Sample records for magmatic aqueous fluids

  1. Magmatic gases in fluid inclusions from hydrothermal ore deposits

    Energy Technology Data Exchange (ETDEWEB)

    Graney, J.; Kesler, S. (University of Michigan, MI (United States))


    In this study, magmatic gases in fluid inclusions from hydrothermal ore deposits have been analyzed. The gas composition of fluid inclusions from a wide range of extinct hydrothermal systems as represented by different ore deposit types was determined using a quadrupole mass spectrometer. Most samples used for analysis consisted of transparent quartz, although barite, jasperoid, opal, sphalerite, pyrite, chalcopyrite, and bornite were also analyzed. H2O was the dominant volatile component in fluid inclusions, and composed 95-99 mole percent of the inclusion fluid. CO2 comprised most of the remaining volatile component and the other gases were generally present in amounts smaller than 0.1 mole percent. Analysis from porphyry and acid-sulfate deposits, in which magmatic gas contributions are considered to be largest, plotted closest to the fumarolic gas compositions. These inclusion fluid volatile component comparisons have shown that there are systematic differences in inclusion fluids from different hydrothermal systems. 9 refs., 3 figs.

  2. Magmatic Hydrothermal Fluids: Experimental Constraints on the Role of Magmatic Sulfide Crystallization and Other Early Magmatic Processes in Moderating the Metal Content of Ore-Forming Fluids (United States)

    Piccoli, P. M.; Candela, P. A.


    It has been recognized for some time that sulfide phases, although common in intermediate-felsic volcanic rocks, are not as common in their plutonic equivalents. That sulfide crystallization, or the lack thereof, is important in the protracted magmatic history of porphyry Cu and related systems is supported by the work of e.g., Rowins (2000). Candela and Holland (1986) suggested that sulfide crystallization could moderate the ore metal concentrations in porphyry environments. Experiments show clearly that Au and Cu can partition into Cl-bearing vapor and brine. This effect can be enhanced by S (Simon, this session). However, in some instances enhances this effect. That is, the partitioning of Au and Cu into vapor+brine is highly efficient (e.g. Simon et al. 2003; Frank et al 2003). This suggests that if sulfides do not sequester ore metals early during the history of a magma body from the melt, they will partition strongly into the volatile phases. Whether volatile release occurs in the porphyry ore environment, or at deeper levels upon magma rise, is a yet unsolved question. Little is known about deep release of volatiles (during magma transport at lower- to mid-crustal levels). Saturation of melts with a CO2-bearing fluid could happen at levels much deeper than those typical of ore formation. CO2 is released preferentially, so a high CO2 concentration in fluids in the porphyry ore environment argues against deep fluid release. Of course, this depends upon the specific processes of crystallization and fluid release, which may be complex. Our experiments on sulfides have concentrated on pyrrhotite and Iss. Our partitioning data for Po/melt exhibit wide variations from metal to metal: Cu (2600); Co (170); Au (140); Ni (100); Bi, Zn and Mn (2). These results suggest that crystallization of Po can contribute to variable ore metal ratios (e.g. Cu/Au). Other sulfides behave differently. If a melt is Iss (Cpy) saturated, then Cu will be buffered at a high value, and Au

  3. Magmatic-dominated fluid evolution in the Jurassic Nambija gold skarn deposits (southeastern Ecuador) (United States)

    Vallance, Jean; Fontboté, Lluís; Chiaradia, Massimo; Markowski, Agnès; Schmidt, Susanne; Vennemann, Torsten


    The Jurassic (approximately 145 Ma) Nambija oxidized gold skarns are hosted by the Triassic volcanosedimentary Piuntza unit in the sub-Andean zone of southeastern Ecuador. The skarns consist dominantly of granditic garnet (Ad20-98) with subordinate pyroxene (Di46-92Hd17-42Jo0-19) and epidote and are spatially associated with porphyritic quartz-diorite to granodiorite intrusions. Endoskarn is developed at the intrusion margins and grades inwards into a potassic alteration zone. Exoskarn has an outer K- and Na-enriched zone in the volcanosedimentary unit. Gold mineralization is associated with the weakly developed retrograde alteration of the exoskarn and occurs mainly in sulfide-poor vugs and milky quartz veins and veinlets in association with hematite. Fluid inclusion data for the main part of the prograde stage indicate the coexistence of high-temperature (500°C to >600°C), high-salinity (up to 65 wt.% eq. NaCl), and moderate- to low-salinity aqueous-carbonic fluids interpreted to have been trapped at pressures around 100-120 MPa, corresponding to about 4-km depth. Lower-temperature (510-300°C) and moderate- to low-salinity (23-2 wt.% eq. NaCl) aqueous fluids are recorded in garnet and epidote of the end of the prograde stage. The microthermometric data (Th from 513°C to 318°C and salinity from 1.0 to 23 wt.% eq. NaCl) and δ18O values between 6.2‰ and 11.5‰ for gold-bearing milky quartz from the retrograde stage suggest that the ore-forming fluid was dominantly magmatic. Pressures during the early retrograde stage were in the range of 50-100 MPa, in line with the evidence for CO2 effervescence and probable local boiling. The dominance of magmatic low-saline to moderately saline oxidizing fluids during the retrograde stage is consistent with the depth of the skarn system, which could have delayed the ingression of external fluids until relatively low temperatures were reached. The resulting low water-to-rock ratios explain the weak retrograde alteration

  4. Magmatic Vapor Phase Transport of Copper in Reduced Porphyry Copper-Gold Deposits: Evidence From PIXE Microanalysis of Fluid Inclusions (United States)

    Rowins, S. M.; Yeats, C. J.; Ryan, C. G.


    Nondestructive proton-induced X-ray emission (PIXE) studies of magmatic fluid inclusions in granite-related Sn-W deposits [1] reveal that copper transport out of reduced felsic magmas is favored by low-salinity vapor and not co-existing high-salinity liquid (halite-saturated brine). Copper transport by magmatic vapor also has been documented in oxidized porphyry Cu-Au deposits, but the magnitude of Cu partitioning into the vapor compared to the brine generally is less pronounced than in the reduced magmatic Sn-W systems [2]. Consideration of these microanalytical data leads to the hypothesis that Cu and, by inference, Au in the recently established "reduced porphyry copper-gold" (RPCG) subclass should partition preferentially into vapor and not high-salinity liquid exsolving directly from fluid-saturated magmas [3-4]. To test this hypothesis, PIXE microanalysis of primary fluid inclusions in quartz-sulfide (pyrite, pyrrhotite & chalcopyrite) veins from two RPCG deposits was undertaken using the CSIRO-GEMOC nuclear microprobe. PIXE microanalysis for the ~30 Ma San Anton deposit (Mexico) was done on halite-saturated aqueous brine (deposit (W. Australia) was done on halite-saturated "aqueous" inclusions, which contain a small (deposits of the new RPCG subclass demonstrate the greater potential of these systems, compared to the classically oxidized porphyry Cu-Au systems, to transport Cu and probably precious metals in a magmatic aqueous vapor phase. These PIXE data also support the possibility that Cu partitions preferentially into an immiscible CO2-rich magmatic fluid. References: [1] Heinrich, C.A. et al. (1992) Econ. Geol., 87, 1566-1583. [2] Heinrich, C.A. et al. (1999) Geology, 27, 755-758. [3] Rowins, S.M. (2000) Geology, 28, 491-494. [4] Rowins, S.M. (2000) The Gangue, GAC-MDD Newsletter, 67, 1-7 ( [5] Rowins, S.M. et al. (1993) Geol. Soc. Australia Abs., 34, 68-70.

  5. The Interplay Between Saline Fluid Flow and Dynamic Permeability in Magmatic-Hydrothermal Systems (United States)

    Weis, P.


    Magmatic-hydrothermal ore deposits document the interplay between saline fluid flow and rock permeability. Numerical simulations of multi-phase flow of variably miscible, compressible H20-NaCl fluids in concert with a dynamic permeability model can reproduce characteristics of porphyry copper and epithermal gold systems. This dynamic permeability model incorporates depth-dependent permeability profiles characteristic for tectonically active crust as well as pressure- and temperature-dependent relationships describing hydraulic fracturing and the transition from brittle to ductile rock behavior. In response to focused expulsion of magmatic fluids from a crystallizing upper crustal magma chamber, the hydrothermal system self-organizes into a hydrological divide, separating an inner part dominated by ascending magmatic fluids under near-lithostatic pressures from a surrounding outer part dominated by convection of colder meteoric fluids under near-hydrostatic pressures. This hydrological divide also provides a mechanism to transport magmatic salt through the crust, and prevents the hydrothermal system to become "clogged" by precipitation of solid halite due to depressurization of saline, high-temperature magmatic fluids. The same physical processes at similar permeability ranges, crustal depths and flow rates are relevant for a number of active systems, including geothermal resources and excess degassing at volcanos. The simulations further suggest that the described mechanism can separate the base of free convection in high-enthalpy geothermal systems from the magma chamber as a driving heat source by several kilometers in the vertical direction in tectonic settings with hydrous magmatism. This hydrology would be in contrast to settings with anhydrous magmatism, where the base of the geothermal systems may be closer to the magma chamber.

  6. Stable isotope evidence for formation from magmatic fluids of the mineralized breccias in the Los Bronces and El Teniente copper deposits, Central Chile

    International Nuclear Information System (INIS)

    Skewes, M.A; Arevalo, A; Holmgren, C.; Stern, C.R


    The giant Miocene and Pliocene Rio Blanco-Los Bronces (Warnaars et al., 1985; Serrano et al., 1996; Vargas et al., 1999) and El Teniente (Camus, 1975; Cuadra, 1986; Skewes and Arevalo, 2000) copper deposits of central Chile are among the largest copper deposits in the world. Hypogene copper ore is more significant than supergene ore in these deposits, and most of the hypogene copper occurs in the matrix of multiple clusters of breccias (Skewes and Stern, 1994; 1995). The origin of the large mineralized breccia pipes in these and other Andean copper deposits has been attributed to the explosive expansion of magmatic aqueous fluids derived from cooling plutons (Emmons, 1938; Kents, 1964; Warnaars et al., 1985; Sillitoe, 1985; Skewes and Stern, 1994, 1995). Warnaars et al. (1985) and Skewes and Stern (1996) suggested that mineral deposition in the matrix of these breccias took place by the rapid cooling of the same magmatic fluids that generated the brecciation. Highly saline, high-temperature magmatic fluid inclusions occur in quartz and tourmaline in the matrix of these breccias (Holmgren et al., 1988; Vargas et al., 1999; Skewes et al., 2001) (au)

  7. Origin of fumarolic fluids from Tupungatito Volcano (Central Chile): interplay between magmatic, hydrothermal, and shallow meteoric sources (United States)

    Benavente, Oscar; Tassi, Franco; Gutiérrez, Francisco; Vaselli, Orlando; Aguilera, Felipe; Reich, Martin


    Tupungatito is a poorly known volcano located about 100 km eastward of Santiago (Chile) in the northernmost sector of the South Volcanic Zone. This 5,682 m high volcano shows intense fumarolic activity. It hosts three crater lakes within the northwestern portion of the summit area. Chemical compositions of fumarolic gases and isotopic signatures of noble gases (3He/4He and 40Ar/36Ar are up to 6.09 Ra and 461, respectively), and steam (δ18O and δD) suggest that they are produced by mixing of fluids from a magmatic source rich in acidic gas compounds (SO2, HCl, and HF), and meteoric water. The magmatic-hydrothermal fluids are affected by steam condensation that controls the outlet fumarolic temperatures (contamination from the subducting slab, (2) the sedimentary basement, and (3) limited contribution from crustal sediments. Gas geothermometry based on the kinetically rapid H2-CO equilibria indicates equilibrium temperatures 200 °C and redox conditions are consistent with those inferred by the presence of the SO2-H2S redox pair, typical of fluids that have attained equilibrium in magmatic environment. A comprehensive conceptual geochemical model describing the circulation pattern of the Tupungatito hydrothermal-magmatic fluids is proposed. It includes fluid source regions and re-equilibration processes affecting the different gas species due to changing chemical-physical conditions as the magmatic-hydrothermal fluids rise up toward the surface.

  8. Formation of magmatic brine lenses via focussed fluid-flow beneath volcanoes (United States)

    Afanasyev, Andrey; Blundy, Jon; Melnik, Oleg; Sparks, Steve


    Many active or dormant volcanoes show regions of high electrical conductivity at depths of a few kilometres beneath the edifice. We explore the possibility that these regions represent lenses of high-salinity brine separated from a single-phase magmatic fluid containing H2O and NaCl. Since chloride-bearing fluids are highly conductive and have an exceptional capacity to transport metals, these regions can be an indication of an active hydrothermal ore-formation beneath volcanoes. To investigate this possibility we have performed hydrodynamic simulations of magma degassing into permeable rock. In our models the magma source is located at 7 km depth and the fluid salinity approximates that expected for fluids released from typical arc magmas. Our model differs from previous models of a similar process because it is (a) axisymmetric and (b) includes a static high-permeability pathway that links the magma source to the surface. This pathway simulates the presence of a volcanic conduit and/or plexus of feeder dykes that are typical of most volcanic systems. The presence of the conduit leads to a number of important hydrodynamic consequences, not observed in previous models. Importantly, we show that an annular brine lens capped by crystallised halite is likely to form above an actively degassing sub-volcanic magma body and can persist for more than 250 kyr after degassing ceases. Parametric analysis shows that brine lenses are more prevalent when the fluid is released at temperatures above the wet granite solidus, when magmatic fluid salinity is high, and when the high-permeability pathway is narrow. The calculated depth, form and electrical conductivity of our modelled system shares many features with published magnetotelluric images of volcano subsurfaces. The formation and persistence of sub-volcanic brine lenses has implications for geothermal systems and hydrothermal ore formation, although these features are not explored in the presented model.

  9. Thermophysical Properties of Aqueous Solutions Used as Secondary Working Fluids


    Melinder, Åke


    Secondary working fluids (secondary refrigerants, heat transfer fluids, antifreezes, brines) have long been used in various indirect re-frigeration and heat pump systems. Aqueous solutions (water solu-tions) have long been used as single phase (liquid only) secondary working fluids for cooling in supermarkets, ice rinks, heat recovery systems, heat pumps and other applications. However, aqueous solutions are increasingly used also for freezers in supermarkets and other applications in low tem...

  10. Aqueous cutting fluid for machining fissionable materials (United States)

    Duerksen, Walter K.; Googin, John M.; Napier, Jr., Bradley


    The present invention is directed to a cutting fluid for machining fissionable material. The cutting fluid is formed of glycol, water and boron compound in an adequate concentration for effective neutron attenuation so as to inhibit criticality incidents during machining.

  11. Stable isotopes as signposts of fluid throughput in Rotokawa and other geothermal fields, and the difficulty of identifying magmatic fingerprints

    International Nuclear Information System (INIS)

    Blattner, P.; Woldemichael, S.; Auckland Univ.; Browne, P.R.L.; Auckland Univ.


    We present a background for water-rock interaction generally, and new data on the Rotokawa geothermal field. The oxygen isotope shift of total rock samples allow the deduction of past flowpaths and total fluid throughput. Estimates of any input true exsolved magmatic water are difficult as the lithosphere can act as an effective isotopic screen. (authors). 1 fig., 6 refs

  12. Pressure-temperature condition and hydrothermal-magmatic fluid evolution of the Cu-Mo Senj deposit, Central Alborz: fluid inclusion evidence

    Directory of Open Access Journals (Sweden)

    Ebrahim Tale Fazel


    The Cu-Mo Senj deposit covering an area about 5 km2 is located in the central part of the Alborz Magmatic Arc (AMA. The Nb/Y versus Zr/TiO2 diagram (after Winchester and Floyd, 1977 illustrates a typical trend for the magmas in the Senj magmatic area–starting from basaltic and evolving to dacite/rhyodacitic compositions, with few data plotting in the alkali basalt field. Most of the igneous rocks plot within the medium- and high-K fields in the K2O versus SiO2 diagram. The igneous rocks from the Senj area define a typical high-K calc-alkaline on SiO2 versus K2O diagram (Le Maitre et al., 1989. All studied rocks show similar incompatible trace element patterns with an enrichment of large ion lithophile elements (LILE: K, Rb, Ba, Th and depletion of high field strength elements (HFSE: Nb and Ti, which are typical features of magmas from convergent margin tectonic settings (Pearce and Can, 1973. At least three veining stages namely QBC, QM, and QP which are related to alteration and mineralization are distinguished at the Senj mineralized area. Three distinct alteration assemblages including K-feldspar-biotite-sericite-quartz, quartz-sericite-K-feldspar-pyrite, and K-feldspar-biotite-sericite-quartz, are distinguishable with these veins. About 80 % of the copper at Senj is associated with the early QBC-stage veins, with another 5 to 15 % in the QM-and QP-stage veins. About 70 % of the molybdenite occur in QM veins. Discussion Fluid inclusion distribution, fluid chemistry, and homogenization behavior document that S2-type fluids are samples of magma-derived aqueous-saline fluids characterized by high salinity and temperature, and high Cu content. Such parental fluids scavenged Cu and Mo from the melt below and transported them to the hydrothermal system above. The increased abundance of S- and LV-types inclusion coinciding with the highest grade Cu mineralization (early QBC-stage veins at the Senj deposit suggests that brine-vapor unmixing and phase separation plays an

  13. Geochemical Signature of Magmatic-Hydrothermal Fluids Exsolved from the Beauvoir Rare-Metal Granite (Massif Central, France: Insights from LA-ICPMS Analysis of Primary Fluid Inclusions

    Directory of Open Access Journals (Sweden)

    Matthieu Harlaux


    Full Text Available The Beauvoir granite (Massif Central, France represents an exceptional case in the European Variscan belt of a peraluminous rare-metal granite crosscutting an early W stockwork. The latter was strongly overprinted by rare-metal magmatic-hydrothermal fluids derived from the Beauvoir granite, resulting in a massive topazification of the quartz-ferberite vein system. This work presents a complete study of primary fluid inclusions hosted in quartz and topaz from the Beauvoir granite and the metasomatized stockwork, in order to characterize the geochemical composition of the magmatic fluids exsolved during the crystallization of this evolved rare-metal peraluminous granite. Microthermometric and Raman spectrometry data show that the earliest fluid (L1 is of high temperature (500 to >600°C, high salinity (17–28 wt.% NaCl eq, and Li-rich (Te100 m and interaction with external fluids.

  14. Magmatic fluid inclusions from the Zaldivar Deposits, Northern Chile: The role of early metal-bearing fluids in a Porphyry copper system

    NARCIS (Netherlands)

    drs Campos, E.; Touret, J.L.R.; Nikogosian, I.


    The occurrence of a distinct type of multi-solid, highly-saline fluid inclusions, hosted in igneous quartz phenocrysts from the Llamo porphyry, in the Zaldívar porphyry copper deposit of northern Chile is documented. Total homogenization of the multi-solid type inclusions occurs at magmatic

  15. "Magmatic fluid inclusions from the Zaldivar deposit, Northern Chile: The role of Early metal-bearing fluids in a porphyry copper system."

    NARCIS (Netherlands)

    drs Campos, E.; Touret, J.L.R.; Nikogosian, I.


    The occurrence of a distinct type of multi-solid, highly-saline fluid inclusions, hosted in igneous quartz phenocrysts from the Llamo porphyry, in the Zaldívar porphyry copper deposit of northern Chile is documented. Total homogenization of the multi-solid type inclusions occurs at magmatic

  16. C-O-H-S magmatic fluid system in shrinkage bubbles of melt inclusions (United States)

    Robidoux, P.; Frezzotti, M. L.; Hauri, E. H.; Aiuppa, A.


    Magmatic volatiles include multiple phases in the C-O-H-S system of shrinkage bubbles for which a conceptual model is still unclear during melt inclusion formation [1,2,3,4]. The present study aims to qualitatively explore the evolution of the volatile migration, during and after the formation of the shrinkage bubble in melt inclusions trapped by olivines from Holocene to present at San Cristóbal volcano (Nicaragua), Central American Volcanic Arc (CAVA). Combined scanning electron microscope (SEM) and Raman spectroscopy observations allow to define the mineral-fluid phases inside typical shrinkage bubbles at ambient temperature. The existence of residual liquid water is demonstrated in the shrinkage bubbles of naturally quenched melt inclusion and this water could represents the principal agent for chemical reactions with other dissolved ionic species (SO42-, CO32-, etc.) and major elements (Mg, Fe, Cu, etc.) [4,5]. With the objective of following the cooling story of the bubble-inclusion system, the new methodological approach here estimate the interval of equilibrium temperatures for each SEM-Raman identified mineral phase (carbonates, hydrous carbonates, sulfurs, sulfates, etc.). Finally, two distinct mechanisms are proposed to describe the evolution of this heterogeneous fluid system in bubble samples at San Cristóbal which imply a close re-examination for similar volcanoes in subduction zone settings: (1) bubbles are already contracted and filled by volatiles by diffusion processes from the glass and leading to a C-O-H-S fluid-glass reaction enriched in Mg-Fe-Cu elements (2) bubbles are formed by oversaturation of the volatiles from the magma which is producing an immiscible metal-rich fluid. [1]Moore et al. (2015). Am. Mineral. 100, 806-823 [2]Wallace et al. (2015). Am. Mineral. 100, 787-794 [3]Lowenstern (2015). Am. Mineral. 100, 672-673 [4]Esposito, et al. (2016). Am. Mineral. 101, 1691-1708 [5]Kamenetsky et al. (2001). Earth Planet. Sci. Lett. 184, 685-702

  17. Magmatic-like fluid source of the Chingshui geothermal field, NE Taiwan evidenced by carbonate clumped-isotope paleothermometry (United States)

    Lu, Yi-Chia; Song, Sheng-Rong; Wang, Pei-Ling; Wu, Chung-Che; Mii, Horng-Sheng; MacDonald, John; Shen, Chuan-Chou; John, Cédric M.


    The Chingshui geothermal field, a moderate-temperature and water-dominated hydrothermal system, was the site of the first geothermal power plant in Taiwan. Many geological, geophysical and geochemical studies using more than 21 drilled wells have been performed since the 1960s. However, there are still controversies regarding the heat and fluid sources due to the tectonically complicated geological setting. To clarify the heat and fluid sources, we analyzed clumped isotopes with carbon and oxygen isotopic compositions of calcite scaling in geothermal wells and veins on outcrops and calculated the δ18O values of the source fluids. Two populations of δ18O values were calculated: -5.8 ± 0.8‰ VSMOW from scaling in the well and -1.0 ± 1.6‰ to 10.0 ± 1.3‰ VSMOW from outcropping calcite veins, indicative of meteoric and magmatic fluid sources, respectively. Meanwhile, two hydrothermal reservoirs at different depths have been identified by magnetotelluric (MT) imaging with micro-seismicity underneath this area. As a result, we propose a two-reservoir model: the shallow reservoir provides fluids from meteoric water for the scaling sampled from wells, whereas the deep reservoir provides magmatic fluids from deep marble decarbonization recorded in outcropping calcite veins.

  18. Magmatic tritium

    International Nuclear Information System (INIS)

    Goff, F.; Aams, A.I.; McMurtry, G.M.; Shevenell, L.; Pettit, D.R.; Stimac, J.A.; Werner, C.


    This is the final report of a three-year, Laboratory-Directed Research and Development (LDRD) project at the Los Alamos National Laboratory. Detailed geochemical sampling of high-temperature fumaroles, background water, and fresh magmatic products from 14 active volcanoes reveal that they do not produce measurable amounts of tritium ( 3 H) of deep origin ( 2 O). On the other hand, all volcanoes produce mixtures of meteoric and magmatic fluids that contain measurable 3 H from the meteoric end-member. The results show that cold fusion is probably not a significant deep earth process but the samples and data have wide application to a host of other volcanological topics

  19. Influence of magmatic volatiles on boron isotope compositions in vent fluids from the Eastern Manus Basin, Papua New Guinea (United States)

    Wilckens, F. K.; Kasemann, S.; Bach, W.; Reeves, E. P.; Meixner, A.; Seewald, J.


    In this study we present boron (B), lithium (Li) and strontium (Sr) concentrations and isotopic composition of submarine hydrothermal fluids collected in 2006 and 2011 from PACMANUS, DESMOS and SuSu Knolls vent fields located in the Eastern Manus Basin [1,2]. Hydrothermal vent fluids within the Eastern Manus Basin range from high-temperature black smoker fluids to low-temperature diffuse fluids and acid-sulfate fluids. In general, the different fluid types show variable water-rock ratios during water-rock interaction and different inputs of magmatic volatiles. End-member black smoker fluids, which have in general high temperatures (mostly higher than 280°C) and pH values higher than 2 (measured at 25°C) are characterized by low δ7Li values (3.9 to 5.9‰) and 87Sr/86Sr ratios (0.704 to 0.705) similar to the values for island arc basalts. These results suggest low water-rock ratios during hydrothermal circulation. B concentrations and isotopic compositions in these fluids range from 1.0 to 2.6μM and 13 to 20‰, respectively. These data match with other vent fluids from island arc settings in the Western Pacific and plot in a B versus δ11B diagram on a two-component mixing line between seawater and island arc basalts [3]. Sr and Li isotopic composition of white smoker and acid-sulfate fluids overlap generally with the isotopic ratios for the black smoker fluids. However, in some fluids Sr isotope ratios are up to 0.709 near seawater composition suggesting higher water-rock ratios during water-rock interaction. B concentrations and isotope ratios in the white smoker and acid-sulfate fluids range from 0.6 to 2.2μM and 9 to 16‰, respectively which are lower compared with the values of black smoker fluids. In addition, these fluids do not fit on the mixing line between seawater and island arc basalt, and define another mixing trend in a B versus δ11B diagram. To explain this contradictory trend, a third mixing endmember is required that shifts B concentrations

  20. Analysis of Direct Samples of Early Solar System Aqueous Fluids (United States)

    Zolensky, Michael E.; Bodnar, R J.; Fedele, L.; Yurimoto,H.; Itoh, S.; Fries, M.; Steele, A.


    Over the past three decades we have become increasingly aware of the fundamental importance of water, and aqueous alteration, on primitive solar-system bodies. Some carbonaceous and ordinary chondrites have been altered by interactions with liquid water within the first 10 million years after formation of their parent asteroids. Millimeter to centimeter-sized aggregates of purple halite containing aqueous fluid inclusions were found in the matrix of two freshly-fallen brecciated H chondrite falls, Monahans (1998, hereafter simply "Monahans") (H5) and Zag (H3-6) (Zolensky et al., 1999; Whitby et al., 2000; Bogard et al., 2001) In order to understand origin and evolution of the aqueous fluids inside these inclusions we much measure the actual fluid composition, and also learn the O and H isotopic composition of the water. It has taken a decade for laboratory analytical techniques to catch up to these particular nanomole-sized aqueous samples. We have recently been successful in (1) measuring the isotopic composition of H and O in the water in a few fluid inclusions from the Zag and Monahans halite, (2) mineralogical characterization of the solid mineral phases associated with the aqueous fluids within the halite, and (3) the first minor element analyses of the fluid itself. A Cameca ims-1270 equipped with a cryo-sample-stage of Hokkaido University was specially prepared for the O and H isotopic measurements. The cryo-sample-stage (Techno. I. S. Corp.) was cooled down to c.a. -190 C using liquid nitrogen at which the aqueous fluid in inclusions was frozen. We excavated the salt crystal surfaces to expose the frozen fluids using a 15 keV Cs+ beam and measured negative secondary ions. The secondary ions from deep craters of approximately 10 m in depth emitted stably but the intensities changed gradually during measurement cycles because of shifting states of charge compensation, resulting in rather poor reproducibility of multiple measurements of standard fluid

  1. Retrogressive hydration of calc-silicate xenoliths in the eastern Bushveld complex: evidence for late magmatic fluid movement (United States)

    Wallmach, T.; Hatton, C. J.; De Waal, S. A.; Gibson, R. L.


    Two calc-silicate xenoliths in the Upper Zone of the Bushveld complex contain mineral assemblages which permit delineation of the metamorphic path followed after incorporation of the xenoliths into the magma. Peak metamorphism in these xenoliths occurred at T=1100-1200°C and P <1.5 kbar. Retrograde metamorphism, probably coinciding with the late magmatic stage, is characterized by the breakdown of akermanite to monticellite and wollastonite at 700°C and the growth of vesuvianite from melilite. The latter implies that water-rich fluids (X CO 2 <0.2) were present and probably circulating through the cooling magmatic pile. In contrast, calc-silicate xenoliths within the lower zones of the Bushveld complex, namely in the Marginal and Critical Zones, also contain melilite, monticellite and additional periclase with only rare development of vesuvianite. This suggests that the Upper Zone cumulate pile was much 'wetter' in the late-magmatic stage than the earlier-formed Critical and Marginal Zone cumulate piles.

  2. Heat flux from magmatic hydrothermal systems related to availability of fluid recharge (United States)

    Harvey, M. C.; Rowland, J.V.; Chiodini, G.; Rissmann, C.F.; Bloomberg, S.; Hernandez, P.A.; Mazot, A.; Viveiros, F.; Werner, Cynthia A.


    Magmatic hydrothermal systems are of increasing interest as a renewable energy source. Surface heat flux indicates system resource potential, and can be inferred from soil CO2 flux measurements and fumarole gas chemistry. Here we compile and reanalyze results from previous CO2 flux surveys worldwide to compare heat flux from a variety of magma-hydrothermal areas. We infer that availability of water to recharge magmatic hydrothermal systems is correlated with heat flux. Recharge availability is in turn governed by permeability, structure, lithology, rainfall, topography, and perhaps unsurprisingly, proximity to a large supply of water such as the ocean. The relationship between recharge and heat flux interpreted by this study is consistent with recent numerical modeling that relates hydrothermal system heat output to rainfall catchment area. This result highlights the importance of recharge as a consideration when evaluating hydrothermal systems for electricity generation, and the utility of CO2 flux as a resource evaluation tool.

  3. Numerical Simulation of Two-Fluid Mingling Using the Particle Finite Element Method with Applications to Magmatic and Volcanic Processes (United States)

    de Mier, M.; Costa, F.; Idelsohn, S.


    Many magmatic and volcanic processes (e.g., magma differentiation, mingling, transport in the volcanic conduit) are controlled by the physical properties and flow styles of high-temperature silicate melts. Such processes can be experimentally investigated using analog systems and scaling methods, but it is difficult to find the suitable material and it is generally not possible to quantitatively extrapolate the results to the natural system. An alternative means of studying fluid dynamics in volcanic systems is with numerical models. We have chosen the Particle Finite Element Method (PFEM), which is based on a Delaunay mesh that moves with the fluid velocity, the Navier-Stokes equations in Lagrangian formulation, and linear elements for velocity, pressure, and temperature. Remeshing is performed when the grid becomes too distorted [E. Oñate et al., 2004. The Particle Finite Element Method: An Overview. Int. J. Comput. Meth. 1, 267-307]. The method is ideal for tracking material interfaces between different fluids or media. Methods based on Eulerian reference frames need special techniques, such as level-set or volume-of-fluid, to capture the interface position, and these techniques add a significant numerical diffusion at the interface. We have performed a series of two-dimensional simulations of a classical problem of fluid dynamics in magmatic and volcanic systems: intrusion of a basaltic melt in a silica-rich magma reservoir. We have used realistic physical properties and equations of state for the silicate melts (e.g., temperature, viscosity, and density) and tracked the changes in the system for geologically relevant time scales (up to 100 years). The problem is modeled by the low-Mach-number equations derived from an asymptotic analysis of the compressible Navier-Stokes equations that removes shock waves from the flow but allows however large variations of density due to temperature variations. Non-constant viscosity and volume changes are taken into account

  4. Hydrothermal, multiphase convection of H2O-NaCl fluids from ambient to magmatic temperatures : A new numerical scheme and benchmarks for code comparison

    NARCIS (Netherlands)

    Weis, P.; Driesner, T.; Coumou, D.; Geiger, S.


    Thermohaline convection of subsurface fluids strongly influences heat and mass fluxes within the Earth's crust. The most effective hydrothermal systems develop in the vicinity of magmatic activity and can be important for geothermal energy production and ore formation. As most parts of these systems

  5. Corrosion penetration monitoring of advanced ceramics in hot aqueous fluids

    Directory of Open Access Journals (Sweden)

    Klaus G. Nickel


    Full Text Available Advanced ceramics are considered as components in energy related systems, because they are known to be strong, wear and corrosion resistant in many environments, even at temperatures well exceeding 1000 °C. However, the presence of additives or impurities in important ceramics, for example those based on Silicon Nitride (Si3N4 or Al2O3 makes them vulnerable to the corrosion by hot aqueous fluids. The temperatures in this type of corrosion range from several tens of centigrade to hydrothermal conditions above 100 °C. The corrosion processes in such media depend on both pH and temperature and include often partial leaching of the ceramics, which cannot be monitored easily by classical gravimetric or electrochemical methods. Successful corrosion penetration depth monitoring by polarized reflected light optical microscopy (color changes, Micro Raman Spectroscopy (luminescence changes and SEM (porosity changes will be outlined. The corrosion process and its kinetics are monitored best by microanalysis of cross sections, Raman spectroscopy and eluate chemistry changes in addition to mass changes. Direct cross-calibrations between corrosion penetration and mechanical strength is only possible for severe corrosion. The methods outlined should be applicable to any ceramics corrosion process with partial leaching by fluids, melts or slags.

  6. Seismic properties of fluid bearing formations in magmatic geothermal systems: can we directly detect geothermal activity with seismic methods? (United States)

    Grab, Melchior; Scott, Samuel; Quintal, Beatriz; Caspari, Eva; Maurer, Hansruedi; Greenhalgh, Stewart


    Seismic methods are amongst the most common techniques to explore the earth's subsurface. Seismic properties such as velocities, impedance contrasts and attenuation enable the characterization of the rocks in a geothermal system. The most important goal of geothermal exploration, however, is to describe the enthalpy state of the pore fluids, which act as the main transport medium for the geothermal heat, and to detect permeable structures such as fracture networks, which control the movement of these pore fluids in the subsurface. Since the quantities measured with seismic methods are only indirectly related with the fluid state and the rock permeability, the interpretation of seismic datasets is difficult and usually delivers ambiguous results. To help overcome this problem, we use a numerical modeling tool that quantifies the seismic properties of fractured rock formations that are typically found in magmatic geothermal systems. We incorporate the physics of the pore fluids, ranging from the liquid to the boiling and ultimately vapor state. Furthermore, we consider the hydromechanics of permeable structures at different scales from small cooling joints to large caldera faults as are known to be present in volcanic systems. Our modeling techniques simulate oscillatory compressibility and shear tests and yield the P- and S-wave velocities and attenuation factors of fluid saturated fractured rock volumes. To apply this modeling technique to realistic scenarios, numerous input parameters need to be indentified. The properties of the rock matrix and individual fractures were derived from extensive literature research including a large number of laboratory-based studies. The geometries of fracture networks were provided by structural geologists from their published studies of outcrops. Finally, the physical properties of the pore fluid, ranging from those at ambient pressures and temperatures up to the supercritical conditions, were taken from the fluid physics

  7. Polyphase tectono-magmatic and fluid history related to mantle exhumation in an ultra-distal rift domain: example of the fossil Platta domain, SE Switzerland (United States)

    Epin, Marie-Eva; Manatschal, Gianreto; Amann, Méderic; Lescanne, Marc


    Despite the fact that many studies have investigated mantle exhumation at magma-poor rifted margins, there are still numerous questions concerning the 3D architecture, magmatic, fluid and thermal evolution of these ultra-distal domains that remain unexplained. Indeed, it has been observed in seismic data from ultra-distal magma-poor rifted margins that top basement is heavily structured and complex, however, the processes controlling the morpho-tectonic and magmatic evolution of these domains remain unknown. The aim of this study is to describe the 3D top basement morphology of an exhumed mantle domain, exposed over 200 km2 in the fossil Platta domain in SE Switzerland, and to define the timing and processes controlling its evolution. The examined Platta nappe corresponds to a remnant of the former ultra-distal Adriatic margin of the Alpine Tethys. The rift-structures are relatively well preserved due to the weak Alpine tectonic and metamorphic overprint during the emplacement in the Alpine nappe stack. Detailed mapping of parts of the Platta nappe enabled us to document the top basement architecture of an exhumed mantle domain and to investigate its link to later, rift/oceanic structures, magmatic additions and fluids. Our observations show a polyphase and/or complex: 1) deformation history associated with mantle exhumation along low-angle exhumation faults overprinted by later high-angle normal faults, 2) top basement morphology capped by magmato-sedimentary rocks, 3) tectono-magmatic evolution that includes gabbros, emplaced at deeper levels and subsequently exhumed and overlain by younger extrusive magmatic additions, and 4) fluid history including serpentinization, calcification, hydrothermal vent, rodingitization and spilitization affecting exhumed mantle and associated magmatic rocks. The overall observations provide important information on the temporal and spatial evolution of the tectonic, magmatic and fluid systems controlling the formation of ultra

  8. A model of sulphur solubility for hydrous mafic melts: application to the determination of magmatic fluid compositions of Italian volcanoes

    Directory of Open Access Journals (Sweden)

    M. Pichavant


    Full Text Available We present an empirical model of sulphur solubility that allows us to calculate f S2 if P, T, fO2 and the melt composition, including H2O and S, are known. The model is calibrated against three main experimental data bases consisting in both dry and hydrous silicate melts. Its prime goal is to calculate the f S2 of hydrous basalts that currently lack experimental constraints of their sulphur solubility behaviour. Application of the model to Stromboli, Vesuvius, Vulcano and Etna eruptive products shows that the primitive magmas found at these volcanoes record f S2 in the range 0.1-1 bar. In contrast, at all volcanoes the magmatic evolution is marked by dramatic variations in f S2 that spreads over up to 9 orders of magnitude. The f S2 can either increase during differentiation or decrease during decompression to shallow reservoirs, and seems to be related to closed versus open conduit conditions, respectively. The calculated f S2 shows that the Italian magmas are undersaturated in a FeS melt, except during closed conduit conditions, in which case differentiation may eventually reach conditions of sulphide melt saturation. The knowledge of f S2, fO2 and fH2O allows us to calculate the fluid phase composition coexisting with magmas at depth in the C-O-H-S system. Calculated fluids show a wide range in composition, with CO2 mole fractions of up to 0.97. Except at shallow levels, the fluid phase is generally dominated by CO2 and H2O species, the mole fractions of SO2 and H2S rarely exceeding 0.05 each. The comparison between calculated fluid compositions and volcanic gases shows that such an approach should provide constraints on both the depth and mode of degassing, as well as on the amount of free fluid in magma reservoirs. Under the assumption of a single step separation of the gas phase in a closed-system condition, the application to Stromboli and Etna suggests that the main reservoirs feeding the eruptions and persistent

  9. Petrography and Mineral Chemistry of Magmatic and Hydrothermal Biotite in Porphyry Copper-Gold Deposits: A Tool for Understanding Mineralizing Fluid Compositional Changes During Alteration Processes


    Arifudin Idrus


    DOI: 10.17014/ijog.5.1.47-64This study aims to understand the petrography and chemistry of both magmatic and hydrothermal biotites in porphyry copper-gold deposits, and to evaluate the fluid compositional changes during alteration processes. A total of 206 biotite grains from selected rock samples taken from the Batu Hijau porphyry Cu-Au deposit was analyzed. Detailed petrography and biotite chemistry analysis were performed on thin sections and polished thin sections, respectively, represent...



    Caumon , Marie-Camille; Tarantola , Alexandre


    International audience; Introduction: Crustal fluids play a major role in ore deposits, basin diagenesis and metamorphic reactions, among others. The knowledge of the chemical composition of individual fluid inclusions is essential for the understanding of past fluid transport and circulations. Microthermometry, by the observation of specific phase transitions as a function of temperature, is the general approach to determine salinity in aqueous fluid inclusions [1]. However in some cases, th...

  11. Magmatic-hydrothermal fluid evolution of the Dalli porphyry Cu-Au deposit; using Amphibole and Plagioclas mineral chemistry

    Directory of Open Access Journals (Sweden)

    Houshang Pourkaseb


    Full Text Available Introduction The formation of porphyry copper deposits is attributed to the shallow emplacement, and subsequent cooling of the hydrothermal system of porphyritic intrusive rocks (Titley and Bean, 1981. These deposits have usually been developed along the chain of subduction-related volcanic and calc-alkalin batholiths (Sillitoe, 2010. Nevertheless, it is now confirmed that porphyry copper systems can also form in collisional and post collisional settings (Zarasvandi et al., 2015b. Detailed studies on the geochemical features of ore-hosting porphyry Cu-Mo-Au intrusions indicate that they are generally adakitic, water and sulfur- riched, and oxidized (Wang et al., 2014. For example, high oxygen fugacity of magma has decisive role in transmission of copper and gold to the porphyry systems as revealed in (Wang et al., 2014. In this regard, the present work deals with the mineral chemistry of amphibole and plagioclase in the Dalli porphyry Cu-Au deposit. The data is used to achieve the physical and chemical conditions of magma and its impact on mineralization. Moreover, the results of previous studies on the hydrothermal system of the Dalli deposit such as Raman laser spectroscopy and fluid inclusion studies are included for determination of the evolution from magmatic to hydrothermal conditions. Materials and methods In order to correctly characterize the physical and chemical conditions affecting the trend of mineralization, 20 least altered and fractured samples of diorite and quartz-diorite intrusions were chosen from boreholes. Subsequently, 20 thin-polished sections were prepared in the Shahid Chamran University of Ahvaz. Finally, mineral chemistry of amphibole and plagioclase were determined using electron micro probe analyses (EMPA in the central lab of the Leoben University. Results Amphibole that is one of the the main rock-forming minerals can form in a wide variety of igneous and metamorphic rocks. Accordingly, amphibole chemistry can be

  12. The search for and analysis of direct samples of early Solar System aqueous fluids. (United States)

    Zolensky, Michael E; Bodnar, Robert J; Yurimoto, Hisayoshi; Itoh, Shoichi; Fries, Marc; Steele, Andrew; Chan, Queenie H-S; Tsuchiyama, Akira; Kebukawa, Yoko; Ito, Motoo


    We describe the current state of the search for direct, surviving samples of early, inner Solar System fluids-fluid inclusions in meteorites. Meteoritic aqueous fluid inclusions are not rare, but they are very tiny and their characterization is at the state of the art for most analytical techniques. Meteoritic fluid inclusions offer us a unique opportunity to study early Solar System brines in the laboratory. Inclusion-by-inclusion analyses of the trapped fluids in carefully selected samples will, in the immediate future, provide us detailed information on the evolution of fluids as they interacted with anhydrous solid materials. Thus, real data can replace calculated fluid compositions in thermochemical calculations of the evolution of water and aqueous reactions in comets, asteroids, moons and the terrestrial planets.This article is part of the themed issue 'The origin, history and role of water in the evolution of the inner Solar System'. © 2017 The Author(s).

  13. Gas geochemistry of the magmatic-hydrothermal fluid reservoir in the Copahue-Caviahue Volcanic Complex (Argentina) (United States)

    Agusto, M.; Tassi, F.; Caselli, A. T.; Vaselli, O.; Rouwet, D.; Capaccioni, B.; Caliro, S.; Chiodini, G.; Darrah, T.


    Copahue volcano is part of the Caviahue-Copahue Volcanic Complex (CCVC), which is located in the southwestern sector of the Caviahue volcano-tectonic depression (Argentina-Chile). This depression is a pull-apart basin accommodating stresses between the southern Liquiñe-Ofqui strike slip and the northern Copahue-Antiñir compressive fault systems, in a back-arc setting with respect to the Southern Andean Volcanic Zone. In this study, we present chemical (inorganic and organic) and isotope compositions (δ13C-CO2, δ15N, 3He/4He, 40Ar/36Ar, δ13C-CH4, δD-CH4, and δD-H2O and δ18O-H2O) of fumaroles and bubbling gases of thermal springs located at the foot of Copahue volcano sampled in 2006, 2007 and 2012. Helium isotope ratios, the highest observed for a Southern American volcano (R/Ra up to 7.94), indicate a non-classic arc-like setting, but rather an extensional regime subdued to asthenospheric thinning. δ13C-CO2 values (from - 8.8‰ to - 6.8‰ vs. V-PDB), δ15N values (+ 5.3‰ to + 5.5‰ vs. Air) and CO2/3He ratios (from 1.4 to 8.8 × 109) suggest that the magmatic source is significantly affected by contamination of subducted sediments. Gases discharged from the northern sector of the CCVC show contribution of 3He-poor fluids likely permeating through local fault systems. Despite the clear mantle isotope signature in the CCVC gases, the acidic gas species have suffered scrubbing processes by a hydrothermal system mainly recharged by meteoric water. Gas geothermometry in the H2O-CO2-CH4-CO-H2 system suggests that CO and H2 re-equilibrate in a separated vapor phase at 200°-220 °C. On the contrary, rock-fluid interactions controlling CO2, CH4 production from Sabatier reaction and C3H8 dehydrogenation seem to occur within the hydrothermal reservoir at temperatures ranging from 250° to 300 °C. Fumarole gases sampled in 2006-2007 show relatively low N2/He and N2/Ar ratios and high R/Ra values with respect to those measured in 2012. Such compositional and

  14. Electroresponsive Aqueous Silk Protein As “Smart” Mechanical Damping Fluid (United States)


    Here we demonstrate the effectiveness of an electroresponsive aqueous silk protein polymer as a smart mechanical damping fluid. The aqueous polymer solution is liquid under ambient conditions, but is reversibly converted into a gel once subjected to an electric current, thereby increasing or decreasing in viscosity. This nontoxic, biodegradable, reversible, edible fluid also bonds to device surfaces and is demonstrated to reduce friction and provide striking wear protection. The friction and mechanical damping coefficients are shown to modulate with electric field exposure time and/or intensity. Damping coefficient can be modulated electrically, and then preserved without continued power for longer time scales than conventional “smart” fluid dampers. PMID:24750065

  15. Natural tracers for identifying the origin of the thermal fluids emerging along the Aegean Volcanic arc (Greece): Evidence of Arc-Type Magmatic Water (ATMW) participation (United States)

    Dotsika, E.; Poutoukis, D.; Michelot, J. L.; Raco, B.


    The Aegean volcanic arc is the result of a lithosphere subduction process during the Quaternary time. Starting from the Soussaki area, from west to east, the arc proceeds through the islands of Egina, Methana, Milos, Santorini, the Columbus Bank, Kos and Nisyros. Volcano-tectonic activities are still pronounced at Santorini and Nisyros in form of seismic activity, craters of hydrothermal explosions, hot fumaroles and thermal springs. A significant number of cold water springs emerge in the vicinity of hot waters on these islands. Chemical and isotopic analyses were applied on water and fumaroles samples collected in different areas of the volcanic arc in order to attempt the assessment of these fluids. Stable isotopes of water and carbon have been used to evaluate the origin of cold and thermal water and CO 2. Chemical solute concentrations and isotopic contents of waters show that the fluids emerging in Egina, Soussaki, Methana and Kos areas represent geothermal systems in their waning stage, while the fluids from Milos, Santorini and Nisyros proceed from active geothermal systems. The δ 2H-δ 18O-Cl - relationships suggest that the parent hydrothermal liquids of Nisyros and Milos are produced through mixing of seawater and Arc-Type Magmatic Water (ATMW), with negligible to nil contribution of local ground waters and with very high participation of the magmatic component, which is close to 70% in both sites. A very high magmatic contribution to the deep geothermal system could occur at Santorini as well, perhaps with a percentage similar to Nisyros and Milos, but it cannot be calculated because of steam condensation heavily affecting the fumarolic fluids of Nea Kameni before the surface discharge. The parent hydrothermal liquid at Methana originates through mixing of local groundwaters, seawater and ATMW, with a magmatic participation close to 19%. All in all, the contribution of ATMW is higher in the central-eastern part of the Aegean volcanic arc than in the

  16. Influence of clay and surfactant content in non-aqueous fluid rheology

    International Nuclear Information System (INIS)

    Guedes, I.C.; Gomes, N.L.; Menezes, R.R.; Campos, L.F.A.; Ferreira, H.S.


    The bentonite clay used as viscosity agent in the production of non-aqueous fluids cannot be used without organic treatment for their surfaces to become hydrophobic. These clays are called organophilic clays, and are generally obtained by adding, in an aqueous way, ionic or a nonionic surfactant. Recent studies of the variables involved in the dispersion of bentonite clays and in the process of organophilization, showed their lack of influence. This work aims to study the influence of clay content and surfactants on the rheology of nonaqueous fluids. To this end, the clays were treats and characterized, evidencing the incorporation of the surfactant, and then formulated non-aqueous fluids, following PETROBRAS standards, being possible to verify the influence of clay content and surfactant both from the point of view as the characterizing and rheological behavior. (author)

  17. Magmatic-hydrothermal fluids and volatile metals in the Spirit Lake pluton and Margaret Cu-Mo porphyry system, SW Washington, USA (United States)

    Iveson, Alexander A.; Webster, James D.; Rowe, Michael C.; Neill, Owen K.


    The halogen-bearing minerals tourmaline, amphibole, and biotite formed during magmatic-hydrothermal processes associated with the late-stage cooling of the Spirit Lake granitoid pluton (Mt. St. Helens, WA) and with the younger sulphide-mineralised rocks of the Margaret Cu-Mo porphyry deposit located entirely within the pluton. Major- and trace-element discrimination suggests that one tourmaline population crystallised from fractionated late-stage melt pockets in granodiorite-monzogranitic dykes of the pluton. These coarse, euhedral, oscillatory, and complexly sector-zoned uvite tourmalines span a limited range in Mg/(Mg + Fe) [Mg#] space (0.4-0.7 apfu) and show the highest Ti, Ca, F, Nb, and Ta contents, and low X-site vacancies (X-site vacancies (>0.6 apfu), lower Ca and F contents, and the highest Li, As, and HREE contents (>80 ppm Li, >1200 ppm As). This population appears to record direct, rapid crystallisation from magmatic ± meteoric fluid(s) bearing the signature of the breakdown of primary feldspars and pyroxenes, with fluid exsolution from fractionated melt patches likely triggered by the formation of the previous generation of tourmaline. Mineralised porphyry deposit tourmaline compositions from the stockwork span a much larger range in Mg# space (0.05-0.9 apfu) and are almost entirely Ca-free. X-sites of these schorl tourmalines are dominated by Na or vacancies, and the Y-sites are strongly Fe enriched. The highest Mn and Zn concentrations (>4000 and >1000 ppm, respectively) potentially reflect the composition of mineralising fluids during ore deposition. A number of boron isotopic analyses yield predominantly heavy boron, but δ11B values range from -5.2 to 6.2 ‰ and average 1.4 ‰. Whilst most plutonic tourmalines conform to reported a- and c-sector element partitioning models, those from the mineralised porphyry show large and variable sector fractionation differences, suggesting that external controls may also be important. Wider evidence for

  18. Fluid and structure coupling analysis of the interaction between aqueous humor and iris. (United States)

    Wang, Wenjia; Qian, Xiuqing; Song, Hongfang; Zhang, Mindi; Liu, Zhicheng


    Glaucoma is the primary cause of irreversible blindness worldwide associated with high intraocular pressure (IOP). Elevated intraocular pressure will affect the normal aqueous humor outflow, resulting in deformation of iris. However, the deformation ability of iris is closely related to its material properties. Meanwhile, the passive deformation of the iris aggravates the pupillary block and angle closure. The nature of the interaction mechanism of iris deformation and aqueous humor fluid flow has not been fully understood and has been somewhat a controversial issue. The purpose here was to study the effect of IOP, localization, and temperature on the flow of the aqueous humor and the deformation of iris interacted by aqueous humor fluid flow. Based on mechanisms of aqueous physiology and fluid dynamics, 3D model of anterior chamber (AC) was constructed with the human anatomical parameters as a reference. A 3D idealized standard geometry of anterior segment of human eye was performed. Enlarge the size of the idealization geometry model 5 times to create a simulation device by using 3D printing technology. In this paper, particle image velocimetry technology is applied to measure the characteristic of fluid outflow in different inlet velocity based on the device. Numerically calculations were made by using ANSYS 14.0 Finite Element Analysis. Compare of the velocity distributions to confirm the validity of the model. The fluid structure interaction (FSI) analysis was carried out in the valid geometry model to study the aqueous flow and iris change. In this paper, the validity of the model is verified through computation and comparison. The results indicated that changes of gravity direction of model significantly affected the fluid dynamics parameters and the temperature distribution in anterior chamber. Increased pressure and the vertical position increase the velocity of the aqueous humor fluid flow, with the value increased of 0.015 and 0.035 mm/s. The results

  19. Designing magnetic composite materials using aqueous magnetic fluids

    CERN Document Server

    Galicia, J A; Cousin, F; Guemghar, D; Menager, C; Cabuil, V


    In this paper, we report on how to take advantage of good knowledge of both the chemistry and the stability of an aqueous magnetic colloidal suspension to realize different magnetic composites. The osmotic pressure of the magnetic nanoparticles is set prior to the realization of the composite to a given value specially designed for the purpose for each hybrid material: magnetic particles in polymer networks, particles as probes for studying the structure of clay suspensions and shape modification of giant liposomes. First, we show that the introduction of magnetic particles in polyacrylamide gels enhances their Young modulus and reduces the swelling caused by water. The particles cause both a mechanical and an osmotic effect. The latter is strongly dependent on the ionic strength and is attributed to an attraction between particles and the polymeric matrix. In the second part, we determine the microscopic structure of suspensions of laponite as a function of concentration, by combining SANS and magneto-optica...

  20. Enhanced oil recovery using improved aqueous fluid-injection methods: an annotated bibliography. [328 citations

    Energy Technology Data Exchange (ETDEWEB)

    Meister, M.J.; Kettenbrink, G.K.; Collins, A.G.


    This annotated bibliography contains abstracts, prepared by the authors, of articles published between 1968 and early 1976 on tests of improved aqueous fluid injection methods (i.e., polymer and surfactant floods). The abstracts have been written and organized to facilitate studies of the oil recovery potential of polymer and surfactant floods under known reservoir conditions. 328 citations.

  1. In situ study at high pressure and temperature of the environment of water in hydrous Na and Ca aluminosilicate melts and coexisting aqueous fluids (United States)

    Le Losq, Charles; Dalou, Célia; Mysen, Bjorn O.


    The bonding and speciation of water dissolved in Na silicate and Na and Ca aluminosilicate melts were inferred from in situ Raman spectroscopy of the samples, in hydrothermal diamond anvil cells, while at crustal temperature and pressure conditions. Raman data were also acquired on Na silicate and Na and Ca aluminosilicate glasses, quenched from hydrous melts equilibrated at high temperature and pressure in a piston cylinder apparatus. In the hydrous melts, temperature strongly influences O-H stretching ν(O-H) signals, reflecting its control on the bonding of protons between different molecular complexes. Pressure and melt composition effects are much smaller and difficult to discriminate with the present data. However, the chemical composition of the melt + fluid system influences the differences between the ν(O-H) signals from the melts and the fluids and, hence, between their hydrogen partition functions. Quenching modifies the O-H stretching signals: strong hydrogen bonds form in the glasses below the glass transition temperature Tg, and this phenomenon depends on glass composition. Therefore, glasses do not necessarily record the O-H stretching signal shape in melts near Tg. The melt hydrogen partition function thus cannot be assessed with certainty using O-H stretching vibration data from glasses. From the present results, the ratio of the hydrogen partition functions of hydrous silicate melts and aqueous fluids mostly depends on temperature and the bulk melt + fluid system chemical composition. This implies that the fractionation of hydrogen isotopes between magmas and aqueous fluids in water-saturated magmatic systems with differences in temperature and bulk chemical composition will be different.

  2. Magmatic nature of Sn-bearing fluids from isotopic (H,O) data of tourmalines (Solnechnoye deposit, Far East of Russia) (United States)

    Sushchevskaya, Tatiana; Ignatiev, Alexander; Velivetskaya, Tatiana


    It was shown, that the main factors, controlled Sn-W ore deposition in hydrothermal systems in connection with granites were: a) cooling, b) mixing of fluids of different composition and genesis, c) heterogenization (boiling) of mineral forming fluids (Heinrich, 1990; et al). The results of physical chemical modelling of water-rock interaction pointed to magmatic nature of tin-bearing fluids in the hydrothermal systems, connected with granites. Tin concentration in model magmatogeneous fluid was calculated to be three times higher than in the model exogenic fluid (Sushchevskaya, Ryzhenko, 1998). New data on the source of ore forming fluids, which had formed the large economic Solnechnoye Sn deposit (Far East of Russia), were obtained from hydrogen and oxygen isotopic composition of tourmalines from successive mineral associations. Hydrogen position in the tourmaline crystal structure allows to suppose, that postproductive processes did not change the initial δD values, in contrast to phyllosilicates, often used for this purpose. During mineral formation at the Solnechnoye deposit tourmaline was formed practically without interruption. Its composition was gradually changed from schorl to dravite, when temperature decreased. The ores of cassiterite-tourmaline type were formed in a vertically dipping fracture zones, extended in a metamorphosed sandstone-shale rocks. Hydrogene and oxygen isotopic composition of fluids were calculated from tourmaline data with the help of equations, proposed in (Kotzer et al., 1993). The temperature intervals for these calculations were accepted as: 1- 450-400o C for quartz-tourmaline preore stage, 2 - 400-350o C -for early productive quartz-cassiterite stage, 3 - 350-300o C - for late quartz- cassiterite stage. The obtained results corresponded to magmatic character of the fluids of productive stage of the Solnechnoye deposit, because their isotopic composition lied in the interval: δ18О (3.2-9.3)‰, δD -(31.7-76.6)‰. The

  3. Alumino-silicate speciation in aqueous fluids at deep crustal conditions (United States)

    Mookherjee, M.; Keppler, H.; Manning, C. E.


    Alumina and silica are major oxides in most crustal rocks. While SiO2 is quite soluble in aqueous fluids at metamorphic conditions, behavior of Al2O3 in crustal metamorphic fluids has been poorly understood. It is known that alumina is dramatically less soluble in aqueous fluids and hence it is difficult to explain the common occurrence of quartz with aluminous minerals in metamorphic veins. In order to understand this complex behavior of alumina, we investigated aluminum speciation in aqueous fluids in equilibrium with corundum using in situ Raman spectroscopy in hydrothermal diamond anvil cells to 20 kbar and 1000 oC. In order to better understand the spectral features of the aqueous fluids, we used first principles simulations based on density functional theory to calculate and predict the energetics and vibrational spectra for various aluminum species that are likely to be present in aqueous solutions. The Raman spectra of pure water in equilibrium with Al2O3 are devoid of any characteristic spectral features. In contrast, aqueous fluids with KOH solution in equilibrium with Al2O3 show a sharp band at ~620 cm-1 which could be attributed to the [Al(OH)4]1- species. The band grows in intensity with temperature along an isochore. In the limited pressure, temperature and density explored in the present study, we do not find any evidence for the polymerization of the [Al(OH)4]1- species to dimers [(OH)2-Al-O2-Al(OH)2]2- or [(OH)3-Al-O-Al(OH)3]2-. This is likely due to the relatively low concentration of Al in the solutions and does not rule out significant polymerization at higher pressures and temperatures. We are also investigating the effect of SiO2 on the solubility of Al2O3 and the relative energetics of formation of pure alumina dimer [(OH)3-Al-O-Al(OH)3]2- vs. the aluminosilicate dimers, [(OH)3-Al-O-Si(OH)3]2- at deep crustal conditions. Acknowledgement- MM is supported by the US National Science Foundation grant (EAR-1250477).

  4. Immiscibility of Fluid Phases at Magmatic-hydrothermal Transition: Formation of Various PGE-sulfide Mineralization for Layered Basic Intrusions (United States)

    Zhitova, L.; Borisenko, A.; Morgunov, K.; Zhukova, I.


    Fluid inclusions in quartz of the Merensky Reef (Bushveld Complex, South Africa) and the Chineisky Pluton (Transbaikal Region, Russia) were studied using cryometry, microthermometry, Raman-spectroscopy, LA ICP- MS, scanning electronic microscopy, gas-chromatography and isotopic methods. This allowed us to document some examples of fluid phase separation resulting in formation of different types of PGE-sulfide mineralization for layered basic intrusions. The results obtained show at least three generations of fluid separated from boiling residual alumosilicate intercumulus liquid of the Merensky Reef. The earliest fluid phase composed of homogenous high-dense methane and nitrogen gas mixture was identified in primary gas and co-existing anomalous fluid inclusions from symplectitic quartz. The next generation, heterophase fluid, composed of brines containing a free low-dense (mostly of carbon dioxide) gas phase, was observed in primary multiphase and coexisting gas-rich inclusions of miarolitic quartz crystals. The latest generation was also a heterophase fluid (low salinity water-salt solution and free low-dense methane gas phase) found in primary water-salt and syngenetic gas inclusions from peripheral zones of miarolitic quartz crystals. For the Chineisky Pluton reduced endocontact magmatogene fluids changed to oxidized low salinity hydrothermal fluids in exocontact zone. This resulted in formation of sulfide-PGE enrichment marginal zones of intrusion. The results obtained give us a possibility to suggest that: 1) Fluid phase separation is a typical feature of magmatogene fluids for layered basic intrusions. 2) Reduced fluids can extract and transport substantial PGE and sulfide concentrations. 3) Oxidation of reduced fluids is one of the most important geochemical barriers causing abundant PGE minerals and sulfides precipitation. This in turn results in both formation of PGE reefs or enriched contact zones of layered basic intrusions. This work was supported by

  5. Time-lapse integrated geophysical imaging of magmatic injections and fluid-induced fracturing causing Campi Flegrei 1983-84 Unrest (United States)

    De Siena, Luca; Crescentini, Luca; Amoruso, Antonella; Del Pezzo, Edoardo; Castellano, Mario


    Geophysical precursors measured during Unrest episodes are a primary source of geophysical information to forecast eruptions at the largest and most potentially destructive volcanic calderas. Despite their importance and uniqueness, these precursors are also considered difficult to interpret and unrepresentative of larger eruptive events. Here, we show how novel geophysical imaging and monitoring techniques are instead able to represent the dynamic evolution of magmatic- and fluid-induced fracturing during the largest period of Unrest at Campi Flegrei caldera, Italy (1983-1984). The time-dependent patterns drawn by microseismic locations and deformation, once integrated by 3D attenuation tomography and absorption/scattering mapping, model injections of magma- and fluid-related materials in the form of spatially punctual microseismic bursts at a depth of 3.5 km, west and offshore the city of Pozzuoli. The shallowest four kilometres of the crust work as a deformation-based dipolar system before and after each microseismic shock. Seismicity and deformation contemporaneously focus on the point of injection; patterns then progressively crack the medium directed towards the second focus, a region at depths 1-1.5 km south of Solfatara. A single high-absorption and high-scattering aseismic anomaly marks zones of fluid storage overlying the first dipolar centre. These results provide the first direct geophysical signature of the processes of aseismic fluid release at the top of the basaltic basement, producing pozzolanic activity and recently observed via rock-physics and well-rock experiments. The microseismicity caused by fluids and gasses rises to surface via high-absorption north-east rising paths connecting the two dipolar centres, finally beingq being generally expelled from the maar diatreme Solfatara structure. Geophysical precursors during Unrest depict how volcanic stress was released at the Campi Flegrei caldera during its period of highest recorded seismicity

  6. Antioxidant content and cytological examination of aqueous fluid from patients with age-related cataracts at different stages. (United States)

    Wang, X; Sun, J; Dang, G F; Gao, Y; Duan, L; Wu, X Y


    We investigated the antioxidant content and conducted a cytological examination of the aqueous fluid and lenses of patients with age-related cataracts at different stages. The levels of superoxide dismutase (SOD), catalase (CAT), and glutathione peroxidase (GSH-PX) in the aqueous fluid and lenses were determined by the xanthine oxidase method, the colorimetric method, and the improved reduced glutathione (GSH) depletion method, respectively. SOD, CAT, and GSH-PX content in the aqueous fluid and lenses decreased significantly with increasing lenticular nucleus hardness grading. However, the number of white blood cells, neutrophils, monocytes, lymphocytes, and eosinophils did not vary significantly with varying lenticular nucleus hardness. Antioxidant content examination is an important quantitative indicator for clinical diagnosis and treatment of age-related cataracts. Antioxidant content in the aqueous fluid and lenses decreased significantly with increasing lenticular nucleus hardness grading. Lenses at hardness level V had the lowest content of antioxidants.

  7. Petrography and Mineral Chemistry of Magmatic and Hydrothermal Biotite in Porphyry Copper-Gold Deposits: A Tool for Understanding Mineralizing Fluid Compositional Changes During Alteration Processes

    Directory of Open Access Journals (Sweden)

    Arifudin Idrus


    Full Text Available DOI: 10.17014/ijog.5.1.47-64This study aims to understand the petrography and chemistry of both magmatic and hydrothermal biotites in porphyry copper-gold deposits, and to evaluate the fluid compositional changes during alteration processes. A total of 206 biotite grains from selected rock samples taken from the Batu Hijau porphyry Cu-Au deposit was analyzed. Detailed petrography and biotite chemistry analysis were performed on thin sections and polished thin sections, respectively, representing various rocks and alteration types. A JEOL JXA-8900R electron microprobe analyzer (EMPA was used for the chemistry analysis. The biotite is texturally divided into magmatic and hydrothermal types. Ti, Fe, and F contents can be used to distinguish the two biotite types chemically. Some oxide and halogen contents of biotite from various rocks and alteration types demonstrate a systematic variation in chemical composition. Biotite halogen chemistry shows a systematic increase in log (XCl/XOH and decrease in log (XF/XOH values from biotite (potassic through chlorite-sericite (intermediate argillic to actinolite (inner propylitic zones. The y-intercepts on the log (XCl/XOH vs. XMg and log (XF/XOH vs. XFe plotted for biotite from potassic and intermediate argillic zones are similar or slightly different. In contrast, the y-intercepts on the log (XCl/XOH vs. XMg and log (XF/XOH vs. XFe plotted for biotite from inner propylitic zone display different values in comparison to the two alteration zones. Halogen (F,Cl fugacity ratios in biotite show a similar pattern: in the potassic and intermediate argillic zones they show little variation, whereas in the inner propylitic zone they are distinctly different. These features suggest the hydrothermal fluid composition remained fairly constant in the inner part of the deposit during the potassic and intermediate argillic alteration events, but changed significantly towards the outer part affected by inner propylitic

  8. Structural aspects of magnetic fluid stabilization in aqueous agarose solutions

    Energy Technology Data Exchange (ETDEWEB)

    Nagornyi, A.V. [Joint Institute for Nuclear Research, Dubna (Russian Federation); Taras Shevchenko National University of Kyiv, Kyiv (Ukraine); Petrenko, V.I., E-mail: [Joint Institute for Nuclear Research, Dubna (Russian Federation); Taras Shevchenko National University of Kyiv, Kyiv (Ukraine); Avdeev, M.V. [Joint Institute for Nuclear Research, Dubna (Russian Federation); Yelenich, O.V.; Solopan, S.O.; Belous, A.G. [V.I.Vernadsky Institute of General and Inorganic Chemistry of the Ukrainian NAS, Kyiv (Ukraine); Gruzinov, A.Yu. [National Research Centre “Kurchatov Institute”, Moscow (Russian Federation); Ivankov, O.I. [Joint Institute for Nuclear Research, Dubna (Russian Federation); Institute for Safety Problems of Nuclear Power Plants of the Ukrainian NAS, Kyiv (Ukraine); Bulavin, L.A. [Taras Shevchenko National University of Kyiv, Kyiv (Ukraine); Institute for Safety Problems of Nuclear Power Plants of the Ukrainian NAS, Kyiv (Ukraine)


    Structure characterization of magnetic fluids (MFs) synthesized by three different methods in aqueous solutions of agarose was done by means of small-angle neutron (SANS) and synchrotron X-ray scattering (SAXS). The differences in the complex aggregation observed in the studied magnetic fluids were related to different stabilizing procedures of the three kinds of MFs. The results of the analysis of the scattering (mean size of single polydisperse magnetic particles, fractal dimensions of the aggregates) are consistent with the data of transmission electron microscopy (TEM). - Highlights: • MFs synthesized by three different methods in agarose solution were studied. • all MFs are agglomerated colloidal systems whose structures are nevertheless stable in time. • differences in the complex aggregation were observed in the studied magnetic fluids. • results of the SAXS and SANS analysis are consistent with TEM data.

  9. The interplay of evolved seawater and magmatic-hydrothermal fluids in the 3.24 Ga panorama volcanic-hosted massive sulfide hydrothermal system, North Pilbara Craton, Western Australia (United States)

    Drieberg, Susan L.; Hagemann, Steffen G.; Huston, David L.; Landis, Gary; Ryan, Chris G.; Van Achterbergh, Esmé; Vennemann, Torsten


    The ~3240 Ma Panorama volcanic-hosted massive sulfide (VHMS) district is unusual for its high degree of exposure and low degree of postdepositional modification. In addition to typical seafloor VHMS deposits, this district contains greisen- and vein-hosted Mo-Cu-Zn-Sn mineral occurrences that are contemporaneous with VHMS orebodies and are hosted by the Strelley granite complex, which also drove VHMS circulation. Hence the Panorama district is a natural laboratory to investigate the role of magmatic-hydrothermal fluids in VHMS hydrothermal systems. Regional and proximal high-temperature alteration zones in volcanic rocks underlying the VHMS deposits are dominated by chlorite-quartz ± albite assemblages, with lesser low-temperature sericite-quartz ± K-feldspar assemblages. These assemblages are typical of VHMS hydrothermal systems. In contrast, the alteration assemblages associated with granite-hosted greisens and veins include quartz-topaz-muscovite-fluorite and quartz-muscovite (sericite)-chlorite-ankerite. These vein systems generally do not extend into the overlying volcanic pile. Fluid inclusion and stable isotope studies suggest that the greisens were produced by high-temperature (~590°C), high-salinity (38–56 wt % NaCl equiv) fluids with high densities (>1.3 g/cm3) and high δ18O (9.3 ± 0.6‰). These fluids are compatible with the measured characteristics of magmatic fluids evolved from the Strelley granite complex. In contrast, fluids in the volcanic pile (including the VHMS ore-forming fluids) were of lower temperature (90°–270°C), lower salinity (5.0–11.2 wt % NaCl equiv), with lower densities (0.88–1.01 g/cm3) and lower δ18O (−0.8 ± 2.6‰). These fluids are compatible with evolved Paleoarchean seawater. Fluids that formed the quartz-chalcopyrite-sphalerite-cassiterite veins, which are present within the granite complex near the contact with the volcanic pile, were intermediate in temperature and isotopic composition between the greisen

  10. Aqueous clay suspensions stabilized by alginate fluid gels for coal spontaneous combustion prevention and control. (United States)

    Qin, Botao; Ma, Dong; Li, Fanglei; Li, Yong


    We have developed aqueous clay suspensions stabilized by alginate fluid gels (AFG) for coal spontaneous combustion prevention and control. Specially, this study aimed to characterize the effect of AFG on the microstructure, static and dynamic stability, and coal fire inhibition performances of the prepared AFG-stabilized clay suspensions. Compared with aqueous clay suspensions, the AFG-stabilized clay suspensions manifest high static and dynamic stability, which can be ascribed to the formation of a robust three-dimensional gel network by AFG. The coal acceleration oxidation experimental results show that the prepared AFG-stabilized clay suspensions can improve the coal thermal stability and effectively inhibit the coal spontaneous oxidation process by increasing crossing point temperature (CPT) and reducing CO emission. The prepared low-cost and nontoxic AFG-stabilized clay suspensions, exhibiting excellent coal fire extinguishing performances, indicate great application potentials in coal spontaneous combustion prevention and control.

  11. Influence of clay, surfactant and presence of dispersant in the non-aqueous fluids rheology

    International Nuclear Information System (INIS)

    Gomes, N.L.; Guedes, I.C.; Menezes, R.R.; Campos, L.F.A.; Ferreira, H.S.


    The bentonite clay used as a thickening agent in production of non-aqueous fluids and can not be used without a prior treatment to their organic surfaces become hydrophobic. These treated clays are called organoclays, and are usually obtained by adding, in aqueous solution, a quaternary ammonium salt. This work makes a detailed study of the variables involved in the dispersion of the bentonite clays in organophilization process, as well, the type of clay, type of surfactant and the presence of dispersant. It was observed this study that the process variables involved in the dispersion of the clays and organophilization, observed through characterization, have low influence on the peaks related to interplanar basal distance caused by the incorporation of the surfactant and bentonite clays been influential the type of clay and surfactant and the presence of sodium as dispersant agent, on the rheological properties. (author)

  12. Ice-VII inclusions in diamonds: Evidence for aqueous fluid in Earth’s deep mantle (United States)

    Tschauner, O.; Huang, S.; Greenberg, E.; Prakapenka, V. B.; Ma, C.; Rossman, G. R.; Shen, A. H.; Zhang, D.; Newville, M.; Lanzirotti, A.; Tait, K.


    Water-rich regions in Earth’s deeper mantle are suspected to play a key role in the global water budget and the mobility of heat-generating elements. We show that ice-VII occurs as inclusions in natural diamond and serves as an indicator for such water-rich regions. Ice-VII, the residue of aqueous fluid present during growth of diamond, crystallizes upon ascent of the host diamonds but remains at pressures as high as 24 gigapascals; it is now recognized as a mineral by the International Mineralogical Association. In particular, ice-VII in diamonds points toward fluid-rich locations in the upper transition zone and around the 660-kilometer boundary.

  13. Aluminum speciation in aqueous fluids at deep crustal pressure and temperature (United States)

    Mookherjee, Mainak; Keppler, Hans; Manning, Craig E.


    We investigated aluminum speciation in aqueous fluids in equilibrium with corundum using in situ Raman spectroscopy in hydrothermal diamond anvil cells to 20 kbar and 1000 °C. We have studied aluminum species in (a) pure H2O, (b) 5.3 m KOH solution, and (c) 1 m KOH solution. In order to better understand the spectral features of the aqueous fluids, we used ab initio simulations based on density functional theory to calculate and predict the energetics and vibrational spectra for various aluminum species that are likely to be present in aqueous solutions. The Raman spectra of pure water in equilibrium with Al2O3 are devoid of any characteristic spectral features. In contrast, aqueous fluids with 5.3 m and 1 m KOH solution in equilibrium with Al2O3 show a sharp band at ˜620 cm-1 which could be attributed to the [ species. The band grows in intensity with temperature along an isochore. A shoulder on the high-frequency side of this band may be due to a hydrated, charge neutral Al(OH)3·H2O species. In the limited pressure, temperature and density explored in the present study, we do not find any evidence for the polymerization of the [ species to dimers [(OH)2-Al-(OH)2-Al(OH)2] or [(OH)3-Al-O-Al(OH)3]2-. This is likely due to the relatively low concentration of Al in the solutions and does not rule out significant polymerization at higher pressures and temperatures. Upon cooling of Al-bearing solutions to room temperatures, Raman bands indicating the precipitation of diaspore (AlOOH) were observed in some experiments. The Raman spectra of the KOH solutions (with or without dissolved alumina) showed a sharp OH stretching band at ˜3614 cm-1 and an in-plane OH bending vibration at ˜1068 cm-1, likely related to an OH- ion with the oxygen atom attached to a water molecule by hydrogen bonding. A weak feature at ˜935 cm-1 may be related to the out-of-plane bending vibration of the same species or to an OH species with a different environment.

  14. Fluid inclusions of the Horní Slavkov Sn-W ore deposit, Bohemian Massif, Czech Republic: evidence for non-magmatic source of greisenizing fluids?

    Czech Academy of Sciences Publication Activity Database

    Dolníček, Z.; René, Miloš; Prochaska, W.


    Roč. 87, - (2011), s. 68-69 ISSN 1017-8880. [Ecrofi XXI. 09.08.2011-11.08.2011, Leoben] R&D Projects: GA ČR GA205/09/0540 Institutional research plan: CEZ:AV0Z30460519 Keywords : fluid inclusion * greisen * tin ore Subject RIV: DB - Geology ; Mineralogy

  15. The partitioning of sulfur between multicomponent aqueous fluids and felsic melts (United States)

    Binder, Bernd; Wenzel, Thomas; Keppler, Hans


    Sulfur partitioning between melt and fluid phase largely controls the environmental impact of volcanic eruptions. Fluid/melt partitioning data also provide the physical basis for interpreting changes in volcanic gas compositions that are used in eruption forecasts. To better constrain some variables that control the behavior of sulfur in felsic systems, in particular the interaction between different volatiles, we studied the partitioning of sulfur between aqueous fluids and haplogranitic melts at 200 MPa and 750-850 °C as a function of oxygen fugacity (Ni-NiO or Re-ReO2 buffer), melt composition (Al/(Na + K) ratio), and fluid composition (NaCl and CO2 content). The data confirm a first-order influence of oxygen fugacity on the partitioning of sulfur. Under "reducing conditions" (Ni-NiO buffer), D fluid/melt is nearly one order of magnitude larger (323 ± 14 for a metaluminous melt) than under "oxidizing conditions" (Re-ReO2 buffer; 74 ± 5 for a metaluminous melt). This effect is likely related to a major change in sulfur speciation in both melt and fluid. Raman spectra of the quenched fluids show the presence of H2S and HS- under reducing conditions and of SO4 2- and HSO4 - under oxidizing conditions, while SO2 is undetectable. The latter observation suggests that already at the Re-ReO2 buffer, sulfur in the fluid is almost completely in the S6+ state and, therefore, more oxidized than expected according to current models. CO2 in the fluid (up to x CO2 = 0.3) has no effect on the fluid/melt partitioning of sulfur, neither under oxidizing nor under reducing conditions. However, the effect of NaCl depends on redox state. While at oxidizing conditions, D fluid/melt is independent of x NaCl, the fluid/melt partition coefficient strongly decreases with NaCl content under reducing conditions, probably due to a change from H2S to NaSH as dominant sulfur species in the fluid. A decrease of D fluid/melt with alkali content in the melt is observed over the entire

  16. Evolution of the magmatic-hydrothermal acid-sulfate system at Summitville, Colorado: Integration of geological, stable-isotope, and fluid-inclusion evidence (United States)

    Bethke, P.M.; Rye, R.O.; Stoffregen, R.E.; Vikre, P.G.


    quartz associated with mineralization, as well as in the deep stockwork veins, suggests that brines originating deep in the system transported the metals. The ??34S values of sulfides in magnetite (-2.3???) and of sulfate in apatite (5.4???) in unaltered quartz latite indicate that ??34S???S was near 0???. The ??34S values of coexisting alteration alunite and pyrite are 18.2??? to 24.5??? and -8.1??? to -2.2???, respectively. Deep in the system, most of the change in ??34S values occurs in the sulfates, indicating that the fluids were initially H2S-dominant, their redox state buffered at depth by equilibration with igneous rocks. However, in the main alteration zone, most of the change in ??34S values occurs in pyrite, indicating that the fluids moved off the rock buffer and became SO42- -dominant as pyrite precipitated and SO2 disproportionation produced the sulfuric acid requisite for acid leaching. The ??34S values of the late-stage barite and sulfides indicate that the system returned to high H2S/SO42- ratios typical of the original rock-buffered fluid. The ??DH2O of alunite parent fluids was near -45??? and their ??18O ranged from 7??? to -1???, depending on the degree of exchange in the alteration zone at low water-rock ratio, or mixing with unexchanged meteoric water. The low ??D values of some alunite samples are interpreted to result from postdepositional exchange with later ore fluids. Fluid exsolved fr om the magma at depth had ??DH2O and ??18OH2O values near -70??? and 10???, respectively. During and following migration to the top of the magma chamber, the fluid underwent isotopic exchange with the partially crystallized magma and its solid and cooler, but still plastic, carapace just below the transition from a lithostatic to hydrostatic pressure regime. These evolved magmatic fluids had ??DH2O and ??18OH2O values close to -40??? and 5???, respectively, prior to release into the superjacent hydrostatically pressured fracture zone, wherein the fluids separat

  17. The effect of magnetic field induced aggregates on ultrasound propagation in aqueous magnetic fluid

    International Nuclear Information System (INIS)

    Parekh, Kinnari; Upadhyay, R.V.


    Ultrasonic wave propagation in the aqueous magnetic fluid is investigated for different particle concentrations. The sound velocity decreases while acoustic impedance increases with increasing concentrations. The velocity anisotropy is observed upon application of magnetic field. The velocity anisotropy fits with Tarapov’s theory suggests the presence of aggregates in the system. We report that these aggregates are thermodynamically unstable and the length of aggregate changes continuously with increasing concentration and, or magnetic field and resulted in a decrease in effective magnetic moment. The Taketomi's theory fits well with the experimental data suggesting that the particle clusters are aligned in the direction of the magnetic field. The radius of cluster found to increase with increasing concentration, and then decreases whereas the elastic force constant increases and then becomes constant. The increase in cluster radius indicates elongation of aggregate length due to tip-to-tip interaction of aggregates whereas for higher concentration, the lateral alignment is more favorable than tip-to-tip alignment of aggregates which reduces the cluster radius making elastic force constant to raise. Optical images show that the chains are fluctuating and confirming the lateral alignment of chains at higher fields. - Highlights: • Magnetic field induced aggregates investigated using ultrasonic wave in aqueous magnetic fluid. • Velocity anisotropy induces upon applications of magnetic field. • Tarapov’s theory fit shows reduction in effective magnetic moment as concentration increases. • Taketomi's theory shows alignment of clusters in field direction. • Cluster radius increases and then decreases with increasing volume fractions. • Optical images show that fluctuating chains and lateral alignment of chains at higher fields.

  18. The effect of magnetic field induced aggregates on ultrasound propagation in aqueous magnetic fluid

    Energy Technology Data Exchange (ETDEWEB)

    Parekh, Kinnari, E-mail: [Dr. KC Patel R& D Center, Charotar University of Science & Technology, Changa, 388421 Dist. Anand, Gujarat (India); Upadhyay, R.V. [PD Patel Institute of Applied Sciences, Charotar University of Science & Technology, Changa, 388421 Dist. Anand, Gujarat (India)


    Ultrasonic wave propagation in the aqueous magnetic fluid is investigated for different particle concentrations. The sound velocity decreases while acoustic impedance increases with increasing concentrations. The velocity anisotropy is observed upon application of magnetic field. The velocity anisotropy fits with Tarapov’s theory suggests the presence of aggregates in the system. We report that these aggregates are thermodynamically unstable and the length of aggregate changes continuously with increasing concentration and, or magnetic field and resulted in a decrease in effective magnetic moment. The Taketomi's theory fits well with the experimental data suggesting that the particle clusters are aligned in the direction of the magnetic field. The radius of cluster found to increase with increasing concentration, and then decreases whereas the elastic force constant increases and then becomes constant. The increase in cluster radius indicates elongation of aggregate length due to tip-to-tip interaction of aggregates whereas for higher concentration, the lateral alignment is more favorable than tip-to-tip alignment of aggregates which reduces the cluster radius making elastic force constant to raise. Optical images show that the chains are fluctuating and confirming the lateral alignment of chains at higher fields. - Highlights: • Magnetic field induced aggregates investigated using ultrasonic wave in aqueous magnetic fluid. • Velocity anisotropy induces upon applications of magnetic field. • Tarapov’s theory fit shows reduction in effective magnetic moment as concentration increases. • Taketomi's theory shows alignment of clusters in field direction. • Cluster radius increases and then decreases with increasing volume fractions. • Optical images show that fluctuating chains and lateral alignment of chains at higher fields.

  19. Evaluation of the stability of linezolid in aqueous solution and commonly used intravenous fluids

    Directory of Open Access Journals (Sweden)

    Taylor R


    Full Text Available Rachel Taylor, Bruce Sunderland, Giuseppe Luna, Petra Czarniak School of Pharmacy, Faculty of Health Sciences, Curtin University, Bentley, WA, Australia Purpose: The aim was to evaluate the stability of linezolid in commonly used intravenous fluids and in aqueous solution to determine the kinetics of degradation and shelf-life values at alkaline pH values. Methods: Forced degradation studies were performed on linezolid in solution to develop a validated high-performance liquid chromatography analysis. Sodium chloride 0.9%, sodium lactate, and glucose 5% and glucose 10% solution containing 2.0 mg/mL linezolid were stored at 25.0°C (±0.1°C for 34 days. The effect of temperature on the stability of linezolid in 0.1 M sodium hydroxide solution was investigated to determine the activation energy. The degradation rates of linezolid at selected pH values at 70.0°C and the influence of ionic strength were also examined. Activation energy data were applied to determine the shelf-life values at selected pH values, and a pH rate profile was constructed over the pH range of 8.7–11.4. The stability of intravenous linezolid (Zyvox® solution was evaluated by storing at 70.0°C for 72 hours. Results: Linezolid was found to maintain >95.0% of its initial concentration after storage at 25.0°C for 34 days in sodium lactate, 0.9% in sodium chloride, and 5% and 10% in glucose solutions. Linezolid was degraded at alkaline pH values by first-order kinetics. Activation energy data showed that temperature, but not ionic strength, influenced the degradation rate significantly. An activation energy of 58.22 kJ/mol was determined for linezolid in 0.1 M sodium hydroxide solution. Linezolid was least stable at high pH values and at elevated temperatures. It was determined that linezolid has adequate stability for the preparation of intravenous fluids for clinical administration. Conclusion: Linezolid was found to have a shelf life of 34 days at 25°C when added to

  20. Trace elements in magnetite from massive iron oxide-apatite deposits indicate a combined formation by igneous and magmatic-hydrothermal processes (United States)

    Knipping, Jaayke L.; Bilenker, Laura D.; Simon, Adam C.; Reich, Martin; Barra, Fernando; Deditius, Artur P.; Wälle, Markus; Heinrich, Christoph A.; Holtz, François; Munizaga, Rodrigo


    Iron oxide-apatite (IOA) deposits are an important source of iron and other elements (e.g., REE, P, U, Ag and Co) vital to modern society. However, their formation, including the namesake Kiruna-type IOA deposit (Sweden), remains controversial. Working hypotheses include a purely magmatic origin involving separation of an Fe-, P-rich, volatile-rich oxide melt from a Si-rich silicate melt, and precipitation of magnetite from an aqueous ore fluid, which is either of magmatic-hydrothermal or non-magmatic surface or metamorphic origin. In this study, we focus on the geochemistry of magnetite from the Cretaceous Kiruna-type Los Colorados IOA deposit (∼350 Mt Fe) located in the northern Chilean Iron Belt. Los Colorados has experienced minimal hydrothermal alteration that commonly obscures primary features in IOA deposits. Laser ablation-inductively coupled plasma-mass spectroscopy (LA-ICP-MS) transects and electron probe micro-analyzer (EPMA) wavelength-dispersive X-ray (WDX) spectrometry mapping demonstrate distinct chemical zoning in magnetite grains, wherein cores are enriched in Ti, Al, Mn and Mg. The concentrations of these trace elements in magnetite cores are consistent with igneous magnetite crystallized from a silicate melt, whereas magnetite rims show a pronounced depletion in these elements, consistent with magnetite grown from an Fe-rich magmatic-hydrothermal aqueous fluid. Further, magnetite grains contain polycrystalline inclusions that re-homogenize at magmatic temperatures (>850 °C). Smaller inclusions (500 ppm) concentrations.

  1. Effects of solid/liquid phase fractionation on pH and aqueous species molality in subduction zone fluids (United States)

    Zhong, X.; Galvez, M. E.


    Metamorphic fluids are a crucial ingredient of geodynamic evolution, i.e. heat transfer, rock mechanics and metamorphic/metasomatic reactions. During crustal evolution at elevated P and T, rock forming components can be effectively fractionated from the reactive rock system by at least two processes: 1. extraction from porous rocks by liquid phases such as solute-bearing (e.g. Na+, Mg2+) aqueous fluids or partial melts. 2. isolation from effective bulk rock composition due to slow intragranular diffusion in high-P refractory phases such as garnet. The effect of phase fractionation (garnet, partial melt and aqueous species) on fluid - rock composition and properties remain unclear, mainly due to a high demand in quantitative computations of the thermodynamic interactions between rocks and fluids over a wide P-T range. To investigate this problem, we build our work on an approach initially introduced by Galvez et al., (2015) with new functionalities added in a MATLAB code (Rubisco). The fluxes of fractionated components in fluid, melt and garnet are monitored along a typical prograde P-T path for a model crustal pelite. Some preliminary results suggest a marginal effect of fractionated aqueous species on fluid and rock properties (e.g. pH, composition), but the corresponding fluxes are significant in the context of mantle wedge metasomatism. Our work provides insight into the role of high-P phase fractionation on mass redistribution between the surface and deep Earth in subduction zones. Existing limitations relevant to our liquid/mineral speciation/fractionation model will be discussed as well. ReferencesGalvez, M.E., Manning, C.E., Connolly, J.A.D., Rumble, D., 2015. The solubility of rocks in metamorphic fluids: A model for rock-dominated conditions to upper mantle pressure and temperature. Earth Planet. Sci. Lett. 430, 486-498.

  2. Redox Equilibria Involving Chromium Minerals in Aqueous Fluids in the Deep Earth - Implications for Diamond Formation (United States)

    Huang, J.; Huang, F.; Hao, J.; Sverjensky, D. A.


    Diamonds are often associated with inclusions of garnet that are characteristically Cr-rich and Ca-poor, suggesting metasomatic reactions involving fluids [1]. To investigate these reactions, we developed a thermodynamic characterization of Cr-bearing minerals and integrated it with our database for the thermodynamic properties of aqueous Cr-species [2]. We retrieved thermodynamic properties of picrochromite (MgCr2O4), and knorringite (Mg3Cr2Si3O12) consistent with minerals in the Berman (1988) using calorimetric data and experimental phase equilibria involving the reactions: MgCr2O4 + SiO2 = Cr2O3 + MgSiO3 [2] and MgCr2O4 + 4MgSiO3 = Mg3Cr2Si3O12 + Mg2SiO4 [3], respectively.At high temperatures and pressures, neutral pH and FMQ, the predicted solubilities of eskolaite and knorringite equilibrium with Cr2+ in a pure water system are very low. However, we found that complexes of Cr2+ and Cl- could increase the solubilities of chromium minerals significantly. At 500°C and 0.2 - 1.0 GPa, we retrieved the CrCl(OH)0 neutral complex from experiments on the solubility of Cr2O3 in HCl solutions [4]. At 1,000°C and 4.0 GPa, we retrieved the properties of a CrCl3- complex from experiments on the solubility of Cr2O3 in KCl solutions [5]. The predicted solubility of a garnet containing 23 mole% of knorringite in equilibrium with CrCl3- in a peridotitic diamond-forming fluid is 22 millimolal (1,144 ppm). This result suggests that a redox reaction relating to diamond formation might involveMg3Al2Si3O12 + 0.5CO2(aq) + 2 CrCl3- + 2H+ = Mg3Cr2Si3O12 + 0.5C-Diamond + 2Al3+ + 6Cl-. In this way, high temperature and pressure fluids containing Cr(II)-complexes might promote the mobility of chromium and be involved in metasomatic reactions and diamond formation.[1]Boyd et al. (1993)[2] Hao et al. (submitted to Geochem. Persp. Letters)[3] Berman (1988)[4] Klemme et al. (2000)[5] Klemme et al. (2004)[6] Watenphul et al. (2014)[7] Klein-BenDavid et al. (2011)

  3. Fluid dynamics simulation of aqueous humour in a posterior-chamber phakic intraocular lens with a central perforation. (United States)

    Kawamorita, Takushi; Uozato, Hiroshi; Shimizu, Kimiya


    A modified implantable collamer lens (ICL) with a central hole (diameter, 0.36 mm), a "Hole-ICL", was created to improve aqueous humour circulation. The aim of this study was to investigate the fluid dynamic characteristics of aqueous humour in a Hole-ICL using computational fluid dynamics. Fluid dynamics simulation using an ICL was performed with thermal-hydraulic analysis software FloEFD V5 (Mentor Graphics Corp.). For the simulation, three-dimensional eye models based on a modified Liou-Brennan model eye with conventional ICL (Model ICM, STAAR SURGICAL) and a Hole-ICL were used. Both ICLs were -9.0 diopters (D) and 12.0 mm in length, with an optic of 5.5 mm. The vaulting was 0.50 mm. The quantity of aqueous humour produced by the ciliary body was set at 2.80 μl/min. Flow distribution between the anterior surface of the crystalline lens and the posterior surface of the ICL was also calculated, and trajectory analysis was performed. The flow velocity 0.25 mm in front of the centre of the crystalline lens was 1.52 × 10(-1) mm/sec for the Hole-ICL and 1.21 × 10(-5) mm/sec for the conventional ICL. Outward flow from the hole in the Hole-ICL was confirmed by trajectory analysis. These results suggest that Hole-ICLs improve the circulation of aqueous humour to the anterior surface of the crystalline lens.

  4. Partitioning of Trace Elements Between Hydrous Minerals and Aqueous Fluids : a Contribution to the Chemical Budget of Subduction Zones (United States)

    Daniel, I.; Koga, K. T.; Reynard, B.; Petitgirard, S.; Chollet, M.; Simionovici, A.


    Subduction zones are powerful chemical engines where the downgoing lithosphere reacts with asthenospheric mantle and produces magmas. Understanding this deep recycling system is a scientific challenge requiring multiple approaches. Among those, it appears that we lack basic information on the composition of the fluid that begins the process of material transfer in subduction zones. Indeed, no pristine fluid sample has yet been collected from this particular environment. Albeit challenging, the alternative would be experimental study of fluids under the appropriate conditions. Consequently, we developed an experimental protocol to measure the concentration of aqueous fluids equilibrated with minerals up to pressures (P) of 5 GPa, at least and temperatures (T) of 550 C. This includes syntheses at high-P and -T conditions, and determination of the fluid composition. Syntheses were performed in a large volume belt-type press at the conditions, 2-5 GPa and ca. 550 C. Oxides or minerals were loaded with water in a gold capsule sealed afterwards. Presence of free fluid during experiments could be confirmed by direct observation of fluid release from the sealed capsule upon puncturing. The composition in trace elements of the fluids that were equilibrated at high-P and -T with minerals was reconstructed from that of the precipitates deposited at the surface of minerals after evaporation of the capsule. The precipitates were dissolved and analyzed by a leaching technique detailed in Koga et al. (2005). Two hydrous minerals of prime interest for subductions were sofar investigated: the high-pressure variety of serpentine, antigorite, and talc. The partitioning coefficients of a series of trace-elements will be presented, as well as their evolution as a function of pressure. Consequences for the composition of the fluids released during the dehydration of hydrous metamorphic minerals will be drawn. Those measurements are unlikely to be feasible at pressures in excess of 5 GPa

  5. Association between aqueous humor and vitreous fluid levels of Th17 cell-related cytokines in patients with proliferative diabetic retinopathy. (United States)

    Takeuchi, Masaru; Sato, Tomohito; Sakurai, Yutaka; Taguchi, Manzo; Harimoto, Kozo; Karasawa, Yoko; Ito, Masataka


    Inflammation is known to be involved in the progression of diabetic retinopathy. We have recently reported that vitreous levels of IL-4, IL-17A, IL-22, IL-31, and TNFα are higher than the respective serum levels in proliferative diabetic retinopathy (PDR) patients, and that vitreous levels of these cytokines are higher in PDR than in other non-inflammatory vitreoretinal diseases or uveitis associated with sarcoidosis. In the present study, we investigated inflammatory cytokines including Th17 cell-related cytokines in aqueous humor samples obtained from eyes with PDR, and analyzed the association between the aqueous humor and vitreous fluid levels of individual cytokines. The study group consisted of 31 consecutive type 2 diabetic patients with PDR who underwent cataract surgery and vitrectomy for vitreous hemorrhage and/or tractional retinal detachment. Undiluted aqueous humor was collected during cataract surgery, and then vitreous fluid was obtained using a 25G vitreous cutter inserted into the mid-vitreous cavity at the beginning of vitrectomy. IL-1β, IL-4, IL-6, IL-10, IL-17A, IL-17F, IL-21, IL-22, IL-23, IL-25, IL-31, IL-33, IFN-γ, soluble CD40 ligand (sCD40L), and TNFα levels in the aqueous humor and vitreous fluid were measured using a beads-array system. Although IL-17A was detected in the aqueous humor of eyes with PDR and the level correlated with IL-17A level in the vitreous fluid, both percent detectable and level of IL-17A in the aqueous humor were significantly lower than those in the vitreous fluid. Vitreous IL-17A level was related significantly to IL-10, IL-22, and TNFα levels in aqueous humor as well as in vitreous fluid, On the other hand, aqueous IL-17A level was not related significantly to aqueous or vitreous levels of IL-10, IL-22 or TNFα level. The present study demonstrated that IL-17A level and detectable rate in the aqueous humor of patients with PDR are markedly lower than those in the vitreous fluid and aqueous IL-17A does not

  6. Flow of Aqueous Humor (United States)

    ... Home Flow of Aqueous Humor Flow of Aqueous Humor Most, but not all, forms of glaucoma are ... remains normal when some of the fluid (aqueous humor) produced by the eye's ciliary body flows out ...

  7. Trace element partitioning between aqueous fluids and silicate melts measured with a proton microprobe

    Energy Technology Data Exchange (ETDEWEB)

    Adam, J.; Green, T.H. [Macquarie Univ., North Ryde, NSW (Australia). School of Earth Sciences; Sie, S.H. [Commonwealth Scientific and Industrial Research Organisation (CSIRO), North Ryde, NSW (Australia). Div. of Exploration Geoscience


    A series of experiments were performed to examine the capacity of H{sub 2}O-fluids to concentrate and transport incompatible elements through peridotitic mantle and metamorphosed (eclogitic) ocean crust. Two naturally occurring rock compositions, trondhjemitic and basanitic, were used in experiments. The proton microprobe was used to determine the trace element concentrations in the solutes from H{sub 2}O-fluids equilibrated at 900-1100 degree C, 2.0 GPa with water saturated melts of trondhjemitic and basanitic compositions. Partitioning data for H{sub 2}O-fluids and silicate melts show that H{sub 2}O-fluids equilibrated with mantle peridotites will not be strongly enriched in trace elements relative to their wallrocks, and thus they melts do not strongly concentrate alkaline earths Th and U, relative to high-field strength elements. 3 refs., 1 tab., 2 figs.

  8. Trace element partitioning between aqueous fluids and silicate melts measured with a proton microprobe

    Energy Technology Data Exchange (ETDEWEB)

    Adam, J; Green, T H [Macquarie Univ., North Ryde, NSW (Australia). School of Earth Sciences; Sie, S H [Commonwealth Scientific and Industrial Research Organisation (CSIRO), North Ryde, NSW (Australia). Div. of Exploration Geoscience


    A series of experiments were performed to examine the capacity of H{sub 2}O-fluids to concentrate and transport incompatible elements through peridotitic mantle and metamorphosed (eclogitic) ocean crust. Two naturally occurring rock compositions, trondhjemitic and basanitic, were used in experiments. The proton microprobe was used to determine the trace element concentrations in the solutes from H{sub 2}O-fluids equilibrated at 900-1100 degree C, 2.0 GPa with water saturated melts of trondhjemitic and basanitic compositions. Partitioning data for H{sub 2}O-fluids and silicate melts show that H{sub 2}O-fluids equilibrated with mantle peridotites will not be strongly enriched in trace elements relative to their wallrocks, and thus they melts do not strongly concentrate alkaline earths Th and U, relative to high-field strength elements. 3 refs., 1 tab., 2 figs.

  9. Numerical model of heat transfer in the human eye with consideration of fluid dynamics of the aqueous humour

    Energy Technology Data Exchange (ETDEWEB)

    Karampatzakis, Andreas; Samaras, Theodoros, E-mail: theosama@auth.g [Department of Physics, Aristotle University of Thessaloniki, GR-54124 Thessaloniki (Greece)


    In this work we present a new 3D numerical model for heat transfer in the human eye, which takes into account the aqueous humour flow in the anterior chamber. We show that consideration of this phenomenon in the calculations alters the temperature distribution on the corneal and lens surfaces, without, however, noticeably changing their absolute values. The most notable effect is that the coolest area of the cornea moves at a point of 2 mm inferior to its geometric centre. The maximum velocity of the fluid in the anterior chamber was found to be 3.36 x 10{sup -4} m s{sup -1}. The effect of the flow on displacing the cool area of the corneal surface temperature is counterbalanced by assuming anisotropic thermal conductivity. The model was implemented in the case of an artificial intraocular lens to show the resulting temperature variations.

  10. Numerical model of heat transfer in the human eye with consideration of fluid dynamics of the aqueous humour. (United States)

    Karampatzakis, Andreas; Samaras, Theodoros


    In this work we present a new 3D numerical model for heat transfer in the human eye, which takes into account the aqueous humour flow in the anterior chamber. We show that consideration of this phenomenon in the calculations alters the temperature distribution on the corneal and lens surfaces, without, however, noticeably changing their absolute values. The most notable effect is that the coolest area of the cornea moves at a point of 2 mm inferior to its geometric centre. The maximum velocity of the fluid in the anterior chamber was found to be 3.36 × 10(-4) m s(-1). The effect of the flow on displacing the cool area of the corneal surface temperature is counterbalanced by assuming anisotropic thermal conductivity. The model was implemented in the case of an artificial intraocular lens to show the resulting temperature variations.

  11. Numerical model of heat transfer in the human eye with consideration of fluid dynamics of the aqueous humour

    International Nuclear Information System (INIS)

    Karampatzakis, Andreas; Samaras, Theodoros


    In this work we present a new 3D numerical model for heat transfer in the human eye, which takes into account the aqueous humour flow in the anterior chamber. We show that consideration of this phenomenon in the calculations alters the temperature distribution on the corneal and lens surfaces, without, however, noticeably changing their absolute values. The most notable effect is that the coolest area of the cornea moves at a point of 2 mm inferior to its geometric centre. The maximum velocity of the fluid in the anterior chamber was found to be 3.36 x 10 -4 m s -1 . The effect of the flow on displacing the cool area of the corneal surface temperature is counterbalanced by assuming anisotropic thermal conductivity. The model was implemented in the case of an artificial intraocular lens to show the resulting temperature variations.

  12. Modeling of aqueous electrolyte solutions with perturbed-chain statistical associated fluid theory

    DEFF Research Database (Denmark)

    Cameretti, Luca F.; Sadowski, Gabriele; Mollerup, Jørgen


    The vapor pressures and liquid densities of single-salt electrolyte solutions containing NaCl, LiCl, KCl, NaBr, LiBr, KBr, NaI, LiI, KI, Li2SO4, Na2SO4, and K2SO4 were modeled with an equation of state based on perturbed-chain statistical associated fluid theory (PC-SAFT). The PC-SAFT model...

  13. Gold nanomaterials for the selective capturing and SERS diagnosis of toxins in aqueous and biological fluids

    DEFF Research Database (Denmark)

    Hassanain, Waleed A.; Izake, Emad L.; Schmidt, Michael Stenbæk


    the extractor nanoparticles within 5min by manipulating the pH environment of the nanoparticles. The regenerated extractor nanoparticles maintained their capture efficiency and, therefore, were re-used to capture of MC-LR from successive samples. The released purified toxin was screened within 10min on gold......A highly sensitive nanosensing method for the combined selective capture and SERS detection of Microcystin-LR (MC-LR) in blood plasma has been developed. The new method utilizes gold coated magnetic nanoparticles that are functionalized with anti MC-LR antibody Fab' fragments for the selective...... capture of MC-LR from aqueous media and blood plasma. Using an oriented immobilization approach, the Fab' fragments are covalently attached to gold surface to form a monolayer with high capture efficiency towards the toxin. After the selective capture, the purified MC-LR molecules were released from...

  14. Fluid sample collection and distribution system. [qualitative analysis of aqueous samples from several points (United States)

    Brooks, R. L. (Inventor)


    A multipoint fluid sample collection and distribution system is provided wherein the sample inputs are made through one or more of a number of sampling valves to a progressive cavity pump which is not susceptible to damage by large unfiltered particles. The pump output is through a filter unit that can provide a filtered multipoint sample. An unfiltered multipoint sample is also provided. An effluent sample can be taken and applied to a second progressive cavity pump for pumping to a filter unit that can provide one or more filtered effluent samples. The second pump can also provide an unfiltered effluent sample. Means are provided to periodically back flush each filter unit without shutting off the whole system.

  15. Aqueous geochemistry in icy world interiors: Equilibrium fluid, rock, and gas compositions, and fate of antifreezes and radionuclides (United States)

    Neveu, Marc; Desch, Steven J.; Castillo-Rogez, Julie C.


    The geophysical evolution of many icy moons and dwarf planets seems to have provided opportunities for interaction between liquid water and rock (silicate and organic solids). Here, we explore two ways by which water-rock interaction can feed back on geophysical evolution: the production or consumption of antifreeze compounds, which affect the persistence and abundance of cold liquid; and the potential leaching into the fluid of lithophile radionuclides, affecting the distribution of a long-term heat source. We compile, validate, and use a numerical model, implemented with the PHREEQC code, of the interaction of chondritic rock with pure water and with C, N, S-bearing cometary fluid, thought to be the materials initially accreted by icy worlds, and describe the resulting equilibrium fluid and rock assemblages at temperatures, pressures, and water-to-rock ratios of 0-200 ° C, 1-1000 bar, and 0.1-10 by mass, respectively. Our findings suggest that water-rock interaction can strongly alter the nature and amount of antifreezes, resulting in solutions rich in reduced nitrogen and carbon, and sometimes dissolved H2, with additional sodium, calcium, chlorine, and/or oxidized carbon. Such fluids can remain partially liquid down to 176 K if NH3 is present. The prominence of Cl in solution seems to hinge on its primordial supply in ices, which is unconstrained by the meteoritical record. Equilibrium assemblages, rich in serpentine and saponite clays, retain thorium and uranium radionuclides unless U-Cl or U-HCO3 complexing, which was not modeled, significantly enhances U solubility. However, the radionuclide 40 K can be leached at high water:rock ratio and/or low temperature at which K is exchanged with ammonium in minerals. We recommend the inclusion of these effects in future models of the geophysical evolution of ocean-bearing icy worlds. Our simulation products match observations of chloride salts on Europa and Enceladus; CI chondrites mineralogies; the observation of

  16. Stability studies of lincomycin hydrochloride in aqueous solution and intravenous infusion fluids

    Directory of Open Access Journals (Sweden)

    Czarniak P


    Full Text Available Petra Czarniak, Michael Boddy, Bruce Sunderland, Jeff D Hughes School of Pharmacy, Curtin University, Perth, WA, Australia Purpose: The purpose of this study was to evaluate the chemical stability of Lincocin® (lincomycin hydrochloride in commonly used intravenous fluids at room temperature (25°C, at accelerated-degradation temperatures and in selected buffer solutions.Materials and methods: The stability of Lincocin® injection (containing lincomycin 600 mg/2 mL as the hydrochloride stored at 25°C±0.1°C in sodium lactate (Hartmann’s, 0.9% sodium chloride, 5% glucose, and 10% glucose solutions was investigated over 31 days. Forced degradation of Lincocin® in hydrochloric acid, sodium hydroxide, and hydrogen peroxide was performed at 60°C. The effect of pH on the degradation rate of lincomycin hydrochloride stored at 80°C was determined.Results: Lincomycin hydrochloride was found to maintain its shelf life at 25°C in sodium lactate (Hartmann’s solution, 0.9% sodium chloride solution, 5% glucose solution, and 10% glucose solution, with less than 5% lincomycin degradation occurring in all intravenous solutions over a 31-day period. Lincomycin hydrochloride showed less rapid degradation at 60°C in acid than in basic solution, but degraded rapidly in hydrogen peroxide. At all pH values tested, lincomycin followed first-order kinetics. It had the greatest stability near pH 4 when stored at 80°C (calculated shelf life of 4.59 days, and was least stable at pH 2 (calculated shelf life of 0.38 days.Conclusion: Lincocin® injection was chemically found to have a shelf life of at least 31 days at 25°C when added to sodium lactate (Hartmann’s solution, 0.9% sodium chloride solution, 5% glucose solution, and 10% glucose solution. Solutions prepared at approximately pH 4 are likely to have optimum stability. Keywords: lincomycin, stability, pH, intravenous fluids, IV additives

  17. Phytochemical Characterization and Biological Evaluation of the Aqueous and Supercritical Fluid Extracts from Salvia sclareoides Brot

    Directory of Open Access Journals (Sweden)

    Batista Daniela


    Full Text Available Plants belonging to the genus Salvia (Lamiaceae are known to have a wide range of biological properties. In this work, extracts obtained from the aerial parts of Salvia sclareoides Brot. were evaluated to investigate their chemical composition, toxicity, bioactivity, and stability under in vitro gastrointestinal conditions. The composition of the supercritical fluid extract was determined by GC and GC-MS, while the identification of the infusion constituents was performed by HPLC-DAD and LC-MS. The in vitro cytotoxicity of both extracts (0-2 mg/mL was evaluated in Caco-2 cell lines by the MTT assay. The anti-inflammatory and anticholinesterase activities were determined through the inhibition of cyclooxygenase-1 and acetylcholinesterase enzymes, while β-carotene/linoleic acid bleaching test and the DPPH assays were used to evaluate the antioxidant activity. The infusion inhibited cyclooxygenase-1 (IC50 = 271.0 μg/mL, and acetylcholinesterase (IC50 = 487.7 μg/ mL enzymes, also demonstrated significant antioxidant properties, as evaluated by the DPPH (IC50 = 10.4 μg/mL and β-carotene/linoleic acid (IC50 = 30.0 μg/mL assays. No remarkable alterations in the composition or in the bioactivities of the infusion were observed after in vitro digestion, which supports the potential of S. sclareoides as a source of bioactive ingredients with neuroprotective, anti-inflammatory and antioxidant properties.

  18. Modulation of magmatic processes by carbon dioxide (United States)

    Caricchi, L.; Sheldrake, T. E.; Blundy, J. D.


    Volatile solubility in magmas increases with pressure, although the solubility of CO2 is much lower than that of H2O. Consequently, magmas rising from depth release CO2-rich fluids, which inevitably interact with H2O-poor magmas in the upper crust (CO2-flushing). CO2-flushing triggers the exsolution of H2O-rich fluids, leading to an increase of volume and magma crystallisation. While the analyses of eruptive products demonstrates that this process operates in virtually all magmatic system, its impact on magmatic and volcanic processes has not been quantified. Here we show that depending on the initial magma crystallinity, and the depth of magma storage, CO2-flushing can lead to volcanic eruptions or promote conditions that favour the impulsive release of mineralising fluids. Our calculations show that the interaction between a few hundred ppm of carbonic fluids, and crystal-poor magmas stored at shallow depths, produces rapid pressurisation that can potentially lead to an eruption. Further addition of CO2 increases magma compressibility and crystallinity, reducing the potential for volcanic activity, promoting the formation of ore deposits. Increasing the depth of fluid-magma interaction dampens the impact of CO2-flushing on the pressurisation of a magma reservoir. CO2-flushing may result in surface inflation and increases in surface CO2 fluxes, which are commonly considered signs of an impending eruption, but may not necessarily result in eruption depending on the initial crystallnity and depth of the magmatic reservoir. We propose that CO2-flushing is a powerful agent modulating the pressurisation of magma reservoirs and the release of mineralising fluids from upper crustal magma reservoirs.

  19. Stability studies of lincomycin hydrochloride in aqueous solution and intravenous infusion fluids. (United States)

    Czarniak, Petra; Boddy, Michael; Sunderland, Bruce; Hughes, Jeff D


    The purpose of this study was to evaluate the chemical stability of Lincocin(®) (lincomycin hydrochloride) in commonly used intravenous fluids at room temperature (25°C), at accelerated-degradation temperatures and in selected buffer solutions. The stability of Lincocin(®) injection (containing lincomycin 600 mg/2 mL as the hydrochloride) stored at 25°C±0.1°C in sodium lactate (Hartmann's), 0.9% sodium chloride, 5% glucose, and 10% glucose solutions was investigated over 31 days. Forced degradation of Lincocin(®) in hydrochloric acid, sodium hydroxide, and hydrogen peroxide was performed at 60°C. The effect of pH on the degradation rate of lincomycin hydrochloride stored at 80°C was determined. Lincomycin hydrochloride w as found to maintain its shelf life at 25°C in sodium lactate (Hartmann's) solution, 0.9% sodium chloride solution, 5% glucose solution, and 10% glucose solution, with less than 5% lincomycin degradation occurring in all intravenous solutions over a 31-day period. Lincomycin hydrochloride showed less rapid degradation at 60°C in acid than in basic solution, but degraded rapidly in hydrogen peroxide. At all pH values tested, lincomycin followed first-order kinetics. It had the greatest stability near pH 4 when stored at 80°C (calculated shelf life of 4.59 days), and was least stable at pH 2 (calculated shelf life of 0.38 days). Lincocin(®) injection was chemically found to have a shelf life of at least 31 days at 25°C when added to sodium lactate (Hartmann's) solution, 0.9% sodium chloride solution, 5% glucose solution, and 10% glucose solution. Solutions prepared at approximately pH 4 are likely to have optimum stability.

  20. Photochemical coupling of 5-bromouracil to tryptophan, tyrosine and histidine, peptide-like derivatives in aqueous fluid solution

    International Nuclear Information System (INIS)

    Dietz, T.M.; Koch, T.H.


    Direct irradiation of 5-bromouracil (BU) in aqueous fluid solution in the presence of tryptophan (trp), tyrosine (tyr) or histidine (his) derivatives using a XeCl excimer laser at 308 nm yielded photocoupling of BU to the aromatic ring of each amino acid. Irradiation of BU at 308 nm most likely results in excitation of the n-π* transition, intersystem crossing to the triplet manifold, and coupling via electron transfer from the aromatic amino acid. The coupling observed was regiospecific between the 5-position of uracil (U) and the 2-position of the indole and phenol rings and the 5-position of the imidazole ring of the respective amino acids. Quantum yields of photocoupling to BU ranged from 1 x 10 -3 to 7 x 10 -3 and paralleled known rates of electron transfer and ionization potentials of the aromatic rings. The photocoupling between BU and some of the aromatic amino acid peptide-like derivatives possibly mimics photocrosslinking of BU-DNA to associated proteins, a potentially useful photoreaction for studying nucleic acid-protein interactions. Formation of crosslinks of the type proposed here might be detected by the characteristic fluorescence emission of the uracil amino acid adducts. (author)

  1. In-situ, high pressure and temperature experimental determination of hydrogen isotope fractionation between coexisting hydrous melt and silicate-saturated aqueous fluid (United States)

    Mysen, B. O.


    Hydrogen isotope fractionation between water-saturated silicate melt and silicate-saturated aqueous fluid has been determined experimentally, in-situ with the samples in the 450-800C and 101-1567 MPa temperature and pressure range, respectively. The temperatures are, therefore higher than those where hydrogen bonding in fluids and melts is important [1]. The experiments were conducted with a hydrothermal diamond anvil cell (HDAC) as the high-temperature/-pressure tool and vibrational spectroscopy to determine D/H fractionation. Compositions were along the haploandesite join, Na2Si4O9 - Na2(NaAl)4O9 [Al/(Al+Si)=0-0.1], and a 50:50 (by volume) H2O:D2O fluid mixture as starting material. Platinum metal was used to enhance equilibration rate. Isotopic equilibrium was ascertained by using variable experimental duration at given temperature and pressure. In the Al-free Na-silicate system, the enthalpy change of the (D/H) equilibrium of fluid is 3.1±0.7 kJ/mol, whereas for coexisting melt, ΔH=0 kJ/mol within error. With Al/(Al+Si)=0.1, ΔH=5.2±0.9 kJ/mol for fluid and near 0 within error for coexisting melt melt. For the exchange equilibrium between melt and fluid, H2O(melt)+D2O(fluid)=H2O(fluid)+D2O(melt), the ΔH=4.6±0.7 and 6.5±0.7 kJ/mol for the two Al-free and Al-bearing compositions, respectively, respectively. The D/H equilibration within fluids and melts and, therefore, D/H partitioning between coexisting fluid and melt reflect the influence of dissolved H2O(D2O) in melts and dissolved silicate components in H2O(D2O) fluid on their structure. The positive temperature- and pressure-dependence of silicate solubility and on silicate structure in silicate-saturated aqueous fluid governs the D/H fractionation in the fluid because increasing silicate solute concentration in fluid results in silicate polymerization [2]. These structural effects may be analogous to observed solute-dependent oxygen isotope fractionation between brine and CO2 [3]. In the temperature

  2. Modulation of magmatic processes by CO2 flushing (United States)

    Caricchi, Luca; Sheldrake, Tom E.; Blundy, Jon


    Magmatic systems are the engines driving volcanic eruptions and the source of fluids responsible for the formation of porphyry-type ore deposits. Sudden variations of pressure, temperature and volume in magmatic systems can produce unrest, which may culminate in a volcanic eruption and/or the abrupt release of ore-forming fluids. Such variations of the conditions within magmatic systems are commonly ascribed to the injection of new magma from depth. However, as magmas fractionating at depth or rising to the upper crust release CO2-rich fluids, the interaction between carbonic fluids and H2O-rich magmas stored in the upper crust (CO2 flushing), must also be a common process affecting the evolution of subvolcanic magma reservoirs. Here, we investigate the effect of gas injection on the stability and chemical evolution of magmatic systems. We calculate the chemical and physical evolution of magmas subjected to CO2-flushing using rhyolite-MELTS. We compare the calculations with a set of melt inclusion data for Mt. St. Helens, Merapi, Etna, and Stromboli volcanoes. We provide an approach that can be used to distinguish between melt inclusions trapped during CO2 flushing, magma ascent and decompression, or those affected by post-entrapment H2O-loss. Our results show that CO2 flushing is a widespread process in both felsic and mafic magmatic systems. Depending upon initial magma crystallinity and duration of CO2 input, flushing can either lead to volcanic eruption or fluid release. We suggest that CO2 flushing is a fundamental process modulating the behaviour and chemical evolution of crustal magmatic systems.

  3. Speciation in Aqueous MgSO4 Fluid at High Pressures and Temperatures Studied by First-Principles Modeling and Raman Spectroscopy (United States)

    Jahn, S.; Schmidt, C.


    Aqueous fluids play an essential role in mass and energy transfer in the lithosphere. Their presence has also a large effect on physical properties of rocks, e.g. the electrical conductivity. Many chemical and physical properties of aqueous fluids strongly depend on the speciation, but very little is known about this fundamental parameter at high pressures and temperatures, e.g. at subduction zone conditions. Here we use a combined approach of first-principles molecular dynamics simulation and Raman spectroscopy to study the molecular structure of aqueous 2~mol/kg MgSO4 fluids up to pressures of 3~GPa and temperatures of 750~°C. MgSO4-H2O is selected as a model system for sulfate bearing subduction zone fluids. The simulations are performed using Car-Parrinello dynamics, a system size of 120 water and four MgSO4 molecules with production runs of at least 10~ps at each P and T. Raman spectra were obtained in situ using a Bassett-type hydrothermal diamond anvil cell with external heating. Both simulation and spectroscopic data show a dynamic co-existence of various associated molecular species as well as dissociated Mg2+ and SO42- in the single phase fluid. Fitting the Raman signal in the frequency range of the ν1-SO42- stretching mode yields the P-T dependence of the relative proportions of different peaks. The latter can be assigned to species based on literature data and related to the species found in the simulation. The dominant associated species found in the P-T range of interest here are Mg-SO4 ion pairs with one (monodentate) and two (bidentate) binding sites. At the highest P and T, an additional peak is identified. At low pressures and high temperature (T>230~°C), kieserite, MgSO4·H2O, nucleated in the experiment. At the same conditions the simulations show a clustering of Mg, which is interpreted as a precursor of precipitation. In conclusion, the speciation of aqueous MgSO4 fluid shows a complex behavior at high P and T that cannot be extrapolated

  4. Tibetan Magmatism Database (United States)

    Chapman, James B.; Kapp, Paul


    A database containing previously published geochronologic, geochemical, and isotopic data on Mesozoic to Quaternary igneous rocks in the Himalayan-Tibetan orogenic system are presented. The database is intended to serve as a repository for new and existing igneous rock data and is publicly accessible through a web-based platform that includes an interactive map and data table interface with search, filtering, and download options. To illustrate the utility of the database, the age, location, and ɛHft composition of magmatism from the central Gangdese batholith in the southern Lhasa terrane are compared. The data identify three high-flux events, which peak at 93, 50, and 15 Ma. They are characterized by inboard arc migration and a temporal and spatial shift to more evolved isotopic compositions.

  5. Felsic magmatism and uranium deposits

    International Nuclear Information System (INIS)

    Cuney, Michel


    The strongly incompatible behaviour of uranium in silicate magmas results in its concentration in the most felsic melts and a prevalence of granites and rhyolites as primary U sources for the formation of U deposits. Despite its incompatible behavior, U deposits resulting directly from magmatic processes are quite rare. In most deposits, U is mobilized by hydrothermal fluids or ground water well after the emplacement of the igneous rocks. Of the broad range of granite types, only a few have U contents and physico-chemical properties that permit the crystallization of accessory minerals from which uranium can be leached for the formation of U deposits. The first granites on Earth, which crystallized uraninite, dated at 3.1 Ga, are the potassic granites from the Kaapval craton (South Africa) which were also the source of the detrital uraninite for the Dominion Reef and Witwatersrand quartz pebble conglomerate deposits. Four types of granites or rhyolites can be sufficiently enriched in U to represent a significant source for the genesis of U deposits: per-alkaline, high-K met-aluminous calc-alkaline, L-type peraluminous and anatectic pegmatoids. L-type peraluminous plutonic rocks in which U is dominantly hosted in uraninite or in the glass of their volcanic equivalents represent the best U source. Per-alkaline granites or syenites are associated with the only magmatic U-deposits formed by extreme fractional crystallization. The refractory character of the U-bearing minerals does not permit their extraction under the present economic conditions and make them unfavorable U sources for other deposit types. By contrast, felsic per-alkaline volcanic rocks, in which U is dominantly hosted in the glassy matrix, represent an excellent source for many deposit types. High-K calc-alkaline plutonic rocks only represent a significant U source when the U-bearing accessory minerals (U-thorite, allanite, Nb oxides) become metamict. The volcanic rocks of the same geochemistry may be

  6. Felsic magmatism and uranium deposits

    International Nuclear Information System (INIS)

    Cuney, M.


    Uranium strongly incompatible behaviour in silicate magmas results in its concentration in the most felsic melts and a prevalence of granites and rhyolites as primary U sources for the formation of U deposits. Despite its incompatible behaviour, U deposits resulting directly from magmatic processes are quite rare. In most deposits, U is mobilized by hydrothermal fluids or ground water well after the emplacement of the igneous rocks. Of the broad range of granite types, only a few have have U contents and physico-chemical properties that permit the crystallization of accessory minerals from which uranium can be leached for the formation of U deposits. The first granites on Earth which crystallized uraninite appeared at 3.1 Ga, are the potassic granites from the Kaapval craton (South Africa) which were also the source of the detrital uraninite for the Dominion Reef and Witwatersrand quartz pebble conglomerate deposits. Four types of granites or rhyolites can be sufficiently enriched in U to represent a significant source for the genesis of U deposits: peralkaline, high-K metaluminous calc-alkaline, L-type peraluminous ones and anatectic pegmatoids. L-type peraluminous plutonic rocks in which U is dominantly hosted in uraninite or in the glass in their volcanic equivalents represent the best U source. Peralkaline granites or syenites represent the only magmatic U-deposits formed by extreme fractional crystallization. The refractory character of the U-bearing minerals does not permit their extraction at the present economic conditions and make them unfavourable U sources for other deposit types. By contrast, felsic peralkaline volcanic rocks, in which U is dominantly hosted in the glassy matrix, represent an excellent source for many deposit types. High-K calc-alkaline plutonic rocks only represent a significant U source when the U-bearing accessory minerals [U-thorite, allanite, Nb oxides] become metamict. The volcanic rocks of the same geochemistry may be also a

  7. Effect of Porous Media and Fluid Properties on Dense Non-Aqueous Phase Liquid Migration and Dilution Mass Flux

    National Research Council Canada - National Science Library

    Totten, Christian T


    .... Media grain size and NAPL wettability were varied for relative comparisons. Fluid properties including density differential and interfacial tension between NAPL and water were varied for relative comparisons...

  8. Modeling seismic stimulation: Enhanced non-aqueous fluid extraction from saturated porous media under pore-pressure pulsing at low frequencies (United States)

    Lo, Wei-Cheng; Sposito, Garrison; Huang, Yu-Han


    Seismic stimulation, the application of low-frequency stress-pulsing to the boundary of a porous medium containing water and a non-aqueous fluid to enhance the removal of the latter, shows great promise for both contaminated groundwater remediation and enhanced oil recovery, but theory to elucidate the underlying mechanisms lag significantly behind the progress achieved in experimental research. We address this conceptual lacuna by formulating a boundary-value problem to describe pore-pressure pulsing at seismic frequencies that is based on the continuum theory of poroelasticity for an elastic porous medium permeated by two immiscible fluids. An exact analytical solution is presented that is applied numerically using elasticity parameters and hydraulic data relevant to recent proof-of-principle laboratory experiments investigating the stimulation-induced mobilization of trichloroethene (TCE) in water flowing through a compressed sand core. The numerical results indicated that significant stimulation-induced increases of the TCE concentration in effluent can be expected from pore-pressure pulsing in the frequency range of 25-100 Hz, which is in good agreement with what was observed in the laboratory experiments. Sensitivity analysis of our numerical results revealed that the TCE concentration in the effluent increases with the porous medium framework compressibility and the pulsing pressure. Increasing compressibility also leads to an optimal stimulation response at lower frequencies, whereas changing the pulsing pressure does not affect the optimal stimulation frequency. Within the context of our model, the dominant physical cause for enhancement of non-aqueous fluid mobility by seismic stimulation is the dilatory motion of the porous medium in which the solid and fluid phases undergo opposite displacements, resulting in stress-induced changes of the pore volume.

  9. Quantitation and identification of organic N-chloramines formed in stomach fluid on ingestion of aqueous hypochlorite

    Energy Technology Data Exchange (ETDEWEB)

    Scully, F.E. Jr.; Mazina, K.; Sonenshine, D.; Kopfler, F.


    The chemical reactions that hypochlorite undergoes in the body when chlorinated water is ingested have received very little attention. Because amino nitrogen compounds are important components of the average diet, the reactions of hypochlorite with amino compounds in the stomach were investigated. Stomach fluid was recovered from Sprague-Dawley rats that had been fasted for 48 hr and administered 4 mL deionized water. The chlorine demand of the stomach fluid was determined. At least part of the chlorine demand is associated with amino acids present in the stomach fluid. Amino acids were identified and quantified in the stomach fluid by precolumn derivatization with o-phthalaldehyde and high-pressure liquid chromatography (HPLC). When stomach fluid is chlorinated to concentrations of chlorine between 200 and 1000 mg/L, organic N-chloramines are formed. After derivatization of chlorinated stomach fluid with dansyl sulfinic acid, fluorescent derivatives of chloramines were separated by HPLC. Three chloramino acid derivatives, N-chloroalanine, N-chloroglycine, and N-chlorophenylalanine, were identified by cochromatography with known standards using two chromatographic methods. The yield of a chloramine that would form in stomach fluid on administration of hypochlorite to animals as determined using tritiated piperidine and doses of 200 and 1000 mg/L chlorine. Yields of tritiated N-chloropiperidine in recovered stomach fluid were 70% and 42%, respectively, of the theoretical amount expected.

  10. Experimental study of REE, Ba, Sr, Mo and W partitioning between carbonatitic melt and aqueous fluid with implications for rare metal mineralization (United States)

    Song, WenLei; Xu, Cheng; Veksler, Ilya V.; Kynicky, Jindrich


    Carbonatites host some unique ore deposits, especially rare earth elements (REE). Hydrothermal fluids have been proposed to play a significant role in the concentration and transport of REE and other rare metals in carbonatites, but experimental constraints on fluid-melt equilibria in carbonatitic systems are sparse. Here we present an experimental study of trace element (REE, Ba, Sr, Mo and W) partitioning between hydrous fluids and carbonatitic melts, bearing on potential hydrothermal activity associated with carbonatite ore-forming systems. The experiments were performed on mixtures of synthetic carbonate melts and aqueous fluids at 700-800 °C and 100-200 MPa using rapid-quench cold-seal pressure vessels and double-capsule assemblages with diamond traps for analyzing fluid precipitates in the outer capsule. Starting mixtures were composed of Ca, Mg and Na carbonates spiked with trace elements. Small amounts of F or Cl were added to some of the mixtures to study the effects of halogens on the element distribution. The results show that REE, Ba, Sr, Mo and W all preferentially partition into carbonatite melt and have fluid-melt distribution coefficients ( D f/m) below unity. The REE partitioning is slightly dependent on the major element (Ca, Mg and Na) composition of the starting mixtures, and it is influenced by temperature, pressure, and the presence of halogens. The fluid-melt D values of individual REE vary from 0.02 to 0.15 with D_{Lu}^{f} / {fm}{m} being larger than D_{La}^{f} / {fm}{m} by a factor of 1.1-2. The halogens F and Cl have strong and opposite effects on the REE partitioning. Fluid-melt D REE are about three times higher in F-bearing compositions and ten times lower in Cl-bearing compositions than in halogen-free systems. D_{W}^{f} / {fm}{m} and D_{Mo}^{f} / {fm}{m} are the highest among the studied elements and vary between 0.6 and 0.7; D_{Ba}^{f} / {fm}{m} is between 0.05 and 0.09, whereas D_{Sr}^{f} / {fm}{m} is at about 0.01-0.02. The

  11. A Designer Fluid for Aluminum Phase Change Devices, Vol. 1 of 3: General Inorganic Aqueous Solution (IAS) Chemistry (United States)


    out in wicked phase change heat transfer devices. Wen [18] used nanoparticle suspensions to successfully increase the boiling heat transfer...Aqueous Solution of an Anionic Surfactant,” Journal of Heat Transfer 122, No. 4: 708. [18] Wen , D. and Ding, Y., 2005, “Experimental Investigation...Li, Y., 1974, “Diffusion of Ions in Sea Water and in Deep -Sea Sediments,” Geochimica et Cosmochimica Acta, Vol. 88, pp. 703-714. [36] Negishi, K

  12. A bio-based, facile approach for the preparation of covalently functionalized carbon nanotubes aqueous suspensions and their potential as heat transfer fluids. (United States)

    Sadri, Rad; Hosseini, Maryam; Kazi, S N; Bagheri, Samira; Zubir, Nashrul; Solangi, K H; Zaharinie, Tuan; Badarudin, A


    In this study, we propose an innovative, bio-based, environmentally friendly approach for the covalent functionalization of multi-walled carbon nanotubes using clove buds. This approach is innovative because we do not use toxic and hazardous acids which are typically used in common carbon nanomaterial functionalization procedures. The MWCNTs are functionalized in one pot using a free radical grafting reaction. The clove-functionalized MWCNTs (CMWCNTs) are then dispersed in distilled water (DI water), producing a highly stable CMWCNT aqueous suspension. The CMWCNTs are characterized using Raman spectroscopy, X-ray photoelectron spectroscopy and transmission electron microscopy. The electrostatic interactions between the CMWCNT colloidal particles in DI water are verified via zeta potential measurements. UV-vis spectroscopy is also used to examine the stability of the CMWCNTs in the base fluid. The thermo-physical properties of the CMWCNT nano-fluids are examined experimentally and indeed, this nano-fluid shows remarkably improved thermo-physical properties, indicating its superb potential for various thermal applications. Copyright © 2017. Published by Elsevier Inc.

  13. Magmatism on the Moon (United States)

    Michaut, Chloé; Thorey, Clément; Pinel, Virginie


    Volcanism on the Moon is dominated by large fissure eruptions of mare basalt and seems to lack large, central vent, shield volcanoes as observed on all the other terrestrial planets. Large shield volcanoes are constructed over millions to several hundreds of millions of years. On the Moon, magmas might not have been buoyant enough to allow for a prolonged activity at the same place over such lengths of time. The lunar crust was indeed formed by flotation of light plagioclase minerals on top of the lunar magma ocean, resulting in a particularly light and relatively thick crust. This low-density crust acted as a barrier for the denser primary mantle melts. This is particularly evident in the fact that subsequent mare basalts erupted primarily within large impact basins where at least part of the crust was removed by the impact process. Thus, the ascent of lunar magmas might have been limited by their reduced buoyancy, leading to storage zone formation deep in the lunar crust. Further magma ascent to shallower depths might have required local or regional tensional stresses. Here, we first review evidences of shallow magmatic intrusions within the lunar crust of the Moon that consist in surface deformations presenting morphologies consistent with models of magma spreading at depth and deforming an overlying elastic layer. We then study the preferential zones of magma storage in the lunar crust as a function of the local and regional state of stress. Evidences of shallow intrusions are often contained within complex impact craters suggesting that the local depression caused by the impact exerted a strong control on magma ascent. The depression is felt over a depth equivalent to the crater radius. Because many of these craters have a radius less than 30km, the minimum crust thickness, this suggests that the magma was already stored in deeper intrusions before ascending at shallower depth. All the evidences for intrusions are also preferentially located in the internal

  14. Thermodynamic Modeling of Several Aqueous Alkanol Solutions Containing Amino Acids with the Perturbed-Chain Statistical Associated Fluid Theory Equation of State

    DEFF Research Database (Denmark)

    Ferreira, Luisa; Breil, Martin Peter; Pinho, S. P.


    parameters for the amino acids were fitted to the densities, activity and osmotic coefficients, vapor pressures, and water activity of their aqueous solutions. The solubilities of amino acids in pure and mixed solvent systems were calculated on the basis of the phase equilibrium conditions for a pure solid...... and a fluid phase. The hypothetical melting properties of each amino acid were fitted, to accurately correlate the solubilities in pure water. Only one temperature independent binary parameter is required for each amino acid/solvent pair. The model can accurately describe the solubility of the amino acids...... in water, but the correlation for the solubility in pure alcohols was not so satisfactory. The solubility in mixed solvents (ternary systems) was predicted on the basis of the modeling of the solubility in pure solvents, without any additional fitting of the parameters, and the results achieved were...

  15. The partitioning of barium and lead between silicate melts and aqueous fluids at high pressures and temperatures

    International Nuclear Information System (INIS)

    Bureau, Helene; Menez, Benedicte; Khodja, Hicham; Daudin, Laurent; Gallien, Jean-Paul; Massare, Dominique; Shaw, Cliff; Metrich, Nicole


    The origin of subduction-related magmas is still a matter of debate in the Earth Sciences. These magmas are characterised by their distinctive trace element compositions compared to magmas from other tectonic settings, e.g. mid-ocean ridges or rifts. The distinct trace element composition of these magmas is generally attributed to alteration of the source region by a contaminating agent: either a silicate melt or a hydrous fluid, possibly chlorine-enriched. In this study, we have used μPIXE (proton induced X-ray emission) to analyse synthetic samples obtained from a micro-experimental petrology study that aims to determine the partitioning behaviour of two key elements, Ba and Pb, between silicate melt and both pure water and saline fluids. Our experiments were performed at high-pressure (>0.34-1.53 GPa) and high-temperature (697-1082 deg. C) in a hydrothermal diamond anvil cell, that was used as a transparent rapid quench autoclave. We observed that at high pressure and temperature, in the presence of pure water, Ba and Pb are not strongly fractionated into one phase or the other. The partition coefficient of Pb is ranging from 0.46 to 1.28. Results from one experiment performed at 0.83 GPa and 847 deg. C, in the presence of a saline fluid indicate that the presence of Cl induces strong fractionation of Pb and moderate fractionation of Ba both into the silicate melt. In addition, our data indicate that Cl is strongly partitioned into the fluid phase

  16. Active Magmatic Underplating in Western Eger Rift, Central Europe

    Czech Academy of Sciences Publication Activity Database

    Hrubcová, Pavla; Geissler, W.H.; Bräuer, K.; Vavryčuk, Václav; Tomek, Č.; Kämpf, H.


    Roč. 36, č. 12 (2017), s. 2846-2862 ISSN 0278-7407 R&D Projects: GA ČR GA17-19297S; GA ČR GC16-19751J Institutional support: RVO:67985530 Keywords : active intraplate magmatic underplating * mantle-derived fluids * high-velocity lower crust * reflection-free magma body Subject RIV: DC - Siesmology, Volcanology, Earth Structure OBOR OECD: Volcanology Impact factor: 3.784, year: 2016

  17. Active Magmatic Underplating in Western Eger Rift, Central Europe (United States)

    Hrubcová, Pavla; Geissler, Wolfram H.; Bräuer, Karin; Vavryčuk, Václav; Tomek, Čestmír.; Kämpf, Horst


    The Eger Rift is an active element of the European Cenozoic Rift System associated with intense Cenozoic intraplate alkaline volcanism and system of sedimentary basins. The intracontinental Cheb Basin at its western part displays geodynamic activity with fluid emanations, persistent seismicity, Cenozoic volcanism, and neotectonic crustal movements at the intersections of major intraplate faults. In this paper, we study detailed geometry of the crust/mantle boundary and its possible origin in the western Eger Rift. We review existing seismic and seismological studies, provide new interpretation of the reflection profile 9HR, and supplement it by new results from local seismicity. We identify significant lateral variations of the high-velocity lower crust and relate them to the distribution and chemical status of mantle-derived fluids and to xenolith studies from corresponding depths. New interpretation based on combined seismic and isotope study points to a local-scale magmatic emplacement at the base of the continental crust within a new rift environment. This concept of magmatic underplating is supported by detecting two types of the lower crust: a high-velocity lower crust with pronounced reflectivity and a high-velocity reflection-free lower crust. The character of the underplated material enables to differentiate timing and tectonic setting of two episodes with different times of origin of underplating events. The lower crust with high reflectivity evidences magmatic underplating west of the Eger Rift of the Late Variscan age. The reflection-free lower crust together with a strong reflector at its top at depths of 28-30 km forms a magma body indicating magmatic underplating of the late Cenozoic (middle and upper Miocene) to recent. Spatial and temporal relations to recent geodynamic processes suggest active magmatic underplating in the intracontinental setting.

  18. The mobility of Nb in rutile-saturated NaCl- and NaF-bearing aqueous fluids from 1–6.5 GPa and 300–800 °C

    Energy Technology Data Exchange (ETDEWEB)

    Tanis, Elizabeth A.; Simon, Adam; Tschauner, Oliver; Chow, Paul; Xiao, Yuming; Burnley, Pamela; Cline II, Christopher J.; Hanchar, John M.; Pettke, Thomas; Shen, Guoyin; Zhao, Yusheng (MUN); (Michigan); (CIW); (UNLV); (Bern)


    Rutile (TiO₂) is an important host phase for high field strength elements (HFSE) such as Nb in metamorphic and subduction zone environments. The observed depletion of Nb in arc rocks is often explained by the hypothesis that rutile sequesters HFSE in the subducted slab and overlying sediment, and is chemically inert with respect to aqueous fluids evolved during prograde metamorphism in the forearc to subarc environment. However, field observations of exhumed terranes, and experimental studies, indicate that HFSE may be soluble in complex aqueous fluids at high pressure (i.e., >0.5 GPa) and moderate to high temperature (i.e., >300 °C). In this study, we investigated experimentally the mobility of Nb in NaCl- and NaF-bearing aqueous fluids in equilibrium with Nb-bearing rutile at pressure-temperature conditions applicable to fluid evolution in arc environments. Niobium concentrations in aqueous fluid at rutile saturation were measured directly by using a hydrothermal diamond-anvil cell (HDAC) and synchrotron X-ray fluorescence (SXRF) at 2.1 to 6.5 GPa and 300–500 °C, and indirectly by performing mass loss experiments in a piston-cylinder (PC) apparatus at ~1 GPa and 700–800 °C. The concentration of Nb in a 10 wt% NaCl aqueous fluid increases from 6 to 11 μg/g as temperature increases from 300 to 500 °C, over a pressure range from 2.1 to 2.8 GPa, consistent with a positive temperature dependence. The concentration of Nb in a 20 wt% NaCl aqueous fluid varies from 55 to 150 μg/g at 300 to 500 °C, over a pressure range from 1.8 to 6.4 GPa; however, there is no discernible temperature or pressure dependence. The Nb concentration in a 4 wt% NaF-bearing aqueous fluid increases from 180 to 910 μg/g as temperature increases from 300 to 500 °C over the pressure range 2.1 to 6.5 GPa. The data for the F-bearing fluid indicate that the Nb content of the fluid exhibits a dependence on temperature between 300 and 500 °C at ≥2 GPa, but there is no observed

  19. Composition and source of salinity of ore-bearing fluids in Cu-Au systems of the Carajás Mineral Province, Brazil (United States)

    Xavier, Roberto; Rusk, Brian; Emsbo, Poul; Monteiro, Lena


    The composition and Cl/Br – NaCl ratios of highly saline aqueous inclusions from large tonnage (> 100 t) IOCG deposits (Sossego, Alvo 118, and Igarapé Bahia) and a Paleoproterozoic intrusion-related Cu-Au-(Mo-W-Bi-Sn) deposit (Breves; Ca-dominated (5 to 10 times more than in porphyry Cu-Au fluids), and contain percent level concentrations of Na and K. IOCG inclusion fluids, however, contain higher Sr, Ba, Pb, and Zn concentrations, but significantly less Bi, than the intrusion-related Breves inclusion fluids. Cu is consistently below detection limits in brine inclusions from the IOCG and intrusion-related systems and Fe was not detected in the latter. Cl/Br and Na/Cl ratios of the IOCG inclusion fluids range from entirely evaporative brines (bittern fluids; e.g. Igarapé Bahia and Alvo 118) to values that indicate mixing with magma-derived brines. Cl/Br and Na/Cl ratios of the Breves inclusion fluids strongly suggest the involvement of magmatic brines, but that possibly also incorporated bittern fluids. Collectively, these data demonstrate that residual evaporative and magmatic brines were important components of the fluid regime involved in the formation of Cu-Au systems in the Carajás Mineral Province.

  20. Effects of non-aqueous fluids-associated drill cuttings discharge on shelf break macrobenthic communities in the Campos Basin, Brazil. (United States)

    Santos, Maria Fernanda L; Silva, Janete; Fachel, Jandyra M G; Pulgati, Fernando H


    This paper assesses the effects of non-aqueous fluids (NAF)-associated drill cuttings discharge on shelf break macrobenthic communities in the Campos Basin, off the southeast Brazilian coast, Rio de Janeiro State. Samples were taken with a 0.25-m2 box corer from surrounding two oil and gas wells on three monitoring cruises: before drilling, three months after drilling, and 22 months after drilling. Statistical methodologies used Bayesian geostatistical and analysis of variance models to evaluate the effects of the NAF-associated drill cuttings discharge and to define the impact area. The results indicated that marked variations were not observed in the number of families between cruises, though there were changes in the fauna composition. The changes seen in biological descriptors in both control and background situation areas were not considered significant, showing a temporal homogeneity in means. The impact area presented changes in biological descriptors of communities and trophic structure during the three cruises and such changes were correlated to chemical and physical variables related to the drilling activities, as a result of the mix of drill cuttings and sediment and the anoxic conditions established in the substrate. In that area, three months after drilling, a decrease in diversity and an increase in density, motile deposit-feeders and Pol/Crp ratio, and dominance of opportunistic organisms, such as the capitellid Capitella sp., were observed and, 22 months after drilling, an increase of diversity, reduction of dominance of capitellid polychaete, changes in the fauna composition, and a dominance of opportunistic burrowing and tube-building organisms were observed, indicating an ecological succession process.

  1. On the Hydrogranular Dynamics of Magmatic Gravity Currents (United States)

    McIntire, M. Z.; Bergantz, G. W.; Schleicher, J.; Burgisser, A.


    Magmatic processes are generally governed by multi-phase interactions of silicate liquid, crystals, and bubbles. However, the modes of dissipation and the manner that stress is transmitted are poorly understood. We use a model of a simple but widely applicable gravity current as a means to exemplify the hydrogranular dynamics in crystal-rich magmas. Viscous and lubrication forces are of special interest because they have a dual role in dispersal and mixing in a crystal-rich gravity current. For example, lubrication forces provide an initial apparent yield strength by inducing a negative pore pressure as crystals move apart. However, once the gravity current is underway, lubrication forces reduce the dissipation due to collision and frictional contact.The gravity current is initiated by a combination of toppling and sliding along a well-defined granular fault. This produces three distinct regimes: a quasi-static base, an overlying particle hump that translates in a quasi-plastic fashion by grain-passing and rolling until the angle of repose is reached, and a viscous particle current. The current initially forms a leading vortex at the head, but the loss of crystals by sedimentation-assisted granular capture by an upward growing particle front drains energy from the flow. The vortex is soon abandoned, but persists in the reservoir as a fossil feature of orphaned crystals in a smear of previous intercumulate fluid. The kinetic energy of the most active crystals decays in a dual fashion, initially linearly, then parabolically with a near symmetrical increase and loss of kinetic energy.There is very little entrainment and mixing between intercumulate and reservoir fluids from magmatic gravity currents. Only a thin seam of reservoir melt is captured by the base of the flow as it descends across the floor. Hence magmatic gravity currents, while producing modest amounts of crystal sorting, are not effective agents of mixing as lubrication and viscous forces inhibit

  2. Fluid Characteristics in the Giant Quartz Reef System of the Bundelkhand Craton, India: Constraints from Fluid Inclusion Study (United States)

    Rout, D.; Panigrahi, M. K.; Pati, J. K.


    Giant quartz reefs are anomalous features indicating extensive mobilization of silica in the crust. Such reefs in the Abitibi belt, Canada and elsewhere are believed to be the result of activity of fluid of diverse sources on terrain boundaries. The Bundelkhand granitoid complex constituting a major part of the Bundelkhnad Craton in north-Central India is traversed by numerous such quartz reefs all across for a length of about 500 km. There are about 20 major reefs having dimensions of 35 to 40 km in length, 50 to 60 m in width standing out as prominent ridges in the region. Almost all are aligned parallel to each other in a sub-vertical to vertical manner following the NE-SW to NNE-SSW trend. Fluid inclusion petrography in quartz from these reefs reveal four types of inclusions viz. aqueous biphase (type-I), pure carbonic (type-II), aqueous carbonic (type-III) and polyphase (type-IV) inclusions. The type-I aqueous biphase inclusions are the dominant type in all the samples studied so far. Salinities calculated from temperature of melting of last ice (Tm) values are low to moderate, ranging from 0.18 to 18.19 wt% NaCl equivalents. Temperature of liquid-vapor homogenization (Th) values of these inclusions show a wide range from 101 ºC to 386 ºC (cluster around 150-250 ºC) essentially into liquid phase ruling out boiling during its course of evolution. Besides, aqueous Biphase inclusions, some data on pure CO2 inclusions furnish a near constant value of TmCO2 at -56.6 ºC in the Bundelkhand Craton indicating absence of CH4. Bivariate plot between Th and salinity suggest three possible water types which are controlling the overall activity of fluid in quartz reefs of Bundelkhand Craton viz. low-T low saline, high-T low saline and moderate-T and moderate saline. A low saline and CO2-bearing and higher temperature nature resembles a metamorphic fluid that may be a source for these giant quartz reefs. The low temperature low-salinity component could be a meteoric

  3. Thermodynamic model for uplift and deflation episodes (bradyseism) associated with magmatic-hydrothermal activity at the Campi Flegrei (Italy) (United States)

    Lima, Annamaria; De Vivo, Benedetto; Spera, Fran J.; Bodnar, Robert J.; Milia, Alfonsa; Nunziata, Concettina; Belkin, Harvey E.; Cannatelli, Claudia


    Campi Flegrei (CF) is a large volcanic complex located west of the city of Naples, Italy. Repeated episodes of bradyseism (slow vertical ground movement) near the town of Pozzuoli have been documented since Roman times. Bradyseismic events are interpreted as the consequence of aqueous fluid exsolution during magma solidification on a slow timescale (103–104 yr) superimposed upon a shorter (1–10 yr) timescale for the episodic expulsion of fluid from a deep (~ 3–5 km) lithostatically-pressured low-permeability reservoir to an overlying hydrostatic reservoir. Cycles of inflation and deflation occur during short duration transient events when connectivity is established between deep and shallow hydrothermal reservoirs. The total seismic energy released (4 × 1013 J) during the 1983–1984 bradyseismic crisis is consistent with the observed volume change (uplift) and consistent with the notion that seismic failure occurs in response to the shear stress release induced by volume change. Fluid transport and concomitant propagation of hydrofractures as fluid expands from lithostatic to hydrostatic pressure during decompression leads to ground surface displacement. Fluid decompression occurs along the fluid isenthalp (Joule–Thompson expansion) during transient periods of reservoir connectivity and leads to mineral precipitation. Each kilogram of fluid precipitates about 3 × 10− 3 kg of silica along a typical decompression path along the isenthalp. Mineral precipitation modifies the permeability and acts to reseal connection paths thereby isolating lithostatic and hydrostatic reservoirs ending one bradyseism phase and beginning another. Crystallization and exsolution of the magmatic fluid generates ≈ 7 × 1015 J of mechanical (PΔV) energy, and this is sufficient to accomplish the observed uplift at CF. Although magma emplacement is the ultimate origin of bradyseism, fresh recharge of magma is not a prerequisite. Instead, short to intermediate

  4. Carbonatite magmatism in northeast India (United States)

    Kumar, D.; Mamallan, R.; Dwivedy, K. K.

    The Shillong Plateau of northeast India is identified as an alkaline province in view of the development of several carbonatite complexes e.g. the Sung Valley (Jaintia Hills), Jasra (Karbi-Anglong), Samchampi and Barpung (Mikir Hills) and lamprophyre dyke swarms (Swangkre, Garo-Khasi Hills). On the basis of limited KAr data, magmatic activity appears to have taken place over a protracted period, ranging from the Late Jurassic to the Early Cretaceous. The carbonatite complexes of the Shillong Plateau share several common traits: they are emplaced along rift zones, either within Archaean gneisses or Proterozoic metasediments and granites, and exhibit enrichment in the light rare-earth elements, U, Th, Nb, Zr, Ti, K and Na. The enrichment in incompatible trace elements can best be accounted for if the parental magmas were of alkali basaltic type (e.g. mela-nephelinite or carbonate-rich alkali picrite).

  5. Geology and ore fluid geochemistry of the Jinduicheng porphyry molybdenum deposit, East Qinling, China (United States)

    Li, Hongying; Ye, Huishou; Wang, Xiaoxia; Yang, Lei; Wang, Xiuyuan


    Jinduicheng deposit is a giant Mesozoic porphyry Mo system deposit in the East Qinling molybdenum belt, Shaanxi Province, China. The mineralization is associated with the I-type Jinduicheng granite porphyry. Both the porphyry stock and country rocks underwent intense hydrothermal alteration. The alteration, with increasing distance from the parent intrusion, changes from silicification, through potassic and phyllic assemblages, carbonation, to propylitic assemblages. Molybdenite, the dominant ore mineral, occurs in veinlets, most of which are hosted by the altered country rocks, with less than 25% of the ore in the porphyry body. The hydrothermal system comprises four stages, including pre-ore quartz and K-feldspar; two ore stages of quartz, K-feldspar, molybdenite, and Pb- And Zn-bearing sulfides; and post-ore quartz and carbonate. Six main types of primary fluid inclusions are present in hydrothermal quartz, including two-phase aqueous, one-phase aqueous, three-phase CO2-bearing, CO2-dominated fluid inclusions, gas inclusions, and melt inclusions. The homogenization temperatures of fluid inclusions range from 210 to 290 °C in the pre-ore stage, 150-310 °C in ore stage I, 150-360 °C in the ore stage II, and 195-325 °C in the post-ore stage quartz. Estimated salinities of the ore-forming fluids range from 6.9 to 13.5, 4.3 to 12.3, 6.2 to 12.4, and 3.4 to 9.9 wt.% NaCl equiv. in stages 1-4, respectively. The δ34S values of pyrite in the two ore stages range from 2.8‰ to 4.3‰, whereas the δ34S values of molybdenite range from 2.9‰ to 6.2‰. The data suggest both magmatic and crustal sources of sulfur. The δD and δ18O values for the hydrothermal fluids are -57.2‰ to -84.4‰ and 8.0‰ to -3.2‰, respectively. The fluid inclusion and stable data indicate that the pre-ore hydrothermal fluids were mostly of magmatic origin, but the fluids responsible for ore deposition were mixed magmatic and meteoric, and eventually meteoric water dominated the system

  6. Isotopic signature of Madeira basaltic magmatism

    International Nuclear Information System (INIS)

    Kogarko, L.N.; Karpenko, S.F.; Bibikova, E.V.; Mato, Zh.


    Chemical composition of the basalts of Madeira Island is studied. To assess the isotopic sources of magmatism the Pb-Sr, Sm-Nd, U-Th-Pb systems were investigated in a number of basalts. It is shown that the island's rocks are characterized by the mostly deplet sources in relation to Pb-Sr and Sm-Nd systems ( 87 Sr/ 86 Sr - 0.70282-0.70292, 143 Nd/ 144 Nd - 0.52303-0.51314). Isotopic composition of lead testifies that the magmatism reservoir is some enriched. It is concluded that the magmatism of Madeira Island is a new example of world ocean island's volcanism [ru

  7. Formation of heterogeneous magmatic series beneath North Santorini, South Aegean island arc

    DEFF Research Database (Denmark)

    Bailey, John C; Jensen, E.S.; Hansen, A.


    magma formation beneath North Santorini throughout its 500 ka history is attributed to variable transfer of sedimentary components - either terrigenous or pelagic, as bulk sediments or high-temperature partial melts rather than fluids or low-temperature partial melts - from a rupture zone...... in the subducted slab to the overlying mantle. The three main magmatic series followed independent paths of assimilation of upper crustal materials during fractional crystallization. Assimilation was more pronounced at the basaltic stage. The long-lived histories of the three main magmatic series imply repetitive...... melting of isolated mantle regions, ascent of magmas through independent feeder systems, and their residence in separate crustal magma chambers....

  8. Different Diversity and Distribution of Archaeal Community in the Aqueous and Oil Phases of Production Fluid From High-Temperature Petroleum Reservoirs

    Directory of Open Access Journals (Sweden)

    Bo Liang


    Full Text Available To get a better knowledge on how archaeal communities differ between the oil and aqueous phases and whether environmental factors promote substantial differences on microbial distributions among production wells, we analyzed archaeal communities in oil and aqueous phases from four high-temperature petroleum reservoirs (55–65°C by using 16S rRNA gene based 454 pyrosequencing. Obvious dissimilarity of the archaeal composition between aqueous and oil phases in each independent production wells was observed, especially in production wells with higher water cut, and diversity in the oil phase was much higher than that in the corresponding aqueous phase. Statistical analysis further showed that archaeal communities in oil phases from different petroleum reservoirs tended to be more similar, but those in aqueous phases were the opposite. In the high-temperature ecosystems, temperature as an environmental factor could have significantly affected archaeal distribution, and archaeal diversity raised with the increase of temperature (p < 0.05. Our results suggest that to get a comprehensive understanding of petroleum reservoirs microbial information both in aqueous and oil phases should be taken into consideration. The microscopic habitats of oil phase, technically the dispersed minuscule water droplets in the oil could be a better habitat that containing the indigenous microorganisms.

  9. Characterization of fluid inclusions from mineralized pegmatites of the Damara Belt, Namibia: insight into late-stage fluid evolution and implications for mineralization (United States)

    Ashworth, Luisa; Kinnaird, Judith Ann; Nex, Paul Andrew Martin; Erasmus, Rudolph Marthinus; Przybyłowicz, Wojciech Józef


    Mineralized NYF and LCT pegmatites occur throughout the northeast-trending Neoproterozoic Damara Belt, Namibia. Mineralization in the pegmatites varies geographically, from the northeast, where they are enriched in Li-Be, to the southwest, where they also contain notable Sn and U. Similar fluid inclusion populations occur throughout the pegmatites, regardless of their respective metal enrichments, and primary fluid inclusion textures were destroyed by continued fluid activity. Pseudosecondary to secondary inclusions are aqueo-carbonic, carbonic, and aqueous in composition, and have been divided into five types. The earliest populations are saline (>26.3 eq. wt.% NaCl), homogenizing at temperatures in excess of 300 °C. Their carbonic phase is composed of CO2, with minor CH4, and micro-elemental mapping indicates they contain trace metals, including Ca, Fe, Zn, Cu, and K. Type 3 inclusions formed later, homogenize at 325 °C, and are less saline, with a carbonic phase composed of CO2. Type 4 carbonic inclusions are composed of pure CO2, and represent the latest stages of fluid evolution, while Type 5 aqueous inclusions are believed to be unrelated to the crystallization of the pegmatites, and rather the result of regional Cretaceous magmatism, or the ingress of meteoric water. The similarities in fluid inclusion populations observed in the pegmatites suggest that differences in mineralization were driven by magma composition rather than fluid activity alone, however saline fluids facilitated the enrichment and deposition of metals during the late stages of crystallization. Furthermore, the similarities between fluid inclusion populations in different pegmatites suggests they share a similar fluid evolution.

  10. Research on antibodies anti toxoplasma gondii in intraocular fluids (Aqueous and vitreous humor) from patients with ocular toxoplasmosis, in the City of Belém, Pará State


    Carmo, Ediclei Lima do; Almeida, Edmundo Frota; Bichara, Cléa Nazaré; Póvoa, Marinete Marins


    Foi realizada pesquisa de anticorpos IgG, IgM e IgA anti-Toxoplasma gondii no soro e fluidos intra-oculares (humor aquoso e vítreo) de pacientes com toxoplasmose ocular. A partir dos resultados obtidos verificou-se que anticorpos IgG e IgA intraocular anti-Toxoplasma gondii podem vir a ser importantes marcadores no diagnóstico de toxoplasmose ocular.Tests were performed for antibodies IgG, IgM and IgA anti-Toxoplasma gondii antibodies in serum and intraocular fluids (Aqueous and vitreous humo...

  11. Japan-U. S. seminar on magmatic contributions to hydrothermal systems

    Energy Technology Data Exchange (ETDEWEB)

    Muffler, L. (U. S. Geological Survey, CA (United States)); Hedenquist, J. (Geological Survey of Japan, Tsukuba (Japan)); Kesler, S. (University of Michigan, MI (United States)); Izawa, E. (Kyushu University, Fukuoka (Japan). Faculty of Engineering)


    A multidisciplinary Seminar on Magmatic Contributions to Hydrothermal Systems'' was held at Ebino and Kagoshima at Kyushu, November, 1991. The principal purpose of the Ebino/Kagoshima Seminar was to bring together a small group of individuals which have been conducting active research on magmatic contributions to hydrothermal systems. The Seminar focussed on the porphyry and epithermal ore environments because of the potential to relate these environments to active volcanic and geothermal systems. Disciplines included valcanology, volcanic gas geochemistry, water geochemistry, isotope geochemistry, geochemical modeling, experimental geochemistry, igneous petrology, geothermal geology, economic geology, fluid-inclusion study, geophysics, and physical modeling. This paper summarizes the outline and significance of the Seminar. It was pointed out that understanding magmatic contributions to hydrothermal systems would require augmented experimental investigations, numerical modeling, field studies, and drilling.

  12. Synchrotron x-ray spectroscopy of EuHN O3 aqueous solutions at high temperatures and pressures and Nb-bearing silicate melt phases coexisting with hydrothermal fluids using a modified hydrothermal diamond anvil cell and rail assembly (United States)

    Mayanovic, Robert A.; Anderson, Alan J.; Bassett, William A.; Chou, I.-Ming


    A modified hydrothermal diamond anvil cell (HDAC) rail assembly has been constructed for making synchrotron x-ray absorption spectroscopy, x-ray fluorescence, and x-ray mapping measurements on fluids or solid phases in contact with hydrothermal fluids up to ???900??C and 700 MPa. The diamond anvils of the HDAC are modified by laser milling grooves or holes, for the reduction of attenuation of incident and fluorescent x rays and sample cavities. The modified HDAC rail assembly has flexibility in design for measurement of light elements at low concentrations or heavy elements at trace levels in the sample and the capability to probe minute individual phases of a multiphase fluid-based system using focused x-ray microbeam. The supporting rail allows for uniform translation of the HDAC, rotation and tilt stages, and a focusing mirror, which is used to illuminate the sample for visual observation using a microscope, relative to the direction of the incident x-ray beam. A structure study of Eu(III) aqua ion behavior in high-temperature aqueous solutions and a study of Nb partitioning and coordination in a silicate melt in contact with a hydrothermal fluid are described as applications utilizing the modified HDAC rail assembly. ?? 2007 American Institute of Physics.

  13. Crustal inheritance and arc magmatism: Magnetotelluric constraints from the Washington Cascades on top-down control (United States)

    Bedrosian, P.; Peacock, J.; Bowles-martinez, E.; Schultz, A.; Hill, G.


    Worldwide, arc volcanism occurs along relatively narrow magmatic arcs, the locations of which are considered to mark the onset of dehydration reactions within the subducting slab. This `bottom-up' approach, in which the location of arc volcanism reflects where fluids and melt are generated, explains first-order differences in trench-to-arc distance and is consistent with known variations in the thermal structure and geometry of subducting slabs. At a finer scale, arc segmentation, magmatic gaps, and anomalous forearc and backarc magmatism are also frequently interpreted in terms of variations in slab geometry, composition, or thermal structure.The role of inherited crustal structure in controlling faulting and deformation is well documented; less well examined is the role of crustal structure in controlling magmatism. While the source distribution of melt and subduction fluids is critical to determining the location of arc magmatism, we argue that crustal structure provides `top-down' control on patterns or seismicity and deformation as well as the channeling and ascent of arc magmas. We present evidence within the Washington Cascades based upon correlation between a new three-dimensional resistivity model, potential-field data, seismicity, and Quaternary volcanism. We image a mid-Tertiary batholith, intruded within an Eocene crustal suture zone, and extending throughout much of the crustal column. This and neighboring plutons are interpreted to channel crustal fluids and melt along their margins within steeply dipping zones of marine to transitional metasedimentary rock. Mount St. Helens is interpreted to be fed by fluids and melt generated further east at greater slab depths, migrating laterally (underplating?) beneath the Spirit Lake batholith, and ascending through metasedimentary rocks within the brittle crust. At a regional scale, we argue that this concealed suture zone controls present-day deformation and seismicity as well as the distribution of forearc

  14. Sources of Magmatic Volatiles Discharging from Subduction Zone Volcanoes (United States)

    Fischer, T.


    Subduction zones are locations of extensive element transfer from the Earth's mantle to the atmosphere and hydrosphere. This element transfer is significant because it can, in some fashion, instigate melt production in the mantle wedge. Aqueous fluids are thought to be the major agent of element transfer during the subduction zone process. Volatile discharges from passively degassing subduction zone volcanoes should in principle, provide some information on the ultimate source of magmatic volatiles in terms of the mantle, the crust and the subducting slab. The overall flux of volatiles from degassing volcanoes should be balanced by the amount of volatiles released from the mantle wedge, the slab and the crust. Kudryavy Volcano, Kurile Islands, has been passively degassing at 900C fumarole temperatures for at least 40 years. Extensive gas sampling at this basaltic andesite cone and application of CO2/3He, N2/3He systematics in combination with C and N- isotopes indicates that 80% of the CO2 and approximately 60% of the N 2 are contributed from a sedimentary source. The mantle wedge contribution for both volatiles is, with 12% and 17% less significant. Direct volatile flux measurements from the volcano using the COSPEC technique in combination with direct gas sampling allows for the calculation of the 3He flux from the volcano. Since 3He is mainly released from the astenospheric mantle, the amount of mantle supplying the 3He flux can be determined if initial He concentrations of the mantle melts are known. The non-mantle flux of CO2 and N2 can be calculated in similar fashion. The amount of non-mantle CO2 and N2 discharging from Kudryavy is balanced by the amount of CO2 and N2 subducted below Kudryavy assuming a zone of melting constrained by the average spacing of the volcanoes along the Kurile arc. The volatile budget for Kudryavy is balanced because the volatile flux from the volcano is relatively small (75 t/day (416 Mmol/a) SO2, 360 Mmol/a of non-mantle CO2 and

  15. Geology, mineralization, and fluid inclusion study of the Kuru-Tegerek Au-Cu-Mo skarn deposit in the Middle Tien Shan, Kyrgyzstan (United States)

    Soloviev, Serguei G.; Kryazhev, Sergey; Dvurechenskaya, Svetlana


    The Kuru-Tegerek Cu-Au-Mo deposit is situated in a system of Late Carboniferous subduction-related magmatic arcs of the Middle Tien Shan, which together constitute a metallogenic belt of Cu-Au-Mo (±W) porphyry, with local skarns, deposits. The deposit is related to magnetite-series gabbro-diorite to tonalite intrusion. It contains prograde magnesian and calcic skarns with abundant magnetite, associated with gabbro-diorite, and retrograde skarn with Cu mineralization, formed after intrusion of tonalite. Subsequent propylitic alteration introduced abundant chalcopyrite and pyrrhotite, and native Au culminating in zones overprinting magnetite and garnet skarn. Later quartz-muscovite-carbonate veins, formed after intrusion of late mafic quartz monzogabbro dikes, contain chalcopyrite, pyrite, arsenopyrite and other sulfides and sulfosalts, tellurides, and native Au. The earliest retrograde skarn garnet contains gaseous low-salinity (1.7-3.4 wt.% NaCl eq.) fluid inclusions homogenizing at 460-500 °C into vapor, indicating that the early fluid released from crystallizing magma was a low-density vapor. It was followed by more saline (4.0-5.0 wt.% NaCl eq.), high-temperature (400-440 °C) aqueous fluid, as fluid release from the magma progressed. Boiling of this fluid at temperatures of 420 to 370 °C and a pressure of 350-300 bar produced a low-salinity (0.6-1.2 wt.% NaCl eq.), essentially gaseous, and high-salinity (from 39 to 31 wt.% NaCl eq.) brine, with possible metal (including Cu) partitioning into both gaseous and aqueous-saline phases. Boiling was coeval with sulfide deposition in the retrograde skarn. The latest episode of the retrograde skarn stage included direct separation of saline ( 40-42 wt.% NaCl eq.) fluid from crystallizing magma. The separation of saline ( 40 to 14 wt.% NaCl eq.) fluids from a crystallizing magmatic melt continued during the propylitic stage, when fluid cooling from 370 to 320 °C, together with decreasing fO2, caused Cu and especially

  16. Desenvolvimento de fluidos aquosos com bentonita para perfuração de poços de petróleo onshore Development of aqueous fluids with bentonite clay for drilling of onshore oil wells

    Directory of Open Access Journals (Sweden)

    R. C. A. M Nascimento


    fluid with specific characteristics in each stage of drilling. Thus, the aim of this work is to develop aqueous fluids with low content of solids and rheological, filtration and lubricity properties adjusted for drilling of onshore oil wells. The fluids were formulated by using industrialized sodium bentonite, polymeric additives and lubricants, in different concentrations, in its composition. Rheological, filtration and lubricity studies showed that the fluids have pseudoplastic behavior and, the selected additives successively play their functions of rheological modifiers, filtrate reducer and lubricant agent. Moreover, it was evidenced the necessity oflubricant additives in aqueous fluids containing bentonite clay and polymers. The addition of 1% of lubricant in the fluid is sufficient to adjust the lubricant capacity of fluids.

  17. Caractérisation des paragenèses et des paléocirculations fluides dans l'indice d'or de Bleïda (Anti-Atlas, Maroc)Characterization of the paragenesis and the fluid palaeo-circulations in the gold showings of Bleida (Anti-Atlas, Morocco) (United States)

    Barakat, Ahmed; Marignac, Christian; Boiron, Marie-Christine; Bouabdelli, Mohamed


    The gold showings at Bleida are hosted in Late Pan-African N50-80 °E quartz-hematite-chlorite 1 tension lenses that are related to the activity of major sinistral sub-east-west thrusts. Ores result from three superimposed stages of fluid migration. Gold occurs in microcracks offsetting the earlier minerals. Fluids evolved from COHN compositions with a saline component to boiling aqueous fluids. Pressure and temperature decreased from 50 MPa and 300 °C to less than 4 MPa and 150 °C. Thus, the gold showings at Bleida were formed in a typical geothermal (epithermal) setting, likely controlled by the Late Pan-African magmatism. To cite this article: A. Barakat et al., C. R. Geoscience 334 (2002) 35-41

  18. Post-magmatic structural evolution of the Troodos Ophiolite Pillow Lavas revealed by microthermometry within vein precipitates, with application to Alpine-Mediterranean supra-subduction zone settings (United States)

    Kurz, W.; Quandt, D.; Micheuz, P.; Krenn, K.


    The Troodos ophiolite, Cyprus, is one of the best preserved ophiolites. Based on geochemical data a supra-subduction zone (SSZ) setting was proposed. Microtextures and fluid inclusions of veins and vesicles within the Pillow Lavas record the post-magmatic structural and geochemical evolution of this SSZ beginning at 75 Ma. Three different vein types from the Upper and Lower Pillow Lavas are distinguished and imply vein precipitation under a dominant extensional regime: (1) syntaxial calcite-, quartz- and zeolite-bearing veins are interpreted as mineralized extension fractures that were pervaded by seawater. This advective fluid flow in an open system changed later into a closed system characterized by geochemical self-organization. (2) Blocky and (3) antitaxial fibrous calcite veins are associated with brecciation due to hydrofracturing and diffusion-crystallization processes, respectively. Based on aqueous fluid inclusion chemistry with seawater salinities in all studied vein types, representative fluid inclusion isochores crossed with calculated litho- and hydrostatic pressure conditions yield mineral precipitation temperatures between 180 and 210 °C, for veins and vesicles hosted in the Upper and Lower Pillow Lavas. This points to a heat source for the circulating seawater and implies that vein and vesicle minerals precipitated shortly after pillow lava crystallization under dominant isobaric cooling conditions. Compared to previous suggestions derived from secondary mineralization a less steep geothermal gradient of 200 °C from the Sheeted Dyke Complex to the Pillow Lavas of the Troodos SSZ is proposed. Further fossil and recent SSZ like the Mirdita ophiolite, Albania, the South-Anatolian ophiolites, Turkey, and the Izu-Bonin fore arc, respectively, reveal similar volcanic sequences. Vein samples recovered during International Ocean Discovery Program expedition 351 and 352 in the Izu-Bonin back and fore arc, respectively, indicate also seawater infiltration

  19. High salinity volatile phases in magmatic Ni-Cu-platinum group element deposits (United States)

    Hanley, J. J.; Mungall, J. E.


    The role of "deuteric" fluids (exsolved magmatic volatile phases) in the development of Ni-Cu-PGE (platinum group element) deposits in mafic-ultramafic igneous systems is poorly understood. Although considerable field evidence demonstrates unambiguously that fluids modified most large primary Ni-Cu-PGE concentrations, models which hypothesize that fluids alone were largely responsible for the economic concentration of the base and precious metals are not widely accepted. Determination of the trace element composition of magmatic volatile phases in such ore-forming systems can offer considerable insight into the origin of potentially mineralizing fluids in such igneous environments. Laser ablation ICP-MS microanalysis allows researchers to confirm the original metal budget of magmatic volatile phases and quantify the behavior of trace ore metals in the fluid phase in the absence of well-constrained theoretical or experimental predictions of ore metal solubility. In this study, we present new evidence from major deposits (Sudbury, Ontario, Canada; Stillwater Complex, Montana, U.S.A.) that compositionally distinct magmatic brines and halide melt phases were exsolved from crystallizing residual silicate melt and trapped within high-T fluid conduits now comprised of evolved rock compositions (albite-quartz graphic granite, orthoclase-quartz granophyre). Petrographic evidence demonstrates that brines and halide melts coexisted with immiscible carbonic phases at the time of entrapment (light aliphatic hydrocarbons, CO2). Brine and halide melt inclusions are rich in Na, Fe, Mn, K, Pb, Zn, Ba, Sr, Al and Cl, and homogenize by either halite dissolution at high T ( ˜450-700° C) or by melting of the salt phase (700-800° C). LA-ICPMS analyses of single inclusions demonstrate that high salinity volatile phases contained abundant base metals (Cu, Fe, Sn, Bi) and precious metals (Pt, Pd, Au, Ag) at the time of entrapment. Notably, precious metal concentrations in the inclusions

  20. Cretaceous magmatism in North-Eastern India and Gondwanaland ...

    Indian Academy of Sciences (India)


    Cretaceous magmatism of NEI: Major Objectives. • Age and duration of Sylhet Traps and its connection to Kerguelene hotspot and Gondwanaland breakup? • Age of carbonatite magmatism associated with the traps? • Relationship of basaltic-carbonatite magmatism with. Aptian (~116 Ma) Mass Extinction event? • Nature of ...

  1. Fluid inclusion characteristics and geological significance of the Dajinshan W-Sn polymetallic deposit in Yunfu, Guangdong Province (United States)

    Yu, Zhangfa; Chen, Maohong; Zhao, Haijie


    The Dajinshan tungsten-tin polymetallic deposit is a quartz-vein-type ore deposit located in Western Guangdong Province. The ore bodies show a fairly simple shape and mainly occur as tungsten-tin polymetallic-bearing sulfide quartz veins, including quartz vein, quartz-greisens, and sulfide quartz veins, and their distribution is spatially related to Dajinshan granitoids. The formation of the deposit experienced three stages: a wolframite-molybdenite-quartz stage, a wolframite-cassiterite-sulfide-quartz stage, and a fluorite-calcite-carbonate stage. Based on detailed petrographic observations, we conducted microthermometric and Raman microspectroscopic studies of fluid inclusions formed at different ore-forming stages in the Dajinshan tungsten-tin polymetallic deposit, identifying four dominant types of fluid inclusions: aqueous two-phase inclusions, CO2-bearing inclusions, solid or daughter mineral-bearing inclusions, and gas-rich inclusions. The gas compositions of ore-forming fluids in the Dajinshan tungsten-tin polymetallic deposit are mostly CO2, CH4, and H2O. The hydrogen, oxygen, and sulfur isotopic data imply that the ore-forming fluids in the Dajinshan tungsten-tin polymetallic deposit were mainly derived from magmatic fluids, mixed with meteoric water in the ore-formation process. These results indicate that the fluid mixing and boiling led to the decomposition of the metal complex in ore-forming fluids and ore deposition.

  2. Nature and source of the ore-forming fluids associated with orogenic gold deposits in the Dharwar Craton

    Directory of Open Access Journals (Sweden)

    Biswajit Mishra


    Full Text Available Neoarchean orogenic gold deposits, associated with the greenstone-granite milieus in the Dharwar Craton include (1 the famous Kolar mine and the world class Hutti deposit; (2 small mines at Hira-Buddini, Uti, Ajjanahalli, and Guddadarangavanahalli; (3 prospects at Jonnagiri; and (4 old mining camps in the Gadag and Ramagiri-Penakacherla belts. The existing diametric views on the source of ore fluid for formation of these deposits include fluids exsolved from granitic melts and extracted by metamorphic devolatilization of the greenstone sequences. Lode gold mineralization occurs in structurally controlled higher order splays in variety of host rocks such as mafic/felsic greenstones, banded iron formations, volcaniclastic rocks and granitoids. Estimated metamorphic conditions of the greenstones vary from lower greenschist facies to mid-amphibolite facies and mineralizations in all the camps are associated with distinct hydrothermal alterations. Fluid inclusion microthermometric and Raman spectroscopic studies document low salinity aqueous-gaseous (H2O + CO2 ± CH4 + NaCl ore fluids, which precipitated gold and altered the host rocks in a narrow P–T window of 0.7–2.5 kbar and 215–320 °C. While the calculated fluid O- and C-isotopic values are ambiguous, S-isotopic compositions of pyrite-precipitating fluid show distinct craton-scale uniformity in terms of its reduced nature and a suggested crustal sulfur source.Available ages on greenstone metamorphism, granitoid plutonism and mineralization in the Hutti Belt are tantamount, making a geochronology-based resolution of the existing debate on the metamorphic vs. magmatic fluid source impossible. In contrast, tourmaline geochemistry suggests involvement of single fluid in formation of gold mineralization, primarily derived by metamorphic devolatilization of mafic greenstones and interlayered sedimentary rocks, with minor magmatic contributions. Similarly, compositions of scheelite

  3. Magmatic sulphides in Quaternary Ecuadorian arc magmas (United States)

    Georgatou, Ariadni; Chiaradia, Massimo; Rezeau, Hervé; Wälle, Markus


    New petrographic and geochemical data on magmatic sulphide inclusions (MSIs) are presented and discussed for 15 Quaternary volcanic centers of the Ecuadorian frontal, main and back volcanic arc. MSIs occur mostly in Fe-Ti oxides (magnetite and/or magnetite-ilmenite pair) and to a lesser extent in silicate minerals (amphibole, plagioclase, and pyroxene). MSIs are present in all volcanic centers ranging in composition from basalt to dacite (SiO2 = 50-67 wt.%), indicating that sulphide saturation occurs at various stages of magmatic evolution and independently from the volcano location along the volcanic arc. MSIs also occur in dioritic, gabbroic and hornblenditic magmatic enclaves of the volcanic rocks. MSIs display variable sizes (1-30 μm) and shapes (globular, ellipsoidal, angular, irregular) and occur mostly as polymineralic inclusions composed of Fe-rich and Cu-poor (pyrrhotite) and Cu-rich (mostly chalcopyrite) phases. Aerial sulphide relative abundances range from 0.3 to 7 ppm in volcanic host rocks and from 13 to 24 ppm in magmatic enclaves. Electron microprobe analyses of MSIs indicate maximum metal contents of Cu = 65.7 wt.%, Fe = 65.2 wt.%, Ni = 10.1 wt.% for those hosted in the volcanic rocks and of Cu = 57.7 wt.%, Fe = 60.9 wt.%, Ni = 5.1 wt.%, for those hosted in magmatic enclaves. Relationships of the sulphide chemistry to the host whole rock chemistry show that with magmatic differentiation (e.g., increasing SiO2) the Cu and Ni content of sulphides decrease whereas the Fe and S contents increase. The opposite behavior is observed with the increase of Cu in the whole rock, because the latter is anti-correlated with the SiO2 whole rock content. Laser ablation ICP-MS analyses of MSIs returned maximum values of PGEs and noble metals of Pd = 30 ppm, Rh = 8.1 ppm, Ag = 92.8 ppm and Au = 0.6 ppm and Pd = 43 ppm, Rh = 22.6 ppm, Ag = 89 ppm and Au = 1 ppm for those hosted in volcanic rocks and magmatic enclaves, respectively. These PGE contents display a

  4. Electrochemistry in near-critical and supercritical fluids. 3. Studies of Br/sup -/, I/sup -/, and hydroquinone in aqueous solutions

    Energy Technology Data Exchange (ETDEWEB)

    Flarsheim, W.J.; Tsou, Y.M.; Trachtenberg, I.; Johnston, K.P.; Bard, A.J.


    A new type of apparatus has been constructed for carrying out electrochemistry in near-critical and supercritical aqueous solutions. The following systems have been studied at a platinum electrode: H/sub 2/O/O/sub 2/, I/sup -//I/sub 2/, Br/sup -//Br/sub 2/, and hydroquinone/benzoquinone. The compact alumina flow cell can be heated or cooled quickly and can be recharged with fresh electrolyte solution while at high temperature and pressure. A large reduction in the potential required for the electrolysis of water was observed. Diffusivities have been measured for iodide ions and hydroquinone. General agreement with the Stokes-Einstein model was observed in the temperature range 25-375/sup 0/C.

  5. Magmatism and deformation during continental breakup (United States)

    Keir, Derek


    The rifting of continents and the transition to seafloor spreading is characterised by extensional faulting and thinning of the lithosphere, and is sometimes accompanied by voluminous intrusive and extrusive magmatism. In order to understand how these processes develop over time to break continents apart, we have traditionally relied on interpreting the geological record at the numerous fully developed, ancient rifted margins around the world. In these settings, however, it is difficult to discriminate between different mechanisms of extension and magmatism because the continent-ocean transition is typically buried beneath thick layers of volcanic and sedimentary rocks, and the tectonic and volcanic activity that characterised breakup has long-since ceased. Ongoing continental breakup in the African and Arabian rift systems offers a unique opportunity to address these problems because it exposes several sectors of tectonically active rift sector development spanning the transition from embryonic continental rifting in the south to incipient seafloor spreading in the north. Here I synthesise exciting, multidisciplinary observational and modelling studies using geophysical, geodetic, petrological and numerical techniques that uniquely constrain the distribution, time-scales, and interactions between extension and magmatism during the progressive breakup of the African Plate. This new research has identified the previously unrecognised role of rapid and episodic dike emplacement in accommodating a large proportion of extension during continental rifting. We are now beginning to realise that changes in the dominant mechanism for strain over time (faulting, stretching and magma intrusion) impact dramatically on magmatism and rift morphology. The challenge now is to take what we're learned from East Africa and apply it to the rifted margins whose geological record documents breakup during entire Wilson Cycles.

  6. Controls on Magmatic and Hydrothermal Processes at Yellowstone Supervolcano: The Wideband Magnetotelluric Component of an Integrated MT/Seismic Investigation (United States)

    Schultz, A.; Bennington, N. L.; Bowles-martinez, E.; Imamura, N.; Cronin, R. A.; Miller, D. J.; Hart, L.; Gurrola, R. M.; Neal, B. A.; Scholz, K.; Fry, B.; Carbonari, R.


    Previous seismic and magnetotelluric (MT) studies beneath Yellowstone (YS) have provided insight into the origin and migration of magmatic fluids within the volcanic system. However, important questions remain concerning the generation of magmatism at YS, the migration and storage of these magmatic fluids, as well as their relationships to hydrothermal expressions. Analysis of regional-scale EarthScope MT data collected previously suggests a relative absence of continuity in crustal partial melt accumulations directly beneath YS. This is in contrast to some seismic interpretations, although such long-period MT data have limited resolving power in the upper-to-mid crustal section. A wideband MT experiment was designed as a component of an integrated MT/seismic project to examine: the origin and location of magmatic fluids at upper mantle/lower crustal depths, the preferred path of migration for these magmatic fluids into the mid- to upper-crust, the resulting distribution of the magma reservoir, the composition of the magma reservoir, and implications for future volcanism at YS. A high-resolution wideband MT survey was carried out in the YS region in the summer of 2017, with more than forty-five wideband stations installed within and immediately surrounding the YS National Park boundary. These data provided nearly six decades of bandwidth ( 10-3 Hz -to- 103 Hz). Extraordinary permitting restrictions prevented us from using conventional installation methods at many of our sites, and an innovative "no-dig" subaerial method of wideband MT was developed and used successfully. Using these new data along with existing MT datasets, we are inverting for the 3D resistivity structure at upper crustal through upper mantle scales at YS. Complementary to this MT work, a joint inversion for the 3D crustal velocity structure is being carried out using both ambient noise and earthquake travel time data. Taken together, these data should better constrain the crustal velocity

  7. The magmatic model for the origin of Archean Au-quartz vein ore systems: an assessment of the evidence

    International Nuclear Information System (INIS)

    Spooner, E.T.C.


    The magmatic model for the origin of Archean Au-quartz vein ore systems suggests that Au was derived by partition between silicate (± sulphide) melts of certain compositions and H 2 O-CO 2 -NaCl magmatic fluids. Supporting evidence includes partial/structural geological relationships, timing relationships, H and C isotope geochemistry, probable primary Au enrichment in the Lamaque stocks, and fluid inclusion volatile geochemistry. Evidence is currently negative with respect to various within- and sub-greenstone belt metamorphic/deep crustal fluid models for primary Au mineralization; however a U-Pb age for vein stage 3 sphene from the Camflo deposit, Quebec which is ∼ 55-60 Ma younger than the host stock at 2685-2680 Ma indicates dissolution/reprecipitation of Au by late, (?) upper crustal saline fluids. Evidence is accumulating that epithermal-meso thermal Au-Ag mineralization in island arc and cordilleran settings may also have been magmatically derived ± high level fluid mixing from calc-alkaline, shoshonitic and other igneous compositions. (author)

  8. Magma flow recorded by magmatic and magnetic fabrics in a shallow granitic pluton: La Gloria Pluton, central Chile (United States)

    Payacán, I. J.; Gutiérrez, F. J.; Gelman, S. E.; Bachmann, O.; Parada, M. A.


    To better understand the dynamics of a small, shallow, silicic magma reservoir, magmatic and magnetic (AMS) fabrics are compared in samples obtained from La Gloria Pluton (LGP), a 10 Ma granitic intrusion located in southern Andes. The magnetic fabric of LGP, mainly given by magnetite, is characterized by oblate shapes. Magnetic lineations have a NW trend with subhorizontal dip, following the main pluton elongation, while magnetic foliation planes have dips varying gradually from vertical at the walls to subhorizontal toward the center and the roof of the pluton. On the basis of numerical simulations, magnetic fabric was interpreted to represent the shear record induced by magmatic convection along solidification fronts as the reservoir reached its rheological locking point. Magmatic fabric (mineral orientation) was determined on 12 samples along the pluton. Three mutually orthogonal thin sections were produced for each sample, perpendicular to the AMS tensor axes. Size and orientation of individual crystals were obtained by image analysis. A 2-D tensor for two mineral groups (plagioclase and amphibole+biotitie) was defined in each mineral plane projecting the crystal lengths on the main crystal orientation (given by Bingham statistics). A 3-D magmatic fabric tensor was obtained. In order to compare the magmatic and magnetic fabrics, magmatic anisotropy parameters were defined similar to the AMS tensors. Magmatic fabric and anisotropy parameter values vary depending on the location inside the pluton: (1) Samples located at the borders exhibit vertical foliations and lineations with a NW trend, similar to the magnetic fabric tensors and higher anisotropy values for plagioclase than amphibole+biotite,; (2) samples located at the center of the LGP commonly present subvertical foliations/lineations, which differ from the magnetic fabric, and higher magmatic anisotropy degree values for amphibole+biotite than plagioclase. Based on numerical simulations of the fluid

  9. Fluid inclusions in jadeitite and jadeite-rich rock from serpentinite mélanges in northern Hispaniola: Trapped ambient fluids in a cold subduction channel (United States)

    Kawamoto, Tatsuhiko; Hertwig, Andreas; Schertl, Hans-Peter; Maresch, Walter V.


    Freezing-point depression was measured in aqueous fluid inclusions to determine salinities in six samples of jadeitite and jadeite-rich rock from the Jagua Clara serpentinite mélange of the Rio San Juan Complex, Dominican Republic. The mélange represents a fossil subduction-zone channel from a cold, mature subduction zone with a geothermal gradient of 6 °C/km. One hundred and twenty-five determinations of salinity in primary inclusions hosted in jadeite, quartz, apatite and lawsonite range between extremes of 1.2 and 8.7, but yield a well-defined mean of 4.5 ± 1.1 wt% (±1 s.d.) NaCl equiv, slightly higher than mean seawater (3.5 wt%). In one sample, eight additional fluid inclusions in quartz aligned along grain boundaries yield slightly lower values of 2.7 ± 1.3 wt% NaCl equiv. Homogenization temperatures were also measured for 47 fluid inclusions in two samples, but primary entrapment densities are not preserved. It is significant that the suite includes two types of samples: those precipitated directly from an aqueous fluid as well as examples of metasomatic replacement of a pre-existing magmatic rock. Nevertheless, the results indicate identical salinity for both types and suggest a much stronger genetic link between the two types of jadeitite and jadeite-rich rock than has previously been assumed. Based on the results of conductivity measurements in modern subduction zones, we envision a pervasive fluid in the subduction channel that evolved from salinity levels lower than those in sea-water up to the measured values due to on-going but largely completed serpentinization in the subduction channel. The present data represent a reference marker for the subduction channel of the Rio San Juan intra-oceanic subduction zone at 30-50 km depth and after 50-60 Myr of operation.

  10. Magmatism at different crustal levels in the ancient North Cascades magmatic arc (United States)

    Shea, E. K.; Bowring, S. A.; Miller, R. B.; Miller, J. S.


    The mechanisms of magma ascent and emplacement inferred from study of intrusive complexes have long been the subject of intense debate. Current models favor incremental construction based on integration of field, geochemical, geochronologic, and modeling studies. Much of this work has been focused on a single crustal level. However, study of magmatism throughout the crust is critical for understanding how magma ascends through and intrudes surrounding crustal material. Here, we present new geochronologic and geochemical work from intrusive complexes emplaced at a range of crustal depths in the Cretaceous North Cascades magmatic arc. These complexes were intruded between 92 and 87 Ma at depths of at ≤5 -10 km, ~20 km, and ~25 km during this time. U-Pb CA-TIMS geochronology in zircon can resolve Jack-Entiat intrusive complex, a highly elongate amalgamation of intrusions recording two episodes of magmatism between~92-88 Ma and ~80-77 Ma. Each of these complexes provides a window into crustal processes that occur at different depths. Our data suggest assembly of the Black Peak intrusive complex occurred via a series of small (0.5-2 km2) magmatic increments from ~92 Ma to ~87 Ma. Field relations and zircon trace element geochemistry indicate each of these increments were emplaced and crystallized as closed systems-we find no evidence for mixing between magmas in the complex. However, zircon inheritance becomes more common in younger intrusions, indicating assimilation of older plutonic material, possibly during magma production or transport. The Seven-Fingered Jack intrusive complex, emplaced around 15-20 km, preserves a much more discontinuous record of intrusion than the Black Peak. Our data indicate major magmatism in the complex occurred between ~92.1-91.1 Ma. Inheritance in the Seven-Fingered Jack is common, particularly along contacts between intrusions. The Tenpeak intrusive complex, assembled between ~92 Ma and 89 Ma, represents one of the deepest exhumed

  11. Geology, mineralization, and fluid inclusion characteristics of the Skrytoe reduced-type W skarn and stockwork deposit, Sikhote-Alin, Russia (United States)

    Soloviev, Serguei G.; Kryazhev, Sergey G.


    The Skrytoe deposit (>145 Kt WO3, average grade 0.449% WO3) in the Sikhote-Alin orogenic system (Eastern Russia) is situated in a metallogenic belt of W, Sn-W, Au, and Au-W deposits formed in a late to post-collisional tectonic environment after cessation of active subduction. It is localized within a mineralized district of reduced-type skarn W and veined Au (±W) deposits and occurrences related to the Early Cretaceous ilmenite-series plutonic suite. The deposit incorporates large stockworks of scheelite-bearing veinlets related to propylitic (amphibole, chlorite, quartz) and phyllic (quartz, sericite, albite, apatite, and carbonate) hydrothermal alteration. The stockwork cuts flat-lying mafic volcanic rocks and limestone partially replaced by pyroxene skarn that host the major W orebodies. Scheelite is associated with pyrrhotite and/or arsenopyrite, with minor chalcopyrite and other sulfide minerals; the late phyllic stage assemblages hosts Bi and Au mineralization. The fluid evolution included low-salinity moderate-temperature, moderate-pressure (˜370-390 °C, ˜800 bars) methane-dominated carbonic-aqueous fluids that formed post-skarn propylitic alteration assemblages. Then, at the phyllic stage, there has been an evolution from methane-dominated, moderate-temperature (330-360 °C), low-salinity (<12.3 wt% NaCl equiv.) fluids forming the early quartz-sericite-albite-arsenopyrite assemblage, through lower temperature (290-330 °C) methane-dominated, low-salinity (˜9-10 wt% NaCl equiv.) fluids forming the intermediate quartz-sericite-albite-scheelite-pyrrhotite assemblage, to yet lower temperature (245-320 °C) CO2-dominated carbonic-aqueous low-salinity (˜1-7 wt% NaCl equiv.) fluids forming the late quartz-sericite-sulfide-Bi-Au assemblage. Recurrent fluid immiscibility (phase separation) and cooling probably affected W solubility and promoted scheelite deposition. The stable isotope data support a sedimentary source of carbon (δ13Cfluid = ˜-21 to -10

  12. Geochemical modeling of magmatic gas scrubbing

    Directory of Open Access Journals (Sweden)

    B. Gambardella


    Full Text Available The EQ3/6 software package, version 7.2 was successfully used to model scrubbing of magmatic gas by pure water at 0.1 MPa, in the liquid and liquid-plus-gas regions. Some post-calculations were necessary to account for gas separation effects. In these post-calculations, redox potential was considered to be fixed by precipitation of crystalline a-sulfur, a ubiquitous and precocious process. As geochemical modeling is constrained by conservation of enthalpy upon water-gas mixing, the enthalpies of the gas species of interest were reviewed, adopting as reference state the liquid phase at the triple point. Our results confirm that significant emissions of highly acidic gas species (SO2(g, HCl(g, and HF(g are prevented by scrubbing, until dry conditions are established, at least locally. Nevertheless important outgassing of HCl(g can take place from acid, HCl-rich brines. Moreover, these findings support the rule of thumb which is generally used to distinguish SO2-, HCl-, and HF-bearing magmatic gases from SO2-, HCl-, and HF-free hydrothermal gases.

  13. Tourmaline orbicules in peraluminous monzogranites of Argentina: A study case of fluid-rock interaction between leucogranite and country-rock metasediments (United States)

    Lira, Raúl; Poklepovic, María F.


    Tourmaline orbicules hosted in peraluminous granites are documented worldwide. Seven occurrences were identified in Argentina. Petrography, mineral chemistry, whole-rock geochemistry mass balance and microthermometric studies were performed in orbicules formed at the cupola of a peraluminous A-type leucogranite (Los Riojanos pluton), as well as complementary investigation was achieved in other orbicules of similar geological setting. Mass balance computations in zoned orbicules consistently confirmed immobility of Si both in core and halo, immobility of K and little loss of Al during halo reactions. Elements gained and lost in the schorl-rich core are Fe, Al, Mg, Ti, Ba, Sr, Y and Zr, and Na, K, Rb and Nb, respectively; in the halo, K, Ba, Sr, Y, Zr and locally CaO, were gained, and Fe, Mg, Na, Al, Rb and Nb were lost. The schorl-rich core is enriched in LREE relative to the leucogranite host. A temperature-salinity plot from fluid inclusion data delineates a magmatic-meteoric mixing trend of diluting salinity with descending temperature. Computed δDH20 values from Los Riojanos orbicule schorl suggest magmatic and magmatic-meteoric mixed origins. In Los Riojanos, mass balance constraints suggest that Fe, Mg, Ba, Sr and metallic traces like Zn and V (±Pb) were most likely derived from country-rock schists and gneisses through fluid-rock exchange reactions. A late magmatic-, volatile-rich- fluid exsolution scenario for the formation of orbicules is envisaged. Schorl crystallization was likely delayed to the latest stages of leucogranite consolidation, not only favored by the high diffusivity of B2O3 preferentially partitioned into the exsolved aqueous-rich fluid, but also likely limited to the low availability of Fe and Mg from the scarce granitic biotite, and to the high F- content of the melt. The spatial confination of orbicules to the contact zone granite-metasediments suggests that orbicules were not formed until exsolved fluids reached the boundary with the

  14. Fluid inclusions in minerals associated to uranium mineralization in Jazida do Engenho (anomaly 09), Lagoa Real uranium province - Bahia, Brazil

    International Nuclear Information System (INIS)

    Souza, Aurelio da Silva de


    associated, at least in this Lagoa Real area. Otherwise, the presence of this fluid should be present in the mineral para genesis. Finally, the data from the Engenho deposit indicate the occurrence of fluids showing compositional variations in, at least, three different stages: magmatic pyroxene -metamorphic pyroxene associated to uranium -- albite (recristalized) associated to uranium. The place of the aqueous-carbonic fluid associated to previous albite is still unknown. (author)

  15. Fluids in the Siilinjärvi carbonatite complex, eastern Finland: Fluid inclusion evidence for the formation conditions of zircon and apatite

    Directory of Open Access Journals (Sweden)

    Poutiainen, M.


    Full Text Available In the studied zircon and apatite crystals, data recorded two different compositional types of fluid inclusions: Type 1 H2O-CO2, low salinity inclusions (XCO2 = 0.42 to 0.87; XNaCl = 0.001 to 0.005 with bulk densities of 0.73 to 0.87 g/cm3, and Type 2 H2O moderate salinity (XNaCl = 0.03 to 0.06 inclusions with densities of 0.83 to 1.02 g/cm3. The Type 1 inclusions are not present in apatite. In zircon, the observed fluid inclusion types occur in separate domains: around (Type 1 and outside (Type 2 the apparent core. Fluid inclusions are further subdivided into pseudosecondary and secondary inclusions. Using a combination of SEM-EDS, optical characteristics and crushing-stage, various daughter and captive minerals were identified. The fluid inclusion data suggest that the pseudosecondary Type 1 and Type 2 inclusions in zircon and apatite were trapped during the pre-emplacement evolution of the carbonatite at mid-crustal conditions (P≥4 kbar, T≥625°C. The Type 1 fluid was depleted in CO2, during crystal fractionation and cooling leading to a fluid phase enriched in water and alkalies. Fenitization was obviously induced by these saline aqueous fluids. During emplacement of the carbonatite to the present level, zircon phenocrysts were intensively fractured, some Type 1 inclusions were re-equilibrated, and multiphase Type 2 inclusions were trapped. It is assumed that all these inclusions in zircon and the pseudosecondary Type 2 inclusions in apatite have a magmatic origin. In apatite, calcite inclusions occur side-by-side with the secondary Type 2 inclusions. These calcites co-existed with the aqueous fluid during fracturing and metamorphic re-crystallization of apatites. Probably, this metamorphic fluid also is responsible for the transport and deposition of at least some of the calcite at low temperatures (200-350°C.

  16. Structural controls on the emission of magmatic carbon dioxide gas, Long Valley Caldera, USA (United States)

    Lucic, Gregor; Stix, John; Wing, Boswell


    We present a degassing study of Long Valley Caldera that explores the structural controls upon emissions of magmatic carbon dioxide gas. A total of 223 soil gas samples were collected and analyzed for stable carbon isotopes using a field-portable cavity ring-down spectrometer. This novel technique is flexible, accurate, and provides sampling feedback on a daily basis. Sampling sites included major and minor volcanic centers, regional throughgoing faults, caldera-related structures, zones of elevated seismicity, and zones of past and present hydrothermal activity. The classification of soil gases based on their δ13C and CO2 values reveals a mixing relationship among three end-members: atmospheric, biogenic, and magmatic. Signatures dominated by biogenic contributions (~4 vol %, -24‰) are found on the caldera floor, the interior of the resurgent dome, and areas associated with the Hilton Creek and Hartley Springs fault systems. With the introduction of the magmatic component (~100 vol %, -4.5‰), samples acquire mixing and hydrothermal signatures and are spatially associated with the central caldera and Mammoth Mountain. In particular, they are concentrated along the southern margin of the resurgent dome where the interplay between resurgence-related reverse faulting and a bend in the regional fault system has created a highly permeable fracture network, suitable for the formation of shallow hydrothermal systems. This contrasts with the south moat, where despite elevated seismicity, a thick sedimentary cover has formed an impermeable cap, inhibiting the ascent of fluids and gases to the surface.

  17. Fluid evolution and ore genesis of the Dalingshang deposit, Dahutang W-Cu ore field, northern Jiangxi Province, South China (United States)

    Peng, Ning-Jun; Jiang, Shao-Yong; Xiong, Suo-Fei; Pi, Dao-Hui


    The Dalingshang W-Cu deposit is located in the North section of the Dahutang ore field, northern Jiangxi Province, South China. Vein- and breccia-style tungsten-copper mineralization is genetically associated with Mesozoic S-type granitic rocks. Infrared and conventional microthermometric studies of both gangue and ore minerals show that the homogenization temperatures for primary fluid inclusions in wolframite ( 340 °C) are similar to those in scheelite ( 330 °C), but about 40 °C higher than those of apatite ( 300 °C) and generally 70 °C higher than those in coexisting quartz ( 270 °C). Laser Raman analysis identifies CH4 and N2 without CO2 in fluid inclusions in scheelite and coexisting quartz, while fluid inclusions in quartz of the sulfide stage have variable CO2 content. The ore-forming fluids overall are characterized by high- to medium-temperature, low-salinity, CH4, N2, and/or CO2-bearing aqueous fluids. Chalcopyrite, muscovite, and sphalerite are the most abundant solids recognized in fluid inclusions from different ores. The H-O-S-Pb isotope compositions favor a dominantly magmatic origin for ores and fluids, while some depleted δ34S values (- 14.4 to - 0.9‰) of sulfides from the sulfide stage are most likely produced by an increase of oxygen fugacity, possibly caused by inflow of oxidized meteoric waters. The microthermometric data also indicate that a simple cooling process formed early scheelite and wolframite. However, increasing involvement of meteoric waters and fluid mixing may trigger a successive deposition of base metal sulfides. Fluid-rock interaction was critical for scheelite mineralization as indicated by in-situ LA-ICP-MS analysis of trace elements in scheelite.

  18. Monitoring the State of the Magmatic Structures of Elbrus Volcano Based on Observation of Lithosphere Strains

    International Nuclear Information System (INIS)

    Milyukov, Vadim; Myasnikov, Andrey; Mironov, Alexey


    An analysis of crustal strain recorded by the Baksan laser interferometer revealed a shallow magma chamber in the structure of Elbrus Volcano (The Northern Caucasus, Russia). The analysis is based on estimation of parameters of magmatic structures resonant modes excited by teleseismic signals. The resonance parameters we have found were interpreted in the framework of contemporary models of magma resonators. The depth and dimension of the magma chamber, as well as the properties of the magma fluid were estimated. It was suggested the changing the magma state due to rising the intrachamber pressure

  19. Unraveling the dynamics of magmatic CO2 degassing at Mammoth Mountain, California (United States)

    Peiffer, Loïc; Wanner, Christoph; Lewicki, Jennifer L.


    The accumulation of magmatic CO2 beneath low-permeability barriers may lead to the formation of CO2-rich gas reservoirs within volcanic systems. Such accumulation is often evidenced by high surface CO2 emissions that fluctuate over time. The temporal variability in surface degassing is believed in part to reflect a complex interplay between deep magmatic degassing and the permeability of degassing pathways. A better understanding of the dynamics of CO2 degassing is required to improve monitoring and hazards mitigation in these systems. Owing to the availability of long-term records of CO2 emissions rates and seismicity, Mammoth Mountain in California constitutes an ideal site towards such predictive understanding. Mammoth Mountain is characterized by intense soil CO2 degassing (up to ∼1000 t d-1) and tree kill areas that resulted from leakage of CO2 from a CO2-rich gas reservoir located in the upper ∼4 km. The release of CO2-rich fluids from deeper basaltic intrusions towards the reservoir induces seismicity and potentially reactivates faults connecting the reservoir to the surface. While this conceptual model is well-accepted, there is still a debate whether temporally variable surface CO2 fluxes directly reflect degassing of intrusions or variations in fault permeability. Here, we report the first large-scale numerical model of fluid and heat transport for Mammoth Mountain. We discuss processes (i) leading to the initial formation of the CO2-rich gas reservoir prior to the occurrence of high surface CO2 degassing rates and (ii) controlling current CO2 degassing at the surface. Although the modeling settings are site-specific, the key mechanisms discussed in this study are likely at play at other volcanic systems hosting CO2-rich gas reservoirs. In particular, our model results illustrate the role of convection in stripping a CO2-rich gas phase from a rising hydrothermal fluid and leading to an accumulation of a large mass of CO2 (∼107-108 t) in a shallow

  20. Unravelling the sulphur isotope systematics of an alkaline magmatic province: implications for REE mineralization and exploration (United States)

    Hutchison, W.; Finch, A.; Boyce, A.; Friis, H.; Borst, A. M.; Horsburgh, N. J.


    Some of the world's best alkaline rare earth element (REE) deposits are formed in magmatic systems that are sealed (i.e., those that are autometasomatised and maintain reducing conditions). Conversely, in open systems where oxidizing fluids infiltrate, it is commonly assumed that REE are redistributed over a wider (less concentrated) zone. Sulphur isotope fractionation is sensitive to variations in temperature and redox, and, although sulphide minerals are relatively abundant in alkaline systems, there have been few attempts to test these hypotheses and develop a sulphur isotope proxy for alkaline metasomatism and formation of associated REE deposits. The Gardar Rift Province in southern Greenland was volcanically active in two periods between 1300 and 1100 Ma and is an ideal natural laboratory to explore sulphur isotope systematics because a near-complete alkaline magmatic lineage is exposed. We present new δ34S from across the province with a particular focus on three alkaline systems (Ilímaussaq, Motzfeldt and Ivigtût) that also host major REE deposits. Primitive mafic rocks from regional Gardar dykes and lavas have a restricted range of δ34S between 0 and 3 ‰ and fractional crystallization imparts no observable change in δ34S. In a few cases high-δ34S rocks (>15 ‰) occur when intrusive units have assimilated local sedimentary crust (δ34S = 25 ‰). Most δ34S variation takes place in the roof zones of alkaline intrusions during late-magmatic and hydrothermal stages, and we identify clear differences between the complexes. At Ilímaussaq, where the magmatic series is exceptionally reduced (below QFM buffer), roof zone δ34S remains narrow (0-3 ‰). At Motzfeldt, a more open oxidizing roof zone (MH buffer), δ34S ranges from -12 ‰ in late-stage fluorite veins to +12 ‰ where local crust has been assimilated. Ivigtût is intermediate between these end-members varying between -5 to +5 ‰. The δ34S variations primarily relate to temperature and

  1. Removing sulphur oxides from a fluid stream (United States)

    Katz, Torsten; Riemann, Christian; Bartling, Karsten; Rigby, Sean Taylor; Coleman, Luke James Ivor; Lail, Marty Alan


    A process for removing sulphur oxides from a fluid stream, such as flue gas, comprising: providing a non-aqueous absorption liquid containing at least one hydrophobic amine, the liquid being incompletely miscible with water; treating the fluid stream in an absorption zone with the non-aqueous absorption liquid to transfer at least part of the sulphur oxides into the non-aqueous absorption liquid and to form a sulphur oxide-hydrophobic amine-complex; causing the non-aqueous absorption liquid to be in liquid-liquid contact with an aqueous liquid whereby at least part of the sulphur oxide-hydrophobic amine-complex is hydrolyzed to release the hydrophobic amine and sulphurous hydrolysis products, and at least part of the sulphurous hydrolysis products is transferred into the aqueous liquid; separating the aqueous liquid from the non-aqueous absorption liquid. The process mitigates absorbent degradation problems caused by sulphur dioxide and oxygen in flue gas.

  2. Laser microprobe analyses of Cl, Br, I, and K in fluid inclusions: Implications for sources of salinity in some ancient hydrothermal fluids (United States)

    Böhlke, J.K.; Irwin, J.J.


    The relative concentrations of Cl, Br, I, and K in fluid inclusions in hydrothermal minerals were measured by laser microprobe noble gas mass spectrometry on irradiated samples containing 10−10 to 10−8 L of fluid. Distinctive halogen signatures indicate contrasting sources of fluid salinity in fluid inclusions from representative “magmatic” (St. Austell), “metamorphic” (Alleghany), and “geothermal” (Creede, Salton Sea) aqueous systems. Br/Cl mol ratios are lowest at Salton Sea (0.27–0.33 × 10−3), where high salinities are largely due to halite dissolution; intermediate at St. Austell (0.85 × 10−3), possibly representative of magmatic volatiles; and highest (near that of seawater) at Creede (1.5–2.1 × 10−3) and Alleghany (1.2–2.4 × 10−3), where dissolved halogens probably were leached from volcanic and (or) nonevaporitic sedimentary rocks. IC1">IC1 mol ratios are lowest (near that of seawater) at Creede (1–14 × 10−6), possibly because organisms scavenged I during low temperature recharge; intermediate at Salton Sea (24–26 × 10−6) and St. Austell (81× 10−6); and highest at Alleghany (320–940 × 10−6), probably because the fluids interacted with organic-rich sediments at high temperatures before being trapped. KCl">KCl mol ratios indicate disequilibrium with respect to hypothetical feldspathic alkali-Al-silicate mineral buffers at fluid inclusion trapping temperatures at Creede, and large contributions of (Na, K)-bicarbonate to total fluid ionic strength at Alleghany. Significant variations in Cl/Br/I/K ratios among different fluid inclusion types are correlated with previously documented mineralization stages at Creede, and with the apparent oxidation state of dissolved carbon at Alleghany. The new data indicate that Cl/ Br/I ratios in hydrothermal fluid inclusions vary by several orders of magnitude, as they do in modern surface and ground waters. This study demonstrates that halogen signatures of fluid inclusions

  3. Drilling to investigate processes in active tectonics and magmatism (United States)

    Shervais, J.; Evans, J.; Toy, V.; Kirkpatrick, J.; Clarke, A.; Eichelberger, J.


    Coordinated drilling efforts are an important method to investigate active tectonics and magmatic processes related to faults and volcanoes. The US National Science Foundation (NSF) recently sponsored a series of workshops to define the nature of future continental drilling efforts. As part of this series, we convened a workshop to explore how continental scientific drilling can be used to better understand active tectonic and magmatic processes. The workshop, held in Park City, Utah, in May 2013, was attended by 41 investigators from seven countries. Participants were asked to define compelling scientific justifications for examining problems that can be addressed by coordinated programs of continental scientific drilling and related site investigations. They were also asked to evaluate a wide range of proposed drilling projects, based on white papers submitted prior to the workshop. Participants working on faults and fault zone processes highlighted two overarching topics with exciting potential for future scientific drilling research: (1) the seismic cycle and (2) the mechanics and architecture of fault zones. Recommended projects target fundamental mechanical processes and controls on faulting, and range from induced earthquakes and earthquake initiation to investigations of detachment fault mechanics and fluid flow in fault zones. Participants working on active volcanism identified five themes: the volcano eruption cycle; eruption sustainability, near-field stresses, and system recovery; eruption hazards; verification of geophysical models; and interactions with other Earth systems. Recommended projects address problems that are transferrable to other volcanic systems, such as improved methods for identifying eruption history and constraining the rheological structure of shallow caldera regions. Participants working on chemical geodynamics identified four major themes: large igneous provinces (LIPs), ocean islands, continental hotspot tracks and rifts, and

  4. Non-aqueous slurries used as thickeners

    Energy Technology Data Exchange (ETDEWEB)

    Hatfield, J C


    A non-aqueous slurry is described that is suitable for use as a thickener or viscosifier in oil or gas drilling, fracturing, flow diversion completion or workover fluids. The slurry comprises a water-soluble cellulose ether polymer, a water-insoluble liquid hydrocarbon, a non-ionic surfactant having an HLB of from 7 to 14, and an organo modified clay. There also is described a process for thickening or viscosifying a drilling, fracturing, flow diversion, completion or workover fluid. The use of the slurry prevents bumping during addition to aqueous fluids. (27 claims)

  5. The physical hydrology of magmatic-hydrothermal systems: High-resolution 18O records of magmatic-meteoric water interaction from the Yankee Lode tin deposit (Mole Granite, Australia) (United States)

    Fekete, Szandra; Weis, Philipp; Driesner, Thomas; Heinrich, Christoph A.; Baumgartner, Lukas; Bouvier, Anne-Sophie


    Magmatic-hydrothermal ore deposits are important economic Cu, Au, Mo and Sn resources (Sillitoe, 2010, Kesler, 1994). The ore formation is a result of superimposed enrichment processes and metals can precipitate due to fluid-rock interaction and/or temperature drop caused by convection or mixing with meteoric fluid (Heinrich and Candela 2014). Microthermometry and LA-ICP MS trace element analyses of fluid inclusions of a well-characterized quartz sample from the Yankee Lode quartz-cassiterite vein deposit (Mole Granite, Australia) suggest that tin precipitation was driven by dilution of hot magmatic water by meteoric fluids (Audétat et al.1998). High resolution in situ oxygen isotope measurements of quartz have the potential to detect changing fluid sources during the evolution of a hydrothermal system. We analyzed the euhedral growth zones of this previously well-studied quartz sample. Growth temperatures are provided by Audétat et al. (1998) and Audétat (1999). Calculated δ 18O values of the quartz- and/or cassiterite-precipitating fluid show significant variability through the zoned crystal. The first and second quartz generations (Q1 and Q2) were precipitated from a fluid of magmatic isotopic composition with δ 18O values of ˜ 8 - 10 ‰. δ 18O values of Q3- and tourmaline-precipitating fluids show a transition from magmatic δ 18O values of ˜ 8 ‰ to ˜ -5 ‰. The outermost quartz-chlorite-muscovite zone was precipitated from a fluid with a significant meteoric water component reflected by very light δ 18O values of about -15 ‰ which is consistent with values found by previous studies (Sun and Eadington, 1987) using conventional O-isotope analysis of veins in the distal halo of the granite intrusion. Intense incursion of meteoric water during Q3 precipitation (light δ 18O values) agrees with the main ore formation event, though the first occurrence of cassiterite is linked to Q2 precipitating fluid with magmatic-like isotope signature. This

  6. Experimental Investigation of Biotite-Rich Schist Reacting with B-Bearing Fluids at Upper Crustal Conditions and Correlated Tourmaline Formation

    Directory of Open Access Journals (Sweden)

    Andrea Orlando


    Full Text Available Fluid–rock interaction experiments between a biotite-rich schist (from Mt. Calamita Formation, Elba Island, Italy and B-bearing aqueous fluids were carried out at 500–600 °C and 100–130 MPa. The experiments have been carried out in order to reproduce the reaction, which would have produced tourmalinisation of the biotite schist, supposedly by circulation of magmatic fluids issued from leucogranitic dykes. The reacting fluids were either NaCl-free or NaCl-bearing (20 wt % aqueous solutions, with variable concentration of H3BO3 (0.01–3.2 M. The experimental results show that tourmaline (belonging to the alkali group crystallise under high-temperature and upper crustal conditions (500–600 °C, 100–130 MPa when H3BO3 concentration in the system is greater than 1.6 M. The composition of tourmaline is either dravitic (Mg-rich or schorlitic (Fe-rich, depending if an NaCl-bearing or NaCl-free aqueous solution is used. In the first case, a significant amount of Fe released from biotite dissolution remains in the Cl-rich solution resulting from the experiment. By contrast, when pure water is used, Na/K exchange in feldspars makes Na available for tourmaline crystallisation. The high concentration of Fe in the residual fluid has an important metallogenic implication because it indicates that the interaction between the saline B-rich fluid of magmatic derivation and biotite-rich schists, besides producing tourmalinisation, is capable of mobilising significant amounts of Fe. This process could have produced, in part or totally, the Fe deposits located close to the quartz–tourmaline veins and metasomatic bodies of the Mt. Calamita Formation. Moreover, the super-hot reservoir that likely occurs in the deepest part of the Larderello–Travale geothermal field would also be the site of an extensive reaction between the B-rich fluid and biotite-bearing rocks producing tourmaline. Thus, tourmaline occurrence can be a useful guide during deep

  7. Moho and magmatic underplating in continental lithosphere

    DEFF Research Database (Denmark)

    Thybo, Hans; Artemieva, Irina M.


    interacts with the surrounding crustal rocks which leads to smearing of geophysical signals from the underplated material. In terms of processes, there is no direct discriminator between the traditional concept of underplated material and lower crustal magmatic intrusions in the form of batholiths and sill......Underplating was originally proposed as the process of magma ponding at the base of the crust and was inferred from petrologic considerations. This process not only may add high density material to the deep crust, but also may contribute low density material to the upper parts of the crust by magma...... fractionation during cooling and solidification in the lower crust. Separation of the low density material from the high-density residue may be a main process of formation of continental crust with its characteristic low average density, also during the early evolution of the Earth. Despite the assumed...

  8. Carbonate reservoirs modified by magmatic intrusions in the Bachu area, Tarim Basin, NW China

    Directory of Open Access Journals (Sweden)

    Kang Xu


    Full Text Available Oil and gas exploration in carbonate rocks was extremely successful in recent years in the Ordovician in Tarim Basin, NW China. Here, we investigate the carbonate reservoirs in the Bachu area of the Tarim Basin through petrological and geochemical studies combined with oil and gas exploration data. Geochemical analysis included the major, trace, and rare earth elements; fluid inclusion thermometry; clay mineral characterization; and carbon and oxygen isotopes of the carbonate rocks. Homogenization temperatures of the fluid inclusions of Well He-3 in the Bachu area indicate three groups, 60–80 °C, 90–130 °C, and 140–170 °C, and suggest that the carbonate rocks experienced modification due to heating events. The porosity in the reservoir is defined by fractures and secondary pores, and there is a notable increase in the porosity of the carbonate reservoirs in proximity to magmatic intrusion, particularly approximately 8–10 m from the intrusive rocks. The development of secondary pores was controlled by lithofacies and corrosion by various fluids. We identify supercritical fluids with high density (138.12–143.97 mg/cm3 in the Bachu area. The negative correlations of δ13C (−2.76‰ to −0.97‰ and δ18O (−7.91‰ to −5.07‰ suggest that the carbonate rocks in the study area were modified by high-salinity hydrothermal fluid. The formation of clay minerals, such as illite and montmorillonite, caused a decrease in porosity. Our study demonstrates the effect of magmatic intrusions in modifying the reservoir characteristics of carbonate rocks and has important implications for oil and gas exploration.

  9. Efficient cooling of rocky planets by intrusive magmatism (United States)

    Lourenço, Diogo L.; Rozel, Antoine B.; Gerya, Taras; Tackley, Paul J.


    The Earth is in a plate tectonics regime with high surface heat flow concentrated at constructive plate boundaries. Other terrestrial bodies that lack plate tectonics are thought to lose their internal heat by conduction through their lids and volcanism: hotter planets (Io and Venus) show widespread volcanism whereas colder ones (modern Mars and Mercury) are less volcanically active. However, studies of terrestrial magmatic processes show that less than 20% of melt volcanically erupts, with most melt intruding into the crust. Signatures of large magmatic intrusions are also found on other planets. Yet, the influence of intrusive magmatism on planetary cooling remains unclear. Here we use numerical magmatic-thermo-mechanical models to simulate global mantle convection in a planetary interior. In our simulations, warm intrusive magmatism acts to thin the lithosphere, leading to sustained recycling of overlying crustal material and cooling of the mantle. In contrast, volcanic eruptions lead to a thick lithosphere that insulates the upper mantle and prevents efficient cooling. We find that heat loss due to intrusive magmatism can be particularly efficient compared to volcanic eruptions if the partitioning of heat-producing radioactive elements into the melt phase is weak. We conclude that the mode of magmatism experienced by rocky bodies determines the thermal and compositional evolution of their interior.

  10. Imaging the magmatic system of Mono Basin, California with magnetotellurics in three--dimensions (United States)

    Peacock, Jared R.; Mangan, Margaret T.; McPhee, Darcy K.; Ponce, David A.


    A three–dimensional (3D) electrical resistivity model of Mono Basin in eastern California unveils a complex subsurface filled with zones of partial melt, fluid–filled fracture networks, cold plutons, and regional faults. In 2013, 62 broadband magnetotelluric (MT) stations were collected in an array around southeastern Mono Basin from which a 3D electrical resistivity model was created with a resolvable depth of 35 km. Multiple robust electrical resistivity features were found that correlate with existing geophysical observations. The most robust features are two 300 ± 50 km3 near-vertical conductive bodies (3–10 Ω·m) that underlie the southeast and north-eastern margin of Mono Craters below 10 km depth. These features are interpreted as magmatic crystal–melt mush zones of 15 ± 5% interstitial melt surrounded by hydrothermal fluids and are likely sources for Holocene eruptions. Two conductive east–dipping structures appear to connect each magma source region to the surface. A conductive arc–like structure (resistivity (200 Ω·m) suggestive of a cooled connection. A third, less constrained conductive feature (4–10 Ω·m) 15 km deep extending to 35 km is located west of Mono Craters near the eastern front of the Sierra Nevada escarpment, and is coincident with a zone of sporadic, long–period earthquakes that are characteristic of a fluid-filled (magmatic or metamorphic) fracture network. A resistive feature (103–105 Ω·m) located under Aeolian Buttes contains a deep root down to 25 km. The eastern edge of this resistor appears to structurally control the arcuate shape of Mono Craters. These observations have been combined to form a new conceptual model of the magmatic system beneath Mono Craters to a depth of 30 km.

  11. Shallow magmatic degassing into the hydrothermal system of Copahue, Argentina (United States)

    Varekamp, J.; Ouimette, A.; Kreulen, R.; Delpino, D.; Bermudez, A.


    Copahue volcano has a crater lake and acid hot springs that discharge into the Rio Agrio river system. These fluids are very concentrated (up to 6 percent sulfate), rich in rock-forming elements (up to 2000 ppm Mg) and small spheres of native sulfur float in the crater lake. The stable isotope composition of the waters (delta 18O =-2.1 to + 3.6 per mille; delta D = -49 to -26 per mille) indicates that the hot spring waters are at their most concentrated about 70 percent volcanic brine and 30 percent glacial meltwater. The crater lake waters have similar mixing proportions but added isotope effects from intense evaporation. Further dilution of the waters in the Rio Agrio gives values closer to local meteoric waters (delta 18O = -11 per mille; delta D = -77 per mille), whereas evaporation in closed ponds led to very heavy water (up to delta 18O = +12 per mille). The delta 34S value of dissolved sulfate is +14.2 per mille, whereas the native sulfur has values of -8.2 to -10.5 per mille. The heavy sulfate probably formed when SO2 disproportionated into bisulfate and native sulfur. We measured the sulfate fluxes in the Rio Agrio, and from these flux values and the stoichiometry of the disproportionation reaction we calculated the rate of liquid sulfur storage inside the volcano (6000 m3/year). During the eruptions of 1995/2000, large amounts of that stored liquid sulfur were ejected as pyroclastic sulfur. The calculated rate of rock dissolution (from rock- forming element fluxes in the Rio Agrio) suggests that the void space generated by rock dissolution is largely filled by native sulfur. The isotopic signature of the magmatic sulfur can be reconstituted at about +7 per mille, which is a source signature with superposed effects of shallow degassing. Lead isotope and 129Iodine data from the fluids indicate that subducted components may have played a role in the Copahue magma formation. Primary glass inclusions in plagioclase and olivine have 1110-1670 ppm Cl, 90-400 ppm

  12. The evolution of pegmatite-hosted Sn-W mineralization at Nong Sua, Thailand: Evidence from fluid inclusions and stable isotopes (United States)

    Linnen, Robert L.; Williams-Jones, Anthony E.


    The Nong Sua aplite-pergmatite complex contains two dominant styles of Sn-W-Ta-Nb mineralization. Cassiterite ± Nb-Ta-Ti oxide minerals are disseminated in the pegmatite, and cassiterite and wolframite are hosted by quartz-tourmaline veins which are contained solely within aplite. The orthomagmatic fluid at Nong Sua is preserved as primary fluid inclusions in the cores of magmatic garnet crystals that have high tin concentrations (garnet cores without fluid inclusions do not contain elevated tin concentrations). These fluid inclusions have a composition of 3 wt% NaCl eq. The low salinity suggests that, at vapor saturation, tin was partitioned in favour of the melt, which allowed cassiterite to initially crystallize directly from the melt. Primary, pseudosecondary, and secondary fluid inclusions in cassiterite, tourmaline, and quartz record three-component mixing of the orthomagmatic fluid with high salinity aqueous and with CO 2-rich fluids. The orthomagmatic water is interpreted to have had δ 18O value of +8.7 to +9.9 per mil and a δD value of -72 to -78 per mil from δ18O analyses of muscovite and quartz, and δD of muscovite. The δ18O composition of muscovite decreased from 10.1 to 8.0 per mil and δD increased from - 106 to - 85 per mil, from the magmatic to the hydrothermal stages of pegmatite evolution. These changes are consistent with an influx of metamorphic fluids or evolved meteoric waters. We consider that the saturation of the melt with vapor caused the pressure in the pegmatite to rise to approximately 3.8 kbar, at a temperature of 650°C. Fluid overpressure caused the aplite to fracture, and veins to form from fluids which migrated into the fracture-induced low pressure zones. This event can be modeled by an isothermal decompression to 2.7 kbar. Cassiterite deposition was probably controlled by increasing fO 2, whereas wolframite deposition resulted from the mixing of W-rich with Fe-Mn-rich fluids. In both cases decompression, cooling, and

  13. Possible genetic link between I-type granite and orogenic gold deposits in Egypt (metamorphic-magmatic interaction?) (United States)

    Abd El Monsef, Mohamed


    The orogenic gold deposits are a distinctive type of deposits that revealed unique temporal and spatial association with an orogeny. Where, the system of gold veins and related ore minerals was confined to hydrothermal solutions formed during compressional to transpressional deformation processes at convergent plate margins in accretionary and collisional orogens, with the respect to ongoing deep-crustal, subduction-related thermal processes. In Egypt, most of vein-type and dyke-type gold mineralization are restricted to granitic rocks or at least near of granitic intrusion that seems to have had an important influence on gold mineralization. Shear zone-related, mesothermal gold deposits of Fatira and Gidami mines in the northern Eastern Desert of Egypt are found within granitic bodies or at the contact between granites and metavolcanic rocks. The hosting-granitic rocks in Fatira and Gidami areas are mainly of granodioritic composition (I-Type granite) which is related to calc-alkaline magmatic series. However, Fatira granitoids were developed within island arc tectonic settings related to mature island arc system (Late-orogenic stage), at relatively low temperature (around 660° C) and medium pressure between (5 - 10 Kbar). On the other hand, Gidami granitoids were developed during the collision stage in continental arc regime related to active continental margin (Syn-orogeny), which were crystallized at relatively high temperature (700-720° C) and low pressure (around 0.1 Kbar). The ore mineralogy includes pyrite, chalcopyrite, sphalerite, covellite, ilmenite, goethite ± pyrrhotite ± pentlandite ± galena ± molybdenite. Native gold is detected only in Gidami mineralization as small inclusions within pyrite and goethite or as tiny grains scattered within quartz vein (in close proximity to the sulfides). In Fatira deposits, it is detected only by microprobe analysis within the crystal lattice of pyrite and jarosite. Fluid inclusions study for the mineralized

  14. 3D Volumetric Analysis of Fluid Inclusions Using Confocal Microscopy (United States)

    Proussevitch, A.; Mulukutla, G.; Sahagian, D.; Bodnar, B.


    Fluid inclusions preserve valuable information regarding hydrothermal, metamorphic, and magmatic processes. The molar quantities of liquid and gaseous components in the inclusions can be estimated from their volumetric measurements at room temperatures combined with knowledge of the PVTX properties of the fluid and homogenization temperatures. Thus, accurate measurements of inclusion volumes and their two phase components are critical. One of the greatest advantages of the Laser Scanning Confocal Microscopy (LSCM) in application to fluid inclsion analsyis is that it is affordable for large numbers of samples, given the appropriate software analysis tools and methodology. Our present work is directed toward developing those tools and methods. For the last decade LSCM has been considered as a potential method for inclusion volume measurements. Nevertheless, the adequate and accurate measurement by LSCM has not yet been successful for fluid inclusions containing non-fluorescing fluids due to many technical challenges in image analysis despite the fact that the cost of collecting raw LSCM imagery has dramatically decreased in recent years. These problems mostly relate to image analysis methodology and software tools that are needed for pre-processing and image segmentation, which enable solid, liquid and gaseous components to be delineated. Other challenges involve image quality and contrast, which is controlled by fluorescence of the material (most aqueous fluid inclusions do not fluoresce at the appropriate laser wavelengths), material optical properties, and application of transmitted and/or reflected confocal illumination. In this work we have identified the key problems of image analysis and propose some potential solutions. For instance, we found that better contrast of pseudo-confocal transmitted light images could be overlayed with poor-contrast true-confocal reflected light images within the same stack of z-ordered slices. This approach allows one to narrow

  15. Magmatic intrusions in the lunar crust (United States)

    Michaut, C.; Thorey, C.


    The lunar highlands are very old, with ages covering a timespan between 4.5 to 4.2 Gyr, and probably formed by flotation of light plagioclase minerals on top of the lunar magma ocean. The lunar crust provides thus an invaluable evidence of the geological and magmatic processes occurring in the first times of the terrestrial planets history. According to the last estimates from the GRAIL mission, the lunar primary crust is particularly light and relatively thick [1] This low-density crust acted as a barrier for the dense primary mantle melts. This is particularly evident in the fact that subsequent mare basalts erupted primarily within large impact basin: at least part of the crust must have been removed for the magma to reach the surface. However, the trajectory of the magma from the mantle to the surface is unknown. Using a model of magma emplacement below an elastic overlying layer with a flexural wavelength Λ, we characterize the surface deformations induced by the presence of shallow magmatic intrusions. We demonstrate that, depending on its size, the intrusion can show two different shapes: a bell shape when its radius is smaller than 4 times Λ or a flat top with small bended edges if its radius is larger than 4 times Λ[2]. These characteristic shapes for the intrusion result in characteristic deformations at the surface that also depend on the topography of the layer overlying the intrusion [3].Using this model we provide evidence of the presence of intrusions within the crust of the Moon as surface deformations in the form of low-slope lunar domes and floor-fractured craters. All these geological features have morphologies consistent with models of magma spreading at depth and deforming an overlying elastic layer. Further more,at floor-fractured craters, the deformation is contained within the crater interior, suggesting that the overpressure at the origin of magma ascent and intrusion was less than the pressure due to the weight of the crust removed by

  16. Subduction-like fluids in the genesis of Mt. Etna magmas: evidence from boron isotopes and fluid mobile elements (United States)

    Tonarini, Sonia; Armienti, Pietro; D'Orazio, Massimo; Innocenti, Fabrizio


    New whole-rock B, Sr, Nd isotope ratios and 87Sr/ 86Sr on clinopyroxenes have been collected to study the enrichment of fluid mobile elements (FMEs) observed in Mt. Etna volcanics. Etna volcano, one of the most active in the world, is located in an extremely complex tectonic context at the boundary between colliding African and European plates. The analytical work focuses on current (1974-1998) and historic (1851-1971) eruptive activity, including some key prehistoric lavas, in order to interpret the secular shift of its geochemical signature to more alkaline compositions. Boron is used as a tool to unravel the role of fluids in the genesis of magmas, revealing far-reaching consequences, beyond the case study of Mt. Etna. Small variations are observed in δ 11B (-3.5 to -8.0‰), 87Sr/ 86Sr (0.70323-0.70370), and 143Nd/ 144Nd (0.51293-0.51287). Moreover, temporal evolution to higher δ 11B and 87Sr/ 86Sr, and to lower 143Nd/ 144Nd, is observed in the current activity, defining a regular trend. Sr isotopic equilibrium between whole-rock and clinopyroxene pairs indicates the successive introduction of three distinct magma types into the Etna plumbing system over time; these are characterized by differing degrees of FME enrichment. In addition, certain lavas exhibit evidence for country rock assimilation, magma-fluid interaction, or magma mixing in the shallow feeding system; at times these processes apparently lowered magmatic δ 11B and/or induced Sr isotopic disequilibrium between whole rock and clinopyroxene. The regular increase of δ 11B values is correlated with Nb/FME and 87Sr/ 86Sr ratios; these correlations are consistent with simple mixing between the mantle source and aqueous fluids derived from nearby Ionian slab. The best fit of Mt. Etna data is obtained using an enriched-MORB mantle source and a fluid phase with δ 11B of about -2‰ and 87Sr/ 86Sr of 0.708. We argue that the slab window generated by differential roll-back of subducting Ionian

  17. Early Paleozoic dioritic and granitic plutons in the Eastern Tianshan Orogenic Belt, NW China: Constraints on the initiation of a magmatic arc in the southern Central Asian Orogenic Belt (United States)

    Du, Long; Long, Xiaoping; Yuan, Chao; Zhang, Yunying; Huang, Zongying; Sun, Min; Zhao, Guochun; Xiao, Wenjiao


    Early Paleozoic dioritic and granitic plutons in the Eastern Tianshan Orogenic Belt (ETOB) have been studied in order to constraint the initiation of a magmatic arc formed in this region. Zircon U-Pb dating indicates that two dioritic plutons in the northern ETOB were generated in the Late Ordovician (452 ± 4 Ma) and the Early Silurian (442 ± 3 Ma), respectively. Diorites from the two plutons are characterized by enrichments in large ion lithophile elements (LILE) and highly incompatible elements, with depletions in high field strength elements (HSFE) displaying typical geochemical features of a subduction-related origin. They have positive εNd(t) values (+5.08-+6.58), relatively young Nd model ages (TDM = 0.71-1.08 Ga), with Ta/Yb (0.05-0.09) and Nb/Ta ratios (12.06-15.19) similar to those of depleted mantle, suggesting a juvenile mantle origin. Their high Ba/La (13.3-35.9), low Th/Yb (0.72-2.02), and relatively low Ce/Th (4.57-14.7) and Ba/Th (47.8-235) ratios indicate that these diorites were probably produced by partial melting of a depleted mantle wedge metasomatized by both subducted sediment-derived melts and slab-derived aqueous fluids. Zircon U-Pb dating of a granitic pluton in the northern ETOB yielded a Late Ordovician intrusion age of 447 ± 5 Ma. Granites from this pluton show calc-alkaline compositions with geochemical characteristics of I-type granites. They also show positive εNd(t) values (+6.49-+6.95) and young Nd model ages (TDM = 0.69-0.87 Ga), indicating that the granites were most likely derived from juvenile lower crust. Our new dating results on the dioritic and granitic plutons suggest that arc-type magmatism in the northern ETOB began prior to or at the Late Ordovician (452-442 Ma). In addition, north-dipping subduction of the Kangguertage oceanic lithosphere may account for the arc-type magmatism and the geodynamic process of the ETOB in the Early Paleozoic.

  18. Drilling to investigate processes in active tectonics and magmatism


    J. Shervais; J. Evans; V. Toy; J. Kirkpatrick; A. Clarke; J. Eichelberger


    Coordinated drilling efforts are an important method to investigate active tectonics and magmatic processes related to faults and volcanoes. The US National Science Foundation (NSF) recently sponsored a series of workshops to define the nature of future continental drilling efforts. As part of this series, we convened a workshop to explore how continental scientific drilling can be used to better understand active tectonic and magmatic processes. The workshop, held in Park C...

  19. Formation of continental crust by intrusive magmatism (United States)

    Rozel, A. B.; Golabek, G. J.; Jain, C.; Tackley, P. J.; Gerya, T.


    How were the continents formed in the Earth? No global numerical simulation of our planet ever managed to generate continental material self-consistently. In the present study, we show that the latest developments of the convection code StagYY enable to estimate how to produce the early continents, more than 3 billion years ago. In our models, melting of pyrolitic rocks generates a basaltic melt and leaves behind a depleted solid residue (a harzburgite). The melt generated in the mantle is transported to the surface. Only basaltic rocks melting again can generate continental crust. Should the basaltic melt always reach the open air and cool down? Should the melt be intruded warm in the pre-existing crust? The present study shows that both processes have to be considered to produce continents. Indeed, granitoids can only be created in a tight window of pressure-temperature. If all basalt is quickly cooled by surface volcanism, the lithosphere will be too cold. If all basalt is intruded warm below the crust then the lithosphere will be too warm. The key is to have both volcanism and plutonism (intrusive magmatism) to reach the optimal temperature and form massive volumes of continental material.

  20. Magnetic movement of biological fluid droplets

    International Nuclear Information System (INIS)

    Garcia, Antonio A.; Egatz-Gomez, Ana; Lindsay, Solitaire A.; Dominguez-Garcia, P.; Melle, Sonia; Marquez, Manuel; Rubio, Miguel A.; Picraux, S.T.; Yang, Dongqing; Aella, P.; Hayes, Mark A.; Gust, Devens; Loyprasert, Suchera; Vazquez-Alvarez, Terannie; Wang, Joseph


    Magnetic fields can be used to control the movement of aqueous drops on non-patterned, silicon nanowire superhydrophobic surfaces. Drops of aqueous and biological fluids are controlled by introducing magnetizable carbonyl iron microparticles into the liquid. Key elements of operations such as movement, coalescence, and splitting of water and biological fluid drops, as well as electrochemical measurement of an analyte are demonstrated. Superhydrophobic surfaces were prepared using vapor-liquid-solid (VLS) growth systems followed by coating with a perfluorinated hydrocarbon molecule. Drops were made from aqueous and biological fluid suspensions with magnetizable microparticle concentrations ranging from 0.1 to 10 wt%

  1. A geochemical approach to distinguishing competing tectono-magmatic processes preserved in small eruptive centres (United States)

    McGee, Lucy E.; Brahm, Raimundo; Rowe, Michael C.; Handley, Heather K.; Morgado, Eduardo; Lara, Luis E.; Turner, Michael B.; Vinet, Nicolas; Parada, Miguel-Ángel; Valdivia, Pedro


    Small eruptive centres (SECs) representing short-lived, isolated eruptions are effective samples of mantle heterogeneity over a given area, as they are generally of basaltic composition and show evidence of little magmatic processing. This is particularly powerful in volcanic arcs where the original melting process generating stratovolcanoes is often obscured by additions from the down-going slab (fluids and sediments) and the overlying crust. The Pucón area of southern Chile contains active and dormant stratovolcanoes, Holocene, basaltic SECs and an arc-scale strike-slip fault (the Liquiñe Ofqui Fault System: LOFS). The SECs show unexpected compositional heterogeneity considering their spatial proximity. We present a detailed study of these SECs combining whole rock major and trace element concentrations, U-Th isotopes and olivine-hosted melt inclusion major element and volatile contents to highlight the complex inter-relations in this small but active area. We show that heterogeneity preserved at individual SECs relates to different processes: some start in the melting region with the input of slab-derived fluids, whilst others occur later in a centre's magmatic history with the influence of crustal contamination prior to olivine crystallisation. These signals are deduced through the combination of the different geochemical tools used in this study. We show that there is no correlation between composition and distance from the arc front, whilst the local tectonic regime has an effect on melt composition: SECs aligned along the LOFS have either equilibrium U-Th ratios or small Th-excesses instead of the large—fluid influenced—U-excesses displayed by SECs situated away from this feature. One of the SECs is modelled as being generated from fluid-enriched depleted mantle, a source which it may share with the stratovolcano Villarrica, whilst another SEC with abundant evidence of crustal contamination may share its plumbing system with its neighbouring

  2. Intraplate mafic magmatism: New insights from Africa and N. America (United States)

    Ebinger, C. J.; van der Lee, S.; Tepp, G.; Pierre, S.


    Plate tectonic concepts consider that continental interiors are stable, with magmatism and strain localized to plate boundaries. We re-evaluate the role of pre-existing and evolving lithospheric heterogeneities in light of perspectives afforded by surface to mantle results from active and ancient rift zones in Africa and N. America. Our process-oriented approach addresses the localization of strain and magmatism and stability of continental plate interiors. In both Africa and N. America, geophysical imaging and xenolith studies reveal that thick, buoyant, and chemically distinct Archaean cratons with deep roots may deflect mantle flow, and localize magmatism and strain over many tectonic cycles. Studies of the Colorado Plateau and East African rift reveal widespread mantle metasomatism, and high levels of magma degassing along faults and at active volcanoes. The volcanoes and magmatic systems show a strong dependence on pre-existing heterogeneities in plate structure. Syntheses of the EarthScope program ishow that lateral density contrasts and migration of volatiles that accumulated during subduction can refertilize mantle lithosphere, and enable volatile-rich magmatism beneath relatively thick continental lithosphere. For example, the passive margin of eastern N. America shows uplift and magmatism long after the onset of seafloor spreading, demonstrating the dynamic nature of coupling between the lithosphere, asthenosphere, and deeper mantle. As demonstrated by the East African Rift, the Mid-Continent Rift, and other active and ancient rift zones, the interiors of continents, including thick, cold Archaean cratons are not immune to mafic magmatism and tectonism. Recent studies in N. America and Africa reveal ca. 1000 km-wide zones of dynamic uplift, low upper mantle velocities, and broadly distributed strain. The distribution of magmatism and volatile release, in combination with geophysical signals, indicates a potentially convective origin for widespread

  3. Physical processes and effects of magmatism in the Yucca Mountain region

    International Nuclear Information System (INIS)

    Valentine, G.A.; Crowe, B.M.; Perry, F.V.


    This paper describes initial studies related to the effects of volcanism on performance of the proposed Yucca Mountain radioactive waste repository, and to the general processes of magmatism in the Yucca Mountain region. Volcanism or igneous activity can affect the repository performance by ejection of waste onto the earth's surface (eruptive effects), or by subsurface effects of hydrothermal processes and altered hydrology if an intrusion occurs within the repository block. Initial, conservative calculations of the volume of waste that might be erupted during a small-volume basaltic eruption (such as those which occurred in the Yucca Mountain region) indicate that regulatory limits might be exceeded. Current efforts to refine these calculations, based upon field studies at analog sites, are described. Studies of subsurface effects are just beginning, and are currently focused on field studies of intrusion properties and contact metamorphism at deeply eroded analog sites. General processes of magmatism are important for providing a physical basis for predictions of future volcanic activity. Initial studies have focused on modeling basaltic magma chambers in conjunction with petrographic and geochemical studies. An example of the thermal-fluid dynamic evolution of a small basaltic sill is described, based on numerical simulation. Quantification of eruption conditions can provide valuable information on the overall magmatic system. We are developing quantitative methods for mapping pyroclastic facies of small basaltic centers and, in combination with two-phase hydrodynamic simulation, using this information to estimate eruption conditions. Examples of such hydrodynamic simulations are presented, along with comparison to an historical eruption in Hawaii

  4. Microchemistry, geochemistry and geochronology of the Lagoa Real Uranium Province (BA) magmatic association: petrological and evolutionary significance

    International Nuclear Information System (INIS)

    Amorim, Lucas Eustaquio Dias


    The Lagoa Real Uranium Province (PULR) is located in the center-south of the Bahia State, in the central part of Sao Francisco Craton and consists of an association of Paleoproterozoic meta-granites, alkali-gneiss, albitites, meta-leucodiorite and charnockites. This work has as objective the studies of the magmatic association, trying to understand its petrological and evolutionary meaning. For this purpose, representative bodies were sampled in order to develop unpublished studies of litogeochemistry, isotopes, geochronology and mineral chemistry. These analyzes were performed in: different preserved granitoid facies (Lagoa do Barro, Sao Timoteo, Juazeirinho and late pegmatitic phases), the meta-leucodiorites and charnockite. The data obtained using several modern methodologies, such as geochronology and mineral chemistry by LA-ICP-MS, provided results that allowed the characterization of two magmatic lithologies not described in the literature (Juazeirinho granite e late pegmatitic phases), and also a lithology preliminarily described (Lagoa do Barro granite). Moreover, these data contributed to elucidate the origin and meaning of the leucodiorite and charnoquito varieties, and made it possible to verify new compositional and mineral chemistry tendencies of Sao Timoteo granite. The data presented show that the studied granites were affected by albititization events (tardi or post-magmatic), which have different micro-chemical characteristics from the processes of albite formation related to the non-mineralized albitites bodies. Three albititization events were identified: a) An event that affected the granites characterized by the formation of albite with Rb and U, (b) Another event related to fluids associated with late pegmatitic bodies that formed albite with high levels of U, Rb and Ba, and partially affected the granites of the next pegmatoids portions; and (c) a final albititization event that caused the formation of the albite gneiss bodies, with albite

  5. Stable isotope and fluid inclusion evidence for the origin of the Brandberg West area Sn-W vein deposits, NW Namibia (United States)

    Macey, Paul; Harris, Chris


    The Brandberg West region of NW Namibia is dominated by poly-deformed turbidites and carbonate rocks of the Neoproterozoic Damara Supergoup, which have been regionally metamorphosed to greenschist facies and thermally metamorphosed up to mid-amphibolite facies by Neoproterozoic granite plutons. The meta-sedimentary rocks host Damaran-age hydrothermal quartz vein-hosted Sn-W mineralization at Brandberg West and numerous nearby smaller deposits. Fluid inclusion microthermometric studies of the vein quartz suggests that the ore-forming fluids at the Brandberg West mine were CO2-bearing aqueous fluids represented by the NaCl-CaCl2-H2O-CO2 system with moderate salinity (mean=8.6 wt% NaClequivalent).Temperatures determined using oxygen isotope thermometry are 415-521°C (quartz-muscovite), 392-447°C (quartz-cassiterite), and 444-490°C (quartz-hematite). At Brandberg West, the oxygen isotope ratios of quartz veins and siliciclastic host rocks in the mineralized area are lower than those in the rocks and veins of the surrounding areas suggesting that pervasive fluid-rock interaction occurred during mineralization. The O- and H-isotope data of quartz-muscovite veins and fluid inclusions indicate that the ore fluids were dominantly of magmatic origin, implying that mineralization occurred above a shallow granite pluton. Simple mass balance calculations suggest water/rock ratios of 1.88 (closed system) and 1.01 (open system). The CO2 component of the fluid inclusions had similar δ 13C to the carbonate rocks intercalated with the turbidites. It is most likely that mineralization at Brandberg West was caused by a combination of an impermeable marble barrier and interaction of the fluids with the marble. The minor deposits in the area have quartz veins with higher δ 18O values, which is consistent with these deposits being similar geological environments exposed at higher erosion levels.

  6. Mesozoic to Cenozoic magmatic history of the Pamir (United States)

    Chapman, James B.; Scoggin, Shane H.; Kapp, Paul; Carrapa, Barbara; Ducea, Mihai N.; Worthington, James; Oimahmadov, Ilhomjon; Gadoev, Mustafo


    New geochronologic, geochemical, and isotopic data for Mesozoic to Cenozoic igneous rocks and detrital minerals from the Pamir Mountains help to distinguish major regional magmatic episodes and constrain the tectonic evolution of the Pamir orogenic system. After final accretion of the Central and South Pamir terranes during the Late Triassic to Early Jurassic, the Pamir was largely amagmatic until the emplacement of the intermediate (SiO2 > 60 wt.%), calc-alkaline, and isotopically evolved (-13 to -5 zircon εHf(t)) South Pamir batholith between 120-100 Ma, which is the most volumetrically significant magmatic complex in the Pamir and includes a high flux magmatic event at ∼105 Ma. The South Pamir batholith is interpreted as the northern (inboard) equivalent of the Cretaceous Karakoram batholith and the along-strike equivalent of an Early Cretaceous magmatic belt in the northern Lhasa terrane in Tibet. The northern Lhasa terrane is characterized by a similar high-flux event at ∼110 Ma. Migration of continental arc magmatism into the South Pamir terrane during the mid-Cretaceous is interpreted to reflect northward directed, low-angle to flat-slab subduction of the Neo-Tethyan oceanic lithosphere. Late Cretaceous magmatism (80-70 Ma) in the Pamir is scarce, but concentrated in the Central and northern South Pamir terranes where it is comparatively more mafic (SiO2 roll-back of the Neotethyan oceanic slab, which is consistent with similarly aged extension-related magmatism in the Karakoram terrane and Kohistan. There is an additional pulse of magmatism in the Pamir at 42-36 Ma that is geographically restricted (∼150 km diameter ellipsoidal area) and referred to as the Vanj magmatic complex. The Vanj complex comprises metaluminous, high-K calc-alkaline to shoshonitic monzonite, syenite, and granite that is adakitic (La/YbN = 13 to 57) with low Mg# (35-41). The Vanj complex displays a range of SiO2 (54-75 wt.%) and isotopic compositions (-7 to -3 εNd(i), 0.706 to

  7. The geochemical evolution of syncollisional magmatism and the implications for significant magmatic-hydrothermal lead-zinc mineralization (Gangdese, Tibet) (United States)

    Zhou, Jinsheng; Yang, Zhusen; Hou, Zengqian; Liu, Yingchao; Zhao, Xiaoyan; Zhang, Xiong; Zhao, Miao; Ma, Wang


    In addition to well-known subduction processes, the collision of two continents also generates abundant ore deposits, as in the case of the Tibetan Plateau, which is the youngest and most spectacular collisional belt on Earth. During the building history of the Gangdese magmatic belt, several magmatic flare-up events developed, however, significant magmatic-hydrothermal lead-zinc mineralization dominantly accompanied the magmatism during the syncollisional period ( 65-41 Ma). Based on integrated geochemical and isotopic data, we provide insights into the genesis and evolution of syncollisional magmas, and their implications for significant magmatic-hydrothermal lead-zinc mineralization. The Sr-Nd isotopic compositions of most syncollisional igneous rocks (87Sr/86Sr = 0.7034-0.7123; εNd(t) = - 9.0 to + 1.8) indicate a mixing origin between mantle-derived basaltic magmas and ancient crustal melts, and fractional crystallization is a fundamental mechanism by which syncollisional magmas evolve towards intermediate to silicic compositions. Most lead-zinc mineralization-related plutons are high silica (76.14% wt.% SiO2 on average), high oxygen fugacity (average ΔFMQ + 2.5) granites with highly evolved chemical signatures [average Eun/Eun* = 0.33, high Rb/Sr (average = 3.9)], and they represent the final products from primary magmas. Due to the contribution of ancient crustal melts to the genesis of mineralization-related parent magmas, the spatial distribution of Pb-Zn deposits within the northern Gangdese magmatic belt is controlled by the lithospheric architecture. In compressional environments, magmas have low evacuation efficiency and long magma chamber lifespan, which is favorable for basaltic parents evolved to high silica granites through sufficient fractional crystallization. This scenario contributes to our understanding of the significant magmatic-hydrothermal lead-zinc mineralization that occurred in the syncollisional period.

  8. Mineralogy, fluid inclusion petrography, and stable isotope geochemistry of Pb-Zn-Ag veins at the Shizhuyuan deposit, Hunan Province, southeastern China (United States)

    Wu, Shenghua; Mao, Jingwen; Yuan, Shunda; Dai, Pan; Wang, Xudong


    The Shizhuyuan polymetallic deposit is located in the central part of the Nanling region, southeastern China, and consists of proximal W-Sn-Mo-Bi skarns and greisens and distal Pb-Zn-Ag veins. The sulfides and sulfosalts in the distal veins formed in three distinct stages: (1) an early stage of pyrite and arsenopyrite, (2) a middle stage of sphalerite and chalcopyrite, and (3) a late stage of galena, Ag-, Sn-, and Bi-bearing sulfides and sulfosalts, and pyrrhotite. Combined sulfide and sulfosalt geothermometry and fluid inclusion analyses indicate that the early stage of mineralization occurred at a temperature of 400 °C and involved boiling under hydrostatic pressure ( 200 bar), with the temperature of the system dropping during the late stage to 200 °C. Laser Raman analysis indicates that the fluid inclusions within the studied minerals are dominated by H2O, although some contain carbonate solids and CH4 gas. Vein-hosted sulfides have δ34S values of 3.8-6.3‰ that are interpreted as indicative of a magmatic source of sulfur. The mineralization process can be summarized as follows: an aqueous fluid exsolved on final crystallization of the Qianlishan pluton, ascended along fracture zones, cooled to <400 °C, and boiled under hydrostatic conditions, and with decreasing temperature and sulfur fugacity, sulfide and sulfosalt minerals precipitated successively from the Ag-Cu-Zn-Fe-Pb-Sb-As-S-bearing fluid system.

  9. Argon isotopes as recorders of magmatic processes (United States)

    Layer, P. W.; Gardner, J. E.; Mora Chaparro, J. C.; Arce, J. L.


    Argon isotopic ratios vary enough between different reservoirs (atmosphere, crust, mantle) and diffuse fast enough through most minerals at magmatic temperatures (700-1200 C) to make them ideal for looking at magma chamber dynamics. Indeed, diffusion is sufficiently fast to allow short time scales to be deciphered, setting argon apart from many other isotopic methods. A mineral's ability to retain "excess" argon (40Ar/36Ar ratios greater than the atmospheric value and apparent ages older than the known eruption age) during post-eruption cooling is key to Ar studies. Previous work shows that both phenocrysts (crystallizing in the magma chamber; e.g. Mt St. Helens; Layer and Gardner, 2001) and xenocrysts (introduced into the magma chamber; e.g Toba; Gardner et al., 2002) preserve excess argon, which enables magma chamber processes to be deciphered through the variable diffusion rates between crystal phases. Single crystal 40Ar/39Ar step-heating of biotite from the 10.5 ka eruption of Nevado de Toluca volcano, Mexico indicates that they are xenocrystic and resided for only a short (< 1 year) time in the magma before it erupted. The biotite has reaction rims of hornblende, orthopyroxene and plagioclase, and failed to grow experimentally at pressure-temperature conditions of the magma, confirming the xenocrystic nature of this phase. Single-step fusion of plagioclase phenocrysts from eruptions of El Chichon volcano, Mexico, shows evidence of excess (mantle) argon, whereas hornblende from the same eruptions contains little or none. In this case, faster diffusion of Ar in plagioclase than in hornblende allow plagioclase to incorporate excess argon during magma recharge; hornblende does not. Combining such results with other isotopic systems may in fact better determine magma chamber processes. At El Chichon, Sr isotopes suggest magma recharges ocurred (Tepley et al., 2000), whereas the argon isotopes suggest such pulses occurred just before each eruption. The fast and

  10. Influence of volatile degassing on the eruptibility of large igneous province magmatic systems (United States)

    Mittal, T.; Richards, M. A.


    Magmatic volatiles, in particular their buoyancy, may play a critical role in determining whether a magma reservoir can build up enough overpressure leading to drive flood basalt eruptions (Black & Manga 2017). Thus, it is important to understand the extent to which volatiles can remain trapped in a magmatic system and how they influence the eruptibility. Although the high-temperature metamorphic aureloe around a magma chamber is typically considered to have low permeability due to ductile creep, recent theoretical, experimental, and field work (e.g. Noriaki et al. 2017) have highlighted the role of dynamic permeability in magmatic systems. Consequently, the effective permeability of the crust when magma is present in the system can be orders of magnitude larger than that of exhumed rock samples. We model dynamic permeability changes as a competition between hydro-fracturing (increased porosity) and fracture closure by ductile creep and hydrothermal mineral precipitation (reduced porosity) and find yearly-to-decadal time-scales for periodic fracturing and fluid loss events and an increase in average permeability. We then use a fully coupled poro-thermo-elastic framework to model to explore the macroscopic influence of volatile loss on the stress state of the crust in this higher time-averaged permeability setting. We derive new semi-analytical solutions and combine them with a magma chamber box model (modified from Degruyter & Huber 2014) to analyze system-scale dynamics for both basaltic and silicic magmatic systems. We find that passive degassing likely has a substantial temporal influence on the stress distribution in the crust and the highly crystalline mush zone immediately surrounding a magma reservoir, and find an additional scale : pore-pressure diffusion timescale that exerts a first-order control on the magnitude and frequency of volcanic eruptions. We also explore how disconnected magma batches interact indirectly with each other and its implications for

  11. Magmatic systems of large continental igneous provinces

    Directory of Open Access Journals (Sweden)

    E. Sharkov


    Full Text Available Large igneous provinces (LIPs formed by mantle superplume events have irreversibly changed their composition in the geological evolution of the Earth from high-Mg melts (during Archean and early Paleoproterozoic to Phanerozoic-type geochemically enriched Fe-Ti basalts and picrites at 2.3 Ga. We propose that this upheaval could be related to the change in the source and nature of the mantle superplumes of different generations. The first generation plumes were derived from the depleted mantle, whereas the second generation (thermochemical originated from the core-mantle boundary (CMB. This study mainly focuses on the second (Phanerozoic type of LIPs, as exemplified by the mid-Paleoproterozoic Jatulian–Ludicovian LIP in the Fennoscandian Shield, the Permian–Triassic Siberian LIP, and the late Cenozoic flood basalts of Syria. The latter LIP contains mantle xenoliths represented by green and black series. These xenoliths are fragments of cooled upper margins of the mantle plume heads, above zones of adiabatic melting, and provide information about composition of the plume material and processes in the plume head. Based on the previous studies on the composition of the mantle xenoliths in within-plate basalts around the world, it is inferred that the heads of the mantle (thermochemical plumes are made up of moderately depleted spinel peridotites (mainly lherzolites and geochemically-enriched intergranular fluid/melt. Further, it is presumed that the plume heads intrude the mafic lower crust and reach up to the bottom of the upper crust at depths ∼20 km. The generation of two major types of mantle-derived magmas (alkali and tholeiitic basalts was previously attributed to the processes related to different PT-parameters in the adiabatic melting zone whereas this study relates to the fluid regime in the plume heads. It is also suggested that a newly-formed melt can occur on different sides of a critical plane of silica undersaturation and can

  12. The Axum-Adwa basalt-trachyte complex: a late magmatic activity at the periphery of the Afar plume (United States)

    Natali, C.; Beccaluva, L.; Bianchini, G.; Siena, F.


    The Axum-Adwa igneous complex consists of a basalt-trachyte (syenite) suite emplaced at the northern periphery of the Ethiopian plateau, after the paroxysmal eruption of the Oligocene (ca 30 Ma) continental flood basalts (CFB), which is related to the Afar plume activity. 40Ar/39Ar and K-Ar ages, carried out for the first time on felsic and basaltic rocks, constrain the magmatic age of the greater part of the complex around Axum to 19-15 Ma, whereas trachytic lavas from volcanic centres NE of Adwa are dated ca 27 Ma. The felsic compositions straddle the critical SiO2-saturation boundary, ranging from normative quartz trachyte lavas east of Adwa to normative (and modal) nepheline syenite subvolcanic domes (the obelisks stones of ancient axumites) around Axum. Petrogenetic modelling based on rock chemical data and phase equilibria calculations by PELE (Boudreau 1999) shows that low-pressure fractional crystallization processes, starting from mildly alkaline- and alkaline basalts comparable to those present in the complex, could generate SiO2-saturated trachytes and SiO2-undersaturated syenites, respectively, which correspond to residual liquid fractions of 17 and 10 %. The observed differentiation processes are consistent with the development of rifting events and formation of shallow magma chambers plausibly located between displaced (tilted) crustal blocks that favoured trapping of basaltic parental magmas and their fractionation to felsic differentiates. In syenitic domes, late- to post-magmatic processes are sometimes evidenced by secondary mineral associations (e.g. Bete Giorgis dome) which overprint the magmatic parageneses, and mainly induce additional nepheline and sodic pyroxene neo-crystallization. These metasomatic reactions were promoted by the circulation of Na-Cl-rich deuteric fluids (600-400 °C), as indicated by mineral and bulk rock chemical budgets as well as by δ18O analyses on mineral separates. The occurrence of this magmatism post-dating the

  13. Extensive crustal melting during craton destruction: Evidence from the Mesozoic magmatic suite of Junan, eastern North China Craton (United States)

    Yang, Fan; Santosh, M.; Tang, Li


    The cratonic destruction associated with the Pacific plate subduction beneath the eastern North China Craton (NCC) shows a close relationship with the widespread magmatism during the Late Mesozoic. Here we investigate a suite of intrusive and extrusive magmatic rocks from the Junan region of the eastern NCC in order to evaluate the role of extensive crustal melting related to decratonization. We present petrological, geochemical, zircon U-Pb geochronological and Lu-Hf isotopic data to evaluate the petrogenesis, timing and tectonic significance of the Early Cretaceous magmatism. Zircon grains in the basalt from the extrusive suite of Junan show multiple populations with Neoproterozoic and Early Paleozoic xenocrystic grains ranging in age from 764 Ma to 495 Ma as well as Jurassic grains with an age range of 189-165 Ma. The dominant population of magmatic zircon grains in the syenite defines three major age peaks of 772 Ma, 132 Ma and 126 Ma. Zircons in the granitoids including alkali syenite, monzonite and granodiorite yield a tightly restricted age range of 124-130 Ma representing their emplacement ages. The Neoproterozoic (841-547 Ma) zircon grains from the basalt and the syenite possess εHf(t) values of -22.9 to -8.4 and from -18.8 to -17.3, respectively. The Early Paleozoic (523-494 Ma) zircons from the basalt and the syenite also show markedly negative εHf(t) values of -22.7 to -18.0. The dominant population of Early Cretaceous (134-121 Ma) zircon grains presented in all the samples also displays negative εHf(t) values range from -31.7 to -21.1, with TDM of 1653-2017 Ma and TDMC in the range of 2193-3187 Ma. Accordingly, the Lu-Hf data suggest that the parent magma was sourced through melting of Mesoarchean to Paleoproterozoic basement rocks. Geochemical data on the Junan magmatic suite display features similar to those associated with the arc magmatic rocks involving subduction-related components, with interaction of fluids and melts in the suprasubduction

  14. Unraveling the dynamics of magmatic CO2 degassing at Mammoth Mountain, California (United States)

    Pfeiffer, Loic; Wanner, Christoph; Lewicki, Jennifer L.


    The accumulation of magmatic CO2 beneath low-permeability barriers may lead to the formation of CO2-rich gas reservoirs within volcanic systems. Such accumulation is often evidenced by high surface CO2 emissions that fluctuate over time. The temporal variability in surface degassing is believed in part to reflect a complex interplay between deep magmatic degassing and the permeability of degassing pathways. A better understanding of the dynamics of CO2 degassing is required to improve monitoring and hazards mitigation in these systems. Owing to the availability of long-term records of CO2 emissions rates and seismicity, Mammoth Mountain in California constitutes an ideal site towards such predictive understanding. Mammoth Mountain is characterized by intense soil CO2 degassing (up to ∼1000 t d−1) and tree kill areas that resulted from leakage of CO2 from a CO2-rich gas reservoir located in the upper ∼4 km. The release of CO2-rich fluids from deeper basaltic intrusions towards the reservoir induces seismicity and potentially reactivates faults connecting the reservoir to the surface. While this conceptual model is well-accepted, there is still a debate whether temporally variable surface CO2 fluxes directly reflect degassing of intrusions or variations in fault permeability. Here, we report the first large-scale numerical model of fluid and heat transport for Mammoth Mountain. We discuss processes (i) leading to the initial formation of the CO2-rich gas reservoir prior to the occurrence of high surface CO2 degassing rates and (ii) controlling current CO2 degassing at the surface. Although the modeling settings are site-specific, the key mechanisms discussed in this study are likely at play at other volcanic systems hosting CO2-rich gas reservoirs. In particular, our model results illustrate the role of convection in stripping a CO2-rich gas phase from a rising hydrothermal fluid and leading to an accumulation of a large mass of CO2 (∼107–108

  15. Fluid inclusions in minerals associated to uranium mineralization in Jazida do Engenho (anomaly 09), Lagoa Real uranium province - Bahia, Brazil; Inclusoes fluidas nos minerais associados a mineralizacao uranifera da Jazida do Engenho (Anomalia 09), provincia uranifera de Lagoa Real, BA

    Energy Technology Data Exchange (ETDEWEB)

    Souza, Aurelio da Silva de


    event without a predominant fluid associated, at least in this Lagoa Real area. Otherwise, the presence of this fluid should be present in the mineral para genesis. Finally, the data from the Engenho deposit indicate the occurrence of fluids showing compositional variations in, at least, three different stages: magmatic pyroxene -metamorphic pyroxene associated to uranium -- albite (recristalized) associated to uranium. The place of the aqueous-carbonic fluid associated to previous albite is still unknown. (author)

  16. Quaternary Magmatism in the Cascades - Geologic Perspectives (United States)

    Hildreth, Wes


    Foreward The Cascade magmatic arc is a belt of Quaternary volcanoes that extends 1,250 km from Lassen Peak in northern California to Meager Mountain in Canada, above the subduction zone where the Juan de Fuca Plate plunges beneath the North American Plate. This Professional Paper presents a synthesis of the entire volcanic arc, addressing all 2,300 known Quaternary volcanoes, not just the 30 or so visually prominent peaks that comprise the volcanic skyline. Study of Cascade volcanoes goes back to the geological explorers of the late 19th century and the seminal investigations of Howel Williams in the 1920s and 1930s. However, major progress and application of modern scientific methods and instrumentation began only in the 1970s with the advent of systematic geological, geophysical, and geochemical studies of the entire arc. Initial stimulus from the USGS Geothermal Research Program was enhanced by the USGS Volcano Hazards Program following the 1980 eruption of Mount St. Helens. Together, these two USGS Programs have provided more than three decades of stable funding, staffing, and analytical support. This Professional Paper summarizes the resultant USGS data sets and integrates them with the parallel contributions of other investigators. The product is based upon an all-encompassing and definitive geological database, including chemical and isotopic analyses to characterize the rocks and geochronology to provide the critical time constraints. Until now, this massive amount of data has not been summarized, and a systematic and uniform interpretation firmly grounded in geological fact has been lacking. Herein lies the primary utility of this Cascade volume. It not only will be the mandatory starting point for new workers, but also will provide essential geological context to broaden the perspectives of current investigators of specific Cascade volcanoes. Wes Hildreth's insightful understanding of volcanic processes and his uncompromising scientific integrity make him

  17. S/Se ratio of pyrite from eastern Australian VHMS deposits: implication of magmatic input into volcanogenic hydrothermal systems

    Energy Technology Data Exchange (ETDEWEB)

    Huston, D L [Geological Survey of Canada, Ottawa, ON (Canada); Sie, S H; Suter, G F [Commonwealth Scientific and Industrial Research Organisation (CSIRO), North Ryde, NSW (Australia). Div. of Exploration Geoscience; Cooke, D R [Tasmania Univ., Sandy Bay, TAS (Australia)


    The proton microprobe was used to determine the concentrations of over twenty trace elements in pyrite grains from four volcanic-hosted massive sulphide (VHMS) deposits in eastern Australia. Of the elements determined, Se has the most potential in resolving important problems in the genesis of this class of ore deposits. This paper summarises analytical conditions, describes the distribution of Se in pyrite in VHMS deposits as determined in this and other studies, discusses the speciation of Se in hydrothermal fluids, and presents a genetic model on the relative contribution of magmatic versus sea water Se (and S) in VHMS systems. 2 refs., 1 fig.

  18. S/Se ratio of pyrite from eastern Australian VHMS deposits: implication of magmatic input into volcanogenic hydrothermal systems

    Energy Technology Data Exchange (ETDEWEB)

    Huston, D.L. [Geological Survey of Canada, Ottawa, ON (Canada); Sie, S.H.; Suter, G.F. [Commonwealth Scientific and Industrial Research Organisation (CSIRO), North Ryde, NSW (Australia). Div. of Exploration Geoscience; Cooke, D.R. [Tasmania Univ., Sandy Bay, TAS (Australia)


    The proton microprobe was used to determine the concentrations of over twenty trace elements in pyrite grains from four volcanic-hosted massive sulphide (VHMS) deposits in eastern Australia. Of the elements determined, Se has the most potential in resolving important problems in the genesis of this class of ore deposits. This paper summarises analytical conditions, describes the distribution of Se in pyrite in VHMS deposits as determined in this and other studies, discusses the speciation of Se in hydrothermal fluids, and presents a genetic model on the relative contribution of magmatic versus sea water Se (and S) in VHMS systems. 2 refs., 1 fig.

  19. The Krásná Hora, Milešov, and Příčovy Sb-Au ore deposits, Bohemian Massif: mineralogy, fluid inclusions, and stable isotope constraints on the deposit formation (United States)

    Němec, Matěj; Zachariáš, Jiří


    The Krásná Hora-Milešov and Příčovy districts (Czech Republic) are the unique examples of Sb-Au subtype orogenic gold deposits in the Bohemian Massif. They are represented by quartz-stibnite veins and massive stibnite lenses grading into low-grade, disseminated ores in altered host rocks. Gold postdates the stibnite and is often replaced by aurostibite. The ore zones are hosted by hydrothermally altered dikes of lamprophyres (Krásná Hora-Milešov) or are associated with local strike-slip faults (Příčovy). Formation of Sb-Au deposits probably occurred shortly after the main gold-bearing event (348-338 Ma; Au-only deposits) in the central part of the Bohemian Massif. Fluid inclusion analyses suggest that stibnite precipitated at 250 to 130 °C and gold at 200 to 130 °C from low-salinity aqueous fluids. The main quartz gangue hosting the ore precipitated from the same type of fluid at about 300 °C. Early quartz-arsenopyrite veins are not associated with the Sb-Au deposition and formed from low-salinity, aqueous-carbonic fluid at higher pressure and temperature ( 250 MPa, 400 °C). The estimated oxygen isotope composition of the ore-bearing fluid (4 ± 1‰ SMOW; based on post-ore calcite) suggests its metamorphic or mixed magmatic-metamorphic origin and excludes the involvement of meteoric water. Rapid cooling of warm hydrothermal fluids reacting with "cold" host rock was probably the most important factor in the formation of both stibnite and gold.

  20. Fluid and mass transfer at subduction interfaces-The field metamorphic record (United States)

    Bebout, Gray E.; Penniston-Dorland, Sarah C.


    The interface between subducting oceanic slabs and the hanging wall is a structurally and lithologically complex region. Chemically disparate lithologies (sedimentary, mafic and ultramafic rocks) and mechanical mixtures thereof show heterogeneous deformation. These lithologies are tectonically juxtaposed at mm to km scales, particularly in more intensely sheared regions (mélange zones, which act as fluid channelways). This juxtaposition, commonly in the presence of a mobile fluid phase, offers up huge potential for mass transfer and related metasomatic alteration. Fluids in this setting appear capable of transporting mass over scales of kms, along flow paths with widely varying geometries and P-T trajectories. Current models of arc magmatism require km-scale migration of fluids from the interface into mantle wedge magma source regions and implicit in these models is the transport of any fluids generated in the subducting slab along and ultimately through the subduction interface. Field and geochemical studies of high- and ultrahigh-pressure metamorphic rocks elucidate the sources and compositions of fluids in subduction interfaces and the interplay between deformation and fluid and mass transfer in this region. Recent geophysical studies of the subduction interface - its thickness, mineralogy, density, and H2O content - indicate that its rheology greatly influences the ways in which the subducting plate is coupled with the hanging wall. Field investigation of the magnitude and styles of fluid-rock interaction in metamorphic rocks representing "seismogenic zone" depths (and greater) yields insight regarding the roles of fluids and elevated fluid pore pressure in the weakening of plate interface rocks and the deformation leading to seismic events. From a geochemical perspective, the plate interface contributes to shaping the "slab signature" observed in studies of the composition of arc volcanic rocks. Understanding the production of fluids with hybridized chemical

  1. Magmatic-vapor expansion and the formation of high-sulfidation gold deposits: Chemical controls on alteration and mineralization (United States)

    Henley, R.W.; Berger, B.R.


    Large bulk-tonnage high-sulfidation gold deposits, such as Yanacocha, Peru, are the surface expression of structurally-controlled lode gold deposits, such as El Indio, Chile. Both formed in active andesite-dacite volcanic terranes. Fluid inclusion, stable isotope and geologic data show that lode deposits formed within 1500. m of the paleo-surface as a consequence of the expansion of low-salinity, low-density magmatic vapor with very limited, if any, groundwater mixing. They are characterized by an initial 'Sulfate' Stage of advanced argillic wallrock alteration ?? alunite commonly with intense silicification followed by a 'Sulfide' Stage - a succession of discrete sulfide-sulfosalt veins that may be ore grade in gold and silver. Fluid inclusions in quartz formed during wallrock alteration have homogenization temperatures between 100 and over 500 ??C and preserve a record of a vapor-rich environment. Recent data for El Indio and similar deposits show that at the commencement of the Sulfide Stage, 'condensation' of Cu-As-S sulfosalt melts with trace concentrations of Sb, Te, Bi, Ag and Au occurred at > 600 ??C following pyrite deposition. Euhedral quartz crystals were simultaneously deposited from the vapor phase during crystallization of the vapor-saturated melt occurs to Fe-tennantite with progressive non-equilibrium fractionation of heavy metals between melt-vapor and solid. Vugs containing a range of sulfides, sulfosalts and gold record the changing composition of the vapor. Published fluid inclusion and mineralogical data are reviewed in the context of geological relationships to establish boundary conditions through which to trace the expansion of magmatic vapor from source to surface and consequent alteration and mineralization. Initially heat loss from the vapor is high resulting in the formation of acid condensate permeating through the wallrock. This Sulfate Stage alteration effectively isolates the expansion of magmatic vapor in subsurface fracture arrays

  2. Is there excess argon in the Fish Canyon magmatic system? (United States)

    Wilkinson, C. M.; Sherlock, S.; Kelley, S. P.; Charlier, B. L.


    Some phenocrysts from the Fish Canyon Tuff (San Juan volcanic field, south-western Colorado, USA) have yielded anomalously old 40Ar/39Ar apparent ages and yet the sanidine ages are sufficiently reproducible to allow its use as an international standard. The eruption age of the Fish Canyon tuff has recently been determined by high precision analysis and recalibration of the decay constants based on the sanidine standard at 28.305 ± 0.036 Ma [1], slightly younger than the generally accepted U-Pb age. Previously, minerals from the tuff have been used in various geochronological studies e.g., fission-track; U-Pb; Rb-Sr; K-Ar and 40Ar/39Ar, but U-Pb zircon ages which range 28.37 - 28.61 Ma appear to be older than the sanidine and other minerals, including biotite, yield older ages (27.41 - 28.25 Ma for biotite) [2]. In the Fish Canyon volcanic system, the erupted products are thought to exist in the magma chamber for significant periods prior to eruption [3] and then pass rapidly from a high temperature magmatic environment (where Ar is free to re-equilibrate among the minerals), to effectively being quenched upon eruption (where Ar becomes immobile). Artificially elevated ages, older than eruption age, have been identified in some 40Ar/39Ar geochronological studies (e.g. [4]). These older ages may either reflect; 1) argon accumulation in pheno- or xenocrysts (by radioactive decay of parent 40K), 2) excess argon (40ArE) incorporated into a mineral during crystallisation (via diffusion into the mineral lattice or hosted within fluid or melt inclusions) or 3) inherited radiogenic argon (the dated material contains a component older than the age of eruption) [5]. To better understand the effects of 40ArE on 40Ar/39Ar apparent ages we have conducted a detailed study of intra-grain grain age variations by UV-LAMP Ar-analysis. Analysis of polished thick sections has been performed in-situ using a 213nm laser and Nu Instruments Noblesse which is able to discriminate against

  3. From source to surface: Tracking magmatic boron and chlorine input into the geothermal systems of the Taupo Volcanic Zone, New Zealand (United States)

    Bégué, Florence; Deering, Chad D.; Gravley, Darren M.; Chambefort, Isabelle; Kennedy, Ben M.


    The magmatic contribution into geothermal fluids in the central Taupo Volcanic Zone (TVZ), New Zealand, has been attributed to either andesitic, 'arc-type' fluids, or rhyolitic, 'rift-type' fluids to explain the compositional diversity of discharge waters. However, this model relies on outdated assumptions related to geochemical trends associated with the magma at depth of typical arc to back-arc settings. Current tectonic models have shown that the TVZ is situated within a rifting arc and hosts magmatic systems dominated by distinct rhyolite types, that are likely to have evolved under different conditions than the subordinate andesites. Therefore, a new appraisal of the existing models is required to further understand the origin of the spatial compositional diversity observed in the geothermal fluids and its relationship to the structural setting. Here, we use volatile concentrations (i.e. H2O, Cl, B) from rhyolitic and andesitic mineral-hosted melt inclusions to evaluate the magmatic contribution to the TVZ geothermal systems. The andesite and two different types of rhyolites (R1 and R2) are each distinct in Cl/H2O and B/Cl, which will affect volatile solubility and phase separation (vapor vs. hydrosaline liquid) of the exsolved volatile phase. Ultimately, these key differences in the magmatic volatile constituents will play a significant role in governing the concentration of Cl discharged into geothermal systems. We estimate bulk fluid compositions (B and Cl) in equilibrium with the different melt types to show the potential contribution of 'parent' fluids to the geothermal systems throughout the TVZ. The results of this analysis show that the variability in fluid compositions partly reflects degassing from previously unaccounted for distinct magma source compositions. We suggest the geothermal systems that appear to have an 'arc-type' andesitic fluid contribution are actually derived from a rhyolite melt in equilibrium with a highly crystalline andesite

  4. Magmatic densities control erupted volumes in Icelandic volcanic systems (United States)

    Hartley, Margaret; Maclennan, John


    Magmatic density and viscosity exert fundamental controls on the eruptibility of magmas. In this study, we investigate the extent to which magmatic physical properties control the eruptibility of magmas from Iceland's Northern Volcanic Zone (NVZ). By studying subaerial flows of known age and volume, we are able to directly relate erupted volumes to magmatic physical properties, a task that has been near-impossible when dealing with submarine samples dredged from mid-ocean ridges. We find a strong correlation between magmatic density and observed erupted volumes on the NVZ. Over 85% of the total volume of erupted material lies close to a density and viscosity minimum that corresponds to the composition of basalts at the arrival of plagioclase on the liquidus. These magmas are buoyant with respect to the Icelandic upper crust. However, a number of small-volume eruptions with densities greater than typical Icelandic upper crust are also found in Iceland's neovolcanic zones. We use a simple numerical model to demonstrate that the eruption of magmas with higher densities and viscosities is facilitated by the generation of overpressure in magma chambers in the lower crust and uppermost mantle. This conclusion is in agreement with petrological constraints on the depths of crystallisation under Iceland.

  5. Bimodal magmatism produced by progressively inhibited crustal assimilation 2 (PICA)

    NARCIS (Netherlands)

    Meade, F.C.; Troll, V.R.; Ellam, R.M.; Freda, C.; Font Morales, L.; Donaldson, C.H.; Klonowska, I.


    The origin of bimodal (mafic-felsic) rock suites is a fundamental question in volcanology. Here we use major and trace elements, high-resolution Sr, Nd and Pb isotope analyses, experimental petrology and thermodynamic modelling to investigate bimodal magmatism at the iconic Carlingford Igneous

  6. Magmatic Densities Control Erupted Volumes in Icelandic Volcanic Systems

    Directory of Open Access Journals (Sweden)

    Margaret Hartley


    Full Text Available Magmatic density and viscosity exert fundamental controls on the eruptibility of magmas. In this study, we investigate the extent to which magmatic physical properties control the eruptibility of magmas from Iceland's Northern Volcanic Zone (NVZ. By studying subaerial flows of known age and volume, we are able to directly relate erupted volumes to magmatic physical properties, a task that has been near-impossible when dealing with submarine samples dredged from mid-ocean ridges. We find a strong correlation between magmatic density and observed erupted volumes on the NVZ. Over 85% of the total volume of erupted material lies close to a density and viscosity minimum that corresponds to the composition of basalts at the arrival of plagioclase on the liquidus. These magmas are buoyant with respect to the Icelandic upper crust. However, a number of small-volume eruptions with densities greater than typical Icelandic upper crust are also found in Iceland's neovolcanic zones. We use a simple numerical model to demonstrate that the eruption of magmas with higher densities and viscosities is facilitated by the generation of overpressure in magma chambers in the lower crust and uppermost mantle. This conclusion is in agreement with petrological constraints on the depths of crystallization under Iceland.

  7. Re-evaluating Gondwana breakup: Magmatism, movement and microplates (United States)

    Ferraccioli, F.; Jordan, T. A.


    Gondwana breakup is thought to have initiated in the Early- to Mid-Jurassic between South Africa and East Antarctica. The critical stages of continental extension and magmatism which preceded breakup remain controversial. It is agreed that extensive magmatism struck this region 180 Ma, and that significant extension occurred in the Weddell Sea Rift System (WSRS) and around the Falkland Plateau. However, the timing and volume of magmatism, extent and mechanism of continental extension, and the links with the wider plate circuit are poorly constrained. Jordan et al (Gondwana Research 2017) recently proposed a two-stage model for the formation of the WSRS: initial extension and movement of the Ellsworth Whitmore Mountains microplate along the margin of the East Antarctic continent on a sinistral strike slip fault zone, followed by transtensional extension closer to the continental margin. Here we identify some key questions raised by the two-stage model, and identify regions where these can be tested. Firstly, is the magmatism inferred to have facilitated extension in the WSRS directly linked to the onshore Dufek Intrusion? This question relates to both the uncertainty in the volume of magmatism and potentially the timing of extension, and requires improved resolution of aeromagnetic data in the eastern WSRS. Secondly, did extension in the WSRS terminate against a single strike slip fault zone or into a distributed fault system? By integrating new and existing aeromagnetic data along the margin of East Antarctica we evaluate the possibility of a distributed shear zone penetrating the East Antarctic continent, and identify critical remaining data gaps. Finally we question how extension within the WSRS could fit into the wider plate circuit. By integrating the two-stage model into Gplates reconstructions we identify regions of overlap and areas where tracers of past plate motion could be identified.

  8. Role of Sulfur in the Formation of Magmatic-Hydrothermal Copper-Gold Deposits (United States)

    Seo, J.; Guillong, M.; Heinrich, C.


    Sulfur plays essential roles in hydrothermal ore-forming processes [1], which calls for precise and accurate quantitative sulfur determination in fluid inclusions. Feasibility tests for sulfur quantification by comparing data from both LA-Quadrupole (Q) - ICP-MS and LA-High Resolution (HR) - ICP-MS show that reliable sulfur quantification in fluid inclusions is possible [2], provided that a very careful baseline correction is applied. We investigate the metal transporting capabilities of sulfur by measuring sulfur together with copper and other elements in cogenetic brine and vapor inclusions ('boiling assemblages') in single healed crack hosted by quartz veins. Samples are from high-temperature magmatic-hydrothermal ore deposits and miarolitic cavities of barren granitoid. Clear compositional correlations of sulfur with copper and gold were found. A molar S/Cu ratio commonly close to 2 but never above 2, indicates sulfur-complexed metal transportation in the high-temperature hydrothermal vapor, and probably also in the Na-Fe-K-Cl-enriched brines. Vapor/brine partitioning trends of the S and Cu are shown to be related with the chemistry of the fluids (possibly by various sulfur speciations in varying pH, fO2) and causative magma source. In the boiling hydrothermal environments, higher vapor partitioning of Cu and S is observed at reduced and peraluminous Sn-W granite, whereas oxidized and perakaline porphyry-style deposits have a lower partitioning to the vapor although the total concentration of S, Cu, Au in both fluid phase is higher than in the Sn-W granite [3]. Vapor inclusion in the boiling assemblages from magmatic-hydrothermal ore deposits and granitic intrusions generally contain an excess of sulfur over ore metals such as Cu, Fe, and Mo. This allows efficient sulfide ore precipitation in high-temperature porphyry-type deposits, and complexation of gold by the remaining sulfide down to lower temperatures. The results confirm earlier interpretations [1] and

  9. Origin of sulfur and crustal recycling of copper in polymetallic (Cu-Au-Co-Bi-U ± Ag) iron-oxide-dominated systems of the Great Bear Magmatic Zone, NWT, Canada (United States)

    Acosta-Góngora, P.; Gleeson, S. A.; Samson, I. M.; Corriveau, L.; Ootes, L.; Jackson, S. E.; Taylor, B. E.; Girard, I.


    The Great Bear Magmatic Zone, in northwest Canada, contains numerous polymetallic mineral occurrences, prospects, and deposits of the iron oxide copper-gold deposit (IOCG) family. The mineralization is hosted by the Treasure Lake Group and igneous rocks of the Great Bear arc and was deposited concomitantly with the arc magmatism (ca. 1.88 to 1.87 Ga). In situ δ 34S ( n = 48) and δ 65Cu ( n = 79) analyses were carried out on ore-related sulfides from a number of these systems. The δ 34S values mainly vary between 0 and +5‰, consistent with derivation of sulfur from the mantle. Lower δ 34S values (-7.7 to +1.4‰) from the Sue-Dianne breccia may indicate SO2 disproportionation of a magmatic hydrothermal fluid. The δ 65Cu values vary between -1.2 and -0.3‰, and are lower than the igneous δ 65Cu range of values (0.0 ± 0.27‰). The S and Cu isotopic data are decoupled, which suggests that Cu (and possibly some S) was dissolved and remobilized from supracrustal rocks during early stages of alteration (e.g., sodic alteration) and then precipitated by lower temperature, more oxidizing fluids (e.g., Ca-Fe-K alteration). A limited fluid inclusion dataset and δ 13C and δ 18O values are also presented. The δ 18Ofluid values are consistent with a magmatic origin or a host-rock equilibrated meteoric water source, whereas the δ 13Cfluid values support a marine carbonate source. Combined, the S and Cu isotopic data indicate that while the emplacement of the Great Bear magmatic bodies may have driven fluid convection and may be the source of fluids and sulfur, metals such as Cu could have been recycled from crustal sources.

  10. New geologic, fluid inclusion and stable isotope studies on the controversial Igarapé Bahia Cu-Au deposit, Carajás Province, Brazil (United States)

    Dreher, Ana M.; Xavier, Roberto P.; Taylor, Bruce E.; Martini, Sérgio L.


    The Igarapé Bahia Cu-Au deposit in the Carajás Province, Brazil, is hosted by steeply dipping metavolcano-sedimentary rocks of the Igarapé Bahia Group. This group consists of a low greenschist grade unit of the Archean (˜2,750 Ma) Itacaiúnas Supergroup, in which other important Cu-Au and iron ore deposits of the Carajás region are also hosted. The orebody at Igarapé Bahia is a fragmental rock unit situated between chloritized basalt, with associated hyaloclastite, banded iron formation (BIF), and chert in the footwall and mainly coarse- to fine-grained turbidites in the hanging wall. The fragmental rock unit is a nearly concordant, 2 km long and 30-250 m thick orebody made up of heterolithic, usually matrix-supported rocks composed mainly of coarse basalt, BIF, and chert clasts derived from the footwall unit. Mineralization is confined to the fine-grained matrix and comprises disseminated to massive chalcopyrite accompanied by magnetite, gold, U- and light rare earth element (LREE)-minerals, and minor other sulfides like bornite, molybdenite, cobaltite, digenite, and pyrite. Gangue minerals include siderite, chlorite, amphibole, tourmaline, quartz, stilpnomelane, epidote, and apatite. A less important mineralization style at Igarapé Bahia is represented by late quartz-chalcopyrite-calcite veins that crosscut all rocks in the deposit area. Fluid inclusions trapped in a quartz cavity in the ore unit indicate that saline aqueous fluids (5 to 45 wt% NaCl + CaCl2 equiv), together with carbonic (CO2 ± CH4) and low-salinity aqueous carbonic (6 wt% NaCl equiv) fluids, were involved in the mineralization process. Carbonates from the fragmental layer have δ13C values from -6.7 to -13.4 per mil that indicate their origin from organic and possibly also from magmatic carbon. The δ34S values for chalcopyrite range from -1.1 to 5.6 per mil with an outlier at -10.8 per mil, implying that most sulfur is magmatic or leached from magmatic rocks, whereas a limited

  11. Cu-Mo-Au mineralization in Qarachilar area, Qaradagh batholith (NW Iran): Fluid inclusion and stable isotope studies and Re-Os dating (United States)

    Simmonds, Vartan; Moazzen, Mohssen


    disappearance display TH values between 300 and 360 °C. The data-point trend in TH(L-V)-Salinity plot may signify boiling of low-salinity fluids and distillation by superficial fluids. Therefore, it can be concluded that the ore-forming magmatic-hydrothermal aqueous fluids have most likely experienced boiling and also mixed with low temperature and low salinity superficial fluids. Occurrence of boiling is also supported by the coexistence of liquid-rich and vapor-rich 2-phase inclusions as well as multi-phase halite-bearing inclusions which homogenize in a similar range of TH. The calculated minimum pressure at the time of entrapment is estimated about 50 to 120 bar, which is equal to the hydrostatic depth of 500-1100 m. Stable isotope studies of O, H and S on the quartz and sulfide samples taken from quartz-sulfide veins-veinlets reveal a magmatic origin for the ore-bearing fluid and its sulfur content. The δ18O values for quartz and fluid are about 11.13-12.47 ‰ and 5.78-6.89 ‰ (SMOW), respectively, the δD values are about -93 and -50 ‰ and the δ34S values of sulfide minerals are about -1.37-0.49‰ (VCDT). Re-Os model ages calculated for molybdenite samples range between 25.19±0.19 and 31.22±0.28 Ma, referring to middle-late Oligocene, contemporaneous with the third metallogenic epoch in the Lesser Caucasus (especially Kadjaran and Paragachai PCDs in South Armenian Block).

  12. Contrasting fluids and reservoirs in the contiguous Marcona and Mina Justa iron oxide-Cu (-Ag-Au) deposits, south-central Perú (United States)

    Chen, Huayong; Kyser, T. Kurtis; Clark, Alan H.


    The Marcona-Mina Justa deposit cluster, hosted by Lower Paleozoic metaclastic rocks and Middle Jurassic shallow marine andesites, incorporates the most important known magnetite mineralization in the Andes at Marcona (1.9 Gt at 55.4% Fe and 0.12% Cu) and one of the few major iron oxide-copper-gold (IOCG) deposits with economic Cu grades (346.6 Mt at 0.71% Cu, 3.8 g/t Ag and 0.03 g/t Au) at Mina Justa. The Middle Jurassic Marcona deposit is centred in Ica Department, Perú, and the Lower Cretaceous Mina Justa Cu (Ag, Au) prospect is located 3-4 km to the northeast. New fluid inclusion studies, including laser ablation time-of-flight inductively coupled plasma mass spectrometry (LA-TOF-ICPMS) analysis, integrated with sulphur, oxygen, hydrogen and carbon isotope analyses of minerals with well-defined paragenetic relationships, clarify the nature and origin of the hydrothermal fluid responsible for these contiguous but genetically contrasted deposits. At Marcona, early, sulphide-free stage M-III magnetite-biotite-calcic amphibole assemblages are inferred to have crystallized from a 700-800°C Fe oxide melt with a δ18O value from +5.2‰ to +7.7‰. Stage M-IV magnetite-phlogopite-calcic amphibole-sulphide assemblages were subsequently precipitated from 430-600°C aqueous fluids with dominantly magmatic isotopic compositions (δ34S = +0.8‰ to +5.9‰; δ18O = +9.6‰ to +12.2‰; δD = -73‰ to -43‰; and δ13C = -3.3‰). Stages M-III and M-IV account for over 95% of the magnetite mineralization at Marcona. Subsequent non-economic, lower temperature sulphide-calcite-amphibole assemblages (stage M-V) were deposited from fluids with similar δ34S (+1.8‰ to +5.0‰), δ18O (+10.1‰ to +12.5‰) and δ13C (-3.4‰), but higher δD values (average -8‰). Several groups of lower (200°C) fluids can be recognized in the main polymetallic (Cu, Zn, Pb) sulphide stage M-V and may record the involvement of modified seawater. At Mina Justa, early magnetite

  13. Geochemical characteristics of Antarctic magmatism connected with Karoo-Maud and Kerguelen mantle plumes (United States)

    Sushchevskaya, Nadezhda; Krymsky, Robert; Belyatsky, Boris; Antonov, Anton; Migdisova, Natalya


    dykes of the Schirmacher Oasis and basalts and dolerites of the Queen Maud Land (180 Ma) are identical in petrology and geochemistry terms and supposedly could be interpreted as the manifestation of the Karoo-Maud plume activity in Antarctica [Sushchevskaya et al., 2012]. The spatial distribution of the dikes indicates the eastward spreading of the plume material from DML to the Schirmacher Oasis within at least 10 Ma (up to ~35 Ma, taking into account the uncertainty of age determination). On the other hand, the considerable duration and multistage character of plume magmatism related to the activity of the Karoo-Maud plume in Antarctica and Africa [Leat et al., 2007; Luttinen et al., 2002] may indicate that the Mesozoic dikes of the oasis correspond to a single stage of plume magmatism. On the basis of obtained isotopic data it has been determined two magmatic melt evolution trends for basalts from: Queen Maud Land - Kerguelen Archipelago - Afanasy Nikitin Rise (Indian Ocean) and Jetty - Schirmacher oasises which mantle sources are quite different. Thus the Jetty - Schirmacher oasises magmatic melt sources are characterized by prevalence of the matter of moderately enriched or primitive chondritic mantle source and lithospheric mantle of Proterozoic ages but the substances of depleted mantle source similar to MORB-type and ancient mantle are absent. New data obtained on Nd, Sr, Pb isotopic and lithophile elements compositions of the alkaline-ultrabasic rocks from the Jetty oasis and Gaussberg volcano completed imagine of the Kerguelen-plume evolution. It has been confirmed unique character of the alkaline lamproiites of the Gaussberg volcano enrichments. Highly radiogenic Sr and Pb isotope ratios of these lamproiites reflect melting of the ancient sublithospheric depleted mantle which was stored from the Archean till nowadays unaffected by metasomatic-enrichment processes. During modern melting of this mantle part there is input of additional substances (crustal fluid

  14. Magmatic formations in the Okhotsk--Chukotka volcanogenic belt

    Energy Technology Data Exchange (ETDEWEB)

    Osipov, A.P.


    The relationship between the Okhotsk-Chukotka volcanogenic belt of Northeast USSR and the stage of evolution of magnetism and tectonic development of the region are examined. Recognizing the associations of effusive and intrusive rocks that are typical of the southern part of the volcanogenic belt and that are joined together by some characteristic features, a basic plan is presented for examination of the problem of magnetic formations. On the basis of the distinctive characteristics of epigeosynclinal tectonic development of the territory and the sequence of formation of the magmatic rocks within it, three main groups: volcanic, coleanoplutonic, and plutonic, can be distinguished; and a general scheme of development of these types in space and time within the volcanogenic belt can be developed. According to this scheme, four main stages can be recognized in the Mesozoic and Cenozoic magmatic evolution of the Okhotsk-Chukotka belt. This scheme of classification takes into consideration the factor of the structural development of this tectonomagmatic element.

  15. Magmatically Greedy Reararc Volcanoes of the N. Tofua Segment of the Tonga Arc (United States)

    Rubin, K. H.; Embley, R. W.; Arculus, R. J.; Lupton, J. E.


    Volcanism along the northernmost Tofua Arc is enigmatic because edifices of the arc's volcanic front are mostly, magmatically relatively anemic, despite the very high convergence rate of the Pacific Plate with this section of Tonga Arc. However, just westward of the arc front, in terrain generally thought of as part of the adjacent NE Lau Backarc Basin, lie a series of very active volcanoes and volcanic features, including the large submarine caldera Niuatahi (aka volcano 'O'), a large composite dacite lava flow terrain not obviously associated with any particular volcanic edifice, and the Mata volcano group, a series of 9 small elongate volcanoes in an extensional basin at the extreme NE corner of the Lau Basin. These three volcanic terrains do not sit on arc-perpendicular cross chains. Collectively, these volcanic features appear to be receiving a large proportion of the magma flux from the sub-Tonga/Lau mantle wedge, in effect 'stealing' this magma flux from the arc front. A second occurrence of such magma 'capture' from the arc front occurs in an area just to the south, on southernmost portion of the Fonualei Spreading Center. Erupted compositions at these 'magmatically greedy' volcanoes are consistent with high slab-derived fluid input into the wedge (particularly trace element abundances and volatile contents, e.g., see Lupton abstract this session). It is unclear how long-lived a feature this is, but the very presence of such hyperactive and areally-dispersed volcanism behind the arc front implies these volcanoes are not in fact part of any focused spreading/rifting in the Lau Backarc Basin, and should be thought of as 'reararc volcanoes'. Possible tectonic factors contributing to this unusually productive reararc environment are the high rate of convergence, the cold slab, the highly disorganized extension in the adjacent backarc, and the tear in the subducting plate just north of the Tofua Arc.

  16. The Magmatic Plumbing System of the Campi Flegrei Caldera. (United States)

    Lucia, C.; Ilenia, A.; Massimo, D.; Valeria, D.; Mauro, D.; Giovanni, O.


    The Campi Flegrei caldera is a nested and resurgent structure generated by at least two major collapses. Large sectors of the structural boundary of both calderas resulted from partial reactivation of pre-existing faults generated by regional tectonism. Its magmatic system is still active with the last eruption occurring in 1538 A.D. (Monte Nuovo), widespread fumaroles and hot springs activity, and the unrest episodes in the last 35 years, with a maximum net uplift of about 3.5 m in the Pozzuoli area. The definition of the history of the magmatic feeding system of this caldera, in terms of composition, time- scale and depth of crystallization, relation between composition of the erupted magma and structural position of the vent, and magma chamber processes, is of extreme importance for a better understanding of the dynamic conditions of the present day magma chamber and for evaluating of the extent to which the behavior of the magmatic system can be predicted. The Campi Flegrei caldera magmatic plumbing system is characterized by deep and shallow reservoirs. Campi Flegrei magmas originated in a subduction modified mantle source, stagnate at mid crustal level (20- 10 km depth), where they differentiated and are contaminated with the continental crust. From the "deep reservoir" shoshonitic to latitic magmas rise towards the surface along the NE aligned regional fault reactivated during the caldera collapse, whereas trachytic magmas rise mostly along faults and fractures bordering the resurgent block and the southern part of the Campi Flegrei caldera. Repeated arrival of trachytic to phonolitic magmas form shallow reservoirs at 4-3 km depth, in which differentiation and mixing processes occur before and during the eruption.

  17. Failed magmatic eruptions: Late-stage cessation of magma ascent (United States)

    Moran, S.C.; Newhall, C.; Roman, D.C.


    When a volcano becomes restless, a primary question is whether the unrest will lead to an eruption. Here we recognize four possible outcomes of a magmatic intrusion: "deep intrusion", "shallow intrusion", "sluggish/viscous magmatic eruption", and "rapid, often explosive magmatic eruption". We define "failed eruptions" as instances in which magma reaches but does not pass the "shallow intrusion" stage, i. e., when magma gets close to, but does not reach, the surface. Competing factors act to promote or hinder the eventual eruption of a magma intrusion. Fresh intrusion from depth, high magma gas content, rapid ascent rates that leave little time for enroute degassing, opening of pathways, and sudden decompression near the surface all act to promote eruption, whereas decreased magma supply from depth, slow ascent, significant enroute degassing and associated increases in viscosity, and impingement on structural barriers all act to hinder eruption. All of these factors interact in complex ways with variable results, but often cause magma to stall at some depth before reaching the surface. Although certain precursory phenomena, such as rapidly escalating seismic swarms or rates of degassing or deformation, are good indicators that an eruption is likely, such phenomena have also been observed in association with intrusions that have ultimately failed to erupt. A perpetual difficulty with quantifying the probability of eruption is a lack of data, particularly on instances of failed eruptions. This difficulty is being addressed in part through the WOVOdat database. Papers in this volume will be an additional resource for scientists grappling with the issue of whether or not an episode of unrest will lead to a magmatic eruption.

  18. Fluid Mechanics. (United States)

    Drazin, Philip


    Outlines the contents of Volume II of "Principia" by Sir Isaac Newton. Reviews the contributions of subsequent scientists to the physics of fluid dynamics. Discusses the treatment of fluid mechanics in physics curricula. Highlights a few of the problems of modern research in fluid dynamics. Shows that problems still remain. (CW)

  19. The 2006 Eruption of Raoul Volcano (Kermadecs): A Phreato-magmatic Event From a Hydrothermally-Sealed Volcanic Conduit System. (United States)

    Christenson, B. W.; Reyes, A. G.; Werner, C. A.


    The March 17, 2006 eruption from Raoul volcano (Kermadec Islands, NZ), which tragically claimed the life of NZ Department of Conservation staff member Mark Kearney, is being interpreted as a magmatic-hydrothermal event triggered by shaking associated with regional earthquake swarm activity. Although the eruption released ca. 200 T of SO2, thus confirming its magmatic nature, it occurred without significant precursory volcanic seismicity, and without any of the precursory responses of the volcanic hydrothermal system which were observed prior to the last eruption in 1964. Raoul Island has a long and varied eruption history dating back > 1.4 ma, and has been hydrothermally active throughout historic time. Present day fumarolic and hotspring discharges within Raoul caldera point to the existence of a small but well established, mixed meteoric - seawater hydrothermal system within the volcano. Magmatic signatures are apparent in fumarolic gas discharges, but are heavily masked by their interaction with hydrothermal system fluids (eg. near complete scrubbing of sulphur and halogen gases from the boiling point fumarolic discharges). A diffuse degassing study conducted in 2004 revealed that ca. 80 T/d CO2 is passively discharged from the volcano, suggesting that ongoing (albeit low level) convective degassing of magma occurs at depth. Interestingly, vent locations from the 2006 eruption correspond to areas of relatively low CO2 discharge on the crater floor in 2004. This, in conjunction with the preliminary findings of abundant hydrothermal mineralisation (calcite, anhydrite, quartz) in eruption ejecta, suggests that the main volcanic conduits had become effectively sealed during the interval since the last eruption. Calcite-hosted fluid inclusions are CO2 clathrate-bearing, and have relatively low homogenisation temperatures (165-180 °C), suggesting that the seal environment was both gas-charged and shallowly seated (< 200 m). Shaking associated with the regional

  20. The La Unión Au ± Cu prospect, Camagüey District, Cuba: fluid inclusion and stable isotope evidence for ore-forming processes (United States)

    Santana, Miriela María Ulloa; Moura, Márcia Abrahão; Olivo, Gema R.; Botelho, Nilson Francisquini; Kyser, T. Kurtis; Bühn, Bernhard


    The Camagüey district, Cuba, is known for its epithermal precious metal deposits in a Cretaceous volcanic arc setting. Recently, the La Unión prospect was discovered in the southern part of the district, containing gold and minor copper mineralization interpreted as porphyry type. Mineralization is hosted in a 73.0 ± 1.5 Ma calc-alkaline I-type oxidized porphyry quartz diorite intrusive within volcanic and volcaniclastic rocks of the early Cretaceous Guáimaro Formation. The porphyry is affected by propylitic alteration and crosscut by a network of quartz and carbonate veinlets and veins. Chlorite, epidote, sericite, quartz, and pyrite are the main minerals in the early veins which are cut by late carbonate and zeolite veins. Late barite pseudomorphously replaces pyrite. Gold is associated with pyrite as disseminations in the altered quartz diorite and in the veins, occurring as inclusions or filling fractures in pyrite with 4 g/t Au in bulk samples, and up to 900 ppm Au in in pyrite. Fluid inclusion and oxygen isotope data are consistent with a H2O-NaCl-(KCl) mineralizing fluid, derived from the quartz diorite magma, and trapped at least at 425°C and 1.2 kbar. This primary fluid unmixed into two fluid phases, a hypersaline aqueous fluid and a low-salinity vapor-rich fluid. Boiling during cooling may have played an important role in metal precipitation. Pyrite δ34S values for the La Unión prospect range between 0.71‰ and 1.31‰, consistent with a homogeneous magmatic sulfur source. The fluids in equilibrium with the mineralized rocks have estimated δ18O values from 8‰ to 11.8‰, calculated for a temperature range of 480-505°C. The tectonic environment of the La Unión prospect, its high gold and low copper contents, the physical-chemical characteristics of the mineralizing fluids and the isotopic signature of the alteration minerals and fluids indicate that the La Unión gold mineralization is similar to the porphyry gold type, even though the ore

  1. Semi-adakitic magmatism of the Satkatbong diorite, South Korea: Geochemical implications for post-adakitic magmatism in southeastern Eurasia (United States)

    Lim, Hoseong; Woo, Hyeon Dong; Myeong, Bora; Park, Jongkyu; Jang, Yun-Deuk


    The Satkatbong diorite (190 Ma) and the older Yeongdeok granite (250 Ma) in the Yeongnam massif, which is part of the southeastern margin of the Eurasian plate, are affected by a subduction system that is associated with the Izanagi and Farallon plates. The Satkatbong diorite is characterized by its abundant mafic magmatic enclaves (MMEs), mantle affinity, and intermediate adakitic Sr/Y vs. Y signature, whereas the Yeongdeok granite is distinctly adakitic and felsic and contains few MMEs. These differences in adakitic features might be due to differences in the lithospheric mantle material and/or different mafic MME sources. The results of rare earth element (REE) analyses and newly proposed Sr/La modeling in this study indicate that these two plutons were both generated by slab-mantle mixing and continental assimilation, whereas the Satkatbong diorite was additionally affected by the injection of a mafic source of MMEs, which "diluted" its adakitic chemistry. The young and hot subducting ridge passing toward the northeast due to the oblique subduction of the Izanagi and Farallon plates during the Early Mesozoic could have given rise to slab melting and asthenospheric influence through slab melting regions and a slab window, respectively. This implies that the adakitic Yeongdeok granite produced by slab melting and then the semi-adakitic Satkatbong diorite produced by asthenospheric influence, including other similar adakitic to semi-adakitic magmatism, might have occurred along the areas affected by ridge subduction. We suggest that this sequential magmatism would be applicable for many continental arcs which experienced ridge subduction being one of the mechanisms of adakite to semi-adakite magmatism.

  2. Late Jurassic-Early Cretaceous episodic development of the Bangong Meso-Tethyan subduction: Evidence from elemental and Sr-Nd isotopic geochemistry of arc magmatic rocks, Gaize region, central Tibet, China (United States)

    Zhang, Yu-Xiu; Li, Zhi-Wu; Yang, Wen-Guang; Zhu, Li-Dong; Jin, Xin; Zhou, Xiao-Yao; Tao, Gang; Zhang, Kai-Jun


    The Bangong Meso-Tethys plays a critical role in the development of the Tethyan realm and the initial elevation of the Tibetan Plateau. However, its precise subduction polarity, and history still remain unclear. In this study, we synthesize a report for the Late Jurassic-Early Cretaceous two-phase magmatic rocks in the Gaize region at the southern margin of the Qiangtang block located in central Tibet. These rocks formed during the Late Jurassic-earliest Cretaceous (161-142 Ma) and Early Cretaceous (128-106 Ma), peaking at 146 Ma and 118 Ma, respectively. The presence of inherited zircons indicates that an Archean component exists in sediments in the shallow Qiangtang crust, and has a complex tectonomagmatic history. Geochemical and Sr-Nd isotopic data show that the two-phase magmatic rocks exhibit characteristics of arc magmatism, which are rich in large-ion incompatible elements (LIIEs), but are strongly depleted in high field strength elements (HFSEs). The Late Jurassic-earliest Cretaceous magmatic rocks mixed and mingled among mantle-derived mafic magmas, subduction-related sediments, or crustally-derived felsic melts and fluids, formed by a northward and steep subduction of the Bangong Meso-Tethys ocean crust. The magmatic gap at 142-128 Ma marks a flat subduction of the Meso-Tethys. The Early Cretaceous magmatism experienced a magma MASH (melting, assimilation, storage, and homogenization) process among mantle-derived mafic magmas, or crustally-derived felsic melts and fluids, as a result of the Meso-Tethys oceanic slab roll-back, which triggered simultaneous back-arc rifting along the southern Qiangtang block margin.

  3. Monzonitoid magmatism of the copper-porphyritic Lazurnoe deposit (South Primor'e): U-Pb and K-Ar geochronology and peculiarities of ore-bearing magma genesis by the data of isotopic-geochemical studies (United States)

    Sakhno, V. G.; Kovalenko, S. V.; Alenicheva, A. A.


    Magmatic rocks from the copper-porphyritic Lazurnoe deposit (Central Primor'e) have been studied. It has been found that rocks from the Lazurnyi massif are referred to gabbro-monzodiorites, monzodiorites, and monzo-granodiorites formed during two magmatic phases of different ages. The earlier phase is represented by gabbro-monzodiorites and diorites of the North Stock, and the later one, by gabbro-monzodiorites and monzo-grano-diorites of the South Stock. On the basis of isotopic dating by the U-Pb (SHRIMP) method for zircon and by the K-Ar method for hornblendes and biotites, the age of magmatic rocks is determined at 110 ± 4 for the earlier phase and at 103.5 ± 1.5 for the later one. Examination of the isotopic composition for Nd, Sr, Pb, Hf, δ18O, and REE spectra has shown that melts of the first phase are contaminated with crustal rocks and they are typical for a high degree of secondary alterations. Potassiumfeldspar, biotite, propylitic alterations, and sulfidization are manifested in these rocks. The rocks of the later stage of magmatism are characteristic for a primitive composition of isotopes and the absence of secondary alterations. They carry the features of adakite specifics that allows us to consider them derivatives of mantle generation under high fluid pressure. The intrusion of fluid-saturated melts of the second phase into the magmatic source of the first phase caused both an alteration pattern of rocks and copper-porphyritic mineralization. Isotopes of sulfur and oxygen allow us to consider the ore component to be of magmatic origin.

  4. Porphyry-Copper Ore Shells Form at Stable Pressure-Temperature Fronts Within Dynamic Fluid Plumes (United States)

    Weis, P.; Driesner, T.; Heinrich, C. A.


    Porphyry-type ore deposits are major resources of copper and gold, precipitated from fluids expelled by crustal magma chambers. The metals are typically concentrated in confined ore shells within vertically extensive vein networks, formed through hydraulic fracturing of rock by ascending fluids. Numerical modeling shows that dynamic permeability responses to magmatic fluid expulsion can stabilize a front of metal precipitation at the boundary between lithostatically pressured up-flow of hot magmatic fluids and hydrostatically pressured convection of cooler meteoric fluids. The balance between focused heat advection and lateral cooling controls the most important economic characteristics, including size, shape, and ore grade. This self-sustaining process may extend to epithermal gold deposits, venting at active volcanoes, and regions with the potential for geothermal energy production.

  5. The role of carbon dioxide in the transport and fractionation of metals by geological fluids (United States)

    Kokh, Maria A.; Akinfiev, Nikolay N.; Pokrovski, Gleb S.; Salvi, Stefano; Guillaume, Damien


    depletion in metamorphic gold deposits formed by CO2-rich fluids. The transport of gold is unfavorable in the presence of CO2 only in S-rich (>0.5 wt% S) fluids in which Au forms the negatively charged Au(HS)2- and Au(HS)S3- complexes. By contrast, it is only weakly affected in S-poor (50 wt% CO2), the capacity of such fluids to transport gold (up to 100s ppb Au) remains comparable to that of aqueous fluids. These findings are in agreement with analyses of natural fluid inclusions in metamorphic deposits. In more saline oxidizing and S-rich fluids such as those in magmatic porphyry Cu-Au deposits, the Fe, Cu, and Au solubilities in the presence of CO2 decrease by ∼1 order of magnitude with CO2 increasing to 20-30 wt%, following the decrease in the stability of their dominant charged species (FeCl42-, CuCl2-, Au(HS)2- and Au(HS)S3-), but stay almost constant at higher CO2 contents (30-70 wt%) as controlled by the neutral species (FeCl20, Cu(HS)0 and Au(HS)0). Such solubility trends suggest a new potential trigger of ore precipitation in porphyry systems by CO2 pulses from the magmatic chamber, which may operate along with commonly admitted depositional mechanisms such as cooling, vapor-brine immiscibility, and water-rock interaction. The direct effect of CO2 on the mobility of Pt and Mo, metals that likely form hydrogen sulfide and oxy-hydroxide complexes, respectively, is expected to be weak in most settings. Among the studied elements, Sn is the only one whose solubility may be favored at high CO2 content (>20 wt%) due to carbonate complexing. This study demonstrates, for the first time, that, contrary to common belief, the presence of CO2 in a supercritical fluid may lead to enhanced mobility or, on contrary, to massive precipitation of some metals, depending on salinity and sulfur content, and, more generally, to significant fractionations between different metals.

  6. Fluid inclusions study in thermal gradient wells, Nevado del Ruiz Volcano

    International Nuclear Information System (INIS)

    Uruena Suarez, Cindy L; Zuluaga, Carlos A; Molano, Juan Carlos


    A fluid inclusions study in the Nevado del Ruiz volcano hydrothermal system allowed to characterize fluids involved in the evolution of the geothermal system. Fluid inclusions hosted in quartz, plagioclase and carbonate from samples of the deepest parts of three thermal gradient wells were analyzed to understand fluid-rock interaction. Fluid inclusions hosted in carbonate veins with coloform microestructure represent hydrothermal fluids with temperatures higher than 250 Celsius degrade. This interpretation is supported by microprobe and cathodoluminescence analysis that also indicate a hydrothermal origin for the veins. Fluid inclusions hosted in quartz (mylonite) were originated by metamorphic fluids and fluid inclusions hosted in plagioclase (andesitic lavas) are considered to be originated from magmatic fluids (H 2 O + CO 2 system).

  7. Fluids engineering

    International Nuclear Information System (INIS)



    Fluids engineering has played an important role in many applications, from ancient flood control to the design of high-speed compact turbomachinery. New applications of fluids engineering, such as in high-technology materials processing, biotechnology, and advanced combustion systems, have kept up unwaining interest in the subject. More accurate and sophisticated computational and measurement techniques are also constantly being developed and refined. On a more fundamental level, nonlinear dynamics and chaotic behavior of fluid flow are no longer an intellectual curiosity and fluid engineers are increasingly interested in finding practical applications for these emerging sciences. Applications of fluid technology to new areas, as well as the need to improve the design and to enhance the flexibility and reliability of flow-related machines and devices will continue to spur interest in fluids engineering. The objectives of the present seminar were: to exchange current information on arts, science, and technology of fluids engineering; to promote scientific cooperation between the fluids engineering communities of both nations, and to provide an opportunity for the participants and their colleagues to explore possible joint research programs in topics of high priority and mutual interest to both countries. The Seminar provided an excellent forum for reviewing the current state and future needs of fluids engineering for the two nations. With the Seminar ear-marking the first formal scientific exchange between Korea and the United States in the area of fluids engineering, the scope was deliberately left broad and general

  8. Magmatic dyking and recharge in the Asal Rift, Republic of Djibouti (United States)

    Peltzer, G.; Harrington, J.; Doubre, C.; Tomic, J.


    The Asal Rift, Republic of Djibouti, has been the locus of a major magmatic event in 1978 and seems to have maintained a sustained activity in the three decade following the event. We compare the dyking event of 1978 with the magmatic activity occurring in the rift during the 1997-2008 time period. We use historical air photos and satellite images to quantify the horizontal opening on the major faults activated in 1978. These observations are combined with ground based geodetic data acquired between 1973 and 1979 across the rift to constrain a kinematic model of the 1978 rifting event, including bordering faults and mid-crustal dykes under the Asal Rift and the Ghoubbet Gulf. The model indicates that extension was concentrated between the surface and a depth of 3 km in the crust, resulting in the opening of faults, dykes and fissures between the two main faults, E and gamma, and that the structure located under the Asal Rift, below 3 km, deflated. These results suggest that, during the 1978 event, magmatic fluids transferred from a mid-crustal reservoir to the shallow structures, injecting dykes and filling faults and fissures, and reaching the surface in the Ardoukoba fissural eruption. Surface deformation observed by InSAR during the 1997-2008 decade reveals a slow, yet sustained inflation and extension across the Asal Rift combined with continuous subsidence of the rift inner floor. Modeling shows that these observations cannot be explained by visco-elastic relaxation, a process, which mostly vanishes 20 to 30 years after the 1978 event. However, the InSAR observations over this decade are well explained by a kinematic model in which an inflating body is present at mid-crustal depth, approximately under the Fieale caldera, and shallow faults accommodate both horizontal opening and down-dip slip. The total geometric moment rate, or inflation rate, due to the opening of the mid-crustal structure and the deeper parts of the opening faults is 3 106 m3yr. Such a

  9. Magmatic evolution of Panama Canal volcanic rocks: A record of arc processes and tectonic change.

    Directory of Open Access Journals (Sweden)

    David W Farris

    Full Text Available Volcanic rocks along the Panama Canal present a world-class opportunity to examine the relationship between arc magmatism, tectonic forcing, wet and dry magmas, and volcanic structures. Major and trace element geochemistry of Canal volcanic rocks indicate a significant petrologic transition at 21-25 Ma. Oligocene Bas Obispo Fm. rocks have large negative Nb-Ta anomalies, low HREE, fluid mobile element enrichments, a THI of 0.88, and a H2Ocalc of >3 wt. %. In contrast, the Miocene Pedro Miguel and Late Basalt Fm. exhibit reduced Nb-Ta anomalies, flattened REE curves, depleted fluid mobile elements, a THI of 1.45, a H2Ocalc of <1 wt. %, and plot in mid-ocean ridge/back-arc basin fields. Geochemical modeling of Miocene rocks indicates 0.5-0.1 kbar crystallization depths of hot (1100-1190°C magmas in which most compositional diversity can be explained by fractional crystallization (F = 0.5. However, the most silicic lavas (Las Cascadas Fm. require an additional mechanism, and assimilation-fractional-crystallization can reproduce observed compositions at reasonable melt fractions. The Canal volcanic rocks, therefore, change from hydrous basaltic pyroclastic deposits typical of mantle-wedge-derived magmas, to hot, dry bi-modal magmatism at the Oligocene-Miocene boundary. We suggest the primary reason for the change is onset of arc perpendicular extension localized to central Panama. High-resolution mapping along the Panama Canal has revealed a sequence of inward dipping maar-diatreme pyroclastic pipes, large basaltic sills, and bedded silicic ignimbrites and tuff deposits. These volcanic bodies intrude into the sedimentary Canal Basin and are cut by normal and subsequently strike-slip faults. Such pyroclastic pipes and basaltic sills are most common in extensional arc and large igneous province environments. Overall, the change in volcanic edifice form and geochemistry are related to onset of arc perpendicular extension, and are consistent with the

  10. Magmatic evolution of Panama Canal volcanic rocks: A record of arc processes and tectonic change (United States)

    Cardona, Agustin; Montes, Camilo; Foster, David; Jaramillo, Carlos


    Volcanic rocks along the Panama Canal present a world-class opportunity to examine the relationship between arc magmatism, tectonic forcing, wet and dry magmas, and volcanic structures. Major and trace element geochemistry of Canal volcanic rocks indicate a significant petrologic transition at 21–25 Ma. Oligocene Bas Obispo Fm. rocks have large negative Nb-Ta anomalies, low HREE, fluid mobile element enrichments, a THI of 0.88, and a H2Ocalc of >3 wt. %. In contrast, the Miocene Pedro Miguel and Late Basalt Fm. exhibit reduced Nb-Ta anomalies, flattened REE curves, depleted fluid mobile elements, a THI of 1.45, a H2Ocalc of arc basin fields. Geochemical modeling of Miocene rocks indicates 0.5–0.1 kbar crystallization depths of hot (1100–1190°C) magmas in which most compositional diversity can be explained by fractional crystallization (F = 0.5). However, the most silicic lavas (Las Cascadas Fm.) require an additional mechanism, and assimilation-fractional-crystallization can reproduce observed compositions at reasonable melt fractions. The Canal volcanic rocks, therefore, change from hydrous basaltic pyroclastic deposits typical of mantle-wedge-derived magmas, to hot, dry bi-modal magmatism at the Oligocene-Miocene boundary. We suggest the primary reason for the change is onset of arc perpendicular extension localized to central Panama. High-resolution mapping along the Panama Canal has revealed a sequence of inward dipping maar-diatreme pyroclastic pipes, large basaltic sills, and bedded silicic ignimbrites and tuff deposits. These volcanic bodies intrude into the sedimentary Canal Basin and are cut by normal and subsequently strike-slip faults. Such pyroclastic pipes and basaltic sills are most common in extensional arc and large igneous province environments. Overall, the change in volcanic edifice form and geochemistry are related to onset of arc perpendicular extension, and are consistent with the idea that Panama arc crust fractured during collision

  11. Fluid Evolution of the Magmatic Hydrothermal Porphyry Copper Deposit Based on Fluid Inclusion and Stable Isotope Studies at Darrehzar, Iran


    Alizadeh Sevari, B.; Hezarkhani, A.


    The Darrehzar porphyry Cu-Mo deposit is located in southwestern Iran (~70 km southwest of Kerman City). The porphyries occur as Tertiary quartz-monzonite stocks and dikes, ranging in composition from microdiorite to diorite and granodiorite. Hydrothermal alteration and mineralization at Darrehzar are centered on the stock and were broadly synchronous with its emplacement. Early hydrothermal alteration was dominantly potassic and propylitic and was followed by later phyllic and argillic altera...

  12. Geology, mineralization, and fluid inclusion characteristics of the Kashkasu W-Mo-Cu skarn deposit associated with a high-potassic to shoshonitic igneous suite in Kyrgyzstan, Tien Shan: Toward a diversity of W mineralization in Central Asia (United States)

    Soloviev, Serguei G.; Kryazhev, Sergey G.


    The Kashkasu deposit is part of the subduction-related Late Paleozoic (Late Carboniferous) metallogenic belt of Tien Shan. It is associated with a multiphase monzodiorite-monzonite-granodiorite-granite pluton of the magnetite-series high-K calc-alkaline to shoshonitic igneous suite. The deposit contains zones of W-Mo-Cu oxidized prograde and retrograde skarns, with abundant andraditic garnet, magnetite, locally scapolite and K-feldspar, as well as scheelite, chalcopyrite, and molybdenite. Skarns are overprinted by quartz-carbonate-sericite (phyllic alteration) zones with scheelite and sulfides. Prograde calcic skarn and initial retrograde skarns were formed from a high temperature (650 °C to 450-550 °C), high pressure (2000 bars to 600-900 bars) magmatic-hydrothermal low- to high-salinity aqueous chloride fluid. The gradual fluid evolution was interrupted by the intrusion of granodiorite and likely associated release of low-salinity (∼7-8 wt% NaCl equiv.) fluid. Ascent of this fluid to shallower levels and/or its cooling to 400-500 °C has resulted in phase separation into low-salinity (2.1-3.1 wt% NaCl equiv.) vapor and coexisting brine (35-40 wt% NaCl equiv.). The boiling was coincident with most intense scheelite deposition in retrograde skarn. Later retrograde skarn assemblages were formed from a gaseous, low- to moderate-salinity (3.4-8.1 wt% NaCl equiv.) fluid and then from high salinity (37-42 wt% NaCl equiv.) aqueous chloride fluids, the latter being enriched in Ca (17-20 wt% CaCl2) that could also affect scheelite deposition. Another cycle of fluid exsolution from crystallizing magma corresponded to quartz-carbonate-sericite-scheelite-sulfide (phyllic) alteration stage, with the early low-salinity (5.3-8.4 wt% NaCl-equiv.) fluid followed by later high-salinity (33.5-38.2 wt% NaCl-equiv.) fluid. The sulfur isotope data (δ34S = +5.1 to +9.0) suggest significant sulfur sourcing from sedimentary rocks enriched in seawater sulfate, possibly evaporites.

  13. Buffer fluid

    Energy Technology Data Exchange (ETDEWEB)

    Mirzadzhanzade, A Kh; Dedusanko, G Ya; Dinaburg, L S; Markov, Yu M; Rasizade, Ya N; Rozov, V N; Sherstnev, N M


    A drilling fluid is suggested for separating the drilling and plugging fluids which contains as the base increased solution of polyacrylamide and additive. In order to increase the viscoelastic properties of the liquid with simultaneous decrease in the periods of its fabrication, the solution contains as an additive dry bentonite clay. In cases of the use of a buffer fluid under conditions of negative temperatures, it is necessary to add to it table salt or ethylene glycol.

  14. A historical overview of Moroccan magmatic events along northwest edge of the West African Craton (United States)

    Ikenne, Moha; Souhassou, Mustapha; Arai, Shoji; Soulaimani, Abderrahmane


    Located along the northwestern edge of the West African Craton, Morocco exhibits a wide variety of magmatic events from Archean to Quaternary. The oldest magmatic rocks belong to the Archean Reguibat Shield outcrops in the Moroccan Sahara. Paleoproterozoic magmatism, known as the Anti-Atlas granitoids, is related to the Eburnean orogeny and initial cratonization of the WAC. Mesoproterozoic magmatism is represented by a small number of mafic dykes known henceforth as the Taghdout mafic volcanism. Massive Neoproterozoic magmatic activity, related to the Pan-African cycle, consists of rift-related Tonian magmatism associated with the Rodinia breakup, an Early Cryogenian convergent margin event (760-700 Ma), syn-collisional Bou-Azzer magmatism (680-640 Ma), followed by widespread Ediacaran magmatism (620-555 Ma). Each magmatic episode corresponded to a different geodynamic environment and produced different types of magma. Phanerozoic magmatism began with Early Cambrian basaltic (rift?) volcanism, which persisted during the Middle Cambrian, and into the Early Ordovician. This was succeeded by massive Late Devonian and Carboniferous, pre-Variscan tholeiitic and calc-alkaline (Central Morocco) volcanic flows in basins of the Moroccan Meseta. North of the Atlas Paleozoic Transform Zone, the Late Carboniferous Variscan event was accompanied by the emplacement of 330-300 Ma calc-alkaline granitoids in upper crustal shear zones. Post-Variscan alkaline magmatism was associated with the opening of the Permian basins. Mesozoic magmatism began with the huge volumes of magma emplaced around 200 Ma in the Central Atlantic Magmatic Province (CAMP) which was associated with the fragmentation of Pangea and the subsequent rifting of Central Atlantic. CAMP volcanism occurs in all structural domains of Morocco, from the Anti-Atlas to the External Rif domain with a peak activity around 199 Ma. A second Mesozoic magmatic event is represented by mafic lava flows and gabbroic intrusions in

  15. Thermodynamic properties of potassium chloride aqueous solutions (United States)

    Zezin, Denis; Driesner, Thomas


    Potassium chloride is a ubiquitous salt in natural fluids, being the second most abundant dissolved salt in many geological aqueous solutions after sodium chloride. It is a simple solute and strong electrolyte easily dissociating in water, however the thermodynamic properties of KCl aqueous solutions were never correlated with sufficient accuracy for a wide range of physicochemical conditions. In this communication we propose a set of parameters for a Pitzer-type model which allows calculation of all necessary thermodynamic properties of KCl solution, namely excess Gibbs free energy and derived activity coefficient, apparent molar enthalpy, heat capacity and volume, as well as osmotic coefficient and activity of water in solutions. The system KCl-water is one of the best studied aqueous systems containing electrolytes. Although extensive experimental data were collected for thermodynamic properties of these solutions over the years, the accurate volumetric data became available only recently, thus making possible a complete thermodynamic formulation including a pressure dependence of excess Gibbs free energy and derived properties of the KCl-water liquids. Our proposed model is intended for calculation of major thermodynamic properties of KCl aqueous solutions at temperatures ranging from freezing point of a solution to 623 K, pressures ranging from saturated water vapor up to 150 MPa, and concentrations up to the salt saturation. This parameterized model will be further implemented in geochemical software packages and can facilitate the calculation of aqueous equilibrium for reactive transport codes.

  16. Magmatic development of the outer Vøring Margin (United States)

    Breivik, Asbjorn; Faleide, Jan Inge; Mjelde, Rolf; Flueh, Ernst; Murai, Yoshio


    The Vøring Plateau off mid-Norway is a volcanic passive margin, located north of the East Jan Mayen Fracture Zone (EJMFZ). Large volumes of magmatic rocks were emplaced during Early Eocene margin formation. In 2003, an ocean bottom seismometer survey was acquired on the Vøring and Lofoten margins. One profile crosses from the Vøring Plateau to the Vøring Spur, an oceanic plateau north of the EJMFZ. The P-wave data were modeled by ray-tracing in a 2D velocity model of the crust. The process behind the excess magmatism can be estimated by comparing seismic velocity (VP) with igneous thickness (H). This profile and two other profiles farther north show a positive H-VP correlation, consistent with a hot mantle reservoir of finite extent under the margin at breakup. However, during the first two million years, magma production appears to be augmented by a secondary process. By 51-51.5 Ma melting may be caused by elevated mantle temperature alone. Seismic stratigraphy around the Vøring Spur shows at least two inversion events, with the main episode tentatively in the Upper Miocene, apparently through igneous growth to create the up to 15 km crustal thickness. The H-VP correlation of the spur is low, indicating constant and moderate-degree mantle melting not tied to the breakup magmatism. The admittance function between bathymetry and free-air gravity shows that the high is near local isostatic equilibrium, discounting that compressional flexure at the EJMFZ shaped the high. We also find no evidence for the proposed Early Eocene triple junction in the area.

  17. Magmatic carbon dioxide emissions at Mammoth Mountain, California (United States)

    Farrar, Christopher D.; Neil, John M.; Howle, James F.


    Carbon dioxide (CO2) of magmatic origin is seeping out of the ground in unusual quantities at several locations around the flanks of Mammoth Mountain, a dormant volcano in Eastern California. The most recent volcanic activity on Mammoth Mountain was steam eruptions about 600 years ago, but seismic swarms and long-period earthquakes over the past decade are evidence of an active magmatic system at depth. The CO2 emission probably began in 1990 but was not recognized until 1994. Seismic swarms and minor ground deformation during 1989, believed to be results of a shallow intrusion of magma beneath Mammoth Mountain, probably triggered the release of CO2, which persists in 1998. The CO2 gas is at ambient temperatures and emanates diffusely from the soil surface rather than flowing from distinct vents. The CO2 has collected in the soil by displacing air in the pore spaces and reaches concentrations of greater than 95 percent by volume in places. The total area affected by high CO2 concentrations and high CO2 flux from the soil surface was estimated at 60 hectares in 1997. Coniferous forest covering about 40 hectares has been killed by high CO2 concentrations in the root zone. In more than 300 soil-gas samples collected from depths of 0.5 to 2 m in 1995, CO2 concentrations ranged from background levels (less than 1 percent) to greater than 95 percent by volume. At 250 locations, CO2 flux was measured using a closed chamber in 1996; values, in grams per square meter per day, ranged from background (less than 25) to more than 30,000. On the basis of these data, the total emission of magmatic CO2 in 1996 is estimated to be about 530 megagrams per day. Concentrations of CO2 exceeding Occupational Safety and Health Administration standards have been measured in pits dug in soil and snow, in poorly ventilated buildings, and in below-ground valve-boxes around Mammoth Mountain. CO2 concentrations greater than 10 percent in poorly ventilated spaces are not uncommon on some parts

  18. MIPs in Aqueous Environments. (United States)

    Wan, Ying-chun; Ma, Hui-ting; Lu, Bin


    When organic solvent-compatible molecularly imprinted polymers (MIPs) are used in aqueous environment, how to reduce nonspecific binding is a major challenge. By modifying the binding solvents and introducing appropriate washing and elution steps, even relatively hydrophobic MIPs can gain optimal rebinding selectivity in aqueous conditions. Furthermore, water-compatible MIPs that can be used to treat aqueous samples directly have been prepared. The use of hydrophilic co-monomers, the controlled surface modification through controlled radical polymerization, and the new interfacial molecular imprinting methods are different strategies to prepare water-compatible MIPs. By combining MIPs with other techniques, both organic solvent-compatible and water-compatible MIPs can display better functional performances in aqueous conditions. Intensive studies on MIPs in aqueous conditions can provide new MIPs with much-improved compatibilities that will lead to more interesting applications in biomedicine and biotechnology.

  19. Liposomes as potential masking agents in sport doping. Part 1: analysis of phospholipids and sphingomyelins in drugs and biological fluids by aqueous normal-phase liquid chromatography-tandem mass spectrometry. (United States)

    Esposito, Simone; Colicchia, Sonia; de la Torre, Xavier; Mazzarino, Monica; Botrè, Francesco


    In the present work, aqueous normal-phase liquid chromatography coupled to tandem mass spectrometry (LC-MS/MS), in different acquisition modes, was employed for the direct analysis and profiling of nine phospholipid classes (phosphatidic acids, phosphatidylserines, phosphatidylethanolamines, lysophosphatidylethanolamines, phosphatidylglycerols, phosphatidylinositols, phosphatidylcholines, lysophosphatidylcholines, and sphingomyelins) in biological and pharmaceutical matrices. After chromatographic separation by a diol column, detection and elucidation of phospholipid and sphingomyelin classes and molecular species were performed by different scan acquisition modes. For screening analysis, molecular ions [M + H] + were detected in positive precursor ion scan of m/z 184 for the classes of phosphatidylcholines, lyso-phosphatidylcholines and sphingomyelins; while phosphatidylethanolamines and lyso-phosphatidylethanolamines were detected monitoring neutral loss scan of 141 Da; and phosphatidylserines detected using neutral loss scan of 184 Da. Molecular ions [M-H] - were instead acquired in negative precursor ion scan of m/z 153 for the classes of phosphatidic acids and phosphatidylglycerols; and of m/z 241 for the phosphatidylinositols. For the identification of the single molecular species, product ion scan mass spectra of the [M + HCOO] - ions for phosphatidylcholines and [M + H] + ions for the other phospholipids considered were determined for each class and compared with the fragmentation pattern of model phospholipid reference standard. By this approach, nearly 100 phospholipids and sphingomyelins were detected and identified. The optimized method was then used to characterize the phospholipid and sphingomyelin profiles in human plasma and urine samples and in two phospholipid-based pharmaceutical formulations, proving that it also allows to discriminate compounds of endogenous origin from those resulting from the intake of pharmaceutical products

  20. Hydrothermal activity at slow-spreading ridges: variability and importance of magmatic controls (United States)

    Escartin, Javier


    Hydrothermal activity along mid-ocean ridge axes is ubiquitous, associated with mass, chemical, and heat exchanges between the deep lithosphere and the overlying envelopes, and sustaining chemiosynthetic ecosystems at the seafloor. Compared with hydrothermal fields at fast-spreading ridges, those at slow spreading ones show a large variability as their location and nature is controlled or influenced by several parameters that are inter-related: a) tectonic setting, ranging from 'volcanic systems' (along the rift valley floor, volcanic ridges, seamounts), to 'tectonic' ones (rift-bounding faults, oceanic detachment faults); b) the nature of the host rock, owing to compositional heterogeneity of slow-spreading lithosphere (basalt, gabbro, peridotite); c) the type of heat source (magmatic bodies at depth, hot lithosphere, serpentinization reactions); d) and the associated temperature of outflow fluids (high- vs.- low temperature venting and their relative proportion). A systematic review of the distribution and characteristics of hydrothermal fields along the slow-spreading Mid-Atlantic Ridge suggests that long-lived hydrothermal activity is concentrated either at oceanic detachment faults, or along volcanic segments with evidence of robust magma supply to the axis. A detailed study of the magmatically robust Lucky Strike segment suggests that all present and past hydrothermal activity is found at the center of the segment. The association of these fields to central volcanos, and the absence of indicators of hydrothermal activity along the remaining of the ridge segment, suggests that long-lived hydrothermal activity in these volcanic systems is maintained by the enhanced melt supply and the associated magma chamber(s) required to build these volcanic edifices. In this setting, hydrothermal outflow zones at the seafloor are systematically controlled by faults, indicating that hydrothermal fluids in the shallow crust exploit permeable fault zones to circulate. While

  1. Schroedinger fluid

    International Nuclear Information System (INIS)

    Kan, K.K.


    The relationship of nuclear internal flow and collective inertia, the difference of this flow from that of a classical fluid, and the approach of this flow to rigid flow in independent-particle model rotation are elucidated by reviewing the theory of Schroedinger fluid and its implications for collective vibration and rotation. (author)

  2. Hot subduction: Magmatism along the Hunter Ridge, SW Pacific

    International Nuclear Information System (INIS)

    Crawford, A.J.; Verbeeten, A.; Danyushevsky, L.V.; Sigurdsson, I.A.; Maillet, P.; Monzier, M.


    The Hunter 'fracture zone' is generally regarded as a transform plate boundary linking the oppositely dipping Tongan and Vanuatu subduction systems. Dredging along the Hunter Ridge and sampling of its northernmost extent, exposed as the island of Kadavu in Fiji, has yielded a diversity of magmatic suites, including arc tholeiites and high-Ca boninites, high-Mg lavas with some affinities to boninites and some affinities to adakites, and true adakitic lavas associated with remarkable low-Fe, high-Na basalts with 8-16 ppm Nb (herein high-Nb basalts). Lavas which show clear evidence of slab melt involvement in their petrogenesis occur at either end of the Hunter Ridge, whereas the arc tholeiites and high-Ca boninites appear to be restricted to the south central part of the ridge. Mineralogical and whole rock geochemical data for each of these suites are summarized, and a tectono-magmatic model for their genesis and distribution is suggested. Trace element features and radiogenic isotope data for the Hunter Ridge lavas indicate compositions analogue to Pacific MORB-like mantle

  3. Paired Magmatic-Metallogenic Belts in Myanmar - an Andean Analogue? (United States)

    Gardiner, Nicholas; Robb, Laurence; Searle, Michael; Morley, Christopher


    Myanmar (Burma) is richly endowed in precious and base metals, having one of the most diverse collections of natural resources in SE Asia. Its geological history is dominated by the staged closing of Tethys and the suturing of Gondwana-derived continental fragments onto the South China craton during the Mesozoic-Cenozoic. The country is located at a crucial geologic juncture where the main convergent Tethyan collision zone swings south around the Namche Barwa Eastern Himalayan syntaxis. However, despite recent work, the geological and geodynamic history of Myanmar remains enigmatic. Plate margin processes, magmatism, metasomatism and the genesis of mineral deposits are intricately linked, and there has long been recognized a relationship between the distribution of certain mineral deposit types, and the tectonic settings which favour their genesis. A better knowledge of the regional tectonic evolution of a potential exploration jurisdiction is therefore crucial to understanding its minerals prospectivity. This strong association between tectonics and mineralization can equally be applied in reverse. By mapping out the spatial, and temporal, distribution of presumed co-genetic mineral deposits, coupled with an understanding of their collective metallogenetic origin, a better appreciation of the tectonic evolution of a terrane may be elucidated. Identification and categorization of metallotects within a geodynamically-evolving terrane thus provides a complimentary tool to other methodologies (e.g. geochemical, geochronological, structural, geophysical, stratigraphical), for determining the tectonic history and inferred geodynamic setting of that terrane through time. Myanmar is one such study area where this approach can be undertaken. Here are found two near-parallel magmatic belts, which together contain a significant proportion of that country's mineral wealth of tin, tungsten, copper, gold and silver. Although only a few 100 km's apart, these belts exhibit a

  4. Intrusion of Magmatic Bodies Into the Continental Crust: 3-D Numerical Models (United States)

    Gorczyk, Weronika; Vogt, Katharina


    Magma intrusion is a major material transfer process in the Earth's continental crust. Yet the mechanical behavior of the intruding magma and its host are a matter of debate. In this study we present a series of numerical thermomechanical simulations on magma emplacement in 3-D. Our results demonstrate the response of the continental crust to magma intrusion. We observe change in intrusion geometries between dikes, cone sheets, sills, plutons, ponds, funnels, finger-shaped and stock-like intrusions, and injection time. The rheology and temperature of the host are the main controlling factors in the transition between these different modes of intrusion. Viscous deformation in the warm and deep crust favors host rock displacement and plutons at the crust-mantle boundary forming deep-seated plutons or magma ponds in the lower to middle crust. Brittle deformation in the cool and shallow crust induces cone-shaped fractures in the host rock and enables emplacement of finger- or stock-like intrusions at shallow or intermediate depth. Here the passage of magmatic and hydrothermal fluids from the intrusion through the fracture pattern may result in the formation of ore deposits. A combination of viscous and brittle deformation forms funnel-shaped intrusions in the middle crust. Intrusion of low-density magma may more over result in T-shaped intrusions in cross section with magma sheets at the surface.

  5. Micas at magmatic and hydrothermal stages in the environment of the Cerro Verde Santa Rosa porphyry copper type deposit

    Energy Technology Data Exchange (ETDEWEB)

    Le Bel, L


    The chemical composition of biotites and sericites from the Cerro Verde porphyry copper type deposit have been investigated in detail, using an electron microprobe. The main results of the study are: Al/sup vi/ and Ti contents of biotites of magmatic as well as hydrothermal origin may be related to the temperature of crystallization estimed by independent methods. On the other hand the Mg/Fe and Mg/(Mg + Fe) ratios are almost constant. This fact is interpreted in terms of fO/sub 2/; sericites have a phengitic composition in which the solubilities of the two end-members celadonite and paragonite are controlled by a fluid phase under P, T conditions that could be estimated.

  6. Flow of mantle fluids through the ductile lower crust: Heliumisotope trends

    Energy Technology Data Exchange (ETDEWEB)

    Kennedy, B. Mack; van Soest, Matthijs C.


    Heat and mass are injected into the shallow crust when mantle fluids are able to flow through the ductile lower crust. Minimum 3He/4He ratios in surface fluids from the northern Basin and Range province, western North America increase systematically from low, crustal values in the east to high, mantle values in the west, a regional trend that correlates with the rates of active crustal deformation. The highest ratios occur where the extension and shear strain rates are greatest. The correspondence of helium isotope ratios and active trans-tensional deformation indicates a deformation enhanced permeability and that mantle fluids can penetrate the ductile lithosphere in regions even where there is no significant magmatism. Superimposed on the regional trend are local, high-{sup 3}He/{sup 4}He anomalies signifying hidden magmatic activity and/or deep fluid production with locally enhanced permeability, identifying zones with high resource potential, particularly for geothermal energy development.

  7. Variability of orogenic magmatism during Mediterranean-style continental collisions : A numerical modelling approach

    NARCIS (Netherlands)

    Andrić, N.; Vogt, K.; Matenco, L.; Cvetković, V.; Cloetingh, S.; Gerya, T.

    The relationship between magma generation and the tectonic evolution of orogens during subduction and subsequent collision requires self-consistent numerical modelling approaches predicting volumes and compositions of the produced magmatic rocks. Here, we use a 2D magmatic-thermomechanical numerical

  8. Magmatic activity stages of the El'brus volcanic center (Great Caucasus): isotope geochronological data

    International Nuclear Information System (INIS)

    Chernyshev, I.V.; Lebedev, V.A.; Bubnov, S.N.; Arakelyants, M.M.; Gol'tsman, Yu.V.


    The age of volcanites in the Elbrus volcanic center was determined by the methods of K-Ar- and Rb-Sr-dating to ascertain stages of magmatic activity in the area. The data obtained suggest existence of at least two stages of magmatic activity: Middle Neopleistocene (225-180 thous. years) and Late Neopleistocene-Holocene ( [ru

  9. A Palaeoproterozoic tectono-magmatic lull as a potential trigger for the supercontinent cycle (United States)

    Spencer, Christopher J.; Murphy, J. Brendan; Kirkland, Christopher L.; Liu, Yebo; Mitchell, Ross N.


    The geologic record exhibits periods of active and quiescent geologic processes, including magmatism, metamorphism and mineralization. This apparent episodicity has been ascribed either to bias in the geologic record or fundamental changes in geodynamic processes. An appraisal of the global geologic record from about 2.3 to 2.2 billion years ago demonstrates a Palaeoproterozoic tectono-magmatic lull. During this lull, global-scale continental magmatism (plume and arc magmatism) and orogenic activity decreased. There was also a lack of passive margin sedimentation and relative plate motions were subdued. A global compilation of mafic igneous rocks demonstrates that this episode of magmatic quiescence was terminated about 2.2 billion years ago by a flare-up of juvenile magmatism. This post-lull magmatic flare-up is distinct from earlier such events, in that the material extracted from the mantle during the flare-up yielded significant amounts of continental material that amalgamated to form Nuna — Earth's first hemispheric supercontinent. We posit that the juvenile magmatic flare-up was caused by the release of significant thermal energy that had accumulated over some time. This flux of mantle-derived energy could have provided a mechanism for dramatic growth of continental crust, as well as the increase in relative plate motions required to complete the transition to modern plate tectonics and the supercontinent cycle. These events may also be linked to Palaeoproterozoic atmospheric oxygenation and equilibration of the carbon cycle.

  10. Magmatic control along a strike-slip volcanic arc: The central Aeolian arc (Italy)

    KAUST Repository

    Ruch, Joel; Vezzoli, L.; De Rosa, R.; Di Lorenzo, R.; Acocella, V


    -slip motion; consistent with an E-W extension direction, with minor dextral and sinistral shear. Our data highlight six eruptive periods during the last 55 ka, which allow considering both islands as a single magmatic system, in which tectonic and magmatic

  11. Microfluidics with fluid walls. (United States)

    Walsh, Edmond J; Feuerborn, Alexander; Wheeler, James H R; Tan, Ann Na; Durham, William M; Foster, Kevin R; Cook, Peter R


    Microfluidics has great potential, but the complexity of fabricating and operating devices has limited its use. Here we describe a method - Freestyle Fluidics - that overcomes many key limitations. In this method, liquids are confined by fluid (not solid) walls. Aqueous circuits with any 2D shape are printed in seconds on plastic or glass Petri dishes; then, interfacial forces pin liquids to substrates, and overlaying an immiscible liquid prevents evaporation. Confining fluid walls are pliant and resilient; they self-heal when liquids are pipetted through them. We drive flow through a wide range of circuits passively by manipulating surface tension and hydrostatic pressure, and actively using external pumps. Finally, we validate the technology with two challenging applications - triggering an inflammatory response in human cells and chemotaxis in bacterial biofilms. This approach provides a powerful and versatile alternative to traditional microfluidics.The complexity of fabricating and operating microfluidic devices limits their use. Walsh et al. describe a method in which circuits are printed as quickly and simply as writing with a pen, and liquids in them are confined by fluid instead of solid walls.

  12. Basin scale permeability and thermal evolution of a magmatic hydrothermal system (United States)

    Taron, J.; Hickman, S. H.; Ingebritsen, S.; Williams, C.


    Large-scale hydrothermal systems are potentially valuable energy resources and are of general scientific interest due to extreme conditions of stress, temperature, and reactive chemistry that can act to modify crustal rheology and composition. With many proposed sites for Enhanced Geothermal Systems (EGS) located on the margins of large-scale hydrothermal systems, understanding the temporal evolution of these systems contributes to site selection, characterization and design of EGS. This understanding is also needed to address the long-term sustainability of EGS once they are created. Many important insights into heat and mass transfer within natural hydrothermal systems can be obtained through hydrothermal modeling assuming that stress and permeability structure do not evolve over time. However, this is not fully representative of natural systems, where the effects of thermo-elastic stress changes, chemical fluid-rock interactions, and rock failure on fluid flow and thermal evolution can be significant. The quantitative importance of an evolving permeability field within the overall behavior of a large-scale hydrothermal system is somewhat untested, and providing such a parametric understanding is one of the goals of this study. We explore the thermal evolution of a sedimentary basin hydrothermal system following the emplacement of a magma body. The Salton Sea geothermal field and its associated magmatic system in southern California is utilized as a general backdrop to define the initial state. Working within the general framework of the open-source scientific computing initiative OpenGeoSys (, we introduce full treatment of thermodynamic properties at the extreme conditions following magma emplacement. This treatment utilizes a combination of standard Galerkin and control-volume finite elements to balance fluid mass, mechanical deformation, and thermal energy with consideration of local thermal non-equilibrium (LTNE) between fluids and solids

  13. Aqueous lithium air batteries (United States)

    Visco, Steven J.; Nimon, Yevgeniy S.; De Jonghe, Lutgard C.; Petrov, Alexei; Goncharenko, Nikolay


    Aqueous Li/Air secondary battery cells are configurable to achieve high energy density and prolonged cycle life. The cells include a protected a lithium metal or alloy anode and an aqueous catholyte in a cathode compartment. The aqueous catholyte comprises an evaporative-loss resistant and/or polyprotic active compound or active agent that partakes in the discharge reaction and effectuates cathode capacity for discharge in the acidic region. This leads to improved performance including one or more of increased specific energy, improved stability on open circuit, and prolonged cycle life, as well as various methods, including a method of operating an aqueous Li/Air cell to simultaneously achieve improved energy density and prolonged cycle life.

  14. Magmatic and non-magmatic history of the Tyrrhenain backarc Basin: new constraints from geophysical and geological data (United States)

    Prada, Manel; Sallares, Valenti; Ranero, Cesar R.; Zitellini, Nevio; Grevemeyer, Ingo


    The Western Mediterranean region is represented by a system of backarc basins associated to slab rollback and retreat of subduction fronts. The onset of formation of these basins took place in the Oligocene with the opening of the Valencia Through, the Liguro-Provençal and the Algero-Balearic basins, and subsequently, by the formation of the Alboran and Tyrrhenian basins during the early Tortonian. The opening of these basins involved rifting that in some regions evolved until continental break up, that is the case of the Liguro-Provençal, Algero-Balearic, and Tyrrhenian basins. Previous geophysical works in the first two basins revealed a rifted continental crust that transitions to oceanic crust along a region where the basement nature is not clearly defined. In contrast, in the Tyrrhenian Basin, recent analysis of new geophysical and geological data shows a rifted continental crust that transitions along a magmatic-type crust to a region where the mantle is exhumed and locally intruded by basalts. This basement configuration is at odds with current knowledge of rift systems and implies rapid variations of strain and magma production. To understand these processes and their implications on lithospheric backarc extension we first need to constrain in space and time these observations by further analysis of geophysical and geological data. Here we present two analyses; the first one is focused on the spatial variability of magmatism along the Cornaglia Terrace axis, where magmatic-type crust has been previously interpreted. The comparison of three different seismic refraction transects, acquired across the basin axis from North to South, allows to infer that the highest magmatic activity occurred beneath the central and most extended region of the terrace; while it was less important in the North and almost non-existent in the South. The second analysis focuses on the presence of exhumed mantle in the deepest region of the Tyrrhenian, previously interpreted by

  15. The magmatism and metamorphism at the Malayer area, Western Iran (United States)

    Ahadnejad, V.; Valizadeh, M. V.; Esmaeily, D.


    The Malayer area is located in the NW-SE aligned Sanandaj-Sirjan metamorphic belt, western Iran and consists mainly of Mesozoic schists so-called Hamadan Phyllites, Jurassic to Tertiary intrusive rocks and related contact metamorphic aureoles, aplites and pegmatites. The Sanandj-Sirjan Zone is produced by oblique collisional event between Arabian plate and Central Iran microcontinent. Highest level of regional metamorphism in the area is greenschist facies and injection of felsic magmas is caused contact metamorphism. Magmatism is consist of a general northwest trend large felsic to intermediate intrusive bodies. The main trend of structural features i.e. faults, fractures and other structural features is NW-SE. The Malayer granitoid complex is ellipsoid in shape and has NW-SE foliation especially at the corners of the intrusions. Petrography of the magmatic rocks revealed recrystallization of quartz and feldspars, bending of biotite, and aligment of minerals paralle to the main trend of magmatic and metamorphic country rocks. These indicated that intrusion of felsic magma is coincide to the regional metamorphism and is syn-tectoinc. Non-extensive contact metamorphism aureoles and rareness of pegmatite and aplite in the area are interpreted as injection of felsic magmas into the high-strain metamorphic zone. The regional metamorphic rocks mainly consist of meta-sandstone, slate, phyllite, schist. These gray to dark metasedimentary rocks are consist of quartz, muscovite, turmaline, epidote, biotite and chlorite. Sheeted minerals form extended schistosity and study of porphyroblast-matrix relationships shows that injection of granitic magma into the country rocks is syn to post-tectonic. Syn-tectonic indicating porphyroblast growth synchronous with the development of the external fabric. The thermal contact area of the granite can be observed in the contact margin of granite and regional metamorphic rocks, where it produced hornfelses, andalusit-garnet schists and

  16. Water-rock interaction in the magmatic-hydrothermal system of Nisyros Island (Greece) (United States)

    Ambrosio, Michele; Doveri, Marco; Fagioli, Maria Teresa; Marini, Luigi; Principe, Claudia; Raco, Brunella


    In this work, we investigated the water-rock interaction processes taking place in the hydrothermal reservoir of Nisyros through both: (1) a review of the hydrothermal mineralogy encountered in the deep geothermal borehole Nisyros-2; and (2) a comparison of the analytically-derived redox potentials and acidities of fumarolic-related liquids, with those controlled by redox buffers and pH buffers, involving hydrothermal mineral phases. The propylitic zone met in the deep geothermal borehole Nisyros-2, from 950 to 1547 m (total depth), is characterised by abundant, well crystallised epidote, adularia, albite, quartz, pyrite, chlorite, and sericite-muscovite, accompanied by less abundant anhydrite, stilpnomelane, wairakite, garnet, tremolite and pyroxene. These hydrothermal minerals were produced in a comparatively wide temperature range, from 230 to 300 °C, approximately. Hydrothermal assemblages are well developed from 950 to 1360 m, whereas they are less developed below this depth, probably due to low permeability. Based on the RH values calculated for fumarolic gases and for the deep geothermal fluids of Nisyros-1 and Nisyros-2 wells, redox equilibrium with the (FeO)/(FeO 1.5) rock buffer appears to be closely attained throughout the hydrothermal reservoir of Nisyros. This conclusion may be easily reconciled with the nearly ubiquitous occurrence of anhydrite and pyrite, since RH values controlled by coexistence of anhydrite and pyrite can be achieved by gas separation. The pH of the liquids feeding the fumarolic vents of Stephanos and Polybote Micros craters was computed, by means of the EQ3 code, based on the Cl- δD relationship which is constrained by the seawater-magmatic water mixing occurring at depth in the hydrothermal-magmatic system of Nisyros. The temperature dependence of analytically-derived pH values for the reservoir liquids feeding the fumarolic vents of Stephanos and Polybote Micros craters suggests that some unspecified pH buffer fixes the

  17. Fluid dynamics

    CERN Document Server

    Bernard, Peter S


    This book presents a focused, readable account of the principal physical and mathematical ideas at the heart of fluid dynamics. Graduate students in engineering, applied math, and physics who are taking their first graduate course in fluids will find this book invaluable in providing the background in physics and mathematics necessary to pursue advanced study. The book includes a detailed derivation of the Navier-Stokes and energy equations, followed by many examples of their use in studying the dynamics of fluid flows. Modern tensor analysis is used to simplify the mathematical derivations, thus allowing a clearer view of the physics. Peter Bernard also covers the motivation behind many fundamental concepts such as Bernoulli's equation and the stream function. Many exercises are designed with a view toward using MATLAB or its equivalent to simplify and extend the analysis of fluid motion including developing flow simulations based on techniques described in the book.

  18. Magmatism and petroleum exploration in the Brazilian Paleozoic basins

    Energy Technology Data Exchange (ETDEWEB)

    Thomaz Filho, Antonio; Antonioli, Luzia [Universidade do Estado do Rio de Janeiro, Faculdade de Geologia, Rua Sao Francisco Xavier, no 524/2030, CEP 20550-900, Rio de Janeiro, RJ (Brazil); Mizusaki, Ana Maria Pimentel [Universidade Federal do Rio Grande do Sul, Instituto de Geociencias, Avenida Bento Goncalves, no 9500, Campus do Vale, CEP 91509-900, Porto Alegre, RS (Brazil)


    Petroleum exploration in the Paleozoic sedimentary basins of Brazil has proven very challenging for explorationists. Except for the Solimoes Basin, in which transcurrent tectonism formed prospective structural highs, Brazilian Paleozoic basins lack intense structural deformation, and hence the detection and prospecting of place is often difficult. Magmatic intrusive and associated rocks in all these basins have traditionally been considered heat sources and hydrocarbon traps. The role of tholeiitic basic dikes in the generation, migration and accumulation of petroleum in the Anhembi oil occurrence (Sao Paulo State) is discussed herein. It follows that similar geological settings in other Paleozoic basins can be regarded as promising sites for oil accumulation that warrant investigation via modern geological and geophysical methods. (author)

  19. A review of aqueous foam in microscale. (United States)

    Anazadehsayed, Abdolhamid; Rezaee, Nastaran; Naser, Jamal; Nguyen, Anh V


    In recent years, significant progress has been achieved in the study of aqueous foams. Having said this, a better understanding of foam physics requires a deeper and profound study of foam elements. This paper reviews the studies in the microscale of aqueous foams. The elements of aqueous foams are interior Plateau borders, exterior Plateau borders, nodes, and films. Furthermore, these elements' contribution to the drainage of foam and hydraulic resistance are studied. The Marangoni phenomena that can happen in aqueous foams are listed as Marangoni recirculation in the transition region, Marangoni-driven flow from Plateau border towards the film in the foam fractionation process, and Marangoni flow caused by exposure of foam containing photosurfactants under UV. Then, the flow analysis of combined elements of foam such as PB-film along with Marangoni flow and PB-node are studied. Next, we contrast the behavior of foams in different conditions. These various conditions can be perturbation in the foam structure caused by injected water droplets or waves or using a non-Newtonian fluid to make the foam. Further review is about the effect of oil droplets and particles on the characteristics of foam such as drainage, stability and interfacial mobility. Copyright © 2018 Elsevier B.V. All rights reserved.

  20. Uranium metallogeny, magmatism and structure in southeast China

    International Nuclear Information System (INIS)

    Simpson, P.R.


    Granite magmatism and the associated uranium metallogeny in southeast China are considered in relation to a plate tectonic model previously developed for Jiangxi Province which envisages the suturing of three separate continental fault blocks or plates which are thought to have existed as separate continental microplates until the Permian, namely the Sino-Korean, Yangtze and South China Plates. In Jiangxi Province, most of the granitic magmas, including those considered in the paper to be associated with U ore deposits, can be shown to be systematically distributed in relation to the postulated destructive plate margins which are thought to have existed along all the plate boundaries between the continental microplates. The granitic intrusions in Jiangxi range from those more proximal to the inferred location of the subduction zone in a modified Andean type model, such as porphyries of Cu, Cu-Mo and W-Cu type, to more distal granites of U-W-Sn-F-Nb-REE type. They range in age from Indosinian to Yanshanian (but mainly the latter) and are intruded in tensional settings along major lithospheric fracture zones, with sinistral strike slip, many of which continued to move both during and after granite emplacement. These U, W, Sn, F, Nb and REE rich metalliferous granites, which all intruded post-tectonically long after the principal metamorphic events, which are Jinningian (Late Proterozoic on the Yangtze Plate) and Caledonian (South China Plate), and the younger suturing events, are considered in the study to be essentially of juvenile magmatic rather than crustal origin. Such a tectonic model helps to account for the well developed and structurally zoned metallogeny of southeast China and the genesis of the Southeast China Uranium Province. Selected examples of U ore deposits which occur within the Southeast China Uranium Province are considered in order to develop the basis for a genetic model for U which would be more generally applicable to this region and possibly

  1. Antidiarrhoeal activity of aqueous extract of Combretum sericeum ...

    African Journals Online (AJOL)

    The antidiarrhoeal activity of aqueous extract of Combretum sericeum roots was evaluated in rats. Studies were carried out on castor oil induced diarrhea, gastrointestinal motility and castor oil induced fluid accumulation. The extract (25 and 50 mg/kg) causes a dose dependent protection against castor oil induced diarrhea ...

  2. Ancient aqueous environments at Endeavour crater, Mars (United States)

    Arvidson, R. E.; Squyres, S. W.; Bell, J.F.; Catalano, J.G.; Clark, B. C.; Crumpler, L.S.; de Souza, P.A.; Fairén, A.G.; Farrand, W. H.; Fox, V.K.; Gellert, Ralf; Ghosh, A.; Golombeck, M.P.; Grotzinger, J.P.; Guinness, E.A.; Herkenhoff, Kenneth E.; Jolliff, B.L.; Knoll, A.H.; Li, R.; McLennan, S.M.; Ming, D. W.; Mittlefehldt, D. W.; Moore, Johnnie N.; Morris, R.V.; Murchie, S.L.; Parker, T.J.; Paulsen, G.; Rice, J.W.; Ruff, S.W.; Smith, M.D.; Wolff, M.J.


    Opportunity has investigated in detail rocks on the rim of the Noachian age Endeavour crater, where orbital spectral reflectance signatures indicate the presence of Fe+3-rich smectites. The signatures are associated with fine-grained, layered rocks containing spherules of diagenetic or impact origin. The layered rocks are overlain by breccias, and both units are cut by calcium sulfate veins precipitated from fluids that circulated after the Endeavour impact. Compositional data for fractures in the layered rocks suggest formation of Al-rich smectites by aqueous leaching. Evidence is thus preserved for water-rock interactions before and after the impact, with aqueous environments of slightly acidic to circum-neutral pH that would have been more favorable for prebiotic chemistry and microorganisms than those recorded by younger sulfate-rich rocks at Meridiani Planum.

  3. The Magmatic Budget of Rifted Margins: is it Related to Inheritance? (United States)

    Manatschal, G.; Tugend, J.; Gillard, M.; Sauter, D.


    High quality reflection and refraction seismic surveys show a divergent style of margin architecture often referred to as magma-poor or magma-rich. More detailed studies show, however, that the evolution of these margins can be similar, despite the variable quantity and distribution of magmatism. These observations suggest that simple relations between magmatic and extensional systems are inappropriate to describe the magmatic history of rifted margins. Moreover, the study of magmatic additions indicates that they may occur, prior to, during or after lithospheric breakup. Furthermore, the observation that the magmatic budget may change very abruptly along strike and across the margin is difficult to reconcile with the occurrence of plumes or other deep-seated large-scale mantle phenomena only. These overall observations result in questions on how magmatic and tectonic processes are interacting during rifting and lithospheric breakup and on how far the inherited composition and temperature of the decompressing mantle may control the magmatic budget during rifting. In our presentation we will review examples from present-day and fossil rifted margins to discuss their structural and magmatic evolution and whether they are considered as magma-rich or magma-poor. The key questions that we aim to address are: 1) whether decompression melting is the driving force, or rather the consequence of extension, 2) how far the magmatic budget is controlled by inherited mantle composition and temperature, and 3) how important magma storage is during initial stages of rifting. Eventually, we will discuss to what extent the evolution of margins may reflect the interplay between inheritance (innate/"genetic code") and the actual physical processes (acquired/external factors).

  4. Magmatism and Epithermal Gold-Silver Deposits of the Southern Ancestral Cascade Arc, Western Nevada and Eastern California (United States)

    John, David A.; du Bray, Edward A.; Henry, Christopher D.; Vikre, Peter


    Many epithermal gold-silver deposits are temporally and spatially associated with late Oligocene to Pliocene magmatism of the southern ancestral Cascade arc in western Nevada and eastern California. These deposits, which include both quartz-adularia (low- and intermediate-sulfidation; Comstock Lode, Tonopah, Bodie) and quartz-alunite (high-sulfidation; Goldfield, Paradise Peak) types, were major producers of gold and silver. Ancestral Cascade arc magmatism preceded that of the modern High Cascades arc and reflects subduction of the Farallon plate beneath North America. Ancestral arc magmatism began about 45 Ma, continued until about 3 Ma, and extended from near the Canada-United States border in Washington southward to about 250 km southeast of Reno, Nevada. The ancestral arc was split into northern and southern segments across an inferred tear in the subducting slab between Mount Shasta and Lassen Peak in northern California. The southern segment extends between 42°N in northern California and 37°N in western Nevada and was active from about 30 to 3 Ma. It is bounded on the east by the northeast edge of the Walker Lane. Ancestral arc volcanism represents an abrupt change in composition and style of magmatism relative to that in central Nevada. Large volume, caldera-forming, silicic ignimbrites associated with the 37 to 19 Ma ignimbrite flareup are dominant in central Nevada, whereas volcanic centers of the ancestral arc in western Nevada consist of andesitic stratovolcanoes and dacitic to rhyolitic lava domes that mostly formed between 25 and 4 Ma. Both ancestral arc and ignimbrite flareup magmatism resulted from rollback of the shallowly dipping slab that began about 45 Ma in northeast Nevada and migrated south-southwest with time. Most southern segment ancestral arc rocks have oxidized, high potassium, calc-alkaline compositions with silica contents ranging continuously from about 55 to 77 wt%. Most lavas are porphyritic and contain coarse plagioclase

  5. Comparison of the distribution of large magmatic centers on Earth, Venus, and Mars (United States)

    Crumpler, L. S.


    Volcanism is widely distributed over the surfaces of the major terrestrial planets: Venus, Earth, and Mars. Anomalous centers of magmatic activity occur on each planet and are characterized by evidence for unusual concentrations of volcanic centers, long-lived activity, unusual rates of effusion, extreme size of volcanic complexes, compositionally unusual magmatism, and evidence for complex geological development. The purpose of this study is to compare the characteristics and distribution of these magmatic anomalies on Earth, Venus, and Mars in order to assess these characteristics as they may relate to global characteristics and evolution of the terrestrial planets.

  6. Fluid Shifts (United States)

    Stenger, M. B.; Hargens, A. R.; Dulchavsky, S. A.; Arbeille, P.; Danielson, R. W.; Ebert, D. J.; Garcia, K. M.; Johnston, S. L.; Laurie, S. S.; Lee, S. M. C.; hide


    Introduction. NASA's Human Research Program is focused on addressing health risks associated with long-duration missions on the International Space Station (ISS) and future exploration-class missions beyond low Earth orbit. Visual acuity changes observed after short-duration missions were largely transient, but now more than 50 percent of ISS astronauts have experienced more profound, chronic changes with objective structural findings such as optic disc edema, globe flattening and choroidal folds. These structural and functional changes are referred to as the visual impairment and intracranial pressure (VIIP) syndrome. Development of VIIP symptoms may be related to elevated intracranial pressure (ICP) secondary to spaceflight-induced cephalad fluid shifts, but this hypothesis has not been tested. The purpose of this study is to characterize fluid distribution and compartmentalization associated with long-duration spaceflight and to determine if a relation exists with vision changes and other elements of the VIIP syndrome. We also seek to determine whether the magnitude of fluid shifts during spaceflight, as well as any VIIP-related effects of those shifts, are predicted by the crewmember's pre-flight status and responses to acute hemodynamic manipulations, specifically posture changes and lower body negative pressure. Methods. We will examine a variety of physiologic variables in 10 long-duration ISS crewmembers using the test conditions and timeline presented in the figure below. Measures include: (1) fluid compartmentalization (total body water by D2O, extracellular fluid by NaBr, intracellular fluid by calculation, plasma volume by CO rebreathe, interstitial fluid by calculation); (2) forehead/eyelids, tibia, and calcaneus tissue thickness (by ultrasound); (3) vascular dimensions by ultrasound (jugular veins, cerebral and carotid arteries, vertebral arteries and veins, portal vein); (4) vascular dynamics by MRI (head/neck blood flow, cerebrospinal fluid

  7. Aqueous Boric acid injection facility of PWR type reactor

    International Nuclear Information System (INIS)

    Matsuoka, Tsuyoshi; Iwami, Masao.


    If a rupture should be caused in a secondary system of a PWR type reactor, pressure of a primary coolant recycling system is lowered, and a back flow check valve is opened in response to the lowering of the pressure. Then, low temperature aqueous boric acid in the lower portion of a pressurized tank is flown into the primary coolant recycling system based on the pressure difference, and the aqueous boric acid reaches the reactor core together with coolants to suppress reactivity. If the injection is continued, high temperature aqueous boric acid in the upper portion boils under a reduced pressure, further urges the low temperature aqueous boric acid in the lower portion by the steam pressure and injects the same to the primary system. The aqueous boric acid stream from the pressurized tank flowing by self evaporation of the high temperature aqueous boric acid itself is rectified by a rectifying device to prevent occurrence of vortex flow, and the steam is injected in a state of uniform stream. When the pressure in the pressurized tank is lowered, a bypass valve is opened to introduce the high pressure fluid of primary system into the pressurized tank to keep the pressure to a predetermined value. When the pressure in the pressurized tank is elevated to higher than the pressure of the primary system, a back flow check valve is opened, and high pressure aqueous boric acid is flown out of the pressurized tank to keep the pressure to a predetermined value. (N.H.)

  8. Fluid mechanics

    International Nuclear Information System (INIS)

    Granger, R.A.


    This text offers the most comprehensive approach available to fluid mechanics. The author takes great care to insure a physical understanding of concepts grounded in applied mathematics. The presentation of theory is followed by engineering applications, helping students develop problem-solving skills from the perspective of a professional engineer. Extensive use of detailed examples reinforces the understanding of theoretical concepts

  9. Physical and chemical properties of fluid and melt inclusions of the Lagoa Real uraniferous albitites (Brazil)

    International Nuclear Information System (INIS)

    Chaves, Alexandre de Oliveira


    Data of melt and fluid inclusions obtained by LA-ICP-MS and microthermometry techniques represent an important investigation complement to understand geological processes which took place in Lagoa Real uraniferous albitites (Brazil). Melt inclusions found in augite structure, which reveals the previous presence of U in the syenitic magma. Primary fluid inclusions in magmatic augite of the albitites contain Na, denoting once more its presence in original magma. The formation of andradite from augite during shear events that generated the metamorphosed syenite (uraniferous albitite) was certified by the ICP-MS signals and uranium released by magmatic titanite (U source mineral)during the 1.9 Ga metamorphism was recorded in the fluid inclusions found in andradite, mineral that was formed in this same metamorphic event which recrystallized titanite crystals. Such uranium was responsible by precipitation of the disseminated uraninite found inside andradite. (author)

  10. Basalt Reactivity Variability with Reservoir Depth in Supercritical CO2 and Aqueous Phases

    Energy Technology Data Exchange (ETDEWEB)

    Schaef, Herbert T.; McGrail, B. Peter; Owen, Antionette T.


    Long term storage of CO{sub 2} in geologic formations is currently considered the most attractive option to reduce greenhouse gas emissions while continuing to utilize fossil fuels for energy production. Injected CO{sub 2} is expected to reside as a buoyant water-saturated supercritical fluid in contact with reservoir rock, the caprock system, and related formation waters. As was reported for the first time at the GHGT-9 conference, experiments with basalts demonstrated surprisingly rapid carbonate mineral formation occurring with samples suspended in the scCO{sub 2} phase. Those experiments were limited to a few temperatures and CO{sub 2} pressures representing relatively shallow (1 km) reservoir depths. Because continental flood basalts can extend to depths of 5 km or more, in this paper we extend the earlier results across a pressure-temperature range representative of these greater depths. Different basalt samples, including well cuttings from the borehole used in a pilot-scale basalt sequestration project (Eastern Washington, U.S.) and core samples from the Central Atlantic Magmatic Province (CAMP), were exposed to aqueous solutions in equilibrium with scCO{sub 2} and water-rich scCO{sub 2} at six different pressures and temperatures for select periods of time (30 to 180 days). Conditions corresponding to a shallow injection of CO{sub 2} (7.4 MPa, 34 C) indicate limited reactivity with basalt; surface carbonate precipitates were not easily identified on post-reacted basalt grains. Basalts exposed under identical times appeared increasingly more reacted with simulated depths. Tests, conducted at higher pressures (12.0 MPa) and temperatures (55 C), reveal a wide variety of surface precipitates forming in both fluid phases. Under shallow conditions tiny clusters of aragonite needles began forming in the wet scCO{sub 2} fluid, whereas in the CO{sub 2} saturated water, cation substituted calcite developed thin radiating coatings. Although these types of coatings

  11. Hydrothermal plume anomalies over the southwest Indian ridge: magmatic control (United States)

    Yue, X.; Li, H.; Tao, C.; Ren, J.; Zhou, J.; Chen, J.; Chen, S.; Wang, Y.


    Here we firstly reported the extensive survey results of the hydrothermal activity along the ultra-slow spreading southwest Indian ridge (SWIR). The study area is located at segment 27, between the Indomed and Gallieni transform faults, SWIR. The seismic crustal thickness reaches 9.5km in this segment (Li et al., 2015), which is much thicker than normal crustal. The anomaly thickened crust could be affected by the Crozet hotspot or highly focused melt delivery from the mantle. The Duanqiao hydrothermal field was reported at the ridge valley of the segment by Tao et al (2009). The Deep-towed Hydrothermal Detection System (DHDS) was used to collect information related with hydrothermal activity, like temperature, turbidity, oxidation-reduction potential (ORP) and seabed types. There are 15 survey lines at the interval of 2 to 3 km which are occupied about 1300 km2 in segment 27. After processing the raw data, including wiping out random noise points, 5-points moving average processing and subtracting the ambient, we got anomalous Nephelometric Turbidity Units values (ΔNTU). And dE/dt was used to identify the ORP anomalous as the raw data is easily influenced by electrode potentials drifting (Baker et al., 2016). According to the results of water column turbidity and ORP distributions, we confirmed three hydrothermal anomaly fields named A1, A2 and A3. The three fields are all located in the western part of the segment. The A1 field lies on the ridge valley, west side of Duanqiao field. The A2 and A3 field lie on the northern and southern of the ridge valley, respectively. We propose that recent magmatic activity probably focus on the western part of segment 27.And the extensive distribution of hydrothermal plume in the segment is the result of the discrete magma intrusion. References Baker E T, et al. How many vent fields? New estimates of vent field populations on ocean ridges from precise mapping of hydrothermal discharge locations. EPSL, 2016, 449:186-196. Li J

  12. Geophysical Observations Supporting Research of Magmatic Processes at Icelandic Volcanoes (United States)

    Vogfjörd, Kristín. S.; Hjaltadóttir, Sigurlaug; Roberts, Matthew J.


    Magmatic processes at volcanoes on the boundary between the European and North American plates in Iceland are observed with in-situ multidisciplinary geophysical networks owned by different national, European or American universities and research institutions, but through collaboration mostly operated by the Icelandic Meteorological Office. The terrestrial observations are augmented by space-based interferometric synthetic aperture radar (InSAR) images of the volcanoes and their surrounding surface. Together this infrastructure can monitor magma movements in several volcanoes from the base of the crust up to the surface. The national seismic network is sensitive enough to detect small scale seismicity deep in the crust under some of the voclanoes. High resolution mapping of this seismicity and its temporal progression has been used to delineate the track of the magma as it migrates upwards in the crust, either to form an intrusion at shallow levels or to reach the surface in an eruption. Broadband recording has also enabled capturing low frequency signals emanating from magmatic movements. In two volcanoes, Eyjafjallajökull and Katla, just east of the South Iceland Seismic Zone (SISZ), seismicity just above the crust-mantle boundary has revealed magma intruding into the crust from the mantle below. As the magma moves to shallower levels, the deformation of the Earth‘s surface is captured by geodetic systems, such as continuous GPS networks, (InSAR) images of the surface and -- even more sensitive to the deformation -- strain meters placed in boreholes around 200 m below the Earth‘s surface. Analysis of these signals can reveal the size and shape of the magma as well as the temporal evolution. At near-by Hekla volcano flanking the SISZ to the north, where only 50% of events are of M>1 compared to 86% of earthquakes in Eyjafjallajökull, the sensitivity of the seismic network is insufficient to detect the smallest seismicity and so the volcano appears less

  13. Magmatic and fragmentation controls on volcanic ash surface chemistry (United States)

    Ayris, Paul M.; Diplas, Spyros; Damby, David E.; Hornby, Adrian J.; Cimarelli, Corrado; Delmelle, Pierre; Scheu, Bettina; Dingwell, Donald B.


    The chemical effects of silicate ash ejected by explosive volcanic eruptions on environmental systems are fundamentally mediated by ash particle surfaces. Ash surfaces are a composite product of magmatic properties and fragmentation mechanisms, as well as in-plume and atmospheric alteration processes acting upon those surfaces during and after the eruption. Recent attention has focused on the capacity of alteration processes to shape ash surfaces; most notably, several studies have utilised X-ray photoelectron spectroscopy (XPS), a technique probing the elemental composition and coordination state of atoms within the top 10 nm of ash surfaces, to identify patterns of elemental depletions and enrichments relative to bulk ash chemical composition. Under the presumption of surface and bulk equivalence, any disparities have been previously attributed to surface alteration processes, but the ubiquity of some depletions (e.g., Ca, Fe) across multiple ash studies, irrespective of eruptive origin, could suggest these to be features of the surface produced at the instant of magma fragmentation. To investigate this possibility further, we conducted rapid decompression experiments at different pressure conditions and at ambient and magmatic temperature on porous andesitic rocks. These experiments produced fragmented ash material untouched by secondary alteration, which were compared to particles produced by crushing of large clasts from the same experiments. We investigated a restricted size fraction (63-90 μm) from both fragmented and crushed materials, determining bulk chemistry and mineralogy via XRF, SEM-BSE and EPMA, and investigated the chemical composition of the ash surface by XPS. Analyses suggest that fragmentation under experimental conditions partitioned a greater fraction of plagioclase-rich particles into the selected size fraction, relative to particles produced by crushing. Trends in surface chemical composition in fragmented and crushed particles mirror that

  14. Evolution of the Bucium Rodu and Frasin magmatic-hydrothermal system, Metaliferi Mountains, Romania (United States)

    Iatan, Elena Luisa; Berbeleac, Ion; Visan, Madalina; Minut, Adrian; Nadasan, Laurentiu


    The Miocene Bucium Rodu and Frasin maar-diatreme structures and related Au-Ag epithermal low sulfidation with passing to mesothermal mineralizations are located in the Bucium-Rosia Montana-Baia de Aries metallogenetic district, within so called the "Golden Quatrilaterum", in the northeastern part of the Metaliferi Mountains. These structures are situated at about 5 km southeast from Rosia Montana, the largest European Au-Ag deposit. The total reserves for Bucium Rodu-Frasin are estimated at 43.3 Mt with average contents of 1.3 g/t Au and 3 g/t Ag. The Miocene geological evolution of Bucium Rodu and Frasin magmatic-hydrothermal system took place in closely relationships with tectonic, magmatic and metallogenetic activity from Bucium-Rosia Montana-Baia de Aries district in general, and adjacent areas, in special. The hydrothermal alteration is pervasive; adularia followed by phyllic, carbonatization and silicification alterations, usually show a close relationship with the mineralizations. Propylitic alteration occurs dominantly towards the depth; argillic alteration shows a local character. The mineralization occurs in veins, breccias, stockworks and disseminations and is hosted within two volcanic structures emplaced into a sequence of Cretaceous sediments in closely genetically relations with the Miocene phreatomagmatic fracturing and brecciation events. Within Rodu maar-diatreme structure the mineralizations follow especially the contact between the diatreme and Cretaceous flysch. The vein sets with low, moderately and near vertical dippings, cover 400x400m with N-S trend. The most important mineralization style is represented by veins, accompanied by hydrothermal breccias and disseminations. The veins spatial distribution relives as "en echelon" tension veins. They carry gold, minor base metal sulphides (pyrite, chalcopyrite, sphalerite, galena, tetrahedrite, arsenopyrite). Gangue is represented by carbonates (calcite, dolomite, ankerite, siderite, rhodochrosite

  15. Adakite-like volcanism of Ecuador: lower crust magmatic evolution and recycling (United States)

    Chiaradia, Massimo; Müntener, Othmar; Beate, Bernardo; Fontignie, Denis


    In the Northern Andes of Ecuador, a broad Quaternary volcanic arc with significant across-arc geochemical changes sits upon continental crust consisting of accreted oceanic and continental terranes. Quaternary volcanic centers occur, from west to east, along the Western Cordillera (frontal arc), in the Inter-Andean Depression and along the Eastern Cordillera (main arc), and in the Sub-Andean Zone (back-arc). The adakite-like signatures of the frontal and main arc volcanoes have been interpreted either as the result of slab melting plus subsequent slab melt-mantle interactions or of lower crustal melting, fractional crystallization, and assimilation processes. In this paper, we present petrographic, geochemical, and isotopic (Sr, Nd, Pb) data on dominantly andesitic to dacitic volcanic rocks as well as crustal xenolith and cumulate samples from five volcanic centers (Pululagua, Pichincha, Ilalo, Chacana, Sumaco) forming a NW-SE transect at about 0° latitude and encompassing the frontal (Pululagua, Pichincha), main (Ilalo, Chacana), and back-arc (Sumaco) chains. All rocks display typical subduction-related geochemical signatures, such as Nb and Ta negative anomalies and LILE enrichment. They show a relative depletion of fluid-mobile elements and a general increase in incompatible elements from the front to the back-arc suggesting derivation from progressively lower degrees of partial melting of the mantle wedge induced by decreasing amounts of fluids released from the slab. We observe widespread petrographic evidence of interaction of primary melts with mafic xenoliths as well as with clinopyroxene- and/or amphibole-bearing cumulates and of magma mixing at all frontal and main arc volcanic centers. Within each volcanic center, rocks display correlations between evolution indices and radiogenic isotopes, although absolute variations of radiogenic isotopes are small and their values are overall rather primitive (e.g., ɛNd = +1.5 to +6, 87Sr/86Sr = 0

  16. It's the little things that matter most: The role of volatiles in volcanoes and their magmatic roots (United States)

    Keller, T.; Suckale, J.


    Many volcanic eruptions are driven by volatiles - mostly H2O and CO2 - that degas from magmas rising up beneath the volcano. Gas expands during ascent, thus frequently creating lavas with upward of 50% vesicularity. That is a particularly compelling observation considering that volatiles are only present at concentrations of order 100 ppm in the mantle source. Yet, even at these small concentrations, volatiles significantly lower the peridotite solidus. That leads to the production of reactive volatile-rich melts at depth, which has important consequences for melt transport in the asthenosphere. Thus, volatiles have a pivotal role both at the beginning and the end of the magmatic storyline. A growing amount of observational evidence provides various perspectives on these systems. Volcanic products are characterised increasingly well by geochemical and petrological data. And, volcano monitoring now often provides continuous records of degassing flux and composition. What is missing to better interpret these data are coupled fluid mechanic and thermodynamic models that link melt production and reactive transport in the mantle and crust with degassing-driven volcanic activity at the surface. Such models need to describe the deformation and segregation of multiple material phases (liquids, solids, gases) and track the reactive transport of diverse chemical components (major elements, trace elements, volatiles). I will present progress towards a generalization of existing two-phase model for melt transport in the mantle, extending them to three-phase flows appropriate for magma circulation and degassing in volcanoes. What sets the two environments apart is the presence of a compressible vapor in volcanoes. Also, volcanic degassing may occur by convecting suspensions as well as porous segregation. The model framework we are developing for these processes is based on mixture theory. Uncovering the underlying physics that connects these diverse expressions of magma

  17. Aqueous polyethylene oxide solutions

    International Nuclear Information System (INIS)

    Breen, J.


    A number of aspects concerning the reorientation of polymer, water and ion hydration complexes have been studied in aqueous solution of polyethylene oxide (PEO). The polymer dynamics are investigated by 1 H-PEO and 13 C-PEO nuclear relaxation experiments. 162 refs.; 30 figs.; 19 tabs

  18. Assessment of lithogenic radioactivity in the Euganean Hills magmatic district (NE Italy). (United States)

    Tositti, Laura; Cinelli, Giorgia; Brattich, Erika; Galgaro, Antonio; Mostacci, Domiziano; Mazzoli, Claudio; Massironi, Matteo; Sassi, Raffaele


    The Euganean Hills of North East Italy have long been recognised as an area characterized by a higher than average natural radiation background. This is due to two main reasons: a) primary lithogenic radiation due to rhyolitic and trachytic outcrops, which are "acidic alkaline" magmatic rocks potentially enriched in uranium and thorium; b) secondary sources related to a geothermal field - widely exploited for spa tourism in the area since the Roman age - producing surface release of radon-enriched fluids. Though radioactivity levels in the Euganean district have been often investigated in the past - including recent works aimed at assessing the radiation doses from radon and/or total gamma radiation - no effort has been put so far into producing a thorough assessment linking radiation protection data to geological-structural features (lithology, faults, water, organic matter content, etc.). This work represents the first part of the interdisciplinary project "Geological and geochemical control on Radon occurrence and natural radioactivity in the Euganean Hills district (North-Eastern Italy)", aimed at producing detailed results of the actual radiation levels in connection mainly with lithological parameters. A detailed sampling strategy, based on lithostratigraphy, petrology and mineralogy, has been adopted. The 151 rock samples collected were analyzed by high resolution γ-ray spectrometry with ex situ HPGe detectors. Statistical and geostatistical analyses were performed, and outlier values of U and Th - possibly associated with anomalies in the geological formation - were identified. U, Th and K concentration maps were developed using both the entire database and then again after expunging the outliers; the two were then compared. In all maps the highest values can be associated to trachyte and rhyolite lithologies, and the lowest ones to sedimentary formations. The external dose due to natural radionuclides in the soil - the so called terrestrial gamma dose

  19. The genesis of Mo-Cu deposits and mafic igneous rocks in the Senj area, Alborz magmatic belt, Iran (United States)

    Nabatian, Ghasem; Li, Xian-Hua; Wan, Bo; Honarmand, Maryam


    The geochemical and isotopic investigations were provided on the Upper Eocene Senj mafic intrusion and Mo-Cu mineralization to better understand the tectono-magmatic evolution and metallogeny of the central part of the Alborz magmatic belt. The Senj mafic intrusion is composed of gabbro to monzodiorite and monzonite in lithology, and intruded as a sill into volcano-sedimentary rocks of the Eocene Karaj Formation. The Karaj Formation consists of volcano-sedimentary rocks, such as altered crystalline to shaly tuffs. The Senj intrusion (39.7 ± 0.4 Ma) shows LILE and LREE enrichment and negative anomaly of Nb, Ta and Ti, the geochemical signatures similar to those from subduction-related mafic magmas. The Hf-O zircon analyses yield ɛHf(t) values of + 4.1 to + 11.1 and δ18O values of + 4.8 to + 6.2‰. The zircon isotopic signatures together with shoshonitic affinity in the Senj mafic samples suggest partial melting of an enriched lithospheric mantle that had already been metasomatized by slab-derived melts and fluids. The Mo-Cu mineralization mainly occurs as veins and veinlets in the volcano-sedimentary rocks of the Karaj Formation and is dominated by molybdenite with minor amounts of chalcopyrite, bornite, pyrite and tetrahedrite-tennantite. The associated gangue minerals are tremolite, actinolite, quartz, calcite, chlorite and epidote. The Senj Mo-Cu deposit formed in volcano-sedimentary rocks following the emplacement of the Late Eocene Senj sill. The source of molybdenite in the Senj deposit is dominantly from crustal materials as it is revealed by Re contents in the molybdenite minerals (0.5 to 0.7 ppm). In fact, the molybdenite occurrence may be a remobilization process related to the emplacement of the Senj mafic magma.

  20. Attenuation tomography in the western central Andes: A detailed insight into the structure of a magmatic arc (United States)

    Haberland, Christian; Rietbrock, Andreas


    High-quality data from 1498 local earthquakes recorded by the PISCO '94 (Proyecto de Investigatión Sismológica de la Cordillera Occidental, 1994) and ANCORP '96 (Andean Continental Research Project, 1996) temporary seismological networks allowed the detailed determination of the three-dimensional (3-D) attenuation structure (Qp-1) beneath the recent magmatic arc in the western central Andes (20° to 24°S). Assuming a frequency-independent Qp-1 in a frequency band between 1 and 30 Hz, whole path attenuation (t*) was estimated from the amplitude spectra of the P waves using spectral ratios and a spectral inversion technique. The damped least squares inversion (tomography) of the data reveals a complex attenuation structure. Crust and mantle of the forearc and subducting slab are generally characterized by low attenuation (Qp > 1000). Crust and mantle beneath the magmatic arc show elevated attenuation. The strongest anomaly of extremely low Qp is found in the crust between 22° and 23°S beneath the recent volcanic arc (Qp < 100). N-S variations can be observed: The western flank of the crustal attenuation anomaly follows the curved course of the volcanic front. North of 21°S the attenuation is less developed. In the northern part of the study area the low-Qp zone penetrates in the forearc mantle down to the subducting slab. In the south a deeper zone of high attenuation is resolved between 23° and 24°S directly above the subducting slab. Low Qp in the mantle correlates with earthquake clusters. The strong crustal attenuation is confined to the distribution of young ignimbrites and silicic volcanism and is interpreted as a thermally weakened zone with partial melts. The attenuation pattern in the upper mantle might reflect the variable extent of the asthenosphere and maps variations of subduction-related hydration processes in the mantle wedge from slab-derived fluids.

  1. Uranium metallogenesis of the peraluminous leucogranite from the Pontivy-Rostrenen magmatic complex (French Armorican Variscan belt): the result of long-term oxidized hydrothermal alteration during strike-slip deformation (United States)

    Ballouard, C.; Poujol, M.; Mercadier, J.; Deloule, E.; Boulvais, P.; Baele, J. M.; Cuney, M.; Cathelineau, M.


    In the French Armorican Variscan belt, most of the economically significant hydrothermal U deposits are spatially associated with peraluminous leucogranites emplaced along the south Armorican shear zone (SASZ), a dextral lithospheric scale wrench fault that recorded ductile deformation from ca. 315 to 300 Ma. In the Pontivy-Rostrenen complex, a composite intrusion, the U mineralization is spatially associated with brittle structures related to deformation along the SASZ. In contrast to monzogranite and quartz monzodiorite (3 3), the leucogranite samples are characterized by highly variable U contents ( 3 to 27 ppm) and Th/U ratios ( 0.1 to 5) suggesting that the crystallization of magmatic uranium oxide in the more evolved facies was followed by uranium oxide leaching during hydrothermal alteration and/or surface weathering. U-Pb dating of uranium oxides from the deposits reveals that they mostly formed between ca. 300 and 270 Ma. In monzogranite and quartz monzodiorite, apatite grains display magmatic textures and provide U-Pb ages of ca. 315 Ma reflecting the time of emplacement of the intrusions. In contrast, apatite grains from the leucogranite display textural, geochemical, and geochronological evidences for interaction with U-rich oxidized hydrothermal fluids contemporaneously with U mineralizing events. From 300 to 270 Ma, infiltration of surface-derived oxidized fluids leached magmatic uranium oxide from fertile leucogranite and formed U deposits. This phenomenon was sustained by brittle deformation and by the persistence of thermal anomalies associated with U-rich granitic bodies.

  2. Fluid dynamics of dilatant fluid

    DEFF Research Database (Denmark)

    Nakanishi, Hiizu; Nagahiro, Shin-ichiro; Mitarai, Namiko


    of the state variable, we demonstrate that the model can describe basic features of the dilatant fluid such as the stress-shear rate curve that represents discontinuous severe shear thickening, hysteresis upon changing shear rate, and instantaneous hardening upon external impact. An analysis of the model...

  3. Observational constraints on the identification of shallow lunar magmatism : insights from floor-fractured craters


    Jozwiak, Lauren; Head, James; Neumann, G. A.; Wilson, Lionel


    Floor-fractured craters are a class of lunar crater hypothesized to form in response to the emplacement of a shallow magmatic intrusion beneath the crater floor. The emplacement of a shallow magmatic body should result in a positive Bouguer anomaly relative to unaltered complex craters, a signal which is observed for the average Bouguer anomaly interior to the crater walls. We observe the Bouguer anomaly of floor-fractured craters on an individual basis using the unfiltered Bouguer gravity so...

  4. Transient magmatic control in a tectonic domain: the central Aeolian volcanic arc (South Italy)

    KAUST Repository

    Ruch, Joel; Vezzoli, Luigina; Di Lorenzo, Riccardo; De Rosa, Rosanna; Acocella, Valerio


    The background stress field in volcanic areas may be overprinted by that produced by transient magmatic intrusions, generating local faulting. These events are rarely monitored and thus not fully understood, generating debate about the role of magma and tectonics in any geodynamic setting. Here we carried out a field structural analysis on the NNW-SSE strike-slip system of the central Aeolian Arc, Italy (Lipari and Vulcano islands) with ages constrained by stratigraphy to better capture the tectonic and magmatic evolution at the local and regional scales. We consider both islands as a single magmatic system and define 5 principal stratigraphic units based on magmatic and tectonic activity. We collected >500 measurements of faults, extension fractures and dikes at 40 sites, mostly NNE-SSW to NNW-SSE oriented with a dominant NS orientation. These structures are governed quasi exclusively by pure dip-slip motion, consistent with an E-W extension direction, with minor dextral and sinistral slip, the latter being mostly related to old deposits (>50 ka). We further reconstructed the evolution of the Vulcano-Lipari system during the last ~20 ka and find that it consists of an overall half-graben-like structure, with faults with predominant eastward dips. Field evidence suggests that faulting occurs often in temporal and spatial relation with magmatic events, suggesting that most of the observable deformation derived from transient magmatic activity, rather than from steady regional tectonics. To explain the dominant magmatic and episodic extension in a tectonic dominant domain, we propose a model where the regional N-S trending maximum horizontal stress, responsible for strike-slip activity, locally rotates to vertical in response to transient pressurization of the magmatic system and magma rise below Lipari and Vulcano. This has possibly generated the propagation of N-S trending dikes in the past 1 ka along a 10 km long by 1 km wide crustal corridor, with important

  5. Transient magmatic control in a tectonic domain: the central Aeolian volcanic arc (South Italy)

    KAUST Repository

    Ruch, Joel


    The background stress field in volcanic areas may be overprinted by that produced by transient magmatic intrusions, generating local faulting. These events are rarely monitored and thus not fully understood, generating debate about the role of magma and tectonics in any geodynamic setting. Here we carried out a field structural analysis on the NNW-SSE strike-slip system of the central Aeolian Arc, Italy (Lipari and Vulcano islands) with ages constrained by stratigraphy to better capture the tectonic and magmatic evolution at the local and regional scales. We consider both islands as a single magmatic system and define 5 principal stratigraphic units based on magmatic and tectonic activity. We collected >500 measurements of faults, extension fractures and dikes at 40 sites, mostly NNE-SSW to NNW-SSE oriented with a dominant NS orientation. These structures are governed quasi exclusively by pure dip-slip motion, consistent with an E-W extension direction, with minor dextral and sinistral slip, the latter being mostly related to old deposits (>50 ka). We further reconstructed the evolution of the Vulcano-Lipari system during the last ~20 ka and find that it consists of an overall half-graben-like structure, with faults with predominant eastward dips. Field evidence suggests that faulting occurs often in temporal and spatial relation with magmatic events, suggesting that most of the observable deformation derived from transient magmatic activity, rather than from steady regional tectonics. To explain the dominant magmatic and episodic extension in a tectonic dominant domain, we propose a model where the regional N-S trending maximum horizontal stress, responsible for strike-slip activity, locally rotates to vertical in response to transient pressurization of the magmatic system and magma rise below Lipari and Vulcano. This has possibly generated the propagation of N-S trending dikes in the past 1 ka along a 10 km long by 1 km wide crustal corridor, with important

  6. Colorado Plateau magmatism and uplift by warming of heterogeneous lithosphere. (United States)

    Roy, Mousumi; Jordan, Thomas H; Pederson, Joel


    The forces that drove rock uplift of the low-relief, high-elevation, tectonically stable Colorado Plateau are the subject of long-standing debate. While the adjacent Basin and Range province and Rio Grande rift province underwent Cenozoic shortening followed by extension, the plateau experienced approximately 2 km of rock uplift without significant internal deformation. Here we propose that warming of the thicker, more iron-depleted Colorado Plateau lithosphere over 35-40 Myr following mid-Cenozoic removal of the Farallon plate from beneath North America is the primary mechanism driving rock uplift. In our model, conductive re-equilibration not only explains the rock uplift of the plateau, but also provides a robust geodynamic interpretation of observed contrasts between the Colorado Plateau margins and the plateau interior. In particular, the model matches the encroachment of Cenozoic magmatism from the margins towards the plateau interior at rates of 3-6 km Myr(-1) and is consistent with lower seismic velocities and more negative Bouguer gravity at the margins than in the plateau interior. We suggest that warming of heterogeneous lithosphere is a powerful mechanism for driving epeirogenic rock uplift of the Colorado Plateau and may be of general importance in plate-interior settings.

  7. The inception of a Paleotethyan magmatic arc in Iberia

    Directory of Open Access Journals (Sweden)

    M.F. Pereira


    Full Text Available This paper presents a compilation of recent U-Pb (zircon ages of late Carboniferous–early Permian (LC–EP calc-alkaline batholiths from Iberia, together with a petrogenetic interpretation of magma generation based on comparisons with Mesozoic and Tertiary Cordilleran batholiths and experimental melts. Zircon U-Pb ages distributed over the range ca. 315–280 Ma, indicate a linkage between calc-alkaline magmatism, Iberian orocline generation and Paleotethys subduction. It is also shown that Iberian LC–EP calc-alkaline batholiths present unequivocal subduction-related features comparable with typical Cordilleran batholiths of the Pacific Americas active margin, although geochemical features were partially obscured by local modifications of magmas at the level of emplacement by country rock assimilation. When and how LC–EP calc-alkaline batholiths formed in Iberia is then discussed, and a new and somewhat controversial interpretation for their sources and tectonic setting (plume-assisted relamination is suggested. The batholiths are proposed to have formed during the subduction of the Paleotethys oceanic plate (Pangaea self-subduction and, consequently, they are unrelated to Variscan collision. The origin of the Iberian batholiths is related to the Eurasian active margin and probably represents the inception of a Paleotethyan arc in the core of Pangaea.

  8. Updated Magmatic Flux Rate Estimates for the Hawaii Plume (United States)

    Wessel, P.


    Several studies have estimated the magmatic flux rate along the Hawaiian-Emperor Chain using a variety of methods and arriving at different results. These flux rate estimates have weaknesses because of incomplete data sets and different modeling assumptions, especially for the youngest portion of the chain (little or no quantification of error estimates for the inferred melt flux, making an assessment problematic. Here we re-evaluate the melt flux for the Hawaii plume with the latest gridded data sets (SRTM30+ and FAA 21.1) using several methods, including the optimal robust separator (ORS) and directional median filtering techniques (DiM). We also compute realistic confidence limits on the results. In particular, the DiM technique was specifically developed to aid in the estimation of surface loads that are superimposed on wider bathymetric swells and it provides error estimates on the optimal residuals. Confidence bounds are assigned separately for the estimated surface load (obtained from the ORS regional/residual separation techniques) and the inferred subsurface volume (from gravity-constrained isostasy and plate flexure optimizations). These new and robust estimates will allow us to assess which secondary features in the resulting melt flux curve are significant and should be incorporated when correlating melt flux variations with other geophysical and geochemical observations.

  9. Dating the magmatism of Maio, Cape Verde Islands

    Energy Technology Data Exchange (ETDEWEB)

    Mitchell, J G [Newcastle upon Tyne Univ. (UK). School of Physics; Le Bas, M J [Leicester Univ. (UK). Dept. of Geology; Furnes, H [Bergen Univ. (Norway). Geologisk Inst.


    Conventional K-Ar and /sup 40/Ar//sup 39/Ar studies of Mesozoic ocean floor basalts and Tertiary plutonic and volcanic rocks from Maio, Cape Verde Islands, have been determined to elucidate the magmatic evolution of this ocean island. Pillow lavas of the Basement Complex yield a minimum age of 113 +- 8 Ma though thermal overprinting of their formation age by the younger Central Intrusive Complex (CIC) and subsequent sheet intrusions is in some cases almost total. Activity in the CIC began before 20 Ma and plutons continued to develop until about 8 Ma, the youngest ages possibly indicating a cooling history of more than 2 Ma for these bodies relative to their volcanic counterparts. Sheet intrusion occurred throughout the period 20 to 9 Ma though the peak of this activity probably occurred 11 Ma ago. Field relations allow the time of thrusting(s) on the Monte Branco Thrust to be bracketed between 9 and 7 Ma. Volcanic activity began in the Tertiary, probably before 12 Ma, and culminated in the development of a stratovolcano at 7 Ma.

  10. The Mozambique Ridge: a document of massive multistage magmatism (United States)

    Fischer, Maximilian D.; Uenzelmann-Neben, Gabriele; Jacques, Guillaume; Werner, Reinhard


    The Mozambique Ridge, a prominent basement high in the southwestern Indian Ocean, consists of four major geomorphological segments associated with numerous phases of volcanic activity in the Lower Cretaceous. The nature and origin of the Mozambique Ridge have been intensely debated with one hypothesis suggesting a Large Igneous Province origin. High-resolution seismic reflection data reveal a large number of extrusion centres with a random distribution throughout the southern Mozambique Ridge and the nearby Transkei Rise. Intrabasement reflections emerge from the extrusion centres and are interpreted to represent massive lava flow sequences. Such lava flow sequences are characteristic of eruptions leading to the formation of continental and oceanic flood basalt provinces, hence supporting a Large Igneous Province origin of the Mozambique Ridge. We observe evidence for widespread post-sedimentary magmatic activity that we correlate with a southward propagation of the East African Rift System. Based on our volumetric analysis of the southern Mozambique Ridge we infer a rapid sequential emplacement between ˜131 and ˜125 Ma, which is similar to the short formation periods of other Large Igneous Provinces like the Agulhas Plateau.

  11. K/Ar dating of the Eastern Rhodope Paleogene magmatism

    Energy Technology Data Exchange (ETDEWEB)

    Lilov, P.; Yanev, Y.; Marchev, P.


    Paleogene magmatic rocks from the Eastern Rhodope Mountains have seldom been an object of radiogeochronological studies and very few data are available from the geological literature. Until now their dating relied heavily on paleontological data from fossil-bearing sediments, alternating with the lava flows. However, there are also many cross bodies (extrusions, dikes and intrusions) as well as volcanic areas of no sediments or of fossil-free sediments which require the combined use of both methods. This paper aims at characterizing geochronologically the Eastern Rhodope Paleogene volcanism. The K/Ar method was used to date reference volcanoes (mostly with well-defined positions in the Paleogene sequence) associated with the various phases of volcanic activity, as well as some separate intrusive bodies. Nomenclature of volcanics followed the classification of the Soviet Petrographic Commission and that of Peccerillo and Taylor as supplemented by Marchey. The paper characterizes only two of the three main volcanic districts, the Momcilgrad-Arda and the Borovica districts. The third one, Susica district, has restricted exposures near the state boundary between Bulgari and Greece and was excluded from the study. The results obtained are compared with the geochronological scales proposed by Odin and Cavelier and Pomerol which correlate radiogeochronological and paleontological data (nannoplancton data included).

  12. Progress in aqueous rechargeable batteries


    Jilei Liu; Chaohe Xu; Zhen Chen; Shibing Ni; Ze Xiang Shen


    Over the past decades, a series of aqueous rechargeable batteries (ARBs) were explored, investigated and demonstrated. Among them, aqueous rechargeable alkali-metal ion (Li+, Na+, K+) batteries, aqueous rechargeable-metal ion (Zn2+, Mg2+, Ca2+, Al3+) batteries and aqueous rechargeable hybrid batteries are standing out due to peculiar properties. In this review, we focus on the fundamental basics of these batteries, and discuss the scientific and/or technological achievements and challenges. B...

  13. Geochronology, geochemical and Sr-Nd-Hf-Pb isotopic compositions of the granitoids in the Yemaquan orefield, East Kunlun orogenic belt, northern Qinghai-Tibet Plateau: Implications for magmatic fractional crystallization and sub-solidus hydrothermal alteration (United States)

    Yin, Shuo; Ma, Changqian; Xu, Jiannan


    A general consensus has emerged that high field strength elements (HFSE) can mobile to some extent in a hydrothermal fluid. However, there are hot debates on whether sub-solidus hydrothermal alteration can lower the Nb/Ta ratio in evolved melts. In this study, we present petrography, geochronology and geochemistry of the barren and mineralized rocks in the Yemaquan skarn iron deposit, northern Qinghai-Tibet Plateau, to probe magmatic-hydrothermal transition. The barren rocks consist of diorites, granodiorites, granites and syenogranites, whereas the porphyritic granodiorites are associated with mineralization for an excellent consistency between the magmatic zircon U-Pb age (225 ± 2 Ma) and the hydrothermal phlogopite 40Ar-39Ar age (225 ± 1.5 Ma). The Sr-Nd-Hf-Pb isotopic data demonstrate that the Yemaquan granitoids are originated from a relatively homogenous enriched mantle with different degrees of crust contamination (assimilation fractional crystallization, AFC). Trace elements signatures indicate that the porphyritic granodiorites related to mineralization display amphibole crystallization for high water contents, whereas the barren granites have gone through biotite crystallization due to potassium enrichment by continuous upper crust contamination, both of which are responsible for their Nb/Ta ratios, respectively. Modeling results suggest that a basaltic melt with Nb/Ta ratio of 15.3 can reach a minimum Nb/Ta ratio of 12 in the producing granodioritic melt by amphibole fractional crystallization based on partition coefficients of Nb and Ta between amphibole and melts from previous experiments. This may explain the average Nb/Ta ratio (13.7) of the barren granodiorites, while it cannot account for the average Nb/Ta ratio (8.4) of the mineralized porphyritic granodiorites, and it is even lower than that of the granites (10.3) with biotite fractional crystallization. Exsolution of a magmatic-hydrothermal fluid is inevitable when a water saturated magma

  14. Fluid dynamics

    CERN Document Server

    Ruban, Anatoly I

    This is the first book in a four-part series designed to give a comprehensive and coherent description of Fluid Dynamics, starting with chapters on classical theory suitable for an introductory undergraduate lecture course, and then progressing through more advanced material up to the level of modern research in the field. The present Part 1 consists of four chapters. Chapter 1 begins with a discussion of Continuum Hypothesis, which is followed by an introduction to macroscopic functions, the velocity vector, pressure, density, and enthalpy. We then analyse the forces acting inside a fluid, and deduce the Navier-Stokes equations for incompressible and compressible fluids in Cartesian and curvilinear coordinates. In Chapter 2 we study the properties of a number of flows that are presented by the so-called exact solutions of the Navier-Stokes equations, including the Couette flow between two parallel plates, Hagen-Poiseuille flow through a pipe, and Karman flow above an infinite rotating disk. Chapter 3 is d...

  15. Review Of Applied Mathematical Models For Describing The Behaviour Of Aqueous Humor In Eye Structures (United States)

    Dzierka, M.; Jurczak, P.


    In the paper, currently used methods for modeling the flow of the aqueous humor through eye structures are presented. Then a computational model based on rheological models of Newtonian and non-Newtonian fluids is proposed. The proposed model may be used for modeling the flow of the aqueous humor through the trabecular meshwork. The trabecular meshwork is modeled as an array of rectilinear parallel capillary tubes. The flow of Newtonian and non-Newtonian fluids is considered. As a results of discussion mathematical equations of permeability of porous media and velocity of fluid flow through porous media have been received.

  16. Co-composting of Non-aqueous Drilling Fluid Contaminated ...

    African Journals Online (AJOL)

    Prof. Ogunji

    observed in electrical conductivity of the compost systems. Macrocosms containing poultry manure .... pH, Electrical conductivity (µS/cm): The samples were prepared by homogenizing 25 g of the sample in 25 ml of water. ..... Thus, as the electrical conductivity (ionic strength) reduced more micro-organisms are proliferating.

  17. Geochemical studies, magmatic evolution, microstructures and replacement mechanisms in Jebale-Barez granitoid Complex (East and Southeast Jiroft

    Directory of Open Access Journals (Sweden)

    Jamal Rasouli


    Full Text Available Introduction The Jebale-Barez Plutonic Complex (JBPC is composed of many intrusive bodies and is located in the southeastern province of Kerman on the longitude of the 57◦ 45 ' east to 58◦ 00' and Northern latitudes 28◦ 30' to 29◦ 00'. The petrologic composition is composed of granodiorite, quartzdiorite, granite, alkali-granite, and trace amounts of tonalite with dominant granodiorite composition. Previously, the JBPC was separated into three plutonic phases by Ghorbani (2014. The first plutonic phase is the main body of the complex with composition of quartz-diorite to granodiorite. After differentiation of magma in the magmatic chamber, the porphyritic and not fully consolidated magmas have intruded into the main body. Their compositions were dominantly granodiorite and granite that are defined as the second plutonic phase. Finally, the last phase was started by an intrusion of the holo- leucogranite into the previous bodies. This plutonic activity was pursued by the minor Quaternary basaltic volcanism that shows metamorphic haloes in the contacts. They are dominantly porphyric leucogranites. However, some bodies show dendritic texture that may imply the existence of silicic fluids in the latest crystallization stages. Materials and methods In this article different analysis methods were used. For example, we used a total of two hundred samples of the various granitoids that were selected for common thin section study. Forty four representative samples from the different granitic rocks were selected for whole rock chemical analyses. The analyses of both major and trace elements were performed at the Department of Earth Sciences, the University of Perugia, Italy. The analysis for all major elements was carried out by an X-ray fluorescence spectrometry (XRF using a tube completed with a Rn and W anode under conditions with acceleration voltage of 40-45 kV and electric current ranging from I=30-35 mA. After calcination of powdered

  18. Tunable aqueous virtual micropore. (United States)

    Park, Jae Hyun; Guan, Weihua; Reed, Mark A; Krstić, Predrag S


    A charged microparticle can be trapped in an aqueous environment by forming a narrow virtual pore--a cylindrical space region in which the particle motion in the radial direction is limited by forces emerging from dynamical interactions of the particle charge and dipole moment with an external radiofrequency quadrupole electric field. If the particle satisfies the trap stability criteria, its mean motion is reduced exponentially with time due to the viscosity of the aqueous environment; thereafter the long-time motion of particle is subject only to random, Brownian fluctuations, whose magnitude, influenced by the electrophoretic and dielectrophoretic effects and added to the particle size, determines the radius of the virtual pore, which is demonstrated by comparison of computer simulations and experiment. The measured size of the virtual nanopore could be utilized to estimate the charge of a trapped micro-object. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  19. Lower-crustal xenoliths from Jurassic kimberlite diatremes, upper Michigan (USA): Evidence for Proterozoic orogenesis and plume magmatism in the lower crust of the southern Superior Province (United States)

    Zartman, Robert E.; Kempton, Pamela D.; Paces, James B.; Downes, Hilary; Williams, Ian S.; Dobosi, Gábor; Futa, Kiyoto


    unique peraluminous composition. It has the lowest εNd and εHf values of the suite. Its isotopic compositions indicate that it is significantly older than the other granulites. Broken zircon cores encased by younger overgrowths suggest that this granulite includes a large component of pre-existing sedimentary rocks. Two distinct populations of zircons from S69-5 were dated by sensitive high-resolution ion microprobe. Abundant rounded zircons yield ages of 1104 ± 42 (2σ) Ma, which coincide with the Mid-Continent Rift flood basalt eruptions. Their morphology is similar to those found in lower-crustal rocks that have undergone granulite-facies metamorphism and thus they are considered to represent the age of Group 2 granulites. Also present are less abundant elongate zircon grains that yield a mean age of 1387 ± 32 (2σ) Ma. Their elongate shapes indicate growth from a melt or fluid, possibly associated with 1·3–1·5 Ga anorogenic granite magmatism exposed in the shallow crust to the south in Wisconsin, or related to an initial encroachment of the Keweenawan plume upon the lower crust. Older ages recognized in zircon cores are less well constrained but may be related to tectono-magmatic events in the southern Superior craton. Within the studied suite only S69-5 was recognized as a remnant of the Late Archean lower crust into which the Group 1 and 2 mafic granulite precursor basalts were intruded. Collectively, the data show that the lower crust beneath northern Michigan formed in Archean times and underwent a variety of tectono-magmatic processes throughout the Proterozoic, including orogenesis, partial melting and mafic magmatic underplating in response to upwelling mantle plumes.

  20. Fluids in volcanic and geothermal systems (United States)

    Sigvaldason, Gudmundur E.

    Mineral buffers control the composition of most volatile components of magmas and dissolved species in geothermal fluids. The only element which occurs in significant quantities in volcanic and geothermal fluids and is not controlled by mineral buffers is chlorine. It is argued that in absence of marine influence, geothermal fluids reflect the chlorine content of associated magmatic fluids. The chlorine content of oceanic volcanic rocks has a positive correlation with elements, which are believed to indicate a heterogenous source region. Since the source is generally believed to be the Earth's mantle, the implication is that the mantle is heterogenous with regard to chlorine and other volatiles. Such heterogeneities would have important consequences for genesis and distribution of ore. All major magma types of the oceanic environment occur in Iceland. Their spatial distribution is closely related to a volcanotectonic pattern, suggesting crustal control. A geophysical model of crustal accretion in a rift zone is used in conjunction with classical petrology to predict geochemical processes in a rift zone crust. The model has two kinematic parameters-drift rate and subsidence rate-which combined describe trajectories of mass particles deposited on the surface. When considering in conjunction with thermal gradients of the rift zone a series of metamorphic reactions and chemical fractionation processes are bound to occur, eventually resulting in a layering of the oceanic crust. The physical parameters result in a derived variable, rift zone residence time, which depends on the width of a rift zone. Long residence times in a wide rift zone lead to multistage recycling of material. Other properties of the model, based on geometric arrangement of productive fissure swarms within a rift zone, explain off-rift volcanism as directly related to rift zone processes, either as plate trapped magmatic domains or a transgressive thermal anomaly into an older crust. Off

  1. Aqueous liquid redox desulfurisation

    Energy Technology Data Exchange (ETDEWEB)

    Reicher, M.; Niemiec, B.; Katona, T.


    The LO-CAT II process is an aqueous liquid redox process which uses ferric and ferrous iron catalysts to oxidise hydrogen sulfide (from sour gas) to elemental sulfur: the relevant chemical equations are given. Chelating agents keep the iron in solution. The system is described under the headings of (i) LO-CAT chemistry, (ii) design parameters, (iii) startup challenges, (iv) present situation and (v) anticipated future conditions. Further improvements to the system are anticipated.

  2. A Parent Magma for the Nakhla Martian Meteorite: Reconciliation of Estimates from 1-Bar Experiments, Magmatic Inclusions in Olivine, and Magmatic Inclusions in Augite (United States)

    Treiman, Allan H.; Goodrich, Cyrena Anne


    The composition of the parent magma for the Nakhla (martian) meteorite has been estimated from mineral-melt partitioning and from magmatic inclusions in olivine and in augite. These independent lines of evidence have converged on small range of likely compositions. Additional information is contained in the original extended abstract.

  3. Modelling Subduction Zone Magmatism Due to Hydraulic Fracture (United States)

    Lawton, R.; Davies, J. H.


    The aim of this project is to test the hypothesis that subduction zone magmatism involves hydraulic fractures propagating from the oceanic crust to the mantle wedge source region (Davies, 1999). We aim to test this hypothesis by developing a numerical model of the process, and then comparing model outputs with observations. The hypothesis proposes that the water interconnects in the slab following an earthquake. If sufficient pressure develops a hydrofracture occurs. The hydrofracture will expand in the direction of the least compressive stress and propagate in the direction of the most compressive stress, which is out into the wedge. Therefore we can calculate the hydrofracture path and end-point, given the start location on the slab and the propagation distance. We can therefore predict where water is added to the mantle wedge. To take this further we have developed a thermal model of a subduction zone. The model uses a finite difference, marker-in-cell method to solve the heat equation (Gerya, 2010). The velocity field was prescribed using the analytical expression of cornerflow (Batchelor, 1967). The markers contained within the fixed grid are used to track the different compositions and their properties. The subduction zone thermal model was benchmarked (Van Keken, 2008). We used the hydrous melting parameterization of Katz, (2003) to calculate the degree of melting caused by the addition of water to the wedge. We investigate models where the hydrofractures, with properties constrained by estimated water fluxes, have random end points. The model predicts degree of melting, magma productivity, temperature of the melt and water content in the melt for different initial water fluxes. Future models will also include the buoyancy effect of the melt and residue. Batchelor, Cambridge UP, 1967. Davies, Nature, 398: 142-145, 1999. Gerya, Cambridge UP, 2010. Katz, Geochem. Geophys. Geosy, 4(9), 2003 Van Keken Phys. Earth. Planet. In., 171:187-197, 2008.

  4. Fluid mechanics

    International Nuclear Information System (INIS)

    Paraschivoiu, I.; Prud'homme, M.; Robillard, L.; Vasseur, P.


    This book constitutes at the same time theoretical and practical base relating to the phenomena associated with fluid mechanics. The concept of continuum is at the base of the approach developed in this work. The general advance proceeds of simple balances of forces as into hydrostatic to more complex situations or inertias, the internal stresses and the constraints of Reynolds are taken into account. This advance is not only theoretical but contains many applications in the form of solved problems, each chapter ending in a series of suggested problems. The major part of the applications relates to the incompressible flows

  5. Principles of fluid mechanics

    International Nuclear Information System (INIS)

    Kreider, J.F.


    This book is an introduction on fluid mechanics incorporating computer applications. Topics covered are as follows: brief history; what is a fluid; two classes of fluids: liquids and gases; the continuum model of a fluid; methods of analyzing fluid flows; important characteristics of fluids; fundamentals and equations of motion; fluid statics; dimensional analysis and the similarity principle; laminar internal flows; ideal flow; external laminar and channel flows; turbulent flow; compressible flow; fluid flow measurements

  6. Magmatic control along a strike-slip volcanic arc: The central Aeolian arc (Italy) (United States)

    Ruch, J.; Vezzoli, L.; De Rosa, R.; Di Lorenzo, R.; Acocella, V.


    The regional stress field in volcanic areas may be overprinted by that produced by magmatic activity, promoting volcanism and faulting. In particular, in strike-slip settings, the definition of the relationships between the regional stress field and magmatic activity remains elusive. To better understand these relationships, we collected stratigraphic, volcanic, and structural field data along the strike-slip central Aeolian arc (Italy): here the islands of Lipari and Vulcano separate the extensional portion of the arc (to the east) from the contractional one (to the west). We collected >500 measurements of faults, extension fractures, and dikes at 40 sites. Most structures are NNE-SSW to NNW-SSE oriented, eastward dipping, and show almost pure dip-slip motion, consistent with an E-W extension direction, with minor dextral and sinistral shear. Our data highlight six eruptive periods during the last 55 ka, which allow considering both islands as a single magmatic system, in which tectonic and magmatic activities steadily migrated eastward and currently focus on a 10 km long × 2 km wide active segment. Faulting appears to mostly occur in temporal and spatial relation with magmatic events, supporting that most of the observable deformation derives from transient magmatic activity (shorter term, days to months), rather than from steady longer-term regional tectonics (102-104 years). More in general, the central Aeolian case shows how magmatic activity may affect the structure and evolution of volcanic arcs, overprinting any strike-slip motion with magma-induced extension at the surface.

  7. Magmatic control along a strike-slip volcanic arc: The central Aeolian arc (Italy)

    KAUST Repository

    Ruch, Joel


    The regional stress field in volcanic areas may be overprinted by that produced by magmatic activity, promoting volcanism and faulting. In particular, in strike-slip settings, the definition of the relationships between the regional stress field and magmatic activity remains elusive. To better understand these relationships, we collected stratigraphic, volcanic and structural field data along the strike-slip Central Aeolian arc (Italy): here the islands of Lipari and Vulcano separate the extensional portion of the arc (to the east) from the contractional one (to the west). We collected >500 measurements of faults, extension fractures and dikes at 40 sites. Most structures are NNE-SSW to NNW-SSE oriented, eastward dipping, and show almost pure dip-slip motion; consistent with an E-W extension direction, with minor dextral and sinistral shear. Our data highlight six eruptive periods during the last 55 ka, which allow considering both islands as a single magmatic system, in which tectonic and magmatic activity steadily migrated eastward and currently focus on a 10 km long x 2 km wide active segment. Faulting appears to mostly occur in temporal and spatial relation with magmatic events, supporting that most of the observable deformation derives from transient magmatic activity (shorter-term, days to months), rather than from steady longer-term regional tectonics (102-104 years). More in general, the Central Aeolian case shows how magmatic activity may affect the structure and evolution of volcanic arcs, overprinting any strike-slip motion with magma-induced extension at the surface.

  8. Study of fluid inclusions in rodioactive mineralized pegmatites, dara area northern eastern desert, Egypt

    International Nuclear Information System (INIS)

    Ali, B.H.; Abdel Warith, A.


    Numerous pegmatite pockets of un zoned and zoned types are the most important rock types from the radioactive point of view. They occur at the marginal parts and higher topographic level of G.Dara younger granites. Zoned pegmatites are composed of extremely coarse-grained milky quartz core, intermediate zone and wall zone. The alteration zone is found at the contact between quartz core and intermediate zone. It is recorded the highest radioactive values due to their mineral composition, as a result of alteration processes associated with radioactive minerals. Only two alteration zones (P1 and P2) has been studied in this paper. The late magmatic alteration process (hematization, kaolinization, chloritization and fluortization) of the pegmatite resulted in the formation of chlorite, fluorite, clay minerals and carbonates (calcite) in the alteration zones as mineral assemblage. opaque minerals are found as pyrite, iron oxyhydroxide and garnet. Fluid inclusion studies by microthermometry were carried out on authigenic minerals (such as quartz and fluorite) in alteration zones (primary fluid inclusions). This study revealed that, at least two stages of the post-magmatic hydrothermal alteration are involved. The first stages of high temperature, low saline fluids are involved. The first stage is of high temperature, low saline fluids which characterized with hematization and/or chloritization resulted from fluid-rock interaction with late magmatic fluids that very probably mixed with external low salinity fluids along brittle structure. The second stage is of low temperature the main role in re high saline fluids characterized the fluoritized alteration due to consequent reaction with wall rocks and mixing with meteoric water. Mixing of low salinity meteoric water with hot a sending saline hydrothermal solution leads to ph change and continuous interaction with wall rock

  9. Amphibole trace elements as indicators of magmatic processes at Mount St. Helens (United States)

    Hampel, T. R.; Rowe, M. C.; Kent, A.; Thornber, C. R.


    Amphibole has the capability of incorporating a wide variety of trace elements resulting from a range of magmatic processes. Prior studies have used trace elements such as Li and Cu in amphibole to investigate volatile mobility associated with magma ascent regarding the 2004-2008 eruption of Mount St. Helens (Rowe et al. 2008). In order to investigate magmatic processes associated with the 2004-2008 eruption of Mount St. Helens we have measured a range of fluid-mobile trace elements in conjunction with major element compositions of amphibole phenocrysts in dacite lava. Major elements and volatiles (Cl, F) were measured by electron microprobe analysis at Washington State University and trace elements (Li, Sc, Co, Cu, Zn, Sr, Y, Zr, Mo, Ag, Sn, Sb, Te, Ba, Ce, W, and Pb) were analyzed by laser ablation (LA)-ICP-MS at Oregon State University. Amphibole crystallization temperatures were calculated after Ridolfi et al. (2010). Core to rim transects were measured by electron microprobe to evaluate volatile concentrations and temperature profiles across individual phenocrysts. Core temperatures from 17 days and 226 days post eruption are consistently hotter than the rim temperatures 997 to 881 degrees C, respectively. Amphiboles from the end of the eruption (811 days post eruption) appear to be more complex, with phenocrysts having both increasing and decreasing temperatures toward the rims. The overall calculated temperature range of the amphiboles at the end of the eruption is 1022 to 919 degrees C. There is much diversity in the concentrations of Li and Cu within the phenocrysts in both the samples and throughout the eruption. Concentrations steadily increase in the beginning of the eruption then drop dramatically toward the middle, slowly increase toward the end eruption. Overall concentrations of Sr, Sb, Co, Sn, Mo, Ba, Ce, Sc, and Y do not change over the course of the eruption but do vary sample to sample. Preliminary data for Zn, Sb, Ag, and W suggest the

  10. The late Variscan ferroan granite magmatism of southern Sardinia: inferences from Mo metallogenesis (United States)

    Naitza, Stefano; Conte, Aida Maria; Cuccuru, Stefano; Fadda, Sandro; Fiori, Maddalena; Oggiano, Giacomo; Secchi, Francesco


    Metallogeny is a powerful tool to investigate crustal evolution; a good example is offered by the Variscan basement of Sardinia and its Mo deposits. Mo ores are poorly represented in Variscan metallogenic provinces of Europe: however, in Sardinia, numerous small Mo deposits, often associated to Sn, W and F ores, are present, invariably related to an early Permian intrusive peak bracketed at about 290 Ma (Fadda et al., 2015; Naitza et al., 2017). In Sardinia, two main magmatic peaks have been schematized at pre-300 and 290 Ma. In southern Sardinia, the 290 magmatic peak is made up of several intrusive F-bearing rock-suites (Conte et al., 2016), belonging to ilmenite series, showing a slight peraluminous character and mostly classifiable as ferroan granites (sensu Frost and Frost, 2011). Mo-bearing granites form a distinct suite of relatively small plutons, emplaced at very shallow depth (about 1kb) in an exhumed Variscan low-grade basement. Peculiar characters of Mo-bearing granites are the occurrence of greisenized microgranite and granophyre cupolas, with fayalite-bearing pegmatites, and ilmenite, xenotime-(Y), monazite, fluorite, and local topaz as accessory phases. Recently, Conte et al. (2016) interpreted these granites as originated by partial melting of low crustal felsic metaigneous photoliths enriched in granophiles (Mo, Sn, W). Mo ores occur as: a) endo- and exo- quartz-muscovite greisens with molybdenite±Fe-Cu sulphides, and b) quartz-molybdenite±wolframite±Fe-Cu-Zn sulphides±fluorite±topaz hydrothermal veins and stockworks, hosted in granites or in country rocks. Redox state of magmas exerts a strong control on Mo metallogeny, as in Mo districts worldwide ores are usually hosted by high-fO2 magnetite series intrusions (Ishihara, 1981). The close field association of Sardinian Mo mineralization with ferroan, low-fO2 ilmenite-series granites may be explained in terms of Mo-enriched crustal sources of magmas, and very efficient geochemical

  11. Magmatic Flow Record From AMS Data La Gloria Pluton, Central Chile (United States)

    Gutierrez, F.; Payacan, I. J.; Calderon, S.


    La Gloria Pluton (LGP) is a 10 Ma epizonal intrusion in the Southern Andes, located 40 km east of Santiago, in central Chile. 20 km long and 5 km wide LPG has a thickness of 2.5 km, in the form of a NW elongating inverted canoe. LGP intrudes Miocene volcanics as NS extending cluster of Miocene granitoids. LGP was emplaced at the west of an inverse fault system without exhibiting significant post-intrusion deformation. The fault system includes the Laguna Negra Fault and the El Coironal Fault, at its southern and northern ends respectively. LGP has been interpreted to have had a short cooling time, where subsolidus reequilibration was not pervasive, allowing identification of early and late magmatic conditions and suggesting it to be a single closed chamber. LGP is zoned vertically from granodiorite/quartz monzodiorite to quartz monzonite towards the roof, where hornblende and biotite and minor magnetite-ilmenite are omnipresent. AMS samples were collected at 39 sites to determine of the magnetic anisotropy susceptibility tensor. Magnetic fabric is generally oblate and anisotropy values range from 1.3 to 13.9%, consistent with the prescience magnetite and ilmenite. Magnetic lineation (ML) has a NNW trend, a subhorizontal dip and values between 0.4 and 5.3%. Magnetic foliation (MF) has a NW trend and dip varying from vertical at the walls of the intrusive to subhorizontal inside and under the roof. MF values ranges between 0.8 and 13.3%. Since linear trend of MF is restricted to the LGP interior only and can not be caused by a simple inverse fault system, we interpret the AMS results as a consequence of magmatic flow. ML represents the main flow direction, where several shallow plutons intrude at 10Ma in NW direction. MF is consequence of convection, related to cooling and differentiation, and is comparable to numerical simulations of magma fluid-dynamics during differentiation (R4). Two profiles (EW and NS) indicate that MF linear trend is from 29°/km to 50

  12. Disappearing fluid?

    International Nuclear Information System (INIS)

    Graney, K.; Chu, J.; Lin, P.C.


    Full text: A 78-year old male in end stage renal failure (ESRF) with a background of NIDDM retinopathy, nephropathy, and undergoing continuous ambulatory peritoneal dialysis (CAPD) presented with anorexia, clinically unwell, decreased mobility and right scrotal swelling. There was no difficulty during CAPD exchange except there was a positive fluid balance Peritoneal dialysates remained clear A CAPD peritoneal study was requested. 100Mbq 99mTc Sulphur Colloid was injected into a standard dialysate bag containing dialysate. Anterior dynamic images were acquired over the abdomen pelvis while the dialysate was infused Static images with anatomical markers were performed 20 mins post infusion, before and after patient ambulation and then after drainage. The study demonstrated communication between the peritoneal cavity and the right scrotal sac. Patient underwent right inguinal herniaplasty with a marlex mesh. A repeat CAPD flow study was performed as follow up and no abnormal connection between the peritoneal cavity and the right scrotal sac was demonstrated post operatively. This case study shows that CAPD flow studies can be undertaken as a simple, minimally invasive method to evaluate abnormal peritoneal fluid flow dynamics in patients undergoing CAPD, and have an impact on dialysis management. Copyright (2002) The Australian and New Zealand Society of Nuclear Medicine Inc

  13. Auxillary Fluid Flowmeter

    DEFF Research Database (Denmark)

    RezaNejad Gatabi, Javad; Forouzbakhsh, Farshid; Ebrahimi Darkhaneh, Hadi


    The Auxiliary Fluid Flow meter is proposed to measure the fluid flow of any kind in both pipes and open channels. In this kind of flow measurement, the flow of an auxiliary fluid is measured Instead of direct measurement of the main fluid flow. The auxiliary fluid is injected into the main fluid ...

  14. Aqueous shunts for glaucoma. (United States)

    Tseng, Victoria L; Coleman, Anne L; Chang, Melinda Y; Caprioli, Joseph


    Aqueous shunts are employed to control intraocular pressure (IOP) for people with primary or secondary glaucomas who fail or are not candidates for standard surgery. To assess the effectiveness and safety of aqueous shunts for reducing IOP in glaucoma compared with standard surgery, another type of aqueous shunt, or modification to the aqueous shunt procedure. We searched CENTRAL (which contains the Cochrane Eyes and Vision Trials Register) (2016, Issue 8), MEDLINE Ovid (1946 to August 2016), (1947 to August 2016), PubMed (1948 to August 2016), LILACS (Latin American and Caribbean Health Sciences Literature Database) (1982 to August 2016), (; searched 15 August 2016, and the World Health Organization (WHO) International Clinical Trials Registry Platform (ICTRP) (; searched 15 August 2016. We did not use any date or language restrictions in the electronic search for trials. We last searched the electronic databases on 15 August 2016. We also searched the reference lists of identified trial reports and the Science Citation Index to find additional trials. We included randomized controlled trials that compared various types of aqueous shunts with standard surgery or to each other in eyes with glaucoma. Two review authors independently screened search results for eligibility, assessed the risk of bias, and extracted data from included trials. We contacted trial investigators when data were unclear or not reported. We graded the certainty of the evidence using the GRADE approach. We followed standard methods as recommended by Cochrane. We included 27 trials with a total of 2099 participants with mixed diagnoses and comparisons of interventions. Seventeen studies reported adequate methods of randomization, and seven reported adequate allocation concealment. Data collection and follow-up times varied.Four trials compared an aqueous shunt (Ahmed or Baerveldt) with trabeculectomy, of which

  15. Breakup Style and Magmatic Underplating West of the Lofoten Islands, Norway, Based on OBS Data. (United States)

    Breivik, A. J.; Faleide, J. I.; Mjelde, R.; Murai, Y.; Flueh, E. R.


    The breakup of the Northeast Atlantic in the Early Eocene was magma-rich, forming the major part of the North Atlantic Igneous Province (NAIP). This is seen as extrusive and intrusive magmatism in the continental domain, and as a thicker than normal oceanic crust produced the first few million years after continental breakup. The maximum magma productivity and the duration of excess magmatism varies along the margins of Northwest Europe and East Greenland, to some extent as a function of the distance from the Iceland hotspot. The Vøring Plateau off mid-Norway is the northernmost of the margin segments in northwestern Europe with extensive magmatism. North of the plateau, magmatism dies off towards the Lofoten Margin, marking the northern boundary of the NAIP here. In 2003, as part of the Euromargins Program we collected an Ocean Bottom Seismometer (OBS) profile from mainland Norway, across the Lofoten Islands, and out into the deep ocean. Forward velocity modeling using raytracing reveals a continental margin that shows transitional features between magma-rich and magma-poor rifting. On one hand, we detect an up to 2 km thick and 40-50 km wide magmatic underplate of the outer continent, on the other hand, continental thinning is greater and intrusive magmatism less than farther south. Continental breakup also appears to be somewhat delayed compared to breakup on the Vøring Plateau, consistent with increased extension. This indicates that magmatic diking, believed to quickly lead to continental breakup of volcanic margins and thus to reduce continental thinning, played a much lesser role here than at the plateau. Early post-breakup oceanic crust is up to 8 km thick, less than half of that observed farther south. The most likely interpretation of these observations, is that the source for the excess magmatism of the NAIP was not present at the Lofoten Margin during rifting, and that the excess magmatism actually observed was the result of lateral transport from the

  16. Gyroelastic fluids

    Energy Technology Data Exchange (ETDEWEB)

    Kerbel, G.D.


    A study is made of a scale model in three dimensions of a guiding center plasma within the purview of gyroelastic (also known as finite gyroradius-near theta pinch) magnetohydrodynamics. The (nonlinear) system sustains a particular symmetry called isorrhopy which permits the decoupling of fluid modes from drift modes. Isorrhopic equilibria are analyzed within the framework of geometrical optics resulting in (local) dispersion relations and ray constants. A general scheme is developed to evolve an arbitrary linear perturbation of a screwpinch equilibrium as an invertible integral transform (over the complete set of generalized eigenfunctions defined naturally by the equilibrium). Details of the structure of the function space and the associated spectra are elucidated. Features of the (global) dispersion relation owing to the presence of gyroelastic stabilization are revealed. An energy principle is developed to study the stability of the tubular screwpinch.

  17. Gyroelastic fluids

    International Nuclear Information System (INIS)

    Kerbel, G.D.


    A study is made of a scale model in three dimensions of a guiding center plasma within the purview of gyroelastic (also known as finite gyroradius-near theta pinch) magnetohydrodynamics. The (nonlinear) system sustains a particular symmetry called isorrhopy which permits the decoupling of fluid modes from drift modes. Isorrhopic equilibria are analyzed within the framework of geometrical optics resulting in (local) dispersion relations and ray constants. A general scheme is developed to evolve an arbitrary linear perturbation of a screwpinch equilibrium as an invertible integral transform (over the complete set of generalized eigenfunctions defined naturally by the equilibrium). Details of the structure of the function space and the associated spectra are elucidated. Features of the (global) dispersion relation owing to the presence of gyroelastic stabilization are revealed. An energy principle is developed to study the stability of the tubular screwpinch

  18. Acoustic Streaming and Its Suppression in Inhomogeneous Fluids. (United States)

    Karlsen, Jonas T; Qiu, Wei; Augustsson, Per; Bruus, Henrik


    We present a theoretical and experimental study of boundary-driven acoustic streaming in an inhomogeneous fluid with variations in density and compressibility. In a homogeneous fluid this streaming results from dissipation in the boundary layers (Rayleigh streaming). We show that in an inhomogeneous fluid, an additional nondissipative force density acts on the fluid to stabilize particular inhomogeneity configurations, which markedly alters and even suppresses the streaming flows. Our theoretical and numerical analysis of the phenomenon is supported by ultrasound experiments performed with inhomogeneous aqueous iodixanol solutions in a glass-silicon microchip.

  19. Modelling Laccoliths: Fluid-Driven Fracturing in the Lab (United States)

    Ball, T. V.; Neufeld, J. A.


    Current modelling of the formation of laccoliths neglects the necessity to fracture rock layers for propagation to occur [1]. In magmatic intrusions at depth the idea of fracture toughness is used to characterise fracturing, however an analogue for near surface intrusions has yet to be explored [2]. We propose an analytical model for laccolith emplacement that accounts for the energy required to fracture at the tip of an intrusion. For realistic physical parameters we find that a lag region exists between the fluid magma front and the crack tip where large negative pressures in the tip cause volatiles to exsolve from the magma. Crucially, the dynamics of this tip region controls the spreading due to the competition between viscous forces and fracture energy. We conduct a series of complementary experiments to investigate fluid-driven fracturing of adhered layers and confirm the existence of two regimes: viscosity dominant spreading, controlled by the pressure in the lag region, and fracture energy dominant spreading, controlled by the energy required to fracture layers. Our experiments provide the first observations, and evolution, of a vapour tip. These experiments and our simplified model provide insight into the key physical processes in near surface magmatic intrusions with applications to fluid-driven fracturing more generally. Michaut J. Geophys. Res. 116(B5), B05205. Bunger & Cruden J. Geophys. Res. 116(B2), B02203.

  20. Geologic Mapping, Volcanic Stages and Magmatic Processes in Hawaiian Volcanoes (United States)

    Sinton, J. M.


    rise to various Hawaiian lithologies. This analysis indicates that the important magmatic process that links geologic mapping to volcanic stage is thermal state of the volcano, as manifest by depth of magma evolution. The only criterion for rejuvenation volcanism is the presence of a significant time break (more than several hundred thousand years) preceding eruption.

  1. Exhumation History Of Brasilian Highlands After Late Cretaceous Alcaline Magmatism (United States)

    Doranti Tiritan, Carolina; Hackspacher, Peter Christian; Carina Siqueira Ribeiro, Marli; Glasmacher, Ulrich Anton; Françoso de Godoy, Daniel


    The southeast Brazilian margin recorded a long history of tectonic and magmatic events after the Gondwana continent break up. The drifting of the South American Platform over a thermal anomaly generated a series of alkaline intrusions that are distributed from the interior to the coast from west to east. Several exhumation events are recorded on the region and we are providing insights on the landscape evolution of the region since Late Cretaceous, comparing low temperature thermochronology results from two alkaline intrusions regions. Poços de Caldas Alkaline Massif (PCAM), is lied in the interior, 300km from the coastline, covering over 800km2 intruding the Precambrian basement around 83Ma, nepheline syenites, phonolites and tinguaites intruded in a continuous and rapid sequence lasting between 1 to 2 Ma. São Sebastião Island (SSI) on the other hand is located at the coast, 200 km southeast of São Paulo. It is characterized by an intrusion in Precambrian/Brazilian orogen and intruded by Early Cretaceous sub-alkaline basic and acid dykes, as well as by Late Cretaceous alkaline stocks (syenites) and dykes (basanite to phonolite). Will be presenting the apatite fission track (AFT) and (U-Th)/He results that shows the main difference between the areas is that PCAM region register older history then the coastal area of SSI, where thermal history starts register cooling event after the South Atlantic rifting process, while in the PCAM area register a previous history, since Carboniferous. The results are giving support to studies that indicate the development of the relief in Brazil being strongly influenced by the local and regional tectonic movements and the lithological and structural settings. The landscape at the Late Cretaceous was witness of heating process between 90 and 60Ma due the intense uplift of South American Platform. The elevation of the isotherms is associated with the mantellic plumes and the crustal thickness that caused thermal anomalies due

  2. Sulfur concentration at sulfide saturation (SCSS) in magmatic silicate melts (United States)

    Liu, Yanan; Samaha, Naji-Tom; Baker, Don R.


    the MELTS software to calculate the saturation of natural magmas with a sulfide phase and evolution of the SCSS during magmatic differentiation.

  3. Magma Mixing: Magmatic Enclaves in Morne Micotrin, Dominica (United States)

    Hickernell, S.; Frey, H. M.; Manon, M. R. F.; Waters, L. E.


    Magmatic enclaves in volcanic rocks provide direct evidence of magma mingling/mixing within a magma reservoir and may reinvigorate the system and trigger eruption, as documented at the Soufriere Hills in Montserrat. Lava domes on the neighboring island of Dominica also contain multiple enclave populations and may be evidence for similar magma chamber processes. The central dome of Micotrin is at the head of the Roseau Valley, which was filled with 3 km3 of pyroclastic deposits from eruptions spanning 65 - 25 ka. There appear to be two distinct types of enclaves in the crystal-rich Micotrin andesites (60 wt% SiO2), fine-grained and coarse-grained. Fine-grained mafic enclaves (52 wt% SiO2) vary in size from 1 to 15 cm in diameter, whereas the coarse-grained enclaves are generally larger and range from 3-20 cm. Fine-grained enclaves are saturated in plag (35%) + opx (35%) + cpx (20%) + oxides (10%). Average pyroxenes are 0.01 to 0.02 cm in size, whereas plagioclase averages 0.05 cm and up to 0.1 cm. The texture of the fine-grained enclaves is cumulate-like, devoid of microlites and matrix glass. Coarse-grained enclaves lack cpx and have different modal abundances and textures: plag (75%) + opx (10%) + oxides (5%) + plag microlites (10%). Plagioclase are 0.1 cm in size and orthopyroxenes average 0.05 cm. The coarse-grained enclaves are highly vesicular, a notable difference from the host as well as the fine-grained enclaves. The boundaries of both the fine- and coarse-grained enclaves are quite sharp and distinct and there do not appear to be enclave minerals disaggregated in the host rock. Temperatures were determined by two oxides. The fine-grained enclaves had two populations of magnetite, yielding 847 + 21° and 920 + 17°C. The coarse-grained enclave was 890 + 42 °C, but the oxides were extensively exsolved. Plagioclase composition in both coarse and fine-grained samples was comparable, ranging from An50 to An80. Despite compositional similarity the textures of

  4. Magmatic Volatiles as an Amplifier of Centrifugal Volcanism (United States)

    Pratt, V. R.


    There is a striking correlation between negated Length of Day -LOD and the 60-70 year period in 20th century global climate, associated by some with the so-called Atlantic Multidecadal Oscillation or AMO. A number of authors have suggested mechanisms by which the former might cause the latter. One such that this author finds quite compelling is that gravity fluctuations at low latitudes increase essentially linearly with LOD fluctuations and therefore moves magma towards or away from the surface as LOD decreases or increases, i.e. angular velocity increases or decreases, respectively. At AGU FM2016 we proposed the term "centrifugal volcanism" for this mechanism and listed four possible objections to it, explaining three to our satisfaction. The remaining objection is the very obvious one that the 4 ms increase in LOD between 1880 and 1910 seems far too small to be able to account for the observed variation of about a quarter of a degree. A basic mechanism underlying many violent eruptions is the strong positive feedback between reduction of pressure in magma and evaporation of dissolved volatiles found in some magmas, driving the magma outwards and thereby further reducing the pressure. The normal state of magma is equilibrium. Any fluctuation in gravity, even a very small one, can be sufficient to shift this equilibrium sufficiently far to set this positive feedback in motion. The relevant electrical analogy would be an operational amplifier whose amplification is greatly increased by a positive feedback. We therefore propose that the same mechanism responsible for some violent eruptions also serves to amplify the tiny changes in gravity sufficiently to increase or decrease the vertical component of the movement of magma in general. This movement, felt throughout the planet albeit most strongly at low latitudes, influences the temperature at ocean bottoms wherever there is a significant level of magmatic volatiles. This in turn creates thermals that are large

  5. Phase equilibria constraints on models of subduction zone magmatism (United States)

    Myers, James D.; Johnston, Dana A.

    Petrologic models of subduction zone magmatism can be grouped into three broad classes: (1) predominantly slab-derived, (2) mainly mantle-derived, and (3) multi-source. Slab-derived models assume high-alumina basalt (HAB) approximates primary magma and is derived by partial fusion of the subducting slab. Such melts must, therefore, be saturated with some combination of eclogite phases, e.g. cpx, garnet, qtz, at the pressures, temperatures and water contents of magma generation. In contrast, mantle-dominated models suggest partial melting of the mantle wedge produces primary high-magnesia basalts (HMB) which fractionate to yield derivative HAB magmas. In this context, HMB melts should be saturated with a combination of peridotite phases, i.e. ol, cpx and opx, and have liquid-lines-of-descent that produce high-alumina basalts. HAB generated in this manner must be saturated with a mafic phase assemblage at the intensive conditions of fractionation. Multi-source models combine slab and mantle components in varying proportions to generate the four main lava types (HMB, HAB, high-magnesia andesites (HMA) and evolved lavas) characteristic of subduction zones. The mechanism of mass transfer from slab to wedge as well as the nature and fate of primary magmas vary considerably among these models. Because of their complexity, these models imply a wide range of phase equilibria. Although the experiments conducted on calc-alkaline lavas are limited, they place the following limitations on arc petrologic models: (1) HAB cannot be derived from HMB by crystal fractionation at the intensive conditions thus far investigated, (2) HAB could be produced by anhydrous partial fusion of eclogite at high pressure, (3) HMB liquids can be produced by peridotite partial fusion 50-60 km above the slab-mantle interface, (4) HMA cannot be primary magmas derived by partial melting of the subducted slab, but could have formed by slab melt-peridotite interaction, and (5) many evolved calc

  6. Petrologic Modeling of Magmatic Evolution in The Elysium Volcanic Province (United States)

    Susko, D.; Karunatillake, S.; Hood, D.


    The Elysium Volcanic Province (EVP) on Mars is a massive expanse of land made up of many hundreds of lava flows of various ages1. The variable surface ages within this volcanic province have distinct elemental compositions based on the derived values from the Gamma Ray Spectrometer (GRS) suite2. Without seismic data or ophiolite sequences on Mars, the compositions of lavas on the surface provide some of the only information to study the properties of the interior of the planet. The Amazonian surface age and isolated nature of the EVP in the northern lowlands of Mars make it ideal for analyzing the mantle beneath Elysium during the most recent geologic era on Mars. The MELTS algorithm is one of the most commonly used programs for simulating compositions and mineral phases of basaltic melt crystallization3. It has been used extensively for both terrestrial applications4 and for other planetary bodies3,5. The pMELTS calibration of the algorithm allows for higher pressure (10-30 kbars) regimes, and is more appropriate for modeling melt compositions and equilibrium conditions for a source within the martian mantle. We use the pMELTS program to model how partial melting of the martian mantle could evolve magmas into the surface compositions derived from the GRS instrument, and how the mantle beneath Elysium has changed over time. We attribute changes to lithospheric loading by long term, episodic volcanism within the EVP throughout its history. 1. Vaucher, J. et al. The volcanic history of central Elysium Planitia: Implications for martian magmatism. Icarus 204, 418-442 (2009). 2. Susko, D. et al. A record of igneous evolution in Elysium, a major martian volcanic province. Scientific Reports 7, 43177 (2017). 3. El Maarry, M. R. et al. Gamma-ray constraints on the chemical composition of the martian surface in the Tharsis region: A signature of partial melting of the mantle? Journal of Volcanology and Geothermal Research 185, 116-122 (2009). 4. Ding, S. & Dasgupta, R. The

  7. Aqueous radioactive waste bituminization

    International Nuclear Information System (INIS)

    Williamson, A.S.


    The bituminzation of decontamination and ion exchange resin stripping wastes with four grades of asphalt was investigated to determine the effects of asphalt type on the properties of the final products. All waste forms deformed readily under light loads indicating they would flow if not restrained. It was observed in all cases that product leaching rates increased as the hardness of the asphalt used to treat the waste increased. If bituminization is adopted for any Ontario Hydro aqueous radioactive wastes they should be treated with soft asphalt to obtain optimum leaching resistance and mechanical stability during interim storage should be provided by a corrosion resistant container

  8. Investigating Magmatic Processes in the Lower Levels of Mantle-derived Magmatic Systems: The Age & Emplacement of the Kunene Anorthosite Complex (SW Angola) (United States)

    Hayes, B.; Bybee, G. M.; Owen-Smith, T.; Lehmann, J.; Brower, A. M.; Ashwal, L. D.; Hill, C. M.


    Our understanding of mantle-derived magmatic systems has shifted from a notion of upper crustal, melt-dominated magma chambers that feed short-lived volcanic eruptions, to a view of more long-lived trans-crustal, mush-dominated systems. Proterozoic massif-type anorthosite systems are voluminous, plagioclase-dominated plutonic suites with ubiquitous intermediate compositions (An 50 ± 10) that represent mantle-derived magmas initially ponded at Moho depths and crystallized polybarically until emplacement at mid-crustal levels. Thus, these systems provide unique insight into magma storage and processing in the lower reaches of the magma mush column, where such interpretation has previously relied on cumulate xenoliths in lavas, geophysical data and experimental/numerical modeling. We present new CA-ID-TIMS ages and a series of detailed field observations from the largest Proterozoic anorthosite massif on Earth, the Kunene Anorthosite Complex (KAC) of SW Angola. Field structures indicate that (i) the bulk of the material was emplaced in the form of crystal mushes, as both plutons and sheet-like intrusions; (ii) prolonged magmatism led to cumulate disaggregation (block structure development) and remobilization, producing considerable textural heterogeneity; (iii) crystal-rich magmatic flow induced localized recrystallization and the development of protoclastic (mortar) textures; and (iv) late residual melts were able to migrate locally prior to complete solidification. Dating of pegmatitic pods entrained from cumulate zones at the base of the crust (1500 ± 13 Ma) and their host anorthosites (1375-1438 Ma) reveals time periods in the range of 60-120 Myr between the earliest products of the system and the final mushes emplaced at higher crustal levels. Therefore, the KAC represents a complex, mushy magmatic system that developed over a long period of time. Not only do these observations help in refining our understanding of Proterozoic anorthosite petrogenesis, they

  9. Mars aqueous chemistry experiment (United States)

    Clark, Benton C.; Mason, Larry W.


    Mars Aqueous Chemistry Experiment (MACE) is designed to conduct a variety of measurements on regolith samples, encompassing mineral phase analyses, chemical interactions with H2O, and physical properties determinations. From these data, much can be learned or inferred regarding the past weathering environment, the contemporaneous soil micro-environments, and the general chemical and physical state of the Martian regolith. By analyzing both soil and duricrust samples, the nature of the latter may become more apparent. Sites may be characterized for comparative purposes and criteria could be set for selection of high priority materials on future sample return missions. The second year of the MACE project has shown significant progress in two major areas. MACE Instrument concept definition is a baseline design that has been generated for the complete MACE instrument, including definition of analysis modes, mass estimates and thermal model. The design includes multiple reagent reservoirs, 10 discrete analysis cells, sample manipulation capability, and thermal control. The MACE Measurement subsystems development progress is reported regarding measurement capabilities for aqueous ion sensing, evolved gas sensing, solution conductivity measurement, reagent addition (titration) capabilities, and optical sensing of suspended particles.

  10. Mars aqueous chemistry experiment (United States)

    Clark, Benton C.; Mason, Larry W.


    Mars Aqueous Chemistry Experiment (MACE) is designed to conduct a variety of measurements on regolith samples, encompassing mineral phase analyses, chemical interactions with H2O, and physical properties determinations. From these data, much can be learned or inferred regarding the past weathering environment, the contemporaneous soil micro-environments, and the general chemical and physical state of the Martian regolith. By analyzing both soil and duricrust samples, the nature of the latter may become more apparent. Sites may be characterized for comparative purposes and criteria could be set for selection of high priority materials on future sample return missions. The second year of the MACE project has shown significant progress in two major areas. MACE Instrument concept definition is a baseline design that has been generated for the complete MACE instrument, including definition of analysis modes, mass estimates and thermal model. The design includes multiple reagent reservoirs, 10 discrete analysis cells, sample manipulation capability, and thermal control. The MACE Measurement subsystems development progress is reported regarding measurement capabilities for aqueous ion sensing, evolved gas sensing, solution conductivity measurement, reagent addition (titration) capabilities, and optical sensing of suspended particles.

  11. Red-Sea rift magmatism near Al Lith, Kingdom of Saudi Arabia (United States)

    Pallister, J.S.


    A newly recognized Tertiary dike complex and comagmatic volcanic rocks exposed on the central Saudi Arabian coastal plain record early stages of magmatism related to Red Sea rifting. Intrusive and stratigraphic relationships, and new potassium-argon dating indicate episodic magmatism from about 30 Ma to the present. Additional stratigraphic and radiometric evidence suggests that limited rift-related magmatism may have began as early as about 50 Ma ago. An early phase of crustal extension in the region was accompanied by faulting and graben formation and by dike-swarm intrusion. The style of extension and intrusion changed approximately 20 Ma ago. Localized volcanism and sheeted dike injection ceased and were replaced by the intrusion of thick gabbro dikes. This change may mark the onset of sea-floor spreading in the central Red Sea.

  12. Pluton emplacement and magmatic arc construction: A model from the Patagonian batholith (United States)

    Bruce, Robert; Nelson, Eric; Weaver, Stephen


    A model of batholithic construction in Andean arcs and its applicability to possibly similar environments in the past is described. Age and compositional data from the Patagonian batholith of southern Chile show a long history of magmatism in any given area (total age range is 15 to 157 Ma), but different regions appear to have different magmatic starting ages. Furthermore, mafic rocks seem to be the oldest components of any given region. An assembly line model involving semicontinuous magmatism and uplift was outlined, which has implications for other terranes: uplift rates will be proportional to observed ranges in age, and total uplift will be proportional to the age of the oldest pluton in any given area. It is suggested that misleading results would be obtained if only small areas of similar terranes in the Archean were available for study.

  13. Geodynamic setting of mesozoic magmatism and its relationship to uranium metallogenesis in southeastern China

    International Nuclear Information System (INIS)

    Chen Peirong


    In the southeastern China, magmatism was developed quite intensely in Mesozoic forming a large quantity of rare and nonferrous metal deposits. The Indosinian orogenic movement ( Early Mesozoic) and the Yanshanian movement (Late Mesozoic) provided the dynamic force for magmatism and metallogenesis in this region. The intra-plate extension was induced by the Indosinian orogenic movement in South China continent under a regionally compressional framework to form Indosinian granites. The Yanshanian movement was a post-orogenic geologic event in relation to the Indosinian orogeny, and characterized by intense lithosphere breaking-up, resulting in large scale magmatic activities and a great amount of mineral resources was formed. The Indosinian granites overprinted by the Yanshanian tectono-magma event were closely related to uranium metallogenesis and were likely a kind of uranium source rock. Therefore, research on the distribution pattern of Indosinian granitoids and factors favorable to uranium ore-formation should be enhanced during prospecting in southern China. (author)

  14. Characteristics of mesozoic magmatic rocks in western Zhejiang and their relation with uranium mineralization

    International Nuclear Information System (INIS)

    Zhou Jiazhi


    The author summarizes characteristics of Mesozoic (Yangshanian Period) acid-intermediate volcanics, sub-volcanics and basic intrusive from aspects of formation time of rock series, petrogenic sequence, chemical composition, rock -controlling factors and petrogenic environments. It is suggested that these rocks were originated from different source areas of crust and mantle. Based on the time-space relation between different types uranium deposits and magmatic rocks, the author proposes that: the earlier stage (Earlier Cretaceous) U-hematite ores were originated from acid volcanic magmatism of crustal source, but the later stage (Late Cretaceous) pitchblende-polymetallic sulfide and pitchblende-purple fluorite rich ores were derived from basic magmatism of mantle source. Finally, the author proposes prospecting criteria of the above two types of uranium deposits

  15. Decreasing Magmatic Footprints of Individual Volcanos in a Waning Basaltic Field

    Energy Technology Data Exchange (ETDEWEB)

    G.A> Valentine; F.V. Perry


    The distribution and characteristics of individual basaltic volcanoes in the waning Southwestern Nevada Volcanic Field provide insight into the changing physical nature of magmatism and the controls on volcano location. During Pliocene-Pleistocene times the volumes of individual volcanoes have decreased by more than one order of magnitude, as have fissure lengths and inferred lava effusion rates. Eruptions evolved from Hawaiian-style eruptions with extensive lavas to eruptions characterized by small pulses of lava and Strombolian to violent Strombolian mechanisms. These trends indicate progressively decreasing partial melting and length scales, or magmatic footprints, of mantle source zones for individual volcanoes. The location of each volcano is determined by the location of its magmatic footprint at depth, and only by shallow structural and topographic features that are within that footprint. The locations of future volcanoes in a waning system are less likely to be determined by large-scale topography or structures than were older, larger volume volcanoes.

  16. Understanding the Yellowstone magmatic system using 3D geodynamic inverse models (United States)

    Kaus, B. J. P.; Reuber, G. S.; Popov, A.; Baumann, T.


    The Yellowstone magmatic system is one of the largest magmatic systems on Earth. Recent seismic tomography suggest that two distinct magma chambers exist: a shallow, presumably felsic chamber and a deeper much larger, partially molten, chamber above the Moho. Why melt stalls at different depth levels above the Yellowstone plume, whereas dikes cross-cut the whole lithosphere in the nearby Snake River Plane is unclear. Partly this is caused by our incomplete understanding of lithospheric scale melt ascent processes from the upper mantle to the shallow crust, which requires better constraints on the mechanics and material properties of the lithosphere.Here, we employ lithospheric-scale 2D and 3D geodynamic models adapted to Yellowstone to better understand magmatic processes in active arcs. The models have a number of (uncertain) input parameters such as the temperature and viscosity structure of the lithosphere, geometry and melt fraction of the magmatic system, while the melt content and rock densities are obtained by consistent thermodynamic modelling of whole rock data of the Yellowstone stratigraphy. As all of these parameters affect the dynamics of the lithosphere, we use the simulations to derive testable model predictions such as gravity anomalies, surface deformation rates and lithospheric stresses and compare them with observations. We incorporated it within an inversion method and perform 3D geodynamic inverse models of the Yellowstone magmatic system. An adjoint based method is used to derive the key model parameters and the factors that affect the stress field around the Yellowstone plume, locations of enhanced diking and melt accumulations. Results suggest that the plume and the magma chambers are connected with each other and that magma chamber overpressure is required to explain the surface displacement in phases of high activity above the Yellowstone magmatic system.

  17. Geology of the Baskil (Elazığ Area and the Petrology of Baskil Magmatics

    Directory of Open Access Journals (Sweden)

    H. Jerf ASUTAY


    Full Text Available The study area which covers the region around Baskil on Eastern Taurus Range comprises of Keban metamorphics and Baskil magmatics overlain by a Tertiary sedimentary cover. The Keban metamorphics are represented by regional and contact metamorphic rocks in the study area. Calc schist and marble associations are widespread on the regional scale. Between Baskil granite and Keban metamorphics exomorphism and endomorphism zones have been developed. Metasomatic effects are observed in the contact metamorphic rocks which reflect the pyroxene-hornfels facies. The sedimentary sequence begins with Middle Paleocene (Thanetian aged rocks in the study area. The same sequence, however, has been deposited starting in Santonian-Campanian in the surrounding area. The sedimentary rock sequence which is composed of Kuşçular conglomerate, Seske formation, Kırkgeçit formation (Paleocene-Plio-Quaternary are represented by conglomerate, carbonates and flysch kind of sedimentary rocks. Baskil magmatics are an association of plutonic, hypabyssal and volcanic rocks. Of this association, Baskil granite contains dioritic, monzonitic and tonalitic kind of magmatic rocks which are mostly observed as transitional. Baskil granite, in the study area, is frequently cut across by basic and acidic dykes which locally intrudes between the granite and the basaltic, andesitic rocks overlying the granite and are transitional with the volcanics. Chemically, Baskil granite is of calc-alkaline type. It is rich in silica and alkaline. Trace element distribution is quite regular. Baskil granite which is determined as of type 'I' is generally rich in hornblende but poor in muscovite and biotite. It shows the features of continental margin magmatism and is an example of systematic differentiation. Considering their features and under the light of plate tectonics concept, Baskil magmatics may be said to be a product of continental margin magmatism. They are, presumably, the products of an

  18. Aqueous electrolytes for redox flow battery systems (United States)

    Liu, Tianbiao; Li, Bin; Wei, Xiaoliang; Nie, Zimin; Wang, Wei; Liu, Jun; Sprenkle, Vincent L.


    An aqueous redox flow battery system includes an aqueous catholyte and an aqueous anolyte. The aqueous catholyte may comprise (i) an optionally substituted thiourea or a nitroxyl radical compound and (ii) a catholyte aqueous supporting solution. The aqueous anolyte may comprise (i) metal cations or a viologen compound and (ii) an anolyte aqueous supporting solution. The catholyte aqueous supporting solution and the anolyte aqueous supporting solution independently may comprise (i) a proton source, (ii) a halide source, or (iii) a proton source and a halide source.

  19. Magmatism and fenitization in the Cretaceous potassium-alkaline-carbonatitic complex of Ipanema São Paulo State, Brazil (United States)

    Guarino, Vincenza; Azzone, Rogério Guitarrari; Brotzu, Pietro; de Barros Gomes, Celso; Melluso, Leone; Morbidelli, Lucio; Ruberti, Excelso; Tassinari, Colombo Celso Gaeta; Brilli, Mauro


    The Ipanema alkaline-carbonatitic complex is part of the Meso-Cenozoic alkaline magmatism located within the southeastern part of the Brazilian Platform. Drill-core and field sampling have indicated the occurrence of glimmerites, with subordinate shonkinites (mela-syenites), clinopyroxene-bearing glimmerites, diorites and syenites. The glimmerites are cross-cut by lamprophyric dykes and calciocarbonatites. Fenitization has deeply affected the country rocks, originating dioritic and syenitic rocks. The Ipanema rocks show a distinct potassic affinity. The initial Sr-Nd- isotopic composition of the Ipanema rocks (87Sr/86Sr = 0.70661-0.70754 and 143Nd/144Nd = 0.51169-0.51181) is similar to that of tholeiitic and potassium-rich-alkaline rocks of the Eastern Paraguay. Stable isotope data for the Ipanema calciocarbonatite suggest interaction with fluids at temperatures typical of hydrothermal stages, as hypothesized for other carbonatite complexes from southeastern Brazil. The chemical differences between the lamprophyre, glimmerites, carbonatites, apatitites and magnetitites, and the absence of marked REE enrichment in the evolved lithologies, all indicate that fractional crystallization and accumulus of liquidus phases in a magma reservoir, likely coupled with liquid immiscibility processes, may have played an important role in the genesis of the Ipanema rocks.

  20. Magmatic and Crustal Differentiation History of Granitic Rocks from Hf-O Isotopes in Zircon (United States)

    Kemp, , A. I. S.; Hawkesworth, , C. J.; Foster, , G. L.; Paterson, , B. A.; Woodhead, , J. D.; Hergt, , J. M.; Gray, , C. M.; Whitehouse, M. J.


    Granitic plutonism is the principal agent of crustal differentiation, but linking granite emplacement to crust formation requires knowledge of the magmatic evolution, which is notoriously difficult to reconstruct from bulk rock compositions. We unlocked the plutonic archive through hafnium (Hf) and oxygen (O) isotope analysis of zoned zircon crystals from the classic hornblende-bearing (I-type) granites of eastern Australia. This granite type forms by the reworking of sedimentary materials by mantle-like magmas instead of by remelting ancient metamorphosed igneous rocks as widely believed. I-type magmatism thus drives the coupled growth and differentiation of continental crust.

  1. Duration of Parana magmatism and implications for the evolution and source regions of continental flood basalts

    International Nuclear Information System (INIS)

    Mantovani, M.S.M.; Stewart, K.; Turner, S.; Hawkesworth, C.J.


    Duration of Continental Floods Basalts magmatism has generally been considered to be extremely short. Ar-Ar data for different magma type, over a broad region within Parana, demonstrate a duration of 10 Ma, an order of magnitude greater than the usually accepted duration of magmatism. The dating method included rigorous geochemical selection tests, to discard altered samples, combined with the analysis of laser spot technique using the isochron approach. This methodology allows discrimination between rocks which yield precise ages and those which are too altered or heterogeneous. The agreement between the determined age and the relative stratigraphic position of samples supports the above statement. 4 figs

  2. Duration of Parana magmatism and implications for the evolution and source regions of continental flood basalts

    Energy Technology Data Exchange (ETDEWEB)

    Mantovani, M.S.M. [Sao Paulo Univ., SP (Brazil). Inst. Astronomico e Geofisico; Stewart, K.; Turner, S.; Hawkesworth, C.J. [Open Univ., Milton Keynes (United Kingdom). Dept. of Earth Sciences


    Duration of Continental Floods Basalts magmatism has generally been considered to be extremely short. Ar-Ar data for different magma type, over a broad region within Parana, demonstrate a duration of 10 Ma, an order of magnitude greater than the usually accepted duration of magmatism. The dating method included rigorous geochemical selection tests, to discard altered samples, combined with the analysis of laser spot technique using the isochron approach. This methodology allows discrimination between rocks which yield precise ages and those which are too altered or heterogeneous. The agreement between the determined age and the relative stratigraphic position of samples supports the above statement. 4 figs.

  3. Asymmetric rifting, breakup and magmatism across conjugate margin pairs: insights from Newfoundland to Ireland (United States)

    Peace, Alexander L.; Welford, J. Kim; Foulger, Gillian R.; McCaffrey, Ken J. W.


    Continental extension, subsequent rifting and eventual breakup result in the development of passive margins with transitional crust between extended continental crust and newly created oceanic crust. Globally, passive margins are typically classified as either magma-rich or magma-poor. Despite this simple classification, magma-poor margins like the West Orphan Basin, offshore Newfoundland, do exhibit some evidence of localized magmatism, as magmatism to some extent invariably accompanies all continental breakup. For example, on the Newfoundland margin, a small volcanic province has been interpreted near the termination of the Charlie Gibbs Fracture Zone, whereas on the conjugate Irish margin within the Rockall Basin, magmatism appears to be more widespread and has been documented both in the north and in the south. The broader region over which volcanism has been identified on the Irish margin is suggestive of magmatic asymmetry across this conjugate margin pair and this may have direct implications for the mechanisms governing the nature of rifting and breakup. Possible causes of the magmatic asymmetry include asymmetric rifting (simple shear), post-breakup thermal anomalies in the mantle, or pre-existing compositional zones in the crust that predispose one of the margins to more melting than its conjugate. A greater understanding of the mechanisms leading to conjugate margin asymmetry will enhance our fundamental understanding of rifting processes and will also reduce hydrocarbon exploration risk by better characterizing the structural and thermal evolution of hydrocarbon bearing basins on magma-poor margins where evidence of localized magmatism exists. Here, the latest results of a conjugate margin study of the Newfoundland-Ireland pair utilizing seismic interpretation integrated with other geological and geophysical datasets are presented. Our analysis has begun to reveal the nature and timing of rift-related magmatism and the degree to which magmatic asymmetry

  4. Magmatic Diversity of the Wehrlitic Intrusions in the Oceanic Lower Crust of the Northern Oman Ophiolite (United States)

    Kaneko, R.; Adachi, Y.; Miyashita, S.


    The Oman ophiolite extends along the east coast of Oman, and is the world's largest and best-preserved slice of obducted oceanic lithosphere. The magmatic history of this ophiolite is complex and is generally regarded as having occurred in three stages (MOR magmatism, subduction magmatism and intraplate magmatism). Wehrlitic intrusions constitute an important element of oceanic lower crust of the ophiolite, and numerous intrusions cut gabbro units in the northern Salahi block of this ophiolite. In this study area, we identified two different types of wehrlitic intrusions. One type of the intrusions mainly consists of dunite, plagioclase (Pl) wehrlite and mela-olivine (Ol) gabbro, in which the crystallization sequence is Ol followed by the contemporaneous crystallization of Pl and clinopyroxene (Cpx). This type is called "ordinary" wehrlitic intrusions and has similar mineral compositions to host gabbros (Adachi and Miyashita 2003; Kaneko et al. 2014). Another type of the intrusions is a single intrusion that crops out in an area 250 m × 150 m along Wadi Salahi. This intrusion consists of Pl-free "true" wehrlite, in which the crystallization sequence is Ol and then Cpx. The forsterite contents (Fo%) of Ol from the "ordinary" wehrlitic intrusions and "true" wehrlitic intrusions have ranges of 90.8-87.0 (NiO = 0.36-0.13 wt%) and 84.7 (NiO = 0.31 wt%), respectively. Cr numbers (Cr#) of Cr-spinel from the "true" wehrlitic intrusions show higher Cr# value of 0.85 than those of the "ordinary" wehrlitic intrusions (0.48-0.64). But the former is characterized by very high Fe3+ values (YFe3+ = 0.49-0.68). Kaneko et al. (2014) showed that the "ordinary" ubiquitous type has similar features to MOR magmatism and the depleted type in the Fizh block (Adachi and Miyashita 2003) links to subduction magmatism. These types are distinguished by their mineral chemistries (TiO2 and Na2O contents of Cpx). The TiO2 and Na2O contents of Cpx from the "true" wehrlitic intrusions have 0

  5. Episodic melting and magmatic recycling along 50 Ma in the Variscan belt linked to the orogenic evolution in NW Iberia (United States)

    Gutiérrez-Alonso, G.; López-Carmona, A.; García Acera, G.; Martín Garro, J.; Fernández-Suárez, J.; Gärtner, A.; Hofmann, M.


    The advent of a large amount of more precise U-Pb age data on Variscan granitoids from NW Iberia in recent years has provided a more focused picture of the magmatic history of the Western European Variscan belt (WEVB). Based on these data, three main pulses of magmatic activity seem to be well established.

  6. Reconstructing Magmatic-Hydrothermal Systems via Geologic Mapping of the Tilted, Cross-sectional Exposures of the Yerington District, Nevada (United States)

    Dilles, J. H.; Proffett, J. M.


    The Jurassic Yerington batholith was cut by Miocene to recent normal faults and tilted ~90° west (Proffett, 1977). Exposures range from the volcanic environment to ~6 km depth in the batholith. Magmatic-hydrothermal fluids derived from the Luhr Hill granite and associated porphyry dikes produced characteristic porphyry copper mineralization and rock alteration (K-silicate, sericitic, and advanced argillic) in near-vertical columnar zones above cupolas on the deep granite. In addition, saline brines derived from the early Mesozoic volcanic and sedimentary section intruded by the batholith were heated and circulated through the batholith producing voluminous sodic-calcic and propylitic alteration. The magnetite-copper ore body at Pumpkin Hollow is hosted in early Mesozoic sedimentary rocks in the contact aureole of the batholith, and appears to be an IOCG type deposit produced where the sedimentary brines exited the batholith. Although many advances in understanding of Yerington have been made by lab-based geochronology and geochemistry studies, the first order igneous and hydrothermal features were recognized first in the 1960s and 1970s and are best documented by geological mapping at a variety of scales ranging from 1:500 to 1:24,000. The Anaconda technique of mapping mine benches, trenches, and drill cores was perfected here (Einaudi, 1997), and other techniques were used for surface exposures. The geologic and hydrothermal alteration maps establish that hydrothermal alteration accompanied each of several porphyry dike intrusions, and affected more than 100 km3 of rock. Both zonation in alteration mineralogy and vein orientations allow reconstruction of source areas and >5 km-long flow-paths of hydrothermal fluids through the batholith and contact aureole.

  7. The aqueous chemistry of oxides

    CERN Document Server

    Bunker, Bruce C


    The Aqueous Chemistry of Oxides is a comprehensive reference volume and special topics textbook that explores all of the major chemical reactions that take place between oxides and aqueous solutions. The book highlights the enormous impact that oxide-water reactions have in advanced technologies, materials science, geochemistry, and environmental science.

  8. Aqueous reprocessing - some dreams!

    International Nuclear Information System (INIS)

    Srinivasan, T.G.


    India has been pursuing a aqueous reprocessing based closed fuel cycle for both thermal and fast reactor fuels employing the PUREX process. Though the country has more than six decades of experience, the dreams or wish lists such as, a highly efficient process with textbook specifications of 99.9% recovery of U and Pu, a DF of more than 10 7 for both U and Pu from the fission products, operating with name plate capacity with high safety, low waste generation, recovery of useful fission products and minor actinides from high level waste are never ceasing and ever growing. The talk will cover safety precautions and actions to be taken in the steps listed below, to ensure a safe and successful process

  9. Aqueous chemical dosimetry

    International Nuclear Information System (INIS)

    Matthews, R.W.


    Aqueous chemical dosimetry based on ceric and ferrous sulfate solutions and on a number of fluorescence-induced systems is reviewed. Particular attention is given to the factors affecting the response of these dosimeters to radiation and the corrections necessary for more accurate dosimetry under various irradiation conditions. The effect of cerous and ceric ion, oxygen, and sulfuric acid concentration on the ceric dosimeter is discussed together with the effects of temperature, energy of radiation, degraded energy spectra, and peroxysulfuric acids. Practical aspects of ceric/cerous dosimetry are given. Although ferrous sulfate solution is the most important and widely studied reference dosimeter, general agreement has not been reached on the ''best'' value for the molar extinction coefficient of ferric ions nor on the correction necessary to the G(Fe 3 - ) value for irradiations at temperatures significantly different from 25 0 C. New data are presented which indicate that the larger temperature coefficients given in the literature are more accurate. The ferrous sulfate system has been of great importance in establishing the primary radiolytic yields for 0.4 M sulfuric acid solution; it is shown how the failure to take into account the effect of oxygen and ferrous sulfate concentrations has led to erroneously high estimates of the zero solute concentration values in acid solutions. Some of the methods for extending the dose ranges measurable with ferrous sulfate-based solutions are reviewed. Substances which on irradiation give highly fluorescent products are among the most sensitive aqueous chemical dosimeters. These include benzoate and terephthalate solutions and the more recent coumarin and trimesate solutions. Advantages and disadvantages system are discussed. (author)

  10. The non-destructive analysis of fluid inclusions in minerals using the proton microprobe

    Energy Technology Data Exchange (ETDEWEB)

    Ryan, C.G.; Van Achterbergy, E. [Commonwealth Scientific and Industrial Research Organisation (CSIRO), North Ryde, NSW (Australia). Div. of Exploration Geoscience; Heinrich, C.A. [ETH Zentrum, Zurich, (Switzerland). Department Erdwissenschaften; Mernagh, T.P. [Max-Planck-Institut fuer Chemie (Otto-Hahn-Institut), Mainz (Germany); Zaw, K. [Tasmania Univ., Sandy Bay, TAS (Australia)


    The study of ore forming fluids trapped as fluid inclusions in minerals is the key to understanding fluid flow paths at the time of ore formation and to predicting the location of ore bodies within large-scale magmatic hydrothermal systems. The large penetration depths and the predictable nature of MeV proton trajectories and X-ray absorption enables reliable modelling of PIXE yields and the development of standardless quantitative analytical methods. This permits quantitative microanalysis of minerals at ppm levels, and more recently has enabled the development of methods for quantitative trace-element imaging and the quantitative, non-destructive analysis of individual fluid inclusions. This paper reports on recent developments in Proton Microprobe techniques with special emphasis on ore systems and fluid inclusion analysis. 6 refs., 2 figs.

  11. The non-destructive analysis of fluid inclusions in minerals using the proton microprobe

    Energy Technology Data Exchange (ETDEWEB)

    Ryan, C G; Van Achterbergy, E [Commonwealth Scientific and Industrial Research Organisation (CSIRO), North Ryde, NSW (Australia). Div. of Exploration Geoscience; Heinrich, C A [ETH Zentrum, Zurich, (Switzerland). Department Erdwissenschaften; Mernagh, T P [Max-Planck-Institut fuer Chemie (Otto-Hahn-Institut), Mainz (Germany); Zaw, K [Tasmania Univ., Sandy Bay, TAS (Australia)


    The study of ore forming fluids trapped as fluid inclusions in minerals is the key to understanding fluid flow paths at the time of ore formation and to predicting the location of ore bodies within large-scale magmatic hydrothermal systems. The large penetration depths and the predictable nature of MeV proton trajectories and X-ray absorption enables reliable modelling of PIXE yields and the development of standardless quantitative analytical methods. This permits quantitative microanalysis of minerals at ppm levels, and more recently has enabled the development of methods for quantitative trace-element imaging and the quantitative, non-destructive analysis of individual fluid inclusions. This paper reports on recent developments in Proton Microprobe techniques with special emphasis on ore systems and fluid inclusion analysis. 6 refs., 2 figs.

  12. Synovial fluid analysis (United States)

    Joint fluid analysis; Joint fluid aspiration ... El-Gabalawy HS. Synovial fluid analysis, synovial biopsy, and synovial pathology. In: Firestein GS, Budd RC, Gabriel SE, McInnes IB, O'Dell JR, eds. Kelly's Textbook of ...

  13. Sildenafil Stimulates Aqueous Humor Turnover in Rabbits (United States)

    Alvarez, Lawrence J.; Zamudio, Aldo C.; Candia, Oscar A.


    Sildenafil citrate increases ocular blood flow and accelerates the rate of anterior chamber refilling after paracentesis. The latter effect could have resulted from a reduction in outflow facility or from an increase in aqueous humor (AH) production. In this study, we used scanning ocular fluorophotometry to examine the effects of sildenafil on AH turnover, and thus, AH production in eyes of live normal rabbits. For this, the rate of aqueous humor flow (AHF) was quantified with a commercially available fluorophotometer that measured the rate of fluorescein clearance from the anterior segment, which predominantly occurs via the trabecular meshwork. After ≈ 2 hrs of control scans to determine the baseline rate of AHF, the rabbits were fed 33 mg of sildenafil and allowed ≈ 45 min for the drug to enter the systemic circulation. Thereafter, fluorescence scans were retaken for an additional 90–120 min. Sildenafil ingestion increased AHF by about 36%, from 2.31 μL/min to 3.14 μL/min (PViagra, Revatio), stimulates AHF in rabbits. Our results seem consistent with reports indicating that the drug dilates intraocular arteries and augments intraocular vascular flow. These physiological responses to the agent apparently led to increased fluid entry into the anterior chamber. As such, the drug might have utility in patients with ocular hypotony resulting from insufficient AH formation. PMID:23562660

  14. Jurassic-Paleogene intraoceanic magmatic evolution of the Ankara Mélange, north-central Anatolia, Turkey (United States)

    Sarifakioglu, E.; Dilek, Y.; Sevin, M.


    Oceanic rocks in the Ankara Mélange along the Izmir-Ankara-Erzincan suture zone (IAESZ) in north-central Anatolia include locally coherent ophiolite complexes (∼ 179 Ma and ∼ 80 Ma), seamount or oceanic plateau volcanic units with pelagic and reefal limestones (96.6 ± 1.8 Ma), metamorphic rocks with ages of 256.9 ± 8.0 Ma, 187.4 ± 3.7 Ma, 158.4 ± 4.2 Ma, and 83.5 ± 1.2 Ma indicating northern Tethys during the late Paleozoic through Cretaceous, and subalkaline to alkaline volcanic and plutonic rocks of an island arc origin (∼ 67-63 Ma). All but the arc rocks occur in a shale-graywacke and/or serpentinite matrix, and are deformed by south-vergent thrust faults and folds that developed in the middle to late Eocene due to continental collisions in the region. Ophiolitic volcanic rocks have mid-ocean ridge (MORB) and island arc tholeiite (IAT) affinities showing moderate to significant large ion lithophile elements (LILE) enrichment and depletion in Nb, Hf, Ti, Y and Yb, which indicate the influence of subduction-derived fluids in their melt evolution. Seamount/oceanic plateau basalts show ocean island basalt (OIB) affinities. The arc-related volcanic rocks, lamprophyric dikes and syenodioritic plutons exhibit high-K shoshonitic to medium- to high-K calc-alkaline compositions with strong enrichment in LILE, rare earth elements (REE) and Pb, and initial ɛNd values between +1.3 and +1.7. Subalkaline arc volcanic units occur in the northern part of the mélange, whereas the younger alkaline volcanic rocks and intrusions (lamprophyre dikes and syenodioritic plutons) in the southern part. The late Permian, Early to Late Jurassic, and Late Cretaceous amphibole-epidote schist, epidote-actinolite, epidote-chlorite and epidote-glaucophane schists represent the metamorphic units formed in a subduction channel in the northern Neotethys. The Middle to Upper Triassic neritic limestones spatially associated with the seamount volcanic rocks indicate that the northern

  15. Jurassic-Paleogene intra-oceanic magmatic evolution of the Ankara Mélange, North-Central Anatolia, Turkey (United States)

    Sarifakioglu, E.; Dilek, Y.; Sevin, M.


    Oceanic rocks in the Ankara Mélange along the Izmir-Ankara-Erzincan suture zone (IAESZ) in North-Central Anatolia include locally coherent ophiolite complexes (~179 Ma and ~80 Ma), seamount or oceanic plateau volcanic units with pelagic and reefal limestones (96.6 ± 1.8 Ma), metamorphic rocks with ages of 187.4 ± 3.7 Ma, 158.4 ± 4.2 Ma, and 83.5 ± 1.2 Ma, and subalkaline to alkaline volcanic and plutonic rocks of an island arc origin (~67-63 Ma). All but the arc rocks occur in a shaly-graywacke and/or serpentinite matrix, and are deformed by south-vergent thrust faults and folds that developed in the Middle to Late Eocene due to continental collisions in the region. Ophiolitic volcanic rocks have mid-ocean ridge (MORB) and island arc tholeiite (IAT) affinities showing moderate to significant LILE enrichment and depletion in Nb, Hf, Ti, Y and Yb, which indicate the influence of subduction-derived fluids in their melt evolution. Seamount/oceanic plateau basalts show ocean island basalt (OIB) affinities. The arc-related volcanic rocks, lamprophyric dikes and syeno-dioritic plutons exhibit high-K shoshonitic to medium-to high-K calc-alkaline compositions with strong enrichment in LILE, REE and Pb, and initial ϵNd values between +1.3 and +1.7. Subalkaline arc volcanic units occur in the northern part of the mélange, whereas the younger alkaline volcanic rocks and intrusions (lamprophyre dikes and syeno-dioritic plutons) in the southern part. The Early to Late Jurassic and Late Cretaceous epidote-actinolite, epidote-chlorite and epidote-glaucophane schists represent the metamorphic units formed in a subduction channel in the Northern Neotethys. The Middle to Upper Triassic neritic limestones spatially associated with the seamount volcanic rocks indicate that the Northern Neotethys was an open ocean with its MORB-type oceanic lithosphere by the Early Triassic. The Latest Cretaceous-Early Paleocene island arc volcanic, dike and plutonic rocks with

  16. D/N and /sup 18/O//sup 16/O in magmatic waters and gases of the Great Tolbachik fissure eruption, Kamchatka

    Energy Technology Data Exchange (ETDEWEB)

    Menyailov, I A; Vetshtein, V E; Nikitina, L P; Artemchuk, V G [AN SSSR, Petropavlovsk-Kamchatskii. Inst. Vulkanologii; AN Ukrainskoj SSR, Kiev. Inst. Geokhimii i Fiziki Mineralov)


    Isotope content of magmatic gases and their condensates (magmatic waters) is studied on the basis of the Great Tolbachik fissure eruption, Kamchatka. The phenomenon of regular increase of deuterium content in magmatic water and protium content in gases is found out. It is supposed that this fact is conditioned by isotope fractionation during phase transitions in liquid-steam-gas system in the process of the formation of magmatic hearth and gas release from magma during eruption.

  17. The Kalatongke magmatic Ni-Cu deposits in the Central Asian Orogenic Belt, NW China: product of slab window magmatism? (United States)

    Li, Chusi; Zhang, Mingjie; Fu, Piaoer; Qian, Zhuangzhi; Hu, Peiqing; Ripley, Edward M.


    The Permian Kalatongke Ni-Cu deposits in the Central Asian Orogenic Belt are among the most important Ni-Cu deposits in northern Xinjiang, western China. The deposits are hosted by three small mafic intrusions comprising mainly norite and diorite. Its tectonic context, petrogenesis, and ore genesis have been highly contested. In this paper, we present a new model involving slab window magmatism for the Kalatongke intrusions. The origin of the associated sulfide ores is explained in the context of this new model. Minor amounts of olivine in the intrusions have Fo contents varying between 71 and 81.5 mol%, which are similar to the predicted values for olivine crystallizing from coeval basalts in the region. Analytic modeling based on major element concentrations suggests that the parental magma of the Kalatongke intrusions and the coeval basalts represent fractionated liquids produced by ˜15% of olivine crystallization from a primary magma, itself produced by 7-8% partial melting of depleted mantle peridotite. Positive ɛ Nd values (+4 to +10) and significant negative Nb anomalies for both intrusive and extrusive rocks can be explained by the mixing of magma derived from depleted mantle with 6-18% of a partial melt derived from the lower part of a juvenile arc crust with a composition similar to coeval A-type granites in the region, plus up to 10% contamination with the upper continental crust. Our model suggests that a slab window was created due to slab break-off during a transition from oceanic subduction to arc-arc or arc-continent collision in the region in the Early Permian. Decompression melting in the upwelling oceanic asthenosphere produced the primary magma. When this magma ascended to pond in the lower parts of a juvenile arc crust, it underwent olivine crystallization and at the same time triggered partial melting of the arc crust. Mixing between these two magmas followed by contamination with the upper crust after the magma ascended to higher crustal

  18. Study of Mururoa's basaltic massif alteration (French Polynesia): solid and fluid phases analysis and thermodynamical modeling

    International Nuclear Information System (INIS)

    Destrigneville, Christine


    The alteration processes occurring in the volcanics of Mururoa have been studied using petrological data on secondary minerals, chemical analyses of the interstitial fluids and isotopic analyses on both minerals and fluids. Chemical and isotopic exchanges were first modelled, then thermodynamical modeling characterized the chemical evolution during the alteration of the secondary assemblage and of the fluid. The main secondary sequences which have been observed in Mururoa volcanics result from the alteration occurring during the lavas setting. Two different processes have been evidenced. The first one is the deuteric alteration with the CO_2-rich magmatic fluid exsolved from the magma and trapped in the vesicles and the olivine microcracks of the lava intrusions. This alteration in a closed system is dominated by the solid phases when the CO_2 molar fraction in the fluid is higher than 0.25. The second process is the alteration of the lavas by seawater or a meteoric fluid. The basaltic flows present alteration assemblages composed of clay minerals and zeolites whose chemical composition has been forced by the fluid composition. Shallowness emissions of lavas result in completely argillized levels. The present interstitial fluids chemistry result from the percolation of seawater in the volcano. In the argillized levels the fluids have interacted with the clay minerals and their chemical compositions have been modified. The important chemical changes in the present interstitial fluids show that the present alteration in the volcano is higher than the fluids circulation. (author) [fr

  19. Self lubricating fluid bearings

    International Nuclear Information System (INIS)

    Kapich, D.D.


    The invention concerns self lubricating fluid bearings, which are used in a shaft sealed system extending two regions. These regions contain fluids, which have to be isolated. A first seal is fluid tight for the first region between the carter shaft and the shaft. The second seal is fluid tight between the carter and the shaft, it communicates with the second region. The first fluid region is the environment surrounding the shaft carter. The second fluid region is a part of a nuclear reactor which contains the cooling fluid. The shaft is conceived to drive a reactor circulating and cooling fluid [fr

  20. Modern fluid dynamics

    CERN Document Server

    Kleinstreuer, Clement


    Modern Fluid Dynamics, Second Edition provides up-to-date coverage of intermediate and advanced fluids topics. The text emphasizes fundamentals and applications, supported by worked examples and case studies. Scale analysis, non-Newtonian fluid flow, surface coating, convection heat transfer, lubrication, fluid-particle dynamics, microfluidics, entropy generation, and fluid-structure interactions are among the topics covered. Part A presents fluids principles, and prepares readers for the applications of fluid dynamics covered in Part B, which includes computer simulations and project writing. A review of the engineering math needed for fluid dynamics is included in an appendix.

  1. Observational Constraints on the Identification of Shallow Lunar Magmatism: Insights from Floor-Fractured Craters (United States)

    Jozwiak, L. M.; Head, J. W., III; Neumann, G. A.; Wilson, L.


    Floor-fractured craters are a class of lunar crater hypothesized to form in response to the emplacement of a shallow magmatic intrusion beneath the crater floor. The emplacement of a shallow magmatic body should result in a positive Bouguer anomaly relative to unaltered complex craters, a signal which is observed for the average Bouguer anomaly interior to the crater walls. We observe the Bouguer anomaly of floor-fractured craters on an individual basis using the unfiltered Bouguer gravity solution from GRAIL and also a degree 100-600 band-filtered Bouguer gravity solution. The low-magnitude of anomalies arising from shallow magmatic intrusions makes identification using unfiltered Bouguer gravity solutions inconclusive. The observed anomalies in the degree 100-600 Bouguer gravity solution are spatially heterogeneous, although there is spatial correlation between volcanic surface morphologies and positive Bouguer anomalies. We interpret these observations to mean that the spatial heterogeneity observed in the Bouguer signal is the result of variable degrees of magmatic degassing within the intrusions.

  2. Magmatic tempo of Earth's youngest exposed plutons as revealed by detrital zircon U-Pb geochronology. (United States)

    Ito, Hisatoshi; Spencer, Christopher J; Danišík, Martin; Hoiland, Carl W


    Plutons are formed by protracted crystallization of magma bodies several kilometers deep within the crust. The temporal frequency (i.e. episodicity or 'tempo') of pluton formation is often poorly constrained as timescales of pluton formation are largely variable and may be difficult to resolve by traditional dating methods. The Hida Mountain Range of central Japan hosts the youngest exposed plutons on Earth and provides a unique opportunity to assess the temporal and spatial characteristics of pluton emplacement at high temporal resolution. Here we apply U-Pb geochronology to zircon from the Quaternary Kurobegawa Granite and Takidani Granodiorite in the Hida Mountain Range, and from modern river sediments whose fluvial catchments include these plutons in order to reconstruct their formation. The U-Pb data demonstrate that the Kurobegawa pluton experienced two magmatic pulses at ~2.3 Ma and ~0.9 Ma; whereas, to the south, the Takidani pluton experienced only one magmatic pulse at ~1.6 Ma. These data imply that each of these magmatic systems were both spatially and temporally distinct. The apparent ~0.7 Myr age gap between each of the three magmatic pulses potentially constrains the recharge duration of a single pluton within a larger arc plutonic complex.

  3. The timing and sources of intraplate magmatism related to continental breakup in southern New Zealand

    DEFF Research Database (Denmark)

    van der Meer, Quinten

    related I- to I/S-type plutons of the Rahu suite up to 105 Ma. Isolated plutonism continued on a smaller scale after 105 Ma. O and Hf isotopes in zircon from later felsic plutons indicate waning subduction related magmatism up to 101 Ma. This is followed by the regional dominance of intraplate signatures...

  4. Evidence for triple-junction rifting focussed on local magmatic centres along Parga Chasma, Venus (United States)

    Graff, J. R.; Ernst, R. E.; Samson, C.


    Parga Chasma is a discontinuous rift system marking the southern boundary of the Beta-Atla-Themis (BAT) region on Venus. Along a 1500 km section of Parga Chasma, detailed mapping of Magellan Synthetic Aperture Radar images has revealed 5 coronae, 11 local rift zones distinct from a regional extension pattern, and 47 graben-fissure systems with radiating (28), linear (12) and circumferential (7) geometries. The magmatic centres of these graben-fissure systems typically coincide with coronae or large volcanoes, although a few lack any central magmatic or tectonic feature (i.e. are cryptic). Some of the magmatic centres are interpreted as the foci of triple-junction rifting that form the 11 local rift zones. Cross-cutting relationships between graben-fissure systems and local rift faults reveal synchronous formation, implying a genetic association. Additionally, cross-cutting relationships show that local rifting events postdate the regional extension along Parga Chasma, further indicating multiple stages of rifting. Evidence for multiple centres of younger magmatism and local rifting against a background of regional extension provides an explanation for the discontinuous morphology of Parga Chasma. Examination of the Atlantic Rift System (prior to ocean opening) on Earth provides an analogue to the rift morphologies observed on Venus.

  5. Sr-Nd-Pb isotopes of the post-paleozoic magmatism from eastern Paraguay

    International Nuclear Information System (INIS)

    Comin-Chiaramonti, P; Gasparon, M; Gomes, C.B; Antonini, P


    The Parana Angola-Namibia igneous province (PAN) is characterized by Early Cretaceous flood tholeiites and tholeiitic dyke swarms associated with alkaline rocks of Early and Late Cretaceous ages, respectively, and with scarce post-Mesozoic magmatic rocks (Comin-Chiaramonti et al., 1997; 1999; Marques et al., 1999). The Eastern Paraguay, at the westernmost side of the Parana Basin, is of special interest because: (1) it is located between two main cratonic blocks, i.e. the southernmost tip of the Amazon Craton, and the northermost exposure of the Rio de La Plata Craton; (2) it was the site of repeated Na-K-alkaline magmatism since Late-Permian-Triassic times (i.e.: 250-240 Ma, Na-alkaline; c. 145 Ma, K-alkaline; 128-126 Ma, K-alkaline; 120-90 Ma, Na-alkaline; 61-33 Ma, Na-alkaline; cf. Comin-Chiaramonti and Gomes, 1996; Comin-Chiaramonti et al., 1999), and of Early Cretaceous tholeiitic magmatism, both low- and high-Ti variants, L-Ti and H-Ti, respectively (133-131 Ma; cf. Marzoli et al., 1999); (3) the younger sodic magmatic rocks are closely associated in space to the potassic analogues (Comin- Chiaramonti et al., 1999). The paper aims discussing the most important Sr- Nd-Pb isotope features of the alkaline and tholeiitic magmas from Eastern Paraguay in comparison with the PAN analogues (au)

  6. History of the magmatic feeding system of the Campi Flegrei caldera (Italy) (United States)

    Civetta, L.; Arienzo, I.; D'Antonio, M.; di Renzo, V.; di Vito, M. A.; Orsi, G.


    The definition of the magmatic feeding system of active volcanoes in terms of architecture, composition, crystallization time-scale, relationships between composition of the erupted magmas and structural position of the vents, and magma processes, is of paramount importance for volcanic hazards evaluation. Investigations aimed at defining the Campi Flegeri magmatic system, include detailed mineralogical, geochemical and isotopic analyses (Sr, Nd, Pb, Th,U). The magmatic feeding system of the Campi Flegrei caldera is characterized by deep and shallow magma reservoirs. In the deep reservoirs (20-10 km depth) mantle- derived magmas differentiated and were contaminated by continental crust. In the shallow reservoirs isotopically distinct magmas, further differentiated, contaminated, and mixed and mingled before eruptions. These processes generated isotopically distinct components, variably interacting with the different structural elements of the Campi Flegrei caldera through time. The relationships between the structural position of the eruption vents, during the last 15 ka of activity, and the isotopic composition of the magmas erupted at the Campi Flegrei caldera allow us to reconstruct the architecture of the magmatic feeding system and to infer the chemical and isotopic composition of the magma feeding a future eruption, according to vent position.

  7. History of the Magmatic Feeding System of the Campi Flegrei Caldera (United States)

    Orsi, G.; Civetta, L.; Arienzo, I.; D'Antonio, M.; di Renzo, V.; di Vito, M. A.


    The definition of the magmatic feeding system of active volcanoes, in terms of composition, time-scale of crystallization, relation between composition of the erupted magma and structural position of vents, magma chamber processes and architecture, is of extreme importance for the hazard evaluation. The studies that are carried out for the definition of the magmatic systems include detailed mineralogical, geochemical and isotopic analyses (Sr, Nd, Pb). The Campi Flegrei caldera magmatic structure is characterized by deep and shallow magma chambers. In the deep reservoir (20-10 km depth) mantle derived magmas differentiate and are contaminated with continental crust. In the shallow reservoirs isotopically distinct magmas further differentiate, mix and mingle before the eruptions. These processes generated isotopically distinct components that were variably involved along different structures of the Campi Flegrei caldera during time. At Campi Flegrei caldera the relation between the structural position of the eruptive vent, for the last 14 ka of activity, and the isotopic composition of the emitted magma allow us to reconstruct the architecture of the magmatic feeding system and to infer the chemical and isotopic composition, and the magma chamber location and processes, of the future eruption, according to the position of the vent

  8. An isotopic perspective on growth and differentiation of Proterozoic orogenic crust: From subduction magmatism to cratonization (United States)

    Johnson, Simon P.; Korhonen, Fawna J.; Kirkland, Christopher L.; Cliff, John B.; Belousova, Elena A.; Sheppard, Stephen


    The in situ chemical differentiation of continental crust ultimately leads to the long-term stability of the continents. This process, more commonly known as 'cratonization', is driven by deep crustal melting with the transfer of those melts to shallower regions resulting in a strongly chemically stratified crust, with a refractory, dehydrated lower portion overlain by a complementary enriched upper portion. Since the lower to mid portions of continental crust are rarely exposed, investigation of the cratonization process must be through indirect methods. In this study we use in situ Hf and O isotope compositions of both magmatic and inherited zircons from several felsic magmatic suites in the Capricorn Orogen of Western Australia to highlight the differentiation history (i.e. cratonization) of this portion of late Archean to Proterozoic orogenic crust. The Capricorn Orogen shows a distinct tectonomagmatic history that evolves from an active continental margin through to intracratonic reworking, ultimately leading to thermally stable crust that responds similarly to the bounding Archean Pilbara and Yilgarn Cratons. The majority of magmatic zircons from the main magmatic cycles have Hf isotopic compositions that are generally more evolved than CHUR, forming vertical arrays that extend to moderately radiogenic compositions. Complimentary O isotope data, also show a significant variation in composition. However, combined, these data define not only the source components from which the magmas were derived, but also a range of physio-chemical processes that operated during magma transport and emplacement. These data also identify a previously unknown crustal reservoir in the Capricorn Orogen.

  9. Beating the Heat: Magmatism in the Low-Temperature Thermochronologic Record (United States)

    Murray, K. E.; Reiners, P. W.; Braun, J.; Karlstrom, L.; Morriss, M. C.


    The low-temperature thermochronology community was quick to recognize upper-crustal complexities in the geotherm that reflect landscape evolution, but the complex effects of crustal magmatism on thermochronometers can be difficult to independently document and remain underexplored. Because magmatism is common in many regions central to our understanding of tectonics, this is a significant gap in our ability to robustly interpret rock cooling. Here, we use several different numerical approaches to examine how local and regional crustal magmatism affects cooling age patterns and present examples from the western US that demonstrate the importance—and utility—of considering these effects. We modified the finite-element code Pecube to calculate how thermochronometers document the emplacement of simple hot bodies at different crustal levels. Results demonstrate the potential for mid-crustal plutons, emplaced at 10-15 km depth, to reset cooling ages in the overlying rocks at partial-retention depths at the time of magmatism. Permo-Triassic sandstones from the Colorado Plateau's Canyonlands region have apatite cooling ages that exemplify the resulting ambiguity: Oligocene rock cooling can be attributed to either 1 km of erosion or relaxation of a geothermal gradient transiently doubled by mid-crustal magmatism. Despite these complexities, there are compelling reasons to target rocks with magmatic histories. Shallowly emplaced plutons can usefully reset cooling ages in country rocks with protracted near-surface histories, as we have demonstrated in the Colorado Plateau's Henry Mountains. Cooling age patterns are also useful for quantifying magmatic processes themselves. In an ongoing project, we use the pattern of thermochronometer resetting around individual dikes that fed the Columbia River flood basalts, which are exposed in the Wallowa Mountains, to identify long-lived feeder dikes and model their thermal aureoles to further constrain eruptive dynamics. The pattern

  10. Silver in geological fluids from in situ X-ray absorption spectroscopy and first-principles molecular dynamics (United States)

    Pokrovski, Gleb S.; Roux, Jacques; Ferlat, Guillaume; Jonchiere, Romain; Seitsonen, Ari P.; Vuilleumier, Rodolphe; Hazemann, Jean-Louis


    The molecular structure and stability of species formed by silver in aqueous saline solutions typical of hydrothermal settings were quantified using in situ X-ray absorption spectroscopy (XAS) measurements, quantum-chemical modeling of near-edge absorption spectra (XANES) and extended fine structure spectra (EXAFS), and first-principles molecular dynamics (FPMD). Results show that in nitrate-bearing acidic solutions to at least 200 °C, silver speciation is dominated by the hydrated Ag+ cation surrounded by 4-6 water molecules in its nearest coordination shell with mean Ag-O distances of 2.32 ± 0.02 Å. In NaCl-bearing acidic aqueous solutions of total Cl concentration from 0.7 to 5.9 mol/kg H2O (m) at temperatures from 200 to 450 °C and pressures to 750 bar, the dominant species are the di-chloride complex AgCl2- with Ag-Cl distances of 2.40 ± 0.02 Å and Cl-Ag-Cl angle of 160 ± 10°, and the tri-chloride complex AgCl32- of a triangular structure and mean Ag-Cl distances of 2.60 ± 0.05 Å. With increasing temperature, the contribution of the tri-chloride species decreases from ˜50% of total dissolved Ag in the most concentrated solution (5.9m Cl) at 200 °C to less than 10-20% at supercritical temperatures for all investigated solutions, so that AgCl2- becomes by far the dominant Ag-bearing species at conditions typical of hydrothermal-magmatic fluids. Both di- and tri-chloride species exhibit outer-sphere interactions with the solvent as shown by the detection, using FPMD modeling, of H2O, Cl-, and Na+ at distances of 3-4 Å from the silver atom. The species fractions derived from XAS and FPMD analyses, and total AgCl(s) solubilities, measured in situ in this work from the absorption edge height of XAS spectra, are in accord with thermodynamic predictions using the stability constants of AgCl2- and AgCl32- from Akinfiev and Zotov (2001) and Zotov et al. (1995), respectively, which are based on extensive previous AgCl(s) solubility measurements. These data

  11. Mars Aqueous Processing System (United States)

    Berggren, Mark; Wilson, Cherie; Carrera, Stacy; Rose, Heather; Muscatello, Anthony; Kilgore, James; Zubrin, Robert


    The goal of the Mars Aqueous Processing System (MAPS) is to establish a flexible process that generates multiple products that are useful for human habitation. Selectively extracting useful components into an aqueous solution, and then sequentially recovering individual constituents, can obtain a suite of refined or semi-refined products. Similarities in the bulk composition (although not necessarily of the mineralogy) of Martian and Lunar soils potentially make MAPS widely applicable. Similar process steps can be conducted on both Mars and Lunar soils while tailoring the reaction extents and recoveries to the specifics of each location. The MAPS closed-loop process selectively extracts, and then recovers, constituents from soils using acids and bases. The emphasis on Mars involves the production of useful materials such as iron, silica, alumina, magnesia, and concrete with recovery of oxygen as a byproduct. On the Moon, similar chemistry is applied with emphasis on oxygen production. This innovation has been demonstrated to produce high-grade materials, such as metallic iron, aluminum oxide, magnesium oxide, and calcium oxide, from lunar and Martian soil simulants. Most of the target products exhibited purities of 80 to 90 percent or more, allowing direct use for many potential applications. Up to one-fourth of the feed soil mass was converted to metal, metal oxide, and oxygen products. The soil residue contained elevated silica content, allowing for potential additional refining and extraction for recovery of materials needed for photovoltaic, semiconductor, and glass applications. A high-grade iron oxide concentrate derived from lunar soil simulant was used to produce a metallic iron component using a novel, combined hydrogen reduction/metal sintering technique. The part was subsequently machined and found to be structurally sound. The behavior of the lunar-simulant-derived iron product was very similar to that produced using the same methods on a Michigan iron

  12. Mantle dynamics and Cretaceous magmatism in east-central China: Insight from teleseismic tomograms (United States)

    Jiang, Guoming; Zhang, Guibin; Zhao, Dapeng; Lü, Qingtian; Li, Hongyi; Li, Xinfu


    Both the rich mineralization in the Lower Yangtze Block (LYB) and the post-collisional mafic rocks in the Dabie Orogen (DBO) are closely related to the Cretaceous magmatism in east-central China. Various geodynamic models have been proposed for explaining the mechanism of the Cretaceous magmatism, but these models are controversial and even contradictory with each other, especially on the mechanism of adakites. A unified geodynamic model is required for explaining the magmatism in east-central China, in particular, the spatial and temporal correlations of magmatic activity in the DBO and that in the LYB. For this purpose, we apply teleseismic tomography to study P-wave velocity structure down to 800 km depth beneath east-central China. A modified multiple-channel cross-correlation method is used to collect 28,805 high-quality P-wave arrival-time data from seismograms of distant earthquakes recorded by permanent seismic stations and our temporary stations in the study region. To remove the influence of crustal heterogeneity on the mantle tomography, we used the CRUST1.0 model to correct the teleseismic relative residuals. Our tomography revealed distinct high-velocity (high-V) anomalies beneath the DBO and two flanks of the LYB, and low-velocity (low-V) anomalies above the high-V zones. Combining our tomographic images with previous geological, geochemical and geophysical results, we infer that these high-V and low-V anomalies reflect the detached lithosphere and upwelling asthenospheric materials, respectively, which are associated with the Late Mesozoic dynamic process and the Cretaceous magmatism. We propose a double-slab subduction model that a ridge subduction yielded the adakitic rocks in the LYB during 150-135 Ma and the subsequent Pacific Plate subduction played a crucial role in not only the formation of igneous rocks in the LYB but also remelting of the subducted South China Block beneath the DBO during 135-101 Ma.

  13. Mueilha rare metals granite, Eastern Desert of Egypt: An example of a magmatic-hydrothermal system in the Arabian-Nubian Shield (United States)

    Abu El-Rus, Mohamed A.; Mohamed, Mohamed A.; Lindh, Anders


    The Mueilha granite pluton is one of the rare-metals bearing peraluminous granitic plutons in the Arabian-Nubian Shield. It represents the apical part of a highly evolved magma chamber emplaced at a shallow level subsequent to the post Pan-African orogeny. The pluton can be seen as a highly leucocratic medium-grained albite/oligoclase framework infilled with quartz, K-feldspar and muscovite that are variably overgrown by K-feldspar, muscovite, quartz and topaz megacrysts. The increasing number and size of the K-feldspar megacrysts at the expense of the whitened albite/oligoclase framework imparts variably red color to the Mueilha granite. Contacts between the milky white and red granites are usually gradational, but may be locally sharp or may form narrow transition zones resulting from abrupt variations in texture and lithology. Textural relations indicate an initial stage of hydrothermal albitization of magmatic plagioclase and crystallization of topaz megacrysts resulting from infiltration of Na-rich fluorine bearing fluids. A subsequent stage of metasomatic enrichment is characterized by extensive growth of large K-feldspar, quartz and muscovite megacrysts at the expense of the albite/oligoclase crystals as a result of infiltration of K-Si rich hydrous fluids. Post-magmatic infiltration of hydrous fluids along the fault planes is shown by the intense replacement of alkali feldspar megacrysts by quartz, development of myrmekitic intergrowth pockets along the K-feldspar megacrysts and sealing of the micro-fractures by cryptocrystalline mixtures of clay minerals, iron oxides, sericite and chlorite. Compositionally, the red granitic rocks have higher SiO2, Fe2O3total, K2O/Na2O, Σ REE, Y, Th, U, Zr and Zn and lower Al2O3, Ga, Ta, Nb and Mo compared to the milky white granites. LILE and Sn do not show clear variation trends throughout the Mueilha granite pluton, suggesting their immobility during hydrothermal alteration. Microthermometric measurements indicate that

  14. The mobility of U and Th in subduction zone fluids: an indicator of oxygen fugacity and fluid salinity (United States)

    Bali, Enikő; Audétat, Andreas; Keppler, Hans


    The solubility of U and Th in aqueous solutions at P-T-conditions relevant for subduction zones was studied by trapping uraninite or thorite saturated fluids as synthetic fluid inclusions in quartz and analyzing their composition by Laser Ablation-ICPMS. Uranium is virtually insoluble in aqueous fluids at Fe-FeO buffer conditions, whereas its solubility increases both with oxygen fugacity and with salinity to 960 ppm at 26.1 kbar, Re-ReO2 buffer conditions and 14.1 wt% NaCl in the fluid. At 26.1 kbar and 800°C, uranium solubility can be reproduced by the equation: log {{U}} = 2.681 + 0.1433log f{{O}}2 + 0.594{{Cl,}} where fO2 is the oxygen fugacity, and Cl is the chlorine content of the fluid in molality. In contrast, Th solubility is generally low (uranium increases strongly both with oxygen fugacity and with salinity. We show that reducing or NaCl-free fluids cannot produce primitive arc magmas with U/Th ratio higher than MORB. However, the dissolution of several wt% of oxidized, saline fluids in arc melts can produce U/Th ratios several times higher than in MORB. We suggest that observed U/Th ratios in arc magmas provide tight constraints on both the salinity and the oxidation state of subduction zone fluids.

  15. Aqueous chemistry of transactinides

    International Nuclear Information System (INIS)

    Schaedel, M.


    The aqueous chemistry of the first three transactinide elements is briefly reviewed with special emphasis given to recent experimental results. Short introductory remarks are discussing the atom-at-a-time situation of transactinide chemistry as a result of low production cross-sections and short half-lives. In general, on-line experimental techniques and, more specifically, the automated rapid chemistry apparatus, ARCA, are presented. Present and future developments of experimental techniques and resulting perspectives are outlined at the end. The central part is mainly focussing on hydrolysis and complex formation aspects of the superheavy group 4, 5, and 6 transition metals with F - and Cl - anions. Experimental results are compared with the behaviour of lighter homologous elements and with relativistic calculations. It will be shown that the chemical behaviour of the first superheavy elements is already strongly influenced by relativistic effects. While it is justified to place rutherfordium, dubnium and seaborgium in the Periodic Table of the Elements into group 4, 5 and 6, respectively, it is no more possible to deduce from this position in detail the chemical properties of these transactinide or superheavy elements. (orig.)

  16. Depressurization and boiling of a single magmatic fluid as a mechanism for tin-tungsten deposit formation


    Maximilian Korges; Philipp Weis; Volker Lüders; Oscar Laurent


    Tin (Sn) and tungsten (W) mineralization are commonly associated with each other in relation to highly evolved granites, but economical ore grades are restricted to rare global occurrences and mineralization styles are highly variable, indicating different mechanisms for ore formation. The Sn-W Zinnwald deposit in the Erzgebirge (Germany and the Czech Republic) in the roof zone of a Variscan Li-F granite hosts two contrasting styles of mineralization: (1) cassiterite (Sn) in greisen bodies, a...

  17. Fluid mechanics in fluids at rest. (United States)

    Brenner, Howard


    Using readily available experimental thermophoretic particle-velocity data it is shown, contrary to current teachings, that for the case of compressible flows independent dye- and particle-tracer velocity measurements of the local fluid velocity at a point in a flowing fluid do not generally result in the same fluid velocity measure. Rather, tracer-velocity equality holds only for incompressible flows. For compressible fluids, each type of tracer is shown to monitor a fundamentally different fluid velocity, with (i) a dye (or any other such molecular-tagging scheme) measuring the fluid's mass velocity v appearing in the continuity equation and (ii) a small, physicochemically and thermally inert, macroscopic (i.e., non-Brownian), solid particle measuring the fluid's volume velocity v(v). The term "compressibility" as used here includes not only pressure effects on density, but also temperature effects thereon. (For example, owing to a liquid's generally nonzero isobaric coefficient of thermal expansion, nonisothermal liquid flows are to be regarded as compressible despite the general perception of liquids as being incompressible.) Recognition of the fact that two independent fluid velocities, mass- and volume-based, are formally required to model continuum fluid behavior impacts on the foundations of contemporary (monovelocity) fluid mechanics. Included therein are the Navier-Stokes-Fourier equations, which are now seen to apply only to incompressible fluids (a fact well-known, empirically, to experimental gas kineticists). The findings of a difference in tracer velocities heralds the introduction into fluid mechanics of a general bipartite theory of fluid mechanics, bivelocity hydrodynamics [Brenner, Int. J. Eng. Sci. 54, 67 (2012)], differing from conventional hydrodynamics in situations entailing compressible flows and reducing to conventional hydrodynamics when the flow is incompressible, while being applicable to both liquids and gases.

  18. Reduced abrasion drilling fluid

    NARCIS (Netherlands)


    A reduced abrasion drilling fluid system and method of drilling a borehole by circulating the reduced abrasion drilling fluid through the borehole is disclosed. The reduced abrasion drilling fluid comprises a drilling fluid, a first additive and a weighting agent, wherein the weighting agent has a

  19. Reduced abrasion drilling fluid

    NARCIS (Netherlands)


    A reduced abrasion drilling fluid system and method of drilling a borehole by circulating the reduced abrasion drilling fluid through the borehole is disclosed. The reduced abrasion drilling fluid comprises a drilling fluid, a first additive and a weighting agent, wherein the weighting agent has a

  20. Process fluid cooling system

    International Nuclear Information System (INIS)

    Farquhar, N.G.; Schwab, J.A.


    A system of heat exchangers is disclosed for cooling process fluids. The system is particularly applicable to cooling steam generator blowdown fluid in a nuclear plant prior to chemical purification of the fluid in which it minimizes the potential of boiling of the plant cooling water which cools the blowdown fluid

  1. Preliminary results on the petrology and fluid inclusions of the Rossing uraniferous alaskites

    International Nuclear Information System (INIS)

    Cuney, M.


    Petrography, radioactivity distribution and fluid inclusions have been studied in three samples of the Rossing alaskites from the S.H. anomaly outside of the Rossing deposit. After the crystallization of the alaskitic magma which involved oligoclase, biotite, orthoclase and quartz, a deuteric alteration produced a quartz, microcline, albite, muscovite, calcite plus minus chlorite mineral association similar to those observed in several French uraniferous granites. Uranium redistribution occurred during this alteration. From fluid inclusions data, the pressure at the time of the intrusion is estimated to have been at least 6kbar for a temperature of 625 degrees Celsius. Reaction of the magma with the marbles of the Rossing formation led to the boiling of the magma by an increase in the CO 2 partial pressure as well as to its crystallization. Immiscibility between a dense saline (more than 30 per cent NaCl) and CO 2 -rich fluid is proposed to have occurred simultaneously or after the fluid oversaturation of the magma. Part of uraninite is formed at the magmatic stage, another part crystallized from the magmatic fluids in the biotite-rich selvages of the alaskites or in the uraninite-fluorite veins. Uraninite crystallization appears to be mainly controlled by the oxygen fugacity prevailing in the magma and in the surrounding rocks

  2. Progress in aqueous rechargeable batteries

    Directory of Open Access Journals (Sweden)

    Jilei Liu


    Full Text Available Over the past decades, a series of aqueous rechargeable batteries (ARBs were explored, investigated and demonstrated. Among them, aqueous rechargeable alkali-metal ion (Li+, Na+, K+ batteries, aqueous rechargeable-metal ion (Zn2+, Mg2+, Ca2+, Al3+ batteries and aqueous rechargeable hybrid batteries are standing out due to peculiar properties. In this review, we focus on the fundamental basics of these batteries, and discuss the scientific and/or technological achievements and challenges. By critically reviewing state-of-the-art technologies and the most promising results so far, we aim to analyze the benefits of ARBs and the critical issues to be addressed, and to promote better development of ARBs.

  3. aqueous root extract on spermatogenesis

    African Journals Online (AJOL)

    Four groups were gavaged with the whole plant or root aqueous extract in low or high doses. The male ... motility and morphology as well as chromatin integrity were evaluated. Results: Serum ... Treatment of disease began long ago with the.

  4. Linking fault permeability, fluid flow, and earthquake triggering in a hydrothermally active tectonic setting: Numerical Simulations of the hydrodynamics in the Tjörnes Fracture Zone, Iceland. (United States)

    Lupi, M.; Geiger, S.; Graham, C.; Claesson, L.; Richter, B.


    A good insight into the transient fluid flow evolution within a hydrothermal system is of primary importance for the understanding of several geologic processes, for example the hydrodynamic triggering of earthquakes or the formation of mineral deposits. The strong permeability contrast between different crustal layers as well as the high geothermal gradient of these areas are elements that strongly affect the flow behaviour. In addition, the sudden and transient occurrence of joints, faults and magmatic intrusions are likely to change the hydrothermal flow paths in very short time. The Tjörnes Fracture Zone (TFZ) north of Iceland, is such a hydrothermal area where a high geothermal gradient, magmatic bodies, faults, and the strong contrast between sediments and fractured lava layers govern the large-scale fluid flow. The TFZ offsets the Kolbeinsey Ridge and the Northern Rift Zone. It is characterized by km-scale faults that link sub-seafloor sediments and lava layers with deeper crystalline rocks. These structures focus fluid flow and allow for the mixing between cold seawater and deep hydrothermal fluids. A strong seismic activity is present in the TFZ: earthquakes up to magnitude 7 have been recorded over the past years. Hydrogeochemical changes before, during and after a magnitude 5.8 earthquake suggest that the evolving stress state before the earthquake leads to (remote) permeability variations, which alter the fluid flow paths. This is in agreement with recent numerical fluid flow simulations which demonstrate that fluid flow in magmatic- hydrothermal systems is often convective and very sensitive to small variations in permeability. In order to understand the transient fluid flow behaviour in this complex geological environment, we have conducted numerical simulations of heat and mass transport in two geologically realistic cross-sectional models of the TFZ. The geologic models are discretised using finite element and finite volume methods. They hence have

  5. Evolution of the Campanian Ignimbrite Magmatic System II: Trace Element and Th Isotopic Evidence for Open-System Processes (United States)

    Bohrson, W. A.; Spera, F. J.; Fowler, S.; Belkin, H.; de Vivo, B.


    The Campanian Ignimbrite, a large volume (~200 km3 DRE) trachytic to phonolitic ignimbrite was deposited at ~39.3 ka and represents the largest of a number of highly explosive volcanic events in the region near Naples, Italy. Thermodynamic modeling of the major element evolution using the MELTS algorithm (see companion contribution by Fowler et al.) provides detailed information about the identity of and changes in proportions of solids along the liquid line of descent during isobaric fractional crystallization. We have derived trace element mass balance equations that explicitly accommodate changing mineral-melt bulk distribution coefficients during crystallization and also simultaneously satisfy energy and major element mass conservation. Although major element patterns are reasonably modeled assuming closed system fractional crystallization, modeling of trace elements that represent a range of behaviors (e.g. Zr, Nb, Th, U, Rb, Sm, Sr) yields trends for closed system fractionation that are distinct from those observed. These results suggest open-system processes were also important in the evolution of the Campanian magmatic system. Th isotope data yield an apparent isochron that is ~20 kyr younger than the age of the deposit, and age-corrected Th isotope data indicate that the magma body was an open-system at the time of eruption. Because open-system processes can profoundly change isotopic characteristics of a magma body, these results illustrate that it is critical to understand the contribution that open-system processes make to silicic magma bodies prior to assigning relevance to age or timescale information derived from isotope systematics. Fluid-magma interaction has been proposed as a mechanism to change isotopic and elemental characteristics of magma bodies, but an evaluation of the mass and thermal constraints on such a process suggest large-scale fluid-melt interaction at liquidus temperatures is unlikely. In the case of the magma body associated with

  6. Stable-isotope geochemistry of the Pierina high-sulfidation Au-Ag deposit, Peru: Influence of hydrodynamics on SO42--H2S sulfur isotopic exchange in magmatic-steam and steam-heated environments (United States)

    Fifarek, R.H.; Rye, R.O.


    The Pierina high-sulfidation Au-Ag deposit formed 14.5 my ago in rhyolite ash flow tuffs that overlie porphyritic andesite and dacite lavas and are adjacent to a crosscutting and interfingering dacite flow dome complex. The distribution of alteration zones indicates that fluid flow in the lavas was largely confined to structures but was dispersed laterally in the tuffs because of a high primary and alteration-induced permeability. The lithologically controlled hydrodynamics created unusual fluid, temperature, and pH conditions that led to complete SO42--H2S isotopic equilibration during the formation of some magmatic-steam and steam-heated alunite, a phenomenon not previously recognized in similar deposits. Isotopic data for early magmatic hydrothermal and main-stage alunite (??34S=8.5??? to 31.7???; ??18 OSO4=4.9??? to 16.5???; ??18 OOH=2.2??? to 14.4???; ??D=-97??? to -39???), sulfides (??34 S=-3.0??? to 4.3???), sulfur (??34S=-1.0??? to 1.1???), and clay minerals (??18O=4.3??? to 12.5???; ??D=-126??? to -81???) are typical of high-sulfidation epithermal deposits. The data imply the following genetic elements for Pierina alteration-mineralization: (1) fluid and vapor exsolution from an I-type magma, (2) wallrock buffering and cooling of slowing rising vapors to generate a reduced (H2S/SO4???6) highly acidic condensate that mixed with meteoric water but retained a magmatic ??34S???S signature of ???1???, (3) SO2 disproportionation to HSO4- and H2S between 320 and 180 ??C, and (4) progressive neutralization of laterally migrating acid fluids to form a vuggy quartz???alunite-quartz??clay???intermediate argillic???propylitic alteration zoning. Magmatic-steam alunite has higher ??34S (8.5??? to 23.2???) and generally lower ??18OSO4 (1.0 to 11.5???), ??18OOH (-3.4 to 5.9???), and ??D (-93 to -77???) values than predicted on the basis of data from similar occurrences. These data and supporting fluid-inclusion gas chemistry imply that the rate of vapor ascent for this

  7. The evolution of Yellowstone's magmatic system over the past 630 kyr: Insights from the crystal record (United States)

    Stelten, M. E.


    The Yellowstone Plateau volcanic field in northwestern Wyoming is one of the world's largest, active silicic volcanic centers, and has produced three caldera-forming "super eruptions" over the past 2.1 Myr. As a result, the petrologic evolution of Yellowstone's magmatic system has been the focus of numerous studies over the past 60 years. Early studies at Yellowstone focused on characterizing whole-rock chemical and isotopic variations observed in magmas erupted over Yellowstone's lifetime. While these have provided important insights into the source of Yellowstone magmas and the processes controlling their compositional evolution though time, whole-rock studies are limited in their ability to identify the mechanisms and timescales of rhyolite generation. In contrast, much of the recent work at Yellowstone has focused on applying micro-analytical techniques to characterize the age and composition of phenocrysts hosted in Yellowstone rhyolites. These studies have greatly advanced our understanding of the magmatic system at Yellowstone and have provided crucial new insights into the mechanisms and timescales of rhyolite generation. In particular, recent work has focused on applying micro-analytical techniques to study the age and origin of the [1] three caldera-forming eruptions that produced the Huckleberry Ridge, Mesa Falls, Lava Creek tuffs and [2] post-Lava Creek tuff intracaldera rhyolites that compose the Plateau Rhyolite. As a result, a wealth of crystal-chemical data now exists for rhyolites erupted throughout Yellowstone's 2.1 Myr history. These data provide a unique opportunity to create a detailed reconstruction of Yellowstone's magmatic system through time. In this contribution, I integrate available age, chemical, and isotopic data for phenocrysts hosted in Yellowstone rhyolites to construct a model for the evolution of Yellowstone's magmatic system from the caldera-forming eruption of the Lava Creek tuff at ca. 0.63 Ma to the present day. In particular

  8. Continental extension, magmatism and elevation; formal relations and rules of thumb (United States)

    Lachenbruch, A.H.; Morgan, P.


    To investigate simplified relations between elevation and the extensional, magmatic and thermal processes that influence lithosphere buoyancy, we assume that the lithosphere floats on an asthenosphere of uniform density and has no flexural strength. A simple graph relating elevation to lithosphere density and thickness provides an overview of expectable conditions around the earth and a simple test for consistancy of continental and oceanic lithosphere models. The mass-balance relations yield simple general rules for estimating elevation changes caused by various tectonic, magmatic and thermal processes without referring to detailed models. The rules are general because they depend principally on buoyancy, which under our assumptions is specified by elevation, a known quantity; they do not generally require a knowledge of lithosphere thickness and density. The elevation of an extended terrain contains important information on its tectonic and magmatic history. In the Great Basin where Cenozoic extension is estimated to be 100%, the present high mean elevation ( ~ 1.75 km) probably requires substantial low-density magmatic contributions to the extending lithosphere. The elevation cannot be reasonably explained solely as the buoyant residue of a very high initial terrane, or of a lithosphere that was initially very thick and subsequently delaminated and heated. Even models with a high initial elevation typically call for 10 km or so of accumulated magmatic material of near-crustal density. To understand the evolution of the Great Basin, it is important to determine whether such intruded material is present; some could replenish the stretching crust by underplating and crustal intrusion and some might reside in the upper mantle. The elevation maintained or approached by an intruded extending lithosphere depends on the ratio B of how fast magma is supplied from the asthenosphere ( b km/Ma) to how fast the lithosphere spreads the magma out by extension (?? Ma-1). For a

  9. Mg isotope systematics during magmatic processes: Inter-mineral fractionation in mafic to ultramafic Hawaiian xenoliths (United States)

    Stracke, A.; Tipper, E. T.; Klemme, S.; Bizimis, M.


    Observed differences in Mg isotope ratios between bulk magmatic rocks are small, often on a sub per mill level. Inter-mineral differences in the 26Mg/24Mg ratio (expressed as δ26Mg) in plutonic rocks are on a similar scale, and have mostly been attributed to equilibrium isotope fractionation at magmatic temperatures. Here we report Mg isotope data on minerals in spinel peridotite and garnet pyroxenite xenoliths from the rejuvenated stage of volcanism on Oahu and Kauai, Hawaii. The new data are compared to literature data and to theoretical predictions to investigate the processes responsible for inter-mineral Mg isotope fractionation at magmatic temperatures. Theory predicts up to per mill level differences in δ26Mg between olivine and spinel at magmatic temperatures and a general decrease in Δ26Mgolivine-spinel (=δ26Mgolivine - δ26Mgspinel) with increasing temperature, but also with increasing Cr# in spinel. For peridotites with a simple petrogenetic history by melt depletion, where increasing depletion relates to increasing melting temperatures, Δ26Mgolivine-spinel should thus systematically decrease with increasing Cr# in spinel. However, most natural peridotites, including the Hawaiian spinel peridotites investigated in this study, are overprinted by variable extents of melt-rock reaction, which disturb the systematic primary temperature and compositionally related olivine-spinel Mg isotope systematics. Diffusion, subsolidus re-equilibration, or surface alteration may further affect the observed olivine-spinel Mg isotope fractionation in peridotites, making Δ26Mgolivine-spinel in peridotites a difficult-to-apply geothermometer. The available Mg isotope data on clinopyroxene and garnet suggest that this mineral pair is a more promising geothermometer, but its application is restricted to garnet-bearing igneous (garnet pyroxenites) and metamorphic rocks (eclogites). Although the observed δ26Mg variation is on a sub per mill range in bulk magmatic rocks

  10. Hydrothermal Fluid evolution in the Dalli porphyry Cu-Au Deposit: Fluid Inclusion microthermometry studies

    Directory of Open Access Journals (Sweden)

    Alireza Zarasvandi


    Full Text Available Introduction A wide variety of world-class porphyry Cu deposits occur in the Urumieh-Dohktar magmatic arc (UDMA of Iran.The arc is composed of calc-alkaline granitoid rocks, and the ore-hosting porphyry intrusions are dominantly granodiorite to quartz-monzonite (Zarasvandi et al., 2015. It is believed that faults played an important role in the emplacement of intrusions and subsequentporphyry-copper type mineralization (Shahabpour, 1999. Three main centers host the porphyry copper mineralization in the UDMA: (1 Ardestan-SarCheshmeh-Kharestan zone, (2 Saveh-Ardestan district; in the central parts of the UDMA, hosting the Dalli porphyry Cu-Au deposit, and (3 Takab-Mianeh-Qharahdagh-Sabalan zone. Mineralized porphyry coppersystems in the UDMA are restricted to Oligocene to Mioceneintrusions and show potassic, sericitic, argillic, propylitic and locally skarn alteration (Zarasvandi et al., 2005; Zarasvandi et al., 2015. In the Dalli porphyry deposit, four hydrothermal alteration zones, includingpotassic, sericitic, propylitic, and argillic types have been described in the two discrete mineralized areas, namely, northern and southern stocks. Hypogenemineralization includes chalcopyrite, pyrite, and magnetite, with minor occurrences of bornite.Supergene activity has produced gossan, oxidized minerals and enrichment zones. The supergene enrichment zone contains chalcocite and covellite with a 10-20 m thickness. Mineralization in the northern stock is mainly composed of pyrite and chalcopyrite. The aim of this study is the investigation and classification of hydrothermal veins and the constraining of physicochemical compositions of ore-forming fluids using systematic investigation of fluid inclusions. Materials and methods Twenty samples were collected from drill holes. Thin and polished sections were prepared from hydrothermal veins of thepotassic, sericitic and propylitic alteration zones. Samples used for fluid inclusion measurements were collected

  11. Multiple magmatism in an evolving suprasubduction zone mantle wedge: The case of the composite mafic-ultramafic complex of Gaositai, North China Craton (United States)

    Yang, Fan; Santosh, M.; Tsunogae, T.; Tang, Li; Teng, Xueming


    The suprasubduction zone mantle wedge of active convergent margins is impregnated by melts and fluids leading to the formation of a variety of magmatic and metasomatic rock suites. Here we investigate a composite mafic-ultramafic intrusion at Gaositai, in the northern margin of the North China Craton (NCC). The hornblende gabbro-serpentinite-dunite-pyroxenite-gabbro-diorite suite surrounded by hornblendites of this complex has long been considered to represent an "Alaskan-type" zoned pluton. We present petrologic, mineral chemical, geochemical and zircon U-Pb and Lu-Hf data from the various rock types from Gaositai including hornblende gabbro, serpentinite, dunite, pyroxenite, diorite and the basement hornblendite which reveal the case of multiple melt generation and melt-peridotite interaction. Our new mineral chemical data from the mafic-ultramafic suite exclude an "Alaskan-type" affinity, and the bulk geochemical features are consistent with subduction-related magmatism with enrichment of LILE (K, Rb, and Ba) and LREE (La and Ce), and depletion of HFSE (Nb, Ta, Zr, and Hf) and HREE. Zircon U-Pb geochronology reveals that the hornblendites surrounding the Gaositai complex are nearly 2 billion years older than the intrusive complex and yield early Paleoproterozoic emplacement ages (2433-2460 Ma), followed by late Paleoproterozoic metamorphism (1897 Ma). The serpentinites trace the history of a long-lived and replenished ancient sub-continental lithospheric mantle with the oldest zircon population dated as 2479 Ma and 1896 Ma, closely corresponding with the ages obtained from the basement rock, followed by Neoproterozoic and Phanerozoic zircon growth. The oldest member in the Gaositai composite intrusion is the dunite that yields emplacement age of 755 Ma, followed by pyroxenite formed through the interaction of slab melt and wedge mantle peridotite at 401 Ma. All the rock suites also carry multiple population of younger zircons ranging in age from Paleozoic to

  12. Percolation of diagenetic fluids in the Archaean basement of the Franceville basin (United States)

    Mouélé, Idalina Moubiya; Dudoignon, Patrick; Albani, Abderrazak El; Cuney, Michel; Boiron, Marie-Christine; Gauthier-Lafaye, François


    The Palaeoproterozoic Franceville basin, Gabon, is mainly known for its high-grade uranium deposits, which are the only ones known to act as natural nuclear fission reactors. Previous work in the Kiéné region investigated the nature of the fluids responsible for these natural nuclear reactors. The present work focuses on the top of the Archaean granitic basement, specifically, to identify and date the successive alteration events that affected this basement just below the unconformity separating it from the Palaeoproterozoic basin. Core from four drill holes crosscutting the basin-basement unconformity have been studied. Dating is based on U-Pb isotopic analyses performed on monazite. The origin of fluids is discussed from the study of fluid inclusion planes (FIP) in quartz from basement granitoids. From the deepest part of the drill holes to the unconformable boundary with the basin, propylitic alteration assemblages are progressively replaced by illite and locally by a phengite + Fe chlorite ± Fe oxide assemblage. Illitic alteration is particularly strong along the sediment-granitoid contact and is associated with quartz dissolution. It was followed by calcite and anhydrite precipitation as fracture fillings. U-Pb isotopic dating outlines three successive events: a 3.0-2.9-Ga primary magmatic event, a 2.6-Ga propylitic alteration and a late 1.9-Ga diagenetic event. Fluid inclusion microthermometry suggests the circulation of three types of fluids: (1) a Na-Ca-rich diagenetic brine, (2) a moderately saline (diagenetic + meteoric) fluid, and (3) a low-salinity fluid of probable meteoric origin. These fluids are similar to those previously identified within the overlying sedimentary rocks of the Franceville basin. Overall, the data collected in this study show that the Proterozoic-Archaean unconformity has operated as a major flow corridor for fluids circulation, around 1.9 Ga. highly saline diagenetic brines; hydrocarbon-rich fluids derived from organic matter

  13. Natural gas hydrate formation and inhibition in gas/crude oil/aqueous systems

    DEFF Research Database (Denmark)

    Daraboina, Nagu; Pachitsas, Stylianos; von Solms, Nicolas


    Gas hydrate formation in multi phase mixtures containing an aqueous phase (with dissolved salts), reservoir fluid (crude oil) and natural gas phase was investigated by using a standard rocking cell (RC-5) apparatus. The hydrate formation temperature was reduced in the presence of crude oils...... can contribute to the safe operation of sub sea pipelines in the oil and gas industry....

  14. Radon and its decay product activities in the magmatic area and the adjacent volcano-sedimentary Intrasudetic Basin

    Directory of Open Access Journals (Sweden)

    D. Tchorz


    Full Text Available In the magmatic area of Sudetes covering the Karkonosze granite and adjacent volcano-sedimentary Intrasudetic Basin a study of atmospheric radon activity was performed by means of SSNTD Kodak LR-115. The study was completed by gamma spectrometric survey of eU and eTh determined by gamma activity of radon decay products 214Bi and 208Tl respectively. In the case of the western part of the Karkonosze granite area the radon decay products activity in the granitic basement was found to be as high as 343 Bq/kg for 214Bi and 496 Bq/kg for 208Tl respectively. Atmospheric radon content measured by means of Kodak LR115 track detector at the height of 1.5 m was found as high as 70 Bq/m3 in the regions, where no mining activities took place. However in the eastern part of the granitic massif in the proximity of abandoned uranium mine atmospheric radon content was found to be 6000 Bq/m3. In the case of sedimentary basin where sedimentary sequence of Carboniferous rocks has been penetrated by younger gases and fluids of volcanic origin uranium mineralization developed. The region known from its CO2 outburst during coal mining activity is characterized by good ventilation of the uranium enriched geological basement resulting in increased atmospheric radon activity being in average 72 Bq/m3. In the vicinity of coal mine tailing an increase up to 125 Bq/m3 can be observed. Seasonal variations of atmospheric radon content are influenced in agricultural areas by cyclic cultivation works (plough on soils of increased uranium content and in the case of post-industrial brownfields varying rates of radon exhalation from tailings due to different meteorological conditions.

  15. Formation of albitite-hosted uranium within IOCG systems: the Southern Breccia, Great Bear magmatic zone, Northwest Territories, Canada (United States)

    Montreuil, Jean-François; Corriveau, Louise; Potter, Eric G.


    Uranium and polymetallic U mineralization hosted within brecciated albitites occurs one kilometer south of the magnetite-rich Au-Co-Bi-Cu NICO deposit in the southern Great Bear magmatic zone (GBMZ), Canada. Concentrations up to 1 wt% U are distributed throughout a 3 by 0.5 km albitization corridor defined as the Southern Breccia zone. Two distinct U mineralization events are observed. Primary uraninite precipitated with or without pyrite-chalcopyrite ± molybdenite within magnetite-ilmenite-biotite-K-feldspar-altered breccias during high-temperature potassic-iron alteration. Subsequently, pitchblende precipitated in earthy hematite-specular hematite-chlorite veins associated with a low-temperature iron-magnesium alteration. The uraninite-bearing mineralization postdates sodic (albite) and more localized high-temperature potassic-iron (biotite-magnetite ± K-feldspar) alteration yet predates potassic (K-feldspar), boron (tourmaline) and potassic-iron-magnesium (hematite ± K-feldspar ± chlorite) alteration. The Southern Breccia zone shares attributes of the Valhalla (Australia) and Lagoa Real (Brazil) albitite-hosted U deposits but contains greater iron oxide contents and lower contents of riebeckite and carbonates. Potassium, Ni, and Th are also enriched whereas Zr and Sr are depleted with respect to the aforementioned albitite-hosted U deposits. Field relationships, geochemical signatures and available U-Pb dates on pre-, syn- and post-mineralization intrusions place the development of the Southern Breccia and the NICO deposit as part of a single iron oxide alkali-altered (IOAA) system. In addition, this case example illustrates that albitite-hosted U deposits can form in albitization zones that predate base and precious metal ore zones in a single IOAA system and become traps for U and multiple metals once the tectonic regime favors fluid mixing and oxidation-reduction reactions.

  16. DOE workshop: Sedimentary systems, aqueous and organic geochemistry

    International Nuclear Information System (INIS)


    A DOE workshop on sedimentary systems, aqueous and organic geochemistry was held July 15-16, 1993 at Lawrence Berkeley Laboratory. Papers were organized into several sections: Fundamental Properties, containing papers on the thermodynamics of brines, minerals and aqueous electrolyte solutions; Geochemical Transport, covering 3-D imaging of drill core samples, hydrothermal geochemistry, chemical interactions in hydrocarbon reservoirs, fluid flow model application, among others; Rock-Water Interactions, with presentations on stable isotope systematics of fluid/rock interaction, fluid flow and petotectonic evolution, grain boundary transport, sulfur incorporation, tracers in geologic reservoirs, geothermal controls on oil-reservoir evolution, and mineral hydrolysis kinetics; Organic Geochemistry covered new methods for constraining time of hydrocarbon migration, kinetic models of petroleum formation, mudstones in burial diagenesis, compound-specific carbon isotope analysis of petroleums, stability of natural gas, sulfur in sedimentary organic matter, organic geochemistry of deep ocean sediments, direct speciation of metal by optical spectroscopies; and lastly, Sedimentary Systems, covering sequence stratigraphy, seismic reflectors and diagenetic changes in carbonates, geochemistry and origin of regional dolomites, and evidence of large comet or asteroid impacts at extinction boundaries

  17. DOE workshop: Sedimentary systems, aqueous and organic geochemistry

    Energy Technology Data Exchange (ETDEWEB)


    A DOE workshop on sedimentary systems, aqueous and organic geochemistry was held July 15-16, 1993 at Lawrence Berkeley Laboratory. Papers were organized into several sections: Fundamental Properties, containing papers on the thermodynamics of brines, minerals and aqueous electrolyte solutions; Geochemical Transport, covering 3-D imaging of drill core samples, hydrothermal geochemistry, chemical interactions in hydrocarbon reservoirs, fluid flow model application, among others; Rock-Water Interactions, with presentations on stable isotope systematics of fluid/rock interaction, fluid flow and petotectonic evolution, grain boundary transport, sulfur incorporation, tracers in geologic reservoirs, geothermal controls on oil-reservoir evolution, and mineral hydrolysis kinetics; Organic Geochemistry covered new methods for constraining time of hydrocarbon migration, kinetic models of petroleum formation, mudstones in burial diagenesis, compound-specific carbon isotope analysis of petroleums, stability of natural gas, sulfur in sedimentary organic matter, organic geochemistry of deep ocean sediments, direct speciation of metal by optical spectroscopies; and lastly, Sedimentary Systems, covering sequence stratigraphy, seismic reflectors and diagenetic changes in carbonates, geochemistry and origin of regional dolomites, and evidence of large comet or asteroid impacts at extinction boundaries.

  18. Magmatism during Gondwana break-up : new geochronological data from Westland, New Zealand

    International Nuclear Information System (INIS)

    Van der Meer, Q.H.A.; Scott, J.M.; Waight, T.E.; Sudo, M.; Schersten, A.; Cooper, A.F.; Spell, T.L.


    Newly determined Late Cretaceous 40 Ar/ 39 Ar ages on megacrystic kaersutite from four lamprophyre dikes, and a U-Pb zircon age on a trachyte, from central and north Westland (New Zealand) are presented. These ages suggest that the intrusion of mafic dikes (88-86 and 69 Ma) was not necessarily restricted to the previously established narrow age range of 80-92 Ma. The younger lamprophyre and trachyte dikes (c. 68-70 Ma) imply that tensional stresses in the Western Province were either renewed at this time, or that extension and related magmatism continued during opening of the Tasman Sea. Extension-related magmatism in the region not only preceded Tasman seafloor spreading initiation (starting at c. 83 Ma, lasting to c. 53 Ma), but may have sporadically continued for up to 15 Ma after continental break-up. (author)

  19. Role of magmatism in continental lithosphere extension: an introduction to tectnophysics special issue

    Energy Technology Data Exchange (ETDEWEB)

    Van Wijk, Jolante W [Los Alamos National Laboratory


    The dynamics and evolution of rifts and continental rifted margins have been the subject of intense study and debate for many years and still remain the focus of active investigation. The 2006 AGU Fall Meeting session 'Extensional Processes Leading to the Formation of Basins and Rifted Margins, From Volcanic to Magma-Limited' included several contributions that illustrated recent advances in our understanding of rifting processes, from the early stages of extension to breakup and incipient seafloor spreading. Following this session, we aimed to assemble a multi-disciplinary collection of papers focussing on the architecture, formation and evolution of continental rift zones and rifted margins. This Tectonophysics Special Issue 'Role of magmatism in continental lithosphere extension' comprises 14 papers that present some of the recent insights on rift and rifted margins dynamics, emphasising the role of magmatism in extensional processes. The purpose of this contribution is to introduce these papers.

  20. Dating emplacement and evolution of the orogenic magmatism in the internal Western Alps

    DEFF Research Database (Denmark)

    Berger, Alfons; Thomsen, Tonny B.; Ovtcharova, Maria


    The Canavese Line in the Western Alps represents the position in the Alpine chain, where alkaline and calc-alkaline magmatism occur in close spatial and temporal association. In addition to available data on the alkaline Valle del Cervo Pluton, we present petrological and geochemical data...... on the Miagliano tonalite. The latter is of special interest, because it is located in the south-eastern side of the Canavese Line, in contrast to most Periadriatic Plutons. The dioritic to tonalitic rocks of the Miagliano Pluton represent an intermediate stage of a calc-alkaline differentiation, demonstrated...... by relics of two different pyroxenes as well as the texture of allanite. Hornblende barometry indicates pressures of similar to 0.46 GPa consistent with the presence of magmatic epidote. Field relationships between the two Plutons, the volcanic and volcaniclastic rocks of the Biella Volcanic Suite...

  1. The influence of inherited structures on magmatic and amagmatic processes in the East African Rift. (United States)

    Biggs, J.; Lloyd, R.; Hodge, M.; Robertson, E.; Wilks, M.; Fagereng, A.; Kendall, J. M.; Mdala, H. S.; Lewi, E.; Ayele, A.


    The idea that crustal heterogeneities, particularly inherited structures, influence the initiation and evolution of continental rifts is not new, but now modern techniques allow us to explore these controls from a fresh perspective, over a range of lengthscales, timescales and depths. In amagmatic rifts, I will demonstrate that deep fault structure is controlled by the stress orientation during the earliest phase of rifting, while the surface expression exploits near-surface weaknesses. I will show that pre-existing structures control the storage and orientation of deeper magma reservoirs in magmatic rifts, while the tectonic stress regime controls intra-rift faulting and shallow magmatism and stresses related to surface loading and cycles of inflation and deflation dominate at volcanic edifices. Finally, I will show how cross-rift structures influence short-term processes such as deformation and seismicity. I will illustrate the talk throughout using examples from along the East African Rift, including Malawi, Tanzania, Kenya and Ethiopia.


    Directory of Open Access Journals (Sweden)

    Jakob Pamić


    Full Text Available In the paper are presented basic geological, petrologieca1, geochemi-cal and mineral deposit data for five main magmatic-metallogenic formations of the northwestern and central Dinarides: (lThe Permo Triassic rifting related andesite-diorite formations; (2 The Jurassic-Lower Cretaceous accretionary (ophiolite formations; (3 The Upper Cretaceous-Paleogene subduction related basalt-rhyohite formations; (4 The Paleogene collisional granite formations, and (5 The Oligo-cene-Neogene postsubduction andesite formations. All these magmatic-metallogenic formations originated in different geotectonic settings during the Alpine evolution of the Dinaridic parts of thc Tethys and the postorogenic evolution of the Paratethys and the Pannonian Basin, respectively.

  3. Trouble Upstairs: Reconstructing Permian-Triassic Climate during Siberian Traps Magmatism (United States)

    Black, B. A.; Neely, R. R., III; Lamarque, J. F.; Elkins-Tanton, L. T.; Mills, M. J.


    The eruption of large igneous provinces can transfer significant masses of volatiles from Earth's interior to the atmosphere. What are the consequences of this degassing for habitability and extinction? In this presentation, we consider this question in the context of Siberian Traps magmatism, which has been shown to overlap within geochronologic uncertainty with catastrophic deterioration of Permian-Triassic marine and terrestrial ecosystems. To investigate the impacts of endogenic gases on climate, atmospheric chemistry, and ocean circulation, we conducted a series of numerical experiments with a comprehensive global model for the Permian-Triassic. Our simulations predict the intensity and distribution of acid rain and ozone depletion, with implications for terrestrial biota. We further explore feedbacks between sulfur emissions, transient cooling, and shifts in ocean circulation. We suggest that Siberian Traps magmatism may have triggered several distinct kill mechanisms in the oceans and on land, contributing to a complex combined pattern of environmental stress and latest Permian ecological failure.


    Directory of Open Access Journals (Sweden)

    Ioan Bâca


    Full Text Available Igneous intrusive structures from Bârgău Mountains belong to the group of central Neogene volcanic chain of the Eastern Carpathians of Romania. The evolution of the relief developed on these structures are three main stages: the stage of injection of structures (Pannonian, the stage of uncovering of igneous intrusive bodies from Oligo-Miocene sedimentary cover (Pliocene, and the stage of subaerial modeling of magmatic bodies (Pliocene-current.In those circumstances, the geodiversity of intrusive magmatic structures from Bârgău Mountains is represented by several types of landforms such as: polycyclic landforms (erosional levels, structural landforms (the configuration of igneous intrusive structures, petrographic landforms (andesites, lithological contact, fluvial landforms (valleys, slopes, ridges, periglacial landforms (cryogenic and crionival landforms, biogenic and anthropogenic landforms. This study highlights certain features of the landforms modeled on igneous intrusive bodies with the aim of developing some strategy for tourism recovery by local and county authorities.

  5. FOREWORD Fluid Mechanics and Fluid Power (FMFP)

    Indian Academy of Sciences (India)

    This section of the Special Issue carries selected articles from the Fluid Mechanics and Fluid. Power Conference held during 12–14 December 2013 at the National Institute of Technology,. Hamirpur (HP). The section includes three review articles and nine original research articles. These were selected on the basis of their ...

  6. Rb-Sr geochronology of neoproterozoic syenites in parts of northern Tamil Nadu: implication on Pan-African magmatism

    International Nuclear Information System (INIS)

    Pandey, U.K.; Prasad, R.N.; Krishna, Veena; Paneer Selvam, A.; Chabria, Tikam


    This paper presents Rb-Sr whole rock isochron age data on two syenite plutons viz. Elagiri and Rasimalai, and results of this study may constrain the timing of magmatic event and crystal evolution in northern granulite segment

  7. Physical processes of magmatism and effects on the potential repository: Synthesis of technical work through Fiscal Year 1995

    International Nuclear Information System (INIS)

    Valentine, G.A.


    This chapter summarizes data collection and model calculations through FY 95 under Study Plan Physical Processes of Magmatism and Effects on the Potential Repository. The focus of this study plan is to gather information that ultimately constrains the consequences of small-volume, basaltic magmatic activity at or near a potential repository. This is then combined with event probability estimates, described elsewhere in this synthesis report, to yield a magmatic risk assessment. Tere are two basic classes of effects of magmatisms that are considered here: (1) Eruptive effects, whereby rising magma intersects a potential repository, entrains radioactive waste, and erupts it onto the earth's surface. (2) Subsurface effects, which includes a wide range of processes such as hydrothermal flow, alteration of mineral assemblages in the potential repository system, and alteration of hydrologic flow properties of the rocks surrounding a potential repository

  8. Physical processes of magmatism and effects on the potential repository: Synthesis of technical work through Fiscal Year 1995

    Energy Technology Data Exchange (ETDEWEB)

    Valentine, G.A.


    This chapter summarizes data collection and model calculations through FY 95 under Study Plan Physical Processes of Magmatism and Effects on the Potential Repository. The focus of this study plan is to gather information that ultimately constrains the consequences of small-volume, basaltic magmatic activity at or near a potential repository. This is then combined with event probability estimates, described elsewhere in this synthesis report, to yield a magmatic risk assessment. Tere are two basic classes of effects of magmatisms that are considered here: (1) Eruptive effects, whereby rising magma intersects a potential repository, entrains radioactive waste, and erupts it onto the earth`s surface. (2) Subsurface effects, which includes a wide range of processes such as hydrothermal flow, alteration of mineral assemblages in the potential repository system, and alteration of hydrologic flow properties of the rocks surrounding a potential repository.

  9. Degradation of alachlor in aqueous solution by using hydrodynamic cavitation. (United States)

    Wang, Xikui; Zhang, Yong


    The degradation of alachlor aqueous solution by using hydrodynamic cavitation was systematically investigated. It was found that alachlor in aqueous solution can be deomposed with swirling jet-induced cavitation. The degradation can be described by a pseudo-first-order kinetics and the degradation rate was found to be 4.90x10(-2)min(-1). The effects of operating parameters such as fluid pressure, solution temperature, initial concentration of alachlor and medium pH on the degradation rates of alachlor were also discussed. The results showed that the degradation rates of alachlor increased with increasing pressure and decreased with increasing initial concentration. An optimum temperature of 40 degrees C existed for the degradation rate of alachlor and the degradation rate was also found to be slightly depend on medium pH. Many degradation products formed during the process, and some of them were qualitatively identified by GC-MS.

  10. Meso- and microscale structures related to post-magmatic deformation of the outer Izu-Bonin-Mariana fore arc system: preliminary results from IODP Expedition 352 (United States)

    Micheuz, P.; Kurz, W.; Ferre, E. C.


    IODP Expedition 352 aimed to drill through the entire volcanic sequence of the Bonin fore arc. Four sites were drilled, two on the outer fore arc and two on the upper trench slope. Analysis of structures within drill cores, combined with borehole and site survey seismic data, indicates that tectonic deformation in the outer Izu-Bonin-Mariana fore arc is mainly post-magmatic, associated with the development of syn-tectonic sedimentary basins. Within the magmatic basement, deformation was accommodated by shear along cataclastic fault zones, and the formation of tension fractures, hybrid (tension and shear) fractures, and shear fractures. Veins commonly form by mineral filling of tension or hybrid fractures and, generally, show no or limited observable macroscale displacement along the fracture plane. The vein filling generally consists of (Low Mg-) calcite and/or various types of zeolite as well as clay. Vein frequency varies with depth but does not seem to correlate with the proximity of faults. This may indicate that these veins are genetically related to hydrothermal activity taking place shortly after magma cooling. Host-rock fragments are commonly embedded within precipitated vein material pointing to a high fluid pressure. Vein thickness varies from < 1 mm up to 15 mm. The wider veins appear to have formed in incremental steps of extension. Calcite veins tend to be purely dilational at shallow depths, but gradually evolve towards oblique tensional veins at depth, as shown by the growth of stretched calcite and/or zeolites (idiomorphic and/or stretched) with respect to vein margins. With increasing depth, the calcite grains exhibit deformation microstructures more frequently than at shallower core intervals. These microstructures include thin twinning (type I twins), increasing in width with depth (type I and type II twins), curved twins, and subgrain boundaries indicative of incipient plastic deformation.

  11. Xenopumice erupted on 15 October 2011 offshore of El Hierro (Canary Islands): a subvolcanic snapshot of magmatic, hydrothermal and pyrometamorphic processes (United States)

    Del Moro, S.; Di Roberto, A.; Meletlidis, S.; Pompilio, M.; Bertagnini, A.; Agostini, S.; Ridolfi, F.; Renzulli, A.


    On 15 October 2011, a submarine eruption offshore of El Hierro Island gave rise to floating volcanic products, known as xenopumices, i.e., pumiceous xenoliths partly mingled and coated with the juvenile basanitic magma. Over the last few years, no consensus in the scientific community in explaining the origin of these products has been reached. In order to better understand the formation of xenopumice, we present a textural, mineralogical, and geochemical study of the possible magmatic, hydrothermal, and pyrometamorphic processes, which usually operate in the plumbing systems of active volcanoes. We carried out a comprehensive SEM investigation and Sr-Nd-Pb isotope analyses on some samples representative of three different xenopumice facies. All the data were compared with previous studies, new data for El Hierro extrusives and a literature dataset of Canary Islands igneous and sedimentary rocks. In the investigated xenopumices, we emphasize the presence of restitic magmatic phases as well as crystallization of minerals (mainly olivine + pyroxene + magnetite aggregates) as pseudomorphs after pre-existing mafic phenocrysts, providing evidence of pyrometamorphism induced by the high-T juvenile basanitic magma. In addition, we identify veins consisting of zircon + REE-oxides + mullite associated with Si-rich glass and hydrothermal quartz, which indicate the fundamental role played by hydrothermal fluid circulation in the xenopumice protolith. The petrological data agree with a pre-syneruptive formation of the xenopumice, when El Hierro basanite magma intruded hydrothermally altered trachyandesite to trachyte rocks and triggered local partial melting. Therefore, the El Hierro xenopumice represents a snapshot of the transient processes at the magma-wall rock interface, which normally occurs in the feeding system of active volcanoes.

  12. Gondwana subduction-modified mantle domain prevents magmatic seafloor generation in the Central Indian Ridge (United States)

    Morishita, T.; Nakamura, K.; Senda, R.; Suzuki, K.; Kumagai, H.; Sato, H.; Sato, T.; Shibuya, T.; Minoguchi, K.; Okino, K.


    The creation of oceanic crust at mid-ocean ridges is essential to understanding the genesis of oceanic plate and the evolution of the Earth. Detailed bathymetric measurements coupled with dense sample recovery at mid-ocean ridge revealed a wide range of variations in the ridge and seafloor morphologies, which cannot be simply explained by a spreading rate, but also by ridge geometry, mantle compositions and thermal structure (Dick et al., 2003 Nature; Cannat et al. 2006 Geology). It is now widely accepted that very limited magmatic activity with tectonic stretching generates oceanic core complex and/or smooth seafloor surface in the slow to ultraslow-spreading ridges, where serpentinized peridotite and gabbros are expected to be exposed associated with detachment faults (Cann et al., 1997 Nature; Cannat et al., 2006), although magmatism might be an essential role for the formation of oceanic core complexes (Buck et al., 2005 Nature; Tucholke et al 2008 JGR). A rising question is why magmatic activity is sometimes prevented during the oceanic plate formation. Ancient melting domain, that are too refractory to melt even in adiabatically upwelling to the shallow upper mantle, might cause the amagmatic spreading ridges (Harvey et al., 2006 EPSL, Liu et al.,2008 Nature). Its origin and effect on seafloor generations are, however, not well understood yet. We report an oceanic hill as an example of an ancient subduction-modified mantle domain, probably formed at continental margin of the Gondwanaland~Pangea supercontinent, existing beneath the Central Indian Ridge. This domain is the most likely to have prevented magmatic seafloor generation, resulting in creation of very deep oceanic valley and serpentine diaper (now the studied oceanic hill) at the present Central Indian ridge.

  13. 50 Myr of pulsed mafic magmatism in the High Arctic Large Igneous Province (United States)

    Pearson, D. G.; Dockman, D. M.; Heaman, L. M.; Gibson, S. A.; Sarkar, C.


    Extensive and voluminous Cretaceous mafic magmatism in the Sverdrup Basin of Arctic Canada forms the circum-Arctic High Arctic Large Igneous Province (HALIP). The small number of published high-precision ages for this LIP indicate its eruption over a considerable timespan raising concerns over whether the HALIP can be strictly defined as a single LIP and questioning the role of a single or multiple plumes in its genesis. Here we present an integrated geochemical and geochronological study to better constrain the timing and cause of mafic magma genesis in the Canadian HALIP. Six new U-Pb and four 40Ar/39Ar ages of mafic lavas and intrusive sheets range from 121 Ma to 78 Ma. The U-Pb ages are the first analyzed from the mafic intrusions of Axel Heiberg and Ellesmere Islands. The new geochronology, combined with other published high-precision ages, reveal a > 50 Myr duration of mafic magmatism in the HALIP defined by three main pulses. Tholeiites dominate the initial 25 Myr of magmatism, transitioning to coeval emplacement of alkali and tholeiitic basalts. Whole-rock Sr-Nd isotope ratios indicate that both magma types are derived from a similar source dominated by convecting mantle. Rare-earth-element inversion models reveal that the alkalic and tholeiitic magmas were generated beneath a bimodal lithospheric `lid' thickness of 65 ± 5 and 45 ± 4 km, respectively. We suggest that the early 128 - 122 Ma tholeiitic event is primarily plume-generated and correlates across the circum-Arctic with the other HALIP tholeiites. Younger HALIP magmatism, with coeval alkalic and tholeiitic magmas erupting over 25 Myr, may be explained by alternating modes of edge-driven mantle convection as the primary control on magma genesis. A distal plume may have intensified magma production by edge-driven convection.

  14. Magmatic versus tectonic influence in the Eolian arc: the case of Vulcano and Lipari islands revisited (United States)

    Ruch, Joel; Di Lorenzo, Riccardo; Vezzoli, Luigina Maria; De Rosa, Rosanna; Acocella, Valerio; Catalano, Stefano; Romagnoli, Gino


    The prevalent influence of magma versus tectonics for the edification and the evolution of volcanic zones is matter of debate. Here we focus on Vulcano and Lipari, two active volcanic islands located in the central sector of the Eolian arc (North of Sicily). Both systems are influenced by regional tectonics and affected by historical magmatic events taking place along a NS oriented structure, connecting both islands. We revisit and implement previous structural studies performed during the 1980's considering several new geophysical, geochemical and geodynamical findings. Four extensive structural campaigns have been performed on both islands and along the shorelines in 2012-2013 covering about 80% of the possible accessible outcrops. We collected ~500 measurements (e.g. faults, fractures and dikes) at 40 sites. Overall, most of the observed structures are oriented N-S and NNW-SSE, confirming previous studies, however, almost all features are strikingly dominated by an EW-oriented extensive regime, which is a novelty. These findings are supported by kinematic indicators and suggest a predominant dip-slip component (pitch from 80 and 130°) with alternating left and right kinematics. Marginal faulting in most recent formations have been observed, suggesting that the deformation may occur preferentially during transient deformation related to periods of magmatic activity, instead of resulting from continuous regional tectonic processes. Overall, fault and dike planes are characterized by a dominant eastward immersion, suggesting an asymmetric graben-like structure of the entire area. This may be explained by the presence of a topographic gradient connecting both islands to the deep Gioia basin to the East, leading to a preferential ample gravitational collapse. Finally, we propose a model in which the stress field rotates northward. It transits from a pure right lateral strike-slip regime along the Tindari fault zone (tectonic-dominant) to an extensive regime

  15. Late Carboniferous Monzonite-Granosyenite Magmatism in the Northern Balkhash Region (Central Kazakhstan) (United States)

    Ermolov, P. V.; Degtyarev, K. E.; Salnikova, E. B.; Tretyakov, A. A.; Kotov, A. B.; Anisimova, I. V.; Plotkina, Yu. V.


    U-Pb dating of the Torangalyk Complex (Northern Balkhash) yielded a Late Carboniferous age of 305 ± 2 Ma. Taking into account the previous data, a new scheme for Late Paleozoic granitic magmatism in this region has been proposed. It includes the Early Carboniferous granite-granodiorite Balkhash Complex, Late Carboniferous monzonite-granosyenite Kokdombak and Torangalyk complexes, and the Late Carboniferous-Early Permian granite-leucogranite Akchatau Complex.

  16. Evidence for extreme partitioning of copper into a magmatic vapor phase

    International Nuclear Information System (INIS)

    Lowenstern, J.B.; Mahood, G.A.; Rivers, M.L.; Sutton, S.R.


    The discovery of copper sulfides in carbon dioxide- and chlorine-bearing bubbles in phenocryst-hosted melt inclusions shows that copper resides in a vapor phase in some shallow magma chambers. Copper is several hundred times more concentrated in magmatic vapor than in coexisting pantellerite melt. The volatile behavior of copper should be considered when modeling the volcanogenic contribution of metals to the atmosphere and may be important in the formation of copper porphyry ore deposits

  17. Hierarchically porous graphene in natural graphitic globules from silicate magmatic rocks




    Naturally-occurring nanostructured graphites from silicate magmatic rocks, which are rare, were characterized using electron microscope and X-ray spectroscopy. This graphite consists of porous carbon, nanographite layers, microand nanotubes. The porous carbon is classified as macroporous matter with a small amount of mezopores. Evidence for the unusual properties of porous carbon are given: nanographite layers are created at the exposed surface of sample and the nanotubes occurs in the bulk o...

  18. Evolution of the earliest mantle caused by the magmatism-mantle upwelling feedback: Implications for the Moon and the Earth (United States)

    Ogawa, M.


    The two most important agents that cause mantle evolution are magmatism and mantle convection. My earlier 2D numerical models of a coupled magmatism-mantle convection system show that these two agents strongly couple each other, when the Rayleigh number Ra is sufficiently high: magmatism induced by a mantle upwelling flow boosts the upwelling flow itself. The mantle convection enhanced by this positive feedback (the magmatism-mantle upwelling, or MMU, feedback) causes vigorous magmatism and, at the same time, strongly stirs the mantle. I explored how the MMU feedback influences the evolution of the earliest mantle that contains the magma ocean, based on a numerical model where the mantle is hot and its topmost 1/3 is partially molten at the beginning of the calculation: The evolution drastically changes its style, as Ra exceeds the threshold for onset of the MMU feedback, around 107. At Ra 107, however, the mantle remains compositionally more homogeneous in spite of the widespread magmatism, and the deep mantle remains hotter than the shallow mantle, because of the strong convective stirring caused by the feedback. The threshold value suggests that the mantle of a planet larger than Mars evolves in a way substantially different from that in the Moon does. Indeed, in my earlier models, magmatism makes the early mantle compositionally stratified in the Moon, but the effects of strong convective stirring overwhelms that of magmatism to keep the mantle compositionally rather homogeneous in Venus and the Earth. The MMU feedback is likely to be a key to understanding why vestiges of the magma ocean are so scarce in the Earth.

  19. Repeated magmatic intrusions at El Hierro Island following the 2011-2012 submarine eruption (United States)

    Benito-Saz, Maria A.; Parks, Michelle M.; Sigmundsson, Freysteinn; Hooper, Andrew; García-Cañada, Laura


    After more than 200 years of quiescence, in July 2011 an intense seismic swarm was detected beneath the center of El Hierro Island (Canary Islands), culminating on 10 October 2011 in a submarine eruption, 2 km off the southern coast. Although the eruption officially ended on 5 March 2012, magmatic activity continued in the area. From June 2012 to March 2014, six earthquake swarms, indicative of magmatic intrusions, were detected underneath the island. We have studied these post-eruption intrusive events using GPS and InSAR techniques to characterize the ground surface deformation produced by each of these intrusions, and to determine the optimal source parameters (geometry, location, depth, volume change). Source inversions provide insight into the depth of the intrusions ( 11-16 km) and the volume change associated with each of them (between 0.02 and 0.13 km3). During this period, > 20 cm of uplift was detected in the central-western part of the island, corresponding to approximately 0.32-0.38 km3 of magma intruded beneath the volcano. We suggest that these intrusions result from deep magma migrating from the mantle, trapped at the mantle/lower crust discontinuity in the form of sill-like bodies. This study, using joint inversion of GPS and InSAR data in a post-eruption period, provides important insight into the characteristics of the magmatic plumbing system of El Hierro, an oceanic intraplate volcanic island.

  20. Neogene magmatism and its possible causal relationship with hydrocarbon generation in SW Colombia (United States)

    Vásquez, Mónica; Altenberger, Uwe; Romer, Rolf L.


    The Cretaceous oil-bearing source and reservoir sedimentary succession in the Putumayo Basin, SW Colombia, was intruded by gabbroic dykes and sills. The petrological and geochemical character of the magmatic rocks shows calc-alkaline tendency, pointing to a subduction-related magmatic event. K/Ar dating of amphibole indicates a Late Miocene to Pliocene age (6.1 ± 0.7 Ma) for the igneous episode in the basin. Therefore, we assume the intrusions to be part of the Andean magmatism of the Northern Volcanic Zone (NVZ). The age of the intrusions has significant tectonic and economic implications because it coincides with two regional events: (1) the late Miocene/Pliocene Andean orogenic uplift of most of the sub-Andean regions in Peru, Ecuador and Colombia and (2) a pulse of hydrocarbon generation and expulsion that has reached the gas window. High La/Yb, K/Nb and La/Nb ratios, and the obtained Sr-Nd-Pb isotopic compositions suggest the involvement of subducted sediments and/or the assimilation of oceanic crust of the subducting slab. We discuss the possibility that magma chamber(s) west of the basin, below the Cordillera, did increase the heat flow in the basin causing generation and expulsion of hydrocarbons and CO2.

  1. Geothermal constraints on Emeishan mantle plume magmatism: paleotemperature reconstruction of the Sichuan Basin, SW China (United States)

    Zhu, Chuanqing; Hu, Shengbiao; Qiu, Nansheng; Jiang, Qiang; Rao, Song; Liu, Shuai


    The Middle-Late Permian Emeishan Large Igneous Province (ELIP) in southwestern China represents a classic example of a mantle plume origin. To constrain the thermal regime of the ELIP and contemporaneous magmatic activity in the northeastern Sichuan Basin, maximum paleotemperature profiles of deep boreholes were reconstructed using vitrinite reflectance (Ro) and apatite fission track data. Two heating patterns were identified: (1) heating of the overlying lithosphere by magma storage regions and/or magmatic activity related to the mantle plume, which resulted in a relatively strong geothermal field and (2) direct heating of country rock by stock or basalt. Borehole Ro data and reconstructed maximum paleotemperature profiles near the ELIP exhibit abrupt tectonothermal unconformities between the Middle and Late Permian. The profiles in the lower subsections (i.e., pre-Middle Permian) exhibited significantly higher gradients than those in the upper subsections. Distal to the basalt province, high paleo-geotemperatures (hereafter, paleotemperatures) were inferred, despite deformation of the paleogeothermal curve due to deep faults and igneous rocks within the boreholes. In contrast, Ro profiles from boreholes without igneous rocks (i.e., Late Permian) contained no break at the unconformity. Paleotemperature gradients of the upper and the lower subsections and erosion at the Middle/Late Permian unconformity revealed variations in the thermal regime. The inferred spatial distribution of the paleothermal regime and the erosion magnitudes record the magmatic and tectonic-thermal response to the Emeishan mantle plume.

  2. Present-day Opening of the Natron Rift: Tectonic and Magmatic Processes at Work (United States)

    Calais, E.; Dalaison, M.; Saria, E.; Doubre, C.; Masson, F.


    The young Natron basin (system, is an important locale to study the initial stage of continental rifting. It was the locus of a rarely observed tectono-magmatic event in July 2007, with slow slip on an intra-basin normal fault followed by a 10 km-long dike intrusion underneath the Gelai shield volcano. Here we report on a series of GPS observations over a 20-site network spanning the basin, measured repeatedly since 2013. We observe a long wavelength ( 200 km wide) extension with a horizontal rate of about 2 mm/yr, consistent with recentlty published regional kinematic models, and a velocity gradient centered on the west-bounding fault of the Natron basin. Initial models show that the data is best fit by a normal fault dipping 60 degrees to the east and slipping at a rate of 6 mm/yr. Superimposed on this long wavelength extension, we observe a smaller scale ( 30 km wide) extensional signal in the middle of the basin, roughly coincident with the location of the Gelai volcano, which was the locale of the 2007 seismic-magmatic crisis. We investigate the relative importance of tectonic faulting, post-diking relaxation following the 2007 intrusion (as observed for instance in Afar or Iceland after similar events), and melt recharge of the intra-basin magmatic system in present-day extension across this young segment of the East African Rift.

  3. Post-rift magmatism in the Pearl River Mouth Basin, northern South China Sea (United States)

    Xu, H.; Zhao, F.; Xia, S.; Sun, J.; Fan, C.


    Multi-beam, 2D seismic reflection and borehole data reveal that post-rift magmatism are widespread in the northern margin of South China Sea. A large-scale volcanic complex was identified at water depths of 500 to 3000 m, covering an area of ca. 8000 km2. This volcanic complex includes seamounts, igneous sills, dykes and intruded volcanic bodies. Combining data from exploration wells BY7-1 and BY2 with published seismic stratigraphic data, we can highlight multiple extrusive events from the Early Oligocene to Early Miocene, reflecting progressive continental breakup in the South China Sea. Most intruded magma through the continental crust also uplifted sediments up to the T6 unconformity. Given the evidence in this work that Early Miocene magmatic bodies were developed above or along faults, we suggest that post-rift magmatism in the northern margin of the South China Sea was largely controlled by the faults. Reactivation events in the faults are suggested to have generated preferential vertical pathways for the ascent of magma within a context of progressive continental breakup and thinned continental crust, as the South China Sea was being formed.

  4. Remote detection of magmatic water in Bullialdus crater on the Moon (United States)

    Klima, Rachel L.; Cahill, John; Hagerty, Justin J.; Lawrence, David


    Once considered dry compared with Earth, laboratory analyses of igneous components of lunar samples have suggested that the Moon’s interior is not entirely anhydrous. Water and hydroxyl have also been detected from orbit on the lunar surface, but these have been attributed to nonindigenous sources, such as interactions with the solar wind. Magmatic lunar volatiles—evidence for water indigenous to the lunar interior—have not previously been detected remotely. Here we analyse spectroscopic data from the Moon Mineralogy Mapper (M3) and report that the central peak of Bullialdus Crater is significantly enhanced in hydroxyl relative to its surroundings. We suggest that the strong and localized hydroxyl absorption features are inconsistent with a surficial origin. Instead, they are consistent with hydroxyl bound to magmatic minerals that were excavated from depth by the impact that formed Bullialdus Crater. Furthermore, estimates of thorium concentration in the central peak using data from the Lunar Prospector orbiter indicate an enhancement in incompatible elements, in contrast to the compositions of water-bearing lunar samples. We suggest that the hydroxyl-bearing material was excavated from a magmatic source that is distinct from that of samples analysed thus far.

  5. Effects of magmatic processes on the potential Yucca Mountain repository: Field and computational studies

    International Nuclear Information System (INIS)

    Valentine, G.A.; Groves, K.R.; Gable, C.W.; Perry, F.V.; Crowe, B.M.


    Assessing the risk of future magmatic activity at a potential Yucca Mountain radioactive waste repository requires, in addition to event probabilities, some knowledge of the consequences of such activity. Magmatic consequences are divided into an eruptive component, which pertains to the possibility of radioactive waste being erupted onto the surface of Yucca Mountain, and a subsurface component, which occurs whether there is an accompanying eruption or not. The subsurface component pertains to a suite of processes such as hydrothermal activity, changes in country rock properties, and long term alteration of the hydrologic flow field which change the waste isolation system. This paper is the second in a series describing progress on studies of the effects of magmatic activity. We describe initial results of field analog studies at small volume basaltic centers where detailed measurements are being conducted of the amount of wall rock debris that can be erupted as a function of depth in the volcanic plumbing system. Constraints from field evidence of wall rock entrainment mechanisms are also discussed. Evidence is described for a mechanism of producing subhorizontal sills versus subvertical dikes, an issue that is important for assessing subsurface effects. Finally, new modeling techniques, which are being developed in order to capture the three dimensional complexities of real geologic situations in subsurface effects, are described

  6. Fluid and heat transport at the Torres del Paine laccolith (Patagonia/Chile)

    International Nuclear Information System (INIS)

    Putliz, B; Baumgartner, L.P; Oberhansli, R; Diamond, L; Altenberger, U


    The 12 Ma old Torres del Paine laccolith (TPL) is part of a chain of isolated Miocene plutons and subvolcanic rocks which intruded the foothills of the southern Andes of Chile and Argentina (Halpern, 1973; Michael, 1984). The 12x12 km big laccolith, an I-type granite, intruded mudstones, sandstones, carbonates and conglomerates of the Cretaceous Cerro Torre and Punta Barrosa formation (Wilson, 1991) creating a well defined, but small contact aureole of 200-400m width. The TPL contains abundant textural evidence of fluid exsolution and eutectic crystallisation. It hence represents a good example for the transport of large quantities of magmatic aqueous fluids to the uppermost level of the crust. The pluton is well exposed and its rugged topography allows the investigation of the roof, the lateral rims and the base of the intrusion. Field and textural observations, phase petrological constraints, oxygen isotope and fluid inclusion data are used to unravel mechanism and patterns of fluid and heat transport in the intrusion and the contact aureole. The Torres del Paine Intrusives form a calcalkaline suite, ranging from gabbros through diorites to leucogranites. The intrusive body has the general shape of a laccolith (Skarmeta and Castelli, 1997). Gabbroic and dioritic rocks are only exposed at the lower levels. Granites are clearly predominant - the main body of the laccolith is composed of a fine to medium grained biotite-orthoclase granite. The TPL is remarkable for its abundance of miarolitic cavities. Locally, at the margins of the pluton, a microgranitic phase is found with up to 15% of cavities. While some miaroles are isolated, others are interconnected, forming tube-like structures. Open miaroles contain euhedral crystals of quartz and feldspar. Other important phases are biotite, tourmaline, fayalite and late chlorite and carbonate. Individual crystals are typically between < 1cm up to a few cm in length. Some miaroles are completely filled with coarse quartz

  7. Lectures on fluid mechanics

    CERN Document Server

    Shinbrot, Marvin


    Readable and user-friendly, this high-level introduction explores the derivation of the equations of fluid motion from statistical mechanics, classical theory, and a portion of the modern mathematical theory of viscous, incompressible fluids. 1973 edition.

  8. Synovial Fluid Analysis (United States)

    ... Plasma Free Metanephrines Platelet Count Platelet Function Tests Pleural Fluid Analysis PML-RARA Porphyrin Tests Potassium Prealbumin ... is being tested? Synovial fluid is a thick liquid that acts as a lubricant for the body's ...

  9. Electric fluid pump (United States)

    Van Dam, Jeremy Daniel; Turnquist, Norman Arnold; Raminosoa, Tsarafidy; Shah, Manoj Ramprasad; Shen, Xiaochun


    An electric machine is presented. The electric machine includes a hollow rotor; and a stator disposed within the hollow rotor, the stator defining a flow channel. The hollow rotor includes a first end portion defining a fluid inlet, a second end portion defining a fluid outlet; the fluid inlet, the fluid outlet, and the flow channel of the stator being configured to allow passage of a fluid from the fluid inlet to the fluid outlet via the flow channel; and wherein the hollow rotor is characterized by a largest cross-sectional area of hollow rotor, and wherein the flow channel is characterized by a smallest cross-sectional area of the flow channel, wherein the smallest cross-sectional area of the flow channel is at least about 25% of the largest cross-sectional area of the hollow rotor. An electric fluid pump and a power generation system are also presented.

  10. Cerebrospinal fluid culture (United States)

    ... Alternative Names Culture - CSF; Spinal fluid culture; CSF culture Images Pneumococci organism References Karcher DS, McPherson RA. Cerebrospinal, synovial, serous body fluids, and alternative specimens. In: McPherson RA, Pincus ...

  11. Cerebrospinal fluid leak (image) (United States)

    ... brain and spinal cord by acting like a liquid cushion. The fluid allows the organs to be buoyant protecting them from blows or other trauma. Inside the skull the cerebrospinal fluid is contained by the dura which covers ...

  12. Computational Fluid Dynamics

    International Nuclear Information System (INIS)

    Myeong, Hyeon Guk


    This book deals with computational fluid dynamics with basic and history of numerical fluid dynamics, introduction of finite volume method using one-dimensional heat conduction equation, solution of two-dimensional heat conduction equation, solution of Navier-Stokes equation, fluid with heat transport, turbulent flow and turbulent model, Navier-Stokes solution by generalized coordinate system such as coordinate conversion, conversion of basic equation, program and example of calculation, application of abnormal problem and high speed solution of numerical fluid dynamics.

  13. Fluid Density and Impact Cavity Formation

    Directory of Open Access Journals (Sweden)

    Ga-Chun Lin


    Full Text Available Characteristics of the impact cavity formed when a steel ball is dropped into aqueous solutions of densities ranging from 0.98 g·cm-3 to 1.63 g·cm-3 were investigated. A high-speed camera was used to record the formation and collapse of the cavity. The results showed cavity diameter, volume, and pinch-off time are independent of fluid density, on average. There was an unexplained reduction in cavity formation for densities of 1.34 g·cm-3 and 1.45 g·cm-3.

  14. Linking precious metal enrichment and halogen cycling in mafic magmatic systems: insights from the Rum layered intrusion, NW Scotland (United States)

    Kelly, A. P.; O'Driscoll, B.; Clay, P. L.; Burgess, R.


    Layered intrusions host the world's largest known concentrations of the platinum-group elements (PGE). Emphasis has been attached to the role of halogen-bearing fluids in concentrating the precious metals, but whether this occurs at the magmatic stage, or via subsequent metasomatism, is actively debated. One obstacle to progress has been the analytical difficulty of measuring low abundances of the halogens in the cumulate products of layered intrusions. To elucidate the importance of the halogens in facilitating PGE-mineralisation, as well as fingerprint halogen provenance and assess the importance of halogen cycling in mafic magma systems more generally, a suite of samples encompassing different stages of activity of the Palaeogene Rum layered intrusion was investigated. Halogen abundances were measured by neutron irradiation noble gas mass spectrometric analysis, permitting the detection of relatively low (ppm-ppb) abundances of Cl, Br and I in mg-sized samples. The samples include PGE-enriched chromite seams, various cumulates (e.g., peridotites), picrites (approximating the Rum parental magma), and pegmatites representing volatile-rich melts that circulated the intrusion at a late-stage in its solidification history. The new data reveal that PGE-bearing chromite seams contain relatively low Cl concentrations (2-3 ppm), with high molar ratios of Br/Cl and I/Cl (0.005 and 0.009, respectively). The picrites and cumulates have Br/Cl and I/Cl ratios close to sub-continental lithospheric mantle values of approximately 0.0013 and 0.00002, respectively, and thus likely reflect the Rum magma source region. A positive correlation between Cl and Br signifies comparable partitioning behaviour in all samples. However, I is more variable, displaying a positive correlation with Cl for more primitive samples (e.g. picrite and peridotite), and seemingly decoupling from Br and Cl in chromite seams and pegmatites. The relative enrichment of I over Cl in the chromite seams points

  15. The behaviour of the elements Ni, Co, Cu, Pb, Zn, Au, Ag, Mo, Sn, W and U in the magmatic, hydrothermal, sedimentary and weathering environments

    International Nuclear Information System (INIS)

    Anderson, J.R.


    In the last two decades much has been published on the behaviour of certain elements in the magmatic, hydrothermal, sedimentary and weathering environments, but the information is scattered throughout the literature. This situation prompted the present study on the elements Ni, Co, Cu, Pb, Zn, Au, Ag, Mo, Sn, W and U. The behaviour of the elements Ni, Cu, Pb, Zn, Au, Sn, W and U has been studied experimentally in some depth. Ag has been moderately studied, but there is very little information about Co and Mo. Studies on the complexes formed by the elements within the hydrothermal and aqueous environment are often inconclusive and controversial, but conclusions are drawn as to the more likely complexes formed. A genetic classification of ore deposits is used as a framework for the discussion. The source of the elements is regarded as being the mantle, and therefore discussion on other possible sources is beyond the scope of this dissertation. The crystal chemistry and geochemistry of the elements are presented and the essay concludes with a discussion on the elements within their depositional environments

  16. Genesis of the Hengling magmatic belt in the North China Craton: Implications for Paleoproterozoic tectonics (United States)

    Peng, Peng; Guo, Jinghui; Zhai, Mingguo; Windley, Brian F.; Li, Tiesheng; Liu, Fu


    The 2200-1880 Ma igneous rocks in the central and eastern parts of the North China Craton (NCC) constitute a new Hengling magmatic belt (HMB), which includes the ~ 2147 Ma Hengling mafic sill/dyke swarm, the ~ 2060 Ma Yixingzhai mafic dyke swarm, and the ~ 1973 Ma Xiwangshan mafic dyke swarm. The three swarms are contiguous and have experienced variable degrees of metamorphism from greenschist to low amphibolite facies (Hengling), medium granulite facies (Yixingzhai), and medium/high-pressure granulite facies (Xiwangshan). They are all tholeiitic in composition typically with 47-52 wt.% SiO2 and 4-10 wt.% MgO, and all show light rare earth element enrichments and Nb- and Ta-depletion. Their Nd TDM ages are in the range of 2.5-3.0 Ga. Specifically, the Hengling and Yixingzhai dykes/sills are depleted in Th, U, Zr, Hf and Ti, whereas the Xiwangshan dykes are enriched in U and weakly depleted in other elements. Variable Sr-anomalies indicate significant feldspar accumulation (positive anomalies) or fractionation. The ɛNd(t) values of the three swarms are: - 3.2-+3.0 (Hengling), - 1.7-+ 1.8 (Yixingzhai) and - 1.4-+ 1.0 (Xiwangshan). These mafic representatives of the HMB originated from the > 2.5 Ga sub-continental lithospheric mantle of the NCC, and with A-type granites and other igneous associations in this belt they likely evolved in an intra-continental rift. The progressive changing compositions of the three swarms are interpreted in terms of their source regions at different depths, i.e., shallower and shallower through time. And the decrease in scale and size of the intrusions and their magma volumes indicate the progressive weakening of magmatism in this rift. The rocks in this belt are different chronologically, petrologically and chemically from those in the Xuwujia magmatic belt (XMB). We propose that the two magmatic belts represent two different magmatic systems in different blocks of the NCC, i.e., an eastern block (with the HMB) and a western block

  17. Fluid Statics and Archimedes

    Indian Academy of Sciences (India)

    librium of a vertical slice fluid (Figure Id) of height H and again using the fact .... same fluid having the same shape and same volume as the body. This fluid volume .... example, can be caused by the heating of air near the ground by the sun ...

  18. Fullerol ionic fluids

    KAUST Repository

    Fernandes, Nikhil; Dallas, Panagiotis; Rodriguez, Robert; Bourlinos, Athanasios B.; Georgakilas, Vasilios; Giannelis, Emmanuel P.


    ®). The ionic fluid was compared to a control synthesized by mixing the partially protonated form (sodium form) of the fullerols with the same oligomeric amine in the same ratio as in the ionic fluids (20 wt% fullerol). In the fullerol fluid the ionic bonding

  19. Similar and Contrasting Response of Rifting and Transtension in the Gulf of California and Walker Lane to Preceding Arc Magmatism (United States)

    Henry, C. D.; Faulds, J. E.


    The Gulf of California (GC) and Walker Lane (WL) have undergone strikingly similar development with strike- slip faulting following initial extension. They differ significantly in the amount of Pacific-North American plate motion taken up by each: essentially all relative motion in the GC and ~25% in the WL. In both areas, ancestral arc magmatism preceded and probably focused deformation, perhaps because heating and/or hydration weakened the lithosphere. However, differences in migration of the Rivera (RTJ) and Mendocino triple junctions (MTJ) related to differences in the orientation of plate boundaries determined how strike-slip faulting developed. Abrupt southward jumps in the RTJ led to abrupt cessation of magmatism over arc lengths of as much as 1000 km and initiation of east-northeast extension within the future GC. The best known jump was at ~13 Ma, but an earlier jump occurred at ~18 Ma. Arc magmatism has been best documented in Baja California, Sonora, and Nayarit, although Baja constituted the most-trenchward fringe of the ancestral arc. New and published data indicate that Sinaloa underwent a similar history of arc magmatism. The greatest volume of the arc immediately preceding RTJ jumps was probably in mainland Mexico. Arc magmatism shut off following these jumps, extension began in the future GC, and strike-slip faulting either followed or accompanied extension in the GC. In contrast, the MTJ migrated progressively northward. New and published data indicate magmatism generally shut off coincident with this retreat, but distinct nodes or zones of magmatism, presumably unrelated to subduction, persisted or initiated after arc activity ceased. We have suggested that the WL has grown progressively northward, following the retreating arc, and that the northern WL is its youngest part. However, the timing of initiation of strike-slip faulting in most of the WL is poorly known and controversial. Testing our hypothesis requires determining initiation and

  20. Timing and thermochemical constraints on multi-element mineralisation at the Nori/RA Cu-Mo-U prospect, Great Bear magmatic zone, Northwest Territories, Canada (United States)

    Ootes, Luke; Goff, Steve; Jackson, Valerie A.; Gleeson, Sarah A.; Creaser, Robert A.; Samson, Iain M.; Evensen, Norman; Corriveau, Louise; Mumin, A. Hamid


    The timing of Cu-Mo-U mineralisation at the Nori/RA prospect in the Paleoproterozoic Great Bear magmatic zone has been investigated using Re-Os molybdenite and 40Ar-39Ar biotite geochronology. The Re-Os molybdenite ages presented are the first robust sulphide mineralisation ages derived from the Great Bear magmatic zone. Cu-Mo-U mineralisation is hosted in early to syn-deformational hydrothermal veins consisting of quartz and K-feldspar or more commonly tourmaline-biotite-quartz-K-feldspar, with associated wall-rock alteration assemblages being predominantly biotite. Sulphide and oxide minerals consist of chalcopyrite, molybdenite and uraninite with lesser pyrite and magnetite. Elevated light rare earth elements and tungsten concentrations associated with the Cu-Mo-U mineralisation have also been reported at the prospect by previous workers. Molybdenite and uraninite occur intimately in dravitic tourmaline growth zones and at grain margins, attesting to their syngenetic nature (with respect to hydrothermal veining). Two molybdenite separates yield Re-Os model ages of 1,874.4 ± 8.7 (2 σ) and 1,872.4 ± 8.8 Ma (2 σ) with a weighted average model age of 1,873.4 ± 6.1 Ma (2 σ). Laser step heating of biotite from the marginal alteration of the wall-rock adjacent to the veins yields a 40Ar-39Ar maximum cooling age of 1,875 ± 8 Ma (MSWD = 3.8; 2 σ), indistinguishable from the Re-Os molybdenite model age and a previously dated ‘syn-tectonic’ aplitic dyke in the region. Dravitic tourmaline hosts abundant primary liquid-vapour-solid-bearing fluid inclusions. Analytical results indicate liquid-vapour homogenisation at >260°C constraining the minimum temperature of mineralisation. The solids, which are possibly trapped, did not homogenise with the liquid-vapour by 400°C. Salinities in the inclusions are variable. Raman spectra identify that at least some of the solids are calcite and anhydrite. Raman spectra also confirm the vapour phases contain some CO2; whereas

  1. Discovering geothermal supercritical fluids: a new frontier for seismic exploration. (United States)

    Piana Agostinetti, Nicola; Licciardi, Andrea; Piccinini, Davide; Mazzarini, Francesco; Musumeci, Giovanni; Saccorotti, Gilberto; Chiarabba, Claudio


    Exploiting supercritical geothermal resources represents a frontier for the next generation of geothermal electrical power plant, as the heat capacity of supercritical fluids (SCF),which directly impacts on energy production, is much higher than that of fluids at subcritical conditions. Reconnaissance and location of intensively permeable and productive horizons at depth is the present limit for the development of SCF geothermal plants. We use, for the first time, teleseismic converted waves (i.e. receiver function) for discovering those horizons in the crust. Thanks to the capability of receiver function to map buried anisotropic materials, the SCF-bearing horizon is seen as the 4km-depth abrupt termination of a shallow, thick, ultra-high (>30%) anisotropic rock volume, in the center of the Larderello geothermal field. The SCF-bearing horizon develops within the granites of the geothermal field, bounding at depth the vapor-filled heavily-fractured rock matrix that hosts the shallow steam-dominated geothermal reservoirs. The sharp termination at depth of the anisotropic behavior of granites, coinciding with a 2 km-thick stripe of seismicity and diffuse fracturing, points out the sudden change in compressibility of the fluid filling the fractures and is a key-evidence of deep fluids that locally traversed the supercritical conditions. The presence of SCF and fracture permeability in nominally ductile granitic rocks open new scenarios for the understanding of magmatic systems and for geothermal exploitation.

  2. Fluid and particle mechanics

    CERN Document Server

    Michell, S J


    Fluid and Particle Mechanics provides information pertinent to hydraulics or fluid mechanics. This book discusses the properties and behavior of liquids and gases in motion and at rest. Organized into nine chapters, this book begins with an overview of the science of fluid mechanics that is subdivided accordingly into two main branches, namely, fluid statics and fluid dynamics. This text then examines the flowmeter devices used for the measurement of flow of liquids and gases. Other chapters consider the principle of resistance in open channel flow, which is based on improper application of th

  3. Fluid inclusion geothermometry (United States)

    Cunningham, C.G.


    Fluid inclusions trapped within crystals either during growth or at a later time provide many clues to the histories of rocks and ores. Estimates of fluid-inclusion homogenization temperature and density can be obtained using a petrographic microscope with thin sections, and they can be refined using heating and freezing stages. Fluid inclusion studies, used in conjunction with paragenetic studies, can provide direct data on the time and space variations of parameters such as temperature, pressure, density, and composition of fluids in geologic environments. Changes in these parameters directly affect the fugacity, composition, and pH of fluids, thus directly influencing localization of ore metals. ?? 1977 Ferdinand Enke Verlag Stuttgart.

  4. Fluid Mechanics and Fluid Power (FMFP)

    Indian Academy of Sciences (India)

    Amitabh Bhattacharya

    of renewable energy (e.g., via wind, hydrokinetic generators), creating low-cost healthcare ... multiphase flow, turbulence, bio-fluid dynamics, atmospheric flows, microfluidic flows, and ... study the challenging problem of entry of solids in water.

  5. Hydrothermal Evolution of the Giant Cenozoic Kadjaran porphyry Cu-Mo deposit, Tethyan metallogenic belt, Armenia, Lesser Caucasus: mineral paragenetic, cathodoluminescence and fluid inclusion constraints (United States)

    Hovakimyan, Samvel; Moritz, Robert; Tayan, Rodrik; Rezeau, Hervé


    stockwork. One of them is the east-west-oriented 6th vein zone in the northern part of the deposit, which contains quartz-molybdenite veins and late quartz-galena-sphalerite veins. This is interpreted as a telescoping between porphyry and epithermal environments. It is supported by microscopic studies of mineral paragenesis, which reveal the presence of enargite and tennantite-tetrahedrite, luzonite, sphalerite, and galena, generally in a gangue of quartz, followed by a late carbonate and gypsum stage. On-going fluid inclusion studies are being carried out on quartz samples from the different mineralization stages. Five types of fluid inclusions were distinguished according to their nature, bubble size, and daughter mineral content: vapor-rich, aqueous-carbonic, brine, polyphase brine and liquid-rich inclusions. Cathodoluminescence images from the porphyry veins reveal four generations of quartz. Molybdenite and chalcopyrite are associated with two different dark luminescent quartz generations, which contain typical brine, aqueous-carbonic and vapour-rich H2O fluid inclusions, with some of them coexisting locally as boiling assemblages. Epithermal veins are mainly characterized by liquid-rich H2O fluid inclusions. Microthermometric studies of fluid inclusions reveal a major difference in homogenisation temperatures between the early quartz-molybdenite- chalcopyrite stage (Thtotal between 3600 and 4250C) and the late quartz-galena-sphalerite vein stage (Thtotal 300-2700C), which is attributed to the transition from a porphyry to an epithermal environment in the Kadjaran deposit.

  6. Spatial Distribution of b-value of the Copahue volcano during 2012-2014 eruptive period: Relationship between magmatic and hydrothermal system (United States)

    Lazo, Jonathan; Basualto, Daniel; Bengoa, Cintia; Cardona, Carlos; Franco, Luis; Gil-Cruz, Fernando; Hernández, Erasmo; Lara, Luis; Lundgren, Paul; Medina, Roxana; Morales, Sergio; Peña, Paola; Quijada, Jonathan; Samsonov, Sergey; San Martin, Juan; Valderrama, Oscar


    Temporal and spatial variations of b-value have been interpreted as regional stress changes on active tectonic zones or magma ascent and/or hydrothermal fluids mobilization that could affect to active volcanic arc. Increasing of fluids pressure, medium heterogeneities or temperature changes would be the cause of these variations. The Copahue volcano is a shield strato-volcano that has been edified on the western margin of the Caviahue Caldera, located in the international border between Chile and Argentina, which contain an important geothermic field and is located at a horse-tail structure of the Liquiñe-Ofqui Fault Zone. The pre-fracture nature of its basement, as well as an extensive geothermic field, would be producing very complex conditions to fluids movement that could be exploring to use the 'b' value of the recorded seismicity between 2012 and 2014. Based in the database of VT seismic events, we used 2.073 events to calculate the b-value to obtain the 2D and 3D distribution maps. Results showed two anomalous zones: the first one located 9 Km to NE of the active crater, 3-6 Km depth, with high b-values (>1.2) that is associated with a very high production rate of small earthquakes that could suggest a brittle zone, located in the active geothermal field. The second zone, showed a low b-values (~ 0.7), located to east of the volcano edifice at volcano sitting on top of a geothermal system, the b-value offers a tool to understand the distribution of the seismic sources and hence a physical constrain for the coupled magmatic/hydrothermal system.

  7. Recent results on aqueous electrolyte cells

    KAUST Repository

    Wessells, Colin; Huggins, Robert A.; Cui, Yi


    The improved safety of aqueous electrolytes makes aqueous lithium-ion batteries an attractive alternative to commercial cells utilizing flammable and expensive organic electrolytes. Two important issues relating to their use have been addressed

  8. Titaniferous magnetite and barite from the San Gregorio de Polanco dike swarm, Paraná Magmatic Province, Uruguay

    Directory of Open Access Journals (Sweden)

    Rossana Muzio


    Full Text Available The San Gregorio de Polanco Dike Swarm (Tacuarembó Department, Uruguay is the southernmost set of dikes in the Paraná Magmatic Province of Uruguay. Five major dikes have been identified with two main structural trends: N140º–N170º and N50º–N80º. The dikes have tholeiitic affinities and are composed of plagioclase (An55, augite and augite-pigeonite, relicts of olivine and opaque minerals. These rocks have high contents of Fe–Ti oxides (titanomagnetites, the mineralogical and textural characteristics of which have been studied using scanning electron microscopy and energy dispersive spectrometry techniques (SEM – EDS. These features, along with other mineralogical and textural relationships, have been used to propose the following crystallization sequence for the dikes: (i crystallization of olivine, plagioclase and Ca-rich pyroxene phenocrysts; (ii precipitation of the first population of Ti-magnetite; (iii crystallization of plagioclase and pyroxene in the groundmass; (iv partial dissolution of Ti-magnetite by reaction with magmatic fluids; (v crystallization of the second population of Ti-magnetite and finally, (vi crystallization of interstitial barite.   Resumen El Haz de Diques de San Gregorio de Polanco (Departamento de Tacuarembó, Uruguay es la ocurrencia más meridional de diques pertenecientes a la Provincia Magmática Paraná en Uruguay. Fueron identificados cinco 5 diques principales con dos direcciones estructurales principales: N140º - N170º y N50º - N80º, respectivamente. Son diques de afinidad tholeítica compuestos por plagioclasa (An55, augita y augita-pigeonita, relictos de olivina y minerales opacos. Estos diques se caracterizan por el alto contenido de óxidos de Fe y Ti (titanomagnetitas, cuyas características mineralógicas y texturales fueron estudiadas con microscopio electrónico de barrido y espectrometría de energía dispersiva (SEM-EDS, incluyendo mapeos composicionales. Estas caracter

  9. Cryogenian alkaline magmatism in the Southern Granulite Terrane, India: Petrology, geochemistry, zircon U-Pb ages and Lu-Hf isotopes (United States)

    Santosh, M.; Yang, Qiong-Yan; Ram Mohan, M.; Tsunogae, T.; Shaji, E.; Satyanarayanan, M.


    The Southern Granulite Terrane (SGT) in India preserves the records of the formation and recycling of continental crust from Mesoarchean through Paleoproterozoic to Neoproterozoic and Cambrian, involving multiple subduction-accretion-collision associated with major orogenic cycles. A chain of unmetamorphosed and undeformed alkaline magmatic intrusions occurs along the northern margin of the SGT aligned along paleo-suture zones. Here we investigate two representative plutons from this suite, the Angadimogar syenite (AM) and the Peralimala alkali granite (PM) through field, petrological, geochemical, zircon U-Pb and Lu-Hf studies. Magma mixing and mingling textures and mineral assemblages typical of alkaline rocks are displayed by these plutons. The whole-rock major and trace element data characterize their alkaline nature. In trace element discrimination diagrams, the AM rocks straddle between the VAG (volcanic-arc granites) and WPG (within plate granites) fields with most of the samples confined to the VAG field, whereas the PM rocks are essentially confined to the WPG field. The diversity in some of the geochemical features between the two plutons is interpreted to be the reflection of source heterogeneities. Most zircon grains from the AM and PM plutons display oscillatory zoning typical of magmatic crystallization although some grains, particularly those from the PM pluton, show core-rim structures with dark patchy zoned cores surrounded by irregular thin rims resulting from fluid alteration. The weighted mean 206Pb/238U ages of the magmatic zircons from three samples of the AM syenite are in the range of 781.8 ± 3.8 Ma to 798 ± 3.6 Ma and those from two samples of the PM alkali granite yield ages of 797.5 ± 3.7 Ma and 799 ± 6.2 Ma. A mafic magmatic enclave from the AM pluton shows weighted mean 206Pb/238U age of 795 ± 3.3 Ma. The AM and PM plutons also carry rare xeneocrystic zircons which define upper intercept concordia ages of 3293 ± 13 Ma and 2530

  10. Growth Rates and Mechanisms of Magmatic Orbicule Formation: Insights from Calcium Isotopes (United States)

    Antonelli, M. A.; Watkins, J. M.; DePaolo, D. J.


    Orbicular diorites and granites are rare plutonic rock textures that remain enigmatic despite a century of study. Orbicules consist of a rounded core (xenolith, xenocryst, or autolith) surrounded by a variable number of concentric rings defined by different modal mineralogies and textures. Recent work suggests that the alternating layers of mineral growth are a consequence of either changes in external conditions of the magma (e.g. temperature, magma composition due to mixing, changes in volatile abundances), or rapid growth of one mineral phase (e.g plagioclase) creating a depleted boundary layer that then promotes precipitation of an alternative mineral phase (e.g. pyroxene). This process can be repeated to produce multiple layers. The rates at which orbicules grow is also of interest and relates to the mechanisms. Studies of orbicular diorites from the northern Sierra Nevada suggest exceptionally high growth rates (McCarthy et al., 2016). Ca isotopes can offer a unique perspective on orbicule formation, as diffusive isotope fractionation should be substantial when growth rates are high, and they are also sensitive to the nature of the growth medium (silicate liquid or supercritical fluid phase). We present δ44Ca measurements and chemistry for a transect of a dioritic orbicule collected from Emerald Lake, California (Sierra Nevada), where the growth layers are defined by variations in plagioclase/pyroxene ratio, grain size, and texture. Ca concentration varies from 5-13 wt%, and d44Ca values oscillate between -0.5 to 0.0‰ relative to BSE, correlating with changes in mineralogy and texture. Zones of plagioclase comb texture are associated with negative δ44Ca excursions of -0.2 to -0.4‰, consistent with diffusive isotope fractionation during rapid mineral growth. Assuming a 10‰ difference in diffusivity for 44Ca vs. 40Ca in dioritic liquids (Watson et al., 2016), and using the models of Watson and Muller (2009) as a guide, these small fractionations

  11. Martian Magmatic-Driven Hydrothermal Sites: Potential Sources of Energy, Water, and Life (United States)

    Anderson, R. C.; Dohm, J. M.; Baker, V. R.; Ferris, J. C.; Hare, T. M.; Tanaka, K. L.; Klemaszewski, J. E.; Skinner, J. A.; Scott, D. H.


    Magmatic-driven processes and impact events dominate the geologic record of Mars. Such recorded geologic activity coupled with significant evidence of past and present-day water/ice, above and below the martian surface, indicate that hydrothermal environments certainly existed in the past and may exist today. The identification of such environments, especially long-lived magmatic-driven hydrothermal environments, provides NASA with significant target sites for future sample return missions, since they (1) could favor the development and sustenance of life, (2) may comprise a large variety of exotic mineral assemblages, and (3) could potentially contain water/ice reservoirs for future Mars-related human activities. If life developed on Mars, the fossil record would presumably be at its greatest concentration and diversity in environments where long-term energy sources and water coexisted such as at sites where long-lived, magmatic-driven hydrothermal activity occurred. These assertions are supported by terrestrial analogs. Small, single-celled creatures (prokaryotes) are vitally important in the evolution of the Earth; these prokaryotes are environmentally tough and tolerant of environmental extremes of pH, temperature, salinity, and anoxic conditions found around hydrothermal vents. In addition, there is a great ability for bacteria to survive long periods of geologic time in extreme conditions, including high temperature hydrogen sulfide and sulfur erupted from Mount St. Helens volcano. Our team of investigators is conducting a geological investigation using multiple mission-derived datasets (e.g., existing geologic map data, MOC imagery, MOLA, TES image data, geophysical data, etc.) to identify prime target sites of hydrothermal activity for future hydrological, mineralogical, and biological investigations. The identification of these sites will enhance the probability of success for future missions to Mars.

  12. Intense magmatic degassing through the lake of Copahue volcano, 2013-2014 (United States)

    Tamburello, G.; Agusto, M.; Caselli, A.; Tassi, F.; Vaselli, O.; Calabrese, S.; Rouwet, D.; Capaccioni, B.; Di Napoli, R.; Cardellini, C.; Chiodini, G.; Bitetto, M.; Brusca, L.; Bellomo, S.; Aiuppa, A.


    Here we report on the first assessment of volatile fluxes from the hyperacid crater lake hosted within the summit crater of Copahue, a very active volcano on the Argentina-Chile border. Our observations were performed using a variety of in situ and remote sensing techniques during field campaigns in March 2013, when the crater hosted an active fumarole field, and in March 2014, when an acidic volcanic lake covered the fumarole field. In the latter campaign, we found that 566 to 1373 t d-1 of SO2 were being emitted from the lake in a plume that appeared largely invisible. This, combined with our derived bulk plume composition, was converted into flux of other volcanic species (H2O ~ 10989 t d-1, CO2 ~ 638 t d-1, HCl ~ 66 t d-1, H2 ~ 3.3 t d-1, and HBr ~ 0.05 t d-1). These levels of degassing, comparable to those seen at many open-vent degassing arc volcanoes, were surprisingly high for a volcano hosting a crater lake. Copahue's unusual degassing regime was also confirmed by the chemical composition of the plume that, although issuing from a hot (65°C) lake, preserves a close-to-magmatic signature. EQ3/6 models of gas-water-rock interaction in the lake were able to match observed compositions and demonstrated that magmatic gases emitted to the atmosphere were virtually unaffected by scrubbing of soluble (S and Cl) species. Finally, the derived large H2O flux (10,988 t d-1) suggested a mechanism in which magmatic gas stripping drove enhanced lake water evaporation, a process likely common to many degassing volcanic lakes worldwide.

  13. Do Hf isotopes in magmatic zircons represent those of their host rocks? (United States)

    Wang, Di; Wang, Xiao-Lei; Cai, Yue; Goldstein, Steven L.; Yang, Tao


    Lu-Hf isotopic system in zircon is a powerful and widely used geochemical tracer in studying petrogenesis of magmatic rocks and crustal evolution, assuming that zircon Hf isotopes can represent initial Hf isotopes of their parental whole rock. However, this assumption may not always be valid. Disequilibrium partial melting of continental crust would preferentially melt out non-zircon minerals with high time-integrated Lu/Hf ratios and generate partial melts with Hf isotope compositions that are more radiogenic than those of its magma source. Dissolution experiments (with hotplate, bomb and sintering procedures) of zircon-bearing samples demonstrate this disequilibrium effect where partial dissolution yielded variable and more radiogenic Hf isotope compositions than fully dissolved samples. A case study from the Neoproterozoic Jiuling batholith in southern China shows that about half of the investigated samples show decoupled Hf isotopes between zircons and the bulk rocks. This decoupling could reflect complex and prolonged magmatic processes, such as crustal assimilation, magma mixing, and disequilibrium melting, which are consistent with the wide temperature spectrum from ∼630 °C to ∼900 °C by Ti-in-zircon thermometer. We suggest that magmatic zircons may only record the Hf isotopic composition of their surrounding melt during crystallization and it is uncertain whether their Hf isotopic compositions can represent the primary Hf isotopic compositions of the bulk magmas. In this regard, using zircon Hf isotopic compositions to trace crustal evolution may be biased since most of these could be originally from disequilibrium partial melts.

  14. Magmatic plumbing system of Kilauea Volcano: Insights from Petrologic and Geochemical Monitoring (United States)

    Garcia, M. O.; Pietruszka, A. J.; Marske, J.; Greene, A.; Lynn, K. J.


    Monitoring the petrology and geochemistry of lavas from active volcanoes in near realtime affords the opportunity to formulate and evaluate models for magma transport, mixing, and storage to help predict eruption scenarios with greater confidence and better understand magmatic plumbing systems (e.g., Poland et al. 2012, Nat. Geosci. 5, 295-300). Continous petrologic and geochemical monitoring of two ongoing eruptions at the summit and east rift zone of Kilauea Volcano on the Island of Hawaii have revealed much about the dynamics of magmatic processes. When the composition of lava shifted to a more MgO-rich composition in April 1983, we predicted that the Puu Oo eruption would not be short-lived. We had no idea it would continue for over 33 years. Subsequent changes in lava composition have highlighted the interplay between mixing pockets of rift-zone stored magma with new mantle-derived magma and the cooling-induced crystal fractionation during brief (usually days) eruption hiatuses. Surprisingly, the mantle derived magma has continued to change in composition including several 10-year cycles in Pb isotope ratios superimposed on a progressive depletion in highly incompatible elements (Greene et al. 2013, G3, doi: 10.1002/ggge.20285). These compositional trends are contrary to those observed for sustained basaltic eruptions on continents and argue for melt extraction from a multi-component source with 1-3 km wide heterogeneities. Compositional zoning within olivine phenocrysts, created by diffusive re-equilibration, also provide insights into magma mixing, storage, and transport at Kilauea. Timescales modeling of Fe-Mg and Ni concentration gradients within Puu Oo olivine indicate that crystals can be stored at magmatic temperatures for months to a few years before eruption (Shea et al. 2015, Geology 43, 935-938). Kilauea's ongoing eruptions continue to provide a dynamic laboratory for positing and testing models for the generation and evolution of basaltic magma.

  15. Porphyry Cu-Au mineralization in the Mirkuh Ali Mirza magmatic complex, NW Iran (United States)

    Maghsoudi, A.; Yazdi, M.; Mehrpartou, M.; Vosoughi, M.; Younesi, S.


    The Mirkuh Ali Mirza Cu-Au porphyry system in East Azerbaijan Province is located on the western part of the Cenozoic Alborz-Azerbaijan volcanic belt. The belt is also an important Cu-Mo-Au metallogenic province in northwestern Iran. The exposed rocks in the study area consist of a volcaniclastic sequence, subvolcanic rocks and intermediate to mafic lava flows of Neogene age. The volcanic rocks show a typical subduction-related magmatic arc geological and geochemical signature, with low concentration of Nb, Ta, and Ti. Mineralization is hosted by Neogene dacitic tuff and porphyritic dacite situated at the intersections of northeast and northwest faults. Field observations, alteration zonation, geochemical haloes and isotopic data of the Mirkuh Ali Mirza magmatic complex show similarities with typical convergent margin Cu-Au porphyry type deposits. The following features confirm the classic model for Cu-Au porphyry systems: (a) close spatial association with high-K calcalkaline to shoshonitic rock related to post-collision extensional setting (b) low grade Cu (0.57%) (c) stockworks as well as disseminated sulfides (c) zonality of the alteration patterns from intense phyllic at the center to outward weak-phyllic, argillic, and propylitic (d) the presence of a pyritic halo (e) accompanied by sheeted veins and low-sulfidation epithermal gold (f) mineralization spatially associated with intersection of structures, (g) genetically related to diorite porphyry stocks at depth (h) geochemical zonation of (Cu ± Au ± Ag ± Bi) → (Cu + Mo ± Bi ± Au ± Pb ± Zn ± As) → (Au + Mo ± Pb ± Zn) → (As + Ag + Sb + Mn + Ba + Pb + Zn + Hg) → Hg from center to outwards (i) The range of sulfur isotopic values is approximately zero (interpreted to have magmatic source) and similar to other subduction-related porphyry Cu deposits.

  16. Magmatic development of the outer Vøring margin from seismic data (United States)

    Breivik, Asbjørn; Faleide, Jan Inge; Mjelde, Rolf; Flueh, Ernst; Murai, Yoshio


    The Vøring Plateau off mid-Norway is a volcanic passive margin, located north of the East Jan Mayen Fracture Zone (EJMFZ). Large volumes of magmatic rocks were emplaced during Early Eocene margin formation. In 2003, an ocean bottom seismometer survey was acquired over the margin. One profile crosses from the Vøring Plateau to the Vøring Spur, a bathymetric high north of the EJMFZ. The P wave data were ray traced into a 2-D crustal velocity model. The velocity structure of the Vøring Spur indicates up to 15 km igneous crustal thickness. Magmatic processes can be estimated by comparing seismic velocity (VP) with igneous thickness (H). This and two other profiles show a positive H-VP correlation at the Vøring Plateau, consistent with elevated mantle temperature at breakup. However, during the first 2 Ma magma production was augmented by a secondary process, possibly small-scale convection. From ˜51.5 Ma excess melting may be caused by elevated mantle temperature alone. Seismic stratigraphy around the Vøring Spur shows that it was created by at least two uplift events, with the main episode close to the Miocene/Pliocene boundary. Low H-VP correlation of the spur is consistent with renewed igneous growth by constant, moderate-degree mantle melting, not related to the breakup magmatism. The admittance function between bathymetry and free-air gravity shows that the high is near local isostatic equilibrium, precluding that compressional flexure at the EJMFZ uplifted the high. We find a proposed Eocene triple junction model for the margin to be inconsistent with observations.

  17. Paleomagnetism of Siberian Trap Intrusions: Implications for the Timing and Intensity of the Magmatic Activity (United States)

    Latyshev, Anton; Veselovskiy, Roman; Mirsayanova, Elina; Ulyahina, Polina


    Large Igneous Provinces (LIPs) are the areas of the exceptional interest due to associated Cu-Ni-Pt deposits, problems of the causal link between volcanic hazards and mass extinctions, and questions about mantle plume dynamics. High-precise U-Pb and 40Ar/39Ar dating determined the duration of the main phase of the most voluminous Siberian Trap province formation as 1-2 Ma (Kamo et al., 2003; Reichow et al., 2008). Recent paleomagnetic investigations demonstrated the predominance of pulsating volcanic activity during LIPs formation (Chenet et al., 2009; Pavlov et al., 2015). We perform the results of detailed paleomagnetic study of intrusive complexes from Tunguska syncline and Angara-Taseeva depression (Siberian Trap province). Our data taken together with the previous paleomagnetic results from trap intrusions revealed two different styles of magmatic activity. In the central part of Tunguska syncline emplacement of was rather even without sharp bursts. Local intrusive events coeval to volcanic eruptions took place within spatially limited areas. In contrast, in the periphery of Tunguska syncline several short and powerful peaks of magmatic activity happened on the background of weak prolonged magmatism. These events resulted in huge Padunsky, Tulunsky and some other sills in the southern part of the Siberian platform. According to our paleomagnetic data, the duration of such pulses did not exceed 10-100 thousand years. Taking into account our paleomagnetic data and recent U-Pb ages for Siberian trap intrusions from (Burgess, Bowring, 2015), it is possible to correlate intrusive complexes with the volcanic section. In particular, formation the largest Tulunsky and Padunsky sills happened right after the termination of the main phase of Permian-Triassic volcanic activity on the Siberian platform. This work was supported by grants RFBR # 16-35-60114 and 15-35-20599 and Ministry of Education and Science of the Russian Federation (grant 14.Z50.31.0017).

  18. Mantle refertilization and magmatism in old orogenic regions: The role of late-orogenic pyroxenites (United States)

    France, Lydéric; Chazot, Gilles; Kornprobst, Jacques; Dallai, Luigi; Vannucci, Riccardo; Grégoire, Michel; Bertrand, Hervé; Boivin, Pierre


    Pyroxenites and garnet pyroxenites are mantle heterogeneities characterized by a lower solidus temperature than the enclosing peridotites; it follows that they are preferentially involved during magma genesis. Constraining their origin, composition, and the interactions they underwent during their subsequent evolution is therefore essential to discuss the sources of magmatism in a given area. Pyroxenites could represent either recycling of crustal rocks in mantle domains or mantle originated rocks (formed either by olivine consuming melt-rock reactions or by crystal fractionation). Petrological and geochemical (major and trace elements, Sr-Nd and O isotopes) features of xenoliths from various occurrences (French Massif-Central, Jordan, Morocco and Cameroon) show that these samples represent cumulates crystallized during melt percolation at mantle conditions. They formed in mantle domains at pressures of 1-2 GPa during post-collisional magmatism (possibly Hercynian for the French Massif-Central, and Panafrican for Morocco, Jordan and Cameroon). The thermal re-equilibration of lithospheric domains, typical of the late orogenic exhumation stages, is also recorded by the samples. Most of the samples display a metasomatic overprint that may be either inherited or likely linked to the recent volcanic activity that occurred in the investigated regions. The crystallization of pyroxenites during late orogenic events has implications for the subsequent evolution of the mantle domains. The presence of large amounts of mantle pyroxenites in old orogenic regions indeed imparts peculiar physical and chemical characteristics to these domains. Among others, the global solidus temperature of the whole lithospheric domain will be lowered; in turn, this implies that old orogenic regions are refertilized zones where magmatic activity would be enhanced.

  19. Surface deformation induced by magmatic processes at Pacaya Volcano, Guatemala revealed by InSAR (United States)

    Wnuk, K.; Wauthier, C.


    Pacaya Volcano, Guatemala is a continuously active, basaltic volcano with an unstable western flank. Despite continuous activity since 1961, a lack of high temporal resolution geodetic surveying has prevented detailed modeling of Pacaya's underlying magmatic plumbing system. A new, temporally dense dataset of Interferometric Synthetic Aperture Radar (InSAR) RADARSAT-2 images, spanning December 2012 to March 2014, show magmatic deformation before and during major eruptions in January and March 2014. Inversion of InSAR surface displacements using simple analytical forward models suggest that three magma bodies are responsible for the observed deformation: (1) a 4 km deep spherical reservoir located northwest of the summit, (2) a 0.4 km deep spherical source located directly west of the summit, and (3) a shallow dike below the summit. Periods of heightened volcanic activity are instigated by magma pulses at depth, resulting in rapid inflation of the edifice. We observe an intrusion cycle at Pacaya that consists of deflation of one or both magma reservoirs followed by dike intrusion. Intrusion volumes are proportional to reservoir volume loss and do not always result in an eruption. Periods of increased activity culminate with larger dike-fed eruptions. Large eruptions are followed by inter-eruptive periods marked by a decrease in crater explosions and a lack of detected deformation. Co-eruptive flank motion appears to have initiated a new stage of volcanic rifting at Pacaya defined by repeated NW-SE oriented dike intrusions. This creates a positive feedback relationship whereby magmatic forcing from eruptive dike intrusions induce flank motion.

  20. Paleomagnetic evidence for counterclockwise rotation of the Dofan magmatic segment, Main Ethiopian Rift (United States)

    Nugsse, Kahsay; Muluneh, Ameha A.; Kidane, Tesfaye


    Twenty-six paleomagnetic sites in basalt and trachyte flows and ignimbrite deposits sampled in the Dofan magmatic segment, Main Ethiopian Rift (MER). From each site, 6 to 8 core samples were collected. The samples were then cut into 200 standard specimens and their Natural Remanent Magnetization (NRM) directions were measured using a JR6A spinner magnetometer. Most specimens were subjected to stepwise alternating field (AF) and at least one specimen per site to thermal (TH) demagnetization. The directional analysis of these individual specimens revealed either one or two components of NRM. Where two components are present, the first is isolated below a temperature of 300 °C or AF field below 20 mT; the second is isolated above those steps and mostly defined straight lines directed towards the origin and are interpreted as the Characteristic Remanent Magnetization (ChRM) acquired during cooling. Rock magnetic experiments on representative specimens indicate that the dominant magnetic minerals are titanium poor titanomagnetite and in few cases titanohematites. The overall mean directions calculated for the 23 sites of Dofan is Dec = 354.1°, Inc. = +11.6° (N = 23, K = 35.1, α95 = 5.2°). When these values are compared with the 1.5 Ma expected mean geomagnetic dipole reference field directions Dec = 1.0°, Inc. = +16.4° (N = 32, K = 105.6, α95 = 2.3°), obtained from African Apparent Polar Wander Path Curve; a difference in declination ΔD = -6.9° ± 4.7° and inclination ΔI = +4.8° ± 5.5° are determined. The declination difference is interpreted as a very slight counterclockwise rotation about vertical axis of the Dofan magmatic segment and the result is consistent with previous paleomagnetic reports and analogue modeling in Fentale magmatic segment.

  1. The McMurdo Dry Valleys Magmatic Laboratory Workshop of 2005 in Antarctica (United States)

    Marsh, B. D.; Simon, A.; Charrier, A. D.; Hersum, T. G.; Eschholz, E.


    In January of 2005, twenty-five petrologists, volcanologists, geochemists, structural geologists, and magma dynamicists spent two weeks studying and discussing the Magmatic Mush Column represented by the 180 Ma Ferrar Dolerites of the McMurdo Dry Valleys, Antarctica. This exceptionally well-exposed system shows a series of massive interconnected sills culminating in a capping of regional flood basalts. The lowermost sill, the Basement Sill, contains a massive ultramafic tongue of large phenocrysts of orthopyroxene (Opx) with subordinate Cpx and much smaller plagioclase. The 3-D distribution of this Opx Tongue serves as a tracer for the filling dynamics and local motion of the magma. Ponding of the Basement Sill has resulted in a small (500 m), but exceedingly diversified and extensively layered ultramafic intrusion, the Dais Intrusion. Because of the relatively rapid cooling time of this body, the Dais textures have been preserved before extensive annealing, which presents the possibility of using these textures to understand those of much larger, slowly cooled bodies. The combination of seeing in detail a wide variety of exceptional field relations depicting layering, sill emplacement mechanics, internal ordering and crystal sorting in the Opx Tongue, dike and fissure distributions, wall rock thermal effects, and many other first order features of central interest to understanding magmatic processes and performing research in real time was a new challenge to all involved. Facilities were set up at McMurdo Station for rock cutting, thin-section making, map making, GIS analysis, petrographic analysis, and computer modeling using existing chemical and physical data on a spectrum of the representative rock types. At any one time half the group was housed in the field in Bull Pass near Wright Valley and the remaining group was shuttled in by helicopter each day. The principal groups were switched about every three days. Areas for daily field-work were decided upon by

  2. Oceanic magmatic evolution during ocean opening under influence of mantle plume (United States)

    Sushchevskaya, Nadezhda; Melanholina, Elena; Belyatsky, Boris; Krymsky, Robert; Migdisova, Natalya


    Petrology, geochemistry and geophysics as well as numerical simulation of spreading processes in plume impact environments on examples of Atlantic Ocean Iceland and the Central Atlantic plumes and Kerguelen plume in the Indian Ocean reveal: - under interaction of large plume and continental landmass the plume can contribute to splitting off individual lithosphere blocks, and their subsequent movement into the emergent ocean. At the same time enriched plume components often have geochemical characteristics of the intact continental lithosphere by early plume exposure. This is typical for trap magmatism in Antarctica, and for magmatism of North and Central Atlantic margins; - in the course of the geodynamic reconstruction under the whole region of the South Atlantic was formed (not in one step) metasomatized enriched sub-oceanic mantle with pyroxenite mantle geochemical characteristics and isotopic composition of enriched HIMU and EM-2 sources. That is typical for most of the islands in the West Antarctic. This mantle through spreading axes jumping involved in different proportions in the melting under the influence of higher-temperature rising asthenospheric lherzolite mantle; - CAP activity was brief enough (200 ± 2 Ma), but Karoo-Maud plume worked for a longer time and continued from 180 to 170 Ma ago in the main phase. Plume impact within Antarctica distributed to the South and to the East, leading to the formation of extended igneous provinces along the Transantarctic Mountains and along the east coast (Queen Maud Land province and Schirmacher Oasis). Moreover, this plume activity may be continued later on, after about 40 million years cessation, as Kerguelen plume within the newly-formed Indian Ocean, significantly affects the nature of the rift magmatism; - a large extended uplift in the eastern part of the Indian Ocean - Southeastern Indian Ridge (SEIR) was formed on the ancient spreading Wharton ridge near active Kerguelen plume. The strongest plume

  3. Geophysical evidence for the crustal variation and distribution of magmatism along the central coast of Mozambique (United States)

    Mueller, Christian Olaf; Jokat, Wilfried


    For our understanding of the timing and geometry of the initial Gondwana break-up, still a consistent image of the crustal composition of the conjugated margins of central Mozambique and Antarctica and the location of their continent-ocean boundaries is missing. In this regard, a main objective is the explanation for the source of the different magnetic signature of the conjugate margins. Based on a revised investigation of wide-angle seismic data along two profiles across the Mozambican margin by means of an amplitude modelling, this study presents the crustal composition across and along the continental margin of central Mozambique. Supported by 2D magnetic modelling, the results are compared to the conjugate margin in Antarctica and allow new conclusions about their joined tectonic evolution. An observed crustal diversity between the north-eastern and south-western parts of the central Mozambican margin, testifies to the complex break-up history of this area. Conspicuous is the equal spatial extent of the HVLCB along the margin of 190-215 km. The onset of oceanic crust at the central Mozambican margin is refined to chron M38n.2n (164.1 Ma). Magnetic modelling supports the presence of reversed polarized SDRs in the continent-ocean transition that were mainly emplaced between 168.5 and 166.8 Ma (M42-M40). Inferred SDRs in the Riiser-Larsen Sea might be emplaced sometime between 166.8 and 164.1 Ma (M39-M38), but got overprinted by normal polarized intrusions of a late stage of rift volcanism, causing the opposite magnetic signature of the conjugate margins. The distribution of the magmatic material along the central coast of Mozambique clearly indicates the eastern extension of the north-eastern branch of the Karoo triple rift along the entire margin. The main magmatic phase affecting this area lasted for at least 12 Myr between 169 and 157 Ma, followed by the cease of the magmatism, perhaps due to the relative southwards motion of the magmatic centre.

  4. Magma sources during Gondwana breakup: chemistry and chronology of Cretaceous magmatism in Westland, New Zealand

    DEFF Research Database (Denmark)

    van der Meer, Quinten Har Adriaan; Waight, Tod Earle; Scott, James M.


    by emplacement of granitoid plutons, the deposition of terrestrial Pororari Group sediments in extensional half-grabens across on- and offshore Westland, and the intrusion of mafic dikes from 90 Ma. These dikes are concentrated in the swarms of the Paparoa and Hohonu Ranges and were intruded prior...... to and simultaneous with volumetrically minor A-type plutonism at 82 Ma. The emplacement of mafic dikes and A-type plutonism at 82 Ma is significant as it coincides with the age of the oldest seafloor in the Tasman Sea, therefore it represents magmatism coincident with the initiation of seafloor spreading which...

  5. Floor-fractured craters on the Moon: an evidence of past intrusive magmatic activity (United States)

    Thorey, C.; Michaut, C.


    Floor-fractured lunar craters (FFC's) are a class of craters modified by post impact mechanisms. They are defined by distinctive shallow, often plate-like or convex floors, wide floor moats and radial, concentric and polygonal floor-fractures, suggesting an endogenous process of modification. Two main mechanisms have been proposed to account for such observations : 1) viscous relaxation and 2) spreading of magmatic intrusions at depth below the crater. Here, we propose to test the case of magmatic intrusions. We develop a model for the dynamics of magma spreading below an elastic crust with a crater-like topography and above a rigid horizontal surface. Results show first that the lithostatic pressure increase at the crater rim prevents the intrusion from spreading horizontally giving rise to intrusion thickening and to an uplift of the crater floor. Second, the deformation of the overlying crust exerts a strong control on the intrusion shape, and hence, on the nature of the crater floor uplift. As the deformation can only occur over a minimum flexural wavelength noted Λ, the intrusion shape shows a bell-shaped geometry for crater radius smaller than 3Λ, or a flat top with smooth edges for crater radius larger than 3Λ. For given crustal elastic properties, the crust flexural wavelength increases with the intrusion depth. Therefore, for a large intrusion depth or small crater size, we observe a convex uplift of the crater floor. On the contrary, for a small intrusion depth or large crater size, the crater floor undergoes a piston-like uplift and a circular moat forms just before the rim. The depth of the moat is controlled by the thickening of the crust at the crater rim. On the contrary to viscous relaxation models, our model is thus able to reproduce most of the features of FFC's, including small-scale features. Spreading of a magmatic intrusion at depth can thus be considered as the main endogenous mechanism at the origin of the deformations observed at FFC

  6. Lithospheric low-velocity zones associated with a magmatic segment of the Tanzanian Rift, East Africa (United States)

    Plasman, M.; Tiberi, C.; Ebinger, C.; Gautier, S.; Albaric, J.; Peyrat, S.; Déverchère, J.; Le Gall, B.; Tarits, P.; Roecker, S.; Wambura, F.; Muzuka, A.; Mulibo, G.; Mtelela, K.; Msabi, M.; Kianji, G.; Hautot, S.; Perrot, J.; Gama, R.


    Rifting in a cratonic lithosphere is strongly controlled by several interacting processes including crust/mantle rheology, magmatism, inherited structure and stress regime. In order to better understand how these physical parameters interact, a 2 yr long seismological experiment has been carried out in the North Tanzanian Divergence (NTD), at the southern tip of the eastern magmatic branch of the East African rift, where the southward-propagating continental rift is at its earliest stage. We analyse teleseismic data from 38 broad-band stations ca. 25 km spaced and present here results from their receiver function (RF) analysis. The crustal thickness and Vp/Vs ratio are retrieved over a ca. 200 × 200 km2 area encompassing the South Kenya magmatic rift, the NTD and the Ngorongoro-Kilimanjaro transverse volcanic chain. Cratonic nature of the lithosphere is clearly evinced through thick (up to ca. 40 km) homogeneous crust beneath the rift shoulders. Where rifting is present, Moho rises up to 27 km depth and the crust is strongly layered with clear velocity contrasts in the RF signal. The Vp/Vs ratio reaches its highest values (ca. 1.9) beneath volcanic edifices location and thinner crust, advocating for melting within the crust. We also clearly identify two major low-velocity zones (LVZs) within the NTD, one in the lower crust and the second in the upper part of the mantle. The first one starts at 15-18 km depth and correlates well with recent tomographic models. This LVZ does not always coexist with high Vp/Vs ratio, pleading for a supplementary source of velocity decrease, such as temperature or composition. At a greater depth of ca. 60 km, a mid-lithospheric discontinuity roughly mimics the step-like and symmetrically outward-dipping geometry of the Moho but with a more slanting direction (NE-SW) compared to the NS rift. By comparison with synthetic RF, we estimate the associated velocity reduction to be 8-9 per cent. We relate this interface to melt ponding

  7. Uranium mineralization associated with late Palaeozoic acid magmatism in northeast Queensland

    International Nuclear Information System (INIS)

    Bain, J.H.C.


    The late Palaeozoic acid igneous petrographic province, covering some 120,000 km 2 in the Cairns-Townsville hinterland, has associated uranium mineralization characterized by various combinations of uranium, fluorine, and molybdenum. Mineralization of this type has been described from other parts of the world, but is best known in the USSR. Information about the Australian deposits and occurrences is very limited, but it is apparent that the mineralization is mainly of hydrothermal origin and genetically related to extensive late Palaeozoic magmatism. A detailed description of the mineralization and the prospect of additional discoveries of uranium deposits of similar and related types in other parts of Australia are discussed. (J.R.)

  8. Extrusive and Intrusive Magmatism Greatly Influence the Tectonic Mode of Earth-Like Planets (United States)

    Lourenco, D.; Tackley, P. J.; Rozel, A.; Ballmer, M.


    Plate tectonics on Earth-like planets is typically modelling using a strongly temperature-dependent visco-plastic rheology. Previous analyses have generally focussed on purely thermal convection. However, we have shown that the influence of compositional heterogeneity in the form of continental or oceanic crust can greatly influence plate tectonics by making it easier (i.e. it occurs at a lower yield stress or friction coefficient). Here we present detailed results on this topic, in particular focussing on the influence of intrusive vs. extrusive magmatism on the tectonic mode.

  9. Radioactivity and decay heat generation in precambrian magmatic rocks (with the South Pamirs as an example)

    International Nuclear Information System (INIS)

    Batyrmurzaev, A.S.; Alibekov, G.I.; Bekieva, A.A.


    The evaluation of the heat generation share in the results of the long-living radioactive elements (RAE) decay in the Earth surface layers is accomplished on the basis of the data on the uranium and thorium concentration in the precambrian magmatic rocks of the South Pamirs. It was supposed by the calculations, that the value of the heat flux, generated by the rocks, is determined mainly by the RAE content in the Earth upper layer crust itself of 10-15 km. It is shown that the radioheat generation share is within the range of 5-10% from the measured values of the geothermal flows [ru

  10. Regional setting and geochronology of the Late Cretaceous Banatitic Magmatic and Metallogenetic Belt (United States)

    Ciobanu, Cristiana L.; Cook, Nigel J.; Stein, Holly


    The 1,500-km-long Banatitic Magmatic and Metallogenetic Belt (BMMB) of Romania, Serbia and Bulgaria is a complex calc-alkaline magmatic arc of Late Cretaceous age. It hosts a variety of magmatic-hydrothermal Cu, Au, Mo, Zn, Pb and Fe deposits, including Europe's only world-class porphyry-copper deposits. Regional metallogeny can be linked to subduction of the Vardar Ocean during the Late Cretaceous, as part of the closure of the Neotethys Ocean that had separated Europe and Africa in the Mesozoic. Porphyry Cu-(Au)-(Mo) and intimately associated epithermal massive sulphides dominate in the central segments of the belt in southernmost Banat (Romania), Serbia and north-west Bulgaria. These districts are the economically most important today, including major active Cu-Au mines at Moldova Nouă in Romania, Majdanpek, Veliki Krivelj and Bor in Serbia, and Elatsite, Assarel and Chelopech in Bulgaria. More numerous (and mostly mined in the past) are Fe, Cu and Zn-Pb skarns, which occur mainly at the two ends of the belt, in Eastern Bulgaria and in Romania. This paper summarises some of the deposit characteristics within the geodynamic framework of terminal Vardar subduction. Heterogeneous terranes of the belt, including the Apuseni Mountains at the western end, are aligned parallel to the Vardar front following continental collision of the Dacia and Tisza blocks. All available geochronological data (numerous K-Ar and some U-Pb and Re-Os ages) are compiled, and are complemented by a new high-precision Re-Os date for the Dognecea skarn deposit, south-west Romania (76.6±0.3 Ma). These data indicate that magmatism extended over at least 25 million years, from about 90 to 65 Ma in each segment of the belt. Within Apuseni Mountains and Banat, where magma emplacement was related to syn-collisional extension in the orogenic belt of Carpathians, ore formation seems to be restricted in time and maybe constrained by a shared tectonic event.

  11. Apatite: A New Tool For Understanding The Temporal Variability Of Magmatic Volatile Contents (United States)

    Stock, M. J.; Humphreys, M.; Smith, V.; Pyle, D. M.; Isaia, R.


    The apatite crystal structure is capable of incorporating H2O, F and Cl, as well as trace CO2 and sulphur. These can be related to parental magma compositions through application of a series of pressure and temperature-dependent exchange reactions (Piccoli and Candela, 1994), permitting apatite crystals to preserve a record of all major volatile species in the melt. Furthermore, due to the general incompatibility of P in other rock-forming minerals, apatite is ubiquitous in igneous systems and often begins crystallising early, such that apatite inclusions within phenocrysts record melt volatile contents throughout magmatic differentiation. In this work, we compare the compositions of apatite inclusions and microphenocrysts with pyroxene-hosted melt inclusions from the Astroni 1 eruption of Campi Flegrei, Italy. These data are coupled with magmatic differentiation models (Gualda et al., 2012), experimental volatile solubility data (Webster et al., 2014) and thermodynamic models of apatite compositional variations (Piccoli and Candela, 1994) to determine a time-series of magmatic volatile evolution in the build-up to eruption. We find that apatite halogen/OH ratios decreased through magmatic differentiation, while melt inclusion F and Cl concentrations increased. Melt inclusion H2O contents are constant at ~2.5 wt%. These data are best explained by volatile-undersaturated differentiation over most of the crystallisation history of the Astroni 1 melt, with melt inclusion H2O contents reset during ascent, due to rapid H diffusion through the phenocryst hosts (Woods et al., 2000). Given the rapid diffusivity of volatiles in apatite (Brenan, 1993), preservation of undersaturated compositions in microphenocrysts suggests that saturation was only achieved a few days to months before eruption and that it may have been the transition into a volatile-saturated state that ultimately triggered eruption. Piccoli and Candela, 1994. Am. J. of Sc., 294, 92-135. Gualda et al., 2012

  12. Fullerol ionic fluids (United States)

    Fernandes, Nikhil; Dallas, Panagiotis; Rodriguez, Robert; Bourlinos, Athanasios B.; Georgakilas, Vasilios; Giannelis, Emmanuel P.


    We report for the first time an ionic fluid based on hydroxylated fullerenes (fullerols). The ionic fluid was synthesized by neutralizing the fully protonated fullerol with an amine terminated polyethylene/polypropylene oxide oligomer (Jeffamine®). The ionic fluid was compared to a control synthesized by mixing the partially protonated form (sodium form) of the fullerols with the same oligomeric amine in the same ratio as in the ionic fluids (20 wt% fullerol). In the fullerol fluid the ionic bonding significantly perturbs the thermal transitions and melting/crystallization behavior of the amine. In contrast, both the normalized heat of fusion and crystallization of the amine in the control are similar to those of the neat amine consistent with a physical mixture of the fullerols/amine with minimal interactions. In addition to differences in thermal behavior, the fullerol ionic fluid exhibits a complex viscoelastic behavior intermediate between the neat Jeffamine® (liquid-like) and the control (solid-like).