A tri-continuous mesoporous material with a silica pore wall following a hexagonal minimal surface

KAUST Repository

Han, Yu; Zhang, Daliang; Chng, Leng Leng; Sun, Junliang; Zhao, L. J.; Zou, Xiaodong; Ying, Jackie

2009-01-01

Ordered porous materials with unique pore structures and pore sizes in the mesoporous range (2-50nm) have many applications in catalysis, separation and drug delivery. Extensive research has resulted in mesoporous materials with one-dimensional, cage-like and bi-continuous pore structures. Three families of bi-continuous mesoporous materials have been made, with two interwoven but unconnected channels, corresponding to the liquid crystal phases used as templates. Here we report a three-dimensional hexagonal mesoporous silica, IBN-9, with a tri-continuous pore structure that is synthesized using a specially designed cationic surfactant template. IBN-9 consists of three identical continuous interpenetrating channels, which are separated by a silica wall that follows a hexagonal minimal surface. Such a tri-continuous mesostructure was predicted mathematically, but until now has not been observed in real materials. © 2009 Macmillan Publishers Limited. All rights reserved.

A barcode of organellar genome polymorphisms identifies the geographic origin of Plasmodium falciparum strains

KAUST Repository

Preston, Mark D.

2014-06-13

Malaria is a major public health problem that is actively being addressed in a global eradication campaign. Increased population mobility through international air travel has elevated the risk of re-introducing parasites to elimination areas and dispersing drug-resistant parasites to new regions. A simple genetic marker that quickly and accurately identifies the geographic origin of infections would be a valuable public health tool for locating the source of imported outbreaks. Here we analyse the mitochondrion and apicoplast genomes of 711 Plasmodium falciparum isolates from 14 countries, and find evidence that they are non-recombining and co-inherited. The high degree of linkage produces a panel of relatively few single-nucleotide polymorphisms (SNPs) that is geographically informative. We design a 23-SNP barcode that is highly predictive (?92%) and easily adapted to aid case management in the field and survey parasite migration worldwide. 2014 Macmillan Publishers Limited. All rights reserved.

Is signal detection theory fundamentally flawed? A response to Balakrishnan (1998a, 1998b, 1999).

Science.gov (United States)

Treisman, Michel

2002-12-01

For nearly 50 years, signal detection theory (SDT; Green & Swvets, 1966; Macmillan & Creelman, 1991) has been of central importance in the development of psychophysics and other areas of psychology. The theory has recently been challenged by Balakrishnan (1998b), who argues that, within SDT, an alternative index is "better justified" than d' and who claims to show (1998a, 1999) that SDT is fundamentally flawed and should be rejected. His evidence is based on new nonparametric measures that he has introduced and applied to experimental data. He believes his results show that basic assumptions of SDT are not supported-in particular, that payoff and probability manipulations do not affect the position of the decision criterion. In view of the importance of SDT in psychology, these claims deserve careful examination. They are critically reviewed here. It appears that it is Balakrishnans arguments that fail, and not SDT

Enantioselective construction of quaternary N-heterocycles by palladium-catalysed decarboxylative allylic alkylation of lactams

KAUST Repository

Behenna, Douglas C.

2011-12-18

The enantioselective synthesis of nitrogen-containing heterocycles (N-heterocycles) represents a substantial chemical research effort and resonates across numerous disciplines, including the total synthesis of natural products and medicinal chemistry. In this Article, we describe the highly enantioselective palladium-catalysed decarboxylative allylic alkylation of readily available lactams to form 3,3-disubstituted pyrrolidinones, piperidinones, caprolactams and structurally related lactams. Given the prevalence of quaternary N-heterocycles in biologically active alkaloids and pharmaceutical agents, we envisage that our method will provide a synthetic entry into the de novo asymmetric synthesis of such structures. As an entry for these investigations we demonstrate how the described catalysis affords enantiopure quaternary lactams that intercept synthetic intermediates previously used in the synthesis of the Aspidosperma alkaloids quebrachamine and rhazinilam, but that were previously only available by chiral auxiliary approaches or as racemic mixtures. © 2012 Macmillan Publishers Limited. All rights reserved.

Sponges with covalently tethered amines for high-efficiency carbon capture

KAUST Repository

Qi, Genggeng

2014-12-12

© 2014 Macmillan Publishers Limited. All rights reserved. Adsorption using solid amine sorbents is an attractive emerging technology for energy-efficient carbon capture. Current syntheses for solid amine sorbents mainly based on physical impregnation or grafting-to methods (for example, aminosilane-grafting) lead to limited sorbent performance in terms of stability and working capacity, respectively. Here we report a family of solid amine sorbents using a grafting-from synthesis approach and synthesized by cationic polymerization of oxazolines on mesoporous silica. The sorbent with high amount of covalently tethered amines shows fast adsorption rate, high amine efficiency and sorbent capacity well exceeding the highest value reported to date for lowerature carbon dioxide sorbents under simulated flue gas conditions. The demonstrated efficiency of the new amine-immobilization chemistry may open up new avenues in the development of advanced carbon dioxide sorbents, as well as other nitrogen-functionalized systems.

Anti-apoptotic effect of hyperglycemia can allow survival of potentially autoreactive T cells.

Science.gov (United States)

Ramakrishnan, P; Kahn, D A; Baltimore, D

2011-04-01

Thymocyte development is a tightly controlled multi-step process involving selective elimination of self-reactive and non-functional T cells by apoptosis. This developmental process depends on signaling by Notch, IL-7 and active glucose metabolism. In this study, we explored the requirement of glucose for thymocyte survival and found that in addition to metabolic regulation, glucose leads to the expression of anti-apoptotic genes. Under hyperglycemic conditions, both mouse and human thymocytes demonstrate enhanced survival. We show that glucose-induced anti-apoptotic genes are dependent on NF-κB p65 because high glucose is unable to attenuate normal ongoing apoptosis of thymocytes isolated from p65 knockout mice. Furthermore, we demonstrate that in vivo hyperglycemia decreases apoptosis of thymocytes allowing for survival of potentially self-reactive thymocytes. These results imply that hyperglycemic conditions could contribute to the development of autoimmunity through dysregulated thymic selection. © 2011 Macmillan Publishers Limited

A barcode of organellar genome polymorphisms identifies the geographic origin of Plasmodium falciparum strains

KAUST Repository

Preston, Mark D.; Campino, Susana; Assefa, Samuel A.; Echeverry, Diego F.; Ocholla, Harold; Amambua-Ngwa, Alfred; Stewart, Lindsay B.; Conway, David J.; Borrmann, Steffen; Michon, Pascal; Zongo, Issaka; Oué draogo, Jean-Bosco; Djimde, Abdoulaye A.; Doumbo, Ogobara K.; Nosten, Francois; Pain, Arnab; Bousema, Teun; Drakeley, Chris J.; Fairhurst, Rick M.; Sutherland, Colin J.; Roper, Cally; Clark, Taane G.

2014-01-01

Malaria is a major public health problem that is actively being addressed in a global eradication campaign. Increased population mobility through international air travel has elevated the risk of re-introducing parasites to elimination areas and dispersing drug-resistant parasites to new regions. A simple genetic marker that quickly and accurately identifies the geographic origin of infections would be a valuable public health tool for locating the source of imported outbreaks. Here we analyse the mitochondrion and apicoplast genomes of 711 Plasmodium falciparum isolates from 14 countries, and find evidence that they are non-recombining and co-inherited. The high degree of linkage produces a panel of relatively few single-nucleotide polymorphisms (SNPs) that is geographically informative. We design a 23-SNP barcode that is highly predictive (?92%) and easily adapted to aid case management in the field and survey parasite migration worldwide. 2014 Macmillan Publishers Limited. All rights reserved.

Behavioural memory reconsolidation of food and fear memories.

Science.gov (United States)

Flavell, Charlotte R; Barber, David J; Lee, Jonathan L C

2011-10-18

The reactivation of a memory through retrieval can render it subject to disruption or modification through the process of memory reconsolidation. In both humans and rodents, briefly reactivating a fear memory results in effective erasure by subsequent extinction training. Here we show that a similar strategy is equally effective in the disruption of appetitive pavlovian cue-food memories. However, systemic administration of the NMDA receptor partial agonist D-cycloserine, under the same behavioural conditions, did not potentiate appetitive memory extinction, suggesting that reactivation does not enhance subsequent extinction learning. To confirm that reactivation followed by extinction reflects a behavioural analogue of memory reconsolidation, we show that prevention of contextual fear memory reactivation by the L-type voltage-gated calcium channel blocker nimodipine interferes with the amnestic outcome. Therefore, the reconsolidation process can be manipulated behaviourally to disrupt both aversive and appetitive memories. © 2011 Macmillan Publishers Limited. All rights reserved.

Energy and Development

Directory of Open Access Journals (Sweden)

Gilles Carbonnier

2012-03-01

Full Text Available Published by Palgrave MacmillanThis chapter introduces the thematic dossier of International Development Policy on the intimate relationship between energy and development. The authors discuss the centrality of fossil fuels in the economic growth of the Western world since the nineteenth century and the key role of oil in the twentieth century and question the future of this development model in the face of geological and climatic constraints. They examine the gaps and misunderstandings that separate social sciences and natural sciences as well as recent attempts to establish interdisciplinary dialogue around ecological economics and industrial ecology. The authors then analyse what is at stake for developing countries, inequalities in access to energy resources, the failure of the global governance system to deal with mounting tensions associated with the depletion of oil and the environmental consequences of an ever increasing consumption of non-renewable resources.

Gravitational redshift of galaxies in clusters as predicted by general relativity.

Science.gov (United States)

Wojtak, Radosław; Hansen, Steen H; Hjorth, Jens

2011-09-28

The theoretical framework of cosmology is mainly defined by gravity, of which general relativity is the current model. Recent tests of general relativity within the Lambda Cold Dark Matter (ΛCDM) model have found a concordance between predictions and the observations of the growth rate and clustering of the cosmic web. General relativity has not hitherto been tested on cosmological scales independently of the assumptions of the ΛCDM model. Here we report an observation of the gravitational redshift of light coming from galaxies in clusters at the 99 per cent confidence level, based on archival data. Our measurement agrees with the predictions of general relativity and its modification created to explain cosmic acceleration without the need for dark energy (the f(R) theory), but is inconsistent with alternative models designed to avoid the presence of dark matter. © 2011 Macmillan Publishers Limited. All rights reserved

Enhanced energy storage in chaotic optical resonators

KAUST Repository

Liu, Changxu; Di Falco, Andrea; Molinari, Diego P.; Khan, Yasser; Ooi, Boon S.; Krauss, Thomas F.; Fratalocchi, Andrea

2013-01-01

Chaos is a phenomenon that occurs in many aspects of contemporary science. In classical dynamics, chaos is defined as a hypersensitivity to initial conditions. The presence of chaos is often unwanted, as it introduces unpredictability, which makes it difficult to predict or explain experimental results. Conversely, we demonstrate here how chaos can be used to enhance the ability of an optical resonator to store energy. We combine analytic theory with ab initio simulations and experiments in photonic-crystal resonators to show that a chaotic resonator can store six times more energy than its classical counterpart of the same volume. We explain the observed increase by considering the equipartition of energy among all degrees of freedom of the chaotic resonator (that is, the cavity modes) and discover a convergence of their lifetimes towards a single value. A compelling illustration of the theory is provided by enhanced absorption in deformed polystyrene microspheres. © 2013 Macmillan Publishers Limited. All rights reserved.

Inorganic hole conductor-based lead halide perovskite solar cells with 12.4% conversion efficiency

KAUST Repository

Qin, Peng

2014-05-12

Organo-lead halide perovskites have attracted much attention for solar cell applications due to their unique optical and electrical properties. With either low-temperature solution processing or vacuum evaporation, the overall conversion efficiencies of perovskite solar cells with organic hole-transporting material were quickly improved to over 15% during the last 2 years. However, the organic hole-transporting materials used are normally quite expensive due to complicated synthetic procedure or high-purity requirement. Here, we demonstrate the application of an effective and cheap inorganic p-type hole-transporting material, copper thiocyanate, on lead halide perovskite-based devices. With low-temperature solution-process deposition method, a power conversion efficiency of 12.4% was achieved under full sun illumination. This work represents a well-defined cell configuration with optimized perovskite morphology by two times of lead iodide deposition, and opens the door for integration of a class of abundant and inexpensive material for photovoltaic application. © 2014 Macmillan Publishers Limited.

Twee afdelings van een fakulteit 1934−1940

Directory of Open Access Journals (Sweden)

J.P. Oberholzer

2010-09-01

Full Text Available Die Universiteit benoem op voordrag van die Nederduitsch Hervormde of Gereformeerde Kerk vir dominee G.M. Pellisier in die pos Godsdienswetenskap wat deur die bedanking van professor Macmillan vakant gelaat is. Dit word die begin van ‘n ontwikkeling van twee feitlik selfstandige afdelings binne die Fakulteit Teologie. Die toetrede van H.P. Wolmarans as vierde dosent vanweë die Nederduitsch Hervormde Kerk bring nuwe teologiese aksente. Die verhouding tussen die Nederduitsch Hervormde Kerk en die Universiteit kry beslag in ‘n skriftelike kontrak. In 1937 word dit gevolg deur ‘n tweede kontrak waarin die ruimte geskep word vir die bestaan van twee fakulteitsafdelings. Vanaf 1938 funksioneer die twee afdelings naas mekaar met gelykluidende kontrakte. Hierdie kroniek volg dan verder die gang van Afdeling A, die afdeling beman deur ampsdraers van die Nederduitsch Hervormde Kerk. Die benoeming as lektore van A. van Selms in 1938 en C.H. Rautenbach in 1939 verhoog die akademiese kwaliteit van die afdeling verder.

Die Departement Godsdiens- en Sendingwetenskap (Afd A, Universiteit van Pretoria, 1917-1978

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P. J. van der Merwe

1992-01-01

Full Text Available The Department of Science of Religion and Missiology (Sec A, University of Pretoria, 1917-1978 The Transvaal University College began its Faculty of Theology in 1917 in co-operation with the Presbyterian Church and the Nederduitsch Hervormde Kerk. A Presbyterian minister, Prof E MacMillan, lectured from 1917 till 1934. This marked the end of Presbyterian participation. In the next period, 1935-1937, the Department suffered from a controversy between the Nederduitsch Hervormde Kerk and its new partner, the Nederduitsch Hervormde of Gereformeerde Kerk. The issue was solved when the Faculty divided into two sections, Section A for the Nederduitsch Hervormde Kerk and Section B for the Nederduitsch Hervormde of G ereformeerde Kerk. Prof H P Wolmarans was appointed to the chair of Science of Religion (Sec A in 1938 and served as head of the Department till 1959. He was succeeded by Prof F J van Zyl in 1960, who served till 1978.

Uma investigação dos sentidos de um phrasal verb por meio dos corpora e dicionários on-line

Directory of Open Access Journals (Sweden)

Emiliana Fernandes Bonalumi

2014-06-01

Full Text Available Nesta pesquisa analisamos o uso do phrasal verbs throw up encontrado em dois corpora on-line originalmente escritos em língua inglesa, a saber: British National Corpus (BNC e Corpus of Contemporary American English (COCA, bem como no livro didático adotado em sala de aula New English File Upper-Intermediate, com o suporte dos dicionários on-line Cambridge Online Dictionary e Macmillan Dictionary. Objetivamos identificar, classificar e generalizar o uso e significados do phrasal verb selecionado para a análise nos respectivos corpora on-line em relação ao seu uso e significado no livro didático anteriormente mencionado. Por meio dos corpora e dicionários on-line, o aluno expandirá seu conhecimento acerca do uso e significados de um determinado phrasal verb, como o analisado nesta investigação. Palavras-chave: linguística de corpus; ensino movido por dados; phrasal verbs.

Multiple reference genomes and transcriptomes for Arabidopsis thaliana

KAUST Repository

Gan, Xiangchao

2011-08-28

Genetic differences between Arabidopsis thaliana accessions underlie the plants extensive phenotypic variation, and until now these have been interpreted largely in the context of the annotated reference accession Col-0. Here we report the sequencing, assembly and annotation of the genomes of 18 natural A. thaliana accessions, and their transcriptomes. When assessed on the basis of the reference annotation, one-third of protein-coding genes are predicted to be disrupted in at least one accession. However, re-annotation of each genome revealed that alternative gene models often restore coding potential. Gene expression in seedlings differed for nearly half of expressed genes and was frequently associated with cis variants within 5 kilobases, as were intron retention alternative splicing events. Sequence and expression variation is most pronounced in genes that respond to the biotic environment. Our data further promote evolutionary and functional studies in A. thaliana, especially the MAGIC genetic reference population descended from these accessions. ©2011 Macmillan Publishers Limited. All rights reserved.

Too close and too rigid: applying the Circumplex Model of Family Systems to first-generation family firms.

Science.gov (United States)

Michael-Tsabari, Nava; Lavee, Yoav

2012-06-01

Despite growing research interest in family businesses, little is known about the characteristics of the families engaging in them. The present paper uses Olson's (Journal of Psychotherapy & the Family, 1988, 4(12), 7-49; Journal of Family Therapy, 2000, 22, 144-167) Circumplex Model of Marital and Family Systems to look at first-generation family firms. We describe existing typologies of family businesses and discuss similarities between the characteristics of first-generation family firms and the rigidly enmeshed family type described in the Circumplex Model. The Steinberg family business (Gibbon & Hadekel (1990) Steinberg: The breakup of a family empire. ON, Canada: MacMillan) serves to illustrate the difficulties of rigidly enmeshed first-generation family firms. Implications for understanding troubled family businesses are discussed together with guidelines for the assessment of a family business in crisis and for intervention: enhancing open communication; allowing for more flexible leadership style, roles, and rules; and maintaining a balance between togetherness and separateness. © 2012 American Association for Marriage and Family Therapy.

Ultra-low carrier concentration and surface-dominant transport in antimony-doped Bi2Se3 topological insulator nanoribbons

KAUST Repository

Hong, Seung Sae; Cha, Judy J.; Kong, Desheng; Cui, Yi

2012-01-01

A topological insulator is the state of quantum matter possessing gapless spin-locking surface states across the bulk band gap, which has created new opportunities from novel electronics to energy conversion. However, the large concentration of bulk residual carriers has been a major challenge for revealing the property of the topological surface state by electron transport measurements. Here we report the surface-state-dominant transport in antimony-doped, zinc oxide-encapsulated Bi2Se3 nanoribbons with suppressed bulk electron concentration. In the nanoribbon with sub-10-nm thickness protected by a zinc oxide layer, we position the Fermi levels of the top and bottom surfaces near the Dirac point by electrostatic gating, achieving extremely low two-dimensional carrier concentration of 2×10 11cm-2. The zinc oxide-capped, antimony-doped Bi 2Se3 nanostructures provide an attractive materials platform to study fundamental physics in topological insulators, as well as future applications. © 2012 Macmillan Publishers Limited. All rights reserved.

Efficient charge generation by relaxed charge-transfer states at organic interfaces

KAUST Repository

Vandewal, Koen

2013-11-17

Interfaces between organic electron-donating (D) and electron-accepting (A) materials have the ability to generate charge carriers on illumination. Efficient organic solar cells require a high yield for this process, combined with a minimum of energy losses. Here, we investigate the role of the lowest energy emissive interfacial charge-transfer state (CT1) in the charge generation process. We measure the quantum yield and the electric field dependence of charge generation on excitation of the charge-transfer (CT) state manifold via weakly allowed, low-energy optical transitions. For a wide range of photovoltaic devices based on polymer:fullerene, small-molecule:C60 and polymer:polymer blends, our study reveals that the internal quantum efficiency (IQE) is essentially independent of whether or not D, A or CT states with an energy higher than that of CT1 are excited. The best materials systems show an IQE higher than 90% without the need for excess electronic or vibrational energy. © 2014 Macmillan Publishers Limited.

Bias-voltage dependence of perpendicular spin-transfer torque in asymmetric MgO-based magnetic tunnel junctions

KAUST Repository

Oh, Se Chung

2009-10-25

Spin-transfer torque (STT) allows the electrical control of magnetic states in nanostructures. The STT in magnetic tunnel junctions (MTJs) is of particular importance owing to its potential for device applications. It has been demonstrated that the MTJ has a sizable perpendicular STT (, field-like torque), which substantially affects STT-driven magnetization dynamics. In contrast to symmetric MTJs where the bias dependence of is quadratic, it is theoretically predicted that the symmetry breaking of the system causes an extra linear bias dependence. Here, we report experimental results that are consistent with the predicted linear bias dependence in asymmetric MTJs. The linear contribution is quite significant and its sign changes from positive to negative as the asymmetry is modified. This result opens a way to design the bias dependence of the field-like term, which is useful for device applications by allowing, in particular, the suppression of the abnormal switching-back phenomena. © 2009 Macmillan Publishers Limited. All rights reserved.

Photocurrent mapping of near-field optical antenna resonances

KAUST Repository

Barnard, Edward S.; Pala, Ragip A.; Brongersma, Mark L.

2011-01-01

An increasing number of photonics applications make use of nanoscale optical antennas that exhibit a strong, resonant interaction with photons of a specific frequency. The resonant properties of such antennas are conventionally characterized by far-field light-scattering techniques. However, many applications require quantitative knowledge of the near-field behaviour, and existing local field measurement techniques provide only relative, rather than absolute, data. Here, we demonstrate a photodetector platform that uses a silicon-on-insulator substrate to spectrally and spatially map the absolute values of enhanced fields near any type of optical antenna by transducing local electric fields into photocurrent. We are able to quantify the resonant optical and materials properties of nanoscale (∼50nm) and wavelength-scale (∼1μm) metallic antennas as well as high-refractive-index semiconductor antennas. The data agree well with light-scattering measurements, full-field simulations and intuitive resonator models. © 2011 Macmillan Publishers Limited. All rights reserved.

Determination of nanoparticle size distribution together with density or molecular weight by 2D analytical ultracentrifugation

KAUST Repository

Carney, Randy P.; Kim, Jin Young; Qian, Huifeng; Jin, Rongchao; Mehenni, Hakim; Stellacci, Francesco; Bakr, Osman

2011-01-01

Nanoparticles are finding many research and industrial applications, yet their characterization remains a challenge. Their cores are often polydisperse and coated by a stabilizing shell that varies in size and composition. No single technique can characterize both the size distribution and the nature of the shell. Advances in analytical ultracentrifugation allow for the extraction of the sedimentation (s) and diffusion coefficients (D). Here we report an approach to transform the s and D distributions of nanoparticles in solution into precise molecular weight (M), density (?P) and particle diameter (dp) distributions. M for mixtures of discrete nanocrystals is found within 4% of the known quantities. The accuracy and the density information we achieve on nanoparticles are unparalleled. A single experimental run is sufficient for full nanoparticle characterization, without the need for standards or other auxiliary measurements. We believe that our method is of general applicability and we discuss its limitations. 2011 Macmillan Publishers Limited. All rights reserved.

Biomimetic block copolymer particles with gated nanopores and ultrahigh protein sorption capacity

KAUST Repository

Yu, Haizhou

2014-06-17

The design of micro-or nanoparticles that can encapsulate sensitive molecules such as drugs, hormones, proteins or peptides is of increasing importance for applications in biotechnology and medicine. Examples are micelles, liposomes and vesicles. The tiny and, in most cases, hollow spheres are used as vehicles for transport and controlled administration of pharmaceutical drugs or nutrients. Here we report a simple strategy to fabricate microspheres by block copolymer self-assembly. The microsphere particles have monodispersed nanopores that can act as pH-responsive gates. They contain a highly porous internal structure, which is analogous to the Schwarz P structure. The internal porosity of the particles contributes to their high sorption capacity and sustained release behaviour. We successfully separated similarly sized proteins using these particles. The ease of particle fabrication by macrophase separation and self-assembly, and the robustness of the particles makes them ideal for sorption, separation, transport and sustained delivery of pharmaceutical substances. © 2014 Macmillan Publishers Limited.

Caring for independent lives: geographies of caring for young adults with intellectual disabilities.

Science.gov (United States)

Power, Andrew

2008-09-01

This paper engages with the emerging disciplinary clash between 'care' and 'independence' within disability studies by examining the geography of home care for young adults with intellectual disabilities. The care system as a whole is viewed as central to disablist structures within disability studies (see Thomas, C. (2007). Sociologies of disability and illness: Contested ideas in disability studies and medical sociology. Hampshire: Palgrave Macmillan.). However, despite the theorisation of dependency as being in antipathy to the goals of the disability movement, caregiving at home still continues to dominate community care. The paper attempts to address how family carers are 'caught-in-the-middle' between their 'duty' to care and at the same time, perpetuating dependency; the reality being that parents have to deal with issues of being overprotective and confronting various social assumptions about disability. It examines the narratives from 25 family caregivers in Ireland who provide personal assistance to young adults with intellectual disabilities.

On the form of ROCs constructed from confidence ratings.

Science.gov (United States)

Malmberg, Kenneth J

2002-03-01

A classical question for memory researchers is whether memories vary in an all-or-nothing, discrete manner (e.g., stored vs. not stored, recalled vs. not recalled), or whether they vary along a continuous dimension (e.g., strength, similarity, or familiarity). For yes-no classification tasks, continuous- and discrete-state models predict nonlinear and linear receiver operating characteristics (ROCs), respectively (D. M. Green & J. A. Swets, 1966; N. A. Macmillan & C. D. Creelman, 1991). Recently, several authors have assumed that these predictions are generalizable to confidence ratings tasks (J. Qin, C. L. Raye, M. K. Johnson, & K. J. Mitchell, 2001; S. D. Slotnick, S. A. Klein, C. S. Dodson, & A. P. Shimamura, 2000, and A. P. Yonelinas, 1999). This assumption is shown to be unwarranted by showing that discrete-state ratings models predict both linear and nonlinear ROCs. The critical factor determining the form of the discrete-state ROC is the response strategy adopted by the classifier.

A high-rate and long cycle life aqueous electrolyte battery for grid-scale energy storage

KAUST Repository

Pasta, Mauro; Wessells, Colin D.; Huggins, Robert A.; Cui, Yi

2012-01-01

New types of energy storage are needed in conjunction with the deployment of solar, wind and other volatile renewable energy sources and their integration with the electric grid. No existing energy storage technology can economically provide the power, cycle life and energy efficiency needed to respond to the costly short-term transients that arise from renewables and other aspects of grid operation. Here we demonstrate a new type of safe, fast, inexpensive, long-life aqueous electrolyte battery, which relies on the insertion of potassium ions into a copper hexacyanoferrate cathode and a novel activated carbon/polypyrrole hybrid anode. The cathode reacts rapidly with very little hysteresis. The hybrid anode uses an electrochemically active additive to tune its potential. This high-rate, high-efficiency cell has a 95% round-trip energy efficiency when cycled at a 5C rate, and a 79% energy efficiency at 50C. It also has zero-capacity loss after 1,000 deep-discharge cycles. © 2012 Macmillan Publishers Limited. All rights reserved.

Bias-voltage dependence of perpendicular spin-transfer torque in asymmetric MgO-based magnetic tunnel junctions

KAUST Repository

Oh, Se Chung; Park, Seung Young; Manchon, Aurelien; Chshiev, Mairbek; Han, Jae Ho; Lee, Hyun Woo; Lee, Jang Eun; Nam, Kyung Tae; Jo, Younghun; Kong, Yo Chan; Dieny, Bernard; Lee, Kyung Jin

2009-01-01

Spin-transfer torque (STT) allows the electrical control of magnetic states in nanostructures. The STT in magnetic tunnel junctions (MTJs) is of particular importance owing to its potential for device applications. It has been demonstrated that the MTJ has a sizable perpendicular STT (, field-like torque), which substantially affects STT-driven magnetization dynamics. In contrast to symmetric MTJs where the bias dependence of is quadratic, it is theoretically predicted that the symmetry breaking of the system causes an extra linear bias dependence. Here, we report experimental results that are consistent with the predicted linear bias dependence in asymmetric MTJs. The linear contribution is quite significant and its sign changes from positive to negative as the asymmetry is modified. This result opens a way to design the bias dependence of the field-like term, which is useful for device applications by allowing, in particular, the suppression of the abnormal switching-back phenomena. © 2009 Macmillan Publishers Limited. All rights reserved.

Tandem colloidal quantum dot solar cells employing a graded recombination layer

KAUST Repository

Wang, Xihua; Koleilat, Ghada I.; Tang, Jiang; Liu, Huan; Kramer, Illan J.; Debnath, Ratan; Brzozowski, Lukasz; Barkhouse, D. Aaron R.; Levina, Larissa; Hoogland, Sjoerd; Sargent, Edward H.

2011-01-01

Tuning of the electronic bandgap in colloidal quantum dots (CQDs) by changing their size enables the spectral response of CQD-based photodetectors and photovoltaic devices to be tailored. Multi-junction solar cells made from a combination of CQDs of differing sizes and thus bandgaps are a promising means by which to increase the energy harvested from the Sun's broad spectrum. Here, we report the first CQD tandem solar cells using the size-effect tuning of a single CQD material, PbS. We use a graded recombination layer to provide a progression of work functions from the hole-accepting electrode in the bottom cell to the electron-accepting electrode in the top cell, allowing matched electron and hole currents to meet and recombine. Our tandem solar cell has an open-circuit voltage of 1.06Â V, equal to the sum of the two constituent single-junction devices, and a solar power conversion efficiency of up to 4.2%. © 2011 Macmillan Publishers Limited. All rights reserved.

Tuning upconversion through energy migration in core-shell nanoparticles

KAUST Repository

Wang, Feng; Deng, Renren; Wang, Juan; Wang, Qingxiao; Han, Yu; Zhu, Haomiao; Chen, Xueyuan; Liu, Xiaogang

2011-01-01

Photon upconversion is promising for applications such as biological imaging, data storage or solar cells. Here, we have investigated upconversion processes in a broad range of gadolinium-based nanoparticles of varying composition. We show that by rational design of a core-shell structure with a set of lanthanide ions incorporated into separated layers at precisely defined concentrations, efficient upconversion emission can be realized through gadolinium sublattice-mediated energy migration for a wide range of lanthanide activators without long-lived intermediary energy states. Furthermore, the use of the core-shell structure allows the elimination of deleterious cross-relaxation. This effect enables fine-tuning of upconversion emission through trapping of the migrating energy by the activators. Indeed, the findings described here suggest a general approach to constructing a new class of luminescent materials with tunable upconversion emissions by controlled manipulation of energy transfer within a nanoscopic region. © 2011 Macmillan Publishers Limited. All rights reserved.

Pay to Preserve: The Global Politics of Ecuador’s Yasuní-ITT Proposal

Directory of Open Access Journals (Sweden)

Pamela L. Martin

2011-05-01

Full Text Available Published by Palgrave MacmillanThe case to leave nearly 900 million barrels of oil underground in Ecuador’s Amazonian Yasuní National Park demonstrates the significance of transnational networks in the institutionalisation of alternative norms for global environmental governance. Through complex local and global networks, the Yasuní Fund, governed with UNDP, has created a potential model of replication for other developing, megadiverse countries that are trapped in the petro-curse and yet seek solutions contributing towards sustainable development and social justice. What makes the Yasuní-ITT initiative unique is its call to protect the environment and the indigenous societies that live within it by paying for avoided carbon emissions. Such a plan unites global climate change goals for a post-Kyoto solution that involves the South with Ecuador’s constitutional and normative base of living in harmony with nature, sumak kawsay in Quichua (el buen vivir in Spanish or ‘the good life’.

One-dimensional self-confinement promotes polymorph selection in large-area organic semiconductor thin films

KAUST Repository

Giri, Gaurav; Li, Ruipeng; Smilgies, Detlef Matthias; Li, Erqiang; Diao, Ying; Lenn, Kristina M.; Chiu, Melanie; Lin, Debora W.; Allen, Ranulfo A.; Reinspach, Julia A.; Mannsfeld, Stefan C B; Thoroddsen, Sigurdur T; Clancy, Paulette; Bao, Zhenan; Amassian, Aram

2014-01-01

A crystal's structure has significant impact on its resulting biological, physical, optical and electronic properties. In organic electronics, 6,13(bis-triisopropylsilylethynyl)pentacene (TIPS-pentacene), a small-molecule organic semiconductor, adopts metastable polymorphs possessing significantly faster charge transport than the equilibrium crystal when deposited using the solution-shearing method. Here, we use a combination of high-speed polarized optical microscopy, in situ microbeam grazing incidence wide-angle X-ray-scattering and molecular simulations to understand the mechanism behind formation of metastable TIPS-pentacene polymorphs. We observe that thin-film crystallization occurs first at the air-solution interface, and nanoscale vertical spatial confinement of the solution results in formation of metastable polymorphs, a one-dimensional and large-area analogy to crystallization of polymorphs in nanoporous matrices. We demonstrate that metastable polymorphism can be tuned with unprecedented control and produced over large areas by either varying physical confinement conditions or by tuning energetic conditions during crystallization through use of solvent molecules of various sizes. © 2014 Macmillan Publishers Limited.

Receiver operating characteristic analysis and its potential role in evaluating the effect of head movement in PET of the brain

International Nuclear Information System (INIS)

Patterson, H.; Clarke, G.H.; Lombardo, P.; McKay, W.J.; Austin and Repatriation Medical Centre, Heidelberg, VIC

1999-01-01

Full text: We outline an example of receiver operating characteristic (ROC) analysis in the assessment of image quality. ROC analysis is a measure of image quality that accounts for the consequences of the decision and the role of the observer. Kim and Haynie (Nuclear Diagnostic Imaging: Practical Clinical Applications. Melbourne: Macmillan, 1987) describe ROC analysis as an 'objective approach to the evaluation of diagnostic decision making'. ROC analysis is an ideal technique for evaluating images of a Hoffman brain phantom obtained using positron emission tomography. Images have been acquired with the phantom in different positions. The position of the phantom and the time the phantom remained in each position was based on the measurements of head movement during simulated brain imaging (Patterson et al., Technologists Symposium, ANZSNM, 1998). This study was undertaken to explore the potential of ROC analysis in determining the effect of movement on the ability to detect lesions of various sizes

Copper hexacyanoferrate battery electrodes with long cycle life and high power

KAUST Repository

Wessells, Colin D.; Huggins, Robert A.; Cui, Yi

2011-01-01

Short-term transients, including those related to wind and solar sources, present challenges to the electrical grid. Stationary energy storage systems that can operate for many cycles, at high power, with high round-trip energy efficiency, and at low cost are required. Existing energy storage technologies cannot satisfy these requirements. Here we show that crystalline nanoparticles of copper hexacyanoferrate, which has an ultra-low strain open framework structure, can be operated as a battery electrode in inexpensive aqueous electrolytes. After 40,000 deep discharge cycles at a 17g-C rate, 83% of the original capacity of copper hexacyanoferrate is retained. Even at a very high cycling rate of 83g-C, two thirds of its maximum discharge capacity is observed. At modest current densities, round-trip energy efficiencies of 99% can be achieved. The low-cost, scalable, room-temperature co-precipitation synthesis and excellent electrode performance of copper hexacyanoferrate make it attractive for large-scale energy storage systems. © 2011 Macmillan Publishers Limited. All rights reserved.

Tuning upconversion through energy migration in core-shell nanoparticles

KAUST Repository

Wang, Feng

2011-10-23

Photon upconversion is promising for applications such as biological imaging, data storage or solar cells. Here, we have investigated upconversion processes in a broad range of gadolinium-based nanoparticles of varying composition. We show that by rational design of a core-shell structure with a set of lanthanide ions incorporated into separated layers at precisely defined concentrations, efficient upconversion emission can be realized through gadolinium sublattice-mediated energy migration for a wide range of lanthanide activators without long-lived intermediary energy states. Furthermore, the use of the core-shell structure allows the elimination of deleterious cross-relaxation. This effect enables fine-tuning of upconversion emission through trapping of the migrating energy by the activators. Indeed, the findings described here suggest a general approach to constructing a new class of luminescent materials with tunable upconversion emissions by controlled manipulation of energy transfer within a nanoscopic region. © 2011 Macmillan Publishers Limited. All rights reserved.

Self-limited plasmonic welding of silver nanowire junctions

KAUST Repository

Garnett, Erik C.

2012-02-05

Nanoscience provides many strategies to construct high-performance materials and devices, including solar cells, thermoelectrics, sensors, transistors, and transparent electrodes. Bottom-up fabrication facilitates large-scale chemical synthesis without the need for patterning and etching processes that waste material and create surface defects. However, assembly and contacting procedures still require further development. Here, we demonstrate a light-induced plasmonic nanowelding technique to assemble metallic nanowires into large interconnected networks. The small gaps that form naturally at nanowire junctions enable effective light concentration and heating at the point where the wires need to be joined together. The extreme sensitivity of the heating efficiency on the junction geometry causes the welding process to self-limit when a physical connection between the wires is made. The localized nature of the heating prevents damage to low-thermal-budget substrates such as plastics and polymer solar cells. This work opens new avenues to control light, heat and mass transport at the nanoscale. © 2012 Macmillan Publishers Limited. All rights reserved.

Photocurrent mapping of near-field optical antenna resonances

KAUST Repository

Barnard, Edward S.

2011-08-21

An increasing number of photonics applications make use of nanoscale optical antennas that exhibit a strong, resonant interaction with photons of a specific frequency. The resonant properties of such antennas are conventionally characterized by far-field light-scattering techniques. However, many applications require quantitative knowledge of the near-field behaviour, and existing local field measurement techniques provide only relative, rather than absolute, data. Here, we demonstrate a photodetector platform that uses a silicon-on-insulator substrate to spectrally and spatially map the absolute values of enhanced fields near any type of optical antenna by transducing local electric fields into photocurrent. We are able to quantify the resonant optical and materials properties of nanoscale (∼50nm) and wavelength-scale (∼1μm) metallic antennas as well as high-refractive-index semiconductor antennas. The data agree well with light-scattering measurements, full-field simulations and intuitive resonator models. © 2011 Macmillan Publishers Limited. All rights reserved.

Creativity for people in vulnerable life situations: Emerging understandings

DEFF Research Database (Denmark)

Hansen, Bodil Winther; la Cour, Karen; Pedersen, Helle Andrea

From an occupational science perspective human life and existence takes place though the doing of activity such creative activity. According to Schmid creativity involves “the capacity to think and act in original ways, to be inventive, to be imagina¬tive and to find new and original solutions.......J Occup Sci 20. 2004;11(2):51-7. 21. Dickie VA, Frank G.Artisan occupations in the global economy: a conceptual framework.J Occup Sci 1996;3(2):45-55. 22. Sundt EL.Om husfliden i Norge.København: Gyldendal; 1975. 23. Dewey J.Experience and education.New York, NY: The Macmillan Company; 1938. 24. Wenger E...... transplant patient experiences participating in art making and music listening.Eur J Oncol Nurs 2016;22:71-7. 28. la Cour K, Josephsson S, Tishelman C et al.Experiences of engagement in cre¬ative activity at a palliative care 29. facility.Palliat Support Care 2007;5(3):241-50. 30. la Cour K, Johannessen H...

Successful partnerships with third sector organisations to enhance the healthcare student experience: a partnership evaluation.

Science.gov (United States)

Bell, Katie; Tanner, Judith; Rutty, Jane; Astley-Pepper, Maxine; Hall, Richard

2015-03-01

There is limited research surrounding academic partnerships and more research is needed to educate universities, and the private, public and third sectors about the benefits and limitations of such partnerships. The aim of this study was to outline the unique partnership between Macmillan Cancer Support and De Montfort University and to evaluate the progress of this partnership. A qualitative approach was employed which involved interviews with nine members of the partnership's steering group. Interviews were transcribed and analysed using thematic analysis. The results showed that a partnership between a university and a third sector charity can have mutual benefits for all those involved, particularly for students and those affected by cancer. Furthermore, the module to develop volunteering among families affected cancer, created through this partnership is now being considered by other universities as a way of providing holistic and non-traditional lecture based learning experiences. Recommendations are made for future partnerships between third sector charities and universities. Copyright © 2014 Elsevier Ltd. All rights reserved.

A high-rate and long cycle life aqueous electrolyte battery for grid-scale energy storage

KAUST Repository

Pasta, Mauro

2012-10-23

New types of energy storage are needed in conjunction with the deployment of solar, wind and other volatile renewable energy sources and their integration with the electric grid. No existing energy storage technology can economically provide the power, cycle life and energy efficiency needed to respond to the costly short-term transients that arise from renewables and other aspects of grid operation. Here we demonstrate a new type of safe, fast, inexpensive, long-life aqueous electrolyte battery, which relies on the insertion of potassium ions into a copper hexacyanoferrate cathode and a novel activated carbon/polypyrrole hybrid anode. The cathode reacts rapidly with very little hysteresis. The hybrid anode uses an electrochemically active additive to tune its potential. This high-rate, high-efficiency cell has a 95% round-trip energy efficiency when cycled at a 5C rate, and a 79% energy efficiency at 50C. It also has zero-capacity loss after 1,000 deep-discharge cycles. © 2012 Macmillan Publishers Limited. All rights reserved.

Efficient charge generation by relaxed charge-transfer states at organic interfaces

KAUST Repository

Vandewal, Koen; Albrecht, Steve N.; Hoke, Eric T.; Graham, Kenneth; Widmer, Johannes; Douglas, Jessica D.; Schubert, Marcel; Mateker, William R.; Bloking, Jason T.; Burkhard, George F.; Sellinger, Alan; Frechet, Jean; Amassian, Aram; Riede, Moritz Kilian; McGehee, Michael D.; Neher, Dieter; Salleo, Alberto

2013-01-01

Interfaces between organic electron-donating (D) and electron-accepting (A) materials have the ability to generate charge carriers on illumination. Efficient organic solar cells require a high yield for this process, combined with a minimum of energy losses. Here, we investigate the role of the lowest energy emissive interfacial charge-transfer state (CT1) in the charge generation process. We measure the quantum yield and the electric field dependence of charge generation on excitation of the charge-transfer (CT) state manifold via weakly allowed, low-energy optical transitions. For a wide range of photovoltaic devices based on polymer:fullerene, small-molecule:C60 and polymer:polymer blends, our study reveals that the internal quantum efficiency (IQE) is essentially independent of whether or not D, A or CT states with an energy higher than that of CT1 are excited. The best materials systems show an IQE higher than 90% without the need for excess electronic or vibrational energy. © 2014 Macmillan Publishers Limited.

Direct observation of ultrafast long-range charge separation at polymer–fullerene heterojunctions

KAUST Repository

Provencher, Franç oise; Bé rubé , Nicolas; Parker, Anthony W.; Greetham, Gregory M.; Towrie, Michael; Hellmann, Christoph; Cô té , Michel; Stingelin, Natalie; Silva, Carlos; Hayes, Sophia C.

2014-01-01

In polymeric semiconductors, charge carriers are polarons, which means that the excess charge deforms the molecular structure of the polymer chain that hosts it. This results in distinctive signatures in the vibrational modes of the polymer. Here, we probe polaron photogeneration dynamics at polymer:fullerene heterojunctions by monitoring its time-resolved resonance-Raman spectrum following ultrafast photoexcitation. We conclude that polarons emerge within 300 fs. Surprisingly, further structural evolution on ≤50-ps timescales is modest, indicating that the polymer conformation hosting nascent polarons is not significantly different from that near equilibrium. We interpret this as suggestive that charges are free from their mutual Coulomb potential because we would expect rich vibrational dynamics associated with charge-pair relaxation. We address current debates on the photocarrier generation mechanism at molecular heterojunctions, and our work is, to our knowledge, the first direct probe of molecular conformation dynamics during this fundamentally important process in these materials. © 2014 Macmillan Publishers Limited. All rights reserved.

A High-Resolution LC-MS-Based Secondary Metabolite Fingerprint Database of Marine Bacteria

KAUST Repository

Lu, Liang

2014-10-09

© 2014 Macmillan Publishers Limited. All rights reserved. Marine bacteria are the most widely distributed organisms in the ocean environment and produce a wide variety of secondary metabolites. However, traditional screening for bioactive natural compounds is greatly hindered by the lack of a systematic way of cataloguing the chemical profiles of bacterial strains found in nature. Here we present a chemical fingerprint database of marine bacteria based on their secondary metabolite profiles, acquired by high-resolution LC-MS. Till now, 1,430 bacterial strains spanning 168 known species collected from different marine environments were cultured and profiled. Using this database, we demonstrated that secondary metabolite profile similarity is approximately, but not always, correlated with taxonomical similarity. We also validated the ability of this database to find species-specific metabolites, as well as to discover known bioactive compounds from previously unknown sources. An online interface to this database, as well as the accompanying software, is provided freely for the community to use.

A general relationship between disorder, aggregation and charge transport in conjugated polymers

KAUST Repository

Noriega, Rodrigo; Rivnay, Jonathan; Vandewal, Koen; Koch, Felix P. V.; Stingelin, Natalie; Smith, Paul; Toney, Michael F.; Salleo, Alberto

2013-01-01

Conjugated polymer chains have many degrees of conformational freedom and interact weakly with each other, resulting in complex microstructures in the solid state. Understanding charge transport in such systems, which have amorphous and ordered phases exhibiting varying degrees of order, has proved difficult owing to the contribution of electronic processes at various length scales. The growing technological appeal of these semiconductors makes such fundamental knowledge extremely important for materials and process design. We propose a unified model of how charge carriers travel in conjugated polymer films. We show that in high-molecular-weight semiconducting polymers the limiting charge transport step is trapping caused by lattice disorder, and that short-range intermolecular aggregation is sufficient for efficient long-range charge transport. This generalization explains the seemingly contradicting high performance of recently reported, poorly ordered polymers and suggests molecular design strategies to further improve the performance of future generations of organic electronic materials. © 2013 Macmillan Publishers Limited. All rights reserved.

Enhanced energy storage in chaotic optical resonators

KAUST Repository

Liu, Changxu

2013-05-05

Chaos is a phenomenon that occurs in many aspects of contemporary science. In classical dynamics, chaos is defined as a hypersensitivity to initial conditions. The presence of chaos is often unwanted, as it introduces unpredictability, which makes it difficult to predict or explain experimental results. Conversely, we demonstrate here how chaos can be used to enhance the ability of an optical resonator to store energy. We combine analytic theory with ab initio simulations and experiments in photonic-crystal resonators to show that a chaotic resonator can store six times more energy than its classical counterpart of the same volume. We explain the observed increase by considering the equipartition of energy among all degrees of freedom of the chaotic resonator (that is, the cavity modes) and discover a convergence of their lifetimes towards a single value. A compelling illustration of the theory is provided by enhanced absorption in deformed polystyrene microspheres. © 2013 Macmillan Publishers Limited. All rights reserved.

Determination of nanoparticle size distribution together with density or molecular weight by 2D analytical ultracentrifugation

KAUST Repository

Carney, Randy P.

2011-06-07

Nanoparticles are finding many research and industrial applications, yet their characterization remains a challenge. Their cores are often polydisperse and coated by a stabilizing shell that varies in size and composition. No single technique can characterize both the size distribution and the nature of the shell. Advances in analytical ultracentrifugation allow for the extraction of the sedimentation (s) and diffusion coefficients (D). Here we report an approach to transform the s and D distributions of nanoparticles in solution into precise molecular weight (M), density (?P) and particle diameter (dp) distributions. M for mixtures of discrete nanocrystals is found within 4% of the known quantities. The accuracy and the density information we achieve on nanoparticles are unparalleled. A single experimental run is sufficient for full nanoparticle characterization, without the need for standards or other auxiliary measurements. We believe that our method is of general applicability and we discuss its limitations. 2011 Macmillan Publishers Limited. All rights reserved.

A general relationship between disorder, aggregation and charge transport in conjugated polymers

KAUST Repository

Noriega, Rodrigo

2013-08-04

Conjugated polymer chains have many degrees of conformational freedom and interact weakly with each other, resulting in complex microstructures in the solid state. Understanding charge transport in such systems, which have amorphous and ordered phases exhibiting varying degrees of order, has proved difficult owing to the contribution of electronic processes at various length scales. The growing technological appeal of these semiconductors makes such fundamental knowledge extremely important for materials and process design. We propose a unified model of how charge carriers travel in conjugated polymer films. We show that in high-molecular-weight semiconducting polymers the limiting charge transport step is trapping caused by lattice disorder, and that short-range intermolecular aggregation is sufficient for efficient long-range charge transport. This generalization explains the seemingly contradicting high performance of recently reported, poorly ordered polymers and suggests molecular design strategies to further improve the performance of future generations of organic electronic materials. © 2013 Macmillan Publishers Limited. All rights reserved.

Extreme diving behaviour in devil rays links surface waters and the deep ocean

KAUST Repository

Thorrold, Simon R.

2014-07-01

Ecological connections between surface waters and the deep ocean remain poorly studied despite the high biomass of fishes and squids residing at depths beyond the euphotic zone. These animals likely support pelagic food webs containing a suite of predators that include commercially important fishes and marine mammals. Here we deploy pop-up satellite archival transmitting tags on 15 Chilean devil rays (Mobula tarapacana) in the central North Atlantic Ocean, which provide movement patterns of individuals for up to 9 months. Devil rays were considered surface dwellers but our data reveal individuals descending at speeds up to 6.0 ms-1 to depths of almost 2,000 m and water temperatures <4 C. The shape of the dive profiles suggests that the rays are foraging at these depths in deep scattering layers. Our results provide evidence of an important link between predators in the surface ocean and forage species occupying pelagic habitats below the euphotic zone in ocean ecosystems. 2014 Macmillan Publishers Limited. All rights reserved.

A robust SNP barcode for typing Mycobacterium tuberculosis complex strains

KAUST Repository

Coll, Francesc

2014-09-01

Strain-specific genomic diversity in the Mycobacterium tuberculosis complex (MTBC) is an important factor in pathogenesis that may affect virulence, transmissibility, host response and emergence of drug resistance. Several systems have been proposed to classify MTBC strains into distinct lineages and families. Here, we investigate single-nucleotide polymorphisms (SNPs) as robust (stable) markers of genetic variation for phylogenetic analysis. We identify ∼92k SNP across a global collection of 1,601 genomes. The SNP-based phylogeny is consistent with the gold-standard regions of difference (RD) classification system. Of the ∼7k strain-specific SNPs identified, 62 markers are proposed to discriminate known circulating strains. This SNP-based barcode is the first to cover all main lineages, and classifies a greater number of sublineages than current alternatives. It may be used to classify clinical isolates to evaluate tools to control the disease, including therapeutics and vaccines whose effectiveness may vary by strain type. © 2014 Macmillan Publishers Limited.

Cobalt phosphate-modified barium-doped tantalum nitride nanorod photoanode with 1.5% solar energy conversion efficiency

KAUST Repository

Li, Yanbo

2013-10-03

Spurred by the decreased availability of fossil fuels and global warming, the idea of converting solar energy into clean fuels has been widely recognized. Hydrogen produced by photoelectrochemical water splitting using sunlight could provide a carbon dioxide lean fuel as an alternative to fossil fuels. A major challenge in photoelectrochemical water splitting is to develop an efficient photoanode that can stably oxidize water into oxygen. Here we report an efficient and stable photoanode that couples an active barium-doped tantalum nitride nanostructure with a stable cobalt phosphate co-catalyst. The effect of barium doping on the photoelectrochemical activity of the photoanode is investigated. The photoanode yields a maximum solar energy conversion efficiency of 1.5%, which is more than three times higher than that of state-of-the-art single-photon photoanodes. Further, stoichiometric oxygen and hydrogen are stably produced on the photoanode and the counter electrode with Faraday efficiency of almost unity for 100 min. © 2013 Macmillan Publishers Limited. All rights reserved.

Copper hexacyanoferrate battery electrodes with long cycle life and high power

KAUST Repository

Wessells, Colin D.

2011-11-22

Short-term transients, including those related to wind and solar sources, present challenges to the electrical grid. Stationary energy storage systems that can operate for many cycles, at high power, with high round-trip energy efficiency, and at low cost are required. Existing energy storage technologies cannot satisfy these requirements. Here we show that crystalline nanoparticles of copper hexacyanoferrate, which has an ultra-low strain open framework structure, can be operated as a battery electrode in inexpensive aqueous electrolytes. After 40,000 deep discharge cycles at a 17g-C rate, 83% of the original capacity of copper hexacyanoferrate is retained. Even at a very high cycling rate of 83g-C, two thirds of its maximum discharge capacity is observed. At modest current densities, round-trip energy efficiencies of 99% can be achieved. The low-cost, scalable, room-temperature co-precipitation synthesis and excellent electrode performance of copper hexacyanoferrate make it attractive for large-scale energy storage systems. © 2011 Macmillan Publishers Limited. All rights reserved.

Ultra-low carrier concentration and surface-dominant transport in antimony-doped Bi2Se3 topological insulator nanoribbons

KAUST Repository

Hong, Seung Sae

2012-03-27

A topological insulator is the state of quantum matter possessing gapless spin-locking surface states across the bulk band gap, which has created new opportunities from novel electronics to energy conversion. However, the large concentration of bulk residual carriers has been a major challenge for revealing the property of the topological surface state by electron transport measurements. Here we report the surface-state-dominant transport in antimony-doped, zinc oxide-encapsulated Bi2Se3 nanoribbons with suppressed bulk electron concentration. In the nanoribbon with sub-10-nm thickness protected by a zinc oxide layer, we position the Fermi levels of the top and bottom surfaces near the Dirac point by electrostatic gating, achieving extremely low two-dimensional carrier concentration of 2×10 11cm-2. The zinc oxide-capped, antimony-doped Bi 2Se3 nanostructures provide an attractive materials platform to study fundamental physics in topological insulators, as well as future applications. © 2012 Macmillan Publishers Limited. All rights reserved.

Pedro Zamora and Pedro and Me in Requiem: Scoring the Loss

Directory of Open Access Journals (Sweden)

A. David Lewis

2015-09-01

Full Text Available When originally published at the turn of the century, 'Pedro and Me: Friendship, Loss, and What I Learned' (2000 was riding both the popularity of its reality television roots ''and the growing awareness of homosexuality in the popular consciousness. At that time, too, Macmillan publisher Henry Holt had its own website set up to support Winick’s work; it featured interviews, tour dates, and, most importantly, omitted scenes originally drafted but not completed by the author. The opportunity to finally include this apocrypha was missed in the newer 2009 addition, as the publisher opted for a one-page afterword.  This paper discusses how this constitutes a missed opportunity to reconnect with Pedro. In as much as the original graphic novel—or 'any' graphic novel—is a construction, the tenth anniversary edition of 'Pedro and Me' disallowed the excluded raw material from being included in audience’s score-overdue deconstruction of the work.

Tandem colloidal quantum dot solar cells employing a graded recombination layer

KAUST Repository

Wang, Xihua

2011-06-26

Tuning of the electronic bandgap in colloidal quantum dots (CQDs) by changing their size enables the spectral response of CQD-based photodetectors and photovoltaic devices to be tailored. Multi-junction solar cells made from a combination of CQDs of differing sizes and thus bandgaps are a promising means by which to increase the energy harvested from the Sun\\'s broad spectrum. Here, we report the first CQD tandem solar cells using the size-effect tuning of a single CQD material, PbS. We use a graded recombination layer to provide a progression of work functions from the hole-accepting electrode in the bottom cell to the electron-accepting electrode in the top cell, allowing matched electron and hole currents to meet and recombine. Our tandem solar cell has an open-circuit voltage of 1.06Â V, equal to the sum of the two constituent single-junction devices, and a solar power conversion efficiency of up to 4.2%. © 2011 Macmillan Publishers Limited. All rights reserved.

Soil clay content underlies prion infection odds

Science.gov (United States)

David, Walter W.; Walsh, D.P.; Farnsworth, Matthew L.; Winkelman, D.L.; Miller, M.W.

2011-01-01

Environmental factors-especially soil properties-have been suggested as potentially important in the transmission of infectious prion diseases. Because binding to montmorillonite (an aluminosilicate clay mineral) or clay-enriched soils had been shown to enhance experimental prion transmissibility, we hypothesized that prion transmission among mule deer might also be enhanced in ranges with relatively high soil clay content. In this study, we report apparent influences of soil clay content on the odds of prion infection in free-ranging deer. Analysis of data from prion-infected deer herds in northern Colorado, USA, revealed that a 1% increase in the clay-sized particle content in soils within the approximate home range of an individual deer increased its odds of infection by up to 8.9%. Our findings suggest that soil clay content and related environmental properties deserve greater attention in assessing risks of prion disease outbreaks and prospects for their control in both natural and production settings. ?? 2011 Macmillan Publishers Limited. All rights reserved.

Direct observation of ultrafast long-range charge separation at polymer–fullerene heterojunctions

KAUST Repository

Provencher, Françoise

2014-07-01

In polymeric semiconductors, charge carriers are polarons, which means that the excess charge deforms the molecular structure of the polymer chain that hosts it. This results in distinctive signatures in the vibrational modes of the polymer. Here, we probe polaron photogeneration dynamics at polymer:fullerene heterojunctions by monitoring its time-resolved resonance-Raman spectrum following ultrafast photoexcitation. We conclude that polarons emerge within 300 fs. Surprisingly, further structural evolution on ≤50-ps timescales is modest, indicating that the polymer conformation hosting nascent polarons is not significantly different from that near equilibrium. We interpret this as suggestive that charges are free from their mutual Coulomb potential because we would expect rich vibrational dynamics associated with charge-pair relaxation. We address current debates on the photocarrier generation mechanism at molecular heterojunctions, and our work is, to our knowledge, the first direct probe of molecular conformation dynamics during this fundamentally important process in these materials. © 2014 Macmillan Publishers Limited. All rights reserved.

La empresa familiar en México. Situación actual de la investigación

Directory of Open Access Journals (Sweden)

Argentina Soto Maciel

2013-01-01

Full Text Available La empresa familiar forma parte fundamental de las estructuras productivas tanto de las economías industrializadas como en vías de desarrollo. A pesar de carecer de datos rigurosos que permitan corroborarlo, la empresa familiar tiene un papel preponderante en la generación de riqueza nacional, aunque con frecuencia se trata de estructuras productivas poco conocidas. En el mundo, la investigación sobre la empresa familiar es relativamente reciente; así, en este trabajo se trata de reconstruir el estado en que se encuentra la investigación realizada en México. El interés de reunir este material es el de ofrecer una mayor visibilidad a los trabajos que han sido realizados y, con ello, fomentar su desarrollo temático entre los interesados. Los resultados de este trabajo están influidos por los de Chua et al. (1999, Low y MacMillan (1988 y Sharma (2004.

Inorganic hole conductor-based lead halide perovskite solar cells with 12.4% conversion efficiency

KAUST Repository

Qin, Peng; Tanaka, Soichiro; Ito, Seigo; Tetreault, Nicolas; Manabe, Kyohei; Nishino, Hitoshi; Nazeeruddin, Mohammad Khaja; Grä tzel, Michael

2014-01-01

Organo-lead halide perovskites have attracted much attention for solar cell applications due to their unique optical and electrical properties. With either low-temperature solution processing or vacuum evaporation, the overall conversion efficiencies of perovskite solar cells with organic hole-transporting material were quickly improved to over 15% during the last 2 years. However, the organic hole-transporting materials used are normally quite expensive due to complicated synthetic procedure or high-purity requirement. Here, we demonstrate the application of an effective and cheap inorganic p-type hole-transporting material, copper thiocyanate, on lead halide perovskite-based devices. With low-temperature solution-process deposition method, a power conversion efficiency of 12.4% was achieved under full sun illumination. This work represents a well-defined cell configuration with optimized perovskite morphology by two times of lead iodide deposition, and opens the door for integration of a class of abundant and inexpensive material for photovoltaic application. © 2014 Macmillan Publishers Limited.

The optimum decision rules for the oddity task.

Science.gov (United States)

Versfeld, N J; Dai, H; Green, D M

1996-01-01

This paper presents the optimum decision rule for an m-interval oddity task in which m-1 intervals contain the same signal and one is different or odd. The optimum decision rule depends on the degree of correlation among observations. The present approach unifies the different strategies that occur with "roved" or "fixed" experiments (Macmillan & Creelman, 1991, p. 147). It is shown that the commonly used decision rule for an m-interval oddity task corresponds to the special case of highly correlated observations. However, as is also true for the same-different paradigm, there exists a different optimum decision rule when the observations are independent. The relation between the probability of a correct response and d' is derived for the three-interval oddity task. Tables are presented of this relation for the three-, four-, and five-interval oddity task. Finally, an experimental method is proposed that allows one to determine the decision rule used by the observer in an oddity experiment.

Multiple reference genomes and transcriptomes for Arabidopsis thaliana

KAUST Repository

Gan, Xiangchao; Stegle, Oliver; Behr, Jonas; Steffen, Joshua G.; Drewe, Philipp; Hildebrand, Katie L.; Lyngsoe, Rune; Schultheiss, Sebastian J.; Osborne, Edward J.; Sreedharan, Vipin T.; Kahles, André ; Bohnert, Regina; Jean, Gé raldine; Derwent, Paul; Kersey, Paul; Belfield, Eric J.; Harberd, Nicholas P.; Kemen, Eric; Toomajian, Christopher; Kover, Paula X.; Clark, Richard M.; Rä tsch, Gunnar; Mott, Richard

2011-01-01

Genetic differences between Arabidopsis thaliana accessions underlie the plants extensive phenotypic variation, and until now these have been interpreted largely in the context of the annotated reference accession Col-0. Here we report the sequencing, assembly and annotation of the genomes of 18 natural A. thaliana accessions, and their transcriptomes. When assessed on the basis of the reference annotation, one-third of protein-coding genes are predicted to be disrupted in at least one accession. However, re-annotation of each genome revealed that alternative gene models often restore coding potential. Gene expression in seedlings differed for nearly half of expressed genes and was frequently associated with cis variants within 5 kilobases, as were intron retention alternative splicing events. Sequence and expression variation is most pronounced in genes that respond to the biotic environment. Our data further promote evolutionary and functional studies in A. thaliana, especially the MAGIC genetic reference population descended from these accessions. ©2011 Macmillan Publishers Limited. All rights reserved.

Made-to-order metal-organic frameworks for trace carbon dioxide removal and air capture

KAUST Repository

Shekhah, Osama

2014-06-25

Direct air capture is regarded as a plausible alternate approach that, if economically practical, can mitigate the increasing carbon dioxide emissions associated with two of the main carbon polluting sources, namely stationary power plants and transportation. Here we show that metal-organic framework crystal chemistry permits the construction of an isostructural metal-organic framework (SIFSIX-3-Cu) based on pyrazine/copper(II) two-dimensional periodic 4 4 square grids pillared by silicon hexafluoride anions and thus allows further contraction of the pore system to 3.5 versus 3.84 for the parent zinc(II) derivative. This enhances the adsorption energetics and subsequently displays carbon dioxide uptake and selectivity at very low partial pressures relevant to air capture and trace carbon dioxide removal. The resultant SIFSIX-3-Cu exhibits uniformly distributed adsorption energetics and offers enhanced carbon dioxide physical adsorption properties, uptake and selectivity in highly diluted gas streams, a performance, to the best of our knowledge, unachievable with other classes of porous materials. 2014 Macmillan Publishers Limited.

Charge-extraction strategies for colloidal quantum dot photovoltaics

KAUST Repository

Lan, Xinzheng

2014-02-20

The solar-power conversion efficiencies of colloidal quantum dot solar cells have advanced from sub-1% reported in 2005 to a record value of 8.5% in 2013. Much focus has deservedly been placed on densifying, passivating and crosslinking the colloidal quantum dot solid. Here we review progress in improving charge extraction, achieved by engineering the composition and structure of the electrode materials that contact the colloidal quantum dot film. New classes of structured electrodes have been developed and integrated to form bulk heterojunction devices that enhance photocharge extraction. Control over band offsets, doping and interfacial trap state densities have been essential for achieving improved electrical communication with colloidal quantum dot solids. Quantum junction devices that not only tune the optical absorption spectrum, but also provide inherently matched bands across the interface between p-and n-materials, have proven that charge separation can occur efficiently across an all-quantum-tuned rectifying junction. © 2014 Macmillan Publishers Limited.

Colloidal-quantum-dot photovoltaics using atomic-ligand passivation

KAUST Repository

Tang, Jiang

2011-09-18

Colloidal-quantum-dot (CQD) optoelectronics offer a compelling combination of solution processing and spectral tunability through quantum size effects. So far, CQD solar cells have relied on the use of organic ligands to passivate the surface of the semiconductor nanoparticles. Although inorganic metal chalcogenide ligands have led to record electronic transport parameters in CQD films, no photovoltaic device has been reported based on such compounds. Here we establish an atomic ligand strategy that makes use of monovalent halide anions to enhance electronic transport and successfully passivate surface defects in PbS CQD films. Both time-resolved infrared spectroscopy and transient device characterization indicate that the scheme leads to a shallower trap state distribution than the best organic ligands. Solar cells fabricated following this strategy show up to 6% solar AM1.5G power-conversion efficiency. The CQD films are deposited at room temperature and under ambient atmosphere, rendering the process amenable to low-cost, roll-by-roll fabrication. © 2011 Macmillan Publishers Limited. All rights reserved.

A High-Resolution LC-MS-Based Secondary Metabolite Fingerprint Database of Marine Bacteria

KAUST Repository

Lu, Liang; Wang, Jijie; Xu, Ying; Wang, Kailing; Hu, Yingwei; Tian, Renmao; Yang, Bo; Lai, Qiliang; Li, Yongxin; Zhang, Weipeng; Shao, Zongze; Lam, Henry; Qian, Pei-Yuan

2014-01-01

© 2014 Macmillan Publishers Limited. All rights reserved. Marine bacteria are the most widely distributed organisms in the ocean environment and produce a wide variety of secondary metabolites. However, traditional screening for bioactive natural compounds is greatly hindered by the lack of a systematic way of cataloguing the chemical profiles of bacterial strains found in nature. Here we present a chemical fingerprint database of marine bacteria based on their secondary metabolite profiles, acquired by high-resolution LC-MS. Till now, 1,430 bacterial strains spanning 168 known species collected from different marine environments were cultured and profiled. Using this database, we demonstrated that secondary metabolite profile similarity is approximately, but not always, correlated with taxonomical similarity. We also validated the ability of this database to find species-specific metabolites, as well as to discover known bioactive compounds from previously unknown sources. An online interface to this database, as well as the accompanying software, is provided freely for the community to use.

BOOK REVIEW: Cătălina Neculai, URBAN SPACE AND LATE TWENTIETH-CENTURY NEW YORK LITERATURE. REFORMED GEOGRAPHIES, New York: Palgrave, Macmillan

Directory of Open Access Journals (Sweden)

Ruxanda BONTILĂ

2014-12-01

Full Text Available Very much like a number of New York writers, who, back in the 1970s and 1980s, dared to tread where the sociologist, the urban geographer, or the documenter treads by professional default, and to engage head-on with the hard city of socioeconomic networks (p. 60, Catalina Neculai, through her seminal book, trespasses new territories for the philologist who she is, and in the process, she manages to make a powerful statement—namely, that written culture, just like visual arts, can telescope urban change. One must only know how to read the signs.

Biodegradation of oil refinery wastes under OPA and CERCLA

International Nuclear Information System (INIS)

Banipal, B.S.; Myers, J.M.; Fisher, C.W.

1995-01-01

Land treatment of oil refinery wastes has been used as a disposal method for decades. More recently, numerous laboratory studies have been performed attempting to quantify degradation rates of more toxic polycyclic aromatic hydrocarbon compounds (PAHs). This paper discusses the results of the full-scale aerobic biodegradation operations using land treatment at the Macmillan Ring-Free Oil refining facility. The tiered feasibility approach in the evaluation of using biodegradation as a treatment method to achieve site-specific clean-up including pilot scale biodegradation operations is included in an earlier paper. Analytical results of biodegradation indicate that degradation rates observed in the laboratory can be met and exceeded under field conditions and that the site-specific cleanup criteria can be attained within a proposed project time. Also presented are degradation rates and half-lives for PAHs for which cleanup criteria has been established. PAH degradation rates and half-life values are determined and compared with the laboratory degradation rates and half-life values which used similar oil refinery wastes by other investigators (API 1987)

The future prospects for the protection of human rights in South Africa*

Directory of Open Access Journals (Sweden)

J. D. van der Vyver

1977-03-01

Full Text Available It must by now be obvious to every intelligence, I presume, hat the winds of change which have been sweeping across the continent of Africa over the last two decades, are presently also raging south of the Limpopo. Ever since Mr Harold Macmillan, the then prime minister of the United Kingdom, in his historic address of 3 February 1960 to the South African parliament, directed our attention to the political significance of the prevail­ ing tide of national consciousness of the African peoples, the while man in Africa has felt the increasing chill of the side- elïects of those winds so accurately predicted by him. Not only have we seen our western allies turning their backs on the White regime of South Africa, but on the domestic scene we have also experienced the murmurs of the African breeze and the unrest and even violence which signified an impatient urge on the part of the less privileged sections of the South African population for a better deal in what is their fatherland too.

Enhanced single-photon emission from a diamond–silver aperture

KAUST Repository

Choy, Jennifer T.

2011-10-09

Solid-state quantum emitters, such as the nitrogen-vacancy centre in diamond, are robust systems for practical realizations of various quantum information processing protocols2-5 and nanoscale magnetometry schemes6,7 at room temperature. Such applications benefit from the high emission efficiency and flux of single photons, which can be achieved by engineering the electromagnetic environment of the emitter. One attractive approach is based on plasmonic resonators8-13, in which sub-wavelength confinement of optical fields can strongly modify the spontaneous emission of a suitably embedded dipole despite having only modest quality factors. Meanwhile, the scalability of solid-state quantum systems critically depends on the ability to control such emitterg-cavity interaction in a number of devices arranged in parallel. Here, we demonstrate a method to enhance the radiative emission rate of single nitrogen-vacancy centres in ordered arrays of plasmonic apertures that promises greater scalability over the previously demonstrated bottom-up approaches for the realization of on-chip quantum networks. © 2011 Macmillan Publishers Limited. All rights reserved.

Transcription factor PIF4 controls the thermosensory activation of flowering

KAUST Repository

Kumar, S. Vinod; Lucyshyn, Doris; Jaeger, Katja E.; Aló s, Enriqueta; Alvey, Elizabeth; Harberd, Nicholas P.; Wigge, Philip A.

2012-01-01

Plant growth and development are strongly affected by small differences in temperature. Current climate change has already altered global plant phenology and distribution, and projected increases in temperature pose a significant challenge to agriculture. Despite the important role of temperature on plant development, the underlying pathways are unknown. It has previously been shown that thermal acceleration of flowering is dependent on the florigen, FLOWERING LOCUS T (FT). How this occurs is, however, not understood, because the major pathway known to upregulate FT, the photoperiod pathway, is not required for thermal acceleration of flowering. Here we demonstrate a direct mechanism by which increasing temperature causes the bHLH transcription factor PHYTOCHROME INTERACTING FACTOR4 (PIF4) to activate FT. Our findings provide a new understanding of how plants control their timing of reproduction in response to temperature. Flowering time is an important trait in crops as well as affecting the life cycles of pollinator species. A molecular understanding of how temperature affects flowering will be important for mitigating the effects of climate change. © 2012 Macmillan Publishers Limited. All rights reserved.

Mesophase behaviour of polyhedral particles

KAUST Repository

Agarwal, Umang; Escobedo, Fernando A.

2011-01-01

Translational and orientational excluded-volume fields encoded in particles with anisotropic shapes can lead to purely entropy-driven assembly of morphologies with specific order and symmetry. To elucidate this complex correlation, we carried out detailed Monte Carlo simulations of six convex space-filling polyhedrons, namely, truncated octahedrons, rhombic dodecahedrons, hexagonal prisms, cubes, gyrobifastigiums and triangular prisms. Simulations predict the formation of various new liquid-crystalline and plastic-crystalline phases at intermediate volume fractions. By correlating these findings with particle anisotropy and rotational symmetry, simple guidelines for predicting phase behaviour of polyhedral particles are proposed: high rotational symmetry is in general conducive to mesophase formation, with low anisotropy favouring plastic-solid behaviour and intermediate anisotropy (or high uniaxial anisotropy) favouring liquid-crystalline behaviour. It is also found that dynamical disorder is crucial in defining mesophase behaviour, and that the apparent kinetic barrier for the liquid-mesophase transition is much lower for liquid crystals (orientational order) than for plastic solids (translational order). © 2011 Macmillan Publishers Limited. All rights reserved.

Enhanced single-photon emission from a diamond–silver aperture

KAUST Repository

Choy, Jennifer T.; Hausmann, Birgit J. M.; Babinec, Thomas M.; Bulu, Irfan; Khan, Mughees; Maletinsky, Patrick; Yacoby, Amir; Lončar, Marko

2011-01-01

Solid-state quantum emitters, such as the nitrogen-vacancy centre in diamond, are robust systems for practical realizations of various quantum information processing protocols2-5 and nanoscale magnetometry schemes6,7 at room temperature. Such applications benefit from the high emission efficiency and flux of single photons, which can be achieved by engineering the electromagnetic environment of the emitter. One attractive approach is based on plasmonic resonators8-13, in which sub-wavelength confinement of optical fields can strongly modify the spontaneous emission of a suitably embedded dipole despite having only modest quality factors. Meanwhile, the scalability of solid-state quantum systems critically depends on the ability to control such emitterg-cavity interaction in a number of devices arranged in parallel. Here, we demonstrate a method to enhance the radiative emission rate of single nitrogen-vacancy centres in ordered arrays of plasmonic apertures that promises greater scalability over the previously demonstrated bottom-up approaches for the realization of on-chip quantum networks. © 2011 Macmillan Publishers Limited. All rights reserved.

Engineering colloidal quantum dot solids within and beyond the mobility-invariant regime

KAUST Repository

Zhitomirsky, David

2014-05-06

© 2014 Macmillan Publishers Limited. Colloidal quantum dots are attractive materials for efficient, low-cost and facile implementation of solution-processed optoelectronic devices. Despite impressive mobilities (1-30 cm2V-1 s-1) reported for new classes of quantum dot solids, it is-surprisingly-the much lower-mobility (10-3-10-2 cm2V-1 s-1) solids that have produced the best photovoltaic performance. Here we show that it is not mobility, but instead the average spacing among recombination centres that governs the diffusion length of charges in today\\'s quantum dot solids. In this regime, colloidal quantum dot films do not benefit from further improvements in charge carrier mobility. We develop a device model that accurately predicts the thickness dependence and diffusion length dependence of devices. Direct diffusion length measurements suggest the solid-state ligand exchange procedure as a potential origin of the detrimental recombination centres. We then present a novel avenue for in-solution passivation with tightly bound chlorothiols that retain passivation from solution to film, achieving an 8.5% power conversion efficiency.

Replisome speed determines the efficiency of the Tus−Ter replication termination barrier

KAUST Repository

Elshenawy, Mohamed; Jergic, Slobodan; Xu, Zhi Qiang; Sobhy, Mohamed Abdelmaboud; Takahashi, Masateru; Oakley, Aaron J.; Dixon, Nicholas E.; Hamdan, Samir

2015-01-01

In all domains of life, DNA synthesis occurs bidirectionally from replication origins. Despite variable rates of replication fork progression, fork convergence often occurs at specific sites. Escherichia coli sets a 'replication fork trap' that allows the first arriving fork to enter but not to leave the terminus region. The trap is set by oppositely oriented Tus-bound Ter sites that block forks on approach from only one direction. However, the efficiency of fork blockage by Tus-Ter does not exceed 50% in vivo despite its apparent ability to almost permanently arrest replication forks in vitro. Here we use data from single-molecule DNA replication assays and structural studies to show that both polarity and fork-arrest efficiency are determined by a competition between rates of Tus displacement and rearrangement of Tus-Ter interactions that leads to blockage of slower moving replisomes by two distinct mechanisms. To our knowledge this is the first example where intrinsic differences in rates of individual replisomes have different biological outcomes. ©2015 Macmillan Publishers Limited. All rights reserved.

Selective contacts drive charge extraction in quantum dot solids via asymmetry in carrier transfer kinetics

KAUST Repository

Mora-Sero, Ivan; Bertoluzzi, Luca; Gonzalez-Pedro, Victoria; Gimenez, Sixto; Fabregat-Santiago, Francisco; Kemp, Kyle W.; Sargent, Edward H.; Bisquert, Juan

2013-01-01

Colloidal quantum dot solar cells achieve spectrally selective optical absorption in a thin layer of solution-processed, size-effect tuned, nanoparticles. The best devices built to date have relied heavily on drift-based transport due to the action of an electric field in a depletion region that extends throughout the thickness of the quantum dot layer. Here we study for the first time the behaviour of the best-performing class of colloidal quantum dot films in the absence of an electric field, by screening using an electrolyte. We find that the action of selective contacts on photovoltage sign and amplitude can be retained, implying that the contacts operate by kinetic preferences of charge transfer for either electrons or holes. We develop a theoretical model to explain these experimental findings. The work is the first to present a switch in the photovoltage in colloidal quantum dot solar cells by purposefully formed selective contacts, opening the way to new strategies in the engineering of colloidal quantum dot solar cells. © 2013 Macmillan Publishers Limited. All rights reserved.

Replisome speed determines the efficiency of the Tus−Ter replication termination barrier

KAUST Repository

Elshenawy, Mohamed

2015-08-31

In all domains of life, DNA synthesis occurs bidirectionally from replication origins. Despite variable rates of replication fork progression, fork convergence often occurs at specific sites. Escherichia coli sets a \\'replication fork trap\\' that allows the first arriving fork to enter but not to leave the terminus region. The trap is set by oppositely oriented Tus-bound Ter sites that block forks on approach from only one direction. However, the efficiency of fork blockage by Tus-Ter does not exceed 50% in vivo despite its apparent ability to almost permanently arrest replication forks in vitro. Here we use data from single-molecule DNA replication assays and structural studies to show that both polarity and fork-arrest efficiency are determined by a competition between rates of Tus displacement and rearrangement of Tus-Ter interactions that leads to blockage of slower moving replisomes by two distinct mechanisms. To our knowledge this is the first example where intrinsic differences in rates of individual replisomes have different biological outcomes. ©2015 Macmillan Publishers Limited. All rights reserved.

Metamaterial mirrors in optoelectronic devices

KAUST Repository

Esfandyarpour, Majid; Garnett, Erik C.; Cui, Yi; McGehee, Michael D.; Brongersma, Mark L.

2014-01-01

The phase reversal that occurs when light is reflected from a metallic mirror produces a standing wave with reduced intensity near the reflective surface. This effect is highly undesirable in optoelectronic devices that use metal films as both electrical contacts and optical mirrors, because it dictates a minimum spacing between the metal and the underlying active semiconductor layers, therefore posing a fundamental limit to the overall thickness of the device. Here, we show that this challenge can be circumvented by using a metamaterial mirror whose reflection phase is tunable from that of a perfect electric mirror († = €) to that of a perfect magnetic mirror († = 0). This tunability in reflection phase can also be exploited to optimize the standing wave profile in planar devices to maximize light-matter interaction. Specifically, we show that light absorption and photocurrent generation in a sub-100 nm active semiconductor layer of a model solar cell can be enhanced by ∼20% over a broad spectral band. © 2014 Macmillan Publishers Limited.

Genesis of a bad idea

Science.gov (United States)

Carlowicz, Michael

According to an article in Business Week (June 10), Macmillan/McGraw-Hill Inc. has agreed to custom-publish a version of its fourth-grade textbook Changing Earth in order to omit a chapter entitled “Birth of Earth.” Parents in the Cobb County, Georgia, school district complained that since the chapter does not include creationism as a theory for the origin of the universe and of Earth, the entire discussion ought to be left out.According to McGraw-Hill, customizing its textbooks is good business. Changing Earth and other such books are designed to allow teachers to build their own programs; the company is willing to customize texts because it does not want to dictate curricula, and it tries to meet demands of school districts. Business Week noted that the theory of evolution still is taught in the sixth and eighth grades, as well as high school, in Cobb County. Changing Earth also contains references to evolution in other chapters besides the one being deleted.

Radically enhanced molecular recognition

KAUST Repository

Trabolsi, Ali

2009-12-17

The tendency for viologen radical cations to dimerize has been harnessed to establish a recognition motif based on their ability to form extremely strong inclusion complexes with cyclobis(paraquat-p-phenylene) in its diradical dicationic redox state. This previously unreported complex involving three bipyridinium cation radicals increases the versatility of host-guest chemistry, extending its practice beyond the traditional reliance on neutral and charged guests and hosts. In particular, transporting the concept of radical dimerization into the field of mechanically interlocked molecules introduces a higher level of control within molecular switches and machines. Herein, we report that bistable and tristable [2]rotaxanes can be switched by altering electrochemical potentials. In a tristable [2]rotaxane composed of a cyclobis(paraquat-p-phenylene) ring and a dumbbell with tetrathiafulvalene, dioxynaphthalene and bipyridinium recognition sites, the position of the ring can be switched. On oxidation, it moves from the tetrathiafulvalene to the dioxynaphthalene, and on reduction, to the bipyridinium radical cation, provided the ring is also reduced simultaneously to the diradical dication. © 2010 Macmillan Publishers Limited. All rights reserved.

One-dimensional self-confinement promotes polymorph selection in large-area organic semiconductor thin films

KAUST Repository

Giri, Gaurav

2014-04-16

A crystal\\'s structure has significant impact on its resulting biological, physical, optical and electronic properties. In organic electronics, 6,13(bis-triisopropylsilylethynyl)pentacene (TIPS-pentacene), a small-molecule organic semiconductor, adopts metastable polymorphs possessing significantly faster charge transport than the equilibrium crystal when deposited using the solution-shearing method. Here, we use a combination of high-speed polarized optical microscopy, in situ microbeam grazing incidence wide-angle X-ray-scattering and molecular simulations to understand the mechanism behind formation of metastable TIPS-pentacene polymorphs. We observe that thin-film crystallization occurs first at the air-solution interface, and nanoscale vertical spatial confinement of the solution results in formation of metastable polymorphs, a one-dimensional and large-area analogy to crystallization of polymorphs in nanoporous matrices. We demonstrate that metastable polymorphism can be tuned with unprecedented control and produced over large areas by either varying physical confinement conditions or by tuning energetic conditions during crystallization through use of solvent molecules of various sizes. © 2014 Macmillan Publishers Limited.

Metamaterial mirrors in optoelectronic devices

KAUST Repository

Esfandyarpour, Majid

2014-06-22

The phase reversal that occurs when light is reflected from a metallic mirror produces a standing wave with reduced intensity near the reflective surface. This effect is highly undesirable in optoelectronic devices that use metal films as both electrical contacts and optical mirrors, because it dictates a minimum spacing between the metal and the underlying active semiconductor layers, therefore posing a fundamental limit to the overall thickness of the device. Here, we show that this challenge can be circumvented by using a metamaterial mirror whose reflection phase is tunable from that of a perfect electric mirror († = €) to that of a perfect magnetic mirror († = 0). This tunability in reflection phase can also be exploited to optimize the standing wave profile in planar devices to maximize light-matter interaction. Specifically, we show that light absorption and photocurrent generation in a sub-100 nm active semiconductor layer of a model solar cell can be enhanced by ∼20% over a broad spectral band. © 2014 Macmillan Publishers Limited.

Advancing Sustainable Development in Global Trade and Multilateral Negotiations

Directory of Open Access Journals (Sweden)

Christophe Bellmann

2011-05-01

Full Text Available Published by Palgrave MacmillanWorld exports and imports are quickly recovering after the 2008-09 sharp decline in merchandise trade, as illustrated by global trade performances in the first and second quarters of 2010. In spite of this impressive recovery, domestic concerns in OECD countries about employment, competitiveness and China’s exchange rate policy have created a difficult political environment for further liberalisation under the Doha Round. Interestingly, developing countries, which were reluctant to engage in a new round of trade negotiations back in 2001, are now in the vanguard of those that wish for a swift conclusion of the talks, even if consensus on the ambitious ‘development package’ envisaged in Doha remains elusive. At the same time trade has been the subject of unprecedented attention and scrutiny in the climate change talks. In a world where multilateral cooperation is in crisis there is a dire need for the international community to generate new types of arrangements and innovative responses to the imperatives of development and the global transition to a low-carbon economy.

Spin injection and detection in lanthanum- and niobium-doped SrTiO3 using the Hanle technique

KAUST Repository

Han, Wei

2013-07-08

There has been much interest in the injection and detection of spin-polarized carriers in semiconductors for the purposes of developing novel spintronic devices. Here we report the electrical injection and detection of spin-polarized carriers into Nb-doped strontium titanate single crystals and La-doped strontium titanate epitaxial thin films using MgO tunnel barriers and the three-terminal Hanle technique. Spin lifetimes of up to ∼100 ps are measured at room temperature and vary little as the temperature is decreased to low temperatures. However, the mobility of the strontium titanate has a strong temperature dependence. This behaviour and the carrier doping dependence of the spin lifetime suggest that the spin lifetime is limited by spin-dependent scattering at the MgO/strontium titanate interfaces, perhaps related to the formation of doping induced Ti 3+. Our results reveal a severe limitation of the three-terminal Hanle technique for measuring spin lifetimes within the interior of the subject material. © 2013 Macmillan Publishers Limited. All rights reserved.

Surface modification-induced phase transformation of hexagonal close-packed gold square sheets

KAUST Repository

Fan, Zhanxi

2015-03-13

Conventionally, the phase transformation of inorganic nanocrystals is realized under extreme conditions (for example, high temperature or high pressure). Here we report the complete phase transformation of Au square sheets (AuSSs) from hexagonal close-packed (hcp) to face-centered cubic (fcc) structures at ambient conditions via surface ligand exchange, resulting in the formation of (100)f-oriented fcc AuSSs. Importantly, the phase transformation can also be realized through the coating of a thin metal film (for example, Ag) on hcp AuSSs. Depending on the surfactants used during the metal coating process, two transformation pathways are observed, leading to the formation of (100)f-oriented fcc Au@Ag core-shell square sheets and (110)h/(101)f-oriented hcp/fcc mixed Au@Ag nanosheets. Furthermore, monochromated electron energy loss spectroscopy reveals the strong surface plasmon resonance absorption of fcc AuSS and Au@Ag square sheet in the infrared region. Our findings may offer a new route for the crystal-phase and shape-controlled synthesis of inorganic nanocrystals. © 2015 Macmillan Publishers Limited. All rights reserved.

Surface modification-induced phase transformation of hexagonal close-packed gold square sheets

KAUST Repository

Fan, Zhanxi; Huang, Xiao; Han, Yu; Bosman, Michel; Wang, Qingxiao; Zhu, Yihan; Liu, Qing; Li, Bing; Zeng, Zhiyuan; Wu, Jumiati; Shi, Wenxiong; Li, Shuzhou; Gan, Chee Lip; Zhang, Hua

2015-01-01

Conventionally, the phase transformation of inorganic nanocrystals is realized under extreme conditions (for example, high temperature or high pressure). Here we report the complete phase transformation of Au square sheets (AuSSs) from hexagonal close-packed (hcp) to face-centered cubic (fcc) structures at ambient conditions via surface ligand exchange, resulting in the formation of (100)f-oriented fcc AuSSs. Importantly, the phase transformation can also be realized through the coating of a thin metal film (for example, Ag) on hcp AuSSs. Depending on the surfactants used during the metal coating process, two transformation pathways are observed, leading to the formation of (100)f-oriented fcc Au@Ag core-shell square sheets and (110)h/(101)f-oriented hcp/fcc mixed Au@Ag nanosheets. Furthermore, monochromated electron energy loss spectroscopy reveals the strong surface plasmon resonance absorption of fcc AuSS and Au@Ag square sheet in the infrared region. Our findings may offer a new route for the crystal-phase and shape-controlled synthesis of inorganic nanocrystals. © 2015 Macmillan Publishers Limited. All rights reserved.

A genomic history of Aboriginal Australia

KAUST Repository

Malaspinas, Anna-Sapfo; Westaway, Michael C.; Muller, Craig; Sousa, Vitor C.; Lao, Oscar; Alves, Isabel; Bergströ m, Anders; Athanasiadis, Georgios; Cheng, Jade Y.; Crawford, Jacob E.; Heupink, Tim H.; Macholdt, Enrico; Peischl, Stephan; Rasmussen, Simon; Schiffels, Stephan; Subramanian, Sankar; Wright, Joanne L.; Albrechtsen, Anders; Barbieri, Chiara; Dupanloup, Isabelle; Eriksson, Anders; Margaryan, Ashot; Moltke, Ida; Pugach, Irina; Korneliussen, Thorfinn S.; Levkivskyi, Ivan P.; Moreno-Mayar, J. Ví ctor; Ni, Shengyu; Racimo, Fernando; Sikora, Martin; Xue, Yali; Aghakhanian, Farhang A.; Brucato, Nicolas; Brunak, Sø ren; Campos, Paula F.; Clark, Warren; Ellingvå g, Sturla; Fourmile, Gudjugudju; Gerbault, Pascale; Injie, Darren; Koki, George; Leavesley, Matthew; Logan, Betty; Lynch, Aubrey; Matisoo-Smith, Elizabeth A.; McAllister, Peter J.; Mentzer, Alexander J.; Metspalu, Mait; Migliano, Andrea B.; Murgha, Les; Phipps, Maude E.; Pomat, William; Reynolds, Doc; Ricaut, Francois-Xavier; Siba, Peter; Thomas, Mark G.; Wales, Thomas; Wall, Colleen Ma’ run; Oppenheimer, Stephen J.; Tyler-Smith, Chris; Durbin, Richard; Dortch, Joe; Manica, Andrea; Schierup, Mikkel H.; Foley, Robert A.; Lahr, Marta Mirazó n; Bowern, Claire; Wall, Jeffrey D.; Mailund, Thomas; Stoneking, Mark; Nielsen, Rasmus; Sandhu, Manjinder S.; Excoffier, Laurent; Lambert, David M.; Willerslev, Eske

2016-01-01

The population history of Aboriginal Australians remains largely uncharacterized. Here we generate high-coverage genomes for 83 Aboriginal Australians (speakers of Pama-Nyungan languages) and 25 Papuans from the New Guinea Highlands. We find that Papuan and Aboriginal Australian ancestors diversified 25-40 thousand years ago (kya), suggesting pre-Holocene population structure in the ancient continent of Sahul (Australia, New Guinea and Tasmania). However, all of the studied Aboriginal Australians descend from a single founding population that differentiated ∼10-32 kya. We infer a population expansion in northeast Australia during the Holocene epoch (past 10,000 years) associated with limited gene flow from this region to the rest of Australia, consistent with the spread of the Pama-Nyungan languages. We estimate that Aboriginal Australians and Papuans diverged from Eurasians 51-72 kya, following a single out-of-Africa dispersal, and subsequently admixed with archaic populations. Finally, we report evidence of selection in Aboriginal Australians potentially associated with living in the desert. © 2016 Macmillan Publishers Limited, part of Springer Nature. All rights reserved

Transcription factor PIF4 controls the thermosensory activation of flowering

KAUST Repository

Kumar, S. Vinod

2012-03-21

Plant growth and development are strongly affected by small differences in temperature. Current climate change has already altered global plant phenology and distribution, and projected increases in temperature pose a significant challenge to agriculture. Despite the important role of temperature on plant development, the underlying pathways are unknown. It has previously been shown that thermal acceleration of flowering is dependent on the florigen, FLOWERING LOCUS T (FT). How this occurs is, however, not understood, because the major pathway known to upregulate FT, the photoperiod pathway, is not required for thermal acceleration of flowering. Here we demonstrate a direct mechanism by which increasing temperature causes the bHLH transcription factor PHYTOCHROME INTERACTING FACTOR4 (PIF4) to activate FT. Our findings provide a new understanding of how plants control their timing of reproduction in response to temperature. Flowering time is an important trait in crops as well as affecting the life cycles of pollinator species. A molecular understanding of how temperature affects flowering will be important for mitigating the effects of climate change. © 2012 Macmillan Publishers Limited. All rights reserved.

Mesophase behaviour of polyhedral particles

KAUST Repository

Agarwal, Umang

2011-02-13

Translational and orientational excluded-volume fields encoded in particles with anisotropic shapes can lead to purely entropy-driven assembly of morphologies with specific order and symmetry. To elucidate this complex correlation, we carried out detailed Monte Carlo simulations of six convex space-filling polyhedrons, namely, truncated octahedrons, rhombic dodecahedrons, hexagonal prisms, cubes, gyrobifastigiums and triangular prisms. Simulations predict the formation of various new liquid-crystalline and plastic-crystalline phases at intermediate volume fractions. By correlating these findings with particle anisotropy and rotational symmetry, simple guidelines for predicting phase behaviour of polyhedral particles are proposed: high rotational symmetry is in general conducive to mesophase formation, with low anisotropy favouring plastic-solid behaviour and intermediate anisotropy (or high uniaxial anisotropy) favouring liquid-crystalline behaviour. It is also found that dynamical disorder is crucial in defining mesophase behaviour, and that the apparent kinetic barrier for the liquid-mesophase transition is much lower for liquid crystals (orientational order) than for plastic solids (translational order). © 2011 Macmillan Publishers Limited. All rights reserved.

Ancient deuterostome origins of vertebrate brain signalling centres.

Science.gov (United States)

Pani, Ariel M; Mullarkey, Erin E; Aronowicz, Jochanan; Assimacopoulos, Stavroula; Grove, Elizabeth A; Lowe, Christopher J

2012-03-14

Neuroectodermal signalling centres induce and pattern many novel vertebrate brain structures but are absent, or divergent, in invertebrate chordates. This has led to the idea that signalling-centre genetic programs were first assembled in stem vertebrates and potentially drove morphological innovations of the brain. However, this scenario presumes that extant cephalochordates accurately represent ancestral chordate characters, which has not been tested using close chordate outgroups. Here we report that genetic programs homologous to three vertebrate signalling centres-the anterior neural ridge, zona limitans intrathalamica and isthmic organizer-are present in the hemichordate Saccoglossus kowalevskii. Fgf8/17/18 (a single gene homologous to vertebrate Fgf8, Fgf17 and Fgf18), sfrp1/5, hh and wnt1 are expressed in vertebrate-like arrangements in hemichordate ectoderm, and homologous genetic mechanisms regulate ectodermal patterning in both animals. We propose that these genetic programs were components of an unexpectedly complex, ancient genetic regulatory scaffold for deuterostome body patterning that degenerated in amphioxus and ascidians, but was retained to pattern divergent structures in hemichordates and vertebrates. © 2012 Macmillan Publishers Limited. All rights reserved

Energy Security and Sub-Saharan Africa

Directory of Open Access Journals (Sweden)

Emily Meierding

2013-02-01

Full Text Available Published by Palgrave MacmillanOver the last decade the topic of energy security has reappeared on global policy agendas. Most analyses of international energy geopolitics examine the interests and behaviour of powerful energy-importing countries like the US and China. This chapter begins by examining foreign powers’ expanded exploitation of oil and uranium resources in Sub-Saharan Africa. It goes on to examine how energy importers’ efforts to enhance their energy security through Africa are impacting energy security within Africa. It assesses Sub-Saharan states’ attempts to increase consumption of local oil and uranium reserves. Observing the constraints on these efforts, it then outlines some alternative strategies that have been employed to enhance African energy security. It concludes that, while local community-based development projects have improved the well-being of many households, they are not a sufficient guarantor of energy security. Inadequate petroleum access, in particular, remains a development challenge. Foreign powers’ efforts to increase their oil security are undermining the energy security of Sub-Saharan African citizens.

Radically enhanced molecular recognition

KAUST Repository

Trabolsi, Ali; Khashab, Niveen M.; Fahrenbach, Albert C.; Friedman, Douglas C.; Colvin, Michael T.; Coti, Karla K.; Bení tez, Diego S.; Tkatchouk, Ekaterina; Olsen, John Carl; Belowich, Matthew E.; Carmieli, Raanan; Khatib, Hussam A.; Goddard, William Andrew III; Wasielewski, Michael R.; Stoddart, Fraser Fraser Raser

2009-01-01

The tendency for viologen radical cations to dimerize has been harnessed to establish a recognition motif based on their ability to form extremely strong inclusion complexes with cyclobis(paraquat-p-phenylene) in its diradical dicationic redox state. This previously unreported complex involving three bipyridinium cation radicals increases the versatility of host-guest chemistry, extending its practice beyond the traditional reliance on neutral and charged guests and hosts. In particular, transporting the concept of radical dimerization into the field of mechanically interlocked molecules introduces a higher level of control within molecular switches and machines. Herein, we report that bistable and tristable [2]rotaxanes can be switched by altering electrochemical potentials. In a tristable [2]rotaxane composed of a cyclobis(paraquat-p-phenylene) ring and a dumbbell with tetrathiafulvalene, dioxynaphthalene and bipyridinium recognition sites, the position of the ring can be switched. On oxidation, it moves from the tetrathiafulvalene to the dioxynaphthalene, and on reduction, to the bipyridinium radical cation, provided the ring is also reduced simultaneously to the diradical dication. © 2010 Macmillan Publishers Limited. All rights reserved.

A genomic history of Aboriginal Australia

KAUST Repository

Malaspinas, Anna-Sapfo

2016-09-20

The population history of Aboriginal Australians remains largely uncharacterized. Here we generate high-coverage genomes for 83 Aboriginal Australians (speakers of Pama-Nyungan languages) and 25 Papuans from the New Guinea Highlands. We find that Papuan and Aboriginal Australian ancestors diversified 25-40 thousand years ago (kya), suggesting pre-Holocene population structure in the ancient continent of Sahul (Australia, New Guinea and Tasmania). However, all of the studied Aboriginal Australians descend from a single founding population that differentiated ∼10-32 kya. We infer a population expansion in northeast Australia during the Holocene epoch (past 10,000 years) associated with limited gene flow from this region to the rest of Australia, consistent with the spread of the Pama-Nyungan languages. We estimate that Aboriginal Australians and Papuans diverged from Eurasians 51-72 kya, following a single out-of-Africa dispersal, and subsequently admixed with archaic populations. Finally, we report evidence of selection in Aboriginal Australians potentially associated with living in the desert. © 2016 Macmillan Publishers Limited, part of Springer Nature. All rights reserved

Selective contacts drive charge extraction in quantum dot solids via asymmetry in carrier transfer kinetics

KAUST Repository

Mora-Sero, Ivan

2013-08-12

Colloidal quantum dot solar cells achieve spectrally selective optical absorption in a thin layer of solution-processed, size-effect tuned, nanoparticles. The best devices built to date have relied heavily on drift-based transport due to the action of an electric field in a depletion region that extends throughout the thickness of the quantum dot layer. Here we study for the first time the behaviour of the best-performing class of colloidal quantum dot films in the absence of an electric field, by screening using an electrolyte. We find that the action of selective contacts on photovoltage sign and amplitude can be retained, implying that the contacts operate by kinetic preferences of charge transfer for either electrons or holes. We develop a theoretical model to explain these experimental findings. The work is the first to present a switch in the photovoltage in colloidal quantum dot solar cells by purposefully formed selective contacts, opening the way to new strategies in the engineering of colloidal quantum dot solar cells. © 2013 Macmillan Publishers Limited. All rights reserved.

Challenges in the Energy Sector in Eastern Europe and Central Asia: An Evaluation of 18 Years of Swiss Economic Cooperation

Directory of Open Access Journals (Sweden)

Guy Bonvin

2011-05-01

Full Text Available Published by Palgrave MacmillanSwitzerland’s State Secretariat for Economic Affairs (SECO has been working in the energy sectors of Eastern Europe and Central Asia since 1992, financing 41 projects to the value of CHF 316 million. In 2009 an independent evaluation was commissioned to assess the effects of these projects in the region and to draw lessons for future project funding. The evaluation found the projects to be highly satisfactory in terms of relevance, satisfactory in terms of effectiveness and sustainability, and — because of external factors relating to governance, transparency and political stability in a country — generally unsatisfactory in terms of efficiency.Lessons drawn from the successful projects will be used to further improve them in the future. With limited financial resources governments are attempting to find a balance between energy security and environmental sustainability. SECO will support this mission by helping to reduce inefficient consumption, to increase the share of renewable energy, to strengthen the sustainability of utility companies and to develop effective energy policies.

Biodegradation of oil refinery wastes under OPA and CERCLA

Energy Technology Data Exchange (ETDEWEB)

Gamblin, W.W.; Banipal, B.S.; Myers, J.M. [Ecology and Environment, Inc., Dallas, TX (United States)] [and others

1995-12-31

Land treatment of oil refinery wastes has been used as a disposal method for decades. More recently, numerous laboratory studies have been performed attempting to quantify degradation rates of more toxic polycyclic aromatic hydrocarbon compounds (PAHs). This paper discusses the results of the fullscale aerobic biodegradation operations using land treatment at the Macmillan Ring-Free Oil refining facility. The tiered feasibility approach of evaluating biodegradation as a treatment method to achieve site-specific cleanup criteria, including pilot biodegradation operations, is discussed in an earlier paper. Analytical results of biodegradation indicate that degradation rates observed in the laboratory can be met and exceeded under field conditions and that site-specific cleanup criteria can be attained within a proposed project time. Also prevented are degradation rates and half-lives for PAHs for which cleanup criteria have been established. PAH degradation rates and half-life values are determined and compared with the laboratory degradation rates and half-life values which used similar oil refinery wastes by other in investigators (API 1987).

Unconscious perception: a model-based approach to method and evidence.

Science.gov (United States)

Snodgrass, Michael; Bernat, Edward; Shevrin, Howard

2004-07-01

Unconscious perceptual effects remain controversial because it is hard to rule out alternative conscious perception explanations for them. We present a novel methodological framework, stressing the centrality of specifying the single-process conscious perception model (i.e., the null hypothesis). Various considerations, including those of SDT (Macmillan & Creelman, 1991), suggest that conscious perception functions hierarchically, in such a way that higher level effects (e.g., semantic priming) should not be possible without lower level discrimination (i.e., detection and identification). Relatedly, alternative conscious perception accounts (as well as the exhaustiveness, null sensitivity, and exclusiveness problems-Reingold & Merikle, 1988, 1990) predict positive relationships between direct and indirect measures. Contrariwise, our review suggests that negative and/or nonmonotonic relationships are found, providing strong evidence for unconscious perception and further suggesting that conscious and unconscious perceptual influences are functionally exclusive (cf. Jones, 1987), in such a way that the former typically override the latter when both are present. Consequently, unconscious perceptual effects manifest reliably only when conscious perception is completely absent, which occurs at the objective detection (but not identification) threshold.

Controlled growth of high-density CdS and CdSe nanorod arrays on selective facets of two-dimensional semiconductor nanoplates

KAUST Repository

Wu, Xue-Jun

2016-03-14

The rational synthesis of hierarchical three-dimensional nanostructures with specific compositions, morphologies and functionalities is important for applications in a variety of fields ranging from energy conversion and electronics to biotechnology. Here, we report a seeded growth approach for the controlled epitaxial growth of three types of hierarchical one-dimensional (1D)/two-dimensional (2D) nanostructures, where nanorod arrays of II-VI semiconductor CdS or CdSe are grown on the selective facets of hexagonal-shaped nanoplates, either on the two basal facets of the nanoplate, or on one basal facet, or on the two basal facets and six side facets. The seed engineering of 2D hexagonal-shaped nanoplates is the key factor for growth of the three resulting types of 1D/2D nanostructures. The wurtzite- and zinc-blende-type polymorphs of semiconductors are used to determine the facet-selective epitaxial growth of 1D nanorod arrays, resulting in the formation of different hierarchical three-dimensional (3D) nanostructures. © 2016 Macmillan Publishers Limited. All rights reserved.

Technical clarification to Silbert and Thomas (2013): "decisional separability, model identification, and statistical inference in the general recognition theory framework".

Science.gov (United States)

Thomas, Robin D; Silbert, Noah H

2014-04-01

We offer a minor technical correction to the published proof of part (ii) of the main theorem in Silbert and Thomas (Psychonomic Bulletin & Review, 20, 1-20, 2013) that somewhat limits the scope of the equivalence observed in that work. Specifically, in order for a mean shift integrality with decisional separability to be mimicked by a perceptually separable but nondecisionally separable configuration, one needs to assume stimulus invariance. This holds when all of the covariance matrices in the stimulus configuration are equal to each other. We note that part (i) of the theorem is unaffected by this modification; an empirical finding of perceptual separability and the failure of decisional separability can be mimicked by a perceptually nonseparable, decisionally separable configuration without restricting the covariance matrices to be equal. We also note that stimulus invariance is often assumed in simple designs (e.g., Macmillan & Ornstein in Journal of the Acoustical Society of America, 97, 1261-1285, 1998), due to the implausibility of different perceptual correlations being present within stimuli perched very closely in perceptual space.

Discovery and introduction of a (3,18)-connected net as an ideal blueprint for the design of metal-organic frameworks

KAUST Repository

Guillerm, Vincent

2014-06-29

Metal-organic frameworks (MOFs) are a promising class of porous materials because it is possible to mutually control their porous structure, composition and functionality. However, it is still a challenge to predict the network topology of such framework materials prior to their synthesis. Here we use a new rare earth (RE) nonanuclear carboxylate-based cluster as an 18-connected molecular building block to form a gea-MOF (gea-MOF-1) based on a (3,18)-connected net. We then utilized this gea net as a blueprint to design and assemble another MOF (gea-MOF-2). In gea-MOF-2, the 18-connected RE clusters are replaced by metal-organic polyhedra, peripherally functionalized so as to have the same connectivity as the RE clusters. These metal-organic polyhedra act as supermolecular building blocks when they form gea-MOF-2. The discovery of a (3,18)-connected MOF followed by deliberate transposition of its topology to a predesigned second MOF with a different chemical system validates the prospective rational design of MOFs. © 2014 Macmillan Publishers Limited. All rights reserved.

High-performance flat-panel solar thermoelectric generators with high thermal concentration.

Science.gov (United States)

Kraemer, Daniel; Poudel, Bed; Feng, Hsien-Ping; Caylor, J Christopher; Yu, Bo; Yan, Xiao; Ma, Yi; Wang, Xiaowei; Wang, Dezhi; Muto, Andrew; McEnaney, Kenneth; Chiesa, Matteo; Ren, Zhifeng; Chen, Gang

2011-05-01

The conversion of sunlight into electricity has been dominated by photovoltaic and solar thermal power generation. Photovoltaic cells are deployed widely, mostly as flat panels, whereas solar thermal electricity generation relying on optical concentrators and mechanical heat engines is only seen in large-scale power plants. Here we demonstrate a promising flat-panel solar thermal to electric power conversion technology based on the Seebeck effect and high thermal concentration, thus enabling wider applications. The developed solar thermoelectric generators (STEGs) achieved a peak efficiency of 4.6% under AM1.5G (1 kW m(-2)) conditions. The efficiency is 7-8 times higher than the previously reported best value for a flat-panel STEG, and is enabled by the use of high-performance nanostructured thermoelectric materials and spectrally-selective solar absorbers in an innovative design that exploits high thermal concentration in an evacuated environment. Our work opens up a promising new approach which has the potential to achieve cost-effective conversion of solar energy into electricity. © 2011 Macmillan Publishers Limited. All rights reserved

‘A refutation of (post-) narrativism, or: why postmodernists love Austro-Hungary’: Jouni-Matti Kuukkanen, Postnarrativist philosophy of historiography, Houndmills: Palgrave Macmillan, 2015

OpenAIRE

Branko Mitrović

2016-01-01

Jouni-Matti Kuukkanen’s book Postnarrativist philosophy of historiography presents a new variation of the postmodernist, social-constructivist and anti-realist philosophy of historiography. Kuukkanen articulates a position that significantly differs from some other postmodernist perspectives on history writing, such as Frank Ankersmit’s. In this review I analyse the implications of Kuukkanen’s programme, as well as the application of its tenets in Christopher Clark’s book Sleepwalkers. How Eu...

‘A refutation of (post- narrativism, or: why postmodernists love Austro-Hungary’: Jouni-Matti Kuukkanen, Postnarrativist philosophy of historiography, Houndmills: Palgrave Macmillan, 2015

Directory of Open Access Journals (Sweden)

Branko Mitrović

2016-12-01

Full Text Available Jouni-Matti Kuukkanen’s book Postnarrativist philosophy of historiography presents a new variation of the postmodernist, social-constructivist and anti-realist philosophy of historiography. Kuukkanen articulates a position that significantly differs from some other postmodernist perspectives on history writing, such as Frank Ankersmit’s. In this review I analyse the implications of Kuukkanen’s programme, as well as the application of its tenets in Christopher Clark’s book Sleepwalkers. How Europe went to war in 1914 (London: Penguin, 2012 which Kuukkanen strongly endorses.

Blackchested Prinia Prinia flavicans in Breeding Plumage at Satara, Kruger National Park

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H. Roome

1988-10-01

Full Text Available On 8 October 1986 a pair of Blackchested Prinia Prinia flavicans in breeding plumage was observed in the camping area of Satara Rest Camp, Kruger National Park. Playing and replaying a tape recording of the call of a Pearlspotted Owl Glaucidium perlatum, in order to see what avian activity would be aroused, the recording attracted Blackeyed Bulbul Pycnonotus barbatus, Whitebellied Sunbird Nectarinia talatala and Tawnyflanked Prinia Prinia subflava, in addition to the pair of Blackchested Prinia, all highly excited and in search of the intruding Pearlspotted Owl. The birds homed in on the source of the call and all species were observed from a distance of some 2 m-3 m. Although recorded previously from the Kruger National Park (Newman 1980, Birds of Southern Africa 1: Kruger National Park, Johannesburg: Macmillan in non-breeding plumage and also referred to by Milstein & Milstein (1981, Koedoe 24: 109-117 as a species which they probably observed near Punda Milia (in winter plumage, the Blackchested Prinia recorded at Satara were most obliging and it was possible to positively identify the presence of this species in the Kruger National Park in its breeding plumage.

Vulnerability of deep groundwater in the Bengal Aquifer System to contamination by arsenic

Science.gov (United States)

Burgess, W.G.; Hoque, M.A.; Michael, H.A.; Voss, C.I.; Breit, G.N.; Ahmed, K.M.

2010-01-01

Shallow groundwater, the primary water source in the Bengal Basin, contains up to 100 times the World Health Organization (WHO) drinking-water guideline of 10g l 1 arsenic (As), threatening the health of 70 million people. Groundwater from a depth greater than 150m, which almost uniformly meets the WHO guideline, has become the preferred alternative source. The vulnerability of deep wells to contamination by As is governed by the geometry of induced groundwater flow paths and the geochemical conditions encountered between the shallow and deep regions of the aquifer. Stratification of flow separates deep groundwater from shallow sources of As in some areas. Oxidized sediments also protect deep groundwater through the ability of ferric oxyhydroxides to adsorb As. Basin-scale groundwater flow modelling suggests that, over large regions, deep hand-pumped wells for domestic supply may be secure against As invasion for hundreds of years. By contrast, widespread deep irrigation pumping might effectively eliminate deep groundwater as an As-free resource within decades. Finer-scale models, incorporating spatial heterogeneity, are needed to investigate the security of deep municipal abstraction at specific urban locations. ?? 2010 Macmillan Publishers Limited. All rights reserved.

A gate-latch-lock mechanism for hormone signalling by abscisic acid receptors

KAUST Repository

Melcher, Karsten

2009-12-03

Abscisic acid (ABA) is a ubiquitous hormone that regulates plant growth, development and responses to environmental stresses. Its action is mediated by the PYR/PYL/RCAR family of START proteins, but it remains unclear how these receptors bind ABA and, in turn, how hormone binding leads to inhibition of the downstream type 2C protein phosphatase (PP2C) effectors. Here we report crystal structures of apo and ABA-bound receptors as well as a ternary PYL2-ABA-PP2C complex. The apo receptors contain an open ligand-binding pocket flanked by a gate that closes in response to ABA by way of conformational changes in two highly conserved ?-loops that serve as a gate and latch. Moreover, ABA-induced closure of the gate creates a surface that enables the receptor to dock into and competitively inhibit the PP2C active site. A conserved tryptophan in the PP2C inserts directly between the gate and latch, which functions to further lock the receptor in a closed conformation. Together, our results identify a conserved gate-latch-lock mechanism underlying ABA signalling. © 2009 Macmillan Publishers Limited. All rights reserved.

Asymptomatic bacteriuria: when the treatment is worse than the disease.

Science.gov (United States)

Trautner, Barbara W

2011-12-06

Asymptomatic bacteriuria (ABU) is a condition in which bacteria are present in a noncontaminated urine sample collected from a patient without signs or symptoms related to the urinary tract. ABU must be distinguished from symptomatic UTI by the absence of signs and symptoms compatible with UTI or by clinical determination that a nonurinary etiology accounts for the patient's symptoms. Interactions between the organism, the host, and the bladder environment determine whether bacteriuria leads to ABU or to UTI. ABU is a very common condition that is often treated unnecessarily with antibiotics-it should be detected and treated in pregnant women and patients undergoing urologic surgery, but in most other patient groups, treatment does not confer benefit and can be harmful. A change in prescribing behavior for ABU has been achieved through several fairly high-intensity interventions, such as interactive educational sessions for physicians, but whether these improvements persist beyond the study period is not known. Further research is needed to determine whether screening for and treatment of ABU is beneficial in patients with renal transplants, patients with orthotopic neobladders, patients undergoing prosthetic joint implantation, and patients with neutropenia. © 2012 Macmillan Publishers Limited. All rights reserved

The New Realities of Global Health: Dynamics and Obstacles

Directory of Open Access Journals (Sweden)

Marine Buissonnière

2012-03-01

Full Text Available Published by Palgrave MacmillanThe past 15 years have seen the arrival of new actors in the field of global health and an increase in development aid in the healthcare sector. These actors have claimed a significant share of the additional public and private resources available becoming the driving force in this new paradigm, often at the expense of traditional institutions, which have gradually lost their policy hegemony. Making choices and formulating policies on the matter of healthcare have ceased to be the sole prerogative of the institutions that had hitherto held the mandate and the responsibility for doing so. Entire areas of the healthcare sector are now dominated by private funders, which have become the de facto decision-makers on public health policy. This new situation raises fundamental questions about governance and accountability. Who decides policy? How are decisions made? All too often, countries in receipt of aid continue to suffer from inadequate coordination between donors and from the lack of a common agenda. With this in mind, it is worth exploring a number of ways of ensuring that global healthcare policies best reflect the beneficiary countries’ actual needs and aspirations.

Solution coating of large-area organic semiconductor thin films with aligned single-crystalline domains

KAUST Repository

Diao, Ying

2013-06-02

Solution coating of organic semiconductors offers great potential for achieving low-cost manufacturing of large-area and flexible electronics. However, the rapid coating speed needed for industrial-scale production poses challenges to the control of thin-film morphology. Here, we report an approach - termed fluid-enhanced crystal engineering (FLUENCE) - that allows for a high degree of morphological control of solution-printed thin films. We designed a micropillar-patterned printing blade to induce recirculation in the ink for enhancing crystal growth, and engineered the curvature of the ink meniscus to control crystal nucleation. Using FLUENCE, we demonstrate the fast coating and patterning of millimetre-wide, centimetre-long, highly aligned single-crystalline organic semiconductor thin films. In particular, we fabricated thin films of 6,13-bis(triisopropylsilylethynyl) pentacene having non-equilibrium single-crystalline domains and an unprecedented average and maximum mobilities of 8.1±1.2 cm2 V-1 s -1 and 11 cm2 V-1 s-1. FLUENCE of organic semiconductors with non-equilibrium single-crystalline domains may find use in the fabrication of high-performance, large-area printed electronics. © 2013 Macmillan Publishers Limited. All rights reserved.

Stable cycling of double-walled silicon nanotube battery anodes through solid–electrolyte interphase control

KAUST Repository

Wu, Hui

2012-03-25

Although the performance of lithium ion-batteries continues to improve, their energy density and cycle life remain insufficient for applications in consumer electronics, transport and large-scale renewable energy storage 1-5. Silicon has a large charge storage capacity and this makes it an attractive anode material, but pulverization during cycling and an unstable solid-electrolyte interphase has limited the cycle life of silicon anodes to hundreds of cycles 6-11. Here, we show that anodes consisting of an active silicon nanotube surrounded by an ion-permeable silicon oxide shell can cycle over 6,000 times in half cells while retaining more than 85% of their initial capacity. The outer surface of the silicon nanotube is prevented from expansion by the oxide shell, and the expanding inner surface is not exposed to the electrolyte, resulting in a stable solid-electrolyte interphase. Batteries containing these double-walled silicon nanotube anodes exhibit charge capacities approximately eight times larger than conventional carbon anodes and charging rates of up to 20C (a rate of 1C corresponds to complete charge or discharge in one hour). © 2012 Macmillan Publishers Limited. All rights reserved.

Large modulation of carrier transport by grain-boundary molecular packing and microstructure in organic thin films

KAUST Repository

Rivnay, Jonathan

2009-11-08

Solution-processable organic semiconductors are central to developing viable printed electronics, and performance comparable to that of amorphous silicon has been reported for films grown from soluble semiconductors. However, the seemingly desirable formation of large crystalline domains introduces grain boundaries, resulting in substantial device-to-device performance variations. Indeed, for films where the grain-boundary structure is random, a few unfavourable grain boundaries may dominate device performance. Here we isolate the effects of molecular-level structure at grain boundaries by engineering the microstructure of the high-performance n-type perylenediimide semiconductor PDI8-CN 2 and analyse their consequences for charge transport. A combination of advanced X-ray scattering, first-principles computation and transistor characterization applied to PDI8-CN 2 films reveals that grain-boundary orientation modulates carrier mobility by approximately two orders of magnitude. For PDI8-CN 2 we show that the molecular packing motif (that is, herringbone versus slip-stacked) plays a decisive part in grain-boundary-induced transport anisotropy. The results of this study provide important guidelines for designing device-optimized molecular semiconductors. © 2009 Macmillan Publishers Limited. All rights reserved.

Foucault on methadone: beyond biopower.

Science.gov (United States)

Keane, Helen

2009-09-01

This essay reviews four texts which critically analyse methadone maintenance therapy using Foucault as a key theoretical framework: [Friedman, J., & Alicea, M. (2001). Surviving heroin: Interviews with women in methadone clinics. Florida: University Press of Florida], [Bourgois, P. (2000). Disciplining addictions: The bio-politics of methadone and heroin in the United States. Culture Medicine and Psychiatry, 24, 165-195], [Bull, M. (2008). Governing the heroin trade: From treaties to treatment. Ashgate: Aldershot], and [Fraser, S., & valentine, k. (2008). Substance & substitution: Methadone subjects in liberal societies. New York: Palgrave Macmillan]. Taken together these works demonstrate one trajectory in the development of critical drug studies over the past decade. While all four view MMT as a regulatory technology which aims to create productive and obedient subjects, their understandings of the power relations of the clinic are quite distinct. The first two texts emphasise the social control of drug users, the third, issues of governmentality and liberal political practice, while the fourth engages with ontological questions about substances themselves. Thus while Foucauldian analysis has become familiar in social studies of drugs and alcohol, new uses for its conceptual tools continue to emerge.

High atmosphere–ocean exchange of semivolatile aromatic hydrocarbons

KAUST Repository

González-Gaya, Belén

2016-05-16

Polycyclic aromatic hydrocarbons, and other semivolatile aromatic-like compounds, are an important and ubiquitous fraction of organic matter in the environment. The occurrence of semivolatile aromatic hydrocarbons is due to anthropogenic sources such as incomplete combustion of fossil fuels or oil spills, and other biogenic sources. However, their global transport, fate and relevance for the carbon cycle have been poorly assessed, especially in terms of fluxes. Here we report a global assessment of the occurrence and atmosphere-ocean fluxes of 64 polycyclic aromatic hydrocarbons analysed in paired atmospheric and seawater samples from the tropical and subtropical Atlantic, Pacific and Indian oceans. The global atmospheric input of polycyclic aromatic hydrocarbons to the global ocean is estimated at 0.09 Tg per month, four times greater than the input from the Deepwater Horizon spill. Moreover, the environmental concentrations of total semivolatile aromatic-like compounds were 10 2 -10 3 times higher than those of the targeted polycyclic aromatic hydrocarbons, with a relevant contribution of an aromatic unresolved complex mixture. These concentrations drive a large global deposition of carbon, estimated at 400 Tg C yr -1, around 15% of the oceanic CO2 uptake. © 2016 Macmillan Publishers Limited.

The United Nations and Global Public Goods: Historical Contributions and Future Challenges.

Directory of Open Access Journals (Sweden)

Bruce Jenks

2012-03-01

Full Text Available Published by Palgrave MacmillanThis chapter explores the thesis that the United Nations’ (UN most important contribution to the production of global public goods has been its role in creating the space and capacity to generate shared values. Starting with the UN Charter itself, the chapter traces the evolution of this contribution through different historical phases. It analyses the impact of globalisation on the role of the UN; in particular it identifies the quality of porousness as a product of globalisation which is critical to understanding the current challenges faced by the UN as well as central to the global public goods agenda. Through this lens the author briefly reviews the evolution of the UN’s role in the fields of peace and security, human rights and development cooperation. He concludes by identifying eight levers for change that will determine the UN’s ability to contribute significantly to the global public goods: the generation of norms and shared values, the quality of leadership, improved governance, innovative financing, institutional realignment, the further consolidation of legal instruments, focus, and the power of networks.

Air-stable n-type colloidal quantum dot solids

KAUST Repository

Ning, Zhijun; Voznyy, Oleksandr; Pan, Jun; Hoogland, Sjoerd H.; Adinolfi, Valerio; Xu, Jixian; Li, Min; Kirmani, Ahmad R.; Sun, Jonpaul; Minor, James C.; Kemp, Kyle W.; Dong, Haopeng; Rollny, Lisa R.; Labelle, André J.; Carey, Graham H.; Sutherland, Brandon R.; Hill, Ian G.; Amassian, Aram; Liu, Huan; Tang, Jiang; Bakr, Osman; Sargent, E. H.

2014-01-01

Colloidal quantum dots (CQDs) offer promise in flexible electronics, light sensing and energy conversion. These applications rely on rectifying junctions that require the creation of high-quality CQD solids that are controllably n-type (electron-rich) or p-type (hole-rich). Unfortunately, n-type semiconductors made using soft matter are notoriously prone to oxidation within minutes of air exposure. Here we report high-performance, air-stable n-type CQD solids. Using density functional theory we identify inorganic passivants that bind strongly to the CQD surface and repel oxidative attack. A materials processing strategy that wards off strong protic attack by polar solvents enabled the synthesis of an air-stable n-type PbS CQD solid. This material was used to build an air-processed inverted quantum junction device, which shows the highest current density from any CQD solar cell and a solar power conversion efficiency as high as 8%. We also feature the n-type CQD solid in the rapid, sensitive, and specific detection of atmospheric NO2. This work paves the way for new families of electronic devices that leverage air-stable quantum-tuned materials. © 2014 Macmillan Publishers Limited. All rights reserved.

China’s Foreign Aid and Its Role in the International Architecture

Directory of Open Access Journals (Sweden)

Meibo Huang

2012-03-01

Full Text Available Published by Palgrave MacmillanThough China has long been an aid provider, the recent and remarkable surge in China’s foreign aid has important implications for the global aid architecture. It relies on aid principles that diverge in many ways from those of traditional Development Assistance Committee (DAC donor countries, particularly in relation to non-interference, mutual benefit and non-conditionality. China’s foreign aid also relies on a mixing of economic cooperation, trade and investment deals. While several Western scholars have examined the Chinese development cooperation system, few voices from China have been heard in European and North American journals and media. This chapter aims to offer a Chinese perspective on the evolution of China’s foreign aid. It focuses on the aid principles that have thus far informed Chinese development assistance, highlighting the successful outcomes achieved so far in Africa and South-East Asia. The chapter also addresses the main shortcomings of the Chinese approach, by recommending the improvement of institutional transparency, and strengthening of dialogue with DAC donors, all with a view towards learning from past experiences and exchanging best practices.

Air-stable n-type colloidal quantum dot solids

KAUST Repository

Ning, Zhijun

2014-06-08

Colloidal quantum dots (CQDs) offer promise in flexible electronics, light sensing and energy conversion. These applications rely on rectifying junctions that require the creation of high-quality CQD solids that are controllably n-type (electron-rich) or p-type (hole-rich). Unfortunately, n-type semiconductors made using soft matter are notoriously prone to oxidation within minutes of air exposure. Here we report high-performance, air-stable n-type CQD solids. Using density functional theory we identify inorganic passivants that bind strongly to the CQD surface and repel oxidative attack. A materials processing strategy that wards off strong protic attack by polar solvents enabled the synthesis of an air-stable n-type PbS CQD solid. This material was used to build an air-processed inverted quantum junction device, which shows the highest current density from any CQD solar cell and a solar power conversion efficiency as high as 8%. We also feature the n-type CQD solid in the rapid, sensitive, and specific detection of atmospheric NO2. This work paves the way for new families of electronic devices that leverage air-stable quantum-tuned materials. © 2014 Macmillan Publishers Limited. All rights reserved.

A gate-latch-lock mechanism for hormone signalling by abscisic acid receptors

KAUST Repository

Melcher, Karsten; Ng, Ley-Moy; Zhou, X. Edward; Soon, Fen-Fen; Xu, Yong; Suino-Powell, Kelly M.; Park, Sang-Youl; Weiner, Joshua J.; Fujii, Hiroaki; Chinnusamy, Viswanathan; Kovach, Amanda; Li, Jun; Wang, Yonghong; Li, Jiayang; Peterson, Francis C.; Jensen, Davin R.; Yong, Eu-Leong; Volkman, Brian F.; Cutler, Sean R.; Zhu, Jian-Kang; Xu, H. Eric

2009-01-01

Abscisic acid (ABA) is a ubiquitous hormone that regulates plant growth, development and responses to environmental stresses. Its action is mediated by the PYR/PYL/RCAR family of START proteins, but it remains unclear how these receptors bind ABA and, in turn, how hormone binding leads to inhibition of the downstream type 2C protein phosphatase (PP2C) effectors. Here we report crystal structures of apo and ABA-bound receptors as well as a ternary PYL2-ABA-PP2C complex. The apo receptors contain an open ligand-binding pocket flanked by a gate that closes in response to ABA by way of conformational changes in two highly conserved ?-loops that serve as a gate and latch. Moreover, ABA-induced closure of the gate creates a surface that enables the receptor to dock into and competitively inhibit the PP2C active site. A conserved tryptophan in the PP2C inserts directly between the gate and latch, which functions to further lock the receptor in a closed conformation. Together, our results identify a conserved gate-latch-lock mechanism underlying ABA signalling. © 2009 Macmillan Publishers Limited. All rights reserved.

Cognitive Modeling of Social Behaviors

Science.gov (United States)

Clancey, William J.; Sierhuis, Maarten; Damer. Bruce; Brodsky, Boris

2004-01-01

The driving theme of cognitive modeling for many decades has been that knowledge affects how and which goals are accomplished by an intelligent being (Newell 1991). But when one examines groups of people living and working together, one is forced to recognize that whose knowledge is called into play, at a particular time and location, directly affects what the group accomplishes. Indeed, constraints on participation, including roles, procedures, and norms, affect whether an individual is able to act at all (Lave & Wenger 1991; Jordan 1992; Scribner & Sachs 1991). To understand both individual cognition and collective activity, perhaps the greatest opportunity today is to integrate the cognitive modeling approach (which stresses how beliefs are formed and drive behavior) with social studies (which stress how relationships and informal practices drive behavior). The crucial insight is that norms are conceptualized in the individual &nd as ways of carrying out activities (Clancey 1997a, 2002b). This requires for the psychologist a shift from only modeling goals and tasks - why people do what they do - to modeling behavioral patterns-what people do-as they are engaged in purposeful activities. Instead of a model that exclusively deduces actions from goals, behaviors are also, if not primarily, driven by broader patterns of chronological and located activities (akin to scripts). This analysis is particular inspired by activity theory (Leont ev 1979). While acknowledging that knowledge (relating goals and operations) is fundamental for intelligent behavior, activity theory claims that a broader driver is the person s motives and conceptualization of activities. Such understanding of human interaction is normative (i.e., viewed with respect to social standards), affecting how knowledge is called into play and applied in practice. Put another way, how problems are discovered and framed, what methods are chosen, and indeed who even cares or has the authority to act, are all

Developing a Model for Pharmaceutical Palliative Care in Rural Areas—Experience from Scotland

Directory of Open Access Journals (Sweden)

Gazala Akram

2017-02-01

Full Text Available Palliative care is increasingly delivered in the community but access to medicines, particularly ‘out of hours’ remains problematic. This paper describes the experience of developing a model to deliver pharmaceutical palliative care in rural Scotland via the MacMillan Rural Palliative Care Pharmacist Practitioner (MRPP project. The focus of the service was better integration of the MRPP into different care settings and professional teams, and to develop educational resources for the wider MDT including Care Home and Social Care staff on medicine related issues in palliative care. A variety of integration activities are reported in the paper with advice on how to achieve this. Similarly, many resources were developed, including bespoke training on pharmaceutical matters for Care Home staff. The experience allowed for a three step service and sustainability model for community pharmacy palliative care services to be developed. Moving through the steps, the key roles and responsibilities of the MRPP gradually shift towards the local Community Pharmacist(s, with the MRPP starting from a locality-based hands-on role to a wider supportive facilitating role for local champions. It is acknowledged that successful delivery of the model is dependent on alignment of resources, infrastructure and local community support.

Pharmaceutical Company Corruption and the Moral Crisis in Medicine.

Science.gov (United States)

Batt, Sharon

2016-07-01

A much-debated series of articles in the New England Journal of Medicine in May 2015 labeled the pharmaceutical industry's critics "pharmascolds." Having followed the debate for two decades, I count myself among the scolds. The weight of the evidence overwhelmingly supports the claim that pharmaceutical policy no longer serves the public interest; the central questions now are how this happened and what to do about it. I approached three of the most recent books on the industry with these questions in mind. Deadly Medicine and Organized Crime (CRC Press, 2013), by Peter Gøtzsche, Bad Pharma (Faber & Faber, 2013), by Ben Goldacre, and Good Pharma (Palgrave MacMillan, 2015), by Donald Light and Antonio Maturo, all situate their critical assessments in high-income countries globally, depicting the problem of pharmaceuticals as too many drugs approved with too little evidence, causing too many needless deaths, and prices spiraling to heights unimaginable just a decade ago. Light and Maturo, while no less critical of the status quo than Gøtzsche and Goldacre, take a different tack: they detail the success of an alternative model for pharmaceutical research, the Mario Negri Institute in Italy, citing it as proof positive that we can indeed defy capitalism's profit imperative. © 2016 The Hastings Center.

A functional SNP in the regulatory region of the decay-accelerating factor gene associates with extraocular muscle pareses in myasthenia gravis

KAUST Repository

Heckmann, J M

2009-08-13

Complement activation in myasthenia gravis (MG) may damage muscle endplate and complement regulatory proteins such as decay-accelerating factor (DAF) or CD55 may be protective. We hypothesize that the increased prevalence of severe extraocular muscle (EOM) dysfunction among African MG subjects reported earlier may result from altered DAF expression. To test this hypothesis, we screened the DAF gene sequences relevant to the classical complement pathway and found an association between myasthenics with EOM paresis and the DAF regulatory region c.-198CG SNP (odds ratio8.6; P0.0003). This single nucleotide polymorphism (SNP) results in a twofold activation of a DAF 5?-flanking region luciferase reporter transfected into three different cell lines. Direct matching of the surrounding SNP sequence within the DAF regulatory region with the known transcription factor-binding sites suggests a loss of an Sp1-binding site. This was supported by the observation that the c.-198CG SNP did not show the normal lipopolysaccharide-induced DAF transcriptional upregulation in lymphoblasts from four patients. Our findings suggest that at critical periods during autoimmune MG, this SNP may result in inadequate DAF upregulation with consequent complement-mediated EOM damage. Susceptible individuals may benefit from anti-complement therapy in addition to immunosuppression. © 2010 Macmillan Publishers Limited. All rights reserved.

Bright infrared quantum-dot light-emitting diodes through inter-dot spacing control

KAUST Repository

Sun, Liangfeng; Choi, Joshua J.; Stachnik, David; Bartnik, Adam C.; Hyun, Byung-Ryool; Malliaras, George G.; Hanrath, Tobias; Wise, Frank W.

2012-01-01

Infrared light-emitting diodes are currently fabricated from direct-gap semiconductors using epitaxy, which makes them expensive and difficult to integrate with other materials. Light-emitting diodes based on colloidal semiconductor quantum dots, on the other hand, can be solution-processed at low cost, and can be directly integrated with silicon. However, so far, exciton dissociation and recombination have not been well controlled in these devices, and this has limited their performance. Here, by tuning the distance between adjacent PbS quantum dots, we fabricate thin-film quantum-dot light-emitting diodes that operate at infrared wavelengths with radiances (6.4 W sr '1 m '2) eight times higher and external quantum efficiencies (2.0%) two times higher than the highest values previously reported. The distance between adjacent dots is tuned over a range of 1.3 nm by varying the lengths of the linker molecules from three to eight CH 2 groups, which allows us to achieve the optimum balance between charge injection and radiative exciton recombination. The electroluminescent powers of the best devices are comparable to those produced by commercial InGaAsP light-emitting diodes. By varying the size of the quantum dots, we can tune the emission wavelengths between 800 and 1,850 nm.© 2012 Macmillan Publishers Limited.

Emerging ‘Donor’, Geopolitical Actor: South Africa in the Global Terrain

Directory of Open Access Journals (Sweden)

Elizabeth Sidiropoulos

2012-03-01

Full Text Available Published by Palgrave MacmillanAn active participant in the various global debates and motivated by a desire to address global inequalities and power imbalances in rule-making, South Africa seeks to balance its domestic imperatives with an enlightened developmentally-minded foreign policy where Africa is the priority. Since 1994 South Africa has initiated many activities that may be described as development cooperation. However, with the exception of the African Renaissance Fund (ARF, it has lacked an overarching architecture for its assistance, which has been fragmented among various departments and agencies with very little coherence, bar their focus on Africa. The establishment of the South African Development Partnership Agency (SADPA within the Department of International Relations and Cooperation (DIRCO by the first half of 2012 is poised to address many of these shortcomings, ensuring greater intragovernmental coordination and evaluation. In embarking on this path, South Africa will engage more in the future structure of international development, arguing for a broader definition of development cooperation and a framework that has evolved with input from the South. The fluidity in global development provides an opportunity for South Africa to help bridge the divide between North and South, and encourage policy innovation in the aid debate.

Early childhood numeracy in a multiage setting

Science.gov (United States)

Wood, Karen; Frid, Sandra

2005-10-01

This research is a case study examining numeracy teaching and learning practices in an early childhood multiage setting with Pre-Primary to Year 2 children. Data were collected via running records, researcher reflection notes, and video and audio recordings. Video and audio transcripts were analysed using a mathematical discourse and social interactions coding system designed by MacMillan (1998), while the running records and reflection notes contributed to descriptions of the children's interactions with each other and with the teachers. Teachers used an `assisted performance' approach to instruction that supported problem solving and inquiry processes in mathematics activities, and this, combined with a child-centred pedagogy and specific values about community learning, created a learning environment designed to stimulate and foster learning. The mathematics discourse analysis showed a use of explanatory language in mathematics discourse, and this language supported scaffolding among children for new mathematics concepts. These and other interactions related to peer sharing, tutoring and regulation also emerged as key aspects of students' learning practices. However, the findings indicated that multiage grouping alone did not support learning. Rather, effective learning was dependent upon the teacher's capacities to develop productive discussion among children, as well as implement developmentally appropriate curricula that addressed the needs of the different children.

Harnessing structural darkness in the visible and infrared wavelengths for a new source of light

KAUST Repository

Huang, Jianfeng

2015-10-19

Engineering broadband light absorbers is crucial to many applications, including energy-harvesting devices and optical interconnects. The performances of an ideal absorber are that of a black body, a dark material that absorbs radiation at all angles and polarizations. Despite advances in micrometre-thick films, the absorbers available to date are still far from an ideal black body. Here, we describe a disordered nanostructured material that shows an almost ideal black-body absorption of 98-99% between 400 and 1,400 nm that is insensitive to the angle and polarization of the incident light. The material comprises nanoparticles composed of a nanorod with a nanosphere of 30 nm diameter attached. When diluted into liquids, a small concentration of nanoparticles absorbs on average 26% more than carbon nanotubes, the darkest material available to date. By pumping a dye optical amplifier with nanosecond pulses of 100 mW power, we harness the structural darkness of the material and create a new type of light source, which generates monochromatic emission (5 nm wide) without the need for any resonance. This is achieved through the dynamics of light condensation in which all absorbed electromagnetic energy spontaneously generates single-colour energy pulses. © 2016 Macmillan Publishers Limited. All rights reserved.

Iron solubility driven by speciation in dust sources to the ocean

Science.gov (United States)

Schroth, A.W.; Crusius, John; Sholkovitz, E.R.; Bostick, B.C.

2009-01-01

Although abundant in the Earths crust, iron is present at trace concentrations in sea water and is a limiting nutrient for phytoplankton in approximately 40% of the ocean. Current literature suggests that aerosols are the primary external source of iron to offshore waters, yet controls on iron aerosol solubility remain unclear. Here we demonstrate that iron speciation (oxidation state and bonding environment) drives iron solubility in arid region soils, glacial weathering products (flour) and oil combustion products (oil fly ash). Iron speciation varies by aerosol source, with soils in arid regions dominated by ferric (oxy)hydroxides, glacial flour by primary and secondary ferrous silicates and oil fly ash by ferric sulphate salts. Variation in iron speciation produces systematic differences in iron solubility: less than 1% of the iron in arid soils was soluble, compared with 2-3% in glacial products and 77-81% in oil combustion products, which is directly linked to fractions of more soluble phases. We conclude that spatial and temporal variations in aerosol iron speciation, driven by the distribution of deserts, glaciers and fossil-fuel combustion, could have a pronounced effect on aerosol iron solubility and therefore on biological productivity and the carbon cycle in the ocean. ?? 2009 Macmillan Publishers Limited.

The Transformation of International NGOs and Their Impact on Development Aid

Directory of Open Access Journals (Sweden)

Thomas Richard Davies

2012-03-01

Full Text Available Published by Palgrave MacmillanInternational non-governmental organisations (INGOs are among the key actors in the transformation of development as a global public policy issue in the post-Cold War era. This chapter explores how in the past two decades INGOs concerned with development have transformed their structures and practices as well as development discourse. The author shows how development INGOs have globalised, in terms of both the formation of international confederations and the collaboration of multiple INGOs in global coalitions. A key development has been the erosion of the apparent North–South divide among development INGOs, with INGOs that originated in donor countries reforming their structures to give a greater voice to their affiliates in recipient countries, and organisations that originated in developing countries forming affiliates in developed countries. The reorientation of INGO advocacy from states toward intergovernmental and corporate actors is also explored, as is the creation of new forms of partnerships with both governmental and private actors. The chapter addresses how development INGOs have attempted to respond to critiques of their accountability and legitimacy through reforms such as the International NGO Charter on Accountability, while the conclusion explores the limitations of the transformations of development INGOs, and the challenges that these new configurations pose.

Tectonic evolution of the Salton Sea inferred from seismic reflection data

Science.gov (United States)

Brothers, D.S.; Driscoll, N.W.; Kent, G.M.; Harding, A.J.; Babcock, J.M.; Baskin, R.L.

2009-01-01

Oblique extension across strike-slip faults causes subsidence and leads to the formation of pull-apart basins such as the Salton Sea in southern California. The formation of these basins has generally been studied using laboratory experiments or numerical models. Here we combine seismic reflection data and geological observations from the Salton Sea to understand the evolution of this nascent pull-apart basin. Our data reveal the presence of a northeast-trending hinge zone that separates the sea into northern and southern sub-basins. Differential subsidence (10 mm yr 1) in the southern sub-basin suggests the existence of northwest-dipping basin-bounding faults near the southern shoreline, which may control the spatial distribution of young volcanism. Rotated and truncated strata north of the hinge zone suggest that the onset of extension associated with this pull-apart basin began after 0.5 million years ago. We suggest that slip is partitioned spatially and temporally into vertical and horizontal domains in the Salton Sea. In contrast to previous models based on historical seismicity patterns, the rapid subsidence and fault architecture that we document in the southern part of the sea are consistent with experimental models for pull-apart basins. ?? 2009 Macmillan Publishers Limited.

Enhancing multiphoton upconversion through energy clustering at sublattice level

KAUST Repository

Wang, Juan

2013-11-24

The applications of lanthanide-doped upconversionnanocrystals in biological imaging, photonics, photovoltaics and therapeutics have fuelled a growing demand for rational control over the emission profiles of the nanocrystals. A common strategy for tuning upconversion luminescence is to control the doping concentration of lanthanide ions. However, the phenomenon of concentration quenching of the excited state at high doping levels poses a significant constraint. Thus, the lanthanide ions have to be stringently kept at relatively low concentrations to minimize luminescence quenching. Here we describe a new class of upconversion nanocrystals adopting an orthorhombic crystallographic structure in which the lanthanide ions are distributed in arrays of tetrad clusters. Importantly, this unique arrangement enables the preservation of excitation energy within the sublattice domain and effectively minimizes the migration of excitation energy to defects, even in stoichiometric compounds with a high Yb 3+ content (calculated as 98 mol%). This allows us to generate an unusual four-photon-promoted violet upconversion emission from Er 3+ with an intensity that is more than eight times higher than previously reported. Our results highlight that the approach to enhancing upconversion through energy clustering at the sublattice level may provide new opportunities for light-triggered biological reactions and photodynamic therapy. © 2014 Macmillan Publishers Limited. All rights reserved.

Simultaneous phase and size control of upconversion nanocrystals through lanthanide doping

KAUST Repository

Wang, Feng

2010-02-25

Doping is a widely applied technological process in materials science that involves incorporating atoms or ions of appropriate elements into host lattices to yield hybrid materials with desirable properties and functions. For nanocrystalline materials, doping is of fundamental importance in stabilizing a specific crystallographic phase, modifying electronic properties, modulating magnetism as well as tuning emission properties. Here we describe a material system in which doping influences the growth process to give simultaneous control over the crystallographic phase, size and optical emission properties of the resulting nanocrystals. We show that NaYF 4 nanocrystals can be rationally tuned in size (down to ten nanometres), phase (cubic or hexagonal) and upconversion emission colour (green to blue) through use of trivalent lanthanide dopant ions introduced at precisely defined concentrations. We use first-principles calculations to confirm that the influence of lanthanide doping on crystal phase and size arises from a strong dependence on the size and dipole polarizability of the substitutional dopant ion. Our results suggest that the doping-induced structural and size transition, demonstrated here in NaYF 4 upconversion nanocrystals, could be extended to other lanthanide-doped nanocrystal systems for applications ranging from luminescent biological labels to volumetric three-dimensional displays. © 2010 Macmillan Publishers Limited. All rights reserved.

Bright infrared quantum-dot light-emitting diodes through inter-dot spacing control

KAUST Repository

Sun, Liangfeng

2012-05-06

Infrared light-emitting diodes are currently fabricated from direct-gap semiconductors using epitaxy, which makes them expensive and difficult to integrate with other materials. Light-emitting diodes based on colloidal semiconductor quantum dots, on the other hand, can be solution-processed at low cost, and can be directly integrated with silicon. However, so far, exciton dissociation and recombination have not been well controlled in these devices, and this has limited their performance. Here, by tuning the distance between adjacent PbS quantum dots, we fabricate thin-film quantum-dot light-emitting diodes that operate at infrared wavelengths with radiances (6.4 W sr \\'1 m \\'2) eight times higher and external quantum efficiencies (2.0%) two times higher than the highest values previously reported. The distance between adjacent dots is tuned over a range of 1.3 nm by varying the lengths of the linker molecules from three to eight CH 2 groups, which allows us to achieve the optimum balance between charge injection and radiative exciton recombination. The electroluminescent powers of the best devices are comparable to those produced by commercial InGaAsP light-emitting diodes. By varying the size of the quantum dots, we can tune the emission wavelengths between 800 and 1,850 nm.© 2012 Macmillan Publishers Limited.

Current standards for infection control: audit assures compliance.

Science.gov (United States)

Flanagan, Pauline

Having robust policies and procedures in place for infection control is fundamentally important. However, each organization has to go a step beyond this; evidence has to be provided that these policies and procedures are followed. As of 1 April 2009, with the introduction of the Care Quality Commission and The Health and Social Care Act 2008 Code of Practice for the NHS on the Prevention and Control of Healthcare-Associated Infections and Related Guidance, the assurance of robust infection control measures within any UK provider of health care became an even higher priority. Also, the commissioning of any service by the NHS must provide evidence that the provider has in place robust procedures for infection control. This article demonstrates how the clinical audit team at the Douglas Macmillan Hospice in North Staffordshire, UK, have used audit to assure high rates of compliance with the current national standards for infection control. Prior to the audit, hospice staff had assumed that the rates of compliance for infection control approached 100%. This article shows that a good quality audit tool can be used to identify areas of shortfall in infection control and the effectiveness of putting in place an action plan followed by re-audit.

Ethics, Law and Professional Issues Gallagher Ann and Hodge Sue Ethics, Law and Professional Issues 192pp £20.99 Palgrave Macmillan 9780230279940 0230279945 [Formula: see text].

Science.gov (United States)

2014-10-01

THE EDITORS provide a sound introduction to ethics, law and professional issues in health care. Scenarios before each chapter help the reader to digest and comprehend the information. My only criticism is that it is not directly relevant to nursing alone. Although there is some benefit in being aware of how other practitioners may be affected by these issues, another book aimed at nurses would be more appropriate. Later chapters about responding to unprofessional practice and promoting professional healthcare practice may be of more interest to nursing students and recently qualified healthcare professionals.

Surface-temperature trends and variability in the low-latitude North Atlantic since 1552

KAUST Repository

Saenger, Casey

2009-06-21

Sea surface temperature variability in the North Atlantic Ocean recorded since about 1850 has been ascribed to a natural multidecadal oscillation superimposed on a background warming trend1-6. It has been suggested that the multidecadal variability may be a persistent feature6-8, raising the possibility that the associated climate impacts may be predictable7,8. owever, our understanding of the multidecadal ocean variability before the instrumental record is based on interpretations of high-latitude terrestrial proxy records. Here we present an absolutely dated and annually resolved record of sea surface temperature from the Bahamas, based on a 440-year time series of coral growth rates. The reconstruction indicates that temperatures were as warm as today from about 1552 to 1570, then cooled by about 1° C from 1650 to 1730 before warming until the present. Our estimates of background variability suggest that much of the warming since 1900 was driven by anthropogenic forcing. Interdecadal variability with a period of 15-25 years is superimposed on most of the record, but multidecadal variability becomes significant only after 1730. We conclude that the multidecadal variability in sea surface temperatures in the low-latitude western Atlantic Ocean may not be persistent, potentially making accurate decadal climate forecasts more difficult to achieve. © 2009 Macmillan Publishers Limited. All rights reserved.

Surface-temperature trends and variability in the low-latitude North Atlantic since 1552

KAUST Repository

Saenger, Casey; Cohen, Anne L.; Oppo, Delia W.; Halley, Robert B.; Carilli, Jessica E.

2009-01-01

Sea surface temperature variability in the North Atlantic Ocean recorded since about 1850 has been ascribed to a natural multidecadal oscillation superimposed on a background warming trend1-6. It has been suggested that the multidecadal variability may be a persistent feature6-8, raising the possibility that the associated climate impacts may be predictable7,8. owever, our understanding of the multidecadal ocean variability before the instrumental record is based on interpretations of high-latitude terrestrial proxy records. Here we present an absolutely dated and annually resolved record of sea surface temperature from the Bahamas, based on a 440-year time series of coral growth rates. The reconstruction indicates that temperatures were as warm as today from about 1552 to 1570, then cooled by about 1° C from 1650 to 1730 before warming until the present. Our estimates of background variability suggest that much of the warming since 1900 was driven by anthropogenic forcing. Interdecadal variability with a period of 15-25 years is superimposed on most of the record, but multidecadal variability becomes significant only after 1730. We conclude that the multidecadal variability in sea surface temperatures in the low-latitude western Atlantic Ocean may not be persistent, potentially making accurate decadal climate forecasts more difficult to achieve. © 2009 Macmillan Publishers Limited. All rights reserved.

Current-induced transition from particle-by-particle to concurrent intercalation in phase-separating battery electrodes

KAUST Repository

Li, Yiyang; El Gabaly, Farid; Ferguson, Todd R.; Smith, Raymond B.; Bartelt, Norman C.; Sugar, Joshua D.; Fenton, Kyle R.; Cogswell, Daniel A.; Kilcoyne, A. L. David; Tyliszczak, Tolek; Bazant, Martin Z.; Chueh, William C.

2014-01-01

©2014 Macmillan Publishers Limited. All rights reserved. Many battery electrodes contain ensembles of nanoparticles that phase-separate on (de)intercalation. In such electrodes, the fraction of actively intercalating particles directly impacts cycle life: a vanishing population concentrates the current in a small number of particles, leading to current hotspots. Reports of the active particle population in the phase-separating electrode lithium iron phosphate (LiFePO 4; LFP) vary widely, ranging from near 0% (particle-by-particle) to 100% (concurrent intercalation). Using synchrotron-based X-ray microscopy, we probed the individual state-of-charge for over 3,000 LFP particles. We observed that the active population depends strongly on the cycling current, exhibiting particle-by-particle-like behaviour at low rates and increasingly concurrent behaviour at high rates, consistent with our phase-field porous electrode simulations. Contrary to intuition, the current density, or current per active internal surface area, is nearly invariant with the global electrode cycling rate. Rather, the electrode accommodates higher current by increasing the active particle population. This behaviour results from thermodynamic transformation barriers in LFP, and such a phenomenon probably extends to other phase-separating battery materials. We propose that modifying the transformation barrier and exchange current density can increase the active population and thus the current homogeneity. This could introduce new paradigms to enhance the cycle life of phase-separating battery electrodes.

Enzymatic catalysis of anti-Baldwin ring closure in polyether biosynthesis.

Science.gov (United States)

Hotta, Kinya; Chen, Xi; Paton, Robert S; Minami, Atsushi; Li, Hao; Swaminathan, Kunchithapadam; Mathews, Irimpan I; Watanabe, Kenji; Oikawa, Hideaki; Houk, Kendall N; Kim, Chu-Young

2012-03-04

Polycyclic polyether natural products have fascinated chemists and biologists alike owing to their useful biological activity, highly complex structure and intriguing biosynthetic mechanisms. Following the original proposal for the polyepoxide origin of lasalocid and isolasalocid and the experimental determination of the origins of the oxygen and carbon atoms of both lasalocid and monensin, a unified stereochemical model for the biosynthesis of polyether ionophore antibiotics was proposed. The model was based on a cascade of nucleophilic ring closures of postulated polyepoxide substrates generated by stereospecific oxidation of all-trans polyene polyketide intermediates. Shortly thereafter, a related model was proposed for the biogenesis of marine ladder toxins, involving a series of nominally disfavoured anti-Baldwin, endo-tet epoxide-ring-opening reactions. Recently, we identified Lsd19 from the Streptomyces lasaliensis gene cluster as the epoxide hydrolase responsible for the epoxide-opening cyclization of bisepoxyprelasalocid A to form lasalocid A. Here we report the X-ray crystal structure of Lsd19 in complex with its substrate and product analogue to provide the first atomic structure-to our knowledge-of a natural enzyme capable of catalysing the disfavoured epoxide-opening cyclic ether formation. On the basis of our structural and computational studies, we propose a general mechanism for the enzymatic catalysis of polyether natural product biosynthesis. © 2012 Macmillan Publishers Limited. All rights reserved

Genomic analyses inform on migration events during the peopling of Eurasia

KAUST Repository

Pagani, Luca

2016-09-20

High-Coverage whole-genome sequence studies have so far focused on a limited number of geographically restricted populations, or been targeted at specific diseases, such as cancer. Nevertheless, the availability of high-resolution genomic data has led to the development of new methodologies for inferring population history and refuelled the debate on the mutation rate in humans. Here we present the Estonian Biocentre Human Genome Diversity Panel (EGDP), a dataset of 483 high-coverage human genomes from 148 populations worldwide, including 379 new genomes from 125 populations, which we group into diversity and selection sets. We analyse this dataset to refine estimates of continent-wide patterns of heterozygosity, long-and short-distance gene flow, archaic admixture, and changes in effective population size through time as well as for signals of positive or balancing selection. We find a genetic signature in present-day Papuans that suggests that at least 2% of their genome originates from an early and largely extinct expansion of anatomically modern humans (AMHs) out of Africa. Together with evidence from the western Asian fossil record, and admixture between AMHs and Neanderthals predating the main Eurasian expansion, our results contribute to the mounting evidence for the presence of AMHs out of Africa earlier than 75,000 years ago. © 2016 Macmillan Publishers Limited, part of Springer Nature.

Reduction of thermal conductivity in phononic nanomesh structures

KAUST Repository

Yu, Jen-Kan

2010-07-25

Controlling the thermal conductivity of a material independently of its electrical conductivity continues to be a goal for researchers working on thermoelectric materials for use in energy applications1,2 and in the cooling of integrated circuits3. In principle, the thermal conductivity κ and the electrical conductivity σ may be independently optimized in semiconducting nanostructures because different length scales are associated with phonons (which carry heat) and electric charges (which carry current). Phonons are scattered at surfaces and interfaces, so κ generally decreases as the surface-to-volume ratio increases. In contrast, σ is less sensitive to a decrease in nanostructure size, although at sufficiently small sizes it will degrade through the scattering of charge carriers at interfaces. Here, we demonstrate an approach to independently controlling κ based on altering the phonon band structure of a semiconductor thin film through the formation of a phononic nanomesh film. These films are patterned with periodic spacings that are comparable to, or shorter than, the phonon mean free path. The nanomesh structure exhibits a substantially lower thermal conductivity than an equivalently prepared array of silicon nanowires, even though this array has a significantly higher surface-to-volume ratio. Bulk-like electrical conductivity is preserved. We suggest that this development is a step towards a coherent mechanism for lowering thermal conductivity. © 2010 Macmillan Publishers Limited. All rights reserved.

An RNA polymerase II-and AGO4-associated protein acts in RNA-directed DNA methylation

KAUST Repository

Gao, Zhihuan

2010-04-21

DNA methylation is an important epigenetic mark in many eukaryotes. In plants, 24-nucleotide small interfering RNAs (siRNAs) bound to the effector protein, Argonaute 4 (AGO4), can direct de novo DNA methylation by the methyltransferase DRM2 (refs 2, 4-6). Here we report a new regulator of RNA-directed DNA methylation (RdDM) in Arabidopsis: RDM1. Loss-of-function mutations in the RDM1 gene impair the accumulation of 24-nucleotide siRNAs, reduce DNA methylation, and release transcriptional gene silencing at RdDM target loci. RDM1 encodes a small protein that seems to bind single-stranded methyl DNA, and associates and co-localizes with RNA polymerase II (Pol II, also known as NRPB), AGO4 and DRM2 in the nucleus. Our results indicate that RDM1 is a component of the RdDM effector complex and may have a role in linking siRNA production with pre-existing or de novo cytosine methylation. Our results also indicate that, although RDM1 and Pol V (also known as NRPE) may function together at some RdDM target sites in the peri-nucleolar siRNA processing centre, Pol II rather than Pol V is associated with the RdDM effector complex at target sites in the nucleoplasm. © 2010 Macmillan Publishers Limited. All rights reserved.

Can comprehensive specialised end-of-life care be provided at home? Lessons from a study of an innovative consultant-led community service in the UK.

Science.gov (United States)

Noble, B; King, N; Woolmore, A; Hughes, P; Winslow, M; Melvin, J; Brooks, J; Bravington, A; Ingleton, C; Bath, P A

2015-03-01

The Midhurst Macmillan Specialist Palliative Care Service (MMSPCS) is a UK, medical consultant-led, multidisciplinary team aiming to provide round-the-clock advice and care, including specialist interventions, in the home, community hospitals and care homes. Of 389 referrals in 2010/11, about 85% were for cancer, from a population of about 155 000. Using a mixed method approach, the evaluation comprised: a retrospective analysis of secondary-care use in the last year of life; financial evaluation of the MMSPCS using an Activity Based Costing approach; qualitative interviews with patients, carers, health and social care staff and MMSPCS staff and volunteers; a postal survey of General Practices; and a postal survey of bereaved caregivers using the MMSPCS. The mean cost is about 3000 GBP (3461 EUR) per patient with mean cost of interventions for cancer patients in the last year of life 1900 GBP (2192 EUR). Post-referral, overall costs to the system are similar for MMSPCS and hospice-led models; however, earlier referral avoided around 20% of total costs in the last year of life. Patients and carers reported positive experiences of support, linked to the flexible way the service worked. Seventy-one per cent of patients died at home. This model may have application elsewhere. © 2014 The Authors. European Journal of Cancer Care published by John Wiley & Sons Ltd.

The small academic press in the land of giants

Directory of Open Access Journals (Sweden)

Frances Pinter

2015-11-01

Full Text Available Mergers and acquisitions, for example the merger of Macmillan Science and Education with Springer Science+Business Media, might suggest that large is the future for academic publishing.  It might seem that giant players will dominate the future of scholarly publishing, but, at the same time, this year has seen the launch of UCL Press, the University’s in-house publishing arm. Goldsmiths, University of London, has also announced it is preparing to launch Goldsmiths Press, a new university press built on digital-first publishing, especially around unconventional projects traditionally excluded by publishers. Some of the more established university presses also seem to be increasing their scope. For example, Stanford University Press launched a new trade imprint and Manchester University Press has announced it has acquired forward titles from Bloomsbury Publishing.  'Insights 'asked two experts if there really is scope for the small academic press in the modern scholarly publishing environment. Frances Pinter has provided the perspective of the small university press. She is realistic about the challenges small academic publishers face, but concludes that there is space and opportunity for them to coexist with the giants. Michael Magoulias is equally realistic about the challenges of small, but sees the university press as a necessary, not to say, vital, alternative to commercial publishing.

Genomic analyses inform on migration events during the peopling of Eurasia

KAUST Repository

Pagani, Luca; Lawson, Daniel John; Jagoda, Evelyn; Mö rseburg, Alexander; Eriksson, Anders; Mitt, Mario; Clemente, Florian; Hudjashov, Georgi; DeGiorgio, Michael; Saag, Lauri; Wall, Jeffrey D.; Cardona, Alexia; Mä gi, Reedik; Sayres, Melissa A. Wilson; Kaewert, Sarah; Inchley, Charlotte; Scheib, Christiana L.; Jä rve, Mari; Karmin, Monika; Jacobs, Guy S.; Antao, Tiago; Iliescu, Florin Mircea; Kushniarevich, Alena; Ayub, Qasim; Tyler-Smith, Chris; Xue, Yali; Yunusbayev, Bayazit; Tambets, Kristiina; Mallick, Chandana Basu; Saag, Lehti; Pocheshkhova, Elvira; Andriadze, George; Muller, Craig; Westaway, Michael C.; Lambert, David M.; Zoraqi, Grigor; Turdikulova, Shahlo; Dalimova, Dilbar; Sabitov, Zhaxylyk; Sultana, Gazi Nurun Nahar; Lachance, Joseph; Tishkoff, Sarah; Momynaliev, Kuvat; Isakova, Jainagul; Damba, Larisa D.; Gubina, Marina; Nymadawa, Pagbajabyn; Evseeva, Irina; Atramentova, Lubov; Utevska, Olga; Ricaut, Franç ois-Xavier; Brucato, Nicolas; Sudoyo, Herawati; Letellier, Thierry; Cox, Murray P.; Barashkov, Nikolay A.; Škaro, Vedrana; Mulahasanovic´ , Lejla; Primorac, Dragan; Sahakyan, Hovhannes; Mormina, Maru; Eichstaedt, Christina A.; Lichman, Daria V.; Abdullah, Syafiq; Chaubey, Gyaneshwer; Wee, Joseph T. S.; Mihailov, Evelin; Karunas, Alexandra; Litvinov, Sergei; Khusainova, Rita; Ekomasova, Natalya; Akhmetova, Vita; Khidiyatova, Irina; Marjanović, Damir; Yepiskoposyan, Levon; Behar, Doron M.; Balanovska, Elena; Metspalu, Andres; Derenko, Miroslava; Malyarchuk, Boris; Voevoda, Mikhail; Fedorova, Sardana A.; Osipova, Ludmila P.; Lahr, Marta Mirazó n; Gerbault, Pascale; Leavesley, Matthew; Migliano, Andrea Bamberg; Petraglia, Michael; Balanovsky, Oleg; Khusnutdinova, Elza K.; Metspalu, Ene; Thomas, Mark G.; Manica, Andrea; Nielsen, Rasmus; Villems, Richard; Willerslev, Eske; Kivisild, Toomas; Metspalu, Mait

2016-01-01

High-Coverage whole-genome sequence studies have so far focused on a limited number of geographically restricted populations, or been targeted at specific diseases, such as cancer. Nevertheless, the availability of high-resolution genomic data has led to the development of new methodologies for inferring population history and refuelled the debate on the mutation rate in humans. Here we present the Estonian Biocentre Human Genome Diversity Panel (EGDP), a dataset of 483 high-coverage human genomes from 148 populations worldwide, including 379 new genomes from 125 populations, which we group into diversity and selection sets. We analyse this dataset to refine estimates of continent-wide patterns of heterozygosity, long-and short-distance gene flow, archaic admixture, and changes in effective population size through time as well as for signals of positive or balancing selection. We find a genetic signature in present-day Papuans that suggests that at least 2% of their genome originates from an early and largely extinct expansion of anatomically modern humans (AMHs) out of Africa. Together with evidence from the western Asian fossil record, and admixture between AMHs and Neanderthals predating the main Eurasian expansion, our results contribute to the mounting evidence for the presence of AMHs out of Africa earlier than 75,000 years ago. © 2016 Macmillan Publishers Limited, part of Springer Nature.

Complex rupture during the 12 January 2010 Haiti earthquake

Science.gov (United States)

Hayes, G.P.; Briggs, R.W.; Sladen, A.; Fielding, E.J.; Prentice, C.; Hudnut, K.; Mann, P.; Taylor, F.W.; Crone, A.J.; Gold, R.; Ito, T.; Simons, M.

2010-01-01

Initially, the devastating Mw 7.0, 12 January 2010 Haiti earthquake seemed to involve straightforward accommodation of oblique relative motion between the Caribbean and North American plates along the Enriquillog-Plantain Garden fault zone. Here, we combine seismological observations, geologic field data and space geodetic measurements to show that, instead, the rupture process may have involved slip on multiple faults. Primary surface deformation was driven by rupture on blind thrust faults with only minor, deep, lateral slip along or near the main Enriquillog-Plantain Garden fault zone; thus the event only partially relieved centuries of accumulated left-lateral strain on a small part of the plate-boundary system. Together with the predominance of shallow off-fault thrusting, the lack of surface deformation implies that remaining shallow shear strain will be released in future surface-rupturing earthquakes on the Enriquillog-Plantain Garden fault zone, as occurred in inferred Holocene and probable historic events. We suggest that the geological signature of this earthquakeg-broad warping and coastal deformation rather than surface rupture along the main fault zoneg-will not be easily recognized by standard palaeoseismic studies. We conclude that similarly complex earthquakes in tectonic environments that accommodate both translation and convergenceg-such as the San Andreas fault through the Transverse Ranges of Californiag-may be missing from the prehistoric earthquake record. ?? 2010 Macmillan Publishers Limited. All rights reserved.

Seismic hazard of the Enriquillog-Plantain Garden fault in Haiti inferred from palaeoseismology

Science.gov (United States)

Prentice, C.S.; Mann, P.; Crone, A.J.; Gold, R.D.; Hudnut, K.W.; Briggs, R.W.; Koehler, R.D.; Jean, P.

2010-01-01

The Enriquillog-Plantain Garden fault zone is recognized as one of the primary plate-bounding fault systems in Haiti. The strike-slip fault runs adjacent to the city of Port-au-Prince and was initially thought to be the source of the 12 January 2010, M w 7.0 earthquake. Haiti experienced significant earthquakes in 1751 and 1770 (refsA, 3, 4, 5), but the role of the Enriquillog-Plantain Garden fault zone in these earthquakes is poorly known. We use satellite imagery, aerial photography, light detection and ranging (LIDAR) and field investigations to document Quaternary activity on the Enriquillog-Plantain Garden fault. We report late Quaternary, left-lateral offsets of up to 160m, and a set of small offsets ranging from 1.3 to 3.3m that we associate with one of the eighteenth century earthquakes. The size of the small offsets implies that the historical earthquake was larger than M w 7.0, but probably smaller than M w 7.6. We found no significant surface rupture associated with the 2010 earthquake. The lack of surface rupture, coupled with other seismologic, geologic and geodetic observations, suggests that little, if any, accumulated strain was released on the Enriquillog-Plantain Garden fault in the 2010 earthquake. These results confirm that the Enriquillog-Plantain Garden fault remains a significant seismic hazard. ?? 2010 Macmillan Publishers Limited. All rights reserved.

Current-induced transition from particle-by-particle to concurrent intercalation in phase-separating battery electrodes

KAUST Repository

Li, Yiyang

2014-09-14

©2014 Macmillan Publishers Limited. All rights reserved. Many battery electrodes contain ensembles of nanoparticles that phase-separate on (de)intercalation. In such electrodes, the fraction of actively intercalating particles directly impacts cycle life: a vanishing population concentrates the current in a small number of particles, leading to current hotspots. Reports of the active particle population in the phase-separating electrode lithium iron phosphate (LiFePO 4; LFP) vary widely, ranging from near 0% (particle-by-particle) to 100% (concurrent intercalation). Using synchrotron-based X-ray microscopy, we probed the individual state-of-charge for over 3,000 LFP particles. We observed that the active population depends strongly on the cycling current, exhibiting particle-by-particle-like behaviour at low rates and increasingly concurrent behaviour at high rates, consistent with our phase-field porous electrode simulations. Contrary to intuition, the current density, or current per active internal surface area, is nearly invariant with the global electrode cycling rate. Rather, the electrode accommodates higher current by increasing the active particle population. This behaviour results from thermodynamic transformation barriers in LFP, and such a phenomenon probably extends to other phase-separating battery materials. We propose that modifying the transformation barrier and exchange current density can increase the active population and thus the current homogeneity. This could introduce new paradigms to enhance the cycle life of phase-separating battery electrodes.

Landslide movement in southwest Colorado triggered by atmospheric tides

Science.gov (United States)

Schulz, W.H.; Kean, J.W.; Wang, G.

2009-01-01

Landslides are among the most hazardous of geological processes, causing thousands of casualties and damage on the order of billions of dollars annually. The movement of most landslides occurs along a discrete shear surface, and is triggered by a reduction in the frictional strength of the surface. Infiltration of water into the landslide from rainfall and snowmelt and ground motion from earthquakes are generally implicated in lowering the frictional strength of this surface. However, solid-Earth and ocean tides have recently been shown to trigger shear sliding in other processes, such as earthquakes and glacial motion. Here we use observations and numerical modelling to show that a similar processatmospheric tidescan trigger movement in an ongoing landslide. The Slumgullion landslide, located in the SanJuan Mountains of Colorado, shows daily movement, primarily during diurnal low tides of the atmosphere. According to our model, the tidal changes in air pressure cause air and water in the sediment pores to flow vertically, altering the frictional stress of the shear surface; upward fluid flow during periods of atmospheric low pressure is most conducive to sliding. We suggest that tidally modulated changes in shear strength may also affect the stability of other landslides, and that the rapid pressure variations associated with some fast-moving storm systems could trigger a similar response. ?? 2009 Macmillan Publishers Limited. All rights reserved.

Triggered creep as a possible mechanism for delayed dynamic triggering of tremor and earthquakes

Science.gov (United States)

Shelly, David R.; Peng, Zhigang; Hill, David P.; Aiken, Chastity

2011-01-01

The passage of radiating seismic waves generates transient stresses in the Earth's crust that can trigger slip on faults far away from the original earthquake source. The triggered fault slip is detectable in the form of earthquakes and seismic tremor. However, the significance of these triggered events remains controversial, in part because they often occur with some delay, long after the triggering stress has passed. Here we scrutinize the location and timing of tremor on the San Andreas fault between 2001 and 2010 in relation to distant earthquakes. We observe tremor on the San Andreas fault that is initiated by passing seismic waves, yet migrates along the fault at a much slower velocity than the radiating seismic waves. We suggest that the migrating tremor records triggered slow slip of the San Andreas fault as a propagating creep event. We find that the triggered tremor and fault creep can be initiated by distant earthquakes as small as magnitude 5.4 and can persist for several days after the seismic waves have passed. Our observations of prolonged tremor activity provide a clear example of the delayed dynamic triggering of seismic events. Fault creep has been shown to trigger earthquakes, and we therefore suggest that the dynamic triggering of prolonged fault creep could provide a mechanism for the delayed triggering of earthquakes. ?? 2011 Macmillan Publishers Limited. All rights reserved.

Recent reversal in loss of global terrestrial biomass

KAUST Repository

Liu, Yi Y.; Van Dijk, Albert I J M; De Jeu, Richard A M; Canadell., Josep G.; McCabe, Matthew; Evans, Jason P.; Wang, Guojie

2015-01-01

Vegetation change plays a critical role in the Earth's carbon (C) budget and its associated radiative forcing in response to anthropogenic and natural climate change. Existing global estimates of aboveground biomass carbon (ABC) based on field survey data provide brief snapshots that are mainly limited to forest ecosystems. Here we use an entirely new remote sensing approach to derive global ABC estimates for both forest and non-forest biomes during the past two decades from satellite passive microwave observations. We estimate a global average ABC of 362 PgC over the period 1998-2002, of which 65% is in forests and 17% in savannahs. Over the period 1993-2012, an estimated '0.07 PgC yr '1 ABC was lost globally, mostly resulting from the loss of tropical forests ('0.26 PgC yr '1) and net gains in mixed forests over boreal and temperate regions (+0.13 PgC yr '1) and tropical savannahs and shrublands (+0.05 PgC yr '1). Interannual ABC patterns are greatly influenced by the strong response of water-limited ecosystems to rainfall variability, particularly savannahs. From 2003 onwards, forest in Russia and China expanded and tropical deforestation declined. Increased ABC associated with wetter conditions in the savannahs of northern Australia and southern Africa reversed global ABC loss, leading to an overall gain, consistent with trends in the global carbon sink reported in recent studies. © 2015 Macmillan Publishers Limited. All rights reserved.

Measurement of interaction between antiprotons

Energy Technology Data Exchange (ETDEWEB)

Adamczyk, L.; Adkins, J. K.; Agakishiev, G.; Aggarwal, M. M.; Ahammed, Z.; Alekseev, I.; Alford, J.; Aparin, A.; Arkhipkin, D.; Aschenauer, E. C.; Averichev, G. S.; Bairathi, V.; Banerjee, A.; Bellwied, R.; Bhasin, A.; Bhati, A. K.; Bhattarai, P.; Bielcik, J.; Bielcikova, J.; Bland, L. C.; Bordyuzhin, I. G.; Bouchet, J.; Brandenburg, J. D.; Brandin, A. V.; Bunzarov, I.; Butterworth, J.; Caines, H.; Calderón de la Barca Sánchez, M.; Campbell, J. M.; Cebra, D.; Cervantes, M. C.; Chakaberia, I.; Chaloupka, P.; Chang, Z.; Chattopadhyay, S.; Chen, J. H.; Chen, X.; Cheng, J.; Cherney, M.; Christie, W.; Contin, G.; Crawford, H. J.; Das, S.; De Silva, L. C.; Debbe, R. R.; Dedovich, T. G.; Deng, J.; Derevschikov, A. A.; di Ruzza, B.; Didenko, L.; Dilks, C.; Dong, X.; Drachenberg, J. L.; Draper, J. E.; Du, C. M.; Dunkelberger, L. E.; Dunlop, J. C.; Efimov, L. G.; Engelage, J.; Eppley, G.; Esha, R.; Evdokimov, O.; Eyser, O.; Fatemi, R.; Fazio, S.; Federic, P.; Fedorisin, J.; Feng, Z.; Filip, P.; Fisyak, Y.; Flores, C. E.; Fulek, L.; Gagliardi, C. A.; Garand, D.; Geurts, F.; Gibson, A.; Girard, M.; Greiner, L.; Grosnick, D.; Gunarathne, D. S.; Guo, Y.; Gupta, A.; Gupta, S.; Guryn, W.; Hamad, A.; Hamed, A.; Haque, R.; Harris, J. W.; He, L.; Heppelmann, S.; Heppelmann, S.; Hirsch, A.; Hoffmann, G. W.; Hofman, D. J.; Horvat, S.; Huang, B.; Huang, H. Z.; Huang, X.; Huck, P.; Humanic, T. J.; Igo, G.; Jacobs, W. W.; Jang, H.; Jiang, K.; Judd, E. G.; Kabana, S.; Kalinkin, D.; Kang, K.; Kauder, K.; Ke, H. W.; Keane, D.; Kechechyan, A.; Khan, Z. H.; Kikoła, D. P.; Kisel, I.; Kisiel, A.; Klein, S.; Kochenda, L.; Koetke, D. D.; Kollegger, T.; Kosarzewski, L. K.; Kraishan, A. F.; Kravtsov, P.; Krueger, K.; Kulakov, I.; Kumar, L.; Kycia, R. A.; Lamont, M. A. C.; Landgraf, J. M.; Landry, K. D.; Lauret, J.; Lebedev, A.; Lednicky, R.; Lee, J. H.; Li, X.; Li, Z. M.; Li, Y.; Li, W.; Li, X.; Li, C.; Lisa, M. A.; Liu, F.; Ljubicic, T.; Llope, W. J.; Lomnitz, M.; Longacre, R. S.; Luo, X.; Ma, G. L.; Ma, R.; Ma, Y. G.; Ma, L.; Magdy, N.; Majka, R.; Manion, A.; Margetis, S.; Markert, C.; Masui, H.; Matis, H. S.; McDonald, D.; Meehan, K.; Minaev, N. G.; Mioduszewski, S.; Mishra, D.; Mohanty, B.; Mondal, M. M.; Morozov, D. A.; Mustafa, M. K.; Nandi, B. K.; Nasim, Md.; Nayak, T. K.; Nigmatkulov, G.; Nogach, L. V.; Noh, S. Y.; Novak, J.; Nurushev, S. B.; Odyniec, G.; Ogawa, A.; Oh, K.; Okorokov, V.; Olvitt, D.; Page, B. S.; Pak, R.; Pan, Y. X.; Pandit, Y.; Panebratsev, Y.; Pawlik, B.; Pei, H.; Perkins, C.; Peterson, A.; Pile, P.; Planinic, M.; Pluta, J.; Poljak, N.; Poniatowska, K.; Porter, J.; Posik, M.; Poskanzer, A. M.; Putschke, J.; Qiu, H.; Quintero, A.; Ramachandran, S.; Raniwala, R.; Raniwala, S.; Ray, R. L.; Ritter, H. G.; Roberts, J. B.; Rogachevskiy, O. V.; Romero, J. L.; Roy, A.; Ruan, L.; Rusnak, J.; Rusnakova, O.; Sahoo, N. R.; Sahu, P. K.; Sakrejda, I.; Salur, S.; Sandweiss, J.; Sarkar, A.; Schambach, J.; Scharenberg, R. P.; Schmah, A. M.; Schmidke, W. B.; Schmitz, N.; Seger, J.; Seyboth, P.; Shah, N.; Shahaliev, E.; Shanmuganathan, P. V.; Shao, M.; Sharma, M. K.; Sharma, B.; Shen, W. Q.; Shi, S. S.; Shou, Q. Y.; Sichtermann, E. P.; Sikora, R.; Simko, M.; Skoby, M. J.; Smirnov, N.; Smirnov, D.; Song, L.; Sorensen, P.; Spinka, H. M.; Srivastava, B.; Stanislaus, T. D. S.; Stepanov, M.; Stock, R.; Strikhanov, M.; Stringfellow, B.; Sumbera, M.; Summa, B.; Sun, Z.; Sun, X. M.; Sun, Y.; Sun, X.; Surrow, B.; Svirida, N.; Szelezniak, M. A.; Tang, Z.; Tang, A. H.; Tarnowsky, T.; Tawfik, A.; Thomas, J. H.; Timmins, A. R.; Tlusty, D.; Tokarev, M.; Trentalange, S.; Tribble, R. E.; Tribedy, P.; Tripathy, S. K.; Trzeciak, B. A.; Tsai, O. D.; Ullrich, T.; Underwood, D. G.; Upsal, I.; Van Buren, G.; van Nieuwenhuizen, G.; Vandenbroucke, M.; Varma, R.; Vasiliev, A. N.; Vertesi, R.; Videbæk, F.; Viyogi, Y. P.; Vokal, S.; Voloshin, S. A.; Vossen, A.; Wang, G.; Wang, H.; Wang, J. S.; Wang, Y.; Wang, Y.; Wang, F.; Webb, J. C.; Webb, G.; Wen, L.; Westfall, G. D.; Wieman, H.; Wissink, S. W.; Witt, R.; Wu, Y. F.; Xiao, Z. G.; Xie, W.; Xin, K.; Xu, Y. F.; Xu, Q. H.; Xu, H.; Xu, N.; Xu, Z.; Yang, Y.; Yang, C.; Yang, S.; Yang, Y.; Yang, Q.; Ye, Z.; Yepes, P.; Yi, L.; Yip, K.; Yoo, I. -K.; Yu, N.; Zbroszczyk, H.; Zha, W.; Zhang, J. B.; Zhang, Z.; Zhang, J.; Zhang, S.; Zhang, X. P.; Zhang, J.; Zhang, Y.; Zhao, J.; Zhong, C.; Zhou, L.; Zhu, X.; Zoulkarneeva, Y.; Zyzak, M.

2015-11-04

© 2015 Macmillan Publishers Limited. All rights reserved. One of the primary goals of nuclear physics is to understand the force between nucleons, which is a necessary step for understanding the structure of nuclei and how nuclei interact with each other. Rutherford discovered the atomic nucleus in 1911, and the large body of knowledge about the nuclear force that has since been acquired was derived from studies made on nucleons or nuclei. Although antinuclei up to antihelium-4 have been discovered and their masses measured, little is known directly about the nuclear force between antinucleons. Here, we study antiproton pair correlations among data collected by the STAR experiment at the Relativistic Heavy Ion Collider (RHIC), where gold ions are collided with a centre-of-mass energy of 200 gigaelectronvolts per nucleon pair. Antiprotons are abundantly produced in such collisions, thus making it feasible to study details of the antiproton-antiproton interaction. By applying a technique similar to Hanbury Brown and Twiss intensity interferometry, we show that the force between two antiprotons is attractive. In addition, we report two key parameters that characterize the corresponding strong interaction: the scattering length and the effective range of the interaction. Our measured parameters are consistent within errors with the corresponding values for proton-proton interactions. Our results provide direct information on the interaction between two antiprotons, one of the simplest systems of antinucleons, and so are fundamental to understanding the structure of more-complex antinuclei and the ir properties.

The 2009 Samoa-Tonga great earthquake triggered doublet

Science.gov (United States)

Lay, T.; Ammon, C.J.; Kanamori, H.; Rivera, L.; Koper, K.D.; Hutko, Alexander R.

2010-01-01

Great earthquakes (having seismic magnitudes of at least 8) usually involve abrupt sliding of rock masses at a boundary between tectonic plates. Such interplate ruptures produce dynamic and static stress changes that can activate nearby intraplate aftershocks, as is commonly observed in the trench-slope region seaward of a great subduction zone thrust event1-4. The earthquake sequence addressed here involves a rare instance in which a great trench-slope intraplate earthquake triggered extensive interplate faulting, reversing the typical pattern and broadly expanding the seismic and tsunami hazard. On 29 September 2009, within two minutes of the initiation of a normal faulting event with moment magnitude 8.1 in the outer trench-slope at the northern end of the Tonga subduction zone, two major interplate underthrusting subevents (both with moment magnitude 7.8), with total moment equal to a second great earthquake of moment magnitude 8.0, ruptured the nearby subduction zone megathrust. The collective faulting produced tsunami waves with localized regions of about 12metres run-up that claimed 192 lives in Samoa, American Samoa and Tonga. Overlap of the seismic signals obscured the fact that distinct faults separated by more than 50km had ruptured with different geometries, with the triggered thrust faulting only being revealed by detailed seismic wave analyses. Extensive interplate and intraplate aftershock activity was activated over a large region of the northern Tonga subduction zone. ?? 2010 Macmillan Publishers Limited. All rights reserved.

Old Wine in New Bottles? Does Climate Policy Determine Bilateral Development Aid for Renewable Energy and Energy Efficiency?

Directory of Open Access Journals (Sweden)

Axel Michaelowa

2011-05-01

Full Text Available Published by Palgrave MacmillanSince the UN Conference on Environment and Development in Rio de Janeiro in 1992 bilateral and multilateral donors have stressed that development assistance has increasingly been oriented towards climate-friendly interventions. With respect to energy aid, this should lead to a substantial increase in projects related to renewable energy and energy efficiency. Given a new database of hundreds of thousands of bilateral development assistance projects, we can assess whether such a reorientation has indeed taken place. We find that, contrary to expectations, the share of bilaterally-funded renewable energy and energy efficiency projects did not increase over the period from 1980 to 2008. This share fluctuated greatly, following the price of oil, peaking with the second oil crisis of the early 1980s. The impacts of global climate policy treaties are minor or inexistent. ‘Traditional’ renewable energies such as hydro and geothermal declined, while “new” renewables showed two peaks in the early 1980s and late 1990s. Differences between donor countries are huge. Several countries, including climate sceptics such as the US and Australia, but also the UK and Switzerland, saw a consistent decline. The self-proclaimed climate pioneers such as Germany, the Netherlands, Norway and Sweden show peaks related to both the oil crises and international climate policy. Only in Austria, Denmark, Finland and Spain can ‘new’ climate mitigation development assistance be found.

Broad accommodation of rift-related extension recorded by dyke intrusion in Saudi Arabia

KAUST Repository

Pallister, John S.

2010-09-26

The extensive harrat lava province of Arabia formed during the past 30 million years in response to Red Sea rifting and mantle upwelling. The area was regarded as seismically quiet, but between April and June 2009 a swarm of more than 30,000 earthquakes struck one of the lava fields in the province, Harrat Lunayyir, northwest Saudi Arabia. Concerned that larger damaging earthquakes might occur, the Saudi Arabian government evacuated 40,000 people from the region. Here we use geologic, geodetic and seismic data to show that the earthquake swarm resulted from magmatic dyke intrusion. We document a surface fault rupture that is 8 km long with 91 cm of offset. Surface deformation is best modelled by the shallow intrusion of a north-west trending dyke that is about 10 km long. Seismic waves generated during the earthquakes exhibit overlapping very low- and high-frequency components. We interpret the low frequencies to represent intrusion of magma and the high frequencies to represent fracturing of the crystalline basement rocks. Rather than extension being accommodated entirely by the central Red Sea rift axis, we suggest that the broad deformation observed in Harrat Lunayyir indicates that rift margins can remain as active sites of extension throughout rifting. Our analyses allowed us to forecast the likelihood of a future eruption or large earthquake in the region and informed the decisions made by the Saudi Arabian government to return the evacuees. © 2010 Macmillan Publishers Limited. All rights reserved.

Ambipolar field effect in the ternary topological insulator (BixSb1–x)2Te3 by composition tuning

KAUST Repository

Kong, Desheng

2011-10-02

Topological insulators exhibit a bulk energy gap and spin-polarized surface states that lead to unique electronic properties 1-9, with potential applications in spintronics and quantum information processing. However, transport measurements have typically been dominated by residual bulk charge carriers originating from crystal defects or environmental doping 10-12, and these mask the contribution of surface carriers to charge transport in these materials. Controlling bulk carriers in current topological insulator materials, such as the binary sesquichalcogenides Bi 2Te 3, Sb 2Te 3 and Bi 2Se 3, has been explored extensively by means of material doping 8,9,11 and electrical gating 13-16, but limited progress has been made to achieve nanostructures with low bulk conductivity for electronic device applications. Here we demonstrate that the ternary sesquichalcogenide (Bi xSb 1-x) 2Te 3 is a tunable topological insulator system. By tuning the ratio of bismuth to antimony, we are able to reduce the bulk carrier density by over two orders of magnitude, while maintaining the topological insulator properties. As a result, we observe a clear ambipolar gating effect in (Bi xSb 1-x) 2Te 3 nanoplate field-effect transistor devices, similar to that observed in graphene field-effect transistor devices 17. The manipulation of carrier type and density in topological insulator nanostructures demonstrated here paves the way for the implementation of topological insulators in nanoelectronics and spintronics. © 2011 Macmillan Publishers Limited. All rights reserved.

Quantum-dot-in-perovskite solids

KAUST Repository

Ning, Zhijun; Gong, Xiwen; Comin, Riccardo; Walters, Grant; Fan, Fengjia; Voznyy, Oleksandr; Yassitepe, Emre; Buin, Andrei; Hoogland, Sjoerd; Sargent, Edward H.

2015-01-01

© 2015 Macmillan Publishers Limited. All rights reserved. Heteroepitaxy - atomically aligned growth of a crystalline film atop a different crystalline substrate - is the basis of electrically driven lasers, multijunction solar cells, and blue-light-emitting diodes. Crystalline coherence is preserved even when atomic identity is modulated, a fact that is the critical enabler of quantum wells, wires, and dots. The interfacial quality achieved as a result of heteroepitaxial growth allows new combinations of materials with complementary properties, which enables the design and realization of functionalities that are not available in the single-phase constituents. Here we show that organohalide perovskites and preformed colloidal quantum dots, combined in the solution phase, produce epitaxially aligned 'dots-in-a-matrix' crystals. Using transmission electron microscopy and electron diffraction, we reveal heterocrystals as large as about 60 nanometres and containing at least 20 mutually aligned dots that inherit the crystalline orientation of the perovskite matrix. The heterocrystals exhibit remarkable optoelectronic properties that are traceable to their atom-scale crystalline coherence: photoelectrons and holes generated in the larger-bandgap perovskites are transferred with 80% efficiency to become excitons in the quantum dot nanocrystals, which exploit the excellent photocarrier diffusion of perovskites to produce bright-light emission from infrared-bandgap quantum-tuned materials. By combining the electrical transport properties of the perovskite matrix with the high radiative efficiency of the quantum dots, we engineer a new platform to advance solution-processed infrared optoelectronics.

High-fidelity projective read-out of a solid-state spin quantum register.

Science.gov (United States)

Robledo, Lucio; Childress, Lilian; Bernien, Hannes; Hensen, Bas; Alkemade, Paul F A; Hanson, Ronald

2011-09-21

Initialization and read-out of coupled quantum systems are essential ingredients for the implementation of quantum algorithms. Single-shot read-out of the state of a multi-quantum-bit (multi-qubit) register would allow direct investigation of quantum correlations (entanglement), and would give access to further key resources such as quantum error correction and deterministic quantum teleportation. Although spins in solids are attractive candidates for scalable quantum information processing, their single-shot detection has been achieved only for isolated qubits. Here we demonstrate the preparation and measurement of a multi-spin quantum register in a low-temperature solid-state system by implementing resonant optical excitation techniques originally developed in atomic physics. We achieve high-fidelity read-out of the electronic spin associated with a single nitrogen-vacancy centre in diamond, and use this read-out to project up to three nearby nuclear spin qubits onto a well-defined state. Conversely, we can distinguish the state of the nuclear spins in a single shot by mapping it onto, and subsequently measuring, the electronic spin. Finally, we show compatibility with qubit control: we demonstrate initialization, coherent manipulation and single-shot read-out in a single experiment on a two-qubit register, using techniques suitable for extension to larger registers. These results pave the way for a test of Bell's inequalities on solid-state spins and the implementation of measurement-based quantum information protocols. © 2011 Macmillan Publishers Limited. All rights reserved

Broad accommodation of rift-related extension recorded by dyke intrusion in Saudi Arabia

KAUST Repository

Pallister, John S.; McCausland, Wendy A.; Jonsson, Sigurjon; Lu, Zhong; Zahran, Hani M.; El-Hadidy, Salah Y.; Aburukbah, Abdallah; Stewart, Ian C F; Lundgren, Paul R.; White, Randal A.; Moufti, Mohammed Rashad H

2010-01-01

The extensive harrat lava province of Arabia formed during the past 30 million years in response to Red Sea rifting and mantle upwelling. The area was regarded as seismically quiet, but between April and June 2009 a swarm of more than 30,000 earthquakes struck one of the lava fields in the province, Harrat Lunayyir, northwest Saudi Arabia. Concerned that larger damaging earthquakes might occur, the Saudi Arabian government evacuated 40,000 people from the region. Here we use geologic, geodetic and seismic data to show that the earthquake swarm resulted from magmatic dyke intrusion. We document a surface fault rupture that is 8 km long with 91 cm of offset. Surface deformation is best modelled by the shallow intrusion of a north-west trending dyke that is about 10 km long. Seismic waves generated during the earthquakes exhibit overlapping very low- and high-frequency components. We interpret the low frequencies to represent intrusion of magma and the high frequencies to represent fracturing of the crystalline basement rocks. Rather than extension being accommodated entirely by the central Red Sea rift axis, we suggest that the broad deformation observed in Harrat Lunayyir indicates that rift margins can remain as active sites of extension throughout rifting. Our analyses allowed us to forecast the likelihood of a future eruption or large earthquake in the region and informed the decisions made by the Saudi Arabian government to return the evacuees. © 2010 Macmillan Publishers Limited. All rights reserved.

Quantum-dot-in-perovskite solids

KAUST Repository

Ning, Zhijun

2015-07-15

© 2015 Macmillan Publishers Limited. All rights reserved. Heteroepitaxy - atomically aligned growth of a crystalline film atop a different crystalline substrate - is the basis of electrically driven lasers, multijunction solar cells, and blue-light-emitting diodes. Crystalline coherence is preserved even when atomic identity is modulated, a fact that is the critical enabler of quantum wells, wires, and dots. The interfacial quality achieved as a result of heteroepitaxial growth allows new combinations of materials with complementary properties, which enables the design and realization of functionalities that are not available in the single-phase constituents. Here we show that organohalide perovskites and preformed colloidal quantum dots, combined in the solution phase, produce epitaxially aligned \\'dots-in-a-matrix\\' crystals. Using transmission electron microscopy and electron diffraction, we reveal heterocrystals as large as about 60 nanometres and containing at least 20 mutually aligned dots that inherit the crystalline orientation of the perovskite matrix. The heterocrystals exhibit remarkable optoelectronic properties that are traceable to their atom-scale crystalline coherence: photoelectrons and holes generated in the larger-bandgap perovskites are transferred with 80% efficiency to become excitons in the quantum dot nanocrystals, which exploit the excellent photocarrier diffusion of perovskites to produce bright-light emission from infrared-bandgap quantum-tuned materials. By combining the electrical transport properties of the perovskite matrix with the high radiative efficiency of the quantum dots, we engineer a new platform to advance solution-processed infrared optoelectronics.

Recent reversal in loss of global terrestrial biomass

KAUST Repository

Liu, Yi Y.

2015-03-30

Vegetation change plays a critical role in the Earth\\'s carbon (C) budget and its associated radiative forcing in response to anthropogenic and natural climate change. Existing global estimates of aboveground biomass carbon (ABC) based on field survey data provide brief snapshots that are mainly limited to forest ecosystems. Here we use an entirely new remote sensing approach to derive global ABC estimates for both forest and non-forest biomes during the past two decades from satellite passive microwave observations. We estimate a global average ABC of 362 PgC over the period 1998-2002, of which 65% is in forests and 17% in savannahs. Over the period 1993-2012, an estimated \\'0.07 PgC yr \\'1 ABC was lost globally, mostly resulting from the loss of tropical forests (\\'0.26 PgC yr \\'1) and net gains in mixed forests over boreal and temperate regions (+0.13 PgC yr \\'1) and tropical savannahs and shrublands (+0.05 PgC yr \\'1). Interannual ABC patterns are greatly influenced by the strong response of water-limited ecosystems to rainfall variability, particularly savannahs. From 2003 onwards, forest in Russia and China expanded and tropical deforestation declined. Increased ABC associated with wetter conditions in the savannahs of northern Australia and southern Africa reversed global ABC loss, leading to an overall gain, consistent with trends in the global carbon sink reported in recent studies. © 2015 Macmillan Publishers Limited. All rights reserved.

Development and evaluation of radiographer led telephone follow up following radical radiotherapy to the prostate. A report of a Macmillan Cancer Support Sponsored Pilot project at Mount Vernon Hospital

International Nuclear Information System (INIS)

Verma, R.; Treasure, P.; Hughes, R.

2015-01-01

Radiotherapy for localised prostate cancer is an effective and well tolerated treatment. Following radiotherapy, most men are followed up either in doctor or specialist nurse led hospital outpatient clinics. Attending clinics may be of little personal benefit as the majority of patients have few ongoing symptoms post radiotherapy and have very good cancer prognoses. Recognising the limitations outpatient clinic follow up, we developed a radiographer led model of remote telephone follow up of patients completing radiotherapy for low to intermediate risk prostate cancer. Standardised toxicity assessments were performed and patient satisfaction assessed. Radiographer led follow up detected similar levels of post radiotherapy GI, GU and sexual toxicity as outpatient clinic appointments, with a very high level of patient satisfaction compared to routine outpatient clinics. We believe that radiographer led telephone follow up provides an alternative model for long term follow up of men after prostate radiotherapy

Stabilization of Leidenfrost vapour layer by textured superhydrophobic surfaces

KAUST Repository

Vakarelski, Ivan Uriev

2012-09-12

In 1756, Leidenfrost observed that water drops skittered on a sufficiently hot skillet, owing to levitation by an evaporative vapour film. Such films are stable only when the hot surface is above a critical temperature, and are a central phenomenon in boiling. In this so-called Leidenfrost regime, the low thermal conductivity of the vapour layer inhibits heat transfer between the hot surface and the liquid. When the temperature of the cooling surface drops below the critical temperature, the vapour film collapses and the system enters a nucleate-boiling regime, which can result in vapour explosions that are particularly detrimental in certain contexts, such as in nuclear power plants. The presence of these vapour films can also reduce liquid-solid drag. Here we show how vapour film collapse can be completely suppressed at textured superhydrophobic surfaces. At a smooth hydrophobic surface, the vapour film still collapses on cooling, albeit at a reduced critical temperature, and the system switches explosively to nucleate boiling. In contrast, at textured, superhydrophobic surfaces, the vapour layer gradually relaxes until the surface is completely cooled, without exhibiting a nucleate-boiling phase. This result demonstrates that topological texture on superhydrophobic materials is critical in stabilizing the vapour layer and thus in controlling-by heat transfer-the liquid-gas phase transition at hot surfaces. This concept can potentially be applied to control other phase transitions, such as ice or frost formation, and to the design of low-drag surfaces at which the vapour phase is stabilized in the grooves of textures without heating. © 2012 Macmillan Publishers Limited. All rights reserved.

The 'other' London effect: the diversification of London's suburban grammar schools and the rise of hyper-selective elite state schools.

Science.gov (United States)

Gamsu, Sol

2018-03-30

This paper examines the rise of a new elite of 'super-state' schools in London, revealing a growing divide within the state sector which problematizes claims that the capital is a 'hotspot' for social mobility (Social Mobility Commission ). Although recent research has revealed a 'London effect' in which students in the capital on Free School Meals outperform their peers in other regions (Greaves, Macmillan and Sibieta ), inequalities between London's schools in access to elite universities have been overlooked. Drawing on a case study of a suburban London grammar school, 'King Henry's School', I show how ethnic-minority suburbanization has combined with an institutional strategy to compete with elite private schools. Strategies of selection have been mobilized alongside elements of elite 'gentlemanly' educational culture in order to reposition the school within the hierarchy of London's schools. The result is a hyper-selective school which provides a conduit to elite universities for upwardly mobile British-Asian students. I show that this strategy has strong parallels with the school's attempts in the early twentieth century to compete with London's fee-paying 'public' schools. The continuing symbolic value of 'traditional' forms of elite educational culture to a school seeking to reposition itself within the field reflects deep structural patterns of inequality in English education. To understand how apparent improvements in social mobility can sit alongside deepening inequalities between state schools, there is a need for a historical sociological approach that takes account of long-term processes of institutional change (Savage ; Inglis ). © London School of Economics and Political Science 2018.

Libraries as 'everyday' settings: the Glasgow MCISS project.

Science.gov (United States)

Whitelaw, Sandy; Coburn, Jonathan; Lacey, Marion; McKee, Martin J; Hill, Carol

2017-10-01

A settings-based approach is now well-established in health promotion, initially undertaken in conventional places like schools and workplaces, but more recently being expressed in a wider range of what Torp et al. call 'everyday' settings. In this context, libraries have emerged as another potential setting whose ubiquity and accessibility suggests that they may be particularly effective in addressing health inequalities. Drawing on a case study-the Glasgow Macmillan Cancer Information and Support Services Library project-this paper reports on the potential for seeing 'libraries as settings' and in the context of a set of associated theoretical resources, specifically scrutinizes the nature of initiative implementation. Data were drawn from multiple sources: semi-structured interviews and focus groups with strategic partners and stakeholders, operational staff, project volunteers, service users and members of the general public. Qualitative data were complemented by quantitative insights from surveys with members of the partnership, libraries staff and volunteers. Despite some concerns associated with potentially hostile cultural and financial contexts that might threaten longer term sustainability, insights suggested that in pragmatic terms, the project was attracting sizable 'footfall' and successfully addressing a range of needs. Additionally, the formal implementation processes associated with project implementation were considered to have been highly successful in embedding the model into the library culture. In summary, there is evidence that libraries have the potential to be considered as supportive settings and could act as a model for an emergent vision of what libraries do. © The Author 2016. Published by Oxford University Press. All rights reserved. For Permissions, please email: journals.permissions@oup.com.

Low strength of deep San Andreas fault gouge from SAFOD core.

Science.gov (United States)

Lockner, David A; Morrow, Carolyn; Moore, Diane; Hickman, Stephen

2011-04-07

The San Andreas fault accommodates 28-34 mm yr(-1) of right lateral motion of the Pacific crustal plate northwestward past the North American plate. In California, the fault is composed of two distinct locked segments that have produced great earthquakes in historical times, separated by a 150-km-long creeping zone. The San Andreas Fault Observatory at Depth (SAFOD) is a scientific borehole located northwest of Parkfield, California, near the southern end of the creeping zone. Core was recovered from across the actively deforming San Andreas fault at a vertical depth of 2.7 km (ref. 1). Here we report laboratory strength measurements of these fault core materials at in situ conditions, demonstrating that at this locality and this depth the San Andreas fault is profoundly weak (coefficient of friction, 0.15) owing to the presence of the smectite clay mineral saponite, which is one of the weakest phyllosilicates known. This Mg-rich clay is the low-temperature product of metasomatic reactions between the quartzofeldspathic wall rocks and serpentinite blocks in the fault. These findings provide strong evidence that deformation of the mechanically unusual creeping portions of the San Andreas fault system is controlled by the presence of weak minerals rather than by high fluid pressure or other proposed mechanisms. The combination of these measurements of fault core strength with borehole observations yields a self-consistent picture of the stress state of the San Andreas fault at the SAFOD site, in which the fault is intrinsically weak in an otherwise strong crust. ©2011 Macmillan Publishers Limited. All rights reserved

The whole is more than the sum of its parts: Aristotle, metaphysical.

Science.gov (United States)

Upton, Joseph; Janeka, Ivo; Ferraro, Nalton

2014-01-01

This phrase, a favorite of Dr. Joseph E. Murray, can be interpreted in many ways. Mathematically, the whole is equal to the sum of its parts, neither more nor less. Psychological Gestalt theory would maintain that the whole is something else or something different than the sum of its parts. Merely adding up the component parts is meaningless compared with the "part-whole" relationship (SYNERGETICS: Explorations of Thinking. MacMillan Publishing Co, Inc; 1975). Organizational pundits maintain that this principle describes the synergy, which exists between individuals working together in a cooperative effort. Collectively, they are able to achieve an outcome superior to that of 1 or 2 people working alone. This concept is vintage Joseph E. Murray. He was an integral part of the Peter Bent Brigham team, which transformed the dream of organ transplantation into clinical reality over 50 years ago. Although many advances in medicine are made by the serendipity of a prepared mind making a critical observation (Alexander Fleming and penicillin), individual brilliance (Judah Folkman and angiogenesis), or by technology (magnetic resonance imaging), most are achieved by groups of physicians and scientists working together. All have prepared minds. When the Peter Bent Brigham Hospital physicians and researchers at the Harvard Medical School dedicated all of their energy on solving the problems of end-stage renal disease, their effort was concentrated and primarily regional. Today, this cooperation is global, as communication has been facilitated by the Internet, iPhone, iPad, video conferencing, electronic libraries, and the like.

Stabilization of Leidenfrost vapour layer by textured superhydrophobic surfaces

KAUST Repository

Vakarelski, Ivan Uriev; Patankar, Neelesh A.; Marston, Jeremy; Chan, Derek Y C; Thoroddsen, Sigurdur T

2012-01-01

In 1756, Leidenfrost observed that water drops skittered on a sufficiently hot skillet, owing to levitation by an evaporative vapour film. Such films are stable only when the hot surface is above a critical temperature, and are a central phenomenon in boiling. In this so-called Leidenfrost regime, the low thermal conductivity of the vapour layer inhibits heat transfer between the hot surface and the liquid. When the temperature of the cooling surface drops below the critical temperature, the vapour film collapses and the system enters a nucleate-boiling regime, which can result in vapour explosions that are particularly detrimental in certain contexts, such as in nuclear power plants. The presence of these vapour films can also reduce liquid-solid drag. Here we show how vapour film collapse can be completely suppressed at textured superhydrophobic surfaces. At a smooth hydrophobic surface, the vapour film still collapses on cooling, albeit at a reduced critical temperature, and the system switches explosively to nucleate boiling. In contrast, at textured, superhydrophobic surfaces, the vapour layer gradually relaxes until the surface is completely cooled, without exhibiting a nucleate-boiling phase. This result demonstrates that topological texture on superhydrophobic materials is critical in stabilizing the vapour layer and thus in controlling-by heat transfer-the liquid-gas phase transition at hot surfaces. This concept can potentially be applied to control other phase transitions, such as ice or frost formation, and to the design of low-drag surfaces at which the vapour phase is stabilized in the grooves of textures without heating. © 2012 Macmillan Publishers Limited. All rights reserved.

Reconsidering the Grenada revolution

Directory of Open Access Journals (Sweden)

Jay R. Mandle

1995-01-01

Full Text Available [First paragraph] Caribbean Revolutions and Revolutionary Theory: An Assessment of Cuba, Nicaragua and Grenada. BRIAN MEEKS. London: Macmillan Caribbean, 1993. ix + 210 pp. (Paper n.p. The Grenada Invasion: Politics, Law, and Foreign Policy Decisionmaking. ROBERT J. BECK. Boulder: Westview, 1993. xiv + 263 pp. (Cloth US$ 49.95 The Gorrión Tree: Cuba and the Grenada Revolution. JOHN WALTON COTMAN. New York: Peter Lang, 1993. xvi + 272 pp. (Cloth US$ 48.95 These three books might be thought of as a second generation of studies concerned with the rise, rule, and destruction of the People's Revolutionary Government (PRG in Grenada. The circumstances surrounding the accession to power in 1979 of the government led by Maurice Bishop, the nature of its rule, and its violent demise in 1983 resulted in the appearance during the mid-1980s of an extensive literature on the Grenada Revolution. Some of these works were scholarly, others polemical. But what they all had in common was the desire to examine, either critically or otherwise, something which was unique in the historical experience of the English-speaking Caribbean. Never, before the rule of the New JEWEL Movement (NJM in Grenada, had a Leninist party come to power; never had a violent coup initiated a new political regime; never had a Caribbean government so explicitly rejected U.S. hegemony in the area; and never, before October 1983, had a government experienced quite so dramatic a crisis as that in Grenada, one which resulted in the killing of the Prime Minister and numerous others of his supporters.

Transpressional rupture of an unmapped fault during the 2010 Haiti earthquake

KAUST Repository

Calais, Éric

2010-10-24

On 12 January 2010, a Mw7.0 earthquake struck the Port-au-Prince region of Haiti. The disaster killed more than 200,000 people and caused an estimated $8 billion in damages, about 100% of the country?s gross domestic product. The earthquake was initially thought to have ruptured the Enriquillog-Plantain Garden fault of the southern peninsula of Haiti, which is one of two main strike-slip faults inferred to accommodate the 2cmyr -1 relative motion between the Caribbean and North American plates. Here we use global positioning system and radar interferometry measurements of ground motion to show that the earthquake involved a combination of horizontal and contractional slip, causing transpressional motion. This result is consistent with the long-term pattern of strain accumulation in Hispaniola. The unexpected contractional deformation caused by the earthquake and by the pattern of strain accumulation indicates present activity on faults other than the Enriquillog-Plantain Garden fault. We show that the earthquake instead ruptured an unmapped north-dipping fault, called the Léogâne fault. The Léogâne fault lies subparallel tog-but is different fromg-the Enriquillog-Plantain Garden fault. We suggest that the 2010 earthquake may have activated the southernmost front of the Haitian fold-and-thrust belt as it abuts against the Enriquillog-Plantain Garden fault. As the Enriquillog-Plantain Garden fault did not release any significant accumulated elastic strain, it remains a significant seismic threat for Haiti and for Port-au-Prince in particular. © 2010 Macmillan Publishers Limited. All rights reserved.

Early intervention for relapse in schizophrenia: impact of cognitive behavioural therapy on negative beliefs about psychosis and self-esteem.

Science.gov (United States)

Gumley, Andrew; Karatzias, Athanasios; Power, Kevin; Reilly, James; McNay, Lisa; O'Grady, Margaret

2006-06-01

The study aimed to test two hypotheses. Firstly, that participants who relapsed during the 12-month follow-up period of our randomized controlled trial, would show increased negative beliefs about their illness and reduced self-esteem, in comparison to the non-relapsed participants. Secondly, that cognitive behavioural therapy (CBT) for early signs of relapse would result in a reduction in negative beliefs about psychosis and an improvement in self-esteem at 12 months. A total of 144 participants with schizophrenia or a related disorder were randomized to receive either treatment as usual (TAU; N=72) or CBT (N=72). Participants completed the Personal Beliefs about Illness Questionnaire (PBIQ; Birchwood, Mason, MacMillan, & Healy, 1993) and the Rosenberg Self-Esteem Scale (RSES; Rosenberg, 1965) at entry, 3 months, 6 months, and 12 months. At 12 months, relapsers showed greater increase in scores for PBIQ entrapment compared with non-relapsers. In addition, after controlling for baseline covariates (treatment group and PBIQ self versus illness), relapsers also showed greater increase in scores for PBIQ self versus illness at 12 months. Furthermore, in comparison to treatment as usual, participants who received CBT showed greater improvement in PBIQ loss and in Rosenberg self-esteem. The study provides evidence that relapse is associated with the development of negative appraisals of entrapment and self-blame (self vs. illness). In addition, this is the first study to show that CBT reduces negative appraisals of loss arising from psychosis and improvements in self-esteem. Implications for future research and treatment are discussed.

Transpressional rupture of an unmapped fault during the 2010 Haiti earthquake

KAUST Repository

Calais, É ric; Freed, Andrew M.; Mattioli, Glen S.; Amelung, Falk; Jonsson, Sigurjon; Jansma, Pamela E.; Hong, Sanghoon; Dixon, Timothy H.; Pré petit, Claude; Momplaisir, Roberte

2010-01-01

On 12 January 2010, a Mw7.0 earthquake struck the Port-au-Prince region of Haiti. The disaster killed more than 200,000 people and caused an estimated $8 billion in damages, about 100% of the country?s gross domestic product. The earthquake was initially thought to have ruptured the Enriquillog-Plantain Garden fault of the southern peninsula of Haiti, which is one of two main strike-slip faults inferred to accommodate the 2cmyr -1 relative motion between the Caribbean and North American plates. Here we use global positioning system and radar interferometry measurements of ground motion to show that the earthquake involved a combination of horizontal and contractional slip, causing transpressional motion. This result is consistent with the long-term pattern of strain accumulation in Hispaniola. The unexpected contractional deformation caused by the earthquake and by the pattern of strain accumulation indicates present activity on faults other than the Enriquillog-Plantain Garden fault. We show that the earthquake instead ruptured an unmapped north-dipping fault, called the Léogâne fault. The Léogâne fault lies subparallel tog-but is different fromg-the Enriquillog-Plantain Garden fault. We suggest that the 2010 earthquake may have activated the southernmost front of the Haitian fold-and-thrust belt as it abuts against the Enriquillog-Plantain Garden fault. As the Enriquillog-Plantain Garden fault did not release any significant accumulated elastic strain, it remains a significant seismic threat for Haiti and for Port-au-Prince in particular. © 2010 Macmillan Publishers Limited. All rights reserved.

A heteromeric Texas coral snake toxin targets acid-sensing ion channels to produce pain.

Science.gov (United States)

Bohlen, Christopher J; Chesler, Alexander T; Sharif-Naeini, Reza; Medzihradszky, Katalin F; Zhou, Sharleen; King, David; Sánchez, Elda E; Burlingame, Alma L; Basbaum, Allan I; Julius, David

2011-11-16

Natural products that elicit discomfort or pain represent invaluable tools for probing molecular mechanisms underlying pain sensation. Plant-derived irritants have predominated in this regard, but animal venoms have also evolved to avert predators by targeting neurons and receptors whose activation produces noxious sensations. As such, venoms provide a rich and varied source of small molecule and protein pharmacophores that can be exploited to characterize and manipulate key components of the pain-signalling pathway. With this in mind, here we perform an unbiased in vitro screen to identify snake venoms capable of activating somatosensory neurons. Venom from the Texas coral snake (Micrurus tener tener), whose bite produces intense and unremitting pain, excites a large cohort of sensory neurons. The purified active species (MitTx) consists of a heteromeric complex between Kunitz- and phospholipase-A2-like proteins that together function as a potent, persistent and selective agonist for acid-sensing ion channels (ASICs), showing equal or greater efficacy compared with acidic pH. MitTx is highly selective for the ASIC1 subtype at neutral pH; under more acidic conditions (pH 100-fold) proton-evoked activation of ASIC2a channels. These observations raise the possibility that ASIC channels function as coincidence detectors for extracellular protons and other, as yet unidentified, endogenous factors. Purified MitTx elicits robust pain-related behaviour in mice by activation of ASIC1 channels on capsaicin-sensitive nerve fibres. These findings reveal a mechanism whereby snake venoms produce pain, and highlight an unexpected contribution of ASIC1 channels to nociception. © 2011 Macmillan Publishers Limited. All rights reserved

Single-ion quantum lock-in amplifier.

Science.gov (United States)

Kotler, Shlomi; Akerman, Nitzan; Glickman, Yinnon; Keselman, Anna; Ozeri, Roee

2011-05-05

Quantum metrology uses tools from quantum information science to improve measurement signal-to-noise ratios. The challenge is to increase sensitivity while reducing susceptibility to noise, tasks that are often in conflict. Lock-in measurement is a detection scheme designed to overcome this difficulty by spectrally separating signal from noise. Here we report on the implementation of a quantum analogue to the classical lock-in amplifier. All the lock-in operations--modulation, detection and mixing--are performed through the application of non-commuting quantum operators to the electronic spin state of a single, trapped Sr(+) ion. We significantly increase its sensitivity to external fields while extending phase coherence by three orders of magnitude, to more than one second. Using this technique, we measure frequency shifts with a sensitivity of 0.42 Hz Hz(-1/2) (corresponding to a magnetic field measurement sensitivity of 15 pT Hz(-1/2)), obtaining an uncertainty of less than 10 mHz (350 fT) after 3,720 seconds of averaging. These sensitivities are limited by quantum projection noise and improve on other single-spin probe technologies by two orders of magnitude. Our reported sensitivity is sufficient for the measurement of parity non-conservation, as well as the detection of the magnetic field of a single electronic spin one micrometre from an ion detector with nanometre resolution. As a first application, we perform light shift spectroscopy of a narrow optical quadrupole transition. Finally, we emphasize that the quantum lock-in technique is generic and can potentially enhance the sensitivity of any quantum sensor. ©2011 Macmillan Publishers Limited. All rights reserved

Indian Energy Policy and Strategy: Pre- and Post-Copenhagen 2009

Directory of Open Access Journals (Sweden)

Megha Shenoy

2013-02-01

Full Text Available Published by Palgrave MacmillanIndia is an extraordinarily diverse democratic country with one of the fastest growing economies in the world. It is the world’s sixth largest consumer of energy. Interest in its energy policies and strategies is escalating due to their huge impact on geopolitical relations, global energy prices and climate change. Its current per capita energy consumption and GHG emission values are low; however, these are bound to increase if it continues on the path of development that the West has followed. If India is to ‘leapfrog’ the already well-trodden path to one that ensures sustainable development, it is imperative for the country to redefine its development paradigm in order to ensure inclusive growth. Unsustainable subsidies, poor reform implementation, distorted energy prices and inadequate investment in renewables are some of the major constraints that the Indian government needs to re-examine so as to increase energy security and provide a framework for transition to a low-carbon economy. In addition to innovative energy policies such as the National Solar Mission, the National Mission on Enhanced Energy Efficiency and the National Mission on Sustainable Habitat, India needs to adopt a framework for decoupled growth, which we consider as an increase in the quality of life for its citizens without an increase in environmental damage. Since 2008 India has demonstrated that it is serious about changing its growth pattern and moving towards clean energy alternatives. However, this vision will not be fully realised unless the global North provides technical and financial assistance to collectively mitigate the adverse impact of global warming and subsequent climate change.

Sequential deposition as a route to high-performance perovskite-sensitized solar cells

KAUST Repository

Burschka, Julian

2013-07-10

Following pioneering work, solution-processable organic-inorganic hybrid perovskites - such as CH 3 NH 3 PbX 3 (X = Cl, Br, I) - have attracted attention as light-harvesting materials for mesoscopic solar cells. So far, the perovskite pigment has been deposited in a single step onto mesoporous metal oxide films using a mixture of PbX 2 and CH 3 NH 3 X in a common solvent. However, the uncontrolled precipitation of the perovskite produces large morphological variations, resulting in a wide spread of photovoltaic performance in the resulting devices, which hampers the prospects for practical applications. Here we describe a sequential deposition method for the formation of the perovskite pigment within the porous metal oxide film. PbI 2 is first introduced from solution into a nanoporous titanium dioxide film and subsequently transformed into the perovskite by exposing it to a solution of CH 3 NH 3 I. We find that the conversion occurs within the nanoporous host as soon as the two components come into contact, permitting much better control over the perovskite morphology than is possible with the previously employed route. Using this technique for the fabrication of solid-state mesoscopic solar cells greatly increases the reproducibility of their performance and allows us to achieve a power conversion efficiency of approximately 15 per cent (measured under standard AM1.5G test conditions on solar zenith angle, solar light intensity and cell temperature). This two-step method should provide new opportunities for the fabrication of solution-processed photovoltaic cells with unprecedented power conversion efficiencies and high stability equal to or even greater than those of today\\'s best thin-film photovoltaic devices. © 2013 Macmillan Publishers Limited. All rights reserved.

The ribosome uses two active mechanisms to unwind messenger RNA during translation.

Science.gov (United States)

Qu, Xiaohui; Wen, Jin-Der; Lancaster, Laura; Noller, Harry F; Bustamante, Carlos; Tinoco, Ignacio

2011-07-06

The ribosome translates the genetic information encoded in messenger RNA into protein. Folded structures in the coding region of an mRNA represent a kinetic barrier that lowers the peptide elongation rate, as the ribosome must disrupt structures it encounters in the mRNA at its entry site to allow translocation to the next codon. Such structures are exploited by the cell to create diverse strategies for translation regulation, such as programmed frameshifting, the modulation of protein expression levels, ribosome localization and co-translational protein folding. Although strand separation activity is inherent to the ribosome, requiring no exogenous helicases, its mechanism is still unknown. Here, using a single-molecule optical tweezers assay on mRNA hairpins, we find that the translation rate of identical codons at the decoding centre is greatly influenced by the GC content of folded structures at the mRNA entry site. Furthermore, force applied to the ends of the hairpin to favour its unfolding significantly speeds translation. Quantitative analysis of the force dependence of its helicase activity reveals that the ribosome, unlike previously studied helicases, uses two distinct active mechanisms to unwind mRNA structure: it destabilizes the helical junction at the mRNA entry site by biasing its thermal fluctuations towards the open state, increasing the probability of the ribosome translocating unhindered; and it mechanically pulls apart the mRNA single strands of the closed junction during the conformational changes that accompany ribosome translocation. The second of these mechanisms ensures a minimal basal rate of translation in the cell; specialized, mechanically stable structures are required to stall the ribosome temporarily. Our results establish a quantitative mechanical basis for understanding the mechanism of regulation of the elongation rate of translation by structured mRNAs. ©2011 Macmillan Publishers Limited. All rights reserved

Porous materials with optimal adsorption thermodynamics and kinetics for CO2 separation

KAUST Repository

Nugent, Patrick S.

2013-02-27

The energy costs associated with the separation and purification of industrial commodities, such as gases, fine chemicals and fresh water, currently represent around 15 per cent of global energy production, and the demand for such commodities is projected to triple by 2050 (ref. 1). The challenge of developing effective separation and purification technologies that have much smaller energy footprints is greater for carbon dioxide (CO2) than for other gases; in addition to its involvement in climate change, CO 2 is an impurity in natural gas, biogas (natural gas produced from biomass), syngas (CO/H 2, the main source of hydrogen in refineries) and many other gas streams. In the context of porous crystalline materials that can exploit both equilibrium and kinetic selectivity, size selectivity and targeted molecular recognition are attractive characteristics for CO 2 separation and capture, as exemplified by zeolites 5A and 13X (ref. 2), as well as metal-organic materials (MOMs). Here we report that a crystal engineering or reticular chemistry strategy that controls pore functionality and size in a series of MOMs with coordinately saturated metal centres and periodically arrayed hexafluorosilicate (SiF 6 2-) anions enables a \\'sweet spot\\' of kinetics and thermodynamics that offers high volumetric uptake at low CO2 partial pressure (less than 0.15 bar). Most importantly, such MOMs offer an unprecedented CO 2 sorption selectivity over N2, H 2 and CH 4, even in the presence of moisture. These MOMs are therefore relevant to CO2 separation in the context of post-combustion (flue gas, CO2/N2), pre-combustion (shifted synthesis gas stream, CO 2/H 2) and natural gas upgrading (natural gas clean-up, CO2/CH 4). © 2013 Macmillan Publishers Limited. All rights reserved.

Method for Determining the Sensitivity of a Physical Security System.

Energy Technology Data Exchange (ETDEWEB)

Speed, Ann [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Gauthier, John H. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Hoffman, Matthew John [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Wachtel, Amanda [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Kittinger, Robert Scott [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Munoz-Ramos, Karina [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

2017-05-23

Modern systems, such as physical security systems, are often designed to involve complex interactions of technological and human elements. Evaluation of the performance of these systems often overlooks the human element. A method is proposed here to expand the concept of sensitivity—as denoted by d’—from signal detection theory (Green & Swets 1966; Macmillan & Creelman 2005), which came out of the field of psychophysics, to cover not only human threat detection but also other human functions plus the performance of technical systems in a physical security system, thereby including humans in the overall evaluation of system performance. New in this method is the idea that probabilities of hits (accurate identification of threats) and false alarms (saying “threat” when there is not one), which are used to calculate d’ of the system, can be applied to technologies and, furthermore, to different functions in the system beyond simple yes-no threat detection. At the most succinct level, the method returns a single number that represents the effectiveness of a physical security system; specifically, the balance between the handling of actual threats and the distraction of false alarms. The method can be automated, and the constituent parts revealed, such that given an interaction graph that indicates the functional associations of system elements and the individual probabilities of hits and false alarms for those elements, it will return the d’ of the entire system as well as d’ values for individual parts. The method can also return a measure of the response bias* of the system. One finding of this work is that the d’ for a physical security system can be relatively poor in spite of having excellent d’s for each of its individual functional elements.

In vitro reconstitution of an abscisic acid signalling pathway

KAUST Repository

Fujii, Hiroaki; Chinnusamy, Viswanathan; Rodrigues, Americo; Rubio, Silvia; Antoni, Regina; Park, Sang-Youl; Cutler, Sean R.; Sheen, Jen; Rodriguez, Pedro L.; Zhu, Jian-Kang

2009-01-01

The phytohormone abscisic acid (ABA) regulates the expression of many genes in plants; it has critical functions in stress resistance and in growth and development. Several proteins have been reported to function as ABA receptors, and many more are known to be involved in ABA signalling. However, the identities of ABA receptors remain controversial and the mechanism of signalling from perception to downstream gene expression is unclear. Here we show that by combining the recently identified ABA receptor PYR1 with the type 2C protein phosphatase (PP2C) ABI1, the serine/threonine protein kinase SnRK2.6/OST1 and the transcription factor ABF2/AREB1, we can reconstitute ABA-triggered phosphorylation of the transcription factor in vitro. Introduction of these four components into plant protoplasts results in ABA-responsive gene expression. Protoplast and test-tube reconstitution assays were used to test the function of various members of the receptor, protein phosphatase and kinase families. Our results suggest that the default state of the SnRK2 kinases is an autophosphorylated, active state and that the SnRK2 kinases are kept inactive by the PP2Cs through physical interaction and dephosphorylation. We found that in the presence of ABA, the PYR/PYL (pyrabactin resistance 1/PYR1-like) receptor proteins can disrupt the interaction between the SnRK2s and PP2Cs, thus preventing the PP2C-mediated dephosphorylation of the SnRK2s and resulting in the activation of the SnRK2 kinases. Our results reveal new insights into ABA signalling mechanisms and define a minimal set of core components of a complete major ABA signalling pathway. © 2009 Macmillan Publishers Limited. All rights reserved.

Observed increase in local cooling effect of deforestation at higher latitudes.

Science.gov (United States)

Lee, Xuhui; Goulden, Michael L; Hollinger, David Y; Barr, Alan; Black, T Andrew; Bohrer, Gil; Bracho, Rosvel; Drake, Bert; Goldstein, Allen; Gu, Lianhong; Katul, Gabriel; Kolb, Thomas; Law, Beverly E; Margolis, Hank; Meyers, Tilden; Monson, Russell; Munger, William; Oren, Ram; Paw U, Kyaw Tha; Richardson, Andrew D; Schmid, Hans Peter; Staebler, Ralf; Wofsy, Steven; Zhao, Lei

2011-11-16

Deforestation in mid- to high latitudes is hypothesized to have the potential to cool the Earth's surface by altering biophysical processes. In climate models of continental-scale land clearing, the cooling is triggered by increases in surface albedo and is reinforced by a land albedo-sea ice feedback. This feedback is crucial in the model predictions; without it other biophysical processes may overwhelm the albedo effect to generate warming instead. Ongoing land-use activities, such as land management for climate mitigation, are occurring at local scales (hectares) presumably too small to generate the feedback, and it is not known whether the intrinsic biophysical mechanism on its own can change the surface temperature in a consistent manner. Nor has the effect of deforestation on climate been demonstrated over large areas from direct observations. Here we show that surface air temperature is lower in open land than in nearby forested land. The effect is 0.85 ± 0.44 K (mean ± one standard deviation) northwards of 45° N and 0.21 ± 0.53 K southwards. Below 35° N there is weak evidence that deforestation leads to warming. Results are based on comparisons of temperature at forested eddy covariance towers in the USA and Canada and, as a proxy for small areas of cleared land, nearby surface weather stations. Night-time temperature changes unrelated to changes in surface albedo are an important contributor to the overall cooling effect. The observed latitudinal dependence is consistent with theoretical expectation of changes in energy loss from convection and radiation across latitudes in both the daytime and night-time phase of the diurnal cycle, the latter of which remains uncertain in climate models. © 2011 Macmillan Publishers Limited. All rights reserved

The genome of a Late Pleistocene human from a Clovis burial site in western Montana

KAUST Repository

Rasmussen, Morten Arendt Rendt

2014-02-12

Clovis, with its distinctive biface, blade and osseous technologies, is the oldest widespread archaeological complex defined in North America, dating from 11,100 to 10,700 14 C years before present (bp) (13,000 to 12,600 calendar years bp). Nearly 50 years of archaeological research point to the Clovis complex as having developed south of the North American ice sheets from an ancestral technology. However, both the origins and the genetic legacy of the people who manufactured Clovis tools remain under debate. It is generally believed that these people ultimately derived from Asia and were directly related to contemporary Native Americans. An alternative, Solutrean, hypothesis posits that the Clovis predecessors emigrated from southwestern Europe during the Last Glacial Maximum. Here we report the genome sequence of a male infant (Anzick-1) recovered from the Anzick burial site in western Montana. The human bones date to 10,705 ± 35 14 C years bp (approximately 12,707-12,556 calendar years bp) and were directly associated with Clovis tools. We sequenced the genome to an average depth of 14.4× and show that the gene flow from the Siberian Upper Palaeolithic Mal\\'ta population into Native American ancestors is also shared by the Anzick-1 individual and thus happened before 12,600 years bp. We also show that the Anzick-1 individual is more closely related to all indigenous American populations than to any other group. Our data are compatible with the hypothesis that Anzick-1 belonged to a population directly ancestral to many contemporary Native Americans. Finally, we find evidence of a deep divergence in Native American populations that predates the Anzick-1 individual. © 2014 Macmillan Publishers Limited. All rights reserved.

Hybrid passivated colloidal quantum dot solids

KAUST Repository

Ip, Alex

2012-07-29

Colloidal quantum dot (CQD) films allow large-area solution processing and bandgap tuning through the quantum size effect. However, the high ratio of surface area to volume makes CQD films prone to high trap state densities if surfaces are imperfectly passivated, promoting recombination of charge carriers that is detrimental to device performance. Recent advances have replaced the long insulating ligands that enable colloidal stability following synthesis with shorter organic linkers or halide anions, leading to improved passivation and higher packing densities. Although this substitution has been performed using solid-state ligand exchange, a solution-based approach is preferable because it enables increased control over the balance of charges on the surface of the quantum dot, which is essential for eliminating midgap trap states. Furthermore, the solution-based approach leverages recent progress in metal:chalcogen chemistry in the liquid phase. Here, we quantify the density of midgap trap states in CQD solids and show that the performance of CQD-based photovoltaics is now limited by electrong-"hole recombination due to these states. Next, using density functional theory and optoelectronic device modelling, we show that to improve this performance it is essential to bind a suitable ligand to each potential trap site on the surface of the quantum dot. We then develop a robust hybrid passivation scheme that involves introducing halide anions during the end stages of the synthesis process, which can passivate trap sites that are inaccessible to much larger organic ligands. An organic crosslinking strategy is then used to form the film. Finally, we use our hybrid passivated CQD solid to fabricate a solar cell with a certified efficiency of 7.0%, which is a record for a CQD photovoltaic device. © 2012 Macmillan Publishers Limited. All rights reserved.

Spin-transfer torque generated by a topological insulator

KAUST Repository

Mellnik, A. R.

2014-07-23

Magnetic devices are a leading contender for the implementation of memory and logic technologies that are non-volatile, that can scale to high density and high speed, and that do not wear out. However, widespread application of magnetic memory and logic devices will require the development of efficient mechanisms for reorienting their magnetization using the least possible current and power. There has been considerable recent progress in this effort; in particular, it has been discovered that spin-orbit interactions in heavy-metal/ferromagnet bilayers can produce strong current-driven torques on the magnetic layer, via the spin Hall effect in the heavy metal or the Rashba-Edelstein effect in the ferromagnet. In the search for materials to provide even more efficient spin-orbit-induced torques, some proposals have suggested topological insulators, which possess a surface state in which the effects of spin-orbit coupling are maximal in the sense that an electron\\' s spin orientation is fixed relative to its propagation direction. Here we report experiments showing that charge current flowing in-plane in a thin film of the topological insulator bismuth selenide (Bi2Se3) at room temperature can indeed exert a strong spin-transfer torque on an adjacent ferromagnetic permalloy (Ni81Fe19) thin film, with a direction consistent with that expected from the topological surface state. We find that the strength of the torque per unit charge current density in Bi 2Se3 is greater than for any source of spin-transfer torque measured so far, even for non-ideal topological insulator films in which the surface states coexist with bulk conduction. Our data suggest that topological insulators could enable very efficient electrical manipulation of magnetic materials at room temperature, for memory and logic applications. © 2014 Macmillan Publishers Limited. All rights reserved.

Experimental infection of bats with Geomyces destructans causes white-nose syndrome

Science.gov (United States)

Lorch, J.M.; Meteyer, C.U.; Behr, M.J.; Boyles, J.G.; Cryan, P.M.; Hicks, A.C.; Ballmann, A.E.; Coleman, J.T.H.; Redell, D.N.; Reeder, D.M.; Blehert, D.S.

2011-01-01

White-nose syndrome (WNS) has caused recent catastrophic declines among multiple species of bats in eastern North America. The disease's name derives from a visually apparent white growth of the newly discovered fungus Geomyces destructans on the skin (including the muzzle) of hibernating bats. Colonization of skin by this fungus is associated with characteristic cutaneous lesions that are the only consistent pathological finding related to WNS. However, the role of G. destructans in WNS remains controversial because evidence to implicate the fungus as the primary cause of this disease is lacking. The debate is fuelled, in part, by the assumption that fungal infections in mammals are most commonly associated with immune system dysfunction. Additionally, the recent discovery that G. destructans commonly colonizes the skin of bats of Europe, where no unusual bat mortality events have been reported, has generated further speculation that the fungus is an opportunistic pathogen and that other unidentified factors are the primary cause of WNS. Here we demonstrate that exposure of healthy little brown bats (Myotis lucifugus) to pure cultures of G. destructans causes WNS. Live G. destructans was subsequently cultured from diseased bats, successfully fulfilling established criteria for the determination of G. destructans as a primary pathogen. We also confirmed that WNS can be transmitted from infected bats to healthy bats through direct contact. Our results provide the first direct evidence that G. destructans is the causal agent of WNS and that the recent emergence of WNS in North America may represent translocation of the fungus to a region with a naive population of animals. Demonstration of causality is an instrumental step in elucidating the pathogenesis and epidemiology of WNS and in guiding management actions to preserve bat populations against the novel threat posed by this devastating infectious disease. ?? 2011 Macmillan Publishers Limited. All rights reserved.

In vitro reconstitution of an abscisic acid signalling pathway

KAUST Repository

Fujii, Hiroaki

2009-11-18

The phytohormone abscisic acid (ABA) regulates the expression of many genes in plants; it has critical functions in stress resistance and in growth and development. Several proteins have been reported to function as ABA receptors, and many more are known to be involved in ABA signalling. However, the identities of ABA receptors remain controversial and the mechanism of signalling from perception to downstream gene expression is unclear. Here we show that by combining the recently identified ABA receptor PYR1 with the type 2C protein phosphatase (PP2C) ABI1, the serine/threonine protein kinase SnRK2.6/OST1 and the transcription factor ABF2/AREB1, we can reconstitute ABA-triggered phosphorylation of the transcription factor in vitro. Introduction of these four components into plant protoplasts results in ABA-responsive gene expression. Protoplast and test-tube reconstitution assays were used to test the function of various members of the receptor, protein phosphatase and kinase families. Our results suggest that the default state of the SnRK2 kinases is an autophosphorylated, active state and that the SnRK2 kinases are kept inactive by the PP2Cs through physical interaction and dephosphorylation. We found that in the presence of ABA, the PYR/PYL (pyrabactin resistance 1/PYR1-like) receptor proteins can disrupt the interaction between the SnRK2s and PP2Cs, thus preventing the PP2C-mediated dephosphorylation of the SnRK2s and resulting in the activation of the SnRK2 kinases. Our results reveal new insights into ABA signalling mechanisms and define a minimal set of core components of a complete major ABA signalling pathway. © 2009 Macmillan Publishers Limited. All rights reserved.

'Being a conduit' between hospital and home: stakeholders' views and perceptions of a nurse-led Palliative Care Discharge Facilitator Service in an acute hospital setting.

Science.gov (United States)

Venkatasalu, Munikumar Ramasamy; Clarke, Amanda; Atkinson, Joanne

2015-06-01

To explore and critically examine stakeholders' views and perceptions concerning the nurse-led Palliative Care Discharge Service in an acute hospital setting and to inform sustainability, service development and future service configuration. The drive in policy and practice is to enable individuals to achieve their preferred place of care during their last days of life. However, most people in UK die in acute hospital settings against their wishes. To facilitate individuals' preferred place of care, a large acute hospital in northeast England implemented a pilot project to establish a nurse-led Macmillan Palliative Care Discharge Facilitator Service. A pluralistic evaluation design using qualitative methods was used to seek stakeholders' views and perceptions of this service. In total, 12 participants (five bereaved carers and seven health professionals) participated in the evaluation. Semi-structured interviews were conducted with bereaved carers who used this service for their relatives. A focus group and an individual interview were undertaken with health professionals who had used the service since its inception. Individual interviews were also conducted with the Discharge Facilitator and service manager. Analysis of all data was guided by Framework Analysis. Four key themes emerged relating to the role of the Discharge Facilitator Service: achieving preferred place of care; the Discharge Facilitator as the 'conduit' between hospital and community settings; delays in hospital discharge and stakeholders' perceptions of the way forward for the service. The Discharge Facilitator Service acted as a reliable resource and support for facilitating the fast-tracking of end-of-life patients to their preferred place of care. Future planning for hospital-based palliative care discharge facilitating services need to consider incorporating strategies that include: increased profile of the service, expansion of service provision and the Discharge Facilitator's earlier

Hybrid passivated colloidal quantum dot solids

KAUST Repository

Ip, Alex; Thon, Susanna; Hoogland, Sjoerd H.; Voznyy, Oleksandr; Zhitomirsky, David; Debnath, Ratan K.; Levina, Larissa; Rollny, Lisa R.; Carey, Graham H.; Fischer, Armin H.; Kemp, Kyle W.; Kramer, Illan J.; Ning, Zhijun; Labelle, André J.; Chou, Kang Wei; Amassian, Aram; Sargent, E. H.

2012-01-01

Colloidal quantum dot (CQD) films allow large-area solution processing and bandgap tuning through the quantum size effect. However, the high ratio of surface area to volume makes CQD films prone to high trap state densities if surfaces are imperfectly passivated, promoting recombination of charge carriers that is detrimental to device performance. Recent advances have replaced the long insulating ligands that enable colloidal stability following synthesis with shorter organic linkers or halide anions, leading to improved passivation and higher packing densities. Although this substitution has been performed using solid-state ligand exchange, a solution-based approach is preferable because it enables increased control over the balance of charges on the surface of the quantum dot, which is essential for eliminating midgap trap states. Furthermore, the solution-based approach leverages recent progress in metal:chalcogen chemistry in the liquid phase. Here, we quantify the density of midgap trap states in CQD solids and show that the performance of CQD-based photovoltaics is now limited by electrong-"hole recombination due to these states. Next, using density functional theory and optoelectronic device modelling, we show that to improve this performance it is essential to bind a suitable ligand to each potential trap site on the surface of the quantum dot. We then develop a robust hybrid passivation scheme that involves introducing halide anions during the end stages of the synthesis process, which can passivate trap sites that are inaccessible to much larger organic ligands. An organic crosslinking strategy is then used to form the film. Finally, we use our hybrid passivated CQD solid to fabricate a solar cell with a certified efficiency of 7.0%, which is a record for a CQD photovoltaic device. © 2012 Macmillan Publishers Limited. All rights reserved.

Aspects of Development Financing After the Financial and Economic Crisis

Directory of Open Access Journals (Sweden)

Bruno Gurtner

2011-05-01

Full Text Available Published by Palgrave MacmillanThe financial and economic crisis saw developing and emerging countries experience more severe setbacks in their growth rates than industrialised countries and they did not all have sufficient funds to finance robust stimulus measures. The major emerging economies have nevertheless recovered quickly and are currently the most important growth engines in the world economy.Private capital flows collapsed, leaving the global South with an overall deficit in financing. Greater official financing flows have not yet been able to compensate for the shortfalls and the slow increase in private capital flows since the end of 2009 has not been able to do so either. Overall, according to the UN, more capital flows from the South to the North than vice versa. The South thus continues to finance the North.Discussions regarding a reform of the global financial and economic order are ongoing but to date have had little impact on developing countries. The international financing institutions do have more funds at their disposal, but developing countries are still under-represented. The IMF and the World Bank have begun to question some of their previous dogmas. Opinions are divided on whether one can already speak of a new policy.The debate on the role of taxation in the mobilisation of local resources for development financing has intensified. Insight favouring comprehensive reforms of the taxation systems in developing countries has sharpened, but technical aid provided by industrialised countries to realise these reforms is still insufficient. Taxation is acquiring growing recognition as an instrument of State-building, democratisation and governance. The campaign to deal with international tax evasion and illicit capital flows is gaining momentum and the exchange of information on tax issues has improved. However, it is difficult to establish newer and more trenchant instruments for improved transparency, given the predominant

The earliest evidence for anatomically modern humans in northwestern Europe.

Science.gov (United States)

Higham, Tom; Compton, Tim; Stringer, Chris; Jacobi, Roger; Shapiro, Beth; Trinkaus, Erik; Chandler, Barry; Gröning, Flora; Collins, Chris; Hillson, Simon; O'Higgins, Paul; FitzGerald, Charles; Fagan, Michael

2011-11-02

The earliest anatomically modern humans in Europe are thought to have appeared around 43,000-42,000 calendar years before present (43-42 kyr cal BP), by association with Aurignacian sites and lithic assemblages assumed to have been made by modern humans rather than by Neanderthals. However, the actual physical evidence for modern humans is extremely rare, and direct dates reach no farther back than about 41-39 kyr cal BP, leaving a gap. Here we show, using stratigraphic, chronological and archaeological data, that a fragment of human maxilla from the Kent's Cavern site, UK, dates to the earlier period. The maxilla (KC4), which was excavated in 1927, was initially diagnosed as Upper Palaeolithic modern human. In 1989, it was directly radiocarbon dated by accelerator mass spectrometry to 36.4-34.7 kyr cal BP. Using a Bayesian analysis of new ultrafiltered bone collagen dates in an ordered stratigraphic sequence at the site, we show that this date is a considerable underestimate. Instead, KC4 dates to 44.2-41.5 kyr cal BP. This makes it older than any other equivalently dated modern human specimen and directly contemporary with the latest European Neanderthals, thus making its taxonomic attribution crucial. We also show that in 13 dental traits KC4 possesses modern human rather than Neanderthal characteristics; three other traits show Neanderthal affinities and a further seven are ambiguous. KC4 therefore represents the oldest known anatomically modern human fossil in northwestern Europe, fills a key gap between the earliest dated Aurignacian remains and the earliest human skeletal remains, and demonstrates the wide and rapid dispersal of early modern humans across Europe more than 40 kyr ago. ©2011 Macmillan Publishers Limited. All rights reserved

The genome of a Late Pleistocene human from a Clovis burial site in western Montana

KAUST Repository

Rasmussen, Morten Arendt Rendt; Anzick, Sarah L.; Waters, Michael R.; Skoglund, Pontus; Degiorgio, Michael; Stafford, Thomas W Jr; Rasmussen, Simon B.; Moltke, Ida; Albrechtsen, Anders; Doyle, Shane M.; Poznik, G. David; Gudmundsdottir, Valborg; Yadav, Rachita; Malaspinas, Anna Sapfo; Samuel Stockton White, V.; Allentoft, Morten Erik; Cornejo, Omar Eduardo; Tambets, Kristiina; Eriksson, Anders; Heintzman, Peter D.; Karmin, Monika; Korneliussen, Thorfinn Sand; Meltzer, David J.; Pierre, Tracey L.; Stenderup, Jesper T.; Saag, Lauri; Warmuth, Vera M.; Lopes, Margarida C.; Malhi, Ripan Singh; Brunak, Sö ren; Sicheritz-Ponté n, Thomas; Barnes, Ian; Collins, Matthew J.; Orlando, Ludovic A A; Balloux, Franç ois; Manica, Andrea; Gupta, Ramneek; Metspalu, Mait; Bustamante, Carlos D.; Jakobsson, Mattias; Nielsen, Rasmus Wedel; Willerslev, Eske

2014-01-01

Clovis, with its distinctive biface, blade and osseous technologies, is the oldest widespread archaeological complex defined in North America, dating from 11,100 to 10,700 14 C years before present (bp) (13,000 to 12,600 calendar years bp). Nearly 50 years of archaeological research point to the Clovis complex as having developed south of the North American ice sheets from an ancestral technology. However, both the origins and the genetic legacy of the people who manufactured Clovis tools remain under debate. It is generally believed that these people ultimately derived from Asia and were directly related to contemporary Native Americans. An alternative, Solutrean, hypothesis posits that the Clovis predecessors emigrated from southwestern Europe during the Last Glacial Maximum. Here we report the genome sequence of a male infant (Anzick-1) recovered from the Anzick burial site in western Montana. The human bones date to 10,705 ± 35 14 C years bp (approximately 12,707-12,556 calendar years bp) and were directly associated with Clovis tools. We sequenced the genome to an average depth of 14.4× and show that the gene flow from the Siberian Upper Palaeolithic Mal'ta population into Native American ancestors is also shared by the Anzick-1 individual and thus happened before 12,600 years bp. We also show that the Anzick-1 individual is more closely related to all indigenous American populations than to any other group. Our data are compatible with the hypothesis that Anzick-1 belonged to a population directly ancestral to many contemporary Native Americans. Finally, we find evidence of a deep divergence in Native American populations that predates the Anzick-1 individual. © 2014 Macmillan Publishers Limited. All rights reserved.

The Logic of Reflection: Samuel Taylor Coleridge's "treatise on Logic"

Science.gov (United States)

Land, Janet Sanders

Though others discuss Coleridge's interest in science, light imagery, the phenomenon of reflection, and his references to Newton and Opticks,^1 this is the first study to examine Coleridge's art in terms of optics, its developing theories, and the nature-of-light debate. This study examines Coleridge's early predilection for visions, illusions, and the supernatural and demonstrates that he gradually shifts from the supernatural to the scientific aspects of "visions" and "illusions," concentrating on causes of illusions and the effects of their deceptive qualities rather than their mystical features. By the 1820's, his preoccupation with illusions had become an interest in optics, fueled, no doubt, by the increasing controversy of the nature-of-light debate and the number of advances in optics resulting from the efforts of its opponents to prove their theories. Tracing the development of the debate, its escalation in the early nineteenth century, and the formation of Coleridge's opinion concerning key issues of the debate, I outline the evolution of Coleridge's theory of reflection and examine the exposition of that theory in his treatise, Logic (1981). Finally, I analyze the relationship between the advances in optics and Coleridge's concepts of thought and knowledge and his notion of the mind as an instrument of knowledge. These ideas in turn, altered his opinions concerning the validity of knowledge resulting from philosophic debate, scientific experiment, and poetic exploration. ftn^1John Beer, "Coleridge and Wordsworth on Reflection," The Wordsworth Circle 20 (1989): 20-29; Coleridge the Visionary. London: Chatto and Windus, 1959; and Coleridge's Poetic Intelligence. London: Macmillan, 1977 and M. H. Abrams Natural Supernaturalism: Tradition and Revolution in Romantic Literature. New York: Norton, 1971; and "Coleridge's 'A Light in Sound': Science, Metascience, and Poetic Imagination." The Correspondent Breeze: Essays on English Romanticism. Eds. M. H. Abrams

Book Reviews

Directory of Open Access Journals (Sweden)

Redactie KITLV

1996-07-01

Full Text Available -Bridget Brereton, Emilia Viotti Da Costa, Crowns of glory, tears of blood: The Demerara slave rebellion of 1823. New York: Oxford University Press, 1994. xix + 378 pp. -Grant D. Jones, Assad Shoman, 13 Chapters of a history of Belize. Belize city: Angelus, 1994. xviii + 344 pp. -Donald Wood, K.O. Laurence, Tobago in wartime 1793-1815. Kingston: The Press, University of the West Indies, 1995. viii + 280 pp. -Trevor Burnard, Howard A. Fergus, Montserrat: History of a Caribbean colony. London: Macmillan Caribbean, 1994. x + 294 pp. -John L. Offner, Joseph Smith, The Spanish-American War: Conflict in the Caribbean and the Pacific, 1895-1902. London: Longman, 1994. ix + 262 pp. -Louis Allaire, John M. Weeks ,Ancient Caribbean. New York: Garland, 1994. lxxi + 325 pp., Peter J. Ferbel (eds -Aaron Segal, Hilbourne A. Watson, The Caribbean in the global political economy. Boulder CO: Lynne Rienner, 1994. ix + 261 pp. -Aaron Segal, Anthony P. Maingot, The United States and the Caribbean. London: Macmillan Caribbean, 1994. xi + 260 pp. -Bill Maurer, Helen I. Safa, The myth of the male breadwinner: Women and industrialization in the Caribbean. Boulder CO: Westview, 1995. xvi + 208 pp. -Peter Meel, Edward M. Dew, The trouble in Suriname, 1975-1993. Westport CT: Praeger, 1994. xv + 243 pp. -Henry Wells, Jorge Heine, The last Cacique: Leadership and politics in a Puerto Rican city. Pittsburgh PA: University of Pittsburgh Press, 1993. ix + 310 pp. -Susan Eckstein, Jorge F. Pérez-López, Cuba at a crossroads: Politics and economics after the fourth party congress. Gainesville: University Press of Florida, 1994. xviii + 282 pp. -David A.B. Murray, Marvin Leiner, Sexual politics in Cuba: Machismo, homosexuality, and AIDS. Boulder CO: Westview, 1994. xv + 184 pp. -Kevin A. Yelvington, Selwyn Ryan ,Sharks and sardines: Blacks in business in Trinidad and Tobago. St. Augustine, Trinidad: Institute of social and economic studies, University of the West Indies, 1992

Similar healthy osteoclast and osteoblast activity on nanocrystalline hydroxyapatite and nanoparticles of tri-calcium phosphate compared to natural bone

Directory of Open Access Journals (Sweden)

MacMillan AK

2014-12-01

Full Text Available Adam K MacMillan,1 Francis V Lamberti,1 Julia N Moulton,2 Benjamin M Geilich,2 Thomas J Webster2,3 1RTI Surgical, Alachua, FL, USA; 2Department of Chemical Engineering, Northeastern University, Boston, MA, USA; 3Center of Excellence for Advanced Materials Research, King Abdulaziz University, Jeddah, Saudi Arabia Abstract: While there have been numerous studies to determine osteoblast (bone forming cell functions on nanocrystalline compared to micron crystalline ceramics, there have been few studies which have examined osteoclast activity (including tartrate-resistant acid phosphatase, formation of resorption pits, size of resorption pits, and receptor activator of nuclear factor κB [RANK]. This is despite the fact that osteoclasts are an important part of maintaining healthy bone since they resorb bone during the bone remodeling process. Moreover, while it is now well documented that bone formation is enhanced on nanoceramics compared to micron ceramics, some have pondered whether osteoblast functions (such as osteoprotegerin and RANK ligand [RANKL] are normal (ie, non-diseased on such materials compared to natural bone. For these reasons, the objective of the present in vitro study was to determine various functions of osteoclasts and osteoblasts on nanocrystalline and micron crystalline hydroxyapatite as well as tri-calcium phosphate materials and compare such results to cortical and cancellous bone. Results showed for the first time similar osteoclast activity (including tartrate-resistant acid phosphatase, formation of resorption pits, size of resorption pits, and RANK and osteoblast activity (osteoprotegerin and RANKL on nanocrystalline hydroxyapatite compared to natural bone, whereas osteoclast and osteoblast functions on micron crystalline versions of these ceramics were much different than natural bone. In this manner, this study provides additional evidence that nanocrystalline calcium phosphates can serve as suitable synthetic

Debating the viability of ethnicity

Directory of Open Access Journals (Sweden)

Vilna Bashi

2004-01-01

Full Text Available [First paragraph] Immigration and the Political Economy of Home: West Indian Brooklyn and American Indian Minneapolis, 1945-1992. RACHEL BUFF. Berkeley: University of Califomia Press, 2001. xv + 240 pp. (Paper US$ 18.95 Black Cuban, Black American: A Memoir. EVELIO GRILLO. Houston TX: Arte Püblico Press, 2000. xvi + 134 pp. (Paper US$ 13.95 West Indian in the West: Self Representations in an Immigrant Community. PERCY C. HINTZEN. New York: New York University Press, 2001. x + 200pp. (Paper US$ 18.50 Caribbean Families in Britain and the Transatlantic World. HARRY GOULBOURNE & MARY CHAMBERLAIN (eds.. Oxford UK: Macmillan, 2001. xvi + 270 pp. (Paper £15.50 Legacies: The Story of the Immigrant Second Generation. ALEJANDRO PORTES & RUBÉN G. RUMBAUT. Berkeley: University of Califomia Press/ New York: Russell Sage Foundation, 2001. xxiv + 406 pp. (Paper US$ 19.95 "Ethnicity" and its meaning, both as an identity and as a resilient cultural influence, has dominated late twentieth-century social scientific analyses of the process of immigrant incorporation. Perhaps we may mark the crowning of the term with the publication of Glazer and Moynihan's The Melting Pot, one famous tome that "explained" varying "assimilation" outcomes among the "new" (post-1965 newcomers by examining their ethnic culture for flaws or strengths that justified socioeconomic failure or success. Muddying the ensuing policy debate was the use of buzzwords, like mainstream, deviant, assimilated, minority, black matriarch, absent father, and underclass, that were themselves categorizing and hierarchical. The tautology of hierarchically labeling groups and then asking why groups with different labels have different outcomes seems to be perpetually invisible to the parties in the assimilation debate, but the debate itself rages on. Newer scholarship has added a different voice to that debate, arguing that variance in "assimilation" is instead explained by incorporation into

Competences, education and support for new roles in cancer genetics services: outcomes from the cancer genetics pilot projects.

Science.gov (United States)

Bennett, Catherine; Burton, Hilary; Farndon, Peter

2007-01-01

In 2004 the Department of Health in collaboration with Macmillan Cancer Support set up service development projects to pilot the integration of genetics in mainstream medicine in the area of cancer genetics.In developing these services, new roles and responsibilities were devised that required supporting programmes of education and training. The NHS National Genetics Education and Development Centre has worked with the projects to draw together their experience in these aspects. New roles include the Cancer Family Nurse Specialist, in which a nurse working in a cancer setting was trained to identify and manage genetic or family history concerns, and the Genetic Risk Assessment Practitioner--a small team of practitioners working within a secondary care setting to deliver a standardised risk assessment pathway. Existing roles were also adapted for a different setting, in particular the use of genetic counsellors working in a community ethnic minority setting. These practitioners undertook a range of clinical activities that can be mapped directly to the 'UK National Workforce Competences for Genetics in Clinical Practice for Non-genetics Healthcare Staff' framework developed by Skills for Health and the NHS National Genetics Education and Development Centre (2007; draft competence framework). The main differences between the various roles were in the ordering of genetic tests and the provision of advice on invasive preventive options such as mastectomy. Those involved in service development also needed to develop competences in project management, business skills, audit and evaluation, working with users, general management (personnel, multi-agency work and marketing), educational supervision, IT, public and professional outreach, and research. Important resources to support the development of new roles and competences included pathways and guidelines, a formal statement of competences, a recognised syllabus, appropriate and timely courses, the availability of a

A close nuclear black-hole pair in the spiral galaxy NGC 3393.

Science.gov (United States)

Fabbiano, G; Wang, Junfeng; Elvis, M; Risaliti, G

2011-08-31

The current picture of galaxy evolution advocates co-evolution of galaxies and their nuclear massive black holes, through accretion and galactic merging. Pairs of quasars, each with a massive black hole at the centre of its galaxy, have separations of 6,000 to 300,000 light years (refs 2 and 3; 1 parsec = 3.26 light years) and exemplify the first stages of this gravitational interaction. The final stages of the black-hole merging process, through binary black holes and final collapse into a single black hole with gravitational wave emission, are consistent with the sub-light-year separation inferred from the optical spectra and light-variability of two such quasars. The double active nuclei of a few nearby galaxies with disrupted morphology and intense star formation (such as NGC 6240 with a separation of about 2,600 light years and Mrk 463 with a separation of about 13,000 light years between the nuclei) demonstrate the importance of major mergers of equal-mass spiral galaxies in this evolution; such mergers lead to an elliptical galaxy, as in the case of the double-radio-nucleus elliptical galaxy 0402+379 (with a separation of about 24 light years between the nuclei). Minor mergers of a spiral galaxy with a smaller companion should be a more common occurrence, evolving into spiral galaxies with active massive black-hole pairs, but have hitherto not been seen. Here we report the presence of two active massive black holes, separated by about 490 light years, in the Seyfert galaxy NGC 3393 (50 Mpc, about 160 million light years). The regular spiral morphology and predominantly old circum-nuclear stellar population of this galaxy, and the closeness of the black holes embedded in the bulge, provide a hitherto missing observational point to the study of galaxy/black hole evolution. Comparison of our observations with current theoretical models of mergers suggests that they are the result of minor merger evolution. © 2011 Macmillan Publishers Limited. All rights

Ecogenomics and potential biogeochemical impacts of globally abundant ocean viruses

KAUST Repository

Roux, Simon

2016-05-12

they act as key players in nutrient cycling and trophic networks. © 2016 Macmillan Publishers Limited, part of Springer Nature.

Private equity and venture capitalists' investment criteria in the Czech Republic

Directory of Open Access Journals (Sweden)

Marek Zinecker

2010-01-01

Full Text Available For investment decision making to be rational, the existence of investment criteria is required. In the theory of financial management, the effectiveness of investment is traditionally judged by the degree to which an investment proposal contributes to achieving the main financial goal of business, i.e. market value maximization of the firm.So far, potential businesses for Private Equity and Venture Capital financing in the Czech Republic have not had information regarding investment criteria and their significance, when considered by investors, at their disposal, which is due to absence of relevant research results.This article presents results of the research project whose aim is to establish which criteria are considered to perform an essential role in the selection of business proposals by firms investing Private Equity and Venture Capital in the Czech Republic as well as the most common reasons for rejecting the proposals. Based on practical experience of financing by Private Equity and Venture Capital, the research made it possible to identify the most significant criteria, namely characterization of mana­gement, market, product and the rate of investment capital appreciation. The results of the research are consequently compared with findings which were published in similar studies undertaken in the past (e.g. Tyebjee, Bruno, 1984; Fried, Hisrich, 1994; MacMillan et al., 1985, 1987; Muzyka et al., 1996; Eisele, 2002.The research supports the thesis that, when considering business proposals, above-average weight is attached to criteria concerning the characterization of management, i.e. experience and competencies in all stages of business life cycle. Nevertheless, the fulfilment of the criteria is not sufficient for investors to evaluate a business proposal positively. They also place an emphasis on selected criteria related to market and product. By publishing empirical data, an important signal regarding up-to-date evaluative criteria

Reseñas de Libros

Directory of Open Access Journals (Sweden)

Daniel Alcalde Güelfo

2009-12-01

Full Text Available Achcar, Gilbert, El choque de barbaries, terrorismo y desorden mundial. Barcelona, Icaria-Antrazyt, 2007, 197 pp.Páginas 213-214Daniel Alcalde GüelfoDel Arco Blanco, Miguel Ángel, Hambre de Siglos. Mundo rural y apoyos sociales del franquismo en Andalucía Oriental (1936-1951. Granada, Comares Historia, 2007, 513 pp.Páginas 214-217Mª Candelaria Fuentes NavarroBen-Ghiat, Ruth; Fuller, Mia (eds., Italian Colonialism. New York, Palgrave MacMillan, 2005, 266 pp.Páginas 217-219Karl J. TrybusBlack, Edwin, IBM y el Holocausto: La alianza estratégica entre la Alemania nazi y la más poderosa corporación norteamericana. Buenos Aires, Atlántida, 2001, 508 pp.Páginas 219-220Flavia PascarielloCasassas, Jordi (coord., La construcción del presente. El mundo desde 1848 hasta nuestros días. Barcelona, Ariel, 2005, 696 pp.Páginas 220-223Alfonso Pinilla GarcíaFerguson, Niall, La guerra del mundo. Los conflictos del siglo XX y el declive de Occidente (1904-1953. Barcelona, Debate, 2007, 888 pp.Páginas 223-225David Molina RabadánGentile, Emilio, Fascismo di pietra. Roma-Bari, Laterza, 2007, 284 pp.Páginas 225-227Jan NelisKelly, Eamonn, La década decisiva. Tres escenarios para el futuro del mundo. Barcelona, Granica, 2007, 318 pp.Páginas 227-228David Molina RabadánLuzzatto, Sergio, The Body of Il Duce: Mussolini’s Corpse and the Fortunes of Italy. New York, Metropolitan Books, 2005, 258pp.Páginas 228-230Karl J. TrybusSánchez Blanco, Ángel, Organización Intermunicipal. Madrid, Iustel, Biblioteca de Derecho Municipal, 2006, 258 pp.Páginas 230-232José Joaquín Fernández AllesSantacreu Soler, José Miguel; Aura Murcia, Federico y Millán Llin, Vicente, El municipi del liberalisme: Sant Vicent del Raspeig 1806-1848. Simat de la Valldigna, Edicions La Xarxa, 2004, 156 pp.Páginas 232-235Antonio J. Piqueres Díez

An application of the multilayer perceptron: Solar radiation maps in Spain

Energy Technology Data Exchange (ETDEWEB)

Hontoria, L.; Aguilera, J. [Grupo Investigacion y Desarrollo en Energia Solar y Automatica, Dpto. de Ingenieria Electronica, de Telecomunicaciones y Automatica, Escuela Politecnica Superior de Jaen, Campus de las Lagunillas, Universidad de Jaen, 23071 Jaen (Spain); Zufiria, P. [Grupo de Redes Neuronales, Dpto. de Matematica Aplicada a las Tecnologias de la Informacion, ETSI Telecomunicaciones, UPM Ciudad Universitaria s/n, 28040 Madrid (Spain)

2005-11-01

In this work an application of a methodology to obtain solar radiation maps is presented. This methodology is based on a neural network system [Lippmann, R.P., 1987. An introduction to computing with neural nets. IEEE ASSP Magazine, 4-22] called Multi-Layer Perceptron (MLP) [Haykin, S., 1994. Neural Networks. A Comprehensive Foundation. Macmillan Publishing Company; Hornik, K., Stinchcombe, M., White, H., 1989. Multilayer feedforward networks are universal approximators. Neural Networks, 2(5), 359-366]. To obtain a solar radiation map it is necessary to know the solar radiation of many points spread wide across the zone of the map where it is going to be drawn. For most of the locations all over the world the records of these data (solar radiation in whatever scale, daily or hourly values) are non-existent. Only very few locations have the privilege of having good meteorological stations where records of solar radiation have being registered. But even in those locations with historical records of solar data, the quality of these solar series is not as good as it should be for most purposes. In addition, to draw solar radiation maps the number of points on the maps (real sites) that it is necessary to work with makes this problem difficult to solve. Nevertheless, with the application of the methodology proposed in this paper, this problem has been solved and solar radiation maps have been obtained for a small region of Spain: Jaen province, a southern province of Spain between parallels 38{sup o}25' N and 37{sup o}25' N, and meridians 4{sup o}10' W and 2{sup o}10' W, and for a larger region: Andalucia, the most southern region of Spain situated between parallels 38{sup o}40' N and 36{sup o}00' N, and meridians 7{sup o}30' W and 1{sup o}40' W. (author)

Ecogenomics and potential biogeochemical impacts of globally abundant ocean viruses

KAUST Repository

Roux, Simon; Brum, Jennifer R; Dutilh, Bas E.; Sunagawa, Shinichi; Duhaime, Melissa B; Loy, Alexander; Poulos, Bonnie T; Solonenko, Natalie; Lara, Elena; Poulain, Julie; Pesant, Stephane; Kandels-Lewis, Stefanie; Dimier, Celine; Picheral, Marc; Searson, Sarah; Cruaud, Corinne; Alberti, Adriana; Duarte, Carlos M.; Gasol, Josep M M; Vaque, Dolors; Bork, Peer; Acinas, Silvia G; Wincker, Patrick; Sullivan, Matthew B

2016-01-01

act as key players in nutrient cycling and trophic networks. © 2016 Macmillan Publishers Limited, part of Springer Nature.

Perceptions of the Nature of Happiness: Cultural, but Related to the Dynamics of the Human Mind and the Gratification of General Needs : Laura Hyman: Happiness; Understanding Narratives and Discourses, Palgrave Macmillan, 2014, ISBN: 978-1-137-32152-7

NARCIS (Netherlands)

J.C. Ott (Jan Cornelis)

2017-01-01

markdownabstractIn her book ‘Happiness’ Laura Hyman identifies some discourses, as defined by Foucault, about happiness among 19 middle-class respondents in the UK. A discourse is a way of thinking and communicating about some issue, and comparable to a ‘perception’ or a’ view’. The dominant

The Gendered Realities of Managerialism in Education: An Essay Review of Kathleen Lynch, Bernie Grummell, and Dympna Devine's, "New Managerialism in Education: Commercialization, Carelessness, and Gender" (New York, NY: Palgrave Macmillan, 2012. ISBN 978-0-230-27511-9)

Science.gov (United States)

Apple, Michael W.

2014-01-01

Over the years that I have been writing the Reviewing Policy section of this journal, I have paid particular attention to critical conceptual and empirical work that either overtly supports or directly challenges the taken-for-granted assumptions that tend to guide dominant policies in education. These policies may deal with larger issues…

Book Reviews

Directory of Open Access Journals (Sweden)

Redactie KITLV

2001-07-01

Full Text Available -Stanley L. Engerman, Heather Cateau ,Capitalism and slavery fifty years later: Eric Eustace Williams - A reassessment of the man and his work. New York: Peter Lang, 2000. xvii + 247 pp., S.H.H. Carrington (eds -Philip D. Morgan, B.W. Higman, Writing West Indian histories. London: Macmillan Caribbean, 1999. xiv + 289 pp. -Daniel Vickers, Alison Games, Migration and the origins of the English Atlantic world. Cambridge MA: Harvard University Press, 1999. xiii + 322 pp. -Christopher L. Brown, Andrew Jackson O'Shaughnessy, An empire divided: The American revolution and the British Caribbean. Philadelphia: University of Pennsylvania Press, 2000. xviii + 357 pp. -Lennox Honychurch, Samuel M. Wilson, The indigenous people of the Caribbean. Gainesville: University Press of Florida, 1997. xiv + 253 pp. -Kenneth Bilby, Bev Carey, The Maroon story: The authentic and original history of the Maroons in the history of Jamaica 1490-1880. St. Andrew, Jamaica: Agouti Press, 1997. xvi + 656 pp. -Bernard Moitt, Doris Y. Kadish, Slavery in the Caribbean Francophone world: Distant voices, forgotten acts, forged identities. Athens: University of Georgia Press, 2000. xxiii + 247 pp. -Michael J. Guasco, Virginia Bernhard, Slaves and slaveholders in Bermuda, 1616-1782. Columbia: University of Missouri Press, 1999. xviii + 316 pp. -Michael J. Jarvis, Roger C. Smith, The maritime heritage of the Cayman Islands. Gainesville: University Press of Florida, 2000. xxii + 230 pp. -Paul E. Hoffman, Peter R. Galvin, Patterns of pillage: A geography of Caribbean-based piracy in Spanish America, 1536-1718. New York: Peter Lang, 1999. xiv + 271 pp. -David M. Stark, Raúl Mayo Santana ,Cadenas de esclavitud...y de solidaridad: Esclavos y libertos en San Juan,siglo XIX. Río Piedras: Centro de Investigaciones Sociales, Universidad de Puerto Rico, 1997. 204 pp., Mariano Negrón Portillo, Manuel Mayo López (eds -Ada Ferrer, Philip A. Howard, Changing history: Afro-Cuban Cabildos and

Preface

Directory of Open Access Journals (Sweden)

Baldev Arora

2009-06-01

., Macmillan et al., Matzka et al. describe magnetic observations
in the region of the South Atlantic anomaly. This is the region between
Africa and South America where Earth’s main magnetic field is depressed causing
localized space weather hazards (some described in Macmillan et al., especially
satellite outages. Korte et al. describes the installation of new magnetic observatories
in Bolivia, Namibia and St Helena, and Macmillan et al. describe two older
magnetic observatories located on Ascension Island and Port Stanely.
Repeat station surveys are a way of measuring the secular variation of main field.
Matzka et al. contains a detailed report of a repeat station survey in this region at
Tristan da Cunha Island. They also describe the drawbacks of repeat station surveys
and prefer a magnetic observatory in the region which will be established for the
SWARM satellite mission. However, Korte et al. show that when nothing else exists
repeat stations are still a good way of obtaining secular variation data. They describe
the addition of several repeat stations in the South Atlantic anomaly area in
Africa.
Torta et al. and Korte et al. also describe efforts being made to create an unmanned
magnetic observatory, which would have INTERMAGNET standards.
The Guest Editors wish to thank Enkelejda Qamili for her assistance during the
session in Perugia, the numerous referees who reviewed the papers and the Editorial
office of Annals of Geophysics for their continued support and encouragement in
bring out this special issue of the Journal.

Book Reviews

Directory of Open Access Journals (Sweden)

Redactie KITLV

1995-07-01

Full Text Available -Dennis Walder, Robert D. Hamner, Derek Walcott. New York: Twayne Publishers, 1993. xvi + 199 pp.''Critical perspectives on Derek Walcott. Washington DC: Three continents, 1993. xvii + 482 pp. -Yannick Tarrieu, Lilyan Kesteloot, Black writers in French: A literary history of Negritude. Translated by Ellen Conroy Kennedy. Washington DC: Howard University Press, 1991. xxxiii + 411 pp. -Renée Larrier, Carole Boyce Davies ,Out of the Kumbla: Caribbean women and literature. Trenton NJ: Africa World Press, 1990. xxiii + 399 pp., Elaine Savory Fido (eds -Renée Larrier, Evelyn O'Callaghan, Woman version: Theoretical approaches to West Indian fiction by women. London: Macmillan Caribbean, 1993. viii + 126 pp. -Lisa Douglass, Carolyn Cooper, Noises in the blood: Orality, gender and the 'vulgar' body of Jamaican popular culture. London: Macmillan Caribbean, 1993. ix + 214 pp. -Christine G.T. Ho, Kumar Mahabir, East Indian women of Trinidad & Tobago: An annotated bibliography with photographs and ephemera. San Juan, Trinidad: Chakra, 1992. vii + 346 pp. -Eva Abraham, Richenel Ansano ,Mundu Yama Sinta Mira: Womanhood in Curacao. Eithel Martis (eds.. Curacao: Fundashon Publikashon, 1992. xii + 240 pp., Joceline Clemencia, Jeanette Cook (eds -Louis Allaire, Corrine L. Hofman, In search of the native population of pre-Colombian Saba (400-1450 A.D.: Pottery styles and their interpretations. Part one. Amsterdam: Natuurwetenschappelijke Studiekring voor het Caraïbisch Gebied, 1993. xiv + 269 pp. -Frank L. Mills, Bonham C. Richardson, The Caribbean in the wider world, 1492-1992: A regional geography. Cambridge: Cambridge University Press, 1992. xvi + 235 pp. -Frank L. Mills, Thomas D. Boswell ,The Caribbean Islands: Endless geographical diversity. New Brunswick NJ: Rutgers University Press, 1992. viii + 240 pp., Dennis Conway (eds -Alex van Stipriaan, H.W. van den Doel ,Nederland en de Nieuwe Wereld. Utrecht: Aula, 1992. 348 pp., P.C. Emmer, H.PH. Vogel (eds

Guidelines for Authors

Directory of Open Access Journals (Sweden)

Abdullah Demir

2016-06-01

. As’ad Abukhalil, “Maronites,” in Encyclopedia of the Modern Middle East and North Africa, ed. Philip Mattar, 2nd ed., vol. 3 (New York: Macmillan Reference, 2004, 1491-92.2. Abukhalil, “Maronites,” 1492.Bibliography: Abukhalil, As’ad. “Maronites.” In Encycloedia or the Modern Middle East and North Africa. Edited by Philip Mattar. 2nd ed. Vol. 3. New York: Macmillan Reference, 1491-92.    DISSERTATIONFor theses and dissertations, the following order should be followed: name of the author and surname, full title of thesis in italics, thesis type, the name of the university and date.1. Mihwa Choi, “Contesting Imaginaires in Death Rituals during the Northern Song Dynasty” (PhD diss., University of Chicago, 2008, 55.2. Choi, “Contesting Imaginaires,” 59. Bibliography: Choi, Mihwa. “Contesting Imaginaires in Death Rituals during the Northern Song Dynasty.” PhD diss., University of Chicago, 2008. Chicago-Style Citation Quick Guide:http://www.chicagomanualofstyle.org/tools_citationguide.html 

Informing the patient about a fatal disease: from paternalism to autonomy--the Jewish view.

Science.gov (United States)

Rosner, Fred

2004-01-01

Until the late 20th century, withholding a fatal diagnosis functioned as a paradigm for sharing other medical information with patients. The obligation of confidentiality was emphasized and disclosure was ignored. Ethicists perceived the doctor-patient relationship as oriented to therapy, reassurance, and avoiding harm. Physicians were to provide lies and truth instrumentally only insofar as they aided therapy (Jameton, A. Information disclosure. Ethical issues. In Encyclopedia of Bioethics. Revised Ed.; Reich, T.N.T., Ed.; MacMillan: New York, 1995; Vol. 3, 1225-1232). This was the era of paternalism. Since the 1960s, opinion on the role of disclosure was changed rapidly in the United States stimulated by the patient's rights movement and the rise of bioethics. The current climate supports honest and complete disclosure of medical information. In 1972, the Board of Trustees of the American Hospital Association affirmed A Patient's Bill of Rights, which states that the patient has the right to obtain from his physician complete current information concerning his diagnosis, treatment, and prognosis in terms the patient can be reasonably expected to understand (Lee, A.L.; Jacobs, G. Workshop airs patient's rights. Hospitals 1973, 47, 39-43). Bioethicists now favor full disclosure as a means of respecting patient autonomy (Katz, J. The Silent World of Doctor and Patient; Free Press: New York, 1984). The American College of Physician Ethics Manual states that disclosure to patients is a fundamental ethical requirement (American College of Physicians. American College of Physicians Ethics Manual, 3rd Ed. Ann. Intern. Med. 1992, 117, 947-960). The era of patient autonomy ended the traditional pattern of withholding information, which was characteristic of the previous era of paternalism. The Jewish view toward full disclosure of a fatal illness to a patient and especially a patient who is terminally ill is in general a negative one because of the fear that the patient

Economic cycles and their synchronization: Spectral analysis of macroeconomic series from Italy, The Netherlands, and the UK

Science.gov (United States)

Sella, Lisa; Vivaldo, Gianna; Ghil, Michael; Groth, Andreas

2010-05-01

economy of a country: Hallegatte and Ghil (Ecol. Econ., 2008) have shown that the presence of business cycles modifies substantially this impact with respect to their impact on an economy in or near equilibrium. The present work concludes with a study of the synchronization of economic fluctuations, which follows a similar study of macroeconomic indicators for the United States, presented in a nearby poster. Since business cycles are not country-specific phenomena, but show common characteristics across countries, our aim is to uncover hidden global behavior across the European economies (cf. Mazzi and Savio, Macmillan, 2006).

The human role in changing river channels

Science.gov (United States)

Gregory, K. J.

2006-09-01

Direct consequences of the human role, where human activity affects river channels through engineering works including channelization, dam construction, diversion and culverting, have been long recognised [Marsh, G.P., 1864. Man and Nature or Physical Geography as Modified by Human Action. Charles Scribner, New York; Thomas Jr., W.L., (ed.) 1956. Man's Role in Changing the Face of the Earth. Chicago, University of Chicago Press, Chicago.]. The less obvious indirect effects of point and reach changes occurring downstream and throughout the basin, however, are much more recently appreciated, dating from key contributions by Strahler [Strahler, A.N., 1956. The nature of induced erosion and aggradation. In W. L. Thomas (Ed.), Man's Role in Changing the Face of the Earth. University of Chicago Press, Chicago, 621-638.], Wolman [Wolman, M.G., 1967. A cycle of sedimentation and erosion in urban river channels. Geografiska Annaler 49A, 385-95.], Schumm [Schumm, S.A., 1969. River metamorphosis. Proceedings American Society of Civil Engineers, Journal Hydraulics Division 95, 255-73.], and Graf [Graf, W.L., 1977. The rate law in fluvial geomorphology. American Journal of Science, 277, 178-191.]. These are complemented by effects of alterations of land use, such as deforestation, intensive agriculture and incidence of fire, with the most extreme effects produced by building activity and urbanisation. Changing river channels are most evident in the channel cross-section where changes of size, shape and composition are now well-established, with up to tenfold increases or decreases illustrated by results from more than 200 world studies. In addition the overall channel planform, the network and the ecology have changed. Specific terms have become associated with changing river channels including enlargement, shrinkage and metamorphosis. Although the scope of adjustment has been established, it has not always been possible to predict what will happen in a particular location

Book Reviews

Directory of Open Access Journals (Sweden)

Redactie KITLV

1997-07-01

Full Text Available -Leslie G. Desmangles, Joan Dayan, Haiti, history, and the Gods. Berkeley: University of California Press, 1995. xxiii + 339 pp. -Barry Chevannes, James T. Houk, Spirits, blood, and drums: The Orisha religion in Trinidad. Philadelphia: Temple University Press, 1995. xvi + 238 pp. -Barry Chevannes, Walter F. Pitts, Jr., Old ship of Zion: The Afro-Baptist ritual in the African Diaspora. New York: Oxford University Press, 1993. xvi + 199 pp. -Robert J. Stewart, Lewin L. Williams, Caribbean theology. New York: Peter Lang, 1994. xiii + 231 pp. -Robert J. Stewart, Barry Chevannes, Rastafari and other African-Caribbean worldviews. London: Macmillan, 1995. xxv + 282 pp. -Michael Aceto, Maureen Warner-Lewis, Yoruba songs of Trinidad. London: Karnak House, 1994. 158 pp.''Trinidad Yoruba: From mother tongue to memory. Tuscaloosa: University of Alabama Press, 1996. xviii + 279 pp. -Erika Bourguignon, Nicola H. Götz, Obeah - Hexerei in der Karibik - zwischen Macht und Ohnmacht. Frankfurt am Main: Peter Lang, 1995. 256 pp. -John Murphy, Hernando Calvo Ospina, Salsa! Havana heat: Bronx Beat. London: Latin America Bureau, 1995. viii + 151 pp. -Donald R. Hill, Stephen Stuempfle, The steelband movement: The forging of a national art in Trinidad and Tobago. Philadelphia: University of Pennsylvania Press, 1995. xx + 289 pp. -Hilary McD. Beckles, Jay R. Mandle ,Caribbean Hoops: The development of West Indian basketball. Langhorne PA: Gordon and Breach, 1994. ix + 121 pp., Joan D. Mandle (eds -Edmund Burke, III, Lewis R. Gordon ,Fanon: A critical reader. Oxford: Blackwell, 1996. xxi + 344 pp., T. Denean Sharpley-Whiting, Renée T. White (eds -Keith Alan Sprouse, Ikenna Dieke, The primordial image: African, Afro-American, and Caribbean Mythopoetic text. New York: Peter Lang, 1993. xiv + 434 pp. -Keith Alan Sprouse, Wimal Dissanayake ,Self and colonial desire: Travel writings of V.S. Naipaul. New York : Peter Lang, 1993. vii + 160 pp., Carmen Wickramagamage (eds

Application of ray-traced tropospheric slant delays to geodetic VLBI analysis

Science.gov (United States)

Hofmeister, Armin; Böhm, Johannes

2017-08-01

National Aeronautics and Space Administration Goddard Space Flight Center (NASA GSFC) (Eriksson and MacMillan in http://lacerta.gsfc.nasa.gov/tropodelays, 2016) with respect to the analysis performances in terms of BLR results. If tropospheric gradient estimation is included in the analysis, 51.3% of the baselines benefit from the RADIATE ray-traced delays at sub-mm difference level. If no tropospheric gradients are estimated within the analysis, the RADIATE ray-traced delays deliver a better BLR at 63% of the baselines compared to the NASA GSFC ray-traced delays.

Reseñas

Directory of Open Access Journals (Sweden)

HC Reseñas

2010-02-01

Full Text Available LE CROM, Jean-Pierre y MARTIN, Jean-Clément. Vérité historique, vérité judiciaire (Droit et société ns 38. París, 1998. STEINBERG,J. Why Swüzerland? Cambridge, Cambridge University Press, 1996. GOLDHAGEN, Daniel Jonah. Los verdugos voluntarios de Hitler. Los alemanes corrientes y el holocausto. Madrid, Taurus, 1997. RHODES, M., HEYWOOD, P. y WRIGHT, V. Developments in West European Politics. Londres, Macmillan Press, 1997. FUSI, Juan Pablo y PALAFOX, Jordi. España, 1808-1996. El desafío de la modernidad. Madrid, Espasa, 1997. CRUZ, Rafael y PÉREZ LEDESMA, Manuel (eds.. Cultura y movilización en la España contemporánea. Madrid, Alianza, 1997. TUSELL, Javier, MONTERO, Feliciano y MARÍN, José María (eds.. Las derechas en la España contemporánea. Barcelona, Anthropos-UNED, 1997. LÓPEZ MORA, Fernando. Pobreza y acción social en Córdoba, 1750-1900. Córdoba, Diputación Provincial, 1997. TOSCAS Y SANTAMANS, Eliseu. L'Estat i els poders locáis a la Catalunya del segle XIX. Una visto desde Sarria (1780-1860. Barcelona, Publicacions de L'Abadía de Montserrat, 1997. SABIO ALCUTÉN, Alberto. Los montes públicos en Huesca, 1850-1930. Huesca, Instituto de Estudios Altoaragoneses,1998. ZURITA ALDEGUER, Rafael. Notables, políticos y clientes. La política conservadora en Alicante. 1875-1898. Alicante, Instituto de Cultura "Juan Gil Albert", 1996. JULIA, Santos. Los socialistas en la política española. 1879-1982. Madrid, Taurus, 1997. MARTÍN RAMOS, José Luis. Historia de la Unión General de Trabajadores. Volumen II: Historia de UGT (1914-1930. Madrid, Publicaciones Unión y Centro de Estudios Históricos, 1998. CASTILLO, Santiago. Historia de la Unión General de Trabajadores. Volumen I: Hacia la mayoría de edad (1888-1914. Madrid, Publicaciones Unión y Centro de Estudios Históricos, 1998. Cien años después. Colección dirigida por Juan Pablo FUSI. Madrid, Biblioteca Nueva, 1996, 1997 y 1998. LUIS MARTÍN, Francisco de y

STRATEGY IMPLEMENTATION STYLES OF MALAYSIAN, THAI AND HUNGARIAN MIDDLE MANAGERS

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Maheshkumar P. Joshi

2004-01-01

Full Text Available There is a need for more comparative empirical research that examines middle manager roles in strategic change. This paper reports a study of middle managers in two dynamic settings: the Asia/Pacific region – Malaysia and Thailand; and Central/Eastern Europe – Hungary. Results of 213 respondents across three countries indicate that middle managers from all three tend toward use of authoritarian management styles even in proactive strategic change situations. However, Hungarians are less likely to use these styles than Thai and Malaysian middle managers. For all three countries, managers with less work experience were found to have lower tendencies to use an authoritarian style of implementation. When top managers exhibit an aggressive strategic posture, middle-managers from all three countries are also less likely to use an authoritarian style.Firms that want to stay competitive in the global market place must continuously evolve by successfully accomplishing strategic change (Struckman & Yammarino 2003. Although senior managers are critical in leading the strategic change process, even the best-planned strategic changes will not achieve their full potential unless they are well implemented. Part of the strategic leadership responsibility, therefore, includes establishing a climate in which the organization's rank and file will experience both a positive attitude about change and the confidence to actively seek change opportunities (Kanter 2003. Research attention is bringing more insight into the important roles of middle-managers in this process of implementing strategic change (Balogun & Jenkins 2003; Floyd & Wooldridge, 1992, 1994; Wooldridge & Floyd 1990. Although there is little doubt that active support by middle managers is critical for the strategies to be well implemented (Guth & MacMillan 1986, there remain many important questions with regard to how middle managers participate in this process (Balogun 2003.The need for research

Tales of sociology and the nursing curriculum: revisiting the debates.

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Aranda, Kay; Law, Kate

2007-08-01

The relationship between nursing and sociology has been extensively debated for more than two decades [Cox, C.A., 1979. Who cares? Nursing and sociology: the development of a symbiotic relationship. Journal of Advanced Nursing 4, 237-252; Cooke, H., 1993. Why teach sociology? Nurse Education Today 13, (3) 210-216; Sharpe, K., 1994. Sociology and the nursing curriculum: a note of caution. Journal of Advanced Nursing 20, (2) 391-395; Sharpe, K., 1995. Why indeed should we teach sociology? A response to Hannah Cooke. Nurse Education Today 15, (1) 52-55; Sharpe, K., 1996. Feedback - sociology and the nursing curriculum: a reply to Sam Porter. Journal of Advanced Nursing 23, (7) 1275-1278; Balsamo, D., Martin, S.I., 1995a. Developing the sociology of health in nurse education: towards a more critical curriculum. Part 1. Andragogy and sociology in Project 2000. Nurse Education Today 15, 427-432; Balsamo, D., Martin, S.I., 1995b. Developing the sociology of health in nurse education: towards a more critical curriculum. Part 2. Linking methodology and epistemology. Nurse Education Today 15, 427-432; Porter, S., 1995. Sociology and the nursing curriculum: a defence. Journal of Advanced Nursing 21, (6) 1130-1135; Porter, S., 1996. Why teach sociology? A contribution to the debate. Nurse Education Today, 16, 170-174; Porter, S., 1997. Sociology and the nursing curriculum: a further comment. Journal of Advanced Nursing 26, (1) 214-218; Porter, S., 1998. Social Theory and Nursing Practice. Macmillan, Basingstoke; Corlett, J., 2000. The perceptions of nurse teacher, student nurses and preceptors of the theory-practice gap in nurse education. Nurse Education Today 20, 499-505; Allen, D., 2001. Review article: nursing and sociology: an uneasy marriage?. Sociology of Health and Illness 23, (3) 386-396; Pinikahana, J., 2003. Role of sociology within the nursing enterprise: some reflections on the unfinished debate. Nursing and health Sciences 5, (2) 175-180; Holland, K., 2004

Book Reviews

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Nico G. Schulte Nordholt

1996-01-01

Full Text Available - Timothy P. Barnard, Raja Ali Haji, Di dalam berkekalan persahabatan: ‘In everlasting friendship’; Letters from Raja Ali Haji, edited by Jan van der Putten and Al Azhar. Semaian 13. Leiden: Department of Languages and Cultures of Southeast Asia and Oceania, 1995, 292 + x pp., maps. - Robert Blust, L. Smits, Irian Jaya source materials, no. 5, series B-no. 2. The J.C. Anceaux collection of wordlists of Irian Jaya Languages. A: Austronesian languages (part II. Leiden/Jakarta, 1992, 288 pp., C.L. Voorhoeve (eds. - Peter Boomgaard, Mason C. Hoadley, Towards a feudal mode of production; West Java, 1680-1800. Singapore: Institute of Southeast Asian Studies [ in cooperation with the Nordic Institute of Asian Studies, Copenhagen], 1994, x + 241 pp. - Freek Colombijn, Muriel Charras, Spontaneous settlements in Indonesia; Agricultural pioneers in southern Sumatra. Migrations spontanées en Indonésie; La colonisation agricole de sud de Sumatra. Jakarta: Departemen Transmigrasi; Paris: ORSTOM-CNRS, 1993, 405 pp., Marc Pain (eds. - Dick Douwes, Hussin Mutalib, Islam, Muslims and the modern state; Case-studies of Muslims in thirteen countries. London: MacMillan; New York: St. Martin Press, 1994, 374 pp., Taj ul-Islam Hashimi (eds. - J. van Goor, H.W. van den Doel, De stille macht; Het Europse binnenlands bestuur op Java en Madoera, 1808-1942. Amsterdam: Bert Bakker, 1994, 578 pp. - Stuart Kirsch, J.W. Schoorl, Culture and change among the Muyu. Translated by G.J. van Exel. Translation Series 23. Leiden: KITLV Press, 1993, xiv + 322 pp. - Bernd Nothofer, Ger P. Resink, Topics in descriptive Papuan linguistics. Leiden: Vakgroep Talen en Culturen van Zuidoost-Azië en Oceanië, Rijksuniversiteit te Leiden, 1994, viii + 154 pp. - Gerard Persoon, Robin Broad, Plundering paradise; The struggle for the environment in the Philippines. Berkeley: University of California Press, 1993, xvi + 197 pp., John Cavanagh (eds. - Gerard Persoon, Thomas N. Headland

BOOK REVIEW An Introduction to Relativity An Introduction to Relativity

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Dray, Tevian

2011-02-01

cosmology, a formula for Lorentz transformations in an arbitrary direction, and numerous discussions of early work in the field, complete with original references. My only real quibble with this book (apart from the use of signature (+ - - -) is that, without comment, it makes some rather sophisticated assumptions about the reader. Chapter 1, the self-described `crash course' in special relativity, expects the reader to be comfortable with standard but nontrivial manipulations of Maxwell's equations, with hyperbolic trigonometry, and to be able to comprehend a statement that Newton's first law `remains as it is' in special relativity, without any statement of the law itself. Tensor notation is also introduced much too quickly in this chapter, although this topic is revisited later in more detail. These are not unreasonable assumptions about the intended audience, who are likely to be graduate students in physics or workers in the field. But the addition of a few explanatory remarks, or an explicit statement of the intended audience, might have encouraged the less experienced reader to keep reading. In summary, this is an excellent book, which researchers in relativity will treasure for its historical perspective. Instructors of a first course in general relativity who are seeking a `math first' approach should definitely take a look, although they should be prepared to explain some missing details in the presentation. References [1] Narlikar J V 1979 Lectures on General Relativity and Cosmology (London: Macmillan) [2] Narlikar J V 2002 An Introduction to Cosmology (Cambridge: Cambridge University Press)

Effects of Mineral Phosphorous Fertilization and cd Loading on cd Translocation from Soil to Corn (Zea mays L.)

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László, Márton, ,, Dr.

2010-05-01

monographs on the evaluation of carcinogenic risk to humans, vol 58. Lyon. Márton L. 2004. Annual Report. RISSAC. Budapest. 10 p. Meagher, D. 1991. The Macmillan Dictionary of The Australian Environment, Macmillan Education Australia Pty Ltd. National Environment Protection Council (NEPC). 1998. National Environment Protection Measure for the National Pollutant Inventory (accessed, May, 1999) New Jersey Department of Health (NDH), Right to Know Program. 1986. TRIFacts, Cadmium (accessed, May, 1999) NTP Chemical Repository, Radian Corporation, Cadmium. 1991. (accessed, May, 1999) Occupational Health and Safety Administration (OSHA). 1992. Occupational exposure to cadmium. Department of Labour. 42102-42427. Richardson, M. 1992. Dictionary of Substances and their Effects, Royal Society of Chemistry, Clays Ltd, England. Risk Assessment Information System (RAIS). 1991. Toxicity summary for cadmium. Chemical Hazard Evaluation and Communication Group, Biomedical and Environmental Information Analysis Section, Health and Safety Research Division. Sittig, M. 1991. Handbook of Toxic and Hazardous Chemicals and Carcinogens, 3rd edition, Noyes Publications, USA. Technical Advisory Panel (TAP). 1999. Final Report to the National Environment Protection Council. US Department of Health and Human Services. 1990. NIOSH Pocket Guide to Chemical Hazards, Publication No. 90-117. Worksafe Australia (WA). 1996. Exposure Standard Cadmium and compounds (as Cd) (accessed, May, 1999) World Health Organisation (WHO). 1992. Environmental Health Criteria 134 - Cadmium International Programme on Chemical Safety (IPCS) Monograph. World Health Organisation (WHO). 2001. Safety evaluation of certain food additives and contaminants. Fifty-fifth meeting of the joint FAO/WHO expert committee on feed additives, Toxicological monographs, WHO food additives series No 46. WHO. Geneva.

Book Reviews

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Redactie KITLV

2002-07-01

Full Text Available -Martin Baier, Han Knapen, Forests of fortune?; The environmental history of Southeast Borneo, 1600-1880. Leiden: The KITLV Press, 2001, xiv + 487 pp. [Verhandelingen 189] -Jean-Pascal Bassino, Per Ronnas ,Entrepreneurship in Vietnam; Transformations and dynamics. Copenhagen: Nordic Institute of Asian Studies (NIAS and Singapore: Institute of Southeast Asian Studies, 2001, xii + 354 pp., Bhargavi Ramamurty (eds -Adriaan Bedner, Renske Biezeveld, Between individualism and mutual help; Social security and natural resources in a Minangkabau village. Delft: Eburon, 2001, xi + 307 pp. -Linda Rae Bennett, Alison Murray, Pink fits; Sex, subcultures and discourses in the Asia-Pacific. Clayton, Victoria: Monash Asia Institute, 2001, xii + 198 pp. [Monash Papers on Southeast Asia 53.] -Peter Boomgaard, Laurence Monnais-Rousselot, Médecine et colonisation; L'aventure indochinoise 1860-1939. Paris: CNRS Editions, 1999, 489 pp. -Ian Coxhead, Yujiro Hayami ,A rice village saga; Three decades of Green revolution in the Philippines. Houndmills, Basingstoke: MacMillan, 2000, xviii + 274 pp., Masao Kikuchi (eds -Robert Cribb, Frans Hüsken ,Violence and vengeance; Discontent and conflict in New Order Indonesia. Saarbrücken: Verlag für Entwicklungspolitik, 2002, 163 pp. [Nijmegen Studies in Development and Cultural Change 37.], Huub de Jonge (eds -Frank Dhont, Michael Leifer, Asian nationalism. London: Routledge, 2000, x + 210 pp. -David van Duuren, Joseph Fischer ,The folk art of Bali; The narrative tradition. Kuala Lumpur: Oxford University Press, 1998, xx + 116 pp., Thomas Cooper (eds -Cassandra Green, David J. Stuart-Fox, Pura Besakih; Temple, religion and society in Bali. Leiden: KITLV Press, xvii + 470 pp. [Verhandelingen 193.] -Hans Hägerdal, Vladimir I. Braginsky ,Images of Nusantara in Russian literature. Leiden: KITLV Press, 1999, xxvi + 516 pp., Elena M. Diakonova (eds -Hans Hägerdal, David Chandler, A history of Cambodia (third edition. Boulder

Book Reviews

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Redactie KITLV

2002-07-01

Full Text Available -Alan L. Karras, Lauren A. Benton, Law and colonial cultures: Legal regimes in world history, 1400-1900. Cambridge: Cambridge University Press, 2002. xiii + 285 pp. -Sidney W. Mintz, Douglass Sullivan-González ,The South and the Caribbean. Jackson: University Press of Mississippi, 2001. xii + 208 pp., Charles Reagan Wilson (eds -John Collins, Peter Redfield, Space in the tropics: From convicts to rockets in French Guiana. Berkeley: University of California Press, 2000. xiii + 345 pp. -Vincent Brown, Keith Q. Warner, On location: Cinema and film in the Anglophone Caribbean. Oxford: Macmillan, 2000. xii + 194 pp. -Ann Marie Stock, Jacqueline Barnitz, Twentieth-century art of Latin America. Austin: University of Texas Press, 2001. 416 pp. -Ineke Phaf, J.J. Oversteegen, Herscheppingen: De wereld van José Maria Capricorne. Emmastad, Curacao: Uitgeverij ICS Nederland/Curacao, 1999. 168 pp. -Halbert Barton, Frances R. Aparicio, Listening to Salsa: Gender, latin popular music, and Puerto Rican cultures. Hanover NH: Wesleyan University Press, 1998. xxi + 290 pp. -Pedro Pérez Sarduy, John M. Kirk ,Culture and the Cuban revolution: Conversations in Havana. Gainesville: University Press of Florida, 2001. xxvi + 188 pp., Leonardo Padura Fuentes (eds -Luis Martínez-Fernández, Damián J. Fernández, Cuba and the politics of passion. Austin: University of Texas Press, 2000. 192 pp. -Eli Bartra, María de Los Reyes Castillo Bueno, Reyita: The life of a black Cuban woman in the twentieth century. Durham NC: Duke University Press, 2000. 182 pp. -María del Carmen Baerga, Felix V. Matos Rodríguez, Women and urban change in San Juan, Puerto Rico, 1820-1868. Gainesville: University Press of Florida, 1999. xii + 180 pp. [Reissued in 2001 as: Women in San Juan, 1820-1868. Princeton NJ: Markus Weiner Publishers.] -Kevin A. Yelvington, Winston James, Holding aloft the banner of Ethiopa: Caribbean radicalism in early twentieth-century America. New York: Verso, 1998

3D-Digital soil property mapping by geoadditive models

Science.gov (United States)

Papritz, Andreas

2016-04-01

account for nonlinear effects of covariates by fitting componentwise smooth, nonlinear functions to the covariates (additive terms). REML estimation of model parameters and computing best linear unbiased predictions (BLUP) builds in the geoAM framework on the fact that both geostatistical and additive models can be parametrized as linear mixed models Wand, 2003. For 3D-DSM analysis of soil data, it is natural to model depth profiles of soil properties by additive terms of soil depth. Including interactions between these additive terms and covariates of the spatial mean function allows to model spatially varying depth profiles. Furthermore, with suitable choice of the basis functions of the additive term (e.g. polynomial regression splines), non-constant support of the soil data can be taken into account. Finally, boosting (Bühlmann and Hothorn, 2007) can be used for selecting covariates for the spatial mean function. The presentation will detail the geoAM approach and present an example of geoAM for 3D-analysis of legacy soil data. Arrouays, D., McBratney, A. B., Minasny, B., Hempel, J. W., Heuvelink, G. B. M., MacMillan, R. A., Hartemink, A. E., Lagacherie, P., and McKenzie, N. J. (2014). The GlobalSoilMap project specifications. In GlobalSoilMap Basis of the global spatial soil information system, pages 9-12. CRC Press. Bishop, T., McBratney, A., and Laslett, G. (1999). Modelling soil attribute depth functions with equal-area quadratic smoothing splines. Geoderma, 91(1-2), 27-45. Bühlmann, P. and Hothorn, T. (2007). Boosting algorithms: Regularization, prediction and model fitting. Statistical Science, 22(4), 477-505. Kammann, E. E. and Wand, M. P. (2003). Geoadditive models. Journal of the Royal Statistical Society. Series C: Applied Statistics, 52(1), 1-18. Kyriakidis, P. (2004). A geostatistical framework for area-to-point spatial interpolation. Geographical Analysis, 36(3), 259-289. Orton, T., Pringle, M., and Bishop, T. (2016). A one-step approach for modelling

Book Reviews

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Redactie KITLV

2004-07-01

, and modernity in Dominican history. Stanford CA: Stanford University Press, 2003. x + 384 pp. -Eric Paul Roorda, Bernardo Vega, Almoina, Galíndez y otros crímenes de Trujillo en el extranjero. Santo Domingo: Fundación Cultural Dominicana, 2001. 147 pp.''Diario de una misión en Washington. Santo Domingo: Fundación Cultural Dominicana, 2002. 526 pp. -Gerben Nooteboom, Aspha Bijnaar, Kasmoni: Een spaartraditie in Suriname en Nederland. Amsterdam: Uitgeverij Bert Bakker, 2002. 378 pp. -Dirk H.A. Kolff, Chan E.S. Choenni ,Hindostanen: Van Brits-Indische emigranten via Suriname tot burgers van Nederland. The Hague: Communicatiebureau Sampreshan, 2003. 224 pp., Kanta Sh. Adhin (eds -Dirk H.A. Kolff, Sandew Hira, Het dagboek van Munshi Rahman Khan. The Hague: Amrit/Paramaribo: NSHI, 2003. x + 370 pp. -William H. Fisher, Neil L. Whitehead, Dark Shamans: Kanaimà and the poetics of violent death. Durham NC: Duke University Press, 2002. 309 pp. -David Scott, A.J. Simoes da Silva, The luxury of nationalist despair: George Lamming's fiction as decolonizing project. Amsterdam: Rodopi, 2000. 217 pp. -Lyn Innes, Maria Cristina Fumagalli, The flight of the vernacular. Amsterdam: Rodopi, 2001. xvi + 303 pp. -Maria Cristina Fumagalli, Tobias Döring, Caribbean-English passages: Intertextuality in a postcolonial tradition. London: Routledge, 2002. xii + 236 pp. -A. James Arnold, Celia Britton, Race and the unconscious: Freudianism in French Caribbean thought. Oxford: Legenda, 2002. 115 pp. -Nicole Roberts, Dorothy E. Mosby, Place, language, and identity in Afro-Costa Rican literature. Columbia: University of Missouri Press, 2003. xiii + 248 pp. -Stephen Steumpfle, Philip W. Scher, Carnival and the formation of a Caribbean transnation. Gainesville: University Press of Florida, 2003. xvi + 215 pp. -Peter Manuel, Frances R. Aparicho ,Musical migrations: transnationalism and cultural hybridity in Latin/o America, Volume 1. With Maria Elena Cepeda. New York: Palgrave Macmillan, 2003. 216

Book Reviews

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Redactie KITLV

2004-01-01

Pennsylvania Press, 2003. viii + 305 pages. -Lise Winer, Kim Johnson, Renegades: The history of the renegades steel orchestra of Trinidad and Tobago. With photos by Jeffrey Chock. Oxford UK: Macmillan Caribbean Publishers, 2002. 170 pp. -Jerome Teelucksingh, Glenford Deroy Howe, Race, war and nationalism: A social history of West Indians in the first world war. Kingston: Ian Randle/Oxford UK: James Currey, 2002. vi + 270 pp. -Geneviève Escure, Glenn Gilbert, Pidgin and Creole linguistics in the twenty-first century. New York: Peter Lang Publishing, 2002. 379 pp. -George L. Huttar, Eithne B. Carlin ,Atlas of the languages of Suriname. Leiden, The Netherlands: KITLV Press/Kingston: Ian Randle, 2002. vii + 345 pp., Jacques Arends (eds

Direct laboratory observation of fluid distribution and its influence on acoustic properties of patchy saturated rocks

Science.gov (United States)

Lebedev, M.; Clennell, B.; Pervukhina, M.; Shulakova, V.; Mueller, T.; Gurevich, B.

2009-04-01

predictions of White's model. The results illustrate the non-unique relationships between saturation and velocity in sandstones dependent on texture and fluid displacement history: fuller understanding of these phenomena is needed for accurate assessment of time lapse seismic measurements, be they for oil and gas recovery or for CO2 disposal purposes. Gassmann, F., 1951, Elastic waves through a packing of spheres. Geophysics 16, 673-685; Mavko, G., T. Mukerji, and J. Dvorkin, 1998, The Rock Physics Handbook: Tools for seismic analysis in porous media: Cambridge University Press. Wood, A. W., 1955, A Textbook of Sound, The MacMillan Co., New York, 360 pp. Hill, R., 1963, Elastic properties of reinforced solids: some theoretical principles. J. Mech. Phys. Solids, 11, 357-372. Hill, R., 1952, The elastic behavior of crystalline aggregates. Proc. Physical Soc., London, A65, 349-354. J. Toms, T.M. Mueller, B. Gurevich, 2007 Seismic attenuation in porous rocks with random patchy saturation. Geophysical Prospecting, 55, 671-678.

Book Reviews

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Redactie KITLV

1995-01-01

Full Text Available -Sidney W. Mintz, Paget Henry ,C.L.R. James' Caribbean. Durham: Duke University Press, 1992. xvi + 287 pp., Paul Buhle (eds -Allison Blakely, Jan M. van der Linde, Over Noach met zijn zonen: De Cham-ideologie en de leugens tegen Cham tot vandaag. Utrecht: Interuniversitair Instituut voor Missiologie en Oecumenica, 1993. 160 pp. -Helen I. Safa, Edna Acosta-Belén ,Researching women in Latin America and the Caribbean. Boulder CO: Westview, 1993. x + 201 pp., Christine E. Bose (eds -Helen I. Safa, Janet H. Momsen, Women & change in the Caribbean: A Pan-Caribbean Perspective. Bloomington: Indiana University Press; Kingston: Ian Randle, 1993. x + 308 pp. -Paget Henry, Janet Higbie, Eugenia: The Caribbean's Iron Lady. London: Macmillan, 1993. 298 pp. -Kathleen E. McLuskie, Moira Ferguson, Subject to others: British women writers and Colonial Slavery 1670-1834. New York: Routledge, 1992. xii + 465 pp. -Samuel Martínez, Senaida Jansen ,Género, trabajo y etnia en los bateyes dominicanos. Santo Domingo: Instituto Tecnológico de Santo Domingo, Programa de Estudios se la Mujer, 1991. 195 pp., Cecilia Millán (eds -Michiel Baud, Roberto Cassá, Movimiento obrero y lucha socialista en la República Dominicana (desde los orígenes hasta 1960. Santo Domingo: Fundación Cultural Dominicana, 1990. 620 pp. -Paul Farmer, Robert Lawless, Haiti's Bad Press. Rochester VT: Schenkman Press, 1992. xxvii + 261 pp. -Bill Maurer, Karen Fog Olwig, Global culture, Island identity: Continuity and change in the Afro-Caribbean Community of Nevis. Chur, Switzerland: Harwood Academic Publishers, 1993. xi + 239 pp. -Viranjini Munasinghe, Kevin A. Yelvington, Trinidad Ethnicity. Knoxville: University of Tennesee Press, 1993. vii + 296 pp. -Kevin K. Birth, Christine Ho, Salt-water Trinnies: Afro-Trinidadian Immigrant Networks and Non-Assimilation in Los Angeles. New York: AMS Press, 1991. xvi + 237 pp. -Steven Gregory, Andrés Isidoro Pérez y Mena, Speaking with the dead

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Redactie KITLV

1999-01-01

: Editorial de la Universidad de Puerto Rico, 1993. xxvi + 321 pp. -Andrés Serbin, Jorge Rodríguez Beruff ,Security problems and policies in the post-cold war Caribbean. London: :Macmillan; New York: St. Martin's, 1996. 249 pp., Humberto García Muñiz (eds -Alex Dupuy, Irwin P. Stotzky, Silencing the guns in Haiti: The promise of deliberative democracy. Chicago: University of Chicago Press, 1997. xvi + 294 pp. -Carrol F. Coates, Myriam J.A. Chancy, Framing silence: Revolutionary novels by Haitian women. New Brunswick NJ: Rutgers University Press, 1997. ix + 200 pp. -Havidán Rodríguez, Walter Díaz, Francisco L. Rivera-Batiz ,Island paradox: Puerto Rico in the 1990's. New York: Russel Sage Foundation, 1996. xi + 198 pp., Carlos E. Santiago (eds -Ramona Hernández, Alan Cambeira, Quisqueya la Bella: The Dominican Republic in historical and cultural perspective. Armonk NY: M.E. Sharpe, 1996. xi + 272 pp. -Ramona Hernández, Emilio Betances ,The Dominican Republic today: Realities and perspectives. New York: Bildner Center for Western Hemisphere studies, CUNY, 1996. 205 pp., Hobart A. Spalding, Jr. (eds -Bonham C. Richardson, Eberhard Bolay, The Dominican Republic: A country between rain forest and desert. Wekersheim, FRG: Margraf Verlag, 1997. 456 pp. -Virginia R. Dominguez, Patricia R. Pessar, A visa for a dream: Dominicans in the United States. Boston: Allyn and Bacon, 1995. xvi + 98 pp. -Diane Austin-Broos, Nicole Rodriguez Toulis, Believing identity: Pentecostalism and the mediation of Jamaican ethnicity and gender in England. Oxford NY: Berg, 1997. xv + 304 p. -Mary Chamberlain, Trevor A. Carmichael, Barbados: Thirty years of independence. Kingston: Ian Randle Publishers, 1996. xxxv + 294 pp. -Paul van Gelder, Gert Oostindie, Het paradijs overzee: De 'Nederlandse' Caraïben en Nederland. Amsterdam: Bert Bakker, 1997. 385 pp. -Roger D. Abrahams, Richard D.E. Burton, Afro-Creole: Power, Opposition, and Play in the Caribbean. Ithaca NY: Cornell University Press, 1997. x

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Redactie KITLV

1994-01-01

Full Text Available -Peter Hulme, Simon Gikandi, Writing in limbo: Modernism and Caribbean literature. Ithaca: Cornell University Press, 1992. x + 260 pp. -Charles V. Carnegie, Alistair Hennessy, Intellectuals in the twentieth-century Caribbean (Volume 1 - Spectre of the new class: The Commonwealth Caribbean. London: Macmillan, 1992. xvii 204 pp. -Nigel Rigby, Anne Walmsley, The Caribbean artists movement, 1966-1972: A literary and cultural history. London: New Beacon Books, 1992. xx + 356 pp. -Carl Pedersen, Tyrone Tillery, Claude McKay: A black poet's struggle for identity. Amherst: University of Massachusetts Press, 1992. xii + 235 pp. -Simone Dreyfus, Irving Rouse, The Tainos: Rise and decline of the people who greeted Columbus. New Haven: Yale University Press, 1992. xii + 211 pp. -Louis Allaire, Antonio M. Stevens-Arroyo, Cave of the Jagua: The mythological world of the Taino. Alburquerque: University of New Mexico Press, 1988. xiii + 282 pp. -Irving Rouse, William F. Keegan, The people who discovered Columbus: The prehistory of the Bahamas. Gainesville: University of Florida Press, 1992. xx + 279 pp. -Neil L. Whitehead, Philip P. Boucher, Cannibal encounters: Europeans and Island Caribs, 1492-1763. Baltimore: John Hopkins University Press, 1992. xii + 217 pp. -Peter Kloos, Kaliña, des amérindiens à Paris: Photographies du prince Roland. Présentées par Gérard Collomb. Paris: Créaphis, 1992. 119 pp. -Maureen Warner-Lewis, Alan Gregor Cobley ,The African-Caribbean connection: Historical and cultural perspectives. Bridgetown, Barbados: Department of History, University of the West Indies, Cave Hill, 1990. viii + 171 pp., Alvin Thompson (eds -H. Hoetink, Jean-Luc Bonniol, La couleur comme maléfice: une illustration créole de la généalogie des 'Blancs' et des 'Noirs'. Paris: Albin Michel, 1992. 304 pp. -Michael Aceto, Richard Price ,Two evenings in Saramaka. Chicago and London: University of Chicago Press, 1991. xvi + 417 pp., Sally Price (eds -Jorge P�

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Redactie KITLV

2003-07-01

Full Text Available -Edward L. Cox, Judith A. Carney, Black rice: The African origin of rice cultivation in the Americas. Cambridge MA: Harvard University Press, 2001. xiv + 240 pp. -David Barry Gaspar, Brian Dyde, A history of Antigua: The unsuspected Isle. Oxford: Macmillan Education, 2000. xi + 320 pp. -Carolyn E. Fick, Stewart R. King, Blue coat or powdered wig: Free people of color in pre-revolutionary Saint Domingue. Athens: University of Georgia Press, 2001. xxvi + 328 pp. -César J. Ayala, Birgit Sonesson, Puerto Rico's commerce, 1765-1865: From regional to worldwide market relations. Los Angeles: UCLA Latin American Center Publications, 200. xiii + 338 pp. -Nadine Lefaucheur, Bernard Moitt, Women and slavery in the French Antilles, 1635-1848. Bloomington: Indiana University Press, 2001. xviii + 217 pp. -Edward L. Cox, Roderick A. McDonald, Between slavery and freedom: Special magistrate John Anderson's journal of St. Vincent during the apprenticeship. Jamaica: University of the West Indies Press, 2001. xviii + 309 pp. -Jaap Jacobs, Benjamin Schmidt, Innocence abroad: The Dutch imagination and the new world, 1570-1670. New York: Cambridge University Press, 2001. xxviii + 450 pp. -Wim Klooster, Johanna C. Prins ,The Low countries and the New World(s: Travel, Discovery, Early Relations. Lanham NY: University Press of America, 2000. 226 pp., Bettina Brandt, Timothy Stevens (eds -Wouter Gortzak, Gert Oostindie ,Knellende koninkrijksbanden: Het Nederlandse dekolonisatiebeleid in de Caraïben, 1940-2000. Volume 1, 1940-1954; Volume 2, 1954-1975; Volume 3, 1975-2000. 668 pp. Amsterdam: Amsterdam University Press, 2001., Inge Klinkers (eds -Richard Price, Ellen-Rose Kambel, Resource conflicts, gender and indigenous rights in Suriname: Local, national and global perspectives. Leiden, The Netherlands: self-published, 2002, iii + 266. -Peter Redfield, Richard Price ,Les Marrons. Châteauneuf-le-Rouge: Vents d'ailleurs, 2003. 127 pp., Sally Price (eds -Mary Chamberlain

Fault Control on Copper Depositsin the Sar Cheshmeh Area Indicated by Remote Sensing & Geographic Information Systems (GIS

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Hojjat Ollah Safari

2016-07-01

Iran. Sabins, F.F., 1996. Remote sensing principle and interpretation. Macmillan Education Australia, New York, 494 pp. Safari, H., Pirasteh, S. and Shattri, B.M., 2011. Role of Kazerun Fault for Localizing Oil Seepage in the Zagros Mountains, Iran: an Application of GiT. International Journal of Remote sensing, 32(1: 1-16. Shafiei, B., 2010. Lead isotope signatures of the igneous rocks and porphyry copper deposits from the Kerman Cenozoic magmatic arc (SE Iran, and their magmatic-metallogenetic implication. Ore Geology Reviews, 38: 27-36. Zarasvandi, A.R., 2004. Geology and genesis of the Darreh-Zerreshk and Ali-Abad copper deposits, Southwest of Yazd, based on fluid inclusion and isotope studies. Ph.D. Thesis, Shiraz University, Shiraz, Iran, 280 pp.

Book Reviews

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Redactie KITLV

2002-01-01

invasion. New York: Viking, 1999. xix + 408 pp. -Alex Dupuy, John R. Ballard, Upholding democracy: The United States military campaign in Haiti, 1994-1997. Westport CT: Praeger, 1998. xviii + 263 pp. -Anthony Payne, Jerry Haar ,Canadian-Caribbean relations in transition: Trade, sustainable development and security. London: Macmillan, 1999. xxii + 255 pp., Anthony T. Bryan (eds -Bonham C. Richardson, Sergio Díaz-Briquets ,Conquering nature: The environmental legacy of socialism in Cuba. Pittsburgh: University of Pittsburgh Press, 2000. xiii + 328 pp., Jorge Pérez-López (eds -Neil L. Whitehead, Gérard Collomb ,Na'na Kali'na: Une histoire des Kali'na en Guyane. Petit Bourg, Guadeloupe: Ibis Rouge Editions, 2000. 145 pp., Félix Tiouka (eds -Neil L. Whitehead, Upper Mazaruni Amerinidan District Council, Amerinidan Peoples Association of Guyana, Forest Peoples Programme, Indigenous peoples, land rights and mining in the Upper Mazaruni. Nijmegan, Netherlands: Global Law Association, 2000. 132 pp. -Salikoko S. Mufwene, Ronald F. Kephart, 'Broken English': The Creole language of Carriacou. New York: Peter Lang, 2000. xvi + 203 pp. -Salikoko S. Mufwene, Velma Pollard, Dread talk: The language of Rastafari. Kingston: Canoe Press: Montreal: McGill-Queen's University Press. Revised edition, 2000. xv + 117 pp.

Book reviews

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Redactie KITLV

1992-07-01

Full Text Available -Jay B. Haviser, Jerald T. Milanich ,First encounters: Spanish explorations in the Caribbean and the United States, 1492-1570. Gainesville FL: Florida Museum of Natural History & University Presses of Florida, 1989. 221 pp., Susan Milbrath (eds -Marvin Lunenfeld, The Libro de las profecías of Christopher Columbus: an en face edition. Delano C. West & August Kling, translation and commentary. Gainesville FL: University of Florida Press, 1991. x + 274 pp. -Suzannah England, Charles R. Ewen, From Spaniard to Creole: the archaeology of cultural formation at Puerto Real, Haiti. Tuscaloosa AL; University of Alabama Press, 1991. xvi + 155 pp. -Piero Gleijeses, Bruce Palmer Jr., Intervention in the Caribbean: the Dominican crisis of 1965. Lexington KY: University Press of Kentucky, 1989. -Piero Gleijeses, Herbert G. Schoonmaker, Military crisis management: U.S. intervention in the Dominican Republic, 1965. Westport CT: Greenwood Press, 1990. 152 pp. -Jacqueline A. Braveboy-Wagner, Fitzroy André Baptiste, War, cooperation, and conflict: the European possessions in the Caribbean, 1939-1945. Westport CT: Greenwood Press, 1988. xiv + 351 pp. -Peter Meel, Paul Sutton, Europe and the Caribbean. London: Macmillan Caribbean, 1991. xii + 260 pp. -Peter Meel, Betty Secoc-Dahlberg, The Dutch Caribbean: prospects for democracy. New York: Gordon and Breach, 1990. xix + 333 pp. -Michiel Baud, Rosario Espinal, Autoritarismo y democracía en la política dominicana. San José, Costa Rica: Ediciones CAPEL, 1987. 208 pp. -A.J.G. Reinders, J.M.R. Schrils, Een democratie in gevaar: een verslag van de situatie op Curacao tot 1987. Assen, Maastricht: Van Gorcum, 1990. xii + 292 pp. -Andrés Serbin, David W. Dent, Handbook of political science research on Latin America: trends from the 1960s to the 1990s. Westport CT: Greenwood, 1990. -D. Gail Saunders, Dean W. Collinwood, The Bahamas between worlds. Decatur IL: White Sound Press, 1989. vii + 119 pp. -D. Gail Saunders, Dean

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Redactie KITLV

1996-01-01

Full Text Available -Sandra L. Richards, Judy S.J. Stone, Theatre. London: Macmillan Caribbean, 1994. xii + 268 pp. -Lowell Fiet, Errol Hill, The Jamaican stage, 1655-1900: profile of a colonial theatre. Amherst: University of Massachusetts Press, 1992. xiv + 346 pp. -Supriya Nair, Bruce King, V.S. Naipaul. New York: St. Martin's Press, 1993. viii + 170 pp. -Agnes Lugo-Ortiz, Donald E. Rice, The rhetorical uses of the authorizing figure: Fidel Castro and José Martí. Westport CT: Praeger, 1992. xviii + 163 pp. -Graciella Cruz-Taura, Juan A. Martínez, Cuban art and national identity: The Vanguardia painters, 1927-1950. Gainesville: University Press of Florida, 1994. xiv + 189 pp. -Graciella Cruz-Taura, Luis Camnitzer, New art of Cuba. Austin; University of Texas Press, 1994. xxx + 400 pp. -Gary Brana-Shute, Richard Price ,On the mall: Presenting Maroon tradition-bearers at the 1992 festival of American folklife. Bloomington: Folklore Institute, Indiana University, 1994. xi + 123 pp., Sally Price (eds -Erika Bourguignon, Stephan Palmié, Das Exil der Götter: Geschichte und Vorstellungswelt einer afrokubanischen Religion. Frankfurt: Peter Lang, 1991. vii + 520 pp. -Carla Freeman, Daniel Miller, Modernity, an ethnographic approach: Dualism and mass consumption in Trinidad. Oxford: Berg Publishers, 1994. 340 pp. -Daniel A. Segal, Kelvin Singh, Race and class: Struggles in a colonial state: Trinidad 1917-1945. Kingston; The Press - University of the West Indies, 1994. xxii + 284 pp. -Evelyne Huber, Patsy Lewis, Jamaica: Preparing for the twenty-first century. Kingston: Ian Randle, 1994. xvi + 272 pp. -Diane Vernon, Elisa Janine Sobo, One blood: The Jamaican body. Albany NY: State University of New York Press, 1993. vii + 329 pp. -Robert Myers, Patrick L. Baker, Centring the periphery: Chaos. order and the ethnohistory of Dominica. Kingston: The Press - University of the West Indies, 1994. xxviii + 251 pp. -Riva Berleant-Schiller, Debra Evenson, Revolution in the

Risk Governance of Multiple Natural Hazards: Centralized versus Decentralized Approach in Europe

Science.gov (United States)

Komendantova, Nadejda; Scolobig, Anna; Vinchon, Charlotte

2014-05-01

social sciences. The implementation of a multi-risk approach can be strengthened through the creation of multi-risk platforms and multi-risk commissions, which can liaise between risk management experts and local communities and to unify numerous actions on natural hazard management. However, the multi-risk approach cannot be a subsidiary to a single risk approach, and both have to be pursued. References: IRGC. (2011). Concept note: Improving the management of emerging risks: Risks from new technologies, system interactions, and unforeseen or changing circumstances. International Risk Governance Council (IRGC), Geneva. Kappes, M. S., Keiler, M., Elverfeldt, von K., & Glade, T, (2012). Challenges of analyzing multi-hazard risk: A review. Natural Hazards, 64(2), 1925-1958. doi: 10.1007/s11069-012-0294-2. Komendantova N, Scolobig A, Vinchon C (2013). Multi-risk approach in centralized and decentralized risk governance systems: Case studies of Naples, Italy and Guadeloupe, France. International Relations and Diplomacy, 1(3):224-239 (December 2013) Scolobig, A., Vichon, C., Komendantova, N., Bengoubou-Valerius, M., & Patt, A. (2013). Social and institutional barriers to effective multi-hazard and multi-risk decision-making governance. D6.3 MATRIX project. Selva, J. (2013). Long-term multi-risk assessment: statistical treatment of interaction among risks. Natural Hazards, 67(2),701-722. UNISDR. (2013). Implementing the HYOGO framework for action in Europe: Regional synthesis report 2011-2013. Verweij, M., & Thompson, M. (Eds.). (2006). Clumsy solutions for a complex world: Governance, politics, and plural perceptions. New York: Palgrave Macmillan. White, G., Kates, R., & Burton, I. (2001). Knowing better and losing even more: the use of knowledge in hazards management. Environmental Hazards, 3, 81-92.

Book Reviews

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Redactie KITLV

1994-07-01

Halebsky ,Cuba in transition: Crisis and transformation. With Carolee Bengelsdorf, Richard L. Harris, Jean Stubbs & Andrew Zimbalist. Boulder CO: Westview, 1992. xi + 244 pp., John M. Kirk (eds -Michiel Baud, Andrés L. Mateo, Mito y cultura en la era de Trujillo. Santo Domingo: Librería La Trinitario/Instituto del Libro, 1993. 224 pp. -Edgardo Meléndez, Andrés Serbin, Medio ambiente, seguridad y cooperacíon regional en el Caribe. Caracas: Editorial Nueva Sociedad, 1992. 147 pp. -Dean W. Collinwood, Michael Craton ,Islanders in the stream: A history of the Bahamian people. Volume One: From Aboriginal times to the end of slavery. Athens: University of Georgia Press, 1992. xxxiii + 455 pp., Gail Saunders (eds -Gary Brana-Shute, Alan A. Block, Masters of paradise: Organized crime and the internal revenue service in the Bahamas. New Brunswick NJ: Transaction Publishers, 1991. vii + 319 pp. -Michaeline Crichlow, Patrick Bryan, The Jamaican people 1880-1902. London: Macmillan Caribbean, 1991. xiv + 300 pp. -Faye V Harrison, Lisa Douglass, The power of sentiment: Love, hierarchy, and the Jamaican family elite. Boulder CO: Westview, 1992. xviii + 298 pp. -Frank Jan van Dijk, Bob Marley, Songs of freedom: From 'Judge Not' to 'Redemption Song.' Kingston: Tuff Gong/Bob Marley Foundation / London : Island Records, 1992 (limited edition. 63 pp. + 4 compact discs. -Riva Berleant-Schiller, Veront M. Satchell, From plots to plantations: Land transactions in Jamaica, 1866-1900. Mona: University of the West Indies, 1990. xiii + 197 pp. -Hymie Rubenstein, Christine Barrow, Family, land and development in St. Lucia. Cave Hill, Barbados: Institute for social and economic studies (ISER, University of the West Indies, 1992. xii + 83 pp. -Bonham C. Richardson, Selwyn Ryan, Social and occupational stratification in contemporary Trinidad and Tobago. St. Augustine, Trinidad: ISER, 1991. xiv + 474 pp. -Bill Maurer, Roland Littlewood, Pathology and identity: The work of Mother Earth in Trinidad

Book Reviews

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Redactie KITLV

1993-07-01

the Caribbean. Ames: Iowa State University Press. 1990. xviii + 398 pp. -Ellen M. Schnepel, Max Sulty ,La migration de l'Hindouisme vers les Antilles au XIXe siècle, après l'abolition de l'esclavage. Paris: Librairie de l'Inde, 1989. 255 pp., Jocelyn Nagapin (eds -Viranjini Munasinghe, Steven Vertovec, Hindu Trinidad: Religion, ethnicity and socio-economic change. -Alvina Ruprecht, Selwyn R. Cudjoe, Caribbean women writers: Essays from the first international conference. Amherst: University of Massachusetts Press, 1990. xv + 382 pp. -J. van Donselaar, Michiel van Kempen et al, Nieuwe Surinaamse verhalen. Paramaribo: De Volksboekwinkel, 1986. 202 pp.''Suriname. De Gids 153:791-954. Amsterdam: Meulenhoff, 1990. -J. van Donselaar, Literatuur in Suriname: nieuwe, nog niet eerder gepubliceerde verhalen en gedichten van Surinaamse auteurs. Preludium 5(3: 1-80. Michiel van Kempen (compiler. Breda: Stichting Preludium, 1988.''Verhalen van Surinaamse schrijvers. Michiel van Kempen (compiler. Amsterdam: De Arbeiderspers. 1989. 248 pp.''Hoor die tori! Surinaamse vertellingen. Michiel van Kempen (compiler. Amsterdam: In de Knipscheer, 1990. 267 pp. -Beth Craig, Francis Byrne ,Development and structures of creole languages: Essays in honor of Derek Bickerton. Amsterdam/Philadelphia: John Benjamins, 1991. x + 222 pp., Thom Huebner (eds -William W. Megenney, John M. Lipski, The speech of the negros congos of Panama. Amsterdam/Philadelphia: John Benjamins, 1989. vii + 159 pp. -Hein D. Vruggink, Clare Wolfowitz, Language, style and social space: Stylistic choice in Suriname Javanese. Champaign; University of Illinois Press, 1992. viii + 265 pp. -Keith A.P. Sandiford, Brian Douglas Tennyson, Canadian-Caribbean relations: Aspects of a relationship. Sydney, Nova Scotia: Centre for international studies, 1990. vii + 379 pp. -Gloria Cumper, Philip Sherlock ,The University of the West Indies: A Caribbean response to the challenge of change. London: Macmillan Caribbean, 1990. viii + 315 pp

EDITORIAL: Sensitive structures: refractive indices in nanotechnology Sensitive structures: refractive indices in nanotechnology

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Demming, Anna

2012-12-01

. Express 19 22305-15 [12] Houstoun R A 1925 Kepler's law of refraction Math. Notes 23 1516 [13] Koestler A C 1959 The Sleepwalkers (London: Macmillan)

MODEL PENELITIAN HUBUNGAN POLA PERMUKIMAN DAN KONFLIK ANTAR ETNIK

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Emilya Kalsum

2015-01-01

��. Jurnal Penelitian Antropologi. Pelly, Usman. 1999. “Akar Kerusuhan Etnis di Indonesia: Suatu Kajian Awal Konflik dan Disintegrasi Nasional di Era Reformasi” dalam seminar Memasuki Abad Ke-21: Antropologi Indonesia Menghadapi Krisis Budaya Bangsa. Kampus Universitas Indonesia. 6-8 Mei 1999. Polak, Mayor .1979. Sosiologi, Suatu Buku Pengantar Ringkas. Jakarta: Ikhtiar Baru. Pondy, Louis R. 1967. “Organizational Conflict: Concepts and Models”. Administrative Science Quarterly. Vol. 12, No. 2. September 1967. Porteous, Douglas J. 1977. Environment And Behaviour. Massachusset: Addison Wishley Publishing Co. Putra, Hedhi Sri Ahimsa. 1978. The Transmigration Village of Sidomulyo Yogyakarta. Yogyakarta: Lembaga Pendidikan Kependudukan UGM. Rahardjo, Chodijah B. 1984. Transmigrasi dari Daerah Asal Sampai Benturan Budaya di Tempat Pemukiman. Jakarta: Rajawali. Rapoport, Amos. 1969. House, Form And Culture. London: Prentice-Hall, Inc. Scott, Suzie & Parkey, Hillary. 1998., "Myths And Reality: Anti-Social Behavior In Scotland". Housing Studies. Vol. 13, No. 1, 1998. Sill, David L. 1968. International Encyclopedia of The Social Sciences. The MacMillan Company & The Free Press. Soekanto, Soerjono. 2001. Sosiologi Suatu Pengantar. Jakarta: PT Rajagrafindo Persada. Soelaeman, M. Munandar. 1986. Ilmu Sosial Dasar, Teori dan Konsep Ilmu Sosial. Jakarta : LP FE-UI., Soelaeman, M. Munandar. 1993. Ilmu Sosial Dasar. Bandung: Eresco, Bandung. Sudagung, Hendro Suroyo 2001. Mengurai Pertikaian Etnis, Migrasi Swakarsa Etnis Madura Ke Kalimantan Barat. Institut Studi Arus Informasi. Sulistyo, Hermawan. 1982. Aspek-Aspek Sosial Transmigrasi. Economica. Vol. 10, No.2. Suparlan, Parsudi. 1972. The Javanese In Bandung: Ethnicity In A Medium Sized Indonesian City. M.A., Thesis, University Of Illinois. Suparlan, Parsudi, 1999. Kemajemukan, Hipotesis Kebudayaan Dominan Dan Kesukubangsaan, dalam seminar 'Memasuki Abad ke-21 : Antropologi Indonesia Menghadapi Krisis Budaya Bangsa', di Kampus

New views on changing Arctic vegetation

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Kennedy, Robert E.

2012-03-01

, Caine T N, McKnight D, Townsend A and Williams M W 2004 The landscape continuum: a model for high-elevation ecosystems Bioscience 54 111-21 Stow D A et al 2004 Remote sensing of vegetation and land-cover change in Arctic Tundra Ecosystems Remote Sens. Environ. 89 281-308 Sturm M, Schimel J, Michaelson G, Welker J M, Oberbauer S F, Liston G E, Fahnestock J and Romanovsky V E 2005 Winter biological processes could help convert arctic tundra to shrubland BioScience 55 17-26 Tape K, Sturm M and Racine C 2006 The evidence for shrub expansion in Northern Alaska and the Pan-Arctic Glob. Change Biol. 12 686-702 Thuiller W et al 2008 Predicting global change impacts on plant species' distributions: future challenges Perspect. Plant Ecol. Evol. Syst. 9 137-52 Vogelmann J E, Tolk B and Zhu Z 2009 Monitoring forest changes in the southwestern United States using multitemporal Landsat data Remote Sens. Environ. 113 1739-48 Whittaker R H 1975 Communities and Ecosystems (New York: Macmillan) Woodcock C F et al 2008 Free access to Landsat imagery Science 320 1011 Wulder M A, White J C, Goward S N, Masek J G, Irons J R, Herold M, Cohen W B, Loveland T R and Woodcock C F 2008 Landsat continuity: issues and opportunities for land cover monitoring Remote Sens. Environ. 112 955-69 Zhao M and Running S W 2010 Drought-induced reduction in global terrestrial net primary production from 2000 through 2009 Science 329 940-3

EDITORIAL: Deep brain stimulation, deontology and duty: the moral obligation of non-abandonment at the neural interface Deep brain stimulation, deontology and duty: the moral obligation of non-abandonment at the neural interface

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Fins, Joseph J.; MD; FACP

2009-10-01

conscious state, funded by Intelect Medical Inc. References [1] 1972 Editorial: Psychosurgery Lancet 7767 69-70 [2] Fins J J 2002 The ethical limits of neuroscience The Lancet Neurology 1 213 [3] Fins J J 2003 From psychosurgery to neuromodulation and palliation: history's lessons for the ethical conduct and regulation of neuropsychiatric research Neurosurgery Clinics of North America 14 303-19 [4] Fins J J 2004 Deep brain stimulation Encyclopedia of Bioethics, Vol 2 3rd edn, ed S G Post (New York: MacMillan Reference) pp 629-34 [5] Fins J J 2004 Neuromodulation, free will and determinism: lessons from the psychosurgery debate Clinical Neuroscience Research 4 113-18 [6] Fins J J 2009 Deep brain stimulation: ethical issues in clinical practice and neurosurgical research Neuromodulation eds E Krames, P H Peckham and A Rezai (London: Elsevier) pp 81-91 [7] Schiff N D, Giacino J T, Kalmar K, Victor J D, Baker K, Gerber M, Fritz B, Eisenberg B, O'Connor J, Kobylarz E J, Farris S, Machado A, McCagg C, Plum F, Fins J J, Rezai A R 2007 Behavioral improvements with thalamic stimulation after severe traumatic brain injury Nature 448 600-3 [8] Schiff N D and Fins J J 2007 Deep brain stimulation and cognition: moving from animal to patient Current Opinion in Neurology 20 638-42 [9] Schiff N D, Giacino J T and Fins J J 2009 Deep brain stimulation, neuroethics and the minimally conscious state: moving beyond proof of principle Arch. Neurology 66 697-702 [10] CMS 160.24 NCD for deep brain stimulation for essential tremor and Parkinson's disease, 1~April~2003 [11] CMS Manual System 100-04 Medicare claims processing, transmittal 128, 26 March 2004 http://www.cms.hhs.gov/Transmittals/Downloads/R128CP.pdf [12] Schwalb J M, Riina H A, Skolnick B, Jaggi J L, Simuni T and Baltuch G H 2001 Revision of deep brain stimulator for tremor: technical note J. Neurosurg. 94 1010-12 [13] Speelman J D and Bosch D A 1998 Resurgence of functional neurosurgery for Parkinson's disease: a historical perspective

Liming and Fertilization Effects on Triticale (XTriticosecale W.) Yield Between 1999 and 2006

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László Phd, M., ,, Dr.

2009-04-01

, pp. 219-232. RS (Royal Society). 2005. Climate change warming over food production. Web address: http://www.newscientist.com Runge, E. C. 1968. Effect of rainfall and temperature interaction during the growing season on corn yield. Agron. J, 60:503-507. Russell, C. M.-Jennifer, A. B. 1991. Climatic Risk in Crop Production: Models and Management for the Semiarid Tropics and Subtropics. C. A. B. International, Wallingford Semenov, M. A. and Porter, J. R. 1995. Climatic variability and modeling of crop yields. Agric. For Meteorol. 73:265-283. Seth, G. P. & Yeffrey, S. A. 2005. Crops and Environmental Change. Food Product Press. New York-London-Oxford Schulze, R. E., Gregory, A. K. and Richard, P. K. 1993. Global climate change and agricultural productivity in southern Africa. Global Environmental Change, Vol. 3, No. 4, December, pp. 330-349 Smith, W. J. 1920. Agricultural meteorology. The effect of weather on crops. Macmillan Comp., New York. Singh, B., Mustapha, E. M., Pierre A., Christopher, R. B. and Jean, P. T. 1998. Impacts of a Ghg-induced climate change on crop yields: Efects of acceleration in maturation, moisture stress and optimal temperature. Climatic change, Vol. 38, No. 1, January, pp. 51-86. SPSS. 2000. SigmaPlot for Windows. Ver. 3.2, Chicago, III.: SPSS, Inc Szász G. 2005. Climatic instability causing variability in crop output in the Carpathian Basin. (In Hungarian) In: „AGRO-21" Füzetek. 40. 33-69. Tubiello, F. N., Rosenzweig, C., Goldberg, R. A. Jagtap, S. and Jones, J. W. 2002. Effects of climate change on U.S. crop production: Simulation results using two different GCM scenarios. Part I: Wheat, potato, maize and citrus. Climate Research, Vol. 20, pp. 259-270. Uprety, D. C. 1999. Global change series. IARI, New Delhi Vesselin, A., Eitzinger, J., Vesna, C. and Michael, O. 2002. Potential impact of climate change on selected agricultural crops in north-eastern Austria. Global Change Biology. 8:372. Várallyay, Gy. 1992. Globális kl