WorldWideScience

Sample records for materials special isotopes

  1. On the source material of magmas - with special reference to Nd isotopic ratios of igneous rocks

    International Nuclear Information System (INIS)

    Shuto, Kenji

    1980-01-01

    In 1973, the Sm-Nd method was first used for the measurement of the absolute age of igneous rocks and meteorites. Subsequently in the following years, the research works by means of the Nd isotopic ratio in igneous rocks have been made strenuously in order to reveal the chemistry of the source materials of magma giving rise to the igneous rocks and further the evolution process of mantle and earth's crust. The fundamental items for the Sm-Nd method are explained. Then, the research results more important in the above connection are given. Finally, the ideas by the author concerning the source materials of magma are presented from the data available on the Nd isotopes in meteorites and igneous rocks. The following matters are described: the fundamentals of Sm-Nd method, the Nd content in seawater, the negative correlation between Nd and Sr isotopic ratios in igneous rocks, magma source materials and Nd isotopes, and considerations on magma source materials. (J.P.N.)

  2. Uranium isotopic composition and uranium concentration in special reference material SRM A (uranium in KCl/LiCl salt matrix)

    International Nuclear Information System (INIS)

    Graczyk, D.G.; Essling, A.M.; Sabau, C.S.; Smith, F.P.; Bowers, D.L.; Ackerman, J.P.

    1997-07-01

    To help assure that analysis data of known quality will be produced in support of demonstration programs at the Fuel Conditioning Facility at Argonne National Laboratory-West (Idaho Falls, ID), a special reference material has been prepared and characterized. Designated SRM A, the material consists of individual units of LiCl/KCl eutectic salt containing a nominal concentration of 2.5 wt. % enriched uranium. Analyses were performed at Argonne National Laboratory-East (Argonne, IL) to determine the uniformity of the material and to establish reference values for the uranium concentration and uranium isotopic composition. Ten units from a batch of approximately 190 units were analyzed by the mass spectrometric isotope dilution technique to determine their uranium concentration. These measurements provided a mean value of 2.5058 ± 0.0052 wt. % U, where the uncertainty includes estimated limits to both random and systematic errors that might have affected the measurements. Evidence was found of a small, apparently random, non-uniformity in uranium content of the individual SRM A units, which exhibits a standard deviation of 0.078% of the mean uranium concentration. Isotopic analysis of the uranium from three units, by means of thermal ionization mass spectrometry with a special, internal-standard procedure, indicated that the uranium isotopy is uniform among the pellets with a composition corresponding to 0.1115 ± 0.0006 wt. % 234 U, 19.8336 ± 0.0059 wt. % 235 U, 0.1337 ± 0.0006 wt. % 236 U, and 79.9171 ± 0.0057 wt. % 238 U

  3. Isotope research materials

    International Nuclear Information System (INIS)

    Anon.

    1977-01-01

    Preparation of research isotope materials is described. Topics covered include: separation of tritium from aqueous effluents by bipolar electrolysis; stable isotope targets and research materials; radioisotope targets and research materials; preparation of an 241 Am metallurgical specimen; reactor dosimeters; ceramic and cermet development; fission-fragment-generating targets of 235 UO 2 ; and wire dosimeters for Westinghouse--Bettis

  4. Special Application Thermoelectric Micro Isotope Power Sources

    International Nuclear Information System (INIS)

    Heshmatpour, Ben; Lieberman, Al; Khayat, Mo; Leanna, Andrew; Dobry, Ted

    2008-01-01

    Promising design concepts for milliwatt (mW) size micro isotope power sources (MIPS) are being sought for use in various space and terrestrial applications, including a multitude of future NASA scientific missions and a range of military applications. To date, the radioisotope power sources (RPS) used on various space and terrestrial programs have provided power levels ranging from one-half to several hundred watts. In recent years, the increased use of smaller spacecraft and planned new scientific space missions by NASA, special terrestrial and military applications suggest the need for lower power, including mW level, radioisotope power sources. These power sources have the potential to enable such applications as long-lived meteorological or seismological stations distributed across planetary surfaces, surface probes, deep space micro-spacecraft and sub-satellites, terrestrial sensors, transmitters, and micro-electromechanical systems. The power requirements are in the range of 1 mW to several hundred mW. The primary technical requirements for space applications are long life, high reliability, high specific power, and high power density, and those for some special military uses are very high power density, specific power, reliability, low radiological induced degradation, and very low radiation leakage. Thermoelectric conversion is of particular interest because of its technological maturity and proven reliability. This paper summarizes the thermoelectric, thermal, and radioisotope heat source designs and presents the corresponding performance for a number of mW size thermoelectric micro isotope power sources

  5. Smuggling special nuclear materials

    International Nuclear Information System (INIS)

    Lazaroiu, Gheorghe

    1999-01-01

    Ever since the collapse of the former Soviet Union reports have circulated with increasing frequency concerning attempts to smuggle materials from that country's civil and military nuclear programs. Such an increase obviously raises a number of concerns (outlined in the author's introduction), chief among which is the possibility that these materials might eventually fall into the hands of proliferant states or terrorist groups. The following issues are presented: significance of materials being smuggled; sources and smuggling routes; potential customers; international efforts to reduce nuclear smuggling; long-term disposition of fissile materials. (author)

  6. Supercapacitors specialities - Materials review

    Science.gov (United States)

    Obreja, Vasile V. N.

    2014-06-01

    The electrode material is a key component for supercapacitor cell performance. As it is known, performance comparison of commercial available batteries and supercapacitors reveals significantly lower energy storage capability for supercapacitor devices. The energy density of commercial supercapacitor cells is limited to 10 Wh/kg whereas that of common lead acid batteries reaches 35-40 Wh/kg. For lithium ion batteries a value higher than 100 Wh/kg is easily available. Nevertheless, supercapacitors also known as ultracapacitors or electrochemical capacitors have other advantages in comparison with batteries. As a consequence, many efforts have been made in the last years to increase the storage energy density of electrochemical capacitors. A lot of results from published work (research and review papers, patents and reports) are available at this time. The purpose of this review is a presentation of the progress to date for the use of new materials and approaches for supercapacitor electrodes, with focus on the energy storage capability for practical applications. Many reported results refer to nanostructured carbon based materials and the related composites, used for the manufacture of experimental electrodes. A specific capacitance and a specific energy are seldom revealed as the main result of the performed investigation. Thus for nanoprous (activated) carbon based electrodes a specific capacitance up to 200-220 F/g is mentioned for organic electrolyte, whereas for aqueous electrolyte, the value is limited to 400-500 F/g. Significant contribution to specific capacitance is possible from fast faradaic reactions at the electrode-electrolyte interface in addition to the electric double layer effect. The corresponding energy density is limited to 30-50 Wh/kg for organic electrolyte and to 12-17 Wh/kg for aqueous electrolyte. However such performance indicators are given only for the carbon material used in electrodes. For a supercapacitor cell, where two electrodes

  7. Supercapacitors specialities - Materials review

    Energy Technology Data Exchange (ETDEWEB)

    Obreja, Vasile V. N. [National Research and Development Institute for Microtechnologies (IMT-Bucuresti), Bucharest, 126A Erou Iancu Nicolae Street, 077190 (Romania)

    2014-06-16

    The electrode material is a key component for supercapacitor cell performance. As it is known, performance comparison of commercial available batteries and supercapacitors reveals significantly lower energy storage capability for supercapacitor devices. The energy density of commercial supercapacitor cells is limited to 10 Wh/kg whereas that of common lead acid batteries reaches 35-40 Wh/kg. For lithium ion batteries a value higher than 100 Wh/kg is easily available. Nevertheless, supercapacitors also known as ultracapacitors or electrochemical capacitors have other advantages in comparison with batteries. As a consequence, many efforts have been made in the last years to increase the storage energy density of electrochemical capacitors. A lot of results from published work (research and review papers, patents and reports) are available at this time. The purpose of this review is a presentation of the progress to date for the use of new materials and approaches for supercapacitor electrodes, with focus on the energy storage capability for practical applications. Many reported results refer to nanostructured carbon based materials and the related composites, used for the manufacture of experimental electrodes. A specific capacitance and a specific energy are seldom revealed as the main result of the performed investigation. Thus for nanoprous (activated) carbon based electrodes a specific capacitance up to 200-220 F/g is mentioned for organic electrolyte, whereas for aqueous electrolyte, the value is limited to 400-500 F/g. Significant contribution to specific capacitance is possible from fast faradaic reactions at the electrode-electrolyte interface in addition to the electric double layer effect. The corresponding energy density is limited to 30-50 Wh/kg for organic electrolyte and to 12-17 Wh/kg for aqueous electrolyte. However such performance indicators are given only for the carbon material used in electrodes. For a supercapacitor cell, where two electrodes

  8. Supercapacitors specialities - Materials review

    International Nuclear Information System (INIS)

    Obreja, Vasile V. N.

    2014-01-01

    The electrode material is a key component for supercapacitor cell performance. As it is known, performance comparison of commercial available batteries and supercapacitors reveals significantly lower energy storage capability for supercapacitor devices. The energy density of commercial supercapacitor cells is limited to 10 Wh/kg whereas that of common lead acid batteries reaches 35-40 Wh/kg. For lithium ion batteries a value higher than 100 Wh/kg is easily available. Nevertheless, supercapacitors also known as ultracapacitors or electrochemical capacitors have other advantages in comparison with batteries. As a consequence, many efforts have been made in the last years to increase the storage energy density of electrochemical capacitors. A lot of results from published work (research and review papers, patents and reports) are available at this time. The purpose of this review is a presentation of the progress to date for the use of new materials and approaches for supercapacitor electrodes, with focus on the energy storage capability for practical applications. Many reported results refer to nanostructured carbon based materials and the related composites, used for the manufacture of experimental electrodes. A specific capacitance and a specific energy are seldom revealed as the main result of the performed investigation. Thus for nanoprous (activated) carbon based electrodes a specific capacitance up to 200-220 F/g is mentioned for organic electrolyte, whereas for aqueous electrolyte, the value is limited to 400-500 F/g. Significant contribution to specific capacitance is possible from fast faradaic reactions at the electrode-electrolyte interface in addition to the electric double layer effect. The corresponding energy density is limited to 30-50 Wh/kg for organic electrolyte and to 12-17 Wh/kg for aqueous electrolyte. However such performance indicators are given only for the carbon material used in electrodes. For a supercapacitor cell, where two electrodes

  9. Isotope exchange reaction on solid breeder materials

    International Nuclear Information System (INIS)

    Baba, A.; Nishikawa, M.; Eguchi, T.; Kawagoe, T.

    2000-01-01

    Lithium ceramic materials such as Li 2 O, LiAlO 2 , Li 2 ZrO 3 , Li 2 TiO 3 and Li 4 SiO 4 are considered to be as candidate for the tritium breeding material in a deuterium-tritium (D-T) fusion reactor. In the recent blanket designs, helium gas with hydrogen or deuterium is planned to be used as the blanket purge gas to reduce tritium inventory and promote tritium release from the breeding material. In addition, the rate of isotope exchange reaction between hydrogen isotopes in the purge gas and tritium on the surface of the breeding material is necessary to analyze the tritium release behavior from the breeding materials. However, the rate of isotope exchange reactions between hydrogen isotopes in the purge gas and tritium on the surface of those materials has not been quantified until recently. Recently, the present authors quantified the rate of isotope exchange reaction on Li 2 O and Li 2 ZrO 3 . The overall mass transfer coefficients representing the isotope exchange reaction between H 2 and D 2 O on breeding materials or the same between D 2 and H 2 O are experimentally obtained in this study. Comparison to isotope exchange reaction rates on various breeding materials is also performed in this study. Discussions about the effects of temperature, concentration of hydrogen in the purge gas or flow rate of the purge gas on the conversion of tritiated water to tritium gas are also performed

  10. Special nuclear material simulation device

    Science.gov (United States)

    Leckey, John H.; DeMint, Amy; Gooch, Jack; Hawk, Todd; Pickett, Chris A.; Blessinger, Chris; York, Robbie L.

    2014-08-12

    An apparatus for simulating special nuclear material is provided. The apparatus typically contains a small quantity of special nuclear material (SNM) in a configuration that simulates a much larger quantity of SNM. Generally the apparatus includes a spherical shell that is formed from an alloy containing a small quantity of highly enriched uranium. Also typically provided is a core of depleted uranium. A spacer, typically aluminum, may be used to separate the depleted uranium from the shell of uranium alloy. A cladding, typically made of titanium, is provided to seal the source. Methods are provided to simulate SNM for testing radiation monitoring portals. Typically the methods use at least one primary SNM spectral line and exclude at least one secondary SNM spectral line.

  11. Considerations for sampling nuclear materials for SNM accounting measurements. Special nuclear material accountability report

    International Nuclear Information System (INIS)

    Brouns, R.J.; Roberts, F.P.; Upson, U.L.

    1978-05-01

    This report presents principles and guidelines for sampling nuclear materials to measure chemical and isotopic content of the material. Development of sampling plans and procedures that maintain the random and systematic errors of sampling within acceptable limits for SNM(Special Nuclear Materials) accounting purposes are emphasized

  12. Brazing of special metallic materials and material combinations using a special material

    International Nuclear Information System (INIS)

    Lison, R.

    1981-01-01

    The special materials include metals of groups IVa, Va and VIa of the periodic tables and their alloys. Their particular properties have won them applications in many highly specialized industries. For these materials to be used, mastery of thermal joining methods appropriate to their characteristics is necessary. High-temperature brazing is one such method for joining special materials. This paper presents variants of this technique suitable for each individual special material. Compatibility tests between various brazing metals and various special materials have been carried out by simulating the temperature/time cycle involved in brazing procedures. Special materials are relatively expensive, and their special properties are not required at every point in a structure: elsewhere they can be replaced by a different special material or by other metals or alloys. This means that joints must be made between two special materials or between a special material and a conventional material. When certain conditions are fulfilled, such joins can be made by high-temperature brazing. This paper also shows the extent to which the geometry of the join determines the choice of process. Example of applications are also given. (orig.)

  13. Isotope specific arbitrary material flow meter

    Science.gov (United States)

    Barty, Christopher P. J.; Post, John C.; Jones, Edwin

    2016-10-25

    A laser-based mono-energetic gamma-ray source is used to provide non-destructive and non-intrusive, quantitative determination of the absolute amount of a specific isotope contained within pipe as part of a moving fluid or quasi-fluid material stream.

  14. Isotopically enriched structural materials in nuclear devices

    Energy Technology Data Exchange (ETDEWEB)

    Morgan, L.W.G., E-mail: Lee.Morgan@ccfe.ac.uk [CCFE, Culham Science Centre, Abingdon, Oxfordshire OX14 3DB (United Kingdom); Shimwell, J. [CCFE, Culham Science Centre, Abingdon, Oxfordshire OX14 3DB (United Kingdom); Department of Physics and Astronomy, University of Sheffield, Hicks Building, Hounsfield Road, Sheffield S3 7RH (United Kingdom); Gilbert, M.R. [CCFE, Culham Science Centre, Abingdon, Oxfordshire OX14 3DB (United Kingdom)

    2015-01-15

    Highlights: • C-B analysis of isotopic enrichment of structural materials is presented. • Some, previously, prohibited elements could be used as alloying elements in LAM's. • Adding enriched molybdenum and nickel, to EUROFER, could increase availability. • Isotope enrichment for EUROFER could be cost-effective. • Isotopically enriching copper, in CuCrZr, can reduce helium production by 50%. - Abstract: A large number of materials exist which have been labeled as low activation structural materials (LAM). Most often, these materials have been designed in order to substitute-out or completely remove elements that become activated and contribute significantly to shut-down activity after being irradiated by neutrons in a reactor environment. To date, one of the fundamental principles from which LAMs have been developed is that natural elemental compositions are the building blocks of LAMs. Thus, elements such as Co, Al, Ni, Mo, Nb, N and Cu that produce long-lived decay products are significantly reduced or removed from the LAM composition. These elements have an important part to play in the composition of steels and the removal/substitution can have a negative impact on materials properties such as yield stress and fracture toughness. This paper looks in more detail at whether using isotopic selection of the more mechanically desirable, but prohibited due to activation, elements can improve matters. In particular, this paper focuses on the activation of Eurofer. Carefully chosen isotopically enriched elements, which are normally considered to be on the prohibited element list, are added to EUROFER steel as potential alloying elements. The EUROFER activation results show that some prohibited elements can be used as alloying elements in LAM steels, providing the selected isotopes do not have a significant impact on waste disposal rating or shut-down dose. The economic implications of isotopically enriching elements and the potential implications for

  15. Stable isotopes in Lithuanian bioarcheological material

    Science.gov (United States)

    Skipityte, Raminta; Jankauskas, Rimantas; Remeikis, Vidmantas

    2015-04-01

    Investigation of bioarcheological material of ancient human populations allows us to understand the subsistence behavior associated with various adaptations to the environment. Feeding habits are essential to the survival and growth of ancient populations. Stable isotope analysis is accepted tool in paleodiet (Schutkowski et al, 1999) and paleoenvironmental (Zernitskaya et al, 2014) studies. However, stable isotopes can be useful not only in investigating human feeding habits but also in describing social and cultural structure of the past populations (Le Huray and Schutkowski, 2005). Only few stable isotope investigations have been performed before in Lithuanian region suggesting a quite uniform diet between males and females and protein intake from freshwater fish and animal protein. Previously, stable isotope analysis has only been used to study a Stone Age population however, more recently studies have been conducted on Iron Age and Late medieval samples (Jacobs et al, 2009). Anyway, there was a need for more precise examination. Stable isotope analysis were performed on human bone collagen and apatite samples in this study. Data represented various ages (from 5-7th cent. to 18th cent.). Stable carbon and nitrogen isotope analysis on medieval populations indicated that individuals in studied sites in Lithuania were almost exclusively consuming C3 plants, C3 fed terrestrial animals, and some freshwater resources. Current investigation demonstrated social differences between elites and country people and is promising in paleodietary and daily life reconstruction. Acknowledgement I thank prof. dr. G. Grupe, Director of the Anthropological and Palaeoanatomical State Collection in Munich for providing the opportunity to work in her laboratory. The part of this work was funded by DAAD. Antanaitis-Jacobs, Indre, et al. "Diet in early Lithuanian prehistory and the new stable isotope evidence." Archaeologia Baltica 12 (2009): 12-30. Le Huray, Jonathan D., and Holger

  16. Safeguards for special nuclear materials

    International Nuclear Information System (INIS)

    Carlson, R.L.

    1979-12-01

    Safeguards, accountability, and nuclear materials are defined. The accuracy of measuring nuclear materials is discussed. The use of computers in nuclear materials accounting is described. Measures taken to physically protect nuclear materials are described

  17. Seismic design criteria for special isotope separation plant structures

    International Nuclear Information System (INIS)

    Wrona, M.W.; Wuthrich, S.J.; Rose, D.L.; Starkey, J.

    1989-01-01

    This paper describes the seismic criteria for the design of the Special Isotope Separation (SIS) production plant. These criteria are derived from the applicable Department of Energy (DOE) orders, references and proposed standards. The SIS processing plant consistent of Load Center Building (LCB), Dye Pump Building (DPB), Laser Support Building (LSB) and Plutonium Processing Building (PPB). The facility-use category for each of the SIS building structures is identified and the applicable seismic design criteria and parameters are selected

  18. An inter-laboratory comparison of Si isotope reference materials

    NARCIS (Netherlands)

    Reynolds, B.C.; Aggarwal, J.; André, L.; Baxter, B.; Beucher, C.; Brzezinski, M.A.; Engström, E.; Georg, R.B.; Land, M.; Leng, M.J.; Opfergelt, S.; Rodushkin, I.; Sloane, H.J.; Van den Boorn, S.H.J.M.; Vroon, P.Z.; Cardinal, D.

    2007-01-01

    Three Si isotope materials have been used for an inter-laboratory comparison exercise to ensure reproducibility between international laboratories investigating natural Si isotope variations using a variety of chemical preparation methods and mass spectrometric techniques. These proposed standard

  19. Hydrogen isotope permeation in elastomeric materials

    International Nuclear Information System (INIS)

    Steinmeyer, R.H.; Braun, J.D.

    1976-01-01

    The permeabilities of elastomeric and polymeric materials to hydrogen isotopes were measured at room temperature. The technique for measuring permeation rates is based on the following constant-volume method: a fixed pressure of gas is applied to one side of the specimen to be studied and the permeability constant is determined from the observed rate of pressure increase in an initially evacuated volume on the other side of the specimen. Permeability constants for hydrogen, deuterium, and tritium were measured for Mylar, Teflon, Kapton, Saran, Buna-N, and latex rubber. Results were compared with literature values for hydrogen and deuterium where available and showed excellent agreement

  20. Estimation methods for special nuclear materials holdup

    International Nuclear Information System (INIS)

    Pillay, K.K.S.; Picard, R.R.

    1984-01-01

    The potential value of statistical models for the estimation of residual inventories of special nuclear materials was examined using holdup data from processing facilities and through controlled experiments. Although the measurement of hidden inventories of special nuclear materials in large facilities is a challenging task, reliable estimates of these inventories can be developed through a combination of good measurements and the use of statistical models. 7 references, 5 figures

  1. Isotopic-spectral determination of hydrogen, nitrogen, oxygen and carbon in semiconductor materials

    International Nuclear Information System (INIS)

    Dudich, G.K.; Eremeev, V.A.; Li, V.N.; Nemets, V.M.

    1981-01-01

    Techniques of low-temperature isotopic-spectral determination of impurities of hydrogen, nitrogen, oxygen and carbon in semiconductor materials Bi, Ge, Pb tellurides are developed. The techniques include selection into special vessel with the known volume (exchanger) of sample analyzed, dosed introduction into exchanger of rare isotope of the element determined ( 2 H, 15 N, 18 O, 13 C) in the form of isotope-containing gas, balancing of the determined element isotopes in the system sample-isotope, containing gas, spectroscopic, determination of its isotope composition in gaseous phase of the system and calculation of the amount of the element determined in the sample. The lower boundaries of the amounts determined constitute 10 -7 , 10 -7 , 10 -6 and 10 -5 mass % respectively when sample of 20 g are used [ru

  2. Isotope materials availability and services for target production at the Oak Ridge National Laboratory

    International Nuclear Information System (INIS)

    Ratledge, J.E.; Dahl, T.L.; Ottinger, C.L.; Aaron, W.S.; Adair, H.L.

    1987-01-01

    Materials available through the Isotope Distribution Program include separated stable isotopes, byproduct radioisotopes, and research quantities of source and special nuclear materials. Isotope products are routinely available in the forms listed in the product description section of the Isotopes Products and Services Catalog distributed by the Oak Ridge National Laboratory (ORNL). Different forms can be provided in some cases, usually at additional cost. Routinely available services include cyclotron target irradiations, fabrication of special physical forms, source encapsulation, ion implantation, and special purifications. Materials and services that are not offered as part of the routine distribution program may be made available from commercial sources in the United States. Specific forms of isotopic research materials include thin films and foils for use as accelerator targets, metal or other compounds in the form of bars or wires, and metal foils. Methods of fabrication include evaporation, sputtering, rolling, electrolytic deposition, pressing, sintering, and casting. High-purity metal forms of plutonium, americium, and curium are prepared by vacuum reduction/distillation. Both fissionable and nonfissionable neutron dosimeters are prepared for determining the neutron energy spectra, flux, and fluence at various locations within a reactor. Details on what materials are available and how the materials and related services can be obtained from ORNL are described. (orig.)

  3. Three New Offset {delta}{sup 11}B Isotope Reference Materials for Environmental Boron Isotope Studies

    Energy Technology Data Exchange (ETDEWEB)

    Rosner, M. [BAM Federal Institute for Materials Research and Testing, Berlin (Germany); IsoAnalysis UG, Berlin (Germany); Vogl, J. [BAM Federal Institute for Materials Research and Testing, Berlin (Germany)

    2013-07-15

    The isotopic composition of boron is a well established tool in various areas of science and industry. Boron isotope compositions are typically reported as {delta}{sup 11}B values which indicate the isotopic difference of a sample relative to the isotope reference material NIST SRM 951. A significant drawback of all of the available boron isotope reference materials is that none of them covers a natural boron isotope composition apart from NIST SRM 951. To fill this gap of required {delta}{sup 11}B reference materials three new solution boric acid reference materials were produced, which cover 60 per mille of the natural boron isotope variation (-20 to 40 per mille {delta}{sup 11}B) of about 100 per mille . The new reference materials are certified for their {delta}{sup 11}B values and are commercially available through European Reference Materials (http://www.erm-crm.org). The newly produced and certified boron isotope reference materials will allow straightforward method validation and quality control of boron isotope data. (author)

  4. Gamma spectrometric discrimination of special nuclear materials

    International Nuclear Information System (INIS)

    Dowdall, M.; Mattila, A.; Ramebaeck, H.; Aage, H.K.; Palsson, S.E.

    2012-12-01

    This report presents details pertaining to an exercise conducted as part of the NKS-B programme using synthetic gamma ray spectra to simulate the type of data that may be encountered in the interception of material potentially containing special nuclear materials. A range of scenarios were developed involving sources that may or may not contain special nuclear materials. Gamma spectral data was provided to participants as well as ancillary data and participants were asked, under time constraint, to determine whether or not the data was indicative of circumstances involving special nuclear materials. The situations varied such that different approaches were required in order to obtain the correct result in each context. In the majority of cases participants were able to correctly ascertain whether or not the situations involved special nuclear material. Although fulfilling the primary goal of the exercise, some participants were not in a position to correctly identify with certainty the material involved, Situations in which the smuggled material was being masked by another source proved to be the most challenging for participants. (Author)

  5. Gamma spectrometric discrimination of special nuclear materials

    Energy Technology Data Exchange (ETDEWEB)

    Dowdall, M. [Norwegian Radiation Protection Authority (Norway); Mattila, A. [Radiation and Nuclear Safety Authority, Helsinki (Finland); Ramebaeck, H. [Swedish Defence Research Agency, Stockholm (Sweden); Aage, H.K. [Danish Emergency Management Agency, Birkeroed (Denmark); Palsson, S.E. [Icelandic Radiation Safety Authority, Reykjavik (Iceland)

    2012-12-15

    This report presents details pertaining to an exercise conducted as part of the NKS-B programme using synthetic gamma ray spectra to simulate the type of data that may be encountered in the interception of material potentially containing special nuclear materials. A range of scenarios were developed involving sources that may or may not contain special nuclear materials. Gamma spectral data was provided to participants as well as ancillary data and participants were asked, under time constraint, to determine whether or not the data was indicative of circumstances involving special nuclear materials. The situations varied such that different approaches were required in order to obtain the correct result in each context. In the majority of cases participants were able to correctly ascertain whether or not the situations involved special nuclear material. Although fulfilling the primary goal of the exercise, some participants were not in a position to correctly identify with certainty the material involved, Situations in which the smuggled material was being masked by another source proved to be the most challenging for participants. (Author)

  6. Availability of enriched isotopic material for accelerator targets

    International Nuclear Information System (INIS)

    Newman, E.

    1982-01-01

    The electromagnetic isotope enrichment facility at ORNL provides a broad spectrum of highly enriched stable isotopes to the worldwide scientific community. The continued timely availability of these materials is of vital importance in many areas of basic research and, in particular, as source material for the fabrication of accelerator targets. A brief description of the facility and its capabilities and limitations is presented

  7. Special isotope separation project, Idaho National Engineering Laboratory, Idaho Falls, Idaho

    International Nuclear Information System (INIS)

    1988-02-01

    Construction and operation of a Special Isotope Separation (SIS) project using the Atomic Vapor Laser Isotope Separation (AVLIS) process technology at the Idaho National Engineering Laboratory (INEL) near Idaho Falls, Idaho are proposed. The SIS project would process fuel-grade plutonium administered by the Department of Energy (DOE) into weapon-grade plutonium using AVLIS and supporting chemical processes. The SIS project would require construction and operation of a Laser Support Facility to house the laser system and a Plutonium Processing Facility. The SIS project would be integrated with existing support and waste management facilities at the selected site. The SIS project would provide DOE with the capability of segregating the isotopes of DOE-owned plutonium into specific isotopic concentrations. This capability would provide redundancy in production capacity, technological diversity, and flexibility in DOE's production of nuclear materials for national defense. Use of the INEL site would impact 151,350 square meters (37.4 acres) of land, of which more than 70% has been previously disturbed. During construction, plant and animal habitat associated with a sagebrush vegetation community would be lost. During operation of the SIS facilities, unavoidable radiation exposures would include occupational exposures and exposures to the public from normal atmospheric releases of radioactive materials that would be minimal compared to natural background radiation

  8. Thermal desorption spectroscopy for investigating hydrogen isotope behavior in materials

    International Nuclear Information System (INIS)

    Xia Tirui; Yang Hongguang; Zhan Qin; Han Zhibo; He Changshui

    2012-01-01

    The behavior of hydrogen isotope generated in fusion reactor materials is the key issue for safety and economic operation of fusion reactors and becomes an interesting field. In order to investigate the mechanism of hydrogen isotope such as diffusion, release and retention, a high-sensitivity thermal desorption spectroscopy (TDS) in combination with a quadruple mass spectrometer (QMS) was developed. A major technical breakthrough in ultrahigh vacuum (UHV), low hydrogen background, linear heating and sensitivity calibration of TDS system was made. UHV of l × 10 -7 Pa and low hydrogen background of l × 10 -9 Pa were obtained by combining turbo molecule pump and sputter ion pump. Specimens can be linearly heated up to 1173 K at the rate of 1 to 50 K/min under the MCGS PID software. Sensitivity calibration of the TDS system was accomplished using a special deuterium leak in the detector mode of QMS second electron multiplier. The desorption sensitivity coefficient and the minimum detection limit of deuterium desorption rate are 6.22 × l0 24 s -l · and l.24 × l0 -10 s -1 , respectively. The measurement was also routinely conducted on a specimen of standard, deuterium-containing Zr-4 alloy maintained in the laboratory, so as to validate the TDS method. (authors)

  9. LDEF materials special investigation group's data bases

    Science.gov (United States)

    Strickland, John W.; Funk, Joan G.; Davis, John M.

    1993-01-01

    The Long Duration Exposure Facility (LDEF) was composed of and contained a wide array of materials, representing the largest collection of materials flown for space exposure and returned for ground-based analyses to date. The results and implications of the data from these materials are the foundation on which future space missions will be built. The LDEF Materials Special Investigation Group (MSIG) has been tasked with establishing and developing data bases to document these materials and their performance to assure not only that the data are archived for future generations but also that the data are available to the space user community in an easily accessed, user-friendly form. The format and content of the data bases developed or being developed to accomplish this task are discussed. The hardware and software requirements for each of the three data bases are discussed along with current availability of the data bases.

  10. Development of Separation Materials Containing Palladium for Hydrogen Isotopes Separation

    International Nuclear Information System (INIS)

    Deng Xiaojun; Luo Deli; Qian Xiaojing

    2010-01-01

    Displacement chromatography (DC) is a ascendant technique for hydrogen isotopes separation. The performance of separation materials is a key factor to determine the separation effect of DC. At present,kinds of materials are researched, including palladium materials and non-palladium materials. It is hardly replaceable because of its excellent separation performance, although palladium is expensive. The theory of hydrogen isotopes separation using DC was introduced at a brief manner, while several palladium separation materials were expatiated in detail(Pd/K, Pd-Al 2 O 3 , Pd-Pt alloy). Development direction of separation materials for DC was forecasted elementarily. (authors)

  11. Special purpose materials for fusion application

    International Nuclear Information System (INIS)

    Scott, J.L.; Clinard, F.W. Jr.; Wiffen, F.W.

    1984-01-01

    Originally in 1978 the Special Purpose Materials Task Group was concerned with tritium breeding materials, coolants, tritium barriers, graphite and silicon carbide, ceramics, heat-sink materials, and magnet components. Since then several other task groups have been created, so now the category includes only materials for superconducting magnets and ceramics. For the former application copper-stabilized Nb 3 Sn (Ti) insulated with polyimides will meet the general requirements, so that testing of prototype components is the priority task. Ceramics are required for several critical components of fusion reactors either as dielectrics or as a structural material. Components near the first wall will receive exposures of 5 to 20 MW.year/m"2. Other ceramic applications are well behind the first wall, with lower damage levels. Most insulators operate near room temperature, but ceramic blanket structures may operate up to 1000 0 C. Because of a meager data base, one cannot identify optimum ceramics for structural application; but MgAl 2 O 4 is an attractive dielectric material

  12. Revisited. Euratom's ownership of special fissile materials

    International Nuclear Information System (INIS)

    Pelzer, Norbert

    2015-01-01

    Among all Treaties on the Foundation of the European Community, seemingly, the Euratom Treaty ist the most unobtrusive one having even nearly been declared dead occasionally. For the opponents of nuclear energy the treaty is a thorn in their side because it aims for the peaceful exploitation of nuclear energy. Actually, the treaty likewise aims for the protection of dangers of nuclear energy and encloses a bundle of collective control instruments. The protective purpose provides the community with a strong position in numerous fields towards nuclear energy users including the right to intervene in the operations of nuclear facilities. The communitie's position is further strengthened by the communitie's ownership on special fissile materials. The EAEC Treaty determines: 'Special fissile materials are owned by the community'. The material content of Euratom's ownership is limited by Article 87 of the EAEC Treaty: Unlimited right of use and consumption is granted to the properly possessors unless obligations of the Euratom Treaty oppose. Inherently, the community does not have these rights. It was asked what would be left to the owner Euratom if the properly possessor is entitled to unlimited right of use and even right of consumption.

  13. Room temperature Sieving of Hydrogen Isotopes Using 2-D Materials

    Energy Technology Data Exchange (ETDEWEB)

    Hitchcock, D. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Colon-Mercado, H. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Krentz, T. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Serkiz, S. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Velten, J. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Xiao, S. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

    2017-09-28

    Hydrogen isotope separation is critical to the DOE’s mission in environmental remediation and nuclear nonproliferation. Isotope separation is also a critical technology for the NNSA, and the ability to perform the separations at room temperature with a relatively small amount of power and space would be a major advancement for their respective missions. Recent work has shown that 2-D materials such as graphene and hexagonal boron nitride can act as an isotopic sieve at room temperature; efficiently separating hydrogen isotopes in water with reported separation ratios of 10:1 for hydrogen: deuterium separation for a single pass. The work performed here suggests that this technique has merit, and furthermore, we are investigating optimization and scale up of the required 2-D material based membranes.

  14. Introduction to chemistry and applications in nature of mass independent isotope effects special feature.

    Science.gov (United States)

    Thiemens, Mark H

    2013-10-29

    Stable isotope ratio variations are regulated by physical and chemical laws. These rules depend on a relation with mass differences between isotopes. New classes of isotope variation effects that deviate from mass dependent laws, termed mass independent isotope effects, were discovered in 1983 and have a wide range of applications in basic chemistry and nature. In this special edition, new applications of these effects to physical chemistry, solar system origin models, terrestrial atmospheric and biogenic evolution, polar paleo climatology, snowball earth geology, and present day atmospheric sciences are presented.

  15. Determination of zinc stable isotopes in biological materials using isotope dilution inductively coupled plasma mass spectrometry

    International Nuclear Information System (INIS)

    Patterson, K.Y.; Veillon, Claude

    1992-01-01

    A method is described for using isotope dilution to determine both the amount of natural zinc and enriched isotopes of zinc in biological samples. Isotope dilution inductively coupled plasma mass spectrometry offers a way to quantify not only the natural zinc found in a sample but also the enriched isotope tracers of zinc. Accurate values for the enriched isotopes and natural zinc are obtained by adjusting the mass count rate data for measurable instrumental biases. Analytical interferences from the matrix are avoided by extracting the zinc from the sample matrix using diethylammonium diethyldithiocarbamate. The extraction technique separates the zinc from elements which form interfering molecular ions at the same nominal masses as the zinc isotopes. Accuracy of the method is verified using standard reference materials. The detection limit is 0.06 μg Zn per sample. Precision of the abundance ratios range from 0.3-0.8%. R.S.D. for natural zinc concentrations is about 200-600 μg g -1 . The accuracy and precision of the measurements make it possible to follow enriched isotopic tracers of zinc in biological samples in metabolic tracer studies. (author). 19 refs.; 1 fig., 4 tabs

  16. Special nuclear material inventory sampling plans

    International Nuclear Information System (INIS)

    Vaccaro, H.; Goldman, A.

    1987-01-01

    Since their introduction in 1942, sampling inspection procedures have been common quality assurance practice. The U.S. Department of Energy (DOE) supports such sampling of special nuclear materials inventories. The DOE Order 5630.7 states, Operations Offices may develop and use statistically valid sampling plans appropriate for their site-specific needs. The benefits for nuclear facilities operations include reduced worker exposure and reduced work load. Improved procedures have been developed for obtaining statistically valid sampling plans that maximize these benefits. The double sampling concept is described and the resulting sample sizes for double sample plans are compared with other plans. An algorithm is given for finding optimal double sampling plans that assist in choosing the appropriate detection and false alarm probabilities for various sampling plans

  17. Hydrogen isotopes transport parameters in fusion reactor materials

    International Nuclear Information System (INIS)

    Serra, E.; Ogorodnikova, O.V.

    1998-01-01

    This work presents a review of hydrogen isotopes-materials interactions in various materials of interest for fusion reactors. The relevant parameters cover mainly diffusivity, solubility, trap concentration and energy difference between trap and solution sites. The list of materials includes the martensitic steels (MANET, Batman and F82H-mod.), beryllium, aluminium, beryllium oxide, aluminium oxide, copper, tungsten and molybdenum. Some experimental work on the parameters that describe the surface effects is also mentioned. (orig.)

  18. Developing Potential New Reference Materials for Light Isotopes in Foodstuffs

    Science.gov (United States)

    Frew, Russell; Van Hale, Robert; Clarke, Dianne; Abrahim, Aiman; Resch, Christian; Mayr, Leopold; Cannavan, Andrew; Gröning, Manfred

    2013-04-01

    Measurements of subtle variations in stable isotope ratios provide the means for verifying food integrity in numerous ways. Adulterants usually have different isotopic composition so their presence in a food is readily detectable. Stable isotope measurements can also be used to determine the region of production of the food. In most cases the ability of stable isotope measurements to verify, or otherwise reject, the authenticity of the food is greatly enhanced by comparison of a result to a reference database. The more high-quality data in the database, the more statistical power is afforded by the comparison. A serious weakness at present is the lack of reference materials in food matrices available to the community. Thus researchers have to rely on in-house standards for calibration and quality assurance. The result is that there are numerous datasets published that may be internally consistent but it is exceedingly difficult to combine these datasets into a cohesive database. This is particularly important for measurements of the hydrogen isotopes. Here we present a survey of the stable isotope (^2H, ^13C and ^15N) composition of 12 Reference Materials from the International Atomic Energy Agency catalogue. All but one of these materials are plant matter and have been developed as reference materials for other applications such as radionuclide or trace element measurements. Thus they have been verified as suitable materials in terms of stability and homogeneity for those tests. The purpose of this work is to ascertain if they are similarly suitable as stable isotope reference materials. The results from our survey show that there is a wide range in elemental and isotopic composition among these materials. For example, the ^15N values range from-13.5‰ to +18.6‰ and the nitrogen elemental composition range is from 0.7% to 9.7%. The ^13C values range from -20‰ to -40‰ and the carbon elemental composition ranges from 15% to 47%. We are now in the process of

  19. U.S. N.R.C. special safeguards study on nuclear material control and accounting

    International Nuclear Information System (INIS)

    Smith, G.D.

    1976-01-01

    In Feb. 1975, NRC directed that an effort be made to determine a safeguards program for Pu recycle. This paper summarizes results of individual contractor evaluations of upgrading material control and accounting concepts as applied to strategically important special nuclear material and describes staff interpretations of these results as applied to future high-throughput fuel-cycle facilities. Real-time material control, design for physical inventory, Pu isotopics control and calorimetry, and material control and accounting for highly enriched uranium fuel materials were the concepts studied. 1 table, 15 references

  20. Requirements for the special examination of isotope diagnostic specialists

    International Nuclear Information System (INIS)

    Csakany, Gyoergy

    1986-01-01

    Isotope diagnostic specialists are required to possess general paraclinical knowledge about nuclear physical principles, basic radiological measuring methods including up-to-date ones such as scintiscanning and tomography, as well as about radiopharmacology, radiation biology, health physics, radiation protection and organizational and economic aspects of the examinations. Clinical isotope diagnostic requirements comprise the proper selection among different radiological methods, the correct application of certain diagnostic procedures in practise, and the evaluation of the results in accordance with the symptoms on various fields of medical science. (V.N.)

  1. Preparation, characterization and certification of uranium isotope reference materials

    International Nuclear Information System (INIS)

    Oliveira Junior, Olivio Pereira de

    2006-01-01

    This work describes the preparation, characterization and certification of a set of uranium isotope reference materials ranging from 0.5 to 20.0 % of 235 U in mass. The most important concepts of metrology in chemical measurements were applied so that the certified quantities in these materials could be directly traceable to the International System of Units (SI). As a consequence of this approach, these materials can be used in the instruments calibration, estimation of measurement uncertainty, method validation, assessment of performance of analysts, quality control routines and interlaboratory comparison programmes. The most advanced methods and techniques in mass spectrometry, that is, gas source mass spectrometry (GSMS), thermal ionisation mass spectrometry (TIMS) and inductively coupled plasma mass spectrometry (ICPMS) were investigated to identify which are the dominant components in the uncertainty and to quantify its contribution to the final value of the measurement uncertainty of the isotopic ratio. The results obtained were then compared to verify which are the methods and techniques associated to the lowest measurement uncertainty values. The isotope amount ratio n( 235 U)/n( 238 U) was certified in the materials produced to expanded uncertainties ranging from 0.02 to 0.10 % and the ratios n( 234 U)/n( 238 U) and n( 236 U)/n( 238 U), to uncertainties ranging from 0.03 to 2.20 %. These values fully comply to the requirements of the isotopic characterization of nuclear fuel as well as the analysis of environmental samples for nuclear safeguards. (author)

  2. Preparation of isotopic molybdenum foils utilizing small quantities of material

    Science.gov (United States)

    Lipski, A. R.; Lee, L. L.; Liang, J. F.; Mahon, J. C.

    1993-09-01

    A simple method utilizing a small amount of isotopic material for production of molybdenum foils is discussed. An e-gun is used in the procedure. The Mo powder undergoes reduction-sintering and melting-solidifying steps leading to the creation of a metallic droplet suitable for further cold rolling or vacuum deposition.

  3. A specialized isotope mass spectrometer for noninvasive diagnostics of Helicobacter pylori infection in human beings

    Science.gov (United States)

    Blashenkov, N. M.; Sheshenya, E. S.; Solov'ev, S. M.; Sachenko, V. D.; Gall, L. N.; Zarutskii, I. V.; Gall, N. R.

    2013-05-01

    A specialized isotope mass spectrometer for noninvasive diagnostics of Helicobacter pylori infection in human beings based on the carbon-13 isotope breath test has been designed and constructed. Important stages of the work included (i) calculating a low-aberration mass analyzer, (ii) manufacturing and testing special gas inlet system, and (iii) creating a small-size collector of ions. The proposed instrument ensures 13C/12C isotopic ratio measurement to within 1.7‰ (pro mille) accuracy, which corresponds to requirements for a diagnostic tool. Preliminary medical testing showed that the mass spectrometer is applicable to practical diagnostics. The instrument is also capable of measuring isotopic ratios of other light elements, including N, O, B (for BF2+ ions), Ar, Cl, and S.

  4. Cadmium isotope fractionation of materials derived from various industrial processes

    Energy Technology Data Exchange (ETDEWEB)

    Martinková, Eva, E-mail: eva.cadkova@geology.cz [Czech Geological Survey, Geologická 6, 152 00 Prague 5 (Czech Republic); Chrastný, Vladislav, E-mail: chrastny@fzp.czu.cz [Faculty of Environmental Sciences, Czech University of Life Sciences Prague, Kamýcká 129, 165 21 Prague 6 (Czech Republic); Francová, Michaela, E-mail: michaela.francova@fzp.czu.cz [Faculty of Environmental Sciences, Czech University of Life Sciences Prague, Kamýcká 129, 165 21 Prague 6 (Czech Republic); Šípková, Adéla, E-mail: adela.sipkova@geology.cz [Czech Geological Survey, Geologická 6, 152 00 Prague 5 (Czech Republic); Čuřík, Jan, E-mail: jan.curik@geology.cz [Czech Geological Survey, Geologická 6, 152 00 Prague 5 (Czech Republic); Myška, Oldřich, E-mail: oldrich.myska@geology.cz [Czech Geological Survey, Geologická 6, 152 00 Prague 5 (Czech Republic); Mižič, Lukáš, E-mail: lukas.mizic@geology.cz [Czech Geological Survey, Geologická 6, 152 00 Prague 5 (Czech Republic)

    2016-01-25

    Highlights: • All studied industrial processes were accompanied by Cd isotope fractionation. • ϵ{sup 114/110} Cd values of the waste materials were discernible from primary sources. • Technology in use plays an important role in Cd isotope fractionation. - Abstract: Our study represents ϵ{sup 114/110} Cd {sub NIST3108} values of materials resulting from anthropogenic activities such as coal burning, smelting, refining, metal coating, and the glass industry. Additionally, primary sources (ore samples, pigment, coal) processed in the industrial premises were studied. Two sphalerites, galena, coal and pigment samples exhibited ϵ{sup 114/110} Cd{sub NIST3108} values of 1.0 ± 0.2, 0.2 ± 0.2, 1.3 ± 0.1, −2.3 ± 0.2 and −0.1 ± 0.3, respectively. In general, all studied industrial processes were accompanied by Cd isotope fractionation. Most of the industrial materials studied were clearly distinguishable from the samples used as a primary source based on ϵ{sup 114/110} Cd {sub NIST3108} values. The heaviest ϵ{sup 114/110} Cd{sub NIST3108} value of 58.6 ± 0.9 was found for slag resulting from coal combustion, and the lightest ϵ{sup 114/110} Cd{sub NIST3108} value of −23 ± 2.5 was observed for waste material after Pb refinement. It is evident that ϵ{sup 114/110} Cd {sub NIST3108} values depend on technological processes, and in case of incomplete Cd transfer from source to final waste material, every industrial activity creates differences in Cd isotope composition. Our results show that Cd isotope analysis is a promising tool to track the origins of industrial waste products.

  5. Nuclear material safeguards surveillance and accountancy by isotope correlation techniques

    International Nuclear Information System (INIS)

    Persiani, P.J.; Goleb, J.A.; Kroc, T.K.

    1981-11-01

    The purpose of this study is to investigate the applicability of isotope correlation techniques (ICT) to the Light Water Reactor (LWR) and the Liquid Metal Fast Breeder Reactor (LMFBR) fuel cycles for nuclear material accountancy and safeguards surveillance. The isotopic measurement of the inventory input to the reprocessing phase of the fuel cycle is the primary direct determination that an anomaly may exist in the fuel management of nuclear material. The nuclear materials accountancy gap which exists between the fabrication plant output and the input to the reprocessing plant can be minimized by using ICT at the dissolver stage of the reprocessing plant. The ICT allows a level of verification of the fabricator's fuel content specifications, the irradiation history, the fuel and blanket assemblies management and scheduling within the reactor, and the subsequent spent fuel assembly flows to the reprocessing plant. The investigation indicates that there exist relationships between isotopic concentration which have predictable, functional behavior over a range of burnup. Several cross-correlations serve to establish the initial core assembly-averaged composition. The selection of the more effective functionals will depend not only on the level of reliability of ICT for verification, but also on the capability, accuracy and difficulty of developing measurement methods. The propagation of measurement errors on the correlation functions and respective sensitivities to isotopic compositional changes have been examined and found to be consistent with current measurement methods

  6. Development of the NBS beryllium isotopic standard reference material

    International Nuclear Information System (INIS)

    Inn, K.G.W; Fassett, J.D.; Coursey, B.M.; Walker, R.L.; Raman, S.

    1987-01-01

    The National Bureau of Standards, in conjunction with the Oak Ridge National Laboratory and the Accelerator Mass Spectrometry community, is in the process of developing a beryllium isotopic solution Standard Reference Material. The master 10 Be/ 9 Be solution was characterized isotopically by resonance-ionization and secondary-ion mass-spectrometric-based techniques, and radioactivity measurements were by liquid scintillation counting. The master solution was gravimetrically diluted with 9 Be to a final 10 Be/ 9 Be atomic ratio of 3 x 10 -11 . The preliminary data indicate a half life for 10 Be of 1.3 million years, and AMS measurements are within 10% of the known beryllium isotopic ratio

  7. 10 CFR 74.51 - Nuclear material control and accounting for strategic special nuclear material.

    Science.gov (United States)

    2010-01-01

    ... 10 Energy 2 2010-01-01 2010-01-01 false Nuclear material control and accounting for strategic special nuclear material. 74.51 Section 74.51 Energy NUCLEAR REGULATORY COMMISSION (CONTINUED) MATERIAL CONTROL AND ACCOUNTING OF SPECIAL NUCLEAR MATERIAL Formula Quantities of Strategic Special Nuclear...

  8. Some political issues related to future special nuclear materials production

    International Nuclear Information System (INIS)

    Peaslee, A.T. Jr.

    1981-08-01

    The Federal Government must take action to assure the future adequate supply of special nuclear materials for nuclear weapons. Existing statutes permit the construction of advanced defense production reactors and the reprocessing of commercial spent fuel for the production of special materials. Such actions would not only benefit the US nuclear reactor manufacturers, but also the US electric utilities that use nuclear reactors

  9. Alloy-steel bolting materials for special applications

    International Nuclear Information System (INIS)

    Anon.

    1981-01-01

    This specification covers regular and special-quality alloy steel bolting materials which may be used for nuclear and other special applications. Bolting materials as used in the specification cover rolled or forged bars, rotary pierced or extruded seamless tubes, bored bars, or forged hollows from forged or rolled bar segments to be machined into bolts, studs, washers, and nuts. Several grades of steel are covered and supplementary requirements of an optional nature are provided for use when special quality is desired

  10. Special requirements for bolting material for nuclear and other special applications

    International Nuclear Information System (INIS)

    Anon.

    1981-01-01

    A specification that provides special requirements for bolting material for use in nuclear and other special applications is presented. The requirements of the specification are supplemental to the requirements of the basic material specifications and they include tempering, welding, elimination of surface defects, certification and identification, quality assurance and various examination methods

  11. Isotope correlation verification of analytical measurements for dissolver materials

    International Nuclear Information System (INIS)

    Satkowski, J.

    1988-01-01

    An independent verification of analytical results for accountability measurements of dissolver materials can be performed using the Iosotop Correlation Technique (ICT). ICT is based on the relationships that exist between the initial and final elemental concentration and isotopic abundances of the nuclear fuel. Linear correlation functions between isotopic ratios and plutonium/uranium ratios have been developed for specific reactor fuels. The application of these correlations to already existing analytical data provides a laboratory additional confidence in the reported results. Confirmation is done by a test of consistancy with historical data. ICT is being utilized with dissolver accountability measurements at the Savannah River Plant Laboratory. The application, implementation, and operating experience of this technique are presented

  12. Special metals - materials of modern technology

    International Nuclear Information System (INIS)

    Booss, H.J.

    1977-01-01

    This article is anether attempt to give a survey of special metals, their production, processing and application, as has been made in four previous articles. The article confines itself essentially to publications made in 12 German and 12 English journals, focussed on metallurgy, metallography, electrochemistry, and sections of electrical engineering. For the first time, some articles written in Russian have been included. (orig./IHOE) [de

  13. New Carbonate Standard Reference Materials for Boron Isotope Geochemistry

    Science.gov (United States)

    Stewart, J.; Christopher, S. J.; Day, R. D.

    2015-12-01

    The isotopic composition of boron (δ11B) in marine carbonates is well established as a proxy for past ocean pH. Yet, before palaeoceanographic interpretation can be made, rigorous assessment of analytical uncertainty of δ11B data is required; particularly in light of recent interlaboratory comparison studies that reported significant measurement disagreement between laboratories [1]. Well characterised boron standard reference materials (SRMs) in a carbonate matrix are needed to assess the accuracy and precision of carbonate δ11B measurements throughout the entire procedural chemistry; from sample cleaning, to ionic separation of boron from the carbonate matrix, and final δ11B measurement by multi-collector inductively coupled plasma mass spectrometry. To date only two carbonate reference materials exist that have been value-assigned by the boron isotope measurement community [2]; JCp-1 (porites coral) and JCt-1 (Giant Clam) [3]. The National Institute of Standards and Technology (NIST) will supplement these existing standards with new solution based inorganic carbonate boron SRMs that replicate typical foraminiferal and coral B/Ca ratios and δ11B values. These new SRMs will not only ensure quality control of full procedural chemistry between laboratories, but have the added benefits of being both in abundant supply and free from any restrictions associated with shipment of biogenic samples derived from protected species. Here we present in-house δ11B measurements of these new boron carbonate SRM solutions. These preliminary data will feed into an interlaboratory comparison study to establish certified values for these new NIST SRMs. 1. Foster, G.L., et al., Chemical Geology, 2013. 358(0): p. 1-14. 2. Gutjahr, M., et al., Boron Isotope Intercomparison Project (BIIP): Development of a new carbonate standard for stable isotopic analyses. Geophysical Research Abstracts, EGU General Assembly 2014, 2014. 16(EGU2014-5028-1). 3. Inoue, M., et al., Geostandards and

  14. Control of Nuclear Materials and Special Equipment (Nuclear Safety Regulations)

    International Nuclear Information System (INIS)

    Cizmek, A.; Prah, M.; Medakovic, S.; Ilijas, B.

    2008-01-01

    Based on Nuclear Safety Act (OG 173/03) the State Office for Nuclear Safety (SONS) in 2008 adopted beside Ordinance on performing nuclear activities (OG 74/06) and Ordinance on special conditions for individual activities to be performed by expert organizations which perform activities in the area of nuclear safety (OG 74/06) the new Ordinance on the control of nuclear material and special equipment (OG 15/08). Ordinance on the control of nuclear material and special equipment lays down the list of nuclear materials and special equipment as well as of nuclear activities covered by the system of control of production of special equipment and non-nuclear material, the procedure for notifying the intention to and filing the application for a license to carry out nuclear activities, and the format and contents of the forms for doing so. This Ordinance also lays down the manner in which nuclear material records have to be kept, the procedure for notifying the State administration organization (regulatory body) responsible for nuclear safety by the nuclear material user, and the keeping of registers of nuclear activities, nuclear material and special equipment by the State administration organization (regulatory body) responsible for nuclear safety, as well as the form and content of official nuclear safety inspector identification card and badge.(author)

  15. Report on strategic special nuclear material inventory differences

    International Nuclear Information System (INIS)

    1977-08-01

    Information concerning accounting for significant quantities of strategic special nuclear material (SSNM) in ERDA facilities is reported. Inventory difference data are provided for fiscal year 1976 for ERDA and ERDA contractor facilities that possessed significant quantities of SSNM

  16. Preparation and use of nitrogen (2) oxide of special purity for production of oxygen and nitrogen isotopes

    International Nuclear Information System (INIS)

    Polevoj, A.S.

    1989-01-01

    Problems related with production of oxygen and nitrogen isotopes by means of low-temperature rectification of nitrogen (2) oxide are analyzed. Special attention, in particular, is payed to the techniques of synthesis and high purification of initial NO, utilization of waste flows formed during isotope separation. Ways to affect the initial isotope composition of nitrogen oxide and the rate of its homogeneous-isotope exchange, which provide for possibility of simultaneous production of oxygen and nitrogen isotopes by means of NO rectification, are considered. Description of a new technique for high purification of nitrogen oxide, prepared at decomposition of nitric acid by sulfurous anhydride, suggested by the author is presented

  17. Using stable isotopes to investigate individual diet specialization in California sea otters (Enhydra lutris nereis)

    Science.gov (United States)

    Newsome, S.D.; Tinker, M.T.; Monson, Daniel H.; Oftedal, O.T.; Ralls, K.; Staedler, M.M.; Fogel, M.L.; Estes, J.A.

    2009-01-01

    Differences in diet composition among conspecifics (dietary specialization) have been documented across a broad range of taxonomic groups and habitats, and such variation at the individual level is increasingly recognized as an important component of diversity in trophic interactions. Accurate identification of individual dietary specialization, however, requires longitudinal dietary records that are labor-intensive and cost-prohibitive to obtain for many species. Here we explore the use of stable isotopes (δ13C and δ15N) as a promising technique for detecting and quantifying patterns of individual dietary specialization. Southern sea otters (Enhydra lutris nereis) offer a unique opportunity for testing this approach because (1) they consume a wide variety of prey that span multiple trophic levels, habitats, and ecologically defined functional groups; and (2) individual diet specialization can be validated with existing observational data. We analyzed the isotopic composition of sea otter vibrissae (n = 31) in order to characterize inter- and intra-individual variation in sea otter diets at Monterey Bay, California, USA. At the population level, sea otters showed substantial variation in both δ13C and δ15N values, occupying nearly all of the “isotopic space” created by the diversity of isotopic signatures of potential prey taxa. Most of the variation in sea otter vibrissae was accounted for by differences between individuals, with much less contributed by within-individual variation. A majority of sea otters (∼80%) showed relatively little temporal variability in isotopic composition, suggesting that the proportional composition of most individuals' diets is relatively constant over time; a few individuals (∼20%) exhibited a high degree of intra-vibrissa isotopic variability, suggesting seasonal shifts in diet composition. These results and our interpretation of them were supported by long-term observational data on the diets of radio-tagged sea otters

  18. General and special engineering materials science. Vol. 1

    International Nuclear Information System (INIS)

    Ondracek, G.; Voehringer, O.

    1983-04-01

    The present report about general and special engineering materials science is the result of lectures given by the authors in two terms in 1982 at Instituto Balseiro, San Carlos de Bariloche, the graduated college of the Universidad de Cuyo and Comision Nacional de Energia Atomica, Republica Argentina. These lectures were organised in the frame of the project ''nuclear engineering'' (ARG/78/020) of the United Nations Development Program (UNDP) by the International Atomic Energy Agency (IAEA). Some chapters of the report are written in English, others in Spanish. The report is subdivided into three volumes: Volume I treats general engineering materials science in 4 capital chapters on the structure of materials, the properties of materials, materials technology and materials testing and investigation supplemented by a selected detailed chapter about elasticity plasticity and rupture mechanics. Volume II concerns special engineering materials science with respect to nuclear materials under normal reactor operation conditions including reactor clad and structural materials, nuclear fuels and fuel elements and nuclear waste as a materials viewpoint. Volume III - also concerning special engineering materials science - considers nuclear materials with respect to off-normal (''accident'') reactor operation conditions including nuclear materials in loss-of-coolant accidents and nuclear materials in core melt accidents. (orig.) [de

  19. Molten salt processes in special materials preparation

    International Nuclear Information System (INIS)

    Krishnamurthy, N.; Suri, A.K.

    2013-01-01

    As a class, molten salts are the largest collection of non aqueous inorganic solvents. On account of their stability at high temperature and compatibility to a number of process requirements, molten salts are considered indispensable to realize many of the numerous benefits of high temperature technology. They play a crucial role and form the basis for numerous elegant processes for the preparation of metals and materials. Molten salt are considered versatile heat transfer media and have led to the evolution of many interesting reactor concepts in fission and possibly in fusion. They also have been the basis of thinking for few novel processes for power generation. While focusing principally on the actual utilization of molten salts for a variety of materials preparation efforts in BARC, this lecture also covers a few of the other areas of technological applications together with the scientific basis for considering the molten salts in such situations. (author)

  20. Optoelectronic inventory system for special nuclear material

    International Nuclear Information System (INIS)

    Sieradzki, F.H.

    1994-01-01

    In support of the Department of Energy's Dismantlement Program, the Optoelectronics Characterization and Sensor Development Department 2231 at Sandia National Laboratories/New Mexico has developed an in situ nonintrusive Optoelectronic Inventory System (OIS) that has the potential for application wherever periodic inventory of selected material is desired. Using a network of fiber-optic links, the OIS retrieves and stores inventory signatures from data storage devices (which are permanently attached to material storage containers) while inherently providing electromagnetic pulse immunity and electrical noise isolation. Photovoltaic cells (located within the storage facility) convert laser diode optic power from a laser driver to electrical energy. When powered and triggered, the data storage devices sequentially output their digital inventory signatures through light-emitting diode/photo diode data links for retrieval and storage in a mobile data acquisition system. An item's exact location is determined through fiber-optic network and software design. The OIS provides an on-demand method for obtaining acceptable inventory reports while eliminating the need for human presence inside the material storage facility. By using modularization and prefabricated construction with mature technologies and components, an OIS installation with virtually unlimited capacity can be tailored to the customer's requirements

  1. Special Purpose Materials annual progress report, October 1, 1979

    International Nuclear Information System (INIS)

    1980-04-01

    The scope of Special Purpose Materials covers fusion reactor materials problems other than the first-wall and blanket structural materials, which are under the purview of the ADIP, DAFS, and PMI task groups. Components that are considered as special purpose materials include breeding materials, coolants, neutron multipliers, barriers for tritium control, materials for compression and OH coils and waveguides, graphite and SiC, heat-sink materials, ceramics, and materials for high-field (> 10-T) superconducting magnets. It is recognized that there will be numerous materials problems that will arise during the design and construction of large magnetic-fusion energy devices such as the Engineering Test Facility (ETF) and Demonstration Reactor (DEMO). Most of these problems will be specific to a particular design or project and are the responsibility of the project, not the Materials and Radiation Effects Branch. Consequently, the Task Group on Special Purpose Materials has limited its concern to crucial and generic materials problems that must be resolved if magnetic-fusion devices are to succeed. Important areas specifically excluded include low-field (8-T) superconductors, fuels for hybrids, and materials for inertial-confinement devices. These areas may be added in the future when funding permits

  2. Enviromental Development Plan: special nuclear materials production

    International Nuclear Information System (INIS)

    1980-07-01

    This Environmental Development Plan includes the process steps and facilities necessary for the production of plutonium and tritium for Government needs and the production of some other radioactive materials that will be used for heat and radiation sources by domestic and international customers. The production reactors and the spent fuel processing plants and their effluents are discussed, but the defense wastes from them are treated in a separate EDP. The scope does not include transportation, decontamination and decommissioning, safeguards and security, or use of the SNM products

  3. Specialized equipment needs for the transportation of radioactive material

    International Nuclear Information System (INIS)

    Condrey, D.; Lambert, M.

    1998-01-01

    To ensure the safe and reliable transportation of radioactive materials and components, from both the front and back-end of the nuclear fuel cycle, a transport management company needs three key elements: specialized knowledge, training and specialized equipment. These three elements result, in part, from national and international regulations which require specialized handling of all radioactive shipments. While the reasons behind the first two elements are readily apparent, the role of specialized equipment is often not considered until too late shipment process even though it plays an integral part of any radioactive material transport. This paper will describe the specialized equipment needed to transport three of the major commodities comprising the bulk of international nuclear transports: natural uranium (UF6), low enriched uranium (UF6) and fresh nuclear fuel. (authors)

  4. Microchannel plate special nuclear materials sensor

    International Nuclear Information System (INIS)

    Feller, W.B.; White, P.L.; White, P.B.; Siegmund, O.H.W.; Martin, A.P.; Vallerga, J.V.

    2011-01-01

    Nova Scientific Inc., is developing for the Domestic Nuclear Detection Office (DNDO SBIR no. HSHQDC-08-C-00190), a solid-state, high-efficiency neutron detection alternative to 3 He gas tubes, using neutron-sensitive microchannel plates (MCPs) containing 10 B and/or Gd. This work directly supports DNDO development of technologies designed to detect and interdict nuclear weapons or illicit nuclear materials. Neutron-sensitized MCPs have been shown theoretically and more recently experimentally, to be capable of thermal neutron detection efficiencies equivalent to 3 He gas tubes. Although typical solid-state neutron detectors typically have an intrinsic gamma sensitivity orders of magnitude higher than that of 3 He gas detectors, we dramatically reduce gamma sensitivity by combining a novel electronic coincidence rejection scheme, employing a separate but enveloping gamma scintillator. This has already resulted in a measured gamma rejection ratio equal to a small 3 He tube, without in principle sacrificing neutron detection efficiency. Ongoing improvements to the MCP performance as well as the coincidence counting geometry will be described. Repeated testing and validation with a 252 Cf source has been underway throughout the Phase II SBIR program, with ongoing comparisons to a small commercial 3 He gas tube. Finally, further component improvements and efforts toward integration maturity are underway, with the goal of establishing functional prototypes for SNM field testing.

  5. Sample preparation techniques of biological material for isotope analysis

    International Nuclear Information System (INIS)

    Axmann, H.; Sebastianelli, A.; Arrillaga, J.L.

    1990-01-01

    Sample preparation is an essential step in all isotope-aided experiments but often it is not given enough attention. The methods of sample preparation are very important to obtain reliable and precise analytical data and for further interpretation of results. The size of a sample required for chemical analysis is usually very small (10mg-1500mg). On the other hand the amount of harvested plant material from plots in a field experiment is often bulky (several kilograms) and the entire sample is too large for processing. In addition, while approaching maturity many crops show not only differences in physical consistency but also a non-uniformity in 15 N content among plant parts, requiring a plant fractionation or separation into parts (vegetative and reproductive) e.g. shoots and spikes, in case of small grain cereals, shoots and pods in case of grain legumes and tops and roots or beets (including crown) in case of sugar beet, etc. In any case the ultimate goal of these procedures is to obtain representative subsample harvested from greenhouse or field experiments for chemical analysis. Before harvesting an isotopic-aided experiment the method of sampling has to be selected. It should be based on the type of information required in relation to the objectives of the research and the availability of resources (staff, sample preparation equipment, analytical facilities, chemicals and supplies, etc.). 10 refs, 3 figs, 3 tabs

  6. Special Issue: NextGen Materials for 3D Printing

    Directory of Open Access Journals (Sweden)

    Chee Kai Chua

    2018-04-01

    Full Text Available Only a handful of materials are well-established in three-dimensional (3D printing and well-accepted in industrial manufacturing applications. However, recent advances in 3D printable materials have shown potential for enabling numerous novel applications in the future. This special issue, consisting of 2 reviews and 10 research articles, intends to explore the possible materials that could define next-generation 3D printing.

  7. Annual report on strategic special nuclear material inventory differences

    International Nuclear Information System (INIS)

    1991-01-01

    This report of unclassified Inventory Difference (ID's) covers the twelve months from April 1, 1989 through March 31, 1990 for all key Department of Energy (DOE) and DOE contractor operated facilities possessing strategic special nuclear material. Classified information is not included in this report. This classified information includes data for the Rocky Flats and Y-12 nuclear weapons production facilities or facilities under ID investigation. However, classified ID data from such facilities receive the same scrutiny and analyses was the included data. The data in this report have been prepared and reviewed by DOE contractors, field offices, and Headquarters. When necessary, special investigations have been performed in addition to these reviews: This ID data, explanations, reviews, and any additional special investigations, together with the absence of physical indications of any theft attempt, support a finding that no theft or diversion of significant quantities of strategic special nuclear material has occurred in DOE facilities during the twelve-month period covered by this report

  8. General and special engineering materials science. Vol. 3

    International Nuclear Information System (INIS)

    Ondracek, G.; Hofmann, P.

    1983-04-01

    The report about general and special engineering materials science is the result of lectures given by the authors in two terms in 1982 at Instituto Balseiro, San Carlos de Bariloche, the graduated college of the Universidad de Cuyo and Comision Nacional de Energia Atomica, Republica Argentina. These lectures were organised in the frame of the project ''nuclear engineering'' (ARG/78/020) of the United Nations Development Program (UNDP) by the International Atomic Energy Agency (IAEA). Some chapters of the report are written in English, others in Spanish. The report is subdivided into three volumes. The present volume III concerns special engineering materials science and considers nuclear materials with respect to off-normal (''accident'') reactor operation conditions including nuclear materials in loss-of-coolant accident and nuclear materials in core melt accidents. (orig./IHOE) [de

  9. General and special engineering materials science. Vol. 2

    International Nuclear Information System (INIS)

    Anderko, K.; Kummerer, K.R.; Ondracek, G.

    1983-04-01

    The present report about general and special engineering materials science is the result of lectures given by the authors in two terms in 1982 at Instituto Balseiro, San Carlos de Bariloche, the graduated college of the Universidad de Cuyo and Comision Nacional de Energia Atomica, Republica Argentina. These lectures were organised in the frame of the project ''nuclear engineering'' (ARG/78/020) of the United Nations Development Program (UNDP) by the International Atomic Energy Agency (IAEA). Some chapters of the report are written in English, others in Spanish. The report is subdivided into three volumes. The present volume II concerns special engineering materials science with respect to nuclear materials under normal reactor operation conditions including 1. reactor clad and structural materials, 2. nuclear fuels and fuel elements, 3. nuclear waste as a materials viewpoint. (orig./IHOE) [de

  10. Active neutron technique for detecting attempted special nuclear material diversion

    International Nuclear Information System (INIS)

    Smith, G.W.; Rice, L.G. III.

    1979-01-01

    The identification of special nuclear material (SNM) diversion is necessary if SNM inventory control is to be maintained at nuclear facilities. (Special nuclear materials are defined for this purpose as either 235 U of 239 Pu.) Direct SNM identification by the detection of natural decay or fission radiation is inadequate if the SNM is concealed by appropriate shielding. The active neutron interrogation technique described combines direct SNM identification by delayed fission neutron (DFN) detection with implied SNM detection by the identification of materials capable of shielding SNM from direct detection. This technique is being developed for application in an unattended material/equipment portal through which items such as electronic instruments, packages, tool boxes, etc., will pass. The volume of this portal will be 41-cm wide, 53-cm high and 76-cm deep. The objective of this technique is to identify an attempted diversion of at least 20 grams of SNM with a measurement time of 30 seconds

  11. Materials technology for accelerator production of fissile isotopes

    International Nuclear Information System (INIS)

    Horak, J.A.

    1978-02-01

    The materials used for the accelerator production of fissile isotopes must enable the facility to achieve maximum fuel production at a minimum cost. Neutron production in the target would be maximized by use of thorium cooled with Pb--56 percent Bi or with sodium. The thorium should be ion-plated with approximately 1 mil of nickel or stainless steel for retention of fission products. The target container will have to be replaced at frequent intervals because of the copious quantities of neutronically produced helium and hydrogen in the container. Replacement would coincide with shutdown of the facility for the removal of the fissile material produced. If sodium is used to cool both the target and fertile blanket, a simple basket-type target container could be used. This would greatly reduce radiation effects in the target container. Type 316 stainless steel or V--20 wt percent Ti should perform satisfactorily as a target container. The fertile blanket should be 233 Th or 238 U that is coated with approximately 1 mil of nickel or stainless steel and cooled with sodium. The blanket container could be an austenitic stainless steel such as type 304 or 316; some ferritic alloys may also provide a satisfactory blanket container. 31 references

  12. Seismic analysis procedures for the plutonium processing building of the Special Isotope Separation Plant

    International Nuclear Information System (INIS)

    Chen, C.P.; Tajirian, F.F.; Todeschini, R.A.A.; Dahlke, H.J.

    1989-01-01

    This paper describes the methodology for the seismic soil-structure interaction (SSI) analysis of the Plutonium Processing Building (PPB) which is part of the Special Isotope Separation (SIS) Production Plant. The PPB consists of two structures, the enclosure building and the optics/separator area. These are founded on two independent foundations which are supported on the surface of a soil medium consisting of gravel overlying basalt. The PPB is classified as a safety related structure and is required to withstand the effects of a Design Basis Earthquake (DBE)

  13. [Preface for special issue on bio-based materials (2016)].

    Science.gov (United States)

    Weng, Yunxuan

    2016-06-25

    Bio-based materials are new materials or chemicals with renewable biomass as raw materials such as grain, legume, straw, bamboo and wood powder. This class of materials includes bio-based polymer, biobased fiber, glycotechnology products, biobased rubber and plastics produced by biomass thermoplastic processing and basic biobased chemicals, for instance, bio-alcohols, organic acids, alkanes, and alkenes, obtained by bio-synthesis, bio-processing and bio-refinery. Owing to its environmental friendly and resource conservation, bio-based materials are becoming a new dominant industry taking the lead in the world scientific and technological innovation and economic development. An overview of bio-based materials development is reported in this special issue, and the industrial status and research progress of the following aspects, including biobased fiber, polyhydroxyalkanoates, biodegradable mulching film, bio-based polyamide, protein based biomedical materials, bio-based polyurethane, and modification and processing of poly(lactic acid), are introduced.

  14. Active and Passive Diagnostic Signatures of Special Nuclear Materials

    Energy Technology Data Exchange (ETDEWEB)

    Myers, William L. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Karpius, Peter Joseph [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Myers, Steven Charles [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2017-05-26

    An overview will be given discussing signatures associated with special nuclear materials acquired using both active and passive diagnostic techniques. Examples of how technology advancements have helped improve diagnostic capabilities to meet the challenges of today’s applications will be discussed.

  15. Assessment of international reference materials for isotope-ratio analysis (IUPAC Technical Report)

    Science.gov (United States)

    Brand, Willi A.; Coplen, Tyler B.; Vogl, Jochen; Rosner, Martin; Prohaska, Thomas

    2014-01-01

    Since the early 1950s, the number of international measurement standards for anchoring stable isotope delta scales has mushroomed from 3 to more than 30, expanding to more than 25 chemical elements. With the development of new instrumentation, along with new and improved measurement procedures for studying naturally occurring isotopic abundance variations in natural and technical samples, the number of internationally distributed, secondary isotopic reference materials with a specified delta value has blossomed in the last six decades to more than 150 materials. More than half of these isotopic reference materials were produced for isotope-delta measurements of seven elements: H, Li, B, C, N, O, and S. The number of isotopic reference materials for other, heavier elements has grown considerably over the last decade. Nevertheless, even primary international measurement standards for isotope-delta measurements are still needed for some elements, including Mg, Fe, Te, Sb, Mo, and Ge. It is recommended that authors publish the delta values of internationally distributed, secondary isotopic reference materials that were used for anchoring their measurement results to the respective primary stable isotope scale.

  16. 10 CFR 74.41 - Nuclear material control and accounting for special nuclear material of moderate strategic...

    Science.gov (United States)

    2010-01-01

    ... 10 Energy 2 2010-01-01 2010-01-01 false Nuclear material control and accounting for special nuclear material of moderate strategic significance. 74.41 Section 74.41 Energy NUCLEAR REGULATORY COMMISSION (CONTINUED) MATERIAL CONTROL AND ACCOUNTING OF SPECIAL NUCLEAR MATERIAL Special Nuclear Material...

  17. Stable isotope enrichment: Current and future potential

    International Nuclear Information System (INIS)

    Tracy, J.G.; Aaron, W.S.

    1992-01-01

    Oak Ridge National Laboratory (ORNL) operates the Isotope Enrichment Facility for the purpose of providing enriched stable isotopes, selected radioactive isotopes (including the actinides), and isotope-related materials and services for use in various research applications. ORNL is responsible for isotope enrichment and the distribution of approximately 225 nongaseous stable isotopes from 50 multi-isotopic elements. Many enriched isotope products are of prime importance in the fabrication of nuclear targets and the subsequent production of special radionuclides. State-of-the-art techniques to achieve special isotopic, chemical, and physical requirements are performed at ORNL This report describes the status and capabilities of the Isotope Enrichment Facility and the Isotope Research Materials Laboratory as well as emphasizing potential advancements in enrichment capabilities

  18. Stable isotope enrichment - current and future potential

    International Nuclear Information System (INIS)

    Tracy, J.G.; Aaron, W.S.

    1993-01-01

    Oak Ridge National Laboratory (ORNL) operates the Isotope Enrichment Facility for the purpose of providing enriched stable isotopes, selected radioactive isotopes (including the actinides), and isotope-related materials and services for use in various research applications. ORNL is responsible for isotope enrichment and the distribution of approximately 225 nongaseous stable isotopes from 50 multi-isotopic elements. Many enriched isotope products are of prime importance in the fabrication of nuclear targets and the subsequent production of special radionuclides. State-of-the-art techniques to achieve special isotopic, chemical, and physical requirements are performed at ORNL. This report describes the status and capabilities of the Isotope Enrichment Facility and the Isotope Research Materials Laboratory as well as emphasizing potential advancements in enrichment capabilities. (orig.)

  19. Environmental-impact appraisal related to special nuclear materials. License No. SNM-696; Docket No. 70-734

    International Nuclear Information System (INIS)

    1983-06-01

    This Environmental Impact Appraisal is issued by the US Nuclear Regulatory Commission in response to an application by GA Technologies, Inc., (GA) for renewal of Special Nuclear Material (SNM) License No. SNM-696 covering plant operations at San Diego, California. The proposed action provides for continuing research, development, and production activities involving SNM, uranium enriched in the U-235 and U-233 isotopes, and plutonium

  20. Nuclear material safeguards surveillance and accountancy by isotope correlation techniques

    International Nuclear Information System (INIS)

    Persiani, P.J.; Goleb, J.A.

    1981-01-01

    This paper presents the initial phase of the US study program and involves the computation of isotopic correlations for the LMFBR fuel cycle. The LWR fuel cycle phase of the study is currently in progress. The selection of the more safeguards effective functionals will depend not only on the level of reliability of isotope correlation technique (ICT) for verification, but also on the capability and difficulty of developing measurement methods. Performance characteristics of existing and proposed isotopic measurement techniques cover the general areas including assay and isotopic wet chemistry and NDA: (1) simultaneous multicomponent analysis techniques, (2) mass spectrometry, (3) x-ray fluorescence or densitometry with high flux monochromatic x-ray sources and high dispersion spectrometers, (4) passive and active neutron interrogation, (5) high level gamma-ray spectroscopy, (6) coulometry, and (7) potentiometry. The measurement capabilities and inherent limitations of these systems are to be evaluated in terms of total systems, operational mode, sample preparation requirements and consequent effect on dissolver solution representation, accuracy and precision estimates (if available), development status of the technique, and development requirements. The isotopic correlation technique shows considerable promise for use in verifying the initial isotopic composition and burnup of discharged assemblies based on the measured ratios of several key isotopes, obtained probably at the dissolver stage in reprocessing. This technique should, for example, easily be capable of indicating the exchange of a blanket assembly for a fuel assembly

  1. Methods of Verification, Accountability and Control of Special Nuclear Material

    International Nuclear Information System (INIS)

    Stewart, J.E.

    1999-01-01

    This session demonstrates nondestructive assay (NDA) measurement, surveillance and analysis technology required to protect, control and account (MPC and A) for special nuclear materials (SNM) in sealed containers. These measurements, observations and analyses comprise state-of-the art, strengthened, SNM safeguards systems. Staff member specialists, actively involved in research, development, training and implementation worldwide, will present six NDA verification systems and two software tools for integration and analysis of facility MPC and A data

  2. Physical protection of facilities and special nuclear materials in france

    International Nuclear Information System (INIS)

    Jeanpierre, G.

    1980-01-01

    Physical protection of nuclear facilities and special nuclear materials is subject in France to a national governmental regulation which provides for the basic principles to be taken into account and the minimal level of protection deemed necessary. But the responsibility of implementation is left to the facility management and the resulting decentralization allows for maximum efficiency. All safeguards measures comply with the commitments taken at the international level by the French government

  3. Isotope ratios of strontium and neodymium for characterizing earth mantle materials

    International Nuclear Information System (INIS)

    Brandt, S.B.; Lepin, V.S.; Maslovskaja, M.N.

    1985-01-01

    It is shown that the shares of mantle, crustal and sedimentary materials in rocks and ore deposits can be determined by isotope methods. Using Yakutian kimberlites as an example, mixing processes of mantle and crustal materials are illustrated with the aid of strontium isotopes. Due to the high sensitivity of strontium to hydrothermal effects, the combined use of neodymium and strontium isotopes is considered more appropriate to solve the problem of determining the share of mantle materials. This is demonstrated for rare earth minerals and alkaline rocks of Eastern Siberia and Mongolia. (author)

  4. The first Polish conference: Special glasses and amorphous materials. Introduction

    International Nuclear Information System (INIS)

    1993-01-01

    The present issue brings a collection of papers submitted to the 1. Polish Conference on special glasses and amorphous materials, held on June 1993 at the University of Mining and Metallurgy in Cracow. It was a survey of the research topics and attainments of the research teams working in this referring to the nature of the glassy state of the matter and the relation between glasses and other amorphous materials, properties of these materials as well as modern methods of their synthesis both at low and high temperatures. Some of the results presented at the Conference have already found application in industry. Here belong, among others, the works on optic fibres. Several new materials which have been recently elaborated may also find interesting and new practical application. (author)

  5. High-precision isotopic characterization of USGS reference materials by TIMS and MC-ICP-MS

    Science.gov (United States)

    Weis, Dominique; Kieffer, Bruno; Maerschalk, Claude; Barling, Jane; de Jong, Jeroen; Williams, Gwen A.; Hanano, Diane; Pretorius, Wilma; Mattielli, Nadine; Scoates, James S.; Goolaerts, Arnaud; Friedman, Richard M.; Mahoney, J. Brian

    2006-08-01

    The Pacific Centre for Isotopic and Geochemical Research (PCIGR) at the University of British Columbia has undertaken a systematic analysis of the isotopic (Sr, Nd, and Pb) compositions and concentrations of a broad compositional range of U.S. Geological Survey (USGS) reference materials, including basalt (BCR-1, 2; BHVO-1, 2), andesite (AGV-1, 2), rhyolite (RGM-1, 2), syenite (STM-1, 2), granodiorite (GSP-2), and granite (G-2, 3). USGS rock reference materials are geochemically well characterized, but there is neither a systematic methodology nor a database for radiogenic isotopic compositions, even for the widely used BCR-1. This investigation represents the first comprehensive, systematic analysis of the isotopic composition and concentration of USGS reference materials and provides an important database for the isotopic community. In addition, the range of equipment at the PCIGR, including a Nu Instruments Plasma MC-ICP-MS, a Thermo Finnigan Triton TIMS, and a Thermo Finnigan Element2 HR-ICP-MS, permits an assessment and comparison of the precision and accuracy of isotopic analyses determined by both the TIMS and MC-ICP-MS methods (e.g., Nd isotopic compositions). For each of the reference materials, 5 to 10 complete replicate analyses provide coherent isotopic results, all with external precision below 30 ppm (2 SD) for Sr and Nd isotopic compositions (27 and 24 ppm for TIMS and MC-ICP-MS, respectively). Our results also show that the first- and second-generation USGS reference materials have homogeneous Sr and Nd isotopic compositions. Nd isotopic compositions by MC-ICP-MS and TIMS agree to within 15 ppm for all reference materials. Interlaboratory MC-ICP-MS comparisons show excellent agreement for Pb isotopic compositions; however, the reproducibility is not as good as for Sr and Nd. A careful, sequential leaching experiment of three first- and second-generation reference materials (BCR, BHVO, AGV) indicates that the heterogeneity in Pb isotopic compositions

  6. Release of hydrogen isotopes from carbon based fusion reactor materials

    International Nuclear Information System (INIS)

    Vainonen-Ahlgren, E.

    2000-01-01

    The purpose of this study is to understand the annealing behavior of hydrogen isotopes in carbon based materials. Also, the density of the material and structural changes after thermal treatment and ion irradiation are examined. The study of hydrogen diffusion in diamondlike carbon films revealed an activation energy of 2.0 eV, while the deuterium diffusion, due to better measuring sensitivity, is found to be concentration dependent with the effective diffusion coefficient becoming smaller with decreasing deuterium concentration. To explain the experimentally observed profiles, a model according to which atomic deuterium diffuses and deuterium in clusters is immobile is developed. The concentration of immobile D was assumed to be an analytical function of the total D concentration. To describe the annealing behavior of D incorporated in diamondlike carbon films during the deposition process, a model taking into account diffusion of free D and thermal detrapping and trapping of D was developed. The difference in the analysis explains the disagreement of activation energy (1.5 ± 0.2 eV) with the value of 2,9± 0.1 eV obtained for D implanted samples earlier. The same model was applied to describe the experimental profiles in Si doped diamondlike carbon films. Si affects the retention of D in diamondlike carbon films. The amount of D depends on Si content in the co-deposited but not implanted samples. Besides, Si incorporation into carbon coating decreases to some extent the graphitization of the films and leads to formation of a structure which is stable under thermal treatment and ion irradiation. Hydrogen migration in the hydrogen and methane co-deposited films was also studied. In samples produced in methane atmosphere and annealed at different temperatures, the hydrogen concentration level decreases in the bulk, with more pronounced release at the surface region. In the case of coatings deposited by a methane ion beam, the H level also decreases with increasing

  7. Integrated safeguards and security for the INEL Special Isotope Separation Plant

    International Nuclear Information System (INIS)

    Warner, G.F.; Zack, N.R.

    1990-01-01

    This paper describes the development of the safeguards and security system that was to be used for the Special Isotope Separation (SIS) Production Plant. The US Department of Energy has postponed the construction of the SIS Plant that was to be built at the Idaho National Engineering Laboratory (INEL) site near Idaho Falls, Idaho. The Plant was designed to produce weapons grade plutonium from DOE owned fuel grade plutonium by converting off-spec. plutonium dioxide into metal buttons that would meet required chemical and isotopic specifications. Because this was to be a completely new facility there was a unique opportunity to provide an in-depth, ''state-of-the- art'' safeguards and security system without attempting to overlay upon an existing, older system. This facility was being designed to be in complete compliance with the new DOE Orders by integrating safeguards and security into the plant operating system and by providing graded protection to the areas of varying sensitivity within the plant

  8. Special purpose materials. Annual progress report, October 1, 1979

    International Nuclear Information System (INIS)

    1980-04-01

    Fusion reactor materials problems other than the first-wall and blanket structural materials are investigated. Components that are considered as special purpose materials include breeding materials, coolants, neutron multipliers, barriers for tritium control, materials for compression and OH coils and waveguides, grahite and SiC, heat-sink materials, ceramics, and materials for high-field (>10-T) superconducting magnets. Radiation-induced conductivity of three forms of Al 2 O 3 was measured as a function of ionizing dose rate and temperature. Increases observed are large enough to affect performance of insulators under some fusion reactor operating conditions. Single-crystal MgAl 2 O 4 was shown to exhibit zero swelling when irradiated to approx. 2 x 10 26 n/m 2 at 925 and 1100 K. This ceramic is resistant to nucleation and growth of defect aggregates, and is not characterized by those microstructural conditions which lead to void formation and swelling in Al 2 O 3 . Fracture toughness of single-crystal Al 2 O 3 was significantly increased by elevated-temperature irradiation to approx. 2 x 10 26 n/m 2 , while that for MgAl 2 O 4 and Y 3 Al 5 O 12 showed little or no change. These results show that ceramics can retain their original resistance to crack propagation after high-dose neutron irradiation

  9. LBA-ECO CD-02 Carbon, Nitrogen, Oxygen Stable Isotopes in Organic Material, Brazil

    Data.gov (United States)

    National Aeronautics and Space Administration — This data set reports the measurement of stable carbon, nitrogen, and oxygen isotope ratios in organic material (plant, litter and soil samples) in forest canopy...

  10. LBA-ECO CD-02 Carbon, Nitrogen, Oxygen Stable Isotopes in Organic Material, Brazil

    Data.gov (United States)

    National Aeronautics and Space Administration — ABSTRACT: This data set reports the measurement of stable carbon, nitrogen, and oxygen isotope ratios in organic material (plant, litter and soil samples) in forest...

  11. Normalization Methods and Selection Strategies for Reference Materials in Stable Isotope Analyes. Review

    Energy Technology Data Exchange (ETDEWEB)

    Skrzypek, G. [West Australian Biogeochemistry Centre, John de Laeter Centre of Mass Spectrometry, School of Plant Biology, University of Western Australia, Crawley (Australia); Sadler, R. [School of Agricultural and Resource Economics, University of Western Australia, Crawley (Australia); Paul, D. [Department of Civil Engineering (Geosciences), Indian Institute of Technology Kanpur, Kanpur (India); Forizs, I. [Institute for Geochemical Research, Hungarian Academy of Sciences, Budapest (Hungary)

    2013-07-15

    Stable isotope ratio mass spectrometers are highly precise, but not accurate instruments. Therefore, results have to be normalized to one of the isotope scales (e.g., VSMOW, VPDB) based on well calibrated reference materials. The selection of reference materials, numbers of replicates, {delta}-values of these reference materials and normalization technique have been identified as crucial in determining the uncertainty associated with the final results. The most common normalization techniques and reference materials have been tested using both Monte Carlo simulations and laboratory experiments to investigate aspects of error propagation during the normalization of isotope data. The range of observed differences justifies the need to employ the same sets of standards worldwide for each element and each stable isotope analytical technique. (author)

  12. Detecting special nuclear material using muon-induced neutron emission

    Energy Technology Data Exchange (ETDEWEB)

    Guardincerri, Elena; Bacon, Jeffrey; Borozdin, Konstantin; Matthew Durham, J.; Fabritius II, Joseph [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Hecht, Adam [University of New Mexico, Albuquerque, NM 87131 (United States); Milner, Edward C. [Southern Methodist University, Dallas, TX 75205 (United States); Miyadera, Haruo; Morris, Christopher L. [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Perry, John [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); University of New Mexico, Albuquerque, NM 87131 (United States); Poulson, Daniel [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States)

    2015-07-21

    The penetrating ability of cosmic ray muons makes them an attractive probe for imaging dense materials. Here, we describe experimental results from a new technique that uses neutrons generated by cosmic-ray muons to identify the presence of special nuclear material (SNM). Neutrons emitted from SNM are used to tag muon-induced fission events in actinides and laminography is used to form images of the stopping material. This technique allows the imaging of SNM-bearing objects tagged using muon tracking detectors located above or to the side of the objects, and may have potential applications in warhead verification scenarios. During the experiment described here we did not attempt to distinguish the type or grade of the SNM.

  13. The Transport of Radioactive Materials under special arrangement

    International Nuclear Information System (INIS)

    Biaggio, A.L.; Vietri, J.R.L.

    1993-01-01

    The Agency's Regulations for the Safe Transport of Radioactive Material rule the international transport of these materials and provide the basis of national and regional regulations. The Regulations establish the technical, operational and administrative requirements which shall be accomplished to carry out the transport of radioactive materials (RAM). They also allow the transport in different conditions of those currently applicable and, in such cases, establish that the transport shall be made under special arrangement. To approve a transport under special arrangement the involved Competent Authority shall be satisfied that the alternative provisions are adequate to ensure that the overall level of safety in transport and in-transit storage is at least equivalent to that which would be provided if all the applicable requirements had been met (para. 2ll of the International Atomic Energy Agency Safety Series No. 6). This paper explains some difficulties the Argentine Competent. Authority has experienced trying by comparing the equivalence between the level of safety resulting from the compliance with current requirements and the overall level of safety which is provided by the application of alternative provisions. As most of the experience gained come from the transport of RAM by road, only this mode of transport is considered. (J.P.N.)

  14. Special nuclear material information, security classification guidance. Instruction

    International Nuclear Information System (INIS)

    Flickinger, A.

    1982-01-01

    The Instruction reissues DoD Instruction 5210.67, July 5, 1979, and provides security classification guidance for information concerning significant quantities of special nuclear material, other than that contained in nuclear weapons and that used in the production of energy in the reactor plant of nuclear-powered ships. Security classification guidance for these data in the latter two applications is contained in Joint DoE/DoD Nuclear Weapons Classification Guide and Joint DoE/DoD Classification Guide for the Naval Nuclear Propulsion Program

  15. Real-time inventory system for special nuclear material

    Energy Technology Data Exchange (ETDEWEB)

    Kuckertz, T.H.; Ethridge, C.D.; Nicholson, N.

    1979-01-01

    This paper describes a special purpose peripheral device for a minicomputer that can monitor SNM in vault storage in real time and give timely indication of any tampering with the material. This device, called a shelf monitor, is designed around a single-chip microcomputer, and can be manufactured in quantity for about $100. A typical system of shelf monitors controlled by a minicomputer is described. The minicomputer is used to acquire data associated with the weight and gamma activity of the sample of SNM under observation. Significant deviations in the weight and gamma activity are cause for a tampering alarm.

  16. Real-time inventory system for special nuclear material

    International Nuclear Information System (INIS)

    Kuckertz, T.H.; Ethridge, C.D.; Nicholson, N.

    1979-01-01

    This paper describes a special purpose peripheral device for a minicomputer that can monitor SNM in vault storage in real time and give timely indication of any tampering with the material. This device, called a shelf monitor, is designed around a single-chip microcomputer, and can be manufactured in quantity for about $100. A typical system of shelf monitors controlled by a minicomputer is described. The minicomputer is used to acquire data associated with the weight and gamma activity of the sample of SNM under observation. Significant deviations in the weight and gamma activity are cause for a tampering alarm

  17. Semiannual report on strategic special nuclear material inventory differences

    International Nuclear Information System (INIS)

    1987-07-01

    This twentieth periodic semiannual report of unclassified Inventory Differences (ID's) covers the second six months of fiscal year 1986 (April 1, 1986, through September 30, 1986) for all key Department of Energy (DOE) and DOE contractor operated facilities possessing strategic special nuclear materials. Data for the Rocky Flats and Y-12 nuclear weapons production facilities are not included in the report in order to protect classified nuclear weapons information; however, classified ID data from these facilities receive the same scrutiny and analyses as the unclassified data

  18. Westinghouse Hanford Company special nuclear material vault storage study

    International Nuclear Information System (INIS)

    Borisch, R.R.

    1996-01-01

    Category 1 and 2 Special Nuclear Materials (SNM) require storage in vault or vault type rooms as specified in DOE orders 5633.3A and 6430.1A. All category 1 and 2 SNM in dry storage on the Hanford site that is managed by Westinghouse Hanford Co (WHC) is located in the 200 West Area at Plutonium Finishing Plant (PFP) facilities. This document provides current and projected SNM vault inventories in terms of storage space filled and forecasts available space for possible future storage needs

  19. ISOTOPIC CHARACTERIZATION OF ORGANIC MATERIALS LEACHED FROM LEAVES IN WATER OF MUNDARING WEIR DAM

    Directory of Open Access Journals (Sweden)

    Markus Heryanto Langsa

    2010-06-01

    Full Text Available This study examined the organic constituents aquatically leached from leaf components of two tree species (wandoo eucalyptus and pinus radiate. In particular this study aimed to assess the stable isotope composition behaviour of dissolved organic carbon (DOC from the residue leaves after leaching over five months. The changes in the stable carbon and nitrogen isotope compositions of the leached leaves materials were investigated using an elemental analyzer-isotope ratio mass spectrometry (EA-irMS. The stable isotope compositions were found to vary according to microbially-mediated alteration and decomposition. The average  d13C content of the raw plant elements was consistent with the  d13C values of terrestrial plants using a C3 photosynthetic pathway. The isotope compositions of leached materials of wandoo eucalyptus fresh leaf were continually depleted in d13C over the leaching period of three months. These variations correlated well with its DOC profile. Changes in  d13C values may also relate to the differential leaching of the macromolecular precursors of the original material. Lignin, for example, has a typically low  d13C and probably contributed to the decrease of  d13C in residue of the plant materials.   Keywords: isotope composition, leached materials, C3 plant

  20. Special issue on "Frontiers in Materials Science: Condensed matters"

    Science.gov (United States)

    Hoang, Nam-Nhat; Yamamoto, Tomoyuki; Pham, Duc-Thang

    2018-03-01

    This special issue includes the editor-invited and selected papers from 3rd International Symposium on Frontiers in Materials Science (FMS2016), held in Hanoi, Vietnam, from the 28th to 30th of September 2016, which coincided with the 65th anniversary of the Faculty of Physics, Hanoi University of Education. The FMS2016 is a continuation of a series of meetings starting from 2010. A first event was a bilateral Vietnamese-German meeting in Hanoi, Vietnam, in 2010, and the second one was held in Frankfurt, Germany, in 2011. The idea at that time was to initiate interactions between scientists from both countries and to further develop the field of materials science in Southeast Asia. After these successful bilateral meetings, a next step was taken by advancing the format of the symposium into an international event. In 2013, the 1st International Symposium on Frontiers in Materials Science (FMS2013) was successfully organized in Hanoi, which followed 2nd symposium, FMS2015, in Tokyo, in 2015. The FMS2016 continues this idea of providing an international forum for physicists, material scientists and chemists for discussing their latest results and the recent developments in the important field of materials science.

  1. Special Nuclear Material Portal Monitoring at the Nevada Test Site

    International Nuclear Information System (INIS)

    DeAnn Long; Michael Murphy

    2008-01-01

    Prior to April 2007, acceptance and performance testing of the various Special Nuclear Material (SNM) monitoring devices at the Nevada Test Site (NTS) was performed by the Radiological Health Instrumentation department. Calibration and performance testing on the PM-700 personnel portal monitor was performed, but there was no test program for the VM-250 vehicle portal monitor. The handheld SNM monitors, the TSA model 470B, were being calibrated annually, but there was no performance test program. In April of 2007, the Material Control and Accountability Manager volunteered to take over performance testing of all SNM portal monitors at NTS in order to strengthen the program and meet U.S. Department of Energy Order requirements. This paper will discuss the following activities associated with developing a performance testing program: changing the culture, learning the systems, developing and implementing procedures, troubleshooting and repair, validating the process, physical control of equipment, acquisition of new systems, and implementing the performance test program

  2. Special Nuclear Material Gamma-Ray Signatures for Reachback Analysts

    Energy Technology Data Exchange (ETDEWEB)

    Karpius, Peter Joseph [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Myers, Steven Charles [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2016-08-29

    These are slides on special nuclear material gamma-ray signatures for reachback analysts for an LSS Spectroscopy course. The closing thoughts for this presentation are the following: SNM materials have definite spectral signatures that should be readily recognizable to analysts in both bare and shielded configurations. One can estimate burnup of plutonium using certain pairs of peaks that are a few keV apart. In most cases, one cannot reliably estimate uranium enrichment in an analogous way to the estimation of plutonium burnup. The origin of the most intense peaks from some SNM items may be indirect and from ‘associated nuclides.' Indirect SNM signatures sometimes have commonalities with the natural gamma-ray background.

  3. Lead isotopic compositions of environmental certified reference materials for an inter-laboratory comparison of lead isotope analysis

    International Nuclear Information System (INIS)

    Aung, Nyein Nyein; Uryu, Tsutomu; Yoshinaga, Jun

    2004-01-01

    Lead isotope ratios, viz. 207 Pb/ 206 Pb and 208 Pb/ 206 Pb, of the commercially available certified reference materials (CRMs) issued in Japan are presented with an objective to provide a data set, which will be useful for the quality assurance of analytical procedures, instrumental performance and method validation of the laboratories involved in environmental lead isotope ratio analysis. The analytical method used in the present study was inductively coupled plasma quadrupole mass spectrometry (ICPQMS) presented by acid digestion and with/without chemical separation of lead from the matrix. The precision of the measurements in terms of the relative standard deviation (RSD) of triplicated analyses was 0.19% and 0.14%, for 207 Pb/ 206 Pb and 208 Pb/ 206 Pb, respectively. The trueness of lead isotope ratio measurements of the present study was tested with a few CRMs, which have been analyzed by other analytical methods and reported in various literature. The lead isotopic ratios of 18 environmental matrix CRMs (including 6 CRMs analyzed for our method validation) are presented and the distribution of their ratios is briefly discussed. (author)

  4. Internal transfers of special nuclear material - March 1975

    International Nuclear Information System (INIS)

    Anon.

    1976-01-01

    Paragraph 70.51(e) of 10 CFR Part 70 requires, with certain exceptions stated in the rule, that each licensee authorized to possess more than one effective kilogram of special nuclear material (SNM) maintain certain procedures. These procedures are to include: (1) records of the quantities of SNM added to or removed from the process; (2) documentation of all transfers of SNM between material-balance areas to show the identity and quantity of SNM transferred; (3) requirements for authorized signatures on each document used to record the transfer of SNM between material-balance areas; and (4) means for control of and accounting for internal transfer documents. Paragraph 70.58(e) requires licensees to establish, maintain, and follow a system for measuring the SNM transferred between material-balance areas and item-control areas. Paragraph 70.58(f) requires that licensees have a program that evaluates and controls the quality of their measurement system. Additionally, all licensees authorized to possess SNM must comply with paragraph 70.51(b) of 10 CFR Part 70. That rule requires licensees to keep records showing, among other things, the inventory of all SNM in their possession and its location. This guide sets forth acceptable methods for controlling and documenting transfers of SNM within a plant site in order to meet the requirements listed above

  5. The application of isotopic dating methods for prospection and exploration of nuclear raw material

    International Nuclear Information System (INIS)

    Komlev, L.V.; Anderson, E.B.

    1977-01-01

    Among the geological and geochemical methods for prospecting and searching the nuclear raw material, the isotope-dating methods determine the most important search criterion - the time of the ore-forming. The elaboration and use of these methods in uranium-ore regions reveal a series of geochemical epochs of uranium and thorium accumulation connected naturally with the history of geological evolution of the earth crust. The isotope-dating methods enable with confidence to establish the stages of tectono-magmatic activity resulting in the redistribution and the local concentration of uranium. The wide use of isotopic methods is a necessary condition for reasonable trends of the modern geological exploration [ru

  6. Neutron interrogation system using high gamma ray signature to detect contraband special nuclear materials in cargo

    Science.gov (United States)

    Slaughter, Dennis R [Oakland, CA; Pohl, Bertram A [Berkeley, CA; Dougan, Arden D [San Ramon, CA; Bernstein, Adam [Palo Alto, CA; Prussin, Stanley G [Kensington, CA; Norman, Eric B [Oakland, CA

    2008-04-15

    A system for inspecting cargo for the presence of special nuclear material. The cargo is irradiated with neutrons. The neutrons produce fission products in the special nuclear material which generate gamma rays. The gamma rays are detecting indicating the presence of the special nuclear material.

  7. Thallium determination in reference materials by isotope dilution mass spectrometry (IDMS) using thermal ionization

    International Nuclear Information System (INIS)

    Waidmann, E.; Hilpert, K.; Stoeppler, M.

    1990-01-01

    Using Isotope Dilution Mass Spectrometry (IDMS) with thermal ionization, thallium concentrations were determined in reference materials from NIST and BCR, from other sources, and reference materials from the German Environmental Specimen Bank 203 Tl spike solution is applied for the isotope dilution technique. Thallium concentrations in the investigated materials range from 2.67 μg Tl.kg -1 to 963 μg Tl.kg -1 with a relative standard deviation from 0.14 to 10%. The detection limit was 0.1 ng thallium for this work. (orig.)

  8. Isotopic power materials development. Quarterly progress report for period ending March 31, 1976

    International Nuclear Information System (INIS)

    Schaffhauser, A.C.

    1976-06-01

    The second in a series of quarterly reports for Technology and Space Applications materials programs conducted by the Metals and Ceramics Division of Oak Ridge National Laboratory for the Nuclear Research and Applications Division of ERDA is presented. These quarterly reports replace the monthly and annual reports previously issued on this work. The areas of research covered include high-temperature alloys for space isotopic heat sources, physical and mechanical metallurgy of heat source containment materials, isotope Brayton system materials support, and space nuclear flight systems hardware

  9. Detection of special nuclear materials with the associate particle technique

    International Nuclear Information System (INIS)

    Carasco, Cédric; Deyglun, Clément; Pérot, Bertrand; Eléon, Cyrille; Normand, Stéphane; Sannié, Guillaume; Boudergui, Karim; Corre, Gwenolé; Konzdrasovs, Vladimir; Pras, Philippe

    2013-01-01

    In the frame of the French trans-governmental R and D program against chemical, biological, radiological, nuclear and explosives (CBRN-E) threats, CEA is studying the detection of Special Nuclear Materials (SNM) by neutron interrogation with fast neutrons produced by an associated particle sealed tube neutron generator. The deuterium-tritium fusion reaction produces an alpha particle and a 14 MeV neutron almost back to back, allowing tagging neutron emission both in time and direction with an alpha particle position-sensitive sensor embedded in the generator. Fission prompt neutrons and gamma rays induced by tagged neutrons which are tagged by an alpha particle are detected in coincidence with plastic scintillators. This paper presents numerical simulations performed with the MCNP-PoliMi Monte Carlo computer code and with post processing software developed with the ROOT data analysis package. False coincidences due to neutron and photon scattering between adjacent detectors (cross talk) are filtered out to increase the selectivity between nuclear and benign materials. Accidental coincidences, which are not correlated to an alpha particle, are also taken into account in the numerical model, as well as counting statistics, and the time-energy resolution of the data acquisition system. Such realistic calculations show that relevant quantities of SNM (few kg) can be distinguished from cargo and shielding materials in 10 min acquisitions. First laboratory tests of the system under development in CEA laboratories are also presented.

  10. Special nuclear material radiation monitors for the 1980's

    International Nuclear Information System (INIS)

    Fehlau, P.E.

    1985-01-01

    During the two decades that automatic gamma-radiation monitors have been applied to detecting special nuclear material (SNM), little attention has been devoted to how well the monitors perform in plant environments. Visits to 11 DOE facilities revealed poor information flow between developers, manufacturers, and maintainers of SNM radiation monitors. To help users achieve best performance from their monitors or select new ones, Los Alamos National Laboratory developed a hand-held monitor user's guide, calibration manuals for some commercial SNM pedestrian monitors, and an application guide for SNM pedestrian monitors. In addition, Los Alamos evaluated new commercial SNM monitors, considered whether to apply neutron detection to SNM monitoring, and investigated the problem of operating gamma-ray SNM monitors in variable plutonium gamma-radiation fields. As a result, the performance of existing SNM monitors will improve and alternative monitoring methods will become commerciallly available during the 1980s. 9 refs., 6 figs., 1 tab

  11. Approach for domestic preparation of standard material (LSD spike) for isotope dilution mass spectrometry

    International Nuclear Information System (INIS)

    Ishikawa, Fumitaka; Sumi, Mika; Chiba, Masahiko; Suzuki, Toru; Abe, Tomoyuki; Kuno, Yusuke

    2008-01-01

    The accountancy analysis of the nuclear fuel material at Plutonium Fuel Development Center of JAEA is performed by isotope dilution mass spectrometry (IDMS; Isotope Dilution Mass Spectrometry). IDMS requires the standard material called LSD spike (Large Size Dried spike) which is indispensable for the accountancy in the facilities where the nuclear fuel materials are handled. Although the LSD spike and Pu source material have been supplied from foreign countries, the transportation for such materials has been getting more difficult recently. This difficulty may affect the operation of nuclear facilities in the future. Therefore, research and development of the domestic LSD spike and base material has been performed at JAEA. Certification for such standard nuclear materials including spikes produced in Japan is being studied. This report presents the current status and the future plan for the technological development. (author)

  12. Special cluster issue on tribocorrosion of dental materials

    Science.gov (United States)

    Mathew, Mathew T.; Stack, Margaret M.

    2013-10-01

    Tribocorrosion affects all walks of life from oil and gas conversion to biomedical materials. Wear can interact with corrosion to enhance it or impede it; conversely, corrosion can enhance or impede wear. The understanding of the interactions between physical and chemical phenomena has been greatly assisted by electrochemical and microscopic techniques. In dentistry, it is well recognized that erosion due to dissolution (a term physicists use to denote wear) of enamel can result in tooth decay; however, the effects of the oral environment, i.e. pH levels, electrochemical potential and any interactions due to the forces involved in chewing are not well understood. This special cluster issue includes investigations on the fundamentals of wear-corrosion interactions involved in simulated oral environments, including candidate dental implant and veneer materials. The issue commences with a fundamental study of titanium implants and this is followed by an analysis of the behaviour of commonly used temporomandibular devices in a synovial fluid-like environment. The analysis of tribocorrosion mechanisms of Ti6Al4V biomedical alloys in artificial saliva with different pHs is addressed and is followed by a paper on fretting wear, on hydroxyapatite-titanium composites in simulated body fluid, supplemented with protein (bovine serum albumin). The effects of acid treatments on tooth enamel, and as a surface engineering technique for dental implants, are investigated in two further contributions. An analysis of the physiological parameters of intraoral wear is addressed; this is followed by a study of candidate dental materials in common beverages such as tea and coffee with varying acidity and viscosity and the use of wear maps to identify the safety zones for prediction of material degradation in such conditions. Hence, the special cluster issue consists of a range of tribocorrosion contributions involving many aspects of dental tribocorrosion, from analysis of physiological

  13. Special Nuclear Material Portal Monitoring at the Nevada Test Site

    International Nuclear Information System (INIS)

    Mike Murphy

    2008-01-01

    In the past, acceptance and performance testing of the various Special Nuclear Material (SNM) monitoring devices at the Nevada Test Site has been performed by the Radiological Health Instrumentation Department. Calibration and performance tests on the PM-700 personnel portal monitor were performed but there was no test program for the VM-250 vehicle portal monitor because it had never been put into service. The handheld SNM monitors, the TSA model 470B, were being calibrated annually, but there was no program in place to test them quarterly. In April of 2007, the Material Control and Accountability (MC and A) Manager at the time decided that the program needed to be strengthened and MC and A took over performance testing of all SNM portal monitoring equipment. This paper will discuss the following activities associated with creating a performance testing program: changing the culture, learning the systems, writing procedures, troubleshooting/repairing, validating the process, control of equipment, acquisition of new systems, and running the program

  14. Selected topics in special nuclear materials safeguard system design

    International Nuclear Information System (INIS)

    King, L.L.; Thatcher, C.D.; Clarke, J.D.; Rodriguez, M.P.

    1991-01-01

    During the past two decades the improvements in circuit integration have given rise to many new applications in digital processing technology by continuously reducing the unit cost of processing power. Along with this increase in processing power a corresponding decrease in circuit volume has been achieved. Progress has been so swift that new classes of applications become feasible every 2 or 3 years. This is especially true in the application of proven new technology to special nuclear materials (SNM) safeguard systems. Several areas of application were investigated in establishing the performance requirements for the SNM safeguard system. These included the improvements in material control and accountability and surveillance by using multiple sensors to continuously monitor SNM inventory within the selected value(s); establishing a system architecture to provide capabilities needed for present and future performance requirements; and limiting operating manpower exposure to radiation. This paper describes two selected topics in the application of state-of-the-art, well-proven technology to SNM safeguard system design

  15. Diamond and Diamond-Like Materials as Hydrogen Isotope Barriers

    International Nuclear Information System (INIS)

    Foreman, L.R.; Barbero, R.S.; Carroll, D.W.; Archuleta, T.; Baker, J.; Devlin, D.; Duke, J.; Loemier, D.; Trukla, M.

    1999-01-01

    This is the final report of a two-year, Laboratory Directed Research and Development (LDRD) project at Los Alamos National Laboratory (LANL). The purpose of this project was to develop diamond and diamond-like thin-films as hydrogen isotope permeation barriers. Hydrogen embrittlement limits the life of boost systems which otherwise might be increased to 25 years with a successful non-reactive barrier. Applications in tritium processing such as bottle filling processes, tritium recovery processes, and target filling processes could benefit from an effective barrier. Diamond-like films used for low permeability shells for ICF and HEDP targets were also investigated. Unacceptable high permeabilities for hydrogen were obtained for plasma-CVD diamond-like-carbon films

  16. Isotopes as tracers of the sources of the lunar material and processes of lunar origin.

    Science.gov (United States)

    Pahlevan, Kaveh

    2014-09-13

    Ever since the Apollo programme, isotopic abundances have been used as tracers to study lunar formation, in particular to study the sources of the lunar material. In the past decade, increasingly precise isotopic data have been reported that give strong indications that the Moon and the Earth's mantle have a common heritage. To reconcile these observations with the origin of the Moon via the collision of two distinct planetary bodies, it has been proposed (i) that the Earth-Moon system underwent convective mixing into a single isotopic reservoir during the approximately 10(3) year molten disc epoch after the giant impact but before lunar accretion, or (ii) that a high angular momentum impact injected a silicate disc into orbit sourced directly from the mantle of the proto-Earth and the impacting planet in the right proportions to match the isotopic observations. Recently, it has also become recognized that liquid-vapour fractionation in the energetic aftermath of the giant impact is capable of generating measurable mass-dependent isotopic offsets between the silicate Earth and Moon, rendering isotopic measurements sensitive not only to the sources of the lunar material, but also to the processes accompanying lunar origin. Here, we review the isotopic evidence that the silicate-Earth-Moon system represents a single planetary reservoir. We then discuss the development of new isotopic tracers sensitive to processes in the melt-vapour lunar disc and how theoretical calculations of their behaviour and sample observations can constrain scenarios of post-impact evolution in the earliest history of the Earth-Moon system. © 2014 The Author(s) Published by the Royal Society. All rights reserved.

  17. The determination of minor isotope abundances in naturally occurring uranium materials. The tracing power of isotopic signatures for uranium

    Energy Technology Data Exchange (ETDEWEB)

    Ovaskainen, R

    1999-11-01

    The mass spectrometric determination of minor abundant isotopes, {sup 234}U and {sup 236}U in naturally occurring uranium materials requires instruments of high abundance sensitivity and the use of highly sensitive detection systems. In this study the thermal ionisation mass spectrometer Finnigan MAT 262RPQ was used. It was equipped with 6 Faraday cups and a Secondary Electron Multiplier (SEM), which was operated in pulse counting mode for the detection of extremely low ion currents. The dynamic measurement range was increased considerably combining these two different detectors. The instrument calibration was performed carefully. The linearity of each detector, the deadtime of the ion counting detector, the detector normalisation factor, the baseline of each detector and the mass discrimination in the ion source were checked and optimised. A measurement technique based on the combination of a Gas Source Mass Spectrometry (GSMS) and a Thermal Ionisation Mass Spectrometry (TIMS) was developed for the accurate determination of isotopic composition in naturally occurring uranium materials. Because the expected ratio of n({sup 234}U)/n({sup 238}U) exceeded the dynamic measurement range of the Faraday detectors of the TIMS instrument, an experimental design using a combination of two detectors was developed. The n({sup 234}U)/n({sup 235}U) and n({sup 236}U)/n({sup 235}U) ratios were determined using ion counting in combination with the decelerating device. The n({sup 235}U)/n({sup 238}U) ratio was determined by the Faraday detector. This experimental design allowed the detector cross calibration to be circumvented. Precisions of less than 1 percent for the n({sup 234}U)/n({sup 235}U) ratios and 5-25 percent for the n({sup 236}U)/n({sup 235}U) ratios were achieved. The purpose of the study was to establish a register of isotopic signatures for natural uranium materials. The amount ratio, and isotopic composition of 18 ore concentrates, collected by the International

  18. The determination of minor isotope abundances in naturally occurring uranium materials. The tracing power of isotopic signatures for uranium

    International Nuclear Information System (INIS)

    Ovaskainen, R.

    1999-01-01

    The mass spectrometric determination of minor abundant isotopes, 234 U and 236 U in naturally occurring uranium materials requires instruments of high abundance sensitivity and the use of highly sensitive detection systems. In this study the thermal ionisation mass spectrometer Finnigan MAT 262RPQ was used. It was equipped with 6 Faraday cups and a Secondary Electron Multiplier (SEM), which was operated in pulse counting mode for the detection of extremely low ion currents. The dynamic measurement range was increased considerably combining these two different detectors. The instrument calibration was performed carefully. The linearity of each detector, the deadtime of the ion counting detector, the detector normalisation factor, the baseline of each detector and the mass discrimination in the ion source were checked and optimised. A measurement technique based on the combination of a Gas Source Mass Spectrometry (GSMS) and a Thermal Ionisation Mass Spectrometry (TIMS) was developed for the accurate determination of isotopic composition in naturally occurring uranium materials. Because the expected ratio of n( 234 U)/n( 238 U) exceeded the dynamic measurement range of the Faraday detectors of the TIMS instrument, an experimental design using a combination of two detectors was developed. The n( 234 U)/n( 235 U) and n( 236 U)/n( 235 U) ratios were determined using ion counting in combination with the decelerating device. The n( 235 U)/n( 238 U) ratio was determined by the Faraday detector. This experimental design allowed the detector cross calibration to be circumvented. Precisions of less than 1 percent for the n( 234 U)/n( 235 U) ratios and 5-25 percent for the n( 236 U)/n( 235 U) ratios were achieved. The purpose of the study was to establish a register of isotopic signatures for natural uranium materials. The amount ratio, and isotopic composition of 18 ore concentrates, collected by the International Atomic Energy Agency (IAEA) from uranium milling and mining

  19. 77 FR 36607 - Office of Hazardous Materials Safety Notice of Applications for Modification of Special Permit

    Science.gov (United States)

    2012-06-19

    ... modification of special permits (e.g. to provide for additional hazardous materials, packaging design changes... hazardous materials. 12102-M EQ Industrial 49 CFR 173.56(i); To modify the special Services, Inc. 173.56(b... 4.1. 13102-M Robertshaw Industrial 49 CFR 173.150(b); To modify the special Products dba 173.222(c...

  20. Novel methods for estimating 3D distributions of radioactive isotopes in materials

    Energy Technology Data Exchange (ETDEWEB)

    Iwamoto, Y., E-mail: y.iwamoto0805@ruri.waseda.jp [Research Institute for Science and Engineering, Waseda University, Shinjuku, Tokyo 169-8555 (Japan); Kataoka, J.; Kishimoto, A.; Nishiyama, T.; Taya, T.; Okochi, H.; Ogata, H. [Research Institute for Science and Engineering, Waseda University, Shinjuku, Tokyo 169-8555 (Japan); Yamamoto, S. [Nagoya University Graduate School of Medicine, 1-1-20, Daikominami, Higashi-ku, Nagoya-shi, Aichi 461-8673 (Japan)

    2016-09-21

    In recent years, various gamma-ray visualization techniques, or gamma cameras, have been proposed. These techniques are extremely effective for identifying “hot spots” or regions where radioactive isotopes are accumulated. Examples of such would be nuclear-disaster-affected areas such as Fukushima or the vicinity of nuclear reactors. However, the images acquired with a gamma camera do not include distance information between radioactive isotopes and the camera, and hence are “degenerated” in the direction of the isotopes. Moreover, depth information in the images is lost when the isotopes are embedded in materials, such as water, sand, and concrete. Here, we propose two methods of obtaining depth information of radioactive isotopes embedded in materials by comparing (1) their spectra and (2) images of incident gamma rays scattered by the materials and direct gamma rays. In the first method, the spectra of radioactive isotopes and the ratios of scattered to direct gamma rays are obtained. We verify experimentally that the ratio increases with increasing depth, as predicted by simulations. Although the method using energy spectra has been studied for a long time, an advantage of our method is the use of low-energy (50–150 keV) photons as scattered gamma rays. In the second method, the spatial extent of images obtained for direct and scattered gamma rays is compared. By performing detailed Monte Carlo simulations using Geant4, we verify that the spatial extent of the position where gamma rays are scattered increases with increasing depth. To demonstrate this, we are developing various gamma cameras to compare low-energy (scattered) gamma-ray images with fully photo-absorbed gamma-ray images. We also demonstrate that the 3D reconstruction of isotopes/hotspots is possible with our proposed methods. These methods have potential applications in the medical fields, and in severe environments such as the nuclear-disaster-affected areas in Fukushima.

  1. Novel methods for estimating 3D distributions of radioactive isotopes in materials

    Science.gov (United States)

    Iwamoto, Y.; Kataoka, J.; Kishimoto, A.; Nishiyama, T.; Taya, T.; Okochi, H.; Ogata, H.; Yamamoto, S.

    2016-09-01

    In recent years, various gamma-ray visualization techniques, or gamma cameras, have been proposed. These techniques are extremely effective for identifying "hot spots" or regions where radioactive isotopes are accumulated. Examples of such would be nuclear-disaster-affected areas such as Fukushima or the vicinity of nuclear reactors. However, the images acquired with a gamma camera do not include distance information between radioactive isotopes and the camera, and hence are "degenerated" in the direction of the isotopes. Moreover, depth information in the images is lost when the isotopes are embedded in materials, such as water, sand, and concrete. Here, we propose two methods of obtaining depth information of radioactive isotopes embedded in materials by comparing (1) their spectra and (2) images of incident gamma rays scattered by the materials and direct gamma rays. In the first method, the spectra of radioactive isotopes and the ratios of scattered to direct gamma rays are obtained. We verify experimentally that the ratio increases with increasing depth, as predicted by simulations. Although the method using energy spectra has been studied for a long time, an advantage of our method is the use of low-energy (50-150 keV) photons as scattered gamma rays. In the second method, the spatial extent of images obtained for direct and scattered gamma rays is compared. By performing detailed Monte Carlo simulations using Geant4, we verify that the spatial extent of the position where gamma rays are scattered increases with increasing depth. To demonstrate this, we are developing various gamma cameras to compare low-energy (scattered) gamma-ray images with fully photo-absorbed gamma-ray images. We also demonstrate that the 3D reconstruction of isotopes/hotspots is possible with our proposed methods. These methods have potential applications in the medical fields, and in severe environments such as the nuclear-disaster-affected areas in Fukushima.

  2. Qualifications of and acceptance criteria for transporting special form radioactive material

    International Nuclear Information System (INIS)

    Hovingh, J.

    1991-01-01

    A special form radioactive material is a radioactive material that is in an inert, insoluble, indispersible form such that even in the event of an accident, it will not be dispersed into the environment in a way that could have an adverse impact on public health and safety. Methods of qualifying a special form radioactive material are discussed. Interpretation of acceptance criteria are proposed for the transportation of Type B quantities of a special form radioactive material. 11 refs

  3. Saturation and isotopic replacement of deuterium in low-Z material

    International Nuclear Information System (INIS)

    Doyle, B.L.; Wampler, W.R.; Brice, D.K.; Picraux, S.T.

    1980-01-01

    The saturation and replacement of hydrogen isotopes implanted into TiC, TiB 2 , VB 2 , B 4 C, B, Si, and C has been examined experimentally and modeled theoretically. The deuterium saturation concentrations for these materials varied from .16 to .57. A new isotopic replacement model is presented which predicts isotopic trapping and exchange on the basis of the depth dependence of the implanted ions and the experimentally determined hydrogen saturation concentration. Our results indicate that, for these materials used as coatings on components in a D-T fueled tokamak, T recovery by ion induced replacement with H or D should be feasible and that T buildup will be at tolerable levels

  4. Estimation methods for process holdup of special nuclear materials

    International Nuclear Information System (INIS)

    Pillay, K.K.S.; Picard, R.R.; Marshall, R.S.

    1984-06-01

    The US Nuclear Regulatory Commission sponsored a research study at the Los Alamos National Laboratory to explore the possibilities of developing statistical estimation methods for materials holdup at highly enriched uranium (HEU)-processing facilities. Attempts at using historical holdup data from processing facilities and selected holdup measurements at two operating facilities confirmed the need for high-quality data and reasonable control over process parameters in developing statistical models for holdup estimations. A major effort was therefore directed at conducting large-scale experiments to demonstrate the value of statistical estimation models from experimentally measured data of good quality. Using data from these experiments, we developed statistical models to estimate residual inventories of uranium in large process equipment and facilities. Some of the important findings of this investigation are the following: prediction models for the residual holdup of special nuclear material (SNM) can be developed from good-quality historical data on holdup; holdup data from several of the equipment used at HEU-processing facilities, such as air filters, ductwork, calciners, dissolvers, pumps, pipes, and pipe fittings, readily lend themselves to statistical modeling of holdup; holdup profiles of process equipment such as glove boxes, precipitators, and rotary drum filters can change with time; therefore, good estimation of residual inventories in these types of equipment requires several measurements at the time of inventory; although measurement of residual holdup of SNM in large facilities is a challenging task, reasonable estimates of the hidden inventories of holdup to meet the regulatory requirements can be accomplished through a combination of good measurements and the use of statistical models. 44 references, 62 figures, 43 tables

  5. New Organic Stable Isotope Reference Materials for Distribution through the USGS and the IAEA

    Science.gov (United States)

    Schimmelmann, Arndt; Qi, Haiping

    2014-05-01

    The widespread adoption of relative stable isotope-ratio measurements in organic matter by diverse scientific disciplines is at odds with the dearth of international organic stable isotopic reference materials (RMs). Only two of the few carbon (C) and nitrogen (N) organic RMs, namely L-glutamic acids USGS40 and USGS41 [1], both available from the U.S. Geological Survey (USGS) and the International Atomic Energy Agency (IAEA), provide an isotopically contrasting pair of organic RMs to enable essential 2-point calibrations for δ-scale normalization [2, 3]. The supply of hydrogen (H) organic RMs is even more limited. Numerous stable isotope laboratories have resorted to questionable practices, for example by using 'CO2, N2, and H2 reference gas pulses' for isotopic calibrations, which violates the principle of identical treatment of sample and standard (i.e., organic unknowns should be calibrated directly against chemically similar organic RMs) [4], or by using only 1 anchor instead of 2 for scale calibration. The absence of international organic RMs frequently serves as an excuse for indefensible calibrations. In 2011, the U.S. National Science Foundation (NSF) funded an initiative of 10 laboratories from 7 countries to jointly develop much needed new organic RMs for future distribution by the USGS and the IAEA. The selection of targeted RMs attempts to cover various common compound classes of broad technical and scientific interest. We had to accept compromises to approach the ideal of high chemical stability, lack of toxicity, and low price of raw materials. Hazardous gases and flammable liquids were avoided in order to facilitate international shipping of future RMs. With the exception of polyethylene and vacuum pump oil, all organic RMs are individual, chemically-pure substances, which can be used for compound-specific isotopic measurements in conjunction with liquid and gas chromatographic interfaces. The compounds listed below are under isotopic calibration by

  6. Superheated emulsions for the detection of special nuclear material

    International Nuclear Information System (INIS)

    D’Errico, Francesco; Di Fulvio, Angela

    2011-01-01

    A novel solution for the detection and smuggling interdiction of special nuclear materials is presented here consisting of large detector modules which contain superheated emulsions and which are readout with an optical approach. The detectors can be produced to be fully sensitive to prompt fission neutrons and totally insensitive to the interrogation beam, whether X-rays or neutrons below a chosen energy threshold. Therefore, the detectors are able to operate while the selected interrogation beam is on and they will only pick up the signal from fission neutrons. A position-sensitive readout mechanism is used in our design, relying on the scattering of light by neutron-induced bubbles. A beam of coherent light crosses the active area of the detector, and local variations in scattered light due to the presence of bubbles are detected in real time by arrays of silicon planar photodiodes affixed along the whole length of the detector. The system may offer a variety of advantages compared to current approaches, such as the possibility of simultaneous irradiation and detection, i.e. a 100% duty cycle, without requiring complex signal analysis, and high signal-to-noise ratio, minimizing costly nuisance alarms, thanks to its inherent insensitivity to photons.

  7. Tamper and radiation resistant instrumentation for safeguarding special nuclear materials

    International Nuclear Information System (INIS)

    Parsons, B.B.; Wells, J.L.

    1977-01-01

    A tamper-resistant liquid level/accountability instrumentation system for safeguards use has been developed and tested. The tests demonstrate the accuracy of liquid level measurement using TDR (Time Domain Reflectometry) techniques and the accuracy of differential pressure and temperature measurements utilizing a custom designed liquid level sensor probe. The calibrated liquid level, differential pressure, and temperature data provide sufficient information to accurately determine volume, density, and specific gravity. Test solutions used include ordinary tap water, diluted nitric acid in varying concentrations, and diluted uranium trioxide also in varying concentrations. System operations and preliminary test results conducted at the General Electric Midwest Fuel Recovery Plant and the National Bureau of Standards, respectively, suggest that the system will provide the safeguards inspector with an additional tool for real-time independent verification of normal operations and special nuclear materials accountancy data for chemical reprocessing plants. This paper discusses the system design concepts, including a brief description of the tamper and radiation resistant features, the preliminary test results, and the significance of the work

  8. Special Nuclear Material Detection with a Water Cherenkov based Detector

    International Nuclear Information System (INIS)

    Sweany, M.; Bernstein, A.; Bowden, N.; Dazeley, S.; Svoboda, R.

    2008-01-01

    Fission events from Special Nuclear Material (SNM), such as highly enriched uranium or plutonium, produce a number of neutrons and high energy gamma-rays. Assuming the neutron multiplicity is approximately Poissonian with an average of 2 to 3, the observation of time correlations between these particles from a cargo container would constitute a robust signature of the presence of SNM inside. However, in order to be sensitive to the multiplicity, one would require a high total efficiency. There are two approaches to maximize the total efficiency; maximizing the detector efficiency or maximizing the detector solid angle coverage. The advanced detector group at LLNL is investigating one way to maximize the detector size. We are designing and building a water Cerenkov based gamma and neutron detector for the purpose of developing an efficient and cost effective way to deploy a large solid angle car wash style detector. We report on our progress in constructing a larger detector and also present preliminary results from our prototype detector that indicates detection of neutrons

  9. Determination of the hydrogen isotopic compositions of organic materials and hydrous minerals using thermal combustion laser spectroscopy.

    Science.gov (United States)

    Koehler, Geoff; Wassenaar, Leonard I

    2012-04-17

    Hydrogen isotopic compositions of hydrous minerals and organic materials were measured by combustion to water, followed by optical isotopic analysis of the water vapor by off-axis integrated cavity output spectroscopy. Hydrogen and oxygen isotopic compositions were calculated by numerical integration of the individual isotopologue concentrations measured by the optical spectrometer. Rapid oxygen isotope exchange occurs within the combustion reactor between water vapor and molecular oxygen so that only hydrogen isotope compositions may be determined. Over a wide range in sample sizes, precisions were ±3-4 per mil. This is comparable but worse than continuous flow-isotope ratio mass spectroscopy (CF-IRMS) methods owing to memory effects inherent in water vapor transfer. Nevertheless, the simplicity and reduced cost of this analysis compared to classical IRMS or CF-IRMS methods make this an attractive option to determine the hydrogen isotopic composition of organic materials where the utmost precision or small sample sizes are not needed.

  10. Intercomparison of enriched stable isotope reference materials for medical and biological studies

    International Nuclear Information System (INIS)

    Parr, R.M.; Clements, S.A.

    1991-01-01

    This report summarizes the results of an intercomparison exercise organized by the IAEA during the latter part of 1988 and 1989. Data are presented for 13 different kinds of enriched stable isotope reference material containing 2 H, 13 C, 15 N and 18 O. Results were submitted by forty participants in twenty countries. 2 refs, 13 figs, 18 tabs

  11. Isotope exchange reactions on ceramic breeder materials and their effect on tritium inventory

    Energy Technology Data Exchange (ETDEWEB)

    Nishikawa, M; Baba, A [Kyushu Univ., Fukuoka (Japan). Faculty of Engineering; Kawamura, Y; Nishi, M

    1998-03-01

    Though lithium ceramic materials such as Li{sub 2}O, LiAlO{sub 2}, Li{sub 2}ZrO{sub 3}, Li{sub 2}TiO{sub 3} and Li{sub 4}SiO{sub 4} are considered as breeding materials in the blanket of a D-T fusion reactor, the release behavior of the bred tritium in these solid breeder materials has not been fully understood. The isotope exchange reaction rate between hydrogen isotopes in the purge gas and tritium on the surface of breeding materials have not been quantified yet, although helium gas with hydrogen or deuterium is planned to be used as the blanket purge gas in the recent blanket designs. The mass transfer coefficient representing the isotope exchange reaction between H{sub 2} and D{sub 2}O or that between D{sub 2} and H{sub 2}O in the ceramic breeding materials bed is experimentally obtained in this study. Effects of isotope exchange reactions on the tritium inventory in the bleeding blanket is discussed based on data obtained in this study where effects of diffusion of tritium in the grain, absorption of water in the bulk of grain, and adsorption of water on the surface of grain, together with two types of isotope exchange reactions are considered. The way to estimate the tritium inventory in a Li{sub 2}ZrO{sub 3} blanket used in this study shows a good agreement with data obtained in such in-situ experiments as MOZART, EXOTIC-5, 6 and TRINE experiments. (author)

  12. Determination of molybdenum in plant reference material by thermal-ionization isotope-dilution mass spectrometry

    International Nuclear Information System (INIS)

    Saumer, M.; Gantner, E.; Reinhardt, J.; Ache, H.J.

    1992-01-01

    An analytical method is described for the determination of the concentration and the isotopic composition of molybdenum in plant samples using thermal ionization mass spectrometry. After microwave acid digestion and liquid-liquid extractive separation with Amberlite LA-2, the molybdenum isotopes are measured as MoO 3 - -ions in a quadrupole mass spectrometer. In all cases, the relative standard deviation of the measurements of both natural and spike molybdenum was better than 3% for all ratios measured. The concentration of molybdenum found in three different plant reference materials agreed well with the certified values. (orig.)

  13. Special features of the isotope ratio determination using mass-spectrometer with induction-bound plasma

    International Nuclear Information System (INIS)

    Stepanov, A.I.; Ramendik, G.I.; Fatyushina, E.V.

    2000-01-01

    The origin of the errors arising upon measuring relative abundance of Nd, Yb, and Gd isotopes on a HP-4500 mass-spectrometer (USA) is studied. It is shown that the main origin of the error is the different sensitivity of the mass-spectrometer to ions of different masses. Optimal content of the elements in the solutions is established upon determination of their isotopic abundance [ru

  14. Isotopic fractionation of NBS oxalic acid and its influence in the calculated age of materials

    International Nuclear Information System (INIS)

    Nehmi, V.A.

    1979-10-01

    The intensity of the isotopic fractionation during the oxidation of NBS oxalic acid to carbon dioxide was checked. 30 reactions of oxidation of NBS oxalic acid with potassium permanganate were made. The resultant isotopic composition of CO 2 has been determined with a mass-spectrometer. A conclusion has been reached that the average of Δ 13 C is - 18.9% o with variation between - 17.7 and - 21.2%o. For values of Δ 13 C equal to - 22.0%o, the calculated age with isotopic correction shows the following deviations in relation to non-corrected age: 4% for materials of 1,000 years and 0.3% for 20,000 years.(Author) [pt

  15. Assessment of fibrous insulation materials for the selenide isotope generator system

    International Nuclear Information System (INIS)

    Wei, G.C; Tennery, V.J.

    1977-11-01

    Fibrous insulations for use in the converter and the heat source of the radioisotope-powered, selenide element, thermoelectric generator (selenide isotope generator) are assessed. The most recent system design and material selection basis is presented. Several fibrous insulation materials which have the potential for use as load-bearing or nonload-bearing thermal insulations are reviewed, and thermophysical properties supplied by manufacturers or published in the literature are presented. Potential problems with the application of fibrous insulations in the selenide isotope generator are as follows: compatibility with graphite, the thermoelectric elements, and the isolation hot frame; devitrification, grain growth, and sintering with an accompanying degradation of insulation quality; impurity diffusion from the insulation to adjoining structures; outgassing and storage of fibrous materials. Areas in which thermophysical data or quantitative information on the insulation and structural stability is lacking are identified

  16. Isotope production

    Energy Technology Data Exchange (ETDEWEB)

    Lewis, Dewi M.

    1995-07-15

    Some 2 0% of patients using radiopharmaceuticals receive injections of materials produced by cyclotrons. There are over 200 cyclotrons worldwide; around 35 are operated by commercial companies solely for the production of radio-pharmaceuticals with another 25 accelerators producing medically useful isotopes. These neutron-deficient isotopes are usually produced by proton bombardment. All commonly used medical isotopes can be generated by 'compact' cyclotrons with energies up to 40 MeV and beam intensities in the range 50 to 400 microamps. Specially designed target systems contain gram-quantities of highly enriched stable isotopes as starting materials. The targets can accommodate the high power densities of the proton beams and are designed for automated remote handling. The complete manufacturing cycle includes large-scale target production, isotope generation by cyclotron beam bombardment, radio-chemical extraction, pharmaceutical dispensing, raw material recovery, and labelling/packaging prior to the rapid delivery of these short-lived products. All these manufacturing steps adhere to the pharmaceutical industry standards of Good Manufacturing Practice (GMP). Unlike research accelerators, commercial cyclotrons are customized 'compact' machines usually supplied by specialist companies such as IBA (Belgium), EBCO (Canada) or Scanditronix (Sweden). The design criteria for these commercial cyclotrons are - small magnet dimensions, power-efficient operation of magnet and radiofrequency systems, high intensity extracted proton beams, well defined beam size and automated computer control. Performance requirements include rapid startup and shutdown, high reliability to support the daily production of short-lived isotopes and low maintenance to minimize the radiation dose to personnel. In 1987 a major step forward in meeting these exacting industrial requirements came when IBA, together with the University of Louvain-La-Neuve in Belgium, developed the Cyclone-30

  17. Preparation and development of new Pu spike isotopic reference materials at IRMM

    Energy Technology Data Exchange (ETDEWEB)

    Jakopic, Rozle; Bauwens, Jeroen; Richter, Stephan; Sturm, Monika; Verbruggen, Andre; Wellum, Roger; Eykens, Roger; Kehoe, Frances; Kuehn, Heinz; Aregbe, Yetunde [Institute for Reference Materials and Measurements (IRMM) Joint Research Centre, European Commission, Geel, (Belgium)

    2011-12-15

    Reliable isotope measurements of nuclear material and the availability of reference materials with small uncertainties in the certified values are of great importance for safeguarding of nuclear materials. They provide the basis for a credible measurement system in the verification of states declarations of their nuclear activities. Worldwide needs for continued and improved Isotopic Reference Materials (IRM) are the main reason for developments of new nuclear reference materials at IRMM. Measurement capabilities of laboratories have evolved considerably over the years, along with progress in modern analytical techniques. Some plutonium reference materials, however, have been on the market for decades and they need to be re-certified to smaller uncertainties. Moreover, new reference materials with appropriately small uncertainties in the certified values need to be made available enabling measurement laboratories to reduce their combined measurement uncertainties. Such high quality plutonium isotopic reference materials are essential for laboratories striving to meet the International Target Values for Measurement Uncertainties in Safeguarding Nuclear Materials (ITVs). The preparation and the certification of such materials are demanding and challenging tasks that require state-of-theart measurement procedures and equipment. The Institute for Reference Materials and Measurements (IRMM) has repeatedly demonstrated its capabilities in plutonium analysis and represents one of the few institutes that supplies plutonium IRMs worldwide. An inter-calibration campaign has been set up at IRMM inter-linking selected plutonium spike IRMs. In the scope of this compatibility study, new reference materials have been prepared for Isotope Dilution Mass Spectrometry (IDMS) in nuclear fuel cycle measurements. A new series of large-sized dried (LSD) spikes, IRMM- 1027n, has been prepared and certified for plutonium and uranium amount content and isotopic composition. These mixed

  18. Fourth annual progress report on special-purpose materials for magnetically confined fusion reactors

    International Nuclear Information System (INIS)

    1982-08-01

    The scope of Special Purpose Materials covers fusion reactor materials problems other than the first-wall and blanket structural materials, which are under the purview of the ADIP, DAFS, and PMI task groups. Components that are considered as special purpose materials include breeding materials, coolants, neutron multipliers, barriers for tritium control, materials for compression and OH coils and waveguides, graphite and SiC, heat-sink materials, ceramics, and materials for high-field (>10-T) superconducting magnets. The Task Group on Special Purpose Materials has limited its concern to crucial and generic materials problems that must be resolved if magnetic-fusion devices are to succeed. Important areas specifically excluded include low-field (8-T) superconductors, fuels for hybrids, and materials for inertial-confinement devices. These areas may be added in the future when funding permits

  19. Order of 25 March 1981 concerning the approval of special form radioactive materials in sealed sources

    International Nuclear Information System (INIS)

    1981-01-01

    This order determines the models of sealed sources which constitute special form radioactive materials within the meaning of the Order of 24 November 1977 concerning the characteristics of such materials. (NEA) [fr

  20. Oxygen Isotopes in Early Solar System Materials: A Perspective Based on Microbeam Analyses of Chondrules from CV Carbonaceous Chondrites

    Science.gov (United States)

    Jones, R. H.; Leshin, L. A.; Guan, Y.

    2004-01-01

    Some of the biggest challenges to understanding the early history of the solar system include determining the distribution of oxygen isotopes amongst materials that existed in the solar nebula, and interpreting the processes that might have resulted in the observed isotopic distributions. Oxygen isotope ratios in any individual mineral grain from a chondritic meteorite may be the cumulative product of a variety of processes, including stellar nucleosynthetic events, gas/solid interactions in the molecular cloud, mixing of independent isotopic reservoirs in the nebula, mass-independent processing in the nebula, and mass-dependent fractionation effects in various environments. It is not possible to unravel this complex isotopic record unless the distribution of oxygen isotope ratios in chondritic materials is fully understood.

  1. Research on utilization of isotopes for metallic materials

    International Nuclear Information System (INIS)

    Maebashi, Yoichi; Kagaya, Yutaka; Kametani, Hiroshi

    1983-01-01

    As the research on the utilization of unsealed radioisotopes for metallic materials, among the refining of nonferrous metals already carried out in the National Research Institute for Metals, the refining reaction of copper sulfide was taken up. In this refining reaction, it is important to know the oxidation behavior of sulfur in copper sulfide for improving the refining method. However in the oxidation of sulfur, the kinds of the oxides formed are many, and when copper and iron ions coexist as in this case, their separation and analysis are very difficult. The utilization of radioisotopes is required for identifying the oxidation products and the oxides in melt, and for identifying various compound ions. The solvent for thin layer chromatography was selected, and the effects exerted by the moving rate, concentration and coexisting elements of various sulfur acid ions on the thin layer of silica gel were clarified. In the suspension reaction of copper sulfide without a power source, it was elucidated that S 2 O 3 2- arose consistently from the initial stage of reaction, and the reaction equation was forecast. The melting state of sulfur in anode oxidation reaction was studied. (Kako, I.)

  2. 75 FR 2163 - Constellation Energy; Notice of Docketing of Special Nuclear Material License SNM-2505 Amendment...

    Science.gov (United States)

    2010-01-14

    ... NUCLEAR REGULATORY COMMISSION [Docket No. 72-8; NRC-2010-0011] Constellation Energy; Notice of Docketing of Special Nuclear Material License SNM-2505 Amendment Application for the Calvert Cliffs... Constellation Energy (Constellation) to amend its Special Nuclear Material License No. SNM-2505, under the...

  3. Normalization Methods and Selection Strategies for Reference Materials in Stable Isotope Analyses - Review

    International Nuclear Information System (INIS)

    Skrzypek, G.; Sadler, R.; Paul, D.; Forizs, I.

    2011-01-01

    A stable isotope analyst has to make a number of important decisions regarding how to best determine the 'true' stable isotope composition of analysed samples in reference to an international scale. It has to be decided which reference materials should be used, the number of reference materials and how many repetitions of each standard is most appropriate for a desired level of precision, and what normalization procedure should be selected. In this paper we summarise what is known about propagation of uncertainties associated with normalization procedures and propagation of uncertainties associated with reference materials used as anchors for the determination of 'true' values for δ''1''3C and δ''1''8O. Normalization methods Several normalization methods transforming the 'raw' value obtained from mass spectrometers to one of the internationally recognized scales has been developed. However, as summarised by Paul et al. different normalization transforms alone may lead to inconsistencies between laboratories. The most common normalization procedures are: single-point anchoring (versus working gas and certified reference standard), modified single-point normalization, linear shift between the measured and the true isotopic composition of two certified reference standards, two-point and multipoint linear normalization methods. The accuracy of these various normalization methods has been compared by using analytical laboratory data by Paul et al., with the single-point and normalization versus tank calibrations resulting in the largest normalization errors, and that also exceed the analytical uncertainty recommended for δ 13 C. The normalization error depends greatly on the relative differences between the stable isotope composition of the reference material and the sample. On the other hand, the normalization methods using two or more certified reference standards produces a smaller normalization error, if the reference materials are bracketing the whole range of

  4. PLANETARY-SCALE STRONTIUM ISOTOPIC HETEROGENEITY AND THE AGE OF VOLATILE DEPLETION OF EARLY SOLAR SYSTEM MATERIALS

    Energy Technology Data Exchange (ETDEWEB)

    Moynier, Frederic; Podosek, Frank A. [Department of Earth and Planetary Science and McDonnell Center for Space Sciences, Washington University, St. Louis, MO 63130 (United States); Day, James M. D. [Geosciences Research Division, Scripps Institution of Oceanography, La Jolla, CA 92093-0244 (United States); Okui, Wataru; Yokoyama, Tetsuya [Department of Earth and Planetary Sciences, Tokyo Institute of Technology, Tokyo 152-8551 (Japan); Bouvier, Audrey [Department of Earth Sciences, University of Minnesota, Minneapolis, MN 55455-0231 (United States); Walker, Richard J., E-mail: moynier@levee.wustl.edu, E-mail: fap@levee.wustl.edu, E-mail: jmdday@ucsd.edu, E-mail: rjwalker@umd.edu, E-mail: okui.w.aa@m.titech.ac.jp, E-mail: tetsuya.yoko@geo.titech.ac.jp, E-mail: abouvier@umn.edu [Department of Geology, University of Maryland, College Park, MD 20742 (United States)

    2012-10-10

    Isotopic anomalies in planetary materials reflect both early solar nebular heterogeneity inherited from presolar stellar sources and processes that generated non-mass-dependent isotopic fractionations. The characterization of isotopic variations in heavy elements among early solar system materials yields important insight into the stellar environment and formation of the solar system, and about initial isotopic ratios relevant to long-term chronological applications. One such heavy element, strontium, is a central element in the geosciences due to wide application of the long-lived {sup 87}Rb-{sup 87}Sr radioactive as a chronometer. We show that the stable isotopes of Sr were heterogeneously distributed at both the mineral scale and the planetary scale in the early solar system, and also that the Sr isotopic heterogeneities correlate with mass-independent oxygen isotope variations, with only CI chondrites plotting outside of this correlation. The correlation implies that most solar system material formed by mixing of at least two isotopically distinct components: a CV-chondrite-like component and an O-chondrite-like component, and possibly a distinct CI-chondrite-like component. The heterogeneous distribution of Sr isotopes may indicate that variations in initial {sup 87}Sr/{sup 86}Sr of early solar system materials reflect isotopic heterogeneity instead of having chronological significance, as interpreted previously. For example, given the differences in {sup 84}Sr/{sup 86}Sr between calcium aluminum inclusions and eucrites ({epsilon}{sup 84}Sr > 2), the difference in age between these materials would be {approx}6 Ma shorter than previously interpreted, placing the Sr chronology in agreement with other long- and short-lived isotope systems, such as U-Pb and Mn-Cr.

  5. Possible application of laser isotope separation

    International Nuclear Information System (INIS)

    Delionback, L.M.

    1975-05-01

    The laser isotope separation process is described and its special economic features discussed. These features are its low cost electric power operation, capital investment costs, and the costs of process materials. (Author)

  6. Isotope effect in monolayer, localised, immobilised adsorption with special reference to neon adsorption on porous glass at cryogenic temperatures

    International Nuclear Information System (INIS)

    Srisaila, S.; Bajpai, M.B.

    1980-01-01

    Using statistical mechanics, a general formula for the separation factor of two isotopes between gas and adsorbate phases in a monolayer, localised, immobile adsorption on a heterogeneous surface, is derived. Special forms of this are discussed for which the familiar Bigeleisen form is one. Purer, Kalplan and Smith, in their work on neon isotopes separation by gas chromatography through porous glass column at cryogenic temperatures, have reported that the separation factor first increased and then decreased as the temperature was decreased, whereas monotonic increase was the normally expected behaviour. Moiseyev has attempted to explain the anomaly after assuming two types of adsorption sites. The present theory gives the conditions in which monotonic and nonmonotonic variations can occur and after making some assumptions, the experimental curve of Purer et al could be reproduced computationally using one form of the general expression. This theoretical treatment highlights the importance of both potential energy and force constant in isotope effect whereas it is only the potential energy that is much involved in most adsorption studies. (auth.)

  7. 10 CFR 74.31 - Nuclear material control and accounting for special nuclear material of low strategic significance.

    Science.gov (United States)

    2010-01-01

    ... and maintain a measurement system which assures that all quantities in the material accounting records...) In each inventory period, control total material control and accounting measurement uncertainty so... 10 Energy 2 2010-01-01 2010-01-01 false Nuclear material control and accounting for special...

  8. Determination of cadmium, lead and zinc in a candidate reference materials using isotope dilution mass spectrometry

    International Nuclear Information System (INIS)

    Munoz, Luis; Gras, Nuri; Quejido, Alberto; Fernandez, Marta

    2001-01-01

    The growing demands placed on analytical laboratories to ensure the reliability of their results, due to the introduction of systems of quality and to the increasing use of metrology in chemical measurements has led most laboratories to validate their methodologies and to control them statistically. One of the techniques used most often for these purposes is based on the use of reference materials. The proper use of these materials means that laboratory results may be traced to the International System of Units, analytical methodologies can be validated, instruments calibrated and chemical measurements harmonized. One of the biggest challenges in developing reference materials is that of certifying their properties, a process that has been defined as assigning a concentration value that is as close as possible to the true value together with its uncertainty. Organizations that produce reference materials use several options for their certification process, and among these is the use of a primary method. Among the primary methods recognized by the International Office of Weights and Measures is the Isotope Dilution Mass Spectrometry technique. The Chilean Nuclear Energy Commission, through its Reference Materials Program, has prepared a reference material of clam tissue, which has been chemically defined by different analytical methodologies applied in different national and international laboratories. This work describes the methodology developed with the CIEMAT for determining the elements lead, cadmium and zinc in the clam tissue reference material using the primary technique of Isotope Dilution Mass Spectrometry. The calculation is described for obtaining the spike amounts to be added to the sample and the procedure is explained for carrying out the isotopic exchange. The isotopic relationships 204 Pb/ 205 Pb, 111 Cd/ 114 Cd and 66 Zn/ 67 Zn were determined in an atomic emission spectrometer with a plasma source with the following characteristics: plasma

  9. Mineral associations and character of isotopically anomalous organic material in the Tagish Lake carbonaceous chondrite

    Science.gov (United States)

    Zega, Thomas J.; Alexander, Conel M. O.'D.; Busemann, Henner; Nittler, Larry R.; Hoppe, Peter; Stroud, Rhonda M.; Young, Andrea F.

    2010-10-01

    We report a coordinated analytical study of matrix material in the Tagish Lake carbonaceous chondrite in which the same small (⩽20 μm) fragments were measured by secondary ion mass spectrometry (SIMS), transmission electron microscopy (TEM), energy-dispersive X-ray spectroscopy (EDS), electron energy-loss spectroscopy (EELS), and X-ray absorption near-edge spectroscopy (XANES). SIMS analysis reveals H and N isotopic anomalies (hotspots), ranging from hundreds to thousands of nanometers in size, which are present throughout the fragments. Although the differences in spatial resolution of the SIMS techniques we have used introduce some uncertainty into the exact location of the hotspots, in general, the H and N isotopic anomalies are spatially correlated with C enrichments, suggesting an organic carrier. TEM analysis, enabled by site-specific extraction using a focused-ion-beam scanning-electron microscope, shows that the hotspots contain an amorphous component, Fe-Ni sulfides, serpentine, and mixed-cation carbonates. TEM imaging reveals that the amorphous component occurs in solid and porous forms, EDS indicates that it contains abundant C, and EELS and XANES at the C K edge reveal that it is largely aromatic. This amorphous component is probably macromolecular C, likely the carrier of the isotopic anomalies, and similar to the material extracted from bulk samples as insoluble organic matter. However, given the large sizes of some of the hotspots, the disparity in spatial resolution among the various techniques employed in our study, and the phases with which they are associated, we cannot entirely rule out that some of the isotopic anomalies are carried by inorganic material, e.g., sheet silicates. The isotopic composition of the organic matter points to an initially primitive origin, quite possibly within cold interstellar clouds or the outer reaches of the solar protoplanetary disk. The association of organic material with secondary phases, e.g., serpentine

  10. Isotope Dilution - Thermal Ionisation Mass Spectrometric Analysis for Tin in a Fly Ash Material

    International Nuclear Information System (INIS)

    Hernandez, C.; Fernandez, M.; Quejido, A. L.

    2006-01-01

    Isotope dilution-thermal ionisation mass spectrometry (ID-TIMS) analysis has been applied to the determination of tin in a fly ash sample supplied by the EC Joint Research Centre (Ispra, Italy). The proposed procedure includes the silica gel/phosphoric acid technique for tin thermal ionisation activation and a strict heating protocol for isotope ratio measurements. Instrumental mass discrimination factor has been previously determined measuring a natural tin standard solution. Spike solutions has been prepared from 112Sn-enriched metal and quantified by reverse isotope dilution analysis. Two sample aliquots were spiked and tin was extracted with 4,5 M HCI during 25 min ultrasound esposure time. Due to the complex matrix of this fly ash material, a two-steps purification stage using ion-exchange chromatography was required prior TIMS analysis. Obtained results for the two sample-spike blends (10,10 + - 0,55 y 10,50 + - 0,64 imolg-1) are comprarable, both value and uncertainty. Also a good reproducibility is observed between measurements. The proposed ID-TIMS procedure, as a primary method and due to the lack of fly ash reference material certified for tin content, can be used to validate more routine methodologies applied to tin determination in this kind of materials. (Author) 75 refs

  11. A revision in hydrogen isotopic composition of USGS42 and USGS43 human-hair stable isotopic reference materials for forensic science

    Science.gov (United States)

    Coplen, Tyler B.; Qi, Haiping

    2016-01-01

    The hydrogen isotopic composition (δ2HVSMOW-SLAP) of USGS42 and USGS43 human hair stable isotopic reference materials, normalized to the VSMOW (Vienna-Standard Mean Ocean Water)–SLAP (Standard Light Antarctic Precipitation) scale, was originally determined with a high temperature conversion technique using an elemental analyzer (TC/EA) with a glassy carbon tube and glassy carbon filling and analysis by isotope-ratio mass spectrometer (IRMS). However, the TC/EA IRMS method can produce inaccurate δ2HVSMOW-SLAPresults when analyzing nitrogen-bearing organic substances owing to the formation of hydrogen cyanide (HCN), leading to non-quantitative conversion of a sample into molecular hydrogen (H2) for IRMS analysis. A single-oven, chromium-filled, elemental analyzer (Cr-EA) coupled to an IRMS substantially improves the measurement quality and reliability of hydrogen isotopic analysis of hydrogen- and nitrogen-bearing organic material because hot chromium scavenges all reactive elements except hydrogen. USGS42 and USGS43 human hair isotopic reference materials have been analyzed with the Cr-EA IRMS method, and the δ2HVSMOW-SLAP values of their non-exchangeable hydrogen fractions have been revised:where mUr = 0.001 = ‰. On average, these revised δ2HVSMOW-SLAP values are 5.7 mUr more positive than those previously measured. It is critical that readers pay attention to the δ2HVSMOW-SLAP of isotopic reference materials in publications as they may need to adjust the δ2HVSMOW–SLAP measurement results of human hair in previous publications to ensure all results are on the same isotope-delta scale.

  12. Source and special nuclear material sealing and labeling requirements

    International Nuclear Information System (INIS)

    Jordan, K.N.

    1978-04-01

    Purpose of this document is to define requirements for the use of tamper-indicating seals and identifying labels on SS Material containers at Rockwell Hanford Operations. The requirements defined in this document are applicable to all Rockwell Hanford Operation employees involved in handling, processing, packaging, transferring, shipping, receiving or storing SS Material

  13. A trap activation model for hydrogen retention and isotope exchange in some refractory materials

    International Nuclear Information System (INIS)

    Brice, D.K.; Doyle, B.L.

    1982-01-01

    Our recently-developed Local Mixing Model (LMM) has been successful in describing and predicting the properties of hydrogen retention and isotope exchange for a variety of refractory materials. For some materials, however, the detailed predictions of the LMM are not observed. A Trap Activation Model (TAM) is proposed here to account for the observed departures from the LMM. Comparison of experimental room temperature saturation depth profiles for H + →Si with the predictions of TAM suggests that the hydrogen traps are multiple-vacancy complexes in this system. The observed profiles result from a beam-induced competition between trap creation/annihilation and H-trapping/detrapping. (orig.)

  14. Nitrogen and carbon isotopes in soil with special reference to the diagnosis of organic matter

    International Nuclear Information System (INIS)

    Wada, Eitaro; Nakamura, Koichi.

    1980-01-01

    Distributions of nitrogen and carbon isotopes in terrestrial ecosystems are described based on available data and our recent findings for soil organic matters. Major processes regulating N-isotope and C-isotope ratios in biogenic substances are discussed. The biological di-nitrogen fixation and the precipitation are major sources which lower the delta 15 N value for forested soil organic matters. Denitrification enhances delta 15 N value for soil in cultivated fields. An addition of chemical fertilizer lowers 15 N content in soils. The permiation of soil water is an important factor controlling vertical profiles of delta 15 N in soil systems. Among soil organic matters, non-hydrolizable fraction seems to give unique low delta 15 N value, suggesting the utility of delta 15 N analysis in studying the nature of the fractions. delta 13 C of soil organic matter is significantly lower than that for marine sediments. delta 13 C for soil humus varies with respect to chemical forms as well as an age of soil organic matters. The variation is large in paddy fields. It is, thus, probable that delta 13 C is an useful parameter in studying the early epidiagenesis of soil organic matters. Based on the known delta 15 N-delta 13 C relationships, a two-source mixing model has been applied to assess sources of organic matters in coastal sediment. (author)

  15. Accounting systems for special nuclear material control. Technical report

    International Nuclear Information System (INIS)

    Korstad, P.A.

    1980-05-01

    Nuclear material accounting systems were examined and compared to financial double-entry accounting systems. Effective nuclear material accounting systems have been designed using the principles of double-entry financial accounting. The modified double-entry systems presently employed are acceptable if they provide adequate control over the recording and summarizing of transactions. Strong internal controls, based on principles of financial accounting, can help protect nuclear materials and produce accurate, reliable accounting data. An electronic data processing system can more accurately maintain large volumes of data and provide management with more current, reliable information

  16. Automatic isotope gas analysis of tritium labelled organic materials Pt. 1

    International Nuclear Information System (INIS)

    Gacs, I.; Mlinko, S.

    1978-01-01

    A new automatic procedure developed to convert tritium in HTO hydrogen for subsequent on-line gas counting is described. The water containing tritium is introduced into a column prepared from molecular sieve-5A and heated to 550 deg C. The tritium is transferred by isotopic exchange into hydrogen flowing through the column. The radioactive gas is led into an internal detector for radioactivity measurement. The procedure is free of memory effects, provides quantitative recovery with analytical reproducibility better than 0.5% rel. at a preset number of counts. The experimental and analytical results indicate that isotopic exchange between HTO and hydrogen over a column prepared from alumina or molecular sieve-5A can be successfully applied for the quantitative transfer of tritium from HTO into hydrogen for on-line gas countinq. This provides an analytical procedure for the automatic determination of tritium in water with an analytical reproducibility better than 0.5% rel. The exchange process will also be suitable for rapid tritium transfer from water formed during the decomposition of tritium-labelled organic compounds or biological materials. The application of the procedure in automatic isotope gas analysis of organic materials labelled with tritium will be described in subsequent papers (Parts II and III). (T.G.)

  17. Recycled materials in geotechnical applications. Geotechnical special publication No. 79

    Energy Technology Data Exchange (ETDEWEB)

    Vipulanandan, C.; Elton, D.J. [eds.

    1998-07-01

    Recycled materials have the potential for use in a variety of geotechnical and geoenvironmental applications. This proceedings contains 15 papers on field applications and laboratory testing related to recycled materials. Papers cover: geotechnics of industrial by-products; paper mill sludge for landfill cover; mitigation of void development under bridge approach slabs using rubber tire chips; tire shreds as lightweight fill for embankments and retaining walls; performance of a highway embankment and hydraulic barriers constructed using waste foundry sand, and recycled materials; lagoon-stored lime for embankment; construction and demolition debris for base and subbase applications; fly ash for fill, pavement, earth structures and aggregate; compaction of contaminated soils-reuse as a road base material; and database on beneficial reuse of foundry by-products; and more.

  18. Real-Time Characterization of Special Nuclear Materials

    Energy Technology Data Exchange (ETDEWEB)

    Walston, Sean [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Candy, Jim [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Chambers, Dave [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Chandrasekaran, Hema [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Snyderman, Neal [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

    2015-09-04

    When confronting an item that may contain nuclear material, it is urgently necessary to determine its characteristics. Our goal is to provide accurate information with high-con dence as rapidly as possible.

  19. Strategy of radioactive waste management of special materials

    International Nuclear Information System (INIS)

    Bruecher, H.; Merz, E.

    1986-11-01

    Special attention is being paid to the treatment and disposal of the volatile radionuclides tritium, carbon-14, krypton-85, and iodine-129 arising from reprocessing of spent nuclear fuel. This is shown by a large number of investigations on this subject as well as the 1983 recommendation of the German Radiation Protection Commission. In the present study, recent investigations on these four nuclides have been analysed, and it has been tried to draw conclusions for the realisation of the management concept for these radionuclides. (orig.) [de

  20. Automatic isotope gas analysis of tritium labelled organic materials Pt. 3

    International Nuclear Information System (INIS)

    Gacs, I.; Mlinko, S.; Payer, K.; Otvos, L.; Banfi, D.; Palagyi, T.

    1978-01-01

    An isotope analytical procedure and an automatic instrument developed for the determination of tritium in organic compounds and biological materials by internal gas counting are described. The sample is burnt in a stream of oxygen and the combustion products including water vapour carrying the tritium are led onto a column of molecular sieve-5A heated to 550 deg C. Tritium is retained temporarily on the column, then transferred into a stream of hydrogen by isotope exchange. After addition of butane, the tritiated hydrogen is led into an internal detector and enclosed there for radioactivity measurement. The procedure, providing quantitative recovery, is completed in five minutes. It is free of memory effect and suitable for the determination of tritium in a wide range of organic compounds and samples of biological origin. (author)

  1. Dating of oilfield contamination by Natural Occurring Radioactive Materials (NORM) using isotopic ratios

    International Nuclear Information System (INIS)

    Al-Masri, M. S.; Othman, I.; Aba, A.

    2008-05-01

    In the present work, the possibility of using radium isotope ratios (226, 224, 228) for dating of NORM contaminated sites in the oilfields due to uncontrolled disposal of produced water into the environmental NORM contaminated soil sample were collected from different locations in Syrian Oilfields and radioactivity analysed. In addition, production water samples were collected and analysed to determine the isotopes ratios of the naturally occurring radioactive materials. The results have shown that the 228 Ra/ 226 Ra can be successfully used to date contaminated soil provided that this ratio is determined in production water. Moreover, the 210 Pb/ 226 Ra activity ratios was used for the first time for dating of contaminated soil where all factors affecting the method application have been evaluated. Furthermore, the obtained results for dating using the three methods were compared with the actual contamination dates provided by the oil companies. (Authors)

  2. Isotopes: technologies, materials and application. II International scientific conference of young scientists, post-graduate students and students. Book of abstracts

    International Nuclear Information System (INIS)

    2015-01-01

    The collection contains materials of abstracts of the conference participants to sum up the experience of research and development in the field of isotope production technologies, the use of compounds specified isotopic composition in different sectors of the economy, as well as the disposal and storage technology of the isotope production wastes. Advanced ideas produce isotopes of rare elements for medicine, microelectronics and nuclear industries are presented. Prospectively projects of scientists of Tomsk Polytechnic University in isotope modifying substances are discussed [ru

  3. Mandatory special or dedicated trains for radioactive materials shipments evidence shows they're not needed

    International Nuclear Information System (INIS)

    Goodman, L.S.; Garrison, R.F.; Harmon, L.H.

    1988-01-01

    The rejection of mandatory special or dedicated trains by all responsible Federal agencies for transportation of radioactive materials in shielded casks has a long history. Working with the railroads and the National Academy of Sciences, the ICC adopted standards for transporting radioactive materials in regular freight trains in the mid 1940's. The standards rested primarily on ensuring the integrity of the radioactive materials packaging. AEC, then NRC and DOT, followed the ICC lead, supplementing the licensing rules for casks with a series of performance or stress tests. At no time did these agencies require special trains or special routing for rail casks. Mandatory special trains have too many disadvantages without any proven safety benefit to be worth their high cost to the shipper. The ICC, in a series of litigated cases, found that given the strength of the casks, mandatory special trains were wasteful transportation and an unreasonable railroad practice

  4. 49 CFR 173.476 - Approval of special form Class 7 (radioactive) materials.

    Science.gov (United States)

    2010-10-01

    ... (radioactive) materials must maintain on file for at least one year after the latest shipment, and provide to... evidence based on calculative methods to show that the material is able to pass the tests; or other... shipping papers as “Radioactive Material, Special Form, n.o.s.” [Amdt. 173-244, 60 FR 50307, Sept. 28, 1995...

  5. Special nuclear materials cutoff exercise: Issues and lessons learned. Volume 3

    Energy Technology Data Exchange (ETDEWEB)

    Libby, R.A.; Segal, J.E.; Stanbro, W.D.; Davis, C.

    1995-08-01

    This document is appendices D-J for the Special Nuclear Materials Cutoff Exercise: Issues and Lessons Learned. Included are discussions of the US IAEA Treaty, safeguard regulations for nuclear materials, issue sheets for the PUREX process, and the LANL follow up activity for reprocessing nuclear materials.

  6. Special nuclear materials cutoff exercise: Issues and lessons learned. Volume 3

    International Nuclear Information System (INIS)

    Libby, R.A.; Segal, J.E.; Stanbro, W.D.; Davis, C.

    1995-08-01

    This document is appendices D-J for the Special Nuclear Materials Cutoff Exercise: Issues and Lessons Learned. Included are discussions of the US IAEA Treaty, safeguard regulations for nuclear materials, issue sheets for the PUREX process, and the LANL follow up activity for reprocessing nuclear materials

  7. Reexamination of the source material of acid igneous rocks, based on the selected Sr isotopic data

    International Nuclear Information System (INIS)

    Kagami, Hiroo; Shuto, Kenji; Gorai, Masao

    1975-01-01

    The relation between the ages and the initial strontium isotopic compositions obtained from acid igneous rocks by the whole-rock isochron method is re-examined, on the basis of the selected data. The points based on the data having high values of standard deviation (on the isochrons) show considerable scattering. This is probably ascribed to admixture of sialic materials, or secondary alteration and other geologic causes. The points based on the data having lower values of standard deviation (sigma value: 0.0001 - 0.0019), on the other hand, are evidently plotted within a narrow region just above the presumed Sr evolutional region of the source material of oceanic tholeiites. It is noteworthy that the former region meets the latter region at an earlier stage of the evolutional history of the earth (about 40 x 10 8 yrs. ago or older). It may be conceivable that the former region is the Sr evolutional region of the source material of acid igneous rocks. Considering from the inclination of the above Sr evolutional region, the source material of most of acid igneous rocks may possibly be a certain basic material, chemically similar to the continental tholeiitic basalts or basaltic andesites. On the other hand, the source material of a few acid igneous rocks with low initial strontium isotopic ratios may be a certain basic material resembling the oceanic tholeiites. Another possibility is that these acid igneous rocks and oceanic tholeiites may have been formed, under different physical conditions, directly from a certain common source material presumably of peridotitic composition. (auth.)

  8. {sup 3}He detector analysis of some special shielding materials

    Energy Technology Data Exchange (ETDEWEB)

    Avdic, S; Pesic, M [Boris Kidric, Institute of Nuclear Sciences, Beograd (Yugoslavia); Marinkovic, P [ETF Belgrade Univ. (Yugoslavia)

    1990-07-01

    The shielding properties of commercial materials of reactor Experiments, Inc. (R/X) were analyzed at the facility which includes bare heavy water experimental reactor RB with external neutron converter ENC, The fast neutron spectrum measurements in energy range from 1 MeV to 10 MeV was performed using ORTEC semiconductor neutron detector with He{sup 3} in diode coincidence arrangement. The neutron spectra have been evaluated from measured pulse-height distribution using numerical code HE3 for computation of detector efficiency in a collimated neutron beam. The neutron dose rates behind ENC with and without sample R/X material were determined using cubic spline interpolation routine for calculating the corresponding flux-dose rate conversion factors. Satisfactory shielding properties of the examined material in a fast neutron field in measurements and calculations are demonstrated. (author)

  9. Introduction to Special Edition (of the Journal of Nuclear Materials Management) on Reducing the Threat from Radioactive Materials

    International Nuclear Information System (INIS)

    Mladineo, Stephen V.

    2007-01-01

    Introductory article for special edition of the JOURNAL OF NUCLEAR MATERIALS MANAGEMENT outlining the Institute of Nuclear Materials Management Nonproliferation and Arms Control Technical Division. In particular the International Nuclear and Radiological Security Standing Committee and its initial focus covering four topical areas--Radiological Threat Reduction, Nuclear Smuggling and Illicit Trafficking, Countering Nuclear Terrorism, and Radiological Terrorism Consequence Management

  10. Vulnerability Analysis Considerations for the Transportation of Special Nuclear Material

    International Nuclear Information System (INIS)

    Nicholson, Lary G.; Purvis, James W.

    1999-01-01

    The vulnerability analysis methodology developed for fixed nuclear material sites has proven to be extremely effective in assessing associated transportation issues. The basic methods and techniques used are directly applicable to conducting a transportation vulnerability analysis. The purpose of this paper is to illustrate that the same physical protection elements (detection, delay, and response) are present, although the response force plays a dominant role in preventing the theft or sabotage of material. Transportation systems are continuously exposed to the general public whereas the fixed site location by its very nature restricts general public access

  11. Development of soft magnetic materials with special properties

    International Nuclear Information System (INIS)

    Mager, A.

    1979-01-01

    New steps in the development of soft magnetic alloys are based on a better understanding of the magnetizing processes in close connection with the development of magnetic forms and components for different applications. New result on the influence of crystal grains, inclusions, and mechanical stresses on the soft magnetic properties of Ni-Fe-alloys with ca. 50 to 75% Nickel-contents are given. Special soft magnetic alloys were developed and improved for low temperature applications, for small temperature coefficients, for different shapes of hysteresis loops, or for high wear resistance - and moreover forms, components, and basic designs of chokes for RFI suppression, of transformers for electronic power supplies, of transformers for ground-fault interrupters, and for magnetic shielding equipments. (orig.) 891 GSC/orig. 892 AV [de

  12. Special Issue: 15 Years of SU8 as MEMS Material

    Directory of Open Access Journals (Sweden)

    Arnaud Bertsch

    2015-06-01

    Full Text Available In 1997, the first paper using SU-8 as a material for microfabrication was published [1], demonstrating the interest of this negative photoresist for the near-UV structuration of thick layers and the manufacturing of high aspect-ratio components.[...

  13. Growing a Primary Science Specialism: Assembling People, Places, Materials and Ideas

    Science.gov (United States)

    Lynch, Julianne; Frankel, Nadine; McCarthy, Kerry; Sharp, Lindy

    2015-01-01

    This paper derives from the authors' experiences of the development of a successful science specialism implemented in a large primary school in regional Victoria, Australia, since 2012. We discuss how diverse resources--people, spaces, equipment, materials and ideas--were brought together to support a science specialism that focuses on positioning…

  14. 10 CFR 70.20a - General license to possess special nuclear material for transport.

    Science.gov (United States)

    2010-01-01

    ... 10 Energy 2 2010-01-01 2010-01-01 false General license to possess special nuclear material for transport. 70.20a Section 70.20a Energy NUCLEAR REGULATORY COMMISSION (CONTINUED) DOMESTIC LICENSING OF... transport. (a) A general license is issued to any person to possess formula quantities of strategic special...

  15. Special from encapsulation for radioactive material shipments from Oak Ridge National Laboratory

    International Nuclear Information System (INIS)

    Schaich, R.W.

    1980-01-01

    Special Form encapsulation has been used at Oak Ridge National Laboratory to ship radioactive solids for the past fifteen years. A family of inexpensive stainless steel containers has been developed and tested to meet the USA Department of Transportation (DOT) and the International Atomic Energy Agency (IAEA) regulations concerning radioactive material shipments as Special Form

  16. Special purpose materials: an assessment of needs and the role of these materials in the national program

    International Nuclear Information System (INIS)

    Gold, R.E.; Clinard, F.W. Jr.; Davis, J.W.

    1978-01-01

    The scope of activities of the Task Group on Special Purpose Materials includes those materials requirements not specifically addressed by the other OFE materials task groups. These materials can be organized according to seven broad materials applications or functions which appear to be generic to all magnetically confined fusion reactor concepts. These are breeding materials, coolants, materials for tritium service, graphite and silicon carbide, electrical insulators and ceramics, heat-sink materials, and magnet materials. The present paper describes the importance of each of these areas of materials technology, outlines major problems or areas of uncertainty, and reviews past and current contributions to our state of understanding as it may relate to fusion power applications

  17. Nanoporous materials for hydrogen storage and H2/D2 isotope separation

    International Nuclear Information System (INIS)

    Oh, Hyunchul

    2014-01-01

    This thesis presents a study of hydrogen adsorption properties at RT with noble metal doped porous materials and an efficient separation of hydrogen isotopes with nanoporous materials. Most analysis is performed via thermal desorption spectra (TDS) and Sieverts-type apparatus. The result and discussion is presented in two parts; Chapter 4 focuses on metal doped nanoporous materials for hydrogen storage. Cryogenic hydrogen storage by physisorption on porous materials has the advantage of high reversibility and fast refuelling times with low heat evolution at modest pressures. At room temperature, however, the physisorption mechanism is not abEle to achieve enough capacity for practical application due to the weak van der Waals interaction, i.e., low isosteric heats for hydrogen sorption. Recently, the ''spillover'' effect has been proposed by R. Yang et al. to enhance the room temperature hydrogen storage capacity. However, the mechanism of this storage enhancement by decoration of noble metal particles inside high surface area supports is not yet fully understood and still under debate. In this chapter, noble metal (Pt / Pd) doped nanoporous materials (i.e. porous carbon, COFs) have been investigated for room temperature hydrogen storage. Their textural properties and hydrogen storage capacity are characterized by various analytic techniques (e.g. SEM, HRTEM, XRD, BET, ICP-OES, Thermal desorption spectra, Sievert's apparatus and Raman spectroscopy). Firstly, Pt-doped and un-doped templated carbons possessing almost identical textural properties were successfully synthesized via a single step wet impregnation method. This enables the study of Pt catalytic activities and hydrogen adsorption kinetics on porous carbons at ambient temperature by TDS after H 2 /D 2 gas exposure and PCT measurement, respectively. While the H 2 adsorption kinetics in the microporous structure is enhanced by Pt catalytic activities (spillover), only a small enhancement of the hydrogen

  18. Stable isotope evidence of meat eating and hunting specialization in adult male chimpanzees

    Science.gov (United States)

    Fahy, Geraldine E.; Richards, Michael; Riedel, Julia; Hublin, Jean-Jacques; Boesch, Christophe

    2013-01-01

    Observations of hunting and meat eating in our closest living relatives, chimpanzees (Pan troglodytes), suggest that among primates, regular inclusion of meat in the diet is not a characteristic unique to Homo. Wild chimpanzees are known to consume vertebrate meat, but its actual dietary contribution is, depending on the study population, often either unknown or minimal. Constraints on continual direct observation throughout the entire hunting season mean that behavioral observations are limited in their ability to accurately quantify meat consumption. Here we present direct stable isotope evidence supporting behavioral observations of frequent meat eating among wild adult male chimpanzees (Pan troglodytes verus) in Taï National Park, Côte d’Ivoire. Meat eating among some of the male chimpanzees is significant enough to result in a marked isotope signal detectable on a short-term basis in their hair keratin and long-term in their bone collagen. Although both adult males and females and juveniles derive their dietary protein largely from daily fruit and seasonal nut consumption, our data indicate that some adult males also derive a large amount of dietary protein from hunted meat. Our results reinforce behavioral observations of male-dominated hunting and meat eating in adult Taï chimpanzees, suggesting that sex differences in food acquisition and consumption may have persisted throughout hominin evolution, rather than being a recent development in the human lineage. PMID:23530185

  19. Isotope dilution surface ionization mass spectrometry of silver in environmental materials

    Energy Technology Data Exchange (ETDEWEB)

    Murozumi, M; Nakamura, S; Suga, K [Muroran Inst. of Tech., Hokkaido (Japan)

    1981-03-01

    Surface ionization mass spectrometry has been developed to measure isotopic abundances and concentrations of silver in commercial high-purity metals, environmental materials such as rocks and plants, and /sup 109/Ag and /sup 107/Ag spikes. A minute amount of silver is extracted into a dithizone chloroform solution from a nitric acid solution of above samples. After the silver is back-extracted into 6.0 ml of a 7 mol/l HNO/sub 3/ solution, the solution is evaporated to dryness under the nitrogen atmosphere. Silver nitrate thus formed is dissolved in a mixture of 60 ..mu..l of an 0.003% silica gel suspended water and 5 ..mu..l of a 2% phosphoric acid. An aliquot of this solution is applied to the mass spectrometry using a rhenium single filament as an ion emitter. The proposed method can detect the presence of 10/sup -14/ g of silver on the ion emitter, and measure the /sup 109/Ag//sup 107/Ag isotopic ratio in environmental materials with the accuracy of 0.1 -- 0.2% in the coefficient of variation. Isotope dilution mass spectrometry using a /sup 107/Ag spike has revealed the silver concentration in the environmental standard materials, which were prepared by the National Bureau of Standards, U.S.A. and National Institute of Environmental Studies of Japan, as follows; 27.9 +- 0.2 ppb for the Orchard Leaves and 34.3 +- 0.3 ppb in the Pepper Bush. The determined values of silver in the Granodiorite, JG-1, and Basalt, JB-1 powders made by the Geological Survey of Japan are 25.4 +- 0.4 ppb and 41.3 +- 0.1 ppb respectively. Silver concentration in a coastal sea water sample is found to be at the level of 2.5 +- 0.4 ppt.

  20. Errors of isotope conveyor weigher caused by profile variations and shift of material

    International Nuclear Information System (INIS)

    Machaj, B.

    1977-01-01

    Results of investigations of isotope conveyor weigher in transmission geometry and with long plastic scintillator as a detector are presented in the paper. The results indicate that errors caused by material shift across the conveyor belt can be decreased by forming probe sensitivity to incident radiation along its axis by means of additional radiation absorbents. The errors caused by material profile variations can effectively be diminished by increase of photon energy. Application of 60 Co instead of 137 Cs ensured more than three times lower errors caused by profile variation. Errors caused by vertical movements of the belt with material, decrease considerably, when single point source situated in the center of the measuring head is replaced at least by two point sources situated out of the center, above the edges of the belt. (author)

  1. Special-purpose materials for magnetically confined fusion reactors. Third annual progress report

    International Nuclear Information System (INIS)

    1981-11-01

    The scope of Special Purpose Materials covers fusion reactor materials problems other than the first-wall and blanket structural materials, which are under the purview of the ADIP, DAFS, and PMI task groups. Components that are considered as special purpose materials include breeding materials, coolants, neutron multipliers, barriers for tritium control, materials for compression and OH coils and waveguides, graphite and SiC, heat-sink materials, ceramics, and materials for high-field (>10-T) superconducting magnets. It is recognized that there will be numerous materials problems that will arise during the design and construction of large magnetic-fusion energy devices such as the Engineering Test Facility (ETF) and Demonstration Reactor (DEMO). Most of these problems will be specific to a particular design or project and are the responsibility of the project, not the Materials and Radiation Effects Branch. Consequently, the Task Group on Special Purpose Materials has limited its concern to crucial and generic materials problems that must be resolved if magnetic-fusion devices are to succeed. Important areas specifically excluded include low-field (8-T) superconductors, fuels for hybrids, and materials for inertial-confinement devices. These areas may be added in the future when funding permits

  2. Isotope-beam modification of materials at eV energies

    International Nuclear Information System (INIS)

    Krug, C.; Radtke, C.; Stedile, F.C.; Baumvol, I.J.R.

    2001-01-01

    We developed a low energy ion beam deposition system for isotope-selective modification of materials. It consists of a conventional ion implanter (HVEE 500 kV) and an attachable deceleration system. 29 (N 2 ) + ion beams were used for the nitridation of Si(0 0 1) and the resulting 15 N retained doses and profiles were determined by narrow nuclear resonance profiling. 29 Si was deposited on amorphous carbon films on Si(0 0 1) and the doses evaluated by channeled α particle beams with detection of scattered α at grazing angles. 29 Si was also deposited on Si(0 0 1) and the resulting profiles determined by narrow nuclear resonance

  3. Compilation of minimum and maximum isotope ratios of selected elements in naturally occurring terrestrial materials and reagents

    Science.gov (United States)

    Coplen, T.B.; Hopple, J.A.; Böhlke, J.K.; Peiser, H.S.; Rieder, S.E.; Krouse, H.R.; Rosman, K.J.R.; Ding, T.; Vocke, R.D.; Revesz, K.M.; Lamberty, A.; Taylor, P.; De Bievre, P.

    2002-01-01

    Documented variations in the isotopic compositions of some chemical elements are responsible for expanded uncertainties in the standard atomic weights published by the Commission on Atomic Weights and Isotopic Abundances of the International Union of Pure and Applied Chemistry. This report summarizes reported variations in the isotopic compositions of 20 elements that are due to physical and chemical fractionation processes (not due to radioactive decay) and their effects on the standard atomic weight uncertainties. For 11 of those elements (hydrogen, lithium, boron, carbon, nitrogen, oxygen, silicon, sulfur, chlorine, copper, and selenium), standard atomic weight uncertainties have been assigned values that are substantially larger than analytical uncertainties because of common isotope abundance variations in materials of natural terrestrial origin. For 2 elements (chromium and thallium), recently reported isotope abundance variations potentially are large enough to result in future expansion of their atomic weight uncertainties. For 7 elements (magnesium, calcium, iron, zinc, molybdenum, palladium, and tellurium), documented isotope-abundance variations in materials of natural terrestrial origin are too small to have a significant effect on their standard atomic weight uncertainties. This compilation indicates the extent to which the atomic weight of an element in a given material may differ from the standard atomic weight of the element. For most elements given above, data are graphically illustrated by a diagram in which the materials are specified in the ordinate and the compositional ranges are plotted along the abscissa in scales of (1) atomic weight, (2) mole fraction of a selected isotope, and (3) delta value of a selected isotope ratio. There are no internationally distributed isotopic reference materials for the elements zinc, selenium, molybdenum, palladium, and tellurium. Preparation of such materials will help to make isotope ratio measurements among

  4. An enhanced search methodology for special nuclear materials

    International Nuclear Information System (INIS)

    Carichner, S.

    1996-06-01

    This report is an overview of the first phase of work done to use data fusion to improve the search process for weaponizable radioactive materials. Various methods were examined to provide a system-level optimization to the problem. Data fusion signal- processing techniques using sensor counts and sensor position information with reasonable computation time showed an initial four- fold improvement in the overall search system performance compared to optimal processing without knowledge of sensor position. With the inclusion of data visualization techniques, a centralized search controller has access to information that improves the main search parameters: range, search time, and search confidence. The improvement is significant enough to justify the next phase of work which includes: adding neutron sensor data, investigating the position location system, and further tests and refinements of the system

  5. Criteria for cesium capsules to be shipped as special form radioactive material

    International Nuclear Information System (INIS)

    Lundeen, J.E.

    1994-01-01

    The purpose of this report is to compile all the documentation which defines the criteria for Waste Encapsulation and Storage Facility (WESF) cesium capsules at the IOTECH facility and Applied Radiant Energy Corporation (ARECO) to be shipped as special form radioactive material in the Beneficial Uses Shipping System (BUSS) Cask. The capsules were originally approved as special form in 1975, but in 1988 the integrity of the capsules came into question. WHC developed the Pre-shipment Acceptance Test Criteria for capsules to meet in order to be shipped as special form material. The Department of Energy approved the criteria and directed WHC to ship the capsules at IOTECH and ARECO meeting this criteria to WHC as special form material

  6. Contribution of bulk mass spectrometry isotopic analysis to characterization of materials in the framework of CMX-4

    International Nuclear Information System (INIS)

    Kuchkin, A.; Stebelkov, V.; Zhizhin, K.; Lierse von Gostomski, Ch.; Kardinal, Ch.; Loi, E.; Keegan, E.; Kristo, M.J.

    2018-01-01

    Seven laboratories used the results of bulk uranium isotopic analysis by either inductively coupled plasma mass spectrometry (ICP-MS) or thermal ionization mass spectrometry (TIMS) for characterization of the samples in the Nuclear Forensic International Technical Working Group fourth international collaborative material exercise, CMX-4. Comparison of the measured isotopic compositions of uranium in three exercise samples is implemented for identifying any differences or similarities between the samples. The role of isotopic analyses in the context of a real nuclear forensic investigation is discussed. Several limitations in carrying out ICP-MS or TIMS analysis in CMX-4 are noted. (author)

  7. Preparation and certification of a uranium isotope certified reference material JAERI-U5

    International Nuclear Information System (INIS)

    Tamura, Shuzo; Hashitani, Hiroshi

    1982-06-01

    The Committee on Analytical Chemistry of Nuclear Fuels and Reactor Materials, JAERI had planned to prepare a new reference material, JAERI-U5 for uranium isotopic measurement since 1978. The reference material is composed of 6 samples of different enrichment in the range of 0.2 to 4.5 wt. percents of 235 U. The preparation includes dissolution of raw materials, blending of solutions, precipitation of ammonium diuranate, drying and ignition to U 3 O 8 . A mass-spectrometric collaborative analysis was carried out by well-trained two laboratories in this country, JAERI and PNC. The certified values were decided from the result of the collaborative work. As the measurements were based on NBS SRM's, JAERI-U5 should be called tertiary standard. The materials are packed in bottles of low-potassium-content glass for a possible use in non-destructive gamma-rays spectrometry. The reference material has been distributing from JAERI with a price of yen 140,000 per set (6 samples of 2 g of each) since 1979. (author)

  8. 78 FR 38739 - Special Nuclear Material Control and Accounting Systems for Nuclear Power Plants

    Science.gov (United States)

    2013-06-27

    ... Systems for Nuclear Power Plants AGENCY: Nuclear Regulatory Commission. ACTION: Regulatory guide; issuance... Guide (RG) 5.29, ``Special Nuclear Material Control and Accounting Systems for Nuclear Power Plants... material control and accounting. This guide applies to all nuclear power plants. ADDRESSES: Please refer to...

  9. Microcomputer based shelf system to monitor special nuclear materials in storage

    International Nuclear Information System (INIS)

    Nicholson, N.; Kuckertz, T.H.; Ethridge, C.D.

    1980-01-01

    Diversion of special nuclear material has become a matter of grave concern in recent years. Large quantities of this material are kept in long-term storage and must be inventoried periodically, resulting in a time-consuming activity that exposes personnel to additional radiation. A system that provides continuous surveillance of stored special nuclear materials has been developed. A shelf monitor has been designed using a single component microcomputer to collect data from a Geiger Muller tube that monitors gamma emissions and a scale that monitors the total weight of the special nuclear material and its container. A network of these shelf monitors reports their acquired data to a minicomputer for analysis and storage. Because a large number of these monitors is likely to be needed in most storage facilities, one objective of this program has been to develop a low cost but reliable monitor

  10. Semi-annual report on strategic special nuclear material inventory differences

    International Nuclear Information System (INIS)

    1981-08-01

    This eighth periodic semiannual report of inventory differences covers the second six months of fiscal year 1980 (April 1, 1980, through September 30, 1980), for the Department of Energy (DOE) and DOE contractor facilities possessing significant quantities of strategic special nuclear material. Strategic special nuclear material is plutonium or uranium-233 or uranium-235 in material whose uranium-235 content is 20 percent or greater (known as highly enriched uranium). A significant quantity is either 2 kilograms of plutonium or uranium-233 or 5 kilograms of uranium-235 in highly enriched uranium or the appropriate weighted combination. All Inventory Differences reported here have been analyzed, investigated when necessary, and resolved. These data and explanations, together with the absences of physical indications of any theft attempt, support a finding that during this period no theft or diversion of strategic special nuclear material has occurred

  11. Isotope enrichment

    International Nuclear Information System (INIS)

    Garbuny, M.

    1979-01-01

    The invention discloses a method for deriving, from a starting material including an element having a plurality of isotopes, derived material enriched in one isotope of the element. The starting material is deposited on a substrate at less than a critical submonatomic surface density, typically less than 10 16 atoms per square centimeter. The deposit is then selectively irradiated by a laser (maser or electronic oscillator) beam with monochromatic coherent radiation resonant with the one isotope causing the material including the one istope to escape from the substrate. The escaping enriched material is then collected. Where the element has two isotopes, one of which is to be collected, the deposit may be irradiated with radiation resonant with the other isotope and the residual material enriched in the one isotope may be evaporated from the substrate and collected

  12. Platinum stable isotope analysis of geological standard reference materials by double-spike MC-ICPMS.

    Science.gov (United States)

    Creech, J B; Baker, J A; Handler, M R; Bizzarro, M

    2014-01-10

    We report a method for the chemical purification of Pt from geological materials by ion-exchange chromatography for subsequent Pt stable isotope analysis by multiple-collector inductively coupled plasma mass spectrometry (MC-ICPMS) using a 196 Pt- 198 Pt double-spike to correct for instrumental mass bias. Double-spiking of samples was carried out prior to digestion and chemical separation to correct for any mass-dependent fractionation that may occur due to incomplete recovery of Pt. Samples were digested using a NiS fire assay method, which pre-concentrates Pt into a metallic bead that is readily dissolved in acid in preparation for anion-exchange chemistry. Pt was recovered from anion-exchange resin in concentrated HNO 3 acid after elution of matrix elements, including the other platinum group elements (PGE), in dilute HCl and HNO 3 acids. The separation method has been calibrated using a precious metal standard solution doped with a range of synthetic matrices and results in Pt yields of ≥90% with purity of ≥95%. Using this chemical separation technique, we have separated Pt from 11 international geological standard reference materials comprising of PGE ores, mantle rocks, igneous rocks and one sample from the Cretaceous-Paleogene boundary layer. Pt concentrations in these samples range from ca. 5 ng g -1 to 4 μg g -1 . This analytical method has been shown to have an external reproducibility on δ 198 Pt (permil difference in the 198 Pt/ 194 Pt ratio from the IRMM-010 standard) of ±0.040 (2 sd) on Pt solution standards (Creech et al., 2013, J. Anal. At. Spectrom. 28, 853-865). The reproducibility in natural samples is evaluated by processing multiple replicates of four standard reference materials, and is conservatively taken to be ca. ±0.088 (2 sd). Pt stable isotope data for the full set of reference materials have a range of δ 198 Pt values with offsets of up to 0.4‰ from the IRMM-010 standard, which are readily resolved with this technique. These

  13. The Influence of Irradiation Regimes on Retention Hydrogen Isotopes in Structural Materials

    International Nuclear Information System (INIS)

    Zaluzhnyi, A.

    2007-01-01

    Full text of publication follows: In the present work was investigated the influence of irradiation regimes on retention hydrogen isotopes in samples of austenitic steel during heating. The samples of studied materials were irradiated both in the reactor and by hydrogen isotopes ions of different energies and fluencies bombardment in an accelerator. Kinetic of hydrogen release from the samples worked with deuterium plasma was investigated. The following results were obtained. Heating the irradiate d samples of steel (irradiated in the reactor or by hydrogen isotopes ions bombardment), which have been kept in normal temperature during quite a long period after the irradiation, a shift of the diffusion peak of hydrogen release to higher temperatures, comparing to no irradiated samples, was observed. It means that atoms of hydrogen in the irradiated sample were caught by radiation defects, which are very effective as traps for hydrogen atoms till quite high temperatures (700 K). The worked out analysis of the received results supposes that vacancy complexes. On thermodesorption curves of hydrogen release from irradiated samples of austenitic steels a high temperature peak (900-1000 K) was observed because of dissociation of hydrogen containing compounds in micro pores. During investigations of hydrogen release from irradiated samples of austenitic steel, after it had been saturated with hydrogen plasma, abnormally big blisters were registered with cover thickness of about 1 mkm. Three peaks were observed on the thermodesorption curves of hydrogen release from irradiated samples, contained blisters. The low temperature spike (∼500 K) was showed to correspond to hydrogen release because of its resolution from blisters, where it was in molecular form. The high temperature peak (∼900 K) corresponds to hydrogen release from dissociating blisters, which contain hydrocarbons. The mechanism of abnormal blisters generation is offered. Inasmuch methane is not soluble in

  14. Directory of national competent authorities' approval certificates for packages, shipments, special arrangements and special form radioactive material

    International Nuclear Information System (INIS)

    1987-11-01

    The Agency's transport regulations prescribe various requirements for the authorization of packages and shipments in respect of both national and international movement of radioactive material. These authorizations are issued by the relevant competent authority of the country concerned; they take the form of package approval and/or shipment approval certificates. At the request of the Standing Advisory Group of the Safe Transport of Radioactive Material (SAGSTRAM), the Agency has established a programme to maintain a file of those certificates for packages and shipments which are either transported internationally or used outside the country of origin. The purpose of this directory is to facilitate the transfer of information to competent authorities and any other person wishing details on the packaging, authorized contents or special conditions pertinent to any package or shipment. The directory enables competent authorities to be aware of the status of any certificate submitted for validation. It also indicates any change in status of any certificate already validated

  15. Estimated long lived isotope activities in ET-RR-1 reactor structural materials for decommissioning study

    International Nuclear Information System (INIS)

    Ashoub, N.; Saleh, H.

    1995-01-01

    The first Egyptian research reactor, ET-RR-1 is tank type with light water as a moderator, coolant and reflector. Its nominal power is 2MWt and the average thermal neutron flux is 10 13 n/cm 2 sec -1 . Its criticality was on the fall of 1961. The reactor went through several modifications and updating and is still utilized for experimental research. A plan for decommissioning of ET-RR-1 reactor should include estimation of radioactivity in structural materials. The inventory will help in assessing the radiological consequences of decommissioning. This paper presents a conservative calculation to estimate the activity of the long lived isotopes which can be produced by neutron activation. The materials which are presented in significant quantities in the reactor structural materials are aluminum, cast iron, graphite, ordinary and iron shot concrete. The radioactivity of each component is dependent not only upon the major elements, but also on the concentration of the trace elements. The main radioactive inventory are expected to be from 60 Co and 55 Fe which are presented in aluminium as trace elements and in large quantities in other construction materials. (author)

  16. A method for assay of special nuclear material in high level liquid waste streams

    International Nuclear Information System (INIS)

    Venkata Subramani, C.R.; Swaminathan, K.; Asuvathraman, R.; Kutty, K.V.G.

    2003-01-01

    The assay of special nuclear material in the high level liquid waste streams assumes importance as this is the first stage in the extraction cycle and considerable losses of plutonium could occur here. This stream contains all the fission products as also the minor actinides and hence normal nuclear techniques cannot be used without prior separation of the special nuclear material. This paper presents the preliminary results carried out using wavelength dispersive x-ray fluorescence as part of the developmental efforts to assay SNM in these streams by instrumental techniques. (author)

  17. Performance of alpha spectrometry in the analysis of uranium isotopes in environmental and nuclear materials

    International Nuclear Information System (INIS)

    Carvalho, F.P.; Oliveira, J.M.

    2009-01-01

    The accuracy of alpha spectrometry in the determination of uranium isotopes at various concentrations levels and with various isotope ratios was tested in a round robin international intercomparison exercise. Results of isotope activity/mass and isotope mass ratios obtained by alpha spectrometry were accurate in a wide range of uranium masses and in isotopic ratios typical of depleted, natural, and low enriched uranium samples. Determinations by alpha spectrometry compared very satisfactorily in accuracy with those by mass spectrometry. For example, determination of U isotopes in natural uranium by alpha spectrometry agreed with mass spectrometry determinations at within ±1%. However, the 236 U isotope, particularly if present in activities much lower than 235 U, might not be determined accurately due to overlap in the alpha particle energies of these two uranium isotopes. (author)

  18. Uncertainty evaluation in normalization of isotope delta measurement results against international reference materials.

    Science.gov (United States)

    Meija, Juris; Chartrand, Michelle M G

    2018-01-01

    Isotope delta measurements are normalized against international reference standards. Although multi-point normalization is becoming a standard practice, the existing uncertainty evaluation practices are either undocumented or are incomplete. For multi-point normalization, we present errors-in-variables regression models for explicit accounting of the measurement uncertainty of the international standards along with the uncertainty that is attributed to their assigned values. This manuscript presents framework to account for the uncertainty that arises due to a small number of replicate measurements and discusses multi-laboratory data reduction while accounting for inevitable correlations between the laboratories due to the use of identical reference materials for calibration. Both frequentist and Bayesian methods of uncertainty analysis are discussed.

  19. Method for determination of radioactive iodine isotopes in environmental objects and biologic materials

    International Nuclear Information System (INIS)

    Dubynin, O.D.; Pogodin, R.I.

    1981-01-01

    The method proposed for determination of radioactive iodine isotopes content in environmental objects and biologic materials is based on the extraction of iodine with carbon tetrachloride and subsequent precipitation of bismuthyl iodine (BiOI) in perchloric medium. Sample preparation for analysis is carried out using conventional alkaline ashing methods. Quantitative iodine separation is hampered if macroquantities of Cl - , Br - , SO 4 2 - , SO 8 2 - , Cr 2 O 7 2 - and other ions are present in the solution. Iodine extraction is carried out before its precipitation. Separated iodine preparation activity is measured using scintillation (NaI) Tl gamma spectrometer. The method's sensitivity when measuring iodine-131 preparations makes up 0.07 Bq per 1 sample with the error +-25 %

  20. Macroscopic rate equation modeling of trapping/detrapping of hydrogen isotopes in tungsten materials

    Energy Technology Data Exchange (ETDEWEB)

    Hodille, E.A., E-mail: etienne.hodille@cea.fr [CEA, IRFM, F-13108 Saint Paul lez Durance (France); Bonnin, X. [LSPM-CNRS, Université Paris 13, Sorbonne Paris Cité, F-93430 Villetaneuse (France); Bisson, R.; Angot, T. [Aix-Marseille Université, PIIM, CNRS, UMR 7345, 13397 Marseille (France); Becquart, C.S. [Université Lille I, UMET, UMR 8207, 59655 Villeneuve d’Ascq cédex France (France); Layet, J.M. [Aix-Marseille Université, PIIM, CNRS, UMR 7345, 13397 Marseille (France); Grisolia, C. [CEA, IRFM, F-13108 Saint Paul lez Durance (France)

    2015-12-15

    Relevant parameters for trapping of Hydrogen Isotopes (HIs) in polycrystalline tungsten are determined with the MHIMS code (Migration of Hydrogen Isotopes in MaterialS) which is used to reproduce Thermal Desorption Spectrometry experiments. Three types of traps are found: two intrinsic traps (detrapping energy of 0.87 eV and 1.00 eV) and one extrinsic trap created by ion irradiation (detrapping energy of 1.50 eV). Then MHIMS is used to simulate HIs retention at different fluences and different implantation temperatures. Simulation results agree well with experimental data. It is shown that at 300 K the retention is limited by diffusion in the bulk. For implantation temperatures above 500 K, the retention is limited by trap creation processes. Above 600 K, the retention drops by two orders of magnitude as compared to the retention at 300 K. With the determined detrapping energies, HIs outgassing at room temperature is predicted. After ions implantation at 300 K, 45% of the initial retention is lost to vacuum in 300 000 s while during this time the remaining trapped HIs diffuse twice as deep into the bulk. - Highlights: • Code development to solve numerically the model equations of diffusion and trapping of hydrogen in metals. • Parametrization of the model trapping parameters (detrapping energies and density): fitting of experimental TDS spectrum. • Confrontation model/experiment: evolution of retention with fluence and implantation temperature. • Investigation of period of rest between implantation and TDS on retention and depth profile.

  1. Reality of dielectric materials in special environment with radiation and others

    International Nuclear Information System (INIS)

    1993-01-01

    In this report, the results of investigation by the expert committee on the title problem in the Institute of Electrical Engineers of Japan from April, 1989 to March, 1992 are summarized. The objectives were to collect the data on the deterioration of dielectric and insulation materials in the special environment including radiation, to investigate the deterioration mechanism, and to grasp the state of development of the materials which can withstand special environment. The actual conditions of temperature, humidity and radiation in nuclear reactors, nuclear fuel cycle facilities, spaceships, accelerator facilities and nuclear fusion experiment facilities are reported. As the new materials which can withstand special environment, the properties of aromatic engineering plastics such as polyimide, PEEK and others, no-halogen incombustible materials, thermoplastic polyurethane, ethylene propylene rubber, cross-linked polyethylene, ceramics, high temperature superconductors, fiber-reinforced composite materials, silica glass and quartz optical fibers are shown. The factors of material deterioration, the method of forecasting lifetime and the examples are explained. The new methods of measuring material properties such as ion microprobe, positron annihilation, scanning tunnel microscopes, optical detection magnetic resonance and so on are explained. (K.I.)

  2. Circumstellar and interstellar material in the CO3 chondrite ALHA77307: An isotopic and elemental investigation

    Science.gov (United States)

    Bose, Maitrayee; Floss, Christine; Stadermann, Frank J.; Stroud, Rhonda M.; Speck, Angela K.

    2012-09-01

    We have carried out a NanoSIMS C, N and O ion imaging study of the CO3.0 chondrite ALHA77307. The distribution of O-anomalous grains in ALHA77307 is similar to that observed in other primitive meteorites, and is dominated (84%) by 17O-rich Group 1 grains from low-mass asymptotic giant branch (AGB) stars of close-to-solar metallicity. Four percent of the grains belong to Group 2, whose 18O depletions suggest cool-bottom processing in low-mass stars during the AGB phase, while 8% are Group 4 grains with likely origins in Type II supernova (SN) ejecta. One ferromagnesian silicate has a very high 17O enrichment; nova explosions have been suggested as sources for such grains, but recent models with updated reaction rates show large discrepancies with the grain data, leaving the origins of these grains uncertain. Most of the grains are silicates (86%) with the remainder consisting of oxides (8%), three silica grains and two 'composite' grains composed of multiple subgrains with different elemental compositions. The elemental compositions of the silicates are similar to those found in other studies, with a predominance of non-stoichiometric compositions and high (up to 44 at.%) Fe concentrations. A comparison of isotopic and elemental compositions for all presolar silicates shows that olivine compositions are overabundant in Group 4 grains compared to grains from Groups 1 and 2. This may reflect injection of presolar material from a nearby supernova into the early solar nebula and incorporation into parent bodies before alteration of compositions through irradiation and sputtering in the interstellar medium, as is likely to have occurred for the Group 1 and 2 grains from more distant AGB stars. The matrix material in ALHA77307 contains abundant carbonaceous hotspots with excesses in 15N. However, unlike CR chondrites, the insoluble organic matter (IOM) in ALHA77307 does not have a bulk N isotopic anomaly, consistent with Raman evidence that it has experienced more

  3. Contributions of each isotope in structural material on radiation damage in a hybrid reactor

    International Nuclear Information System (INIS)

    Günay, Mehtap

    2016-01-01

    In this study, the fluids were used in the liquid first-wall, blanket and shield zones of the designed hybrid reactor system. In this study, salt-heavy metal mixtures consisting of 93–85% Li_2_0Sn_8_0 + 5% SFG-PuO_2 and 2-10% UO_2, 93–85% Li_2_0Sn_8_0 + 5% SFG-PuO_2 and 2-10% NpO_2, and 93–85% Li_2_0Sn_8_0 + 5% SFG-PuO_2 and 2-10% UCO were used as fluids. In this study, the effect on the radiation damage of spent fuel-grade (SFG)-PuO_2, UO_2, NpO_2 and UCO contents was investigated in the structural material of a designed fusion–fission hybrid reactor system. In the designed hybrid reactor system were investigated the effect on the radiation damage of the selected fluid according to each isotopes of structural material in the structural material for 30 full power years (FPYs). Three-dimensional analyses were performed using the most recent MCNPX-2.7.0 Monte Carlo radiation transport code and the ENDF/B-VII.0 nuclear data library

  4. Changes in nitrogen isotopic compositions during composting of cattle feedlot manure: effects of bedding material type.

    Science.gov (United States)

    Kim, Young-Joo; Choi, Woo-Jung; Lim, Sang-Sun; Kwak, Jin-Hyeob; Chang, Scott X; Kim, Han-Yong; Yoon, Kwang-Sik; Ro, Hee-Myong

    2008-09-01

    Temporal changes in delta(15)N of cattle feedlot manure during its composting with either rice hull (RHM) or sawdust (SDM) as bedding materials were investigated. Regardless of the bedding material used, the delta(15)N of total N in the manure increased sharply from +7.6 per thousand to +9.9 per thousand and from +11.4 per thousand to +14.3 per thousand, respectively, in RHM or SDM, within 10 days from the commencement of composting. Such increases could be attributed primarily to N loss via NH(3) volatilization and denitrification based on the very high delta(15)N values (greater than +20 per thousand) of NH(4)(+) and NO(3)(-) in the co-composted manure. The delta(15)N of total N in RHM was substantially lower (by more than 3 per thousand) than that in SDM, suggesting that the delta(15)N of the composted manure was affected not only by N loss but also by the type of bedding material used. Specifically, the higher N concentration in the rice hull than in the saw dust could lead to a greater (15)N isotope dilution.

  5. Decree 2805 by means of which the National Accounting and Control of Basic Nuclear Materials and Special Fusionable Materials System, is established

    International Nuclear Information System (INIS)

    1979-01-01

    This Decree has for object to establish a National Accounting and Control of Basic Nuclear Materials and Special Fusionable Materials System, under the supervision of the National Council for the Nuclear Industry Development. Its aims are to account nuclear materials, to control nuclear activities, to preserve and control nuclear information, to keep technical relationship with specialized organizations, and to garant nuclear safeguards [es

  6. Report on {open_quotes}audit of internal controls over special nuclear materials{close_quotes}

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-04-01

    The Department of Energy (Department) is responsible for safeguarding a significant amount of plutonium, uranium-233 and enriched uranium - collectively referred to as special nuclear materials - stored in the United States. The Department`s office of Nonproliferation and National Security has overall management cognizance for developing policies for safeguarding these materials, while other Headquarters program offices have {open_quotes}landlord{close_quotes} responsibilities for the sites where the materials are stored, and the Department`s operations and field offices provide onsite management of contractor operations. The Department`s management and operating contractors, under the direction of the Department, safeguard and account for the special nuclear material stored at Department sites.

  7. The SNM Scanner: A Non-invasive Protocol for Effective Monitoring of Special Nuclear Material Inventories

    International Nuclear Information System (INIS)

    Lanier, R G; Dauffy, L S; Hodge, A M

    2004-01-01

    We suggest a system of monitoring special nuclear material inventories which uses simple mathematical techniques to compare the gross features of emitted gamma-ray spectra. In this report we develop the techniques necessary to make such spectral comparisons and describe their application. We also apply these ideas and develop inventory confirmation results using a room-temperature CdTe detector in a real nuclear-material inventory environment

  8. Rate of Isotope Exchange Reaction Between Tritiated Water in a Gas Phase and Water on the Surface of Piping Materials

    International Nuclear Information System (INIS)

    Nakashio, Nobuyuki; Yamaguchi, Junya; Kobayashi, Ryusuke; Nishikawa, Masabumi

    2001-01-01

    The system effect of tritium arises from the interaction of tritium in the gas phase with water on the surface of piping materials. It has been reported that the system effect can be quantified by applying the serial reactor model to the piping system and that adsorption and isotope exchange reactions play the main roles in the trapping of tritium. The isotope exchange reaction that occurs when the chemical form of tritium in the gas phase is in the molecular form, i.e., HT or T 2 , has been named isotope exchange reaction 1, and that which occurs when tritium in the gas phase is in water form, i.e., HTO or T 2 O, has been named isotope exchange reaction 2.The rate of isotope exchange reaction 2 is experimentally quantified, and the rate is observed to be about one-third of the rate of adsorption. The trapping and release behavior of tritium from the piping surface due to isotope exchange reaction 2 is also discussed. It is certified that swamping of water vapor to process gas is effective to release tritium from the surface contaminated with tritium

  9. Magnesium Isotopes as a Tracer of Crustal Materials in Volcanic Arc Magmas in the Northern Cascade Arc

    Directory of Open Access Journals (Sweden)

    Aaron W. Brewer

    2018-03-01

    Full Text Available Fifteen North Cascade Arc basalts and andesites were analyzed for Mg isotopes to investigate the extent and manner of crustal contributions to this magmatic system. The δ26Mg of these samples vary from within the range of ocean island basalts (the lightest being −0.33 ± 0.07‰ to heavier compositions (as heavy as −0.15 ± 0.06‰. The observed range in chemical and isotopic composition is similar to that of other volcanic arcs that have been assessed to date in the circum-pacific subduction zones and in the Caribbean. The heavy Mg isotope compositions are best explained by assimilation and fractional crystallization within the deep continental crust with a possible minor contribution from the addition of subducting slab-derived fluids to the primitive magma. The bulk mixing of sediment into the primitive magma or mantle source and the partial melting of garnet-rich peridotite are unlikely to have produced the observed range of Mg isotope compositions. The results show that Mg isotopes may be a useful tracer of crustal input into a magma, supplementing traditional methods such as radiogenic isotopic and trace element data, particularly in cases in which a high fraction of crustal material has been added.

  10. Special conditions for the application of coating materials in nuclear power plants

    International Nuclear Information System (INIS)

    Boetius, I.

    1980-01-01

    Proceeding from the special conditions for the application of coating materials in nuclear power plants the following factors influencing the decontamination of surface coatings are discussed from the point of view of radiation protection: abrasion resistance, waterproofness, mechanical and adhesion strength, and permeability. For practical use it is recommended to test the surface tightness of coatings with radiation-exposed specimens

  11. Semi-annual report on strategic special nuclear material inventory differences

    International Nuclear Information System (INIS)

    1983-07-01

    This report covers data for the period from April 1, 1982, through September 30, 1982, and includes accounting corrections for data from earlier periods. These data and explanations, together with the absences of physical indications of any theft attempt, support a finding that during this period no theft or diversion of strategic special nuclear material has occurred

  12. 75 FR 27205 - Hazardous Materials: Incorporation of Special Permits Into Regulations

    Science.gov (United States)

    2010-05-14

    ... specially designed radiation detectors containing a Division 2.2 (non-flammable gas) material under a new.... Radiation Detectors Radiation detectors are used for measuring the intensity of ionizing radiation. The... visual inspection of the rupture disc in a non-reclosing pressure relief device of a rail tank car...

  13. 75 FR 57830 - Office of Hazardous Materials Safety; Notice of Applications for Modification of Special Permit

    Science.gov (United States)

    2010-09-22

    ... permits (e.g. to provide for additional hazardous materials, packaging design changes, additional mode of... special permit Application No. Docket No. Applicant affected thereof 7951-M ConAgra Foods, 49 CFR To... outer packaging when no other means of transportation exist. 14953-M Applied 49 CFR To modify the...

  14. Study of lead isotopes for investigating the origin of endogenic deposits with special reference to some ore deposits from India

    International Nuclear Information System (INIS)

    Chernyshev, I.V.; Safonov, Yu. G.; Radhakrishna, B.P.; Vasudev, V.N.; Krishna Rao, B.; Deb, M.

    1980-01-01

    The isotope composition of leads from ore deposits in general reflects the age of ore mineralisation and its genetical features. Calculations of the model age from lead isotope data form the basis for genetic reconstructions of Precambrain deposits. Radical improvement in the accuracy of mass spectrometric isotope lead analysis has made possible the employment of two-stage and in some cases more complicated models for genetic reconstructions. Fifteen galena samples from five sulphide and gold-sulphide deposits of the Indian Shield have been selected and determination of lead isotope composition has been carried out in the USSR using recently developed M.I.1320 Mass Spectrometer. The isotopic ratios of galena from Ingaldhal copper deposit are the most primitive among the analysed ores of the Indian Shield. The results of lead isotopic determination have been interpreted in terms of the general theory of 'plumbotectonics'. (auth.)

  15. Lead Isotopic Composition in Biogenic Certified Reference Materials Determined by Different ICP-based Mass Spectrometric Techniques

    Czech Academy of Sciences Publication Activity Database

    Ďurišová, Jana; Ackerman, Lukáš; Strnad, L.; Chrastný, V.; Borovička, Jan

    2015-01-01

    Roč. 39, č. 2 (2015), s. 209-220 ISSN 1639-4488 Institutional support: RVO:67985831 Keywords : Pb isotopes * 206 Pb/ 207 Pb * 208 Pb/ 206 Pb * ICP-MS * certified reference materials * vegetation Subject RIV: CB - Analytical Chemistry, Separation Impact factor: 2.885, year: 2015

  16. Lead Isotopic Composition in Biogenic Certified Reference Materials Determined by Different ICP-based Mass Spectrometric Techniques

    Czech Academy of Sciences Publication Activity Database

    Ďurišová, J.; Ackerman, L.; Strnad, L.; Chrastný, V.; Borovička, Jan

    2015-01-01

    Roč. 39, č. 2 (2015), s. 209-220 ISSN 1639-4488 R&D Projects: GA ČR(CZ) GAP504/11/0484 Institutional support: RVO:61389005 Keywords : Pb isotopes * Pb-206 * Pb-207 * Pb-208 * ICP-MS * certified reference materials * vegetation Subject RIV: CB - Analytical Chemistry, Separation Impact factor: 2.885, year: 2015

  17. Compound specific stable isotopes as probes for distinguishing the sources of biomolecules in terrestrial and extraterrestrial materials

    Science.gov (United States)

    Engel, M. H.; Macko, S. A.

    2003-04-01

    Life on Earth consists of orderly arrangements of several key types of organic compounds (amino acids, sugars, fatty acids, nucleic bases) that are the building blocks of proteins, carbohydrates, lipids and nucleotides. Subsequent to death, macromolecules are commonly broken down to their molecular constituents or other similar scale components. Thus, in ancient terrestrial and extraterrestrial materials, it is far more likely to expect the presence of simple compounds such as amino acids rather than the proteins from which they were possibly derived. Given that amino acids, for example, are common components of all extinct and extant organisms, the challenge has been to develop methods for distinguishing their sources. Stable isotopes are powerful probes for determining the origins of organic matter. Amino acid constituents of all organisms on Earth exhibit characteristic stable isotope compositions owing to fractionations associated with their biosynthesis. These fractionations are distinct from those observed for amino acids formed by abiotic processes. Thus it should be possible to use isotopes as probes for determining whether amino acids in ancient rocks on Earth are biotic or abiotic, based on their relative isotopic compositions. Also, owing to differences in the isotope compositions of precursors, amino acids in extraterrestrial materials such as carbonaceous meteorites are moderately to substantially enriched in the heavy isotopes of C, N and H relative to terrestrial amino acids. Assuming that the isotope compositions of the gaseous components of, for example, the Martian atmosphere were distinct from Earth at such time when organic molecules may have formed, it should be possible to distinguish these components from terrestrial contaminants by determining their isotope compositions and/or those of their respective enantiomers. Also, if life as we know it existed on another planet such as Mars, fractionations characteristic of biosynthesis should be

  18. The origin of volatile element depletion in early solar system material: Clues from Zn isotopes in chondrules

    Science.gov (United States)

    Pringle, Emily A.; Moynier, Frédéric; Beck, Pierre; Paniello, Randal; Hezel, Dominik C.

    2017-06-01

    Volatile lithophile elements are depleted in the different planetary materials to various degrees, but the origin of these depletions is still debated. Stable isotopes of moderately volatile elements such as Zn can be used to understand the origin of volatile element depletions. Samples with significant volatile element depletions, including the Moon and terrestrial tektites, display heavy Zn isotope compositions (i.e. enrichment of 66Zn vs. 64Zn), consistent with kinetic Zn isotope fractionation during evaporation. However, Luck et al. (2005) found a negative correlation between δ66Zn and 1/[Zn] between CI, CM, CO, and CV chondrites, opposite to what would be expected if evaporation caused the Zn abundance variations among chondrite groups. We have analyzed the Zn isotope composition of multiple samples of the major carbonaceous chondrite classes: CI (1), CM (4), CV (2), CO (4), CB (2), CH (2), CK (4), and CK/CR (1). The bulk chondrites define a negative correlation in a plot of δ66Zn vs 1/[Zn], confirming earlier results that Zn abundance variations among carbonaceous chondrites cannot be explained by evaporation. Exceptions are CB and CH chondrites, which display Zn systematics consistent with a collisional formation mechanism that created enrichment in heavy Zn isotopes relative to the trend defined by CI-CK. We further report Zn isotope analyses of chondrite components, including chondrules from Allende (CV3) and Mokoia (CV3), as well as an aliquot of Allende matrix. All chondrules are enriched in light Zn isotopes (∼500 ppm on 66Zn/64Zn) relative to the bulk, contrary to what would be expected if Zn were depleted during evaporation, on the other hand the matrix has a complementary heavy isotope composition. We report sequential leaching experiments in un-equilibrated ordinary chondrites, which show sulfides are isotopically heavy compared to silicates and the bulk meteorite by ca. +0.65 per mil on 66Zn/64Zn. We suggest isotopically heavy sulfides were

  19. Oxygen and Magnesium Isotopic Compositions of Asteroidal Materials Returned from Itokawa by the Hayabusa Mission

    Science.gov (United States)

    Yurimoto, H; Abe, M.; Ebihara, M.; Fujimura, A.; Hashizume, K.; Ireland, T. R.; Itoh, S.; Kawaguchi, K.; Kitajima, F.; Mukai, T.; hide

    2011-01-01

    The Hayabusa spacecraft made two touchdowns on the surface of Asteroid 25143 Itokawa on November 20th and 26th, 2005. The Asteroid 25143 Itokawa is classified as an S-type asteroid and inferred to consist of materials similar to ordinary chondrites or primitive achondrites [1]. Near-infrared spectroscopy by the Hayabusa spacecraft proposed that the surface of this body has an olivine-rich mineral assemblage potentially similar to that of LL5 or LL6 chondrites with different degrees of space weathering [2]. The spacecraft made the reentry into the Earth s atmosphere on June 12th, 2010 and the sample capsule was successfully recovered in Australia on June 13th, 2010. Although the sample collection processes on the Itokawa surface had not been made by the designed operations, more than 1,500 grains were identified as rocky particles in the sample curation facility of JAXA, and most of them were judged to be of extraterrestrial origin, and definitely from Asteroid Itokawa on November 17th, 2010 [3]. Although their sizes are mostly less than 10 microns, some larger grains of about 100 microns or larger were also included. The mineral assembly is olivine, pyroxene, plagioclase, iron sulfide and iron metal. The mean mineral compositions are consistent with the results of near-infrared spectroscopy from Hayabusa spacecraft [2], but the variations suggest that the petrologic type may be smaller than the spectroscopic results. Several tens of grains of relatively large sizes among the 1,500 grains will be selected by the Hayabusa sample curation team for preliminary examination [4]. Each grain will be subjected to one set of preliminary examinations, i.e., micro-tomography, XRD, XRF, TEM, SEM, EPMA and SIMS in this sequence. The preliminary examination will start from the last week of January 2011. Therefore, samples for isotope analyses in this study will start from the last week of February 2011. By the time of the LPSC meeting we will have measured the oxygen and

  20. Reference materials for nondestructive assay of special nuclear material. Volume 1. Uranium oxide plus graphite powder

    International Nuclear Information System (INIS)

    Sprinkle, J.K.; Likes, R.N.; Parker, J.L.; Smith, H.A.

    1983-10-01

    This manual describes the fabrication of reference materials for use in gamma-ray-based nondestructive assay of low-density uranium-bearing samples. The sample containers are 2-l bottles. The reference materials consist of small amounts of UO 2 spread throughout a graphite matrix. The 235 U content ranges from 0 to 100 g. The manual also describes the far-field assay procedure used with low-resolution detectors

  1. RETIMAC: a real-time material control concept for strategic special nuclear material

    International Nuclear Information System (INIS)

    Shea, T.E.

    1975-01-01

    As one possible means to upgrade licensee safeguards systems, the NRC is exploring a real-time material control concept. The concept incorporates process controls, material containment provisions, and extensive instrumentation. Plants incorporating this concept would be better able to prevent, deter, and detect diversion, and to assure that diversion has not gone undetected. A substantial methods development, evaluation, and preliminary standards development program is under way to develop the basis for future policy decisions

  2. The development of maple technology for materials testing, isotope production, and neutron-beam applications

    International Nuclear Information System (INIS)

    Lidstone, R.F.; Gillespie, G.E.; Lee, A.G.; Bishop, W.E.

    1996-01-01

    AECL has been developing MAPLE technology to meet Canadian and international requirements for high-performance research reactors. MAPLE refers to a family of open-tank-in-pool reactors that employ compact H 2 O-cooled cores within D 2 O vessels to efficiently furnish neutrons to various types of irradiation facilities. The initial focus was on a 10-MW t Canadian facility for radioisotope production, the HANARO multipurpose-reactor project, and an associated R and D program. Recently, AECL began to develop the concept for a new Canadian Irradiation Research Facility (IRF) which will support the continued evolution of CANDU (CANadian Deuterium Uranium) technology and generate neutrons for basic and applied materials science. Additionally, AECL is currently developing a standardized MAPLE research-centre design with integrated neutron-application facilities; various reactor-core options have been optimized for different combinations of utilization: a 19-site core for neutron-beam applications and ancillary isotope production, a 31-site core for multipurpose materials testing and neutron-beam applications, and twin 18-site cores for high-flux neutron-beam applications. (author)

  3. Data on trapping and re-emission of energetic hydrogen isotopes and helium in materials, supplement 1

    International Nuclear Information System (INIS)

    Yamaguchi, Sadae; Sugizaki, Yasuaki; Ozawa, Kunio; Nakai, Yohta.

    1984-05-01

    This is the supplement to the data on trapping and re-emission of energetic hydrogen isotopes and helium in materials (JAERI-M 82-118). It contains 32 data up to end of 1982, dividing it into following 6 sections: 1) Dose Dependence, 2) Target Material Dependence, 3) Target Temperature Dependence, 4) Incident Energy Dependence, 5) Damage Effects and 6) Ion-Induced Release. (author)

  4. Foraminifera isotopic records... with special attention to high northern latitudes and the impact of sea-ice distillation processes

    Energy Technology Data Exchange (ETDEWEB)

    Hillaire-Marcel, Claude, E-mail: hillaire-marcel.claude@uqam.ca [GEOTOP, Universite du Quebec a Montreal, PO Box 8888, succursale ' centre ville' Montreal, Qc, H3C 3P8 (Canada)

    2011-05-15

    Since the reassessment of oxygen isotope paleotemperatures by N. Shackleton in the late 60s, most papers using isotopic records from planktic or benthic foraminifers imply a direct relationship between oxygen isotopes in seawater and the ice/ocean volume, thus some linkage with salinity, sea level, etc. Such assumptions are also made when incorporating 'isotopic modules' in coupled models. Here, we will further examine the linkages between salinity and oxygen isotope ratios of sea-water recorded by foraminifers, and their potential temporal and spatial variability, especially in the northern North Atlantic and the Arctic oceans. If temporal and spatial changes in the isotopic composition of precipitations and ice meltwaters tune the isotopic properties of the fresh water end-member that dilutes the ocean, rates of sea-ice formation and evaporation at the ocean surface play a further role on the salt and oxygen isotope contents of water masses. Thus, the oxygen 18-salinity relationship carries a specific isotopic signature for any given water mass. At the ocean scale, residence time and mixing of these water masses, as well as the time dependent-achievement of proxy-tracer equilibrium, will also result in variable recordings of mass transfers into the hydrosphere, notable between ice-sheets and ocean. Since these records in water mass may vary in both amplitude and time, direct correlations of isotopic records will potentially be misleading. Implications of such issues on the interpretation of oxygen isotope records from the sub-arctic seas will be discussed, as well as the inherent flaws of such records due to sedimentological and or ecological parameters.

  5. Directory of national competent authorities' approval certificates for packages, shipments, special arrangements and special form radioactive material

    International Nuclear Information System (INIS)

    1986-09-01

    The Agency's transport regulations prescribe various requirements for the authorization of packages and shipments in respect of both national and international movement of radioactive materials. These authorizations are issued by the relevant competent authority of the country concerned; they take the form of package approval and/or shipment approval certificates. At the request of the Standing Advisory Group of the Safe Transport of Radioactive Material (SAGSTRAM), the Agency has established a programme to maintain a file of those certificates for packages and shipments which are either transported internationally or used outside the country of origin. The purpose of this directory is to facilitate the transfer of information to competent authorities and any other person wishing details on the packaging, authorized contents or special conditions pertinent to any package or shipment. The directory enables competent authorities to be aware of the status of any certificate submitted for validation. It also indicates any change in status of any certificate already validated. Future updates of the complete data will be distributed annually in a TECDOC form and, in addition, summary listings of the certificates will be issued every six months thereafter

  6. Titanium carbide-carbon porous nanocomposite materials for radioactive ion beam production: processing, sintering and isotope release properties

    CERN Document Server

    AUTHOR|(CDS)2081922; Stora, Thierry

    2017-01-26

    The Isotope Separator OnLine (ISOL) technique is used at the ISOLDE - Isotope Separator OnLine DEvice facility at CERN, to produce radioactive ion beams for physics research. At CERN protons are accelerated to 1.4 GeV and made to collide with one of two targets located at ISOLDE facility. When the protons collide with the target material, nuclear reactions produce isotopes which are thermalized in the bulk of the target material grains. During irradiation the target is kept at high temperatures (up to 2300 °C) to promote diffusion and effusion of the produced isotopes into an ion source, to produce a radioactive ion beam. Ti-foils targets are currently used at ISOLDE to deliver beams of K, Ca and Sc, however they are operated at temperatures close to their melting point which brings target degradation, through sintering and/or melting which reduces the beam intensities over time. For the past 10 years, nanostructured target materials have been developed and have shown improved release rates of the produced i...

  7. 76 FR 51324 - Hazardous Materials: Incorporating Rail Special Permits Into the Hazardous Materials Regulations

    Science.gov (United States)

    2011-08-18

    ... through use of electronic data interchange (EDI). The IVOHMA states ``differences in hazard communication... and on the possible effects EDI may have on distributing hazardous materials shipping paper... consider the use of EDI in other modes of transport in a future rulemaking. Petition No. P-1567 PHMSA...

  8. Five Years of Analyses of Volatiles, Isotopes and Organics in Gale Crater Materials

    Science.gov (United States)

    McAdam, A.; Mahaffy, P. R.; Andrejkovicova, S. C.; Archer, P. D., Jr.; Atreya, S. K.; Buch, A.; Coll, P. J.; Conrad, P. G.; Eigenbrode, J. L.; Farley, K. A.; Flesch, G.; Franz, H. B.; Freissinet, C.; Glavin, D. P.; Hogancamp, J. V.; House, C. H.; Knudson, C. A.; Lewis, J. M.; Malespin, C.; Martin, P. M.; Millan, M.; Ming, D. W.; Morris, R. V.; Navarro-Gonzalez, R.; Steele, A.; Stern, J. C.; Summons, R. E.; Sutter, B.; Szopa, C.; Teinturier, S.; Trainer, M. G.; Webster, C. R.; Wong, G. M.

    2017-12-01

    Over the last five years, the Curiosity rover has explored a variety of fluvial, lacustrine and aeolian sedimentary rocks, and soils. The Sample Analysis at Mars (SAM) instrument has analysed 3 soil and 12 rock samples, which exhibit significant chemical and mineralogical diversity in over 200 meters of vertical section. Here we will highlight several key insights enabled by recent measurements of the chemical and isotopic composition of inorganic volatiles and organic compounds detected in Gale Crater materials. Until recently samples have evolved O2 during SAM evolved gas analyses (EGA), attributed to the thermal decomposition of oxychlorine phases. A lack of O2 evolution from recent mudstone samples may indicate a difference in the composition of depositional or diagenetic fluids, and can also have implications for the detection of organic compounds since O2 can combust organics to CO2 in the SAM ovens. Recent mudstone samples have also shown little or no evolution of NO attributable to nitrate salts, possibly also as a result of changes in the chemical composition of fluids [1]. Measurements of the isotopic composition of sulfur, hydrogen, nitrogen, chlorine, and carbon in methane evolved during SAM pyrolysis are providing constraints on the conditions of possible paleoenvironments [e.g., 2, 3]. There is evidence of organic C from both EGA and GCMS measurements of Gale samples [e.g., 4, 5]. Organic sulfur volatiles have been detected in several samples, and the first opportunistic derivatization experiment produced a rich dataset indicating the presence of several organic compounds [6, 7]. A K-Ar age has been obtained from the Mojave mudstone, and the age of secondary materials formed by aqueous alteration is likely history and habitability. [1] Sutter et al. (2017) LPSC 3009. [2] Franz et al., this mtg. [3] Stern et al., this mtg. [4] Ming et al. (2014) Science 343. [5] Freissinet et al. (2015) JGR 120. [6] Eigenbrode et al. (2016) AGU P21D-08. [7] Freissinet

  9. Semi-annual report on strategic special nuclear material inventory differences

    International Nuclear Information System (INIS)

    1984-07-01

    This fourteenth periodic semiannual report of Inventory Differences (ID) covers the last six months of fiscal year 1983 (April 1, 1983 through September 30, 1983), for the Department of Energy (DOE) and DOE contractor facilities possessing significant quantities of strategic special nuclear material (SSNM). Inventory Differences are expected in nuclear material processing and are not, in and of themselves, evidence of lost or stolen material. On the other hand, ID analysis provides valuable information on the effectiveness of the safeguards system's physical protection and material control measures as well as a check on the process controls and material management procedures. ID's outside safeguards control limits or involving a missing SSNM discrete item are investigated. If necessary, an operation may be shut down until an ID is resolved

  10. Rattling nucleons: New developments in active interrogation of special nuclear material

    International Nuclear Information System (INIS)

    Runkle, Robert C.; Chichester, David L.; Thompson, Scott J.

    2012-01-01

    Active interrogation is a vigorous area of research and development due to its promise of offering detection and characterization capabilities of special nuclear material in environments where passive detection fails. The primary value added by active methods is the capability to penetrate shielding - special nuclear material itself, incidental materials, or intentional shielding - and advocates hope that active interrogation will provide a solution to the problem of detecting shielded uranium, which is at present the greatest obstacle to interdiction efforts. The technique also provides a unique benefit for quantifying nuclear material in high background-radiation environments, an area important for nuclear material safeguards and material accountancy. Progress has been made in the field of active interrogation on several fronts, most notably in the arenas of source development, systems integration, and the integration and exploitation of multiple fission and non-fission signatures. But penetration of interrogating radiation often comes at a cost, not only in terms of finance and dose but also in terms of induced backgrounds, system complexity, and extended measurement times (including set up and acquisition). These costs make the calculus for deciding to implement active interrogation more subtle than may be apparent. The purpose of this review is thus to examine existing interrogation methods, compare and contrast their attributes and limitations, and identify missions where active interrogation may hold the most promise.

  11. Nondestructive assay of special nuclear material for uranium fuel-fabrication facilities

    International Nuclear Information System (INIS)

    Smith, H.A. Jr.; Schillebeeckx, P.

    1997-01-01

    A high-quality materials accounting system and effective international inspections in uranium fuel-fabrication facilities depend heavily upon accurate nondestructive assay measurements of the facility's nuclear materials. While item accounting can monitor a large portion of the facility inventory (fuel rods, assemblies, storage items), the contents of all such items and mass values for all bulk materials must be based on quantitative measurements. Weight measurements, combined with destructive analysis of process samples, can provide highly accurate quantitative information on well-characterized and uniform product materials. However, to cover the full range of process materials and to provide timely accountancy data on hard-to-measure items and rapid verification of previous measurements, radiation-based nondestructive assay (NDA) techniques play an important role. NDA for uranium fuel fabrication facilities relies on passive gamma spectroscopy for enrichment and U isotope mass values of medium-to-low-density samples and holdup deposits; it relies on active neutron techniques for U-235 mass values of high-density and heterogeneous samples. This paper will describe the basic radiation-based nondestructive assay techniques used to perform these measurements. The authors will also discuss the NDA measurement applications for international inspections of European fuel-fabrication facilities

  12. Ultra-high-precision Nd-isotope measurements of geological materials by MC-ICPMS

    DEFF Research Database (Denmark)

    Saji, Nikitha Susan; Wielandt, Daniel Kim Peel; Paton, Chad

    2016-01-01

    We report novel techniques allowing the measurement of Nd-isotope ratios with unprecedented accuracy and precision by multi-collector inductively coupled plasma mass spectrometry. Using the new protocol, we have measured the Nd-isotopic composition of rock and synthetic Nd standards as well as th...

  13. The precise measurement of TL isotopic compositions by MC-ICPMS: Application to the analysis of geological materials and meteorites.

    Science.gov (United States)

    Rehkämper, Mark; Halliday, Alex N.

    1999-07-01

    The precision of Tl isotopic measurements by thermal ionization mass spectrometry (TIMS) is severely limited by the fact that Tl possesses only two naturally occurring isotopes, such that there is no invariant isotope ratio that can be used to correct for instrumental mass discrimination. In this paper we describe new chemical and mass spectrometric techniques for the determination of Tl isotopic compositions at a level of precision hitherto unattained. Thallium is first separated from the geological matrix using a two-stage anion-exchange procedure. Thallium isotopic compositions are then determined by multiple-collector inductively coupled plasma-mass spectrometry with correction for mass discrimination using the known isotopic composition of Pb that is admixed to the sample solutions. With these procedures we achieve a precision of 0.01-0.02% for Tl isotope ratio measurements in geological samples and this is a factor of ≥3-4 better than the best published results by TIMS. However, without adequate precautions, experimental artifacts can be generated that result in apparent Tl isotopic fractionations of up to one per mil. Analysis of five terrestrial samples indicate the existence of Tl isotopic variations related to natural fractionation processes on the Earth. Two of the three igneous rocks analyzed in this study display Tl isotopic compositions indistinguishable from our laboratory standard, the reference material NIST-997 Tl. A third sample, however, is characterized by ɛ Tl ≈ 2.5 ± 1.5, where ɛ Tl represents the deviation of the 205Tl/ 203Tl ratio of the sample relative to NIST-997 Tl in parts per 10 4. Even larger deviations were identified for two ferromanganese crusts from the Pacific Ocean, which display ɛ Tl-values of +5.0 ± 1.5 and +11.7 ± 1.3. We suggest that the large variability of Tl isotopic compositions in the latter samples are caused by low-temperature processes related to the formation of the Fe-Mn crusts by precipitation and

  14. Study on material attractiveness aspect of spent nuclear fuel of LWR and FBR cycles based on isotopic plutonium production

    International Nuclear Information System (INIS)

    Permana, Sidik; Suzuki, Mitsutoshi; Saito, Masaki; Novitrian,; Waris, Abdul; Suud, Zaki

    2013-01-01

    Highlights: • The paper analyzes the plutonium production of recycling nuclear fuel option. • To evaluate material attractiveness based on intrinsic feature of material barrier. • Evaluation based on isotopic plutonium composition of spent fuel LWR and FBR. • Even mass number of plutonium gives a significant contribution to material barrier, in particular Pu-238 and Pu-240. • Doping MA in FBR blanket is effective to increase material barrier from weapon grade plutonium to more than MOX fuel grade. - Abstract: Recycling minor actinide (MA) as well as used uranium and plutonium can be considered to reduce nuclear waste production as well as to increase the intrinsic aspect of nuclear nonproliferation as doping material. Plutonium production as a significant aspect of recycling nuclear fuel option, gives some advantages and challenges, such as fissile material utilization of plutonium as well as production of some even mass number plutonium. The study intends to evaluate the material attractiveness based on the intrinsic feature of material barrier such as plutonium composition, decay heat and spontaneous fission neutron components from spent fuel (SF) light water reactor (LWR) and fast breeder reactor (FBR) cycles. A significant contribution has been shown by decay heat (DH) and spontaneous fission neutron (SFN) of even mass number of plutonium isotopes to the total DH and SFN of plutonium element, in particular from isotopic plutonium Pu-238 and Pu-240 contributions. Longer decay cooling time and higher burnup are effective to increase the material barrier (DH and SFN) level from reactor grade plutonium level to MOX grade plutonium level. Material barrier of plutonium element from spent fuel (SF) FBR in the core regions has similarity to the material barrier profile of SF LWR which can be categorized as MOX fuel grade plutonium. Plutonium compositions, DH and SFN components are categorized as weapon grade plutonium level for FBR blanket regions with no

  15. 10 CFR 73.25 - Performance capabilities for physical protection of strategic special nuclear material in transit.

    Science.gov (United States)

    2010-01-01

    ... strategic special nuclear material in transit. 73.25 Section 73.25 Energy NUCLEAR REGULATORY COMMISSION... Transit § 73.25 Performance capabilities for physical protection of strategic special nuclear material in transit. (a) To meet the general performance objective and requirements of § 73.20 an in-transit physical...

  16. 10 CFR 70.11 - Persons using special nuclear material under certain Department of Energy and Nuclear Regulatory...

    Science.gov (United States)

    2010-01-01

    ... 10 Energy 2 2010-01-01 2010-01-01 false Persons using special nuclear material under certain Department of Energy and Nuclear Regulatory Commission contracts. 70.11 Section 70.11 Energy NUCLEAR... using special nuclear material under certain Department of Energy and Nuclear Regulatory Commission...

  17. Technical criteria for terminating or reducing domestic safeguards on low-grade special nuclear material

    International Nuclear Information System (INIS)

    Crawford, D.W.

    1996-01-01

    A graded table for terminating or reducing domestic safeguards has been developed for use by programs and facilities within the Department of Energy in decisions regarding the need for or levels of protection of low-grade nuclear materials. Contained in this table are technical criteria which can allow for complete removal of safeguards over many special nuclear material forms and concentrations of typical low-grade materials either currently located at generating or processing sites and materials which may arise from processing operations related to stabilization and disposition activities. In addition, these criteria include higher concentration levels which may warrant maintaining some level of (albeit reduced) security on low-grade materials while allowing reductions in materials control and accountability requirements. These reductions can range from complete removal of these materials from materials control and accountability requirements such as measurements, physical inventories and recordkeeping, to deferring these measurements and physical inventories until a time that either the material is removed from the site or resubmitted for processing. It is important to note that other conditions contained in current Departmental safeguards and security policy be met prior to safeguards termination or reduction

  18. Survey of special nuclear material vehicle monitors for domestic and international safeguards

    International Nuclear Information System (INIS)

    Fehlau, P.E.; Atwater, H.F.; Caldwell, J.T.; Shunk, E.R.

    1979-01-01

    Special nuclear materials vehicle monitors, including gateside vehicle monitors, hand-held personnel-vehicle monitors, and a new tunnel monitor concept for very large vehicles, are discussed. The results of a comparison of effectiveness of monitors for domestic application are presented. The results of calculations and small scale prototype measurements are given for a tunnel-like neutron monitor for monitoring at the perimeter of an enrichment plant subjected to International Safeguards

  19. Intelligent data-acquisition instrumentation for special nuclear material assay data analysis

    International Nuclear Information System (INIS)

    Ethridge, C.D.

    1980-01-01

    The Detection, Surveillance, Verification, and Recovery Group of the Los Alamos Scientific Laboratory Energy Division/Nuclear Safeguards Programs is now utilizing intelligent data-acquisition instrumentation for assay data analysis of special nuclear material. The data acquisition and analysis are enabled by the incorporation of a number-crunching microprocessor sequenced by a single component microcomputer. Microcomputer firmware establishes the capability for processing the computation of several selected functions and also the ability of instrumentation self-diagnostics

  20. Quality assurance in production and use of special form radioactive material - focal points in BAM approvals

    International Nuclear Information System (INIS)

    Rolle, A.; Buhlemann, L.

    2004-01-01

    BAM as the competent authority for approval of special form radioactive material attaches great importance to a detailed audit of the required quality assurance programs for design, manufacture, testing, documentation, use, maintenance and inspection. Applicants have to submit, together with application documentation information on general arrangements for quality assurance, as well as on quality assurance in production and in operation. Fields where BAM has often found deficiencies are leak test methods, weld seam quality and the safety level after use

  1. Special Issue: 14th International Symposium on Novel and Nano Materials

    Science.gov (United States)

    Kim, Woo-Byoung; Choa, Yong-Ho; Ahn, Hyo-Jin; Park, Il-Kyu

    2017-09-01

    This Special Issue of Applied Surface Science is intended to provide a collection of peer-reviewed contributions presented at the 14th International Symposium on Novel Nano Materials (ISNNM) held in Budapest, Hungary as one of the most beautiful cities in Europe from July 3 to July 8, 2016. All selected papers underwent the regular peer review process as set by the journal of Applied Surface Science and its publisher (Elsevier).

  2. On-line double isotope dilution laser ablation inductively coupled plasma mass spectrometry for the quantitative analysis of solid materials.

    Science.gov (United States)

    Fernández, Beatriz; Rodríguez-González, Pablo; García Alonso, J Ignacio; Malherbe, Julien; García-Fonseca, Sergio; Pereiro, Rosario; Sanz-Medel, Alfredo

    2014-12-03

    We report on the determination of trace elements in solid samples by the combination of on-line double isotope dilution and laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS). The proposed method requires the sequential analysis of the sample and a certified natural abundance standard by on-line IDMS using the same isotopically-enriched spike solution. In this way, the mass fraction of the analyte in the sample can be directly referred to the certified standard so the previous characterization of the spike solution is not required. To validate the procedure, Sr, Rb and Pb were determined in certified reference materials with different matrices, including silicate glasses (SRM 610, 612 and 614) and powdered samples (PACS-2, SRM 2710a, SRM 1944, SRM 2702 and SRM 2780). The analysis of powdered samples was carried out both by the preparation of pressed pellets and by lithium borate fusion. Experimental results for the analysis of powdered samples were in agreement with the certified values for all materials. Relative standard deviations in the range of 6-21% for pressed pellets and 3-21% for fused solids were obtained from n=3 independent measurements. Minimal sample preparation, data treatment and consumption of the isotopically-enriched isotopes are the main advantages of the method over previously reported approaches. Copyright © 2014 Elsevier B.V. All rights reserved.

  3. Design of a compact thermal ionization mass spectrometer for isotopic ratio measurement of nuclear material

    International Nuclear Information System (INIS)

    Bhatia, R.K.; Yadav, V.K.; Ravisankar, E.; Nataraju, V.; Gadkari, S.C.

    2017-01-01

    High precision isotope ratio analysis of materials of interest in nuclear and geological applications is carried out by thermal ionization mass spectrometry (TIMS) technique. One of the important mandates of Bhabha Atomic Research Centre (BARC) has been developing these instruments and several TIMS instruments have been developed and deployed at user sites covering a wide range material of interest relevant to various stages of the nuclear power cycle. The instrument designs for above applications are based on two geometries of magnetic sector ie., 15 cm sector radius and 30 cm sector radius with resolutions as 200 and 400 respectively. There has been a conscious effort to improve the the sensitivity and precision of these models by modifying the designs of the sub-systems. In the recent past, a new ion optical element viz., variable dispersion zoom optics (VDZO) was introduced in the collector system of the standard model with 30cm radius magnet, to increase the dispersion of the ion beams which enabled to fix the locations of the Faraday cups (upto 6 nos.) instead of the conventional movable ones. After establishing the usefulness of VDZO, an attempt is being made to design and develop a 20 cm magnet based TIMS which will have a much smaller foot print compared to the standard 30 cm model and also covers the usual range of elements (viz. Li - U). The ion optical design was optimized using computer simulations with SIMION 7.0 software and subsequently the mechanical design was carried out using Autocad computer software. Some of the details of this new design are presented in this abstract

  4. On evaluated nuclear data for beta-delayed gamma rays following of special nuclear materials

    Energy Technology Data Exchange (ETDEWEB)

    Mencarini, Leonardo de H.; Caldeira, Alexandre D., E-mail: mencarini@ieav.cta.b, E-mail: alexdc@ieav.cta.b [Instituto de Estudos Avancados (IEAv/CTA), Sao Jose dos Campos, SP (Brazil)

    2011-07-01

    In this paper, a new type of information available in ENDF is discussed. During a consistency check of the evaluated nuclear data library ENDF/B-VII.0 performed at the Nuclear Data Subdivision of the Institute for Advanced Studies, the size of the files for some materials drew the attention of one of the authors. Almost 94 % of all available information for these special nuclear materials is used to represent the beta-delayed gamma rays following fission. This is the first time this information is included in an ENDF version. (author)

  5. Semi-annual report on strategic special nuclear material inventory differences

    International Nuclear Information System (INIS)

    1979-01-01

    This report provides and explains the generally small differences between the amounts of nuclear materials charged to DOE facilities and the amounts that could be physically inventoried. This report covers data for the period from October 1, 1977, through March 31, 1978, and includes accounting corrections for data from earlier periods. The data and explanations, together with the absence of physical indications of any theft attempt, support a finding that during this period no theft or diversion of a significant amount of strategic special nuclear material has occurred

  6. On evaluated nuclear data for beta-delayed gamma rays following of special nuclear materials

    International Nuclear Information System (INIS)

    Mencarini, Leonardo de H.; Caldeira, Alexandre D.

    2011-01-01

    In this paper, a new type of information available in ENDF is discussed. During a consistency check of the evaluated nuclear data library ENDF/B-VII.0 performed at the Nuclear Data Subdivision of the Institute for Advanced Studies, the size of the files for some materials drew the attention of one of the authors. Almost 94 % of all available information for these special nuclear materials is used to represent the beta-delayed gamma rays following fission. This is the first time this information is included in an ENDF version. (author)

  7. Project plan remove special nuclear material from PFP project plutonium finishing plant; TOPICAL

    International Nuclear Information System (INIS)

    BARTLETT, W.D.

    1999-01-01

    This plan presents the overall objectives, description, justification and planning for the Plutonium Finishing Plant (PFP) Remove Special Nuclear Material (SNM) Materials. The intent of this plan is to describe how this project will be managed and integrated with other facility stabilization and deactivation activities. This plan supplements the overall integrated plan presented in the Plutonium Finishing Plant Integrated Project Management Plan (IPMP), HNF-3617,Rev. 0. This project plan is the top-level definitive project management document for PFP Remove SNM Materials project. It specifies the technical, schedule, requirements and the cost baselines to manage the execution of the Remove SNM Materials project. Any deviations to the document must be authorized through the appropriate change control process

  8. Project plan remove special nuclear material from PFP project plutonium finishing plant

    International Nuclear Information System (INIS)

    BARTLETT, W.D.

    1999-01-01

    This plan presents the overall objectives, description, justification and planning for the Plutonium Finishing Plant (PFP) Remove Special Nuclear Material (SNM) Materials. The intent of this plan is to describe how this project will be managed and integrated with other facility stabilization and deactivation activities. This plan supplements the overall integrated plan presented in the Plutonium Finishing Plant Integrated Project Management Plan (IPMP), HNF-3617, Rev. 0. This project plan is the top-level definitive project management document for PFP Remove SNM Materials project. It specifies the technical, schedule, requirements and the cost baselines to manage the execution of the Remove SNM Materials project. Any deviations to the document must be authorized through the appropriate change control process

  9. Analysis of the material's expenditure of electric contacts by means of the isotopic method

    International Nuclear Information System (INIS)

    Farkash, K.

    1979-01-01

    To investigate lifetime of the weak-current and heavy-current contacts different radioisotopic methods have been developed. Advantages of the radioisotopic methods as compared with other methods of testing consists of the fact that due to their sensitivity they permit to determine low expense of material; permit to determine quantitatively expense of each element separately from the elements, composing the contacts alloy; by means of these methods it is possible to evaluate quantitatively topological distribution of the matter separated from the contacts into the environment; it is possible to determine morphological characteristics of the matter separated from the contact. During investigation of the lifetime of contacts there were determined: value of the expense of the material of contacts; composition of the expense of the material of contacts; composition of the matter separated from the contact; distribution of the separated matter depending on the electrical parameters and number of the closings of contact in the case of different compositions of contacts and in different conditions. Strength of the contacts' alloys related to the electrical load was investigated at the special stand [ru

  10. Strategic special nuclear material Inventory Differences. Semiannual report, April 1-September 30, 1984

    International Nuclear Information System (INIS)

    1985-07-01

    This sixteenth periodic semiannual report of Inventory Differences (ID) covers the last six months of fiscal year 1984 (April 1, 1984, through September 30, 1984), for the Department of Energy (DOE) and DOE contractor facilities possessing significant quantities of strategic special nuclear material (SSNM). Inventory Differences are simply the differences between the amount of material shown in the accounting records and the amount of material reported in the physical inventory. These differences are generally due to errors in estimating material in unmeasurable form at the time of an inventory, unmeasurable holdup in equipment, measurement imprecisions, inaccuracies in initial determinations of SSNM produced or used in nuclear reactors, and inventory or bookkeeping errors. Both DOE and contractors operating DOE facilities carefully maintain, analyze, and investigate ID data. Inventory Differences are expected in nuclear material processing and are not, in and of themselves, evidence of lost or stolen material. On the other hand, ID analysis provides valuable information on the effectiveness of the safeguards system's physical protection and material control measures as well as a check on the process controls and material management procedures. ID's outside safeguards control limits or involving a missing SSNM discrete item are investigated. If necessary, an operation may be shut down until an ID is resolved

  11. Nicotine, acetanilide and urea multi-level2H-,13C- and15N-abundance reference materials for continuous-flow isotope ratio mass spectrometry

    Science.gov (United States)

    Schimmelmann, A.; Albertino, A.; Sauer, P.E.; Qi, H.; Molinie, R.; Mesnard, F.

    2009-01-01

    Accurate determinations of stable isotope ratios require a calibration using at least two reference materials with different isotopic compositions to anchor the isotopic scale and compensate for differences in machine slope. Ideally, the S values of these reference materials should bracket the isotopic range of samples with unknown S values. While the practice of analyzing two isotopically distinct reference materials is common for water (VSMOW-SLAP) and carbonates (NBS 19 and L-SVEC), the lack of widely available organic reference materials with distinct isotopic composition has hindered the practice when analyzing organic materials by elemental analysis/isotope ratio mass spectrometry (EA-IRMS). At present only L-glutamic acids USGS40 and USGS41 satisfy these requirements for ??13C and ??13N, with the limitation that L-glutamic acid is not suitable for analysis by gas chromatography (GC). We describe the development and quality testing of (i) four nicotine laboratory reference materials for on-line (i.e. continuous flow) hydrogen reductive gas chromatography-isotope ratio mass-spectrometry (GC-IRMS), (ii) five nicotines for oxidative C, N gas chromatography-combustion-isotope ratio mass-spectrometry (GC-C-IRMS, or GC-IRMS), and (iii) also three acetanilide and three urea reference materials for on-line oxidative EA-IRMS for C and N. Isotopic off-line calibration against international stable isotope measurement standards at Indiana University adhered to the 'principle of identical treatment'. The new reference materials cover the following isotopic ranges: ??2Hnicotine -162 to -45%o, ??13Cnicotine -30.05 to +7.72%, ?? 15Nnicotine -6.03 to +33.62%; ??15N acetanilide +1-18 to +40.57%; ??13Curea -34.13 to +11.71%, ??15Nurea +0.26 to +40.61% (recommended ?? values refer to calibration with NBS 19, L-SVEC, IAEA-N-1, and IAEA-N-2). Nicotines fill a gap as the first organic nitrogen stable isotope reference materials for GC-IRMS that are available with different ??13N

  12. Nicotine, acetanilide and urea multi-level 2H-, 13C- and 15N-abundance reference materials for continuous-flow isotope ratio mass spectrometry.

    Science.gov (United States)

    Schimmelmann, Arndt; Albertino, Andrea; Sauer, Peter E; Qi, Haiping; Molinie, Roland; Mesnard, François

    2009-11-01

    Accurate determinations of stable isotope ratios require a calibration using at least two reference materials with different isotopic compositions to anchor the isotopic scale and compensate for differences in machine slope. Ideally, the delta values of these reference materials should bracket the isotopic range of samples with unknown delta values. While the practice of analyzing two isotopically distinct reference materials is common for water (VSMOW-SLAP) and carbonates (NBS 19 and L-SVEC), the lack of widely available organic reference materials with distinct isotopic composition has hindered the practice when analyzing organic materials by elemental analysis/isotope ratio mass spectrometry (EA-IRMS). At present only L-glutamic acids USGS40 and USGS41 satisfy these requirements for delta13C and delta15N, with the limitation that L-glutamic acid is not suitable for analysis by gas chromatography (GC). We describe the development and quality testing of (i) four nicotine laboratory reference materials for on-line (i.e. continuous flow) hydrogen reductive gas chromatography-isotope ratio mass-spectrometry (GC-IRMS), (ii) five nicotines for oxidative C, N gas chromatography-combustion-isotope ratio mass-spectrometry (GC-C-IRMS, or GC-IRMS), and (iii) also three acetanilide and three urea reference materials for on-line oxidative EA-IRMS for C and N. Isotopic off-line calibration against international stable isotope measurement standards at Indiana University adhered to the 'principle of identical treatment'. The new reference materials cover the following isotopic ranges: delta2H(nicotine) -162 to -45 per thousand, delta13C(nicotine) -30.05 to +7.72 per thousand, delta15N(nicotine) -6.03 to +33.62 per thousand; delta15N(acetanilide) +1.18 to +40.57 per thousand; delta13C(urea) -34.13 to +11.71 per thousand, delta15N(urea) +0.26 to +40.61 per thousand (recommended delta values refer to calibration with NBS 19, L-SVEC, IAEA-N-1, and IAEA-N-2). Nicotines fill a gap as

  13. Preparation, characterization and certification of uranium isotope reference materials; Preparacao, Caracterizacao e certificacao de materiais de referencia isotopicos de uranio

    Energy Technology Data Exchange (ETDEWEB)

    Oliveira Junior, Olivio Pereira de

    2006-07-01

    This work describes the preparation, characterization and certification of a set of uranium isotope reference materials ranging from 0.5 to 20.0 % of {sup 235}U in mass. The most important concepts of metrology in chemical measurements were applied so that the certified quantities in these materials could be directly traceable to the International System of Units (SI). As a consequence of this approach, these materials can be used in the instruments calibration, estimation of measurement uncertainty, method validation, assessment of performance of analysts, quality control routines and interlaboratory comparison programmes. The most advanced methods and techniques in mass spectrometry, that is, gas source mass spectrometry (GSMS), thermal ionisation mass spectrometry (TIMS) and inductively coupled plasma mass spectrometry (ICPMS) were investigated to identify which are the dominant components in the uncertainty and to quantify its contribution to the final value of the measurement uncertainty of the isotopic ratio. The results obtained were then compared to verify which are the methods and techniques associated to the lowest measurement uncertainty values. The isotope amount ratio n({sup 235}U)/n({sup 238}U) was certified in the materials produced to expanded uncertainties ranging from 0.02 to 0.10 % and the ratios n({sup 234}U)/n({sup 238}U) and n({sup 236}U)/n({sup 238}U), to uncertainties ranging from 0.03 to 2.20 %. These values fully comply to the requirements of the isotopic characterization of nuclear fuel as well as the analysis of environmental samples for nuclear safeguards. (author)

  14. Hot vacuum extraction-isotopic dilution mass spectrometry for determination of hydrogen isotopes in zircaloys

    International Nuclear Information System (INIS)

    Shi, Y.; Leeson, P.K.; Wilkin, D.; Britton, A.; Macleod, R.

    2016-01-01

    A hot vacuum extraction-isotope dilution mass spectrometry (HVE-IDMS) was studied for determination of hydrogen isotopes in zirconium metal and alloys as nuclear reactor materials. A theoretical assessment of the completeness of the extraction of hydrogen isotopes under the chosen condition was carried out based on the hydrogen and deuterium solubility data for zirconium. The optimal isotopic spiking condition for conventional IDMS was further explored for the special case IDMS where the isotope abundance of the samples is varied and non-natural. Applying the optimal conditions, the accurate IDMS determination was realized. The agreement between the measured values and the certified or prepared values of standard reference materials and homemade standard materials validate the method developed. (author)

  15. Reference and intercomparison materials for stable isotopes of light elements. Proceedings of a consultants meeting held in Vienna, 1-3 December 1993

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-09-01

    The stable isotope composition of elements varies in natural compounds as a consequence of the slightly different physico-chemical behaviour of isotopes. The possibility of measuring the stable isotope relative variations with high precision, using mass spectrometry, promoted the rise of new fields of research in geochemistry and hydrology and, more recently, in environmental studies. The steady growth of these investigations and of their practical applications has emphasized the need for high quality isotopic standards and intercomparison samples, with well determined isotopic composition, for the intercalibration of analytical techniques and results among laboratories. The organization of the Consultants Meeting on Stable Isotope Standards and Intercomparison Materials held in Vienna from 1 to 3 December 1993, the fifth of this type (the previous meetings took place in 1966, 1976, 1983 and 1985), called for a review and a discussion of the characteristics, quality and availability of the existing standards and intercalibration materials, and for an assessment of needs for new materials, in view of recent developments and applications. A large part of the discussions was devoted to the new materials prepared for sulphur isotope analysis and the analytical requirements for highly precise isotopic analysis of CO{sub 2}. The papers presented at the meeting are assembled in this volume. Refs, figs and tabs.

  16. Reference and intercomparison materials for stable isotopes of light elements. Proceedings of a consultants meeting held in Vienna, 1-3 December 1993

    International Nuclear Information System (INIS)

    1995-09-01

    The stable isotope composition of elements varies in natural compounds as a consequence of the slightly different physico-chemical behaviour of isotopes. The possibility of measuring the stable isotope relative variations with high precision, using mass spectrometry, promoted the rise of new fields of research in geochemistry and hydrology and, more recently, in environmental studies. The steady growth of these investigations and of their practical applications has emphasized the need for high quality isotopic standards and intercomparison samples, with well determined isotopic composition, for the intercalibration of analytical techniques and results among laboratories. The organization of the Consultants Meeting on Stable Isotope Standards and Intercomparison Materials held in Vienna from 1 to 3 December 1993, the fifth of this type (the previous meetings took place in 1966, 1976, 1983 and 1985), called for a review and a discussion of the characteristics, quality and availability of the existing standards and intercalibration materials, and for an assessment of needs for new materials, in view of recent developments and applications. A large part of the discussions was devoted to the new materials prepared for sulphur isotope analysis and the analytical requirements for highly precise isotopic analysis of CO 2 . The papers presented at the meeting are assembled in this volume. Refs, figs and tabs

  17. Enhancement of isotope exchange reactions over ceramic breeder material by deposition of catalyst metal

    International Nuclear Information System (INIS)

    Narisato, Y.; Munakata, K.; Koga, A.; Yokoyama, Y.; Takata, T.; Okabe, H.

    2004-01-01

    The deposition of catalyst metals in ceramic breeders could enhance the release rate of tritium due to the promotion of isotope exchange reactions taking place at the interface of the breeder surface and the sweep gas. In this work, the authors examined the effects of catalytic active metal deposited on lithium titanate on the isotope exchange reactions. With respect to the virgin lithium titanate, it was found that the rate of the isotope exchange reactions taking place on the surface is quite low. However, the deposition of palladium greatly increased the exchange reaction rate. The effect of the amounts of deposited palladium on the isotope exchange reaction rate was also investigated. The results indicate that the exchange reactions are still enhanced even if the amounts of deposited palladium are as low as 0.04%

  18. Directory of national competent authorities' approval certificates for package design, special form material and shipment of radioactive material. 2003 ed

    International Nuclear Information System (INIS)

    2003-10-01

    This is the fourteenth annual report being published by the Secretariat of the International Atomic Energy Agency since implementing its database on package approval certificates (PACKTRAM) at the recommendation of the Transport Safety Standards Committee (TRANSSC). It supersedes IAEA-TECDOC-1302 'Directory of National Competent Authorities' Approval Certificates for Package Design, Special Form Material and Shipment of Radioactive Material, 2002 Edition'. Through the database, the Secretariat collects administrative and technical information provided by the issuing competent authority about package approval certificates. Such data are used mainly by national competent authorities and port and customs officials to assist in regulating radioactive material movements in their country, and also by manufacturers and shippers of radioactive material. The database carries information on extant certificates and those that expired within the last complete calendar year. The PACKTRAM database only contains information that has been provided to the IAEA. The data are not complete nor guaranteed to be accurate. If detailed information is required, the original package approval certificates must be consulted. If information is required about package approval certificates that are not contained in the database, the issuing competent authority must be consulted

  19. Directory of national competent authorities' approval certificates for package design, special form material and shipment of radioactive material. 2003 ed

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2003-10-01

    This is the fourteenth annual report being published by the Secretariat of the International Atomic Energy Agency since implementing its database on package approval certificates (PACKTRAM) at the recommendation of the Transport Safety Standards Committee (TRANSSC). It supersedes IAEA-TECDOC-1302 'Directory of National Competent Authorities' Approval Certificates for Package Design, Special Form Material and Shipment of Radioactive Material, 2002 Edition'. Through the database, the Secretariat collects administrative and technical information provided by the issuing competent authority about package approval certificates. Such data are used mainly by national competent authorities and port and customs officials to assist in regulating radioactive material movements in their country, and also by manufacturers and shippers of radioactive material. The database carries information on extant certificates and those that expired within the last complete calendar year. The PACKTRAM database only contains information that has been provided to the IAEA. The data are not complete nor guaranteed to be accurate. If detailed information is required, the original package approval certificates must be consulted. If information is required about package approval certificates that are not contained in the database, the issuing competent authority must be consulted.

  20. Introduction to the special issue on the technical status of materials for a fusion reactor

    Science.gov (United States)

    Stork, D.; Zinkle, S. J.

    2017-09-01

    Materials determine in a fundamental way the performance and environmental attractiveness of a fusion reactor: through the size (power fluxes to the divertor, neutron fluxes to the first wall); economics (replacement lifetime of critical in-vessel components, thermodynamic efficiency through operating temperature etc); plasma performance (erosion by plasma fluxes to the divertor surfaces); robustness against off-normal accidents (safety); and the effects of post-operation radioactivity on waste disposal and maintenance. The major philosophies and methodologies used to formulate programmes for the development of fusion materials are outlined, as the basis for other articles in this special issue, which deal with the fundamental understanding of the issues regarding these materials and their technical status and prospects for development.

  1. Evaluating safeguards effectiveness against protracted theft of special nuclear material by insiders

    International Nuclear Information System (INIS)

    Al-Ayat, R.A.; Sicherman, A.

    1991-01-01

    The new draft DOE Material Control and Accountability Order 5633.3 requires that facilities handling special nuclear material (SNM) evaluate their effectiveness against protracted theft of SNM. Protracted theft means repeated thefts of small quantities of material to accumulate a goal quantity. In this paper the authors discuss issues regarding the evaluation of safeguards and describe how we are augmenting the Analytic System and Software for Evaluating Safeguards and Security (ASSESS) to provide the user with a tool for evaluating effectiveness against protracted theft. Currently, the Insider module of ASSESS focuses on evaluating the timely detection of abrupt theft attempts by various types of single nonviolent insiders. In this paper we describe the approach we're implementing to augment ASSESS to handle various cases of protracted theft attempts

  2. Environmental considerations associated with siting, constructing, and operating a special isotope separation plant at INEL: Volume 1, Proceedings: Report of public hearings

    International Nuclear Information System (INIS)

    1987-03-01

    This report documents the two public hearings conducted for the purpose of determining the scope of issues to be addressed in relation to the siting, constructing, and operating of a special isotope separation plant at INEL. The report includes transcripts of the public hearings held in Idaho Falls, Idaho, February 24, 1987, and in Boise, Idaho, February 26, 1987, and includes the exhibits of records relating to those hearings. The review and hearing process meets pertinent National Environmental Policy Act (NEPA) requirements, Council on Environmental Quality (CEQ) regulations, and DOE guidelines

  3. Environmental considerations associated with siting, constructing, and operating a special isotope separation plant at INEL: Volume 2, Proceedings: Report of public hearings

    International Nuclear Information System (INIS)

    1987-03-01

    This report documents the two public hearings conducted for the purpose of determining the scope of issues to be addressed in relation to the siting, constructing, and operating of a special isotope separation plant at INEL. The report includes transcripts of the public hearings held in Idaho Falls, Idaho, February 24, 1987, and in Boise, Idaho, February 26, 1987, and includes the exhibits of record relating to those hearings. The review and hearing process meets pertinent National Environmental Policy Act (NEPA) requirements, Council on Environmental Quality (CEQ) regulations, and DOE guidelines

  4. Essentials of iron, chromium, and calcium isotope analysis of natural materials by thermal ionization mass spectrometry

    Science.gov (United States)

    Fantle, M.S.; Bullen, T.D.

    2009-01-01

    The use of isotopes to understand the behavior of metals in geological, hydrological, and biological systems has rapidly expanded in recent years. One of the mass spectrometric techniques used to analyze metal isotopes is thermal ionization mass spectrometry, or TIMS. While TIMS has been a useful analytical technique for the measurement of isotopic composition for decades and TIMS instruments are widely distributed, there are significant difficulties associated with using TIMS to analyze isotopes of the lighter alkaline earth elements and transition metals. Overcoming these difficulties to produce relatively long-lived and stable ion beams from microgram-sized samples is a non-trivial task. We focus here on TIMS analysis of three geologically and environmentally important elements (Fe, Cr, and Ca) and present an in-depth look at several key aspects that we feel have the greatest potential to trouble new users. Our discussion includes accessible descriptions of different analytical approaches and issues, including filament loading procedures, collector cup configurations, peak shapes and interferences, and the use of isotopic double spikes and related error estimation. Building on previous work, we present quantitative simulations, applied specifically in this study to Fe and Ca, that explore the effects of (1) time-variable evaporation of isotopically homogeneous spots from a filament and (2) interferences on the isotope ratios derived from a double spike subtraction routine. We discuss how and to what extent interferences at spike masses, as well as at other measured masses, affect the double spike-subtracted isotope ratio of interest (44Ca/40Ca in the case presented, though a similar analysis can be used to evaluate 56Fe/54Fe and 53Cr/52Cr). The conclusions of these simulations are neither intuitive nor immediately obvious, making this examination useful for those who are developing new methodologies. While all simulations are carried out in the context of a

  5. High Precision Zinc Stable Isotope Measurement of Certified Biological Reference Materials Using the Double Spike Technique and Multiple Collector-ICP-MS.

    Science.gov (United States)

    Moore, Rebekah E T; Larner, Fiona; Coles, Barry J; Rehkämper, Mark

    2017-04-01

    Biological reference materials with well-characterised stable isotope compositions are lacking in the field of 'isotope biochemistry', which seeks to understand bodily processes that rely on essential metals by determining metal stable isotope ratios. Here, we present Zn stable isotope data for six biological reference materials with certified trace metal concentrations: fish muscle, bovine muscle, pig kidney, human hair, human blood serum and human urine. Replicate analyses of multiple aliquots of each material achieved reproducibilities (2sd) of 0.04-0.13‰ for δ 66/64 Zn (which denotes the deviation of the 66 Zn/ 64 Zn ratio of a sample from a pure Zn reference material in parts per 1000). This implies only very minor isotopic heterogeneities within the samples, rendering them suitable as quality control materials for Zn isotope analyses. This endorsement is reinforced by (i) the close agreement of our Zn isotope data for two of the samples (bovine muscle and human blood serum) to previously published results for different batches of the same material and (ii) the similarity of the isotopic data for the samples (δ 66/64 Zn ≈ -0.8 to 0.0‰) to previously published Zn isotope results for similar biological materials. Further tests revealed that the applied Zn separation procedure is sufficiently effective to enable accurate data acquisition even at low mass resolving power (M/ΔM ≈ 400), as measurements and analyses conducted at much higher mass resolution (M/ΔM ≈ 8500) delivered essentially identical results.

  6. Evaluating safeguards effectiveness against protracted theft of special nuclear material by insiders

    International Nuclear Information System (INIS)

    Al-Ayat, R.; Sicherman, A.

    1991-01-01

    The new draft DOE Material Control and Accountability Order 5633.3 requires that facilities handling special nuclear material (SNM) evaluate their effectiveness against provided theft of SNMProtracted theft means repeated thefts of small quantities of material to accumulate a goal quanfity. To evaluate the safeguards effectiveness against pro thefts, one must addresses several issues: (1) defining relevant time frames for various threat scenarios and delayed detection safeguards: (2) identifying which safeguards come into play more than once because of repeated adversary actions or because of periodic occurrence during the theft time frame (e.g., daily administrative check on presence of material): (3) considering whether the second and subsequent applications of safeguards are different in effectiveness from the first; (4)synthesizing how physical security, material control, and material accountability safeguards combine to provide protection against protracted theft scenarios. In this paper we discuss these issues and describe how we are augmenting the Analytic System and Software for Evaluating Safeguards and Security (ASSESS) to provide the user with a tool for evaluating effectiveness against protracted theft. Currently, the Insider module of ASSESS focuses on evaluating the ''timely'' detection of abrupt theft attempts by various types of single nonviolent insiders. In this paper we describe the approach we're implementing to augment ASSESS to handle various cases of protracted theft attempts

  7. Determination of platinum-group elements in the geological standard reference materials by isotope dilution-ICPMS

    Energy Technology Data Exchange (ETDEWEB)

    Mingyue, Hu; Hongliao, He [National Research Center for Geoanalysis, Beijing (China)

    2005-10-15

    Platinum group elements (PGEs) includes platinum, palladium, iridium, osmium, rhodium and ruthenium. It has very high economic and scientific value in the field of geoscience and environmental science. But the analysis data referred by the different lab are very disperse because of the difficulty of the determination of PGEs. It makes very difficult to fix the value of the PGEs in the standard reference materials. In the article, the values of the PGEs in the standard reference materials of ocean sediment are determined by isotope dilution technique and dependable values of these elements are provided. (authors)

  8. Determination of platinum-group elements in the geological standard reference materials by isotope dilution-ICPMS

    International Nuclear Information System (INIS)

    Hu Mingyue; He Hongliao

    2005-01-01

    Platinum group elements (PGEs) includes platinum, palladium, iridium, osmium, rhodium and ruthenium. It has very high economic and scientific value in the field of geoscience and environmental science. But the analysis data referred by the different lab are very disperse because of the difficulty of the determination of PGEs. It makes very difficult to fix the value of the PGEs in the standard reference materials. In the article, the values of the PGEs in the standard reference materials of ocean sediment are determined by isotope dilution technique and dependable values of these elements are provided. (authors)

  9. Nuclear and isotopic techniques for addressing nutritional problems, with special reference to current applications in developing countries.

    Science.gov (United States)

    Iyengar, Venkatesh

    2002-03-01

    Nuclear and isotopic techniques are valuable tools in human nutritional research studies. Isotopes, both radioactive and nonradioactive, enable detailed evaluations of nutrient intake, body composition, energy expenditure, status of micronutrients, and nutrient bioavailability. In recent times, isotopic methods have been widely used in a number of coordinated research projects and technical cooperation projects of the International Atomic Energy Agency's Nutrition Programme. The doubly labeled water technique combines the use of the stable isotopes oxygen-18 and hydrogen-2 (deuterium) to measure total energy expenditure in free-living human subjects, and to investigate the magnitude and causes of both undernutrition and the emergence of obesity in developing countries. The deuterium dilution technique is a reliable tool to measure breastmilk intake and thereby infant growth and development. In collaboration with the World Health Organization's Growth Monitoring Program, this technique is being used to generate new data on growth standards for children in developing countries. This technique is also used in the measurement of body composition by the estimation of lean body mass and fat mass in individuals. Stable isotopes of iron and zinc have been successfully used to assess the nutritional impact of several nationwide food supplementation-programs conducted on pregnant and lactating women and children in both industrialized and developing countries. Isotopic techniques are especially suitable for monitoring changes in body composition, energy metabolism, and mineral status (with particular reference to osteoporosis) in the elderly. Nuclear methods have also served to develop models for a physiological reference man in Asia in support of radiological health and safety issues, for establishing elemental composition of foods, and for measurement of pollutants in the environment.

  10. A data communications systems for tamper-protected special nuclear materials (SNM) inventory management

    International Nuclear Information System (INIS)

    Hurkamp, A.C.

    1995-01-01

    The Department of Energy (D.O.E.) is responsible for the long term storage and protection of large quantities of Special Nuclear Material (SNM). This material is stored within individual containers located in vaults. Security measures are required to ensure that the SNM remains within the canisters where it is stored and that it is not disturbed in any manner. Conventional security and inventory techniques are manpower intensive and often require exposure to radiation hazards. The Purpose of this D.O.E sponsored project is to develop a cost effective system to monitor Special Nuclear Materials that, when fielded, would result in an extension of manual inventory cycles at a wide variety of SNM storage locations. The system consists of a computer, radio frequency interrogator, and individual miniaturized radio frequency transponders (tags) that are co-located with individual SNM containers. Each tag can perform SNM inventory, tamper alarm, and multiple sensor data transmission to the interrogator under the control of software designed by the user. SNM custodians can customize the system by their choice of packaging, software, and sensors. When implemented in accordance with current department of energy (D.O.E.) Policy on SNM inventory extension, the system has the potential to qualify for maximum extension times thus saving considerable resources through reduction of radiation exposure

  11. A novel method to assay special nuclear materials by measuring prompt neutrons from polarized photofission

    Energy Technology Data Exchange (ETDEWEB)

    Mueller, J.M., E-mail: mueller@tunl.duke.edu [Triangle Universities Nuclear Laboratory, Durham, NC 27710 (United States); Department of Physics, Duke University, Durham, NC 27708 (United States); Ahmed, M.W. [Triangle Universities Nuclear Laboratory, Durham, NC 27710 (United States); Department of Physics, Duke University, Durham, NC 27708 (United States); Department of Mathematics and Physics, North Carolina Central University, Durham, NC 27707 (United States); Weller, H.R. [Triangle Universities Nuclear Laboratory, Durham, NC 27710 (United States); Department of Physics, Duke University, Durham, NC 27708 (United States)

    2014-08-01

    A novel method of measuring the enrichment of special nuclear material is presented. Recent photofission measurements using a linearly polarized γ-ray beam were performed on samples of {sup 232}Th, {sup 233,235,238}U, {sup 237}Np, and {sup 239,240}Pu. Prompt neutron polarization asymmetries, defined to be the difference in the prompt neutron yields parallel and perpendicular to the plane of beam polarization divided by their sum, were measured. It was discovered that the prompt neutron polarization asymmetries differed significantly depending on the sample. Prompt neutrons from photofission of even–even (non-fissile) targets had significant polarization asymmetries (∼0.2 to 0.5), while those from odd-A (generally fissile) targets had polarization asymmetries close to zero. This difference in the polarization asymmetries could be exploited to measure the fissile versus non-fissile content of special nuclear materials, and potentially to detect the presence of fissile material during active interrogation. The proposed technique, its expected performance, and its potential applicability are discussed.

  12. A novel method to assay special nuclear materials by measuring prompt neutrons from polarized photofission

    International Nuclear Information System (INIS)

    Mueller, J.M.; Ahmed, M.W.; Weller, H.R.

    2014-01-01

    A novel method of measuring the enrichment of special nuclear material is presented. Recent photofission measurements using a linearly polarized γ-ray beam were performed on samples of 232 Th, 233,235,238 U, 237 Np, and 239,240 Pu. Prompt neutron polarization asymmetries, defined to be the difference in the prompt neutron yields parallel and perpendicular to the plane of beam polarization divided by their sum, were measured. It was discovered that the prompt neutron polarization asymmetries differed significantly depending on the sample. Prompt neutrons from photofission of even–even (non-fissile) targets had significant polarization asymmetries (∼0.2 to 0.5), while those from odd-A (generally fissile) targets had polarization asymmetries close to zero. This difference in the polarization asymmetries could be exploited to measure the fissile versus non-fissile content of special nuclear materials, and potentially to detect the presence of fissile material during active interrogation. The proposed technique, its expected performance, and its potential applicability are discussed

  13. Detecting special nuclear materials in suspect containers using high-energy gamma rays emitted by fission products

    Science.gov (United States)

    Norman, Eric B [Oakland, CA; Prussin, Stanley G [Kensington, CA

    2009-01-27

    A method and a system for detecting the presence of special nuclear materials in a suspect container. The system and its method include irradiating the suspect container with a beam of neutrons, so as to induce a thermal fission in a portion of the special nuclear materials, detecting the gamma rays that are emitted from the fission products formed by the thermal fission, to produce a detector signal, comparing the detector signal with a threshold value to form a comparison, and detecting the presence of the special nuclear materials using the comparison.

  14. Magnesium isotope compositions of Solar System materials determined by double spiking

    Science.gov (United States)

    Hin, R.; Lai, Y. J.; Coath, C.; Elliott, T.

    2015-12-01

    As a major element, magnesium is of interest for investigating large scale processes governing the formation and evolution of rocky planetary bodies. Determining the Mg isotope composition of the Earth and other planetary bodies has hence been a topic of interest ever since mass-dependent fractionation of 'non-traditional' stable isotopes has been used to study high-temperature processes. Published results, however, suffer from disagreement on the Mg isotope compositions of the Earth and chondrites [1-5], which is attributed to residual matrix effects. Nonetheless, most recent studied have converged towards a homogeneous (chondritic) Mg isotope composition in the Solar System [2-5]. However, in several of the recent studies there is a hint of a systematic difference of about 0.02-0.06‰ in the 26Mg/24Mg isotope compositions of chondrites and Earth. Such difference, however, is only resolvable by taking standard errors, which assumes robust data for homogenous sample sets. The discrepancies between various studies unfortunately undermine the confidence in such robustness and homogeneity. The issues with matrix effects during isotopic analyses can be overcome by using a double spike approach. Such methodology generally requires three isotope ratios to solve for three unknowns, a requirement that cannot be met for Mg. However, using a newly developed approach, we present Mg isotope compositions obtained by critical mixture double spiking. This new approach should allow greater confidence in the robustness of the data and hence enable improvement of. Preliminary data indicate that chondrites have a resolvable ~0.04‰ lighter 26Mg/24Mg than (ultra)mafic rocks from Earth, Mars and the eucrite parent body, which appear indistinguishable from each other. It seems implausible that this difference is caused by magmatic process such as partial melting or crystallisation. More likely, Mg isotopes are fractionated by a non-magmatic process during the formation of planets, e

  15. Investigation of the isotopic composition of lead and of trace elements concentrations in natural uranium materials as a signature in nuclear forensics

    Energy Technology Data Exchange (ETDEWEB)

    Svedkauskaite-LeGore, J. [European Commission, Joint Research Centre, Karlsruhe (Germany). Inst. for Transuranium Elements; Institute of Physics, Vilnius (Lithuania); Mayer, K.; Millet, S.; Nicholl, A.; Rasmussen, G. [European Commission, Joint Research Centre, Karlsruhe (Germany). Inst. for Transuranium Elements; Baltrunas, D. [Institute of Physics, Vilnius (Lithuania)

    2007-07-01

    Lead is contained as trace element in uranium ores and propagates throughout the production process to intermediate products like yellow cake or uranium oxide. The lead isotopes in such material originate from two sources: natural lead and radiogenic lead. The variability of the isotopic composition of lead in ores and yellow cakes was studied and the applicability of this parameter for nuclear forensic investigations was investigated. Furthermore, the chemical impurities contained in these materials were measured in order to identify characteristic differences between materials from different mines. For the samples investigated, it could be shown, that the lead isotopic composition varies largely from mine to mine and it may be used as one of the parameters to distinguish between materials of different origins. Some of the chemical impurities show a similar pattern and support the conclusions drawn from the lead isotope data. (orig.)

  16. Special training for drivers of vehicles carrying radioactive materials in Germany

    International Nuclear Information System (INIS)

    Ridder, K.

    1993-01-01

    In Germany drivers of vehicles carrying radioactive materials have to undergo special training since midyear 1991. Training is organized in a modular system, which means that the driver can customize his dangerous goods training programme by combining several modules. The contents of the training programme, its organization and supervision as well as the means for checking the successful completion of the programme can be seen from the slides. This paper will close with an outlook on the European development, considering the framework set by the regulations of the Economic Commission for Europe (ECE) and the European Community (EC). (J.P.N.)

  17. Computer-based accountability system (Phase I) for special nuclear materials at Argonne-West

    International Nuclear Information System (INIS)

    Ingermanson, R.S.; Proctor, A.E.

    1982-05-01

    An automated accountability system for special nuclear materials (SNM) is under development at Argonne National Laboratory-West. Phase I of the development effort has established the following basic features of the system: a unique file organization allows rapid updating or retrieval of the status of various SNM, based on batch numbers, storage location, serial number, or other attributes. Access to the program is controlled by an interactive user interface that can be easily understood by operators who have had no prior background in electronic data processing. Extensive use of structured programming techniques make the software package easy to understand and to modify for specific applications. All routines are written in FORTRAN

  18. Stable isotope analyses of oxygen (18O:17O:16O) and chlorine (37Cl:35Cl) in perchlorate: reference materials, calibrations, methods, and interferences

    Science.gov (United States)

    Böhlke, John Karl; Mroczkowski, Stanley J.; Sturchio, Neil C.; Heraty, Linnea J.; Richman, Kent W.; Sullivan, Donald B.; Griffith, Kris N.; Gu, Baohua; Hatzinger, Paul B.

    2017-01-01

    RationalePerchlorate (ClO4−) is a common trace constituent of water, soils, and plants; it has both natural and synthetic sources and is subject to biodegradation. The stable isotope ratios of Cl and O provide three independent quantities for ClO4− source attribution and natural attenuation studies: δ37Cl, δ18O, and δ17O (or Δ17O or 17Δ) values. Documented reference materials, calibration schemes, methods, and interferences will improve the reliability of such studies.MethodsThree large batches of KClO4 with contrasting isotopic compositions were synthesized and analyzed against VSMOW-SLAP, atmospheric O2, and international nitrate and chloride reference materials. Three analytical methods were tested for O isotopes: conversion of ClO4− to CO for continuous-flow IRMS (CO-CFIRMS), decomposition to O2 for dual-inlet IRMS (O2-DIIRMS), and decomposition to O2 with molecular-sieve trap (O2-DIIRMS+T). For Cl isotopes, KCl produced by thermal decomposition of KClO4 was reprecipitated as AgCl and converted into CH3Cl for DIIRMS.ResultsKClO4 isotopic reference materials (USGS37, USGS38, USGS39) represent a wide range of Cl and O isotopic compositions, including non-mass-dependent O isotopic variation. Isotopic fractionation and exchange can affect O isotope analyses of ClO4− depending on the decomposition method. Routine analyses can be adjusted for such effects by normalization, using reference materials prepared and analyzed as samples. Analytical errors caused by SO42−, NO3−, ReO42−, and C-bearing contaminants include isotope mixing and fractionation effects on CO and O2, plus direct interference from CO2 in the mass spectrometer. The results highlight the importance of effective purification of ClO4− from environmental samples.ConclusionsKClO4 reference materials are available for testing methods and calibrating isotopic data for ClO4− and other substances with widely varying Cl or O isotopic compositions. Current ClO4−extraction, purification

  19. Isotopic Determination of Nuclear Materials Using Nuclear Fission Track Registration Technique and Thermal Ionization Mass Spectrometric Technique

    International Nuclear Information System (INIS)

    Jeon, Young Sin; Pyo, Hyeong Yeol; Park, Yong Joon; Song, Kyu Seok; Kim, Won Ho; Jee, Kwang Yong

    2007-05-01

    It is very important to develope the technology for the determination of isotopic ratios of hot particles( 234 U, 235 U, 236 U etc.) detected from swipe samples of various nuclear facilities. This technology is highly competitive internationally and has to be established independently as long as our government maintains atomic energy and treats nuclear materials. In this text, sample pretreatment procedure, gamma-ray counting, alpha or fission track techniques, isotopic analysis of U and Pu, background problems and detection limits for mass determination, and their application to the real swipe sample were described with detailed procedure. This technology would contribute to the Korean economy's high growth rate as well as to superiority of government's leading research and development programs if successfully established

  20. Stable carbon isotope composition of organic material and carbonate in sediment of a swamp and lakes in Honshu island, Japan

    International Nuclear Information System (INIS)

    Ishizuka, Toshio

    1978-01-01

    Recent sediments from a swamp and lakes in Honshu were analyzed for organic carbon and carbonate contents, and stable isotope ratios of carbon in the organic materials and carbonate. delta C 13 values of the carbonate tend to be distinctly larger than those of organic carbon in reducing condition as natural gas field, whereas in oxidizing SO 4 -reducing conditions, they are slightly larger than those of organic carbon within the limited range of a few per mil. Carbon isotopic compositions of organic carbon in sediment of the swamp, Obuchi-numa, were analyzed and compared with habitat analysis of associated fossil diatoms. deltaC 13 values of organic carbon in the sediment vary in correlation with the species abundance in habitat of the associated fossil diatoms, ranging from fresh-water (-0.0282) to coastal marine (-0.0236) via brackish. (auth.)

  1. Glass fiber sensors for detecting special nuclear materials at portal and monitor stations

    International Nuclear Information System (INIS)

    Hull, C.D.; Seymour, R.; Crawford, T.; Bliss, M.; Craig, R.A.

    2001-01-01

    Nuclear Safeguards and Security Systems LLC (NucSafe) participated in the Illicit Trafficking Radiation Assessment Program (ITRAP) recently conducted by the Austrian Research Center, Seibersdorf (ARCS) for IAEA, INTERPOL, and the World Customs Organization (IAEA, in press). This presentation reviews ITRAP test results of NucSafe instrumentation. NucSafe produces stationary, mobile, and hand-held systems that use neutron and gamma ray sensors to detect Special Nuclear Materials (SNM). Neutron sensors are comprised of scintillating glass fibers (trade name 'PUMA' for Pu Materials Analysis), which provide several advantages over 3 He and 10 BF 3 tubes. PUMA 6 Li glass fiber sensors offer greater neutron sensitivity and dynamic counting range with significantly less microphonic susceptibility than tubes, while eliminating transport and operational hazards. PUMA sensors also cost less per active area than gas tubes, which is important since rapid neutron detection at passenger, freight, and vehicle portals require large sensor areas to provide the required sensitivity

  2. Commissioning of calorimeter in radiochemical laboratory for non-destructive assay of special nuclear materials

    International Nuclear Information System (INIS)

    Patra, S.; Mhatre, A.M.; Agarwal, C.; Chaudhury, S.; Pujari, P.K.

    2017-01-01

    Accounting of special nuclear materials (SNM) in every stages of nuclear fuel cycle is a necessity where one needs the quantitative estimation of SNM in variety of samples like sealed containers or finished products without altering its physical and chemical form. Non-destructive assay (NDA) techniques are capable of assaying such samples by the way of measuring passive/active neutrons/gamma rays or by the measurement of decay heat. Radiochemistry Division has been actively involved in the development and deployment of various NDA methodologies for meeting the demand of nuclear material accounting as and when required. Recently a radiometric calorimeter, developed by Reactor Control Division, E and I Group, BARC, has been installed in Lab C-33, Radiochemistry Division

  3. The full bayesian evaluation technique and its application to isotopes of structural materials

    International Nuclear Information System (INIS)

    Neudecker, D.

    2012-01-01

    the experiments contrary to the too small evaluated uncertainties of other modern evaluation techniques. In addition, Peelle's Pertinent Puzzle - the occurrence of pathological mean values below the considered observables - was revisited. It could be shown that this long-standing problem in Nuclear Data Evaluation was caused by the improper estimate of the experimental covariance matrix and not exclusively by the non-linearities hidden in the experimental data as was generally believed. Because of the importance of prior knowledge for evaluations and in order to simplify future evaluations, a library of priors was set up containing prior cross sections and covariance matrices of 276 isotopes relevant for structural materials from Mg to Bi for nine frequently measured cross section channels. The feasibility and applicability of this library and the Full Bayesian Evaluation Technique is demonstrated by means of evaluations of Mn-55 and Pb-208. (author) [de

  4. Metabolic studies in man using stable isotopes

    International Nuclear Information System (INIS)

    Faust, H.; Jung, K.; Krumbiegel, P.

    1993-01-01

    In this project, stable isotope compounds and stable isotope pharmaceuticals were used (with emphasis on the application of 15 N) to study several aspects of nitrogen metabolism in man. Of the many methods available, the 15 N stable isotope tracer technique holds a special position because the methodology for application and nitrogen isotope analysis is proven and reliable. Valid routine methods using 15 N analysis by emission spectrometry have been demonstrated. Several methods for the preparation of biological material were developed during our participation in the Coordinated Research Programme. In these studies, direct procedures (i.e. use of diluted urine as a samples without chemical preparation) or rapid isolation methods were favoured. Within the scope of the Analytical Quality Control Service (AQCS) enriched stable isotope reference materials for medical and biological studies were prepared and are now available through the International Atomic Energy Agency. The materials are of special importance as the increasing application of stable isotopes as tracers in medical, biological and agricultural studies has focused interest on reliable measurements of biological material of different origin. 24 refs

  5. Characterization of a new candidate isotopic reference material for natural Pb using primary measurement method.

    Science.gov (United States)

    Nonose, Naoko; Suzuki, Toshihiro; Shin, Ki-Cheol; Miura, Tsutomu; Hioki, Akiharu

    2017-06-29

    A lead isotopic standard solution with natural abundance has been developed by applying a mixture of a solution of enriched 208 Pb and a solution of enriched 204 Pb ( 208 Pb- 204 Pb double spike solution) as bracketing method. The amount-of-substance ratio of 208 Pb: 204 Pb in this solution is accurately measured by applying EDTA titrimetry, which is one of the primary measurement methods, to each enriched Pb isotope solution. Also metal impurities affecting EDTA titration and minor lead isotopes contained in each enriched Pb isotope solution are quantified by ICP-SF-MS. The amount-of-substance ratio of 208 Pb: 204 Pb in the 208 Pb- 204 Pb double spike solution is 0.961959 ± 0.000056 (combined standard uncertainty; k = 1). Both the measurement of lead isotope ratios in a candidate isotopic standard solution and the correction of mass discrimination in MC-ICP-MS are carried out by coupling of a bracketing method with the 208 Pb- 204 Pb double spike solution and a thallium internal addition method, where thallium solution is added to the standard and the sample. The measured lead isotope ratios and their expanded uncertainties (k = 2) in the candidate isotopic standard solution are 18.0900 ± 0.0046 for 206 Pb: 204 Pb, 15.6278 ± 0.0036 for 207 Pb: 204 Pb, 38.0626 ± 0.0089 for 208 Pb: 204 Pb, 2.104406 ± 0.00013 for 208 Pb: 206 Pb, and 0.863888 ± 0.000036 for 207 Pb: 206 Pb. The expanded uncertainties are about one half of the stated uncertainty for NIST SRM 981, for 208 Pb: 204 Pb, 207 Pb: 204 Pb and 206 Pb: 204 Pb, or one eighth, for 208 Pb: 206 Pb and 207 Pb: 206 Pb, The combined uncertainty consists of the uncertainties due to lead isotope ratio measurements and the remaining time-drift effect of mass discrimination in MC-ICP-MS, which is not removed by the coupled correction method. In the measurement of 208 Pb: 204 Pb, 207 Pb: 204 Pb and 206 Pb: 204 Pb, the latter contribution is two or three times larger than the former. When the coupling of

  6. Physical protection of special nuclear materials in the Federal Republic of Germany

    International Nuclear Information System (INIS)

    Rossnagel, A.

    1987-01-01

    Measures to protect special nuclear materials in West Germany are based on a relatively likely average threat and not on the less-likely but maximum credible threat. The reason is to avoid the costs of maintaining a very high level of security that is seldom needed. The concept of delayed action, which divides the responsibility for security between private protection forces and local police forces, would be insufficient in the event of the maximum credible threat. In principle, sufficient security is possible only when the facilities and transports are constantly protected by a police force large enough to deal with the maximum credible threat without assistance from outside. They must also be adequately armed to avert all possible attackers, and they must be paid by the licensees. The threat of an insider(s) diverting special nuclear material can be addressed only by strengthening the scope and depth of the checks on applicants and employees and the permanent work controls. It is recognized, however, that such security measures may not be compatible with constitutional civil liberties

  7. Nickel-based materials and high-alloy, special stainless steels. 2. new rev. and enl. ed.

    International Nuclear Information System (INIS)

    Heubner, U.; Brill, U.; Hoffmann, T.; Jasner, M.; Kirchheiner, R.; Koecher, R.; Richter, H.; Rockel, M.; White, F.

    1993-01-01

    The book is intended as a source of information on nickel-based materials and special stainless steels and apart from the up-to-date materials data presents information on recent developments and knowledge gained, so that it may be a valuable aid to materials engineers looking for cost-effective resolutions of their materials problems in the chemical process industry, power plant operation, and high-temperature applications. The book presents eight individual contributions entitled as follows: (1) Nickel-base alloys and high-alloy, special stainless steels. - Materials survey and data sheets (Ulrich Heubner). (2) Corrosion of nickel-base alloys and special stainless steels (Manfred Rockel). (3) Welding of nickel-base alloys and high-alloy, special stainless steels (Theo Hoffmann). (4) High-temperature resistant materials (Ulrich Brill). (5) Application and processing of nickel-base materials in the chemical process industry and in pollution abatement equipment (Reiner Koecher). (6) Selected examples of applications of nickel-base materials in chemical plant (Manfred Jasner, Frederick White). (7) Applications of nickel-base alloys and special stainless steels in power plant. (8) The use of nickel-base alloys and stainless steels in pollution abatement processes (R. Kirchheiner). (orig./MM). 151 figs., 226 refs [de

  8. Isotope dilution mass spectrometry for nuclear material accountability measurements: dreams and reality

    International Nuclear Information System (INIS)

    Deron, S.; )

    1996-01-01

    Gravimetry, titration, coulometry and isotope dilution mass spectrometry are alternative techniques which can be used to obtain elemental assays of the desirable accuracy. The communication briefly describes the characteristics of the procedure and summarizes a wealth of experience accumulated during actual accountability verification activities

  9. Building materials as intrinsic sources of sulphate: A hidden face of salt weathering of historical monuments investigated through multi-isotope tracing (B, O, S)

    International Nuclear Information System (INIS)

    Kloppmann, W.; Bromblet, P.; Vallet, J.M.; Verges-Belmin, V.; Rolland, O.; Guerrot, C.; Gosselin, C.

    2011-01-01

    Sulphate neoformation is a major factor of degradation of stone monuments. Boron, sulphur and oxygen isotope signatures were investigated for five French historical monuments (Bourges, Chartres and Marseille cathedrals, Chenonceau castle, and Versailles garden statues) to investigate the role of intrinsic sulphate sources (gypsum plasters and mortars) in stone degradation, compared to the influence of extrinsic sources such as atmospheric pollution. Gypsum plasters and gypsum-containing mortars fall systematically in the δ 34 S and δ 18 O range of Paris Basin Eocene evaporites indicating the origin of the raw materials (so-called 'Paris plaster'). Black crusts show the typical S and O isotope signatures observed elsewhere in Europe that can be attributed to atmospheric pollution, together with a marine component for Marseille. Boron isotopes for black crusts indicate coal combustion as principal boron source. Mortar isotope compositions discriminate three types, one similar to gypsum plasters, one strongly depleted in 34 S, attributed to pyrite oxidation, and a third one close to atmospheric sulphates. The isotopic composition of sulphates and boron of most degraded building stones of the different monuments is well explained by the identified sulphate sources. In several cases (in particular for Chenonceau and Bourges, to some extent for Chartres), the impact of gypsum plaster as building and restoration material on the degradation of the stones in its vicinity was clearly demonstrated. The study illustrates the usefulness of multi-isotope studies to investigate stone degradation factors, as the combination of several isotope systematics increases the discriminatory power of isotope studies with respect to contaminant sources. - Research Highlights: → Insight in stone weathering mechanisms by multi-isotope fingerprinting (B, S, O). → Intrinsic sulphate sources (gypsum plaster, mortar) contribute to stone degradation. → Origin of building materials

  10. Building materials as intrinsic sources of sulphate: A hidden face of salt weathering of historical monuments investigated through multi-isotope tracing (B, O, S)

    Energy Technology Data Exchange (ETDEWEB)

    Kloppmann, W., E-mail: w.kloppmann@brgm.fr [BRGM, BP 6009, F-45060 Orleans cedex 2 (France); Bromblet, P.; Vallet, J.M. [CICRP, 21, rue Guibal, F-13003 Marseille (France); Verges-Belmin, V. [LRMH, 29, rue de Paris, F-77420 Champs sur Marne (France); Rolland, O. [Independent restorer, 3, rue du Gue, 37270 Montlouis s/Loire (France); Guerrot, C. [BRGM, BP 6009, F-45060 Orleans cedex 2 (France); Gosselin, C. [BRGM, BP 6009, F-45060 Orleans cedex 2 (France); LRMH, 29, rue de Paris, F-77420 Champs sur Marne (France)

    2011-04-01

    Sulphate neoformation is a major factor of degradation of stone monuments. Boron, sulphur and oxygen isotope signatures were investigated for five French historical monuments (Bourges, Chartres and Marseille cathedrals, Chenonceau castle, and Versailles garden statues) to investigate the role of intrinsic sulphate sources (gypsum plasters and mortars) in stone degradation, compared to the influence of extrinsic sources such as atmospheric pollution. Gypsum plasters and gypsum-containing mortars fall systematically in the {delta}{sup 34}S and {delta}{sup 18}O range of Paris Basin Eocene evaporites indicating the origin of the raw materials (so-called 'Paris plaster'). Black crusts show the typical S and O isotope signatures observed elsewhere in Europe that can be attributed to atmospheric pollution, together with a marine component for Marseille. Boron isotopes for black crusts indicate coal combustion as principal boron source. Mortar isotope compositions discriminate three types, one similar to gypsum plasters, one strongly depleted in {sup 34}S, attributed to pyrite oxidation, and a third one close to atmospheric sulphates. The isotopic composition of sulphates and boron of most degraded building stones of the different monuments is well explained by the identified sulphate sources. In several cases (in particular for Chenonceau and Bourges, to some extent for Chartres), the impact of gypsum plaster as building and restoration material on the degradation of the stones in its vicinity was clearly demonstrated. The study illustrates the usefulness of multi-isotope studies to investigate stone degradation factors, as the combination of several isotope systematics increases the discriminatory power of isotope studies with respect to contaminant sources. - Research Highlights: {yields} Insight in stone weathering mechanisms by multi-isotope fingerprinting (B, S, O). {yields} Intrinsic sulphate sources (gypsum plaster, mortar) contribute to stone degradation

  11. Investigation of special capsule technologies for material in-pile irradiation test and development plan in HANARO

    Energy Technology Data Exchange (ETDEWEB)

    Cho, M. S.; Son, J. M.; Kim, D. S.; Park, S. J.; Cho, Y. G.; Seo, C. K.; Kang, Y. H. [KAERI, Taejon (Korea, Republic of)

    2002-10-01

    In-pile test for several materials such as Zr alloy, stainless steel, Cr-Ni steel etc. which are used as structural material of the advanced reactor and KNGR(Korea Next Generation Reactor) like SMART, is necessary to produce the design data for developing new reactor materials. Advanced countries like USA, Europe and Japan etc. are not only performing the simple irradiation test for materials, but developing many kinds of special capsule to perform in-pile test having special purpose. For the special test items of fuel rod, fission products, total heat generation, swelling, deformation, sweep gas, temperature ramping and BOCA etc. are being actively concerned. There are capsules measuring creep, fatigue, crack growth, and controlling fluence etc. for special irradiation test of materials. In addition, the advanced countries are developing several instrument technologies suitable for the special capsules. In HANARO, non-instrumented, instrumented material capsules and non-instrumented fuel capsule have been developed and they have been utilized in the irradiation test for users, and creep capsule loading single specimen was made and is planned to test in the reactor soon. For some forthcoming years, special capsules not only measuring creep deformation with multi-specimens, fatigue, controlling fluence but crack propagation and gas sweep considering the requirements of users will be developed in HANARO.

  12. Nuclear Resonance Fluorescence and Isotopic Mapping of Containers

    Science.gov (United States)

    Johnson, Micah S.; McNabb, Dennis P.

    2009-03-01

    National security programs have expressed interest in developing systems to isotopically map shipping containers, fuel assemblies, and waste barrels for various materials including special nuclear material (SNM). Current radiographic systems offer little more than an ambiguous density silhouette of a container's contents. In this paper we will present a system being developed at LLNL to isotopically map containers using the nuclear resonance fluorescence (NRF) method. Recent experimental measurements on NRF strengths in SNM are discussed.

  13. Uncovering Special Nuclear Materials by Low-energy Nuclear Reaction Imaging.

    Science.gov (United States)

    Rose, P B; Erickson, A S; Mayer, M; Nattress, J; Jovanovic, I

    2016-04-18

    Weapons-grade uranium and plutonium could be used as nuclear explosives with extreme destructive potential. The problem of their detection, especially in standard cargo containers during transit, has been described as "searching for a needle in a haystack" because of the inherently low rate of spontaneous emission of characteristic penetrating radiation and the ease of its shielding. Currently, the only practical approach for uncovering well-shielded special nuclear materials is by use of active interrogation using an external radiation source. However, the similarity of these materials to shielding and the required radiation doses that may exceed regulatory limits prevent this method from being widely used in practice. We introduce a low-dose active detection technique, referred to as low-energy nuclear reaction imaging, which exploits the physics of interactions of multi-MeV monoenergetic photons and neutrons to simultaneously measure the material's areal density and effective atomic number, while confirming the presence of fissionable materials by observing the beta-delayed neutron emission. For the first time, we demonstrate identification and imaging of uranium with this novel technique using a simple yet robust source, setting the stage for its wide adoption in security applications.

  14. Use of stable isotopes method in hydrological investigations with special reference to studies in Lower Maner Basin, Andhra Pradesh

    International Nuclear Information System (INIS)

    Kumar, B.; Athavale, R.N.; Sahay, K.S.N.

    1982-01-01

    The study of variations of stable isotope ratios in water is becoming increasingly important in hydrological investigations and is being widely used for: (i) characterizing water masses and indicating their origin, (ii) finding interconnection of water bodies, (iii) estimating leakages for reservoirs, (iv) water balances studies of lakes, (v) glaciological studies, etc. This paper briefly describes the principle of the method and details of isotope ratio measurement techniques used at the National Geophysical Research Institute, Hyderabad. Integrated geohydrological investigations comprising photogeological, hydrogeochemical, geophysical, nuclear and modelling studies have been carried out in the Lower Maner Basin, A.P., under an Indo-German collaboration project. As a part of this programme,, precipitation, surface and sub-surface water samples from the basin were analysed for their D:H and O 18 :O 16 ratios. The results of these measurements are presented and discussed. (author)

  15. Directory of national competent authorities' approval certificates for package design, special form material and shipment of radioactive material. 1992 ed

    International Nuclear Information System (INIS)

    1992-08-01

    Being in a unique position to facilitate information exchange, the Secretariat of the International Atomic Energy Agency was requested by its Standing Advisory Group on the Safe Transport of Radioactive Material (SAGSTRAM) to collate package approval data and publish periodical reports thereon. A database was implemented on the mainframe computer in the mid-1980s but this was soon adapted for use on a personal computer. A fully menu-driven system programme was designed that allows both contributing Member States and the Secretariat more flexibility in data processing and reporting. Complete documentation is available in the form of a user guide. The cut-off date used for this report is 31 August 1992. This report supersedes IAEA-TECDOC-617 ''Directory of National Competent Authorities' Approval Certificates for Package Design, Special Form Material and Shipment of Radioactive Material, 1991 Edition''. The information contained in this report is given in six tables. In each of these, information is presented in alphabetical order based on the certificate number. The certificate number is identical with the competent authority identification mark. It is composed of the issuing Member State's international vehicle registration identification (VRI) code, followed by a slash, then a unique number specific to a particular design or shipment that is assigned by the competent authority, another slash and finally a code identifying the type of package involved. ''-85'' is appended to those certificates that were approved on the basis of the 1985 Edition of Safety Series No. 6. Tables 1 to 4 present administrative data including issue and expiry dates, package identification, package serial numbers, modes for which the package/shipment is approved and the edition of Safety Series No. 6 on which the approval has been based. The technical information on package mass, authorized contents, and detailed and general description of the package are contained in Table 5. Table 6

  16. Identifying the material of original and restored parts of a 14^{th} century alabaster annunciation group through stable isotopes

    Science.gov (United States)

    Kloppmann, Wolfram; Leroux, Lise; Le Pogam, Pierre-Yves; Bromblet, Philippe

    2017-04-01

    The origin of raw materials for sculpture is often obscure before the 17th century due to the scarcity of written sources. Identifying this origin provides hints to economic exchanges but also, potentially, allows for attributing sculptures to a specific context of creation (regional workshops, artists). Another challenge for art historians is the identification of restorations and their potential chronology. We present an example of a 14th century group of two statues, made of gypsum alabaster, representing an annunciation group, with the Virgin Mary and the angel Gabriel. Their original position was a near Troyes in the eastern Paris Basin, they are now separated being conserved at the Louvre Museum (Virgin Mary) and the Cleveland Museum of Art (Gabriel). Our multi-isotope study revealed the common origin of the material used for both sculptures, their isotope fingerprints being identical within the analytical error. These fingerprints are highly specific and point to an origin in a historical gypsum and alabaster quarry in the northern part of Provence, France, first mentioned at the end of the 13th century. We were also able to identify an unknown restoration of lower part of the Virgin Mary statue with an optically undistinguishable material, using Tuscan alabaster, most likely in the 19th century. This underlines the potential and usefulness of independent geochemical evidence to underpin stylistic hypotheses on grouping of individual artworks, historical economic relationships between regions and on past restoration activities.

  17. Decree of 4 November 1982 on conditions for notification of possession of special fissile materials and source materials and for keeping accounts thereof

    International Nuclear Information System (INIS)

    1982-01-01

    This Decree lays down a detailed procedure for notification of the possession and accounting of special fissile materials and source materials. The Decree was made in pursuance of Decree No. 185 of 13 February 1964 of the President of the Republic concerning radiation protection and licensing procedures. (NEA) [fr

  18. California GAMA Special Study: An isotopic and dissolved gas investigation of nitrate source and transport to a public supply well in California's Central Valley

    Energy Technology Data Exchange (ETDEWEB)

    Singleton, M J; Moran, J E; Esser, B K; Roberts, S K; Hillegonds, D J

    2010-04-14

    study provides two new pieces of evidence that the Ripon Farm Services Plant is the source of elevated nitrate in Ripon City Well 12. (1) Chemical mass balance calculations using nitrate concentration, nitrate isotopic composition, and initial tritium activity all indicate that that the source water for elevated nitrate to Ripon City Well 12 is a very small component of the water produced by City Well 12 and thus must have extremely high nitrate concentration. The high source water nitrate concentration ({approx}1500 mg/L as nitrate) required by these mass balance calculations precludes common sources of nitrate such as irrigated agriculture, dairy wastewater, and septic discharge. Shallow groundwater under the Ripon Farm Services RFS plant does contain extremely high concentrations of nitrate (>1700 mg/L as nitrate). (2) Nitrogen and oxygen isotope compositions of nitrate indicate that the additional anthropogenic nitrate source to Ripon City Well 12 is significantly enriched in {delta}{sup 18}O-NO{sub 3}, an isotopic signature consistent with synthetic nitrate fertilizer, and not with human or animal wastewater discharge (i.e. dairy operations, septic system discharge, or municipal wastewater discharge), or with organic fertilizer. Monitoring wells on and near the RFS plant also have high {delta}{sup 18}O-NO{sub 3}, and the plant has handled and stored synthetic nitrate fertilizer that will have this isotopic signature. The results described here highlight the complexity of attributing nitrate found in long screened, high capacity wells to specific sources. In this case, the presence of a very high concentration source near the well site combined with sampling using multiple isotopic tracer techniques and specialized depth-specific techniques allowed fingerprinting of the source in the mixed-age samples drawn from the production well.

  19. Hydrogen isotopes confinement in the over-dusted layers of fusion reactor candidate materials

    International Nuclear Information System (INIS)

    Klepikov, A.Kh.; Tazhibaeva, I.L.; Shestakov, V.P.; Lisitsyn, V.N.; Tuleushev, Yu.Zh.

    2001-01-01

    In the work the experiments on gas-emission determination from samples of sputtered beryllium, graphite, tungsten, jointly sputtered graphite and tungsten obtained by the magnetron sputtering method at the 'Argamak' facility (National Nuclear Center of the Republic of Kazakhstan), as well as the samples processed on the 'OSPA' plasma accelerator (TRINITI, Russia). The gas-release curves were obtained for indicated samples under different heating velocities within temperature range from 300 up to 1200 K. Gas-release parameters and hydrogen isotopes confinement in these layers were determined. Simulation of hydrogen isotopes gas-emission from samples sputtered layers on the base of obtained experiments with application of simulating programs and TMAP code was carried out

  20. On screening for Special Nuclear Materials (SNMs) with X-ray diffraction

    International Nuclear Information System (INIS)

    Harding, G.

    2010-01-01

    A novel detection technique employing X-ray diffraction (XRD) to screen for Special Nuclear Materials (SNMs), in particular for uranium, has been recently proposed. It is based on the interesting fact that uranium (and incidentally, plutonium) has a non-cubic lattice structure, in contrast to all other non-SNM, high-density elements of the Periodic Table. The principle of this screening technique is briefly elucidated by comparing the XRD lines of uranium with those of lead, a material of high atomic number (Z) commonly found in container traffic. Several physical conditions that must be satisfied to enable XRD for SNM screening are considered. To achieve adequate penetration, both of suspicious high-Z materials and their containers, photon energies of 1 MeV and above must be employed. Implications from partial coherence theory for the XRD measurement geometry at such photon energies are presented. The question of multiple scatter degradation of the coherent scatter signal is addressed. Technological considerations relevant to performing XRD at 1 MeV, particularly regarding the radiation source and detector, are discussed. A novel secondary aperture scheme permitting high energy XRD is presented. It is concluded that the importance of the application and the prospect of its feasibility are sufficient to warrant experimental verification.

  1. Neutron activation determination of phosphorus and sulfur in semiconductor materials by 32P-isotope

    International Nuclear Information System (INIS)

    Nikolaev, A.V.; Gol'dshtejn, M.M.; Gil'bert, Eh.N.; Verevkin, G.V.; Yudelevich, I.G.

    1977-01-01

    A neutron-activation method has been developed for determining phosphorus and sulphur in germanium, gallium, gallium arsenide, and silicon structures using 32 P isotope. The dioctyl-sulphoxide (DOSO) extraction of phosphoric molybdenum acid (PMA) has been used to separate 32 P in a radiochemically pure form. Correction factors have been calculated due to the 2nd order interference on 30 Si nuclei in determining phosphorus in silicon for various irradiation times and at various cadmium proportions

  2. An activated barrier for protection of special nuclear materials in vital areas

    International Nuclear Information System (INIS)

    Timm, R.E.; Miranda, J.E.

    1984-01-01

    The Argonne National Laboratory and Sandia National Laboratory have recently installed an activated barrier, the Access Denial System (ADS) for the upgrade of safeguards of special nuclear materials. The technology of this system was developed in the late 70's by Sandia National Laboratory-Albuquerque. The installation was the first for the Department of Energy. Subsequently, two additional installations have been completed. The Access Denial System, combined with physical restraints, provide the system delay. The principal advantages of the activated barrier are: (1) it provides an order of magnitude improvement in delay over that of a fixed barrier, (2) it can be added to existing vital areas with a minimum of renovations, (3) existing operations are minimally impacted, and (4) health and safety risks are virtually nonexistent. Hardening of the vital areas using the ADS was accomplished in a costeffective manner

  3. Activated barrier for protection of special nuclear materials in vital areas

    International Nuclear Information System (INIS)

    Timm, R.E.; Miranda, J.E.; Reigle, D.L.; Valente, A.D.

    1984-01-01

    The Argonne National Laboratory and Sandia National Laboratory have recently installed an activated barrier, the Access Denial System (ADS) for the upgrade of safeguards of special nuclear materials. The technology of this system was developed in the late 70's by Sandia National Laboratory-Albuquerque. The installation was the first for the Department of Energy. Subsequently, two additional installations have been completed. The Access Denial System, combined with physical restraints, provide the system delay. The principal advantages of the activated barrier are: (1) it provides an order of magnitude improvement in delay over that of a fixed barrier, (2) it can be added to existing vital areas with a minimum of renovations, (3) existing operations are minimally impacted, and (4) health and safety risks are virtually nonexistent. Hardening of the vital areas using the ADS was accomplished in a cost-effective manner. 3 references, 1 figure, 1 table

  4. 10 CFR 73.73 - Requirement for advance notice and protection of export shipments of special nuclear material of...

    Science.gov (United States)

    2010-01-01

    ... shipments of special nuclear material of low strategic significance. 73.73 Section 73.73 Energy NUCLEAR REGULATORY COMMISSION (CONTINUED) PHYSICAL PROTECTION OF PLANTS AND MATERIALS Records and Reports § 73.73... Incident Response, using any appropriate method listed in § 73.4; (2) Assure that the notification will be...

  5. Directory of national competent authorities' approval certificates for package design, special form material and shipment of radioactive material. 2002 ed

    International Nuclear Information System (INIS)

    2002-08-01

    The current edition of the transport Regulations was published in 1996 and is more commonly referred to as 'ST-1'. Earlier Editions were known as Safety Series No. 6. The latest English reprint (2000) is now identified as TS-R-1 (ST-1, Revised). The transport Regulations elaborate requirements for the design, fabrication and maintenance of packaging as well as those for preparation, consigning, handling, carriage, storage in transit and receipt of the packages at final destination. Approval issued in the form of certificates is required for the design or shipment of packages. This report supersedes IAEA-TECDOC-1237 Directory of National Competent Authorities' Approval Certificates for Package Design, Special Form Material and Shipment of Radioactive Material, 2001 Edition. It is distributed worldwide to the IAEA Member States' competent authorities for transport, and other entities who have requested copies. Electronic copies of the main data file are provided to registered users of the PACKTRAM database. The information contained in this report is given in six tables. In each of these, information is presented in alphabetical order based on the certificate number. Tables 1 to 4 present administrative data including issue and expiry dates, package identification, package serial numbers, modes for which the package/shipment is approved and the edition of the IAEA Transport Safety Regulations on which the approval has been based. The technical information on package mass, authorized contents, and detailed and general description of the package are contained in Table 5. Table 6 shows the certificates reported to the Secretariat by each participating Member State

  6. Directory of national competent authorities' approval certificates for package design, special form material and shipment of radioactive material. 2001 edition

    International Nuclear Information System (INIS)

    2001-08-01

    The current edition of the transport Regulations was published in 1996 and is more commonly referred to as 'ST-1'. Earlier Editions were known as Safety Series No. 6. The latest English reprint (2000) is now identified as TS-R-1 (ST-1, Revised). The transport Regulations elaborate requirements for the design, fabrication and maintenance of packaging as well as those for preparation, consigning, handling, carriage, storage in transit and receipt of the packages at final destination. Approval issued in the form of certificates is required for the design or shipment of packages. This report supersedes IAEA-TECDOC-1171 D irectory of National Competent Authorities' Approval Certificates for Package Design, Special Form Material and Shipment of Radioactive Material, 2000 Edition . It is distributed worldwide to the IAEA Member States' competent authorities for transport, and other entities who have requested copies. Electronic copies of the main data file are provided to registered users of the PACKTRAM database. The information contained in this report is given in six tables. In each of these, information is presented in alphabetical order based on the certificate number. Tables 1 to 4 present administrative data including issue and expiry dates, package identification, package serial numbers, modes for which the package/shipment is approved and the edition of the IAEA Transport Safety Regulations on which the approval has been based. The technical information on package mass, authorized contents, and detailed and general description of the package are contained in Table 5. Table 6 shows the certificates reported to the Secretariat by each participating Member State

  7. Proposed real-time data processing system to control source and special nuclear material (SS) at Mound Laboratory

    International Nuclear Information System (INIS)

    DeVer, E.A.; Baston, M.; Bishop, T.C.

    1976-01-01

    The SS Acountability System was designed to provide accountability of all SS materials by unit identification and grams. The existing system is a gram-accountable system. The new system was designed to incorporate unit identification into an ADP (Automated Data Processing) System. It also records all transactions performed against a particular unit of accountable material. The high volume of data is input via CRT terminals. Input data will consist of the following: source of the material (its unit identification), amount of material being moved, isotopic content, type of material, Health Physics number of the person moving the material, account number from which the material is being moved, unit identification of the material being moved (if all material is not moved), Health Physics number of the person receiving the material, account number to which material is being moved, and acceptance of the material by the receiver. A running inventory of all material is kept. At the end of the month the physical inventory will be compared to the data base and all discrepancies reported. Since a complete history of transactions has been kept, the source and cause for any discrepancies should be easily located. Discrepancies are held to a minimum since errors are detected before entrance into the data base. The system will also furnish all reports necessary to control SS Accountability. These reports may be requested at any time via an accountability master terminal

  8. Status of the isotope enrichment program at Oak Ridge National Laboratory

    Science.gov (United States)

    Tracy, J. G.

    1991-05-01

    The objectives of the isotope enrichment program at the Oak Ridge National Laboratory are to prepare and distribute electromagnetically separated stable isotopes to the research, medical and industrial communities on a worldwide basis. Topics discussed in this presentation include (1) a review of facility modifications, (2) current facility capabilities, (3) enrichment processes, and (4) final product distribution. An update on alternative separations methods to augment the electromagnetic separations process is covered, as well as special services that are available for providing custom materials to meet special applications. Recent changes in U.S. Department of Energy policy that impact the nation's isotope and isotope-related programs are summarized, with special emphasis on the effects on isotope enrichment, radioisotope production, target fabrication, pricing, and marketing and distribution of stable isotopes.

  9. Book of abstracts of the 3rd International conference and the 3rd International School for young scientists Interaction of hydrogen isotopes with structural materials. IHISM-07

    International Nuclear Information System (INIS)

    2007-01-01

    The book involves abstracts of presentations at the 3rd International Conference and the 3rd International School for Young Scientists Interaction of Hydrogen Isotopes with Structural Materials (IHISM-07). The activities of Russian and foreign scientific centers associated with the use of hydrogen isotopes in power engineering, national economy and basic research are considered. The presentations cover the following areas: kinetics and interaction between hydrogen isotopes and solids including effects of radiogenic helium accumulation, hydrides and hydride transformations; structural transformations and mechanical properties; equipment and research techniques [ru

  10. Book of abstracts of the Fifth International School for young scientists and specialists Interaction of hydrogen isotopes with structural materials. IHISM-09 JUNIOR

    International Nuclear Information System (INIS)

    2009-01-01

    The book includes abstracts of presentations at the Fifth International School for young scientists and specialists Interaction of hydrogen isotopes with structural materials (IHISM-09 JUNIOR). Abstracts of lecture faculty and reports of young scientists and specialists covering the use of hydrogen isotopes in energetics, national economy and fundamental researches are given. Papers presented on the following topics: mechanical properties and structural transformations; kinetics and thermodynamics of interaction between hydrogen isotopes and solids including effects of radiogenic helium accumulation, hydrides and hydride transformations; equipment and research techniques

  11. Book of abstracts of the fourth international school for young scientists and specialists Interaction of hydrogen isotopes with structural materials (IHISM-08)

    International Nuclear Information System (INIS)

    2008-01-01

    The book includes abstracts of presentations at the 4th International School for young scientists and specialists Interaction of hydrogen isotopes with structural materials (IHISM-08). The lectures of lecturer and presentations of young scientists associated with the use of hydrogen isotopes in power engineering, national economy and basic research are considered. The presentations cover the following areas: kinetics and thermodynamics of interaction between hydrogen isotopes and solids including effects of radiogenic helium accumulation; hydrides and hydride transformations; structural transformations and mechanical properties; equipment and research techniques [ru

  12. The RaDIATE High-Energy Proton Materials Irradiation Experiment at the Brookhaven Linac Isotope Producer Facility

    Energy Technology Data Exchange (ETDEWEB)

    Ammigan, Kavin; et al.

    2017-05-01

    The RaDIATE collaboration (Radiation Damage In Accelerator Target Environments) was founded in 2012 to bring together the high-energy accelerator target and nuclear materials communities to address the challenging issue of radiation damage effects in beam-intercepting materials. Success of current and future high intensity accelerator target facilities requires a fundamental understanding of these effects including measurement of materials property data. Toward this goal, the RaDIATE collaboration organized and carried out a materials irradiation run at the Brookhaven Linac Isotope Producer facility (BLIP). The experiment utilized a 181 MeV proton beam to irradiate several capsules, each containing many candidate material samples for various accelerator components. Materials included various grades/alloys of beryllium, graphite, silicon, iridium, titanium, TZM, CuCrZr, and aluminum. Attainable peak damage from an 8-week irradiation run ranges from 0.03 DPA (Be) to 7 DPA (Ir). Helium production is expected to range from 5 appm/DPA (Ir) to 3,000 appm/DPA (Be). The motivation, experimental parameters, as well as the post-irradiation examination plans of this experiment are described.

  13. USGS42 and USGS43: Human-hair stable hydrogen and oxygen isotopic reference materials and analytical methods for forensic science and implications for published measurement results

    Science.gov (United States)

    Coplen, T.B.; Qi, H.

    2012-01-01

    Because there are no internationally distributed stable hydrogen and oxygen isotopic reference materials of human hair, the U.S. Geological Survey (USGS) has prepared two such materials, USGS42 and USGS43. These reference materials span values commonly encountered in human hair stable isotope analysis and are isotopically homogeneous at sample sizes larger than 0.2 mg. USGS42 and USGS43 human-hair isotopic reference materials are intended for calibration of δ(2)H and δ(18)O measurements of unknown human hair by quantifying (1) drift with time, (2) mass-dependent isotopic fractionation, and (3) isotope-ratio-scale contraction. While they are intended for measurements of the stable isotopes of hydrogen and oxygen, they also are suitable for measurements of the stable isotopes of carbon, nitrogen, and sulfur in human and mammalian hair. Preliminary isotopic compositions of the non-exchangeable fractions of these materials are USGS42(Tibetan hair)δ(2)H(VSMOW-SLAP) = -78.5 ± 2.3‰ (n = 62) and δ(18)O(VSMOW-SLAP) = +8.56 ± 0.10‰ (n = 18) USGS42(Indian hair)δ(2)H(VSMOW-SLAP) = -50.3 ± 2.8‰ (n = 64) and δ(18)O(VSMOW-SLAP) = +14.11 ± 0.10‰ (n = 18). Using recommended analytical protocols presented herein for δ(2)H(VSMOW-SLAP) and δ(18)O(VSMOW-SLAP) measurements, the least squares fit regression of 11 human hair reference materials is δ(2)H(VSMOW-SLAP) = 6.085δ(2)O(VSMOW-SLAP) - 136.0‰ with an R-square value of 0.95. The δ(2)H difference between the calibrated results of human hair in this investigation and a commonly accepted human-hair relationship is a remarkable 34‰. It is critical that readers pay attention to the δ(2)H(VSMOW-SLAP) and δ(18)O(VSMOW-SLAP) of isotopic reference materials in publications, and they need to adjust the δ(2)H(VSMOW-SLAP) and δ(18)O(VSMOW-SLAP) measurement results of human hair in previous publications, as needed, to ensure all results on are on the same scales.

  14. Development of special radiation shielding concretes using natural local materials and evaluation of their shielding characteristics

    International Nuclear Information System (INIS)

    Kharita, M. H.; Takeyeddin, M.; Al-Nassri, M.; Yousef, S.

    2008-01-01

    Concrete is one of the most important materials used for radiation shielding in facilities containing radioactive sources and radiation generating machines. The concrete shielding properties may vary depending on the composite of the concrete. Aggregates is the largest constituent (about 70-80% of the total weight of normal concrete). The aim of this work is to develop special concrete with good shielding properties for gamma and neutrons, using natural local materials. For this reason two types of typical concrete widely used in Syria (in Damascus and Aleppo) and four other types of concrete, using aggregates from different regions, have been prepared. The shielding properties of these six types were studied for gamma ray (from Cs-137 and Co-60 sources)and for neutrons (from am-Be source). A reduction of about 10% in the HVL was obtained for the concrete from Damascus in comparison with that from Aleppo, for both neutrons and gammas. One of the other four types of concrete (from Rajo site, mostly Hematite), was found to further reduce the HVL by about 10% for both neutrons and gamma rays.(author)

  15. Special quasirandom structures for gadolinia-doped ceria and related materials

    KAUST Repository

    Wang, Hao

    2012-01-01

    Gadolinia doped ceria in its doped or strained form is considered to be an electrolyte for solid oxide fuel cell applications. The simulation of the defect processes in these materials is complicated by the random distribution of the constituent atoms. We propose the use of the special quasirandom structure (SQS) approach as a computationally efficient way to describe the random nature of the local cation environment and the distribution of the oxygen vacancies. We have generated two 96-atom SQS cells describing 9% and 12% gadolinia doped ceria. These SQS cells are transferable and can be used to model related materials such as yttria stabilized zirconia. To demonstrate the applicability of the method we use density functional theory to investigate the influence of the local environment around a Y dopant in Y-codoped gadolinia doped ceria. It is energetically favourable if Y is not close to Gd or an oxygen vacancy. Moreover, Y-O bonds are found to be weaker than Gd-O bonds so that the conductivity of O ions is improved. © 2012 the Owner Societies.

  16. Isotope puzzle in sputtering

    International Nuclear Information System (INIS)

    Zheng Liping

    1998-01-01

    Mechanisms affecting multicomponent material sputtering are complex. Isotope sputtering is the simplest in the multicomponent materials sputtering. Although only mass effect plays a dominant role in the isotope sputtering, there is still an isotope puzzle in sputtering by ion bombardment. The major arguments are as follows: (1) At the zero fluence, is the isotope enrichment ejection-angle-independent or ejection-angle-dependent? (2) Is the isotope angular effect the primary or the secondary sputter effect? (3) How to understand the action of momentum asymmetry in collision cascade on the isotope sputtering?

  17. Special nuclear materials cutoff exercise: Issues and lessons learned. Volume 1: Summary of exercise

    International Nuclear Information System (INIS)

    Libby, R.A.; Davis, C.; Segal, J.E.; Stanbro, W.D.

    1995-08-01

    In a September 1993 address to the United Nations General Assembly, President Clinton announced a new nonproliferation and export control policy that established a framework for US efforts to prevent the proliferation of weapons of mass destruction. The new policy proposed that the US undertake a comprehensive approach to the growing accumulation of fissile material. One of the key elements was for the US to support a special nuclear materials (SNM) multilateral convention prohibiting the production of highly enriched uranium (HEU) or plutonium for nuclear explosives purposes or outside of international safeguards. This policy is often referred to as the President's Cutoff Initiative or the Fissile Material Cutoff Treaty (FMCT). Because both the US Department of Energy (DOE) and foreign reprocessing facilities similar to PUREX will likely to be inspected under a FMCT, the DOE Office of Arms Control and Nonproliferation, Negotiations and Analysis Division (DOE/NN-41) tasked Pacific Northwest Laboratory (PNL) to perform an information gathering exercise, the PUREX Exercise, using the Plutonium-Uranium Extraction (PUREX) Plant located on the Hanford Site in Washington State. PUREX is a former production reactor fuel reprocessing plant currently undergoing a transition to a ''decontamination and decommissioning (D ampersand D) ready'' mode. The PUREX Exercise was conducted March 29--30, 1994, to examine aspects of the imposition of several possible cutoff regimes and to study verification of non-production of SNM for nuclear weapons purposes or outside of safeguards. A follow-up activity to further examine various additional verification regimes was held at Los Alamos National Laboratory (LANL) on May 10, 1994

  18. Mobile Pit verification system design based on passive special nuclear material verification in weapons storage facilities

    Energy Technology Data Exchange (ETDEWEB)

    Paul, J. N.; Chin, M. R.; Sjoden, G. E. [Nuclear and Radiological Engineering Program, George W. Woodruff School of Mechanical Engineering, Georgia Institute of Technology, 770 State St, Atlanta, GA 30332-0745 (United States)

    2013-07-01

    A mobile 'drive by' passive radiation detection system to be applied in special nuclear materials (SNM) storage facilities for validation and compliance purposes has been designed through the use of computational modeling and new radiation detection methods. This project was the result of work over a 1 year period to create optimal design specifications to include creation of 3D models using both Monte Carlo and deterministic codes to characterize the gamma and neutron leakage out each surface of SNM-bearing canisters. Results were compared and agreement was demonstrated between both models. Container leakages were then used to determine the expected reaction rates using transport theory in the detectors when placed at varying distances from the can. A 'typical' background signature was incorporated to determine the minimum signatures versus the probability of detection to evaluate moving source protocols with collimation. This established the criteria for verification of source presence and time gating at a given vehicle speed. New methods for the passive detection of SNM were employed and shown to give reliable identification of age and material for highly enriched uranium (HEU) and weapons grade plutonium (WGPu). The finalized 'Mobile Pit Verification System' (MPVS) design demonstrated that a 'drive-by' detection system, collimated and operating at nominally 2 mph, is capable of rapidly verifying each and every weapon pit stored in regularly spaced, shelved storage containers, using completely passive gamma and neutron signatures for HEU and WGPu. This system is ready for real evaluation to demonstrate passive total material accountability in storage facilities. (authors)

  19. Research within the coordinated programme on isotope-aided micronutrient studies in rice production with special reference to zinc deficiencies

    International Nuclear Information System (INIS)

    Rosales, C.M.

    1980-07-01

    An extensive survey identified 500,000 ha of soil in the Philippines as being potentially Zn-deficient for rice production. Isotope-aided laboratory, greenhouse, and field experiments were conducted to identify the most efficient methods of supplying fertilizer Zn to flooded rice. The application of 5 kg Zn/ha as ZnSO 4 effectively corrected a Zn deficiency and increased rice yield and Zn uptake for three successive growing seasons. No further increases were noted with higher rates of Zn application. Fertilizer ZnSO 4 was equally effective when mixed with the soil, combined with urea fertilizers, or surface-applied at or two weeks after transplanting the rice. Mine tailings were also shown to be an effective source of Zn. Mixing organic compost with the ZnSO 4 decreased the percent Zn derived from the fertilizer and the rice yield. 65 Zn-labelled ZnSO 4 was used

  20. Terminating Safeguards on Excess Special Nuclear Material: Defense TRU Waste Clean-up and Nonproliferation - 12426

    Energy Technology Data Exchange (ETDEWEB)

    Hayes, Timothy [Los Alamos National Laboratory, Carlsbad Operations Group (United States); Nelson, Roger [Department Of Energy, Carlsbad Operations Office (United States)

    2012-07-01

    The Department of Energy (DOE) and the National Nuclear Security Administration (NNSA) manages defense nuclear material that has been determined to be excess to programmatic needs and declared waste. When these wastes contain plutonium, they almost always meet the definition of defense transuranic (TRU) waste and are thus eligible for disposal at the Waste Isolation Pilot Plant (WIPP). The DOE operates the WIPP in a manner that physical protections for attractiveness level D or higher special nuclear material (SNM) are not the normal operating condition. Therefore, there is currently a requirement to terminate safeguards before disposal of these wastes at the WIPP. Presented are the processes used to terminate safeguards, lessons learned during the termination process, and how these approaches might be useful for future defense TRU waste needing safeguards termination prior to shipment and disposal at the WIPP. Also described is a new criticality control container, which will increase the amount of fissile material that can be loaded per container, and how it will save significant taxpayer dollars. Retrieval, compliant packaging and shipment of retrievably stored legacy TRU waste has dominated disposal operations at WIPP since it began operations 12 years ago. But because most of this legacy waste has successfully been emplaced in WIPP, the TRU waste clean-up focus is turning to newly-generated TRU materials. A major component will be transuranic SNM, currently managed in safeguards-protected vaults around the weapons complex. As DOE and NNSA continue to consolidate and shrink the weapons complex footprint, it is expected that significant quantities of transuranic SNM will be declared surplus to the nation's needs. Safeguards termination of SNM varies due to the wide range of attractiveness level of the potential material that may be directly discarded as waste. To enhance the efficiency of shipping waste with high TRU fissile content to WIPP, DOE designed an

  1. 76 FR 454 - Hazardous Materials Transportation: Revisions of Special Permits Procedures

    Science.gov (United States)

    2011-01-05

    ... special permits. The HMR generally are performance-oriented regulations that provide the regulated... forbidden for transportation by aircraft except under a special permit (see Columns 9A and 9B in the table...

  2. Indications of a major Neolithic trade route? An archaeometric geochemical and Sr, Pb isotope study on amphibolitic raw material from present day Europe

    International Nuclear Information System (INIS)

    Christensen, A.-M.; Holm, P.M.; Schuessler, U.; Petrasch, J.

    2006-01-01

    In order to interpret pre-historic cultural interactions, the provenance of amphibolitic raw material used for flat-axes and adzes in lower to middle Neolithic cultures throughout present day Germany were investigated by elemental and Sr, Pb isotopic methods. Within all settlements studied, a homogeneous actinolite-hornblende schist rock type (AHS) was found to be massively dominating, with a distinct petrography of needle-shaped actinolite interwoven with single larger grains of hornblende along with calcic plagioclase and large amounts of ilmenite. Geochemically, the AHS group is very homogeneous and has a signature of an enriched basaltic precursor with high concentrations of particularly the LIL-elements. The geochemical signature is relatively rare and can not be matched in nearby geological outcrops, wherefore the conclusion of 'imported material' is quickly reached. Strontium and Pb isotopic analyses of the AHS were compared to the isotopic composition of amphibolitic rocks with similar petrography and trace elemental signatures within possible archaeological trade regions. The isotopic data of the archaeological material point roughly to a Proterozoic age of the stone used; an age which can be reasonable matched to a single outcrop situated at Jistebsko within the Czech Republic. This area further shows archaeological traces of prehistoric mining. Based on petrographic, geochemical and isotopic evidence, this area is here presented as the provenance area of the stone raw material, which later spread throughout prehistoric Europe - establishing contact and trade routes between Neolithic cultures

  3. Discrimination of source reactor type by multivariate statistical analysis of uranium and plutonium isotopic concentrations in unknown irradiated nuclear fuel material.

    Science.gov (United States)

    Robel, Martin; Kristo, Michael J

    2008-11-01

    The problem of identifying the provenance of unknown nuclear material in the environment by multivariate statistical analysis of its uranium and/or plutonium isotopic composition is considered. Such material can be introduced into the environment as a result of nuclear accidents, inadvertent processing losses, illegal dumping of waste, or deliberate trafficking in nuclear materials. Various combinations of reactor type and fuel composition were analyzed using Principal Components Analysis (PCA) and Partial Least Squares Discriminant Analysis (PLSDA) of the concentrations of nine U and Pu isotopes in fuel as a function of burnup. Real-world variation in the concentrations of (234)U and (236)U in the fresh (unirradiated) fuel was incorporated. The U and Pu were also analyzed separately, with results that suggest that, even after reprocessing or environmental fractionation, Pu isotopes can be used to determine both the source reactor type and the initial fuel composition with good discrimination.

  4. Guide for the preparation of applications for special nuclear material licenses of less than critical mass quantities - July 1976

    International Nuclear Information System (INIS)

    Anon.

    1977-01-01

    This guide describes the type of information needed to evaluate an application for a specific license for receipt, possession, use, and transfer of special nuclear material. It is intended for applicants requesting authorization to possess and use up to 2000 grams of plutonium, total, in the form of sealed plutonium-beryllium neutron sources, and any special nuclear material in quantities and forms not sufficient to form a critical mass. The latter quantities are considered to be 350 grams of contained uranium-235, 200 grams of uranium-233, 200 grams of plutonium (in any form other than plutonium-beryllium neutron sources) or any combination of them

  5. USGS48 Puerto Rico precipitation - A new isotopic reference material for δ2H and δ18O measurements of water

    Science.gov (United States)

    Qi, Haiping; Coplen, Tyler B.; Tarbox, Lauren V.; Lorenz, Jennifer M.; Scholl, Martha A.

    2014-01-01

    A new secondary isotopic reference material has been prepared from Puerto Rico precipitation, which was filtered, homogenised, loaded into glass ampoules, sealed with a torch, autoclaved to eliminate biological activity, and calibrated by dual-inlet isotope-ratio mass spectrometry. This isotopic reference material, designated as USGS48, is intended to be one of two isotopic reference waters for daily normalisation of stable hydrogen (δ2H) and stable oxygen (δ18O) isotopic analysis of water with a mass spectrometer or a laser absorption spectrometer. The δ2H and δ18O values of this reference water are−2.0±0.4 and−2.224±0.012 ‰, respectively, relative to Vienna Standard Mean Ocean Water on scales normalised such that the δ2H and δ18O values of Standard Light Antarctic Precipitation reference water are−428 and−55.5 ‰, respectively. Each uncertainty is an estimated expanded uncertainty (U=2uc) about the reference value that provides an interval that has about a 95 % probability of encompassing the true value. This isotopic reference water is available by the case of 144 glass ampoules containing 5 mL of water in each ampoule.

  6. Analysis of hydrogen isotopes in materials by secondary ion mass spectrometry and nuclear microanalysis

    International Nuclear Information System (INIS)

    Ross, G.G.

    1994-01-01

    Only two techniques are really appropriate for the depth profiling of hydrogen isotopes: nuclear microanalysis (NMA) and secondary ion mass spectrometry (SIMS). The intent of this paper is to give an up to date review of both techniques and to show how they can be used in conjunction. Both techniques (SIMS and NMA) will be described briefly. NMA will divided into two different categories: nuclear reaction analysis (NRA) and elastic recoil detection (ERD). Both techniques (SIMS and NMA) will be discussed in terms of sensitivity, resolution, probing depth, quantitative measurement, generality and selectivity, beam induced effects and surface roughness effects. The principal advantages and disadvantages of each of these techniques will be specified, supporting the contention that SIMS and NMA are complementary and should be used in conjunction. Finally, some examples of, and perspectives for, the complementary use of both techniques will be presented. (Author)

  7. Laser separation of uranium isotopes

    International Nuclear Information System (INIS)

    Porter, J.T.

    1981-01-01

    Method and apparatus for separating uranium isotopes are claimed. The method comprises the steps of irradiating a uranyl source material at a wavelength selective to a desired isotope and at an effective temperature for isotope spectral line splitting below about 77 deg.K., further irradiating the source material within the fluorescent lifetime of the source material to selectively photochemically reduce the excited isotopic species, and chemically separating the reduced isotope species from the remaining uranyl salt compound

  8. 235Uranium isotope abundance certified reference material for gamma spectrometry EC nuclear reference material 171 certification report

    International Nuclear Information System (INIS)

    De Bievre, P.; Eschbach, H.L.; Lesser, R.; Meyer, H.; Audenhove, Van J.

    1986-01-01

    This certification report contains the information necessary for the final certification of EC nuclear reference material 171. It is also intended to inform the user of the reference material concerned on technical/scientific details which are not given in the certificate. The report describes the reference material which consists of sets of U 3 O 8 samples with five different 235 U/U abundances, filled in cylindrical aluminium cans. The can bottom serves as window for emitted gamma radiation. The report describes how the 235 U/U abundances were characterized, how the other properties relevant for gamma measurements were determined and gives all connected results as well as those from the verification measurements. Appendix A represents the draft certificate. 32 refs

  9. Multi-MW accelerator target material properties under proton irradiation at Brookhaven National Laboratory linear isotope producer

    Science.gov (United States)

    Simos, N.; Ludewig, H.; Kirk, H.; Dooryhee, E.; Ghose, S.; Zhong, Z.; Zhong, H.; Makimura, S.; Yoshimura, K.; Bennett, J. R. J.; Kotsinas, G.; Kotsina, Z.; McDonald, K. T.

    2018-05-01

    The effects of proton beams irradiating materials considered for targets in high-power accelerator experiments have been studied using the Brookhaven National Laboratory's (BNL) 200 MeV proton linac. A wide array of materials and alloys covering a wide range of the atomic number (Z) are being scoped by the high-power accelerator community prompting the BNL studies to focus on materials representing each distinct range, i.e. low-Z, mid-Z and high-Z. The low range includes materials such as beryllium and graphite, the midrange alloys such as Ti-6Al-4V, gum metal and super-Invar and finally the high-Z range pure tungsten and tantalum. Of interest in assessing proton irradiation effects are (a) changes in physiomechanical properties which are important in maintaining high-power target functionality, (b) identification of possible limits of proton flux or fluence above which certain materials cease to maintain integrity, (c) the role of material operating temperature in inducing or maintaining radiation damage reversal, and (d) phase stability and microstructural changes. The paper presents excerpt results deduced from macroscopic and microscopic post-irradiation evaluation (PIE) following several irradiation campaigns conducted at the BNL 200 MeV linac and specifically at the isotope producer beam-line/target station. The microscopic PIE relied on high energy x-ray diffraction at the BNL NSLS X17B1 and NSLS II XPD beam lines. The studies reveal the dramatic effects of irradiation on phase stability in several of the materials, changes in physical properties and ductility loss as well as thermally induced radiation damage reversal in graphite and alloys such as super-Invar.

  10. Dual Neutral Particle Beam Interrogation of Intermodal Shipping Containers for Special Nuclear Material

    Science.gov (United States)

    Keith, Rodney Lyman

    Intermodal shipping containers entering the United States provide an avenue to smuggle unsecured or stolen special nuclear material (SNM). The only direct method fielded to indicate the presence of SNM is by passive photon/neutron radiation detection. Active interrogation using neutral particle beams to induce fission in SNM is a method under consideration. One by-product of fission is the creation of fragments that undergo radioactive decay over a time period on the order of tens of seconds after the initial event. The "delayed" gamma-rays emitted from these fragments over this period are considered a hallmark for the presence of SNM. A fundamental model is developed using homogenized cargos with a SNM target embedded at the center and computationally interrogated using simultaneous neutron and photon beams. Findings from analysis of the delayed gamma emissions from these experiments are intended to mitigate the effects of poor quality information about the composition and disposition of suspect cargo before examination in an active interrogation portal.

  11. Development of a re-brazeable containment system for special nuclear material storage and transport

    International Nuclear Information System (INIS)

    Pierce, J.D.; Stephens, J.J.; Walker, C.A.; Hosking, F.M.; Curlee, R.M.

    1995-01-01

    This report describes a novel means of closing and sealing small type B radioactive material transport packages for surface or air transport as governed by 10CFR71 or NUREG-0360 has been developed at Sandia National Laboratories (SNL). This method is a controlled brazing process that may be used to attach and seal a closure lid to a containment vessel and then remove it at a later time. The process may be performed multiple times without the need for special preparations of the braze joint. A number of advantages for utilization of this technique have been determined. A brazed seal has integrity at high temperatures for better protection in accident or abnormal environments. A properly designed joint has essentially the same strength as the parent metal. A closure that is brazed, therefore, will no longer be the anticipated point of failure for a broad range of accident environments. This technique will allow the containment vessel design to be optimized with a lighter, more uniform wall thickness throughout. Finally, with a well defined process for sealing, mechanical inspection, leak testing, and then reopening at a later time, automation of the process is relatively straightforward and the overall system should be as easy to use as one that utilizes elastomeric seals for containment

  12. Investigation of Active Interrogation Techniques to Detect Special Nuclear Material in Maritime Environments

    International Nuclear Information System (INIS)

    Miller, Thomas Martin; Patton, Bruce W.

    2010-01-01

    The detection and interdiction of special nuclear material (SNM) is still a high-priority focus area for many organizations around the world. One method that is commonly considered a leading candidate in the detection of SNM is active interrogation (AI). AI is different from its close relative, passive interrogation, in that an active source is used to enhance or create a detectable signal (usually fission) from SNM, particularly in shielded scenarios or scenarios where the SNM has a low activity. The use of AI thus makes the detection of SNM easier or, in some scenarios, even enables previously impossible detection. In this work the signal from prompt neutrons and photons as well as delayed neutrons and photons will be combined, as is typically done in AI. In previous work AI has been evaluated experimentally and computationally. However, for the purposes of this work, past scenarios are considered lightly shielded and tightly coupled spatially. At most, the previous work interrogated the contents of one standard cargo container (2.44 x 2.60 x 6.10 m) and the source and detector were both within a few meters of the object being interrogated. A few examples of this type of previous work can be found in references 1 and 2. Obviously, more heavily shielded AI scenarios will require larger source intensities, larger detector surface areas (larger detectors or more detectors), greater detector efficiencies, longer count times, or some combination of these.

  13. Development of "material-specific" hemispheric specialization from beginning to end.

    Science.gov (United States)

    Gingras, Benjamin; Braun, Claude M J

    2018-07-01

    Disparity of verbal and performance intelligence (VIQ, PIQ) on the Wechsler scales of intelligence is a conceptually cluttered and empirically weak measure of hemispheric specialization (HS). However, in the context of life span research, it is the only measure that can be exploited meta-analytically with the lesion method from prenatal life to late senescence. We assembled 1917 cases with a unilateral cortical focal brain lesion occurring at all ages and a post-lesion VIQ and PIQ. Lesion locus, volume and side were documented for each case, as well as age at lesion onset, age at first symptoms and age at the IQ test, presence/absence of epilepsy, lesion aetiology, gender, date of publication or of transfer of medical file. With and without covariate adjustment, HS was significant across the life span though its pattern changed. HS increased linearly and highly significantly until late senescence. Only in early adulthood did VIQ appear to vacate the right temporal lobe and occupy the left and PIQ vacate the left parietal lobe and occupy the right until late senescence. Biomaturational factors are more important in the ontogeny of material-specific HS over the whole life span than previously established.

  14. Technique for detecting a small magnitude loss of special nuclear material

    International Nuclear Information System (INIS)

    Pike, D.H.; Chernick, M.R.; Downing, D.J.

    The detection of losses of special nuclear materials has been the subject of much research in recent years. The standard industry practice using ID/LEID will detect large magnitude losses. Time series techniques such as the Kalman Filter or CUSUM methods will detect small magnitude losses if they occur regularly over a sustained period of time. To date no technique has been proposed which adequately addresses the problem of detecting a small magnitude loss occurring in a single period. This paper proposes a method for detecting a small magnitude loss. The approach makes use of the influence function of Hempel. The influence function measures the effect of a single inventory difference on a group of statistics. An inventory difference for a period in which a loss occurs can be expected to produce an abnormality in the calculated statistics. This abnormality is measurable by the influence function. It is shown that a one period loss smaller in magnitude than the LEID can be detected using this approach

  15. High accuracy determination of trace elements in NIST standard reference materials by isotope dilution ICP-MS

    International Nuclear Information System (INIS)

    Paulsen, P.J.; Beary, E.S.

    1996-01-01

    At NIST (National Institute of Standards and Technology), ICP-MS ID (inductively coupled mass spectrometry isotope dilution) has been used to certify a wide range of elements in a variety of materials with high accuracy. Both the chemical preparation and instrumental procedures are simpler than with other ID mass spectrometric techniques. The ICP-MS has picogram/ml detection limits for most elements using fixed operating parameters. Chemical separations are required only to remove an interference (from molecular ions as well as isobaric atoms), or to pre-concentrate the analyte. For example, chemical separations were required for the analysis of SRM 2711, Montana II Soil, but not for boron in peach leaves, SRM 1547.(3 refs., 3 tabs., 2 figs

  16. Plans of reorganization of USA nuclear military complex and provision of military program by special nuclear materials

    International Nuclear Information System (INIS)

    Semenovskaya, I.V.

    1996-01-01

    Consideration is given to plans and implementation of the program of reorganization of USA nuclear military complex, related with conducted reduction of nuclear arsenal after concluding the Strategic Nuclear Armament Reduction Treaty. Particular attention is paid to problems of satisfying short-term and long-term requirements in special nuclear materials and in tritium in particular

  17. Design of special purpose products made of nanomodified collagen-containing materials with radio-frequency discharge

    Science.gov (United States)

    Makhotkina, L. Yu; Sharifullin, S. N.

    2016-06-01

    Research results shows that RF-plasma treatment increases the adhesion of the coating film to the leather uppers and resistance to abrasion and repeated bending of uppers, which define the ability of material to preserve its consumer properties and characterize longer safety of special purpose footwear form during its wearing.

  18. Laser ionization time of flight mass spectrometer for isotope mass detection and elemental analysis of materials

    Science.gov (United States)

    Ahmed, Nasar; Ahmed, Rizwan; Umar, Z. A.; Aslam Baig, M.

    2017-08-01

    In this paper we present the construction and modification of a linear time-of-flight mass spectrometer to improve its mass resolution. This system consists of a laser ablation/ionization section based on a Q-switched Nd:YAG laser (532 nm, 500 mJ, 5 ns pulse duration) integrated with a one meter linear time-of-flight mass spectrometer coupled with an electric sector and a magnetic lens and outfitted with a channeltron electron multiplier for ion detection. The resolution of the system has been improved by optimizing the accelerating potential and inserting a magnetic lens after the extraction region. The isotopes of lithium, lead and cadmium samples have been resolved and detected in accordance with their natural abundance. The capability of the system has been further exploited to determine the elemental composition of a brass alloy, having a certified composition of zinc and copper. Our results are in excellent agreement with its certified composition. This setup is found to be extremely efficient and convenient for fast analyses of any solid sample.

  19. Isotopic evidence for primordial molecular cloud material in metal-rich carbonaceous chondrites

    DEFF Research Database (Denmark)

    van Kooten, Elishevah M. M. E.; Wielandt, Daniel Kim Peel; Schiller, Martin

    2016-01-01

    product of (26)Al. This correlation is interpreted as reflecting progressive thermal processing of in-falling (26)Al-rich molecular cloud material in the inner Solar System. The thermally unprocessed molecular cloud matter reflecting the nucleosynthetic makeup of the molecular cloud before the last......)Mg*-depleted and (54)Cr-enriched component. This composition is consistent with that expected for thermally unprocessed primordial molecular cloud material before its pollution by stellar-derived (26)Al. The (26)Mg* and (54)Cr compositions of bulk metal-rich chondrites require significant amounts (25......-50%) of primordial molecular cloud matter in their precursor material. Given that such high fractions of primordial molecular cloud material are expected to survive only in the outer Solar System, we infer that, similarly to cometary bodies, metal-rich carbonaceous chondrites are samples of planetesimals...

  20. New ceramic material specially designed to optimise the output of the heating systems; Nuevo material ceramico disenado especificamente para optimizar el rendimiento de los sistemas de calefaccion

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2010-07-01

    This article sets out the main features of Dual Kherr, its development and uses. Dual Kherr(reg.) is a ceramic composite based on porcelain clay. It has been specially designed to work as a storage heater and a radiant heating system. Jointly developed by the R and D departments of both companies, PAMESA and CLIMASTAR, this new material optimises the output of any heating system and it has been specially conceived to save energy. It is a great revolution, mainly due to the following: On the one hand, Dual Kherr incorporates ceramic to the heating business, opening a new and important market. On the other hand, this new material adds the aesthetics proper of the ceramic material to the design of the heating systems. It even allows the development of artistic collections. (Author)

  1. 77 FR 9298 - Office of Hazardous Materials Safety; Actions on Special Permit Applications

    Science.gov (United States)

    2012-02-16

    ... Lake 173.302(f). special permit Charles, LA. issued on an emergency basis to a permanent special permit... and Space authorize the Administration transportation in (NASA) commerce of certain Washington, DC... Aeronautics & transportation in Space commerce of certain Administration hydrazine fuels on (NASA) the same...

  2. 41 CFR 101-42.404 - Special requirements for the sale of hazardous materials.

    Science.gov (United States)

    2010-07-01

    ... 41 Public Contracts and Property Management 2 2010-07-01 2010-07-01 true Special requirements for... Management Federal Property Management Regulations System FEDERAL PROPERTY MANAGEMENT REGULATIONS UTILIZATION... special storage and handling. It is the responsibility of the holding agency to properly store hazardous...

  3. 77 FR 23803 - Office of Hazardous Materials Safety; Actions on Special Permit Applications

    Science.gov (United States)

    2012-04-20

    ...-M......... Conference of 49 CFR To modify the Radiation 172.203(d); special permit add Control Part............ Conference of 49 CFR Part To modify the Radiation 172, Subparts, special permit add Control C, D, E, F, G, 49...; additional mode of Berlin 173.345; transportation Packaging 173.346; (cargo vessel). (Former 173.359; Grantee...

  4. 75 FR 43898 - Hazardous Materials Transportation: Revisions of Special Permits Procedures

    Science.gov (United States)

    2010-07-27

    .... The HMR generally are performance-oriented regulations that provide the regulated community with a... aircraft except under a special permit (see Columns 9A and 9B in the table in 49 CFR 172.101), an applicant... forbidden for transportation by aircraft except under a special permit (see Columns 9A and 9B in the table...

  5. Experimental screening of carbon-base materials for impact members in isotopic heat sources

    International Nuclear Information System (INIS)

    Bansal, G.K.; Duckworth, W.H.

    1976-11-01

    Fourteen C/C composites and three reentry-grade bulk graphites were evaluated experimentally to determine their applicability for impact member use in radioisotope heat sources. The composites included the following generic types: (1) 2-D cloth lay-ups; (2) 2-D and 3-D felts; (3) 3-D weaves; (4) 3-D pierced fabrics; (5) 7-D weave; and (6) coarse polar weave. Also included was the 2-D randomly wound, resin-impregnated C/C material presently used as the impact member in the MHW RTG and commonly designated ''GIS'' (an acronym for graphite impact shell). The various materials were evaluated as energy absorbing materials. None of the materials in these tests performed appreciably better than the GIS impact member material now used in the MHW heat source, HITCO Pyro Carb 814. Two cloth lay-up composites, HITCO's Pyro Carb 903 and Carborundum's Carbitex 700, were somewhat superior in performance, while the bulk graphites and felt-base composites ranked least effective as energy absorbers. All experimental data and other factors considered to date suggest that Pyro Carb 903 is the best prospect for a bifunctional heat shield and impact member. Its high density (1.80 g/cm 3 ) indicates potentially good ablation resistance to accompany its indicated good performance as an energy absorber

  6. STUDY ON THE USAGE OF SPECIAL MATERIALS FOR HIGH-STRENGTH PARTS USED IN THE MACHINES MANUFACTURING INDUSTRY

    Directory of Open Access Journals (Sweden)

    BIBU Marius

    2016-09-01

    Full Text Available Whereas formerly metallic materials were used extensively and for various purposes in the machines manufacturing industry, nowadays new materials are sought that can replace the "conventional" machines manufacturing materials with new ones. This is especially challenging in areas where parts need to be able to withstand very tough conditions, such as high temperatures or large forces applied to them. The current paper intends to analyze some of the most widely used materials for high-strength applications. A special focus in this regard is on the one hand in fiber-reinforced composite materials with the polymer matrix and on the other hand on basalt. The most important properties, processing technologies and applications of these materials are analyzed and discussed and conclusions are drawn regarding their compatibility with the intended purpose.

  7. Determination of the isotopic composition of neutron irradiated nuclear fuel materials by MCNPX

    International Nuclear Information System (INIS)

    Cerba, S.; Necas, V.

    2012-01-01

    The aim of this study was to examine whether the MCNPX code can provide acceptable results in fuel depletion calculation. There sets of cross section libraries have been process with the NJOY code on the basis of three different cross section evaluations. These libraries had been validated and the statistical evaluation of the results showed that all three sets had been processed correctly and they are applicable for the burnup calculation. To verify the burnup capabilities of the MCNPX code the third case of the IV-B phase of the OECD NEA Burnup credit benchmark has been chosen, which is a code to code validation. The main task was to compare the k and the isotope concentrations at 4 burnup steps. The comparison of the calculation results clearly showed that the results obtained by MCNPX were in the range of other codes used in nuclear research. There were some discrepancies between the calculated and the benchmark data, but it was not possible to definitely conclude whether they were caused by the accuracy of the program or not. On the one hand, the results showed that some discrepancies may have been caused by the different cross section evaluations used in the calculation. On the other hand we cannot determine, how accurate the results from the other codes were; thus the deviations that at the first glance seemed to be high might not have necessarily meant inaccuracies in the calculation. Despite the fact that the MCNPX code is still in development, we can conclude that the code is capable of obtaining relevant results. (authors)

  8. A measuring system for the fast simultaneous isotope ratio and elemental analysis of carbon, hydrogen, nitrogen and sulfur in food commodities and other biological material.

    Science.gov (United States)

    Sieper, Hans-Peter; Kupka, Hans-Joachim; Williams, Tony; Rossmann, Andreas; Rummel, Susanne; Tanz, Nicole; Schmidt, Hanns-Ludwig

    2006-01-01

    The isotope ratio of each of the light elements preserves individual information on the origin and history of organic natural compounds. Therefore, a multi-element isotope ratio analysis is the most efficient means for the origin and authenticity assignment of food, and also for the solution of various problems in ecology, archaeology and criminology. Due to the extraordinary relative abundances of the elements hydrogen, carbon, nitrogen and sulfur in some biological material and to the need for individual sample preparations for H and S, their isotope ratio determination currently requires at least three independent procedures and approximately 1 h of work. We present here a system for the integrated elemental and isotope ratio analysis of all four elements in one sample within 20 min. The system consists of an elemental analyser coupled to an isotope ratio mass spectrometer with an inlet system for four reference gases (N(2), CO(2), H(2) and SO(2)). The combustion gases are separated by reversible adsorption and determined by a thermoconductivity detector; H(2)O is reduced to H(2). The analyser is able to combust samples with up to 100 mg of organic material, sufficient to analyse samples with even unusual elemental ratios, in one run. A comparison of the isotope ratios of samples of water, fruit juices, cheese and ethanol from wine, analysed by the four-element analyser and by classical methods and systems, respectively, yielded excellent agreements. The sensitivity of the device for the isotope ratio measurement of C and N corresponds to that of other systems. It is less by a factor of four for H and by a factor of two for S, and the error ranges are identical to those of other systems. Copyright (c) 2006 John Wiley & Sons, Ltd.

  9. The EC thematic network on the analysis of thorium and its isotopes in workplace materials

    International Nuclear Information System (INIS)

    Howe, A.M.; Bernot, C.; Woods, M.J.

    2001-01-01

    Accurate measurements of workplace exposure to 232 Th and its progeny are required to estimate internal radiation doses received by persons working with thorium-containing materials. However, a small intercomparison carried out in the mid-nineteen nineties raised doubts about the reliability of results obtained by methods available for measurement of thorium. An EC-funded thematic network was therefore established to bring together experts in the field of thorium analysis in order to coordinate research activity and identify best analytical practice, requirements for reference materials, etc. This network has now successfully completed its work programme, which included a survey to determine future research needs; a series of intercomparisons to test the performance of methods for measuring thorium in workplace materials, and a workshop held to promote best practice and transfer information to regulatory authorities and industry. Results of the work have been used to make various recommendations concerning future needs in this field. (author)

  10. [Care and specialized clinical follow-up of nursing professionals who have been victims of accidents with biological material].

    Science.gov (United States)

    Pimenta, Flaviana Regina; Ferreira, Milene Dias; Gir, Elucir; Hayashida, Miyeko; Canini, Silvia Rita Marin da Silva

    2013-02-01

    This cross-sectional study aimed to evaluate the conduct of nursing professionals who had been victims of accidents with biological material in a teaching hospital in the interior of the state of São Paulo, Brazil, regarding their care and specialized clinical follow-up. The study population consisted of 1,215 nursing professionals, who were interviewed individually between 2010 and 2011. Of the 1,215 nursing professionals interviewed, 636 (52.3%) reported having experienced accidents with biological material; of this population, 182 (28.6%) didn't sought specialized care. The most frequent reason reported for not seeking care was believing that it was a low-risk accident. The reasons professionals do not seek care and do not complete treatment and the clinical follow-up can contribute to strategies to increase professionals' adherence to prophylaxis measures after occupational exposure to biological material.

  11. Laser Isotope Enrichment for Medical and Industrial Applications

    Energy Technology Data Exchange (ETDEWEB)

    Leonard Bond

    2006-07-01

    Laser Isotope Enrichment for Medical and Industrial Applications by Jeff Eerkens (University of Missouri), Jay Kunze (Idaho State University), and Leonard Bond (Idaho National Laboratory) The principal isotope enrichment business in the world is the enrichment of uranium for commercial power reactor fuels. However, there are a number of other needs for separated isotopes. Some examples are: 1) Pure isotopic targets for irradiation to produce medical radioisotopes. 2) Pure isotopes for semiconductors. 3) Low neutron capture isotopes for various uses in nuclear reactors. 4) Isotopes for industrial tracer/identification applications. Examples of interest to medicine are targets to produce radio-isotopes such as S-33, Mo-98, Mo-100, W-186, Sn-112; while for MRI diagnostics, the non-radioactive Xe-129 isotope is wanted. For super-semiconductor applications some desired industrial isotopes are Si-28, Ga-69, Ge-74, Se-80, Te-128, etc. An example of a low cross section isotope for use in reactors is Zn-68 as a corrosion inhibitor material in nuclear reactor primary systems. Neutron activation of Ar isotopes is of interest in industrial tracer and diagnostic applications (e.g. oil-logging). . In the past few years there has been a sufficient supply of isotopes in common demand, because of huge Russian stockpiles produced with old electromagnetic and centrifuge separators previously used for uranium enrichment. Production of specialized isotopes in the USA has been largely accomplished using old ”calutrons” (electromagnetic separators) at Oak Ridge National Laboratory. These methods of separating isotopes are rather energy inefficient. Use of lasers for isotope separation has been considered for many decades. None of the proposed methods have attained sufficient proof of principal status to be economically attractive to pursue commercially. Some of the authors have succeeded in separating sulfur isotopes using a rather new and different method, known as condensation

  12. Laser Isotope Enrichment for Medical and Industrial Applications

    International Nuclear Information System (INIS)

    Leonard Bond

    2006-01-01

    Laser Isotope Enrichment for Medical and Industrial Applications by Jeff Eerkens (University of Missouri), Jay Kunze (Idaho State University), and Leonard Bond (Idaho National Laboratory) The principal isotope enrichment business in the world is the enrichment of uranium for commercial power reactor fuels. However, there are a number of other needs for separated isotopes. Some examples are: (1) Pure isotopic targets for irradiation to produce medical radioisotopes. (2) Pure isotopes for semiconductors. (3) Low neutron capture isotopes for various uses in nuclear reactors. (4) Isotopes for industrial tracer/identification applications. Examples of interest to medicine are targets to produce radio-isotopes such as S-33, Mo-98, Mo-100, W-186, Sn-112; while for MRI diagnostics, the non-radioactive Xe-129 isotope is wanted. For super-semiconductor applications some desired industrial isotopes are Si-28, Ga-69, Ge-74, Se-80, Te-128, etc. An example of a low cross section isotope for use in reactors is Zn-68 as a corrosion inhibitor material in nuclear reactor primary systems. Neutron activation of Ar isotopes is of interest in industrial tracer and diagnostic applications (e.g. oil-logging). . In the past few years there has been a sufficient supply of isotopes in common demand, because of huge Russian stockpiles produced with old electromagnetic and centrifuge separators previously used for uranium enrichment. Production of specialized isotopes in the USA has been largely accomplished using old ''calutrons'' (electromagnetic separators) at Oak Ridge National Laboratory. These methods of separating isotopes are rather energy inefficient. Use of lasers for isotope separation has been considered for many decades. None of the proposed methods have attained sufficient proof of principal status to be economically attractive to pursue commercially. Some of the authors have succeeded in separating sulfur isotopes using a rather new and different method, known as condensation

  13. Isotope production and distribution Programs Fiscal Year (FY) 1995 Financial Statement Audit (ER-FC-96-01)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-02-12

    The charter of the Department of Energy (DOE) Isotope Production and Distribution Program (Isotope Program) covers the production and sale of radioactive and stable isotopes, associated byproducts, surplus materials such as lithium and deuterium, and related isotope services. Services provided include, but are not limited to, irradiation services, target preparation and processing, source encapsulation and other special preparations, analyses, chemical separations, and leasing of stable isotopes for research purposes. Isotope Program products and services are sold worldwide for use in a wide variety of research, development, biomedical, and industrial applications. The Isotope Program reports to the Director of the Office of Nuclear Energy, Science and Technology. The Isotope Program operates under a revolving fund, as established by the Fiscal Year 1990 Energy and Water Appropriations Act (Public Law 101-101). The Fiscal Year 1995 Appropriations Act (Public Law 103-316) modified predecessor acts to allow prices charged for Isotope Program products and services to be based on production costs, market value, the needs of the research community, and other factors. Prices set for small-volume, high-cost isotopes that are needed for research may not achieve full-cost recovery. Isotope Program costs are financed by revenues from the sale of isotopes and associated services and through payments from the isotope support decision unit, which was established in the DOE fiscal year 1995 Energy, Supply, Research, and Development appropriation. The isotope decision unit finances the production and processing of unprofitable isotopes that are vital to the national interest.

  14. High-precision Mg isotope measurements of terrestrial and extraterrestrial material by HR-MC-ICPMS—implications for the relative and absolute Mg isotope composition of the bulk silicate Earth

    DEFF Research Database (Denmark)

    Bizzarro, Martin; Paton, Chad; Larsen, Kirsten Kolbjørn

    2011-01-01

    -isotope composition for Earth’s mantle – and hence that of the bulk silicate Earth – to be 25Mg/24Mg 1/4 0.126896 ¿ 0.000025 and 26Mg/24Mg 1/4 0.139652 ¿ 0.000033. Given the restricted range of m25Mg obtained for bulk planetary material by the sample-standard bracketing technique and the excellent agreement between...

  15. Destructive and non-destructive methods of measuring the quantity and isotopic composition of fissile materials for purposes of national safeguards in the German Democratic Republic

    International Nuclear Information System (INIS)

    Villun, K.; Gruner, V.; Siebert, Kh.U.; Hoffmann, D.

    1979-01-01

    The authors give a brief description of the destructive and non-destructive methods of measuring the quantity and isotopic composition of fissile materials used in the nuclear materials accounting and control system of the German Democratic Republic. They cite examples of the use of gamma-spectrometry, X-ray fluorescence analysis, neutron activation, radiochemical techniques, mass-spectrometry and alpha-spectrometry. (author)

  16. Future Applications in Quantitative Isotopic Tracing using Homogeneously Carbon-13 Labelled Plant Material

    International Nuclear Information System (INIS)

    Slaets, Johanna I.F.; Chen, Janet; Resch, Christian; Mayr, Leopold; Weltin, Georg; Heiling, Maria; Gruber, Roman; Dercon, Gerd

    2017-01-01

    Carbon-13 ("1"3C) and nitrogen-15 ("1"5N) labelled plant material is increasingly being used to trace the fate of plant-derived C and N into the atmosphere, soil, water and organisms in many studies, including those investigating the potential of soils to store greenhouse gases belowground. Storage of C in soils can offset and even reduce atmospheric levels of the greenhouse gas, CO_2, and interest in such studies is growing due to problems associated with anthropogenic greenhouse gas emissions impacting climate change. Reduction of N loss in soils is also of great interest, as it reduces release of the greenhouse gas, N_2O, into the atmosphere. However, accurate quantitative tracing of plant-derived C and N in such research is only possible if plant material is labelled both homogeneously and in sufficient quantities.

  17. Chemical preparation of biological materials for accurate chromium determination by isotope dilution mass spectrometry

    International Nuclear Information System (INIS)

    Dunstan, L.P.; Garner, E.L.

    1977-01-01

    The current interest in trace elements in biological materials has created a need for accurate methods of analysis. The source of discrepancies and variations in chromium concentration determinations is often traceable to inadequate methods of sample preparation. Any method of Cr analysis that requires acid digestion of a biological matrix must take into consideration the existence or formation of a volatile Cr component. In addition, because Cr is often present at concentrations less than 1 μg/g, the analytical blank becomes a potential source of error. Chemical procedures have been developed for the digestion of the biological matrix and the separation of Cr without either large analytical blanks or significant losses by volatilization. These procedures have been used for the analysis of NBS Standard Reference Material (SRM) 1569 Brewers Yeast; SRM 1577 Bovine Liver; SRM 1570 Spinach and other biological materials including human hair and nails. At this time, samples containing 1 μg of Cr can be determined with an estimated accuracy of 2 percent

  18. Analysis of ceramic materials for impact members in isotopic heat sources

    International Nuclear Information System (INIS)

    Simonen, F.A.; Duckworth, W.H.

    1976-01-01

    Of the available high strength ceramics, silicon nitride offers the most promise followed by silicon carbide and aluminum oxide, and stress analyses show severe limitations on allowable velocities for impact with granite following reentry for these ceramics. Impact velocities in the 100 to 200 fps regime can be achieved only by the addition of an additional layer to distribute the high contact stress. Besides impact limitations, application of ceramic materials in heat sources would present problems both in terms of weight and fabrication. The required thickness of a ceramic impact member would be comparable to that for a carbon-carbon composite material, but the least dense of the high strength ceramics are 2 to 3 times more dense than the carbon-carbon composites. Fabrication of a ceramic heat source would require a high strength bond between the fuel and the impact member if reasonable impact velocities are to be achieved. Formation of such a bond in ceramic materials is a difficult task under normal circumstances, and would be more difficult under the restrictions imposed on the processing and handling of the 238 PuO 2 fuel. 16 fig

  19. Recent progresses and achievements in photovoltaic-phase change material technology: A review with special treatment on photovoltaic thermal-phase change material systems

    International Nuclear Information System (INIS)

    Islam, M.M.; Pandey, A.K.; Hasanuzzaman, M.; Rahim, N.A.

    2016-01-01

    Highlights: • Broad summary of phase change materials based cooling for photovoltaic modules. • Compendium on phase change materials that are mostly used in photovoltaic systems. • Extension of heat availability period by 75–100% with phase change material. • Heat storage potential improves by 33–50% more with phase change material. • Future trend and move in photovoltaic thermal research. - Abstract: This communication lays out an appraisal on the recent works of phase change materials based thermal management techniques for photovoltaic systems with special focus on the so called photovoltaic thermal-phase change material system. Attempt has also been made to draw wide-ranging classification of both photovoltaic and photovoltaic thermal systems and their conventional cooling or heat harvesting methods developed so far so that feasible phase change materials application area in these systems can be pointed out. In addition, a brief literature on phase change materials with particular focus on their solar application has also been presented. Overview of the researches and studies establish that using phase change materials for photovoltaic thermal control is technically viable if some issues like thermal conductivity or phase stability are properly addressed. The photovoltaic thermal-phase change material systems are found to offer 33% (maximum 50%) more heat storage potential than the conventional photovoltaic-thermal water system and that with 75–100% extended heat availability period and around 9% escalation in output. Reduction in temperature attained with photovoltaic thermal-phase change material system is better than that with regular photovoltaic-thermal water system, too. Studies also show the potential of another emerging technology of photovoltaic thermal-microencapsulated phase change material system that makes use of microencapsulated phase change materials in thermal regulation. Future focus areas on photovoltaic thermal-phase change

  20. A Stochastic Imaging Technique for Spatio-Spectral Characterization of Special Nuclear Material

    Science.gov (United States)

    Hamel, Michael C.

    Radiation imaging is advantageous for detecting, locating and characterizing special nuclear material (SNM) in complex environments. A dual-particle imager (DPI) has been designed that is capable of detecting gamma-ray and neutron signatures from shielded SNM. The system combines liquid organic and NaI(Tl) scintillators to form a combined Compton and neutron scatter camera. Effective image reconstruction of detected particles is a crucial component for maximizing the performance of the system; however, a key deficiency exists in the widely used list-mode maximum-likelihood estimation-maximization (MLEM) image reconstruction technique. The steady-state solution produced by this iterative method will have poor quality compared to solutions produced with fewer iterations. A stopping condition is required to achieve a better solution but these conditions fail to achieve maximum image quality. Stochastic origin ensembles (SOE) imaging is a good candidate to address this problem as it uses Markov chain Monte Carlo to reach a stochastic steady-state solution that has image quality comparable to the best MLEM solution. The application of SOE to the DPI is presented in this work. SOE was originally applied in medical imaging applications with no mechanism to isolate spectral information based on location. This capability is critical for non-proliferation applications as complex radiation environments with multiple sources are often encountered. This dissertation extends the SOE algorithm to produce spatially dependent spectra and presents experimental result showing that the technique was effective for isolating a 4.1-kg mass of weapons grade plutonium (WGPu) when other neutron and gamma-ray sources were present. This work also demonstrates the DPI as an effective tool for localizing and characterizing highly enriched uranium (HEU). A series of experiments were performed with the DPI using a deuterium-deuterium (DD) and deuterium-tritium (DT) neutron generator, as well as

  1. Platinum stable isotope analysis of geological standard reference materials by double-spike MC-ICPMS

    DEFF Research Database (Denmark)

    Creech, John Benjamin; Baker, J. A.; Handler, M. R.

    2014-01-01

    . Double-spiking of samples was carried out prior to digestion and chemical separation to correct for any mass-dependent fractionation that may occur due to incomplete recovery of Pt. Samples were digested using a NiS fire assay method, which pre-concentrates Pt into a metallic bead that is readily...... metal standard solution doped with a range of synthetic matrices and results in Pt yields of ≥90% with purity of ≥95%. Using this chemical separation technique, we have separated Pt from 11 international geological standard reference materials comprising of PGE ores, mantle rocks, igneous rocks and one...

  2. Source term estimation and the isotopic ratio of radioactive material released from the WIPP repository in New Mexico, USA

    International Nuclear Information System (INIS)

    Thakur, P.

    2016-01-01

    lifted its lid to allow release of waste into the underground air. - Highlights: • February 14, 2014 radiation release from the Nation's only TRU waste repository is discussed. • Environmental monitoring results in the vicinity of the WIPP site are presented. • Source term estimation of the radioactive material released is assessed. • The isotopic ratio of the radioactive material release from the WIPP is discussed.

  3. Environmental controls on the boron and strontium isotopic composition of aragonite shell material of cultured Arctica islandica

    Directory of Open Access Journals (Sweden)

    Y.-W. Liu

    2015-06-01

    Full Text Available Ocean acidification, the decrease in ocean pH associated with increasing atmospheric CO2, is likely to impact marine organisms, particularly those that produce carbonate skeletons or shells. Therefore, it is important to investigate how environmental factors (seawater pH, temperature and salinity influence the chemical compositions in biogenic carbonates. In this study we report the first high-resolution strontium (87Sr / 86Sr and δ88 / 86Sr and boron (δ11B isotopic values in the aragonite shell of cultured Arctica islandica (A. islandica. The 87Sr / 86Sr ratios from both tank water and shell samples show ratios nearly identical to the open ocean, which suggests that the shell material reflects ambient ocean chemistry without terrestrial influence. The 84Sr–87Sr double-spike-resolved shell δ88 / 86Sr and Sr concentration data show no resolvable change throughout the culture period and reflect no theoretical kinetic mass fractionation throughout the experiment despite a temperature change of more than 15 °C. The δ11B records from the experiment show at least a 5‰ increase through the 29-week culture season (January 2010–August 2010, with low values from the beginning to week 19 and higher values thereafter. The larger range in δ11B in this experiment compared to predictions based on other carbonate organisms (2–3‰ suggests that a species-specific fractionation factor may be required. A significant correlation between the ΔpH (pHshell − pHsw and seawater pH (pHsw was observed (R2 = 0.35, where the pHshell is the calcification pH of the shell calculated from boron isotopic composition. This negative correlation suggests that A. islandica partly regulates the pH of the extrapallial fluid. However, this proposed mechanism only explains approximately 35% of the variance in the δ11B data. Instead, a rapid rise in δ11B of the shell material after week 19, during the summer, suggests that the boron uptake changes when a thermal

  4. The PACKTRAM database on national competent authorities' approval certificates for package design, special form material and shipment of radioactive material. User's guide for compiled system program

    International Nuclear Information System (INIS)

    1995-01-01

    The PACKTRAM system program enables Member States to prepare data diskettes on national competent authorities' approval certificates for package design, special form material and shipment of radioactive material, for submission to the IAEA, and facilitates data manipulation and report preparation for the IAEA. The system program is provided as a 424 kbyte executable file, for which this document is the User Guide. The system is fully menu-driven and requires an IBM-compatible personal computer with a minimum of 640 kbyte random access memory, a hard drive and one 3-1/2 inch diskette drive. 3 refs, 6 tabs

  5. Thematic network on the analysis of thorium and its isotopes in workplace materials

    International Nuclear Information System (INIS)

    Bernot, C.; Butler, O.; Howe, A.

    2002-05-01

    An EC-funded thematic network was established to bring together experts in the field of thorium analysis in order to co-ordinate research activity and identify best analytical practice, requirements for reference materials, etc. The work programme of the network included (i) a survey of past, current and proposed research to determine future research needs; (ii) a series of intercomparison exercises to test the performance of methods for measuring thorium in workplace materials; and (iii) a workshop to promote best practice and transfer information to regulatory authorities and industry. Three interlaboratory comparisons were carried out, as planned, to test the performance of techniques and methodologies available for measurement of thorium. Test solutions containing 232 Th and 228 Th in equilibrium, test solutions containing 232 Th and 228 Th in disequilibrium and solid test samples containing 232 Th and 228 Th in equilibrium were supplied to participants. These were analysed by a variety of techniques. Full details of the three laboratory intercomparisons are given in a series of HSL reports and in other publications

  6. A green strategy for lithium isotopes separation by using mesoporous silica materials doped with ionic liquids and benzo-15-crown-5

    International Nuclear Information System (INIS)

    Wen Zhou; Xiao-Li Sun; Lin Gu; Fei-Fei Bao; Xin-Xin Xu; Chun-Yan Pang; Zaijun Li; Zhi-Guo Gu; Jiangnan University, Wuxi

    2014-01-01

    Three new mesoporous silica materials IL15SGs (HF15SG, TF15SG and DF15SG) doped with benzo-15-crown-5 and imidazolium based ionic liquids (C 8 mim + PF 6 - , C 8 mim + BF 4 - or C 8 mim + NTf 2 - ) have been prepared by a simple approach to separating lithium isotopes. The formed mesoporous structures of silica gels have been confirmed by transmission electron microscopy image and N 2 gas adsorption-desorption isotherm. Imidazolium ionic liquids acted as templates to prepare mesoporous materials, additives to stabilize extractant within silica gel, and synergetic agents to separate the lithium isotopes. Factors such as lithium salt concentration, initial pH, counter anion of lithium salt, extraction time, and temperature on the lithium isotopes separation were examined. Under optimized conditions, the extraction efficiency of HF15SG, TF15SG and DF15SG were found to be 11.43, 10.59 and 13.07 %, respectively. The heavier isotope 7 Li was concentrated in the solution phase while the lighter isotope 6 Li was enriched in the gel phase. The solid-liquid extraction maximum single-stage isotopes separation factor of 6 Li- 7 Li in the solid-liquid extraction was up to 1.046 ± 0.002. X-ray crystal structure analysis indicated that the lithium salt was extracted into the solid phase with crown ether forming [(Li 0.5 ) 2 (B 15 ) 2 (H 2 O)] + complexes. IL15SGs were also easily regenerated by stripping with 20 mmol L -1 HCl and reused in the consecutive removal of lithium ion in five cycles. (author)

  7. Performance evaluation of a commercially available heat flow calorimeter and applicability assessment for safeguarding special nuclear materials

    International Nuclear Information System (INIS)

    Bracken, D.S.; Biddle, R.; Rudy, C.

    1998-01-01

    The performance characteristics of a commercially available heat-flow calorimeter will be presented. The heat-flow sensors within the calorimeter are based on thermopile technology with a vendor-quoted sensitivity of 150 microV/mW. The calorimeter is a full-twin design to compensate for ambient temperature fluctuations. The efficacy of temperature fluctuation compensations will also be detailed. Finally, an assessment of design applicability to special nuclear materials control and accountability and safeguarding will be presented

  8. Development of RIMS apparatus for isotope analysis of calcium in nuclear waste materials

    International Nuclear Information System (INIS)

    Miyabe, Masabumi; Oba, Masaki; Kato, Masaaki; Wakaida, Ikuo; Watanabe, Kazuo

    2006-01-01

    We have developed a frequency stabilized laser system of RIMS analysis of a long-lived radionuclide of calcium ( 41 Ca) in concrete waste materials. A stable reference laser has been developed using magnetically induced circular dichroism of atomic rubidium. The frequency stability was estimated to be 50 kHz over 8-h period from beat frequency measurement. Furthermore, a computer-controlled fringe offset lock system has been developed to transfer the high frequency stability to the other lasers for three-step excitation of atomic calcium. By using the system precise frequency tuning of 1 MHz error over 1 GHz scan was realized. The overall frequency tuning precision was also confirmed by a multistep fluorescence and resonance ionization spectroscopy of calcium. (author)

  9. Isotope separation process

    International Nuclear Information System (INIS)

    Lyon, R.K.

    1976-01-01

    The instant invention relates to a process for separating a material into two or more parts in each of which the abundances of the isotopes of a given element differ from the abundances of the isotopes of the same material in said material. In one embodiment, the invention relates to a method for the isotopically selective excitation of gas phase molecules by multiple infrared photon absorption followed by selective dissociation of said excited molecules by the absorption of a single photon of visible or ultraviolet light. This invention is useful for, but not limited to, the separation of the principal isotopes of uranium. 11 Claims, 2 Drawing Figures

  10. Special purpose materials for the fusion reactor environment: a technical assessment

    Energy Technology Data Exchange (ETDEWEB)

    None

    1978-02-01

    This technology assessment considers the following areas: (1) breeding materials, (2) coolants, (3) tritium barriers, (4) graphite and silicon carbide, (5) ceramics, (6) heat-sink materials, and (7) magnet materials. Some questions and analyses forming the assessment are described. (MOW)

  11. Directory of national competent authorities' approval certificates for package design, special form material and shipment of radioactive material. 1993 ed

    International Nuclear Information System (INIS)

    1993-10-01

    This is the fourth annual report being published by the Secretariat of the International Atomic Energy Agency since implementing its database on package approval certificates (PACKTRAM) at the recommendation of the Standing Advisory Group on the Safe Transport of Radioactive Material (SAGSTRAM). The reporting format was established at consecutive meetings of SAGSTRAM, whose memberships consists of national competent authorities responsible for the transport of radioactive material from those Member States who have a nuclear industry and others who have shown a keen interest in the IAEA's transport safety programme. Through the PACKTRAM database, the Secretariat collects administrative and technical information on package approval certificates to assist national competent authorities in regulating radioactive material movements in their country. The database carries information on extant certificates and those that expired within the last two complete calendar years. The 1985 Edition of IAEA Safety Series No. 6, the 'Regulations for the Safe Transport of Radioactive Material'' highlights the role of competent authorities in assuring regulatory compliance in their own countries. Package approval certificates are an important aspect of that function. This document aims to be a useful reference for competent authorities as well as for manufacturers and shippers of radioactive material. 6 tabs

  12. Directory of national competent authorities` approval certificates for package design, special form material and shipment of radioactive material. 1995 edition

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-09-01

    This is the sixth annual report being published by the Secretariat of the International Atomic Energy Agency since implementing its database on package approval certificates (PACKTRAM) at the recommendation of the Standing Advisory Group on the Safe Transport of Radioactive Material (SAGSTRAM). The reporting format was established at consecutive meetings of SAGSTRAM, whose membership consists of national competent authorities responsible for the transport of radioactive material from those Member States who have a nuclear industry and others who have shown a keen interest in the IAEA`s transport safety programme. Through the PACKTRAM database, the Secretariat collects administrative and technical information on package approval certificates to assist national competent authorities in regulating radioactive material movements in their country. The database carries information on extant certificates and those that expired within the last complete calendar year. The 1985 Edition of IAEA Safety Series No. 6, the ``Regulations for the Safe Transport of Radioactive Material`` highlights the role of competent authorities in assuring regulatory compliance in their own countries. Package approval certificates are an important aspect of that function. This document aims to be a useful reference for competent authorities as well as for manufacturers and shippers of radioactive material. 6 tabs.

  13. Directory of national competent authorities' approval certificates for package design, special form material and shipment of radioactive material. 1999 Edition

    International Nuclear Information System (INIS)

    1999-08-01

    This is the tenth annual report being published by the Secretariat of the International Atomic Energy Agency since implementing its database on package approval certificates (PACKTRAM) at the recommendation of the Transport Safety Standards Advisory Committee (TRANSSAC), formerly known as the Standing Advisory Group on the Safe Transport of Radioactive Material (SAGSTRAM). The reporting format was established at consecutive meetings of SAGSTRAM and endorsed by TRANSSAC, whose membership consists of national competent authorities responsible for the transport of radioactive material from those Member States who have a nuclear industry and others who have shown a keen interest in the IAEA's transport safety programme. Through the PACKTRAM database, the Secretariat collects administrative and technical information on package approval certificates to assist national competent authorities in regulating radioactive material movements in their country. The database carries information on extant certificates and those that expired within the last complete calendar year. The 1985 Edition of IAEA Safety Series No. 6, the 'Regulations for the Safe Transport of Radioactive Material' highlights the role of competent authorities in assuring regulatory compliance in their own countries. Package approval certificates are an important aspect of that function. This document aims to be a useful reference for competent authorities as well as for manufacturers and shippers of radioactive material

  14. Directory of national competent authorities' approval certificates for package design, special form material and shipment of radioactive material. 1994 ed

    International Nuclear Information System (INIS)

    1994-08-01

    This is the fifth annual report being published by the Secretariat of the International Atomic Energy Agency since implementing its database on package approval certificates (PACKTRAM) at the recommendation of the Standing Advisory Group on the Safe Transport of Radioactive Material (SAGSTRAM). The reporting format was established at consecutive meetings of SAGSTRAM, whose membership consists of national competent authorities responsible for the transport of radioactive material from those Member States who have a nuclear industry and others who have shown a keen interest in the IAEA's transport safety programme. Through the PACKTRAM database, the Secretariat collects administrative and technical information on package approval certificates to assist national competent authorities in regulating radioactive material movements in their country. The database carries information on extant certificates and those that expired within the last two complete calendar years. The 1985 Edition of IAEA Safety Series No. 6, the ''Regulations for the Safe Transport of Radioactive Material'' highlights the role of competent authorities in assuring regulatory compliance in their own countries. Package approval certificates are an important aspect of that function. This document aims to be a useful reference for competent authorities as well as for manufacturers and shippers of radioactive material

  15. Directory of national competent authorities' approval certificates for package design, special form material and shipment of radioactive material. 1996 edition

    International Nuclear Information System (INIS)

    1996-09-01

    This is the seventh annual report being published by the Secretariat of the International Atomic Energy Agency since implementing its database on package approval certificated (PACKTRAM) at the recommendation of the then Standing Advisory Group on the Sate Transport of Radioactive Material (SAGSTRAM). The functions of SAGSTRAM were taken over in 1996 by the Transport Safety Standards Advisory Committee (TRANSSAC). The reporting format was established at consecutive meetings of SAGSTRAM, whose membership consists of national competent authorities responsible for the transport of radioactive material from those Member States who have a nuclear industry and others who have shown a keen interest in the IAEA's transport safety programme. Through the PACKTRAM database, the Secretariat collects administrative and technical information on package approval certificates to assist national competent authorities in regulating radioactive material movements in their country. The database carries information on extant certificates and those that expired within the last complete calendar year. The 1985 Edition of IAEA Safety Series No. 6, the ''Regulations for the Safe Transport of Radioactive Material'', highlights the role of competent authorities in assuring regulatory compliance in their own countries. Package approval certificates are an important aspect of that function. This document aims to be a useful reference for competent authorities as well as for manufacturers and shippers of radioactive material. 6 tabs

  16. Directory of national competent authorities' approval certificates for package design, special form material and shipment of radioactive material. 1995 edition

    International Nuclear Information System (INIS)

    1995-09-01

    This is the sixth annual report being published by the Secretariat of the International Atomic Energy Agency since implementing its database on package approval certificates (PACKTRAM) at the recommendation of the Standing Advisory Group on the Safe Transport of Radioactive Material (SAGSTRAM). The reporting format was established at consecutive meetings of SAGSTRAM, whose membership consists of national competent authorities responsible for the transport of radioactive material from those Member States who have a nuclear industry and others who have shown a keen interest in the IAEA's transport safety programme. Through the PACKTRAM database, the Secretariat collects administrative and technical information on package approval certificates to assist national competent authorities in regulating radioactive material movements in their country. The database carries information on extant certificates and those that expired within the last complete calendar year. The 1985 Edition of IAEA Safety Series No. 6, the ''Regulations for the Safe Transport of Radioactive Material'' highlights the role of competent authorities in assuring regulatory compliance in their own countries. Package approval certificates are an important aspect of that function. This document aims to be a useful reference for competent authorities as well as for manufacturers and shippers of radioactive material. 6 tabs

  17. Determination of some trace elements in biological materials using the short living isotopes

    International Nuclear Information System (INIS)

    Taskaev, E.

    1985-01-01

    A method for determination of V, Cu, Rb, Mo and K in breast cancer tumors is described. Samples were irradiated with ICIS pneumatic irradiation system of University of London Reactor Centre for 5 min. with mixed neutron flux: 1,7.10 1 2 thermal neutrons.cm -2 .s -1 and 9.10 11 fast neutrons.cm -2 .s -1 . Wet ashing procedure of Byrne and Kosta was used for the dissolution. Consecutive separation procedures of V and Mo, Cu, Mn, K and Rb, followed by counting and activity measuring were carried out. In order to study the chemical yields for all the elements both animal and plant matrixes were used. The error of 3% ( 0.05 confidence level) for single determination of chemical yield was chosen as the highest value acceptable. The possibility of using 137-Cs tracer for K and Rb chemical yield determination was also checked. To check the whole procedure the standard reference materials SRM-1577 Bovine Liver, SRM-1571 Orchard Leaves and Bowen's Kale were analysed

  18. A real-time material control concept for safeguarding special nuclear material in United States licensed processing facilities

    International Nuclear Information System (INIS)

    Shea, T.E.

    1976-01-01

    This paper describes general safeguards research being undertaken by the United States Nuclear Regulatory Commission. Efforts to improve the ability of United States licensed plants to contend with the perceived threat of covert material theft are emphasized. The framework for this improvement is to break down the internal control and accounting system into subsystems to achieve material isolation, inventory control, inventory characterization, and inventory containment analysis. A general programme is outlined to develop and evaluate appropriate mechanisms, integrate selected mechanisms into subsystems, and evaluate the subsystems in the context of policy requirements. (author)

  19. 77 FR 64450 - Hazardous Materials: Incorporation of Certain Special Permits and Competent Authorities Into...

    Science.gov (United States)

    2012-10-22

    ... posted without change to the Federal Docket Management System (FDMS), including any personal information.... Transportation of solid coal tar pitch compounds. Transportation of certain ammonia solutions in UN1H1 and UN6HA1... production and the transportation stream. Thus, special permits provide a mechanism for testing new...

  20. 41 CFR 101-42.304 - Special requirements for donation of certain hazardous materials.

    Science.gov (United States)

    2010-07-01

    ... 41 Public Contracts and Property Management 2 2010-07-01 2010-07-01 true Special requirements for... Management Federal Property Management Regulations System FEDERAL PROPERTY MANAGEMENT REGULATIONS UTILIZATION... is the responsibility of the Federal holding agency or State agency to properly store hazardous...

  1. Physical protection of special nuclear material in the commercial fuel cycle. Volume I. Executive summary

    International Nuclear Information System (INIS)

    1976-04-01

    This is the summary of the work and recommendations resulting from Sandia's participation in the Special Safeguards Study, which covered three areas: protection of SNM at fixed facilities, protection of SNM while in transit, and relocation and recovery of lost SNM. The results are published in full in five other volumes. 6 tables, 4 fig

  2. 77 FR 71031 - Office of Hazardous Materials Safety; Actions on Special Permit Applications

    Science.gov (United States)

    2012-11-28

    ...-Mart Stores, Inc. 49 CFR part 172, part To authorize the one-time, Bentonville, AR. 173 and part 177...- impaired retail stores impacted by Hurricane Sandy to a temporary warehousing facility for approximately 10... Request by EQ Industrial Services, Inc. Ypsilanti, MI October 4, 2012. To modify the special permit to...

  3. Far infrared conductivity of charge density wave materials and the oxygen isotope effect in high-Tc superconductors

    International Nuclear Information System (INIS)

    Creager, W.N.

    1991-09-01

    The far infrared reflectance and conductivity of (Ta 1-x Nb x Se 4 ) 2 I and TaS 3 have been measured to determine the origin of a huge infrared resonance that dominates the charge density wave (CDW) dynamics along with the pinned acoustic phason mode in the related materials (TaSe 4 ) 2 I and K 0. 3 MoO 3 . The measurements cover frequencies from 3 to 700cm -1 and the temperature range from 15K to 300K. In the niobium-doped alloys (Ta 1-x Nb x Se 4 ) 2 I, the size and frequency of the giant infrared mode remain nearly constant as the impurity concentration x is increased. For TaS 3 , the pinned acoustic phason near 0.5cm -1 dominates var-epsilon(ω) and an additional small mode lies near 9cm -1 . The latter mode is much smaller than the infrared mode in other CDW materials. These results rule out several models of a ''generic infrared mode'' in CDW excitations. They are compared in detail to the predictions of a recent theory attributing the infrared mode to a bound collective mode localized at impurity sites within the crystal. The transmittance of K 0.3 MoO 3 has been measured at 1.2K with a strong dc electric field applied across the crystal. Under these conditions, the charge density wave depins abruptly and carries large currents with near-zero differential resistance. For some samples, the low-frequency transmittance is enhanced slightly when the CDW depins. The magnitude of the oxygen isotope effect in the high-T c superconductor YBa 2 Cu 3 O 7 has been determined by substitution of 18 O for 16 O. A series of cross-exchanges was performed on high-quality polycrystalline specimens to eliminate uncertainties due to sample heat treatments and sample inhomogeneities

  4. Directory of national competent authorities' approval certificates for package design, special form material and shipment of radioactive material. 2000 edition

    International Nuclear Information System (INIS)

    2000-08-01

    Safety in the transport of radioactive material is dependent on packaging appropriate for the contents being shipped, rather than on operational and/or administrative actions required on the package. The grater the radiological risk posed by the material being moved, the more stringent become the performance for the packaging that can be authorised to contain it. These principles have been expanded since 1061 into a set of regulations that are responsible for safety moving the ever-growing number and complexity of radioactive material shipments throughout the world. The IAEA Regulations for the Safe Transport of Radioactive Material are incorporated into UN regulations, as well as the requirements of other international transport organizations. This is the eleventh report published by the IAEA since implementing its database on package approval certificates (PACKTRAM) at the recommendation of the Transport safety Standards Advisory Committee (TRANSSAC). Through the PACKTRAM database, the IAEA collects administrative and technical information provided by the issuing competent authority about package approval certificates

  5. Directory of national competent authorities' approval certificates for package design, special form material and shipment of radioactive material. 1997 Edition

    International Nuclear Information System (INIS)

    1997-08-01

    This is the eighth annual report being published by the Secretariat of the International Atomic Energy Agency since implementing its database on package approval certificates (PACKTRAM) at the recommendation of the then Standing Advisory Group on the Safe Transport of Radioactive Material (SAGSTRAM). The functions of SAGSTRAM were taken over in 1996 by the Transport Safety Standards Advisory Committee (TRANSSAC). The reporting format was established at consecutive meetings of SAGSTRAM, whose membership consisted of national competent authorities responsible for the transport of radioactive material from those Member States who have a nuclear industry and others who showed a keen interest in the IAEA's transport safety programme. TRANSSAC underscores the importance of data collecting activities and recommends the continued publication of this annual report. The 1985 Edition of Safety Series No. 6, the ''Regulations for the Safe Transport of Radioactive Material'', highlights the role of competent authorities in assuring regulatory compliance in their own countries. The issuance of package approval certificates is an important aspects of that function. This document aims to be a useful reference for competent authorities as well as for manufacturers and shippers of radioactive material. 6 tabs

  6. Separation of uranium isotopes

    International Nuclear Information System (INIS)

    Porter, J.T.

    1980-01-01

    Methods and apparatus are disclosed for separation of uranium isotopes by selective isotopic excitation of photochemically reactive uranyl salt source material at cryogenic temperatures, followed by chemical separation of selectively photochemically reduced U+4 thereby produced from remaining uranyl source material

  7. Applications of stable isotopes

    International Nuclear Information System (INIS)

    Letolle, R.; Mariotti, A.; Bariac, T.

    1991-06-01

    This report reviews the historical background and the properties of stable isotopes, the methods used for their measurement (mass spectrometry and others), the present technics for isotope enrichment and separation, and at last the various present and foreseeable application (in nuclear energy, physical and chemical research, materials industry and research; tracing in industrial, medical and agronomical tests; the use of natural isotope variations for environmental studies, agronomy, natural resources appraising: water, minerals, energy). Some new possibilities in the use of stable isotope are offered. A last chapter gives the present state and forecast development of stable isotope uses in France and Europe

  8. Instructional Modules for Training Special Education Teachers: A Final Report on the Development and Field Testing of the CUNY-CBTEP Special Education Modules. Case 30-76. Toward Competence Instructional Materials for Teacher Education.

    Science.gov (United States)

    City Univ. of New York, NY. Center for Advanced Study in Education.

    The City University of New York Competency Based Teacher Education Project (CUNY-CBTEP) in Special Education studied Modularization, focusing on the variables in the instructional setting that facilitate learning from modular materials for a wide range of students. Four of the five modules for the training of special education teachers developed…

  9. Some new high energy materials and their formulations for specialized applications

    Energy Technology Data Exchange (ETDEWEB)

    Agrawal, Jai Prakash [Directorate of Materials, DRDO HQrs, ' B' Wing, Sena Bhavan, New Delhi - 110 011 (India)

    2005-10-01

    Energetic materials form an integral part of most weapon systems and a large number of new high-energy materials: thermally stable explosives, high-performance explosives, melt-castable explosives, insensitive high explosives and energetic binders have been reported in the literature in recent years. Some explosive formulations based on these new energetic materials are also vaguely reported. This paper examines these materials and their formulations from the point of view of stability, reliability, safety and specific applications. (Abstract Copyright [2005], Wiley Periodicals, Inc.)

  10. Analysis of alternative transportation methods for radioactive materials shipments including the use of special trains for spent fuel and wastes

    International Nuclear Information System (INIS)

    Smith, D.R.; Luna, R.E.; Taylor, J.M.

    1978-01-01

    Two studies were completed which evaluate the environmental impact of radioactive material transport. The first was a generic study which evaluated all radioactive materials and all transportation modes; the second addressed spent fuel and fuel-cycle wastes shipped by truck, rail and barge. A portion of each of those studies dealing with the change in impact resulting from alternative shipping methods is presented in this paper. Alternatives evaluated in each study were mode shifts, operational constraints, and, in generic case, changes in material properties and package capabilities. Data for the analyses were obtained from a shipper survey and from projections of shipments that would occur in an equilibrium fuel cycle supporting one hundred 1000-MW(e) reactors. Population exposures were deduced from point source radiation formulae using separation distances derived for scenarios appropriate to each shipping mode and to each exposed population group. Fourteen alternatives were investigated for the generic impact case. All showed relatively minor changes in the overall radiological impact. Since the radioactive material transport is estimated to be fewer than 3 latent cancer fatalities (LCF) for each shipment year (compared to some 300,000 yearly cancer fatalities or 5000 LCF's calculated for background radiation using the same radiological effects model), a 15% decrease caused by shifting from passenger air to cargo air is a relatively small effect. Eleven alternatives were considered for the fuel cycle/special train study, but only one produced a reduction in total special train baseline LCF's (.047) that was larger than 5%

  11. Directory of national competent authorities' approval certificates for package design, special form material and shipment of radioactive material. 2004 ed

    International Nuclear Information System (INIS)

    2004-10-01

    The PACKTRAM database contains administrative and technical information provided annually by the issuing competent authority about package approval certificates. Such data are used mainly by national competent authorities and port and customs officials to assist in regulating radioactive material movements in their country, and also by manufacturers and shippers of radioactive material. The database carries information on extant certificates and those that expired within the last complete calendar year. This is the fifteenth PACKTRAM annual report to being published by the IAEA. It is distributed worldwide mainly to designated competent authorities, as well as to registered interested parties. The database itself is maintained at www.packtram.org and can be accessed by the general public

  12. Statues of the study on the irradiated materials by a special capsule in HANARO

    International Nuclear Information System (INIS)

    Kang, Y.-H.; Kim, B.-G.; Cho, M.-S.; Choi, Y.

    2005-01-01

    A special capsule installed with multi-specimens for HANARO has been designed and its parts were fabricated based on the design criteria of sustaining it at the working conditions of 20 n/cm 2 of a fast neutron fluence with energies above 1 MeV and a maximum load of 200 MPa. The special capsule consists of four modules which work independently. Two of them are located in the upper part of the machine and the others are located in the lower part with a 90 degree rotation. Each module has three separate chambers, each of which contains a loading system, various measuring and controlling units. Each module was evaluated by determining the load-displacement curve of four zirconium specimens. Reliable load-displacement curves of the four specimens were obtained by a simultaneous loading at a controlled temperature. (authors)

  13. The effect of petrographical composition of coals and bituminous sediments on the material and isotopic composition of dry natural gases from artificial recoalification reactions. 2

    International Nuclear Information System (INIS)

    Maass, I.; Huebner, H.; Nitzsche, H.-M.; Schuetze, H.; Zschiesche, M.

    1975-01-01

    Experimental results indicate that on the basis of the material and isotopic composition of natural gases conclusions can be drawn with regard to the character (humic or bituminous) of the parent rock. Thus, genetic relations assumed to exist between humic sediments (e.g. coal seams) and dry natural gases as well as bituminous rocks and wet natural gases are experimentally confirmed. In addition, from analyses of the materials approximate data can be derived on the degree of carbonization of coal or bituminous sediments in the main phase of gas separation. Furthermore, these analyses were used to elucidate the question whether authochthonous or allochthonous deposits are present. It could be shown that the maceral composition of coals and of the organo-petrographical inclusions in bituminous sediments determines the isotopic composition of methane in recoalification gases to a considerable degree. (author)

  14. A Characterization of the Ship-Effect in a Maritime Environment and Special Nuclear Material Detection

    Science.gov (United States)

    2015-05-18

    physics where cosmic radiation interacts preferentially with high atomic number materials to produce additional background radiation. This research...physics where cosmic radiation interacts preferentially with high atomic number materials to produce additional background radiation. A classic...LTC Michael Shannon, Director, J9-NSERC, Defense Threat Reduction Agency IV Table of Contents Abstract

  15. A survey of infrared technology for special nuclear materials control and accounting

    International Nuclear Information System (INIS)

    Stanbro, W.D.; Leonard, R.S.; Steverson, C.A.; Angerman, M.I.

    1992-03-01

    This report reviews some aspects of current infrared measurement technology and suggests two applications in which it may be used in nuclear safeguards. These applications include both materials control and materials accounting. In each case, the measurements rely on passive detection of infrared radiation generated from the heat produced by the radioactive decay of plutonium. Both imaging and non-imaging techniques are discussed

  16. Technical appendix for the special safeguards study on material control and accounting systems. Final report

    International Nuclear Information System (INIS)

    1975-01-01

    The appendixes contain information on alarm levels for detection of theft, computer simulation of theft detection capabilities, benefits and liabilities related to real-time material control, cost analysis, and impact of collocated facilities on the real-time material control concept

  17. Oak Ridge Isotope Products and Services - Current and Expected Supply and Demand

    International Nuclear Information System (INIS)

    Aaron, W.S.; Alexander, C.W.; Cline, R.L.; Collins, E.D.; Klein, J.A.; Knauer, J.B. Jr.; Mirzadeh, S.

    1999-01-01

    Oak Ridge National Laboratory (ORNL) has been a major center of isotope production research, development, and distribution for over 50 years. Currently, the major isotope production activities include (1) the production of transuranium element radioisotopes, including 252 Cf; (2) the production of medical and industrial radioisotopes; (3) maintenance and expansion of the capabilities for production of enriched stable isotopes; and, (4) preparation of a wide range of custom-order chemical and physical forms of isotope products, particularly in accelerator physics research. The recent supply of and demand for isotope products and services in these areas, research and development (R ampersand D), and the capabilities for future supply are described in more detail below. The keys to continuing the supply of these important products and services are the maintenance, improvement, and potential expansion of specialized facilities, including (1) the High Flux Isotope Reactor (HFIR), (2) the Radiochemical Engineering Development Center (REDC) and Radiochemical Development Laboratory (RDL) hot cell facilities, (3) the electromagnetic calutron mass separators and the plasma separation process equipment for isotope enrichment, and (4) the Isotope Research Materials Laboratory (IRML) equipment for preparation of specialized chemical and physical forms of isotope products. The status and plans for these ORNL isotope production facilities are also described below

  18. Project Plan For Remove Special Nuclear Material (SNM) from Plutonium Finishing Plant (PFP) Project

    International Nuclear Information System (INIS)

    BARTLETT, W.D.

    1999-01-01

    This plan presents the overall objectives, description, justification and planning for the Plutonium Finishing Plant (PFP) Remove SNM Materials. The intent of this plan is to describe how this project will be managed and integrated with other facility stabilization and deactivation activities. This plan supplements the overall integrated plan presented in the Plutonium Finishing Plant Integrated Project Management Plan (IPMP), HNF-3617. This project plan is the top-level definitive project management document for the PFP Remove SNM Materials project. It specifies the technical, schedule, requirements and the cost baseline to manage the execution of the Remove SNM Materials project. Any deviation to the document must be authorized through the appropriate change control process. The Remove SNM Materials project provides the necessary support and controls required for DOE-HQ, DOE-RL, BWHC, and other DOE Complex Contractors the path forward to negotiate shipped/receiver agreements, schedule shipments, and transfer material out of PFP to enable final deactivation

  19. Modeling most likely pathways for smuggling radioactive and special nuclear materials on a worldwide multimodal transportation network

    Energy Technology Data Exchange (ETDEWEB)

    Saeger, Kevin J [Los Alamos National Laboratory; Cuellar, Leticia [Los Alamos National Laboratory

    2010-01-01

    Nuclear weapons proliferation is an existing and growing worldwide problem. To help with devising strategies and supporting decisions to interdict the transport of nuclear material, we developed the Pathway Analysis, Threat Response and Interdiction Options Tool (PATRIOT) that provides an analytical approach for evaluating the probability that an adversary smuggling radioactive or special nuclear material will be detected during transit. We incorporate a global, multi-modal transportation network, explicit representation of designed and serendipitous detection opportunities, and multiple threat devices, material types, and shielding levels. This paper presents the general structure of PATRIOT, and focuses on the theoretical framework used to model the reliabilities of all network components that are used to predict the most likely pathways to the target.

  20. Modeling most likely pathways for smuggling radioactive and special nuclear materials on a worldwide multi-modal transportation network

    Energy Technology Data Exchange (ETDEWEB)

    Saeger, Kevin J [Los Alamos National Laboratory; Cuellar, Leticia [Los Alamos National Laboratory

    2010-10-28

    Nuclear weapons proliferation is an existing and growing worldwide problem. To help with devising strategies and supporting decisions to interdict the transport of nuclear material, we developed the Pathway Analysis, Threat Response and Interdiction Options Tool (PATRIOT) that provides an analytical approach for evaluating the probability that an adversary smuggling radioactive or special nuclear material will be detected during transit. We incorporate a global, multi-modal transportation network, explicit representation of designed and serendipitous detection opportunities, and multiple threat devices, material types, and shielding levels. This paper presents the general structure of PATRIOT, all focuses on the theoretical framework used to model the reliabilities of all network components that are used to predict the most likely pathways to the target.

  1. Locating sensors for detecting source-to-target patterns of special nuclear material smuggling: a spatial information theoretic approach.

    Science.gov (United States)

    Przybyla, Jay; Taylor, Jeffrey; Zhou, Xuesong

    2010-01-01

    In this paper, a spatial information-theoretic model is proposed to locate sensors for detecting source-to-target patterns of special nuclear material (SNM) smuggling. In order to ship the nuclear materials from a source location with SNM production to a target city, the smugglers must employ global and domestic logistics systems. This paper focuses on locating a limited set of fixed and mobile radiation sensors in a transportation network, with the intent to maximize the expected information gain and minimize the estimation error for the subsequent nuclear material detection stage. A Kalman filtering-based framework is adapted to assist the decision-maker in quantifying the network-wide information gain and SNM flow estimation accuracy.

  2. Standard guide for application of radiation monitors to the control and physical security of special nuclear material

    International Nuclear Information System (INIS)

    Anon.

    1989-01-01

    This guide briefly describes the state-of-the-art of radiation monitors for detecting special nuclear material (SNM) in order to establish the context in which to write performance standards for the monitors. This guide extracts information from technical documentation to provide information for selecting, calibrating, testing, and operating such radiation monitors when they are used for the control and protection of SNM. This guide offers an unobtrusive means of searching pedestrians, packages, and motor vehicles for concealed SNM as one part of a nuclear material control or security plan for nuclear materials. The radiation monitors can provide an efficient, sensitive, and reliable means of detecting the theft of small quantities of SNM while maintaining a low likelihood of nuisance alarms

  3. Standard guide for application of radiation monitors to the control and physical security of special nuclear material

    CERN Document Server

    American Society for Testing and Materials. Philadelphia

    1999-01-01

    1.1 This guide briefly describes the state-of-the-art of radiation monitors for detecting special nuclear material (SNM) (see 3.1.11) in order to establish the context in which to write performance standards for the monitors. This guide extracts information from technical documentation to provide information for selecting, calibrating, testing, and operating such radiation monitors when they are used for the control and protection of SNM. This guide offers an unobtrusive means of searching pedestrians, packages, and motor vehicles for concealed SNM as one part of a nuclear material control or security plan for nuclear materials. The radiation monitors can provide an efficient, sensitive, and reliable means of detecting the theft of small quantities of SNM while maintaining a low likelihood of nuisance alarms. 1.2 Dependable operation of SNM radiation monitors rests on selecting appropriate monitors for the task, operating them in a hospitable environment, and conducting an effective program to test, calibrat...

  4. Locating Sensors for Detecting Source-to-Target Patterns of Special Nuclear Material Smuggling: A Spatial Information Theoretic Approach

    Directory of Open Access Journals (Sweden)

    Xuesong Zhou

    2010-08-01

    Full Text Available In this paper, a spatial information-theoretic model is proposed to locate sensors for detecting source-to-target patterns of special nuclear material (SNM smuggling. In order to ship the nuclear materials from a source location with SNM production to a target city, the smugglers must employ global and domestic logistics systems. This paper focuses on locating a limited set of fixed and mobile radiation sensors in a transportation network, with the intent to maximize the expected information gain and minimize the estimation error for the subsequent nuclear material detection stage. A Kalman filtering-based framework is adapted to assist the decision-maker in quantifying the network-wide information gain and SNM flow estimation accuracy.

  5. Spanish experiences with marginal and special materials on the construction of road embankments

    International Nuclear Information System (INIS)

    Cano Linares, H.; Perucho Martinez, A.

    2015-01-01

    The use of existing materials along the alignment of a road is an essential problem within the Sustainable Development policies, which is being promoting worldwide since a long time. In the Word road Association (PIARC-AIPCR) this subject has being investigated by different Technical Committees during last decades. Additionally, the review of the article 330 Embankment of PG-3 (FOM 1382/2002) has opened the door to new non-conventional materials, as wastes and artificial materials, to be used on embankments. This could come to adequate solutions, technically, and environmentally, contributing with national legislation on valorisation policies. In this sense, the use of marginal materials and wastes con represent and important save on natural resources and dumping sites. In Spain, some experiences with marginal materials and wastes have being carried out. The work presented has consisted in compiling and analysing the experiences executed with marginal materials and wastes on Spanish road embankments. Although there are many other cases, 24 cases published with adequate information have being analysed, summarising aspects as: materials problems arrangement solutions or treatments employed. Analysing these experiences and making them public can be a way to transmit confidence, help to improve knowledge, and progress on the preparation of recommendations. This work has being carried out on the frame of the Project Geotechnical Engineering, Materials and Structures and Impact of Infrastructure in Civil engineering (TTIGEM), within the frame Program Border Cooperation Spain-External Borders (POCTEFEX); particularly in the Activity 2 related to Technology Transfer of Construction Materials, including marginal materials and wastes. (Author)

  6. Directory of national competent authorities' approval certificates for package design, special form material and shipment of radioactive material. 1991 edition

    International Nuclear Information System (INIS)

    1991-08-01

    The format of this report is a result of recommendations made by the Standing Advisory Group on the Safe Transport of Radioactive Material (SAGSTRAM) at its 6th meeting in November 1987. The database was at that time maintained on the main frame and it was felt that adapting it for use on a personal computer would allow more flexibility in data processing and reporting. This document supersedes TECDOC-552 ''Directory of National Competent Authorities' Approval Certificates for Package Design and Shipment of Radioactive Material 1990 Edition''. Since publication of TECDOC-552, some modifications affecting the structure of the database and reporting formats were undertaken. These are fully described in ''Working Material: The PACKTRAM Database National Competent Authority Package Approval Certificates, User Guide Rev. 1'', which was released in early 1991. The present report is contained in five tables. In each of these, information is presented in alphabetical order based on the certificate number. This is composed of the issuing Member State's VRI code, followed by a slash, then a three- or four-digit number, another slash and finally a code identifying the type of package involved. ''-85'' is appended to those certificates that were approved on the basis of the 1985 Edition of Safety Series No. 6. Tables 1 to 4 present administrative data including issue and expire, dates, package identification, package serial numbers, modes for which the package/shipment is approved and the edition of Safety Series No. 6 on which the approval has been based. The technical information on package mass, authorized contents, and detailed and general description of the package are contained in Table. 5

  7. On-site transportation and handling of uranium-233 special nuclear material: Preliminary hazards and accident analysis. Final

    International Nuclear Information System (INIS)

    Solack, T.; West, D.; Ullman, D.; Coppock, G.; Cox, C.

    1995-01-01

    U-233 Special Nuclear Material (SNM) currently stored at the T-Building Storage Areas A and B must be transported to the SW/R Tritium Complex for repackaging. This SNM is in the form of oxide powder contained in glass jars which in turn are contained in heat sealed double polyethylene bags. These doubled-bagged glass jars have been primarily stored in structural steel casks and birdcages for approximately 20 years. The three casks, eight birdcages, and one pail/pressure vessel will be loaded onto a transport truck and moved over an eight day period. The Preliminary Hazards and Accident Analysis for the on-site transportation and handling of Uranium-233 Special Nuclear Material, documented herein, was performed in accordance with the format and content guidance of DOE-STD-3009-94, Preparation Guide for US Department of Energy Nonreactor Nuclear Facility Safety Analysis Reports, dated July 1994, specifically Chapter Three, Hazard and Accident Analysis. The Preliminary Hazards Analysis involved detailed walkdowns of all areas of the U-233 SNM movement route, including the T-Building Storage Area A and B, T-Building truck tunnel, and the roadway route. Extensive discussions were held with operations personnel from the Nuclear Material Control Group, Nuclear Materials Accountability Group, EG and G Mound Security and the Material Handling Systems Transportation Group. Existing documentation related to the on-site transportation of hazardous materials, T-Building and SW/R Tritium Complex SARs, and emergency preparedness/response documentation were also reviewed and analyzed to identify and develop the complete spectrum of energy source hazards

  8. Frontiers of ferroelectricity a special issue of the journal of materials science

    CERN Document Server

    Lang, Sidney B

    2007-01-01

    The book presents theory, fundamentals and some applications of ferroelectricy. The 24 chapters comprise reviews and research reports covering the spectrum of ferroelectricity. It is intended to describe the current levels of understanding of various aspects of ferroelectricity as presented by authorities in the field. Topics include relaxors, piezoelectrics, microscale and nanoscale studies, polymers and composites, unusual properties, and techniques and devices. The information in this book is intended for physicists, engineers and materials scientists working with ferroelectric materials including ceramics, single crystals, polymers, composites and even some biological materials.

  9. Savannah River Site's H-Canyon Facility: Impacts of Foreign Obligations on Special Nuclear Material Disposition

    International Nuclear Information System (INIS)

    Magoulas, Virginia

    2013-01-01

    The US has a non-proliferation policy to receive foreign and domestic research reactor returns of spent fuel materials of US origin. These spent fuel materials are returned to the Department of Energy (DOE) and placed in storage in the L-area spent fuel basin at the Savannah River Site (SRS). The foreign research reactor returns fall subject to the 123 agreements for peaceful cooperation. These ''123 agreements'' are named after section 123 of the Atomic Energy Act of 1954 and govern the conditions of nuclear cooperation with foreign partners. The SRS management of these foreign obligations while planning material disposition paths can be a challenge.

  10. New possibilities of the isotope distribution examination in irradiated absorbing materials using secondary ion mass spectrometry method

    International Nuclear Information System (INIS)

    Goncharenko, Y. D.; Evseev, L.A.; Risovany, V.D.

    2005-01-01

    The SIMS technique (with using a linear analysis and 2D surface imaging) has been to measure the radial distribution of the boron isotope ratio in the boron carbide pellets irradiated in the fast reactor. It was revealed that a radial distribution of isotope ratio in the boron carbide pellets is significantly different after irradiation in fast and thermal reactors. It was showed the advisability of using ion images for such examinations. (Author)

  11. Calcium isotopic anomalies in the Allende meteorite

    International Nuclear Information System (INIS)

    Lee, T.; Papanastassiou, D.A.; Wasserburg, G.J.

    1978-01-01

    We report isotopic anomalies in Ca which were found in two Ca-Al-rich inclusions of the Allende meteorite. These inclusions previously had been shown to contain special anomalies for Mg and O which were attributed to fractionation and unknown nuclear effects. The Ca data, when corrected for mass fractionation by using 40 Ca/ 44 Ca as a standard, show nonlinear isotopic effects in 48 Ca of +13.5 per mil and in 42 Ca of +1.7 per mil for one sample. The second sample shows a 48 Ca depletion of -2.9 per mil, but all other isotopes are normal. Samples with large excesses in 26 Mg show no Ca anomalies. The effects demonstrate that isotopic anomalies exist for higher-atomic-number refractory elements in solar-system materials and do not appear to be readily explainable by a simple model. The correlation of O, Mg, and Ca results on the same inclusions requires the addition and preservation in the solar system of components from idverse nucleosynthetic sources. Observed anomalous Mg and Ca compositions for coexisting mineral phases are uniform within each inclusion, and require initial isotopic homogeneity within an inclusion but the preservation of wide variations between inclusions. Assuming formation of these inclusions by condensation from a gaseous part of the solar nebula, this implies isotopic heterogeneity on a scale of 10-10 2 km within the nebula

  12. Field experimentation in isotope-aided studies

    International Nuclear Information System (INIS)

    Zapata, F.

    1990-01-01

    Isotopic-aided studies involve the application of isotopically labelled fertilizer as tracers for the quantitative and precise determination of the fate of specific nutrient elements in the soil/plant system. The planning of isotopic-aided studies requires a different approach from that followed in the design of normal fertilizer trials because of the cost and supply of isotopically labelled materials, the use of highly specialized equipment and the need for skillful trained staff in the use of isotope techniques both in the field/greenhouse and the laboratory. This report is intended to highlight the main points to be considered while applying those techniques in the field or greenhouse. It has been well established that nuclear techniques are a powerful tool in agricultural research. One should take advantage of the use of such techniques if the following criteria are met: The isotope method is the only way to solve a particular question or to obtain a specific piece of information. There are other methods available for such a purpose but the nuclear method provides a direct and quick means to obtain the needed information resulting in higher economic return

  13. Certification of methylmercury in cod fish tissue certified reference material by species-specific isotope dilution mass spectrometric analysis

    Energy Technology Data Exchange (ETDEWEB)

    Inagaki, Kazumi; Kuroiwa, Takayoshi; Narukawa, Tomohiro; Yarita, Takashi; Takatsu, Akiko; Okamoto, Kensaku; Chiba, Koichi [National Metrology Institute of Japan (NMIJ), National Institute of Advanced Industrial Science and Technology (AIST), Environmental Standard Section, Tsukuba, Ibaraki (Japan)

    2008-07-15

    A new cod fish tissue certified reference material, NMIJ CRM 7402-a, for methylmercury analysis was certified by the National Metrological Institute of Japan in the National Institute of Advanced Industrial Science and Technology (NMIJ/AIST). Cod fish was collected from the sea close to Japan. The cod muscle was powdered by freeze-pulverization and was placed into 600 glass bottles (10 g each), which were sterilized with {gamma}-ray irradiation. The certification was carried out using species-specific isotope dilution gas chromatography inductively coupled plasma mass spectrometry (SSID-GC-ICPMS), where {sup 202}Hg-enriched methylmercury (MeHg) was used as the spike compound. In order to avoid any possible analytical biases caused by nonquantitative extraction, degradation and/or formation of MeHg in sample preparations, two different extraction methods (KOH/methanol and HCl/methanol extractions) were performed, and one of these extraction methods utilized two different derivatization methods (ethylation and phenylation). A double ID method was adopted to minimize the uncertainty arising from the analyses. In order to ensure not only the reliability of the analytical results but also traceability to SI units, the standard solution of MeHg used for the reverse-ID was prepared from high-purity MeHg chloride and was carefully assayed as follows: the total mercury was determined by ID-ICPMS following aqua regia digestion, and the ratio of Hg as MeHg to the total Hg content was estimated by GC-ICPMS. The certified value given for MeHg is 0.58 {+-} 0.02 mg kg{sup -1} as Hg. (orig.)

  14. Elemental analysis of biological materials. Current problems and techniques with special reference to trace elements

    International Nuclear Information System (INIS)

    1980-01-01

    Selected techniques were reviewed for the assay of trace and minor elements in biological materials. Other relevant information is also presented on the need for such analyses, sampling, sample preparation and analytical quality control. In order to evaluate and compare the applicability of the various analytical techniques on a meaningful and objective basis, the materials chosen for consideration were intended to be typical of a wide range of biological matrics of different elemental compositions, namely Bowen's kale, representing a plant material, and NBS bovine liver, IAEA animal muscle, and blood serum, representing animal tissues. The subject is reviewed under the following headings: on the need for trace element analyses in the life sciences (4 papers); sampling and sample preparation for trace element analysis (2 papers); analytical techniques for trace and minor elements in biological materials (7 papers); analytical quality control (2 papers)

  15. Special quasirandom structures for gadolinia-doped ceria and related materials

    KAUST Repository

    Wang, Hao; Chroneos, Alexander I.; Jiang, Chao; Schwingenschlö gl, Udo

    2012-01-01

    cells describing 9% and 12% gadolinia doped ceria. These SQS cells are transferable and can be used to model related materials such as yttria stabilized zirconia. To demonstrate the applicability of the method we use density functional theory

  16. 76 FR 34273 - Environmental Assessment and Finding of No Significant Impact for Special Nuclear Material...

    Science.gov (United States)

    2011-06-13

    ... Nuclear Material, TVA applied for an SNM license by application dated November 12, 2009 (ML100120487). The..., including site geography, demographics, meteorology, hydrology, and geology. The proposed activity is...

  17. Assessing Worker Exposures during Composite Material and Fiberglass Repair: A Special

    Science.gov (United States)

    2015-01-01

    OEEL, without regard to the use of respirators, shall have shower facilities or other suitable decontamination available [32]. 6.4.2 Dust Removal...use mechanically fastened aluminum or stainless steel patches to repair composite material damage, or repair the composite material damage using...world CBRN environment. If the vacuum mechanism of ventilated tools becomes contaminated with radioactive particulates or chemical/biological agents

  18. Cataloguing outside the box a practical guide to cataloguing special collections materials

    CERN Document Server

    Falk, Patricia

    2010-01-01

    A practical guide to cataloguing and processing the unique special collections formats in the Browne Popular Culture Library (BPCL) and the Music Library and Sound Recordings Archives (MLSRA) at Bowling Green State University (BGSU) (e.g. fanzines, popular sound recordings, comic books, motion picture scripts and press kits, popular fiction). Cataloguing Outside the Box provides guidance to professionals in library and information science facing the same cataloguing challenges. Additionally, name authority work for these collections is addressed.provides practical guidelines and solutions for

  19. Data quality objectives for moisture measurement in stabilized special nuclear material

    International Nuclear Information System (INIS)

    Weier, D.R.; Pulsipher, B.A.; Silvers, K.L.

    2000-01-01

    Data Quality Objectives methodology is applied to Loss-on-Ignition (LOI) moisture content testing for stabilized nuclear materials. This work was performed by Pacific Northwest National Laboratory in support of the Plutonium Finishing Plant (PFP)/Fluor Hanford, Inc. Historical results on LOI test results for two material types, oxide and sludge, are used to estimate within container variability. This variability estimate is then used in formulating the two recommended acceptance criteria for containers of material. The criteria which follow are proposed to replace the current criterion, which requires recycle if either of two container LOI measurements exceed 0.5 wt%, the DOE Standard 3013-99 threshold value. (1) The 95% upper confidence limit (UCL) for the true mean underlying moisture content in the container material should be less than 0.5 wt%. (2) The difference between the two LOI measurements per container should not exceed their expected 95th percentile relative to the estimated variability. Containers not meeting the first criterion, or those that generate in any negative LOI result, require material recycle. Containers not meeting the second criteria require review of the measurement results, potentially leading to resampling and retesting. Data from Los Alamos National Laboratory studies on moisture testing are obtained and analyzed. The performance of Supercritical Fluid Extraction (SFE), which will soon be implemented at the PFP, is described for several material types. This information will be used to establish initial acceptance criteria when SFE comes on line

  20. Catalog of NBS standard reference materials, 1975--76 edition. Special pub

    International Nuclear Information System (INIS)

    Seward, R.W.

    1975-06-01

    This Catalog lists and describes the Standard Reference Materials (SRM's), Research Materials (RM's), and General Materials (GM's) currently distributed by the National Bureau of Standards, as well as many of the materials currently in preparation. SRM's are used to calibrate measurement systems and to provide a central basis for uniformity and accuracy of measurement. The unit and quantity, the type, and the certified characterization are listed for each SRM, as well as directions for ordering. The RM's are not certified, but are issued to meet the needs of scientists engaged in materials research. RM's are issued with a 'Report of Investigation', the sole authority of which is the author of the report. The GM's are standardized by some agency other than NBS. NBS acts only as a distribution point and does not participate in the standardization of these materials. Announcements of new and renewal SRM's, RM's and GM's are made in the semi-annual supplements of this Catalog, SRM Price List, and in scientific and trade journals

  1. Finding of no significant impact. Consolidation and interim storage of special nuclear material at Rocky Flats Environmental Technology Site

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-06-01

    The Department of Energy (DOE) has prepared an environmental assessment (EA), DOE/EA -- 1060, for the consolidation, processing, and interim storage of Category I and II special nuclear material (SNM) in Building 371 at the Rocky Flats Environmental Technology Site (hereinafter referred to as Rocky Flats or Site), Golden, Colorado. The scope of the EA included alternatives for interim storage including the no action alternative, the construction of a new facility for interim storage at Rocky Flats, and shipment to other DOE facilities for interim storage.

  2. Finding of no significant impact. Consolidation and interim storage of special nuclear material at Rocky Flats Environmental Technology Site

    International Nuclear Information System (INIS)

    1995-06-01

    The Department of Energy (DOE) has prepared an environmental assessment (EA), DOE/EA -- 1060, for the consolidation, processing, and interim storage of Category I and II special nuclear material (SNM) in Building 371 at the Rocky Flats Environmental Technology Site (hereinafter referred to as Rocky Flats or Site), Golden, Colorado. The scope of the EA included alternatives for interim storage including the no action alternative, the construction of a new facility for interim storage at Rocky Flats, and shipment to other DOE facilities for interim storage

  3. Far infrared conductivity of charge density wave materials and the oxygen isotope effect in high-T sub c superconductors

    Energy Technology Data Exchange (ETDEWEB)

    Creager, W.N.

    1991-09-01

    The far infrared reflectance and conductivity of (Ta{sub 1-x}Nb{sub x}Se{sub 4}){sub 2}I and TaS{sub 3} have been measured to determine the origin of a huge infrared resonance that dominates the charge density wave (CDW) dynamics along with the pinned acoustic phason mode in the related materials (TaSe{sub 4}){sub 2}I and K{sub 0. 3}MoO{sub 3}. The measurements cover frequencies from 3 to 700cm{sup {minus}1} and the temperature range from 15K to 300K. In the niobium-doped alloys (Ta{sub 1-x}Nb{sub x}Se{sub 4}){sub 2}I, the size and frequency of the giant infrared mode remain nearly constant as the impurity concentration x is increased. For TaS{sub 3}, the pinned acoustic phason near 0.5cm{sup {minus}1} dominates {var epsilon}({omega}) and an additional small mode lies near 9cm{sup {minus}1}. The latter mode is much smaller than the infrared mode in other CDW materials. These results rule out several models of a generic infrared mode'' in CDW excitations. They are compared in detail to the predictions of a recent theory attributing the infrared mode to a bound collective mode localized at impurity sites within the crystal. The transmittance of K{sub 0.3}MoO{sub 3} has been measured at 1.2K with a strong dc electric field applied across the crystal. Under these conditions, the charge density wave depins abruptly and carries large currents with near-zero differential resistance. For some samples, the low-frequency transmittance is enhanced slightly when the CDW depins. The magnitude of the oxygen isotope effect in the high-{Tc} superconductor YBa{sub 2}Cu{sub 3}O{sub 7} has been determined by substitution of {sup 18}O for {sup 16}O. A series of cross-exchanges was performed on high-quality polycrystalline specimens to eliminate uncertainties due to sample heat treatments and sample inhomogeneities.

  4. Thematic network on the analysis of thorium and its isotopes in workplace materials. Report on the 2nd intercomparison exercise

    International Nuclear Information System (INIS)

    Howe, A.; White, M.

    2000-12-01

    Work Package 2 (WP 2) of the EC Thematic Network on ''The analysis of thorium and its isotopes in workplace materials'' is concerned with ''Examination and comparison of analytical techniques for the determination of thorium and its progeny in bulk materials and the development of standards, both for the calibration of associated metrological facilities, and for routine quality control purposes''. The primary objective of WP 2 is ''To evaluate appropriate techniques and determine best practice for analysis of 232 Th at workplace levels and environments'', and is to be achieved through a series of intercomparison exercises. Following the results of the 1st intercomparison exercise, a 2nd intercomparison exercise was designed to evaluate the capability of the analytical methods currently being used by European laboratories to determine thorium at very low levels in the presence of a complex inorganic matrix. The intercomparison exercise involved the analysis of three samples of thorium in solution, prepared by the United Kingdom National Physical Laboratory. One sample was the equilibrium solution, analysed in the 1st intercomparison exercise. The other two samples were prepared by dilution of a non-equilibrium thorium solution, one of which was spiked with impurity elements. (i) The results showed a further improvement in the accuracy of measurements in the equilibrium solution, when compared with the results from the 1st intercomparison study. There was an overall drop in u-test values and the number of u-test values above the upper limit of significance fell from 6 to 3. (ii) Overall, participating laboratories also performed well in the analysis of the low level non-equilibrium solutions. However, several laboratories using y-spectrometry had insufficient sensitivity for measurement of low level non-equilibrium sample solutions and did not report results. (iii) There was little evidence that the presence of impurities had a detrimental effect on measurements made

  5. Special Features of Using Secondary Materials in the Interior Design of Public Dining Establishments

    Science.gov (United States)

    Kuznetsova, Irina; Hapchuk, Olena; Lukinov, Vitaly

    2017-10-01

    This article analyses the latest publications studying the use and practical application of secondary resources as raw materials in design. This analysis is based on the list of secondary resources and their applications in interior decoration. In particular, the interiors of public catering enterprises were analysed. Restaurants with different functional purposes that were classified into several categories with specific peculiarities of interior design were identified. This article presents and describes different types of public catering enterprises based on those categories. The interior design of a public catering enterprise is regarded as a considerably complex system. Different types of secondary materials were reviewed to identify the most frequently used materials for interior space design. This article describes the main peculiarities of the use of secondary materials and presents examples of their practical application. The function of secondary materials in the interior design of public catering enterprises were detected and reviewed. On the basis of the analysis, several directions for the practical application of our results in the field of public catering enterprise design were suggested.

  6. Use of 15N in nitrification inhibitor studies with special reference to indigenous materials

    International Nuclear Information System (INIS)

    Sahrawat, K.L.

    1988-01-01

    Non-edible oil seed cakes and their constituents have been advantageously used for increasing the efficiency of fertilizer nitrogen (N) for crop production. The beneficial effects of these materials have been attributed to retardation of nitrification, which lessen the loss of N associated with nitrification by leaching and denitrification in situations where these losses are high. However, it is possible that some of the effects of these materials could be due to immobilization-remineralization of N particularly when the carbonaceous materials are added with fertilizers at high rates. A methodology involving the use of 15 N-labelled fertilizers is advanced to sort out whether the beneficial effects of non-edible oil seed cakes and other materials are due to retardation of nitrification and or immobilization-remineralization of fertilizer N. Using the proposed technique it would be possible to make realistic evaluation of the wealth of indigenous products as nitrification inhibitors. Following the proposed approach it would also be possible to widen the scope and depth of research in this area for ultimately better exploitation of indigenous materials as nitrification inhibitors. (author). 18 refs

  7. The transport of radioactive materials, paying special attention to nuclear fuels

    International Nuclear Information System (INIS)

    Blechschmidt, M.

    1977-06-01

    The transport of radioactive materials, particularly within the nuclear fuel cycle, is of increasing importance, and is more than ever a matter of public debate. This report provides information concerning the necessary physical, technical and administrative precautions which must be taken to ensure protection of the environment. The international standard of requirements for the packing of the materials is emphasized, as in many cases, transports cross national borders. The relatively comprehensive list of references can be used for the study of details. (orig.) [de

  8. Selfwelding, friction and wear behaviour of special materials in sodium under corroding conditions

    International Nuclear Information System (INIS)

    Borgstedt, H.U.; Mattes, K.; Wild, E.

    1975-11-01

    Control rod guides and fuel element duct load pads have to be fabricated from materials exhibiting optimum slide behaviour. Galling or self-welding under static conditions should not be tolerated. Given bearing clearances have to be maintained constant and loop contamination, caused by wear particles, have to be prevented. Since high friction between contacting pads may impose severe limitations on core compaction, for the duct load pads a maximum friction coefficient of 0.5 is acceptable. The effect of sodium corrosion should not impair the friction and wear behaviour of the materials applied. This report covers the work performed to optain appropriate mechanical design data. (orig.) [de

  9. Single access laparoscopic cholecystectomy: technique without the need for special materials and with better ergonomics

    Directory of Open Access Journals (Sweden)

    Marco Aurélio Lameirão Pinto

    Full Text Available The authors describe a surgical technique which allows, without increasing costs, to perform laparoscopic cholecystectomy with a single incision, without using specific materials and with better surgical ergonomics. The technique consists of a longitudinal umbilical incision, navel detachment, use of a permanent 10mm trocar and two clamps directly and bilaterally through the aponeurosis without the use of 5mm trocars, transcutaneous gallbladder repair with straight needle cotton suture, ligation with unabsorbable suture and umbilical incision for the specimen extraction. The presented technique enables the procedure with conventional and permanent materials, improving surgical ergonomics, with safety and aesthetic advantages.

  10. Semi-annual report on strategic special nuclear material inventory differences

    International Nuclear Information System (INIS)

    1981-01-01

    This report provides and explains the differences between the amounts of nuclear materials charged to DOE facilities and the amounts that could be physically inventoried. This report covers data for the period from October 1, 1979, through March 31, 1980, and includes accounting corrections for data from earlier periods. It is the seventh such semiannual report. These data and explanations, together with the absences of physical indications of any theft attempt, support a finding that during this period no theft or diversion of strategic spcial nuclear material has occurred

  11. Special training for drivers of vehicles carrying radioactive materials in Germany

    International Nuclear Information System (INIS)

    Ridder, K.

    1992-01-01

    No rule, not even the best, serves its purpose if it is not complied with just because it is not known. In Europe, and in Germany particularly, this has been accepted wisdom for 12 years. With respect to the greater risk emanating form tank-vehicles, and in the aftermath of a tank-vehicle accident due to the driver's error in Spain 1987 (Los Alfaques) that killed more than 200 persons, tank-vehicle drivers had to undergo special training since midyear 1991. Training is organised in a modular system, which means that the driver can customise his dangerous goods training programme by combining several modules. The contents of the training programme, its organisation and supervision as well as the means for checking the successful completion of the programme are shown. (Author)

  12. Executive summary of the special safeguards study on material control and accounting systems. Final report

    International Nuclear Information System (INIS)

    1975-01-01

    This report assesses the feasibility of real-time systems applied to mixed-oxide fuel rod fabrication. Their interaction with other material control and accounting measures are considered. Economics, effectiveness, and acceptance factors are discussed. A cost-benefit evaluation is made and recommendations given for safeguards improvements

  13. 75 FR 45195 - Office of Hazardous Materials Safety; Notice of Applications for Modification of Special Permit

    Science.gov (United States)

    2010-08-02

    ... permits (e.g. to provide for additional hazardous materials, packaging design changes, additional mode of... compressed oxygen without rigid outer packaging when no other means of transportation exist. 14860-M Alaska... authorizing the transportation in commerce of compressed oxygen without rigid outer packaging when no other...

  14. 75 FR 42364 - Hazardous Materials: Incorporation of Certain Cargo Tank Special Permits Into Regulations

    Science.gov (United States)

    2010-07-21

    .... Moveable fuel storage tenders are used to supply LPG fuel to farmers for crop drying, crop irrigation... vegetables, fruits, and ornamentals. Control of soil- borne pests increases plant aesthetics, plant quality... liquid lacquer base. Paint related material including paint 3 UN1263 II thinning drying, removing, or...

  15. 77 FR 22362 - Exemption Requests for Special Nuclear Material License SNM-362, Department of Commerce...

    Science.gov (United States)

    2012-04-13

    ... Nuclear Material License SNM-362, Department of Commerce, Gaithersburg, MD AGENCY: Nuclear Regulatory... Commerce, National Institutes of Standards and Technology (NIST) in Gaithersburg, Maryland. NIST requested... within the Department of Commerce. The SNM license was renewed in 1979, 1985, 1991, and 1997. The current...

  16. United States Department of Energy Office of Nuclear Energy, Isotope Production and Distribution Program financial statements, September 30, 1996 and 1995

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-04-01

    The charter of the Department of Energy (DOE) Isotope Production and Distribution Program (Isotope Program) covers the production and sale of radioactive and stable isotopes, associated byproducts, surplus materials such as lithium, and related isotope services. Service provided include, but are not limited to, irradiation services, target preparation and processing, source encapsulation and other special preparations, analyses, chemical separations, and leasing of stable isotopes for research purposes. Isotope Program products and services are sold worldwide for use in a wide variety of research, development, biomedical, and industrial applications. This report presents the results of the independent certified public accountants` audit of the Isotope Production and Distribution Program`s (Isotope) financial statements as of September 30, 1996.

  17. Department of Energy (DOE) system for the transportation of strategic quantities of special nuclear material (SQ SNM)

    International Nuclear Information System (INIS)

    Dickason, D.P.

    1978-01-01

    Since 1947 DOE and its predecessor agencies, AEC and ERDA, have moved nuclear materials by a variety of commercial and government transportation modes. In the late 1960's world-wide terrorism and other dissident activities prompted the then-AEC to review its procedures for safeguarding SNM. These reviews resulted in immediate and long-range programs for improvement of overall safeguards. Domestic transportation of completed nuclear weapons and SNM used in the weapons program was selected for special consideration. In the early 1970's AEC started the development of a Safe Secure Trailer (SST) to transport nuclear weapons and nuclear components and the development and installation of a high frequency (HF) communications system to assure continuous radio contact between selected highway and rail shipments and Headquarters, Albuquerque Operations (ALO). Late 1974 AEC directed ALO to develop a transportation system to extend weapons-level protection to all AEC SQ SNM shipments and to consolidate, manage, and operate this system. As of September 1976 all SQ SNM was being transported in the Safe Secure DOE (then ERDA) transportation safeguards system, composed of the following principal elements: (1) Transport equipment consisting of Safe Secure Trailers and specially modified towing tractors; Safe Secure Railcars and specially modified escort coaches; and specially designed highway escort vehicles. (2) An automated high-frequency digital radio system that enables continuous communications between the transporting equipment and central control. (3) A courier force that operates all transport equipment (except aircraft and rail power units) and mobile communications equipment; provides armed protection for shipments; and assures proper safety en route. (4) A central Headquarters staff that plans, executes, and controls shipments and directs, manages, and operates the system

  18. Application and evaluation of the mass spectrometric isotope dilution technique in the determination of rare earths in geological materials

    International Nuclear Information System (INIS)

    Moraes, N.M.P. de.

    1988-01-01

    Establishment of the experimental procedures employed in the rare earth element determination of geological samples by mass spectrometric isotope dilution analysis is discussed in the present work. The procedures involve preparation and calibration of the isotope tracers isotope dilution, dissolution in a teflon pressure vessel, chemical separation and isotope analysis using a fully automated Micromass VG ISOTOPES model 354 thermal ionization mass spectrometer. For the initial chemical separation of total rare earths the cationic resin was employed and HC1 and HNO 3 acids as eluents. In the second step rare earths elements were separated into individual (La, Ce and Nd) and subgroups (Sm-Eu-Gd, Yb-Er-Dy) fractions using the same cationic resin and α-HIBA as eluent. Nine elements La, Ce, Nd, Sm, Eu, Gd, Dy, Er and Yb are determined by this method in the ''United States Geological Survey'' (USGS) standard samples GSP-1, AGV-1 and G-2, with an overall precision of +- 1 to 2% and an accuracy of 5%. The concentration of rare earth element determined in the standard sample PCC-1 showed that the total analytical blanks are in submicrogram levels. The concentration of rare earth elements in the same USGS standard samples were also determined by Instrumental neutron activation analysis, neutron activation analysis with chemical separation before irradiation and inductively coupled argon plasma spectroscopy. The chemical procedures employed for these methods are the same as that used for mass spectrometric isotope dilution. Based on the results obtained, each method was evaluated pointing out their merits and defects. The study clearly showed that the chemical procedure employed for all these techniques was satisfactory. (author) [pt

  19. Special Issue: Adaptive/Smart Structures and Multifunctional Materials with Application to Morphing Aircraft

    Directory of Open Access Journals (Sweden)

    Rafic Ajaj

    2014-12-01

    Full Text Available Recent advances in smart structures and multifunctional materials have facilitated many novel aerospace technologies such as morphing aircraft. A morphing aircraft, bio-inspired by natural fliers, has gained a lot of interest as a potential technology to meet the ambitious goals of the Advisory Council for Aeronautics Research in Europe (ACARE Vision 2020 and the FlightPath 2050 documents. A morphing aircraft continuously adjusts its wing geometry to enhance flight performance, control authority, and multi-mission capability.[...

  20. Astrophysical implications of extraterrestrial materials: A special issue for Ernst K. Zinner

    Science.gov (United States)

    Nittler, Larry R.

    2018-01-01

    This special issue is dedicated to the memory of Dr. Ernst K. Zinner (Fig. 1). Dr. Zinner (1937-2015) was a pioneer in the use of Secondary Ion Mass Spectrometry (SIMS) in geo- and cosmochemistry. His contributions to science were vast, but in addition to his foundational SIMS development work, he is best known for the discovery and detailed characterization of presolar stardust grains in meteorites. This discovery opened up important new connections between astrophysics and meteoritical research and this is the overarching theme of this issue. Throughout his career, Ernst was a teacher, mentor, friend, and generous collaborator to legions of scientists. This issue presents research by many who were taught by, inspired by, and/or collaborated with this innovative cosmochemist and astrophysicist. In addition to the author, Ernst's former students and collaborators Drs. Christine Floss (Washington University) Peter Hoppe (MPI for chemistry, Mainz, Germany), and Kevin McKeegan (University of California, Los Angeles) served as Guest Editors for this issue.

  1. Isotope separation process

    International Nuclear Information System (INIS)

    1976-01-01

    The invention relates to a process for separating a given material into two or more parts, in each of which the abundances of the isotopes of a given element differ from the abundances of the isotopes of the same material in the said material. More particularly, the invention relates to a method for the isotopically selective excitation of gas phase UF 6 by infrared photon absorption followed by selective reaction of said excited UF 6 with atomic chlorine, bromine, or iodine to form a product which may be separated by means known in the art

  2. Standard test method for analysis of isotopic composition of uranium in nuclear-grade fuel material by quadrupole inductively coupled plasma-mass spectrometry

    CERN Document Server

    American Society for Testing and Materials. Philadelphia

    2000-01-01

    1.1 This test method is applicable to the determination of the isotopic composition of uranium (U) in nuclear-grade fuel material. The following isotopic weight percentages are determined using a quadrupole inductively coupled plasma-mass spectrometer (Q-ICP-MS): 233U, 234U, 235U, 236U, and 238U. The analysis can be performed on various material matrices after acid dissolution and sample dilution into water or dilute nitric (HNO3) acid. These materials include: fuel product, uranium oxide, uranium oxide alloys, uranyl nitrate (UNH) crystals, and solutions. The sample preparation discussed in this test method focuses on fuel product material but may be used for uranium oxide or a uranium oxide alloy. Other preparation techniques may be used and some references are given. Purification of the uranium by anion-exchange extraction is not required for this test method, as it is required by other test methods such as radiochemistry and thermal ionization mass spectroscopy (TIMS). This test method is also described i...

  3. ONE YEAR'S EXPERIENCE IN REGULATING BYPRODUCT, SOURCE, AND SPECIAL NUCLEAR MATERIAL IN THE COMMONWEALTH OF KENTUCKY

    Energy Technology Data Exchange (ETDEWEB)

    Weaver, C L

    1963-06-15

    On March 26, 1962, Kentucky assumed regulatory control for the licensing of subcritical nuclear materials within its boundaries. The administration of the state radiological health program is described, and the manpower, fiscal, and equipment requirements are outlined. The licensing activity of the state is also described. Results are reported of preliminary studies of state-owned land for low-level radioactive waste disposal. The procedures for inspection of licensees are described. Proposed changes in the Radiological Health regulations of Kentucky in order to bring about compatibility with AEC's code of Federal Regulations are outlined. (D.L.C.)

  4. Standard practice for sampling special nuclear materials in multi-container lots

    CERN Document Server

    American Society for Testing and Materials. Philadelphia

    1987-01-01

    1.1 This practice provides an aid in designing a sampling and analysis plan for the purpose of minimizing random error in the measurement of the amount of nuclear material in a lot consisting of several containers. The problem addressed is the selection of the number of containers to be sampled, the number of samples to be taken from each sampled container, and the number of aliquot analyses to be performed on each sample. 1.2 This practice provides examples for application as well as the necessary development for understanding the statistics involved. The uniqueness of most situations does not allow presentation of step-by-step procedures for designing sampling plans. It is recommended that a statistician experienced in materials sampling be consulted when developing such plans. 1.3 The values stated in SI units are to be regarded as the standard. 1.4 This standard does not purport to address all of the safety problems, if any, associated with its use. It is the responsibility of the user of this standar...

  5. Achievements in testing of the MGA and FRAM isotopic software codes under the DOE/NNSA-IRSN cooperation of gamma-ray isotopic measurement systems

    International Nuclear Information System (INIS)

    Vo, Duc; Wang, Tzu-Fang; Funk, Pierre; Weber, Anne-Laure; Pepin, Nicolas; Karcher, Anna

    2009-01-01

    DOE/NNSA and IRSN collaborated on a study of gamma-ray instruments and analysis methods used to perform isotopic measurements of special nuclear materials. The two agencies agreed to collaborate on the project in response to inconsistencies that were found in the various versions of software and hardware used to determine the isotopic abundances of uranium and plutonium. IRSN used software developed internally to test the MGA and FRAM isotopic analysis codes for criteria used to stop data acquisition. The stop-criterion test revealed several unusual behaviors in both the MGA and FRAM software codes.

  6. A Special Material or a New State of Matter: A Review and Reconsideration of the Aerogel

    Directory of Open Access Journals (Sweden)

    Jun Shen

    2013-03-01

    Full Text Available The ultrahighly nanoporous aerogel is recognized as a state of matter rather than as a functional material, because of its qualitative differences in bulk properties, transitional density and enthalpy between liquid and gas, and diverse chemical compositions. In this review, the characteristics, classification, history and preparation of the aerogel were introduced. More attention was paid to the sol-gel method for preparing different kinds of aerogels, given its important role on bridging the synthetic parameters with the properties. At last, preparation of a novel single-component aerogel, design of a composite aerogel and industrial application of the aerogel were regarded as the research tendency of the aerogel state in the near future.

  7. The ''nuclear car wash'': a scanner to detect illicit special nuclear material in cargo containers

    International Nuclear Information System (INIS)

    Slaughter, D. R.; Accatino, M. R.; Bernstein, A.; Dougan, A. D.; Hall, J. M.; Loshak, A.; Manatt, D. R.; Pohl, B. A.; Prussin, S. G.; Walling, R. S.; Weirup, D. L.

    2004-01-01

    There is an urgent need to improve the reliability of screening cargo containers for illicit nuclear material that may be hidden there for terrorist purposes. A screening system is described for detection of fissionable material hidden in maritime cargo containers. The system makes use of a low intensity neutron beam for producing fission; and the detection of the abundant high-energy γ rays emitted in the β-decay of short-lived fission products and β-delayed neutrons. The abundance of the delayed γ rays is almost an order of magnitude larger than that of the delayed neutrons normally used to detect fission and they are emitted on about the same time scale as the delayed neutrons, i.e., ∼1 min. The energy and temporal distributions of the delayed γ rays provide a unique signature of fission. Because of their high energy, these delayed γ rays penetrate loW--Z cargoes much more readily than the delayed neutrons. Coupled with their higher abundance, the signal from the delayed γ rays escaping from the container is predicted to be as much as six decades more intense than the delayed neutron signal, depending upon the type and thickness of the intervening cargo. The γ rays are detected in a large array of scintillators located along the sides of the container as it is moved through them. Measurements have confirmed the signal strength in somewhat idealized experiments and have also identified one interference when 14.5 MeV neutrons from the D, T reaction are used for the interrogation. The interference can be removed easily by the appropriate choice of the neutron source

  8. New biotite and muscovite isotopic reference materials, USGS57 and USGS58, for δ2H measurements–A replacement for NBS 30

    Science.gov (United States)

    Qi, Haiping; Coplen, Tyler B.; Gehre, Matthias; Vennemann, Torsten W.; Brand, Willi A.; Geilmann, Heike; Olack, Gerard; Bindeman, Ilya N.; Palandri, Jim; Huang, Li; Longstaffe, Fred J.

    2017-01-01

    The advent of continuous-flow isotope-ratio mass spectrometry (CF-IRMS) coupled with a high temperature conversion (HTC) system enabled faster, more cost effective, and more precise δ2H analysis of hydrogen-bearing solids. Accurate hydrogen isotopic analysis by on-line or off-line techniques requires appropriate isotopic reference materials (RMs). A strategy of two-point calibrations spanning δ2H range of the unknowns using two RMs is recommended. Unfortunately, the supply of the previously widely used isotopic RM, NBS 30 biotite, is exhausted. In addition, recent measurements have shown that the determination of δ2H values of NBS 30 biotite on the VSMOW-SLAP isotope-delta scale by on-line HTC systems with CF-IRMS may be unreliable because hydrogen in this biotite may not be converted quantitatively to molecular hydrogen. The δ2HVSMOW-SLAP values of NBS 30 biotite analyzed by on-line HTC systems can be as much as 21 mUr (or ‰) too positive compared to the accepted value of − 65.7 mUr, determined by only a few conventional off-line measurements. To ensure accurate and traceable on-line hydrogen isotope-ratio determinations in mineral samples, we here propose two isotopically homogeneous, hydrous mineral RMs with well-characterized isotope-ratio values, which are urgently needed. The U.S. Geological Survey (USGS) has prepared two such RMs, USGS57 biotite and USGS58 muscovite. The δ2H values were determined by both glassy carbon-based on-line conversion and chromium-based on-line conversion, and results were confirmed by off-line conversion. The quantitative conversion of hydrogen from the two RMs using the on-line HTC method was carefully evaluated in this study. The isotopic compositions of these new RMs with 1-σ uncertainties and mass fractions of hydrogen are:USGS57 (biotite)δ2HVSMOW-SLAP = − 91.5 ± 2.4 mUr (n = 24)Mass fraction hydrogen = 0.416 ± 0.002% (n = 4)Mass fraction water = 3.74 ± 0.02% (n = 4)USGS58 (muscovite

  9. The Study on the analysis of the revised regulation on the special nuclear materials

    International Nuclear Information System (INIS)

    Ahn, Seung Ho; Koh, Byung Marn; Kim, Ki Hyun

    2015-01-01

    In accordance with successful implementation of the IS in the ROK, the IAEA request the enhanced partnership between the ROK and the IAEA to increase the role of the SSAC(State System of Accounting for and Control of nuclear material) in the ROK. For this reason, the ROK and the IAEA signed the EC(Enhanced Cooperation) arrangement to expand the cooperation area beyond existing LWR enhanced cooperation. The IAEA set up it the one of the EC's objectives to increase the practical use and enhancement of the SSAC. In 2013, the NSSC(Nuclear Safety and Security Committee) formed task force team which included the TSO(Technical Support Organization) staffs and operators to establish scope, object and role of the SSAC for improving it. The improvement of the state safeguards system envisioned in the amendment to the notification is intended to ensure the integrity of the state safeguards with the agreement reached with the IAEA to enhance cooperation, enable facility operators to ensure compliance with their obligatory requirements without assuming unnecessarily duplicate administrative workload, and eliminate unreasonableness of the state accounting and control inspection

  10. Using natural local materials for developing special radiation shielding concretes, and deduction of its shielding characteristics

    International Nuclear Information System (INIS)

    Kharita, M. H.; Takeyeddin, M.; Al-Nassar, M.; Yousef, S.

    2006-06-01

    Concrete is considered as the most important material to be used for radiation shielding in facilities contain radioactive sources and radiation generating machines. The concrete shielding properties may vary depending on the construction of the concrete, which is highly relative to the composing aggregates i.e. aggregates consist about 70 - 80% of the total weight of normal concrete. In this project tow types of concrete used in Syria (in Damascus and Aleppo) had been studied and their shielding properties were defined for gamma ray from Cs-137 and Co-60 sources, and for neutrons from Am-Be source. About 10% reduction in HVL was found in the comparison between the tow concrete types for both neutrons and gammas. Some other types of concrete were studied using aggregates from different regions in Syria, to improve the shielding properties of concrete, and another 10% of reduction was achieved in comparison with Damascene concrete (20% in comparison with the concrete from Aleppo) for both neutrons and gamma rays. (author)

  11. The Study on the analysis of the revised regulation on the special nuclear materials

    Energy Technology Data Exchange (ETDEWEB)

    Ahn, Seung Ho; Koh, Byung Marn; Kim, Ki Hyun [Korea Institute of Nuclear Non-proliferation and Control, Daejeon (Korea, Republic of)

    2015-05-15

    In accordance with successful implementation of the IS in the ROK, the IAEA request the enhanced partnership between the ROK and the IAEA to increase the role of the SSAC(State System of Accounting for and Control of nuclear material) in the ROK. For this reason, the ROK and the IAEA signed the EC(Enhanced Cooperation) arrangement to expand the cooperation area beyond existing LWR enhanced cooperation. The IAEA set up it the one of the EC's objectives to increase the practical use and enhancement of the SSAC. In 2013, the NSSC(Nuclear Safety and Security Committee) formed task force team which included the TSO(Technical Support Organization) staffs and operators to establish scope, object and role of the SSAC for improving it. The improvement of the state safeguards system envisioned in the amendment to the notification is intended to ensure the integrity of the state safeguards with the agreement reached with the IAEA to enhance cooperation, enable facility operators to ensure compliance with their obligatory requirements without assuming unnecessarily duplicate administrative workload, and eliminate unreasonableness of the state accounting and control inspection.

  12. Availability of special local rock materials for using in radiation shielding concrete

    International Nuclear Information System (INIS)

    Rammah, S.; Al-Hent, R.; Aissa, M.; Yousef, S.

    2003-11-01

    Concrete is an excellent and versatile material for using in radiation shielding of nuclear power plants, hot cells and medical facilities that deal with ionizing radiations, Because it is easy controlled with composition and density by using aggregates with high specific gravity such as Barite, Hematite, Magnetite, or minerals with high hydrogen content such as Serpentine. This research offered the essential information about local resources rocks and minerals can be used in this inclination, as aggregates for heavy/high hydrion concrete. The present work indicates that iron ores, which located in RAJO-EFREEN is better than other locations like ANTI-LEBANON or AL-KADMOUS. While the heavy beach sands in AL-BASSIT are the best compared with other locations on the Syrian seaside, because it has acceptable percentage of heavy mineral. Barite concretions were found in KALAMON, HOMS and other sites, which its percentages approach 50%, but however in small quantities. Finally, high hydrion concrete can be used by Serpentinite were found with high Serpentine percentage in BAYER and BASSIT blocks. (author)

  13. Technological physics and special materials: wood-plastic composites obtained by radiation polymerization

    International Nuclear Information System (INIS)

    Peteu, Gh.; Iliescu, V.

    1995-01-01

    General estimates and references are made in connection with the role of technological physics in obtaining materials with specific features. The first part of the paper presents the modification of weak wood essences as well as technological processes at bench-scale and semi industrial scale of wood-plastic composites, under various irradiation conditions. Two technological installations for the fabrication of wood-plastic composites on both scales with technical and practical specifications of their performances are presented. Experimental data for different wood-plastic composite systems using some local wood essences in combination with several polymer and copolymer systems are given. Impregnation and polymerization levels are mentioned for every specific system. The radiation dose rate and integrated dose are given for every experimental polymerization system. The features of the wood-plastic composites are compared with the initial wood essences. Finally, a few technical and economic assessments of wood-plastic composites and their implications in the domestic economy are presented. (author)

  14. Isotope dilution inductively coupled plasma mass spectrometry (ID ICP-MS) for the certification of lead and cadmium in environmental standard reference materials.

    Science.gov (United States)

    Murphy, K E; Beary, E S; Rearick, M S; Vocke, R D

    2000-10-01

    Lead (Pb) and cadmium (Cd) have been determined in six new environmental standard reference materials (SRMs) using isotope dilution inductively coupled plasma mass spectrometry (ID ICP-MS). The SRMs are the following: SRM 1944, New York-New Jersey Waterway Sediment, SRMs 2583 and 2584, Trace Elements in Indoor Dust, Nominal 90 mg/kg and 10,000 mg/kg Lead, respectively, SRMs 2586 and 2587, Trace Elements in Soil Containing Lead from Paint, Nominal 500 mg/kg and 3,000 mg/kg Lead, respectively, and SRM 2782, Industrial Sludge. The capabilities of ID ICP-MS for the certification of Pb and Cd in these materials are assessed. Sample preparation and ratio measurement uncertainties have been evaluated. Reproducibility and accuracy of the established procedures are demonstrated by determination of gravimetrically prepared primary standard solutions and by comparison with isotope dilution thermal ionization mass spectrometry (ID TIMS). Material heterogeneity was readily demonstrated to be the dominant source of uncertainty in the certified values.

  15. Increasing the Accuracy in the Measurement of the Minor Isotopes of Uranium: Care in Selection of Reference Materials, Baselines and Detector Calibration

    Science.gov (United States)

    Poths, J.; Koepf, A.; Boulyga, S. F.

    2008-12-01

    The minor isotopes of uranium (U-233, U-234, U-236) are increasingly useful for tracing a variety of processes: movement of anthropogenic nuclides in the environment (ref 1), sources of uranium ores (ref 2), and nuclear material attribution (ref 3). We report on improved accuracy for U-234/238 and U-236/238 by supplementing total evaporation protocol TIMS measurement on Faraday detectors (ref 4)with multiplier measurement for the minor isotopes. Measurement of small signals on Faraday detectors alone is limited by noise floors of the amplifiers and accurate measurement of the baseline offsets. The combined detector approach improves the reproducibility to better than ±1% (relative) for the U-234/238 at natural abundance, and yields a detection limit for U-236/U-238 of <0.2 ppm. We have quantified contribution of different factors to the uncertainties associated with these peak jumping measurement on a single detector, with an aim of further improvement. The uncertainties in the certified values for U-234 and U-236 in the uranium standard NBS U005, if used for mass bias correction, dominates the uncertainty in their isotopic ratio measurements. Software limitations in baseline measurement drives the detection limit for the U-236/U-238 ratio. This is a topic for discussion with the instrument manufacturers. Finally, deviation from linearity of the response of the electron multiplier with count rate limits the accuracy and reproducibility of these minor isotope measurements. References: (1) P. Steier et al(2008) Nuc Inst Meth(B), 266, 2246-2250. (2) E. Keegan et al (2008) Appl Geochem 23, 765-777. (3) K. Mayer et al (1998) IAEA-CN-98/11, in Advances in Destructive and Non-destructive Analysis for Environmental Monitoring and Nuclear Forensics. (4) S. Richter and S. Goldberg(2003) Int J Mass Spectrom, 229, 181-197.

  16. A new infiltration method for coating highly permeable matrices with compound materials for high-power isotope-separator-on-line production target applications

    International Nuclear Information System (INIS)

    Kawai, Y.; Bilheux, Jean-Christophe; Stracener, Daniel W; Alton, Gerald D

    2005-01-01

    A new infiltration coating method has been conceived for uniform and controlled thickness deposition of target materials onto highly permeable, complex-structure matrices to form short-diffusion-length isotope-separator-on-line (ISOL) production targets for radioactive ion beam research applications. In this report, the infiltration technique is described in detail and the universal character of the technique illustrated in the form of SEMs of several metal-carbide, metal-oxide and metal-sulfide targets for potential use at present or future radioactive ion beam research facilities

  17. Some regularities of spatial and time distribution of organogenous material in Upper-Pleistocene and Holocene sediments of Central Asia (from the data of Carbon-isotope dating)

    International Nuclear Information System (INIS)

    Pshenin, G.N.; Steklenkov, A.P.; Varushchenko, A.N.

    1991-01-01

    The analysis of space time distribution of ancient organogenous material is carried out through generalization of practically all available at the present time data on radiocarbon dating of Upper-Pleistocene and Holocene sediments in the Middle Asia. The investigations were performed to study the variability of humidification over the specific territory of the Middle Asia within a determined period of time. Three rather clearly limited vertical height intervals are determined by the results of the isotope dating of wood, coal, peat and mollus samples

  18. Standard format and content of a licensee physical protection plan for strategic special nuclear material in transit - April 1980

    International Nuclear Information System (INIS)

    Anon.

    1981-01-01

    A predetermined plan to respond to safeguards contingency events is required to be prepared, based on personnel and other physical protection resources described in the Physical Protection Plan for strategic special nuclear material (SSNM) in transit. Specific requirements for the contingency plan are provided in Appendix C. Licensee Safeguards Contingency Plans, to 10 CFR Part 73. Regulatory Guide 5.56, Standard Format and Content of Safeguards Contingency Plans for Transportation, provides guidance for the preparation of transportation contingency plans. Licensee is reminded that all three submissions - the Physical Protection Plan, the Physical Protection Arrangements for Specific Shipments, and the Safeguards Contingency Plan - together describe the system for physical protection of each particular shipment. They should be developed and maintained to be completely consistent with each other for each shipment

  19. Investigations and characterization of the microstructure of special ceramic materials using the high-resolution electron microscope

    International Nuclear Information System (INIS)

    Kirn, M.

    1979-01-01

    The possibilities to characterize phases and microstructures by direct lattice imaging are indicated in the following work. Ceramic materials are particularly suitable for this as these exhibit a high mechanical stability in the investigation in the transmission electron microscope. First of all the fundamentals of the high-resolution electron microscopy are introduced and the various resulting possibilities to characterize microstructures are presented. A report then follows on experimental observations on undisturbed crystals of special ceramics on a Si 3 N 4 basis. Furthermore, it is shown that the high-resolution electron microscope provides valuable contributions to the determination of structure, in particular of twin variants. Finally, revealing information on the structure of the interfaces was obtained with the help of high-resolution electron microscopy. (orig./IHOE) [de

  20. Research of Acoustic Properties of Materials with the Purpose of Their Use at Design of Special Noise Protective Clothes for Oil and Gas Industry

    Science.gov (United States)

    Drofa, E. A.; Lipilina, E. Yu

    2018-01-01

    The article is devoted to the substantiation of the choice of a rational package of materials, which has the greatest noise-protective properties when designing special clothes with reference to the oil and gas industry. Studies were conducted to assess the factors that have the most significant effect on the noise-protective properties of clothing. Conclusions are made about the possibility of using the developed technique for studying the noise-protective properties of materials in selecting rational packages of materials for the production of special clothes with high noise-protective properties.

  1. Matrix separation by chelation to prepare biological materials for isotopic zinc analysis by inductively coupled plasma mass spectrometry

    International Nuclear Information System (INIS)

    Durrant, S.F.; Krushevska, A.; Amarasiriwardena, D.; Argentine, M.D.; Romon-Guesnier, S.; Barnes, R.M.

    1994-01-01

    Following an evaluation of three chelating resins [Chelex-100, poly(dithiocarbamate) (PDTC) and carboxymethylated poly(ethyleneimine)-poly(methylenepolyphenylene) isocyanate (CPPI)], a procedure was established with the last of these for the separation of Zn from biological matrix elements prior to 70 Zn: 68 Zn isotopic analysis by inductively coupled plasma mass spectrometry (ICP-MS). The method was verified by establishing Zn recoveries and by determining its effectiveness in removing Cl and Na from buffered test solutions. Calcium, Na, and Zn concentration data were determined by inductively coupled plasma atomic emission spectrometry. Chlorine was measured by electrothermal vaporization ICP-MS. The efficacy of the technique was demonstrated by the determination of zinc isotope ratios in bovine milk and human urine. (Author)

  2. Metrology for stable isotope reference materials: 13C/12C and 18O/16O isotope ratio value assignment of pure carbon dioxide gas samples on the Vienna PeeDee Belemnite-CO2 scale using dual-inlet mass spectrometry.

    Science.gov (United States)

    Srivastava, Abneesh; Michael Verkouteren, R

    2018-05-25

    Isotope ratio measurements have been conducted on a series of isotopically distinct pure CO 2 gas samples using the technique of dual-inlet isotope ratio mass spectrometry (DI-IRMS). The influence of instrumental parameters, data normalization schemes on the metrological traceability and uncertainty of the sample isotope composition have been characterized. Traceability to the Vienna PeeDee Belemnite(VPDB)-CO 2 scale was realized using the pure CO 2 isotope reference materials(IRMs) 8562, 8563, and 8564. The uncertainty analyses include contributions associated with the values of iRMs and the repeatability and reproducibility of our measurements. Our DI-IRMS measurement system is demonstrated to have high long-term stability, approaching a precision of 0.001 parts-per-thousand for the 45/44 and 46/44 ion signal ratios. The single- and two-point normalization bias for the iRMs were found to be within their published standard uncertainty values. The values of 13 C/ 12 C and 18 O/ 16 O isotope ratios are expressed relative to VPDB-CO 2 using the [Formula: see text] and [Formula: see text] notation, respectively, in parts-per-thousand (‰ or per mil). For the samples, value assignments between (-25 to +2) ‰ and (-33 to -1) ‰ with nominal combined standard uncertainties of (0.05, 0.3) ‰ for [Formula: see text] and [Formula: see text], respectively were obtained. These samples are used as laboratory reference to provide anchor points for value assignment of isotope ratios (with VPDB traceability) to pure CO 2 samples. Additionally, they serve as potential parent isotopic source material required for the development of gravimetric based iRMs of CO 2 in CO 2 -free dry air in high pressure gas cylinder packages at desired abundance levels and isotopic composition values. Graphical abstract CO 2 gas isotope ratio metrology.

  3. Basic methods of isotope analysis

    International Nuclear Information System (INIS)

    Ochkin, A.V.; Rozenkevich, M.B.

    2000-01-01

    The bases of the most applied methods of the isotope analysis are briefly presented. The possibilities and analytical characteristics of the mass-spectrometric, spectral, radiochemical and special methods of the isotope analysis, including application of the magnetic resonance, chromatography and refractometry, are considered [ru

  4. Detection of special nuclear material from delayed neutron emission induced by a dual-particle monoenergetic source

    Energy Technology Data Exchange (ETDEWEB)

    Mayer, M. [Department of Mechanical and Nuclear Engineering, The Pennsylvania State University, University Park, Pennsylvania 16802 (United States); Nattress, J.; Jovanovic, I., E-mail: ijov@umich.edu [Department of Nuclear Engineering and Radiological Sciences, University of Michigan, Ann Arbor, Michigan 48109 (United States)

    2016-06-27

    Detection of unique signatures of special nuclear materials is critical for their interdiction in a variety of nuclear security and nonproliferation scenarios. We report on the observation of delayed neutrons from fission of uranium induced in dual-particle active interrogation based on the {sup 11}B(d,n γ){sup 12}C nuclear reaction. Majority of the fissions are attributed to fast fission induced by the incident quasi-monoenergetic neutrons. A Li-doped glass–polymer composite scintillation neutron detector, which displays excellent neutron/γ discrimination at low energies, was used in the measurements, along with a recoil-based liquid scintillation detector. Time-dependent buildup and decay of delayed neutron emission from {sup 238}U were measured between the interrogating beam pulses and after the interrogating beam was turned off, respectively. Characteristic buildup and decay time profiles were compared to the common parametrization into six delayed neutron groups, finding a good agreement between the measurement and nuclear data. This method is promising for detecting fissile and fissionable materials in cargo scanning applications and can be readily integrated with transmission radiography using low-energy nuclear reaction sources.

  5. Development and application of special instrumentation for materials accountancy and process control in spent fuel recycle plants

    International Nuclear Information System (INIS)

    Clark, P.A.; Gardner, N.; Merrill, N.H.; Whitehouse, K.R.

    1996-01-01

    Safe and optimum operations of spent fuel recycle plants rely on the availability of real time measurement systems at key points in the process. More than thirty types of special instrument systems have been developed and commissioned on the THORP reprocessing plant at Sellafield. These systems are compiled together with the associated information on measurement purpose, measurement technique and plant performance. A number of these measurement systems are of interest to support Safeguards arrangements on the plant. A more detailed overview of two such instrument systems respectively within the Head End and Product Finishing Stages of THORP is provided. The first of these is the Hulls Monitor, based on high resolution gamma spectrometry, as well as active and passive neutron measurements, of the basket of leached fuel cladding. This provides vital data for criticality assurance, nuclear material accountancy and inventory determination for ultimate disposal of the cladding waste. The second system is the Plutonium Inventory Monitoring System (PIMS) which employs passive neutron counting from a distributed array of neutron detectors within the Pu Finishing Line. This provides a near real time estimate of Pu inventories both during operations and at clean out of the Finishing Line. Both the Hulls Monitor and PIMS technologies are applicable to MOX Fuel recycle. Both systems enhance the control of fissile material in key areas of the recycle process which are of interest to the Safeguards authorities. (author)

  6. Oxygen isotope analysis of plant water without extraction procedure

    International Nuclear Information System (INIS)

    Gan, K.S.; Wong, S.C.; Farquhar, G.D.; Yong, J.W.H.

    2001-01-01

    Isotopic analyses of plant water (mainly xylem, phloem and leaf water) are gaming importance as the isotopic signals reflect plant-environment interactions, affect the oxygen isotopic composition of atmospheric O 2 and CO 2 and are eventually incorporated into plant organic matter. Conventionally, such isotopic measurements require a time-consuming process of isolating the plant water by azeotropic distillation or vacuum extraction, which would not complement the speed of isotope analysis provided by continuous-flow IRMS (Isotope-Ratio Mass Spectrometry), especially when large data sets are needed for statistical calculations in biological studies. Further, a substantial amount of plant material is needed for water extraction and leaf samples would invariably include unenriched water from the fine veins. To measure sub-microlitre amount of leaf mesophyll water, a new approach is undertaken where a small disc of fresh leaf is cut using a specially designed leaf punch, and pyrolysed directly in an IRMS. By comparing with results from pyrolysis of the dry matter of the same leaf, the 18 O content of leaf water can be determined without extraction from fresh leaves. This method is validated using a range of cellulose-water mixtures to simulate the constituents of fresh leaf. Cotton leaf water δ 18 O obtained from both methods of fresh leaf pyrolysis and azeotropic distillation will be compared. The pyrolysis technique provides a robust approach to measure the isotopic content of water or any volatile present in a homogeneous solution or solid hydrous substance

  7. Environmental isotope hydrology

    International Nuclear Information System (INIS)

    1973-01-01

    Environmental isotope hydrology is a relatively new field of investigation based on isotopic variations observed in natural waters. These isotopic characteristics have been established over a broad space and time scale. They cannot be controlled by man, but can be observed and interpreted to gain valuable regional information on the origin, turnover and transit time of water in the system which often cannot be obtained by other techniques. The cost of such investigations is usually relatively small in comparison with the cost of classical hydrological studies. The main environmental isotopes of hydrological interest are the stable isotopes deuterium (hydrogen-2), carbon-13, oxygen-18, and the radioactive isotopes tritium (hydrogen-3) and carbon-14. Isotopes of hydrogen and oxygen are ideal geochemical tracers of water because their concentrations are usually not subject to change by interaction with the aquifer material. On the other hand, carbon compounds in groundwater may interact with the aquifer material, complicating the interpretation of carbon-14 data. A few other environmental isotopes such as 32 Si and 238 U/ 234 U have been proposed recently for hydrological purposes but their use has been quite limited until now and they will not be discussed here. (author)

  8. High-fidelity MCNP modeling of a D-T neutron generator for active interrogation of special nuclear material

    International Nuclear Information System (INIS)

    Katalenich, Jeff; Flaska, Marek; Pozzi, Sara A.; Hartman, Michael R.

    2011-01-01

    Fast and robust methods for interrogation of special nuclear material (SNM) are of interest to many agencies and institutions in the United States. It is well known that passive interrogation methods are typically sufficient for plutonium identification because of a relatively high neutron production rate from 240 Pu . On the other hand, identification of shielded uranium requires active methods using neutron or photon sources . Deuterium-deuterium (2.45 MeV) and deuterium-tritium (14.1 MeV) neutron-generator sources have been previously tested and proven to be relatively reliable instruments for active interrogation of nuclear materials . In addition, the newest generators of this type are small enough for applications requiring portable interrogation systems. Active interrogation techniques using high-energy neutrons are being investigated as a method to detect hidden SNM in shielded containers . Due to the thickness of some containers, penetrating radiation such as high-energy neutrons can provide a potential means of probing shielded SNM. In an effort to develop the capability to assess the signal seen from various forms of shielded nuclear materials, University of Michigan Neutron Science Laboratory's D-T neutron generator and its shielding were accurately modeled in MCNP. The generator, while operating at nominal power, produces approximately 1x10 10 neutrons/s, a source intensity which requires a large amount of shielding to minimize the dose rates around the generator. For this reason, the existing shielding completely encompasses the generator and does not include beam ports. Therefore, several MCNP simulations were performed to estimate the yield of uncollided 14.1-MeV neutrons from the generator for active interrogation experiments. Beam port diameters of 5, 10, 15, 20, and 25 cm were modeled to assess the resulting neutron fluxes. The neutron flux outside the beam ports was estimated to be approximately 2x10 4 n/cm 2 s.

  9. Comparison of the reactivity of the materials having two different kinds of functional groups by applying hydrogen-isotope exchange reaction

    International Nuclear Information System (INIS)

    Imaizumi, H.; Yumoto, Y.

    1995-01-01

    The hydrogen-isotope exchange reaction between m- (or p-) aminobenzoic acid and HTO vapor has been observed in order to estimate the scale of the reactivity of the material. Each rate constant has been obtained by the A''-McKay plot method. Comparing the rate constants, the following three items have been confirmed: (1) the reactivity of both COOH and NH 2 groups increases with temperature; (2) the degree of the effect of the COOH (or NH 2 ) group on the reactivity in m-aminobenzoic acid is larger than that in p-aminobenzoic acid; (3) the A''-McKay plot method is useful in studying the reactivity of the materials not only with one (or the same kinds of) functional group(s), but also with two different kinds of functional groups. (orig.)

  10. The solid-liquid extraction separation of lithium isotopes by porous composite materials doped with ionic liquids and 2,2'-binaphthyldiyl-17-crown-5

    International Nuclear Information System (INIS)

    Xiao-Li Sun; Ling Gu; Dan Qiu; Dong-Hong Ren; Zaijun Li; Zhi-Guo Gu; Jiangnan University, Wuxi

    2015-01-01

    A green and efficient solid-liquid extraction method of lithium isotopes separation by porous composite materials doped with imidazolium ionic liquids and 2,2'-binaphthyldiyl-17-crown-5 has been reported in this paper. The composite materials of mesoporous silica and impregnated resin were synthesized by sol-gel and direct impregnation process, respectively. Various extraction parameters such as the concentration of lithium salt, anion of lithium salt, initial pH, time and temperature were investigated. Under optimized conditions, the maximum single-stage separation factor of 6 Li/ 7 Li was 1.048 ± 0.002, the maximum extraction efficiency was 15.86 %. The sorbents can be regenerated easily with HCl solution and reused repeatedly. (author)

  11. Selection of support structure materials for irradiation experiments in the HFIR [High Flux Isotope Reactor] at temperatures up to 500 degrees C

    International Nuclear Information System (INIS)

    Farrell, K.; Longest, A.W.

    1990-01-01

    The key factor in the design of capsules for irradiation of test specimens in the High Flux Isotope Reactor at preselected temperatures up to 500 degree C utilizing nuclear heating is a narrow gas-filled gap which surrounds the specimens and controls the transfer of heat from the specimens through the wall of a containment tube to the reactor cooling water. Maintenance of this gap to close tolerances is dependent on the characteristics of the materials used to support the specimens and isolate them from the water. These support structure materials must have low nuclear heating rates, high thermal conductivities, and good dimensional stabilities under irradiation. These conditions are satisfied by certain aluminum alloys. One of these alloys, a powder metallurgy product containing a fine dispersion of aluminum oxide, is no longer manufactured. A new alloys of this type, with the trade name DISPAL, is determined to be a suitable substitute. 23 refs., 13 figs., 3 tabs

  12. Isotope separation process

    International Nuclear Information System (INIS)

    Lyon, R.K.

    1977-01-01

    The instant invention relates to a process for separating a material into two or more parts in each of which the abundances of the isotopes of a given element differ from the abundances of the isotopes of the same material in said material. More particularly, the invention relates to a method for the isotopically selective excitation of gas phase molecules by multiple infrared photon absorption followed by a step wherein more of the excited molecules than nonexcited molecules are converted to a chemically different form which may be separated by means known in the art. This invention is useful for, but not limited to, the separation of the principal isotopes of uranium. 15 claims, 1 figure

  13. Uranium isotopic analysis of depleted uranium in presence of other radioactive materials by using nondestructive gamma-ray measurements in coaxial and planar Ge detectors

    International Nuclear Information System (INIS)

    Yucel, H.; Yeltepe, E.; Dikmen, H.; Turhan, Sh.; Vural, M.

    2006-01-01

    Full text: The isotopic abundance of depleted uranium samples in the presence of other radioactive materials, especially actinide isotopes such as Th 232, Np 237-Pa 233 and Am 241 can be determined from two gamma-ray spectrometric methods. One is the absolute method which employs non-destructive gamma-ray spectrometry for energies below 1001 keV using a coaxial Ge detector calibrated with a set of standards. The other is the multi-group analysis (MGA) method using the low energy region (< 300 keV) with a planar Ge detector intrinsically calibrated with gamma and X-rays of uranium without use of standards. At present absolute method, less intense but cleaner gamma peaks at 163.33 keV (5.08 percent) and 205 keV(5.01 percent) of U 235 are preferred over more intense peaks at 143.76 keV(10.76 percent), possible interference with 143.25 keV(0.44 percent) of Np 237 and 185.705 keV(57.2 percent), possible interference with 186.21 keV(3.51 percent) of Ra 226. In the high energy region the 1001.03 keV(0.837 percent) peak of Pa 234 m is used for the isotopic abundance analysis because the more intense 63.3 keV peak of Th 234 daughter of U 238 parent has a fully multiplet(62.86 keV+63.29 keV) and include the interferences of the 62.70 keV(1.5 percent) peak of Pa 234, the 63.81 keV(0.263 percent) peak of Th 232 and the 63.90 keV(0.011 percent) peak of Np 237. Although the MGA method is quicker and more practical, the more laborious absolute gamma spectrometric method can give more accurate results for the isotopic determination of depleted uranium samples. The relative uranium abundances obtained with the second method (i,e., MGA) are in general inconsistent with the declared values for the uranium samples in the presence of the above mentioned actinides. The reason for these erroneous results is proposed to be the interference of the gamma and X-rays of uranium in the 80-130 keV region used in MGA with those emissions from other radioactive materials present

  14. Targets and special materials

    International Nuclear Information System (INIS)

    Blanc, R.; Bouriant, M.; Richaud, J.P.

    1997-01-01

    The target preparation group supplied a large number of samples to nuclear physicists for experiments using SARA and also other accelerators throughout the world. Particular preparation and projects include: 208 Pb, 116 Cd, 6 LiF, 123 Sb, In and Ta targets, strippers for SARA and GANIL, optical silicone disks for POLDER and GRAAL experiments, active participations for the AMS project and finally filament preparation for the GENEPI project. (authors)

  15. Isotopes and atomic weights

    International Nuclear Information System (INIS)

    Zhang Qinglian

    1990-01-01

    A review of the chemical and mass spectrometric methods of determining the atomic weights of elements is presented. A, special discussion is devoted to the calibration of the mass spectrometer with highly enriched isotopes. It is illustrated by the recent work on europium. How to choose the candidate element for new atomic weight determination forms the last section of the article

  16. Applications of isotopes

    International Nuclear Information System (INIS)

    Kirby-Smith, J.S.

    1976-01-01

    Current and potential applications of stable isotopes as tracers in a number of biomedical and environmental areas are discussed. It is pointed out that a wide variety of problems exist in these fields whose solutions in principle are amenable to the isotopic approach. The number and diversity of these problems as well as the unique role stable isotopes can play in their solution illustrate the importance of achieving and maintaining a broad inventory of isotopic species. Experience has demonstrated unequivocally an additional overriding requirement for widespread exploration of stable isotopes by the scientific and technical community, i.e., the need for low cost availability of the materials in quantity. Some representative applications of 12 C, 13 C, 14 N, 15 N, 16 O, 17 O, and 18 O are discussed

  17. Nd-Sr isotopic compositions of dissolved and particulate material transported by the Parana and Uruguay rivers during high (december 1993) and low (september 1994) water periods

    International Nuclear Information System (INIS)

    Henry, F.; Thouron, D.; Garcon, V.; Henry, F.; Probst, J.L.

    1996-01-01

    Our motivation is to better constrain the neodymium and strontium isotopic signatures of the closest continental riverine source (Parana and Uruguay rivers) to the Brazil/Malvinas Confluence zone in the Southwest Atlantic Ocean. We thus present new isotopic data on the Nd and Sr of the dissolved and suspended loads of the Parana and Uruguay rivers for two water periods forming the Rio de la Plata whose drainage basin is the second largest one in South America. The Parana dissolved material shows less radiogenic (ε Nd (0) ranging between -12.1 and -8.2) than the Uruguay one with a mean ε Nd (0) value of -6.3 ± 0.3. Suspended particulates display the same isotopic trend (mean ε Nd (0) value of -10.3 and -6.0 for the Parana and Uruguay rivers, respectively). Dissolved load 87 Sr/ 86 Sr in the Parana (0.7123) is found to be more radiogenic than the Uruguay one (0.7097); the suspended load follows the same trend with 87 Sr/ 86 Sr ratios of 0.7247 and 0.7115 in the Parana and Uruguay rivers, respectively. The relatively radiogenic Nd and non radiogenic Sr of the Uruguay River as compared to the Parana River could be attributed to a predominance of tholeiitic basalts in the drainage basin. A revisited estimation of the fluxes of Nd considering all South American rivers delivering into the western South and Tropical Atlantic Ocean yields a Nd particulate flux to estuarine water two orders of magnitude higher than the Nd dissolved flux. Considering the net dissolved and suspended fluxes of Nd reaching the Rio de la Plata, we have calculated a resulting ε Nd (0) equal to -10.2. The computation of ε Nd (0) of the Rio de la Plata outflow waters gives a value of -8.3, taking into account various removal processes within the estuary. (authors)

  18. Technical testing of portable isotope identification instruments

    International Nuclear Information System (INIS)

    Smith, D.E.

    2001-01-01

    Full text: The United States Customs Service has, as a part of its mission, the protection of the borders of the United States from the import or export of illicit radioactive materials. Of paramount importance is the ability to interdict the smuggling of special nuclear material, nuclear weapons and other radioactive materials that could be used as a weapon of mass destruction against the population and infrastructure of the U.S. or another country. Radiation detection technology exists in the form of pocket size, hand-held and portal radiation detectors that have the ability to detect radiation with great sensitivity and low false alarm rates. U.S. Customs has chosen to implement pocket size detectors or radiation pagers as the personal tool of each inspector for the detection of radioactive material. In the search for illicit shipment of radioactive materials, innocent radiation detections may occur with some frequency due to common radioactive sources that may be encountered in day to day living. Examples include lantern mantles, some camera lenses, welding rods, certain dishware containing uranium glaze, and natural marble objects such as statues or architectural pieces. Perhaps the most common innocent detection encountered at the border and in public areas in general is due to the in vivo placement of radioactive sources for use in nuclear medicine therapy and diagnostics. Outpatients from such therapy can remain detectable for three weeks or more. Also, legal shipments of radioisotopes are common occurrences in cargo and express mail shipments. The customs inspector who detects radioactive material in the course of his duties must decide whether detection is innocent; is indicative of a nuclear device or special nuclear material; or whether the source could be injurious to him/her or the general public. It is at this point that a portable instrument capable of identifying gamma or neutron emitting isotopes is essential to the customs examination procedure

  19. Competence and lastingness in specialized clinical laboratories: technical report about requirements concerning quality of users competence and used processes in immunochemical diagnostic procedures using isotopic and non-isotopic tracer technologies

    International Nuclear Information System (INIS)

    Wiegel, B.

    2005-01-01

    From the citizens view this technical report about immunochemical diagnostic procedures using radioactive and nonradioactive tracer technologies describes the requirements in special laboratory diagnostics concerning competency and process control. Governmental or administrational obligations of inspecting both skill and sites to guarantee patients security are pointed out. (orig.)

  20. Age and isotopic fingerprints of some plutonic rocks in the Wiborg rapakivi granite batholith with special reference to the dark wiborgite of the Ristisaari Island

    Directory of Open Access Journals (Sweden)

    Rämö, O.T.

    2014-12-01

    Full Text Available The mid-Proterozoic, locus classicus Wiborg rapakivi granite batholith of southeastern Finland and adjacent Russia comprises a varying, bimodal (silicic-basic sequence of plutonic, subvolcanic, and volcanic rocks. At the current level of erosion silicic rocks are dominant, the most prominent of which are wiborgites and dark wiborgites (that have been considered to mark the main build-up stage of the batholith and pyterlites. New observations and optical microscopy data from the dark wiborgite-dominated Ristisaari Island in the southern, off-shore part of the Wiborg batholith show that dark plagioclase megacrysts in dark wiborgite are calcic xenocrysts. They were probably incorporated into wiborgite magma from consanguineous massiftype anorthosite magmas in the course of the evolution of the bimodal magmatic system. Our new ID-TIMS U-Pb zircon age of the Ristisaari Island dark wiborgite, 1627±3 Ma, is the youngest isotopic age so far determined for the plutonic rocks of the Wiborg batholith. This, combined with preexisting U-Pb zircon data, implies a minimum duration of 12 m.y. (1642–1630 Ma for the emplacement of the plutonic rocks of the batholith. Combined with data on highlevel dike rocks, a window of at least 20 m.y. (1642–1622 Ma is implied. Furthermore, as the batholith grew, the overall locus of magmatism may have shifted southwards. New whole-rock Nd isotope data on the dark wiborgite of the Ristisaari Island and three further granites of the batholith, as well as Nd (whole-rock and Sr (whole-rock, plagioclase isotope data on a spectrolite massif-type anorthosite from the east-central part of the batholith, are also presented. These data suggest that the lithosphere across the Wiborg batholith area in the southeastern part of the Svecofennian orogen may vary slightly in overall mantle separation age.

  1. Nondestructive Inspection System for Special Nuclear Material Using Inertial Electrostatic Confinement Fusion Neutrons and Laser Compton Scattering Gamma-Rays

    Science.gov (United States)

    Ohgaki, H.; Daito, I.; Zen, H.; Kii, T.; Masuda, K.; Misawa, T.; Hajima, R.; Hayakawa, T.; Shizuma, T.; Kando, M.; Fujimoto, S.

    2017-07-01

    A Neutron/Gamma-ray combined inspection system for hidden special nuclear materials (SNMs) in cargo containers has been developed under a program of Japan Science and Technology Agency in Japan. This inspection system consists of an active neutron-detection system for fast screening and a laser Compton backscattering gamma-ray source in coupling with nuclear resonance fluorescence (NRF) method for precise inspection. The inertial electrostatic confinement fusion device has been adopted as a neutron source and two neutron-detection methods, delayed neutron noise analysis method and high-energy neutron-detection method, have been developed to realize the fast screening system. The prototype system has been constructed and tested in the Reactor Research Institute, Kyoto University. For the generation of the laser Compton backscattering gamma-ray beam, a race track microtron accelerator has been used to reduce the size of the system. For the NRF measurement, an array of LaBr3(Ce) scintillation detectors has been adopted to realize a low-cost detection system. The prototype of the gamma-ray system has been demonstrated in the Kansai Photon Science Institute, National Institutes for Quantum and Radiological Science and Technology. By using numerical simulations based on the data taken from these prototype systems and the inspection-flow, the system designed by this program can detect 1 kg of highly enriched 235U (HEU) hidden in an empty 20-ft container within several minutes.

  2. Study of the prompt gamma ray signal from fissions in special nuclear materials induced using an associated particle neutron generator

    International Nuclear Information System (INIS)

    Koltick, D. S.; Kane, S. Z.

    2009-01-01

    More than 42 million cargo containers entered the United States in 2005. To search for a few kilograms of special nuclear material (SNM) within this vast stream of cargo, an inspection system based on neutron-induced fission followed by the coincident detection of multiple prompt fission gamma rays is investigated using MCNP-Polimi code. The system utilizes two deuterium-tritium (DT) associated particle neutron generators, each capable of 10 9 neutrons/s at 14.1 MeV, with sub-nanosecond timing resolution ZnO:Ga alpha detectors internal to the generator. Because prompt fission signals are approximately 100 times stronger than the delayed signals, the neutron flux is greatly reduced compared to 10 11-12 neutrons/s required for systems based on delayed signals such as the 'nuclear car wash' [4]. In addition the system utilizes 30 cm deep liquid krypton (LKr) noble gas detectors having 94% detection efficiency for 1 MeV gamma rays, high solid angle coverage (∼ 50% of the total solid angle), and sub-nanosecond timing resolution (∼ 600 ps). An algorithm for distinguishing U-235 from U-238 is presented. (authors)

  3. Natural isotopes

    International Nuclear Information System (INIS)

    Vogel, J.C.

    1986-01-01

    14 C dates between 600 and 900 AD were obtained for early Iron Age sites in Natal, and from 1300 to 1450 AD for rock engraving sites in Bushmanland. Palaeoenvironmental data derived from the dating of samples related to sedimentary and geomorphic features in the central and northern Namib Desert enabled the production of a tentative graph for the changes in humidity in the region over the past 40000 years. These results suggest that relatively humid conditions came to an end in the Namib at ±25000 BP (before present). The increased precision of the SIRA mass spectrometer enabled the remeasurement of 13 C and 18 O in the Cango stalagmite. This data confirmed that the environmental temperatures in the Southern Cape remained constant to within ±1 o C during the past 5500 years. Techniques and applications for environmental isotopes in hydrology were developed to determine the origin and movement of ground water. Isotopic fractionation effects in light elements in nature were investigated. The 15 N/ 14 N ratio in bones of animals and humans increases in proportion to the aridity of the environment. This suggests that 15 N in bone from dated archaeological sites could be used to detect changes in past climatic conditions as naturally formed nitrate minerals are higly soluble and are only preserved in special, very dry environments. The sources and sinks of CO 2 on the South African subcontinent were also determined. The 13 C/ 12 C ratios of air CO 2 obtained suggest that the vegetation provides the major proportion of respired CO 2 . 9 refs., 1 fig

  4. Isotopic separation by ion chromatography

    International Nuclear Information System (INIS)

    Albert, M.G.; Barre, Y.; Neige, R.

    1994-01-01

    The isotopic exchange reaction and the isotopic separation factor are first recalled; the principles of ion chromatography applied to lithium isotope separation are then reviewed (displacement chromatography) and the process is modelled in the view of dimensioning and optimizing the industrial process; the various dimensioning parameters are the isotopic separation factor, the isotopic exchange kinetics and the material flow rate. Effects of the resin type and structure are presented. Dimensioning is also affected by physico-chemical and hydraulic parameters. Industrial implementation features are also discussed. 1 fig., 1 tab., 5 refs

  5. Isotopically controlled semiconductors

    Energy Technology Data Exchange (ETDEWEB)

    Haller, Eugene E.

    2006-06-19

    The following article is an edited transcript based on the Turnbull Lecture given by Eugene E. Haller at the 2005 Materials Research Society Fall Meeting in Boston on November 29, 2005. The David Turnbull Lectureship is awarded to recognize the career of a scientist who has made outstanding contributions to understanding materials phenomena and properties through research, writing, and lecturing, as exemplified by the life work of David Turnbull. Haller was named the 2005 David Turnbull Lecturer for his 'pioneering achievements and leadership in establishing the field of isotopically engineered semiconductors; for outstanding contributions to materials growth, doping and diffusion; and for excellence in lecturing, writing, and fostering international collaborations'. The scientific interest, increased availability, and technological promise of highly enriched isotopes have led to a sharp rise in the number of experimental and theoretical studies with isotopically controlled semiconductor crystals. This article reviews results obtained with isotopically controlled semiconductor bulk and thin-film heterostructures. Isotopic composition affects several properties such as phonon energies, band structure, and lattice constant in subtle, but, for their physical understanding, significant ways. Large isotope-related effects are observed for thermal conductivity in local vibrational modes of impurities and after neutron transmutation doping. Spectacularly sharp photoluminescence lines have been observed in ultrapure, isotopically enriched silicon crystals. Isotope multilayer structures are especially well suited for simultaneous self- and dopant-diffusion studies. The absence of any chemical, mechanical, or electrical driving forces makes possible the study of an ideal random-walk problem. Isotopically controlled semiconductors may find applications in quantum computing, nanoscience, and spintronics.

  6. Isotope separation process

    International Nuclear Information System (INIS)

    Thomas, W.R.L.

    1979-01-01

    The instant invention relates to an improved process for separating a material into two or more parts in each of which the abundances of the isotopes of a given element differ from the abundances of the isotopes of the same element in said material. More particularly, the invention relates to a method for the isotopically selective excitation of gas phase molecules by multiple infrared photon absorption followed by a step wherein more of the excited molecules than non-excited molecules are converted to a chemically different form which may be separated by means known in the art. This invention is useful for, but not limited to, the separation of the principal isotopes of uranium

  7. Gaseous emissions from biogas-digestate management and from fertilized soils. A study with special reference to nitrous oxide determination by stable isotope and isotopomer techniques

    Energy Technology Data Exchange (ETDEWEB)

    Koester, Jan Reent

    2014-07-02

    distribution within the asymmetric N{sub 2}O molecules (the so called 'site preference', SP) allows some insights into these source processes. Here, this approach confirmed denitrification as the predominating N{sub 2}O source. The isotopic fractionation factors during N{sub 2}O production and reduction via denitrification are still an uncertainty factor for stable isotope approaches relying on isotope ratios at natural abundance level. Therefore, these fractionation factors have been further investigated using different soil incubation approaches in two studies. The observed isotope fractionation during these experiments was partly in agreement with previous studies; however, in some cases the results deviated from literature values, probably due to experimental artefacts in some of the previous studies. N{sub 2}O Isotopomer analysis is commonly done by isotope ratio mass spectrometry (IRMS), which has relatively low throughput and does not allow real time analysis. Here, recently developed laser spectroscopic techniques capable of site specific N{sub 2}O {sup 15}N analysis may provide significant advantages compared to IRMS. Therefore, an experimental setup involving a new QCL absorption spectrometer was tested for its applicability in soil studies. The SP values of soil derived N{sub 2}O were successfully determined continuously over several days, and were in good agreement with IRMS analysis, presenting laser spectroscopy as a promising new analytical approach for analyzing N{sub 2}O in soil studies.

  8. Gaseous emissions from biogas-digestate management and from fertilized soils. A study with special reference to nitrous oxide determination by stable isotope and isotopomer techniques

    International Nuclear Information System (INIS)

    Koester, Jan Reent

    2014-01-01

    ', SP) allows some insights into these source processes. Here, this approach confirmed denitrification as the predominating N_2O source. The isotopic fractionation factors during N_2O production and reduction via denitrification are still an uncertainty factor for stable isotope approaches relying on isotope ratios at natural abundance level. Therefore, these fractionation factors have been further investigated using different soil incubation approaches in two studies. The observed isotope fractionation during these experiments was partly in agreement with previous studies; however, in some cases the results deviated from literature values, probably due to experimental artefacts in some of the previous studies. N_2O Isotopomer analysis is commonly done by isotope ratio mass spectrometry (IRMS), which has relatively low throughput and does not allow real time analysis. Here, recently developed laser spectroscopic techniques capable of site specific N_2O "1"5N analysis may provide significant advantages compared to IRMS. Therefore, an experimental setup involving a new QCL absorption spectrometer was tested for its applicability in soil studies. The SP values of soil derived N_2O were successfully determined continuously over several days, and were in good agreement with IRMS analysis, presenting laser spectroscopy as a promising new analytical approach for analyzing N_2O in soil studies.

  9. Isotopic clusters

    International Nuclear Information System (INIS)

    Geraedts, J.M.P.

    1983-01-01

    Spectra of isotopically mixed clusters (dimers of SF 6 ) are calculated as well as transition frequencies. The result leads to speculations about the suitability of the laser-cluster fragmentation process for isotope separation. (Auth.)

  10. Stable isotopes

    International Nuclear Information System (INIS)

    Evans, D.K.

    1986-01-01

    Seventy-five percent of the world's stable isotope supply comes from one producer, Oak Ridge Nuclear Laboratory (ORNL) in the US. Canadian concern is that foreign needs will be met only after domestic needs, thus creating a shortage of stable isotopes in Canada. This article describes the present situation in Canada (availability and cost) of stable isotopes, the isotope enrichment techniques, and related research programs at Chalk River Nuclear Laboratories (CRNL)

  11. The Text of Tile Master Agreement between the Agency and the United States of America Governing Sales of Source, By- Product and Special Nuclear Materials for research Purposes

    International Nuclear Information System (INIS)

    1974-01-01

    The text of the Master Agreement Governing Sales of Source, Bye Product and Special Nuclear Materials for Research Purposes, which has been concluded between the Agency and the Government of the United States of America, is reproduced herein for the information of all Members,

  12. Substoichiometric isotope dilution analysis of arsenic in biological and environmental standard reference materials by solvent extraction using toluene-3,4-dithiol in benzene

    International Nuclear Information System (INIS)

    Chutke, N.L.; Ambulkar, Ms.M.N.; Weginwar, R.G.; Garg, A.N.

    1994-01-01

    A radiochemical solvent extraction procedure has been developed for the determination of As(III) using 76 As tracer. It is based on the complexation of As(III) with toluene-3,4-dithiol (TDT) at pH 2 and subsequent extraction in benzene. The effect of various parameters such as pH, time of equilibration, nature of solvent, quantitative character and interferences have been studied. The method has been further developed into substoichiometric isotope dilution analysis for the determination of As at < 1μg level and employed for the analysis of several environmental and biological standard Reference Materials from NIST (USA), IAEA (Vienna) and NIES (Japan). (author) 39 refs.; 4 figs.; 4 tabs

  13. Isotope separation

    International Nuclear Information System (INIS)

    Eerkens, J.W.

    1979-01-01

    A method of isotope separation is described which involves the use of a laser photon beam to selectively induce energy level transitions of an isotope molecule containing the isotope to be separated. The use of the technique for 235 U enrichment is demonstrated. (UK)

  14. Overview of the U.S. Department of Energy's Isotope Programs

    International Nuclear Information System (INIS)

    Carty, J.

    2004-01-01

    This presentation provides an overview of the U.S. Department of Energy's Isotopes Program. The charter of the Isotope Programs covers the production and sale of radioactive and stable isotopes, associated byproducts, surplus materials, and related isotope services

  15. CSER-98-002: Criticality analysis for the storage of special nuclear material sources and standards in the WRAP Facility

    International Nuclear Information System (INIS)

    Goldberg, H.J.

    1998-01-01

    The Waste Receiving and Processing (WRAP) Facility will store uranium and transuranic (TRU) sources and standards for certification that WRAP meets the requirements of the Quality Assurance Program Plan (QAPP) for the Waste Isolation Pilot Plant (WIPP). In addition, WRAP must meet internal requirements for testing and validation of measuring instruments for nondestructive assay (NDA). In order to be certified for WIPP, WRAP will participate in the NDA Performance Demonstration Program (PDP). This program is a blind test of the NDA capabilities for TRU waste. It is intended to ensure that the NDA capabilities of this facility satisfy the requirements of the quality assurance program plan for the WIPP. The PDP standards have been provided by the Los Alamos National Laboratory (LANL) for this program. These standards will be used in the WRAP facility. To internally check the accuracy and sensitivity of the NDA instruments, a further set of sources and standards will also be used by the facility. Each sealed source or standard will be referred to herein as a unit. Various combinations of these units will be placed in test drums and/or boxes which will be subject to their own limits until unloaded. There will be two sealed test drums with five grams of weapons grade plutonium loaded in them. These drums will be appropriately marked and will be subject to the unit limits rather than the drum limits. This analysis shows that the storage and use of special nuclear material sources and standards within the limited control facility of WRAP (Rooms 101 and 104) is safe from a criticality standpoint. With the form, geometry, and masses involved with this evaluation, a criticality is not possible. The limits given in Section 2 should be imposed on facility operations

  16. Analysis of transient permeation behavior of hydrogen isotope caused by abrupt temperature change of first wall and blanket wall material

    International Nuclear Information System (INIS)

    Yamawaki, Michio; Tanaka, Satoru; Kiyoshi, Tsukasa

    1989-01-01

    To obtain further information on the transient permeation behavior of hydrogen isotopes as caused by an abrupt temperature change, numerical calculations were carried out for two typical metals, nickel and vanadium. Deuterium permeation through nickel is analyzed as a typical case of bulk-diffusion-limited permeation. Its transient behavior changed dramatically according to the specimen thickness. The transient behavior, in general, is separated into two parts, initial and latter period behaviors. Conditions which cause such a separation were evaluated. Evaluation of the hydrogen diffusivity and solubility by an analysis of transient curves of hydrogen permeation was carried out. The transient behavior of simultaneous gas- and ion-driven hydrogen permeation through vanadium was also analyzed. Overshooting of the hydrogen permeation rate appears with an abrupt temperature increase. Increasing the impinging ion flux causes the overshooting peak to become sharper, and also reduces the change of the steady-state permeation rate to be attained after the temperature change compared with the initial value. (orig.)

  17. NKS-Norcmass reference material for analysis of Pu-isotopes and 237Np by mass spectrometry

    International Nuclear Information System (INIS)

    Ross, P.; Nygren, U.; Appelblad, P.; Skipperud, L.; Sjoegren, A.

    2006-04-01

    The aim of the reference material in the Norcmass-project was to produce a low-level ( 239 Pu) sample of sufficient amount to allow individual laboratories to perform several tests without risk of using up the material. Although there are several reference materials available (eg IAEA) few have 239 Pu/ 240 Pu data and almost none have 237 Np/ 239 Pu-data. Those who have (eg IAEA-384) have very high concentrations and are not useful for testing analytical methods designed for low-level measurements where a large sample mass may be required. The reference material consist of the top 10cm of 2mm sieved soil pooled together from 12 different Danish locations collected during 2003. The Soil was blended and sieved through 0.6 and finally through a 0.4 mm sieve. A total amount of 17 kg soil was produced. Several aliquots of the material was subject to analysis by alpha spectrometry and ICP-MS. The material contain 239 + 240 Pu at a concentration of 0.24 ± 0.01 mBq/g and a 240 Pu/ 239 Pu atom ratio of 0.19 ± 0.006. The ratio 237 Np/ 239 Pu was determined to 0.32 ± 0.01. (au)

  18. Lunar and Planetary Science XXXV: Special Session: Oxygen in the Solar System, I

    Science.gov (United States)

    2004-01-01

    The Special Session: Oxygen in the Solar System, I, included the following reports:Oxygen in the Solar System: Origins of Isotopic and Redox Complexity; The Origin of Oxygen Isotope Variations in the Early Solar System; Solar and Solar-Wind Oxygen Isotopes and the Genesis Mission; Solar 18O/17O and the Setting for Solar Birth; Oxygen Isotopes in Early Solar System Materials: A Perspective Based on Microbeam Analyses of Chondrules from CV Carbonaceous Chondrites; Insight into Primordial Solar System Oxygen Reservoirs from Returned Cometary Samples; Tracing Meteorites to Their Sources Through Asteroid Spectroscopy; Redox Conditions Among the Terrestrial Planets; Redox Complexity in Martian Meteorites: Implications for Oxygen in the Terrestrial Planets; Implications of Sulfur Isotopes for the Evolution of Atmospheric Oxygen; Oxygen in the Outer Solar System; and On the Oxidation States of the Galilean Satellites: Implications for Internal Structures.

  19. Isotopes in environmental research

    International Nuclear Information System (INIS)

    Bowen, G.; Rozanski, K.; Vose, P.

    1990-01-01

    Radioactive and stable isotopes have long been considered a very efficient tool for studying physical and biological aspects of how the global ecosystem functions. Their applications in environmental research are numerous, embracing research at all levels. This article looks at only a few of the approaches to environmental problems that involve the use of isotopes. Special attention is given to studies of the Amazon Basin. Environmental isotopes are very efficient tools in water cycle studies. Tritium, a radioactive tracer, is especially useful in studying dynamics of water movement in different compartments of the hydrosphere, both on the local and global scales. Heavy stable isotopes of hydrogen and oxygen (deuterium and oxygen-18) provide information about steady-state characteristics of the water cycle. Isotope methods, some relatively new, have a major role in site-specific studies. Some indicative examples include: Studying turnover of organic matter. Changes in the carbon-13/carbon-12 isotopic ratio of organic matter were used to determine the respective contributions of organic carbon derived from forest and pasture. Studying biological nitrogen fixation. One of the ways nitrogen levels in soil can be maintained for productivity is by biological nitrogen fixation. Studying nitrogen availability and losses. The experimental use of nitrogen-15 is invaluable for defining losses of soil nitrogen to the atmosphere and to groundwater. Studies can similarly be done with stable and radioactive sulphur isotopes. This article indicates some potential uses of isotopes in environmental research. While the major problem of global climate change has not been specifically addressed here, the clearing of the Amazon forest, one focus of the IAEA's environmental programme, may have serious consequences for the global climate. These include substantial reduction of the amount of latent heat transported to the regions outside the tropics and acceleration of the greenhouse

  20. The use of composite ferrocyanide materials for treatment of high salinity liquid radioactive wastes rich in cesium isotopes

    Energy Technology Data Exchange (ETDEWEB)

    Toropov, Andrey S. [National Nuclear Centre of the Republic of Kazakhstan, Kurchatov (Kazakhstan); Shakarim Semey State Univ. (Kazakhstan); Satayeva, Aliya R. [Shakarim Semey State Univ. (Kazakhstan); Mikhalovsky, Sergey [Nazarbayev Univ. (Kazakhstan); Brighton Univ. (United Kingdom); Cundy, Andrew B. [Brighton Univ. (United Kingdom)

    2014-07-01

    The use of composite materials based on metal ferrocyanides combined with natural mineral sorbents for treatment of high salinity Cs-containing liquid radioactive waste (LRW) was investigated. The study indicated that among the investigated composites, the best sorption characteristics for Cs were shown by materials based on copper ferrocyanide. Several factors affecting the removal of cesium from LRW, namely total salt content, pH and organic matter content, were also investigated. High concentrations of complexing organic matter significantly reduced the sorption capacity of ferrocyanide sorbents.