facility (ETF) at Hanford. The ETF, a multi-waste, treatment-and-storage unit that has been permitted under the Resource Conservation and Recovery Act (RCRA), can accept dangerous, low-level, and mixed wastewaters for treatment. The STU needs to be operational by 2018 to receive secondary liquid waste generated during operation of the WTP. The STU will provide the additional capacity needed for ETF to process the increased volume of secondary waste expected to be produced by WTP. This report on radionuclide retention mechanisms describes the testing and characterization results that improve understanding of radionuclide retention mechanisms, especially for pertechnetate, {sup 99}TcO{sub 4}{sup -} in four different waste forms: Cast Stone, DuraLith alkali aluminosilicate geopolymer, encapsulated fluidized bed steam reforming (FBSR) product, and Ceramicrete phosphate bonded ceramic. These data and results will be used to fill existing data gaps on the candidate technologies to support a decision-making process that will identify a subset of the candidate waste forms that are most promising and should undergo further performance testing.

Thermal-mechanical aspects for radioactive waste storage into underground caverns

International Nuclear Information System (INIS)

Vieira, Alvaro.

1985-12-01

The thermal and mechanical behaviors of rock mass by analytical models, considering transient effects of the heat generation from radioactive wastes, are analysed. The models were applied to Brazilian gneissic type of rock, considering the usual design of vitrified waste cylinders individually installed into conveniently spaced holes. (M.C.K.) [pt

Environmental impact of APC residues from municipal solid waste incineration: Reuse assessment based on soil and surface water protection criteria

International Nuclear Information System (INIS)

Quina, Margarida J.; Bordado, Joao C.M.; Quinta-Ferreira, Rosa M.

2011-01-01

Highlights: → The Dutch Building Material Decree (BMD) was used to APC residues from MSWI. → BMD is a straightforward tool to calculate expectable loads to the environment of common pollutants. → Chloride load to the environment lead to classification of building material not allowed. → At least a pre-treatment (e.g. washing) is required in order to remove soluble salts. → The stabilization with phosphates or silicates eliminate the problem of heavy metals. - Abstract: Waste management and environmental protection are mandatory requirements of modern society. In our study, air pollution control (APC) residues from municipal solid waste incinerators (MSWI) were considered as a mixture of fly ash and fine particulate solids collected in scrubbers and fabric filters. These are hazardous wastes and require treatment before landfill. Although there are a number of treatment options, it is highly recommended to find practical applications rather than just dump them in landfill sites. In general, for using a construction material, beyond technical specifications also soil and surface water criteria may be used to ensure environmental protection. The Dutch Building Materials Decree (BMD) is a valuable tool in this respect and it was used to investigate which properties do not meet the threshold criteria so that APC residues can be further used as secondary building material. To this end, some scenarios were evaluated by considering release of inorganic species from unmoulded and moulded applications. The main conclusion is that the high amount of soluble salts makes the APC residues a building material prohibited in any of the conditions tested. In case of moulding materials, the limits of heavy metals are complied, and their use in Category 1 would be allowed. However, also in this case, the soluble salts lead to the classification of 'building material not allowed'. The treatments with phosphates or silicates are able to solve the problem of heavy metals, but

COSMOS-rice technology abrogates the biotoxic effects of municipal solid waste incinerator residues.

Science.gov (United States)

Guarienti, Michela; Cardozo, Sdenka Moscoso; Borgese, Laura; Lira, Gloria Rodrigo; Depero, Laura E; Bontempi, Elza; Presta, Marco

2016-07-01

Fly ashes generated by municipal solid waste incinerator (MSWI) are classified as hazardous waste and usually landfilled. For the sustainable reuse of these materials is necessary to reduce the resulting impact on human health and environment. The COSMOS-rice technology has been recently proposed for the treatment of fly ashes mixed with rice husk ash, to obtain a low-cost composite material with significant performances. Here, aquatic biotoxicity assays, including daphnidae and zebrafish embryo-based tests, were used to assess the biosafety efficacy of this technology. Exposure to lixiviated MSWI fly ash caused dose-dependent biotoxic effects on daphnidae and zebrafish embryos with alterations of embryonic development, teratogenous defects and apoptotic events. On the contrary, no biotoxic effects were observed in daphnidae and zebrafish embryos exposed to lixiviated COSMOS-rice material. Accordingly, whole-mount in situ hybridization analysis of the expression of various tissue-specific genes in zebrafish embryos provided genetic evidence about the ability of COSMOS-rice stabilization process to minimize the biotoxic effects of MSWI fly ash. These results demonstrate at the biological level that the newly developed COSMOS-rice technology is an efficient and cost-effective method to process MSWI fly ash, producing a biologically safe and reusable material. Copyright © 2016 Elsevier Ltd. All rights reserved.

Leaching of gold from a mechanically and mechanochemically activated waste

Directory of Open Access Journals (Sweden)

Jana Ficeriová

2010-03-01

Full Text Available The intensification of leaching of gold from a waste using mechanical activation (milling in water and mechanochemical activation(milling in thiourea solution were studied as the pretreatment steps. The leaching of “as-received“ sample in an acid thiourea solutionresulted in 78 % Au dissolution, after mechanical activation 98 % and mechanochemical activation up to 99 % of the gold was leachedduring 120 min. The mechanochemical activation resulted in an increase of the specific surface area of the waste from 0.6 m2g-1to a maximum value of 20.5 m2g-1. The activation was performed in an attritor using variable milling times. The physico-chemical changesin the waste as a consequence of mechanochemical activation had a pronounced influence on the subsequent gold extraction.

Mechanical Characterization of Thermomechanical Matrix Residual Stresses Incurred During MMC Processing

Science.gov (United States)

Castelli, Michael G.

1998-01-01

In recent years, much effort has been spent examining the residual stress-strain states of advanced composites. Such examinations are motivated by a number of significant concerns that affect composite development, processing, and analysis. The room-temperature residual stress states incurred in many advanced composite systems are often quite large and can introduce damage even prior to the first external mechanical loading of the material. These stresses, which are induced during the cooldown following high-temperature consolidation, result from the coefficient of thermal expansion mismatch between the fiber and matrix. Experimental techniques commonly used to evaluate composite internal residual stress states are non-mechanical in nature and generally include forms of x-ray and neutron diffraction. Such approaches are usually complex, involving a number of assumptions and limitations associated with a wide range of issues, including the depth of penetration, the volume of material being assessed, and erroneous effects associated with oriented grains. Furthermore, and more important to the present research, these techniques can assess only "single time" stress in the composite. That is, little, if any, information is obtained that addresses the time-dependent point at which internal stresses begin to accumulate, the manner in which the accumulation occurs, and the presiding relationships between thermoelastic, thermoplastic, and thermoviscous behaviors. To address these critical issues, researchers at the NASA Lewis Research Center developed and implemented an innovative mechanical test technique to examine in real time, the time-dependent thermomechanical stress behavior of a matrix alloy as it went through a consolidation cycle.

Factors influencing the life cycle burdens of the recovery of energy from residual municipal waste.

Science.gov (United States)

Burnley, Stephen; Coleman, Terry; Peirce, Adam

2015-05-01

A life cycle assessment was carried out to assess a selection of the factors influencing the environmental impacts and benefits of incinerating the fraction of municipal waste remaining after source-separation for reuse, recycling, composting or anaerobic digestion. The factors investigated were the extent of any metal and aggregate recovery from the bottom ash, the thermal efficiency of the process, and the conventional fuel for electricity generation displaced by the power generated. The results demonstrate that incineration has significant advantages over landfill with lower impacts from climate change, resource depletion, acidification, eutrophication human toxicity and aquatic ecotoxicity. To maximise the benefits of energy recovery, metals, particularly aluminium, should be reclaimed from the residual bottom ash and the energy recovery stage of the process should be as efficient as possible. The overall environmental benefits/burdens of energy from waste also strongly depend on the source of the power displaced by the energy from waste, with coal giving the greatest benefits and combined cycle turbines fuelled by natural gas the lowest of those considered. Regardless of the conventional power displaced incineration presents a lower environmental burden than landfill. Copyright © 2015 Elsevier Ltd. All rights reserved.

Geopolymers based on the valorization of Municipal Solid Waste Incineration residues

Science.gov (United States)

Giro-Paloma, J.; Maldonado-Alameda, A.; Formosa, J.; Barbieri, L.; Chimenos, J. M.; Lancellotti, I.

2017-10-01

The proper management of Municipal Solid Waste (MSW) has become one of the main environmental commitments for developed countries due to the uncontrolled growth of waste caused by the consumption patterns of modern societies. Nowadays, municipal solid waste incineration (MSWI) is one of the most feasible solutions and it is estimated to increase in Europe where the accessibility of landfill is restricted. Bottom ash (BA) is the most significant by-product from MSWI as it accounts for 85 - 95 % of the solid product resulting from combustion, which is classified as a non-hazardous residue that can be revalorized as a secondary aggregate in road sub-base, bulk lightweight filler in construction. In this way, revalorization of weathered BA (WBA) for the production of geopolymers may be a good alternative to common reuse as secondary aggregate material; however, the chemical process to obtain these materials involves several challenges that could disturb the stability of the material, mainly from the environmental point of view. Accordingly, it is necessary that geopolymers are able to stabilize heavy metals contained in the WBA in order to be classified as non-hazardous materials. In this regard, the SiO2/Al2O3 ratio plays an important role for the encapsulation of heavy metals and other toxic elements. The aim of this research is to formulate geopolymers starting from the 0 - 2 mm particle size fraction of WBA, as a unique raw material used as aluminumsilicate precursor. Likewise, leaching tests of the geopolymers formulated were performed to assess their environmental impact. The findings show that it is possible to formulate geopolymers using 100 % WBA as precursor, although more investigations are needed to sustain that geopolymer obtained can be considered as non-hazardous materials.

40 CFR 279.67 - Management of residues.

Science.gov (United States)

2010-07-01

... 40 Protection of Environment 26 2010-07-01 2010-07-01 false Management of residues. 279.67 Section 279.67 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED... for Energy Recovery § 279.67 Management of residues. Burners who generate residues from the storage or...

40 CFR 279.47 - Management of residues.

Science.gov (United States)

2010-07-01

... 40 Protection of Environment 26 2010-07-01 2010-07-01 false Management of residues. 279.47 Section 279.47 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED... Management of residues. Transporters who generate residues from the storage or transport of used oil must...

Physical mechanisms of biological molecular motors

Energy Technology Data Exchange (ETDEWEB)

Miller, John H. Jr. [Department of Physics and Texas Center for Superconductivity, University of Houston, 4800 Calhoun Road, Ste. 617 SR1 Houston, TX 77204-5005 (United States)], E-mail: jhmiller@uh.edu; Vajrala, Vijayanand; Infante, Hans L. [Department of Physics and Texas Center for Superconductivity, University of Houston, 4800 Calhoun Road, Ste. 617 SR1 Houston, TX 77204-5005 (United States); Claycomb, James R. [Department of Physics and Texas Center for Superconductivity, University of Houston, 4800 Calhoun Road, Ste. 617 SR1 Houston, TX 77204-5005 (United States); Department of Mathematics and Physics, Houston Baptist University, 7502 Fondren Road, Houston, TX 77074-3298 (United States); Palanisami, Akilan; Fang Jie; Mercier, George T. [Department of Physics and Texas Center for Superconductivity, University of Houston, 4800 Calhoun Road, Ste. 617 SR1 Houston, TX 77204-5005 (United States)

2009-03-01

Biological motors generally fall into two categories: (1) those that convert chemical into mechanical energy via hydrolysis of a nucleoside triphosphate, usually adenosine triphosphate, regarded as life's chemical currency of energy and (2) membrane bound motors driven directly by an ion gradient and/or membrane potential. Here we argue that electrostatic interactions play a vital role for both types of motors and, therefore, the tools of physics can greatly contribute to understanding biological motors.

Quality and generation rate of solid residues in the boiler of a waste-to-energy plant.

Science.gov (United States)

Allegrini, E; Boldrin, A; Jansson, S; Lundtorp, K; Fruergaard Astrup, T

2014-04-15

The Danish waste management system relies significantly on waste-to-energy (WtE) plants. The ash produced at the energy recovery section (boiler ash) is classified as hazardous waste, and is commonly mixed with fly ash and air pollution control residues before disposal. In this study, a detailed characterization of boiler ash from a Danish grate-based mass burn type WtE was performed, to evaluate the potential for improving ash management. Samples were collected at 10 different points along the boiler's convective part, and analysed for grain size distribution, content of inorganic elements, polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD and PCDF), and leaching of metals. For all samples, PCDD and PCDF levels were below regulatory limits, while high pH values and leaching of e.g. Cl were critical. No significant differences were found between boiler ash from individual sections of the boiler, in terms of total content and leaching, indicating that separate management of individual ash fractions may not provide significant benefits. Copyright © 2014 Elsevier B.V. All rights reserved.

Biological response of Tradescantia stamen-hairs in Brazilian radioactive waste deposits

International Nuclear Information System (INIS)

Gomes, Heliana A.; Macacini, Jose Flavio

2005-01-01

The objective of the present study was to apply a highly sensitive botanical test of mutagenicity (the Tradescantia stamen-hair mutation bioassay), to assess in situ the biological responses induced by occurring radiation in Brazilian radioactive waste deposits (waste deposits from the Mineral Treatment Unit/Brazilian Nuclear Industries (UTM/INB), from the Centro de Desenvolvimento de Tecnologia Nuclear (CDTN) and from the Instituto de Pesquisas Energeticas e Nucleares (IPEN). The mutagenesis was evaluated in environments presenting gamma radiation exposure rates ranging from 1.6 μR.min -1 up to 3300.0 μR.min -1 . It was detected a significant increase in the mutation rate for pink Tradescantia stamen-hair only for the local presenting the highest exposition rate within UTM/INB which had a radiation exposition rate of 750 μR.min -1 . The Tradescantia plants exposed to the radioactive waste deposits from CDTN and IPEN presented an insufficient number of flowers for the statistical evaluation of mutagenicity. (author)

Study of Methanogenesis while Bioutilisation of Plant Residuals

Science.gov (United States)

Ilyin, V. K.; Korniushenkova, I. N.; Starkova, L. V.; Lauriniavichius, K. S.

respect principals of planet ecology, and compatibility with other habitability systems. For these purpose the waste management technologies, relevant to application of the biodegradation properties of bacteria are of great value. Biological treatment method is based upon the biodegradation of organic substances by various microorganisms. vegetable non-edible residual, using artificial inoculum; to study peculiarities of biogas, possibilities to optimize or to reduce the share of methane. fermentation. The biogas production achieved 46 l per 1 kg of substrate. The microbial studies of biodegradation process revealed following peculiarities: (i)gradual quantitative increasing of Lactobacillus sp. (from 103 to 105 colony forming units (CFU) per ml); (ii)activation of Clostridia sp. (from 102 to 104 CFU/ml); (iii) elimination of aerobic conventional pathogens (Enterobacteriaceae sp., Protea sp., staphylococci). methane content measures revealed traces 0.1-0.4%. granules, the amount of methane in biogas reached 80-90%. biodegradation of vegetable wastes. This inoculum consists of active sludge adapted to wastes mixed with excretes of insects which consume plant wastes. Using this inoculum the biodegradation process takes less time, then that using active sludge. Regulation of methane concentration from traces to 90% may be achieved by adding of methane reactor to the plant digester.

Electrodialytic remediation of air pollution control residues in bench scale

DEFF Research Database (Denmark)

Jensen, Pernille Erland; Ferreira, Celia; Hansen, Henrik K.

2008-01-01

Air pollution control (APC) residue from municipal solid waste incineration (MSWI) is considered a hazardous waste due to its alkalinity and high content of salts and mobile heavy metals. Various solutions for the handling of APC-residue exist in different regions; however, most commercial soluti...

Airborne microorganisms from waste containers.

Science.gov (United States)

Jedlicka, Sabrina S; Stravitz, David M; Lyman, Charles E

2012-01-01

In physician's offices and biomedical labs, biological waste is handled every day. This waste is disposed of in waste containers designed for holding red autoclave bags. The containers used in these environments are closed hands-free containers, often with a step pedal. While these containers protect the user from surface-borne microorganisms, the containers may allow airborne microorganisms to escape via the open/close mechanism because of the air current produced upon open/close cycles. In this study, the air current was shown to be sufficient to allow airborne escape of microorganisms held in the container, including Aspergillus niger. However, bacterial cultures, such as Escherichia coli and Lactococcus lactis did not escape. This may be due to the choice of bacterial cultures and the absence of solid waste, such as dust or other particulate matter in the waste containers, that such strains of bacteria could travel on during aerosolization. We compared these results to those obtained using a re-designed receptacle, which mimimizes air currents, and detected no escaping microorganisms. This study highlights one potential source of airborne contamination in labs, hospitals, and other environments that dispose of biological waste.

Chemical and mechanical performance properties for various final waste forms -- PSPI scoping study

International Nuclear Information System (INIS)

Farnsworth, R.K.; Larsen, E.D.; Sears, J.W.; Eddy, T.L.; Anderson, G.L.

1996-09-01

The US DOE is obtaining data on the performance properties of the various final waste forms that may be chosen as primary treatment products for the alpha-contaminated low-level and transuranic waste at the INEL's Transuranic Storage Area. This report collects and compares selected properties that are key indicators of mechanical and chemical durability for Portland cement concrete, concrete formed under elevated temperature and pressure, sulfur polymer cement, borosilicate glass, and various forms of alumino-silicate glass, including in situ vitrification glass and various compositions of iron-enriched basalt (IEB) and iron-enriched basalt IV (IEB4). Compressive strength and impact resistance properties were used as performance indicators in comparative evaluation of the mechanical durability of each waste form, while various leachability data were used in comparative evaluation of each waste form's chemical durability. The vitrified waste forms were generally more durable than the non-vitrified waste forms, with the iron-enriched alumino-silicate glasses and glass/ceramics exhibiting the most favorable chemical and mechanical durabilities. It appears that the addition of zirconia and titania to IEB (forming IEB4) increases the leach resistance of the lanthanides. The large compositional ranges for IEB and IEB4 more easily accommodate the compositions of the waste stored at the INEL than does the composition of borosilicate glass. It appears, however, that the large potential variation in IEB and IEB4 compositions resulting from differing waste feed compositions can impact waste form durability. Further work is needed to determine the range of waste stream feed compositions and rates of waste form cooling that will result in acceptable and optimized IEB or IEB4 waste form performance. 43 refs

Physical and mechanical properties of microcrystalline cellulose prepared from local agricultural residues

International Nuclear Information System (INIS)

El-Sakhawy, M.M.; Hassan, M.L.

2005-01-01

Microcrystalline cellulose (MCC) was prepared from local agricultural residues, namely, bagasse, rice straw, and cotton stalks bleached pulps. Hydrolysis of bleached pulps was carried out using hydrochloric or sulfuric acid to study the effect of the acid used on the properties of produced microcrystalline cellulose such as degree of polymerization (DP), crystallinity index (CrI), crystallite size, bulk density, particle size, and thermal stability. The mechanical properties of tablets made from microcrystalline cellulose of the different agricultural residues were tested and compared to commercial grade MCC. The use of rice straw pulp in different proportions as a source of silica to prepare silicified microcrystalline cellulose (SMCC) was carried out. The effect of the percent of silica on the mechanical properties of tablets before and after wet granulation was tested

Physical and mechanical properties of microcrystalline cellulose prepared from local agricultural residues

Energy Technology Data Exchange (ETDEWEB)

El-Sakhawy, M M; Hassan, M L [Cellulose and Paper Dept., National Research Center, Dokki, Cairo (Egypt)

2005-07-01

Microcrystalline cellulose (MCC) was prepared from local agricultural residues, namely, bagasse, rice straw, and cotton stalks bleached pulps. Hydrolysis of bleached pulps was carried out using hydrochloric or sulfuric acid to study the effect of the acid used on the properties of produced microcrystalline cellulose such as degree of polymerization (DP), crystallinity index (CrI), crystallite size, bulk density, particle size, and thermal stability. The mechanical properties of tablets made from microcrystalline cellulose of the different agricultural residues were tested and compared to commercial grade MCC. The use of rice straw pulp in different proportions as a source of silica to prepare silicified microcrystalline cellulose (SMCC) was carried out. The effect of the percent of silica on the mechanical properties of tablets before and after wet granulation was tested.

Biological (flue) gas desulfurization

Energy Technology Data Exchange (ETDEWEB)

Buisman, C.J.N.; Dijkman, H. [PAQUES, Balk (Netherlands); Prins, W.L.; Verbraak, P. [Biostar CV, Balk (Netherlands); Den Hartog, A.J. [Hoogovens Groep BV, IJmuiden (Netherlands)

1995-12-31

Biotechnological research has been carried out to find new micro-organisms and processes to make useful products, and to reveal new ways and biotechnological mechanisms to produce elemental sulfur in waste water treatment. Biotechnological development work has been carried out and the first commercial installation (on 300 m{sup 3}/hr scale) to produce sulfur from polluted waste water was started up in 1992. The importance of this recent research and development in the area of waste water treatment was recognized. In an intensive cooperation between Hoogovens Technical Services and PACQUES the concept for a totally new Biological Flue Gas Desulfurization process (BIO-FGD), producing sulfur as by-product, was invented. It consists of the combination of a sodium scrubber with two biological reactors resulting in a very attractive new concept for a gas cleaning process. A description of the process is given and the pilot plant results are outlined. 4 figs., 5 refs.

The Emerging Role of Skeletal Muscle Metabolism as a Biological Target and Cellular Regulator of Cancer-Induced Muscle Wasting

Science.gov (United States)

Carson, James A.; Hardee, Justin P.; VanderVeen, Brandon N.

2015-01-01

While skeletal muscle mass is an established primary outcome related to understanding cancer cachexia mechanisms, considerable gaps exist in our understanding of muscle biochemical and functional properties that have recognized roles in systemic health. Skeletal muscle quality is a classification beyond mass, and is aligned with muscle’s metabolic capacity and substrate utilization flexibility. This supplies an additional role for the mitochondria in cancer-induced muscle wasting. While the historical assessment of mitochondria content and function during cancer-induced muscle loss was closely aligned with energy flux and wasting susceptibility, this understanding has expanded to link mitochondria dysfunction to cellular processes regulating myofiber wasting. The primary objective of this article is to highlight muscle mitochondria and oxidative metabolism as a biological target of cancer cachexia and also as a cellular regulator of cancer-induced muscle wasting. Initially, we examine the role of muscle metabolic phenotype and mitochondria content in cancer-induced wasting susceptibility. We then assess the evidence for cancer-induced regulation of skeletal muscle mitochondrial biogenesis, dynamics, mitophagy, and oxidative stress. In addition, we discuss environments associated with cancer cachexia that can impact the regulation of skeletal muscle oxidative metabolism. The article also examines the role of cytokine-mediated regulation of mitochondria function regulation, followed by the potential role of cancer-induced hypogonadism. Lastly, a role for decreased muscle use in cancer-induced mitochondrial dysfunction is reviewed. PMID:26593326

Aqueous recovery of plutonium from pyrochemical processing residues

International Nuclear Information System (INIS)

Gray, L.W.; Gray, J.H.

1984-01-01

Pyrochemical processes provide rapid methods to reclaim plutonium from scrap residues. Frequently, however, these processes yield an impure plutonium product and waste residues that are contaminated with actinides and are therefore nondiscardable. The Savannah River Laboratory and Plant and the Rocky Flats Plant are jointly developing new processes using both pyrochemistry and aqueous chemistry to generate pure product and discardable waste. An example of residue being treated is that from the molten salt extraction (MSE), a mixture of NaCl, KCl, MgCl 2 , PuCl 3 , AmCl 3 , PuO 2 , and Pu 0 . This mixture is scrubbed with molten aluminum containing a small amount of magnesium to produce a nonhomogeneous Al-Pu-Am-Mg alloy. This process, which rejects most of the NaCl-KCl-MgCl 2 salts, results in a product easily dissolved in 6M HNO 3 -0.1M HF. Any residual chloride in the product is removed by precipitation with Hg(I) followed by centrifuging. Plutonium and americium are then separated by the standard Purex process. The americium, initially diverted to the solvent extraction waste stream, can either be recovered or sent to waste

A tiered analytical protocol for the characterization of heavy oil residues at petroleum-contaminated hazardous waste sites

International Nuclear Information System (INIS)

Pollard, S.J.T.; Kenefick, S.L.; Hrudey, S.E.; Fuhr, B.J.; Holloway, L.R.; Rawluk, M.

1994-01-01

The analysis of hydrocarbon-contaminated soils from abandoned refinery sites in Alberta, Canada is used to illustrate a tiered analytical approach to the characterization of complex hydrocarbon wastes. Soil extracts isolated from heavy oil- and creosote-contaminated sites were characterized by thin layer chromatography with flame ionization detection (TLC-FID), ultraviolet fluorescence, simulated distillation (GC-SIMDIS) and chemical ionization GC-MS analysis. The combined screening and detailed analytical methods provided information essential to remedial technology selection including the extent of contamination, the class composition of soil extracts, the distillation profile of component classes and the distribution of individual class components within various waste fractions. Residual contamination was characteristic of heavy, degraded oils, consistent with documented site operations and length of hydrocarbon exposure at the soil surface

Building flexibility into the design of a pilot plant for the immobilisation of Pu containing residues and wastes

Energy Technology Data Exchange (ETDEWEB)

Scales, C R; Maddrell, E R [NNL, Havelock Rd, Workington, CA14 3YQ (United Kingdom); Hobbs, J; Stephen, R [Sellafield Ltd, Sellafield, CA20 1 PG (United Kingdom); Moricca, S; Stewart, M W A [ANSTO, New Illawara Road, Lucas Heights 2234 (Australia)

2013-07-01

NNL and ANSTO on behalf of Sellafield Ltd have developed a process for the immobilisation of a range of Pu containing wastes and residues. Following the inactive demonstration of the technology the project is now focusing on the design of an active pilot plant capable of validating the technology and ultimately immobilising a waste inventory containing around 100 kg plutonium. The diverse wastes from which it is uneconomic to recover Pu, require a flexible process with a wide product envelope capable of producing a wasteform suitable for disposal in a UK repository. Ceramics, glass ceramics and metal encapsulated waste-forms can be delivered by the process line which incorporates size reduction and heat treatment techniques with the aim of feeding a hot isostatic pressing process designed to deliver the highly durable waste-forms. Following a demonstration of feasibility, flowsheet development is progressing to support the design which has the aim of a fully flexible facility based in NNL's Central Laboratory on the Sellafield site. Optimisation of the size reduction, mixing and blending operations is being carried out using UO{sub 2} as a surrogate for PuO{sub 2}. This work is supporting the potential of using an enhanced glass ceramic formulation in place of the full ceramic with the aim of simplifying glove box operations. Heat treatment and subsequent HIPing strategies are being explored in order to eliminate any carbon from the feeds without increasing the valence state of the uranium present in some of the inventory which can result in an unwanted increase in wasteform volumes. The HIP and ancillary systems are being specifically designed to meet the requirements of the Sellafield site and within the constraints of the NNL Central Laboratory. The HIP is being configured to produce consolidated product cans consistent with the requirements of ongoing storage and disposal. With the aim of one cycle per day, the facility will deliver its mission of