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Sample records for major oil producing

  1. Oil and gas technology transfer activities and potential in eight major producing states. Volume 1

    Energy Technology Data Exchange (ETDEWEB)

    1993-07-01

    In 1990, the Interstate Oil and Gas Compact Commission (the Compact) performed a study that identified the structure and deficiencies of the system by which oil and gas producers receive information about the potential of new technologies and communicate their problems and technology needs back to the research community. The conclusions of that work were that major integrated companies have significantly more and better sources of technology information than independent producers. The majors also have significantly better mechanisms for communicating problems to the research and development (R&D) community. As a consequence, the Compact recommended analyzing potential mechanisms to improve technology transfer channels for independents and to accelerate independents acceptance and use of existing and emerging technologies. Building on this work, the Compact, with a grant from the US Department Energy, has reviewed specific technology transfer organizations in each of eight major oil producing states to identify specific R&D and technology transfer organizations, characterize their existing activities, and identify potential future activities that could be performed to enhance technology transfer to oil and gas producers. The profiles were developed based on information received from organizations,follow-up interviews, site visit and conversations, and participation in their sponsored technology transfer activities. The results of this effort are reported in this volume. In addition, the Compact has also developed a framework for the development of evaluation methodologies to determine the effectiveness of technology transfer programs in performing their intended functions and in achieving desired impacts impacts in the producing community. The results of that work are provided in a separate volume.

  2. Mitsubishi Oil to become a major oil player?

    International Nuclear Information System (INIS)

    Ash, N.

    1994-01-01

    Mitsubishi Oil became a wholly-owned Japanese company in 1984. Before that, since 1981, it had been a joint venture between Mitsubishi and Getty oil. Recently the company has discovered a major new oilfield off the coast of Vietnam. In addition it has a strategic stake in the Canadian Athabasca Far Sands, major investments in Angola and operations in Papua New Guinea and Gabon. It aims to cover 30 % of the crude oil imports to its four existing, and fifth projected, refineries from owned sources by the end of the century. Mitsubishi has a network of 4500 service stations in Japan and has become one of the largest lubricating oil producers. The company's main overseas sales are of jet fuel, lubricating and tanker oils, sulphur and some petrochemicals. (UK)

  3. Modelling the oil producers: Capturing oil industry knowledge in a behavioural simulation model

    International Nuclear Information System (INIS)

    Morecroft, J.D.W.; Van der Heijden, K.A.J.M.

    1992-01-01

    A group of senior managers and planners from a major oil company met to discuss the changing structure of the oil industry with the purpose of improving group understanding of oil market behaviour for use in global scenarios. This broad ranging discussion led to a system dynamics simulation model of the oil producers. The model produced new insights into the power and stability of OPEC (the major oil producers' organization), the dynamic of oil prices, and the investment opportunities of non-OPEC producers. The paper traces the model development process, starting from group discussions and leading to working simulation models. Particular attention is paid to the methods used to capture team knowledge and to ensure that the computer models reflected opinions and ideas from the meetings. The paper describes how flip-chart diagrams were used to collect ideas about the logic of the principal producers' production decisions. A sub-group of the project team developed and tested an algebraic model. The paper shows partial model simulations used to build confidence and a sense of ownership in the algebraic formulations. Further simulations show how the full model can stimulate thinking about producers' behaviour and oil prices. The paper concludes with comments on the model building process. 11 figs., 37 refs

  4. Performance profiles of major energy producers 1993

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-01-01

    Performance Profiles of Major Energy Producers 1993 is the seventeenth annual report of the Energy Information Administration`s (EIA) Financial Reporting System (FRS). The report examines financial and operating developments in energy markets, with particular reference to the 25 major US energy companies required to report annually on Form EIA-28. Financial information is reported by major liens of business, including oil and gas production, petroleum refining and marketing, other energy operations, and nonenergy businesses. Financial and operating results are presented in the context of energy market developments with a view toward identifying changing corporate strategies and measuring the performance of ongoing operations both in the US and abroad. This year`s report analyzes financial and operating developments for 1993 (Part 1: Developments in 1993) and also reviews key developments during the 20 years following the Arab Oil Embargo of 1973--1974 (Part 2: Major Energy Company Strategies Since the Arab Oil Embargo). 49 figs., 104 tabs.

  5. MAJOR OIL PLAYS IN UTAH AND VICINITY

    International Nuclear Information System (INIS)

    Chidsey, Thomas C. Jr.; Morgan, Craig D.; Bon, Roger L.

    2003-01-01

    Utah oil fields have produced over 1.2 billion barrels (191 million m 3 ). However, the 13.7 million barrels (2.2 million m 3 ) of production in 2002 was the lowest level in over 40 years and continued the steady decline that began in the mid-1980s. The Utah Geological Survey believes this trend can be reversed by providing play portfolios for the major oil producing provinces (Paradox Basin, Uinta Basin, and thrust belt) in Utah and adjacent areas in Colorado and Wyoming. Oil plays are geographic areas with petroleum potential caused by favorable combinations of source rock, migration paths, reservoir rock characteristics, and other factors. The play portfolios will include: descriptions and maps of the major oil plays by reservoir; production and reservoir data; case-study field evaluations; summaries of the state-of-the-art drilling, completion, and secondary/tertiary techniques for each play; locations of major oil pipelines; descriptions of reservoir outcrop analogs; and identification and discussion of land use constraints. All play maps, reports, databases, and so forth, produced for the project will be published in interactive, menu-driven digital (web-based and compact disc) and hard-copy formats. This report covers research activities for the third quarter of the first project year (January 1 through March 31, 2003). This work included gathering field data and analyzing best practices in the eastern Uinta Basin, Utah, and the Colorado portion of the Paradox Basin. Best practices used in oil fields of the eastern Uinta Basin consist of conversion of all geophysical well logs into digital form, running small fracture treatments, fingerprinting oil samples from each producing zone, running spinner surveys biannually, mapping each producing zone, and drilling on 80-acre (32 ha) spacing. These practices ensure that induced fractures do not extend vertically out of the intended zone, determine the percentage each zone contributes to the overall production of

  6. Decomposition analysis of CO2 emission intensity between oil-producing and non-oil-producing sub-Saharan African countries

    International Nuclear Information System (INIS)

    Ebohon, Obas John; Ikeme, Anthony Jekwu

    2006-01-01

    The need to decompose CO 2 emission intensity is predicated upon the need for effective climate change mitigation and adaptation policies. Such analysis enables key variables that instigate CO 2 emission intensity to be identified while at the same time providing opportunities to verify the mitigation and adaptation capacities of countries. However, most CO 2 decomposition analysis has been conducted for the developed economies and little attention has been paid to sub-Saharan Africa. The need for such an analysis for SSA is overwhelming for several reasons. Firstly, the region is amongst the most vulnerable to climate change. Secondly, there are disparities in the amount and composition of energy consumption and the levels of economic growth and development in the region. Thus, a decomposition analysis of CO 2 emission intensity for SSA affords the opportunity to identify key influencing variables and to see how they compare among countries in the region. Also, attempts have been made to distinguish between oil and non-oil-producing SSA countries. To this effect a comparative static analysis of CO 2 emission intensity for oil-producing and non oil-producing SSA countries for the periods 1971-1998 has been undertaken, using the refined Laspeyres decomposition model. Our analysis confirms the findings for other regions that CO 2 emission intensity is attributable to energy consumption intensity, CO 2 emission coefficient of energy types and economic structure. Particularly, CO 2 emission coefficient of energy use was found to exercise the most influence on CO 2 emission intensity for both oil and non-oil-producing sub-Saharan African countries in the first sub-interval period of our investigation from 1971-1981. In the second subinterval of 1981-1991, energy intensity and structural effect were the two major influencing factors on emission intensity for the two groups of countries. However, energy intensity effect had the most pronounced impact on CO 2 emission

  7. Major Oil Plays in Utah and Vicinity

    Energy Technology Data Exchange (ETDEWEB)

    Thomas C. Chidsey; Craig D. Morgan; Kevin McClure; Douglas A. Sprinkel; Roger L. Bon; Hellmut H. Doelling

    2003-12-31

    Utah oil fields have produced over 1.2 billion barrels (191 million m{sup 3}). However, the 13.7 million barrels (2.2 million m{sup 3}) of production in 2002 was the lowest level in over 40 years and continued the steady decline that began in the mid-1980s. The Utah Geological Survey believes this trend can be reversed by providing play portfolios for the major oil-producing provinces (Paradox Basin, Uinta Basin, and thrust belt) in Utah and adjacent areas in Colorado and Wyoming. Oil plays are geographic areas with petroleum potential caused by favorable combinations of source rock, migration paths, reservoir rock characteristics, and other factors. The play portfolios will include: descriptions and maps of the major oil plays by reservoir; production and reservoir data; case-study field evaluations; locations of major oil pipelines; identification and discussion of land-use constraints; descriptions of reservoir outcrop analogs; and summaries of the state-of-the-art drilling, completion, and secondary/tertiary techniques for each play. This report covers research activities for the sixth quarter of the project (October 1 through December 31, 2003). This work included describing outcrop analogs for the Jurassic Twin Creek Limestone and Mississippian Leadville Limestone, major oil producers in the thrust belt and Paradox Basin, respectively, and analyzing best practices used in the southern Green River Formation play of the Uinta Basin. Production-scale outcrop analogs provide an excellent view of reservoir petrophysics, facies characteristics, and boundaries contributing to the overall heterogeneity of reservoir rocks. They can be used as a ''template'' for evaluation of data from conventional core, geophysical and petrophysical logs, and seismic surveys. In the Utah/Wyoming thrust belt province, the Jurassic Twin Creek Limestone produces from subsidiary closures along major ramp anticlines where the low-porosity limestone beds are extensively

  8. Major Oil Plays In Utah And Vicinity

    Energy Technology Data Exchange (ETDEWEB)

    Thomas Chidsey

    2007-12-31

    Utah oil fields have produced over 1.33 billion barrels (211 million m{sup 3}) of oil and hold 256 million barrels (40.7 million m{sup 3}) of proved reserves. The 13.7 million barrels (2.2 million m3) of production in 2002 was the lowest level in over 40 years and continued the steady decline that began in the mid-1980s. However, in late 2005 oil production increased, due, in part, to the discovery of Covenant field in the central Utah Navajo Sandstone thrust belt ('Hingeline') play, and to increased development drilling in the central Uinta Basin, reversing the decline that began in the mid-1980s. The Utah Geological Survey believes providing play portfolios for the major oil-producing provinces (Paradox Basin, Uinta Basin, and thrust belt) in Utah and adjacent areas in Colorado and Wyoming can continue this new upward production trend. Oil plays are geographic areas with petroleum potential caused by favorable combinations of source rock, migration paths, reservoir rock characteristics, and other factors. The play portfolios include descriptions and maps of the major oil plays by reservoir; production and reservoir data; case-study field evaluations; locations of major oil pipelines; identification and discussion of land-use constraints; descriptions of reservoir outcrop analogs; and summaries of the state-of-the-art drilling, completion, and secondary/tertiary recovery techniques for each play. The most prolific oil reservoir in the Utah/Wyoming thrust belt province is the eolian, Jurassic Nugget Sandstone, having produced over 288 million barrels (46 million m{sup 3}) of oil and 5.1 trillion cubic feet (145 billion m{sup 3}) of gas. Traps form on discrete subsidiary closures along major ramp anticlines where the depositionally heterogeneous Nugget is also extensively fractured. Hydrocarbons in Nugget reservoirs were generated from subthrust Cretaceous source rocks. The seals for the producing horizons are overlying argillaceous and gypsiferous beds in

  9. Performance profiles of major energy producers, 1991

    International Nuclear Information System (INIS)

    1992-01-01

    Performance Profiles of Major Energy Producers 1991 is the fifteenth annual report of the Energy Information Administration's (EIA) Financial Reporting System (FRS). The report examines financial and operating developments, with particular reference to the 23 major energy companies (the FRS companies) required to report annually on Form EIA-28. It also traces key developments affecting the financial performance of major energy companies in 1991, as well as reviews important trends. Financial information is reported by major lines of business including oil and gas production, petroleum refining and marketing, and other energy operations. Domestic and international operations are examined separately in this report

  10. MAJOR OIL PLAYS IN UTAH AND VICINITY

    International Nuclear Information System (INIS)

    Chidsey, Thomas C.; Morgan, Craig D.; McClure, Kevin; Willis, Grant C.

    2003-01-01

    Utah oil fields have produced over 1.2 billion barrels (191 million m 3 ). However, the 13.7 million barrels (2.2 million m 3 ) of production in 2002 was the lowest level in over 40 years and continued the steady decline that began in the mid-1980s. The Utah Geological Survey believes this trend can be reversed by providing play portfolios for the major oil-producing provinces (Paradox Basin, Uinta Basin, and thrust belt) in Utah and adjacent areas in Colorado and Wyoming. Oil plays are geographic areas with petroleum potential caused by favorable combinations of source rock, migration paths, reservoir rock characteristics, and other factors. The play portfolios will include: descriptions and maps of the major oil plays by reservoir; production and reservoir data; case-study field evaluations; summaries of the state-of-the-art drilling, completion, and secondary/tertiary techniques for each play; locations of major oil pipelines; descriptions of reservoir outcrop analogs; and identification and discussion of land use constraints. All play maps, reports, databases, and so forth, produced for the project will be published in interactive, menu-driven digital (web-based and compact disc) and hard-copy formats. This report covers research activities for the fourth quarter of the first project year (April 1 through June 30, 2003). This work included describing outcrop analogs to the Jurassic Nugget Sandstone and Pennsylvanian Paradox Formation, the major oil producers in the thrust belt and Paradox Basin, respectively. Production-scale outcrop analogs provide an excellent view, often in three dimensions, of reservoir-facies characteristics and boundaries contributing to the overall heterogeneity of reservoir rocks. They can be used as a ''template'' for evaluation of data from conventional core, geophysical and petrophysical logs, and seismic surveys. The Nugget Sandstone was deposited in an extensive dune field that extended from Wyoming to Arizona. Outcrop analogs are

  11. Progress in reorganization of international oil industry and moves of majors

    Energy Technology Data Exchange (ETDEWEB)

    (Institute of Energy Economics, Tokyo (Japan))

    1988-10-15

    Of oil majors, Texaco, Chevron and Mobil have become depressed because of the sharp decrease in oil abundance due to the OPEC members' nationalization policy of resources in the first half of 1970's, whereas Exxon and Shell, who have made steady efforts in investment for exploration and development, have grown. BP has made a wide stride by acquisitions. Business acquisitions and mergers are increasing again in oil industries of Europe and U.S. with the dull oil price as the background. A particular feature of this trend is active involvement of western firms in North Sea oil. Oil producing countries are actively penetrating in downstream markets of consuming countries to establish stable selling routes. Whereas two directions are possible for changes in the international petroleum industry, that is, either coordinated action of producing countries and majors or increased competition among them, the age of co-existence and co-prosperity is most probable. 1 figure.

  12. Performance profiles of major energy producers 1989

    Energy Technology Data Exchange (ETDEWEB)

    1991-01-23

    Performance Profiles of Major Energy Producers 1989 is the thirteenth annual report of the Energy Information Administration's (EIA) Financial Reporting System (FRS). The report examines financial and operating developments, with particular reference to the 23 major energy companies (the FRS companies'') required to report annually on Form EIA-28. Financial information is reported by major lines of business including oil and gas production, petroleum refining and marketing, and other energy operations. Domestic and international operations are examined separately in this report. It also traces key developments affecting the financial performance of major energy companies in 1989, as well as review of important trends.

  13. Non-Renewable Energy and Macroeconomic Efficiency of Seven Major Oil Producing Economies in Africa

    Directory of Open Access Journals (Sweden)

    Awodumi Olabanji Benjamin

    2016-05-01

    Full Text Available This study adopted two-stage DEA to estimate the technical efficiency scores and assess the impact of the two most important components of fossil fuel associated with oil production on macroeconomic efficiency of Seven oil producing African countries during 2005-2012. Our results showed that increasing the consumption of natural gas would improve technical efficiency. Furthermore, increasing the share of fossil fuel in total energy consumption has negative effect on the efficiency of the economies of the top African oil producers. Also, we found that increasing the consumption of primary energy improves efficiency in these economies. We therefore, recommend that governments and other stakeholders in the energy industry should adopt inclusive strategies that will promote the use of natural gas in the short term. However, in the long-run, efforts should be geared towards increasing the use of primary energy, thereby reducing the percentage share of fossil fuel in total energy consumption.

  14. Performance profiles of major energy producers 1994

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-02-01

    Performance Profiles of Major Energy Producers 1994 is the eighteenth annual report of the Energy Information Administration`s (EIA) Financial Reporting System (FRS). The report examines financial and operating developments in energy markets, with particular reference to the 24 major U.S. energy companies required to report annually on Form EIA-28. Financial information is reported by major lines of business, including oil and gas production, petroleum refining and marketing, other energy operations, and nonenergy businesses. Financial and operating results are presented in the context of energy market developments with a view toward identifying changing corporate strategies and measuring the performance of ongoing operations both in the United States and abroad.

  15. Performance profiles of major energy producers 1992

    Energy Technology Data Exchange (ETDEWEB)

    1994-01-13

    Performance Profiles of Major Energy Producers 1992 is the sixteenth annual report of the Energy Information Administration`s (EIA) Financial Reporting System (FRS). The report examines financial and operating developments, with particular reference to the 25 major energy companies (the FRS companies) required to report annually on Form EIA-28. Financial information is reported by major lines of business, including oil and gas production, petroleum refining and marketing, and other energy operations. Domestic and international operations are examined separately in this report. The data are presented in the context of key energy market developments with a view toward identifying changing strategies of corporate development and measuring the apparent success of current ongoing operations.

  16. Performance profiles of major energy producers 1992

    International Nuclear Information System (INIS)

    1994-01-01

    Performance Profiles of Major Energy Producers 1992 is the sixteenth annual report of the Energy Information Administration's (EIA) Financial Reporting System (FRS). The report examines financial and operating developments, with particular reference to the 25 major energy companies (the FRS companies) required to report annually on Form EIA-28. Financial information is reported by major lines of business, including oil and gas production, petroleum refining and marketing, and other energy operations. Domestic and international operations are examined separately in this report. The data are presented in the context of key energy market developments with a view toward identifying changing strategies of corporate development and measuring the apparent success of current ongoing operations

  17. Air Permitting Implications of a Biorefinery Producing Raw Bio-Oil in Comparison with Producing Gasoline and Diesel Blendstocks

    Energy Technology Data Exchange (ETDEWEB)

    Bhatt, Arpit H [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Zhang, Yi Min [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

    2018-02-01

    A biorefinery, considered a chemical process plant under the Clean Air Act permitting program, could be classified as a major or minor source based on the size of the facility and magnitude of regulated pollutants emitted. Our previous analysis indicates that a biorefinery using fast pyrolysis conversion process to produce finished gasoline and diesel blendstocks with a capacity of processing 2,000 dry metric tons of biomass per day would likely be classified as a major source because several regulated pollutants (such as particulate matter, sulfur dioxide, nitrogen oxide) are estimated to exceed the 100 tons per year (tpy) major source threshold, applicable to chemical process plants. Being subject to a major source classification could pose additional challenges associated with obtaining an air permit in a timely manner before the biorefinery can start its construction. Recent developments propose an alternative approach to utilize bio-oil produced via the fast pyrolysis conversion process by shipping it to an existing petroleum refinery, where the raw bio-oil can be blended with petroleum-based feedstocks (e.g., vacuum gas oil) to produce gasoline and diesel blendstocks with renewable content. Without having to hydro-treat raw bio-oil, a biorefinery is likely to reduce its potential-to-emit to below the 100 tpy major source threshold, and therefore expedite its permitting process. We compare the PTE estimates for the two biorefinery designs with and without hydrotreating of bio-oils and examine the air permitting implications on potential air permit classification and discuss the best available control technology requirements for the major source biorefinery utilizing hydrotreating operation. Our analysis is expected to provide useful information to new biofuel project developers to identify opportunities to overcome challenges associated with air permitting.

  18. Performance profiles of major energy producers, 1997

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-01-01

    The energy industry generally and petroleum and natural gas operations in particular are frequently reacting to a variety of unsettling forces. Falling oil prices, economic upswings, currency devaluations, increasingly rigorous environmental quality standards, deregulation of electricity markets, and continued advances in exploration and production technology were among the challenges and opportunities to the industry in 1997. To analyze the extent to which these and other developments have affected energy industry financial and operating performance, strategies, and industry structure, the Energy Information Administration (EIA) maintains the Financial Reporting Systems (FRS). Through Form EIA-28, major US energy companies annually report to the FRS. Financial and operating information is reported by major lines of business, including oil and gas production (upstream), petroleum refining and marketing (downstream), other energy operations, and nonenergy business. Performance Profiles of Major Producers 1997 examines the interplays of energy markets, companies` strategies, and government policies (in 1997 and in historical context) that gave rise to the results given here. The report also analyzes other key aspects of energy company financial performance as seen through the multifaceted lens provided by the FRS data and complementary data for industry overall. 41 figs., 77 tabs.

  19. Yemen - the next big player? [as an oil producer

    International Nuclear Information System (INIS)

    Roberts, J.

    1993-01-01

    1993 should be the year in which United Yemen finally starts to fulfil its potential as a significant oil producer. In recession for three years, the country desperately needs the revenues and has spared no effort in its attempt to provide the right financial climate within which international oil companies can operate. But the last three years, in terms of revenues from actual oil production, have been disastrous, with production from the much-touted Shabwa fields persistently deferred and with the overall climate for the oil industry clouded by a border dispute with Saudi Arabia that prompted at least one western major, BP, to suspend operations for a while. (author)

  20. Major Oil Plays in Utah and Vicinity. Quarterly Technical Progress Report

    International Nuclear Information System (INIS)

    Thomas C. Chidsey; Craig D. Morgan; Kevin McClure; Douglas A. Sprinkel; Roger L. Bon; Hellmut H. Doelling

    2003-01-01

    Utah oil fields have produced over 1.2 billion barrels (191 million m 3 ). However, the 13.7 million barrels (2.2 million m 3 ) of production in 2002 was the lowest level in over 40 years and continued the steady decline that began in the mid-1980s. The Utah Geological Survey believes this trend can be reversed by providing play portfolios for the major oil-producing provinces (Paradox Basin, Uinta Basin, and thrust belt) in Utah and adjacent areas in Colorado and Wyoming. Oil plays are geographic areas with petroleum potential caused by favorable combinations of source rock, migration paths, reservoir rock characteristics, and other factors. The play portfolios will include: descriptions and maps of the major oil plays by reservoir; production and reservoir data; case-study field evaluations; locations of major oil pipelines; identification and discussion of land-use constraints; descriptions of reservoir outcrop analogs; and summaries of the state-of-the-art drilling, completion, and secondary/tertiary techniques for each play. This report covers research activities for the sixth quarter of the project (October 1 through December 31, 2003). This work included describing outcrop analogs for the Jurassic Twin Creek Limestone and Mississippian Leadville Limestone, major oil producers in the thrust belt and Paradox Basin, respectively, and analyzing best practices used in the southern Green River Formation play of the Uinta Basin. Production-scale outcrop analogs provide an excellent view of reservoir petrophysics, facies characteristics, and boundaries contributing to the overall heterogeneity of reservoir rocks. They can be used as a ''template'' for evaluation of data from conventional core, geophysical and petrophysical logs, and seismic surveys. In the Utah/Wyoming thrust belt province, the Jurassic Twin Creek Limestone produces from subsidiary closures along major ramp anticlines where the low-porosity limestone beds are extensively fractured and sealed by

  1. Intrastate conflict in oil producing states: A threat to global oil supply?

    International Nuclear Information System (INIS)

    Toft, Peter

    2011-01-01

    In this paper I investigate how often and how much outbreaks of intrastate conflict in oil producing states translates into oil supply shortfalls. The Libyan conflict that broke out in February 2011 highlighted the fear that intrastate conflict in oil producing states may imply shortfalls and ensuing volatile global oil prices. I argue, however, that it is far from certain that shortfalls following conflict outbreak will occur, since both sides in a conflict face incentives simultaneously to protect and maintain oil installations and to strike and destroy these. Based on a quantitative analysis of 39 intrastate wars in oil producing countries (1965-2007) I conclude that outbreak of conflict does not translate into production decline with any certainty. In fact, likelihoods are less than 50% for reductions to occur. In many cases growing production actually followed conflict outbreak. I conclude by investigating four characteristics of intrastate conflict that may explain when oil production is at risk during conflict: (1) proximity of oil producing fields to key battle zones, (2) duration of conflict, (3) separatism and the location of oil in separatist territory, and (4) the relative size of oil production. While the first three factors did not prove important, oil producer size could be significant. But further research is needed to establish this with greater certainty. - Highlights: → Oil shortfall during intrastate conflict is not a given. → Statistical analysis of 39 intrastate conflicts in oil producing countries since 1965. → Examination of four characteristics of intrastate conflict in oil producing countries. → Marginal significance related to large producers and production shortfall.

  2. Intrastate conflict in oil producing states: A threat to global oil supply?

    Energy Technology Data Exchange (ETDEWEB)

    Toft, Peter, E-mail: peter.toft@ec.europa.eu [Institute for Energy, Joint Research Centre of the European Commission, Westerduinweg 3, 1755 ZG Petten (Netherlands)

    2011-11-15

    In this paper I investigate how often and how much outbreaks of intrastate conflict in oil producing states translates into oil supply shortfalls. The Libyan conflict that broke out in February 2011 highlighted the fear that intrastate conflict in oil producing states may imply shortfalls and ensuing volatile global oil prices. I argue, however, that it is far from certain that shortfalls following conflict outbreak will occur, since both sides in a conflict face incentives simultaneously to protect and maintain oil installations and to strike and destroy these. Based on a quantitative analysis of 39 intrastate wars in oil producing countries (1965-2007) I conclude that outbreak of conflict does not translate into production decline with any certainty. In fact, likelihoods are less than 50% for reductions to occur. In many cases growing production actually followed conflict outbreak. I conclude by investigating four characteristics of intrastate conflict that may explain when oil production is at risk during conflict: (1) proximity of oil producing fields to key battle zones, (2) duration of conflict, (3) separatism and the location of oil in separatist territory, and (4) the relative size of oil production. While the first three factors did not prove important, oil producer size could be significant. But further research is needed to establish this with greater certainty. - Highlights: > Oil shortfall during intrastate conflict is not a given. > Statistical analysis of 39 intrastate conflicts in oil producing countries since 1965. > Examination of four characteristics of intrastate conflict in oil producing countries. > Marginal significance related to large producers and production shortfall.

  3. Performance profiles of major energy producers 1996

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-01-01

    This publication examines developments in the operations of the major US e energy-producing companies on a corporate level, by major line of business, by major function within each line of business, and by geographic area. In 1996, 24 companies filed Form EIA-28. The analysis and data presented in this report represents the operations of the Financial Reporting System companies in the context of their worldwide operations and in the context of the major energy markets which they serve. Both energy and nonenergy developments of these companies are analyzed. Although the focus is on developments in 1996, important trends prior to that time are also featured. Sections address energy markets in 1996; key financial developments; oil and gas exploration, development, and production; downstream petroleum in 1996; coal and alternative energy; and foreign direct investment in US energy. 30 figs., 104 tabs.

  4. Performance profiles of major energy producers 1996

    International Nuclear Information System (INIS)

    1998-01-01

    This publication examines developments in the operations of the major US e energy-producing companies on a corporate level, by major line of business, by major function within each line of business, and by geographic area. In 1996, 24 companies filed Form EIA-28. The analysis and data presented in this report represents the operations of the Financial Reporting System companies in the context of their worldwide operations and in the context of the major energy markets which they serve. Both energy and nonenergy developments of these companies are analyzed. Although the focus is on developments in 1996, important trends prior to that time are also featured. Sections address energy markets in 1996; key financial developments; oil and gas exploration, development, and production; downstream petroleum in 1996; coal and alternative energy; and foreign direct investment in US energy. 30 figs., 104 tabs

  5. Strategic issues for the oil majors - 1992

    Energy Technology Data Exchange (ETDEWEB)

    Oppenheimer, P M [Oxford Univ. (United Kingdom)

    1992-01-01

    Strategic issues facing major oil producers in the 1990s are very diffuse - in contrast with both the 1970s (when strategy meant the response to high oil prices) and the 1980s (when it meant anticipating and exploiting a drop in prices). Mainly upstream issues include the future of price management by OPEC or a successor, the speed of development of new markets for natural gas in power generation and the role of Russia in world energy markets. Other issues include the impact of environmental regulations and taxes on the product mix and on marketing. Human-resource management will continue to face the task of reconciling career opportunities with static or declining manpower requirements; and corporate cash mountains may periodically recur. (Author).

  6. Strategic issues for the oil majors - 1992

    International Nuclear Information System (INIS)

    Oppenheimer, P.M.

    1992-01-01

    Strategic issues facing major oil producers in the 1990s are very diffuse - in contrast with both the 1970s (when strategy meant the response to high oil prices) and the 1980s (when it meant anticipating and exploiting a drop in prices). Mainly upstream issues include the future of price management by OPEC or a successor, the speed of development of new markets for natural gas in power generation and the role of Russia in world energy markets. Other issues include the impact of environmental regulations and taxes on the product mix and on marketing. Human-resource management will continue to face the task of reconciling career opportunities with static or declining manpower requirements; and corporate cash mountains may periodically recur. (Author)

  7. Producers and oil markets

    International Nuclear Information System (INIS)

    Greaves, W.

    1993-01-01

    This article attempts an assessment of the potential use of futures by the Middle East oil producers. It focuses on Saudi Arabia since the sheer size of Saudi Arabian sales poses problems, but the basic issues discussed are similar for the other Middle East producers. (Author)

  8. Partitioning of semi-soluble organic compounds between the water phase and oil droplets in produced water

    Energy Technology Data Exchange (ETDEWEB)

    Faksness, Liv-Guri; Grini, Per Gerhard; Daling, Per S

    2004-04-01

    When selecting produced water treatment technologies, one should focus on reducing the major contributors to the total environmental impact. These are dispersed oil and semi-soluble hydrocarbons, alkylated phenols, and added chemicals. Experiments with produced water have been performed offshore on the Statoil operated platforms Gullfaks C and Statfjord B. These experiments were designed to find how much of the environmentally relevant compounds were dissolved in the water phase and not associated to the dispersed oil in the produced water. Results show that the distribution between the dispersed oil and the water phase varies highly for the different components groups. For example the concentration of PAHs and the C6-C9 alkylated phenols is strongly correlated to the content of dispersed oil. Therefore, the technologies enhancing the removal of dispersed oil have a higher potential for reducing the environmental impact of the produced water than previously considered.

  9. Partitioning of semi-soluble organic compounds between the water phase and oil droplets in produced water

    International Nuclear Information System (INIS)

    Faksness, Liv-Guri; Grini, Per Gerhard; Daling, Per S.

    2004-01-01

    When selecting produced water treatment technologies, one should focus on reducing the major contributors to the total environmental impact. These are dispersed oil and semi-soluble hydrocarbons, alkylated phenols, and added chemicals. Experiments with produced water have been performed offshore on the Statoil operated platforms Gullfaks C and Statfjord B. These experiments were designed to find how much of the environmentally relevant compounds were dissolved in the water phase and not associated to the dispersed oil in the produced water. Results show that the distribution between the dispersed oil and the water phase varies highly for the different components groups. For example the concentration of PAHs and the C6-C9 alkylated phenols is strongly correlated to the content of dispersed oil. Therefore, the technologies enhancing the removal of dispersed oil have a higher potential for reducing the environmental impact of the produced water than previously considered

  10. Treatment of Oil & Gas Produced Water.

    Energy Technology Data Exchange (ETDEWEB)

    Dwyer, Brian P. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2016-02-01

    Production of oil and gas reserves in the New Mexico Four Corners Region results in large volumes of "produced water". The common method for handling the produced water from well production is re-injection in regulatory permitted salt water disposal wells. This is expensive (%7E $5/bbl.) and does not recycle water, an ever increasingly valuable commodity. Previously, Sandia National Laboratories and several NM small business tested pressure driven membrane-filtration techniques to remove the high TDS (total dissolved solids) from a Four Corners Coal Bed Methane produced water. Treatment effectiveness was less than optimal due to problems with pre-treatment. Inadequate pre-treatment allowed hydrocarbons, wax and biological growth to foul the membranes. Recently, an innovative pre-treatment scheme using ozone and hydrogen peroxide was pilot tested. Results showed complete removal of hydrocarbons and the majority of organic constituents from a gas well production water. ACKNOWLEDGEMENTS This report was made possible through funding from the New Mexico Small Business Administration (NMSBA) Program at Sandia National Laboratories. Special thanks to Juan Martinez and Genaro Montoya for guidance and support from project inception to completion. Also, special thanks to Frank McDonald, the small businesses team POC, for laying the ground work for the entire project; Teresa McCown, the gas well owner and very knowledgeable- fantastic site host; Lea and Tim Phillips for their tremendous knowledge and passion in the oil & gas industry.; and Frank Miller and Steve Addleman for providing a pilot scale version of their proprietary process to facilitate the pilot testing.

  11. Oil and gas development in the United States in the early 1990`s: An expanded role for independent producers

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-10-01

    Since 1991, the major petroleum companies` foreign exploration and development expenditures have exceeded their US exploration and development expenditures. The increasing dependence of US oil and gas development on the typically much smaller nonmajor companies raises a number of issues. Did those companies gain increased prominence largely through the reduced commitments of the majors or have they been significantly adding to the US reserve base? What are the characteristics of surviving and growing producers compared with companies exiting the US oil and gas business? Differences between majors` development strategies and those of other US oil and gas producers appear considerable. As the mix of exploration and development strategies in US oil and gas increasingly reflects the decisions of smaller, typically more specialized producers, what consequences can be seen regarding the costs of adding to US reserves? How are capital markets accessed? Are US oil and gas investments by the nonmajors likely to be undertaken only with higher costs of capital? This report analyzes these issues. 20 figs., 6 tabs.

  12. Recycling used palm oil and used engine oil to produce white bio oil, bio petroleum diesel and heavy fuel

    Science.gov (United States)

    Al-abbas, Mustafa Hamid; Ibrahim, Wan Aini Wan; Sanagi, Mohd. Marsin

    2012-09-01

    Recycling waste materials produced in our daily life is considered as an additional resource of a wide range of materials and it conserves the environment. Used engine oil and used cooking oil are two oils disposed off in large quantities as a by-product of our daily life. This study aims at providing white bio oil, bio petroleum diesel and heavy fuel from the disposed oils. Toxic organic materials suspected to be present in the used engine oil were separated using vacuum column chromatography to reduce the time needed for the separation process and to avoid solvent usage. The compounds separated were detected by gas chromatography-mass spectrometry (GC-MS) and found to contain toxic aromatic carboxylic acids. Used cooking oils (thermally cracked from usage) were collected and separated by vacuum column chromatography. White bio oil produced was examined by GC-MS. The white bio oil consists of non-toxic hydrocarbons and is found to be a good alternative to white mineral oil which is significantly used in food industry, cosmetics and drugs with the risk of containing polycyclic aromatic compounds which are carcinogenic and toxic. Different portions of the used cooking oil and used engine were mixed to produce several blends for use as heavy oil fuels. White bio oil was used to produce bio petroleum diesel by blending it with petroleum diesel and kerosene. The bio petroleum diesel produced passed the PETRONAS flash point and viscosity specification test. The heat of combustion of the two blends of heavy fuel produced was measured and one of the blends was burned to demonstrate its burning ability. Higher heat of combustion was obtained from the blend containing greater proportion of used engine oil. This study has provided a successful recycled alternative for white bio oil, bio petroleum fuel and diesel which can be an energy source.

  13. Thermal Cracking of Jatropha Oil with Hydrogen to Produce Bio-Fuel Oil

    Directory of Open Access Journals (Sweden)

    Yi-Yu Wang

    2016-11-01

    Full Text Available This study used thermal cracking with hydrogen (HTC to produce bio-fuel oil (BFO from jatropha oil (JO and to improve its quality. We conducted HTC with different hydrogen pressures (PH2; 0–2.07 MPa or 0–300 psig, retention times (tr; 40–780 min, and set temperatures (TC; 623–683 K. By applying HTC, the oil molecules can be hydrogenated and broken down into smaller molecules. The acid value (AV, iodine value, kinematic viscosity (KV, density, and heating value (HV of the BFO produced were measured and compared with the prevailing standards for oil to assess its suitability as a substitute for fossil fuels or biofuels. The results indicate that an increase in PH2 tends to increase the AV and KV while decreasing the HV of the BFO. The BFO yield (YBFO increases with PH2 and tr. The above properties decrease with increasing TC. Upon HTC at 0.69 MPa (100 psig H2 pressure, 60 min time, and 683 K temperature, the YBFO was found to be 86 wt%. The resulting BFO possesses simulated distillation characteristics superior to those of boat oil and heavy oil while being similar to those of diesel oil. The BFO contains 15.48% light naphtha, 35.73% heavy naphtha, 21.79% light gas oil, and 27% heavy gas oil and vacuum residue. These constituents can be further refined to produce gasoline, diesel, lubricants, and other fuel products.

  14. Do Oil-Producing Countries Have Normal Oil Overconsumption? An Investigation of Economic Growth and Energy Subsidies

    Directory of Open Access Journals (Sweden)

    Seyed Reza Mirnezami

    2015-07-01

    Full Text Available The data shows that oil-producing countries have low oil retail prices and low economic growth compared with other countries. Considering that oil-producing countries experience high oil consumption and low economic growth, it is possible to argue that economic growth is not an appropriate justification for oil consumption and that the main cause for high oil consumption is the low retail price. In addition, it should be noted that the global environmental movement against increasing greenhouse gas emissions—for example, the Kyoto 1998 agreement—seems to have had no effect on oil consumption in oil-producing countries.

  15. Biopretreatment of palm oil mill effluent by thermotolerant polymer-producing fungi

    Directory of Open Access Journals (Sweden)

    Masao Ukita

    2001-11-01

    Full Text Available Palm oil industry is one of the three major agro-industries in Southern Thailand and generates large quantities of effluent with high organic matter (BOD and COD values of 58,000 and 110,000 mg/l, respectively, total solids and suspended solids (70,000 and 40,000 mg/l, respectively, oil & grease (25,600 mg/l, and has a low pH (4.5. Conventional anaerobic ponding system is normally employed in palm oil mills to treat the effluent. To increase its efficiency, biopretreatment to remove the organic matter and oil & grease by thermotolerant polymer-producing fungi was investigated. The palm oil mill effluent (POME was treated by the two thermotolerant polymer-producing fungi, Rhizopus sp. ST4 and Rhizopus sp. ST29, at 45ºC under aseptic and septic conditions. Rhizopus sp. ST4 gave the same oil & grease removal (84.2% under both conditions but COD removal under septic condition (62.2% was 8.8% higher than that under aseptic condition (53.4%. On the contrary, Rhizopus sp. ST 29 under aseptic condition showed 11% and 25.4% higher oil & grease removal (91.4% and COD removal (66.0% than those under septic condition. Comparison between the two isolates under aseptic condition revealed that Rhizopus sp. ST29 exhibited higher oil & grease removal (91.4% as well as COD removal (66.0% than those of Rhizopus sp. ST4 (84.2% and 53.4%, respectively. Under septic condition, Rhizopus sp. ST4 gave higher oil & grease removal (84.2% and COD removal (62.2% than did Rhizopus sp. ST 29 (80.5 and 40.6%, respectively.

  16. Yeast: A new oil producer?

    Directory of Open Access Journals (Sweden)

    Beopoulos Athanasios

    2012-01-01

    Full Text Available The increasing demand of plant oils or animal fat for biodiesel and specific lipid derivatives for the oleochemical field (such as lubricants, adhesives or plastics have created price imbalance in both the alimentary and energy field. Moreover, the lack of non-edible oil feedstock has given rise to concerns on land-use practices and on oil production strategies. Recently, much attention has been paid to the exploitation of microbial oils. Most of them present lipid profiles similar in type and composition to plants and could therefore have many advantages as are no competitive with food, have short process cycles and their cultivation is independent of climate factors. Among microorganisms, yeasts seem to be very promising as they can be easily genetically enhanced, are suitable for large-scale fermentation and are devoid of endotoxins. This review will focus on the recent understanding of yeasts lipid metabolism, the succeeding genetic engineering of the lipid pathways and the recent developments on fermentation techniques that pointed out yeasts as promising alternative producers for oil or plastic.

  17. Do Oil-Producing Countries Have Normal Oil Overconsumption? An Investigation of Economic Growth and Energy Subsidies

    OpenAIRE

    Seyed Reza Mirnezami

    2015-01-01

    The data shows that oil-producing countries have low oil retail prices and low economic growth compared with other countries. Considering that oil-producing countries experience high oil consumption and low economic growth, it is possible to argue that economic growth is not an appropriate justification for oil consumption and that the main cause for high oil consumption is the low retail price. In addition, it should be noted that the global environmental movement against increasing greenhou...

  18. ECONOMIC CONSEQUENCES OF PEAK OIL FOR THE MAJOR MULTINATIONAL OIL AND GAS COMPANIES

    Directory of Open Access Journals (Sweden)

    Antonio García-Amate

    2018-03-01

    Full Text Available The main goal of this work is to analyze the financial statements of the five major multinational oil and gas companies, for the 2011-2015 period, in the framework of the peak oil phenomenon. Peak oil can affect key financial indicators (e.g., earnings volatility, leverage that are used by managers, investors, and stockholders and which may potentially lead to changes in the decision making by management. Our results show that the decline in oil production affects the decisions about investment in new oil wells, leverage, dividends paid, shares purchased and net income involving the five major companies. In addition, we study the evolution of oil prices, and its influence in several items of the financial statements. Even though oil prices were at high levels during 2011-2014, however, the net income of the five companies actually declined due to the impact of peak oil. Finally, data for the last year studied (2015 indicate a general deterioration in return ratios and other accounting variables. Although the new investments should have been profitable, they have been influenced by peak oil, compromising the economic position of the companies. The advice to these companies would be to relax their investments, especially during a period of falling oil prices. Company managers need to recognize the prolonged duration of peak oil and price trends to promote profitability recovery decisions.

  19. Canadian Occidental joins Hunt as Yemen oil producer

    International Nuclear Information System (INIS)

    Gurney, J.

    1994-01-01

    On 23 September 1993, the Canadian Occidental Petroleum Company initiated the export of 120,000 b/d (barrels a day) of low sulphur, medium gravity crude oil from its Masila Block concession in Yemen. The oil is transported from Masila via a pipeline built by CanOxy and its partners to a new terminal at Ash Shihr, near Mukalla, in the Gulf of Aden. CanOxy is the third operator oil company to produce oil commercially in Yemen. The first, the Hunt Oil Company, began production in December 1987 and its output now totals about 187,000 b/d. The second, Nimir Petroleum, a Saudi venture which took over the facilities developed in the 1980s by two Soviet companies, is currently producing about 10,000 b/d and expects to increase its output to 25,000 b/d during this year. (Author)

  20. Advanced Membrane Filtration Technology for Cost Effective Recovery of Fresh Water from Oil & Gas Produced Brine

    Energy Technology Data Exchange (ETDEWEB)

    David B. Burnett

    2004-09-29

    Produced water is a major waste generated at the oil and natural gas wells in the state of Texas. This water could be a possible source of new fresh water to meet the growing demands of the state after treatment and purification. Treatment of brine generated in oil fields or produced water with an ultrafiltration membranes were the subject of this thesis. The characterization of ultrafiltration membranes for oil and suspended solids removal of produced water, coupled with the reverse osmosis (RO) desalination of brine were studied on lab size membrane testing equipment and a field size testing unit to test whether a viable membrane system could be used to treat produced water. Oil and suspended solids were evaluated using turbidity and oil in water measurements taken periodically. The research considered the effect of pressure and flow rate on membrane performance of produced water treatment of three commercially available membranes for oily water. The study also analyzed the flux through the membrane and any effect it had on membrane performance. The research showed that an ultrafiltration membrane provided turbidity removal of over 99% and oil removal of 78% for the produced water samples. The results indicated that the ultrafiltration membranes would be asset as one of the first steps in purifying the water. Further results on selected RO membranes showed that salt rejection of greater than 97% could be achieved with satisfactory flux and at reasonable operating cost.

  1. Isolation of Biosurfactant Producing Bacteria from Oil Reservoirs

    OpenAIRE

    A Tabatabaee, M Mazaheri Assadi, AA Noohi,VA Sajadian

    2005-01-01

    Biosurfactants or surface-active compounds are produced by microoaganisms. These molecules reduce surface tension both aqueous solutions and hydrocarbon mixtures. In this study, isolation and identification of biosurfactant producing bacteria were assessed. The potential application of these bacteria in petroleum industry was investigated. Samples (crude oil) were collected from oil wells and 45 strains were isolated. To confirm the ability of isolates in biosurfactant production, haemolysis ...

  2. Wage Inequality and Violent Protests in Oil/Gas Producing Countries

    Science.gov (United States)

    Nuraliyev, Nurlan

    This work examines contrasting claims made by academic scholars on the relationship between income inequality and political discontent. Does income inequality directly cause social unrest or is this relationship conditional on the level of democratic development? Using the data from 55 oil/gas producing countries between 2010-2013, the author finds: 1) income disparity between an average income per capita of local population and an average income of foreign labor employed in the oil/gas industry results in higher number of violent protests in more democratic oil/gas producing societies; 2) wage disparity between local and foreign labor in the oil/gas industry is associated with higher number of protests in this industry in more democratic oil/gas producing states.

  3. Flavor profiles of monovarietal virgin olive oils produced in the Oriental region of Morocco

    Directory of Open Access Journals (Sweden)

    Mansouri Farid

    2017-09-01

    Full Text Available The purpose of this study is the evaluation of flavor profiles of monovarietal virgin olive oils (VOO produced in the Oriental region of Morocco via the characterization of volatile compounds, using SPME-GC/MS technique, and the determination of total phenolic content (colorimetric method. The study concerns oils of three European olive cultivars (Arbosana, Arbequina and Koroneiki which were recently introduced in Morocco under irrigated high-density plantation system. GC/MS aroma profiles of analyzed VOOs showed the presence of 35 volatile compounds. The major compounds in such oils are C6 compounds produced from linoleic and linolenic acids via lipoxygenase pathway such as trans-2-hexenal, cis-2-hexenal, cis-3-hexen-1-ol, trans-3-hexen-1-ol, trans-3-hexen-1-ol acetate, hexanal and 1-hexanol in different proportions depending on the cultivar (p < 0.05. In addition, statistical analyses indicate that the analyzed VOOs have different aroma profiles. Arbequina oil has a high proportion of compounds with sensory notes “green” and “sweet” giving it a fruity sensation compared to Arbosana and Koroneiki. In parallel, Arbosana and Koroneiki oils are rich in phenolic compounds and provide relatively bitter and pungent tastes to these oils.

  4. Biosurfactant Producing Microbes from Oil Contaminated Soil - Isolation, Screening and Characterization

    OpenAIRE

    , A Pandey; , D Nandi; , N Prasad; , S Arora

    2016-01-01

    Th1s paper bas1cally deals W1th 1solat10n, productıon and characterızatıon of biosurfactant producing microbes from oil contaminated soil sample. In this paper, we are comparing and discussing different methods to screen & characterize microbes from soil which can degrade oil due to their biosurfactant producing activity which helps in reduction of surface tension of oil. Oils used to check the biosurfactant activity of microbes, were engine oil and vegetable oil. Further isolation of...

  5. Optimization of Malaxation Process using Major Aroma Compounds in Virgin Olive Oil

    Directory of Open Access Journals (Sweden)

    Serife Cevik

    Full Text Available ABSTRACT Optimization of major aroma compounds in olive oils produced from fruits at three maturity stages wasstudied. A central composite design was used for the optimization of malaxation conditions of temperature and times, each at five levels with 13 runs including five central points. The responses of interest were trans-2-hexenal and hexanal, which were investigated and their contents were optimized. A full quadratic second order regression model including the linear, quadratic, and two factor interaction effects was proposed to explain the variation in the contents of target compounds depending on the malaxation conditions. Adequacies of models were evaluated by checking regression coefficients for each model. Models were found to work with high success for trans-2-hexenal prediction for oils from fruits at both purple and black stages, whereas the model for hexanalwas only in black stage oil. Their regression coefficients were higher than 0.86. Influences of time and temperature for the malaxation process were found to be significant for the transition of major aroma compounds from the fruit matrix to olive oil. The optimum conditions of temperature and time pairs to maximize trans-2-hexenal and hexanal was found to be 23°C/31 minutes for black olive and to maximize only trans-2-hexenal was also 29°C/41 minutes for purple olive.

  6. Preliminary evaluation of fuel oil produced from pyrolysis of waste ...

    African Journals Online (AJOL)

    It could be refined further to produce domestic kerosene and gasoline. The physical and structural properties of the fuel oil produced compared favorably with that of Aviation fuel JP-4 (a wide-cut US Air force fuel). Presently African countries are importing aviation fuels. The fuel oil produced from the pyrolysis of waste water ...

  7. Genome Annotation and Transcriptomics of Oil-Producing Algae

    Science.gov (United States)

    2015-03-16

    AFRL-OSR-VA-TR-2015-0103 GENOME ANNOTATION AND TRANSCRIPTOMICS OF OIL-PRODUCING ALGAE Sabeeha Merchant UNIVERSITY OF CALIFORNIA LOS ANGELES Final...2010 To 12-31-2014 4. TITLE AND SUBTITLE GENOME ANNOTATION AND TRANSCRIPTOMICS OF OIL-PRODUCING ALGAE 5a. CONTRACT NUMBER FA9550-10-1-0095 5b...NOTES 14. ABSTRACT Most algae accumulate triacylglycerols (TAGs) when they are starved for essential nutrients like N, S, P (or Si in the case of some

  8. TECHNOLOGY TRANSFER TO U.S. INDEPENDENT OIL AND NATURAL GAS PRODUCERS

    Energy Technology Data Exchange (ETDEWEB)

    Unknown

    2003-04-30

    The Petroleum Technology Transfer Council (PTTC) continued pursuing its mission of helping U.S. independent oil and natural gas producers make timely, informed technology decisions. Networking opportunities that occur with a Houston Headquarters (HQ) location are increasing name awareness. Focused efforts by Executive Director Don Duttlinger to interact with large independents, national service companies and some majors are continuing to supplement the support base of the medium to smaller industry participants around the country. PTTC is now involved in many of the technology-related activities that occur in high oil and natural gas activity areas. Access to technology remains the driving force for those who do not have in-house research and development capabilities and look to the PTTC to provide services and options for increased efficiency.

  9. Developments in the strategic planning of the major oil companies

    International Nuclear Information System (INIS)

    Jenkins, Gilbert

    2000-01-01

    This paper focuses on the changes in strategic planning of the major oil companies since the 1970s, and considers the reorganisations of the companies, and upstream and downstream planning. New directions for the major companies downstream operation in the retail and aviation sectors, and the influence of the BP/AMOCO/ARCO/BURMAH, EXXON/MOBIL and TOTAL/FINA/ELF mergers on the international oil industry are explored. Tables illustrating the earnings of the major oil companies for upstream and downstream operations, and chemicals in 1999, and for BP UK exploration and production, and refining and marketing profits (quarterly) for 1983-2000 are presented

  10. Exploring oil market dynamics: a system dynamics model and microworld of the oil producers

    Energy Technology Data Exchange (ETDEWEB)

    Morecroft, J.D.W. [London Business School (United Kingdom); Marsh, B. [St Andrews Management Institute, Fife (United Kingdom)

    1997-11-01

    This chapter focuses on the development of a simulation model of global oil markets by Royal Dutch/Shell Planners in order to explore the implications of different scenarios. The model development process, mapping the decision making logic of the oil producers, the swing producer making enough to defend the intended price, the independents, quota setting, the opportunists, and market oil price and demand are examined. Use of the model to generate scenarios development of the model as a gaming simulator for training, design of the user interface, and the value of the model are considered in detail. (UK)

  11. Optimization of Malaxation Process using Major Aroma Compounds in Virgin Olive Oil

    OpenAIRE

    Cevik,Serife; Ozkan,Gulcan; Kıralan,Mustafa

    2016-01-01

    ABSTRACT Optimization of major aroma compounds in olive oils produced from fruits at three maturity stages wasstudied. A central composite design was used for the optimization of malaxation conditions of temperature and times, each at five levels with 13 runs including five central points. The responses of interest were trans-2-hexenal and hexanal, which were investigated and their contents were optimized. A full quadratic second order regression model including the linear, quadratic, and two...

  12. Fuel properties of biodiesel produced from the crude fish oil from the soapstock of marine fish

    Energy Technology Data Exchange (ETDEWEB)

    Lin, Cherng-Yuan; Li, Rong-Ji [Department of Marine Engineering, National Taiwan Ocean, University, Keelung 20224 (China)

    2009-01-15

    The soapstock of a mixture of marine fish was used as the raw material to produce the biodiesel in this study. The soapstock was collected from discarded fish products. Crude fish oil was squeezed from the soapstock of the fish and refined by a series of processes. The refined fish oil was transesterified to produce biodiesel. The fuel properties of the biodiesel were analyzed. The experimental results showed that oleic acid (C18:1) and palmitic acid (C16:0) were the two major components of the marine fish-oil biodiesel. The biodiesel from the mixed marine fish oil contained a significantly greater amount of polyunsaturated fatty acids than did the biodiesel from waste cooking oil. In addition, the marine fish-oil biodiesel contained as high as 37.07 wt.% saturated fatty acids and 37.3 wt.% long chain fatty acids in the range between C20 and C22. Moreover, the marine fish-oil biodiesel appeared to have a larger acid number, a greater increase in the rate of peroxidization with the increase in the time that it was stored, greater kinematic viscosity, higher heating value, higher cetane index, more carbon residue, and a lower peroxide value, flash point, and distillation temperature than those of waste cooking-oil biodiesel. (author)

  13. Upgrading of Intermediate Bio-Oil Produced by Catalytic Pyrolysis

    Energy Technology Data Exchange (ETDEWEB)

    Abdullah, Zia [Battelle Memorial Inst., Columbus, OH (United States); Chadwell, Brad [Battelle Memorial Inst., Columbus, OH (United States); Taha, Rachid [Battelle Memorial Inst., Columbus, OH (United States); Hindin, Barry [Battelle Memorial Inst., Columbus, OH (United States); Ralston, Kevin [Battelle Memorial Inst., Columbus, OH (United States)

    2015-06-30

    The objectives of this project were to (1) develop a process to upgrade catalytic pyrolysis bio-oil, (2) investigate new upgrading catalysts suited for upgrading catalytic pyrolysis bio-oil, (3) demonstrate upgrading system operation for more than 1,000 hours using a single catalyst charge, and (4) produce a final upgraded product that can be blended to 30 percent by weight with petroleum fuels or that is compatible with existing petroleum refining operations. This project has, to the best of our knowledge, for the first time enabled a commercially viable bio-oil hydrotreatment process to produce renewable blend stock for transportation fuels.

  14. Potential use of produced oil sample analysis to monitor SAGD performance

    Energy Technology Data Exchange (ETDEWEB)

    Li, Z. [Society of Petroleum Engineers, Canadian Section, Calgary, AB (Canada)]|[Nexen Petroleum International, Calgary, AB (Canada); Wollen, C. [Society of Petroleum Engineers, Canadian Section, Calgary, AB (Canada)]|[OPTI-Nexen Inc., Calgary, AB (Canada); Yang, P.; Fustic, M. [Nexen Petroleum International, Calgary, AB (Canada)

    2008-10-15

    Oil viscosity and compositional gradients can affect the performance of steam injection recovery processes. In this study, reservoir simulations were conducted to investigate the effects of viscosity variation with depth on steam assisted gravity drainage (SAGD) processes and produced oil characteristics. The 2-D reservoir model consisted of a reservoir with a 40 m clean sand matrix, overtopped with interbedded shales and sand. The oil phase was comprised of 2 pseudo-components representing top and bottom bitumens. Viscosities and concentrations of the pseudo-components were calculated using linear mixing rules. Four different viscosity distribution scenarios were examined. Conceptual 3-D models were then constructed to examine the characteristics of produced oil samples in scenarios with shale barriers extending down the well directions and blocking parts of the reservoir. Results from the simulations showed that produced oil characteristics are related to the in situ profiles of reservoir flow barriers. Produced oil characteristics can be used in conjunction with oil rates, surface heave and other data to predict steam chamber development and detect the presence of baffles and barriers. The relationship between the SAGD steam chamber and variations in produced fluid characteristics were accurately characterized by the simulations. It was concluded that the approach can be used to monitor SAGD steam chamber growth. 10 refs., 1 tab., 19 figs.

  15. Biomarker chemistry and flux quantification methods for natural petroleum seeps and produced oils, offshore southern California

    Science.gov (United States)

    Lorenson, T.D.; Leifer, Ira; Wong, Florence L.; Rosenbauer, Robert J.; Campbell, Pamela L.; Lam, Angela; Hostettler, Frances D.; Greinert, Jens; Finlayson, David P.; Bradley, Eliza S.; Luyendyk, Bruce P.

    2011-01-01

    Sustained, natural oil seepage from the seafloor is common off southern California, and is of great interest to resource managers, who are tasked with distinguishing natural from anthropogenic oil sources. The major purpose of this study was to build upon the work previously funded by the Bureau of Ocean Energy Management (BOEM) and the U.S. Geological Survey (USGS) that has refined the oil-fingerprinting process to enable differentiation of the highly similar Monterey Formation oils from Outer Continental Shelf (OCS) production and adjacent natural seeps. In these initial studies, biomarker and stable carbon isotope ratios were used to infer the age, lithology, organic-matter input, and depositional environment of the source rocks for 388 samples of produced crude oil, seep oil, and tarballs mainly from coastal California. The analysis resulted in a predictive model of oil source families that could be applied to samples of unknown origin.

  16. The Other Major 2010 Oil Spill: Oil weathering after the Kalamazoo River Dilbit Spill

    Science.gov (United States)

    Swarthout, B.; Reddy, C. M.; Nelson, R. K.; Hamilton, S. K.; Aeppli, C.; Valentine, D. L.; Fundaun, S. E.; Oliveira, A. H.

    2016-02-01

    Diluted bitumen (dilbit) from the oil sands (tar sands) of western Canada is increasingly being transported to US markets. North America's largest inland oil spill and the first major oil sands spill in a freshwater environment occurred in 2010, when at least 843,000 gallons leaked from a pipeline into the Kalamazoo River of southwest Michigan. Cleanup of this oil was unusually difficult and protracted, lasting through 2014 and costing over a billion dollars, largely because a substantial fraction of the oil became submersed and deposited in slack water areas over 60 km of river channel, reservoirs, and floodplain backwaters. To investigate the fate of the spilled dilbit from the 2010 Kalamazoo River release, black rings, presumably oil residues, on the bark of dead trees were collected in 2015. These residues were deposited on the trees during high flood levels that have not been observed since the spill and represent an opportunity to constrain weathering processes excluding dissolution. This material contained a major non-GC amenable fraction of 90-95%, presumably oxygenated hydrocarbons. The GC amenable portion was consistent with laboratory weathered dilbit. We used a variety of analytical tools to characterize the dilbit residues, as well as to identify dilbit weathering processes that occurred since the spill.

  17. Oil producers facing a common challenge

    International Nuclear Information System (INIS)

    Galal, E.E.

    1992-01-01

    Among the numerous challenges facing our modern world, perhaps the most urgent and dominant are energy related. From the perspective of developing countries they are, in order of priorities, development, energy security and environment. Oil covers above 38% of the global commercial energy needs and gas about 20%. In some commanding sectors of the economy, like transport, oil is for now virtually the irreplaceable source of energy. In addition, oil and gas are two valuable primary materials of the chemical industry. It also happens that oil consumption is one of the sources of environmental pollution through the emission of CO 2 . Utilisation of the world's finite fossil energy resources (88% of total commercial energy) in the service of development reflects all the negative attributes of the mismanagement of the global economy, exemplified by waste, inefficiency, unfair terms of trade, market instability and short-sighted policies. These serious inequities have been further compounded by the growing menace of environmental and climatic degradation. In dealing with the interactions between these three complex systems, i.e., energy, environment and development, it is important for oil producers to delineate their priorities clearly, if they are to disentangle credible common goals for an international convention. (author)

  18. Technology transfer to US oil producers: A policy tool to sustain or increase oil production

    Energy Technology Data Exchange (ETDEWEB)

    Dowd, W. T.

    1990-03-01

    The Department of Energy provided the Interstate Oil Compact Commission with a grant to identify and evaluate existing technology transfer channels to operators, to devise and test improvements or new technology transfer channels and to make recommendations as to how the Department of Energy's oil and gas technology transfer methods could be improved. The IOCC conducted this effort in a series of four tasks: a structural analysis to characterize the oil producing industry according to operator production size class, geographic location, awareness and use of reservoir management technologies, and strategies for adding reserves and replacing produced reserves; targeted interviews conducted with some 300 oil and gas industry participants to identify current technology transfer channels and their relative usefulness for various classes of industry participants; a design and testing phase, in which the IOCC critiqued the current technology transfer structure, based on results of the structural analysis and targeted interviews, and identified several strategies for improvement; and an evaluation of existing state outreach programs to determine whether they might provide a model for development of additional outreach programs in other producing states.

  19. Oil majors under states pressure: two examples in the Caspian basin

    International Nuclear Information System (INIS)

    Lussac, Samuel; Raballand, Gael

    2011-01-01

    All over the world, and especially in developing countries, governments strive to strengthen national oil companies over oil and gas majors. The Caspian, and notably Azerbaijan and Kazakhstan, is not an exception to this current trend. This article sheds light on the leverages both Azerbaijani and Kazakhstani governments have used to increase pressure over oil and gas multinationals. In a first step, they both established a publicly-owned integrated company managed by the presidential entourage. Then, Azerbaijan and Kazakhstan have applied various instruments. Baku has sought to increase its own oil production to decrease the role of majors while Astana has preferred to use ecological, fiscal, legal and logistical leverages. However, in both cases, the outcome has been rather similar since the increasing pressure over majors has not necessarily led to benefit local populations

  20. Major oil spills, St. Croix, U.S. Virgin Islands

    International Nuclear Information System (INIS)

    Bills, C.E.; Whiting, D.C.

    1990-01-01

    The destruction caused by Hurricane Hugo resulted in two major oil spills on the island of St. Croix, U.S. Virgin Islands. Roughly 10,000 barrels of oil were discharged from damaged storage tanks at the Hess Oil Virgin Island Corporation and 14,000 barrels of oil were discharged from the Virgin Islands Water and Power Authority facility in Christiansted. Pollution responders overcame the lack of power, water, food lodging, communications and transportation to perform an effective cleanup of these spills. This paper presents details of the pollution response effort as coordinated by the Federal On Scene Coordinator

  1. Sub-Sahara's second largest oil producer

    Energy Technology Data Exchange (ETDEWEB)

    Clarke, C

    1991-05-01

    With the prospects for peace in Angola following the settlement of the civil war, the oil producing potential for the country is briefly reviewed. Topics covered include the problems of economic growth and development because of the civil war and communist ideology, US foreign policy, production sharing, military expenditure and economic planning. (UK).

  2. Operational Aspects of Fiscal Policy in Oil-Producing Countries

    OpenAIRE

    Steven A Barnett; Rolando Ossowski

    2002-01-01

    Oil-producing countries face challenges arising from the fact that oil revenue is exhaustible, volatile, and uncertain, and largely originates from abroad. Reflecting these challenges, the paper proposes some important general principles for the formulation and assessment of fiscal policy in these countries. The main findings can be summarized in some key guidelines: the non-oil balance should feature prominently in the formulation of fiscal policy; it should generally be adjusted gradually; ...

  3. Isolation of Biosurfactant Producing Bacteria from Oil Reservoirs

    Directory of Open Access Journals (Sweden)

    A Tabatabaee, M Mazaheri Assadi, AA Noohi,VA Sajadian

    2005-01-01

    Full Text Available Biosurfactants or surface-active compounds are produced by microoaganisms. These molecules reduce surface tension both aqueous solutions and hydrocarbon mixtures. In this study, isolation and identification of biosurfactant producing bacteria were assessed. The potential application of these bacteria in petroleum industry was investigated. Samples (crude oil were collected from oil wells and 45 strains were isolated. To confirm the ability of isolates in biosurfactant production, haemolysis test, emulsification test and measurement of surface tension were conducted. We also evaluated the effect of different pH, salinity concentrations, and temperatures on biosurfactant production. Among importance features of the isolated strains, one of the strains (NO.4: Bacillus.sp showed high salt tolerance and their successful production of biosurfactant in a vast pH and temperature domain and reduced surface tension to value below 40 mN/m. This strain is potential candidate for microbial enhanced oil recovery. The strain4 biosurfactant component was mainly glycolipid in nature.

  4. Producing Biosurfactants from Purified Microorganisms Obtained from Oil-contaminated Soil

    Directory of Open Access Journals (Sweden)

    Nader Mokhtarian

    2010-09-01

    Full Text Available Contamination of soil by crude oil can pose serious problems to ecosystems. Soil washing by solutions containing biosurfactants is one of the most efficient methods for the remediation of contaminated soil by crude oil because it removes not only the crude oil but also heavy metals. In this study, five soil samples were taken from fields exposed to oil compounds over the years in order to produce biosurfactants from microorganisms that were capable of degrading oil compounds. Sixteen such microorganisms were isolated. After cultivation, their emulsification strength was examined using E24 test. From among the experimental microorganisms, a gram-negative and rod-shape microorganism called A-12 showed the greatest value of the E24 test index (36%. For each liter of the culture medium containing 365 mg of microorganisms, 3 gr of the biosurfactant compound was produced and separated as dried powder. The purified biosurfactant was used in the soil washing process. Also, the insulated microorganisms were capable of degrading crude oil floating on wastewaters.

  5. Produced water: Market and global trends - oil production - water production - choice of technology

    International Nuclear Information System (INIS)

    Robertson, Steve

    2006-01-01

    The presentation discusses various aspects of the world oil production, the energy demand, the future oil supply, the oil prices and the production growth. Some problems with produced water are also discussed as well as aspects of the market for produced water technology (tk)

  6. ECOLOGICAL REGIONALIZATION METHODS OF OIL PRODUCING AREAS

    Directory of Open Access Journals (Sweden)

    Inna Ivanovna Pivovarova

    2017-01-01

    Full Text Available The paper analyses territory zoning methods with varying degrees of anthropogenic pollution risk. The summarized results of spatial analysis of oil pollution of surface water in the most developed oil-producing region of Russia. An example of GIS-zoning according to the degree of environmental hazard is presented. All possible algorithms of cluster analysis are considered for isolation of homogeneous data structures. The conclusion is made on the benefits of using combined methods of analysis for assessing the homogeneity of specific environmental characteristics in selected territories.

  7. Investigation of biosurfactant-producing indigenous microorganisms that enhance residue oil recovery in an oil reservoir after polymer flooding.

    Science.gov (United States)

    She, Yue-Hui; Zhang, Fan; Xia, Jing-Jing; Kong, Shu-Qiong; Wang, Zheng-Liang; Shu, Fu-Chang; Hu, Ji-Ming

    2011-01-01

    Three biosurfactant-producing indigenous microorganisms (XDS1, XDS2, XDS3) were isolated from a petroleum reservoir in the Daqing Oilfield (China) after polymer flooding. Their metabolic, biochemical, and oil-degradation characteristics, as well as their oil displacement in the core were studied. These indigenous microorganisms were identified as short rod bacillus bacteria with white color, round shape, a protruding structure, and a rough surface. Strains have peritrichous flagella, are able to produce endospores, are sporangia, and are clearly swollen and terminal. Bacterial cultures show that the oil-spreading values of the fermentation fluid containing all three strains are more than 4.5 cm (diameter) with an approximate 25 mN/m surface tension. The hydrocarbon degradation rates of each of the three strains exceeded 50%, with the highest achieving 84%. Several oil recovery agents were produced following degradation. At the same time, the heavy components of crude oil were degraded into light components, and their flow characteristics were also improved. The surface tension and viscosity of the crude oil decreased after being treated by the three strains of microorganisms. The core-flooding tests showed that the incremental oil recoveries were 4.89-6.96%. Thus, XDS123 treatment may represent a viable method for microbial-enhanced oil recovery.

  8. Carbonyl Compounds Produced by Vaporizing Cannabis Oil Thinning Agents.

    Science.gov (United States)

    Troutt, William D; DiDonato, Matthew D

    2017-11-01

    Cannabis use has increased in the United States, particularly the use of vaporized cannabis oil, which is often mixed with thinning agents for use in vaporizing devices. E-cigarette research shows that heated thinning agents produce potentially harmful carbonyls; however, similar studies have not been conducted (1) with agents that are commonly used in the cannabis industry and (2) at temperatures that are appropriate for cannabis oil vaporization. The goal of this study was to determine whether thinning agents used in the cannabis industry produce potentially harmful carbonyls when heated to a temperature that is appropriate for cannabis oil vaporization. Four thinning agents (propylene glycol [PG], vegetable glycerin [VG], polyethylene glycol 400 [PEG 400], and medium chain triglycerides [MCT]) were heated to 230°C and the resulting vapors were tested for acetaldehyde, acrolein, and formaldehyde. Each agent was tested three times. Testing was conducted in a smoking laboratory. Carbonyl levels were measured in micrograms per puff block. Analyses showed that PEG 400 produced significantly higher levels of acetaldehyde and formaldehyde than PG, MCT, and VG. Formaldehyde production was also significantly greater in PG compared with MCT and VG. Acrolein production did not differ significantly across the agents. PG and PEG 400 produced high levels of acetaldehyde and formaldehyde when heated to 230°C. Formaldehyde production from PEG 400 isolate was particularly high, with one inhalation accounting for 1.12% of the daily exposure limit, nearly the same exposure as smoking one cigarette. Because PG and PEG 400 are often mixed with cannabis oil, individuals who vaporize cannabis oil products may risk exposure to harmful formaldehyde levels. Although more research is needed, consumers and policy makers should consider these potential health effects before use and when drafting cannabis-related legislation.

  9. Growth Inhibition of Sulfate-Reducing Bacteria in Produced Water from the Petroleum Industry Using Essential Oils.

    Science.gov (United States)

    Souza, Pamella Macedo de; Goulart, Fátima Regina de Vasconcelos; Marques, Joana Montezano; Bizzo, Humberto Ribeiro; Blank, Arie Fitzgerald; Groposo, Claudia; Sousa, Maíra Paula de; Vólaro, Vanessa; Alviano, Celuta Sales; Moreno, Daniela Sales Alviano; Seldin, Lucy

    2017-04-19

    Strategies for the control of sulfate-reducing bacteria (SRB) in the oil industry involve the use of high concentrations of biocides, but these may induce bacterial resistance and/or be harmful to public health and the environment. Essential oils (EO) produced by plants inhibit the growth of different microorganisms and are a possible alternative for controlling SRB. We aimed to characterize the bacterial community of produced water obtained from a Brazilian petroleum facility using molecular methods, as well as to evaluate the antimicrobial activity of EO from different plants and their major components against Desulfovibrio alaskensis NCIMB 13491 and against SRB growth directly in the produced water. Denaturing gradient gel electrophoresis revealed the presence of the genera Pelobacter and Marinobacterium , Geotoga petraea , and the SRB Desulfoplanes formicivorans in our produced water samples. Sequencing of dsrA insert-containing clones confirmed the presence of sequences related to D. formicivorans . EO obtained from Citrus aurantifolia , Lippia alba LA44 and Cymbopogon citratus , as well as citral, linalool, eugenol and geraniol, greatly inhibited (minimum inhibitory concentration (MIC) = 78 µg/mL) the growth of D. alaskensis in a liquid medium. The same MIC was obtained directly in the produced water with EO from L. alba LA44 (containing 82% citral) and with pure citral. These findings may help to control detrimental bacteria in the oil industry.

  10. Growth Inhibition of Sulfate-Reducing Bacteria in Produced Water from the Petroleum Industry Using Essential Oils

    Directory of Open Access Journals (Sweden)

    Pamella Macedo de Souza

    2017-04-01

    Full Text Available Strategies for the control of sulfate-reducing bacteria (SRB in the oil industry involve the use of high concentrations of biocides, but these may induce bacterial resistance and/or be harmful to public health and the environment. Essential oils (EO produced by plants inhibit the growth of different microorganisms and are a possible alternative for controlling SRB. We aimed to characterize the bacterial community of produced water obtained from a Brazilian petroleum facility using molecular methods, as well as to evaluate the antimicrobial activity of EO from different plants and their major components against Desulfovibrio alaskensis NCIMB 13491 and against SRB growth directly in the produced water. Denaturing gradient gel electrophoresis revealed the presence of the genera Pelobacter and Marinobacterium, Geotoga petraea, and the SRB Desulfoplanes formicivorans in our produced water samples. Sequencing of dsrA insert-containing clones confirmed the presence of sequences related to D. formicivorans. EO obtained from Citrus aurantifolia, Lippia alba LA44 and Cymbopogon citratus, as well as citral, linalool, eugenol and geraniol, greatly inhibited (minimum inhibitory concentration (MIC = 78 µg/mL the growth of D. alaskensis in a liquid medium. The same MIC was obtained directly in the produced water with EO from L. alba LA44 (containing 82% citral and with pure citral. These findings may help to control detrimental bacteria in the oil industry.

  11. Turbidity and oil removal from oilfield produced water, middle oil company by electrocoagulation technique

    Directory of Open Access Journals (Sweden)

    Mohammed Thamer

    2018-01-01

    Full Text Available Huge quantity of produced water is salty water trapped in the oil wells rock and brought up along with oil or gas during production. It usually contains hydrocarbons as oil and suspended solids or turbidity. Therefore the aim of this study is to treat produced water before being discharge to surface water or re injected in oil wells. In this paper experimental results were investigated on treating produced water (which is obtained from Middle Oil Company-Iraq, through electrocoagulation (EC. The performance of EC was investigated for reduction of turbidity and oil content up to allowable limit. Effect of different parameters were studied; (pH, current density, distance between two electrodes, and electrolysis time. The experimental runs carried out by an electrocoagulation unit was assembled and installed in the lab and the reactor was made of a material Perspex, with a capacity of approximately 2.5 liters and dimensions were 20 cm in length, 14 cm in width and 16 cm height. The electrodes employed were made of commercial materials. The anode was a perforated aluminum rectangular plate with a thickness of 1.72 mm, a height of 60 mm and length of 140 mm and the cathode was a mesh iron. The current was used in the unit with different densities to test the turbidity removing efficiency (0.0025, 0.00633, 0.01266 and 0.0253 A/cm2.The experiment showed that the best turbidity removing was (10, 9.7, 9.2, 18 NTU respectively. The distance between the electrodes of the unit was 3cm. The present turbidity removing was 92.33%. A slight improvement of turbidity removing was shown when the distance between the electrodes was changed from 0.5 to 3 cm with fixation of current density. The best turbidity removing was 93.5% , (7.79 NTU when the distance between the electrodes were 1 cm. The experimental results found that concentration of oil had decreased to (10.7, 11.2, 11.7, 12.3 mg/l when different current densities (0.00253, 0.00633, 0.01266, 0.0253 A/cm2

  12. Characteristics of gas-liquid dynamics in operation of oil fields producing non-Newtonian crude oils

    Energy Technology Data Exchange (ETDEWEB)

    Mirzadzhanzade, A Kh; Khasaev, A M; Gurbanov, R S; Akhmedov, Z M

    1968-08-01

    Experimental studies have shown that crude oils from Azerbaidzhan, Uzbekistan, Tataria, Kazakhstan and other areas have anomalous properties under reservoir conditions. Such crude oils are non-Newtonian and (1) obey Darcys Law at low velocities; (2) obey an exponential law at higher velocities; and (3) obey a modified Darcys Law at most velocities. A discussion is given of (1) flow of non-Newtonian crude oils together with gas or water; (2) flow of non-Newtonian crude oils in well tubing; (3) behavior of wells producing non-Newtonian crude oils; and (4) pumping of non-Newtonian oils in wells. Experiments have shown that a visco-plastic liquid does not fill pump inlets completely; as the diameter of the pump inlet decreases so also does the degree of liquid filling. A statistical analysis of production data from 160 fields with Newtonian oil and 129 fields with non- Newtonian oil has shown that much higher production is obtained from fields with Newtonian crude oils.

  13. Isolation and Identification of Crude Oil Degrading and Biosurfactant Producing Bacteria from the Oil-Contaminated Soils of Gachsaran

    Directory of Open Access Journals (Sweden)

    Seyyedeh Zahra Hashemi

    2016-03-01

    Full Text Available Background and Objectives: Petroleum hydrocarbons are harmful to the environment, human health, and all other living creatures. Oil and its byproducts in contact with water block sunshine to phytoplanktons and thus break the food chain and damage the marine food source. This study aims to isolate the crude oil degrading and biosurfactant producing bacteria from the oil contaminated soils of Gachsaran, Iran. Materials and Methods: Isolation was performed in peptone-water medium with yeast extract. Oil displacement area, emulsification index and bacterial phylogeny using 16S rRNA analysis were studied. Results and Conclusion: Three isolates were able to degrade the crude oil. In the first day, there were two phases in the medium; after a few days, these three bacteria degraded the crude oil until there was only one phase left in the medium. One strain was selected as a superior strain by homogenizing until the medium became clear and transparent. This method confirmed that the strain produces biosurfactant. According to the morphological and biochemical tests, the strain isolated from the oil contaminated soils is a member of Bacillus subtilis, so to study the bacterial phylogeny and taxonomy of the strain, an analysis of 16S rRNA was carried out, and the phylogenic tree confirmed them. The results verified that oil contaminated soils are good source for isolation of the biosurfactant producing bacteria.

  14. Utilization of oil palm tree residues to produce bio-oil and bio-char via pyrolysis

    International Nuclear Information System (INIS)

    Abnisa, Faisal; Arami-Niya, Arash; Wan Daud, W.M.A.; Sahu, J.N.; Noor, I.M.

    2013-01-01

    Highlights: • About 14.72% of the total landmass in Malaysia was used for oil palm plantations. • Oil palm tree residues were pyrolyzed to produce bio-oil and bio-char. • The process was performed at a temperature of 500 °C and reaction time of 60 min. • Characterization of the products was performed. - Abstract: Oil palm tree residues are a rich biomass resource in Malaysia, and it is therefore very important that they be utilized for more beneficial purposes, particularly in the context of the development of biofuels. This paper described the possibility of utilizing oil palm tree residues as biofuels by producing bio-oil and bio-char via pyrolysis. The process was performed in a fixed-bed reactor at a temperature of 500 °C, a nitrogen flow rate of 2 L/min and a reaction time of 60 min. The physical and chemical properties of the products, which are important for biofuel testing, were then characterized. The results showed that the yields of the bio-oil and bio-char obtained from different residues varied within the ranges of 16.58–43.50 wt% and 28.63–36.75 wt%, respectively. The variations in the yields resulted from differences in the relative amounts of cellulose, hemicellulose, lignin, volatiles, fixed carbon, and ash in the samples. The energy density of the bio-char was found to be higher than that of the bio-oil. The highest energy density of the bio-char was obtained from a palm leaf sample (23.32 MJ/kg), while that of the bio-oil was obtained from a frond sample (15.41 MJ/kg)

  15. Hollow rods for the oil producing industry

    Energy Technology Data Exchange (ETDEWEB)

    Khalimova, L M; Elyasheva, M A

    1970-01-01

    Hollow sucker rods have several advantages over conventional ones. The hollow rods actuate the well pump and at the same time conduct produced fluids to surface. When paraffin deposition occurs, it can be minimized by injecting steam, hot oil or hot water into the hollow rod. Other chemicals, such as demulsifiers, scale inhibitors, corrosion inhibitors, etc., can also be placed in the well through the hollow rods. This reduces cost of preventive treatments, reduces number of workovers, increases oil production, and reduces cost of oil. Because the internal area of the rod is small, the passing liquids have a high velocity and thereby carry sand and dirt out of the well. This reduces pump wear between the piston and the plunger. Specifications of hollow rods, their operating characteristics, and results obtained with such rods under various circumstances are described.

  16. Kinetics of hydrocarbon extraction from oil shale using biosurfactant producing bacteria

    International Nuclear Information System (INIS)

    Haddadin, Malik S.Y.; Abou Arqoub, Ansam A.; Abu Reesh, Ibrahim; Haddadin, Jamal

    2009-01-01

    This study was done to extract hydrocarbon compounds from El-Lajjun oil shale using biosurfactant produced from two strains Rhodococcus erythropolis and Rhodococcus ruber. The results have shown that, optimal biosurfactant production was found using naphthalene and diesel as a carbon source for R. erthropolis and R. ruber, respectively. Optimum nitrogen concentration was 9 g/l and 7 g/l for R. erthropolis and R. ruber, respectively. Optimum K 2 HPO 4 to KH 2 PO 4 ratio, temperature, pH, and agitation speeds were 2:1, 37 deg. C, 7 and 200 rpm. Under optimal conditions R. erthropolis and R. ruber produced 5.67 and 6.9 g/l biosurfactant, respectively. Maximum recovery of oil achieved with hydrogen peroxide pre-treatment was 25% and 26% at biosurfactant concentration of 8 g/l and 4 g/l for R. erthropolis and R. ruber, respectively. The extent desorption of hydrocarbons from the pre-treated oil shale by biosurfactant were inversely related to the concentration of high molecular weight hydrocarbons, asphaltenes compounds. Pre- treatment of oil shale with hydrogen peroxide produced better improvement in aromatic compounds extraction in comparison with improvement which resulted from demineralization of the oil shale

  17. Thermal stability of butter oils produced from sheep’s non-pasteurized and pasteurized milk

    Directory of Open Access Journals (Sweden)

    FLAVIA POP

    Full Text Available The physical and chemical characteristics and thermal stability of butter oil produced from non-pasteurized and pasteurized sheep’s milk were studied. Thermal stability of samples was estimated by using the accelerated shelf-life testing method. Samples were stored at 50, 60 and 70oC in the dark and the reaction was monitored by measuring peroxide, thiobarbituric acid and free fatty acid values. The peroxide and thiobarbituric acid values increased as the temperature increased. The increase of acid values of the two samples was not significant. A slight increase in free fatty acid value showed that hydrolytic reactions were not responsible for the deterioration of butter oil samples in thermal stability studies. When compared, butter oil produced from pasteurized sheep’s milk has higher thermal stability than butter oil produced from non-pasteurized sheep’s milk. Although butter oil produced from non-pasteurized milk was not exposed to any heat treatment, the shelf-life of this product was lower than the shelf-life of butter oil produced from pasteurized sheep’s milk. Therefore, heat treatment for pasteurization did not affect the thermal stability of butter oil.

  18. Produced water ponds are an important source of aromatics and alcohols in Rocky Mountain oil and gas basins

    Science.gov (United States)

    Lyman, S. N.

    2017-12-01

    Most of the water extracted with oil and natural gas (i.e., produced water) is disposed of by injection into the subsurface. In the arid western United States, however, a significant portion of produced water is discharged in ponds for evaporative disposal, and produced water is often stored in open ponds prior to subsurface injection. Even though they are common in the West (Utah's Uinta Basin has almost 200 ha), produced water ponds have been excluded from oil and gas emissions inventories because little information about their emission rates and speciation is available. We used flux chambers and inverse plume modeling to measure emissions of methane, C2-C11 hydrocarbons, light alcohols, carbonyls, and carbon dioxide from oil and gas produced water storage and disposal ponds in the Uinta Basin and the Upper Green River Basin, Wyoming, during 2013-2017. Methanol was the most abundant organic compound in produced water (91 ± 2% of the total volatile organic concentration; mean ± 95% confidence interval) but accounted for only 25 ± 30% of total organic compound emissions from produced water ponds. Non-methane hydrocarbons, especially C6-C9 alkanes and aromatics, accounted for the majority of emitted organics. We were able to predict emissions of individual compounds based on water concentrations, but only to within an order of magnitude. The speciation and magnitude of emissions varied strongly across facilities and was influenced by water age, the presence or absence of oil sheens, and with meteorological conditions (especially ice cover). Flux chamber measurements were lower than estimates from inverse modeling techniques.Based on our flux chamber measurements, we estimate that produced water ponds are responsible for between 3 and 9% of all non-methane organic compound emissions in the Uinta Basin (or as much as 18% if we rely on our inverse modeling results). Emissions from produced water ponds contain little methane and are more reactive (i.e., they have

  19. Produced water management - clean and safe oil and gas production

    International Nuclear Information System (INIS)

    2006-01-01

    The conference contains 22 presentations on topics within pollution sources and abatement, discharge reductions, water analysis and monitoring, water production, treatment and injection, enhanced recovery, condensate water, produced water markets, separation technologies for oil/gas/condensate and water, oil removal from solids, environmental risks of oil and gas production and environmental impacts on ecosystems and fisheries. Some oil field case histories are presented. The main focus is on the northern areas such as the North Sea, the north Atlantic Ocean and the Barents Sea, and technological aspects (tk)

  20. Produced water management - clean and safe oil and gas production

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2006-07-01

    The conference contains 22 presentations on topics within pollution sources and abatement, discharge reductions, water analysis and monitoring, water production, treatment and injection, enhanced recovery, condensate water, produced water markets, separation technologies for oil/gas/condensate and water, oil removal from solids, environmental risks of oil and gas production and environmental impacts on ecosystems and fisheries. Some oil field case histories are presented. The main focus is on the northern areas such as the North Sea, the north Atlantic Ocean and the Barents Sea, and technological aspects (tk)

  1. Country analysis briefs: 1994. Profiles of major world energy producers, consumers, and transport centers

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-05-01

    Country Analysis Briefs: 1994 is a compilation of country profiles prepared by the Energy Markets and Contingency Information Division (EMCID) of the Office of Energy Markets and End Use. EMCID maintains Country Analysis Briefs (CABs) for specific countries or geographical areas that are important to world energy markets. As a general rule, CABs are prepared for all members of the Organization of Petroleum Exporting Countries (OPEC), major non-OPEC oil producers (i.e., the North Sea, Russia), major energy transit areas (i.e., Ukraine), and other areas of current interest to energy analysts and policy makers. As of January 1995, EMCID maintained over 40 CABs, updated on an annual schedule and subject to revision as events warrant. This report includes 25 CABs updated during 1994. All CABs contain a profile section, a map showing the country`s location, and a narrative section. The profile section includes outlines of the country`s economy, energy sector, and environment. The narrative provides further information and discussion of these topics. Some CABs also include a detailed map displaying locations of major oil and gas fields, pipelines, ports, etc. These maps were created as a result of special individual requests and so are not typically a standard feature of the CABs. They are presented here wherever available as a supplement to the information contained in the CABs.

  2. Kinetics of hydrocarbon extraction from oil shale using biosurfactant producing bacteria

    Energy Technology Data Exchange (ETDEWEB)

    Haddadin, Malik S.Y.; Abou Arqoub, Ansam A.; Abu Reesh, Ibrahim [Faculty of Graduate Studies, Jordan University, Queen Rania Street, Amman, 11942 (Jordan); Haddadin, Jamal [Faculty of Agriculture, Mutah University, P.O. Box 59, Mutah 61710 (Jordan)

    2009-04-15

    This study was done to extract hydrocarbon compounds from El-Lajjun oil shale using biosurfactant produced from two strains Rhodococcus erythropolis and Rhodococcus ruber. The results have shown that, optimal biosurfactant production was found using naphthalene and diesel as a carbon source for R. erthropolis and R. ruber, respectively. Optimum nitrogen concentration was 9 g/l and 7 g/l for R. erthropolis and R. ruber, respectively. Optimum K{sub 2}HPO{sub 4} to KH{sub 2}PO{sub 4} ratio, temperature, pH, and agitation speeds were 2:1, 37 C, 7 and 200 rpm. Under optimal conditions R. erthropolis and R. ruber produced 5.67 and 6.9 g/l biosurfactant, respectively. Maximum recovery of oil achieved with hydrogen peroxide pre-treatment was 25% and 26% at biosurfactant concentration of 8 g/l and 4 g/l for R. erthropolis and R. ruber, respectively. The extent desorption of hydrocarbons from the pre-treated oil shale by biosurfactant were inversely related to the concentration of high molecular weight hydrocarbons, asphaltenes compounds. Pre-treatment of oil shale with hydrogen peroxide produced better improvement in aromatic compounds extraction in comparison with improvement which resulted from demineralization of the oil shale. (author)

  3. Identification of molecular species of polyol oils produced from soybean oil by Pseudomonas aeruginosa e03-12 nrrl b-59991

    Science.gov (United States)

    The objective of this study is to develop a bioprocess for the production of polyol oils directly from soybean oil. We reported earlier methods for microbial screening and production of polyol oils from soybean oil (Hou and Lin, 2013). The polyol oil produced by Acinetobacter haemolyticus A01-35 (NR...

  4. The macroeconomic effects of oil price fluctuations on a small open oil-producing country. The case of Trinidad and Tobago

    International Nuclear Information System (INIS)

    Lorde, Troy; Thomas, Chrystol; Jackman, Mahalia

    2009-01-01

    Using vector autoregressive (VAR) methodology, this paper empirically investigates the macroeconomic effects of oil price fluctuations on Trinidad and Tobago. Overall, we find that the price of oil is a major determinant of economic activity of the country. Our impulse response functions suggest that following a positive oil price shock, output falls within the first two years followed by positive and growing response. We also investigate the macroeconomic impact of oil price volatility. Results suggest that an unanticipated shock to oil price volatility brings about random swings in the macroeconomy; however, only government revenue and the price level exhibit significant responses. With regard to the magnitude of the responses, shocks to oil price volatility tend to yield smaller macroeconomic impacts in comparison to shocks to oil prices. Variance decompositions suggest that the price of oil is a major component of forecast variation for most macroeconomic variables. Finally, Granger-causality tests indicate causality from oil prices to output and oil prices to government revenue. (author)

  5. Comparison of Moringa Oleifera seeds oil characterization produced chemically and mechanically

    Science.gov (United States)

    Eman, N. A.; Muhamad, K. N. S.

    2016-06-01

    It is established that virtually every part of the Moringa oleifera tree (leaves, stem, bark, root, flowers, seeds, and seeds oil) are beneficial in some way with great benefits to human being. The tree is rich in proteins, vitamins, minerals. All Moringa oleifera food products have a very high nutritional value. They are eaten directly as food, as supplements, and as seasonings as well as fodder for animals. The purpose of this research is to investigate the effect of seeds particle size on oil extraction using chemical method (solvent extraction). Also, to compare Moringa oleifera seeds oil properties which are produced chemically (solvent extraction) and mechanically (mechanical press). The Moringa oleifera seeds were grinded, sieved, and the oil was extracted using soxhlet extraction technique with n-Hexane using three different size of sample (2mm, 1mm, and 500μm). The average oil yield was 36.1%, 40.80%, and 41.5% for 2mm, 1mm, and 500μm particle size, respectively. The properties of Moringa oleifera seeds oil were: density of 873 kg/m3, and 880 kg/m3, kinematic viscosity of 42.2mm2/s and 9.12mm2/s for the mechanical and chemical method, respectively. pH, cloud point and pour point were same for oil produced with both methods which is 6, 18°C and 12°C, respectively. For the fatty acids, the oleic acid is present with high percentage of 75.39%, and 73.60% from chemical and mechanical method, respectively. Other fatty acids are present as well in both samples which are (Gadoleic acid, Behenic acid, Palmitic acid) which are with lower percentage of 2.54%, 5.83%, and 5.73%, respectively in chemical method oil, while they present as 2.40%, 6.73%, and 6.04%, respectively in mechanical method oil. In conclusion, the results showed that both methods can produce oil with high quality. Moringa oleifera seeds oil appear to be an acceptable good source for oil rich in oleic acid which is equal to olive oil quality, that can be consumed in Malaysia where the olive oil

  6. Chemical investigation of Nigella sativa L. seed oil produced in Morocco

    Directory of Open Access Journals (Sweden)

    Said Gharby

    2015-06-01

    Full Text Available Seeds of Nigella sativa L. (black cumin or black seeds are widely used in traditional Islamic medicine and for culinary purposes worldwide. Nigella seed oil is becoming popular in and out of the Islamic world. Composition of Nigella seed oil is known to be location-dependent. We investigated the composition of Nigella seed oil prepared by solvent- or cold press-extraction of Nigella seeds grown in Morocco. Oil extraction yield was 37% and 27% when solvent or cold press extraction methods were used, respectively. In terms of oil major components, composition of Nigella seed oil from Morocco is similar to that from other Mediterranean countries known for their Nigella seed-oil quality.

  7. Optimal gasoline tax in developing, oil-producing countries: The case of Mexico

    International Nuclear Information System (INIS)

    Antón-Sarabia, Arturo; Hernández-Trillo, Fausto

    2014-01-01

    This paper uses the methodology of Parry and Small (2005) to estimate the optimal gasoline tax for a less-developed oil-producing country. The relevance of the estimation relies on the differences between less-developed countries (LDCs) and industrial countries. We argue that lawless roads, general subsidies on gasoline, poor mass transportation systems, older vehicle fleets and unregulated city growth make the tax rates in LDCs differ substantially from the rates in the developed world. We find that the optimal gasoline tax is $1.90 per gallon at 2011 prices and show that the estimate differences are in line with the factors hypothesized. In contrast to the existing literature on industrial countries, we show that the relative gasoline tax incidence may be progressive in Mexico and, more generally, in LDCs. - Highlights: • We estimate the optimal gasoline tax for a typical less-developed, oil-producing country like Mexico. • The relevance of the estimation relies on the differences between less-developed and industrial countries. • The optimal gasoline tax is $1.90 per gallon at 2011 prices. • Distance-related pollution damages, accident costs and gas subsidies account for the major differences. • Gasoline tax incidence may be progressive in less developed countries

  8. An Exogenous Surfactant-Producing Bacillus subtilis Facilitates Indigenous Microbial Enhanced Oil Recovery.

    Science.gov (United States)

    Gao, Peike; Li, Guoqiang; Li, Yanshu; Li, Yan; Tian, Huimei; Wang, Yansen; Zhou, Jiefang; Ma, Ting

    2016-01-01

    This study used an exogenous lipopeptide-producing Bacillus subtilis to strengthen the indigenous microbial enhanced oil recovery (IMEOR) process in a water-flooded reservoir in the laboratory. The microbial processes and driving mechanisms were investigated in terms of the changes in oil properties and the interplay between the exogenous B. subtilis and indigenous microbial populations. The exogenous B. subtilis is a lipopeptide producer, with a short growth cycle and no oil-degrading ability. The B. subtilis facilitates the IMEOR process through improving oil emulsification and accelerating microbial growth with oil as the carbon source. Microbial community studies using quantitative PCR and high-throughput sequencing revealed that the exogenous B. subtilis could live together with reservoir microbial populations, and did not exert an observable inhibitory effect on the indigenous microbial populations during nutrient stimulation. Core-flooding tests showed that the combined exogenous and indigenous microbial flooding increased oil displacement efficiency by 16.71%, compared with 7.59% in the control where only nutrients were added, demonstrating the application potential in enhanced oil recovery in water-flooded reservoirs, in particular, for reservoirs where IMEOR treatment cannot effectively improve oil recovery.

  9. Oil price risk management in the 1990s - issues for producers and lenders

    International Nuclear Information System (INIS)

    Lambert, S.

    1994-01-01

    Oil prices have exhibited considerable volatility over the past five or ten years and the management of oil price risk has become an important factor in underpinning the viability of many oil producing operations from both a lender's and investor's perspective. Various oil based hedging products are now available to protect against such volatility, ranging from products which fix forward prices to option based arrangements which set a floor price but retain some (or all) of the potential upside. These products have particular relevance for petroleum companies with limited financial resources or who are looking to limit recourse to particular assets/cash flows. There are a number of techniques which can be successfully combined to mitigate oil price volatility and the most relevant of these to a producer are discussed. The recent development of the Tapis swap and option markets, which have provided flexibility to Australasian producers, is also discussed. Oil based financial products can also be used as a method of funding (e.g. for a development or acquisition) as an alternative to traditional cash based borrowing structures, thus creating a natural hedge against oil price movements. It is estimated that the use of such structures, coupled with a well structured revenue hedging program, can enhance a project's attractiveness from a lender's perspective (particularly with respect to protection against down side movements in oil price) and/or provide greater certainty of returns to producers. A case study of a recent commodity risk management based financing is presented. 1 fig., 6 tabs

  10. Evolution of oil-producing trichomes in Sisyrinchium (Iridaceae): insights from the first comprehensive phylogenetic analysis of the genus

    Science.gov (United States)

    Chauveau, Olivier; Eggers, Lilian; Raquin, Christian; Silvério, Adriano; Brown, Spencer; Couloux, Arnaud; Cruaud, Corine; Kaltchuk-Santos, Eliane; Yockteng, Roxana; Souza-Chies, Tatiana T.; Nadot, Sophie

    2011-01-01

    Background and Aims Sisyrinchium (Iridaceae: Iridoideae: Sisyrinchieae) is one of the largest, most widespread and most taxonomically complex genera in Iridaceae, with all species except one native to the American continent. Phylogenetic relationships within the genus were investigated and the evolution of oil-producing structures related to specialized oil-bee pollination examined. Methods Phylogenetic analyses based on eight molecular markers obtained from 101 Sisyrinchium accessions representing 85 species were conducted in the first extensive phylogenetic analysis of the genus. Total evidence analyses confirmed the monophyly of the genus and retrieved nine major clades weakly connected to the subdivisions previously recognized. The resulting phylogenetic hypothesis was used to reconstruct biogeographical patterns, and to trace the evolutionary origin of glandular trichomes present in the flowers of several species. Key Results and Conclusions Glandular trichomes evolved three times independently in the genus. In two cases, these glandular trichomes are oil-secreting, suggesting that the corresponding flowers might be pollinated by oil-bees. Biogeographical patterns indicate expansions from Central America and the northern Andes to the subandean ranges between Chile and Argentina and to the extended area of the Paraná river basin. The distribution of oil-flower species across the phylogenetic trees suggests that oil-producing trichomes may have played a key role in the diversification of the genus, a hypothesis that requires future testing. PMID:21527419

  11. Radioactive contamination of oil produced from nuclear-broken shale

    International Nuclear Information System (INIS)

    Arnold, W.D.; Crouse, D.J.

    1970-01-01

    The results of small-scale exposure and retorting tests indicate that oil recovered from shale that has been broken with nuclear explosives will be contaminated with tritium. When oil shale was heated in sealed flasks with tritiated water vapor or with tritiated hydrogen, both the shale and the oil subsequently retorted from the shale contained tritium. There was much less contamination of the shale or oil, however, when the shale was exposed to tritiated methane and ethane. Contamination of shale and oil with tritium, as the result, of exposure to tritiated water, increased as the exposure temperature, exposure pressure, and the tritium concentration in the water were increased. This contamination also increased as the exposure time was increased up to 25 days, but not significantly thereafter. More than 90% of the tritium was removed from contaminated shale by treating the shale with moist air at elevated temperatures. Only small amounts of the tritium were removed from crude oil by contacting it with solid drying agents or with water. When tritium-contaminated shale oil was distilled, the tritium contents of the recovered fractions were found to be approximately equal. After being heated with a sample of underground test-shot debris, liquid shale oil became contaminated with radioactive fission products. Most of the radioactivity of the oil was due to finely dispersed solids rather than to dissolved radionuclides. Filtration of the oil removed a major fraction of the radioactive material. When the contaminated oil was distilled, more than 99% of the radionuclides remained in the pot residue. (author)

  12. Radioactive contamination of oil produced from nuclear-broken shale

    Energy Technology Data Exchange (ETDEWEB)

    Arnold, W D; Crouse, D J

    1970-05-15

    The results of small-scale exposure and retorting tests indicate that oil recovered from shale that has been broken with nuclear explosives will be contaminated with tritium. When oil shale was heated in sealed flasks with tritiated water vapor or with tritiated hydrogen, both the shale and the oil subsequently retorted from the shale contained tritium. There was much less contamination of the shale or oil, however, when the shale was exposed to tritiated methane and ethane. Contamination of shale and oil with tritium, as the result, of exposure to tritiated water, increased as the exposure temperature, exposure pressure, and the tritium concentration in the water were increased. This contamination also increased as the exposure time was increased up to 25 days, but not significantly thereafter. More than 90% of the tritium was removed from contaminated shale by treating the shale with moist air at elevated temperatures. Only small amounts of the tritium were removed from crude oil by contacting it with solid drying agents or with water. When tritium-contaminated shale oil was distilled, the tritium contents of the recovered fractions were found to be approximately equal. After being heated with a sample of underground test-shot debris, liquid shale oil became contaminated with radioactive fission products. Most of the radioactivity of the oil was due to finely dispersed solids rather than to dissolved radionuclides. Filtration of the oil removed a major fraction of the radioactive material. When the contaminated oil was distilled, more than 99% of the radionuclides remained in the pot residue. (author)

  13. Bridging the Gap between Chemical Flooding and Independent Oil Producers

    Energy Technology Data Exchange (ETDEWEB)

    Stan McCool; Tony Walton; Paul Whillhite; Mark Ballard; Miguel Rondon; Kaixu Song; Zhijun Liu; Shahab Ahmed; Peter Senior

    2012-03-31

    Ten Kanas oil reservoirs/leases were studied through geological and engineering analysis to assess the potential performance of chemical flooding to recover oil. Reservoirs/leases that have been efficiently waterflooded have the highest performance potential for chemical flooding. Laboratory work to identify efficient chemical systems and to test the oil recovery performance of the systems was the major effort of the project. Efficient chemical systems were identified for crude oils from nine of the reservoirs/leases. Oil recovery performance of the identified chemical systems in Berea sandstone rocks showed 90+ % recoveries of waterflood residual oil for seven crude oils. Oil recoveries increased with the amount of chemical injected. Recoveries were less in Indiana limestone cores. One formulation recovered 80% of the tertiary oil in the limestone rock. Geological studies for nine of the oil reservoirs are presented. Pleasant Prairie, Trembley, Vinland and Stewart Oilfields in Kansas were the most favorable of the studied reservoirs for a pilot chemical flood from geological considerations. Computer simulations of the performance of a laboratory coreflood were used to predict a field application of chemical flooding for the Trembley Oilfield. Estimates of field applications indicated chemical flooding is an economically viable technology for oil recovery.

  14. Oxidative stability during storage of structured lipids produced from fish oil and caprylic acid

    DEFF Research Database (Denmark)

    Nielsen, Nina Skall; Xu, Xuebing; Timm Heinrich, Maike

    2004-01-01

    Structured lipids produced by enzymatic or chemical methods for different applications have been receiving considerable attention. The oxidative stability of a randomized structured lipid (RFO), produced by chemical interesterification from fish oil (FO) and tricaprylin, and a specific structured...... lipid (SFO), produced by enzymatic interesterification from the same oil and caprylic acid, was compared with the stability of FO. Oils were stored at 2degreesC for 11 wk followed by storage at 20degreesC for 6 wk. In addition, the antioxidative effect of adding the metal chelators EDTA or citric acid...

  15. Analysis of Petroleum Technology Advances Through Applied Research by Independent Oil Producers

    Energy Technology Data Exchange (ETDEWEB)

    Brashear, Jerry P.; North, Walter B.; Thomas Charles P.; Becker, Alan B.; Faulder, David D.

    2000-01-12

    Petroleum Technology Advances Through Applied Research by Independent Oil Producers is a program of the National Oil Research Program, U.S. Department of Energy. Between 1995 and 1998, the program competitively selected and cost-shared twenty-two projects with small producers. The purpose was to involve small independent producers in testing technologies of interest to them that would advance (directly or indirectly) one or more of four national program objectives: (1) Extend the productive life of reservoirs; (2) Increase production and/or reserves; (3) Improve environmental performance; and (4) Broaden the exchange of technology information.

  16. Enzymatic transesterification of waste vegetable oil to produce biodiesel.

    Science.gov (United States)

    Lopresto, C G; Naccarato, S; Albo, L; De Paola, M G; Chakraborty, S; Curcio, S; Calabrò, V

    2015-11-01

    An experimental study on enzymatic transesterification was performed to produce biodiesel from waste vegetable oils. Lipase from Pseudomonas cepacia was covalently immobilized on a epoxy-acrylic resin support. The immobilized enzyme exhibited high catalytic specific surface and allowed an easy recovery, regeneration and reutilisation of biocatalyst. Waste vegetable oils - such as frying oils, considered not competitive with food applications and wastes to be treated - were used as a source of glycerides. Ethanol was used as a short chain alcohol and was added in three steps with the aim to reduce its inhibitory effect on lipase activity. The effect of biocatalyst/substrate feed mass ratios and the waste oil quality have been investigated in order to estimate the process performances. Biocatalyst recovery and reuse have been also studied with the aim to verify the stability of the biocatalyst for its application in industrial scale. Copyright © 2015 Elsevier Inc. All rights reserved.

  17. Can Producing Oil Store Carbon? Greenhouse Gas Footprint of CO2EOR, Offshore North Sea.

    Science.gov (United States)

    Stewart, R Jamie; Haszeldine, R Stuart

    2015-05-05

    Carbon dioxide enhanced oil recovery (CO2EOR) is a proven and available technology used to produce incremental oil from depleted fields while permanently storing large tonnages of injected CO2. Although this technology has been used successfully onshore in North America and Europe, there are currently no CO2EOR projects in the United Kingdom. Here, we examine whether offshore CO2EOR can store more CO2 than onshore projects traditionally have and whether CO2 storage can offset additional emissions produced through offshore operations and incremental oil production. Using a high-level Life Cycle system approach, we find that the largest contribution to offshore emissions is from flaring or venting of reproduced CH4 and CO2. These can already be greatly reduced by regulation. If CO2 injection is continued after oil production has been optimized, then offshore CO2EOR has the potential to be carbon negative--even when emissions from refining, transport, and combustion of produced crude oil are included. The carbon intensity of oil produced can be just 0.056-0.062 tCO2e/bbl if flaring/venting is reduced by regulation. This compares against conventional Saudi oil 0.040 tCO2e/bbl or mined shale oil >0.300 tCO2e/bbl.

  18. Pigments in Extra-Virgin Olive Oils Produced in Tuscany (Italy) in Different Years

    Science.gov (United States)

    Lazzerini, Cristina; Domenici, Valentina

    2017-01-01

    Pigments are responsible for the color of olive oils, and are an important ingredient that is directly related to the quality of this food. However, the concentration of pigments can vary significantly depending on the climate conditions, harvesting time, and olive cultivars. In this work, we quantified the main pigments in several extra-virgin olive oils produced from a blend of three cultivars (Moraiolo, Frantoio, and Leccino) typical of Tuscany (Italy) harvested in three different years: 2012, 2013, and 2014. Pigments—namely, β-carotene, lutein, pheophytin A, and pheophytin B—were quantified by a method based on the mathematical analysis of the near ultraviolet-visible absorption spectra of the oils. Data were analyzed by a multivariate statistical approach. The results show that the pigments’ content of extra-virgin olive oils produced in 2014 can be well distinguished with respect to previous years. This can be explained by the anomalous climate conditions, which strongly affected Italy and, in particular, Tuscany, where the olives were harvested. This study represents an interesting example of how pigment content can be significant in characterizing olive oils. Moreover, this is the first report of pigment quantification in extra-virgin olive oils produced in Tuscany. PMID:28353651

  19. Applications of supercritical fluid extraction (SFE) of palm oil and oil from natural sources.

    Science.gov (United States)

    Akanda, Mohammed Jahurul Haque; Sarker, Mohammed Zaidul Islam; Ferdosh, Sahena; Manap, Mohd Yazid Abdul; Ab Rahman, Nik Norulaini Nik; Ab Kadir, Mohd Omar

    2012-02-10

    Supercritical fluid extraction (SFE), which has received much interest in its use and further development for industrial applications, is a method that offers some advantages over conventional methods, especially for the palm oil industry. SC-CO₂ refers to supercritical fluid extraction (SFE) that uses carbon dioxide (CO₂) as a solvent which is a nontoxic, inexpensive, nonflammable, and nonpolluting supercritical fluid solvent for the extraction of natural products. Almost 100% oil can be extracted and it is regarded as safe, with organic solvent-free extracts having superior organoleptic profiles. The palm oil industry is one of the major industries in Malaysia that provides a major contribution to the national income. Malaysia is the second largest palm oil and palm kernel oil producer in the World. This paper reviews advances in applications of supercritical carbon dioxide (SC-CO₂) extraction of oils from natural sources, in particular palm oil, minor constituents in palm oil, producing fractionated, refined, bleached, and deodorized palm oil, palm kernel oil and purified fatty acid fractions commendable for downstream uses as in toiletries and confectionaries.

  20. Applications of Supercritical Fluid Extraction (SFE of Palm Oil and Oil from Natural Sources

    Directory of Open Access Journals (Sweden)

    Mohd Omar Ab Kadir

    2012-02-01

    Full Text Available Supercritical fluid extraction (SFE, which has received much interest in its use and further development for industrial applications, is a method that offers some advantages over conventional methods, especially for the palm oil industry. SC-CO2 refers to supercritical fluid extraction (SFE that uses carbon dioxide (CO2 as a solvent which is a nontoxic, inexpensive, nonflammable, and nonpolluting supercritical fluid solvent for the extraction of natural products. Almost 100% oil can be extracted and it is regarded as safe, with organic solvent-free extracts having superior organoleptic profiles. The palm oil industry is one of the major industries in Malaysia that provides a major contribution to the national income. Malaysia is the second largest palm oil and palm kernel oil producer in the World. This paper reviews advances in applications of supercritical carbon dioxide (SC-CO2 extraction of oils from natural sources, in particular palm oil, minor constituents in palm oil, producing fractionated, refined, bleached, and deodorized palm oil, palm kernel oil and purified fatty acid fractions commendable for downstream uses as in toiletries and confectionaries.

  1. Study Of The Physicochemical Analysis Of Biodiesel Produced From Waste Vegetable Oil.

    Directory of Open Access Journals (Sweden)

    C. O. Okpanachi

    2017-07-01

    Full Text Available The study of the physicochemical analysis of biodiesel produced from waste vegetable oil in Sedi Minna Nigeria was carried out in order to ascertain the quality of the biodiesel produced as regards physical and chemical parameters which include visual appearance colour cloud point flash point and cetane index diesel index kinematic velocity calorific value. Biodiesel is a renewable resource that can replace petroleum diesel which comes from fossil fuels that are limited and will be exhausted in the near future. Biodiesel can be made from the transesterification of vegetable oils animal fat greases and oil crops such as soybean and it is biodegradable. The biodiesel produced was subjected to physicochemical analysis and results of cetane index was established to be 52 the flash point using pensky martens close cup was determine to be 1600C diesel index using IP21 0.3411 kinematic viscosity at 400C to be 4.12 and calorific value of 10867calg. The investigated physicochemical parameters show that the biodiesel produced is suitable for use in diesel engines without modifications and is cheaper to produce compared to petroleum diesel.

  2. Environmental contaminants in oil field produced waters discharged into wetlands

    International Nuclear Information System (INIS)

    Ramirez, P. Jr.

    1994-01-01

    The 866-acre Loch Katrine wetland complex in Park County, Wyoming provides habitat for many species of aquatic birds. The complex is sustained primarily by oil field produced waters. This study was designed to determine if constituents in oil field produced waters discharged into Custer Lake and to Loch Katrine pose a risk to aquatic birds inhabiting the wetlands. Trace elements, hydrocarbons and radium-226 concentrations were analyzed in water, sediment and biota collected from the complex during 1992. Arsenic, boron, radium-226 and zinc were elevated in some matrices. The presence of radium-226 in aquatic vegetation suggests that this radionuclide is available to aquatic birds. Oil and grease concentrations in water from the produced water discharge exceeded the maximum 10 mg/l permitted by the WDEQ (1990). Total aliphatic and aromatic hydrocarbon concentrations in sediments were highest at the produced water discharge, 6.376 μg/g, followed by Custer Lake, 1.104 μg/g. The higher levels of hydrocarbons found at Custer Lake, compared to Loch Katrine, may be explained by Custer Lake's closer proximity to the discharge. Benzo(a)pyrene was not detected in bile from gadwalls collected at Loch Katrine but was detected in bile from northern shovelers collected at Custer Lake. Benzo(a)pyrene concentrations in northern shoveler bile ranged from 500 to 960 ng/g (ppb) wet weight. The presence of benzo(a)pyrene in the shovelers indicates exposure to petroleum hydrocarbons

  3. Produced water treatment for beneficial use : emulsified oil removal

    NARCIS (Netherlands)

    Waisi, Basma

    2016-01-01

    The development of novel carbon material, high accessible surface area, interconnected porosity, and stable nanofiber nonwoven media for emulsified oil droplets separation from oily wastewater, in particular for oilfields produced water treatment, is discussed in this thesis. Firstly, the quantity

  4. Major oil exporters may profit rather than lose, in a carbon-constrained world

    International Nuclear Information System (INIS)

    Persson, Tobias A.; Azar, C.; Johansson, D.; Lindgren, K.

    2007-01-01

    The Organization of Petroleum Exporting Countries (OPEC) claims compensation for losses in expected oil export revenues due to CO 2 mitigation measures in developing countries. These losses are expected for two primary reasons: a reduction in the consumption of oil in importing countries and a reduction in the producer price of oil (taxation in an importing country implies a transfer of rents from producers to consumers). So far, most studies have focused on these two mechanisms and corroborated that revenue losses for OPEC are to be expected. However, there are also mechanisms that may be expected to raise the price of oil products. In a cost-effective regime for dealing with climate change, i.e., a regime in which all or most countries participate and in which the same carbon price is applied on all carbon-emitting activities, the cost of using unconventional oil, or synthetic diesel from coal, will increase even more than the cost of using conventional oil. Given that reserves of conventional oil are expected to dwindle over time, heavy oils and coal to liquids might set the long-run price for liquid fuels, which means that the price of oil would increase beyond the carbon fee; i.e., the rent on conventional oil would increase. We use an energy-economic optimization model to analyze these three mechanisms. We find that the net present value of OPEC revenue from conventional oil increases slightly (at most by 4 percent) with a global CO 2 restriction regime. We also consider conditions under which this result does not hold

  5. Determining the water cut and water salinity in an oil-water flowstream by measuring the sulfur content of the produced oil

    International Nuclear Information System (INIS)

    Smith, H.D.; Arnold, D.M.

    1980-01-01

    A technique for detecting water cut and water salinity in an oil/water flowstream in petroleum refining and producing operations is described. The fluid is bombarded with fast neutrons which are slowed down and then captured producing gamma spectra characteristic of the fluid material. Analysis of the spectra indicates the relative presence of the elements sulfur, hydrogen and chlorine and from the sulfur measurement, the oil cut (fractional oil content) of the fluid is determined, enabling the water cut to be found. From the water cut, water salinity can also be determined. (U.K.)

  6. Effect of Kelussia odoratissima Mozaff essential oil on promastigot form of Leishmania major (in vitro)

    OpenAIRE

    Pirali Kheirabadi Khodadad; Saei Dehkordi Siavash; Kheibari Parviz

    2015-01-01

    Introduction: Leishmaniasis is a zoonotic disease caused by a protozoan of the genus Leishmania. In this study, the effects of Kelussia odoratissima Mozaff essential oil on the promastigot form of Leishmania major were studied. Methods: In this study, the effects of Kelussia odoratissima Mozaff essential oil on the promastigot form of Leishmania major were assessed by calculating the average number of surviving promastigots after exposure to different concentrations of essential oil, relativ...

  7. Oil output's changing fortunes

    International Nuclear Information System (INIS)

    Eldridge, D.

    1994-01-01

    The Petroleum Economist, previously the Petroleum Press Service, has been making annual surveys of output levels of petroleum in all the oil-producing countries since its founding in 1934. This article documents trends and changes in the major oil-producing countries output from 1934 until the present. This analysis is linked with the political and historical events accompanying these changes, notably the growth of Middle Eastern oil production, the North Sea finds and most recently, Iraq's invasion of Kuwait in 1990. (UK)

  8. Removal of oil, grease, and suspended solids from produced water with ceramic crossflow microfiltration

    International Nuclear Information System (INIS)

    Chen, A.S.C.; Flynn, J.T.; Cook, R.G.; Casaday, A.L.

    1991-01-01

    In this paper results of studies of two onshore and two offshore pilot plants that use ceramic crossflow microfiltration (CCFM) to separate oil, grease, and suspended solids from produced water are discussed. The method is capable of producing permeate quality with < =5 mg/L (detection limit) of dispersed oil and grease and <1 mg/L of suspended solids

  9. Strategic planning among the oil and gas major

    International Nuclear Information System (INIS)

    Grant, R.M.

    1998-01-01

    The increased focus on profitability and shareholder return, the impossibility of forecasting and the increased need for flexibility have made the strategic planning processes of the oil majors to change considerably in the past decade. While shifting from control to co-ordination, strategic planning has been acting less as a guidance and more as a mechanism for improving the quality of strategic decision-making [it

  10. The opening up of Middle Eastern Oil Producing countries

    International Nuclear Information System (INIS)

    Giannesini, J.F.

    2000-01-01

    Between them, Saudi Arabia, Iraq, Iran and Kuwait control nearly 56 % of the world's oil reserves. They account for almost 25 % of production. There are signs that they are opening their territories to foreign companies in different ways and to various degrees, according to the country. The reasons are technical (decline of production and human resources), economic (increasing state budgetary requirements and growing oil production investment costs) and geopolitical (protective military isolation of territories and regimes). The opening up to these countries will in the future, have a major impact on the strategies of large western company operators. (authors)

  11. Ready or Not: Namibia As a Potentially Successful Oil Producer

    Directory of Open Access Journals (Sweden)

    Andrzej Polus

    2015-01-01

    Full Text Available The primary objective of this paper is to assess whether Namibia is ready to become an oil producer. The geological estimates suggest that the country may possess the equivalent of as many as 11 billion barrels of crude oil. If the numbers are correct, Namibia would be sitting on the second-largest oil reserves in sub-Saharan Africa, and exploitation could start as soon as 2017. This clearly raises the question of whether Namibia is next in line to become a victim of the notorious “resource curse.” On the basis of critical discourse analysis and findings from field research, the authors have selected six dimensions of the resource curse and contextualised them within the spheres of Namibian politics and economy. While Namibia still faces a number of important challenges, our findings offer little evidence that the oil will have particularly disruptive effects.

  12. Properties and quality verification of biodiesel produced from tobacco seed oil

    Energy Technology Data Exchange (ETDEWEB)

    Usta, N., E-mail: n_usta@pau.edu.t [Pamukkale University, Mechanical Engineering Department, 20070 Denizli (Turkey); Aydogan, B. [Pamukkale University, Mechanical Engineering Department, 20070 Denizli (Turkey); Con, A.H. [Pamukkale University, Food Engineering Department, 20070 Denizli (Turkey); Uguzdogan, E. [Pamukkale University, Chemical Engineering Department, 20070 Denizli (Turkey); Ozkal, S.G. [Pamukkale University, Food Engineering Department, 20070 Denizli (Turkey)

    2011-05-15

    Research highlights: {yields} High quality biodiesel fuel can be produced from tobacco seed oil. {yields} Pyrogallol was found to be effective antioxidant improving the oxidation stability. {yields} The iodine number was reduced with a biodiesel including more saturated fatty acids. {yields} Octadecene-1-maleic anhydride copolymer was an effective cold flow improver. {yields} The appropriate amounts of the additives do not affect the properties negatively. -- Abstract: Tobacco seed oil has been evaluated as a feedstock for biodiesel production. In this study, all properties of the biodiesel that was produced from tobacco seed oil were examined and some solutions were derived to bring all properties of the biodiesel within European Biodiesel Standard EN14214 to verify biodiesel quality. Among the properties, only oxidation stability and iodine number of the biodiesel, which mainly depend on fatty acid composition of the oil, were not within the limits of the standard. Six different antioxidants that are tert-butylhydroquinone, butylated hydroxytoluene, propyl gallate, pyrogallol, {alpha}-tocopherol and butylated hydroxyanisole were used to improve the oxidation stability. Among them, pyrogallol was found to be the most effective antioxidant. The iodine number was improved with blending the biodiesel produced from tobacco seed oil with a biodiesel that contains more saturated fatty acids. However, the blending caused increasing the cold filter plugging point. Therefore, four different cold flow improvers, which are ethylene-vinyl acetate copolymer, octadecene-1-maleic anhydride copolymer and two commercial cold flow improvers, were used to decrease cold filter plugging point of the biodiesel and the blends. Among the improvers, the best improver is said to be octadecene-1-maleic anhydride copolymer. In addition, effects of temperature on the density and the viscosity of the biodiesel were investigated.

  13. Research advancements in palm oil nutrition*

    Science.gov (United States)

    May, Choo Yuen; Nesaretnam, Kalanithi

    2014-01-01

    Palm oil is the major oil produced, with annual world production in excess of 50 million tonnes. About 85% of global palm oil produced is used in food applications. Over the past three decades, research on nutritional benefits of palm oil have demonstrated the nutritional adequacy of palm oil and its products, and have resulted in transitions in the understanding these attributes. Numerous studies have demonstrated that palm oil was similar to unsaturated oils with regards to effects on blood lipids. Palm oil provides a healthy alternative to trans-fatty acid containing hydrogenated fats that have been demonstrated to have serious deleterious effects on health. The similar effects of palm oil on blood lipids, comparable to other vegetable oils could very well be due to the structure of the major triglycerides in palm oil, which has an unsaturated fatty acid in the stereospecific numbers (sn)-2 position of the glycerol backbone. In addition, palm oil is well endowed with a bouquet of phytonutrients beneficial to health, such as tocotrienols, carotenoids, and phytosterols. This review will provide an overview of studies that have established palm oil as a balanced and nutritious oil. PMID:25821404

  14. Research advancements in palm oil nutrition.

    Science.gov (United States)

    May, Choo Yuen; Nesaretnam, Kalanithi

    2014-10-01

    Palm oil is the major oil produced, with annual world production in excess of 50 million tonnes. About 85% of global palm oil produced is used in food applications. Over the past three decades, research on nutritional benefits of palm oil have demonstrated the nutritional adequacy of palm oil and its products, and have resulted in transitions in the understanding these attributes. Numerous studies have demonstrated that palm oil was similar to unsaturated oils with regards to effects on blood lipids. Palm oil provides a healthy alternative to trans-fatty acid containing hydrogenated fats that have been demonstrated to have serious deleterious effects on health. The similar effects of palm oil on blood lipids, comparable to other vegetable oils could very well be due to the structure of the major triglycerides in palm oil, which has an unsaturated fatty acid in the stereospecific numbers ( sn) -2 position of the glycerol backbone. In addition, palm oil is well endowed with a bouquet of phytonutrients beneficial to health, such as tocotrienols, carotenoids, and phytosterols. This review will provide an overview of studies that have established palm oil as a balanced and nutritious oil.

  15. Effect of Kelussia odoratissima Mozaff essential oil on promastigot form of Leishmania major (in vitro

    Directory of Open Access Journals (Sweden)

    Pirali Kheirabadi Khodadad

    2015-01-01

    Full Text Available Introduction: Leishmaniasis is a zoonotic disease caused by a protozoan of the genus Leishmania. In this study, the effects of Kelussia odoratissima Mozaff essential oil on the promastigot form of Leishmania major were studied. Methods: In this study, the effects of Kelussia odoratissima Mozaff essential oil on the promastigot form of Leishmania major were assessed by calculating the average number of surviving promastigots after exposure to different concentrations of essential oil, relative to the control Glucantime, at different time intervals. To achieve this, various essential oil concentrations (7.5 μl, 15 μl, 25 μl, 35.25 μl, 50 μl were added to parasites. Different groups in this study were kept in a 26°C incubator under identical conditions. 24, 48 and 72 hours after incubation, living promastigots were counted. Results: The effect of the essential oil of Kelussia odoratissima Mozaff differed from the negative and positive controls and depended on the concentration: higher concentrations (35.25 μl, 50 μl had a stronger effect on promastigots, causing total mortality. Conclusion: This study showed that Kelussia odoratissima Mozaff essential oil had effects on promastigot form of Leishmania major. So it might be possible to use the essential oil of Kelussia odoratissima instead of chemical drugs.

  16. Rhamnolipids Produced by Indigenous Acinetobacter junii from Petroleum Reservoir and its Potential in Enhanced Oil Recovery

    Science.gov (United States)

    Dong, Hao; Xia, Wenjie; Dong, Honghong; She, Yuehui; Zhu, Panfeng; Liang, Kang; Zhang, Zhongzhi; Liang, Chuanfu; Song, Zhaozheng; Sun, Shanshan; Zhang, Guangqing

    2016-01-01

    Biosurfactant producers are crucial for incremental oil production in microbial enhanced oil recovery (MEOR) processes. The isolation of biosurfactant-producing bacteria from oil reservoirs is important because they are considered suitable for the extreme conditions of the reservoir. In this work, a novel biosurfactant-producing strain Acinetobacter junii BD was isolated from a reservoir to reduce surface tension and emulsify crude oil. The biosurfactants produced by the strain were purified and then identified via electrospray ionization-Fourier transform ion cyclotron resonance mass spectrometry (ESI FT-ICR-MS). The biosurfactants generated by the strain were concluded to be rhamnolipids, the dominant rhamnolipids were C26H48O9, C28H52O9, and C32H58O13. The optimal carbon source and nitrogen source for biomass and biosurfactant production were NaNO3 and soybean oil. The results showed that the content of acid components increased with the progress of crude oil biodegradation. A glass micromodel test demonstrated that the strain significantly increased oil recovery through interfacial tension reduction, wettability alteration and the mobility of microorganisms. In summary, the findings of this study indicate that the newly developed BD strain and its metabolites have great potential in MEOR. PMID:27872613

  17. Rhamnolipids produced by indigenous Acinetobacter junii from petroleum reservoir and its potential in enhanced oil recovery

    Directory of Open Access Journals (Sweden)

    Hao Dong

    2016-11-01

    Full Text Available Biosurfactant producers are crucial for incremental oil production in microbial enhanced oil recovery (MEOR processes. The isolation of biosurfactant-producing bacteria from oil reservoirs is important because they are considered suitable for the extreme conditions of the reservoir. In this work, a novel biosurfactant-producing strain Acinetobacter junii BD was isolated from a reservoir to reduce surface tension and emulsify crude oil. The biosurfactants produced by the strain were purified and then identified via electrospray ionization-Fourier transform ion cyclotron resonance mass spectrometry (ESI FT-ICR-MS. The biosurfactants generated by the strain were concluded to be rhamnolipids, the dominant rhamnolipids were C26H48O9, C28H52O9 and C32H58O13. The optimal carbon source and nitrogen source for biomass and biosurfactant production were NaNO3 and soybean oil. The results showed that the content of acid components increased with the progress of crude oil biodegradation. A glass micromodel test demonstrated that the strain significantly increased oil recovery through interfacial tension reduction, wettability alteration and the mobility of microorganisms. In summary, the findings of this study indicate that the newly developed BD strain and its metabolites have great potential in MEOR.

  18. Rhamnolipids Produced by Indigenous Acinetobacter junii from Petroleum Reservoir and its Potential in Enhanced Oil Recovery.

    Science.gov (United States)

    Dong, Hao; Xia, Wenjie; Dong, Honghong; She, Yuehui; Zhu, Panfeng; Liang, Kang; Zhang, Zhongzhi; Liang, Chuanfu; Song, Zhaozheng; Sun, Shanshan; Zhang, Guangqing

    2016-01-01

    Biosurfactant producers are crucial for incremental oil production in microbial enhanced oil recovery (MEOR) processes. The isolation of biosurfactant-producing bacteria from oil reservoirs is important because they are considered suitable for the extreme conditions of the reservoir. In this work, a novel biosurfactant-producing strain Acinetobacter junii BD was isolated from a reservoir to reduce surface tension and emulsify crude oil. The biosurfactants produced by the strain were purified and then identified via electrospray ionization-Fourier transform ion cyclotron resonance mass spectrometry (ESI FT-ICR-MS). The biosurfactants generated by the strain were concluded to be rhamnolipids, the dominant rhamnolipids were C 26 H 48 O 9 , C 28 H 52 O 9 , and C 32 H 58 O 13 . The optimal carbon source and nitrogen source for biomass and biosurfactant production were NaNO 3 and soybean oil. The results showed that the content of acid components increased with the progress of crude oil biodegradation. A glass micromodel test demonstrated that the strain significantly increased oil recovery through interfacial tension reduction, wettability alteration and the mobility of microorganisms. In summary, the findings of this study indicate that the newly developed BD strain and its metabolites have great potential in MEOR.

  19. 77 FR 8254 - Notice of Data Availability Concerning Renewable Fuels Produced From Palm Oil Under the RFS...

    Science.gov (United States)

    2012-02-14

    ... Concerning Renewable Fuels Produced From Palm Oil Under the RFS Program; Extension of Comment Period AGENCY... of Data Availability Concerning Renewable Fuels Produced From Palm Oil Under the RFS Program'' (the notice is herein referred to as the ``palm oil NODA''). EPA published a NODA, which included a request...

  20. 77 FR 19663 - Notice of Data Availability Concerning Renewable Fuels Produced from Palm Oil Under the RFS...

    Science.gov (United States)

    2012-04-02

    ... Concerning Renewable Fuels Produced from Palm Oil Under the RFS Program; Extension of Comment Period AGENCY... of Data Availability Concerning Renewable Fuels Produced from Palm Oil under the RFS Program'' (the notice is herein referred to as the ``palm oil NODA''). EPA published a NODA, which included a request...

  1. Producing bio-pellets from sunflower oil cake for use as an energy source

    Energy Technology Data Exchange (ETDEWEB)

    Kobayashi, Yuichi; Kato, Hitoshi; Kanai, Genta; Togashi, Tatsushi [National Agricultural Research Center (Japan)], E-mail: kobay@affrc.go.jp

    2008-07-01

    Pellet fuels were produced from ground sunflower oil cake using a pelletizer. The length, hardness, and powder characteristics of dried pellets depend on the initial water content of the oil cake. The appropriate values of water contents were 19.9 - 21.0% w.b. Oil cake pellets were found to contain 6.07% ash and 20.99 MJ/kg caloric value, which are within the standard range of wood pellets. Combustion experiments using a commercial pellet stove demonstrate that oil cake pellets burn as well as wood pellets. Oil cake pellets are useful as a fuel alternative to wood pellets. (author)

  2. Rhamnolipid produced by Pseudomonas aeruginosa USM-AR2 facilitates crude oil distillation.

    Science.gov (United States)

    Asshifa Md Noh, Nur; Al-Ashraf Abdullah, Amirul; Nasir Mohamad Ibrahim, Mohamad; Ramli Mohd Yahya, Ahmad

    2012-01-01

    A biosurfactant-producing and hydrocarbon-utilizing bacterium, Pseudomonas aeruginosa USM-AR2, was used to assist conventional distillation. Batch cultivation in a bioreactor gave a biomass of 9.4 g L(-1) and rhamnolipid concentration of 2.4 g L(-1) achieved after 72 h. Biosurfactant activity (rhamnolipid) was detected by the orcinol assay, emulsification index and drop collapse test. Pretreatment of crude oil TK-1 and AG-2 with a culture of P. aeruginosa USM-AR2 that contains rhamnolipid was proven to facilitate the distillation process by reducing the duration without reducing the quality of petroleum distillate. It showed a potential in reducing the duration of the distillation process, with at least 2- to 3-fold decreases in distillation time. This is supported by GC-MS analysis of the distillate where there was no difference between compounds detected in distillate obtained from treated or untreated crude oil. Calorimetric tests showed the calorie value of the distillate remained the same with or without treatment. These two factors confirmed that the quality of the distillate was not compromised and the incubation process by the microbial culture did not over-degrade the oil. The rhamnolipid produced by this culture was the main factor that enhanced the distillation performance, which is related to the emulsification of hydrocarbon chains in the crude oil. This biotreatment may play an important role to improve the existing conventional refinery and distillation process. Reducing the distillation times by pretreating the crude oil with a natural biosynthetic product translates to energy and cost savings in producing petroleum products.

  3. Methods of refining natural oils, and methods of producing fuel compositions

    Science.gov (United States)

    Firth, Bruce E.; Kirk, Sharon E.

    2015-10-27

    A method of refining a natural oil includes: (a) providing a feedstock that includes a natural oil; (b) reacting the feedstock in the presence of a metathesis catalyst to form a metathesized product that includes olefins and esters; (c) passivating residual metathesis catalyst with an agent that comprises nitric acid; (d) separating the olefins in the metathesized product from the esters in the metathesized product; and (e) transesterifying the esters in the presence of an alcohol to form a transesterified product and/or hydrogenating the olefins to form a fully or partially saturated hydrogenated product. Methods for suppressing isomerization of olefin metathesis products produced in a metathesis reaction, and methods of producing fuel compositions are described.

  4. Performance profiles of major energy producers 1995, January 1997

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-02-01

    This publication examines developments in the operations of the major U.S. energy-producing companies on a corporate level, by major line of business, by major function within each line of business, and by geographic area.

  5. Performance profiles of major energy producers 1995, January 1997

    International Nuclear Information System (INIS)

    1997-01-01

    This publication examines developments in the operations of the major U.S. energy-producing companies on a corporate level, by major line of business, by major function within each line of business, and by geographic area

  6. Plant-wide Control for Better De-oiling of Produced Water in Offshore Oil & Gas Production

    DEFF Research Database (Denmark)

    Yang, Zhenyu; Stigkær, Jens Peter; Løhndorf, Bo

    2013-01-01

    This paper discusses the application of plant-wide control philosophy to enhance the performance and capacity of the Produced Water Treatment (PWT) in offshore oil & gas production processes. Different from most existing facility- or material-based PWT innovation methods, the objective of this work...

  7. Isolation, screening, and characterization of surface-active agent-producing, oil-degrading marine bacteria of Mumbai Harbor.

    Science.gov (United States)

    Mohanram, Rajamani; Jagtap, Chandrakant; Kumar, Pradeep

    2016-04-15

    Diverse marine bacterial species predominantly found in oil-polluted seawater produce diverse surface-active agents. Surface-active agents produced by bacteria are classified into two groups based on their molecular weights, namely biosurfactants and bioemulsifiers. In this study, surface-active agent-producing, oil-degrading marine bacteria were isolated using a modified Bushnell-Haas medium with high-speed diesel as a carbon source from three oil-polluted sites of Mumbai Harbor. Surface-active agent-producing bacterial strains were screened using nine widely used methods. The nineteen bacterial strains showed positive results for more than four surface-active agent screening methods; further, these strains were characterized using biochemical and nucleic acid sequencing methods. Based on the results, the organisms belonged to the genera Acinetobacter, Alcanivorax, Bacillus, Comamonas, Chryseomicrobium, Halomonas, Marinobacter, Nesterenkonia, Pseudomonas, and Serratia. The present study confirmed the prevalence of surface-active agent-producing bacteria in the oil-polluted waters of Mumbai Harbor. Copyright © 2016 Elsevier Ltd. All rights reserved.

  8. Isolation and Characterization of Biosurfactant Producing Bacteria for the Application in Enhanced Oil Recovery

    Science.gov (United States)

    Prasad, Niraj; Dasgupta, Sumita; Chakraborty, Mousumi; Gupta, Smita

    2017-07-01

    In the present study, a biosurfactant producing bacterial strain was isolated, screened and identified. Further, various fermentation conditions (such as pH (5-10), incubation period (24-96h) and incubation temperature (20-60 °C) were optimized for maximum production of biosurfactant. The produced biosurfactant was characterized by measuring emulsification index, foaming characteristics, rhamnolipid detection, interfacial tension between water and oil and stability against pH and temperature for its potential application in oil recovery process. The additional oil recovery for two different sand, sand1 and sand2, was found to be 49% and 38%, respectively.

  9. The end of cheap oil

    International Nuclear Information System (INIS)

    Zagar, J.J.; Campbell, C.J.

    1999-01-01

    Easy to find 'conventional' oil in huge quantities has fueled and satisfied the World's thirst for energy this century. About 95% of all oil produced-and 90% of today's production---comes from this group of hydrocarbons. But the coming century of the new millennium will see the exit of conventional oil as a major player on the World's energy stage. Already, outside the Middle East, conventional oil production is on the decline. And the Middle East with its vast reservoirs of oil will soon reach the mid-point of depletion and begin its irreversible decline. Currently, one barrel of oil is being found for every four barrels that are produced. The Middle East now supplies 30% of the World's conventional oil production and that trend is rising because, unlike in the 1970s, no new major provinces, save perhaps the Caspian, are there to deliver flush production. The stage is now set for another 'energy crisis' starting with higher prices from Middle East control and followed by the onset of physical shortage around 2010. We face something new to human experience. (author)

  10. Low oxygen biomass-derived pyrolysis oils and methods for producing the same

    Science.gov (United States)

    Marinangeli, Richard; Brandvold, Timothy A; Kocal, Joseph A

    2013-08-27

    Low oxygen biomass-derived pyrolysis oils and methods for producing them from carbonaceous biomass feedstock are provided. The carbonaceous biomass feedstock is pyrolyzed in the presence of a catalyst comprising base metal-based catalysts, noble metal-based catalysts, treated zeolitic catalysts, or combinations thereof to produce pyrolysis gases. During pyrolysis, the catalyst catalyzes a deoxygenation reaction whereby at least a portion of the oxygenated hydrocarbons in the pyrolysis gases are converted into hydrocarbons. The oxygen is removed as carbon oxides and water. A condensable portion (the vapors) of the pyrolysis gases is condensed to low oxygen biomass-derived pyrolysis oil.

  11. Physicochemical characterization and quality of cold-pressed peanut oil obtained from organically produced peanuts from Macedonian Virginia” variety

    Energy Technology Data Exchange (ETDEWEB)

    Kostadinovic Velickovska, S.; Mitrev, S.; Mihajlov, L.

    2016-07-01

    The physicochemical characterization and quality of cold pressed peanut edible oil from the “Virginia” variety, organically produced from the region of Macedonia, were examined in this work for the first time. The fatty acid composition of the oil showed almost equal levels of oleic and linoleic acids with an abundance of 34.19±0.01 and 36.13±0.01%, respectively. The most dominant saturated fatty acid was palmitic acid with a level of 10.06±0.00%. The level of tocopherols and other vitamin-E-related compounds was in strong agreement with the antioxidant activity of the oils measured by the DPPH assay. Almost equal amounts of α and γ tocopherols indicated an antioxidant potential of 288.63±59.78 mg·L−1 α-tocopherol. Phytosterols, as minor compounds present in the oils, can be additional antioxidants responsible for the health benefits of this oil in human nutrition. The four major pytosterols were β-sitosterol (1812.21±22.17 mg·kg−1 oil), champesterol (320.55±17.07 mg·kg−1 oil), Δ5-avenasterol (236.16±14.18 mg·kg−1) and stigmasterol (133.12±12.51 mg·kg−1 oil). Induction time, Peroxide number, FFA and specific extinction (K232 and K270, values 1.82 and 0.22) gave us an indication of the oxidative stability of cold pressed peanut oil. (Author)

  12. Transesterification of mustard (Brassica nigra) seed oil with ethanol: Purification of the crude ethyl ester with activated carbon produced from de-oiled cake

    International Nuclear Information System (INIS)

    Fadhil, Abdelrahman B.; Abdulahad, Waseem S.

    2014-01-01

    Highlights: • Biodiesel ethyl ester has been developed from mustard seed oil. • Variables affect the transesterification were investigated. • Dry washing using the activated carbon produced from the extraction remaining was applied to purify the ethyl esters. • Properties of the produced fuels were measured. • Blending of the produced ethyl ester with petro diesel was also investigated. - Abstract: The present study reports the production of mustard seed oil ethyl esters (MSOEE) through alkali-catalyzed transesterification with ethanol using potassium hydroxide as a catalyst. The influence of the process parameters such as catalyst concentration, ethanol to oil molar ratio, reaction temperature, reaction duration and the catalyst type was investigated so as to find out the optimal conditions for the transesterification process. As a result, optimum conditions for production of MSOEE were found to be: 0.90% KOH wt/wt of oil, 8:1 ethanol to oil molar ratio, a reaction temperature of 60 °C, and a reaction time of 60 min. Dry washing method with (2.50% wt.) of the activated carbon that was produced from the de-oiled cake was used to purify the crude ethyl ester from the residual catalyst and glycerol. The transesterification process provided a yield of 94% w/w of ethyl esters with an ester content of 98.22% wt. under the optimum conditions. Properties of the produced ethyl esters satisfied the specifications prescribed by the ASTM standards. Blending MSOEE with petro diesel was also investigated. The results showed that the ethyl esters had a slight influence on the properties of petro diesel

  13. 21 CFR 172.225 - Methyl and ethyl esters of fatty acids produced from edible fats and oils.

    Science.gov (United States)

    2010-04-01

    ... from edible fats and oils. 172.225 Section 172.225 Food and Drugs FOOD AND DRUG ADMINISTRATION... Methyl and ethyl esters of fatty acids produced from edible fats and oils. Methyl esters and ethyl esters of fatty acids produced from edible fats and oils may be safely used in food, subject to the...

  14. TREATMENT OF PRODUCED OIL AND GAS WATERS WITH SURFACTANT-MODIFIED ZEOLITE

    Energy Technology Data Exchange (ETDEWEB)

    Lynn E. Katz; R.S. Bowman; E.J. Sullivan

    2003-11-01

    Co-produced water from the oil and gas industry accounts for a significant waste stream in the United States. It is by some estimates the largest single waste stream in the country, aside from nonhazardous industrial wastes. Characteristics of produced water include high total dissolved solids content, dissolved organic constituents such as benzene and toluene, an oil and grease component, and chemicals added during the oil-production process. While most of the produced water is disposed via reinjection, some must be treated to remove organic constituents before the water is discharged. Current treatment options are successful in reducing the organic content; however, they cannot always meet the levels of current or proposed regulations for discharged water. Therefore, an efficient, cost-effective treatment technology is needed. Surfactant-modified zeolite (SMZ) has been used successfully to treat contaminated ground water for organic and inorganic constituents. In addition, the low cost of natural zeolites makes their use attractive in water-treatment applications. This report summarizes the work and results of this four-year project. We tested the effectiveness of surfactant-modified zeolite (SMZ) for removal of BTEX with batch and column experiments using waters with BTEX concentrations that are comparable to those of produced waters. The data from our experimental investigations showed that BTEX sorption to SMZ can be described by a linear isotherm model, and competitive effects between compounds were not significant. The SMZ can be readily regenerated using air stripping. We field-tested a prototype SMZ-based water treatment system at produced water treatment facilities and found that the SMZ successfully removes BTEX from produced waters as predicted by laboratory studies. When compared to other existing treatment technologies, the cost of the SMZ system is very competitive. Furthermore, the SMZ system is relatively compact, does not require the storage of

  15. Chemical composition and antiprotozoal activities of Colombian Lippia spp essential oils and their major components

    Directory of Open Access Journals (Sweden)

    Patricia Escobar

    2010-03-01

    Full Text Available The chemical composition and biological activities of 19 essential oils and seven of their major components were tested against free and intracellular forms of Leishmania chagasi and Trypanosoma cruzi parasites as well as Vero and THP-1 mammalian cell lines. The essential oils were obtained from different species of Lippia, a widely distributed genus of Colombian plants. They were extracted by microwave radiation-assisted hydro-distillation and characterised by GC-FID and GC-MS. The major components were geranial, neral, limonene, nerol, carvacrol, p-cymene, γ-terpinene, carvone and thymol. The essential oil of Lippia alba exhibited the highest activity against T. cruzi epimastigotes and intracellular amastigotes with an IC50 of 5.5 μg/mL and 12.2 μg/mL, respectively. The essential oil of Lippia origanoides had an IC50 of 4.4 μg/mL in L. chagasi promastigotes and exhibited no toxicity in mammalian cells. Thymol (IC50 3.2 ± 0.4 μg/mL and S-carvone (IC50 6.1 ± 2.2 μg/mL, two of the major components of the active essential oils, were active on intracellular amastigotes of T. cruziinfected Vero cells, with a selective index greater than 10. None of the essential oils or major components tested in this study was active on amastigotes of L. chagasi infected THP-1 cells.

  16. An efficient thermotolerant and halophilic biosurfactant-producing bacterium isolated from Dagang oil field for MEOR application

    Science.gov (United States)

    Wu, Langping; Richnow, Hans; Yao, Jun; Jain, Anil

    2014-05-01

    Dagang Oil field (Petro China Company Limited) is one of the most productive oil fields in China. In this study, 34 biosurfactant-producing strains were isolated and cultured from petroleum reservoir of Dagang oil field, using haemolytic assay and the qualitative oil-displacement test. On the basis of 16S rDNA analysis, the isolates were closely related to the species in genus Pseudomonas, Staphylococcus and Bacillus. One of the isolates identified as Bacillus subtilis BS2 were selected for further study. This bacterium was able to produce a type of biosurfactant with excessive foam-forming properties at 37ºC as well as at higher temperature of 55ºC. The biosurfactant produced by the strain BS2 could reduce the surface tension of the culture broth from 70.87 mN/m to 28.97 mN/m after 8 days of incubation at 37ºC and to 36.15 mN/m after 20 days of incubation at 55ºC, respectively. The biosurfactant showed stability at high temperature (up to 120ºC), a wide range of pH (2 to 12) and salt concentrations (up to 12%) offering potential for biotechnology. Fourier transform infrared (FT-IR) spectrum of extracted biosurfactant tentatively characterized the produced biosurfactant as glycolipid derivative. Elemental analysis of the biosurfactant by energy dispersive X-ray spectroscopy (EDS) reveals that the biosurfactant was anionic in nature. 15 days of biodegradation of crude oil suggested a preferential usage of n-alkane upon microbial metabolism of BS2 as a carbon substrate and consequently also for the synthesis of biosurfactants. Core flood studies for oil release indicated 9.6% of additional oil recovery over water flooding at 37ºC and 7.2% of additional oil recovery at 55 ºC. Strain BS2 was characterized as an efficient biosurfactant-producing, thermotolerant and halophillic bacterium and has the potential for application for microbial enhanced oil recovery (MEOR) through water flooding in China's oil fields even in situ as adapted to reservoir chemistry and

  17. Hydrotreatment of bio-oil distillates produced from pyrolysis and hydrothermal liquefaction of duckweed: A comparison study.

    Science.gov (United States)

    Wang, Feng; Tian, Ye; Zhang, Cai-Cai; Xu, Yu-Ping; Duan, Pei-Gao

    2018-09-15

    A comprehensive comparison of hydrothermal liquefaction (HTL) to the pyrolysis of duckweed was conducted to determine the yields and components of the crude bio-oils and their distillates. The upgrading behaviors of the distillates were thoroughly investigated with the use of used engine oil as a solvent. With all other variables fixed, HTL produced crude bio-oil with a lower H/C ratio (1.28 ± 0.03) than pyrolysis did (1.45 ± 0.04). However, its distillates had a higher H/C ratio (1.60 ± 0.05) and total yield (66.1 ± 2.0 wt%) than pyrolysis (1.46 ± 0.04 and 47.2 ± 1.4 wt%, respectively). Phenolics and nitrogenous heterocycles constituted relatively major proportions of the two crude bio-oils and most of their distillates. Obvious differences in molecular composition between the two crude bio-oils and their distillates were ascribed to the distinct impacts of HTL and pyrolysis and were affected by the distillate temperature. Co-hydrotreating with used engine oil (UEO) provided the upgraded bio-oils much higher H/C ratios (~1.78 ± 0.05) and higher heating values (~45.5 ± 1.4 MJ·kg -1 ), as well as much lower contents of N, O and S compared to their initial distillates. Aromatics and alkanes constituted a large proportion in most of upgraded bio-oils. N removal from the pyrolysis distillates was easier than from the HTL distillates. Distinct differences in yields and molecular compositions for the upgraded bio-oils were also attributed to the different influences associated with the two conversion routes. Copyright © 2018 Elsevier B.V. All rights reserved.

  18. Sector Modeling for the Prediction and Evaluation of Cretan olive oil

    NARCIS (Netherlands)

    Migdalas, A.; Baourakis, G.; Kalogeras, N.; Meriem, H.B.

    2004-01-01

    Greece is a major international olive oil producer. Olive oil varieties constitute the major crops for Greek farmers growing certain oriental olive oil varieties. Currently, the olive oil sector in Greece is undergoing substantial changes and the response of farmers and consumers to this will be a

  19. Chemical Characterization of Major and Minor Compounds of Nut Oils: Almond, Hazelnut, and Pecan Nut

    Directory of Open Access Journals (Sweden)

    Gabriel D. Fernandes

    2017-01-01

    Full Text Available The aim of this work was to characterize the major and minor compounds of laboratory-extracted and commercial oils from sweet almond, hazelnut, and pecan nut. Oils from sweet almond, hazelnut, and pecan nut were obtained by means of an expeller system, while the corresponding commercial oils were provided from Vital Âtman (BR. The contents of triacylglycerols, fatty acids, aliphatic and terpenic alcohols, desmethyl-, methyl-, and dimethylsterols, squalene, and tocopherols were determined. Oleic, palmitic, and linoleic acids were the main fatty acids. Desmethylsterols were the principal minor compounds with β-sitosterol being the most abundant component. Low amounts of aliphatic and terpenic alcohols were also found. The major tocopherol in hazelnut and sweet almond oils was α-tocopherol, whereas γ-tocopherol prevailed in pecan nut oil. Principal component analysis made it possible for us to differentiate among samples, as well as to distinguish between commercial and laboratory-extracted oils. Heatmap highlighted the main variables featuring each sample. Globally, these results have brought a new approach on nut oil characterization.

  20. OIL AS POLITICAL WEAPON

    Directory of Open Access Journals (Sweden)

    Mariana, BUICAN

    2013-12-01

    Full Text Available Oil (called by some black gold has not always been as coveted and used, but only in the last hundred years has established itself as a highly sought after as an indispensable proper functioning of modern economic activity that an important factor in international politics. International oil regime has changed in the last decades. In 1960, oil regime was a private oligopol which had links with governments main consuming countries. By then the price of a barrel of oil was two U.S. dollars and seven major transnational oil companies decided the amount of oil that will be produced. Meanwhile the world region with the largest oil exports were more strongly expressed nationalism and decolonization. Result, it was so in the late 60s in the region occur independent states. They have created an organization aim of this resource to their advantage - OPEC (Organization of Petroleum Exporting Countries. Thus since 1973 there have been changes in the international regime governing oil field, namely producing countries were fixed production rate and price. After this time the oil weapon has become increasingly important in the management of international relations. Oil influenced the great powers to Middle East conflicts that occurred in the last century, but their attitude about the emergence of new sources of oil outside OPEC. In the late 90's, Russia has become a major supplier of oil to the West.

  1. Characterization of Biosurfactant Produced during Degradation of Hydrocarbons Using Crude Oil As Sole Source of Carbon.

    Science.gov (United States)

    Patowary, Kaustuvmani; Patowary, Rupshikha; Kalita, Mohan C; Deka, Suresh

    2017-01-01

    Production and spillage of petroleum hydrocarbons which is the most versatile energy resource causes disastrous environmental pollution. Elevated oil degrading performance from microorganisms is demanded for successful microbial remediation of those toxic pollutants. The employment of biosurfactant-producing and hydrocarbon-utilizing microbes enhances the effectiveness of bioremediation as biosurfactant plays a key role by making hydrocarbons bio-available for degradation. The present study aimed the isolation of a potent biosurfactant producing indigenous bacteria which can be employed for crude oil remediation, along with the characterization of the biosurfactant produced during crude oil biodegradation. A potent bacterial strain Pseudomonas aeruginosa PG1 (identified by 16s rDNA sequencing) was isolated from hydrocarbon contaminated soil that could efficiently produce biosurfactant by utilizing crude oil components as the carbon source, thereby leading to the enhanced degradation of the petroleum hydrocarbons. Strain PG1 could degrade 81.8% of total petroleum hydrocarbons (TPH) after 5 weeks of culture when grown in mineral salt media (MSM) supplemented with 2% (v/v) crude oil as the sole carbon source. GCMS analysis of the treated crude oil samples revealed that P. aeruginosa PG1 could potentially degrade various hydrocarbon contents including various PAHs present in the crude oil. Biosurfactant produced by strain PG1 in the course of crude oil degradation, promotes the reduction of surface tension (ST) of the culture medium from 51.8 to 29.6 mN m -1 , with the critical micelle concentration (CMC) of 56 mg L -1 . FTIR, LC-MS, and SEM-EDS studies revealed that the biosurfactant is a rhamnolipid comprising of both mono and di rhamnolipid congeners. The biosurfactant did not exhibit any cytotoxic effect to mouse L292 fibroblastic cell line, however, strong antibiotic activity against some pathogenic bacteria and fungus was observed.

  2. Characterization of Biosurfactant Produced during Degradation of Hydrocarbons Using Crude Oil As Sole Source of Carbon

    Science.gov (United States)

    Patowary, Kaustuvmani; Patowary, Rupshikha; Kalita, Mohan C.; Deka, Suresh

    2017-01-01

    Production and spillage of petroleum hydrocarbons which is the most versatile energy resource causes disastrous environmental pollution. Elevated oil degrading performance from microorganisms is demanded for successful microbial remediation of those toxic pollutants. The employment of biosurfactant-producing and hydrocarbon-utilizing microbes enhances the effectiveness of bioremediation as biosurfactant plays a key role by making hydrocarbons bio-available for degradation. The present study aimed the isolation of a potent biosurfactant producing indigenous bacteria which can be employed for crude oil remediation, along with the characterization of the biosurfactant produced during crude oil biodegradation. A potent bacterial strain Pseudomonas aeruginosa PG1 (identified by 16s rDNA sequencing) was isolated from hydrocarbon contaminated soil that could efficiently produce biosurfactant by utilizing crude oil components as the carbon source, thereby leading to the enhanced degradation of the petroleum hydrocarbons. Strain PG1 could degrade 81.8% of total petroleum hydrocarbons (TPH) after 5 weeks of culture when grown in mineral salt media (MSM) supplemented with 2% (v/v) crude oil as the sole carbon source. GCMS analysis of the treated crude oil samples revealed that P. aeruginosa PG1 could potentially degrade various hydrocarbon contents including various PAHs present in the crude oil. Biosurfactant produced by strain PG1 in the course of crude oil degradation, promotes the reduction of surface tension (ST) of the culture medium from 51.8 to 29.6 mN m−1, with the critical micelle concentration (CMC) of 56 mg L−1. FTIR, LC-MS, and SEM-EDS studies revealed that the biosurfactant is a rhamnolipid comprising of both mono and di rhamnolipid congeners. The biosurfactant did not exhibit any cytotoxic effect to mouse L292 fibroblastic cell line, however, strong antibiotic activity against some pathogenic bacteria and fungus was observed. PMID:28275373

  3. China's oil resources

    Energy Technology Data Exchange (ETDEWEB)

    Wiesegart, K

    1981-03-01

    The United Nations International Meeting on Petroleum Geology is being held this month from 18-25 in China, a country whose oil reserves up to mid-sixties had been judged by foreign observers to be minute and the development of her oil sector of no major importance. Today, with an annual crude output of 106 mn tons, China already ranks ninth among the world's oil producers. And, with the prospect of a further advance towards leadership among producers and exporters of the coveted energy material, the West is showing growing interest in China's energy potential. How real is this prospect forms the subject of this article. 3 tables.

  4. Volatile-organic molecular characterization of shale-oil produced water from the Permian Basin.

    Science.gov (United States)

    Khan, Naima A; Engle, Mark; Dungan, Barry; Holguin, F Omar; Xu, Pei; Carroll, Kenneth C

    2016-04-01

    Growth in unconventional oil and gas has spurred concerns on environmental impact and interest in beneficial uses of produced water (PW), especially in arid regions such as the Permian Basin, the largest U.S. tight-oil producer. To evaluate environmental impact, treatment, and reuse potential, there is a need to characterize the compositional variability of PW. Although hydraulic fracturing has caused a significant increase in shale-oil production, there are no high-resolution organic composition data for the shale-oil PW from the Permian Basin or other shale-oil plays (Eagle Ford, Bakken, etc.). PW was collected from shale-oil wells in the Midland sub-basin of the Permian Basin. Molecular characterization was conducted using high-resolution solid phase micro extraction gas chromatography time-of-flight mass spectrometry. Approximately 1400 compounds were identified, and 327 compounds had a >70% library match. PW contained alkane, cyclohexane, cyclopentane, BTEX (benzene, toluene, ethylbenzene, and xylene), alkyl benzenes, propyl-benzene, and naphthalene. PW also contained heteroatomic compounds containing nitrogen, oxygen, and sulfur. 3D van Krevelen and double bond equivalence versus carbon number analyses were used to evaluate molecular variability. Source composition, as well as solubility, controlled the distribution of volatile compounds found in shale-oil PW. The salinity also increased with depth, ranging from 105 to 162 g/L total dissolved solids. These data fill a gap for shale-oil PW composition, the associated petroleomics plots provide a fingerprinting framework, and the results for the Permian shale-oil PW suggest that partial treatment of suspended solids and organics would support some beneficial uses such as onsite reuse and bio-energy production. Copyright © 2016 Elsevier Ltd. All rights reserved.

  5. Volatile-organic molecular characterization of shale-oil produced water from the Permian Basin

    Science.gov (United States)

    Khan, Naima A.; Engle, Mark A.; Dungan, Barry; Holguin, F. Omar; Xu, Pei; Carroll, Kenneth C.

    2016-01-01

    Growth in unconventional oil and gas has spurred concerns on environmental impact and interest in beneficial uses of produced water (PW), especially in arid regions such as the Permian Basin, the largest U.S. tight-oil producer. To evaluate environmental impact, treatment, and reuse potential, there is a need to characterize the compositional variability of PW. Although hydraulic fracturing has caused a significant increase in shale-oil production, there are no high-resolution organic composition data for the shale-oil PW from the Permian Basin or other shale-oil plays (Eagle Ford, Bakken, etc.). PW was collected from shale-oil wells in the Midland sub-basin of the Permian Basin. Molecular characterization was conducted using high-resolution solid phase micro extraction gas chromatography time-of-flight mass spectrometry. Approximately 1400 compounds were identified, and 327 compounds had a >70% library match. PW contained alkane, cyclohexane, cyclopentane, BTEX (benzene, toluene, ethylbenzene, and xylene), alkyl benzenes, propyl-benzene, and naphthalene. PW also contained heteroatomic compounds containing nitrogen, oxygen, and sulfur. 3D van Krevelen and double bond equivalence versus carbon number analyses were used to evaluate molecular variability. Source composition, as well as solubility, controlled the distribution of volatile compounds found in shale-oil PW. The salinity also increased with depth, ranging from 105 to 162 g/L total dissolved solids. These data fill a gap for shale-oil PW composition, the associated petroleomics plots provide a fingerprinting framework, and the results for the Permian shale-oil PW suggest that partial treatment of suspended solids and organics would support some beneficial uses such as onsite reuse and bio-energy production.

  6. TECHNOLOGY TRANSFER TO U.S. INDEPENDENT OIL AND NATURAL GAS PRODUCERS

    Energy Technology Data Exchange (ETDEWEB)

    Unknown

    2002-05-31

    The Petroleum Technology Transfer Council (PTTC) continued pursuing its mission of helping U.S. independent oil and natural gas producers make timely, informed technology decisions. Networking opportunities that occur with a Houston Headquarters (HQ) location are increasing name awareness. Focused efforts by Executive Director Don Duttlinger to interact with large independents, national service companies and some majors are continuing to supplement the support base of the medium to smaller industry participants around the country. PTTC is now involved in many of the technology-related activities that occur in high oil and natural gas activity areas. Access to technology remains the driving force for those who do not have in-house research and development capabilities and look to the PTTC to provide services and options for increased efficiency. Looking forward to the future, the Board, Regional Lead Organization (RLO) Directors and HQ staff developed a 10-year vision outlining what PTTC needs to accomplish in supporting a national energy plan. This vision has been communicated to Department of Energy (DOE) staff and PTTC looks forward to continuing this successful federal-state-industry partnership. As part of this effort, several more examples of industry using information gained through PTTC activities to impact their bottom line were identified. Securing the industry pull on technology acceptance was the cornerstone of this directional plan.

  7. Predicting the nutritional health status of locally produced palm oil ...

    African Journals Online (AJOL)

    Three physical properties of locally produced palm oil – viscosity, thermal conductivity and density for varying temperatures were determined. The values obtained were compared with corresponding internationally stipulated standard values using statistics of mean and graphs. The purpose of the comparison was to predict ...

  8. Oil shale derived pollutant control materials and methods and apparatuses for producing and utilizing the same

    Science.gov (United States)

    Boardman, Richard D.; Carrington, Robert A.

    2010-05-04

    Pollution control substances may be formed from the combustion of oil shale, which may produce a kerogen-based pyrolysis gas and shale sorbent, each of which may be used to reduce, absorb, or adsorb pollutants in pollution producing combustion processes, pyrolysis processes, or other reaction processes. Pyrolysis gases produced during the combustion or gasification of oil shale may also be used as a combustion gas or may be processed or otherwise refined to produce synthetic gases and fuels.

  9. Characterization of dioxygenases and biosurfactants produced by crude oil degrading soil bacteria

    Directory of Open Access Journals (Sweden)

    Santhakumar Muthukamalam

    Full Text Available ABSTRACT Role of microbes in bioremediation of oil spills has become inevitable owing to their eco friendly nature. This study focused on the isolation and characterization of bacterial strains with superior oil degrading potential from crude-oil contaminated soil. Three such bacterial strains were selected and subsequently identified by 16S rRNA gene sequence analysis as Corynebacterium aurimucosum, Acinetobacter baumannii and Microbacterium hydrocarbonoxydans respectively. The specific activity of catechol 1,2 dioxygenase (C12O and catechol 2,3 dioxygenase (C23O was determined in these three strains wherein the activity of C12O was more than that of C23O. Among the three strains, Microbacterium hydrocarbonoxydans exhibited superior crude oil degrading ability as evidenced by its superior growth rate in crude oil enriched medium and enhanced activity of dioxygenases. Also degradation of total petroleum hydrocarbon (TPH in crude oil was higher with Microbacterium hydrocarbonoxydans. The three strains also produced biosurfactants of glycolipid nature as indicated d by biochemical, FTIR and GCMS analysis. These findings emphasize that such bacterial strains with superior oil degrading capacity may find their potential application in bioremediation of oil spills and conservation of marine and soil ecosystem.

  10. Identification, Verification, and Compilation of Produced Water Management Practices for Conventional Oil and Gas Production Operations

    Energy Technology Data Exchange (ETDEWEB)

    Rachel Henderson

    2007-09-30

    The project is titled 'Identification, Verification, and Compilation of Produced Water Management Practices for Conventional Oil and Gas Production Operations'. The Interstate Oil and Gas Compact Commission (IOGCC), headquartered in Oklahoma City, Oklahoma, is the principal investigator and the IOGCC has partnered with ALL Consulting, Inc., headquartered in Tulsa, Oklahoma, in this project. State agencies that also have partnered in the project are the Wyoming Oil and Gas Conservation Commission, the Montana Board of Oil and Gas Conservation, the Kansas Oil and Gas Conservation Division, the Oklahoma Oil and Gas Conservation Division and the Alaska Oil and Gas Conservation Commission. The objective is to characterize produced water quality and management practices for the handling, treating, and disposing of produced water from conventional oil and gas operations throughout the industry nationwide. Water produced from these operations varies greatly in quality and quantity and is often the single largest barrier to the economic viability of wells. The lack of data, coupled with renewed emphasis on domestic oil and gas development, has prompted many experts to speculate that the number of wells drilled over the next 20 years will approach 3 million, or near the number of current wells. This level of exploration and development undoubtedly will draw the attention of environmental communities, focusing their concerns on produced water management based on perceived potential impacts to fresh water resources. Therefore, it is imperative that produced water management practices be performed in a manner that best minimizes environmental impacts. This is being accomplished by compiling current best management practices for produced water from conventional oil and gas operations and to develop an analysis tool based on a geographic information system (GIS) to assist in the understanding of watershed-issued permits. That would allow management costs to be kept in

  11. Microbiological techniques for paraffin reduction in producing oil wells: Final report

    Energy Technology Data Exchange (ETDEWEB)

    Oppenheimer, C. H.; Hiebert, F. K.

    1989-04-01

    Alpha Environmental has completed an eighteen month field oriented, cooperative research program with the US Department of Energy to demonstrate a new economically viable process using petroleum degrading microorganisms, a biocatalyst, formation water and inorganic nutrients to recover residual oil from reservoirs. Alpha's mixed community of microorganisms decomposes crude oil to produce detergents, CO/sub 2/, and new cells, thus mechanically and chemically releasing oil from reservoir pores. The naturally-occurring bacteria utilized in this project were previously selected by screening and isolating microorganisms from soils contaminated with crude oil and petroleum products. The activity and level of salt tolerance (to 20% salinity) of the bacteria is enhanced by a biocatalyst, previously developed by Alpha Environmental. Field evidence suggests that the biocatalyst provides catalytic oxygen to the microorganisms in the reservoir, which augments low levels of in-situ molecular oxygen. 25 refs., 10 figs., 6 tabs.

  12. Application of Biosurfactants Produced by Pseudomonas putida using Crude Palm Oil (CPO) as Substrate for Crude Oil Recovery using Batch Method

    Science.gov (United States)

    Suryanti, V.; Handayani, D. S.; Masykur, A.; Septyaningsih, I.

    2018-03-01

    The application of biosurfactants which have been produced by Pseudomonas putida in nutrient broth medium supplemented with NaCl and crude palm oil (CPO) for oil recovery has been evaluated. The crude and purified biosurfactants have been examined for oil recovery from a laboratory oil-contaminated sand in agitated flask (batch method). Two synthetic surfactants and water as control was also performed for oil recovery as comparisons. Using batch method, the results showed that removing ability of crude oil from the oil-contaminated sand by purified and crude biosurfactants were 79.40±3.10 and 46.84±2.23 %, respectively. On other hand, the recoveries obtained with the SDS, Triton X-100 and water were 94.33±0.47, 74.84±7.39 and 34.42±1.21%respectively.

  13. Catalytic upgrading of bio-oil produced from hydrothermal liquefaction of Nannochloropsis sp.

    Science.gov (United States)

    Shakya, Rajdeep; Adhikari, Sushil; Mahadevan, Ravishankar; Hassan, El Barbary; Dempster, Thomas A

    2018-03-01

    Upgrading of bio-oil obtained from hydrothermal liquefaction (HTL) of algae is necessary for it to be used as a fuel. In this study, bio-oil obtained from HTL of Nannochloropsis sp. was upgraded using five different catalysts (Ni/C, ZSM-5, Ni/ZSM-5, Ru/C and Pt/C) at 300 °C and 350 °C. The upgraded bio-oil yields were higher at 300 °C; however, higher quality upgraded bio-oils were obtained at 350 °C. Ni/C gave the maximum upgraded bio-oil yield (61 wt%) at 350 °C. However, noble metal catalysts (Ru/C and Pt/C) gave the better upgraded bio-oils in terms of acidity, heating values, and nitrogen values. The higher heating value of the upgraded bio-oils ranged from 40 to 44 MJ/kg, and the nitrogen content decreased from 5.37 to 1.29 wt%. Most of the upgraded bio-oils (35-40 wt%) were in the diesel range. The major components present in the gaseous products were CH 4 , CO, CO 2 and lower alkanes. Copyright © 2017 Elsevier Ltd. All rights reserved.

  14. Determination of naturally occurring radionuclides in scales produced in oil industry

    Energy Technology Data Exchange (ETDEWEB)

    Al-Masri, M S; Ali, A F; Kitue, M; Kawash, A [Atomic Energy Commission, Dept. of Radiation Protection and Nuclear Safety, Damascus (Syrian Arab Republic)

    1997-04-01

    Scales produced by Oil production operations contain relatively high concentrations of natural radionuclides especially radium isotopes (Ra-226, Ra-228, Ra-224) and their daughters. These scales deposit in oil surface equipment such as separator tanks, tubular, and storage tanks. In this work, naturally occurring radionuclides and radiation exposure levels in some Syrian oil lines have been determined. Radiation measurements have shown high radiation exposure in some production sites and reached about 23 {mu}Sv/hr (production wellhead) which is higher than the normal background (0.09 - 012 {mu}Sv/hr). The highest value of the exposure around storage tanks was about o.5 {mu}Sv/hr. Moreover, the highest concentration of radionuclides in scales were found to be 47000 Bq/Kg and 55000 Bq/Kg for Ra-226 and Ra-228 respectively while in sludge samples, the Ra-226 concentration was about 24.2 Bq/Kg, a relatively very low activity. In addition, results have shown that soil contamination can occur by disposal of produced water to the surrounding environment. Furthermore, the present paper shows some of protection procedures, which should be followed by workers for radiation protection. (author). 10 refs., 4 tabs.

  15. Gasoline from biomass through refinery-friendly carbohydrate-based bio-oil produced by ketalization.

    Science.gov (United States)

    Batalha, Nuno; da Silva, Alessandra V; de Souza, Matheus O; da Costa, Bruna M C; Gomes, Elisa S; Silva, Thiago C; Barros, Thalita G; Gonçalves, Maria L A; Caramão, Elina B; dos Santos, Luciana R M; Almeida, Marlon B B; de Souza, Rodrigo O M A; Lam, Yiu L; Carvalho, Nakédia M F; Miranda, Leandro S M; Pereira, Marcelo M

    2014-06-01

    The introduction of biomass-derived compounds as an alternative feed into the refinery structure that already exists can potentially converge energy uses with ecological sustainability. Herein, we present an approach to produce a bio-oil based on carbohydrate-derived isopropylidene ketals obtained by reaction with acetone under acidic conditions directly from second-generation biomass. The obtained bio-oil showed a greater chemical inertness and miscibility with gasoil than typical bio-oil from fast pyrolysis. Catalytic upgrading of the bio-oil over zeolites (USY and Beta) yielded gasoline with a high octane number. Moreover, the co-processing of gasoil and bio-oil improved the gasoline yield and quality compared to pure gasoil and also reduced the amount of oxygenated compounds and coke compared with pure bio-oil, which demonstrates a synergistic effect. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  16. Recovery of Fresh Water Resources from Desalination of Brine Produced During Oil and Gas Production Operations

    Energy Technology Data Exchange (ETDEWEB)

    David B. Burnett; Mustafa Siddiqui

    2006-12-29

    Management and disposal of produced water is one of the most important problems associated with oil and gas (O&G) production. O&G production operations generate large volumes of brine water along with the petroleum resource. Currently, produced water is treated as a waste and is not available for any beneficial purposes for the communities where oil and gas is produced. Produced water contains different contaminants that must be removed before it can be used for any beneficial surface applications. Arid areas like west Texas produce large amount of oil, but, at the same time, have a shortage of potable water. A multidisciplinary team headed by researchers from Texas A&M University has spent more than six years is developing advanced membrane filtration processes for treating oil field produced brines The government-industry cooperative joint venture has been managed by the Global Petroleum Research Institute (GPRI). The goal of the project has been to demonstrate that treatment of oil field waste water for re-use will reduce water handling costs by 50% or greater. Our work has included (1) integrating advanced materials into existing prototype units and (2) operating short and long-term field testing with full size process trains. Testing at A&M has allowed us to upgrade our existing units with improved pre-treatment oil removal techniques and new oil tolerant RO membranes. We have also been able to perform extended testing in 'field laboratories' to gather much needed extended run time data on filter salt rejection efficiency and plugging characteristics of the process train. The Program Report describes work to evaluate the technical and economical feasibility of treating produced water with a combination of different separation processes to obtain water of agricultural water quality standards. Experiments were done for the pretreatment of produced water using a new liquid-liquid centrifuge, organoclay and microfiltration and ultrafiltration membranes

  17. Combined effect of ultrasound and essential oils to reduce Listeria monocytogenes on fresh produce.

    Science.gov (United States)

    Özcan, Gülçin; Demirel Zorba, Nükhet Nilüfer

    2016-06-01

    Salads prepared from contaminated fresh produce have a high risk of causing food-borne illnesses. Essential oils obtained from plants have antimicrobial activity and may provide a natural approach to reduce the pathogens on fresh produce. Additionally, ultrasound treatments have been shown to reduce the microbial counts on different foods. The objective of this study was to investigate the antimicrobial activities of cinnamon and lemon essential oils in vitro and in food applications. Mixtures of lettuce, parsley and dill were inoculated with Listeria monocytogenes and then dip-treated for 5 min in one of the following treatments: sterile tap water, chlorinated water, 1% lemon essential oil, 2% cinnamon essential oil or 2% cinnamon essential oil + ultrasound. The samples were stored at 4 ℃ and collected at d 0, 1, 3, 5, 7 and 9 post inoculation. The 1% lemon (4 log) and 2% cinnamon (2 log) essential oil washes provided partial inhibition against L. monocytogenes by d 1. The combined application of 2% cinnamon oil and ultrasound resulted in only 0.85 log inhibition by d 1; however, the number of L. monocytogenes increased during storage and became nearly equal to the control at d 9. Therefore, different combinations of essential oils with other antimicrobials or novel technologies are required. © The Author(s) 2015.

  18. Energy consumption in desalinating produced water from shale oil and gas extraction

    OpenAIRE

    Tow, Emily W.; Chung, Hyung Won; Lienhard, John H.; Thiel, Gregory Parker; Banchik, Leonardo David

    2014-01-01

    On-site treatment and reuse is an increasingly preferred option for produced water management in unconventional oil and gas extraction. This paper analyzes and compares the energetics of several desalination technologies at the high salinities and diverse compositions commonly encountered in produced water from shale formations to guide technology selection and to inform further system development. Produced water properties are modeled using Pitzer's equations, and emphasis is placed on how t...

  19. Oil-producing flowers within the Iridoideae (Iridaceae): evolutionary trends in the flowers of the New World genera.

    Science.gov (United States)

    Chauveau, Olivier; Eggers, Lilian; Souza-Chies, Tatiana T; Nadot, Sophie

    2012-08-01

    Oil-producing flowers related to oil-bee pollination are a major innovation in Neotropical and Mexican Iridaceae. In this study, phylogenetic relationships were investigated among a wide array of New World genera of the tribes Sisyrinchieae, Trimezieae and Tigridieae (Iridaceae: Iridoideae) and the evolution of floral glandular structures, which are predominantly trichomal elaiophores, was examined in relation to the diversification of New World Iridaceae. Phylogenetic analyses based on seven molecular markers obtained from 97 species were conducted to produce the first extensive phylogeny of the New World tribes of subfamily Iridoideae. The resulting phylogenetic hypothesis was used to trace the evolutionary history of glandular structures present in the flowers of numerous species in each tribe. Hypotheses of differential diversification rates among lineages were also investigated using both topological and Binary-State Speciation and Extinction methods. Floral glandular structures and especially trichomal elaiophores evolved multiple times independently in the American tribes of Iridoideae. The distribution pattern of species displaying glandular trichomes across the phylogeny reveals lability in the pollination system and suggests that these structures may have played a significant role in the diversification of the Iridoideae on the American continent.

  20. New technology for producing petrochemical feedstock from heavy oils derived from Alberta oil sands

    International Nuclear Information System (INIS)

    Oballa, M.; Simanzhenkov, V.; Clark, P.; Laureshen, C.; Plessis du, D.

    2006-01-01

    This paper presented the results of a study demonstrating the feasibility of producing petrochemical feedstock or petrochemicals from vacuum gas oils derived from oil sands. A typical bitumen upgrader flow scheme was integrated with several new technologies and coupled with an ethane/propane cracker. Technologies included steam cracking, fluid catalytic cracking (FCC); and the catalytic pyrolysis process (CPP). The scheme was then integrated with the Nova Heavy Oil Cracking (NHC) technology. The NHC process uses a reactor to perform catalytic cracking followed by a main tower that separates gas and liquid products. Aromatic ring cleavage (ARORINCLE) technology was explored as a method of catalytic treatment. Experimental runs were conducted in a laboratory scale fixed bed reactor. A stacked catalyst bed was used, followed by a zeolite-based noble metal catalyst. Examples from process run results were presented. Results indicated that the NHC technology should be used on an FCC unit technology platform. The ARORINCLE technology was considered for use on a hydrotreating unit technology platform. Once the catalysts are fully developed and demonstrated, the economics of the technologies will be enhanced through the construction of world-scale complexes integrating upgrading, refining and petrochemical plants. refs., tabs., figs

  1. Composition of essential oil of costmary [Balsamita major (L.) Desf.] at different growth phases

    NARCIS (Netherlands)

    Bylaite, E.; Venskutonis, R.; Roozen, J.P.; Posthumus, M.A.

    2000-01-01

    The essential oils from leaves and flowers of costmary, Balsamita major (L.) Desf. (syn. Chrysanthemum balsamita L.), were analyzed at various phases of plant growth. The highest contents of oil both in leaves and in flowers were determined before full blooming, 1.15 and 1.34øw/w), respectively.

  2. TECHNOLOGY TRANSFER TO U.S. INDEPENDENT OIL AND NATURAL GAS PRODUCERS

    Energy Technology Data Exchange (ETDEWEB)

    Donald F. Duttlinger; E. Lance Cole

    2003-12-15

    The Petroleum Technology Transfer Council (PTTC) continued pursuing its mission of assisting U.S. independent oil and gas producers to make timely, informed technology decisions. Functioning as a cohesive national organization, PTTC has active grassroots programs through its 10 Regional Lead Organizations (RLOs) and 3 Satellite Offices that encompass all of the oil- and natural gas-producing regions in the U.S. Active volunteer leadership from the Board and regional Producer Advisory Groups keeps activities focused on producer's needs. Technical expertise and personal networks of national and regional staff enable PTTC to deliver focused, technology-related information in a manner that is cost and time effective for independents. The organization effectively combines federal funding through the Department of Energy's (DOE) Office of Fossil Energy with matching state and industry funding, forming a unique partnership. This final report summarizes PTTC's accomplishments. In this final fiscal year of the contract, activities exceeded prior annual activity levels by significant percentages. Strategic planning implemented during the year is focusing PTTC's attention on changes that will bear fruit in the future. Networking and connections are increasing PTTC's sphere of influence with both producers and the service sector. PTTC's reputation for unbiased bottom-line information stimulates cooperative ventures. In FY03 PTTC's regions held 169 workshops, drawing 8,616 attendees. There were nearly 25,000 reported contacts. This represents a 38% increase in attendance and 34% increase in contacts as compared to FY02 activity. Repeat attendance at regional workshops, a measure of customer satisfaction and value received, remained strong at 50%. 39% of participants in regional workshops respond ''Yes'' on feedback forms when asked if they are applying technologies based on knowledge gained through PTTC. This feedback

  3. Combustion of biodiesel fuel produced from hazelnut soapstock/waste sunflower oil mixture in a Diesel engine

    International Nuclear Information System (INIS)

    Usta, N.; Oeztuerk, E.; Can, Oe.; Conkur, E.S.; Nas, S.; Con, A.H.; Can, A.C.; Topcu, M.

    2005-01-01

    Biodiesel is considered as an alternative fuel to Diesel fuel No. 2, which can be generally produced from different kinds of vegetable oils. Since the prices of edible vegetable oils are higher than that of Diesel fuel No. 2, waste vegetable oils and non-edible crude vegetable oils are preferred as potential low priced biodiesel sources. In addition, it is possible to use soapstock, a by-product of edible oil production, for cheap biodiesel production. In this study, a methyl ester biodiesel was produced from a hazelnut soapstock/waste sunflower oil mixture using methanol, sulphuric acid and sodium hydroxide in a two stage process. The effects of the methyl ester addition to Diesel No. 2 on the performance and emissions of a four cycle, four cylinder, turbocharged indirect injection (IDI) Diesel engine were examined at both full and partial loads. Experimental results showed that the hazelnut soapstock/waste sunflower oil methyl ester can be partially substituted for the Diesel fuel at most operating conditions in terms of the performance parameters and emissions without any engine modification and preheating of the blends

  4. Essential-oil composition of Daucus carota ssp. major (Pastinocello Carrot) and nine different commercial varieties of Daucus carota ssp. sativus fruits.

    Science.gov (United States)

    Flamini, Guido; Cosimi, Elena; Cioni, Pier Luigi; Molfetta, Ilaria; Braca, Alessandra

    2014-07-01

    The chemical composition of the essential oils obtained by hydrodistillation from the pastinocello carrot, Daucus carota ssp. major (Vis.) Arcang. (flowers and achenes), and from nine different commercial varieties of D. carota L. ssp. sativus (achenes) was investigated by GC/MS analyses. Selective breeding over centuries of a naturally occurring subspecies of the wild carrot, D. carota L. ssp. sativus, has produced the common garden vegetable with reduced bitterness, increased sweetness, and minimized woody core. On the other hand, the cultivation of the pastinocello carrot has been abandoned, even if, recently, there has been renewed interest in the development of this species, which risks genetic erosion. The cultivated carrot (D. carota ssp. sativus) and the pastinocello carrot (D. carota ssp. major) were classified as different subspecies of the same species. This close relationship between the two subspecies urged us to compare the chemical composition of their essential oils, to evaluate the differences. The main essential-oil constituents isolated from the pastinocello fruits were geranyl acetate (34.2%), α-pinene (12.9%), geraniol (6.9%), myrcene (4.7%), epi-α-bisabolol (4.5%), sabinene (3.3%), and limonene (3.0%). The fruit essential oils of the nine commercial varieties of D. carota ssp. sativus were very different from that of pastinocello, as also confirmed by multivariate statistical analyses. Copyright © 2014 Verlag Helvetica Chimica Acta AG, Zürich.

  5. Radionuclides in produced water from Norwegian oil and gas installations - concentrations and bioavailability

    International Nuclear Information System (INIS)

    Eriksen, D.Oe.; Sidhu, R.; Stralberg, E.; Iden, K.I.; Hylland, K.; Ruus, A.; Roeyset, O.; Berntssen, M.H.G.; Rye, H.

    2006-01-01

    Substantial amounts of produced water, containing elevated levels of radionuclides (mainly 226 Ra and 228 Ra) are discharged to the sea as a result of oil and gas production on the Norwegian Continental Shelf. So far no study has assessed the potential radiological effects on marine biota in connection with radionuclide discharges to the North Sea. The main objective of the project is to establish radiological safe discharge limits for radium, lead and polonium associated with other components in produced water from oil and gas installations on the Norwegian continental shelf. This study reports results indicating that the presence of added chemicals such as scale inhibitors in produced water has a marked influence on the formation of radium and barium sulphates when produced water is mixed with sea water. Thus, the mobility and bioavailability of radium (and barium) will be larger than anticipated. Also, the bioavailability of food-borne radium is shown to increase due to presence of such chemicals. (author)

  6. Financial Times oil and gas international year book 1994

    International Nuclear Information System (INIS)

    Williams, Julian

    1993-01-01

    The greater part of this book aims to provide narrative, production and financial details of major oil and gas companies, both upstream and downstream, across the world. Smaller sections give details on major oil and gas brokers and traders, and on the principal oil and gas associations. These sections are arranged alphabetically by company name. A geographical index towards the end of the book enables the user to identify upstream companies exploring for or producing oil and gas in particular areas. The company index includes every company mentioned in the book and includes all subsidiary and related companies to the major companies. Four introductory tables give data on world petroleum production, oil refining, tanker tonnage and oil consumption. (Author)

  7. Oil and natural gas

    International Nuclear Information System (INIS)

    Hamm, Keith

    1992-01-01

    The two major political events of 1991 produced a much less dramatic reaction in the global oil industry than might have been expected. The economic dislocation in the former USSR caused oil production to fall sharply but this was largely offset by a concurrent fall in demand. Within twelve months of the invasion of Kuwait, crude oil prices had returned to their pre-invasion level; there was no shortage of supply due to the ability of some producers to boost their output rapidly. Details are given of world oil production and developments in oil demand. Demand stagnated in 1991 due to mainly to the economic chaos in the former USSR and a slowdown in sales in the USA; this has produced problems for the future of the refining industry. By contrast, the outlook for the natural gas industry is much more buoyant. Most clean air or carbon emissions legislation is designed to promote the use of gas rather than other hydrocarbons. World gas production rose by 1.5% in 1991; details by production on a country by country basis are given. (UK)

  8. Indonesia palm oil production without deforestation and peat conversion by 2050

    NARCIS (Netherlands)

    Afriyanti, Dian; Kroeze, Carolien; Saad, Asmadi

    2016-01-01

    Palm oil is a promising source of cooking oil and biodiesel. The demand for palm oil has been increasing worldwide. However, concerns exist surrounding the environmental and socio-economic sustainability of palm oil production. Indonesia is a major palm oil producing country. We explored

  9. How equity markets view heavy oil

    International Nuclear Information System (INIS)

    Janisch, M.L.

    2001-01-01

    A review of heavy oil economics was presented in this power point presentation with particular focus on investor motivation, the importance of heavy oil, and an outlook on commodity price for oil and natural gas. Heavy oil from oil sands is playing a major role on the Canadian domestic production front as well as globally. Almost all senior Canadian producers have a major heavy oil project in the works. Oil prices are forecasted to remain strong, but a more bullish outlook is expected for natural gas prices for both the short and long term. Natural gas drilling has increased, but the number of natural gas wells as a percentage of total wells has decreased. Recent Canadian drilling activity has placed more emphasis on crude oil production which has contributed to the lower overall natural gas drilling success rate. It was shown that infrastructure issues regarding tankers, refining capacity (at or near capacity) will be the major factor affecting the availability of crude products to market. It was also shown that heavy oil differentials have increased substantially, which could be a potential issue if oil prices begin to weaken. 1 tab., 12 figs

  10. Cleaning the Produced Water in Offshore Oil Production by Using Plant-wide Optimal Control Strategy

    DEFF Research Database (Denmark)

    Yang, Zhenyu; Pedersen, Simon; Løhndorf, Petar Durdevic

    2014-01-01

    To clean the produced water is always a challenging critical issue in the offshore oil & gas industry. By employing the plant-wide control technology, this paper discussed the opportunity to optimize the most popular hydrocyclone-based Produced Water Treatment (PWT) system. The optimizations of t...... of this research is to promote a technical breakthrough in the PWT control design, which can lead to the best environmental protection in the oil & gas production, without sacrificing the production capability and production costs....

  11. Essential oil of Machilus bombycina King from Northeast India

    NARCIS (Netherlands)

    Choudhury, S.N.; Leclercq, P.A.

    1995-01-01

    The essential oil of Mac hilus bombycina Kingwas produced by hydrodistillation from fresh leaves, collected from Northeast India. The oil was analyzed by GC/MS and 40 components were identified, which constituted 93.7% of the oiL The major components of the oil were decanal (12.5%), ll-dodecenal

  12. Response strategies for oil producers in the face of environmental taxation

    International Nuclear Information System (INIS)

    Walker, I.O.; Brennand, G.J.

    1993-01-01

    The impact of environmental taxes on the oil export revenues of developing countries, particularly OPEC, is considered; the possibility of amelioration through production management is investigated. A model of oil market dynamics is considered and applied to for different tax secenarios. These are a base case scenario where no environmental tax is imposed; an unmanaged market where a $100/t of carbon tax is imposed in all OECD regions and the resulting fall in oil demand is absorbed by OPEC, thereby keeping oil prices at base case levels; a partially managed market where the same tax is imposed, but only OPEC responds by reducing oil production even further to maintain base case revenue; a totally managed market where the same tax is imposed but both OPEC and non-OPEC agree to manage and control the market. The conclusions reached is that as long as OPEC is not able to target a revenue-maximizing path, a totally managed market is likely to prove beneficial to all developing country producers with a much more manageable, higher than base case price in a partially managed market. If, however, OPEC were able to implement a revenue-maximizing course, there would be no need for total management, since non-OPEC revenue would be concomitantly maximized. (2 tables, 4 figures). (UK)

  13. Feasibility and comparative studies of thermochemical liquefaction of Camellia oleifera cake in different supercritical organic solvents for producing bio-oil

    International Nuclear Information System (INIS)

    Chen, Hongmei; Zhai, Yunbo; Xu, Bibo; Xiang, Bobin; Zhu, Lu; Li, Ping; Liu, Xiaoting; Li, Caiting; Zeng, Guangming

    2015-01-01

    Highlights: • Thermochemical liquefaction of COC was a prominent process for producing bio-oil. • Type of solvent affected the yield and composition of bio-oil considerably. • Liquefaction of COC in SCEL at 300 °C was preferred for producing bio-oil. - Abstract: Thermochemical liquefaction of Camellia oleifera cake (COC) for producing bio-oil was conducted in supercritical methanol (SCML), ethanol (SCEL) and acetone (SCAL), respectively. GC–MS, elemental analysis and ICP-OES were used to characterize properties of bio-oil. Results showed that thermochemical liquefaction of COC was a prominent process for generating bio-oil. Increase of temperature was beneficial to the increase of bio-oil yield, and yield of bio-oil followed the sequence of SCAL > SCEL > SCML. In spite of the highest bio-oil yield, the lowest calorific value and highest contents of Zn, Pb, Cd, Ni, Fe, Mn, and Cr were found in bio-oil from SCAL. Though SCML has very similar bio-oil composition and calorific value with SCEL, higher bio-oil yield and lower contents of heavy metals could be obtained with SCEL, especially in bio-oil from SCEL at 300 °C. Moreover, the origin of ethanol could make the bio-oil product totally renewable. Therefore, liquefaction of COC in SCEL at 300 °C could have great potential in generating bio-oil

  14. A comparison of cold flow properties of biodiesel produced from virgin and used frying oil

    Energy Technology Data Exchange (ETDEWEB)

    Al-Shanableh, Filiz [Food Engineering Department, Near East University (Cyprus); Evcil, Ali; Govsa, Cemal [Mechanical Engineering Department, Near East University (Cyprus); Savasdylmac, Mahmut A. [Mechanical Engineering Department, Booazici University (Turkey)

    2011-07-01

    Bio-diesel can be produced from different kinds of feedstock. The purpose of this paper is to research and make the comparison of the cold flow properties of bio-diesel produced from refined-virgin frying vegetable oil (RVFVO) and waste frying vegetable oil (WFVO). As is known, bio-diesel fuel will have higher cloud points (CP), cold filter plugging points (CFPP) and pour points (PP) if it is derived from fat or oil which consists of significant amounts of saturated fatty compounds. Both RVFVO and WFVO were derived from the same cafeteria on a Near East University campus and converted to biodiesel fuel through base catalyzed transesterification reaction. As the current results show, there is no considerable difference in cold flow properties of the bio-diesel produced from RVFVO and WFVO. So WFVO seems be better positioned to serve as raw material in biodiesel production because of its lower cost and its environmental benefits.

  15. Analyzing and forecasting volatility spillovers, asymmetries and hedging in major oil markets

    International Nuclear Information System (INIS)

    Chang, Chia-Lin; McAleer, Michael; Tansuchat, Roengchai

    2010-01-01

    Crude oil price volatility has been analyzed extensively for organized spot, forward and futures markets for well over a decade, and is crucial for forecasting volatility and Value-at-Risk (VaR). There are four major benchmarks in the international oil market, namely West Texas Intermediate (USA), Brent (North Sea), Dubai/Oman (Middle East), and Tapis (Asia-Pacific), which are likely to be highly correlated. This paper analyses the volatility spillover and asymmetric effects across and within the four markets, using three multivariate GARCH models, namely the constant conditional correlation (CCC), vector ARMA-GARCH (VARMA-GARCH) and vector ARMA-asymmetric GARCH (VARMA-AGARCH) models. A rolling window approach is used to forecast the 1-day ahead conditional correlations. The paper presents evidence of volatility spillovers and asymmetric effects on the conditional variances for most pairs of series. In addition, the forecast conditional correlations between pairs of crude oil returns have both positive and negative trends. Moreover, the optimal hedge ratios and optimal portfolio weights of crude oil across different assets and market portfolios are evaluated in order to provide important policy implications for risk management in crude oil markets. (author)

  16. Analyzing and forecasting volatility spillovers, asymmetries and hedging in major oil markets

    Energy Technology Data Exchange (ETDEWEB)

    Chang, Chia-Lin [Department of Applied Economics National Chung Hsing University Taichung, 250 Kuo Kuang Road, National Chung Hsing University Taichung 402 (China); McAleer, Michael [Econometric Institute, Erasmus School of Economics, Erasmus University Rotterdam (Netherlands); Tinbergen Institute (Netherlands); Tansuchat, Roengchai [Faculty of Economics, Maejo University (Thailand)

    2010-11-15

    Crude oil price volatility has been analyzed extensively for organized spot, forward and futures markets for well over a decade, and is crucial for forecasting volatility and Value-at-Risk (VaR). There are four major benchmarks in the international oil market, namely West Texas Intermediate (USA), Brent (North Sea), Dubai/Oman (Middle East), and Tapis (Asia-Pacific), which are likely to be highly correlated. This paper analyses the volatility spillover and asymmetric effects across and within the four markets, using three multivariate GARCH models, namely the constant conditional correlation (CCC), vector ARMA-GARCH (VARMA-GARCH) and vector ARMA-asymmetric GARCH (VARMA-AGARCH) models. A rolling window approach is used to forecast the 1-day ahead conditional correlations. The paper presents evidence of volatility spillovers and asymmetric effects on the conditional variances for most pairs of series. In addition, the forecast conditional correlations between pairs of crude oil returns have both positive and negative trends. Moreover, the optimal hedge ratios and optimal portfolio weights of crude oil across different assets and market portfolios are evaluated in order to provide important policy implications for risk management in crude oil markets. (author)

  17. A novel method of producing a microcrystalline beta-sitosterol suspension in oil

    DEFF Research Database (Denmark)

    Christiansen, Leena I; Rantanen, Jukka T; von Bonsdorff, Anna K

    2002-01-01

    This paper describes a novel method of producing a microcrystalline oral suspension containing beta-sitosterol in oil for the treatment of hypercholesterolaemia. beta-Sitosterol pseudopolymorphs with different water contents were crystallized from acetone and acetone-water solutions. Structural...

  18. Oil markets to 2010: the impact of non-Opec oil

    International Nuclear Information System (INIS)

    Enav, Peter

    1998-09-01

    This report provides an in-depth assessment of oil development scenarios in every non-Opec oil producing country from 1998 to 2010, in addition to evaluating the extent and direction of future oil trade for Opec and non-Opec countries alike. It re-assesses world oil consumption patterns in light of the Asian financial crisis, providing a concise yet comprehensive coverage of an often-neglected oil production group. The oil market development scenario is analysed in each country, with detailed consideration of the major players providing historical production, consumption, import and export data; current oil balance - production, imports and exports; an assessment of oil development policy; analysis of potential development obstacles considering regulatory, financial, political and environmental issues; oil production and consumption projections to 2010, by type; and import and export projections to 2010, by destination and source. More than 80 tables supplying essential statistics on the world's non-Opec markets accompany the report, with maps and schematic diagrams showing existing and potential infrastructure and fields. (Author)

  19. Oxidative stability of mayonnaise containing structured lipids produced from sunflower oil and caprylic acid

    DEFF Research Database (Denmark)

    Jacobsen, Charlotte; Xu, Xuebing; Nielsen, Nina Skall

    2003-01-01

    Mayonnaise based on enzymatically produced specific structured lipid (SL) from sunflower oil and caprylic acid was compared with mayonnaise based on traditional sunflower oil (SO) or chemically randomized lipid (RL) with respect to their oxidative stability, sensory and rheological properties......, but was most likely influenced by the structure of the lipid, the lower tocopherol content and the higher initial levels of lipid hydroperoxides and secondary volatile oxidation compounds in the SL itself compared with the RL and traditional sunflower oil employed. EDTA was a strong antioxidant, while propyl...

  20. Physical and chemical properties of olive oil extracted from olive cultivars grown in Shiraz and Kazeroon

    DEFF Research Database (Denmark)

    Homapour, M.; Hamedi, M.; Moslehishad, M.

    2014-01-01

    Background and objective: The composition of olive oil is significantly affected by the cultivar and climatic conditions. The present study determined the chemical characteristics of olive oil extracted from two major Iranian varieties of olive (yellow and local oil-grade) in Shiraz and Kazeroon......, two major olive-producing areas in Fars province. Materials and methods: The composition of olive oil is significantly affected by the cultivar and climatic conditions. The present study determined the chemical characteristics of olive oil extracted from two major Iranian varieties of olive (yellow...... and local oil-grade) in Shiraz and Kazeroon, two major olive-producing areas in Fars province. Results: The results showed that the physical and chemical properties of both cultivars are in accordance with national and international standards. There was a significant difference in acidity, iodine content...

  1. 76 FR 61933 - Marketing Order Regulating the Handling of Spearmint Oil Produced in the Far West; Revision of...

    Science.gov (United States)

    2011-10-06

    ..., 733,877 pounds of Scotch spearmint oil have already been sold or committed, which leaves just 186,505... of essential oils and the products of essential oils. In addition, the Committee estimates that 8 of...-1A IR] Marketing Order Regulating the Handling of Spearmint Oil Produced in the Far West; Revision of...

  2. Novel Downhole Electromagnetic Flowmeter for Oil-Water Two-Phase Flow in High-Water-Cut Oil-Producing Wells.

    Science.gov (United States)

    Wang, Yanjun; Li, Haoyu; Liu, Xingbin; Zhang, Yuhui; Xie, Ronghua; Huang, Chunhui; Hu, Jinhai; Deng, Gang

    2016-10-14

    First, the measuring principle, the weight function, and the magnetic field of the novel downhole inserted electromagnetic flowmeter (EMF) are described. Second, the basic design of the EMF is described. Third, the dynamic experiments of two EMFs in oil-water two-phase flow are carried out. The experimental errors are analyzed in detail. The experimental results show that the maximum absolute value of the full-scale errors is better than 5%, the total flowrate is 5-60 m³/d, and the water-cut is higher than 60%. The maximum absolute value of the full-scale errors is better than 7%, the total flowrate is 2-60 m³/d, and the water-cut is higher than 70%. Finally, onsite experiments in high-water-cut oil-producing wells are conducted, and the possible reasons for the errors in the onsite experiments are analyzed. It is found that the EMF can provide an effective technology for measuring downhole oil-water two-phase flow.

  3. Novel Downhole Electromagnetic Flowmeter for Oil-Water Two-Phase Flow in High-Water-Cut Oil-Producing Wells

    Directory of Open Access Journals (Sweden)

    Yanjun Wang

    2016-10-01

    Full Text Available First, the measuring principle, the weight function, and the magnetic field of the novel downhole inserted electromagnetic flowmeter (EMF are described. Second, the basic design of the EMF is described. Third, the dynamic experiments of two EMFs in oil-water two-phase flow are carried out. The experimental errors are analyzed in detail. The experimental results show that the maximum absolute value of the full-scale errors is better than 5%, the total flowrate is 5–60 m3/d, and the water-cut is higher than 60%. The maximum absolute value of the full-scale errors is better than 7%, the total flowrate is 2–60 m3/d, and the water-cut is higher than 70%. Finally, onsite experiments in high-water-cut oil-producing wells are conducted, and the possible reasons for the errors in the onsite experiments are analyzed. It is found that the EMF can provide an effective technology for measuring downhole oil-water two-phase flow.

  4. Identification of Major Quantitative Trait Loci for Seed Oil Content in Soybeans by Combining Linkage and Genome-Wide Association Mapping.

    Science.gov (United States)

    Cao, Yongce; Li, Shuguang; Wang, Zili; Chang, Fangguo; Kong, Jiejie; Gai, Junyi; Zhao, Tuanjie

    2017-01-01

    Soybean oil is the most widely produced vegetable oil in the world and its content in soybean seed is an important quality trait in breeding programs. More than 100 quantitative trait loci (QTLs) for soybean oil content have been identified. However, most of them are genotype specific and/or environment sensitive. Here, we used both a linkage and association mapping methodology to dissect the genetic basis of seed oil content of Chinese soybean cultivars in various environments in the Jiang-Huai River Valley. One recombinant inbred line (RIL) population (NJMN-RIL), with 104 lines developed from a cross between M8108 and NN1138-2 , was planted in five environments to investigate phenotypic data, and a new genetic map with 2,062 specific-locus amplified fragment markers was constructed to map oil content QTLs. A derived F 2 population between MN-5 (a line of NJMN-RIL) and NN1138-2 was also developed to confirm one major QTL. A soybean breeding germplasm population (279 lines) was established to perform a genome-wide association study (GWAS) using 59,845 high-quality single nucleotide polymorphism markers. In the NJMN-RIL population, 8 QTLs were found that explained a range of phenotypic variance from 6.3 to 26.3% in certain planting environments. Among them, qOil-5-1, qOil-10-1 , and qOil-14-1 were detected in different environments, and qOil-5-1 was further confirmed using the secondary F 2 population. Three loci located on chromosomes 5 and 20 were detected in a 2-year long GWAS, and one locus that overlapped with qOil-5-1 was found repeatedly and treated as the same locus. qOil-5-1 was further localized to a linkage disequilibrium block region of approximately 440 kb. These results will not only increase our understanding of the genetic control of seed oil content in soybean, but will also be helpful in marker-assisted selection for breeding high seed oil content soybean and gene cloning to elucidate the mechanisms of seed oil content.

  5. Oil and gas: year full of major events and dramatic changes

    International Nuclear Information System (INIS)

    Hirman, K.

    2004-01-01

    European gas industry encountered a historical precedent this February. Russian gas concern Gazprom has for the first time in its over thirty-year history of gas delivery from Siberia to Europe deliberately stopped the export. Even though this did not last for more then one day, customers in Latvia immediately noticed problems and also Polish customers mentioned some losses. Slovakia, still fully dependent on Russian gas supplies and at the same time major transported of Russian gas to European, was not touched by this situation as the deliveries were stopped on gas pipeline Jamal-Europe delivering gas to Germany through Belarus and Poland. But this affair can become a major issue in gas and political relations between Russia, Belarus and Ukraine and can also have a long-term impact on a dialog between Europe and Russia and consequently on building of new gas pipelines. And that could have a major impact on Slovakia's position as a transit country. Important for Slovakia is also the ongoing discussion about Ukrainian pipeline Odessa-Brody. A political decision made by Ukrainian cabinet that this pipeline should only be used to transport oil from Caspian Sea can give Slovakia the opportunity to diversify its oil import and at the same time increase the transit volumes should German refineries show interest in this transit route. On the other hand ratification of an intergovernmental agreement on integration of pipelines Druzba and Adria by Ukrainian Parliaments is also good news for Bratislava. This step politically opened the possibility to deliver Russian oil through Slovakia to Croatian Omisajl and from there with tankers to Europe and Northern America. The capacity of pipeline Druzba in Ukraine and Slovakia is not sufficient to take both the increased volumes of Russian and Caspian oil these two projects are competing for the free capacity. And the process and outcome of this competition may be of direct influence on Slovak interests. At the moment there are

  6. Radionuclides in produced water from Norwegian oil and gas installations — Concentrations and bioavailability

    Science.gov (United States)

    Eriksen, D. Ø.; Sidhu, R.; Strålberg, E.; Iden, K. I.; Hylland, K.; Ruus, A.; Røyset, O.; Berntssen, M. H. G.; Rye, H.

    2006-01-01

    Substantial amounts of produced water, containing elevated levels of radionuclides (mainly 226Ra and 228Ra) are discharged to the sea as a result of oil and gas production on the Norwegian Continental Shelf. So far no study has assessed the potential radiological effects on marine biota in connection with radionuclide discharges to the North Sea. The main objective of the project is to establish radiological safe discharge limits for radium, lead and polonium associated with other components in produced water from oil and gas installations on the Norwegian continental shelf. This study reports results indicating that the presence of added chemicals such as scale inhibitors in produced water has a marked influence on the formation of radium and barium sulphates when produced water is mixed with sea water. Thus, the mobility and bioavailability of radium (and barium) will be larger than anticipated. Also, the bioavailability of food-borne radium is shown to increase due to presence of such chemicals.

  7. Composition of Asarum heterotropoides var. mandshuricum radix oil from different extraction methods and activities against human body odor-producing bacteria.

    Science.gov (United States)

    Haque, A S M Tanbirul; Moon, Jin Nam; Saravana, P S; Tilahun, Adane; Chun, Byung-Soo

    2016-10-01

    In this study, oils from Asarum heterotropoides were extracted by traditional solvent extraction and supercritical CO 2 (SC-CO 2 ) extraction methods and their antioxidant activities along with antimicrobial and inhibitory activities against five human body odor-producing bacteria (Staphylococcus epidermidis, Propionibacterium freudenreichii, Micrococcus luteus, Corynebacterium jeikeium, and Corynebacterium xerosis) were evaluated. The oil was found to contain 15 components, among which the most abundant component was methyl eugenol (37.6%), which was identified at every condition studied in different extraction methods. The oil extracted with n-hexane and ethanol mixture exhibited a strong antioxidant activity (92% ± 2%) and the highest ABTS and 2,2-diphenyl-1-picrylhydrazyl scavenging activities (89% ± 0.2%). The highest amounts of total phenolic content and total flavonoid content were 23.1±0.4 mg/g and 4.9±0.1 mg/g, respectively, in the traditional method. In the SC-CO 2 method performed at 200 bar/50°C using ethanol as an entrainer, the highest inhibition zone was recorded against all the aforementioned bacteria. In particular, strong antibacterial activity (38±2 mm) was found against M. luteus. The minimum inhibitory concentration (MIC) for the oil against bacteria ranged from 10.1±0.1 μg/mL to 46±2 μg/mL. The lowest MIC was found against M. luteus. Methyl eugenol was found to be one of the major compounds working against human body odor-producing bacteria. Copyright © 2016. Published by Elsevier B.V.

  8. Composition of Asarum heterotropoides var. mandshuricum radix oil from different extraction methods and activities against human body odor-producing bacteria

    Directory of Open Access Journals (Sweden)

    A.S.M. Tanbirul Haque

    2016-10-01

    Full Text Available In this study, oils from Asarum heterotropoides were extracted by traditional solvent extraction and supercritical CO2 (SC-CO2 extraction methods and their antioxidant activities along with antimicrobial and inhibitory activities against five human body odor-producing bacteria (Staphylococcus epidermidis, Propionibacterium freudenreichii, Micrococcus luteus, Corynebacterium jeikeium, and Corynebacterium xerosis were evaluated. The oil was found to contain 15 components, among which the most abundant component was methyl eugenol (37.6%, which was identified at every condition studied in different extraction methods. The oil extracted with n-hexane and ethanol mixture exhibited a strong antioxidant activity (92% ± 2% and the highest ABTS and 2,2-diphenyl-1-picrylhydrazyl scavenging activities (89% ± 0.2%. The highest amounts of total phenolic content and total flavonoid content were 23.1±0.4 mg/g and 4.9±0.1 mg/g, respectively, in the traditional method. In the SC-CO2 method performed at 200 bar/50°C using ethanol as an entrainer, the highest inhibition zone was recorded against all the aforementioned bacteria. In particular, strong antibacterial activity (38±2 mm was found against M. luteus. The minimum inhibitory concentration (MIC for the oil against bacteria ranged from 10.1±0.1 μg/mL to 46±2 μg/mL. The lowest MIC was found against M. luteus. Methyl eugenol was found to be one of the major compounds working against human body odor-producing bacteria.

  9. Achieving a Carbon Neutral Society without Industry Contraction in the Five Major Steel Producing Countries

    Directory of Open Access Journals (Sweden)

    Kyunsuk Choi

    2016-05-01

    Full Text Available This study analyzed the direct and indirect CO2 emissions of the energy-intensive basic metals industry, in particular steels, using the distributions of various energy sources, including coal/peat, oil, and electricity, from an input–output table. An analysis of five major steel producing countries indicated that direct CO2 emissions increased 1.4-fold and that indirect CO2 emissions increased by more than two-fold between 1995 and 2010. The elasticity of the CO2 emissions and the total energy costs indicated that Korea, Japan, and Germany are sensitive to energy sources from the electric power industry, whereas China and the US are more sensitive to energy sources pertaining to the coal and oil industry. Using the available forest area and photosynthesis, the potential neutralization ability of CO2 was estimated using the eco-CO2 index. The US yielded the highest CO2 neutralization ability of 66.1%, whereas Korea yielded a CO2 neutralization ability of 15%. Future trends of the 2030 eco-CO2 index revealed China and Korea will rapidly lose their neutralization ability resulting in a net negative neutralization ability if left unabated. The significant decline in the eco-CO2 index for the basic metals industry may be inhibited by utilizing bamboo wood charcoal for pulverized coal injection (PCI in the steelmaking process.

  10. Analyzing and Forecasting Volatility Spillovers and Asymmetries in Major Crude Oil Spot, Forward and Futures Markets

    NARCIS (Netherlands)

    C-L. Chang (Chia-Lin); M.J. McAleer (Michael); R. Tansuchat (Roengchai)

    2010-01-01

    textabstractCrude oil price volatility has been analyzed extensively for organized spot, forward and futures markets for well over a decade, and is crucial for forecasting volatility and Value-at-Risk (VaR). There are four major benchmarks in the international oil market, namely West Texas

  11. Characterization of water-in-oil emulsions produced with microporous hollow polypropylene fibers

    Directory of Open Access Journals (Sweden)

    HELMAR SCHUBERT

    2000-11-01

    Full Text Available The preparation of fine and monodispersed water-in-oil (W/O emulsions by utilizing hydrophobic hollow polypropylene fibers with 0.4 mm pores was investigated in this work. The experiments were carried out using demineralized water as the disperse phase, mineral oil Velocite No. 3 as the continuous phase, and polyglycerol polyricinoleate (PGPR 90 in the concentration range of 2.5 – 10 wt % as the oil-soluble emulsifier. The size of the water droplets in the prepared emulsions and the droplet size distribution strongly depend on the content of the disperse phase, the transmembrane pressure difference, and the emulsifier concentration. Stable emulsions with a very narrow droplet size distribution and a mean droplet diameter lower than 0.27 µm were produced using 10 wt % PGPR 90 at a pressure difference below 30 kPa.

  12. Research needs to maximize economic producibility of the domestic oil resource

    International Nuclear Information System (INIS)

    Tham, M.K.; Burchfield, T.; Chung, Ting-Horng; Lorenz, P.; Bryant, R.; Sarathi, P.; Chang, Ming Ming; Jackson, S.; Tomutsa, L.; Dauben, D.L.

    1991-10-01

    NIPER was contracted by the US Department of Energy Bartlesville (Okla.) Project Office (DOE/BPO) to identify research needs to increase production of the domestic oil resource, and K ampersand A Energy Consultants, Inc. was subcontracted to review EOR field projects. This report summarizes the findings of that investigation. Professional society and trade journals, DOE reports, dissertations, and patent literature were reviewed to determine the state-of-the-art of enhanced oil recovery (EOR) and drilling technologies and the constraints to wider application of these technologies. The impacts of EOR on the environment and the constraints to the application of EOR due to environmental regulations were also reviewed. A review of well documented EOR field projects showed that in addition to the technical constraints, management factors also contributed to the lower-than-predicted oil recovery in some of the projects reviewed. DOE-sponsored projects were reviewed, and the achievements by these projects and the constraints which these projects were designed to overcome were also identified. Methods of technology transfer utilized by the DOE were reviewed, and several recommendations for future technology transfer were made. Finally, several research areas were identified and recommended to maximize economic producibility of the domestic oil resource. 14 figs., 41 tabs

  13. Research needs to maximize economic producibility of the domestic oil resource

    Energy Technology Data Exchange (ETDEWEB)

    Tham, M.K.; Burchfield, T.; Chung, Ting-Horng; Lorenz, P.; Bryant, R.; Sarathi, P.; Chang, Ming Ming; Jackson, S.; Tomutsa, L. (National Inst. for Petroleum and Energy Research, Bartlesville, OK (United States)); Dauben, D.L. (K and A Energy Consultants, Inc., Tulsa, OK (United States))

    1991-10-01

    NIPER was contracted by the US Department of Energy Bartlesville (Okla.) Project Office (DOE/BPO) to identify research needs to increase production of the domestic oil resource, and K A Energy Consultants, Inc. was subcontracted to review EOR field projects. This report summarizes the findings of that investigation. Professional society and trade journals, DOE reports, dissertations, and patent literature were reviewed to determine the state-of-the-art of enhanced oil recovery (EOR) and drilling technologies and the constraints to wider application of these technologies. The impacts of EOR on the environment and the constraints to the application of EOR due to environmental regulations were also reviewed. A review of well documented EOR field projects showed that in addition to the technical constraints, management factors also contributed to the lower-than-predicted oil recovery in some of the projects reviewed. DOE-sponsored projects were reviewed, and the achievements by these projects and the constraints which these projects were designed to overcome were also identified. Methods of technology transfer utilized by the DOE were reviewed, and several recommendations for future technology transfer were made. Finally, several research areas were identified and recommended to maximize economic producibility of the domestic oil resource. 14 figs., 41 tabs.

  14. 78 FR 9575 - Marketing Order Regulating the Handling of Spearmint Oil Produced in the Far West; Change to...

    Science.gov (United States)

    2013-02-11

    ... reserve oil in such manner as to accurately account for its receipt, storage, and disposition. In a rule... FR] Marketing Order Regulating the Handling of Spearmint Oil Produced in the Far West; Change to Administrative Rules Regarding the Transfer and Storage of Excess Spearmint Oil AGENCY: Agricultural Marketing...

  15. COMPETITIVE POSITION OF THE MAIN PRODUCERS AND EXPORTERS OF OILSEEDS AND VEGETABLE OILS IN THE INTRA-EU TRADE

    Directory of Open Access Journals (Sweden)

    Karolina Pawlak

    2014-09-01

    Full Text Available The aim of the paper was to assess the competitive position of the main producers and exporters of oilseeds and vegetable oils in the intra-EU trade in 2004 and 2012. The competitiveness was assessed with the use of a selected set of quantitative measures of international competitive position. Moreover, some shares of the analysed countries in the intra-EU trade, as well as relative export intensity of oilseeds and vegetable oils in these countries were estimated. On the basis of the conducted analyses it is possible to conclude that apart from Germany in trade in rapeseed and soya beans, as well as the Netherlands in trade in rapeseed and sunflower-seed, the main producers and exporters of oilseeds were competitive on the Single European Market. Excluding soya-bean oil produced in the EU mainly from imported raw material, competitive advantage of most of the countries decreased together with the level of processing and was lower in trade in vegetable oils.

  16. Canada's crude oil resources : crude oil in our daily lives

    International Nuclear Information System (INIS)

    Bott, R.

    2001-10-01

    Created in 1975, the Petroleum Communication Foundation is a not-for-profit organization. The objective of the Foundation is to inform Canadians about the petroleum industry in Canada. It produces educational, fact-based publications and programs, employing a multi-stakeholder review process. The first section of this publication is devoted to crude oil and the benefits that are derived from it. It begins by providing a brief definition of crude oil, then moves to the many uses in our daily lives and the environmental impacts like air pollution, spills, and footprint on the land from exploration and production activities. Section 2 details the many uses of crude oil and identifies the major oil producing regions of Canada. A quick mention is made of non-conventional sources of crude oil. The search for crude oil is the topic of section 3 of the document, providing an overview of the exploration activities, the access rights that must be obtained before gaining access to the resource. The drilling of oil is discussed in section 4. Section 5 deals with issues pertaining to reservoirs within rocks, while section 6 covers the feeding of the refineries, discussing topics from the movement of oil to market to the refining of the crude oil, and the pricing issues. In section 7, the uncertain future is examined with a view of balancing the supply and demand, as crude oil is a non-renewable resource. Supplementary information is provided concerning additional publications published by various organizations and agencies. figs

  17. Is it better to import palm oil from Thailand to produce biodiesel in Ireland than to produce biodiesel from indigenous Irish rape seed?

    International Nuclear Information System (INIS)

    Thamsiriroj, T.; Murphy, J.D.

    2009-01-01

    The proposed EU Directive on the promotion of Renewable Energy stipulates that only biofuels that achieve greenhouse emissions savings of 35% will be eligible for inclusion with respect to meeting the 2020 target of 10% for the share of biofuels. This paper examines biodiesel for use in Ireland, produced from two different sources: indigenous rape seed and palm oil imported from Thailand. The palm oil system generates more biodiesel per hectare than the rape seed system, and has less parasitic demand. Greenhouse-gas reductions of 29% and 55%, respectively were calculated for the rape seed and palm oil systems. (author)

  18. Simulating surface oil transport during the Deepwater Horizon oil spill: Experiments with the BioCast system

    Science.gov (United States)

    Jolliff, Jason Keith; Smith, Travis A.; Ladner, Sherwin; Arnone, Robert A.

    2014-03-01

    The U.S. Naval Research Laboratory (NRL) is developing nowcast/forecast software systems designed to combine satellite ocean color data streams with physical circulation models in order to produce prognostic fields of ocean surface materials. The Deepwater Horizon oil spill in the Gulf of Mexico provided a test case for the Bio-Optical Forecasting (BioCast) system to rapidly combine the latest satellite imagery of the oil slick distribution with surface circulation fields in order to produce oil slick transport scenarios and forecasts. In one such sequence of experiments, MODIS satellite true color images were combined with high-resolution ocean circulation forecasts from the Coupled Ocean-Atmosphere Mesoscale Prediction System (COAMPS®) to produce 96-h oil transport simulations. These oil forecasts predicted a major oil slick landfall at Grand Isle, Louisiana, USA that was subsequently observed. A key driver of the landfall scenario was the development of a coastal buoyancy current associated with Mississippi River Delta freshwater outflow. In another series of experiments, longer-term regional circulation model results were combined with oil slick source/sink scenarios to simulate the observed containment of surface oil within the Gulf of Mexico. Both sets of experiments underscore the importance of identifying and simulating potential hydrodynamic conduits of surface oil transport. The addition of explicit sources and sinks of surface oil concentrations provides a framework for increasingly complex oil spill modeling efforts that extend beyond horizontal trajectory analysis.

  19. TECHNOLOGY TRANSFER TO U.S. INDEPENDENT OIL AND NATURAL GAS PRODUCERS

    Energy Technology Data Exchange (ETDEWEB)

    Unknown

    2002-11-01

    The Petroleum Technology Transfer Council (PTTC) continued pursuing its mission of assisting U.S. independent oil and gas producers make timely, informed technology decisions by providing access to information during Fiscal Year 2002 (FY02). Functioning as a cohesive national organization, PTTC has active grassroots programs through its ten Regional Lead Organizations (RLOs) and three satellite offices that efficiently extend the program reach. They bring research and academia to the table via their association with geological surveys and engineering departments. The regional directors interact with independent oil and gas producers through technology workshops, resource centers, websites, newsletters, various technical publications and other outreach efforts. These are guided by regional Producer Advisory Groups (PAGs), who are area operators and service companies working with the regional networks. The role of the national Headquarters (HQ) staff includes planning and managing the PTTC program, conducting nation wide technology transfer activities, and implementing a comprehensive communications effort. The organization effectively combines federal funding through the Department of Energy's (DOE) Office of Fossil Energy with state and industry funding to achieve important goals for all of these sectors. This integrated funding base is combined with industry volunteers guiding PTTC's activities and the dedication of national and regional staff to achieve notable results. PTTC is increasingly recognized as a critical resource for information and access to technologies, especially for smaller companies without direct contact with R&D efforts. The DOE participation is managed through the National Energy Technology Laboratory (NETL), which deploys a national natural gas program via the Strategic Center for Natural Gas (SCNG) and a national oil program through the National Petroleum Technology Office (NTPO). This technical progress report summarizes PTTC

  20. Non-Invasive Rapid Harvest Time Determination of Oil-Producing Microalgae Cultivations for Biodiesel Production by Using Chlorophyll Fluorescence

    Energy Technology Data Exchange (ETDEWEB)

    Qiao, Yaqin [Key Laboratory of Algal Biology, Institute of Hydrobiology, Chinese Academy of Sciences, Wuhan (China); University of Chinese Academy of Sciences, Beijing (China); Rong, Junfeng [SINOPEC Research Institute of Petroleum Processing, Beijing (China); Chen, Hui; He, Chenliu; Wang, Qiang, E-mail: wangqiang@ihb.ac.cn [Key Laboratory of Algal Biology, Institute of Hydrobiology, Chinese Academy of Sciences, Wuhan (China)

    2015-10-05

    For the large-scale cultivation of microalgae for biodiesel production, one of the key problems is the determination of the optimum time for algal harvest when algae cells are saturated with neutral lipids. In this study, a method to determine the optimum harvest time in oil-producing microalgal cultivations by measuring the maximum photochemical efficiency of photosystem II, also called Fv/Fm, was established. When oil-producing Chlorella strains were cultivated and then treated with nitrogen starvation, it not only stimulated neutral lipid accumulation, but also affected the photosynthesis system, with the neutral lipid contents in all four algae strains – Chlorella sorokiniana C1, Chlorella sp. C2, C. sorokiniana C3, and C. sorokiniana C7 – correlating negatively with the Fv/Fm values. Thus, for the given oil-producing algae, in which a significant relationship between the neutral lipid content and Fv/Fm value under nutrient stress can be established, the optimum harvest time can be determined by measuring the value of Fv/Fm. It is hoped that this method can provide an efficient way to determine the harvest time rapidly and expediently in large-scale oil-producing microalgae cultivations for biodiesel production.

  1. Amine functionalized magnetic nanoparticles for removal of oil droplets from produced water and accelerated magnetic separation

    Energy Technology Data Exchange (ETDEWEB)

    Ko, Saebom, E-mail: saebomko@austin.utexas.edu [University of Texas, Department of Petroleum and Geosystems Engineering (United States); Kim, Eun Song [University of Texas, Department of Biomedical Engineering (United States); Park, Siman [University of Texas, Department of Civil, Architectural and Environmental Engineering (United States); Daigle, Hugh [University of Texas, Department of Petroleum and Geosystems Engineering (United States); Milner, Thomas E. [University of Texas, Department of Biomedical Engineering (United States); Huh, Chun [University of Texas, Department of Petroleum and Geosystems Engineering (United States); Bennetzen, Martin V. [Maersk Oil Corporate (Denmark); Geremia, Giuliano A. [Maersk Oil Research and Technology Centre (Qatar)

    2017-04-15

    Magnetic nanoparticles (MNPs) with surface coatings designed for water treatment, in particular for targeted removal of contaminants from produced water in oil fields, have drawn considerable attention due to their environmental merit. The goal of this study was to develop an efficient method of removing very stable, micron-scale oil droplets dispersed in oilfield produced water. We synthesized MNPs in the laboratory with a prescribed surface coating. The MNPs were superparamagnetic magnetite, and the hydrodynamic size of amine functionalized MNPs ranges from 21 to 255 nm with an average size of 66 nm. The initial oil content of 0.25 wt.% was reduced by as much as 99.9% in separated water. The electrostatic attraction between negatively charged oil-in-water emulsions and positively charged MNPs controls, the attachment of MNPs to the droplet surface, and the subsequent aggregation of the electrically neutral oil droplets with attached MNPs (MNPs-oils) play a critical role in accelerated and efficient magnetic separation. The total magnetic separation time was dramatically reduced to as short as 1 s after MNPs, and oil droplets were mixed, in contrast with the case of free, individual MNPs with which separation took about 36∼72 h, depending on the MNP concentrations. Model calculations of magnetic separation velocity, accounting for the MNP magnetization and viscous drag, show that the total magnetic separation time will be approximately 5 min or less, when the size of the MNPs-oils is greater than 360 nm, which can be used as an optimum operating condition.

  2. Development of More Effective Biosurfactants for Enhanced Oil Recovery

    Energy Technology Data Exchange (ETDEWEB)

    McInerney, J.J.; Han, S.O.; Maudgalya, S.; Mouttaki, H.; Folmsbee, M.; Knapp, R.; Nagle, D.; Jackson, B.E.; Stuadt, M.; Frey, W.

    2003-01-16

    The objectives of this were two fold. First, core displacement studies were done to determine whether microbial processes could recover residual oil at elevated pressures. Second, the importance of biosurfactant production for the recovery of residual oil was studies. In these studies, a biosurfactant-producing, microorganisms called Bacillus licheniformis strain JF-2 was used. This bacterium produces a cyclic peptide biosurfactant that significantly reduces the interfacial tension between oil and brine (7). The use of a mutant deficient in surfactant production and a mathematical MEOR simulator were used to determine the major mechanisms of oil recovery by these two strains.

  3. The oil barrel price

    International Nuclear Information System (INIS)

    Blondy, J.; Papon, P.

    2009-01-01

    This paper proposes an overview and a prospective glance on the oil barrel price. It indicates the relevant indicators: Brent quotation, euro/dollar parity, economic activity indicators, world oil consumption distribution, crude oil production, refining capacity. It briefly presents the involved stake holders: crude oil producers, oil refiners, refined product dealers, and the OPEC. It discusses the major retrospective trends: evolution in relationship with geopolitical events and energy policies, strong correlation between oil demand and economic growth, prevalence of OPEC, growing importance of national oil companies. An emerging trend is noticed: growing role of emerging countries on the crude market. Some prospective issues are discussed: duration and intensity of economic recession, separation between economic growth and energy consumption, pace and ambition level of policies of struggle against climate change, exploitable resources, and geopolitical hazards. Four evolution hypotheses are discussed

  4. Semisubmersible oil platforms: understudied and potentially major vectors of biofouling-mediated invasions.

    Science.gov (United States)

    Yeo, Darren C J; Ahyong, Shane T; Lodge, David M; Ng, Peter K L; Naruse, Tohru; Lane, David J W

    2010-01-01

    Biofouling has long been recognised as a major pathway for the introduction of non-indigenous species. This study records the decapods and stomatopod crustaceans fouling a semisubmersible oil platform dry docked for hull cleaning in Jurong Port, Singapore. Of the 25 species of decapods identified, 13 were non-indigenous and represent new records to Singapore waters. Of these, the crabs Glabropilumnus seminudus and Carupa tenuipes are known to be invasive in other parts of the world. The stomatopod, Gonodactylaceus randalli, is the first mantis shrimp recorded in a biofouling community. The richness and diversity of this fouling community, consisting of many vagile species, highlights the difference between platforms and ships. With the expansion of maritime oil and gas exploration, the threat posed by an expanded fleet of semisubmersible oil platforms translocating non-indigenous fouling communities across biogeographical boundaries is very serious. Scientists, policy-makers, and stakeholders should turn their attention to this growing problem.

  5. Variation in Scent Compounds of Oil-Bearing Rose (Rosa damascena Mill. Produced by Headspace Solid Phase Microextraction, Hydrodistillation and Solvent Extraction

    Directory of Open Access Journals (Sweden)

    Sabri Erbaş

    2016-03-01

    Full Text Available In this research, rose oil and rose water were hydro-distilled from the fresh oil-bearing rose flowers (Rosa damascena Mill. using Clevenger-type apparatus. Rose concretes were extracted from the fresh rose flowers by using non-polar solvents, e.g. diethyl ether, petroleum ether, cyclo-hexane, chloroform and n-hexane, and subsequently by evaporation of the solvents under vacuum. Absolutes were produced from the concretes with ethyl alcohol extraction at -20°C, leaving behind the wax and other paraffinic substances. Scent compounds of all these products detected by gas chromatography (GC-FID/GC-MS were compared with the natural scent compounds of fresh rose flower detected by using headspace solid phase microextraction (HS-SPME with carboxen/polydimethylsiloxane (CAR/PDMS fiber. A total of 46 compounds analysis were identified by HS-SPME-GC-MS in the fresh flower, and a total of 15 compounds were identified by GC-MS in the hydrodistilled rose oil. While main compounds in rose oil were geraniol (35.4%, citronellol (31.6%, and nerol (15.3%, major compound in fresh rose flower, rose water and residue water was phenylethyl alcohol (43.2, 35.6 and 98.2%, respectively. While the highest concrete yield (0.7% was obtained from diethyl ether extraction, the highest absolute yield (70.9% was obtained from the n-hexane concrete. The diethyl ether concrete gave the highest productivity of absolute, as 249.7 kg of fresh rose flowers was needed to produce 1 kg of absolute.

  6. Observations of VOC emissions and photochemical products over US oil- and gas-producing regions using high-resolution H3O+ CIMS (PTR-ToF-MS

    Directory of Open Access Journals (Sweden)

    A. Koss

    2017-08-01

    Full Text Available VOCs related to oil and gas extraction operations in the United States were measured by H3O+ chemical ionization time-of-flight mass spectrometry (H3O+ ToF-CIMS/PTR-ToF-MS from aircraft during the Shale Oil and Natural Gas Nexus (SONGNEX campaign in March–April 2015. This work presents an overview of major VOC species measured in nine oil- and gas-producing regions, and a more detailed analysis of H3O+ ToF-CIMS measurements in the Permian Basin within Texas and New Mexico. Mass spectra are dominated by small photochemically produced oxygenates and compounds typically found in crude oil: aromatics, cyclic alkanes, and alkanes. Mixing ratios of aromatics were frequently as high as those measured downwind of large urban areas. In the Permian, the H3O+ ToF-CIMS measured a number of underexplored or previously unreported species, including aromatic and cycloalkane oxidation products, nitrogen heterocycles including pyrrole (C4H5N and pyrroline (C4H7N, H2S, and a diamondoid (adamantane or unusual monoterpene. We additionally assess the specificity of a number of ion masses resulting from H3O+ ion chemistry previously reported in the literature, including several new or alternate interpretations.

  7. Observations of VOC emissions and photochemical products over US oil- and gas-producing regions using high-resolution H3O+ CIMS (PTR-ToF-MS)

    Science.gov (United States)

    Koss, Abigail; Yuan, Bin; Warneke, Carsten; Gilman, Jessica B.; Lerner, Brian M.; Veres, Patrick R.; Peischl, Jeff; Eilerman, Scott; Wild, Rob; Brown, Steven S.; Thompson, Chelsea R.; Ryerson, Thomas; Hanisco, Thomas; Wolfe, Glenn M.; St. Clair, Jason M.; Thayer, Mitchell; Keutsch, Frank N.; Murphy, Shane; de Gouw, Joost

    2017-08-01

    VOCs related to oil and gas extraction operations in the United States were measured by H3O+ chemical ionization time-of-flight mass spectrometry (H3O+ ToF-CIMS/PTR-ToF-MS) from aircraft during the Shale Oil and Natural Gas Nexus (SONGNEX) campaign in March-April 2015. This work presents an overview of major VOC species measured in nine oil- and gas-producing regions, and a more detailed analysis of H3O+ ToF-CIMS measurements in the Permian Basin within Texas and New Mexico. Mass spectra are dominated by small photochemically produced oxygenates and compounds typically found in crude oil: aromatics, cyclic alkanes, and alkanes. Mixing ratios of aromatics were frequently as high as those measured downwind of large urban areas. In the Permian, the H3O+ ToF-CIMS measured a number of underexplored or previously unreported species, including aromatic and cycloalkane oxidation products, nitrogen heterocycles including pyrrole (C4H5N) and pyrroline (C4H7N), H2S, and a diamondoid (adamantane) or unusual monoterpene. We additionally assess the specificity of a number of ion masses resulting from H3O+ ion chemistry previously reported in the literature, including several new or alternate interpretations.

  8. Co-production of bio-oil and propylene through the hydrothermal liquefaction of polyhydroxybutyrate producing cyanobacteria.

    Science.gov (United States)

    Wagner, Jonathan; Bransgrove, Rachel; Beacham, Tracey A; Allen, Michael J; Meixner, Katharina; Drosg, Bernhard; Ting, Valeska P; Chuck, Christopher J

    2016-05-01

    A polyhydroxybutyrate (PHB) producing cyanobacteria was converted through hydrothermal liquefaction (HTL) into propylene and a bio-oil suitable for advanced biofuel production. HTL of model compounds demonstrated that in contrast to proteins and carbohydrates, no synergistic effects were detected when converting PHB in the presence of algae. Subsequently, Synechocystis cf. salina, which had accumulated 7.5wt% PHB was converted via HTL (15% dry weight loading, 340°C). The reaction gave an overall propylene yield of 2.6%, higher than that obtained from the model compounds, in addition to a bio-oil with a low nitrogen content of 4.6%. No propylene was recovered from the alternative non-PHB producing cyanobacterial strains screened, suggesting that PHB is the source of propylene. PHB producing microorganisms could therefore be used as a feedstock for a biorefinery to produce polypropylene and advanced biofuels, with the level of propylene being proportional to the accumulated amount of PHB. Copyright © 2016 Elsevier Ltd. All rights reserved.

  9. Comparative Effect of Dietary Soybean Oil, Fish Oil, and Coconut Oil on Performance, Egg Quality and Some Blood Parameters in Laying Hens.

    Science.gov (United States)

    Dong, X F; Liu, S; Tong, J M

    2018-04-14

    Two hundred and sixteen 28-wk-old Hy-line laying hens were randomly distributed to three dietary treatments and fed 1of 3 diets containing 8% soybean oil, fish oil, or coconut oil from 28 to 47 wk of age to investigate comparative effect of dietary soybean oil, fish oil, and coconut oil on the performance, egg quality and blood malondialdehyde (MDA), aspartate transaminase (AST) and uric acid (UA). Hens fed fish oil showed poor performance compared with soybean oil or coconut oil, and especially egg weight throughout the trial was significantly and consistently decreased (P oil. Unexpectedly, shell reflectivity throughout the majority of the trial was consistently and significantly higher (P oil than that when fed soybean oil or coconut oil. Dietary treatments affected (P oil treatment was higher (P oil group. Albumen height, Haugh unit and yolk color were influenced by dietary treatments only at 1 or 2 time points. However, average albumen height and Haugh unit in fish oil treatment were higher (P soybean oil or coconut oil treatments and average yolk color in coconut oil treatment was higher (P soybean oil group. Serum MDA, AST and UA concentrations were increased (P oil during the majority of the first 2 mo of the trial. These data suggested that the inclusion of fish oil into feed may reduce the performance of laying hens, especially the egg weight, decrease the intensity of egg brown color and increase blood MDA, AST and UA levels compared with soybean oil or coconut oil. As a result, hens fed fish oil may lay smaller, longer and lighter-brown eggs whereas those fed coconut oil produce blunter and darker-brown eggs relative to soybean oil.

  10. Oil Palm Expansion in the Brazilian Amazon (2006-2014): Effects of the 2010 Sustainable Oil Palm Production Program

    Science.gov (United States)

    Benami, E.; Curran, L. M.

    2017-12-01

    Brazil has the world's largest suitable land area for oil palm (Elaeis guineensis) establishment, with estimates as high as 238 million ha. To promote oil palm development, Brazil launched the Sustainable Palm Oil Production Program (SPOPP) in 2010 and delineated 30 million ha for its growth that excluded forested areas and indigenous reserves. Here we examine oil palm expansion (2006-2014) as well as the SPOPP's effectiveness in Pará, the major oil palm producing state in Brazil. By combining analyses of satellite imagery, land registration data, and site based interviews, we found that oil palm area expanded 205%. Although >50% of oil palm parcels were located within 0.5 km of intact forests, lands. Direct intact forest conversion pre- and post-SPOPP declined from 4% to <1%; however, <1% of the 30 million ha promoted for oil palm was developed by 2014. To explore the major factors that may have constrained oil palm expansion under the SPOPP, we conducted microeconomic simulations of oil palm production, combined with interviews with actors/individuals from oil palm companies, civil society, researchers at universities and NGOs, and governmental agencies. Brazil's oil palm-deforestation dynamics, policies, and economic conditions will be discussed.

  11. Life Cycle Assessment for the Production of Oil Palm Seeds.

    Science.gov (United States)

    Muhamad, Halimah; Ai, Tan Yew; Khairuddin, Nik Sasha Khatrina; Amiruddin, Mohd Din; May, Choo Yuen

    2014-12-01

    The oil palm seed production unit that generates germinated oil palm seeds is the first link in the palm oil supply chain, followed by the nursery to produce seedling, the plantation to produce fresh fruit bunches (FFB), the mill to produce crude palm oil (CPO) and palm kernel, the kernel crushers to produce crude palm kernel oil (CPKO), the refinery to produce refined palm oil (RPO) and finally the palm biodiesel plant to produce palm biodiesel. This assessment aims to investigate the life cycle assessment (LCA) of germinated oil palm seeds and the use of LCA to identify the stage/s in the production of germinated oil palm seeds that could contribute to the environmental load. The method for the life cycle impact assessment (LCIA) is modelled using SimaPro version 7, (System for Integrated environMental Assessment of PROducts), an internationally established tool used by LCA practitioners. This software contains European and US databases on a number of materials in addition to a variety of European- and US-developed impact assessment methodologies. LCA was successfully conducted for five seed production units and it was found that the environmental impact for the production of germinated oil palm was not significant. The characterised results of the LCIA for the production of 1000 germinated oil palm seeds showed that fossil fuel was the major impact category followed by respiratory inorganics and climate change.

  12. Malaysia: oil, gas, petrochemicals

    International Nuclear Information System (INIS)

    1990-01-01

    Petronas or Petroliam Nasional Berhad was established on 17 August 1974 as the national petroleum corporation of Malaysia. The Petroleum Development Act, passed by the Malaysian Parliament in October of that same year, vested in Petronas the entire ownership of all oil and natural gas resources in the country. These resources are considerable and Malaysia is poised to become one of the major petrochemical producers in the region. This report outlines the extent of oil, gas and petrochemicals production in Malaysia, lists companies holding licences and contracts from Petronas and provides a directory of the Malaysian oil industry. (Author)

  13. Agrochemical characterization of vermicomposts produced from residues of Palo Santo (Bursera graveolens) essential oil extraction

    DEFF Research Database (Denmark)

    Carrión-Paladines, Vinicio; Fries, Andreas; Gomez Muñoz, Beatriz

    2016-01-01

    Fruits of Palo Santo (Bursera graveolens) are used for essential oil extraction. The extraction process is very efficient, because up to 3% of the fresh fruits can be transformed into essential oil; however, a considerable amount of waste is concurrently produced (>97% of the fresh biomass). Rece...

  14. Anti-listerial effects of essential oils and herbs in fresh-cut produce: opportunities and limitations

    OpenAIRE

    Scollard, Johann

    2011-01-01

    peer-reviewed The potential anti-listerial benefits of essential oils and herbs in fresh-cut produce systems were investigated. Interactions with modified atmospheres and product types were examined in detail, including effects on quality. A strong anti-listerial response from rosemary herb was discovered during maceration and the chemical basis of this determined for future exploitation. The anti-listerial properties of essential oils (thyme, oregano and rosemary), under a ...

  15. The instability of world oil market and its impact on economic development: Indonesia's experience

    International Nuclear Information System (INIS)

    Patmosukismo, S.

    1991-01-01

    The world oil market has been characterized by fluctuating prices which have a direct impact on the world economy. If the world oil price rises in real terms, upstream activities become more attractive to producers, and if the price declines, downstream opportunities become more attractive. The world oil market is currently determined not only by producers and consumers, but also by the futures trade. In addition, the elasticity of oil prices has increased since the 1970s through competition among producers and competition from other energy sources. The Asia Pacific countries are experiencing rapid economic growth, and are thus heavily dependent on oil, but generally have small reserves. Their reserves/production ratio is ca 20 years, with a major share coming from China and Indonesia. The current situation of tight and inadequate supply may increase the region's dependence on Middle East sources. The effects of the three recent major oil crises on the Asia Pacific countries are reviewed and the role of oil and gas in Indonesia's economic development is described. Export earnings from oil and gas represent a major share of total Indonesian export revenues, and taxes and receipts from oil companies continue to be the largest receipts in Indonesian government revenues. Slow changes in the primary fuel mix and high growth in domestic consumption may turn Indonesia into a net oil importer before the year 2000. A major effort to decrease domestic oil consumption has been implemented by using natural gas and coal in the power generation sector. On the supply side, recoverable oil and gas reserves of 50 billion bbl and 200 trillion ft 3 respectively may be present but their development depends on the investment scheme of the continuing exploration program

  16. Characterization of Oilseed Lipids from “DHA-Producing Camelina sativa”: A New Transformed Land Plant Containing Long-Chain Omega-3 Oils

    Directory of Open Access Journals (Sweden)

    Maged P. Mansour

    2014-02-01

    Full Text Available New and sustainable sources of long-chain (LC, ≥C20 omega-3 oils containing DHA (docosahexaenoic acid, 22:6ω3 are required to meet increasing demands. The lipid content of the oilseed of a novel transgenic, DHA-producing land plant, Camelina sativa, containing microalgal genes able to produce LC omega-3 oils, contained 36% lipid by weight with triacylglycerols (TAG as the major lipid class in hexane extracts (96% of total lipid. Subsequent chloroform-methanol (CM extraction recovered further lipid (~50% polar lipid, comprising glycolipids and phospholipids and residual TAG. The main phospholipid species were phosphatidyl choline and phosphatidyl ethanolamine. The % DHA was: 6.8% (of total fatty acids in the TAG-rich hexane extract and 4.2% in the polar lipid-rich CM extract. The relative level of ALA (α-linolenic acid, 18:3ω3 in DHA-camelina seed was higher than the control. Major sterols in both DHA- and control camelina seeds were: sitosterol, campesterol, cholesterol, brassicasterol and isofucosterol. C16–C22 fatty alcohols, including iso-branched and odd-chain alcohols were present, including high levels of iso-17:0, 17:0 and 19:0. Other alcohols present were: 16:0, iso-18:0, 18:0 and 18:1 and the proportions varied between the hexane and CM extracts. These iso-branched odd-chain fatty alcohols, to our knowledge, have not been previously reported. These components may be derived from wax esters, or free fatty alcohols.

  17. Risk Reduction and Soil Ecosystem Restoration in an Active Oil Producing Area in an Ecologically Sensitive Setting

    Energy Technology Data Exchange (ETDEWEB)

    Kerry L. Sublette; Greg Thoma; Kathleen Duncan

    2006-01-01

    The empowerment of small independent oil and gas producers to solve their own remediation problems will result in greater environmental compliance and more effective protection of the environment as well as making small producers more self-reliant. In Chapter 1 we report on the effectiveness of a low-cost method of remediation of a combined spill of crude oil and brine in the Tallgrass Prairie Preserve in Osage County, OK. Specifically, we have used hay and fertilizer as amendments for remediation of both the oil and the brine. No gypsum was used. Three spills of crude oil plus produced water brine were treated with combinations of ripping, fertilizers and hay, and a downslope interception trench in an effort to demonstrate an inexpensive, easily implemented, and effective remediation plan. There was no statistically significant effect of treatment on the biodegradation of crude oil. However, TPH reduction clearly proceeded in the presence of brine contamination. The average TPH half-life considering all impacted sites was 267 days. The combination of hay addition, ripping, and a downslope interception trench was superior to hay addition with ripping, or ripping plus an interception trench in terms of rates of sodium and chloride leaching from the impacted sites. Reductions in salt inventories (36 months) were 73% in the site with hay addition, ripping and an interception trench, 40% in the site with hay addition and ripping only, and < 3% in the site with ripping and an interception trench.

  18. Non-invasive rapid harvest time determination of oil-producing microalgae cultivations for bio-diesel production by using Chlorophyll fluorescence

    Directory of Open Access Journals (Sweden)

    Yaqin eQiao

    2015-10-01

    Full Text Available For the large-scale cultivation of microalgae for biodiesel production, one of the key problems is the determination of the optimum time for algal harvest when algae cells are saturated with neutral lipids. In this study, a method to determine the optimum harvest time in oil-producing microalgal cultivations by measuring the maximum photochemical efficiency of photosystem II (PSII, also called Fv/Fm, was established. When oil-producing Chlorella strains were cultivated and then treated with nitrogen starvation, it not only stimulated neutral lipid accumulation, but also affected the photosynthesis system, with the neutral lipid contents in all four algae strains – Chlorella sorokiniana C1, Chlorella sp. C2, C. sorokiniana C3, C. sorokiniana C7 – correlating negatively with the Fv/Fm values. Thus, for the given oil-producing algae, in which a significant relationship between the neutral lipid content and Fv/Fm value under nutrient stress can be established, the optimum harvest time can be determined by measuring the value of Fv/Fm. It is hoped that this method can provide an efficient way to determine the harvest time rapidly and expediently in large-scale oil-producing microalgae cultivations for biodiesel production.

  19. Revitalizing a mature oil play: Strategies for finding and producing unrecovered oil in frio fluvial-deltaic sandstone reservoirs at South Texas. Annual report, October 1994--October 1995

    Energy Technology Data Exchange (ETDEWEB)

    Holtz, M.; Knox, P.; McRae, L. [and others

    1996-02-01

    The Frio Fluvial-Deltaic Sandstone oil play of South Texas has produced nearly 1 billion barrels of oil, yet it still contains about 1.6 billion barrels of unrecovered mobile oil and nearly the same amount of residual oil resources. Interwell-scale geologic facise models of Frio Fluvial-deltaic reservoirs are being combined with engineering assessments and geophysical evaluations in order to determine the controls that these characteristics exert on the location and volume or unrecovered mobile and residual oil. Progress in the third year centered on technology transfer. An overview of project tasks is presented.

  20. Processing of palm oil mill wastes based on zero waste technology

    Science.gov (United States)

    Irvan

    2018-02-01

    Indonesia is currently the main producer of palm oil in the world with a total production reached 33.5 million tons per year. In the processing of fresh fruit bunches (FFB) besides producing palm oil and kernel oil, palm oil mills also produce liquid and solid wastes. The increase of palm oil production will be followed by an increase in the production of waste generated. It will give rise to major environmental issues especially the discharge of liquid waste to the rivers, the emission of methane from digestion pond and the incineration of empty fruit bunches (EFB). This paper describes a zero waste technology in processing palm oil mill waste after the milling process. The technology involves fermentation of palm oil mill effluent (POME) to biogas by using continuous stirred tank reactor (CSTR) in the presence of thermophilic microbes, producing activated liquid organic fertilizer (ALOF) from discharge of treated waste effluent from biogas digester, composting EFB by spraying ALOF on the EFB in the composter, and producing pellet or biochar from EFB by pyrolysis process. This concept can be considered as a promising technology for palm oil mills with the main objective of eliminating the effluent from their mills.

  1. Review of four major environmental effects monitoring programs in the oil sands region

    International Nuclear Information System (INIS)

    Lott, E.O.; Jones, R.K.

    2010-10-01

    The lack of knowledge on current environmental effects monitoring programs for the mineable oil sands region generates a low public confidence in environment health monitoring and reporting programs for the oil sands operations. In 2010, the Oil Sands Research and Information Network (OSRIN) supervised a study reviewing the major environmental effects monitoring programs that are underway in the Regional Municipality of Wood Buffalo. Four main environmental effects monitoring and reporting organizations existing in the oil sands area were engaged to describe their programs through this study: Alberta Biodiversity Monitoring Institute (ABMI), Cumulative Environmental Management Association (CEMA), Regional Aquatic Monitoring Program (RAMP), Wood Buffalo Environmental Association (WBEA). These different organizations have specific roles in providing information, data and understanding of ecosystem effects. A one page visual summary of environmental effects monitoring in the oil sands area resulted from the information received from these organizations and detailed fact sheets were presented for each one of the programs. The report of this study also presents seven other environmental monitoring initiatives or organizations such as Alberta Environment and Environment Canada environmental effects monitoring program. The main observation that emerged from the review was the lack of detailed understanding shown by the stakeholders regarding the monitoring activities performed in the oil sands area. There is a lack of communication of the different programs that are conducted in the region. The study also pointed out that no efforts were put in cross-linking the various programs to be assured that every concerns related to environmental effects associated with oil sands operations were addressed. A better understanding of environmental effects and an improvement in public confidence in the data and its interpretation would probably be observed with the establishment of a

  2. The prospects for oil prices, supply and demand

    International Nuclear Information System (INIS)

    Al-Fathi, S.A.

    1991-01-01

    The major factors that have influenced price developments are briefly discussed. The future course of oil prices and the supply/demand fundamentals that are likely to influence them will be reviewed in the light of OPEC producers' quest for stability in the market and the maintenance of the role of oil in the energy spectrum. The environment and climate change debate is likely to influence development in the energy and oil markets for a long time to come. Its impact on oil demand is thus discussed, together with its implication for oil prices. (author)

  3. Impact on world oil prices when larger and fewer producers emerge from a political restructuring of the Middle East

    International Nuclear Information System (INIS)

    Wirl, F.

    1992-01-01

    We investigate how a redistribution of oil reserves among a (probably reduced) set of producers affects OPEC's oil extraction policies and thus international crude oil-prices. The empirical investigation shows that this impact is fairly small, as long as OPEC members do not cooperate. Only cooperation will have a substantial impact. (author)

  4. Major components in oils obtained from Amazonian palm fruits

    Directory of Open Access Journals (Sweden)

    Santos, M. F. G.

    2013-06-01

    Full Text Available Native palm trees belong to the Arecaceae family and are among the most useful plant resources in the Amazons. Despite its great diversity and various uses, few species have been study in detail, which makes it necessary to perform more comprehensive studies on the quality and composition of species not yet explored. This study deals with the characterization of the major compounds in the oils obtained from the mesocarp of fruits of the main palm species from the State of Amapá, Brasil, i.e. bacaba (Oenocarpus bacaba, buriti (Mauritia flexuosa, inajá (Maximiliana maripa, pupunha (Bactris gasipaes and tucumã (Astrocaryum vulgare. Physicochemical characteristics, fatty acids and triacylglycerol (TAG contents were analyzed by HPLC and GC. The proximate composition of the fruits was also analyzed. The results relating to acidity, peroxide value and polar compounds indicate good quality of the oils obtained. Oleic acid ranging from 39.2 to 71.6% and palmitic acid ranging from 20.8 to 39.6% were the two major fatty acids in all the samples. The oils from inajá were characterized by the presence of significant amounts of lauric (4.6% and miristic (10.7% acids while in bacaba, buriti, pupunha and tucumã, as in most edible vegetable oils, only the fatty acids of 16 and 18 carbon atoms were present. Accordingly, the major TAG species in all the samples were POP, POO and OOO. The mesocarp of the palm fruit had a high content in lipids ranging from 17.0% for pupunha to 38.3% for bacaba, expressed as dry basis.Las palmeras nativas de la familia Arecaceae constituyen recursos alimentarios de gran importancia en la región amazónica. A pesar de su diversidad y utilidad, muchas especies son poco conocidas por lo que son de interés los estudios dirigidos a conocer la calidad y composición de las especies menos exploradas para evaluar su potencial económico. El objetivo de este estudio fue la caracterización de los aceites obtenidos del mesocarpio

  5. Phase separation of bio-oil produced by co-pyrolysis of corn cobs and polypropylene

    Science.gov (United States)

    Supramono, D.; Julianto; Haqqyana; Setiadi, H.; Nasikin, M.

    2017-11-01

    In co-pyrolysis of biomass-plastics, bio-oil produced contains both oxygenated and non-oxygenated compounds. High oxygen composition is responsible for instability and low heating value of bio-oil and high acid content for corrosiveness. Aims of the present work are to evaluate possibilities of achieving phase separation between oxygenated and non-oxygenated compounds in bio-oil using a proposed stirred tank reactor and to achieve synergistic effects on bio-oil yield and non-oxygenated compound layer yield. Separation of bio-oil into two layers, i.e. that containing oxygenated compounds (polar phase) and non-oxygenated compounds (non-polar phase) is important to obtain pure non-polar phase ready for the next processing of hydrogenation and used directly as bio-fuel. There has been no research work on co-pyrolysis of biomass-plastic considering possibility of phase separation of bio-oil. The present work is proposing a stirred tank reactor for co-pyrolysis with nitrogen injection, which is capable of tailoring co-pyrolysis conditions leading to low viscosity and viscosity asymmetry, which induce phase separation between polar phase and non-polar phase. The proposed reactor is capable of generating synergistic effect on bio-oil and non-polar yields as the composition of PP in feed is more than 25% weight in which non-polar layers contain only alkanes, alkenes, cycloalkanes and cycloalkenes.

  6. TECHNOLOGY TRANSFER TO U.S. INDEPENDENT OIL AND NATURAL GAS PRODUCERS

    Energy Technology Data Exchange (ETDEWEB)

    Donald Duttlinger

    2001-11-01

    The Petroleum Technology Transfer Council (PTTC) continued pursuing its mission of helping U.S. independent oil and gas producers make timely, informed technology decisions during Fiscal Year 2001 (FY01). Functioning as a cohesive national organization, PTTC has active grassroots programs through its ten Regional Lead Organizations (RLOs). They bring research and academia to the table via their association with geological surveys and engineering departments. The regional directors interact with independent oil and gas producers through technology workshops, resource centers, websites, newsletters, various technical publications and other outreach efforts. These are guided by regional Producer Advisory Groups (PAGs), who are area operators and service companies working with the regional networks. The role of the national Headquarters (HQ) staff includes planning and managing the PTTC program, conducting nation wide technology transfer activities, and implementing a comprehensive communications effort. The organization effectively combines federal funding through the Department of Energy's (DOE) Office of Fossil Energy, state, and industry funding to achieve important goals for all of these sectors. This integrated funding base, combined with industry volunteers guiding PTTC's activities and the dedication of national and regional staff, are achieving notable results. PTTC is increasingly recognized as a critical resource for information and access to technologies, especially for smaller companies without direct contact to R&D efforts. This technical progress report summarizes PTTC's accomplishments during FY01, which lays the groundwork for further growth in the future. At a time of many industry changes and wide market movements, the organization itself is adapting to change. PTTC has built a reputation and expectation among producers and other industry participants to quickly distribute information addressing technical needs. The organization

  7. TECHNOLOGY TRANSFER TO U.S. INDEPENDENT OIL AND NATURAL GAS PRODUCERS

    Energy Technology Data Exchange (ETDEWEB)

    Unknown

    2000-11-01

    The Petroleum Technology Transfer Council (PTTC) continued pursuing its mission of helping U.S. independent oil and gas producers make timely, informed technology decisions during Fiscal Year 2000 (FY00). Functioning as a cohesive national organization, PTTC has active grassroots programs through its ten Regional Lead Organizations (RLOs) who bring research and academia to the table via their association with geological surveys and engineering departments. The regional directors connect with independent oil and gas producers through technology workshops, resource centers, websites, newsletters, various technical publications and other outreach efforts. These are guided by regional Producer Advisory Groups (PAGs), who are area operators and service companies working with the Regional Lead Organizations. The role of the national headquarters (HQ) staff includes planning and managing the PTTC program, conducting nation-wide technology transfer activities, and implementing a comprehensive communications effort. The organization effectively combines federal, state, and industry funding to achieve important goals for all of these sectors. This integrated funding base, combined with industry volunteers guiding PTTC's activities and the dedication of national and regional staff, are achieving notable results. PTTC is increasingly recognized as a critical resource for information and access to technologies, especially for smaller companies. This technical progress report summarizes PTTC's accomplishments during FY00, which lays the groundwork for further growth in the future. At a time of many industry changes and market movements, the organization has built a reputation and expectation to address industry needs of getting information distributed quickly which can impact the bottom line immediately.

  8. Alpinia Essential Oils and Their Major Components against Rhodnius nasutus, a Vector of Chagas Disease

    Directory of Open Access Journals (Sweden)

    Thamiris de A. de Souza

    2018-01-01

    Full Text Available Species of the genus Alpinia are widely used by the population and have many described biological activities, including activity against insects. In this paper, we describe the bioactivity of the essential oil of two species of Alpinia genus, A. zerumbet and A. vittata, against Rhodnius nasutus, a vector of Chagas disease. The essential oils of these two species were obtained by hydrodistillation and analyzed by GC-MS. The main constituent of A. zerumbet essential oil (OLALPZER was terpinen-4-ol, which represented 19.7% of the total components identified. In the essential oil of A. vittata (OLALPVIT the monoterpene β-pinene (35.3% was the main constituent. The essential oils and their main constituents were topically applied on R. nasutus fifth-instar nymphs. In the first 10 min of application, OLALPVIT and OLALPZER at 125 μg/mL provoked 73.3% and 83.3% of mortality, respectively. Terpinen-4-ol at 25 μg/mL and β-pinene at 44 μg/mL provoked 100% of mortality. The monitoring of resistant insects showed that both essential oils exhibited antifeedant activity. These results suggest the potential use of A. zerumbet and A. vittata essential oils and their major constituents to control R. nasutus population.

  9. TECHNOLOGY TRANSFER TO U.S. INDEPENDENT OIL AND NATURAL GAS PRODUCERS

    Energy Technology Data Exchange (ETDEWEB)

    Unknown

    2000-05-01

    During FY00, the Petroleum Technology Transfer Council (PTTC) continued pursuing its mission of helping U.S. independent oil and gas producers make timely, informed technology decisions. PTTC's national organization has active grassroots programs that connect with independents through its 10 Regional Lead Organizations (RLOs). These activities--including technology workshops, resource centers, websites, newsletters, and other outreach efforts--are guided by regional Producer Advisory Groups (PAGs). The role of the national headquarters (HQ) staff includes planning and managing the PTTC program, conducting nation-wide technology transfer activities, and implementing a comprehensive communications effort. This technical progress report summarizes PTTC's accomplishments during FY00, which lay the groundwork for further growth in the future.

  10. TECHNOLOGY TRANSFER TO U.S. INDEPENDENT OIL AND NATURAL GAS PRODUCERS

    Energy Technology Data Exchange (ETDEWEB)

    Donald Duttlinger

    1999-12-01

    During FY99, the Petroleum Technology Transfer Council (PTTC) continued pursuing its mission of helping U.S. independent oil and gas producers make timely, informed technology decisions. PTfC's national organization has active grassroots programs that connect with independents through its 10 Regional Lead Organizations (RLOs). These activities--including technology workshops, resource centers, websites, newsletters, and other outreach efforts--are guided by regional Producer Advisory Groups (PAGs). The role of the national headquarters (HQ) staff includes planning and managing the PTTC program, conducting nation-wide technology transfer activities, and implementing a comprehensive communications effort. This technical progress report summarizes PTTC's accomplishments during FY99, which lay the groundwork for further growth in the future.

  11. Oil and influence: the oil weapon examined

    Energy Technology Data Exchange (ETDEWEB)

    Maull, H

    1975-01-01

    The term ''oil weapon'' as used here signifies any manipulation of the price and/or supply of oil by exporting nations with the intention of changing the political behavior of the consumer nations. The political potential of the oil price is fairly restricted so, in effect, the supply interruptions are of prime concern. Manipulating price does, in principle, offer the possibilities of both conferring rewards and inflicting sanctions. Oil could be sold on preferential prices and terms. A precondition for using the oil weapon successfully would be the ability to cause real and serious damage to the consumer countries. Four damaging potentials for using the oil weapon could include its application by: (1) one producer against one consumer; (2) one producer against all consumers; (3) a group of producers against one consumer; and (4) by a group of producers against all consumers. It is concluded that the oil weapon will continue to be a force in the international system. (MCW)

  12. Assessment of the quality of bran and bran oil produced from some Egyptian rice varieties.

    Science.gov (United States)

    Salem, Eglal G; El Hissewy, Ahmed; Agamy, Neveen F; Abd El Barry, Doaa

    2014-04-01

    Rice (Oryza sativa L.) is one of the leading food crops of the world, the staple food of over half the world's population. The bran, which is an important byproduct obtained during rice milling, constitutes about 1/10 of the weight of the rice grain. Rice bran is the outer brown layer including the rice germ that is removed during the milling process of brown grain. This milling byproduct is reported to be high in natural vitamins and minerals, particularly vitamin E. The present study was conducted to determine the chemical composition of bran and bran oil of 13 different rice varieties commonly produced in Egypt, to study the utilization of rice bran in bread production, and to assess the quality and acceptance of the rice bran edible oil produced. Rice bran was produced from 13 Egyptian varieties of recently harvested rice as well as from paddy rice stored for 1 year. The extracted bran was immediately stabilized then subjected to chemical analysis (such as moisture content, protein, fat, carbohydrates, fiber, and ash) as well as trace and heavy metals determination (P, K, Na, Ca, Fe, Zn, Cu, and Mg). Bread was produced by adding Giza172 rice bran at three different concentrations to wheat flour then subjected to chemical analysis, caloric content, and organoleptic examination. Bran oil was extracted from the different varieties of rice bran (recently harvested and stored) then subjected to chemical and organoleptic examinations as well as vitamin E and oryzanol determination. The percentage of rice bran of newly harvested Egyptian rice was 11.68% and was 10.97% in stored rice. The analysis showed mean values of 5.91 and 5.53% for moisture, 14.60 and 14.40% for crude protein, 14.83 and 15.20% for fat, 44.77 and 45.40% for carbohydrates, 6.55 and 7.06% for crude fiber, and 8.87 and 8.50% for ash for newly harvested and stored rice bran, respectively. Bread containing 15% rice bran showed the highest score percentages for organoleptic quality compared with the

  13. Aostra claims major oilsands breakthrough

    International Nuclear Information System (INIS)

    Anon.

    1991-01-01

    This paper reports that Alberta Oil Sands Technology and Research Authority (Aostra) has completed a horizontal well in-situ steam injection project it calls a major breakthrough in commercially producing bitumen from the bast Athabasca oilsands deposit in Alberta. Aostra the its $71 million (Canadian) proof of concept pilot underground test facility (UTF) near Fort McMurray, achieved a 60% bitumen recovery rate, compared with less than 20% recovery typically achieved with Alberta bitumen. More than 100,000 bbl of bitumen was produced during the project

  14. Differing perspectives of major oil firms on future energy developments: An illustrative framework

    International Nuclear Information System (INIS)

    Chang Youngho; Yong Jiayun

    2007-01-01

    This study develops a framework to analyse the perspectives of major oil firms in terms of their perceptions of current energy developments and projections of future energy potentials, and illustrates their views on the possibility of a paradigm shift in fuel use. The three A's themes-availability of resource (AV), applicability of technology (AP) and acceptability by society (AC)-make up the analytical framework. Divergence in oil firms' behaviour and perspectives are captured by the 3-A triangle that illustrates how the four largest oil firms in the world balance their stakes among the three A's. ExxonMobil's position is markedly skewed towards the theme of AV, whilst BP has the most balanced approach among the four. Shell and Total both share a similarly shaped 3-A triangle with more stakes placed on the theme of AP. The results would imply that a paradigm shift in resource use or a full-scale transition to a backstop technology is unlikely in the coming decades

  15. Quantitative effects of the shale oil revolution

    International Nuclear Information System (INIS)

    Belu Mănescu, Cristiana; Nuño, Galo

    2015-01-01

    The aim of this paper is to analyze the impact of the so-called “shale oil revolution” on oil prices and economic growth. We employ a general equilibrium model of the world oil market in which Saudi Arabia is the dominant firm, with the rest of the producers as a competitive fringe. Our results suggest that most of the expected increase in US oil supply due to the shale oil revolution has already been incorporated into prices and that it will produce an additional increase of 0.2% in the GDP of oil importers in the period 2010–2018. We also employ the model to analyze the collapse in oil prices in the second half of 2014 and conclude that it was mainly due to positive unanticipated supply shocks. - Highlights: • We analyze the impact of the “shale oil revolution” on oil prices and economic growth. • We employ a general equilibrium model of the oil market in which Saudi Arabia is the dominant firm. • We find that most of the shale oil revolution is already priced in. • We also analyze the decline in oil prices in the second half of 2014. • We find that unanticipated supply shocks played the major role in the fall.

  16. Purification of produced waters in oil fields

    Energy Technology Data Exchange (ETDEWEB)

    Niyazov, R S; Baikov, U M

    1970-01-01

    Experience has shown that a single step water-conditioning process cannot be used to prepare Bashkirian produced waters for underground injection. In the single-step process, the water is passed through horizontal or vertical settling basins to remove solids. This system does not work when suspended solids increase above 200 to 500 mg/liter. The required quality of injection water can be obtained by filtering the water through sand at flow velocities of 5 to 10 m/hr. The filter has a sand layer 0.6 to 1 m thick, composed of 0.35 to 1.0 mm sand. Water entering the filters should not contain more than 100 to 150 mg/liter of oil products. The filters are backwashed at velocity of 10 to 15 m/hr and rates of 12 to 16 liters/sec sq m for 10 to 15 min. Clean water is used in backwashing. When surfactant is added to the backwash water, the filter cycle lasts longer.

  17. Oil and democracy in Argentina, 1916-1930

    International Nuclear Information System (INIS)

    Biddle, N.L.

    1991-01-01

    Argentine society in the 1920s experience strong political, cultural, and economic divisions between the littoral regional surrounding Buenos Aires and the interior provinces to the west and north. Economic recession through World War 1 sparked efforts to wean the economy from total dependence upon agricultural production and export, and petroleum deposits in the south and northwest corners of Argentina offered a wider economic base. Regional conflict quickly arose concerning oil production and control over oil revenues. By mounting a popular anti-imperialist campaign against Standard Oil of New Jersey, the primary interior oil producer, dominant political forces in Buenos Aires worked to nationalize all oil deposits to the detriment of interior provincial interests. To maintain the kinds of political control necessary to fend off this threat, interior conservatives reverted to electoral fraud and violence, especially in the major oil-producing province of Salta. This thesis reconstructs and analyzes the process by which political division on the oil issue hardened and gave way to a conservative reaction leading to an authoritarian regime

  18. US oil companies ready to take the high ground again

    International Nuclear Information System (INIS)

    Odell, P.

    1994-01-01

    In the 1930s, the petroleum industry, which essentially started in the United States of America (USA), was prevented from expanding its influence to Middle East petroleum producing countries because of the colonial control exercised by Britain, France and the Netherlands. However, with the Second World War, these relationships changed, and gradually the oil traded internationally became the principle source of energy on the world market. A well-known oil industry commentator and critic describes these developments and notes that since the Gulf War, the USA has drawn closer to Saudi Arabia, a major oil producer, and hence permitted U S. oil companies to dominate the world scene. (UK)

  19. Linking Agricultural Trade, Land Demand and Environmental Externalities: Case of Oil Palm in South East Asia

    OpenAIRE

    Othman, Jamal

    2003-01-01

    Reduction of support measures affecting soybean oil in the major soybean producing countries, as a consequence of WTO rules, coupled with rising demand for palm oil in non-traditional palm oil importing countries may lead to pronounced increases in agricultural land demand for oil palm expansion in Malaysia and Indonesia – two main palm oil producing and exporting countries. However, it is expected that the effects on agricultural land demand and consequently impact upon the environment will ...

  20. Dual fuel mode operation in diesel engines using renewable fuels: Rubber seed oil and coir-pith producer gas

    Energy Technology Data Exchange (ETDEWEB)

    Ramadhas, A.S.; Jayaraj, S.; Muraleedharan, C. [Department of Mechanical Engineering, National Institute of Technology Calicut, Calicut-673601 (India)

    2008-09-15

    Partial combustion of biomass in the gasifier generates producer gas that can be used as supplementary or sole fuel for internal combustion engines. Dual fuel mode operation using coir-pith derived producer gas and rubber seed oil as pilot fuel was analyzed for various producer gas-air flow ratios and at different load conditions. The engine is experimentally optimized with respect to maximum pilot fuel savings in the dual fuel mode operation. The performance and emission characteristics of the dual fuel engine are compared with that of diesel engine at different load conditions. Specific energy consumption in the dual-fuel mode of operation with oil-coir-pith operation is found to be in the higher side at all load conditions. Exhaust emission was found to be higher in the case of dual fuel mode of operation as compared to neat diesel/oil operation. Engine performance characteristics are inferior in fully renewable fueled engine operation but it suitable for stationary engine application, particularly power generation. (author)

  1. Reliable in the long run? Petroleum policy and long-term oil supplier reliability

    International Nuclear Information System (INIS)

    Toft, Peter; Duero, Arash

    2011-01-01

    Accelerating oil import dependence in energy consuming nations highlights the importance of having energy supplies at sufficient levels and at stable and reasonable prices. Consequently, it is crucial that oil exporters realize their full production potential. Current debates on energy security are often focused on short-term risks e.g. sudden disruptions due to wars, domestic instability, etc. However, when it comes to assessing oil supplier reliability it is equally important to assess their longer term ability and willingness to deliver oil to the global market. This study analyzes the effects of petroleum investment policies on crude oil production trends in 14 major oil producing countries (2000-2010) by focusing on the political-institutional frameworks that shape the investment conditions for the upstream oil sector. Our findings indicate that countries with less favorable oil sector frameworks systematically performed worse than countries with investor friendly and privatized sectors. The findings indicate that assessments based on remaining reserves and planned production capacities alone could inflate expectations about future oil supplies in a world where remaining crude reserves are located in countries with unfavorable investment frameworks. - Highlights: → We explore if policies favoring state-ownership in upstream oil undermine output expectations. → We compare petroleum policies of 14 major oil producers vis-a-vis production trends 2000-2010. → We find major differences between countries favorable to state-owned or private investors. → Substantial private investment seems needed for oil production to meet long-term demand growth.

  2. Assessment of the repellent effect of Lippia alba essential oil and major monoterpenes on the cattle tick Rhipicephalus microplus.

    Science.gov (United States)

    Lima, A da Silva; Carvalho, J F de; Peixoto, M G; Blank, A F; Borges, L M F; Costa Junior, L M

    2016-03-01

    The control of Rhipicephalus microplus (Ixodida: Ixodidae) is achieved using synthetic acaricides. However, resistant tick populations are widespread around the world. Plant essential oils can act as repellents, keeping ticks away from hosts and decreasing the selection pressure on synthetic acaricides. The aim of this study was to evaluate the in vitro repellent effect of Lippia alba essential oil on R. microplus larvae. Leaves from two L. alba genotypes maintained under the same agronomic and environmental conditions were collected. Essential oil was extracted by hydrodistillation and analysed by gas chromatography-mass spectrometry (GC-MS). The major monoterpenes detected in the chemical analysis were commercially acquired and tested. For the repellency test, a glass rod was vertically fixed to measure active climbing of approximately 30 R. microplus larvae aged 14-21 days in response to essential oils and monoterpenes. Repellency was evaluated at 1 h, 3 h and 5 h after treatment. Variation in repellent action was detected between the genotypes. The major monoterpenes identified in the essential oils (limonene and carvone) showed low repellent effects in comparison with intact essential oils. Thus, the present results showed that L. alba essential oil contains bioactive compounds with great repellent activity against ticks that varies according to the plant genotype. © 2015 The Royal Entomological Society.

  3. NM WAIDS: A PRODUCED WATER QUALITY AND INFRASTRUCTURE GIS DATABASE FOR NEW MEXICO OIL PRODUCERS

    Energy Technology Data Exchange (ETDEWEB)

    Martha Cather; Robert Lee; Ibrahim Gundiler; Andrew Sung; Naomi Davidson; Ajeet Kumar Reddy; Mingzhen Wei

    2003-04-01

    The New Mexico Water and Infrastructure Data System (NM WAIDS) seeks to alleviate a number of produced water-related issues in southeast New Mexico. The project calls for the design and implementation of a Geographical Information System (GIS) and integral tools that will provide operators and regulators with necessary data and useful information to help them make management and regulatory decisions. The major components of this system are: (1) databases on produced water quality, cultural and groundwater data, oil pipeline and infrastructure data, and corrosion information, (2) a web site capable of displaying produced water and infrastructure data in a GIS or accessing some of the data by text-based queries, (3) a fuzzy logic-based, site risk assessment tool that can be used to assess the seriousness of a spill of produced water, and (4) a corrosion management toolkit that will provide operators with data and information on produced waters that will aid them in deciding how to address corrosion issues. The various parts of NM WAIDS will be integrated into a website with a user-friendly interface that will provide access to previously difficult-to-obtain data and information. Primary attention during the first six months of this project has been focused on creating the water quality databases for produced water and surface water, along with collection of corrosion information and building parts of the corrosion toolkit. Work on the project to date includes: (1) Creation of a water quality database for produced water analyses. The database was compiled from a variety of sources and currently has over 4000 entries for southeast New Mexico. (2) Creation of a web-based data entry system for the water quality database. This system allows a user to view, enter, or edit data from a web page rather than having to directly access the database. (3) Creation of a semi-automated data capturing system for use with standard water quality analysis forms. This system improves the

  4. NM WAIDS: A PRODUCED WATER QUALITY AND INFRASTRUCTURE GIS DATABASE FOR NEW MEXICO OIL PRODUCERS

    Energy Technology Data Exchange (ETDEWEB)

    Martha Cather; Robert Lee; Ibrahim Gundiler; Andrew Sung

    2003-09-24

    The New Mexico Water and Infrastructure Data System (NM WAIDS) seeks to alleviate a number of produced water-related issues in southeast New Mexico. The project calls for the design and implementation of a Geographical Information System (GIS) and integral tools that will provide operators and regulators with necessary data and useful information to help them make management and regulatory decisions. The major components of this system are: (1) Databases on produced water quality, cultural and groundwater data, oil pipeline and infrastructure data, and corrosion information. (2) A web site capable of displaying produced water and infrastructure data in a GIS or accessing some of the data by text-based queries. (3) A fuzzy logic-based, site risk assessment tool that can be used to assess the seriousness of a spill of produced water. (4) A corrosion management toolkit that will provide operators with data and information on produced waters that will aid them in deciding how to address corrosion issues. The various parts of NM WAIDS will be integrated into a website with a user-friendly interface that will provide access to previously difficult-to-obtain data and information. Primary attention during the first six months of this project was focused on creating the water quality databases for produced water and surface water, along with collecting of corrosion information and building parts of the corrosion toolkit. Work on the project to date includes: (1) Creation of a water quality database for produced water analyses. The database was compiled from a variety of sources and currently has over 7000 entries for New Mexico. (2) Creation of a web-based data entry system for the water quality database. This system allows a user to view, enter, or edit data from a web page rather than having to directly access the database. (3) Creation of a semi-automated data capturing system for use with standard water quality analysis forms. This system improves the accuracy and speed

  5. Trends in heavy oil production and refining in California

    International Nuclear Information System (INIS)

    Olsen, D.K.; Ramzel, E.B.; Pendergrass, R.A. II.

    1992-07-01

    This report is one of a series of publications assessing the feasibility of increasing domestic heavy oil production and is part of a study being conducted for the US Department of Energy. This report summarizes trends in oil production and refining in Canada. Heavy oil (10 degrees to 20 degrees API gravity) production in California has increased from 20% of the state's total oil production in the early 1940s to 70% in the late 1980s. In each of the three principal petroleum producing districts (Los Angeles Basin, Coastal Basin, and San Joaquin Valley) oil production has peaked then declined at different times throughout the past 30 years. Thermal production of heavy oil has contributed to making California the largest producer of oil by enhanced oil recovery processes in spite of low oil prices for heavy oil and stringent environmental regulation. Opening of Naval Petroleum Reserve No. 1, Elk Hills (CA) field in 1976, brought about a major new source of light oil at a time when light oil production had greatly declined. Although California is a major petroleum-consuming state, in 1989 the state used 13.3 billion gallons of gasoline or 11.5% of US demand but it contributed substantially to the Nation's energy production and refining capability. California is the recipient and refines most of Alaska's 1.7 million barrel per day oil production. With California production, Alaskan oil, and imports brought into California for refining, California has an excess of oil and refined products and is a net exporter to other states. The local surplus of oil inhibits exploitation of California heavy oil resources even though the heavy oil resources exist. Transportation, refining, and competition in the market limit full development of California heavy oil resources

  6. Evaluation of the oil Produced from lettuce crop cultivated under three irrigation conditions

    Directory of Open Access Journals (Sweden)

    Hassan El-Mallah, M.

    2012-10-01

    Full Text Available Three oil lettuce seed samples (lactuca Sativa LS10, LS20, LS30 were cultivated under three irrigation conditions (well, normal and water deficient conditions, after 10, 20 and 30 days respectively to evaluate their oils and to see to what extent the oil lettuce plant resists draught conditions. The oils extracted from the three seed samples were evaluated by determining eight lipid profiles using HPLC in conjunction with capillary GLC. Lettuce seed oils are characterized by high contents of linoleic and oleic acids. Of the triacyl glycerols determined, those containing linoleyl and oleyl acyles are the major ones. The whole sterol profiles include β-sitosterol (as major component followed by 7-stigmasterol, campesterol and 5-stigmasterol, which were found in all the lettuce seed oil samples but with slight differences. Furthermore, sterol patterns of the free and acylated sterols, free and acylated sterylglycosides were determined. It was found that LS30 oil has the highest tocopherol content and α-tocopherol is the only constituent in all the lettuce seed oil samples. On the other hand, the 2-position in the lettuce seed oil samples is mainly acylated by unsaturated fatty acids (98.6% namely, oleic and linoleic acids. According to these results, it can be concluded that irrigation conditions do not affect the lipid constituents of the oil and the oil lettuce plant resists draught and its lipid profiles are in agreement with those of conventional vegetable oils.

    Tres muestras de semillas de lechuga (Lactuca Sativa LS10, LS20, LS30 se cultivaron bajo tres condiciones de riego (bien regado, normal y con deficiencia de agua, después de 10, 20 y 30 días, respectivamente para evaluar sus aceites y ver hasta qué punto el aceite de la planta de lechuga resiste las condiciones de riego. Los aceites extraídos de las tres muestras de semillas se evaluó mediante la determinación de ocho perfiles de lípidos usando cromatograf

  7. PLAY ANALYSIS AND DIGITAL PORTFOLIO OF MAJOR OIL RESERVOIRS IN THE PERMIAN BASIN: APPLICATION AND TRANSFER OF ADVANCED GEOLOGICAL AND ENGINEERING TECHNOLOGIES FOR INCREMENTAL PRODUCTION OPPORTUNITIES

    Energy Technology Data Exchange (ETDEWEB)

    Shirley P. Dutton; Eugene M. Kim; Ronald F. Broadhead; William Raatz; Cari Breton; Stephen C. Ruppel; Charles Kerans; Mark H. Holtz

    2003-04-01

    A play portfolio is being constructed for the Permian Basin in west Texas and southeast New Mexico, the largest petroleum-producing basin in the US. Approximately 1300 reservoirs in the Permian Basin have been identified as having cumulative production greater than 1 MMbbl of oil through 2000. Of these major reservoirs, approximately 1,000 are in Texas and 300 in New Mexico. On a preliminary basis, 32 geologic plays have been defined for Permian Basin oil reservoirs and assignment of each of the 1300 major reservoirs to a play has begun. The reservoirs are being mapped and compiled in a Geographic Information System (GIS) by play. Detailed studies of three reservoirs are in progress: Kelly-Snyder (SACROC unit) in the Pennsylvanian and Lower Permian Horseshoe Atoll Carbonate play, Fullerton in the Leonardian Restricted Platform Carbonate play, and Barnhart (Ellenburger) in the Ellenburger Selectively Dolomitized Ramp Carbonate play. For each of these detailed reservoir studies, technologies for further, economically viable exploitation are being investigated.

  8. Bioactivity of Licaria puchury-major Essential Oil Against Aedes aegypti , Tetranychus urticae and Cerataphis lataniae

    Directory of Open Access Journals (Sweden)

    Sidney G. Azevedo

    2018-05-01

    Full Text Available The present study was carried out to evaluate an alternative controlling agent for greenhouse pests and the yellow fever mosquito larvae. The potential bioactivity of Licaria puchury-major (Mart. Kosterm. (“puxuri” was evaluated here against three most common pests in tropical and subtropical countries: Aedes aegypti Linn. Larvae, Tetranychus urticae Koch. mites and Cerataphis lataniae Boisd. aphids. The essential oil from seeds was analyzed by GC-FID and GC-MS. The major compounds were safrole (38.8% and eucalyptol (21.7%. Phenylpropanes (51.7% was the main group of compounds and oxygenated monoterpenes represented 28.8% of the total oil. The essential oil has shown no inhibition of acetylcholinesterase (AChE in the tested concentrations. However, potential antioxidant activities were evaluated by different methods [DPPH: LD 50 = (27.8 ± 1.0 µg/.mL; ABTS: (977.3 ± 25.2 µM TEs/g (Trolox Equivalents; FRAP: (548.2 ± 29.0 µM Fe(II/g]. A significant larvicidal potential for 24 h of exposure was observed with LD 50 = 98.9 µg/mL, being an indicative that the larval mortality may occur by ingestion or contact due to the no inhibition against AChE. Volatile phase effects were evaluated against T. urticae Koch. and C. lataniae Boisd. and LD 50 were found about 30.8 and 13.5 µg/mL , respectively. These results are consistent with an octopaminergic effect , since some phenylpropanoids (such as Safrole, identified as the major compound in this work can block octopamine, a multi-functional, naturally occurring biogenic amine. Then, this study clearly illustrated the efficacy of the investigated seeds, which encourages the development of a new potential natural controlling agent against these common pests due to the abundance of these seeds in the Amazon region and to the high essential oil yield .

  9. Study on the hydrodeoxygenative upgrading of crude bio-oil produced from woody biomass by fast pyrolysis

    International Nuclear Information System (INIS)

    Kim, Tae-Seung; Oh, Shinyoung; Kim, Jae-Young; Choi, In-Gyu; Choi, Joon Weon

    2014-01-01

    Crude bio-oil produced from fast pyrolysis of yellow poplar wood was subjected to HDO (hydrodeoxygenation) for the purpose of reducing water content as well as increasing heating value. HDO was performed in an autoclave reactor at three different reaction factors: temperature (250–370 °C), reaction time (40–120 min), and Pd/C catalyst loading (0–6 wt%) under hydrogen atmosphere. After completion of HDO, gas, char, and two immiscible liquid products (light oil and heavy oil) were obtained. Liquid products were less acidic and contained less water than crude bio-oil. Water content of heavy oil was ranged between 0.4 wt% and 1.9 wt%. Heating values of heavy oil were estimated between 28.7 and 37.4 MJ/kg, which was about twice higher than that of crude bio-oil. Elemental analysis revealed that heavy oil had a lower O/C ratio (0.17–0.36) than crude bio-oil (0.71). H/C ratio of heavy oil decreased from 1.50 to 1.32 with an increase of temperature from 250 °C to 350 °C, respectively. - Highlights: • Bio-oil was subjected to hydrodeoxygenation with Pd/C catalyst in supercritical ethanol. • Gas, char and two immiscible liquids (light/heavy oil) were obtained as final products. • Ethanol addition reduced the char formation during hydrodeoxygenation. • The heavy oil was characteristic to less acidic and less water content than bio-oil. • Higher heating value of the heavy oil was measured to 28.7–37.4 MJ/kg

  10. Environmentalism in the Periphery: Institutional Embeddedness and Deforestation among Fifteen Palm Oil Producers, 1990 – 2012

    Directory of Open Access Journals (Sweden)

    Kent Henderson

    2017-08-01

    Full Text Available Environmental sociologists highlight the exploitative nature of the global capitalist economy where resource extraction from nations in the periphery tends to disproportionately benefit those of the core. From the Brazilian Amazon to mineral-rich Sub-Saharan Africa, the practice of “unequal ecological exchange” persists. Simultaneously, a “global environmental regime” has coalesced as a prominent feature of the contemporary world system. In the post-World War II era, legitimate nation-states must take steps to protect the natural environment and prevent its degradation even at their own economic expense. Stronger national ties to global institutions, particularly international nongovernmental organizations (INGOs consistently yield more positive environmental outcomes. However, previous work suggests that normative expectations for improved environmental practice will be weak or nonexistent in the periphery. We use the case of palm oil production and its relationship to deforestation to provide a more nuanced analysis of the relationship between material and institutional forces in the periphery. Using unbalanced panels of fifteen palm oil producing countries from 1990 to 2012, we find that stronger national ties to world society via citizen memberships in INGOs result in greater primary forest area among palm oil producers. However, this effect is strongest where production is lowest and weakens as production increases. Even in the cases of Indonesia and Malaysia, where palm oil production is substantially higher than any other producer, ties to global institutions are significantly related to reduced forest loss. These results indicate the variable importance of national embeddedness into global institutions within the periphery of the world system.

  11. New bioemulsifiers produced by Candida lipolytica using D-glucose and babassu oil as carbon sources

    Directory of Open Access Journals (Sweden)

    Vance-Harrop Mabel H.

    2003-01-01

    Full Text Available Candida lipolytica IA 1055 produced extracellular biosurfactants with emulsification activity by fermentation using babassu oil and D-glucose as carbon sources. Natural seawater diluted at 50% supplemented with urea, ammonium sulfate, and phosphate was used as economic basal medium. The best results were achieved with the YSW-B2 medium, which contained urea, ammonium sulfate, and babassu oil and with YSW-B3 medium, which contained urea, ammonium sulfate, phosphate, and babassu oil, kept under fed batch fermentation for 60 hours with 5% of babassu oil. For the two media, the maximum specific growth rates were 0.02 h-1 and 0.04 h-1; the generation times were 34.6 h-1 and 17.3 h-1, and the emulsification activities were 0.666 and 0.158 units, respectively. The molecules of these new bioemulsifiers were contituted of carbohydrates, proteins and lipids.

  12. 76 FR 33969 - Marketing Order Regulating the Handling of Spearmint Oil Produced in the Far West; Revision of...

    Science.gov (United States)

    2011-06-10

    ... the allotment percentage from 43 percent to 50 percent. This change is expected to balance the supply... cultural practice in the production of spearmint oil for weed, insect, and disease control. To remain... farms fall into the SBA category of large businesses. Small spearmint oil producers generally are not as...

  13. Antioxidant capacity and phenolic acids of virgin coconut oil.

    Science.gov (United States)

    Marina, A M; Man, Y B Che; Nazimah, S A H; Amin, I

    2009-01-01

    The antioxidant properties of virgin coconut oil produced through chilling and fermentation were investigated and compared with refined, bleached and deodorized coconut oil. Virgin coconut oil showed better antioxidant capacity than refined, bleached and deodorized coconut oil. The virgin coconut oil produced through the fermentation method had the strongest scavenging effect on 1,1-diphenyl-2-picrylhydrazyl and the highest antioxidant activity based on the beta-carotene-linoleate bleaching method. However, virgin coconut oil obtained through the chilling method had the highest reducing power. The major phenolic acids detected were ferulic acid and p-coumaric acid. Very high correlations were found between the total phenolic content and scavenging activity (r=0.91), and between the total phenolic content and reducing power (r=0.96). There was also a high correlation between total phenolic acids and beta-carotene bleaching activity. The study indicated that the contribution of antioxidant capacity in virgin coconut oil could be due to phenolic compounds.

  14. Biodiesel production in methyl esterification in the frying oil using catalyst Ni_0_,_5Zn_0_,_5Fe_2O_4 to produce biodiesel

    International Nuclear Information System (INIS)

    Vasconcelos, E.V.; Dantas, J.; Pereira, K.B.O.; Barros, A.B.; Moura, T.F.B.; Costa, A.C.F.M.

    2016-01-01

    The use of magnetic catalysts for biodiesel production has gaining prominence because of possibility about its recovery and its reuse, as well as, the reuse of materials that would be discarded in the environment. Thus, we propose to evaluate the efficiency of the catalyst Ni_0_,_5Zn_0_,_5Fe_2O_4 in methyl esterification in the frying oil to produce biodiesel. The catalyst was produced by combustion reaction using containers with different production capacity and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and infrared spectrometry with Fourier transform (FTIR). The catalytic tests were conducted in a stainless steel reactor at 180°C/1h, 2% of catalyst, oil/ethanol ratio of 1:12. Regardless of the container production capacity it was verified the catalyst obtaining with the major phase formation of the inverse spinel and traces of segregated phases with an average crystallite size of 42.13, 32.07 and 36.93 nm. All catalysts showed satisfactory results with conversions of 74%, 77% and 71%. (author)

  15. Isolation and characterization of a biosurfactant-producing Fusarium sp. BS-8 from oil contaminated soil.

    Science.gov (United States)

    Qazi, Muneer A; Kanwal, Tayyaba; Jadoon, Muniba; Ahmed, Safia; Fatima, Nighat

    2014-01-01

    This study reports characterization of a biosurfactant-producing fungal isolate from oil contaminated soil of Missa Keswal oil field, Pakistan. It was identified as Fusarium sp. BS-8 on the basis of macroscopic and microscopic morphology, and 18S rDNA gene sequence homology. The biosurfactant-producing capability of the fungal isolates was screened using oil displacement activity, emulsification index assay, and surface tension (SFT) measurement. The optimization of operational parameters and culture conditions resulted in maximum biosurfactant production using 9% (v/v) inoculum at 30°C, pH 7.0, using sucrose and yeast extract, as carbon and nitrogen sources, respectively. A C:N ratio of 0.9:0.1 (w/w) was found to be optimum for growth and biosurfactant production. At optimal conditions, it attained lowest SFT (i.e., 32 mN m(-1) ) with a critical micelle concentration of ≥ 1.2 mg mL(-1) . During 5 L shake flask fermentation experiments, the biosurfactant productivity was 1.21 g L(-1) pure biosurfactant having significant emulsifying index (E24 , 70%) and oil-displacing activity (16 mm). Thin layer chromatography and Fourier transform infrared spectrometric analyses indicated a lipopeptide type of the biosurfactant. The Fusarium sp. BS-8 has substantial potential of biosurfactant production, yet it needs to be fully characterized with possibility of relatively new class of biosurfactants. © 2014 American Institute of Chemical Engineers.

  16. THE SITUATION OF IRAQI OIL INDUSTRY AND ITS PROSPECTS

    Directory of Open Access Journals (Sweden)

    Al Dulaimi Haidar Ali

    2013-11-01

    Full Text Available Iraq is a major oil producer and exporter(the second one after Saudi Arabia, member of OPEC and was able to reform its oil sector and to gradually pass to a market economy system, by restructuring and privatizing its oil production, processing and distribution. Some medium term and long term priorities set for economic development are presented in the article and also investment and business opportunities existing for domestic and foreign investors.

  17. The role of the US in the geopolitics of climate policy and stranded oil reserves

    Science.gov (United States)

    Jaffe, Amy Myers

    2016-10-01

    Computer-assisted technological innovation and breakthroughs in drilling are revolutionizing the energy landscape, creating greater uncertainty about the future trends for oil use. These new dynamics are prompting major oil producers to reconsider the commercial value of their assets, potentially changing the long-term outlook for oil prices. A shift in investment and production strategy by major oil-producing countries and large multinational companies to pre-empt the risk of stranded assets would have significant implications on energy markets. This Perspective surveys the competitive forces at play that are able to shift the dynamics of the global oil market and discusses their implications for US climate and energy policy. A declining long-term oil price might imply that energy and climate scientists and policymakers should revisit the road map of the optimum policies to promote the transition to lower carbon energy and to defend technology gains already achieved.

  18. ISOLATION AND IDENTIFICATION OF LIPASE-PRODUCING FUNGI FROM LOCAL OLIVE OIL MANUFACTURE IN EAST OF ALGERIA

    Directory of Open Access Journals (Sweden)

    ALIMA RIHANI

    2018-03-01

    Full Text Available The main objective of this work was primary screening and isolation of lipase-producing microorganisms from oil-mill waste. For the screening of fungal strains with lipolytic activity, we employed a sensitive agar plate method, using a medium supplemented with CaCl2 and Tween 80. Another Tributyrin lipase activity was detected from clearing zones due to the hydrolysis of the triacylglycerols. The evolution of biomass and enzyme production has been assayed. A quantitative analysis of lipase activity was performed by the titration method using olive oil as a substrate supplemented with glucose or Tween 80. We have isolated some lipolytic strains from oil-mill effluent. Three of them were found to be excellent lipase producers that were identified as Penicillium sp, Aspergillus fumigatus and Aspergillus terreus. Lipolytic activity and biomass were enhanced in the medium supplemented by glucose. Tween 80 is also considered as a best inducer at the concentration of 1 %. In this condition, these isolates showed maximum lipase production within 24 h; achieved (3.91 IU‧mL-1 ± 0.12 for Penicillium sp.

  19. Radioactivity in produced water from Norwegian oil and gas installations - concentrations, bioavailability and doses to marine biota

    Energy Technology Data Exchange (ETDEWEB)

    Sidhu, R.; Eriksen, D. Oe.; Straalberg, E.; Iden, K. I.; Rye, H.; Hylland, K.; Ruus, A.; Roeyset, O.; Berntssen, M. H. G.

    2006-03-15

    Substantial amounts of produced water, containing elevated levels of radionuclides (mainly 226Ra and 228Ra) are discharged to the sea as a result of oil and gas production on the Norwegian Continental Shelf. So far no study has assessed the potential radiological effects on marine biota in connection with radionuclide discharges to the North Sea. The main objective of the project is to establish radiological safe discharge limits for radium, lead and polonium associated with other components in produced water from oil and gas installations on the Norwegian continental shelf. Preliminary results indicate that presence of added chemicals such as scale inhibitors in the produced water has a marked influence on the formation of radium and barium sulphates when produced water is mixed with sea water. Thus, the mobility and bio-availability of radium (and barium) may be larger than anticipated. Also, the bio-availability of radium may be increased due to presence of such chemicals, and this is presently being studied. (author) (tk)

  20. Anti-oxidant activity and major chemical component analyses of twenty-six commercially available essential oils

    Directory of Open Access Journals (Sweden)

    Hsiao-Fen Wang

    2017-10-01

    Full Text Available This study analyzed 26 commercially available essential oils and their major chemical components to determine their antioxidant activity levels by measuring their total phenolic content (TPC, reducing power (RP, β-carotene bleaching (BCB activity, trolox equivalent antioxidant capacity (TEAC, and 1,1-diphenyl-2-picrylhydrazyl free radical scavenging (DFRS ability. The clove bud and thyme borneol essential oils had the highest RP, BCB activity levels, and TPC values among the 26 commercial essential oils. Furthermore, of the 26 essential oils, the clove bud and ylang ylang complete essential oils had the highest TEAC values, and the clove bud and jasmine absolute essential oils had the highest DFRS ability. At a concentration of 2.5 mg/mL, the clove bud and thyme borneol essential oils had RP and BCB activity levels of 94.56% ± 0.06% and 24.64% ± 0.03% and 94.58% ± 0.01% and 89.33% ± 0.09%, respectively. At a concentration of 1 mg/mL, the clove bud and thyme borneol essential oils showed TPC values of 220.00 ± 0.01 and 69.05 ± 0.01 mg/g relative to gallic acid equivalents, respectively, and the clove bud and ylang ylang complete essential oils had TEAC values of 809.00 ± 0.01 and 432.33 ± 0.01 μM, respectively. The clove bud and jasmine absolute essential oils showed DFRS abilities of 94.13% ± 0.01% and 78.62% ± 0.01%, respectively. Phenolic compounds of the clove bud, thyme borneol and jasmine absolute essential oils were eugenol (76.08%, thymol (14.36% and carvacrol (12.33%, and eugenol (0.87%, respectively. The phenolic compounds in essential oils were positively correlated with the RP, BCB activity, TPC, TEAC, and DFRS ability.

  1. Anti-oxidant activity and major chemical component analyses of twenty-six commercially available essential oils.

    Science.gov (United States)

    Wang, Hsiao-Fen; Yih, Kuang-Hway; Yang, Chao-Hsun; Huang, Keh-Feng

    2017-10-01

    This study analyzed 26 commercially available essential oils and their major chemical components to determine their antioxidant activity levels by measuring their total phenolic content (TPC), reducing power (RP), β-carotene bleaching (BCB) activity, trolox equivalent antioxidant capacity (TEAC), and 1,1-diphenyl-2-picrylhydrazyl free radical scavenging (DFRS) ability. The clove bud and thyme borneol essential oils had the highest RP, BCB activity levels, and TPC values among the 26 commercial essential oils. Furthermore, of the 26 essential oils, the clove bud and ylang ylang complete essential oils had the highest TEAC values, and the clove bud and jasmine absolute essential oils had the highest DFRS ability. At a concentration of 2.5 mg/mL, the clove bud and thyme borneol essential oils had RP and BCB activity levels of 94.56% ± 0.06% and 24.64% ± 0.03% and 94.58% ± 0.01% and 89.33% ± 0.09%, respectively. At a concentration of 1 mg/mL, the clove bud and thyme borneol essential oils showed TPC values of 220.00 ± 0.01 and 69.05 ± 0.01 mg/g relative to gallic acid equivalents, respectively, and the clove bud and ylang ylang complete essential oils had TEAC values of 809.00 ± 0.01 and 432.33 ± 0.01 μM, respectively. The clove bud and jasmine absolute essential oils showed DFRS abilities of 94.13% ± 0.01% and 78.62% ± 0.01%, respectively. Phenolic compounds of the clove bud, thyme borneol and jasmine absolute essential oils were eugenol (76.08%), thymol (14.36%) and carvacrol (12.33%), and eugenol (0.87%), respectively. The phenolic compounds in essential oils were positively correlated with the RP, BCB activity, TPC, TEAC, and DFRS ability. Copyright © 2017. Published by Elsevier B.V.

  2. Comparison of Chemical and Enzymatic Interesterification of Fully Hydrogenated Soybean Oil and Walnut Oil to Produce a Fat Base with Adequate Nutritional and Physical Characteristics

    Directory of Open Access Journals (Sweden)

    Mariel Farfán

    2015-01-01

    Full Text Available The optimal physical, chemical and nutritional properties of natural lipids depend on the structure and composition of triacylglycerols. However, they are not always mutually compatible. Lipid modification is a good way to give them specific functionalities, increase their oxidative stability, or improve their nutritional value. As such, chemical and enzymatic interesterification may be used to modify them and produce structured lipids. In accordance, the aim of this study is to compare chemical and enzymatic interesterifi cation of binary blends of fully hydrogenated soybean oil and walnut oil, using sodium methoxide or Lipozyme TL IM, respectively, to produce a fat base with adequate nutritional and physical characteristics. Three different mass ratios of fully hydrogenated soybean oil and walnut oil blends (20:80, 40:60 and 60:40 were interesterified and evaluated. Total interesterification was determined by the stabilization of the solid fat content. Chemical reaction of the 20:80 blend was completed in 10 min and of the 40:60 and 60:40 blends in 15 min. Enzymatically interesterified blends were stabilized in 120 min at all of the mass ratios. Complete interesterification significantly reduced the solid fat content of the blends at any composition. Chemical and enzymatically interesterified fully hydrogenated blend of soybean and walnut oil at mass ratio of 40:60 showed the plastic curve of an all-purpose-type shortening rich in polyunsaturated fatty acids, with a high linolenic acid (C18:3n3 content and with zero trans-fatty acids.

  3. Efficient way of importing crude oil from oil producing countries - A review on diversification policy of crude oil import

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Dal Sok [Korea Energy Economics Institute, Euiwang (Korea)

    1999-03-01

    Since the second oil crisis, the government has operated the import diversification support program to reduce the risk of crude oil import from Middle-East region and to raise the ability of dealing with the risk. This study tried to seek policy trends in future through reviewing the market environment related to the crude oil import diversification policy and the goal, instrument and effect of the policy. The supply and demand of crude oil and the price are influenced by market system in the world oil market and there are various types of crude oil trading available to both sellers and buyers. There is a probability that the suspension of supply in a certain area could be led to the price issue rather than the physical use of crude oil. In addition, the advantage of price with long-term contract of crude oil was abolished since the price of crude oil imported by term contract has been linked to spot prices. As a result, it is shown that the potential benefit from crude oil import diversification policy is reduced although political and social insecurity still exists in Middle-East region. Therefore, it is desirable to maintain the existing support program until the amount of stored oil reaches the optimum level and to help private enterprises determine the import considering economical efficiency and risk. (author). 36 refs., 5 figs., 23 tabs.

  4. Feasibility study of heavy oil recovery in the Permian Basin (Texas and New Mexico)

    International Nuclear Information System (INIS)

    Olsen, D.K.; Johnson, W.I.

    1993-05-01

    This report is one of a series of publications assessing the feasibility of increasing domestic heavy oil production. Each report covers select areas of the United States. The Permian Basin of West Texas and Southeastern New Mexico is made up of the Midland, Delaware, Val Verde, and Kerr Basins; the Northwestern, Eastern, and Southern shelves; the Central Basin Platform, and the Sheffield Channel. The present day Permian Basin was one sedimentary basin until uplift and subsidence occurred during Pennsylvanian and early Permian Age to create the configuration of the basins, shelves, and platform of today. The basin has been a major light oil producing area served by an extensive pipeline network connected to refineries designed to process light sweet and limited sour crude oil. Limited resources of heavy oil (10'' to 20'' API gravity) occurs in both carbonate and sandstone reservoirs of Permian and Cretaceous Age. The largest cumulative heavy oil production comes from fluvial sandstones of the Cretaceous Trinity Group. Permian heavy oil is principally paraffinic and thus commands a higher price than asphaltic California heavy oil. Heavy oil in deeper reservoirs has solution gas and low viscosity and thus can be produced by primary and by waterflooding. Because of the nature of the resource, the Permian Basin should not be considered a major heavy oil producing area

  5. Used oil issues and opportunities

    International Nuclear Information System (INIS)

    Teintze, L.M.

    1992-01-01

    The authors have heard the distressing comparisons in the press: More used oil is illegally disposed of or dumped in the United States each year than the sum total of more than 35 Valdez crude spills in Alaska. 1 gallon of used oil alone has the potential to contaminate 1 million gallons of drinking water, if all used oil improperly disposed of by Do-it-Yourselfers were recycled, it could produce enough energy to power 360,000 homes each year or could provide 96 million quarts of high quality motor oil. This paper presents an overview of the used oil situation faced by the oil industry today. major issues such as the size of the problem, the current disposition of used oil, the role of the Do-it-Yourselfers, federal and state legislation, and used oil activities in foreign countries will be addressed. Likewise, the opportunities that the industry has to voluntarily and favorably respond to the used oil issues, in order to control and improve the impact on the environment, will be reviewed

  6. In vitro susceptibility of Trypanosoma brucei brucei to selected essential oils and their major components.

    Science.gov (United States)

    Costa, Sonya; Cavadas, Cláudia; Cavaleiro, Carlos; Salgueiro, Lígia; do Céu Sousa, Maria

    2018-07-01

    Aiming for discovering effective and harmless antitrypanosomal agents, 17 essential oils and nine major components were screened for their effects on T. b. brucei. The essential oils were obtained by hydrodistillation from fresh plant material and analyzed by GC and GC-MS. The trypanocidal activity was assessed using blood stream trypomastigotes cultures of T. b. brucei and the colorimetric resazurin method. The MTT test was used to assess the cytotoxicity of essential oils on macrophage cells and Selectivity Indexes were calculated. Of the 17 essential oils screened three showed high trypanocidal activity (IC 50  oils had no cytotoxic effects on macrophage cells showing the highest values of Selectivity Index (63.4, 9.0 and 11.8, respectively). The oils of Distichoselinum tenuifolium, Lavandula viridis, Origanum virens, Seseli tortuosom, Syzygium aromaticum, and Thymbra capitata also exhibited activity (IC 50 of 10-25 μg/mL) but showed cytotoxicity on macrophages. Of the nine compounds tested, α-pinene (IC 50 of 2.9 μg/mL) and citral (IC 50 of 18.9 μg/mL) exhibited the highest anti-trypanosomal activities. Citral is likely the active component of C. citratus and α-pinene is responsible for the antitrypanosomal effects of J. oxycedrus. The present work leads us to propose the J. oxycedrus, C. citratus and L. luisieri oils as valuable sources of new molecules for African Sleeping Sickness treatment. Copyright © 2018 Elsevier Inc. All rights reserved.

  7. Biotechnology of oil palm: strategies towards manipulation of lipid content and composition.

    Science.gov (United States)

    Parveez, Ghulam Kadir Ahmad; Rasid, Omar Abdul; Masani, Mat Yunus Abdul; Sambanthamurthi, Ravigadevi

    2015-04-01

    Oil palm is a major economic crop for Malaysia. The major challenges faced by the industry are labor shortage, availability of arable land and unstable commodity price. This has caused the industry to diversify its applications into higher value products besides increasing its yield. While conventional breeding has its limitations, biotechnology was identified as one of the tools for overcoming the above challenges. Research on biotechnology of oil palm began more than two decades ago leveraging a multidisciplinary approach involving biochemical studies, gene and promoter isolation, transformation vector construction and finally genetic transformation to produce the targeted products. The main target of oil palm biotechnology research is to increase oleic acid in the mesocarp. Other targets are stearic acid, palmitoleic acid, ricinoleic acid, lycopene (carotenoid) and biodegradable plastics. Significant achievements were reported for the biochemical studies, isolation of useful oil palm genes and characterization of important promoters. A large number of transformation constructs for various targeted products were successfully produced using the isolated oil palm genes and promoters. Finally transformation of these constructs into oil palm embryogenic calli was carried out while the regeneration of transgenic oil palm harboring the useful genes is in progress.

  8. A framework for the assessment of the oil price

    International Nuclear Information System (INIS)

    Oliveira, A. de; Guimaraes Lodi, C.F.

    1994-01-01

    There is a wide diversity of interpretations in the literature about the mechanisms that govern oil prices. None of them has been able to produce reasonable price forecasts. Estimates of future oil prices, or at least of a range of prices, are essential for policy-making. A better understanding of the interplay of the forces that affect oil prices is absolutely necessary. This paper aims to offer a contribution to the improvement of this understanding. It suggests a rational analytical framework to estimate the future price of oil, based on the objectives and policies of the major players in the oil market. (author)

  9. After the Gulf crisis: The third oil shock is yet to come

    International Nuclear Information System (INIS)

    Criqui, P.

    1991-01-01

    The Gulf crisis had a major impact on world oil markets: for several months the flow of oil and the capacity to produce oil in the future in several key oil-producing countries were directly or indirectly threatened. A genuine oil shock was avoided because those who are involved in oil markets and in related international organizations maintained their composure. However, an examination of market fundamentals suggests that a return to strong dependence on supplies from the Gulf is probable during this decade if the price of oil does not rise sufficiently to bring about a growth trend in oil production by non-OPEC countries consistent with growth in world oil consumption. An analysis is presented of the oil price trends prior to, during and subsequent to the Gulf crisis, and two alternative scenarios are detailed for the year 2000: sustainable vs a third oil shock. 30 refs., 6 figs., 1 tab

  10. Economics Of Small-Scale Palm Oil Processing In Ikwerre And ...

    African Journals Online (AJOL)

    Palm oil is one of the most common products used by almost everybody in Nigeria. Small holders constitute the major producers of palm oil in Ikwerre and Etche Local Government Areas. This study was conducted in Ikwerre and Etche Local Government Areas of Rivers State to determine the economic analysis of ...

  11. A cost-benefit analysis of produced water management opportunities in selected unconventional oil and gas plays

    Science.gov (United States)

    Marsters, P.; Macknick, J.; Bazilian, M.; Newmark, R. L.

    2013-12-01

    Unconventional oil and gas production in North America has grown enormously over the past decade. The combination of horizontal drilling and hydraulic fracturing has made production from shale and other unconventional resources economically attractive for oil and gas operators, but has also resulted in concerns over potential water use and pollution issues. Hydraulic fracturing operations must manage large volumes of water on both the front end as well as the back end of operations, as significant amounts of water are coproduced with hydrocarbons. This water--often called flowback or produced water--can contain chemicals from the hydraulic fracturing fluid, salts dissolved from the source rock, various minerals, volatile organic chemicals, and radioactive constituents, all of which pose potential management, safety, and public health issues. While the long-term effects of hydraulic fracturing on aquifers, drinking water supplies, and surface water resources are still being assessed, the immediate impacts of produced water on local infrastructure and water supplies are readily evident. Produced water management options are often limited to underground injection, disposal at centralized treatment facilities, or recycling for future hydraulic fracturing operations. The costs of treatment, transport, and recycling are heavily dependent on local regulations, existing infrastructure, and technologies utilized. Produced water treatment costs also change over time during energy production as the quality of the produced water often changes. To date there is no publicly available model that evaluates the cost tradeoffs associated with different produced water management techniques in different regions. This study addresses that gap by characterizing the volume, qualities, and temporal dynamics of produced water in several unconventional oil and gas plays; evaluating potential produced water management options, including reuse and recycling; and assessing how hydraulic

  12. Precipitation Chemistry and Occurrence of Acid Rain over the Oil-Producing Niger Delta Region of Nigeria

    Directory of Open Access Journals (Sweden)

    John Kanayo Chukwu Nduka

    2010-01-01

    Full Text Available This study investigated the nitrate, sulfate, total dissolved solid (TDS, electrical conductivity, total hardness (TH, and bicarbonates of rainwater samples collected from Warri and Port Harcourt between April–June, July–August, and September–October of 2005 and 2006 to depict onset of rainy season, mid-rainy season, and end of rainy season for the two major crude oil–producing cities of the Niger Delta region of Nigeria (although Port Harcourt is also noted for non-oil manufacturing industries. The same was done in Awka, a non-oil producing city in the hinterland of southeastern Nigeria. In each of the cities, rain samples were collected from three points in a triangular equilibrium using a clean plastic basin fastened to a table 2 m above ground level and 115 m away from tall buildings and trees. The parameters were determined after filtering, using their respective standard methods. Averages of 1.50, 1.81, 1.13 and 2.14, 1.50, 1.86 mg/l of nitrate for April–June, July–August, and September–October were recorded for Warri in 2005 and 2006, respectively. While 15.21, 3.23, 22.31 and 20.89, 9.96, and 14.27 mg/l were recorded in Port Harcourt. Sulfate levels for Warri and Port Harcourt for the same periods are follows: 1.38, 1.88, 1.06, 1.50, 1.43, 1.50 and 2.64, 1.15, 5.88, 4.73, 1.90, 1.55 mg/l, respectively. Nitrate levels were higher than sulfate. Other parameters include TDS (5.44, 4.79, 3.30 and 7.63, 3.69, 2.56 mg/l for Warri in 2005 and 2006; 12.57, 2.07, 25.214 and 28.87, 6.73, 7.80 mg/l for Port Harcourt for the same periods. Other parameters also varied in that order for the 2 years in same cities. Crude oil exploration and gas flaring in the Niger Delta, and multiplicity of cottage industries in Awka, impacted on the inorganic ion pollution of the rainwater. This may have public health implications in the region.

  13. Isolation of lipase producing fungi from palm oil Mill effluent (POME dump sites at Nsukka

    Directory of Open Access Journals (Sweden)

    Charles Ogugua Nwuche

    2011-02-01

    Full Text Available In this study, twelve fungal lipase producing strains belonging to Aspergillus, Penicillium, Trichoderma and Mucor genera were isolated from palm oil mill effluent composts. The Aspergillus spp. were more frequent (42% and was present in all the samples assayed. Mucor sp. was the least encountered (8.3%.The lipase producing profile showed that Trichoderma (8.07-8.24 u/mL and Aspergillus (6.25 -7.54 u/mL spp. were the highest lipase producers while Mucor (5.72 u/mL was the least.

  14. Development of More Effective Biosurfactants for Enhanced Oil Recovery/Advanced Recovery Concepts Awards

    Energy Technology Data Exchange (ETDEWEB)

    McInerney, M.J.; Marsh, T.L.; Zhang, X.; Knapp, R.M.; Nagle, Jr., D.P.; Sharma, P.K.; Jackson, B.E.

    2002-05-28

    The objectives of this were two fold. First, core displacement studies were done to determine whether microbial processes could recover residual oil at elevated pressures. Second, the importance of biosurfactant production for the recovery of residual oil was studies. In these studies, a biosurfactant-producing, microorganisms called Bacillus licheniformis strain JF-2 was used. This bacterium produces a cyclic peptide biosurfactant that significantly reduces the interfacial tension between oil and brine (7). The use of a mutant deficient in surfactant production and a mathematical MEOR simulator were used to determine the major mechanisms of oil recovery by these two strains.

  15. Shale-oil-derived additives for fuel oils

    International Nuclear Information System (INIS)

    Raidma, E.; Leetsman, L.; Muoni, R.; Soone, Y.; Zhiryakov, Y.

    2002-01-01

    Studies have shown that the oxidation, wearing, and anticorrosive properties of shale oil as an additive to liquid fuels and oils enable to improve the conditions of their use. Studies conducted by Institute of Oil Shale have shown that it is possible, on the basis of shale oil produced by Viru Keemia Grupp AS (Viru Chemistry Group Ltd.) and, particularly, on the basis of its fractions 230-320 and 320-360 deg C to produce efficient and stable additives for liquid fuels to improve their combustion and storage properties. In the production of additives from shale oil the prerequisite taken into account is its complexity of composition and high concentration of neutral and phenolic oxygen compounds. Additives produced from shale oil have multifunctional properties which enable to improve operational data of liquid fuels and to increase the power of diesel engines and boilers. (author)

  16. Heavy oils clean up

    International Nuclear Information System (INIS)

    Collitt, R.

    1997-01-01

    High production, transport and refining costs have long led oil companies to shun heavy crude oils. Advances in the technology of upgrading heavy oils, however, are likely to reduce transport costs and improve the refinery output. Research and development by Venezuela's state oil company, Petroleos de Venezuela (PDVSA), has resulted in a process called Aquaconversion which permits the upgrading of heavy crude oils using a catalyst and the hydrogen from steam. This may be carried out at the wellhead in small low-pressure and relatively inexpensive units. In addition, higher distillate yields of higher value could be produced by revamping the thermal cracking units of refineries to incorporate the new technology. This has generated considerable interest in Venezuela's large extra-heavy crude oil reserves and has led multinational oil companies along with PDVSA to pledge $17 billion to their development. Even at a $2 to $3 per barrel upgrading cost, Venezuela's extra heavy crudes are competitive with lighter oils from other countries. Other major markets for the new technology are likely to be China and Russia, given their own large heavy crude reserves. (UK)

  17. Special report: EC oil market

    International Nuclear Information System (INIS)

    Anon.

    1992-01-01

    A European Commission report on the EC's oil market has conceded that the Community will not meet its official objective of reducing oil's share of energy consumption to 40% by 1995. The paper, a 'Communication' to the European Council entitled ''The Oil Market and the Refining Industry in the Community: Recent Developments and Prospects'' says oil will ''continue to account for a major share - of the order of 45% -of the Community's energy consumption'' up to the year 2000. Nonetheless, the report's authors insist the Commission has proposed ''a number of measures'' which could reduce the potential consumption of fossil fuels and help limit CO2 emissions. The report confirms that though lower in 1990 than 1980 at 530mt, oil demand picked up in the second half of the 1980s, reflecting world trends. Little impression has been made on the proportion of the Community's crude supply that is imported. However, one area where the report did find energy objectives successes was that of diversifying sources of crude oil supply. A major source of concern for the Commission at one stage in the second half of the 1980s was the possibility of massive imports of finished oil products from refineries in the oil producing countries. However, the fact that this threat did not materialise is taken as a vindication of the Commission's assessment in previous analyses that ''an open Community market should be maintained''. (author)

  18. Essential oil composition of Lavandula angustifolia Mill. cultivated in the mid hills of Uttarakhand, India

    Directory of Open Access Journals (Sweden)

    RAM S. VERMA

    2010-03-01

    Full Text Available The essential oil content in the inflorescence of lavender (Lavandula angustifolia Mill. cultivated in the mid hills of Uttarakhand was found to be 2.8 % based on the fresh weight. The oil was analysed by capillary GC and GC–MS. Thirty seven constituents, representing 97.81 % of the oil were identified. The major components of the oil were linalyl acetate (47.56 %, linalool (28.06 %, lavandulyl acetate (4.34 % and α-terpineol (3.75 %. The quality of lavender oil produced in India was found to be comparable to that produced in Hungary, France, China, Bulgaria, Russia and the USA.

  19. ANAEROBIC BIOLOGICAL TREATMENT OF PRODUCED WATER

    Energy Technology Data Exchange (ETDEWEB)

    John R. Gallagher

    2001-07-31

    During the production of oil and gas, large amounts of water are brought to the surface and must be disposed of in an environmentally sensitive manner. This is an especially difficult problem in offshore production facilities where space is a major constraint. The chief regulatory criterion for produced water is oil and grease. Most facilities have little trouble meeting this criterion using conventional oil-water separation technologies. However, some operations have significant amounts of naphthenic acids in the water that behave as oil and grease but are not well removed by conventional technologies. Aerobic biological treatment of naphthenic acids in simulated-produced water has been demonstrated by others; however, the system was easily overloaded by the large amounts of low-molecular-weight organic acids often found in produced waters. The objective of this research was to determine the ability of an anaerobic biological system to treat these organic acids in a simulated produced water and to examine the potential for biodegradation of the naphthenic acids in the anaerobic environment. A small fixed-film anaerobic biological reactor was constructed and adapted to treat a simulated produced water. The bioreactor was tubular, with a low-density porous glass packing material. The inocula to the reactor was sediment from a produced-water holding pond from a municipal anaerobic digester and two salt-loving methanogenic bacteria. During start-up, the feed to the reactor contained glucose as well as typical produced-water components. When glucose was used, rapid gas production was observed. However, when glucose was eliminated and the major organic component was acetate, little gas was generated. Methane production from acetate may have been inhibited by the high salt concentrations, by sulfide, or because of the lack, despite seeding, of microbes capable of converting acetate to methane. Toluene, a minor component of the produced water (0.1 g/L) was removed in the

  20. Characterization and Performance Test of Palm Oil Based Bio-Fuel Produced Via Ni/Zeolite-Catalyzed Cracking Process

    Directory of Open Access Journals (Sweden)

    Sri Kadarwati

    2015-02-01

    Full Text Available Catalytic cracking process of palm oil into bio-fuel using Ni/zeolite catalysts (2-10% wt. Ni at various reaction temperatures (400-500oC in a flow-fixed bed reactor system has been carried out. Palm oil was pre-treated to produce methyl ester of palm oil as feedstock in the catalytic cracking reactions. The Ni/zeolite catalysts were prepared by wetness impregnation method using Ni(NO32.6H2O as the precursor. The products were collected and analysed using GC, GC-MS, and calorimeter. The effects of process temperatures and Ni content in Ni/zeolite have been studied. The results showed that Ni-2/zeolite could give a yield of 99.0% at 500oC but only produced gasoline fraction of 18.35%. The physical properties of bio-fuel produced in this condition in terms of density, viscosity, flash point, and specific gravity were less than but similar to commercial fuel. The results of performance test in a 4-strike engine showed that the mixture of commercial gasoline (petrol and bio-fuel with a ratio of 9:1 gave similar performance to fossil-based gasoline with much lower CO and O2 emissions and more efficient combustion

  1. Support of enhanced oil recovery to independent producers in Texas. Quarterly technical progress report, July 1, 1995--September 30, 1995

    Energy Technology Data Exchange (ETDEWEB)

    Fotouh, K.H.

    1995-09-30

    The main objective of this project is to support independent oil producers in Texas and to improve the productivity of marginal wells utilizing enhanced oil recovery techniques. The main task carried out this quarter was the generation of an electronic data base.

  2. SAGD pilot project, wells MFB-772 (producer) / MFB-773 (injector), U1,3 MFB-53 reservoir, Bare Field. Orinoco oil belt. Venezuela

    Energy Technology Data Exchange (ETDEWEB)

    Mago, R.; Franco, L.; Armas, F.; Vasquez, R.; Rodriguez, J.; Gil, E. [PDVSA EandP (Venezuela)

    2011-07-01

    In heavy oil and extra heavy oil fields, steam assisted gravity drainage is a thermal recovery method used to reduce oil viscosity and thus increase oil recovery. For SAGD to be successfully applied in deep reservoirs, drilling and completion of the producer and injector wells are critical. Petroleos de Venezuela SA (PDVSA) is currently assessing the feasibility of SAGD in the Orinoco oil belt in Venezuela and this paper aims at presenting the methodology used to ensure optimal drilling and completion of the project. This method was divided in several stages: planning, drilling and completion of the producer, injector and then of the observer wells and cold information capture. It was found that the use of magnetic guidance tools, injection pipe pre-insulated and pressure and temperature sensors helps optimize the drilling and completion process. A methodology was presented to standardize operational procedures in the drilling and completion of SAGD projects in the Orinoco oil belt.

  3. An overview of empty fruit bunch from oil palm as feedstock for bio-oil production

    International Nuclear Information System (INIS)

    Chang, Siu Hua

    2014-01-01

    Empty fruit bunch (EFB) from oil palm is one of the potential biomass to produce biofuels like bio-oil due to its abundant supply and favorable physicochemical characteristics. Confirming the assertion, this paper presents an overview of EFB as a feedstock for bio-oil production. The fundamental characteristics of EFB in terms of proximate analysis, ultimate analysis and chemical composition, as well as the recent advances in EFB conversion processes for bio-oil production like pyrolysis and solvolysis are outlined and discussed. A comparison of properties in terms of proximate analysis, ultimate analysis and fuel properties between the bio-oil from EFB and petroleum fuel oil is included. The major challenges and future prospects towards the utilization of EFB as a useful resource for bio-oil production are also addressed. - Highlights: • Palm EFB has high heating value and low greenhouse gas emissions during combustion. • Conversion of EFB to bio-oil is mainly by fast pyrolysis without and with catalyst. • Bio-oil from EFB is lower in heating value, heavier and more acidic than fuel oil. • The viscosity of bio-oil from EFB is between those of light and heavy fuel oils. • The flash and pour points of bio-oil from EFB are close to those of light fuel oil

  4. Biological treatment process for removing petroleum hydrocarbons from oil field produced waters

    Energy Technology Data Exchange (ETDEWEB)

    Tellez, G.; Khandan, N.

    1995-12-31

    The feasibility of removing petroleum hydrocarbons from oil fields produced waters using biological treatment was evaluated under laboratory and field conditions. Based on previous laboratory studies, a field-scale prototype system was designed and operated over a period of four months. Two different sources of produced waters were tested in this field study under various continuous flow rates ranging from 375 1/D to 1,800 1/D. One source of produced water was an open storage pit; the other, a closed storage tank. The TDS concentrations of these sources exceeded 50,000 mg/l; total n-alkanes exceeded 100 mg/l; total petroleum hydrocarbons exceeded 125 mg/l; and total BTEX exceeded 3 mg/l. Removals of total n-alkanes, total petroleum hydrocarbons, and BTEX remained consistently high over 99%. During these tests, the energy costs averaged $0.20/bbl at 12 bbl/D.

  5. Investigation of bio-oil produced by hydrothermal liquefaction of food waste using ultrahigh resolution Fourier transform ion cyclotron resonance mass spectrometry.

    Science.gov (United States)

    Kostyukevich, Yury; Vlaskin, Mikhail; Borisova, Ludmila; Zherebker, Alexander; Perminova, Irina; Kononikhin, Alexey; Popov, Igor; Nikolaev, Eugene

    2018-02-01

    Recent research has revealed that more than 1.3 billion tons of food is wasted globally every year. The disposal of such huge biomass has become a challenge. In the present paper, we report the production of the bio-oil by hydrothermal liquefaction of three classes of food waste: meat, cheese and fruits. The highest yield of the bio-oil was observed for meat (∼60%) and cheese (∼75%), while for fruits, it was considerably low (∼10%). The molecular composition of the obtained bio-oil was investigated using ultrahigh resolution Fourier Transform Ion Cyclotron Resonance mass spectrometry and was found to be similar to that obtained from algae. Several thousand heteroatom compounds (N, N 2 , ON 2 , etc. classes) were reliably identified from each sample. It was found that bio-oils produced from meat and cheese have many compounds (∼90%) with common molecular formulas, while bio-oil produced from fruits differs considerably (∼30% of compounds are unique).

  6. Antioxidant Activity of the Essential Oil and its Major Terpenes of Satureja macrostema (Moc. and Sessé ex Benth.) Briq.

    Science.gov (United States)

    Torres-Martínez, Rafael; García-Rodríguez, Yolanda Magdalena; Ríos-Chávez, Patricia; Saavedra-Molina, Alfredo; López-Meza, Joel Edmundo; Ochoa-Zarzosa, Alejandra; Garciglia, Rafael Salgado

    2018-01-01

    The aim of this study was to investigate the in vitro antioxidant activity of Satureja macrostema (Moc. and Sessé ex Benth.) Briq. (Lamiaceae) essential oil, a Mexican medicinal plant known as nurite. Fresh aerial parts of S. macrostema plants cultivated in greenhouse for 3 months were subjected to hydrodistillation in a Clevenger apparatus to obtain essential oil. Volatile compounds were identified by gas chromatography (GC) and GC/mass spectrometry. Antioxidant effectiveness of essential oil and its major terpenes of S. macrostema was examined by three different radical scavenging methods: 2,2-diphenyl-1-picrylhydrazyl (DPPH), 2,2'-azinobis-3-ethylbenzothiazoline-6-sulfonic acid (ABTS), and total antioxidant capacity (TAC). The concentrations tested were 0.001, 0.01, 0.1, and 1 mg/mL. The major volatile compounds were caryophyllene, limonene, linalool, pulegone, menthone, and thymol. S. macrostema essential oil showed the highest free radical scavenging activity with DPPH and ABTS methods (53.10% and 92.12%, respectively) at 1 mg/mL and 98% with TAC method at 0.1 mg/mL. Thymol exerted the highest antioxidant capacity with 0.1 mg/mL, reaching 83.38%, 96.96%, and 98.57% by DPPH, ABTS, and TAC methods. Caryophyllene, limonene, linalool, pulegone, and menthone exhibited an antioxidant capacity essential oil of S. macrostema and thymol showed a free radical scavenging activity close to that of the synthetic butylated hydroxytoluene. The major volatile compounds of essential oil of Satureja macrostema were caryophyllene, limonene, linalool, pulegone, menthone and thymolThe essential oil of S. macrostema showed a high free radical scavengingThymol exerted the highest antioxidant capacity by DPPH, ABTS and TAC methods. Abbreviations used: GC: Gas Chromatography; DPPH: 2,2-diphenyl-1-picrylhydrazyl; ABTS: 2,2'-azino-bis-3-ethylbenzothiazoline-6-sulfonic acid; TAC: Total antioxidant capacity.

  7. Health promoting effects of phytonutrients found in palm oil.

    Science.gov (United States)

    Loganathan, R; Selvaduray, K R; Nesaretnam, K; Radhakrishnan, A K

    2010-08-01

    The oil palm tree, Elaeis guineesis, is the source of palm oil, otherwise known as the "tropical golden oil". To date, Malaysia and Indonesia are the leading producers of palm oil. Palm oil is widely used for domestic cooking in Malaysia. Palm oil is a rich source of phytonutrients such as tocotrienols, tocopherol, carotene, phytosterols, squalene, coenzyme Q10, polyphenols, and phospholipids. Although the phytonutrients constitute only about 1% of its weight in crude palm oil, these are the main constituents through which palm oil exhibits its nutritional properties. Among the major health promoting properties shown to be associated with the various types of phytonutrients present in palm oil are anti-cancer, cardio-protection and anti-angiogenesis, cholesterol inhibition, brain development and neuro protective properties, antioxidative defence mechanisms, provitamin A activity and anti-diabetes.

  8. Development of More Effective Biosurfactants for Enhanced Oil Recovery/Advanced Recovery Concepts Awards; SEMIANNUAL

    International Nuclear Information System (INIS)

    McInerney, M.J.; Marsh, T.L.; Zhang, X.; Knapp, R.M.; Nagle, Jr. D.P.; Sharma, P.K.; Jackson, B.E.

    2002-01-01

    The objectives of this were two fold. First, core displacement studies were done to determine whether microbial processes could recover residual oil at elevated pressures. Second, the importance of biosurfactant production for the recovery of residual oil was studies. In these studies, a biosurfactant-producing, microorganisms called Bacillus licheniformis strain JF-2 was used. This bacterium produces a cyclic peptide biosurfactant that significantly reduces the interfacial tension between oil and brine (7). The use of a mutant deficient in surfactant production and a mathematical MEOR simulator were used to determine the major mechanisms of oil recovery by these two strains

  9. Physico-chemical characteristics of oil produced from seeds of some date palm cultivars (Phoenix dactylifera L.) .

    Science.gov (United States)

    Soliman, S S; Al-Obeed, R S; Ahmed, T A

    2015-03-01

    The oil content of saturated and unsaturated fatty acids with some physico-chemical properties and nutrients were investigated in oil produced from seeds of six important date palm cultivars and one seed strain present in Saudi Arabia. The results indicated that the oil extracted from six seed cultivars of date palm ranged from 6.73-10.89% w/w oil. The refractive index of date seeds oil was found to be between 1.4574 to 1.4615. The iodine values, acid values and saponification values were in the range of 74.2-86.6 g iodine 100 g(-1); 2.50-2.58 mg KOH g(-1) and 0.206-0.217 mg KOH g(-1), respectively. Lauric acid, Myristic acid, Palmitic acid C15, Palmitic acid C16 Stearic acid, Arachidic acid and Behenic acid of date seeds oil contents were found between 8.67-49.27; 7.01-15.43; 0-0.57; 4.82-18.09; 1.02-7.86; 0-0.08; and 0-0.15% w/w, in that order. Omega-6 and Omega-9 of date seeds oil were found between 7.31-17.87 and 52.12-58.78%, respectively. Khalas, Barhy cvs. and seed strain gave highest K and Ca, Na and Fe, Mg as compared with other studied cultivars.

  10. Past, Present, and Future Production of Bio-oil

    Energy Technology Data Exchange (ETDEWEB)

    Steele, Philip; Yu, Fei; Gajjela, Sanjeev

    2009-04-01

    have developed means to increase the anhydrosugars content of bio-oil above the usual 3% produced during normal pyrolysis by mild acid pretreatment of the biomass feedstock. Mississippi State University has developed a proprietary method to produce an aqueous fraction containing more than 50% of anhydrosugars content. These anhydrosugars can be catalyzed to hydrogen or hydrocarbons; alter-nately, the aqueous fraction can be hydrolyzed to pro-duce a high-glucose content. The hydrolyzed product can then be filtered to remove microbial inhibitor compounds followed by production of alcohols by fer-mentation. Production of bio-oil is now considered a major candidate as a technology promising production of drop-in transportation and boiler fuels.

  11. Upstream oil and gas. Subsector no. 7: Oil and gas exploration and development 1995 to 1999

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-08-01

    Prepared by the Alberta Human Resources and Employment, this report provides a summary of the lost-time injuries and disease descriptions of workers injured while employed in the upstream oil and gas industries in Alberta during the period 1995 to 1999. The report includes the characteristics of the injured worker and the risk of injury to workers in the industries in Alberta, as well as the cost of injuries and revenue by means of total premiums paid by the employers. The occupational fatalities that were accepted by the Workers Compensation Board and investigated by the Occupational Health and Safety were summarized in the report along with a brief description of the injuries. The aim was to provide information concerning health and safety issues to government, employers, workers, and health and safety officers in the industries in Alberta about health and safety issues. The focus was placed on the oil and gas exploration and development sub-sector. Defined as all upstream oil field activities of employers which generate revenue from the production and sale of crude oil and/or natural gas, the sub-sector comprises major integrated oil and gas companies and small independent producers. In those cases where the owner/producer operates its own upstream production/processing facilities, they form an integral part of this sub-section. In addition, oil and gas marketing firms are included. Oil/gas well, well head equipment; flow lines/gathering systems tied into field processing facilities; battery sites/compressors stations; crude oil separators and natural gas dehydrators/treaters; natural gas/sulfur processing plants; heavy oil projects including steam generation; and other enhanced recovery methods are all included in the sub-sector. The other sub-sectors in the upstream oil and gas industries are: exploration, oilfield maintenance and construction, well servicing with service rigs and power swivels, drilling of oil and gas wells, oilfield downhole and other

  12. Oil Producers vulnerability: restrictions for oil supply strategy - OPEC, Mexico and Norway; Indicadores de vulnerabilidade do produtor de petroleo: restricoes a estrategia de oferta - OPEP, Mexico and Norway

    Energy Technology Data Exchange (ETDEWEB)

    Delgado, Fernanda; Schaeffer, Roberto; Szklo, Alexandre [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Coordenacao dos Programas de Pos-Graduacao de Engenharia (COPPE)

    2008-07-01

    Few analysts address the socio-economic vulnerability faced by large oil producers countries that restricts their oil supply strategies. However, such as net import countries may be vulnerable to oil supply, large oil exporters countries may also become vulnerable due to their socio-economic dependence on oil, as export revenues are so important to their wealth generation and their populations' well-fare status. The objective of this paper is to evaluate the vulnerabilities of some oil exporters as the OPEC's member-countries, Mexico and Norway face, or may face, and that may restrict their degree of freedom for productive decision making (including investments) and for elaborating oil supply strategies (aiming at taking a larger share of the oil revenue). In order to do that this paper is divided in 3 sections. Initially, socio-economic vulnerability indicators for the oil exporting countries are presented, built and analyzed. Socio-economic vulnerability indicators comprehend, for instance, the following dimensions: physical, productive, fiscal, commercial, macroeconomic and social. The next section regards the application of a multi criteria method, the AHP - Analytic Hierarchy Process in order to summarize and organize the indicators. Finally, implications of the socio-economic vulnerabilities of these oil export countries for the world oil supply and price are derived. (author)

  13. The economic impact of oil prices

    International Nuclear Information System (INIS)

    Krymm, R.

    1974-01-01

    During the last three months of 1973, the tax-paid costs of typical grades of crude petroleum in the main producing areas of the world, around the Persian Gulf, were roughly quadrupled, rising for typical Iranian and Arabian Ugh t crudes from about $1.85 per barrel in September 1973 to more than $7.00 by 1 January 1974, or from approximately $13.30 to more than $50.00 per ton. Since the cost of production represents an insignificantly small fraction of the new cost level (less than 2%) and subject to complex adjustments reflecting varying qualities of crude oils and advantages of geographical location, the producing countries may expect to receive a minimum average revenue of $50.00 per ton of crude oil produced on their territory instead of $12.50. If we ignore the purchases which carried the prices of relatively small amounts of oil to the $100-$150 range, this figure of $50.00 per ton with future adjustments for inflation represents a probable guide line for future cost estimates. The change affects exports of close to 1.4 billion tons of oil and consequently involves an immediate shift of financial resources of close to 60 billion dollars per year from the oil-consuming to the oil-producing countries. Tables 1, 2 and 3 give an idea of the distribution of this burden by main geographical regions and of its possible evolution over the next seven years. The figures involved are so large that comparisons have been made by some authors with the reparations proposals advanced by the Allies at the end of the First World War. It has been pointed out that the market price of a typical quality of crude such as Arabian light had in fact fallen from $1.93 per barrel in 1955 to $1.26 in 1970. When the intervening industrial price inflation is taken into account this means that the price of oil had in fact been divided by 3 during a period when oil consumption was growing at an annual rate of more than 7% and oil was displacing coal as the major fuel of the world. During the

  14. Hyperspectral imaging of oil producing microalgae under thermal and nutritional stress.

    Energy Technology Data Exchange (ETDEWEB)

    Van Benthem, Mark Hilary; Davis, Ryan W.; Ricken, James Bryce; Powell, Amy Jo; Keenan, Michael Robert

    2008-09-01

    This short-term, late-start LDRD examined the effects of nutritional deprivation on the energy harvesting complex in microalgae. While the original experimental plan involved a much more detailed study of temperature and nutrition on the antenna system of a variety of TAG producing algae and their concomitant effects on oil production, time and fiscal constraints limited the scope of the study. This work was a joint effort between research teams at Sandia National Laboratories, New Mexico and California. Preliminary results indicate there is a photosystem response to silica starvation in diatoms that could impact the mechanisms for lipid accumulation.

  15. 30 CFR 250.1157 - How do I receive approval to produce gas-cap gas from an oil reservoir with an associated gas cap?

    Science.gov (United States)

    2010-07-01

    ... 30 Mineral Resources 2 2010-07-01 2010-07-01 false How do I receive approval to produce gas-cap gas from an oil reservoir with an associated gas cap? 250.1157 Section 250.1157 Mineral Resources... do I receive approval to produce gas-cap gas from an oil reservoir with an associated gas cap? (a...

  16. Melittin, the Major Pain-Producing Substance of Bee Venom.

    Science.gov (United States)

    Chen, Jun; Guan, Su-Min; Sun, Wei; Fu, Han

    2016-06-01

    Melittin is a basic 26-amino-acid polypeptide that constitutes 40-60% of dry honeybee (Apis mellifera) venom. Although much is known about its strong surface activity on lipid membranes, less is known about its pain-producing effects in the nervous system. In this review, we provide lines of accumulating evidence to support the hypothesis that melittin is the major pain-producing substance of bee venom. At the psychophysical and behavioral levels, subcutaneous injection of melittin causes tonic pain sensation and pain-related behaviors in both humans and animals. At the cellular level, melittin activates primary nociceptor cells through direct and indirect effects. On one hand, melittin can selectively open thermal nociceptor transient receptor potential vanilloid receptor channels via phospholipase A2-lipoxygenase/cyclooxygenase metabolites, leading to depolarization of primary nociceptor cells. On the other hand, algogens and inflammatory/pro-inflammatory mediators released from the tissue matrix by melittin's pore-forming effects can activate primary nociceptor cells through both ligand-gated receptor channels and the G-protein-coupled receptor-mediated opening of transient receptor potential canonical channels. Moreover, subcutaneous melittin up-regulates Nav1.8 and Nav1.9 subunits, resulting in the enhancement of tetrodotoxin-resistant Na(+) currents and the generation of long-term action potential firing. These nociceptive responses in the periphery finally activate and sensitize the spinal dorsal horn pain-signaling neurons, resulting in spontaneous nociceptive paw flinches and pain hypersensitivity to thermal and mechanical stimuli. Taken together, it is concluded that melittin is the major pain-producing substance of bee venom, by which peripheral persistent pain and hyperalgesia (or allodynia), primary nociceptive neuronal sensitization, and CNS synaptic plasticity (or metaplasticity) can be readily induced and the molecular and cellular mechanisms

  17. Prospects for non-OPEC oil supply

    International Nuclear Information System (INIS)

    O'Dell, S.

    1994-01-01

    An International Energy Agency forecast is provided of non-OPEC oil production over a 15-year horizon. Reference-case forecasts are derived from Hubbert-type resource models, official industry announcements about such matters as oil discoveries and development projects, and an oil industry consensus. Separate regional profiles are provided for North America, Europe, the former Soviet Union, and the rest of non-OPEC countries (South America, Asia, non-OPEC Middle East). Under a flat-price scenario ($18/bbl), total non-OPEC oil supply rises slightly from 41.4 million bbl/d (MBD) in 1995 to 41.9 MBD in 2010. Under a scenario in which prices rise to $28/bbl, oil supply rises to 47.5 MBD in 2010. The latter results depend on specific assumptions concerning economic growth, energy prices, the geological potential of some areas which are not yet well understood, technological advances, and the nature of political developments. Uncertainties regarding these assumptions are discussed, with reference to reserves, price responsiveness, world oil industry investment, technology, and costs. A major uncertainty is the issue of investment in the OPEC countries, since the rising-price scenario assumes that OPEC invests only reluctantly. If major OPEC producers choose to open their upstream sectors to international oil companies, the situation will change completely. Otherwise, oil markets are expected to continue to behave in the manner of the past 20 years, with highest-cost oil being developed first while cheaper oil remains in the ground. 8 refs., 10 figs., 3 tabs

  18. Asymmetric membranes for destabilization of oil droplets in produced water from alkaline-surfactant-polymer (ASP) flooding

    Science.gov (United States)

    Ramlee, Azierah; Chiam, Chel-Ken; Sarbatly, Rosalam

    2018-05-01

    This work presents a study of destabilization of oil droplets in the produced water from alkaline-surfactant-polymer (ASP) flooding by using four types of laboratory-fabricated polyvinylidene fluoride (PVDF) membranes. The PVDF membranes were fabricated via immersion precipitation method with ethanol (0 - 30 %, v/v) as the coagulant. The membranes with the effective area of 17.35 cm2 were tested with synthesized ASP solution as the feed in cross-flow microfiltration process. The ASP feed solution initially contained the oil droplets with radius ranged from 40 to 100 nm and the mean radius was 61 nm. Results have shown that the concentration of the ethanol in the coagulation bath affects the formation of the membrane structure and the corresponding porosity, while no significance influence on the membrane thickness. Coalescence of the oil droplets was occurred when the ASP solution permeated through the asymmetric PVDF membranes. Through the coalescence process, the oil droplets were destabilized where the radius of the oil droplets in the permeates increased to 1.5-4 µm with the corresponding mean radius ranged from 2.4 to 2.7 µm.

  19. Innovating a system for producing and distributing hybrid oil palm seedlings to smallholder farmers in Benin

    NARCIS (Netherlands)

    Vissoh, Pierre V.; Tossou, Rigobert C.; Akpo, Essegbemon; Kossou, Dansou; Jiggins, Janice

    2017-01-01

    This article analyses the development of a system for producing and distributing hybrid oil palm seedlings to small-scale famers. The existing seed system had become so corrupted that the seedlings actually planted were largely of unimproved kinds. The article describes institutional experiments

  20. ANAEROBIC BIOLOGICAL TREATMENT OF PRODUCED WATER; TOPICAL

    International Nuclear Information System (INIS)

    John R. Gallagher

    2001-01-01

    During the production of oil and gas, large amounts of water are brought to the surface and must be disposed of in an environmentally sensitive manner. This is an especially difficult problem in offshore production facilities where space is a major constraint. The chief regulatory criterion for produced water is oil and grease. Most facilities have little trouble meeting this criterion using conventional oil-water separation technologies. However, some operations have significant amounts of naphthenic acids in the water that behave as oil and grease but are not well removed by conventional technologies. Aerobic biological treatment of naphthenic acids in simulated-produced water has been demonstrated by others; however, the system was easily overloaded by the large amounts of low-molecular-weight organic acids often found in produced waters. The objective of this research was to determine the ability of an anaerobic biological system to treat these organic acids in a simulated produced water and to examine the potential for biodegradation of the naphthenic acids in the anaerobic environment. A small fixed-film anaerobic biological reactor was constructed and adapted to treat a simulated produced water. The bioreactor was tubular, with a low-density porous glass packing material. The inocula to the reactor was sediment from a produced-water holding pond from a municipal anaerobic digester and two salt-loving methanogenic bacteria. During start-up, the feed to the reactor contained glucose as well as typical produced-water components. When glucose was used, rapid gas production was observed. However, when glucose was eliminated and the major organic component was acetate, little gas was generated. Methane production from acetate may have been inhibited by the high salt concentrations, by sulfide, or because of the lack, despite seeding, of microbes capable of converting acetate to methane. Toluene, a minor component of the produced water (0.1 g/L) was removed in the

  1. A review on risk assessment techniques for hydraulic fracturing water and produced water management implemented in onshore unconventional oil and gas production.

    Science.gov (United States)

    Torres, Luisa; Yadav, Om Prakash; Khan, Eakalak

    2016-01-01

    The objective of this paper is to review different risk assessment techniques applicable to onshore unconventional oil and gas production to determine the risks to water quantity and quality associated with hydraulic fracturing and produced water management. Water resources could be at risk without proper management of water, chemicals, and produced water. Previous risk assessments in the oil and gas industry were performed from an engineering perspective leaving aside important social factors. Different risk assessment methods and techniques are reviewed and summarized to select the most appropriate one to perform a holistic and integrated analysis of risks at every stage of the water life cycle. Constraints to performing risk assessment are identified including gaps in databases, which require more advanced techniques such as modeling. Discussions on each risk associated with water and produced water management, mitigation strategies, and future research direction are presented. Further research on risks in onshore unconventional oil and gas will benefit not only the U.S. but also other countries with shale oil and gas resources. Copyright © 2015 Elsevier B.V. All rights reserved.

  2. Isotope and chemical investigation of geothermal springs and thermal water produced by oil wells in potwat area, Pakistan

    International Nuclear Information System (INIS)

    Ahmad, M.; Rafique, M.; Tariq, J.A; Choudhry, M.A.; Hussain, Q.M.

    2008-10-01

    Isotopes and geochemical techniques were applied to investigate the origin, subsurface history and reservoir temperatures of geothermal springs in Potwar. Two sets of water samples were collected. Surface temperatures of geothermal springs ranges from 52 to 68.3 C. Waters produced by oil wells in Potwar area were also investigated. Geothermal springs of Potwar area are Na-HCO/sub 3/ type, while the waters produced by oil wells are Na-Cl and Ca-Cl types. Source of both the categories of water is meteoric water recharged from the outcrops of the formations in the Himalayan foothills. These waters undergo very high /sup 18/O-shift (up to 18%) due to rock-water interaction at higher temperatures. High salinity of the oil field waters is due to dissolution of marine evaporites. Reservoir temperatures of thermal springs determined by the Na-K geo thermometers are in the range of 56-91 deg. C, while Na-K-Ca, Na-K-Mg, Na-K-Ca-Mg and quartz geo thermometers give higher temperatures up to 177 C. Reservoir temperature determined by /sup 18/O(SO/Sub 4/-H/sub 2/O) geo thermometer ranges from 112 to 138 deg. C. There is wide variation in reservoir temperatures (54-297 deg. C) of oil fields estimated by different chemical geo thermometers. Na-K geo thermometer seems more reliable which gives close estimates to real temperature (about 100 deg. C) determined during drilling of oil wells. (author)

  3. Oil palm land conversion in Pará, Brazil, from 2006-2014: evaluating the 2010 Brazilian Sustainable Palm Oil Production Program

    Science.gov (United States)

    Benami, E.; Curran, L. M.; Cochrane, M.; Venturieri, A.; Franco, R.; Kneipp, J.; Swartos, A.

    2018-03-01

    Global models of biophysical suitability for oil palm consistently rank Brazil as having the greatest potential for expansion, with estimates as high as 238 Mha of suitable lands. In 2010, Brazil launched the Sustainable Palm Oil Production Program (SPOPP) to incentivize oil palm development without deforestation on as much as 30 Mha. Here we examine oil palm expansion before and after the SPOPP’s launch. In Pará, the major oil palm producing state in Brazil, we analyze the extent and change in oil palm cultivation from 2006-2014 using satellite imagery, ground-truthed verification, site-based interviews, and rural environmental (land) registration data. Between 2006-2014, oil palm area (≥9 ha) expanded >200% to ~219 000 ha. Of the ~148 000 ha of oil palm developed, ~91% converted pasturelands while ~8% replaced natural vegetation, including intact and secondary forests. Although >80% of all oil palm parcels rest role of agro-ecological suitability mapping among them. Interviews indicated that: (1) individual effects of suitability mapping efforts to encourage oil palm expansion on cleared areas, i.e. without deforestation, cannot be disentangled from pre-existing public and private deforestation reduction initiatives; and, (2) socio-economic constraints, e.g. high relative production costs and limited familiarity with this crop, appear to partially explain the major discrepancy between estimated potential suitable areas with realized oil palm development.

  4. Challenges and issues concerning mycotoxins contamination in oil seeds and their edible oils: Updates from last decade.

    Science.gov (United States)

    Bhat, Rajeev; Reddy, Kasa Ravindra Nadha

    2017-01-15

    Safety concerns pertaining towards fungal occurrence and mycotoxins contamination in agri-food commodities has been an issue of high apprehension. With the increase in evidence based research knowledge on health effects posed by ingestion of mycotoxins-contaminated food and feed by humans and livestock, concerns have been raised towards providing more insights on screening of agri-food commodities to benefit consumers. Available reports indicate majority of edible oil-yielding seeds to be contaminated by various fungi, capable of producing mycotoxins. These mycotoxins can enter human food chain via use of edible oils or via animals fed with contaminated oil cake residues. In this review, we have decisively evaluated available data (from the past decade) pertaining towards fungal occurrence and level of mycotoxins in various oil seeds and their edible oils. This review can be of practical use to justify the prevailing gaps, especially relevant to the research on presence of mycotoxins in edible plant based oils. Copyright © 2016 Elsevier Ltd. All rights reserved.

  5. Maximization of Egyptian Gas Oil Production Through the Optimal Use of the Operating Parameters

    International Nuclear Information System (INIS)

    Marawan, H.

    2004-01-01

    Gas oil is the major fossil fuel consumed around the world. Global gas oil consumption is rising at a steadily fast pace because of its higher combustion efficiency (versus gasoline). The annual increase rate of gas oil consumption in Egypt is 7 % whereas, the world increase rates range from 1.5 % to 2 % . The main sources for producing gas oil in Egypt refiners is the direct production from the atmospheric distillation process units or it may be produced as a side product from vacuum distillation units . Gas oil is produced through hydrocracking process of vacuum distillation side streams and heavy cocked gas oil. Gas oil production yield can be increased through the existing operation process units. Modifications of the current atmospheric and vacuum tower operations will increase gas oil yield rates to 20 % more than the existing production rates. The modification of the operating conditions and adoption of the optimum catalyst of the existing hydrocracking and mild hydro cracking process units improve gas oil production yield. Operating delayed cocker at high temperatures, low pressure and low cycle ratio also support achieving the maximization of gas oil yield

  6. Lipid components and oxidative status of selected specialty oils

    Energy Technology Data Exchange (ETDEWEB)

    Madawala, S. R. P.; Kochhar, S. P.; Dutta, P. C.

    2012-11-01

    Many vegetable oils are marketed as specialty oils because of their retained flavors, tastes and distinct characteristics. Specialty oil samples which were commercially produced and retailed were purchased from local superstores in Reading, UK, and Uppsala, Sweden and profiled for detailed lipid composition and oxidative status. These oil samples include: almond, hazelnut, walnut, macadamia nut, argan, avocado, grape seed, roasted sesame, rice bran, cold pressed, organic and cold pressed, warm pressed and refined rapeseed oils. The levels of PV were quite low (0.5-1.3mEq O{sub 2}/kg) but AV and Rancimat values at 100 degree centigrade (except for rapeseed oils) varied considerably at (0.5-15.5) and (4.2-37.0 h) respectively. Macadamia nut oil was found to be the most stable oil followed by argan oil, while walnut oil was the least stable. Among the specialty oils, macadamia nut oil had the lowest (4%) and walnut oil had the highest (71%) level of total PUFA. The organic cold pressed rapeseed oil had considerably lower PUFA (27%) compared with other rapeseed oils (28- 35%). In all the samples, {alpha}- and {gamma}- tocopherols were the major tocopherols; nut oils had generally lower levels. Total sterols ranged from 889 to 15,106 {mu}g/g oil. The major sterols were {beta}-sitosterol (61-85%) and campesterol (6-20%). Argan oil contained schottenol (35%) and spinasterol (32%). Compared with literature values, no marked differences were observed among the differently processed, organically grown or cold pressed rapeseed oils and other specialty oils in this study. (Author) 33 refs.

  7. Composition and qualitative characteristics of virgin olive oils produced in northern Adriatic region, Republic of Croatia

    Directory of Open Access Journals (Sweden)

    Milin, Cedomila

    2001-12-01

    Full Text Available Istria and Island Krk are located in the Northern Adriatic region, Republic of Croatia. The majority of oils produced on the islands of this Region correspond to extra virgin classification as a consequence of olive cultivars (Debela, Naska, Rosulja, Slatka, Buza, Carbonera, Bianchera, Leccino. The characterisation of these oils is little known. The objective of this work was the characterisation of virgin olive oils during the 1997/98, 1998/99 and six months of 1999/2000 harvest. Acidity, peroxide value and UV absorption constants were determined for all samples. Fatty acid composition, sterol and aliphatic alcohol contents, saturated fatty acids in the 2-position of the triglyceride and trilinolein content were determined for the virgin olive oils during 1997/98 harvest. The chemical analyses were supported by the determination of polyphenol content expressed as caffeic acid, squalene and α-tocopherol content.Istria y la isla Krk están localizadas en el norte de la región Adriática, República de Croacia. La mayoría de los aceites producidos en las islas de esta región corresponden a la clasificación extra virgen de las variedades (Debela, Naska, Rosulja, Slatka, Buza, Carbonera, Bianchera, Leccino. La caracterización de estos aceites es poco conocida. El objetivo de este trabajo fue la caracterización de los aceites de oliva vírgenes durante las campañas 1997/98, 1998/99 y seis meses de 1999/2000. Para todas las muestras se determinó la acidez, el índice de peróxido y las constantes de absorción en el UV. Para los aceites de oliva vírgenes durante la campaña 1997/98 se determinaron la composición en ácidos grasos, los contenidos en esteroles y alcoholes alifáticos, los ácidos grasos saturados en posición 2 de los triglicéridos y el contenido en trilinoleína. Los análisis químicos se completaron con la determinación del contenido en polifenoles expresado como ácido cafeico, y la determinación de escualeno y α-tocoferol.

  8. Producing electricity from Israel oil shale with PFBC technology

    International Nuclear Information System (INIS)

    Grinberg, A.; Keren, M.; Podshivalov, V.; Anderson, J.

    2000-01-01

    Results of Israeli oil shale combustion at atmospheric pressure in the AFBC commercial boiler manufactured by Foster Wheeler Energia Oy (Finland) and in the pressurized test facility of ABB Carbon AB (Finspong, Sweden) confirm suitability of fluidized-bed technologies in case of oil shale. The results approve possibility to use the PFBC technology in case of oil shale after solving of some problems connected with great amounts of fine fly ash. (author)

  9. Radioactivity concentration and heavy metal content in fuel oil and oil-ashes in Venezuela

    International Nuclear Information System (INIS)

    Barros, H.; Sajo-Bohus, L.; Abril, J.M.; Greaves, E.D.

    2004-01-01

    During the last years an intensive national program was developed to determine the environmental radioactivity levels in Venezuela. Gamma dose and the radon concentrations indoors, in drinking water, in caves and in artificial cavities including the effect of radon transported to the surface with the earth gas have been studied. To continue this project the oil and other natural energy resource should be considered. It is expected that the environmental radiation level is modified in regions where the oil industrial activity is more aggressive such as in the Zulia State and the Faja Petrolifera del Orinoco, (Central Region). In these regions Venezuela is producing 1.750 thousand barrels of oil from the near-to-the- surface or deep oil drilling. Petroleum constitutes an important source of energy and as the majority of natural source contains radionuclides and their disintegration products, being U, Ra, Pb, Bi, Po and K the most often encountered. The combustion of petroleum concentrate in the ashes those radioelements, and later enter the environment by different ways producing adverse effects on the quality of man life. The concentration of radioelements varies greatly between oil fields, then we still requiring local survey studies in this area. Moreover due to the recent national interest in recycling processes, it becomes important to take precaution in the selection of materials that may contain by-products of industrial origin, including oil. In fact the oil ashes, oil slurry and other mining by-products are thought to be employable in the building industry. The concentration of radioactivity in the ash from thermoelectric power plants that use petroleum as a primary energy source was determined. The analysis include the two major thermoelectric power plants in Venezuela, Ricardo Zuluaga on the northern sea side of Caracas and Planta Centro on the littoral of Carabobo State. The study cover different samples: fuel oil No 6, ashes, heavy and medium petroleum

  10. The Effect of Essential Oil of Nigella sativa and Satureia hortensis on Promastigot Stage of Lishmania major

    Directory of Open Access Journals (Sweden)

    KH Pirali-Kheirabadi

    2013-12-01

    Full Text Available Abstract Background & aim: Leishmaniasis is a zoonotic disease caused by a protozoan parasite of the genus Leishmania. Traditionally, medicinal plants have been used for topical effects of leishmaniasis. The aim of this study was to evaluate the effect of the essential oil of Satureia hortensis and Nigella sativa on the Leishmania major. Methods: In this experimental study, the effects of the plant’s essential oils and savory black beans on the Leishmania major form were studied. Evaluation was determined based on the average of Leishmania parasites form survival after exposure to different concentrations of herbs and chemical drugs MA dose at different intervals. For this purpose, different extracts with ratios of 0.1, 0.2, 0.4, 0.8, 1.2, 1.6, and 2% were added. Different groups of this study were kept in the same condition (incubated at 26 ° C. The parasites were removed from the incubator and the numbers of viable parasites were counted after 24hours. Data were analyzed using descriptive statistics, Tukey test and GM. Results: There was a significant difference in reducing parasites on groups receiving Satureia hortensis and Nigella sativa with Glucantime (p <0.05. Conclusion: Due to the increasing drug resistance of Leishmania, plant oils such as Satureia hortensis and Nigella sativa could be used as an alternative treatment for controlling leishmaniasis. Key words: Essential oil, Leishmaniasis, Nigella sativa, Satureia hortensis

  11. Oxidative stability of structured lipids produced from sunflower oil and caprylic acid

    DEFF Research Database (Denmark)

    Timm Heinrich, Maike; Xu, Xuebing; Nielsen, Nina Skall

    2003-01-01

    Traditional sunflower oil (SO), randomized lipid (RL) and specific structured lipid (SL), both produced from SO and tricaprylin/caprylic acid, respectively, were stored for up to 12 wk to compare their oxidative stabilities by chemical and sensory analyses. Furthermore, the effect of adding...... a commercial antioxidant blend Grindox 117 (propyl gallate/citric acid/ascorbyl palmitate) or gallic acid to the SL was investigated. The lipid type affected the oxidative stability: SL was less stable than SO and RL. The reduced stability was most likely caused by both the structure of the lipid...

  12. Antimicrobial activity of Tulsi (Ocimum tenuiflorum essential oil and their major constituents against three species of bacteria

    Directory of Open Access Journals (Sweden)

    Hanaa Abbas M Yamani

    2016-05-01

    Full Text Available In recent years scientists worldwide have realized that the effective life span of any antimicrobial agent is limited, due to increasing development of resistance by microorganisms. Consequently, numerous studies have been conducted to find new alternative sources of antimicrobial agents, especially from plants. The aims of this project were to examine the antimicrobial properties of essential oils distilled from Australian-grown Ocimum teniflorum (Tulsi, to quantify the volatile components present in flower spikes, leaves and the essential oil, and to investigate the compounds responsible for any activity. Broth micro-dilution was used to determine the minimum inhibitory concentration (MIC of Tulsi essential oil against selected microbial pathogens. The oils, at concentrations of 4.5% and 2.25% completely inhibited the growth of Staphylococcus aureus (including MRSA and Escherichia coli, while the same concentrations only partly inhibited the growth of Pseudomonas aeruginosa. Of 54 compounds identified in Tulsi leaves, flower spikes or essential oil, three are proposed to be responsible for this activity; camphor, eucalyptol and eugenol. Since S. aureus (including MRSA, P. aeruginosa and E. coli are major pathogens causing skin and soft tissue infections, Tulsi essential oil could be a valuable topical antimicrobial agent for management of skin infections caused by these organisms.

  13. Identification of vegetable oil botanical speciation in refined vegetable oil blends using an innovative combination of chromatographic and spectroscopic techniques.

    Science.gov (United States)

    Osorio, Maria Teresa; Haughey, Simon A; Elliott, Christopher T; Koidis, Anastasios

    2015-12-15

    European Regulation 1169/2011 requires producers of foods that contain refined vegetable oils to label the oil types. A novel rapid and staged methodology has been developed for the first time to identify common oil species in oil blends. The qualitative method consists of a combination of a Fourier Transform Infrared (FTIR) spectroscopy to profile the oils and fatty acid chromatographic analysis to confirm the composition of the oils when required. Calibration models and specific classification criteria were developed and all data were fused into a simple decision-making system. The single lab validation of the method demonstrated the very good performance (96% correct classification, 100% specificity, 4% false positive rate). Only a small fraction of the samples needed to be confirmed with the majority of oils identified rapidly using only the spectroscopic procedure. The results demonstrate the huge potential of the methodology for a wide range of oil authenticity work. Copyright © 2014 Elsevier Ltd. All rights reserved.

  14. An evaluation of known remaining oil resources in the United States: Project on advanced oil recovery and the states. Volume 1

    International Nuclear Information System (INIS)

    1994-10-01

    The Interstate Oil and Gas Compact Commission (IOGCC) has conducted a series of studies to evaluate the known, remaining oil resource in twenty-three (23) states. The primary objective of the IOGCC's effort is to examine the potential impact of an aggressive and focused program of research, development, and demonstration (RD ampersand D) and technology transfer on future oil recovery in the United States. As part of a larger effort by the IOGCC, this report focuses on the potential economic, social, and political benefits of improved oil recovery to the nation as a whole. Individual reports for major oil producing states have been separately published. The individual state reports include California, Illinois, Kansas, Louisiana, New Mexico, Oklahoma, Texas, and Wyoming. The analysis presented in this report is based on the databases and models available in the Tertiary Oil Recovery Information System (TORIS). TORIS is a tested and verified system maintained and operated by the Department of Energy's Bartlesville Project Office. The TORTS system was used to evaluate over 2,300 major reservoirs in a consistent manner and on an individual basis, the results of which have been aggregated to arrive at the national total

  15. Vegetable oils as fuels and lubrificants: Commercialization problematics

    International Nuclear Information System (INIS)

    Bartolelli, V.

    1992-01-01

    The aim of this paper is to assess the commercialization feasibility of vegetable oils as industrial fuels and lubricants. The paper also discusses what should be the suitable mix of Italian Government agricultural, environmental and fiscal strategies to support and encourage the production and use of industrial vegetable fuel oils and lubricants. It points out the main advantages of bio-fuel oils - they are much less polluting than conventional fossil fuel oils and can be produced domestically, thus reducing national dependency on foreign energy imports and increasing employment opportunities. The major obstacle to their development is identified as being the creation of suitable pricing and fiscal policies in harmony with traditional energy markets

  16. Bacillus amyloliquefaciens TSBSO 3.8, a biosurfactant-producing strain with biotechnological potential for microbial enhanced oil recovery.

    Science.gov (United States)

    Alvarez, Vanessa Marques; Jurelevicius, Diogo; Marques, Joana Montezano; de Souza, Pamella Macedo; de Araújo, Livia Vieira; Barros, Thalita Gonçalves; de Souza, Rodrigo Octavio Mendonça Alves; Freire, Denise Maria Guimarães; Seldin, Lucy

    2015-12-01

    A screening for biosurfactant-producing bacteria was conducted with 217 strains that were isolated from environmental samples contaminated with crude oil and/or petroleum derivatives. Although 19 promising biosurfactant producers were detected, strain TSBSO 3.8, which was identified by molecular methods as Bacillus amyloliquefaciens, drew attention for its production of a high-activity compound that presented an emulsification activity of 63% and considerably decreased surface (28.5 mN/m) and interfacial (11.4 mN/m) tensions in Trypticase Soy Broth culture medium. TSBSO 3.8 growth and biosurfactant production were tested under different physical and chemical conditions to evaluate its biotechnological potential. Biosurfactant production occurred between 0.5% and 7% NaCl, at pH values varying from 6 to 9 and temperatures ranging from 28 to 50 °C. Moreover, biosurfactant properties remained the same after autoclaving at 121 °C for 15 min. The biosurfactant was also successful in a test to simulate microbial enhanced oil recovery (MEOR). Mass spectrometry analysis showed that the surface active compound was a surfactin, known as a powerful biosurfactant that is commonly produced by Bacillus species. The production of a high-efficiency biosurfactant, under some physical and chemical conditions that resemble those experienced in an oil production reservoir, such as high salinities and temperatures, makes TSBSO 3.8 an excellent candidate and creates good expectations for its application in MEOR. Copyright © 2015 Elsevier B.V. All rights reserved.

  17. Assessing the environmental impact of palm oil produced in Thailand

    NARCIS (Netherlands)

    Saswattecha, K.; Kroeze, C.; Jawjit, W.; Hein, L.G.

    2015-01-01

    There are several concerns related to the increasing production of palm oil in Southeast Asia, including pollution, greenhouse gas emissions and land conversion. The RSPO (Roundtable on Sustainable Palm Oil) certification standard provides an incentive for reducing environmental impacts of palm oil

  18. Interest grows in African oil and gas opportunities

    International Nuclear Information System (INIS)

    Knott, D.

    1997-01-01

    As African countries continue a slow drift towards democratic government and market economics, the continent is increasingly attractive to international oil and gas companies. Though Africa remains politically diverse, and its volatile politics remains a major barrier to petroleum companies, a number of recent developments reflect its growing significance for the industry. Among recent projects and events reflecting changes in Africa: oil and gas exporter Algeria has invited foreign oil companies to help develop major gas discoveries, with a view to boosting exports to Europe; oil and gas producer Egypt invited foreign companies to explore in the Nile Delta region, and the result appears to be a flowering world scale gas play; west African offshore exploration has entered deep water and new areas, and a number of major projects are expected in years to come; Nigeria's reputation as a difficult place to operate has been justified by recent political and civil events, but a long-planned liquefied natural gas (LNG) export plant is being built there; South Africa, which has returned to the international scene after years of trade isolation because of apartheid, is emerging as a potential driver for energy industry schemes throughout the continent. Activities are discussed

  19. Current status and policies on biodiesel industry in Malaysia as the world's leading producer of palm oil

    International Nuclear Information System (INIS)

    Abdullah, A.Z.; Salamatinia, B.; Mootabadi, H.; Bhatia, S.

    2009-01-01

    This article discusses current status of palm oil-based biodiesel industry in Malaysia, the policies introduced and strategies for its implementation. Due to renewability, high production rate, technical feasibility and role in reducing greenhouse gases (GHG) emission, palm oil is in the right position to supply the energy needs by the incorporation into the diesel supply. As a leading producer of palm oil, Malaysia has embarked on a comprehensive palm biofuel program since 1982. It has successfully established the use of palm biodiesel blend (B5) as a suitable fuel for the transport and industrial sectors through the introduction of the National Biofuel Policy. The current scenario of biodiesel program in Malaysia, as well as biofuel policies with respect to its use, technology, export, environmental issues and implementation aspects are thoroughly discussed. The roles of the policy towards the prosperity of the stakeholders, oil price and the reduction of greenhouse gasses are also highlighted. (author)

  20. Management of Reclaimed Produced Water in the Rocky Mountain States Enhanced with the Expanded U.S. Geological Survey Produced Waters Geochemical Database

    Science.gov (United States)

    Gans, K. D.; Blondes, M. S.; Reidy, M. E.; Conaway, C. H.; Thordsen, J. J.; Rowan, E. L.; Kharaka, Y. K.; Engle, M.

    2016-12-01

    The Rocky Mountain states; Wyoming, Colorado, Montana, New Mexico and Utah produce annually approximately 470,000 acre-feet (3.66 billion barrels) of produced water - water that coexists with oil and gas and is brought to the surface with the pumping of oil and gas wells. Concerns about severe drought, groundwater depletion, and contamination have prompted petroleum operators and water districts to examine the recycling of produced water. Knowledge of the geochemistry of produced waters is valuable in determining the feasibility of produced water reuse. Water with low salinity can be reclaimed for use inside and outside of the petroleum industry. Since a great proportion of petroleum wells in the Rocky Mountain states, especially coal-bed methane wells, have produced water with relatively low salinity (generally oil recovery, and even for municipal uses, such as drinking water. The USGS Produced Waters Geochemical Database, available at http://eerscmap.usgs.gov/pwapp, has 60,000 data points in this region (this includes 35,000 new data points added to the 2002 database) and will facilitate studies on the management of produced water for reclamation in the Rocky Mountain region. Expanding on the USGS 2002 database, which contains geochemical analyses of major ions and total dissolved solids, the new data also include geochemical analyses of minor ions and stable isotopes. We have added an interactive web map application which allows the user to filter data on chosen fields (e.g. TDS data set can provide critical insight for better management of produced waters in water-constrained regions of the Rocky Mountains.

  1. Using Biosurfactants Produced from Agriculture Process Waste Streams to Improve Oil Recovery in Fractured Carbonate Reservoirs

    Energy Technology Data Exchange (ETDEWEB)

    Stephen Johnson; Mehdi Salehi; Karl Eisert; Sandra Fox

    2009-01-07

    This report describes the progress of our research during the first 30 months (10/01/2004 to 03/31/2007) of the original three-year project cycle. The project was terminated early due to DOE budget cuts. This was a joint project between the Tertiary Oil Recovery Project (TORP) at the University of Kansas and the Idaho National Laboratory (INL). The objective was to evaluate the use of low-cost biosurfactants produced from agriculture process waste streams to improve oil recovery in fractured carbonate reservoirs through wettability mediation. Biosurfactant for this project was produced using Bacillus subtilis 21332 and purified potato starch as the growth medium. The INL team produced the biosurfactant and characterized it as surfactin. INL supplied surfactin as required for the tests at KU as well as providing other microbiological services. Interfacial tension (IFT) between Soltrol 130 and both potential benchmark chemical surfactants and crude surfactin was measured over a range of concentrations. The performance of the crude surfactin preparation in reducing IFT was greater than any of the synthetic compounds throughout the concentration range studied but at low concentrations, sodium laureth sulfate (SLS) was closest to the surfactin, and was used as the benchmark in subsequent studies. Core characterization was carried out using both traditional flooding techniques to find porosity and permeability; and NMR/MRI to image cores and identify pore architecture and degree of heterogeneity. A cleaning regime was identified and developed to remove organic materials from cores and crushed carbonate rock. This allowed cores to be fully characterized and returned to a reproducible wettability state when coupled with a crude-oil aging regime. Rapid wettability assessments for crushed matrix material were developed, and used to inform slower Amott wettability tests. Initial static absorption experiments exposed limitations in the use of HPLC and TOC to determine

  2. Characterization and Catalytic Upgrading of Crude Bio-oil Produced by Hydrothermal Liquefaction of Swine Manure and Pyrolysis of Biomass

    Science.gov (United States)

    Cheng, Dan

    The distillation curve of crude bio-oil from glycerol-assisted hydrothermal liquefaction of swine manure was measured using an advanced distillation apparatus. The crude bio-oil had much higher distillation temperatures than diesel and gasoline and was more distillable than the bio-oil produced by the traditional liquefaction of swine manure and the pyrolysis of corn stover. Each 10% volumetric fraction was analyzed from aspects of its chemical compositions, chemical and physical properties. The appearance of hydrocarbons in the distillates collected at the temperature of 410.9°C and above indicated that the thermal cracking at a temperature from 410°C to 500°C may be a proper approach to upgrade the crude bio-oil produced from the glycerol-assisted liquefaction of swine manure. The effects of thermal cracking conditions including reaction temperature (350-425°C), retention time (15-60 min) and catalyst loadings (0-10 wt%) on the yield and quality of the upgraded oil were analyzed. Under the optimum thermal cracking conditions at 400°C, a catalyst loading of 5% by mass and the reaction time of 30 min, the yield of bio-oil was 46.14% of the mass of the crude bio-oil and 62.5% of the energy stored in the crude bio-oil was recovered in the upgraded bio-oil. The upgraded bio-oil with a heating value of 41.4 MJ/kg and viscosity of 3.6 cP was comparable to commercial diesel. In upgrading crude bio-oil from fast pyrolysis, converting organic acids into neutral esters is significant and can be achieved by sulfonated activated carbon/bio-char developed from fermentation residues. Acitivated carbon and bio-char were sulfonated by concentrated sulfuric acid at 150°C for 18 h. Sulfonation helped activated carbon/bio-char develop acid functional groups. Sulfonated activated carbon with BET surface area of 349.8 m2/g, was effective in converting acetic acid. Acetic acid can be effectively esterified by sulfonated activated carbon (5 wt%) at 78°C for 60 min with the

  3. Properties of a biosurfactant produced by Bacillus pumilus using vinasse and waste frying oil as alternative carbon sources

    Directory of Open Access Journals (Sweden)

    Juliana Guerra de Oliveira

    2013-02-01

    Full Text Available Biosurfactants are chemical molecules produced by the microorganisms with potential for application in various industrial and environmental sectors. The production parameters and the physicochemical properties of a biosurfactant synthesized by Bacillus pumilus using different concentrations of vinasse and waste frying oil as alternative carbon sources were analyzed. The microorganism was able to grow and produce a biosurfactant using both the residues. The surface tension was reduced up to 45 mN/m and the maximum production of crude biosurfactant was 27.7 and 5.7 g/l for vinasse and waste frying oil, respectively, in concentration of 5%. The critical micelle concentration (CMC results of 1.5 and 0.2 g/l showed the efficiency of the biosurfactant produced on both the substrates. The results showed that the alternative substrates could be used for the production of an efficient biosurfactant by B. pumilus. These properties have potential for industrial and environmental applications.

  4. Chemical profiling of clove bud oil (Syzygium aromaticum) from Toli-Toli and Bali by GC-MS analysis

    Science.gov (United States)

    Sulistyoningrum, A. S.; Saepudin, E.; Cahyana, A. H.; Rahayu, D. U. C.; Amelia, B.; Haib, J.

    2017-07-01

    Indonesia is the largest clove producer in the world. In 2012, total world clove production is 113,215 tons where nearly 71 % (79,250 tons) comes from Indonesia. Although Indonesia is a major producer of clove in the world, research and publications about cloves in this country are scarce and hence knowledge about characteristics of difference varieties of cloves is very limited. The present study was aimed to compare major and minor constituents in clove oil responsible for their flavor based on origin which are cloves from Toli-Toli and Bali. The clove bud oil was isolated from clove bud (Syzygium aromaticum) using steam distillation. The compounds of clove bud oil was analyzed using GC-MS. The major compounds of clove oil were eugenol, caryophyllene, α-humulene and eugenyl acetate with composition 66.37 %, 15.38 %, 1.97 % and 12.99 %, respectively (Toli-Toli) and clove from Bali were 72.34 %, 12.51 %, 2.34 % and 5.33 %, respectively. The unique minor compounds of clove oil from Toli-Toli were (+)-δ-cadinene (0.13 %) and β-caryophylladienol (0.19 %) while in clove oil from Bali were valencene (0.17 %), δ-selinene (0.22 %) and alloaromadendrene (0.24 %). A total of 36 compounds were identified from the clove bud oil Toli-Toli and 38 compounds from the clove bud oil Bali.

  5. Sources of environmental disturbance associated with offshore oil and gas developments

    International Nuclear Information System (INIS)

    Davies, J.M.; Kingston, P.F.

    1992-01-01

    The North Sea is one of the most productive fishing areas in the world, producing 3.5% of the world's catch of fish, and as a consequence is one of the most widely studied areas of sea. The potential sources of disturbance to the environment from oil and gas production are seismic surveys, physical disturbance to the sediment during platform placement, drilling, and through burying and trenching of pipelines, and pollution from pipeline and platform discharges and oil spills. Studies on the biological effects of such disturbances are repeated. These include investigations into the impact on the species diversity of marine fauna and oil taint and petrogenic hydrocarbons in fish. It has become clear that oil based mud cuttings discharge accounts for the major source of hydrocarbon contaminations from oil production and has a major deleterious effect on benthors in the immediate vicinity of the discharge. (Author)

  6. Analysis of Flue Gas Emissions Using a Semi-industrial Boiler Fueled by Biodiesel Produced from Two-stage Transesterification of Waste Cooking Oil

    OpenAIRE

    Mansourpoor, M.; Shariati, A.

    2014-01-01

    In this work, waste cooking oil and methanol as feedstock together with sulfuric acid and potassium hydroxide as catalysts were used to produce biodiesel. The physical properties of the waste cooking oil, the produced biodiesel and the purchased petrodiesel were measured using specified ASTM standards. To examine their performance and their flue gases emissions, biodiesel and petrodiesel were burnt in a wet base semi-industrial boiler. The emitted combustion gases, including CO, NOx, SO2 and ...

  7. Oil recovery enhancement from fractured, low permeability reservoirs. Annual report 1990--1991, Part 1

    Energy Technology Data Exchange (ETDEWEB)

    Poston, S.W.

    1991-12-31

    Joint funding by the Department of Energy and the State of Texas has Permitted a three year, multi-disciplinary investigation to enhance oil recovery from a dual porosity, fractured, low matrix permeability oil reservoir to be initiated. The Austin Chalk producing horizon trending thru the median of Texas has been identified as the candidate for analysis. Ultimate primary recovery of oil from the Austin Chalk is very low because of two major technological problems. The commercial oil producing rate is based on the wellbore encountering a significant number of natural fractures. The prediction of the location and frequency of natural fractures at any particular region in the subsurface is problematical at this time, unless extensive and expensive seismic work is conducted. A major portion of the oil remains in the low permeability matrix blocks after depletion because there are no methods currently available to the industry to mobilize this bypassed oil. The following multi-faceted study is aimed to develop new methods to increase oil and gas recovery from the Austin Chalk producing trend. These methods may involve new geological and geophysical interpretation methods, improved ways to study production decline curves or the application of a new enhanced oil recovery technique. The efforts for the second year may be summarized as one of coalescing the initial concepts developed during the initial phase to more in depth analyses. Accomplishments are predicting natural fractures; relating recovery to well-log signatures; development of the EOR imbibition process; mathematical modeling; and field test.

  8. Laboratory Evaluation of Acute Toxicity of the Essential Oil of Allium tuberosum Leaves and Its Selected Major Constituents Against Apolygus lucorum (Hemiptera: Miridae).

    Science.gov (United States)

    Shi, Jizhe; Liu, Xinchao; Li, Zhen; Zheng, Yuanyuan; Zhang, Qingwen; Liu, Xiaoxia

    2015-01-01

    The aim of this research was to evaluate acute toxicity of the essential oil of leaves of Chinese chives, Allium tuberosum Rottler ex Spreng (Asparagales: Alliaceae) and its major constituents against Apolygus lucorum Meyer-Dür (Hemiptera: Miridae). The essential oil of A. tuberosum leaves was obtained by hydrodistillation and analyzed by gas chromatography and gas chromatography-mass spectrometry. The major constituents of the oil were sulfur-containing compounds, including allyl methyl trisulfide (36.24%), diallyl disulfide (27.26%), diallyl trisulfide (18.68%), and dimethyl trisulfide (9.23%). The essential oil of A. tuberosum leaves exhibited acute toxicity against Ap. lucorum with an LD50 value of 20.03 μg per adult. Among the main compounds, diallyl trisulfide (LD50 = 10.13 μg per adult) showed stronger acute toxicity than allyl methyl trisulfide (LD50 = 21.10 μg per adult) and dimethyl trisulfide (LD50 = 21.65 μg per adult). The LD50 value of diallyl disulfide against Ap. lucorum was 28.10 μg per adult. The results indicated that the essential oil of A. tuberosum and its major constituents may have a potential to be developed as botanical insecticides against Ap. lucorum. © The Author 2015. Published by Oxford University Press on behalf of the Entomological Society of America.

  9. Energy security: it's not only oil. Increasing and replacing oil resources

    International Nuclear Information System (INIS)

    Mandil, C.; Appert, O.

    2006-01-01

    The security of energy supplies is once again right at the top of the list of energy policy subjects, following the political tensions in the Middle East, as well as major electricity failures of recent years, the hurricanes of August and September 2005 and the gas dispute between Russia and Ukraine. Even if the system of strategic oil stocks managed by the International Energy Agency has proved to be efficient, today keywords for guarding against the risks are diversification (of energy, of its sources, its suppliers and of its supply lines) and flexibility. Dialogue with the producers is essential. It will be difficult to find substitutes for hydrocarbons (oil and natural gas) in the short and medium terms to meet the needs of transport and for the petrochemical industry; they are likely to represent, in the order of two-thirds of the total demand for the world energy by the year 2030. In order to replace oil resources, taking account of all the risks of climate change, technological innovation will play a major role and should allow us to benefit from today potentially unreliable hydrocarbon supplies for many more years, allowing our society sufficient time to develop other sources of energy, and to do so at a cost that is acceptable to everybody. (authors)

  10. Is it true that polymerization of vegetable oil occurs through Diels-Alder reaction?

    Science.gov (United States)

    Diels-Alder reaction mechanism is known to be one of the major reaction mechanisms to produce dimers and polymers during heating process of vegetable oil. However, our NMR study showed no evidence for Diels-Alder products. Soybean oil oxidized at 180 °C for 24 hrs with 1.45 surface area-to-volume ...

  11. Corrosion behavior of Cu Al Ni shape memory alloy in an oil land field produced fluid; Corrosao da liga com memoria de forma CuAlNi em fluido produzido de campo terrestre de petroleo

    Energy Technology Data Exchange (ETDEWEB)

    Souza, Ricardo Estefany Aquino [PETROBRAS S.A., Aracaju/Maceio, SE/AL (Brazil). Unidade de Negocios SE-AL; Cruz, Maria Clara Pinto; Figueiredo, Renan T.; Souza, Luciete da Paixao; Araujo, Paulo M.M. [Universidade Tiradentes (UNIT), Aracaju, SE (Brazil)

    2008-07-01

    The corrosion behavior of the CuAlNi shape memory alloy in oil landfield produced groundwater was investigated with polarization curve and mass loss measurements, the latter carried out by immersion in laboratory and field tests. The physico-chemical analysis of five types of oil landfield produced groundwater showed the presence of H{sub 2}S and CO{sub 2}, high salinity, chloride, sulfide and iron ions and relatively neutral pH. The results from electrochemical tests in aerated produced groundwater, in the range of salinity encountered, suggested that the corrosion rate increases at higher saline concentrations. The results from field tests with corrosion test specimens showed a moderate to severe corrosion rate and suggested, in the other hand, that corrosion rates were influenced not only by salinity and oxidizing ions present in the flowing fluid, but also by solid materials in suspension, the fluid's temperature, and the flow velocity. This research is part of a major project which aims to develop couplings for landfield produced fluid transportation pipe connections without welded nor threaded joints. (author)

  12. Microbial communities inhabiting oil-contaminated soils from two major oilfields in Northern China: Implications for active petroleum-degrading capacity.

    Science.gov (United States)

    Sun, Weimin; Dong, Yiran; Gao, Pin; Fu, Meiyan; Ta, Kaiwen; Li, Jiwei

    2015-06-01

    Although oilfields harbor a wide diversity of microorganisms with various metabolic potentials, our current knowledge about oil-degrading bacteria is limited because the vast majority of oil-degrading bacteria remain uncultured. In the present study, microbial communities in nine oil-contaminated soils collected from Daqing and Changqing, two of the largest oil fields in China, were characterized through highthroughput sequencing of 16S rRNA genes. Bacteria related to the phyla Proteobacteria and Actinobacteria were dominant in four and three samples, respectively. At the genus level, Alkanindiges, Arthrobacter, Pseudomonas, Mycobacterium, and Rhodococcus were frequently detected in nine soil samples. Many of the dominant genera were phylogenetically related to the known oil-degrading species. The correlation between physiochemical parameters within the microbial communities was also investigated. Canonical correspondence analysis revealed that soil moisture, nitrate, TOC, and pH had an important impact in shaping the microbial communities of the hydrocarbon-contaminated soil. This study provided an in-depth analysis of microbial communities in oilcontaminated soil and useful information for future bioremediation of oil contamination.

  13. Investigation of produced waters radioactivity of oil and gas deposits in the Dnieper-Donets province

    Directory of Open Access Journals (Sweden)

    Plyatsuk L. D.

    2017-12-01

    Full Text Available The process of radioactive pollution of produced waters, oilfield equipment, oil-contaminated soils and sludge is widely spread and differs within the various oil and gas regions. Formation waters contained radioactive element isotopes become the significant source and cause of elevated level of equivalent dose power and as a consequence, an increase in the incidence among the population. The author's idea is formulation of specific recommendations on the decontamination of the investigated objects by conducting the necessary appropriate experimental studies. The purpose of the article is to determine the content of radionuclides, γ- and α-emitters in technogenic objects of Bugruvate oil and gas fields, and to reveal the relationship with the features of mineralogical composition, geological structure and technological process. The γ-spectrometric analysis was used to determine the radionuclide composition of the natural radiators of the 238U (226Ra, 214Pо, 214Bi and 232Th (228Ac, 212Pb, 212Вi series in samples of technological sludge, oil, individual soil samples and water. The content of radionuclides of α-emitters was determined using separate radiochemical techniques. It was investigated that the radioactivity of the formation water is mainly determined by 226Ra and 228Ra and the products of their decay.

  14. Distillation Parameters for Pilot Plant Production of Laurus nobilis Essential oil

    Directory of Open Access Journals (Sweden)

    Temel Özek

    2012-01-01

    Full Text Available Essential oils have increasing importance in flavour and fragrance industries. They are obtained by distillation techniques. In order to produce an oil with market potential its optimum production parameters have to be well known prior to its commercial production. Determination of the steam distillation parameters of commercially available Laurel leaves oil in pilot plant scale is described. The effect of steam rate and processing time play a major role in distillation of essential oils. Distillation speed was high in the beginning of the process, then gradually reduced as the distillation proceeded. The main component of the oil of Laurel leaf oil was 1,8-cineole accumulating significantly in the early fractions.

  15. Utilization of oil palm fronds in producing activated carbon using Na2CO3 as an activator

    Science.gov (United States)

    Maulina, S.; Anwari, FN

    2018-02-01

    Oil Palm Frond is a waste in palm oil plantations that have the potential to be processed into more valuable products. This possibility is because of the presence of cellulose, hemicellulose, and lignin in oil palm fronds. Therefore, this study aimed to utilize oil palm fronds in manufacturing of activated carbon through pyrolysis and impregnation that meets the requirements of the Industrial National Standard 06-3730-1995. The palm-fringed oil palm fronds were pyrolyzed in reactors at 150°C, 200°C, and 250°C for 60 minutes. Subsequently, the charcoal produced from the pyrolysis was smoothed with a ball mill, sieved with a size of 140 meshes, and impregnated using a Sodium Carbonate (Na2CO3) for 24 hours at a concentration of 0 %, 2.5%, 5%, and 7.5 % (w/v). The activated carbon has 35.13% of charcoal yield, 8.6% of water content, 14.25% of ash content, 24.75% of volatile matter, 72.75% of fixed carbon, and 492.29 of iodine number. Moreover, SEM analysis indicated that activated carbon porous are coarse and distributed.

  16. Challenges facing the international oil and gas industry in the 21st century

    International Nuclear Information System (INIS)

    Subroto, Dr.

    1992-01-01

    In the world league of energy suppliers, crude oil producers will continue to lead the field, lubricating the wheels of commerce and industry well into the next century. Oil has now been discovered in most of the world's regions, and some 80% of all oil produced is traded internationally. No other energy commodity offers quite the same qualities of transformability and transportability. Over the last three decades OPEC has been a major player in that trade. This paper briefly examines the turbulent history of oil since OPEC's formation over 30 years ago, noting the events leading up to the decision taken by the Organization in 1985 to abandon its role as oil price administrator and go all out to defend its market share. As the oil world moved from confrontation to dialogue in the late 1980s, OPEC sought constructive talks on the subject of proposed environmental constraints on oil development. (author)

  17. Tail dependence between oil and stocks of major oil-exporting countries using the CoVaR approach

    Directory of Open Access Journals (Sweden)

    Nader Trabelsi

    2017-12-01

    Full Text Available This paper investigates the negative tail risk dependence between oil shocks and stock indices (at aggregated and desegregated levels for Saudi Arabia (KSA, United Arab Emirates (UAE and Russia, over the period between 2007 and 2016. DCC-MGARCH approach and CoVaR measure are employed to assess the oil shock exposure. The results show that the tail dependence is significant and depends on the origin of the oil shocks, with intensity that varies across countries and sectors. Keywords: Oil price shocks, Oil-exporting countries, Conditional VaR, JEL Classification: C58, G11, Q4

  18. Micro Fine Sized Palm Oil Fuel Ash Produced Using a Wind Tunnel Production System

    Directory of Open Access Journals (Sweden)

    R. Ahmadi

    2016-01-01

    Full Text Available Micro fine sized palm oil fuel ash (POFA is a new supplementary cementitious material that can increase the strength, durability, and workability of concrete. However, production of this material incurs high cost and is not practical for the construction industry. This paper investigates a simple methodology of producing micro fine sized POFA by means of a laboratory scale wind tunnel system. The raw POFA obtained from an oil palm factory is first calcined to remove carbon residue and then grinded in Los Angeles abrasion machine. The grinded POFA is then blown in the fabricated wind tunnel system for separation into different ranges of particle sizes. The physical, morphological, and chemical properties of the micro fine sized POFA were then investigated using Laser Particle Size Analyser (PSA, nitrogen sorption, and Scanning Electron Microscopy with Energy Dispersive X-Ray (SEM-EDX. A total of 32.1% micro fine sized POFA were collected from each sample blown, with the size range of 1–10 micrometers. The devised laboratory scale of wind tunnel production system is successful in producing micro fine sized POFA and, with modifications, this system is envisaged applicable to be used to commercialize micro fine sized POFA production for the construction industry.

  19. Greenhouse gas intensity of palm oil produced in Colombia addressing alternative land use change and fertilization scenarios

    International Nuclear Information System (INIS)

    Castanheira, Érica Geraldes; Acevedo, Helmer; Freire, Fausto

    2014-01-01

    Highlights: • A comprehensive evaluation of alternative LUC and fertilization schemes. • The GHG intensity of palm oil greatly depends on the LUC scenario. • Colombian palm area expansion resulted in negative or low palm oil GHG intensity. • GHG emissions from plantation vary significantly with N 2 O emission parameters. - Abstract: The main goal of this article is to assess the life-cycle greenhouse gas (GHG) intensity of palm oil produced in a specific plantation and mill in Colombia. A comprehensive evaluation of the implications of alternative land use change (LUC) scenarios (forest, shrubland, savanna and cropland conversion) and fertilization schemes (four synthetic and one organic nitrogen-fertilizer) was performed. A sensitivity analysis to field nitrous oxide emission calculation, biogas management options at mill, time horizon considered for global warming and multifunctionality approach were also performed. The results showed that the GHG intensity of palm oil greatly depends on the LUC scenario. Significant differences were observed between the LUC scenarios (−3.0 to 5.3 kg CO 2 eq kg −1 palm oil). The highest result is obtained if tropical rainforest is converted and the lowest if palm is planted on previous cropland, savanna and shrubland, in which almost all LUC from Colombian oil palm area expansion occurred between 1990 and 2009. Concerning plantation and oil extraction, it was shown that field nitrous oxide emissions and biogas management options have a high influence on GHG emissions

  20. Oil and development

    Energy Technology Data Exchange (ETDEWEB)

    Ellis, F

    1974-10-01

    The shift in world income due to the increase in oil prices has resulted in a world economy that has been thrown off balance. Nine papers are presented that explore the background and the main implications of this ''watershed'' in international relations, particularly the extent to which it will affect the development prospects of poor countries and the climate of trade between poor and rich nations in the next few years. Two papers, ''Diary of Events in the Oil Market 1971--1974'' and ''Statistical Background,'' provide information on the financial changes implied by the price increase; some of the figures should be treated as preliminary estimates only. ''Large International Firms in the Oil Industry'' examines the part played by the major oil companies in developments in the oil market leading up to the events of 1973. Two papers, ''Can OPEC Maintain Current Prices'' and ''OPEC As a Model for Other Mineral Exporters,'' present optimistic conclusions, from the viewpoint of developing countries, on their future capability for controlling their own destinies in trade. ''A Note on Some Issues Raised for Science and Technology Policy by the Increase in Oil Prices'' looks at options open to producers and consumers of raw materials. ''Assessing the Economic Impact on Developing Countries and Some Policy Suggestions,'' ''A Note on the Implications of the Oil Price Increases for British Aid Policy,'' and ''Confrontation Versus Co-operation'' are three papers concerned with difficulties of developing countries and particularly India, Bangladesh, and Sri Lanka. (MCW)

  1. Hopanoid-producing bacteria in the Red Sea include the major marine nitrite-oxidizers

    KAUST Repository

    Kharbush, Jenan J

    2018-04-10

    Hopanoids, including the extended side chain-containing bacteriohopanepolyols (BHPs), are bacterial lipids found abundantly in the geological record and across Earth\\'s surface environments. However, the physiological roles of this biomarker remain uncertain, limiting interpretation of their presence in current and past environments. Recent work investigating the diversity and distribution of hopanoid producers in the marine environment implicated low-oxygen regions as important loci of hopanoid production, and data from marine oxygen minimum zones (OMZs) suggested that the dominant hopanoid producers in these environments are nitrite-utilizing organisms, revealing a potential connection between hopanoid production and the marine nitrogen cycle. Here we use metagenomic data from the Red Sea to investigate the ecology of hopanoid producers in an environmental setting that is biogeochemically distinct from those investigated previously. The distributions of hopanoid production and nitrite oxidation genes in the Red Sea are closely correlated, and the majority of hopanoid producers are taxonomically affiliated with the major marine nitrite oxidizers, Nitrospinae and Nitrospirae. These results suggest that the relationship between hopanoid production and nitrite oxidation is conserved across varying biogeochemical conditions in dark ocean microbial ecosystems.

  2. Hopanoid-producing bacteria in the Red Sea include the major marine nitrite-oxidizers

    KAUST Repository

    Kharbush, Jenan J; Thompson, Luke R; Haroon, Mohamed; Knight, Rob; Aluwihare, Lihini I

    2018-01-01

    Hopanoids, including the extended side chain-containing bacteriohopanepolyols (BHPs), are bacterial lipids found abundantly in the geological record and across Earth's surface environments. However, the physiological roles of this biomarker remain uncertain, limiting interpretation of their presence in current and past environments. Recent work investigating the diversity and distribution of hopanoid producers in the marine environment implicated low-oxygen regions as important loci of hopanoid production, and data from marine oxygen minimum zones (OMZs) suggested that the dominant hopanoid producers in these environments are nitrite-utilizing organisms, revealing a potential connection between hopanoid production and the marine nitrogen cycle. Here we use metagenomic data from the Red Sea to investigate the ecology of hopanoid producers in an environmental setting that is biogeochemically distinct from those investigated previously. The distributions of hopanoid production and nitrite oxidation genes in the Red Sea are closely correlated, and the majority of hopanoid producers are taxonomically affiliated with the major marine nitrite oxidizers, Nitrospinae and Nitrospirae. These results suggest that the relationship between hopanoid production and nitrite oxidation is conserved across varying biogeochemical conditions in dark ocean microbial ecosystems.

  3. Nigeria's oil production and the need for increased producing capacity

    International Nuclear Information System (INIS)

    Okoroji, C. E. I.

    1998-01-01

    After 40 years of commercial oil production, Nigeria's crude oil production is moving through difficult times. This transition period has been made more difficult because of recurring international economic recession, lack-luster crude prices, and slow oil demand growth and Government funding problems etc. Crude oil remains the most important export revenue earner in Nigeria, and more efforts are required to encourage higher output levels to support more foreign exchange generation. Nigeria's crude oil production at present stands at 2.2 million barrels per day (mbpd). This study, covers the period 1998-2005, during which oil production is forecast to grow to about 2.85 mbpd while potential for new discoveries could raise production to more than 3.0 mbpd. These projected rates could depend to a large extent on the rate and size of new discoveries. However, Nigeria's crude oil potential is being constrained by both lack of infrastructure and inadequate investment. The massive investment needed to raise the country's productive capacity will require foreign capital, yet the current fiscal environment leaves much to be desired. The purpose of this paper is to present a review of Nigeria's past, present and future oil production. To meet the projected production capacity very early in the next millennium, current estimates put the overall potential investment needed for an accelerated capacity-expansion drive in order to ensure that there is adequate cushion of crude potential at $19.7 billion during the next seven years. Furthermore, not more than $12.0 billion of this requirement can be generated from Nigeria's government cash flow

  4. Compositional simulations of producing oil-gas ratio behaviour in low permeable gas condensate reservoir

    OpenAIRE

    Gundersen, Pål Lee

    2013-01-01

    Master's thesis in Petroleum engineering Gas condensate flow behaviour below the dew point in low permeable formations can make accurate fluid sampling a difficult challenge. The objective of this study was to investigate the producing oil-gas ratio behaviour in the infinite-acting period for a low permeable gas condensate reservoir. Compositional isothermal flow simulations were performed using a single-layer, radial and two-dimensional, gas condensate reservoir model with low permeabili...

  5. Europe and oil: beware of the glass ceiling

    International Nuclear Information System (INIS)

    Durand, B.

    2011-01-01

    Because current oil exporting countries consume an increasing share of their production and will shortly be producing less and less, available amounts of oil for the international market will decrease faster than world production, in spite of the emergence of new exporting countries such as Brazil or Kazakhstan. Owing to expanding consumption of major emerging countries, the share le for developed countries will drop rapidly, by approximately one third in the coming fifteen years. Europe, whose oil reserves will soon be exhausted, will almost entirely depend on outside sources. If it does not adjust through massive and swift consumption reduction, its material growth will be durably jeopardized due to substantial oil price increases. The adjustment requires strong and urgent measures to reduce the consumption of oil-based fuel in transportation, as well as of fuel oil by the residential and tertiary sectors. A selection of measures is set out. (author)

  6. Quality Attributes of Fresh Palm Oils Produced from Selected ...

    African Journals Online (AJOL)

    The oils were analyzed for their physical (refractive index, impurities, density, smoke point, flash point and fire point) and chemical (moisture, free fatty acids, peroxide value, saponification value iodine value and unsaponificable matter) qualities using standard methods. Palm oil processors in the selected communities were ...

  7. Wettability of Oil-Producing Reservoir Rocks as Determined from X-ray Photoelectron Spectroscopy

    Science.gov (United States)

    Toledo; Araujo; Leon

    1996-11-10

    Wettability has a dominant effect in oil recovery by waterflooding and in many other processes of industrial and environmental interest. Recently, the suggestion has been made that surface science analytical techniques (SSAT) could be used to rapidly determine the wettability of reservoir materials. Here, we bring the capability of X-ray photoelectron spectroscopy (XPS) to bear on the wettability evaluation of producing reservoir rocks. For a suite of freshly exposed fracture surfaces of rocks we investigate the relationship between wettability and surface composition as determined from XPS. The classical wettability index as measured with the Amott-Harvey test is used here as an indicator of the wettability of natural sandstones. The XPS spectra of oil-wet surfaces of rocks reveal the existence of organic carbon and also of an "organic" silicon species, of the kind Si-CH relevant to silanes, having a well-defined binding energy which differs from that of the Si-O species of mineral grains. We provide quantifiable evidence that chemisorbed organic material on the pore surfaces defines the oil-wetting character of various reservoir sandstones studied here which on a mineralogic basis are expected to be water-wet. This view is supported by a strong correlation between C content of pore surfaces and rock wettability. The results also suggest a correlation between organic silicon content on the pore surfaces and rock hydrophobicity.

  8. Impact of Expanded North Slope of Alaska Crude Oil Production on Oil Flows in the Contiguous United States (Summary)

    Energy Technology Data Exchange (ETDEWEB)

    DeRosa, Sean e. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Flanagan, Tatiana Paz [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2017-05-01

    Crude oil produced on the North Slope of Alaska (NSA) is primarily transported on the Trans-Alaska Pipeline System (TAPS) to in-state refineries and the Valdez Marine Terminal in southern Alaska. From the Terminal, crude oil is loaded onto tankers and is transported to export markets or to three major locations along the U.S. West Coast: Anacortes-Ferndale area (Washington), San Francisco Bay area, and Los Angeles area. North Slope of Alaska production has decreased about 75% since the 1980s, which has reduced utilization of TAPS.

  9. A review on technologies for oil shale surface retort

    International Nuclear Information System (INIS)

    Pan, Y.; Zhang, X.; Liu, S.; Yang, S.A.; Ren, N.

    2012-01-01

    In recent years, with the shortage of oil resources and the continuous increase in oil prices, oil shale has seized much more attention. Oil shale is a kind of important unconventional oil and gas resources. Oil shale resources are plentiful according to the proven reserves in places. And shale oil is far richer than crude oil in the world. Technology processing can be divided into two categories: surface retorting and in-situ technology. The process and equipment of surface retorting are more mature, and are still up to now, the main way to produce shale oil from oil shale. According to the variations of the particle size, the surface retorting technologies of oil shale can be notified and classified into two categories such as lump shale process and particulate shale process. The lump shale processes introduced in this article include the Fushun retorting technology, the Kiviter technology and the Petrosix technology; the particulate processes include the Gloter technology, the LR technology, the Tosco-II technology, the ATP (Alberta Taciuk Process) technology and the Enefit-280 technology. After the thorough comparison of these technologies, we can notice that, this article aim is to show off that : the particulate process that is environmentally friendly, with its low cost and high economic returns characteristics, will be the major development trend; Combined technologies of surface retorting technology and other oil producing technology should be developed; the comprehensive utilization of oil shale should be considered during the development of surface retorting technology, meanwhile the process should be harmless to the environment. (author)

  10. Oil Spills

    Science.gov (United States)

    Oil spills often happen because of accidents, when people make mistakes or equipment breaks down. Other causes include natural disasters or deliberate acts. Oil spills have major environmental and economic effects. Oil ...

  11. Oil in Syria between Terrorism and Dictatorship

    Directory of Open Access Journals (Sweden)

    Hussein Almohamad

    2016-05-01

    Full Text Available The sale of oil and gas is one of the most important components of the Syrian economy. Unfortunately, since the discovery of these resources, the Syrian people have not benefited from the revenues earned. This study deals with the development of oil and gas production and the geographical distribution of fields, as well as production control, deterioration of production, refining and selling mechanisms, and the resulting health and environmental impacts following Islamic State’s (IS control of the majority of oilfields in Syria. Since summer 2015, IS controls 80% of the fields with a production of 65,000 barrels per day (b/d; the Assad regime controls 8% of fields with 10,000 b/d; and Kurdish forces dominate the remaining 12% with 25,000 b/d. IS depends on oil as a major source of financing for its military and civilian activities, and has also managed to set up an extensive network of middlemen in neighbouring territories and countries, with the aim of trading crude oil for cash and other resources. IS produces and exports within its areas of control and sells part of the oil to the Assad regime, and another portion to the liberated areas, as well as to Iraq and Turkey.

  12. Chemical composition and major odor-active compounds of essential oil from PINELLIA TUBER (dried rhizome of Pinellia ternata) as crude drug.

    Science.gov (United States)

    Iwasa, Megumi; Iwasaki, Toshiki; Ono, Toshirou; Miyazawa, Mitsuo

    2014-01-01

    The chemical composition of the essential oil from PINELLIA TUBER (Japanese name: Hange), the dried rhizome of Pinellia ternata, was investigated by capillary gas chromatography (GC) and GC-mass spectrometry (MS) analyses. The oil obtained from Pinellia tuber was revealed the presence of 114 compounds, representing 90.6% of the total oil identified. This colorless oil had a spicy and woody odor. The main components of the oil were β-cubebene (8.8%), atractylon (7.8%), methyl eugenol (6.2%), and δ-cadinene (5.3%). Fifteen major odor-active compounds were identified in the essential oil from PINELLIA TUBER by the GC-olfactometry (GC-O) and aroma extract dilution analysis (AEDA). Among these, safrole (spicy) and β-vatirenene (woody) showed the highest flavor dilution (FD) factor (128), followed by paeonol (FD = 64; woody, spicy), α-humulene (FD = 64; woody), and β-phenylnaphthalene (FD = 64; spicy).

  13. PEMANFAATAN MINYAK SAWIT MERAH DALAM PEMBUATANBISKUIT KACANG KAYA BETA KAROTEN [Utilization of Red Palm Oil To Produce BetaCarotene-Rich Nuts Biscuit

    Directory of Open Access Journals (Sweden)

    Robiyansyah Robiyansyah

    2017-03-01

    Full Text Available The purpose of this research was to get formulation of red palm oil and cooking oil to produce nuts biscuits with the best organoleptic properties. The formula consisted of red palm oil and cooking oil mixture with 6 comparisons: (0:100, (20:80, (40:60, (60:40, (80:20 and (100:0. These formula were then used as basis to produce nuts biscuits. Observation was done on the organoleptic properties (aroma, texture, taste and color for all biscuits for all samples, while  proximates test (water, fat,protein,ash content and betacarotene content were done only for the best formulation. The data were descriptively analyzed and presented in tables and graphs. The best organoleptic properties of these betacarotene rich nuts biscuits was formulation of 20:80. This biscuits had water content 1,42%, ash content 1,21%, fat content 32,60%, protein content 12,59%, and the total of beta carotene 347,15 ppm, with the less normal for aroma (4,55, less crunchy for the texture (4,40, distinctive flavor beans for the taste (4,28, and yellowish for the color (4,50. Keywords: β-carotene, nuts biscuits,red palm oil.

  14. Need for refining capacity creates opportunities for producers in Middle East

    International Nuclear Information System (INIS)

    Ali, M.S.S.

    1994-01-01

    Oil industry interest in refining has revived in the past few years in response to rising oil consumption. The trend creates opportunities, for countries in the Middle East, which do not own refining assets nearly in proportion to their crude oil reserved. By closing this gap between reserves and refining capacity, the countries can ease some of the instability now characteristic of the oil market. Some major oil producing countries have begun to move downstream. During the 1980s, Venezuela, Kuwait, Saudi Arabia, Libya, and other members of the Organization of Petroleum Exporting Countries acquired refining assets through direct total purchase or joint ventures. Nevertheless, the oil industry remains largely unintegrated, with the Middle East holding two thirds of worldwide oil reserves but only a small share downstream. As worldwide refining capacity swings from a period of surplus toward one in which the need for new capacity will be built. The paper discusses background of the situation, shrinking surplus, investment requirements, sources of capital, and shipping concerns

  15. 77 FR 13019 - Marketing Order Regulating the Handling of Spearmint Oil Produced in the Far West; Salable...

    Science.gov (United States)

    2012-03-05

    ... DEPARTMENT OF AGRICULTURE Agricultural Marketing Service 7 CFR Part 985 [Doc. No. AMS-FV-11-0088; FV12-985-1 PR] Marketing Order Regulating the Handling of Spearmint Oil Produced in the Far West; Salable Quantities and Allotment Percentages for the 2012-2013 Marketing Year AGENCY: Agricultural...

  16. 78 FR 32070 - Marketing Order Regulating the Handling of Spearmint Oil Produced in the Far West; Salable...

    Science.gov (United States)

    2013-05-29

    ... DEPARTMENT OF AGRICULTURE Agricultural Marketing Service 7 CFR Part 985 [Doc. No. AMS-FV-12-0064; FV13-985-1 FR] Marketing Order Regulating the Handling of Spearmint Oil Produced in the Far West; Salable Quantities and Allotment Percentages for the 2013-2014 Marketing Year AGENCY: Agricultural...

  17. 76 FR 27852 - Marketing Order Regulating the Handling of Spearmint Oil Produced in the Far West; Salable...

    Science.gov (United States)

    2011-05-13

    ... DEPARTMENT OF AGRICULTURE Agricultural Marketing Service 7 CFR Part 985 [Doc. No. AMS-FV-10-0094; FV11-985-1 FR] Marketing Order Regulating the Handling of Spearmint Oil Produced in the Far West; Salable Quantities and Allotment Percentages for the 2011-2012 Marketing Year AGENCY: Agricultural...

  18. Core Flood study for enhanced oil recovery through ex-situ bioaugmentation with thermo- and halo-tolerant rhamnolipid produced by Pseudomonas aeruginosa NCIM 5514.

    Science.gov (United States)

    Varjani, Sunita J; Upasani, Vivek N

    2016-11-01

    The aim of this work was to study the Microbial Enhanced Oil Recovery (MEOR) employing core field model ex-situ bioaugmenting a thermo- and halo-tolerant rhamnolipid produced by Pseudomonas aeruginosa. Thin Layer Chromatography (TLC) revealed that the biosurfactant produced was rhamnolipid type. Nuclear Magnetic Resonance analysis showed that the purified rhamnolipids comprised two principal rhamnolipid homologues, i.e., Rha-Rha-C10-C14:1 and Rha-C8-C10. The rhamnolipid was stable under wide range of temperature (4°C, 30-100°C), pH (2.0-10.0) and NaCl concentration (0-18%, w/v). Core Flood model was designed for oil recovery operations using rhamnolipid. The oil recovery enhancement over Residual Oil Saturation was 8.82% through ex-situ bioaugmentation with rhamnolipid. The thermal stability of rhamnolipid shows promising scope for its application at conditions where high temperatures prevail in oil recovery processes, whereas its halo-tolerant nature increases its application in marine environment. Copyright © 2016 Elsevier Ltd. All rights reserved.

  19. Oxidative stability of mayonnaise and milk drink produced with structured lipids based on fish oil and caprylic acid

    DEFF Research Database (Denmark)

    Timm Heinrich, Maike; Xu, Xuebing; Nielsen, Nina Skall

    2004-01-01

    The oxidative stabilities of traditional fish oil (FO), randomized lipids (RFO), or specific structured lipids (SFO) produced from fish oil were compared when incorporated into either milk drink or mayonnaise. Furthermore, the effect of adding the potential antioxidants EDTA (240 mg...... not be ascribed to a single factor, but was most likely influenced by the structure of the lipids and differences in the processes used to produce and purify the lipids. In milk drinks based on SFO, EDTA slightly reduced oxidation, while lactoferrin did not exert a distinct antioxidative effect....../kg) or lactoferrin (1000 mg/kg) to the milk drink based on SFO was investigated. The lipid type significantly affected the oxidative stability of both mayonnaises and milk drinks: The oxidative stability decreased in the order RFO>FO>SFO. The reduced oxidative stability in the SFO food emulsions could...

  20. Environmental Degradation in Oil Producing Areas of Niger Delta ...

    African Journals Online (AJOL)

    Due to oil exploration and other human activities in the Niger Delta region, there is evidence of environmental degradation all over the area (Oronto, 1998). Environmental degradation is occasioned by consistent flow of industrial waste, oil spills, gas flares, fire disaster, acid rain, flooding erosion, etc., which has led to the ...

  1. Effect of subsidies to fossil fuel companies on United States crude oil production

    Science.gov (United States)

    Erickson, Peter; Down, Adrian; Lazarus, Michael; Koplow, Doug

    2017-11-01

    Countries in the G20 have committed to phase out `inefficient' fossil fuel subsidies. However, there remains a limited understanding of how subsidy removal would affect fossil fuel investment returns and production, particularly for subsidies to producers. Here, we assess the impact of major federal and state subsidies on US crude oil producers. We find that, at recent oil prices of US50 per barrel, tax preferences and other subsidies push nearly half of new, yet-to-be-developed oil investments into profitability, potentially increasing US oil production by 17 billion barrels over the next few decades. This oil, equivalent to 6 billion tonnes of CO2, could make up as much as 20% of US oil production through 2050 under a carbon budget aimed at limiting warming to 2 °C. Our findings show that removal of tax incentives and other fossil fuel support policies could both fulfil G20 commitments and yield climate benefits.

  2. Interest grows in African oil and gas opportunities

    Energy Technology Data Exchange (ETDEWEB)

    Knott, D.

    1997-05-12

    As African countries continue a slow drift towards democratic government and market economics, the continent is increasingly attractive to international oil and gas companies. Though Africa remains politically diverse, and its volatile politics remains a major barrier to petroleum companies, a number of recent developments reflect its growing significance for the industry. Among recent projects and events reflecting changes in Africa: oil and gas exporter Algeria has invited foreign oil companies to help develop major gas discoveries, with a view to boosting exports to Europe; oil and gas producer Egypt invited foreign companies to explore in the Nile Delta region, and the result appears to be a flowering world scale gas play; west African offshore exploration has entered deep water and new areas, and a number of major projects are expected in years to come; Nigeria`s reputation as a difficult place to operate has been justified by recent political and civil events, but a long-planned liquefied natural gas (LNG) export plant is being built there; South Africa, which has returned to the international scene after years of trade isolation because of apartheid, is emerging as a potential driver for energy industry schemes throughout the continent. Activities are discussed.

  3. CO2 Enhanced Oil Recovery from the Residual Zone - A Sustainable Vision for North Sea Oil Production

    Science.gov (United States)

    Stewart, Jamie; Haszeldine, Stuart; Wilkinson, Mark; Johnson, Gareth

    2014-05-01

    This paper presents a 'new vision for North Sea oil production' where previously unattainable residual oil can be produced with the injection of CO2 that has been captured at power stations or other large industrial emitters. Not only could this process produce incremental oil from a maturing basin, reducing imports, it also has the capability to store large volumes of CO2 which can offset the emissions of additional carbon produced. Around the world oil production from mature basins is in decline and production from UK oil fields peaked in 1998. Other basins around the world have a similar story. Although in the UK a number of tax regimes, such as 'brown field allowances' and 'new field allowances' have been put in place to re-encourage investment, it is recognised that the majority of large discoveries have already been made. However, as a nation our demand for oil remains high and in the last decade imports of crude oil have been steadily increasing. The UK is dependent on crude oil for transport and feedstock for chemical and plastics production. Combined with the necessity to provide energy security, there is a demand to re-assess the potential for CO2 Enhanced Oil Recovery (CO2-EOR) in the UK offshore. Residual oil zones (ROZ) exist where one of a number of natural conditions beyond normal capillary forces have caused the geometry of a field's oil column to be altered after filling [1]. When this re-structuring happens the primary interest to the hydrocarbon industry has in the past been in where the mobile oil has migrated to. However it is now considered that significant oil resource may exist in the residual zone play where the main oil column has been displaced. Saturations within this play are predominantly close to residual saturation (Sr) and would be similar to that of a water-flooded field [2]. Evidence from a number of hydrocarbon fairways shows that, under certain circumstances, these residual zones in US fields are comparable in thickness to the

  4. Effect of hydrothermal pretreatment on product distribution and characteristics of oil produced by the pyrolysis of Huadian oil shale

    International Nuclear Information System (INIS)

    Jiang, Haifeng; Deng, Sunhua; Chen, Jie; Zhang, Mingyue; Li, Shu; Shao, Yifei; Yang, Jiaqi; Li, Junfeng

    2017-01-01

    Highlights: • The maximum yield of pyrolysis oil is obtained at the pretreatment time of 2.0 h. • The higher H/C ratio of oil is obtained after hydrothermal pretreatment. • Hydrothermal treatment promotes the formation of aliphatic hydrocarbons in the oil. • Long pretreatment time causes the increase of heavier oil fraction in the oil. - Abstract: In this work, Huadian oil shale from China was treated by hydrothermal pretreatment at 200 °C with 1.0–2.5 h in order to investigate the effect of hydrothermal pretreatment on pyrolysis product distribution and characteristics of oil. The differences in the elemental composition and thermal behavior between the untreated and treated oil shale were analyzed and compared. The hydrothermal treatment process could decompose oxygen functional groups and remove some water soluble inorganics in oil shale, which decreased the formation of gas and water during the pyrolysis. However, hydrothermal pretreatment was conducive to increasing shale oil yield. The maximum of oil yield was obtained at the pretreatment time of 2.0 h. The enhancement of the free-radical reactions during the pyrolysis and the reduction of the secondary cracking reactions of the generated oil vapors were considered as the main reasons. The oil obtained by the treated oil shale had a higher H/C ratio, indicating it had high energy content. The analysis results of chemical compositions in oils showed that the relative content of aliphatic hydrocarbons significantly increased after hydrothermal pretreatment. The further analysis demonstrated that the increase in the pretreatment time caused the generated long chain hydrocarbons tended to be directly released from oil shale particles, and were condensed into the oil.

  5. Antileishmanial Activity of Lavandula angustifolia and Rosmarinus Officinalis Essential Oils and Nano-emulsions on Leishmania major (MRHO/IR/75/ER

    Directory of Open Access Journals (Sweden)

    Azar SHOKRI

    2017-12-01

    Full Text Available AbstractBackground: The aim of present study was to evaluate antileishmanial effects of Lavandula angustifolia (L. angustifolia and Rosmarinus officinalis (R. officinalis medicinal plants essential oils and nano-emulsions on Leishmania major (L. major. Methods: The present study was performed in Leishmaniasis Reference Lab at Mazandaran University of Medical Sciences, Iran during 2016-2017. The IC50 values were calculated in both the promastigote and amastigote stages in J774 macrophage in comparison with meglumine antimoniate (MA as positive control. In addition, cytotoxicity effects of essential oils and nano-emulsions prepared from both plants against macrophages were evaluated.Results: Both essential oil and nano-emulsion of Lavander and Rosemary showed anti-leishmania activity on promastigote with IC50=0.11 μl/mL, IC50=0.26 μl/mL, and IC50=0.08 μl/mL respectively. Moreover, during amastigote assay, Lavander and Rosemary essential oils and nano-emulsion were effective at least in concentration of 0.12 μl/mL and 0.06 µl/mL (P=0.0001 respectively, on mean infected macrophages (MIR and amastigotes in macrophages (P=0.0001. Additionally, cytotoxicity assay against macrophage revealed no toxicity on the host cells at IC50 concentrations.Conclusion: The nano-emulsions of both plants were more effective than essential oil in both MIR and amastigote. However, in comparison with MA, the Lavander essential oil is more effective in reducing MIR. Rosemary nano-emulsion reduced MIR significantly more than MA in concentration of 0.25 μl/mL (P<0.001. Further investigations are recommended to evaluate the effect of these medicinal plants in murine models.

  6. Laboratory scale conceptual process development for the isolation of renewable glycolaldehyde from pyrolysis oil to produce fermentation feedstock

    NARCIS (Netherlands)

    Vitasari, C.R.; Meindersma, G.W.; Haan, de A.B.

    2012-01-01

    A laboratory-based separation sequence has been developed to produce an aqueous glycolaldehyde solution as fermentation feedstock. It consists of water extraction of pyrolysis oil, acid removal, water removal, octanol extraction, phenolic removal, back-extraction, and washing. The octanol-free

  7. FY 2000 report on the research cooperation project - Research cooperation in developmental support for oil producing countries. Development of the new field of usage of Orinoco oil for fuel of gas turbine combined power generation; 2000 nendo san'yukoku kaihatsu shien kenkyu kyoryoku jigyo seika hokokusho. Gasu tabin fukugo hatsuden nenryo muke Orinoko oil no shin yoto kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-09-01

    For the purpose of spreading the usage of Orinoco crude oil which is suffering from sluggishness in the export and heightening the economical efficiency in Venezuela, research cooperation was made for a project for reduction of the power cost and environmental loads in Japan by producing the advanced gas turbine use fuel oil from Orinoco oil and exporting it to Japan. In this project, conducted were the technical verification that the gas turbine use fuel oil (GTF) can be produced from Orinoco oil and the economical verification based on the result thereof. As a result of the technical verification, it was confirmed that from the Orinoco crude oil which is heavy, high in sulfur and high in heavy metal concentration, a refined oil satisfying the following properties of the advanced gas turbine fuel oil could be trial-produced using the distilling unit, SDA unit, desulfurizer and de-metaling unit: vanadium concentration: 0.5 wtppm or below; sodium + potassium concentration: 1.0 wtppm or below; viscosity: 20 cSt or below at 135 degrees C. Further, from the economical verification, the good result was obtained that the price was lower than the LNG price and the domestic price of A heavy oil/C heavy oil. (NEDO)

  8. Characterization of macadamia and pecan oils and detection of mixtures with other edible seed oils by Raman spectroscopy

    Directory of Open Access Journals (Sweden)

    Carmona, M. A.

    2015-09-01

    Full Text Available Authenticating fats and detecting their adulteration with substantially cheaper fats can pose major problems for producers of high-value oils for nutritional and cosmetic use. In this work, we used Raman spectroscopy to discriminate macadamia and pecan oils from other, cheaper vegetable oils including corn and sunflower oils. This technique additionally allows one to detect and assess the adulteration of macadamia oil with another vegetable oil.La autentificación de grasas para detectar su adulteración con otras grasas más baratas es uno de los principales problemas a los que se enfrentan los productores de aceites de alto valor, ya sea para uso alimentario o para uso cosmético. En este trabajo se emplea la espectroscopia Raman, por un lado, para caracterizar los aceites de macadania y de nuez pecanera, de alto valor y diferenciarlos de otros más baratos, como los de maíz y de girasol, y por otro, para detectar mezclas del aceite de macadamia con estos aceites vegetales más baratos.

  9. Transformation of iron sulfide to greigite by nitrite produced by oil field bacteria.

    Science.gov (United States)

    Lin, Shiping; Krause, Federico; Voordouw, Gerrit

    2009-05-01

    Nitrate, injected into oil fields, can oxidize sulfide formed by sulfate-reducing bacteria (SRB) through the action of nitrate-reducing sulfide-oxidizing bacteria (NR-SOB). When reservoir rock contains siderite (FeCO(3)), the sulfide formed is immobilized as iron sulfide minerals, e.g. mackinawite (FeS). The aim of our study was to determine the extent to which oil field NR-SOB can oxidize or transform FeS. Because no NR-SOB capable of growth with FeS were isolated, the well-characterized oil field isolate Sulfurimonas sp. strain CVO was used. When strain CVO was presented with a mixture of chemically formed FeS and dissolved sulfide (HS(-)), it only oxidized the HS(-). The FeS remained acid soluble and non-magnetic indicating that it was not transformed. In contrast, when the FeS was formed by adding FeCl(2) to a culture of SRB which gradually produced sulfide, precipitating FeS, and to which strain CVO and nitrate were subsequently added, transformation of the FeS to a magnetic, less acid-soluble form was observed. X-ray diffraction and energy-dispersive spectrometry indicated the transformed mineral to be greigite (Fe(3)S(4)). Addition of nitrite to cultures of SRB, containing microbially formed FeS, was similarly effective. Nitrite reacts chemically with HS(-) to form polysulfide and sulfur (S(0)), which then transforms SRB-formed FeS to greigite, possibly via a sulfur addition pathway (3FeS + S(0) --> Fe(3)S(4)). Further chemical transformation to pyrite (FeS(2)) is expected at higher temperatures (>60 degrees C). Hence, nitrate injection into oil fields may lead to NR-SOB-mediated and chemical mineral transformations, increasing the sulfide-binding capacity of reservoir rock. Because of mineral volume decreases, these transformations may also increase reservoir injectivity.

  10. Treatment of Oily Wastewater Produced From Old Processing Plant of North Oil Company

    Directory of Open Access Journals (Sweden)

    Dr. Faris Hammoodi Al-Ani

    2012-03-01

    Full Text Available The main objectives of this research were to study and analyses oily wastewater characteristics originating from old-processing plant of North Oil Company and to find a suitable and simple method to treat the waste so it can be disposed off safely. The work consists of two stages; the first was the study of oily wastewater characteristics and its negative impacts. The results indicated that oil and grease were the most dominant pollutant with concentration range between 1069 – 3269.3 mg/l that must be removed; other pollutants were found to be within Iraqi and EPA standards. The next stage was the use of these characteristics to choose the proper technology to treat that wastewater. This stage was divided into two stages: the first stage was a jar tests to find the optimum doses of alum, lime and powdered activated carbon (PAC. The second stage was the treatment by a batch pilot plant constructed for this purpose employing the optimum doses as determined from the first stage to treat the waste using a flotation unit followed by a filtration-adsorption unit. The removal efficiencies of flotation unit for oil and grease, COD, and T.S.S found to be 0.9789, 0.974, and 0.9933, respectively, while the removal efficiency for T.D.S was very low 0.0293. From filtration – adsorption column the removal efficiencies of oil and grease, T.D.S, COD, and T.S.S were found to be 0.9486, 0.8908, 0.6870, and 0.7815, respectively. The overall removal efficiencies of pilot plant were 0.9986, 0.8939, 0.9921, and 0.9950, respectively. The results indicated that this type of treatment was the simplest and most effective method that can be used to treat produced oily wastewater before disposal

  11. Genetic determinism of oil acidity among some DELI oil palm (Elaeis ...

    African Journals Online (AJOL)

    USER

    2016-08-24

    Aug 24, 2016 ... Key words: Elaeis guineensis Jacq., free fatty acid content, crude palm oil, inheritance. INTRODUCTION. The oil palm (Elaeis ... of world's production of vegetable oils. The highest palm oil producing countries ... Without prior refining, acidic palm oil is improper for human consumption (Anonymous, 2005).

  12. AL-PAM assisted filtration of mature fine tailings produced from oil sands development

    Energy Technology Data Exchange (ETDEWEB)

    Alamgir, A.; Masliyah, J.; Xu, Z. [Alberta Univ., Edmonton, AB (Canada). Dept. of Chemical and Materials Engineering

    2010-07-01

    The inventory of mature fine tailings (MFT) produced by the oil sands extraction process continues to grow, and is considered as a long-term environmental liability. Large amounts of water are trapped in the MFT, and the tailings ponds present a threat to local wildlife and ecosystems. This PowerPoint presentation discussed a research project that is being conducted to identify conditions for producing stackable MFT deposits. The study is investigating various types and dosages of polymers and evaluating the degrees of MFT dilution and process configurations needed to maximize re-usable water recovery. Polymeric flocculants include AL-PAM and Magnafloc 1011. Settling tests have demonstrated that 50 ppm is the optimum dosage for both polymers when MFT is diluted to 5 wt percent solids, while 75 ppm of AL-PAM and 100 ppm of MF1011 are optimum dosages for MFT diluted to 10 wt percent solids. A novel supernatant filtration method was then used to produce filtration cakes and water. The study showed that the supernatant can be used to further dilute the MFTs. tabs., figs.

  13. How Unilever palm oil suppliers are burning up Borneo

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2008-04-15

    New evidence shows expansion by Unilever palm oil suppliers is driving species extinction in Central Kalimantan, and fuelling climate change. In November 2007, Greenpeace released 'Cooking the Climate', an 82-page report summarizing the findings of a two-year investigation that revealed how the world's largest food, cosmetic and biofuel companies were driving the wholesale destruction of Indonesia's rainforests and peatlands through growing palm oil consumption. This follow-up report provides further evidence of the expansion of the palm oil sector in Indonesia into remaining rainforests, orang-utan habitat and peatlands in Kalimantan. It links the majority of the largest producers in Indonesia to Unilever, probably the largest palm oil corporate consumer in the world.

  14. Study on the basic properties of Indonesian oil sands

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Qing; Jiang, Qian-qian; Bai, Jing-ru; Sun, Jian; Liu, Hong-peng [Northeast Dianli Univ., Jilin (China). Inst. of Energy and Power Engineering

    2013-07-01

    The basic properties of three Indonesian oil sands have been investigated. The results show that since the high content of volatile, heating value and oil yield, Indonesian oil sands could be combusted for power generation and retorting for oil refining. Moreover, oil sand ash with the low content of fixed carbon and high content of CaO, could not only be used as solid heat carrier during retorting, but also comprehensively used as construction material. Based on the thermogravimeric analysis (TGA), pyrolysis and combustion behaviors have been identified. As for pyrolysis, 350-520 C could be regarded as the major oil-producing region, the apparent activation energy E is not a constant obtained by distributed activation energy model (DAEM). For combustion, 620-800 C is the high-temperature oxidation (HTO) stage. TG-DTG extrapolation method was applied to determine the combustion characteristics parameters such as ignition temperature, burn-out temperature, combustion stability and combustion reactivity, and finally gave a comparison with those of oil shale and coal.

  15. Solar Thermal Enhanced Oil Recovery, (STEOR) Volume 1: Executive summary

    Science.gov (United States)

    Elzinga, E.; Arnold, C.; Allen, D.; Garman, R.; Joy, P.; Mitchell, P.; Shaw, H.

    1980-11-01

    Thermal enhanced oil recovery is widely used in California to aid in the production of heavy oils. Steam injection either to stimulate individual wells or to drive oil to the producing wells, is by far the major thermal process today and has been in use for over 20 years. Since steam generation at the necessary pressures (generally below 4000 kPa (580 psia)) is within the capabilities of present day solar technology, it is logical to consider the possibilities of solar thermal enhanced oil recovery (STEOR). The present project consisted of an evaluation of STEOR. Program objectives, system selection, trade-off studies, preliminary design, cost estimate, development plan, and market and economic analysis are summarized.

  16. Environmental regulations handbook for enhanced oil recovery. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, T.D.

    1980-08-01

    A guide to environmental laws and regulations which have special significance for enhanced oil recovery (EOR) is presented. The Clean Air Act, the Clean Water Act, the Safe Drinking Water Act, Resource Conservation and Recovery Act, federal regulations, and state regulations are discussed. This handbook has been designed as a planning tool and a convenient reference source. The 16 states included comprise the major oil-producing states in various regions of the state. The major topics covered are: general guidelines for complying with environmental laws and regulations; air pollution control; water pollution control; protecting drinking water: underground injection control; hazardous waste management; and federal laws affecting siting or operation of EOR facilities. (DMC)

  17. Co-processing of standard gas oil and biocrude oil to hydrocarbon fuels

    International Nuclear Information System (INIS)

    Agblevor, Foster A.; Mante, O.; McClung, R.; Oyama, S.T.

    2012-01-01

    The major obstacle in thermochemical biomass conversion to hydrocarbon fuels using pyrolysis has been the high oxygen content and the poor stability of the product oils, which cause them to solidify during secondary processing. We have developed a fractional catalytic pyrolysis process to convert biomass feedstocks into a product termed “biocrude oils” (stable biomass pyrolysis oils) which are distinct from unstable conventional pyrolysis oils. The biocrude oils are stable, low viscosity liquids that are storable at ambient conditions without any significant increases in viscosity; distillable at both atmospheric pressure and under vacuum without char or solid formation. About 15 wt% biocrude oils containing 20–25% oxygen were blended with 85 wt% standard gas oil and co-cracked in an Advanced Catalyst Evaluation (ACE™) unit using fluid catalytic cracking (FCC) catalysts to produce hydrocarbon fuels that contain negligible amount of oxygen. For the same conversion of 70% for both the standard gas oil and the biocrude oil/gas oil blends, the product gasoline yield was 44 wt%, light cycle oil (LCO) 17 wt%, heavy cycle oil (HCO) 13 wt%, and liquefied petroleum gas (LPG) 16 wt%. However, the coke yield for the standard gas oil was 7.06 wt% compared to 6.64–6.81 wt% for the blends. There appeared to be hydrogen transfer from the cracking of the standard gas oil to the biocrude oil which subsequently eliminated the oxygen in the fuel without external hydrogen addition. We have demonstrated for the first time that biomass pyrolysis oils can be successfully converted into hydrocarbons without hydrogenation pretreatment. -- Highlights: ► The co-processed product had less than 1% oxygen content and contained biocarbons determined by 14 C analysis. ► The co-processing did not affect the yields of gasoline, LCO, and HCO. ► First demonstration of direct conversion of pyrolysis oils into drop-in hydrocarbon fuels.

  18. Management of soybean oil refinery wastes through recycling them for producing biosurfactant using Pseudomonas aeruginosa MR01.

    Science.gov (United States)

    Partovi, Maryam; Lotfabad, Tayebe Bagheri; Roostaazad, Reza; Bahmaei, Manochehr; Tayyebi, Shokoufe

    2013-06-01

    Biosurfactant production through a fermentation process involving the biodegradation of soybean oil refining wastes was studied. Pseudomonas aeruginosa MR01 was able to produce extracellular biosurfactant when it was cultured in three soybean oil refinement wastes; acid oil, deodorizer distillate and soapstock, at different carbon to nitrogen ratios. Subsequent fermentation kinetics in the three types of waste culture were also investigated and compared with kinetic behavior in soybean oil medium. Biodegradation of wastes, biosurfactant production, biomass growth, nitrate consumption and the number of colony forming units were detected in four proposed media, at specified time intervals. Unexpectedly, wastes could stimulate the biodegradation activity of MR01 bacterial cells and thus biosurfactant synthesis beyond that of the refined soybean oil. This is evident from higher yields of biodegradation and production, as revealed in the waste cultures (Ydeg|(Soybean oil) = 53.9 % YP/S|(Soybean oil) = 0.31 g g(-1), respectively). Although production yields were approximately the same in the three waste cultures (YP/S|(wastes) =/~ 0.5 g g(-1)), microbial activity resulted in higher yields of biodegradation (96.5 ± 1.13 %), maximum specific growth rate (μ max = 0.26 ± 0.02 h(-1)), and biosurfactant purity (89.6 %) with a productivity of 14.55 ± 1.10 g l(-1), during the bioconversion of soapstock into biosurfactant. Consequently, applying soybean oil soapstock as a substrate for the production of biosurfactant with commercial value has the potential to provide a combination of economical production with environmental protection through the biosynthesis of an environmentally friendly (green) compound and reduction of waste load entering the environment. Moreover, this work inferred spectrophotometry as an easy method to detect rhamnolipids in the biosurfactant products.

  19. Volatile constituents of essential oil and rose water of damask rose (Rosa damascena Mill.) cultivars from North Indian hills.

    Science.gov (United States)

    Verma, Ram Swaroop; Padalia, Rajendra Chandra; Chauhan, Amit; Singh, Anand; Yadav, Ajai Kumar

    2011-10-01

    Rosa damascena Mill. is an important aromatic plant for commercial production of rose oil, water, concrete and absolute. The rose water and rose oil produced under the mountainous conditions of Uttarakhand were investigated for their chemical composition. The major components of rose water volatiles obtained from the bud, half bloom and full bloom stages of cultivar 'Ranisahiba' were phenyl ethyl alcohol (66.2-79.0%), geraniol (3.3-6.6%) and citronellol (1.8-5.5%). The rose water volatiles of cultivar 'Noorjahan' and 'Kannouj' also possessed phenyl ethyl alcohol (80.7% and 76.7%, respectively) as a major component at full bloom stage. The essential oil of cultivar 'Noorjahan' obtained from two different growing sites was also compared. The major components of these oils were citronellol (15.9-35.3%), geraniol (8.3-30.2%), nerol (4.0-9.6%), nonadecane (4.5-16.0%), heneicosane (2.6-7.9%) and linalool (0.7-2.8%). This study clearly showed that the flower ontogeny and growing site affect the composition of rose volatiles. The rose oil produced in this region was comparable with ISO standards. Thus, it was concluded that the climatic conditions of Uttarakhand are suitable for the production of rose oil of international standards.

  20. Characteristic of oil palm residue for energy conversion system

    International Nuclear Information System (INIS)

    Muharnif; Zainal, Z.A.

    2006-01-01

    Malaysia is the major producer of palm oil in the world. It produces 8.5 tones per year (8.5 x 10 6 ty -1 ) of palm oil from 38.6 x 10 6 ty - 1 of fresh fruit bunches. Palm oil production generates large amounts of process residue such as fiber (5.4 x 10 6 ty - 1 ), shell (2.3 x 10 6 ty - 1 ), and empty fruit bunches (8.8 x 10 6 ty - 1 ). A large fraction of the fiber and much of the shell are used as fuel to generate process steam and electricity. The appropriate energy conversion system depends on the characteristic of the oil palm residue. In this paper, a description of characteristic of the oil palm residue is presented. The types of the energy conversion system presented are stoker type combustor and gasified. The paper focuses on the pulverized biomass material and the use of fluidized bed gasified. In the fluidized bed gasified, the palm shell and fiber has to be pulverized before feeding into gasified. For downdraft gasified and furnace, the palm shell and fiber can be used directly into the reactor for energy conversion. The heating value, burning characteristic, ash and moisture content of the oil palm residue are other parameters of the study

  1. Dynamics of two methanogenic microbiomes incubated in polycyclic aromatic hydrocarbons, naphthenic acids, and oil field produced water.

    Science.gov (United States)

    Oko, Bonahis J; Tao, Yu; Stuckey, David C

    2017-01-01

    Oil field produced water (OFPW) is widely produced in large volumes around the world. Transforming the organic matter in OFPW into bioenergy, such as biomethane, is one promising way to sustainability. However, OFPW is difficult to biologically degrade because it contains complex compounds such as naphthenic acids (NAs), or polycyclic aromatic hydrocarbons (PAHs). Although active microbial communities have been found in many oil reservoirs, little is known about how an exotic microbiome, e.g. the one which originates from municipal wastewater treatment plants, would evolve when incubated with OFPW. In this study, we harvested methanogenic biomass from two sources: a full-scale anaerobic digester (AD) treating oil and gas processing wastewater (named O&G sludge), and from a full-scale AD reactor treating multiple fractions of municipal solid wastes (named MS, short for mixed sludge). Both were incubated in replicate microcosms fed with PAHs, NAs, or OFPW. The results showed that the PAHs, NAs, and OFPW feeds could rapidly alter the methanogenic microbiomes, even after 14 days, while the O&G sludge adapted faster than the mixed sludge in all the incubations. Two rarely reported microorganisms, a hydrogenotrophic methanogen Candidatus methanoregula and a saccharolytic fermenter Kosmotoga , were found to be prevalent in the PAHs and OFPW microcosms, and are likely to play an important role in the syntrophic degradation of PAHs and OFPW, cooperating with methanogens such as Methanoregula, Methanosarcina, or Methanobacterium . The dominant phyla varied in certain patterns during the incubations, depending on the biomass source, feed type, and variation in nutrients. The sludge that originated from the oil and gas processing wastewater treatment (O&G) reactor adapted faster than the one from municipal solid waste reactors, almost certainly because the O&G biomass had been "pre-selected" by the environment. This study reveals the importance of biomass selection for other

  2. Essential oil of Artemisia vestita exhibits potent in vitro and in vivo antibacterial activity: Investigation of the effect of oil on biofilm formation, leakage of potassium ions and survival curve measurement.

    Science.gov (United States)

    Yang, Chang; Hu, Dong-Hui; Feng, Yan

    2015-10-01

    The aim of the present study was to investigate the chemical composition of the essential oil of Artemisia vestita and to determine the antibacterial activity of the essential oil and its two major components, grandisol and 1,8‑cineole, against certain respiratory infection‑causing bacterial strains, in vitro and in vivo. The chemical composition of the essential oil was analyzed using gas chromatography‑mass spectrometry. A micro‑well dilution method was used to determine the minimum inhibition concentration (MIC) values of the essential oil and its major constituents. A model of Streptococcus pyogenes infection in mice was used to determine its in vivo activities. Lung and blood samples were obtained to assess bacterial cell counts. Toxicity evaluation of the essential oil and its components was completed by performing biochemical analysis of the serum, particularly monitoring aspartate transaminase, alanine transaminase, urea and creatinine. The essential oil exhibited potent antibacterial activity, whereas the two major constituents were less potent. The essential oil exhibited MIC values between 20 and 80 µg/ml, while the values of the two constituents were between 130 and 200 µg/ml. Scanning electron microscopy results demonstrated that the essential oil inhibited biofilm formation and altered its architecture. Survival curves indicated that the essential oil led to a reduction in the viability of different bacteria. The essential oil also induced significant leakage of potassium ions from S. pyogenes. The essential oil (100 µg/mouse) and grandisol (135 µg/mouse) significantly reduced the number of viable bacterial cells in the lungs (Pessential oil or grandisol 135 µg/mouse once or twice each day for 9 days did not produce any toxic effects in the mice. In conclusion, the in vitro and in vivo results suggested that the essential oil of A. vestita and one of its major constituents, grandisol, can significantly inhibit the growth of different

  3. SYNTHESIS OF 3,4-DIMETHOXY ISOAMYL CINNAMIC AS THE SUNSCREEN COMPOUND FROM CLOVE OIL AND FUSEL OIL

    Directory of Open Access Journals (Sweden)

    Tutik Dwi Wahyuningsih

    2010-06-01

    Full Text Available Synthesis of sunscreen compound 3,4-dimethoxy isoamyl cinnamic from clove oil and fusel oil has been done. The majoring component of clove oil that is eugenol has been isolated, followed with several chemical processes i.e. isomerization into isoeugenol, oxidation of the product to change into vanillin, then modification vanillin into veratraldehyde. From the fusel oil, we isolate isoamyl alcohol and modified by acetylation into isoamyl acetic. The final product could be produce by Claissen's condensation of isoamyl acetic and veratraldehyde to give 3,4-dimethoxy isoamyl cinnamic. All of the processes are followed with structure characterization using GC, IR, GC-MS and 1H-NMR spectroscopy. The result shown that compound has 46.98% purity and potent as the UV-B sunscreen's type (lmax = 313 nm. In-vitro sunscreen's activity of the compound was tested by UV-Vis spectrophotometry and resulting a maximum Sun Protection Factor value (SPFin-vitro at low concentration, 10.25 mg/mL.   Keywords: UV absorber, sunscreen, clove oil, cinnamic esther.

  4. Water issues associated with heavy oil production.

    Energy Technology Data Exchange (ETDEWEB)

    Veil, J. A.; Quinn, J. J.; Environmental Science Division

    2008-11-28

    Crude oil occurs in many different forms throughout the world. An important characteristic of crude oil that affects the ease with which it can be produced is its density and viscosity. Lighter crude oil typically can be produced more easily and at lower cost than heavier crude oil. Historically, much of the nation's oil supply came from domestic or international light or medium crude oil sources. California's extensive heavy oil production for more than a century is a notable exception. Oil and gas companies are actively looking toward heavier crude oil sources to help meet demands and to take advantage of large heavy oil reserves located in North and South America. Heavy oil includes very viscous oil resources like those found in some fields in California and Venezuela, oil shale, and tar sands (called oil sands in Canada). These are described in more detail in the next chapter. Water is integrally associated with conventional oil production. Produced water is the largest byproduct associated with oil production. The cost of managing large volumes of produced water is an important component of the overall cost of producing oil. Most mature oil fields rely on injected water to maintain formation pressure during production. The processes involved with heavy oil production often require external water supplies for steam generation, washing, and other steps. While some heavy oil processes generate produced water, others generate different types of industrial wastewater. Management and disposition of the wastewater presents challenges and costs for the operators. This report describes water requirements relating to heavy oil production and potential sources for that water. The report also describes how water is used and the resulting water quality impacts associated with heavy oil production.

  5. Review on the national and regional response to oil spill in the Arabian Gulf

    International Nuclear Information System (INIS)

    Fakhro, K.M.

    1991-01-01

    Over the past decades, the oil industry has grown enormously, resulting in a considerable number of island's oil and gas fields being fully developed. Over 30% of all oil carried by ships is produced in this region. It is exported through a narrow bottle-neck passage, Straight of Hormuz creating a continuous heavy traffic that increases the daily risk potential for ships collision, grounding or explosion that threaten the marine environment and the economy of the coastal states, should a major oil spill occur anytime. The paper reviews some major spills in the area and the action taken by the responsible authorities. The high risk potential of pollution by oil or any other harmful substances in the Arabian Gulf always exists and the need for a competent national and regional bodies was felt necessary to co-ordinate efforts in combating or mitigating marine oil pollution. The paper reviews and discusses the status of such bodies and concludes with an emphasis on strengthening them

  6. Producing deep-water hydrocarbons

    International Nuclear Information System (INIS)

    Pilenko, Thierry

    2011-01-01

    Several studies relate the history and progress made in offshore production from oil and gas fields in relation to reserves and the techniques for producing oil offshore. The intention herein is not to review these studies but rather to argue that the activities of prospecting and producing deep-water oil and gas call for a combination of technology and project management and, above all, of devotion and innovation. Without this sense of commitment motivating men and women in this industry, the human adventure of deep-water production would never have taken place

  7. AN OVERVIEW OF GAS-UPGRADING TECHNOLOGIES FOR BIOHYDROGEN PRODUCED FROM TREATMENT OF PALM OIL MILL EFFLUENT

    Directory of Open Access Journals (Sweden)

    IZZATI NADIA MOHAMAD

    2017-03-01

    Full Text Available To date, a high energy demand has led to massive research efforts towards improved gas-separation techniques for more energy-efficient and environmenttally friendly methods. One of the potential alternative energies is biogas produced from the fermentation of liquid waste generated from the oil-extraction process, which is known as palm oil mill effluent (POME. Basically, the gas produced from the POME fermentation process consists mainly of a CO2 and H2 gas mixture. CO2 is known as an anthropogenic greenhouse gas, which contributes towards the climate change phenomenon. Hence, it is crucial to determine a suitable technique for H2 separation and purification with good capability for CO2 capture, as this will reduce CO2 emission to the environment as well. This paper reviewed the current gas-separation techniques that consist of absorption, adsorption and a membrane in order to determine the advantages and disadvantages of these techniques towards the efficiency of the separation system. Crucial aspects for gas-separation techniques such as energy, economic, and environmental considerations are discussed, and a potential biohydrogen and biogas-upgrading technique for industrial POME application is presented and concluded in this paper. Based on the comparison on these aspects, water scrubbing is found to be the best technique to be used in the biogas-upgrading industry, followed by membrane and chemical scrubbing as well as PSA. Hence, these guidelines are justified for selecting the best gas-upgrading technique to be used in palm oil mill industry applications.

  8. The voice of Canada's oil and natural gas industry : oil and natural gas

    International Nuclear Information System (INIS)

    2001-04-01

    The Canadian Association of Petroleum Producers (CAPP) represents 150 members of the oil and gas industry, which together are responsible for approximately 95 per cent of the oil and natural gas produced in Canada. The upstream sector comprises companies that explore for, develop and produce petroleum resources, while the downstream sector involves companies that refine and market the resources. CAPP works closely with governments of 11 of Canada's 13 provinces and territories and with public groups to represent upstream producers active across the country. The enhancement of the economic well-being and sustainability of the upstream petroleum industry is the mission of the CAPP. The main priorities of the CAPP are: Environment, Health and Safety Stewardship, reasonable and timely access to resources, competitiveness of the Canadian industry on a global basis, the secure and efficient access to markets, and open and constructive public, government and media affairs. Some of the issues dealt with by the CAPP are sour gas, flaring, venting and industry-landowner relations, improved safety performance, federal issues such as corporate taxes and environmental issues, Aboriginal and First Nations issues, transportation costs for natural gas on major pipelines, and oil and sands bitumen issues, to name a few. The board of the CAPP is made up of 32 members. The work is carried out by hundreds of volunteers from member companies who provide their time and expertise for various committees and working groups, as well as a staff of approximately 40 people to assist them. The members provide the entire funding for CAPP, which is located in Calgary, Alberta. The document concluded with a few facts concerning the petroleum industry in general. 12 figs

  9. Investigation on the Influence of Bio-catalytic Enzyme Produced from Fruit and Vegetable Waste on Palm Oil Mill Effluent

    Science.gov (United States)

    Rasit, Nazaitulshila; Chee Kuan, Ooi

    2018-04-01

    Pre-consumer waste from supermarkets, such as vegetables and fruits dreg are always discarded as solid waste and disposed to landfill. Implementing waste recovery method as a form of waste management strategy will reduce the amount of waste disposed. One of the ways to achieve this goal is through fermentation of the pre-consumer supermarket waste to produce a solution known as garbage enzyme. This study has been conducted to produce and characterize biocatalytic garbage enzyme and to evaluate its influence on palm oil mill effluent as a pre-treatment process before further biological process takes place. Garbage enzyme was produced by three-month long fermentation of a mixture of molasses, pre-consumer supermarket residues, and water in the ratio of 1:3:10. Subsequently, the characterization of enzyme was conducted based on pH, total solids (TS), total suspended solids (TSS), total dissolved solids (TDS), chemical oxygen demand (COD), and enzyme activities. The influence of produced enzyme was evaluated on oil & grease (O&G), TSS and COD of palm oil mill effluent (POME). Different levels of dilution of garbage enzyme to POME samples (5%, 10%, 15%) were explored as pre-treatment (duration of six days) and the results showed that the garbage enzyme contained bio-catalytic enzyme such as amylase, protease, and lipase. The pre-treatment showed removal of 90% of O&G in 15% dilution of garbage enzyme. Meanwhile, reduction of TSS and COD in dilution of 10% garbage enzyme were measured at 50% and 25% respectively. The findings of this study are important to analyse the effectiveness of pre-treatment for further improvement of anaerobic treatment process of POME, especially during hydrolysis stage.

  10. Synthesis, characterization, and oil recovery application of biosurfactant produced by indigenous pseudomonas aeruginosa WJ-1 using waste vegetable oils.

    Science.gov (United States)

    Xia, Wen-Jie; Luo, Zhi-Bin; Dong, Han-Ping; Yu, Li; Cui, Qing-Feng; Bi, Yong-Qiang

    2012-03-01

    A bacterial strain was isolated and cultured from the oil excavation areas in tropical zone in northern China. The biochemical characteristics and partial sequenced 16S rRNA gene of isolate, WJ-1, was identical to those of cultured representatives of the species Pseudomonas aeruginosa. This bacterium was able to produce a type of biosurfactant. Compositional analysis revealed that the extracted biosurfactant was composed of high percentage lipid (∼74%, w/w) and carbohydrate (∼20%, w/w) in addition to a minor fraction of protein (∼6%, w/w). The best production of 50.2 g/l was obtained when the cells were grown on minimal salt medium containing 6.0% (w/v) glucose and 0.75% (w/v) sodium nitrate supplemented with 0.1% (v/v) element solution at 37 °C and 180 rpm after 96 h. The optimum biosurfactant production pH value was found to be 6.0-8.0. The biosurfactant of WJ-1, with the critical micelle concentration of 0.014 g/L, could reduce surface tension to 24.5 mN/m and emulsified kerosene up to EI(24) ≈95. The results obtained from time course study indicated that the surface tension reduction and emulsification potential was increased in the same way to cell growth. However, maximum biosurfactant production occurred and established in the stationary growth phase (after 90 h). Thin layer chromatography, Fourier transform infrared spectrum, and mass spectrum analysis indicate the extracted biosurfactant was affiliated with rhamnolipid. The core holder flooding experiments demonstrated that the oil recovery efficiency of strain and its biosurfactant was 23.02% residual oil.

  11. Indonesia palm oil production without deforestation and peat conversion by 2050.

    Science.gov (United States)

    Afriyanti, Dian; Kroeze, Carolien; Saad, Asmadi

    2016-07-01

    Palm oil is a promising source of cooking oil and biodiesel. The demand for palm oil has been increasing worldwide. However, concerns exist surrounding the environmental and socio-economic sustainability of palm oil production. Indonesia is a major palm oil producing country. We explored scenarios for palm oil production in Indonesia until 2050, focusing on Sumatra, Kalimantan and Papua. Our scenarios describe possible trends in crude palm oil production in Indonesia, while considering the demand for cooking oil and biodiesel, the available land for plantations, production capacity (for crude palm oil and fresh fruit bunches) and environmentally restricting conditions. We first assessed past developments in palm oil production. Next, we analysed scenarios for the future. In the past 20years, 95% of the Indonesian oil palm production area was in Sumatra and Kalimantan and was increasingly cultivated in peatlands. Our scenarios for the future indicate that Indonesia can meet a considerable part of the global and Asian demand for palm oil, while avoiding further cultivation of peatlands and forest. By 2050, 264-447Mt crude palm oil may be needed for cooking oil and biodiesel worldwide. In Indonesia, the area that is potentially suitable for oil palm is 17 to 26Mha with a potential production rate of 27-38t fresh fruit bunches/ha, yielding 130-176Mt crude palm oil. Thus Indonesia can meet 39-60% of the international demand. In our scenarios this would be produced in Sumatra (21-26%), Kalimantan (12-16%), and Papua (2%). The potential areas include the current oil palm plantation in mineral lands, but exclude the current oil palm plantations in peatlands. Copyright © 2016 Elsevier B.V. All rights reserved.

  12. Agrochemical characterization of vermicomposts produced from residues of Palo Santo (Bursera graveolens) essential oil extraction.

    Science.gov (United States)

    Carrión-Paladines, Vinicio; Fries, Andreas; Gómez-Muñoz, Beatriz; García-Ruiz, Roberto

    2016-12-01

    Fruits of Palo Santo (Bursera graveolens) are used for essential oil extraction. The extraction process is very efficient, because up to 3% of the fresh fruits can be transformed into essential oil; however, a considerable amount of waste is concurrently produced (>97% of the fresh biomass). Recent developments in Ecuadorian policies to foster environmentally friendly agroforestry and industrial practices have led to widespread interest in reusing the waste. This study evaluated the application of four vermicomposts (VMs), which are produced from the waste of the Palo Santo fruit distillation in combination with other raw materials (kitchen leftovers, pig manure, goat manure, and King Grass), for agrochemical use and for carbon (C) and nitrogen (N) decomposition in two soils with different textures. The results showed that the vermicompost mixtures (VMM) were valuable for agricultural utilisation, because total N (min. 2.63%) was relatively high and the C/N ratio (max. 13.3), as well as the lignin (max. 3.8%) and polyphenol (max. 1.6%) contents were low. In addition, N availability increased for both soil types after the application of the VMM. In contrast, N became immobile during decomposition if the VM of the pure waste was added. This likely occurred because of the relatively low total N (1.16%) content and high C/N ratio (35.0). However, the comparatively low C decomposition of this VM type makes its application highly recommendable as a strategy to increase the levels of organic matter and C, as well as for soil reclamation. Overall, these results suggest that the residues of the Palo Santo essential oil extraction are a potential source for vermicompost production and sustainable agriculture. Copyright © 2016 Elsevier Ltd. All rights reserved.

  13. Oil and the U.S. foreign policy

    International Nuclear Information System (INIS)

    Hegburg, A.S.

    2001-01-01

    Oil and natural gas play a major role in the formulation and implementation of U.S. foreign oil policy. It was emphasized that the U.S. oil policy will adjust in response to market developments, both political and commercial. It will also adjust to structural changes and constituency pressures. U.S. foreign oil policy has been drastically different in each of the last 3 decades. The 1970s were a period of oil crisis and shortage when OPEC producers were in control of domestic pricing and production. The defining moment was the Arab oil embargo of the United States and the Netherlands in response to the U.S. military resupply of Israel. After that moment, production and depletion policy shifted to sovereign rule. This embargo prompted many responses, one of which was the short-lived notion that the world would have to rely mostly on synthetics and alternatives to oil. The embargo prompted a multilateral consumer country cooperation, and a staged deregulation of U.S. oil prices. It also prompted a strong U.S. denunciation of Arab producers' use of the oil weapon for foreign policy reasons. The author described the many lessons learned from the 1970s and discussed the use of sanctions against Libya, Cuba and Iran and how these have become a tool to pursue U.S. national security interests or accommodate a domestic constituency. It was predicted that forthcoming changes in U.S. energy policy will reflect unilateral, bilateral and multilateral cooperation. It was noted that beyond the extensive trade and investment links between Canada and the United States, the additional Canadian component is the Alaskan gas line which is currently being considered. It was also noted that early administrative attention should be given to improving the intergovernmental relationship within the International Energy Agency

  14. Experiment on the Effects of Storage Duration of Biodiesel produced from Crude Palm Oil, Waste Cooking oil and Jatropha

    Science.gov (United States)

    Nanihar, Nadiarulah; Khalid, Amir; Mustaffa, Norrizal; Jaat, Norrizam; Sapit, Azwan; Razali, Azahari; Sunar, Norshuhaila Mohamed

    2017-10-01

    Biodiesel based on vegetable oil is an alternative that had various advantage in term of sustainability and environmental attractive compare to others conventional diesel. Biodiesel is product of any fat or oil that derived from any organic sources through a refinery process called transesterification process. This research investigates the effects of storage duration and variant ambient condition on the biodiesel properties and characteristics. In this study, there are three types of blending which is 5vol% blends ( 5vol% plant oil 95vol% diesel), 10vol% blending (10vol% plant oil and 90vol% diesel) and 15vol% blending (15vol% plant oil and 85vol% diesel) each called CPO5 (crude palm oil 5vol%), CPO10 (crude palm oil 10vol%),CPO15 (crude palm oil 15vol%), JO5 (jatropha oil 5vol%), JO10 (jatropha oil 10vol%),and JO15 (jatropha oil 15vol%) respectively. Biodiesel samples were stored at indoor condition and outdoor condition for a 3 months period. The fuel properties such as acid value, viscosity, density, water content and flash point are observed with the laboratory instrument. Flash point value and water content increased under both of indoor and outdoor condition and a steady data for viscosity and density. However, acid value at indoor condition nearly constant but increased dramatically for outdoor condition over the time.

  15. How the Addition of Spices and Herbs to Virgin Olive Oil to Produce Flavored Oils Affects Consumer Acceptance.

    Science.gov (United States)

    Issaoui, Manel; Flamini, Guido; Souid, Sondess; Bendini, Alessandra; Barbieri, Sara; Gharbi, Ines; Toschi, Tullia Gallina; Cioni, Pier Luigi; Hammami, Mohamed

    2016-06-01

    With the aim to expand the olive oil market to a larger number of consumers who are not familiar with the sensory characteristics of virgin olive oil, the use of novel products known as "flavored olive oils", obtained by adding different kind of spices and aromatic herbs, is spreading in many countries. In order to test consumer acceptability of this type of product, in a country (Tunisia) in which virgin olive oil is regularly consumed, flavored olive oils were prepared by adding aromatic extracts of thyme, oregano, a mix of herbs (used as pizza seasoning), rosemary, and basil to a monovarietal Chemlali virgin olive oil and a consumer test on 206 subjects was performed. Selected quality parameters (free acidity, peroxide number, oxidative stability, specific absorption at K232 nm and K270 nm) were also measured and no significant variations were detected. Slight differences were found concerning the content of minor compounds (chlorophylls, carotenoids and total phenols). On the other hand, notable differences were seen in the profiles of volatile compounds, which appeared to be responsible for the observed variability in consumer acceptance. Although the unflavored oil was more appreciated than the flavored ones, among the latter, thyme flavored olive oil was the most appreciated.

  16. Implementation of a World Wide Web server for the oil and gas industry

    International Nuclear Information System (INIS)

    Blaylock, R.E.; Martin, F.D.; Emery, R.

    1996-01-01

    The Gas and Oil Technology Exchange and Communication Highway (GO-TECH) provides an electronic information system for the petroleum community for exchanging ideas, data, and technology. The PC-based system fosters communication and discussion by linking the oil and gas producers with resource centers, government agencies, consulting firms, service companies, national laboratories, academic research groups, and universities throughout the world. The oil and gas producers can access the GO-TECH World Wide Web (WWW) home page through modem links, as well as through the Internet. Future GO-TECH applications will include the establishment of virtual corporations consisting of consortia of small companies, consultants, and service companies linked by electronic information systems. These virtual corporations will have the resources and expertise previously found only in major corporations

  17. Thermal enhanced oil recovery in Indonesia. Prospect of HTGR application

    International Nuclear Information System (INIS)

    Rahman, M.; Sumardiono; Lasman, A.N.; Sudarto; Prihardany, D.

    1997-01-01

    In the next future, Indonesia will face oil scarcity. The present reserves are estimated to be depleted in 20 years. However, after primary and secondary recovery processes, there are still more than 50% of original oil in place remaining in the reservoir, and this could be recovered by using tertiary recovery method or which is known as enhanced oil recovery (EOR) processes. Among the three major methods of EOR, steam flooding is a thermal recovery method into which High Temperature Reactor (HTR) module can be integrated for producing steam. However, the feasibility of application of HTR as an alternative to conventional oil-fired steam generator will depend strongly on the price of oil. This paper discusses EOR screening for Indonesian oil fields to identify the appropriate oil reservoirs for steam flooding application as well as the possibility of steam supply by HTR module. Also reviewed is the previous study on HTR application for Duri Steam Flood Project. (author). 8 refs, 6 figs, 5 tabs

  18. An evaluation of known remaining oil resources in the state of Kansas: Project on advanced oil recovery and the states. Volume 4

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1993-11-01

    The Interstate Oil and Gas Compact Commission (IOGCC) has conducted a series of studies to evaluate the known, remaining oil resource in twenty-three (23) states. The primary objective of die IOGCC`s effort is to examine the potential impact of an aggressive and focused program of research, development, and demonstration (RD&D) and technology transfer on future oil recovery in the United States. As part of a larger effort by the IOGCC, this report focuses on the potential economic benefits of improved oil recovery in the state of Kansas. Individual reports for seven other oil producing states and a national report have been separately published by the IOGCC. Several major technical insights for state and Federal policymakers and regulators can be reached from this analysis. Overall, well abandonments and more stringent environmental regulations could limit economic access to the nation`s known, remaining oil resource. The high risk of near-term abandonment and the significant benefits of future application of improved oil recovery technoloy, clearly point to a need for more aggressive transfer of currently available technologies to domestic oil producers. Development and application of advanced oil recovery technologies could leave even greater benefits to the nation. A collaborative, focused RD&D effort, integrating the resources and expertise of industry, state and local governments, and the Federal government, is clearly warranted. With effective RD&D and a program of aggressive technology transfer to widely disseminate its results, Kansas oil production could be maximized. The resulting increase in production rates, employment, operator profits, state and Federal tax revenues, energy security will benefit the state of Kansas and the nation as a whole.

  19. An evaluation of known remaining oil resources in the state of Louisiana: Project on advanced oil recovery and the states. Volume 5

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1993-11-01

    The Interstate Oil and Gas Compact Commission (IOGCC) has conducted a series of studies to evaluate the known, remaining oil resource in twenty-three (23) states. The primary objective of die IOGCC`s effort is to examine the potential impact of an aggressive and focused program of research, development, and demonstration (RD&D) and technology transfer on future oil recovery in the United States. As part of a larger effort by the IOGCC, this report focuses on the potential economic benefits of improved oil recovery in the state of Louisiana. Individual reports for seven other oil producing states and a national report have been separately published by the IOGCC. Several major technical insights for state and Federal policymakers and regulators can be reached from this analysis. Overall, well abandonments and more stringent environmental regulations could limit economic access to the nation`s known, remaining oil resource. The high risk of near-term abandonment and the significant benefits of future application of improved oil recovery technoloy, clearly point to a need for more aggressive transfer of currently available technologies to domestic oil producers. Development and application of advanced oil recovery technologies could leave even greater benefits to the nation. A collaborative, focused RD&D effort, integrating the resources and expertise of industry, state and local governments, and the Federal government, is clearly warranted. With effective RD&D and a program of aggressive technology transfer to widely disseminate its results, Louisiana oil production could be maximized. The resulting increase and improvement in production rates, employment, operator profits, state and Federal tax revenues, energy security will benefit both the state of Louisiana and the nation as a whole.

  20. Does postoperative 'M' technique (R) massage with or without mandarin oil reduce infants' distress after major craniofacial surgery?

    NARCIS (Netherlands)

    de Jong, Marjan; Lucas, Cees; Bredero, Hansje; van Adrichem, Leon; Tibboel, Dick; van Dijk, Monique

    2012-01-01

    de jong m., lucas c., bredero h., van adrichem l., tibboel d. & van dijk m. (2011) Does postoperative M technique (R) massage with or without mandarin oil reduce infants distress after major craniofacial surgery? Journal of Advanced Nursing68(6), 17481757. Abstract Aim. This article is a report of a

  1. Proceedings of the 1999 Oil and Gas Conference: Technology Options for Producer Survival

    Energy Technology Data Exchange (ETDEWEB)

    None available

    2000-04-12

    The 1999 Oil & Gas Conference was cosponsored by the U.S. Department of Energy (DOE), Office of Fossil Energy, Federal Energy Technology Center (FETC) and National Petroleum Technology Office (NPTO) on June 28 to 30 in Dallas, Texas. The Oil & Gas Conference theme, Technology Options for Producer Survival, reflects the need for development and implementation of new technologies to ensure an affordable, reliable energy future. The conference was attended by nearly 250 representatives from industry, academia, national laboratories, DOE, and other Government agencies. Three preconference workshops (Downhole Separation Technologies: Is it Applicable for Your Operations, Exploring and developing Naturally Fractured Low-Permeability Gas Reservoirs from the Rocky Mountains to the Austin Chalk, and Software Program Applications) were held. The conference agenda included an opening plenary session, three platform sessions (Sessions 2 and 3 were split into 2 concurrent topics), and a poster presentation reception. The platform session topics were Converting Your Resources Into Reserves (Sessions 1 and 2A), Clarifying Your Subsurface Vision (Session 2B), and High Performance, Cost Effective Drilling, Completion, Stimulation Technologies (Session 3B). In total, there were 5 opening speakers, 30 presenters, and 16 poster presentations.

  2. Physicochemical characterization and quality of cold-pressed peanut oil obtained from organically produced peanuts from Macedonian “Virginia” variety

    Directory of Open Access Journals (Sweden)

    Kostadinović Veličkovska, S.

    2016-03-01

    Full Text Available The physicochemical characterization and quality of cold pressed peanut edible oil from the “Virginia” variety, organically produced from the region of Macedonia, were examined in this work for the first time. The fatty acid composition of the oil showed almost equal levels of oleic and linoleic acids with an abundance of 34.19±0.01 and 36.13±0.01%, respectively. The most dominant saturated fatty acid was palmitic acid with a level of 10.06±0.00%. The level of tocopherols and other vitamin-E-related compounds was in strong agreement with the antioxidant activity of the oils measured by the DPPH assay. Almost equal amounts of α and γ tocopherols indicated an antioxidant potential of 288.63±59.78 mg·L−1 α-tocopherol. Phytosterols, as minor compounds present in the oils, can be additional antioxidants responsible for the health benefits of this oil in human nutrition. The four major pytosterols were β-sitosterol (1812.21±22.17 mg·kg−1 oil, champesterol (320.55±17.07 mg·kg−1 oil, Δ5-avenasterol (236.16±14.18 mg·kg−1 and stigmasterol (133.12±12.51 mg·kg−1 oil. Induction time, Peroxide number, FFA and specific extinction (K232 and K270, values 1.82 and 0.22 gave us an indication of the oxidative stability of cold pressed peanut oil.Se ha abordado por primera vez, en este trabajo, la caracterización físico-química y la calidad de aceite comestible de maní prensado en frío de la variedad “Virginia”, de producción ecológica y procedente de la región de Macedonia La composición de ácidos grasos del aceite mostró casi los mismos niveles de los ácidos oleico y linoleico: 34,19±0,01 y 36,13±0,01%, respectivamente. El ácido graso saturado dominante fué el palmítico, 10,06±0,00%. El nivel de tocoferoles y otros compuestos relacionados con la vitamina-E estaba en estrecha relación con la actividad antioxidante de los aceites medidos mediante el ensayo de DPPH. Casi igual cantidad de α y γ tocoferol indic

  3. Profiler : Canadian oil and gas : the First Nations : building successful partnerships

    Energy Technology Data Exchange (ETDEWEB)

    Anon.

    2010-05-15

    Canada's petroleum and natural gas is often produced in remote areas where the majority of the population is Aboriginal. Many First Nations and Metis communities are now playing an active role in Canada's oil and gas industry. Aboriginal-owned companies have earned more than $2.6 billion in the oil sands region since 1999. In 2007, the value of contracts between Alberta oil sands companies and Aboriginal companies was estimated at $606 million. This special supplement discussed First Nations partnerships in the oil and gas industry. Articles in the supplement presented new employment, training and partnership activities in the oil and gas industry as well as activities related to emerging unconventional resources. Educational programs and training facilities were described. The employment and procurement practices of leading oil and gas operators were discussed. The supplement featured presentations by several leading oil and gas companies. tabs., figs.

  4. The changing structure of the international oil industry: implications for OPEC

    International Nuclear Information System (INIS)

    Abdalla, K.L.; )

    1995-01-01

    This paper examines the changes in international oil market structure observed in the 1980s and early 1990s and assesses possible effects on oil market conditions in the future and implications for OPEC. It focuses on the trend toward a more vertical organization mainly resulting from substantial purchases of downstream assets by state owned oil companies in major oil producing countries. While the Gulf war prevented greater horizontal concentration of oil reserves, it merely interrupted the trend toward vertical concentration in the international oil industry. The vertical integration of only some of the OPEC members will cause a further divergence of goals within the organization resulting in a lower likelihood of OPEC regaining its former position as an effective cartel. If the trend toward greater vertical concentration increases, future oil prices will, in part, be affected by decisions made by vertically integrated firms. (author)

  5. Transesterification of Jatropha oil with dimethyl carbonate to produce fatty acid methyl ester over reusable Ca–La–Al mixed-oxide catalyst

    International Nuclear Information System (INIS)

    Syamsuddin, Y.; Murat, M.N.; Hameed, B.H.

    2015-01-01

    Highlights: • Transesterification of Jatropha oil over CaO-based catalyst. • Physicochemical properties of the synthesized catalyst. • Best reaction condition for FAME synthesis. • The catalyst showed high activity and stability for transesterification with Jatropha oil. - Abstract: Jatropha oil (JO) was transesterified with dimethyl carbonate (DMC) to produce fatty acid methyl ester (FAME) over synthesized Ca–La–Al mixed-oxide catalyst. The influence of different parameters on transesterification of Jatropha oil was investigated in a batch reactor. These parameters included reaction temperature (110–160 °C), reaction time (30–240 min), DMC-to-oil molar ratio (4:1–18:1) and catalyst loading amount (1–10 wt.%, based on the oil weight). The mixed-oxide catalyst with a molar ratio of 6:2:1 (Ca–La–Al) showed high catalytic activity for FAME synthesis. More than 90% of FAME was obtained under the following reaction conditions: 150 °C, reaction temperature; 180 min, reaction time; 15:1, DMC-to-oil molar ratio; and 7 wt.% amount of catalyst loading. The catalyst also exhibited high stability and could be reused for up to five cycles with less than 5% yield reduction per cycle.

  6. Environmental aspects of produced-water salt releases in onshore and coastal petroleum-producing areas of the conterminous U.S. - a bibliography

    Science.gov (United States)

    Otton, James K.

    2006-01-01

    Environmental effects associated with the production of oil and gas have been reported since the first oil wells were drilled in the Appalachian Basin in Pennsylvania and Kentucky in the early to mid-1800s. The most significant of these effects are the degradation of soils, ground water, surface water, and ecosystems they support by releases of suspended and dissolved hydrocarbons and co-produced saline water. Produced water salts are less likely than hydrocarbons to be adsorbed by mineral phases in the soil and sediment and are not subject to degradation by biologic processes. Sodium is a major dissolved constituent in most produced waters and it causes substantial degradation of soils through altering of clays and soil textures and subsequent erosion. Produced water salts seem to have the most wide-ranging effects on soils, water quality, and ecosystems. Trace elements, including boron, lithium, bromine, fluorine, and radium, also occur in elevated concentrations in some produced waters. Many trace elements are phytotoxic and are adsorbed and may remain in soils after the saline water has been flushed away. Radium-bearing scale and sludge found in oilfield equipment and discarded on soils pose additional hazards to human health and ecosystems. This bibliography includes studies from across the oil- and natural-gas-producing areas of the conterminous United States that were published in the last 80 yrs. The studies describe the effects of produced water salts on soils, water quality, and ecosystems. Also included are reports that describe (1) the inorganic chemistry of produced waters included in studies of formation waters for various purposes, (2) other sources of salt affecting water quality that may be mistaken for produced water effects, (3) geochemical and geophysical techniques that allow discrimination of salt sources, (4) remediation technologies designed to repair damage caused to soils and ground water by produced water salts, and (5) contamination by

  7. An assessment of the radiation protection programme within a major multi-national oil service company

    International Nuclear Information System (INIS)

    Nelis, P.; Simpkin, P.; Christie, K.

    2002-01-01

    In this paper we are going to look at the radiation protection programme which has been developed within one of the corporation's newer operating divisions, Baker Hughes INTEQ, which is a major supplier of drilling and real-time formation evaluation services. These enable the company to steer and drill complex wells, in the most challenging down-hole environments, into multiple target zones in oil and gas reservoirs. We will focus here on INTEQ's measurement while drilling or MWD services. These provide precise well navigation information and evaluation of the formation being drilled through, in real time, to the rig operators. Prior to the development of MWD technology, such information could only be obtained by lowering equipment into the hole after the drill had been removed, using wireline logging techniques. MWD tools carrying radioactive sources, commonly known in the oil field, albeit incorrectly, as nuclear tools, provide information on the density and porosity of the underground formation being drilled through

  8. 77 FR 5385 - Marketing Order Regulating the Handling of Spearmint Oil Produced in the Far West; Revision of...

    Science.gov (United States)

    2012-02-03

    ... the ``order.'' The order is effective under the Agricultural Marketing Agreement Act of 1937, as... DEPARTMENT OF AGRICULTURE Agricultural Marketing Service 7 CFR Part 985 [Doc. Nos. AMS-FV-10-0094; FV11-985-1A FIR] Marketing Order Regulating the Handling of Spearmint Oil Produced in the Far West...

  9. 78 FR 23673 - Marketing Order Regulating the Handling of Spearmint Oil Produced in the Far West; Revision of...

    Science.gov (United States)

    2013-04-22

    ... the ``order.'' The order is effective under the Agricultural Marketing Agreement Act of 1937, as... DEPARTMENT OF AGRICULTURE Agricultural Marketing Service 7 CFR Part 985 [Doc. Nos. AMS-FV-11-0088; FV12-985-1A FIR] Marketing Order Regulating the Handling of Spearmint Oil Produced in the Far West...

  10. Short-term outlook for Canadian crude oil to 2006 : an energy market assessment

    International Nuclear Information System (INIS)

    2005-09-01

    The National Energy Board monitors the supply of all energy commodities in Canada along with the demand for Canadian energy commodities in domestic and export markets. This report is intended to expand the effectiveness of the Board's monitoring activities by providing an assessment of the current state of the petroleum industry and the potential for growth. It provides an 18-month outlook on international and domestic crude oil prices; drilling and exploration activity; supply projections for Canadian crude oil and petroleum products; Canada's crude oil trade balance and markets for Canadian crude; existing export pipeline networks and project expansion plans; and, the Canadian petroleum products industry and the impact of higher prices. It also identifies the major issues and challenges associated with the development of Canada's crude oil. The 2 major oil producing areas in Canada are the Western Canada Sedimentary Basin (WCSB) including the oil sands, and offshore eastern Canada. While conventional production in the WCSB is declining, development focus has shifted to Alberta's oil sands as well as Hibernia, Terra Nova and White Rose, the 3 major oil fields offshore Newfoundland and Labrador. High energy prices have resulted in record profits for the Canadian oil and gas industry, and has stimulated billions of dollars in investment, with Alberta's oil sands being the main beneficiary. The 19 refineries in Canada have been operating at about 90 per cent capacity for the last several years due to strong demand for transportation fuels. 10 tabs., 37 figs., 2 appendices

  11. Manitoba 2004 oil activity review

    International Nuclear Information System (INIS)

    Fox, J.N.

    2005-01-01

    This paper presented data on oil and gas activities in Manitoba during 2004, the busiest year in Manitoba's oil patch since the mid 1980s. Increases in the leasing of Crown and freehold acreage were also noted, with accompanying increases in drilling activity for the latter part of 2004. Details of Crown land sales were presented, with a total of 43,725 hectares of crown oil and gas rights under lease. During 2004, over 15,000 hectares of Crown oil and gas leases were sold, the highest figures since 1997. More wells were licensed and drilled in 2004 than in any year since 1986. Overall drilling success rate was 96.7 per cent. Details of top drillers in Manitoba were presented, with drilling activity focused in Waskada and Daly fields and the Sinclair area. Oil production increased by 0.7 per cent, with 1474 wells in production. Daily oil production statistics were presented, with the total value of Manitoba's oil production being $196 million. Details of the top 5 producers were provided, in addition to details of horizontal well production. Recent developments in Sinclair Field, Pierson L. Amaranth MC 3b A Pool, Waskada L. Amaranth I Pool and Virden Lodgepole D Pool were reviewed. The Manitoba Drilling Incentive Program was discussed with reference to the following enhancements: new well incentives, horizontal well incentives; holiday oil volume accounts; and marginal well major workover programs. Various Oil and Gas Act amendments were reviewed. In addition, the Williston Basin Architecture and Hydrocarbon Potential Project was discussed. 3 figs

  12. Immersion piston for producing crude oil and liquids from boreholes

    Energy Technology Data Exchange (ETDEWEB)

    Fekete, I; Hornyos, J

    1967-02-09

    When using a free piston to pump an oil well, oil and gas accumulates above and below the piston; upon venting the gas pressure above the piston, the gas pressure below it drives the piston and the oil above it to the surface. In the past, such pistons were too heavy and did not run tight in the tubing, causing loss of efficiency and high gas consumption. According to this invention, the piston is made of aluminum or plastic; it consists of at least 2 parts flexibly connected by wire rope or plastic strings, and is equipped with a labyrinth gasket and a paraffin scraper. (3 claims)

  13. 7 CFR 985.56 - Excess oil.

    Science.gov (United States)

    2010-01-01

    ... 7 Agriculture 8 2010-01-01 2010-01-01 false Excess oil. 985.56 Section 985.56 Agriculture... HANDLING OF SPEARMINT OIL PRODUCED IN THE FAR WEST Order Regulating Handling Volume Limitations § 985.56 Excess oil. Oil of any class in excess of a producer's applicable annual allotment shall be identified as...

  14. A case study of pyrolysis of oil palm wastes in Malaysia

    Science.gov (United States)

    Abdullah, Nurhayati; Sulaiman, Fauziah; Aliasak, Zalila

    2013-05-01

    Biomass seems to have a great potential as a source of renewable energy compared with other sources. The use of biomass as a source of energy could help to reduce the wastes and also to minimize the dependency on non-renewable energy, hence minimize environmental degradation. Among other types of biomass, oil palm wastes are the major contribution for energy production in Malaysia since Malaysia is one of the primary palm oil producers in the world. Currently, Malaysia's plantation area covers around 5 million hectares. In the oil palm mill, only 10% palm oil is produced and the other 90% is in the form of wastes such as empty fruit bunches (EFB), oil palm shells (OPS), oil palm fibre (OPFb) and palm oil mill effluent (POME). If these wastes are being used as a source of renewable energy, it is believed that it will help to increase the country's economy. Recently, the most potential and efficient thermal energy conversion technology is pyrolysis process. The objective of this paper is to review the current research on pyrolysis of oil palm wastes in Malaysia. The scope of this paper is to discuss on the types of pyrolysis process and its production. At present, most of the research conducted in this country is on EFB and OPS by fast, slow and microwave-assisted pyrolysis processes for fuel applications.

  15. Effects of oil drops containing Lactobacillus salivarius WB21 on periodontal health and oral microbiota producing volatile sulfur compounds.

    Science.gov (United States)

    Suzuki, Nao; Tanabe, Kazunari; Takeshita, Toru; Yoneda, Masahiro; Iwamoto, Tomoyuki; Oshiro, Sueko; Yamashita, Yoshihisa; Hirofuji, Takao

    2012-03-01

    The objective of this paper is to evaluate the effects of oil drops containing Lactobacillus salivarius WB21 on periodontal health and oral microbiota producing volatile sulfur compounds (VSCs). For this study, 42 subjects were randomly assigned to receive oil samples containing L. salivarius WB21 or a placebo for two weeks. Oral assessment and saliva collection were performed on days 1 and 15. Bacterial analysis was performed using the real-time polymerase chain reaction and terminal restriction fragment length polymorphism (T-RFLP). In both the experimental and placebo groups, the average probing depth, number of periodontal pockets, and the percentage of bleeding on probing (BOP) decreased while stimulated salivary flow increased on day 15. BOP was reduced in the experimental group compared with the placebo group (P = 0.010). In the experimental group, total bacterial numbers decreased, and the number of L. salivarius increased. The number of Prevotella intermedia, which is correlated with hydrogen sulfide concentration in mouth air, increased in the placebo group and did not change in the experimental group. T-RFLP analysis found that the peak area proportions representing Porphyromonas gingivalis, P. intermedia, Tannerella forsythensis, and Fusobacterium nucleatum decreased in the experimental group, although there was no significant change in the bacterial composition. Thus we observed oil drops containing L. salivarius WB21 improved BOP and inhibited the reproduction of total and VSC-producing periodontopathic bacteria compared with the placebo group, but also showed the limit of its efficacy in controlling VSCs producing and periodontal pathogens.

  16. Life-Cycle Assessment of Pyrolysis Bio-Oil Production*

    Energy Technology Data Exchange (ETDEWEB)

    Steele, Philip; Puettmann, Maureen E.; Penmetsa, Venkata Kanthi; Cooper, Jerome E.

    2012-07-01

    As part ofthe Consortium for Research on Renewable Industrial Materials' Phase I life-cycle assessments ofbiofuels, lifecycle inventory burdens from the production of bio-oil were developed and compared with measures for residual fuel oil. Bio-oil feedstock was produced using whole southern pine (Pinus taeda) trees, chipped, and converted into bio-oil by fast pyrolysis. Input parameters and mass and energy balances were derived with Aspen. Mass and energy balances were input to SimaPro to determine the environmental performance of bio-oil compared with residual fuel oil as a heating fuel. Equivalent functional units of 1 MJ were used for demonstrating environmental preference in impact categories, such as fossil fuel use and global warming potential. Results showed near carbon neutrality of the bio-oil. Substituting bio-oil for residual fuel oil, based on the relative carbon emissions of the two fuels, estimated a reduction in CO2 emissions by 0.075 kg CO2 per MJ of fuel combustion or a 70 percent reduction in emission over residual fuel oil. The bio-oil production life-cycle stage consumed 92 percent of the total cradle-to-grave energy requirements, while feedstock collection, preparation, and transportation consumed 4 percent each. This model provides a framework to better understand the major factors affecting greenhouse gas emissions related to bio-oil production and conversion to boiler fuel during fast pyrolysis.

  17. 7 CFR 985.58 - Exempt oil.

    Science.gov (United States)

    2010-01-01

    ... 7 Agriculture 8 2010-01-01 2010-01-01 false Exempt oil. 985.58 Section 985.58 Agriculture... HANDLING OF SPEARMINT OIL PRODUCED IN THE FAR WEST Order Regulating Handling Volume Limitations § 985.58 Exempt oil. Oil held by a producer or handler on the effective date of this subpart shall not be...

  18. POLICY ANALYSIS OF PRODUCED WATER ISSUES ASSOCIATED WITH IN-SITU THERMAL TECHNOLOGIES

    Energy Technology Data Exchange (ETDEWEB)

    Robert Keiter; John Ruple; Heather Tanana

    2011-02-01

    Commercial scale oil shale and oil sands development will require water, the amount of which will depend on the technologies adopted and the scale of development that occurs. Water in oil shale and oil sands country is already in scarce supply, and because of the arid nature of the region and limitations on water consumption imposed by interstate compacts and the Endangered Species Act, the State of Utah normally does not issue new water rights in oil shale or oil sands rich areas. Prospective oil shale and oil sands developers that do not already hold adequate water rights can acquire water rights from willing sellers, but large and secure water supplies may be difficult and expensive to acquire, driving oil shale and oil sands developers to seek alternative sources of supply. Produced water is one such potential source of supply. When oil and gas are developed, operators often encounter ground water that must be removed and disposed of to facilitate hydrocarbon extraction. Water produced through mineral extraction was traditionally poor in quality and treated as a waste product rather than a valuable resource. However, the increase in produced water volume and the often-higher quality water associated with coalbed methane development have drawn attention to potential uses of produced water and its treatment under appropriations law. This growing interest in produced water has led to litigation and statutory changes that must be understood and evaluated if produced water is to be harnessed in the oil shale and oil sands development process. Conversely, if water is generated as a byproduct of oil shale and oil sands production, consideration must be given to how this water will be disposed of or utilized in the shale oil production process. This report explores the role produced water could play in commercial oil shale and oil sands production, explaining the evolving regulatory framework associated with produced water, Utah water law and produced water regulation

  19. GLOBAL PROSPECTS OF SYNTHETIC DIESEL FUEL PRODUCED FROM HYDROCARBON RESOURCES IN OIL&GAS EXPORTING COUNTRIES

    OpenAIRE

    Kurevija, Tomislav; Kukulj, Nenad; Rajković, Damir

    2007-01-01

    Production of synthetic diesel fuel through Fischer-Tropsch process is a well known technology which dates from II World War, when Germany was producing transport fuel from coal. This process has been further improved in the South Africa due to period of international isolation. Today, with high crude oil market cost and increased demand of energy from China and India, as well as global ecological awareness and need to improve air quality in urban surroundings, many projects are being planned...

  20. 17 CFR 210.4-10 - Financial accounting and reporting for oil and gas producing activities pursuant to the Federal...

    Science.gov (United States)

    2010-04-01

    ... 17 Commodity and Securities Exchanges 2 2010-04-01 2010-04-01 false Financial accounting and... of General Application § 210.4-10 Financial accounting and reporting for oil and gas producing... section prescribes financial accounting and reporting standards for registrants with the Commission...

  1. Oil use and oil dependency: Long-term issues

    International Nuclear Information System (INIS)

    Serot, D.E.; Belzer, D.B.; Guthrie, S.A.; Roop, J.M.

    1989-06-01

    The continued dependence of the United States on imported oil is a matter of increasing concern. Under the direction of the Department of Energy's Office of Policy Integration, Pacific Northwest Laboratory conducted a study which was to examine long-term issues related to oil dependence. Major issues addressed are (1) energy efficiency and the role of new technologies, (2) fuel switching, and (3) regional factors affecting fuel use. The study examines all major end-use sectors in the economy, covering the industrial, commercial, residential, transportation, and electric utility sectors. The potential impacts of efficiency improvements in oil- using equipment are assessed through the year 2000. 107 refs., 8 figs., 9 tabs

  2. Effects of cooking method, cooking oil, and food type on aldehyde emissions in cooking oil fumes.

    Science.gov (United States)

    Peng, Chiung-Yu; Lan, Cheng-Hang; Lin, Pei-Chen; Kuo, Yi-Chun

    2017-02-15

    Cooking oil fumes (COFs) contain a mixture of chemicals. Of all chemicals, aldehydes draw a great attention since several of them are considered carcinogenic and formation of long-chain aldehydes is related to fatty acids in cooking oils. The objectives of this research were to compare aldehyde compositions and concentrations in COFs produced by different cooking oils, cooking methods, and food types and to suggest better cooking practices. This study compared aldehydes in COFs produced using four cooking oils (palm oil, rapeseed oil, sunflower oil, and soybean oil), three cooking methods (stir frying, pan frying, and deep frying), and two foods (potato and pork loin) in a typical kitchen. Results showed the highest total aldehyde emissions in cooking methods were produced by deep frying, followed by pan frying then by stir frying. Sunflower oil had the highest emissions of total aldehydes, regardless of cooking method and food type whereas rapeseed oil and palm oil had relatively lower emissions. This study suggests that using gentle cooking methods (e.g., stir frying) and using oils low in unsaturated fatty acids (e.g., palm oil or rapeseed oil) can reduce the production of aldehydes in COFs, especially long-chain aldehydes such as hexanal and t,t-2,4-DDE. Copyright © 2016 Elsevier B.V. All rights reserved.

  3. The separation of stable water-in-oil emulsions

    International Nuclear Information System (INIS)

    Velicogna, D.; Koundakjiian, A.; Beausejour, I.

    1993-01-01

    Stable oil-in-water emulsions are a major problem in the recovery of spilled oils. Such emulsions can contain as little as 10% oil and can have properties very different from the original oils, making their storage and disposal difficult. These problems have led to experiments testing the feasibility of a process for separating these stable emulsions into dischargeable water and reusable oil. The technique investigated involves use of a recyclable solvent to remove the oil and subsequent distillation and/or membrane treatment to recover the oil and recycle the solvent. Results of preliminary tests show that stable water-in-oil emulsions can be separated quite readily with a regenerated solvent system. The only products of these systems are oil, which can be sent to a refinery, and dischargeable water. The recycled solvent can be used many times without any significant decrease in separation efficiency. In order to enhance the throughput of the system, a solvent vapor stripping method was invented. This stripping method also improves the quality of the products and the recycled solvent. Membrane methods can be used as a post-treatment for the produced water in order to achieve more adequate compliance with discharge limits. 4 refs., 3 figs., 5 tabs

  4. Disposal of oil cuttings by downhole fracturing injections : slurry product specifications issues

    International Nuclear Information System (INIS)

    Radzuan Junin

    1994-01-01

    The technique of using on-site injection of oil contaminated drill cuttings is attracting considerable attention as a cost effective means of complying with environmental legislation concerning discharges of drilling wastes. The slurrification and injection of oil based cuttings into a casing annulus, a process developed in 1989 by a major oil and gas producer/ operator, has proven to be a significant step toward reduction of such environmental waste. This paper discusses the development of the cuttings reinjection, slurrification, slurry properties and benefits of quality slurry, and behaviour of solid laden slurries in a fracture in conjunction with down-hole disposal operations

  5. Essential oil of Artemisia vestita exhibits potent in vitro and in vivo antibacterial activity: Investigation of the effect of oil on biofilm formation, leakage of potassium ions and survival curve measurement

    Science.gov (United States)

    YANG, CHANG; HU, DONG-HUI; FENG, YAN

    2015-01-01

    The aim of the present study was to investigate the chemical composition of the essential oil of Artemisia vestita and to determine the antibacterial activity of the essential oil and its two major components, grandisol and 1,8-cineole, against certain respiratory infection-causing bacterial strains, in vitro and in vivo. The chemical composition of the essential oil was analyzed using gas chromatography-mass spectrometry. A micro-well dilution method was used to determine the minimum inhibition concentration (MIC) values of the essential oil and its major constituents. A model of Streptococcus pyogenes infection in mice was used to determine its in vivo activities. Lung and blood samples were obtained to assess bacterial cell counts. Toxicity evaluation of the essential oil and its components was completed by performing biochemical analysis of the serum, particularly monitoring aspartate transaminase, alanine transaminase, urea and creatinine. The essential oil exhibited potent antibacterial activity, whereas the two major constituents were less potent. The essential oil exhibited MIC values between 20 and 80 μg/ml, while the values of the two constituents were between 130 and 200 μg/ml. Scanning electron microscopy results demonstrated that the essential oil inhibited biofilm formation and altered its architecture. Survival curves indicated that the essential oil led to a reduction in the viability of different bacteria. The essential oil also induced significant leakage of potassium ions from S. pyogenes. The essential oil (100 μg/mouse) and grandisol (135 μg/mouse) significantly reduced the number of viable bacterial cells in the lungs (Pessential oil or grandisol 135 μg/mouse once or twice each day for 9 days did not produce any toxic effects in the mice. In conclusion, the in vitro and in vivo results suggested that the essential oil of A. vestita and one of its major constituents, grandisol, can significantly inhibit the growth of different bacterial

  6. The geopolitics of $10 oil

    International Nuclear Information System (INIS)

    Anon.

    1998-01-01

    The market and the geopolitical implications of the possibility of $10 a barrel becoming the norm for oil prices in 1999 are examined. The low price will present budgetary difficulties for all the world's major oil producing countries with the exception of Brunei. In some countries, such as Nigeria and Venezuela, general financial and economic reform will become inevitable with the pressure for political reform to follow. If energy development is to continue in the Caspian region in a low price era, long term political stability will be necessary and a move towards democracy from the present autocracies may be necessary to achieve this. In the Middle East, countries are facing the erosion of their core financial base. Depressed oil prices could force Gulf States, which in the past have depended on their oil revenues alone, to introduce taxation as an alternative source of income. Hitherto, oil has meant power in political as well as in energy terms, but the diminished value of oil in a world where their are alternative energy sources will reduce the importance, even of key regions such as the Middle East. The power of OPEC is threatened by its failure to bring about the massive co-ordinated production cutbacks which alone might turn the market around. The beneficiaries of cheap oil will be the consuming nations, particularly those of East Asia where the pace of economic recovery will be speeded up. (UK)

  7. Quality assessment of palm oil sold in major markets in Abia State ...

    African Journals Online (AJOL)

    This paper examines the quality of palm oil samples obtained from different locations in Abia State, Nigeria in terms of their physicochemical properties. The results obtained showed that the saponification value (SV) ranged from 129.04 – 198.03KOH/g of oil. The free fatty acid (FFA) of the palm oil samples ranged from 2.73 ...

  8. An energy-saving opportunity in producing lubricating oil using mixed-solventin simulated Rotary Disc Contacting (RDC) extraction tower

    Energy Technology Data Exchange (ETDEWEB)

    Hatamipour, M.S.; Fakhr Hoseini, S.M.; Tavakkoli, T.; Mehrkesh, A.H. [Chemical Engineering Department, University of Isfahan, Isfahan (Iran)

    2010-05-15

    Industrial processes are the most energy consuming processes in the world. Modification of these processes helps us with controlling the consumption of energy and minimizing energy loss. Changing raw materials is one of the ways through which we can optimize industrial processes. In this paper, a new solvent mixture (furfural + a co-solvent) was used for the extraction of lubricating base oil from lube-oil cut. It was found that the energy consumption of the new solvent mixture for obtaining a product with the same quality was much lower than the original solvent. By using this new solvent mixture, the operating temperature of the top of tower was reduced by 30 K. This leads to a high reduction in energy consumption in extraction of aromatics from lube oil. At our new extraction process by means of using new solvent mixture, the maximum energy saving was 38% per cubic meter of produced raffinate. (author)

  9. Near-Infrared Spectroscopy Combined with Multivariate Calibration to Predict the Yield of Sesame Oil Produced by Traditional Aqueous Extraction Process

    Directory of Open Access Journals (Sweden)

    Yong-Dong Xu

    2017-01-01

    Full Text Available Sesame oil produced by the traditional aqueous extraction process (TAEP has been recognized by its pleasant flavor and high nutrition value. This paper developed a rapid and nondestructive method to predict the sesame oil yield by TAEP using near-infrared (NIR spectroscopy. A collection of 145 sesame seed samples was measured by NIR spectroscopy and the relationship between the TAEP oil yield and the spectra was modeled by least-squares support vector machine (LS-SVM. Smoothing, taking second derivatives (D2, and standard normal variate (SNV transformation were performed to remove the unwanted variations in the raw spectra. The results indicated that D2-LS-SVM (4000–9000 cm−1 obtained the most accurate calibration model with root mean square error of prediction (RMSEP of 1.15 (%, w/w. Moreover, the RMSEP was not significantly influenced by different initial values of LS-SVM parameters. The calibration model could be helpful to search for sesame seeds with higher TAEP oil yields.

  10. Steam producing plant concept of 4S for oil sand extraction

    International Nuclear Information System (INIS)

    Matsuyama, Shinichiro; Nishiguchi, Youhei; Sakashita, Yoshiaki; Kasuga, Shoji; Kawashima, Masatoshi

    2009-01-01

    Plant concept of small fast reactor '4S' applying to continuous steam production for recovery of crude oil from oil sands was investigated. Assuming typical steam assisted gravity drainage (SAGD) plant whose production scale is 120,000 barrels per day of a crude oil, concept of nuclear steam supply system consisting of eight reactor modules for steam production and three reactor modules for electric generation of the 4S with a thermal rating of 135 MWt was established without any essential or significant design change from the preceding 4S with a thermal rating of 30 MWt. The 4S, provided for an oil sand extraction, will reduce greenhouse gas emission significantly, and has not much burden for development and licensing and has economic competitiveness. (author)

  11. Research of losses of oil oil and mineral oil at transportation and storage

    International Nuclear Information System (INIS)

    Akzhigitov, A.S.

    2005-01-01

    Full text : All way of hydrocarbonic raw material from a mouth of oil wells up to the consumer is accompanied by losses which occur as a result of evaporation, outflow and change of quality. Therefore preservation of quantity and quality of oil and mineral oil during transportation and storages is the major not only economic, but also an ecological problem. The facilitated fractional structure, the big maintenance concern to prominent features of the majority oil from underground salts adjournment Prycaspi in them of the easy hydrocarbons, the raised gas factor in conditions of deposits and presence in structure of gases, except for hydrocarbons and sour a component, - hydrogen sulphide, carbonic gas, etc. The superficial tests stabilized on phase structure oil depending on conditions of preparation for external transport and the subsequent processing can contain this or that quantity of residual hydrogen sulphide, easy hydrocarbons and the lowest sulfhydrates. For change of temperature and external pressure, during transportation and storage the part of easy hydrocarbons and not hydrocarbonic connections (sulfur organic) can be allocated from oil in a gaseous phase and in case of hit in an atmosphere sharply worsens ecology. In the Western Kazakhstan during the years period the temperature of air sometimes reaches up to 40-45 degrees. As is known, at such temperature there is a strengthened warming up of the open surface of oil tanks, that finally leads to increase evaporation easy oil and oil hydrocarbons. With this purpose experiences by quantitative definition evaporation lungs oil and petromixes of the Western Kazakhstan were spent. As a result of the lead works it is found out, that the size of losses at the given fixed temperature depends on evaporation by nature, fractional and hydrocarbonic structures of oil

  12. Oil and gas business in changing times

    Directory of Open Access Journals (Sweden)

    Brasoveanu Sergiu

    2017-07-01

    Full Text Available The top 5 oil majors (British Petroleum, ExxonMobil, Total, Chevron and Royal Dutch Shell are analyzed in terms of investments, earnings and financial & operational performance along the entire business value chain, for a period of 5 years. One of the key objectives is to understand how the Upstream and Downstream segments may play different roles in the definition of a winning corporate strategy, considering how they may reveal very different strengths and weaknesses during crude oil price crises. When the crude oil price goes down, the upstream sector is running big cost cutting measures, in order to reduce expenditures and keep acceptable gross margins per barrel of oil equivalent. On the other hand, the downstream segment receives cheaper raw material without a significant decrease in the final price of the oil products. Thus, how can oil companies leverage this flexibility in order to pass successfully through periods of crude oil price slides, and even take advantage of those? The paper aims to analyze the correlation between oil price and oil volume produced on one hand, and investments and earnings, split by business segments, on the other hand. The variation of investment and earnings is hence compared to crude oil price fluctuations for a clearer picture of the business profitability per segment during the peak and bottom periods of the oil market. Upstream and Downstream segments are also benchmarked against each other to understand the role that each of them is playing in the industry. The results are expected to provide some trend lines to understand how much the cost cutting measures are impacting the overall business, as well as to appreciate whether the reduction in the oil production, which in theory should be followed by a rise in prices, is indeed in the best interest of the oil majors. Going further into analysis, the paper is trying to define an optimum production interval, that will maximize profits along the entire value

  13. Development of new antioxidant systems for frying oil and omega-3 oils

    Science.gov (United States)

    The development of natural antioxidant systems for frying oil will be discussed in this presentation. This study aimed to utilize vegetable oils such as soybean oil for frying, of which the United States is the world’s largest producer. To overcome the vulnerability of soybean oil to oxidation due t...

  14. Oil shale activities in China

    International Nuclear Information System (INIS)

    Peng, D.; Jialin, Q.

    1991-01-01

    China has abundant oil shale resources, of the Early Silurian to Neogene age, the most important being the Tertiary period. The proved oil shale reserves in Fushun amount to 3.6 billion t, in Maoming 4.1 billion t. In Fushun, oil shale is produced by open-pit mining as a byproduct of coal, in Maoming it is also mined in open pits, but without coal. In China, scale oil has been produced from oil shale for 60 years. Annual production of crude shale oil amounts to about 200 000 t. The production costs of shale oil are lower than the price of crude petroleum on the world market. China has accumulated the experience and technologies of oil shale retorting. The Fushun type retort has been elaborated, in which the latent and sensible heat of shale coke is well utilized. But the capacity of such retort is relatively small, therefore it is suitable for use in small or medium oil plants. China has a policy of steadily developing shale oil industry. China is conducting oil shale research and developing oil shale processing technology. Much attention is being pay ed to the comprehensive utilization of oil shale, shale oil, and to environmental problems. In China, oil shale is mostly used for producing shale by retorting, attention will also be paid to direct combustion for power generation. Great achievements in oil shale research have been made in the eighties, and there will be a further development in the nineties. (author), 12 refs., 3 tabs

  15. The US gasoline situation and crude oil prices

    International Nuclear Information System (INIS)

    Anon.

    2004-01-01

    Before and during the United States' summer driving season, concern over the country's gasoline supply can potentially influence the direction of the petroleum market. There are three causes of concern: a persistent lack of gasoline-producing capacity; a patchwork of as many as 18 different kinds of gasoline specifications; and the introduction of stringent new specifications for reformulated gasoline. However, gasoline stocks should be able to meet the needs of this year's driving season, at a time of ample crude oil availability, with strong imports. But, unplanned outages in the US logistics system and refining centres, or major disruptions in external gasoline supplies, could trigger price spikes that would, in turn, lead to frequently stronger crude oil prices, especially with the observed robust oil demand growth in China. (Author)

  16. The role of transnational companies as oil suppliers to the United States

    International Nuclear Information System (INIS)

    Palazuelos, Enrique

    2010-01-01

    This paper analyzes the extent to which the international oil production of transnational companies meets the oil requirements of the United States. Disaggregated data from each company have been used to determine which companies (refineries) are importing crude oil, how much oil each transnational company is produced abroad, and where this production goes to. The analysis show that American international oil production represents a small part of U.S. oil imports. Two conclusions are reached. The first is that U.S. refineries buy the majority of the crude oil they process on the international market and, as a result, are dependent on the unstable conditions of this market. The second is that the economic interests the large American oil companies have abroad are far greater than those they have within the United States and, as a result, these companies do not play a decisive role in a national strategy to guarantee foreign supply.

  17. GLOBAL PROSPECTS OF SYNTHETIC DIESEL FUEL PRODUCED FROM HYDROCARBON RESOURCES IN OIL&GAS EXPORTING COUNTRIES

    Directory of Open Access Journals (Sweden)

    Tomislav Kurevija

    2007-12-01

    Full Text Available Production of synthetic diesel fuel through Fischer-Tropsch process is a well known technology which dates from II World War, when Germany was producing transport fuel from coal. This process has been further improved in the South Africa due to period of international isolation. Today, with high crude oil market cost and increased demand of energy from China and India, as well as global ecological awareness and need to improve air quality in urban surroundings, many projects are being planned regarding production of synthetic diesel fuel, known as GTL (Gas To Liquid. Most of the future GTL plants are planned in oil exporting countries, such are Qatar and Nigeria, where natural gas as by-product of oil production is being flared, losing in that way precious energy and profit. In that way, otherwise flared natural gas, will be transformed into synthetic diesel fuel which can be directly used in all modern diesel engines. Furthermore, fossil fuel transportation and distribution technology grid can be used without any significant changes. According to lower emissions of harmful gasses during combustion than fossil diesel, this fuel could in the future play a significant part of EU efforts to reach 23% of alternative fuel share till 2020., which are now mostly relied on biodiesel, LPG (liquefied petroleum gas and CNG (compressed natural gas.

  18. The information content of supplemental reserve-based replacement measures relative to that of historical cost income and its cash and accrual components of oil and gas producing companies

    International Nuclear Information System (INIS)

    Spear, N.A.

    1992-01-01

    The empirical analysis indicated that two of the three reserve-based quantity replacement measures are very useful, in terms of explaining the security returns of full cost oil and gas producing companies during the release week of the 1982-1986 annual reports or 10-K filings of these companies. The analysis also indicated that two of the three reserve-based value replacement measures are very useful, in terms of explaining the security returns of full cost oil and gas producing companies during the release week of the 1984-1986 annual reports or 10-K filings. For the period 1987-1988, the empirical analysis indicated that all of the reserve-based quantity and value replacement measures are not useful, in terms of explaining the security returns of full cost oil and gas producing companies during the release week of the annual reports or 10-K filings. The empirical analysis showed no consistent evidence to indicate any systematic difference between the implications of the cash and accrual components of earnings of either the full cost or the successful efforts oil and gas producing companies during the release week of the annual report or 10-K filings

  19. Peculiarity of radioactivity pollution of manufacturing environment gas and oil producing firms of the apsheron region

    International Nuclear Information System (INIS)

    Mamedov, A.M.; Alekperova, J.A.

    2002-01-01

    Full text: Present time protection of the biosphere from technogene pollution is the important problem, having common to all mankind value. In circuits of the technogene pollution of the environment the soil is a carrying on link for through soil the contaminants freely go to air environment, in underground waters in plants and in foodstuff of a vegetative and animal genesis. In subsequent these contaminants on the indicated chains by penetrating in an organism of the people render an ill effect on their health. In this plane the radiological contamination of soil introduces still large dangerous. As the radionuclides of soil can render as external radiation, and by getting in an organism with air, water and foodstuff can cause internal radiation. In this plane, for detection of a role of gas and oil producing firms in radiological contamination soil as object of an environment, we conduct researches by a hygienic estimation of radiological contamination of soil of territory of oil-fields OOGE 'Gum adasi' of the Apsheron region. By spectrometric method were studied a natural background radiation and radioactivity of soil of different territories of shop of complex opening-up of oil. Established, that for the raw tank the specific activity reaches 4438-9967 Bk/kg, close of the product repair shop the radioactivity reached 650- 700 micro R/hour. In territory of the region 'Gum adasi', where the waste from cleaning chisel tubes were accumulated, the radioactivity made 600 micro R/hour. These indexes the superior background level is significant. The analysis of power spectrums a gamma of radiations is model from the indicated sites has shown, that the radioactivity is conditioned by isotopes of a radium. The researches have allowed to demonstrate a radioactivity technogene of impurity of rocks to recommend urgent dumping of above-stated waste in bunkers on sites, retracted by it. Thus, was established, that gas and oil producing firms contributing to radiological

  20. The U.S. natural gas and oil resource base is abundant; but can we produce what the country needs?

    International Nuclear Information System (INIS)

    Ewing, T.E.

    1994-01-01

    Recent studies agree that the United States has abundant resources of gas and oil left to find and produce over the next 50--75 years -- if its exploration and production companies are given the resources to do the job. The NPC's estimate of 1,295 TCF of natural gas (advanced technology case) represents a resource/present production ration of 68 years. A similar estimate for oil gives 62 years. Furthermore, these resource estimates have been increasing through the 1980s, as the effects of new geological, geophysical, and engineering technologies has become more apparent. However, only 30% of this tremendous resource will be available under today's business-as-usual economic regime. The rest of the resource will be accessed if: (1) tax policies (and financial and trade policies) are adopted to stabilize prices and stimulate exploration and production (estimated 27% of the resource base); (2) technology is developed, transferred, and used (17%); (3) environmental regulation is held to a balanced level, considers economic costs as well as environmental benefits, and is applied consistently (13%); (4) access to Federal lands is eased for environmentally responsible drilling and development (13%). To convert America's gas and oil resources into delivered products in a timely manner, assuring the nation's gas users of a reliable supply -- and contribute up to $8.7 trillion to the nation's economy -- a doubling of industry effort is required, even at today's high levels of finding and producing efficiency. Coordinated action by industry, government, and the investment community is required to secure the future development of energy supplies. Government in particular must develop policies that encourage the needed investment in America's natural gas and oil

  1. Virgin olive oil yeasts: A review.

    Science.gov (United States)

    Ciafardini, Gino; Zullo, Biagi Angelo

    2018-04-01

    This review summarizes current knowledge on virgin olive oil yeasts. Newly produced olive oil contains solid particles and micro drops of vegetation water in which yeasts reproduce to become the typical microbiota of olive oil. To date, about seventeen yeast species have been isolated from different types of olive oils and their by-products, of which six species have been identified as new species. Certain yeast species contribute greatly to improving the sensorial characteristics of the newly produced olive oil, whereas other species are considered harmful as they can damage the oil quality through the production of unpleasant flavors and triacylglycerol hydrolysis. Studies carried out in certain yeast strains have demonstrated the presence of defects in olive oil treated with Candida adriatica, Nakazawaea wickerhamii and Candida diddensiae specific strains, while other olive oil samples treated with other Candida diddensiae strains were defect-free after four months of storage and categorized as extra virgin. A new acetic acid producing yeast species, namely, Brettanomyces acidodurans sp. nov., which was recently isolated from olive oil, could be implicated in the wine-vinegary defect of the product. Other aspects related to the activity of the lipase-producing yeasts and the survival of the yeast species in the flavored olive oils are also discussed. Copyright © 2017 Elsevier Ltd. All rights reserved.

  2. Sleeving-back of horizontal wells to control downstream oil saturation and improve oil recovery

    Energy Technology Data Exchange (ETDEWEB)

    Greaves, M.; Saghr, A. M. [Bath Univ (United Kingdom)

    1998-12-31

    Air injection has become popular as an enhanced recovery technology, applicable over a wide variety of reservoir conditions including heavy, medium and light oils. One problem observed in light oil reservoirs is the tendency to desaturate the oil layer downstream of the moving front. This is particularly common in the case of thermal recovery processes. In this experiment designed to study ways to restrict the de-saturation of the oil layer, a modified horizontal producer well, incorporating a `sleeve-back` principal was used. The objective was to replicate the `toe-to-heel` displacement process occurring during heavy oil recovery, wherein downstream oil is essentially immobile due to its high viscosity. The `sleeve-back` of the well was achieved using a co-aligned, two-well assembly, so that the upstream section of the horizontal producer well was active, and continuously adjusted during propagation of the combustion front. The use of this continuous `sleeve-back` operation to control the level of de-saturation in the downstream section of a sand pack was successful as confirmed by the very high oil recovery achieved, equivalent to 93.5 per cent of oil in place. The level of CO{sub 2} production was also very high. The `sleeve-back` of the horizontal producer well made the light oil in-situ combustion more efficient compared to what would be expected in a fully-open well. The `sleeve-back` of the well also produced thermal contours in the sand pack that closely resembled those observed with heavy, highly viscous oil. By sealing-off the otherwise open well in the downstream part of the reservoir, the de-saturation of the oil layer was prevented. 9 refs., 4 tabs., 9 figs.

  3. Artificial weathering of oils by rotary evaporator

    International Nuclear Information System (INIS)

    Fieldhouse, B.; Hollebone, B.P.; Singh, N.R.; Tong, T.S.; Mullin, J.

    2009-01-01

    Oil weathering has a considerable affect on the behaviour, impact and ultimate fate of an oil spill. As such, efforts have been made to study weathering as a whole using bench-scale procedures. The studies are generally divided into individual processes where the effect of other major processes are introduce as an amended sample input rather than a concurrent process. The weathering process that has the greatest effect immediately following an oil spill is evaporation, particularly for lighter oils. The rotary evaporator apparatus offers a convenient means of producing artificially weathered oil for laboratory studies. This paper reported on a study that examined the representativeness of samples obtained by this method compared to pan evaporation and the impact of changes to the apparatus or method parameters on sample chemistry. Experiments were performed on Alberta Sweet Mixed Blend no. 5 in a rotary evaporator under varying conditions of temperature and air flow at ambient pressure using 2 apparatus. The rate of mass loss increased with temperature and air flow rate as expected, but the quantitative relationships could not be defined from the data due to contributions by other uncontrolled factors. It was concluded that the rotary evaporator is not suited for evaporation rate studies, but rather for producing samples suitable for use in other studies. Chemical analysis showed that the relative abundance distributions of target n-alkane hydrocarbons varied with the degree of weathering of an oil in a consistent manner at ambient pressure, regardless of the temperature, rate of air exchange or other factors related to the apparatus and procedure. The composition of the artificially weathered oil was also consistent with that from an open pan simulation of a weathered oil slick. Loss of water content varied with the conditions of evaporation because of the differential rates of evaporation due to relative humidity considerations. It was concluded that weathering

  4. Two-stage hydroprocessing of synthetic crude gas oil

    Energy Technology Data Exchange (ETDEWEB)

    Mahay, A.; Chmielowiec, J.; Fisher, I.P.; Monnier, J. (Petro-Canada Products, Missisauga, ON (Canada). Research and Development Centre)

    1992-02-01

    The hydrocracking of synthetic crude gas oils (SGO), which are commercially produced from Canadian oil sands, is strongly inhibited by nitrogen-containing species. To alleviate the pronounced effect of these nitrogenous compounds, SGO was hydrotreated at severe conditions prior to hydrocracking to reduce its N content from 1665 to about 390 ppm (by weight). Hydrocracking was then performed using a commercial nickel-tungsten catalyst supported on silica-alumina. Two-stage hydroprocessing of SGO was assessed in terms of product yields and quality. As expected, higher gas oil conversion were achieved mostly from an increase in naphtha yield. The middle distillate product quality was also clearly improved as the diesel fuel cetane number increased by 13%. Diesel engine tests indicated that particulate emissions in exhaust gases were lowered by 20%. Finally, pseudo first-order kinetic equations were derived for the overall conversion of the major gas oil components. 17 refs., 2 figs., 8 tabs.

  5. Oil price, biofuels and food supply

    International Nuclear Information System (INIS)

    Timilsina, Govinda R.; Mevel, Simon; Shrestha, Ashish

    2011-01-01

    The price of oil could play a significant role in influencing the expansion of biofuels, but this issue has yet to be fully investigated in the literature. Using a global computable general equilibrium (CGE) model, this study analyzes the impact of oil price on biofuel expansion, and subsequently, on food supply. The study shows that a 65% increase in oil price in 2020 from the 2009 level would increase the global biofuel penetration to 5.4% in 2020 from 2.4% in 2009. If oil prices rise 150% from their 2009 levels by 2020, the resulting penetration of biofuels would be 9%, which is higher than that would be caused by current mandates and targets introduced in more than forty countries around the world. The study also shows that aggregate agricultural output drops due to an oil price increase, but the drop is small in major biofuel producing countries as the expansion of biofuels would partially offset the negative impacts of the oil price increase on agricultural outputs. An increase in oil price would reduce global food supply through direct impacts as well as through the diversion of food commodities and cropland towards the production of biofuels. - Highlights: ► A global CGE model to analyze impacts of oil price on biofuels and food supply. ► Global biofuel penetration increases from 2.4% (2009) to 5.4% (2020) in baseline. ► A 150% rise of oil price boosts biofuels more than current mandates and targets do. ► Biofuels partially offset drops in agricultural outputs caused by oil price rise. ► Biofuels as well as oil price rise negatively affect global food supply.

  6. Lipase-catalyzed acidolysis of canola oil with caprylic acid to produce medium-, long- and medium-chain-type structured lipids

    DEFF Research Database (Denmark)

    Wang, Yingyao; Xia, Luan; Xu, Xuebing

    2012-01-01

    Lipase-catalyzed acidolysis of canola oil with caprylic acid was performed to produce structured lipids (SLs) containing medium-chain fatty acid (M) at position sn-1,3 and long-chain fatty acid (L) at the sn-2 position in a solvent-free system. Six commercial lipases from different sources were...

  7. Recovery of oil from underground drill sites

    International Nuclear Information System (INIS)

    Streeter, W.S.; Hutchinson, T.S.; Ameri, S.; Wasson, J.A.; Aminian, K.

    1991-01-01

    This paper reports that a significant quantity of oil is left in reservoirs after conventional oil recovery techniques have been applied. In West Virginia and Pennsylvania alone, this oil has been estimated at over 4.5 billion barrels (0.72 billion m 3 ). Conventional recovery methods are already being used when applicable. But a new recovery method is needed for use in reservoirs that have been abandoned. One alternative method for recovery of the residual oil is known as oil recovery from underground drill sites. This recovery technology is a combination of proven methods and equipment from the petroleum, mining, and civil construction industries. Underground oil recovery can be an economically viable method of producing oil. This has been shown in producing fields, field tests, and feasibility, studies. Faced with decreasing domestic oil production, the petroleum industry should give serious consideration to the use of oil recovery from underground drill sites as a safe, practical, and environmentally sensitive alternative method of producing oil from many reservoirs

  8. Sulfate-Reducing Prokaryotes from North Sea Oil reservoirs; organisms, distribution and origin

    Energy Technology Data Exchange (ETDEWEB)

    Beeder, Janiche

    1997-12-31

    During oil production in the North Sea, anaerobic seawater is pumped in which stimulates the growth of sulphate-reducing prokaryotes that produce hydrogen sulphide. This sulphide causes major health hazards, economical and operational problems. As told in this thesis, several strains of sulphate reducers have been isolated from North Sea oil field waters. Antibodies have been produced against these strains and used to investigate the distribution of sulphate reducers in a North Sea oil reservoir. The result showed a high diversity among sulphate reducers, with different strains belonging to different parts of the reservoir. Some of these strains have been further characterized. The physiological and phylogenetic characterization showed that strain 7324 was an archaean. Strain A8444 was a bacterium, representing a new species of a new genus. A benzoate degrading sulphate reducing bacterium was isolated from injection water, and later the same strain was detected in produced water. This is the first field observations indicating that sulphate reducers are able to penetrate an oil reservoir. It was found that the oil reservoir contains a diverse population of thermophilic sulphate reducers able to grow on carbon sources in the oil reservoir, and to live and grow in this extreme environment of high temperature and pressure. The mesophilic sulphate reducers are established in the injection water system and in the reservoir near the injection well during oil production. The thermophilic sulphate reducers are able to grow in the reservoir prior to, as well as during production. It appears that the oil reservoir is a natural habitat for thermophilic sulphate reducers and that they have been present in the reservoir long before production started. 322 refs., 9 figs., 11 tabs.

  9. Sulfate-Reducing Prokaryotes from North Sea Oil reservoirs; organisms, distribution and origin

    Energy Technology Data Exchange (ETDEWEB)

    Beeder, Janiche

    1996-12-31

    During oil production in the North Sea, anaerobic seawater is pumped in which stimulates the growth of sulphate-reducing prokaryotes that produce hydrogen sulphide. This sulphide causes major health hazards, economical and operational problems. As told in this thesis, several strains of sulphate reducers have been isolated from North Sea oil field waters. Antibodies have been produced against these strains and used to investigate the distribution of sulphate reducers in a North Sea oil reservoir. The result showed a high diversity among sulphate reducers, with different strains belonging to different parts of the reservoir. Some of these strains have been further characterized. The physiological and phylogenetic characterization showed that strain 7324 was an archaean. Strain A8444 was a bacterium, representing a new species of a new genus. A benzoate degrading sulphate reducing bacterium was isolated from injection water, and later the same strain was detected in produced water. This is the first field observations indicating that sulphate reducers are able to penetrate an oil reservoir. It was found that the oil reservoir contains a diverse population of thermophilic sulphate reducers able to grow on carbon sources in the oil reservoir, and to live and grow in this extreme environment of high temperature and pressure. The mesophilic sulphate reducers are established in the injection water system and in the reservoir near the injection well during oil production. The thermophilic sulphate reducers are able to grow in the reservoir prior to, as well as during production. It appears that the oil reservoir is a natural habitat for thermophilic sulphate reducers and that they have been present in the reservoir long before production started. 322 refs., 9 figs., 11 tabs.

  10. Influence of extraction techniques on physical-chemical characteristics and volatile compounds of extra virgin olive oil.

    Science.gov (United States)

    Volpe, Maria Grazia; De Cunzo, Fausta; Siano, Francesco; Paolucci, Marina; Barbarisi, Costantina; Cammarota, Giancarlo

    2014-01-01

    The purpose of this study was to investigate three types of extraction methods of extra virgin olive oil (EVOO) from the same cultivar (Ortice olive cultivar): traditional or pressing (T) system, decanter centrifugation (DC) system and a patented horizontal axis decanter centrifugation (HADC) system. Oil samples were subjected to chemical analyses: free acidity, peroxide value, ultraviolet light absorption K232 and K270, total polyphenols, antioxidant capacity, volatile compounds and olfactory characteristics by electronic nose. The two centrifugation systems showed better free acidity and peroxides value but total polyphenol content was particularly high in extra virgin olive oil produced by patented HADC system. Same volatile substances that positively characterize the oil aroma were found in higher amount in the two centrifugation systems, although some differences have been detected between DC and HADC system, other were found in higher amount in extra virgin olive oil produced by T system. The electronic nose analysis confirmed these results, principal component analysis (PCA) and correlation matrix showed the major differences between EVOO produced by T and HADC system. Taken together the results showed that DC and HADC systems produce EVOO with better characteristics than T system and patented HADC is the best extraction system.

  11. Chemical Structure, Property and Potential Applications of Biosurfactants Produced by Bacillus subtilis in Petroleum Recovery and Spill Mitigation

    Science.gov (United States)

    Liu, Jin-Feng; Mbadinga, Serge Maurice; Yang, Shi-Zhong; Gu, Ji-Dong; Mu, Bo-Zhong

    2015-01-01

    Lipopeptides produced by microorganisms are one of the five major classes of biosurfactants known and they have received much attention from scientific and industrial communities due to their powerful interfacial and biological activities as well as environmentally friendly characteristics. Microbially produced lipopeptides are a series of chemical structural analogues of different families and, among them, 26 families covering about 90 lipopeptide compounds have been reported in the last two decades. This paper reviews the chemical structural characteristics and molecular behaviors of surfactin, one of the representative lipopeptides of the 26 families. In particular, two novel surfactin molecules isolated from cell-free cultures of Bacillus subtilis HSO121 are presented. Surfactins exhibit strong self-assembly ability to form sphere-like micelles and larger aggregates at very low concentrations. The amphipathic and surface properties of surfactins are related to the existence of the minor polar and major hydrophobic domains in the three 3-D conformations. In addition, the application potential of surfactin in bioremediation of oil spills and oil contaminants, and microbial enhanced oil recovery are discussed. PMID:25741767

  12. Chemical Structure, Property and Potential Applications of Biosurfactants Produced by Bacillus subtilis in Petroleum Recovery and Spill Mitigation

    Directory of Open Access Journals (Sweden)

    Jin-Feng Liu

    2015-03-01

    Full Text Available Lipopeptides produced by microorganisms are one of the five major classes of biosurfactants known and they have received much attention from scientific and industrial communities due to their powerful interfacial and biological activities as well as environmentally friendly characteristics. Microbially produced lipopeptides are a series of chemical structural analogues of different families and, among them, 26 families covering about 90 lipopeptide compounds have been reported in the last two decades. This paper reviews the chemical structural characteristics and molecular behaviors of surfactin, one of the representative lipopeptides of the 26 families. In particular, two novel surfactin molecules isolated from cell-free cultures of Bacillus subtilis HSO121 are presented. Surfactins exhibit strong self-assembly ability to form sphere-like micelles and larger aggregates at very low concentrations. The amphipathic and surface properties of surfactins are related to the existence of the minor polar and major hydrophobic domains in the three 3-D conformations. In addition, the application potential of surfactin in bioremediation of oil spills and oil contaminants, and microbial enhanced oil recovery are discussed.

  13. Artificial intelligence applications in offshore oil and gas production

    International Nuclear Information System (INIS)

    Attia, F.G.

    1994-01-01

    The field of Artificial Intelligence (AI) has gained considerable acceptance in virtually all fields, of engineering applications. Artificial intelligence is now being applied in several areas of offshore oil and gas operations, such as drilling, well testing, well logging and interpretation, reservoir engineering, planning and economic evaluation, process control, and risk analysis. Current AI techniques offer a new and exciting technology for solving problems in the oil and gas industry. Expert systems, fuzzy logic systems, neural networks and genetic algorithms are major AI technologies which have made an impact on the petroleum industry. Presently, these technologies are at different stages of maturity with expert systems being the most mature and genetic algorithms the least. However, all four technologies have evolved such that practical applications were produced. This paper describes the four major Al techniques and their many applications in offshore oil and gas production operations. A summary description of future developments in Al technology that will affect the execution and productivity of offshore operations will be also provided

  14. Challenge - oil crisis

    International Nuclear Information System (INIS)

    Vogler, O.

    1981-01-01

    After a short survey on recent developments of energy supply the risks of future energy supply and its effects are discussed. The parameters of dependence on oil-producing countries are studied and an evaluation is given on the measures which have to be taken by the Western industrialized countries in response to the dependence on oil. Further subjects are: mechanism of oil distribution in case of crisis, long-term cooperation of producer countries, measures on international level in the USA and Japan, and the energy-importing countries in the conflict area between OPEC- and industrialized countries. (UA) [de

  15. Metabolism of citral, the major constituent of lemongrass oil, in the cabbage looper, Trichoplusia ni, and effects of enzyme inhibitors on toxicity and metabolism.

    Science.gov (United States)

    Tak, Jun-Hyung; Isman, Murray B

    2016-10-01

    Although screening for new and reliable sources of botanical insecticides remains important, finding ways to improve the efficacy of those already in use through better understanding of their modes-of-action or metabolic pathways, or by improving formulations, deserves greater attention as the latter may present lesser regulation hurdles. Metabolic processing of citral (a combination of the stereoisomers geranial and neral), a main constituent of lemongrass (Cymbopogon citratus) essential oil has not been previously examined in insects. To address this, we investigated insecticidal activities of lemongrass oil and citral, as well as the metabolism of citral in larvae of the cabbage looper, Trichoplusia ni, in associations with well-known enzyme inhibitors. Among the inhibitors tested, piperonyl butoxide showed the highest increase in toxicity followed by triphenyl phosphate, but no synergistic interaction between the inhibitors was observed. Topical application of citral to fifth instar larvae produced mild reductions in food consumption, and frass analysis after 24h revealed geranic acid (99.7%) and neric acid (98.8%) as major metabolites of citral. Neither citral nor any other metabolites were found following in vivo analysis of larvae after 24h, and no significant effect of enzyme inhibitors was observed on diet consumption or citral metabolism. Copyright © 2016 Elsevier B.V. All rights reserved.

  16. No evidence found for Diels-Alder reaction products in soybean oil oxidized at the frying temperature by NMR study

    Science.gov (United States)

    It has been generally accepted that the Diels-Alder reaction mechanism is one of the major reaction mechanisms to produce dimers and polymers during heating process of vegetable oil. Soybean oil oxidized at 180 °C for 24 hrs with 1.45 surface area-to-volume ratio showed 36.1% polymer peak area in g...

  17. The anti-dermatophyte activity of Zataria multiflora essential oils.

    Science.gov (United States)

    Mahboubi, M; HeidaryTabar, R; Mahdizadeh, E

    2017-06-01

    Dermtophytes are a group of pathogenic fungi and the major cause of dermatophytosis in humans and animals. Fighting dermatophytes by natural essential oils is one important issue in new researches. In this investigation, we evaluated the anti-dermatophyte activities of three samples of Z. multiflora essential oils against dermatophytes along with analysis of chemical compositions of the essential oils and their anti-elastase activities on elastase production in dermatophytes. Carvacrol (1.5-34.4%), thymol (25.8-41.2%), carvacrol methyl ether (1.9-28.3%) and p-cymene (2.3-8.3%) were the main components of Z. multiflora essential oils. Z. multiflora essential oils (100ppm) inhibited the mycelium growth of dermatophytes (6±1.7-47.0±1.4%) and had the minimal inhibitory concentration (MIC) and minimal fungicidal concentration (MFC) values of 0.03-0.25μl/ml against dermatophytes. Essential oils inhibited elastase produced in dermatophytes and pure porcine elastase. Z. multiflora essential oils can be used as natural anti-dermatophyte agent for fighting dermatophytes in further preclinical and clinical studies. Copyright © 2017 Elsevier Masson SAS. All rights reserved.

  18. [Effect of β-cyclodextrin inclusion complex on transport of major components of Xiangfu Siwu decoction essential oil in Caco-2 cell monolayer model].

    Science.gov (United States)

    Xi, Jun-zuan; Qian, Da-wei; Duan, Jin-ao; Liu, Pei; Zhu, Yue; Zhu, Zhen-hua; Zhang, Li

    2015-08-01

    Although the essential oil of Xiangfu Siwu decoction (XFSWD) has strong pharmacological activity, its special physical and chemical properties restrict the clinical application and curative effect. In this paper, Xiangfu Siwu decoction essential oil (XFS-WO) was prepared by forming inclusion complex with β-cyclodextrin (β-CD). The present study is to investigate the effect of β-CD inclusion complex on the transport of major components of XFSWO using Caco-2 cell monolayer model, thus to research the effect of this formation on the absorption of drugs with low solubility and high permeability, which belong to class 2 in biopharmaceutics classification system. A sensitive and rapid UPLC-MS/MS method was developed for simultaneous quantification of senkyunolide A, 3-n-butylphthalide, Z-ligustilide, dehydrocostus lactone and α-cyperone, which are active compounds in XFSWO. The transport parameters were analyzed and compared in free oil and its β-CD inclusion complex. The result revealed that the formation of XFSWO/β-CD inclusion complex has significantly increased the transportation and absorption of major active ingredients than free oil. Accordingly, it can be speculated that cyclodextrin inclusion complex can improve bioavailability of poorly water-soluble drugs. Above all these mentioned researches, it provided foundation and basis for physiological disposition and pharmaceutical study of XFSWD.

  19. World electricity generation, nuclear power, and oil markets

    International Nuclear Information System (INIS)

    1990-01-01

    Striking changes have characterized the world's production and use of energy over the past 15 years. Most prominent have been the wide price fluctuations, politicization of world oil prices and supply, along with profound changes in patterns of production and consumption. This report, based on a study by energy analysts at Science Concepts, Inc., in the United States, traces changes in world energy supply since 1973-74 - the time of the first oil ''price shocks''. In so doing, it identifies important lessons for the future. The study focused in particular on the role of the electric power sector because the growth in fuel use in it has been accomplished without oil. Instead, the growth has directly displaced oil. In the pre-1973 era, the world relied increasingly on oil for many energy applications, including the production of electricity. By 1973, more than on-fourth of the world's electricity was produced by burning oil. By 1987, however, despite a large increase in electric demand, the use of oil was reigned back to generating less than 10% of the world's electricity. Nuclear power played a major role in this turnaround. From 1973-87, analysts at Science Concepts found, nuclear power displaced the burning of 11.7 billion barrels of oil world-wide and avoided US $323 billion in oil purchases

  20. Trends in real costs of crude oil production: The Middle East vs its competitors

    International Nuclear Information System (INIS)

    Stauffer, T.R.

    1993-01-01

    The costs of oil production in the major areas of the world, including both OPEC and non-OPEC countries are discussed. The success of Saudi Arabia's policy of squeezing out non-OPEC oil by unilaterally cutting prices is assessed by examining the variation in costs of production within OPEC, between OPEC and non-OPEC producers, whether there are producing areas which are cost-constrained, whether non-OPEC development has been curbed, and whether lack of capital might constrain future production, especially in OPEC states. It is concluded that low prices have been only partially successful, because in most areas the full-cycle cost of new oil production is still less than the current oil price, even allowing for a 15% rate of return. Low prices have limited new oil development only in the North Sea, the U.S. and Canada, while Oman and Malaysia continue to expand. The pace of drilling has been affected by low prices, and net increases in non-OPEC output has been forestalled. 4 figs

  1. Production of oil from Israeli oil shale

    International Nuclear Information System (INIS)

    Givoni, D.

    1993-01-01

    Oil shale can be utilized in two-ways: direct combustion to generate steam and power or retorting to produce oil or gas. PAMA has been developing both direct combustion and retorting processes. Its main effort is in the combustion. An oil shale fired steam boiler was erected in the Rotem industrial complex for demonstration purposes. PAMA has also been looking into two alternative retorting concepts - slow heating of coarse particles and fast heating of fine particles. The present paper provides operating data of oil shale processing in the following scheme: (a) retorting in moving bed, pilot and bench scale units, and (b) retorting in a fluidized bed, bench scale units. (author)

  2. Behenic acid pyrolysis to produce diesel-like hydrocarbons

    International Nuclear Information System (INIS)

    Xu, Zhi-Xiang; Liu, Peng; Xu, Gui-Sheng; He, Zhi-Xia; Ji, Heng-Song; Wang, Qian

    2017-01-01

    Highlights: • Behenic acid is a suitable bio-renewable resource to produce bio-fuel oil using catalytic cracking. • Little fraction of aromatic compounds presented in bio-fuel oil. • Carbon chain of fatty acid was cracked to form short carbon chain carboxyl firstly. • ESI FT-ICR MS experiment was an effective method to analyze bio-fuel oil heavy compounds. - Abstract: In order to obtain diesel-like bio-fuel oil, behenic acid was selected to carry out fast pyrolysis. The decomposition temperature of behenic acid was in the range of 250–450 °C at 20 k/min according to TG experiment. The bio-fuel oil mainly contained alkane, alkene and fatty acid. Components of products were C_1_3–C_2_0 hydrocarbon. Little fraction of aromatic compounds was found in bio-fuel oil. According to ESI FT-ICR MS analysis results, the oxygen containing compounds in bio-fuel oil were mainly O_2–O_4 classes, with the O_3 being the major class. According to GC–MS and ESI FT-ICR MS results, it was found that the carbon chain of behenic acid was cracked to form short carbon chain carboxyl firstly. And then decarboxylation reaction carried out. In other means carboxyl groups were more stable than carbon chain of fatty acid. The probable mechanism of O_4 species was free radical reaction. The recommended pyrolysis path was also proposed. Diesel-like bio-fuel oil can be obtained using behenic acid catalytic cracking.

  3. Multiclass pesticide determination in olives and their processing factors in olive oil: comparison of different olive oil extraction systems.

    Science.gov (United States)

    Amvrazi, Elpiniki G; Albanis, Triantafyllos A

    2008-07-23

    The processing factors (pesticide concentration found in olive oil/pesticide concentration found in olives) of azinphos methyl, chlorpyrifos, lambda-cyhalothrin, deltamethrin, diazinon, dimethoate, endosulfan, and fenthion were determined in olive oil production process in various laboratory-scale olive oil extractions based on three- or two-phase centrifugation systems in comparison with samples collected during olive oil extractions in conventional olive mills located at different olive oil production areas in Greece. Pesticide analyses were performed using a multiresidue method developed in our laboratory for the determination of different insecticides and herbicides in olive oil by solid-phase extraction techniques coupled to gas chromatography detection (electron capture detection and nitrogen phosphorus detection), optimized, and validated for olive fruits sample preparation. Processing factors were found to vary among the different pesticides studied. Water addition in the oil extraction procedure (as in a three-phase centrifugation system) was found to decrease the processing factors of dimethoate, alpha-endosulfan, diazinon, and chlorpyrifos, whereas those of fenthion, azinphos methyl, beta-endosulfan, lambda-cyhalothrin, and deltamethrin residues were not affected. The water content of olives processed was found to proportionally affect pesticide processing factors. Fenthion sulfoxide and endosulfan sulfate were the major metabolites of fenthion and endosulfan, respectively, that were detected in laboratory-produced olive oils, but only the concentration of fenthion sulfoxide was found to increase with the increase of water addition in the olive oil extraction process.

  4. Basic properties of crude rubber seed oil and crude palm oil blend as a potential feedstock for biodiesel production with enhanced cold flow characteristics

    Energy Technology Data Exchange (ETDEWEB)

    Yusup, Suzana; Khan, Modhar [Chemical Engineering Department, Universiti Teknologi PETRONAS, Bandar Seri Iskandar, 31750 Tronoh, Perak (Malaysia)

    2010-10-15

    Research and development in the field of biodiesel showed that fatty acid methyl esters synthesized from agriculture or animal oils and fats, which exhibit qualifying properties, can replace diesel fuel used in internal combustion engine. However, the industry had some downfall recently with the fluctuating prices of edible oils and increasing demand for nutritional needs. Crude rubber seed oil (CRSO) and crude palm oil (CPO) were used in this study since both can be extracted and produced locally in Malaysia from their abundant plantations. The benefits of introducing such blend are that CRSO is considered a non-edible feedstock with no major industrial utilizations that has the potential to reduce the usage of CPO in biodiesel industry and was found to enhance the cold flow characteristics when blended with CPO by reducing the saturated fatty acids in the feedstock. The oils and blends were characterized for density, kinematic viscosity, heating value, acid value, free fatty acid content, refractive index, mono-, di- and triglycerides and sulphur content. Fatty acids composition and iodine value were established for an equivolume blend of the oils. (author)

  5. Basic properties of crude rubber seed oil and crude palm oil blend as a potential feedstock for biodiesel production with enhanced cold flow characteristics

    International Nuclear Information System (INIS)

    Yusup, Suzana; Khan, Modhar

    2010-01-01

    Research and development in the field of biodiesel showed that fatty acid methyl esters synthesized from agriculture or animal oils and fats, which exhibit qualifying properties, can replace diesel fuel used in internal combustion engine. However, the industry had some downfall recently with the fluctuating prices of edible oils and increasing demand for nutritional needs. Crude rubber seed oil (CRSO) and crude palm oil (CPO) were used in this study since both can be extracted and produced locally in Malaysia from their abundant plantations. The benefits of introducing such blend are that CRSO is considered a non-edible feedstock with no major industrial utilizations that has the potential to reduce the usage of CPO in biodiesel industry and was found to enhance the cold flow characteristics when blended with CPO by reducing the saturated fatty acids in the feedstock. The oils and blends were characterized for density, kinematic viscosity, heating value, acid value, free fatty acid content, refractive index, mono-, di- and triglycerides and sulphur content. Fatty acids composition and iodine value were established for an equivolume blend of the oils.

  6. China's new oil import status underpins world's most dynamic petroleum scene

    International Nuclear Information System (INIS)

    Anon.

    1994-01-01

    China is poised to become a net importer of oil in 1994--95. That sets the stage for China importing more than 1 million b/d of crude oil and refined products on a net basis by the turn of the century. That development underpins a bigger story -- arguably the biggest story on the petroleum scene today. The turnabout that is seeing the world's fifth biggest oil producer go from significant oil exporter in recent years to major oil importer by the turn of the century points to several other truisms in the petroleum industry: That an oil demand surge in the Asia-Pacific region led by China will fuel overall world oil demand growth for years to come; that a refining and petrochemical boom in a country that accounts for about one fifth of the world's population has dramatic implications for those two industries; that privatization has gathered so much momentum in the global petroleum industry that even Communist China has embraced some form of it; that China's domestic crude supply shortfall is creating unprecedented opportunities for foreign upstream investors in one of the world's most prospective yet underexplored and underexploited regions; and that the same new openness that is distinguishing China's petroleum industry today is turning some of its state owned companies into major competitors to be reckoned with on the international scene, upstream and downstream. The paper discusses China's oil export/import balance, supply/demand outlook, policy changes, and new regulations governing export of crude oil and products

  7. The chemistry which created Green River Formation oil shale

    Energy Technology Data Exchange (ETDEWEB)

    Smith, J.W.

    1983-02-01

    The genesis pattern presented for Green River Formation oil shale explains the major observation. Deposition of relatively large quantities of hydrogen-rich organic matter in the oil shales is a natural consequence of the chemical conditions (basic water and reducing atmosphere) and the physical limitation of clastic materials developed in the stratified ancient Lake Uinta. Stability of the stratification produced the continuous deposition of the organic matter and its uniformity over the deposit. Authigenic formation of the oil-shale minerals proceeds naturally from the lake stratification, and the varve production stems from the seasonable development of organic matter. The lake's stratification produced uniform deposition over the entire area it covered, making the correlatable lateral persistence of the thin laminations a natural consequence. As the lake developed, the attack on aluminosilicates by sodium carbonate in the lake's lower layer produced a silicate skeleton protected by aluminum trihydroxide. On deposition, this aluminum-rich skeleton formed illite in quantity. As the lake became more basic, the protecting aluminum hydroxide coating dissolved amphoterically and illite production dropped at a specific point. Continual build-up of sodium carbonate and aluminate ion in the water of the lake's lower layer reached conditions which

  8. Corruption and reduced oil production: An additional resource curse factor?

    International Nuclear Information System (INIS)

    Al-Kasim, Farouk; Søreide, Tina; Williams, Aled

    2013-01-01

    Prominent contributions to the resource curse literature suggest weak governance and corruption are important factors behind the wide welfare variations observed among oil producing countries. How weak governance and corruption influence revenue management and expenditure decisions, as well as the possible welfare benefits derived from oil, are broadly discussed. How they impact upon volumes of oil produced has, however, attracted little attention. This paper combines a review of the resource curse and oil production literatures with findings from qualitative interviews with oil sector experts to appreciate the feasibility of connections between corruption and oil production below its potential. We make particular reference to environments where regulatory institutions or political accountability are weak and focus primarily on producer government and oil firm relations. Drawing on insights from geology, political science and economics, we suggest suboptimal production solutions can impact volumes of oil actually produced and create constraints on long term revenues for oil producing countries. We argue greater disclosure of information on oil production efficiency on a field-by-field and country-by-country basis will assist further investigation of the relationships between corruption and volumes of oil produced. - Highlights: ► We combine a literature review with qualitative interviews with oil experts. ► We focus on feasible connections between corruption and oil production levels. ► We suggest suboptimal production solutions can impact volumes of oil produced. ► Corruption may reinforce suboptimal oil production. ► More data on oil production efficiency by field and country will assist research

  9. Challenge of the oil market

    Energy Technology Data Exchange (ETDEWEB)

    Jaidah, A M

    1981-11-01

    The oil market is experiencing a different environment in 1981 as demand for OPEC oil fades while customers run down their inventories. The oil-producing countries face a new challenge, but the need of consuming countries for secure oil supplies and the need of producing countries to broaden their economies and reduce dependence on a depleting resource continue. Two episodes 1973 to 1975 and late 1978 to the present, illustrate the current market situation. The impact of these episodes is the basis for recommended long-run goals that go beyond market management to the real challenge of converting oil resources into the real assets of economic development. (DCK)

  10. Bulk oil clauses

    International Nuclear Information System (INIS)

    Gough, N.

    1993-01-01

    The Institute Bulk Oil Clauses produced by the London market and the American SP-13c Clauses are examined in detail in this article. The duration and perils covered are discussed, and exclusions, adjustment clause 15 of the Institute Bulk Oil Clauses, Institute War Clauses (Cargo), and Institute Strikes Clauses (Bulk Oil) are outlined. (UK)

  11. A MODEL FOR THE PALM OIL MARKET IN NIGERIA: AN ECONOMETRICS APPROACH

    Directory of Open Access Journals (Sweden)

    Henry Egwuma

    2016-04-01

    Full Text Available The aim of this study is to formulate and estimate a model for the palm oil market in Nigeria with a view to identifying principal factors that shape the Nigerian palm oil industry. Four structural equation models comprising palm oil production, import demand, domestic demand and producer price have been estimated using the autoregressive distributed lag (ARDL cointegration approach over the 1970 to 2011 period. The results reveal that significant factors that influence the Nigerian palm oil industry include the own price, technological improvements, and income level. Government expenditure on agricultural development is also an important determinant, which underscores the need for government support in agriculture. Our model provides a useful framework for analyzing the effects of changes in major exogenous variables such as income or import tariff on the production, demand, and price of palm oil.

  12. Extraction, Characterization and Modification of Castor Seed Oil

    Directory of Open Access Journals (Sweden)

    A. D. MOHAMMED

    2006-01-01

    Full Text Available This paper carried out experimental study, through extraction and characterization of both crude and refined castor oil. Normal hexane was used as solvent for the extraction process. The oil produced was refined through degumming, neutralization and bleaching process using local adsorbent (activated clay. The characterization analysis revealed that tested parameters, which include specific gravity, refractive index, acid value, saponification value and iodine value for both crude and refined castor oil produced, were within the ASTM standard specifications. In fact the iodine value obtained (84.8 for the refined oil indicates that the oil could certainly be used as lubricant, hydraulic break fluid and protecting coatings. The oil was modified via sulphation method to produce Turkey – red oil that was tested on wooden material, paper and cloth. The test revealed that the Turkey – red oil produced is suitable to be used as a good dying agent and polish.

  13. Utilization possibilities of palm shell as a source of biomass energy in Malaysia by producing bio-oil in pyrolysis process

    International Nuclear Information System (INIS)

    Abnisa, Faisal; Daud, W.M.A. Wan; Husin, W.N.W.; Sahu, J.N.

    2011-01-01

    Agriculture residues such as palm shell are one of the biomass categories that can be utilized for conversion to bio-oil by using pyrolysis process. Palm shells were pyrolyzed in a fluidized-bed reactor at 400, 500, 600, 700 and 800 o C with N 2 as carrier gas at flow rate 1, 2, 3, 4 and 5 L/min. The objective of the present work is to determine the effects of temperature, flow rate of N 2 , particle size and reaction time on the optimization of production of renewable bio-oil from palm shell. According to this study the maximum yield of bio-oil (47.3 wt%) can be obtained, working at the medium level for the operation temperature (500 o C) and 2 L/min of N 2 flow rate at 60 min reaction time. Temperature is the most important factor, having a significant positive effect on yield product of bio-oil. The oil was characterized by Fourier Transform infra-red (FT-IR) spectroscopy and gas chromatography/mass spectrometry (GC-MS) techniques. -- Highlights: → This study reports the results of experimental investing of conversion palm shell into bio-oil by using pyrolysis and to find the optimum condition to produce the highest yield of bio-oil. → Several parameters which have effect to the process such as temperature, N 2 flow rate, reaction time and particle size is will be investigated in this study. → The outcome of this result will be important for abatement and control of increasingly waste palm shell storage problems any energy source to the world.

  14. Trade linkages and macroeconomic effects of the price of oil

    International Nuclear Information System (INIS)

    Korhonen, Iikka; Ledyaeva, Svetlana

    2010-01-01

    In this paper we assess the impact of oil price shocks on oil-producer and oil-consuming economies. VAR models for different countries are linked together via a trade matrix, as in Abeysinghe (2001). As expected, we find that oil producers (here, Russia and Canada) benefit from oil price shocks. For example, a large oil shock leading to a price increase of 50% boosts Russian GDP by about 6%. However, oil producers are hurt by indirect effects of positive oil price shocks, as economic activity in their exporter countries suffers. For oil consumers, the effects are more diverse. In some countries, output falls in response to an oil price shock, while other countries seem to be relatively immune to oil price changes. Finally, indirect effects are also detected for oil-consumer countries. Those countries, which trade more with oil producers, gain indirect benefits via higher demand from oil-producing countries. In general, the largest negative total effects from positive oil price shocks are found for Japan, China, the USA, Finland and Switzerland, while other countries in our sample seem to have fared quite well during recent positive oil price shocks. The indirect effects are negative for Russia, Finland, Germany and Netherlands. (author)

  15. Seasonal and spatial trends in production and stable isotope signatures of primary producers in Alberta oil sands reclamation wetlands

    International Nuclear Information System (INIS)

    Boutsivongsakd, M; Chen, H.; Legg, A.; Farwell, A.; Dixon, G.

    2010-01-01

    Oil sands processing produces large amounts of waste water that contains polycyclic aromatic hydrocarbons (PAHs) and naphthenic acids (NAs). This study investigated the effects of exposure to PAHs and NA in aquatic organisms. The carbon and nitrogen dynamics in primary producers using stable isotopes in process-affected and reference wetlands were studied. Plankton and periphytic samples from artificial wetland substrates were collected and analyzed. Periphyton was collected in 14 to 20 day intervals for 5 different time periods in 2007 and 2008 in order to analyze seasonal trends in isotopic composition. Results of the study showed d15N enriched values for some consolidated tailings (CT) at sites in 2008. Other sites with mature fine tailings (MFT) as well as non-MFT sites did not have enriched d15N values. The study suggested that there are variations in ammonia levels in the CTs of different oil sands operators. Differences in the quality of the CT resulted in differences in d15N values of the periphyton-dominated by algae as well as in the periphyton dominated by microbes.

  16. Tenth oil recovery conference

    International Nuclear Information System (INIS)

    Sleeper, R.

    1993-01-01

    The Tertiary Oil Recovery Project is sponsored by the State of Kansas to introduce Kansas producers to the economic potential of enhanced recovery methods for Kansas fields. Specific objectives include estimation of the state-wide tertiary oil resource, identification and evaluation of the most applicable processes, dissemination of technical information to producers, occasional collaboration on recovery projects, laboratory studies on Kansas applicable processes, and training of students and operators in tertiary oil recovery methods. Papers have been processed separately for inclusion on the data base

  17. State companies dominate OGJ100 list of non-U.S. oil producers

    International Nuclear Information System (INIS)

    Anon.

    1993-01-01

    State owned oil and gas companies dominate the OGJ100 list of non-U.S. producers. Because many of them report only operating information, companies on the worldwide list cannot be ranked by assets or revenues. The list, therefore, is organized regionally, based on location of companies' corporate headquarters. The leading nongovernment company in both reserves and production is Royal Dutch/Shell. It ranks sixth in the world in liquids production and 11th in liquids reserves, as it has for the past 2 years. British Petroleum is the next largest nongovernment company. BP ranks 11th in liquids production and 16th in liquids reserves. Elf Aquitaine, 55.8% government-controlled, ranked 17th in liquids production. AGIP was 20th in liquids production. Kuwait Petroleum returned to the list of top 20 producers, ranking 12th, as it restored production shut in by facilities damage sustained during the Persian Gulf crisis. New to the top 20 reserves list is Petroleo Brasileiro, which moved to 20th position. The top 20 companies in the OGJ100 held reserves estimated at 869.3 billion bbl in 1992 vs. 869.5 billion bbl in 1991 and 854.2 billion bbl in 1990

  18. Maximizing heavy oil value while minimizing environmental impact with HTL upgrading of heavy to light oil

    Energy Technology Data Exchange (ETDEWEB)

    Koshka, E. [Ivanhoe Energy Inc., Calgary, AB (Canada)

    2009-07-01

    This presentation described Ivanhoe Energy Inc.'s proprietary HTL upgrading technology which was designed to process heavy oil in the field to cost effectively produce an upgraded synthetic oil that meets pipeline requirements. Steam and electricity are generated from the energy produced during the process. HTL improves the economics of heavy oil production by reducing the need for natural gas and diluent, and by capturing most of the heavy to light oil price differential. Integrated HTL heavy oil production also provides many environmental benefits regarding greenhouse gas (GHG) emissions. The HTL upgrading process is ready for full scale application. tabs., figs.

  19. Performance profiles of major energy producers 1979

    International Nuclear Information System (INIS)

    1981-07-01

    The purpose of this report is to examine year-to-year developments in the operations of 26 major US energy companies on a corporate level and also by major line of energy business and by major functions within each line of business. The period covered is 1977 to 1979. Comparisons of income and investment flow are featured and related to functionally allocated net investment in place. The presentation seeks to identify similarities and dissimilarities in results across lines-of-business activity or by firm size

  20. Synthesis of polyhydroxyalkanoate from palm oil and some new applications.

    Science.gov (United States)

    Sudesh, Kumar; Bhubalan, Kesaven; Chuah, Jo-Ann; Kek, Yik-Kang; Kamilah, Hanisah; Sridewi, Nanthini; Lee, Yan-Fen

    2011-03-01

    Polyhydroxyalkanoate (PHA) is a potential substitute for some petrochemical-based plastics. This biodegradable plastic is derived from microbial fermentation using various carbon substrates. Since carbon source has been identified as one of the major cost-absorbing factors in PHA production, cheap and renewable substrates are currently being investigated as substitutes for existing sugar-based feedstock. Plant oils have been found to result in high-yield PHA production. Malaysia, being the world's second largest producer of palm oil, is able to ensure continuous supply of palm oil products for sustainable PHA production. The biosynthesis and characterization of various types of PHA using palm oil products have been described in detail in this review. Besides, by-products and waste stream from palm oil industry have also demonstrated promising results as carbon sources for PHA biosynthesis. Some new applications in cosmetic and wastewater treatment show the diversity of PHA usage. With proper management practices and efficient milling processes, it may be possible to supply enough palm oil-based raw materials for human consumption and other biotechnological applications such as production of PHA in a sustainable manner.