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Sample records for lma ft imf

  1. Troubleshooting ProSeal LMA

    Directory of Open Access Journals (Sweden)

    Bimla Sharma

    2009-01-01

    Full Text Available Supraglottic devices have changed the face of the airway management. These devices have contributed in a big way in airway management especially, in the difficult airway scenario significantly decreasing the pharyngolaryngeal morbidity. There is a plethora of these devices, which has been well matched by their wider acceptance in clinical practice. ProSeal laryngeal mask airway (PLMA is one such frequently used device employed for spontaneous as well as controlled ventilation. However, the use of PLMAat tunes maybe associated with certain problems. Some of the problems related with its use are unique while others are akin to the classic laryngeal mask airway (eLMA. However, expertise is needed for its safe and judicious use, correct placement, recognition and management of its various malpositions and complications. The present article describes the tests employed for proper confirmation of placementto assess the ventilatooy and the drain tube functions of the mask, diagnosis of various malpositions and the management of these aspects. All these areas have been highlighted under the heading of troubleshooting PLMA. Many problems can be solved by proper patient and procedure selection, maintaining adequate depth of anaesthesia, diagnosis and management of malpositions. Proper fixation of the device and monitoring cuff pressure intraopera-tively may bring down the incidence of airway morbidity.

  2. Endotracheal Intubation in Patients with Unstable Cervical Spine Using LMA-Fastrach and Gum Elastic Bogie

    International Nuclear Information System (INIS)

    Khan, M. U.

    2014-01-01

    Objective: To evaluate the success of alternative technique of ET- intubation in patients with unstable cervical spine with Philadelphia collar around the neck. Study Design: Case series. Place and Duration of Study: The Department of Anaesthesia, College of Medicine, King Saud University, Riyadh, Saudi Arabia, from June 2009 to June 2012. Methodology: Adult patients of either gender with unstable cervical spine wearing Philadelphia collar electively scheduled for cervical spine decompression and fixation more than one level were included. Those with anticipated difficult intubation, mouth opening 27 kg/m2 were excluded. After induction of anaesthesia FT-LMA was inserted. Correct position of FT-LMA was confirmed then soft straight end of gum elastic bogie was passed through FTLMA into trachea. FT-ILMA was removed on bogie. Reinforced silicon ET- tube was rail road on bogie. The bogie was pulled out and position of ET- tube was confirmed with ETCO2, chest movement and auscultation on bag ventilation. The ease of insertion of FT-LMA, ET- intubation and maximum time taken for successful intubation was noted. Results: 26 patients were studied with mean age of 59.3 A +- 2.93 years and M: F ratio of 7:3. The mean time taken from the insertion of gum elastic bogie to the ET intubation was 38.9 A +- 1.20 seconds. The success rate of ET- intubation in the first attempt was 88.4% and 7.6% in two attempts. Intubation failed in one patient. The mean ease of insertion of FT-LMA and ET- intubation in all patients was 46.7 A +- 2.59 and 46.5 A +- 2.66 respectively on VAS ( 0-100). No complication was noted in any patient. Conclusion: This technique is safe and reliable for achieving adequate ventilation and intubation in patients with unstable cervical spine with Philadelphia collar in place. (author)

  3. Improving LMA predictions with non standard interactions

    CERN Document Server

    Das, C R

    2010-01-01

    It has been known for some time that the well established LMA solution to the observed solar neutrino deficit fails to predict a flat energy spectrum for SuperKamiokande as opposed to what the data indicates. It also leads to a Chlorine rate which appears to be too high as compared to the data. We investigate the possible solution to these inconsistencies with non standard neutrino interactions, assuming that they come as extra contributions to the $\

  4. Comparisons of GLM and LMA Observations

    Science.gov (United States)

    Thomas, R. J.; Krehbiel, P. R.; Rison, W.; Stanley, M. A.; Attanasio, A.

    2017-12-01

    Observations from 3-dimensional VHF lightning mapping arrays (LMAs) provide a valuable basis for evaluating the spatial accuracy and detection efficiencies of observations from the recently launched, optical-based Geosynchronous Lightning Mapper (GLM). In this presentation, we describe results of comparing the LMA and GLM observations. First, the observations are compared spatially and temporally at the individual event (pixel) level for sets of individual discharges. For LMA networks in Florida, Colorado, and Oklahoma, the GLM observations are well correlated time-wise with LMA observations but are systematically offset by one- to two pixels ( 10 to 15 or 20 km) in a southwesterly direction from the actual lightning activity. The graphical comparisons show a similar location uncertainty depending on the altitude at which the scattered light is emitted from the parent cloud, due to being observed at slant ranges. Detection efficiencies (DEs) can be accurately determined graphically for intervals where individual flashes in a storm are resolved time-wise, and DEs and false alarm rates can be automated using flash sorting algorithms for overall and/or larger storms. This can be done as a function of flash size and duration, and generally shows high detection rates for larger flashes. Preliminary results during the May 1 2017 ER-2 overflight of Colorado storms indicate decreased detection efficiency if the storm is obscured by an overlying cloud layer.

  5. Comparison of LMA-ProSealTM with LMA ClassicTM in Anaesthetised Paralysed Children

    Directory of Open Access Journals (Sweden)

    Pravesh Kanthed

    2008-01-01

    Full Text Available The classic laryngeal mask airway (cLMA, though popular in anaesthesia practice provides low oropharyngeal seal pressure and there are concerns with its use during positive pressure ventilation for fear of gastric distension with subsequent gastric regurgitation and pulmonary aspiration. The ProSeal laryngeal mask airway (PLMA is a modified LMA with a larger, wedge shaped cuff and a drain tube. This modification improves the seal around glottis when compared to a cLMA and its drain tube prevents gastric distension and offers protection against aspiration when properly placed. We compared PLMA and cLMA in 100 anaesthetized, paralysed children with 50 patients in each group with respect to ease of insertion, oropharyngeal seal pressure and pharyngolaryngeal morbidity. Gastric tube insertion was also assessed for the PLMA. The ease of insertion and the number of attempts at insertion were found to be comparable in the two groups while the oropharyngeal seal pressure was significantly higher in the PLMA group (P < 0.001. The pharyngolaryngeal morbidity was comparable in both the groups. There was no incidence of regurgitation or aspiration in either group. The PLMA offered high reliability of gastric tube placement and significantly increased oropharyngeal seal pressure over the cLMA. This might have an important implication for use of this device for positive pressure ventilation in children.

  6. Laryngeal mask airway (LMA) artefact resulting in MRI misdiagnosis

    International Nuclear Information System (INIS)

    Schieble, Thomas; Patel, Anuradha; Davidson, Melissa

    2008-01-01

    We report a 7-year-old child who underwent brain MRI for a known seizure disorder. The technique used for general anesthesia included inhalation induction followed by placement of a laryngeal mask airway (LMA) for airway maintenance. Because the reviewing radiologist was unfamiliar with the use of an LMA during anesthesia, and because the attending anesthesiologist did not communicate his technique to the radiologist, an MRI misdiagnosis was reported because of artefact created by the in situ LMA. As a result of this misdiagnosis the child was subjected to unnecessary subsequent testing to rule out a reported anatomic abnormality induced by the LMA. Our case illustrates the need for coordination of patient care among hospital services. (orig.)

  7. Laryngeal mask airway (LMA) artefact resulting in MRI misdiagnosis

    Energy Technology Data Exchange (ETDEWEB)

    Schieble, Thomas [University of Medicine and Dentistry of New Jersey, Department of Anesthesiology, New Jersey Medical School, Newark, NJ (United States); Maimonides Medical Center, Department of Anesthesiology, Brooklyn, NY (United States); Patel, Anuradha; Davidson, Melissa [University of Medicine and Dentistry of New Jersey, Department of Anesthesiology, New Jersey Medical School, Newark, NJ (United States)

    2008-03-15

    We report a 7-year-old child who underwent brain MRI for a known seizure disorder. The technique used for general anesthesia included inhalation induction followed by placement of a laryngeal mask airway (LMA) for airway maintenance. Because the reviewing radiologist was unfamiliar with the use of an LMA during anesthesia, and because the attending anesthesiologist did not communicate his technique to the radiologist, an MRI misdiagnosis was reported because of artefact created by the in situ LMA. As a result of this misdiagnosis the child was subjected to unnecessary subsequent testing to rule out a reported anatomic abnormality induced by the LMA. Our case illustrates the need for coordination of patient care among hospital services. (orig.)

  8. The Laryngeal Mask Airway (LMA) as an alternative to airway ...

    African Journals Online (AJOL)

    Adele

    patient dental procedures in the MR patient and in individuals ... The parameters assessed during the pilot study included ease of LMA insertion and its seal, inspiratory pressures with ... mouth opposite to that used for the surgical procedure.

  9. IMF and economic reform in developing countries

    DEFF Research Database (Denmark)

    Abbott, Philip; Andersen, Thomas Barnebeck; Tarp, Finn

    2010-01-01

    approach is in order. However, the cross-country approach is unlikely to provide a sound basis for drawing clear conclusions, so we review IMF programs from a different perspective, involving a broader literature on development strategy. In particular, it is widely accepted that a common characteristic......In this paper we assess the IMF approach to economic reform in developing countries. The impact of IMF program participation on economic growth has been evaluated empirically in a cross-country literature, with little evidence of IMF programs having been successful. This suggests that a fresh...... of IMF programs is a high degree of policy rigidity. This is in contrast with studies which hold that unleashing an economy's growth potential hinges on a set of well-targeted policy interventions aimed at removing country-specific binding constraints. The process of locating constraints that bind...

  10. The Laryngeal Mask Airway (LMA) as an alternative to airway ...

    African Journals Online (AJOL)

    Background: To evaluate the possibility of airway management using a laryngeal mask airway (LMA) during dental procedures on mentally retarded (MR) patients and patients with genetic diseases. Design: A prospective pilot study. Setting: University Hospital. Methods: A pilot study was designed to induce general ...

  11. THE END OF IMF - TURKEY RELATIONSHIP

    Directory of Open Access Journals (Sweden)

    ZUNGUN DENIZ

    2013-07-01

    Full Text Available Abstract: IMF has been created to make international cooperation on financial matters stronger and for solving the problems of balance of payment. However, the IMF formed policies in order to solve problems of balance of payment till the 1980s, expanded its effectiveness much more by controlling the structural adjustment programs after the 1980s, and undertook the role as an international lender of last resort on crises caused by globalization trends. In developing nations, foreign and domestic deficit occurred due to infrastructural causes that have created economic instabilities portrayed through inflation and unemployment. Especially foreign debt problems sourced by the foreign trade deficit transformed into an economic crisis for these countries. Many countries affected by such economic crisis applied to IMF and its Stabilization Program with the aim of providing economic stability in the hopes of recovering. The important thing here to point out is that the economic programs used by countries during their economic crisis are supported by the IMF in reality. In this situation Mexico and Argentina can be given as a good example. IMF has undertaken the same mission in Turkey with seven stabilization programs put in practice and nineteen Stand-By Arrangements between them. But IMF has failed many times in Turkey just like in many developing countries. This is because IMF did not take into consideration economic and social structure of countries in stabilization programs put in practice. Today, Turkey has reached to an important point from the way of its relationship with IMF; more clearly, Turkey is determined to achieve its future without IMF. Turkey-IMF relationship in the framework of stand-by agreements in the past half century of our economic and political history has come to an ending point. After a period of 51 years of intense relations, Turkey decided to determine its calculations of credit limit by the way of advantages and

  12. The North Alabama Lightning Mapping Array (LMA): A Network Overview

    Science.gov (United States)

    Blakeslee, R. J.; Bailey, J.; Buechler, D.; Goodman, S. J.; McCaul, E. W., Jr.; Hall, J.

    2005-01-01

    The North Alabama Lightning Mapping Array (LMA) is s a 3-D VHF regional lightning detection system that provides on-orbit algorithm validation and instrument performance assessments for the NASA Lightning Imaging Sensor, as well as information on storm kinematics and updraft evolution that offers the potential to improve severe storm warning lead time by up t o 50% and decrease te false alarm r a t e ( for non-tornado producing storms). In support of this latter function, the LMA serves as a principal component of a severe weather test bed to infuse new science and technology into the short-term forecasting of severe and hazardous weather, principally within nearby National Weather Service forecast offices. The LMA, which became operational i n November 2001, consists of VHF receivers deployed across northern Alabama and a base station located at the National Space Science and Technology Center (NSSTC), which is on t h e campus of the University of Alabama in Huntsville. The LMA system locates the sources of impulsive VHF radio signals s from lightning by accurately measuring the time that the signals aririve at the different receiving stations. Each station's records the magnitude and time of the peak lightning radiation signal in successive 80 ms intervals within a local unused television channel (channel 5, 76-82 MHz in our case ) . Typically hundreds of sources per flash can be reconstructed, which i n t u r n produces accurate 3-dimensional lightning image maps (nominally network topology and the links have an effective data throughput rate ranging from 600 kbits s -1 t o 1.5 %its s -1. This presentation provides an overview of t h e North Alabama network, the data processing (both real-time and post processing) and network statistics.

  13. The Stellar IMF from Isothermal MHD Turbulence

    Science.gov (United States)

    Haugbølle, Troels; Padoan, Paolo; Nordlund, Åke

    2018-02-01

    We address the turbulent fragmentation scenario for the origin of the stellar initial mass function (IMF), using a large set of numerical simulations of randomly driven supersonic MHD turbulence. The turbulent fragmentation model successfully predicts the main features of the observed stellar IMF assuming an isothermal equation of state without any stellar feedback. As a test of the model, we focus on the case of a magnetized isothermal gas, neglecting stellar feedback, while pursuing a large dynamic range in both space and timescales covering the full spectrum of stellar masses from brown dwarfs to massive stars. Our simulations represent a generic 4 pc region within a typical Galactic molecular cloud, with a mass of 3000 M ⊙ and an rms velocity 10 times the isothermal sound speed and 5 times the average Alfvén velocity, in agreement with observations. We achieve a maximum resolution of 50 au and a maximum duration of star formation of 4.0 Myr, forming up to a thousand sink particles whose mass distribution closely matches the observed stellar IMF. A large set of medium-size simulations is used to test the sink particle algorithm, while larger simulations are used to test the numerical convergence of the IMF and the dependence of the IMF turnover on physical parameters predicted by the turbulent fragmentation model. We find a clear trend toward numerical convergence and strong support for the model predictions, including the initial time evolution of the IMF. We conclude that the physics of isothermal MHD turbulence is sufficient to explain the origin of the IMF.

  14. On US politics and IMF lending

    DEFF Research Database (Denmark)

    Andersen, Thomas Barnebeck; Harr, Thomas; Tarp, Finn

    2006-01-01

    The political factors shaping IMF lending to developing countries have attracted attention in recent empirical work. This goes in particular for the role and influence of the US. However, scant formal modelling makes interpretation of empirical results difficult. In this paper, we propose a model...... in which the US acts as principal within the IMF and seeks to maximize its impact on the policy stance of debtor countries. We derive an optimal loan allocation mechanism, which leads to the testable hypothesis that the probability of an IMF loan is increasing in the amount of political concessions...... countries make. A political concession is defined as the distance between a country's bliss point and its actual policy stance measured relative to the US. We introduce a bliss-point proxy and demonstrate that our hypothesis is strongly supported in the data. Moreover, we show that not accounting for bliss...

  15. Solar cycle variations in IMF intensity

    International Nuclear Information System (INIS)

    King, J.H.

    1979-01-01

    Annual averages of logarithms of hourly interplanetary magnetic field (IMF) intensities, obtained from geocentric spacecraft between November 1963 and December 1977, reveal the following solar cycle variation. For 2--3 years at each solar minimum period, the IMF intensity is depressed by 10--15% relative to its mean value realized during a broad 9-year period contered at solar maximum. No systematic variations occur during this 9-year period. The solar minimum decrease, although small in relation to variations in some other solar wind parameters, is both statistically and physically significant

  16. Photonic lantern adaptive spatial mode control in LMA fiber amplifiers.

    Science.gov (United States)

    Montoya, Juan; Aleshire, Chris; Hwang, Christopher; Fontaine, Nicolas K; Velázquez-Benítez, Amado; Martz, Dale H; Fan, T Y; Ripin, Dan

    2016-02-22

    We demonstrate adaptive-spatial mode control (ASMC) in few-moded double-clad large mode area (LMA) fiber amplifiers by using an all-fiber-based photonic lantern. Three single-mode fiber inputs are used to adaptively inject the appropriate superposition of input modes in a multimode gain fiber to achieve the desired mode at the output. By actively adjusting the relative phase of the single-mode inputs, near-unity coherent combination resulting in a single fundamental mode at the output is achieved.

  17. Hoidu IMF-i eest! / Heido Vitsur

    Index Scriptorium Estoniae

    Vitsur, Heido, 1944-

    2000-01-01

    Maailmapangast oma avameelsete avalduste pärast lahkuma sunnitud endine peaökonomist Joseph Stieglitz hoiatas üleminekumaid, et nad ei jälgiks liiga täpselt IMF-i soovitusi, sest need võivad kahjulikud olla

  18. Signals of dynamical and statistical process from IMF-IMF correlation function

    Science.gov (United States)

    Pagano, E. V.; Acosta, L.; Auditore, L.; Baran, V.; Cap, T.; Cardella, G.; Colonna, M.; De Luca, S.; De Filippo, E.; Dell'Aquila, D.; Francalanza, L.; Gnoffo, B.; Lanzalone, G.; Lombardo, I.; Maiolino, C.; Martorana, N. S.; Norella, S.; Pagano, A.; Papa, M.; Piasecki, E.; Pirrone, S.; Politi, G.; Porto, F.; Quattrocchi, L.; Rizzo, F.; Rosato, E.; Russotto, P.; Siwek-Wilczyńska, K.; Trifiro, A.; Trimarchi, M.; Verde, G.; Vigilante, M.; Wilczyńsky, J.

    2017-11-01

    In this paper we briefly discuss about a novel application of the IMF-IMF correlation function to the physical case of binary massive projectile-like (PLF) splitting for dynamical and statistical breakup/fission in heavy ion collisions at Fermi energy. Theoretical simulations are also shown for comparisons with the data. These preliminary results have been obtained for the reverse kinematics reaction 124Sn + 64Ni at 35 AMeV that was studied using the forward part of CHIMERA detector. In that reaction a strong competition between a dynamical and a statistical components and its evolution with the charge asymmetry of the binary break up was already shown. In this work we show that the IMF-IMF correlation function can be used to pin down the timescale of the fragments production in binary fission-like phenomena. We also made simulations with the CoMDII model in order to compare to the experimental IMF-IMF correlation function. In future we plan to extend these studies to different reaction mechanisms and nuclear systems and to compare with different theoretical transport simulations.

  19. Need kolm õudset tähte - IMF / Andrei Hvostov

    Index Scriptorium Estoniae

    Hvostov, Andrei, 1963-

    2008-01-01

    Autor käsitleb lähemalt Rahvusvahelist Valuutafondi (IMF) ja kriitikat fondi tegutsemise kohta. Mitmed IMF-iga kokku puutunud riigid püüavad iga hinna eest võlast vabaneda, samas suunib praegune majanduskriis IMF-i poole pöörduma

  20. Taxonomy and remote sensing of leaf mass per area (LMA) in humid tropical forests

    Science.gov (United States)

    Gregory P. Asner; Roberta E. Martin; Raul Tupayachi; Ruth Emerson; Paola Martinez; Felipe Sinca; George V.N. Powell; S. Joseph Wright; Ariel E. Lugo

    2011-01-01

    Leaf mass per area (LMA) is a trait of central importance to plant physiology and ecosystem function, but LMA patterns in the upper canopies of humid tropical forests have proved elusive due to tall species and high diversity. We collected top-of-canopy leaf samples from 2873 individuals in 57 sites spread across the Neotropics, Australasia, and Caribbean and Pacific...

  1. IMF and Economic Reform in Developing Countries

    DEFF Research Database (Denmark)

    Abbott, Philip; Andersen, Thomas Barnebeck; Tarp, Finn

    2010-01-01

    relevant to actors and entities with a broader, and more microeconomic, focus such as national policymakers and the World Bank. It is in choices among competing projects and programs that trial and error is most likely to be necessary. Nevertheless, reforms of the IMF such as the “streamlining initiative......” should start from a good understanding of the reasons for adherence to policy orthodoxy. We discuss underlying institutional and organizational reasons for policy rigidity and consider some suggested reforms....

  2. Overcome IMF crisis with idea and invention

    International Nuclear Information System (INIS)

    Wang, Yeon Jung

    1998-01-01

    This book introduces the invention as a tool to overcome IMF crisis. These are the titles of the way to create invention and idea : what is idea? everyone can create something, have a confidence, this is patent, replace or change something, invention is not logical, challenge the normal law, throw away stereotype, movement of idea, original imagination, there are a lot of solutions, there is no expert, have a positive thought, why does inventor invent? necessity is invention of mother, three stage of idea and invention and imitation for invention.

  3. Overcome IMF crisis with idea and invention

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Yeon Jung

    1998-01-15

    This book introduces the invention as a tool to overcome IMF crisis. These are the titles of the way to create invention and idea : what is idea? everyone can create something, have a confidence, this is patent, replace or change something, invention is not logical, challenge the normal law, throw away stereotype, movement of idea, original imagination, there are a lot of solutions, there is no expert, have a positive thought, why does inventor invent? necessity is invention of mother, three stage of idea and invention and imitation for invention.

  4. Effects of the IMF on the plasma sheet

    International Nuclear Information System (INIS)

    Akasofu, S.-I.; Meng, C.-I.

    1986-01-01

    It is suggested that the IMF Bsub(z) component controls partially the geometry of the cross-section (y-z plane) of the plasma sheet. Our vacuum superposition model suggests that the cross-section has a dumbbell shape for te IMF Bsub(z) O. It is also suggested that the thinning and subsequent expansion of the plasma sheet during magnetospheric substorms are partially due to a direct effect of the IMF Bsub(z). (author)

  5. Geomagnetic Dst index forecast based on IMF data only

    Directory of Open Access Journals (Sweden)

    G. Pallocchia

    2006-05-01

    Full Text Available In the past years several operational Dst forecasting algorithms, based on both IMF and solar wind plasma parameters, have been developed and used. We describe an Artificial Neural Network (ANN algorithm which calculates the Dst index on the basis of IMF data only and discuss its performance for several individual storms. Moreover, we briefly comment on the physical grounds which allow the Dst forecasting based on IMF only.

  6. Transformation of analcime into IMF structure during the synthesis of IMF zeolite

    Czech Academy of Sciences Publication Activity Database

    Kubů, Martin; Přech, Jan

    2015-01-01

    Roč. 206, APR 2015 (2015), s. 121-126 ISSN 1387-1811 R&D Projects: GA ČR GP13-17593P Institutional support: RVO:61388955 Keywords : IMF zeolite * analcime * crystallization Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 3.349, year: 2015

  7. Transformation of analcime into IMF structure during the synthesis of IMF zeolite

    Czech Academy of Sciences Publication Activity Database

    Kubů, Martin; Přech, Jan

    2015-01-01

    Roč. 206, C (2015), s. 121-126 ISSN 1387-1811 R&D Projects: GA ČR GP13-17593P Institutional support: RVO:61388955 Keywords : Analcime * Crystallization * IMF zeolite Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 3.349, year: 2015

  8. Enough room for Williams and IMF? / Paul Beckman

    Index Scriptorium Estoniae

    Beckman, Paul

    1999-01-01

    Lõppesid Leedu ja USA energeetikakompanii Williams International läbirääkimised Leedu naftakompleksis osaluse omandamise asjus. IMF uurib Leedu majanduslikku arengut, mida tehing Williamsiga komplitseerib

  9. A COMPARISON OF CLINICAL PERFORMANCE OF I-GEL WITH PROSEAL LMA IN PATIENTS UNDERGOING MASTECTOMY

    Directory of Open Access Journals (Sweden)

    Basheer Padinhare Madathil

    2016-04-01

    Full Text Available AIM To assess the ease of insertion of I-gel and ProSeal LMA and incidence of post op complications. Study design-A prospective randomised controlled trial comparing the clinical performance of I-gel and ProSeal LMA. METHODS After induction and good muscle relaxation LMA/I-gel was introduced as per randomised computer allocation. After insertion, nasogastric tube was inserted through the gastric channel. Parameters monitored were heart rate, nubp, SpO2, ETCO2 at 1, 5 minutes after insertion of the device and thereafter every 5 minutes till the end of surgery. In case of failure, airway was secured with an endotracheal tube. Ease of gastric tube insertion was noted at the end of surgery; postop complications were noted. Blood staining of the device, injury to the lips, teeth, and tongue were noted. Incidence of sore throat 24 hrs. after surgery was also noted. Statistical analysis was done with SPSS software. RESULTS Age, height, weight and BMI were comparable in both groups. The airway characteristics was also comparable in both the groups. Ease of introduction was also the same for both the groups, but the time taken was much lesser for I-gel group. The ease of insertion of gastric tube was much easier for the I-gel group. Blood staining of the device was more with the ProSeal LMA group. There was no injury to any of the structures mentioned above. Postop sore throat was more in the ProSeal LMA group. CONCLUSION From our study, we conclude that the airway can be secured much faster with I-gel than ProSeal LMA. Postop sore throat was much less for I-gel than ProSeal LMA. Both were comparable in number of attempts of insertion, gastric tube introduction. Trauma to the airway structures was also minimum with both I-gel and ProSeal LMA.

  10. Effects of IMF programs on school enrollment in developing countries

    NARCIS (Netherlands)

    Vranken, M.; Smits, J.P.J.M.; Jong, E. de

    2011-01-01

    The IMF is one of the most heavily criticized international financial institutions in the world and has been accused of having a negative effect on education. By using multi-level analyses, this paper estimates the effects of IMF supported programs on the growth in school enrollment in developing

  11. IMF toetab Eesti maksureformi / Andris Feldmanis, Kertu Ruus

    Index Scriptorium Estoniae

    Feldmanis, Andris, 1982-

    2004-01-01

    Rahvusvahelise Valuutafondi (IMF) Eesti missiooni juht Richard Haas tutvustab äsjailmunud IMF-i raportis esitatud hinnangut Eesti majanduse hetkeseisu kohta ja võimalikke järgneva 15 aasta makroohtusid, sh jooksevkonto puudujääki ja laenamise kiiret kasvu. Rahandusminister Taavi Veskimägi ja Eesti Panga presidendi Vahur Krafti kommentaarid. Diagramm: Eesti laenukoormuse kasv kiireim

  12. IMF gives an 'A' for effort / Ella Karapetyan

    Index Scriptorium Estoniae

    Karapetyan, Ella

    2010-01-01

    23.-29. märtsini külastas Eestit Rahvusvahelise Valuutafondi (IMF) delegatsioon. Delegatsiooni juhi Christoph Rosenbergi sõnul on IMF igati rahul Eesti eelarvepoliitikaga. Christoph Rosenbergi soovitused. Delegatsioon kohtus ka president Toomas Hendrik Ilvese ja peaminister Andrus Ansipiga

  13. The Asian Crisis, the IMF and Dr. Mahathir

    NARCIS (Netherlands)

    Visser, H.; ter Wengel, J.

    1999-01-01

    While in the literature concerning the Asian crisis extensive coverage has been given to the course of events in the countries implementing IMF-supported programmes, scant attention has been paid to other countries that also suffered from the crisis. Potential alternatives to the IMF way of handling

  14. Field-aligned currents during northward IMF: Morphology and causes

    DEFF Research Database (Denmark)

    Vennerstrøm, Susanne; Moretto, T.; Rastätter, L.

    2005-01-01

    We present the results of a global MHD simulation of solar wind magnetosphere interaction during northward IMF. In particular, we emphasize the effect of the IMF B y component on the reconnection geometry and the mapping along field lines to the polar ionosphere, through field-aligned currents. We...... find that the existence and geometry of the polar cap is closely connected to the IMF B y component. During strictly northward IMF the simulated magnetosphere can remain essentially closed because the solar wind field lines reconnect in both hemispheres, thereby creating newly reconnected closed...... exist both on open and closed field lines and are created by the shear of the newly reconnected field lines against the mantle field as they are convected tailward by the solar wind. When the IMF rotates from northward toward east, the magnetospheric mapping regions of the NBZ currents likewise rotates...

  15. Influence of the IMF azimuthal component on magnetospheric substorm dynamics

    International Nuclear Information System (INIS)

    Troshichev, O.A.; Kotikov, A.L.; Bolotinskaya, B.D.; Andrezen, V.G.

    1986-01-01

    The effect of the IMF azimuthal component on magnetospheric substorm dynamics has been studied on the basis of five-minute average values of the IMF B y and B z components and the AL index. The results obtained from case studies and from superposed epoch analysis show the dependence of substorm dynamics on the azimuthal component: the reversal of B y from positive to negative increases the activity with minimum delay time, while the opposite reversal either does not change or only slightly changes the activity level. This effect is more evident in winter. The reversal of the IMF vertical component from south to north after an interval of sustained southward IMF statistically gives rise to magnetic activity, too but this growth is less intense than that produced by the B y negative turning. The role of both vertical and azimuthal IMF components must be considered in future studies of substorm triggering mechanisms. (author)

  16. A Critical Evaluation of IMF History and Policies

    Directory of Open Access Journals (Sweden)

    Syed Ahmed

    2018-01-01

    Full Text Available The International Monetary Fund (IMF was originally mandated to maintain exchange rate stability and adjustment of external imbalances in member countries and to act as a lender for countries facing short-term balance-of-payment crises. With the breakdown of the fixed exchange rate system, the IMF had to adjust its role in exchange rate management. The international banking crisis in the 1980s required a recalibration of IMF policies. Most of the policies in the 1980s and 1990s were driven by “Washington Consensus,” a doctrinaire view of economic development that called for structural adjustment through market liberalization and privatizations. However, critics indicate that the IMF, by failing to consider the unique conditions in developing economies and lumping them under a “one size fits all,” category may have caused more damage than good. In addition, it was alleged that IMF loans imposed unrealistic conditions on borrowers. All these policies are under review now in a quest for appropriate policies that will address some of these concerns and aid economic development. This paper provides a brief review of IMF policies from a historical perspective and a critique of IMF policies over the last few decades.

  17. Reforming the IMF: some organizational and operational issues

    Directory of Open Access Journals (Sweden)

    H. ASKARI

    1999-12-01

    Full Text Available While financial crises during the 1990s have started a lively debate on IMF policies toward member countries, reform of the Fund's organisational structure and operations have been largely ignored. Improved organisation and operations would increase IMF efficiency and membership participation, which would in turn increase IMF effectiveness in enhancing global economic conditions. In this paper, a number of such issues--quotas, voting structure and decision making; executive board and ministerial committees; management structure and staff; political dimensions, transparency andcredibility--are assessed.

  18. EXPANDED ROLE OF LMA IN MINOR OBSTETRIC PROCEDURE: A PROSPECTIVE STUDY

    Directory of Open Access Journals (Sweden)

    Kousalya

    2015-05-01

    Full Text Available INTRODUCTION : The Laryngeal Mask Airway (LMA has been used extensively to provide a safe airway in spontaneously breathing patients who are not at risk from aspiration of gastric contents. The increased risk of aspiration in Obstetric population was initially considered as a relative contra indication for LMA usage. But LMA proved to be safe in this subgroup and in fact significantly decreased tidal volume was noted during IPPV with a decre ased the risk of aspiration. METHOD : This is a prospective study , performed in Niloufer Hospital for Children & Women from June 2011 – January 2014 over a period of 30months. We studied the ease of insertion of single use ILMA and associated complications in 35 ASA 1 obstetric patients. RESULTS : The mean age of the patients was 27.4 years. The mean BMI was 28.4 kg /m 2 . 21 patients were admitted for cerclage (60.0% , 5 Bartholin’s abscess (14.28% , 6 cases of manual removal of placenta (17.14% , 3 cases of vescicular mole for evacuation (8.57%. The duration of anesthesia ranged from 20 - 40 min with a mean duration of 19 minutes. The first time insertion rate was 88.57% , 31 out of 35 patients had the LMA inserted in first attempt. 4 patients needed reinsertio n. None of the patients had aspiration or other complications associated with LMA. There were no failed insertions. CONCLUSION : We conclude that the LMA is effective and safe for in carefully selected ASA 1 pregnant patients in the hands of experienced Ane sthesiologist.

  19. The Consequences of IMF Conditionality for Government Expenditure on Health

    Directory of Open Access Journals (Sweden)

    Nisreen Moosa

    2018-01-01

    Full Text Available The International Monetary Fund (IMF was established in 1944 to supervise the international monetary system that collapsed in 1971. Since then, the Fund has reinvented itself as some sort of a “development agency,” providing loans with strings attached. Any country that wishes to obtain loans must follow the IMF-prescribed policies that reflect the neoliberal ideas of the Washington Consensus. As these policies are typically contractionary and involve austerity, the IMF has been accused of pursuing policies that exhibit a negative impact on health expenditure, with dire consequences for the population. Although the empirical evidence on this issue is mixed, it is well known that the IMF operations are more likely to exert a negative effect than a positive effect on government spending on health.

  20. Lithuania manages to steer clear of IMF loans

    Index Scriptorium Estoniae

    2009-01-01

    Leedu peaministri Andrius Kubiliuse sõnul saab Leedu finantssüsteem rahvusvahelistel finantsturgudel kindlust juurde, mis tähendab, et riik võib hakkama saada ilma IMF-i abita. Peaminister eelarvepoliitikast

  1. Miks IMF ei kiirusta riike rahanduskriisist päästma? / Heiki Suurkask

    Index Scriptorium Estoniae

    Suurkask, Heiki, 1972-

    2008-01-01

    Mitu riiki taotleb IMF-ilt kriisiabi, IMF esitab neile abi andmiseks rangeid nõudeid. Varasemates kriisides on IMF-i rahast piisanud, kuid suuremaid tööstusriike ta välja aidata ei suudaks, selle juhi Dominique Strauss-Kahni prognoosi kohaselt peab IMF seekord välja andma sadu miljardeid dollareid. Lisa: Pangajuhti tabas seksiskandaal

  2. Eesti ja Venemaa uue külma sõja õhutamise avangardis / Herbert Vainu

    Index Scriptorium Estoniae

    Vainu, Herbert, 1929-2011

    2008-01-01

    Eesti ja Venemaa juhtide mängimine rahvustundel tõstab rahvusvahelist pinget, mis võib viia külma sõja taastekkimisele. Autor kritiseerib muuhulgas president Toomas Hendrik Ilvese poliitilist tegevust ja esinemist Hantõ-Manskiiskis toimunud soome-ugri maailmakongressil. Vabariigi President töövisiidil Venemaal 27.-30.06.2008

  3. Fusion technology (FT)

    International Nuclear Information System (INIS)

    1978-01-01

    The annual report of tha fusion technology (FT) working group discusses the projects carried out by the participating institutes in the fields of 1) fuel injection and plasma heating, 2) magnetic field technology, and 3) systems investigations. (HK) [de

  4. High-Latitude Ionospheric Dynamics During Conditions of Northward IMF

    Science.gov (United States)

    Sharber, J. R.

    1996-01-01

    In order to better understand the physical processes operating during conditions of northward interplanetary magnetic field (IMF), in situ measurements from the Dynamics Explorer-2 (low altitude) polar satellite and simultaneous observations from the auroral imager on the Dynamics Explorer-1 (high altitude) satellite were used to investigate the relationships between optical emissions, particle precipitation, and convective flows in the high-latitude ionosphere. Field aligned current and convective flow patterns during IMF north include polar cap arcs, the theta aurora or transpolar arc, and the 'horse-collar' aurora. The initial part of the study concentrated on the electrodynamics of auroral features in the horse-collar aurora, a contracted but thickened emission region in which the dawn and dusk portions can spread to very high latitudes, while the latter part focused on the evolution of one type of IMF north auroral pattern to another, specifically the quiet-time horse-collar pattern to a theta aurora.

  5. Negative pressure pulmonary oedema following use of ProSeal LMA

    Directory of Open Access Journals (Sweden)

    Richa Jain

    2013-01-01

    Full Text Available Negative pressure pulmonary oedema (NPPO is a life threatening condition, manifested due to upper airway obstruction in a spontaneously breathing patient. Upper airway obstruction caused by classic laryngeal mask airway (cLMA and ProSeal laryngeal mask airway (PLMA has been reported, and NPPO has also been reported following the use of cLMA. Search of literature did not confirm NPPO following the use of PLMA. We encountered a female patient of NPPO scheduled for incision and drainage of an abscess who had signs of airway obstruction following PLMA insertion. Multiple attempts were made to get patent airway without success. PLMA was replaced with endotracheal tube following which pink frothy secretion appeared in breathing circuit. Patient was managed successfully with ICU care.

  6. Sao Paulo Lightning Mapping Array (SP-LMA): Deployment, Operation and Initial Data Analysis

    Science.gov (United States)

    Blakeslee, R.; Bailey, J. C.; Carey, L. D.; Rudlosky, S.; Goodman, S. J.; Albrecht, R.; Morales, C. A.; Anseimo, E. M.; Pinto, O.

    2012-01-01

    An 8-10 station Lightning Mapping Array (LMA) network is being deployed in the vicinity of Sao Paulo to create the SP-LMA for total lightning measurements in association with the international CHUVA [Cloud processes of the main precipitation systems in Brazil: A contribution to cloud resolving modeling and to the GPM (Global Precipitation Measurement)] field campaign. Besides supporting CHUVA science/mission objectives and the Sao Luiz do Paraitinga intensive operation period (IOP) in November-December 2011, the SP-LMA will support the generation of unique proxy data for the Geostationary Lightning Mapper (GLM) and Advanced Baseline Imager (ABI), both sensors on the NOAA Geostationary Operational Environmental Satellite-R (GOES-R), presently under development and scheduled for a 2015 launch. The proxy data will be used to develop and validate operational algorithms so that they will be ready for use on "day1" following the launch of GOES-R. A preliminary survey of potential sites in the vicinity of Sao Paulo was conducted in December 2009 and January 2010, followed up by a detailed survey in July 2010, with initial network deployment scheduled for October 2010. However, due to a delay in the Sao Luiz do Paraitinga IOP, the SP-LMA will now be installed in July 2011 and operated for one year. Spacing between stations is on the order of 15-30 km, with the network "diameter" being on the order of 30-40 km, which provides good 3-D lightning mapping 150 km from the network center. Optionally, 1-3 additional stations may be deployed in the vicinity of Sao Jos dos Campos.

  7. Sao Paulo Lightning Mapping Array (SP-LMA): Deployment and Plans

    Science.gov (United States)

    Bailey, J. C.; Carey, L. D.; Blakeslee, R. J.; Albrecht, R.; Morales, C. A.; Pinto, O., Jr.

    2011-01-01

    An 8-10 station Lightning Mapping Array (LMA) network is being deployed in the vicinity of Sao Paulo to create the SP-LMA for total lightning measurements in association with the international CHUVA [Cloud processes of tHe main precipitation systems in Brazil: A contribUtion to cloud resolVing modeling and to the GPM (GlobAl Precipitation Measurement)] field campaign. Besides supporting CHUVA science/mission objectives and the Sao Luz Paraitinga intensive operation period (IOP) in December 2011-January 2012, the SP-LMA will support the generation of unique proxy data for the Geostationary Lightning Mapper (GLM) and Advanced Baseline Imager (ABI), both sensors on the NOAA Geostationary Operational Environmental Satellite-R (GOES-R), presently under development and scheduled for a 2015 launch. The proxy data will be used to develop and validate operational algorithms so that they will be ready for use on "day1" following the launch of GOES-R. A preliminary survey of potential sites in the vicinity of Sao Paulo was conducted in December 2009 and January 2010, followed up by a detailed survey in July 2010, with initial network deployment scheduled for October 2010. However, due to a delay in the Sa Luz Paraitinga IOP, the SP-LMA will now be installed in July 2011 and operated for one year. Spacing between stations is on the order of 15-30 km, with the network "diameter" being on the order of 30-40 km, which provides good 3-D lightning mapping 150 km from the network center. Optionally, 1-3 additional stations may be deployed in the vicinity of Sa Jos dos Campos.

  8. Improving LMA predictions with non-standard interactions: neutrino decay in solar matter?

    CERN Document Server

    Das, C R

    2010-01-01

    It has been known for some time that the well established LMA solution to the observed solar neutrino deficit fails to predict a flat energy spectrum for SuperKamiokande as opposed to what the data indicates. It also leads to a Chlorine rate which appears to be too high as compared to the data. We investigate the possible solution to these inconsistencies with non standard neutrino interactions, assuming that they come as extra contributions to the $\

  9. Polar ionospheric responses to solar wind IMF changes

    Directory of Open Access Journals (Sweden)

    Y. Zhang

    2000-06-01

    Full Text Available Auroral and airglow emissions over Eureka (89° CGM during the 1997-98 winter show striking variations in relation to solar wind IMF changes. The period January 19 to 22, 1998, was chosen for detailed study, as the IMF was particularly strong and variable. During most of the period, Bz was northward and polar arcs were observed. Several overpasses by DMSP satellites during the four day period provided a clear picture of the particle precipitation producing the polar arcs. The spectral character of these events indicated excitation by electrons of average energy 300 to 500 eV. Only occasionally were electrons of average energy up to ~1 keV observed and these appeared transitory from the ground optical data. It is noted that polar arcs appear after sudden changes in IMF By, suggesting IMF control over arc initiation. When By is positive there is arc motion from dawn to dusk, while By is negative the motion is consistently dusk to dawn. F-region (anti-sunward convections were monitored through the period from 630.0 nm emissions. The convection speed was low (100-150 m/s when Bz was northward but increased to 500 m/s after Bz turned southward on January 20.Key words: Atmospheric composition and structure (airglow and aurora - Ionosphere (particle precipitation - Magnetospheric Physics (polar cap phenomena

  10. IMF on jäänud usalduskriisi / Harold James

    Index Scriptorium Estoniae

    James, Harold

    2008-01-01

    Rahvusvaheline Valuutafond (IMF) peab enda ees seisvate uute ülesannete täitmiseks taastama oma liikmete usalduse. Ta võiks olla võimas finantsalane stabiliseerija, kui saaks hakkama uute ülejäägiga riikide reservvaraga. Äripäevas art. lüh.

  11. IMF BY dependence of the extent of substorm westward electrojet

    Indian Academy of Sciences (India)

    Auroral ground magnetogram signatures near .... The bottom panel shows the. Sym-H ... coordinate system for the event depicted in figure 1(a). ... ring current build-up at the substorm onset sug- ... tem with the polarity of IMF BY was first shown.

  12. Multilateral organizations and global inequality: A focus on IMF ...

    African Journals Online (AJOL)

    The paper examines issues relating to multilateral organizations, taking a particular look at the three multilateral organizations viz IMF, World Bank and WTO. It establishes that institutional and structural variables in the multilateral organizations are skewed in favour of the developed countries and this tends to entrench their ...

  13. Observations of the cusp region under northward IMF

    Directory of Open Access Journals (Sweden)

    F. Pitout

    2001-09-01

    Full Text Available We present a comparative study of the cusp region using the EISCAT Svalbard Radars (ESR and the Cluster spacecraft. We focus in this paper on 2 February 2001, over the time period from 07:30 UT to 12:00 UT when the oblique ESR antenna pointing northward at a low elevation recorded latitudinal motions of the cusp region in response to the IMF. Meanwhile, the Cluster satellites were flying over the EISCAT Svalbard Radar field-of-view around local magnetic noon. The spacecraft first flew near ESR, northeast of Svalbard and then passed over the field-of-view of the antenna at about 11:30 UT. From 08:00 UT to 09:00 UT, the IMF remains primarily southward yet several variations in the Z-component are seen to move the cusp. Around 09:00 UT, an abrupt northward turning of the IMF moves the cusp region to higher latitudes. As a result, the Cluster satellites ended up in the northernmost boundary of the high-altitude cusp region where the CIS instrument recorded highly structured plasma due to ion injections in the lobe of the magnetosphere. After 09:00 UT, the IMF remains northward for more than two hours. Over this period, the ESR records sunward plasma flow in the cusp region due to lobe reconnection, while Cluster spacecraft remain in the high-altitude cusp.Key words. Magnetospheric physics (magnetopause, cusp, and boundary layers; plasma convection Ionosphere (polar ionosphere

  14. Photographic and LMA observations of a blue starter over a New Mexico thunderstorm

    Science.gov (United States)

    Edens, H. E.; Krehbiel, P. R.; Rison, W.; Hunyady, S. J.

    2010-12-01

    On the evening of August 3, 2010 we photographed a blue starter over an electrically active storm complex about 120 km to the WNW of Langmuir Laboratory in central New Mexico. The event occurred close to a broad overshooting top at an altitude of 15 km above MSL. It was also observed visually and detected by the Lightning Mapping Array (LMA) deployed around the mountaintop observatory. The blue starter appears as a white-blue leader channel propagating away from the storm top not straight upward but at a large angle from vertical, slightly curving upward and transitioning to an increasingly diffuse blue glow. In addition to this leader, a more diffuse glow of blue light from one or two additional leaders is seen in the background. The curved channel of the main leader and the fact that it did not propagate along a straight path upward indicates that a relatively strong local electric field near the storm top existed that dictated leader propagation and direction rather than the large-scale storm electric field. The visible part of the starter is estimated to have developed to about 1 km above the storm top. From the LMA data we infer that the blue starter was a screening layer discharge that initiated between upper positive charge and a negatively charged screening layer. A negative leader appears to initiate at 15 km altitude and propagates downward for 2 to 3 km, after which scattered and ill-defined activity occurred in the cloud between 10 to 15 km altitude. This indicates that the visible part of the blue starter emanating out of the storm top, which was photographed but not detected by the LMA, was positive breakdown. The event lasted for 100 ms in the LMA data. The storm where the starter occurred in was producing predominantly intracloud (IC) flashes at a rate of about 20 per minute. The starter itself occurred independently of other discharges in the storm about 4 seconds after a normal polarity IC flash. About 5 minutes after the first blue starter, a

  15. Polar ionospheric responses to solar wind IMF changes

    Directory of Open Access Journals (Sweden)

    Y. Zhang

    Full Text Available Auroral and airglow emissions over Eureka (89° CGM during the 1997-98 winter show striking variations in relation to solar wind IMF changes. The period January 19 to 22, 1998, was chosen for detailed study, as the IMF was particularly strong and variable. During most of the period, Bz was northward and polar arcs were observed. Several overpasses by DMSP satellites during the four day period provided a clear picture of the particle precipitation producing the polar arcs. The spectral character of these events indicated excitation by electrons of average energy 300 to 500 eV. Only occasionally were electrons of average energy up to ~1 keV observed and these appeared transitory from the ground optical data. It is noted that polar arcs appear after sudden changes in IMF By, suggesting IMF control over arc initiation. When By is positive there is arc motion from dawn to dusk, while By is negative the motion is consistently dusk to dawn. F-region (anti-sunward convections were monitored through the period from 630.0 nm emissions. The convection speed was low (100-150 m/s when Bz was northward but increased to 500 m/s after Bz turned southward on January 20.

    Key words: Atmospheric composition and structure (airglow and aurora - Ionosphere (particle precipitation - Magnetospheric Physics (polar cap phenomena

  16. Negative Pressure Pulmonary Edema Following use of Laryngeal Mask Airway (LMA

    Directory of Open Access Journals (Sweden)

    Yesim Bayraktar

    2013-06-01

    Full Text Available Negative pressure pulmonary edema (NPPE following upper airway obstruction is a non-cardiogenic pulmonary edema. The first cause in the etiology of NPPE is developed laryngospasm after intubation or extubation, while the other causes are epiglotitis, croup, hiccups, foreign body aspiration, pharyngeal hematoma and oropharyngeal tumors.The Late diagnosis and treatment causes high morbidity and mortality. The protection of the airway and maintainance of arterial oxygenation will be life saving.In this article we aimed to report  a case of negative pressure pulmonary edema, resolved succesfully after treatment, following use of laryngeal mask airway (LMA.

  17. Implications of Galaxy Buildup for Putative IMF Variations in Massive Galaxies

    Science.gov (United States)

    Blancato, Kirsten; Genel, Shy; Bryan, Greg

    2017-08-01

    Recent observational evidence for initial mass function (IMF) variations in massive quiescent galaxies at z = 0 challenges the long-established paradigm of a universal IMF. While a few theoretical models relate the IMF to birth cloud conditions, the physical driver underlying these putative IMF variations is still largely unclear. Here we use post-processing analysis of the Illustris cosmological hydrodynamical simulation to investigate possible physical origins of IMF variability with galactic properties. We do so by tagging stellar particles in the simulation (each representing a stellar population of ≈ {10}6 {M}⊙ ) with individual IMFs that depend on various physical conditions, such as velocity dispersion, metallicity, or star formation rate, at the time and place in which the stars are formed. We then follow the assembly of these populations throughout cosmic time and reconstruct the overall IMF of each z = 0 galaxy from the many distinct IMFs it is composed of. Our main result is that applying the observed relations between IMF and galactic properties to the conditions at the star formation sites does not result in strong enough IMF variations between z = 0 galaxies. Steeper physical IMF relations are required for reproducing the observed IMF trends, and some stellar populations must form with more extreme IMFs than those observed. The origin of this result is the hierarchical nature of massive galaxy assembly, and it has implications for the reliability of the strong observed trends, for the ability of cosmological simulations to capture certain physical conditions in galaxies, and for theories of star formation aiming to explain the physical origin of a variable IMF.

  18. Linear relations between leaf mass per area (LMA) and seasonal climate discovered through Linear Manifold Clustering (LMC)

    Science.gov (United States)

    Kiang, N. Y.; Haralick, R. M.; Diky, A.; Kattge, J.; Su, X.

    2016-12-01

    Leaf mass per area (LMA) is a critical variable in plant carbon allocation, correlates with leaf activity traits (photosynthetic activity, respiration), and is a controller of litterfall mass and hence carbon substrate for soil biogeochemistry. Recent advances in understanding the leaf economics spectrum (LES) show that LMA has a strong correlation with leaf life span, a trait that reflects ecological strategy, whereas physiological traits that control leaf activity scale with each other when mass-normalized (Osnas et al., 2013). These functional relations help reduce the number of independent variables in quantifying leaf traits. However, LMA is an independent variable that remains a challenge to specify in dynamic global vegetation models (DGVMs), when vegetation types are classified into a limited number of plant functional types (PFTs) without clear mechanistic drivers for LMA. LMA can range orders of magnitude across plant species, as well as vary within a single plant, both vertically and seasonally. As climate relations in combination with alternative ecological strategies have yet to be well identified for LMA, we have assembled 22,000 records of LMA spanning 0.004 - 33 mg/m2 from the numerous contributors to the TRY database (Kattge et al., 2011), with observations distributed over several climate zones and plant functional categories (growth form, leaf type, phenology). We present linear relations between LMA and climate variables, including seasonal temperature, precipitation, and radiation, as derived through Linear Manifold Clustering (LMC). LMC is a stochastic search technique for identifying linear dependencies between variables in high dimensional space. We identify a set of parsimonious classes of LMA-climate groups based on a metric of minimum description to identify structure in the data set, akin to data compression. The relations in each group are compared to Köppen-Geiger climate classes, with some groups revealing continuous linear relations

  19. Rahahädas riigid teevad IMF-i kukru kiirelt tühjaks / Heiki Suurkask

    Index Scriptorium Estoniae

    Suurkask, Heiki, 1972-

    2008-01-01

    Finantskrahhi tõttu raskustesse sattunud riigid taotlevad IMF-ilt laenu, esimesed kuus riiki taotlevad kokku summat, mis küünib veerandini IMF-i reservidest. Briti peaministri Gordon Browni teatel ei piisa IMF-i kriisivarudest globaalsete tagasilöökide ärahoidmiseks. Lisa: IMF peab raha juurde küsima

  20. The future of the IMF: A Latin American Perspective

    Directory of Open Access Journals (Sweden)

    Maritza Cabezas

    2008-04-01

    Full Text Available The accelerating trend of globalization of the  world economy is putting high demands on global  institutions. The IMF has been looking for new  legitimacy in a world where countries traditionally seeking IMF support have become more financially independent. Latin America, a frequent user  of IMF lending facilities, has also entered a new  phase of economic autonomy with the IMF. This  has not come unnoticed since Latin America has  traditionally accounted for more than 40 per cent  of total IMF credit. This article brings up lessons  from Latin America’s long-term experience with  the IMF. It tries to assess whether the Institution  is still relevant for the region, and, if so, whether a  ‘mild’ reform is sufficient for the IMF or a more  radical reform is necessary to meet the challenges  faced by Latin American countries in a fast changing global economy. Resumen: El futuro del Fondo  Monetario Internacional: Una perspectiva latinoamericanaLa acelerada tendencia hacia la globalización de  la economía mundial está planteando enormes  demandas a las instituciones globales. El FMI ha  estado buscando una nueva legitimidad en un  mundo donde los países que solicitaban tradicionalmente el respaldo del FMI son cada vez más  independientes económicamente. América Latina,  un usuario frecuente de las facilidades crediticias  del FMI, también ha entrado en una nueva fase de  autonomía financiera con respecto al FMI. Esto  no ha pasado desapercibido, ya que América  Latina da cuenta tradicionalmente de más del 40  por ciento del total de los créditos del FMI. Este  artículo trata las lecciones de la larga experiencia  de América Latina con el FMI. Trata de determinar si la institución es todavía relevante para la  región y, en caso de ser así, si una reforma ‘moderada’ sería suficiente para el FMI o si se necesita  una reforma más radical para responder a los  desafíos que enfrentan los pa

  1. Resonantly cladding-pumped Yb-free Er-doped LMA fiber laser with record high power and efficiency.

    Science.gov (United States)

    Zhang, Jun; Fromzel, Viktor; Dubinskii, Mark

    2011-03-14

    We report the results of our power scaling experiments with resonantly cladding-pumped Er-doped eye-safe large mode area (LMA) fiber laser. While using commercial off-the-shelf LMA fiber we achieved over 88 W of continuous-wave (CW) single transverse mode power at ~1590 nm while pumping at 1532.5 nm. Maximum observed optical-to-optical efficiency was 69%. This result presents, to the best of our knowledge, the highest power reported from resonantly-pumped Yb-free Er-doped LMA fiber laser, as well as the highest efficiency ever reported for any cladding-pumped Er-doped laser, either Yb-co-doped or Yb-free.

  2. Amphiphilic HPMA-LMA copolymers increase the transport of Rhodamine 123 across a BBB model without harming its barrier integrity.

    Science.gov (United States)

    Hemmelmann, Mirjam; Metz, Verena V; Koynov, Kaloian; Blank, Kerstin; Postina, Rolf; Zentel, Rudolf

    2012-10-28

    The successful non-invasive treatment of diseases associated with the central nervous system (CNS) is generally limited by poor brain permeability of various developed drugs. The blood-brain barrier (BBB) prevents the passage of therapeutics to their site of action. Polymeric drug delivery systems are promising solutions to effectively transport drugs into the brain. We recently showed that amphiphilic random copolymers based on the hydrophilic p(N-(2-hydroxypropyl)-methacrylamide), pHPMA, possessing randomly distributed hydrophobic p(laurylmethacrylate), pLMA, are able to mediate delivery of domperidone into the brain of mice in vivo. To gain further insight into structure-property relations, a library of carefully designed polymers based on p(HPMA) and p(LMA) was synthesized and tested applying an in vitro BBB model which consisted of human brain microvascular endothelial cells (HBMEC). Our model drug Rhodamine 123 (Rh123) exhibits, like domperidone, a low brain permeability since both substances are recognized by efflux transporters at the BBB. Transport studies investigating the impact of the polymer architecture in relation to the content of hydrophobic LMA revealed that random p(HPMA)-co-p(LMA) having 10mol% LMA is the most auspicious system. The copolymer significantly increased the permeability of Rh123 across the HBMEC monolayer whereas transcytosis of the polymer was very low. Further investigations on the mechanism of transport showed that integrity and barrier function of the BBB model were not harmed by the polymer. According to our results, p(HPMA)-co-p(LMA) copolymers are a promising delivery system for neurological therapeutics and their application might open alternative treatment strategies. Copyright © 2012 Elsevier B.V. All rights reserved.

  3. IMF sector behavior estimated from geomagnetic data at South Pole

    International Nuclear Information System (INIS)

    Matsushita, S.; Xu, W.h.

    1981-01-01

    IMF sector behavior which has previously been estimated from the geomagnetic data at Godhavn is confirmed by study of the data at South Pole for 1959--1970 with the same estimation technique, taking the difference between northern and southern hemispheres into consideration. A method to improve (about 18%) the agreement between assigned and actual sector structures by study of the data at the two stations is suggested. Geomagnetic disturbance effects on sector estimation are discussed, and reversed sector effects in winter are given special emphasis

  4. Strong gravitational lensing and the stellar IMF of early-type galaxies

    Science.gov (United States)

    Leier, Dominik; Ferreras, Ignacio; Saha, Prasenjit; Charlot, Stéphane; Bruzual, Gustavo; La Barbera, Francesco

    2016-07-01

    Systematic variations of the initial mass function (IMF) in early-type galaxies, and their connection with possible drivers such as velocity dispersion or metallicity, have been much debated in recent years. Strong lensing over galaxy scales combined with photometric and spectroscopic data provides a powerful method to constrain the stellar mass-to-light ratio and hence the functional form of the IMF. We combine photometric and spectroscopic constraints from the latest set of population synthesis models of Charlot & Bruzual, including a varying IMF, with a non-parametric analysis of the lens masses of 18 ETGs from the SLACS survey, with velocity dispersions in the range 200-300 km s-1. We find that very bottom-heavy IMFs are excluded. However, the upper limit to the bimodal IMF slope (μ ≲ 2.2, accounting for a dark matter fraction of 20-30 per cent, where μ = 1.3 corresponds to a Kroupa-like IMF) is compatible at the 1σ level with constraints imposed by gravity-sensitive line strengths. A two-segment power-law parametrization of the IMF (Salpeter-like for high masses) is more constrained (Γ ≲ 1.5, where Γ is the power index at low masses) but requires a dark matter contribution of ≳25 per cent to reconcile the results with a Salpeter IMF. For a standard Milky Way-like IMF to be applicable, a significant dark matter contribution is required within 1Re. Our results reveal a large range of allowed IMF slopes, which, when interpreted as intrinsic scatter in the IMF properties of ETGs, could explain the recent results of Smith et al., who find Milky Way-like IMF normalizations in a few massive lensing ETGs.

  5. Review of Poor States, Power and the Politics of IMF Reform

    Directory of Open Access Journals (Sweden)

    Mulatu Amare Desta

    2017-08-01

    Full Text Available The book examines the major cases and policy initiatives of International Monetary Fund (IMF in Low-Income Developing Countries (LIDCs in the post-Washington consensus. The IMF policy reform invites scholarly debate, different theoretical explanation and practically problem oriented in addressing the LIDCs needs and powerful states interests. Hibben analyses the driving factors of IMF LIDCs reforms and stakeholder interests and policy tools to achieve the objectives in place.  In doing so, even though author presents the book through lenses of various IPE theories, mainly he posits the IMF policy reforms through the frameworks of the Principal Agent, Constructivist, and Historical structural theories.

  6. Has the IMF Outlived Its Usefulness or Gone Past Its “Use-by” Date?

    Directory of Open Access Journals (Sweden)

    Imad A. Moosa

    2018-01-01

    Full Text Available Since the advent of the Asian financial crisis of the late 1990s, a debate has ensued on whether the International Monetary Fund (IMF should be reformed, abolished, or left as is because it is performing a good and useful job. In this paper, it is argued that the IMF should be abolished because its work, particularly in developing countries, has been useless at best and harmful at worst. Several reasons, as well as examples of how IMF operations have been detrimental to the welfare of people living in countries that the IMF is supposed to help, are presented to support this proposition.

  7. lma sõja piirid Ida-Aasias ajaloolaste pilgu läbi / Jaanika Erne

    Index Scriptorium Estoniae

    Erne, Jaanika, 1967-

    2016-01-01

    Raamatuülevaade: The Cold War in East Asia 1945–1991. T. Hasegawa (Ed.). Washington D.C.: Woodrow Wilson Center Press 2011, Stanford: Stanford University Press 2011, viii + 340 lk. Külma sõja aegsetest poliitilistest sündmustest

  8. Tracheal intubation in patients with cervical spine immobilization: a comparison of the Airwayscope, LMA CTrach, and the Macintosh laryngoscopes.

    LENUS (Irish Health Repository)

    Malik, M A

    2009-05-01

    The purpose of this study was to evaluate the effectiveness of the Pentax AWS, and the LMA CTrach, in comparison with the Macintosh laryngoscope, when performing tracheal intubation in patients with neck immobilization using manual in-line axial cervical spine stabilization.

  9. The financial crisis and global health: the International Monetary Fund's (IMF) policy response.

    Science.gov (United States)

    Ruckert, Arne; Labonté, Ronald

    2013-09-01

    In this article, we interrogate the policy response of the International Monetary Fund (IMF) to the global financial crisis, and discuss the likely global health implications, especially in low-income countries. In doing so, we ask if the IMF has meaningfully loosened its fiscal deficit targets in light of the economic challenges posed by the financial crisis and adjusted its macro-economic policy advice to this new reality; or has the rhetoric of counter-cyclical spending failed to translate into additional fiscal space for IMF loan-recipient countries, with negative health consequences? To answer these questions, we assess several post-crisis IMF lending agreements with countries requiring financial assistance, and draw upon recent academic studies and civil society reports examining policy conditionalities still being prescribed by the IMF. We also reference recent studies examining the health impacts of these conditionalities. We demonstrate that while the IMF has been somewhat more flexible in its crisis response than in previous episodes of financial upheaval, there has been no meaningful rethinking in the application of dominant neoliberal macro-economic policies. After showing some flexibility in the initial crisis response, the IMF is pushing for excessive contraction in most low and middle-income countries. We conclude that there remains a wide gap between the rhetoric and the reality of the IMF's policy and programming advice, with negative implications for global health.

  10. VizieR Online Data Catalog: GalIMF version 1.0.0 (Yan+, 2017)

    Science.gov (United States)

    Yan, Z.; Jerabkova, T.; Kroupa, P.

    2017-08-01

    GalIMF stands for the Galaxy-wide Initial Mass Function. It is a Python 3 module that allows users to compute galaxy-wide initial stellar mass functions based on locally derived empirical constraints following the IGIMF theory. See the GalIMF homepage https://sites.google.com/view/galimf/home for more information. (1 data file).

  11. Advanced fuel cycles options for LWRs and IMF benchmark definition

    International Nuclear Information System (INIS)

    Breza, J.; Darilek, P.; Necas, V.

    2008-01-01

    In the paper, different advanced nuclear fuel cycles including thorium-based fuel and inert-matrix fuel are examined under light water reactor conditions, especially VVER-440, and compared. Two investigated thorium based fuels include one solely plutonium-thorium based fuel and the second one plutonium-thorium based fuel with initial uranium content. Both of them are used to carry and burn or transmute plutonium created in the classical UOX cycle. The inert-matrix fuel consist of plutonium and minor actinides separated from spent UOX fuel fixed in Yttria-stabilised zirconia matrix. The article shows analysed fuel cycles and their short description. The conclusion is concentrated on the rate of Pu transmutation and Pu with minor actinides cumulating in the spent advanced thorium fuel and its comparison to UOX open fuel cycle. Definition of IMF benchmark based on presented scenario is given. (authors)

  12. Regulating capital flows in emerging markets: The IMF and the global financial crisis

    Directory of Open Access Journals (Sweden)

    Kevin P. Gallagher

    2017-12-01

    Full Text Available In the wake of the financial crisis the International Monetary Fund (IMF began to publicly express support for what have traditionally been referred to as ‘capital controls’. This paper empirically examines the extent to which the change in IMF discourse on these matters has resulted in significant changes in actual IMF policy advice. By creating and analyzing a database of IMF Article IV reports, we examine whether the financial crisis had an independent impact on IMF support for capital controls. We find that the IMF’s level of support for capital controls has increased as a result of the crisis and as the vulnerabilities associated with capital flows accentuate.

  13. IMF-Slices for GPR Data Processing Using Variational Mode Decomposition Method

    Directory of Open Access Journals (Sweden)

    Xuebing Zhang

    2018-03-01

    Full Text Available Using traditional time-frequency analysis methods, it is possible to delineate the time-frequency structures of ground-penetrating radar (GPR data. A series of applications based on time-frequency analysis were proposed for the GPR data processing and imaging. With respect to signal processing, GPR data are typically non-stationary, which limits the applications of these methods moving forward. Empirical mode decomposition (EMD provides alternative solutions with a fresh perspective. With EMD, GPR data are decomposed into a set of sub-components, i.e., the intrinsic mode functions (IMFs. However, the mode-mixing effect may also bring some negatives. To utilize the IMFs’ benefits, and avoid the negatives of the EMD, we introduce a new decomposition scheme termed variational mode decomposition (VMD for GPR data processing for imaging. Based on the decomposition results of the VMD, we propose a new method which we refer as “the IMF-slice”. In the proposed method, the IMFs are generated by the VMD trace by trace, and then each IMF is sorted and recorded into different profiles (i.e., the IMF-slices according to its center frequency. Using IMF-slices, the GPR data can be divided into several IMF-slices, each of which delineates a main vibration mode, and some subsurface layers and geophysical events can be identified more clearly. The effectiveness of the proposed method is tested using synthetic benchmark signals, laboratory data and the field dataset.

  14. The «Group of Twenty», IMF and EU and Reforming of Global Governance

    Directory of Open Access Journals (Sweden)

    Evgeniy J. Il'in

    2014-01-01

    Full Text Available This article is devoted to the process of reforming the global financial system and world economic organizations since the foundation of the International Monetary Fund at the Bretton Woods Conference in 1944 to present time. Special attention is given to results of cooperation of the IMF and the "Group of Twenty"in the context of the world financial crisis 2008-2009. This article mentions the key benchmarks of the historical development of world economy: foundation of the Bretton Woods financial system, rejection of the gold standard at the Jamaica Conference, transition to the floating exchange rates, the wave of crises in the 1990-s, the world financial crisis of 2008-2009. The process of evolution of the IMF within the framework of these global events is considered here. The cooperation of EU, IMF and "Group of Twenty" is considered. The reforms of the IMF and their results are analyzed. The policy of the IMF at different historical stages of its evolution is estimated. As well as it results, the article also deals with the formation and development of the "Group of Twenty". The increasing role of the "Group of Twenty" in the global economic governance and reforming the IMF is considered. Especially is marked the necessity of the further reforms of the IMF and increasing of participation of the "G-20" in the world economic and politic system.

  15. Testing the Universality of the Stellar IMF with Chandra and HST

    Science.gov (United States)

    Coulter, D. A.; Lehmer, B. D.; Eufrasio, R. T.; Kundu, A.; Maccarone, T.; Peacock, M.; Hornschemeier, A. E.; Basu-Zych, A.; Gonzalez, A. H.; Maraston, C.; Zepf, S. E.

    2017-02-01

    The stellar initial mass function (IMF), which is often assumed to be universal across unresolved stellar populations, has recently been suggested to be “bottom-heavy” for massive ellipticals. In these galaxies, the prevalence of gravity-sensitive absorption lines (e.g., Na I and Ca II) in their near-IR spectra implies an excess of low-mass (m≲ 0.5 {M}⊙ ) stars over that expected from a canonical IMF observed in low-mass ellipticals. A direct extrapolation of such a bottom-heavy IMF to high stellar masses (m≳ 8 {M}⊙ ) would lead to a corresponding deficit of neutron stars and black holes, and therefore of low-mass X-ray binaries (LMXBs), per unit near-IR luminosity in these galaxies. Peacock et al. searched for evidence of this trend and found that the observed number of LMXBs per unit K-band luminosity (N/{L}K) was nearly constant. We extend this work using new and archival Chandra X-ray Observatory and Hubble Space Telescope observations of seven low-mass ellipticals where N/{L}K is expected to be the largest and compare these data with a variety of IMF models to test which are consistent with the observed N/{L}K. We reproduce the result of Peacock et al., strengthening the constraint that the slope of the IMF at m≳ 8 {M}⊙ must be consistent with a Kroupa-like IMF. We construct an IMF model that is a linear combination of a Milky Way-like IMF and a broken power-law IMF, with a steep slope ({α }1=3.84) for stars 0.5 {M}⊙ , and discuss its wider ramifications and limitations.

  16. Utilization program of HANARO under IMF situation in Korea

    International Nuclear Information System (INIS)

    Choi, Chang Oong; Kuk, Il Hiun; Chae, Sung Ki; Sohn, Jae Min

    1999-01-01

    Some of utilization facilities in HANARO are still being installed and among them CNS and FTL are yet in the design stage. This kind of situation in HANARO was mainly caused by the shortage of total budget of the reactor project during the period of reactor construction (1985 ∼ 1994). Installation of remaining utilization facilities to be equipped after HANARO construction had to rely on the resources of the long-term nuclear R and D program. The program commenced in 1992 with the 10-year implementation plan. It stipulates to be revised every 5 years in order to reflect changing national and international nuclear circumstances. The original nuclear R and D program (1992 ∼ 2001) set up in 1992 was amended in 1997 to establish nuclear policy infrastructure and to strengthen technological self-reliance in nuclear power. In this amended long-term nuclear R and D program (1997 ∼ 2006), full scope of utilization facility in HANARO was accommodated. However, economical difficulty befell to Korea from the end of 1997 and every social structure in Korea had to be reshaped with top priority of productivity base. Every industrial sector was desperately striving to cope with the financial difficulty by utilizing maximum production efficiency and by minimizing other functions or activities, which are not directly related to production activity. Even though nationwide endeavor strenuously to get over the economical difficulty, the government had to be supported from IMF (International Monetary Fund). Under the IMF situation in Korea, the nuclear R and D program must be adjusted due to cut-down of research fund from the government. Consequently utilization facility of HANARO is to be evaluated based on the users' program and their requirements. According to the evaluation results from the users' conditions, among the HANARO utilization facilities the first priority is pointed to be RI production facility, the second is to be neutron scattering facility, the third to be fuel

  17. Evaluating LMA and CLAMP: Using information criteria to choose a model for estimating elevation

    Science.gov (United States)

    Miller, I.; Green, W.; Zaitchik, B.; Brandon, M.; Hickey, L.

    2005-12-01

    The morphology of leaves and composition of the flora respond strongly to the moisture and temperature of their environment. Elevation and latitude correlate, at first order, to these atmospheric parameters. An obvious modern example of this relationship between leaf morphology and environment is the tree line, where boreal forests give way to artic (high latitude) or alpine (high elevation) tundra. Several quantitative methods, all of which rely on uniformitarianism, have been developed to estimate paleoelevation using fossil leaf morphology. These include 1) the univariate leaf-margin analysis (LMA), which estimates mean annual temperature (MAT) by the positive linear correlation between MAT and P, the proportion of entire or smooth to non-entire or toothed margined woody dicot angiosperm leaves within a flora and 2) the Climate Leaf Analysis Multivariate Program (CLAMP) which uses Canonical Correspondence Analysis (CCA) to estimate MAT, moist enthalpy, and other atmospheric parameters using 31 explanatory leaf characters from woody dicot angiosperms. Given a difference in leaf-estimated MAT or moist enthalpy between contemporaneous, synlatitudinal fossil floras-one at sea-level, the other at an unknown paleoelevation-paleoelevation may be estimated. These methods have been widely applied to orogenic settings and concentrate particularly in the Western US. We introduce the use of information criteria to compare different models for estimating elevation and show how the additional complexity of the CLAMP analytical methodology does not necessarily improve on the elevation estimates produced by simpler regression models. In addition, we discuss the signal-to-noise ratio in the data, give confidence intervals for detecting elevations, and address the problem of spatial autocorrelation and irregular sampling in the data.

  18. Effect of the IMF By component on the ionospheric flow overhead at EISCAT: observations and theory

    Directory of Open Access Journals (Sweden)

    S. W. H. Cowley

    Full Text Available We have analysed a database of ∼300 h of tristatic ionospheric velocity measurements obtained overhead at Tromsø (66.3° magnetic latitude by the EISCAT UHF radar system, for the presence of flow effects associated with the y-component of the IMF. Since it is already known that the flow depends upon IMF Bz, a least-squares multivariate analysis has been used to determine the flow dependence on both IMF By and Bz simultaneously. It is found that significant flow variations with IMF By occur, predominantly in the midnight sector (∼2100–0300 MLT, but also pre-dusk (∼1600–1700 MLT, which are directed eastward for IMF By positive and westward for IMF By negative. The flows are of magnitude 20–30 m s–1 nT–1 in the midnight sector, and smaller, 10–20 m s–1 nT–1, pre-dusk, and are thus associated with significant changes of flow of order a few hundred m s–1 over the usual range of IMF By of about ±5 nT. At other local times the IMF By-related perturbation flows are much smaller, less than ∼5 m s–1 nT–1, and consistent with zero within the uncertainty estimates. We have investigated whether these IMF By-dependent flows can be accounted for quantitatively by a theoretical model in which the equatorial flow in the inner magnetosphere is independent of IMF By, but where distortions of the magnetospheric magnetic field associated with a "penetrating" component of the IMF By field changes the mapping of the field to the ionosphere, and hence the ionospheric flow. We find that the principal flow perturbation produced by this effect is an east-west flow whose sense is determined by the north-south component of the unperturbed flow. Perturbations in the north-south flow are typically smaller by more than an order of magnitude, and generally negligible in terms of observations. Using equatorial flows which are determined from EISCAT data for zero IMF By, to which the corotation flow has been added, the theory predicts the presence

  19. Effect of the IMF By component on the ionospheric flow overhead at EISCAT: observations and theory

    Directory of Open Access Journals (Sweden)

    H. Khan

    2000-12-01

    Full Text Available We have analysed a database of ∼300 h of tristatic ionospheric velocity measurements obtained overhead at Tromsø (66.3° magnetic latitude by the EISCAT UHF radar system, for the presence of flow effects associated with the y-component of the IMF. Since it is already known that the flow depends upon IMF Bz, a least-squares multivariate analysis has been used to determine the flow dependence on both IMF By and Bz simultaneously. It is found that significant flow variations with IMF By occur, predominantly in the midnight sector (∼2100–0300 MLT, but also pre-dusk (∼1600–1700 MLT, which are directed eastward for IMF By positive and westward for IMF By negative. The flows are of magnitude 20–30 m s–1 nT–1 in the midnight sector, and smaller, 10–20 m s–1 nT–1, pre-dusk, and are thus associated with significant changes of flow of order a few hundred m s–1 over the usual range of IMF By of about ±5 nT. At other local times the IMF By-related perturbation flows are much smaller, less than ∼5 m s–1 nT–1, and consistent with zero within the uncertainty estimates. We have investigated whether these IMF By-dependent flows can be accounted for quantitatively by a theoretical model in which the equatorial flow in the inner magnetosphere is independent of IMF By, but where distortions of the magnetospheric magnetic field associated with a "penetrating" component of the IMF By field changes the mapping of the field to the ionosphere, and hence the ionospheric flow. We find that the principal flow perturbation produced by this effect is an east-west flow whose sense is determined by the north-south component of the unperturbed flow. Perturbations in the north-south flow are typically smaller by more than an order of magnitude, and generally negligible in terms of observations. Using equatorial flows which are determined from EISCAT data for zero IMF By, to which the corotation flow has been added, the theory predicts the presence

  20. Large Scale Earth's Bow Shock with Northern IMF as Simulated by ...

    Indian Academy of Sciences (India)

    results with the available MHD simulations under same scaled solar wind. (SW) and (IMF) ... their effects in dissipating flow-energy, in heating matter, in accelerating particles to high, presumably ... such as hybrid models (Omidi et al. 2013 ...

  1. Developing Economies and Global Governance: Will IMF Rethink Its Orthodox View?

    Directory of Open Access Journals (Sweden)

    Manjula Jain

    2018-01-01

    Full Text Available It has been constantly viewed that the developed economies unevenly ruled the governance structures in the international organizations such as International Monetary Fund (MF. The continuous development in Emerging and Developing Economies (EDEs over the last 20 years witnessed their growing importance in the world economy, but at the same time little increase in their voice in the IMF. There are reasons for the discontent of the EDEs in the present structure such as the increase of regional monetary arrangements, uneven distribution of quota shares, IMF quota reforms, and IMF voting structure. The world economy is witnessing a tremendous growth of these EDEs and is now at the verge where Asian economies are capable of leading, rather than the North Atlantic economies. This issue should be acknowledged properly and must be responded adequately. This paper makes an attempt to understand the prime issues that should be fixed in the current quotas system and voting structure in the IMF.

  2. Kas BRICS-i pank suudab võistelda IMF-iga? / Mark Adomanis

    Index Scriptorium Estoniae

    Adomanis, Mark

    2014-01-01

    Suurte tärkavate turgude e. BRICS-i riikide pank on katse tasakaalustada suurenevat lõhet areneva maailma majandusliku võimsuse ja tema mõjuvõimu vahel rahvusvahelistele rahandusorganisatsioonidele, nagu IMF ja Maailmapank

  3. Populism versus IMF Conditionalities: Demand Management Policies in Present Regime of Globalization

    Directory of Open Access Journals (Sweden)

    Ayub Mehar

    2018-01-01

    Full Text Available The end of a bipolar regime after the collapse of the Soviet Union diverted the world economies to globalization regime, where economic freedom and liberalization were adopted as most powerful and popular philosophies of the economic welfare and development. The origination of a free trade regime, decentralization in public finance, and revival of the classical school of thought in economic policies are the natural outcomes of the global failure of centrally controlled economic planning experiences. Autonomy of the central banks, market-oriented exchange rates, convertibility of the currencies, privatization, deregulation, and free trade are the banners of classical economic thoughts in the present regime. Meanwhile, the International Monetary Fund (IMF came into force when the world was divided into left and right arms. The IMF conditionality and recommended measures are still based on demand management mechanism where most of the advices belong to exchange rate mechanism (devaluation, increase in interest rate, increase in tax revenue, reduction in subsidies, transfer payments, so on. The core objective of this study is to review the IMF policies and practices in the contemporary world where supply-side policies and classical theories are regaining their importance in post-Soviet regime. Before any recommendation and contemplating the role of the IMF in the contemporary world, it will be appropriate to review and analyze the current practices of the IMF by three dimensions: History and cause of the creation of the IMF, its governance and financial structure, and its role in global economy and lending activities. The study suggests the change in the IMF governance structure and the coordination between World Trade Organization (WTO, World Economic Forum (WEF, and IMF policies.

  4. Randomized comparison of the i-gel™, the LMA Supreme™, and the Laryngeal Tube Suction-D using clinical and fibreoptic assessments in elective patients

    Directory of Open Access Journals (Sweden)

    Russo Sebastian G

    2012-08-01

    Full Text Available Abstract Background The i-gel™, LMA-Supreme (LMA-S and Laryngeal Tube Suction-D (LTS-D are single-use supraglottic airway devices with an inbuilt drainage channel. We compared them with regard to their position in situ as well as to clinical performance data during elective surgery. Methods Prospective, randomized, comparative study of three groups of 40 elective surgical patients each. Speed of insertion and success rates, leak pressures (LP at different cuff pressures, dynamic airway compliance, and signs of postoperative airway morbidity were recorded. Fibreoptic evaluation was used to determine the devices’ position in situ. Results Leak pressures were similar (i-gel™ 25.9, LMA-S 27.1, LTS-D 24.0 cmH2O; the latter two at 60 cmH2O cuff pressure as were insertion times (i-gel™ 10, LMA-S 11, LTS-D 14 sec. LP of the LMA-S was higher than that of the LTS-D at lower cuff pressures (p p p 0.05. Airway morbidity was more pronounced with the LTS-D (p 0.01. Conclusion All devices were suitable for ventilating the patients’ lungs during elective surgery. Trial registration German Clinical Trial Register DRKS00000760

  5. Evidence for a constant IMF in early-type galaxies based on their X-ray binary populations

    OpenAIRE

    Peacock, Mark B.; Zepf, Stephen E.; Maccarone, Thomas J.; Kundu, Arunav; Gonzalez, Anthony H.; Lehmer, Bret D.; Maraston, Claudia

    2014-01-01

    A number of recent studies have proposed that the stellar initial mass function (IMF) of early type galaxies varies systematically as a function of galaxy mass, with higher mass galaxies having bottom heavy IMFs. These bottom heavy IMFs have more low-mass stars relative to the number of high mass stars, and therefore naturally result in proportionally fewer neutron stars and black holes. In this paper, we specifically predict the variation in the number of black holes and neutron stars based ...

  6. Fault diagnosis of rotating machinery using an improved HHT based on EEMD and sensitive IMFs

    International Nuclear Information System (INIS)

    Lei, Yaguo; Zuo, Ming J

    2009-01-01

    A Hilbert–Huang transform (HHT) is a time–frequency technique and has been widely applied to analyzing vibration signals in the field of fault diagnosis of rotating machinery. It analyzes the vibration signals using intrinsic mode functions (IMFs) extracted using empirical mode decomposition (EMD). However, EMD sometimes cannot reveal the signal characteristics accurately because of the problem of mode mixing. Ensemble empirical mode decomposition (EEMD) was developed recently to alleviate this problem. The IMFs generated by EEMD have different sensitivity to faults. Some IMFs are sensitive and closely related to the faults but others are irrelevant. To enhance the accuracy of the HHT in fault diagnosis of rotating machinery, an improved HHT based on EEMD and sensitive IMFs is proposed in this paper. Simulated signals demonstrate the effectiveness of the improved HHT in diagnosing the faults of rotating machinery. Finally, the improved HHT is applied to diagnosing an early rub-impact fault of a heavy oil catalytic cracking machine set, and the application results prove that the improved HHT is superior to the HHT based on all IMFs of EMD

  7. High-latitude convection on open and closed field lines for large IMF B(y)

    Science.gov (United States)

    Moses, J. J.; Crooker, N. U.; Gorney, D. J.; Siscoe, G. L.

    1985-01-01

    S3-3 electric field observations for August 23, 1976, show a single convection cell engulfing the northern polar cap. The flow direction is that for a positive IMF B(y) component. The particle data indicate that nearly half the duskside sunward flow occurs on closed field lines whereas the dawnside flow is entirely on open field lines. This is interpreted in terms of an IMF B(y)-induced deformation in the polar cap boundary, where the deformation moves with the convective flow. Thus, convection streamlines cross the deformed polar cap boundary, but no flow crosses the boundary because it is carried by the flow. Since southern hemisphere convection is expected to occur with the opposite sense of rotation, closed field lines that will be forced to tilt azimuthally are predicted. On the nightside the tilt produces a y component of the magnetic field in the same direction as the IMF for either sign of IMF B(y). This interpretation is consistent with observations of a greater y component in the plasma sheet than the tail lobes, which are difficult to understand in terms of the common explanation of IMF penetration. Alternatives to this interpretation are also discussed.

  8. Reconnection During Periods of Large IMF By Producing Shear Instabilities at the Dayside Convection Reversal Boundary

    Science.gov (United States)

    Qamar, S.; Clauer, C. R.; Hartinger, M.; Xu, Z.

    2017-12-01

    During periods of large interplanetary magnetic field (IMF) By component and small negative Bz (GSM Coordinates), the ionospheric polar electric potential system is distorted so as to produce large east-west convection shears across local noon. Past research has shown examples of ULF waves with periods of approximately 10 - 20 minutes observed at this convection shear by the Greenland west coast chain of magnetometers. Past work has shown examples of these waves and associated them with conditions in the solar wind and IMF, particularly periods of large IMF By component. Here we report the results of a search of several years of solar wind data to identify periods when the IMF By component is large and the magnetometer chains along the 40-degree magnetic meridian (Greenland west coast and conjugate Antarctic chains) are within a few hours of local noon. We test here the hypothesis that large IMF By reconnection leads to large convection shears across local noon that generate ULF waves through, presumably, a shear instability such as Kelvin-Helmholtz.

  9. The influence of IMF cone angle on invariant latitudes of polar region footprints of FACs in the magnetotail: Cluster observatio

    Science.gov (United States)

    Cheng, Z.; Shi, J.; Zhang, J.; Kistler, L. M.

    2017-12-01

    The influence of the interplanetary magnetic field (IMF) cone angle θ (the angle between the IMF direction and the Sun-Earth line) on the invariant latitudes (ILATs) of the footprints of the field-aligned currents (FACs) in the magnetotail has been investigated. We performed a statistic study of 542 FAC cases observed by the four Cluster spacecraft in the northern hemisphere. The results show that the large FAC (>10 nA/m2) cases occur at the low ILATs (60º, which implies the footprints of the large FACs mainly expand equatorward with large IMF cone angle. The equatorward boundary of the FAC footprints in the polar region decreases with the IMF cone angle especially when IMF Bz is positive. There is almost no correlation or a weak positive correlation of the poleward boundary and IMF cone angle no matter IMF is northward or southward. The equatorward boundary is more responsive to the IMF cone angle. Compared to the equatorward boundary, the center of the FAC projected location changes very little. This is the first time a correlation between FAC projected location and IMF cone angle has been determined.

  10. SWiFT Software Quality Assurance Plan.

    Energy Technology Data Exchange (ETDEWEB)

    Berg, Jonathan Charles [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2016-01-01

    This document describes the software development practice areas and processes which contribute to the ability of SWiFT software developers to provide quality software. These processes are designed to satisfy the requirements set forth by the Sandia Software Quality Assurance Program (SSQAP). APPROVALS SWiFT Software Quality Assurance Plan (SAND2016-0765) approved by: Department Manager SWiFT Site Lead Dave Minster (6121) Date Jonathan White (6121) Date SWiFT Controls Engineer Jonathan Berg (6121) Date CHANGE HISTORY Issue Date Originator(s) Description A 2016/01/27 Jon Berg (06121) Initial release of the SWiFT Software Quality Assurance Plan

  11. Sao Paulo Lightning Mapping Array (SP-LMA): Network Assessment and Analyses for Intercomparison Studies and GOES-R Proxy Activities

    Science.gov (United States)

    Bailey, J. C.; Blakeslee, R. J.; Carey, L. D.; Goodman, S. J.; Rudlosky, S. D.; Albrecht, R.; Morales, C. A.; Anselmo, E. M.; Neves, J. R.; Buechler, D. E.

    2014-01-01

    A 12 station Lightning Mapping Array (LMA) network was deployed during October 2011 in the vicinity of Sao Paulo, Brazil (SP-LMA) to contribute total lightning measurements to an international field campaign [CHUVA - Cloud processes of tHe main precipitation systems in Brazil: A contribUtion to cloud resolVing modeling and to the GPM (GlobAl Precipitation Measurement)]. The SP-LMA was operational from November 2011 through March 2012 during the Vale do Paraiba campaign. Sensor spacing was on the order of 15-30 km, with a network diameter on the order of 40-50km. The SP-LMA provides good 3-D lightning mapping out to 150 km from the network center, with 2-D coverage considerably farther. In addition to supporting CHUVA science/mission objectives, the SP-LMA is supporting the generation of unique proxy data for the Geostationary Lightning Mapper (GLM) and Advanced Baseline Imager (ABI), on NOAA's Geostationary Operational Environmental Satellite-R (GOES-R: scheduled for a 2015 launch). These proxy data will be used to develop and validate operational algorithms so that they will be ready to use on "day1" following the GOES-R launch. As the CHUVA Vale do Paraiba campaign opportunity was formulated, a broad community-based interest developed for a comprehensive Lightning Location System (LLS) intercomparison and assessment study, leading to the participation and/or deployment of eight other ground-based networks and the space-based Lightning Imaging Sensor (LIS). The SP-LMA data is being intercompared with lightning observations from other deployed lightning networks to advance our understanding of the capabilities/contributions of each of these networks toward GLM proxy and validation activities. This paper addresses the network assessment including noise reduction criteria, detection efficiency estimates, and statistical and climatological (both temporal and spatially) analyses for intercomparison studies and GOES-R proxy activities.

  12. Autocorrelation Study of Solar Wind Plasma and IMF Properties as Measured by the MAVEN Spacecraft

    Science.gov (United States)

    Marquette, Melissa L.; Lillis, Robert J.; Halekas, J. S.; Luhmann, J. G.; Gruesbeck, J. R.; Espley, J. R.

    2018-04-01

    It has long been a goal of the heliophysics community to understand solar wind variability at heliocentric distances other than 1 AU, especially at ˜1.5 AU due to not only the steepening of solar wind stream interactions outside 1 AU but also the number of missions available there to measure it. In this study, we use 35 months of solar wind and interplanetary magnetic field (IMF) data taken at Mars by the Mars Atmosphere and Volatile EvolutioN (MAVEN) spacecraft to conduct an autocorrelation analysis of the solar wind speed, density, and dynamic pressure, which is derived from the speed and density, as well as the IMF strength and orientation. We found that the solar wind speed is coherent, that is, has an autocorrelation coefficient above 1/e, over roughly 56 hr, while the density and pressure are coherent over smaller intervals of roughly 25 and 20 hr, respectively, and that the IMF strength is coherent over time intervals of approximately 20 hr, while the cone and clock angles are considerably less steady but still somewhat coherent up to time lags of roughly 16 hr. We also found that when the speed, density, pressure, or IMF strength is higher than average, the solar wind or IMF becomes uncorrelated more quickly, while when they are below average, it tends to be steadier. This analysis allows us to make estimates of the values of solar wind plasma and IMF parameters when they are not directly measured and provide an approximation of the error associated with that estimate.

  13. Exploring the IMF of star clusters: a joint SLUG and LEGUS effort

    Science.gov (United States)

    Ashworth, G.; Fumagalli, M.; Krumholz, M. R.; Adamo, A.; Calzetti, D.; Chandar, R.; Cignoni, M.; Dale, D.; Elmegreen, B. G.; Gallagher, J. S., III; Gouliermis, D. A.; Grasha, K.; Grebel, E. K.; Johnson, K. E.; Lee, J.; Tosi, M.; Wofford, A.

    2017-08-01

    We present the implementation of a Bayesian formalism within the Stochastically Lighting Up Galaxies (slug) stellar population synthesis code, which is designed to investigate variations in the initial mass function (IMF) of star clusters. By comparing observed cluster photometry to large libraries of clusters simulated with a continuously varying IMF, our formalism yields the posterior probability distribution function (PDF) of the cluster mass, age and extinction, jointly with the parameters describing the IMF. We apply this formalism to a sample of star clusters from the nearby galaxy NGC 628, for which broad-band photometry in five filters is available as part of the Legacy ExtraGalactic UV Survey (LEGUS). After allowing the upper-end slope of the IMF (α3) to vary, we recover PDFs for the mass, age and extinction that are broadly consistent with what is found when assuming an invariant Kroupa IMF. However, the posterior PDF for α3 is very broad due to a strong degeneracy with the cluster mass, and it is found to be sensitive to the choice of priors, particularly on the cluster mass. We find only a modest improvement in the constraining power of α3 when adding Hα photometry from the companion Hα-LEGUS survey. Conversely, Hα photometry significantly improves the age determination, reducing the frequency of multi-modal PDFs. With the aid of mock clusters, we quantify the degeneracy between physical parameters, showing how constraints on the cluster mass that are independent of photometry can be used to pin down the IMF properties of star clusters.

  14. Heliographic latitude dependence of the IMF dominant polarity in 1972--1973 using Pioneer 10 data

    International Nuclear Information System (INIS)

    Rosenberg, R.L.

    1975-01-01

    The heliographic latitude dependence of the interplanetary magnetic field (IMF) was studied by using Pioneer 10 data taken from March 1972 through June 1973 over Bartels solar rotation (SR) periods 1896--1913. The daily IMF sector polarities were plotted for each of these SR periods. Then the number of days of positive polarity (''away'' directed fields) per SR was plotted versus the average heliographic latitude. The dominant polarity behaved in accordance with the latitude effects found by Rosenberg and Coleman in 1969. The phase of the cycle has reversed from what it was prior to the sunspot maximum in 1968. The polarity is now predominantly positive at northern heliographic latitudes. (auth)

  15. IMF By-Related Cusp Currents Observed from the Ørsted Satellite and from Ground

    DEFF Research Database (Denmark)

    Stauning, P.; Primdahl, Fritz; Watermann, J.

    2001-01-01

    Orsted is the first satellite to conduct high-precision magnetometer observations from low-altitude noonmidnight orbits passing through the polar cusp regions. Field-aligned currents (FAC) derived from Orsted magnetic field measurements have been combined with ionospheric current patterns inferred...... statistical analysis defines for the noon region the variations in FAC latitude with IMF B-Z. Comparisons with the statistical cusp location indicate that the more equatorward region of IMF B-gamma-while the more B related FAC is located on field lines closing at the dayside poleward FAC are on "open" field...

  16. On the cause of IMF By related mid- and low latitude magnetic disturbances

    DEFF Research Database (Denmark)

    Vennerstrøm, Susanne; Christiansen, Freddy; Olsen, Nils

    2007-01-01

    An analysis of the effect of the IMF By on near-Earth low and mid-latitude magnetic disturbances is presented. In particular the contribution from field-aligned currents ( FACs) connected to the polar regions is investigated. Based on statistically determined high-latitude FAC patterns for various...... that the long-distance effect of the high-latitude FACs constitute the major source to IMF By and B-z related magnetic east-west disturbances at mid-and low latitudes....

  17. The IMF-World Bank's economic stabilisation and structural adjustment policies and the Uganda economy, 1981-1989

    NARCIS (Netherlands)

    Nabudere, D.W.

    1990-01-01

    This research report traces all the main developments in IMF-World Bank policies in Uganda. Most of the material concerns the three IMF standby arrangements with Uganda for 1981-1984 and the World Bank Group's Structural Adjustment Programmes. These programmes introduced two contradictory policies

  18. Structural adjustment programmes on the African continent : the theoretical foundations of IMF/World Bank reform policies

    NARCIS (Netherlands)

    Meilink, H.A.

    2003-01-01

    Since the early 1980s the majority of countries in sub-Saharan Africa embarked on the implementation of IMF/World Bank designed 'structural adjustment programmes' (SAPs). This paper examines the theoretical underpinnings of the SAPs. It shows that IMF policies are based on a theoretical framework

  19. Controlling of merging electric field and IMF magnitude on storm-time changes in thermospheric mass density

    NARCIS (Netherlands)

    Zhou, Y.L.; Ma, S.Y.; Liu, R.S.; Luehr, H.; Doornbos, E.

    2013-01-01

    The controls of merging electrical field, Em, and IMF (interplanetary magnetic field) magnitude, B, on the storm-time changes in upper thermospheric mass density are statistically investigated using GRACE accelerometer observations and the OMNI data of solar wind and IMF for 35 great storms during

  20. IMF-screws or arch bars as conservative treatment for mandibular condyle fractures: Quality of life aspects

    NARCIS (Netherlands)

    van den Bergh, B.; van Otterloo, J.J.D.M.; van der Ploeg, T.; Tuinzing, D.B.; Forouzanfar, T.

    2015-01-01

    Objective Arch bars as treatment for a fractured mandibular condyle are inconvenient to patients and lead to lowered quality of life (QOL). To overcome these inconveniences, IMF-screws (IMFS) to facilitate intermaxillary fixation during surgery have been developed. The purpose of the present study

  1. IMF-screws or arch bars as conservative treatment for mandibular condyle fractures: quality of life aspects

    NARCIS (Netherlands)

    van den Bergh, B.; de Mol van Otterloo, J.J.; van der Ploeg, T.; Tuinzing, D.B.; Forouzanfar, T.

    2015-01-01

    Objective Arch bars as treatment for a fractured mandibular condyle are inconvenient to patients and lead to lowered quality of life (QOL). To overcome these inconveniences, IMF-screws (IMFS) to facilitate intermaxillary fixation during surgery have been developed. The purpose of the present study

  2. IMF : reservide kasutamise kõrval võiks Eesti ka laenata / Franciszek Rozwadowski ; interv. Jan Jõgis-Laats

    Index Scriptorium Estoniae

    Rozwadowski, Franciszek

    2008-01-01

    IMF-i delegatsiooni juhi sõnul ei vaja Eesti IMF-i tugilaenu ja ajalugu näitab, et Eesti suudab asjadega omal käel toime tulla. Soovitatav on, et Eesti kõiki oma reserve ära ei kasutaks, selleks on kaks moodust: eelarvedefitsiidi vähendamine ja kulutuste osaline katmine laenu abil

  3. Forankring af kvarterløft

    DEFF Research Database (Denmark)

    Mazanti, B.

    Kvarterløft er et offentligt initiativ, der har til formål at forbedre sociale, bygningsmæssige og andre forhold i en afgrænset bydel. Kvarterløft er per definition tidsbegrænset til fem eller syv år. Mens et kvarterløft står på, er der ofte en mængde og mangfoldighed af aktiviteter og projekter....

  4. Q-switching and efficient harmonic generation from a single-mode LMA photonic bandgap rod fiber laser

    DEFF Research Database (Denmark)

    Laurila, Marko; Saby, Julien; Alkeskjold, Thomas T.

    2011-01-01

    We demonstrate a Single-Mode (SM) Large-Mode-Area (LMA) ytterbium-doped PCF rod fiber laser with stable and close to diffraction limited beam quality with 110W output power. Distributed-Mode-Filtering (DMF) elements integrated in the cladding of the rod fiber provide a robust spatial mode...... with a Mode-Field-Diameter (MFD) of 59 mu m. We further demonstrate high pulse energy Second-Harmonic-Generation (SHG) and Third Harmonic Generation (THG) using a simple Q-switched single-stage rod fiber laser cavity architecture reaching pulse energies up to 1mJ at 515nm and 0.5mJ at 343nm. (C) 2011 Optical...

  5. Interhemispheric Asymmetry of the Sunward Plasma Flows for Strongly Dominant IMF BZ > 0

    Science.gov (United States)

    Yakymenko, K. N.; Koustov, A. V.; Fiori, R. A. D.

    2018-01-01

    Super Dual Auroral Radar Network (SuperDARN) convection maps obtained simultaneously in both hemispheres are averaged to infer polar cap ionospheric flow patterns under strongly dominant positive interplanetary magnetic field (IMF) Bz component. The data set consisted of winter observations in the Northern Hemisphere simultaneously with summer observations in the Southern Hemisphere. Long-lasting high-latitude dayside reverse convection cells are shown to have faster sunward flows at near-magnetic noon hours in the summer/Southern Hemisphere. Sunward flows typically deviate from the midnight-noon meridian toward 10-11 h of magnetic local time in the summer/Southern Hemisphere and are more aligned with the midnight-noon meridian in the winter/Northern Hemisphere. Flow deviations in the winter/Northern Hemisphere can be both toward prenoon and postnoon hours, and there is no clear relationship between flow deviation and the IMF By component. No strong preference for the sunward flow occurrence depending on the IMF Bx polarity was found. In addition, the rate of the sunward flow speed increase in response to an increase in driving conditions was found to be comparable for the IMF Bx > 0 and Bx < 0.

  6. Multi-instrument observations of nightside plasma patches under conditions of IMF Bz positive

    Directory of Open Access Journals (Sweden)

    V. S. C. Howells

    2008-08-01

    Full Text Available Results are presented from two multi-instrument case studies showing patches of cold, long-lived plasma in the winter nightside ionosphere during times when the z-component of the Interplanetary Magnetic Field (IMF Bz was positive. These enhancements were coincident with the antisunward convective plasma drift, flowing from polar to nightside auroral latitudes. In the first case, on 5 December 2005 with IMF By negative, two regions of enhanced electron density were observed extended in MLT in the magnetic midnight sector separated by lower densities near midnight. It is likely that the earlier enhancement originated on the dayside near magnetic noon and was transported to the nightside sector in the convective flow, whilst the later feature originated in the morning magnetic sector. The lower densities separating the two enhancements were a consequence of a pair of lobe cells essentially blocking the direct antisunward cross polar flow from the dayside. A second case study on 4 February 2006 with IMF By positive revealed a single nightside enhancement likely to have originated in the morning magnetic sector. These multi-instrument investigations, incorporating observations by the EISCAT radar facility, the SuperDARN network and radio tomography, reveal that plasma flowing from the dayside can play a significant role in the nightside ionosphere under conditions of IMF Bz positive. The observations are reinforced by simulations of flux-tube transport and plasma decay.

  7. La "condizionalità" del FMI: per un sistema migliore. (IMF conditionality – a better way

    Directory of Open Access Journals (Sweden)

    J. SPRAOS

    2013-12-01

    Full Text Available L' articolo esamina le condizioni del FMI per la tranche di credito accordi stand-by superiori. L' FMI deve affrontare le critiche che le sue azioni recenti hanno comportato sul ' territorio a causa di errori nei prestiti di banche   ai paesi del terzo mondo banche private - una questione che avrebbe potuto essere lasciata alle forze di mercato libere .Le condizioni di assistenza del FMI dovrebbero concentrarsi non sugli strumenti di politica ma su obiettivi politici , come la crescita , l'occupazione , l'inflazione e , in ultima analisi , il ripristino della bilancia dei pagamenti dei paesi.The article looks at IMF conditions for upper credit tranche stand-by arrangements. The IMF must face the criticism that its recent actions have transgressed on private banks' territory because of banks' errors in lending to third world countries - a matter that could have been left to free market forces. Conditions for IMF aid should focus not on policy instruments but on policy targets, such as growth, employment, inflation and, ultimately, restoration of countries' balance of payments positions. Conditions for IMF help should be centred squarely on the balance of payments of aid-seeking countries if a backwards trend is to be avoided.JEL: F32, F33

  8. Personal View: How IMF's loan freeze will affect health care in Malawi

    African Journals Online (AJOL)

    the country failed to meet some of the loan conditions. This was partly ... The need for doctors. The latest ... been pushed to the wall: if the country wants to satisfy the. IMF, then is ... could be employed and service the people who need health.

  9. The Asian Crisis, the IMF and Dr Mahathir, Intereconomics 34:4, 1999.

    NARCIS (Netherlands)

    Visser, H.; Wengel, J. ter

    2005-01-01

    In the 1997-8 Asian crisis, the IMF's strategy was to impose deflationary measures on Thailand and Korea. With the help of the dependent-economy model it is found that this strategy was unnecessarily restrictive and that Malaysia's solution of introducing temporary capital controls was not

  10. Radial measurements of IMF-sensitive absorption features in two massive ETGs

    Science.gov (United States)

    Vaughan, Sam P.; Davies, Roger L.; Zieleniewski, Simon; Houghton, Ryan C. W.

    2018-03-01

    We make radial measurements of stellar initial mass function (IMF) sensitive absorption features in the two massive early-type galaxies NGC 1277 and IC 843. Using the Oxford Short Wavelength Integral Field specTrogaph (SWIFT), we obtain resolved measurements of the Na I 0.82 and FeH 0.99 indices, amongst others, finding both galaxies show strong gradients in Na I absorption combined with flat FeH profiles at ˜0.4 Å. We find these measurements may be explained by radial gradients in the IMF, appropriate abundance gradients in [Na/Fe] and [Fe/H], or a combination of the two, and our data are unable to break this degeneracy. We also use full spectral fitting to infer global properties from an integrated spectrum of each object, deriving a unimodal IMF slope consistent with Salpeter in IC 843 (x = 2.27 ± 0.17) but steeper than Salpeter in NGC 1277 (x = 2.69 ± 0.11), despite their similar FeH equivalent widths. Independently, we fit the strength of the FeH feature and compare to the E-MILES and CvD12 stellar population libraries, finding agreement between the models. The IMF values derived in this way are in close agreement with those from spectral fitting in NGC 1277 (x_{CvD}=2.59^{+0.25}_{-0.48}, x_{E-MILES}=2.77± 0.31), but are less consistent in IC 843, with the IMF derived from FeH alone leading to steeper slopes than when fitting the full spectrum (x_{CvD}=2.57^{+0.30}_{-0.41}, x_{E-MILES}=2.72± 0.25). This work highlights the importance of a large wavelength coverage for breaking the degeneracy between abundance and IMF variations, and may bring into doubt the use of the Wing-Ford band as an IMF index if used without other spectral information.

  11. IMF BY and the seasonal dependences of the electric field in the inner magnetosphere

    Directory of Open Access Journals (Sweden)

    H. Matsui

    2005-10-01

    Full Text Available It is known that the electric field pattern at high latitudes depends on the polarity of the Y component of the interplanetary magnetic field (IMF BY and season. In this study, we investigate the seasonal and BY dependences in the inner magnetosphere using the perigee (4IMF BZ and BY, and by seasons or hemispheres. It is demonstrated from our statistics that the electric fields in the inner magnetosphere depend on these quantities. The following three points are inferred: 1 The electric fields exhibit some differences statistically between Cluster locations at the Northern and Southern Hemispheres with the same dipole L and magnetic local time (MLT values and during the same IMF conditions. These differences in the electric fields might result from hemispherical differences in magnetic field geometry and/or those in field-aligned potential difference. 2 The IMF BY and seasonal dependence of the dawnside and duskside electric fields at 4IMF BY and season into a realistic model of the inner magnetospheric convection electric field. Keywords. Magnetospheric physics (Electric fields; Magnetosphere-ionosphere interactions; Solar windmagnetosphere interactions

  12. Plasma jets and FTE Dayside Generation for Northward IMF on 8 June 2007: THEMIS Observations

    Science.gov (United States)

    Eriksson, S.; Cully, C. M.; Ergun, R. E.; Gosling, J. T.; Angelopoulos, V.; Bonnell, J. W.; McFadden, J. P.; Glassmeier, K.; Roux, A.; Auster, H.; Le Contel, O.

    2007-12-01

    Five-spacecraft THEMIS (TH) observations are presented for a 15.5 MLT equatorial magnetopause crossing on 8 June 2007 when the upstream IMF was predominantly northward with a negative IMF By component at Wind. During the 0650-0855 UT period on this day TH-B was the most tailward probe while TH-A was the most sunward probe. TH-E was closest to TH-A with a maximum separation of only 0.71 RE. The maximum TH-A to TH-B GSM separation was 1.85 RE. TH-B showed a clean magnetopause crossing into the magnetosphere as the magnetopause expanded over the probes while TH-A spent this 2-hour period within a boundary layer inside the magnetopause with frequent transitions between a magnetosheath-like and a magnetosphere-like plasma as previously seen by Cluster at high-latitudes for southward IMF [Wild et al., 2003]. TH-E observed similar activity for a shorter period of time. Many of the sheath-like transitions showed evidence of plasma jets at TH-A with enhanced speed in the tailward and/or duskward direction suggesting a subsolar component merging region. Some jets were related to frequent bipolar FTE signatures in the normal BN component with enhanced total pressure observed at their centers. The more common ±BN sequence suggests that TH-A observed tailward propagating FTEs on the sheath side of the magnetopause. We compare TH-E ExB velocities with the enhanced jet velocities observed by TH-A and discuss whether the jets observed within this boundary layer were caused by subsolar magnetopause reconnection. We also compare these low-latitude northward IMF observations with prior Cluster FTE observations at high-latitude for southward IMF.

  13. Reforming the IMF to Increase FDI Led Economic Growth: The Case of Latin American and Caribbean Countries

    Directory of Open Access Journals (Sweden)

    Ashraf Mahate

    2018-01-01

    Full Text Available There is a strong body of literature that finds a direct connection between inward foreign direct investment and economic growth in the host country. At the same time, economic growth in the host country attracts additional Foreign Direct Investment (FDI. This bidirectional relationship can be supported by the IMF through its lending program to countries to assist in dealing with short-term shocks as well as managing more long-term structural issues. In fact, the IMF programs in theory should provide an indicator to potential investors that the country is committed to making a change and opening its economy, which are typical requirements under IMF conditions. IMF intervention should lead to a positive impact on inward FDI. This study examines the impact of IMF-support programs on inward FDI for a sample of Latin American and Caribbean Countries. The results from this study reveal that being on an IMF borrowing program has a negative impact on inward FDI in the second and third year. We argue that being on an IMF borrowing program does not provide inward FDI with the seal of approval that it requires in making an investment.

  14. IMF-screws or arch bars as conservative treatment for mandibular condyle fractures: Quality of life aspects.

    Science.gov (United States)

    van den Bergh, B; de Mol van Otterloo, J J; van der Ploeg, T; Tuinzing, D B; Forouzanfar, T

    2015-09-01

    Arch bars as treatment for a fractured mandibular condyle are inconvenient to patients and lead to lowered quality of life (QOL). To overcome these inconveniences, IMF-screws (IMFS) to facilitate intermaxillary fixation during surgery have been developed. The purpose of the present study is to investigate and compare QOL for patients treated for a fractured mandibular condyle with either IMFS or arch bars. This research trial was conducted from 2010 to 2014 as part of an earlier prospective, multicenter, randomized clinical trial in which the use of IMFS was compared to the use of arch bars in the treatment of mandibular condylar fractures. In total, 50 patients were included: 30 (60%) male patients and 20 (40%) female patients (mean age: 31.8 years, standard deviation [SD] = 13.9 years, range = 18-64 years). A total of 24 (48%) patients were allocated in the IMFS group, and 26 (52%) patients were assigned to the arch-bars control group. Significant results were observed in the subscales social isolation, possibility to eat and vary diet, influence on sleep, and satisfaction with the given treatment, all in favour of IMFS. In conclusion, using IMFS as a method for conservative treatment of condylar fractures led to a higher QOL during the 6-week period of fracture healing. In comparison to arch bars, patients treated with IMFS experienced less social isolation, had fewer problems with eating, and express the feeling they are able to continue their normal diet. Furthermore it seems that the use of IMFS has a lower negative impact on social and financial aspects of the patient. Copyright © 2015 European Association for Cranio-Maxillo-Facial Surgery. Published by Elsevier Ltd. All rights reserved.

  15. La riforma del FMI: alcune questioni organizzatIve e operative (Reforming the IMF: Some Organizational and Operational Issues

    Directory of Open Access Journals (Sweden)

    Hossein Askari

    2000-03-01

    Full Text Available While financial crises during the 1990s have started a lively debate on IMF policies toward member countries, reform of the Fund's organizational structure and operations have been largely ignored. Improved organization and operations would increase IMF efficiency and membership participation, which would in turn increase IMF effectiveness in enhancing global economic conditions. In this paper, a number of such issues--quotas, voting structure and decision making; executive board and ministerial committees; management structure and staff; political dimensions, transparency and credibility--are assessed.

  16. Statistical against dynamical PLF fission as seen by the IMF-IMF correlation functions and comparisons with CoMD model

    Science.gov (United States)

    Pagano, E. V.; Acosta, L.; Auditore, L.; Cap, T.; Cardella, G.; Colonna, M.; De Filippo, E.; Geraci, E.; Gnoffo, B.; Lanzalone, G.; Maiolino, C.; Martorana, N.; Pagano, A.; Papa, M.; Piasecki, E.; Pirrone, S.; Politi, G.; Porto, F.; Quattrocchi, L.; Rizzo, F.; Russotto, P.; Trifiro’, A.; Trimarchi, M.; Siwek-Wilczynska, K.

    2018-05-01

    In nuclear reactions at Fermi energies two and multi particles intensity interferometry correlation methods are powerful tools in order to pin down the characteristic time scale of the emission processes. In this paper we summarize an improved application of the fragment-fragment correlation function in the specific physics case of heavy projectile-like (PLF) binary massive splitting in two fragments of intermediate mass(IMF). Results are shown for the reverse kinematics reaction 124 Sn+64 Ni at 35 AMeV that has been investigated by using the forward part of CHIMERA multi-detector. The analysis was performed as a function of the charge asymmetry of the observed couples of IMF. We show a coexistence of dynamical and statistical components as a function of the charge asymmetry. Transport CoMD simulations are compared with the data in order to pin down the timescale of the fragments production and the relevant ingredients of the in medium effective interaction used in the transport calculations.

  17. Annual report 1992 on research and development work by the IMF, Institute for Materials Research

    International Nuclear Information System (INIS)

    1993-03-01

    The present annual report describes the activities undertaken by the IMF in the following areas: 1. Low-pollutant and low-waste techniques (treatment and utilization of special wastes); 2. Nuclear fusion (studies for NET/ITER; structural materials for fusion devices; superconducting magnets; plasmas heating technique; blanket development; component-related safety investigations); 3. Nuclear safety research (safety and materials of fast breeders; transient behaviour of fast breeder fuel elements; LWR-oriented safety research; containment concepts for PWR-plants); 4. Nuclear waste management (materials studies of waste forms); 5. Superconductivity (superconductor developments); 6. Microsystems engineering (development and testing of compact and laminated materials of microsystems engineering); 7. Handling technique (remote handling components for invasive surgery); 8. Materials and interfaces (inter alia high-performance ceramics, failure behaviour, LCP, biomechanics). The appendix lists all publications or primary reports by the IMF in 1992. (orig./HP) [de

  18. Book review: Unholy trinity: The IMF, World Bank and WTO Richard Peet

    Directory of Open Access Journals (Sweden)

    M Breitenbach

    2014-05-01

    Full Text Available In this timely book Richard Peet and his team lay the foundation with an excellent analysis of the process of globalisation and the resultant emergence of the global economy. The authors are especially critical of the increasing influence of institutions like the International Monetary Fund (IMF, World Bank and World Trade Organisation (WTO on the economy and the consequences experienced by peoples, cultures and the environment. The single ideology of neo-liberalism is blamed for the undesirable outcomes. This book considers concepts of power, political interest, hegemony, discourse, responsibility and the power of practicality, in critically examining the IMF, World Bank and WTO. The conclusion is reached that “all three institutions play roles greatly different from those originally agreed to under the charters that set them up”.

  19. Galaxy structure from multiple tracers - III. Radial variations in M87's IMF

    Science.gov (United States)

    Oldham, Lindsay; Auger, Matthew

    2018-03-01

    We present the first constraints on stellar mass-to-light ratio gradients in an early-type galaxy (ETG) using multiple dynamical tracer populations to model the dark and luminous mass structure simultaneously. We combine the kinematics of the central starlight, two globular cluster populations and satellite galaxies in a Jeans analysis to obtain new constraints on M87's mass structure, employing a flexible mass model which allows for radial gradients in the stellar-mass-to-light ratio. We find that, in the context of our model, a radially declining stellar-mass-to-light ratio is strongly favoured. Modelling the stellar-mass-to-light ratio as following a power law, ϒ⋆ ˜ R-μ, we infer a power-law slope μ = -0.54 ± 0.05; equally, parametrizing the stellar-mass-to-light ratio via a central mismatch parameter relative to a Salpeter initial mass function (IMF), α, and scale radius RM, we find α > 1.48 at 95% confidence and RM = 0.35 ± 0.04 kpc. We use stellar population modelling of high-resolution 11-band HST photometry to show that such a steep gradient cannot be achieved by variations in only the metallicity, age, dust extinction and star formation history if the stellar IMF remains spatially constant. On the other hand, the stellar-mass-to-light ratio gradient that we find is consistent with an IMF whose inner slope changes such that it is Salpeter-like in the central ˜0.5 kpc and becomes Chabrier-like within the stellar effective radius. This adds to recent evidence that the non-universality of the IMF in ETGs may be confined to their core regions, and points towards a picture in which the stars in these central regions may have formed in fundamentally different physical conditions.

  20. Economic Development through Globalisation in Nigeria : An analysis of Shell & the IMF Structural Adjustment Programs

    OpenAIRE

    Bokhari, Sven; Del Duca, Fabrizio

    2008-01-01

    Date: 2008/06/03 Level: Master thesis in International Business and Entrepreneurship, 10p (15ECTS) Authors: Sven Bokhari Fabrizio Del Duca Title: Economic Development through globalisation in Nigeria. An analysis of Shell & the IMF Structural Adjustment Programs Tutor: Leif Linnskog, Ph.D. Research Question: Can globalisation be seen as positive or negative for the Economic Development of Nigeria? A focus on Shell and the International Monetary Fund Research Issue: Globalisation in its cu...

  1. IMF By associated interhemispheric asymmetries in ionospheric convection and field-aligned currents

    Science.gov (United States)

    Kunduri, B.; Baker, J.; Ruohoniemi, J. M.; Clausen, L.; Ribeiro, A.

    2012-12-01

    The solar wind-magnetosphere interaction plays an important role in controlling the dynamics of ionospheric convection. It is widely known that the By component of IMF generates asymmetries in ionospheric convection between the northern and southern polar caps. Some studies show that IMF By-generated electric field penetrates into the closed magnetosphere producing differences in the high latitude ionospheric convection between hemispheres. The differences in convection were attributed to field-aligned potential drop between hemispheres resulting in flow of interhemispheric field aligned currents. In the current paper we present interhemispheric observations of high latitude ionospheric convection on closed field lines in the noon-dusk sector. The observations reveal that the convection is stronger in the northern (southern) hemisphere when IMF By is positive (negative) irrespective of season. The inter-hemispheric differences can be attributed to the flow of interhemispheric field aligned currents which support the existence of oppositely-directed zonal plasma flows in the closed field line regions, suppressing the convection in one hemisphere and aiding it in the other. We estimate the strength of these currents, analyze their characteristics and identify the various factors such as magnetic local time, magnetic latitude and ionospheric conductivity that impact them.

  2. Optimum IMFs Selection Based Envelope Analysis of Bearing Fault Diagnosis in Plunger Pump

    Directory of Open Access Journals (Sweden)

    Wenliao Du

    2016-01-01

    Full Text Available As the plunger pump always works in a complicated environment and the hydraulic cycle has an intrinsic fluid-structure interaction character, the fault information is submerged in the noise and the disturbance impact signals. For the fault diagnosis of the bearings in plunger pump, an optimum intrinsic mode functions (IMFs selection based envelope analysis was proposed. Firstly, the Wigner-Ville distribution was calculated for the acquired vibration signals, and the resonance frequency brought on by fault was obtained. Secondly, the empirical mode decomposition (EMD was employed for the vibration signal, and the optimum IMFs and the filter bandwidth were selected according to the Wigner-Ville distribution. Finally, the envelope analysis was utilized for the selected IMFs filtered by the band pass filter, and the fault type was recognized by compared with the bearing character frequencies. For the two modes, inner race fault and compound fault in the inner race and roller of rolling element bearing in plunger pump, the experiments show that a promising result is achieved.

  3. Influence of the solar wind and IMF on Jupiter's magnetosphere: Results from global MHD simulations

    Science.gov (United States)

    Sarkango, Y.; Jia, X.; Toth, G.; Hansen, K. C.

    2017-12-01

    Due to its large size, rapid rotation and presence of substantial internal plasma sources, Jupiter's magnetosphere is fundamentally different from that of the Earth. How and to what extent do the external factors, such as the solar wind and interplanetary magnetic field (IMF), influence the internally-driven magnetosphere is an open question. In this work, we solve the 3D semi-relativistic magnetohydrodynamic (MHD) equations using a well-established code, BATSRUS, to model the Jovian magnetosphere and study its interaction with the solar wind. Our global model adopts a non-uniform mesh covering the region from 200 RJ upstream to 1800 RJ downstream with the inner boundary placed at a radial distance of 2.5 RJ. The Io plasma torus centered around 6 RJ is generated in our model through appropriate mass-loading terms added to the set of MHD equations. We perform systematic numerical experiments in which we vary the upstream solar wind properties to investigate the impact of solar wind events, such as interplanetary shock and IMF rotation, on the global magnetosphere. From our simulations, we extract the location of the magnetopause boundary, the bow shock and the open-closed field line boundary (OCB), and determine their dependence on the solar wind properties and the IMF orientation. For validation, we compare our simulation results, such as density, temperature and magnetic field, to published empirical models based on in-situ measurements.

  4. Simulated orbits of heavy planetary ions at Mars for different IMF configurations

    Science.gov (United States)

    Curry, Shannon; Luhmann, Janet; Livi, Roberto; Hara, Takuya; Dong, Chuanfei; Ma, Yingjuan; McFadden, James; Bougher, Stephen

    2014-11-01

    We present simulated detections of O+, O2+ and CO2+ ions at Mars along a virtual orbit in the Mars space environment. Planetary pick-up ions are formed through the direct interaction of the solar wind with the neutral upper atmosphere, causing the newly created ions to be picked up and accelerated by the background convective electric field. Because previous missions such as Mars Global Surveyor (MGS) and Mars Express (MEX) have not been able to measure the interplanetary magnetic field (IMF) components simultaneously with plasma measurements, the response of heavy planetary pick-up ions to changes in the IMF has not been well characterized. Using a steady-state multi-species MHD model to provide the background electric and magnetic fields, the Mars Test Particle (MTP) simulation can trace each of these particles along field lines in near-Mars space and construct virtual ion detections from a spacecraft orbit. Specifically, we will present energy-time spectrograms and velocity space distributions (VSDs) for a selection of orbits during different IMF configurations and solar cycle conditions. These simulated orbits have broader implications for how to measure ion escape. Using individual particle traces, the origin and trajectories of different ion populations can be analyzed in order to assess how and where they contribute to the total atmospheric escape rate, which is a major objective of the upcoming MAVEN mission.

  5. On the Effect of IMF Turning on Ion Dynamics at Mercury

    Science.gov (United States)

    Delcourt, D. C.; Moore, T. E.; Fok, M.-C. H.

    2011-01-01

    We investigate the effect of a rotation of the Interplanetary Magnetic Field (IMF) on the transport of magnetospheric ion populations at Mercury. We focus on ions of planetary origin and investigate their large-scale circulation using three-dimensional single-particle simulations. We show that a nonzero Bx component of the IMF leads to a pronounced asymmetry in the overall circulation pattern . In particular, we demonstrate that the centrifugal acceleration due to curvature of the E x B drift paths is more pronounced in one hemisphere than the other, leading to filling of the magnetospheric lobes and plasma sheet with more or less energetic material depending upon the hemisphere of origin. Using a time-varying electric and magnetic field model, we investigate the response of ions to rapid (a few tens of seconds) re-orientation of the IMF. We show that, for ions with gyroperiods comparable to the field variation time scale, the inductive electric field should lead to significant nonadiabatic energization, up to several hundreds of eVs or a few keVs. It thus appears that IMP turning at Mercury should lead to localized loading of the magnetosphere with energetic material of planetary origin (e.g., Na+).

  6. A Fault Diagnosis Approach for Gears Based on IMF AR Model and SVM

    Directory of Open Access Journals (Sweden)

    Yu Yang

    2008-05-01

    Full Text Available An accurate autoregressive (AR model can reflect the characteristics of a dynamic system based on which the fault feature of gear vibration signal can be extracted without constructing mathematical model and studying the fault mechanism of gear vibration system, which are experienced by the time-frequency analysis methods. However, AR model can only be applied to stationary signals, while the gear fault vibration signals usually present nonstationary characteristics. Therefore, empirical mode decomposition (EMD, which can decompose the vibration signal into a finite number of intrinsic mode functions (IMFs, is introduced into feature extraction of gear vibration signals as a preprocessor before AR models are generated. On the other hand, by targeting the difficulties of obtaining sufficient fault samples in practice, support vector machine (SVM is introduced into gear fault pattern recognition. In the proposed method in this paper, firstly, vibration signals are decomposed into a finite number of intrinsic mode functions, then the AR model of each IMF component is established; finally, the corresponding autoregressive parameters and the variance of remnant are regarded as the fault characteristic vectors and used as input parameters of SVM classifier to classify the working condition of gears. The experimental analysis results show that the proposed approach, in which IMF AR model and SVM are combined, can identify working condition of gears with a success rate of 100% even in the case of smaller number of samples.

  7. Kerr geometry in f(T) gravity

    Energy Technology Data Exchange (ETDEWEB)

    Bejarano, Cecilia; Guzman, Maria Jose [Instituto de Astronomia y Fisica del Espacio (IAFE, CONICET-UBA), Buenos Aires (Argentina); Ferraro, Rafael [Instituto de Astronomia y Fisica del Espacio (IAFE, CONICET-UBA), Buenos Aires (Argentina); Universidad de Buenos Aires, Departamento de Fisica, Facultad de Ciencias Exactas y Naturales, Buenos Aires (Argentina)

    2015-02-01

    Null tetrads are shown to be a valuable tool in teleparallel theories of modified gravity. We use them to prove that Kerr geometry remains a solution for a wide family of f(T) theories of gravity. (orig.)

  8. Kerr geometry in f(T) gravity

    International Nuclear Information System (INIS)

    Bejarano, Cecilia; Guzman, Maria Jose; Ferraro, Rafael

    2015-01-01

    Null tetrads are shown to be a valuable tool in teleparallel theories of modified gravity. We use them to prove that Kerr geometry remains a solution for a wide family of f(T) theories of gravity. (orig.)

  9. IMF soovitab uue töölepinguseaduse kiiresti vastu võtta / Peep Lillemägi

    Index Scriptorium Estoniae

    Lillemägi, Peep, 1967-

    2008-01-01

    Ilmunud ka: Tallinnskii Vestnik juuli 2008, lk. 3. Eestis viibinud IMF-i delegatsiooni hinnangul sõltub Eesti majanduskasvu taastumine suurel määral majanduse konkurentsivõimest, delegatsioon toetab kavatsust leida edasisi võimalusi kokkuhoiuks ning soovitab töölepinguseaduse eelnõu kiiresti vastu võtta ja ellu viia. Rahandusminister Ivari Padari arvamus IMF-i hinnangute kohta

  10. Sandia SWiFT Wind Turbine Manual.

    Energy Technology Data Exchange (ETDEWEB)

    White, Jonathan; LeBlanc, Bruce Philip; Berg, Jonathan Charles; Bryant, Joshua; Johnson, Wesley D.; Paquette, Joshua

    2016-01-01

    The Scaled Wind Farm Technology (SWiFT) facility, operated by Sandia National Laboratories for the U.S. Department of Energy's Wind and Water Power Program, is a wind energy research site with multiple wind turbines scaled for the experimental study of wake dynamics, advanced rotor development, turbine control, and advanced sensing for production-scale wind farms. The SWiFT site currently includes three variable-speed, pitch-regulated, three-bladed wind turbines. The six volumes of this manual provide a detailed description of the SWiFT wind turbines, including their operation and user interfaces, electrical and mechanical systems, assembly and commissioning procedures, and safety systems. Further dissemination only as authorized to U.S. Government agencies and their contractors; other requests shall be approved by the originating facility or higher DOE programmatic authority. 111 UNCLASSIFIED UNLIMITED RELEASE Sandia SWiFT Wind Turbine Manual (SAND2016-0746 ) approved by: Department Manager SWiFT Site Lead Dave Minster (6121) Date Jonathan White (6121) Date SWiFT Site Supervisor Dave Mitchell (6121) Date Note: Document revision logs are found after the title page of each volume of this manual. iv

  11. Randomised Comparison of the AMBU AuraOnce Laryngeal Mask and the LMA Unique Laryngeal Mask Airway in Spontaneously Breathing Adults

    OpenAIRE

    Williams, Daryl Lindsay; Zeng, James M.; Alexander, Karl D.; Andrews, David T.

    2012-01-01

    We conducted a randomised single-blind controlled trial comparing the LMA-Unique (LMAU) and the AMBU AuraOnce (AMBU) disposable laryngeal mask in spontaneously breathing adult patients undergoing general anaesthesia. Eighty-two adult patients (ASA status I–IV) were randomly allocated to receive the LMAU or AMBU and were blinded to device selection. Patients received a standardized anesthetic and all airway devices were inserted by trained anaesthetists. Size selection was guided by manufactur...

  12. M*/L gradients driven by IMF variation: large impact on dynamical stellar mass estimates

    Science.gov (United States)

    Bernardi, M.; Sheth, R. K.; Dominguez-Sanchez, H.; Fischer, J.-L.; Chae, K.-H.; Huertas-Company, M.; Shankar, F.

    2018-06-01

    Within a galaxy the stellar mass-to-light ratio ϒ* is not constant. Recent studies of spatially resolved kinematics of nearby early-type galaxies suggest that allowing for a variable initial mass function (IMF) returns significantly larger ϒ* gradients than if the IMF is held fixed. We show that ignoring such IMF-driven ϒ* gradients can have dramatic effect on dynamical (M_*^dyn), though stellar population (M_*^SP) based estimates of early-type galaxy stellar masses are also affected. This is because M_*^dyn is usually calibrated using the velocity dispersion measured in the central regions (e.g. Re/8) where stars are expected to dominate the mass (i.e. the dark matter fraction is small). On the other hand, M_*^SP is often computed from larger apertures (e.g. using a mean ϒ* estimated from colours). If ϒ* is greater in the central regions, then ignoring the gradient can overestimate M_*^dyn by as much as a factor of two for the most massive galaxies. Large ϒ*-gradients have four main consequences: First, M_*^dyn cannot be estimated independently of stellar population synthesis models. Secondly, if there is a lower limit to ϒ* and gradients are unknown, then requiring M_*^dyn=M_*^SP constrains them. Thirdly, if gradients are stronger in more massive galaxies, then accounting for this reduces the slope of the correlation between M_*^dyn/M_*^SP of a galaxy with its velocity dispersion. In particular, IMF-driven gradients bring M_*^dyn and M_*^SP into agreement, not by shifting M_*^SP upwards by invoking constant bottom-heavy IMFs, as advocated by a number of recent studies, but by revising M_*^dyn estimates in the literature downwards. Fourthly, accounting for ϒ* gradients changes the high-mass slope of the stellar mass function φ (M_*^dyn), and reduces the associated stellar mass density. These conclusions potentially impact estimates of the need for feedback and adiabatic contraction, so our results highlight the importance of measuring ϒ* gradients in

  13. Polar cap ion beams during periods of northward IMF: Cluster statistical results

    Directory of Open Access Journals (Sweden)

    R. Maggiolo

    2011-05-01

    Full Text Available Above the polar caps and during prolonged periods of northward IMF, the Cluster satellites detect upward accelerated ion beams with energies up to a few keV. They are associated with converging electric field structures indicating that the acceleration is caused by a quasi-static field-aligned electric field that can extend to altitudes higher than 7 RE (Maggiolo et al., 2006; Teste et al., 2007. Using the AMDA science analysis service provided by the Centre de Données de la Physique des Plasmas, we have been able to extract about 200 events of accelerated upgoing ion beams above the polar caps from the Cluster database. Most of these observations are taken at altitudes lower than 7 RE and in the Northern Hemisphere. We investigate the statistical properties of these ion beams. We analyze their geometry, the properties of the plasma populations and of the electric field inside and around the beams, as well as their dependence on solar wind and IMF conditions. We show that ~40 % of the ion beams are collocated with a relatively hot and isotropic plasma population. The density and temperature of the isotropic population are highly variable but suggest that this plasma originates from the plasma sheet. The ion beam properties do not change significantly when the isotropic, hot background population is present. Furthermore, during one single polar cap crossing by Cluster it is possible to detect upgoing ion beams both with and without an accompanying isotropic component. The analysis of the variation of the IMF BZ component prior to the detection of the beams indicates that the delay between a northward/southward turning of IMF and the appearance/disappearance of the beams is respectively ~2 h and 20 min. The observed electrodynamic characteristics of high altitude polar cap ion beams suggest that they are closely connected to polar cap auroral arcs. We discuss the implications of these Cluster observations above the polar cap on the magnetospheric

  14. Response of the auroral electrojet indices to abrupt southward IMF turnings

    Science.gov (United States)

    Gjerloev, J. W.; Hoffman, R. A.; Ohtani, S.; Weygand, J.; Barnes, R.

    2010-05-01

    We present results from a study of the behavior of the auroral electrojet indices following abrupt southward turnings of the IMF Bz. The auroral electrojet indices are calculated from observations made by more than 100 ground based stations provided by the SuperMAG collaborators. Based on three simple criteria we selected 73 events. In each event the interval of analysis started at the time of the IMF Bz southward turning and ended 45 minutes later or at the onset of any abrupt energy unloading event in the magnetosphere, regardless of size. We refer to this period as the "pre-unloading phase". To isolate the dependence of the auroral electrojets on the solar induced ionospheric conductivity during this phase we separated the standard AU/AL indices into two new sets of indices defined by the upper and lower envelope of the north-south component for all sunlit stations (AUs/ALs) and for all stations in darkness (AUd/ALd). Based on events and statistical analyses we can conclude that following a southward turning of the IMF Bz the AUd/ALd indices show no measurable response while the AUs/ALs indices clearly intensify. The intensifications of AUs/ALs are dependent on the intensity of the solar wind driver (as measured by IMF Bz or the Akasofu ɛ parameter). The lack of AUd/ALd response does not depend on the intensity of any subsequent substorm. We find that during these isolated events the ionospheric current system is primarily confined to the sunlit ionosphere. This truncated version of the classical global DP-2 current system suggests that auroral electrojet continuity is not maintained across the terminator. Because of its conductivity dependence on the solar zenith angle, this truncated global current pattern is expected to be highly dependent on UT and season and thus can be asymmetric between hemispheres. Thus we argue that the global two-cell DP-2 current system is not a consequence only of a southward turning of the IMF but requires also the reduction of the

  15. High-time resolution conjugate SuperDARN radar observations of the dayside convection response to changes in IMF By

    Directory of Open Access Journals (Sweden)

    G. Chisham

    2000-02-01

    Full Text Available We present data from conjugate SuperDARN radars describing the high-latitude ionosphere's response to changes in the direction of IMF By during a period of steady IMF Bz southward and Bx positive. During this interval, the radars were operating in a special mode which gave high-time resolution data (30 s sampling period on three adjacent beams with a full scan every 3 min. The location of the radars around magnetic local noon at the time of the event allowed detailed observations of the variations in the ionospheric convection patterns close to the cusp region as IMF By varied. A significant time delay was observed in the ionospheric response to the IMF By changes between the two hemispheres. This is explained as being partially a consequence of the location of the dominant merging region on the magnetopause, which is ~8-12RE closer to the northern ionosphere than to the southern ionosphere (along the magnetic field line due to the dipole tilt of the magnetosphere and the orientation of the IMF. This interpretation supports the anti-parallel merging hypothesis and highlights the importance of the IMF Bx component in solar wind-magnetosphere coupling.Key words: Ionosphere (plasma convection - Magnetospheric physics (magnetopause, cusp, and boundary layers; solar wind - magnetosphere interactions

  16. The impact of IMF conditionality on government health expenditure: A cross-national analysis of 16 West African nations.

    Science.gov (United States)

    Stubbs, Thomas; Kentikelenis, Alexander; Stuckler, David; McKee, Martin; King, Lawrence

    2017-02-01

    How do International Monetary Fund (IMF) policy reforms-so-called 'conditionalities'-affect government health expenditures? We collected archival documents on IMF programmes from 1995 to 2014 to identify the pathways and impact of conditionality on government health spending in 16 West African countries. Based on a qualitative analysis of the data, we find that IMF policy reforms reduce fiscal space for investment in health, limit staff expansion of doctors and nurses, and lead to budget execution challenges in health systems. Further, we use cross-national fixed effects models to evaluate the relationship between IMF-mandated policy reforms and government health spending, adjusting for confounding economic and demographic factors and for selection bias. Each additional binding IMF policy reform reduces government health expenditure per capita by 0.248 percent (95% CI -0.435 to -0.060). Overall, our findings suggest that IMF conditionality impedes progress toward the attainment of universal health coverage. Copyright © 2016 Elsevier Ltd. All rights reserved.

  17. DFT, FT-IR, FT-Raman and vibrational studies of 3-methoxyphenyl boronic acid

    Science.gov (United States)

    Patil, N. R.; Hiremath, Sudhir M.; Hiremath, C. S.

    2018-05-01

    The aim of this work is to study the possible stable, geometrical molecular structure, experimental and theoretical FT-IR and FT-Raman spectroscopic methods of 3-Methoxyphenyl boronic acid (3MPBA). FT-IR and FT-Raman spectra were recorded in the region of 4000-400 cm-1 and 40000-50 cm-1 respectively. The optimized geometric structure and vibrational wavenumbers of the title compound were searched by B3LYP hybrid density functional theory method with 6-311++G (d, p) basis set. The Selectedexperimentalbandswereassignedandcharacterizedonthebasisofthescaledtheoreticalwavenumbersby their potential energy distribution (PED) of the vibrational modes obtained from VEDA 4 program. Finally, the predicted calculation results were applied to simulated FT-IR and FT-Raman spectra of the title compound, which show agreement with the observed spectra. Whereas, it is observed that, the theoretical frequencies are more than the experimental one for O-H stretching vibration modes of the title molecule.

  18. Analysis of Wind Vorticity and Divergence in the High-latitude Lower Thermosphere: Dependence on the Interplanetary Magnetic Field (IMF

    Directory of Open Access Journals (Sweden)

    Young-Sil Kwak

    2008-12-01

    Full Text Available To better understand the physical processes that control the high-latitude lower thermospheric dynamics, we analyze the divergence and vorticity of the high-latitude neutral wind field in the lower thermosphere during the southern summertime for different IMF conditions. For this study the National Center for Atmospheric Research Thermosphere-Ionosphere Electrodynamics General Circulation Model (NCAR-TIEG CM is used. The analysis of the large-scale vorticity and divergence provides basic understanding flow configurations to help elucidate the momentum sources that ultimately determine the total wind field in the lower polar thermosphere and provides insight into the relative strengths of the different sources of momentum responsible for driving winds. The mean neutral wind pattern in the high-latitude lower thermosphere is dominated by rotational flow, imparted primarily through the ion drag force, rather than by divergent flow, imparted primarily through Joule and solar heating. The difference vorticity, obtained by subtracting values with zero IMF from those with non-zero IMF, in the high-latitude lower thermosphere is much larger than the difference divergence for all IMF conditions, indicating that a larger response of the thermospheric wind system to enhancement in the momentum input generating the rotational motion with elevated IMF than the corresponding energy input generating the divergent motion. the difference vorticity in the high-latitude lower thermosphere depends on the direction of the IMF. The difference vorticity for negative and positive B_y shows positive and negative, respectively, at higher magnetic latitudes than -70°. For negative B_z, the difference vorticities have positive in the dusk sector and negative in the dawn sector. The difference vorticities for positive B_z have opposite sign. Negative IMF B_z has a stronger effect on the vorticity than does positive B_z.

  19. Testing the Universality of the Stellar IMF with Chandra and HST

    OpenAIRE

    Coulter, D. A.; Lehmer, B. D.; Eufrasio, R. T.; Kundu, A.; Maccarone, T.; Peacock, M.; Hornschemeier, A. E.; Basu-Zych, A.; Gonzalez, A. H.; Maraston, C.; Zepf, S. E.

    2016-01-01

    The stellar initial mass function (IMF), which is often assumed to be universal across unresolved stellar populations, has recently been suggested to be "bottom-heavy" for massive ellipticals. In these galaxies, the prevalence of gravity-sensitive absorption lines (e.g. Na I and Ca II) in their near-IR spectra implies an excess of low-mass ($m = 8$ $M_\\odot$) would lead to a corresponding deficit of neutron stars and black holes, and therefore of low-mass X-ray binaries (LMXBs), per unit near...

  20. Ionospheric flow during extended intervals of northward but By -dominated IMF

    Directory of Open Access Journals (Sweden)

    J. B. Sigwarth

    Full Text Available We present SuperDARN radar observations of the nightside high-latitude ionospheric flow during two 6-hour intervals of quasi-steady northward interplanetary magnetic field (IMF. During both intervals (01:30–07:30 UT on 2 December and 21:00–03:00 UT on 14/15 December 1999, the solar wind and IMF remained relatively steady with Bz positive and By negative, such that the IMF clock angle was ~ - 50° to - 60°. Throughout both intervals the radar data clearly indicate the presence of a highly distorted By-dominated twin cell flow pattern, indicative of an open magnetosphere, which is confirmed by DMSP and auroral data. Estimates of the changes in open flux present during each interval indicate approximately balanced dayside and nightside reconnection at rates of ~ 30–35 kV over the full 6 h. However, strong bursts of flow with speeds of over ~ 1000 ms-1 are observed near magnetic midnight on time scales of ~ 1 h, which are associated with increases in the transpolar voltage. These are indicative of the net closure of open flux by recon-nection in the tail. During one large flow burst, the night-side reconnection rate is estimated to have been ~ 1.5 times the dayside rate, i.e. ~ 45–60 kV compared with ~ 30–40 kV. Magnetic bays, which would indicate the formation of a sub-storm current wedge, are not observed in association with these bursts. In addition, no low-latitude Pi2s or geostationary particle injections were observed, although some local, small amplitude Pi2-band (5–50 mHz activity does accompany the bursts. Coincident measurements of the flow and of the low amplitude magnetic perturbations reveal nightside ionospheric conductances of no more than a few mho, indicative of little associated precipitation. Therefore, we suggest that the flow bursts are the ionospheric manifestation of bursty reconnection events occurring in the more distant geomagnetic tail. The main implication of these findings is that, under the circumstances

  1. THE STELLAR INITIAL MASS FUNCTION OF ULTRA-FAINT DWARF GALAXIES: EVIDENCE FOR IMF VARIATIONS WITH GALACTIC ENVIRONMENT

    Energy Technology Data Exchange (ETDEWEB)

    Geha, Marla [Astronomy Department, Yale University, New Haven, CT 06520 (United States); Brown, Thomas M.; Tumlinson, Jason; Kalirai, Jason S.; Avila, Roberto J.; Ferguson, Henry C. [Space Telescope Science Institute, 3700 San Martin Drive, Baltimore, MD 21218 (United States); Simon, Joshua D. [Observatories of the Carnegie Institution of Washington, 813 Santa Barbara Street, Pasadena, CA 91101 (United States); Kirby, Evan N. [Department of Physics and Astronomy, University of California Irvine, 4129 Frederick Reines Hall, Irvine, CA 92697 (United States); VandenBerg, Don A. [Department of Physics and Astronomy, University of Victoria, P.O. Box 3055, Victoria, BC V8W 3P6 (Canada); Munoz, Ricardo R. [Departamento de Astronomia, Universidad de Chile, Casilla 36-D, Santiago (Chile); Guhathakurta, Puragra, E-mail: marla.geha@yale.edu, E-mail: tbrown@stsci.edu, E-mail: tumlinson@stsci.edu [UCO/Lick Observatory and Department of Astronomy and Astrophysics, University of California, Santa Cruz, CA 95064 (United States)

    2013-07-01

    We present constraints on the stellar initial mass function (IMF) in two ultra-faint dwarf (UFD) galaxies, Hercules and Leo IV, based on deep Hubble Space Telescope Advanced Camera for Surveys imaging. The Hercules and Leo IV galaxies are extremely low luminosity (M{sub V} = -6.2, -5.5), metal-poor (([Fe/H]) = -2.4, -2.5) systems that have old stellar populations (>11 Gyr). Because they have long relaxation times, we can directly measure the low-mass stellar IMF by counting stars below the main-sequence turnoff without correcting for dynamical evolution. Over the stellar mass range probed by our data, 0.52-0.77 M{sub Sun }, the IMF is best fit by a power-law slope of {alpha}= 1.2{sub -0.5}{sup +0.4} for Hercules and {alpha} = 1.3 {+-} 0.8 for Leo IV. For Hercules, the IMF slope is more shallow than a Salpeter ({alpha} = 2.35) IMF at the 5.8{sigma} level, and a Kroupa ({alpha} = 2.3 above 0.5 M{sub Sun }) IMF slope at 5.4{sigma} level. We simultaneously fit for the binary fraction, f{sub binary}, finding f{sub binary}= 0.47{sup +0.16}{sub -0.14} for Hercules, and 0.47{sup +0.37}{sub -0.17} for Leo IV. The UFD binary fractions are consistent with that inferred for Milky Way stars in the same mass range, despite very different metallicities. In contrast, the IMF slopes in the UFDs are shallower than other galactic environments. In the mass range 0.5-0.8 M{sub Sun }, we see a trend across the handful of galaxies with directly measured IMFs such that the power-law slopes become shallower (more bottom-light) with decreasing galactic velocity dispersion and metallicity. This trend is qualitatively consistent with results in elliptical galaxies inferred via indirect methods and is direct evidence for IMF variations with galactic environment.

  2. IMF dependence of Saturn's auroras: modelling study of HST and Cassini data from 12–15 February 2008

    Directory of Open Access Journals (Sweden)

    E. S. Belenkaya

    2010-08-01

    Full Text Available To gain better understanding of auroral processes in Saturn's magnetosphere, we compare ultraviolet (UV auroral images obtained by the Hubble Space Telescope (HST with the position of the open-closed field line boundary in the ionosphere calculated using a magnetic field model that employs Cassini measurements of the interplanetary magnetic field (IMF as input. Following earlier related studies of pre-orbit insertion data from January 2004 when Cassini was located ~ 1300 Saturn radii away from the planet, here we investigate the interval 12–15 February 2008, when UV images of Saturn's southern dayside aurora were obtained by the HST while the Cassini spacecraft measured the IMF in the solar wind just upstream of the dayside bow shock. This configuration thus provides an opportunity, unique to date, to determine the IMF impinging on Saturn's magnetosphere during imaging observations, without the need to take account of extended and uncertain interplanetary propagation delays. The paraboloid model of Saturn's magnetosphere is then employed to calculate the magnetospheric magnetic field structure and ionospheric open-closed field line boundary for averaged IMF vectors that correspond, with appropriate response delays, to four HST images. We show that the IMF-dependent open field region calculated from the model agrees reasonably well with the area lying poleward of the UV emissions, thus supporting the view that the poleward boundary of Saturn's auroral oval in the dayside ionosphere lies adjacent to the open-closed field line boundary.

  3. La riforma del FMI: alcune questioni organizzatIve e operative (Reforming the IMF: Some Organizational and Operational Issues. With English summary

    Directory of Open Access Journals (Sweden)

    Hossein Askari

    2012-10-01

    Full Text Available While financial crises during the 1990s have started a lively debate on IMF policies toward member countries, reform of the Fund's organizational structure and operations have been largely ignored. Improved organization and operations would increase IMF efficiency and membership participation, which would in turn increase IMF effectiveness in enhancing global economic conditions. In this paper, a number of such issues--quotas, voting structure and decision making; executive board and ministerial committees; management structure and staff; political dimensions, transparency and credibility--are assessed.  JEL Codes: F33Keywords: IMF

  4. Biochemical applications of FT-IR spectroscopy

    NARCIS (Netherlands)

    Pistorius, A.M.A.

    1996-01-01

    This thesis describes the use of (FT-)IR spectroscopy in general biochemical research. In chapter 3, IR spectroscopy is used in the quantitation of residual detergent after reconstitution of an integral membrane protein in a pre-defined lipid matrix. This chapter discusses the choice of the

  5. Quantitative gas analysis with FT-IR

    DEFF Research Database (Denmark)

    Bak, J.; Larsen, A.

    1995-01-01

    Calibration spectra of CO in the 2.38-5100 ppm concentration range (22 spectra) have been measured with a spectral resolution of 4 cm(-1), in the mid-IR (2186-2001 cm(-1)) region, with a Fourier transform infrared (FT-IR) instrument. The multivariate calibration method partial least-squares (PLS1...

  6. FT 3 Flight Test Cards for Export

    Science.gov (United States)

    Marston, Michael L.

    2015-01-01

    These flight test cards will be made available to stakeholders who participated in FT3. NASA entered into the relationship with our stakeholders, including the FAA, to develop requirements that will lead to routine flights of unmanned aircraft systems flying in the national airspace system.

  7. Escape of high-energy oxygen ions through magnetopause reconnection under northward IMF

    Directory of Open Access Journals (Sweden)

    S. Kasahara

    2008-12-01

    Full Text Available During a storm recovery phase on 15 May 2005, the Geotail spacecraft repeatedly observed high-energy (>180 keV oxygen ions in the dayside magnetosheath near the equatorial plane. We focused on the time period from 11:20 UT to 13:00 UT, when Geotail observed the oxygen ions and the interplanetary magnetic field (IMF was constantly northward. The magnetic reconnection occurrence northward and duskward of Geotail is indicated by the Walén analysis and convective flows in the magnetopause boundary layer. Anisotropic pitch angle distributions of ions suggest that high-energy oxygen ions escaped from the northward of Geotail along the reconnected magnetic field lines. From the low-energy particle precipitation in the polar cap observed by DMSP, which is consistent with magnetic reconnection occurring between the magnetosheath field lines and the magnetospheric closed field lines, we conclude that these oxygen ions are of ring current origin. Our results thus suggest a new escape route of oxygen ions during northward IMF. In the present event, this escape mechanism is more dominant than the leakage via the finite Larmor radius effect across the dayside equatorial magnetopause.

  8. A discussion paper for emerging markets: The role of IMF and the World Bank

    Directory of Open Access Journals (Sweden)

    Edmundo R. Lizarzaburu

    2012-09-01

    Full Text Available While both the World Bank and International Monetary Fund, are two separate entities, often not clear the role of each of them is therefore that this paper seeks to consolidate diverse information reviewed from both entities with the purpose of being able to understand the functioning and scope of each of these important institutions that have had successes and setbacks and ultimately have an active role in global finance and economy, despite the many detractors who are at levels world. There is an anecdote which is worth mentioning. “John Maynard Keynes, recognized at the inaugural meeting of the International Monetary Fund was confused by the names he thought the Fund should be called a bank, and the World Bank should be called a bottom. Confusion has reigned ever since. The Bank and the IMF are two intergovernmental pillars supporting the structure of economic and financial world”. The fundamental difference between the two is understood as: the Bank institution primarily for the development, while the IMF is a cooperative institution that seeks to maintain an orderly system of payments and receipts between nations. The manner followed to choose the head of each organization has a different procedure, but the important thing is that in the next few years, several countries such as Brazil, India have more active participation and Latin America as a group may perhaps lead some of them.

  9. Orientation of Birkeland current sheets in the dayside polar region and its relationship to the IMF

    International Nuclear Information System (INIS)

    Saflekos, N.A.; Potemra, T.A.

    1980-01-01

    Vector magnetic field observations made with the three-axes magnetometer on the Triad satellite have been used to study the orientation of magnetic disturbances in the dayside polar region. These measurements were all made over the southern polar region and recorded at McMurdo, Antarctica. These disturbances are transverse to the main geomagnetic field and may be interpreted as being caused by field-aligned Birkeland current sheets consistent with Maxwell's equations. The current sheets in the regions usually associated with the morning and afternoon auroral regions are most often aligned in the geomagnetic east-west direction. The amplitudes of these 'south auroral' currents are larger in the morning than in the afternoon when the interplanetary magnetic field (IMF) is directed toward the sun (B/sub y/ 0) and larger in the afternoon when the IMF is directed away (B/sub y/>0, B/sub x/ 0 the Birkeland current flow in the region of the southern cusp is predominantly away from the ionosphere in contrast to the downward flow into the northern cusp as determined earlier (e.g., McDiarmid et al., 1978b; Iijima et al., 1978). The cusp Birkeland current flow directions appear to reverse for B/sub y/>0 and B/sub x/<0. From a search of the Triad data set, some rare examples of magnetic disturbances with a large north-south (noon-midnight) component have been discovered in the polar cap near noon

  10. Test-particle simulations of SEP propagation in IMF with large-scale fluctuations

    Science.gov (United States)

    Kelly, J.; Dalla, S.; Laitinen, T.

    2012-11-01

    The results of full-orbit test-particle simulations of SEPs propagating through an IMF which exhibits large-scale fluctuations are presented. A variety of propagation conditions are simulated - scatter-free, and scattering with mean free path, λ, of 0.3 and 2.0 AU - and the cross-field transport of SEPs is investigated. When calculating cross-field displacements the Parker spiral geometry is accounted for and the role of magnetic field expansion is taken into account. It is found that transport across the magnetic field is enhanced in the λ =0.3 AU and λ =2 AU cases, compared to the scatter-free case, with the λ =2 AU case in particular containing outlying particles that had strayed a large distance across the IMF. Outliers are catergorized by means of Chauvenet's criterion and it is found that typically between 1 and 2% of the population falls within this category. The ratio of latitudinal to longitudinal diffusion coefficient perpendicular to the magnetic field is typically 0.2, suggesting that transport in latitude is less efficient.

  11. Concentration Limits in the Cement Based Swiss Repository for Long-lived, Intermediate-level Radioactive Wastes (LMA)

    International Nuclear Information System (INIS)

    Berner, Urs

    1999-12-01

    The Swiss repository concept for long-lived, intermediate-level radioactive wastes (LMA), in Swiss terminology) foresees cylindrical concrete silos surrounded by a ring of granulated bentonite to deposit the waste. As one of the possible options and similar to the repository for high level wastes, the silos will be located in a deep crystalline host rock. Solidified with concrete in steel drums, the waste is stacked into a silo and the silo is then backfilled with a porous mortar. To characterize the release of radionuclides from the repository, the safety assessment considers first the dissolution into the pore water of the concrete, and then diffusion through the outer bentonite ring into the deep crystalline groundwater. For 19 safety relevant radionuclides (isotopes of U, Th, Pa, Np, Pu, Am, Ni, Zr, Mo, Nb, Se, Sr, Ra, Tc, Sn, I, C, Cs, Cl) the report recommends maximum elemental concentrations to be expected in the cement pore water of the particularly considered repository. These limits will form the parameter base for subsequent release model chains. Concentration limits in a geochemical environment are usually obtained from thermodynamic equilibrium calculations performed with geochemical speciation codes. However, earlier studies revealed that this procedure does not always lead to reliable results. Main reasons for this are the complexity of the systems considered, as well as the lacking completeness of, and the uncertainty associated with the thermodynamic data. To improve the recommended maximum concentrations for a distinct repository design, this work includes additional design- and system-dependent criteria. The following processes, inventories and properties are considered in particular: a) recent experimental investigations, particularly from cement systems, b) thermodynamic model calculations when reliable data are available, c) total inventories of radionuclides, d) sorption- and co-precipitation processes, e) dilution with stable isotopes, f

  12. Effect of Pneumoperitoneum and Lateral Position on Oropharyngeal Seal Pressures of Proseal LMA in Laparoscopic Urological Procedures.

    Science.gov (United States)

    Rustagi, Preeti; Patkar, Geeta A; Ourasang, Anil Kumar; Tendolkar, Bharati A

    2017-02-01

    A sustained and effective oropharyngeal sealing with supraglottic airway is required to maintain the ventilation during laparoscopic surgery. Previous studies have observed the Oropharyngeal Seal Pressure (OSP) for Proseal Laryngeal Mask Airway (PLMA) after pneumoperitoneum in supine and trendelenburg position, where PLMA was found to be an effective airway device. This study was conducted with ProSeal LMA, for laparoscopic Urologic procedures done in lateral position. To measure OSP in supine and lateral position and to observe the effect of pneumoperitoneum in lateral position on OSP. Secondary objectives were to assess adequacy of ventilation and incidence of adverse events. A total number of 25 patients of American Society of Anaesthesiologists (ASA) physical status II and I were enrolled. After induction of anaesthesia using a standardized protocol, PLMA was inserted. Ryle's tube was inserted through drain tube. The position of PLMA was confirmed with ease of insertion of Ryle's tube and fibreoptic grading of vocal cords. Patients were then put in lateral position. The OSP was measured in supine position. This value was baseline comparison for OSP in lateral position and that after pneumoperitoneum. We assessed the efficacy of PLMA for ventilation, after carboperitoneum in lateral position (peak airway pressure, End Tidal Carbon dioxide (EtCO 2 ), SPO 2 ). Incidence of adverse effects (displacement of device, gastric insufflation, regurgitation, coughing, sore throat, blood on device, trauma) was also noted. The OSP was above Peak Airway Pressure (PAP) in supine (22.1±5.4 and 15.4±4.49cm of H 2 O) and lateral position (22.6±5.3 and 16.1±4.6). After pneumoperitoneum, which was in lateral position, there was statistically significant (p-value <0.05) increase in both PAP (19.96±4.015) and OSP (24.32±4.98, p-value 0.03). There was no intraoperative displacement of PLMA. There was no event of suboptimal oxygenation. EtCO 2 was always within normal limits

  13. Energy profile, spectroscopic (FT-IR, FT-Raman and FT-NMR) and DFT studies of 4-bromoisophthalic acid

    Science.gov (United States)

    Arjunan, V.; Thirunarayanan, S.; Mohan, S.

    2018-04-01

    The stable conformer of 4-bromoisophthalic acid (BIPA) has been identified by potential energy profile analysis. All the structural parameters of 4-bromoisophthalic acid are determined by B3LYP method with 6-311++G**, 6-31G** and cc-pVTZ basis sets. The fundamental vibrations are analysed with the use of FT-IR (4000-400 cm-1) and FT-Raman (4000-100 cm-1) spectra. The harmonic vibrational frequencies are theoretically calculated and compared with experimental FTIR and FT-Raman frequencies. The 1H and 13C NMR spectra have been analysed and compared with theoretical 1H and 13C NMR chemical shifts calculated by gauge independent atomic orbital (GIAO) method. The electronic properties, such as HOMO (highest occupied molecular orbital) and LUMO (lowest unoccupied molecular orbital) energies are determined by B3LYP/cc-pVTZ method. The electron density distribution and site of chemical reactivity of BIPA molecule have been obtained by mapping electron density isosurface with molecular electrostatic potential (MEP). Stability of the molecules arising from hyperconjugative interactions, charge delocalizations have been analysed by using natural bond orbital (NBO) analysis. The thermodynamic properties and atomic natural charges of the compound are analysed and the reactive sites of the molecule are identified. The global and local reactivity descriptors are evaluated to analyse the chemical reactivity and site selectivity of molecule through Fukui functions.

  14. SWMF simulation of field-aligned currents for a varying northward and duskward IMF with nonzero dipole tilt

    Directory of Open Access Journals (Sweden)

    H. Wang

    2008-06-01

    Full Text Available This study concentrates on the FACs distribution for the varying northward and duskward interplanetary magnetic field (IMF conditions when the dipole tilt is nonzero. A global MHD simulation (the Space Weather Modeling Framework, SWMF has been used to perform this study. Hemispheric asymmetry of the time evolution of northward IMF Bz (NBZ FACs is found. As the IMF changes from strictly northward to duskward, NBZ FACs shift counterclockwise in both summer and winter hemispheres. However, in the winter hemisphere, the counterclockwise rotation prohibits the duskward NBZ FACs from evolving into the midday R1 FACs. The midday R1 FACs seem to be an intrusion of dawnside R1 FACs. In the summer hemisphere, the NBZ FACs can evolve into the DPY FACs, consisting of the midday R0 and R1 FACs, after the counterclockwise rotation. The hemispheric asymmetry is due to the fact that the dipole tilt favors more reconnection between the IMF and the summer magnetosphere. When mapping the NBZ and DPY FACs into the magnetosphere it is found that the NBZ currents are located on both open and closed field lines, irrespective of the IMF direction. For the DPY FACs the hemispheric asymmetry emerges: the midday R1 FACs and a small part of R0 FACs are on closed field lines in the winter hemisphere, while a small part of the midday R1 FACs and all the R0 FACs are on open field lines in the summer hemisphere. Both IMF By and dipole tilt cause the polar cap hemispheric and local time asymmetric. When the IMF is northward, the summer polar cap is closed on the nightside while the winter polar cap is open. The polar cap boundary tends to move equatorward as the IMF rotates from northward to duskward, except in the summer hemisphere, the polar cap on the dawnside shifts poleward when the clock angle is less than 10°. The further poleward displacement of the polar cap boundary on one oval side is caused by the twist of the tail plasma sheet, which is in accordance with the

  15. Detection of metanil yellow contamination in turmeric using FT-Raman and FT-IR spectroscopy

    Science.gov (United States)

    Dhakal, Sagar; Chao, Kuanglin; Qin, Jianwei; Kim, Moon; Schmidt, Walter; Chan, Dian

    2016-05-01

    Turmeric is well known for its medicinal value and is often used in Asian cuisine. Economically motivated contamination of turmeric by chemicals such as metanil yellow has been repeatedly reported. Although traditional technologies can detect such contaminants in food, high operational costs and operational complexities have limited their use to the laboratory. This study used Fourier Transform Raman Spectroscopy (FT-Raman) and Fourier Transform - Infrared Spectroscopy (FT-IR) to identify metanil yellow contamination in turmeric powder. Mixtures of metanil yellow in turmeric were prepared at concentrations of 30%, 25%, 20%, 15%, 10%, 5%, 1% and 0.01% (w/w). The FT-Raman and FT-IR spectral signal of pure turmeric powder, pure metanil yellow powder and the 8 sample mixtures were obtained and analyzed independently to identify metanil yellow contamination in turmeric. The results show that FT-Raman spectroscopy and FT-IR spectroscopy can detect metanil yellow mixed with turmeric at concentrations as low as 1% and 5%, respectively, and may be useful for non-destructive detection of adulterated turmeric powder.

  16. An FT-Raman, FT-IR, and Quantum Chemical Investigation of Stanozolol and Oxandrolone

    Directory of Open Access Journals (Sweden)

    Tibebe Lemma

    2017-12-01

    Full Text Available We have studied the Fourier Transform Infrared (FT-IR and the Fourier transform Raman (FT-Raman spectra of stanozolol and oxandrolone, and we have performed quantum chemical calculations based on the density functional theory (DFT with a B3LYP/6-31G (d, p level of theory. The FT-IR and FT-Raman spectra were collected in a solid phase. The consistency between the calculated and experimental FT-IR and FT-Raman data indicates that the B3LYP/6-31G (d, p can generate reliable geometry and related properties of the title compounds. Selected experimental bands were assigned and characterized on the basis of the scaled theoretical wavenumbers by their total energy distribution. The good agreement between the experimental and theoretical spectra allowed positive assignment of the observed vibrational absorption bands. Finally, the calculation results were applied to simulate the Raman and IR spectra of the title compounds, which show agreement with the observed spectra.

  17. Energy balance in the ohmically heated FT

    International Nuclear Information System (INIS)

    Bartiromo, R.; Brusati, M.; Cilloco, F.

    1981-01-01

    A typical discharge in the FT Tokamak at 60 kG has been studied in detail in order to derive the power balance between the ohmic input and the plasma losses. Impurity and radiation losses together with ion and electron energy balance are discussed. A power transport term for electrons is derived which is ascribed to anomalous thermal conduction. This resulting thermal transport is compared with those derived from different proposed scalings

  18. Borgerdeltagelse i kvarterløft

    DEFF Research Database (Denmark)

    Larsen, Jacob Norvig

    Rapporten handler om borgerdeltagelse i den første fase af de syv første kvarterløft. Det vil sige det første ca. halvandet år, hvor kvarterløftorganisationen skulle på plads, borgerne skulle mobiliseres og deres idéer og ønsker bringes frem og omsættes til kvarterplaner. Datagrundlaget for analy...

  19. Cosmography in f(T) gravity

    International Nuclear Information System (INIS)

    Capozziello, S.; Cardone, V. F.; Farajollahi, H.; Ravanpak, A.

    2011-01-01

    Based only on the assumption that the Universe is homogenous and isotropic on large scales, cosmography is an ideal tool to investigate the cosmic expansion history in an almost model-independent way. Fitting the data on the luminosity distance and baryon acoustic oscillations allows to determine the confidence ranges for the cosmographic parameters hence giving some quantitative constraints that at whatever theory has to fulfill. As an application, we consider here the case of teleparallel gravity also referred to as f(T) gravity. To this end, we first work out analytical expressions to express the present day values of f(T) derivatives as a function of the cosmographic parameters, which hold under quite general and physically motivated conditions. We then use the constraints coming from cosmography to find out the confidence ranges for f(T) derivatives up to the fifth order and show how these can be used to check the viability of given teleparallel gravity models without the need to explicitly solve the second order dynamic equations.

  20. Formation of a strong southward IMF near the solar maximum of cycle 23

    Directory of Open Access Journals (Sweden)

    S. Watari

    2004-01-01

    Full Text Available We analyzed observations of the solar activities and the solar wind parameters associated with large geomagnetic storms near the maximum of solar cycle 23. This analysis showed that strong southward interplanetary magnetic fields (IMFs, formed through interaction between an interplanetary disturbance, and background solar wind or between interplanetary disturbances are an important factor in the occurrence of intense geomagnetic storms. Based on our analysis, we seek to improve our understanding of the physical processes in which large negative Bz's are created which will lead to improving predictions of space weather.

    Key words. Interplanetary physics (Flare and stream dynamics; Interplanetary magnetic fields; Interplanetary shocks

  1. Dayside aurorae and polar arcs under south-east IMF orientation

    Directory of Open Access Journals (Sweden)

    P. E. Sandholt

    2006-12-01

    Full Text Available We document a characteristic spatial and temporal structure of the aurora in the postnoon sector present during a 10-h-long interval of very steady southeast IMF orientation (clock angle=135° ending in a sharp south-to-north transition. Focus is placed on the detailed morphology of auroral forms/activities corresponding to merging and lobe convection cells obtained from SuperDARN convection data and Greenland magnetograms. The ground optical instruments at Ny Ålesund, Svalbard (76° MLAT recorded different auroral forms/activities as the station moved to higher magnetic local times (MLTs in the 13:00–17:00 MLT sector. Whereas the 13:00–15:00 MLT sector is characterized by classical poleward moving auroral forms (PMAFs associated with merging cell transients, the aurora in the 15:00–17:00 MLT sector shows instead a characteristic latitudinal bifurcation consisting of standard oval forms and polar arcs, and a corresponding composite pattern of merging and lobe convection cells. The merging and lobe cells respond to the southward and northward IMF transitions by activation/fading and fading/activation, respectively. A sequence of brightening events is characterized by successive activations progressing in latitude from the merging cell regime to the lobe cell regime. Emphasis is placed on the association between polar arc brightenings and the activation of the channel of enhanced sunward flow in the lobe cell. The observations are discussed in relation to recent work on solar wind-magnetosphere-ionosphere interconnection topology.

  2. Structure and properties of the subsolar magnetopause for northward IMF: ISEE observations

    International Nuclear Information System (INIS)

    Song, P.; Russell, C.T.; Elphic, R.C.; Gosling, J.T.; Cattell, C.A.

    1990-01-01

    Detailed magnetopause structure and properties for the magnetic field, electric field and plasma are examined for an ISEE 1 magnetopause crossing which occurred near the subsolar point when the interplanetary magnetic field (IMF) was strongly northward. Because the crossing is slow, the spatial variations in the plasma are clearly resolved. This example illustrates the nature of the steady state interface of two magnetized thermal plasma populations with parallel fields and can serve as a guide to theoretical modeling and simulations. The authors have found that the magnetopause is composed of three layers, a sheath transition layer, an outer boundary layer and an inner boundary layer. In the sheath transition layer, there is a gradual density decrease without a change in temperature. The transition layer occurs totally within the magnetosheath plasma. The outer boundary layer and the inner boundary layer are dominated by magnetosheath and magnetospheric particles, respectively. In each of the boundary layers, the plasma can be interpreted as simple mixtures of the magnetosheath and magnetospheric populations. No significant heating or cooling is seen across the magnetopause during this crossing. The plasma within each of these layers is quite uniform and their boundaries are sharp, suggesting that there is very little diffusion present. The sharp boundaries between the transition layer, the boundary layers and the magnetosphere are all thinner than an ion gyroradius. Transverse waves with right hand or linear polarization near the ion gyrofrequency are observed in the transition layer. These appear to be generated in the transition layer and to be a common feature of this layer when the IMF is northward

  3. PERILAKU HARGA DAN VOLUME PERDAGANGAN (Studi Peristiwa Dampak Penundaan Pencairan Bantuan IMF pada Saham Dominasi Asing dengan Pendekatan Koreksi Beta

    Directory of Open Access Journals (Sweden)

    Rini - Mahgianti

    2012-05-01

    Full Text Available ABSTRACT   Theoritically has been stated that any relevant informations can create any market reactions indicated by price behaviour and trading volume. Research aimed  at analysing market reaction through any indicator of  cumulative abnormal return (CAR and cumulative abnormal trading volume (CATVA resulted by the delay of IMF grant.  Research was focused on the broad dominance stock and domestic dominance stock as a comparation. Market model approach was used in this analysis and the beta corection model to determine the expected return. Results show that delay of IMF grant contain any negative informations indicated by the significant reduce of CAR and CATVA, before and after annoucement.   Keywords: prive behaviour, CAR, CATVA, trading volume ABSTRAK   Secara teoritis dinyatakan bahwa informasi yang relevan dapat menimbulkan reaksi pasar yang dapat tercermin dari harga dan volume perdagangan. Penelitian ini bertujuan menguji reaksi pasar melalui indikator cumulative abnormal return (CAR dan cumulative abnormal trading volume (CATVA akibat pengumuman penundaan pencairan bantuan IMF. Obyek penelitian dilakukan pada saham dominasi asing dan sebagai pembanding dilakukan pula pengujian pada saham dominasi domestik. Pengujian dilakukan dengan pendekatan market model dan menambahkan model koreksi beta untuk penentuan expected return. Hasil penelitian yang diperoleh menunjukkan bahwa pengumuman penundaan bantuan IMF memiliki kandungan informasi negatif yang terlihat dari adanya penurunan CAR dan CATVA yang signifikan sebelum dan setelah pengumuman.   Kata kunci: Perilaku harga, CAR, CATVA, volume perdagangan

  4. Läti riik ei suuda IMF-i nõuet mingi hinnaga täita / Kaivo Kopli

    Index Scriptorium Estoniae

    Kopli, Kaivo

    2009-01-01

    Isegi ametiasutuste palkade ja kulude vähendamisel 40% võrra ei suudaks Läti järgida viieprotsendise puudujäägi nõuet, mille täitmise korral on IMF valmis andma edasisi laene. Valitsuse siht on jõuda sel aastal seitsmeprotsendise defitsiidini

  5. High-latitude plasma convection during Northward IMF as derived from in-situ magnetospheric Cluster EDI measurements

    Directory of Open Access Journals (Sweden)

    M. Förster

    2008-09-01

    Full Text Available In this study, we investigate statistical, systematic variations of the high-latitude convection cell structure during northward IMF. Using 1-min-averages of Cluster/EDI electron drift observations above the Northern and Southern polar cap areas for six and a half years (February 2001 till July 2007, and mapping the spatially distributed measurements to a common reference plane at ionospheric level in a magnetic latitude/MLT grid, we obtained regular drift patterns according to the various IMF conditions. We focus on the particular conditions during northward IMF, where lobe cells at magnetic latitudes >80° with opposite (sunward convection over the central polar cap are a permanent feature in addition to the main convection cells at lower latitudes. They are due to reconnection processes at the magnetopause boundary poleward of the cusp regions. Mapped EDI data have a particular good coverage within the central part of the polar cap, so that these patterns and their dependence on various solar wind conditions are well verified in a statistical sense. On average, 4-cell convection pattern are shown as regular structures during periods of nearly northward IMF with the tendency of a small shift toward negative clock angles. The positions of these high-latitude convection foci are within 79° to 85° magnetic latitude and 09:00–15:00 MLT. The MLT positions are approximately symmetric ±2 h about 11:30 MLT, i.e. slightly offset from midday toward prenoon hours, while the maximum (minimum potential of the high-latitude cells is at higher magnetic latitudes near their maximum potential difference at ≈−10° to −15° clock angle for the North (South Hemisphere. With increasing clock angle distances from ≈IMFBz+, a gradual transition occurs from the 4-cell pattern via a 3-cell to the common 2-cell convection pattern, in the course of which one of the medium-scale high-latitude dayside cells diminishes and disappears while the

  6. Effect of hypoproteinemia (HP) upon FT4 and FT3 by kinetic radioligandassay (RLA)

    International Nuclear Information System (INIS)

    Bottger, I.G.; Schneck, H.J.

    1985-01-01

    HP, especially hypoalbuminemia (HA), has been associated with false low FT4 by RLA, predominantly of the analogue tracer type. Based upon previous more favourable findings in severe nonthyroidal illness (NTI), this study was designed to study this problem in more detail. Two groups of patients with severe NTI (polytrauma) were selected on the basis of their total serum protein (TSP) concentration and studied during intensive-care. Group I: N = 25, TSP 5.9 g/dl (6.0 - 7.7), A/G: 1.5, sera: N = 76. I and II: low-dose heparin (i.v. 5000 U/24 h), non-detectable in the periphery. The RLA kits used were: FT4/T4 and FT3/T3 (kinetic two-tube), and TBG, Corning Medical, rT3, Serono, TSH, Henning-Berlin, TSP/electrophoresis standard technique. The findings indicate: 1. Typical findings for follow-up of severe NTI; 2. No detection of a significant effect of HP/HA upon these RLAs for FT4 and FT3; and 3. The inter-group differences are most likely due to more severe NT1 in I (R/sub x/, A/G, rT3)

  7. Star formation in the outskirts of DDO 154: A top-light IMF in a nearly dormant disc

    Science.gov (United States)

    Watts, Adam B.; Meurer, Gerhardt R.; Lagos, Claudia D. P.; Bruzzese, Sarah M.; Kroupa, Pavel; Jerabkova, Tereza

    2018-04-01

    We present optical photometry of Hubble Space Telescope (HST) ACS/WFC data of the resolved stellar populations in the outer disc of the dwarf irregular galaxy DDO 154. The photometry reveals that young main sequence stars are almost absent from the outermost HI disc. Instead, most are clustered near the main stellar component of the galaxy. We constrain the stellar initial mass function (IMF) by comparing the luminosity function of the main sequence stars to simulated stellar populations assuming a constant star formation rate over the dynamical timescale. The best-fitting IMF is deficient in high mass stars compared to a canonical Kroupa IMF, with a best-fit slope α = -2.45 and upper mass limit MU = 16 M⊙. This top-light IMF is consistent with predictions of the Integrated Galaxy-wide IMF theory. Combining the HST images with HI data from The HI Nearby Galaxy Survey Treasury (THINGS) we determine the star formation law (SFL) in the outer disc. The fit has a power law exponent N = 2.92 ± 0.22 and zero point A = 4.47 ± 0.65 × 10-7 M⊙ yr-1 kpc-2. This is depressed compared to the Kennicutt-Schmidt Star Formation Law, but consistent with weak star formation observed in diffuse HI environments. Extrapolating the SFL over the outer disc implies that there could be significant star formation occurring that is not detectable in Hα. Last, we determine the Toomre stability parameter Q of the outer disc of DDO 154 using the THINGS HI rotation curve and velocity dispersion map. 72% of the HI in our field has Q ≤ 4 and this incorporates 96% of the observed MS stars. Hence 28% of the HI in the field is largely dormant.

  8. On the spatial relationship between auroral emissions and magnetic signatures of plasma convection in the midday polar cusp and cap ionospheres during negative and positive IMF Bsub(z)

    International Nuclear Information System (INIS)

    Sandholt, P.E.; Egeland, A.; Lybekk, B.

    1986-03-01

    The dynamics of midday auroras, including polar cusp and cap emissions, and their relation to the interplanetary magnetic field (IMF) have been investigated with optical ground-based observations from Svalbard, Norway and IMF data from spacecraft ISEE-2. One case is presented showing the spatial relationship, along the magnetic meridian in the midday sector, between the cusp aurora and IMF Bγ-related convection currets (the DPY signature) for negative and positive values of IMF Bsub(z)

  9. Development of F.T. Raman Spectroscopy

    Science.gov (United States)

    1989-06-19

    Virginia, 22217 5000, U.S.A*.ELMNNO NONOACSINN. End of Year Report on the contract 2 PERSONAL AU7I40R(S) P.J. Hda and M. Fl cm 3a TYPE OF REPORT 13b. TIME...to do, have .- considerable progress. The area in which we have .ated involves the zeolites. We have sorbed pyridine tc .- of -eolites ( acidic and...react-ion using F.T. Raman methods and then to eX.plore rmechaniszzs, types of acid sites involved and the role o.: temperature. -:olla-’-rators

  10. Development of modified FT (MFT) process

    Energy Technology Data Exchange (ETDEWEB)

    Jinglai Zhou; Zhixin Zhang; Wenjie Shen [Institute of Coal Chemistry, Taiyuan (China)] [and others

    1995-12-31

    Two-Stage Modified FT (MFT) process has been developed for producing high-octane gasoline from coal-based syngas. The main R&D are focused on the development of catalysts and technologies process. Duration tests were finished in the single-tube reactor, pilot plant (100T/Y), and industrial demonstration plant (2000T/Y). A series of satisfactory results has been obtained in terms of operating reliability of equipments, performance of catalysts, purification of coal - based syngas, optimum operating conditions, properties of gasoline and economics etc. Further scaling - up commercial plant is being considered.

  11. Constraining f(T) teleparallel gravity by big bang nucleosynthesis. f(T) cosmology and BBN

    Energy Technology Data Exchange (ETDEWEB)

    Capozziello, S. [Universita di Napoli ' ' Federico II' ' , Complesso Universitario di Monte Sant' Angelo, Dipartimento di Fisica ' ' E. Pancini' ' , Napoli (Italy); Istituto Nazionale di Fisica Nucleare (INFN), Sezione di Napoli (Italy); Gran Sasso Science Institute, L' Aquila (Italy); Lambiase, G. [University of Salerno, Dipartimento di Fisica E.R. Cainaiello, Fisciano (Italy); INFN, Gruppo Collegato di Salerno, Sezione di Napoli, Fisciano (Italy); Saridakis, E.N. [National Technical University of Athens, Department of Physics, Athens (Greece); Baylor University, CASPER, Physics Department, Waco, TX (United States)

    2017-09-15

    We use Big Bang Nucleosynthesis (BBN) observational data on the primordial abundance of light elements to constrain f(T) gravity. The three most studied viable f(T) models, namely the power law, the exponential and the square-root exponential are considered, and the BBN bounds are adopted in order to extract constraints on their free parameters. For the power-law model, we find that the constraints are in agreement with those obtained using late-time cosmological data. For the exponential and the square-root exponential models, we show that for reliable regions of parameters space they always satisfy the BBN bounds. We conclude that viable f(T) models can successfully satisfy the BBN constraints. (orig.)

  12. Constraining f(T) teleparallel gravity by big bang nucleosynthesis. f(T) cosmology and BBN

    International Nuclear Information System (INIS)

    Capozziello, S.; Lambiase, G.; Saridakis, E.N.

    2017-01-01

    We use Big Bang Nucleosynthesis (BBN) observational data on the primordial abundance of light elements to constrain f(T) gravity. The three most studied viable f(T) models, namely the power law, the exponential and the square-root exponential are considered, and the BBN bounds are adopted in order to extract constraints on their free parameters. For the power-law model, we find that the constraints are in agreement with those obtained using late-time cosmological data. For the exponential and the square-root exponential models, we show that for reliable regions of parameters space they always satisfy the BBN bounds. We conclude that viable f(T) models can successfully satisfy the BBN constraints. (orig.)

  13. FT-IR, FT-Raman and UV-visible spectra of potassium 3-furoyltrifluoroborate salt

    Science.gov (United States)

    Iramain, Maximiliano A.; Davies, Lilian; Brandán, Silvia Antonia

    2018-04-01

    The potassium 3-furoyltrifluoroborate salt has been experimentally characterized by means of FT-IR, FT-Raman and UV-Visible spectroscopies. Here, the predicted FT-IR, FT-Raman and UV-visible spectra by using theoretical B3LYP/6-31G* and 6-311++G** calculations show very good correlations with the corresponding experimental ones. The solvation energies were predicted by using both levels of calculations. The NBO analyses reveal the high stability of the salt by using the B3LYP/6-31G* level of theory while the AIM studies evidence the ionic characteristics of the salt in both media. The strong blue colour observed on the K atom by using the molecular electrostatic potential mapped suggests that this region act as typical electrophilic site. The gap values have revealed that the salt in gas phase is more reactive than in solution, as was reported in the literature while, the F13⋯H6 interaction together with the Ksbnd O bond observed by the studies of their charges could probably modulate the reactivities of this salt in aqueous solution. The force fields were computed with the SQMFF methodology and the Molvib program to perform the complete vibrational analysis. Then, the 39 vibration normal modes classified as 26 A'+ 13 A″ were completely assigned and their force constants are also reported.

  14. IMF control of cusp proton emission intensity and dayside convection: implications for component and anti-parallel reconnection

    Directory of Open Access Journals (Sweden)

    M. Lockwood

    2003-04-01

    Full Text Available We study a brightening of the Lyman-a emission in the cusp which occurred in response to a short-lived south-ward turning of the interplanetary magnetic field (IMF during a period of strongly enhanced solar wind plasma concentration. The cusp proton emission is detected using the SI-12 channel of the FUV imager on the IMAGE spacecraft. Analysis of the IMF observations recorded by the ACE and Wind spacecraft reveals that the assumption of a constant propagation lag from the upstream spacecraft to the Earth is not adequate for these high time-resolution studies. The variations of the southward IMF component observed by ACE and Wind allow for the calculation of the ACE-to-Earth lag as a function of time. Application of the derived propagation delays reveals that the intensity of the cusp emission varied systematically with the IMF clock angle, the relationship being particularly striking when the intensity is normalised to allow for the variation in the upstream solar wind proton concentration. The latitude of the cusp migrated equatorward while the lagged IMF pointed southward, confirming the lag calculation and indicating ongoing magnetopause reconnection. Dayside convection, as monitored by the SuperDARN network of radars, responded rapidly to the IMF changes but lagged behind the cusp proton emission response: this is shown to be as predicted by the model of flow excitation by Cowley and Lockwood (1992. We use the numerical cusp ion precipitation model of Lockwood and Davis (1996, along with modelled Lyman-a emission efficiency and the SI-12 instrument response, to investigate the effect of the sheath field clock angle on the acceleration of ions on crossing the dayside magnetopause. This modelling reveals that the emission commences on each reconnected field line 2–2.5 min after it is opened and peaks 3–5 min after it is opened. We discuss how comparison of the Lyman-a intensities with oxygen emissions observed simultaneously by the SI-13

  15. IMF control of cusp proton emission intensity and dayside convection: implications for component and anti-parallel reconnection

    Directory of Open Access Journals (Sweden)

    M. Lockwood

    Full Text Available We study a brightening of the Lyman-a emission in the cusp which occurred in response to a short-lived south-ward turning of the interplanetary magnetic field (IMF during a period of strongly enhanced solar wind plasma concentration. The cusp proton emission is detected using the SI-12 channel of the FUV imager on the IMAGE spacecraft. Analysis of the IMF observations recorded by the ACE and Wind spacecraft reveals that the assumption of a constant propagation lag from the upstream spacecraft to the Earth is not adequate for these high time-resolution studies. The variations of the southward IMF component observed by ACE and Wind allow for the calculation of the ACE-to-Earth lag as a function of time. Application of the derived propagation delays reveals that the intensity of the cusp emission varied systematically with the IMF clock angle, the relationship being particularly striking when the intensity is normalised to allow for the variation in the upstream solar wind proton concentration. The latitude of the cusp migrated equatorward while the lagged IMF pointed southward, confirming the lag calculation and indicating ongoing magnetopause reconnection. Dayside convection, as monitored by the SuperDARN network of radars, responded rapidly to the IMF changes but lagged behind the cusp proton emission response: this is shown to be as predicted by the model of flow excitation by Cowley and Lockwood (1992. We use the numerical cusp ion precipitation model of Lockwood and Davis (1996, along with modelled Lyman-a emission efficiency and the SI-12 instrument response, to investigate the effect of the sheath field clock angle on the acceleration of ions on crossing the dayside magnetopause. This modelling reveals that the emission commences on each reconnected field line 2–2.5 min after it is opened and peaks 3–5 min after it is opened. We discuss how comparison of the Lyman-

  16. Main results of the development of dispersion type IMF at A.A. Bochvar Institute

    International Nuclear Information System (INIS)

    Savchenko, A.; Vatulin, A.; Glagovsky, E.; Konovalov, I.; Morozov, A.; Ershov, S.

    2009-01-01

    At the A.A. Bochvar Institute a novel conception of IMF to burn civil and weapon's grade Pu is currently accepted. It consists in the fact, that instead of using pelletized IMF, that features low serviceability and dust forming route of fuel element fabrication, the usage is made of dispersion type fuel element with Aluminium or Zirconium matrices. Dispersion fuels feature a high irradiation resistance and reliability; they can consequently reach high burn-ups and be serviceable under transient conditions. Three basic fuel element versions are under development in VNIINM for both thermal and fast reactors. The first version is a fuel element with a heterogeneous arrangement of fuel (PuO 2 or YSZ granules) within an Al or Zr matrix. The second version of a fuel element has a heat conducting Al or Zr alloy matrix and an isolated arrangement of PuO 2 in a fuel mini element more fully meets the 'Rock Fuel' requirements. According to the third version a porous meat of Zirconium metallurgically bonded to a fuel cladding is formed through which a PuO 2 powder is introduced. All the versions are technologically simple to fabricate and require minimal quantities of process operations related to treating MA and Pu. Fuel element simulators of similar designs with inert aluminium matrix, in which UO 2 was used in place of PuO 2 were successfully in-pile tested under PWR conditions up to the burn up of 100 MW·d/kg U and fuel element simulators with inert Zirconium matrix clad in stainless steel reached the burnup of 200 MW·d/kgU with the temperature of steam up to 600 0 C, which makes their application promising both in thermal and fast reactors. Currently a lead IFM assembly has been fabricated with two version of fuels with an Al matrix; use was made of a crystalline powder of fuel-grade PuO 2 prepared by the pyrochemical method. At the end of the year we are planning to commence in-pile testing under PWR conditions. The anticipated burn-up is 100 MW·d/kgU

  17. A global MHD simulation of an event with a quasi-steady northward IMF component

    Directory of Open Access Journals (Sweden)

    V. G. Merkin

    2007-06-01

    Full Text Available We show results of the Lyon-Fedder-Mobarry (LFM global MHD simulations of an event previously examined using Iridium spacecraft observations as well as DMSP and IMAGE FUV data. The event is chosen for the steady northward IMF sustained over a three-hour period during 16 July 2000. The Iridium observations showed very weak or absent Region 2 currents in the ionosphere, which makes the event favorable for global MHD modeling. Here we are interested in examining the model's performace during weak magnetospheric forcing, in particular, its ability to reproduce gross signatures of the ionospheric currents and convection pattern and energy deposition in the ionosphere both due to the Poynting flux and particle precipitation. We compare the ionospheric field-aligned current and electric potential patterns with those recovered from Iridium and DMSP observations, respectively. In addition, DMSP magnetometer data are used for comparisons of ionospheric magnetic perturbations. The electromagnetic energy flux is compared with Iridium-inferred values, while IMAGE FUV observations are utilized to verify the simulated particle energy flux.

  18. Assessing Space Weather Applications and Understanding: IMF Bz at L1

    Science.gov (United States)

    Riley, P.; Savani, N.; Mays, M. L.; Austin, H. J.

    2017-12-01

    The CCMC - International (CCMC-I) is designed as a self-organizing informal forum for facilitating novel global initiatives on space weather research, development, forecasting and education. Here we capitalize on CCMC'AGUs experience in providing highly utilized web-based services, leadership and trusted relationships with space weather model developers. One of the CCMC-I initiatives is the International Forum for Space Weather Capabilities Assessment. As part of this initiative, within the solar and heliosphere domain, we focus our community discussion on forecasting the magnetic structure of interplanetary CMEs and the ambient solar wind. During the International CCMC-LWS Working Meeting in April 2017 the group instigated open communication to agree upon a standardized process by which all current and future models can be compared under an unbiased test. In this poster, we present our initial findings how we expect different models will move forward with validating and forecasting the magnetic vectors of the solar wind at L1. We also present a new IMF Bz Score-board which will be used to assist in the transitioning of research models into more operational settings.

  19. The Stellar Initial Mass Function in Early-type Galaxies from Absorption Line Spectroscopy. IV. A Super-Salpeter IMF in the Center of NGC 1407 from Non-parametric Models

    Energy Technology Data Exchange (ETDEWEB)

    Conroy, Charlie [Department of Astronomy, Harvard University, Cambridge, MA, 02138 (United States); Van Dokkum, Pieter G. [Department of Astronomy, Yale University, New Haven, CT, 06511 (United States); Villaume, Alexa [Department of Astronomy and Astrophysics, University of California, Santa Cruz, CA 95064 (United States)

    2017-03-10

    It is now well-established that the stellar initial mass function (IMF) can be determined from the absorption line spectra of old stellar systems, and this has been used to measure the IMF and its variation across the early-type galaxy population. Previous work focused on measuring the slope of the IMF over one or more stellar mass intervals, implicitly assuming that this is a good description of the IMF and that the IMF has a universal low-mass cutoff. In this work we consider more flexible IMFs, including two-component power laws with a variable low-mass cutoff and a general non-parametric model. We demonstrate with mock spectra that the detailed shape of the IMF can be accurately recovered as long as the data quality is high (S/N ≳ 300 Å{sup −1}) and cover a wide wavelength range (0.4–1.0 μ m). We apply these flexible IMF models to a high S/N spectrum of the center of the massive elliptical galaxy NGC 1407. Fitting the spectrum with non-parametric IMFs, we find that the IMF in the center shows a continuous rise extending toward the hydrogen-burning limit, with a behavior that is well-approximated by a power law with an index of −2.7. These results provide strong evidence for the existence of extreme (super-Salpeter) IMFs in the cores of massive galaxies.

  20. The optimally sampled galaxy-wide stellar initial mass function. Observational tests and the publicly available GalIMF code

    Science.gov (United States)

    Yan, Zhiqiang; Jerabkova, Tereza; Kroupa, Pavel

    2017-11-01

    Here we present a full description of the integrated galaxy-wide initial mass function (IGIMF) theory in terms of the optimal sampling and compare it with available observations. Optimal sampling is the method we use to discretize the IMF deterministically into stellar masses. Evidence indicates that nature may be closer to deterministic sampling as observations suggest a smaller scatter of various relevant observables than random sampling would give, which may result from a high level of self-regulation during the star formation process. We document the variation of IGIMFs under various assumptions. The results of the IGIMF theory are consistent with the empirical relation between the total mass of a star cluster and the mass of its most massive star, and the empirical relation between the star formation rate (SFR) of a galaxy and the mass of its most massive cluster. Particularly, we note a natural agreement with the empirical relation between the IMF power-law index and the SFR of a galaxy. The IGIMF also results in a relation between the SFR of a galaxy and the mass of its most massive star such that, if there were no binaries, galaxies with SFR first time, we show optimally sampled galaxy-wide IMFs (OSGIMF) that mimic the IGIMF with an additional serrated feature. Finally, a Python module, GalIMF, is provided allowing the calculation of the IGIMF and OSGIMF dependent on the galaxy-wide SFR and metallicity. A copy of the python code model is available at the CDS via anonymous ftp to http://cdsarc.u-strasbg.fr (http://130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/qcat?J/A+A/607/A126

  1. On the role of IMF By in generating the electric field responsible for the flow across the polar cap

    International Nuclear Information System (INIS)

    Vennerstroem, S.; Friis-Christensen, E.

    1987-01-01

    During periods of southward interplanetary magnetic field (IMF) the authors have examined the relationship between magnetic variations in the central polar cap and the IMF B y and B z components. The geomagnetic polar cap index PC that can be used as a measure of the flow across the polar cap has been derived using data from Thule in the IMS period. The results have been compared with IMP 8 measurements of the IMF and the solar wind velocity. The statistical analysis shows that the absolute value of the azimuthal component |B y | contributes to the cross-polar cap flow in the same manner as the southward component B s . The relative contributions of |B y | and B z have been examined and compared with the theoretical expression υB T sin 2 θ/2 for the merging electric field. It is found that the contribution of |B y | compared to B z is only half as big in the observations as in the theoretical expression. The B y effect on PC is compared to an earlier reported effect of B y on the geomagnetic index AL (Murayama et al., 1980) and found to be quite different from this. This is discussed in relation to interpretations in terms of merging site asymmetry

  2. A Comparison of the IMF Program and Economic Performance among Three Asian Crisis Countries: Thailand, Indonesia, and Korea

    Directory of Open Access Journals (Sweden)

    Yunjong Wang

    1998-09-01

    Full Text Available The whole international society believes that if Korea and Thailand generally carry out the IMF programs, the fruit of the structure reform will be soon put across. In Indonesia, the way of IMF capital support has been changed from the existing 8.25 stand-by agreement to extended credit agreement, so Indonesia gets more support from the international world. But there is an analysis that there is still a lot of uncertainty in Indonesia. Observing the "economic fruit" which was the result of the IMF programs in the countries mentioned above, the cognition of the international world is more evident. In spite of this, because of the rise of the exchange rate of the three countries above, going by US dollar, the rate of foreign exchange risk which is predicted by the index of foreign exchange rate crisis increased on the contrary with the sharp decrease of state financial resource. This is because the amount of foreign debts the country should reimburse increased accordingly due to the rise of exchange rate of Korea and Thailand in which the stability of the foreign exchange rate market recovered in a short period. This considered, in order to overcome the future foreign exchange crisis and decrease foreign debts, the most important thing is to emphasize the basic economic condition presents in the prediction index of foreign exchange crisis.

  3. Field-aligned currents and convection patterns in the Southern Polar Cap during stable northward, southward, and azimuthal IMF

    International Nuclear Information System (INIS)

    Papitashvili, V.O.; Belov, B.A.; Gromova, L.I.

    1989-01-01

    Equivalent ionospheric current patterns are derived from ground-based geomagnetic observations for events on 11-12 November 1979 (B/sub z/ >> 0), 24 November 1981 (B/sub z/ > 0) (B/sub y/ >> 0), and 25-26 November 1979 (B/sub y/ 0 . Due to stable external conditions, it is possible to calculate the field-aligned current (FAC) density within cells formed by two adjacent stations by taking into account the uniform conductivity of the summer polar ionosphere. These results completely correspond to regressional analysis of interplanetary magnetic fields (IMF) and ground-based geomagnetic data, and also to satellite observations of the NBZ current system. During stable southward IMF a new result was obtained, a reversal of antisunward convection flow is identified, and an NBZ-like FAC system is restored in the central part of the southern polar cap. The authors conclude that there may be an additional NBZ-like FAC system poleward of -85 0 , which is independent of the IMF and is generated by the quasi-viscous interaction between solar-wind plasma and high-latitude lobes of the magnetospheric tail

  4. Overlapping ion structures in the mid-altitude cusp under northward IMF: signature of dual lobe reconnection?

    Directory of Open Access Journals (Sweden)

    F. Pitout

    2012-03-01

    Full Text Available On some rare occasions, data from the Cluster Ion Spectrometer (CIS in the mid-altitude cusp reveal overlapping ion populations under northward interplanetary magnetic field (IMF. While the poleward part of the cusp exhibits the expected reverse dispersion due to lobe reconnection, its equatorward part shows a second ion population at higher-energy that coexists with the low energy tail of the dispersion. This second population is either dispersionless or slightly dispersed with energies increasing with increasing latitudes, indicative of lobe reconnection as well. Our analysis of a case that occurred 3 September 2002 when the IMF stayed northward for more than two hours suggests that the second population comes from the opposite hemisphere and is very likely on newly-closed field lines. We interpret this overlap of cusp populations as a clear mid-altitude signature of re-closed magnetic field lines by double lobe reconnection (reconnection in both hemispheres under northward IMF. This interpretation is supported by modelling performed with the Cooling model and an MHD model.

  5. The evaluation of free thyroid hormones (FT4 and FT3) in the routine diagnosis of thyroid function

    International Nuclear Information System (INIS)

    Passath, A.; Leb, G.; Goebel, R.

    1985-01-01

    The validity of the free thyroid hormone parameters (FT 4 and FT 3 ) was verified in a random sample of 154 ambulatory patients with thyroid conditions. The ''euthyroid range'' of FT 4 was between 15.67 and 30.66 pmol/l; median 21.98 pmol/l. The distribution of the FT 4 readings peaked on the left and sloped to the right (log normal). In our laboratory, the ''euthyroid reference range'' of FT 4 is between 10-28 pmol/l. The ''euthyroid range'' of FT 3 extended from 4.6 to 9.7 pmol/l; median 6.63 pmol/l. The distribution of the readings was likewise log normal. The values of FT 4 and FT 3 are not significantly influenced by TBG concentration anomalies in otherwise healthy thyroid patients. For purposes of discrimination between euthyroidism and hyperthyroidism, FT 3 (95%) and FT 4 (90%) are better suited than the corresponding quotients for the free hormone fraction or the total hormone concentrations. On the other hand, the free hormone parameters are less suitable for the diagnosis of hypothyroidism. These results were deduced theoretically from mathematical function analyses between the TBG-independent free hormone parameters and the TBG-dependent hormone concentrations. (orig.) [de

  6. FTIR, FT-Raman, FT-NMR and quantum chemical investigations of 3-acetylcoumarin

    Science.gov (United States)

    Arjunan, V.; Sakiladevi, S.; Marchewka, M. K.; Mohan, S.

    2013-05-01

    3-Acetylcoumarin (3AC) was synthesised by a Knoevenagel reaction. Conformational analysis using the B3LYP method was also carried out to determine the most stable conformation of the compound. FTIR and FT-Raman spectra of 3AC have been recorded in the range 4000-400 and 4000-100 cm-1, respectively. 1H and 13C NMR spectra have also been recorded. The complete vibrational assignment and analysis of the fundamental modes of the compound were carried out using the experimental FTIR and FT-Raman data and quantum mechanical studies. The experimental vibrational frequencies were compared with the wavenumbers obtained theoretically from the DFT-B3LYP/B3PW91 gradient calculations employing the standard 6-31G**, high level 6-311++G** and cc-pVTZ basis sets for optimised geometry of the compound. The frontier molecular orbital energies of the compound are determined by DFT method.

  7. THE NON-UNIVERSALITY OF THE LOW-MASS END OF THE IMF IS ROBUST AGAINST THE CHOICE OF SSP MODEL

    International Nuclear Information System (INIS)

    Spiniello, C.; Trager, S. C.; Koopmans, L. V. E.

    2015-01-01

    We perform a direct comparison of two state-of-the art single stellar population (SSP) models that have been used to demonstrate the non-universality of the low-mass end of the initial mass function (IMF) slope. The two public versions of the SSP models are restricted to either solar abundance patterns or solar metallicity, too restrictive if one aims to disentangle elemental enhancements, metallicity changes, and IMF variations in massive early-type galaxies (ETGs) with star formation histories different from those in the solar neighborhood. We define response functions (to metallicity and α-abundance) to extend the parameter space for each set of models. We compare these extended models with a sample of Sloan Digital Sky Survey (SDSS) ETG spectra with varying velocity dispersions. We measure equivalent widths of optical IMF-sensitive stellar features to examine the effect of the underlying model assumptions and ingredients, such as stellar libraries or isochrones, on the inference of the IMF slope down to ∼0.1 M ⊙ . We demonstrate that the steepening of the low-mass end of the IMF based on a non-degenerate set of spectroscopic optical indicators is robust against the choice of the stellar population model. Although the models agree in a relative sense (i.e., both imply more bottom-heavy IMFs for more massive systems), we find non-negligible differences in the absolute values of the IMF slope inferred at each velocity dispersion by using the two different models. In particular, we find large inconsistencies in the quantitative predictions of the IMF slope variations and abundance patterns when sodium lines are used. We investigate the possible reasons for these inconsistencies

  8. Who Gets a Bailout? A Comparative Analysis of U.S. and IMF Responses to Economic Crisis in Mexico (1995), Brazil (1998), and Argentina (2001)

    Science.gov (United States)

    2009-12-01

    not have finished this paper without the support and understanding of my wife, Melissa, and our dog, Blackjack . x THIS PAGE INTENTIONALLY LEFT...Representatives, November 17, 1993, http://clerk.house.gov/evs/1993/roll575.xml (accessed August 28, 2009). 90 Bill Clinton, My Life : The ... Life : The Presidential Years, Volume 2 (New York: Random House, 2005), 479. 92 IMF Staff, “Recovery from the Asian Crisis and the Role of the IMF

  9. THE NON-UNIVERSALITY OF THE LOW-MASS END OF THE IMF IS ROBUST AGAINST THE CHOICE OF SSP MODEL

    Energy Technology Data Exchange (ETDEWEB)

    Spiniello, C. [Max-Planck Institute for Astrophysics, Karl-Schwarzschild-Strasse 1, D-8l740 Garching (Germany); Trager, S. C.; Koopmans, L. V. E. [Kapteyn Astronomical Institute, University of Groningen, P.O. Box 800, 9700 AV Groningen (Netherlands)

    2015-04-20

    We perform a direct comparison of two state-of-the art single stellar population (SSP) models that have been used to demonstrate the non-universality of the low-mass end of the initial mass function (IMF) slope. The two public versions of the SSP models are restricted to either solar abundance patterns or solar metallicity, too restrictive if one aims to disentangle elemental enhancements, metallicity changes, and IMF variations in massive early-type galaxies (ETGs) with star formation histories different from those in the solar neighborhood. We define response functions (to metallicity and α-abundance) to extend the parameter space for each set of models. We compare these extended models with a sample of Sloan Digital Sky Survey (SDSS) ETG spectra with varying velocity dispersions. We measure equivalent widths of optical IMF-sensitive stellar features to examine the effect of the underlying model assumptions and ingredients, such as stellar libraries or isochrones, on the inference of the IMF slope down to ∼0.1 M{sub ⊙}. We demonstrate that the steepening of the low-mass end of the IMF based on a non-degenerate set of spectroscopic optical indicators is robust against the choice of the stellar population model. Although the models agree in a relative sense (i.e., both imply more bottom-heavy IMFs for more massive systems), we find non-negligible differences in the absolute values of the IMF slope inferred at each velocity dispersion by using the two different models. In particular, we find large inconsistencies in the quantitative predictions of the IMF slope variations and abundance patterns when sodium lines are used. We investigate the possible reasons for these inconsistencies.

  10. FT-IR, FT-Raman spectra and DFT calculations of melaminium perchlorate monohydrate

    Science.gov (United States)

    Kanagathara, N.; Marchewka, M. K.; Drozd, M.; Renganathan, N. G.; Gunasekaran, S.; Anbalagan, G.

    2013-08-01

    Melaminium perchlorate monohydrate (MPM), an organic material has been synthesized by slow solvent evaporation method at room temperature. Powder X-ray diffraction analysis confirms that MPM crystal belongs to triclinic system with space group P-1. FTIR and FT Raman spectra are recorded at room temperature. Functional group assignment has been made for the melaminium cations and perchlorate anions. Vibrational spectra have also been discussed on the basis of quantum chemical density functional theory (DFT) calculations using Firefly (PC GAMESS) version 7.1 G. Vibrational frequencies are calculated and scaled values are compared with experimental values. The assignment of the bands has been made on the basis of the calculated PED. The Mulliken charges, HOMO-LUMO orbital energies are analyzed directly from Firefly program log files and graphically illustrated. HOMO-LUMO energy gap and other related molecular properties are also calculated. The theoretically constructed FT-IR and FT-Raman spectra of MPM coincide with the experimental one. The chemical structure of the compound has been established by 1H and 13C NMR spectra. No detectable signal was observed during powder test for second harmonic generation.

  11. No further gravitational wave modes in F(T) gravity

    Energy Technology Data Exchange (ETDEWEB)

    Bamba, Kazuharu, E-mail: bamba@kmi.nagoya-u.ac.jp [Kobayashi–Maskawa Institute for the Origin of Particles and the Universe, Nagoya University, Nagoya 464-8602 (Japan); Capozziello, Salvatore, E-mail: capozziello@na.infn.it [Kobayashi–Maskawa Institute for the Origin of Particles and the Universe, Nagoya University, Nagoya 464-8602 (Japan); Dipartimento di Fisica, Università di Napoli “Federico II” (Italy); INFN Sez. di Napoli, Compl. Univ. di Monte S. Angelo, Edificio G, Via Cinthia, I-80126 Napoli (Italy); De Laurentis, Mariafelicia, E-mail: felicia@na.infn.it [Kobayashi–Maskawa Institute for the Origin of Particles and the Universe, Nagoya University, Nagoya 464-8602 (Japan); Dipartimento di Fisica, Università di Napoli “Federico II” (Italy); INFN Sez. di Napoli, Compl. Univ. di Monte S. Angelo, Edificio G, Via Cinthia, I-80126 Napoli (Italy); Nojiri, Shin' ichi, E-mail: nojiri@phys.nagoya-u.ac.jp [Kobayashi–Maskawa Institute for the Origin of Particles and the Universe, Nagoya University, Nagoya 464-8602 (Japan); Department of Physics, Nagoya University, Nagoya 464-8602 (Japan); Sáez-Gómez, Diego, E-mail: diego.saezgomez@uct.ac.za [Kobayashi–Maskawa Institute for the Origin of Particles and the Universe, Nagoya University, Nagoya 464-8602 (Japan); Astrophysics, Cosmology and Gravity Centre (ACGC) and Department of Mathematics and Applied Mathematics, University of Cape Town, Rondebosch 7701, Cape Town (South Africa); Fisika Teorikoaren eta Zientziaren Historia Saila, Zientzia eta Teknologia Fakultatea, Euskal Herriko Unibertsitatea, 644 Posta Kutxatila, 48080 Bilbao (Spain)

    2013-11-25

    We explore the possibility of further gravitational wave modes in F(T) gravity, where T is the torsion scalar in teleparallelism. It is explicitly demonstrated that gravitational wave modes in F(T) gravity are equivalent to those in General Relativity. This result is achieved by calculating the Minkowskian limit for a class of analytic function of F(T). This consequence is also confirmed by the preservative analysis around the flat background in the weak field limit with the scalar–tensor representation of F(T) gravity.

  12. McVittie solution in f(T) gravity

    Energy Technology Data Exchange (ETDEWEB)

    Bejarano, Cecilia; Jose Guzman, Maria [Instituto de Astronomia y Fisica del Espacio (IAFE, CONICET-UBA), Buenos Aires (Argentina); Ferraro, Rafael [Instituto de Astronomia y Fisica del Espacio (IAFE, CONICET-UBA), Buenos Aires (Argentina); Universidad de Buenos Aires, Departamento de Fisica, Facultad de Ciencias Exactas y Naturales, Buenos Aires (Argentina)

    2017-12-15

    We show that McVittie geometry, which describes a black hole embedded in a FLRW universe, not only solves the Einstein equations but also remains as a non-deformable solution of f(T) gravity. This search for GR solutions that survive in f(T) gravity is facilitated by a null tetrad approach. We also show that flat FLRW geometry is a consistent solution of f(T) dynamical equations not only for T = -6H{sup 2} but also for T = 0, which could be a manifestation of the additional degrees of freedom involved in f(T) theories. (orig.)

  13. McVittie solution in f(T) gravity

    International Nuclear Information System (INIS)

    Bejarano, Cecilia; Jose Guzman, Maria; Ferraro, Rafael

    2017-01-01

    We show that McVittie geometry, which describes a black hole embedded in a FLRW universe, not only solves the Einstein equations but also remains as a non-deformable solution of f(T) gravity. This search for GR solutions that survive in f(T) gravity is facilitated by a null tetrad approach. We also show that flat FLRW geometry is a consistent solution of f(T) dynamical equations not only for T = -6H 2 but also for T = 0, which could be a manifestation of the additional degrees of freedom involved in f(T) theories. (orig.)

  14. No further gravitational wave modes in F(T) gravity

    International Nuclear Information System (INIS)

    Bamba, Kazuharu; Capozziello, Salvatore; De Laurentis, Mariafelicia; Nojiri, Shin'ichi; Sáez-Gómez, Diego

    2013-01-01

    We explore the possibility of further gravitational wave modes in F(T) gravity, where T is the torsion scalar in teleparallelism. It is explicitly demonstrated that gravitational wave modes in F(T) gravity are equivalent to those in General Relativity. This result is achieved by calculating the Minkowskian limit for a class of analytic function of F(T). This consequence is also confirmed by the preservative analysis around the flat background in the weak field limit with the scalar–tensor representation of F(T) gravity

  15. Measurement of serum FT3 and FT4 in patients with chronic renal failure and its clinical significance

    International Nuclear Information System (INIS)

    Tan Qingling; Zhang Hui

    2003-01-01

    Objective: To investigate the changes of thyroid hormones in patients with chronic renal failure (CRF) and it's clinical significance. Methods: FT 3 , FT 4 and TSH levels were measured with radioimmunoassay for 42 CRF patients (42 CRF patients were subdivided into uremia and azotemia) and 18 cases of renal disease patients with a normal renal function. Results: Levels of FT 3 , FT 4 and TSH in uremia group and azotemia group were significantly lower than that of normal renal function group (P 3 , FT 4 and TSH in uremia group were remarkably lower than azotemia group (P 3 , FT 4 in patients with CRF can reflect the severity of renal function damage, and can also be an important prognosis index

  16. [Effect of selenium on serum TGAb, TMAb, FT3, FT4 and TSH of rats with excessive intake of iodine].

    Science.gov (United States)

    Chi, Haiyan; Zhou, Yuping; Li, Li

    2012-07-01

    To investigate the effect of selenium on the TGAb, TMAb, FT3, FT4 and TSH level of rats with excessive intake of iodine. Wistar rats were divided into three groups by random:normal control, high iodine group and high iodine plus selenium group. Rats in the high iodine plus selenium group were lavaged with sodium selenite for 10 weeks. The levels of serum TGAb, TMAb, FT3, FT4 and TSH were tested at different time of the experiment. There were no significant change on levels of FT3, FT4 and TSH (P > 0.05). The levels of TGAb and TMAb in the high iodine group were increased slowly (P iodine plus selenium group. Excessive intake of iodine might induce goiter, and selenium might have antagonistic effect on it.

  17. The Polar Cusp Observed by Cluster Under Constant Imf-Bz Southward

    Science.gov (United States)

    Escoubet, C. P.; Berchem, J.; Pitout, F.; Trattner, K. J.; Richard, R. L.; Taylor, M. G.; Soucek, J.; Grison, B.; Laakso, H. E.; Masson, A.; Dunlop, M. W.; Dandouras, I. S.; Reme, H.; Fazakerley, A. N.; Daly, P. W.

    2011-12-01

    The Earth's magnetic field is influenced by the interplanetary magnetic field (IMF), specially at the magnetopause where both magnetic fields enter in direct contact and magnetic reconnection can be initiated. In the polar regions, the polar cusp that extends from the magnetopause down to the ionosphere is also directly influenced. The reconnection not only allow ions and electrons from the solar wind to enter the polar cusp but also give an impulse to the magnetic field lines threading the polar cusp through the reconnection electric field. A dispersion in energy of the ions is subsequently produced by the motion of field lines and the time-of-flight effect on down-going ions. If reconnection is continuous and operates at constant rate, the ion dispersion is smooth and continuous. On the other hand if the reconnection rate varies, we expect interruption in the dispersion forming energy steps or staircase. Similarly, multiple entries near the magnetopause could also produce steps at low or mid-altitude when a spacecraft is crossing subsequently the field lines originating from these multiple sources. Cluster with four spacecraft following each other in the mid-altitude cusp can be used to distinguish between these "temporal" and "spatial" effects. We will show two Cluster cusp crossings where the spacecraft were separated by a few minutes. The energy dispersions observed in the first crossing were the same during the few minutes that separated the spacecraft. In the second crossing, two ion dispersions were observed on the first spacecraft and only one of the following spacecraft, about 10 min later. The detailed analysis indicates that these steps result from spatial structures.

  18. Quark stars in f(T, T)-gravity

    Energy Technology Data Exchange (ETDEWEB)

    Pace, Mark; Said, Jackson Levi [University of Malta, Department of Physics, Msida (Malta); University of Malta, Institute of Space Sciences and Astronomy, Msida (Malta)

    2017-02-15

    We derive a working model for the Tolman-Oppenheimer-Volkoff equation for quark star systems within the modified f(T, T)-gravity class of models. We consider f(T, T)-gravity for a static spherically symmetric space-time. In this instance the metric is built from a more fundamental tetrad vierbein from which the metric tensor can be derived. We impose a linear f(T) parameter, namely taking f = αT(r) + βT(r) + φ and investigate the behaviour of a linear energy-momentum tensor trace, T. We also outline the restrictions which modified f(T, T)-gravity imposes upon the coupling parameters. Finally we incorporate the MIT bag model in order to derive the mass-radius and mass-central density relations of the quark star within f(T, T)-gravity. (orig.)

  19. Evaluation of Turmeric Powder Adulterated with Metanil Yellow Using FT-Raman and FT-IR Spectroscopy

    Directory of Open Access Journals (Sweden)

    Sagar Dhakal

    2016-05-01

    Full Text Available Turmeric powder (Curcuma longa L. is valued both for its medicinal properties and for its popular culinary use, such as being a component in curry powder. Due to its high demand in international trade, turmeric powder has been subject to economically driven, hazardous chemical adulteration. This study utilized Fourier Transform-Raman (FT-Raman and Fourier Transform-Infra Red (FT-IR spectroscopy as separate but complementary methods for detecting metanil yellow adulteration of turmeric powder. Sample mixtures of turmeric powder and metanil yellow were prepared at concentrations of 30%, 25%, 20%, 15%, 10%, 5%, 1%, and 0.01% (w/w. FT-Raman and FT-IR spectra were acquired for these mixture samples as well as for pure samples of turmeric powder and metanil yellow. Spectral analysis showed that the FT-IR method in this study could detect the metanil yellow at the 5% concentration, while the FT-Raman method appeared to be more sensitive and could detect the metanil yellow at the 1% concentration. Relationships between metanil yellow spectral peak intensities and metanil yellow concentration were established using representative peaks at FT-Raman 1406 cm−1 and FT-IR 1140 cm−1 with correlation coefficients of 0.93 and 0.95, respectively.

  20. On the location of dayside magnetic reconnection during an interval of duskward oriented IMF

    Directory of Open Access Journals (Sweden)

    J. A. Wild

    2007-02-01

    Full Text Available We present space- and ground-based observations of the signatures of magnetic reconnection during an interval of duskward-oriented interplanetary magnetic field on 25 March 2004. In situ field and plasma measurements are drawn from the Double Star and Cluster satellites during traversals of the pre-noon sector dayside magnetopause at low and high latitudes, respectively. These reveal the typical signatures of flux transfer events (FTEs, namely bipolar perturbations in the magnetic field component normal to the local magnetopause, enhancements in the local magnetic field strength and mixing of magnetospheric and magnetosheath plasmas. Further evidence of magnetic reconnection is inferred from the ground-based signatures of pulsed ionospheric flow observed over an extended interval. In order to ascertain the location of the reconnection site responsible for the FTEs, a simple model of open flux tube motion over the surface of the magnetopause is employed. A comparison of the modelled and observed motion of open flux tubes (i.e. FTEs and plasma flow in the magnetopause boundary layer indicates that the FTEs observed at both low and high latitudes were consistence with the existence of a tilted X-line passing through the sub-solar region, as suggested by the component reconnection paradigm. While a high latitude X-line (as predicted by the anti-parallel description of reconnection may have been present, we find it unlikely that it could have been responsible for the FTEs observed in the pre-noon sector under the observed IMF conditions. Finally, we note that throughout the interval, the magnetosphere was bathed in ULF oscillations within the solar wind electric field. While no one-to-one correspondence with the pulsed reconnection rate suggested by the ground-based observation of pulsed ionospheric flow has been demonstrated, we note that similar periodicity oscillations were observed throughout the solar wind-magnetosphere-ionosphere system. These

  1. High-latitude electromagnetic and particle energy flux during an event with sustained strongly northward IMF

    Directory of Open Access Journals (Sweden)

    H. Korth

    2005-06-01

    Full Text Available We present a case study of a prolonged interval of strongly northward orientation of the interplanetary magnetic field on 16 July 2000, 16:00-19:00 UT to characterize the energy exchange between the magnetosphere and ionosphere for conditions associated with minimum solar wind-magnetosphere coupling. With reconnection occurring tailward of the cusp under northward IMF conditions, the reconnection dynamo should be separated from the viscous dynamo, presumably driven by the Kelvin-Helmholtz (KH instability. Thus, these conditions are also ideal for evaluating the contribution of a viscous interaction to the coupling process. We derive the two-dimensional distribution of the Poynting vector radial component in the northern sunlit polar ionosphere from magnetic field observations by the constellation of Iridium satellites together with drift meter and magnetometer observations from the Defense Meteorological Satellite Program (DMSP F13 and F15 satellites. The electromagnetic energy flux is then compared with the particle energy flux obtained from auroral images taken by the far-ultraviolet (FUV instrument on the Imager for Magnetopause to Aurora Global Exploration (IMAGE spacecraft. The electromagnetic energy input to the ionosphere of 51 GW calculated from the Iridium/DMSP observations is eight times larger than the 6 GW due to particle precipitation all poleward of 78° MLAT. This result indicates that the energy transport is significant, particularly as it is concentrated in a small region near the magnetic pole, even under conditions traditionally considered to be quiet and is dominated by the electromagnetic flux. We estimate the contributions of the high and mid-latitude dynamos to both the Birkeland currents and electric potentials finding that high-latitude reconnection accounts for 0.8 MA and 45kV while we attribute <0.2MA and ~5kV to an interaction at lower latitudes having the sense of a viscous interaction. Given that these

  2. SDSS-IV MaNGA: modelling the metallicity gradients of gas and stars - radially dependent metal outflow versus IMF

    Science.gov (United States)

    Lian, Jianhui; Thomas, Daniel; Maraston, Claudia; Goddard, Daniel; Parikh, Taniya; Fernández-Trincado, J. G.; Roman-Lopes, Alexandre; Rong, Yu; Tang, Baitian; Yan, Renbin

    2018-05-01

    In our previous work, we found that only two scenarios are capable of reproducing the observed integrated mass-metallicity relations for the gas and stellar components of local star-forming galaxies simultaneously. One scenario invokes a time-dependent metal outflow loading factor with stronger outflows at early times. The other scenario uses a time-dependent initial mass function (IMF) slope with a steeper IMF at early times. In this work, we extend our study to investigate the radial profile of gas and stellar metallicity in local star-forming galaxies using spatially resolved spectroscopic data from the SDSS-IV MaNGA survey. We find that most galaxies show negative gradients in both gas and stellar metallicity with steeper gradients in stellar metallicity. The stellar metallicity gradients tend to be mass dependent with steeper gradients in more massive galaxies while no clear mass dependence is found for the gas metallicity gradient. Then we compare the observations with the predictions from a chemical evolution model of the radial profiles of gas and stellar metallicities. We confirm that the two scenarios proposed in our previous work are also required to explain the metallicity gradients. Based on these two scenarios, we successfully reproduce the radial profiles of gas metallicity, stellar metallicity, stellar mass surface density, and star formation rate surface density simultaneously. The origin of the negative gradient in stellar metallicity turns out to be driven by either radially dependent metal outflow or IMF slope. In contrast, the radial dependence of the gas metallicity is less constrained because of the degeneracy in model parameters.

  3. FTIR, FT-Raman, FT-NMR and quantum chemical investigations of 3-acetylcoumarin.

    Science.gov (United States)

    Arjunan, V; Sakiladevi, S; Marchewka, M K; Mohan, S

    2013-05-15

    3-Acetylcoumarin (3AC) was synthesised by a Knoevenagel reaction. Conformational analysis using the B3LYP method was also carried out to determine the most stable conformation of the compound. FTIR and FT-Raman spectra of 3AC have been recorded in the range 4000-400 and 4000-100 cm(-1), respectively. (1)H and (13)C NMR spectra have also been recorded. The complete vibrational assignment and analysis of the fundamental modes of the compound were carried out using the experimental FTIR and FT-Raman data and quantum mechanical studies. The experimental vibrational frequencies were compared with the wavenumbers obtained theoretically from the DFT-B3LYP/B3PW91 gradient calculations employing the standard 6-31G(**), high level 6-311++G(**) and cc-pVTZ basis sets for optimised geometry of the compound. The frontier molecular orbital energies of the compound are determined by DFT method. Copyright © 2013 Elsevier B.V. All rights reserved.

  4. Prediction of SYM-H index during large storms by NARX neural network from IMF and solar wind data

    Directory of Open Access Journals (Sweden)

    L. Cai

    2010-02-01

    Full Text Available Similar to the Dst index, the SYM-H index may also serve as an indicator of magnetic storm intensity, but having distinct advantage of higher time-resolution. In this study the NARX neural network has been used for the first time to predict SYM-H index from solar wind (SW and IMF parameters. In total 73 time intervals of great storm events with IMF/SW data available from ACE satellite during 1998 to 2006 are used to establish the ANN model. Out of them, 67 are used to train the network and the other 6 samples for test. Additionally, the NARX prediction model is also validated using IMF/SW data from WIND satellite for 7 great storms during 1995–1997 and 2005, as well as for the July 2000 Bastille day storm and November 2001 superstorm using Geotail and OMNI data at 1 AU, respectively. Five interplanetary parameters of IMF Bz, By and total B components along with proton density and velocity of solar wind are used as the original external inputs of the neural network to predict the SYM-H index about one hour ahead. For the 6 test storms registered by ACE including two super-storms of min. SYM-H<−200 nT, the correlation coefficient between observed and NARX network predicted SYM-H is 0.95 as a whole, even as high as 0.95 and 0.98 with average relative variance of 13.2% and 7.4%, respectively, for the two super-storms. The prediction for the 7 storms with WIND data is also satisfactory, showing averaged correlation coefficient about 0.91 and RMSE of 14.2 nT. The newly developed NARX model shows much better capability than Elman network for SYM-H prediction, which can partly be attributed to a key feedback to the input layer from the output neuron with a suitable length (about 120 min. This feedback means that nearly real information of the ring current status is effectively directed to take part in the prediction of SYM-H index by ANN. The proper history length of the output-feedback may mainly reflect

  5. The temperature signature of an IMF-driven change to the global atmospheric electric circuit (GEC) in the Antarctic troposphere

    Science.gov (United States)

    Freeman, Mervyn; Lam, Mai Mai; Chisham, Gareth

    2017-04-01

    We use National Centers for Environmental Prediction (NCEP)/National Center for Atmospheric Research (NCAR) reanalysis data to show that Antarctic surface air temperature anomalies result from differences in the daily-mean duskward component,By, of the interplanetary magnetic field (IMF). We find the anomalies have strong geographical and seasonal variations. Regional anomalies are evident poleward of 60˚ S and are of diminishing representative peak amplitude from autumn (3.2˚ C) to winter (2.4˚ C) to spring (1.6˚ C) to summer (0.9˚ C). We demonstrate that anomalies of statistically-significant amplitude are due to geostrophic wind anomalies, resulting from the same By changes, moving air across large meridional gradients in zonal mean air temperature between 60 and 80˚ S. Additionally, we find that the mean tropospheric temperature anomaly for geographical latitudes ≤ -70˚ peaks at about 0.7 K and is statistically significant at the 1 - 5% level between air pressures of 1000 and 500 hPa (i.e., ˜0.1 to 5.6 km altitude above sea level) and for time lags with respect to the IMF of up to 7 days. The signature propagates vertically between air pressure p ≥ 850 hPa (≤ 1.5 km) and p = 500 hPa (˜5.6 km). The characteristics of prompt response and vertical propagation within the troposphere have previously been seen in the correlation between the IMF and high-latitude air pressure anomalies, known as the Mansurov effect, at higher statistical significances (1%). We conclude that we have identified the temperature signature of the Mansurov effect in the Antarctic troposphere. Since these tropospheric anomalies have been associated with By-driven anomalies in the electric potential of the ionosphere, we further conclude that they are caused by IMF-induced changes to the global atmospheric electric circuit (GEC). Our results support the view that variations in the ionospheric potential act on the troposphere via the action of resulting variations in the

  6. Prediction of SYM-H index during large storms by NARX neural network from IMF and solar wind data

    Directory of Open Access Journals (Sweden)

    L. Cai

    2010-02-01

    Full Text Available Similar to the Dst index, the SYM-H index may also serve as an indicator of magnetic storm intensity, but having distinct advantage of higher time-resolution. In this study the NARX neural network has been used for the first time to predict SYM-H index from solar wind (SW and IMF parameters. In total 73 time intervals of great storm events with IMF/SW data available from ACE satellite during 1998 to 2006 are used to establish the ANN model. Out of them, 67 are used to train the network and the other 6 samples for test. Additionally, the NARX prediction model is also validated using IMF/SW data from WIND satellite for 7 great storms during 1995–1997 and 2005, as well as for the July 2000 Bastille day storm and November 2001 superstorm using Geotail and OMNI data at 1 AU, respectively. Five interplanetary parameters of IMF Bz, By and total B components along with proton density and velocity of solar wind are used as the original external inputs of the neural network to predict the SYM-H index about one hour ahead. For the 6 test storms registered by ACE including two super-storms of min. SYM-H<−200 nT, the correlation coefficient between observed and NARX network predicted SYM-H is 0.95 as a whole, even as high as 0.95 and 0.98 with average relative variance of 13.2% and 7.4%, respectively, for the two super-storms. The prediction for the 7 storms with WIND data is also satisfactory, showing averaged correlation coefficient about 0.91 and RMSE of 14.2 nT. The newly developed NARX model shows much better capability than Elman network for SYM-H prediction, which can partly be attributed to a key feedback to the input layer from the output neuron with a suitable length (about 120 min. This feedback means that nearly real information of the ring current status is effectively directed to take part in the prediction of SYM-H index by ANN. The proper history length of the output-feedback may mainly reflect on average the characteristic time of ring

  7. Spherically symmetric static spacetimes in vacuum f(T) gravity

    International Nuclear Information System (INIS)

    Ferraro, Rafael; Fiorini, Franco

    2011-01-01

    We show that Schwarzschild geometry remains as a vacuum solution for those four-dimensional f(T) gravitational theories behaving as ultraviolet deformations of general relativity. In the gentler context of three-dimensional gravity, we also find that the infrared-deformed f(T) gravities, like the ones used to describe the late cosmic speed up of the Universe, have as the circularly symmetric vacuum solution a Deser-de Sitter or a Banados, Teitelboim and Zanelli-like spacetime with an effective cosmological constant depending on the infrared scale present in the function f(T).

  8. Noether symmetry approach in f(T, B) teleparallel cosmology

    Energy Technology Data Exchange (ETDEWEB)

    Bahamonde, Sebastian [University College London, Department of Mathematics, London (United Kingdom); Capozziello, Salvatore [Universita di Napoli ' ' Federico II' ' , Dipartimento di Fisica, Naples (Italy); Gran Sasso Science Institute, L' Aquila (Italy); Compl. Univ. di Monte S. Angelo, Naples (Italy); INFN, Napoli (Italy)

    2017-02-15

    We consider the cosmology derived from f(T, B) gravity where T is the torsion scalar and B = (2)/(e)∂{sub μ}(eT{sup μ}) a boundary term. In particular we discuss how it is possible to recover, under the same standard, the teleparallel f(T) gravity, the curvature f(R) gravity, and the teleparallel-curvature f(R, T) gravity, which are particular cases of f(T, B). We adopt the Noether Symmetry Approach to study the related dynamical systems and to find cosmological solutions. (orig.)

  9. Static solutions with spherical symmetry in f(T) theories

    International Nuclear Information System (INIS)

    Wang Tower

    2011-01-01

    The spherically symmetric static solutions are searched for in some f(T) models of gravity theory with a Maxwell term. To do this, we demonstrate that reconstructing the Lagrangian of f(T) theories is sensitive to the choice of frame, and then we introduce a particular frame based on the conformally Cartesian coordinates. In this particular frame, the existence conditions of various solutions are presented. Our results imply that only a limited class of f(T) models can be solved in this frame. For more general models, the search for spherically symmetric static solutions is still an open and challenging problem, hopefully solvable in other frames.

  10. The configuration of the auroral distribution for interplanetary magnetic field Bz northward. 1. IMF Bx and By dependencies as observed by the Viking satellite

    International Nuclear Information System (INIS)

    Eliphinstone, R.D.; Jankowska, K.; Murphree, J.S.; Cogger, L.L.

    1990-01-01

    Viking images obtained throughout 1986 have been utilized in combination with IMP 8 satellite measurements of the interplanetary magnetic fields (IMF) to determine typical northern hemisphere auroral distributions for a variety of IMF B z positive conditions. Varying B y has an effect which is consistent with expected results. That is, B y positive implies high-latitude auroral arcs in the dusk sector while negative B y gives dawn sector polar arcs. A new result gives significant importance to the B x component of the IMF. B x toward the Sun (B y = 0) gives polar arcs on both dawn and dusk with comparatively weak UV emissions. With B x away from the Sun (B y = 0) a single Sun-aligned morning sector polar arc dominates the auroral distribution. Azimuthal angle changes to the IMF of only 45 degree seem to affect the global auroral distribution with time scales of less than 2-3 hours. Poleward boundaries of the aurora were found to have a strong dependence on the IMF azimuthal angle which varied according to the magnetic local time investigated

  11. IMF B(y) and day-night conductivity effects in the expanding polar cap convection model

    Science.gov (United States)

    Moses, J. J.; Gorney, D. J.; Siscoe, G. L.; Crooker, N. U.

    1987-01-01

    During southward B(z) periods the open field line region in the ionosphere (polar cap) expands due to increased dayside merging. Ionospheric plasma flow patterns result which can be classified by the sign of the interplanetary magnetic field (IMF) B(y) component. In this paper, a time-dependent ionospheric convection model is constructed to simulate these flows. The model consists of a spiral boundary with a gap in it. The sign of the IMF B(y) component determines the geometry of the gap. A potential is applied across the gap and distributed around the boundary. A flow results which enters the polar cap through the gap and uniformly pushes the boundary outward. Results of the model show that B(y) effects are greatest near the gap and virtually unnoticeable on the nightside of the polar cap. Adding a day-night ionospheric conductivity gradient concentrates the polar cap electric field toward dawn. The resulting flow curvature gives a sunward component that is independent of B(y). These patterns are shown to be consistent with published observations.

  12. A new strong-lensing galaxy at z=0.066: Another elliptical galaxy with a lightweight IMF

    Science.gov (United States)

    Collier, William P.; Smith, Russell J.; Lucey, John R.

    2018-05-01

    We report the discovery of a new low-redshift galaxy-scale gravitational lens, identified from a systematic search of publicly available MUSE observations. The lens galaxy, 2MASXJ04035024-0239275, is a giant elliptical at z = 0.06604 with a velocity dispersion of σ = 314 km s-1. The lensed source has a redshift of 0.19165 and forms a pair of bright images on either side of the lens centre. The Einstein radius is 1.5 arcsec, projecting to 1.8 kpc, which is just one quarter of the galaxy effective radius. After correcting for an estimated 19 per cent dark matter contribution, we find that the stellar mass-to-light ratio from lensing is consistent with that expected for a Milky Way initial mass function (IMF). Combining the new system with three previously-studied low-redshift lenses of similar σ, the derived mean mass excess factor (relative to a Kroupa IMF) is ⟨α⟩ = 1.09±0.08. With all four systems, the intrinsic scatter in α for massive elliptical galaxies can be limited to <0.32, at 90 per cent confidence.

  13. Data Sources for NetZero Ft Carson Model

    Data.gov (United States)

    U.S. Environmental Protection Agency — Table of values used to parameterize and evaluate the Ft Carson NetZero integrated Model with published reference sources for each value. This dataset is associated...

  14. Contours - MO 2012 Greene County 5ft Contours (SHP)

    Data.gov (United States)

    NSGIC State | GIS Inventory — 5ft cartographic contour file for Greene County, Missouri. This file was created using the elevation data from the 2011 LiDAR flight. It includes indexes for 10, 25,...

  15. Mapping Discrimination Experienced by Indonesian Trans* FtM Persons.

    Science.gov (United States)

    Gordon, Danny; Pratama, Mario Prajna

    2017-01-01

    This work sought to document how Indonesian trans* FtM persons experienced discrimination across the interlinked domains of social networks, religious and educational institutions, employment and the workplace, and health care institutions. Objectives were (1) to map the discrimination experienced by trans* FtM individuals in Indonesia, and (2) to establish the specific priorities of the Indonesian trans* FtM community. In-depth interviews, focus groups, and participant observation was used involving 14 respondents. Findings revealed that respondents experienced othering through rejection, misidentification, harassment, "correction," and bureaucratic discrimination across the five preestablished domains. Health care and a lack of information emerged as areas of particular concern for respondents. This work calls for health care that is sensitive to the needs of trans* FtM people coupled with high-quality information to alleviate the cycles through which discrimination is sustained.

  16. Characterization of Momordica charantia Ussing FT-IR Spectroscopy

    Directory of Open Access Journals (Sweden)

    Attila Keseru

    2016-11-01

    In this paper, because earlier claim shows that the plant used as stomachic, carminative, tonic, antipyretic, antidiabetic, in rheumatoid arthritis and gout, the present investigation was carried to characterized a principal components of plant using FT-IR technique

  17. New static solutions in f(T) theory

    Energy Technology Data Exchange (ETDEWEB)

    Daouda, M.H.; Rodrigues, Manuel E. [Universidade Federal do Espirito Santo, Centro de Ciencias Exatas, Departamento de Fisica, Vitoria, ES (Brazil); Houndjo, M.J.S. [Universidade Federal da Bahia, Instituto de Fisica, Salvador, BA (Brazil)

    2011-11-15

    We consider the equations of motion of an anisotropic space-time in f(T) theory, where T is the torsion. New spherically symmetric solutions of black holes and wormholes are obtained with a constant torsion and for the cases for which the radial pressure is proportional to a real constant, to some algebraic functions f(T) and their derivatives f{sub T}(T), or vanishes identically. (orig.)

  18. A review of the FT distillate pathway in GHGenius

    International Nuclear Information System (INIS)

    2006-01-01

    Fischer-Tropsch (FT) distillates products are now used throughout the world as a commercial fuel. However, lifecycle greenhouse gas (GHG) emissions from FT distillates fuels are higher than diesel fuel produced from crude oil. This paper provided details of a lifecycle analysis of FT distillates pathways created for GHGenius, a model used to analyze emissions from a variety of combustion sources. The study examined values reported in tests conducted by major oil and gas operators and described the conversion technologies typically used at FT distillates production facilities. Summaries of reports on FT distillates emissions were also provided. Three primary factors were identified that contributed to different results reported for FT distillates emissions: (1) the efficiency of the conversion process; (2) the allocation procedure used in the conventional oil refinery for the emissions of individual products; and (3) the emissions associated with natural gas production. The GHGenius model was used to quantify the impact of the 3 main factors. An alternative system expansion methodology was used to compare crude oil diesel pathways with a high efficiency, low gas leak scenario in order to achieve high values reported by some oil and gas operators. 5 refs., 5 tabs., 5 figs

  19. Radiotherapy combined with Tegafur (FT-207s) for brain tumors

    International Nuclear Information System (INIS)

    Aoki, Yoshiro

    1981-01-01

    5-Fluorouracil (5-FU) has anti-tumor effects as an anti-metabolite, but it cannot pass the Blood-Brain-Barrier (BBB). FT-207 a masked-compound of 5-FU, is easily lipid soluble and is able to pass the BBB. Twenty eight patients of primary brain tumor and 8 patients of metastatic brain tumor were treated with irradiation combined with 750 mg of FT-207 suppository. Twenty four patients of primary brain tumor were treated only with irradiation as control. The mean survival time was 20.4 +- 11.8 months for the combined therapy group and 17.6 +- 8.6 months for the control. The concentration of FT-207 and 5-FU in serum and in cerebrospinal fluid (CSF) was investigated after administration of 750 mg of FT-207 suppository per annum. The maximum concentration of FT-207 and of 5-FU in serum was 20.4 +- 11.8 mcg/ml and 0.06 +- 0.02 mcg/ml, respectively. There were observed several side effects, such as anorexia, nausea, exanthema and etc. These side effects were not so great as to interrupt the therapy at the dose level of 750 mg of FT-207. However, at the dose of 1500 mg, one case showed disturbance of consciousness, to which attention should be called. (author)

  20. Determination of serum free thyroxine concentration (FT4) by means of fT4-fraction and total thyroxine concentration

    International Nuclear Information System (INIS)

    Passath, A.; Leb, G.

    1985-01-01

    A new equilibrium assay for the determination of serum free thyroxine was evaluated in 514 patients. The assay comprises a two-vial-procedure to measure total thyroxine and free thyroxine fraction by use of monoclonal antibodies. Free thyroxine concentrations are calculated from fT 4 -fraction and total thyroxine concentration readings. In euthyroidism the average free thyroxine fraction (%fT 4 ) was 0.011%, in hyperthyroidism this fraction was elevated, in hypothyroidism it was below normal. In patients with TBG anomalies, TBG values were inversely correlated with fT 4 fraction readings. The 'euthyroid reference range' of FT 4 (SPAC ET) was between 0.70 to 1.78ng/dl. This euthyroid range of FT 4 was determined from TT 4 concentrations measured by T 4 -RIA (SPAC T 4 MONO) which were 30% above TT 4 values measured by conventional T 4 -RIA (SPAC T 4 POLY; polyclonal antibodies). However, a different euthyroid range of FT 4 between 0.55 to 1.30 ng/dl was observed as well as by other investigators when conventional T 4 -RIA measurements were used for calculation of FT 4 values. Our results indicate that calculated FT 4 concentration values are highly dependent on the methods used for determination of total thyroxine concentrations. Precision and reproducability of this two vial equilibrium assay did not meet the requirements mandatory for the application as a clinical routine diagnostic procedure, and its general use for this purpose can as yet not be recommended. (Author)

  1. FT-Raman and FT-Infrared investigations of archaeological artefacts from Foeni Neolithic site (Banat, Romania)

    OpenAIRE

    Simona Cîntă Pînzaru; Dana Pop; Loredana Nemeth

    2008-01-01

    An impressive collection of chert artefacts from the Foeni Neolithic archaeological site (Timiş County, Banat region, Romania) is hosted by the Banat Museum in Timişoara. A representative set of seven specimens was non-destructively investigated using FT-Raman and ATR-FT-IR spectroscopy. The research was carried out for checking if these readily-available, non-destructive, fast, and cheap methods, which do not require preliminary sample preparation could provide significant information for ch...

  2. FT-Raman and FT-IR studies of 1:2.5 piroxicam: β-cyclodextrin inclusion compound

    Science.gov (United States)

    Bertoluzza, A.; Rossi, M.; Taddei, P.; Redenti, E.; Zanol, M.; Ventura, P.

    1999-05-01

    The FT-Raman and FT-IR spectra of amorphous 1:2.5 piroxicam (P): β-cyclodextrin (βCD) inclusion compound (PβCD) are presented and discussed in comparison with the spectra of the three main modifications of piroxicam (α,β and monohydrate). In the 1700-1200 cm -1 FT-Raman spectrum of 1:2.5 PβCD inclusion compound the bands of βCD are weak and covered by those stronger of piroxicam, differently from the FT-IR spectrum where the bands of βCD are stronger, so covering a large part of the spectrum. Typical FT-Raman marker bands are assigned for the characterization of the three modifications of piroxicam. The FT-Raman spectrum of 1:2.5 PβCD inclusion compound predominantly shows the bands at about 1465 and 1400 cm -1 of the monohydrate, indicating that piroxicam assumes the zwitterionic structure stabilized by interaction with βCD via electrostatic and hydrogen bonds. The dipolar character of 1:2.5 PβCD inclusion compound improves the solubility and the dissolution rate of piroxicam and thus its rate of absorption.

  3. Phase portraits of general f(T) cosmology

    Science.gov (United States)

    Awad, A.; El Hanafy, W.; Nashed, G. G. L.; Saridakis, Emmanuel N.

    2018-02-01

    We use dynamical system methods to explore the general behaviour of f(T) cosmology. In contrast to the standard applications of dynamical analysis, we present a way to transform the equations into a one-dimensional autonomous system, taking advantage of the crucial property that the torsion scalar in flat FRW geometry is just a function of the Hubble function, thus the field equations include only up to first derivatives of it, and therefore in a general f(T) cosmological scenario every quantity is expressed only in terms of the Hubble function. The great advantage is that for one-dimensional systems it is easy to construct the phase space portraits, and thus extract information and explore in detail the features and possible behaviours of f(T) cosmology. We utilize the phase space portraits and we show that f(T) cosmology can describe the universe evolution in agreement with observations, namely starting from a Big Bang singularity, evolving into the subsequent thermal history and the matter domination, entering into a late-time accelerated expansion, and resulting to the de Sitter phase in the far future. Nevertheless, f(T) cosmology can present a rich class of more exotic behaviours, such as the cosmological bounce and turnaround, the phantom-divide crossing, the Big Brake and the Big Crunch, and it may exhibit various singularities, including the non-harmful ones of type II and type IV. We study the phase space of three specific viable f(T) models offering a complete picture. Moreover, we present a new model of f(T) gravity that can lead to a universe in agreement with observations, free of perturbative instabilities, and applying the Om(z) diagnostic test we confirm that it is in agreement with the combination of SNIa, BAO and CMB data at 1σ confidence level.

  4. Controlling of merging electric field and IMF magnitude on storm-time changes in thermospheric mass density

    Directory of Open Access Journals (Sweden)

    Y. L. Zhou

    2013-01-01

    Full Text Available The controls of merging electrical field, Em, and IMF (interplanetary magnetic field magnitude, B, on the storm-time changes in upper thermospheric mass density are statistically investigated using GRACE accelerometer observations and the OMNI data of solar wind and IMF for 35 great storms during 2002–2006. It reveals the following: (1 The correlation coefficients between the air mass density changes and the parameters of Em and B are generally larger at lower latitudes than at higher latitudes, and larger in noon and midnight sectors than in dawn and dusk. (2 The most likely delay time (MLDT of mass density changes in respect to Em is about 1.5 h (4.5 h at high (low latitudes, having no distinct local time dependence, while it is 6 h at middle latitudes in all the local time sectors except for noon, which is longer than at low latitudes. A similar fact of longer delay time at mid-latitude is also seen for B. The MLDTs for B at various latitudes are all local time dependent distinctly with shorter delay time in noon/midnight sector and larger in dawn/dusk. Despite of widely spread of the delay time, IMF B exhibits still larger correlation coefficients with mass density changes among the interplanetary parameters. (3 The linear control factor of B on the density changes increases for large B, in contrast to somewhat saturation trend for larger Em. (4 The influence of B and Em on the mass densities shows different behavior for different types of storms. The influence intensity of Em is much stronger for CIR-driven than for CME-driven storm, while it is not so distinct for B. On the local time asymmetry of the influence, both Em and B have largest influence at noon sector for CME-driven storms, while an obviously larger intensification of the influence is found in dawn/dusk sector during CIR storms, especially for parameter Em.

  5. Clinical significance of changes of serum FT3, FT4 and SIL-2R levels after treatment in patients with hyperthyroidism

    International Nuclear Information System (INIS)

    Ye Qing

    2008-01-01

    Objective: To explore the clinical significance of changes of serum FT 3 , FT 4 , SIL-2R levels after treatment in patients with hyperthyroidism. Methods: Serum FT 3 , FT 4 , TSH (with RIA) and SIL-2R (with ELISA) levels were measured in 55 patients with hyperthyroidism both before and after treatment as well as in 35 controls. Results: Before treatment, in the patients the serum FT 3 , FT 4 , SIL-2R levels were significantly higher than those in the controls (P 3 , FT 4 , SIL-2 levels were not significantly different from those in controls (P>0.05). Conclusion: Detection of serum FT 3 , FT 4 , SIL-2R levels is valuable for treatment outcome prediction in patients with hyperthyroidism. (authors)

  6. Extended period of polar cap auroral display: auroral dynamics and relation to the IMF and the ionospheric convection

    Directory of Open Access Journals (Sweden)

    V. G. Vorobjev

    Full Text Available An unusually extended period (5 h of polar cap auroral display on 3 August 1986 is examined. Auroras have been investigated using ground-based data as well as measurements from the IMP-8 spacecraft in interplanetary space and simultaneous observations from the polar-orbiting satellites Viking and DE-1 in the northern and southern hemispheres, respectively. It is found that visible Sun-aligned arcs are located inside the transpolar band of the θ-aurora observed from the satellite in ultraviolet wavelengths. The transpolar band can contain several Sun-aligned arcs that move inside the band toward the morning or evening side of the auroral oval independent of the direction of the band movement. Intensifications of polar cap auroras with durations of up to about 30 min are observed. No change has been found in either IMF parameters or substorm activity that can be related to these intensifications. The θ-aurora occurred during a 2-h period when the B z-component of the IMF was negative. A tendency is noted for dawnward (duskward displacement of the transpolar band when By>0 (By<0 in the southern hemisphere. Simultaneous observations of auroral ovals during interplanetary Bz<0, By<0 and Bx>0 in both hemispheres and convection patterns for Bz<0 and By<0 have been displayed using satellite and ground-based measurements. It was found that the transpolar band of the -aurora in the sunlit hemisphere was situated in the region of large-scale downward Birkeland currents.

  7. Extended period of polar cap auroral display: auroral dynamics and relation to the IMF and the ionospheric convection

    Directory of Open Access Journals (Sweden)

    V. G. Vorobjev

    1995-08-01

    Full Text Available An unusually extended period (5 h of polar cap auroral display on 3 August 1986 is examined. Auroras have been investigated using ground-based data as well as measurements from the IMP-8 spacecraft in interplanetary space and simultaneous observations from the polar-orbiting satellites Viking and DE-1 in the northern and southern hemispheres, respectively. It is found that visible Sun-aligned arcs are located inside the transpolar band of the θ-aurora observed from the satellite in ultraviolet wavelengths. The transpolar band can contain several Sun-aligned arcs that move inside the band toward the morning or evening side of the auroral oval independent of the direction of the band movement. Intensifications of polar cap auroras with durations of up to about 30 min are observed. No change has been found in either IMF parameters or substorm activity that can be related to these intensifications. The θ-aurora occurred during a 2-h period when the B z-component of the IMF was negative. A tendency is noted for dawnward (duskward displacement of the transpolar band when By>0 (By<0 in the southern hemisphere. Simultaneous observations of auroral ovals during interplanetary Bz<0, By<0 and Bx>0 in both hemispheres and convection patterns for Bz<0 and By<0 have been displayed using satellite and ground-based measurements. It was found that the transpolar band of the -aurora in the sunlit hemisphere was situated in the region of large-scale downward Birkeland currents.

  8. Convection and field-aligned currents, related to polar cap arcs, during strongly northward IMF (11 January 1983)

    International Nuclear Information System (INIS)

    Israelevich, P.L.; Podgorny, I.M.; Kuzmin, A.K.; Nikolaeva, N.S.; Dubinin, E.M.

    1988-01-01

    Electric and magnetic fields and auroral emissions have been measured by the Intercosmos-Bulgaria-1300 satellite on 10-11 January 1983. The measured distributions of the plasma drift velocity show that viscous convection is diminished in the evening sector under IMF B y y > 0. A number of sun-aligned polar cap arcs were observed at the beginning of the period of strongly northward IMF and after a few hours a θ-aurora appeared. The intensity of ionized oxygen emission increased significantly reaching up to several kilo-Rayleighs in the polar cap arc. A complicated pattern of convection and field-aligned currents existed in the nightside polar cap which differed from the four-cell model of convection and NBZ field-aligned current system. This pattern was observed during 12 h and could be interpreted as six large scale field-aligned current sheets and three convective vortices inside the polar cap. Sun-aligned polar cap arcs may be located in regions both of sunward and anti-sunward convection. Structures of smaller spatial scale-correspond to the boundaries of hot plasma regions related to polar cap arcs. Obviously these structures are due to S-shaped distributions of electric potential. Parallel electric fields in these S-structures provide electron acceleration up to 1 keV at the boundaries of polar cap arcs. The pairs of field-aligned currents correspond to those S-structures: a downward current at the external side of the boundary and an upward current at the internal side of it. (author)

  9. A Vortical Dawn Flank Boundary Layer for Near-Radial IMF: Wind Observations on 24 October 2001

    Science.gov (United States)

    Farrugia, C. J.; Gratton, F. T.; Gnavi, G.; Torbert, R. B.; Wilson, Lynn B., III

    2014-01-01

    We present an example of a boundary layer tailward of the dawn terminator which is entirely populated by rolled-up flow vortices. Observations were made by Wind on 24 October 2001 as the spacecraft moved across the region at the X plane approximately equal to -13 Earth radii. Interplanetary conditions were steady with a near-radial interplanetary magnetic field (IMF). Approximately 15 vortices were observed over the 1.5 hours duration of Wind's crossing, each lasting approximately 5 min. The rolling up is inferred from the presence of a hot tenuous plasma being accelerated to speeds higher than in the adjoining magnetosheath, a circumstance which has been shown to be a reliable signature of this in single-spacecraft observations. A blob of cold dense plasma was entrained in each vortex, at whose leading edge abrupt polarity changes of field and velocity components at current sheets were regularly observed. In the frame of the average boundary layer velocity, the dense blobs were moving predominantly sunward and their scale size along the X plane was approximately 7.4 Earth radii. Inquiring into the generation mechanism of the vortices, we analyze the stability of the boundary layer to sheared flows using compressible magnetohydrodynamic Kelvin-Helmholtz theory with continuous profiles for the physical quantities. We input parameters from (i) the exact theory of magnetosheath flow under aligned solar wind field and flow vectors near the terminator and (ii) the Wind data. It is shown that the configuration is indeed Kelvin-Helmholtz (KH) unstable. This is the first reported example of KH-unstable waves at the magnetopause under a radial IMF.

  10. THE SL2S GALAXY-SCALE LENS SAMPLE. V. DARK MATTER HALOS AND STELLAR IMF OF MASSIVE EARLY-TYPE GALAXIES OUT TO REDSHIFT 0.8

    Energy Technology Data Exchange (ETDEWEB)

    Sonnenfeld, Alessandro; Treu, Tommaso [Physics Department, University of California, Santa Barbara, CA 93106 (United States); Marshall, Philip J. [Kavli Institute for Particle Astrophysics and Cosmology, P.O. Box 20450, MS29, Stanford, CA 94309 (United States); Suyu, Sherry H. [Institute of Astronomy and Astrophysics, Academia Sinica, P.O. Box 23-141, Taipei 10617, Taiwan (China); Gavazzi, Raphaël [Institut d' Astrophysique de Paris, UMR7095 CNRS-Université Pierre et Marie Curie, 98bis bd Arago, F-75014 Paris (France); Auger, Matthew W. [Institute of Astronomy, University of Cambridge, Madingley Road, Cambridge CB3 0HA (United Kingdom); Nipoti, Carlo, E-mail: sonnen@physics.ucsb.edu [Department of Physics and Astronomy, Bologna University, viale Berti-Pichat 6/2, I-40127 Bologna (Italy)

    2015-02-20

    We investigate the cosmic evolution of the internal structure of massive early-type galaxies over half of the age of the universe. We perform a joint lensing and stellar dynamics analysis of a sample of 81 strong lenses from the Strong Lensing Legacy Survey and Sloan ACS Lens Survey and combine the results with a hierarchical Bayesian inference method to measure the distribution of dark matter mass and stellar initial mass function (IMF) across the population of massive early-type galaxies. Lensing selection effects are taken into account. We find that the dark matter mass projected within the inner 5 kpc increases for increasing redshift, decreases for increasing stellar mass density, but is roughly constant along the evolutionary tracks of early-type galaxies. The average dark matter slope is consistent with that of a Navarro-Frenk-White profile, but is not well constrained. The stellar IMF normalization is close to a Salpeter IMF at log M {sub *} = 11.5 and scales strongly with increasing stellar mass. No dependence of the IMF on redshift or stellar mass density is detected. The anti-correlation between dark matter mass and stellar mass density supports the idea of mergers being more frequent in more massive dark matter halos.

  11. BOOSTING LY α   AND He ii λ 1640 LINE FLUXES FROM POPULATION III GALAXIES: STOCHASTIC IMF SAMPLING AND DEPARTURES FROM CASE-B

    International Nuclear Information System (INIS)

    Mas-Ribas, Lluís; Dijkstra, Mark; Forero-Romero, Jaime E.

    2016-01-01

    We revisit calculations of nebular hydrogen Ly α and He ii λ 1640 line strengths for Population III (Pop III) galaxies, undergoing continuous, and bursts of, star formation. We focus on initial mass functions (IMFs) motivated by recent theoretical studies, which generally span a lower range of stellar masses than earlier works. We also account for case-B departures and the stochastic sampling of the IMF. In agreement with previous work, we find that departures from case-B can enhance the Ly α flux by a factor of a few, but we argue that this enhancement is driven mainly by collisional excitation and ionization, and not due to photoionization from the n  = 2 state of atomic hydrogen. The increased sensitivity of the Ly α flux to the high-energy end of the galaxy spectrum makes it more subject to stochastic sampling of the IMF. The latter introduces a dispersion in the predicted nebular line fluxes around the deterministic value by as much as a factor of ∼4. In contrast, the stochastic sampling of the IMF has less impact on the emerging Lyman Werner photon flux. When case-B departures and stochasticity effects are combined, nebular line emission from Pop III galaxies can be up to one order of magnitude brighter than predicted by “standard” calculations that do not include these effects. This enhances the prospects for detection with future facilities such as the James Webb Space Telescope and large, ground-based telescopes.

  12. Boosting Lyα and He II λ1640 Line Fluxes from Population III Galaxies: Stochastic IMF Sampling and Departures from Case-B

    Science.gov (United States)

    Mas-Ribas, Lluís; Dijkstra, Mark; Forero-Romero, Jaime E.

    2016-12-01

    We revisit calculations of nebular hydrogen Lyα and He II λ1640 line strengths for Population III (Pop III) galaxies, undergoing continuous, and bursts of, star formation. We focus on initial mass functions (IMFs) motivated by recent theoretical studies, which generally span a lower range of stellar masses than earlier works. We also account for case-B departures and the stochastic sampling of the IMF. In agreement with previous work, we find that departures from case-B can enhance the Lyα flux by a factor of a few, but we argue that this enhancement is driven mainly by collisional excitation and ionization, and not due to photoionization from the n = 2 state of atomic hydrogen. The increased sensitivity of the Lyα flux to the high-energy end of the galaxy spectrum makes it more subject to stochastic sampling of the IMF. The latter introduces a dispersion in the predicted nebular line fluxes around the deterministic value by as much as a factor of ˜4. In contrast, the stochastic sampling of the IMF has less impact on the emerging Lyman Werner photon flux. When case-B departures and stochasticity effects are combined, nebular line emission from Pop III galaxies can be up to one order of magnitude brighter than predicted by “standard” calculations that do not include these effects. This enhances the prospects for detection with future facilities such as the James Webb Space Telescope and large, ground-based telescopes.

  13. The Non-universality of the Low-mass End of the IMF is Robust against the Choice of SSP Model

    NARCIS (Netherlands)

    Spiniello, C.; Trager, S. C.; Koopmans, L. V. E.

    We perform a direct comparison of two state-of-the art single stellar population (SSP) models that have been used to demonstrate the non-universality of the low-mass end of the initial mass function (IMF) slope. The two public versions of the SSP models are restricted to either solar abundance

  14. Cosmological viability conditions for f(T) dark energy models

    Energy Technology Data Exchange (ETDEWEB)

    Setare, M.R.; Mohammadipour, N., E-mail: rezakord@ipm.ir, E-mail: N.Mohammadipour@uok.ac.ir [Department of Science, University of Kurdistan, Sanandaj (Iran, Islamic Republic of)

    2012-11-01

    Recently f(T) modified teleparallel gravity where T is the torsion scalar has been proposed as the natural gravitational alternative for dark energy. We perform a detailed dynamical analysis of these models and find conditions for the cosmological viability of f(T) dark energy models as geometrical constraints on the derivatives of these models. We show that in the phase space exists two cosmologically viable trajectory which (i) The universe would start from an unstable radiation point, then pass a saddle standard matter point which is followed by accelerated expansion de sitter point. (ii) The universe starts from a saddle radiation epoch, then falls onto the stable matter era and the system can not evolve to the dark energy dominated epoch. Finally, for a number of f(T) dark energy models were proposed in the more literature, the viability conditions are investigated.

  15. Characteristics of merging at the magnetopause inferred from dayside 557.7-nm all-sky images: IMF drivers of poleward moving auroral forms

    Directory of Open Access Journals (Sweden)

    N. C. Maynard

    2006-11-01

    Full Text Available We combine in situ measurements from Cluster with high-resolution 557.7 nm all-sky images from South Pole to investigate the spatial and temporal evolution of merging on the dayside magnetopause. Variations of 557.7 nm emissions were observed at a 6 s cadence at South Pole on 29 April 2003 while significant changes in the Interplanetary Magnetic Field (IMF clock angle were reaching the magnetopause. Electrons energized at merging sites are the probable sources for 557.7 nm cusp emissions. At the same time Cluster was crossing the pre-noon cusp in the Northern Hemisphere. The combined observations confirm results of a previous study that merging events can occur at multiple sites simultaneously and vary asynchronously on time scales of 10 s to 3 min (Maynard et al., 2004. The intensity of the emissions and the merging rate appear to vary with changes in the IMF clock angle, IMF BX and the dynamic pressure of the solar wind. Most poleward moving auroral forms (PMAFs reflect responses to changes in interplanetary medium rather than to local processes. The changes in magnetopause position required by increases in dynamic pressure are mediated by merging and result in the generation of PMAFs. Small (15–20% variations in dynamic pressure of the solar wind are sufficient to launch PMAFs. Changes in IMF BX create magnetic flux compressions and rarefactions in the solar wind. Increases (decreases in IMF BX strengthens |B| near northern (southern hemisphere merging sites thereby enhancing merging rates and triggering PMAFs. When correlating responses in the two hemispheres, the presence of significant IMF BX also requires that different lag-times be applied to ACE measurements acquired ~0.1 AU upstream of Earth. Cluster observations set lag times for merging at Northern Hemisphere sites; post-noon optical emissions set times of Southern Hemisphere merging. All-sky images and magnetohydrodynamic simulations indicate that merging occurs in multiple

  16. Violation of causality in f(T) gravity

    Energy Technology Data Exchange (ETDEWEB)

    Otalora, G. [Pontificia Universidad Catolica de Valparaiso, Instituto de Fisica, Valparaiso (Chile); Reboucas, M.J. [Centro Brasileiro de Pesquisas Fisicas, Rio de Janeiro, RJ (Brazil)

    2017-11-15

    In the standard formulation, the f(T) field equations are not invariant under local Lorentz transformations, and thus the theory does not inherit the causal structure of special relativity. Actually, even locally violation of causality can occur in this formulation of f(T) gravity. A locally Lorentz covariant f(T) gravity theory has been devised recently, and this local causality problem seems to have been overcome. The non-locality question, however, is left open. If gravitation is to be described by this covariant f(T) gravity theory there are a number of issues that ought to be examined in its context, including the question as to whether its field equations allow homogeneous Goedel-type solutions, which necessarily leads to violation of causality on non-local scale. Here, to look into the potentialities and difficulties of the covariant f(T) theories, we examine whether they admit Goedel-type solutions. We take a combination of a perfect fluid with electromagnetic plus a scalar field as source, and determine a general Goedel-type solution, which contains special solutions in which the essential parameter of Goedel-type geometries, m{sup 2}, defines any class of homogeneous Goedel-type geometries. We show that solutions of the trigonometric and linear classes (m{sup 2} < 0 and m = 0) are permitted only for the combined matter sources with an electromagnetic field matter component. We extended to the context of covariant f(T) gravity a theorem which ensures that any perfect-fluid homogeneous Goedel-type solution defines the same set of Goedel tetrads h{sub A}{sup μ} up to a Lorentz transformation. We also showed that the single massless scalar field generates Goedel-type solution with no closed time-like curves. Even though the covariant f(T) gravity restores Lorentz covariance of the field equations and the local validity of the causality principle, the bare existence of the Goedel-type solutions makes apparent that the covariant formulation of f(T) gravity

  17. Astrophysical flows near f(T) gravity black holes

    Energy Technology Data Exchange (ETDEWEB)

    Ahmed, Ayyesha K.; Jamil, Mubasher [National University of Sciences and Technology (NUST), Department of Mathematics, School of Natural Sciences (SNS), Islamabad (Pakistan); Azreg-Ainou, Mustapha [Baskent University, Baglica Campus, Engineering Faculty, Ankara (Turkey); Bahamonde, Sebastian [University College London, Department of Mathematics, London (United Kingdom); Capozziello, Salvatore [Universita di Napoli ' ' Federico II' ' , Dipartimento di Fisica, Naples (Italy); Gran Sasso Science Institute (INFN), L' Aquila (Italy); INFN Sezione di Napoli, Naples (Italy)

    2016-05-15

    In this paper, we study the accretion process for fluids flowing near a black hole in the context of f(T) teleparallel gravity. Specifically, by performing a dynamical analysis by a Hamiltonian system, we are able to find the sonic points. After that, we consider different isothermal test fluids in order to study the accretion process when they are falling onto the black hole. We find that these flows can be classified according to the equation of state and the black hole features. Results are compared in f(T) and f(R) gravity. (orig.)

  18. Organic Scintillator Detector Response Simulations with DRiFT

    Energy Technology Data Exchange (ETDEWEB)

    Andrews, Madison Theresa [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Bates, Cameron Russell [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Mckigney, Edward Allen [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Rising, Michael Evan [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Pinilla, Maria Isabel [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Solomon, Jr., Clell Jeffrey [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Sood, Avneet [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2016-12-19

    Accurate detector modeling is a requirement to design systems in many non-proliferation scenarios; by determining a Detector’s Response Function (DRF) to incident radiation, it is possible characterize measurements of unknown sources. DRiFT is intended to post-process MCNP® output and create realistic detector spectra. Capabilities currently under development include the simulation of semiconductor, gas, and (as is discussed in this work) scintillator detector physics. Energy spectra and pulse shape discrimination (PSD) trends for incident photon and neutron radiation have been reproduced by DRiFT.

  19. Stellar mass spectrum within massive collapsing clumps. II. Thermodynamics and tidal forces of the first Larson core. A robust mechanism for the peak of the IMF

    Science.gov (United States)

    Lee, Yueh-Ning; Hennebelle, Patrick

    2018-04-01

    Context. Understanding the origin of the initial mass function (IMF) of stars is a major problem for the star formation process and beyond. Aim. We investigate the dependence of the peak of the IMF on the physics of the so-called first Larson core, which corresponds to the point where the dust becomes opaque to its own radiation. Methods: We performed numerical simulations of collapsing clouds of 1000 M⊙ for various gas equations of state (eos), paying great attention to the numerical resolution and convergence. The initial conditions of these numerical experiments are varied in the companion paper. We also develop analytical models that we compare to our numerical results. Results: When an isothermal eos is used, we show that the peak of the IMF shifts to lower masses with improved numerical resolution. When an adiabatic eos is employed, numerical convergence is obtained. The peak position varies with the eos, and using an analytical model to infer the mass of the first Larson core, we find that the peak position is about ten times its value. By analyzing the stability of nonlinear density fluctuations in the vicinity of a point mass and then summing over a reasonable density distribution, we find that tidal forces exert a strong stabilizing effect and likely lead to a preferential mass several times higher than that of the first Larson core. Conclusions: We propose that in a sufficiently massive and cold cloud, the peak of the IMF is determined by the thermodynamics of the high-density adiabatic gas as well as the stabilizing influence of tidal forces. The resulting characteristic mass is about ten times the mass of the first Larson core, which altogether leads to a few tenths of solar masses. Since these processes are not related to the large-scale physical conditions and to the environment, our results suggest a possible explanation for the apparent universality of the peak of the IMF.

  20. Coupling FT Raman and FT SERS microscopy with TLC plates for in situ identification of chemical compounds

    Science.gov (United States)

    Caudin, J. P.; Beljebbar, A.; Sockalingum, G. D.; Angiboust, J. F.; Manfait, M.

    1995-11-01

    Direct analysis of sub-femtogram quantities of chemical compounds on thin layer chromatography plates has been made possible by associating Fourier transform Raman microspectroscopy with SERS spectroscopy. The interfacing elements of the FT Raman microscope system are discussed and optimised such that a lateral resolution on the micron scale is achieved in the sample plane. Micro-FT SERS results obtained from a model biological molecule indicate preservation of molecular conformation upon adsorption at the SERS active surface. With NIR radiation it is thus possible to analyse plates with or without fluorescence indicators.

  1. Generalized second law of thermodynamics in f(T) gravity

    Energy Technology Data Exchange (ETDEWEB)

    Karami, K.; Abdolmaleki, A., E-mail: KKarami@uok.ac.ir, E-mail: AAbdolmaleki@uok.ac.ir [Department of Physics, University of Kurdistan, Pasdaran St., Sanandaj (Iran, Islamic Republic of)

    2012-04-01

    We investigate the validity of the generalized second law (GSL) of gravitational thermodynamics in the framework of f(T) modified teleparallel gravity. We consider a spatially flat FRW universe containing only the pressureless matter. The boundary of the universe is assumed to be enclosed by the Hubble horizon. For two viable f(T) models containing f(T) = T+μ{sub 1}((−T)){sup n} and f(T) = T−μ{sub 2}T(1−e{sup βT{sub 0}/T}), we first calculate the effective equation of state and deceleration parameters. Then, (we investigate the null and strong energy conditions and conclude that a sudden future singularity appears in both models. Furthermore, using a cosmographic analysis we check the viability of two models. Finally, we examine the validity of the GSL and find that for both models it) is satisfied from the early times to the present epoch. But in the future, the GSL is violated for the special ranges of the torsion scalar T.

  2. Model FT631 moisture/density combined gauge

    International Nuclear Information System (INIS)

    Ji Changsong; Dai Zhude; Zhang Jianguo; Zhang Enshang; Huang Jiling; Meng Qingbao

    1990-01-01

    Model FT631 Moisture/Density Combined Gauge has been developed, with which both water content and density, the two parameters of measured medium (soil), are obtained in one act of measurement at the same time. A China patent has been taken for this invention

  3. Vibrational microspectroscopy of food. Raman vs. FT-IR

    DEFF Research Database (Denmark)

    Thygesen, Lisbeth Garbrecht; Løkke, Mette Marie; Micklander, Elisabeth

    2003-01-01

    . The high spatial resolution makes it possible to study areas down to approximately 10x10 mum with FT-IR microspectroscopy and approximately 1 x 1 mum with Raman microspectroscopy. This presentation highlights the advantages and disadvantages of the two microspectroscopic techniques when applied...

  4. Analysis of organophosphorus pesticides using FT-NMR

    International Nuclear Information System (INIS)

    Miyata, Yoshihiko; Takahashi, Yoshikazu; Ando, Hiroaki

    1988-01-01

    A rapid and highly selective method of the identification of 23 kinds of organophosphorus pesticides was develop by using 31 P FT-NMR with 1 H complete decoupling method. Chemical shifts referenced by 85 % H 3 PO 4 were within -4 to 100 ppm, and there was no overlapping among the organophosphorus pesticides used in this experiment. (author)

  5. Determination of cellulose I crystallinity by FT-Raman spectroscopy

    Science.gov (United States)

    Umesh P. Agarwal; Richard S. Reiner; Sally A. Ralph

    2009-01-01

    Two new methods based on FT-Raman spectroscopy, one simple, based on band intensity ratio, and the other, using a partial least-squares (PLS) regression model, are proposed to determine cellulose I crystallinity. In the simple method, crystallinity in semicrystalline cellulose I samples was determined based on univariate regression that was first developed using the...

  6. Textural Properties of Agarose Gels described by FT-Rheology

    NARCIS (Netherlands)

    Klein, C.O.; Venema, P.; Sagis, L.M.C.; Linden, van der E.

    2008-01-01

    Large Amplitude Oscillatory Shear was used to determine the non-linear rheological properties of agarose gels. The analysis was performed with the characteristic functions method based on FT-Rheology, that gives access to a physical interpretation of the non-linear regime. This analysis was then

  7. Technical Capability Upgrades to the NASA Langley Research Center 8 ft. by 15 ft. Thermal Vacuum Chamber

    Science.gov (United States)

    Thornblom, Mark N.; Beverly, Joshua; O'Connell, Joseph J.; Duncan, Dwight L.

    2016-01-01

    The 8 ft. by 15 ft. thermal vacuum chamber (TVAC), housed in Building 1250 at the NASA Langley Research Center (LaRC), and managed by the Systems Integration and Test Branch within the Engineering Directorate, has undergone several significant modifications to increase testing capability, safety, and quality of measurements of articles under environmental test. Significant modifications include: a new nitrogen distribution manifold for supplying the shroud and other cold surfaces to liquid nitrogen temperatures; a new power supply and distribution system for accurately controlling a quartz IR lamp suite; a suite of contamination monitoring sensors for outgassing measurements and species identification; a new test article support system; signal and power feed-throughs; elimination of unnecessary penetrations; and a new data acquisition and control commanding system including safety interlocks. This paper will provide a general overview of the LaRC 8 ft. by 15 ft. TVAC chamber, an overview of the new technical capabilities, and will illustrate each upgrade in detail, in terms of mechanical design and predicted performance. Additionally, an overview of the scope of tests currently being performed in the chamber will be documented, and sensor plots from tests will be provided to show chamber temperature and pressure performance with actual flight hardware under test.

  8. Technical Capability Upgrades to the NASA Langley Research Center 6 ft. by 6 ft. Thermal Vacuum Chamber

    Science.gov (United States)

    Thornblom, Mark N.; Beverly, Joshua; O'Connell, Joseph J.; Mau, Johnny C.; Duncan, Dwight L.

    2014-01-01

    The 6 ft. by 6 ft. thermal vacuum chamber (TVAC), housed in Building 1250 at the NASA Langley Research Center (LaRC), and managed by the Systems Integration and Test Branch within the Engineering Directorate, has undergone several significant modifications to increase testing capability, safety, and quality of measurements of articles under environmental test. Significant modifications include: a new nitrogen thermal conditioning unit for controlling shroud temperatures from -150degC to +150degC; two horizontal auxiliary cold plates for independent temperature control from -150degC to +200degC; a suite of contamination monitoring sensors for outgassing measurements and species identification; signal and power feed-throughs; new pressure gauges; and a new data acquisition and control commanding system including safety interlocks. This presentation will provide a general overview of the LaRC 6 ft. by 6 ft. TVAC chamber, an overview of the new technical capabilities, and illustrate each upgrade in detail, in terms of mechanical design and predicted performance. Additionally, an overview of the scope of tests currently being performed in the chamber will be documented, and sensor plots from tests will be provided to show chamber temperature and pressure performance with actual flight hardware under test.

  9. Isolation and functional characterization of JcFT, a FLOWERING LOCUS T (FT) homologous gene from the biofuel plant Jatropha curcas.

    Science.gov (United States)

    Li, Chaoqiong; Luo, Li; Fu, Qiantang; Niu, Longjian; Xu, Zeng-Fu

    2014-05-08

    Physic nut (Jatropha curcas L.) is a potential feedstock for biofuel production because Jatropha oil is highly suitable for the production of the biodiesel and bio-jet fuels. However, Jatropha exhibits low seed yield as a result of unreliable and poor flowering. FLOWERING LOCUS T (FT) -like genes are important flowering regulators in higher plants. To date, the flowering genes in Jatropha have not yet been identified or characterized. To better understand the genetic control of flowering in Jatropha, an FT homolog was isolated from Jatropha and designated as JcFT. Sequence analysis and phylogenetic relationship of JcFT revealed a high sequence similarity with the FT genes of Litchi chinensis, Populus nigra and other perennial plants. JcFT was expressed in all tissues of adult plants except young leaves, with the highest expression level in female flowers. Overexpression of JcFT in Arabidopsis and Jatropha using the constitutive promoter cauliflower mosaic virus 35S or the phloem-specific promoter Arabidopsis SUCROSE TRANSPORTER 2 promoter resulted in an extremely early flowering phenotype. Furthermore, several flowering genes downstream of JcFT were up-regulated in the JcFT-overexpression transgenic plant lines. JcFT may encode a florigen that acts as a key regulator in flowering pathway. This study is the first to functionally characterize a flowering gene, namely, JcFT, in the biofuel plant Jatropha.

  10. FT-IR Microspectroscopy of Rat Ear Cartilage.

    Directory of Open Access Journals (Sweden)

    Benedicto de Campos Vidal

    Full Text Available Rat ear cartilage was studied using Fourier transform-infrared (FT-IR microspectroscopy to expand the current knowledge which has been established for relatively more complex cartilage types. Comparison of the FT-IR spectra of the ear cartilage extracellular matrix (ECM with published data on articular cartilage, collagen II and 4-chondroitin-sulfate standards, as well as of collagen type I-containing dermal collagen bundles (CBs with collagen type II, was performed. Ear cartilage ECM glycosaminoglycans (GAGs were revealed histochemically and as a reduction in ECM FT-IR spectral band heights (1140-820 cm-1 after testicular hyaluronidase digestion. Although ear cartilage is less complex than articular cartilage, it contains ECM components with a macromolecular orientation as revealed using polarization microscopy. Collagen type II and GAGs, which play a structural role in the stereo-arrangement of the ear cartilage, contribute to its FT-IR spectrum. Similar to articular cartilage, ear cartilage showed that proteoglycans add a contribution to the collagen amide I spectral region, a finding that does not recommend this region for collagen type II quantification purposes. In contrast to articular cartilage, the symmetric stretching vibration of -SO3- groups at 1064 cm-1 appeared under-represented in the FT-IR spectral profile of ear cartilage. Because the band corresponding to the asymmetric stretching vibration of -SO3- groups (1236-1225 cm-1 overlapped with that of amide III bands, it is not recommended for evaluation of the -SO3- contribution to the FT-IR spectrum of the ear cartilage ECM. Instead, a peak (or shoulder at 1027-1016 cm-1 could be better considered for this intent. Amide I/amide II ratios as calculated here and data from the literature suggest that protein complexes of the ear cartilage ECM are arranged with a lower helical conformation compared to pure collagen II. The present results could motivate further studies on this tissue

  11. FT-NIR: A Tool for Process Monitoring and More.

    Science.gov (United States)

    Martoccia, Domenico; Lutz, Holger; Cohen, Yvan; Jerphagnon, Thomas; Jenelten, Urban

    2018-03-30

    With ever-increasing pressure to optimize product quality, to reduce cost and to safely increase production output from existing assets, all combined with regular changes in terms of feedstock and operational targets, process monitoring with traditional instruments reaches its limits. One promising answer to these challenges is in-line, real time process analysis with spectroscopic instruments, and above all Fourier-Transform Near Infrared spectroscopy (FT-NIR). Its potential to afford decreased batch cycle times, higher yields, reduced rework and minimized batch variance is presented and application examples in the field of fine chemicals are given. We demonstrate that FT-NIR can be an efficient tool for improved process monitoring and optimization, effective process design and advanced process control.

  12. Constraining f(T) gravity in the Solar System

    Energy Technology Data Exchange (ETDEWEB)

    Iorio, Lorenzo [Ministero dell' Istruzione dell' Università e della Ricerca (M.I.U.R), Viale Unità di Italia 68, 70125 Bari (Italy); Radicella, Ninfa [Dipartimento di Fisica E.R. Caianiello, Università di Salerno, Via Giovanni Paolo II 132, Fisciano (Italy); Ruggiero, Matteo Luca, E-mail: lorenzo.iorio@libero.it, E-mail: ninfa.radicella@sa.infn.it, E-mail: matteo.ruggiero@polito.it [DISAT, Politecnico di Torino, Corso Duca degli Abruzzi 24, Torino (Italy)

    2015-08-01

    In the framework of f(T) theories of gravity, we solve the field equations for f(T)=T+α T{sup n} in the weak-field approximation and for spherical symmetry spacetime. Since f(T)=T corresponds to Teleparallel Gravity, which is equivalent to General Relativity, the non linearity of the Lagrangian are expected to produce perturbations of the general relativistic solutions, parameterized by α. Hence, we use the f(T) solutions to model the gravitational field of the Sun and exploit data from accurate radio-tracking of spacecrafts orbiting Mercury and Saturn to infer preliminary bounds on the model parameter α and on the cosmological constant Λ.

  13. In vivo release of FT-207 from irradiation polymerized composites

    International Nuclear Information System (INIS)

    Xie Huaijiang; Kou Qinghe; Song Juzhong; Peng Tao; Chen Xiaohui; Zhang Dexi

    1999-01-01

    Polymer-drugs composite with long periods of controlled slow release was made by radiation induced polymerization in room temperature. In experiment in vivo, the composite was implanted subcutaneously the back of rabbits. The concentration of 1-(2-tetrahydrofuryl)-5-fluorouracil (FT-207) was determined by HPLC. The results of test showed that the concentration of serum drug is 1.0 μg/mL after 1 week in the polymer-drug composites group. The drug concentration of tissue surrounding the composites is 76.2 +- 10.4 μg/mL. The drug concentration in the far organ (e.g.the lung 1.2 +- 0.5 μg/mL) is lower than the tissue surrounding the composite. The serum drug is higher and shorter time by the routine methods. The serum concentration of FT-207 is lower an retarded by implanted

  14. Applications of FT-IR spectrophotometry in cancer diagnostics.

    Science.gov (United States)

    Bunaciu, Andrei A; Hoang, Vu Dang; Aboul-Enein, Hassan Y

    2015-01-01

    This review provides a brief background to the application of infrared spectroscopy, including Fourier transform-infrared spectroscopy, in biological fluids. It is not meant to be complete or exhaustive but to provide the reader with sufficient background for selected applications in cancer diagnostics. Fourier transform-infrared spectroscopy (FT-IR) is a fast and nondestructive analytical method. The infrared spectrum of a mixture serves as the basis to quantitate its constituents, and a number of common clinical chemistry tests have proven to be feasible using this approach. This review focuses on biomedical FT-IR applications, published in the period 2009-2013, used for early detection of cancer through qualitative and quantitative analysis.

  15. FT-IR spectroscopy of lipoproteins—A comparative study

    Science.gov (United States)

    Krilov, Dubravka; Balarin, Maja; Kosović, Marin; Gamulin, Ozren; Brnjas-Kraljević, Jasminka

    2009-08-01

    FT-IR spectra, in the frequency region 4000-600 cm -1, of four major lipoprotein classes: very low density lipoprotein (VLDL), low density lipoprotein (LDL) and two subclasses of high density lipoproteins (HDL 2 and HDL 3) were analyzed to obtain their detailed spectral characterization. Information about the protein domain of particle was obtained from the analysis of amide I band. The procedure of decomposition and curve fitting of this band confirms the data already known about the secondary structure of two different apolipoproteins: apo A-I in HDL 2 and HDL 3 and apo B-100 in LDL and VLDL. For information about the lipid composition and packing of the particular lipoprotein the well expressed lipid bands in the spectra were analyzed. Characterization of spectral details in the FT-IR spectrum of natural lipoprotein is necessary to study the influence of external compounds on its structure.

  16. Laser Spark Formamide Decomposition Studied by FT-IR Spectroscopy

    Czech Academy of Sciences Publication Activity Database

    Ferus, Martin; Kubelík, Petr; Civiš, Svatopluk

    2011-01-01

    Roč. 115, č. 44 (2011), s. 12132-12141 ISSN 1089-5639 R&D Projects: GA AV ČR IAA400400705; GA AV ČR IAAX00100903; GA ČR GAP208/10/2302 Institutional research plan: CEZ:AV0Z40400503 Keywords : FT-IR spectroscopy * high-power laser * induced dielectric-breakdown Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 2.946, year: 2011

  17. Generalized Noether symmetry in f(T) gravity

    International Nuclear Information System (INIS)

    Mohseni Sadjadi, H.

    2012-01-01

    We consider modified teleparallel gravity (f(T) gravity), as a framework to explain the present accelerated expansion of the universe. The matter component is assumed to be cold dark matter. To find the explicit form of the function f, we utilize generalized Noether theorem and use generalized vector fields as variational symmetries of the corresponding Lagrangian. We study the cosmological consequences of the obtained results.

  18. Wormholes in a viable f(T) gravity

    Energy Technology Data Exchange (ETDEWEB)

    Jamil, Mubasher [National University of Sciences and Technology (NUST), Center for Advanced Mathematics and Physics (CAMP), Islamabad (Pakistan); Eurasian National University, Eurasian International Center for Theoretical Physics, Astana (Kazakstan (Kazakhstan)); Momeni, Davood; Myrzakulov, Ratbay [Eurasian National University, Eurasian International Center for Theoretical Physics, Astana (Kazakstan (Kazakhstan))

    2013-01-15

    In this paper, we derive some new exact solutions of static wormholes in f(T) gravity. We discuss independent cases of the pressure components including isotropic and anisotropic pressure. Lastly we consider radial pressure satisfying a barotropic equation of state. We also check the behavior of null energy condition (NEC) for each case and observe that it is violated for the anisotropic case, while it is satisfied for isotropic and barotropic cases. (orig.)

  19. Completely automated open-path FT-IR spectrometry.

    Science.gov (United States)

    Griffiths, Peter R; Shao, Limin; Leytem, April B

    2009-01-01

    Atmospheric analysis by open-path Fourier-transform infrared (OP/FT-IR) spectrometry has been possible for over two decades but has not been widely used because of the limitations of the software of commercial instruments. In this paper, we describe the current state-of-the-art of the hardware and software that constitutes a contemporary OP/FT-IR spectrometer. We then describe advances that have been made in our laboratory that have enabled many of the limitations of this type of instrument to be overcome. These include not having to acquire a single-beam background spectrum that compensates for absorption features in the spectra of atmospheric water vapor and carbon dioxide. Instead, an easily measured "short path-length" background spectrum is used for calculation of each absorbance spectrum that is measured over a long path-length. To accomplish this goal, the algorithm used to calculate the concentrations of trace atmospheric molecules was changed from classical least-squares regression (CLS) to partial least-squares regression (PLS). For calibration, OP/FT-IR spectra are measured in pristine air over a wide variety of path-lengths, temperatures, and humidities, ratioed against a short-path background, and converted to absorbance; the reference spectrum of each analyte is then multiplied by randomly selected coefficients and added to these background spectra. Automatic baseline correction for small molecules with resolved rotational fine structure, such as ammonia and methane, is effected using wavelet transforms. A novel method of correcting for the effect of the nonlinear response of mercury cadmium telluride detectors is also incorporated. Finally, target factor analysis may be used to detect the onset of a given pollutant when its concentration exceeds a certain threshold. In this way, the concentration of atmospheric species has been obtained from OP/FT-IR spectra measured at intervals of 1 min over a period of many hours with no operator intervention.

  20. Technology development for iron F-T catalysts. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Frame, R.R.; Gala, H.B.

    1994-08-01

    The objectives of this work were twofold. The first objective was to design and construct a pilot plant for preparing precipitated iron oxide F-T precursors and demonstrate that the rate of production from this plant is equivalent to 100 lbs/day of dried metal oxide. Secondly, these precipitates were to be used to prepare catalysts capable of achieving 88% CO + H{sub 2} conversion with {le} 5 mole percent selectivity to methane + ethane.

  1. Computer simulation of FT-NMR multiple pulse experiment

    Science.gov (United States)

    Allouche, A.; Pouzard, G.

    1989-04-01

    Using the product operator formalism in its real form, SIMULDENS expands the density matrix of a scalar coupled nuclear spin system and simulates analytically a large variety of FT-NMR multiple pulse experiments. The observable transverse magnetizations are stored and can be combined to represent signal accumulation. The programming language is VAX PASCAL, but a MacIntosh Turbo Pascal Version is also available.

  2. Computer simulation of FT-NMR multiple pulse experiment

    International Nuclear Information System (INIS)

    Allouche, A.; Pouzard, G.

    1989-01-01

    Using the product operator formalism in its real form, SIMULDENS expands the density matrix of a scalar coupled nuclear spin system and simulates analytically a large variety of FT-NMR multiple pulse experiments. The observable transverse magnetizations are stored and can be combined to represent signal accumulation. The programming language is VAX PASCAL, but a MacIntosh Turbo Pascal Version is also available. (orig.)

  3. Characterization of FLOWERING LOCUS T1 (FT1 gene in Brachypodium and wheat.

    Directory of Open Access Journals (Sweden)

    Bo Lv

    Full Text Available The phase transition from vegetative to reproductive growth is a critical event in the life cycle of flowering plants. FLOWERING LOCUS T (FT plays a central role in the regulation of this transition by integrating signals from multiple flowering pathways in the leaves and transmitting them to the shoot apical meristem. In this study, we characterized FT homologs in the temperate grasses Brachypodium distachyon and polyploid wheat using transgenic and mutant approaches. Downregulation of FT1 by RNAi was associated with a significant downregulation of the FT-like genes FT2 and FT4 in Brachypodium and FT2 and FT5 in wheat. In a transgenic wheat line carrying a highly-expressed FT1 allele, FT2 and FT3 were upregulated under both long and short days. Overexpression of FT1 caused extremely early flowering during shoot regeneration in both Brachypodium and hexaploid wheat, and resulted in insufficient vegetative tissue to support the production of viable seeds. Downregulation of FT1 transcripts by RNA interference (RNAi resulted in non-flowering Brachypodium plants and late flowering plants (2-4 weeks delay in wheat. A similar delay in heading time was observed in tetraploid wheat plants carrying mutations for both FT-A1 and FT-B1. Plants homozygous only for mutations in FT-B1 flowered later than plants homozygous only for mutations in FT-A1, which corresponded with higher transcript levels of FT-B1 relative to FT-A1 in the early stages of development. Taken together, our data indicate that FT1 plays a critical role in the regulation of flowering in Brachypodium and wheat, and that this role is associated with the simultaneous regulation of other FT-like genes. The differential effects of mutations in FT-A1 and FT-B1 on wheat heading time suggest that different allelic combinations of FT1 homoeologs could be used to adjust wheat heading time to improve adaptation to changing environments.

  4. Characterization and identification of microorganisms by FT-IR microspectrometry

    Science.gov (United States)

    Ngo-Thi, N. A.; Kirschner, C.; Naumann, D.

    2003-12-01

    We report on a novel FT-IR approach for microbial characterization/identification based on a light microscope coupled to an infrared spectrometer which offers the possibility to acquire IR-spectra of microcolonies containing only few hundred cells. Microcolony samples suitable for FT-IR microspectroscopic measurements were obtained by a replica technique with a stamping device that transfers spatially accurate cells of microcolonies growing on solid culture plates to a special, IR-transparent or reflecting stamping plate. High quality spectra could be recorded either by applying the transmission/absorbance or the reflectance/absorbance mode of the infrared microscope. Signal to noise ratios higher than 1000 were obtained for microcolonies as small as 40 μm in diameter. Reproducibility levels were established that allowed species and strain identification. The differentiation and classification capacity of the FT-IR microscopic technique was tested for different selected microorganisms. Cluster and factor analysis methods were used to evaluate the complex spectral data. Excellent discrimination between bacteria and yeasts, and at the same time Gram-negative and Gram-positive bacterial strains was obtained. Twenty-two selected strains of different species within the genus Staphylococcus were repetitively measured and could be grouped into correct species cluster. Moreover, the results indicated that the method allows also identifications at the subspecies level. Additionally, the new approach allowed spectral mapping analysis of single colonies which provided spatially resolved characterization of growth heterogeneity within complex microbial populations such as colonies.

  5. Thermodynamics and cosmological reconstruction in f(T , B) gravity

    Science.gov (United States)

    Bahamonde, Sebastian; Zubair, M.; Abbas, G.

    2018-03-01

    Recently, it was formulated a teleparallel theory called f(T , B) gravity which connects both f(T) and f(R) under suitable limits. In this theory, the function in the action is assumed to depend on the torsion scalar T and also on a boundary term related with the divergence of torsion, B = 2∇μTμ. In this work, we study different features of a flat Friedmann-Lemaître-Robertson-Walker (FLRW) cosmology in this theory. First, we show that the FLRW equations can be transformed to the form of Clausius relation TˆhSeff = - dE + WdV, where Tˆh is the horizon temperature and Seff is the entropy which contains contributions both from horizon entropy and an additional entropy term introduced due to the non-equilibrium. We also formulate the constraint for the validity of the generalised second law of thermodynamics (GSLT). Additionally, using a cosmological reconstruction technique, we show that both f(T , B) and - T + F(B) gravity can mimic power-law, de-Sitter and ΛCDM models. Finally, we formulate the perturbed evolution equations and analyse the stability of some important cosmological solutions.

  6. Changes of serum FT3, FT4, sTSH, TRAb, TGA and TMA concentrations in Graves' patients treated with 131I and clinical significances

    International Nuclear Information System (INIS)

    Sun Wenwei; Wei Liqin; Zhao Jie; Ma Qingjie; Sun Hui

    2006-01-01

    Objective: To study the clinical significances of serum FT 3 , FT 4 , sTSH, TRAb, TGA and TMA concentration changes in Graves' patients before and after, 131 I treatment. Methods: The serum FT 3 , FT 4 , sTSH; TRAb, TGA and TMA concentrations before treatment, 3, 6, 12 and 18 months after therapy in 172 Graves' patients and 43 normal controls were obtained by time-resolved fluoroimmunoassay technique. Results: FT 3 and FT 4 concentrations showed an obvious decrease 3 months after treatment, while sTSH and TRAb had remarkable high values, as TGA and TMA demonstrated a trend to increase. FT 3 , FT 4 and sTSH concentrations were close to control group 6 months after treatment, TRAb had a decline trend. All the six indexes approached to normal 18 months after treatment. Conclusion: It is of great of significance for the Graves' patients to accept the developmental observation of serum FT 3 , FT 4 , and sTSH, TRAb, TGA and TMA concentrations before and after 131 I therapy, which provides a great of positive information for therapy guiding, observation and prognosis. (authors)

  7. Characterisation of 1,3-diammonium propylselenate monohydrate by XRD, FT-IR, FT-Raman, DSC and DFT studies

    Science.gov (United States)

    Thirunarayanan, S.; Arjunan, V.; Marchewka, M. K.; Mohan, S.; Atalay, Yusuf

    2016-03-01

    The crystals of 1,3-diammonium propylselenate monohydrate (DAPS) were prepared and characterised X-ray diffraction (XRD), FT-IR, FT-Raman spectroscopy, and DFT/B3LYP methods. It comprises protonated propyl ammonium moieties (diammonium propyl cations), selenate anions and water molecule which are held together by a number of hydrogen bonds and form infinite chains. The XRD data confirm the transfer of two protons from selenic acid to 1,3-diaminopropane molecule. The DAPS complex is stabilised by the presence of O-H···O and N-H···O hydrogen bonds and the electrostatic interactions as well. The N···O and O···O bond distances are 2.82-2.91 and 2.77 Å, respectively. The FT-IR and FT-Raman spectra of 1,3-diammonium propyl selenate monohydrate are recorded and the complete vibrational assignments have been discussed. The geometry is optimised by B3LYP method using 6-311G, 6-311+G and 6-311+G* basis sets and the energy, structural parameters, vibrational frequencies, IR and Raman intensities are determined. Differential scanning colorimetry (DSC) data were also presented to analyse the possibility of the phase transition. Complete natural bonding orbital (NBO) analysis is carried out to analyse the intramolecular electronic interactions and their stabilisation energies. The electrostatic potential of the complex lies in the range +1.902e × 10-2 to -1.902e × 10-2. The limits of total electron density of the complex is +8.43e × 10-2 to -8.43e × 10-2.

  8. FT-Raman and FT-Infrared investigations of archaeological artefacts from Foeni Neolithic site (Banat, Romania

    Directory of Open Access Journals (Sweden)

    Simona Cîntă Pînzaru

    2008-08-01

    Full Text Available An impressive collection of chert artefacts from the Foeni Neolithic archaeological site (Timiş County, Banat region, Romania is hosted by the Banat Museum in Timişoara. A representative set of seven specimens was non-destructively investigated using FT-Raman and ATR-FT-IR spectroscopy. The research was carried out for checking if these readily-available, non-destructive, fast, and cheap methods, which do not require preliminary sample preparation could provide significant information for characterizing the mineral composition of chert artefacts. Based on vibrational data, it was confirmed that the raw material was represented by microcrystalline quartz and moganite, with local concentrations of accessory minerals (calcite, dolomite, and clay minerals. In spite of their wide macroscopic heterogeneity (colour, transparency, based on single point FT-Raman measurements the chert artefacts could not be assigned to distinctive groups of raw silica materials, in order to provide specific arguments for provenance studies. However, the presence of specific accessory minerals (dolomite, illite pointed to distinctive genetic conditions in the case of one lithic material. Sets of measurements (mapping are required for statistically characterizing each artefact specimen. IR data were less significant, due to the rough surface texture of the specimens in contact with the ZnSe crystal of the ATR-FT-IR module. However, illite was identified based solely on its contribution to the IR spectrum. This pioneering study on chert artefacts from Romania based on optical spectroscopic methods shows that there are good premises for a systematic investigation of highly-valuable museum collections, in particular in terms of chert geology.

  9. VT 10 ft Contour Lines generated from bare earth lidar - Chittenden

    Data.gov (United States)

    Vermont Center for Geographic Information — (Link to Metadata) ElevationContours_CN10T (10ft contours) was extracted from ElevationContours_CN2T (2ft contours), which was generated by USGS from the 2004...

  10. Performance Monitoring of a Nearshore Berm at Ft. Myers Beach, Florida

    Science.gov (United States)

    2013-08-01

    Figure 14. Establishing a temporary benchmark. ERDC/CHL TR-13-11 28 Visually estimated vegetation/ toe -of- dune line, MHHW line (identified...sediment samples were taken at the toe of the dune (where present), backbeach, high tide line, mean sea level, low tide line, and then at approximately...2-ft, 4-ft, 6-ft, and 8-ft water depths. In the berm area, surface sediment samples were taken at the toe of the dune (where present), backbeach

  11. Large Scale Earth's Bow Shock with Northern IMF as Simulated by PIC Code in Parallel with MHD Model

    Science.gov (United States)

    Baraka, Suleiman

    2016-06-01

    In this paper, we propose a 3D kinetic model (particle-in-cell, PIC) for the description of the large scale Earth's bow shock. The proposed version is stable and does not require huge or extensive computer resources. Because PIC simulations work with scaled plasma and field parameters, we also propose to validate our code by comparing its results with the available MHD simulations under same scaled solar wind (SW) and (IMF) conditions. We report new results from the two models. In both codes the Earth's bow shock position is found to be ≈14.8 R E along the Sun-Earth line, and ≈29 R E on the dusk side. Those findings are consistent with past in situ observations. Both simulations reproduce the theoretical jump conditions at the shock. However, the PIC code density and temperature distributions are inflated and slightly shifted sunward when compared to the MHD results. Kinetic electron motions and reflected ions upstream may cause this sunward shift. Species distributions in the foreshock region are depicted within the transition of the shock (measured ≈2 c/ ω pi for Θ Bn = 90° and M MS = 4.7) and in the downstream. The size of the foot jump in the magnetic field at the shock is measured to be (1.7 c/ ω pi ). In the foreshocked region, the thermal velocity is found equal to 213 km s-1 at 15 R E and is equal to 63 km s -1 at 12 R E (magnetosheath region). Despite the large cell size of the current version of the PIC code, it is powerful to retain macrostructure of planets magnetospheres in very short time, thus it can be used for pedagogical test purposes. It is also likely complementary with MHD to deepen our understanding of the large scale magnetosphere.

  12. The mass-metallicity relations for gas and stars in star-forming galaxies: strong outflow versus variable IMF

    Science.gov (United States)

    Lian, Jianhui; Thomas, Daniel; Maraston, Claudia; Goddard, Daniel; Comparat, Johan; Gonzalez-Perez, Violeta; Ventura, Paolo

    2018-02-01

    We investigate the mass-metallicity relations for the gaseous (MZRgas) and stellar components (MZRstar) of local star-forming galaxies based on a representative sample from Sloan Digital Sky Survey Data Release 12. The mass-weighted average stellar metallicities are systematically lower than the gas metallicities. This difference in metallicity increases towards galaxies with lower masses and reaches 0.4-0.8 dex at 109 M⊙ (depending on the gas metallicity calibration). As a result, the MZRstar is much steeper than the MZRgas. The much lower metallicities in stars compared to the gas in low-mass galaxies imply dramatic metallicity evolution with suppressed metal enrichment at early times. The aim of this paper is to explain the observed large difference in gas and stellar metallicity and to infer the origin of the mass-metallicity relations. To this end we develop a galactic chemical evolution model accounting for star formation, gas inflow and outflow. By combining the observed mass-metallicity relation for both gas and stellar components to constrain the models, we find that only two scenarios are able to reproduce the observations. Either strong metal outflow or a steep initial mass function (IMF) slope at early epochs of galaxy evolution is needed. Based on these two scenarios, for the first time we successfully reproduce the observed MZRgas and MZRstar simultaneously, together with other independent observational constraints in the local Universe. Our model also naturally reproduces the flattening of the MZRgas at the high-mass end leaving the MZRstar intact, as seen in observational data.

  13. FT4 Data Analysis Summary (SSI-ARC)

    Science.gov (United States)

    Isaacson, Douglas R.; Gong, Chester; Reardon, Scott Edward; Santiago, Confesor

    2016-01-01

    Standards for Unmanned Aircraft System (UAS) Detect-and-Avoid (DAA) systems are currently being developed under the auspices of the RTCA Special Committee 228 (SC-228). To support the development of these standards, a series of flight tests has been conducted at NASAs Armstrong Flight Research Center (NASA-AFRC). The fourth in this series of flight test activities (Flight Test 4, or simply FT4) was conducted during the Spring and Summer of 2016. FT4 supported the objectives of numerous organizations working toward UAS DAA Minimum Operational Performance Standards (MOPS) and UAS DAA Radar MOPS. The summary provided herein is limited to the objectives, analysis and conclusions of the NASA Ames Research Center (NASA-ARC) SSI team toward the refinement of UAS DAA MOPS. This document provides a high-level overview of FT4 and the SSI-ARC objectives, a summary of the data analysis methodology and recommendations for UAS DAA MOPS refinements based on the data analysis results. A total of 72 encounters were flown to support SSI-ARC objectives. Test results were generally consistent with acceptable UAS DAA system performance and will be considered in broader SC-228 requirements validation efforts. Observed alert lead times indicated acceptable UAS DAA alerting performance. Effective interoperability between the UAS DAA system and the Traffic Alert and Collision Avoidance System (TCAS) was observed with one notable exception: TCAS Resolutions Advisories (RA) were observed in the absence of any DAA alert on two occasions, indicating the need for alert parameter refinement. Findings further indicated the need for continued work in the areas of DAA Well Clear Recovery logic and alert stability for Mode-C-only intruders. Finally, results demonstrated a high level of compliance with a set of evaluation criteria designed to provide anecdotal evidence of acceptable UAS DAA system performance.

  14. Differentiation of Leishmania species by FT-IR spectroscopy

    Science.gov (United States)

    Aguiar, Josafá C.; Mittmann, Josane; Ferreira, Isabelle; Ferreira-Strixino, Juliana; Raniero, Leandro

    2015-05-01

    Leishmaniasis is a parasitic infectious disease caused by protozoa that belong to the genus Leishmania. It is transmitted by the bite of an infected female Sand fly. The disease is endemic in 88 countries Desjeux (2001) [1] (16 developed countries and 72 developing countries) on four continents. In Brazil, epidemiological data show the disease is present in all Brazilian regions, with the highest incidences in the North and Northeast. There are several methods used to diagnose leishmaniasis, but these procedures have many limitations, are time consuming, have low sensitivity, and are expensive. In this context, Fourier Transform Infrared Spectroscopy (FT-IR) analysis has the potential to provide rapid results and may be adapted for a clinical test with high sensitivity and specificity. In this work, FT-IR was used as a tool to investigate the promastigotes of Leishmaniaamazonensis, Leishmaniachagasi, and Leishmaniamajor species. The spectra were analyzed by cluster analysis and deconvolution procedure base on spectra second derivatives. Results: cluster analysis found four specific regions that are able to identify the Leishmania species. The dendrogram representation clearly indicates the heterogeneity among Leishmania species. The band deconvolution done by the curve fitting in these regions quantitatively differentiated the polysaccharides, amide III, phospholipids, proteins, and nucleic acids. L. chagasi and L. major showed a greater biochemistry similarity and have three bands that were not registered in L. amazonensis. The L. amazonensis presented three specific bands that were not recorded in the other two species. It is evident that the FT-IR method is an indispensable tool to discriminate these parasites. The high sensitivity and specificity of this technique opens up the possibilities for further studies about characterization of other microorganisms.

  15. FT Raman microscopy of untreated natural plant fibres

    Science.gov (United States)

    Edwards, H. G. M.; Farwell, D. W.; Webster, D.

    1997-11-01

    The application of FT-Raman microscopy to the non-destructive analysis of natural plant fibres is demonstrated with samples of flax, jute, ramie, cotton, kapok, sisal and coconut fibre. Vibrational assignments are proposed and characteristic features of each material are presented. Samples were not pre-treated chemically before analysis and were used directly from their respective storage collection; the adaptation of the Raman microscopic technique to the identification of specimens of natural fibres in archaeological burial sites is explored for its forensic potential.

  16. Use of FT-NIR Spectroscopy for Bovine Colostrum Analysis

    Directory of Open Access Journals (Sweden)

    P. Navrátilová

    2006-01-01

    Full Text Available Fourier transformation near infrared spectroscopy (FT-NIR in combination with partial least squares (PLS method were used to determine the content of total solids, fat, non-fatty solids, lactose and proteins in bovine colostrum. Spectra of 90 samples were measured in the reflectance mode with a transflectance cuvette in the 10000-4000 cm-1 spectral ranges with 100 scans. Calibration was performed and statistical values of correlation coefficients (R and standard error of calibration values (SEC were computed for total solids (0.986 and 0.919, respectively, fat (0.997 and 0.285, respectively, non-fatty solids (0.995 and 0.451, respectively, lactose (0.934 and 0.285, respectively and protein (0.999 and 0.149, respectively. The calibration models developed were verified by cross validation. It follows from the study that FT-NIR spectroscopy can be used to determine the components of bovine colostrum.

  17. Measurement of serum FT/sub 4/ in pregnancy and binding protein abnormalities by different methods

    Energy Technology Data Exchange (ETDEWEB)

    Meinhold, H; Wenzel, K W

    1985-11-01

    In serum of pregnant women in the 3rd trimester, the majority of FT/sub 4/ methods compared in the present study yielded FT/sub 4/ concentrations in the lower parts of normal ranges or beyond the lower normal border lines. In TBG deficiency, serum FT/sub 4/ as measured by six FT/sub 4/ kits was found to be in the manufacturer-specified normal ranges and did not show clearly recognizable systematic differences between single kits or kit groups with different methodological principles. considerable kit-dependent differences of measured FT/sub 4/ were found in euthyroid patients with TBG excess; all values were, however, in the respective normal ranges. In dysalbuminemic hyperthyroxinemia, labelled analogue kits yielded falsely elevated FT/sub 4/ concentrations, while FT/sub 4/ measured by non-analogue methods was normal in agreement with the euthyroid status of the patient.

  18. FTIR, FT-Raman, FT-NMR, UV-visible and quantum chemical investigations of 2-amino-4-methylbenzothiazole.

    Science.gov (United States)

    Arjunan, V; Sakiladevi, S; Rani, T; Mythili, C V; Mohan, S

    2012-03-01

    The FT-IR (4000-400 cm(-1)) and FT-Raman (4000-100 cm(-1)) spectral measurements and complete assignments of the observed spectra of 2-amino-4-methylbenzothiazole (2A4MBT) have been proposed. Ab initio and DFT calculations have been performed and the structural parameters of the compound were determined from the optimised geometry with 6-31G(d,p), 6-311++G(d,p) and cc-pVDZ basis sets and giving energies, harmonic vibrational frequencies, depolarisation ratios, IR intensities and Raman activities. (1)H and (13)C NMR spectra were recorded and (1)H and (13)C nuclear magnetic resonance chemical shifts of the molecule were calculated using the gauge independent atomic orbital (GIAO) method. UV-visible spectrum of the compound was also recorded and the electronic properties, such as HOMO, LUMO and band gap energies were measured by time-dependent DFT (TD-DFT) approach. The geometric parameters, energies, harmonic vibrational frequencies, IR intensities, Raman activities chemical shifts and absorption wavelengths were compared with the available experimental data of the molecule. The influences of methyl and amino groups on the skeletal modes and on the proton chemical shifts have been investigated. Copyright © 2011 Elsevier B.V. All rights reserved.

  19. Do TSH, FT3, and FT4 Impact BAT Visualization of Clinical FDG-PET/CT Images?

    Directory of Open Access Journals (Sweden)

    Ryuichi Nishii

    2018-01-01

    Full Text Available Objective. We retrospectively analyzed activated BAT visualization on FDG-PET/CT in patients with various conditions and TH levels to clarify the relationships between visualization of BAT on FDG-PET/CT and the effect of TH. Methods. Patients who underwent clinical FDG-PET/CT were reviewed and we categorized patients into 5 groups: (i thyroid hormone withdrawal (THW group; (ii recombinant human thyrotropin (rhTSH group; (iii hypothyroidism group; (iv hyperthyroidism group; and (v BAT group. A total of sixty-two FDG-PET/CT imaging studies in fifty-nine patients were performed. To compare each group, gender; age; body weight; serum TSH, FT3, and FT4 levels; and outside temperature were evaluated. Results. No significant visualization of BAT was noted in any of the images in the THW, rhTSH, hypothyroidism, and hyperthyroidism groups. All patients in the BAT group were in a euthyroid state. When the BAT-negative and BAT-positive patient groups were compared, it was noted that the minimum and maximum temperature on the day of the PET study and maximum temperature of the one day before the PET study were significantly lower in BAT-positive group than in all those of other groups. Conclusions. Elevated TSH condition before RIT, hyperthyroidism, or hypothyroidism did not significantly impact BAT visualization of clinical FDG-PET/CT images.

  20. Experimental (FT-IR, FT-Raman, 1H, 13C NMR) and theoretical study of alkali metal 2-aminobenzoates

    Science.gov (United States)

    Samsonowicz, M.; Świsłocka, R.; Regulska, E.; Lewandowski, W.

    2008-09-01

    The influence of lithium, sodium, potassium, rubidium and cesium on the electronic system of the 2-aminobenzoic acid was studied by the methods of molecular spectroscopy. The vibrational (FT-IR, FT-Raman) and NMR ( 1H and 13C) spectra for 2-aminobenzoic acid and its alkali metal salts were recorded. The assignment of vibrational spectra was done on the basis of literature data, theoretical calculations and our previous experience. Characteristic shifts of bands and changes in intensities of bands along the metal series were observed. The changes of chemical shifts of protons ( 1H NMR) and carbons ( 13C NMR) in the series of studied alkali metal 2-aminobenzoates were observed too. Optimized geometrical structures of studied compounds were calculated by B3LYP method using 6-311++G ∗∗ basis set. Geometric aromaticity indices, dipole moments and energies were also calculated. The theoretical wavenumbers and intensities of IR and Raman spectra were obtained. The calculated parameters were compared to experimental characteristic of studied compounds.

  1. Do TSH, FT3, and FT4 Impact BAT Visualization of Clinical FDG-PET/CT Images?

    Science.gov (United States)

    Nishii, Ryuichi; Nagamachi, Shigeki; Mizutani, Youichi; Terada, Tamasa; Kiyohara, Syogo; Wakamatsu, Hideyuki; Fujita, Seigo; Higashi, Tatsuya; Yoshinaga, Keiichiro; Saga, Tsuneo; Hirai, Toshinori

    2018-01-01

    We retrospectively analyzed activated BAT visualization on FDG-PET/CT in patients with various conditions and TH levels to clarify the relationships between visualization of BAT on FDG-PET/CT and the effect of TH. Patients who underwent clinical FDG-PET/CT were reviewed and we categorized patients into 5 groups: (i) thyroid hormone withdrawal (THW) group; (ii) recombinant human thyrotropin (rhTSH) group; (iii) hypothyroidism group; (iv) hyperthyroidism group; and (v) BAT group. A total of sixty-two FDG-PET/CT imaging studies in fifty-nine patients were performed. To compare each group, gender; age; body weight; serum TSH, FT3, and FT4 levels; and outside temperature were evaluated. No significant visualization of BAT was noted in any of the images in the THW, rhTSH, hypothyroidism, and hyperthyroidism groups. All patients in the BAT group were in a euthyroid state. When the BAT-negative and BAT-positive patient groups were compared, it was noted that the minimum and maximum temperature on the day of the PET study and maximum temperature of the one day before the PET study were significantly lower in BAT-positive group than in all those of other groups. Elevated TSH condition before RIT, hyperthyroidism, or hypothyroidism did not significantly impact BAT visualization of clinical FDG-PET/CT images.

  2. Hydrogenated fullerenes in space: FT-IR spectra analysis

    International Nuclear Information System (INIS)

    El-Barbary, A. A.

    2016-01-01

    Fullerenes and hydrogenated fullerenes are found in circumstellar and interstellar environments. But the determination structures for the detected bands in the interstellar and circumstellar space are not completely understood so far. For that purpose, the aim of this article is to provide all possible infrared spectra for C 20 and C 60 fullerenes and their hydrogenated fullerenes. Density Functional theory (DFT) is applied using B3LYP exchange-functional with basis set 6–31G(d, p). The Fourier transform infrared spectroscopy (FT-IR) is found to be capable of distinguishing between fullerenes, mono hydrogenated fullerenes and fully hydrogenated fullerenes. In addition, deposition of one hydrogen atom outside the fully hydrogenated fullerenes is found to be distinguished by forming H 2 molecule at peak around 4440 cm −1 . However, deposition of one hydrogen atom inside the fully hydrogenated fullerenes cannot be distinguished. The obtained spectral structures are analyzed and are compared with available experimental results.

  3. Observational information for f(T) theories and dark torsion

    Energy Technology Data Exchange (ETDEWEB)

    Bengochea, Gabriel R., E-mail: gabriel@iafe.uba.a [Instituto de Astronomia y Fisica del Espacio (IAFE), CC 67, Suc. 28, 1428 Buenos Aires (Argentina)

    2011-01-17

    In the present work we analyze and compare the information coming from different observational data sets in the context of a sort of f(T) theories. We perform a joint analysis with measurements of the most recent type Ia supernovae (SNe Ia), Baryon Acoustic Oscillation (BAO), Cosmic Microwave Background radiation (CMB), Gamma-Ray Bursts data (GRBs) and Hubble parameter observations (OHD) to constraint the only new parameter these theories have. It is shown that when the new combined BAO/CMB parameter is used to put constraints, the result is different from previous works. We also show that when we include Observational Hubble Data (OHD) the simpler {Lambda}CDM model is excluded to one sigma level, leading the effective equation of state of these theories to be of phantom type. Also, analyzing a tension criterion for SNe Ia and other observational sets, we obtain more consistent and better suited data sets to work with these theories.

  4. Determination of nutritional parameters of yoghurts by FT Raman spectroscopy

    Science.gov (United States)

    Czaja, Tomasz; Baranowska, Maria; Mazurek, Sylwester; Szostak, Roman

    2018-05-01

    FT-Raman quantitative analysis of nutritional parameters of yoghurts was performed with the help of partial least squares models. The relative standard errors of prediction for fat, lactose and protein determination in the quantified commercial samples equalled to 3.9, 3.2 and 3.6%, respectively. Models based on attenuated total reflectance spectra of the liquid yoghurt samples and of dried yoghurt films collected with the single reflection diamond accessory showed relative standard errors of prediction values of 1.6-5.0% and 2.7-5.2%, respectively, for the analysed components. Despite a relatively low signal-to-noise ratio in the obtained spectra, Raman spectroscopy, combined with chemometrics, constitutes a fast and powerful tool for macronutrients quantification in yoghurts. Errors received for attenuated total reflectance method were found to be relatively higher than those for Raman spectroscopy due to inhomogeneity of the analysed samples.

  5. Study of the deuterated albumin by FT-IR spectroscopy

    International Nuclear Information System (INIS)

    Stoenescu, Daniela; Sahini, V.E.

    2000-01-01

    The albumin is a protein from the soluble or corpuscular protein class, which exists in cells, in dissolved state or in form of a hydrated gel. Proteins are essential constituents beside water, inorganic salts, lipids, carbon hydrates, vitamins, enzymes. The albumin is also a protein soluble in water and in diluted electrolyte solutions (acids, bases and salts). The investigation of the vibration isotopic effect has a great importance both for the diatomic molecules and for the polyatomic molecules. This paper is the first from a series of works which are intended to study the physico-chemical properties of the deuterated albumin and of the albumin solutions in heavy water by an isotopic exchange method. To put in evidence H-D exchange, the FT-IR spectroscopy is used when the deuterated albumin has different layer thickness. It is also of interest to elucidate the isotopic exchange between the hydrogen and oxygen atoms in bovine serum albumin macromolecules. (authors)

  6. 3D-FT MRI of the facial nerve

    International Nuclear Information System (INIS)

    Girard, N.; Raybaud, C.; Poncet, M.

    1994-01-01

    Contrast-enhanced 3D-FT MRI of the intrapetrous facial nerve was obtained in 38 patients with facial nerve disease, using a 1.0 T magnet and fast gradient-echo acquisition sequences. Contiguous millimetric sections were obtained, which could be reformatted in any desired plane. Acutely ill patients, were examined within the first 2 months, included: 24 with Bell's palsy and 6 with other acute disorders (Herpes zoster, trauma, neuroma, meningeal metastasis, middle ear granuloma). Six patients investigated more than a year after the onset of symptoms included 3 with congenital cholesteatoma, 2 with neuromas and one with a chronic Bell's palsy. The lesion was found incidentally in two cases (a suspected neurofibroma and a presumed drop metastasis from an astrocytoma). Patients with tumours had nodular, focally-enhancing lesions, except for the leptomeningeal metastasis in which the enhancement was linear. Linear, diffuse contrast enhancement of the facial nerve was found in trauma, and in the patient with a middle ear granuloma. Of the 24 patients with an acute Bell's palsy 15 exhibited linear contrast enhancement of the facial nerve. Three of these were lost to follow-up, but correlation of clinical outcome and contrast enhancement showed that only 4 of the 11 patients who made a complete recovery and all 10 patients with incomplete recovery demonstrated enhancement. Possible explanations for these findings are suggested by pathological data from the literature. 3D-FT imaging of the facial nerve thus yields direct information about the of the nerve condition and defines the morphological abnormalities. It can also demonstrate contrast enhancement which seems to have some prognostic value in acute idiopathic Bell's palsy. (orig.)

  7. 3D-FT MRI of the facial nerve

    Energy Technology Data Exchange (ETDEWEB)

    Girard, N. (Neuroradiology, Hopital Nord, 13 Marseille (France)); Raybaud, C. (Neuroradiology, Hopital Nord, 13 Marseille (France)); Poncet, M. (Neuroradiology, Hopital Nord, 13 Marseille (France))

    1994-08-01

    Contrast-enhanced 3D-FT MRI of the intrapetrous facial nerve was obtained in 38 patients with facial nerve disease, using a 1.0 T magnet and fast gradient-echo acquisition sequences. Contiguous millimetric sections were obtained, which could be reformatted in any desired plane. Acutely ill patients, were examined within the first 2 months, included: 24 with Bell's palsy and 6 with other acute disorders (Herpes zoster, trauma, neuroma, meningeal metastasis, middle ear granuloma). Six patients investigated more than a year after the onset of symptoms included 3 with congenital cholesteatoma, 2 with neuromas and one with a chronic Bell's palsy. The lesion was found incidentally in two cases (a suspected neurofibroma and a presumed drop metastasis from an astrocytoma). Patients with tumours had nodular, focally-enhancing lesions, except for the leptomeningeal metastasis in which the enhancement was linear. Linear, diffuse contrast enhancement of the facial nerve was found in trauma, and in the patient with a middle ear granuloma. Of the 24 patients with an acute Bell's palsy 15 exhibited linear contrast enhancement of the facial nerve. Three of these were lost to follow-up, but correlation of clinical outcome and contrast enhancement showed that only 4 of the 11 patients who made a complete recovery and all 10 patients with incomplete recovery demonstrated enhancement. Possible explanations for these findings are suggested by pathological data from the literature. 3D-FT imaging of the facial nerve thus yields direct information about the of the nerve condition and defines the morphological abnormalities. It can also demonstrate contrast enhancement which seems to have some prognostic value in acute idiopathic Bell's palsy. (orig.)

  8. Significance of changes of serum FT3, FT4, s-TSH, TGA, TPO-Ab levels in patients with non-Graves' hyperthyroidism and Graves' disease

    International Nuclear Information System (INIS)

    Zhang Lindi; Xu Changde; Xu Huogen; Wang Wei; Zhang Jie; Nie Shufen; Gu Zhenqi; Zeng Jihua

    2006-01-01

    Objective: To investigate the clinical significance of the changes of thyroid-related hormones (FT 3 , FT 4 , s-TSH, TGA, TPO-Ab) levels in patients with Graves' and non-Graves' hyperthyroidism. Methods: Serum FT 3 , FT 4 , TGA, TPO-Ab (with RIA) and s-TSH (with IRMA) were determined in 43 patients with non-Graves' hyperthyroidism, 29 patients with Graves' disease and 40 controls. Results: In both groups of hyperthyroid patients, the serum levels of FT 3 (15.01 ± 11.01 pg/ml in the non - Graves' group and 15.23 ± 9.57pg/ml in the Graves' group), FT 4 (38.30 ± 19.82, 38.87 ± 17.39pg/ml), TGA(33.89 ± 22. 43%, 49.72 ± 20.55% ) and TPO-Ab (1319.24 ± 1037.78, 2023.24 ± 621.00IU/ml) were significantly higher than those (FT 3 , 6.76 ± 2.01pg/ml, FT 4 16.16 ± 2.58pg/ml, TGA 6.76 ± 2.01%, TPO-Ab 0.01 ± 0.01IU/ml) in the controls (all P 3 , FT 4 and s-TSH levels in both groups were not significantly different from each other. Conclusion: In this study, serum TGA and TPO -Ab levels were lower in patients with non-Graves' hyperthyroidism than those in patients with Graves' disease. (authors)

  9. Comparative FT-Raman, FT-IR and colour shifts spectroscopic evaluation of gamma irradiated experimental models of oil paintings

    International Nuclear Information System (INIS)

    Manca, M.M.; Virgolici, M.; Cutrubinis, M.; Moise, I.V.; Ponta, C.C.; Negut, C.D.; Stanculescu, I.R.; Bucharest University

    2011-01-01

    Complete text of publication follows. The present study follows the changes of gamma irradiated historic pigments and experimental models of oil paintings with non-destructive and non-contact spectroscopic analytical techniques which are the only ones accepted by the conservators/restorers community. Molecular structure characterization was performed by FT-IR / Raman spectroscopy using a Bruker Vertex 70 class equipped with two mobile probes: a MIR fibre module for MIR probes (with LN2 cooled detector) and a Raman RAM II module (LN2 Ge detector) with a RAMPROBE fibre. Colour was measured by a portable reflectance spectrophotometer (Miniscan XE Plus, HunterLab) in diffuse/8 deg geometry with a beam diameter of 4 mm and specular component included. Correlations between colour shifts and changes in molecular structure induced by gamma irradiation were further investigated.

  10. FT-IR, FT-Raman, and DFT computational studies of melaminium nitrate molecular-ionic crystal

    Science.gov (United States)

    Tanak, Hasan; Marchewka, Mariusz K.

    2013-02-01

    The experimental and theoretical vibrational spectra of melaminium nitrate were studied. The Raman and infrared (FT-IR) spectra of the melaminium nitrate and its deuterated analogue were recorded in the solid phase. Molecular geometry and vibrational frequency values of melaminium nitrate in the electronic ground state were calculated using the density functional method (B3LYP) with the 6-31++G(d,p) basis set. The calculated results show that the optimized geometry can well reproduce the crystal structure, and the theoretical vibrational frequency values show good agreement with experimental values. The NBO analysis reveals that the N-H···O and N-H···N intermolecular interactions significantly influence crystal packing in this molecule.

  11. IMF dependence of the open-closed field line boundary in Saturn's ionosphere, and its relation to the UV auroral oval observed by the Hubble Space Telescope

    Directory of Open Access Journals (Sweden)

    E. S. Belenkaya

    2007-06-01

    Full Text Available We study the dependence of Saturn's magnetospheric magnetic field structure on the interplanetary magnetic field (IMF, together with the corresponding variations of the open-closed field line boundary in the ionosphere. Specifically we investigate the interval from 8 to 30 January 2004, when UV images of Saturn's southern aurora were obtained by the Hubble Space Telescope (HST, and simultaneous interplanetary measurements were provided by the Cassini spacecraft located near the ecliptic ~0.2 AU upstream of Saturn and ~0.5 AU off the planet-Sun line towards dawn. Using the paraboloid model of Saturn's magnetosphere, we calculate the magnetospheric magnetic field structure for several values of the IMF vector representative of interplanetary compression regions. Variations in the magnetic structure lead to different shapes and areas of the open field line region in the ionosphere. Comparison with the HST auroral images shows that the area of the computed open flux region is generally comparable to that enclosed by the auroral oval, and sometimes agrees in detail with its poleward boundary, though more typically being displaced by a few degrees in the tailward direction.

  12. A Study on the Ionosphere and Thermosphere Interaction Based on NCAR-TIEGCM: Dependence of the Interplanetary Magnetic Field (IMF on the Momentum Forcing in the High-Latitude Lower Thermosphere

    Directory of Open Access Journals (Sweden)

    Young-Sil Kwak

    2005-06-01

    Full Text Available To understand the physical processes that control the high-latitude lower thermospheric dynamics, we quantify the forces that are mainly responsible for maintaining the high-latitude lower thermospheric wind system with the aid of the National Center for Atmospheric Research Thermosphere-Ionosphere Electrodynamics General Circulation Model (NCAR-TIEGCM. Momentum forcing is statistically analyzed in magnetic coordinates, and its behavior with respect to the magnitude and orientation of the interplanetary magnetic field (IMF is further examined. By subtracting the values with zero IMF from those with non-zero IMF, we obtained the difference winds and forces in the high-latitude lower thermosphere( 0.8 |bar{B}_z| or negative(B_y 0.3125 |bar{B}_y| or negative(B_z 125 km the primary forces that determine the variations of the neutral winds are the pressure gradient, Coriolis and rotational Pedersen ion drag forces; however, at various locations and times significant contributions can be made by the horizontal advection force. On the other hand, at lower altitudes(108-125 km the pressure gradient, Coriolis and non-rotational Hall ion drag forces determine the variations of the neutral winds. At lower altitudes(<108 km it tends to generate a geostrophic motion with the balance between the pressure gradient and Coriolis forces. The northward component of IMF bar{B}_y-dependent average momentum forces act more significantly on the neutral motion except for the ion drag. At lower altitudes(108-125 km for negative IMF-bar{B}_y condition the ion drag force tends to generate a warm clockwise circulation with downward vertical motion associated with the adiabatic compress heating in the polar cap region. For positive IMF-bar{B}_y condition it tends to generate a cold anticlockwise circulation with upward vertical motion associated with the adiabatic expansion cooling in the polar cap region. For negative IMF-bar{B}_z the ion drag force tends to generate a

  13. 3-Iodobenzaldehyde: XRD, FT-IR, Raman and DFT studies.

    Science.gov (United States)

    Kumar, Chandraju Sadolalu Chidan; Parlak, Cemal; Tursun, Mahir; Fun, Hoong-Kun; Rhyman, Lydia; Ramasami, Ponnadurai; Alswaidan, Ibrahim A; Keşan, Gürkan; Chandraju, Siddegowda; Quah, Ching Kheng

    2015-06-15

    The structure of 3-iodobenzaldehyde (3IB) was characterized by FT-IR, Raman and single-crystal X-ray diffraction techniques. The conformational isomers, optimized geometric parameters, normal mode frequencies and corresponding vibrational assignments of 3IB were examined using density functional theory (DFT) method, with the Becke-3-Lee-Yang-Parr (B3LYP) functional and the 6-311+G(3df,p) basis set for all atoms except for iodine. The LANL2DZ effective core basis set was used for iodine. Potential energy distribution (PED) analysis of normal modes was performed to identify characteristic frequencies. 3IB crystallizes in monoclinic space group P21/c with the O-trans form. There is a good agreement between the theoretically predicted structural parameters, and vibrational frequencies and those obtained experimentally. In order to understand halogen effect, 3-halogenobenzaldehyde [XC6H4CHO; X=F, Cl and Br] was also studied theoretically. The free energy difference between the isomers is small but the rotational barrier is about 8kcal/mol. An atypical behavior of fluorine affecting conformational preference is observed. Copyright © 2015 Elsevier B.V. All rights reserved.

  14. Hydrogenated fullerenes in space: FT-IR spectra analysis

    Energy Technology Data Exchange (ETDEWEB)

    El-Barbary, A. A. [Physics Department, Faculty of Education, Ain-Shams University, Cairo, Egypt Physics Department, Faculty of Science, Jazan University, Jazan (Saudi Arabia)

    2016-06-10

    Fullerenes and hydrogenated fullerenes are found in circumstellar and interstellar environments. But the determination structures for the detected bands in the interstellar and circumstellar space are not completely understood so far. For that purpose, the aim of this article is to provide all possible infrared spectra for C{sub 20} and C{sub 60} fullerenes and their hydrogenated fullerenes. Density Functional theory (DFT) is applied using B3LYP exchange-functional with basis set 6–31G(d, p). The Fourier transform infrared spectroscopy (FT-IR) is found to be capable of distinguishing between fullerenes, mono hydrogenated fullerenes and fully hydrogenated fullerenes. In addition, deposition of one hydrogen atom outside the fully hydrogenated fullerenes is found to be distinguished by forming H{sub 2} molecule at peak around 4440 cm{sup −1}. However, deposition of one hydrogen atom inside the fully hydrogenated fullerenes cannot be distinguished. The obtained spectral structures are analyzed and are compared with available experimental results.

  15. Statistical analysis of the Ft. Calhoun reactor coolant pump system

    International Nuclear Information System (INIS)

    Heising, Carolyn D.

    1998-01-01

    In engineering science, statistical quality control techniques have traditionally been applied to control manufacturing processes. An application to commercial nuclear power plant maintenance and control is presented that can greatly improve plant safety. As a demonstration of such an approach to plant maintenance and control, a specific system is analyzed: the reactor coolant pumps (RCPs) of the Ft. Calhoun nuclear power plant. This research uses capability analysis, Shewhart X-bar, R-charts, canonical correlation methods, and design of experiments to analyze the process for the state of statistical control. The results obtained show that six out of ten parameters are under control specifications limits and four parameters are not in the state of statistical control. The analysis shows that statistical process control methods can be applied as an early warning system capable of identifying significant equipment problems well in advance of traditional control room alarm indicators Such a system would provide operators with ample time to respond to possible emergency situations and thus improve plant safety and reliability. (author)

  16. Statistical analysis of the Ft. Calhoun reactor coolant pump system

    International Nuclear Information System (INIS)

    Patel, Bimal; Heising, C.D.

    1997-01-01

    In engineering science, statistical quality control techniques have traditionally been applied to control manufacturing processes. An application to commercial nuclear power plant maintenance and control is presented that can greatly improve plant safety. As a demonstration of such an approach, a specific system is analyzed: the reactor coolant pumps (RCPs) of the Ft. Calhoun nuclear power plant. This research uses capability analysis, Shewhart X-bar, R charts, canonical correlation methods, and design of experiments to analyze the process for the state of statistical control. The results obtained show that six out of ten parameters are under control specification limits and four parameters are not in the state of statistical control. The analysis shows that statistical process control methods can be applied as an early warning system capable of identifying significant equipment problems well in advance of traditional control room alarm indicators. Such a system would provide operators with ample time to respond to possible emergency situations and thus improve plant safety and reliability. (Author)

  17. Breast cancer diagnosis using FT-RAMAN spectroscopy

    Science.gov (United States)

    Bitar, Renata A.; Martin, Airton A.; Criollo, Carlos J. T.; Ramalho, Leandra N. Z.

    2005-04-01

    In this study FT-RAMAN spectra of breast tissue from 35 patients were obtained and separated into nine groups for histopathologic analysis, which are as follows: normal breast tissue, fibrocystic condition, in situ ductal carcinoma, in situ ductal carcinoma with necrosis, infiltrate ductal carcinoma, infiltrate inflammatory ductal carcinoma, infiltrate medullar ductal carcinoma, infiltrate colloid ductal carcinoma, and infiltrate lobular carcinoma. Using spectrum averages taken from each group a qualitative analysis was performed to compare these molecular compositions to those known to be present in abnormal concentrations in pathological situations, e.g. the development of desmoplastic lesions with a stroma of dense collagen in tumoral breast tissues which substitute adipose stroma of non-diseased breast tissue. The band identified as amino acids, offered basis for observation in the existence of alterations in the proteins, thus proving Raman Spectroscopic capacity in identification of primary structures of proteins; secondary protein structure was also identified through the peptic links, Amide I and Amide III, which have also been identified by various authors. Alterations were also identified in the peaks and bandwidths of nucleic acids demonstrating the utilization of Raman Spectroscopy in the analysis of the cells nucleus manifestations. All studies involving Raman Spectroscopy and breast cancer have shown excellent result reliability and therefore a basis for the technical theory.

  18. Response of the polar cap boundary and the current system to changes in IMF observed from the MAGSAT satellite in the southern hemisphere during summer

    International Nuclear Information System (INIS)

    Bhatnagar, V.P.; Burrows, J.R.

    1987-01-01

    The magnetic field vector residuals observed from the Magsat satellite have been used to obtain the dependence of the polar cap boundary and the current system on IMF for quiet and mildly disturbed conditions. The study has been carried out for the summer months in the Southern Hemisphere. ''Shear reversals'' (SRs) in vector residuals indicative of the infinite current sheet approximation of the field-aligned currents (FACs) indicate roughly the polar cap boundary or the poleward boundary of the plasma sheet. This is also the poleward edge of the region 1 FACs. The SR is defined to occur at the latitude where the vector goes to minimum and changes direction by approximately 180 0 . It is found that SRs mainly occur when the interplanetary magnetic field (IMF) has a southward-directed Bsub(z) component and in the latitude range of about 70 0 -80 0 . SRs in the dusk sector occur predominantly when the azimuthal component Bsub(y) is positive and in the dawn sector when Bsub(y) is negative, irrespective of the sign of Bsub(z). These results agree with the known merging process of IMF with magnetopause field lines. When SRs occur on both dawn and dusk sectors, the residuals over the entire polar cap are nearly uniform in direction and magnitude, indicating negligible polar currents. Similar behaviour is observed during highly disturbed conditions usually associated with large negative values of Bsub(z). Forty-one Magsat orbits with such SRs are quantitatively modelled for preliminary case studies of the resulting current distribution. It is found that SRs, in the plane perpendicular to the geomagnetic field, for the current vectors and the magnetic vector residuals (perturbations relative to the unperturbed field) occur at almost the same latitudes. The electrojet intensities range from 1.2 x 10 4 to 6.5 x 10 5 A (amperes). A preliminary classification of polar cap boundary crossings characterized by vector rotations rather than SRs also shows that they tend to

  19. Monitoring lipase-catalyzed interesterification for bulky fats modification with FT-IR/NIR spectroscopy

    DEFF Research Database (Denmark)

    Chang, Tinghong; Lai, Xuxin; Zhang, Hong

    2005-01-01

    This work demonstrates the application of FT-IR and FT-NIR spectroscopy to monitor the enzymatic interesterification process for bulky fat modification. The reaction was conducted between palm stearin and coconut oil (70/30, w/w) with the catalysis of Lipozyme TL IM at 70°C in a batch reactor...

  20. System dependence of the correlation function of IMFs in 36Ar + 112,124Sn at 35 MeV/u

    International Nuclear Information System (INIS)

    Xiao, Z.G.; Hu, R.J.; Wu, H.Y.; Jin, G.M.; Li, Z.Y.; Duan, L.M.; Wang, H.W.; Zhang, B.G.; Wang, S.F.; Wei, Z.Y.; Xu, H.S.; Zhu, Y.T.; Li, S.L.; Fu, F.; Yuan, X.H.; Feng, Z.Q.

    2006-01-01

    The inclusive reduced velocity correlation functions of the intermediate mass fragments were measured in the reactions of 36 Ar + 112,124 Sn at 35 MeV/u. The anti-correlation is observed to be stronger in 36 Ar + 124 Sn system than that in 36 Ar + 112 Sn. The difference of the correlation functions between the two reactions is mainly contributed by the particle pairs with high momenta. A three body Coulomb repulsive trajectory model is employed to calculate the emission time scale of the IMFs for the two systems. The time scale is 150 fm/c in 36 Ar + 112 Sn and 120 fm/c in the 36 Ar + 124 Sn, respectively

  1. FT overexpression induces precocious flowering and normal reproductive development in Eucalyptus.

    Science.gov (United States)

    Klocko, Amy L; Ma, Cathleen; Robertson, Sarah; Esfandiari, Elahe; Nilsson, Ove; Strauss, Steven H

    2016-02-01

    Eucalyptus trees are among the most important species for industrial forestry worldwide. However, as with most forest trees, flowering does not begin for one to several years after planting which can limit the rate of conventional and molecular breeding. To speed flowering, we transformed a Eucalyptus grandis × urophylla hybrid (SP7) with a variety of constructs that enable overexpression of FLOWERING LOCUS T (FT). We found that FT expression led to very early flowering, with events showing floral buds within 1-5 months of transplanting to the glasshouse. The most rapid flowering was observed when the cauliflower mosaic virus 35S promoter was used to drive the Arabidopsis thaliana FT gene (AtFT). Early flowering was also observed with AtFT overexpression from a 409S ubiquitin promoter and under heat induction conditions with Populus trichocarpa FT1 (PtFT1) under control of a heat-shock promoter. Early flowering trees grew robustly, but exhibited a highly branched phenotype compared to the strong apical dominance of nonflowering transgenic and control trees. AtFT-induced flowers were morphologically normal and produced viable pollen grains and viable self- and cross-pollinated seeds. Many self-seedlings inherited AtFT and flowered early. FT overexpression-induced flowering in Eucalyptus may be a valuable means for accelerating breeding and genetic studies as the transgene can be easily segregated away in progeny, restoring normal growth and form. © 2015 Society for Experimental Biology, Association of Applied Biologists and John Wiley & Sons Ltd.

  2. Characterization of additives typically employed in EPDM formulations by using FT-IR of gaseous pyrolyzates

    Directory of Open Access Journals (Sweden)

    Natália Beck Sanches

    2014-06-01

    Full Text Available In this study, Fourier transform infrared spectroscopy (FT-IR was employed to investigate the gaseous pyrolysis products of ethylene - propylene - diene rubber (EPDM. The objective was to evaluate the potential of FT-IR analysis of gaseous pyrolyzates (PY-G/FT-IR for characterization of EPDM additives. Two EPDM formulations, containing additives typically employed in EPDM rubbers, were analyzed. Initially, gaseous pyrolysis products from paraffin oil, stearic acid, 2,2,4-trimethyl-1,2-dihydroquinoline, tetramethylthiuram monosulfide (TMTM, tetramethylthiuram disulfide (TMTD, and 2-mercaptobenzothiazole (MBT were characterized separately, and their main absorptions were identified. Subsequently, the gaseous pyrolysis products of raw, unvulcanized, and vulcanized EPDM formulations were analyzed. The similarities observed in the FT-IR spectra of unvulcanized and vulcanized EPDM show that the vulcanization process does not interfere with the pyrolysis products. The identification of the functional groups of the studied additives was possible in both unvulcanized and vulcanized EPDM samples, without solvent extraction. Results also demonstrate that the PY-G/FT-IR technique can identify additives containing sulfur in concentrations as low as 1.4 phr (1.26% in both unvulcanized and vulcanized EPDM. However, the method showed some limitation due to overlapping and to similarities of TMTM and TMTD PY-G/FT-IR spectra, which could not be distinguished from each other. The PY-G/FT-IR technique is a faster and cheaper alternative to the sophisticated techniques usually applied to detection of additives in rubbers.

  3. Measurement of serum free thyroxine using fT4(fraction) determined by solidphase radioimmunoassay: First clinical results

    International Nuclear Information System (INIS)

    Reiners, C.; Walter, H.; Moll, E.; Boerner, W.

    1983-01-01

    The novel solidphase RIA SPAC ET permits the simultaneous determination of TF 4 , TT 4 and fT 4 -fraction. The duration until the complete results of this assay can be obtained is a little bit less than for parallel radioimmunologic FT 4 - and TT 4 -determinations. The results of our quality control survey indicate that the precision of the precommercial kits tested should be improved. In addition, the normal range of FT 4 from 5.5 pg/ml to 12.5 pg/ml should be adapted in the final assay version of the approximately 30% higher normal ranges which are common with alternative FT 4 -radioimunoassays. In comparison to FT 4 -I, TT 4 /TBG-ratio and other FT 4 -radioimmunoassays, the diagnostic accuracy of FT 4 determined by SPAC ET is equally good. Estrogen-mediated TBG elevations on oral contraceptives are well compensated. In pregnancy, the known tendency towards lower FT 4 levels can be seen with the beginning of the second trimester. While there are no changes of FT 4 levels on medication with acetylosalicyclic acid, a slight tendency towards lower FT 4 determined by SPAC ET can be seen on therapy with phenytoin. Under treatment with heparin, FT 4 by SPAC ET is elevated. This is more reasonable than the decreases of FT 4 concentrations observed with radioimmunoassays using FT 4 analogues as tracers. RIA SPAC ET is an interesting alternative to routinely used direct and indirect methods for determination of free thyroxine. (orig.) [de

  4. Molecular Characterization of FT and FD homologs from Eriobotrya deflexa Nakai forma koshunensis

    Directory of Open Access Journals (Sweden)

    Ling eZhang

    2016-01-01

    Full Text Available In angiosperms, regulation of flowering is a vital process for successful reproduction. To date, the molecular mechanism of flowering is well studied in the model plant, Arabidopsis, in which key genes such as FLOWERING LOCUST (FTor FD have been identified to regulate flowering. However, the flowering mechanisms are still largely unknown in fruit trees like loquat. To this end, we first cloned one FT- and two FD-like genes from the loquat (E. deflexa Nakai f. koshunensis and referred to as EdFT, EdFD1 and EdFD2, respectively. Phylogenetic analysis has shown that EdFT, EdFD1 and EdFD2 are conserved during the evolution process. EdFT is mainly expressed in reproductive tissues (e.g. flower buds, flowers and fruits, while EdFD1 and EdFD2 are mainly expressed in apical buds including leaf buds and flower buds. EdFT is localized in the whole cell, while EdFD1 or EdFD2 is localized in the nucleus. Ectopic expression of EdFT, EdFD1 and EdFD2 in Arabidopsis results in early flowering. In addition, we have also revealed that the EdFT interacts with both EdFD1 and EdFD2. Overall, these data suggest that the EdFT, EdFD1 and EdFD2 are the functional homologs of FT and FD, respectively, which might act together to regulate loquat flowering through a similar mechanism found in Arabidopsis.

  5. Is FT3 by radioligandassay (RLA) superior in the diagnosis of hyperthyroidism (HT)

    Energy Technology Data Exchange (ETDEWEB)

    Bottger, I.G.; Pabst, H.W.

    1985-05-01

    Based upon our routine experience with more than 50,000/15,000 patients having been examined by FT4/FT3 RLA the authors reported a comparable clinical value of routine parameters for free thyroid hormones. The purpose of this study was to investigate the clinical performance of FT3 by RLA in borderline HT (BHT) in more detail. Two groups of patients were studied prospectively: group I: BHT, 48 sera, HT was suspected on grounds of clinical, scintigraphical and ultrasonic findings, no therapy. Subgroup Ia: negative TRH test (TSH before and after 200 ..mu..g TRH i.v. 0.8 mU/1), T4, FT4, T4/TBG ratio and T3 in the normal range (NR), 22 sera. Subgroup Ib: T3 (NR: 1.6 - 3.6 pmol/1): 3.7 - 3.9 and/or FT4 and/or T4/TBG ratio elevated, 26 sera. Group II: thyroid ablated patients with thyroid carcinoma on TSH-suppressive 1-T4 medication (200 ..mu..g/day) with a negative TRH test, no obvious symptoms of HT, T3 normal. RLAs employed routinely: FT4/T4 and FT3/T3 (kinetic, two-tube), and TBG, Corning Medical, TSH, Henning-Berlin. Group I: T3 levels were in the middle to upper NR, 9 (19 %) of Ib being elevated, T3/TBG was predominantly at the upper limit of the NR, 20 (42%) of this group and 5 (10%) of Ia being increased. 29 (60%) of the FT3 levels in I and 8 (17%) in Ia were elevated up to 15 and 13 pmol/l, respectively. Group II: the T3/TBG ratio was increased in 13 (11%) and the FT3 concentration up to 14 pmol/l in 57 (50%) sera.

  6. Is FT3 by radioligandassay (RLA) superior in the diagnosis of hyperthyroidism (HT)

    International Nuclear Information System (INIS)

    Bottger, I.G.; Pabst, H.W.

    1985-01-01

    Based upon our routine experience with more than 50,000/15,000 patients having been examined by FT4/FT3 RLA the authors reported a comparable clinical value of routine parameters for free thyroid hormones. The purpose of this study was to investigate the clinical performance of FT3 by RLA in borderline HT (BHT) in more detail. Two groups of patients were studied prospectively: group I: BHT, 48 sera, HT was suspected on grounds of clinical, scintigraphical and ultrasonic findings, no therapy. Subgroup Ia: negative TRH test (TSH before and after 200 μg TRH i.v. 0.8 mU/1), T4, FT4, T4/TBG ratio and T3 in the normal range (NR), 22 sera. Subgroup Ib: T3 (NR: 1.6 - 3.6 pmol/1): 3.7 - 3.9 and/or FT4 and/or T4/TBG ratio elevated, 26 sera. Group II: thyroid ablated patients with thyroid carcinoma on TSH-suppressive 1-T4 medication (200 μg/day) with a negative TRH test, no obvious symptoms of HT, T3 normal. RLAs employed routinely: FT4/T4 and FT3/T3 (kinetic, two-tube), and TBG, Corning Medical, TSH, Henning-Berlin. Group I: T3 levels were in the middle to upper NR, 9 (19 %) of Ib being elevated, T3/TBG was predominantly at the upper limit of the NR, 20 (42%) of this group and 5 (10%) of Ia being increased. 29 (60%) of the FT3 levels in I and 8 (17%) in Ia were elevated up to 15 and 13 pmol/l, respectively. Group II: the T3/TBG ratio was increased in 13 (11%) and the FT3 concentration up to 14 pmol/l in 57 (50%) sera

  7. Functional correlates of TSH, fT3 and fT4 in Alzheimer disease: a F-18 FDG PET/CT study.

    Science.gov (United States)

    Chiaravalloti, Agostino; Ursini, Francesco; Fiorentini, Alessandro; Barbagallo, Gaetano; Martorana, Alessandro; Koch, Giacomo; Tavolozza, Mario; Schillaci, Orazio

    2017-07-24

    The present study was aimed to investigate the relationships between thyroid stimulating hormone (TSH), freeT3 (fT3) and freeT4 (fT4) and brain glucose consumption as detectable by means of 2-deoxy-2-(F-18) fluoro-D-glucose (F-18 FDG) Positron Emission Tomography/Computed Tomography (PET/CT) in a selected population with Alzheimer disease (AD). We evaluated 87 subjects (37 males and 50 females, mean age 70 (±6) years old) with AD. All of them were subjected to TSH, fT3 and fT4 assay and to cerebrospinal fluid amyloid (Aβ1-42) and tau [phosphorylated-tau (p-tau) and total-tau (t-tau)] assay prior PET/CT examination. Values for TSH, fT3 and fT4 were in the normal range. The relationships were evaluated by means of statistical parametric mapping (SPM8) using age, sex, MMSE, scholarship and CSF values of amyloid and tau as covariates. We found a significant positive correlation between TSH values and cortical glucose consumption in a wide portion of the anterior cingulate cortex bilaterally (BA32) and left frontal lobe (BA25) (p FWE-corr <0.001; p FDRcorr <0.000; cluster extent 66950). No significant relationships were found between cortical F-18 FDG uptake and T3 and T4 serum levels. The results of our study suggest that a cortical dysfunction in anterior cingulate and frontal lobes may affect serum values of TSH in AD patients.

  8. An exploratory study of human teeth enamel by using Ft-Raman spectroscopy

    International Nuclear Information System (INIS)

    Afishah Alias; Siti Rahayu Mohd Hashim; Mihaly, Judith; Julyannie Wajir; Fauziah Abdul Aziz

    2009-01-01

    Unaffected , affected and heavily affected teeth enamel were studied by using FT-Raman spectroscopy. The 14 permanent teeths enamel surface were measured randomly, resulting in total n = 43 FT-Raman spectra. The results obtained from FT-Raman spectra of heavily affected, affected and unaffected tooths enamel surfaces did not show any significant difference. In this study, Kruskal-Wallis and Wilcoxon rank sum tests were used to compare the intensity between the categories of enamel as well as the surfaces of teeth samples. (author)

  9. Observational constraints on f(T) gravity from varying fundamental constants

    Energy Technology Data Exchange (ETDEWEB)

    Nunes, Rafael C.; Bonilla, Alexander [Universidade Federal de Juiz de Fora, Departamento de Fisica, Juiz de Fora, MG (Brazil); Pan, Supriya [Indian Institute of Science Education and Research, Kolkata, Department of Physical Sciences, Mohanpur, West Bengal (India); Saridakis, Emmanuel N. [Pontificia Universidad de Catolica de Valparaiso, Instituto de Fisica, Valparaiso (Chile); National Technical University of Athens, Physics Division, Athens (Greece); Baylor University, CASPER, Physics Department, Waco, TX (United States)

    2017-04-15

    We use observations related to the variation of fundamental constants, in order to impose constraints on the viable and most used f(T) gravity models. In particular, for the fine-structure constant we use direct measurements obtained by different spectrographic methods, while for the effective Newton constant we use a model-dependent reconstruction, using direct observational Hubble parameter data, in order to investigate its temporal evolution. We consider two f(T) models and we quantify their deviation from Λ CDM cosmology through a sole parameter. Our analysis reveals that this parameter can be slightly different from its Λ CDM value, however, the best-fit value is very close to the Λ CDM one. Hence, f(T) gravity is consistent with observations, nevertheless, as every modified gravity, it may exhibit only small deviations from Λ CDM cosmology, a feature that must be taken into account in any f(T) model-building. (orig.)

  10. Der Einsatz von Online-Datenbanken für Objektinnovationen im Systemgeschäft

    OpenAIRE

    Noch, Rainer

    1990-01-01

    Der Einsatz von Online-Datenbanken für Objektinnovationen im Systemgeschäft. - Augsburg : FGM-Verl., 1990. - 62, LVII S. - Zugl.: Augsburg, Univ., Diplomarb. - (Arbeitspapiere zur Schriftenreihe Schwerpunkt Marketing ; 31)

  11. Overexpression of PaFT gene in the wild orchid Phalaenopsis amabilis (L.) Blume

    Science.gov (United States)

    Semiarti, Endang; Mercuriani, Ixora S.; Rizal, Rinaldi; Slamet, Agus; Utami, Bekti S.; Bestari, Ida A.; Aziz-Purwantoro, Moeljopawiro, S.; Jang, Soenghoe; Machida, Y.; Machida, C.

    2015-09-01

    To shorten vegetative stage and induce transition from vegetative to reproductive stage in orchids, we overexpressed Phalaenopsis amabilis Flowering LocusT (PaFT) gene under the control of Ubiquitin promoter into protocorm of Indonesian Wild Orchid Phalaenopsis amabilis (L.) Blume. The dynamic expression of vegetative gene Phalaenopsis Homeobox1 (POH1) and flowering time gene PaFT has been analyzed. Accumulation of mRNA was detected in shoot and leaves of both transgenic and non transgenic plants by using Reverse transcriptase-PCR (RT-PCR) with specific gene primers for POH1 and PaFT in 24 months old plants. To analyze the POH1 and PaFT genes, three pairs of degenerate primers PaFT degF1R1, F2R2 and F3R3 that amplified 531 bp PaFT cDNA were used. We detected 700 bp PaFTcDNA from leaves and shoots of transgenic plants, but not in NT plants. POH1 mRNA was detected in plants. PaFT protein consists of Phospatidyl Ethanolamine-Binding Protein (PEBP) in interval base 73-483 and CETS family protein at base 7-519, which are important motif for transmembrane protein. We inserted Ubipro::PaFT/pGAS101 into P. amabilis protocorm using Agrobacterium. Analysis of transgenic plants showed that PaFTmRNA was accumulated in leaves of 12 months after sowing, although it is not detected in non transgeic plants. Compare to the wild type (NT plants), ectopic expression of PaFT shows alter phenotype as follows: 31% normal, 19% with short-wavy leaves, 5% form rosette leaves and 45% produced multishoots. Analysis of protein profiles of trasgenic plants showed that a putative PaFT protein (MW 19,7 kDa) was produced in 1eaves and shoots.This means that at 12 months, POH1 gene expression gradually decreased/negatively regulated, the expression of PaFT gene was activated, although there is no flower initiation yet. Some environmental factors might play a role to induce inflorescens. This experiment is in progress.

  12. Effect of microwave treatment on structure of binders based on sodium carboxymethyl starch: FT-IR, FT-Raman and XRD investigations

    Science.gov (United States)

    Kaczmarska, Karolina; Grabowska, Beata; Spychaj, Tadeusz; Zdanowicz, Magdalena; Sitarz, Maciej; Bobrowski, Artur; Cukrowicz, Sylwia

    2018-06-01

    The paper deals with the influence of the microwave treatment on sodium carboxymethyl starch (CMS-Na) applied as a binder for moulding sands. The Fourier transformation infrared spectrometry (FT-IR), Raman spectroscopy (FT-Raman) and XRD analysis data of native potato starch and three different carboxymethyl starches (CMS-Na) with various degree of substitution (DS) before and after exposition to microwave radiation have been compared. FT-IR studies showed that polar groups present in CMS-Na structure take part in the formation of new hydrogen bonds network after water evaporation. However, these changes depend on DS value of the modified starch. The FT-Raman study confirmed that due to the impact on the samples by microwave, the changes of intensity in the characteristic bands associated with the crystalline regions in the sample were noticed. The X-ray diffraction data for microwave treated CMS-Na samples have been compared with the diffractograms of initial materials and analysis of XRD patterns confirmed that microwave-treated samples exhibit completely amorphous structure. Analysis of structural changes allows to state that the binding of sand grains in moulding sand with CMS-Na polymeric binder consists in the formation of hydrogen bonds networks (physical cross-linking).

  13. Effect of microwave treatment on structure of binders based on sodium carboxymethyl starch: FT-IR, FT-Raman and XRD investigations.

    Science.gov (United States)

    Kaczmarska, Karolina; Grabowska, Beata; Spychaj, Tadeusz; Zdanowicz, Magdalena; Sitarz, Maciej; Bobrowski, Artur; Cukrowicz, Sylwia

    2018-06-15

    The paper deals with the influence of the microwave treatment on sodium carboxymethyl starch (CMS-Na) applied as a binder for moulding sands. The Fourier transformation infrared spectrometry (FT-IR), Raman spectroscopy (FT-Raman) and XRD analysis data of native potato starch and three different carboxymethyl starches (CMS-Na) with various degree of substitution (DS) before and after exposition to microwave radiation have been compared. FT-IR studies showed that polar groups present in CMS-Na structure take part in the formation of new hydrogen bonds network after water evaporation. However, these changes depend on DS value of the modified starch. The FT-Raman study confirmed that due to the impact on the samples by microwave, the changes of intensity in the characteristic bands associated with the crystalline regions in the sample were noticed. The X-ray diffraction data for microwave treated CMS-Na samples have been compared with the diffractograms of initial materials and analysis of XRD patterns confirmed that microwave-treated samples exhibit completely amorphous structure. Analysis of structural changes allows to state that the binding of sand grains in moulding sand with CMS-Na polymeric binder consists in the formation of hydrogen bonds networks (physical cross-linking). Copyright © 2018 Elsevier B.V. All rights reserved.

  14. Vibrational spectra (FT-IR, FT-Raman), frontier molecular orbital, first hyperpolarizability, NBO analysis and thermodynamics properties of Piroxicam by HF and DFT methods

    Science.gov (United States)

    Suresh, S.; Gunasekaran, S.; Srinivasan, S.

    2015-03-01

    The solid phase FT-IR and FT-Raman spectra of 4-Hydroxy-2-methyl-N-(2-pyridinyl)-2H-1,2-benzothiazine-3-carboxamide-1,1-dioxide (Piroxicam) have been recorded in the region 4000-400 and 4000-100 cm-1 respectively. The molecular geometry, harmonic vibrational frequencies and bonding features of piroxicam in the ground state have been calculated by Hartree-Fock (HF) and density functional theory (DFT) methods using 6-311++G(d,p) basis set. The calculated harmonic vibrational frequencies are scaled and they are compared with experimental obtained by FT-IR and FT-Raman spectra. A detailed interpretation of the vibrational spectra of the title compound has been made on the basis of the calculated potential energy distribution (PED). The electronic properties, such as HOMO and LUMO energies, molecular electrostatic potential (MESP) are also performed. The linear polarizability (α) and the first order hyper polarizability (β) values of the title compound have been computed. The molecular stability arising from hyper conjugative interaction, charge delocalization has been analyzed using natural bond orbital (NBO) analysis.

  15. TG/FT-IR characterization of additives typically employed in EPDM formulations

    Directory of Open Access Journals (Sweden)

    Natália Beck Sanches

    2015-06-01

    Full Text Available AbstractThermogravimetric analysis coupled to Fourier transform infrared spectroscopy (TG/FT-IR is a very popular technique for rubbers characterization. It involves analyses of the base polymer and additives. Ethylene–propylene–diene (EPDM rubbers are frequently investigated by TG/FT-IR; however, the focus has been the degradation temperature range of the polymer. In this study, unvulcanized and vulcanized EPDM rubber and its additives were investigated by TG/FT-IR, without solvent extraction, and in a wide temperature range. Initially, the additives were individually characterized. TG/FT-IR identified the characteristic groups of all the additives analyzed and distinguished them from each other. Afterwards, unvulcanized and vulcanized EPDM rubbers were investigated without prior extraction.TG/FT-IR detected absorptions due to the additives tetramethylthiuram monosulfide and 2-mercaptobenzothiazole. Both of these sulfur-containing additives were present in the EPDM formulation at concentrations of 0.7 phr (0.63 wt %. The TG/FT-IR technique had some limitations, because not all the additives in EPDM rubber were detected. Paraffin oil, stearic acid and 2,2,4-trimethyl-1,2-dihydroquinoline functional groups were not observed in either the unvulcanized or vulcanized EPDM. Nevertheless, in addition to the ability of this method to detect sulfur-containing groups, the lack of a pre-extraction reduces the time and effort required for additive analysis in rubbers.

  16. Developments in FT-ICR MS instrumentation, ionization techniques, and data interpretation methods for petroleomics.

    Science.gov (United States)

    Cho, Yunju; Ahmed, Arif; Islam, Annana; Kim, Sunghwan

    2015-01-01

    Because of the increasing importance of heavy and unconventional crude oil as an energy source, there is a growing need for petroleomics: the pursuit of more complete and detailed knowledge of the chemical compositions of crude oil. Crude oil has an extremely complex nature; hence, techniques with ultra-high resolving capabilities, such as Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS), are necessary. FT-ICR MS has been successfully applied to the study of heavy and unconventional crude oils such as bitumen and shale oil. However, the analysis of crude oil with FT-ICR MS is not trivial, and it has pushed analysis to the limits of instrumental and methodological capabilities. For example, high-resolution mass spectra of crude oils may contain over 100,000 peaks that require interpretation. To visualize large data sets more effectively, data processing methods such as Kendrick mass defect analysis and statistical analyses have been developed. The successful application of FT-ICR MS to the study of crude oil has been critically dependent on key developments in FT-ICR MS instrumentation and data processing methods. This review offers an introduction to the basic principles, FT-ICR MS instrumentation development, ionization techniques, and data interpretation methods for petroleomics and is intended for readers having no prior experience in this field of study. © 2014 Wiley Periodicals, Inc.

  17. FAKTOR-FAKTOR PENGHAMBAT PENGERJAAN TUGAS AKHIR SKRIPSI MAHASISWA PENDIDIKAN TEKNIK OTOMOTIF FT UNY

    Directory of Open Access Journals (Sweden)

    Ibnu Siswanto

    2015-06-01

    Full Text Available Tujuan yang ingin dicapai dalam penelitian ini ialah mengetahui dan mendeskripsikan secara faktual, akurat dan sistematis tentang 1 Implementasi pedoman penulisan tugas akhir skripsi mahasiswa FT UNY di Jurusan PT. Otomotif dan 2 Faktor-faktor yang menjadi penghambat dalam pengerjaan tugas akhir skripsi mahasiswa PT. Otomotif FT UNY Penelitian ini menggunakan pendekatan deskriptif. Objek penelitian ialah Koordinator tugas akhir skripsi, dosen pembimbing, dan mahasiswa PT. Otomotif FT UNY. Pengumpulan data dilakukan dengan wawancara dan dokumentasi. Teknik analisis data yang dipergunakan ialah metode analisis deskriptif.  Hasil penelitian menunjukkan bahwa 1 Implementasi pedoman penulisan tugas akhir skripsi di jurusan PT. Otomotif FT UNY dilakukan dengan pembentukan koordinator tugas akhir skripsi, pembagian tahapan-tahapan pengerjaan skripsi yang terdiri dari pengajuan judul, bimbingan, pengambilan data penelitian, dan ujian TAS sampai dengan pengeluaran nilai TAS. Semua dosen PT. Otomotif FT UNY melaksanakan bimbingan tugas akhir skripsi sesuai dengan pedoman penulisan tugas akhir skripsi. Jurusan PT. Otomotif FT UNY juga melakukan bimbingan klasikal bagi mahasiswa yang akan/sedang mengerjakan tugas akhir skripsi, 2 Faktor-faktor yang menjadi penghambat dalam pengerjaan tugas akhir skripsi yaitu kesulitan dalam menemukan permasalahan yang akan diangkat menjadi judul penelitian, mahasiswa fokus mengerjakan proyek akhir (mahasiswa angkatan 2008 ke bawah, fokus laporan KKN PPL, mengulang banyak mata kuliah, tidak rutin bimbingan dengan dosen, kesulitan dalam menulis karya tulis ilmiah.

  18. Relationships of storm-time changes in thermospheric mass density with solar wind/IMF parameters and ring current index of Sym-H

    Science.gov (United States)

    Zhou, Yunliang; Ma, S. Y.; Xiong, Chao; Luehr, Hermann

    The total air mass densities at about 500 km altitude are derived using super-STAR accelerom-eter measurements onboard GRACE satellites for 25 great magnetic storms with minimum Dst less than 100 nT during 2002 to 2006 years. Taking NRLMSISE-00 model-predicted densities without active ap index input as a reference baseline of quiet-time mass density, the storm-time changes in upper thermospheric mass densities are obtained by subtraction for all the storm events and sorted into different grids of latitude by local time sector. The relationships of the storm-time density changes with various interplanetary parameters and magnetospheric ring current index of Sym-H are statistically investigated. The parameters include Akasofu energy coupling function, the merging electric field Em, the magnitude of IMF component in the GSM y-z plane etc. as calculated from OMNI data at 1 AU. It is found that the storm-time changes in the upper thermospheric mass density have the best linear correlation with the Sym-H index in general, showing nearly zero time delay at low-latitudes and a little time ahead at high-latitudes for most cases. Unexpectedly, the magnitude of IMF component in the y-z plane, Byz, shows correlation with storm-time mass density changes better and closer than Akasofu function and even Em. And, the mass density changes lag behind Byz about 1-4 hours for most cases at low-latitudes. The correlations considered above are local time dependent, showing the lowest at dusk sectors. For the largest superstorm of November 2003, the changes in mass density are correlated very closely with Byz, Em, and Sym-H index, showing correlation coefficients averaged over all latitudes in noon sector as high as 0.93, 0.91 and 0.90 separately. The physical factors controlling the lag times between the mass density changes at mid-low-latitudes and the interplanetary parameter variations are also analyzed. The results in this study may pro-vide useful suggestions for establishing

  19. MSW Oscillations - LMA and Subdominant Effects

    International Nuclear Information System (INIS)

    Friedland, Alexander

    2011-01-01

    These notes, based on a talk given at the Neutrino 2006 conference [Neutrino 2006, Santa Fe, New Mexico, USA, (http://neutrinosantafe06.com/)], review the sensitivity of solar neutrinos to certain types of new physics, namely modifications of neutrino-matter interactions by the exchange of a new heavy particle and a large neutrino transition moment. Both were first proposed in the 1970's as possible explanations for the solar neutrino “problem” and were actively investigated for many years. While since ruled out as the dominant mechanisms of the solar neutrino flavor conversion, they remain of great interest as subdominant effects, which, if observed, would open a window to new physics. We outline the sensitivity of the current experiments and describe progress that may be expected in the near future.

  20. 基于FrFT-MUSIC的空时频算法%Space-time-frequency Algorithm Based on FrFT-MUSIC

    Institute of Scientific and Technical Information of China (English)

    张声杰; 刘梅

    2011-01-01

    针对传统时频分析方法难以对星载分布式合成孔径雷达(SAR)系统中地面目标速度进行准确估计的问题,提出了分数阶傅里叶变换(FrFT)-多重信号分类(MUSIC)空时频方法.利用FrFT获得信号向量并构造空时频分布矩阵;应用该分布矩阵替代传统MUSIC算法中的协方差矩阵,从而求得FrFT- MUSIC空时频谱,通过对谱函数进行搜索估计目标速度.仿真实验表明,该方法的目标速度估计精度高,抗噪声能力强.%The fractional Fourier transform (FrFT)-multipIe signal classification (MUSIC) space-time-frequency algorithm is proposed to solve the problem that it is difficult for the traditional time-frequency analysis method to accurately estimate the ground targets' azimuth speed which is coupled with spaceborne distributed synthetic aperture radar" (SAR). The signal vector is obtained and the space-time-frequency distribution matrix is formed by FrFT. Then, this distribution matrix is used instead of the traditional MUSIC covariance matrix to construct FrFT- MUSIC spectral function. Target speed is estimated by searching. Simulation results show that this algorithm has a high accuracy of parameter estimation and strong resistance to noise.

  1. Probing the End of the IMF in NGC 2024 with NIRCam on JWST: Assessing the Impact of Nebular Emission in Galactic Star Forming Regions

    Science.gov (United States)

    Suri, Veenu; Meyer, Michael; Greenbaum, Alexandra Z.; Bell, Cameron; Beichman, Charles; Gordon, Karl D.; Greene, Thomas P.; Hodapp, K.; Horner, Scott; Johnstone, Doug; Leisenring, Jarron; Manara, Carlos; Mann, Rita; Misselt, K.; Raileanu, Roberta; Rieke, Marcia; Roellig, Thomas

    2018-01-01

    We describe observations of the embedded young cluster associated with the HII region NGC 2024 planned as part of the guaranteed time observing program for the James Webb Space Telescope with the NIRCam (Near Infrared Camera) instrument. Our goal is to obtain a census of the cluster down to 2 Jupiter masses, viewed through 10-20 magnitudes of extinction, using multi-band filter photometry, both broadband filters and intermediate band filters that are expected to be sensitive to temperature and surface gravity. The cluster contains several bright point sources as well as extended emission due to reflected light, thermal emission from warm dust, as well as nebular line emission. We first developed techniques to better understand which point sources would saturate in our target fields when viewed through several JWST NIRCam filters. Using images of the field with the WISE satellite in filters W1 and W2, as well as 2MASS (J and H) bands, we devised an algorithm that takes the K-band magnitudes of point sources in the field, and the known saturation limits of several NIRCam filters to estimate the impact of the extended emission on survey sensitivity. We provide an overview of our anticipated results, detecting the low mass end of the IMF as well as planetary mass objects likely liberated through dynamical interactions.

  2. Annual report 1991 on R and D work by the Institute for Materials and Solid State Research (IMF), Karlsruhe Nuclear Research Center

    International Nuclear Information System (INIS)

    1992-03-01

    The annual report summarises the activities of the IMF in the following subject areas: 1) Contributions to the PKF (fusion technology project (refewing to structural materials, superconducting magnets, blanket development); 2) PSU, project for the management of pollutants in the environment (treatment and recycling of hazardous waste); 3) solid state and materials research (high-temperature materials, ceramic materials as protective coatings, polymer materials, high-performance ceramics, high-TC superconducting materials; biomechanics, laser technology); 4) microtechnology (development and testing of compact or layered materials in microtechnology); 5) PSF project, nuclear safety, research (safety and materials aspects of fast breeder reactors, transient behaviour of fuel elements in fact breeder reactors, LWR-specific safety research, containment design concepts for the next generation of PWR-type reactors); 6) NE project, nuclear waste management (analysis of solid wastes from the dissolution of spent LWR fuels, materials testing in nitric acid). The primary reports and other publications of the Institute issued in 1991 are listed in an annex. (orig./MM) [de

  3. Low FT3: a possible marker of frailty in the elderly

    Directory of Open Access Journals (Sweden)

    Bertoli A

    2017-02-01

    Full Text Available Aldo Bertoli,1 Alessia Valentini,1 Maria Assunta Cianfarani,1 Elena Gasbarra,2 Umberto Tarantino,2 Massimo Federici1 1Department of Systems Medicine, University of Rome “Tor Vergata”, Rome, Italy; 2Department of Orthopaedics and Traumatology, University of Rome “Tor Vergata”, Rome, Italy Introduction: Frailty is associated with a functional decline of multiple physiological systems, of which they may be a cause or consequence. The objective of the study was to evaluate the prevalence of thyroid hormone modifications in elderly frail subjects and its relationship with frailty.Study population and methods: An observational study was carried out at the University Hospital “Tor Vergata” in Rome among ambulatory and hospitalized patients. The study population consisted of 112 elderly subjects: 62 were hospitalized following hip fracture and 50 control subjects were outpatients. Participating patients received a multidimensional geriatric evaluation. The Survey of Health, Ageing and Retirement in Europe Frailty Instrument (SHARE-FI was used to assess the degree of frailty. Thyroid stimulating hormone (TSH, free triiodothyronine (FT3, and free thyroxine (FT4 were measured to evaluate thyroid status.Results: FT3, but not FT4, was significantly correlated with Frailty score, both in patients with hip fracture and in patients from the control group. In the entire study population, FT3 under normal limits is effective in discriminating frail/prefrail subjects from nonfrail subjects.Discussion: The reduction in serum concentrations of FT3 is a clear manifestation of stress associated with fractures. Numerous preexisting factors, such as the fracture patients’ nutritional status, sarcopenia, disability and comorbidities, which characterize the condition of frailty and influence its pathogenesis, are strongly correlated with FT3 values, suggesting the existence of latent nonthyroidal illness syndrome (NTIS.Conclusion: We conclude that measuring

  4. Spectroscopic investigation (FT-IR, FT-Raman), HOMO-LUMO, NBO, and molecular docking analysis of N-ethyl-N-nitrosourea, a potential anticancer agent

    Science.gov (United States)

    Singh, Priyanka; Islam, S. S.; Ahmad, Hilal; Prabaharan, A.

    2018-02-01

    Nitrosourea plays an important role in the treatment of cancer. N-ethyl-N-nitrosourea, also known as ENU, (chemical formula C3H7N3O2), is a highly potent mutagen. The chemical is an alkylating agent and acts by transferring the ethyl group of ENU to nucleobases (usually thymine) in nucleic acids. The molecular structure of N-ethyl-N-nitrosourea has been elucidated using experimental (FT-IR and FT-Raman) and theoretical (DFT) techniques. APT charges, Mulliken atomic charges, Natural bond orbital, Electrostatic potential, HOMO-LUMO and AIM analysis were performed to identify the reactive sites and charge transfer interactions. Furthermore, to evaluate the anticancer activity of ENU molecular docking studies were carried out against 2JIU protein.

  5. Application of Fourier transform infrared (FT-IR) spectroscopy in determination of microalgal compositions.

    Science.gov (United States)

    Meng, Yingying; Yao, Changhong; Xue, Song; Yang, Haibo

    2014-01-01

    Fourier transform infrared spectroscopy (FT-IR) was applied in algal strain screening and monitoring cell composition dynamics in a marine microalga Isochrysis zhangjiangensis during algal cultivation. The content of lipid, carbohydrate and protein of samples determined by traditional methods had validated the accuracy of FT-IR method. For algal screening, the band absorption ratios of lipid/amide I and carbo/amide I from FT-IR measurements allowed for the selection of Isochrysis sp. and Tetraselmis subcordiformis as the most potential lipid and carbohydrate producers, respectively. The cell composition dynamics of I. zhangjiangensis measured by FT-IR revealed the diversion of carbon allocation from protein to carbohydrate and neutral lipid when nitrogen-replete cells were subjected to nitrogen limitation. The carbo/amide I band absorption ratio had also been demonstrated to depict physiological status under nutrient stress in T. subcordiformis. FT-IR serves as a tool for the simultaneous measurement of lipid, carbohydrate, and protein content in cell. Copyright © 2013 Elsevier Ltd. All rights reserved.

  6. Beer fermentation: monitoring of process parameters by FT-NIR and multivariate data analysis.

    Science.gov (United States)

    Grassi, Silvia; Amigo, José Manuel; Lyndgaard, Christian Bøge; Foschino, Roberto; Casiraghi, Ernestina

    2014-07-15

    This work investigates the capability of Fourier-Transform near infrared (FT-NIR) spectroscopy to monitor and assess process parameters in beer fermentation at different operative conditions. For this purpose, the fermentation of wort with two different yeast strains and at different temperatures was monitored for nine days by FT-NIR. To correlate the collected spectra with °Brix, pH and biomass, different multivariate data methodologies were applied. Principal component analysis (PCA), partial least squares (PLS) and locally weighted regression (LWR) were used to assess the relationship between FT-NIR spectra and the abovementioned process parameters that define the beer fermentation. The accuracy and robustness of the obtained results clearly show the suitability of FT-NIR spectroscopy, combined with multivariate data analysis, to be used as a quality control tool in the beer fermentation process. FT-NIR spectroscopy, when combined with LWR, demonstrates to be a perfectly suitable quantitative method to be implemented in the production of beer. Copyright © 2014 Elsevier Ltd. All rights reserved.

  7. [Study of alkaline lignin from Arundo donax linn based on FT Raman spectroscopy].

    Science.gov (United States)

    You, Ting-ting; Ma, Jian-feng; Guo, Si-qin; Xu, Feng

    2014-08-01

    Arundo donax linn, as a perennial energy crop, has promising application prospect. In the present study, Fourier transform Raman (FT Raman) spectroscopy was applied to determine the structural information of materials, milled wood lignin (MWL), and alkaline lignins (AL, under different treated time) from A. donax stem nondestructively. The results indicated that, extractable compounds in A. donax had negative contribution to the Raman spectra without rising new Raman peaks. FT Raman spectrum of MWL indicated that MWL from A. donax was HGS type lignins. Compared with the spectra of MWL from wood materials, the peak at 1173 cm(-1) was much higher in intensity for the MWL from A. donax stem, which may be assigned to hydroxycinnamic acid by analyzing the standard. With respect to FT Raman spectra of ALs, the relatively highest intensity of 1173 cm(-1) was found in alkaline lignin (AL2), which was treated for 40 min by alkaline. Moreover, the peak of coniferaldehyde/sinapaldehyde (1630 cm(-1)) was lowest in intensity while the band attributed to coniferyl alcohol/sinapyl alcohol (1660 cm(-1)) was almost disappeared in AL2. It could be inferred that AL2 demonstrated a highest content of phenolic acid, which may improve its potential application, such as for antioxidant activity. Furthermore, the results obtained by FT Raman spectra were verified by two dimensional heteronuclear singlequantum coherence nuclear magnetic resonance analyses. Above all, FT Raman spectroscopy provided alternative safe, rapid, accurate, and nondestructive technology for lignin structure determination.

  8. FT-IR, FT-Raman, UV spectra and DFT calculations on monomeric and dimeric structure of 2-amino-5-bromobenzoic acid.

    Science.gov (United States)

    Karabacak, Mehmet; Cinar, Mehmet

    2012-02-01

    In this work, the molecular conformation, vibrational and electronic transition analysis of 2-amino-5-bromobenzoic acid (2A5BrBA) were presented for the ground state using experimental techniques (FT-IR, FT-Raman and UV) and density functional theory (DFT) employing B3LYP exchange correlation with the 6-311++G(d,p) basis set. FT-IR and FT-Raman spectra were recorded in the regions of 400-4000 cm(-1) and 50-4000 cm(-1), respectively. There are four conformers, C1, C2, C3 and C4 for this molecule. The geometrical parameters, energies and wavenumbers have been obtained for all four conformers. The computational results diagnose the most stable conformer of 2A5BrBA as the C1 form. The complete assignments of fundamental vibrations were performed on the basis of the total energy distribution (TED) of the vibrational modes, calculated with scaled quantum mechanics (SQM) method. Raman activities calculated by DFT method have been converted to the corresponding Raman intensities using Raman scattering theory. The UV spectra of investigated compound were recorded in the region of 200-400 nm for ethanol and water solutions. The electronic properties were evaluated with help of time-dependent DFT (TD-DFT) theoretically and results were compared with experimental observations. The thermodynamic properties of the studied compound at different temperatures were calculated, revealing the correlations between standard heat capacity, standard entropy, standard enthalpy changes and temperatures. The observed and the calculated geometric parameters, vibrational wavenumbers and electronic transitions were compared with observed data and found to be in good agreement. Copyright © 2011 Elsevier B.V. All rights reserved.

  9. Spontaneous atopic dermatitis-like symptoms in a/a ma ft/ma ft/J flaky tail mice appear early after birth.

    Directory of Open Access Journals (Sweden)

    Magdalini Kypriotou

    Full Text Available Loss-of-function mutations in human profilaggrin gene have been identified as the cause of ichthyosis vulgaris (IV, and as a major predisposition factor for atopic dermatitis (AD. Similarly, flaky tail (a/a ma ft/ma ft/J mice were described as a model for IV, and shown to be predisposed to eczema. The aim of this study was to correlate the flaky tail mouse phenotype with human IV and AD, in order to dissect early molecular events leading to atopic dermatitis in mice and men, suffering from filaggrin deficiency. Thus, 5-days old flaky tail pups were analyzed histologically, expression of cytokines was measured in skin and signaling pathways were investigated by protein analysis. Human biopsies of IV and AD patients were analyzed histologically and by real time PCR assays. Our data show acanthosis and hyperproliferation in flaky tail epidermis, associated with increased IL1β and thymic stromal lymphopoietin (TSLP expression, and Th2-polarization. Consequently, NFκB and Stat pathways were activated, and IL6 mRNA levels were increased. Further, quantitative analysis of late epidermal differentiation markers revealed increased Small proline-rich protein 2A (Sprr2a synthesis. Th2-polarization and Sprr2a increase may result from high TSLP expression, as shown after analysis of 5-days old K14-TSLP tg mouse skin biopsies. Our findings in the flaky tail mouse correlate with data obtained from patient biopsies of AD, but not IV. We propose that proinflammatory cytokines are responsible for acanthosis in flaky tail epidermis, and together with the Th2-derived cytokines lead to morphological changes. Accordingly, the a/a ma ft/ma ft/J mouse model can be used as an appropriate model to study early AD onset associated with profilaggrin deficiency.

  10. Çalışanların İş Güvencesizliğinin İşten Ayrılma Niyetleri Üzerindeki Etkisi: Alanya Bölgesindeki Beş Yıldızlı Otellerde Bir Araştırma

    OpenAIRE

    KARACAOĞLU, Korhan

    2018-01-01

    İş güvencesizliği, mevcut işin sürekliliğine engel olacak her türlü yasal veya yasal olmayan örgütsel değişimler sonucunda ortaya çıkan, işgörende, belirsizlik düşüncesine dayalı olarak işini kaybetme kaygısı doğuran durumlardır. Alan yazında iş güvencesizliğinin sonuçlarından biri olan işten ayrılma niyeti ise bir çalışanın yakın bir zamanda işine son verme isteğiyle ilgili düşüncesi olarak tanımlanmaktadır. Bu çalışmada iş güvencesizliği ile işten ayrılma niyeti arasındaki etkileşim Alanya ...

  11. Some aspects of reconstruction using a scalar field in f(T) gravity

    Energy Technology Data Exchange (ETDEWEB)

    Chakrabarti, Soumya [Indian Institute of Technology, Centre for Theoretical Studies, Kharagpur (India); Said, Jackson Levi [University of Malta, Institute of Space Sciences and Astronomy, Msida, MSD (Malta); Farrugia, Gabriel [University of Malta, Department of Physics, Msida, MSD (Malta)

    2017-12-15

    General relativity characterizes gravity as a geometric property exhibited on spacetime by massive objects, while teleparallel gravity achieves the same results at the level of equations, by taking a torsional perspective of gravity. Similar to the f(R) theory teleparallel gravity can also be generalized to f(T), with the resulting field equations being inherently distinct from f(R) gravity in that they are second order, while in the former case they turn out to be fourth order. In the present case, a minimally coupled scalar field is investigated in the f(T) gravity context for several forms of the scalar field potential. A number of new f(T) solutions are found for these potentials. Their respective state parameters are also being examined. (orig.)

  12. Determination of Free Fatty Acid by FT-NIR Spectroscopy in Esterification Reaction for Biodiesel Production

    Directory of Open Access Journals (Sweden)

    Djéssica Tatiana Raspe

    2013-01-01

    Full Text Available This work reports the use of FT-NIR spectroscopy coupled with multivariate calibration to determine the percentage of free fatty acids (FFA in samples obtained by the esterification of FFA in vegetable oils. The analytical method used as calibration matrix samples of the reaction medium of esterification of oleic acid in soybean oil in proportions of 0.3 to 40 wt% (by weight of oleic acid obtained under different experimental conditions and utilized the partial least squares (PLS regression. The efficiency of the method was tested to predict the content of FFA in reactions of esterification of oleic acid in soybean oil catalysed by KSF clay and Amberlyst 15 commercial resin, both in a batch mode. Good Correlations were observed between the FT-NIR/PLS method and the reference method (AOCS. The results confirm that FT-NIR spectroscopy, in combination with multivariate calibration, is a promising technique for monitoring esterification reaction for biodiesel production.

  13. A perturbative approach to neutron stars in f(T, T)-gravity

    Energy Technology Data Exchange (ETDEWEB)

    Pace, Mark; Said, Jackson Levi [University of Malta, Department of Physics, Msida (Malta); University of Malta, Institute of Space Sciences and Astronomy, Msida (Malta)

    2017-05-15

    We derive a Tolman-Oppenheimer-Volkoff equation in neutron star systems within the modified f(T, T)-gravity class of models using a perturbative approach. In our approach f(T, T)-gravity is considered to be a static spherically symmetric space-time. In this instance the metric is built from a more fundamental vierbein which can be used to relate inertial and global coordinates. A linear function f = T(r) + T(r) + χh(T, T) + O(χ{sup 2}) is taken as the Lagrangian density for the gravitational action. Finally we impose the polytropic equation of state of neutron star upon the derived equations in order to derive the mass profile and mass-central density relations of the neutron star in f(T, T)-gravity. (orig.)

  14. Analytic rotating black-hole solutions in N-dimensional f(T) gravity

    Energy Technology Data Exchange (ETDEWEB)

    Nashed, G.G.L. [The British University in Egypt, Centre for Theoretical Physics, P.O. Box 43, Cairo (Egypt); Ain Shams University, Faculty of Science, Mathematics Department, Cairo (Egypt); Egyptian Relativity Group (ERG), Cairo (Egypt); El Hanafy, W. [The British University in Egypt, Centre for Theoretical Physics, P.O. Box 43, Cairo (Egypt); Egyptian Relativity Group (ERG), Cairo (Egypt)

    2017-02-15

    A non-diagonal vielbein ansatz is applied to the N-dimension field equations of f(T) gravity. An analytical vacuum solution is derived for the quadratic polynomial f(T)=T+εT{sup 2} and an inverse relation between the coupling constant ε and the cosmological constant Λ. Since the induced metric has off-diagonal components, it cannot be removed by a mere coordinate transformation, the solution has a rotating parameter. The curvature and torsion scalars invariants are calculated to study the singularities and horizons of the solution. In contrast to general relativity, the Cauchy horizon differs from the horizon which shows the effect of the higher order torsion. The general expression of the energy-momentum vector of f(T) gravity is used to calculate the energy of the system. Finally, we have shown that this kind of solution satisfies the first law of thermodynamics in the framework of f(T) gravitational theories. (orig.)

  15. FT-IR spectrum of grape seed oil and quantum models of fatty acids triglycerides

    Science.gov (United States)

    Berezin, K. V.; Antonova, E. M.; Shagautdinova, I. T.; Chernavina, M. L.; Dvoretskiy, K. N.; Grechukhina, O. N.; Vasilyeva, L. M.; Rybakov, A. V.; Likhter, A. M.

    2018-04-01

    FT-IR spectra of grape seed oil and glycerol were registered in the 650-4000 cm-1 range. Molecular models of glycerol and some fatty acids that compose the oil under study - linoleic, oleic, palmitic and stearic acids - as well as their triglycerides were developed within B3LYP/6-31G(d) density functional model. A vibrating FT-IR spectrum of grape seed oil was modeled on the basis of calculated values of vibrating wave numbers and IR intensities of the fatty acids triglycerides and with regard to their percentage. Triglyceride spectral bands that were formed by glycerol linkage vibrations were revealed. It was identified that triglycerol linkage has a small impact on the structure of fatty acids and, consequently, on vibrating wave numbers. The conducted molecular modeling became a basis for theoretical interpretation on 10 experimentally observed absorption bands in FT-IR spectrum of grape seed oil.

  16. AKTIP/Ft1, a New Shelterin-Interacting Factor Required for Telomere Maintenance.

    KAUST Repository

    Burla, Romina; Carcuro, Mariateresa; Raffa, Grazia D; Galati, Alessandra; Raimondo, Domenico; Rizzo, Angela; La Torre, Mattia; Micheli, Emanuela; Ciapponi, Laura; Cenci, Giovanni; Cundari, Enrico; Musio, Antonio; Biroccio, Annamaria; Cacchione, Stefano; Gatti, Maurizio; Saggio, Isabella

    2015-01-01

    Telomeres are nucleoprotein complexes that protect the ends of linear chromosomes from incomplete replication, degradation and detection as DNA breaks. Mammalian telomeres are protected by shelterin, a multiprotein complex that binds the TTAGGG telomeric repeats and recruits a series of additional factors that are essential for telomere function. Although many shelterin-associated proteins have been so far identified, the inventory of shelterin-interacting factors required for telomere maintenance is still largely incomplete. Here, we characterize AKTIP/Ft1 (human AKTIP and mouse Ft1 are orthologous), a novel mammalian shelterin-bound factor identified on the basis of its homology with the Drosophila telomere protein Pendolino. AKTIP/Ft1 shares homology with the E2 variant ubiquitin-conjugating (UEV) enzymes and has been previously implicated in the control of apoptosis and in vesicle trafficking. RNAi-mediated depletion of AKTIP results in formation of telomere dysfunction foci (TIFs). Consistent with these results, AKTIP interacts with telomeric DNA and binds the shelterin components TRF1 and TRF2 both in vivo and in vitro. Analysis of AKTIP- depleted human primary fibroblasts showed that they are defective in PCNA recruiting and arrest in the S phase due to the activation of the intra S checkpoint. Accordingly, AKTIP physically interacts with PCNA and the RPA70 DNA replication factor. Ft1-depleted p53-/- MEFs did not arrest in the S phase but displayed significant increases in multiple telomeric signals (MTS) and sister telomere associations (STAs), two hallmarks of defective telomere replication. In addition, we found an epistatic relation for MST formation between Ft1 and TRF1, which has been previously shown to be required for replication fork progression through telomeric DNA. Ch-IP experiments further suggested that in AKTIP-depleted cells undergoing the S phase, TRF1 is less tightly bound to telomeric DNA than in controls. Thus, our results collectively

  17. AKTIP/Ft1, a New Shelterin-Interacting Factor Required for Telomere Maintenance.

    KAUST Repository

    Burla, Romina

    2015-06-25

    Telomeres are nucleoprotein complexes that protect the ends of linear chromosomes from incomplete replication, degradation and detection as DNA breaks. Mammalian telomeres are protected by shelterin, a multiprotein complex that binds the TTAGGG telomeric repeats and recruits a series of additional factors that are essential for telomere function. Although many shelterin-associated proteins have been so far identified, the inventory of shelterin-interacting factors required for telomere maintenance is still largely incomplete. Here, we characterize AKTIP/Ft1 (human AKTIP and mouse Ft1 are orthologous), a novel mammalian shelterin-bound factor identified on the basis of its homology with the Drosophila telomere protein Pendolino. AKTIP/Ft1 shares homology with the E2 variant ubiquitin-conjugating (UEV) enzymes and has been previously implicated in the control of apoptosis and in vesicle trafficking. RNAi-mediated depletion of AKTIP results in formation of telomere dysfunction foci (TIFs). Consistent with these results, AKTIP interacts with telomeric DNA and binds the shelterin components TRF1 and TRF2 both in vivo and in vitro. Analysis of AKTIP- depleted human primary fibroblasts showed that they are defective in PCNA recruiting and arrest in the S phase due to the activation of the intra S checkpoint. Accordingly, AKTIP physically interacts with PCNA and the RPA70 DNA replication factor. Ft1-depleted p53-/- MEFs did not arrest in the S phase but displayed significant increases in multiple telomeric signals (MTS) and sister telomere associations (STAs), two hallmarks of defective telomere replication. In addition, we found an epistatic relation for MST formation between Ft1 and TRF1, which has been previously shown to be required for replication fork progression through telomeric DNA. Ch-IP experiments further suggested that in AKTIP-depleted cells undergoing the S phase, TRF1 is less tightly bound to telomeric DNA than in controls. Thus, our results collectively

  18. Transcript Profile of Flowering Regulatory Genes in VcFT-Overexpressing Blueberry Plants.

    Directory of Open Access Journals (Sweden)

    Aaron E Walworth

    Full Text Available In order to identify genetic components in flowering pathways of highbush blueberry (Vaccinium corymbosum L., a transcriptome reference composed of 254,396 transcripts and 179,853 gene contigs was developed by assembly of 72.7 million reads using Trinity. Using this transcriptome reference and a query of flowering pathway genes of herbaceous plants, we identified potential flowering pathway genes/transcripts of blueberry. Transcriptome analysis of flowering pathway genes was then conducted on leaf tissue samples of transgenic blueberry cv. Aurora ('VcFT-Aurora', which overexpresses a blueberry FLOWERING LOCUS T-like gene (VcFT. Sixty-one blueberry transcripts of 40 genes showed high similarities to 33 known flowering-related genes of herbaceous plants, of which 17 down-regulated and 16 up-regulated genes were identified in 'VcFT-Aurora'. All down-regulated genes encoded transcription factors/enzymes upstream in the signaling pathway containing VcFT. A blueberry CONSTANS-LIKE 5-like (VcCOL5 gene was down-regulated and associated with five other differentially expressed (DE genes in the photoperiod-mediated flowering pathway. Three down-regulated genes, i.e., a MADS-AFFECTING FLOWERING 2-like gene (VcMAF2, a MADS-AFFECTING FLOWERING 5-like gene (VcMAF5, and a VERNALIZATION1-like gene (VcVRN1, may function as integrators in place of FLOWERING LOCUS C (FLC in the vernalization pathway. Because no CONSTAN1-like or FLOWERING LOCUS C-like genes were found in blueberry, VcCOL5 and VcMAF2/VcMAF5 or VRN1 might be the major integrator(s in the photoperiod- and vernalization-mediated flowering pathway, respectively. The major down-stream genes of VcFT, i.e., SUPPRESSOR of Overexpression of Constans 1-like (VcSOC1, LEAFY-like (VcLFY, APETALA1-like (VcAP1, CAULIFLOWER 1-like (VcCAL1, and FRUITFULL-like (VcFUL genes were present and showed high similarity to their orthologues in herbaceous plants. Moreover, overexpression of VcFT promoted expression of all of

  19. Designing means and specifications for model FT-619 kidney function instrument

    International Nuclear Information System (INIS)

    Yu Yongding

    1988-04-01

    In this paper, it is pointed out that the model FT-619 Kidney Function Equipment is a new cost-effective nuclear medicine instrument, which takes the leading position in China. The performance of the model FT-619,especially the lead collimated scintillation detector has reached the same level as the advanced equipment in the world market. It is also described in this article in detail that the design of the lead collimator and the shielding as well as the detection efficiency have achieved the optimum level and that a comparison has been made with foreign products

  20. Aeroderivative Pratt & Whitney FT8-3 gas turbine – an interesting solution for power generation

    Directory of Open Access Journals (Sweden)

    Sorinel-Gicu TALIF

    2011-03-01

    Full Text Available The intermediate load electric power stations become more and more interesting for theelectric power market in Romania. In this context, the Combined Cycle Power Plants came as a veryattractive solution. This paper presents the results of a study regarding the use of the aeroderivativePratt & Whitney FT8-3 gas turbine, available in Romania, for the electric power generation in aCombined Cycle Power Plant. It is also analyzed the Combined Heat in Power generation with FT8-3gas turbine when saturated steam or hot water are required.

  1. Transcript Profile of Flowering Regulatory Genes in VcFT-Overexpressing Blueberry Plants.

    Science.gov (United States)

    Walworth, Aaron E; Chai, Benli; Song, Guo-Qing

    2016-01-01

    In order to identify genetic components in flowering pathways of highbush blueberry (Vaccinium corymbosum L.), a transcriptome reference composed of 254,396 transcripts and 179,853 gene contigs was developed by assembly of 72.7 million reads using Trinity. Using this transcriptome reference and a query of flowering pathway genes of herbaceous plants, we identified potential flowering pathway genes/transcripts of blueberry. Transcriptome analysis of flowering pathway genes was then conducted on leaf tissue samples of transgenic blueberry cv. Aurora ('VcFT-Aurora'), which overexpresses a blueberry FLOWERING LOCUS T-like gene (VcFT). Sixty-one blueberry transcripts of 40 genes showed high similarities to 33 known flowering-related genes of herbaceous plants, of which 17 down-regulated and 16 up-regulated genes were identified in 'VcFT-Aurora'. All down-regulated genes encoded transcription factors/enzymes upstream in the signaling pathway containing VcFT. A blueberry CONSTANS-LIKE 5-like (VcCOL5) gene was down-regulated and associated with five other differentially expressed (DE) genes in the photoperiod-mediated flowering pathway. Three down-regulated genes, i.e., a MADS-AFFECTING FLOWERING 2-like gene (VcMAF2), a MADS-AFFECTING FLOWERING 5-like gene (VcMAF5), and a VERNALIZATION1-like gene (VcVRN1), may function as integrators in place of FLOWERING LOCUS C (FLC) in the vernalization pathway. Because no CONSTAN1-like or FLOWERING LOCUS C-like genes were found in blueberry, VcCOL5 and VcMAF2/VcMAF5 or VRN1 might be the major integrator(s) in the photoperiod- and vernalization-mediated flowering pathway, respectively. The major down-stream genes of VcFT, i.e., SUPPRESSOR of Overexpression of Constans 1-like (VcSOC1), LEAFY-like (VcLFY), APETALA1-like (VcAP1), CAULIFLOWER 1-like (VcCAL1), and FRUITFULL-like (VcFUL) genes were present and showed high similarity to their orthologues in herbaceous plants. Moreover, overexpression of VcFT promoted expression of all of these

  2. M4FT-15LL0806062-LLNL Thermodynamic and Sorption Data FY15 Progress Report

    Energy Technology Data Exchange (ETDEWEB)

    Zavarin, M. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Wolery, T. J. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

    2015-08-31

    This progress report (Milestone Number M4FT-15LL0806062) summarizes research conducted at Lawrence Livermore National Laboratory (LLNL) within Work Package Number FT-15LL080606. The focus of this research is the thermodynamic modeling of Engineered Barrier System (EBS) materials and properties and development of thermodynamic databases and models to evaluate the stability of EBS materials and their interactions with fluids at various physicochemical conditions relevant to subsurface repository environments. The development and implementation of equilibrium thermodynamic models are intended to describe chemical and physical processes such as solubility, sorption, and diffusion.

  3. M4FT-16LL080302052-Update to Thermodynamic Database Development and Sorption Database Integration

    Energy Technology Data Exchange (ETDEWEB)

    Zavarin, Mavrik [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States). Glenn T. Seaborg Inst.. Physical and Life Sciences; Wolery, T. J. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States). Akima Infrastructure Services, LLC; Atkins-Duffin, C. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States). Global Security

    2016-08-16

    This progress report (Level 4 Milestone Number M4FT-16LL080302052) summarizes research conducted at Lawrence Livermore National Laboratory (LLNL) within the Argillite Disposal R&D Work Package Number FT-16LL08030205. The focus of this research is the thermodynamic modeling of Engineered Barrier System (EBS) materials and properties and development of thermodynamic databases and models to evaluate the stability of EBS materials and their interactions with fluids at various physico-chemical conditions relevant to subsurface repository environments. The development and implementation of equilibrium thermodynamic models are intended to describe chemical and physical processes such as solubility, sorption, and diffusion.

  4. Ultra-clean Fischer-Tropsch (F-T) Fuels Production and Demonstration Project

    Energy Technology Data Exchange (ETDEWEB)

    Stephen P. Bergin

    2006-06-30

    The objective of the DOE-NETL Fischer-Tropsch (F-T) Production and Demonstration Program was to produce and evaluate F-T fuel derived from domestic natural gas. The project had two primary phases: (1) fuel production of ultra-clean diesel transportation fuels from domestic fossil resources; and (2) demonstration and performance testing of these fuels in engines. The project also included a well-to-wheels economic analysis and a feasibility study of small-footprint F-T plants (SFPs) for remote locations such as rural Alaska. During the fuel production phase, ICRC partnered and cost-shared with Syntroleum Corporation to complete the mechanical design, construction, and operation of a modular SFP that converts natural gas, via F-T and hydro-processing reactions, into hydrogensaturated diesel fuel. Construction of the Tulsa, Oklahoma plant started in August 2002 and culminated in the production of over 100,000 gallons of F-T diesel fuel (S-2) through 2004, specifically for this project. That fuel formed the basis of extensive demonstrations and evaluations that followed. The ultra-clean F-T fuels produced had virtually no sulfur (less than 1 ppm) and were of the highest quality in terms of ignition quality, saturation content, backend volatility, etc. Lubricity concerns were investigated to verify that commercially available lubricity additive treatment would be adequate to protect fuel injection system components. In the fuel demonstration and testing phase, two separate bus fleets were utilized. The Washington DC Metropolitan Area Transit Authority (WMATA) and Denali National Park bus fleets were used because they represented nearly opposite ends of several spectra, including: climate, topography, engine load factor, mean distance between stops, and composition of normally used conventional diesel fuel. Fuel evaluations in addition to bus fleet demonstrations included: bus fleet emission measurements; F-T fuel cold weather performance; controlled engine dynamometer

  5. The hidden flat like universe. Starobinsky-like inflation induced by f(T) gravity

    Energy Technology Data Exchange (ETDEWEB)

    El Hanafy, W. [The British University in Egypt, Centre for Theoretical Physics, P.O. Box 43, El Sherouk (Egypt); Egyptian Relativity Group, Giza (Egypt); Nashed, G.G.L. [The British University in Egypt, Centre for Theoretical Physics, P.O. Box 43, El Sherouk (Egypt); Ain Shams University, Mathematics Department, Faculty of Science, Cairo (Egypt); Egyptian Relativity Group, Giza (Egypt)

    2015-06-15

    We study a single-fluid component in a flat like universe (FLU) governed by f(T) gravity theories, where T is the teleparallel torsion scalar. The FLU model, regardless of the value of the spatial curvature k, identifies a special class of f(T) gravity theories. Remarkably, FLU f(T) gravity does not reduce to teleparallel gravity theory. In large Hubble spacetime the theory is consistent with the inflationary universe scenario and respects the conservation principle. The equation of state evolves similarly in all models k = 0,±1. We study the case when the torsion tensor consists of a scalar field, which enables to derive a quintessence potential from the obtained f(T) gravity theory. The potential produces Starobinsky-like model naturally without using a conformal transformation, with higher orders continuously interpolate between Starobinsky and quadratic inflation models. The slow-roll analysis shows double solutions, so that for a single value of the scalar tilt (spectral index) n{sub s} the theory can predict double tensor-to-scalar ratios r of E-mode and B-mode polarizations. (orig.)

  6. The hidden flat like universe. Starobinsky-like inflation induced by f(T) gravity

    International Nuclear Information System (INIS)

    El Hanafy, W.; Nashed, G.G.L.

    2015-01-01

    We study a single-fluid component in a flat like universe (FLU) governed by f(T) gravity theories, where T is the teleparallel torsion scalar. The FLU model, regardless of the value of the spatial curvature k, identifies a special class of f(T) gravity theories. Remarkably, FLU f(T) gravity does not reduce to teleparallel gravity theory. In large Hubble spacetime the theory is consistent with the inflationary universe scenario and respects the conservation principle. The equation of state evolves similarly in all models k = 0,±1. We study the case when the torsion tensor consists of a scalar field, which enables to derive a quintessence potential from the obtained f(T) gravity theory. The potential produces Starobinsky-like model naturally without using a conformal transformation, with higher orders continuously interpolate between Starobinsky and quadratic inflation models. The slow-roll analysis shows double solutions, so that for a single value of the scalar tilt (spectral index) n s the theory can predict double tensor-to-scalar ratios r of E-mode and B-mode polarizations. (orig.)

  7. Evaluation of Fungal Deterioration in Liquidambar orientalis Mill. heartwood by FT-IR and light microscopy.

    Science.gov (United States)

    Nural Yilgor; Dilek Dogu; Roderquita Moore; Evren Terzi; S. Nami Kartal

    2013-01-01

    The chemical and morphological changes in heartwood specimens of Liquidambar orientalis Mill. caused by the white-rot fungus Trametes versicolor and the brown-rot fungi Tyromyces palustris and Gloeophyllum trabeum were studied by wet chemistry, FT-IR, GC-MS analyses, and photo-...

  8. Assessment of Azithromycin in Pharmaceutical Formulation by Fourier-transform Infrared (FT-IR Transmission Spectroscopy

    Directory of Open Access Journals (Sweden)

    Muhammad Ali Mallah

    2011-12-01

    Full Text Available A simple, rapid and economical method for azithromycin quantification in solid tablet and capsule formulations has been developed by applying Fourier-transform Infrared (FT-IR transmission spectroscopy for regular quality monitoring. The newly developed method avoids the sample preparation, except grinding for pellet formation and does not involve consumption of any solvent as it absolutely eliminates the need of extraction. KBr pellets were employed for the appraisal of azithromycin while acquiring spectra of standards as well as samples on FT-IR. By selecting the FT-IR carbonyl band (C=O in the region 1,744–1,709 cm−1 the calibration model was developed based on simple Beer’s law. The excellent regression coefficient (R2 0.999 was accomplished for calibration set having standard error of calibration equal to 0.01 mg. The current work exposes that transmission FT-IR spectroscopy can definitely be applied to determine the exact amount of azithromycin to control the processing and quality of solid formulations with reduced cost and short analysis time.

  9. Non-trivial frames for f(T) theories of gravity and beyond

    International Nuclear Information System (INIS)

    Ferraro, Rafael; Fiorini, Franco

    2011-01-01

    Some conceptual issues concerning f(T) theories - a family of modified gravity theories based on absolute parallelism - are analyzed. Due to the lack of local Lorentz invariance, the autoparallel frames satisfying the field equations are evasive to an a priori physical understanding. We exemplify this point by working out the vierbein (tetrad) fields for closed and open Friedmann-Robertson-Walker cosmologies.

  10. The Fast Intelligent Tracking (F!T) tube: A CRT without a shadow mask

    NARCIS (Netherlands)

    Bergman, A.H.; Brink, van den H.B.; Budzelaar, F.P.M.; Engelaar, P.J.; Holtslag, A.H.M.; IJzerman, W.L.; Krijn, M.P.C.M.; Lieshout, van P.J.G.; Notari, A.; Willemsen, O.H.

    2003-01-01

    The F!T tube is a new type of CRT without a shadow mask. The primary function of the mask, color selection, is taken over by an electronic control system that guides the electron beams over the correct phosphor lines. The position of the beams is detected by means of dedicated structures on the

  11. Attenuated total reflectance-FT-IR spectroscopy for gunshot residue analysis: potential for ammunition determination.

    Science.gov (United States)

    Bueno, Justin; Sikirzhytski, Vitali; Lednev, Igor K

    2013-08-06

    The ability to link a suspect to a particular shooting incident is a principal task for many forensic investigators. Here, we attempt to achieve this goal by analysis of gunshot residue (GSR) through the use of attenuated total reflectance (ATR) Fourier transform infrared spectroscopy (FT-IR) combined with statistical analysis. The firearm discharge process is analogous to a complex chemical process. Therefore, the products of this process (GSR) will vary based upon numerous factors, including the specific combination of the firearm and ammunition which was discharged. Differentiation of FT-IR data, collected from GSR particles originating from three different firearm-ammunition combinations (0.38 in., 0.40 in., and 9 mm calibers), was achieved using projection to latent structures discriminant analysis (PLS-DA). The technique was cross (leave-one-out), both internally and externally, validated. External validation was achieved via assignment (caliber identification) of unknown FT-IR spectra from unknown GSR particles. The results demonstrate great potential for ATR-FT-IR spectroscopic analysis of GSR for forensic purposes.

  12. Near-wall effects in improved plasma confinement regimes in tokamak FT-2

    International Nuclear Information System (INIS)

    Budnikov, V.N.; D'yachenko, V.V.; Esipov, L.A.

    1997-01-01

    Transition to the regime of improved plasma confinement (H-mode) revealed in experiments on low hybrid heating in tokamak ft-2 is analyzed. Main attention is paid to processes, taking place in near-wall region. The data are correlated with results of experiments in large tokamaks

  13. Non-trivial frames for f(T) theories of gravity and beyond

    Energy Technology Data Exchange (ETDEWEB)

    Ferraro, Rafael, E-mail: ferraro@iafe.uba.ar [Instituto de Astronomia y Fisica del Espacio, Casilla de Correo 67, Sucursal 28, 1428 Buenos Aires (Argentina); Departamento de Fisica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria, Pabellon I, 1428 Buenos Aires (Argentina); Fiorini, Franco, E-mail: franco@iafe.uba.ar [Instituto de Astronomia y Fisica del Espacio, Casilla de Correo 67, Sucursal 28, 1428 Buenos Aires (Argentina)

    2011-08-03

    Some conceptual issues concerning f(T) theories - a family of modified gravity theories based on absolute parallelism - are analyzed. Due to the lack of local Lorentz invariance, the autoparallel frames satisfying the field equations are evasive to an a priori physical understanding. We exemplify this point by working out the vierbein (tetrad) fields for closed and open Friedmann-Robertson-Walker cosmologies.

  14. Synthetic Fischer-Tropsch (FT) JP-5/JP-8 Aviation Turbine Fuel Elastomer Compatibility

    National Research Council Canada - National Science Library

    Muzzell, Pat; Stavinoha, Leo; Chapin, Rebecca

    2005-01-01

    ... to seal performance may arise, possibly leading to fuel leakage. The key objective of this study was to compare and contrast the material compatibility of nitrile coupons and O-rings with selected petroleum-derived fuels, Fisher-Tropsch (FT...

  15. The application of FT-IR spectrum method in photocuring process for polyester acrylate

    International Nuclear Information System (INIS)

    Cao Jin; Lu Xianliang; Zhang Zhenli

    1995-01-01

    This paper describes that the UV curing process of polyester acrylate can be monitored by measuring the degree of double bonds conversion with FT-IR spectroscopy. The various factors effect the UV curing rate. The relation between the curing rate and the concentration of photoinitiator, crosslinking agent, UV light intensity was discussed. (author)

  16. Agrobacterium-mediated transient MaFT expression in mulberry (Morus alba L.) leaves.

    Science.gov (United States)

    Wu, Su-Li; Yang, Xiao-Bing; Liu, Li-Qun; Jiang, Tao; Wu, Hai; Su, Chao; Qian, Yong-Hua; Jiao, Feng

    2015-01-01

    To optimize Agrobacterium-mediated transient transformation assay in mulberry (Morus alba L.), various infiltration methods, Agrobacterium tumefaciens (A. tumefaciens) strains, and bacterial concentrations were tested in mulberry seedlings. Compared with LBA4404, GV3101 harboring pBE2133 plasmids presented stronger GUS signals at 3 days post infiltration using syringe. Recombinant plasmids pBE2133:GFP and pBE2133:GFP:MaFT were successfully constructed. Transient expression of MaFT:GFP protein was found in leaves, petiole (cross section), and shoot apical meristem (SAM) of mulberry according to the GFP signal. Moreover, MaFT:GFP mRNA was also detected in leaves and SAM via RT-PCR and qRT-PCR. An efficient transient transformation system could be achieved in mulberry seedlings by syringe using A. tumefaciens GV3101 at the OD600 of 0.5. The movement of MaFT expression from leaves to SAM might trigger the precocious flowering of mulberry.

  17. Utility Assessment Report for SPIDERS Phase 2: Ft. Carson (Rev 1.0)

    Energy Technology Data Exchange (ETDEWEB)

    Barr, Jonathan L. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Tuffner, Francis K. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Hadley, Mark D. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Schneider, Kevin P. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    2014-01-01

    This document contains the Utility Assessment Report (UAR) for the Phase 2 operational Demonstration (OD) of the Smart Power Infrastructure Demonstration for Energy Reliability and Security (SPIDERS) Joint Capability Technology Demonstration (JCTD). The UAR for Phase 2 shows that the SPIDERS system was able to meet the requirements of the Implementation Directive at Ft. Carson.

  18. Advanced sampling techniques for hand-held FT-IR instrumentation

    Science.gov (United States)

    Arnó, Josep; Frunzi, Michael; Weber, Chris; Levy, Dustin

    2013-05-01

    FT-IR spectroscopy is the technology of choice to identify solid and liquid phase unknown samples. The challenging ConOps in emergency response and military field applications require a significant redesign of the stationary FT-IR bench-top instruments typically used in laboratories. Specifically, field portable units require high levels of resistance against mechanical shock and chemical attack, ease of use in restrictive gear, extreme reliability, quick and easy interpretation of results, and reduced size. In the last 20 years, FT-IR instruments have been re-engineered to fit in small suitcases for field portable use and recently further miniaturized for handheld operation. This article introduces the HazMatID™ Elite, a FT-IR instrument designed to balance the portability advantages of a handheld device with the performance challenges associated with miniaturization. In this paper, special focus will be given to the HazMatID Elite's sampling interfaces optimized to collect and interrogate different types of samples: accumulated material using the on-board ATR press, dispersed powders using the ClearSampler™ tool, and the touch-to-sample sensor for direct liquid sampling. The application of the novel sample swipe accessory (ClearSampler) to collect material from surfaces will be discussed in some detail. The accessory was tested and evaluated for the detection of explosive residues before and after detonation. Experimental results derived from these investigations will be described in an effort to outline the advantages of this technology over existing sampling methods.

  19. 1064nm FT-Raman spectroscopy for investigations of plant cell walls and other biomass materials

    Science.gov (United States)

    Umesh P. Agarwal

    2014-01-01

    Raman spectroscopy with its various special techniques and methods has been applied to study plant biomass for about 30 years. Such investigations have been performed at both macro- and micro-levels. However, with the availability of the Near Infrared (NIR) (1064 nm) Fourier Transform (FT)-Raman instruments where, in most materials, successful fluorescence suppression...

  20. Antioxidant activity and FT-IR analysis of Datura innoxia and Datura ...

    African Journals Online (AJOL)

    Materials and Methods: Determination of total phenolic content and total flavonoid content and antioxidant activity in terms of total antioxidant assay, ABTS assay, DPPH assay and in-vitro lipid peroxidation inhibiting activity were determined along with the FT-IR (Fourier transform infrared spectroscopy) analysis of the ...

  1. Transcript Profile of Flowering Regulatory Genes in VcFT-Overexpressing Blueberry Plants

    Science.gov (United States)

    Walworth, Aaron E.; Chai, Benli; Song, Guo-qing

    2016-01-01

    In order to identify genetic components in flowering pathways of highbush blueberry (Vaccinium corymbosum L.), a transcriptome reference composed of 254,396 transcripts and 179,853 gene contigs was developed by assembly of 72.7 million reads using Trinity. Using this transcriptome reference and a query of flowering pathway genes of herbaceous plants, we identified potential flowering pathway genes/transcripts of blueberry. Transcriptome analysis of flowering pathway genes was then conducted on leaf tissue samples of transgenic blueberry cv. Aurora (‘VcFT-Aurora’), which overexpresses a blueberry FLOWERING LOCUS T-like gene (VcFT). Sixty-one blueberry transcripts of 40 genes showed high similarities to 33 known flowering-related genes of herbaceous plants, of which 17 down-regulated and 16 up-regulated genes were identified in ‘VcFT-Aurora’. All down-regulated genes encoded transcription factors/enzymes upstream in the signaling pathway containing VcFT. A blueberry CONSTANS-LIKE 5-like (VcCOL5) gene was down-regulated and associated with five other differentially expressed (DE) genes in the photoperiod-mediated flowering pathway. Three down-regulated genes, i.e., a MADS-AFFECTING FLOWERING 2-like gene (VcMAF2), a MADS-AFFECTING FLOWERING 5-like gene (VcMAF5), and a VERNALIZATION1-like gene (VcVRN1), may function as integrators in place of FLOWERING LOCUS C (FLC) in the vernalization pathway. Because no CONSTAN1-like or FLOWERING LOCUS C-like genes were found in blueberry, VcCOL5 and VcMAF2/VcMAF5 or VRN1 might be the major integrator(s) in the photoperiod- and vernalization-mediated flowering pathway, respectively. The major down-stream genes of VcFT, i.e., SUPPRESSOR of Overexpression of Constans 1-like (VcSOC1), LEAFY-like (VcLFY), APETALA1-like (VcAP1), CAULIFLOWER 1-like (VcCAL1), and FRUITFULL-like (VcFUL) genes were present and showed high similarity to their orthologues in herbaceous plants. Moreover, overexpression of VcFT promoted expression of all

  2. Putative sugarcane FT/TFL1 genes delay flowering time and alter reproductive architecture in Arabidopsis

    Directory of Open Access Journals (Sweden)

    Carla P. Coelho

    2014-05-01

    Full Text Available Agriculturally important grasses such as rice, maize and sugarcane are evolutionarily distant from Arabidopsis, yet some components of the floral induction process are highly conserved. Flowering in sugarcane is an important factor that negatively affects cane yield and reduces sugar/ethanol production from this important perennial bioenergy crop. Comparative studies have facilitated the identification and characterization of putative orthologs of key flowering time genes in sugarcane, a complex polyploid plant whose genome has yet to be sequenced completely. Using this approach we identified phosphatidylethanolamine-binding protein (PEBP gene family members in sugarcane that are similar to the archetypical FT and TFL1 genes of Arabidopsis that play an essential role in controlling the transition from vegetative to reproductive growth. Expression analysis of ScTFL1, which falls into the TFL1-clade of floral repressors, showed transcripts in developing leaves surrounding the shoot apex but not at the apex itself. ScFT1 was detected in immature leaves and apical regions of vegetatively growing plants and, after the floral transition, expression also occurred in mature leaves. Ectopic over-expression of ScTFL1 in Arabidopsis caused delayed flowering in Arabidopsis, as might be expected for a gene related to TFL1. In addition, lines with the latest flowering phenotype exhibited aerial rosette formation. Unexpectedly, over-expression of ScFT1, which has greatest similarity to the florigen-encoding FT, also caused a delay in flowering. This preliminary analysis of divergent sugarcane FT and TFL1 gene family members from Saccharum spp. suggests that their expression patterns and roles in the floral transition has diverged from the predicted role of similar PEBP family members.

  3. Putative sugarcane FT/TFL1 genes delay flowering time and alter reproductive architecture in Arabidopsis.

    Science.gov (United States)

    Coelho, Carla P; Minow, Mark A A; Chalfun-Júnior, Antonio; Colasanti, Joseph

    2014-01-01

    Agriculturally important grasses such as rice, maize, and sugarcane are evolutionarily distant from Arabidopsis, yet some components of the floral induction process are highly conserved. Flowering in sugarcane is an important factor that negatively affects cane yield and reduces sugar/ethanol production from this important perennial bioenergy crop. Comparative studies have facilitated the identification and characterization of putative orthologs of key flowering time genes in sugarcane, a complex polyploid plant whose genome has yet to be sequenced completely. Using this approach we identified phosphatidylethanolamine-binding protein (PEBP) gene family members in sugarcane that are similar to the archetypical FT and TFL1 genes of Arabidopsis that play an essential role in controlling the transition from vegetative to reproductive growth. Expression analysis of ScTFL1, which falls into the TFL1-clade of floral repressors, showed transcripts in developing leaves surrounding the shoot apex but not at the apex itself. ScFT1 was detected in immature leaves and apical regions of vegetatively growing plants and, after the floral transition, expression also occurred in mature leaves. Ectopic over-expression of ScTFL1 in Arabidopsis caused delayed flowering in Arabidopsis, as might be expected for a gene related to TFL1. In addition, lines with the latest flowering phenotype exhibited aerial rosette formation. Unexpectedly, over-expression of ScFT1, which has greatest similarity to the florigen-encoding FT, also caused a delay in flowering. This preliminary analysis of divergent sugarcane FT and TFL1 gene family members from Saccharum spp. suggests that their expression patterns and roles in the floral transition has diverged from the predicted role of similar PEBP family members.

  4. Curcumin-β-cyclodextrin inclusion complex: stability, solubility, characterisation by FT-IR, FT-Raman, X-ray diffraction and photoacoustic spectroscopy, and food application.

    Science.gov (United States)

    Mangolim, Camila Sampaio; Moriwaki, Cristiane; Nogueira, Ana Claudia; Sato, Francielle; Baesso, Mauro Luciano; Neto, Antônio Medina; Matioli, Graciette

    2014-06-15

    Curcumin was complexed with β-CD using co-precipitation, freeze-drying and solvent evaporation methods. Co-precipitation enabled complex formation, as indicated by the FT-IR and FT-Raman techniques via the shifts in the peaks that were assigned to the aromatic rings of curcumin. In addition, photoacoustic spectroscopy and X-ray diffraction, with the disappearance of the band related to aromatic rings, by Gaussian fitting, and modifications in the spectral lines, respectively, also suggested complex formation. The possible complexation had an efficiency of 74% and increased the solubility of the pure colourant 31-fold. Curcumin-β-CD complex exhibited a sunlight stability 18% higher than the pure colourant. This material was stable to pH variations and storage at -15 and 4°C. With an isothermal heating at 100 and 150°C for 2h, the material exhibited a colour retention of approximately 99%. The application of curcumin-β-CD complex in vanilla ice creams intensified the colour of the products and produced a great sensorial acceptance. Copyright © 2013 Elsevier Ltd. All rights reserved.

  5. Acid-base properties, FT-IR, FT-Raman spectroscopy and computational study of 1-(pyrid-4-yl)piperazine.

    Science.gov (United States)

    Mary, Y Sheena; Panicker, C Yohannan; Varghese, Hema Tresa; Van Alsenoy, Christian; Procházková, Markéta; Sevčík, Richard; Pazdera, Pavel

    2014-01-01

    We report the vibrational spectral analysis was carried out using FT-IR and FT-Raman spectroscopy for 1-(pyrid-4-yl)piperazine (PyPi). Single crystals of PyPi suitable for X-ray structural analysis were obtained. The acid-base properties are also reported. PyPi supported on a weak acid cation-exchanger in the single protonated form and this system can be used efficiently as the solid supported analogue of 4-N,N-dimethyl-aminopyridine. The complete vibrational assignments of wavenumbers were made on the basis of potential energy distribution. The HOMO and LUMO analysis is used to determine the charge transfer within the molecule and with the molecular electrostatic potential map was applied for the reactivity assessment of PyPi molecule toward proton, electrophiles and nucleopholes as well. The stability of the molecule arising from hyper-conjugative interaction and charge delocalization has been analyzed using NBO analysis. The calculated first hyperpolarizability of PyPi is 17.46 times that of urea. Copyright © 2013 Elsevier B.V. All rights reserved.

  6. Ab initio and DFT study of hydrogen bond interactions between ascorbic acid and dimethylsulfoxide based on FT-IR and FT-Raman spectra

    Science.gov (United States)

    Niazazari, Naser; Zatikyan, Ashkhen L.; Markarian, Shiraz A.

    2013-06-01

    The hydrogen bonding of 1:1 complexes formed between L-ascorbic acid (LAA) and dimethylsulfoxide (DMSO) has been studied by means of ab initio and density functional theory (DFT) calculations. Solutions of L-ascorbic acid (AA) in dimethylsulfoxide (DMSO) have been studied by means of both FT-IR (4000-220 cm-1) and FT-Raman spectroscopy. Ab initio Hartree-Fock (HF) and DFT methods have been used to determine the structure and energies of stable conformers of various types of L-AA/DMSO complexes in gas phase and solution. The basis sets 6-31++G∗∗ and 6-311+G∗ were used to describe the structure, energy, charges and vibrational frequencies of interacting complexes in the gas phase. The optimized geometric parameters and interaction energies for various complexes at different theories have been estimated. Binding energies have been corrected for basis set superposition error (BSSE) and harmonic vibrational frequencies of the structures have been calculated to obtain the stable forms of the complexes. The self-consistent reaction field (SCRF) has been used to calculate the effect of DMSO as the solvent on the geometry, energy and charges of complexes. The solvent effect has been studied using the Onsager models. It is shown that the polarity of the solvent plays an important role on the structures and relative stabilities of different complexes. The results obtained show that there is a satisfactory correlation between experimental and theoretical predictions.

  7. Molecular vibrational investigation [FT-IR, FT-Raman, UV-Visible and NMR] on Bis(thiourea) Nickel chloride using HF and DFT calculations

    Science.gov (United States)

    Anand, S.; Sundararajan, R. S.; Ramachandraraja, C.; Ramalingam, S.; Durga, R.

    2015-03-01

    In the present research work, the FT-IR, FT-Raman spectra of the Bis(thiourea) Nickel chloride (BTNC) were recorded and analyzed. The observed fundamental frequencies in finger print and functional group regions were assigned according to their uniqueness region. The computational calculations were carried out by HF and DFT (B3LYP and B3PW91) methods with 6-31++G(d,p) and 6-311++G(d,p) basis sets and the corresponding results were tabulated. The present organo-metallic compound was made up of covalent and coordination covalent bonds. The modified vibrational pattern of the complex molecule associated with ligand group was analyzed. Furthermore, the 13C NMR and 1H NMR spectral data were calculated by using the gauge independent atomic orbital (GIAO) method with B3LYP/6-311++G(d,p) basis set and their spectra were simulated and the chemical shifts linked to TMS were compared. A investigation on the electronic and optical properties; absorption wavelengths, excitation energy, dipole moment and frontier molecular orbital energies were carried out. The kubo gap of the present compound was calculated related to HOMO and LUMO energies which confirm the occurring of charge transformation between the base and ligand. Besides frontier molecular orbitals (FMO), molecular electrostatic potential (MEP) was performed. The NLO properties related to Polarizability and hyperpolarizability based on the finite-field approach were also discussed.

  8. Spectroscopic [FT-IR and FT-Raman] and theoretical [UV-Visible and NMR] analysis on α-Methylstyrene by DFT calculations

    Science.gov (United States)

    Karthikeyan, N.; Joseph Prince, J.; Ramalingam, S.; Periandy, S.

    2015-05-01

    In the present research work, the FT-IR, FT-Raman and 13C and 1H NMR spectra of the α-Methylstyrene were recorded. The observed fundamental frequencies in finger print as well as functional group regions were assigned according to their uniqueness region. The Gaussian computational calculations are carried out by HF and DFT (B3LYP and B3PW91) methods with 6-31++G(d,p) and 6-311++G(d,p) basis sets and the corresponding results were tabulated. The impact of the presence of vinyl group in phenyl structure of the compound is investigated. The modified vibrational pattern of the molecule associated vinyl group was analyzed. Moreover, 13C NMR and 1H NMR were calculated by using the gauge independent atomic orbital (GIAO) method with B3LYP methods and the 6-311++G(d,p) basis set and their spectra were simulated and the chemical shifts linked to TMS were compared. A study on the electronic and optical properties; absorption wavelengths, excitation energy, dipole moment and frontier molecular orbital energies were carried out. The kubo gap of the present compound was calculated related to HOMO and LUMO energies which confirm the occurring of charge transformation between the base and ligand. Besides frontier molecular orbitals (FMO), molecular electrostatic potential (MEP) was performed. The NLO properties related to Polarizability and hyperpolarizability based on the finite-field approach were also discussed.

  9. Prediction of purine derivatives, creatinine and total nitrogen concentrations in urine by FT-Near-lnfrared Reflectance spectroscopy (FT-NIR)

    International Nuclear Information System (INIS)

    Susmel, P.; Piani, B.; Toso, B.; Stefanon, B.

    2004-01-01

    The objective of this study was to provide an alternative method for the determination of purine derivatives (PD, which include allantoin, uric acid, hypoxanthine and xanthine), creatinine and total nitrogen (N) concentrations in urine. About 180 urine samples from cattle, buffaloes and rabbit were collected and analyzed for PD by HPLC, creatinine by spectrophotometry and N by Kjeldahl method. The urine samples were then analyzed by Fourier Transformed Near Infrared Reflectance Spectroscopy (FT-NIR) to find conformity between this technique and the HPLC and colorimetric methods. FT-NIR can predict allantoin, uric acid, hypoxanthine, xanthine, creatinine, total N and sum of N in both allantoin and uric acid with a satisfactory level of accuracy: the determination coefficient (r 2 ) of validation ranged from 0.888% for uric acid to 0.982% for total N. The coefficients of determination for allantoin, creatinine and sum of N in both allantoin and uric acid were 0.92, 0.894 and 0.90%, respectively. Hypoxanthine and xanthine in urine samples were not detectable by NIRS, probably because of their low concentrations, and therefore they were not considered for instrumental calibration. (author)

  10. Evaluation of a setting reaction pathway in the novel composite TiHA-CSD bone cement by FT-Raman and FT-IR spectroscopy

    Science.gov (United States)

    Paluszkiewicz, Czesława; Czechowska, Joanna; Ślósarczyk, Anna; Paszkiewicz, Zofia

    2013-02-01

    The aim of this study was to determine a setting reaction pathway in a novel, surgically handy implant material, based on calcium sulfate hemihydrate (CSH) and titanium doped hydroxyapatite (TiHA). The previous studies confirmed superior biological properties of TiHA in comparison to the undoped hydroxyapatite (HA) what makes it highly attractive for future medical applications. In this study the three types of titanium modified HA powders: untreated, calcined at 800 °C, sintered at 1250 °C and CSH were used to produce bone cements. The Fourier Transform-InfraRed (FT-IR) spectroscopy and Raman spectroscopy were applied to evaluate processes taking place during the setting of the studied materials. Our results undoubtedly confirmed that the reaction pathways and the phase compositions differed significantly for set cements and were dependent on the initial heat treatment of TiHA powder. Final materials were multiphase composites consisting of calcium sulfate dihydrate, bassanite, tricalcium phosphate, hydroxyapatite and calcium titanate (perovskite). The FT-IR and Scanning Electron Microscopy (SEM) measurements performed after the incubation of the cement samples in the simulated body fluid (SBF), indicate on high bioactive potential of the obtained bone cements.

  11. Experimental and theoretical studies of (FT-IR, FT-Raman, UV-Visible and DFT) 4-(6-methoxynaphthalen-2-yl) butan-2-one.

    Science.gov (United States)

    Govindasamy, P; Gunasekaran, S

    2015-01-01

    In this work, the vibrational spectral analysis was carried out by using FT-Raman and FT-IR spectroscopy in the range 4000-50 cm(-1) and 4000-450 cm(-1) respectively for 4-(6-methoxynaphthalen-2-yl) butan-2-one (abbreviated as 4MNBO) molecule. Theoretical calculations were performed by density functional theory (DFT/B3LYP) method using 6-311G(d,p) and 6-311++G(d,p) basis sets. The difference between the observed and calculated wavenumber value of most of the fundamentals were very small. The complete vibrational assignments of wavenumbers were made on the basis of potential energy distribution (PED). The UV-Vis spectrum was recorded in the methanol solution. The energy, wavelength and oscillator's strength were calculated by Time Dependent Density Functional Theory (TD-DFT) and matched to the experimental findings. The intramolecular contacts have been interpreted using natural bond orbital (NBO) and natural localized molecular orbital (NLMO) analysis. Thermodynamic properties of 4MNBO at different temperature have been calculated. The molecular electrostatic potential surface (MESP) and Frontier molecular orbital's (FMO's) analysis were investigated using theoretical calculations. Copyright © 2015 Elsevier B.V. All rights reserved.

  12. Molecular vibrational investigation [FT-IR, FT-Raman, UV-Visible and NMR] on Bis(thiourea) Nickel chloride using HF and DFT calculations.

    Science.gov (United States)

    Anand, S; Sundararajan, R S; Ramachandraraja, C; Ramalingam, S; Durga, R

    2015-03-05

    In the present research work, the FT-IR, FT-Raman spectra of the Bis(thiourea) Nickel chloride (BTNC) were recorded and analyzed. The observed fundamental frequencies in finger print and functional group regions were assigned according to their uniqueness region. The computational calculations were carried out by HF and DFT (B3LYP and B3PW91) methods with 6-31++G(d,p) and 6-311++G(d,p) basis sets and the corresponding results were tabulated. The present organo-metallic compound was made up of covalent and coordination covalent bonds. The modified vibrational pattern of the complex molecule associated with ligand group was analyzed. Furthermore, the (13)C NMR and (1)H NMR spectral data were calculated by using the gauge independent atomic orbital (GIAO) method with B3LYP/6-311++G(d,p) basis set and their spectra were simulated and the chemical shifts linked to TMS were compared. A investigation on the electronic and optical properties; absorption wavelengths, excitation energy, dipole moment and frontier molecular orbital energies were carried out. The kubo gap of the present compound was calculated related to HOMO and LUMO energies which confirm the occurring of charge transformation between the base and ligand. Besides frontier molecular orbitals (FMO), molecular electrostatic potential (MEP) was performed. The NLO properties related to Polarizability and hyperpolarizability based on the finite-field approach were also discussed. Crown Copyright © 2014. Published by Elsevier B.V. All rights reserved.

  13. Preparation and characterizations of SnO2 nanopowder and spectroscopic (FT-IR, FT-Raman, UV-Visible and NMR) analysis using HF and DFT calculations.

    Science.gov (United States)

    Ayeshamariam, A; Ramalingam, S; Bououdina, M; Jayachandran, M

    2014-01-24

    In this work, pure and singe phase SnO2 Nano powder is successfully prepared by simple sol-gel combustion route. The photo luminescence and XRD measurements are made and compared the geometrical parameters with calculated values. The FT-IR and FT-Raman spectra are recorded and the fundamental frequencies are assigned. The optimized parameters and the frequencies are calculated using HF and DFT (LSDA, B3LYP and B3PW91) theory in bulk phase of SnO2 and are compared with its Nano phase. The vibrational frequency pattern in nano phase gets realigned and the frequencies are shifted up to higher region of spectra when compared with bulk phase. The NMR and UV-Visible spectra are simulated and analyzed. Transmittance studies showed that the HOMO-LUMO band gap (Kubo gap) is reduced from 3.47 eV to 3.04 eV while it is heated up to 800°C. The Photoluminescence spectra of SnO2 powder showed a peak shift towards lower energy side with the change of Kubo gap from 3.73 eV to 3.229 eV for as-prepared and heated up to 800°C. Crown Copyright © 2013. Published by Elsevier B.V. All rights reserved.

  14. The spectroscopic (FT-IR, FT-Raman, UV and NMR) first order hyperpolarizability and HOMO-LUMO analysis of dansyl chloride

    Science.gov (United States)

    Karabacak, M.; Cinar, M.; Kurt, M.; Poiyamozhi, A.; Sundaraganesan, N.

    2014-01-01

    The solid phase FT-IR and FT-Raman spectra of dansyl chloride (DC) have been recorded in the regions 400-4000 and 50-4000 cm-1, respectively. The spectra have been interpreted in terms of fundamentals modes, combination and overtone bands. The structure of the molecule has been optimized and the structural characteristics have been determined by density functional theory (B3LYP) method with 6-311++G(d,p) as basis set. The vibrational frequencies were calculated for most stable conformer and were compared with the experimental frequencies, which yield good agreement between observed and calculated frequencies. The infrared and Raman spectra have also been predicted from the calculated intensities. 1H and 13C NMR spectra were recorded and 1H and 13C nuclear magnetic resonance chemical shifts of the molecule were calculated using the gauge independent atomic orbital (GIAO) method. UV-Visible spectrum of the compound was recorded in the region 200-600 nm and the electronic properties HOMO and LUMO energies were measured by time-dependent TD-DFT approach. Nonlinear optical and thermodynamic properties were interpreted. All the calculated results were compared with the available experimental data of the title molecule.

  15. FT-Raman, FT-IR spectra and total energy distribution of 3-pentyl-2,6-diphenylpiperidin-4-one: DFT method.

    Science.gov (United States)

    Subashchandrabose, S; Saleem, H; Erdogdu, Y; Rajarajan, G; Thanikachalam, V

    2011-11-01

    FT-Raman and FT-IR spectra were recorded for 3-pentyl-2,6-diphenylpiperidin-4-one (PDPO) sample in solid state. The equilibrium geometries, harmonic vibrational frequencies, infrared and the Raman scattering intensities were computed using DFT/6-31G(d,p) level. Results obtained at this level of theory were used for a detailed interpretation of the infrared and Raman spectra, based on the total energy distribution (TED) of the normal modes. Molecular parameters such as bond lengths, bond angles and dihedral angles were calculated and compared with X-ray diffraction data. This comparison was good agreement. The intra-molecular charge transfer was calculated by means of natural bond orbital analysis (NBO). Hyperconjugative interaction energy was more during the π-π* transition. Energy gap of the molecule was found using HOMO and LUMO calculation, hence the less band gap, which seems to be more stable. Atomic charges of the carbon, nitrogen and oxygen were calculated using same level of calculation. Copyright © 2011 Elsevier B.V. All rights reserved.

  16. Quantum computational studies, spectroscopic (FT-IR, FT-Raman and UV-Vis) profiling, natural hybrid orbital and molecular docking analysis on 2,4 Dibromoaniline

    Science.gov (United States)

    Abraham, Christina Susan; Prasana, Johanan Christian; Muthu, S.; Rizwana B, Fathima; Raja, M.

    2018-05-01

    The research exploration will comprise of investigating the molecular structure, vibrational assignments, bonding and anti-bonding nature, nonlinear optical, electronic and thermodynamic nature of the molecule. The research is conducted at two levels: First level employs the spectroscopic techniques - FT-IR, FT-Raman and UV-Vis characterizing techniques; at second level the data attained experimentally is analyzed through theoretical methods using and Density Function Theories which involves the basic principle of solving the Schrodinger equation for many body systems. A comparison is drawn between the two levels and discussed. The probability of the title molecule being bio-active theoretically proved by the electrophilicity index leads to further property analyzes of the molecule. The target molecule is found to fit well with Centromere associated protein inhibitor using molecular docking techniques. Higher basis set 6-311++G(d,p) is used to attain results more concurrent to the experimental data. The results of the organic amine 2, 4 Dibromoaniline is analyzed and discussed.

  17. Quantum mechanical, spectroscopic studies (FT-IR, FT-Raman, NMR, UV) and normal coordinates analysis on 3-([2-(diaminomethyleneamino) thiazol-4-yl] methylthio)-N'-sulfamoylpropanimidamide

    Science.gov (United States)

    Muthu, S.; Uma Maheswari, J.; Sundius, Tom

    2013-05-01

    Famotidine (3-([2-(diaminomethyleneamino) thiazol-4-yl] methylthio)-N'-sulfamoylpropanimidamide) is a histamine H2-receptor antagonist that inhibits stomach acid production, and it is commonly used in the treatment of peptic ulcer disease (PUD) and gastroesophageal reflux disease (GERD/GORD). Quantum chemical calculations of the equilibrium geometry of famotidine in the ground state were carried out using density functional theory (DFT/B3LYP) with the 6-311G(d,p) basis set. In addition, harmonic vibrational frequencies, infrared intensities and Raman activities were calculated at the same level of theory. A detailed interpretation of the infrared and Raman spectrum of the drug is also reported. Theoretical simulations of the FT-IR, and FT-Raman spectra of the title compound have been calculated. Good correlations between the experimental 1H and 13C NMR chemical shifts and calculated GIAO shielding tensors were found. The results of the energy and oscillator strength calculations by time-dependent density functional theory (TD-DFT) supplement the experimental findings. Total and partial density of state (TDOS and PDOS) and also overlap population density of state (COOP or OPDOS) diagrams analysis were presented. The dipole moment, linear polarizability and first order hyperpolarizability values were also computed. The linear polarizability and first order hyperpolarizabilities of the studied molecule indicate that the compound is a good candidate for nonlinear optical materials.

  18. Determination of alkaloids in capsules, milk and ethanolic extracts of poppy (Papaver somniferum L.) by ATR-FT-IR and FT-Raman spectroscopy.

    Science.gov (United States)

    Schulz, Hartwig; Baranska, Malgorzata; Quilitzsch, Rolf; Schütze, Wolfgang

    2004-10-01

    Fourier transform (FT) infrared spectroscopy using a diamond composite ATR crystal and NIR-FT-Raman spectroscopy techniques were applied for the simultaneous identification and quantification of the most important alkaloids in poppy capsules. Most of the characteristic Raman signals of the alkaloids can be identified in poppy milk isolated from unripe capsules. But also poppy extracts present specific bands relating clearly to the alkaloid fraction. Raman spectra obtained by excitation with a Nd:YAG laser at 1064 nm show no disturbing fluorescence effects; therefore the plant tissue can be recorded without any special preparation. The used diamond ATR technique allows to measure very small sample amounts (5-10 microL or 2-5 mg) without the necessity to perform time-consuming pre-treatments. When applying cluster analysis a reliable discrimination of "low-alkaloid" and "high-alkaloid" poppy single-plants can be easily achieved. The examples presented in this study provide clear evidence of the benefits of Raman and ATR-IR spectroscopy in efficient quality control, forensic analysis and high-throughput evaluation of poppy breeding material.

  19. Collaborative Student Laboratory Exercise Using FT-IR Spectroscopy for the Kinetics Study of a Biotin Analogue

    Science.gov (United States)

    Leong, Jhaque; Ackroyd, Nathan C.; Ho, Karen

    2014-01-01

    The synthesis of N-methoxycarbonyl-2-imidazolidone, an analogue of biotin, was conducted by organic chemistry students and confirmed using FT-IR and H NMR. Spectroscopy students used FT-IR to measure the rate of hydrolysis of the product and determined the rate constant for the reaction using the integrated rate law. From the magnitude of the rate…

  20. Hubungan Kadar FT4 dengan Gejala Klinis yang Terkait Efek Simpatis berdasarkan Indek Wayne pada Nagari Koto Salak Kabupaten Dharmasraya

    Directory of Open Access Journals (Sweden)

    Nining Kurniawati

    2015-05-01

    Full Text Available AbstrakPeningkatan aktivitas saraf simpatis dapat terjadi pada keadaan hipertiroid dan sebaliknya pada hipotiroid. Pengukuran kadar hormon tiroid dilakukan dengan mengukur kadar FT4, FT3, TSH, dll. Tujuan penelitian ini adalah untuk mengidentifikasi hubungan kadar FT4 dengan gejala klinis yang terkait efek simpatis di Nagari Koto Salak Kabupaten Dharmasraya. Penelitian ini menggunakan desain penelitian cross sectional study. Hasil penelitian didapatkan subjek dengan peningkatan kadar FT4 12,96%. Subjek dengan gejala klinis palpitasi, penurunan berat badan, nervous, berkeringat lebih dan tremor jari halus dengan persentase berturut-turut adalah 42,59%, 38,89%, 46,30%, 25,93% dan 44,44%. Analisis bivariat dengan menggunakan uji statistik chi-square diperoleh hasil tidak ada hubungan hubungan kadar FT4 dengan 5 gejala klinis yang terkait efek simpatis berdasarkan indeks Wayne (p > 0.05. Penelitian ini masih sederhana dan belum bisa menunjukkan adanya hubungan antara kadar FT4 dengan gejala klinis yang terkait efek simpatis. Sebaiknya untuk penelitian yang akan datang diharapkan dapat memiliki jumlah sampel yang banyak dan cakupan gejala klinis lain yang terlibat dalam aktivitas saraf simpatis yang lebih luas sehingga dapat lebih lengkap dan spesifik.Kata kunci: Kadar FT4, efek simpatis, gejala klinis AbstractIncreased sympathetic nerve activity may occur in the state of hyperthyroidism and conversely in hypothyroidism. Measurement of thyroid hormone levels is done by measuring the levels of FT4, FT3, TSH, etc. The objective of this study was to identify the relation between FT4 levels and the clinical symptoms of sympathetic effects in Nagari Koto Salak Kabupaten Dharmasraya. This research used cross sectional study design. According to the research found that subjects with elevated levels of FT4 12.96%. There are subjects with clinical symptoms of palpitations, weight loss, nervousness, sweating more and fine finger tremor by the following

  1. The effect of heparin administration on the FT4-levels and on an unspecific peripheral thyroid parameter

    International Nuclear Information System (INIS)

    Eber, B.; Borkenstein, J.; Leb, G.

    1984-01-01

    Heparin produces changes in FT 4 -levels both in vivo and in vitro as determined by commercial kits. Methods utilising the principle of equilibrium dialysis show significant increases whereas methods using T 4 -tracer analogue techniques reveal marked decreases in FT 4 -values. Possible clinical side-effects of heparin administration such as heparin-induced hyperthyroidism and tachyarrhythmias are discussed. The present results confirm the FT 4 -decreasing effect of in vivo and in vitro administration of heparin with FT 4 -RIAs based on the tracer analogue technique; however, the unspecific peripheral thyroid parameter of systolic time-intervals did not reveal any tendency towards hyperthyroidism. Also the discrepant results dependent on the method used, indicate that, following heparin administration FT 4 -levels do not reflect that hormone concentration is relevant to the metabolism of the whole body. (orig.) [de

  2. Signal-to-noise ratio of FT-IR CO gas spectra

    DEFF Research Database (Denmark)

    Bak, J.; Clausen, Sønnik

    1999-01-01

    in emission and transmission spectrometry, an investigation of the SNR in CO gas spectra as a function of spectral resolution has been carried out. We present a method to (1) determine experimentally the SNR at constant throughput, (2) determine the SNR on the basis of measured noise levels and Hitran......The minimum amount of a gaseous compound which can be detected and quantified with Fourier transform infrared (FT-IR) spectrometers depends on the signal-to-noise ratio (SNR) of the measured gas spectra. In order to use low-resolution FT-IR spectrometers to measure combustion gases like CO and CO2...... simulated signals, and (3) determine the SNR of CO from high to low spectral resolutions related to the molecular linewidth and vibrational-rotational lines spacing. In addition, SNR values representing different spectral resolutions but scaled to equal measurement times were compared. It was found...

  3. Analysis of Polyadipate Ester Content in PVC Plastics by Means of FT-Raman Spectroscopy

    DEFF Research Database (Denmark)

    Berg, Rolf W.

    2006-01-01

    Plasticizers are needed in flexible PVC (PolyVinylChloride) products. There is serious concern that commonly used phthalate esters may harm life reproduction systems. To avoid the problems, instead adipate di-esters (AEs) of C8 to C10 alcohols are used as higher prized alternatives; e.g. di-2......-ethylhexyl adipate or DEHA [103-23-1], also known as Adimoll or di-octyl adipate, DOA. A widely used plasticizer in food (cling) films is DEHA, often in combination with polymers, epoxidized soya-bean oil, etcetera. DEHA also occurs in children toys. We have previously shown that the presence of phthalate...... esters in PVC can be rapidly analyzed by Fourier transform (FT-) Raman spectroscopy excited with a 1064 nm laser. Here in this project we report a similar study. The aim was to find out whether FT-Raman spectroscopy can be used to determine the presence of adipate esters (AEs) as plasticizers...

  4. Aplicação de FT-MIR e FT-NIR ao estudo de reação de cura de sistemas epoxídicos FT-IR MIR and FT-NIR applied to the study of reaction of epoxy systems

    Directory of Open Access Journals (Sweden)

    Benedita M. V. Romão

    2004-09-01

    Full Text Available A reação de cura entre amostras de resina epoxídica (EP e compostos à base de mercaptana (SH, amino-fenol e amina modificada foi estudada nas regiões espectrais do infravermelho médio (MIR e próximo (NIR. Observou-se, basicamente, que a espectroscopia FT-NIR evidencia melhor as alterações espectrométricas ocorridas durante as reações estudadas, permitindo detectar, inclusive, o agente de cura em menor proporção no sistema epoxídico.The cure reaction of epoxy resin (EP and curing agents based on polymercaptans (SH, amine-phenol and modified amine was studied in the MIR and NIR spectral regions. It was observed that the FT-NIR shows better the spectrometric changes of the reactions studied, which makes it possible to detect the curing agent in lower contents in epoxide systems.

  5. Prediction of the lifetime of nitrile-butadiene rubber by FT-IR.

    Science.gov (United States)

    Kawashima, Tetsuya; Ogawa, Toshio

    2005-12-01

    A quantitative measurement method with FT-IR was proposed for a thermal degradation analysis of nitrile-butadiene rubber (NBR). An NBR film was prepared as a model sample on a barium fluoride (BaF2) crystal plate, which was subjected to a heat treatment. The absorbances of various functional groups were measured directly by FT-IR after thermal degradation at high temperatures. By measuring the absorbances, it was possible to readily determine quantitatively each of the functional groups after the degradation of NBR. By assuming that the NBR lifetime was the point at which the absorbance of a carbon-carbon double bond reaches 45% of that prior to thermal treatment, a method for predicting the lifetime of NBR heated below 150 degrees C was proposed, by using an Arrhenius plot of the heating time versus heating temperature.

  6. Detection of creatinine enriched on a surface imprinted polystyrene film using FT-ATR-IR.

    Science.gov (United States)

    Sreenivasan, K

    2006-01-01

    The surface of polystyrene (PS) was chemically modified by coating a thin layer of polyaniline (PANI) by oxidizing aniline using ammonium persulfate. Affinity sites for creatinine, a clinically relevant molecule, were created in the coated layer by adding creatinine as print molecules during the oxidation. The imprinted layer adsorbed creatinine was compared to non-imprinted surface reflecting the creation of creatinine-specific sites on the surface. The equilibrium was attained rapidly, indicating that a material of this kind is suitable for sensing applications. The adsorbed creatinine on the surface was detected using the technique of Fourier transform attenuated total internal reflection infra red spectroscopy (FT-ATR-IR). The results show that molecularly imprinted surface can enrich molecules of interest and the enriched molecules can be detected using FT-IR.

  7. Application of FT-IR Classification Method in Silica-Plant Extracts Composites Quality Testing

    Science.gov (United States)

    Bicu, A.; Drumea, V.; Mihaiescu, D. E.; Purcareanu, B.; Florea, M. A.; Trică, B.; Vasilievici, G.; Draga, S.; Buse, E.; Olariu, L.

    2018-06-01

    Our present work is concerned with the validation and quality testing efforts of mesoporous silica - plant extracts composites, in order to sustain the standardization process of plant-based pharmaceutical products. The synthesis of the silica support were performed by using a TEOS based synthetic route and CTAB as a template, at room temperature and normal pressure. The silica support was analyzed by advanced characterization methods (SEM, TEM, BET, DLS and FT-IR), and loaded with Calendula officinalis and Salvia officinalis standardized extracts. Further desorption studies were performed in order to prove the sustained release properties of the final materials. Intermediate and final product identification was performed by a FT-IR classification method, using the MID-range of the IR spectra, and statistical representative samples from repetitive synthetic stages. The obtained results recommend this analytical method as a fast and cost effective alternative to the classic identification methods.

  8. Dielectric and FT-Raman spectroscopic approach to molecular identification of breast tumor tissues.

    Science.gov (United States)

    Abd El-Hakam, Rasha; Khalil, Safaa; Mahani, Ragab

    2015-01-01

    FT-Raman spectra and dielectric properties of benign and malignant women breast tissues in vitro were investigated. FT-Raman spectra for the malignant tissues showed a remarkably decrease in the lipid/protein ratio. Dielectric properties of women breast tissues measured in the low frequency range (42-10(6)Hz) were interpreted in spite of electrode polarization effect. Experimental results showed a contrast between the dielectric properties of malignant (Grade II) and benign tissues within the frequency range studied. The permittivity of malignant to normal breast tissue was found to be 160:1 while it could be 1.3:1 for fibrocystic breast tissues. These findings could contribute to distinguish between two breast tissues. The differences in spectral features between benign and malignant tissues may lead to breast cancer detection. Copyright © 2015 Elsevier B.V. All rights reserved.

  9. FINAL DESIGN REVIEW REPORT Subcritical Experiments Gen 2, 3-ft Confinement Vessel Weldment

    Energy Technology Data Exchange (ETDEWEB)

    Romero, Christopher [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2017-09-28

    A Final Design Review (FDR) of the Subcritical Experiments (SCE) Gen 2, 3-ft. Confinement Vessel Weldment was held at Los Alamos National Laboratory (LANL) on September 14, 2017. The review was a focused review on changes only to the confinement vessel weldment (versus a system design review). The changes resulted from lessons-learned in fabricating and inspecting the current set of confinement vessels used for the SCE Program. The baseline 3-ft. confinement vessel weldment design has successfully been used (to date) for three (3) high explosive (HE) over-tests, two (2) fragment tests, and five (5) integral HE experiments. The design team applied lessons learned from fabrication and inspection of these vessel weldments to enhance fit-up, weldability, inspection, and fitness for service evaluations. The review team consisted of five (5) independent subject matter experts with engineering design, analysis, testing, fabrication, and inspection experience. The

  10. Study of the Pyrrol/Diphenylamine Copolymer by FT-IR spectroscopy and conductivity

    Directory of Open Access Journals (Sweden)

    Carlos Alberto Perez

    2004-01-01

    Full Text Available The main goal of this study was to analyze the physical properties of the copolymer formed by the electrochemical deposition of the polydiphenylamine (PDPA on polypyrrole (Ppy and Ppy on PDPA, in different conditions, through the characterization of the materials formed by the resonant Raman, FT-IR and conductivity techniques. The interactions among the species which are present in the new copolymer structure and the changes in electronic conductivity, were verified. The copolymer was also synthesized electrochemically in the presence of iodide species and the material was characterized by FT-IR spectroscopy and conductivity. The role of the dopant was studied in the process of charge transfer between the copolymer-dopant, acting in the stabilization of the species in the polymer backbone and the increase of the electronic conductivity.

  11. Preliminary study of corrosion mechanisms of actinides alloys: calibration of FT-IR spectroscopy

    International Nuclear Information System (INIS)

    Magnien, Veronique; Cadignan, Marx; Faivret, Olivier; Rosa, Gaelle

    2008-01-01

    In situ analyzes of gaseous atmospheres could be performed by FT-IR spectroscopy in order to study the corrosion reactions of actinides. Nevertheless experimental conditions and the nature of studied species have a strong effect on IR absorption laws. Thus a prior calibration of our set-up is required to obtain an accurate estimation of gas concentration. For this purpose, the behavior of several air pure gases has been investigated according to their concentration from IR spectra. Reproducible results revealed subsequent increases of the most significant peak areas with gas pressure and small deviations from Beer Lambert's law. This preliminary work allowed to determine precise absorption laws for each studied pure gas in our in situ experimental conditions. Besides our FT-IR set-up was well suitable to quantitative analysis of gaseous atmosphere during corrosion reactions. Finally the effect of foreign gas will be investigated through more complex air mixtures to obtain a complete calibration network. (authors)

  12. Determination of the Mechanical Properties of Rubber by FT-NIR

    OpenAIRE

    Pornprasit, Rattapol; Pornprasit, Philaiwan; Boonma, Pruet; Natwichai, Juggapong

    2016-01-01

    Mechanical tests, for example, tensile and hardness tests, are usually used to evaluate the properties of rubber materials. In this work, mechanical properties of selected rubber materials, that is, natural rubber (NR), styrene butadiene rubber (SBR), nitrile butadiene rubber (NBR), and ethylene propylene diene monomer (EPDM), were evaluated using a near infrared (NIR) spectroscopy technique. Here, NR/NBR and NR/EPDM blends were first prepared. All of the samples were then scanned using a FT-...

  13. Unlocking Ft: Modeling thermodynamic controls and isotope fractionation factors in nutrient limited environments

    Science.gov (United States)

    Druhan, J. L.; Giannetta, M.; Sanford, R. A.

    2017-12-01

    In recent years, reactive transport principles have expanded from early applications, largely based in contaminant hydrology, to a wide range of biologically mediated redox environments including marine sedimentary diagenesis, terrestrial metal ore deposits, soils, and critical zone weathering profiles. A common observation across this diversity of systems is that they often function under energetically limited conditions in comparison to those typical of contaminated aquifers subject to engineered remediation techniques. As a result, the kinetic rate expressions traditionally employed within reactive transport frameworks to simulate microbially mediated redox transformations have required modification. This was recognized in a series of seminal papers by Jin and Bethke (2005, 2007) in which the authors expanded upon a Monod rate law to include a thermodynamic potential factor `Ft' which exerts a limitation on the overall rate based on the thermodynamic driving force of the electron transfer reaction. This new rate expression is now commonly implemented within many of the major reactive transport software packages, though appropriate application has yet to be thoroughly demonstrated. Notably, the characteristically large partitioning of stable isotopes during microbially mediated reactions, which is extensively utilized to identify and quantify these redox transformations, has yet to be simulated under conditions in which the Ft term may be expected to exert a significant mass dependent influence. Here, we develop a series of simplified simulations for the microbially mediated reduction of sulfate based on the datasets reported by Jin and Bethke, and apply appropriate mass-bias within the Ft term to consider the extent to which the resulting isotopic fractionation is consistent with that observed in energetically limited systems. We show that the Ft term can exert a significant influence on the observed fractionation factor under common environmental conditions

  14. S. Afr. J, Anim. Sci 4, 55-60(1974) EVIDENCE FOR A FT ...

    African Journals Online (AJOL)

    Sci 4, 55-60(1974). EVIDENCE FOR A FT,JNCTIONAL ROLE OF THE PINEAL IN BOVINES. M.lf{.M. llryes, B.K. Knight and R.B. Symington. RreiptofnSr.e.T3. Deprtment of Amtomy, Univasity of Rhodesh, &lisbury, Rhodesia. ONOIIIMING;. BEWYSE VIR 'N .FI,,NKSIONELE ROL VAN DIE EPIFISE TN DIE BEES. Dat die epifisc ...

  15. Can f(T) gravity theories mimic ΛCDM cosmic history

    Energy Technology Data Exchange (ETDEWEB)

    Setare, M.R.; Mohammadipour, N., E-mail: rezakord@ipm.ir, E-mail: N.Mohammadipour@uok.ac.ir [Department of Science, University of Kurdistan, Sanandaj (Iran, Islamic Republic of)

    2013-01-01

    Recently the teleparallel Lagrangian density described by the torsion scalar T has been extended to a function of T. The f(T) modified teleparallel gravity has been proposed as the natural gravitational alternative for dark energy to explain the late time acceleration of the universe. In order to reconstruct the function f(T) by demanding a background ΛCDM cosmology we assume that, (i) the background cosmic history provided by the flat ΛCDM (the radiation ere with ω{sub eff} = (1/3), matter and de Sitter eras with ω{sub eff} = 0 and ω{sub eff} = −1, respectively) (ii) the radiation dominate in the radiation era with Ω{sub 0r} = 1 and the matter dominate during the matter phases when Ω{sub 0m} = 1. We find the cosmological dynamical system which can obey the ΛCDM cosmic history. In each era, we find a critical lines that, the radiation dominated and the matter dominated are one points of them in the radiation and matter phases, respectively. Also, we drive the cosmologically viability condition for these models. We investigate the stability condition with respect to the homogeneous scalar perturbations in each era and we obtain the stability conditions for the fixed points in each eras. Finally, we reconstruct the function f(T) which mimics cosmic expansion history.

  16. Molecular orientation in aligned electrospun polyimide nanofibers by polarized FT-IR spectroscopy.

    Science.gov (United States)

    Yang, Haoqi; Jiang, Shaohua; Fang, Hong; Hu, Xiaowu; Duan, Gaigai; Hou, Haoqing

    2018-07-05

    Quantitative explanation on the improved mechanical properties of aligned electrospun polyimide (PI) nanofibers as the increased imidization temperatures is highly required. In this work, polarized FT-IR spectroscopy is applied to solve this problem. Based on the polarized FT-IR spectroscopy and the molecular model in the fibers, the length of the repeat unit of PI molecule, the angle between the fiber axis and the symmetric stretching direction of carbonyl group on the imide ring, and the angle between the PI molecular axis and fiber axis are all investigated. The Mark-Howink equation is used to calculate the number-average molar mass of PI molecules. The orientation states of PI molecules in the electrospun nanofibers are studied from the number-average molar mass of PI molecules and the average fiber diameter. Quantitative analysis of the orientation factor of PI molecules in the electrospun nanofibers is performed by polarized FT-IR spectroscopy. Copyright © 2018 Elsevier B.V. All rights reserved.

  17. Concepts for the assay of unbound thyroxine (FT4) and thyroxine binding globulin (TBG)

    International Nuclear Information System (INIS)

    Odstrchel, G.; Hertl, W.; Ward, F.B.; Travis, K.; Lindner, R.E.; Mason, R.D.

    1977-01-01

    Two new concepts for the assay of thyroid related substances are presented. One assay (FT 4 ) is based on a kinetic measurement of T 4 as it desorbs from binder proteins onto solid-phase T 4 antibody. This reaction can be described by a second order rate equation; r = k (IMA) (FT 4 ). The assay is rapid (2 hours) and gives good agreement (sigma = 0.92) with equilibrium dialysis and a normal range of 0.9 - 2.3 ng/dl. This assay uses a small sample size (25 μl) and is unaffected by drugs such as aspirin and dilantin. Pregnant and estrogen treated women gave normal FT 4 values. A new method for the measurement of functionally active TEG is also presented. In this case the labeled T 4 is partitioned between bovine serum albumin and the patient's samples. The complex is then removed from solution by solid-phase anti-TBG. A curve remiscent of an immunoradiometric assay is obtained. The assay has a sensitivity of 4 μg/ml and is unaffected by aspirin, dilantin or the patient's T 4 concentrations. Correlation with 'rocket' electrophoresis is 0.90. The normal range was 20 +- 7 μg/ml with pregnant women giving values greater than 30 μg/ml. Five hereditary deficient patients gave a value equivalent to zero TBG concentration. (orig.) [de

  18. Hand dryer noise in public restrooms exceeds 80 dBA at 10 ft (3 m

    Directory of Open Access Journals (Sweden)

    Shari Salzhauer Berkowitz

    2015-01-01

    Full Text Available High airflow hand dryers are found in many public restrooms today. These dryers offer quick and clean hand drying, and are seen as being an environment-friendly alternative to paper towels. However, many new hand dryers are loud, exposing individuals using the facilities as well as those employees who clean the facilities to potentially dangerous noise. Prolonged exposure to high levels of occupational noise can cause damage to hair cells in the cochlea, resulting in varying degrees of noise-induced hearing loss. This study examined the intensity (in dBA of the noise produced by the air dryers in campus restrooms. Hand dryer peak and average noise was measured with a sound level meter at 2.5 ft, 5 ft, and 10 ft from the dryer. Noise measurements did not decrease as predicted by the inverse-square law, probably because of the reverberative surfaces found in the restrooms. The small sample of hand dryers tested was mostly found to be producing more noise than the manufacturer claimed they would; indeed, none of the dryers would be safe for an 8-h workday exposure. While hand dryers do reduce paper trash, they pose as a different sort of hazard to our environment and population.

  19. High performance gamma-ray spectrometer for runaway electron studies on the FT-2 tokamak

    Energy Technology Data Exchange (ETDEWEB)

    Shevelev, A.E., E-mail: Shevelev@cycla.ioffe.ru [Ioffe Institute, Politekhnicheskaya 26, St. Petersburg 194021 (Russian Federation); Khilkevitch, E.M.; Lashkul, S.I.; Rozhdestvensky, V.V.; Altukhov, A.B.; Chugunov, I.N.; Doinikov, D.N.; Esipov, L.A.; Gin, D.B.; Iliasova, M.V.; Naidenov, V.O.; Nersesyan, N.S.; Polunovsky, I.A.; Sidorov, A.V. [Ioffe Institute, Politekhnicheskaya 26, St. Petersburg 194021 (Russian Federation); Kiptily, V.G. [CCFE, Culham Science Centre, Abingdon, Oxon X14 3DB (United Kingdom)

    2016-09-11

    A gamma-ray spectrometer based on LaBr{sub 3}(Ce) scintillator has been used for measurements of hard X-ray emission generated by runaway electrons in the FT-2 tokamak plasmas. Using of the fast LaBr{sub 3}(Ce) has allowed extending count rate range of the spectrometer by a factor of 10. A developed digital processing algorithm of the detector signal recorded with a digitizer sampling rate of 250 MHz has provided a pulse height analysis at count rates up to 10{sup 7} s{sup −1}. A spectrum deconvolution code DeGaSum has been applied for inferring the energy distribution of runaway electrons escaping from the plasma and interacting with materials of the FT-2 limiter in the vacuum chamber. The developed digital signal processing technique for LaBr{sub 3}(Ce) spectrometer has allowed studying the evolution of runaways energy distribution in the FT-2 plasma discharges with time resolution of 1–5 ms.

  20. Monitoring wine aging with Fourier transform infrared spectroscopy (FT-IR

    Directory of Open Access Journals (Sweden)

    Basalekou Marianthi

    2015-01-01

    Full Text Available Oak wood has commonly been used in wine aging but recently other wood types such as Acacia and Chestnut, have attracted the interest of the researchers due to their possible positive contribution to wine quality. However, only the use of oak and chestnut woods is approved by the International Enological Codex of the International Organisation of Vine and Wine. In this study Fourier Transform (FT-mid-infrared spectroscopy combined with Discriminant Analysis was used to differentiate wines aged in barrels made from French oak, American oak, Acacia and Chestnut and in tanks with oak chips, over a period of 12 months. Two red (Mandilaria, Kotsifali and two white (Vilana, Dafni native Greek grape varieties where used to produce four wines. The Fourier Transform Infrared (FT-IR spectra of the samples were recorded on a Zinc Selenide (ZnSe window after incubation at 40 °C for 30 min. A complete differentiation of the samples according to both the type of wood used and the contact time was achieved based on their FT-IR spectra.

  1. New observational constraints on f(T) cosmology from radio quasars

    Energy Technology Data Exchange (ETDEWEB)

    Qi, Jing-Zhao; Cao, Shuo; Zhu, Zong-Hong [Beijing Normal University, Department of Astronomy, Beijing (China); Biesiada, Marek; Zheng, Xiaogang [Beijing Normal University, Department of Astronomy, Beijing (China); University of Silesia, Department of Astrophysics and Cosmology, Institute of Physics, Katowice (Poland)

    2017-08-15

    Using a new recently compiled milliarcsecond compact radio data set of 120 intermediate-luminosity quasars in the redshift range 0.46 < z < 2.76, whose statistical linear sizes show negligible dependence on redshifts and intrinsic luminosity and thus represent standard rulers in cosmology, we constrain three viable and most popular f(T) gravity models, where T is the torsion scalar in teleparallel gravity. Our analysis reveals that constraining power of the quasars data (N = 120) is comparable to the Union2.1 SN Ia data (N = 580) for all three f(T) models. Together with other standard ruler probes such as cosmic microwave background and baryon acoustic oscillation distance measurements, the present value of the matter density parameter Ω{sub m} obtained by quasars is much larger than that derived from other observations. For one of the models considered (f{sub 1}CDM) a small but noticeable deviation from ΛCDM cosmology is present, while in the framework of f{sub 3}CDM the effective equation of state may cross the phantom divide line at lower redshifts. These results indicate that intermediate-luminosity quasars could provide an effective observational probe comparable to SN Ia at much higher redshifts, and f(T) gravity is a reasonable candidate for the modified gravity theory. (orig.)

  2. FY17 Accomplishments - Testing Facilities and Capabilities at SWiFT, SNL

    Energy Technology Data Exchange (ETDEWEB)

    Berg, Jonathan Charles [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2017-10-01

    The Scaled Wind Farm Technologies (SWiFT) facility operated by Sandia National Laboratories (SNL) has, in support of the Atmosphere to electrons (A2e) research program, acquired measurements of wind turbine wake dynamics under various atmospheric conditions and while interacting with a downstream wind turbine. SNL researchers, in collaboration with National Renewable Energy Laboratory (NREL) researchers, installed a customized LIDAR system created by the Technical University of Denmark (DTU) in one of the SWiFT wind turbines (Figure 1) and operated that turbine with intentional yaw-versus-winddirection misalignment to study the behavior of the turbine wake under numerous combinations of atmospheric conditions and turbine yaw offsets. The DTU-customized LIDAR provided detailed measurements of the wake’s shape and location at many distances downwind of the turbine (Figure 2). These measurements will benefit wind energy researchers looking to understand wind turbine wake behavior and improve modeling and simulation of wake dynamics, including the “wake steering” affect that is observed when turbine yaw offset is controlled. During the test campaign, two SWiFT wind turbines were operated at the same time to observe the influence of the turbines on each other as the wake of the upwind turbine was observed sweeping over and interacting with the downwind turbine.

  3. Characterization of prepared In2O3 thin films: The FT-IR, FT-Raman, UV-Visible investigation and optical analysis.

    Science.gov (United States)

    Panneerdoss, I Joseph; Jeyakumar, S Johnson; Ramalingam, S; Jothibas, M

    2015-08-05

    In this original work, the Indium oxide (In2O3) thin film is deposited cleanly on microscope glass substrate at different temperatures by spray pyrolysis technique. The physical properties of the films are characterized by XRD, SEM, AFM and AFM measurements. The spectroscopic investigation has been carried out on the results of FT-IR, FT-Raman and UV-Visible. XRD analysis exposed that the structural transformation of films from stoichiometric to non-stoichiometric orientation of the plane vice versa and also found that, the film is polycrystalline in nature having cubic crystal structure with a preferred grain orientation along (222) plane. SEM and AFM studies revealed that, the film with 0.1M at 500°C has spherical grains with uniform dimension. The complete vibrational analysis has been carried out and the optimized parameters are calculated using HF and DFT (CAM-B3LYP, B3LYP and B3PW91) methods with 3-21G(d,p) basis set. Furthermore, NMR chemical shifts are calculated by using the gauge independent atomic orbital (GIAO) technique. The molecular electronic properties; absorption wavelengths, excitation energy, dipole moment and frontier molecular orbital energies, molecular electrostatic potential energy (MEP) analysis and Polarizability first order hyperpolarizability calculations are performed by time dependent DFT (TD-DFT) approach. The energy excitation on electronic structure is investigated and the assignment of the absorption bands in the electronic spectra of steady compound is discussed. The calculated HOMO and LUMO energies showed the enhancement of energy gap by the addition of substitutions with the base molecule. The thermodynamic properties (heat capacity, entropy, and enthalpy) at different temperatures are calculated and interpreted in gas phase. Crown Copyright © 2015. Published by Elsevier B.V. All rights reserved.

  4. FT-IR, FT-Raman, NMR studies and ab initio-HF, DFT-B3LYP vibrational analysis of 4-chloro-2-fluoroaniline.

    Science.gov (United States)

    Arivazhagan, M; Anitha Rexalin, D

    2012-10-01

    The Fourier transform infrared (FT-IR) and Fourier transform Raman (FT-Raman) spectra of 4-chloro-2-fluoroaniline (CFA) have been recorded and analyzed. The equilibrium geometry, bonding features and harmonic vibrational frequencies have been investigated with the help of ab initio and density functional theory (DFT) methods. The assignments of the vibrational spectra have been carried out with the help of normal coordinate analysis (NCA) following the scaled quantum mechanical force field methodology. The (1)H and (13)C nuclear magnetic resonance (NMR) chemical shifts of the molecule are calculated by the Gauge including atomic orbital (GIAO) method. The first order hyperpolarizability (β(0)) of this novel molecular system and related properties (β, α(0) and Δα) of CFA are calculated using B3LYP/6-311++G(d,p) and HF/6-311++G(d,p) methods on the finite-field approach. The calculated results also show that the CFA molecule might have microscopic nonlinear optical (NLO) behavior with non-zero values. Stability of the molecule arising from hyper conjugative interactions, charge delocalization has been analyzed using natural bond orbital (NBO) analysis. The result confirms the occurrence of intramolecular charge transfer (ICT) within the molecule. The HOMO-LUMO energies UV-vis spectral analysis and MEP are performed by B3LYP/6-311++G(d,p) approach. A detailed interpretation of the infrared and Raman spectra of CFA is also reported based on total energy distribution (TED). The difference between the observed and scaled wave number values of the most of the fundamentals is very small. Copyright © 2012 Elsevier B.V. All rights reserved.

  5. Spectroscopic [FT-IR and FT-Raman] and molecular modeling (MM) study of benzene sulfonamide molecule using quantum chemical calculations

    Science.gov (United States)

    Vinod, K. S.; Periandy, S.; Govindarajan, M.

    2016-07-01

    The spectroscopic and molecular modeling (MM) study includes, FT-IR, FT-Raman and 13C NMR and 1H NMR spectra of the Benzene sulfonamide were recorded for the analysis. The observed experimental and theoretical frequencies (IR and Raman) were assigned according to their distinctive region. The present study of this title molecule have been carried out by hybrid computational calculations of HF and DFT (B3LYP) methods with 6-311+G(d,p) and 6-311++G(d,p) basis sets and the corresponding results are tabulated. The structural modifications of the compound due to the substitutions of NH2 and SO2 were investigated. The minimum energy conformers of the compound were studied using conformational analysis. The alternations of the vibrational pattern of the base structure related to the substitutions were analyzed. The thermodynamic parameters (such as zero-point vibrational energy, thermal energy, specific heat capacity, rotational constants, entropy, and dipole moment) of Benzene sulfonamide have been calculated. The donor acceptor interactions of the compound and the corresponding UV transitions are found out using NBO analysis. The NMR spectra were simulated by using the gauge independent atomic orbital (GIAO) method with B3LYP methods and the 6-311++G(d,p) basis set and their spectra were simulated and the chemical shifts related to TMS were compared. A quantum computational study on the electronic and optical properties absorption wavelengths, excitation energy, dipole moment and frontier molecular orbital energies, were performed by HF and DFT methods. The energy gap of the present compound was calculated related to HOMO and LUMO energies which confirm the occurring of charge transformation between the base and ligand group. Besides frontier molecular orbitals (FMO), molecular electrostatic potential (MEP) was performed. The thermodynamic properties (heat capacity, entropy, and enthalpy) of the title compound at different temperatures were calculated in gas phase and

  6. The spectroscopic (FT-IR, FT-Raman, dispersive Raman and NMR) study of ethyl-6-chloronicotinate molecule by combined density functional theory.

    Science.gov (United States)

    Karabacak, Mehmet; Calisir, Zuhre; Kurt, Mustafa; Kose, Etem; Atac, Ahmet

    2016-01-15

    In this study, ethyl-6-chloronicotinate (E-6-ClN) molecule is recorded in the region 4000-400 cm(-1) and 3500-100 cm(-1) (FT-IR, FT-Raman and dispersive Raman, respectively) in the solid phase. ((1))H and ((13))C nuclear magnetic resonance (NMR) spectra are recorded in DMSO solution. The structural and spectroscopic data of the molecule are obtained for two possible isomers (S1 and S2) from DFT (B3LYP) with 6-311++G(d,p) basis set calculations. The geometry of the molecule is fully optimized, vibrational spectra are calculated and fundamental vibrations are assigned on the basis of the potential energy distribution (PED) of the vibrational modes. ((1))H and ((13))C NMR chemical shifts are calculated by using the gauge-invariant atomic orbital (GIAO) method. The electronic properties, such as excitation energies, oscillator strengths, wavelengths, HOMO and LUMO energies, are performed by time-dependent density functional theory (TD-DFT). Total and partial density of state and overlap population density of state diagrams analysis are presented for E-6-ClN molecule. Furthermore, frontier molecular orbitals (FMO), molecular electrostatic potential, and thermodynamic features are performed. In addition to these, reduced density gradient of the molecule is performed and discussed. As a conclusion, the calculated results are compared with the experimental spectra of the title compound. The results of the calculations are applied to simulate the vibrational spectra of the molecule, which show excellent agreement with the observed ones. The theoretical and tentative results will give us a detailed description of the structural and physicochemical properties of the molecule. Natural bond orbital analysis is done to have more information stability of the molecule arising from charge delocalization, and to reveal the information regarding charge transfer within the molecules. Copyright © 2015 Elsevier B.V. All rights reserved.

  7. FT-IR, FT-Raman, UV-visible, and NMR spectroscopy and vibrational properties of the labdane-type diterpene 13-epi-sclareol.

    Science.gov (United States)

    Chain, Fernando E; Leyton, Patricio; Paipa, Carolina; Fortuna, Mario; Brandán, Silvia A

    2015-03-05

    In this work, FT-IR, FT-Raman, UV-Visible and NMR spectroscopies and density functional theory (DFT) calculations were employed to study the structural and vibrational properties of the labdane-type diterpene 13-epi-sclareol using the hybrid B3LYP method together with the 6-31G(∗) basis set. Three stable structures with minimum energy found on the potential energy curves (PES) were optimized, and the corresponding molecular electrostatic potentials, atomic charges, bond orders, stabilization energies and topological properties were computed at the same approximation level. The complete assignment of the bands observed in the vibrational spectrum of 13-epi-sclareol was performed taking into account the internal symmetry coordinates for the three structures using the scaled quantum mechanical force field (SQMFF) methodology at the same level of theory. In addition, the force constants were calculated and compared with those reported in the literature for similar compounds. The predicted vibrational spectrum and the calculated (1)H NMR and (13)C NMR chemical shifts are in good agreement with the corresponding experimental results. The theoretical UV-Vis spectra for the most stable structure of 13-epi-sclareol demonstrate a better correlation with the corresponding experimental spectrum. The study of the three conformers by means of the theory of atoms in molecules (AIM) revealed different H bond interactions and a strong dependence of the interactions on the distance between the involved atoms. Furthermore, the natural bond orbital (NBO) calculations showed the characteristics of the electronic delocalization for the two six-membered rings with chair conformations. Copyright © 2014 Elsevier B.V. All rights reserved.

  8. Spectroscopic [FT-IR and FT-Raman] and theoretical [UV-Visible and NMR] analysis on α-Methylstyrene by DFT calculations.

    Science.gov (United States)

    Karthikeyan, N; Joseph Prince, J; Ramalingam, S; Periandy, S

    2015-05-15

    In the present research work, the FT-IR, FT-Raman and (13)C and (1)H NMR spectra of the α-Methylstyrene were recorded. The observed fundamental frequencies in finger print as well as functional group regions were assigned according to their uniqueness region. The Gaussian computational calculations are carried out by HF and DFT (B3LYP and B3PW91) methods with 6-31++G(d,p) and 6-311++G(d,p) basis sets and the corresponding results were tabulated. The impact of the presence of vinyl group in phenyl structure of the compound is investigated. The modified vibrational pattern of the molecule associated vinyl group was analyzed. Moreover, (13)C NMR and (1)H NMR were calculated by using the gauge independent atomic orbital (GIAO) method with B3LYP methods and the 6-311++G(d,p) basis set and their spectra were simulated and the chemical shifts linked to TMS were compared. A study on the electronic and optical properties; absorption wavelengths, excitation energy, dipole moment and frontier molecular orbital energies were carried out. The kubo gap of the present compound was calculated related to HOMO and LUMO energies which confirm the occurring of charge transformation between the base and ligand. Besides frontier molecular orbitals (FMO), molecular electrostatic potential (MEP) was performed. The NLO properties related to Polarizability and hyperpolarizability based on the finite-field approach were also discussed. Crown Copyright © 2015. Published by Elsevier B.V. All rights reserved.

  9. Molecular structure, electronic properties, NLO, NBO analysis and spectroscopic characterization of Gabapentin with experimental (FT-IR and FT-Raman) techniques and quantum chemical calculations

    Science.gov (United States)

    Sinha, Leena; Karabacak, Mehmet; Narayan, V.; Cinar, Mehmet; Prasad, Onkar

    2013-05-01

    Gabapentin (GP), structurally related to the neurotransmitter GABA (gamma-aminobutyric acid), mimics the activity of GABA and is also widely used in neurology for the treatment of peripheral neuropathic pain. It exists in zwitterionic form in solid state. The present communication deals with the quantum chemical calculations of energies, geometrical structure and vibrational wavenumbers of GP using density functional (DFT/B3LYP) method with 6-311++G(d,p) basis set. In view of the fact that amino acids exist as zwitterions as well as in the neutral form depending on the environment (solvent, pH, etc.), molecular properties of both the zwitterionic and neutral form of GP have been analyzed. The fundamental vibrational wavenumbers as well as their intensities were calculated and compared with experimental FT-IR and FT-Raman spectra. The fundamental assignments were done on the basis of the total energy distribution (TED) of the vibrational modes, calculated with scaled quantum mechanical (SQM) method. The electric dipole moment, polarizability and the first hyperpolarizability values of the GP have been calculated at the same level of theory and basis set. The nonlinear optical (NLO) behavior of zwitterionic and neutral form has been compared. Stability of the molecule arising from hyper-conjugative interactions and charge delocalization has been analyzed using natural bond orbital analysis. Ultraviolet-visible (UV-Vis) spectrum of the title molecule has also been calculated using TD-DFT method. The thermodynamic properties of both the zwitterionic and neutral form of GP at different temperatures have been calculated.

  10. IMF dependence of the open-closed field line boundary in Saturn's ionosphere, and its relation to the UV auroral oval observed by the Hubble Space Telescope

    Directory of Open Access Journals (Sweden)

    E. S. Belenkaya

    2007-06-01

    Full Text Available We study the dependence of Saturn's magnetospheric magnetic field structure on the interplanetary magnetic field (IMF, together with the corresponding variations of the open-closed field line boundary in the ionosphere. Specifically we investigate the interval from 8 to 30 January 2004, when UV images of Saturn's southern aurora were obtained by the Hubble Space Telescope (HST, and simultaneous interplanetary measurements were provided by the Cassini spacecraft located near the ecliptic ~0.2 AU upstream of Saturn and ~0.5 AU off the planet-Sun line towards dawn. Using the paraboloid model of Saturn's magnetosphere, we calculate the magnetospheric magnetic field structure for several values of the IMF vector representative of interplanetary compression regions. Variations in the magnetic structure lead to different shapes and areas of the open field line region in the ionosphere. Comparison with the HST auroral images shows that the area of the computed open flux region is generally comparable to that enclosed by the auroral oval, and sometimes agrees in detail with its poleward boundary, though more typically being displaced by a few degrees in the tailward direction.

  11. Urea, Uric Acid, Prolactin and fT4 Concentrations in Aqueous Humor of Keratoconus Patients.

    Science.gov (United States)

    Stachon, Tanja; Stachon, Axel; Hartmann, Ulrike; Seitz, Berthold; Langenbucher, Achim; Szentmáry, Nóra

    2017-06-01

    Keratoconus is a noninflammatory disease of the cornea associated with progressive thinning and conical shape. Metabolic alterations in the urea cycle, with changes in collagen fibril stability, oxidative stress, thyroid hormones and prolactin with regulatory effect on biosynthesis and biomechanical stability of corneal stroma, may all play a role in keratoconus etiology. Our purpose was to determine urea, uric acid, prolactin and free thyroxin (fT4) concentrations in human aqueous humor (hAH) of keratoconus and cataract patients. hAH was collected from 100 keratoconus (penetrating keratoplasty) (41.9 ± 14.9 years, 69 males) and 100 cataract patients (cataract surgery) (71.2 ± 12.4 years, 58 males). Urea, uric acid, prolactin and fT4 concentrations were measured by Siemens clinical chemistry or immunoassay system. For statistical analysis, a generalized linear model (GLM) was used. Urea concentration was 11.88 ± 3.03 mg/dl in keratoconus and 16.44 ± 6.40 mg/dl in cataract patients, uric acid 2.04 ± 0.59 mg/dl in keratoconus and 2.18 ± 0.73 mg/dl in cataract groups. Prolactin concentration was 3.18 ± 0.34 ng/ml in keratoconus and 3.33 ± 0.32 ng/ml in cataract patients, fT4 20.57 ± 4.76 pmol/l in KC and 19.06 ± 3.86 pmol/l in cataract group. Urea concentration was effected through gender (p = 0.039), age (p = 0.001) and diagnosis (p = 0.025). Uric acid concentration was not effected through any of the analyzed parameters (p > 0.056). Prolactin and fT4 concentration were effected only through diagnosis (p = 0.009 and p = 0.006). Urea and prolactin concentrations are decreased, fT4 concentration is increased in aqueous humor of keratoconus patients, and uric acid concentration remains unchanged. Urea concentration in aqueous humor is also increased in older and male patients. Therefore, metabolic disorder and hormonal balance may both have an impact on keratoconus development. Further studies are necessary to assess the specific impact.

  12. Drift and transmission FT-IR spectroscopy of forest soils: an approach to determine decomposition processes of forest litter

    International Nuclear Information System (INIS)

    Haberhauer, G.; Gerzabek, M.H.

    1999-06-01

    A method is described to characterize organic soil layers using Fourier transformed infrared spectroscopy. The applicability of FT-IR, either dispersive or transmission, to investigate decomposition processes of spruce litter in soil originating from three different forest sites in two climatic regions was studied. Spectral information of transmission and diffuse reflection FT-IR spectra was analyzed and compared. For data evaluation Kubelka Munk (KM) transformation was applied to the DRIFT spectra. Sample preparation for DRIFT is simpler and less time consuming in comparison to transmission FT-IR, which uses KBr pellets. A variety of bands characteristics of molecular structures and functional groups has been identified for these complex samples. Analysis of both transmission FT-IR and DRIFT, showed that the intensity of distinct bands is a measure of the decomposition of forest litter. Interferences due to water adsorption spectra were reduced by DRIFT measurement in comparison to transmission FT-IR spectroscopy. However, data analysis revealed that intensity changes of several bands of DRIFT and transmission FT-IR were significantly correlated with soil horizons. The application of regression models enables identification and differentiation of organic forest soil horizons and allows to determine the decomposition status of soil organic matter in distinct layers. On the basis of the data presented in this study, it may be concluded that FT-IR spectroscopy is a powerful tool for the investigation of decomposition dynamics in forest soils. (author)

  13. High-definition Fourier Transform Infrared (FT-IR) Spectroscopic Imaging of Human Tissue Sections towards Improving Pathology

    Science.gov (United States)

    Nguyen, Peter L.; Davidson, Bennett; Akkina, Sanjeev; Guzman, Grace; Setty, Suman; Kajdacsy-Balla, Andre; Walsh, Michael J.

    2015-01-01

    High-definition Fourier Transform Infrared (FT-IR) spectroscopic imaging is an emerging approach to obtain detailed images that have associated biochemical information. FT-IR imaging of tissue is based on the principle that different regions of the mid-infrared are absorbed by different chemical bonds (e.g., C=O, C-H, N-H) within cells or tissue that can then be related to the presence and composition of biomolecules (e.g., lipids, DNA, glycogen, protein, collagen). In an FT-IR image, every pixel within the image comprises an entire Infrared (IR) spectrum that can give information on the biochemical status of the cells that can then be exploited for cell-type or disease-type classification. In this paper, we show: how to obtain IR images from human tissues using an FT-IR system, how to modify existing instrumentation to allow for high-definition imaging capabilities, and how to visualize FT-IR images. We then present some applications of FT-IR for pathology using the liver and kidney as examples. FT-IR imaging holds exciting applications in providing a novel route to obtain biochemical information from cells and tissue in an entirely label-free non-perturbing route towards giving new insight into biomolecular changes as part of disease processes. Additionally, this biochemical information can potentially allow for objective and automated analysis of certain aspects of disease diagnosis. PMID:25650759

  14. Gyrokinetic full f analysis of electric field dynamics and poloidal velocity in the FT2-tokamak configuration

    International Nuclear Information System (INIS)

    Leerink, S.; Heikkinen, J. A.; Janhunen, S. J.; Kiviniemi, T. P.; Nora, M.; Ogando, F.

    2008-01-01

    The ELMFIRE gyrokinetic simulation code has been used to perform full f simulations of the FT-2 tokamak. The dynamics of the radial electric field and the creation of poloidal velocity in the presence of turbulence are presented.

  15. Application of FT-IR Absorption Spectroscopy to Characterize Waste and Bio-Fuels for Pyrolysis and Gasification

    Czech Academy of Sciences Publication Activity Database

    Kalisz, S.; Svoboda, Karel; Robak, Z.; Baxter, D.; Andersen, L. K.

    2008-01-01

    Roč. 8, - (2008), s. 51-52 ISSN 1733-4381 Institutional research plan: CEZ:AV0Z40720504 Keywords : ft-Iir spectroscopy * bio-fuels * gasification Subject RIV: CI - Industrial Chemistry, Chemical Engineering

  16. Identification and characterization of salmonella serotypes using DNA spectral characteristics by fourier transform infrared (FT-IR) spectroscopy

    Science.gov (United States)

    Analysis of DNA samples of Salmonella serotypes (Salmonella Typhimurium, Salmonella Enteritidis, Salmonella Infantis, Salmonella Heidelberg and Salmonella Kentucky) were performed using Fourier transform infrared spectroscopy (FT-IR) spectrometer by placing directly in contact with a diamond attenua...

  17. FT-IR imaging for quantitative determination of liver fat content in non-alcoholic fatty liver.

    Science.gov (United States)

    Kochan, K; Maslak, E; Chlopicki, S; Baranska, M

    2015-08-07

    In this work we apply FT-IR imaging of large areas of liver tissue cross-section samples (∼5 cm × 5 cm) for quantitative assessment of steatosis in murine model of Non-Alcoholic Fatty Liver (NAFLD). We quantified the area of liver tissue occupied by lipid droplets (LDs) by FT-IR imaging and Oil Red O (ORO) staining for comparison. Two alternative FT-IR based approaches are presented. The first, straightforward method, was based on average spectra from tissues and provided values of the fat content by using a PLS regression model and the reference method. The second one – the chemometric-based method – enabled us to determine the values of the fat content, independently of the reference method by means of k-means cluster (KMC) analysis. In summary, FT-IR images of large size liver sections may prove to be useful for quantifying liver steatosis without the need of tissue staining.

  18. Aerial Survey of Vessel Usage and Marine Animal Occurrence between Ft. Pierce and Key West Florida, 1992-2004

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — An aerial survey between Ft Pierce and Key West Florida was performed aboard US Coast Guard helicopters and fixed wing aircraft from September 1992 through March...

  19. Application of FT-IR spectroscopy on breast cancer serum analysis

    Science.gov (United States)

    Elmi, Fatemeh; Movaghar, Afshin Fayyaz; Elmi, Maryam Mitra; Alinezhad, Heshmatollah; Nikbakhsh, Novin

    2017-12-01

    Breast cancer is regarded as the most malignant tumor among women throughout the world. Therefore, early detection and proper diagnostic methods have been known to help save women's lives. Fourier Transform Infrared (FT-IR) spectroscopy, coupled with PCA-LDA analysis, is a new technique to investigate the characteristics of serum in breast cancer. In this study, 43 breast cancer and 43 healthy serum samples were collected, and the FT-IR spectra were recorded for each one. Then, PCA analysis and linear discriminant analysis (LDA) were used to analyze the spectral data. The results showed that there were differences between the spectra of the two groups. Discriminating wavenumbers were associated with several spectral differences over the 950-1200 cm- 1(sugar), 1190-1350 cm- 1 (collagen), 1475-1710 cm- 1 (protein), 1710-1760 cm- 1 (ester), 2800-3000 cm- 1 (stretching motions of -CH2 & -CH3), and 3090-3700 cm- 1 (NH stretching) regions. PCA-LDA performance on serum IR could recognize changes between the control and the breast cancer cases. The diagnostic accuracy, sensitivity, and specificity of PCA-LDA analysis for 3000-3600 cm- 1 (NH stretching) were found to be 83%, 84%, 74% for the control and 80%, 76%, 72% for the breast cancer cases, respectively. The results showed that the major spectral differences between the two groups were related to the differences in protein conformation in serum samples. It can be concluded that FT-IR spectroscopy, together with multivariate data analysis, is able to discriminate between breast cancer and healthy serum samples.

  20. Masculine Chest-Wall Contouring in FtM Transgender: a Personal Approach.

    Science.gov (United States)

    Lo Russo, Giulia; Tanini, Sara; Innocenti, Marco

    2017-04-01

    Chest-wall contouring surgery is one of the first steps in sexual reassignment in female-to-male (FtM) transsexuals that contributes to strengthening of the self-image and facilitates living in the new gender role. The main goal is to masculinize the chest by removing the female contour. Chest contour, scar placement, scar shape, scar length, nipple-areola position, nipple size and the areola size are the key points. Between July 2013 and June 2016, 25 FtM transgender patients underwent surgical procedures to create a masculine chest-wall contour. In our study, we just considered 16 patients who have undergone chest surgery with the double incision method. The patients' survey revealed a high satisfaction rate with the aesthetic result. In our group, no complications occurred, and two patients have undergone supplementary surgery for axillary dog-ear revision and nipple reconstruction. The authors propose a new technical approach and indications for FtM transgender patients' surgery. A longer scar that emphasizes the pectoralis muscle, a smaller nipple and a resized and refaced areola are the key points of our technique to give a masculine appearance to the chest. The scars are permanent, but most of them will fade and the patients are enthusiastic with their new "male" chest appearance. The high level of satisfaction, the great aesthetic result and the low rate of complications suggest to us the use of this technique in medium- and large-size breasts. This journal requires that authors assign a level of evidence to each article. For a full description of these Evidence-Based Medicine ratings, please refer to the Table of Contents or the online Instructions to Authors www.springer.com/00266 .

  1. Fluorescence, aggregation properties and FT-IR microspectroscopy of elastin and collagen fibers.

    Science.gov (United States)

    Vidal, Benedicto de Campos

    2014-10-01

    Histological and histochemical observations support the hypothesis that collagen fibers can link to elastic fibers. However, the resulting organization of elastin and collagen type complexes and differences between these materials in terms of macromolecular orientation and frequencies of their chemical vibrational groups have not yet been solved. This study aimed to investigate the macromolecular organization of pure elastin, collagen type I and elastin-collagen complexes using polarized light DIC-microscopy. Additionally, differences and similarities between pure elastin and collagen bundles (CB) were investigated by Fourier transform-infrared (FT-IR) microspectroscopy. Although elastin exhibited a faint birefringence, the elastin-collagen complex aggregates formed in solution exhibited a deep birefringence and formation of an ordered-supramolecular complex typical of collagen chiral structure. The FT-IR study revealed elastin and CB peptide NH groups involved in different types of H-bonding. More energy is absorbed in the vibrational transitions corresponding to CH, CH2 and CH3 groups (probably associated with the hydrophobicity demonstrated by 8-anilino-1-naphtalene sulfonic acid sodium salt [ANS] fluorescence), and to νCN, δNH and ωCH2 groups of elastin compared to CB. It is assumed that the α-helix contribution to the pure elastin amide I profile is 46.8%, whereas that of the B-sheet is 20% and that unordered structures contribute to the remaining percentage. An FT-IR profile library reveals that the elastin signature within the 1360-1189cm(-1) spectral range resembles that of Conex-Toray aramid fibers. Copyright © 2014 Elsevier GmbH. All rights reserved.

  2. FT-IR spectroscopic studies of protein secondary structures for breast cancer diagnosis

    International Nuclear Information System (INIS)

    Karamancheva, I; Simonova, D.; Milev, A.

    2013-01-01

    Full text: Roughly 14 million new cancer cases and 8 million cancer deaths have occurred worldwide in 2012. At least 30 % of all cancer cases and 40 % of the cancer deaths should be avoided by improving the early detection. Fourier transform infrared (FT-IR) spectroscopy has shown many advantages as a tool for the detection of cancer over the traditional methods such as histopathological analysis, X-ray transmission, ultrasonic and computer tomography techniques. With the aim to establish the FT-IR spectroscopy as an alternative method for the diagnosis of human cancers, we have made several studies to examine in details the spectroscopic properties of normal and carcinomatous tissues. Human breast tissues were obtained immediately after surgical breast resection with the informed patient's consent. In our studies we made extensive use of Fourier self-deconvolution, second-order derivatization, difference spectra, curve-fitting procedures and quantitative determinations according to Beer's law. Cancer is a multi-step process. Characteristic differences in both the frequencies and the intensity ratios of several bands have been revealed. Considerable differences have been found in the spectral patterns. The most important and informative region in the mid-IR for determination of protein secondary structure is the amide I and amide II region. The bands between 1730 and 1600 cm -1 are highly sensitive to conformational changes. Considerable changes were observed in the A1735/A1652 absorbance ratio, which provides a measure for the content of a- helix and P-sheet domains. Our investigations have shown that the major biomarker peaks are in the amide I and amide II regions. In the so called 'fingerprint region' many molecular constituents such as lipids, phospholipids, proteins, DNA and RNA, carbohydrates and metabolites may overlap and the quantitative interpretation is impossible. The spectrum may therefore reflect only the average biochemical composition.; key words

  3. Evaluation of Polymerization Efficacy in Composite Resins via FT-IR Spectroscopy and Vickers Microhardness Test

    Directory of Open Access Journals (Sweden)

    Tahereh-Sadat Jafarzadeh

    2015-12-01

    Full Text Available Background and aims. Polymerization efficacy affects the properties and performance of composite resin restorations.The purpose of this study was to evaluate the effectiveness of polymerization of two micro-hybrid, two nano-hybrid and one nano-filled ormocer-based composite resins, cured by two different light-curing systems, using Fourier transformation infrared (FT-IR spectroscopy and Vickers microhardness testing at two different depths (top surface, 2 mm. Materials and methods. For FT-IR spectrometry, five cylindrical specimens (5mm in diameter × 2 mm in length were prepared from each composite resin using Teflon molds and polymerized for 20 seconds. Then, 70-μm wafers were sectioned at the top surface and at2mm from the top surface. The degree of conversion for each sample was calculated using FT-IR spectroscopy. For Vickers micro-hardness testing, three cylindrical specimens were prepared from each composite resin and polymerized for 20 seconds. The Vickers microhardness test (Shimadzu, Type M, Japan was performed at the top and bottom (depth=2 mm surfaces of each specimen. Three-way ANOVA with independent variables and Tukey tests were performed at 95% significance level. Results. No significant differences were detected in degree of conversion and microhardness between LED and QTH light-curing units except for the ormocer-based specimen, CeramX, which exhibited significantly higher DC by LED. All the composite resins showed a significantly higher degree of conversion at the surface. Microhardness was not significantly affected by depth, except for Herculite XRV Ultra and CeramX, which showed higher values at the surface. Conclusion. Composite resins containing nano-particles generally exhibited more variations in degree of conversion and microhardness.

  4. Evaluation of Polymerization Efficacy in Composite Resins via FT-IR Spectroscopy and Vickers Microhardness Test.

    Science.gov (United States)

    Jafarzadeh, Tahereh-Sadat; Erfan, Mohammad; Behroozibakhsh, Marjan; Fatemi, Mostafa; Masaeli, Reza; Rezaei, Yashar; Bagheri, Hossein; Erfan, Yasaman

    2015-01-01

    Background and aims. Polymerization efficacy affects the properties and performance of composite resin restorations.The purpose of this study was to evaluate the effectiveness of polymerization of two micro-hybrid, two nano-hybrid and one nano-filled ormocer-based composite resins, cured by two different light-curing systems, using Fourier transformation infrared (FT-IR) spectroscopy and Vickers microhardness testing at two different depths (top surface, 2 mm). Materials and methods. For FT-IR spectrometry, five cylindrical specimens (5mm in diameter × 2 mm in length) were prepared from each composite resin using Teflon molds and polymerized for 20 seconds. Then, 70-μm wafers were sectioned at the top surface and at2mm from the top surface. The degree of conversion for each sample was calculated using FT-IR spectroscopy. For Vickers micro-hardness testing, three cylindrical specimens were prepared from each composite resin and polymerized for 20 seconds. The Vickers microhardness test (Shimadzu, Type M, Japan) was performed at the top and bottom (depth=2 mm) surfaces of each specimen. Three-way ANOVA with independent variables and Tukey tests were performed at 95% significance level. Results. No significant differences were detected in degree of conversion and microhardness between LED and QTH light-curing units except for the ormocer-based specimen, CeramX, which exhibited significantly higher DC by LED. All the composite resins showed a significantly higher degree of conversion at the surface. Microhardness was not significantly affected by depth, except for Herculite XRV Ultra and CeramX, which showed higher values at the surface. Conclusion. Composite resins containing nano-particles generally exhibited more variations in degree of conversion and microhardness.

  5. Quantification and spatial distribution of salicylic acid in film tablets using FT-Raman mapping with multivariate curve resolution

    OpenAIRE

    Haslet Eksi-Kocak; Sibel Ilbasmis Tamer; Sebnem Yilmaz; Merve Eryilmaz; Ismail Hakkı Boyaci; Ugur Tamer

    2018-01-01

    In this study, we proposed a rapid and sensitive method for quantification and spatial distribution of salicylic acid in film tablets using FT-Raman spectroscopy with multivariate curve resolution (MCR). For this purpose, the constituents of film tablets were identified by using FT-Raman spectroscopy, and then eight different concentrations of salicylic acid tablets were visualized by Raman mapping. MCR was applied to mapping data to expose the active pharmaceutical ingredients in the presenc...

  6. Typing some of lactic acid bacteria in Syria using PCR and FT-IR techniques

    International Nuclear Information System (INIS)

    Al-Mariri, A.; Sharabi, N. D.

    2008-11-01

    Lactic Acid Bacteria (LAB) are considered to be the most useful microorganisms. They are beneficial in flavoring foods, inhibiting pathogenic as well as spoilage bacteria in food products. The isolates of LAB were obtained from traditional Syrian dairy products (white cheese and curdled yogurt) obtained from different regions in Syria. The isolates were subjected to phenotypic characterization analyses. The PCR technique of bacterial DNA was evaluated as an advanced tool for the identification of LAB. It was found that strains: E. faecium, E. faecalis and S. thermophilus dominate in white cheese and in yogurt. Our results demonstrated that we could identify LAB using Fourier transform infrared spectroscopy (FT-IR) patterns. (Authors)

  7. Typing some of lactic acid bacteria in Syria using PCR and FT-IR techniques

    Energy Technology Data Exchange (ETDEWEB)

    Al-Mariri, A; Sharabi, N D [Atomic Energy Commission, Damascus (Syrian Arab Republic), Dept. of Molecular Biology and Biotechnology

    2008-11-15

    Lactic Acid Bacteria (LAB) are considered to be the most useful microorganisms. They are beneficial in flavoring foods, inhibiting pathogenic as well as spoilage bacteria in food products. The isolates of LAB were obtained from traditional Syrian dairy products (white cheese and curdled yogurt) obtained from different regions in Syria. The isolates were subjected to phenotypic characterization analyses. The PCR technique of bacterial DNA was evaluated as an advanced tool for the identification of LAB. It was found that strains: E. faecium, E. faecalis and S. thermophilus dominate in white cheese and in yogurt. Our results demonstrated that we could identify LAB using Fourier transform infrared spectroscopy (FT-IR) patterns. (Authors)

  8. Study on the bywalled plasma near the FT-2 tokamak limiter

    International Nuclear Information System (INIS)

    Budnikov, V.N.; Gerasimenko, G.V.; Esipov, L.A.; Levitskij, A.N.; Sakharov, I.E.; Shatalin, S.V.

    1987-01-01

    Results od investigation into the bywalled plasma near the FT-2 tokamak limiter, conducted using the ternary probe method are presented. Plasma charged particle concentration radial profiles, results of measuring the electron temperature and azimuthal electric field are presented. It is shown, that at l > 2mm, where l is the distance up to the limiter, concentration practically does not depend on the longitudinal coordinate and near the limiter (l < 20 mm) a sharp drop of plasma charged particle concentration measured values (∼ 2-fold) is observed. Neoclassical mechanism of filling the depletion area (the probe shade) is confirmed

  9. FT-IR spectroscopic analysis for studying Clostridium cell response to conversion of enzymatically hydrolyzed hay

    Science.gov (United States)

    Grube, Mara; Gavare, Marita; Nescerecka, Alina; Tihomirova, Kristina; Mezule, Linda; Juhna, Talis

    2013-07-01

    Grass hay is one of assailable cellulose containing non-food agricultural wastes that can be used as a carbohydrate source by microorganisms producing biofuels. In this study three Clostridium strains Clostridium acetobutylicum, Clostridium beijerinckii and Clostridium tetanomorphum, capable of producing acetone, butanol and ethanol (ABE) were adapted to convert enzymatically hydrolyzed hay used as a growth media additive. The results of growth curves, substrate degradation kinetics and FT-IR analyses of bacterial biomass macromolecular composition showed diverse strain-specific cell response to the growth medium composition.

  10. Authenticity study of Phyllanthus species by NMR and FT-IR techniques coupled with chemometric methods

    International Nuclear Information System (INIS)

    Santos, Maiara S.; Pereira-Filho, Edenir R.; Ferreira, Antonio G.; Boffo, Elisangela F.; Figueira, Glyn M.

    2012-01-01

    The importance of medicinal plants and their use in industrial applications is increasing worldwide, especially in Brazil. Phyllanthus species, popularly known as 'quebra-pedras' in Brazil, are used in folk medicine for treating urinary infections and renal calculus. This paper reports an authenticity study, based on herbal drugs from Phyllanthus species, involving commercial and authentic samples using spectroscopic techniques: FT-IR, 1 H HR-MAS NMR and 1 H NMR in solution, combined with chemometric analysis. The spectroscopic techniques evaluated, coupled with chemometric methods, have great potential in the investigation of complex matrices. Furthermore, several metabolites were identified by the NMR techniques. (author)

  11. Authenticity study of Phyllanthus species by NMR and FT-IR Techniques coupled with chemometric methods

    Directory of Open Access Journals (Sweden)

    Maiara S. Santos

    2012-01-01

    Full Text Available The importance of medicinal plants and their use in industrial applications is increasing worldwide, especially in Brazil. Phyllanthus species, popularly known as "quebra-pedras" in Brazil, are used in folk medicine for treating urinary infections and renal calculus. This paper reports an authenticity study, based on herbal drugs from Phyllanthus species, involving commercial and authentic samples using spectroscopic techniques: FT-IR, ¹H HR-MAS NMR and ¹H NMR in solution, combined with chemometric analysis. The spectroscopic techniques evaluated, coupled with chemometric methods, have great potential in the investigation of complex matrices. Furthermore, several metabolites were identified by the NMR techniques.

  12. Matrix isolation FT-IR spectroscopy and molecular orbital study of sarcosine methyl ester

    OpenAIRE

    Gómez-Zavaglia, Andrea; Fausto, R.

    2004-01-01

    N-methylglycine methyl ester (sarcosine-Me) has been studied by matrix isolation FT-IR spectroscopy and molecular orbital calculations undertaken at the DFT/B3LYP and MP2 levels of theory with the 6-311++G(d,p) and 6-31++G(d,p) basis set, respectively. Twelve different conformers were located in the potential energy surface of the studied compound, with the ASC conformer being the ground conformational state. This form is analogous to the dimethylglycine methyl ester most stable conformer and...

  13. Authenticity study of Phyllanthus species by NMR and FT-IR techniques coupled with chemometric methods

    Energy Technology Data Exchange (ETDEWEB)

    Santos, Maiara S.; Pereira-Filho, Edenir R.; Ferreira, Antonio G. [Universidade Federal de Sao Carlos (UFSCAR), SP (Brazil). Dept. de Quimica; Boffo, Elisangela F. [Universidade Federal da Bahia (UFBA), Salvador, BA (Brazil). Inst. de Quimica; Figueira, Glyn M., E-mail: maiarassantos@yahoo.com.br [Universidade Estadual de Campinas (UNICAMP), Campinas, SP (Brazil). Centro Pluridisciplinar de Pesquisas Quimicas, Biologicas e Agricolas

    2012-07-01

    The importance of medicinal plants and their use in industrial applications is increasing worldwide, especially in Brazil. Phyllanthus species, popularly known as 'quebra-pedras' in Brazil, are used in folk medicine for treating urinary infections and renal calculus. This paper reports an authenticity study, based on herbal drugs from Phyllanthus species, involving commercial and authentic samples using spectroscopic techniques: FT-IR, {sup 1}H HR-MAS NMR and {sup 1}H NMR in solution, combined with chemometric analysis. The spectroscopic techniques evaluated, coupled with chemometric methods, have great potential in the investigation of complex matrices. Furthermore, several metabolites were identified by the NMR techniques. (author)

  14. Spherically Symmetric Geometries in f(T) and f(R) Gravitational Theories

    International Nuclear Information System (INIS)

    Nashed, Gamal G. L.

    2015-01-01

    Using the well know relation between Ricci scalar, R, and torsion scalar, T, that is, R=-T-2∇_αT"α, we show that, for any spherically symmetric spacetime whose (i) scalar torsion vanishing, that is, T=T_μ_ν"αS_α"μ"ν=0 or (ii) total derivative term, that is, ∇_αT"α with T"α is the contraction of the torsion, vanishing, or (iii) the combination of scalar torsion and total derivative term vanishing, could be solution for f(T) and f(R) gravitational theories.

  15. Clinical study of FT-207 suppository for head and neck malignancies

    International Nuclear Information System (INIS)

    Tomioka, Masashi; Usami, Masami; Sakamoto, Ayako

    1982-01-01

    Futraful suppository 1.5g per day was administered to 33 patients with head and neck malignancies. Among 33 cases which entered into the study, 16 cases were evaluated. Out of 16 evaluable cases, complete responses (CRs) were obtained in 4 cases and partial responses (PRs) in 7 cases. An overall response rate including 4 CRs and 7 PRs was 68.8%. Side effects due to FT-207 suppository were developed in 14 cases out of 33 patients (42.4%) Side effects such as anal pain, anorexia, diarrhea, pigmentation, exanthema and nail change were observed. No severe side effect was encountered. (author)

  16. Typing some of lactic acid bacteria in Syria using PCR and FT-IR techniques

    International Nuclear Information System (INIS)

    Al-Mariri, A.; Sharabi, N. D.

    2010-01-01

    Lactic Acid Bacteria (LAB) are considered to be the most useful microorganisms. They are beneficial in flavoring foods, inhibiting pathogenic as well as spoilage bacteria in food products. The isolates of LAB were obtained from traditional Syrian dairy products (white cheese and curdled yogurt) obtained from different regions in Syria. The isolates were subjected to phenotypic characterization analyses. The PCR technique of bacterial DNA was evaluated as an advanced tool for the identification of LAB. It was found that strains: E. faecium, E. faecalis and S. thermophilus dominate in white cheese and in yogurt. Our results demonstrated that we could identify LAB using Fourier transform infrared spectroscopy (FT-IR) patterns. (author)

  17. [Application of FT-IR pattern recognition method for the quality control of pharmaceutical ingredients].

    Science.gov (United States)

    Horgos, József; Kóger, Péter; Zelkó, Romána

    2009-01-01

    Nowadays infrared spectroscopy and chemometrics have proven their effectiveness for both qualitative and quantitative analyses in different fields like agriculture, food, chemical and oil industry. Furier Transformation Infrared Spectroscopy (FT-IR) combined with Attenuated Total Reflectance (ATR) plate is a fast identification instrument. It is suitable for analysis of solid and liquid phase, too. Associated with chemometrics, it would be a powerful tool for the pharmaceutical wholesalers to detect the insufficient quality of pharmaceutical ingredients. In the present study beside the review of the infra red technology, pharmaceutical ingredients were examined with the help of our spectra library.

  18. Authenticity study of Phyllanthus species by NMR and FT-IR techniques coupled with chemometric methods

    Energy Technology Data Exchange (ETDEWEB)

    Santos, Maiara S.; Pereira-Filho, Edenir R.; Ferreira, Antonio G. [Universidade Federal de Sao Carlos (UFSCAR), SP (Brazil). Dept. de Quimica; Boffo, Elisangela F. [Universidade Federal da Bahia (UFBA), Salvador, BA (Brazil). Inst. de Quimica; Figueira, Glyn M., E-mail: maiarassantos@yahoo.com.br [Universidade Estadual de Campinas (UNICAMP), Campinas, SP (Brazil). Centro Pluridisciplinar de Pesquisas Quimicas, Biologicas e Agricolas

    2012-07-01

    The importance of medicinal plants and their use in industrial applications is increasing worldwide, especially in Brazil. Phyllanthus species, popularly known as 'quebra-pedras' in Brazil, are used in folk medicine for treating urinary infections and renal calculus. This paper reports an authenticity study, based on herbal drugs from Phyllanthus species, involving commercial and authentic samples using spectroscopic techniques: FT-IR, {sup 1}H HR-MAS NMR and {sup 1}H NMR in solution, combined with chemometric analysis. The spectroscopic techniques evaluated, coupled with chemometric methods, have great potential in the investigation of complex matrices. Furthermore, several metabolites were identified by the NMR techniques. (author)

  19. Using FT-IR Spectroscopy to Elucidate the Structures of Ablative Polymers

    Science.gov (United States)

    Fan, Wendy

    2011-01-01

    The composition and structure of an ablative polymer has a multifaceted influence on its thermal, mechanical and ablative properties. Understanding the molecular level information is critical to the optimization of material performance because it helps to establish correlations with the macroscopic properties of the material, the so-called structure-property relationship. Moreover, accurate information of molecular structures is also essential to predict the thermal decomposition pathways as well as to identify decomposition species that are fundamentally important to modeling work. In this presentation, I will describe the use of infrared transmission spectroscopy (FT-IR) as a convenient tool to aid the discovery and development of thermal protection system materials.

  20. Thermodynamics in f(T Gravity with Nonminimal Coupling to Matter

    Directory of Open Access Journals (Sweden)

    Tahereh Azizi

    2017-01-01

    Full Text Available In the present paper, we study the thermodynamics behavior of the field equations for the generalized f(T gravity with arbitrary coupling between matter and the torsion scalar. In this regard, we explore the verification of the first law of thermodynamics at the apparent horizon of the Friedmann-Robertson-Walker universe in two different perspectives, namely, the nonequilibrium and equilibrium descriptions of thermodynamics. Furthermore, we investigate the validity of the second law of thermodynamics for both descriptions of this scenario with the assumption that the temperature of matter inside the horizon is similar to that of horizon.

  1. Pentalum SpiDAR Deployment at SWiFT FY17.

    Energy Technology Data Exchange (ETDEWEB)

    Westergaard, Carsten [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Pol, Suhas [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Pereira, Tassia [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Castillo, Ricardo [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2016-12-01

    The Texas Tech University ( TTU ) research group is actively studying the wake development of wind turbines, as part of developing innovative wake control strategies to improve the performance of wind farms. Recently, the team received a set of five new gro und lidars to perform field measurements at the Sandia National Laboratories SWiFT site. This document describes tests details including configurations, timeframe, hardware, and the required collaboration from the Sandia team. This test plan will facili tate the coordination between both TTU and the Sandia team in terms of site accessibility, staff training, and data sharing to meet the specific objectives of the tests.

  2. A Controlled-Environment Chamber for Atmospheric Chemistry Studies Using FT-IR Spectroscopy

    Science.gov (United States)

    1990-06-01

    necessary and identify by block number) FELD GROUP SUB-GROUP i >Chamber, controlled environment; long-path cell ; 07 04 FT-IR; Hydrazine decay...modification doubles the useable path length of the original multipass cell described by White (Reference 8). The pattern of images formed on the nesting...system is shown in Figure 13. 24 z C C02, Ibm, El4 944 C3 ta) caC E-4- 252 14 $4 41) 41) 0. 0 04 04 4 41) ~0 to 0.0 V-4 (A q14 0~ 1% 4-r4 $4 0 u P416 4 4

  3. Inflorescence Development and the Role of LsFT in Regulating Bolting in Lettuce (Lactuca sativa L.)

    Science.gov (United States)

    Chen, Zijing; Han, Yingyan; Ning, Kang; Ding, Yunyu; Zhao, Wensheng; Yan, Shuangshuang; Luo, Chen; Jiang, Xiaotang; Ge, Danfeng; Liu, Renyi; Wang, Qian; Zhang, Xiaolan

    2018-01-01

    Lettuce (Lactuca sativa L.) is one of the most important leafy vegetable that is consumed during its vegetative growth. The transition from vegetative to reproductive growth is induced by high temperature, which has significant economic effect on lettuce production. However, the progression of floral transition and the molecular regulation of bolting are largely unknown. Here we morphologically characterized the inflorescence development and functionally analyzed the FLOWERING LOCUS T (LsFT) gene during bolting regulation in lettuce. We described the eight developmental stages during floral transition process. The expression of LsFT was negatively correlated with bolting in different lettuce varieties, and was promoted by heat treatment. Overexpression of LsFT could recover the late-flowering phenotype of ft-2 mutant. Knockdown of LsFT by RNA interference dramatically delayed bolting in lettuce, and failed to respond to high temperature. Therefore, this study dissects the process of inflorescence development and characterizes the role of LsFT in bolting regulation in lettuce. PMID:29403510

  4. Inflorescence Development and the Role of LsFT in Regulating Bolting in Lettuce (Lactuca sativa L.).

    Science.gov (United States)

    Chen, Zijing; Han, Yingyan; Ning, Kang; Ding, Yunyu; Zhao, Wensheng; Yan, Shuangshuang; Luo, Chen; Jiang, Xiaotang; Ge, Danfeng; Liu, Renyi; Wang, Qian; Zhang, Xiaolan

    2017-01-01

    Lettuce ( Lactuca sativa L.) is one of the most important leafy vegetable that is consumed during its vegetative growth. The transition from vegetative to reproductive growth is induced by high temperature, which has significant economic effect on lettuce production. However, the progression of floral transition and the molecular regulation of bolting are largely unknown. Here we morphologically characterized the inflorescence development and functionally analyzed the FLOWERING LOCUS T (LsFT) gene during bolting regulation in lettuce. We described the eight developmental stages during floral transition process. The expression of LsFT was negatively correlated with bolting in different lettuce varieties, and was promoted by heat treatment. Overexpression of LsFT could recover the late-flowering phenotype of ft-2 mutant. Knockdown of LsFT by RNA interference dramatically delayed bolting in lettuce, and failed to respond to high temperature. Therefore, this study dissects the process of inflorescence development and characterizes the role of LsFT in bolting regulation in lettuce.

  5. QM/MM methodology, docking and spectroscopic (FT-IR/FT-Raman, NMR, UV) and Fukui function analysis on adrenergic agonist

    Science.gov (United States)

    Uma Maheswari, J.; Muthu, S.; Sundius, Tom

    2015-02-01

    The Fourier transform infrared, FT-Raman, UV and NMR spectra of Ternelin have been recorded and analyzed. Harmonic vibrational frequencies have been investigated with the help of HF with 6-31G (d,p) and B3LYP with 6-31G (d,p) and LANL2DZ basis sets. The 1H and 13C nuclear magnetic resonance (NMR) chemical shifts of the molecule were calculated by GIAO method. The polarizability (α) and the first hyperpolarizability (β) values of the investigated molecule have been computed using DFT quantum mechanical calculations. Stability of the molecule arising from hyper conjugative interactions, and charge delocalization has been analyzed using natural bond orbital (NBO) analysis. The electron density-based local reactivity descriptors such as Fukui functions were calculated to explain the chemical selectivity or reactivity site in Ternelin. Finally the calculated results were compared to simulated infrared and Raman spectra of the title compound which show good agreement with observed spectra. Molecular docking studies have been carried out in the active site of Ternelin and reactivity with ONIOM was also investigated.

  6. FT-Raman, FT-IR and UV-visible spectral investigations and ab initio computations of anti-epileptic drug: Vigabatrin

    Science.gov (United States)

    Edwin, Bismi; Joe, I. Hubert

    2013-10-01

    Vibrational analysis of anti-epileptic drug vigabatrin, a structural GABA analog was carried out using NIR FT-Raman and FTIR spectroscopic techniques. The equilibrium geometry, various bonding features and harmonic vibrational wavenumbers were studied using density functional theory method. The detailed interpretation of the vibrational spectra has been carried out with the aid of VEDA.4 program. Vibrational spectra, natural bond orbital analysis and optimized molecular structure show clear evidence for the effect of electron charge transfer on the activity of the molecule. Predicted electronic absorption spectrum from TD-DFT calculation has been compared with the UV-vis spectrum. The Mulliken population analysis on atomic charges and the HOMO-LUMO energy were also calculated. Good consistency is found between the calculated results and experimental data for the electronic absorption as well as IR and Raman spectra. The blue-shifting of the Csbnd C stretching wavenumber reveals that the vinyl group is actively involved in the conjugation path. The NBO analysis confirms the occurrence of intramolecular hyperconjugative interactions resulting in ICT causing stabilization of the system.

  7. FT-Raman, FT-IR and UV-visible spectral investigations and ab initio computations of anti-epileptic drug: vigabatrin.

    Science.gov (United States)

    Edwin, Bismi; Joe, I Hubert

    2013-10-01

    Vibrational analysis of anti-epileptic drug vigabatrin, a structural GABA analog was carried out using NIR FT-Raman and FTIR spectroscopic techniques. The equilibrium geometry, various bonding features and harmonic vibrational wavenumbers were studied using density functional theory method. The detailed interpretation of the vibrational spectra has been carried out with the aid of VEDA.4 program. Vibrational spectra, natural bond orbital analysis and optimized molecular structure show clear evidence for the effect of electron charge transfer on the activity of the molecule. Predicted electronic absorption spectrum from TD-DFT calculation has been compared with the UV-vis spectrum. The Mulliken population analysis on atomic charges and the HOMO-LUMO energy were also calculated. Good consistency is found between the calculated results and experimental data for the electronic absorption as well as IR and Raman spectra. The blue-shifting of the C-C stretching wavenumber reveals that the vinyl group is actively involved in the conjugation path. The NBO analysis confirms the occurrence of intramolecular hyperconjugative interactions resulting in ICT causing stabilization of the system. Copyright © 2013 Elsevier B.V. All rights reserved.

  8. Sağlık Kurumlarında Çalışanların Kurumda Kalma ya da Ayrılma Kararlarının Belirlenmesinde Örgütsel Bağlılığın Etkisi: İzmir İlinde Bir Araştırma

    Directory of Open Access Journals (Sweden)

    Suna AKÇA

    2017-12-01

    Full Text Available Sağlık hizmetlerinde hastalara güvenli ve kaliteli sağlık hizmeti sunmak kadar sağlık hizmet sunucularının memnuniyeti ve kuruma bağlılıkları da o kadar önemlidir. Daha verimli ve performansı yüksek çalışmayı amaç edinen sağlık kurum ve kuruluşları, çalışanlarının örgütsel bağlılıklarını artırmak için çeşitli politikalar geliştirmek zorundadırlar. Bu çalışma İzmir’de bulunan bir kamu diş merkezinde sağlık çalışanlarının örgütsel bağlılıkları ve işten ayrılma eğilimleri arasındaki ilişkiyi test etmek için yapılmıştır. Araştırma konularının arasındaki ilişkiyi test etmek için Allen ve Mayer tarafından geliştirilen “Örgütsel Bağlılık Ölçeği” kullanılmıştır. Araştırma sonuçları; sağlık çalışanlarının örgütsel bağlılıklarının düzeylerinin düşük olduğuna, örgütsel bağlılık faktörleri arasında pozitif bir ilişkinin mevcut olduğuna ve işten ayrılma düzeyleri ile negatif orantı gösterdiğine işaret etmektedir. Anahtar Kelimeler: Sağlık Kurumları, Örgütsel Bağlılık, İşten Ayrılma JEL Sınıflandırma Kodları: I19, M19

  9. Numerical analysis of air effect on the powder flow dynamics in the FT4 Powder Rheometer

    Directory of Open Access Journals (Sweden)

    Nan Wenguang

    2017-01-01

    Full Text Available The FT4 powder rheometer of Freeman Technology is widely used nowadays in industry for characterisation of particle flow under dynamic conditions of shear strain rate. It measures the work (termed flow energy required to penetrate a rotating impeller into a powder bed. However, little is known about its underlying powder mechanics, i.e. the relationship between the flow energy and the prevailing local shear stress. This has recently been studied, but only for very simple and ideal systems amenable to analysis by DEM. We analyse the effect of gas flow through the powder bed on the flow behaviour of cohesionless particles in FT4 by DEM-CFD simulation. The results show that the relative particle velocities induced by the mean shear speed, is of the same order as that produced by the root of granular temperature. The shear stress in both cases with and without gas flow could be quantified by the inertial number. The flow energy correlates well with the shear stress in front of the blade, and both increase with the inertial number and could be significantly reduced by the upward gas flow.

  10. Rapid identification of Chinese Sauce liquor from different fermentation positions with FT-IR spectroscopy

    Science.gov (United States)

    Li, Changwen; Wei, Jiping; Zhou, Qun; Sun, Suqin

    2008-07-01

    FT-IR and two-dimensional correlation spectroscopy (2D-IR) technology were applied to discriminate Chinese Sauce liquor from different fermentation positions (top, middle and bottom of fermentation cellar) for the first time. The liquors at top, middle and bottom of fermentation cellar, possessed the characteristic peaks at 1731 cm -1, 1733 cm -1 and 1602 cm -1, respectively. In the 2D correlation infrared spectra, the differences were amplified. A strong auto-peak at 1725 cm -1 showed in the 2D spectra of the Top Liquor, which indicated that the liquor might contain some ester compounds. Different from Top Liquor, three auto-peaks at 1695, 1590 and 1480 cm -1 were identified in 2D spectra of Middle Liquor, which were the characteristic absorption of acid, lactate. In 2D spectra of Bottom Liquor, two auto-peaks at 1570 and 1485 cm -1 indicated that lactate was the major component. As a result, FT-IR and 2D-IR correlation spectra technology provided a rapid and effective method for the quality analysis of the Sauce liquor.

  11. Metabolomic screening using ESI-FT MS identifies potential radiation-responsive molecules in mouse urine

    International Nuclear Information System (INIS)

    Iizuka, Daisuke; Yoshioka, Susumu; Kawai, Hidehiko; Izumi, Shunsuke; Suzuki, Fumio; Kamiya, Kenji

    2017-01-01

    The demand for establishment of high-throughput biodosimetric methods is increasing. Our aim in this study was to identify low-molecular-weight urinary radiation-responsive molecules using electrospray ionization Fourier transform mass spectrometry (ESI-FT MS), and our final goal was to develop a sensitive biodosimetry technique that can be applied in the early triage of a radiation emergency medical system. We identified nine metabolites by statistical comparison of mouse urine before and 8 h after irradiation. Time-course analysis showed that, of these metabolites, thymidine and either thymine or imidazoleacetic acid were significantly increased dose-dependently 8 h after radiation exposure; these molecules have already been reported as potential radiation biomarkers. Phenyl glucuronide was significantly decreased 8 h after radiation exposure, irrespective of the dose. Histamine and 1-methylhistamine were newly identified by MS/MS and showed significant, dose-dependent increases 72 h after irradiation. Quantification of 1-methylhistamine by enzyme-linked immunosorbent assay (ELISA) analysis also showed a significant increase 72 h after 4 Gy irradiation. These results suggest that urinary metabolomics screening using ESI-FT MS can be a powerful tool for identifying promising radiation-responsive molecules, and that urinary 1-methylhistamine is a potential radiation-responsive molecule for acute, high-dose exposure.

  12. Chemical characterization of synthetic cannabinoids by electrospray ionization FT-ICR mass spectrometry.

    Science.gov (United States)

    Kill, Jade B; Oliveira, Izabela F; Tose, Lilian V; Costa, Helber B; Kuster, Ricardo M; Machado, Leandro F; Correia, Radigya M; Rodrigues, Rayza R T; Vasconcellos, Géssica A; Vaz, Boniek G; Romão, Wanderson

    2016-09-01

    The synthetic cannabinoids (SCs) represent the most recent advent of the new psychotropic substances (NPS) and has become popularly known to mitigate the effects of the Δ(9)-THC. The SCs are dissolved in organic solvents and sprayed in a dry herbal blend. However, little information is reported on active ingredients of SCs as well as the excipients or diluents added to the herbal blend. In this work, the direct infusion electrospray ionization Fourier transform ion cyclotron mass spectrometry technique (ESI-FT-ICR MS) was applied to explore the chemical composition of nine samples of herbal extract blends, where a total of 11 SCs (UR-144, JWH-073, XLR-11, JWH-250, JWH-122, AM-2201, AKB48, JWH-210, JWH-081, MAM-2201 and 5F-AKB48) were identified in the positive ionization mode, ESI(+), and other 44 chemical species (saturated and unsaturated fatty acids, sugars, flavonoids, etc.) were detected in the negative ionization mode, ESI(-). Additionally, CID experiments were performed, and fragmentation pathways were proposed to identify the connectivity of SCs. Thus, the direct infusion ESI-FT-ICR MS technique is a powerful tool in forensic chemistry that enables the rapid and unequivocal way for the determination of molecular formula, the degree of unsaturation (DBE-double bond equivalent) and exact mass (<1ppm) of a total of 55 chemical species without the prior separation step. Copyright © 2016 Elsevier Ireland Ltd. All rights reserved.

  13. Application of FT NIR Spectroscopy in the Determination of Basic Physical and Chemical Properties of Sausages

    Directory of Open Access Journals (Sweden)

    Zuzana Procházková

    2010-01-01

    Full Text Available The objectives of this study were to develop calibration models for determination of water activity and the content of fat, dry matter, salt, non collagen muscle protein and pH in dry cooked sausages. Samples (n = 42 were scanned in FT-NIR Analyzer and simultaneously analyzed by standard methods. The spectra were measured in the reflectance mode with a compressive cell between 10 000 and 4 000 cm-1, averaging 100 scans. Calibration models were developed using the partial least squares (PLS method. These calibration models were checked later by crossvalidation. The following statistical values were obtained: R (correlation coefficient = 0.997 and SEC (standard error of calibration = 0.002 for water activity, R = 0.966 and SEC = 0.023 for pH, R = 0.995 and SEC = 0.970 for dry matter content, R = 0.995 and SEC = 0.045 for salt content, R = 0.965 and SEC = 0.652 for non collagen muscle protein, R = 0.996 and SEC = 0.559 for fat content. The results of the study showed that FT-NIR is a suitable method for rapid analysis of physical and chemical properties of sausages.

  14. Physicochemical characterization of Lavandula spp. honey with FT-Raman spectroscopy.

    Science.gov (United States)

    Anjos, Ofélia; Santos, António J A; Paixão, Vasco; Estevinho, Letícia M

    2018-02-01

    This study aimed to evaluate the potential of FT-Raman spectroscopy in the prediction of the chemical composition of Lavandula spp. monofloral honey. Partial Least Squares (PLS) regression models were performed for the quantitative estimation and the results were correlated with those obtained using reference methods. Good calibration models were obtained for electrical conductivity, ash, total acidity, pH, reducing sugars, hydroxymethylfurfural (HMF), proline, diastase index, apparent sucrose, total flavonoids content and total phenol content. On the other hand, the model was less accurate for pH determination. The calibration models had high r 2 (ranging between 92.8% and 99.9%), high residual prediction deviation - RPD (ranging between 4.2 and 26.8) and low root mean square errors. These results confirm the hypothesis that FT-Raman is a useful technique for the quality control and chemical properties' evaluation of Lavandula spp honey. Its application may allow improving the efficiency, speed and cost of the current laboratory analysis. Copyright © 2017 Elsevier B.V. All rights reserved.

  15. Determination of the Mechanical Properties of Rubber by FT-NIR

    Directory of Open Access Journals (Sweden)

    Rattapol Pornprasit

    2016-01-01

    Full Text Available Mechanical tests, for example, tensile and hardness tests, are usually used to evaluate the properties of rubber materials. In this work, mechanical properties of selected rubber materials, that is, natural rubber (NR, styrene butadiene rubber (SBR, nitrile butadiene rubber (NBR, and ethylene propylene diene monomer (EPDM, were evaluated using a near infrared (NIR spectroscopy technique. Here, NR/NBR and NR/EPDM blends were first prepared. All of the samples were then scanned using a FT-NIR spectrometer and fitted with an integration sphere working in a diffused reflectance mode. The spectra were correlated with hardness and tensile properties. Partial least square (PLS calibration models were built from the spectra datasets with preprocessing techniques, that is, smoothing and second derivative. This indicated that reasonably accurate models, that is, with a coefficient of determination [R2] of the validation greater than 0.9, could be achieved for the hardness and tensile properties of rubber materials. This study demonstrated that FT-NIR analysis can be applied to determine hardness and tensile values in rubbers and rubber blends effectively.

  16. Chemical fingerprinting of Arabidopsis using Fourier transform infrared (FT-IR) spectroscopic approaches.

    Science.gov (United States)

    Gorzsás, András; Sundberg, Björn

    2014-01-01

    Fourier transform infrared (FT-IR) spectroscopy is a fast, sensitive, inexpensive, and nondestructive technique for chemical profiling of plant materials. In this chapter we discuss the instrumental setup, the basic principles of analysis, and the possibilities for and limitations of obtaining qualitative and semiquantitative information by FT-IR spectroscopy. We provide detailed protocols for four fully customizable techniques: (1) Diffuse Reflectance Infrared Fourier Transform Spectroscopy (DRIFTS): a sensitive and high-throughput technique for powders; (2) attenuated total reflectance (ATR) spectroscopy: a technique that requires no sample preparation and can be used for solid samples as well as for cell cultures; (3) microspectroscopy using a single element (SE) detector: a technique used for analyzing sections at low spatial resolution; and (4) microspectroscopy using a focal plane array (FPA) detector: a technique for rapid chemical profiling of plant sections at cellular resolution. Sample preparation, measurement, and data analysis steps are listed for each of the techniques to help the user collect the best quality spectra and prepare them for subsequent multivariate analysis.

  17. Study of Car Acceleration and Deceleration Characteristics at Dangerous Route FT050

    Science.gov (United States)

    Omar, N.; Prasetijo, J.; Daniel, B. D.; Abdullah, M. A. E.; Ismail, I.

    2018-04-01

    Individual vehicle acceleration and deceleration are important to generate vehicles speed profile. This study covered acceleration and deceleration characteristics of passenger car in Federal Route FT050 Jalan Batu Pahat-Ayer Hitam that was the top ranking dangerous road. Global Positioning System was used to record 10 cars speed to develop speed profile with clustering zone. At the acceleration manoeuver, the acceleration rate becomes lower as the drivers get near to desired speed. While, at deceleration manoeuver, vehicles with high speed needs more time to stop compare to low speed vehicle. This is because, the drivers need to accelerate more from zero speed to achieve desired speed and drivers need more distance and time to stop their vehicles. However, it was found out that 30% to 50% are driving in dangerous condition that was proven in clustering acceleration and deceleration speed profile. As conclusion, this excessive drivers are the factor that creating high risk in rear-end collision that inline FT050 as dangerous road in Malaysia

  18. Modelling of SOEC-FT reactor: Pressure effects on methanation process

    International Nuclear Information System (INIS)

    Chen, Bin; Xu, Haoran; Ni, Meng

    2017-01-01

    Highlights: • Numerical study on combined SOEC-FT reactor in pressurized condition. • Effects of operating pressure on co-electrolysis and CH_4 production are studied. • The lower limit temperature of the FT section is dependent on the operating pressure. • The CH_4 production can be improved at higher voltage due to the current increase. • Effects of higher exchange current density is predicted at different temperature. - Abstract: In this paper a numerical model is developed for a novel reactor combining a Solid Oxide Electrolyzer Cell (SOEC) section with a Fischer Tropsch like section for methane production under pressurized & temperature-gradient condition. Governing equations for mass, momentum, charge transport are solved with Finite Element Method. The chemical reaction kinetics of reversible water gas shift reaction and reversible methanation reaction in Ni/YSZ cathode are fully considered. The model is validated by comparing simulation results with experimental data. Parametric simulations are conducted to understand the physical-chemical processes in the reactor with a focus on the pressure effect. It is predicted that the optimal operating pressure is around 3 bar, beyond which the CH_4 conversion ratio (2.5 times enhanced than 1 bar operating) cannot be further increased. It is also found that it is feasible to operate the pressurized SOEC at a lower temperature for CH_4 production with improved catalyst activity.

  19. Identification of Reactive and Refractory Components of Dissolved Organic Nitrogen by FT-ICR Mass Spectrometry

    Science.gov (United States)

    Cooper, W. T.; Podgorski, D. C.; Osborne, D. M.; Corbett, J.; Chanton, J.

    2010-12-01

    Dissolved organic nitrogen is an often overlooked but potentially significant bioavailable component of dissolved organic matter. Studies of bulk DON turnover have been reported, but the compositions of the reactive and refractory components of DON are largely unknown. Here we show the unique ability of atmospheric pressure photoionization (APPI) coupled to ultrahigh resolution mass spectrometry to identify the reactive and refractory components of DON. Figure 1 is an isolated 0.30 m/z window from an ultrahigh resolution APPI FT-ICR mass spectrum of DON in surface waters draining an agricultural area in South Florida. Using this optimized, negative-ion APPI strategy we have been able to identify the reactive and refractory components of DON in these nitrogen-rich waters. Similar results were observed with samples from soil porewaters in sedge-dominated fens and sphagnum-dominated bogs within the Glacial Lake Agassiz Peatlands (GLAP) of northern Minnesota. Surprisingly, microbes appear to initially use similar enzymatic pathways to degrade DON and DOC, often with little release of nitrogen. Figure 1. Isolated 0.30 m/z window at nominal mass 432 from negative-ion APPI FT-ICR mass spectrum of DOM from waters draining an agricultural area in South Florida. Peaks marked contain nitrogen.

  20. FT-IR and X-ray spectroscopic investigations of Na-diclofenac-cyclodextrins interactions

    Science.gov (United States)

    Bratu, I.; Astilean, S.; Ionesc, Corina; Indrea, E.; Huvenne, J. P.; Legrand, P.

    1998-01-01

    The association of DCF-Na (the salt of the 2-[(2,6-dichlorophenyl)amino]-phenyl-acetic acid) with β-CD (cyclodextrin) in some therapeutic formulas can contribute to the optimisation of the physico-chemical and pharmaceutical properties of the parent drug. The understanding of the interaction between DCF with β-CD represents the objective of this study. FT-IR spectroscopy is one of the methods which clarify the nature of these interactions in complexes of such type. Therefore the changes in FT-IR spectra of binary dispersed systems DCF/ β-CD in physical mixture and coprecipitate from methanol (molar ratios: 1/1, 1/2, 2/3, 3/4, 7/4) were analysed. The analysis of the broadening of the X-ray powder diffraction line has been applied to investigate the average effective crystallite size, the mean square of the microstrain caused by distortions within β-CD crystallite and the fault probability in the binary dispersed DCF/ β-CD coprecipitate system.

  1. Human and Bovine Dentin Composition and Its Hybridization Mechanism Assessed by FT-Raman Spectroscopy

    Directory of Open Access Journals (Sweden)

    L. E. S. Soares

    2013-01-01

    Full Text Available FT-Raman spectroscopy was used to study the human and bovine dentin and their interactions with adhesive systems. Ten human (H molars and ten bovine (B teeth were prepared exposing the dentin and then each specimen was divided into two parts. The resulted forty dentin segments were treated either with the total-etch one bottle adhesive (Prime & Bond 2.1, PB or with the single-step self-etching adhesive (Xeno III, X and divided into four groups: HPB (control, HX, BPB, and BX. Each group was analyzed by FT-Raman spectroscopy before and after the adhesive treatment. Six regions of the Raman spectrum were analyzed and the integrated areas of organic and inorganic peaks were calculated. Bovine untreated specimens showed higher peak area of PO4 3−ν2  content than in human specimens. Human untreated specimens had higher peak areas of PO4 3−ν4 and CO3 2−ν1  contents than in bovine specimens. The peak areas of amide III, CH2, and amide I contents were higher in human than in bovine specimens (before treatments. Treated dentin showed no significant statistical differences between the adhesives for both inorganic and organic contents considering the same substrate. However, the differences found between human and bovine specimens after adhesives application show a reduced accuracy of these substrates as a substitute to the human specimens.

  2. Intramolecular hydrogen bonding in N-salicylideneaniline: FT-IR spectrum and quantum chemical calculations

    Science.gov (United States)

    Moosavi-Tekyeh, Zainab; Dastani, Najmeh

    2015-12-01

    FT-IR and FT-Raman spectra of N-salicylideneaniline (SAn) and its deuterated analogue (D-SAn) are recorded, and the theoretical calculations are performed on their molecular structures and vibrational frequencies. The same calculations are performed for SAn in different solutions using the polarizable conductor continuum model (CPCM) method. Comparisons between the spectra obtained and the corresponding theoretical calculations are used to assign the vibrational frequencies for these compounds. The spectral behavior of SAn upon deuteration is also used to distinguish the positions of OH vibrational frequencies. The hydrogen bond strength of SAn is investigated by applying the atoms-in-molecules (AIM) theory, natural bond orbital (NBO) analysis, and geometry calculations. The harmonic vibrational frequencies of SAn are calculated at B3LYP and X3LYP levels of theory using 6-31G*, 6-311G**, and 6-311++G** basis sets. The AIM results support a medium hydrogen bonding in SAn. The observed νOH/νOD and γOH/γOD for SAn appear at 2940/2122 and 830/589 cm-1, respectively.

  3. FT-IR emissivity measurements of Nb melt using an electrostatic levitation furnace

    International Nuclear Information System (INIS)

    Sakata, K.; Watanabe, Y.; Okada, J.T.; Kumar, M.V.; Paradis, P.-F.; Ishikawa, T.

    2015-01-01

    Highlights: • Since molten Nb has a high melting point, its thermal properties were measured using FT-IR combined with an electrostatic levitator. • The measured ε_T of molten Nb at the melting temperature in this study was 0.29, and the C_p was calculated as 41.9 J ⋅ mol"−"1 ⋅ K"−"1. - Abstract: Total hemispherical emissivity (ε_T) and constant pressure heat capacity (C_p) of molten Nb, which has a high melting point, was measured using FT-IR combined with an electrostatic levitator. In order to heat the sample to temperatures higher than 2000 °C and avoid chemical reactions between the sample and a crucible, a containerless method was needed. By applying these methods, the measured ε_T of molten Nb at the melting temperature was 0.29, and the C_p was calculated as 41.9 J ⋅ mol"−"1 ⋅ K"−"1. Both data showed good agreement with the literature values. In addition, the result was compared with the Drude model and the difference of emissivity between Zr and Nb was discussed.

  4. Development of a method for determination of fatty acid using FT-IR spectroscopy

    Directory of Open Access Journals (Sweden)

    Dimas Augusto Morozin Zaia

    2011-05-01

    Full Text Available In the present paper a new methodology has been developed for determination of fatty acids in biological systems using FT-IR spectroscopy. For this method is not necessary chromophore reagent or pre sample preparation. Palmitic acid was chosen as standard, because it is found in several biological systems. The FT-IR spectrum of palmitic acid showed two absorption bands in the region of 2852 and 2920 cm-1 attributed to CH stretching. The results for these bands showed that the Beer-Lambert Law was followed in wide range of concentration of palmitic acid (14 to 257 mmol L-1. Potassium ferricyanide (K3[Fe(CN6] was used as internal standard. Several interferents were tested and only cholesterol, ferric chloride (higher concentration, mixture of amino acids for the band at 2919 cm-1 (higher concentration and triglyceride could be interferent if they appear in high concentration. Thus, this new methodology has advantage to be not expensive and simple.

  5. FT-IR microspectroscopy characterization of supports for enzyme immobilization in biosensing applications

    Science.gov (United States)

    Portaccio, M.; Della Ventura, B.; Gabrovska, K.; Marinov, I.; Godjevargova, T.; Mita, D. G.; Lepore, M.

    2010-04-01

    The investigation of materials suitable for enzyme immobilization in biosensing applications has a widespread interest. There are many studies on physico-chemical properties of these materials at macroscopic level but few studies have been devoted to examine and correlate these properties at microscopic level. FT-IR spectroscopy with Micro-Attenuated Total Reflection (Micro-ATR) approach can be extremely useful for understanding a variety of aspects of materials which can be used for optimising immobilization procedures. Moreover, this experimental approach is particularly simple to use (no sample preparation is required) and minimally invasive. Using a Perkin Elmer Spectrum One FT-IR spectrometer equipped with a mercury-cadmium-telluride detector and a micro-ATR element we investigated different materials used for immobilization procedures with various enzymes widely used for biosensing in environmental and clinical applications. In particular, composite membranes constituted by a chemically modified poly-acrylonitrile (PAN) membrane plus layers of tethered chitosan of different molecular weight have been examined. Also silica gel matrices without and with glucose oxidase have been investigated. Spectra have been analysed and the contribution of principal functional groups has been evidenced.

  6. Studies oriented to optimize the image quality of the small animal PET: Clear PET, modifying some of the parameters of the reconstruction algorithm IMF-OSEM 3D on the data acquisition simulated with GAMOS

    International Nuclear Information System (INIS)

    Canadas, M.; Mendoza, J.; Embid, M.

    2007-01-01

    This report presents studies oriented to optimize the image quality of the small animal PET: Clear- PET. Certain figures of merit (FOM) were used to assess a quantitative value of the contrast and delectability of lesions. The optimization was carried out modifying some of the parameters in the reconstruction software of the scanner, imaging a mini-Derenzo phantom and a cylinder phantom with background activity and two hot spheres. Specifically, it was evaluated the incidence of the inter-update Metz filter (IMF) inside the iterative reconstruction algorithm 3D OSEM. The data acquisition was simulated using the GAMOS framework (Monte Carlo simulation). Integrating GAMOS output with the reconstruction software of the scanner was an additional novelty of this work, to achieve this, data sets were written with the list-mode format (LMF) of ClearPET. In order to verify the optimum values obtained, we foresee to make real acquisitions in the ClearPET of CIEMAT. (Author) 17 refs

  7. The Cloning and Functional Characterization of Peach CONSTANS and FLOWERING LOCUS T Homologous Genes PpCO and PpFT.

    Directory of Open Access Journals (Sweden)

    Xiang Zhang

    Full Text Available Flowering is an essential stage of plant growth and development. The successful transition to flowering not only ensures the completion of plant life cycles, it also serves as the basis for the production of economically important seeds and fruits. CONSTANS (CO and FLOWERING LOCUS T (FT are two genes playing critical roles in flowering time control in Arabidopsis. Through homology-based cloning and rapid-amplifications of cDNA ends (RACE, we obtained full-lengths cDNA sequences of Prunus persica CO (PpCO and Prunus persica FT (PpFT from peach (Prunus persica (L. Batsch and investigated their functions in flowering time regulation. PpCO and PpFT showed high homologies to Arabidopsis CO and FT at DNA, mRNA and protein levels. We showed that PpCO and PpFT were nucleus-localized and both showed transcriptional activation activities in yeast cells, consistent with their potential roles as transcription activators. Moreover, we established that the over-expression of PpCO could restore the late flowering phenotype of the Arabidopsis co-2 mutant, and the late flowering defect of the Arabidopsis ft-1 mutant can be rescued by the over-expression of PpFT, suggesting functional conservations of CO and FT genes in peach and Arabidopsis. Our results suggest that PpCO and PpFT are homologous genes of CO and FT in peach and they may function in regulating plant flowering time.

  8. CRISPR/Cas9-mediated targeted mutagenesis of GmFT2a delays flowering time in soya bean.

    Science.gov (United States)

    Cai, Yupeng; Chen, Li; Liu, Xiujie; Guo, Chen; Sun, Shi; Wu, Cunxiang; Jiang, Bingjun; Han, Tianfu; Hou, Wensheng

    2018-01-01

    Flowering is an indication of the transition from vegetative growth to reproductive growth and has considerable effects on the life cycle of soya bean (Glycine max). In this study, we employed the CRISPR/Cas9 system to specifically induce targeted mutagenesis of GmFT2a, an integrator in the photoperiod flowering pathway in soya bean. The soya bean cultivar Jack was transformed with three sgRNA/Cas9 vectors targeting different sites of endogenous GmFT2a via Agrobacterium tumefaciens-mediated transformation. Site-directed mutations were observed at all targeted sites by DNA sequencing analysis. T1-generation soya bean plants homozygous for null alleles of GmFT2a frameshift mutated by a 1-bp insertion or short deletion exhibited late flowering under natural conditions (summer) in Beijing, China (N39°58', E116°20'). We also found that the targeted mutagenesis was stably heritable in the following T2 generation, and the homozygous GmFT2a mutants exhibited late flowering under both long-day and short-day conditions. We identified some 'transgene-clean' soya bean plants that were homozygous for null alleles of endogenous GmFT2a and without any transgenic element from the T1 and T2 generations. These 'transgene-clean' mutants of GmFT2a may provide materials for more in-depth research of GmFT2a functions and the molecular mechanism of photoperiod responses in soya bean. They will also contribute to soya bean breeding and regional introduction. © 2017 The Authors. Plant Biotechnology Journal published by Society for Experimental Biology and The Association of Applied Biologists and John Wiley & Sons Ltd.

  9. Studies oriented to optimize the image quality of the small animal PET: Clear PET, modifying some of the parameters of the reconstruction algorithm IMF-OSEM 3D on the data acquisition simulated with GAMOS; Estudios para la optimizaciOn de la calidad de imagen en el escaner ClearPET, modifi cando parametros del algoritmo IMF-OSEM 3D sobre adquisiciones simuladas con GAMOS

    Energy Technology Data Exchange (ETDEWEB)

    Canadas, M.; Mendoza, J.; Embid, M.

    2007-09-27

    This report presents studies oriented to optimize the image quality of the small animal PET: Clear- PET. Certain figures of merit (FOM) were used to assess a quantitative value of the contrast and delectability of lesions. The optimization was carried out modifying some of the parameters in the reconstruction software of the scanner, imaging a mini-Derenzo phantom and a cylinder phantom with background activity and two hot spheres. Specifically, it was evaluated the incidence of the inter-update Metz filter (IMF) inside the iterative reconstruction algorithm 3D OSEM. The data acquisition was simulated using the GAMOS framework (Monte Carlo simulation). Integrating GAMOS output with the reconstruction software of the scanner was an additional novelty of this work, to achieve this, data sets were written with the list-mode format (LMF) of ClearPET. In order to verify the optimum values obtained, we foresee to make real acquisitions in the ClearPET of CIEMAT. (Author) 17 refs.

  10. Life Cycle Analysis of the Production of FT-Fuels. 4 Different Scenarios

    Energy Technology Data Exchange (ETDEWEB)

    Blinge, M. [Chalmers University of Technology (Sweden); Rehnlund, B. [Atrax Energi AB (Sweden); Larsen, U.; Lundorf, P.; Ivarsson, A.; Schramm, J. [Technical University of Denmark (Denmark)

    2006-11-15

    This paper deals with aspects concerning the life cycle aspects regarding Fischer-Tropsch (FT) fuels. Four different scenarios are being analysed based on Life Cycle Assessment (LCA) figures. The results etc presented below emanates from a project undertaken by the International Energy Agency's (IEA) Implementing Agreement on Advanced Motor Fuels (IEA/AMF). The project has been carried out as an IEA/AMF annex, number XXXI, with financial support from the USA, Finland and Denmark. Some important results from the scenario studies based on the evaluated LCA data are: Production and use of GTL fuel has the potential of contributing about the same or slightly less greenhouse gas to the atmosphere than production and use of conventional diesel; Production and use of CTL emits more than twice as much greenhouse gases compared to traditional fuels; Production and use of BTL reduces the emissions of greenhouse gases by 60-90 %; To substitute 15 % of the EU 15 countries fuel consumption would an area of 310 000 km2 be cultivated with Salix. This corresponds to an area of the size of Poland. It would also require 122 FTplants of 1,6 GW; Theoretically, it is possible supply the worlds need for energy with biomass. However, planning the production, the localization of plants, building the infrastructure, this will take time and requires heavy long-term investments; The demand for Natural gas is increasing and there is no way for the US to meet an increased demand from supplying the vehicle fleet with F-T fuels from domestic reserves. With the political situation in the Middle East and in Venezuela, it doesn't seem likely that this solution will ease the US problems with reducing their oil dependences. The IEA/AMF project has also included emission tests on road vehicles fuelled by FT-Gasoline. These tests have been performed by The Technical University of Denmark and will be presented in another presentation at the ISAF XVI, 'Emissions from Road Vehicles Fuelled

  11. Reconstruction from scalar-tensor theory and the inhomogeneous equation of state in f(T) gravity

    Energy Technology Data Exchange (ETDEWEB)

    Said, Jackson Levi [University of Malta, Institute of Space Sciences and Astronomy, Msida (Malta); University of Malta, Department of Physics, Msida (Malta)

    2017-12-15

    General relativity (GR) characterizes gravity as a geometric properly exhibited as curvature on spacetime. Teleparallelism describes gravity through torsional properties, and can reproduce GR at the level of equations. Similar to f(R) gravity, on taking a generalization, f(T) gravity can produce various modifications its gravitational mechanism. The resulting field equations are inherently distinct to f(R) gravity in that they are second order. In the present work, f(T) gravity is examined in the cosmological context with a number of solutions reconstructed by means of an auxiliary scalar field. To do this, various forms of the Hubble parameter are considered with an f(T) Lagrangian emerging for each instance. In addition, the inhomogeneous equation of state (EoS) is investigated with a particular Hubble parameter model used to show how this can be used to reconstruct the f(T) Lagrangian. Observationally, the auxiliary scalar field and the exotic terms in the FRW field equations give the same results, meaning that the variation in the Hubble parameter may be interpreted as the need to reformulate gravity in some way, as in f(T) gravity. (orig.)

  12. Non-destructive technique for determining the viability of soybean (Glycine max) seeds using FT-NIR spectroscopy.

    Science.gov (United States)

    Kusumaningrum, Dewi; Lee, Hoonsoo; Lohumi, Santosh; Mo, Changyeun; Kim, Moon S; Cho, Byoung-Kwan

    2018-03-01

    The viability of seeds is important for determining their quality. A high-quality seed is one that has a high capability of germination that is necessary to ensure high productivity. Hence, developing technology for the detection of seed viability is a high priority in agriculture. Fourier transform near-infrared (FT-NIR) spectroscopy is one of the most popular devices among other vibrational spectroscopies. This study aims to use FT-NIR spectroscopy to determine the viability of soybean seeds. Viable and artificial ageing seeds as non-viable soybeans were used in this research. The FT-NIR spectra of soybean seeds were collected and analysed using a partial least-squares discriminant analysis (PLS-DA) to classify viable and non-viable soybean seeds. Moreover, the variable importance in projection (VIP) method for variable selection combined with the PLS-DA was employed. The most effective wavelengths were selected by the VIP method, which selected 146 optimal variables from the full set of 1557 variables. The results demonstrated that the FT-NIR spectral analysis with the PLS-DA method that uses all variables or the selected variables showed good performance based on the high value of prediction accuracy for soybean viability with an accuracy close to 100%. Hence, FT-NIR techniques with a chemometric analysis have the potential for rapidly measuring soybean seed viability. © 2017 Society of Chemical Industry. © 2017 Society of Chemical Industry.

  13. Reconstruction from scalar-tensor theory and the inhomogeneous equation of state in f(T) gravity

    International Nuclear Information System (INIS)

    Said, Jackson Levi

    2017-01-01

    General relativity (GR) characterizes gravity as a geometric properly exhibited as curvature on spacetime. Teleparallelism describes gravity through torsional properties, and can reproduce GR at the level of equations. Similar to f(R) gravity, on taking a generalization, f(T) gravity can produce various modifications its gravitational mechanism. The resulting field equations are inherently distinct to f(R) gravity in that they are second order. In the present work, f(T) gravity is examined in the cosmological context with a number of solutions reconstructed by means of an auxiliary scalar field. To do this, various forms of the Hubble parameter are considered with an f(T) Lagrangian emerging for each instance. In addition, the inhomogeneous equation of state (EoS) is investigated with a particular Hubble parameter model used to show how this can be used to reconstruct the f(T) Lagrangian. Observationally, the auxiliary scalar field and the exotic terms in the FRW field equations give the same results, meaning that the variation in the Hubble parameter may be interpreted as the need to reformulate gravity in some way, as in f(T) gravity. (orig.)

  14. İş Özellikleri, İş-Yaşam Dengesi ve Meslekten Ayrılma Niyeti Arasındaki İlişkilerin Aday Öğretmen Görüşlerine Göre İncelenmesi

    OpenAIRE

    Polat, Şule; Özdemir, Murat

    2017-01-01

    Bu araştırmada aday öğretmenlerin görüşlerine bağlı olarak öğretmenlik mesleği iş özellikleri, iş yaşam dengesi ve meslekten ayrılma niyeti arasındaki ilişki incelenmiştir. Araştırmanın çalışma grubunu, 2016-2017 eğitim öğretim yılının birinci döneminde Ankara ilinin dokuz ilçesindeki (Çankaya, Mamak, Altındağ, Keçiören, Yenimahalle, Sincan, Etimesgut, Gölbaşı ve Pursaklar) resmi ortaöğretim kurumlarında görev yapan 225 aday öğretmen oluşturmaktadır. Araştırma verileri “Öğretmenlik Mesleği İş...

  15. Konaklama İşletmelerinde Örgütsel Öğrenme, Örgütsel Bağlılık ve İşten Ayrılma Eğilimi Arasındaki İlişki

    OpenAIRE

    AVCI, Nilgün; KÜÇÜKUSTA, Deniz

    2009-01-01

    Çalışmanın amacı, konaklama işletmelerinde örgütsel öğrenmenin, örgütsel bağlılık ve işten ayrılma eğilimi üzerindeki etkilerini analiz etmektir. Çeşme'de faaliyet gösteren 5 adet beş yıldızlı otel araştırmaya dahil edilmiştir. Alan araştırması kapsamında, literatürden elde edilen bilgiler ışığında oluşturulan yapılandırılmış anket tekniği kullanılmış, elde edilen veriler SPSS 13.0 (Statistical Program for Social Sciences) programı ile analiz edilmiştir. Çalışmada öncelikle geçerlik ve g...

  16. FT-IR microscopical analysis with synchrotron radiation: The microscope optics and system performance

    International Nuclear Information System (INIS)

    Reffner, J.A.; Martoglio, P.A.; Williams, G.P.

    1995-01-01

    When a Fourier transform infrared (FT-IR) microspectrometer was first interfaced with the National Synchrotron Light Source (NSLS) in September 1993, there was an instant realization that the performance at the diffraction limit had increased 40-100 times. The synchrotron source transformed the IR microspectrometer into a true IR microprobe, providing high-quality IR spectra for probe diameters at the diffraction limit. The combination of IR microspectroscopy and synchrotron radiation provides a powerful new tool for molecular spectroscopy. The ability to perform IR microspectroscopy with synchrotron radiation is still under development at Brookhaven National Laboratory, but several initial studies have been completed that demonstrate the broad-ranging applications of this technology and its potential for materials characterization

  17. FT-IR spectroscopic analyses of 2-(2-furanylmethylene) propanedinitrile

    Science.gov (United States)

    Soliman, H. S.; Eid, Kh. M.; Ali, H. A. M.; El-Mansy, M. A. M.; Atef, S. M.

    2013-03-01

    In the present work, a computational study for the optimized molecular structural parameters, thermo-chemical parameters, total dipole moment, HOMO-LUMO energy gap and a combined experimental and computational study for FT-IR spectra for 2-(2-furanylmethylene) propanedinitrile have been investigated using B3LYP utilizing 6-31G and 6-311G basis set. Our calculated results showed that the investigated compound possesses a dipole moment of 7.5 D and HOMO-LUMO energy gap of 3.92 eV using B3LYP/6-311G which indicates that our investigated compound is highly applicable for photovoltaic solar cell applications.

  18. ELITE II and Val-HeFT are different trials: together what do they tell us?

    Directory of Open Access Journals (Sweden)

    Dickstein Kenneth

    2001-09-01

    Full Text Available Abstract The Losartan Heart Failure Survival Study (ELITE II and the Valsartan Heart Failure Trial (Val-HeFT both evaluated the efficacy and tolerability of a selective angiotensin II receptor antagonist on morbidity and mortality in patients with symptomatic heart failure. The trials differed, however, in terms of their primary hypothesis, study design, and treatment regimens, and this must be taken into consideration when comparing and interpreting the data from these studies. The data are in many ways complementary, and add to our understanding of the optimal treatment of symptomatic heart failure. Additional studies are needed, however, to fully define the role of angiotensin II receptor antagonists in the management of this very heterogeneous group of patients.

  19. Analysis of pure and malachite green doped polysulfone sample using FT-IR technique

    Science.gov (United States)

    Nayak, Rashmi J.; Khare, P. K.; Nayak, J. G.

    2018-05-01

    The sample of pure and malachite green doped Polysulfone in the form of foil was prepared by isothermal immersion technique. For the preparation of pure sample 4 gm of Polysulfone was dissolved in 50 ml of Dimethyl farmamide (DMF) solvent, while for the preparation of doped sample 10 mg, 50 mg and 100 mg Malachite Green was mixed with 4 gm of Polysulfone respectively. For the study of structural characterization of these pure and doped sample, Fourier Transform Infra-Red Spectroscopy (FT-IR) technique was used. This study shows that the intensity of transmittance decreases as the ratio of doping increases in pure polysulfone. The reduction in intensity of transmittance is clearly apparent in the present case more over the bands were broader which indicates towards charge transfer interaction between the donar and acceptor molecule.

  20. Spectroelectrochemical study of polyphenylene by in situ external reflection FT-IR spectroscopy. Pt. 2

    International Nuclear Information System (INIS)

    Kvarnstroem, C.; Ivaska, A.

    1994-01-01

    In situ external reflection FT-IR measurements are performed during cyclic voltammetric scans on electrochemically polymerized polyphenylene films. The films are polymerized either in 0.1 or 0.8 M biphenyl in 0.1 M TBABF 4 in acetonitrile. Changes in the IR spectrum of films of different thicknesses are studied when the films are potentially cycled from the neutral to the oxidized states of the polymer. No differences between films made in high or low dimer concentration can be observed in the spectra. The potential-dependent insertion and expulsion of solvent, residual water, anions and cations in and out of the film have different behaviour in films of different thicknesses. Changes in the structure of the segments in the film, from the benzenoid form into the quinoid form, can be followed. Differences between the first and subsequent cyclic potential scans are observed. (orig.)

  1. SHF radiation of plasma and acceleration regime of a discharge in the Tokamak FT-1

    International Nuclear Information System (INIS)

    Larionov, M.M.; Levin, L.S.; Rozhdestvenskij, V.V.; Tokunov, A.I.

    1975-01-01

    It is studied the frequency spectrum of SHF radiation, hard X-radiation, diamagnetism, conductivity and density of plasma in high-temperature and accelerating regimes of the FT-1 tokamak. It is shown that the intensities of hard X-radiation and SHF radiation in an accelerating discharge are far more than in a high-temperature discharge. In the first case radiation temperature of the SHF range reaches 7 keV while in the second one it will be 7 eV. The difference in the radiations points to the diverse role of electron running-away. The total and transverse energies of run-away electrons are evaluated according to the X-ray energy and SHF radiation. The transverse energy of the run-away electrons is found to be 80 keV. This value permits interpretation of the observed plasma diamagnetism

  2. The Thomson scattering experiment pulsed by CO2 laser in FT

    International Nuclear Information System (INIS)

    Bartolini, L.; Fornetti, G.; Nardi, M.; Occhionero, G.; Ferri de Collibus, M.

    1987-01-01

    An experiment carried out to measure the plasma ion temperature Tsub(i) in the tokamak FT in Frascati by Collective Thomson Scattering. A tandem laser system generates two single mode beams (10.6μ) one of which is pulsed and amplified up to levels of 5 MW, 1μs and actively frequency locked to a second continuous wave low pressure CO 2 laser. The pulse beam crosses the plasma and the forward scattered light is collected at angles between 1 degrees centigrade and 1.6 degrees centigrade. An heterodyne technique in which the c.w. beam is the local oscillator is used to measure the Doppler enlarged spectral density of the signal. The experimental apparatus is described and the results are reported and discussed

  3. FT-IR microscopical analysis with synchrotron radiation: The microscope optics and system performance

    Energy Technology Data Exchange (ETDEWEB)

    Reffner, J.A.; Martoglio, P.A. [Spectra-Tech, Inc., Shelton, CT (United States); Williams, G.P. [Brookhaven National Lab., Upton, NY (United States)

    1995-01-01

    When a Fourier transform infrared (FT-IR) microspectrometer was first interfaced with the National Synchrotron Light Source (NSLS) in September 1993, there was an instant realization that the performance at the diffraction limit had increased 40-100 times. The synchrotron source transformed the IR microspectrometer into a true IR microprobe, providing high-quality IR spectra for probe diameters at the diffraction limit. The combination of IR microspectroscopy and synchrotron radiation provides a powerful new tool for molecular spectroscopy. The ability to perform IR microspectroscopy with synchrotron radiation is still under development at Brookhaven National Laboratory, but several initial studies have been completed that demonstrate the broad-ranging applications of this technology and its potential for materials characterization.

  4. Investigation of UV curing reaction of dicyclopentadienyl acrylate by FT-IR

    International Nuclear Information System (INIS)

    Lu Qiting; Hou Yibin

    1999-01-01

    Dicyclopentadienyl acrylate (DCPA) is characterized by low odor, low volatility, high flash point, low toxicity and low shrinkage on cure. Another advantage of DCPA is its insensitiveness to the inhibiting effect of oxygen. DCPA have wide industrial applications. It was used for the preparation of adhesives, UV-curable coatings and polymer concreted). The advantages of DCPA result from its particular structure. There are two unsaturated bonds, one acrylic double bond and one cyclic double bond, in each DCPA molecule. But, few reports on reaction behavior of the two type double bonds were issued up to date. In this paper, reaction behavior of the acrylic and the cyclic double bond of DCPA during and after LTV-curing were investigated by Fourier Transform-Infrared(FT-IR)

  5. Chemical composition and binary mixture of human urinary stones using FT-Raman spectroscopy method.

    Science.gov (United States)

    Selvaraju, R; Raja, A; Thiruppathi, G

    2013-10-01

    In the present study the human urinary stones were observed in their different chemical compositions of calcium oxalate monohydrate, calcium oxalate dihydrate, calcium phosphate, struvite (magnesium ammonium phosphate), uric acid, cystine, oxammite (ammonium oxalate monohydrate), natroxalate (sodium oxalate), glushinkite (magnesium oxalate dihydrate) and moolooite (copper oxalate) were analyzed using Fourier Transform-Raman (FT-Raman) spectroscopy. For the quantitative analysis, various human urinary stone samples are used for ratios calculation of binary mixtures compositions such as COM/COD, HAP/COD, HAP/COD, Uric acid/COM, uric acid/COD and uric acid/HAP. The calibration curve is used for further analysis of binary mixture of human urinary stones. For the binary mixture calculation the various intensities bands at 1462 cm(-1) (I(COM)), 1473 cm(-1) (I(COD)), 961 cm(-1) (I(HAP)) and 1282 cm(-1) (I(UA)) were used. Copyright © 2013 Elsevier B.V. All rights reserved.

  6. Analysis of cosmetic residues on a single human hair by ATR FT-IR microspectroscopy

    Science.gov (United States)

    Pienpinijtham, Prompong; Thammacharoen, Chuchaat; Naranitad, Suwimol; Ekgasit, Sanong

    2018-05-01

    In this work, ATR FT-IR spectra of single human hair and cosmetic residues on hair surface are successfully collected using a homemade dome-shaped Ge μIRE accessary installed on an infrared microscope. By collecting ATR spectra of hairs from the same person, the spectral patterns are identical and superimposed while different spectral features are observed from ATR spectra of hairs collected from different persons. The spectral differences depend on individual hair characteristics, chemical treatments, and cosmetics on hair surface. The "Contact-and-Collect" technique that transfers remarkable materials on the hair surface to the tip of the Ge μIRE enables an identification of cosmetics on a single hair. Moreover, the differences between un-split and split hairs are also studied in this report. These highly specific spectral features can be employed for unique identification or for differentiation of hairs based on the molecular structures of hairs and cosmetics on hairs.

  7. Data preprocessing methods of FT-NIR spectral data for the classification cooking oil

    Science.gov (United States)

    Ruah, Mas Ezatul Nadia Mohd; Rasaruddin, Nor Fazila; Fong, Sim Siong; Jaafar, Mohd Zuli

    2014-12-01

    This recent work describes the data pre-processing method of FT-NIR spectroscopy datasets of cooking oil and its quality parameters with chemometrics method. Pre-processing of near-infrared (NIR) spectral data has become an integral part of chemometrics modelling. Hence, this work is dedicated to investigate the utility and effectiveness of pre-processing algorithms namely row scaling, column scaling and single scaling process with Standard Normal Variate (SNV). The combinations of these scaling methods have impact on exploratory analysis and classification via Principle Component Analysis plot (PCA). The samples were divided into palm oil and non-palm cooking oil. The classification model was build using FT-NIR cooking oil spectra datasets in absorbance mode at the range of 4000cm-1-14000cm-1. Savitzky Golay derivative was applied before developing the classification model. Then, the data was separated into two sets which were training set and test set by using Duplex method. The number of each class was kept equal to 2/3 of the class that has the minimum number of sample. Then, the sample was employed t-statistic as variable selection method in order to select which variable is significant towards the classification models. The evaluation of data pre-processing were looking at value of modified silhouette width (mSW), PCA and also Percentage Correctly Classified (%CC). The results show that different data processing strategies resulting to substantial amount of model performances quality. The effects of several data pre-processing i.e. row scaling, column standardisation and single scaling process with Standard Normal Variate indicated by mSW and %CC. At two PCs model, all five classifier gave high %CC except Quadratic Distance Analysis.

  8. Characterization of Paracoccidioides brasiliensis by FT-IR spectroscopy and nanotechnology

    Science.gov (United States)

    Ferreira, Isabelle; Ferreira-Strixino, Juliana; Castilho, Maiara L.; Campos, Claudia B. L.; Tellez, Claudio; Raniero, Leandro

    2016-01-01

    Paracoccidioides brasiliensis, the etiological agent of paracoccidioidomycosis, is a dimorphic fungus existing as mycelia in the environment (or at 25 °C in vitro) and as yeast cells in the human host (or at 37 °C in vitro). Because mycological examination of lesions in patients frequently is unable to show the presence of the fungus and serological tests can misdiagnose the disease with other mycosis, the development of new approach's for molecular identification of P. brasiliensis spurges is needed. This study describes the use of a gold nanoprobe of a known gene sequence of P. brasiliensis as a molecular tool to identify P. brasiliensis by regular polymerase chain reaction (PCR) associated with a colorimetric methods. This approach is suitable for testing in remote areas because it does not require any further step than gene amplification, being safer and cheaper than electrophoresis methods. The proposed test showed a color change of the PCR reaction mixture from red to blue in negative samples, whereas the solution remains red in positive samples. We also performed a Fourier Transform Infrared (FT-IR) Spectroscopy analysis to characterize and compare the chemical composition between yeast and mycelia forms, which revealed biochemical differences between these two forms. The analysis of the spectra showed that differences were distributed in chemical bonds of proteins, lipids and carbohydrates. The most prominent difference between both forms was vibration modes related to 1,3-β-glucan usually found in mycelia and 1,3-α-glucan found in yeasts and also chitin forms. In this work, we introduce FT-IR as a new method suitable to reveal overall differences that biochemically distinguish each form of P. brasiliensis that could be additionally used to discriminate biochemical differences among a single form under distinct environmental conditions.

  9. Magnetic resonance imaging DTI-FT study on schizophrenic patients with typical negative first symptoms.

    Science.gov (United States)

    Gu, Chengyu; Zhang, Ying; Wei, Fuquan; Cheng, Yougen; Cao, Yulin; Hou, Hongtao

    2016-09-01

    Magnetic resonance imaging (MRI) with diffusion-tensor imaging (DTI) together with a white matter fiber tracking (FT) technique was used to assess different brain white matter structures and functionalities in schizophrenic patients with typical first negative symptoms. In total, 30 schizophrenic patients with typical first negative symptoms, comprising an observation group were paired 1:1 according to gender, age, right-handedness, and education, with 30 healthy individuals in a control group. Individuals in each group underwent routine MRI and DTI examination of the brain, and diffusion-tensor tractography (DTT) data were obtained through whole brain analysis based on voxel and tractography. The results were expressed by fractional anisotropy (FA) values. The schizophrenic patients were evaluated using a positive and negative symptom scale (PANSS) as well as a Global Assessment Scale (GAS). The results of the study showed that routine MRIs identified no differences between the two groups. However, compared with the control group, the FA values obtained by DTT from the deep left prefrontal cortex, the right deep temporal lobe, the white matter of the inferior frontal gyrus and part of the corpus callosum were significantly lower in the observation group (Pscale value in the observation group averaged 7.7±1.5, and the negative scale averaged 46.6±5.9, while the general psychopathology scale averaged 65.4±10.3, and GAS averaged 53.8±19.2. The Pearson statistical analysis, the left deep prefrontal cortex, the right deep temporal lobe, the white matter of the inferior frontal gyrus and the FA value of part of the corpus callosum in the observation group was negatively correlated with the negative scale (Pnegative symptoms and the application of MRI DTI-FT can improve diagnostic accuracy.

  10. Effect of Water on HEMA Conversion by FT-IR Spectroscopy

    Directory of Open Access Journals (Sweden)

    TS. Jafarzadeh Kashi

    2007-09-01

    Full Text Available Objective: The use of HEMA as a biocompatible material in dentin bonding systems and its potential for clinical applications has been well established. Excess water can affect conversion of bonding resins. The aim of this study was to survey the effect of water on the degree of conversion of HEMA by Fourier Transform Infra-red Spectroscopy (FT-IR.Materials and Methods: In this experimental study, distilled water was added in amounts of 0, 0.05, 0.1, 0.2, and 0.4 ml to 1 ml of curable HEMA solution. Six repetitions per wa-ter ratio were made and investigated. Each sample was polymerized for 60 seconds. De-gree of conversion was obtained from the absorbance IR-Spectrum of the materials before and after polymerization by FT-IR spectroscopy. One way ANOVA and Tukey-HSD were carried out to compare and detect any differences among groups.Results: Statistical analysis indicates highly significant difference between pairs of groups at level (P<0.001. The results showed a trend of decreasing in HEMA conversion with increasing water. Degree of conversion changes significantly within the 0.05 ml to 0.2 ml water range. However, degree of conversion did not change after reaching 0.02 ml and before 0.05.Conclusion: Degree of conversion of HEMA decreased by increasing water. The most dramatic effect of water on the polymerization process occurs within a range which exists under clinical conditions. The reason that the degree of conversion did not show signifi-cant result before 0.05 ml may be related to the hydrophilic nature of HEMA.

  11. DG TO FT - AUTOMATIC TRANSLATION OF DIGRAPH TO FAULT TREE MODELS

    Science.gov (United States)

    Iverson, D. L.

    1994-01-01

    Fault tree and digraph models are frequently used for system failure analysis. Both types of models represent a failure space view of the system using AND and OR nodes in a directed graph structure. Each model has its advantages. While digraphs can be derived in a fairly straightforward manner from system schematics and knowledge about component failure modes and system design, fault tree structure allows for fast processing using efficient techniques developed for tree data structures. The similarities between digraphs and fault trees permits the information encoded in the digraph to be translated into a logically equivalent fault tree. The DG TO FT translation tool will automatically translate digraph models, including those with loops or cycles, into fault tree models that have the same minimum cut set solutions as the input digraph. This tool could be useful, for example, if some parts of a system have been modeled using digraphs and others using fault trees. The digraphs could be translated and incorporated into the fault trees, allowing them to be analyzed using a number of powerful fault tree processing codes, such as cut set and quantitative solution codes. A cut set for a given node is a group of failure events that will cause the failure of the node. A minimum cut set for a node is any cut set that, if any of the failures in the set were to be removed, the occurrence of the other failures in the set will not cause the failure of the event represented by the node. Cut sets calculations can be used to find dependencies, weak links, and vital system components whose failures would cause serious systems failure. The DG TO FT translation system reads in a digraph with each node listed as a separate object in the input file. The user specifies a terminal node for the digraph that will be used as the top node of the resulting fault tree. A fault tree basic event node representing the failure of that digraph node is created and becomes a child of the terminal

  12. Two-step versus one-step FT4 assays in heparin treated patients and non-thyroidal illness

    International Nuclear Information System (INIS)

    Reiners, C.; Bieler, G.; Ertl, G.; Gloss, H.; Boerner, W.

    1985-01-01

    The primary intention of this study is to inform the clinician about the direction and the order of magnitude of possible disturbances of different FT 4 parameters under the condition mentioned last, which is not uncommon in daily routine. No single FT 4 -RIA proved be valid in severe NTI. There is the risk to misinterprete hyperthyroidism as euthyroidism with 1step assays and the possibility to classify euthyroid patients falsely as hyperthyroid with 2step assays. In relation to this problem, the sometimes lowered FT 4 values by 1step methods are clinically not so important. It has to be established, wether TSH assays of high sensitivity are able to overcome some of the difficulties with determinations of peripheral thyroid hormones in NTI. (orig./MG)

  13. FT-IR study of gamma-radiation induced degradation of polyvinyl alcohol (PVA) and PVA/humic acids blends

    International Nuclear Information System (INIS)

    Ilcin, M.; Hola, O.; Bakajova, B.; Kucerik, J.

    2010-01-01

    Samples of pure polyvinyl alcohol (PVA) and PVA doped with humic acids were exposed to gamma radiation. Gamma rays induced the degradation of the pure polymer. Degradation changes were observed using ATR FT-IR equipment. Dehydration, double bond creation, and their subsequent oxidation (surrounding atmosphere was air) were found out. Also, other degradation reactions (e.g. chain scission, cyclization) occur simultaneously. Formation of C=C and C=O bonds is apparent from FT-IR spectra. In contrast the presence of humic acids in the PVA sample showed stabilizing effect on PVA structure within the concentration range 0.5-10%. (author)

  14. The particle analysis based on FT-TIMS technique for swipe sample under the frame of nuclear safeguard

    International Nuclear Information System (INIS)

    Yang Tianli; Liu Xuemei; Liu Zhao; Tang Lei; Long Kaiming

    2008-06-01

    Under the frame of nuclear safeguard, the particles analysis for swipe sample is an advance mean to detect the undeclared uranium enriched facilities and undeclared uranium enriched activity. The technique of particle analysis based on fission track-thermal ionization mass spectrometry (FT-TIMS) for swipe sample have been built. The reliability and the experimental background for selecting particles consisting of uranium from swipe sample by FT method have been verified. In addition, the utilization coefficient of particles on the surface of swipe sample have also been tested. These works have provided the technique support for application in the area of nuclear verification. (authors)

  15. Spectroscopic (FT-IR, FT-Raman, NMR and UV-Visible) and quantum chemical studies of molecular geometry, Frontier molecular orbital, NLO, NBO and thermodynamic properties of salicylic acid.

    Science.gov (United States)

    Suresh, S; Gunasekaran, S; Srinivasan, S

    2014-11-11

    The solid phase FT-IR and FT-Raman spectra of 2-hydroxybenzoic acid (salicylic acid) have been recorded in the region 4000-400 and 4000-100 cm(-1) respectively. The optimized molecular geometry and fundamental vibrational frequencies are interpreted with the aid of structure optimizations and normal coordinate force field calculations based on density functional theory (DFT) method and a comparative study between Hartree Fork (HF) method at 6-311++G(d,p) level basis set. The calculated harmonic vibrational frequencies are scaled and they are compared with experimentally obtained FT-IR and FT-Raman spectra. A detailed interpretation of the vibrational spectra of this compound has been made on the basis of the calculated potential energy distribution (PED). The time dependent DFT method is employed to predict its absorption energy and oscillator strength. The linear polarizability (α) and the first order hyper polarizability (β) values of the investigated molecule have been computed. The electronic properties, such as HOMO and LUMO energies, molecular electrostatic potential (MEP) are also performed. Stability of the molecule arising from hyper conjugative interaction, charge delocalization has been analyzed using natural bond orbital (NBO) analysis. Published by Elsevier B.V.

  16. Spectroscopic investigations (FT-IR & FT-Raman) and molecular docking analysis of 6-[1-methyl-4-nitro-1H-imidazol-5-yl) sulfonyl]-7H-purine

    Science.gov (United States)

    Prasath, M.; Govindammal, M.; Sathya, B.

    2017-10-01

    The Azathioprine is used as anticancer agent. Azathioprine is chemically called 6-[1-methyl-4-nitro-1H-imidazol-5-yl) sulfonyl]-7H-purine (6M4N5P). The vibrational analysis of the 6M4N5P compound was carried out by using FT-IR and FT-Raman spectroscopic techniques and compared with aspects. The optimized geometry, frequency and intensity of the vibrational bands of 6M4N5P were obtained from the HF and DFT methods with 6-31G (d,p) basis set. The harmonic vibrational frequencies were calculated and the scaled values have been compared with experimental FT-IR and FT-Raman spectra. The calculated Highest Occupied Molecular Orbital (HOMO) and Lowest Unoccupied Molecular Orbital (LUMO) energies show that charge transfer occur within the molecule. MEP (Molecular Electrostatic Potential) is very useful in the investigation of the charge distributions and molecular structure. The molecule orbital contributions were determined by using the total density of states (TDOS). A molecular docking analysis has been carried out to understand the conformational change and electrostatic properties of 6M4N5P in the active site of Rac1-Receptor.

  17. Matrix isolation FT-IR spectroscopy and molecular orbital study of sarcosine methyl ester

    Science.gov (United States)

    Gómez-Zavaglia, A.; Fausto, R.

    2004-02-01

    N-methylglycine methyl ester (sarcosine-Me) has been studied by matrix isolation FT-IR spectroscopy and molecular orbital calculations undertaken at the DFT/B3LYP and MP2 levels of theory with the 6-311++G(d,p) and 6-31++G(d,p) basis set, respectively. Twelve different conformers were located in the potential energy surface of the studied compound, with the ASC conformer being the ground conformational state. This form is analogous to the dimethylglycine methyl ester most stable conformer and is characterized by a NH⋯O intramolecular hydrogen bond; in this form, the ester group assumes the cis configuration and the OC-C-N and Lp-N-C-C (where Lp is the nitrogen lone electron pair) dihedral angles are ca. -17.8 and 171.3°, respectively. The second most stable conformer ( GSC) differs from the ASC conformer essentially in the conformation assumed by the methylamino group, which in this case is gauche ( Lp-N-C-C dihedral angle equal to 79.4°). On the other hand, the third most stable conformer ( AAC) differs from the most stable form in the conformation of the OC-C-N axis (151.4°). These three forms were predicted to differ in energy by less than ca. 5 kJ mol -1 and represent ≈95% of the total conformational population at room temperature. FT-IR spectra were obtained for sarcosine-Me isolated in argon matrices (T=9 K) revealing the presence in the matrices of the three lowest energy conformers predicted by the calculations. The matrices were prepared by deposition of the vapour of the compound using two different nozzle temperatures, 25 and 60 °C. The relative populations of the three conformers trapped in the matrices were found to be consistent with occurrence of conformational cooling during matrix deposition and with a stabilization of the most polar GSC and AAC conformers in the matrices compared to the gas phase. Indeed, like it was previously observed for the methyl ester of dimethylglycine [Phys. Chem. Chem. Phys. 5 (2003) 52] the different

  18. Collisional Activation of Peptide Ions in FT-ICR Mass Spectrometry

    International Nuclear Information System (INIS)

    Laskin, Julia; Futrell, Jean H.

    2003-01-01

    In the last decade characterization of complex molecules, particularly biomolecules became a focus of both fundamental and applied research in mass spectrometry. Most of these studies utilize tandem mass spectrometry (MS/MS) for obtaining structural information for complex molecules. . Tandem mass spectrometry (MS/MS) typically involves the mass selection of a primary ion, its activation by collision or photon excitation, unimolecular decay into fragment ions characteristic of the ion structure and its internal excitation, and mass analysis of the fragment ions. Although the fundamental principles of tandem mass spectrometry of relatively small molecules are fairly well understood, our understanding of the activation and fragmentation of large molecules is much more primitive. For small ions a single energetic collision is sufficient to dissociate the ion but this is not the case for complex molecules. For large ions two fundamental limits severely constrain fragmentation in tandem mass spectrometry. First the center-of-mass collision energy?the absolute upper limit of energy transfer in a collision process?decreases with increasing mass of the projectile ion for fixed ion kinetic energy and neutral mass. Secondly, the dramatic increase in density of states with increasing internal degrees of freedom of the ion decreases the rate of dissociation by many orders of magnitude at a given internal energy. Consequently most practical MS/MS experiments with complex ions involve multiple collision activation (MCA-CID), multi-photon activation or surface-induced dissociation (SID). This review is focused on what has been learned in recent research studies concerned with fundamental aspects of MCA-CID and SID of model peptides with emphasis on experiments carried out using Fourier transform ion cyclotron resonance mass spectrometers (FT-ICR MS). These studies provide the first quantitative comparison of gas-phase multiple-collision activation and SID of peptide ions

  19. Analysis of Debris Trajectories at the Scaled Wind Farm Technology (SWiFT) Facility

    Energy Technology Data Exchange (ETDEWEB)

    White, Jonathan R. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Burnett, Damon J. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2016-01-01

    Sandia National Laboratories operates the Scaled Wind Farm Technology Facility (SWiFT) on behalf of the Department of Energy Wind and Water Power Technologies Office. An analysis was performed to evaluate the hazards associated with debris thrown from one of SWiFT’s operating wind turbines, assuming a catastrophic failure. A Monte Carlo analysis was conducted to assess the complex variable space associated with debris throw hazards that included wind speed, wind direction, azimuth and pitch angles of the blade, and percentage of the blade that was separated. In addition, a set of high fidelity explicit dynamic finite element simulations were performed to determine the threshold impact energy envelope for the turbine control building located on-site. Assuming that all of the layered, independent, passive and active engineered safety systems and administrative procedures failed (a 100% failure rate of the safety systems), the likelihood of the control building being struck was calculated to be less than 5/10,000 and ballistic simulations showed that the control building would not provide passive protection for the majority of impact scenarios. Although options exist to improve the ballistic resistance of the control building, the recommendation is not to pursue them because there is a low probability of strike and there is an equal likelihood personnel could be located at similar distances in other areas of the SWiFT facility which are not passively protected, while the turbines are operating. A fenced exclusion area has been created around the turbines which restricts access to the boundary of the 1/100 strike probability. The overall recommendation is to neither relocate nor improve passive protection of the control building as the turbine safety systems have been improved to have no less than two independent, redundant, high quality engineered safety systems. Considering this, in combination with a control building strike probability of less than 5/10,000, the

  20. 'Collisional Activation of Peptide Ions in FT-ICR Mass Spectrometry'

    International Nuclear Information System (INIS)

    Laskin, Julia; Futrell, Jean H.

    2003-01-01

    In the last decade characterization of complex molecules, particularly biomolecules became a focus of both fundamental and applied research in mass spectrometry. Most of these studies utilize tandem mass spectrometry (MS/MS) for obtaining structural information for complex molecules. . Tandem mass spectrometry (MS/MS) typically involves the mass selection of a primary ion, its activation by collision or photon excitation, unimolecular decay into fragment ions characteristic of the ion structure and its internal excitation, and mass analysis of the fragment ions. Although the fundamental principles of tandem mass spectrometry of relatively small molecules are fairly well understood, our understanding of the activation and fragmentation of large molecules is much more primitive. For small ions a single energetic collision is sufficient to dissociate the ion but this is not the case for complex molecules. For large ions two fundamental limits severely constrain fragmentation in tandem mass spectrometry. First the center-of-mass collision energy?the absolute upper limit of energy transfer in a collision process?decreases with increasing mass of the projectile ion for fixed ion kinetic energy and neutral mass. Secondly, the dramatic increase in density of states with increasing internal degrees of freedom of the ion decreases the rate of dissociation by many orders of magnitude at a given internal energy. Consequently most practical MS/MS experiments with complex ions involve multiple collision activation (MCA-CID), multi-photon activation or surface-induced dissociation (SID). This review is focused on what has been learned in recent research studies concerned with fundamental aspects of MCA-CID and SID of model peptides with emphasis on experiments carried out using Fourier transform ion cyclotron resonance mass spectrometers (FT-ICR MS). These studies provide the first quantitative comparison of gas-phase multiple-collision activation and SID of peptide ions